National Library of Energy BETA

Sample records for liquid water clouds

  1. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    2004-02-19

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  2. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  3. Radiative Importance of ThinŽ Liquid Water Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Radiative Transfer Models Turner et al., JAS, 2004 * AERI observations ... Long et al., JGR, 2006 Radiative Importance of "Thin" Liquid Water Clouds Shortwave Turner ...

  4. Comparison of Cloud Fraction and Liquid Water Path between ECMWF...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fraction LidarRadar Liquid Water Path Microwave Radiometer Outputs of the ECMWF forecast model Introduction Comparison Strategy Observed-Modeled Cloud Fraction Comparison of...

  5. Posters Radar/Radiometer Retrievals of Cloud Liquid Water and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for retrieving cloud liquid water content and drizzle characteristics using a K -band Doppler radar (Kropfli et al. 1990) and microwave radiometer (Hogg et al. 1983). The...

  6. ARM - Evaluation Product - MWR Retrievals of Cloud Liquid Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Documentation Use the Data File Inventory tool to view data availability at the file...

  7. ARM - PI Product - MWR Retrievals of Cloud Liquid Water and Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govDataPI Data ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us...

  8. Liquid Water the Key to Arctic Cloud Radiative Closure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water the Key to Arctic Cloud Radiative Closure For original submission and image(s), see ARM Research Highlights http:www.arm.govsciencehighlights Research Highlight...

  9. Remote Spectroscopic Sounding of Liquid Water Path in Thick Clouds in Winter Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Remote Spectroscopic Sounding of Liquid Water Path in Thick Clouds in Winter Conditions S. V. Dvoryashin and G. S. Golitsyn A. M. Obukhov Institute of Atmospheric Physics Russian Academy of Sciences Moscow, Russia The liquid water path (LWP) in mixed clouds is restored based on remote measurements of spectral brightness of a cloudy layer in the spectral range 2.15-2.35µm. The results of spectroscopic sounding of dense clouds sounding are presented. Introduction Since the 1980s, in A. M. Obukhov

  10. New Mexico cloud super cooled liquid water survey final report 2009.

    SciTech Connect (OSTI)

    Beavis, Nick; Roskovensky, John K.; Ivey, Mark D.

    2010-02-01

    Los Alamos and Sandia National Laboratories are partners in an effort to survey the super-cooled liquid water in clouds over the state of New Mexico in a project sponsored by the New Mexico Small Business Assistance Program. This report summarizes the scientific work performed at Sandia National Laboratories during the 2009. In this second year of the project a practical methodology for estimating cloud super-cooled liquid water was created. This was accomplished through the analysis of certain MODIS sensor satellite derived cloud products and vetted parameterizations techniques. A software code was developed to analyze multiple cases automatically. The eighty-one storm events identified in the previous year effort from 2006-2007 were again the focus. Six derived MODIS products were obtained first through careful MODIS image evaluation. Both cloud and clear-sky properties from this dataset were determined over New Mexico. Sensitivity studies were performed that identified the parameters which most influenced the estimation of cloud super-cooled liquid water. Limited validation was undertaken to ensure the soundness of the cloud super-cooled estimates. Finally, a path forward was formulized to insure the successful completion of the initial scientific goals which include analyzing different of annual datasets, validation of the developed algorithm, and the creation of a user-friendly and interactive tool for estimating cloud super-cooled liquid water.

  11. Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds K. Ivanova Pennsylvania State University University Park, Pennsylvania T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington M. Ausloos University of Liège B-4000 Liège, Belgium Abstract We present a method on how to derive an underlying mathematical (statistical or model free) equation for a liquid water path (LWP) signal directly from empirical data. The evolution of the probability density

  12. ARM: Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid...

    Office of Scientific and Technical Information (OSTI)

    Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid Water and Precipitable Water Vapor Title: ARM: Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid Water and ...

  13. Radiative Importance of ThinŽ Liquid Water Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Accomplishments of the Cloud Properties Working Group (CPWG) August 2006 Cloud Radiative Forcing at the ARM Climate Research Facility: Using ARM Data to Establish Testable Metrics for GCM Predictions of Cloud Feedback Gerald Mace University of Utah, Salt Lake City, Utah The scientific underpinning of the Atmospheric Radiation Measurement (ARM) Program is largely based on the premise that long term ground-based measurements of certain quantities provide information sufficient to test the

  14. Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates V. Mattioli and P. Basili Department of Electronic and Information Engineering University of Perugia Perugia, Italy E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado Introduction In recent years the Global

  15. BALTEX BRIDGE cloud liquid water network project: CLIWA-NET

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3/2008 ARM-08 Photo courtesy Bjorn Stevens ARM-GEWEX Cloud System Studies (GCSS) Collaborations: Past-Present-Future A. Pier Siebesma siebesma@knmi.nl chair GCCS KNMI, De Bilt, The Netherlands Technical University Delft Multiscale Physics Group Delft, The Netherlands 4/3/2008 ARM-08 Topics Introduction to GCSS activities Examples and Results for parameterization development in the past. (has it made a difference?) Past and Present Collaborations and results between ARM and GCSS The Future: How

  16. Supercooled liquid water Estimation Tool

    Energy Science and Technology Software Center (OSTI)

    2012-05-04

    The Cloud Supercooled liquid water Estimation Tool (SEET) is a user driven Graphical User Interface (GUI) that estimates cloud supercooled liquid water (SLW) content in terms of vertical column and total mass from Moderate resolution Imaging Supercooled liquid water Estimation Tool Spectroradiometer (MODIS) spatially derived cloud products and realistic vertical cloud parameterizations that are user defined. It also contains functions for post-processing of the resulting data in tabular and graphical form.

  17. Active probing of cloud multiple scattering, optical depth, vertical thickness, and liquid water content using wide-angle imaging LIDAR.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B.; Rohde, C. A.; Tellier, L. L.; Ho, Cheng,

    2002-01-01

    At most optical wavelengths, laser light in a cloud lidar experiment is not absorbed but merely scattered out of the beam, eventually escaping the cloud via multiple scattering. There is much information available in this light scattered far from the input beam, information ignored by traditional 'on-beam' lidar. Monitoring these off-beam returns in a fully space- and time-resolved manner is the essence of our unique instrument, Wide Angle Imaging Lidar (WAIL). In effect, WAIL produces wide-field (60-degree full-angle) 'movies' of the scattering process and records the cloud's radiative Green functions. A direct data product of WAIL is the distribution of photon path lengths resulting from multiple scattering in the cloud. Following insights from diffusion theory, we can use the measured Green functions to infer the physical thickness and optical depth of the cloud layer, and, from there, estimate the volume-averaged liquid water content. WAIL is notable in that it is applicable to optically thick clouds, a regime in which traditional lidar is reduced to ceilometry. Here we present recent WAIL data oti various clouds and discuss the extension of WAIL to full diurnal monitoring by means of an ultra-narrow magneto-optic atomic line filter for daytime measurements.

  18. Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment V. Mattioli Department of Electronic and Information Engineering University of Perugia Perugia, Italy E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado V. Morris Pacific Northwest National

  19. ARM - Measurement - Total cloud water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud water ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total cloud water The...

  20. A New Model for Liquid Water Absorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model for Liquid Water Absorption For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Liquid water path (LWP) is a critical measurement for a wide range of atmospheric studies, as the amount of liquid in a cloud is critical to understanding many cloud processes. For example, the radiative impact of the cloud (in both the longwave and shortwave portions of the spectrum) depends heavily on the LWP. Thus, the Atmospheric

  1. Temperature, Water Vapor, and Clouds"

    Office of Scientific and Technical Information (OSTI)

    on "Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor, and Clouds" Project ID: 0011106 Program Managers: Kirankumar V. Alapaty Phone: 301-903-3175 Division: SC-23.3 and Wanda R. Ferrell Phone: 301-903-0043 Division: SC-23.3 PI: Edgeworth R. Westwater Award Register#: ER640150011106 Overview of Project The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric

  2. Intercomparison of the Cloud Water Phase among Global Climate Models

    SciTech Connect (OSTI)

    Komurcu, Muge; Storelvmo, Trude; Tan, Ivy; Lohmann, U.; Yun, Yuxing; Penner, Joyce E.; Wang, Yong; Liu, Xiaohong; Takemura, T.

    2014-03-27

    Mixed-phase clouds (clouds that consist of both cloud droplets and ice crystals) are frequently present in the Earths atmosphere and influence the Earths energy budget through their radiative properties, which are highly dependent on the cloud water phase. In this study, the phase partitioning of cloud water is compared among six global climate models (GCMs) and with Cloud and Aerosol Lidar with Orthogonal Polarization retrievals. It is found that the GCMs predict vastly different distributions of cloud phase for a given temperature, and none of them are capable of reproducing the spatial distribution or magnitude of the observed phase partitioning. While some GCMs produced liquid water paths comparable to satellite observations, they all failed to preserve sufficient liquid water at mixed-phase cloud temperatures. Our results suggest that validating GCMs using only the vertically integrated water contents could lead to amplified differences in cloud radiative feedback. The sensitivity of the simulated cloud phase in GCMs to the choice of heterogeneous ice nucleation parameterization is also investigated. The response to a change in ice nucleation is quite different for each GCM, and the implementation of the same ice nucleation parameterization in all models does not reduce the spread in simulated phase among GCMs. The results suggest that processes subsequent to ice nucleation are at least as important in determining phase and should be the focus of future studies aimed at understanding and reducing differences among the models.

  3. Satellite determination of stratus cloud microphysical properties...

    Office of Scientific and Technical Information (OSTI)

    of liquid water path from SSMI, broadband albedo from ERBE, and cloud characteristics from ISCCP are used to study stratus regions. An average cloud liquid water path of ...

  4. ARM - Measurement - Liquid water path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water path A measure of the weight of the liquid water...

  5. Determining Cloud Ice Water Path from High-Frequency Microwave...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determining Cloud Ice Water Path from High-Frequency Microwave Measurements G. Liu ... A better understanding of cloud water content and its large-scale distribution ...

  6. Determination of Large-Scale Cloud Ice Water Concentration by...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Determination of Large-Scale Cloud Ice Water Concentration by Combining ... Title: Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface ...

  7. Evaluation of Mixed-Phase Cloud Microphysics Parameterizations...

    Office of Scientific and Technical Information (OSTI)

    the partitioning of condensed water into liquid droplets and ice crystals in these Arctic clouds, which affect modeled cloud phase, cloud lifetime and radiative properties. ...

  8. Water clouds in Y dwarfs and exoplanets

    SciTech Connect (OSTI)

    Morley, Caroline V.; Fortney, Jonathan J.; Marley, Mark S.; Lupu, Roxana; Greene, Tom; Saumon, Didier; Lodders, Katharina

    2014-05-20

    The formation of clouds affects brown dwarf and planetary atmospheres of nearly all effective temperatures. Iron and silicate condense in L dwarf atmospheres and dissipate at the L/T transition. Minor species such as sulfides and salts condense in mid- to late T dwarfs. For brown dwarfs below T {sub eff} ? 450 K, water condenses in the upper atmosphere to form ice clouds. Currently, over a dozen objects in this temperature range have been discovered, and few previous theoretical studies have addressed the effect of water clouds on brown dwarf or exoplanetary spectra. Here we present a new grid of models that include the effect of water cloud opacity. We find that they become optically thick in objects below T {sub eff} ? 350-375 K. Unlike refractory cloud materials, water-ice particles are significantly nongray absorbers; they predominantly scatter at optical wavelengths through the J band and absorb in the infrared with prominent features, the strongest of which is at 2.8 ?m. H{sub 2}O, NH{sub 3}, CH{sub 4}, and H{sub 2} CIA are dominant opacity sources; less abundant species may also be detectable, including the alkalis, H{sub 2}S, and PH{sub 3}. PH{sub 3}, which has been detected in Jupiter, is expected to have a strong signature in the mid-infrared at 4.3 ?m in Y dwarfs around T {sub eff} = 450 K; if disequilibrium chemistry increases the abundance of PH{sub 3}, it may be detectable over a wider effective temperature range than models predict. We show results incorporating disequilibrium nitrogen and carbon chemistry and predict signatures of low gravity in planetary mass objects. Finally, we make predictions for the observability of Y dwarfs and planets with existing and future instruments, including the James Webb Space Telescope and Gemini Planet Imager.

  9. The Role of Shallow Cloud Moistening in MJO and Non-MJO Convective...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to quantify bulk shallow cloud moistening through evaporation of condensed water using a simple method based on observations of liquid water path, cloud depth and temporal...

  10. Cloud Optical Properties from the Multi-Filter Shadowband Radiometer...

    Office of Scientific and Technical Information (OSTI)

    Cloud Optical Properties from the Multi-Filter Shadowband Radiometer (MFRSRCLDOD): An ARM ... 7. The retrieval assumes a single cloud layer consisting solely of liquid water drops. ...

  11. Dataset used to improve liquid water absorption models in the microwave

    Office of Scientific and Technical Information (OSTI)

    (Dataset) | Data Explorer Data Explorer Search Results Dataset used to improve liquid water absorption models in the microwave Title: Dataset used to improve liquid water absorption models in the microwave Two datasets, one a compilation of laboratory data and one a compilation from three field sites, are provided here. These datasets provide measurements of the real and imaginary refractive indices and absorption as a function of cloud temperature. These datasets were used in the

  12. Dataset used to improve liquid water absorption models in the...

    Office of Scientific and Technical Information (OSTI)

    (BER) Country of Publication: United States Availability: ORNL Language: English Subject: 54 Environmental Sciences liquid water absorption, liquid water temperature, fkb, smt ...

  13. COLD WATER VAPOR IN THE BARNARD 5 MOLECULAR CLOUD

    SciTech Connect (OSTI)

    Wirstrm, E. S.; Persson, C. M.; Charnley, S. B.; Cordiner, M. A.; Buckle, J. V.; Takakuwa, S.

    2014-06-20

    After more than 30yr of investigations, the nature of gas-grain interactions at low temperatures remains an unresolved issue in astrochemistry. Water ice is the dominant ice found in cold molecular clouds; however, there is only one region where cold (?10K) water vapor has been detectedL1544. This study aims to shed light on ice desorption mechanisms under cold cloud conditions by expanding the sample. The clumpy distribution of methanol in dark clouds testifies to transient desorption processes at worklikely to also disrupt water ice mantles. Therefore, the Herschel HIFI instrument was used to search for cold water in a small sample of prominent methanol emission peaks. We report detections of the ground-state transition of o-H{sub 2}O (J = 1{sub 10}-1{sub 01}) at 556.9360GHz toward two positions in the cold molecular cloud, Barnard 5. The relative abundances of methanol and water gas support a desorption mechanism which disrupts the outer ice mantle layers, rather than causing complete mantle removal.

  14. Liquid chromatographic determination of water

    DOE Patents [OSTI]

    Fortier, Nancy E.; Fritz, James S.

    1990-11-13

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present.

  15. Liquid chromatographic determination of water

    DOE Patents [OSTI]

    Fortier, N.E.; Fritz, J.S.

    1990-11-13

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present. 1 fig.

  16. Dataset used to improve liquid water absorption models in the microwave

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Turner, David

    2015-12-14

    Two datasets, one a compilation of laboratory data and one a compilation from three field sites, are provided here. These datasets provide measurements of the real and imaginary refractive indices and absorption as a function of cloud temperature. These datasets were used in the development of the new liquid water absorption model that was published in Turner et al. 2015.

  17. Satellite determination of stratus cloud microphysical properties (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Satellite determination of stratus cloud microphysical properties Citation Details In-Document Search Title: Satellite determination of stratus cloud microphysical properties Satellite measurements of liquid water path from SSM/I, broadband albedo from ERBE, and cloud characteristics from ISCCP are used to study stratus regions. An average cloud liquid water path of 0.120{+-}0.032 kg m{sup {minus}2} is derived by dividing the average liquid water path for stratus

  18. A Compact, Backscattering Deplolarization Cloud Spectrometer for Ice and Water Discrimination

    SciTech Connect (OSTI)

    Thomson, David

    2014-05-15

    This project was to develop a compact optical particle spectrometer, small enough for operation on UAVS, that measures the optical diameter of cloud hydrometeors and differentiates their water phase (liquid or solid). To reach this goal, a work plan was laid out that would complete three objectives: 1) Evaluation of designs for an optical particle spectrometer that measures the component of light backscattered at two polarization angles. 2) Testing of selected designs on an optical bench. 3) Construction and preliminary testing of a prototype instrument based on the selected, optimum design. A protoype instrument was developed and tested in an icing wind tunnel where the results showed good measurement of cloud droplets and ice particles.

  19. Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds

    SciTech Connect (OSTI)

    Westwater, Edgeworth

    2011-05-06

    The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement (ARM) Program. At the North Slope of Alaska (NSA), both microwave radiometers (MWR) and the MWRProfiler (MWRP), been used operationally by ARM for passive retrievals of the quantities: Precipitable Water Vapor (PWV) and Liquid Water Path (LWP). However, it has been convincingly shown that these instruments are inadequate to measure low amounts of PWV and LWP. In the case of water vapor, this is especially important during the Arctic winter, when PWV is frequently less than 2 mm. For low amounts of LWP (< 50 g/m{sup 2}), the MWR and MWRP retrievals have an accuracy that is also not acceptable. To address some of these needs, in March-April 2004, NOAA and ARM conducted the NSA Arctic Winter Radiometric Experiment - Water Vapor Intensive Operational Period at the ARM NSA/Adjacent Arctic Ocean (NSA/AAO) site. After this experiment, the radiometer group at NOAA moved to the Center for Environmental Technology (CET) of the Department of Electrical and Computer Engineering of the University of Colorado at Boulder. During this 2004 experiment, a total of 220 radiosondes were launched, and radiometric data from 22.235 to 380 GHz were obtained. Primary instruments included the ARM MWR and MWRP, a Global Positioning System (GPS), as well as the CET Ground-based Scanning Radiometer (GSR). We have analyzed data from these instruments to answer several questions of importance to ARM, including: (a) techniques for improved water vapor measurements; (b) improved calibration techniques during cloudy conditions; (c) the spectral response of radiometers to a variety of conditions: clear, liquid, ice, and mixed phase clouds; and (d) forward modeling of microwave and millimeter wave brightness temperatures from 22 to 380 GHz. Many of these results have been published in the open literature. During the third year of this contract, we participated in another ARM-sponsored experiment at the NSA during February-March 2007. This experiment is called the Radiative Heating in Underexplored Bands Campaign (RHUBC) and the GSR was operated successfully for the duration of the campaign. One of the principal goals of the experiment was to provide retrievals of water vapor during PWV amounts less than 2 mm and to compare GSR data with ARM radiometers and radiosondes. A secondary goal was to compare the radiometric response of the microwave and millimeter wavelength radiometers to water and ice clouds. In this final report, we will include the separate progress reports for each of the three years of the project and follow with a section on major accomplishments of the project.

  20. Determination of 3-D Cloud Ice Water Contents by Combining Multiple...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determination of 3-D Cloud Ice Water Contents by Combining Multiple Data Sources from Satellite, Ground Radar, and a Numerical Model Liu, Guosheng Florida State University Seo,...

  1. Posters Ship-Based Measurements of Cloud Optical Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the optical properties of MBL clouds using measurements taken on the NOAA research vessel Malcom Baldrige. We seek the relationship between optical depth and liquid water because...

  2. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Wednesday, 25 May 2005 00:00 The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the

  3. Transport diffusion of liquid water and methanol through membranes (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Transport diffusion of liquid water and methanol through membranes Citation Details In-Document Search Title: Transport diffusion of liquid water and methanol through membranes The authors carried out dual-control-volume grand canonical molecular dynamics simulations of the transport diffusion of liquid water and methanol to vacuum under a fixed chemical potential gradient through a slit pore consisting of Au(111) surfaces covered by -CH{sub 3} and -OH terminated

  4. Distributed Reforming of Renewable Liquids via Water Splitting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Presented at the 2007 ...

  5. PROGRESS REPORT OF FY 2004 ACTIVITIES: IMPROVED WATER VAPOR AND CLOUD RETRIEVALS AT THE NSA/AAO

    SciTech Connect (OSTI)

    E. R. Westwater; V. V. Leuskiy; M. Klein; A. J. Gasiewski; and J. A. Shaw

    2004-11-01

    The basic goals of the research are to develop and test algorithms and deploy instruments that improve measurements of water vapor, cloud liquid, and cloud coverage, with a focus on the Arctic conditions of cold temperatures and low concentrations of water vapor. The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement Program. Although several technologies have been investigated to measure these column amounts, microwave radiometers (MWR) have been used operationally by the ARM program for passive retrievals of these quantities: precipitable water vapor (PWV) and integrated water liquid (IWL). The technology of PWV and IWL retrievals has advanced steadily since the basic 2-channel MWR was first deployed at ARM CART sites Important advances are the development and refinement of the tipcal calibration method [1,2], and improvement of forward model radiative transfer algorithms [3,4]. However, the concern still remains that current instruments deployed by ARM may be inadequate to measure low amounts of PWV and IWL. In the case of water vapor, this is especially important because of the possibility of scaling and/or quality control of radiosondes by the water amount. Extremely dry conditions, with PWV less than 3 mm, commonly occur in Polar Regions during the winter months. Accurate measurements of the PWV during such dry conditions are needed to improve our understanding of the regional radiation energy budgets. The results of a 1999 experiment conducted at the ARM North Slope of Alaska/Adjacent Arctic Ocean (NSA/AAO) site during March of 1999 [5] have shown that the strength associated with the 183 GHz water vapor absorption line makes radiometry in this frequency regime suitable for measuring low amounts of PWV. As a portion of our research, we conducted another millimeter wave radiometric experiment at the NSA/AAO in March-April 2004. This experiment relied heavily on our experiences of the 1999 experiment. Particular attention was paid to issues of radiometric calibration and radiosonde intercomparisons. Our theoretical and experimental work also supplements efforts by industry (F. Solheim, Private Communication) to develop sub-millimeter radiometers for ARM deployment. In addition to quantitative improvement of water vapor measurements at cold temperature, the impact of adding millimeter-wave window channels to improve the sensitivity to arctic clouds was studied. We also deployed an Infrared Cloud Imager (ICI) during this experiment, both for measuring continuous day-night statistics of the study of cloud coverage and identifying conditions suitable for tipcal analysis. This system provided the first capability of determining spatial cloud statistics continuously in both day and night at the NSA site and has been used to demonstrate that biases exist in inferring cloud statistics from either zenith-pointing active sensors (lidars or radars) or sky imagers that rely on scattered sunlight in daytime and star maps at night [6].

  6. Aqueous Processing of Atmospheric Organic Particles in Cloud Water Collected via Aircraft Sampling

    SciTech Connect (OSTI)

    Boone, Eric J.; Laskin, Alexander; Laskin, Julia; Wirth, Christopher; Shepson, Paul B.; Stirm, Brian H.; Pratt, Kerri A.

    2015-07-21

    Cloud water and below-cloud atmospheric particle samples were collected onboard a research aircraft during the Southern Oxidant and Aerosol Study (SOAS) over a forested region of Alabama in June 2013. The organic molecular composition of the samples was studied to gain insights into the aqueous-phase processing of organic compounds within cloud droplets. High resolution mass spectrometry with nanospray desorption electrospray ionization and direct infusion electrospray ionization were utilized to compare the organic composition of the particle and cloud water samples, respectively. Isoprene and monoterpene-derived organosulfates and oligomers were identified in both the particles and cloud water, showing the significant influence of biogenic volatile organic compound oxidation above the forested region. While the average O:C ratios of the organic compounds were similar between the atmospheric particle and cloud water samples, the chemical composition of these samples was quite different. Specifically, hydrolysis of organosulfates and formation of nitrogen-containing compounds were observed for the cloud water when compared to the atmospheric particle samples, demonstrating that cloud processing changes the composition of organic aerosol.

  7. Detecting Cirrus-Overlapping-Water Clouds and Retrieving their...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clouds and Retrieving their Optical Properties Using MODIS Data F.-L. Chang and Z. Li Earth System Science Interdisciplinary Center University of Maryland College...

  8. An Evaluation of MWR Retrievals of Liquid Water Path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of MWR Retrievals of Liquid Water Path and Precipitable Water Vapor R. T. Marchand and T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington Introduction This paper offers some observations on the quality of Microwave Radiometer (MWR) retrievals of precipitable water vapor (PWV) and liquid water path (LWP). The paper shows case study comparisons between the standard "statistical" approach and those obtained using an iterative solution of the microwave

  9. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  10. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  11. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  12. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  13. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  14. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  15. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  16. Thermoluminescence dosimetry measurements of brachytherapy sources in liquid water

    SciTech Connect (OSTI)

    Tailor, Ramesh; Tolani, Naresh; Ibbott, Geoffrey S.

    2008-09-15

    Radiation therapy dose measurements are customarily performed in liquid water. The characterization of brachytherapy sources is, however, generally based on measurements made with thermoluminescence dosimeters (TLDs), for which contact with water may lead to erroneous readings. Consequently, most dosimetry parameters reported in the literature have been based on measurements in water-equivalent plastics, such as Solid Water. These previous reports employed a correction factor to transfer the dose measurements from a plastic phantom to liquid water. The correction factor most often was based on Monte Carlo calculations. The process of measuring in a water-equivalent plastic phantom whose exact composition may be different from published specifications, then correcting the results to a water medium leads to increased uncertainty in the results. A system has been designed to enable measurements with TLDs in liquid water. This system, which includes jigs to support water-tight capsules of lithium fluoride in configurations suitable for measuring several dosimetric parameters, was used to determine the correction factor from water-equivalent plastic to water. Measurements of several {sup 125}I and {sup 131}Cs prostate brachytherapy sources in liquid water and in a Solid Water phantom demonstrated a correction factor of 1.039{+-}0.005 at 1 cm distance. These measurements are in good agreement with a published value of this correction factor for an {sup 125}I source.

  17. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J.; King, Edward E.; Milliron, Dennis L.

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  18. Cloud&Proper+es:& How&much&water&is&in&a&cloud?&

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summer Training 2015 How much water is in a cloud? ! Cloud&Proper+es:& How&much&water&is&in&a&cloud?& ! ! ! ! presented&by&& Sonja&Drueke&(McGill&University)& Mallory&Row&(University&of&Oklahoma)& &Zhiyuan&Jiang&(Penn&State&University)& &Fabian&Hoffmann&(Leibniz&Universität&Hannover)& & with&guidance&from&!

  19. Microsoft PowerPoint - LIQUID_CLOUD_SUMMARY.final.amv.ppt [Compatibili...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dave Turner and Andy Vogelmann ( p ) ( p ) Cloud Property Working Group Breakout Session ... Measurements and Retrievals g p g p Turner Turner - - Combined AERI and MWR ...

  20. Understanding the Effect of Aerosol Properties on Cloud Droplet Formation

    Office of Scientific and Technical Information (OSTI)

    during TCAP Field Campaign Report (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Understanding the Effect of Aerosol Properties on Cloud Droplet Formation during TCAP Field Campaign Report Citation Details In-Document Search Title: Understanding the Effect of Aerosol Properties on Cloud Droplet Formation during TCAP Field Campaign Report The formation of clouds is an essential element in understanding the Earth's radiative budget. Liquid water clouds

  1. ARSCL Cloud Statistics - A Value-Added Product

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARSCL Cloud Statistics - A Value-Added Product Y. Shi Pacific Northwest National Laboratory Richland, Washington M. A. Miller Brookhaven National Laboratory Upton, New York Introduction The active remote sensing of cloud layers (ARSCLs) value-added product (VAP) combines data from active remote sensors to produce an objective determination of cloud location, radar reflectivity, vertical velocity, and Doppler spectral width. Information about the liquid water path (LWP) in these clouds and the

  2. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Richard A. Ferrare; David D. Turner

    2011-09-01

    Project goals: (1) Use the routine surface and airborne measurements at the ARM SGP site, and the routine surface measurements at the NSA site, to continue our evaluations of model aerosol simulations; (2) Determine the degree to which the Raman lidar measurements of water vapor and aerosol scattering and extinction can be used to remotely characterize the aerosol humidification factor; (3) Use the high temporal resolution CARL data to examine how aerosol properties vary near clouds; and (4) Use the high temporal resolution CARL and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds.

  3. Measurement of radiation damage of water-based liquid scintillator and liquid scintillator

    SciTech Connect (OSTI)

    Bignell, L. J.; Diwan, M. V.; Hans, S.; Jaffe, D. E.; Rosero, R.; Vigdor, S.; Viren, B.; Worcester, E.; Yeh, M.; Zhang, C.

    2015-10-19

    Liquid scintillating phantoms have been proposed as a means to perform real-time 3D dosimetry for proton therapy treatment plan verification. We have studied what effect radiation damage to the scintillator will have upon this application. We have performed measurements of the degradation of the light yield and optical attenuation length of liquid scintillator and water-based liquid scintillator after irradiation by 201 MeV proton beams that deposited doses of approximately 52 Gy, 300 Gy, and 800 Gy in the scintillator. Liquid scintillator and water-based liquid scintillator (composed of 5% scintillating phase) exhibit light yield reductions of 1.74 ± 0.55 % and 1.31 ± 0.59 % after ≈ 800 Gy of proton dose, respectively. Some increased optical attenuation was observed in the irradiated samples, the measured reduction to the light yield is also due to damage to the scintillation light production. Based on our results and conservative estimates of the expected dose in a clinical context, a scintillating phantom used for proton therapy treatment plan verification would exhibit a systematic light yield reduction of approximately 0.1% after a year of operation.

  4. Measurement of radiation damage of water-based liquid scintillator and liquid scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bignell, L. J.; Diwan, M. V.; Hans, S.; Jaffe, D. E.; Rosero, R.; Vigdor, S.; Viren, B.; Worcester, E.; Yeh, M.; Zhang, C.

    2015-10-19

    Liquid scintillating phantoms have been proposed as a means to perform real-time 3D dosimetry for proton therapy treatment plan verification. We have studied what effect radiation damage to the scintillator will have upon this application. We have performed measurements of the degradation of the light yield and optical attenuation length of liquid scintillator and water-based liquid scintillator after irradiation by 201 MeV proton beams that deposited doses of approximately 52 Gy, 300 Gy, and 800 Gy in the scintillator. Liquid scintillator and water-based liquid scintillator (composed of 5% scintillating phase) exhibit light yield reductions of 1.74 ± 0.55 % andmore » 1.31 ± 0.59 % after ≈ 800 Gy of proton dose, respectively. Some increased optical attenuation was observed in the irradiated samples, the measured reduction to the light yield is also due to damage to the scintillation light production. Based on our results and conservative estimates of the expected dose in a clinical context, a scintillating phantom used for proton therapy treatment plan verification would exhibit a systematic light yield reduction of approximately 0.1% after a year of operation.« less

  5. Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds

    SciTech Connect (OSTI)

    Turner, David, D.; Ferrare, Richard, A.

    2011-07-06

    The 'Evaluating Global Aerosol Models and Aerosol and Water Vapor Properties Near Clouds' project focused extensively on the analysis and utilization of water vapor and aerosol profiles derived from the ARM Raman lidar at the Southern Great Plains ARM site. A wide range of different tasks were performed during this project, all of which improved quality of the data products derived from the lidar or advanced the understanding of atmospheric processes over the site. These activities included: upgrading the Raman lidar to improve its sensitivity; participating in field experiments to validate the lidar aerosol and water vapor retrievals; using the lidar aerosol profiles to evaluate the accuracy of the vertical distribution of aerosols in global aerosol model simulations; examining the correlation between relative humidity and aerosol extinction, and how these change, due to horizontal distance away from cumulus clouds; inferring boundary layer turbulence structure in convective boundary layers from the high-time-resolution lidar water vapor measurements; retrieving cumulus entrainment rates in boundary layer cumulus clouds; and participating in a field experiment that provided data to help validate both the entrainment rate retrievals and the turbulent profiles derived from lidar observations.

  6. Posters Parameterization of Thin Mid-Level Stratiform Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thickness or its tendency within a GCM layer from the large-scale fields. 5. Develop and test a parameterization of altocumulus cloud layer optical properties (liquid water path...

  7. ARM - Measurement - Cloud effective radius

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the number size distribution of cloud particles, whether liquid or ice. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  8. MWRRET Value-Added Product: The Retrieval of Liquid Water Path...

    Office of Scientific and Technical Information (OSTI)

    MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2) Citation Details In-Document ...

  9. Testing cloud microphysics parameterizations in NCAR CAM5 with ISDAC and M-PACE observations

    SciTech Connect (OSTI)

    Liu X.; Lin W.; Xie, S.; Boyle, J.; Klein, S. A.; Shi, X.; Wang, Z.; Ghan, S. J.; Earle, M.; Liu, P. S. K.; Zelenyuk, A.

    2011-12-24

    Arctic clouds simulated by the National Center for Atmospheric Research (NCAR) Community Atmospheric Model version 5 (CAM5) are evaluated with observations from the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Indirect and Semi-Direct Aerosol Campaign (ISDAC) and Mixed-Phase Arctic Cloud Experiment (M-PACE), which were conducted at its North Slope of Alaska site in April 2008 and October 2004, respectively. Model forecasts for the Arctic spring and fall seasons performed under the Cloud-Associated Parameterizations Testbed framework generally reproduce the spatial distributions of cloud fraction for single-layer boundary-layer mixed-phase stratocumulus and multilayer or deep frontal clouds. However, for low-level stratocumulus, the model significantly underestimates the observed cloud liquid water content in both seasons. As a result, CAM5 significantly underestimates the surface downward longwave radiative fluxes by 20-40 W m{sup -2}. Introducing a new ice nucleation parameterization slightly improves the model performance for low-level mixed-phase clouds by increasing cloud liquid water content through the reduction of the conversion rate from cloud liquid to ice by the Wegener-Bergeron-Findeisen process. The CAM5 single-column model testing shows that changing the instantaneous freezing temperature of rain to form snow from -5 C to -40 C causes a large increase in modeled cloud liquid water content through the slowing down of cloud liquid and rain-related processes (e.g., autoconversion of cloud liquid to rain). The underestimation of aerosol concentrations in CAM5 in the Arctic also plays an important role in the low bias of cloud liquid water in the single-layer mixed-phase clouds. In addition, numerical issues related to the coupling of model physics and time stepping in CAM5 are responsible for the model biases and will be explored in future studies.

  10. Process-model Simulations of Cloud Albedo Enhancement by Aerosols in the Arctic

    SciTech Connect (OSTI)

    Kravitz, Benjamin S.; Wang, Hailong; Rasch, Philip J.; Morrison, H.; Solomon, Amy

    2014-11-17

    A cloud-resolving model is used to simulate the effectiveness of Arctic marine cloud brightening via injection of cloud condensation nuclei (CCN). An updated cloud microphysical scheme is employed, with prognostic CCN and cloud particle numbers in both liquid and mixed-phase marine low clouds. Injection of CCN into the marine boundary layer can delay the collapse of the boundary layer and increase low-cloud albedo. Because nearly all of the albedo effects are in the liquid phase due to the removal of ice water by snowfall when ice processes are involved, albedo increases are stronger for pure liquid clouds than mixed-phase clouds. Liquid precipitation can be suppressed by CCN injection, whereas ice precipitation (snow) is affected less; thus the effectiveness of brightening mixed-phase clouds is lower than for liquid-only clouds. CCN injection into a clean regime results in a greater albedo increase than injection into a polluted regime, consistent with current knowledge about aerosol-cloud interactions. Unlike previous studies investigating warm clouds, dynamical changes in circulation due to precipitation changes are small.

  11. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  12. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  13. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  14. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  15. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  16. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  17. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  18. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  19. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  20. Deriving Arctic Cloud Microphysics at Barrow, Alaska. Algorithms, Results, and Radiative Closure

    SciTech Connect (OSTI)

    Shupe, Matthew D.; Turner, David D.; Zwink, Alexander; Thieman, Mandana M.; Mlawer, Eli J.; Shippert, Timothy

    2015-07-01

    Cloud phase and microphysical properties control the radiative effects of clouds in the climate system and are therefore crucial to characterize in a variety of conditions and locations. An Arctic-specific, ground-based, multi-sensor cloud retrieval system is described here and applied to two years of observations from Barrow, Alaska. Over these two years, clouds occurred 75% of the time, with cloud ice and liquid each occurring nearly 60% of the time. Liquid water occurred at least 25% of the time even in the winter, and existed up to heights of 8 km. The vertically integrated mass of liquid was typically larger than that of ice. While it is generally difficult to evaluate the overall uncertainty of a comprehensive cloud retrieval system of this type, radiative flux closure analyses were performed where flux calculations using the derived microphysical properties were compared to measurements at the surface and top-of-atmosphere. Radiative closure biases were generally smaller for cloudy scenes relative to clear skies, while the variability of flux closure results was only moderately larger than under clear skies. The best closure at the surface was obtained for liquid-containing clouds. Radiative closure results were compared to those based on a similar, yet simpler, cloud retrieval system. These comparisons demonstrated the importance of accurate cloud phase classification, and specifically the identification of liquid water, for determining radiative fluxes. Enhanced retrievals of liquid water path for thin clouds were also shown to improve radiative flux calculations.

  1. A unified parameterization of clouds and turbulence using CLUBB and subcolumns in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thayer-Calder, K.; Gettelman, A.; Craig, C.; Goldhaber, S.; Bogenschutz, P. A.; Chen, C.-C.; Morrison, H.; Höft, J.; Raut, E.; Griffin, B. M.; et al

    2015-06-30

    Most global climate models parameterize separate cloud types using separate parameterizations. This approach has several disadvantages, including obscure interactions between parameterizations and inaccurate triggering of cumulus parameterizations. Alternatively, a unified cloud parameterization uses one equation set to represent all cloud types. Such cloud types include stratiform liquid and ice cloud, shallow convective cloud, and deep convective cloud. Vital to the success of a unified parameterization is a general interface between clouds and microphysics. One such interface involves drawing Monte Carlo samples of subgrid variability of temperature, water vapor, cloud liquid, and cloud ice, and feeding the sample points into amore » microphysics scheme. This study evaluates a unified cloud parameterization and a Monte Carlo microphysics interface that has been implemented in the Community Atmosphere Model (CAM) version 5.3. Results describing the mean climate and tropical variability from global simulations are presented. The new model shows a degradation in precipitation skill but improvements in short-wave cloud forcing, liquid water path, long-wave cloud forcing, precipitable water, and tropical wave simulation. Also presented are estimations of computational expense and investigation of sensitivity to number of subcolumns.« less

  2. A unified parameterization of clouds and turbulence using CLUBB and subcolumns in the Community Atmosphere Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thayer-Calder, K.; Gettelman, A.; Craig, C.; Goldhaber, S.; Bogenschutz, P. A.; Chen, C.-C.; Morrison, H.; Höft, J.; Raut, E.; Griffin, B. M.; et al

    2015-12-01

    Most global climate models parameterize separate cloud types using separate parameterizations. This approach has several disadvantages, including obscure interactions between parameterizations and inaccurate triggering of cumulus parameterizations. Alternatively, a unified cloud parameterization uses one equation set to represent all cloud types. Such cloud types include stratiform liquid and ice cloud, shallow convective cloud, and deep convective cloud. Vital to the success of a unified parameterization is a general interface between clouds and microphysics. One such interface involves drawing Monte Carlo samples of subgrid variability of temperature, water vapor, cloud liquid, and cloud ice, and feeding the sample points into amore » microphysics scheme. This study evaluates a unified cloud parameterization and a Monte Carlo microphysics interface that has been implemented in the Community Atmosphere Model (CAM) version 5.3. Model computational expense is estimated, and sensitivity to the number of subcolumns is investigated. Results describing the mean climate and tropical variability from global simulations are presented. The new model shows a degradation in precipitation skill but improvements in shortwave cloud forcing, liquid water path, long-wave cloud forcing, precipitable water, and tropical wave simulation.« less

  3. Parameterizing Size Distribution in Ice Clouds

    SciTech Connect (OSTI)

    DeSlover, Daniel; Mitchell, David L.

    2009-09-25

    PARAMETERIZING SIZE DISTRIBUTIONS IN ICE CLOUDS David L. Mitchell and Daniel H. DeSlover ABSTRACT An outstanding problem that contributes considerable uncertainty to Global Climate Model (GCM) predictions of future climate is the characterization of ice particle sizes in cirrus clouds. Recent parameterizations of ice cloud effective diameter differ by a factor of three, which, for overcast conditions, often translate to changes in outgoing longwave radiation (OLR) of 55 W m-2 or more. Much of this uncertainty in cirrus particle sizes is related to the problem of ice particle shattering during in situ sampling of the ice particle size distribution (PSD). Ice particles often shatter into many smaller ice fragments upon collision with the rim of the probe inlet tube. These small ice artifacts are counted as real ice crystals, resulting in anomalously high concentrations of small ice crystals (D < 100 m) and underestimates of the mean and effective size of the PSD. Half of the cirrus cloud optical depth calculated from these in situ measurements can be due to this shattering phenomenon. Another challenge is the determination of ice and liquid water amounts in mixed phase clouds. Mixed phase clouds in the Arctic contain mostly liquid water, and the presence of ice is important for determining their lifecycle. Colder high clouds between -20 and -36 oC may also be mixed phase but in this case their condensate is mostly ice with low levels of liquid water. Rather than affecting their lifecycle, the presence of liquid dramatically affects the cloud optical properties, which affects cloud-climate feedback processes in GCMs. This project has made advancements in solving both of these problems. Regarding the first problem, PSD in ice clouds are uncertain due to the inability to reliably measure the concentrations of the smallest crystals (D < 100 m), known as the small mode. Rather than using in situ probe measurements aboard aircraft, we employed a treatment of ice cloud optical properties formulated in terms of PSD parameters in combination with remote measurements of thermal radiances to characterize the small mode. This is possible since the absorption efficiency (Qabs) of small mode crystals is larger at 12 m wavelength relative to 11 m wavelength due to the process of wave resonance or photon tunneling more active at 12 m. This makes the 12/11 m absorption optical depth ratio (or equivalently the 12/11 m Qabs ratio) a means for detecting the relative concentration of small ice particles in cirrus. Using this principle, this project tested and developed PSD schemes that can help characterize cirrus clouds at each of the three ARM sites: SGP, NSA and TWP. This was the main effort of this project. These PSD schemes and ice sedimentation velocities predicted from them have been used to test the new cirrus microphysics parameterization in the GCM known as the Community Climate Systems Model (CCSM) as part of an ongoing collaboration with NCAR. Regarding the second problem, we developed and did preliminary testing on a passive thermal method for retrieving the total water path (TWP) of Arctic mixed phase clouds where TWPs are often in the range of 20 to 130 g m-2 (difficult for microwave radiometers to accurately measure). We also developed a new radar method for retrieving the cloud ice water content (IWC), which can be vertically integrated to yield the ice water path (IWP). These techniques were combined to determine the IWP and liquid water path (LWP) in Arctic clouds, and hence the fraction of ice and liquid water. We have tested this approach using a case study from the ARM field campaign called M-PACE (Mixed-Phase Arctic Cloud Experiment). This research led to a new satellite remote sensing method that appears promising for detecting low levels of liquid water in high clouds typically between -20 and -36 oC. We hope to develop this method in future research.

  4. Detection of water masers toward young stellar objects in the Large Magellanic Cloud

    SciTech Connect (OSTI)

    Johanson, A. K.; Migenes, V.; Breen, S. L.

    2014-02-01

    We present results from a search for water maser emission toward N4A, N190, and N206, three regions of massive star formation in the Large Magellanic Cloud (LMC). Four water masers were detected; two toward N4A, and two toward N190. In the latter region, no previously known maser emission has been reported. Future studies of maser proper motion to determine the galactic dynamics of the LMC will benefit from the independent data points the new masers in N190 provide. Two of these masers are associated with previously identified massive young stellar objects (YSOs), which strongly supports the authenticity of the classification. We argue that the other two masers identify previously unknown YSOs. No masers were detected toward N206, but it does host a newly discovered 22 GHz continuum source, also associated with a massive YSO. We suggest that future surveys for water maser emission in the LMC be targeted toward the more luminous, massive YSOs.

  5. Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud

    SciTech Connect (OSTI)

    Klein, S A; McCoy, R B; Morrison, H; Ackerman, A; Avramov, A; deBoer, G; Chen, M; Cole, J; DelGenio, A; Golaz, J; Hashino, T; Harrington, J; Hoose, C; Khairoutdinov, M; Larson, V; Liu, X; Luo, Y; McFarquhar, G; Menon, S; Neggers, R; Park, S; Poellot, M; von Salzen, K; Schmidt, J; Sednev, I; Shipway, B; Shupe, M; Spangenberg, D; Sud, Y; Turner, D; Veron, D; Falk, M; Foster, M; Fridlind, A; Walker, G; Wang, Z; Wolf, A; Xie, S; Xu, K; Yang, F; Zhang, G

    2008-02-27

    Results are presented from an intercomparison of single-column and cloud-resolving model simulations of a cold-air outbreak mixed-phase stratocumulus cloud observed during the Atmospheric Radiation Measurement (ARM) program's Mixed-Phase Arctic Cloud Experiment. The observed cloud occurred in a well-mixed boundary layer with a cloud top temperature of -15 C. The observed liquid water path of around 160 g m{sup -2} was about two-thirds of the adiabatic value and much greater than the mass of ice crystal precipitation which when integrated from the surface to cloud top was around 15 g m{sup -2}. The simulations were performed by seventeen single-column models (SCMs) and nine cloud-resolving models (CRMs). While the simulated ice water path is generally consistent with the observed values, the median SCM and CRM liquid water path is a factor of three smaller than observed. Results from a sensitivity study in which models removed ice microphysics indicate that in many models the interaction between liquid and ice-phase microphysics is responsible for the large model underestimate of liquid water path. Despite this general underestimate, the simulated liquid and ice water paths of several models are consistent with the observed values. Furthermore, there is some evidence that models with more sophisticated microphysics simulate liquid and ice water paths that are in better agreement with the observed values, although considerable scatter is also present. Although no single factor guarantees a good simulation, these results emphasize the need for improvement in the model representation of mixed-phase microphysics. This case study, which has been well observed from both aircraft and ground-based remote sensors, could be a benchmark for model simulations of mixed-phase clouds.

  6. Testing Cloud Microphysics Parameterizations in NCAR CAM5 with ISDAC and M-PACE Observations

    SciTech Connect (OSTI)

    Liu, Xiaohong; Xie, Shaocheng; Boyle, James; Klein, Stephen A.; Shi, Xiangjun; Wang, Zhien; Lin, Wuyin; Ghan, Steven J.; Earle, Michael; Liu, Peter; Zelenyuk, Alla

    2011-12-24

    Arctic clouds simulated by the NCAR Community Atmospheric Model version 5 (CAM5) are evaluated with observations from the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Indirect and Semi-Direct Aerosol Campaign (ISDAC) and Mixed-Phase Arctic Cloud Experiment (M-PACE), which were conducted at its North Slope of Alaska site in April 2008 and October 2004, respectively. Model forecasts for the Arctic Spring and Fall seasons performed under the Cloud- Associated Parameterizations Testbed (CAPT) framework generally reproduce the spatial distributions of cloud fraction for single-layer boundary layer mixed-phase stratocumulus, and multilayer or deep frontal clouds. However, for low-level clouds, the model significantly underestimates the observed cloud liquid water content in both seasons and cloud fraction in the Spring season. As a result, CAM5 significantly underestimates the surface downward longwave (LW) radiative fluxes by 20-40 W m-2. The model with a new ice nucleation parameterization moderately improves the model simulations by increasing cloud liquid water content in mixed-phase clouds through the reduction of the conversion rate from cloud liquid to ice by the Wegener-Bergeron- Findeisen (WBF) process. The CAM5 single column model testing shows that change in the homogeneous freezing temperature of rain to form snow from -5 C to -40 C has a substantial impact on the modeled liquid water content through the slowing-down of liquid and rain-related processes. In contrast, collections of cloud ice by snow and cloud liquid by rain are of minor importance for single-layer boundary layer mixed-phase clouds in the Arctic.

  7. Arctic Mixed-Phase Cloud Properties from AERI Lidar Observations: Algorithm and Results from SHEBA

    SciTech Connect (OSTI)

    Turner, David D.

    2005-04-01

    A new approach to retrieve microphysical properties from mixed-phase Arctic clouds is presented. This mixed-phase cloud property retrieval algorithm (MIXCRA) retrieves cloud optical depth, ice fraction, and the effective radius of the water and ice particles from ground-based, high-resolution infrared radiance and lidar cloud boundary observations. The theoretical basis for this technique is that the absorption coefficient of ice is greater than that of liquid water from 10 to 13 ?m, whereas liquid water is more absorbing than ice from 16 to 25 ?m. MIXCRA retrievals are only valid for optically thin (?visible < 6) single-layer clouds when the precipitable water vapor is less than 1 cm. MIXCRA was applied to the Atmospheric Emitted Radiance Interferometer (AERI) data that were collected during the Surface Heat Budget of the Arctic Ocean (SHEBA) experiment from November 1997 to May 1998, where 63% of all of the cloudy scenes above the SHEBA site met this specification. The retrieval determined that approximately 48% of these clouds were mixed phase and that a significant number of clouds (during all 7 months) contained liquid water, even for cloud temperatures as low as 240 K. The retrieved distributions of effective radii for water and ice particles in single-phase clouds are shown to be different than the effective radii in mixed-phase clouds.

  8. Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water

    Office of Scientific and Technical Information (OSTI)

    Vapor and Clouds (Technical Report) | SciTech Connect Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds Citation Details In-Document Search Title: Microwave and Millimeter-Wave Radiometric Studies of Temperature, Water Vapor and Clouds The importance of accurate measurements of column amounts of water vapor and cloud liquid has been well documented by scientists within the Atmospheric Radiation Measurement (ARM) Program. At the North Slope of Alaska

  9. MWRRET Value-Added Product: The Retrieval of Liquid Water Path and

    Office of Scientific and Technical Information (OSTI)

    Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2) (Technical Report) | SciTech Connect MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2) Citation Details In-Document Search Title: MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2) This report provides a short description

  10. MWRRET Value-Added Product: The Retrieval of Liquid Water Path and

    Office of Scientific and Technical Information (OSTI)

    Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2) (Technical Report) | SciTech Connect MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2) Citation Details In-Document Search Title: MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2) × You are accessing a document from the

  11. Electrokinetic Hydrogen Generation from Liquid WaterMicrojets

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Saykally, Richard J.

    2007-05-31

    We describe a method for generating molecular hydrogen directly from the charge separation effected via rapid flow of liquid water through a metal orifice, wherein the input energy is the hydrostatic pressure times the volume flow rate. Both electrokinetic currents and hydrogen production rates are shown to follow simple equations derived from the overlap of the fluid velocity gradient and the anisotropic charge distribution resulting from selective adsorption of hydroxide ions to the nozzle surface. Pressure-driven fluid flow shears away the charge balancing hydronium ions from the diffuse double layer and carries them out of the aperture. Downstream neutralization of the excess protons at a grounded target electrode produces gaseous hydrogen molecules. The hydrogen production efficiency is currently very low (ca. 10-6) for a single cylindrical jet, but can be improved with design changes.

  12. Characterization and Modeling of a Water-based Liquid Scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    L. J. Bignell; Beznosko, D.; Diwan, M. V.; Hans, S.; Jaffe, D. E.; S. Kettell; Rosero, R.; Themann, H. W.; Viren, B.; Worcester, E.; et al

    2015-12-15

    We characterised Water-based Liquid Scintillator (WbLS) using low energy protons, UV-VIS absorbance, and fluorescence spectroscopy. We have also developed and validated a simulation model that describes the behaviour of WbLS in our detector configurations for proton beam energies of 210 MeV, 475 MeV, and 2 GeV and for two WbLS compositions. These results have enabled us to estimate the light yield and ionisation quenching of WbLS, as well as to understand the influence of the wavelength shifting of Cherenkov light on our measurements. These results are relevant to the suitability of WbLS materials for next generation intensity frontier experiments.

  13. Detachment of Liquid-Water Droplets from Gas-Diffusion Layers

    SciTech Connect (OSTI)

    Das, Prodip K.; Grippin, Adam; Weber, Adam Z.

    2011-07-01

    A critical issue for optimal water management in proton-exchange-membrane fuel cells at lower temperatures is the removal of liquid water from the cell. This pathway is intimately linked with the phenomena of liquid-water droplet removal from surface of the gas-diffusion layer and into the flow channel. Thus, a good understanding of liquid-water transport and droplet growth and detachment from the gas-diffusion layer is critical. In this study, liquid-water droplet growth and detachment on the gas-diffusion layer surfaces are investigated experimentally to improve the understating of water transport through and removal from gas-diffusion layers. An experiment using a sliding-angle measurement is designed and used to quantify and directly measure the adhesion force for liquid-water droplets, and to understand the droplets? growth and detachment from the gas-diffusion layers.

  14. Microbase Cloud Products and Associated Heating Rates in the Tropical Western Pacific

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microbase Cloud Products and Associated Heating Rates in the Tropical Western Pacific J. H. Mather and S. A. McFarlane Pacific Northwest National Laboratory Richland, Washington Introduction The microbase value added product (Miller et al. 2003) provides a standardized framework for calculating and storing continuous retrievals of cloud microphysical properties including liquid water content (LWC), ice water content (IWC), and cloud droplet size. Microbase is part of the larger broadband heating

  15. Network analysis of proton transfer in liquid water

    SciTech Connect (OSTI)

    Shevchuk, Roman; Rao, Francesco; Agmon, Noam

    2014-06-28

    Proton transfer in macromolecular systems is a fascinating yet elusive process. In the last ten years, molecular simulations have shown to be a useful tool to unveil the atomistic mechanism. Notwithstanding, the large number of degrees of freedom involved make the accurate description of the process very hard even for the case of proton diffusion in bulk water. Here, multi-state empirical valence bond molecular dynamics simulations in conjunction with complex network analysis are applied to study proton transfer in liquid water. Making use of a transition network formalism, this approach takes into account the time evolution of several coordinates simultaneously. Our results provide evidence for a strong dependence of proton transfer on the length of the hydrogen bond solvating the Zundel complex, with proton transfer enhancement as shorter bonds are formed at the acceptor site. We identify six major states (nodes) on the network leading from the special pair to a more symmetric Zundel complex required for transferring the proton. Moreover, the second solvation shell specifically rearranges to promote the transfer, reiterating the idea that solvation beyond the first shell of the Zundel complex plays a crucial role in the process.

  16. METHANE GAS STABILIZES SUPERCOOLED ETHANE DROPLETS IN TITAN'S CLOUDS

    SciTech Connect (OSTI)

    Wang, Chia C.; Lang, E. Kathrin; Signorell, Ruth

    2010-03-20

    Strong evidence for ethane clouds in various regions of Titan's atmosphere has recently been found. Ethane is usually assumed to exist as ice particles in these clouds, although the possible role of liquid and supercooled liquid ethane droplets has been recognized. Here, we report on infrared spectroscopic measurements of ethane aerosols performed in the laboratory under conditions mimicking Titan's lower atmosphere. The results clearly show that liquid ethane droplets are significantly stabilized by methane gas which is ubiquitous in Titan's nitrogen atmosphere-a phenomenon that does not have a counterpart for water droplets in Earth's atmosphere. Our data imply that supercooled ethane droplets are much more abundant in Titan's clouds than previously anticipated. Possibly, these liquid droplets are even more important for cloud processes and the formation of lakes than ethane ice particles.

  17. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Wednesday, 24 September 2008 00:00 The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding

  18. Microphysical Properties of Single and Mixed-Phase Arctic Clouds Derived from AERI Observations

    SciTech Connect (OSTI)

    Turner, David D.

    2003-06-01

    A novel new approach to retrieve cloud microphysical properties from mixed-phase clouds is presented. This algorithm retrieves cloud optical depth, ice fraction, and the effective size of the water and ice particles from ground-based, high-resolution infrared radiance observations. The theoretical basis is that the absorption coefficient of ice is stronger than that of liquid water from 10-13 mm, whereas liquid water is more absorbing than ice from 16-25 um. However, due to strong absorption in the rotational water vapor absorption band, the 16-25 um spectral region becomes opaque for significant water vapor burdens (i.e., for precipitable water vapor amounts over approximately 1 cm). The Arctic is characterized by its dry and cold atmosphere, as well as a preponderance of mixed-phase clouds, and thus this approach is applicable to Arctic clouds. Since this approach uses infrared observations, cloud properties are retrieved at night and during the long polar wintertime period. The analysis of the cloud properties retrieved during a 7 month period during the Surface Heat Budget of the Arctic (SHEBA) experiment demonstrates many interesting features. These results show a dependence of the optical depth on cloud phase, differences in the mode radius of the water droplets in liquid-only and mid-phase clouds, a lack of temperature dependence in the ice fraction for temperatures above 240 K, seasonal trends in the optical depth with the clouds being thinner in winter and becoming more optically thick in the late spring, and a seasonal trend in the effective size of the water droplets in liquid-only and mixed-phase clouds that is most likely related to aerosol concentration.

  19. Water-saving liquid-gas conditioning system

    DOE Patents [OSTI]

    Martin, Christopher; Zhuang, Ye

    2014-01-14

    A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

  20. ARM - Publications: Science Team Meeting Documents: Liquid water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    models (Liebe,1987; Rosenkranz,1998; Liljegren, 2004) and 3 liquid dielectric models (Grant, 1957; Liebe, 1991; Rosenkranz, 2003) are evaluated. The choice of gaseous...

  1. Water-saving liquid-gas conditioning system (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Water-saving liquid-gas conditioning system Citation Details In-Document Search Title: Water-saving liquid-gas conditioning system A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a

  2. Process for hydrogen isotope concentration between liquid water and hydrogen gas

    DOE Patents [OSTI]

    Stevens, William H.

    1976-09-21

    A process for hydrogen isotope exchange and concentration between liquid water and hydrogen gas, wherein liquid water and hydrogen gas are contacted, in an exchange section, with one another and with at least one catalyst body comprising at least one metal selected from Group VIII of the Periodic Table and preferably a support therefor, the catalyst body has a liquid-water-repellent, gas permeable polymer or organic resin coating, preferably a fluorinated olefin polymer or silicone coating, so that the isotope concentration takes place by two simultaneously occurring steps, namely, ##EQU1## WHILE THE HYDROGEN GAS FED TO THE EXCHANGE SECTION IS DERIVED IN A REACTOR VESSEL FROM LIQUID WATER THAT HAS PASSED THROUGH THE EXCHANGE SECTION.

  3. Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface Radar and Satellite Data in Support of ARM SCM Activities

    SciTech Connect (OSTI)

    Liu, Guosheng

    2013-03-15

    Single-column modeling (SCM) is one of the key elements of Atmospheric Radiation Measurement (ARM) research initiatives for the development and testing of various physical parameterizations to be used in general circulation models (GCMs). The data required for use with an SCM include observed vertical profiles of temperature, water vapor, and condensed water, as well as the large-scale vertical motion and tendencies of temperature, water vapor, and condensed water due to horizontal advection. Surface-based measurements operated at ARM sites and upper-air sounding networks supply most of the required variables for model inputs, but do not provide the horizontal advection term of condensed water. Since surface cloud radar and microwave radiometer observations at ARM sites are single-point measurements, they can provide the amount of condensed water at the location of observation sites, but not a horizontal distribution of condensed water contents. Consequently, observational data for the large-scale advection tendencies of condensed water have not been available to the ARM cloud modeling community based on surface observations alone. This lack of advection data of water condensate could cause large uncertainties in SCM simulations. Additionally, to evaluate GCMs’ cloud physical parameterization, we need to compare GCM results with observed cloud water amounts over a scale that is large enough to be comparable to what a GCM grid represents. To this end, the point-measurements at ARM surface sites are again not adequate. Therefore, cloud water observations over a large area are needed. The main goal of this project is to retrieve ice water contents over an area of 10 x 10 deg. surrounding the ARM sites by combining surface and satellite observations. Built on the progress made during previous ARM research, we have conducted the retrievals of 3-dimensional ice water content by combining surface radar/radiometer and satellite measurements, and have produced 3-D cloud ice water contents in support of cloud modeling activities. The approach of the study is to expand a (surface) point measurement to an (satellite) area measurement. That is, the study takes the advantage of the high quality cloud measurements (particularly cloud radar and microwave radiometer measurements) at the point of the ARM sites. We use the cloud ice water characteristics derived from the point measurement to guide/constrain a satellite retrieval algorithm, then use the satellite algorithm to derive the 3-D cloud ice water distributions within an 10° (latitude) x 10° (longitude) area. During the research period, we have developed, validated and improved our cloud ice water retrievals, and have produced and archived at ARM website as a PI-product of the 3-D cloud ice water contents using combined satellite high-frequency microwave and surface radar observations for SGP March 2000 IOP and TWP-ICE 2006 IOP over 10 deg. x 10 deg. area centered at ARM SGP central facility and Darwin sites. We have also worked on validation of the 3-D ice water product by CloudSat data, synergy with visible/infrared cloud ice water retrievals for better results at low ice water conditions, and created a long-term (several years) of ice water climatology in 10 x 10 deg. area of ARM SGP and TWP sites and then compared it with GCMs.

  4. Ab initio calculation of the electronic absorption spectrum of liquid water

    SciTech Connect (OSTI)

    Martiniano, Hugo F. M. C.; Galamba, Nuno; Cabral, Benedito J. Costa; Departamento de Qumica e Bioqumica, Faculdade de Cincias, Universidade de Lisboa, 1749-016 Lisboa; Instituto de Fsica da Universidade de So Paulo, CP 66318, 05314-970 So Paulo, SP

    2014-04-28

    The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the OH stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

  5. Polymer formulation for removing hydrogen and liquid water from an enclosed space

    DOE Patents [OSTI]

    Shepodd, Timothy J.

    2006-02-21

    This invention describes a solution to the particular problem of liquid water formation in hydrogen getters exposed to quantities of oxygen. Water formation is usually desired because the recombination reaction removes hydrogen without affecting gettering capacity and the oxygen removal reduces the chances for a hydrogen explosion once free oxygen is essentially removed. The present invention describes a getter incorporating a polyacrylate compound that can absorb up to 500% of its own weight in liquid water without significantly affecting its hydrogen gettering/recombination properties, but that also is insensitive to water vapor.

  6. Parametric Behaviors of CLUBB in Simulations of Low Clouds in the Community Atmosphere Model (CAM)

    SciTech Connect (OSTI)

    Guo, Zhun; Wang, Minghuai; Qian, Yun; Larson, Vincent E.; Ghan, Steven J.; Ovchinnikov, Mikhail; Bogenschutz, Peter; Gettelman, A.; Zhou, Tianjun

    2015-07-03

    In this study, we investigate the sensitivity of simulated low clouds to 14 selected tunable parameters of Cloud Layers Unified By Binormals (CLUBB), a higher order closure (HOC) scheme, and 4 parameters of the Zhang-McFarlane (ZM) deep convection scheme in the Community Atmosphere Model version 5 (CAM5). A quasi-Monte Carlo (QMC) sampling approach is adopted to effectively explore the high-dimensional parameter space and a generalized linear model is applied to study the responses of simulated cloud fields to tunable parameters. Our results show that the variance in simulated low-cloud properties (cloud fraction and liquid water path) can be explained by the selected tunable parameters in two different ways: macrophysics itself and its interaction with microphysics. First, the parameters related to dynamic and thermodynamic turbulent structure and double Gaussians closure are found to be the most influential parameters for simulating low clouds. The spatial distributions of the parameter contributions show clear cloud-regime dependence. Second, because of the coupling between cloud macrophysics and cloud microphysics, the coefficient of the dissipation term in the total water variance equation is influential. This parameter affects the variance of in-cloud cloud water, which further influences microphysical process rates, such as autoconversion, and eventually low-cloud fraction. This study improves understanding of HOC behavior associated with parameter uncertainties and provides valuable insights for the interaction of macrophysics and microphysics.

  7. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  8. Anomalous Density Properties and Ion Solvation in Liquid Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to a number of fields, ranging from biologybiochemistry to energy storage and electrochemistry. Several key properties of water, are crucial for understanding and predicting...

  9. Interactions between liquid-water and gas-diffusion layers in polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Das, Prodip K.; Santamaria, Anthony D.; Weber, Adam Z.

    2015-06-11

    Over the past few decades, a significant amount of research on polymer-electrolyte fuel cells (PEFCs) has been conducted to improve performance and durability while reducing the cost of fuel cell systems. However, the cost associated with the platinum (Pt) catalyst remains a barrier to their commercialization and PEFC durability standards have yet to be established. An effective path toward reducing PEFC cost is making the catalyst layers (CLs) thinner thus reducing expensive Pt content. The limit of thin CLs is high gas-transport resistance and the performance of these CLs is sensitive to the operating temperature due to their inherent low water uptake capacity, which results in higher sensitivity to liquid-water flooding and reduced durability. Therefore, reducing PEFC's cost by decreasing Pt content and improving PEFC's performance and durability by managing liquid-water are still challenging and open topics of research. An overlooked aspect nowadays of PEFC water management is the gas-diffusion layer (GDL). While it is known that GDL's properties can impact performance, typically it is not seen as a critical component. In this work, we present data showing the importance of GDLs in terms of water removal and management while also exploring the interactions between liquid-water and GDL surfaces. The critical interface of GDL and gas-flow-channel in the presence of liquid-water was examined through systematic studies of adhesion forces as a function of water-injection rate for various GDLs of varying thickness. GDL properties (breakthrough pressure and adhesion force) were measured experimentally under a host of test conditions. Specifically, the effects of GDL hydrophobic (PTFE) content, thickness, and water-injection rate were examined to identify trends that may be beneficial to the design of liquid-water management strategies and next-generation GDL materials for PEFCs.

  10. Interactions between liquid-water and gas-diffusion layers in polymer-electrolyte fuel cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Prodip K.; Santamaria, Anthony D.; Weber, Adam Z.

    2015-06-11

    Over the past few decades, a significant amount of research on polymer-electrolyte fuel cells (PEFCs) has been conducted to improve performance and durability while reducing the cost of fuel cell systems. However, the cost associated with the platinum (Pt) catalyst remains a barrier to their commercialization and PEFC durability standards have yet to be established. An effective path toward reducing PEFC cost is making the catalyst layers (CLs) thinner thus reducing expensive Pt content. The limit of thin CLs is high gas-transport resistance and the performance of these CLs is sensitive to the operating temperature due to their inherent lowmore » water uptake capacity, which results in higher sensitivity to liquid-water flooding and reduced durability. Therefore, reducing PEFC's cost by decreasing Pt content and improving PEFC's performance and durability by managing liquid-water are still challenging and open topics of research. An overlooked aspect nowadays of PEFC water management is the gas-diffusion layer (GDL). While it is known that GDL's properties can impact performance, typically it is not seen as a critical component. In this work, we present data showing the importance of GDLs in terms of water removal and management while also exploring the interactions between liquid-water and GDL surfaces. The critical interface of GDL and gas-flow-channel in the presence of liquid-water was examined through systematic studies of adhesion forces as a function of water-injection rate for various GDLs of varying thickness. GDL properties (breakthrough pressure and adhesion force) were measured experimentally under a host of test conditions. Specifically, the effects of GDL hydrophobic (PTFE) content, thickness, and water-injection rate were examined to identify trends that may be beneficial to the design of liquid-water management strategies and next-generation GDL materials for PEFCs.« less

  11. Sensitivity of CAM5-Simulated Arctic Clouds and Radiation to Ice Nucleation Parameterization

    SciTech Connect (OSTI)

    Xie, Shaocheng; Liu, Xiaohong; Zhao, Chuanfeng; Zhang, Yuying

    2013-08-01

    Sensitivity of Arctic clouds and radiation in the Community Atmospheric Model version 5 to the ice nucleation process is examined by testing a new physically based ice nucleation scheme that links the variation of ice nuclei (IN) number concentration to aerosol properties. The default scheme parameterizes the IN concentration simply as a function of ice supersaturation. The new scheme leads to a significant reduction in simulated IN number concentrations at all latitudes while changes in cloud amount and cloud properties are mainly seen in high latitudes and middle latitude storm tracks. In the Arctic, there is a considerable increase in mid-level clouds and a decrease in low clouds, which result from the complex interaction among the cloud macrophysics, microphysics, and the large-scale environment. The smaller IN concentrations result in an increase in liquid water path and a decrease in ice water path due to the slow-down of the Bergeron-Findeisen process in mixed-phase clouds. Overall, there is an increase in the optical depth of Arctic clouds, which leads to a stronger cloud radiative forcing (net cooling) at the top of the atmosphere. The comparison with satellite data shows that the new scheme slightly improves low cloud simulations over most of the Arctic, but produces too many mid-level clouds. Considerable improvements are seen in the simulated low clouds and their properties when compared to Arctic ground-based measurements. Issues with the observations and the model-observation comparison in the Arctic region are discussed.

  12. Cloud Properties and Radiative Heating Rates for TWP

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Comstock, Jennifer

    2013-11-07

    A cloud properties and radiative heating rates dataset is presented where cloud properties retrieved using lidar and radar observations are input into a radiative transfer model to compute radiative fluxes and heating rates at three ARM sites located in the Tropical Western Pacific (TWP) region. The cloud properties retrieval is a conditional retrieval that applies various retrieval techniques depending on the available data, that is if lidar, radar or both instruments detect cloud. This Combined Remote Sensor Retrieval Algorithm (CombRet) produces vertical profiles of liquid or ice water content (LWC or IWC), droplet effective radius (re), ice crystal generalized effective size (Dge), cloud phase, and cloud boundaries. The algorithm was compared with 3 other independent algorithms to help estimate the uncertainty in the cloud properties, fluxes, and heating rates (Comstock et al. 2013). The dataset is provided at 2 min temporal and 90 m vertical resolution. The current dataset is applied to time periods when the MMCR (Millimeter Cloud Radar) version of the ARSCL (Active Remotely-Sensed Cloud Locations) Value Added Product (VAP) is available. The MERGESONDE VAP is utilized where temperature and humidity profiles are required. Future additions to this dataset will utilize the new KAZR instrument and its associated VAPs.

  13. Drizzle formation in stratocumulus clouds: Effects of turbulent mixing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Magaritz-Ronen, L.; Pinsky, M.; Khain, A.

    2016-02-17

    The mechanism of drizzle formation in shallow stratocumulus clouds and the effect of turbulent mixing on this process are investigated. A Lagrangian–Eularian model of the cloud-topped boundary layer is used to simulate the cloud measured during flight RF07 of the DYCOMS-II field experiment. The model contains ~ 2000 air parcels that are advected in a turbulence-like velocity field. In the model all microphysical processes are described for each Lagrangian air volume, and turbulent mixing between the parcels is also taken into account. It was found that the first large drops form in air volumes that are closest to adiabatic andmore » characterized by high humidity, extended residence near cloud top, and maximum values of liquid water content, allowing the formation of drops as a result of efficient collisions. The first large drops form near cloud top and initiate drizzle formation in the cloud. Drizzle is developed only when turbulent mixing of parcels is included in the model. Without mixing, the cloud structure is extremely inhomogeneous and the few large drops that do form in the cloud evaporate during their sedimentation. Lastly, it was found that turbulent mixing can delay the process of drizzle initiation but is essential for the further development of drizzle in the cloud.« less

  14. Cloud Properties and Radiative Heating Rates for TWP

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Comstock, Jennifer

    A cloud properties and radiative heating rates dataset is presented where cloud properties retrieved using lidar and radar observations are input into a radiative transfer model to compute radiative fluxes and heating rates at three ARM sites located in the Tropical Western Pacific (TWP) region. The cloud properties retrieval is a conditional retrieval that applies various retrieval techniques depending on the available data, that is if lidar, radar or both instruments detect cloud. This Combined Remote Sensor Retrieval Algorithm (CombRet) produces vertical profiles of liquid or ice water content (LWC or IWC), droplet effective radius (re), ice crystal generalized effective size (Dge), cloud phase, and cloud boundaries. The algorithm was compared with 3 other independent algorithms to help estimate the uncertainty in the cloud properties, fluxes, and heating rates (Comstock et al. 2013). The dataset is provided at 2 min temporal and 90 m vertical resolution. The current dataset is applied to time periods when the MMCR (Millimeter Cloud Radar) version of the ARSCL (Active Remotely-Sensed Cloud Locations) Value Added Product (VAP) is available. The MERGESONDE VAP is utilized where temperature and humidity profiles are required. Future additions to this dataset will utilize the new KAZR instrument and its associated VAPs.

  15. Cloud microphysical relationships and their implication on entrainment and mixing mechanism for the stratocumulus clouds measured during the VOCALS project

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yum, Seong Soo; Wang, Jian; Liu, Yangang; Senum, Gunnar; Springston, Stephen; McGraw, Robert; Yeom, Jae Min

    2015-05-27

    Cloud microphysical data obtained from G-1 aircraft flights over the southeastern pacific during the VOCALS-Rex field campaign were analyzed for evidence of entrainment mixing of dry air from above cloud top. Mixing diagram analysis was made for the horizontal flight data recorded at 1 Hz and 40 Hz. The dominant observed feature, a positive relationship between cloud droplet mean volume (V) and liquid water content (L), suggested occurrence of homogeneous mixing. On the other hand, estimation of the relevant scale parameters (i.e., transition length scale and transition scale number) consistently indicated inhomogeneous mixing. Importantly, the flight altitudes of the measurementsmore » were significantly below cloud top. We speculate that mixing of the entrained air near the cloud top may have indeed been inhomogeneous; but due to vertical circulation mixing, the correlation between V and L became positive at the measurement altitudes in mid-level of clouds, because during their descent, cloud droplets evaporate, faster in more diluted cloud parcels, leading to a positive correlation between V and L regardless of the mixing mechanism near the cloud top.« less

  16. Cloud/Aerosol Parameterizations: Application and Improvement of General Circulation Models

    SciTech Connect (OSTI)

    Penner, Joyce

    2012-06-30

    One of the biggest uncertainties associated with climate models and climate forcing is the treatment of aerosols and their effects on clouds. The effect of aerosols on clouds can be divided into two components: The first indirect effect is the forcing associated with increases in droplet concentrations; the second indirect effect is the forcing associated with changes in liquid water path, cloud morphology, and cloud lifetime. Both are highly uncertain. This project applied a cloud-resolving model to understand the response of clouds under a variety of conditions to changes in aerosols. These responses are categorized according to the large-scale meteorological conditions that lead to the response. Meteorological conditions were sampled from various fields, which, together with a global aerosol model determination of the change in aerosols from present day to pre-industrial conditions, was used to determine a first order estimate of the response of global cloud fields to changes in aerosols. The response of the clouds in the NCAR CAM3 GCM coupled to our global aerosol model were tested by examining whether the response is similar to that of the cloud resolving model and methods for improving the representation of clouds and cloud/aerosol interactions were examined.

  17. Ab initio molecular dynamics simulation of liquid water by quantum Monte Carlo

    SciTech Connect (OSTI)

    Zen, Andrea; Luo, Ye Mazzola, Guglielmo Sorella, Sandro; Guidoni, Leonardo

    2015-04-14

    Although liquid water is ubiquitous in chemical reactions at roots of life and climate on the earth, the prediction of its properties by high-level ab initio molecular dynamics simulations still represents a formidable task for quantum chemistry. In this article, we present a room temperature simulation of liquid water based on the potential energy surface obtained by a many-body wave function through quantum Monte Carlo (QMC) methods. The simulated properties are in good agreement with recent neutron scattering and X-ray experiments, particularly concerning the position of the oxygen-oxygen peak in the radial distribution function, at variance of previous density functional theory attempts. Given the excellent performances of QMC on large scale supercomputers, this work opens new perspectives for predictive and reliable ab initio simulations of complex chemical systems.

  18. The effects of charge transfer on the properties of liquid water

    SciTech Connect (OSTI)

    Lee, Alexis J.; Rick, Steven W.

    2011-05-14

    A method for treating charge transfer interactions in classical potential models is developed and applied to water. In this method, a discrete amount of charge is transferred for each hydrogen bond formed. It is designed to be simple to implement, to be applicable to a variety of potential models, and to satisfy various physical requirements. The method does not transfer charge at large intramolecular distances, it does not result in a conductive liquid, and it can be easily parameterized to give the correct amount of charge transfer. Two charge transfer models are developed for a polarizable and a non-polarizable potential. The models reproduce many of the properties of liquid water, including the structure, the diffusion constant, and thermodynamic properties over a range of temperatures.

  19. Validation of Satellite-Derived Liquid Water Paths Using ARM SGP Microwave Radiometers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Satellite-Derived Liquid Water Paths Using ARM SGP Microwave Radiometers M. M. Khaiyer and J. Huang Analytical Services & Materials, Inc. Hampton, Virginia P. Minnis, B. Lin, and W. L. Smith, Jr. National Aeronautics and Space Administration Langley Research Center Hampton, Virginia A. Fan Science Applications International Corporation Hampton, Virginia A. Rapp Colorado State University Fort Collins, Colorado Introduction Satellites are useful for monitoring climatological parameters over

  20. Ultrafast dynamics of liquid water: Frequency fluctuations of the OH stretch and the HOH bend

    SciTech Connect (OSTI)

    Imoto, Sho; Xantheas, Sotiris S.; Saito, Shinji

    2013-07-28

    Frequency fluctuations of the OH stretch and the HOH bend in liquid water are reported from the third-order response function evaluated using the TTM3-F potential for water. The simulated two-dimensional infrared (IR) spectra of the OH stretch are similar to previously reported theoretical results. The present study suggests that the frequency fluctuation of the HOH bend is faster than that of the OH stretch. The ultrafast loss of the frequency correlation of the HOH bend is due to the strong couplings with the OH stretch as well as the intermolecular hydrogen bond bend.

  1. Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process

    SciTech Connect (OSTI)

    Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

    2011-10-16

    Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

  2. Study of Mechanisms of Aerosol Indirect Effects on Glaciated Clouds: Progress during the Project Final Technical Report

    SciTech Connect (OSTI)

    2013-10-18

    This 3-year project has studied how aerosol pollution influences glaciated clouds. The tool applied has been an 'aerosol-cloud model'. It is a type of Cloud-System Resolving Model (CSRM) modified to include 2-moment bulk microphysics and 7 aerosol species, as described by Phillips et al. (2009, 2013). The study has been done by, first, improving the model and then performing sensitivity studies with validated simulations of a couple of observed cases from ARM. These are namely the Tropical Warm Pool International Cloud Experiment (TWP-ICE) over the tropical west Pacific and the Cloud and Land Surface Interaction Campaign (CLASIC) over Oklahoma. During the project, sensitivity tests with the model showed that in continental clouds, extra liquid aerosols (soluble aerosol material) from pollution inhibited warm rain processes for precipitation production. This promoted homogeneous freezing of cloud droplets and aerosols. Mass and number concentrations of cloud-ice particles were boosted. The mean sizes of cloud-ice particles were reduced by the pollution. Hence, the lifetime of glaciated clouds, especially ice-only clouds, was augmented due to inhibition of sedimentation and ice-ice aggregation. Latent heat released from extra homogeneous freezing invigorated convective updrafts, and raised their maximum cloud-tops, when aerosol pollution was included. In the particular cases simulated in the project, the aerosol indirect effect of glaciated clouds was twice than of (warm) water clouds. This was because glaciated clouds are higher in the troposphere than water clouds and have the first interaction with incoming solar radiation. Ice-only clouds caused solar cooling by becoming more extensive as a result of aerosol pollution. This 'lifetime indirect effect' of ice-only clouds was due to higher numbers of homogeneously nucleated ice crystals causing a reduction in their mean size, slowing the ice-crystal process of snow production and slowing sedimentation. In addition to the known indirect effects (glaciation, riming and thermodynamic), new indirect effects were discovered and quantified due to responses of sedimentation, aggregation and coalescence in glaciated clouds to changing aerosol conditions. In summary, the change in horizontal extent of the glaciated clouds ('lifetime indirect effects'), especially of ice-only clouds, was seen to be of higher importance in regulating aerosol indirect effects than changes in cloud properties ('cloud albedo indirect effects').

  3. Aerosol Impacts on California Winter Clouds and Precipitation during CalWater 2011: Local Pollution versus Long-Range Transported Dust

    SciTech Connect (OSTI)

    Fan, Jiwen; Leung, Lai-Yung R.; DeMott, Paul J.; Comstock, Jennifer M.; Singh, Balwinder; Rosenfeld, Daniel; Tomlinson, Jason M.; White, Allen B.; Prather, Kimberly; Minnis, Patrick; Ayers, J. K.; Min, Qilong

    2014-01-03

    Mineral dust aerosols often observed over California in winter and spring, associated with long-range transport from Asia and Sahara, have been linked to enhanced precipitation based on observations. Local anthropogenic pollution, on the other hand, was shown in previous observational and modeling studies to reduce precipitation. Here we incorporate recent developments in ice nucleation parameterizations to link aerosols with ice crystal formation in a spectral-bin cloud microphysical model coupled with the Weather Research and Forecasting (WRF) model, to examine the relative and combined impacts of dust and local pollution particles on cloud properties and precipitation type and intensity. Simulations are carried out for two cloud cases with contrasting meteorology and cloud dynamics that occurred on February 16 (FEB16) and March 02 (MAR02) from the CalWater 2011 field campaign. In both cases, observations show the presence of dust and biological particles in a relative pristine environment. The simulated cloud microphysical properties and precipitation show reasonable agreement with aircraft and surface measurements. Model sensitivity experiments indicate that in the pristine environment, the dust and biological aerosol layers increase the accumulated precipitation by 10-20% from the Central Valley to the Sierra Nevada Mountains for both FEB16 and MAR02 due to a ~40% increase in snow formation, validating the observational hypothesis. Model results show that local pollution increases precipitation over the windward slope of the mountains by few percent due to increased snow formation when dust is present but reduces precipitation by 5-8% if dust is removed on FEB16. The effects of local pollution on cloud microphysics and precipitation strongly depend on meteorology including the strength of the Sierra Barrier Jet, and cloud dynamics. This study further underscores the importance of the interactions between local pollution, dust, and environmental conditions for assessing aerosol effects on cold season precipitation in California.

  4. Method and apparatus for electrokinetic co-generation of hydrogen and electric power from liquid water microjets

    DOE Patents [OSTI]

    Saykally, Richard J; Duffin, Andrew M; Wilson, Kevin R; Rude, Bruce S

    2013-02-12

    A method and apparatus for producing both a gas and electrical power from a flowing liquid, the method comprising: a) providing a source liquid containing ions that when neutralized form a gas; b) providing a velocity to the source liquid relative to a solid material to form a charged liquid microjet, which subsequently breaks up into a droplet spay, the solid material forming a liquid-solid interface; and c) supplying electrons to the charged liquid by contacting a spray stream of the charged liquid with an electron source. In one embodiment, where the liquid is water, hydrogen gas is formed and a streaming current is generated. The apparatus comprises a source of pressurized liquid, a microjet nozzle, a conduit for delivering said liquid to said microjet nozzle, and a conductive metal target sufficiently spaced from said nozzle such that the jet stream produced by said microjet is discontinuous at said target. In one arrangement, with the metal nozzle and target electrically connected to ground, both hydrogen gas and a streaming current are generated at the target as it is impinged by the streaming, liquid spray microjet.

  5. Molecular origin of the difference in the HOH bend of the IR spectra between liquid water and ice

    SciTech Connect (OSTI)

    Imoto, Sho; Xantheas, Sotiris S.; Saito, Shinji

    2013-02-07

    The intensity of the HOH bend in the IR spectrum of ice is significantly smaller than the corresponding one in liquid water. This difference in the IR intensities of the HOH bend in the two systems is investigated using MD simulations with the flexible, polarizable, ab-initio based TTM3-F model for water, a potential that correctly reproduces the experimentally observed increase of the HOH bend in liquid water and ice from the water monomer value. We have identified two factors that are responsible for the difference in the intensity of the HOH bend in liquid water and ice: (i) the decrease of the intensity of the HOH bend in ice caused by the strong anti-correlation between the permanent dipole moment of a molecule and the induced dipole moment of a neighboring hydrogen bond acceptor molecule and (ii) the weakening of this anti-correlation by the disordered hydrogen bond network in liquid water. The presence of the anti-correlation in ice is further confirmed by ab initio electronic structure calculations of water pentamer clusters extracted from the trajectories of the MD simulations for ice and liquid water.

  6. Advantages of liquid fluoride thorium reactor in comparison with light water reactor

    SciTech Connect (OSTI)

    Bahri, Che Nor Aniza Che Zainul Majid, Amran Ab.; Al-Areqi, Wadeeah M.

    2015-04-29

    Liquid Fluoride Thorium Reactor (LFTR) is an innovative design for the thermal breeder reactor that has important potential benefits over the traditional reactor design. LFTR is fluoride based liquid fuel, that use the thorium dissolved in salt mixture of lithium fluoride and beryllium fluoride. Therefore, LFTR technology is fundamentally different from the solid fuel technology currently in use. Although the traditional nuclear reactor technology has been proven, it has perceptual problems with safety and nuclear waste products. The aim of this paper is to discuss the potential advantages of LFTR in three aspects such as safety, fuel efficiency and nuclear waste as an alternative energy generator in the future. Comparisons between LFTR and Light Water Reactor (LWR), on general principles of fuel cycle, resource availability, radiotoxicity and nuclear weapon proliferation shall be elaborated.

  7. Aircraft-measured indirect cloud effects from biomass burning smoke in the Arctic and subarctic

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zamora, L. M.; Kahn, R. A.; Cubison, M. J.; Diskin, G. S.; Jimenez, J. L.; Kondo, Y.; McFarquhar, G. M.; Nenes, A.; Thornhill, K. L.; Wisthaler, A.; et al

    2016-01-21

    The incidence of wildfires in the Arctic and subarctic is increasing; in boreal North America, for example, the burned area is expected to increase by 200–300% over the next 50–100 years, which previous studies suggest could have a large effect on cloud microphysics, lifetime, albedo, and precipitation. However, the interactions between smoke particles and clouds remain poorly quantified due to confounding meteorological influences and remote sensing limitations. Here, we use data from several aircraft campaigns in the Arctic and subarctic to explore cloud microphysics in liquid-phase clouds influenced by biomass burning. Median cloud droplet radii in smoky clouds were ~40–60% smallermore » than in background clouds. Based on the relationship between cloud droplet number (Nliq) and various biomass burning tracers (BBt) across the multi-campaign data set, we calculated the magnitude of subarctic and Arctic smoke aerosol–cloud interactions (ACIs, where ACI = (1/3) × dln(Nliq)/dln(BBt)) to be ~0.16 out of a maximum possible value of 0.33 that would be obtained if all aerosols were to nucleate cloud droplets. Interestingly, in a separate subarctic case study with low liquid water content (~0.02gm–3) and very high aerosol concentrations (2000–3000 cm–3) in the most polluted clouds, the estimated ACI value was only 0.05. In this case, competition for water vapor by the high concentration of cloud condensation nuclei (CCN) strongly limited the formation of droplets and reduced the cloud albedo effect, which highlights the importance of cloud feedbacks across scales. Using our calculated ACI values, we estimate that the smoke-driven cloud albedo effect may decrease local summertime short-wave radiative flux by between 2 and 4 Wm–2 or more under some low and homogeneous cloud cover conditions in the subarctic, although the changes should be smaller in high surface albedo regions of the Arctic. Furthermore, we lastly explore evidence suggesting that numerous northern-latitude background Aitken particles can interact with combustion particles, perhaps impacting their properties as cloud condensation and ice nuclei.« less

  8. Efficacy of Aerosol-Cloud Interactions Under Varying Meteorological Conditions: Southern Great Plains Vs. Pt. Reyes

    SciTech Connect (OSTI)

    Dunn, M.; Schwartz, S.; Kim, B.-G.; Miller, M.; Liu, Y.; Min, Q.

    2008-03-10

    Several studies have demonstrated that cloud dynamical processes such as entrainment mixing may be the primary modulator of cloud optical properties in certain situations. For example, entrainment of dry air alters the cloud drop size distribution by enhancing drop evaporation. However, the effect of entrainment mixing and other forms or turbulence is still quite uncertain. Although these factors and aerosol-cloud interactions should be considered together when evaluating the efficacy of aerosol indirect effects, the underlying mechanisms appear to be dependent upon each other. In addition, accounting for them is impossible with the current understanding of aerosol indirect effect. Therefore, careful objective screening and analysis of observations are needed to determine the extent to which mixing related properties affect cloud optical properties, apart from the aerosol first indirect effect. This study addresses the role of aerosol-cloud interactions in the context of varying meteorological conditions based on ARM data obtained at the Southern Great Plains (SGP) site in Oklahoma and at Pt. Reyes, California. Previous analyses of the continental stratiform clouds at the SGP site have shown that the thicker clouds of high liquid water path (LWP) tend to contain sub adiabatic LWPs. These sub adiabatic LWPs, which result from active mixing processes, correspond to a lower susceptibility of the clouds to aerosol-cloud interactions, and, hence, to reduced aerosol indirect effects. In contrast, the consistently steady and thin maritime stratus clouds observed at Pt. Reyes are much closer to adiabatic. These clouds provide an excellent benchmark for the study of the aerosol influence on modified marine clouds relative to continental clouds, since they form in a much more homogeneous meteorological environment than those at the continental site.

  9. A comparison of cloud properties at a coastal and inland site at the North

    Office of Scientific and Technical Information (OSTI)

    Slope of Alaska (Journal Article) | DOE PAGES A comparison of cloud properties at a coastal and inland site at the North Slope of Alaska « Prev Next » Title: A comparison of cloud properties at a coastal and inland site at the North Slope of Alaska In this study, we have examined differences in cloud liquid water paths (LWPs) at a coastal (Barrow) and an inland (Atqasuk) location on the North Slope of Alaska using microwave radiometer (MWR) data collected by the U.S. Department of Energy's

  10. Fine-scale Horizontal Structure of Arctic Mixed-Phase Clouds.

    SciTech Connect (OSTI)

    Rambukkange,M.; Verlinde, J.; Elorante, E.; Luke, E.; Kollias, P.; Shupe, M.

    2006-07-10

    Recent in situ observations in stratiform clouds suggest that mixed phase regimes, here defined as limited cloud volumes containing both liquid and solid water, are constrained to narrow layers (order 100 m) separating all-liquid and fully glaciated volumes (Hallett and Viddaurre, 2005). The Department of Energy Atmospheric Radiation Measurement Program's (DOE-ARM, Ackerman and Stokes, 2003) North Slope of Alaska (NSA) ARM Climate Research Facility (ACRF) recently started collecting routine measurement of radar Doppler velocity power spectra from the Millimeter Cloud Radar (MMCR). Shupe et al. (2004) showed that Doppler spectra has potential to separate the contributions to the total reflectivity of the liquid and solid water in the radar volume, and thus to investigate further Hallett and Viddaurre's findings. The Mixed-Phase Arctic Cloud Experiment (MPACE) was conducted along the NSA to investigate the properties of Arctic mixed phase clouds (Verlinde et al., 2006). We present surface based remote sensing data from MPACE to discuss the fine-scale structure of the mixed-phase clouds observed during this experiment.

  11. Cloud Optical Properties from the Multifilter Shadowband Radiometer (MFRSRCLDOD): An ARM Value-Added Product

    SciTech Connect (OSTI)

    Turner, DD; McFarlane, SA; Riihimaki, L; Shi, Y; Lo, C; Min, Q

    2014-02-01

    The microphysical properties of clouds play an important role in studies of global climate change. Observations from satellites and surface-based systems have been used to infer cloud optical depth and effective radius. Min and Harrison (1996) developed an inversion method to infer the optical depth of liquid water clouds from narrow band spectral Multifilter Rotating Shadowband Radiometer (MFRSR) measurements (Harrison et al. 1994). Their retrieval also uses the total liquid water path (LWP) measured by a microwave radiometer (MWR) to obtain the effective radius of the warm cloud droplets. Their results were compared with Geostationary Operational Environmental Satellite (GOES) retrieved values at the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site (Min and Harrison 1996). Min et al. (2003) also validated the retrieved cloud optical properties against in situ observations, showing that the retrieved cloud effective radius agreed well with the in situ forward scattering spectrometer probe observations. The retrieved cloud optical properties from Min et al. (2003) were used also as inputs to an atmospheric shortwave model, and the computed fluxes were compared with surface pyranometer observations.

  12. Wind speed response of marine non-precipitating stratocumulus clouds over a diurnal cycle in cloud-system resolving simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kazil, J.; Feingold, G.; Yamaguchi, T.

    2015-10-21

    Observed and projected trends in large scale wind speed over the oceans prompt the question: how might marine stratocumulus clouds and their radiative properties respond to future changes in large scale wind speed? Wind speed drives the surface fluxes of sensible heat, moisture, and momentum, and thereby acts on cloud liquid water path (LWP) and cloud radiative properties. We present an investigation of the dynamical response of non-precipitating, overcast marine stratocumulus clouds to different wind speeds, all else equal. In cloud-system resolving simulations, we find that higher wind speed leads to faster boundary layer growth and stronger entrainment. The dynamicalmoredriver is enhanced buoyant production of turbulence kinetic energy (TKE) from latent heat release in cloud updrafts. LWP is enhanced during the night and in the morning at higher wind speed, and more strongly suppressed later in the day. Wind speed hence accentuates the diurnal LWP cycle by expanding the morning afternoon contrast. The higher LWP at higher wind speed does not, however, enhance cloud top cooling because in clouds with LWP ⪆ 50 g m?2, long wave emissions are very insensitive to LWP. This leads to the more general conclusion that in sufficiently thick stratocumulus clouds, additional boundary layer growth and entrainment due to a boundary layer moistening arises by stronger production of TKE from latent heat release in cloud updrafts, rather than from enhanced longwave cooling. We find furthermore that large scale wind modulates boundary layer decoupling. At nighttime and at low wind speed during daytime, it enhances decoupling in part by faster boundary layer growth and stronger entrainment, and in part because circulation driven by shear from large scale wind in the sub-cloud layer hinders vertical moisture transport between the surface and cloud base. With increasing wind speed, however, in decoupled daytime conditions, shear-driven circulation due to large scale wind takes over from buoyancy-driven circulation in transporting moisture from the surface to cloud base, and thereby reduces decoupling and helps maintain LWP. The cloud radiative effect (CRE) responds to changes in LWP and cloud fraction, and higher wind speed translates to a stronger diurnally averaged CRE. However, the sensitivity of the diurnally averaged CRE to wind speed decreases with increasing wind speed.less

  13. A cobalt(II) bis(salicylate)-based ionic liquid that shows thermoresponsive and selective water coordination

    SciTech Connect (OSTI)

    Kohno, Y; Cowan, MG; Masuda, M; Bhowmick, I; Shores, MP; Gin, DL; Noble, RD

    2014-01-01

    A metal-containing ionic liquid (MCIL) has been prepared in which the [CoII(salicylate)(2)](2-) anion is able to selectively coordinate two water molecules with a visible colour change, even in the presence of alcohols. Upon moderate heating or placement in vacuo, the hydrated MCIL undergoes reversible thermochromism by releasing the bound water molecules.

  14. Tropical Cloud Properties and Radiative Heating Profiles (Dataset...

    Office of Scientific and Technical Information (OSTI)

    Tropical Cloud Properties and Radiative Heating Profiles Title: Tropical Cloud Properties ... in that it uses the microwave radiometer to scale the radiosonde column water vapor. ...

  15. Humidity trends imply increased sensitivity to clouds in a warming...

    Office of Scientific and Technical Information (OSTI)

    is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. ...

  16. The influence of mixed and phase clouds on surface shortwave irradiance during the Arctic spring

    SciTech Connect (OSTI)

    Lubin D.; Vogelmann A.

    2011-10-13

    The influence of mixed-phase stratiform clouds on the surface shortwave irradiance is examined using unique spectral shortwave irradiance measurements made during the Indirect and Semi-Direct Aerosol Campaign (ISDAC), supported by the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program. An Analytical Spectral Devices (ASD, Inc.) spectroradiometer measured downwelling spectral irradiance from 350 to 2200 nm in one-minute averages throughout April-May 2008 from the ARM Climate Research Facility's North Slope of Alaska (NSA) site at Barrow. This study examines spectral irradiance measurements made under single-layer, overcast cloud decks having geometric thickness < 3000 m. Cloud optical depth is retrieved from irradiance in the interval 1022-1033 nm. The contrasting surface radiative influences of mixed-phase clouds and liquid-water clouds are discerned using irradiances in the 1.6-{micro}m window. Compared with liquid-water clouds, mixed-phase clouds during the Arctic spring cause a greater reduction of shortwave irradiance at the surface. At fixed conservative-scattering optical depth (constant optical depth for wavelengths {lambda} < 1100 nm), the presence of ice water in cloud reduces the near-IR surface irradiance by an additional several watts-per-meter-squared. This additional reduction, or supplemental ice absorption, is typically {approx}5 W m{sup -2} near solar noon over Barrow, and decreases with increasing solar zenith angle. However, for some cloud decks this additional absorption can be as large as 8-10 W m{sup -2}.

  17. Cirrus clouds in a global climate model with a statistical cirrus cloud scheme

    SciTech Connect (OSTI)

    Wang, Minghuai; Penner, Joyce E.

    2010-06-21

    A statistical cirrus cloud scheme that accounts for mesoscale temperature perturbations is implemented in a coupled aerosol and atmospheric circulation model to better represent both subgrid-scale supersaturation and cloud formation. This new scheme treats the effects of aerosol on cloud formation and ice freezing in an improved manner, and both homogeneous freezing and heterogeneous freezing are included. The scheme is able to better simulate the observed probability distribution of relative humidity compared to the scheme that was implemented in an older version of the model. Heterogeneous ice nuclei (IN) are shown to decrease the frequency of occurrence of supersaturation, and improve the comparison with observations at 192 hPa. Homogeneous freezing alone can not reproduce observed ice crystal number concentrations at low temperatures (<205 K), but the addition of heterogeneous IN improves the comparison somewhat. Increases in heterogeneous IN affect both high level cirrus clouds and low level liquid clouds. Increases in cirrus clouds lead to a more cloudy and moist lower troposphere with less precipitation, effects which we associate with the decreased convective activity. The change in the net cloud forcing is not very sensitive to the change in ice crystal concentrations, but the change in the net radiative flux at the top of the atmosphere is still large because of changes in water vapor. Changes in the magnitude of the assumed mesoscale temperature perturbations by 25% alter the ice crystal number concentrations and the net radiative fluxes by an amount that is comparable to that from a factor of 10 change in the heterogeneous IN number concentrations. Further improvements on the representation of mesoscale temperature perturbations, heterogeneous IN and the competition between homogeneous freezing and heterogeneous freezing are needed.

  18. Method of extracting iodine from liquid mixtures of iodine, water and hydrogen iodide

    DOE Patents [OSTI]

    Mysels, Karol J.

    1979-01-01

    The components of a liquid mixture consisting essentially of HI, water and at least about 50 w/o iodine are separated in a countercurrent extraction zone by treating with phosphoric acid containing at least about 90 w/o H.sub.3 PO.sub.4. The bottom stream from the extraction zone is substantially completely molten iodine, and the overhead stream contains water, HI, H.sub.3 PO.sub.4 and a small fraction of the amount of original iodine. When the water and HI are present in near-azeotropic proportions, there is particular advantage in feeding the overhead stream to an extractive distillation zone wherein it is treated with additional concentrated phosphoric acid to create an anhydrous HI vapor stream and bottoms which contain at least about 85 w/o H.sub.3 PO.sub.4. Concentration of these bottoms provides phosphoric acid infeed for both the countercurrent extraction zone and for the extractive distillation zone.

  19. Dynamics of soft Nanomaterials captured by transmission electron microscopy in liquid water

    SciTech Connect (OSTI)

    Proetto, Maria T.; Rush, Anthony M.; Chien, Miao-Ping; Abellan Baeza, Patricia; Patterson, Joseph P.; Thompson, Matthew P.; Olson, Norman H.; Moore, Curtis E.; Rheingold, Arnold L.; Andolina, Christopher; Millstone, Jill; Howell, Stephen B.; Browning, Nigel D.; Evans, James E.; Gianneschi, Nathan C.

    2014-01-14

    In this paper we present in situ transmission electron microscopy (TEM) of soft, synthetic nanoparticles with a comparative analysis using conventional TEM methods. This comparison is made with the simple aim of describing what is an unprecedented example of in situ imaging by TEM. However, we contend the technique will quickly become essential in the characterization of analogous systems, especially where dynamics are of interest in the solvated state. In this case, particles were studied which were obtained from the direct polymerization of an oxaliplatin analog, designed for an ongoing program in novel chemotherapeutic delivery systems. The resulting nanoparticles provided sufficient contrast for facile imaging in situ, and point toward key design parameters that enable this new characterization approach for organic nanomaterials. We describe the preparation of the synthetic micellar nanoparticles to- gether with their characterization in liquid water.

  20. Influence of Arctic cloud thermodynamic phase on surface shortwave flux

    SciTech Connect (OSTI)

    Lubin, D.; Vogelmann, A.

    2010-03-15

    As part of the Indirect and Semi-Direct Aerosol Campaign (ISDAC) an Analytical Spectral Devices (ASD, Inc.) spectroradiometer was deployed at the Barrow NSA site during April and May of 2008, and in April-October of 2009. This instrument recorded one-minute averages of surface downwelling spectral flux in the wavelength interval 350-2200 nm, thus sampling the two major near infrared windows (1.6 and 2.2 microns) in which the flux is influenced by cloud microphysical properties including thermodynamic phase and effective particle size. Aircraft in situ measurements of cloud properties show mostly mixed-phase clouds over Barrow during the campaign, but with wide variability in relative liquid versus ice water content. At fixed total optical depth, this variability in phase composition can yield of order 5-10 Watts per square meter in surface flux variability, with greater cloud attenuation of the surface flux usually occurring under higher ice water content. Thus our data show that changes in cloud phase properties, even within the 'mixed-phase' category, can affect the surface energy balance at the same order of magnitude as greenhouse gas increases. Analysis of this spectral radiometric data provides suggestions for testing new mixed-phase parameterizations in climate models.

  1. Charge transfer effects of ions at the liquid water/vapor interface

    SciTech Connect (OSTI)

    Soniat, Marielle; Rick, Steven W.

    2014-05-14

    Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 away from the surface.

  2. ARM - Measurement - Cloud size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    measurements as cloud thickness, cloud area, and cloud aspect ratio. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  3. Cloud Properties Working Group Low Clouds Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Properties Working Group Low Clouds Update Low Clouds Update Jennifer Comstock Jennifer Comstock Dave Turner Dave Turner Andy Andy Vogelmann Vogelmann Instruments Instruments ...

  4. Precipitating clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    processes, especially related ice. * Very large differences between observed IN number concentration and ice concentration in a given clouds. * Many ice nucleation modes are...

  5. Scale dependence of entrainment-mixing mechanisms in cumulus clouds

    SciTech Connect (OSTI)

    Lu, Chunsong; Liu, Yangang; Niu, Shengjie; Endo, Satoshi

    2014-12-17

    This work empirically examines the dependence of entrainment-mixing mechanisms on the averaging scale in cumulus clouds using in situ aircraft observations during the Routine Atmospheric Radiation Measurement Aerial Facility Clouds with Low Optical Water Depths Optical Radiative Observations (RACORO) field campaign. A new measure of homogeneous mixing degree is defined that can encompass all types of mixing mechanisms. Analysis of the dependence of the homogenous mixing degree on the averaging scale shows that, on average, the homogenous mixing degree decreases with increasing averaging scales, suggesting that apparent mixing mechanisms gradually approach from homogeneous mixing to extreme inhomogeneous mixing with increasing scales. The scale dependence can be well quantified by an exponential function, providing first attempt at developing a scale-dependent parameterization for the entrainment-mixing mechanism. The influences of three factors on the scale dependence are further examined: droplet-free filament properties (size and fraction), microphysical properties (mean volume radius and liquid water content of cloud droplet size distributions adjacent to droplet-free filaments), and relative humidity of entrained dry air. It is found that the decreasing rate of homogeneous mixing degree with increasing averaging scales becomes larger with larger droplet-free filament size and fraction, larger mean volume radius and liquid water content, or higher relative humidity. The results underscore the necessity and possibility of considering averaging scale in representation of entrainment-mixing processes in atmospheric models.

  6. Scale dependence of entrainment-mixing mechanisms in cumulus clouds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Chunsong; Liu, Yangang; Niu, Shengjie; Endo, Satoshi

    2014-12-17

    This work empirically examines the dependence of entrainment-mixing mechanisms on the averaging scale in cumulus clouds using in situ aircraft observations during the Routine Atmospheric Radiation Measurement Aerial Facility Clouds with Low Optical Water Depths Optical Radiative Observations (RACORO) field campaign. A new measure of homogeneous mixing degree is defined that can encompass all types of mixing mechanisms. Analysis of the dependence of the homogenous mixing degree on the averaging scale shows that, on average, the homogenous mixing degree decreases with increasing averaging scales, suggesting that apparent mixing mechanisms gradually approach from homogeneous mixing to extreme inhomogeneous mixing with increasingmore » scales. The scale dependence can be well quantified by an exponential function, providing first attempt at developing a scale-dependent parameterization for the entrainment-mixing mechanism. The influences of three factors on the scale dependence are further examined: droplet-free filament properties (size and fraction), microphysical properties (mean volume radius and liquid water content of cloud droplet size distributions adjacent to droplet-free filaments), and relative humidity of entrained dry air. It is found that the decreasing rate of homogeneous mixing degree with increasing averaging scales becomes larger with larger droplet-free filament size and fraction, larger mean volume radius and liquid water content, or higher relative humidity. The results underscore the necessity and possibility of considering averaging scale in representation of entrainment-mixing processes in atmospheric models.« less

  7. Coupling Between Oceanic Upwelling and Cloud-aerosol Properties at the AMF Point Reyes Site

    SciTech Connect (OSTI)

    Dunn, M.; Jensen, M.; Miller, M.; Kollias, P.; Bartholomew, M. J.; Turner, D.; Andrews, E.; Jefferson, A.; Daum, P.

    2008-03-10

    Cloud microphysical properties measured at the ARM Mobile Facility site located on the northern coast of California near Point Reyes, during the 2005 Marine Stratus Radiation, Aerosol and Drizzle experiment, were analyzed to determine their relationship to the coastal sea surface temperature (SST) which was characterized using measurements acquired from a National Oceanic and Atmospheric Administration offshore buoy. An increase in SST resulting from a relaxation of upwelling, occurring in the eastern Pacific Ocean off the coast of California in summer is observed to strongly correlate with nearby ground measured cloud microphysical properties and cloud condensation nuclei (CCN) concentrations. Correlations between these atmospheric and oceanic features provide insight into the interplay between the ocean and cloud radiative properties. We present evidence of this robust correlation and examine the factors controlling these features. The marine boundary layer is in direct contact with the sea surface and is strongly influenced by SST. Moisture and vertical motion are crucial ingredients for cloud development and so we examine the role of SST in providing these key components to the atmosphere. Although upwelling of cold subsurface waters is conventionally thought to increase aerosols in the region, thus increasing clouds, here we observed a relaxation of upwelling associated with changes in the structure of marine stratus clouds. As upwelling relaxes, the SST get warmer, thick clouds with high liquid water paths are observed and persist for a few days. This cycle is repeated throughout the summer upwelling season. A concomitant cyclic increase and decrease of CCN concentration is also observed. Forcing mechanisms and large-scale atmospheric features are discussed. Marine stratocumulus clouds are a critical component of the earth's radiation budget and this site provides an excellent opportunity to study the influence of SST on these clouds.

  8. The melting temperature of liquid water with the effective fragment potential

    SciTech Connect (OSTI)

    Brorsen, Kurt R.; Willow, Soohaeng Y.; Xantheas, Sotiris S.; Gordon, Mark S.

    2015-09-17

    Direct simulation of the solid-liquid water interface with the effective fragment potential (EFP) via the constant enthalpy and pressure (NPH) ensemble was used to estimate the melting temperature (Tm) of ice-Ih. Initial configurations and velocities, taken from equilibrated constant pressure and temperature (NPT) simulations at T = 300 K, 350 K and 400 K, respectively, yielded corresponding Tm values of 37816 K, 38214 K and 38415 K. These estimates are consistently higher than experiment, albeit to the same degree with previously reported estimates using density functional theory (DFT)-based Born-Oppenheimer simulations with the Becke-Lee-Yang-Parr functional plus dispersion corrections (BLYP-D). KRB was supported by a Computational Science Graduate Fellowship from the Department of Energy. MSG was supported by a U.S. National Science Foundation Software Infrastructure (SI2) grant (ACI 1047772). SSX acknowledges support from the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

  9. RACORO continental boundary layer cloud investigations. 2. Large-eddy simulations of cumulus clouds and evaluation with in-situ and ground-based observations

    SciTech Connect (OSTI)

    Endo, Satoshi; Fridlind, Ann M.; Lin, Wuyin; Vogelmann, Andrew M.; Toto, Tami; Ackerman, Andrew S.; McFarquhar, Greg M.; Jackson, Robert C.; Jonsson, Haflidi H.; Liu, Yangang

    2015-06-19

    A 60-hour case study of continental boundary layer cumulus clouds is examined using two large-eddy simulation (LES) models. The case is based on observations obtained during the RACORO Campaign (Routine Atmospheric Radiation Measurement [ARM] Aerial Facility [AAF] Clouds with Low Optical Water Depths [CLOWD] Optical Radiative Observations) at the ARM Climate Research Facility's Southern Great Plains site. The LES models are driven by continuous large-scale and surface forcings, and are constrained by multi-modal and temporally varying aerosol number size distribution profiles derived from aircraft observations. We compare simulated cloud macrophysical and microphysical properties with ground-based remote sensing and aircraft observations. The LES simulations capture the observed transitions of the evolving cumulus-topped boundary layers during the three daytime periods, and generally reproduce variations of droplet number concentration with liquid water content (LWC), corresponding to the gradient between the cloud centers and cloud edges at given heights. The observed LWC values fall within the range of simulated values; the observed droplet number concentrations are commonly higher than simulated, but differences remain on par with potential estimation errors in the aircraft measurements. Sensitivity studies examine the influences of bin microphysics versus bulk microphysics, aerosol advection, supersaturation treatment, and aerosol hygroscopicity. Simulated macrophysical cloud properties are found to be insensitive in this non-precipitating case, but microphysical properties are especially sensitive to bulk microphysics supersaturation treatment and aerosol hygroscopicity.

  10. RACORO continental boundary layer cloud investigations. 2. Large-eddy simulations of cumulus clouds and evaluation with in-situ and ground-based observations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Endo, Satoshi; Fridlind, Ann M.; Lin, Wuyin; Vogelmann, Andrew M.; Toto, Tami; Ackerman, Andrew S.; McFarquhar, Greg M.; Jackson, Robert C.; Jonsson, Haflidi H.; Liu, Yangang

    2015-06-19

    A 60-hour case study of continental boundary layer cumulus clouds is examined using two large-eddy simulation (LES) models. The case is based on observations obtained during the RACORO Campaign (Routine Atmospheric Radiation Measurement [ARM] Aerial Facility [AAF] Clouds with Low Optical Water Depths [CLOWD] Optical Radiative Observations) at the ARM Climate Research Facility's Southern Great Plains site. The LES models are driven by continuous large-scale and surface forcings, and are constrained by multi-modal and temporally varying aerosol number size distribution profiles derived from aircraft observations. We compare simulated cloud macrophysical and microphysical properties with ground-based remote sensing and aircraft observations.more » The LES simulations capture the observed transitions of the evolving cumulus-topped boundary layers during the three daytime periods, and generally reproduce variations of droplet number concentration with liquid water content (LWC), corresponding to the gradient between the cloud centers and cloud edges at given heights. The observed LWC values fall within the range of simulated values; the observed droplet number concentrations are commonly higher than simulated, but differences remain on par with potential estimation errors in the aircraft measurements. Sensitivity studies examine the influences of bin microphysics versus bulk microphysics, aerosol advection, supersaturation treatment, and aerosol hygroscopicity. Simulated macrophysical cloud properties are found to be insensitive in this non-precipitating case, but microphysical properties are especially sensitive to bulk microphysics supersaturation treatment and aerosol hygroscopicity.« less

  11. Effects of Ocean Ecosystem on Marine Aerosol-Cloud Interaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meskhidze, Nicholas; Nenes, Athanasios

    2010-01-01

    Using smore » atellite data for the surface ocean, aerosol optical depth (AOD), and cloud microphysical parameters, we show that statistically significant positive correlations exist between ocean ecosystem productivity, the abundance of submicron aerosols, and cloud microphysical properties over different parts of the remote oceans. The correlation coefficient for remotely sensed surface chlorophyll a concentration ([Chl- a ]) and liquid cloud effective radii over productive areas of the oceans varies between − 0.2 and − 0.6 . Special attention is given to identifying (and addressing) problems from correlation analysis used in the previous studies that can lead to erroneous conclusions. A new approach (using the difference between retrieved AOD and predicted sea salt aerosol optical depth, AOD diff ) is developed to explore causal links between ocean physical and biological systems and the abundance of cloud condensation nuclei (CCN) in the remote marine atmosphere. We have found that over multiple time periods, 550 nm AOD diff (sensitive to accumulation mode aerosol, which is the prime contributor to CCN) correlates well with [Chl- a ] over the productive waters of the Southern Ocean. Since [Chl- a ] can be used as a proxy of ocean biological productivity, our analysis demonstrates the role of ocean ecology in contributing CCN, thus shaping the microphysical properties of low-level marine clouds.« less

  12. Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  13. Radiative Effects of Cloud Inhomogeneity and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiative Effects of Cloud Inhomogeneity and Geometric Association Over the Tropical Western Pacific Warm Pool X. Wu National Center for Atmospheric Research (a) Boulder, Colorado X. -Z. Liang Illinois State Water Survey Champaign, Illinois Introduction The representation of cloud systems and cloud-radiation interaction is considered to be one of major uncertainties in general circulation models (GCMs). This arises because (1) complete observations of cloud systems are impossible and available

  14. Distribution of radionuclides and water in Bandelier Tuff beneath a former Los Alamos liquid waste disposal site after 33 years

    SciTech Connect (OSTI)

    Nyhan, J.W.; Drennon, B.J.; Abeele, W.V.; Trujillo, G.; Herrera, W.J.; Wheeler, M.L.; Booth, J.W.; Purtymun, W.D.

    1984-07-01

    The distribution of radionuclides and water in Bandelier Tuff beneath a former liquid waste disposal site at Los Alamos was investigated. The waste use history of the site was described, as well as several pertinent laboratory and field studies of water and radionuclide migration in Bandelier Tuff. The distribution of plutonium, /sup 241/Am, and water was determined in a set of about 800 tuff samples collected to sampling depths of 30 m beneath two absorption beds. These data were then related to site geohydrologic data. Water and radionuclide concentrations found after 33 years were compared with the results of similar studies previously performed at this site, and the implications of these comparisons are discussed relative to nuclear waste management. 19 references, 6 figures, 4 tables.

  15. Model analysis of the anthropogenic aerosol effect on clouds over East Asia

    SciTech Connect (OSTI)

    Gao, Yi; Zhang, Meigen; Liu, Xiaohong; Zhao, Chun

    2012-01-16

    A coupled meteorology and aerosol/chemistry model WRF-Chem (Weather Research and Forecast model coupled with Chemistry) was used to conduct a pair of simulations with present-day (PD) and preindustrial (PI) emissions over East Asia to examine the aerosol indirect effect on clouds. As a result of an increase in aerosols in January, the cloud droplet number increased by 650 cm{sup -3} over the ocean and East China, 400 cm{sup -3} over Central and Southwest China, and less than 200 cm{sup -3} over North China. The cloud liquid water path (LWP) increased by 40-60 g m{sup -2} over the ocean and Southeast China and 30 g m{sup -2} over Central China; the LWP increased less than 5 g m{sup -2} or decreased by 5 g m{sup -2} over North China. The effective radius (Re) decreased by more than 4 {mu}m over Southwest, Central, and Southeast China and 2 {mu}m over North China. In July, variations in cloud properties were more uniform; the cloud droplet number increased by approximately 250-400 cm{sup -3}, the LWP increased by approximately 30-50 g m{sup -2}, and Re decreased by approximately 3 {mu}m over most regions of China. In response to cloud property changes from PI to PD, shortwave (SW) cloud radiative forcing strengthened by 30 W m{sup -2} over the ocean and 10 W m{sup -2} over Southeast China, and it weakened slightly by approximately 2-10 W m{sup -2} over Central and Southwest China in January. In July, SW cloud radiative forcing strengthened by 15 W m{sup -2} over Southeast and North China and weakened by 10 W m{sup -2} over Central China. The different responses of SW cloud radiative forcing in different regions was related to cloud feedbacks and natural variability.

  16. Multiwavelength observations of a devleoping cloud system: The FIRE II 26 November 1991 case study

    SciTech Connect (OSTI)

    Intrieri, J.M.; Eberhard, W.L.; Uttal, T.

    1995-12-01

    Simultaneous multiwavelength measurements of a developing cloud system were obtained by NOAA Doppler lidar, Doppler radar, Fourier transform infrared interferometer, and microwave and infrared radiometers on 26 November 1991. The evolution of the cloud system is described in terms of lidar backscatter, radar reflectivity and velocity, interferometer atmospheric spectra, and radiometer brightness temperature, integrated liquid water, and water vapor paths. Utilizing the difference in wavelength between the radar and lidar, and therefore their independent sensitivity to different regions of the same cloud, the cloud top, base, depth, and multiple layer heights can be determined with better accuracy than with either instrument alone. Combining the radar, lidar, and radiometer measurements using two different techniques allows an estimation of the vertical profile of cloud microphysical properties such as particle sizes. Enhancement of lidar backscatter near zenith revealed when highly oriented ice crystals were present. The authors demonstrate that no single instrument is sufficient to accurately describe cirrus clouds and that measurements in combination can provide important details on their geometric, radiative, and microphysical properties.

  17. Thermodynamic phase profiles of optically thin midlatitude cloud and their relation to temperature

    SciTech Connect (OSTI)

    Naud, C. M.; Del Genio, Anthony D.; Haeffelin, M.; Morille, Y.; Noel, V.; Dupont, Jean-Charles; Turner, David D.; Lo, Chaomei; Comstock, Jennifer M.

    2010-06-03

    Winter cloud phase and temperature profiles derived from ground-based lidar depolarization and radiosonde measurements are analyzed for two midlatitude locations: the United States Atmospheric Radiation Measurement Program Southern Great Plains (SGP) site and the Site Instrumental de Recherche par Télédétection Atmosphérique (SIRTA) in France. Because lidars are attenuated in optically thick clouds, the dataset only includes optically thin clouds (optical thickness < 3). At SGP, 57% of the clouds observed with the lidar in the temperature range 233-273 K are either completely liquid or completely glaciated, while at SIRTA only 42% of the observed clouds are single phase, based on a depolarization ratio threshold of 11% for differentiating liquid from ice. Most optically thin mixed phase clouds show an ice layer at cloud top, and clouds with liquid at cloud top are less frequent. The relationship between ice phase occurrence and temperature only slightly changes between cloud base and top. At both sites liquid is more prevalent at colder temperatures than has been found previously in aircraft flights through frontal clouds of greater optical thicknesses. Liquid in clouds persists to colder temperatures at SGP than SIRTA. This information on the average temperatures of mixed phase clouds at both locations complements earlier passive satellite remote sensing measurements that sample cloud phase near cloud top and for a wider range of cloud optical thicknesses.

  18. A New Two-Moment Bulk Stratiform Cloud Microphysics Scheme in the Community Atmosphere Model, Version 3 (CAM3). Part II: Single-Column and Global Results

    SciTech Connect (OSTI)

    Gettelman, A.; Morrison, H.; Ghan, Steven J.

    2008-08-11

    The global performance of a new 2-moment cloud microphysics scheme for a General Circulation Model (GCM) is presented and evaluated relative to observations. The scheme produces reasonable representations of cloud particle size and number concentration when compared to observations, and represents expected and observed spatial variations in cloud microphysical quantities. The scheme has smaller particles and higher number concentrations over land than the standard bulk microphysics in the GCM, and is able to balance the radiation budget of the planet with 60% the liquid water of the standard scheme, in better agreement with observations. The new scheme treats both the mixing ratio and number concentration of rain and snow, and is therefore able to differentiate the two key regimes, consisting of drizzle in shallow warm clouds and larger rain drops in deeper cloud systems. The modeled rain and snow size distributions are consistent with observations.

  19. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    Coal liquids can be hydrogenated catalyzed by Catalyst 2 include monocyclic aromatic ... PROGRESS REPORT; ORGANOMETALLIC COMPOUNDS; EXPERIMENTAL DATA Word Cloud More Like ...

  20. ARM - Measurement - Cloud type

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement : Cloud type Cloud type such as cirrus, stratus, cumulus etc Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  1. Ice Concentration Retrieval in Stratiform Mixed-phase Clouds Using Cloud Radar Reflectivity Measurements and 1D Ice Growth Model Simulations

    SciTech Connect (OSTI)

    Zhang, Damao; Wang, Zhien; Heymsfield, Andrew J.; Fan, Jiwen; Luo, Tao

    2014-10-01

    Measurement of ice number concentration in clouds is important but still challenging. Stratiform mixed-phase clouds (SMCs) provide a simple scenario for retrieving ice number concentration from remote sensing measurements. The simple ice generation and growth pattern in SMCs offers opportunities to use cloud radar reflectivity (Ze) measurements and other cloud properties to infer ice number concentration quantitatively. To understand the strong temperature dependency of ice habit and growth rate quantitatively, we develop a 1-D ice growth model to calculate the ice diffusional growth along its falling trajectory in SMCs. The radar reflectivity and fall velocity profiles of ice crystals calculated from the 1-D ice growth model are evaluated with the Atmospheric Radiation Measurements (ARM) Climate Research Facility (ACRF) ground-based high vertical resolution radar measurements. Combining Ze measurements and 1-D ice growth model simulations, we develop a method to retrieve the ice number concentrations in SMCs at given cloud top temperature (CTT) and liquid water path (LWP). The retrieved ice concentrations in SMCs are evaluated with in situ measurements and with a three-dimensional cloud-resolving model simulation with a bin microphysical scheme. These comparisons show that the retrieved ice number concentrations are within an uncertainty of a factor of 2, statistically.

  2. Dispersion of Cloud Droplet Size Distributions, Cloud Parameterization...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Broomfield, Colorado, March 31-April 4, 2003 indicates that for a given liquid water content and droplet concentration, the effect of spectral dispersion alone can cause...

  3. Apparatus and method for pumping hot, erosive slurry of coal solids in coal derived, water immiscible liquid

    DOE Patents [OSTI]

    Ackerman, Carl D.

    1983-03-29

    An apparatus for and method of pumping hot, erosive slurry of coal solids in a coal derived, water immiscible liquid to higher pressure involves the use of a motive fluid which is miscible with the liquid of the slurry. The apparatus includes a pump 12, a remote check valve 14 and a chamber 16 between and in fluid communication with the pump 12 and check valve 14 through conduits 18,20. Pump 12 exerts pressure on the motive fluid and thereby on the slurry through a concentration gradient of coal solids within chamber 16 to alternately discharge slurry under pressure from the outlet port of check valve 14 and draw slurry in through the inlet port of check valve 14.

  4. Final Scientific/Technical Report Grant title: Use of ARM Measurements of Spectral Zenith Radiance for Better Understanding of 3D Cloud-Radiation Processes and Aerosol-Cloud Interaction This is a collaborative project with the NASA GSFC project of Dr. A. Marshak and W. Wiscombe (PIs). This report covers BU activities from February 2011 to June 2011 and BU "œno-cost extension" activities from June 2011 to June 2012. This report summarizes results that complement a final technical report submitted by the PIs in 2011.

    SciTech Connect (OSTI)

    Knyazikhin, Y

    2012-09-10

    Main results are summarized for work in these areas: spectrally-invariant approximation within atmospheric radiative transfer; spectral invariance of single scattering albedo for water droplets and ice crystals at weakly absorbing wavelengths; seasonal changes in leaf area of Amazon forests from leaf flushing and abscission; and Cloud droplet size and liquid water path retrievals from zenith radiance measurements.

  5. Dispelling Clouds of Uncertainty

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lewis, Ernie; Teixeira, João

    2015-06-15

    How do you build a climate model that accounts for cloud physics and the transitions between cloud regimes? Use MAGIC.

  6. Cloud Properties and Radiative Heating Rates for TWP (Dataset...

    Office of Scientific and Technical Information (OSTI)

    irradiance; Liquid water content; Liquid water path; Ozone Concentration; Precipitation; Radar reflectivity; Radiative heating rate; Surface albedo Dataset File size NAView ...

  7. Low-Pressure Solubility of Gases in Liquid Water | Open Energy...

    Open Energy Info (EERE)

    Water Abstract Abstract unavailable. Authors Emmerich Wilhelm, Rubin Battino and Robert J. Wilcock Published Journal Chemical reviews, 1977 DOI Not Provided Check for DOI...

  8. Decontamination of Nuclear Liquid Wastes Status of CEA and AREVA R and D: Application to Fukushima Waste Waters - 12312

    SciTech Connect (OSTI)

    Fournel, B.; Barre, Y.; Lepeytre, C.; Peycelon, H.; Grandjean, A.; Prevost, T.; Valery, J.F.; Shilova, E.; Viel, P.

    2012-07-01

    Liquid wastes decontamination processes are mainly based on two techniques: Bulk processes and the so called Cartridges processes. The first technique has been developed for the French nuclear fuel reprocessing industry since the 60's in Marcoule and La Hague. It is a proven and mature technology which has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The second technique, involving cartridges processes, offers new opportunities for the use of innovative adsorbents. The AREVA process developed for Fukushima and some results obtained on site will be presented as well as laboratory scale results obtained in CEA laboratories. Examples of new adsorbents development for liquid wastes decontamination are also given. A chemical process unit based on co-precipitation technique has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The asset of this technique is its ability to process large volumes in a continuous mode. Several chemical products can be used to address specific radioelements such as: Cs, Sr, Ru. Its drawback is the production of sludge (about 1% in volume of initial liquid volume). CEA developed strategies to model the co-precipitation phenomena in order to firstly minimize the quantity of added chemical reactants and secondly, minimize the size of co-precipitation units. We are on the way to design compact units that could be mobilized very quickly and efficiently in case of an accidental situation. Addressing the problem of sludge conditioning, cementation appears to be a very attractive solution. Fukushima accident has focused attention on optimizations that should be taken into account in future studies: - To better take account for non-typical aqueous matrixes like seawater; - To enlarge the spectrum of radioelements that can be efficiently processed and especially short lives radioelements that are usually less present in standard effluents resulting from nuclear activities; - To develop reversible solid adsorbents for cartridge-type applications in order to minimize wastes. (authors)

  9. Radiative Influences on Glaciation Time-Scales of Mixed-Phase Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiative Influences on Glaciation Time-Scales of Mixed-Phase Clouds Harrington, Jerry The Pennsylvania State University Category: Modeling Mixed-phase stratus clouds are dominant in the Arctic during much of the year. These clouds typically have liquid tops that precipitate ice. Time scales for the complete glaciation of such clouds (the Bergeron process) are typically computed using the classical mass growth equations for crystals and liquid drops. However, mixed phase arctic stratus have

  10. Testing a New Cirrus Cloud Parameterizaton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing a New Cirrus Cloud Parameterization in NCAR CCM3 D. Zurovac-Jevtic, G. J. Zhang, and V. Ramanathan Center for Atmospheric Sciences Scripps Institute of Oceanography La Jolla, California Introduction Cirrus cloud cover and ice water content (IWC) are the two most important properties of cirrus clouds. However, in general circulation models (GCMs), their treatment is very crude. For example, in the National Center for Atmospheric Research (NCAR) Community Climate Model (CCM3), IWC is

  11. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu; Ly, Jennifer; Aldajani, Tiem; Baker, Richard W.

    2011-08-23

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  12. Indirect and Semi-Direct Aerosol Campaign: The Impact of Arctic Aerosols on Clouds

    SciTech Connect (OSTI)

    McFarquhar, Greg; Ghan, Steven J.; Verlinde, J.; Korolev, Alexei; Strapp, J. Walter; Schmid, Beat; Tomlinson, Jason M.; Wolde, Mengistu; Brooks, Sarah D.; Cziczo, Daniel J.; Dubey, Manvendra K.; Fan, Jiwen; Flynn, Connor J.; Gultepe, Ismail; Hubbe, John M.; Gilles, Mary K.; Laskin, Alexander; Lawson, Paul; Leaitch, W. R.; Liu, Peter S.; Liu, Xiaohong; Lubin, Dan; Mazzoleni, Claudio; Macdonald, A. M.; Moffet, Ryan C.; Morrison, H.; Ovchinnikov, Mikhail; Shupe, Matthew D.; Turner, David D.; Xie, Shaocheng; Zelenyuk, Alla; Bae, Kenny; Freer, Matthew; Glen, Andrew

    2011-02-01

    A comprehensive dataset of microphysical and radiative properties of aerosols and clouds in the arctic boundary layer in the vicinity of Barrow, Alaska was collected in April 2008 during the Indirect and Semi-Direct Aerosol Campaign (ISDAC) sponsored by the Department of Energy Atmospheric Radiation Measurement (ARM) and Atmospheric Science Programs. The primary aim of ISDAC was to examine indirect effects of aerosols on clouds that contain both liquid and ice water. The experiment utilized the ARM permanent observational facilities at the North Slope of Alaska (NSA) in Barrow. These include a cloud radar, a polarized micropulse lidar, and an atmospheric emitted radiance interferometer as well as instruments specially deployed for ISDAC measuring aerosol, ice fog, precipitation and spectral shortwave radiation. The National Research Council of Canada Convair-580 flew 27 sorties during ISDAC, collecting data using an unprecedented 42 cloud and aerosol instruments for more than 100 hours on 12 different days. Data were obtained above, below and within single-layer stratus on 8 April and 26 April 2008. These data enable a process-oriented understanding of how aerosols affect the microphysical and radiative properties of arctic clouds influenced by different surface conditions. Observations acquired on a heavily polluted day, 19 April 2008, are enhancing this understanding. Data acquired in cirrus on transit flights between Fairbanks and Barrow are improving our understanding of the performance of cloud probes in ice. Ultimately the ISDAC data will be used to improve the representation of cloud and aerosol processes in models covering a variety of spatial and temporal scales, and to determine the extent to which long-term surface-based measurements can provide retrievals of aerosols, clouds, precipitation and radiative heating in the Arctic.

  13. Interactions between drops of molten Al-Li alloys and liquid water

    SciTech Connect (OSTI)

    Hyder, M.L.; Nelson, L.S.; Duda, P.M.; Hyndman, D.A.

    1993-08-01

    Sandia National Laboratories, at the request of the Savannah River Technology Center (SRTC), studied the interactions between single drops of molten aluminum-lithium alloys and water. Most experiments were performed with ``B`` alloy (3.1 w/o Li, balance A1). Objectives were to develop experimental procedures for preparing and delivering the melt drops and diagnostics for characterizing the interactions, measure hydrogen generated by the reaction between melt and water, examine debris recovered after the interaction, determine changes in the aqueous phase produced by the melt-water chemical reactions, and determine whether steam explosions occur spontaneously under the conditions studied. Although many H{sub 2} bubbles were generated after the drops entered the water, spontaneous steam explosions never occurred when globules of the ``B`` alloy at temperatures between 700 and 1000C fell freely through water at room temperature, or upon or during subsequent contact with submerged aluminum or stainless steel surfaces. Total amounts of H{sub 2} (STP) increased from about 2 to 9 cm{sup 3}/per gram of melt as initial melt temperature increased over this range of temperatures.

  14. Ultrafast dynamics of liquid water: Energy relaxation and transfer processes of the OH stretch and the HOH bend

    SciTech Connect (OSTI)

    Imoto, Sho; Xantheas, Sotiris S.; Saito, Shinji

    2015-08-27

    The vibrational energy relaxation and transfer processes of the OH stretching and the HOH bending vibrations in liquid water are investigated via the theoretical calculation of the pump-probe spectra obtained from non-equilibrium molecular dynamics simulations with the TTM3-F interaction potential. The excitation of the OH stretch induces an instantaneous response of the high frequency librational motions in the 600-1000 cm-1 range. In addition, the excess energy of the OH stretch of a water molecule quickly transfers to the OH stretches of molecules in its first hydration shell with a time constant of ~50 fs, followed by relaxation to the HOH bends of the surrounding molecules with a time constant of 230 fs. The excitation of the HOH bend also results in the ultrafast excitation of the high frequency librational motions. The energy of the excited HOH bend of a water molecule decays, with a time constant of 200 fs, mainly to the relaxation of the HOH bends of its surrounding molecules. The energies of the HOH bends were found to transfer quickly to the intermolecular motions via the coupling with the high frequency librational motions. The excess energy of the OH stretch or the HOH bend relaxes to the high frequency intermolecular librational motions and eventually to the hot ground state with a time scale of ~1 ps via the coupling with the librational and translational motions. The energy relaxation and transfer processes were found to depend on the local hydrogen bonding network; the relaxations of the excess energy of the OH stretch and the HOH bend of four- and five-coordinated molecules are faster than those of a three-coordinated molecule due to the delocalization of the vibrational motions of the former (four- and five-coordinated molecules) compared to those of the later (three-coordinated molecules). The present results highlight the importance of the high frequency intermolecular librational modes in facilitating the ultrafast energy relaxation process in liquid water via their strong nonlinear couplings with the intramolecular OH stretching and HOH bending vibrations. S.S.X. acknowledges the support of the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. The calculation was carried out using the computing resources at the Research Center for Computational Science in Okazaki, Japan.

  15. High-brightness water-window electron-impact liquid-jet microfocus source

    SciTech Connect (OSTI)

    Skoglund, P.; Lundstroem, U.; Vogt, U.; Hertz, H. M.

    2010-02-22

    We demonstrate stable high-brightness operation of an electron-impact water-jet-anode soft x-ray source. A 30 kV, 7.8 W electron beam is focused onto a 20 mum diameter jet resulting in water-window oxygen line emission at 525 eV/2.36 nm with a brightness of 3.0x10{sup 9} ph/(sxmum{sup 2}xsrxline). Monte Carlo-based modeling shows good quantitative agreement with the experiments. The source has potential to increase the x-ray power and brightness by another 1-2 orders of magnitude and fluid-dynamical jet instabilities is determined to be the most important limiting factor. The source properties make it an attractive alternative for table-top x-ray microscopy.

  16. Bringing Clouds into Focus

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    clouds. Instead, global climate models must rely on parameterizations, which are statistical representations of phenomena, such as cloud cover or precipitation rates, that...

  17. ARM - Measurement - Cloud location

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    point in space and time, typically expressed as a binary cloud mask. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  18. Dispelling Clouds of Uncertainty

    SciTech Connect (OSTI)

    Lewis, Ernie; Teixeira, João

    2015-06-15

    How do you build a climate model that accounts for cloud physics and the transitions between cloud regimes? Use MAGIC.

  19. Developing and Evaluating Ice Cloud Parameterizations by

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by remote sensing is that the transfer functions which relate the observables (e. g., radar Doppler spectrum) to cloud properties (e. g., ice water content, or IWC) are not...

  20. Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model

    SciTech Connect (OSTI)

    Liu, Haihu; Valocchi, Albert J.; Werth, Charles J.; Kang, Oinjun; Oostrom, Martinus

    2014-11-01

    A lattice Boltzmann color-fluid model, which was recently proposed by Liu et al. [H. Liu, A.J. Valocchi, and Q. Kang. Three-dimensional lattice Boltzmann model for immiscible two-phase flow simulations. Phys. Rev. E, 85:046309, 2012.] based on a concept of continuum surface force, is improved to simulate immiscible two-phase flows in porous media. The new improvements allow the model to account for different kinematic viscosities of both fluids and to model fluid-solid interactions. The capability and accuracy of this model is first validated by two benchmark tests: a layered two-phase flow with a viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid CO2 (LCO2) displacing water in a dual-permeability pore network. The extent and behavior of LCO2 preferential flow (i.e., fingering) is found to depend on the capillary number (Ca), and three different displacement patterns observed in previous micromodel experiments are reproduced. The predicted variation of LCO2 saturation with Ca, as well as variation of specific interfacial length with LCO2 saturation, are both in good agreement with the experimental observations. To understand the effect of heterogeneity on pore-scale displacement, we also simulate LCO2 displacing water in a randomly heterogeneous pore network, which has the same size and porosity as the dual-permeability pore network. In comparison to the dual-permeability case, the transition from capillary fingering to viscous fingering occurs at a higher Ca, and LCO2 saturation is higher at low Ca but lower at high Ca. In either pore network, the LCO2-water specific interfacial length is found to obey a power-law dependence on LCO2 saturation.

  1. MAGIC Cloud Properties from Zenith Radiance Data Final Campaign Summary

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect MAGIC Cloud Properties from Zenith Radiance Data Final Campaign Summary Citation Details In-Document Search Title: MAGIC Cloud Properties from Zenith Radiance Data Final Campaign Summary Cloud droplet size and optical depth are the most fundamental properties for understanding cloud formation, dissipation and interactions with aerosol and drizzle. They are also a crucial determinant of Earth's radiative and water-energy balances. However, these properties

  2. Effects of excluded volume and correlated molecular orientations on Frster resonance energy transfer in liquid water

    SciTech Connect (OSTI)

    Yang, Mino

    2014-04-14

    Frster theory for the survival probability of excited chromophores is generalized to include the effects of excluded volume and orientation correlation in the molecular distribution. An analytical expression for survival probability was derived and written in terms of a few simple elementary functions. Because of the excluded volume, the survival probability exhibits exponential decay at early times and stretched exponential decay at later times. Experimental schemes to determine the size of the molecular excluded volume are suggested. With the present generalization of theory, we analyzed vibrational resonance energy transfer kinetics in neat water. Excluded volume effects prove to be important and slow down the kinetics at early times. The majority of intermolecular resonance energy transfer was found to occur with exponential kinetics, as opposed to the stretched exponential behavior predicted by Frster theory. Quantum yields of intra-molecular vibrational relaxation, intra-, and intermolecular energy transfer were calculated to be 0.413, 0.167, and 0.420, respectively.

  3. Assessment of Uncertainty in Cloud Radiative Effects and Heating...

    Office of Scientific and Technical Information (OSTI)

    functions of effective radius (Re), ice water content (IWC), extinction, ice number ... quantities on the cloud radiative effect and radiative heating rates are presented. ...

  4. Improved Retrievals of Temperature and Water Vapor Profiles Using a Twelve-Channel Microwave Radiometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrievals of Temperature and Water Vapor Profiles Using a Twelve-Channel Microwave Radiometer J. C. Liljegren Environmental Research Division Argonne National Laboratory Argonne, Illinois Introduction Radiometrics Corporation has developed a twelve-channel microwave radiometer capable of providing continuous, real-time vertical profiles of temperature, water vapor, and limited-resolution cloud liquid water from the surface to 10 km in nearly all weather conditions (Solheim et al. 1998a). Since

  5. Using Doppler spectra to separate hydrometeor populations and analyze ice precipitation in multilayered mixed-phase clouds

    SciTech Connect (OSTI)

    Rambukkange, Mahlon P.; Verlinde, J.; Eloranta, E. W.; Flynn, Connor J.; Clothiaux, Eugene E.

    2011-01-31

    Multimodality of cloud radar Doppler spectra is used to partition cloud particle phases and to separate distinct ice populations in the radar sample volume, thereby facilitating analysis of individual ice showers in multilayered mixed-phase clouds. A 35-GHz cloud radar located at Barrow, Alaska, during the Mixed-Phase Arctic Cloud Experiment collected the Doppler spectra. Data from a pair of collocated depolarization lidars confirmed the presence of two liquid cloud layers reported in this study. Surprisingly, both of these cloud layers were embedded in ice precipitation yet maintained their liquid. Our spectral separation of the ice precipitation yielded two distinct ice populations: ice initiated within the two liquid cloud layers and ice precipitation formed in higher cloud layers. Comparisons of ice fall velocity versus radar reflectivity relationships derived for distinct showers reveal that a single relationship might not properly represent the ice showers during this period.

  6. Transforming the representation of the boundary layer and low clouds for high-resolution regional climate modeling: Final report

    SciTech Connect (OSTI)

    Huang, Hsin-Yuan; Hall, Alex

    2013-07-24

    Stratocumulus and shallow cumulus clouds in subtropical oceanic regions (e.g., Southeast Pacific) cover thousands of square kilometers and play a key role in regulating global climate (e.g., Klein and Hartmann, 1993). Numerical modeling is an essential tool to study these clouds in regional and global systems, but the current generation of climate and weather models has difficulties in representing them in a realistic way (e.g., Siebesma et al., 2004; Stevens et al., 2007; Teixeira et al., 2011). While numerical models resolve the large-scale flow, subgrid-scale parameterizations are needed to estimate small-scale properties (e.g. boundary layer turbulence and convection, clouds, radiation), which have significant influence on the resolved scale due to the complex nonlinear nature of the atmosphere. To represent the contribution of these fine-scale processes to the resolved scale, climate models use various parameterizations, which are the main pieces in the model that contribute to the low clouds dynamics and therefore are the major sources of errors or approximations in their representation. In this project, we aim to 1) improve our understanding of the physical processes in thermal circulation and cloud formation, 2) examine the performance and sensitivity of various parameterizations in the regional weather model (Weather Research and Forecasting model; WRF), and 3) develop, implement, and evaluate the advanced boundary layer parameterization in the regional model to better represent stratocumulus, shallow cumulus, and their transition. Thus, this project includes three major corresponding studies. We find that the mean diurnal cycle is sensitive to model domain in ways that reveal the existence of different contributions originating from the Southeast Pacific land-masses. The experiments suggest that diurnal variations in circulations and thermal structures over this region are influenced by convection over the Peruvian sector of the Andes cordillera, while the mostly dry mountain-breeze circulations force an additional component that results in semi-diurnal variations near the coast. A series of numerical tests, however, reveal sensitivity of the simulations to the choice of vertical grid, limiting the possibility of solid quantitative statements on the amplitudes and phases of the diurnal and semidiurnal components across the domain. According to our experiments, the Mellor-Yamada-Nakanishi-Niino (MYNN) boundary layer scheme and the WSM6 microphysics scheme is the combination of schemes that performs best. For that combination, mean cloud cover, liquid water path, and cloud depth are fairly wellsimulated, while mean cloud top height remains too low in comparison to observations. Both microphysics and boundary layer schemes contribute to the spread in liquid water path and cloud depth, although the microphysics contribution is slightly more prominent. Boundary layer schemes are the primary contributors to cloud top height, degree of adiabaticity, and cloud cover. Cloud top height is closely related to surface fluxes and boundary layer structure. Thus, our study infers that an appropriate tuning of cloud top height would likely improve the low-cloud representation in the model. Finally, we show that entrainment governs the degree of adiabaticity, while boundary layer decoupling is a control on cloud cover. In the intercomparison study using WRF single-column model experiments, most parameterizations show a poor agreement of the vertical boundary layer structure when compared with large-eddy simulation models. We also implement a new Total-Energy/Mass- Flux boundary layer scheme into the WRF model and evaluate its ability to simulate both stratocumulus and shallow cumulus clouds. Result comparisons against large-eddy simulation show that this advanced parameterization based on the new Eddy-Diffusivity/Mass-Flux approach provides a better performance than other boundary layer parameterizations.

  7. Cloud radar Doppler spectra in drizzling stratiform clouds: 1. Forward modeling and remote sensing applications

    SciTech Connect (OSTI)

    Kollias, P.; Luke, E.; Rmillard, J.; Szyrmer, W.

    2011-07-02

    Several aspects of spectral broadening and drizzle growth in shallow liquid clouds remain not well understood. Detailed, cloud-scale observations of microphysics and dynamics are essential to guide and evaluate corresponding modeling efforts. Profiling, millimeter-wavelength (cloud) radars can provide such observations. In particular, the first three moments of the recorded cloud radar Doppler spectra, the radar reflectivity, mean Doppler velocity, and spectrum width, are often used to retrieve cloud microphysical and dynamical properties. Such retrievals are subject to errors introduced by the assumptions made in the inversion process. Here, we introduce two additional morphological parameters of the radar Doppler spectrum, the skewness and kurtosis, in an effort to reduce the retrieval uncertainties. A forward model that emulates observed radar Doppler spectra is constructed and used to investigate these relationships. General, analytical relationships that relate the five radar observables to cloud and drizzle microphysical parameters and cloud turbulence are presented. The relationships are valid for cloud-only, cloud mixed with drizzle, and drizzle-only particles in the radar sampling volume and provide a seamless link between observations and cloud microphysics and dynamics. The sensitivity of the five observed parameters to the radar operational parameters such as signal-to-noise ratio and Doppler spectra velocity resolution are presented. The predicted values of the five observed radar parameters agree well with the output of the forward model. The novel use of the skewness of the radar Doppler spectrum as an early qualitative predictor of drizzle onset in clouds is introduced. It is found that skewness is a parameter very sensitive to early drizzle generation. In addition, the significance of the five parameters of the cloud radar Doppler spectrum for constraining drizzle microphysical retrievals is discussed.

  8. First observations of tracking clouds using scanning ARM cloud...

    Office of Scientific and Technical Information (OSTI)

    Tracking clouds using scanning cloud radars can help to document the temporal evolution of ... Following CITA, the temporal evolution of cloud element properties (number, size, and ...

  9. A High Resolution Hydrometer Phase Classifier Based on Analysis of Cloud

    Office of Scientific and Technical Information (OSTI)

    Radar Doppler Spectra. (Conference) | SciTech Connect High Resolution Hydrometer Phase Classifier Based on Analysis of Cloud Radar Doppler Spectra. Citation Details In-Document Search Title: A High Resolution Hydrometer Phase Classifier Based on Analysis of Cloud Radar Doppler Spectra. The lifecycle and radiative properties of clouds are highly sensitive to the phase of their hydrometeors (i.e., liquid or ice). Knowledge of cloud phase is essential for specifying the optical properties of

  10. First observations of tracking clouds using scanning ARM cloud radars

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: First observations of tracking clouds using scanning ARM cloud radars Citation Details In-Document Search Title: First observations of tracking clouds using scanning ARM cloud radars Tracking clouds using scanning cloud radars can help to document the temporal evolution of cloud properties well before large drop formation (''first echo''). These measurements complement cloud and precipitation tracking using geostationary satellites and

  11. ARM - Measurement - Cloud extinction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud extinction The removal of radiant energy from an incident beam by the process of cloud absorption andor ...

  12. Humidity trends imply increased sensitivity to clouds in a warming...

    Office of Scientific and Technical Information (OSTI)

    at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. ... and variability in clouds14, water vapour15,16 and surface emission16,17 all ...

  13. ARM Cloud Aerosol Precipitation Experiment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Precipitation Experiment a NOAA ship in the Pacific Ocean and on a DOE- sponsored plane over land and sea. These researchers will study: (1) water sources, evolution and structure of atmospheric rivers over the Pacific Ocean (2) long range transport of aerosols over the Pacific Ocean between Hawaii and the U.S. West Coast, and how aerosols interact with atmospheric rivers (3) the point where atmospheric rivers make landfall on the U.S. West Coast, especially how clouds form where

  14. Using Radar, Lidar, and Radiometer measurements to Classify Cloud Type and Study Middle-Level Cloud Properties

    SciTech Connect (OSTI)

    Wang, Zhien

    2010-06-29

    The project is mainly focused on the characterization of cloud macrophysical and microphysical properties, especially for mixed-phased clouds and middle level ice clouds by combining radar, lidar, and radiometer measurements available from the ACRF sites. First, an advanced mixed-phase cloud retrieval algorithm will be developed to cover all mixed-phase clouds observed at the ACRF NSA site. The algorithm will be applied to the ACRF NSA observations to generate a long-term arctic mixed-phase cloud product for model validations and arctic mixed-phase cloud processes studies. To improve the representation of arctic mixed-phase clouds in GCMs, an advanced understanding of mixed-phase cloud processes is needed. By combining retrieved mixed-phase cloud microphysical properties with in situ data and large-scale meteorological data, the project aim to better understand the generations of ice crystals in supercooled water clouds, the maintenance mechanisms of the arctic mixed-phase clouds, and their connections with large-scale dynamics. The project will try to develop a new retrieval algorithm to study more complex mixed-phase clouds observed at the ACRF SGP site. Compared with optically thin ice clouds, optically thick middle level ice clouds are less studied because of limited available tools. The project will develop a new two wavelength radar technique for optically thick ice cloud study at SGP site by combining the MMCR with the W-band radar measurements. With this new algorithm, the SGP site will have a better capability to study all ice clouds. Another area of the proposal is to generate long-term cloud type classification product for the multiple ACRF sites. The cloud type classification product will not only facilitates the generation of the integrated cloud product by applying different retrieval algorithms to different types of clouds operationally, but will also support other research to better understand cloud properties and to validate model simulations. The ultimate goal is to improve our cloud classification algorithm into a VAP.

  15. Wide-angle imaging LIDAR (WAIL): a ground-based instrument for monitoring the thickness and density of optically thick clouds.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B.; Rohde, C. A.; Ho, Cheng,

    2001-01-01

    Traditional lidar provides little information on dense clouds beyond the range to their base (ceilometry), due to their extreme opacity. At most optical wavelengths, however, laser photons are not absorbed but merely scattered out of the beam, and thus eventually escape the cloud via multiple scattering, producing distinctive extended space- and time-dependent patterns which are, in essence, the cloud's radiative Green functions. These Green functions, essentially 'movies' of the time evolution of the spatial distribution of escaping light, are the primary data products of a new type of lidar: Wide Angle Imaging Lidar (WAIL). WAIL data can be used to infer both optical depth and physical thickness of clouds, and hence the cloud liquid water content. The instrumental challenge is to accommodate a radiance field varying over many orders of magnitude and changing over widely varying time-scales. Our implementation uses a high-speed microchannel plate/crossed delay line imaging detector system with a 60-degree full-angle field of view, and a 532 nm doubled Nd:YAG laser. Nighttime field experiments testing various solutions to this problem show excellent agreement with diffusion theory, and retrievals yield plausible values for the optical and geometrical parameters of the observed cloud decks.

  16. Vapor-liquid Equilibria and Polarization Behavior of the GCP Water Model: Gaussian Charge-on-spring versus Dipole Self-consistent Field approaches to induced polarization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chialvo, Ariel A; Moucka, Filip; Vlcek, Lukas; Nezbeda, Ivo

    2015-01-01

    We implemented the Gaussian charge-on-spring (GCOS) version of the original self-consistent field implementation of the Gaussian Charge Polarizable water model and test its accuracy to represent the polarization behavior of the original model involving smeared charges and induced dipole moments. For that purpose we adapted the recently developed multiple-particle-move (MPM) within the Gibbs and isochoric-isothermal ensembles Monte Carlo methods for the efficient simulation of polarizable fluids. We assessed the accuracy of the GCOS representation by a direct comparison of the resulting vapor-liquid phase envelope, microstructure, and relevant microscopic descriptors of water polarization along the orthobaric curve against the corresponding quantitiesmore » from the actual GCP water model.« less

  17. Advantages of liquid fluoride thorium reactor in comparison with...

    Office of Scientific and Technical Information (OSTI)

    comparison with light water reactor Citation Details In-Document Search Title: Advantages of liquid fluoride thorium reactor in comparison with light water reactor Liquid Fluoride ...

  18. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

  19. Polluting of Winter Convective Clouds upon Transition from Ocean Inland

    Office of Scientific and Technical Information (OSTI)

    Over Central California: Contrasting Case Studies (Journal Article) | SciTech Connect Polluting of Winter Convective Clouds upon Transition from Ocean Inland Over Central California: Contrasting Case Studies Citation Details In-Document Search Title: Polluting of Winter Convective Clouds upon Transition from Ocean Inland Over Central California: Contrasting Case Studies In-situ aircraft measurements of aerosol chemical and cloud microphysical properties were conducted during the CalWater

  20. ARM Cloud-Aerosol-Precipitation Experiment (ACAPEX) Field Campaign Report

    Office of Scientific and Technical Information (OSTI)

    (Program Document) | SciTech Connect SciTech Connect Search Results Program Document: ARM Cloud-Aerosol-Precipitation Experiment (ACAPEX) Field Campaign Report Citation Details In-Document Search Title: ARM Cloud-Aerosol-Precipitation Experiment (ACAPEX) Field Campaign Report The U.S. Department of Energy (DOE)'s Atmospheric Radiation Measurement (ARM) Climate Research Facility's ARM Cloud-Aerosol-Precipitation Experiment (ACAPEX) field campaign contributes to CalWater 2015, a multi-agency

  1. Technical Note: Improvements in GEANT4 energy-loss model and the effect on low-energy electron transport in liquid water

    SciTech Connect (OSTI)

    Kyriakou, I.; Incerti, S.

    2015-07-15

    Purpose: The GEANT4-DNA physics models are upgraded by a more accurate set of electron cross sections for ionization and excitation in liquid water. The impact of the new developments on low-energy electron transport simulations by the GEANT4 Monte Carlo toolkit is examined for improving its performance in dosimetry applications at the subcellular and nanometer level. Methods: The authors provide an algorithm for an improved implementation of the Emfietzoglou model dielectric response function of liquid water used in the GEANT4-DNA existing model. The algorithm redistributes the imaginary part of the dielectric function to ensure a physically motivated behavior at the binding energies, while retaining all the advantages of the original formulation, e.g., the analytic properties and the fulfillment of the f-sum-rule. In addition, refinements in the exchange and perturbation corrections to the Born approximation used in the GEANT4-DNA existing model are also made. Results: The new ionization and excitation cross sections are significantly different from those of the GEANT4-DNA existing model. In particular, excitations are strongly enhanced relative to ionizations, resulting in higher W-values and less diffusive dose-point-kernels at sub-keV electron energies. Conclusions: An improved energy-loss model for the excitation and ionization of liquid water by low-energy electrons has been implemented in GEANT4-DNA. The suspiciously low W-values and the unphysical long tail in the dose-point-kernel have been corrected owing to a different partitioning of the dielectric function.

  2. Quantum calculations of the IR spectrum of liquid water using ab initio and model potential and dipole moment surfaces and comparison with experiment

    SciTech Connect (OSTI)

    Liu, Hanchao; Wang, Yimin; Bowman, Joel M.

    2015-05-21

    The calculation and characterization of the IR spectrum of liquid water have remained a challenge for theory. In this paper, we address this challenge using a combination of ab initio approaches, namely, a quantum treatment of IR spectrum using the ab initio WHBB water potential energy surface and a refined ab initio dipole moment surface. The quantum treatment is based on the embedded local monomer method, in which the three intramolecular modes of each embedded H{sub 2}O monomer are fully coupled and also coupled singly to each of six intermolecular modes. The new dipole moment surface consists of a previous spectroscopically accurate 1-body dipole moment surface and a newly fitted ab initio intrinsic 2-body dipole moment. A detailed analysis of the new dipole moment surface in terms of the coordinate dependence of the effective atomic charges is done along with tests of it for the water dimer and prism hexamer double-harmonic spectra against direct ab initio calculations. The liquid configurations are taken from previous molecular dynamics calculations of Skinner and co-workers, using the TIP4P plus E3B rigid monomer water potential. The IR spectrum of water at 300 K in the range of 0–4000 cm{sup −1} is calculated and compared with experiment, using the ab initio WHBB potential and new ab initio dipole moment, the q-TIP4P/F potential, which has a fixed-charged description of the dipole moment, and the TTM3-F potential and dipole moment surfaces. The newly calculated ab initio spectrum is in very good agreement with experiment throughout the above spectral range, both in band positions and intensities. This contrasts to results with the other potentials and dipole moments, especially the fixed-charge q-TIP4P/F model, which gives unrealistic intensities. The calculated ab initio spectrum is analyzed by examining the contribution of various transitions to each band.

  3. ARM - Measurement - Cloud phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that involves property descriptors such as stratus, cumulus, and cirrus. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  4. Finance Idol Word Cloud

    Broader source: Energy.gov [DOE]

    This word cloud represents the topics discussed during the Big and Small Ideas: How to Lower Solar Financing Costs breakout session at the SunShot Grand Challenge.

  5. Cloud Effects on Radiative Heating Rate Profiles over Darwin using ARM and A-train Radar/Lidar Observations

    SciTech Connect (OSTI)

    Thorsen, Tyler J.; Fu, Qiang; Comstock, Jennifer M.

    2013-06-11

    Observations of clouds from the ground-based U.S. Department of Energy Atmospheric Radiation Measurement program (ARM) and satellite-based A-train are used to compute cloud radiative forcing profiles over the ARM Darwin, Australia site. Cloud properties are obtained from both radar (the ARM Millimeter Cloud Radar (MMCR) and the CloudSat satellite in the A-train) and lidar (the ARM Micropulse lidar (MPL) and the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite in the A-train) observations. Cloud microphysical properties are taken from combined radar and lidar retrievals for ice clouds and radar only or lidar only retrievals for liquid clouds. Large, statistically significant differences of up to 1.43 K/day exist between the mean ARM and A-train net cloud radiative forcing profiles. The majority of the difference in cloud radiative forcing profiles is shown to be due to a large difference in the cloud fraction above 12 km. Above this altitude the A-train cloud fraction is significantly larger because more clouds are detected by CALIPSO than by the ground-based MPL. It is shown that the MPL is unable to observe as many high clouds as CALIPSO due to being more frequently attenuated and a poorer sensitivity even in otherwise clear-sky conditions. After accounting for cloud fraction differences and instrument sampling differences due to viewing platform we determined that differences in cloud radiative forcing due to the retrieved ice cloud properties is relatively small. This study demonstrates that A-train observations are better suited for the calculation cloud radiative forcing profiles. In addition, we find that it is necessary to supplement CloudSat with CALIPSO observations to obtain accurate cloud radiative forcing profiles since a large portion of clouds at Darwin are detected by CALIPSO only.

  6. Boundary Layer Cloud Turbulence Characteristics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Boundary Layer Cloud Turbulence Characteristics Virendra Ghate Bruce Albrecht Parameter Observational Readiness (/10) Modeling Need (/10) Cloud Boundaries 9 9 Cloud Fraction Variance Skewness Up/Downdraft coverage Dominant Freq. signal Dissipation rate ??? Observation-Modeling Interface

  7. ARM - Measurement - Cloud droplet size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    droplet size Linear size (e.g. radius or diameter) of a cloud particle Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  8. TC_CLOUD_REGIME.cdr

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    intensity (e.g. May and Ballinger, 2007) Resulting Cloud Properties Examine rain DSD using polarimetric radar Examine ice cloud properties using MMCR and MPL Expect...

  9. Cloud computing security.

    SciTech Connect (OSTI)

    Shin, Dongwan; Claycomb, William R.; Urias, Vincent E.

    2010-10-01

    Cloud computing is a paradigm rapidly being embraced by government and industry as a solution for cost-savings, scalability, and collaboration. While a multitude of applications and services are available commercially for cloud-based solutions, research in this area has yet to fully embrace the full spectrum of potential challenges facing cloud computing. This tutorial aims to provide researchers with a fundamental understanding of cloud computing, with the goals of identifying a broad range of potential research topics, and inspiring a new surge in research to address current issues. We will also discuss real implementations of research-oriented cloud computing systems for both academia and government, including configuration options, hardware issues, challenges, and solutions.

  10. Intercomparison of Large-eddy Simulations of Arctic Mixed-phase Clouds: Importance of Ice Size Distribution Assumptions

    SciTech Connect (OSTI)

    Ovchinnikov, Mikhail; Ackerman, Andrew; Avramov, Alex; Cheng, Anning; Fan, Jiwen; Fridlind, Ann; Ghan, Steven J.; Harrington, Jerry Y.; Hoose, Corinna; Korolev, Alexei; McFarquhar, Greg; Morrison, H.; Paukert, Marco; Savre, Julien; Shipway, Ben; Shupe, Matthew D.; Solomon, Amy; Sulia, Kara

    2014-03-14

    Large-eddy simulations of mixed-phase Arctic clouds by 11 different models are analyzed with the goal of improving understanding and model representation of processes controlling the evolution of these clouds. In a case based on observations from the Indirect and Semi-Direct Aerosol Campaign (ISDAC), it is found that ice number concentration, Ni, exerts significant influence on the cloud structure. Increasing Ni leads to a substantial reduction in liquid water path (LWP) and potential cloud dissipation, in agreement with earlier studies. By comparing simulations with the same microphysics coupled to different dynamical cores as well as the same dynamics coupled to different microphysics schemes, it is found that the ice water path (IWP) is mainly controlled by ice microphysics, while the inter-model differences in LWP are largely driven by physics and numerics of the dynamical cores. In contrast to previous intercomparisons, all models here use the same ice particle properties (i.e., mass-size, mass-fall speed, and mass-capacitance relationships) and a common radiation parameterization. The constrained setup exposes the importance of ice particle size distributions (PSD) in influencing cloud evolution. A clear separation in LWP and IWP predicted by models with bin and bulk microphysical treatments is documented and attributed primarily to the assumed shape of ice PSD used in bulk schemes. Compared to the bin schemes that explicitly predict the PSD, schemes assuming exponential ice PSD underestimate ice growth by vapor deposition and overestimate mass-weighted fall speed leading to an underprediction of IWP by a factor of two in the considered case.

  11. The Radiative Properties of Small Clouds: Multi-Scale Observations and Modeling

    SciTech Connect (OSTI)

    Feingold, Graham; McComiskey, Allison

    2013-09-25

    Warm, liquid clouds and their representation in climate models continue to represent one of the most significant unknowns in climate sensitivity and climate change. Our project combines ARM observations, LES modeling, and satellite imagery to characterize shallow clouds and the role of aerosol in modifying their radiative effects.

  12. Automated detection of cloud and cloud-shadow in single-date Landsat imagery using neural networks and spatial post-processing

    SciTech Connect (OSTI)

    Hughes, Michael J. [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Hayes, Daniel J [ORNL] [ORNL

    2014-01-01

    Use of Landsat data to answer ecological questions is contingent on the effective removal of cloud and cloud shadow from satellite images. We develop a novel algorithm to identify and classify clouds and cloud shadow, \\textsc{sparcs}: Spacial Procedures for Automated Removal of Cloud and Shadow. The method uses neural networks to determine cloud, cloud-shadow, water, snow/ice, and clear-sky membership of each pixel in a Landsat scene, and then applies a set of procedures to enforce spatial rules. In a comparison to FMask, a high-quality cloud and cloud-shadow classification algorithm currently available, \\textsc{sparcs} performs favorably, with similar omission errors for clouds (0.8% and 0.9%, respectively), substantially lower omission error for cloud-shadow (8.3% and 1.1%), and fewer errors of commission (7.8% and 5.0%). Additionally, textsc{sparcs} provides a measure of uncertainty in its classification that can be exploited by other processes that use the cloud and cloud-shadow detection. To illustrate this, we present an application that constructs obstruction-free composites of images acquired on different dates in support of algorithms detecting vegetation change.

  13. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  14. Magellan: A Cloud Computing Testbed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Magellan News & Announcements Archive Petascale Initiative Exascale Computing APEX Home » R & D » Archive » Magellan: A Cloud Computing Testbed Magellan: A Cloud Computing Testbed Cloud computing is gaining a foothold in the business world, but can clouds meet the specialized needs of scientists? That was one of the questions NERSC's Magellan cloud computing testbed explored between 2009 and 2011. The goal of Magellan, a project funded through the U.S. Department of Energy (DOE) Oce

  15. First observations of tracking clouds using scanning ARM cloud radars

    SciTech Connect (OSTI)

    Borque, Paloma; Giangrande, Scott; Kollias, Pavlos

    2014-12-01

    Tracking clouds using scanning cloud radars can help to document the temporal evolution of cloud properties well before large drop formation (first echo). These measurements complement cloud and precipitation tracking using geostationary satellites and weather radars. Here, two-dimensional (2-D) Along-Wind Range Height Indicator (AW-RHI) observations of a population of shallow cumuli (with and without precipitation) from the 35-GHz scanning ARM cloud radar (SACR) at the DOE Atmospheric Radiation Measurements (ARM) program Southern Great Plains (SGP) site are presented. Observations from the ARM SGP network of scanning precipitation radars are used to provide the larger scale context of the cloud field and to highlight the advantages of the SACR to detect the numerous, small, non-precipitating cloud elements. A new Cloud Identification and Tracking Algorithm (CITA) is developed to track cloud elements. In CITA, a cloud element is identified as a region having a contiguous set of pixels exceeding a preset reflectivity and size threshold. The high temporal resolution of the SACR 2-D observations (30 sec) allows for an area superposition criteria algorithm to match cloud elements at consecutive times. Following CITA, the temporal evolution of cloud element properties (number, size, and maximum reflectivity) is presented. The vast majority of the designated elements during this cumulus event were short-lived non-precipitating clouds having an apparent life cycle shorter than 15 minutes. The advantages and disadvantages of cloud tracking using an SACR are discussed.

  16. pCloud: A Cloud-based Power Market Simulation Environment

    SciTech Connect (OSTI)

    Rudkevich, Aleksandr; Goldis, Evgeniy

    2012-12-02

    This research conducted by the Newton Energy Group, LLC (NEG) is dedicated to the development of pCloud: a Cloud-based Power Market Simulation Environment. pCloud is offering power industry stakeholders the capability to model electricity markets and is organized around the Software as a Service (SaaS) concept -- a software application delivery model in which software is centrally hosted and provided to many users via the internet. During the Phase I of this project NEG developed a prototype design for pCloud as a SaaS-based commercial service offering, system architecture supporting that design, ensured feasibility of key architecture's elements, formed technological partnerships and negotiated commercial agreements with partners, conducted market research and other related activities and secured funding for continue development of pCloud between the end of Phase I and beginning of Phase II, if awarded. Based on the results of Phase I activities, NEG has established that the development of a cloud-based power market simulation environment within the Windows Azure platform is technologically feasible, can be accomplished within the budget and timeframe available through the Phase II SBIR award with additional external funding. NEG believes that pCloud has the potential to become a game-changing technology for the modeling and analysis of electricity markets. This potential is due to the following critical advantages of pCloud over its competition: - Standardized access to advanced and proven power market simulators offered by third parties. - Automated parallelization of simulations and dynamic provisioning of computing resources on the cloud. This combination of automation and scalability dramatically reduces turn-around time while offering the capability to increase the number of analyzed scenarios by a factor of 10, 100 or even 1000. - Access to ready-to-use data and to cloud-based resources leading to a reduction in software, hardware, and IT costs. - Competitive pricing structure, which will make high-volume usage of simulation services affordable. - Availability and affordability of high quality power simulators, which presently only large corporate clients can afford, will level the playing field in developing regional energy policies, determining prudent cost recovery mechanisms and assuring just and reasonable rates to consumers. - Users that presently do not have the resources to internally maintain modeling capabilities will now be able to run simulations. This will invite more players into the industry, ultimately leading to more transparent and liquid power markets.

  17. Parameterizations of Cloud Microphysics and Indirect Aerosol Effects

    SciTech Connect (OSTI)

    Tao, Wei-Kuo

    2014-05-19

    1. OVERVIEW Aerosols and especially their effect on clouds are one of the key components of the climate system and the hydrological cycle [Ramanathan et al., 2001]. Yet, the aerosol effect on clouds remains largely unknown and the processes involved not well understood. A recent report published by the National Academy of Science states "The greatest uncertainty about the aerosol climate forcing - indeed, the largest of all the uncertainties about global climate forcing - is probably the indirect effect of aerosols on clouds [NRC, 2001]." The aerosol effect on clouds is often categorized into the traditional "first indirect (i.e., Twomey)" effect on the cloud droplet sizes for a constant liquid water path [Twomey, 1977] and the "semi-direct" effect on cloud coverage [e.g., Ackerman et al., 2000]. Enhanced aerosol concentrations can also suppress warm rain processes by producing a narrow droplet spectrum that inhibits collision and coalescence processes [e.g., Squires and Twomey, 1961; Warner and Twomey, 1967; Warner, 1968; Rosenfeld, 1999]. The aerosol effect on precipitation processes, also known as the second type of aerosol indirect effect [Albrecht, 1989], is even more complex, especially for mixed-phase convective clouds. Table 1 summarizes the key observational studies identifying the microphysical properties, cloud characteristics, thermodynamics and dynamics associated with cloud systems from high-aerosol continental environments. For example, atmospheric aerosol concentrations can influence cloud droplet size distributions, warm-rain process, cold-rain process, cloud-top height, the depth of the mixed phase region, and occurrence of lightning. In addition, high aerosol concentrations in urban environments could affect precipitation variability by providing an enhanced source of cloud condensation nuclei (CCN). Hypotheses have been developed to explain the effect of urban regions on convection and precipitation [van den Heever and Cotton, 2007 and Shepherd, 2005]. Recently, a detailed spectral-bin microphysical scheme was implemented into the Goddard Cumulus Ensemble (GCE) model. Atmospheric aerosols are also described using number density size-distribution functions. A spectral-bin microphysical model is very expensive from a computational point of view and has only been implemented into the 2D version of the GCE at the present time. The model is tested by studying the evolution of deep tropical clouds in the west Pacific warm pool region and summertime convection over a mid-latitude continent with different concentrations of CCN: a low "clean" concentration and a high "dirty" concentration. The impact of atmospheric aerosol concentration on cloud and precipitation will be investigated. 2. MODEL DESCRIPTION AND CASE STUDIES 2.1 GCE MODEL The model used in this study is the 2D version of the GCE model. Modeled flow is anelastic. Second- or higher-order advection schemes can produce negative values in the solution. Thus, a Multi-dimensional Positive Definite Advection Transport Algorithm (MPDATA) has been implemented into the model. All scalar variables (potential temperature, water vapor, turbulent coefficient and all five hydrometeor classes) use forward time differencing and the MPDATA for advection. Dynamic variables, u, v and w, use a second-order accurate advection scheme and a leapfrog time integration (kinetic energy semi-conserving method). Short-wave (solar) and long-wave radiation as well as a subgrid-scale TKE turbulence scheme are also included in the model. Details of the model can be found in Tao and Simpson (1993) and Tao et al. (2003). 2.2 Microphysics (Bin Model) The formulation of the explicit spectral-bin microphysical processes is based on solving stochastic kinetic equations for the size distribution functions of water droplets (cloud droplets and raindrops), and six types of ice particles: pristine ice crystals (columnar and plate-like), snow (dendrites and aggregates), graupel and frozen drops/hail. Each type is described by a special size distribution function containing 33 categories (bins). Atmospheric aerosols are also described using number density size-distribution functions (containing 33 bins). Droplet nucleation (activation) is derived from the analytical calculation of super-saturation, which is used to determine the sizes of aerosol particles to be activated and the corresponding sizes of nucleated droplets. Primary nucleation of each type of ice crystal takes place within certain temperature ranges. A detailed description of these explicitly parameterized processes can be found in Khain and Sednev (1996) and Khain et al. (1999, 2001). 2.3 Case Studies Three cases, a tropical oceanic squall system observed during TOGA COARE (Tropical Ocean and Global Atmosphere Coupled Ocean-Atmosphere Response Experiment, which occurred over the Pacific Ocean warm pool from November 1992 to February 1993), a midlatitude continental squall system observed during PRESTORM (Preliminary Regional Experiment for STORM-Central, which occurred in Kansas and Oklahoma during May-June 1985), and mid-afternoon convection observed during CRYSTAL-FACE (Cirrus Regional Study of Tropical Anvils and Cirrus Layers – Florida Area Cumulus Experiment, which occurred in Florida during July 2002), will be used to examine the impact of aerosols on deep, precipitating systems. 3. SUMMARY of RESULTS • For all three cases, higher CCN produces smaller cloud droplets and a narrower spectrum. Dirty conditions delay rain formation, increase latent heat release above the freezing level, and enhance vertical velocities at higher altitude for all cases. Stronger updrafts, deeper mixed-phase regions, and more ice particles are simulated with higher CCN in good agreement with observations. • In all cases, rain reaches the ground early with lower CCN. Rain suppression is also evident in all three cases with high CCN in good agreement with observations (Rosenfeld, 1999, 2000 and others). Rain suppression, however, only occurs during the first hour of simulation. This result suggests that microphysical processes dominate the impact of aerosols on precipitation in the early stage of precipitation development. • During the mature stage of the simulations, the effect of increasing aerosol concentration ranges from rain suppression in the PRESTORM case to little effect on surface rainfall in the CRYSTAL-FACE case to rain enhancement in the TOGA COARE case. • The model results suggest that evaporative cooling is a key process in determining whether higher CCN reduces or enhances precipitation. Cold pool strength can be enhanced by stronger evaporation. When cold pool interacts with the near surface wind shear, the low-level convergence can be stronger, facilitating secondary cloud formation and more vigorous precipitation processes. Evaporative cooling is more than two times stronger at low levels with higher CCN for the TOGA COARE case during the early stages of precipitation development. However, evaporative cooling is slightly stronger at lower levels with lower CCN for the PRESTORM case. The early formation of rain in the clean environment could allow for the formation of an earlier and stronger cold pool compared to a dirty environment. PRESTORM has a very dry environment and both large and small rain droplets can evaporate. Consequently, the cold pool is relatively weaker, and the system is relatively less intense with higher CCN. • Sensitivity tests are conducted to determine the impact of ice processes on aerosol-precipitation interaction. The results suggested that ice processes are crucial for suppressing precipitation due to high CCN for the PRESTORM case. More and smaller ice particles are generated in the dirty case and transported to the trailing stratiform region. This reduces the heavy convective rain and contributes to the weakening of the cold pool. Warm rain processes dominate the TOGA COARE case. Therefore, ice processes only play a secondary role in terms of aerosol-precipitation interaction. • Two of the three cloud systems presented in this paper formed a line structure (squall system). A 2D simulation, therefore, gives a good approximation to such a line of convective clouds. Since the real atmosphere is 3D, further 3D cloud-resolving simulations are needed to address aerosol-precipitation interactions. 4. REFERENCES Tao, W.-K., X. Li, A. Khain, T. Matsui, S. Lang, and J. Simpson, 2007: The role of atmospheric aerosol concentration on deep convective precipitation: Cloud-resolving model simulations. J. Geophy. Res., 112, D24S18, doi:10.1029/2007JD008728. All other references can be found in above paper. 5. Acknowledgements The GCE model is mainly supported by the NASA Headquarters Atmospheric Dynamics and Thermodynamics Program and the NASA Tropical Rainfall Measuring Mission (TRMM). The research was also supported by the Office of Science (BER), U. S. Department of Energy/Atmospheric Radiation Measurement (DOE/ARM) Interagency. The authors acknowledge NASA Goddard Space Flight Center for computer time used in this research.

  18. Impact of zeolite aging in hot liquid water on activity for acid-catalyzed dehydration of alcohols

    SciTech Connect (OSTI)

    Vjunov, Aleksei; Derewinski, Miroslaw A.; Fulton, John L.; Camaioni, Donald M.; Lercher, Johannes A.

    2015-08-19

    The catalytic performance of zeolite in aqueous medium depends on a multitude of factors, such as the concentration and distribution of active sites and framework integrity. Al Kedge extended Xray absorption fine structure and 27Al MAS NMR spectroscopies in combination with DFT calculations are used to determine the distribution of tetrahedral Al sites both qualitatively and quantitatively for both parent and 48 h 160 C water treated HBEA catalysts. There is no evidence of Al coordination modification after aging in water. The distribution and concentration of Al Tsites, active centers for the dehydration of cyclohexanol, do not markedly impact the catalytic performance in water, because the Brnsted acidic protons are present in the form of hydrated hydronium ions and thus have very similar acid properties. The results suggest that all Brnsted acid sites are equally active in aqueous medium. The decrease of zeolite catalytic performance after water treatment is attributed to the reduced concentration of Brnsted acid sites. Increasing the stability of pore walls and decreasing the rate of SiOSi group hydrolysis may result in improved apparent zeolite catalytic performance in aqueous medium. Authors thank B. W. Arey (PNNL) for HIM measurements, T. Huthwelker for support during Al XAFS measurements at the Swiss Light Source (PSI, Switzerland), J. Z. Hu and S. D. Burton (PNNL) for support during NMR experiments. This work was supported by the U. S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. MD acknowledges support by the Materials Synthesis and Simulation Across Scales (MS3 Initiative) conducted under Laboratory Directed Research & Development Program at PNNL. HIM imaging and NMR experiments were performed at the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the DOE Office of Science, Office of Biological and Environmental Research, located at Pacific Northwest National Laboratory (PNNL). PNNL is a multiprogram national laboratory operated for the DOE by Battelle Memorial Institute under contract # DE-AC05-76RL0-1830

  19. Sodium-Water Reaction and Thermal Hydraulics at Gas-Liquid Interface: Numerical Interpretation of Experimental Observations

    SciTech Connect (OSTI)

    Yamaguchi, Akira; Takata, Takashi; Ohshima, Hiroyuki; Suda, Kazunori

    2006-07-01

    In a sodium-cooled fast reactor development, coupled phenomena of thermal-hydraulics and chemical reaction of sodium and water vapor are of importance from the safety viewpoint. However, the sodium-water reaction (SWR) phenomena are generally complex and the experimental measurement technology is not well matured. Therefore, a numerical simulation is used for the investigation of the SWR. In this paper, a new computer program has been developed and the SWR in a counter-flow diffusion flame is studied by a numerical simulations and an experiment as well. In the computer program, Navier-Stokes equations and chemical reaction equations are solved interactively. In addition, a dynamic equation of airborne particulates is coupled with the governing equations of thermal hydraulics. A source of the particulates is the chemical reaction products, i.e. sodium hydroxide and sodium oxide. The SWR experiment is decided based on the numerical simulation. To obtain a stable reaction flame and to measure the temperature and reaction product distributions, the flow field in the experimental cell needs to be optimized. The numerical simulation is useful for designing experiments of complex phenomena and for obtaining the data. The computations are compared with experimental data. It has been demonstrated that the computational fluid dynamics code coupled with chemical reaction well predict the SWR. (authors)

  20. Scanning ARM Cloud Radars Part I: Operational Sampling Strategies

    SciTech Connect (OSTI)

    Kollias, Pavlos; Bharadwaj, Nitin; Widener, Kevin B.; Jo, Ieng; Johnson, Karen

    2014-03-01

    Probing clouds in three-dimensions has never been done with scanning millimeter-wavelength (cloud) radars in a continuous operating environment. The acquisition of scanning cloud radars by the Atmospheric Radiation Measurement (ARM) program and research institutions around the world generate the need for developing operational scan strategies for cloud radars. Here, the first generation of sampling strategies for the Scanning ARM Cloud Radars (SACRs) is discussed. These scan strategies are designed to address the scientific objectives of the ARM program, however, they introduce an initial framework for operational scanning cloud radars. While the weather community uses scan strategies that are based on a sequence of scans at constant elevations, the SACRs scan strategies are based on a sequence of scans at constant azimuth. This is attributed to the cloud properties that are vastly different for rain and snow shafts that are the primary target of precipitation radars. A cloud surveillance scan strategy is introduced (HS-RHI) based on a sequence of horizon-to-horizon Range Height Indicator (RHI) scans that sample the hemispherical sky (HS). The HS-RHI scan strategy is repeated every 30 min to provide a static view of the cloud conditions around the SACR location. Between HS-RHI scan strategies other scan strategies are introduced depending on the cloud conditions. The SACRs are pointing vertically in the case of measurable precipitation at the ground. The radar reflectivities are corrected for water vapor attenuation and non-meteorological detection are removed. A hydrometeor detection mask is introduced based on the difference of cloud and noise statistics is discussed.

  1. A novel approach for introducing cloud spatial structure into cloud

    Office of Scientific and Technical Information (OSTI)

    radiative transfer parameterizations (Journal Article) | SciTech Connect A novel approach for introducing cloud spatial structure into cloud radiative transfer parameterizations Citation Details In-Document Search Title: A novel approach for introducing cloud spatial structure into cloud radiative transfer parameterizations Authors: Huang, Dong ; Liu, Yangang Publication Date: 2014-12-18 OSTI Identifier: 1222378 Grant/Contract Number: ASR; FASTER Type: Published Article Journal Name:

  2. Biogenic Aerosols - Effects on Climate and Clouds. Cloud Optical Depth

    Office of Scientific and Technical Information (OSTI)

    (COD) Sensor Three-Waveband Spectrally-Agile Technique (TWST) Field Campaign Report (Technical Report) | SciTech Connect Biogenic Aerosols - Effects on Climate and Clouds. Cloud Optical Depth (COD) Sensor Three-Waveband Spectrally-Agile Technique (TWST) Field Campaign Report Citation Details In-Document Search Title: Biogenic Aerosols - Effects on Climate and Clouds. Cloud Optical Depth (COD) Sensor Three-Waveband Spectrally-Agile Technique (TWST) Field Campaign Report This report describes

  3. Cloud Based Applications and Platforms (Presentation)

    SciTech Connect (OSTI)

    Brodt-Giles, D.

    2014-05-15

    Presentation to the Cloud Computing East 2014 Conference, where we are highlighting our cloud computing strategy, describing the platforms on the cloud (including Smartgrid.gov), and defining our process for implementing cloud based applications.

  4. Opaque cloud detection

    DOE Patents [OSTI]

    Roskovensky, John K.

    2009-01-20

    A method of detecting clouds in a digital image comprising, for an area of the digital image, determining a reflectance value in at least three discrete electromagnetic spectrum bands, computing a first ratio of one reflectance value minus another reflectance value and the same two values added together, computing a second ratio of one reflectance value and another reflectance value, choosing one of the reflectance values, and concluding that an opaque cloud exists in the area if the results of each of the two computing steps and the choosing step fall within three corresponding predetermined ranges.

  5. ARM - Measurement - Images of Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Images of Clouds Digital images of cloud scenes (various formats) from satellite, aircraft, and ground-based...

  6. Scanning ARM Cloud Radar Handbook

    SciTech Connect (OSTI)

    Widener, K; Bharadwaj, N; Johnson, K

    2012-06-18

    The scanning ARM cloud radar (SACR) is a polarimetric Doppler radar consisting of three different radar designs based on operating frequency. These are designated as follows: (1) X-band SACR (X-SACR); (2) Ka-band SACR (Ka-SACR); and (3) W-band SACR (W-SACR). There are two SACRs on a single pedestal at each site where SACRs are deployed. The selection of the operating frequencies at each deployed site is predominantly determined by atmospheric attenuation at the site. Because RF attenuation increases with atmospheric water vapor content, ARM's Tropical Western Pacific (TWP) sites use the X-/Ka-band frequency pair. The Southern Great Plains (SGP) and North Slope of Alaska (NSA) sites field the Ka-/W-band frequency pair. One ARM Mobile Facility (AMF1) has a Ka/W-SACR and the other (AMF2) has a X/Ka-SACR.

  7. ARM Cloud Aerosol Precipitation Experiment (ACAPEX) Science Plan (Program

    Office of Scientific and Technical Information (OSTI)

    Document) | SciTech Connect ARM Cloud Aerosol Precipitation Experiment (ACAPEX) Science Plan Citation Details In-Document Search Title: ARM Cloud Aerosol Precipitation Experiment (ACAPEX) Science Plan The western U.S. receives precipitation predominantly during the cold season when storms approach from the Pacific Ocean. The snowpack that accumulates during winter storms provides about 70-90% of water supply for the region. Understanding and modeling the fundamental processes that govern the

  8. Global Distribution and Climate Forcing of Marine Organic Aerosol - Part 2: Effects on Cloud Properties and Radiative Forcing

    SciTech Connect (OSTI)

    Gantt, Brett; Xu, Jun; Meskhidze, N.; Zhang, Yang; Nenes, Athanasios; Ghan, Steven J.; Liu, Xiaohong; Easter, Richard C.; Zaveri, Rahul A.

    2012-07-25

    A series of simulations with the Community Atmosphere Model version 5 (CAM5) with a 7-mode Modal Aerosol Model were conducted to assess the changes in cloud microphysical properties and radiative forcing resulting from marine organic aerosols. Model simulations show that the anthropogenic aerosol indirect forcing (AIF) predicted by CAM5 is decreased in absolute magnitude by up to 0.09 Wm{sup -2} (7 %) when marine organic aerosols are included. Changes in the AIF from marine organic aerosols are associated with small global increases in low-level incloud droplet number concentration and liquid water path of 1.3 cm{sup -3} (1.5 %) and 0.22 gm{sup -2} (0.5 %), respectively. Areas especially sensitive to changes in cloud properties due to marine organic aerosol include the Southern Ocean, North Pacific Ocean, and North Atlantic Ocean, all of which are characterized by high marine organic emission rates. As climate models are particularly sensitive to the background aerosol concentration, this small but non-negligible change in the AIF due to marine organic aerosols provides a notable link for ocean-ecosystem marine low-level cloud interactions and may be a candidate for consideration in future earth system models.

  9. Statistical characteristics of cloud variability. Part 2: Implication for parameterizations of microphysical and radiative transfer processes in climate models

    SciTech Connect (OSTI)

    Huang, Dong; Liu, Yangang

    2014-09-27

    The effects of subgrid cloud variability on grid-average microphysical rates and radiative fluxes are examined by use of long-term retrieval products at the Tropical West Pacific, Southern Great Plains, and North Slope of Alaska sites of the Department of Energy's Atmospheric Radiation Measurement program. Four commonly used distribution functions, the truncated Gaussian, Gamma, lognormal, and Weibull distributions, are constrained to have the same mean and standard deviation as observed cloud liquid water content. The probability density functions are then used to upscale relevant physical processes to obtain grid-average process rates. It is found that the truncated Gaussian representation results in up to 30% mean bias in autoconversion rate, whereas the mean bias for the lognormal representation is about 10%. The Gamma and Weibull distribution function performs the best for the grid-average autoconversion rate with the mean relative bias less than 5%. For radiative fluxes, the lognormal and truncated Gaussian representations perform better than the Gamma and Weibull representations. The results show that the optimal choice of subgrid cloud distribution function depends on the nonlinearity of the process of interest, and thus, there is no single distribution function that works best for all parameterizations. Examination of the scale (window size) dependence of the mean bias indicates that the bias in grid-average process rates monotonically increases with increasing window sizes, suggesting the increasing importance of subgrid variability with increasing grid sizes.

  10. Statistical characteristics of cloud variability. Part 2: Implication for parameterizations of microphysical and radiative transfer processes in climate models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Dong; Liu, Yangang

    2014-09-27

    The effects of subgrid cloud variability on grid-average microphysical rates and radiative fluxes are examined by use of long-term retrieval products at the Tropical West Pacific, Southern Great Plains, and North Slope of Alaska sites of the Department of Energy's Atmospheric Radiation Measurement program. Four commonly used distribution functions, the truncated Gaussian, Gamma, lognormal, and Weibull distributions, are constrained to have the same mean and standard deviation as observed cloud liquid water content. The probability density functions are then used to upscale relevant physical processes to obtain grid-average process rates. It is found that the truncated Gaussian representation results inmoreup to 30% mean bias in autoconversion rate, whereas the mean bias for the lognormal representation is about 10%. The Gamma and Weibull distribution function performs the best for the grid-average autoconversion rate with the mean relative bias less than 5%. For radiative fluxes, the lognormal and truncated Gaussian representations perform better than the Gamma and Weibull representations. The results show that the optimal choice of subgrid cloud distribution function depends on the nonlinearity of the process of interest, and thus, there is no single distribution function that works best for all parameterizations. Examination of the scale (window size) dependence of the mean bias indicates that the bias in grid-average process rates monotonically increases with increasing window sizes, suggesting the increasing importance of subgrid variability with increasing grid sizes.less

  11. First observations of tracking clouds using scanning ARM cloud radars

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Borque, Paloma; Giangrande, Scott; Kollias, Pavlos

    2014-12-01

    Tracking clouds using scanning cloud radars can help to document the temporal evolution of cloud properties well before large drop formation (‘‘first echo’’). These measurements complement cloud and precipitation tracking using geostationary satellites and weather radars. Here, two-dimensional (2-D) Along-Wind Range Height Indicator (AW-RHI) observations of a population of shallow cumuli (with and without precipitation) from the 35-GHz scanning ARM cloud radar (SACR) at the DOE Atmospheric Radiation Measurements (ARM) program Southern Great Plains (SGP) site are presented. Observations from the ARM SGP network of scanning precipitation radars are used to provide the larger scale context of the cloud fieldmore » and to highlight the advantages of the SACR to detect the numerous, small, non-precipitating cloud elements. A new Cloud Identification and Tracking Algorithm (CITA) is developed to track cloud elements. In CITA, a cloud element is identified as a region having a contiguous set of pixels exceeding a preset reflectivity and size threshold. The high temporal resolution of the SACR 2-D observations (30 sec) allows for an area superposition criteria algorithm to match cloud elements at consecutive times. Following CITA, the temporal evolution of cloud element properties (number, size, and maximum reflectivity) is presented. The vast majority of the designated elements during this cumulus event were short-lived non-precipitating clouds having an apparent life cycle shorter than 15 minutes. The advantages and disadvantages of cloud tracking using an SACR are discussed.« less

  12. A 10 Year Climatology of Arctic Cloud Fraction and Radiative Forcing at Barrow, Alaska

    SciTech Connect (OSTI)

    Dong, Xiquan; Xi, Baike; Crosby, Kathryn; Long, Charles N.; Stone, R. S.; Shupe, Matthew D.

    2010-09-15

    A 10-yr record of Arctic cloud fraction and surface radiation budget has been generated using data collected from June 1998 to May 2008 at the Atmospheric Radiation Measurement (ARM) North Slope of Alaska (NSA) site and the nearby NOAA Barrow Observatory (BRW). The record includes the seasonal variations of cloud fraction (CF), cloud liquid water path (LWP), precipitable water vapor (PWV), surface albedo, shortwave (SW) and longwave (LW) fluxes and cloud radative forcings (CRFs), as well as their decadal variations. Values of CF derived from different instruments and methods agree well, having an annual average of ~0.74. Cloudiness increases from March to May, remains high (~0.8-0.9) from May to October, and then decreases over winter. More clouds and higher LWP and PWV occurred during the warm season (May-October) than the cold season (November-April). These results are strongly associated with southerly flow which transports warm, moist air masses to Barrow from the North Pacific and over area of Alaska already free of snow during the warm season and with a dipole pattern of pressure in which a high is centered over the Beaufort Sea and low over the Aleutians during the cold season. The monthly means of estimated clear-sky and measured allsky SW-down and LW-down fluxes at the two facilities are almost identical with the annual mean differences less than 1.6 W m-2. The downwelling and upwelling LW fluxes remain almost constant from January to March, then increase from March and peak during July-August. SW-down fluxes are primarily determined by seasonal changes in the intensity and duration of insolation over Northern Alaska, and are also strongly dependent on cloud fraction and optical depth, and surface albedo. The monthly variations of NET CRF generally follow the cycle of SW CRF, modulated by LW effects. On annual average, the negative SW CRF and positive LW CRF tend to cancel, resulting in annual average NET CRF of 2-4.5 Wm-2. Arctic clouds have a 3 net warming effect on the surface throughout the year, with exception of the snow-free period from middle June to middle September when there tends to be a cooling effect. The daily average surface albedos agree well at the two sites remaining high (>0.8) until late May, dropping below 0.2 after the snow melts around June and increasing during autumn once snow begins to accumulate. On the basis of long-term regression analyses CF has decreased by about 0.048 while temperature has risen by ?1.1 K over the 10-yr period, which can be characterized by tendencies of warming mainly during December and April. With regard to the 2007 record minimum Arctic ice extent, this study provides additional empirical evidence that decreased cloud cover and increased SW-down flux during summer contributed to anomalous ice melt in the region north of Barrow. At Barrow, average June-August CF decreased by 0.062 in 2007 from the 10-yr mean, while SW-down and NET fluxes increased by 28.4 Wm-2 and 11.3 Wm-2, respectively. The increase in the NET radiative flux during summer 2007 most likely contributed to an increase in surface air temperature of 1.6 K.

  13. LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Thornton, J.D.

    1957-12-31

    This patent relates to liquid-liquid extraction columns having a means for pulsing the liquid in the column to give it an oscillatory up and down movement, and consists of a packed column, an inlet pipe for the dispersed liquid phase and an outlet pipe for the continuous liquid phase located in the direct communication with the liquid in the lower part of said column, an inlet pipe for the continuous liquid phase and an outlet pipe for the dispersed liquid phase located in direct communication with the liquid in the upper part of said column, a tube having one end communicating with liquid in the lower part of said column and having its upper end located above the level of said outlet pipe for the dispersed phase, and a piston and cylinder connected to the upper end of said tube for applying a pulsating pneumatic pressure to the surface of the liquid in said tube so that said surface rises and falls in said tube.

  14. ARM - Measurement - Liquid water content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    : PNNL's Atmospheric Remote Sensing Laboratory PARTIMG : Particle imager PDI : Phase Doppler Interferometer RLPROF : Raman LIDAR Vertical Profiles TDLAS : Tunable Diode Laser...

  15. Assessing Cloud Spatial and Vertical Distribution with Infrared Cloud Analyzer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Spatial and Vertical Distribution with Infrared Cloud Analyzer I. Genkova and C. N. Long Pacific Northwest National Laboratory Richland, Washington T. Besnard ATMOS SARL Le Mans, France D. Gillotay Institute d'Aeronomie Spatiale de Belgique Brussels, Belgium Introduction In the effort to resolve uncertainties about global climate change, the Atmospheric Radiation Measurement (ARM) Program (www.arm.gov) is improving the treatment of cloud radiative forcing and feedbacks in general

  16. Cloud Computing Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel ... SubTER Carbon Sequestration Program Leadership EnergyWater Nexus EnergyWater History ...

  17. Evaluating cloud retrieval algorithms with the ARM BBHRP framework

    SciTech Connect (OSTI)

    Mlawer,E.; Dunn,M.; Mlawer, E.; Shippert, T.; Troyan, D.; Johnson, K. L.; Miller, M. A.; Delamere, J.; Turner, D. D.; Jensen, M. P.; Flynn, C.; Shupe, M.; Comstock, J.; Long, C. N.; Clough, S. T.; Sivaraman, C.; Khaiyer, M.; Xie, S.; Rutan, D.; Minnis, P.

    2008-03-10

    Climate and weather prediction models require accurate calculations of vertical profiles of radiative heating. Although heating rate calculations cannot be directly validated due to the lack of corresponding observations, surface and top-of-atmosphere measurements can indirectly establish the quality of computed heating rates through validation of the calculated irradiances at the atmospheric boundaries. The ARM Broadband Heating Rate Profile (BBHRP) project, a collaboration of all the working groups in the program, was designed with these heating rate validations as a key objective. Given the large dependence of radiative heating rates on cloud properties, a critical component of BBHRP radiative closure analyses has been the evaluation of cloud microphysical retrieval algorithms. This evaluation is an important step in establishing the necessary confidence in the continuous profiles of computed radiative heating rates produced by BBHRP at the ARM Climate Research Facility (ACRF) sites that are needed for modeling studies. This poster details the continued effort to evaluate cloud property retrieval algorithms within the BBHRP framework, a key focus of the project this year. A requirement for the computation of accurate heating rate profiles is a robust cloud microphysical product that captures the occurrence, height, and phase of clouds above each ACRF site. Various approaches to retrieve the microphysical properties of liquid, ice, and mixed-phase clouds have been processed in BBHRP for the ACRF Southern Great Plains (SGP) and the North Slope of Alaska (NSA) sites. These retrieval methods span a range of assumptions concerning the parameterization of cloud location, particle density, size, shape, and involve different measurement sources. We will present the radiative closure results from several different retrieval approaches for the SGP site, including those from Microbase, the current 'reference' retrieval approach in BBHRP. At the NSA, mixed-phase clouds and cloud with a low optical depth are prevalent; the radiative closure studies using Microbase demonstrated significant residuals. As an alternative to Microbase at NSA, the Shupe-Turner cloud property retrieval algorithm, aimed at improving the partitioning of cloud phase and incorporating more constrained, conditional microphysics retrievals, also has been evaluated using the BBHRP data set.

  18. TURBULENCE DECAY AND CLOUD CORE RELAXATION IN MOLECULAR CLOUDS

    SciTech Connect (OSTI)

    Gao, Yang; Law, Chung K.; Xu, Haitao

    2015-02-01

    The turbulent motion within molecular clouds is a key factor controlling star formation. Turbulence supports molecular cloud cores from evolving to gravitational collapse and hence sets a lower bound on the size of molecular cloud cores in which star formation can occur. On the other hand, without a continuous external energy source maintaining the turbulence, such as in molecular clouds, the turbulence decays with an energy dissipation time comparable to the dynamic timescale of clouds, which could change the size limits obtained from Jean's criterion by assuming constant turbulence intensities. Here we adopt scaling relations of physical variables in decaying turbulence to analyze its specific effects on the formation of stars. We find that the decay of turbulence provides an additional approach for Jeans' criterion to be achieved, after which gravitational infall governs the motion of the cloud core. This epoch of turbulence decay is defined as cloud core relaxation. The existence of cloud core relaxation provides a more complete understanding of the effect of the competition between turbulence and gravity on the dynamics of molecular cloud cores and star formation.

  19. Tropical Cloud Properties and Radiative Heating Profiles

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mather, James

    2008-01-15

    We have generated a suite of products that includes merged soundings, cloud microphysics, and radiative fluxes and heating profiles. The cloud microphysics is strongly based on the ARM Microbase value added product (Miller et al., 2003). We have made a few changes to the microbase parameterizations to address issues we observed in our initial analysis of the tropical data. The merged sounding product is not directly related to the product developed by ARM but is similar in that it uses the microwave radiometer to scale the radiosonde column water vapor. The radiative fluxes also differ from the ARM BBHRP (Broadband Heating Rate Profile) product in terms of the radiative transfer model and the sampling interval.

  20. Tropical Cloud Properties and Radiative Heating Profiles

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mather, James

    We have generated a suite of products that includes merged soundings, cloud microphysics, and radiative fluxes and heating profiles. The cloud microphysics is strongly based on the ARM Microbase value added product (Miller et al., 2003). We have made a few changes to the microbase parameterizations to address issues we observed in our initial analysis of the tropical data. The merged sounding product is not directly related to the product developed by ARM but is similar in that it uses the microwave radiometer to scale the radiosonde column water vapor. The radiative fluxes also differ from the ARM BBHRP (Broadband Heating Rate Profile) product in terms of the radiative transfer model and the sampling interval.

  1. Holistic Interactions of Shallow Clouds,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems Research Instrumentation HI-SCALE will utilize the ARM Aerial Facility's Gulfstream-159 (G-1), as well as ground instrumentation located at the SGP megasite. 7e G-1 will complete transects over the site at multiple altitudes within the boundary layer, within clouds, and above clouds. 7e payload on the G-1 includes: * high frequency meteorological and radiation (both up and downwelling) measurements that also permit computing

  2. ARM - Measurement - Cloud top height

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RUC : Rapid Update Cycle Model Data Field Campaign Instruments CO2LIDAR : Carbon Dioxide Doppler Lidar MPLCMASK : Cloud mask from Micropulse Lidar VARANAL : Constrained...

  3. TWP Island Cloud Trail Studies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a key to understanding boundary layer cloud formation in the tropics. Except during El Nio periods, Nauru represents a divergent region of the ocean upwind from the...

  4. ARM - Measurement - Cloud optical depth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TWST : Three Waveband Spectrally-agile Technique Sensor WRF-CHEM : Weather Research and Forecasting (WRF) Model Output Value-Added Products LBTM-MINNIS : Minnis Cloud Products...

  5. ARM - Measurement - Cloud condensation nuclei

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AOS : Aerosol Observing System CCN : Cloud Condensation Nuclei Particle Counter TDMA : Tandem Differential Mobility Analyzer Field Campaign Instruments AMT : Aerosol Modeling...

  6. LIQUID TARGET

    DOE Patents [OSTI]

    Martin, M.D.; Salsig, W.W. Jr.

    1959-01-13

    A liquid handling apparatus is presented for a liquid material which is to be irradiated. The apparatus consists essentially of a reservoir for the liquid, a target element, a drain tank and a drain lock chamber. The target is in the form of a looped tube, the upper end of which is adapted to be disposed in a beam of atomic particles. The lower end of the target tube is in communication with the liquid in the reservoir and a means is provided to continuously circulate the liquid material to be irradiated through the target tube. Means to heat the reservoir tank is provided in the event that a metal is to be used as the target material. The apparatus is provided with suitable valves and shielding to provide maximum safety in operation.

  7. Widget:LogoCloud | Open Energy Information

    Open Energy Info (EERE)

    LogoCloud Jump to: navigation, search This widget adds css selectors and javascript for the Template:LogoCloud. For example: Widget:LogoCloud Retrieved from "http:...

  8. Zenith Radiance Retrieval of Cloud Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    retrievals of cloud properties from the AMF/COPS campaign Preliminary retrievals of cloud properties from the AMF/COPS campaign Christine Chiu, UMBC/JCET Alexander Marshak, GSFC Yuri Knyazikhin, Boston University Warren Wiscombe, GSFC Christine Chiu, UMBC/JCET Alexander Marshak, GSFC Yuri Knyazikhin, Boston University Warren Wiscombe, GSFC The cloud optical properties of interest are: The cloud optical properties of interest are: * Cloud optical depth τ - the great unknown * Radiative cloud

  9. Clouds Environmental Ltd | Open Energy Information

    Open Energy Info (EERE)

    Clouds Environmental Ltd Jump to: navigation, search Name: Clouds Environmental Ltd Place: Portsmouth, United Kingdom Zip: PO3 5EG Product: Independent consultancy specialising in...

  10. Cloud Properties Working Group Break Out Session

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    relation to fall speeds, implications for previous measurements. (Mitchell) Q8: Geoengineering of cirrus clouds (Mitchell) Q9: Cold cloud phase partitioning: Roles of...

  11. Microphysical Consequences of the Spatial Distribution of Ice Nucleation in Mixed-Phase Stratiform Clouds

    SciTech Connect (OSTI)

    Yang, Fan; Ovchinnikov, Mikhail; Shaw, Raymond A.

    2014-07-28

    Mixed-phase stratiform clouds can persist even with steady ice precipitation fluxes, and the origin and microphysical properties of the ice crystals are of interest. Vapor deposition growth and sedimentation of ice particles along with a uniform volume source of ice nucleation, leads to a power law relation between ice water content wi and ice number concentration ni with exponent 2.5. The result is independent of assumptions about the vertical velocity structure of the cloud and is therefore more general than the related expression of Yang et al. [2013]. The sensitivity of the wi-ni relationship to the spatial distribution of ice nucleation is confirmed by Lagrangian tracking and ice growth with cloud-volume, cloud-top, and cloud-base sources of ice particles through a time-dependent cloud field. Based on observed wi and ni from ISDAC, a lower bound of 0.006 m^3/s is obtained for the ice crystal formation rate.

  12. Minimalist Model of Ice Microphysics in Mixed-phase Stratiform Clouds

    SciTech Connect (OSTI)

    Yang, F.; Ovchinnikov, Mikhail; Shaw, Raymond A.

    2013-07-28

    The question of whether persistent ice crystal precipitation from super cooled layer clouds can be explained by time-dependent, stochastic ice nucleation is explored using an approximate, analytical model, and a large-eddy simulation (LES) cloud model. The updraft velocity in the cloud defines an accumulation zone, where small ice particles cannot fall out until they are large enough, which will increase the residence time of ice particles in the cloud. Ice particles reach a quasi-steady state between growth by vapor deposition and fall speed at cloud base. The analytical model predicts that ice water content (wi) has a 2.5 power law relationship with ice number concentration ni. wi and ni from a LES cloud model with stochastic ice nucleation also confirm the 2.5 power law relationship. The prefactor of the power law is proportional to the ice nucleation rate, and therefore provides a quantitative link to observations of ice microphysical properties.

  13. The role of ice nuclei recycling in the maintenance of cloud ice in Arctic mixed-phase stratocumulus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Solomon, A.; Feingold, G.; Shupe, M. D.

    2015-09-25

    This study investigates the maintenance of cloud ice production in Arctic mixed-phase stratocumulus in large eddy simulations that include a prognostic ice nuclei (IN) formulation and a diurnal cycle. Balances derived from a mixed-layer model and phase analyses are used to provide insight into buffering mechanisms that maintain ice in these cloud systems. We find that, for the case under investigation, IN recycling through subcloud sublimation considerably prolongs ice production over a multi-day integration. This effective source of IN to the cloud dominates over mixing sources from above or below the cloud-driven mixed layer. Competing feedbacks between dynamical mixing andmore » recycling are found to slow the rate of ice lost from the mixed layer when a diurnal cycle is simulated. The results of this study have important implications for maintaining phase partitioning of cloud ice and liquid that determine the radiative forcing of Arctic mixed-phase clouds.« less

  14. The role of ice nuclei recycling in the maintenance of cloud ice in Arctic mixed-phase stratocumulus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Solomon, A.; Feingold, G.; Shupe, M. D.

    2015-04-21

    This study investigates the maintenance of cloud ice production in Arctic mixed phase stratocumulus in large-eddy simulations that include a prognostic ice nuclei (IN) formulation and a diurnal cycle. Balances derived from a mixed-layer model and phase analyses are used to provide insight into buffering mechanisms that maintain ice in these cloud systems. We find that for the case under investigation, IN recycling through subcloud sublimation considerably prolongs ice production over a multi-day integration. This effective source of IN to the cloud dominates over mixing sources from above or below the cloud-driven mixed layer. Competing feedbacks between dynamical mixing andmore » recycling are found to slow the rate of ice lost from the mixed layer when a diurnal cycle is simulated. The results of this study have important implications for maintaining phase partitioning of cloud ice and liquid that determine the radiative forcing of Arctic mixed-phase clouds.« less

  15. Polluting of Winter Convective Clouds upon Transition from Ocean Inland Over Central California: Contrasting Case Studies

    SciTech Connect (OSTI)

    Rosenfeld, Daniel; Chemke, Rei; Prather, Kimberly; Suski, Kaitlyn; Comstock, Jennifer M.; Schmid, Beat; Tomlinson, Jason M.; Jonsson, Haf

    2014-01-01

    In-situ aircraft measurements of aerosol chemical and cloud microphysical properties were conducted during the CalWater campaign in February and March 2011 over the Sierra Nevada Mountains and the coastal waters of central California. The main objective was to elucidate the impacts of aerosol properties on clouds and precipitation forming processes. In order to accomplish this, we compared contrasting cases of clouds that ingested aerosols from different sources. The results showed that clouds containing pristine oceanic air had low cloud drop concentrations and started to develop rain 500 m above their base. This occurred both over the ocean and over the Sierra Nevada, mainly in the early morning when the radiatively cooled stable continental boundary layer was decoupled from the cloud base. Supercooled rain dominated the precipitation that formed in growing convective clouds in the pristine air, up to the -21C isotherm level. A contrasting situation was documented in the afternoon over the foothills of the Sierra Nevada, when the clouds ingested high pollution aerosol concentrations produced in the Central Valley. This led to slow growth of the cloud drop effective radius with height and suppressed and even prevented the initiation of warm rain while contributing to the development of ice hydrometeors in the form of graupel. Our results show that cloud condensation and ice nuclei were the limiting factors that controlled warm rain and ice processes, respectively, while the unpolluted clouds in the same air mass produced precipitation quite efficiently. These findings provide the motivation for deeper investigations into the nature of the aerosols seeding clouds.

  16. Evaluation of high-level clouds in cloud resolving model simulations with

    Office of Scientific and Technical Information (OSTI)

    ARM and KWAJEX observations (Journal Article) | SciTech Connect Evaluation of high-level clouds in cloud resolving model simulations with ARM and KWAJEX observations Citation Details In-Document Search Title: Evaluation of high-level clouds in cloud resolving model simulations with ARM and KWAJEX observations In this paper, we evaluate high-level clouds in a cloud resolving model during two convective cases, ARM9707 and KWAJEX. The simulated joint histograms of cloud occurrence and radar

  17. Continental Liquid-phase Stratus Clouds at SGP: Meteorological...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Relationship to Adiabacity Kim, Byung-Gon Kangnung National University Schwartz, Stephen Brookhaven National Laboratory Miller, Mark Brookhaven National Laboratory Min,...

  18. Scale#aware Parameterization of Liquid Cloud Inhomogeneity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a fixed parametric distribution such as what was used in the Community Earth System Model (CESM). The parameters often need to be tuned for different resolutions of the...

  19. Advantages of liquid fluoride thorium reactor in comparison with light

    Office of Scientific and Technical Information (OSTI)

    water reactor (Journal Article) | SciTech Connect Advantages of liquid fluoride thorium reactor in comparison with light water reactor Citation Details In-Document Search Title: Advantages of liquid fluoride thorium reactor in comparison with light water reactor Liquid Fluoride Thorium Reactor (LFTR) is an innovative design for the thermal breeder reactor that has important potential benefits over the traditional reactor design. LFTR is fluoride based liquid fuel, that use the thorium

  20. Study concerning the utilization of the ocean spreading center environment for the conversion of biomass to a liquid fuel. (Includes Appendix A: hydrothermal petroleum genesis). [Supercritical water

    SciTech Connect (OSTI)

    Steverson, M.; Stormberg, G.

    1985-01-01

    This document contains a report on the feasibility of utilizing energy obtained from ocean spreading centers as process heat for the conversion of municipal solid wastes to liquid fuels. The appendix contains a paper describing hydrothermal petroleum genesis. Both have been indexed separately for inclusion in the Energy Data Base. (DMC)

  1. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud optical depth, on a variety of scales ranging from tens of meters to tens of kilometers, even for relatively uniform liquid water clouds. Retrievals of cloud effective...

  2. ionic-liquid pretreatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ionic-liquid pretreatment - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  3. cloud | OpenEI Community

    Open Energy Info (EERE)

    - 13:42 How cleantech-as-a-service will drive renewable energy adoption 2015 adoption Big Data clean tech clean-tech cleantech cleantech forum cleantech-as-a-service cloud...

  4. ARM - Measurement - Cloud ice particle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ice particle ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud ice particle...

  5. Millimeter Wave Cloud Radar (MMCR) Handbook

    SciTech Connect (OSTI)

    KB Widener; K Johnson

    2005-01-30

    The millimeter cloud radar (MMCR) systems probe the extent and composition of clouds at millimeter wavelengths. The MMCR is a zenith-pointing radar that operates at a frequency of 35 GHz. The main purpose of this radar is to determine cloud boundaries (e.g., cloud bottoms and tops). This radar will also report radar reflectivity (dBZ) of the atmosphere up to 20 km. The radar possesses a doppler capability that will allow the measurement of cloud constituent vertical velocities.

  6. Refereed Publications:

    Office of Scientific and Technical Information (OSTI)

    (from Brown, 2007 thesis) The cloud water and ice content has been analyzed with respect to large scale distribution of liquid water, iceliquid water partitioning in cloud, ...

  7. Perturbed Physics Ensemble Simulations of Cirrus on the Cloud System-resolving Scale

    SciTech Connect (OSTI)

    Muhlbauer, Andreas; Berry, Elizabeth; Comstock, Jennifer M.; Mace, Gerald G.

    2014-04-16

    In this study, the effect of uncertainties in the parameterization of ice microphysical processes and initial conditions on the variability of cirrus microphysical and radiative properties are investigated in a series of cloud system-resolving perturbed physics ensemble (PPE) and initial condition ensemble (ICE) simulations. Three cirrus cases representative of mid-latitude, subtropical and tropical cirrus are examined. It is found that the variability in cirrus properties induced by perturbing uncertain parameters in ice microphysics parameterizations outweighs the variability induced by perturbing the initial conditions in midlatitude and subtropical cirrus. However, in tropical anvil cirrus the variability in the PPE and ICE simulations is about the same order of magnitude. The cirrus properties showing the largest sensitivity are ice water content (IWC) and cloud thickness whereas the averaged high cloud cover is only marginally affected. Changes in cirrus ice water path and outgoing longwave radiation are controlled primarily by changes in IWC and cloud thickness but not by changes is the averaged high cloud cover. The change in the vertical distribution of cloud fraction and cloud thickness is caused by changes in cirrus cloud base whereas cloud top is not sensitive to either perturbed physics or perturbed initial conditions. In all cirrus cases, the top three parameters controlling the microphysical variability and radiative impact of cirrus clouds are ice fall speeds, ice autoconversion size thresholds and heterogeneous ice nucleation. Changes in the ice deposition coefficient do not affect the ice water path and outgoing longwave radiation. Similarly, changes in the number concentration of aerosols available for homogeneous freezing have virtually no effect on the microphysical and radiative properties of midlatitude and subtropical cirrus but only little impact on tropical anvil cirrus. Overall, the sensitivity of cirrus microphysical and radiative properties to uncertainties in ice microphysics is largest for midlatitude cirrus and smallest for tropical anvil cirrus.

  8. Using Solar Hot Water to Address Piping Heat Losses in Multifamily...

    Office of Scientific and Technical Information (OSTI)

    Subject: residential; Residential Buildings; ARBI; Building America; TRNSYS; multifamily; domestic hot water; solar water heater; recirculation Word Cloud More Like This Full Text ...

  9. Determination of Ice Water Path Over the ARM SGP Using Combined...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determination of Ice Water Path Over the ARM SGP Using Combined Surface and Satellite ... Global information of cloud ice water path (IWP) is urgently needed for testing ...

  10. Evaluation of high-level clouds in cloud resolving model simulations...

    Office of Scientific and Technical Information (OSTI)

    Evaluation of high-level clouds in cloud resolving model simulations with ARM and KWAJEX observations: HIGH CLOUD IN CRM Citation Details In-Document Search This content will ...

  11. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    2008-01-15

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  12. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  13. Evaluation of high-level clouds in cloud resolving model simulations...

    Office of Scientific and Technical Information (OSTI)

    The simulated joint histograms of cloud occurrence and radar reflectivity compare well with cloud radar and satellite observations when using a two-moment microphysics scheme. ...

  14. Retrievals of Cloud Fraction and Cloud Albedo from Surface-based...

    Office of Scientific and Technical Information (OSTI)

    Retrievals of Cloud Fraction and Cloud Albedo from Surface-based Shortwave Radiation Measurements: A Comparison of 16 Year Measurements Citation Details In-Document Search Title: ...

  15. Hybrid Rotor Compression for Multiphase and Liquids-Rich Wellhead

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    but also allows for compression of wet gas, or gas that contains liquid content. At many natural gas wellheads, liquids-typically heavier hydrocarbons and water-are present in the...

  16. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  17. Modification and Application of a New Method for Retrieving Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of a New Method for Retrieving Water-Cloud Microphysics Vertical Profile F.-L Chang and Z. Li Earth System Science Interdisciplinary Center University of Maryland College...

  18. Understanding and Improving CRM and GCM Simulations of Cloud Systems with ARM Observations

    SciTech Connect (OSTI)

    Wu, Xiaoqing

    2014-02-25

    The works supported by this ASR project lay the solid foundation for improving the parameterization of convection and clouds in the NCAR CCSM and the climate simulations. We have made a significant use of CRM simulations and ARM observations to produce thermodynamically and dynamically consistent multi-year cloud and radiative properties; improve the GCM simulations of convection, clouds and radiative heating rate and fluxes using the ARM observations and CRM simulations; and understand the seasonal and annual variation of cloud systems and their impacts on climate mean state and variability. We conducted multi-year simulations over the ARM SGP site using the CRM with multi-year ARM forcing data. The statistics of cloud and radiative properties from the long-term CRM simulations were compared and validated with the ARM measurements and value added products (VAP). We evaluated the multi-year climate simulations produced by the GCM with the modified convection scheme. We used multi-year ARM observations and CRM simulations to validate and further improve the trigger condition and revised closure assumption in NCAR GCM simulations that demonstrate the improvement of climate mean state and variability. We combined the improved convection scheme with the mosaic treatment of subgrid cloud distributions in the radiation scheme of the GCM. The mosaic treatment of cloud distributions has been implemented in the GCM with the original convection scheme and enables the use of more realistic cloud amounts as well as cloud water contents in producing net radiative fluxes closer to observations. A physics-based latent heat (LH) retrieval algorithm was developed by parameterizing the physical linkages of observed hydrometeor profiles of cloud and precipitation to the major processes related to the phase change of atmospheric water.

  19. Atmospheric Radiation Measurement (ARM) Data from Steamboat Springs, Colorado, for the Storm Peak Laboratory Cloud Property Validation Experiment (STORMVEX)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    In October 2010, the initial deployment of the second ARM Mobile Facility (AMF2) took place at Steamboat Springs, Colorado, for the Storm Peak Laboratory Cloud Property Validation Experiment (STORMVEX). The objective of this field campaign was to obtain data about liquid and mixed-phase clouds using AMF2 instruments in conjunction with Storm Peak Laboratory (located at an elevation of 3220 meters on Mt. Werner), a cloud and aerosol research facility operated by the Desert Research Institute. STORMVEX datasets are freely available for viewing and download. Users are asked to register with the ARM Archive; the user's email address is used from that time forward as the login name.

  20. RACORO Extended-Term Aircraft Observations of Boundary-Layer Clouds

    SciTech Connect (OSTI)

    Vogelmann, A. M.; McFarquhar, Greg; Ogren, John A.; Turner, David D.; Comstock, Jennifer M.; Feingold, G.; Long, Charles N.; Jonsson, Haf; Bucholtz, Anthony; Collins, Donald R.; Diskin, G. S.; Gerber, H.; Lawson, Paul; Woods, Roy; Andrews, Elizabeth; Yang, Hee-Jung; Chiu, Christine J.; Hartsock, Daniel; Hubbe, John M.; Lo, Chaomei; Marshak, A.; Monroe, Justin; McFarlane, Sally A.; Schmid, Beat; Tomlinson, Jason M.; Toto, Tami

    2012-06-30

    A first-of-a-kind, extended-term cloud aircraft campaign was conducted to obtain an in-situ statistical characterization of boundary-layer clouds needed to investigate cloud processes and refine retrieval algorithms. Coordinated by the Atmospheric Radiation Measurement (ARM) Aerial Facility (AAF), the Routine AAF Clouds with Low Optical Water Depths (CLOWD) Optical Radiative Observations (RACORO) field campaign operated over the ARM Southern Great Plains (SGP) site from 22 January to 30 June 2009, collecting 260 h of data during 59 research flights. A comprehensive payload aboard the Center for Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS) Twin Otter aircraft measured cloud microphysics, solar and thermal radiation, aerosol properties, and atmospheric state parameters. Proximity to the SGP's extensive complement of surface measurements provides ancillary data that supports modeling studies and enables evaluating a variety of surface retrieval algorithms. The five-month duration enabled sampling a range of conditions associated with the seasonal transition from winter to summer. Although about two-thirds of the cloud flights occurred in May and June, boundary-layer cloud fields were sampled under a variety of environmental and aerosol conditions, with about 75% of the flights occurring in cumulus and stratocumulus. Preliminary analyses show how these data are being used to analyze cloud-aerosol relationships, determine the aerosol sizes that are responsible for nucleating cloud drops, characterize the horizontal variability of the cloud radiative impacts, and evaluate air-borne and surface-based cloud property retrievals. We discuss how conducting an extended-term campaign requires a simplified operating paradigm that is different from that used for typical, short-term, intensive aircraft field programs.

  1. Tropical Warm Pool International Cloud Experiment (TWP-ICE): Cloud and Rain Characteristics in the Australian Monsoon

    SciTech Connect (OSTI)

    PT May; C Jakob; JH Mather

    2004-05-30

    The impact of oceanic convection on its environment and the relationship between the characteristics of the convection and the resulting cirrus characteristics is still not understood. An intense airborne measurement campaign combined with an extensive network of ground-based observations is being planned for the region near Darwin, Northern Australia, during January-February, 2006, to address these questions. The Tropical Warm Pool – International Cloud Experiment (TWP-ICE) will be the first field program in the tropics that attempts to describe the evolution of tropical convection, including the large scale heat, moisture, and momentum budgets, while at the same time obtaining detailed observations of cloud properties and the impact of the clouds on the environment. The emphasis will be on cirrus for the cloud properties component of the experiment. Cirrus clouds are ubiquitous in the tropics and have a large impact on their environment but the properties of these clouds are poorly understood. A crucial product from this experiment will be a dataset suitable to provide the forcing and testing required by cloud-resolving models and parameterizations in global climate models. This dataset will provide the necessary link between cloud properties and the models that are attempting to simulate them. The experiment is a collaboration between the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Program, the Bureau of Meteorology (BoM), the National Aeronautics and Space Administration (NASA), the European Commission DG RTD-1.2, and several United States, Australian, Canadian, and European Universities. This experiment will be undertaken over a 4-week period in early 2006. January and February corresponds to the wet phase of the Australia monsoon. This season has been selected because, despite Darwin’s coastal location, the convection that occurs over and near Darwin at this time is largely of maritime origin with a large fetch over water. Based on previous experiments, the convection appears typical of maritime convection with widespread convection that has complex organization, but is not as deep or as intense as continental or coastal convection. Therefore, it is expected that the convection and cloud characteristics will be representative of conditions typical for wide areas of the tropics.

  2. Cloud Computing Services

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Services - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  3. Evaluating the MMF Using CloudSat

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    its cloud Evaluate the MMF and improve its cloud simulations simulations Borrowed from Dave Randall, CSU The big picture The big picture ... ... . . Data ARM A-Train, MISR etc. ...

  4. ARM - Measurement - Cloud particle size distribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud particle size distribution The number of cloud particles present in any given volume of air...

  5. ARM - Measurement - Cloud particle number concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from you Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud particle number concentration The total number of cloud particles present in any given volume...

  6. Analysis of methyl neodecanamide in lake water by reversed-phase high performance liquid chromatography and gas chromatography-mass spectrometry

    SciTech Connect (OSTI)

    Rasmussen, H.T.; Friedman, S.K.; Mustilli, A.J.; McDonough, R.; McPherson, B.P. )

    1994-01-01

    Methyl Neodecanamide (MNDA) has been quantified in lake water at levels of 0.1 to 1,000 ppm. Total recoveries from spiked placebos were 99.8 [+-] 2.3% at the 1,000 ppm level and 98.3 [+-] 4.3% at the 0.1 ppm level (based on 54 determinations at each level). Plots of actual concentrations vs. determined concentrations were linear from 0.07--0.13 and 700--1,300 ppm (r > 0.999). Stability of MNDA in lake water was verified by determining the composition by GC/MS immediately after dissolution and after 3 days.

  7. Tropical Cloud Life Cycle and Overlap Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tropical Cloud Life Cycle and Overlap Structure Vogelmann, Andrew Brookhaven National Laboratory Jensen, Michael Brookhaven National Laboratory Kollias, Pavlos Brookhaven National Laboratory Luke, Edward Brookhaven National Laboratory Boer, Erwin LUEBEC Category: Cloud Properties The profile of cloud microphysical properties and how the clouds are overlapped within a vertical column have a profound impact on the radiative transfer and subsequent general circulation model simulations. We will

  8. What Makes Clouds Form, Grow and Die?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Makes Clouds Form, Grow and Die? What Makes Clouds Form, Grow and Die? Simulations Show Raindrops Physics May Affect Climate Model Accuracy February 19, 2015 thunderstorm Brazil shuttle NASA 1984 540 PNNL scientists used real-world observations to simulate how small clouds are likely to stay shallow, while larger clouds grow deeper because they mix with less dry air. Pictured are small and large thunderstorms growing over southern Brazil, taken from the space shuttle. Image: NASA Johnson Space

  9. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  10. Evolving the Land Information System into a Cloud Computing Service

    SciTech Connect (OSTI)

    Houser, Paul R.

    2015-02-17

    The Land Information System (LIS) was developed to use advanced flexible land surface modeling and data assimilation frameworks to integrate extremely large satellite- and ground-based observations with advanced land surface models to produce continuous high-resolution fields of land surface states and fluxes. The resulting fields are extremely useful for drought and flood assessment, agricultural planning, disaster management, weather and climate forecasting, water resources assessment, and the like. We envisioned transforming the LIS modeling system into a scientific cloud computing-aware web and data service that would allow clients to easily setup and configure for use in addressing large water management issues. The focus of this Phase 1 project was to determine the scientific, technical, commercial merit and feasibility of the proposed LIS-cloud innovations that are currently barriers to broad LIS applicability. We (a) quantified the barriers to broad LIS utility and commercialization (high performance computing, big data, user interface, and licensing issues); (b) designed the proposed LIS-cloud web service, model-data interface, database services, and user interfaces; (c) constructed a prototype LIS user interface including abstractions for simulation control, visualization, and data interaction, (d) used the prototype to conduct a market analysis and survey to determine potential market size and competition, (e) identified LIS software licensing and copyright limitations and developed solutions, and (f) developed a business plan for development and marketing of the LIS-cloud innovation. While some significant feasibility issues were found in the LIS licensing, overall a high degree of LIS-cloud technical feasibility was found.

  11. Unlocking the Secrets of Clouds

    Broader source: Energy.gov [DOE]

    Clouds may look soft, fluffy and harmless to the untrained eye, but to an expert climate model scientist they represent great challenges. Fortunately the Atmospheric Radiation Measurement (ARM) Climate and Research Facility is kicking off a five-month study which should significantly clear the air.

  12. ARM Data for Cloud Parameterization

    SciTech Connect (OSTI)

    Xu, Kuan-Man

    2006-10-02

    The PI's ARM investigation (DE-IA02-02ER633 18) developed a physically-based subgrid-scale saturation representation that fully considers the direct interactions of the parameterized subgrid-scale motions with subgrid-scale cloud microphysical and radiative processes. Major accomplishments under the support of that interagency agreement are summarized in this paper.

  13. Joint retrievals of cloud and drizzle in marine boundary layer clouds using

    Office of Scientific and Technical Information (OSTI)

    ground-based radar, lidar and zenith radiances (Journal Article) | DOE PAGES Published Article: Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances « Prev Next » Title: Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar

  14. Joint retrievals of cloud and drizzle in marine boundary layer clouds using

    Office of Scientific and Technical Information (OSTI)

    ground-based radar, lidar and zenith radiances (Journal Article) | SciTech Connect Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances Citation Details In-Document Search Title: Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar

  15. Joint retrievals of cloud and drizzle in marine boundary layer clouds using

    Office of Scientific and Technical Information (OSTI)

    ground-based radar, lidar and zenith radiances (Journal Article) | SciTech Connect Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances Citation Details In-Document Search Title: Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar

  16. Joint retrievals of cloud and drizzle in marine boundary layer clouds using

    Office of Scientific and Technical Information (OSTI)

    ground-based radar, lidar and zenith radiances (Journal Article) | DOE PAGES Published Article: Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances Title: Joint retrievals of cloud and drizzle in marine boundary layer clouds using ground-based radar, lidar and zenith radiances Active remote sensing of marine boundary-layer clouds is challenging as drizzle drops often dominate the observed radar reflectivity. We present a

  17. Hybrid Quantum Mechanics/Molecular Mechanics-Based Molecular Dynamics Simulation of Acid-Catalyzed Dehydration of Polyols in Liquid Water

    SciTech Connect (OSTI)

    Caratzoulas, Stavros; Courtney, Timothy; Vlachos, Dionisios G.

    2011-01-01

    We use the conversion of protonated glycerol to acrolein for a case study of the mechanism of acid-catalyzed dehydration of polyols in aqueous environments. We employ hybrid Quamtum Mechanics/Molecular Mechanics Molecular Dynamics (QM/MM MD) simulations with biased sampling and perform free energy calculations for the elementary steps of the reaction. We investigate the effects of solvent dynamics and in particular the role of quantum mechanical water in the dehydration mechanism. We present results supporting a mechanism that proceeds via water-mediated proton transfers and thus through an enol intermediate. We find that the first dehydration may take place by two, low-energy pathways requiring, respectively, 20.9 and 18.8 kcal/mol of activation free energy. The second dehydration requires 19.9 kcal/mol of activation free energy while for the overall reaction we compute a free energy change of -8 kcal/mol.

  18. Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE) Science Plan

    SciTech Connect (OSTI)

    Fast, JD; Berg, LK

    2015-12-01

    Cumulus convection is an important component in the atmospheric radiation budget and hydrologic cycle over the Southern Great Plains and over many regions of the world, particularly during the summertime growing season when intense turbulence induced by surface radiation couples the land surface to clouds. Current convective cloud parameterizations contain uncertainties resulting in part from insufficient coincident data that couples cloud macrophysical and microphysical properties to inhomogeneities in boundary layer and aerosol properties. The Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE) campaign is designed to provide a detailed set of measurements that are needed to obtain a more complete understanding of the life cycle of shallow clouds by coupling cloud macrophysical and microphysical properties to land surface properties, ecosystems, and aerosols. HI-SCALE consists of 2, 4-week intensive observational periods, one in the spring and the other in the late summer, to take advantage of different stages and distribution of “greenness” for various types of vegetation in the vicinity of the Atmospheric Radiation and Measurement (ARM) Climate Research Facility’s Southern Great Plains (SGP) site as well as aerosol properties that vary during the growing season. Most of the proposed instrumentation will be deployed on the ARM Aerial Facility (AAF) Gulfstream 1 (G-1) aircraft, including those that measure atmospheric turbulence, cloud water content and drop size distributions, aerosol precursor gases, aerosol chemical composition and size distributions, and cloud condensation nuclei concentrations. Routine ARM aerosol measurements made at the surface will be supplemented with aerosol microphysical properties measurements. The G-1 aircraft will complete transects over the SGP Central Facility at multiple altitudes within the boundary layer, within clouds, and above clouds.

  19. Microsoft PowerPoint - XDC_ARM_STM_2007_poster_final.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Derived Quantities & Models Advective tendency, cloud liquid water, cloud ice water, net radiation, radiative heating rate, surface skin temperature, fluxes, surface...

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to quantify bulk shallow cloud moistening through evaporation of condensed water using a simple method based on observations of liquid water path, cloud depth and temporal...

  1. Membrane separation of ionic liquid solutions

    DOE Patents [OSTI]

    Campos, Daniel; Feiring, Andrew Edward; Majumdar, Sudipto; Nemser, Stuart

    2015-09-01

    A membrane separation process using a highly fluorinated polymer membrane that selectively permeates water of an aqueous ionic liquid solution to provide dry ionic liquid. Preferably the polymer is a polymer that includes polymerized perfluoro-2,2-dimethyl-1,3-dioxole (PDD). The process is also capable of removing small molecular compounds such as organic solvents that can be present in the solution. This membrane separation process is suitable for drying the aqueous ionic liquid byproduct from precipitating solutions of biomass dissolved in ionic liquid, and is thus instrumental to providing usable lignocellulosic products for energy consumption and other industrial uses in an environmentally benign manner.

  2. Development of a promising filtration method for liquid clarification in nuclear facilities. [For TMI-2 water, reprocessing dissolver solutions, ZnBr/sub 2/ shielding solutions

    SciTech Connect (OSTI)

    Collins, E.D.; Knauer, J.B.; Byrd, L.A.; Ross, R.G.; Savage, H.C.

    1982-01-01

    Conclusions reached are that deep beds of diatomaceous earths are especially attractive for clarification of radioactive solutions, or slurries containing insoluble radioactive material, because the diatomaceous material provides a noncompressible medium that is retentive for a wide variety of particle sizes. Also, the diatomaceous material, because of its inorganic composition, is resistant to degradation by radiation from the retained particulate matter. Its silicious character is especially appropriate for conversion to vitrified or cement-type waste forms. This paper studied the use of diatomaceous earth to filter synthetic TMI-2 water, reprocessing dissolver solutions, and zinc bromide solutions (hot-cell shielding).

  3. Synchrotrons Explore Water's Molecular Mysteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory's Advanced Light Source, scientists observed a surprisingly dense form of water that remained liquid well beyond its typical freezing point. Researchers applied a...

  4. Quantifying Diurnal Cloud Radiative Effects by Cloud Type in the Tropical Western Pacific

    SciTech Connect (OSTI)

    Burleyson, Casey D.; Long, Charles N.; Comstock, Jennifer M.

    2015-06-01

    Cloud radiative effects are examined using long-term datasets collected at the three Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facilities in the tropical western Pacific. We quantify the surface radiation budget, cloud populations, and cloud radiative effects by partitioning the data by cloud type, time of day, and as a function of large scale modes of variability such as El Niño Southern Oscillation (ENSO) phase and wet/dry seasons at Darwin. The novel facet of our analysis is that we break aggregate cloud radiative effects down by cloud type across the diurnal cycle. The Nauru cloud populations and subsequently the surface radiation budget are strongly impacted by ENSO variability whereas the cloud populations over Manus only shift slightly in response to changes in ENSO phase. The Darwin site exhibits large seasonal monsoon related variations. We show that while deeper convective clouds have a strong conditional influence on the radiation reaching the surface, their limited frequency reduces their aggregate radiative impact. The largest source of shortwave cloud radiative effects at all three sites comes from low clouds. We use the observations to demonstrate that potential model biases in the amplitude of the diurnal cycle and mean cloud frequency would lead to larger errors in the surface energy budget compared to biases in the timing of the diurnal cycle of cloud frequency. Our results provide solid benchmarks to evaluate model simulations of cloud radiative effects in the tropics.

  5. Sewage sludge dewatering using flowing liquid metals

    DOE Patents [OSTI]

    Carlson, Larry W.

    1986-01-01

    A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

  6. Rapid microwave hydrothermal synthesis of ZnGa{sub 2}O{sub 4} with high photocatalytic activity toward aromatic compounds in air and dyes in liquid water

    SciTech Connect (OSTI)

    Sun Meng; Li Danzhen; Zhang Wenjuan; Chen Zhixin; Huang Hanjie; Li Wenjuan; He Yunhui; Fu Xianzhi

    2012-06-15

    ZnGa{sub 2}O{sub 4} was synthesized from Ga(NO{sub 3}){sub 3} and ZnCl{sub 2} via a rapid and facile microwave-assisted hydrothermal method. The photocatalytic properties of the as-prepared ZnGa{sub 2}O{sub 4} were evaluated by the degradation of pollutants in air and aqueous solution under ultraviolet (UV) light illumination. The results demonstrated that ZnGa{sub 2}O{sub 4} had exhibited efficient photocatalytic activities higher than that of commercial P25 (Degussa Co.) in the degradation of benzene, toluene, and ethylbenzene, respectively. In the liquid phase degradation of dyes (methyl orange, Rhodamine B, and methylene blue), ZnGa{sub 2}O{sub 4} has also exhibited remarkable activities higher than that of P25. After 32 min of UV light irradiation, the decomposition ratio of methyl orange (10 ppm, 150 mL) over ZnGa{sub 2}O{sub 4} (0.06 g) was up to 99%. The TOC tests revealed that the mineralization ratio of MO (10 ppm, 150 mL) was 88.1% after 90 min of reaction. A possible mechanism of the photocatalysis over ZnGa{sub 2}O{sub 4} was also proposed. - Graphical abstract: In the degradation of RhB under UV light irradiation, ZnGa{sub 2}O{sub 4} had exhibited efficient photo-activity, and after only 24 min of irradiation the decomposition ratio was up to 99.8%. Highlights: Black-Right-Pointing-Pointer A rapid and facile M-H method to synthesize ZnGa{sub 2}O{sub 4} photocatalyst. Black-Right-Pointing-Pointer The photocatalyst exhibits high activity toward benzene and dyes. Black-Right-Pointing-Pointer The catalyst possesses more surface hydroxyl sites than TiO{sub 2} (P25). Black-Right-Pointing-Pointer Deep oxidation of different aromatic compounds and dyes over catalyst.

  7. Vertical microphysical profiles of convective clouds as a tool for

    Office of Scientific and Technical Information (OSTI)

    obtaining aerosol cloud-mediated climate forcings (Technical Report) | SciTech Connect Vertical microphysical profiles of convective clouds as a tool for obtaining aerosol cloud-mediated climate forcings Citation Details In-Document Search Title: Vertical microphysical profiles of convective clouds as a tool for obtaining aerosol cloud-mediated climate forcings Quantifying the aerosol/cloud-mediated radiative effect at a global scale requires simultaneous satellite retrievals of cloud

  8. REDISTRIBUTOR FOR LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Bradley, J.G.

    1957-10-29

    An improved baffle plate construction to intimately mix immiscible liquid solvents for solvent extraction processes in a liquid-liquid pulse column is described. To prevent the light and heavy liquids from forming separate continuous homogeneous vertical channels through sections of the column, a baffle having radially placed rectangular louvers with deflection plates opening upon alternate sides of the baffle is placed in the column, normal to the axis. This improvement substantially completely reduces strippiig losses due to poor mixing.

  9. ionic liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Tomography: a Novel Method for Determining 3D Cloud Liquid Water Distribution Download a printable PDF Submitter: Wiscombe, W. J., Brookhaven National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Huang, D., Y. Liu, and W. Wiscombe, 2007a: Determination of cloud liquid water distribution using 3D cloud tomography. J. Geophys. Res., submitted. Cloud tomography is a novel method for determining cloud water

  11. Vertical tube liquid pollutant separators

    SciTech Connect (OSTI)

    Lynch, W.M.

    1982-06-08

    A plurality of elongated hollow, circular, foraminous substantially vertical tubes contiguously stacked transversely to the direction flowing liquid such as waste water containing foreign matter, I.E., settable solids and free oil, in a coalescer-separator apparatus provide a filter body providing for significant surface area contact by the liquid on both inside and outside surfaces of the tubes to entrap the foreign matter but defining substantially vertical passages permitting the entrapped foreign matter to be gravity separated with the lighter matter coalescing and floating upwardly and the heavier matter settling downwardly so that substantially clarified effluent flows from the apparatus. The stacked tube filter body is contained within an insulated closed container of a sufficient capacity, and the arrays of holes in the tube walls are coordinated with respect to the intended volumetric capacity of the apparatus, so that turbulence in the liquid flowing through the filter body is minimized.

  12. Sensor for detection of liquid spills on surfaces

    DOE Patents [OSTI]

    Davis, Brent C.; Gayle, Tom M.

    1989-01-01

    A surface liquid detector is disclosed for detecting liquids spilled on surfaces such as floors. A temperature-sensitive thermistor probe is used in a bridge circuit to detect the change in resistance in the thermistor due to the change in thermal conductivity that occurs when a liquid contacts the probe. The device is characterized by the ability to detect either conductive or nonconductive liquids, such as water or oil spills.

  13. Fractionation and Removal of Solutes from Ionic Liquids - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Fractionation and Removal of Solutes from Ionic Liquids Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryResearchers at the Joint BioEnergy Institute (JBEI) have developed a technology to fractionate and recover biomaterials dissolved in an ionic liquid and to purify water miscible ionic liquids. The JBEI technology utilizes specific mixtures of solvents to precipitate or extract compounds dissolved in an ionic liquid without high

  14. The LANL Cloud-Aerosol Model

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The K-25 Story The K-25 Story Addthis Description The K-25 Story

    The LANL Cloud-Aerosol Model Reisner, Jon Los Alamos National Laboratory Category: Modeling Additional Authors: Dubey Manvendra, Chris Jeffery, Miroslaw Andrejczuk, and Dave Moulton A cloud-aerosol modeling framework is being developed at Los Alamos National Laboratory that incorporates two unique aspects in its formulation. First, the model employs a nonlinear solver that requires cloud-aerosol parameterizations be smooth or

  15. Midlatitude Continental Convective Clouds Experiment Science Objective

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Midlatitude Continental Convective Clouds Experiment Science Objective Despite improvements in computing power, current weather and climate models are unable to accurately reproduce the formation, growth, and decay of clouds and precipitation associated with storm systems. Not only is this due to a lack of data about precipitation, but also about the 3-dimensional environment of the surrounding clouds, winds, and moisture, and how that affects the transfer of energy between the sun and Earth. To

  16. Retrievals of Cloud Fraction and Cloud Albedo from Surface-based Shortwave

    Office of Scientific and Technical Information (OSTI)

    Radiation Measurements: A Comparison of 16 Year Measurements (Journal Article) | SciTech Connect Retrievals of Cloud Fraction and Cloud Albedo from Surface-based Shortwave Radiation Measurements: A Comparison of 16 Year Measurements Citation Details In-Document Search Title: Retrievals of Cloud Fraction and Cloud Albedo from Surface-based Shortwave Radiation Measurements: A Comparison of 16 Year Measurements Ground-based radiation measurements have been widely conducted to gain information

  17. Mountain-induced Dynamics Influence Cloud Phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2010-2011 via coordinated projects targeting clouds, precipitation, and dynamics in the Park Range of Colorado. The National Science Foundation sponsored aircraft measurements as...

  18. DOE Research and Development Accomplishments Tag Cloud

    Office of Scientific and Technical Information (OSTI)

    Database Tag Cloud This tag cloud is a specific type of weighted list that provides a quick look at the content of the DOE R&D Accomplishments database. It can be easily browsed because terms are in alphabetical order. With this tag cloud, there is a direct correlation between font size and quantity. The more times a term appears in the bibliographic citations, the larger the font size. This tag cloud is also interactive. Clicking on a term will activate a search for that term. Search

  19. Dynamics of Molecular Clouds: Observations, Simulations, and...

    Office of Scientific and Technical Information (OSTI)

    Simulations, and NIF Experiments Citation Details In-Document Search Title: Dynamics of Molecular Clouds: Observations, Simulations, and NIF Experiments You are ...

  20. What Makes Clouds Form, Grow and Die?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    were born and grew. Those formulas did not always reflect reality. With more advanced computers came the ability to explicitly simulate large-cloud systems instead of approximating...

  1. Characterizing Arctic Mixed-phase Cloud Structure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    have two distinguished cloud base heights (CBHs) that can be defined by both ceilometer (black dots) and micropulse lidar (MPL; pink dots) measurements (Figure 1). For a...

  2. Fragmentation in rotating isothermal protostellar clouds

    SciTech Connect (OSTI)

    Bodenheimer, P.; Tohline, J.E.; Black, D.C.

    1980-01-01

    Results of an extensive set of 3-D hydrodynamic calculations that have been performed to investigate the susceptibility of rotating clouds to gravitational fragmentation are presented. (GHT)

  3. ARM - Field Campaign - Midlatitude Continental Convective Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experiment (MC3E) Campaign Links Science Plan MC3E Website Field Campaign Report ARM Data Discovery Browse Data Related Campaigns Midlatitude Continental Convective Clouds...

  4. ARM - Evaluation Product - Cloud Classification VAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    properties includes cloud boundaries, thickness, phase, type, and precipitation information, and hence provides a useful tool for evaluation of model simulations and...

  5. ARM - Field Campaign - Cloud Radar IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of aerosol properties during clear-sky conditions. The ETL Radar Meteorology and Oceanography Division will field their NOAAK scanning cloud radar near the new ARM millimeter...

  6. CHARACTERIZATION OF CLOUDS IN TITAN'S TROPICAL ATMOSPHERE

    SciTech Connect (OSTI)

    Griffith, Caitlin A.; Penteado, Paulo; Rodriguez, Sebastien; Baines, Kevin H.; Buratti, Bonnie; Sotin, Christophe; Clark, Roger; Nicholson, Phil; Jaumann, Ralf

    2009-09-10

    Images of Titan's clouds, possible over the past 10 years, indicate primarily discrete convective methane clouds near the south and north poles and an immense stratiform cloud, likely composed of ethane, around the north pole. Here we present spectral images from Cassini's Visual Mapping Infrared Spectrometer that reveal the increasing presence of clouds in Titan's tropical atmosphere. Radiative transfer analyses indicate similarities between summer polar and tropical methane clouds. Like their southern counterparts, tropical clouds consist of particles exceeding 5 {mu}m. They display discrete structures suggestive of convective cumuli. They prevail at a specific latitude band between 8 deg. - 20 deg. S, indicative of a circulation origin and the beginning of a circulation turnover. Yet, unlike the high latitude clouds that often reach 45 km altitude, these discrete tropical clouds, so far, remain capped to altitudes below 26 km. Such low convective clouds are consistent with the highly stable atmospheric conditions measured at the Huygens landing site. Their characteristics suggest that Titan's tropical atmosphere has a dry climate unlike the south polar atmosphere, and despite the numerous washes that carve the tropical landscape.

  7. Ground-based Microwave Cloud Tomography

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microwave Cloud Tomography Experiment, SGP, May 15-June 15, 2009 Lead Scientist Dong Huang, BNL Co-Investigators Al Gasiewski, UC Boulder Maria Cadeddu, ANL Warren Wiscombe, BNL Radiation Processes Working Group March 30, 2009 multiple radiometers All good cloud radiation modelers should close their airplane window shades so as not to be corrupted by the spectacle of real 3D clouds. - Roger Davies In case you forget to do this, you see 3/30/2009 ARM RPWG 2 Effects of cloud structure on radiation

  8. Dynamics of Molecular Clouds: Observations, Simulations, and...

    Office of Scientific and Technical Information (OSTI)

    Simulations, and NIF Experiments Citation Details In-Document Search Title: Dynamics of Molecular Clouds: Observations, Simulations, and NIF Experiments Authors: Kane, J ...

  9. ARM Cloud Aerosol Precipitation Experiment (ACAPEX) Science Plan

    SciTech Connect (OSTI)

    Leung, L. R.; Prather, K.; Ralph, R.; Rosenfeld, D.; Spackman, R.; DeMott, P.; Fairall, C.; Fan, J.; Hagos, S.; Hughes, M.; Long, C.; Rutledge, S.; Waliser, D.; Wang, H.

    2014-09-01

    The western U.S. receives precipitation predominantly during the cold season when storms approach from the Pacific Ocean. The snowpack that accumulates during winter storms provides about 70-90% of water supply for the region. Understanding and modeling the fundamental processes that govern the large precipitation variability and extremes in the western U.S. is a critical test for the ability of climate models to predict the regional water cycle, including floods and droughts. Two elements of significant importance in predicting precipitation variability in the western U.S. are atmospheric rivers and aerosols. Atmospheric rivers (ARs) are narrow bands of enhanced water vapor associated with the warm sector of extratropical cyclones over the Pacific and Atlantic oceans. Because of the large lower-tropospheric water vapor content, strong atmospheric winds and neutral moist static stability, some ARs can produce heavy precipitation by orographic enhancement during landfall on the U.S. West Coast. While ARs are responsible for a large fraction of heavy precipitation in that region during winter, much of the rest of the orographic precipitation occurs in post-frontal clouds, which are typically quite shallow, with tops just high enough to pass the mountain barrier. Such clouds are inherently quite susceptible to aerosol effects on both warm rain and ice precipitation-forming processes.

  10. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  11. Indirect and semi-direct aerosol campaign: The impact of Arctic aerosols on clouds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McFarquhar, Greg M.; Ghan, Steven; Verlinde, Johannes; Korolev, Alexei; Strapp, J. Walter; Schmid, Beat; Tomlinson, Jason M.; Wolde, Menqistu; Brooks, Sarah D.; Cziczo, Dan; et al

    2011-02-01

    A comprehensive dataset of microphysical and radiative properties of aerosols and clouds in the boundary layer in the vicinity of Barrow, Alaska, was collected in April 2008 during the Indirect and Semi-Direct Aerosol Campaign (ISDAC). ISDAC's primary aim was to examine the effects of aerosols, including those generated by Asian wildfires, on clouds that contain both liquid and ice. ISDAC utilized the Atmospheric Radiation Measurement Pro- gram's permanent observational facilities at Barrow and specially deployed instruments measuring aerosol, ice fog, precipitation, and radiation. The National Research Council of Canada Convair-580 flew 27 sorties and collected data using an unprecedented 41more » stateof- the-art cloud and aerosol instruments for more than 100 h on 12 different days. Aerosol compositions, including fresh and processed sea salt, biomassburning particles, organics, and sulfates mixed with organics, varied between flights. Observations in a dense arctic haze on 19 April and above, within, and below the single-layer stratocumulus on 8 and 26 April are enabling a process-oriented understanding of how aerosols affect arctic clouds. Inhomogeneities in reflectivity, a close coupling of upward and downward Doppler motion, and a nearly constant ice profile in the single-layer stratocumulus suggests that vertical mixing is responsible for its longevity observed during ISDAC. Data acquired in cirrus on flights between Barrow and Fairbanks, Alaska, are improving the understanding of the performance of cloud probes in ice. Furthermore, ISDAC data will improve the representation of cloud and aerosol processes in models covering a variety of spatial and temporal scales, and determine the extent to which surface measurements can provide retrievals of aerosols, clouds, precipitation, and radiative heating.« less

  12. Evaluating Clouds, Aerosols, and their Interactions in Three Global Climate Models using COSP and Satellite Observations

    SciTech Connect (OSTI)

    Ban-Weiss, George; Jin, Ling; Bauer, S.; Bennartz, Ralph; Liu, Xiaohong; Zhang, Kai; Ming, Yi; Guo, Huan; Jiang, Jonathan

    2014-09-23

    Accurately representing aerosol-cloud interactions in global climate models is challenging. As parameterizations evolve, it is important to evaluate their performance with appropriate use of observations. In this work we compare aerosols, clouds, and their interactions in three climate models (AM3, CAM5, ModelE) to MODIS satellite observations. Modeled cloud properties were diagnosed using the CFMIP Observations Simulator Package (COSP). Cloud droplet number concentrations (N) were derived using the same algorithm for both satellite-simulated model values and observations. We find that aerosol optical depth tau simulated by models is similar to observations. For N, AM3 and CAM5 capture the observed spatial pattern of higher values in near-coast versus remote ocean regions, though modeled values in general are higher than observed. In contrast, ModelE simulates lower N in most near-coast versus remote regions. Aerosol- cloud interactions were computed as the sensitivity of N to tau for marine liquid clouds off the coasts of South Africa and Eastern Asia where aerosol pollution varies in time. AM3 and CAM5 are in most cases more sensitive than observations, while the sensitivity for ModelE is statistically insignificant. This widely used sensitivity could be subject to misinterpretation due to the confounding influence of meteorology on both aerosols and clouds. A simple framework for assessing the N tau sensitivity at constant meteorology illustrates that observed sensitivity can change from positive to statistically insignificant when including the confounding influence of relative humidity. Satellite simulated values of N were compared to standard model output and found to be higher with a bias of 83 cm-3.

  13. Electron Cloud Effects in Accelerators

    SciTech Connect (OSTI)

    Furman, M.A.

    2012-11-30

    Abstract We present a brief summary of various aspects of the electron-cloud effect (ECE) in accelerators. For further details, the reader is encouraged to refer to the proceedings of many prior workshops, either dedicated to EC or with significant EC contents, including the entire ?ECLOUD? series [1?22]. In addition, the proceedings of the various flavors of Particle Accelerator Conferences [23] contain a large number of EC-related publications. The ICFA Beam Dynamics Newsletter series [24] contains one dedicated issue, and several occasional articles, on EC. An extensive reference database is the LHC website on EC [25].

  14. Observed Increase of TTL Temperature and Water Vapor in Polluted Couds over Asia

    SciTech Connect (OSTI)

    Su, Hui; Jiang, Jonathan; Liu, Xiaohong; Penner, J.; Read, William G.; Massie, Steven T.; Schoeberl, Mark R.; Colarco, Peter; Livesey, Nathaniel J.; Santee, Michelle L.

    2011-06-01

    Aerosols can affect cloud particle size and lifetime, which impacts precipitation, radiation and climate. Previous studies1-4 suggested that reduced ice cloud particle size and fall speed due to the influence of aerosols may increase evaporation of ice crystals and/or cloud radiative heating in the tropical tropopause layer (TTL), leading to higher water vapor abundance in air entering the stratosphere. Observational substantiation of such processes is still lacking. Here, we analyze new observations from multiple NASA satellites to show the imprint of pollution influence on stratospheric water vapor. We focus our analysis on the highly-polluted South and East Asia region during boreal summer. We find that "polluted" ice clouds have smaller ice effective radius than "clean" clouds. In the TTL, the polluted clouds are associated with warmer temperature and higher specific humidity than the clean clouds. The water vapor difference between the polluted and clean clouds cannot be explained by other meteorological factors, such as updraft and detrainment strength. Therefore, the observed higher water vapor entry value into the stratosphere in the polluted clouds than in the clean clouds is likely a manifestation of aerosol pollution influence on stratospheric water vapor. Given the radiative and chemical importance of stratospheric water vapor, the increasing emission of aerosols over Asia may have profound impacts on stratospheric chemistry and global energy balance and water cycle.

  15. Clouds, aerosol, and precipitation in the Marine Boundary Layer...

    Office of Scientific and Technical Information (OSTI)

    Approximately half of all clouds contained precipitation detectable as radar echoes below the cloud base. Radar and satellite observations show that clouds with tops from 1-11 km ...

  16. ARM - Field Campaign - Measuring Clouds at SGP with Stereo Photogramme...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the form of the Point Cloud of Cloud Points Product (PCCPP). The PCCPP will: provide context on life-cycle stage and cloud position for vertically pointing radars, lidars, and...

  17. Intercomparison of model simulations of mixed-phase clouds observed...

    Office of Scientific and Technical Information (OSTI)

    Intercomparison of model simulations of mixed-phase clouds observed during the ARM Mixed-Phase Arctic Cloud Experiment. Part I: Single layer cloud Citation Details In-Document ...

  18. ARM - PI Product - Cloud Property Retrieval Products for Graciosa...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LWP43*pi*r3*N*dZ with the uncertainty of 30%, sigma0.38 cloud optical thickness taudong: Dong98 calculated cloud optical depth from tau1.575LWPreDong cloud particle...

  19. VOCALS: The VAMOS Ocean-Cloud-Atmosphere-Land Study () | Data...

    Office of Scientific and Technical Information (OSTI)

    VOCALS: The VAMOS Ocean-Cloud-Atmosphere-Land Study Title: VOCALS: The VAMOS Ocean-Cloud-Atmosphere-Land Study VOCALS (VAMOS* Ocean-Cloud-Atmosphere-Land Study) is an international ...

  20. Stratus Cloud Drizzle Retrieval During SHEBA from MMCR Doppler...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    26 132 dBZ 3 D 1 2 x + - - > < the droplet concentration as 1 3 e w 2 x q r 4 3 xp 3 N and the liquid water flux as ( ) ( ) a b 3 exp a b V q F 2 x D 1 q...

  1. “Lidar Investigations of Aerosol, Cloud, and Boundary Layer Properties Over the ARM ACRF Sites”

    SciTech Connect (OSTI)

    Ferrare, Richard; Turner, David

    2015-01-13

    Project goals; Characterize the aerosol and ice vertical distributions over the ARM NSA site, and in particular to discriminate between elevated aerosol layers and ice clouds in optically thin scattering layers; Characterize the water vapor and aerosol vertical distributions over the ARM Darwin site, how these distributions vary seasonally, and quantify the amount of water vapor and aerosol that is above the boundary layer; Use the high temporal resolution Raman lidar data to examine how aerosol properties vary near clouds; Use the high temporal resolution Raman lidar and Atmospheric Emitted Radiance Interferometer (AERI) data to quantify entrainment in optically thin continental cumulus clouds; and Use the high temporal Raman lidar data to continue to characterize the turbulence within the convective boundary layer and how the turbulence statistics (e.g., variance, skewness) is correlated with larger scale variables predicted by models.

  2. ARM - Publications: Science Team Meeting Documents: Tropical Cloud Overlap

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure and Cloud Area Tropical Cloud Overlap Structure and Cloud Area Vogelmann, Andrew Brookhaven National Laboratory Jensen, Michael Brookhaven National Laboratory Boer, Erwin LUEBEC The Tropical Western Pacific (TWP), with its vigorous cloud activity, is an excellent location to investigate the relationships between cloud properties and radiative fluxes. To unlock such issues first requires a better understanding of what the observed structures of clouds are and how they affect the

  3. Vertical microphysical profiles of convective clouds as a tool...

    Office of Scientific and Technical Information (OSTI)

    at a global scale requires simultaneous satellite retrievals of cloud condensation nuclei ... of boundary layer convective clouds from an operational polar orbiting weather satellite. ...

  4. Towards a Characterization of Arctic Mixed-Phase Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    manual classification of cloud phase. Using collocated cloud radar and depolarization lidar observations, it is shown that mixed-phase conditions have a high correlation with a...

  5. ARM - Evaluation Product - CMWG Data - SCM-Forcing Data, Cloud...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    data. Cloud microphysical properties derived from Mace's data of atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates are regridded to a...

  6. ARM - Midlatitude Continental Convective Clouds Experiment (MC3E...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM - Midlatitude Continental Convective Clouds Experiment (MC3E): Multi-Frequency ... (DOE) and NASA sponsored Mid-latitude Continental Convective Cloud Experiment (MC3E). ...

  7. Cloud microphysical relationships and their implication on entrainment...

    Office of Scientific and Technical Information (OSTI)

    Cloud microphysical relationships and their implication on entrainment and mixing mechanism for the stratocumulus clouds measured during the VOCALS project Citation Details ...

  8. ARM - Field Campaign - Azores: Clouds, Aerosol and Precipitation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Campaigns Azores: Above-Cloud Radiation Budget near Graciosa Island 2010.04.15, Miller, AMF Azores: Extension to Clouds, Aerosol and Precipitation in the Marine Boundary...

  9. Simulations of the electron cloud buildups and suppressions in...

    Office of Scientific and Technical Information (OSTI)

    Simulations of the electron cloud buildups and suppressions in Tevatron and main injector Citation Details In-Document Search Title: Simulations of the electron cloud buildups and ...

  10. Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems...

    Office of Scientific and Technical Information (OSTI)

    Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE) Science ... Current convective cloud parameterizations contain uncertainties resulting in part from ...

  11. STORMVEX: Ice Nuclei and Cloud Condensation Nuclei Characterization...

    Office of Scientific and Technical Information (OSTI)

    Nuclei and Cloud Condensation Nuclei Characterization Field Campaign Report D Cziczo March ... warm clouds, require precise separation techniques and accurate identification of phase. ...

  12. STORMVEX. Ice Nuclei and Cloud Condensation Nuclei Characterization...

    Office of Scientific and Technical Information (OSTI)

    Title: STORMVEX. Ice Nuclei and Cloud Condensation Nuclei Characterization Field Campaign ... warm clouds, require precise separation techniques and accurate identification of phase. ...

  13. ARM: Millimeter Wavelength Cloud Radar (MMCR): transmitted RF...

    Office of Scientific and Technical Information (OSTI)

    transmitted RF power Title: ARM: Millimeter Wavelength Cloud Radar (MMCR): transmitted RF power Millimeter Wavelength Cloud Radar (MMCR): transmitted RF power Authors: Karen ...

  14. ARM - Publications: Science Team Meeting Documents: Cloud Radiative...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Facility: Part 2. The Vertical Redistribution of Radiant Energy by Clouds. ... Documentation with data of the effects of clouds on the radiant energy balance of the ...

  15. Distribution and Validation of Cloud Cover Derived from AVHRR...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... maps developed for the Cloud's and the Earth's Radiant Energy System (CERES) Project. ... for the Cloud's and the Earth's Radiant Energy System (CERES) Experiment. J. Appl. ...

  16. ARM - Field Campaign - Biogenic Aerosols - Effects on Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    relevant to DOE's goals in understanding the impact of clouds and aerosols on climate change. TWST contributes significantly to the body of data used for extracting cloud...

  17. Stratus Cloud Structure from MM-Radar Transects and Satellite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    modeling: * cloud-radiation interaction where correlations can trigger three-dimensional (3D) radiative transfer effects; and * dynamical cloud modeling where the goal is to...

  18. ARM - Midlatitude Continental Convective Clouds Experiment (MC3E...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Related Campaigns Meetings Cloud Life Cycle Working Group Contacts Michael Jensen, Lead Scientist Midlatitude Continental Convective Clouds Experiment (MC3E) Thanks to...

  19. ARM - Field Campaign - Marine ARM GPCI Investigation of Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsMarine ARM GPCI Investigation of Clouds (MAGIC) Campaign Links MAGIC Website ARM Data Discovery Browse Data Related Campaigns Marine ARM GPCI Investigation of Clouds...

  20. ARM: Aerosol Observing System (AOS): cloud condensation nuclei...

    Office of Scientific and Technical Information (OSTI)

    Title: ARM: Aerosol Observing System (AOS): cloud condensation nuclei data Aerosol Observing System (AOS): cloud condensation nuclei data Authors: Scott Smith ; Cynthia Salwen ; ...

  1. The relationship between interannual and long-term cloud feedbacks...

    Office of Scientific and Technical Information (OSTI)

    climate models with more positive cloud feedback in response to interannual climate fluctuations also have more positive cloud feedback in response to long-term global warming. ...

  2. City of Red Cloud, Nebraska (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    Red Cloud, Nebraska (Utility Company) Jump to: navigation, search Name: Red Cloud Municipal Power Place: Nebraska Phone Number: 402-746-2215 Website: www.redcloudnebraska.comgover...

  3. Direct Numerical Simulations and Robust Predictions of Cloud...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud. Credit: Computational Science and Engineering Laboratory, ETH Zurich, Switzerland Direct Numerical Simulations and Robust Predictions of Cloud Cavitation Collapse PI Name:...

  4. Evolution in Cloud Population Statistics of the MJO. From AMIE...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Evolution in Cloud Population Statistics of the MJO. From AMIE Field ... Citation Details In-Document Search Title: Evolution in Cloud Population Statistics of the ...

  5. Evolution in Cloud Population Statistics of the MJO. From AMIE...

    Office of Scientific and Technical Information (OSTI)

    Evolution in Cloud Population Statistics of the MJO. From AMIE Field Observations to ... Citation Details In-Document Search Title: Evolution in Cloud Population Statistics of the ...

  6. GFDL ARM Project Technical Report: Using ARM Observations to Evaluate Cloud and Convection Parameterizations & Cloud-Convection-Radiation Interactions in the GFDL Atmospheric General Circulation Model

    SciTech Connect (OSTI)

    V. Ramaswamy; L. J. Donner; J-C. Golaz; S. A. Klein

    2010-06-17

    This report briefly summarizes the progress made by ARM postdoctoral fellow, Yanluan Lin, at GFDL during the period from October 2008 to present. Several ARM datasets have been used for GFDL model evaluation, understanding, and improvement. This includes a new ice fall speed parameterization with riming impact and its test in GFDL AM3, evaluation of model cloud and radiation diurnal and seasonal variation using ARM CMBE data, model ice water content evaluation using ARM cirrus data, and coordination of the TWPICE global model intercomparison. The work illustrates the potential and importance of ARM data for GCM evaluation, understanding, and ultimately, improvement of GCM cloud and radiation parameterizations. Future work includes evaluation and improvement of the new dynamicsPDF cloud scheme and aerosol activation in the GFDL model.

  7. Testing ice microphysics parameterizations in the NCAR Community Atmospheric Model Version 3 using Tropical Warm Pool-International Cloud Experiment data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Weiguo; Liu, Xiaohong; Xie, Shaocheng; Boyle, Jim; McFarlane, Sally A.

    2009-07-23

    Here, cloud properties have been simulated with a new double-moment microphysics scheme under the framework of the single-column version of NCAR Community Atmospheric Model version 3 (CAM3). For comparison, the same simulation was made with the standard single-moment microphysics scheme of CAM3. Results from both simulations compared favorably with observations during the Tropical Warm Pool–International Cloud Experiment by the U.S. Department of Energy Atmospheric Radiation Measurement Program in terms of the temporal variation and vertical distribution of cloud fraction and cloud condensate. Major differences between the two simulations are in the magnitude and distribution of ice water content within themore » mixed-phase cloud during the monsoon period, though the total frozen water (snow plus ice) contents are similar. The ice mass content in the mixed-phase cloud from the new scheme is larger than that from the standard scheme, and ice water content extends 2 km further downward, which is in better agreement with observations. The dependence of the frozen water mass fraction on temperature from the new scheme is also in better agreement with available observations. Outgoing longwave radiation (OLR) at the top of the atmosphere (TOA) from the simulation with the new scheme is, in general, larger than that with the standard scheme, while the surface downward longwave radiation is similar. Sensitivity tests suggest that different treatments of the ice crystal effective radius contribute significantly to the difference in the calculations of TOA OLR, in addition to cloud water path. Numerical experiments show that cloud properties in the new scheme can respond reasonably to changes in the concentration of aerosols and emphasize the importance of correctly simulating aerosol effects in climate models for aerosol-cloud interactions. Further evaluation, especially for ice cloud properties based on in-situ data, is needed.« less

  8. Liquid level detector

    DOE Patents [OSTI]

    Grasso, A.P.

    1984-02-21

    A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  9. Liquid level detector

    DOE Patents [OSTI]

    Grasso, Albert P.

    1986-01-01

    A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  10. Modeling Incoherent Electron Cloud Effects

    SciTech Connect (OSTI)

    Vay, Jean-Luc; Benedetto, E.; Fischer, W.; Franchetti, G.; Ohmi, K.; Schulte, D.; Sonnad, K.; Tomas, R.; Vay, J.-L.; Zimmermann, F.; Rumolo, G.; Pivi, M.; Raubenheimer, T.

    2007-06-18

    Incoherent electron effects could seriously limit the beam lifetime in proton or ion storage rings, such as LHC, SPS, or RHIC, or blow up the vertical emittance of positron beams, e.g., at the B factories or in linear-collider damping rings. Different approaches to modeling these effects each have their own merits and drawbacks. We describe several simulation codes which simplify the descriptions of the beam-electron interaction and of the accelerator structure in various different ways, and present results for a toy model of the SPS. In addition, we present evidence that for positron beams the interplay of incoherent electron-cloud effects and synchrotron radiation can lead to a significant increase in vertical equilibrium emittance. The magnitude of a few incoherent e+e- scattering processes is also estimated. Options for future code development are reviewed.

  11. ARM - Midlatitude Continental Convective Clouds

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jensen, Mike; Bartholomew, Mary Jane; Genio, Anthony Del; Giangrande, Scott; Kollias, Pavlos

    Convective processes play a critical role in the Earth's energy balance through the redistribution of heat and moisture in the atmosphere and their link to the hydrological cycle. Accurate representation of convective processes in numerical models is vital towards improving current and future simulations of Earths climate system. Despite improvements in computing power, current operational weather and global climate models are unable to resolve the natural temporal and spatial scales important to convective processes and therefore must turn to parameterization schemes to represent these processes. In turn, parameterization schemes in cloud-resolving models need to be evaluated for their generality and application to a variety of atmospheric conditions. Data from field campaigns with appropriate forcing descriptors have been traditionally used by modelers for evaluating and improving parameterization schemes.

  12. ARM - Midlatitude Continental Convective Clouds

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Jensen, Mike; Bartholomew, Mary Jane; Genio, Anthony Del; Giangrande, Scott; Kollias, Pavlos

    2012-01-19

    Convective processes play a critical role in the Earth's energy balance through the redistribution of heat and moisture in the atmosphere and their link to the hydrological cycle. Accurate representation of convective processes in numerical models is vital towards improving current and future simulations of Earths climate system. Despite improvements in computing power, current operational weather and global climate models are unable to resolve the natural temporal and spatial scales important to convective processes and therefore must turn to parameterization schemes to represent these processes. In turn, parameterization schemes in cloud-resolving models need to be evaluated for their generality and application to a variety of atmospheric conditions. Data from field campaigns with appropriate forcing descriptors have been traditionally used by modelers for evaluating and improving parameterization schemes.

  13. Photolysis rates in correlated overlapping cloud fields: Cloud-J 7.3c

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Prather, M. J.

    2015-08-14

    A new approach for modeling photolysis rates (J values) in atmospheres with fractional cloud cover has been developed and is implemented as Cloud-J – a multi-scattering eight-stream radiative transfer model for solar radiation based on Fast-J. Using observations of the vertical correlation of cloud layers, Cloud-J 7.3c provides a practical and accurate method for modeling atmospheric chemistry. The combination of the new maximum-correlated cloud groups with the integration over all cloud combinations by four quadrature atmospheres produces mean J values in an atmospheric column with root mean square (rms) errors of 4 % or less compared with 10–20 % errorsmore » using simpler approximations. Cloud-J is practical for chemistry–climate models, requiring only an average of 2.8 Fast-J calls per atmosphere vs. hundreds of calls with the correlated cloud groups, or 1 call with the simplest cloud approximations. Another improvement in modeling J values, the treatment of volatile organic compounds with pressure-dependent cross sections, is also incorporated into Cloud-J.« less

  14. Photolysis rates in correlated overlapping cloud fields: Cloud-J 7.3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Prather, M. J.

    2015-05-27

    A new approach for modeling photolysis rates (J values) in atmospheres with fractional cloud cover has been developed and implemented as Cloud-J – a multi-scattering eight-stream radiative transfer model for solar radiation based on Fast-J. Using observed statistics for the vertical correlation of cloud layers, Cloud-J 7.3 provides a practical and accurate method for modeling atmospheric chemistry. The combination of the new maximum-correlated cloud groups with the integration over all cloud combinations represented by four quadrature atmospheres produces mean J values in an atmospheric column with root-mean-square errors of 4% or less compared with 10–20% errors using simpler approximations. Cloud-Jmore » is practical for chemistry-climate models, requiring only an average of 2.8 Fast-J calls per atmosphere, vs. hundreds of calls with the correlated cloud groups, or 1 call with the simplest cloud approximations. Another improvement in modeling J values, the treatment of volatile organic compounds with pressure-dependent cross sections is also incorporated into Cloud-J.« less

  15. Evaluation of high-level clouds in cloud resolving model simulations with ARM and KWAJEX observations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zheng; Muhlbauer, Andreas; Ackerman, Thomas

    2015-11-05

    In this paper, we evaluate high-level clouds in a cloud resolving model during two convective cases, ARM9707 and KWAJEX. The simulated joint histograms of cloud occurrence and radar reflectivity compare well with cloud radar and satellite observations when using a two-moment microphysics scheme. However, simulations performed with a single moment microphysical scheme exhibit low biases of approximately 20 dB. During convective events, two-moment microphysical overestimate the amount of high-level cloud and one-moment microphysics precipitate too readily and underestimate the amount and height of high-level cloud. For ARM9707, persistent large positive biases in high-level cloud are found, which are not sensitivemore » to changes in ice particle fall velocity and ice nuclei number concentration in the two-moment microphysics. These biases are caused by biases in large-scale forcing and maintained by the periodic lateral boundary conditions. The combined effects include significant biases in high-level cloud amount, radiation, and high sensitivity of cloud amount to nudging time scale in both convective cases. The high sensitivity of high-level cloud amount to the thermodynamic nudging time scale suggests that thermodynamic nudging can be a powerful ‘‘tuning’’ parameter for the simulated cloud and radiation but should be applied with caution. The role of the periodic lateral boundary conditions in reinforcing the biases in cloud and radiation suggests that reducing the uncertainty in the large-scale forcing in high levels is important for similar convective cases and has far reaching implications for simulating high-level clouds in super-parameterized global climate models such as the multiscale modeling framework.« less

  16. Evaluation of Cloud-resolving and Limited Area Model Intercomparison Simulations using TWP-ICE Observations. Part 1: Deep Convective Updraft Properties

    SciTech Connect (OSTI)

    Varble, A. C.; Zipser, Edward J.; Fridlind, Ann; Zhu, Ping; Ackerman, Andrew; Chaboureau, Jean-Pierre; Collis, Scott M.; Fan, Jiwen; Hill, Adrian; Shipway, Ben

    2014-12-27

    Ten 3D cloud-resolving model (CRM) simulations and four 3D limited area model (LAM) simulations of an intense mesoscale convective system observed on January 23-24, 2006 during the Tropical Warm Pool International Cloud Experiment (TWP-ICE) are compared with each other and with observed radar reflectivity fields and dual-Doppler retrievals of vertical wind speeds in an attempt to explain published results showing a high bias in simulated convective radar reflectivity aloft. This high bias results from ice water content being large, which is a product of large, strong convective updrafts, although hydrometeor size distribution assumptions modulate the size of this bias. Snow reflectivity can exceed 40 dBZ in a two-moment scheme when a constant bulk density of 100 kg m-3 is used. Making snow mass more realistically proportional to area rather than volume should somewhat alleviate this problem. Graupel, unlike snow, produces high biased reflectivity in all simulations. This is associated with large amounts of liquid water above the freezing level in updraft cores. Peak vertical velocities in deep convective updrafts are greater than dual-Doppler retrieved values, especially in the upper troposphere. Freezing of large rainwater contents lofted above the freezing level in simulated updraft cores greatly contributes to these excessive upper tropospheric vertical velocities. Strong simulated updraft cores are nearly undiluted, with some showing supercell characteristics. Decreasing horizontal grid spacing from 900 meters to 100 meters weakens strong updrafts, but not enough to match observational retrievals. Therefore, overly intense simulated updrafts may partly be a product of interactions between convective dynamics, parameterized microphysics, and large-scale environmental biases that promote different convective modes and strengths than observed.

  17. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, M.E.; Sullivan, W.H.

    A precision liquid level sensor utilizes a balanced bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

  18. Understanding Ice Supersaturation, Particle Growth, and Number Concentration in Cirrus Clouds

    SciTech Connect (OSTI)

    Comstock, Jennifer M.; Lin, Ruei-Fong; Starr, David O.; Yang, P.

    2008-12-10

    Many factors control the ice supersaturation and microphysical properties in cirrus clouds. We explore the effects of dynamic forcing, ice nucleation mechanisms, and ice crystal growth rate on the evolution and distribution of water vapor and cloud properties in cirrus clouds using a detailed microphysical model and remote sensing measurements obtained at the Department of Energys Atmospheric Radiation Measurement (ARM) Climate Research Facility located near Lamont, OK. To help understand dynamic scales important in cirrus formation, we force the model using both large-scale forcing derived using ARM variational analysis, and mean mesoscale velocity derived from radar Doppler velocity measurements. Both heterogeneous and homogeneous nucleation processes are explored, where we have implemented a rigorous classical theory heterogeneous nucleation scheme to compare with empirical representations. We evaluate model simulations by examining both bulk cloud properties and distributions of measured radar reflectivity, lidar extinction, and water vapor profiles, as well as retrieved cloud microphysical properties. This approach allows for independent verification of both the large and small particle modes of the particle size distribution. Our results suggest that mesoscale variability is the primary mechanism needed to reproduce observed quantities, while nucleation mechanism is secondary. Slow ice crystal growth tends to overestimate the number of small ice crystals, but does not seem to influence bulk properties such as ice water path and cloud thickness. The most realistic simulations as compared with observations are forced using mesoscale waves, include fast ice crystal growth, and initiate ice by either homogeneous or heterogeneous nucleation. Ice crystal number concentrations on the order of 10-100 L-1 produce results consistent with both lidar and radar observations during a cirrus event observed on 7 December 1999, which has an optical depth range typical of midlatitude cirrus.

  19. Renewable liquid reflection grating

    DOE Patents [OSTI]

    Ryutov, Dmitri D.; Toor, Arthur

    2003-10-07

    A renewable liquid reflection grating. Electrodes are operatively connected to a conducting liquid in an arrangement that produces a reflection grating and driven by a current with a resonance frequency. In another embodiment, the electrodes create the grating by a resonant electrostatic force acting on a dielectric liquid.

  20. Super recycled water: quenching computers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Super recycled water: quenching computers Super recycled water: quenching computers New facility and methods support conserving water and creating recycled products. Using reverse osmosis to "super purify" water allows the system to reuse water and cool down our powerful yet thirsty computers. January 30, 2014 Super recycled water: quenching computers LANL's Sanitary Effluent Reclamation Facility, key to reducing the Lab's discharge of liquid. Millions of gallons of industrial

  1. Executive Summary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... probe FSSP, particle measuring system PMS, CPI) and cloud liquid water content (CVI, Rosemount Icing Meter), ARM lacks measurements of the CCN spectrum at cloud base. ...

  2. ARM - Publications: Science Team Meeting Documents: A Climatology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and lidar pair, and rawinsonde sounding; cloud liquid water path (LWP) is retrieved from ground-based microwave radiometer measured brightness temperature; and cloud-droplet...

  3. Section 8

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bulk geometry for liquid water cumulus clouds because individual clouds are nearly black. ... Observations from a whole sky imager (WSI), a micropulse lidar (MPL), and a ceilometer ...

  4. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  5. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, J.E.; Bolton, R.D.

    1999-03-02

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans. 4 figs.

  6. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, James E.; Bolton, Richard D.

    1999-01-01

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans.

  7. Method for removing organic liquids from aqueous solutions and mixtures

    DOE Patents [OSTI]

    Hrubesh, Lawrence W.; Coronado, Paul R.; Dow, Jerome P.

    2004-03-23

    A method for removing organic liquids from aqueous solutions and mixtures. The method employs any porous material preferably in granular form and having small pores and a large specific surface area, that is hydrophobic so that liquid water does not readily wet its surface. In this method, organics, especially organic solvents that mix with and are more volatile than water, are separated from aqueous solution by preferentially evaporating across the liquid/solid boundary formed at the surfaces of the hydrophobic porous materials. Also, organic solvents that are immiscible with water, preferentially wet the surfaces of the hydrophobic material and are drawn within the porous materials by capillary action.

  8. Evaluation of Cloud-Resolving Model Intercomparison Simulations Using TWP-ICE Observations: Precipitation and Cloud Structure

    SciTech Connect (OSTI)

    Varble, Adam C.; Fridlind, Ann; Zipser, Ed; Ackerman, Andrew; Chaboureau, Jean-Pierre; Fan, Jiwen; Hill, Adrian; McFarlane, Sally A.; Pinty, Jean-Pierre; Shipway, Ben

    2011-06-24

    The Tropical Warm Pool - International Cloud Experiment (TWP-ICE) provided high quality model forcing and observational datasets through which detailed model and observational intercomparisons could be performed. In this first of a two part study, precipitation and cloud structures within nine cloud-resolving model simulations are compared with scanning radar reflectivity and satellite infrared brightness temperature observations during an active monsoon period from 19 to 25 January 2006. Most simulations slightly overestimate volumetric convective rainfall. Overestimation of simulated convective area by 50% or more in several simulations is somewhat offset by underestimation of mean convective rain rates. Stratiform volumetric rainfall is underestimated by 13% to 53% despite overestimation of stratiform area by up to 65% because stratiform rain rates in every simulation are much lower than observed. Although simulations match the peaked convective radar reflectivity distribution at low levels, they do not reproduce the peaked distributions observed above the melting level. Simulated radar reflectivity aloft in convective regions is too high in most simulations. 29 In stratiform regions, there is a large spread in model results with none resembling 30 observed distributions. Above the melting level, observed radar reflectivity decreases 31 more gradually with height than simulated radar reflectivity. A few simulations produce 32 unrealistically uniform and cold 10.8-?m infrared brightness temperatures, but several 33 simulations produce distributions close to observed. Assumed ice particle size 34 distributions appear to play a larger role than ice water contents in producing incorrect 35 simulated radar reflectivity distributions aloft despite substantial differences in mean 36 graupel and snow water contents across models. 37

  9. HPC CLOUD APPLIED TO LATTICE OPTIMIZATION

    SciTech Connect (OSTI)

    Sun, Changchun; Nishimura, Hiroshi; James, Susan; Song, Kai; Muriki, Krishna; Qin, Yong

    2011-03-18

    As Cloud services gain in popularity for enterprise use, vendors are now turning their focus towards providing cloud services suitable for scientific computing. Recently, Amazon Elastic Compute Cloud (EC2) introduced the new Cluster Compute Instances (CCI), a new instance type specifically designed for High Performance Computing (HPC) applications. At Berkeley Lab, the physicists at the Advanced Light Source (ALS) have been running Lattice Optimization on a local cluster, but the queue wait time and the flexibility to request compute resources when needed are not ideal for rapid development work. To explore alternatives, for the first time we investigate running the Lattice Optimization application on Amazon's new CCI to demonstrate the feasibility and trade-offs of using public cloud services for science.

  10. Posters Sensitivity of Cirrus Cloud Radiative

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Takahashi, T., and K. Kuhara. 1993. Precipitation mechanisms of cumulonimbus clouds at Pohnpei, Micronesia. Meteor. Soc. Japan 71:21-31. Takano, Y., and K. N. Liou. 1989. Radiative ...

  11. Layered Atlantic Smoke Interactions with Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and atmospheric proIling, researchers will measure clouds, aerosol particles, and radiant energy. 7e ARM Facility, a national scientiIc user facility managed by the U.S. ...

  12. ARM - Field Campaign - Midlatitude Continental Convective Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Midlatitude Continental Convective Clouds Experiment (MC3E): Multi-Frequency...

  13. ARM - Field Campaign - Boundary Layer Cloud IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsBoundary Layer Cloud IOP Campaign Links Campaign Images ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us at...

  14. ARM - Field Campaign - Arctic Cloud Infrared Imaging

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Arctic Cloud Infrared Imaging 2012.07.16 - 2014.07.31 Lead Scientist : Joseph Shaw...

  15. QER- Comment of Cloud Peak Energy Inc

    Broader source: Energy.gov [DOE]

    Dear Ms Pickett Please find attached comments from Cloud Peak Energy as input to the Department of Energy’s Quadrennial Energy Review. If possible I would appreciate a confirmation that this email has been received Thank you.

  16. Building a private cloud with Open Nebula

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Short Ryan Glenn Ross Nordeen Mentors: Andree Jacobson ISTI-OFF David Kennel DCS-1 LA-UR 10-05197 Why use Virtualized Cloud Computing for HPC? * Support Legacy Software Stacks *...

  17. Retrievals of Cloud Fraction and Cloud Albedo from Surface-based Shortwave Radiation Measurements: A Comparison of 16 Year Measurements

    SciTech Connect (OSTI)

    Xie, Yu; Liu, Yangang; Long, Charles N.; Min, Qilong

    2014-07-27

    Ground-based radiation measurements have been widely conducted to gain information on clouds and the surface radiation budget; here several different techniques for retrieving cloud fraction (Long2006, Min2008 and XL2013) and cloud albedo (Min2008, Liu2011 and XL2013) from ground-based shortwave broadband and spectral radiation measurements are examined, and sixteen years of retrievals collected at the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site are compared. The comparison shows overall good agreement between the retrievals of both cloud fraction and cloud albedo, with noted differences however. The Long2006 and Min2008 cloud fractions are greater on average than the XL2013 values. Compared to Min2008 and Liu2011, the XL2013 retrieval of cloud albedo tends to be greater for thin clouds but smaller for thick clouds, with the differences decreasing with increasing cloud fraction. Further analysis reveals that the approaches that retrieve cloud fraction and cloud albedo separately may suffer from mutual contamination of errors in retrieved cloud fraction and cloud albedo. Potential influences of cloud absorption, land-surface albedo, cloud structure, and measurement instruments are explored.

  18. Instabilities during liquid migration into superheated hydrothermal systems

    SciTech Connect (OSTI)

    Fitzgerald, Shaun D.; Woods, Andrew W.

    1995-01-26

    Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor interface may become unstable and break up into fingers.

  19. RACORO continental boundary layer cloud investigations. 2. Large-eddy

    Office of Scientific and Technical Information (OSTI)

    simulations of cumulus clouds and evaluation with in-situ and ground-based observations (Journal Article) | SciTech Connect RACORO continental boundary layer cloud investigations. 2. Large-eddy simulations of cumulus clouds and evaluation with in-situ and ground-based observations Citation Details In-Document Search This content will become publicly available on June 19, 2016 Title: RACORO continental boundary layer cloud investigations. 2. Large-eddy simulations of cumulus clouds and

  20. Cloud Property Retrieval Products for Graciosa Island, Azores (Dataset) |

    Office of Scientific and Technical Information (OSTI)

    Data Explorer Data Explorer Search Results Cloud Property Retrieval Products for Graciosa Island, Azores Title: Cloud Property Retrieval Products for Graciosa Island, Azores The motivation for developing this product was to use the Dong et al. 1998 method to retrieve cloud microphysical properties, such as cloud droplet effective radius, cloud droplets number concentration, and optical thickness. These retrieved properties have been used to validate the satellite retrieval, and evaluate the

  1. Cloud-Scale Vertical Velocity and Turbulent Dissipation Rate Retrievals

    Office of Scientific and Technical Information (OSTI)

    (Dataset) | Data Explorer Data Explorer Search Results Cloud-Scale Vertical Velocity and Turbulent Dissipation Rate Retrievals Title: Cloud-Scale Vertical Velocity and Turbulent Dissipation Rate Retrievals Time-height fields of retrieved in-cloud vertical wind velocity and turbulent dissipation rate, both retrieved primarily from vertically-pointing, Ka-band cloud radar measurements. Files are available for manually-selected, stratiform, mixed-phase cloud cases observed at the North Slope of

  2. ARM - Publications: Science Team Meeting Documents: Day and Night cloud

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fraction - Cloud Inter-Compariosn IOP results Day and Night cloud fraction - Cloud Inter-Compariosn IOP results Genkova, Iliana University of Illinois-Champaign Long, Chuck Pacific Northwest National Laboratory Turner, David Pacific Northwest National Laboratory We present results from the CIC IOP from March-may, 2003. Day time and night time cloud fraction retrieval algorithms have been presented and intercompared. Amount of low, middle and high cloud have been estimated and compared to

  3. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    2008-01-15

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  4. Ignition of Aluminum Particles and Clouds

    SciTech Connect (OSTI)

    Kuhl, A L; Boiko, V M

    2010-04-07

    Here we review experimental data and models of the ignition of aluminum (Al) particles and clouds in explosion fields. The review considers: (i) ignition temperatures measured for single Al particles in torch experiments; (ii) thermal explosion models of the ignition of single Al particles; and (iii) the unsteady ignition Al particles clouds in reflected shock environments. These are used to develop an empirical ignition model appropriate for numerical simulations of Al particle combustion in shock dispersed fuel explosions.

  5. Electron-Cloud Build-Up: Summary

    SciTech Connect (OSTI)

    Furman, M.A.

    2007-06-18

    I present a summary of topics relevant to the electron-cloud build-up and dissipation that were presented at the International Workshop on Electron-Cloud Effects 'ECLOUD 07' (Daegu, S. Korea, April 9-12, 2007). This summary is not meant to be a comprehensive review of the talks. Rather, I focus on those developments that I found, in my personal opinion, especially interesting. The contributions, all excellent, are posted in http://chep.knu.ac.kr/ecloud07/.

  6. ARM Cloud Properties Working Group: Meeting Logistics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Properties WG Breakout Session 2008 ARM Science Team Meeting Mar. 10, 2008, Norfolk, VA Monday March 10, 2008 1500 to 1515: R. Hogan - A Proposal for ARM support of Cloudnet Activities 1515 to 1530: M. Jensen - Cloud Properties Value- Added Product Development 1530 to 1545: C. Long - Instrument Group Report 1545 to 1600: S. Matrosov - WSR-88D data for ARM science 1600 to 1615: Y. Zhao - A BimodalParticle Distribution Assumption in Cirrus: Comparison of retrieval results with in situ

  7. Science on the Hill: Methane cloud hunting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane cloud hunting Science on the Hill: Methane cloud hunting Los Alamos researchers go hunting for methane gas over the Four Corners area of northwest New Mexico and find a strange daily pattern. July 12, 2015 methane map Methane, the primary component of natural gas, is also a potent greenhouse gas, trapping energy in the atmosphere. Last year NASA released satellite images showing a hot spot in the area where New Mexico, Colorado, Utah and Arizona meet, prompting scientists to go in search

  8. Atmospheric State, Cloud Microphysics and Radiative Flux

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Mace, Gerald

    Atmospheric thermodynamics, cloud properties, radiative fluxes and radiative heating rates for the ARM Southern Great Plains (SGP) site. The data represent a characterization of the physical state of the atmospheric column compiled on a five-minute temporal and 90m vertical grid. Sources for this information include raw measurements, cloud property and radiative retrievals, retrievals and derived variables from other third-party sources, and radiative calculations using the derived quantities.

  9. QUANTITATIVELY ASSESSING THE ROLE OF CLOUDS IN THE TRANSMISSION SPECTRUM OF GJ 1214b

    SciTech Connect (OSTI)

    Morley, Caroline V.; Fortney, Jonathan J.; Kempton, Eliza M.-R.; Marley, Mark S.; Zahnle, Kevin; Vissher, Channon

    2013-09-20

    Recent observations of the super-Earth GJ 1214b show that it has a relatively featureless transmission spectrum. One suggestion is that these observations indicate that the planet's atmosphere is vertically compact, perhaps due to a water-rich composition that yields a large mean molecular weight. Another suggestion is that the atmosphere is hydrogen/helium-rich with clouds that obscure predicted absorption features. Previous models that incorporate clouds have included their effect without a strong physical motivation for their existence. Here, we present model atmospheres of GJ 1214b that include physically motivated clouds of two types. We model the clouds that are present in chemical equilibrium, as has been suggested to occur on brown dwarfs, which include KCl and ZnS for this planet. We also include clouds that form as a result of photochemistry, forming a hydrocarbon haze layer. We use a photochemical kinetics model to understand the vertical distribution and available mass of haze-forming molecules. We model both solar and enhanced-metallicity cloudy models and determine the cloud properties necessary to match observations. In enhanced-metallicity atmospheres, we find that the equilibrium clouds can match the observations of GJ 1214b if they are lofted high into the atmosphere and have a low sedimentation efficiency (f{sub sed} = 0.1). We find that models with a variety of hydrocarbon haze properties can match the observations. Particle sizes from 0.01 to 0.25 ?m can match the transmission spectrum with haze-forming efficiencies as low as 1%-5%.

  10. Star formation relations in nearby molecular clouds

    SciTech Connect (OSTI)

    Evans, Neal J. II; Heiderman, Amanda; Vutisalchavakul, Nalin

    2014-02-20

    We test some ideas for star formation relations against data on local molecular clouds. On a cloud by cloud basis, the relation between the surface density of star formation rate and surface density of gas divided by a free-fall time, calculated from the mean cloud density, shows no significant correlation. If a crossing time is substituted for the free-fall time, there is even less correlation. Within a cloud, the star formation rate volume and surface densities increase rapidly with the corresponding gas densities, faster than predicted by models using the free-fall time defined from the local density. A model in which the star formation rate depends linearly on the mass of gas above a visual extinction of 8 mag describes the data on these clouds, with very low dispersion. The data on regions of very massive star formation, with improved star formation rates based on free-free emission from ionized gas, also agree with this linear relation.

  11. Humidity trends imply increased sensitivity to clouds in a warming Arctic

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cox, Christopher J.; Walden, Von P.; Rowe, Penny M.; Shupe, Matthew D.

    2015-12-10

    Infrared radiative processes are implicated in Arctic warming and sea-ice decline. The infrared cloud radiative effect (CRE) at the surface is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. Here we show how temperature and humidity control CRE through competing influences between the mid- and far-infrared. At constant relative humidity, CRE does not decrease with increasing temperature/absolute humidity as expected, but rather is found to be approximately constant for temperatures characteristic of the Arctic. This stability is disrupted if relative humidity varies. Ourmore » findings explain observed seasonal and regional variability in Arctic CRE of order 10Wm 2. With the physical properties of Arctic clouds held constant, we calculate recent increases in CRE of 1–5Wm 2 in autumn and winter, which are projected to reach 5–15Wm 2 by 2050, implying increased sensitivity of the surface to clouds.« less

  12. Humidity trends imply increased sensitivity to clouds in a warming Arctic

    SciTech Connect (OSTI)

    Cox, Christopher J.; Walden, Von P.; Rowe, Penny M.; Shupe, Matthew D.

    2015-12-10

    Infrared radiative processes are implicated in Arctic warming and sea-ice decline. The infrared cloud radiative effect (CRE) at the surface is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. Here we show how temperature and humidity control CRE through competing influences between the mid- and far-infrared. At constant relative humidity, CRE does not decrease with increasing temperature/absolute humidity as expected, but rather is found to be approximately constant for temperatures characteristic of the Arctic. This stability is disrupted if relative humidity varies. Our findings explain observed seasonal and regional variability in Arctic CRE of order 10Wm 2. With the physical properties of Arctic clouds held constant, we calculate recent increases in CRE of 1–5Wm 2 in autumn and winter, which are projected to reach 5–15Wm 2 by 2050, implying increased sensitivity of the surface to clouds.

  13. ARM - VAP Process - ndrop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and liquid water path. They show that the magnitude of the aerosol-cloud interactions (ACI) varies with a range of factors, including the relative value of the cloud liquid water...

  14. Liquid level detector

    DOE Patents [OSTI]

    Tshishiku, Eugene M.

    2011-08-09

    A liquid level detector for conductive liquids for vertical installation in a tank, the detector having a probe positioned within a sheath and insulated therefrom by a seal so that the tip of the probe extends proximate to but not below the lower end of the sheath, the lower end terminating in a rim that is provided with notches, said lower end being tapered, the taper and notches preventing debris collection and bubble formation, said lower end when contacting liquid as it rises will form an airtight cavity defined by the liquid, the interior sheath wall, and the seal, the compression of air in the cavity preventing liquid from further entry into the sheath and contact with the seal. As a result, the liquid cannot deposit a film to form an electrical bridge across the seal.

  15. Derivation of Seasonal Cloud Properties at ARM-NSA from Multispectral...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In this paper, the operational Clouds and the Earth's Radiant Energy System (CERES) cloud ... In Clouds and the Earth's Radiant Energy System (CERES) Algorithm Theoretical Basis ...

  16. Protective tubes for sodium heated water tubes

    DOE Patents [OSTI]

    Essebaggers, Jan

    1979-01-01

    A heat exchanger in which water tubes are heated by liquid sodium which minimizes the results of accidental contact between the water and the sodium caused by failure of one or more of the water tubes. A cylindrical protective tube envelopes each water tube and the sodium flows axially in the annular spaces between the protective tubes and the water tubes.

  17. LIQUID CYCLONE CONTACTOR

    DOE Patents [OSTI]

    Whatley, M.E.; Woods, W.M.

    1962-09-01

    This invention relates to liquid-liquid extraction systems. The invention, an improved hydroclone system, comprises a series of serially connected, axially aligned hydroclones, each of which is provided with an axially aligned overflow chamber. The chambers are so arranged that rotational motion of a fluid being passed through the system is not lost in passing from chamber to chamber; consequently, this system is highly efficient in contacting and separating two immiscible liquids. (AEC)

  18. The Midlatitude Continental Convective Clouds Experiment (MC3E)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jensen, M. P.; Petersen, W. A.; Bansemer, A.; Bharadwaj, N.; Carey, L. D.; Cecil, D. J.; Collis, S. M.; DelGenio, A. D.; Dolan, B.; Gerlach, J.; et al

    2015-12-18

    The Midlatitude Continental Convective Clouds Experiment (MC3E), a field program jointly led by the U.S. Department of Energy’s Atmospheric Radiation Measurement program and the NASA Global Precipitation Measurement (GPM) Mission, was conducted in south-central Oklahoma during April – May 2011. MC3E science objectives were motivated by the need to improve understanding of midlatitude continental convective cloud system lifecycles, microphysics, and GPM precipitation retrieval algorithms. To achieve these objectives a multi-scale surface- and aircraft-based in situ and remote sensing observing strategy was employed. A variety of cloud and precipitation events were sampled during the MC3E, of which results from three deepmore » convective events are highlighted. Vertical structure, air motions, precipitation drop-size distributions and ice properties were retrieved from multi-wavelength radar, profiler, and aircraft observations for an MCS on 11 May. Aircraft observations for another MCS observed on 20 May were used to test agreement between observed radar reflectivities and those calculated with forward-modeled reflectivity and microwave brightness temperatures using in situ particle size distributions and ice water content. Multi-platform observations of a supercell that occurred on 23 May allowed for an integrated analysis of kinematic and microphysical interactions. A core updraft of 25 ms-1 supported growth of hail and large rain drops. As a result, data collected during the MC3E campaign is being used in a number of current and ongoing research projects and is available through the DOE ARM and NASA data archives.« less

  19. The Midlatitude Continental Convective Clouds Experiment (MC3E)

    SciTech Connect (OSTI)

    Jensen, M. P.; Petersen, W. A.; Bansemer, A.; Bharadwaj, N.; Carey, L. D.; Cecil, D. J.; Collis, S. M.; DelGenio, A. D.; Dolan, B.; Gerlach, J.; Giangrande, S. E.; Heymsfield, A.; Heymsfield, G.; Kollias, P.; Lang, T. J.; Nesbitt, S. W.; Neumann, A.; Poellot, M.; Rutledge, S. A.; Schwaller, M.; Tokay, A.; Williams, C. R.; Wolff, D. B.; Xie, S.; Zipser, E. J.

    2015-12-18

    The Midlatitude Continental Convective Clouds Experiment (MC3E), a field program jointly led by the U.S. Department of Energy’s Atmospheric Radiation Measurement program and the NASA Global Precipitation Measurement (GPM) Mission, was conducted in south-central Oklahoma during April – May 2011. MC3E science objectives were motivated by the need to improve understanding of midlatitude continental convective cloud system lifecycles, microphysics, and GPM precipitation retrieval algorithms. To achieve these objectives a multi-scale surface- and aircraft-based in situ and remote sensing observing strategy was employed. A variety of cloud and precipitation events were sampled during the MC3E, of which results from three deep convective events are highlighted. Vertical structure, air motions, precipitation drop-size distributions and ice properties were retrieved from multi-wavelength radar, profiler, and aircraft observations for an MCS on 11 May. Aircraft observations for another MCS observed on 20 May were used to test agreement between observed radar reflectivities and those calculated with forward-modeled reflectivity and microwave brightness temperatures using in situ particle size distributions and ice water content. Multi-platform observations of a supercell that occurred on 23 May allowed for an integrated analysis of kinematic and microphysical interactions. A core updraft of 25 ms-1 supported growth of hail and large rain drops. As a result, data collected during the MC3E campaign is being used in a number of current and ongoing research projects and is available through the DOE ARM and NASA data archives.

  20. Gas scrubbing liquids

    DOE Patents [OSTI]

    Lackey, Walter J.; Lowrie, Robert S.; Sease, John D.

    1981-01-01

    Fully chlorinated and/or fluorinated hydrocarbons are used as gas scrubbing liquids for preventing noxious gas emissions to the atmosphere.

  1. Liquid Crystal Optofluidics

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

    2012-10-11

    By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

  2. RENEWABLE LIQUID GETTERING PUMP

    DOE Patents [OSTI]

    Batzer, T.H.

    1962-08-21

    A method and structure were developed for pumping gases by simple absorption into a liquid gettering material. The invention comprises means ror continuously pumping a liquid getterrng material from a reservoir to the top of a generally vertical surface disposed in a vacuum pumping chamber to receive gaseous and other particles in the liquid gettering material which continuously flows downward over the vertical suiface. Means are provided for continuous removal, degassing, and return of a portion of the liquid gettering material from the reservoir connected with collectrng means at the base of the generally vertical plate. (AEC)

  3. HV in Noble Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Noble Liquids 8 Nov 2013 High Voltage Tests for MicroBooNE Byron Lundberg Fermilab presenting for the Collaboration & Task Force 4 1 Friday, November 8, 13 HV in Noble Liquids MicroBooNE Experiment  A liquid argon time projection chamber (LAr TPC) containing 170 tons of liquid argon, and located on the Booster Neutrino Beamline.  MiniBooNE  MicroBooNE 8,#256#wires;#U,V,Y#planes;#3#mm#spacing# 32#PMTs#for#fast#light#collec?ons# @ L A r T F 2 Friday, November 8, 13 HV in Noble

  4. Ultrasonic liquid level detector

    DOE Patents [OSTI]

    Kotz, Dennis M.; Hinz, William R.

    2010-09-28

    An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

  5. Liquid Propane Injection Applications

    Broader source: Energy.gov [DOE]

    Liquid propane injection technology meets manufacturing/assembly guidelines, maintenance/repair strategy, and regulations, with same functionality, horsepower, and torque as gasoline counterpart.

  6. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    SciTech Connect (OSTI)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-11-06

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice number is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 ?m for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.

  7. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    SciTech Connect (OSTI)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-12-01

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice number is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 ?m for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.

  8. Investigating ice nucleation in cirrus clouds with an aerosol-enabled Multiscale Modeling Framework

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Chengzhu; Wang, Minghuai; Morrison, H.; Somerville, Richard C.; Zhang, Kai; Liu, Xiaohong; Li, J-L F.

    2014-11-06

    In this study, an aerosol-dependent ice nucleation scheme [Liu and Penner, 2005] has been implemented in an aerosol-enabled multi-scale modeling framework (PNNL MMF) to study ice formation in upper troposphere cirrus clouds through both homogeneous and heterogeneous nucleation. The MMF model represents cloud scale processes by embedding a cloud-resolving model (CRM) within each vertical column of a GCM grid. By explicitly linking ice nucleation to aerosol number concentration, CRM-scale temperature, relative humidity and vertical velocity, the new MMF model simulates the persistent high ice supersaturation and low ice number concentration (10 to 100/L) at cirrus temperatures. The low ice numbermore » is attributed to the dominance of heterogeneous nucleation in ice formation. The new model simulates the observed shift of the ice supersaturation PDF towards higher values at low temperatures following homogeneous nucleation threshold. The MMF models predict a higher frequency of midlatitude supersaturation in the Southern hemisphere and winter hemisphere, which is consistent with previous satellite and in-situ observations. It is shown that compared to a conventional GCM, the MMF is a more powerful model to emulate parameters that evolve over short time scales such as supersaturation. Sensitivity tests suggest that the simulated global distribution of ice clouds is sensitive to the ice nucleation schemes and the distribution of sulfate and dust aerosols. Simulations are also performed to test empirical parameters related to auto-conversion of ice crystals to snow. Results show that with a value of 250 μm for the critical diameter, Dcs, that distinguishes ice crystals from snow, the model can produce good agreement to the satellite retrieved products in terms of cloud ice water path and ice water content, while the total ice water is not sensitive to the specification of Dcs value.« less

  9. Impacts of aerosol-cloud interactions on past and future changes in tropospheric composition

    SciTech Connect (OSTI)

    Unger, N.; Menon, S.; Shindell, D. T.; Koch, D. M.

    2009-02-02

    The development of effective emissions control policies that are beneficial to both climate and air quality requires a detailed understanding of all the feedbacks in the atmospheric composition and climate system. We perform sensitivity studies with a global atmospheric composition-climate model to assess the impact of aerosols on tropospheric chemistry through their modification on clouds, aerosol-cloud interactions (ACI). The model includes coupling between both tropospheric gas-phase and aerosol chemistry and aerosols and liquid-phase clouds. We investigate past impacts from preindustrial (PI) to present day (PD) and future impacts from PD to 2050 (for the moderate IPCC A1B scenario) that embrace a wide spectrum of precursor emission changes and consequential ACI. The aerosol indirect effect (AIE) is estimated to be -2.0 Wm{sup -2} for PD-PI and -0.6 Wm{sup -2} for 2050-PD, at the high end of current estimates. Inclusion of ACI substantially impacts changes in global mean methane lifetime across both time periods, enhancing the past and future increases by 10% and 30%, respectively. In regions where pollution emissions increase, inclusion of ACI leads to 20% enhancements in in-cloud sulfate production and {approx}10% enhancements in sulfate wet deposition that is displaced away from the immediate source regions. The enhanced in-cloud sulfate formation leads to larger increases in surface sulfate across polluted regions ({approx}10-30%). Nitric acid wet deposition is dampened by 15-20% across the industrialized regions due to ACI allowing additional re-release of reactive nitrogen that contributes to 1-2 ppbv increases in surface ozone in outflow regions. Our model findings indicate that ACI must be considered in studies of methane trends and projections of future changes to particulate matter air quality.

  10. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, M.E.; Sullivan, W.H.

    1985-01-29

    A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge. 2 figs.

  11. Synthesis of ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng [Knoxville, TN; Luo, Huimin [Knoxville, TN

    2008-09-09

    Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic liqand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

  12. Synthesis of ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Luo, Huimin (Knoxville, TN)

    2011-11-01

    Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic ligand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

  13. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, Michael E. (Albuquerque, NM); Sullivan, William H. (Albuquerque, NM)

    1985-01-01

    A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

  14. Liquid heat capacity lasers

    DOE Patents [OSTI]

    Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

    2007-05-01

    The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

  15. Magellan: experiences from a Science Cloud

    SciTech Connect (OSTI)

    Ramakrishnan, Lavanya; Zbiegel, Piotr; Campbell, Scott; Bradshaw, Rick; Canon, Richard; Coghlan, Susan; Sakrejda, Iwona; Desai, Narayan; Declerck, Tina; Liu, Anping

    2011-02-02

    Cloud resources promise to be an avenue to address new categories of scientific applications including data-intensive science applications, on-demand/surge computing, and applications that require customized software environments. However, there is a limited understanding on how to operate and use clouds for scientific applications. Magellan, a project funded through the Department of Energy?s (DOE) Advanced Scientific Computing Research (ASCR) program, is investigating the use of cloud computing for science at the Argonne Leadership Computing Facility (ALCF) and the National Energy Research Scientific Computing Facility (NERSC). In this paper, we detail the experiences to date at both sites and identify the gaps and open challenges from both a resource provider as well as application perspective.

  16. Kinetics of complex plasma with liquid droplets

    SciTech Connect (OSTI)

    Misra, Shikha; Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India); Mishra, S. K. [Institute for Plasma Research (IPR), Gandhinagar 382428 (India)] [Institute for Plasma Research (IPR), Gandhinagar 382428 (India)

    2013-12-15

    This paper provides a theoretical basis for the reduction of electron density by spray of water (or other liquids) in hot plasma. This phenomenon has been observed in a hypersonic flight experiment for relief of radio black out, caused by high ionization in the plasma sheath of a hypersonic vehicle, re-entering the atmosphere. The analysis incorporates a rather little known phenomenon for de-charging of the droplets, viz., evaporation of ions from the surface and includes the charge balance on the droplets and number cum energy balance of electrons, ions, and neutral molecules; the energy balance of the evaporating droplets has also been taken into account. The analysis has been applied to a realistic situation and the transient variations of the charge and radius of water droplets, and other plasma parameters have been obtained and discussed. The analysis through made in the context of water droplets is applicable to all liquids.

  17. Cloud-based Architecture Capabilities Summary Report

    SciTech Connect (OSTI)

    Vang, Leng; Prescott, Steven R; Smith, Curtis

    2014-09-01

    In collaborating scientific research arena it is important to have an environment where analysts have access to a shared of information documents, software tools and be able to accurately maintain and track historical changes in models. A new cloud-based environment would be accessible remotely from anywhere regardless of computing platforms given that the platform has available of Internet access and proper browser capabilities. Information stored at this environment would be restricted based on user assigned credentials. This report reviews development of a Cloud-based Architecture Capabilities (CAC) as a web portal for PRA tools.

  18. ARM - Field Campaign - Thin Cloud Rotating Shadowband Radiometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thin Cloud Rotating Shadowband Radiometer 2008.01.08 - 2008.07.18 Lead Scientist : Mary Jane Bartholomew For data sets, see below. Abstract The Thin-Cloud Rotating Shadowband...

  19. Analysis of In situ Observations of Cloud Microphysics from M...

    Office of Scientific and Technical Information (OSTI)

    Cloud Microphysics from M-PACE Final Report, DOE Grant Agreement No. DE-FG02-06ER64168 Citation Details In-Document Search Title: Analysis of In situ Observations of Cloud ...

  20. A TWP-ICE High-Level Cloud Case Study

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A TWP-ICE High-Level Cloud Case Study Mace, Gerald University of Utah Category: Field Campaigns The Tropical Warm Pool International Cloud Experiment (TWP ICE) was conducted near...

  1. Microsoft Word - Group3Cloud Properties(RS).docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... for (a) column clouds and (b) circle clouds. 2.0 References Clothiaux, EE, TP Ackerman, GG Mace, KP Moran, RT Marchand, MA Miller, and BE Martner. 2000. "Objective determination ...

  2. ARM - Evaluation Product - ARM Cloud Retrieval Ensemble Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : ARM Cloud Retrieval Ensemble Data The ARM Cloud Retrieval Ensemble Data (ACRED) set...

  3. ARM - PI Product - Cloud Properties and Radiative Heating Rates...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : Cloud Properties and Radiative Heating Rates for TWP A cloud properties and...

  4. E-Cloud Build-up in Grooved Chambers

    SciTech Connect (OSTI)

    Venturini, Marco

    2007-05-01

    We simulate electron cloud build-up in a grooved vacuumchamber including the effect of space charge from the electrons. Weidentify conditions for e-cloud suppression and make contact withprevious estimates of an effective secondary electron yield for groovedsurfaces.

  5. Biogenic Aerosols„Effects on Clouds and Climate (BAECC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biogenic Aerosols-Effects on Clouds and Climate (BAECC) Final Campaign Summary T Petj ... DOESC-ARM-15-051 Biogenic Aerosols-Effects on Clouds and Climate (BAECC) Final Campaign ...

  6. ARM - Field Campaign - Marine ARM GPCI Investigations of Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Marine ARM GPCI Investigations of Clouds (MAGIC): Cloud Properties from Zenith...

  7. ARM - Field Campaign - Biogenic Aerosols - Effects on Clouds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate Campaign Links BAECC Website ARM Data Discovery Browse Data Related Campaigns Biogenic Aerosols - Effects on Clouds and Climate: Cloud OD Sensor TWST 2014.06.15, Scott, AMF...

  8. Simulation of E-Cloud Driven Instability And Its Attenuation...

    Office of Scientific and Technical Information (OSTI)

    Simulation of E-Cloud Driven Instability And Its Attenuation Using a Feedback System in the CERN SPS Citation Details In-Document Search Title: Simulation of E-Cloud Driven ...

  9. The relationship between interannual and long-term cloud feedbacks

    SciTech Connect (OSTI)

    Zhou, Chen; Zelinka, Mark D.; Dessler, Andrew E.; Klein, Stephen A.

    2015-12-11

    The analyses of Coupled Model Intercomparison Project phase 5 simulations suggest that climate models with more positive cloud feedback in response to interannual climate fluctuations also have more positive cloud feedback in response to long-term global warming. Ensemble mean vertical profiles of cloud change in response to interannual and long-term surface warming are similar, and the ensemble mean cloud feedback is positive on both timescales. However, the average long-term cloud feedback is smaller than the interannual cloud feedback, likely due to differences in surface warming pattern on the two timescales. Low cloud cover (LCC) change in response to interannual and long-term global surface warming is found to be well correlated across models and explains over half of the covariance between interannual and long-term cloud feedback. In conclusion, the intermodel correlation of LCC across timescales likely results from model-specific sensitivities of LCC to sea surface warming.

  10. Comparison of Cloud Top Height and Optical Depth Histograms from...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and is not sensitive to the sensor calibration. The technique does, however, require finding the same cloud-top features in multiple views of the same cloud scene. The MODIS...

  11. Simulation of E-Cloud Driven Instability And Its Attenuation...

    Office of Scientific and Technical Information (OSTI)

    of E-Cloud Driven Instability And Its Attenuation Using a Feedback System in the CERN SPS Citation Details In-Document Search Title: Simulation of E-Cloud Driven Instability...

  12. Renewable liquid reflecting zone plate

    DOE Patents [OSTI]

    Toor, Arthur; Ryutov, Dmitri D.

    2003-12-09

    A renewable liquid reflecting zone plate. Electrodes are operatively connected to a dielectric liquid in a circular or other arrangement to produce a reflecting zone plate. A system for renewing the liquid uses a penetrable substrate.

  13. Technical Sessions Parameterization of Convective Clouds, Mesoscale Convective Systems,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Parameterization of Convective Clouds, Mesoscale Convective Systems, and Convective-Generated Clouds W. R. Cotton Department of Atmospheric Science Colorado State University Fort Collins, CO 80523 This presentation is a summary of research progress supported under the Atmospheric Radiation Measurement (ARM) project entitled "Parameterization of Convective Clouds, Mesoscale Convective Systems, and Con'o'ective-Generated Clouds." The approach used in this research is to perform explicit

  14. To the Cloud! Apidae Helps Modelers Turn Information into Knowledge |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy To the Cloud! Apidae Helps Modelers Turn Information into Knowledge To the Cloud! Apidae Helps Modelers Turn Information into Knowledge October 26, 2015 - 2:41pm Addthis Apidae is a collection of cloud-based simulation and data analysis tools that help modelers better understand their models. Image credit: BUILDlab. Apidae is a collection of cloud-based simulation and data analysis tools that help modelers better understand their models. Image credit: BUILDlab. Apidae

  15. LES Modeling of High Resolution Satellite Cloud Spatial and Thermal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure at ARM-SGP site: How well can we Simulate Clouds from Space? LES Modeling of High Resolution Satellite Cloud Spatial and Thermal Structure at ARM-SGP site: How well can we Simulate Clouds from Space? Dubey, Manvendra DOE/Los Alamos National Laboratory Chylek, Petr DOE/Los Alamos National Laboratory Reisner, Jon Los Alamos National Laboratory Porch, William Los Alamos National Laboratory Category: Cloud Properties We report high fidelity observations of the spatial and thermal

  16. Direct Numerical Simulations and Robust Predictions of Cloud Cavitation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Collapse | Argonne Leadership Computing Facility Initiation of cloud cavitation collapse for 50,000 bubbles Initiation of cloud cavitation collapse for 50,000 bubbles. Jonas Sukys, ETH Zurich Direct Numerical Simulations and Robust Predictions of Cloud Cavitation Collapse PI Name: Petros Koumoutsakos PI Email: petros@ethz.ch Institution: ETH Zurich Allocation Program: INCITE Allocation Hours at ALCF: 72 Million Year: 2016 Research Domain: Engineering Cloud cavitation collapse-the evolution

  17. Parameterizations of Cloud Microphysics and Indirect Aerosol Effects

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Parameterizations of Cloud Microphysics and Indirect Aerosol Effects Citation Details In-Document Search Title: Parameterizations of Cloud Microphysics and Indirect Aerosol Effects 1. OVERVIEW Aerosols and especially their effect on clouds are one of the key components of the climate system and the hydrological cycle [Ramanathan et al., 2001]. Yet, the aerosol effect on clouds remains largely unknown and the processes involved not well understood. A

  18. STORMVEX. Ice Nuclei and Cloud Condensation Nuclei Characterization Field

    Office of Scientific and Technical Information (OSTI)

    Campaign Report (Technical Report) | SciTech Connect STORMVEX. Ice Nuclei and Cloud Condensation Nuclei Characterization Field Campaign Report Citation Details In-Document Search Title: STORMVEX. Ice Nuclei and Cloud Condensation Nuclei Characterization Field Campaign Report The relationship between aerosol particles and the formation of clouds is among the most uncertain aspects in our current understanding of climate change. Warm clouds have been the most extensively studied, in large part

  19. Model of E-Cloud Instability in the Fermilab Recycler

    SciTech Connect (OSTI)

    Balbekov, V.

    2015-06-24

    Simple model of electron cloud is developed in the paper to explain e-cloud instability of bunched proton beam in the Fermilab Recycler. The cloud is presented as an immobile snake in strong vertical magnetic field. The instability is treated as an amplification of the bunch injection errors from the batch head to its tail. Nonlinearity of the e-cloud field is taken into account. Results of calculations are compared with experimental data demonstrating good correlation.

  20. Determining Best Estimates and Uncertainties in Cloud Microphysical

    Office of Scientific and Technical Information (OSTI)

    Parameters from ARM Field Data: Implications for Models, Retrieval Schemes and Aerosol-Cloud-Radiation Interactions (Technical Report) | SciTech Connect Determining Best Estimates and Uncertainties in Cloud Microphysical Parameters from ARM Field Data: Implications for Models, Retrieval Schemes and Aerosol-Cloud-Radiation Interactions Citation Details In-Document Search Title: Determining Best Estimates and Uncertainties in Cloud Microphysical Parameters from ARM Field Data: Implications for

  1. Vertical Velocities in Continental Boundary Layer Stratocumulus Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Boundary Layer Stratocumulus Clouds Virendra Ghate Bruce Albrecht and Pavlos Kollias Why BL Stratocumulus?? * Extensive Coverage - Cover ~24% of earth's surface - Persist of long time-scales * Impact on radiation budget - High SW albedo compared to land or ocean Klein and Hartmann 1993 But Why Continental Clouds? * They do exist - Monthly cloud fraction can vary from 10% to 23% * Impact on pollution & Diurnal Cycle - Affect pollutant venting out of BL & Aerosol processing by clouds *

  2. Toward Understanding of Differences in Current Cloud Retrievals of ARM

    Office of Scientific and Technical Information (OSTI)

    Ground-based Measurements (Journal Article) | SciTech Connect Toward Understanding of Differences in Current Cloud Retrievals of ARM Ground-based Measurements Citation Details In-Document Search Title: Toward Understanding of Differences in Current Cloud Retrievals of ARM Ground-based Measurements Accurate observations of cloud microphysical properties are needed for evaluating and improving the representation of cloud processes in climate models. However, large differences are found in

  3. Liquid sampling system

    DOE Patents [OSTI]

    Larson, Loren L.

    1987-01-01

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

  4. Liquid sampling system

    DOE Patents [OSTI]

    Larson, L.L.

    1984-09-17

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    size distribution (3) geosciences (3) ice (3) liquid water content (3) precipitation (3) sensitivity (3) total cloud water (3) water vapor (3) algorithms (2) Filter by Author ...

  6. A GCM Parameterization of Ice Particle Mean Effective Sizes for High Latitude Cirrus Clouds and It's Comparison with Mid-Latitude Parmaterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GCM Parameterization of Ice Particle Mean Effective Sizes for High Latitude Cirrus Clouds and It's Comparison with Mid-Latitude Parameterization F. S. Boudala Department of Oceanography Dalhousie University Halifax, Nova Scotia, Canada Q. Fu Department of Atmospheric Sciences University of Washington Seattle, Washington G. A. Issac Meteorological Service of Canada Toronto, Ontario, Canada Introduction Single-scattering properties of ice clouds depend on both ice water content (IWC) and effective

  7. Cloud Property Retrieval Products for Graciosa Island, Azores

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dong, Xiquan

    The motivation for developing this product was to use the Dong et al. 1998 method to retrieve cloud microphysical properties, such as cloud droplet effective radius, cloud droplets number concentration, and optical thickness. These retrieved properties have been used to validate the satellite retrieval, and evaluate the climate simulations and reanalyses. We had been using this method to retrieve cloud microphysical properties over ARM SGP and NSA sites. We also modified the method for the AMF at Shouxian, China and some IOPs, e.g. ARM IOP at SGP in March, 2000. The ARSCL data from ARM data archive over the SGP and NSA have been used to determine the cloud boundary and cloud phase. For these ARM permanent sites, the ARSCL data was developed based on MMCR measurements, however, there were no data available at the Azores field campaign. We followed the steps to generate this derived product and also include the MPLCMASK cloud retrievals to determine the most accurate cloud boundaries, including the thin cirrus clouds that WACR may under-detect. We use these as input to retrieve the cloud microphysical properties. Due to the different temporal resolutions of the derived cloud boundary heights product and the cloud properties product, we submit them as two separate netcdf files.

  8. Cloud Property Retrieval Products for Graciosa Island, Azores

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dong, Xiquan

    2014-05-05

    The motivation for developing this product was to use the Dong et al. 1998 method to retrieve cloud microphysical properties, such as cloud droplet effective radius, cloud droplets number concentration, and optical thickness. These retrieved properties have been used to validate the satellite retrieval, and evaluate the climate simulations and reanalyses. We had been using this method to retrieve cloud microphysical properties over ARM SGP and NSA sites. We also modified the method for the AMF at Shouxian, China and some IOPs, e.g. ARM IOP at SGP in March, 2000. The ARSCL data from ARM data archive over the SGP and NSA have been used to determine the cloud boundary and cloud phase. For these ARM permanent sites, the ARSCL data was developed based on MMCR measurements, however, there were no data available at the Azores field campaign. We followed the steps to generate this derived product and also include the MPLCMASK cloud retrievals to determine the most accurate cloud boundaries, including the thin cirrus clouds that WACR may under-detect. We use these as input to retrieve the cloud microphysical properties. Due to the different temporal resolutions of the derived cloud boundary heights product and the cloud properties product, we submit them as two separate netcdf files.

  9. Universally oriented renewable liquid mirror

    DOE Patents [OSTI]

    Ryutov, Dmitri D.; Toor, Arthur

    2004-07-20

    A universally oriented liquid mirror. A liquid and a penetrable unit are operatively connected to provide a mirror that can be universally oriented.

  10. Dynamics and diffusion mechanism of low-density liquid silicon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, B.; Wang, Z. Y.; Dong, F.; Guo, Y. R.; Zhang, R. J.; Zheng, Y. X.; Wang, S. Y.; Wang, C. Z.; Ho, K. M.; Chen, L. Y.

    2015-11-05

    A first-order phase transition from a high-density liquid to a low-density liquid has been proposed to explain the various thermodynamic anomies of water. It also has been proposed that such liquid–liquid phase transition would exist in supercooled silicon. Computer simulation studies show that, across the transition, the diffusivity drops roughly 2 orders of magnitude, and the structures exhibit considerable tetrahedral ordering. The resulting phase is a highly viscous, low-density liquid silicon. Investigations on the atomic diffusion of such a novel form of liquid silicon are of high interest. Here we report such diffusion results from molecular dynamics simulations using themore » classical Stillinger–Weber (SW) potential of silicon. We show that the atomic diffusion of the low-density liquid is highly correlated with local tetrahedral geometries. We also show that atoms diffuse through hopping processes within short ranges, which gradually accumulate to an overall random motion for long ranges as in normal liquids. There is a close relationship between dynamical heterogeneity and hopping process. We point out that the above diffusion mechanism is closely related to the strong directional bonding nature of the distorted tetrahedral network. Here, our work offers new insights into the complex behavior of the highly viscous low density liquid silicon, suggesting similar diffusion behaviors in other tetrahedral coordinated liquids that exhibit liquid–liquid phase transition such as carbon and germanium.« less

  11. Dynamics and diffusion mechanism of low-density liquid silicon

    SciTech Connect (OSTI)

    Shen, B.; Wang, Z. Y.; Dong, F.; Guo, Y. R.; Zhang, R. J.; Zheng, Y. X.; Wang, S. Y.; Wang, C. Z.; Ho, K. M.; Chen, L. Y.

    2015-11-05

    A first-order phase transition from a high-density liquid to a low-density liquid has been proposed to explain the various thermodynamic anomies of water. It also has been proposed that such liquid–liquid phase transition would exist in supercooled silicon. Computer simulation studies show that, across the transition, the diffusivity drops roughly 2 orders of magnitude, and the structures exhibit considerable tetrahedral ordering. The resulting phase is a highly viscous, low-density liquid silicon. Investigations on the atomic diffusion of such a novel form of liquid silicon are of high interest. Here we report such diffusion results from molecular dynamics simulations using the classical Stillinger–Weber (SW) potential of silicon. We show that the atomic diffusion of the low-density liquid is highly correlated with local tetrahedral geometries. We also show that atoms diffuse through hopping processes within short ranges, which gradually accumulate to an overall random motion for long ranges as in normal liquids. There is a close relationship between dynamical heterogeneity and hopping process. We point out that the above diffusion mechanism is closely related to the strong directional bonding nature of the distorted tetrahedral network. Here, our work offers new insights into the complex behavior of the highly viscous low density liquid silicon, suggesting similar diffusion behaviors in other tetrahedral coordinated liquids that exhibit liquid–liquid phase transition such as carbon and germanium.

  12. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  13. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1992-01-01

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  14. Liquid-level detector

    DOE Patents [OSTI]

    Not Available

    1981-01-29

    Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

  15. The Magellan Final Report on Cloud Computing

    SciTech Connect (OSTI)

    ,; Coghlan, Susan; Yelick, Katherine

    2011-12-21

    The goal of Magellan, a project funded through the U.S. Department of Energy (DOE) Office of Advanced Scientific Computing Research (ASCR), was to investigate the potential role of cloud computing in addressing the computing needs for the DOE Office of Science (SC), particularly related to serving the needs of mid- range computing and future data-intensive computing workloads. A set of research questions was formed to probe various aspects of cloud computing from performance, usability, and cost. To address these questions, a distributed testbed infrastructure was deployed at the Argonne Leadership Computing Facility (ALCF) and the National Energy Research Scientific Computing Center (NERSC). The testbed was designed to be flexible and capable enough to explore a variety of computing models and hardware design points in order to understand the impact for various scientific applications. During the project, the testbed also served as a valuable resource to application scientists. Applications from a diverse set of projects such as MG-RAST (a metagenomics analysis server), the Joint Genome Institute, the STAR experiment at the Relativistic Heavy Ion Collider, and the Laser Interferometer Gravitational Wave Observatory (LIGO), were used by the Magellan project for benchmarking within the cloud, but the project teams were also able to accomplish important production science utilizing the Magellan cloud resources.

  16. The Tropical Warm Pool International Cloud Experiment

    SciTech Connect (OSTI)

    May, Peter T.; Mather, James H.; Vaughan, Geraint; Jakob, Christian; McFarquhar, Greg; Bower, Keith; Mace, Gerald G.

    2008-05-01

    One of the most complete data sets describing tropical convection ever collected will result from the upcoming Tropical Warm Pool International Cloud Experiment (TWP-ICE) in the area around Darwin, Northern Australia in January and February 2006. The aims of the experiment, which will be operated in conjunction with the DOE Atmospheric Radiation Measurement (ARM) site in Darwin, will be to examine convective cloud systems from their initial stages through to the decay of the cirrus generated and to measure their impact on the environment. The experiment will include an unprecedented network of ground-based observations (soundings, active and passive remote sensors) combined with low, mid and high altitude aircraft for in-situ and remote sensing measurements. A crucial outcome of the experiment will be a data set suitable to provide the forcing and evaluation data required by cloud resolving and single column models as well as global climate models (GCMs) with the aim to contribute to parameterization development. This data set will provide the necessary link between the observed cloud properties and the models that are attempting to simulate them. The experiment is a large multi-agency experiment including substantial contributions from the United States DOE ARM program, ARM-UAV program, NASA, the Australian Bureau of Meteorology, CSIRO, EU programs and many universities.

  17. Argonne's Magellan Cloud Computing Research Project

    ScienceCinema (OSTI)

    Beckman, Pete

    2013-04-19

    Pete Beckman, head of Argonne's Leadership Computing Facility (ALCF), discusses the Department of Energy's new $32-million Magellan project, which designed to test how cloud computing can be used for scientific research. More information: http://www.anl.gov/Media_Center/News/2009/news091014a.html

  18. Parameterization of the Extinction Coefficient in Ice and Mixed-Phase Arctic Clouds during the ISDAC Field Campaign

    SciTech Connect (OSTI)

    Korolev, A; Shashkov, A; Barker, H

    2012-03-06

    This report documents the history of attempts to directly measure cloud extinction, the current measurement device known as the Cloud Extinction Probe (CEP), specific problems with direct measurement of extinction coefficient, and the attempts made here to address these problems. Extinction coefficient is one of the fundamental microphysical parameters characterizing bulk properties of clouds. Knowledge of extinction coefficient is of crucial importance for radiative transfer calculations in weather prediction and climate models given that Earth's radiation budget (ERB) is modulated much by clouds. In order for a large-scale model to properly account for ERB and perturbations to it, it must ultimately be able to simulate cloud extinction coefficient well. In turn this requires adequate and simultaneous simulation of profiles of cloud water content and particle habit and size. Similarly, remote inference of cloud properties requires assumptions to be made about cloud phase and associated single-scattering properties, of which extinction coefficient is crucial. Hence, extinction coefficient plays an important role in both application and validation of methods for remote inference of cloud properties from data obtained from both satellite and surface sensors (e.g., Barker et al. 2008). While estimation of extinction coefficient within large-scale models is relatively straightforward for pure water droplets, thanks to Mie theory, mixed-phase and ice clouds still present problems. This is because of the myriad forms and sizes that crystals can achieve, each having their own unique extinction properties. For the foreseeable future, large-scale models will have to be content with diagnostic parametrization of crystal size and type. However, before they are able to provide satisfactory values needed for calculation of radiative transfer, they require the intermediate step of assigning single-scattering properties to particles. The most basic of these is extinction coefficient, yet it is rarely measured directly, and therefore verification of parametrizations is difficult. The obvious solution is to be able to measure microphysical properties and extinction at the same time and for the same volume. This is best done by in situ sampling by instruments mounted on either balloon or aircraft. The latter is the usual route and the one employed here. Yet the problem of actually measuring extinction coefficient directly for arbitrarily complicated particles still remains unsolved.

  19. Evaluation of high&#8208;level clouds in cloud resolving model simulations with ARM and KWAJEX observations

    Office of Scientific and Technical Information (OSTI)

    fflAGUPUBLICATIONS Journal of Advances in Modeling Earth Systems RESEARCH ARTICLE Evaluation of high-level clouds in cloud resolving model 10.1002/2015MS000478 simulations with ARM and KWAJEX observations Key Points: * Two-moment microphysics improves simulated radar reflectivity histograms * Simulated high cloud amount is not sensitive to uncertainties in tested ice microphysics * Forcing uncertainties and periodic lateral BC lead to bias in high cloud amount Correspondence to: Z. Liu,

  20. Infrared Cloud Imager Measurements of Cloud Statistics from the 2003 Cloudiness Intercomparison Campaign

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Cloud Imager Measurements of Cloud Statistics from the 2003 Cloudiness Intercomparison Campaign B. Thurairajah and J. A. Shaw Department of Electrical and Computer Engineering Montana State University Bozeman, Montana Introduction The Cloudiness Inter-Comparison Intensive Operational Period (CIC IOP) occurred at the Atmospheric Radiation Measurement (ARM), Southern Great Plains (SGP) central facility site in Lamont, Oklahoma from mid-February to mid-April 2003 (Kassianov et al. 2004).

  1. Biogenic Aerosols Effects on Climate and Clouds Cloud OD Sensor TWST

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Biogenic Aerosols - Effects on Climate and Clouds: Cloud Optical Depth (COD) Sensor Three-Waveband Spectrally-Agile Technique (TWST) Field Campaign Report ER Niple HE Scott April 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any

  2. Synchrotrons Explore Water's Molecular Mysteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotrons Explore Water's Molecular Mysteries Synchrotrons Explore Water's Molecular Mysteries Print Friday, 01 February 2013 00:00 In experiments at SLAC National Accelerator Laboratory and Lawrence Berkeley National Laboratory's Advanced Light Source, scientists observed a surprisingly dense form of water that remained liquid well beyond its typical freezing point. Researchers applied a superthin coating of water-no deeper than a few molecules-to the surface of a barium fluoride crystal.

  3. Direct liquid injection of liquid petroleum gas

    SciTech Connect (OSTI)

    Lewis, D.J.; Phipps, J.R.

    1984-02-14

    A fuel injector and injection system for injecting liquified petroleum gas (LPG) into at least one air/fuel mixing chamber from a storage means that stores pressurized LPG in its liquid state. The fuel injector (including a body), adapted to receive pressurized LPG from the storage means and for selectively delivering the LPG to the air/fuel mixing chamber in its liquified state. The system including means for correcting the injector activation signal for pressure and density variations in the fuel.

  4. POWER GENERATION FROM LIQUID METAL NUCLEAR FUEL

    DOE Patents [OSTI]

    Dwyer, O.E.

    1958-12-23

    A nuclear reactor system is described wherein the reactor is the type using a liquid metal fuel, such as a dispersion of fissile material in bismuth. The reactor is designed ln the form of a closed loop having a core sectlon and heat exchanger sections. The liquid fuel is clrculated through the loop undergoing flssion in the core section to produce heat energy and transferrlng this heat energy to secondary fluids in the heat exchanger sections. The fission in the core may be produced by a separate neutron source or by a selfsustained chain reaction of the liquid fuel present in the core section. Additional auxiliary heat exchangers are used in the system to convert water into steam which drives a turbine.

  5. Apparatus for detecting leakage of liquid sodium

    DOE Patents [OSTI]

    Himeno, Yoshiaki

    1978-01-01

    An apparatus for detecting the leakage of liquid sodium includes a cable-like sensor adapted to be secured to a wall of piping or other equipment having sodium on the opposite side of the wall, and the sensor includes a core wire electrically connected to the wall through a leak current detector and a power source. An accidental leakage of the liquid sodium causes the corrosion of a metallic layer and an insulative layer of the sensor by products resulted from a reaction of sodium with water or oxygen in the atmospheric air so as to decrease the resistance between the core wire and the wall. Thus, the leakage is detected as an increase in the leaking electrical current. The apparatus is especially adapted for use in detecting the leakage of liquid sodium from sodium-conveying pipes or equipment in a fast breeder reactor.

  6. CloudSat as a Global Radar Calibrator

    SciTech Connect (OSTI)

    Protat, Alain; Bouniol, Dominique; O'Connor, E. J.; Baltink, Henk K.; Verlinde, J.; Widener, Kevin B.

    2011-03-01

    The calibration of the CloudSat spaceborne cloud radar has been thoroughly assessed using very accurate internal link budgets before launch, comparisons with predicted ocean surface backscatter at 94 GHz, direct comparisons with airborne cloud radars, and statistical comparisons with ground-based cloud radars at different locations of the world. It is believed that the calibration of CloudSat is accurate to within 0.5 to 1 dB. In the present paper it is shown that an approach similar to that used for the statistical comparisons with ground-based radars can now be adopted the other way around to calibrate other ground-based or airborne radars against CloudSat and / or detect anomalies in long time series of ground-based radar measurements, provided that the calibration of CloudSat is followed up closely (which is the case). The power of using CloudSat as a Global Radar Calibrator is demonstrated using the Atmospheric Radiation Measurement cloud radar data taken at Barrow, Alaska, the cloud radar data from the Cabauw site, The Netherlands, and airborne Doppler cloud radar measurements taken along the CloudSat track in the Arctic by the RASTA (Radar SysTem Airborne) cloud radar installed in the French ATR-42 aircraft for the first time. It is found that the Barrow radar data in 2008 are calibrated too high by 9.8 dB, while the Cabauw radar data in 2008 are calibrated too low by 8.0 dB. The calibration of the RASTA airborne cloud radar using direct comparisons with CloudSat agrees well with the expected gains and losses due to the change in configuration which required verification of the RASTA calibration.

  7. Liquid level controller

    DOE Patents [OSTI]

    Mangus, J.D.; Redding, A.H.

    1975-07-15

    A system for maintaining two distinct sodium levels within the shell of a heat exchanger having a plurality of J-shaped modular tube bundles each enclosed in a separate shell which extends from a common base portion. A lower liquid level is maintained in the base portion and an upper liquid level is maintained in the shell enwrapping the long stem of the J-shaped tube bundles by utilizing standpipes with a notch at the lower end which decreases in open area the distance from the end of the stand pipe increases and a supply of inert gas fed at a constant rate to produce liquid levels, which will remain generally constant as the flow of liquid through the vessel varies. (auth)

  8. Water mist injection in oil shale retorting

    DOE Patents [OSTI]

    Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

    1980-07-30

    Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

  9. Liquid blocking check valve

    DOE Patents [OSTI]

    Merrill, John T.

    1984-01-01

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  10. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-02-03

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperaturemore » and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.« less

  11. A cloud detection algorithm using the downwelling infrared radiance measured by an infrared pyrometer of the ground-based microwave radiometer

    SciTech Connect (OSTI)

    Ahn, M. H.; Han, D.; Won, H. Y.; Morris, Victor R.

    2015-02-03

    For better utilization of the ground-based microwave radiometer, it is important to detect the cloud presence in the measured data. Here, we introduce a simple and fast cloud detection algorithm by using the optical characteristics of the clouds in the infrared atmospheric window region. The new algorithm utilizes the brightness temperature (Tb) measured by an infrared radiometer installed on top of a microwave radiometer. The two-step algorithm consists of a spectral test followed by a temporal test. The measured Tb is first compared with a predicted clear-sky Tb obtained by an empirical formula as a function of surface air temperature and water vapor pressure. For the temporal test, the temporal variability of the measured Tb during one minute compares with a dynamic threshold value, representing the variability of clear-sky conditions. It is designated as cloud-free data only when both the spectral and temporal tests confirm cloud-free data. Overall, most of the thick and uniform clouds are successfully detected by the spectral test, while the broken and fast-varying clouds are detected by the temporal test. The algorithm is validated by comparison with the collocated ceilometer data for six months, from January to June 2013. The overall proportion of correctness is about 88.3% and the probability of detection is 90.8%, which are comparable with or better than those of previous similar approaches. Two thirds of discrepancies occur when the new algorithm detects clouds while the ceilometer does not, resulting in different values of the probability of detection with different cloud-base altitude, 93.8, 90.3, and 82.8% for low, mid, and high clouds, respectively. Finally, due to the characteristics of the spectral range, the new algorithm is found to be insensitive to the presence of inversion layers.

  12. Liquid level, void fraction, and superheated steam sensor for nuclear-reactor cores. [PWR; BWR

    DOE Patents [OSTI]

    Tokarz, R.D.

    1981-10-27

    This disclosure relates to an apparatus for monitoring the presence of coolant in liquid or mixed liquid and vapor, and superheated gaseous phases at one or more locations within an operating nuclear reactor core, such as pressurized water reactor or a boiling water reactor.

  13. Metal-air cell comprising an electrolyte with a room temperature ionic liquid and hygroscopic additive

    DOE Patents [OSTI]

    Friesen, Cody A.; Krishnan, Ramkumar; Tang, Toni; Wolfe, Derek

    2014-08-19

    An electrochemical cell comprising an electrolyte comprising water and a hydrophobic ionic liquid comprising positive ions and negative ions. The electrochemical cell also includes an air electrode configured to absorb and reduce oxygen. A hydrophilic or hygroscopic additive modulates the hydrophobicity of the ionic liquid to maintain a concentration of the water in the electrolyte is between 0.001 mol % and 25 mol %.

  14. Prediction of cloud condensation nuclei activity for organic compounds using functional group contribution methods

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petters, M. D.; Kreidenweis, S. M.; Ziemann, P. J.

    2015-09-01

    A wealth of recent laboratory and field experiments demonstrate that organic aerosol composition evolves with time in the atmosphere, leading to changes in the influence of the organic fraction to cloud condensation nuclei (CCN) spectra. There is a need for tools that can realistically represent the evolution of CCN activity to better predict indirect effects of organic aerosol on clouds and climate. This work describes a model to predict the CCN activity of organic compounds from functional group composition. The model combines Khler theory with semi-empirical group contribution methods to estimate molar volumes, activity coefficients and liquid-liquid phase boundaries tomorepredict the effective hygroscopicity parameter, kappa. Model evaluation against a selected database of published laboratory measurements demonstrates that kappa can be predicted within a factor of two. Simulation of homologous series is used to identify the relative effectiveness of different functional groups in increasing the CCN activity of weakly functionalized organic compounds. Hydroxyl, carboxyl, aldehyde, hydroperoxide, carbonyl, and ether moieties promote CCN activity while methylene and nitrate moieties inhibit CCN activity. The model can be incorporated into scale-bridging testbeds such as the Generator of Explicit Chemistry and Kinetics of Organics in the Atmosphere to evaluate the evolution of kappa for a complex mix of organic compounds and to develop suitable parameterizations of CCN evolution for larger scale models.less

  15. Operation Greenhouse. Scientific Director's report of atomic-weapon tests at Eniwetok, 1951. Annex 4. 1. Cloud studies. Part 1. Cloud physics. Part 2. Development of the atomic cloud. Part 3. Cloud-tracking photography

    SciTech Connect (OSTI)

    Anderson, C.E.; Gustafson, P.E.; Kellogg, W.W.; McKown, R.E.; McPherson, D.E.

    1985-09-01

    The cloud-physics project was primarily intended to fulfill a requirements for detailed information on the meteorological microstructure of atomic clouds. By means of a tracking and photographic network extending halfway around Eniwetok Atoll, the behavior of the first three clouds of Operation Greenhouse were observed and recorded. The rise of the fourth cloud was observed visually from only one site. The analysis of these observations, combined with information about the local weather conditions, gives a fairly complete picture of the development of each of the clouds. Particular emphasis was placed on the earlier phases of development, and the heights and sizes of the cloud parts have been determined as functions of time. A summary of important features of some previous atomic clouds are included for comparison.

  16. Liquid crystalline composites containing phyllosilicates

    DOE Patents [OSTI]

    Chaiko, David J.

    2004-07-13

    The present invention provides phyllosilicate-polymer compositions which are useful as liquid crystalline composites. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while at the same time be transparent. Because of the ordering of the particles liquid crystalline composite, liquid crystalline composites are particularly useful as barriers to gas transport.

  17. Ionic Liquids Create More Sustainable Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ionic Liquids Create More Sustainable Processes - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste

  18. imidazolium-based ionic liquid pretreatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    imidazolium-based ionic liquid pretreatment - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste

  19. understanding the chemistries of ionic liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistries of ionic liquids - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  20. Plasmas in Multiphase Media: Bubble Enhanced Discharges in Liquids and Plasma/Liquid Phase Boundaries

    SciTech Connect (OSTI)

    Kushner, Mark Jay

    2014-07-10

    In this research project, the interaction of atmospheric pressure plasmas with multi-phase media was computationally investigated. Multi-phase media includes liquids, particles, complex materials and porous surfaces. Although this investigation addressed fundamental plasma transport and chemical processes, the outcomes directly and beneficially affected applications including biotechnology, medicine and environmental remediation (e.g., water purification). During this project, we made advances in our understanding of the interaction of atmospheric pressure plasmas in the form of dielectric barrier discharges and plasma jets with organic materials and liquids. We also made advances in our ability to use computer modeling to represent these complex processes. We determined the method that atmospheric pressure plasmas flow along solid and liquid surfaces, and through endoscopic like tubes, deliver optical and high energy ion activation energy to organic and liquid surfaces, and produce reactivity in thin liquid layers, as might cover a wound. We determined the mechanisms whereby plasmas can deliver activation energy to the inside of liquids by sustaining plasmas in bubbles. These findings are important to the advancement of new technology areas such as plasma medicine