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1

Radioactive Liquid Waste Treatment Facility: Environmental Information Document  

Science Conference Proceedings (OSTI)

At Los Alamos National Laboratory (LANL), the treatment of radioactive liquid waste is an integral function of the LANL mission: to assure U.S. military deterrence capability through nuclear weapons technology. As part of this mission, LANL conducts nuclear materials research and development (R&D) activities. These activities generate radioactive liquid waste that must be handled in a manner to ensure protection of workers, the public, and the environment. Radioactive liquid waste currently generated at LANL is treated at the Radioactive Liquid Waste Treatment Facility (RLWTF), located at Technical Area (TA)-50. The RLWTF is 30 years old and nearing the end of its useful design life. The facility was designed at a time when environmental requirements, as well as more effective treatment technologies, were not inherent in engineering design criteria. The evolution of engineering design criteria has resulted in the older technology becoming less effective in treating radioactive liquid wastestreams in accordance with current National Pollutant Discharge Elimination System (NPDES) and Department of Energy (DOE) regulatory requirements. Therefore, to support ongoing R&D programs pertinent to its mission, LANL is in need of capabilities to efficiently treat radioactive liquid waste onsite or to transport the waste off site for treatment and/or disposal. The purpose of the EID is to provide the technical baseline information for subsequent preparation of an Environmental Impact Statement (EIS) for the RLWTF. This EID addresses the proposed action and alternatives for meeting the purpose and need for agency action.

Haagenstad, H.T.; Gonzales, G.; Suazo, I.L. [Los Alamos National Lab., NM (United States)

1993-11-01T23:59:59.000Z

2

Low-level liquid waste treatment system start-up  

Science Conference Proceedings (OSTI)

Following removal of Cs-137 by ion exchange in the Supernatant Treatment System immediately upstream, the radioactive liquid waste is volume-reduced by evaporation. Trace amounts of Cs-137 in the resulting distillate are removed by ion exchange, then the distillate is discharged to the existing plant water treatment system. The concentrated product, 37 to 41 percent solids (by weight), is encapsulated in cement, producing a stable low-level waste form. This report provides a summary of work performed to test the Liquid Waste Treatment System following construction turnover and prior to radioactive operation. All mechanical and electrical components, piping, valves, pumps, tanks, controls, and instrumentation required to operate the system were tested; first with water, then with simulated waste. Subsystems (individual tanks, pumps, and control loops) were tested individually, then as a complete system. Finally, the system began a controlled start-up phase, which included the first four months of radioactive operation. Components were tested for operability then for performance data to verify the system`s ability to produce an acceptable waste form at design feed rates.

Baker, M.N.; Gessner, R.F.

1989-07-01T23:59:59.000Z

3

Pilot studies to achieve waste minimization and enhance radioactive liquid waste treatment at the Los Alamos National Laboratory Radioactive Liquid Waste Treatment Facility  

SciTech Connect

The Radioactive and Industrial Wastewater Science Group manages and operates the Radioactive Liquid Waste Treatment Facility (RLWTF) at the Los Alamos National Laboratory (LANL). The RLWTF treats low-level radioactive liquid waste generated by research and analytical facilities at approximately 35 technical areas throughout the 43-square-mile site. The RLWTF treats an average of 5.8 million gallons (21.8-million liters) of liquid waste annually. Clarifloculation and filtration is the primary treatment technology used by the RLWTF. This technology has been used since the RLWTF became operable in 1963. Last year the RLWTF achieved an average of 99.7% removal of gross alpha activity in the waste stream. The treatment process requires the addition of chemicals for the flocculation and subsequent precipitation of radionuclides. The resultant sludge generated during this process is solidified in drums and stored or disposed of at LANL.

Freer, J.; Freer, E.; Bond, A. [and others

1996-07-01T23:59:59.000Z

4

Radioactive Liquid Waste Treatment Facility Discharges in 2011  

Science Conference Proceedings (OSTI)

This report documents radioactive discharges from the TA50 Radioactive Liquid Waste Treatment Facilities (RLWTF) during calendar 2011. During 2011, three pathways were available for the discharge of treated water to the environment: discharge as water through NPDES Outfall 051 into Mortandad Canyon, evaporation via the TA50 cooling towers, and evaporation using the newly-installed natural-gas effluent evaporator at TA50. Only one of these pathways was used; all treated water (3,352,890 liters) was fed to the effluent evaporator. The quality of treated water was established by collecting a weekly grab sample of water being fed to the effluent evaporator. Forty weekly samples were collected; each was analyzed for gross alpha, gross beta, and tritium. Weekly samples were also composited at the end of each month. These flow-weighted composite samples were then analyzed for 37 radioisotopes: nine alpha-emitting isotopes, 27 beta emitters, and tritium. These monthly analyses were used to estimate the radioactive content of treated water fed to the effluent evaporator. Table 1 summarizes this information. The concentrations and quantities of radioactivity in Table 1 are for treated water fed to the evaporator. Amounts of radioactivity discharged to the environment through the evaporator stack were likely smaller since only entrained materials would exit via the evaporator stack.

Del Signore, John C. [Los Alamos National Laboratory

2012-05-16T23:59:59.000Z

5

Biological Information Document, Radioactive Liquid Waste Treatment Facility  

SciTech Connect

This document is intended to act as a baseline source material for risk assessments which can be used in Environmental Assessments and Environmental Impact Statements. The current Radioactive Liquid Waste Treatment Facility (RLWTF) does not meet current General Design Criteria for Non-reactor Nuclear Facilities and could be shut down affecting several DOE programs. This Biological Information Document summarizes various biological studies that have been conducted in the vicinity of new Proposed RLWTF site and an Alternative site. The Proposed site is located on Mesita del Buey, a mess top, and the Alternative site is located in Mortandad Canyon. The Proposed Site is devoid of overstory species due to previous disturbance and is dominated by a mixture of grasses, forbs, and scattered low-growing shrubs. Vegetation immediately adjacent to the site is a pinyon-juniper woodland. The Mortandad canyon bottom overstory is dominated by ponderosa pine, willow, and rush. The south-facing slope was dominated by ponderosa pine, mountain mahogany, oak, and muhly. The north-facing slope is dominated by Douglas fir, ponderosa pine, and oak. Studies on wildlife species are limited in the vicinity of the proposed project and further studies will be necessary to accurately identify wildlife populations and to what extent they utilize the project area. Some information is provided on invertebrates, amphibians and reptiles, and small mammals. Additional species information from other nearby locations is discussed in detail. Habitat requirements exist in the project area for one federally threatened wildlife species, the peregrine falcon, and one federal candidate species, the spotted bat. However, based on surveys outside of the project area but in similar habitats, these species are not expected to occur in either the Proposed or Alternative RLWTF sites. Habitat Evaluation Procedures were used to evaluate ecological functioning in the project area.

Biggs, J.

1995-12-31T23:59:59.000Z

6

The Radioactive Liquid Waste Treatment Facility Replacement Project at Los Alamos National Laboratory  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Radioactive Liquid Waste Radioactive Liquid Waste Treatment Facility Replacement Project at Los Alamos National Laboratory OAS-L-13-15 September 2013 Department of Energy Washington, DC 20585 September 26, 2013 MEMORANDUM FOR THE ASSOCIATE ADMINISTRATOR FOR ACQUISITION AND PROJECT MANAGEMENT MANAGER LOS ALAMOS FIELD OFFICE FROM: David Sedillo Western Audits Division Office of Inspector General SUBJECT: INFORMATION: Audit Report on "The Radioactive Liquid Waste Treatment Facility Replacement Project at Los Alamos National Laboratory" BACKGROUND The Department of Energy's Los Alamos National Laboratory (Los Alamos) is a Government- owned, contractor operated Laboratory that is part of the National Nuclear Security Administration's (NNSA) nuclear weapons complex. Los Alamos' primary responsibility is to

7

Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan  

SciTech Connect

Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

Van Hoesen, S.D.

2003-09-09T23:59:59.000Z

8

Audit of the radioactive liquid waste treatment facility operations at the Los Alamos National Laboratory  

SciTech Connect

Los Alamos National Laboratory (Los Alamos) generates radioactive and liquid wastes that must be treated before being discharged to the environment. Presently, the liquid wastes are treated in the Radioactive Liquid Waste Treatment Facility (Treatment Facility), which is over 30 years old and in need of repair or replacement. However, there are various ways to satisfy the treatment need. The objective of the audit was to determine whether Los Alamos cost effectively managed its Treatment Facility operations. The audit determined that Los Alamos` treatment costs were significantly higher when compared to similar costs incurred by the private sector. This situation occurred because Los Alamos did not perform a complete analysis of privatization or prepare a {open_quotes}make-or-buy{close_quotes} plan for its treatment operations, although a {open_quotes}make-or-buy{close_quotes} plan requirement was incorporated into the contract in 1996. As a result, Los Alamos may be spending $2.15 million more than necessary each year and could needlessly spend $10.75 million over the next five years to treat its radioactive liquid waste. In addition, Los Alamos has proposed to spend $13 million for a new treatment facility that may not be needed if privatization proves to be a cost effective alternative. We recommended that the Manager, Albuquerque Operations Office (Albuquerque), (1) require Los Alamos to prepare a {open_quotes}make-or-buy{close_quotes} plan for its radioactive liquid waste treatment operations, (2) review the plan for approval, and (3) direct Los Alamos to select the most cost effective method of operations while also considering other factors such as mission support, reliability, and long-term program needs. Albuquerque concurred with the recommendations.

1997-11-19T23:59:59.000Z

9

Ultrafiltration treatment for liquid laundry wastes from nuclear power stations  

SciTech Connect

The authors conduct a comprehensive analysis of the waste constituents--radioactive and organic--of the laundry water resulting from the on-site laundering and decontamination of clothing worn in nuclear power plants. The primary isotope contaminants consist of niobium and zirconium 95, manganese 54, cobalt 60, iron 59, and cesium 134 and 137. A variety of filter and adsorbent materials used in an ultrafiltration process are comparatively tested for their effectiveness in removing not only these isotopes but also the organic contaminants in the process of recycling the water. Those materials consist of copper hexacyanoferrate, polyacrylophosphonic acid, and several metal-polymer complexes.

Kichik, V.A.; Maslova, M.N.; Svittsov, A.A.; Kuleshov, N.F.

1988-03-01T23:59:59.000Z

10

Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan  

SciTech Connect

Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

Van Hoesen, S.D.

2003-09-09T23:59:59.000Z

11

Environmental assessment for liquid waste treatment at the Nevada Test Site, Nye County, Nevada  

Science Conference Proceedings (OSTI)

This environmental assessment (EA) examines the potential impacts to the environment from treatment of low-level radioactive liquid and low-level mixed liquid and semi-solid wastes generated at the Nevada Test Site (NTS). The potential impacts of the proposed action and alternative actions are discussed herein in accordance with the National Environmental Policy Act (NEPA) of 1969, as amended in Title 42 U.S.C. (4321), and the US Department of Energy (DOE) policies and procedures set forth in Title 10 Code of Federal Regulations (CFR) Part 1021 and DOE Order 451.1, ``NEPA Compliance Program.`` The potential environmental impacts of the proposed action, construction and operation of a centralized liquid waste treatment facility, were addressed in the Final Environmental Impact Statement for the Nevada Test Site and Off-Site Locations in the State of Nevada. However, DOE is reevaluating the need for a centralized facility and is considering other alternative treatment options. This EA retains a centralized treatment facility as the proposed action but also considers other feasible alternatives.

NONE

1997-01-01T23:59:59.000Z

12

EA-1115: Liquid Waste Treatment at the Nevada Test Site, Nye County, Nevada  

Energy.gov (U.S. Department of Energy (DOE))

This EA evaluates the environmental impacts of the proposal to treat low-level radioactive liquid and low-level mixed liquid and semi-solid wastes generated at the U.S. Department of Energy Nevada...

13

SRS - Programs - Liquid Waste Disposition  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Waste Disposition Liquid Waste Disposition This includes both the solidification of highly radioactive liquid wastes stored in SRS's tank farms and disposal of liquid low-level waste generated as a by-product of the separations process and tank farm operations. This low-level waste is treated in the Effluent Treatment Facility. High-activity liquid waste is generated at SRS as by-products from the processing of nuclear materials for national defense, research and medical programs. The waste, totaling about 36 million gallons, is currently stored in 49 underground carbon-steel waste tanks grouped into two "tank farms" at SRS. While the waste is stored in the tanks, it separates into two parts: a sludge that settles on the bottom of the tank, and a liquid supernate that resides on top of the sludge. The waste is reduced to about 30 percent of its original volume by evaporation. The condensed evaporator "overheads" are transferred to the Effluent Treatment Project for final cleanup prior to release to the environment. As the concentrate cools a portion of it crystallizes forming solid saltcake. The concentrated supernate and saltcake are less mobile and therefore less likely to escape to the environment in the event of a tank crack or leak.

14

MUSHROOM WASTE MANAGEMENT PROJECT LIQUID WASTE MANAGEMENT  

E-Print Network (OSTI)

#12;MUSHROOM WASTE MANAGEMENT PROJECT LIQUID WASTE MANAGEMENT PHASE I: AUDIT OF CURRENT PRACTICE The Mushroom Waste Management Project (MWMP) was initiated by Environment Canada, the BC Ministry of solid and liquid wastes generated at mushroom producing facilities. Environmental guidelines

15

CERTIFICATION DOCKET FOR THE F0RhqE.R SITE OF THE RADIOACTIVE LIQUID WASTE TREATMENT PLANT (TA-45)  

Office of Legacy Management (LM)

CERTIFICATION DOCKET CERTIFICATION DOCKET FOR THE F0RhqE.R SITE OF THE RADIOACTIVE LIQUID WASTE TREATMENT PLANT (TA-45) AND THE EFFLUENT RECEIVING AREAS OF ACID, PUEBLO, AND LOS ALAMOS CANYOM, LOS ALAMOS, NEW MEXICO DEPARTMENT OF ENERGY Office of Nuclear Energy Office of Terminal Waste Disposal and Remedial Action Division of Remedial Action Projects -. CONTENTS A Page - Introduction to the Certification Docket for the Former Site of the Radioactive Liquid Waste Treatment Plant (TA-45) and the Effluent Receiving Areas of Acid, Pueblo, and Los Alamos Canyons, Los Alamos, New Mexico Description of the Formeriy Utilized Sites Program at the Former Site of the T.4-45 Treatment Plant and Acid, Pueblo, and Los Alamos Canyons Purpose Property Identification Docket Contents

16

PLUTONIUM FINISHING PLANT (PFP) 241-Z LIQUID WASTE TREATMENT FACILITY DEACTIVATION AND DEMOLITION  

Science Conference Proceedings (OSTI)

Fluor Hanford, Inc. (FH) is proud to submit the Plutonium Finishing Plant (PFP) 241-Z liquid Waste Treatment Facility Deactivation and Demolition (D&D) Project for consideration by the Project Management Institute as Project of the Year for 2008. The decommissioning of the 241-Z Facility presented numerous challenges, many of which were unique with in the Department of Energy (DOE) Complex. The majority of the project budget and schedule was allocated for cleaning out five below-grade tank vaults. These highly contaminated, confined spaces also presented significant industrial safety hazards that presented some of the most hazardous work environments on the Hanford Site. The 241-Z D&D Project encompassed diverse tasks: cleaning out and stabilizing five below-grade tank vaults (also called cells), manually size-reducing and removing over three tons of process piping from the vaults, permanently isolating service utilities, removing a large contaminated chemical supply tank, stabilizing and removing plutonium-contaminated ventilation ducts, demolishing three structures to grade, and installing an environmental barrier on the demolition site . All of this work was performed safely, on schedule, and under budget. During the deactivation phase of the project between November 2005 and February 2007, workers entered the highly contaminated confined-space tank vaults 428 times. Each entry (or 'dive') involved an average of three workers, thus equaling approximately 1,300 individual confined -space entries. Over the course of the entire deactivation and demolition period, there were no recordable injuries and only one minor reportable skin contamination. The 241-Z D&D Project was decommissioned under the provisions of the 'Hanford Federal Facility Agreement and Consent Order' (the Tri-Party Agreement or TPA), the 'Resource Conservation and Recovery Act of 1976' (RCRA), and the 'Comprehensive Environmental Response, Compensation, and Liability Act of 1980' (CERCLA). The project completed TPA Milestone M-083-032 to 'Complete those activities required by the 241-Z Treatment and Storage Unit's RCRA Closure Plan' four years and seven months ahead of this legally enforceable milestone. In addition, the project completed TPA Milestone M-083-042 to 'Complete transition and dismantlement of the 241-2 Waste Treatment Facility' four years and four months ahead of schedule. The project used an innovative approach in developing the project-specific RCRA closure plan to assure clear integration between the 241-Z RCRA closure activities and ongoing and future CERCLA actions at PFP. This approach provided a regulatory mechanism within the RCRA closure plan to place segments of the closure that were not practical to address at this time into future actions under CERCLA. Lessons learned from th is approach can be applied to other closure projects within the DOE Complex to control scope creep and mitigate risk. A paper on this topic, entitled 'Integration of the 241-Z Building D and D Under CERCLA with RCRA Closure at the PFP', was presented at the 2007 Waste Management Conference in Tucson, Arizona. In addition, techniques developed by the 241-Z D&D Project to control airborne contamination, clean the interior of the waste tanks, don and doff protective equipment, size-reduce plutonium-contaminated process piping, and mitigate thermal stress for the workers can be applied to other cleanup activities. The project-management team developed a strategy utilizing early characterization, targeted cleanup, and close coordination with PFP Criticality Engineering to significantly streamline the waste- handling costs associated with the project . The project schedule was structured to support an early transition to a criticality 'incredible' status for the 241-Z Facility. The cleanup work was sequenced and coordinated with project-specific criticality analysis to allow the fissile material waste being generated to be managed in a bulk fashion, instead of individual waste packages. This approach negated the need for real-time assay of individ

JOHNSTON GA

2008-01-15T23:59:59.000Z

17

Solvent extraction in the treatment of acidic high-level liquid waste : where do we stand?  

SciTech Connect

During the last 15 years, a number of solvent extraction/recovery processes have been developed for the removal of the transuranic elements, {sup 90}Sr and {sup 137}Cs from acidic high-level liquid waste. These processes are based on the use of a variety of both acidic and neutral extractants. This chapter will present an overview and analysis of the various extractants and flowsheets developed to treat acidic high-level liquid waste streams. The advantages and disadvantages of each extractant along with comparisons of the individual systems are discussed.

Horwitz, E. P.; Schulz, W. W.

1998-06-18T23:59:59.000Z

18

Current Practices: Solid Waste Management from Zero Liquid Discharge (ZLD) Wastewater Treatment  

Science Conference Proceedings (OSTI)

A study was conducted to identify current practices used by power plants to manage their solid waste residuals from zero liquid discharge (ZLD) operations treating flue gas desulfurization (FGD) wastewater. Because there are such few FGD ZLD systems in operation not only in the United States but also worldwide, the study scope was expanded to include non-FGD ZLD operations, as well. Only two of the seven facilities interviewed in this study operate ZLDs on FGD water; therefore, much of the current ...

2012-12-31T23:59:59.000Z

19

Development of the SREX process for the treatment of ICPP liquid wastes  

SciTech Connect

The removal of {sup 90}Sr from actual and simulated wastes at the Idaho Chemical Processing Plant (ICPP) at the Idaho National Engineering and Environmental Laboratory (INEEL) has been demonstrated with the SREX process. This solvent extraction process employs the extractant 4{prime},4{prime}(5{prime}) di-(t-butylcyclohexano)-18-crown-6 in 1-octanol or a mixture of tributyl phosphate and a hydrocarbon diluent called Isopar L{reg_sign}. Process flowsheets have been designed for testing in countercurrent experiments with centrifugal contractors. The flowsheets have been designed using batch contract solvent extraction methods. The extraction of Sr as well as other interfering ions has been studied. The effect of various parameters including nitric acid dependence, extractant concentration dependence, hydronium ion concentration, and interferent concentrations upon the extraction efficiency of the process has been evaluated. The radiolysis of the SREX solvent has also been investigated as a function of absorbed gamma radiation. The extraction efficiency of the solvent has been shown to be only slightly dependent upon absorbed dose in the range 0--1,000 kGy. The decontamination of actual sodium-bearing waste and dissolved calcine solutions has been accomplished in batch contact flowsheets. Decontamination factors as high as 10E3 have been obtained with sequential batch contacts. Flowsheets have been developed to accomplish decontamination of the liquid wastes with respect to {sup 90}Sr as well as the removal of Pb and Hg. Pb may be partitioned from the Sr fraction in a separate stripping procedure using ammonium citrate. This work has led to the formulation of countercurrent flowsheets which have been tested in centrifugal contractors with actual waste and reported in the document INEEL/EXT-97-00832.

Wood, D.J.; Law, J.D.; Garn, T.G.; Tillotson, R.D.; Tullock, P.A.; Todd, T.A.

1997-12-01T23:59:59.000Z

20

Development of the SREX Process for the Treatment of ICPP Liquid Wastes  

SciTech Connect

The removal of Sr-90 from actual and simulated wastes at the Idaho Chemical Processing Plant (ICPP) at the Idaho National Engineering and Environmental Laboratory (INEEL) has been demonstrated with the SREX process. This solvent extraction process employs the extractant 4',4' (5') de-(t-butylcyclohexano)-18-crown-6 in 1-octanol or a mixture of tributyl phosphate and a hydrocarbon diluent called Isopar L. This development work is based upon earlier work performed by Horwitz, et al. at Argonne National Laboratory. Process flowsheets have been designed for testing in countercurrent experiments with centrifugal contactors. The flowsheets have been designed using batch contact solvent extraction methods. The extraction of Sr as well as other interfering ions has been studied. The effect of various parameters including nitric acid dependence, extractant concentration dependence, Hydronium ion concentration, and interferent concentrations upon the extraction efficiency of the process has been evaluated. The radiolysis of the SREX solvent has also been investigated as a function of absorbed gamma radiation. The extraction efficiency of the solvent has been shown to be only slightly dependent upon absorbed dose in the range 0-1000 kGy. The decontamination of actual sodium-bearing waste and dissolved calcine solutions has been accomplished in batch contact flowsheets. Decontamination factors as high as 10E3 have been obtained with sequential batch contacts. Flowsheets have been developed to accomplish decontamination of the liquid wastes with respect to Sr-90, as well as the removal of Pb and Hg. Pb may be partitioned from the Sr fraction in a separate stripping procedure using ammonium citrate. This work has led to the formulation of countercurrent flowsheets which have been tested in centrifugal contactors with actual waste and reported in the document INEEL/EXT-97-00832.

D. J. Wood; Garn, T. G.; J. D. Law; P. A. Tullock; R. D. Tillotson; T. A. Todd

1997-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Waste Treatment  

Science Conference Proceedings (OSTI)

...rates, and batch collection volume requirements Water conservation possibilities What is required to meet discharge limits Availability and type of treatment chemicals How sludge will be dewatered, dried, and disposed...

22

Biohazardous Waste Disposal Guidelines Sharps Waste Solid Lab Waste Liquid Waste Animals Pathological Waste  

E-Print Network (OSTI)

Biohazardous Waste Disposal Guidelines Sharps Waste Solid Lab Waste Liquid Waste Animals Pathological Waste Description Biohazard symbol Address: UCSD 9500 Gilman Drive La Jolla, CA 92093 (858) 534) and identity of liquid waste Biohazard symbol Address: UCSD 9500 Gilman Drive La Jolla, CA 92093 (858) 534

Russell, Lynn

23

Biohazardous Waste Disposal Guidelines Sharps Waste Solid Lab Waste Liquid Waste Animals Pathological Waste  

E-Print Network (OSTI)

2/2009 Biohazardous Waste Disposal Guidelines Sharps Waste Solid Lab Waste Liquid Waste Animals Pathological Waste Description Biohazard symbol Address: UCSD 200 West Arbor Dr. San Diego, CA 92103 (619 (9:1) OR Biohazard symbol (if untreated) and identity of liquid waste Biohazard symbol Address

Firtel, Richard A.

24

Mixed Waste Treatment Study  

Science Conference Proceedings (OSTI)

As part of an ongoing integrated mixed waste program, EPRI has documented nuclear utility industry experience in the on-site treatment of mixed waste. This report reviews all available exclusions/exceptions to EPA permitting requirements for environmentally responsible on-site management of mixed waste. Included is a description of emerging mixed waste treatment technologies along with a detailed evaluation of off-site treatment/disposal facilities.

1996-01-31T23:59:59.000Z

25

Liquid low level waste management expert system  

SciTech Connect

An expert system has been developed as part of a new initiative for the Oak Ridge National Laboratory (ORNL) systems analysis program. This expert system will aid in prioritizing radioactive waste streams for treatment and disposal by evaluating the severity and treatability of the problem, as well as the final waste form. The objectives of the expert system development included: (1) collecting information on process treatment technologies for liquid low-level waste (LLLW) that can be incorporated in the knowledge base of the expert system, and (2) producing a prototype that suggests processes and disposal technologies for the ORNL LLLW system. 4 refs., 9 figs.

Ferrada, J.J.; Abraham, T.J. (Oak Ridge National Lab., TN (United States)); Jackson, J.R. (Southwest Baptist Univ., Bolivar, MO (USA))

1991-01-01T23:59:59.000Z

26

INEEL Radioactive Liquid Waste Reduction Program  

SciTech Connect

Reduction of radioactive liquid waste, much of which is Resource Conservation and Recovery Act (RCRA) listed, is a high priority at the Idaho National Technology and Engineering Center (INTEC). Major strides in the past five years have lead to significant decreases in generation and subsequent reduction in the overall cost of treatment of these wastes. In 1992, the INTEC, which is part of the Idaho National Environmental and Engineering Laboratory (INEEL), began a program to reduce the generation of radioactive liquid waste (both hazardous and non-hazardous). As part of this program, a Waste Minimization Plan was developed that detailed the various contributing waste streams, and identified methods to eliminate or reduce these waste streams. Reduction goals, which will reduce expected waste generation by 43%, were set for five years as part of this plan. The approval of the plan led to a Waste Minimization Incentive being put in place between the Department of Energy–Idaho Office (DOE-ID) and the INEEL operating contractor, Lockheed Martin Idaho Technologies Company (LMITCO). This incentive is worth $5 million dollars from FY-98 through FY-02 if the waste reduction goals are met. In addition, a second plan was prepared to show a path forward to either totally eliminate all radioactive liquid waste generation at INTEC by 2005 or find alternative waste treatment paths. Historically, this waste has been sent to an evaporator system with the bottoms sent to the INTEC Tank Farm. However, this Tank Farm is not RCRA permitted for mixed wastes and a Notice of Non-compliance Consent Order gives dates of 2003 and 2012 for removal of this waste from these tanks. Therefore, alternative treatments are needed for the waste streams. This plan investigated waste elimination opportunities as well as treatment alternatives. The alternatives, and the criteria for ranking these alternatives, were identified through Value Engineering meetings with all of the waste generators. The most promising alternatives were compared by applying weighting factors to each based on how well the alternative met the established criteria. From this information, an overall ranking of the various alternatives was obtained and a path forward recommended.

Tripp, Julia Lynn; Archibald, Kip Ernest; Argyle, Mark Don; Demmer, Ricky Lynn; Miller, Rose Anna; Lauerhass, Lance

1999-03-01T23:59:59.000Z

27

INEEL Radioactive Liquid Waste Reduction Program  

SciTech Connect

Reduction of radioactive liquid waste, much of which is Resource Conservation and Recovery Act (RCRA) listed, is a high priority at the Idaho National Technology and Engineering Center (INTEC). Major strides in the past five years have lead to significant decreases in generation and subsequent reduction in the overall cost of treatment of these wastes. In 1992, the INTEC, which is part of the Idaho National Environmental and Engineering Laboratory (INEEL), began a program to reduce the generation of radioactive liquid waste (both hazardous and non-hazardous). As part of this program, a Waste Minimization Plan was developed that detailed the various contributing waste streams, and identified methods to eliminate or reduce these waste streams. Reduction goals, which will reduce expected waste generation by 43%, were set for five years as part of this plan. The approval of the plan led to a Waste Minimization Incentive being put in place between the Department of Energy ? Idaho Office (DOE-ID) and the INEEL operating contractor, Lockheed Martin Idaho Technologies Company (LMITCO). This incentive is worth $5 million dollars from FY-98 through FY-02 if the waste reduction goals are met. In addition, a second plan was prepared to show a path forward to either totally eliminate all radioactive liquid waste generation at INTEC by 2005 or find alternative waste treatment paths. Historically, this waste has been sent to an evaporator system with the bottoms sent to the INTEC Tank Farm. However, this Tank Farm is not RCRA permitted for mixed wastes and a Notice of Non-compliance Consent Order gives dates of 2003 and 2012 for removal of this waste from these tanks. Therefore, alternative treatments are needed for the waste streams. This plan investigated waste elimination opportunities as well as treatment alternatives. The alternatives, and the criteria for ranking these alternatives, were identified through Value Engineering meetings with all of the waste generators. The most promising alternatives were compared by applying weighting factors to each based on how well the alternative met the established criteria. From this information, an overall ranking of the various alternatives was obtained and a path forward recommended.

C. B. Millet; J. L. Tripp; K. E. Archibald; L. Lauerhauss; M. D. Argyle; R. L. Demmer

1999-02-01T23:59:59.000Z

28

Method for treating liquid wastes  

DOE Patents (OSTI)

The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

Katti, Kattesh V. (Columbia, MO); Volkert, Wynn A. (Columbia, MO); Singh, Prahlad (Columbia, MO); Ketring, Alan R. (Columbia, MO)

1995-01-01T23:59:59.000Z

29

Method for treating liquid wastes  

DOE Patents (OSTI)

The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

1995-12-26T23:59:59.000Z

30

Treatment of Waste Soils / Solids  

Science Conference Proceedings (OSTI)

About the 1996 International Symposium on Extraction and Processing for the Treatment and Minimization of Wastes: Treatment of Waste Soils / Solids ...

31

Waste Treatment Plant Overview  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Site, located in southeastern Washington state, Hanford Site, located in southeastern Washington state, was the largest of three defense production sites in the U.S. Over the span of 40 years, it was used to produce 64 metric tons of plutonium, helping end World War II and playing a major role in military defense efforts during the Cold War. As a result, 56 million gallons of radioactive and chemical wastes are now stored in 177 underground tanks on the Hanford Site. To address this challenge, the U.S. Department of Energy contracted Bechtel National, Inc., to design and build the world's largest radioactive waste treatment plant. The Waste Treatment and Immobilization Plant (WTP), also known as the "Vit Plant," will use vitrification to immobilize most of Hanford's dangerous tank waste.

32

Treatment of organic waste  

DOE Patents (OSTI)

An organic waste containing at least one element selected from the group consisting of strontium, cesium, iodine and ruthenium is treated to achieve a substantial reduction in the volume of the waste and provide for fixation of the selected element in an inert salt. The method of treatment comprises introducing the organic waste and a source of oxygen into a molten salt bath maintained at an elevated temperature to produce solid and gaseous reaction products. The gaseous reaction products comprise carbon dioxide and water vapor, and the solid reaction products comprise the inorganic ash constituents of the organic waste and the selected element which is retained in the molten salt. The molten salt bath comprises one or more alkali metal carbonates, and may optionally include from 1 to about 25 wt.% of an alkali metal sulfate.

Grantham, LeRoy F. (Calabasas, CA)

1979-01-01T23:59:59.000Z

33

Hanford Tank Waste - Near Source Treatment of Low Activity Waste  

SciTech Connect

Treatment and disposition of Hanford Site waste as currently planned consists of I 00+ waste retrievals, waste delivery through up to 8+ miles of dedicated, in-ground piping, centralized mixing and blending operations- all leading to pre-treatment combination and separation processes followed by vitrification at the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The sequential nature of Tank Farm and WTP operations requires nominally 15-20 years of continuous operations before all waste can be retrieved from many Single Shell Tanks (SSTs). Also, the infrastructure necessary to mobilize and deliver the waste requires significant investment beyond that required for the WTP. Treating waste as closely as possible to individual tanks or groups- as allowed by the waste characteristics- is being investigated to determine the potential to 1) defer, reduce, and/or eliminate infrastructure requirements, and 2) significantly mitigate project risk by reducing the potential and impact of single point failures. The inventory of Hanford waste slated for processing and disposition as LAW is currently managed as high-level waste (HLW), i.e., the separation of fission products and other radionuclides has not commenced. A significant inventory ofthis waste (over 20M gallons) is in the form of precipitated saltcake maintained in single shell tanks, many of which are identified as potential leaking tanks. Retrieval and transport (as a liquid) must be staged within the waste feed delivery capability established by site infrastructure and WTP. Near Source treatment, if employed, would provide for the separation and stabilization processing necessary for waste located in remote farms (wherein most ofthe leaking tanks reside) significantly earlier than currently projected. Near Source treatment is intended to address the currently accepted site risk and also provides means to mitigate future issues likely to be faced over the coming decades. This paper describes the potential near source treatment and waste disposition options as well as the impact these options could have on reducing infrastructure requirements, project cost and mission schedule.

Ramsey, William Gene

2013-08-15T23:59:59.000Z

34

Explosive Waste Treatment Facility  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

106 106 Environment a 1 Assessment for th.e Explosive Waste Treatment Facility at Site 300 Lawrence Livermore National Laboratory MASTER November 1995 U.S. Department of Energy Office of Environmental Restoration and Waste Management Washington, DOC. 20585 Portions of this document maly be illegible in electronic image products. Images are produced from the best available original document. Table of Contents 1 . 0 2.0 3 . 0 4.0 5 . 0 6.0 7 . 0 8 . 0 Document Summary .............................................................. 1 Purpose and Need for Agency Action ............................................. 3 Description of the Proposed Action and Alternatives ............................ 4 3.1.1 Location ............................................................. 4

35

Newly Generated Liquid Waste Processing Alternatives Study, Volume 1  

SciTech Connect

This report identifies and evaluates three options for treating newly generated liquid waste at the Idaho Nuclear Technology and Engineering Center of the Idaho National Engineering and Environmental Laboratory. The three options are: (a) treat the waste using processing facilities designed for treating sodium-bearing waste, (b) treat the waste using subcontractor-supplied mobile systems, or (c) treat the waste using a special facility designed and constructed for that purpose. In studying these options, engineers concluded that the best approach is to store the newly generated liquid waste until a sodium-bearing waste treatment facility is available and then to co-process the stored inventory of the newly generated waste with the sodium-bearing waste. After the sodium-bearing waste facility completes its mission, two paths are available. The newly generated liquid waste could be treated using the subcontractor-supplied system or the sodium-bearing waste facility or a portion of it. The final decision depends on the design of the sodium-bearing waste treatment facility, which will be completed in coming years.

Landman, William Henry; Bates, Steven Odum; Bonnema, Bruce Edward; Palmer, Stanley Leland; Podgorney, Anna Kristine; Walsh, Stephanie

2002-09-01T23:59:59.000Z

36

Liquid and Gaseous Waste Operations Department Annual Operating Report, CY 1993  

SciTech Connect

This report summarizes the activities of the waste management operations section of the liquid and gaseous waste operations department at ORNL for 1993. The process waste, liquid low-level waste, gaseous waste systems activities are reported, as well as the low-level waste solidification project. Upgrade activities is the various waste processing and treatment systems are summarized. A maintenance activity overview is provided, and program management, training, and other miscellaneous activities are covered.

Maddox, J.J.; Scott, C.B.

1994-02-01T23:59:59.000Z

37

Future radioactive liquid waste streams study  

SciTech Connect

This study provides design planning information for the Radioactive Liquid Waste Treatment Facility (RLWTF). Predictions of estimated quantities of Radioactive Liquid Waste (RLW) and radioactivity levels of RLW to be generated are provided. This information will help assure that the new treatment facility is designed with the capacity to treat generated RLW during the years of operation. The proposed startup date for the RLWTF is estimated to be between 2002 and 2005, and the life span of the facility is estimated to be 40 years. The policies and requirements driving the replacement of the current RLW treatment facility are reviewed. Historical and current status of RLW generation at Los Alamos National Laboratory are provided. Laboratory Managers were interviewed to obtain their insights into future RLW activities at Los Alamos that might affect the amount of RLW generated at the Lab. Interviews, trends, and investigation data are analyzed and used to create scenarios. These scenarios form the basis for the predictions of future RLW generation and the level of RLW treatment capacity which will be needed at LANL.

Rey, A.S.

1993-11-01T23:59:59.000Z

38

Liquid Waste Processing Facilities (LWPF) Reliability and Availability and Maintainability (RAM) Analysis  

SciTech Connect

A reliability, availability, and maintainability (RAM) analysis was prepared for the liquid effluents support being provided to the River Protection Project Waste Treatment Plant (WTP). The availability of liquid effluents services to the WTP was determined. Recommendations are provided on improvements and upgrades to increase the availability of the Liquid Waste Processing Facilities treatment and disposal systems.

LOWE, S.S.

2001-02-20T23:59:59.000Z

39

Liquid and Gaseous Waste Operations Department annual operating report CY 1996  

SciTech Connect

This annual report summarizes operating activities dealing with the process waste system, the liquid low-level waste system, and the gaseous waste system. It also describes upgrade activities dealing with the process and liquid low-level waste systems, the cathodic protection system, a stack ventilation system, and configuration control. Maintenance activities are described dealing with nonradiological wastewater treatment plant, process waste treatment plant and collection system, liquid low-level waste system, and gaseous waste system. Miscellaneous activities include training, audits/reviews/tours, and environmental restoration support.

Maddox, J.J.; Scott, C.B.

1997-03-01T23:59:59.000Z

40

Chemical aspects of nuclear waste treatment  

SciTech Connect

The chemical aspects of the treatment of gaseous, liquid, and solid wastes are discussed in overview. The role of chemistry and the chemical reactions in waste treatment are emphasized. Waste treatment methods encompass the chemistry of radioactive elements from every group of the periodic table. In most streams, the radioactive elements are present in relatively low concentrations and are often associated with moderately large amounts of process reagents, or materials. In general, it is desirable that waste treatment methods are based on chemistry that is selective for the concentration of radionuclides and does not require the addition of reagents that contribute significantly to the volume of the treated waste. Solvent extraction, ion exchange, and sorbent chemistry play a major role in waste treatment because of the high selectivity provided for many radionuclides. This paper deals with the chemistry of the onsite treatment methods that is typically used at nuclear installations and is not concerned with the chemistry of the various alternative materials proposed for long-term storage of nuclear wastes. The chemical aspects are discussed from a generic point of view in which the chemistry of important radionuclides is emphasized.

Bond, W.D.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Integrated Waste Treatment Facility Fact Sheet | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Management Tank Waste and Waste Processing Integrated Waste Treatment Facility Fact Sheet Integrated Waste Treatment Facility Fact Sheet Waste Management Nuclear...

42

ICPP radioactive liquid and calcine waste technologies evaluation. Interim report  

SciTech Connect

The Department of Energy (DOE) has received spent nuclear fuel (SNF) at the Idaho Chemical Processing Plant (ICPP) for interim storage since 1951 and reprocessing since 1953. Until recently, the major activity of the ICPP has been the reprocessing of SNF to recover fissile uranium; however, changing world events have raised questions concerning the need to recover and recycle this material. In April 1992, DOE chose to discontinue reprocessing SNF for uranium recovery and shifted its focus toward the management and disposition of radioactive wastes accumulated through reprocessing activities. Currently, 1.8 million gallons of radioactive liquid wastes (1.5 million gallons of radioactive sodium-bearing liquid wastes and 0.3 million gallons of high-level liquid waste) and 3,800 cubic meters (m{sup 3}) of calcine waste are in inventory at the ICPP. Legal drivers and agreements exist obligating the INEL to develop, demonstrate, and implement technologies for safe and environmentally sound treatment and interim storage of radioactive liquid and calcine waste. Candidate treatment processes and waste forms are being evaluated using the Technology Evaluation and Analysis Methodology (TEAM) Model. This process allows decision makers to (1) identify optimum radioactive waste treatment and disposal form alternatives; (2) assess tradeoffs between various optimization criteria; (3) identify uncertainties in performance parameters; and (4) focus development efforts on options that best satisfy stakeholder concerns. The Systems Analysis technology evaluation presented in this document supports the DOE in selecting the most effective radioactive liquid and calcine waste management plan to implement in compliance with established regulations, court orders, and agreements.

Murphy, J.A.; Pincock, L.F.; Christiansen, I.N.

1994-06-01T23:59:59.000Z

43

Waste treatment at the La Hague and Marcoule sites  

SciTech Connect

In this report, an overview of waste treatment and solidification facilities located at the La Hague and Marcoule sites, which are owned and/or operated by Cogema, provided. The La Hague facilities described in this report include the following: The STE3 liquid effluent treatment facility (in operation); the AD2 solid waste processing facility (also in operation); and the UCD alpha waste treatment facility (under construction). The Marcoule facilities described in this report, both of which are in operation, include the following: The STEL-EVA liquid effluent treatment facilities for the entire site; and the alpha waste incinerator of the UPI plant. This report is organized into four sections: this introduction, low-level waste treatment at La Hague, low-level waste treatment at Marcoule, and new process development. including the solvent pyrolysis process currently in the development stage for Cogema`s plants.

1995-04-01T23:59:59.000Z

44

SRS Liquid Waste Program Partnering Agreement  

Energy.gov (U.S. Department of Energy (DOE))

We the members of the  SRS Liquid Waste Partnering Team do hereby mutually agree to work in a collaborative and cooperative manner through open communication and coordination with team members, and...

45

Waste Logic™ Liquid Waste Manager (WL-LWM) Software, Version 2.0  

Science Conference Proceedings (OSTI)

In response to continuing industry efforts to reduce operating expenditures, EPRI developed the Waste Logic&trade: Liquid Waste Manager code to analyze costs associated with liquid waste processing and the disposition of its resultant solid waste. EPRI's Waste Logic: Liquid Waste Manager software for windows-based PC computers provides a detailed economic and performance view of liquid waste processing activities. The software will help nuclear utilities evaluate the costs associated with liquid radwaste...

2002-06-05T23:59:59.000Z

46

Method for solidifying liquid radioactive wastes  

DOE Patents (OSTI)

The quantity of nitrous oxides produced during the solidification of liquid radioactive wastes containing nitrates and nitrites can be substantially reduced by the addition to the wastes of a stoichiometric amount of urea which, upon heating, destroys the nitrates and nitrites, liberating nontoxic N.sub.2, CO.sub.2 and NH.sub.3.

Berreth, Julius R. (Idaho Falls, ID)

1976-01-01T23:59:59.000Z

47

Recovery of Mercury From Contaminated Liquid Wastes  

SciTech Connect

The Base Contract program emphasized the manufacture and testing of superior sorbents for mercury removal, testing of the sorption process at a DOE site, and determination of the regeneration conditions in the laboratory. During this project, ADA Technologies, Inc. demonstrated the following key elements of a successful regenerable mercury sorption process: (1) sorbents that have a high capacity for dissolved, ionic mercury; (2) removal of ionic mercury at greater than 99% efficiency; and (3) thermal regeneration of the spent sorbent. ADA's process is based on the highly efficient and selective sorption of mercury by noble metals. Contaminated liquid flows through two packed columns that contain microporous sorbent particles on which a noble metal has been finely dispersed. A third column is held in reserve. When the sorbent is loaded with mercury to the point of breakthrough at the outlet of the second column, the first column is taken off-line and the flow of contaminated liquid is switched to the second and third columns. The spent column is regenerated by heating. A small flow of purge gas carries the desorbed mercury to a capture unit where the liquid mercury is recovered. Laboratory-scale tests with mercuric chloride solutions demonstrated the sorbents' ability to remove mercury from contaminated wastewater. Isotherms on surrogate wastes from DOE's Y-12 Plant in Oak Ridge, Tennessee showed greater than 99.9% mercury removal. Laboratory- and pilot-scale tests on actual Y-12 Plant wastes were also successful. Mercury concentrations were reduced to less than 1 ppt from a starting concentration of 1,000 ppt. The treatment objective was 50 ppt. The sorption unit showed 10 ppt discharge after six months. Laboratory-scale tests demonstrated the feasibility of sorbent regeneration. Results show that sorption behavior is not affected after four cycles.

1998-06-12T23:59:59.000Z

48

Independent Oversight Review, Advanced Mixed Waste Treatment...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Review, Advanced Mixed Waste Treatment Project - April 2013 Independent Oversight Review, Advanced Mixed Waste Treatment Project - April 2013 April 2013 Review of Radiation...

49

Treatment of Light Metal Wastes - TMS  

Science Conference Proceedings (OSTI)

... for the Treatment and Minimization of Wastes: Treatment of Light Metal Wastes ... A Decade of Gestation: S. Street, G. Brooks and H.K. Worner, Materials Eng.

50

Independent Oversight Review, Waste Treatment and Immobilization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Review, Waste Treatment and Immobilization Plant - May 2013 May 2013 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality The U.S....

51

Independent Oversight Review, Waste Treatment and Immobilization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Review, Waste Treatment and Immobilization Plant - March 2013 March 2013 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality The U.S....

52

Independent Activity Report, Hanford Waste Treatment Plant -...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Independent Activity Report, Hanford Waste Treatment Plant - February 2011 February 2011 Hanford Waste Treatment Plant Construction Quality Assurance Review ARPT-WTP-2011-002...

53

Independent Oversight Review, Waste Treatment and Immobilization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Immobilization Plant - October 2012 October 2012 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality The U. S....

54

Independent Oversight Review, Waste Treatment and Immobilization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Review, Waste Treatment and Immobilization Plant - March 2012 March 2012 Review of the Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality The...

55

Independent Oversight Review, Waste Treatment and Immobilization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Immobilization Plant - November 2011 November 2011 Review of the Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality The...

56

Independent Oversight Review, Waste Treatment and Immobilization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oversight Review, Waste Treatment and Immobilization Plant - August 2011 August 2011 Hanford Waste Treatment and Immobilization Plant Construction Quality The Office of Safety...

57

Development of a pilot safety information document (PSID) for the replacement of radioactive liquid waste treatment facility at Los Alamos National Laboratory  

E-Print Network (OSTI)

Based on recent decisions made by Los Alamos National Laboratory concerning the development of site-wide National Environmental Policy Act documents, an effort was undertaken to develop a Pilot Safety Information Document (PSID) for the replacement Radioactive Liquid Waste Treatment Facility. The PSID documents risk analysis for the proposed facility and some of the alternatives, accident analysis, radioactive and hazardous material doses to off-site individuals, and the cumulative safety risk from adjacent facilities. In addition, this study also compared two methods for calculating the consequences of a radioactive spill. The methods compared were the Superfund model and the release fraction model. It was determined that the release fraction model gives a more realistic estimate of the doses incurred as the result of an accident, and that the Superfund model should be used for estimating the dose before and during the remediation effort. The cumulative safety risk was determined by calculating the exceedance probability if the individual dose from four geographically related facilities. The risk for cancer fatalities was determined to be within the DOE's Nuclear Safety Policy Goals.

Selvage, Ronald Derek

1995-01-01T23:59:59.000Z

58

HUMAN MACHINE INTERFACE (HMI) EVALUATION OF ROOMS TA-50-1-60/60A AT THE RADIOACTIVE LIQUID WASTE TREATMENT FACILITY (RLWTF)  

Science Conference Proceedings (OSTI)

This effort addressed an evaluation of human machine interfaces (HMIs) in Room TA-50-1-60/60A of the Radioactive Liquid Waste Treatment Facility (RLWTF). The evaluation was performed in accordance with guidance outlined in DOE-STD-3009, DOE Standard Preparation Guide for U.S. Department of Energy Nonreactor Nuclear Facility Documented Safety Analyses, 2006 [DOE 2006]. Specifically, Chapter 13 of DOE 2006 highlights the 10 CFR 830, Nuclear Safety Management, 2012, [CFR 2012] and DOE G 421.1-2 [DOE 2001a] requirements as they relate to the human factors process and, in this case, the safety of the RLWTF. The RLWTF is a Hazard Category 3 facility and, consequently, does not have safety-class (SSCs). However, safety-significant SSCs are identified. The transuranic (TRU) wastewater tanks and associated piping are the only safety-significant SSCs in Rooms TA-50-1-60/60A [LANL 2010]. Hence, the human factors evaluation described herein is only applicable to this particular assemblage of tanks and piping.

Gilmore, Walter E. [Los Alamos National Laboratory; Stender, Kerith K. [Los Alamos National Laboratory

2012-08-29T23:59:59.000Z

59

Waste management system alternatives for treatment of wastes from spent fuel reprocessing  

SciTech Connect

This study was performed to help identify a preferred TRU waste treatment alternative for reprocessing wastes with respect to waste form performance in a geologic repository, near-term waste management system risks, and minimum waste management system costs. The results were intended for use in developing TRU waste acceptance requirements that may be needed to meet regulatory requirements for disposal of TRU wastes in a geologic repository. The waste management system components included in this analysis are waste treatment and packaging, transportation, and disposal. The major features of the TRU waste treatment alternatives examined here include: (1) packaging (as-produced) without treatment (PWOT); (2) compaction of hulls and other compactable wastes; (3) incineration of combustibles with cementation of the ash plus compaction of hulls and filters; (4) melting of hulls and failed equipment plus incineration of combustibles with vitrification of the ash along with the HLW; (5a) decontamination of hulls and failed equipment to produce LLW plus incineration and incorporation of ash and other inert wastes into HLW glass; and (5b) variation of this fifth treatment alternative in which the incineration ash is incorporated into a separate TRU waste glass. The six alternative processing system concepts provide progressively increasing levels of TRU waste consolidation and TRU waste form integrity. Vitrification of HLW and intermediate-level liquid wastes (ILLW) was assumed in all cases.

McKee, R.W.; Swanson, J.L.; Daling, P.M.; Clark, L.L.; Craig, R.A.; Nesbitt, J.F.; McCarthy, D.; Franklin, A.L.; Hazelton, R.F.; Lundgren, R.A.

1986-09-01T23:59:59.000Z

60

Treatment of mercury containing waste  

DOE Patents (OSTI)

A process is provided for the treatment of mercury containing waste in a single reaction vessel which includes a) stabilizing the waste with sulfur polymer cement under an inert atmosphere to form a resulting mixture and b) encapsulating the resulting mixture by heating the mixture to form a molten product and casting the molten product as a monolithic final waste form. Additional sulfur polymer cement can be added in the encapsulation step if needed, and a stabilizing additive can be added in the process to improve the leaching properties of the waste form.

Kalb, Paul D. (Wading River, NY); Melamed, Dan (Gaithersburg, MD); Patel, Bhavesh R (Elmhurst, NY); Fuhrmann, Mark (Babylon, NY)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Alternatives for managing wastes from reactors and post-fission operations in the LWR fuel cycle. Volume 2. Alternatives for waste treatment  

DOE Green Energy (OSTI)

Volume II of the five-volume report is devoted to the description of alternatives for waste treatment. The discussion is presented under the following section titles: fuel reprocessing modifications; high-level liquid waste solidification; treatment and immobilization of chop-leach fuel bundle residues; treatment of noncombustible solid wastes; treatment of combustible wastes; treatment of non-high-level liquid wastes; recovery of transuranics from non-high-level wastes; immobilization of miscellaneous non-high-level wastes; volatile radioisotope recovery and off-gas treatment; immobilization of volatile radioisotopes; retired facilities (decontamination and decommissioning); and, modification and use of selected fuel reprocessing wastes. (JGB)

Not Available

1976-05-01T23:59:59.000Z

62

Review of Potential Candidate Stabilization Technologies for Liquid and Solid Secondary Waste Streams  

SciTech Connect

Pacific Northwest National Laboratory has initiated a waste form testing program to support the long-term durability evaluation of a waste form for secondary wastes generated from the treatment and immobilization of Hanford radioactive tank wastes. The purpose of the work discussed in this report is to identify candidate stabilization technologies and getters that have the potential to successfully treat the secondary waste stream liquid effluent, mainly from off-gas scrubbers and spent solids, produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Down-selection to the most promising stabilization processes/waste forms is needed to support the design of a solidification treatment unit (STU) to be added to the Effluent Treatment Facility (ETF). To support key decision processes, an initial screening of the secondary liquid waste forms must be completed by February 2010.

Pierce, Eric M.; Mattigod, Shas V.; Westsik, Joseph H.; Serne, R. Jeffrey; Icenhower, Jonathan P.; Scheele, Randall D.; Um, Wooyong; Qafoku, Nikolla

2010-01-30T23:59:59.000Z

63

8-Waste treatment and disposal A. Responsibility for waste management  

E-Print Network (OSTI)

8- Waste treatment and disposal A. Responsibility for waste management 1. Each worker is responsible for correctly bagging and labeling his/her own waste. 2. A BSL3 technician will be responsible for transporting and autoclaving the waste. Waste will be autoclaved once or twice per day, depending on use

64

Sodium-Bearing Waste Treatment Alternatives Implementation Study  

SciTech Connect

The purpose of this document is to discuss issues related to the implementation of each of the five down-selected INEEL/INTEC radioactive liquid waste (sodium-bearing waste - SBW) treatment alternatives and summarize information in three main areas of concern: process/technical, environmental permitting, and schedule. Major implementation options for each treatment alternative are also identified and briefly discussed. This report may touch upon, but purposely does not address in detail, issues that are programmatic in nature. Examples of these include how the SBW will be classified with respect to the Nuclear Waste Policy Act (NWPA), status of Waste Isolation Pilot Plant (WIPP) permits and waste storage availability, available funding for implementation, stakeholder issues, and State of Idaho Settlement Agreement milestones. It is assumed in this report that the SBW would be classified as a transuranic (TRU) waste suitable for disposal at WIPP, located in New Mexico, after appropriate treatment to meet transportation requirements and waste acceptance criteria (WAC).

Charles M. Barnes; James B. Bosley; Clifford W. Olsen

2004-07-01T23:59:59.000Z

65

Waste treatment by selective mineral ion exchanger  

Science Conference Proceedings (OSTI)

STMI, subsidiary company of the AREVA Group with over 40 years in the D and D business, has been continuously innovating and developing new decontamination techniques, with the objectives of achieving more efficient decontaminations on a growing spectrum of media. In the field of liquid waste treatment, STMI manufactures uses and commercialises selective inorganic ion exchangers (RAN). These are hydrated synthetic inorganic compounds prepared from very pure raw materials. Different types of RANs (POLYAN, OXTAIN, Fe-Cu, Fe-CoK, Si-Fe-CoK) can be used to trap a large number of radioactive elements in contaminated effluents. Different implementations could be applied depending on technical conditions. STMI's offers consist in building global solution and preliminary design of installation either in dispersed form (batch) or in column (cartridge filtration). Those products are used all over the world not only in the nuclear business (Canada, US, Belgium, France...) but also in other fields. Indeed, it provides competitive solutions to many domains of application especially water pollution control, liquid waste treatment in the nuclear business by decreasing the activity level of waste. The following paper will focus on the theoretical principle of the mineral exchanger, its implementation and the feed back collected by STMI. (author)

Polito, Aurelie [Areva NC - BUA STMI, 1 route de la Noue - 91196 Gif sur Yvette, Cedex (France)

2007-07-01T23:59:59.000Z

66

Thermodynamic estimation of minor element distribution between immiscible liquids in Fe-Cu-based metal phase generated in melting treatment of municipal solid wastes  

SciTech Connect

Graphical abstract: Display Omitted Highlights: Black-Right-Pointing-Pointer Two liquids separation of metal occurs in the melting of municipal solid waste. Black-Right-Pointing-Pointer The distribution of PGMs etc. between two liquid metal phases is studied. Black-Right-Pointing-Pointer Quite simple thermodynamic model is applied to predict the distribution ratio. Black-Right-Pointing-Pointer Au and Ag originated from WEEE are found to be concentrated into Cu-rich phase. - Abstract: Waste electrical and electronic equipment (WEEE) has become an important target in managing material cycles from the viewpoint of not only waste management and control of environmental pollution but also resource conservation. This study investigated the distribution tendency of trace elements in municipal solid waste (MSW) or incinerator ash, including valuable non-ferrous metals (Ni, Co, Cr, Mn, Mo, Ti, V, W, Zr), precious group metals (PGMs) originated from WEEE (Ag, Au, Pd, Pt), and others (Al, B, Pb, Si), between Fe-rich and Cu-rich metal phases by means of simple thermodynamic calculations. Most of the typical alloying elements for steel (Co, Cr, Mo, Nb, Ni, Si, Ti, V, and W) and Rh were preferentially distributed into the Fe-rich phase. PGMs, such as Au, Ag, and Pd, were enriched in the Cu-rich phase, whereas Pt was almost equally distributed into both phases. Since the primary metallurgical processing of Cu is followed by an electrolysis for refining, and since PGMs in crude copper have been industrially recovered from the resulting anode slime, our results indicated that Ag, Au, and Pd could be effectively recovered from MSW if the Cu-rich phase could be selectively collected.

Lu, X. [School of Metallurgical and Ecological Engineering, The University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing 100083 (China); Nakajima, K.; Sakanakura, H. [Research Center for Material Cycles and Waste Management, National Institute for Environmental Studies (NIES), 16-2 Onogawa, Tsukuba 305-8506 (Japan); Matsubae, K. [Graduate School of Engineering, Tohoku University, 6-6-11 Aza-Aoba, Aramaki, Sendai 980-8579 (Japan); Bai, H. [School of Metallurgical and Ecological Engineering, The University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing 100083 (China); Nagasaka, T., E-mail: t-nagasaka@m.tohoku.ac.jp [Graduate School of Engineering, Tohoku University, 6-6-11 Aza-Aoba, Aramaki, Sendai 980-8579 (Japan)

2012-06-15T23:59:59.000Z

67

TRAITEMENT DES EFFLUENTS WASTE TREATMENT  

E-Print Network (OSTI)

TRAITEMENT DES EFFLUENTS WASTE TREATMENT Anaerobic digestion of pig manure B. DE LA FARGE Michèle properties of the methanized effluemt are preserved. A trial on anaerobic digestion of untreated pig manure technique du Porc, Station expérimentale, Les Cabrière.l, 12200 Villefranche-de-Rouer/(ue Frctnce Anaerobic

Recanati, Catherine

68

Geothermal waste treatment biotechnology  

DOE Green Energy (OSTI)

Technical feasibility of a biotechnology based on biochemical reactions for detoxification of geothermal brines has been demonstrated. Laboratory-scale studies have shown that the emerging biotechnology is versatile and is applicable to a variety of geothermal sludges and materials with similar geochemical properties. Materials suitable for treatment are those which may contain few or many metals in concentrations exceeding those allowed by regulatory agencies. Comparison of several possible types of bioreactors and processes have led to the conclusion that a number of variables have to be considered in the design and development of a biochemical plant for the detoxification of geothermal type sludges. These include reactor size, effects of agitation, mixed cultures, state of the biomass, pH and dissolved oxygen, concentration of residual sludge, residence time, and temperature. Under optimum conditions, high rates of metal removal can be achieved. Some recent studies, dealing with the process variables and their optimization, will be discussed. 6 refs., 3 figs.

Premuzic, E.T.; Lin, M.S.

1991-05-01T23:59:59.000Z

69

Overview of Integrated Waste Treatment Unit  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Integrated Waste Treatment Unit Overview Integrated Waste Treatment Unit Overview Overview for the DOE High Level Waste Corporate Board March 5, 2009 safety  performance  cleanup  closure M E Environmental Management Environmental Management 2 2 Integrated Waste Treatment Unit Mission * Mission - Project mission is to provide treatment of approximately 900,000 gallons of tank farm waste - referred to as sodium bearing waste (SBW) - stored at the Idaho Tank Farm Facility to a stable waste form suitable for disposition at the Waste Isolation Pilot Plant (WIPP). - Per the Idaho Cleanup Project contract, the resident Integrated Waste Treatment Unit (IWTU) facility, shall have the capability for future packaging and shipping of the existing high level waste (HLW) calcine to the geologic

70

Animal Waste Treatment System Loan Program (Missouri)  

Energy.gov (U.S. Department of Energy (DOE))

The purpose of the Animal Waste Treatment System Loan Program is to finance animal waste treatment systems for independent livestock and poultry producers at below conventional interest rates. Loan...

71

Scanned Treatment of Mixed Incin. Waste  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Treatment of Mixed Incinerable Treatment of Mixed Incinerable Waste DOE/IG-0588 March 2003 Page 17 Page 18 Use of Treatment Resources Details of Finding ........................................................................1 Recommendations and Comments ............................................6 Appendices Prior Reports ...............................................................................8 Objective, Scope, and Methodology ...........................................9 Management Comments ...........................................................11 TREATMENT OF MIXED INCINERABLE WASTE TABLE OF CONTENTS Page 1 Waste Stored Rather Than Treated We found the Department of Energy (Department) was not treating its mixed incinerable solid waste expeditiously or cost-effectively.

72

Waste treatment facility passes federal inspection, completes final  

NLE Websites -- All DOE Office Websites (Extended Search)

23, 2012 23, 2012 Media Contact: Danielle Miller, 208-526-5709 Erik Simpson, 208-390-9464 Waste treatment facility passes federal inspection, completes final milestone, begins startup The Idaho site today initiated the controlled, phased startup of a new waste treatment facility scheduled to begin treating 900,000 gallons of radioactive liquid waste stored in underground tanks at a former Cold War spent nuclear fuel reprocessing facility next month. An exterior view of the Integrated Waste Treatment Unit A U.S. Department of Energy (DOE) operational readiness review team (made up of Subject Matter Experts across the country) in early April identified a dozen issues for the cleanup contractor CH2M-WG Idaho, LLC (CWI) to resolve before the 53,000-square-foot Integrated Waste Treatment Unit

73

Waste Treatment Facility Passes Federal Inspection, Completes Final  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment Facility Passes Federal Inspection, Completes Final Waste Treatment Facility Passes Federal Inspection, Completes Final Milestone, Begins Startup Waste Treatment Facility Passes Federal Inspection, Completes Final Milestone, Begins Startup April 23, 2012 - 12:00pm Addthis Media Contact Erik Simpson, 208-390-9464 Danielle Miller, 208-526-5709 The Idaho site today initiated the controlled, phased startup of a new waste treatment facility scheduled to begin treating 900,000 gallons of radioactive liquid waste stored in underground tanks at a former Cold War spent nuclear fuel reprocessing facility next month. A U.S. Department of Energy (DOE) operational readiness review team (made up of Subject Matter Experts across the country) in early April identified a dozen issues for the cleanup contractor CH2M-WG Idaho, LLC (CWI) to

74

ICPP radioactive liquid and calcine waste technologies evaluation final report and recommendation  

SciTech Connect

Using a formalized Systems Engineering approach, the Latched Idaho Technologies Company developed and evaluated numerous alternatives for treating, immobilizing, and disposing of radioactive liquid and calcine wastes at the Idaho Chemical Processing Plant. Based on technical analysis data as of March, 1995, it is recommended that the Department of Energy consider a phased processing approach -- utilizing Radionuclide Partitioning for radioactive liquid and calcine waste treatment, FUETAP Grout for low-activity waste immobilization, and Glass (Vitrification) for high-activity waste immobilization -- as the preferred treatment and immobilization alternative.

1995-04-01T23:59:59.000Z

75

ADVANCED MIXED WASTE TREATMENT PROJECT (AMWTP)  

NLE Websites -- All DOE Office Websites (Extended Search)

ADVANCED MIXED WASTE TREATMENT PROJECT Idaho Treatment Group, LLC (ITG) Contract No. DE-EM0001467 You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations >...

76

Conversion of cellulosic wastes to liquid fuels  

DOE Green Energy (OSTI)

The current status and future plans for a project to convert waste cellulosic (biomass) materials to quality liquid hydrocarbon fuels is described. The basic approach is indirect liquefaction, i.e., thermal gasification followed by catalytic liquefaction. The indirect approach results in separation of the oxygen in the biomass feedstock, i.e., oxygenated compounds do not appear in the liquid hydrocarbon fuel product. The process is capable of accepting a wide variety of feedstocks. Potential products include medium quality gas, normal propanol, diesel fuel and/or high octane gasoline. A fluidized bed pyrolysis system is used for gasification. The pyrolyzer can be fluidized with recycle pyrolysis gas, steam or recycle liquefaction system off gas or some combination thereof. Tars are removed in a wet scrubber. Unseparated pyrolysis gases are utilized as feed to a modified Fischer-Tropsch reactor. The liquid condensate from the reactor consists of a normal propanol-water phase and a paraffinic hydrocarbon phase. The reactor can be operated to optimize for either product. The following tasks were specified in the statement of work for the contract period: (1) feedstock studies; (2) gasification system optimization; (3) waste stream characterization; and (4) liquid fuels synthesis. In addition, several equipment improvements were implemented.

Kuester, J.L.

1980-09-01T23:59:59.000Z

77

Performance estimates for waste treatment pyroprocesses in ATW  

SciTech Connect

The author has identified several pyrometallurgical processes for the conceptual ATW waste treatment cycle. These processes include reductive extraction, electrowinning and electrorefining, which constitute some versatile treatment cycles for liquid-metal based and molten-salt based waste forms when they are properly integrated. This paper examines the implementation of these processes and the achievable separations for some typical species. The author also presents a simple analysis of the processing rates limited by mass diffusion through a thin hydrodynamic boundary layer. It is shown that these processes can be realized with compact and efficient devices to meet the ATW demand for the periodic feeding and cleaning of the waste.

Li, N.

1997-05-01T23:59:59.000Z

78

Waste Treatment and Immobilation Plant HLW Waste Vitrification...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

compounds VSL Vitreous State Laboratory of the Catholic University of America WESP Wet Electrostatic Precipitator WGI Washington Group International WTP Waste Treatment and...

79

DOE Chooses Idaho Treatment Group, LLC to Disposition Waste at...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Chooses Idaho Treatment Group, LLC to Disposition Waste at the Advanced Mixed Waste Treatment Project: Contract will continue cleanup and waste operations at the Idaho Site DOE...

80

Mixed waste characterization, treatment & disposal focus area  

Science Conference Proceedings (OSTI)

The mission of the Mixed Waste Characterization, Treatment, and Disposal Focus Area (referred to as the Mixed Waste Focus Area or MWFA) is to provide treatment systems capable of treating DOE`s mixed waste in partnership with users, and with continual participation of stakeholders, tribal governments, and regulators. The MWFA deals with the problem of eliminating mixed waste from current and future storage in the DOE complex. Mixed waste is waste that contains both hazardous chemical components, subject to the requirements of the Resource Conservation and Recovery Act (RCRA), and radioactive components, subject to the requirements of the Atomic Energy Act. The radioactive components include transuranic (TRU) and low-level waste (LLW). TRU waste primarily comes from the reprocessing of spent fuel and the use of plutonium in the fabrication of nuclear weapons. LLW includes radioactive waste other than uranium mill tailings, TRU, and high-level waste, including spent fuel.

NONE

1996-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

DOE mixed waste treatment capacity analysis  

SciTech Connect

This initial DOE-wide analysis compares the reported national capacity for treatment of mixed wastes with the calculated need for treatment capacity based on both a full treatment of mixed low-level and transuranic wastes to the Land Disposal Restrictions and on treatment of transuranic wastes to the WIPP waste acceptance criteria. The status of treatment capacity is reported based on a fifty-element matrix of radiation-handling requirements and functional treatment technology categories. The report defines the classifications for the assessment, describes the models used for the calculations, provides results from the analysis, and includes appendices of the waste treatment facilities data and the waste stream data used in the analysis.

Ross, W.A.; Wehrman, R.R.; Young, J.R.; Shaver, S.R.

1994-06-01T23:59:59.000Z

82

Onsite Wastewater Treatment Systems: Liquid Chlorination  

E-Print Network (OSTI)

This publication explains the process, components, legal requirements, factors affecting performance, and maintenance needs of liquid chlorination systems for onsite wastewater treatment.

Weaver, Richard; Lesikar, Bruce J.; Richter, Amanda; O'Neill, Courtney

2008-10-23T23:59:59.000Z

83

Water Discharge from Waste Treatment - TMS  

Science Conference Proceedings (OSTI)

Oct 29, 1996 ... TMS Logo. About the 1996 International Symposium on Extraction and Processing for the Treatment and Minimization of Wastes ...

84

Independent Oversight Activity Report, Hanford Waste Treatment...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

(VSL). Bechtel National, Inc. (BNI) is the contractor responsible for the design and construction of the Hanford Site Waste Treatment and Immobilization Plant (WTP) for the...

85

Hanford Waste Treatment and Immobilization Plant Construction...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

conducted an independent review of selected aspects of construction quality at the Hanford Waste Treatment and Immobilization Project (WTP). The review, which was performed May...

86

Hanford Waste Treatment Plant Construction Quality Review  

NLE Websites -- All DOE Office Websites (Extended Search)

ARPT-WTP-2011-002 Site: DOE Hanford Waste Treatment Plant Subject: Office of Independent Oversight's Office of Environment, Safety and Health Evaluations Activity Report for the...

87

Hanford ETR Tank Waste Treatment and Immobilization Plant - Hanford Tank  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ETR Tank Waste Treatment and Immobilization Plant - Hanford ETR Tank Waste Treatment and Immobilization Plant - Hanford Tank Waste Treatment and Immobilization Plant Technical Review - External Flowsheet Review Team (Technical) Report Hanford ETR Tank Waste Treatment and Immobilization Plant - Hanford Tank Waste Treatment and Immobilization Plant Technical Review - External Flowsheet Review Team (Technical) Report Full Document and Summary Versions are available for download Hanford ETR Tank Waste Treatment and Immobilization Plant - Hanford Tank Waste Treatment and Immobilization Plant Technical Review - External Flowsheet Review Team (Technical) Report Summary - Flowsheet for the Hanford Waste Treatment Plant More Documents & Publications Waste Treatment and Immobilation Plant HLW Waste Vitrification Facility

88

Thermal Treatment of Solid Wastes Using the Electric Arc Furnace  

Science Conference Proceedings (OSTI)

A thermal waste treatment facility has been developed at the Albany Research Center (ARC) over the past seven years to process a wide range of heterogeneous mixed wastes, on a scale of 227 to 907 kg/h (500 to 2,000 lb/h). The current system includes a continuous feed system, a 3-phase AC, 0.8 MW graphite electrode arc furnace, and a dedicated air pollution control system (APCS) which includes a close-coupled thermal oxidizer, spray cooler, baghouse, and wet scrubber. The versatility of the complete system has been demonstrated during 5 continuous melting campaigns, ranging from 11 to 25 mt (12 to 28 st) of treated wastes per campaign, which were conducted on waste materials such as (a) municipal incinerator ash, (b) simulated low-level radioactive, high combustible-bearing mixed wastes, (c) simulated low-level radioactive liquid tank wastes, (d) heavy metal contaminated soils, and (e) organic-contaminated dredging spoils. In all cases, the glass or slag products readily passed the U.S. Environmental Protection Agency (EPA) Toxicity Characteristic Leachability Program (TCLP) test. Additional studies are currently under way on electric utility wastes, steel and aluminum industry wastes, as well as zinc smelter residues. Thermal treatment of these solid waste streams is intended to produce a metallic product along with nonhazardous glass or slag products.

O'Connor, W.K.; Turner, P.C.

1999-09-01T23:59:59.000Z

89

High-Level Liquid Waste Tank Integrity Workshop - 2008  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Liquid Waste Tank Integrity Liquid Waste Tank Integrity Workshop - 2008 Karthik Subramanian Bruce Wiersma November 2008 High Level Waste Corporate Board Meeting karthik.subramanian@srnl.doe.gov bruce.wiersma@srnl.doe.gov 2 Acknowledgements * Bruce Wiersma (SRNL) * Kayle Boomer (Hanford) * Michael T. Terry (Facilitator) * SRS - Liquid Waste Organization * Hanford Tank Farms * DOE-EM 3 Background * High level radioactive waste (HLW) tanks provide critical interim confinement for waste prior to processing and permanent disposal * Maintaining structural integrity (SI) of the tanks is a critical component of operations 4 Tank Integrity Workshop - 2008 * Discuss the HLW tank integrity technology needs based upon the evolving waste processing and tank closure requirements along with its continued storage mission

90

Independent Oversight Review, Waste Treatment and Immobilization Plant- December 2012  

Energy.gov (U.S. Department of Energy (DOE))

Review of the Hanford Site Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity

91

Waste Treatment and Immobilation Plant HLW Waste Vitrification Facility  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6 6 Technology Readiness Assessment for the Waste Treatment and Immobilization Plant (WTP) HLW Waste Vitrification Facility L. Holton D. Alexander C. Babel H. Sutter J. Young August 2007 Prepared by the U.S. Department of Energy Office of River Protection Richland, Washington, 99352 07-DESIGN-046 Technology Readiness Assessment for the Waste Treatment and Immobilization Plant (WTP) HLW Waste Vitrification Facility L. Holton D. Alexander C. Babel H. Sutter J. Young August 2007 Prepared by the U.S. Department of Energy Office of River Protection under Contract DE-AC05-76RL01830 07-DESIGN-046 iii Summary The U.S. Department of Energy (DOE), Office of River Protection (ORP) and the DOE Office of Environmental and Radioactive Waste Management (EM), Office of Project Recovery have completed a

92

System for recovering methane gas from liquid waste  

SciTech Connect

A system for and method of recovering methane gas from liquid waste which is stored within a pit is disclosed herein. The methane gas is produced by causing the liquid waste to undergo anaerobic fermentation. Therefore, it is necessary to close the pit in an air tight fashion. This is carried out using a cover sheet which is fixedly disposed over the pit in an air tight but readily disengagable fashion. The liquid waste within this air tight pit is preferably agitated intermittently during its storage therein whereby to increase the amount of methane gas produced.

Grabis, D.W.

1983-07-19T23:59:59.000Z

93

Detection of free liquid in containers of solidified radioactive waste  

DOE Patents (OSTI)

A method of nondestructively detecting the presence of free liquid within a sealed enclosure containing solidified waste by measuring the levels of waste at two diametrically opposite locations while slowly tilting the enclosure toward one of said locations. When the measured level remains constant at the other location, the measured level at said one location is noted and any measured difference of levels indicates the presence of liquid on the surface of the solidified waste. The absence of liquid in the enclosure is verified when the measured levels at both locations are equal.

Greenhalgh, Wilbur O. (Richland, WA)

1985-01-01T23:59:59.000Z

94

Liquid and Gaseous Waste Operations Project Annual Operating Report CY 1999  

SciTech Connect

A total of 5.77 x 10 7 gallons (gal) of liquid waste was decontaminated by the Process Waste Treatment Complex (PWTC) - Building 3544 ion exchange system during calendar year (CY) 1999. This averaged to 110 gpm throughout the year. An additional 3.94 x 10 6 gal of liquid waste (average of 8 gpm throughout the year) was decontaminated using the zeolite treatment system due to periods of high Cesium levels in the influent wastewater. A total of 6.17 x 10 7 gal of liquid waste (average of 118 gpm throughout the year) was decontaminated at Building 3544 during the year. During the year, the regeneration of the ion exchange resins resulted in the generation of 8.00 x 10 3 gal of Liquid Low-Level Waste (LLLW) concentrate and 9.00 x 10 2 gal of LLLW supernate. See Table 1 for a monthly summary of activities at Building 3544. Figure 1 shows a diagram of the Process Waste Collection and Transfer System and Figure 2 shows a diagram of the Building 3544 treatment process. Figures 3, 4 5, and 6 s how a comparison of operations at Building 3544 in 1997 with previous years. Figure 7 shows a comparison of annual rainfall at Oak Ridge National Laboratory (ORNL) since 1995.

Maddox, J.J.; Scott, C.B.

2000-03-01T23:59:59.000Z

95

Treatment of Wastes Containing Arsenic, Selenium and Mercury I  

Science Conference Proceedings (OSTI)

TMS Logo. About the 1996 International Symposium on Extraction and Processing for the Treatment and Minimization of Wastes: Treatment of Wastes ...

96

Advanced Mixed Waste Treatment Project Achieves Impressive Safety...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks June...

97

Independent Oversight Review, Hanford Waste Treatment and Immobilizati...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Immobilization Plant - December 2013 December 2013 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality This report...

98

Independent Oversight Review, Hanford Site Waste Treatment and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Immobilization Plant, August 2013 Independent Oversight Review, Hanford Site Waste Treatment and Immobilization Plant, August 2013 August 2013 Review of the...

99

Review of the Hanford Site Waste Treatment and Immobilization...  

NLE Websites -- All DOE Office Websites (Extended Search)

WTP Waste Treatment and Immobilization Plant ii Independent Oversight Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality 1.0 PURPOSE The U....

100

Hanford Tank Waste Treatment and Immobilization Plan Project...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Tank Waste Treatment and Immobilization Plan Project PIA, Richland Operations Office Hanford Tank Waste Treatment and Immobilization Plan Project PIA, Richland Operations...

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Review of the Hanford Site Waste Treatment and Immobilization...  

NLE Websites -- All DOE Office Websites (Extended Search)

WTP Waste Treatment and Immobilization Plant ii Independent Oversight Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality 1.0 PURPOSE The...

102

Review of the Hanford Site Waste Treatment and Immobilization...  

NLE Websites -- All DOE Office Websites (Extended Search)

Waste Treatment and Immobilization Plant Project 1 Independent Oversight Review of the Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality 1.0...

103

Final Hanford Offsite Waste Shipment Leaves Idaho Treatment Facility...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Final Hanford Offsite Waste Shipment Leaves Idaho Treatment Facility Final Hanford Offsite Waste Shipment Leaves Idaho Treatment Facility August 18, 2011 - 12:00pm Addthis Idaho...

104

Idaho Waste Treatment Facility Improves Worker Safety and Efficiency...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment Facility Improves Worker Safety and Efficiency, Saves Taxpayer Dollars Idaho Waste Treatment Facility Improves Worker Safety and Efficiency, Saves Taxpayer Dollars...

105

Idaho Waste Treatment Facility Startup Testing Suspended To Evaluate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Idaho Waste Treatment Facility Startup Testing Suspended To Evaluate System IDAHO FALLS, ID- On Saturday, June 16, startup testing was suspended at the Integrated Waste Treatment...

106

Independent Activity Report, Hanford Waste Treatment Plant - February 2011  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Activity Report, Hanford Waste Treatment Plant - Activity Report, Hanford Waste Treatment Plant - February 2011 Independent Activity Report, Hanford Waste Treatment Plant - February 2011 February 2011 Hanford Waste Treatment Plant Construction Quality Assurance Review [ARPT-WTP-2011-002] The purpose of the visit was to perform a review of construction quality assurance at the Waste Treatment Plant (WTP) site activities concurrently with the Department of Energy (DOE) WTP staff. One focus area for this visit was piping and pipe support installations. Independent Activity Report, Hanford Waste Treatment Plant - February 2011 More Documents & Publications Independent Oversight Review, Waste Treatment and Immobilization Plant - August 2011 Independent Oversight Review, Waste Treatment and Immobilization Plant -

107

WASTE TREATMENT AND DISPOSAL PROBLEMS OF THE FUTURE NUCLEAR POWER INDUSTRY  

SciTech Connect

The elements of waste treatment and disposal are assessed which are expected to become important in the development of the nuclear power industry of the future. Growth of the nuclear power economy is considered along with composition and quantities of anticipated waste. In addition, the economic implications of waste disposal are considered. It is concluded that research should be concentrated on decontaminating off-gases and on conversion of wastes to a more suitable form than liquid for storage. (J.R.D.)

Bruce, F.R.

1959-01-28T23:59:59.000Z

108

RECOVERY OF MERCURY FROM CONTAMINATED LIQUID WASTES  

SciTech Connect

Mercury was widely used in U.S. Department of Energy (DOE) weapons facilities, resulting in a broad range of mercury-contaminated wastes and wastewaters. Some of the mercury contamination has escaped to the local environment, particularly at the Y-12 Plant in Oak Ridge, Tennessee, where approximately 330 metric tons of mercury were discharged to the environment between 1953 and 1963 (TN & Associates, 1998). Effective removal of mercury contamination from water is a complex and difficult problem. In particular, mercury treatment of natural waters is difficult because of the low regulatory standards. For example, the Environmental Protection Agency has established a national ambient water quality standard of 12 parts-per-trillion (ppt), whereas the standard is 1.8 ppt in the Great Lakes Region. In addition, mercury in the environment is typically present in several different forms, but sorption processes are rarely effective with more than one or two of these forms. To meet the low regulatory discharge limits, an effective sorption process must be able to address all forms of mercury present in the water. One approach is to apply different sorbents in series depending on the mercury speciation and the regulatory discharge limits. ADA Technologies, Inc. has developed four new sorbents to address the variety of mercury species present in industrial discharges and natural waters. Three of these sorbents have been field tested on contaminated creek water at the Y-12 Plant. Two of these sorbents have been successfully demonstrated very high removal efficiencies for soluble mercury species, reducing mercury concentrations at the outlet of a pilot-scale system to less than 12 ppt for as long as six months. The other sorbent tested at the Y-12 Plant targeted colloidal mercury not removed by standard sorption or filtration processes. At the Y-12 Plant, colloidal mercury appears to be associated with iron, so a sorbent that removes mercury-iron complexes in the presence of a magnetic field was evaluated. Field results indicated good removal of this mercury fraction from the Y-12 waters. In addition, this sorbent is easily regenerated by simply removing the magnetic field and flushing the columns with water. The fourth sorbent is still undergoing laboratory development, but results to date indicate exceptionally high mercury sorption capacity. The sorbent is capable of removing all forms of mercury typically present in natural and industrial waters, including Hg{sup 2+}, elemental mercury, methyl mercury, and colloidal mercury. The process possesses very fast kinetics, which allows for higher flow rates and smaller treatment units. These sorbent technologies, used in tandem or individually depending on the treatment needs, can provide DOE sites with a cost-effective method for reducing mercury concentrations to very low levels mandated by the regulatory community. In addition, the technologies do not generate significant amounts of secondary wastes for disposal. Furthermore, the need for improved water treatment technologies is not unique to the DOE. The new, stringent requirements on mercury concentrations impact other government agencies as well as the private sector. Some of the private-sector industries needing improved methods for removing mercury from water include mining, chloralkali production, chemical processing, and medical waste treatment. The next logical step is to deploy one or more of these sorbents at a contaminated DOE site or at a commercial facility needing improved mercury treatment technologies. A full-scale deployment is planned in fiscal year 2000.

Robin M. Stewart

1999-09-29T23:59:59.000Z

109

Process development for remote-handled mixed-waste treatment  

SciTech Connect

The Oak Ridge National Laboratory (ORNL) is developing a treatment process for remote-handled (RH) liquid transuranic mixed waste governed by the concept of minimizing the volume of waste requiring disposal. This task is to be accomplished by decontaminating the bulk components so the process effluent can be disposed with less risk and expense. Practical processes have been demonstrated on the laboratory scale for removing cesium 137 and strontium 90 isotopes from the waste, generating a concentrated waste volume, and rendering the bulk of the waste nearly radiation free for downstream processing. The process is projected to give decontamination factors of 10{sup 4} for cesium and 10{sup 3} for strontium. Because of the extent of decontamination, downstream processing will be contact handled. The transuranic, radioactive fraction of the mixed waste stream will be solidified using a thin-film evaporator and/or microwave solidification system. Resultant solidified waste will be disposed at the Waste Isolation Pilot Plant (WIPP). 8 refs., 2 figs., 3 tabs.

Berry, J.B.; Campbell, D.O.; Lee, D.D.; White, T.L.

1990-01-01T23:59:59.000Z

110

NORDIC WASTE WATER TREATMENT SLUDGE TREATMENT  

E-Print Network (OSTI)

biogas, electricity and fertilizer from 30 000 tons of annually waste. The plant was opened in March 2008 together it an- nually produces 18,9 GWh biogas and around 10 GWh of elec- tricity. The Cambi THP ­process

111

Drilling Waste Management Fact Sheet: Thermal Treatment  

NLE Websites -- All DOE Office Websites (Extended Search)

range from 75 to 150ton (Bansal and Sugiarto 1999). Many factors can impact treatment costs, including oil and moisture content of the waste, particle size distribution of the...

112

Independent Oversight Review, Waste Treatment and Immobilization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2013 January 2013 Review of the Hanford Waste Treatment and Immobilization Plant Black-Cell and Hard-To-Reach Pipe Spools Procurement Process and the Office of River...

113

ENVIRONMENTAL ASSESSMENT FOR WASTE WATER TREATMENT MODIFICATIONS  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

WASTE WATER TREATMENT MODIFICATIONS WASTE WATER TREATMENT MODIFICATIONS FOR IMPROVED EFFLUENT COMPLIANCE BROOKHAVEN NATIONAL LABORATORY UPTON, NEW YORK BROOKHAVEN SITE OFFICE JUNE 24, 2011 DOE/EA-1854 i Table of Contents 1.0 INTRODUCTION ............................................................................................................... 1 2.0 SUMMARY ........................................................................................................................ 1 3.0 PURPOSE AND NEED ....................................................................................................17 4.0 ALTERNATIVES ..............................................................................................................17 4.1 Alternative 1 - Groundwater Recharge System (Preferred Alternative) .............. 17

114

HNPF LIQUID WASTE DISPOSAL COST STUDY  

SciTech Connect

The HNPF cost analysis for waste disposal was made on the basis of 10,000 gallons of laundry waste and 9,000 gallons of other plant waste per year. The costs are compared for storage at HNPF site for 10 yr, packaging and shipment to AEC barial ground, packaging and shipment for sea disposal, and disposal by licensed vendor. A graphical comparison is given for the yearly costs of disposal by licensed vendor and the evaporator system as a function of waste volume. Recommendations are included for the handling of the wastes expected from HNPF operations. (B.O.G.)

Piccot, A.R.

1959-11-01T23:59:59.000Z

115

TREATMENT OF FISSION PRODUCT WASTE  

DOE Patents (OSTI)

A pyrogenic method of separating nuclear reactor waste solutions containing aluminum and fission products as buring petroleum coke in an underground retort, collecting the easily volatile gases resulting as the first fraction, he uminum chloride as the second fraction, permitting the coke bed to cool and ll contain all the longest lived radioactive fission products in greatly reduced volume.

Huff, J.B.

1959-07-28T23:59:59.000Z

116

Waste Treatment and Immobilization Plant (WTP) Analytical Laboratory (LAB),  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Immobilization Plant (WTP) Analytical Immobilization Plant (WTP) Analytical Laboratory (LAB), Balance of Facilities (BOF) and Low-Activity Waste Vitrification Facilities (LAW) Waste Treatment and Immobilization Plant (WTP) Analytical Laboratory (LAB), Balance of Facilities (BOF) and Low-Activity Waste Vitrification Facilities (LAW) Full Document and Summary Versions are available for download Waste Treatment and Immobilization Plant (WTP) Analytical Laboratory (LAB), Balance of Facilities (BOF) and Low-Activity Waste Vitrification Facilities (LAW) Summary - WTP Analytical Lab, BOF and LAW Waste Vitrification Facilities More Documents & Publications Waste Treatment and Immobilation Plant HLW Waste Vitrification Facility Waste Treatment and Immobilation Plant Pretreatment Facility Compilation of TRA Summaries

117

Hanford ETR - Tank Waste Treatment and Immobilization Plant - Hanford Tank  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

- Tank Waste Treatment and Immobilization Plant - - Tank Waste Treatment and Immobilization Plant - Hanford Tank Waste Treatment and Immobilization Plant Technical Review - Estimate at Completion (Cost) Report Hanford ETR - Tank Waste Treatment and Immobilization Plant - Hanford Tank Waste Treatment and Immobilization Plant Technical Review - Estimate at Completion (Cost) Report This is a comprehensive review ofthe Hanford WTP estimate at completion - assessing the project scope, contract requirements, management execution plant, schedule, cost estimates, and risks. Hanford ETR - Tank Waste Treatment and Immobilization Plant - Hanford Tank Waste Treatment and Immobilization Plant Technical Review - Estimate at Completion (Cost) Report More Documents & Publications TBH-0042 - In the Matter of Curtis Hall

118

THE TREATMENT OF LOW ACTIVITY AQUEOUS WASTES  

SciTech Connect

The equipment and treatment methods for processing low-activity aqueous wastes at the Latina nuclear power station are discussed. The effluent treatment plant serves two purposes: purification of cooling pond water and decontamination of aqueous wastes from such outlets as regenerant solutions, active laundry and change houses, decontamination center, coffin washing, and charge machine washing. The treatment process consists of chemical precipitation followed by filtration of the sludges thus produced. The process is then followed by ion exchange on a natural inorganic material such as vermiculite and evaporation. This process produces a decontamination factor of l0/sup 3/ to 10/ sup 4/. (N.W.R.)

Cartwright, A.C.

1962-01-01T23:59:59.000Z

119

Energy-Efficient Industrial Waste Treatment Technologies  

Science Conference Proceedings (OSTI)

Rising energy costs coupled with the continuing need for effective environmental treatment methods have stimulated interest in advanced energy-efficient technologies. EPRI has reviewed a wide variety of electricity-based processes for industrial air pollution control, wastewater treatment, and solid waste treatment along with some closely related competing technologies. These technologies ranged from untested concepts to well-established ones. While most offer process cost savings and improvements over e...

2007-10-31T23:59:59.000Z

120

Hanford Waste Treatment Plant Construction Quality Review  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ARPT-WTP-2011-002 ARPT-WTP-2011-002 Site: DOE Hanford Waste Treatment Plant Subject: Office of Independent Oversight's Office of Environment, Safety and Health Evaluations Activity Report for the Hanford Waste Treatment Plant Construction Quality Review Dates of Activity 02/14/2011 - 02/17/2011 Report Preparer Joseph Lenahan Activity Description/Purpose: The purpose of the visit was to perform a review of construction quality assurance at the Waste Treatment Plant (WTP) site activities concurrently with the Department of Energy (DOE) WTP staff. One focus area for this visit was piping and pipe support installations. The Office of Health, Safety and Security (HSS) attended several Bechtel National Incorporated (BNI) project meetings, reviewed the WTP project quality assurance program, reviewed DOE-WTP inspection reports completed by the DOE-WTP

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

WASTE TREATMENT BUILDING VENTILATION SYSTEM DESCRIPTION DOCUMENT  

SciTech Connect

The Waste Treatment Building Ventilation System provides heating, ventilation, and air conditioning (HVAC) for the contaminated, potentially contaminated, and uncontaminated areas of the Monitored Geologic Repository's (MGR) Waste Treatment Building (WTB). In the uncontaminated areas, the non-confinement area ventilation system maintains the proper environmental conditions for equipment operation and personnel comfort. In the contaminated and potentially contaminated areas, in addition to maintaining the proper environmental conditions for personnel comfort and equipment operation, the contamination confinement area ventilation system directs potentially contaminated air away from personnel in the WTB and confines the contamination within high-efficiency particulate air (HEPA) filtration units. The contamination confinement area ventilation system creates airflow paths and pressure zones to minimize the potential for spreading contamination with the building. The contamination confinement ventilation system also protects the environment and the public by limiting airborne releases of radioactive or other hazardous contaminants from the WTB. The Waste Treatment Building Ventilation System confines the radioactive and hazardous material within the building such that the release rates comply with regulatory limits, The system design, operations, and maintenance activities incorporate ALARA (as low as is reasonably achievable) principles to maintain personnel radiation doses to all occupational workers below regulatory limits and as low as is reasonably achievable. The system provides status of important system parameters and equipment operation, and provides audible and/or visual indication of off-normal conditions and equipment failures. The Waste Treatment Building Ventilation System interfaces with the Waste Treatment Building System by being located in the WTB, and by maintaining specific pressure, temperature, and humidity environments within the building. The system also depends on the WTB for normal electric power supply and the required supply of water for heating, cooling, and humidification. Interface with the Waste Treatment Building System includes the WTB fire protection subsystem for detection of fire and smoke. The Waste Treatment Building Ventilation System interfaces with the Site Radiological Monitoring System for continuous monitoring of the exhaust air and key areas within the WTB, the Monitored Geologic Repository Operations Monitoring and Control System for monitoring and control of system operations, and the Site Generated Radiological Waste Handling System and Site Generated Hazardous, Non-Hazardous & Sanitary Waste Disposal System for routing of pretreated toxic, corrosive, and radiologically contaminated effluent from process equipment to the HEPA filter exhaust ductwork and air-cleaning unit.

P.A. Kumar

2000-06-22T23:59:59.000Z

122

Isolation of Metals from Liquid Wastes: Reactive in Turbulent Thermal Reactors  

SciTech Connect

A Generic Technology for treatment of DOE Metal-Bearing Liquid Waste The DOE metal-bearing liquid waste inventory is large and diverse, both with respect to the metals (heavy metals, transuranics, radionuclides) themselves, and the nature of the other species (annions, organics, etc.) present. Separation and concentration of metals is of interest from the standpoint of reducing the volume of waste that will require special treatment or isolation, as well as, potentially, from the standpoint of returning some materials to commerce by recycling. The variety of metal-bearing liquid waste in the DOE complex is so great that it is unlikely that any one process (or class of processes) will be suitable for all material. However, processes capable of dealing with a wide variety of wastes will have major advantages in terms of process development, capital, and operating costs, as well as in environmental and safety permitting. Moreover, to the extent that a process operates well with a variety of metal-bearing liquid feedwastes, its performance is likely to be relatively robust with respect to the inevitable composition variations in each waste feed. One such class of processes involves high-temperature treatment of atomized liquid waste to promote reactive capture of volatile metallic species on collectible particulate substrates injected downstream of a flame zone. Compared to low-temperature processes that remove metals from the original liquid phase by extraction, precipitation, ion exchange, etc., some of the attractive features of high-temperature reactive scavenging are: The organic constituents of some metal-bearing liquid wastes (in particular, some low-level mixed wastes) must be treated thermally in order to meet the requirements of the Resource Conservation and Recovery Act (RCRA) and Toxic Substances Control Act (TSCA), and the laws of various states. No species need be added to an already complex liquid system. This is especially important in light of the fact that DOE has already experienced problems with organic complexants added to precipitate radionuclides. For example, the Defense Nuclear Facilities Safety Board has expressed, in a formal Recommendation to the Secretary of Energy, its concern about the evolution of benzene vapor in concentrations greater then the lower flammability limit from tanks to which sodium tetraphenylborate has been added to precipitate 137Cs in the ''In-Tank Precipitation'' (ITP) process at the Savannah River Site. Other species added to the waste in the ITP process are sodium titanate (to adsorb 90Sr and Pu), and oxalic acid. Avoiding addition of organics to radioactive waste has the additional advantage that is likely to significantly reduce the rate of radiolytic and radiolytically-induced hydrogen generation (c.f. Meisel et al., [1993]), in which it is shown that removal of organics reduces the rate of hydrogen generation in simulated waste from Hanford tank 241-SY-101 by over 70%. Organic species already present are destroyed with very high efficiency. This attribute is especially attractive with respect to high-level tank waste at the Hanford Site, in which large amounts of citrate, glyoxylate, EDTA (ethylenediaminetetraacetic acid), and HEDTA [N-(2- hydroxyethyl)-ethylenediaminetriacetic acid] were added to precipitate radionuclides. These organic species are important in the thermal and radiolytic generation of methane, hydrogen, and nitrous oxide, flammable mixtures of which are episodically vented from 25 tanks on Hanford's Flammable Gas Watch List [Hopkins, 1994]. The same basic approach can be used to treat a broad range of liquid wastes, in each case concentrating the metals (regardless of liquid-phase oxidation state or association with chelators or absorbents) using a collectible sorbent, and destroying any organic species present. In common with the Army's approach (see section 2.2) to the thermal destruction of a 10 range of chemical warfare agents (GB, VX, and two blister agents), this may drastically simplify process and plant design and

Wendt, Jost O.L.

2001-09-30T23:59:59.000Z

123

Independent Activity Report, Waste Treatment and Immobilization Plant- March 2013  

Energy.gov (U.S. Department of Energy (DOE))

Follow-up of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity Review [HIAR-WTP-2013-03-18

124

Audit Report Waste Treatment Plans at the Idaho National Engineering...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Reduction Plans for the Advanced Mixed Waste TreatmentProject at the Idaho National Engineering and EnvironmentalLaboratory, IG-0611 Energy.gov Careers & Internships Hotline...

125

Activity Report for Waste Treatment and Immobilizationi Plant...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Waste Treatment and Immobilization Plant Low Activity Waste Melter Off-gas Process...

126

Strategies for the cost effective treatment of Oak Ridge legacy wastes  

Science Conference Proceedings (OSTI)

Research and development treatment strategies for treatment or elimination of several Oak Ridge plant liquid, solid, and legacy wastes are detailed in this report. Treatment strategies for volumetrically contaminated nickel; enriched uranium-contaminated alkali metal fluorides; uranium-contaminated aluminum compressor blades; large, mercury-contaminated lithium isotope separations equipment; lithium process chlorine gas streams; high-concentration aluminum nitrate wastes, and high-volume, low-level nitrate wastes are discussed. Research needed to support engineering development of treatment processes is detailed.

Compere, A.L.; Griffith, W.L.; Huxtable, W.P.; Wilson, D.F.

1998-03-01T23:59:59.000Z

127

Update of the management strategy for Oak Ridge National Laboratory Liquid Low-Level Waste  

Science Conference Proceedings (OSTI)

The strategy for management of the Oak Ridge National Laboratory`s (ORNL) radioactively contaminated liquid waste was reviewed in 1991. The latest information available through the end of 1990 on waste characterization, regulations, US Department of Energy (DOE) budget guidance, and research and development programs was evaluated to determine how the strategy should be revised. Few changes are needed to update the strategy to reflect new waste characterization, research, and regulatory information. However, recent budget guidance from DOE indicates that minimum funding will not be sufficient to accomplish original objectives to upgrade the liquid low-level waste (LLLW) system to comply with the Federal Facilities Agreement, provide long-term LLLW treatment capability, and minimize environmental, safety, and health risks. Options are presented that might allow the ORNL LLLW system to continue operations temporarily, but they would significantly reduce its capabilities to handle emergency situations, provide treatment for new waste streams, and accommodate waste from the Environmental Restoration Program and from decontamination and decommissioning of surplus facilities. These options are also likely to increase worker radiation exposure, risk of environmental insult, and generation of solid waste for on-site and off-site disposal/storage beyond existing facility capacities. The strategy will be fully developed after receipt of additional guidance. The proposed budget limitations are too severe to allow ORNL to meet regulatory requirements or continue operations long term.

Robinson, S.M.; Abraham, T.J.; DePaoli, S.M.; Walker, A.B.

1995-04-01T23:59:59.000Z

128

HIGH TEMPERATURE TREATMENT OF INTERMEDIATE-LEVEL RADIOACTIVE WASTES - SIA RADON EXPERIENCE  

SciTech Connect

This review describes high temperature methods of low- and intermediate-level radioactive waste (LILW) treatment currently used at SIA Radon. Solid and liquid organic and mixed organic and inorganic wastes are subjected to plasma heating in a shaft furnace with formation of stable leach resistant slag suitable for disposal in near-surface repositories. Liquid inorganic radioactive waste is vitrified in a cold crucible based plant with borosilicate glass productivity up to 75 kg/h. Radioactive silts from settlers are heat-treated at 500-700 0C in electric furnace forming cake following by cake crushing, charging into 200 L barrels and soaking with cement grout. Various thermochemical technologies for decontamination of metallic, asphalt, and concrete surfaces, treatment of organic wastes (spent ion-exchange resins, polymers, medical and biological wastes), batch vitrification of incinerator ashes, calcines, spent inorganic sorbents, contaminated soil, treatment of carbon containing 14C nuclide, reactor graphite, lubricants have been developed and implemented.

Sobolev, I.A.; Dmitriev, S.A.; Lifanov, F.A.; Kobelev, A.P.; Popkov, V.N.; Polkanov, M.A.; Savkin, A.E.; Varlakov, A.P.; Karlin, S.V.; Stefanovsky, S.V.; Karlina, O.K.; Semenov, K.N.

2003-02-27T23:59:59.000Z

129

Biological treatment of refinery wastes  

SciTech Connect

A detailed study of the treatment situation at a Thai refinery that used an API separator with no equalization tank, followed by an activated-sludge system, showed that only 42% of the total COD and 57% of the soluble COD was degradable. In a study of the possibility of additional treatments, an aerated lagoon showed promising results. The wastewater composition of the three main Thai refineries was surveyed.

Mahmud, Z.; Thanh, N.C.

1978-01-01T23:59:59.000Z

130

Recovery of valuable materials from waste liquid crystal display panel  

Science Conference Proceedings (OSTI)

Associated with the rapid development of the information and electronic industry, liquid crystal displays (LCDs) have been increasingly sold as displays. However, during the discarding at their end-of-life stage, significant environmental hazards, impacts on health and a loss of resources may occur, if the scraps are not managed in an appropriate way. In order to improve the efficiency of the recovery of valuable materials from waste LCDs panel in an environmentally sound manner, this study presents a combined recycling technology process on the basis of manual dismantling and chemical treatment of LCDs. Three key processes of this technology have been studied, including the separation of LCD polarizing film by thermal shock method the removal of liquid crystals between the glass substrates by the ultrasonic cleaning, and the recovery of indium metal from glass by dissolution. The results show that valuable materials (e.g. indium) and harmful substances (e.g. liquid crystals) could be efficiently recovered or separated through above-mentioned combined technology. The optimal conditions are: (1) the peak temperature of thermal shock to separate polarizing film, ranges from 230 to 240 deg. C, where pyrolysis could be avoided; (2) the ultrasonic-assisted cleaning was most efficient at a frequency of 40 KHz (P = 40 W) and the exposure of the substrate to industrial detergents for 10 min; and (3) indium separation from glass in a mix of concentrated hydrochloric acid at 38% and nitric acid at 69% (HCl:HNO{sub 3}:H{sub 2}O = 45:5:50, volume ratio). The indium separation process was conducted with an exposure time of 30 min at a constant temperature of 60 deg. C.

Li Jinhui [Department of Environmental Science and Engineering, Tsinghua University (China); Sino-Italia Environmental Energy Building, Room 804, Haidian District, Beijing 100084 (China)], E-mail: jinhui@tsinghua.edu.cn; Gao Song; Duan Huabo; Liu Lili [Department of Environmental Science and Engineering, Tsinghua University (China)

2009-07-15T23:59:59.000Z

131

Medical waste treatment and decontamination system  

DOE Patents (OSTI)

The invention discloses a tandem microwave system consisting of a primary chamber in which hybrid microwave energy is used for the controlled combustion of materials. A second chamber is used to further treat the off-gases from the primary chamber by passage through a susceptor matrix subjected to additional hybrid microwave energy. The direct microwave radiation and elevated temperatures provide for significant reductions in the qualitative and quantitative emissions of the treated off gases. The tandem microwave system can be utilized for disinfecting wastes, sterilizing materials, and/or modifying the form of wastes to solidify organic or inorganic materials. The simple design allows on-site treatment of waste by small volume waste generators.

Wicks, George G. (Aiken, SC); Schulz, Rebecca L. (Aiken, SC); Clark, David E. (Gainesville, FL)

2001-01-01T23:59:59.000Z

132

Treatment of Radioactive Reactive Mixed Waste  

Science Conference Proceedings (OSTI)

PacificEcoSolutions, Inc. (PEcoS) has installed a plasma gasification system that was recently modified and used to destroy a trimethyl-aluminum mixed waste stream from Los Alamos National Laboratory (LANL.) The unique challenge in handling reactive wastes like trimethyl-aluminum is their propensity to flame instantly on contact with air and to react violently with water. To safely address this issue, PacificEcoSolutions has developed a new feed system to ensure the safe containment of these radioactive reactive wastes during transfer to the gasification unit. The plasma gasification system safely processed the radioactively contaminated trimethyl-metal compounds into metal oxides. The waste stream came from LANL research operations, and had been in storage for seven years, pending treatment options. (authors)

Colby, S.; Turner, Z.; Utley, D. [Pacific EcoSolutions, Inc., 2025 Battelle Boulevard, Richland, Washington 99354 (United States); Duy, C. [Los Alamos National Laboratory - LA-UR-05-8410, Post Office Box 1663 MS J595, Los Alamos, New Mexico 97545 (United States)

2006-07-01T23:59:59.000Z

133

Treatment option evaluation for liquid effluent secondary streams on the Hanford Site  

SciTech Connect

This study, conducted by the Pacific Northwest Laboratory (PNL) for Westinghouse Hanford Company (WHC), examines the range of secondary waste types and volumes likely to result from treatment of contaminated liquid effluents. Alternatives for treatment of these effluents were considered, taking into account the implementation of the ''best-available technology'' as assumed in current and ongoing engineering studies for treating the various liquid effluent waste streams. These treatment alternatives, and potential variations in the operating schedules for Hanford Site facilities generating contaminated liquid effluents, were evaluated to project an estimated range for the volume of each of the various secondary waste streams that are likely to be generated. The conclusions and recommendations were developed, based on these estimates. 23 refs., 34 figs., 16 tabs.

Holter, G.M.; Triplett, M.B.; Fow, C.L.; White, M.K.

1988-08-01T23:59:59.000Z

134

IDAHO SITE TO PROVIDE WASTE TREATMENT FOR OTHER DOE SITES  

NLE Websites -- All DOE Office Websites (Extended Search)

March 7, 2008 IDAHO SITE TO PROVIDE WASTE TREATMENT FOR OTHER DOE SITES Plan won't impact DOE commitment to removing all stored waste from Idaho Site Idaho's Advanced Mixed Waste...

135

Idaho Site Launches Startup of Waste Treatment Facility Following Federal  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Launches Startup of Waste Treatment Facility Following Launches Startup of Waste Treatment Facility Following Federal Inspection, DOE Milestone Idaho Site Launches Startup of Waste Treatment Facility Following Federal Inspection, DOE Milestone April 23, 2012 - 12:00pm Addthis A controlled, phased startup of the Integrated Waste Treatment Unit began today after the facility passed a federal inspection. A controlled, phased startup of the Integrated Waste Treatment Unit began today after the facility passed a federal inspection. A view of the interior of the Integrated Waste Treatment Unit. A view of the interior of the Integrated Waste Treatment Unit. A controlled, phased startup of the Integrated Waste Treatment Unit began today after the facility passed a federal inspection. A view of the interior of the Integrated Waste

136

Idaho Site Launches Startup of Waste Treatment Facility Following Federal  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Idaho Site Launches Startup of Waste Treatment Facility Following Idaho Site Launches Startup of Waste Treatment Facility Following Federal Inspection, DOE Milestone Idaho Site Launches Startup of Waste Treatment Facility Following Federal Inspection, DOE Milestone April 23, 2012 - 12:00pm Addthis A controlled, phased startup of the Integrated Waste Treatment Unit began today after the facility passed a federal inspection. A controlled, phased startup of the Integrated Waste Treatment Unit began today after the facility passed a federal inspection. A view of the interior of the Integrated Waste Treatment Unit. A view of the interior of the Integrated Waste Treatment Unit. A controlled, phased startup of the Integrated Waste Treatment Unit began today after the facility passed a federal inspection. A view of the interior of the Integrated Waste

137

Idaho Site Launches Corrective Actions Before Restarting Waste Treatment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Corrective Actions Before Restarting Waste Corrective Actions Before Restarting Waste Treatment Facility Idaho Site Launches Corrective Actions Before Restarting Waste Treatment Facility September 13, 2012 - 12:00pm Addthis Pictured here is the Integrated Waste Treatment Unit's off-gas filter following the June incident. Pictured here is the Integrated Waste Treatment Unit's off-gas filter following the June incident. A view of the process piping installations prior to startup of the Integrated Waste Treatment Unit. A view of the process piping installations prior to startup of the Integrated Waste Treatment Unit. Pictured here is the Integrated Waste Treatment Unit's off-gas filter following the June incident. A view of the process piping installations prior to startup of the Integrated Waste Treatment Unit.

138

Waste Form Development for the Solidification of PDCF/MOX Liquid Waste Streams  

SciTech Connect

At the Savannah River Site, part of the Department of Energy's nuclear materials complex located in South Carolina, cementation has been selected as the solidification method for high-alpha and low-activity waste streams generated in the planned plutonium disposition facilities. A Waste Solidification Building (WSB) that will be used to treat and solidify three radioactive liquid waste streams generated by the Pit Disassembly and Conversion Facility) and the Mixed Oxide Fuel Fabrication Facility is in the preliminary design stage. The WSB is expected to treat a transuranic (TRU) waste stream composed primarily of americium and two low-level waste (LLW) streams. The acidic wastes will be concentrated in the WSB evaporator and neutralized in a cement head tank prior to solidification. A series of TRU mixes were prepared to produce waste forms exhibiting a range of processing and cured properties. The LLW mixes were prepared using the premix from the preferred TRU waste form. All of the waste forms tested passed the Toxicity Characteristic Leaching Procedure. After processing in the WSB, current plans are to dispose of the solidified TRU waste at the Waste Isolation Pilot Plant in New Mexico and the solidified LLW waste at an approved low-level waste disposal facility.

COZZI, ALEX

2004-02-18T23:59:59.000Z

139

Waste Form Development for the Solidification of PDCF/MOX Liquid Waste Streams  

SciTech Connect

At the Savannah River Site, part of the Department of Energy's nuclear materials complex located in South Carolina, cementation has been selected as the solidification method for high-alpha and low-activity waste streams generated in the planned plutonium disposition facilities. A Waste Solidification Building (WSB) that will be used to treat and solidify three radioactive liquid waste streams generated by the Pit Disassembly and Conversion Facility) and the Mixed Oxide Fuel Fabrication Facility is in the preliminary design stage. The WSB is expected to treat a transuranic (TRU) waste stream composed primarily of americium and two low-level waste (LLW) streams. The acidic wastes will be concentrated in the WSB evaporator and neutralized in a cement head tank prior to solidification. A series of TRU mixes were prepared to produce waste forms exhibiting a range of processing and cured properties. The LLW mixes were prepared using the premix from the preferred TRU waste form. All of the waste forms tested passed the Toxicity Characteristic Leaching Procedure. After processing in the WSB, current plans are to dispose of the solidified TRU waste at the Waste Isolation Pilot Plant in New Mexico and the solidified LLW waste at an approved low-level waste disposal facility.

COZZI, ALEX

2004-02-18T23:59:59.000Z

140

Advanced Mixed Waste Treatment: Results of Mixed Waste Treatment at the M-4 Facility  

Science Conference Proceedings (OSTI)

Processing alternatives for commercial nuclear plant mixed wastes are limited. In order to expand potential treatment options, EPRI entered a collaborative research agreement to process mixed wastes at an environmental facility. This report documents the success of that effort to date.

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Plant for the treatment of waste  

SciTech Connect

A plant is described that is comprised of a post combustion chamber connected to the combustion chamber of a household rubbish incineration furnace whose hot gases it uses in order, by means of suitable berners to heat sewage sludges and industrial liquids and a circuit for the treatment of the smoke and residues coming from the post combustion. This circuit, which is held under vacuum by a blower, comprises a dry cooling tower employing semi-liquid sludges as cooling agent, an absorption tower employing a solution adapted to ombine the predominantly acid gases of the smoke, and a separating tower in which the liquids in suspension are removed. A recycle circuit for the solution and liquid separated and means of recovering metallic particles and compounds complete this plant.

Barkhuus, P.W.; Faldt, I.

1980-09-23T23:59:59.000Z

142

RETRIEVAL & TREATMENT OF HANFORD TANK WASTE  

SciTech Connect

The Hanford Tank Farms contain 53 million gal of radioactive waste accumulated during over 50 years of operations. The waste is stored in 177 single-shell and double-shell tanks in the Hanford 200 Areas. The single-shell tanks were put into operation from the early 1940s through the 1960s with wastes received from several generations of processing facilities for the recovery of plutonium and uranium, and from laboratories and other ancillary facilities. The overall hanford Tank Farm system represents one of the largest nuclear legacies in the world driving towards completion of retrieval and treatment in 2028 and the associated closure activity completion by 2035. Remote operations, significant radiation/contamination levels, limited access, and old facilities are just some of the challenges faced by retrieval and treatment systems. These systems also need to be able to successfully remove 99% or more of the waste, and support waste treatment, and tank closure. The Tank Farm retrieval program has ramped up dramatically in the past three years with design, fabrication, installation, testing, and operations ongoing on over 20 of the 149 single-shell tanks. A variety of technologies are currently being pursued to retrieve different waste types, applications, and to help establish a baseline for recovery/operational efficiencies. The paper/presentation describes the current status of retrieval system design, fabrication, installation, testing, readiness, and operations, including: (1) Saltcake removal progress in Tanks S-102, S-109, and S-112 using saltcake dissolution, modified sluicing, and high pressure water lancing techniques; (2) Sludge vacuum retrieval experience from Tanks C-201, C-202, C-203, and C-204; (3) Modified sluicing experience in Tank C-103; (4) Progress on design and installation of the mobile retrieval system for sludge in potentially leaking single-shell tanks, particularly Tank C-101; and (5) Ongoing installation of various systems in the next generation of tanks to be retrieved.

EACKER, J.A.; SPEARS, J.A.; STURGES, M.H.; MAUSS, B.M.

2006-01-20T23:59:59.000Z

143

Process for immobilizing radioactive boric acid liquid wastes  

DOE Patents (OSTI)

Disclosed is a method of immobilizing boric acid liquid wastes containing radionuclides by neutralizing the solution and evaporating the resulting precipitate to near dryness. The dry residue is then fused into a reduced volume, insoluble, inert, solid form containing substantially all the radionuclides.

Greenhalgh, W.O.

1984-05-10T23:59:59.000Z

144

Process for immobilizing radioactive boric acid liquid wastes  

DOE Patents (OSTI)

A method of immobilizing boric acid liquid wastes containing radionuclides by neutralizing the solution and evaporating the resulting precipitate to near dryness. The dry residue is then fused into a reduced volume, insoluble, inert, solid form containing substantially all the radionuclides.

Greenhalgh, Wilbur O. (Richland, WA)

1986-01-01T23:59:59.000Z

145

Biological treatment of hazardous aqueous wastes  

Science Conference Proceedings (OSTI)

Studies were conducted with a rotating biological conractor (RBC) to evaluate the treatability of leachates from the Stringfellow and New Lyme hazardous-waste sites. The leachates were transported from the waste sites to Cincinnati at the United States Environmental Protection Agency's Testing and Evaluation Facility. A series of batches were run with primary effluent from Cincinnati's Mill Creek Sewage Treatment Facility. The paper reports on the results from these experiments and the effectiveness of an RBC to adequately treat leachates from Superfund sites.

Opatken, E.J.; Howard, H.K.; Bond, J.J.

1987-06-01T23:59:59.000Z

146

Iraq liquid radioactive waste tanks maintenance and monitoring program plan.  

SciTech Connect

The purpose of this report is to develop a project management plan for maintaining and monitoring liquid radioactive waste tanks at Iraq's Al-Tuwaitha Nuclear Research Center. Based on information from several sources, the Al-Tuwaitha site has approximately 30 waste tanks that contain varying amounts of liquid or sludge radioactive waste. All of the tanks have been non-operational for over 20 years and most have limited characterization. The program plan embodied in this document provides guidance on conducting radiological surveys, posting radiation control areas and controlling access, performing tank hazard assessments to remove debris and gain access, and conducting routine tank inspections. This program plan provides general advice on how to sample and characterize tank contents, and how to prioritize tanks for soil sampling and borehole monitoring.

Dennis, Matthew L.; Cochran, John Russell; Sol Shamsaldin, Emad (Iraq Ministry of Science and Technology)

2011-10-01T23:59:59.000Z

147

WASTE TREATMENT TECHNOLOGY PROCESS DEVELOPMENT PLAN FOR HANFORD WASTE TREATMENT PLANT LOW ACTIVITY WASTE RECYCLE  

SciTech Connect

The purpose of this Process Development Plan is to summarize the objectives and plans for the technology development activities for an alternative path for disposition of the recycle stream that will be generated in the Hanford Waste Treatment Plant Low Activity Waste (LAW) vitrification facility (LAW Recycle). This plan covers the first phase of the development activities. The baseline plan for disposition of this stream is to recycle it to the WTP Pretreatment Facility, where it will be concentrated by evaporation and returned to the LAW vitrification facility. Because this stream contains components that are volatile at melter temperatures and are also problematic for the glass waste form, they accumulate in the Recycle stream, exacerbating their impact on the number of LAW glass containers. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and reducing the halides in the Recycle is a key component of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, this stream does not have a proven disposition path, and resolving this gap becomes vitally important. This task seeks to examine the impact of potential future disposition of this stream in the Hanford tank farms, and to develop a process that will remove radionuclides from this stream and allow its diversion to another disposition path, greatly decreasing the LAW vitrification mission duration and quantity of glass waste. The origin of this LAW Recycle stream will be from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover or precipitates of scrubbed components (e.g. carbonates). The soluble components are mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet, and will not be available until the WTP begins operation, causing uncertainty in its composition, particularly the radionuclide content. This plan will provide an estimate of the likely composition and the basis for it, assess likely treatment technologies, identify potential disposition paths, establish target treatment limits, and recommend the testing needed to show feasibility. Two primary disposition options are proposed for investigation, one is concentration for storage in the tank farms, and the other is treatment prior to disposition in the Effluent Treatment Facility. One of the radionuclides that is volatile and expected to be in high concentration in this LAW Recycle stream is Technetium-99 ({sup 99}Tc), a long-lived radionuclide with a half-life of 210,000 years. Technetium will not be removed from the aqueous waste in the Hanford Waste Treatment and Immobilization Plant (WTP), and will primarily end up immobilized in the LAW glass, which will be disposed in the Integrated Disposal Facility (IDF). Because {sup 99}Tc has a very long half-life and is highly mobile, it is the largest dose contributor to the Performance Assessment (PA) of the IDF. Other radionuclides that are also expected to be in appreciable concentration in the LAW Recycle are {sup 129}I, {sup 90}Sr, {sup 137}Cs, and {sup 241}Am. The concentrations of these radionuclides in this stream will be much lower than in the LAW, but they will still be higher than limits for some of the other disposition pathways currently available. Although the baseline process will recycle this stream to the Pretreatment Facility, if the LAW facility begins operation first, this stream will not have a disposition path internal to WTP. One potential solution is to return the stream to the tank farms where it can be evaporated in the 242- A evaporator, or perhaps deploy an auxiliary evaporator to concentrate it prior to return to the tank farms. In either case, testing is needed to evalua

McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.

2013-08-29T23:59:59.000Z

148

Use of Chemical Pretreatment to Enhance Liquid Waste of Processing  

Science Conference Proceedings (OSTI)

This report details unique chemical pretreatment and processing techniques presently used by utilities in their nuclear plant liquid radwaste treatment programs. It presents specific utility experience from a number of plants employing these processing alternatives.

1999-04-23T23:59:59.000Z

149

Waste Treatment and Immobilation Plant Pretreatment Facility  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7 7 Technology Readiness Assessment for the Waste Treatment and Immobilization Plant (WTP) Pretreatment Facility L. Holton D. Alexander M. Johnson H. Sutter August 2007 Prepared by the U.S. Department of Energy Office of River Protection Richland, Washington, 99352 07-DESIGN-047 Technology Readiness Assessment for the Waste Treatment and Immobilization Plant (WTP) Pretreatment Facilities L. Holton D. Alexander M. Johnson H. Sutter August 2007 Prepared by the U.S. Department of Energy Office of River Protection under Contract DE-AC05-76RL01830 07-DESIGN-047 iii Summary The U.S. Department of Energy (DOE), Office of River Protection (ORP) and the DOE Office of Environmental Management (EM), Office of Project Recovery has completed a Technology Readiness

150

Department of Energy Idaho - Advanced Mixed Waste Treatment Project...  

NLE Websites -- All DOE Office Websites (Extended Search)

> AMWTP Contract Idaho Treatment Group, LLC (ITG) Advanced Mixed Waste Treatment Project Contract Basic Contract Contract Modifications Documents Related to the AMWTP Contract Last...

151

Digestion of frozen/thawed food waste in the hybrid anaerobic solid-liquid system  

SciTech Connect

The hybrid anaerobic solid-liquid (HASL) system, which is a modified two-phase anaerobic digester, is to be used in an industrial scale operation to minimize disposal of food waste at incineration plants in Singapore. The aim of the present research was to evaluate freezing/thawing of food waste as a pre-treatment for its anaerobic digestion in the HASL system. The hydrolytic and fermentation processes in the acidogenic reactor were enhanced when food waste was frozen for 24 h at -20 deg. C and then thawed for 12 h at 25 deg. C (experiment) in comparison with fresh food waste (control). The highest dissolved COD concentrations in the leachate from the acidogenic reactors were 16.9 g/l on day 3 in the control and 18.9 g/l on day 1 in the experiment. The highest VFA concentrations in the leachate from the acidogenic reactors were 11.7 g/l on day 3 in the control and 17.0 g/l on day 1 in the experiment. The same volume of methane was produced during 12 days in the control and 7 days in the experiment. It gave the opportunity to diminish operational time of batch process by 42%. The effect of freezing/thawing of food waste as pre-treatment for its anaerobic digestion in the HASL system was comparable with that of thermal pre-treatment of food waste at 150 deg. C for 1 h. However, estimation of energy required either to heat the suspended food waste to 150 deg. C or to freeze the same quantity of food waste to -20 deg. C showed that freezing pre-treatment consumes about 3 times less energy than thermal pre-treatment.

Stabnikova, O. [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)], E-mail: costab@ntu.edu.sg; Liu, X.Y.; Wang, J.Y. [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

2008-07-01T23:59:59.000Z

152

Evaluation of interim and final waste forms for the newly generated liquid low-level waste flowsheet  

SciTech Connect

The purpose of this review is to evaluate the final forms that have been proposed for radioactive-containing solid wastes and to determine their application to the solid wastes that will result from the treatment of newly generated liquid low-level waste (NGLLLW) and Melton Valley Storage Tank (MVST) supernate at the Oak Ridge National Laboratory (ORNL). Since cesium and strontium are the predominant radionuclides in NGLLLW and MVST supernate, this review is focused on the stabilization and solidification of solid wastes containing these radionuclides in cement, glass, and polymeric materials-the principal waste forms that have been tested with these types of wastes. Several studies have shown that both cesium and strontium are leached by distilled water from solidified cement, although the leachabilities of cesium are generally higher than those of strontium under similar conditions. The situation is exacerbated by the presence of sulfates in the solution, as manifested by cracking of the grout. Additives such as bentonite, blast-furnace slag, fly ash, montmorillonite, pottery clay, silica, and zeolites generally decrease the cesium and strontium release rates. Longer cement curing times (>28 d) and high ionic strengths of the leachates, such as those that occur in seawater, also decrease the leach rates of these radionuclides. Lower cesium leach rates are observed from vitrified wastes than from grout waste forms. However, significant quantities of cesium are volatilized due to the elevated temperatures required to vitrify the waste. Hence, vitrification will generally require the use of cleanup systems for the off-gases to prevent their release into the atmosphere.

Abotsi, G.M.K. [Clark Atlanta Univ., GA (United States); Bostick, D.T.; Beck, D.E. [Oak Ridge National Lab., TN (United States)] [and others

1996-05-01T23:59:59.000Z

153

Treatment of biomass gasification wastewaters using liquid-liquid extraction  

DOE Green Energy (OSTI)

Pacific Northwest Laboratory (PNL) investigated liquid-liquid extraction as a treatment method for biomass gasification wastewaters (BGW). Distribution coefficients for chemical oxygen demand (COD) removal were determined for the following solvents: methylisobutyl ketone (MIBK), n-butyl acetate, n-butanol, MIBK/n-butyl acetate (50:50 vol), MIBK/n-butanol (50:50 vol), tri-butyl phosphate, tri-n-octyl phosphine oxide (TOPO)/MIBK (10:90 wt), TOPO/kerosene (10:90 wt), kerosene, and toluene. The best distribution coefficient of 1.3 was given by n-butanol. Chemical analysis of the wastewater by gas chromatography (GC) showed acetic acid and propionic acid concentrations of about 4000 mg/1. Methanol, ethanol, and acetone were identified in trace amounts. These five compounds accounted for 45% of the measured COD of 29,000 mg/1. Because of the presence of carboxylic acids, pH was expected to affect extraction of the wastewater. At low pH the acids should be in the acidic form, which increased extraction by MIBK. Extraction by n-butanol was increased at high pH, where the acids should be in the ionic form.

Bell, N.E.

1981-09-01T23:59:59.000Z

154

Hanford Tank Waste Retrieval, Treatment and Disposition Framework |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Tank Waste Retrieval, Treatment and Disposition Framework Hanford Tank Waste Retrieval, Treatment and Disposition Framework Hanford Tank Waste Retrieval, Treatment and Disposition Framework Completing the Office of River Protection (ORP) mission of stabilizing 56 million gallons of chemical and radioactive waste stored in Hanford's 177 tanks is one of the Energy Department's highest priorities. This Framework document outlines a phased approach for beginning tank waste treatment while continuing to resolve technical issues with the Pretreatment and High-Level Waste Facilities. Hanford Tank Waste Retrieval, Treatment and Disposition Framework More Documents & Publications EIS-0391: Draft Environmental Impact Statement Waste Treatment Plant and Tank Farm Program EIS-0356: Notice of Intent to Prepare an Environmental Impact Statement

155

Hanford Tank Waste Retrieval, Treatment and Disposition Framework |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Tank Waste Retrieval, Treatment and Disposition Framework Hanford Tank Waste Retrieval, Treatment and Disposition Framework Hanford Tank Waste Retrieval, Treatment and Disposition Framework Completing the Office of River Protection (ORP) mission of stabilizing 56 million gallons of chemical and radioactive waste stored in Hanford's 177 tanks is one of the Energy Department's highest priorities. This Framework document outlines a phased approach for beginning tank waste treatment while continuing to resolve technical issues with the Pretreatment and High-Level Waste Facilities. Hanford Tank Waste Retrieval, Treatment and Disposition Framework More Documents & Publications EIS-0391: Draft Environmental Impact Statement Waste Treatment Plant and Tank Farm Program EIS-0356: Notice of Intent to Prepare an Environmental Impact Statement

156

EVALUATION OF ULTIMATE DISPOSAL METHOD FOR LIQUID AND SOLID RADIOACTIVE WASTES. PART I. INTERIM LIQUID STORAGE  

SciTech Connect

As the first part of a study to evaluate the economics of the various steps leading to and including the permanent disposal of high-activity liquid and solid radioactive waste, costs of interim liquid storage of acid and alkaline Purex and Thorex wastes were estimated for storage times of 0.5 to 30 years. A 6- ton/day plant was assumed, processing 1500 tons/year of uranium converter fuel at a burnup of 10,000 Mwd/ton and 270 tons/year of thorium converter fuel at a burnup of 20,000 Mwd/ton. Tanks of Savannah River design were assumed, with stainless steel construction for acid wastes and mild steel construction for neutralized wastes. The operating cycle of each tank was assumed to consist of equal filling and emptying periods plus a full (or dead) period. With interim storage time defined as filling time plus full time, tank costs were minimum when full time was 40 to 70% of the interim storage time, using present worth considerations. For waste storage times of 0.5 to 30 years, costs ranged from 2.2 x 10/sup -3/ to 9.5 x 10/sup -3/ mill/kwh/sub e/ for acid wastes and from 1.7 x 10/sup -3/ to 5.1 x 10/sup -3/ mill/kwh/sub e/ for neutralized wastes. (auth)

Bradshaw, R.L.; Perona, J.J.; Roberts, J.T.; Blomeke, J.O.

1961-08-22T23:59:59.000Z

157

Report: Findings, Conclusions, and Recommendations Concerning the Waste Treatment and Immobilization Project at Hanford  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

EMAB Tank Waste Subcommittee Summary Report 1 EMAB Tank Waste Subcommittee Summary Report 1 Report of Findings, Conclusions, and Recommendations Concerning the Waste Treatment and Immobilization Project (WTP) at Hanford Submitted by the Environmental Management Advisory Board Tank Waste Subcommittee September 15, 2010 Introduction In May 2010, the Department of Energy established the Environmental Management Tank Waste Subcommittee (EM-TWS). The EM-TWS was charged with conducting an independent technical review of liquid waste capital and operations projects related to the Office of Environmental Management (EM) tank waste cleanup programs at Hanford, Washington; the Savannah River Site in South Carolina; the Idaho National Laboratory; and the West Valley Demonstration Project in New York. The EM-TWS's review focused on the facilities being

158

EIS-0287: Notice of Preferred Sodium Bearing Waste Treatment Technology |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Preferred Sodium Bearing Waste Treatment Preferred Sodium Bearing Waste Treatment Technology EIS-0287: Notice of Preferred Sodium Bearing Waste Treatment Technology Idaho High-Level Waste (HLW) and Facilities Disposition In October 2002, the U.S. Department of Energy (DOE or the Department) issued the Final Idaho High-Level Waste (HLW) and Facilities Disposition Environmental Impact Statement (DOE/EIS-0287 (Final EIS)). The Final EIS contains an evaluation of reasonable alternatives for the management of mixed transuranic waste/sodium bearing waste (SBW),1 mixed HLW calcine, and associated low-level waste (LLW), as well as disposition alternatives for HLW facilities when their missions are completed. DOE/EIS-0287, Notice of Preferred Sodium Bearing Waste Treatment Technology, Office of Environmental Management, Idaho, 70 FR 44598 (August

159

Independent Oversight Review, Sodium Bearing Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sodium Bearing Waste Treatment Sodium Bearing Waste Treatment Project - Contractor - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Contractor - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Contractor Operational Readiness Review This report documents the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), independent review of the Sodium Bearing Waste Treatment Project-Integrated Waste Treatment Unit (SBWTP-IWTU) contractor Operational Readiness Review (C-ORR). The review was conducted at the Idaho Site from February 27 to March 6, 2012. This report discusses the background, scope, results, and conclusions of the review, as well as

160

Independent Oversight Review, Sodium Bearing Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Sodium Bearing Waste Treatment Sodium Bearing Waste Treatment Project - Federal - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Federal - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Federal Operational Readiness Review This report documents the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), independent review of the Sodium Bearing Waste Treatment Project-Integrated Waste Treatment Unit (SBWTP-IWTU) DOE (Federal) Operational Readiness Review (D-ORR). The review was performed by the HSS Office of Safety and Emergency Management Evaluations and was intended to assess the effectiveness of the CORR process as implemented for

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161

Idaho's Advanced Mixed Waste Treatment Project Details 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Idaho's Advanced Mixed Waste Treatment Project Details 2013 Idaho's Advanced Mixed Waste Treatment Project Details 2013 Accomplishments Idaho's Advanced Mixed Waste Treatment Project Details 2013 Accomplishments December 24, 2013 - 12:00pm Addthis IDAHO FALLS, Idaho - EM and its contractor, Idaho Treatment Group (ITG), safely and compliantly met all of their production and shipping targets in the Advanced Mixed Waste Treatment Project (AMWTP) at the Idaho site in 2013. AMWTP's purpose is to safely process and dispose of transuranic (TRU) and mixed low-level waste (MLLW). The defense-related TRU waste is sent to the Waste Isolation Pilot Plant in New Mexico, and the MLLW is sent to other federal and commercial disposal sites. AMWTP is the largest shipper of contact-handled TRU waste to WIPP. In 2013, AMWTP sent 2,444.69 cubic

162

Idaho's Advanced Mixed Waste Treatment Project Details 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Idaho's Advanced Mixed Waste Treatment Project Details 2013 Idaho's Advanced Mixed Waste Treatment Project Details 2013 Accomplishments Idaho's Advanced Mixed Waste Treatment Project Details 2013 Accomplishments December 24, 2013 - 12:00pm Addthis IDAHO FALLS, Idaho - EM and its contractor, Idaho Treatment Group (ITG), safely and compliantly met all of their production and shipping targets in the Advanced Mixed Waste Treatment Project (AMWTP) at the Idaho site in 2013. AMWTP's purpose is to safely process and dispose of transuranic (TRU) and mixed low-level waste (MLLW). The defense-related TRU waste is sent to the Waste Isolation Pilot Plant in New Mexico, and the MLLW is sent to other federal and commercial disposal sites. AMWTP is the largest shipper of contact-handled TRU waste to WIPP. In 2013, AMWTP sent 2,444.69 cubic

163

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Treatment and Immobilization Treatment and Immobilization Plant - November 2011 Independent Oversight Review, Waste Treatment and Immobilization Plant - November 2011 November 2011 Review of the Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality The Office of Enforcement and Oversight (Independent Oversight) within the Office of Health, Safety and Security conducted an independent review of selected aspects of construction quality at the Hanford Waste Treatment and Immobilization Plant Project (WTP). The independent oversight review, which was performed September 12-15, 2011, was the latest in a series of ongoing quarterly assessments of construction quality at the WTP construction site. Independent Oversight Review, Waste Treatment and Immobilization Plant -

164

Pyrolysis/Steam Reforming Technology for Treatment of TRU Orphan Wastes  

SciTech Connect

Certain transuranic (TRU) waste streams within the Department of Energy (DOE) complex cannot be disposed of at the Waste Isolation Pilot Plant (WIPP) because they do not meet the shipping requirements of the TRUPACT-II or the disposal requirements of the Waste Analysis Plan (WAP) in the WIPP RCRA Part B Permit. These waste streams, referred to as orphan wastes, cannot be shipped or disposed of because they contain one or more prohibited items, such as liquids, volatile organic compounds (VOCs), hydrogen gas, corrosive acids or bases, reactive metals, or high concentrations of polychlorinated biphenyl (PCB), etc. The patented, non-incineration, pyrolysis and steam reforming processes marketed by THOR Treatment Technologies LLC removes all of these prohibited items from drums of TRU waste and produces a dry, inert, inorganic waste material that meets the existing TRUPACT-II requirements for shipping, as well as the existing WAP requirements for disposal of TRU waste at WIPP. THOR Treatment Technologies is a joint venture formed in June 2002 by Studsvik, Inc. (Studsvik) and Westinghouse Government Environmental Services Company LLC (WGES) to further develop and deploy Studsvik's patented THORSM technology within the DOE and Department of Defense (DoD) markets. The THORSM treatment process is a commercially proven system that has treated over 100,000 cu. ft. of nuclear waste from commercial power plants since 1999. Some of this waste has had contact dose rates of up to 400 R/hr. A distinguishing characteristic of the THORSM process for TRU waste treatment is the ability to treat drums of waste without removing the waste contents from the drum. This feature greatly minimizes criticality and contamination issues for processing of plutonium-containing wastes. The novel features described herein are protected by issued and pending patents.

Mason, J. B.; McKibbin, J.; Schmoker, D.; Bacala, P.

2003-02-27T23:59:59.000Z

165

Analysis of waste treatment requirements for DOE mixed wastes: Technical basis  

SciTech Connect

The risks and costs of managing DOE wastes are a direct function of the total quantities of 3wastes that are handled at each step of the management process. As part of the analysis of the management of DOE low-level mixed wastes (LLMW), a reference scheme has been developed for the treatment of these wastes to meet EPA criteria. The treatment analysis in a limited form was also applied to one option for treatment of transuranic wastes. The treatment requirements in all cases analyzed are based on a reference flowsheet which provides high level treatment trains for all LLMW. This report explains the background and basis for that treatment scheme. Reference waste stream chemical compositions and physical properties including densities were established for each stream in the data base. These compositions are used to define the expected behavior for wastes as they pass through the treatment train. Each EPA RCRA waste code was reviewed, the properties, chemical composition, or characteristics which are of importance to waste behavior in treatment were designated. Properties that dictate treatment requirements were then used to develop the treatment trains and identify the unit operations that would be included in these trains. A table was prepared showing a correlation of the waste physical matrix and the waste treatment requirements as a guide to the treatment analysis. The analysis of waste treatment loads is done by assigning wastes to treatment steps which would achieve RCRA compliant treatment. These correlation`s allow one to examine the treatment requirements in a condensed manner and to see that all wastes and contaminant sets are fully considered.

1995-02-01T23:59:59.000Z

166

Selection of liquid-level monitoring method for the Oak Ridge National Laboratory inactive liquid low-level waste tanks, remedial investigation/feasibility study  

SciTech Connect

Several of the inactive liquid low-level waste (LLLW) tanks at Oak Ridge National Laboratory contain residual wastes in liquid or solid (sludge) form or both. A plan of action has been developed to ensure that potential environmental impacts from the waste remaining in the inactive LLLW tank systems are minimized. This document describes the evaluation and selection of a methodology for monitoring the level of the liquid in inactive LLLW tanks. Criteria are established for comparison of existing level monitoring and leak testing methods; a preferred method is selected and a decision methodology for monitoring the level of the liquid in the tanks is presented for implementation. The methodology selected can be used to continuously monitor the tanks pending disposition of the wastes for treatment and disposal. Tanks that are empty, are scheduled to be emptied in the near future, or have liquid contents that are very low risk to the environment were not considered to be candidates for installing level monitoring. Tanks requiring new monitoring equipment were provided with conductivity probes; tanks with existing level monitoring instrumentation were not modified. The resulting data will be analyzed to determine inactive LLLW tank liquid level trends as a function of time.

Not Available

1994-11-01T23:59:59.000Z

167

Independent Oversight Activity Report, Hanford Waste Treatment and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Waste Treatment and Hanford Waste Treatment and Immobilization Plant - June 2013 Independent Oversight Activity Report, Hanford Waste Treatment and Immobilization Plant - June 2013 June 2013 Hanford Waste Treatment and Immobilization Plant Low Activity Waste Melter Off-gas Process System Hazards Analysis Activity Observation [HIAR-WTP-2013-05-13] This Independent Activity Report documents an oversight activity conducted by the Office of Health, Safety and Security's (HSS) Office of Safety and Emergency Management Evaluations from May 13 - June 28, 2013, at the Hanford Waste Treatment and Immobilization Plant (WTP). The activity consisted of HSS staff observing a limited portion of the start of the hazard analysis (HA) for WTP Low Activity Waste (LAW) Primary Off-gas System. The primary purpose of this HSS field activity was to observe and

168

Independent Oversight Activity Report, Hanford Waste Treatment and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Waste Treatment and Immobilization Plant - July 2013 Independent Oversight Activity Report, Hanford Waste Treatment and Immobilization Plant - July 2013 July 2013 Operational Awareness of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity [HIAR-WTP-2013-07-31] This Independent Activity Report documents an oversight activity conducted by the Office of Health, Safety and Security's (HSS) Office of Safety and Emergency Management Evaluations from July 31 - August 5, 2013, at the Hanford Waste Treatment and Immobilization Plant (WTP). The activity consisted of HSS staff observing a limited portion of the hazards analysis (HA) for WTP Low Activity Waste (LAW) Melter Process system. The primary purpose of this HSS field activity was to observe and

169

Independent Activity Report, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Immobilization Waste Treatment and Immobilization Plant - March 2013 Independent Activity Report, Waste Treatment and Immobilization Plant - March 2013 March 2013 Follow-up of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity Review [HIAR-WTP-2013-03-18] The Office of Health, Safety and Security (HSS) staff observed a limited portion of the restart of the Hazard Analysis (HA) for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter Process (LMP) System. The primary purpose of this HSS field activity, on March 18-21, 2013, was to observe and understand the revised approach implemented by Bechtel National, Inc. (BNI), the contractor responsible for the design and construction of WTP for the U.S. Department of Energy (DOE) Office of

170

Mixed and low-level waste treatment facility project. Volume 3, Waste treatment technologies (Draft)  

SciTech Connect

The technology information provided in this report is only the first step toward the identification and selection of process systems that may be recommended for a proposed mixed and low-level waste treatment facility. More specific information on each technology will be required to conduct the system and equipment tradeoff studies that will follow these preengineering studies. For example, capacity, maintainability, reliability, cost, applicability to specific waste streams, and technology availability must be further defined. This report does not currently contain all needed information; however, all major technologies considered to be potentially applicable to the treatment of mixed and low-level waste are identified and described herein. Future reports will seek to improve the depth of information on technologies.

1992-04-01T23:59:59.000Z

171

EVALUATION AND SELECTION OF 99TC GETTERS FOR SEQUESTRATION OF LIQUID SECONDARY WASTE RESULTING FROM VITRIFICATION OF RADIOACTIVE WASTE FROM HANFORD  

Science Conference Proceedings (OSTI)

Getters are most commonly inorganic materials that selectively adsorb radionuclide and metallic contaminants. Typically, these materials have been deployed in two different modes to immobilize and retard contaminant release from monolithic waste forms. One mode is to first use getters to selectively scavenge the radionuclide of interest from a liquid waste stream, and then incorporate the radionuclide-loaded getters in cementitious or other monolithic waste forms. The other mode consists of mixing getters and liquid waste together during formulation of monolithic waste forms. Desirable characteristics for a getter material include, (1) specific adsorption of radionuclide of interest and very high selectivity toward radionuclides of concern in concentrations that would be several orders of magnitude less than the concentrations of competing anions and cations, (2) adsorption capacity that should be sufficient for the mass and volume of the material that will be deployed to be within practicable limits, (3) long-term adsorption and retention of radionuclide, (4) sufficient physical and chemical stability that its radionuclide retention performance will not degrade significantly during the designed life span of the waste form, (5) chemical stability under the range of Eh, pH, and solution conditions that exist in the waste form environment, and (6) should not adversely affect chemical and physical integrity of waste forms. We conducted a literature review to identify getters that are suitable for effectively sequestering 99Tc in monolithic waste forms that are being evaluated for stabilizing secondary liquid waste streams resulting from treatment and vitrification of radioactive tank wastes at Hanford. As a result of this review, we identified a set of getters that warrant further evaluation for this specific application.

Mattigod, Shas V.; Westsik, Joseph H.

2011-03-31T23:59:59.000Z

172

An evaluation of neutralization for processing sodium-bearing liquid waste  

SciTech Connect

This report addresses an alternative concept for potentially managing the sodium-bearing liquid waste generated at the Idaho Chemical Processing Plant from the current method of calcining a blend of sodium waste and high-level liquid waste. The concept is based on removing the radioactive components from sodium-bearing waste by neutralization and grouting the resulting low-level waste for on-site near-surface disposal. Solidifying the sodium waste as a remote-handled transuranic waste is not considered to be practical because of excessive costs and inability to dispose of the waste in a timely fashion. Although neutralization can remove most radioactive components to provide feed for a solidified low-level waste, and can reduce liquid inventories four to nine years more rapidly than the current practice of blending sodium-bearing liquid waste with first-cycle raffinite, the alternative will require major new facilities and will generate large volumes of low-level waste. Additional facility and operating costs are estimated to be at least $500 million above the current practice of blending and calcining. On-site, low-level waste disposal may be technically difficult and conflict which national and state policies. Therefore, it is recommended that the current practice of calcining a blend of sodium-bearing liquid waste and high-level liquid waste be continued to minimize overall cost and process complexities. 17 refs., 4 figs., 16 tabs.

Chipman, N.A.; Engelgau, G.O.; Berreth, J.R.

1989-01-01T23:59:59.000Z

173

Mixed waste characterization, treatment, and disposal focus area. Technology summary  

Science Conference Proceedings (OSTI)

This paper presents details about the technology development programs of the Department of Energy. In this document, waste characterization, thermal treatment processes, non-thermal treatment processes, effluent monitors and controls, development of on-site innovative technologies, and DOE business opportunities are applied to environmental restoration. The focus areas for research are: contaminant plume containment and remediation; mixed waste characterization, treatment, and disposal; high-level waste tank remediation; landfill stabilization; and decontamination and decommissioning.

NONE

1995-06-01T23:59:59.000Z

174

Mixed and Low-Level Waste Treatment Facility project  

SciTech Connect

Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. The engineering studies, initiated in July 1991, identified 37 mixed waste streams, and 55 low-level waste streams. This report documents the waste stream information and potential treatment strategies, as well as the regulatory requirements for the Department of Energy-owned treatment facility option. The total report comprises three volumes and two appendices. This report consists of Volume 1, which explains the overall program mission, the guiding assumptions for the engineering studies, and summarizes the waste stream and regulatory information, and Volume 2, the Waste Stream Technical Summary which, encompasses the studies conducted to identify the INEL's waste streams and their potential treatment strategies.

1992-04-01T23:59:59.000Z

175

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

October 2012 October 2012 Independent Oversight Review, Waste Treatment and Immobilization Plant - October 2012 October 2012 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality The U. S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security, conducted an independent review of selected aspects of construction quality at the Hanford Site Waste Treatment and Immobilization Plant (WTP). The review, which was performed August 6-10, 2012, was the latest in a series of ongoing quarterly assessments of construction quality performed by Independent Oversight at the WTP construction site. Independent Oversight Review, Waste Treatment and Immobilization Plant -

176

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

March 2013 March 2013 Independent Oversight Review, Waste Treatment and Immobilization Plant - March 2013 March 2013 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security, conducted an independent review of selected aspects of construction quality at the Hanford Site Waste Treatment and Immobilization Plant (WTP). The review, which was performed November 26-30, 2012, was the latest in a series of ongoing quarterly assessments of construction quality performed by Independent Oversight at the WTP construction site. Independent Oversight Review, Waste Treatment and Immobilization Plant - March 2013

177

DOE intends to extend the Advanced Mixed Waste Treatment Project...  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE intends to extend the Advanced Mixed Waste Treatment Project contract for four months as competition for long-term contract continues. Scene from inside the Advanced Mixed...

178

Hanford ETR Tank Waste Treatment and Immobilization Plant - Hanford...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

(the percentage of actual operating time). 1 Comprehensive Review of the Hanford Waste Treatment Plant Flowsheet and Throughput Specifically, the following questions were...

179

Review of the Sodium Bearing Waste Treatment Project - Integrated...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

IWTU Integrated Waste Treatment Unit LCO Limiting Condition for Operation LSS Life Safety Systems MSA Management Self-Assessment OFI Opportunity for Improvement ORR Operational...

180

Review of the Sodium Bearing Waste Treatment Project - Integrated...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

IWTU Integrated Waste Treatment Unit LCO Limiting Condition for Operation LSS Life Safety Systems MSA Management Self-Assessment OFI Opportunity for Improvement OGC Off-Gas...

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Sodium Bearing Waste Treatment Project ? Countdown to Startup  

NLE Websites -- All DOE Office Websites (Extended Search)

Date: March 19, 2012 Media Contact: Natalie Packer, 208-533-0253 Sodium Bearing Waste Treatment Project Countdown to Startup Marking completion of another major...

182

REWAS 2008: Global Symposium on Recycling, Waste Treatment ...  

Science Conference Proceedings (OSTI)

Oct 20, 2008 ... REWAS 2008: Global Symposium on Recycling, Waste Treatment and ... on the Recovery of Materials and Energy for Resource Efficiency.

183

Advanced Mixed Waste Treatment Project Achieves Impressive Safety and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advanced Mixed Waste Treatment Project Achieves Impressive Safety Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks Advanced Mixed Waste Treatment Project Achieves Impressive Safety and Production Marks June 26, 2013 - 12:00pm Addthis Only the 620 employees at EM’s Advanced Mixed Waste Treatment Project earned the right to this vanity plate after working more than 14 million hours without a lost-time injury and safely and compliantly shipping more than 50,000 cubic meters of transuranic and mixed low-level radioactive waste for disposal. Only the 620 employees at EM's Advanced Mixed Waste Treatment Project earned the right to this vanity plate after working more than 14 million hours without a lost-time injury and safely and compliantly shipping more than 50,000 cubic meters of transuranic and mixed low-level radioactive

184

The Savannah River Site's liquid radioactive waste operations involves the man  

NLE Websites -- All DOE Office Websites (Extended Search)

Site's liquid radioactive waste operations involves the management of space in the Site's Site's liquid radioactive waste operations involves the management of space in the Site's 49 underground waste tanks, including the removal of waste materials. Once water is removed from the waste tanks, two materials remain: salt and sludge waste. Removing salt waste, which fills approximately 90 percent of the tank space in the SRS tank farms, is a major step toward closing the Site's waste tanks that currently contain approximately 38 million gallons of waste. Due to the limited amount of tank space available in new-style tanks, some salt waste must be dispositioned in the interim to ensure sufficient tank space for continued sludge washing and to support the initial start-up and salt processing operations at the Salt Waste Processing Facility (SWPF).

185

Liquid and Gaseous Waste Operations Department annual operating report, CY 1992  

SciTech Connect

A total of 6.05 x 10{sup 7} gal of liquid waste was decontaminated by the Process Waste Treatment Plant (PWTP) ion exchange system during CY 1992. This averaged to 115 gpm throughout the year. When necessary, a wastewater sidestream of 50--80 gpm was treated through the use of a natural zeolite treatment system. An additional 8.00 x 10{sup 6} gal (average of 15 gpm throughout the year) were treated by the zeolite system. Therefore, the average total flow treated at the PWTP for CY 1992 was 130 gpm. In mid-June, the zeolite system was repiped to allow it the capability to treat the ion exchange system`s discharge due to rising Cs problems in the wastewater. While being used to treat the ion exchange system`s discharge, it cannot treat a sidestream of wastewater. During the year, the regeneration of the cation exchange resins resulted in the generation of 7.83 x 10{sup 3} gal of liquid low-level waste (LLLW) concentrate and 1.15 x 10{sup 4} gal of LLLW evaporator feed. The head-end softening process (precipitation/clarification) generated 604 drums (4.40 x 10{sup 3} ft{sup 3}) of solid low-level waste sludge. The zeolite treatment system generated approximately 8.40 x 10{sup 2} ft{sup 3} of spent zeolite resin, which was turned over to the Solid Waste Operations Department for disposal. See Table 1 for a monthly summary of activities at the PWTP. Figures 1, 2, 3, and 4 show a comparison of operations at the PWTP in 1992 with previous years. Figure 5 shows a comparison of annual rainfall at Oak Ridge National Laboratory (ORNL) since 1987. A total of 1.55 x 10{sup 8} gal of liquid waste (average of 294 gpm throughout the year) was treated at the Nonradiological Wastewater Treatment Plant (NRWTP). Of this amount, 1.40 x 10{sup 7} gal were treated by the precipitation/clarification process for removal of heavy metals. Twenty-five boxes (1.60 x 10{sup 3} ft{sup 3}) of solid sludge generated by the precipitation/clarification process were removed from the filter press room.

Gillespie, M.A.; Maddox, J.J.; Scott, C.B.

1993-03-01T23:59:59.000Z

186

Treatment of halogen-containing waste and other waste materials  

DOE Patents (OSTI)

A process is described for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes. 3 figs.

Forsberg, C.W.; Beahm, E.C.; Parker, G.W.

1997-03-18T23:59:59.000Z

187

Treatment of halogen-containing waste and other waste materials  

DOE Patents (OSTI)

A process for treating a halogen-containing waste material. The process provides a bath of molten glass containing a sacrificial metal oxide capable of reacting with a halogen in the waste material. The sacrificial metal oxide is present in the molten glass in at least a stoichiometric amount with respect to the halogen in the waste material. The waste material is introduced into the bath of molten glass to cause a reaction between the halogen in the waste material and the sacrificial metal oxide to yield a metal halide. The metal halide is a gas at the temperature of the molten glass. The gaseous metal halide is separated from the molten glass and contacted with an aqueous scrubber solution of an alkali metal hydroxide to yield a metal hydroxide or metal oxide-containing precipitate and a soluble alkali metal halide. The precipitate is then separated from the aqueous scrubber solution. The molten glass containing the treated waste material is removed from the bath as a waste glass. The process of the invention can be used to treat all types of waste material including radioactive wastes. The process is particularly suited for separating halogens from halogen-containing wastes.

Forsberg, Charles W. (Oak Ridge, TN); Beahm, Edward C. (Oak Ridge, TN); Parker, George W. (Concord, TN)

1997-01-01T23:59:59.000Z

188

Hanford Site waste treatment/storage/disposal integration  

SciTech Connect

In 1998 Waste Management Federal Services of Hanford, Inc. began the integration of all low-level waste, mixed waste, and TRU waste-generating activities across the Hanford site. With seven contractors, dozens of generating units, and hundreds of waste streams, integration was necessary to provide acute waste forecasting and planning for future treatment activities. This integration effort provides disposition maps that account for waste from generation, through processing, treatment and final waste disposal. The integration effort covers generating facilities from the present through the life-cycle, including transition and deactivation. The effort is patterned after the very successful DOE Complex EM Integration effort. Although still in the preliminary stages, the comprehensive onsite integration effort has already reaped benefits. These include identifying significant waste streams that had not been forecast, identifying opportunities for consolidating activities and services to accelerate schedule or save money; and identifying waste streams which currently have no path forward in the planning baseline. Consolidation/integration of planned activities may also provide opportunities for pollution prevention and/or avoidance of secondary waste generation. A workshop was held to review the waste disposition maps, and to identify opportunities with potential cost or schedule savings. Another workshop may be held to follow up on some of the long-term integration opportunities. A change to the Hanford waste forecast data call would help to align the Solid Waste Forecast with the new disposition maps.

MCDONALD, K.M.

1999-02-24T23:59:59.000Z

189

Production of metal waste forms from spent fuel treatment  

Science Conference Proceedings (OSTI)

Treatment of spent nuclear fuel at Argonne National Laboratory consists of a pyroprocessing scheme in which the development of suitable waste forms is being advanced. Of the two waste forms being proposed, metal and mineral, the production of the metal waste form utilizes induction melting to stabilize the waste product. Alloying of metallic nuclear materials by induction melting has long been an Argonne strength and thus, the transition to metallic waste processing seems compatible. A test program is being initiated to coalesce the production of the metal waste forms with current induction melting capabilities.

Westphal, B.R.; Keiser, D.D.; Rigg, R.H.; Laug, D.V.

1995-02-01T23:59:59.000Z

190

Final Hanford Offsite Waste Shipment Leaves Idaho Treatment Facility |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Final Hanford Offsite Waste Shipment Leaves Idaho Treatment Final Hanford Offsite Waste Shipment Leaves Idaho Treatment Facility Final Hanford Offsite Waste Shipment Leaves Idaho Treatment Facility August 18, 2011 - 12:00pm Addthis Idaho State Patrol Troopers Rick Stouse and Tony Anderson inspected the TRUPACTS, containers which contain TRU waste, and trailer containing the final shipment of Hanford offsite waste. The Idaho State Patrol officers have played an important role in AMWTP's success by inspecting every one of AMWTP's nearly 3,900 shipments. Idaho State Patrol Troopers Rick Stouse and Tony Anderson inspected the TRUPACTS, containers which contain TRU waste, and trailer containing the final shipment of Hanford offsite waste. The Idaho State Patrol officers have played an important role in AMWTP's success by inspecting every one of

191

Metal decontamination for waste minimization using liquid metal refining technology  

Science Conference Proceedings (OSTI)

The current Department of Energy Mixed Waste Treatment Project flowsheet indicates that no conventional technology, other than surface decontamination, exists for metal processing. Current Department of Energy guidelines require retrievable storage of all metallic wastes containing transuranic elements above a certain concentration. This project is in support of the National Mixed Low Level Waste Treatment Program. Because of the high cost of disposal, it is important to develop an effective decontamination and volume reduction method for low-level contaminated metals. It is important to be able to decontaminate complex shapes where surfaces are hidden or inaccessible to surface decontamination processes and destruction of organic contamination. These goals can be achieved by adapting commercial metal refining processes to handle radioactive and organic contaminated metal. The radioactive components are concentrated in the slag, which is subsequently vitrified; hazardous organics are destroyed by the intense heat of the bath. The metal, after having been melted and purified, could be recycled for use within the DOE complex. In this project, we evaluated current state-of-the-art technologies for metal refining, with special reference to the removal of radioactive contaminants and the destruction of hazardous organics. This evaluation was based on literature reports, industrial experience, plant visits, thermodynamic calculations, and engineering aspects of the various processes. The key issues addressed included radioactive partitioning between the metal and slag phases, minimization of secondary wastes, operability of the process subject to widely varying feed chemistry, and the ability to seal the candidate process to prevent the release of hazardous species.

Joyce, E.L. Jr.; Lally, B. [Los Alamos National Lab., NM (United States); Ozturk, B.; Fruehan, R.J. [Carnegie-Mellon Univ., Pittsburgh, PA (United States). Dept. of Materials Science and Engineering

1993-09-01T23:59:59.000Z

192

Summary - Flowsheet for the Hanford Waste Treatment Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment Plant Waste Treatment Plant ETR Report Date: March 2006 ETR-1 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the Flowsheet for the Hanford Waste Treatment Plant (WTP) Why DOE-EM Did This Review The Hanford Waste Treatment and Immobilization Plant (WTP) is being constructed to treat the 53 million gallons of radioactive waste, separate it into high- and low-activity fractions, and produce canisters of high-level (HLW) glass (left) and containers of low-activity waste (LAW) glass (right). At the time of this review, the Plant was at approximately 70% design and 30% construction completion. The external review objective was to determine how well the WTP would meet its throughput capacities based on the current design,

193

Method for aqueous radioactive waste treatment  

DOE Patents (OSTI)

Plutonium, strontium, and cesium found in aqueous waste solutions resulting from nuclear fuel processing are removed by contacting the waste solutions with synthetic zeolite incorporating up to about 5 wt % titanium as sodium titanate in an ion exchange system. More than 99.9% of the plutonium, strontium, and cesium are removed from the waste solutions. 3 figures.

Bray, L.A.; Burger, L.L.

1994-03-29T23:59:59.000Z

194

Method for aqueous radioactive waste treatment  

DOE Patents (OSTI)

Plutonium, strontium, and cesium found in aqueous waste solutions resulting from nuclear fuel processing are removed by contacting the waste solutions with synthetic zeolite incorporating up to about 5 wt % titanium as sodium titanate in an ion exchange system. More than 99.9% of the plutonium, strontium, and cesium are removed from the waste solutions.

Bray, Lane A. (Richland, WA); Burger, Leland L. (Richland, WA)

1994-01-01T23:59:59.000Z

195

Independent Oversight Review, Hanford Waste Treatment and Immobilization  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Waste Treatment and Immobilization Plant - December 2013 Independent Oversight Review, Hanford Waste Treatment and Immobilization Plant - December 2013 December 2013 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality This report documents the results of an independent oversight review of selected aspects of construction quality at the Hanford Site Waste Treatment and Immobilization Plant (WTP). The review, which was performed September 9-13, 2013, was the latest in a series of ongoing quarterly assessments of construction quality performed by the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS). The scope of this quarterly assessment of construction quality review included observations

196

Independent Oversight Review, Advanced Mixed Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Review, Advanced Mixed Waste Treatment Review, Advanced Mixed Waste Treatment Project - April 2013 Independent Oversight Review, Advanced Mixed Waste Treatment Project - April 2013 April 2013 Review of Radiation Protection Program Implementation at the Advanced Mixed Waste Treatment Project of the Idaho Site This report documents an independent review of activity-level radiation protection program (RPP) implementation at the Advanced Mixed Waste Treatment Project (AMWTP) of the Idaho Site, as conducted by the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight) within the Office of Health, Safety and Security (HSS). The review was performed by the HSS Office of Safety and Emergency Management Evaluations. The purpose of this Independent Oversight targeted review

197

Independent Oversight Review, Waste Treatment and Immobilization Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Immobilization Waste Treatment and Immobilization Plant Project - October 2010 Independent Oversight Review, Waste Treatment and Immobilization Plant Project - October 2010 October 2010 Review of Nuclear Safety Culture at the Hanford Site Waste Treatment and Immobilization Plant Project The U.S. Department of Energy (DOE) Office of Health, Safety and Security (HSS) conducted an independent review of the nuclear safety culture at the Waste Treatment and Immobilization Plant (WTP) project at the Hanford Site during August and September 2010. The HSS team performed the review in response to a request in a July 30, 2010, memorandum from the Assistant Secretary for the DOE Headquarters Office of Environmental Management (EM), which referred to nuclear safety concerns raised by a contractor employee

198

Independent Oversight Review, Hanford Site Waste Treatment and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Waste Treatment and Immobilization Plant, August 2013 Independent Oversight Review, Hanford Site Waste Treatment and Immobilization Plant, August 2013 August 2013 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight) within the Office of Health, Safety and Security (HSS) conducted an independent review of selected aspects of construction quality at the Hanford Site Waste Treatment and Immobilization Plant (WTP). The review, which was performed June 10-14, 2013, was the latest in a series of ongoing quarterly assessments of construction quality performed by Independent Oversight at the WTP construction site. The scope of this quarterly assessment of construction quality review

199

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Immobilization Waste Treatment and Immobilization Plant - August 2012 Independent Oversight Review, Waste Treatment and Immobilization Plant - August 2012 August 2012 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality The U. S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security, conducted independent reviews of selected aspects of construction quality at the Hanford Site Waste Treatment and Immobilization Project (WTP). The reviews for this report were performed on site during February 6-10, 2012 and April 30 - May 4, 2012, and were the latest in a series of ongoing quarterly assessments of construction quality performed by Independent Oversight at the WTP.

200

Independent Oversight Review, Sodium Bearing Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Federal - June 2012 Federal - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Federal - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Federal Operational Readiness Review This report documents the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), independent review of the Sodium Bearing Waste Treatment Project-Integrated Waste Treatment Unit (SBWTP-IWTU) DOE (Federal) Operational Readiness Review (D-ORR). The review was performed by the HSS Office of Safety and Emergency Management Evaluations and was intended to assess the effectiveness of the CORR process as implemented for the SBWTP-IWTU. This review also provides additional data regarding

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oversight Review, Waste Treatment and Immobilization Oversight Review, Waste Treatment and Immobilization Plant - August 2011 Independent Oversight Review, Waste Treatment and Immobilization Plant - August 2011 August 2011 Hanford Waste Treatment and Immobilization Plant Construction Quality The Office of Safety and Emergency Management Evaluations (Independent Oversight) within the Office of Health, Safety and Security (HSS) conducted an independent review of selected aspects of construction quality at the Hanford Waste Treatment and Immobilization Project (WTP). The review, which was performed May 9-12, 2011, was the latest in a series of ongoing quarterly assessments of construction quality performed by Independent Oversight at the WTP construction site. HSS determined that construction quality at WTP was adequate in the areas

202

Independent Oversight Review, Advanced Mixed Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advanced Mixed Waste Treatment Advanced Mixed Waste Treatment Project - April 2013 Independent Oversight Review, Advanced Mixed Waste Treatment Project - April 2013 April 2013 Review of Radiation Protection Program Implementation at the Advanced Mixed Waste Treatment Project of the Idaho Site This report documents an independent review of activity-level radiation protection program (RPP) implementation at the Advanced Mixed Waste Treatment Project (AMWTP) of the Idaho Site, as conducted by the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight) within the Office of Health, Safety and Security (HSS). The review was performed by the HSS Office of Safety and Emergency Management Evaluations. The purpose of this Independent Oversight targeted review

203

300 Area waste acid treatment system closure plan  

SciTech Connect

The Hanford Facility Dangerous Waste Permit Application is considered to be a single application organized into a General Information Portion (document number DOERL-91-28) and a Unit-Specific Portion. The scope of the Unit-Specific Portion includes closure plan documentation submitted for individual, treatment, storage, and/or disposal units undergoing closure, such as the 300 Area Waste Acid Treatment System. Documentation contained in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units (e.g., the glossary provided in the General Information Portion). Whenever appropriate, 300 Area Waste Acid Treatment System documentation makes cross-reference to the General Information Portion, rather than duplicating text. This 300 Area Waste Acid Treatment System Closure Plan (Revision 2) includes a Hanford Facility Dangerous Waste Permit Application, Part A, Form 3. Information provided in this closure plan is current as of April 1999.

LUKE, S.N.

1999-05-17T23:59:59.000Z

204

Independent Oversight Review, Sodium Bearing Waste Treatment Project -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Contractor - June 2012 Contractor - June 2012 Independent Oversight Review, Sodium Bearing Waste Treatment Project - Contractor - June 2012 June 2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Contractor Operational Readiness Review This report documents the U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), independent review of the Sodium Bearing Waste Treatment Project-Integrated Waste Treatment Unit (SBWTP-IWTU) contractor Operational Readiness Review (C-ORR). The review was conducted at the Idaho Site from February 27 to March 6, 2012. This report discusses the background, scope, results, and conclusions of the review, as well as opportunities for improvement (OFIs) and items identified for further

205

Independent Oversight Assessment, Waste Treatment and Immobilization Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Waste Treatment and Immobilization Plant - January 2012 Independent Oversight Assessment, Waste Treatment and Immobilization Plant - January 2012 January 2012 Assessment of the Nuclear Safety Culture and Management of Nuclear Safety Concerns at the Hanford Site Waste Treatment and Immobilization Plant The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted an independent assessment at the DOE Waste Treatment and Immobilization Plant (WTP) to evaluate the current status of the nuclear safety culture and the effectiveness of DOE and contractor management in addressing nuclear safety concerns at WTP. This assessment provides DOE management with a follow-up on the October 2010 HSS review of the WTP

206

Feasibility of using biological degradation for the on-site treatment of mixed wastes  

E-Print Network (OSTI)

2002. EPA’s Radiation Protection Program: Mixed Waste.http://www.epa.gov/radiation/mixed-waste/.ON-SITE TREATMENT OF MIXED WASTES William T. Stringfellow (

Stringfellow, William T.; Komada, Tatsuyuki; Chang, Li-Yang

2004-01-01T23:59:59.000Z

207

Idaho waste treatment facility startup testing suspended to evaluate system  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

waste treatment facility startup testing suspended to waste treatment facility startup testing suspended to evaluate system response Idaho waste treatment facility startup testing suspended to evaluate system response June 20, 2012 - 12:00pm Addthis Media Contacts Brad Bugger 208-526-0833 Danielle Miller 208-526-5709 IDAHO FALLS, ID- On Saturday, June 16, startup testing was suspended at the Integrated Waste Treatment Unit (IWTU) located at the U.S. Department of Energy's Idaho Site. Testing and plant heat-up was suspended to allow detailed evaluation of a system pressure event observed during testing on Saturday. Facility startup testing has been ongoing for the past month, evaluating system and component operation and response during operating conditions. No radioactive or hazardous waste has been introduced into the facility,

208

Independent Activity Report, Office of River Protection Waste Treatment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office of River Protection Waste Office of River Protection Waste Treatment Plant and Tank Farms - February 2013 Independent Activity Report, Office of River Protection Waste Treatment Plant and Tank Farms - February 2013 February 2013 Site Familiarization and Introduction of New Office of Safety and Emergency Management Evaluations Site Lead for the Office of River Protection Waste Treatment Plant and Tank Farms [HIAR-HANFORD-2013-02-25] The Office of Health, Safety and Security's (HSS) Office of Safety and Emergency Management Evaluations (HS-45) assigned a new Site Lead to provide continuous oversight of activities at the Office of River Protection (ORP) Waste Treatment Plant (WTP) and tank farms. To gain familiarity with the site programs and personnel, the new Site Lead made two trips to the site, which included tours of the WTP construction site

209

Waste-Lithium-Liquid (WLL) Flow Battery for Stationary Energy Storage Applications Youngsik Kim* and Nina MahootcheianAsl  

E-Print Network (OSTI)

Waste-Lithium-Liquid (WLL) Flow Battery for Stationary Energy Storage Applications Youngsik Kim in a Waste-Lithium-Liquid (WLL) flow battery that can be used in a stationary energy storage application. Li

Zhou, Yaoqi

210

Nuclear waste treatment program: Annual report for FY 1987  

SciTech Connect

Two of the US Department of Energy's (DOE) nuclear waste management-related goals are to ensure that waste management is not an obstacle to the further development of light-water reactors and the closure of the nuclear fuel cycle and to fulfill its institutional responsibility for providing safe storage and disposal of existing and future nuclear wastes. As part of its approach to achieving these goals, the Office of Remedial Action and Waste Technology of DOE established what is now called the Nuclear Waste Treatment Program (NWTP) at the Pacific Northwest Laboratory during the second half of FY 1982. To support DOE's attainment of its goals, the NWTP is to provide technology necessary for the design and operation of nuclear waste treatment facilities by commercial enterprises as part of a licensed waste management system and problem-specific treatment approaches, waste form and treatment process adaptations, equipment designs, and trouble-shooting assistance, as required to treat existing wastes. This annual report describes progress during FY 1987 towards meeting these two objectives. 24 refs., 59 figs., 24 tabs.

Brouns, R.A.; Powell, J.A. (comps.)

1988-09-01T23:59:59.000Z

211

Independent Oversight Activity Report, Hanford Waste Treatment and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

October 2013 October 2013 Independent Oversight Activity Report, Hanford Waste Treatment and Immobilization Plant - October 2013 October 2013 Observation of Waste Treatment and Immobilization Plant Low Activity Waste Melter and Melter Off-gas Process System Hazards Analysis Activities [HIAR-WTP-2013-10-21] This Independent Activity Report documents an oversight activity conducted by the Office of Health, Safety and Security's (HSS) Office of Safety and Emergency Management Evaluations from October 21-31, 2013, at the Hanford Waste Treatment and Immobilization Plant (WTP). The activity consisted of HSS staff reviewing the Insight software hazard evaluation (HE) tables for hazard analysis (HA) generated to date for the WTP Low Activity Waste (LAW) Melter and Off-gas systems, observed a limited portion of the HA for the

212

Mixed Waste Storage and Treatment: Regulatory Compliance Manual  

Science Conference Proceedings (OSTI)

The management and storage of mixed wastes represents one of the most challenging regulatory issues currently facing NRC licensees. This report provides instructions and guidance regarding the on-site storage and treatment of mixed waste in compliance with Resource Conservation and Recovery Act (RCRA) requirements.

1994-12-31T23:59:59.000Z

213

Hanford Waste Treatment Plant Support Task Order Modified | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment Plant Support Task Order Modified Waste Treatment Plant Support Task Order Modified Hanford Waste Treatment Plant Support Task Order Modified March 11, 2013 - 12:00pm Addthis Media Contact Lynette Chafin, 513-246-0461 Lynette.Chafin@emcbc.doe.gov Cincinnati - The Department of Energy (DOE) today awarded a modification to a task order to Aspen Resources Limited, Inc. of Boulder, Colorado for support of the Waste Treatment and Immobilization Plant (WTP) at the Hanford Site. The modification increased the value of the task order to $1.6 million from $833,499. The task order modification has a one-year performance period and two one-year option periods. The Task Order was awarded under an Indefinite Delivery/Indefinite Quantity (ID/IQ) master Contract. Aspen Resources Limited, Inc. is a small-disadvantaged business under the Small Business Administration's

214

300 Area waste acid treatment system closure plan. Revision 1  

SciTech Connect

This section provides a description of the Hanford Site, identifies the proposed method of 300 Area Waste Acid Treatment System (WATS) closure, and briefly summarizes the contents of each chapter of this plan.

NONE

1996-03-01T23:59:59.000Z

215

DOE Chooses Idaho Treatment Group, LLC to Disposition Waste at...  

NLE Websites -- All DOE Office Websites (Extended Search)

doe logo Media Contact: Brad Bugger (208) 526-0833 For Immediate Release: Friday, May 27, 2011 DOE Chooses Idaho Treatment Group, LLC to Disposition Waste at the Advanced Mixed...

216

Office of River Protection Waste Treatment and Immobilizatin...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and Review of the Office of River Protection Waste Treatment and Immobilization Project Construction Site, November 16-18, 2010 The U.S. Department of Energy Office of...

217

Summary - System Planning for Low-Activity Waste Treatment at...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

(DOE-EM) External Technical Review of System Planning for Low-Activity Waste Treatment at Hanford Why DOE-EM Did This Review Construction of the facilities of the Hanford site's...

218

Microsoft Word - FINAL 7-12-10 Site Visit Report - LANL Radioactive Liquid Waste Facility FCA.docx  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Site Visit Report Facility Centered Assessment of the Los Alamos National Laboratory Radioactive Liquid Waste Treatment Facility - June 2010 This site visit report documents the results of the Office of Health, Safety and Security's (HSS) review of the Facility Centered Assessment (FCA) of the Los Alamos National Laboratory (LANL) Radioactive Liquid Waste Treatment Facility (RLW). This review, conducted June 9-25, 2010, was sponsored by the U.S. Department of Energy (DOE) Los Alamos Site Office (LASO) and LANL, and conducted jointly by HSS, LASO, and LANL staff. The Office of Environment, Safety and Health Evaluations was the overall lead organization for evaluation of the FCA process with the participation of the LASO Facility Representative assigned to RLW.

219

Waste Treatment Plant and Tank Farm Program  

Energy.gov (U.S. Department of Energy (DOE))

This photo shows the Pretreatment Facility control room building pad at the Office of River Protection at the Hanford site. The Low-Activity Waste Facility is in the background.

220

Treatment of Mixed Incinerable Waste, IG-0588  

Energy.gov (U.S. Department of Energy (DOE))

We found the Department of Energy (Department) was not treating its mixed incinerable solid waste expeditiously or cost-effectively. Specifically, the Department: • Did not fully utilize the Toxic...

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Idaho Waste Treatment Facility Improves Worker Safety and Efficiency, Saves  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment Facility Improves Worker Safety and Waste Treatment Facility Improves Worker Safety and Efficiency, Saves Taxpayer Dollars Idaho Waste Treatment Facility Improves Worker Safety and Efficiency, Saves Taxpayer Dollars August 27, 2013 - 12:00pm Addthis The box retrieval forklift carriage is used to lift a degraded box as retrieval personnel monitor progress. The box retrieval forklift carriage is used to lift a degraded box as retrieval personnel monitor progress. The new soft-sided overpack is placed for shipment for treatment and repackaging. The new soft-sided overpack is placed for shipment for treatment and repackaging. The box retrieval forklift carriage is used to lift a degraded box as retrieval personnel monitor progress. The new soft-sided overpack is placed for shipment for treatment and repackaging.

222

Biological treatment of concentrated hazardous, toxic, and radionuclide mixed wastes without dilution  

E-Print Network (OSTI)

Report. DOE/MWIP-26. Mixed Waste Integrated Program, U. S.Trial burn activities for a mixed waste incinerator. WasteBiological Treatment of Mixed Wastes Containing Acetonitrile

Stringfellow, William T.; Komada, Tatsuyuki; Chang, Li-Yang

2004-01-01T23:59:59.000Z

223

ONE SYSTEM INTEGRATED PROJECT TEAM: RETRIEVAL AND DELIVERY OF THE HANFORD TANK WASTES FOR VITRIFICATION IN THE WASTE TREATMENT PLANT  

SciTech Connect

The One System Integrated Project Team (IPT) was formed in late 2011 as a way for improving the efficiency of delivery and treatment of highly radioactive waste stored in underground tanks at the U.S. Department of Energy's (DOE's) 586-square-mile Hanford Site in southeastern Washington State. The purpose of the One System IPT is to improve coordination and integration between the Hanford's Waste Treatment Plant (WTP) contractor and the Tank Operations Contractor (TOC). The vision statement is: One System is a WTP and TOC safety conscious team that, through integrated management and implementation of risk-informed decision and mission-based solutions, will enable the earliest start of safe and efficient treatment of Hanford's tank waste, to protect the Columbia River, environment and public. The IPT is a formal collaboration between Bechtel National, Inc. (BNI), which manages design and construction of the WTP for the U.S. Department of Energy's Office of River Protection (DOEORP), and Washington River Protection Solutions (WRPS), which manages the TOC for ORP. More than fifty-six (56) million gallons of highly radioactive liquid waste are stored in one hundred seventy-seven (177) aging, underground tanks. Most of Hanford's waste tanks - one hundred forty-nine (149) of them - are of an old single-shell tank (SST) design built between 1944 and 1964. More than sixty (60) of these tanks have leaked in the past, releasing an estimated one million gallons of waste into the soil and threatening the nearby Columbia River. There are another twenty-eight (28) new double-shelled tanks (DSTs), built from 1968 to 1986, that provide greater protection to the environment. In 1989, DOE, the U.S. Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology) signed a landmark agreement that required Hanford to comply with federal and state environmental standards. It also paved the way for agreements that set deadlines for retrieving the tank wastes and for building and operating the WTP. The tank wastes are the result of Hanford's nearly fifty (50) years of plutonium production. In the intervening years, waste characteristics have been increasingly better understood. However, waste characteristics that are uncertain and will remain as such represent a significant technical challenge in terms of retrieval, transport, and treatment, as well as for design and construction ofWTP. What also is clear is that the longer the waste remains in the tanks, the greater the risk to the environment and the people of the Pacific Northwest. The goal of both projects - tank operations and waste treatment - is to diminish the risks posed by the waste in the tanks at the earliest possible date. About two hundred (200) WTP and TOC employees comprise the IPT. Individual work groups within One System include Technical, Project Integration & Controls, Front-End Design & Project Definition, Commissioning, Nuclear Safety & Engineering Systems Integration, and Environmental Safety and Health and Quality Assurance (ESH&QA). Additional functions and team members will be added as the WTP approaches the operational phase. The team has undertaken several initiatives since its formation to collaborate on issues: (1) alternate scenarios for delivery of wastes from the tank farms to WTP; (2) improvements in managing Interface Control Documents; (3) coordination on various technical issues, including the Defense Nuclear Facilities Nuclear Safety Board's Recommendation 2010-2; (4) deployment of the SmartPlant® Foundation-Configuration Management System; and (5) preparation of the joint contract deliverable of the Operational Readiness Support Plan.

HARP BJ; KACICH RM; SKWAREK RJ

2012-12-20T23:59:59.000Z

224

One System Integrated Project Team: Retrieval And Delivery Of The Hanford Tank Wastes For Vitrification In The Waste Treatment Plant  

Science Conference Proceedings (OSTI)

The One System Integrated Project Team (IPT) was formed in late 2011 as a way for improving the efficiency of delivery and treatment of highly radioactive waste stored in underground tanks at the U.S. Department of Energy's (DOE's) 586-square-mile Hanford Site in southeastern Washington State. The purpose of the One System IPT is to improve coordination and integration between the Hanford's Waste Treatment Plant (WTP) contractor and the Tank Operations Contractor (TOC). The vision statement is: One System is a WTP and TOC safety conscious team that, through integrated management and implementation of risk-informed decision and mission-based solutions, will enable the earliest start of safe and efficient treatment of Hanford's tank waste, to protect the Columbia River, environment and public. The IPT is a formal collaboration between Bechtel National, Inc. (BNI), which manages design and construction of the WTP for the U.S. Department of Energy's Office of River Protection (DOEORP), and Washington River Protection Solutions (WRPS), which manages the TOC for ORP. More than fifty-six (56) million gallons of highly radioactive liquid waste are stored in one hundred seventy-seven (177) aging, underground tanks. Most of Hanford's waste tanks - one hundred forty-nine (149) of them - are of an old single-shell tank (SST) design built between 1944 and 1964. More than sixty (60) of these tanks have leaked in the past, releasing an estimated one million gallons of waste into the soil and threatening the nearby Columbia River. There are another twenty-eight (28) new double-shelled tanks (DSTs), built from 1968 to 1986, that provide greater protection to the environment. In 1989, DOE, the U.S. Environmental Protection Agency (EPA), and the Washington State Department of Ecology (Ecology) signed a landmark agreement that required Hanford to comply with federal and state environmental standards. It also paved the way for agreements that set deadlines for retrieving the tank wastes and for building and operating the WTP. The tank wastes are the result of Hanford's nearly fifty (50) years of plutonium production. In the intervening years, waste characteristics have been increasingly better understood. However, waste characteristics that are uncertain and will remain as such represent a significant technical challenge in terms of retrieval, transport, and treatment, as well as for design and construction ofWTP. What also is clear is that the longer the waste remains in the tanks, the greater the risk to the environment and the people of the Pacific Northwest. The goal of both projects - tank operations and waste treatment - is to diminish the risks posed by the waste in the tanks at the earliest possible date. About two hundred (200) WTP and TOC employees comprise the IPT. Individual work groups within One System include Technical, Project Integration & Controls, Front-End Design & Project Definition, Commissioning, Nuclear Safety & Engineering Systems Integration, and Environmental Safety and Health and Quality Assurance (ESH&QA). Additional functions and team members will be added as the WTP approaches the operational phase. The team has undertaken several initiatives since its formation to collaborate on issues: (1) alternate scenarios for delivery of wastes from the tank farms to WTP; (2) improvements in managing Interface Control Documents; (3) coordination on various technical issues, including the Defense Nuclear Facilities Nuclear Safety Board's Recommendation 2010-2; (4) deployment of the SmartPlant? Foundation-configuration Management System; and (5) preparation of the joint contract deliverable of the Operational Readiness Support Plan.

Harp, Benton J. [Department of Energy, Office of River Protection, Richland, Washington (United States); Kacich, Richard M. [Bechtel National, Inc., Richland, WA (United States); Skwarek, Raymond J. [Washington River Protection Solutions LLC, Richland, WA (United States)

2012-12-20T23:59:59.000Z

225

Waste Treatment Facility Saves Taxpayers Nearly $20 Million | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment Facility Saves Taxpayers Nearly $20 Million Waste Treatment Facility Saves Taxpayers Nearly $20 Million Waste Treatment Facility Saves Taxpayers Nearly $20 Million December 11, 2012 - 1:40pm Addthis A new enclosure for processing radioactive casks has put Oak Ridge on a path to finishing cleanup work two years ahead of schedule, saving nearly $20 million. | Photo courtesy of the Office of Environmental Management. A new enclosure for processing radioactive casks has put Oak Ridge on a path to finishing cleanup work two years ahead of schedule, saving nearly $20 million. | Photo courtesy of the Office of Environmental Management. Erin Szulman Erin Szulman Special Assistant, Office of Environmental Management What Are The Two Types of Waste? One is contact-handled, which has lower radioactivity and can be

226

Waste Treatment Facility Saves Taxpayers Nearly $20 Million | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment Facility Saves Taxpayers Nearly $20 Million Waste Treatment Facility Saves Taxpayers Nearly $20 Million Waste Treatment Facility Saves Taxpayers Nearly $20 Million December 11, 2012 - 1:40pm Addthis A new enclosure for processing radioactive casks has put Oak Ridge on a path to finishing cleanup work two years ahead of schedule, saving nearly $20 million. | Photo courtesy of the Office of Environmental Management. A new enclosure for processing radioactive casks has put Oak Ridge on a path to finishing cleanup work two years ahead of schedule, saving nearly $20 million. | Photo courtesy of the Office of Environmental Management. Erin Szulman Erin Szulman Special Assistant, Office of Environmental Management What Are The Two Types of Waste? One is contact-handled, which has lower radioactivity and can be

227

DEMONSTRATION OF SIMULATED WASTE TRANSFERS FROM TANK AY-102 TO THE HANFORD WASTE TREATMENT FACILITY  

SciTech Connect

In support of Hanford's AY-102 Tank waste certification and delivery of the waste to the Waste Treatment and Immobilization Plant (WTP), Savannah River National Laboratory (SRNL) was tasked by the Washington River Protection Solutions (WRPS) to evaluate the effectiveness of mixing and transferring the waste in the Double Shell Tank (DST) to the WTP Receipt Tank. This work is a follow-on to the previous 'Demonstration of Internal Structures Impacts on Double Shell Tank Mixing Effectiveness' task conducted at SRNL 1. The objective of these transfers was to qualitatively demonstrate how well waste can be transferred out of a mixed DST tank and to provide insights into the consistency between the batches being transferred. Twelve (12) different transfer demonstrations were performed, varying one parameter at a time, in the Batch Transfer Demonstration System. The work focused on visual comparisons of the results from transferring six batches of slurry from a 1/22nd scale (geometric by diameter) Mixing Demonstration Tank (MDT) to six Receipt Tanks, where the consistency of solids in each batch could be compared. The simulant used in this demonstration was composed of simulated Hanford Tank AZ-101 supernate, gibbsite particles, and silicon carbide particles, the same simulant/solid particles used in the previous mixing demonstration. Changing a test parameter may have had a small impact on total solids transferred from the MDT on a given test, but the data indicates that there is essentially no impact on the consistency of solids transferred batch to batch. Of the multiple parameters varied during testing, it was found that changing the nozzle velocity of the Mixer Jet Pumps (MJPs) had the biggest impact on the amount of solids transferred. When the MJPs were operating at 8.0 gpm (22.4 ft/s nozzle velocity, U{sub o}D=0.504 ft{sup 2}/s), the solid particles were more effectively suspended, thus producing a higher volume of solids transferred. When the MJP flow rate was reduced to 5 gpm (14 ft/s nozzle velocity, U{sub o}D = 0.315 ft{sup 2}/s) to each pump, dead zones formed in the tank, resulting in fewer solids being transferred in each batch to the Receipt Tanks. The larger, denser particles were displaced (preferentially to the smaller particles) to one of the two dead zones and not re-suspended for the duration of the test. As the liquid level dropped in the MDT, re-suspending the particles became less effective (6th batch). The poor consistency of the solids transferred in the 6th batch was due to low liquid level in the MDT, thus poor mixing by the MJPs. Of the twelve tests conducted the best transfer of solids occurred during Test 6 and 8 where the MJP rotation was reduced to 1.0 rpm.

Adamson, D.; Poirier, M.; Steeper, T.

2009-12-03T23:59:59.000Z

228

Development of a Waste Treatment Process to Deactivate Reactive Uranium Metal and Produce a Stable Waste Form  

SciTech Connect

This paper highlights the results of initial investigations conducted to support the development of an integrated treatment process to convert pyrophoric metallic uranium wastes to a non-pyrophoric waste that is acceptable for land disposal. Several dissolution systems were evaluated to determine their suitability to dissolve uranium metal and that yield a final waste form containing uranium specie(s) amenable to precipitation, stabilization, adsorption, or ion exchange. During initial studies, one gram aliquots of uranium metal or the uranium alloy U-2%Mo were treated with 5 to 60 mL of selected reagents. Treatment systems screened included acids, acid mixtures, and bases with and without addition of oxidants. Reagents used included hydrochloric, sulfuric, nitric, and phosphoric acids, sodium hypochlorite, sodium hydroxide and hydrogen peroxide. Complete dissolution of the uranium turnings was achieved with the H{sub 3}PO{sub 4}/HCI system at room temperature within minutes. The sodium hydroxide/hydrogen peroxide, and sodium hypochlorite systems achieved complete dissolution but required elevated temperatures and longer reaction times. A ranking system based on criteria, such as corrosiveness, temperature, dissolution time, off-gas type and amount, and liquid to solid ratio, was designed to determine the treatment systems that should be developed further for a full-scale process. The highest-ranking systems, nitric acid/sulfuric acid and hydrochloric acid/phosphoric acid, were given priority in our follow-on investigations.

Gates-Anderson, D D; Laue, C A; Fitch, T E

2002-01-17T23:59:59.000Z

229

Independent Oversight Assessment, Idaho Cleanup Project Sodium Bearing Waste Treatment Project- November 2012  

Energy.gov (U.S. Department of Energy (DOE))

Assessment of Nuclear Safety Culture at the Idaho Cleanup Project Sodium Bearing Waste Treatment Project

230

DOE Selects Savannah River Remediation, LLC for Liquid Waste Contract at  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Selects Savannah River Remediation, LLC for Liquid Waste DOE Selects Savannah River Remediation, LLC for Liquid Waste Contract at Savannah River Site DOE Selects Savannah River Remediation, LLC for Liquid Waste Contract at Savannah River Site December 8, 2008 - 4:58pm Addthis Washington, D.C. -The U.S. Department of Energy (DOE) today announced the award to Savannah River Remediation, LLC as the liquid waste contractor for DOE's Savannah River Site (SRS) in Aiken, South Carolina. The contract is a cost-plus award-fee contract valued at approximately $3.3 billion over the entire contract, consisting of a base period of six years, plus an option to extend for up to two additional years. The base performance period of the contract will be from April 1, 2009 through March 31, 2015. A 90-day transition period will begin January 2, 2009.

231

DOE Selects Savannah River Remediation, LLC for Liquid Waste Contract at  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE Selects Savannah River Remediation, LLC for Liquid Waste DOE Selects Savannah River Remediation, LLC for Liquid Waste Contract at Savannah River Site DOE Selects Savannah River Remediation, LLC for Liquid Waste Contract at Savannah River Site December 8, 2008 - 4:58pm Addthis Washington, D.C. -The U.S. Department of Energy (DOE) today announced the award to Savannah River Remediation, LLC as the liquid waste contractor for DOE's Savannah River Site (SRS) in Aiken, South Carolina. The contract is a cost-plus award-fee contract valued at approximately $3.3 billion over the entire contract, consisting of a base period of six years, plus an option to extend for up to two additional years. The base performance period of the contract will be from April 1, 2009 through March 31, 2015. A 90-day transition period will begin January 2, 2009.

232

Mixed and Low-Level Waste Treatment Facility Project  

SciTech Connect

Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report documents those studies so the project can continue with an evaluation of programmatic options, system tradeoff studies, and the conceptual design phase of the project. This report, appendix B, comprises the engineering design files for this project study. The engineering design files document each waste steam, its characteristics, and identified treatment strategies.

1992-04-01T23:59:59.000Z

233

Reliability analysis of common hazardous waste treatment processes  

Science Conference Proceedings (OSTI)

Five hazardous waste treatment processes are analyzed probabilistically using Monte Carlo simulation to elucidate the relationships between process safety factors and reliability levels. The treatment processes evaluated are packed tower aeration, reverse osmosis, activated sludge, upflow anaerobic sludge blanket, and activated carbon adsorption.

Waters, R.D. [Vanderbilt Univ., Nashville, TN (United States)

1993-05-01T23:59:59.000Z

234

SRS Tank 48H Waste Treatment Project Technology Readiness Assessment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Savannah River Site Tank 48H Savannah River Site Tank 48H Waste Treatment Project Technology Readiness Assessment Harry D. Harmon Joan B. Berkowitz John C. DeVine, Jr. Herbert G. Sutter Joan K. Young SPD-07-195 July 31, 2007 Prepared by the U.S. Department of Energy Aiken, South Carolina SRS Tank 48H Waste Treatment Project SPD-07-195 Technology Readiness Assessment July 31, 2007 Signature Page 7/31/07 ___________________________ _________________________ John C. DeVine, Jr., Team Member Date SRS Tank 48H Waste Treatment Project SPD-07-195 Technology Readiness Assessment July 31, 2007 Executive Summary The purpose of this assessment was to determine the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's

235

Report: EM Tank Waste Subcommittee Full Report for Waste Treatment Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

U.S. DEPARTMENT OF ENERGY U.S. DEPARTMENT OF ENERGY 1000 INDEPENDENCE AVENUE SW WASHINGTON DC 20585 September 30, 2010 Dr. Inés R. Triay Assistant Secretary for Environmental Management 1000 Independence Avenue SW Washington, DC 20585 Dear Dr. Triay: As discussed during our September 15th public meeting, enclosed please find the Environmental Management Advisory Board EM Tank Waste Subcommittee Report for Waste Treatment Plant; Report Number EMAB EM-TWS WTP-001, September 30, 2010, in accordance with the Work Plan directive dated May 10, 2010. This report covers the work plan observations and recommendations concerning the Waste Treatment and Immobilization Plant at Hanford (WTP). The charge is summarized below. Charge 1: Verification of closure of Waste Treatment and Immobilization

236

Liquid low-level waste generation projections for ORNL in 1993  

SciTech Connect

Liquid low-level waste (LLLW) is generated by various programs and projects throughout Oak Ridge National Laboratory (ORNL). These wastes are collected in underground collection tanks, bottles, and trucks; they are then neutralized with sodium hydroxide and treated for volume reduction at the ORNL evaporator facility. This report presents historical and projected data concerning the volume and characterization of LLLW, prior to and after evaporation. Storage space for projected waste generation is also discussed.

DePaoli, S.M.

1994-04-01T23:59:59.000Z

237

Mixed and Low-Level Waste Treatment Facility project  

SciTech Connect

Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report, Appendix A, Environmental Regulatory Planning Documentation, identifies the regulatory requirements that would be imposed on the operation or construction of a facility designed to process the INEL's waste streams. These requirements are contained in five reports that discuss the following topics: (1) an environmental compliance plan and schedule, (2) National Environmental Policy Act requirements, (3) preliminary siting requirements, (4) regulatory justification for the project, and (5) health and safety criteria.

1992-04-01T23:59:59.000Z

238

Preliminary analysis of the ORNL Liquid Low-Level Waste system  

Science Conference Proceedings (OSTI)

The objective of this report is to summarize the status of the Liquid Low-Level Waste (LLLW) Systems Analysis project. The focus of this project has been to collect and tabulate data concerning the LLLW system, analyze the current LLLW system operation, and develop the information necessary for the development of long-term treatment options for the LLLW generated at ORNL. The data used in this report were collected through a survey of Oak Ridge National Laboratory (ORNL) literature, various letter reports, and a survey of all current LLLW generators. These data are also being compiled in a user friendly database for ORNL-wide distribution. The database will allow the quick retrieval of all information collected on the ORNL LLLW system and will greatly benefit any LLLW analysis effort. This report summarizes the results for the analyses performed to date on the LLLW system.

Abraham, T.J.; DePaoli, S.M.; Robinson, S.M.; Walker, A.B.

1994-08-01T23:59:59.000Z

239

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2 2 Independent Oversight Review, Waste Treatment and Immobilization Plant - March 2012 March 2012 Review of the Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security, conducted an independent review of selected aspects of construction quality at the Hanford Site Waste Treatment and Immobilization Plant (WTP). The review, which was performed November 14-17, 2011, was the latest in a series of ongoing quarterly assessments of construction quality performed by Independent Oversight at the WTP construction site. Independent Oversight determined that construction quality at WTP was adequate in the areas reviewed. BNI Engineering has developed appropriate

240

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

January 2013 January 2013 Independent Oversight Review, Waste Treatment and Immobilization Plant - January 2013 January 2013 Review of the Hanford Waste Treatment and Immobilization Plant Black-Cell and Hard-To-Reach Pipe Spools Procurement Process and the Office of River Protection Audit of That Process The Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted a concurrent independent review with the U.S. Department of Energy (DOE) Office of River Protection (ORP) of selected aspects of the Bechtel National, Inc. (BNI) Hanford Site Waste Treatment and Immobilization Plant (WTP) procurement processes for WTP black-cell (BC) and hard-to-reach (HtR) pipe spools. The Independent Oversight review was performed by the HSS Office of Safety and

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

August 2012 August 2012 Independent Oversight Review, Waste Treatment and Immobilization Plant - August 2012 August 2012 Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality The U. S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security, conducted independent reviews of selected aspects of construction quality at the Hanford Site Waste Treatment and Immobilization Project (WTP). The reviews for this report were performed on site during February 6-10, 2012 and April 30 - May 4, 2012, and were the latest in a series of ongoing quarterly assessments of construction quality performed by Independent Oversight at the WTP. Independent Oversight determined that construction quality at WTP is

242

Independent Oversight Activity Report, Hanford Waste Treatment and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

November 2013 November 2013 Independent Oversight Activity Report, Hanford Waste Treatment and Immobilization Plant - November 2013 December 2013 Catholic University of America Vitreous State Laboratory Tour and Discussion of Experiments Conducted in Support of Hanford Site Waste Treatment and Immobilization Plant Select Systems Design [HIAR-VSL-2013-11-18] This Independent Activity Report documents an oversight activity conducted by the Office of Health, Safety and Security's (HSS) Office of Safety and Emergency Management Evaluations on November 18, 2013, at the Catholic University of America Vitreous State Laboratory (VSL). Bechtel National, Inc. (BNI) is the contractor responsible for the design and construction of the Hanford Site Waste Treatment and Immobilization Plant (WTP) for the

243

Independent Oversight Review, Waste Treatment and Immobilization Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

January 2013 January 2013 Independent Oversight Review, Waste Treatment and Immobilization Plant - January 2013 January 2013 Review of the Hanford Waste Treatment and Immobilization Plant Black-Cell and Hard-To-Reach Pipe Spools Procurement Process and the Office of River Protection Audit of That Process The Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted a concurrent independent review with the U.S. Department of Energy (DOE) Office of River Protection (ORP) of selected aspects of the Bechtel National, Inc. (BNI) Hanford Site Waste Treatment and Immobilization Plant (WTP) procurement processes for WTP black-cell (BC) and hard-to-reach (HtR) pipe spools. The Independent Oversight review was performed by the HSS Office of Safety and

244

System for removing liquid waste from a tank  

DOE Patents (OSTI)

A tank especially suited for nuclear applications is disclosed. The tank comprises a tank shell for protectively surrounding the liquid contained therein; an inlet positioned on the tank for passing a liquid into the tank; a sump positioned in an interior portion of the tank for forming a reservoir of the liquid; a sloped incline for resting the tank thereon and for creating a natural flow of the liquid toward the sump; a pump disposed adjacent the tank for pumping the liquid; and a pipe attached to the pump and extending into the sump for passing the liquid therethrough. The pump pumps the liquid in the sump through the pipe and into the pump for discharging the liquid out of the tank.

Meneely, Timothy K. (Penn Hills, PA); Sherbine, Catherine A. (N. Versailles Township, Allegheny County, PA)

1994-01-01T23:59:59.000Z

245

System for removing liquid waste from a tank  

DOE Patents (OSTI)

A tank especially suited for nuclear applications is disclosed. The tank comprises a tank shell for protectively surrounding the liquid contained therein; an inlet positioned on the tank for passing a liquid into the tank; a sump positioned in an interior portion of the tank for forming a reservoir of the liquid; a sloped incline for resting the tank thereon and for creating a natural flow of the liquid toward the sump; a pump disposed adjacent the tank for pumping the liquid; and a pipe attached to the pump and extending into the sump for passing the liquid there through. The pump pumps the liquid in the sump through the pipe and into the pump for discharging the liquid out of the tank. 2 figures.

Meneely, T.K.; Sherbine, C.A.

1994-04-26T23:59:59.000Z

246

The Use of Transportable Processing Systems for the Treatment of Radioactive Nuclear Wastes  

Science Conference Proceedings (OSTI)

EnergySolutions has developed two major types of radioactive processing plants based on its experience in the USA and UK, and its exclusive North American access to the intellectual property and know-how developed over 50 years at the Sellafield nuclear site in the UK. Passive Secure Cells are a type of hot cell used in place of the Canyons typically used in US-designed radioactive facilities. They are used in permanent, large scale plants suitable for long term processing of large amounts of radioactive material. The more recently developed Transportable Processing Systems, which are the subject of this paper, are used for nuclear waste processing and clean-up when processing is expected to be complete within shorter timescales and when it is advantageous to be able to move the processing equipment amongst a series of geographically spread-out waste treatment sites. Such transportable systems avoid the construction of a monolithic waste processing plant which itself would require extensive decommissioning and clean-up when its mission is complete. This paper describes a range of transportable radioactive waste processing equipment that EnergySolutions and its partners have developed including: the portable MOSS drum-based waste grouting system, the skid mounted MILWPP large container waste grouting system, the IPAN skid-mounted waste fissile content non-destructive assay system, the Wiped Film Evaporator low liquid hold-up transportable evaporator system, the CCPU transportable solvent extraction cesium separation system, and the SEP mobile shielded cells for emptying radioactive debris from water-filled silos. Maximum use is made of proven, robust, and compact processing equipment such as centrifugal contactors, remote sampling systems, and cement grout feed and metering devices. Flexible, elastomer-based Hose-in-Hose assemblies and container-based transportable pump booster stations are used in conjunction with these transportable waste processing units for transferring radioactive waste from its source to the processing equipment. (authors)

Phillips, Ch.; Houghton, D.; Crawford, G. [EnergySolutions LLC., 2345 Stevens Drive, Richland, WA (United States)

2008-07-01T23:59:59.000Z

247

WASTE TREATMENT AND IMMOBILIZATION PLANT U. S. DEPARTMENT OF ENERGY OFFICE OF RIVER PROTECTION SUBMERGED BED SCRUBBER CONDENSATE DISPOSITION PROJECT - ABSTRACT # 13460  

SciTech Connect

The Hanford Waste Treatment and Immobilization Plant (WTP) will generate an off-gas treatment system secondary liquid waste stream [submerged bed scrubber (SBS) condensate], which is currently planned for recycle back to the WTP Low Activity Waste (LAW) melter. This SBS condensate waste stream is high in Tc-99, which is not efficiently captured in the vitrified glass matrix. A pre-conceptual engineering study was prepared in fiscal year 2012 to evaluate alternate flow paths for melter off-gas secondary liquid waste generated by the WTP LAW facility. This study evaluated alternatives for direct off-site disposal of this SBS without pre-treatment, which mitigates potential issues associated with recycling.

YANOCHO RM; CORCORAN C

2012-11-15T23:59:59.000Z

248

Conversion of historic waste treatment process for production of an LDR and WIPP/WAC compliant TRU wasteform  

SciTech Connect

In support of the historic weapons production mission at the, Rocky Flats Environmental Technology Site (RFETS), several liquid waste treatment processes were designed, built and operated for treatment of plutonium-contaminated aqueous waste. Most of these @ processes ultimately resulted in the production of a cemented wasteform. One of these treatment processes was the Miscellaneous Aqueous Waste Handling and Solidification Process, commonly referred to as the Bottlebox process. Due to a lack of processing demand, Bottlebox operations were curtailed in late 1989. Starting in 1992, a treatment capability for stabilization of miscellaneous, Resource Conservation and Recovery Act (RCRA) hazardous, plutonium-nitrate solutions was identified. This treatment was required to address potentially unsafe storage conditions for these liquids. The treatment would produce a TRU wasteform. It thus became necessary to restart the Bottlebox process, but under vastly different conditions and constraints than existed prior to its curtailment. This paper provides a description of the historical Bottlebox process and process controls; and then describes, in detail, all of the process and process control changes that were implemented to convert the treatment system such that a Waste Isolation Pilot Plant (WIPP) and a Land Disposal Requirements (LDR) compliant wasteform would be produced. The rationale for imposition of LDRs on a TRU wasteform is discussed. In addition, this paper discusses the program changes implemented to meet modem criticality safety, Conduct of Operations, and Department of Energy Nuclear Facility restart requirements.

Dunn, R.P.; Wagner, R.A.

1997-03-01T23:59:59.000Z

249

Treatment of Mixed Wastes via Fixed Bed Gasification  

SciTech Connect

This report outlines the details of research performed under USDOE Cooperative Agreement DE-FC21-96MC33258 to evaluate the ChemChar hazardous waste system for the destruction of mixed wastes, defined as those that contain both RCRA-regulated haz- ardous constituents and radionuclides. The ChemChar gasification system uses a granular carbonaceous char matrix to immobilize wastes and feed them into the gasifier. In the gasifier wastes are subjected to high temperature reducing conditions, which destroy the organic constituents and immobilize radionuclides on the regenerated char. Only about 10 percent of the char is consumed on each pass through the gasifier, and the regenerated char can be used to treat additional wastes. When tested on a 4-inch diameter scale with a continuous feed unit as part of this research, the ChemChar gasification system was found to be effective in destroying RCRA surrogate organic wastes (chlorobenzene, dichloroben- zene, and napht.halene) while retaining on the char RCRA heavy metals (chromium, nickel, lead, and cadmium) as well as a fission product surrogate (cesium) and a plutonium surrogate (cerium). No generation of harmful byproducts was observed. This report describes the design and testing of the ChemChar gasification system and gives the operating procedures to be followed in using the system safely and effectively for mixed waste treatment.

None

1998-10-28T23:59:59.000Z

250

Environment Canada research on land treatment of petroleum wastes  

Science Conference Proceedings (OSTI)

The purpose of the studies presented in this book is to identify wastes which can be applied to land in an environmentally acceptable manner and to provide information on which to base guidelines for the proper application of such wastes to land. The information which has been collected to date has focused on the persistence and fate of oil and toxic constituents of petroleum wastes when applied to soil, potential environmental impacts and risk to human health associated with application to land, and site managements techniques which enhance treatment of organic constituents of wastes while protecting environmental quality. The potential for contamination of groundwater, the accumulation of hazardous substances in soil and effects on plant growth have undergone the most intensive investigation to date. Impingement on air quality has received limited study.

Bulman, T.L.; Scroggins, R.P. (Wastewater Technolgy Centre, Burlington, Ontario (CA))

1988-01-01T23:59:59.000Z

251

Radiological, physical, and chemical characterization of additional alpha contaminated and mixed low-level waste for treatment at the advanced mixed waste treatment project  

SciTech Connect

This document provides physical, chemical, and radiological descriptive information for a portion of mixed waste that is potentially available for private sector treatment. The format and contents are designed to provide treatment vendors with preliminary information on the characteristics and properties for additional candidate portions of the Idaho National Engineering Laboratory (INEL) and offsite mixed wastes not covered in the two previous characterization reports for the INEL-stored low-level alpha-contaminated and transuranic wastes. This report defines the waste, provides background information, briefly reviews the requirements of the Federal Facility Compliance Act (P.L. 102-386), and relates the Site Treatment Plans developed under the Federal Facility Compliance Act to the waste streams described herein. Each waste is summarized in a Waste Profile Sheet with text, charts, and tables of waste descriptive information for a particular waste stream. A discussion of the availability and uncertainty of data for these waste streams precedes the characterization descriptions.

Hutchinson, D.P.

1995-07-01T23:59:59.000Z

252

Sodium-Bearing Waste Treatment, Applied Technology Plan  

SciTech Connect

Settlement Agreement between the Department of Energy and the State of Idaho mandates treatment of sodium-bearing waste at the Idaho Nuclear Technology and Engineering Center within the Idaho National Engineering and Environmental Laboratory. One of the requirements of the Settlement Agreement is to complete treatment of sodium-bearing waste by December 31, 2012. Applied technology activities are required to provide the data necessary to complete conceptual design of four identified alternative processes and to select the preferred alternative. To provide a technically defensible path forward for the selection of a treatment process and for the collection of needed data, an applied technology plan is required. This document presents that plan, identifying key elements of the decision process and the steps necessary to obtain the required data in support of both the decision and the conceptual design. The Sodium-Bearing Waste Treatment Applied Technology Plan has been prepared to provide a description/roadmap of the treatment alternative selection process. The plan details the results of risk analyzes and the resulting prioritized uncertainties. It presents a high-level flow diagram governing the technology decision process, as well as detailed roadmaps for each technology. The roadmaps describe the technical steps necessary in obtaining data to quantify and reduce the technical uncertainties associated with each alternative treatment process. This plan also describes the final products that will be delivered to the Department of Energy Idaho Operations Office in support of the office's selection of the final treatment technology.

Lance Lauerhass; Vince C. Maio; S. Kenneth Merrill; Arlin L. Olson; Keith J. Perry

2003-06-01T23:59:59.000Z

253

Recovery of Tritium from Pharmaceutical Mixed Waste Liquids  

Science Conference Proceedings (OSTI)

Decontamination and Waste / Proceedings of the Sixth International Conference on Tritium Science and Technology Tsukuba, Japan November 12-16, 2001

W. T. Shmayda; R. D. Gallagher

254

Evaluation of System Level Modeling and Simulation Tools in Support of Savannah River Site Liquid Waste Process  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Savannah River Site Liquid Waste Process Savannah River Site Liquid Waste Process June 2009 Monica C. Regalbuto Office of Waste Processing DOE/EM Kevin G. Brown Vanderbilt University and CRESP David W. DePaoli Oak Ridge National Laboratory Candido Pereira Argonne National Laboratory John R. Shultz Office of Waste Processing DOE/EM Sahid C. Smith Office of Waste Processing DOE/EM External Technical Review for Evaluation of System Level Modeling and Simulation Tools in Support of Savannah River Site Liquid Waste Process June 2009 ACKNOWLEDGEMENTS The Review Team thanks Ms. Sonitza Blanco, Team Lead Planning and Coordination Waste Disposition Project U.S. Department of Energy Savannah River Operations Office and Mr. Pete Hill, Liquid Waste Planning Manager for Washington Savannah River Company, for their

255

Cost of meeting geothermal liquid effluent disposal regulations  

DOE Green Energy (OSTI)

Background information is presented on the characteristics of liquid wastes and the available disposal options. Regulations that may directly or indirectly influence liquid waste disposal are reviewed. An assessment of the available wastewater-treatment systems is provided. A case study of expected liquid-waste-treatment and disposal costs is summarized. (MHR)

Wells, K.D.; Currie, J.W.; Price, B.A.; Rogers, E.A.

1981-06-01T23:59:59.000Z

256

PMB-Waste: An analysis of fluidized bed thermal treatment  

SciTech Connect

A fluidized bed treatment process was evaluated for solid waste from plastic media blasting of aircraft protective coating. The treatment objective is to decompose and oxidize all organic components, and concentrate all the hazardous metals in the ash. The reduced volume and mass are expected to reduce disposal cost. A pilot test treatment was done in an existing fluidized bed equipped with emissions monitors, and emissions within regulatory requirements were demonstrated. A economic analysis of the process is inconclusive due to lack of reliable cost data of disposal without thermal treatment.

Gat, U.; Kass, M.D.; Lloyd, D.B.

1995-07-01T23:59:59.000Z

257

Mixed and low-level waste treatment facility project  

SciTech Connect

The technology information provided in this report is only the first step toward the identification and selection of process systems that may be recommended for a proposed mixed and low-level waste treatment facility. More specific information on each technology will be required to conduct the system and equipment tradeoff studies that will follow these preengineering studies. For example, capacity, maintainability, reliability, cost, applicability to specific waste streams, and technology availability must be further defined. This report does not currently contain all needed information; however, all major technologies considered to be potentially applicable to the treatment of mixed and low-level waste are identified and described herein. Future reports will seek to improve the depth of information on technologies.

Not Available

1992-04-01T23:59:59.000Z

258

Principles of biotechnological treatment of industrial wastes  

Science Conference Proceedings (OSTI)

This review includes current information on biodegradation processes of pollutants, digestor biocenosis and bioadditives, sludge production, measurement of pollution, and advances regarding biotechnological treatment of a series of specific industrial effluents. It was foreseen in 1980 that biotechnology would foster the creation of new industries with low energy requirements. This is because the growth of microorganisms provides a renewable source of energy.

Roig, M.G.; Martin Rodriguez, M.J.M.; Cachaza, J.M. (Univ. de Salamanca, Salamanca (Spain). Dept. de Quimica Fisica); Mendoza Sanchez, L. (C/Sol Oriente, Salamanca (Spain). Estudios y Proyectos); Kennedy, J.F. (Univ. of Birmingham, Birmingham (United Kingdom). Research Lab. for the Chemistry of Bioactive Carbohydrates and Proteins)

1993-07-01T23:59:59.000Z

259

Physical/chemical treatment of mixed waste soils  

Science Conference Proceedings (OSTI)

This report discusses the results and findings of the demonstration testing of a physical/chemical treatment technology for mixed wastes. The principal objective of the tests was to demonstrate the capability of the low temperature thermal separation (LTTS) technology for rendering PCB-contaminated mixed waste soils as nonhazardous and acceptable for low level radioactive waste disposal. The demonstration testing of this technology was a jointly-conducted project by the US Department of Energy (DOE), the Martin Marietta Energy Systems (Energy Systems) Waste Management Technology Center at the Oak Ridge National Laboratory, and IT Corporation. This pilot-scale demonstration program testing of IT's thermal separator technology in Oak Ridge was conducted as part of the DOE Model Program. This program has private industry, regulators, and universities helping to solve DOE waste management problems. Information gained from the DOE Model is shared with the participating organizations, other federal agencies, and regulatory agencies. The following represent the most significant findings from these demonstration tests: Thermal separation effectively separated PCB contamination from a mixed waste to enable the treated soil to be managed as low level radioactive waste. At the same operating conditions, mercury contamination of 0.8 ppM was reduced to less than 0.1 ppM. The majority of uranium and technetium in the waste feeds oil remained in the treated soil. Radionuclide concentration in cyclone solids is due to carry-over of entrained particles in the exit gas and not due to volatilization/condensation. Thermal separation also effectively treated all identified semi-volatile contaminants in the waste soil to below detection limits with the exception of di-n-butylphthalate in one of the two runs. 4 refs., 1 fig., 6 tabs.

Morris, M.I. (Oak Ridge National Lab., TN (USA)); Alperin, E.S.; Fox, R.D. (IT Corp., Knoxville, TN (USA))

1991-01-01T23:59:59.000Z

260

Hanford Waste Treatment and Immobilization Plant Construction Quality, August 2011  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Independent Review Report Independent Review Report Waste Treatment and Immobilization Plant Construction Quality May 2011 August 2011 Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Background .......................................................................................................................................... 1 3.0 Scope .................................................................................................................................................... 1 4.0 Results .................................................................................................................................................. 2

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Progress in geothermal waste treatment biotechnology  

SciTech Connect

Studies directed at the development of an environmentally acceptable technology for the treatment and disposal of geothermal sludges have shown that a biotechnology based on microbial biochemical processes is technically and economically feasible. Process designs for the emerging biotechnology have to take several variables into consideration. In the present paper some of these variables will be discussed in terms of their effect on the cost and efficiency of potential processes. 7 refs., 4 figs., 4 tabs.

Premuzic, E.T.; Lin, M.S. (Brookhaven National Lab., Upton, NY (USA)); Kang, Sun Ki (Oregon State Univ., Corvallis, OR (USA). Dept. of Chemical Engineering)

1991-05-01T23:59:59.000Z

262

Automated Sampling and Sample Pneumatic Transport of High Level Tank Wastes at the Hanford Waste Treatment Plant  

Science Conference Proceedings (OSTI)

This paper describes the development work, and design and engineering tasks performed, to provide a fully automated sampling system for the Waste Treatment Plant (WTP) project at the Hanford Site in southeastern Washington State, USA. WTP is being built to enable the emptying and immobilization of highly active waste resulting from processing of irradiated nuclear fuel since the 1940's. The Hanford Tank Wastes are separated into Highly Level Waste (HLW), and Low Active Waste (LAW) fractions, which are separately immobilized by vitrification into borosilicate glass. Liquid samples must be taken of the waste and Glass Forming Chemicals (GFCs) before vitrification, and analyzed to insure the glass products will comply with specifications established in the WTP contract. This paper describes the non-radioactive testing of the sampling of the HLW and LAW melter feed simulants that was performed ahead of final equipment design. These trials were essential to demonstrate the effectiveness and repeatability of the integrated sampling system to collect representative samples, free of cross-contamination. Based on existing tried and proven equipment, the system design is tailored to meet the WTP project's specific needs. The design provides sampling capabilities from 47 separate sampling points and includes a pneumatic transport system to move the samples from the 3 separate facilities to the centralized analytical laboratory. The physical and rheological compositions of the waste simulants provided additional challenges in terms of the sample delivery, homogenization, and sample capture equipment design requirements. The activity levels of the actual waste forms, specified as 486 E9 Bq/liter (Cs-137), 1.92 E9 Bq/liter (Co-60), and 9.67 E9 Bq/liter (Eu-154), influenced the degree of automation provided, and justified the minimization of manual intervention needed to obtain and deliver samples from the process facilities to the analytical laboratories. Maintaining high integrity primary and secondary confinement, including during the cross-site transportation of the samples, is a key requirement that is achieved and assured at all times. (authors)

Phillips, C.; Richardson, J. E. [BNG America, 2345 Stevens Drive, Richland, WA, 99354 (United States)

2006-07-01T23:59:59.000Z

263

Information; and Other Matters- Amount of Uranium in Liquid Waste Effluents, Treated Domestic Sanitary Wastewater Sampling, and Liquid Effluent Collection and  

E-Print Network (OSTI)

for the AES exemption request related to commencement of construction (Ref. 2). On October 15, 2009, AES submitted the response to the NRC RAIs related to commencement of construction (Ref. 3). Subsequently, the NRC requested additional information regarding the AES response. Enclosure 1.1 provides the AES response to the additional information regarding preconstrucion activities requested by the NRC. Enclosure 2.1 provides the markup pages of the EREF ER. On August 10, 2009, the NRC transmitted to AES RAIs regarding the EREF Environmental Report (ER) (Ref. 4). On September 9, 2009, AES submitted the response to the NRC ER RAIs (Ref. 5). Subsequently, the NRC requested additional information regarding other matters including the amount of uranium in liquid waste effluents, treated domestic sanitary wastewater sampling, and Liquid Effluent Collection and Treatment System evaporator sediment sampling. Enclosure 1.2 provides the AES response regarding the amount of uranium in liquid waste effluent. There are no markup pages to the EREF ER for this response. Enclosure 1.3 provides the AES response regarding treated domestic sanitary wastewater sampling. Enclosure 2.2 provides the markup pages of the EREF ER. Enclosure 1.4 provides the AES

Eagle Rock; Enrichment Facility

2009-01-01T23:59:59.000Z

264

Mixed and Low-Level Treatment Facility Project. Appendix B, Waste stream engineering files, Part 1, Mixed waste streams  

SciTech Connect

This appendix contains the mixed and low-level waste engineering design files (EDFS) documenting each low-level and mixed waste stream investigated during preengineering studies for Mixed and Low-Level Waste Treatment Facility Project. The EDFs provide background information on mixed and low-level waste generated at the Idaho National Engineering Laboratory. They identify, characterize, and provide treatment strategies for the waste streams. Mixed waste is waste containing both radioactive and hazardous components as defined by the Atomic Energy Act and the Resource Conservation and Recovery Act, respectively. Low-level waste is waste that contains radioactivity and is not classified as high-level waste, transuranic waste, spent nuclear fuel, or 11e(2) byproduct material as defined by DOE 5820.2A. Test specimens of fissionable material irradiated for research and development only, and not for the production of power or plutonium, may be classified as low-level waste, provided the concentration of transuranic is less than 100 nCi/g. This appendix is a tool that clarifies presentation format for the EDFS. The EDFs contain waste stream characterization data and potential treatment strategies that will facilitate system tradeoff studies and conceptual design development. A total of 43 mixed waste and 55 low-level waste EDFs are provided.

1992-04-01T23:59:59.000Z

265

Assessment of Tank 241-S-112 Liquid Waste Mixing in Tank 241-SY-101  

SciTech Connect

The objectives of this study were to evaluate mixing of liquid waste from Tank 241-S-112 with waste in Tank 241-SY-101 and to determine the properties of the resulting waste for the cross-site transfer to avoid potential double-shell tank corrosion and pipeline plugging. We applied the time-varying, three-dimensional computer code TEMPEST to Tank SY-101 as it received the S-112 liquid waste. The model predicts that temperature variations in Tank SY-101 generate a natural convection flow that is very slow, varying from about 7 x 10{sup -5} to 1 x 10{sup -3} ft/sec (0.3 to about 4 ft/hr) in most areas. Thus, natural convection would eventually mix the liquid waste in SY-101 but would be very slow to achieve nearly complete mixing. These simulations indicate that the mixing of S-112 and SY-101 wastes in Tank SY-101 is a very slow process, and the density difference between the two wastes would further limit mixing. It is expected to take days or weeks to achieve relatively complete mixing in Tank SY-101.

Onishi, Yasuo; Trent, Donald S.; Wells, Beric E.; Mahoney, Lenna A.

2003-10-01T23:59:59.000Z

266

DOE Chooses Idaho Treatment Group, LLC to Disposition Waste at the Advanced  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Chooses Idaho Treatment Group, LLC to Disposition Waste at the Chooses Idaho Treatment Group, LLC to Disposition Waste at the Advanced Mixed Waste Treatment Project: Contract will continue cleanup and waste operations at the Idaho Site DOE Chooses Idaho Treatment Group, LLC to Disposition Waste at the Advanced Mixed Waste Treatment Project: Contract will continue cleanup and waste operations at the Idaho Site May 27, 2011 - 12:00pm Addthis Media Contact Brad Bugger (208) 526-0833 Idaho Falls - In order to further meet the U.S. Department of Energy's commitments to the citizens of the state of Idaho, the DOE today announced that it has selected Idaho Treatment Group, LLC (ITG) to perform waste processing at the Advanced Mixed Waste Treatment Project (AMWTP) at DOE's Idaho Site near Idaho Falls. The contract is estimated at approximately

267

Mixed Waste Focus Area Mercury Working Group: An integrated approach to mercury waste treatment and disposal  

SciTech Connect

In May 1996, the US Department of Energy (DOE) Mixed Waste Focus Area (MWFA) initiated the Mercury Working Group (HgWG). The HgWG was established to address and resolve the issues associated with mercury contaminated mixed wastes. During the MWFA`s initial technical baseline development process, three of the top four technology deficiencies identified were related to the need for amalgamation, stabilization, and separation removal technologies for the treatment of mercury and mercury contaminated mixed waste. The HgWG is assisting the MWFA in soliciting, identifying, initiating, and managing efforts to address these areas. The focus of the HgWG is to better establish the mercury related treatment technologies at the DOE sites, refine the MWFA technical baseline as it relates to mercury treatment, and make recommendations to the MWFA on how to most effectively address these needs. Based on the scope and magnitude of the mercury mixed waste problem, as defined by HgWG, solicitations and contract awards have been made to the private sector to demonstrate both the amalgamation and stabilization processes using actual mixed wastes. Development efforts are currently being funded that will address DOE`s needs for separation removal processes. This paper discusses the technology selection process, development activities, and the accomplishments of the HgWG to date through these various activities.

Conley, T.B.; Morris, M.I.; Osborne-Lee, I.W.

1998-01-01T23:59:59.000Z

268

Radiological Monitoring of Waste Treatment Plant  

Science Conference Proceedings (OSTI)

Scheduled waste in West Malaysia is handled by Concession Company and is stored and then is incinerated. It is known that incineration process may result in naturally occurring radioactive materials (NORM) to be concentrated. In this study we have measured three samples consist of by-product from the operation process such as slag, filter cake and fly ash. Other various environmental media such as air, surface water, groundwater and soil within and around the plant have also been analysed for their radioactivity levels. The concentration of Ra-226, Ac-228 and K-40 in slag are 0.062 Bq/g, 0.016 Bq/g and 0.19 Bq/g respectively. The total activity (Ra{sub eq}) in slag is 99.5 Bq/kg. The concentration in fly ash is 0.032 Bq/g, 0.16 Bq/g and 0.34 Bq/g for Ra-226, Ac-228 and K-40 respectively resulting in Raeq of 287.0 Bq/kg. For filter cake, the concentration is 0.13 Bq/g, 0.031 Bq/g and 0.33 Bq/g for Ra-226, Ac-228 and K-40 respectively resulting in Raeq of 199.7 Bq/kg. The external radiation level ranges from 0.08 {mu}Sv/h (Administrative building) to 0.35 {mu}Sv/h (TENORM storage area). The concentration level of radon and thoron progeny varies from 0.0001 to 0.0016 WL and 0.0006 WL to 0.002 WL respectively. For soil samples, the activity ranges from 0.11 Bq/g to 0.29 Bq/g, 0.06 Bq/g to 0.18 Bq/g and 0.065 Bq/g to 0.38 Bq/g for Ra-226, Ac-228 and K-40 respectively. While activity in water, except for a trace of K-40, it is non-detectable.

Amin, Y. M. [Physics Dept, University of Malaya, 50603 Kuala Lumpur (Malaysia); Nik, H. W. [Asialab (Malaysia) Sdn Bhd, 14 Jalan Industri USJ 1, 47600 Subang Jaya (Malaysia)

2011-03-30T23:59:59.000Z

269

Feed Composition for Sodium-Bearing Waste Treatment Process  

SciTech Connect

Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated by a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is to complete treatment of SBW by December 31, 2012. To support both design and development studies for the SBW treatment process, detailed feed compositions are needed. This report contains the expected compositions of these feed streams and the sources and methods used in obtaining these compositions.

Barnes, C.M.

2000-10-30T23:59:59.000Z

270

Sulfur polymer stabilization/solidification (SPSS) treatment of mixed waste mercury recovered from environmental restoration activities at BNL  

SciTech Connect

Over 1,140 yd{sup 3} of radioactively contaminated soil containing toxic mercury (Hg) and several liters of mixed-waste elemental mercury were generated during a Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) removal action at Brookhaven National Laboratory (BNL). The US Department of Energy's (DOE) Office of Science and Technology Mixed Waste Focus Area (DOE MWFA) is sponsoring a comparison of several technologies that may be used to treat these wastes and similar wastes at BNL and other sites across the DOE complex. This report describes work conducted at BNL on the application and pilot-scale demonstration of the newly developed Sulfur Polymer Stabilization/Solidification (SPSS) process for treatment of contaminated mixed-waste soils containing high concentrations ({approximately} 5,000 mg/L) of mercury and liquid elemental mercury. BNL's SPSS (patent pending) process chemically stabilizes the mercury to reduce vapor pressure and leachability and physically encapsulates the waste in a solid matrix to eliminate dispersion and provide long-term durability. Two 55-gallon drums of mixed-waste soil containing high concentrations of mercury and about 62 kg of radioactive contaminated elemental mercury were successfully treated. Waste loadings of 60 wt% soil were achieved without resulting in any increase in waste volume, while elemental mercury was solidified at a waste loading of 33 wt% mercury. Toxicity Characteristic Leaching Procedure (TCLP) analyses indicate the final waste form products pass current Environmental Protection Agency (EPA) allowable TCLP concentrations as well as the more stringent proposed Universal Treatment Standards. Mass balance measurements show that 99.7% of the mercury treated was successfully retained within the waste form, while only 0.3% was captured in the off gas system.

Kalb, P.; Adams, J.; Milian, L.

2001-01-29T23:59:59.000Z

271

Role of Liquid Waste Pretreatment Technologies in Solving the DOE Clean-up Mission  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Role of Liquid Waste Pretreatment Technologies in Role of Liquid Waste Pretreatment Technologies in Solving the DOE Clean-up Mission W. R. Wilmarth March 5 2009 March 5, 2009 HLW Corporate Board Phoenix AZ HLW Corporate Board, Phoenix, AZ Co-authors M. E. Johnson, CH2M Hill Plateau Remediation Company G. Lumetta, Pacific Northwest National Laboratory N Machara DOE Office of Engineering and Technology N. Machara, DOE Office of Engineering and Technology M. R. Poirier, Savannah River National Laboratory P C S DOE S h Ri P. C. Suggs, DOE Savannah River M. C. Thompson, Savannah River National Laboratory, Retired Retired 2 Background Separations is a fundamental business within DOE. The role of separations today is to expedite waste retrieval The role of separations today is to expedite waste retrieval, processing and closure. Recognized as part of E&T Roadmap

272

Recent developments in geothermal waste treatment biotechnology  

DOE Green Energy (OSTI)

Continuing studies at Brookhaven National Laboratory (BNL) have shown that cost-efficient biotechnology for the removal of toxic trace metals from geothermal sludge is feasible. Pilot-scale experiments have shown that fast rates (< 24-h) of metal removal at 55{degree}C--60{degree}C can be achieved with removal efficiencies of better than 80%, yielding a product well within the environmental regulatory limits. Recent studies have shown that radionuclides, such as radium present in low concentrations in some sludges, can also be removed by means of a secondary biotreatment. The process produces an aqueous phase which contains all of the regulatory metals in a soluble form. A follow-up technology for the treatment of the aqueous phase is concurrently being developed at BNL. Preliminary results indicate that a small volume concentrate of metals can be generated producing an aqueous phase which meets drinking water standards. In this paper the current state-of-the-biotechnology will be discussed.

Premuzic, E.T.; Lin, M.S.; Jin, J.Z.

1993-05-01T23:59:59.000Z

273

Novel Solvent for the Simultaneous recovery of Radioactive Nuclides from Liquid Radioactive Wastes  

DOE Patents (OSTI)

The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.

Romanovskiy, Valeriy Nicholiavich; Smirnov, Lgor V.; Babain, Vasiliy A.; Todd, Terry A.; Brewer, Ken N.

1999-10-07T23:59:59.000Z

274

Pyrochemical treatment of Idaho Chemical Processing Plant high-level waste calcine  

SciTech Connect

The Idaho Chemical Processing Plant (ICPP), located at the Idaho National Engineering Laboratory (INEL), has reprocessed irradiated nuclear fuels for the US Department of Energy (DOE) since 1951 to recover uranium, krypton-85, and isolated fission products for interim treatment and immobilization. The acidic radioactive high-level liquid waste (HLLW) is routinely stored in stainless steel tanks and then, since 1963, calcined to form a dry granular solid. The resulting high-level waste (HLW) calcine is stored in seismically hardened stainless steel bins that are housed in underground concrete vaults. A research and development program has been established to determine the feasibility of treating ICPP HLW calcine using pyrochemical technology.This technology is described.

Todd, T.A.; DelDebbio, J.A.; Nelson, L.O.; Sharpsten, M.R.

1993-06-01T23:59:59.000Z

275

Magnetic Adsorption Method for the Treatment of Metal Contaminated Aqueous Waste  

SciTech Connect

There have been many recent developments in separation methods used for treating radioactive and non-radioactive metal bearing liquid wastes. These methods have included adsorption, ion exchange, solvent extraction and other chemical and physical techniques. To date very few, if any, of these processes can provide a low cost and environmentally benign solution. Recent research into the use of magnetite for wastewater treatment indicates the potential for magnetite both cost and environment drivers. A brief review of recent work in using magnetite as a sorbent is presented as well as recent work performed in our laboratory using supported magnetite in the presence of an external magnetic field. The application to groundwater and other aqueous waste streams is discussed. Recent research has focused on supporting magnetite in an economical (as compared to the magnetic polymine-epichlorohydrine resin) and inert (non-reactive, chemically or otherwise) environment that promotes both adsorption and satisfactory flow characteristics.

G. B. Cotten (Parsons); J. D. Navratil (INEEL); H. B. Eldredge (U of Idaho)

1999-03-01T23:59:59.000Z

276

SECONDARY WASTE/ETF (EFFLUENT TREATMENT FACILITY) PRELIMINARY PRE-CONCEPTUAL ENGINEERING STUDY  

Science Conference Proceedings (OSTI)

This pre-conceptual engineering study is intended to assist in supporting the critical decision (CD) 0 milestone by providing a basis for the justification of mission need (JMN) for the handling and disposal of liquid effluents. The ETF baseline strategy, to accommodate (WTP) requirements, calls for a solidification treatment unit (STU) to be added to the ETF to provide the needed additional processing capability. This STU is to process the ETF evaporator concentrate into a cement-based waste form. The cementitious waste will be cast into blocks for curing, storage, and disposal. Tis pre-conceptual engineering study explores this baseline strategy, in addition to other potential alternatives, for meeting the ETF future mission needs. Within each reviewed case study, a technical and facility description is outlined, along with a preliminary cost analysis and the associated risks and benefits.

MAY TH; GEHNER PD; STEGEN GARY; HYMAS JAY; PAJUNEN AL; SEXTON RICH; RAMSEY AMY

2009-12-28T23:59:59.000Z

277

Remote handling equipment at the hanford waste treatment plant  

Science Conference Proceedings (OSTI)

Cold war plutonium production led to extensive amounts of radioactive waste stored in tanks at the Department of Energy's Hanford Waste Treatment Plant. The storage tanks could potentially leak into the ground water and into the Columbia River. The solution for this risk of the leaking waste is vitrification. Vitrification is a process of mixing molten glass with radioactive waste to form a stable condition for storage. The Department of Energy has contracted Bechtel National, Inc. to build facilities at the Hanford site to process the waste. The waste will be separated into high and low level waste. Four major systems will process the waste, two pretreatment and two high level. Due to the high radiation levels, high integrity custom cranes have been designed to remotely maintain the hot cells. Several critical design parameters were implemented into the remote machinery design, including radiation limitations, remote operations, Important to Safety features, overall equipment effectiveness, minimum wall approaches, seismic constraints, and recovery requirements. Several key pieces of equipment were designed to meet these design requirements - high integrity crane bridges, trolleys, main hoists, mast hoists, slewing hoists, a monorail hoist, and telescoping mast deployed tele-robotic manipulator arms. There were unique and challenging design features and equipment needed to provide the remotely operated high integrity crane/manipulator systems for the Hanford Waste Treatment Plant. The cranes consist of a double girder bridge with various main hoist capacities ranging from one to thirty ton and are used for performing routine maintenance. A telescoping mast mounted tele-robotic manipulator arm with a one-ton hook is deployed from the trolley to perform miscellaneous operations in-cell. A dual two-ton slewing jib hoist is mounted to the bottom of the trolley and rotates 360 degrees around the mast allowing the closest hook wall approaches. Each of the two hoists on this slewer is mounted 180 degrees opposite each other. Another system utilizes a single one-ton slewing jib hoist that can extend and retract as well as rotate 270 degrees around the mast. Yet, another system utilizes an under-hung monorail trolley with one-ton hoist capacity mounted to the bottom of the bridge girder. The main, slewer and monorail hoists each have power-rotating hooks for installing and removing equipment in the hot cell. (authors)

Bardal, M.A. [PaR Systems, Inc., Shoreview, MN, (United States); Roach, J.D. [Bechtel National, Inc., Richland, WA (United States)

2007-07-01T23:59:59.000Z

278

Treatment technology analysis for mixed waste containers and debris  

SciTech Connect

A team was assembled to develop technology needs and strategies for treatment of mixed waste debris and empty containers in the Department of Energy (DOE) complex, and to determine the advantages and disadvantages of applying the Debris and Empty Container Rules to these wastes. These rules issued by the Environmental Protection Agency (EPA) apply only to the hazardous component of mixed debris. Hazardous debris that is subjected to regulations under the Atomic Energy Act because of its radioactivity (i.e., mixed debris) is also subject to the debris treatment standards. The issue of treating debris per the Resource Conservation and Recovery Act (RCRA) at the same time or in conjunction with decontamination of the radioactive contamination was also addressed. Resolution of this issue requires policy development by DOE Headquarters of de minimis concentrations for radioactivity and release of material to Subtitle D landfills or into the commercial sector. The task team recommends that, since alternate treatment technologies (for the hazardous component) are Best Demonstrated Available Technology (BDAT): (1) funding should focus on demonstration, testing, and evaluation of BDAT on mixed debris, (2) funding should also consider verification of alternative treatments for the decontamination of radioactive debris, and (3) DOE should establish criteria for the recycle/reuse or disposal of treated and decontaminated mixed debris as municipal waste.

Gehrke, R.J. [Idaho National Engineering Lab., Idaho Falls, ID (United States); Brown, C.H. [Oak Ridge National Lab., TN (United States); Langton, C.A.; Askew, N.M. [Savannah River Lab., Aiken, SC (United States); Kan, T. [Lawrence Livermore National Lab., CA (United States); Schwinkendorf, W.E. [BDM Federal, Inc., Albuquerque, NM (United States)

1994-03-01T23:59:59.000Z

279

Overview of non-thermal mixed waste treatment technologies: Treatment of mixed waste (ex situ); Technologies and short descriptions  

SciTech Connect

This compendium contains brief summaries of new and developing non- thermal treatment technologies that are candidates for treating hazardous or mixed (hazardous plus low-level radioactive) wastes. It is written to be all-encompassing, sometimes including concepts that presently constitute little more than informed ``ideas``. It bounds the universe of existing technologies being thought about or considered for application on the treatment of such wastes. This compendium is intended to be the very first step in a winnowing process to identify non-thermal treatment systems that can be fashioned into complete ``cradle-to-grave`` systems for study. The purpose of the subsequent systems paper studies is to investigate the cost and likely performance of such systems treating a representative sample of U.S. Department of Energy (DOE) mixed low level wastes (MLLW). The studies are called Integrated Non-thermal Treatment Systems (INTS) Studies and are being conducted by the Office of Science and Technology (OST) of the Environmental Management (EM) of the US Department of Energy. Similar studies on Integrated Thermal Treatment Systems have recently been published. These are not designed nor intended to be a ``downselection`` of such technologies; rather, they are simply a systems evaluation of the likely costs and performance of various non- thermal technologies that have been arranged into systems to treat sludges, organics, metals, soils, and debris prevalent in MLLW.

NONE

1995-07-01T23:59:59.000Z

280

Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology  

DOE Green Energy (OSTI)

This report investigated the potential of using municipal solid waste (MSW) to make synthesis gas (syngas) suitable for production of liquid fuels. Issues examined include: • MSW physical and chemical properties affecting its suitability as a gasifier feedstock and for liquid fuels synthesis • expected process scale required for favorable economics • the availability of MSW in quantities sufficient to meet process scale requirements • the state-of-the-art of MSW gasification technology.

Valkenburg, Corinne; Walton, Christie W.; Thompson, Becky L.; Gerber, Mark A.; Jones, Susanne B.; Stevens, Don J.

2008-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

MEASUREMENTS TAKEN IN SUPPORT OF QUALIFICATION OF PROCESSING SAVANNAH RIVER SITE LOW-LEVEL LIQUID WASTE INTO SALTSTONE  

Science Conference Proceedings (OSTI)

The Saltstone Facility at the Savannah River Site (SRS) immobilizes low-level liquid waste into Saltstone to be disposed of in the Z-Area Saltstone Disposal Facility, Class Three Landfill. In order to meet the permit conditions and regulatory limits set by the South Carolina Department of Health and Environmental Control (SCDHEC), the Resource Conservation and Recovery Act (RCRA) and the Environmental Protection Agency (EPA), both the low-level salt solution and Saltstone samples are analyzed quarterly. Waste acceptance criteria (WAC) are designed to confirm the salt solution sample from the Tank Farm meets specific radioactive and chemical limits. The toxic characteristic leaching procedure (TCLP) is used to confirm that the treatment has immobilized the hazardous constituents of the salt solution. This paper discusses the methods used to characterize the salt solution and final Saltstone samples from 2007-2009.

Reigel, M.; Bibler, N.; Diprete, C.; Cozzi, A.; Staub, A.; Ray, J.

2010-01-27T23:59:59.000Z

282

APPLICATION OF A THIN FILM EVAPORATOR SYSTEM FOR MANAGEMENT OF LIQUID HIGH-LEVEL WASTES AT HANFORD  

Science Conference Proceedings (OSTI)

A modular, transportable evaporator system, using thin film evaporative technology, is planned for deployment at the Hanford radioactive waste storage tank complex. This technology, herein referred to as a wiped film evaporator (WFE), will be located at grade level above an underground storage tank to receive pumped liquids, concentrate the liquid stream from 1.1 specific gravity to approximately 1.4 and then return the concentrated solution back into the tank. Water is removed by evaporation at an internal heated drum surface exposed to high vacuum. The condensed water stream will be shipped to the site effluent treatment facility for final disposal. This operation provides significant risk mitigation to failure of the aging 242-A Evaporator facility; the only operating evaporative system at Hanford maximizing waste storage. This technology is being implemented through a development and deployment project by the tank farm operating contractor, Washington River Protection Solutions (WRPS), for the Office of River Protection/Department of Energy (ORP/DOE), through Columbia Energy & Environmental Services, Inc. (Columbia Energy). The project will finalize technology maturity and install a system at one of the double-shell tank farms. This paper discusses results of pre-project pilot-scale testing by Columbia Energy and ongoing technology maturation development scope through fiscal year 2012, including planned additional pilot-scale and full-scale simulant testing and operation with actual radioactive tank waste.

TEDESCHI AR; WILSON RA

2010-01-14T23:59:59.000Z

283

Hanford Waste Treatment Plant Sets Massive Protective Shield door in  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment Plant Sets Massive Protective Shield door Waste Treatment Plant Sets Massive Protective Shield door in Pretreatment Facility Hanford Waste Treatment Plant Sets Massive Protective Shield door in Pretreatment Facility January 12, 2011 - 12:00pm Addthis The carbon steel doors come together to form an upside-down L-shape. The 102-ton door was set on top of the 85-ton door that was installed at the end of December. The carbon steel doors come together to form an upside-down L-shape. The 102-ton door was set on top of the 85-ton door that was installed at the end of December. The 102-ton shield door measures 52 feet wide and 15 feet tall The 102-ton shield door measures 52 feet wide and 15 feet tall The carbon steel doors come together to form an upside-down L-shape. The 102-ton door was set on top of the 85-ton door that was installed at the end of December.

284

Hazardous Waste/Mixed Waste Treatment Building Safety Information Document (SID)  

SciTech Connect

This Safety Information Document (SID) provides a description and analysis of operations for the Hazardous Waste/Mixed Waste Disposal Facility Treatment Building (the Treatment Building). The Treatment Building has been classified as a moderate hazard facility, and the level of analysis performed and the methodology used are based on that classification. Preliminary design of the Treatment Building has identified the need for two separate buildings for waste treatment processes. The term Treatment Building applies to all these facilities. The evaluation of safety for the Treatment Building is accomplished in part by the identification of hazards associated with the facility and the analysis of the facility`s response to postulated events involving those hazards. The events are analyzed in terms of the facility features that minimize the causes of such events, the quantitative determination of the consequences, and the ability of the facility to cope with each event should it occur. The SID presents the methodology, assumptions, and results of the systematic evaluation of hazards associated with operation of the Treatment Building. The SID also addresses the spectrum of postulated credible events, involving those hazards, that could occur. Facility features important to safety are identified and discussed in the SID. The SID identifies hazards and reports the analysis of the spectrum of credible postulated events that can result in the following consequences: Personnel exposure to radiation; Radioactive material release to the environment; Personnel exposure to hazardous chemicals; Hazardous chemical release to the environment; Events leading to an onsite/offsite fatality; and Significant damage to government property. The SID addresses the consequences to the onsite and offsite populations resulting from postulated credible events and the safety features in place to control and mitigate the consequences.

Fatell, L.B.; Woolsey, G.B.

1993-04-15T23:59:59.000Z

285

THE ROLE OF LIQUID WASTE PRETREATMENT TECHNOLOGIES IN SOLVING THE DOE CLEAN-UP MISSION  

Science Conference Proceedings (OSTI)

The objective of this report is to describe the pretreatment solutions that allow treatment to be tailored to specific wastes, processing ahead of the completion schedules for the main treatment facilities, and reduction of technical risks associated with future processing schedules. Wastes stored at Hanford and Savannah River offer challenging scientific and engineering tasks. At both sites, space limitations confound the ability to effectively retrieve and treat the wastes. Additionally, the radiation dose to the worker operating and maintaining the radiochemical plants has a large role in establishing the desired radioactivity removal. However, the regulatory requirements to treat supernatant and saltcake tank wastes differ at the two sites. Hanford must treat and remove radioactivity from the tanks based on the TriParty Agreement and Waste Incidental to Reprocessing (WIR) documentation. These authorizing documents do not specify treatment technologies; rather, they specify endstate conditions. Dissimilarly, Waste Determinations prepared at SRS in accordance with Section 3116 of the 2005 National Defense Authorization Act along with state operating permits establish the methodology and amounts of radioactivity that must be removed and may be disposed of in South Carolina. After removal of entrained solids and site-specific radionuclides, supernatant and saltcake wastes are considered to be low activity waste (LAW) and are immobilized in glass and disposed of at the Hanford Site Integrated Disposal Facility (IDF) or formulated into a grout for disposal at the Savannah River Site Saltstone Disposal Facility. Wastes stored at the Hanford Site or SRS comprise saltcake, supernate, and sludges. The supernatant and saltcake waste fractions contain primarily sodium salts, metals (e.g., Al, Cr), cesium-137 (Cs-137), technetium-99 (Tc-99) and entrained solids containing radionuclides such as strontium-90 (Sr-90) and transuranic elements. The sludges contain many of the transition metal hydroxides that precipitate when the spent acidic process solutions are rendered alkaline with sodium hydroxide. The sludges contain Sr-90 and transuranic elements. The wastes stored at each site have been generated and stored for over fifty years. Although the majority of the wastes were generated to support nuclear weapons production and reprocessing, the wastes differ substantially between the sites. Table 5 shows the volumes and total radioactivity (including decay daughters) of the waste phases stored in tanks at each site. At Hanford, there are 177 tanks that contain 56.5 Mgal of waste. SRS has 51 larger tanks, of which 2 are closed, that contain 36.5 Mgal. Mainly due to recovery operations, the waste stored at Hanford has less total curies than that stored at Savannah River. The total radioactivity of the Hanford wastes contains approximately 190 MCi, and the total radioactivity of the Savannah River wastes contains 400 MCi.

Wilmarth, B; Sheryl Bush, S

2008-10-31T23:59:59.000Z

286

Groundwater impact assessment report for the 1325-N Liquid Waste Disposal Facility  

Science Conference Proceedings (OSTI)

In 1943 the Hanford Site was chosen as a location for the Manhattan Project to produce plutonium for use in nuclear weapons. The 100-N Area at Hanford was used from 1963 to 1987 for a dual-purpose, plutonium production and steam generation reactor and related operational support facilities (Diediker and Hall 1987). In November 1989, the reactor was put into dry layup status. During operations, chemical and radioactive wastes were released into the area soil, air, and groundwater. The 1325-N LWDF was constructed in 1983 to replace the 1301-N Liquid Waste Disposal Facility (1301-N LWDF). The two facilities operated simultaneously from 1983 to 1985. The 1301-N LWDF was retired from use in 1985 and the 1325-N LWDF continued operation until April 1991, when active discharges to the facility ceased. Effluent discharge to the piping system has been controlled by administrative means. This report discusses ground water contamination resulting from the 1325-N Liquid Waste Disposal facility.

Alexander, D.J.; Johnson, V.G.

1993-09-01T23:59:59.000Z

287

Treatment of Organic-Contaminated Mixed Waste Utilizing the Oak Ridge Broad Spectrum Contracts  

SciTech Connect

To meet the requirements of the State of Tennessee's Department of Environment and Conservation Commissioner's Order for treatment of mixed low level wastes, Oak Ridge has utilized commercial treatment companies to treat and dispose mixed waste. Over the past year, Oak Ridge has shipped organic-contaminated mixed waste for treatment to meet milestones under the Site Treatment Plan. Oak Ridge has established contracts with commercial treatment companies accessible by all DOE sites for treatment of a wide range of mixed wastes. The paper will describe and summarize the activities involved in treating and disposing of organic-contaminated mixed waste utilizing DOE complex-wide contracts and the treatment and disposal activities required. This paper will describe the case history of treatment of several organic-contaminated mixed wastes from the Oak Ridge Reservation requiring treatment prior to disposal. The paper will include waste category information, implementation activities, and contract access. The paper will discuss the specifics of the mixed waste treatment including waste characteristics, treatment process and equipment utilized, and treatment results. Additional information will be provided on task order development, waste profiling, treatment pricing, and the disposal process.

Estes, C. H.; Heacker, F. K.; Cunningham, J.; Westich, B.

2003-02-25T23:59:59.000Z

288

Ionic Liquids for Utilization of Waste Heat from Distributed Power Generation Systems  

Science Conference Proceedings (OSTI)

The objective of this research project was the development of ionic liquids to capture and utilize waste heat from distributed power generation systems. Ionic Liquids (ILs) are organic salts that are liquid at room temperature and they have the potential to make fundamental and far-reaching changes in the way we use energy. In particular, the focus of this project was fundamental research on the potential use of IL/CO2 mixtures in absorption-refrigeration systems. Such systems can provide cooling by utilizing waste heat from various sources, including distributed power generation. The basic objectives of the research were to design and synthesize ILs appropriate for the task, to measure and model thermophysical properties and phase behavior of ILs and IL/CO2 mixtures, and to model the performance of IL/CO2 absorption-refrigeration systems.

Joan F. Brennecke; Mihir Sen; Edward J. Maginn; Samuel Paolucci; Mark A. Stadtherr; Peter T. Disser; Mike Zdyb

2009-01-11T23:59:59.000Z

289

Secondary Waste Forms and Technetium Management  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

November 18, 2010 What are Secondary Wastes? Process condensates and scrubber andor off-gas treatment liquids from the pretreatment and ILAW melter facilities at the Hanford WTP....

290

HIGH ALUMINUM HLW (HIGH LEVEL WASTE ) GLASSES FOR HANFORDS WTP (WASTE TREATMENT PROJECT)  

Science Conference Proceedings (OSTI)

This paper presents the results of glass formulation development and melter testing to identify high waste loading glasses to treat high-Al high level waste (HLW) at Hanford. Previous glass formulations developed for this HLW had high waste loadings but their processing rates were lower that desired. The present work was aimed at improving the glass processing rate while maintaining high waste loadings. Glass formulations were designed, prepared at crucible-scale and characterized to determine their properties relevant to processing and product quality. Glass formulations that met these requirements were screened for melt rates using small-scale tests. The small-scale melt rate screening included vertical gradient furnace (VGF) and direct feed consumption (DFC) melter tests. Based on the results of these tests, modified glass formulations were developed and selected for larger scale melter tests to determine their processing rate. Melter tests were conducted on the DuraMelter 100 (DMIOO) with a melt surface area of 0.11 m{sup 2} and the DuraMelter 1200 (DMI200) HLW Pilot Melter with a melt surface area of 1.2 m{sup 2}. The newly developed glass formulations had waste loadings as high as 50 wt%, with corresponding Al{sub 2}O{sub 3} concentration in the glass of 26.63 wt%. The new glass formulations showed glass production rates as high as 1900 kg/(m{sup 2}.day) under nominal melter operating conditions. The demonstrated glass production rates are much higher than the current requirement of 800 kg/(m{sup 2}.day) and anticipated future enhanced Hanford Tank Waste Treatment and Immobilization Plant (WTP) requirement of 1000 kg/(m{sup 2}.day).

KRUGER AA; BOWAN BW; JOSEPH I; GAN H; KOT WK; MATLACK KS; PEGG IL

2010-01-04T23:59:59.000Z

291

Recycle of the treated effluent from the Liquid Effluent Treatment Facility: Engineering study  

SciTech Connect

During normal N Reactor operation there will be low-level radioactive liquid effluent flows discharged to the planned Liquid Effluent Treatment Facility (LETF). The LETF will filter and treat these flows to decrease the radioactive prior to discharging the effluent to the Liquid Waste Disposal Facility (LWDF) soil column. This report examines the feasibility and economics of recycling the treated effluent to the N Reactor for reuse thus eliminating or reducing discharges to the soil. The study concluded that recycling LETF effluent for reuse in the primary coolant system and in the fuel storage basin is technically feasible. However, the high cost to provide recycle water meeting the minimum N reactor chemical requirements and radiological concerns may not be justified due to the limited reactor operating life. The study concluded that inexpensive piping modifications to the Building 107N recirculation system would provide additional flow to alleviate the fuel basin clarity problem during refueling. This change would avoid the disposal of 62.2 million gal of treated water per year to the soil column. 21 refs., 5 figs., 7 tabs.

Shearer, E.A.; Janke, D.S.

1988-04-01T23:59:59.000Z

292

External Technical Review for Evaluation of System Level Modeling and Simulation Tools in Support of Hanford Site Liquid Waste Process  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Site Liquid Waste Process Hanford Site Liquid Waste Process September 2009 Monica C. Regalbuto Office of Waste Processing DOE/EM Kevin G. Brown Vanderbilt University and CRESP David W. DePaoli Oak Ridge National Laboratory Candido Pereira Argonne National Laboratory John R. Shultz Office of Waste Processing DOE/EM External Technical Review for Evaluation of System Level Modeling and Simulation Tools in Support of Hanford Site Liquid Waste Process September 2009 Acknowledgements The Review Team thanks Mr. Glyn Trenchard, Team Lead for Planning and Coordination Waste Disposition Project, U.S. Department of Energy--Office of River Protection, Mr. Paul Rutland, RPP System Planning Manager for Washington River Protection Solutions, and Mr. Ernie Lee,

293

Process for Removing Radioactive Wastes from Liquid Streams  

SciTech Connect

The process is under development at Mound Laboratory to remove radioactive waste (principally plutonium-238) from process water prior to discharge of the water to the Miami river. The contaminated water, as normally received, is at a pH between 6 and 90. Under these conditions, plutonium in all its oxidation states is hydrolyzed; however, the level of the radioactive solids varies from about 50ppm down to about 50 ppb and the plutonium remains in a colloidal or subcolloidal condition. The permissible concentration for discharge to the river is about 50 parts per trillion. Pilot plant test show that 95-99% of the radioactive material is removed by adsorption on diatomaceous earth. The remainder is removed by passage through a bed of either dibasic or tribasic calcium phosphate. Ground phosphate rock is equally effective in removing the radioactive material if the flow rate is controlled to permit sufficient contact time. Parameters for optimizing the process are now under study. Future plans include application of the process to wastes from reactor fuels reprocessing.

Kirby, H. W.; Blane, D. E.; Smolin, R. I.

1972-10-01T23:59:59.000Z

294

Sodium-bearing Waste Treatment Technology Evaluation Report  

SciTech Connect

Sodium-bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL has been working over the past several years to identify a treatment technology that meets NE-ID and regulatory treatment requirements, including consideration of stakeholder input. Many studies, including the High-Level Waste and Facilities Disposition Environmental Impact Statement (EIS), have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. This report presents a summary of the applied technology and process design activities performed through February 2004. The SBW issue and the five alternatives are described in Sections 2 and 3, respectively. Details of preliminary process design activities for three of the alternatives (steam reforming, CsIX, and direct evaporation) are presented in three appendices. A recent feasibility study provides the details for calcination. There have been no recent activities performed with regard to vitrification; that section summarizes and references previous work.

Charles M. Barnes; Arlin L. Olson; Dean D. Taylor

2004-05-01T23:59:59.000Z

295

Summary - Savannah River Site Tank 48H Waste Treatment Project  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

S S Wet Air Savan contain liquid w contain potent to the option tank w Bed S condu be pur The as Techn Techn as liste * W o o The Ele Site: S roject: S P Report Date: J ited States Savanna Why DOE r Oxidation Proc nnah River Tan ning approxima waste. The wa ns tetraphenylb tially flammable tank head spa s have been id waste: Wet Air O team Reformin cted to aid in d rsued for treatin What th ssessment team ology Element ology Readine ed below: Wet Air Oxidatio Reactor sys Offgas Trea To view the full T http://www.em.doe. objective of a Tech ements (CTEs), usin Savannah Rive SRS Tank 48H Project July 2007 Departmen ah River E-EM Did This cess k 48H is a 1.3 ately 250, 000 aste is a salt so borate (TPB), w e concentration ce. Two poten dentified for this Oxidation (WAO ng (FBSR). Th deciding which ng the Tank 48

296

Techniques and Facilities for Handling and Packaging Tritiated Liquid Wastes for Burial  

SciTech Connect

Methods and facilities have been developed for the collection, storage, measurement, assay, solidification, and packaging of tritiated liquid wastes (concentrations up to 5 Ci/ml) for disposal by land burial. Tritium losses to the environment from these operations are less than 1 ppm. All operations are performed in an inert gas-purged glovebox system vented to an effluent removal system which permits nearly complete removal of tritium from the exhaust gases prior to their dischardge to the environment. Waste oil and water from tritium processing areas are vacuum-transferred to glovebox storage tanks through double-walled lines. Accommodations are also available for emptying portable liquid waste containers and for removing tritiated water from molecular sieve beds with heat and vacuum. The tritium concentration of the collected liquids is measured by an in-line calorimeter. A low-volume metering pump is used to transfer liquids from holding tanks to heavy walled polyethylene drums filled with an absorbent or cement for solidification. Final packaging of the sealed polyethylene drums is in either an asphalt-filled combination 30- and 55- gallon metal drum package or a 30-gallon welded stainless steel container.

Rhinehammer, T. B.; Mershad, E. A.

1974-06-01T23:59:59.000Z

297

Assessment of incineration and melting treatment technologies for RWMC buried waste  

SciTech Connect

This report provides an identification, description, and ranking evaluation of the available thermal treatment technologies potentially capable of treating the Idaho National Engineering Laboratory Radioactive Waste Management Complex (RWMC) buried mixed waste. The ranking evaluation focused separately upon incinerators for treatment of combustible wastes and melters for noncombustible wastes. The highest rank incinerators are rotary kilns and controlled air furnaces, while the highest rank melters are the hearth configuration plasma torch, graphite electrode arc, and joule-heated melters. 4 refs.

Geimer, R.; Hertzler, T.; Gillins, R. (Science Applications International Corp., Idaho Falls, ID (United States)); Anderson, G.L. (EG and G Idaho, Inc., Idaho Falls, ID (United States))

1992-02-01T23:59:59.000Z

298

Waste treatment: Beverage industry. (Latest citations from Food Science & Technology Abstracts (FSTA)). Published Search  

SciTech Connect

The bibliography contains citations concerning waste treatment in the alcoholic and non-alcoholic beverage industries. Brewery effluent and wastewater management and disposal are reviewed. References cover aerobic treatment, sources of effluents, waste reduction, waste fermentation, effluent purification, and cost-effectiveness evaluation. The use of wastes for biogas production and for building material manufacture is examined. (Contains 50-250 citations and includes a subject term index and title list.)

NONE

1995-08-01T23:59:59.000Z

299

Microsoft PowerPoint - S05-07_Varona_Solid-Liquid Waste Interface.pptx  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Interface Monitor Liquid Interface Monitor (SLIM) Jose Varona D. Roelant, A. Awwad, D. McDaniel Florida International University's Applied Research Center EM Waste Processing Technical Exchange November 17, 2010 Print Close Disclaimer This presentation was prepared as an account of work sponsored by an agency of the United States government (Department of Energy, Office of Environmental Management, under Grant No. DE-FG01-05EW07033). Neither the United States government nor any agency thereof, nor any of their employees, nor any of its contractors, subcontractors, nor their employees makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness,

300

Drop Dynamics and Speciation in Isolation of Metals from Liquid Wastes by Reactive Scavenging  

SciTech Connect

Computational and experimental studies of the motion and dynamics of liquid drops in gas flows were conducted with relevance to reactive scavenging of metals from atomized liquid waste. Navier-Stoke's computations of deformable drops revealed a range of conditions from which prolate drops are expected, and showed how frajectiones of deformable drops undergoing deceleration can be computed. Experimental work focused on development of emission fluorescence, and scattering diagnostics. The instrument developed was used to image drop shapes, soot, and nonaxisymmetric departures from steady flow in a 22kw combustor

Arne J. Pearlstein; Alexander Scheeline

2002-08-30T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Demonstration of the TRUEX process for the treatment of actual high activity tank waste at the INEEL using centrifugal contactors  

SciTech Connect

The Idaho Chemical Processing Plant (ICPP), located at the Idaho National Engineering and Environmental Laboratory (INEEL), formerly reprocessed spent nuclear fuel to recover fissionable uranium. The radioactive raffinates from the solvent extraction uranium recovery processes were converted to granular solids (calcine) in a high temperature fluidized bed. A secondary liquid waste stream was generated during the course of reprocessing, primarily from equipment decontamination between campaigns and solvent wash activities. This acidic tank waste cannot be directly calcined due to the high sodium content and has historically been blended with reprocessing raffinates or non-radioactive aluminum nitrate prior to calcination. Fuel reprocessing activities are no longer being performed at the ICPP, thereby eliminating the option of waste blending to deplete the waste inventory. Currently, approximately 5.7 million liters of high-activity waste are temporarily stored at the ICPP in large underground stainless-steel tanks. The United States Environmental Protection Agency and the Idaho Department of Health and Welfare filed a Notice of Noncompliance in 1992 contending some of the underground waste storage tanks do not meet secondary containment. As part of a 1995 agreement between the State of Idaho, the Department of Energy, and the Department of Navy, the waste must be removed from the tanks by 2012. Treatment of the tank waste inventories by partitioning the radionuclides and immobilizing the resulting high-activity and low-activity waste streams is currently under evaluation. A recent peer review identified the most promising radionuclide separation technologies for evaluation. The Transuranic Extraction-(TRUEX) process was identified as a primary candidate for separation of the actinides from ICPP tank waste.

Law, J.D.; Brewer, K.N.; Todd, T.A.; Olson, L.G.

1997-10-01T23:59:59.000Z

302

Successful Waste Treatment Methods at Sandia National Laboratories  

SciTech Connect

During the remediation of the waste landfills at Sandia National Laboratory in Albuquerque, New Mexico nine drums of mock high explosives were generated. This mixed waste stream was proposed to several offsite vendors for treatment and prices ranged from $2.50 to $10 per gram a total cost estimated to be in excess of $2 million dollars. This cost represents more than 30 percent of the annual budget for the Sandia Waste Management Operations. Concentrated solutions of common oxidizers, such as nitrates, nitrites, and peroxides, will also act as oxidizers and will give positive results in the Hazard Categorization oxidizer test. These solutions carry an EPA Hazardous Waste Number D001, Ignitable Waste, and Oxidizer as defined in 49 CFR 173.151. Sandia decided that given budget and time constraints to meet a Federal Facilities Compliance Act milestone, a process for onsite treatment should be evaluated. Clean samples of mock high explosive materials were obtained from Pantex excess inventory and treatability studies initiated to develop a treatment formula and process. The following process was developed and implemented in the summer of 2006: - Size reduction to allow for dissolution of the barium nitrate in water; - Dissolution of the Mock HE in water; - Deactivation of the oxidizer; - Stabilization of the barium and the cadmium contamination present as an underlying hazardous constituent. This project was completed and the treatment milestone achieved for less than $300,000. The Disassembly Sanitization Operation (DSO) is a process that was implemented to support weapon disassembly and disposition using recycling and waste minimization while achieving the demilitarization mission. The Department of Energy is faced with disassembling and disposition of a huge inventory of retired weapons, components, training equipment, spare parts, and weapon maintenance equipment. Environmental regulations have caused a dramatic increase for information needed to support the disposal and handling of these parts and materials. Manufacturing information from past decades often does not meet the needs for regulatory decisions of today to assure proper management of weapons components. Huge inventories of classified weapon components were required to have long-term storage at Sandia and many other locations throughout the complex. These materials are stored because they are classified, they may also contain radiological and/or hazardous components and disposal options may not have existed for this material. Long-term storage is costly and somewhat problematic. It requires a secured storage area, monitoring, auditing and it also has the potential for loss or theft of this material. Overall recycling rates for materials sent through the DSO process have enabled 70 to 80% of these components to be recycled. These components are made to extreme standards and are made of high quality materials. Once the material has been sanitized, the demand for these metals is very high. The DSO process for the NGPF classified components established the credibility of this technique as a viable process for addressing the long-term storage requirements of classified weapons component inventory. The success of this operation has generated interest from other Sandia Organization other locations throughout the complex. Other organizations are soliciting the help of the DSO team and the DSO is responding to these solicitations by expanding its scope to include work for other projects. For example, Pantex has asked the DSO team to assist with the destruction of their classified components. The operation is full scale and continues to grow and serve SNL/NM and DoE by providing a solution to this evolving issue. On an ongoing basis, SNL has been incurring expenses for the management and storage of classified components. It is estimated that this project will save the DoE and Sandia several hundreds of thousands of dollars until the excess inventory is eliminated. This innovative approach eliminates the need for long-term storage of classified weapons components and the

Rast, D.M.; Thompson, J.J.; Cooper, T.W.; Stockham, D.J

2007-07-01T23:59:59.000Z

303

Croatian refiner meets waste water treatment standards, reduces fines  

Science Conference Proceedings (OSTI)

A new approach to waste water treatment at a refinery in Croatia produces effluent that not only meets the region`s regulations for disposal into the Adriatic Sea, but also surpasses the refinery`s specifications for recycling process water. Key to the dramatic reduction in pollutants was the installation of a Sandfloat unit developed by Krofta Engineering Corp. The Sandfloat unit is a dissolved air flotation clarifier that combines flocculation, flotation, and multilayer filtration to produce high-quality effluent. In fact, the effluent from the unit has a lower hydrocarbon concentration than water from the underground wells that supply process water to the refinery. While similar systems have been used for decades in industrial applications, this is the first time a Sandfloat unit has been installed in an oil refinery. The article describes the problem, refinery operations, treatment costs, and effluent recycling.

Meier, A.L. [Krofta Engineering Corp., Lenox, MA (United States); Nikolic, O. [INA Oil Refinery, Rijeka (Croatia)

1995-11-27T23:59:59.000Z

304

Integrated Waste Treatment Unit GFSI Risk Management Plan  

SciTech Connect

This GFSI Risk Management Plan (RMP) describes the strategy for assessing and managing project risks for the Integrated Waste Treatment Unit (IWTU) that are specifically within the control and purview of the U.S. Department of Energy (DOE), and identifies the risks that formed the basis for the DOE contingency included in the performance baseline. DOE-held contingency is required to cover cost and schedule impacts of DOE activities. Prior to approval of the performance baseline (Critical Decision-2) project cost contingency was evaluated during a joint meeting of the Contractor Management Team and the Integrated Project Team for both contractor and DOE risks to schedule and cost. At that time, the contractor cost and schedule risk value was $41.3M and the DOE cost and schedule risk contingency value is $39.0M. The contractor cost and schedule risk value of $41.3M was retained in the performance baseline as the contractor's management reserve for risk contingency. The DOE cost and schedule risk value of $39.0M has been retained in the performance baseline as the DOE Contingency. The performance baseline for the project was approved in December 2006 (Garman 2006). The project will continue to manage to the performance baseline and change control thresholds identified in PLN-1963, ''Idaho Cleanup Project Sodium-Bearing Waste Treatment Project Execution Plan'' (PEP).

W. A. Owca

2007-06-21T23:59:59.000Z

305

Integrated Waste Treatment Unit GFSI Risk Management Plan  

SciTech Connect

This GFSI Risk Management Plan (RMP) describes the strategy for assessing and managing project risks for the Integrated Waste Treatment Unit (IWTU) that are specifically within the control and purview of the U.S. Department of Energy (DOE), and identifies the risks that formed the basis for the DOE contingency included in the performance baseline. DOE-held contingency is required to cover cost and schedule impacts of DOE activities. Prior to approval of the performance baseline (Critical Decision-2) project cost contingency was evaluated during a joint meeting of the Contractor Management Team and the Integrated Project Team for both contractor and DOE risks to schedule and cost. At that time, the contractor cost and schedule risk value was $41.3M and the DOE cost and schedule risk contingency value is $39.0M. The contractor cost and schedule risk value of $41.3M was retained in the performance baseline as the contractor's management reserve for risk contingency. The DOE cost and schedule risk value of $39.0M has been retained in the performance baseline as the DOE Contingency. The performance baseline for the project was approved in December 2006 (Garman 2006). The project will continue to manage to the performance baseline and change control thresholds identified in PLN-1963, ''Idaho Cleanup Project Sodium-Bearing Waste Treatment Project Execution Plan'' (PEP).

W. A. Owca

2007-06-21T23:59:59.000Z

306

Advanced Off-Gas Control System Design For Radioactive And Mixed Waste Treatment  

SciTech Connect

Treatment of radioactive and mixed wastes is often required to destroy or immobilize hazardous constituents, reduce waste volume, and convert the waste to a form suitable for final disposal. These kinds of treatments usually evolve off-gas. Air emission regulations have become increasingly stringent in recent years. Mixed waste thermal treatment in the United States is now generally regulated under the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. These standards impose unprecedented requirements for operation, monitoring and control, and emissions control. Off-gas control technologies and system designs that were satisfactorily proven in mixed waste operation prior to the implementation of new regulatory standards are in some cases no longer suitable in new mixed waste treatment system designs. Some mixed waste treatment facilities have been shut down rather than have excessively restrictive feed rate limits or facility upgrades to comply with the new standards. New mixed waste treatment facilities in the U. S. are being designed to operate in compliance with the HWC MACT standards. Activities have been underway for the past 10 years at the INL and elsewhere to identify, develop, demonstrate, and design technologies for enabling HWC MACT compliance for mixed waste treatment facilities. Some specific off-gas control technologies and system designs have been identified and tested to show that even the stringent HWC MACT standards can be met, while minimizing treatment facility size and cost.

Nick Soelberg

2005-09-01T23:59:59.000Z

307

Hanford Waste Simulants Created to Support the Research and Development on the River Protection Project - Waste Treatment Plant  

Science Conference Proceedings (OSTI)

The development of nonradioactive waste simulants to support the River Protection Project - Waste Treatment Plant bench and pilot-scale testing is crucial to the design of the facility. The report documents the simulants development to support the SRTC programs and the strategies used to produce the simulants.

Eibling, R.E.

2001-07-26T23:59:59.000Z

308

DuraLith Alkali-Aluminosilicate Geopolymer Waste Form Testing for Hanford Secondary Waste  

SciTech Connect

The primary objective of the work reported here was to develop additional information regarding the DuraLith alkali aluminosilicate geopolymer as a waste form for liquid secondary waste to support selection of a final waste form for the Hanford Tank Waste Treatment and Immobilization Plant secondary liquid wastes to be disposed in the Integrated Disposal Facility on the Hanford Site. Testing focused on optimizing waste loading, improving waste form performance, and evaluating the robustness of the waste form with respect to waste variability.

Gong, W. L.; Lutz, Werner; Pegg, Ian L.

2011-07-21T23:59:59.000Z

309

Hanford ETR - Tank Waste Treatment and Immobilization Plant - Hanford Tank Waste Treatment and Immobilization Plant Technical Review - Estimate at Completion (Cost) Report  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Comprehensive Review of the Hanford Tank Waste Treatment and Immobilization Plant Estimate at Completion Assessment Conducted by an Independent Team of External Experts March 2006 Comprehensive Review of the Hanford Waste Treatment Plant Estimate at Completion Page i of vi Executive Summary Following an August 2005 corporate commitment to the Secretary of Energy, Bechtel National, Inc. chartered a team of industry experts to review the technical, cost, and schedule aspects of the Waste Treatment and Immobilization Plant (WTP) project. This summary reflects the observations and recommendations of the EAC Review Team (ERT), comprised of six senior industry consultants, six retired Bechtel employees, one current Bechtel employee, three employees of Bechtel's competitors, and

310

EA-437; Environmental Assessment Process Equipment Waste and Process Waste Liquid Collection Systems Idaho Chemical Processing Plant Idaho National Engineering Laboratory  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

437; Environmental Assessment Process Equipment Waste and 437; Environmental Assessment Process Equipment Waste and Process Waste Liquid Collection Systems Idaho Chemical Processing Plant Idaho National Engineering Laboratory TABLE OF CONTENTS Environmental Assessment Process Equipment Waste and Process Waste Liquid Collection Systems Idaho Chemical Processing Plant Idaho National Engineering Laboratory 1. INTRODUCTION 2. DESCRIPTION OF THE PROPOSED ACTION AND ALTERNATIVES 2.1 Purpose and Need of the Proposed Action 2.2 Description of the Affected Facilities 2.3 Description of Proposed Action 2.4 Alternatives to the Proposed Action 2.5 Separate But Related Actions 3. AFFECTED ENVIRONMENT 3.1 Introduction 3.2 Physical Environment 3.3 Biological Resources 3.4 Cultural Resources 3.5 Environmental Quality and Monitoring Programs

311

EA-1106: Explosive Waste Treatment Facility at Site 300, Lawrence Livermore  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

106: Explosive Waste Treatment Facility at Site 300, Lawrence 106: Explosive Waste Treatment Facility at Site 300, Lawrence Livermore National Laboratory, San Joaquin County, California EA-1106: Explosive Waste Treatment Facility at Site 300, Lawrence Livermore National Laboratory, San Joaquin County, California SUMMARY This EA evaluates the environmental impacts of the proposal to build, permit, and operate the Explosive Waste Treatment Facility to treat explosive waste at the U.S. Department of Energy's Lawrence Livermore National Laboratory Experimental Test Site, Site 300. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD April 16, 1996 EA-1106: Finding of No Significant Impact Explosive Waste Treatment Facility at Site 300, Lawrence Livermore National Laboratory April 16, 1996

312

Plasma-chemical waste treatment of acid gases  

DOE Green Energy (OSTI)

The research to date has shown that a H{sub 2}S waste-treatment process based on plasma-chemical dissociation technology is compatible with refinery and high-carbon-oxide acid-gas streams. The minor amounts of impurities produced in the plasma-chemical reactor should be treatable by an internal catalytic reduction step. Furthermore, the plasma-chemical technology appears to be more efficient and more economical than the current technology. The principal key to achieving high conversions with relatively low energies of dissociation is the concept of the high-velocity, cyclonic-flow pattern in the plasma reaction zone coupled with the recycling of unconverted hydrogen sulfide. Future work will include testing the effects of components that might be carried over to the plasma reactor by ``upset`` conditions in the amine purification system of a plant and testing the plasma-chemical process on other industrial wastes streams that contain potentially valuable chemical reagents. The strategy for the commercialization of this technology is to form a Cooperative Research and Development Agreement with the Institute of Hydrogen Energy and Plasma Technology of the Russian Scientific Center/Kurchatov Institute and with an American start-up company to develop an ``American`` version of the process and to build a commercial-scale demonstration unit in the United States. The timetable proposed would involve building a ``field test`` facility which would test the plasma-chemical reactor and sulfur recovery unit operations on an industrial hydrogen sulfide waste s at a scale large enough to obtain the energy and material balance data required for a final analysis of the commercial potential of this technology. The field test would then be followed by construction of a commercial demonstration unit in two to three years. The commercial demonstration unit would be a fully integrated plant consisting of one commercial-scale module.

Harkness, J.B.L.; Doctor, R.D.; Daniels, E.J.

1993-09-01T23:59:59.000Z

313

Preliminary analysis of treatment strategies for transuranic wastes from reprocessing plants  

Science Conference Proceedings (OSTI)

This document provides a comparison of six treatment options for transuranic wastes (TRUW) resulting from the reprocessing of commercial spent fuel. Projected transuranic waste streams from the Barnwell Nuclear Fuel Plant (BNFP), the reference fuel reprocessing plant in this report, were grouped into the five categories of hulls and hardware, failed equipment, filters, fluorinator solids, and general process trash (GPT) and sample and analytical cell (SAC) wastes. Six potential treatment options were selected for the five categories of waste. These options represent six basic treatment objectives: (1) no treatment, (2) minimum treatment (compaction), (3) minimum number of processes and products (cementing or grouting), (4) maximum volume reduction without decontamination (melting, incinerating, hot pressing), (5) maximum volume reduction with decontamination (decontamination, treatment of residues), and (6) noncombustible waste forms (melting, incinerating, cementing). Schemes for treatment of each waste type were selected and developed for each treatment option and each type of waste. From these schemes, transuranic waste volumes were found to vary from 1 m/sup 3//MTU for no treatment to as low as 0.02 m/sup 3//MTU. Based on conceptual design requirements, life-cycle costs were estimated for treatment plus on-site storage, transportation, and disposal of both high-level and transuranic wastes (and incremental low-level wastes) from 70,000 MTU. The study concludes that extensive treatment is warranted from both cost and waste form characteristics considerations, and that the characteristics of most of the processing systems used are acceptable. The study recommends that additional combinations of treatment methods or strategies be evaluated and that in the interim, melting, incineration, and cementing be further developed for commercial TRUW. 45 refs., 9 figs., 32 tabs.

Ross, W.A.; Schneider, K.J.; Swanson, J.L.; Yasutake, K.M.; Allen, R.P.

1985-07-01T23:59:59.000Z

314

RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES  

SciTech Connect

The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

2011-02-24T23:59:59.000Z

315

Treatability studies and large-scale treatment of aqueous mixed waste containing heavy metals  

SciTech Connect

Wastes have accumulated at the Idaho National Engineering Laboratory through routine laboratory practices, experimental engineering operations, and decommissioning and decontamination of nuclear reactor facilities. A storage tank at the Test Area North held approximately 129,000 L of acidic wastewater and contained prohibited levels of lead and mercury. Radioactive constituents were also present; the most predominant being radiocesium Cs-137 and radiocobalt Co-60. Bench-scale studio were undertaken to evaluate ion exchange as a means of removing the contaminants. A set of breakthrough curves was obtained and identified capacity constraints, selectivities, and operating requirements of candidate resins. Treatment studies indicated that Purolite S-920 resin could effectively remove mercury, while Rohm and Haas` Amberlite 200-CH was used for lead and radionuclide removal. Based on these laboratory tests a full-scale facility, using multiple ion exchange columns, was designed and operated in the spring of 1994. The liquid effluents were discharged to an onsite evaporation pond and met RCRA disposal limits for hazardous metals and self-imposed radionuclide limits. All secondary wastes and residues were sampled and subjected to the to)dc characteristic leaching procedure. The resulting leachate concentrations were below RCRA discharge limits and, therefore, these will be disposed of at the onsite low-level disposal facility. After concluding the tank wastewater operations, enough reserve resin capacity was available to treat three additional mixed wastes residing onsite. These totaled about 1,900 L (500 gal) and contained prohibited levels of chromium, cadmium, and barium. Laboratory studies demonstrated that these heavy metals could also be removed by the existing resins. Treatment was performed at the full-scale facility with the effluents discharged to the evaporation pond.

Haefner, D.R.

1995-12-01T23:59:59.000Z

316

EA-1189: Non-thermal Treatment of Hanford Site Low-level Mixed Waste,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

9: Non-thermal Treatment of Hanford Site Low-level Mixed 9: Non-thermal Treatment of Hanford Site Low-level Mixed Waste, Richland, Washington EA-1189: Non-thermal Treatment of Hanford Site Low-level Mixed Waste, Richland, Washington SUMMARY This EA evaluates the environmental impacts for the proposal to demonstrate the feasibility of commercial treatment of contact-handled low-level mixed waste to meet existing Federal and State regulatory standards for eventual land disposal at the U.S. Department of Energy Richland Operations Office. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD September 29, 1998 EA-1189: Finding of No Significant Impact Non-thermal Treatment of Hanford Site Low-level Mixed Waste September 29, 1998 EA-1189: Final Environmental Assessment Non-thermal Treatment of Hanford Site Low-level Mixed Waste

317

RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN CHEMISTRY FOR HIGH LEVEL WASTE TREATMENT  

Science Conference Proceedings (OSTI)

A principal goal at the Savannah River Site is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange technology is being considered for cesium removal using a polymer resin made of resorcinol formaldehyde that has been engineered into microspheres. The waste under study is generally lower in potassium and organic components than Hanford waste; therefore, the resin performance was evaluated with actual dissolved salt waste. The ion exchange performance and resin chemistry results are discussed.

Nash, C.; Duignan, M.

2010-01-14T23:59:59.000Z

318

WASTE TREATMENT AND DISPOSAL PROGRESS REPORT FOR AUGUST AND SEPTEMBER 1961  

SciTech Connect

Work is being carried out to develop and demonstrate on pilot plant scale integrated processes for treatment and disposal of radmoactive wastes. High-level waste calcination, low-level waste treatment, economic and hazards evaluation, engineering evaluation, disposal in deep wells, disposal in natural salt formations, Clinch River studies, fundamental studies of minerals, and White Oak Creek basin study are discussed. (M.C.G.)

Blanco, R.E.; Struxness, E.G.

1961-11-29T23:59:59.000Z

319

WASTE TREATMENT AND DISPOSAL PROGRESS REPORT FOR DECEMBER 1961 AND JANUARY 1962  

SciTech Connect

Progress in the development and demonstration on a pilot plant scale integrated processes for treatment and ultimate disposal of radioactive wastes is reported. Topics covered include: high-level waste calcination; lowlevel waste treatment; engineering, economics, and hazards evaluation; disposal ln deep wells; disposal in natural salt formations; Clinch River study; fundamental study of minerals; and White Oak Creek basin study. (M.C.G.)

Blanco, R.E.; Struxness, E.G.

1962-10-31T23:59:59.000Z

320

Mixed Waste Focus Area mercury contamination product line: An integrated approach to mercury waste treatment and disposal  

SciTech Connect

The US Department of Energy (DOE) Mixed Waste Focus Area (MWFA) is tasked with ensuring that solutions are available for the mixed waste treatment problems of the DOE complex. During the MWFA`s initial technical baseline development process, three of the top four technology deficiencies identified were related to the need for amalgamation, stabilization, and separation/removal technologies for the treatment of mercury and mercury-contaminated mixed waste. The focus area grouped mercury-waste-treatment activities into the mercury contamination product line under which development, demonstration, and deployment efforts are coordinated to provide tested technologies to meet the site needs. The Mercury Working Group (HgWG), a selected group of representatives from DOE sites with significant mercury waste inventories, is assisting the MWFA in soliciting, identifying, initiating, and managing efforts to address these areas. Based on the scope and magnitude of the mercury mixed waste problem, as defined by HgWG, solicitations and contract awards have been made to the private sector to demonstrate amalgamation and stabilization processes using actual mixed wastes. Development efforts are currently being funded under the product line that will address DOE`s needs for separation/removal processes. This paper discusses the technology selection process, development activities, and the accomplishments of the MWFA to date through these various activities.

Hulet, G.A. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States); Conley, T.B.; Morris, M.I. [Oak Ridge National Lab., TN (United States)

1998-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality, August 2012  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Treatment and Waste Treatment and Immobilization Plant Construction Quality May 2011 August 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy i Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Background .......................................................................................................................................... 1 3.0 Scope .................................................................................................................................................... 1

322

Review of the Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality, November 2011  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Site Waste Treatment and Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality May 2011 November 2011 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Background .......................................................................................................................................... 1 3.0 Scope .................................................................................................................................................... 1

323

Review of the Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality, November 2011  

NLE Websites -- All DOE Office Websites (Extended Search)

Hanford Site Waste Treatment and Hanford Site Waste Treatment and Immobilization Plant Project Construction Quality May 2011 November 2011 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Background .......................................................................................................................................... 1 3.0 Scope .................................................................................................................................................... 1

324

Review of the Hanford Site Waste Treatment and Immobilization Plant Construction Quality, August 2012  

NLE Websites -- All DOE Office Websites (Extended Search)

Hanford Site Waste Treatment and Hanford Site Waste Treatment and Immobilization Plant Construction Quality May 2011 August 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy i Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Background .......................................................................................................................................... 1 3.0 Scope .................................................................................................................................................... 1

325

Geothermal Waste Treatment Biotechnology: Progress and Advantages to the Utilities  

DOE Green Energy (OSTI)

Development of biotechnology for treatment of geothermal residual waste is aimed at the application of low-cost biochemical processes for the surface treatment and disposal of residual geothermal sludges. These processes, in addition to the lowering of disposal cost, are designed to be environmentally acceptable. Recent studies at Brookhaven National Laboratory (BNL) have shown that optimization of several process variables results in fast rates (<24h) of metal removal from residual sludges at acidic pH ({approx}1-2). Optimization of the process variables also enables the removal of radioactive isotopes. In addition, the aqueous phase produced during the bioprocessing which contains solubilized metals can be further treated in a manner which precipitates out the metals and renders the aqueous effluent toxic metal free. In this paper, the various process options will be discussed in terms of biotreatment variables. Chemical composition before and after biotreatment will also be discussed in terms of long-range effects, quality assurance and potential disposal costs.

Premuzic, E.T.; Lin, M.S.; Jin, J.

1992-03-24T23:59:59.000Z

326

Geothermal waste treatment biotechnology: Progress and advantages to the utilities  

DOE Green Energy (OSTI)

Development of biotechnology for treatment of geothermal residual waste is aimed at the application of low-cost biochemical processes for the surface treatment and disposal of residual geothermal sludges. These processes, in addition to the lowering of disposal cost, are designed to be environmentally acceptable. Recent studies at Brookhaven National Laboratory (BNL) have shown that optimization of several process variables results in fast rates (<24h) of metal removal from residual sludges at acidic pH ({minus}1--2). Optimization of the process variables also enables the removal of radioactive isotopes. In addition, the aqueous phase produced during the bioprocessing which contains solubilized metals can be further treated in a manner which precipitates out the metals and renders the aqueous effluent toxic metal free. In this paper, the various process options will be discussed in terms of biotreatment variables. Chemical composition before and after biotreatment will also be discussed in terms of long-range effects, quality assurance and potential disposal costs.

Premuzic, E.T.; Lin, M.S.; Jin, J.

1992-03-01T23:59:59.000Z

327

A preliminary evaluation of alternatives for treatment of INEL Low-Level Waste and low-level mixed waste  

SciTech Connect

The Mixed and Low-Level Waste Treatment Facility (MLLWTF) project was established in 1991 by the US Department of Energy Idaho Field Office to provide treatment capabilities for Idaho National Engineering Laboratory (INEL) low-level mixed waste and low-level waste. This report identifies and evaluates the alternatives for treating that waste. Twelve treatment alternatives, ranging from ``no-action`` to constructing and operating the MLLWTF, are identified and evaluated. Evaluations include facility performance, environmental, safety, institutional, schedule, and rough order-of-magnitude cost comparisons. The performance of each alternative is evaluated against lists of ``musts`` and ``wants.`` Also included is a discussion of other key considerations for decision making. Analysis of results indicated further study is necessary to obtain the best estimate of future waste volumes and characteristics from the expanded INEL Decontamination and Decommissioning Program. It is also recommended that conceptual design begin as scheduled on the MLLWTF, maximum treatment alternative while re-evaluating the waste volume projections.

Smith, T.H.; Roesener, W.S.; Jorgensen-Waters, M.J.; Edinborough, C.R.

1992-06-01T23:59:59.000Z

328

Followup of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process Systems Hazards Analysis Activity Review, March 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

HSS Independent Activity Report - HSS Independent Activity Report - Rev. 0 Report Number: HIAR-WTP-2013-03-18 Site: Hanford Site Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Follow-up of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity Review Dates of Activity : 03/18/13 - 03/21/13 Report Preparer: James O. Low Activity Description/Purpose: The Office of Health, Safety and Security (HSS) staff observed a limited portion of the restart of the Hazard Analysis (HA) for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter Process (LMP) System. The primary purpose of this HSS field activity, on March 18-21, 2013, was to observe and understand the revised approach

329

Followup of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process Systems Hazards Analysis Activity Review, March 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HSS Independent Activity Report - HSS Independent Activity Report - Rev. 0 Report Number: HIAR-WTP-2013-03-18 Site: Hanford Site Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for Follow-up of Waste Treatment and Immobilization Plant Low Activity Waste Melter Process System Hazards Analysis Activity Review Dates of Activity : 03/18/13 - 03/21/13 Report Preparer: James O. Low Activity Description/Purpose: The Office of Health, Safety and Security (HSS) staff observed a limited portion of the restart of the Hazard Analysis (HA) for the Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) Melter Process (LMP) System. The primary purpose of this HSS field activity, on March 18-21, 2013, was to observe and understand the revised approach

330

Environmental sampling program for a solar evaporation pond for liquid radioactive wastes  

Science Conference Proceedings (OSTI)

Los Alamos Scientific Laboratory (LASL) is evaluating solar evaporation as a method for disposal of liquid radioactive wastes. This report describes a sampling program designed to monitor possible escape of radioactivity to the environment from a solar evaporation pond prototype constructed at LASL. Background radioactivity levels at the pond site were determined from soil and vegetation analyses before construction. When the pond is operative, the sampling program will qualitatively and quantitatively detect the transport of radioactivity to the soil, air, and vegetation in the vicinity. Possible correlation of meteorological data with sampling results is being investigated and measures to control export of radioactivity by biological vectors are being assessed.

Romero, R.; Gunderson, T.C.; Talley, A.D.

1980-04-01T23:59:59.000Z

331

New methods for determination of interstitial liquid levels in Hanford waste tanks  

Science Conference Proceedings (OSTI)

The key to the leak detection program for many tanks at Hanford is the method used to evaluate the apparent interstitial liquid interface (ILL) within the pore space of the solid waste medium (either crystalline or sludge). Three new approaches were introduced in the summer of 1993 (count rate, derivative, and sigmoid), all of which significantly improved the accuracy and repeatability of interstitial liquid level values from neutron survey data. This paper summarizes the three new methods and details a case study in which, as a direct result of this improved analysis, a tank that had been declared an ``assumed leaker`` was reclassified as ``sound`` for the first time in Hanford`s 50 year history.

Barnes, D.A.; Raymond, R.E. [Westinghouse Hanford Co., Richland, WA (United States); Whitney, P.D. [Pacific Northwest Lab., Richland, WA (United States)

1995-01-01T23:59:59.000Z

332

Detection of free liquid in drums of radioactive waste. [Patent application  

DOE Patents (OSTI)

A nondestructive thermal imaging method for detecting the presence of a liquid such as water within a sealed container is described. The process includes application of a low amplitude heat pulse to an exterior surface area of the container, terminating the heat input and quickly mapping the resulting surface temperatures. The various mapped temperature values can be compared with those known to be normal for the container material and substances in contact. The mapped temperature values show up in different shades of light or darkness that denote different physical substances. The different substances can be determined by direct observation or by comparison with known standards. The method is particularly applicable to the detection of liquids above solidified radioactive wastes stored in sealed containers.

Not Available

1979-10-16T23:59:59.000Z

333

Process for converting sodium nitrate-containing, caustic liquid radioactive wastes to solid insoluble products  

DOE Patents (OSTI)

A method for converting sodium nitrate-containing, caustic, radioactive wastes to a solid, relatively insoluble, thermally stable form is provided and comprises the steps of reacting powdered aluminum silicate clay, e.g., kaolin, bentonite, dickite, halloysite, pyrophyllite, etc., with the sodium nitrate-containing radioactive wastes which have a caustic concentration of about 3 to 7 M at a temperature of 30.degree. C to 100.degree. C to thereby entrap the dissolved radioactive salts in the aluminosilicate matrix. In one embodiment the sodium nitrate-containing, caustic, radioactive liquid waste, such as neutralized Purex-type waste, or salts or oxide produced by evaporation or calcination of these liquid wastes (e.g., anhydrous salt cake) is converted at a temperature within the range of 30.degree. C to 100.degree. C to the solid mineral form-cancrinite having an approximate chemical formula 2(NaAlSiO.sub.4) .sup.. xSalt.sup.. y H.sub.2 O with x = 0.52 and y = 0.68 when the entrapped salt is NaNO.sub.3. In another embodiment the sodium nitrate-containing, caustic, radioactive liquid is reacted with the powdered aluminum silicate clay at a temperature within the range of 30.degree. C to 100.degree. C, the resulting reaction product is air dried eitheras loose powder or molded shapes (e.g., bricks) and then fired at a temperature of at least 600.degree. C to form the solid mineral form-nepheline which has the approximate chemical formula of NaAlSiO.sub.4. The leach rate of the entrapped radioactive salts with distilled water is reduced essentially to that of the aluminosilicate lattice which is very low, e.g., in the range of 10.sup.-.sup.2 to 10.sup.-.sup.4 g/cm.sup.2 -- day for cancrinite and 10.sup.-.sup.3 to 10.sup.-.sup.5 g/cm.sup.2 -- day for nepheline.

Barney, Gary S. (Richland, WA); Brownell, Lloyd E. (Richland, WA)

1977-01-01T23:59:59.000Z

334

Mixed Waste Focus Area Working Group: An Integrated Approach to Mercury Waste Treatment and Disposal. Revision 1  

SciTech Connect

May 1996, the U.S. Department of Energy (DOE) Mixed Waste Focus Area (MWFA) initiated the Mercury Work Group (HgWG). The HgWG was established to address and resolve the issues associated with Mercury- contaminated mixed wastes (MWs). During the initial technical baseline development process of the MWFA, three of the top four technology deficiencies identified were related to (1) amalgamation, (2) stabilization, and (3) separation and removal for the treatment of mercury and mercury-contaminated mixed waste (MW). The HgWG is assisting the MWFA in soliciting, identifying, initiating, and managing efforts to address these needs.

Morris, M.I.; Conley, T.B.; Osborne-Lee, I.W.

1997-09-08T23:59:59.000Z

335

RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

2012-02-02T23:59:59.000Z

336

Waste Characterization Data Manual for the inactive liquid low-level waste tank systems at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Environmental Restoration Program  

Science Conference Proceedings (OSTI)

This Waste Characterization Data Manual contains the results of an analysis of the contents of liquid low-level waste (LLLW) tanks that have been removed from service in accordance with the requirements of the Oak Ridge National Laboratory (ORNL) Federal Facility Agreement (FFA), Section IX.G.1. Section IX.G.1 of the FFA requires waste characterizations be conducted and provided to EPA and TDEC for all LLLW tanks that are removed from service. These waste characterizations shall include the results of sampling and analysis of the tank contents, including wastes, liquids, and sludges. This manual was first issued as ORNL/ER-80 in June 1992. The waste characterization data were extracted from ORNL reports that described tank sampling and analysis conducted in 1988 for 32 out-of-service tanks. This revision of the manual contains waste characterization data for 54 tanks, including the 32 tanks from the 1988 sampling campaign (Sects. 2.1 through 2.32) and the 22 additional tanks from a subsequent sampling campaign in 1992 and 1993 (Sects. 2.33 through 2.54). Data are presented from analyses of volatile organic compounds, semivolatile organic compounds, polychlorinated biphenyls (PCBs), pesticides, radiochemical compounds, and inorganic compounds. As additional data resulting from analyses of out-of-service tank samples become available, they will be added to this manual.

Not Available

1993-06-01T23:59:59.000Z

337

GRR/Section 18-HI-b - RCRA - Hazardous Waste Treatment, Storage, and  

Open Energy Info (EERE)

8-HI-b - RCRA - Hazardous Waste Treatment, Storage, and 8-HI-b - RCRA - Hazardous Waste Treatment, Storage, and Disposal Permit (TSD) < GRR Jump to: navigation, search GRR-logo.png GEOTHERMAL REGULATORY ROADMAP Roadmap Home Roadmap Help List of Sections Section 18-HI-b - RCRA - Hazardous Waste Treatment, Storage, and Disposal Permit (TSD) 18HIB - RCRAHazardousWasteTreatmentStorageAndDisposalPermitTSD.pdf Click to View Fullscreen Contact Agencies Hawaii Department of Health Solid and Hazardous Waste Branch United States Environmental Protection Agency Regulations & Policies Resource Conversation and Recovery Act (42 U.S.C. 6901, et seq.) 40 CFR 270 Hawaii Administrative Rules Title 11, Chapter 261 Hawaii Administrative Rules Title 11, Chapter 265 Triggers None specified Click "Edit With Form" above to add content

338

Mixed Waste Advanced Treatment Technology: Waste Processing Products and Their Recycling Applications  

Science Conference Proceedings (OSTI)

During their operations, nuclear power plants generate mixed waste containing both hazardous and radioactive constituents. Disposal options for such mixed waste are limited and expensive. EPRI research has demonstrated that an innovative molten metal process for destroying hazardous wastes can be used effectively on nuclear power plant wastes containing both hazardous and radioactive constituents. Preliminary results of this research indicate that the destruction of the hazardous constituents is complete...

1997-12-31T23:59:59.000Z

339

Mixed and Low-Level Waste Treatment Facility Project. Appendix B, Waste stream engineering files: Part 2, Low-level waste streams  

SciTech Connect

Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. This report documents those studies so the project can continue with an evaluation of programmatic options, system tradeoff studies, and the conceptual design phase of the project. This report, appendix B, comprises the engineering design files for this project study. The engineering design files document each waste steam, its characteristics, and identified treatment strategies.

1992-04-01T23:59:59.000Z

340

Steam Reforming Application for Treatment of DOE Sodium Bearing Tank Wastes at INL for ICP  

SciTech Connect

The patented THOR® steam reforming waste treatment technology has been selected as the technology of choice for treatment of Sodium Bearing Waste (SBW) at the Idaho National Laboratory (INL) for the Idaho Cleanup Project (ICP). SBW is an acidic tank waste at the Idaho Nuclear Technology and Engineering Center (INTEC) at INL. It consists primarily of waste from decontamination activities and laboratory wastes. SBW contains high concentrations of nitric acid, alkali and aluminum nitrates, with minor amounts of many inorganic compounds including radionuclides, mainly cesium and strontium. The THOR® steam reforming process will convert the SBW tank waste feed into a dry, solid, granular product. The THOR® technology was selected to treat SBW, in part, because it can provide flexible disposal options to accommodate the final disposition path selected for SBW. THOR® can produce a final end-product that will meet anticipated requirements for disposal as Remote-Handled TRU (RH-TRU) waste; and, with modifications, THOR® can also produce a final endproduct that could be qualified for disposal as High Level Waste (HLW). SBW treatment will be take place within the Integrated Waste Treatment Unit (IWTU), a new facility that will be located at the INTEC. This paper provides an overview of the THOR® process chemistry and process equipment being designed for the IWTU.

J. Bradley Mason; Kevin Ryan; Scott Roesener; Michael Cowen; Duane Schmoker; Pat Bacala; Bill Landman

2006-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Initial Selection of Supplemental Treatment Technologies for Hanford's Low-Activity Tank Waste  

Science Conference Proceedings (OSTI)

In 2002, the U.S. Department of Energy (DOE) documented a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years (DOE 2002). A key element of the accelerated cleanup plan was a strategic initiative for acceleration of the tank waste program and completion of "tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (ETP) and using supplemental technologies for waste treatment and immobilization." The plan identified specific technologies to be evaluated for supplemental treatment of as much as 70% of the low-activity waste (LAW). The objective was to complete required testing and evaluation that would "...bring an appropriate combination of the above technologies to deployment to supplement LAW treatment and immobilization in the WTP to achieve the completion of tank waste treatment by 2028." In concert with this acceleration plan, DOE, the U.S. Environmental Protection Agency, and the Washington State Department of Ecology have proposed to accelerate from 2012 to 2005 the Hanford Federal Facility Compliance Agreement (Tri-Party Agreement) milestone (M-62-08) associated with a final decision on treatment of the balance of tank waste that is beyond the capacity of the currently designed WTP.

Raymond, Richard E.; Powell, Roger W.; Hamilton, Dennis W.; Kitchen, William A.; Mauss, Billie M.; Brouns, Thomas M.

2004-07-15T23:59:59.000Z

342

Double liquid membrane system for the removal of actinides and lanthanides from acidic nuclear wastes  

SciTech Connect

Supported liquid membranes (SLM), consisting of an organic solution of n-octyl-(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) and tributyl-phosphate (TBP) in decalin are able to perform selective separation and concentration of actinide and lanthanide ions from aqueous nitrate feed solutions and synthetic nuclear wastes. In the membrane process a possible strip solution is a mixture of formic acid and hydroxylammonium formate (HAF). The effectiveness of this strip solution is reduced and eventually nullified by the simultaneous transfer through the SLM of nitric acid which accumulates in the strip solution. A possible way to overcome this drawback is to make use of a second SLM consisting of a primary amine which is able to extract only HNO/sub 3/ from the strip solution. In this work the results obtained by experimentally studying the membrane system: synthetic nuclear waste/CMPO-TBP membrane/HCOOH-HAF strip solution/primary amine membrane/NaOH solution, are reported. They show that the use of a second liquid membrane is effective in controlling the HNO/sub 3/ concentration in the strip solution, thus allowing the actinide and lanthanide ions removal from the feed solution to proceed to completion. 15 refs., 10 figs., 1 tab.

Chiarizia, R.; Danesi, P.R.

1985-01-01T23:59:59.000Z

343

Plutonium Finishing Plan (PFP) Treatment and Storage Unit Waste Analysis Plan  

Science Conference Proceedings (OSTI)

The purpose of this waste analysis plan (WAP) is to document waste analysis activities associated with the Plutonium Finishing Plant Treatment and Storage Unit (PFP Treatment and Storage Unit) to comply with Washington Administrative Code (WAC) 173-303-300(1), (2), (4)(a) and (5). The PFP Treatment and Storage Unit is an interim status container management unit for plutonium bearing mixed waste radiologically managed as transuranic (TRU) waste. TRU mixed (TRUM) waste managed at the PFP Treatment and Storage Unit is destined for the Waste Isolation Pilot Plant (WIPP) and therefore is not subject to land disposal restrictions [WAC 173-303-140 and 40 CFR 268]. The PFP Treatment and Storage Unit is located in the 200 West Area of the Hanford Facility, Richland Washington (Figure 1). Because dangerous waste does not include source, special nuclear, and by-product material components of mixed waste, radionuclides are not within the scope of this documentation. The information on radionuclides is provided only for general knowledge.

PRIGNANO, A.L.

2000-07-01T23:59:59.000Z

344

Liquidization of dewatered organic sludge and anaerobic treatment  

SciTech Connect

Dewatered sewage sludge was thermochemically liquidized at 175 {degrees}C and the liquidized sludge was separated by centrifugation to 58% (w/w) supernatant and 42% precipitate. The amount of proteins in the liquidized sludge slightly decreased through the liquidization process, however, that of lipids increased. The supernatant separated from the sludge liquidized with dewatered sewage sludge was successfully anaerobically digested. Biogas yield from the supernatant from dewatered sewage sludge at organic loading concentrations of 1.9-2.2 g VS/l during 9 days incubation was 440 ml/g-added VS and digestion ratio was 66% (w/w). Biogas yield in the case of dewatered sewage sludge was 257 ml/g-added VS and digestion ratio was 45%. Similar results were obtained in the case of the anaerobically digested with sewage sludge and dewatered sludge. Anaerobic digestion of the supernatants from the liquidized sludges resulted in high biogas productivity and high digestion ratio compared with these of the original sludges. Moreover, the precipitates contained lower moisture, therefore, they can be incinerated easier than the respective original sludges.

Sawayama, Shigeki; Inoue, Seiichi; Ogi, Tomoko [National Institute for Resources and Environment, Tsukuba, Ibaraki (Japan)

1996-12-31T23:59:59.000Z

345

Characterization and monitoring of 300 Area Facility liquid waste streams: Status report  

SciTech Connect

This report summarizes the results of characterizing and monitoring the following sources during a portion of this year: liquid waste streams from Buildings 331, 320, and 3720; treated and untreated Columbia River water; and water at the confluence of the waste streams (that is, end-of-pipe). Characterization and monitoring data were evaluated for samples collected between March 22 and June 21, 1994, and subsequently analyzed for hazardous chemicals, radioactivity, and general parameters. Except for bis(2-ethylhexyl)phthalate, concentrations of chemicals detected and parameters measured at end-of-pipe were below the US Environmental Protection Agency existing and proposed drinking water standards. The source of the chemicals, except bis(2-ethylhexyl)phthalate, is not currently known. The bis(2-ethylhexyl)phthalate is probably an artifact of the plastic tubing used in the early stages of the sampling program. This practice was stopped. Concentrations and clearance times for contaminants at end-of-pipe depended strongly on source concentration at the facility release point, waste stream flow rates, dispersion, and the mechanical action of sumps. When present, the action of sumps had the greatest impact on contaminant clearance times. In the absence of sump activity, dispersion and flow rate were the controlling factors.

Manke, K.L. [ed.; Riley, R.G.; Ballinger, M.Y.; Damberg, E.G.; Evans, J.C.; Ikenberry, A.S.; Olsen, K.B.; Ozanich, R.M.; Thompson, C.J.

1994-09-01T23:59:59.000Z

346

Mixed Waste Treatment Cost Analysis for a Range of GeoMelt Vitrification Process Configurations  

Science Conference Proceedings (OSTI)

GeoMelt is a batch vitrification process used for contaminated site remediation and waste treatment. GeoMelt can be applied in several different configurations ranging from deep subsurface in situ treatment to aboveground batch plants. The process has been successfully used to treat a wide range of contaminated wastes and debris including: mixed low-level radioactive wastes; mixed transuranic wastes; polychlorinated biphenyls; pesticides; dioxins; and a range of heavy metals. Hypothetical cost estimates for the treatment of mixed low-level radioactive waste were prepared for the GeoMelt subsurface planar and in-container vitrification methods. The subsurface planar method involves in situ treatment and the in-container vitrification method involves treatment in an aboveground batch plant. The projected costs for the subsurface planar method range from $355-$461 per ton. These costs equate to 18-20 cents per pound. The projected cost for the in-container method is $1585 per ton. This cost equates to 80 cents per pound. These treatment costs are ten or more times lower than the treatment costs for alternative mixed waste treatment technologies according to a 1996 study by the US Department of Energy.

Thompson, L. E.

2002-02-27T23:59:59.000Z

347

Record of Decision for the Department of Energy's Waste Management Program; Treatment and Storage of Transuranic Waste  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3630 3630 Federal Register / Vol. 63, No. 15 / Friday, January 23, 1998 / Notices to agreements DOE has entered into, such as those with States, relating to the treatment and storage of TRU waste. Future NEPA review could include, but would not necessarily be limited to, analysis of the need to supplement existing environmental reviews. DOE would conduct all such TRU waste shipments between sites in accordance with applicable transportation requirements and would coordinate these shipments with appropriate State, Tribal and local authorities. This Record of Decision was prepared in coordination with the Record of Decision issued on January 16, 1998, on disposal of DOE's TRU waste, which is based on the Waste Isolation Pilot Plant Disposal Phase Final Supplemental Environmental Impact Statement (WIPP

348

Development of an Alternative Treatment Scheme for Sr/TRU Removal: Permanganate Treatment of AN-107 Waste  

SciTech Connect

A number of Hanford tanks received waste containing organic complexants, which increase the volubility of Sr-90 and transuranic (TRU) elements. Wastes from these tanks require additional pretreatment to remove Sr-90 and TRU for immobilization as low activity waste (Waste Envelope C). The baseline pretreatment process for Sr/TRU removal was isotopic exchange and precipitation with added strontium and iron. However, studies at both Battelle and Savannah River Technology Center (SRTC) have shown that the Sr/Fe precipitates were very difficult to filter. This was a result of the formation of poor filtering iron solids. An alternate treatment technology was needed for Sr/TRU removal. Battelle had demonstrated that permanganate treatment was effective for decontaminating waste samples from Hanford Tank SY-101 and proposed that permanganate be examined as an alternative Sr/TRU removal scheme for complexant-containing tank wastes such as AW107. Battelle conducted preliminary small-scale experiments to determine the effectiveness of permanganate treatment with AN-107 waste samples that had been archived at Battelle from earlier studies. Three series of experiments were performed to evaluate conditions that provided adequate Sr/TRU decontamination using permanganate treatment. The final series included experiments with actual AN-107 diluted feed that had been obtained specifically for BNFL process testing. Conditions that provided adequate Sr/TRU decontamination were identified. A free hydroxide concentration of 0.5M provided adequate decontamination with added Sr of 0.05M and permanganate of 0.03M for archived AN-107. The best results were obtained when reagents were added in the sequence Sr followed by permanganate with the waste at ambient temperature. The reaction conditions for Sr/TRU removal will be further evaluated with a 1-L batch of archived AN-107, which will provide a large enough volume of waste to conduct crossflow filtration studies (Hallen et al. 2000a).

RT Hallen; SA Bryan; FV Hoopes

2000-08-04T23:59:59.000Z

349

Mixed and low-level waste treatment project: Appendix C, Health and safety criteria for the mixed and low-level waste treatment facility at the Idaho National Engineering Laboratory. Part 1, Waste streams and treatment technologies  

SciTech Connect

This report describes health and safety concerns associated with the Mixed and Low-level Waste Treatment Facility at the Idaho National Engineering Laboratory. Various hazards are described such as fire, electrical, explosions, reactivity, temperature, and radiation hazards, as well as the potential for accidental spills, exposure to toxic materials, and other general safety concerns.

Neupauer, R.M.; Thurmond, S.M.

1992-09-01T23:59:59.000Z

350

Geology of the Waste Treatment Plant Seismic Boreholes  

Science Conference Proceedings (OSTI)

In 2006, DOE-ORP initiated the Seismic Boreholes Project (SBP) to emplace boreholes at the Waste Treatment Plant (WTP) site in order to obtain direct Vs measurements and other physical property measurements in Columbia River basalt and interbedded sediments of the Ellensburg Formation. The goal was to reduce the uncertainty in the response spectra and seismic design basis, and potentially recover design margin for the WTP. The characterization effort within the deep boreholes included 1) downhole measurements of the velocity properties of the suprabasalt, basalt, and sedimentary interbed sequences, 2) downhole measurements of the density of the subsurface basalt and sediments, and 3) confirmation of the geometry of the contact between the various basalt and interbedded sediments through examination of retrieved core from the corehole and data collected through geophysical logging of each borehole. This report describes the results of the geologic studies from three mud-rotary boreholes and one cored borehole at the WTP. All four boreholes penetrated the entire Saddle Mountains Basalt and the upper part of the Wanapum Basalt where thick sedimentary interbeds occur between the lava flows. The basalt flows penetrated in Saddle Mountains Basalt included the Umatilla Member, Esquatzel Member, Pomona Member and the Elephant Mountain Member. The underlying Priest Rapids Member of the Wanapum Basalt was also penetrated. The Ellensburg Formation sediments consist of the Mabton Interbed, the Cold Creek Interbed, the Selah Interbed and the Rattlesnake Ridge Interbed; the Byron Interbed occurs between two flows of the Priest Rapids Member. The Mabton Interbed marks the contact between the Wanapum and Saddle Mountains Basalts. The thicknesses of the basalts and interbedded sediments were within expected limits. However, a small reverse fault was found in the Pomona Member flow top. This fault has three periods of movement and less than 15 feet of repeated section. Most of the movement on the fault appears to have occurred before the youngest lava flow, the 10.5 million year old Elephant Mountain Member was emplaced above the Pomona Member.

Barnett, D. BRENT; Bjornstad, Bruce N.; Fecht, Karl R.; Lanigan, David C.; Reidel, Steve; Rust, Colleen F.

2007-02-28T23:59:59.000Z

351

Technology Evaluations Related to Mercury, Technetium, and Chloride in Treatment of Wastes at the Idaho Nuclear Technology and Engineering Center of the Idaho National Engineering and Environmental Laboratory  

SciTech Connect

The Idaho High-Level Waste and Facility Disposition Environmental Impact Statement defines alternative for treating and disposing of wastes stored at the Idaho Nuclear Technology and Engineering Center. Development is required for several technologies under consideration for treatment of these wastes. This report contains evaluations of whether specific treatment is needed and if so, by what methods, to remove mercury, technetium, and chlorides in proposed Environmental Impact Statement treatment processes. The evaluations of mercury include a review of regulatory requirements that would apply to mercury wastes in separations processes, an evaluation of the sensitivity of mercury flowrates and concentrations to changes in separations processing schemes and conditions, test results from laboratory-scale experiments of precipitation of mercury by sulfide precipitation agents from the TRUEX carbonate wash effluent, and evaluations of methods to remove mercury from New Waste Calcining Facility liquid and gaseous streams. The evaluation of technetium relates to the need for technetium removal and alternative methods to remove technetium from streams in separations processes. The need for removal of chlorides from New Waste Calcining Facility scrub solution is also evaluated.

C. M. Barnes; D. D. Taylor; S. C. Ashworth; J. B. Bosley; D. R. Haefner

1999-10-01T23:59:59.000Z

352

Application of thermogravimetric analysis to study the thermal degradation of solid and liquid organic wastes  

Science Conference Proceedings (OSTI)

In this work, the thermolysis of composite binary mixtures of refinery or coal-processing waste with waste biomass and D-grade (long-flame) coal was analyzed in order to increase the efficiency of the cothermolysis of chemically different organic wastes mainly because of the synergism of the thermolysis of mixture components and, correspondingly, the selectivity of formation of high-quality by-products (solid, gaseous, or liquid). A new approach to the analysis of thermogravimetric data was proposed and developed as applied to complex binary mixtures of carbon-containing materials. This approach was based on (1) the preliminary separation of the thermal degradation of individual carbon-containing mixture components into individual structural constituents and (2) the monitoring of the conversion of each particular structure fragment as a constituent of the mixtures in the course of the cothermolysis of the mixtures of starting components. Based on the approach developed, data on the main synergism effects in the course of cothermolysis in the binary test systems were obtained: the temperature regions of the appearance of these effects were distinguished, the main conclusions were made with respect to particular structure fragments in complex organic wastes responsible for the interaction of components in composite systems, and the directions (positive or negative) of changes in the yields of solid by-products and the degrees of effects (difference between the yields of cothermolysis by-products in each particular region of the appearance of synergistic effects in the systems) were determined. Additionally, the influence of alkali metal carbonate additives on synergistic effects in the interaction between binary system components under the process conditions of cothermolysis was analyzed.

E.S. Lygina; A.F. Dmitruk; S.B. Lyubchik; V.F. Tret'yakov [Tugan-Baranovsky State University of Economy and Trade, Donetsk (Ukraine)

2009-07-01T23:59:59.000Z

353

Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste  

SciTech Connect

Various forms of general and localized corrosion represent principal threats to the integrity of DOE liquid waste storage tanks. These tanks, which are of a single wall or double wall design, depending upon their age, are fabricated from welded carbon steel and contain a complex waste-form comprised of NaOH and NaNO{sub 3}, along with trace amounts of phosphate, sulfate, carbonate, and chloride. Because waste leakage can have a profound environmental impact, considerable interest exists in predicting the accumulation of corrosion damage, so as to more effectively schedule maintenance and repair. The different tasks that are being carried out under the current program are as follows: (1) Theoretical and experimental assessment of general corrosion of iron/steel in borate buffer solutions by using electrochemical impedance spectroscopy (EIS), ellipsometry and XPS techniques; (2) Development of a damage function analysis (DFA) which would help in predicting the accumulation of damage due to pitting corrosion in an environment prototypical of DOE liquid waste systems; (3) Experimental measurement of crack growth rate, acoustic emission signals and coupling currents for fracture in carbon and low alloy steels as functions of mechanical (stress intensity), chemical (conductivity), electrochemical (corrosion potential, ECP), and microstructural (grain size, precipitate size, etc) variables in a systematic manner, with particular attention being focused on the structure of the noise in the current and its correlation with the acoustic emissions; (4) Development of fracture mechanisms for carbon and low alloy steels that are consistent with the crack growth rate, coupling current data and acoustic emissions; (5) Inserting advanced crack growth rate models for SCC into existing deterministic codes for predicting the evolution of corrosion damage in DOE liquid waste storage tanks; (6) Computer simulation of the anodic and cathodic activity on the surface of the steel samples in order to exactly predict the corrosion mechanisms; (7) Wavelet analysis of EC noise data from steel samples undergoing corrosion in an environment similar to that of the high level waste storage containers, to extract data pertaining to general, pitting and stress corrosion processes, from the overall data. The Point Defect Model (PDM) is directly applied as the theoretical assessment method for describing the passive film formed on iron/steels. The PDM is used to describe general corrosion in the passive region of iron. In addition, previous work suggests that pit formation is due to the coalescence of cation vacancies at the metal/film interface which would make it possible to use the PDM parameters to predict the onset of pitting. This previous work suggests that once the critical vacancy density is reached, the film ruptures to form a pit. Based upon the kinetic parameters derived for the general corrosion case, two parameters relating to the cation vacancy formation and annihilation can be calculated. These two parameters can then be applied to predict the transition from general to pitting corrosion for iron/mild steels. If cation vacancy coalescence is shown to lead to pitting, it can have a profound effect on the direction of future studies involving the onset of pitting corrosion. The work has yielded a number of important findings, including an unequivocal demonstration of the role of chloride ion in passivity breakdown on nickel in terms of cation vacancy generation within the passive film, the first detection and characterization of individual micro fracture events in stress corrosion cracking, and the determination of kinetic parameters for the generation and annihilation of point defects in the passive film on iron. The existence of coupling between the internal crack environment and the external cathodic environment, as predicted by the coupled environment fracture model (CEFM), has also been indisputably established for the AISI 4340/NaOH system. It is evident from the studies that analysis of coupling current noise is a very sensitive tool f

Digby D. Macdonald; Brian M. Marx; Sejin Ahn; Julio de Ruiz; Balaji Soundararaja; Morgan Smith; and Wendy Coulson

2008-01-15T23:59:59.000Z

354

EA-1292: On-site Treatment of Low Level Mixed Waste, Golden, Colorado  

Energy.gov (U.S. Department of Energy (DOE))

This EA evaluates the environmental impacts for the proposal to evaluate the proposed treatment of low level mixed waste at the U.S. Department of Energy's Rocky Flats Environmental Technology Site.

355

GRR/Section 18-HI-b - RCRA - Hazardous Waste Treatment, Storage...  

Open Energy Info (EERE)

8-HI-b - RCRA - Hazardous Waste Treatment, Storage, and Disposal Permit (TSD) < GRR Jump to: navigation, search GRR-logo.png GEOTHERMAL REGULATORY ROADMAP Roadmap Home Roadmap Help...

356

Independent Activity Report, Office of River Protection Waste Treatment Plant and Tank Farms- February 2013  

Energy.gov (U.S. Department of Energy (DOE))

Site Familiarization and Introduction of New Office of Safety and Emergency Management Evaluations Site Lead for the Office of River Protection Waste Treatment Plant and Tank Farms [HIAR-HANFORD-2013-02-25

357

Department of Energy treatment capabilities for greater-than-Class C low-level radioactive waste  

SciTech Connect

This report provides brief profiles for 26 low-level and high-level waste treatment capabilities available at the Idaho National Engineering Laboratory (INEL), Lawrence Livermore National Laboratory (LLNL), Los Alamos National Laboratory (LANL), Oak Ridge National Laboratory (ORNL), Pacific Northwest Laboratory (PNL), Rocky Flats Plant (RFP), Savannah River Site (SRS), and West Valley Demonstration Plant (WVDP). Six of the treatments have potential use for greater-than-Class C low-level waste (GTCC LLW). They include: (a) the glass ceramic process and (b) the Waste Experimental Reduction Facility incinerator at INEL; (c) the Super Compaction and Repackaging Facility and (d) microwave melting solidification at RFP; (e) the vitrification plant at SRS; and (f) the vitrification plant at WVDP. No individual treatment has the capability to treat all GTCC LLW streams. It is recommended that complete physical and chemical characterizations be performed for each GTCC waste stream, to permit using multiple treatments for GTCC LLW.

Morrell, D.K.; Fischer, D.K.

1995-01-01T23:59:59.000Z

358

DOE names Bechtel BWXT Idaho and the Advanced Mixed Waste Treatment...  

NLE Websites -- All DOE Office Websites (Extended Search)

names Bechtel BWXT Idaho and the Advanced Mixed Waste Treatment Project as a VPP Star Site Rick Provencher of DOE-ID, Jeff Mousseau of BBWI and co-safety chairs Tracy Anderson and...

359

Mixed and Low-Level Waste Treatment Facility project. Executive summary: Volume 1, Program summary information; Volume 2, Waste stream technical summary: Draft  

SciTech Connect

Mixed and low-level wastes generated at the Idaho National Engineering Laboratory (INEL) are required to be managed according to applicable State and Federal regulations, and Department of Energy Orders that provide for the protection of human health and the environment. The Mixed and Low-Level Waste Treatment Facility Project was chartered in 1991, by the Department of Energy to provide treatment capability for these mixed and low-level waste streams. The first project task consisted of conducting engineering studies to identify the waste streams, their potential treatment strategies, and the requirements that would be imposed on the waste streams and the facilities used to process them. The engineering studies, initiated in July 1991, identified 37 mixed waste streams, and 55 low-level waste streams. This report documents the waste stream information and potential treatment strategies, as well as the regulatory requirements for the Department of Energy-owned treatment facility option. The total report comprises three volumes and two appendices. This report consists of Volume 1, which explains the overall program mission, the guiding assumptions for the engineering studies, and summarizes the waste stream and regulatory information, and Volume 2, the Waste Stream Technical Summary which, encompasses the studies conducted to identify the INEL`s waste streams and their potential treatment strategies.

1992-04-01T23:59:59.000Z

360

Review of the Hanford Site Waste Treatment and Immobilization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

U.S. Department of Energy DOE-WTP ORP WTP Project Office HLW High-Level Waste Facility HVAC Heating, Ventilation, and Air Conditioning LAB Analytical Laboratory LAW Low-Activity...

Note: This page contains sample records for the topic "liquid waste treatment" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Biological treatment of concentrated hazardous, toxic, andradionuclide mixed wastes without dilution  

DOE Green Energy (OSTI)

Approximately 10 percent of all radioactive wastes produced in the U. S. are mixed with hazardous or toxic chemicals and therefore can not be placed in secure land disposal facilities. Mixed wastes containing hazardous organic chemicals are often incinerated, but volatile radioactive elements are released directly into the biosphere. Some mixed wastes do not currently have any identified disposal option and are stored locally awaiting new developments. Biological treatment has been proposed as a potentially safer alternative to incineration for the treatment of hazardous organic mixed wastes, since biological treatment would not release volatile radioisotopes and the residual low-level radioactive waste would no longer be restricted from land disposal. Prior studies have shown that toxicity associated with acetonitrile is a significant limiting factor for the application of biotreatment to mixed wastes and excessive dilution was required to avoid inhibition of biological treatment. In this study, we demonstrate that a novel reactor configuration, where the concentrated toxic waste is drip-fed into a complete-mix bioreactor containing a pre-concentrated active microbial population, can be used to treat a surrogate acetonitrile mixed waste stream without excessive dilution. Using a drip-feed bioreactor, we were able to treat a 90,000 mg/L acetonitrile solution to less than 0.1 mg/L final concentration using a dilution factor of only 3.4. It was determined that the acetonitrile degradation reaction was inhibited at a pH above 7.2 and that the reactor could be modeled using conventional kinetic and mass balance approaches. Using a drip-feed reactor configuration addresses a major limiting factor (toxic inhibition) for the biological treatment of toxic, hazardous, or radioactive mixed wastes and suggests that drip-feed bioreactors could be used to treat other concentrated toxic waste streams, such as chemical warfare materiel.

Stringfellow, William T.; Komada, Tatsuyuki; Chang, Li-Yang

2004-06-15T23:59:59.000Z

362

MWIP: Surrogate formulations for thermal treatment of low-level mixed waste. Part 4, Wastewater treatment sludges  

Science Conference Proceedings (OSTI)

The category of sludges, filter cakes, and other waste processing residuals represent the largest volume of low-level mixed (hazardous and radioactive) wastes within the US Department of Energy (DOE) complex. Treatment of these wastes to minimize the mobility of contaminants, and to eliminate the presence of free water, is required under the Federal Facility Compliance Act agreements between DOE and the Environmental Protection Agency. In the text, we summarize the currently available data for several of the high priority mixed-waste sludge inventories within DOE. Los Alamos National Laboratory TA-50 Sludge and Rocky Flats Plant By-Pass Sludge are transuranic (TRU)-contaminated sludges that were isolated with the use of silica-based filter aids. The Oak Ridge Y-12 Plant West End Treatment Facility Sludge is predominantly calcium carbonate and biomass. The Oak Ridge K-25 Site Pond Waste is a large-volume waste stream, containing clay, silt, and other debris in addition to precipitated metal hydroxides. We formulate ``simulants`` for the waste streams described above, using cerium oxide as a surrogate for the uranium or plutonium present in the authentic material. Use of nonradiological surrogates greatly simplifies material handling requirements for initial treatability studies. The use of synthetic mixtures for initial treatability testing will facilitate compositional variation for use in conjunction with statistical design experiments; this approach may help to identify any ``operating window`` limitations. The initial treatability testing demonstrations utilizing these ``simulants`` will be based upon vitrification, although the materials are also amenable to testing grout-based and other stabilization procedures. After the feasibility of treatment and the initial evaluation of treatment performance has been demonstrated, performance must be verified using authentic samples of the candidate waste stream.

Bostick, W.D.; Hoffmann, D.P.; Stevenson, R.J.; Richmond, A.A. [Oak Ridge National Lab., TN (United States); Bickford, D.F. [Westinghouse Savannah River Co., Aiken, SC (United States)

1994-01-01T23:59:59.000Z

363

Testing of antimony selective media for treatment of liquid radwaste  

SciTech Connect

Nuclear power plants have sought radiation source term reduction and reduced discharge of radioactive constituents for many years. In the case of pressurized water reactors (PWRs), the latter efforts have been directed toward capture and immobilization of recalcitrant (ubiquitous radionuclides with long half-lives) species such as Cs-134 and Cs-137 and Co-58 and Co-60. As these plants resolved, or at least mitigated, the problems with radiocesium and radio-cobalt, antimony radionuclides (Sb-122, Sb-124, and Sb-125) have become a primary concern in liquid liquid radwaste systems Graver Technologies developed a granular composite metal oxide media with good selectivity for radio-antimony. Initial laboratory data were collected using non-radioactive salts of antimony, cesium, and cobalt to judge efficacy of selective removal of antimony. Based on success of those trials, the media, designated Gravex GX187, was tested in partnership with Energy Solutions (nee Duratek) using actual liquid liquid radwaste in two PWR plants. One of these plants performed extensive slip-stream trials comparing the GX187 with strong base anion resins. With more than 2500 bed volumes of throughput, the GX187 outperformed the other competitors by reducing both Sb-124 and Sb-125 radionuclides below minimum detectable activity (MDA) with average decontamination factors (DF's) of 170, even when subjected to high levels of borate. Based on these favorable results, Energy Solutions installed the GX187 in a layered bed in their ALPS liquid radwaste processing system at this plant in August 2005. After one year of intermittent, batchwise operation including an outage, the GX187 processed more than 2.25 million liters (>600,000 gallons) of liquid liquid radwaste while reducing the Sb-125 activity to 2.9 E-08 Bq/L (DF=111) on average. This evaluation is ongoing and will continue at least until the fall 2006 outage at this plant. Concurrently, Graver developed a second generation antimony selective media designated Gravex GX194. Again in partnership with Energy Solutions, the GX194 is currently undergoing slip-stream testing in the liquid radwaste system in one PWR and installed and operating in ALPS systems in 3 other PWRs. After 5 months of slip-stream testing, the GX194 media has produced only MDA quality water in terms of Sb-122 and Sb-125 radionuclides, albeit with relatively low levels of influent antimony. The GX194 installed at the first plant has processed more than 1.2 million liters (>325,000 gallons) of liquid radwaste, consistently produced MDA quality water for Sb-125, and typically offered a DF>100. Similarly, the GX194 in the second plant has processed almost 1.3 million liters ({approx}340,000 gallons) of liquid radwaste, produced MDA quality water for Sb-125 for 36% of 42 batches, and typically offered a DF>35. The GX194 was not installed in the third plant until August 2006, so performance data is still pending. (authors)

Yarnell, P.A. [Graver Technologies, LLC, Glasgow, DE (United States)

2007-07-01T23:59:59.000Z

364

A Database for Reviewing and Selecting Radioactive Waste Treatment Technologies and Vendors  

Science Conference Proceedings (OSTI)

Several attempts have been made in past years to collate and present waste management technologies and solutions to waste generators. These efforts have been manifested as reports, buyers' guides, and databases. While this information is helpful at the time it is assembled, the principal weakness is maintaining the timeliness and accuracy of the information over time. In many cases, updates have to be published or developed as soon as the product is disseminated. The recently developed National Low-Level Waste Management Program's Technologies Database is a vendor-updated Internet based database designed to overcome this problem. The National Low-Level Waste Management Program's Technologies Database contains information about waste types, treatment technologies, and vendor information. Information is presented about waste types, typical treatments, and the vendors who provide those treatment methods. The vendors who provide services update their own contact information, their treatment processes, and the types of wastes for which their treatment process is applicable. This information is queriable by a generator of low-level or mixed low-level radioactive waste who is seeking information on waste treatment methods and the vendors who provide them. Timeliness of the information in the database is assured using time clocks and automated messaging to remind featured vendors to keep their information current. Failure to keep the entries current results in a vendor being warned and then ultimately dropped from the database. This assures that the user is dealing with the most current information available and the vendors who are active in reaching and serving their market.

P. C. Marushia; W. E. Schwinkendorf

1999-07-01T23:59:59.000Z

365

NATURE OF RADIOACTIVE WASTES  

SciTech Connect

The integrated processes of nuclear industry are considered to define the nature of wastes. Processes for recovery and preparation of U and Th fuels produce wastes containing concentrated radioactive materials which present problems of confinement and dispersal. Fundamentals of waste treatment are considered from the standpoint of processes in which radioactive materials become a factor such as naturally occurring feed materials, fission products, and elements produced by parasitic neutron capture. In addition, the origin of concentrated fission product wastes is examined, as well as characteristics of present wastes and the level of fission products in wastes. Also, comments are included on high-level wastes from processes other than solvent extraction, active gaseous wastes, and low- to intermediate-level liquid wastes. (J.R.D.)

Culler, F.L. Jr.

1959-01-26T23:59:59.000Z

366

Summary - System Planning for Low-Activity Waste Treatment at Hanford  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Hanford EM Project: WTP ETR Report Date: November 2008 ETR-18 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of System Planning for Low-Activity Waste Treatment at Hanford Why DOE-EM Did This Review Construction of the facilities of the Hanford site's Waste Treatment Plant (WTP) are scheduled for completion in 2017, with radioactive waste processing scheduled to begin in 2019. An estimated 23 to 35 years will then be required to complete high-level waste (HLW) vitrification. However, vitrification of low-activity waste (LAW) may extend the WTP mission duration by decades more if supplemental LAW processing beyond the capacity of the present facility is not incorporated. The purpose of this independent review was to

367

Sanitary Waste Water Treatment System for the Hanford Decontamination Laundry Facility  

SciTech Connect

This is an engineering report for the Decontamination Laundry Facility (DLF) which will be located in the 200 East Area of the Hanford Site. The proposed Sanitary Waste Treatment System is new and does not involve interfacing with existing sanitary waste treatment systems. It will utilize a subsurface soil absorption system (SSAS), which are frequently used to dispose of sanitary waste water from facilities at the Hanford Site, since a majority of its` facilities are located in remote areas. Construction of the DLF is scheduled to start in 1992 and startup of the DLF is planned during the summer of 1994.

Yanochko, R.M.

1992-09-01T23:59:59.000Z

368

Sanitary Waste Water Treatment System for the Hanford Decontamination Laundry Facility  

SciTech Connect

This is an engineering report for the Decontamination Laundry Facility (DLF) which will be located in the 200 East Area of the Hanford Site. The proposed Sanitary Waste Treatment System is new and does not involve interfacing with existing sanitary waste treatment systems. It will utilize a subsurface soil absorption system (SSAS), which are frequently used to dispose of sanitary waste water from facilities at the Hanford Site, since a majority of its' facilities are located in remote areas. Construction of the DLF is scheduled to start in 1992 and startup of the DLF is planned during the summer of 1994.

Yanochko, R.M.

1992-09-01T23:59:59.000Z

369

Geology of the Waste Treatment Plant Seismic Boreholes  

Science Conference Proceedings (OSTI)

In 2006, the U.S. Department of Energy initiated the Seismic Boreholes Project (SBP) to emplace boreholes at the Waste Treatment Plant (WTP) site in order to obtain direct shear wave velocity (Vs) measurements and other physical property measurements in Columbia River basalt and interbedded sediments of the Ellensburg Formation. The goal was to reduce the uncertainty in the response spectra and seismic design basis, and potentially recover design margin for the WTP. The characterization effort within the deep boreholes included 1) downhole measurements of the velocity properties of the suprabasalt, basalt, and sedimentary interbed sequences, 2) downhole measurements of the density of the subsurface basalt and sediments, and 3) geologic studies to confirm the geometry of the contact between the various basalt and interbedded sediments through examination of retrieved core from the core hole and data collected through geophysical logging of each borehole. This report describes the results of the geologic studies from three mud-rotary boreholes and one cored borehole at the WTP. All four boreholes penetrated the entire Saddle Mountains Basalt and the upper part of the Wanapum Basalt where thick sedimentary interbeds occur between the lava flows. The basalt flows penetrated in Saddle Mountains Basalt included the Umatilla Member, Esquatzel Member, Pomona Member, and the Elephant Mountain Member. The underlying Priest Rapids Member of the Wanapum Basalt also was penetrated. The Ellensburg Formation sediments consist of the Mabton Interbed, the Cold Creek Interbed, the Selah Interbed, and the Rattlesnake Ridge Interbed; the Byron Interbed occurs between two flows of the Priest Rapids Member. The Mabton Interbed marks the contact between the Wanapum and Saddle Mountains Basalts. The thicknesses of the basalts and interbedded sediments were within expected limits. However, a small reverse fault was found in the Pomona Member flow top. This fault has three periods of movement and less than 15 ft of repeated section. Most of the movement on the fault appears to have occurred before the youngest lava flow, the 10.5-million-year-old Elephant Mountain Member, was emplaced above the Pomona Member.

Barnett, D. Brent; Fecht, Karl R.; Reidel, Stephen P.; Bjornstad, Bruce N.; Lanigan, David C.; Rust, Colleen F.

2007-05-11T23:59:59.000Z

370

Idaho's Advanced Mixed Waste Treatment Project Details 2013Accomplish...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Treatment Project Details 2013 Accomplishments December 24, 2013 - 12:00pm Addthis IDAHO FALLS, Idaho - EM and its contractor, Idaho Treatment Group (ITG), safely and...

371

Development and demonstration of treatment technologies for the processing of US Department of Energy mixed waste  

SciTech Connect

Mixed waste is defined as waste contaminated with chemically hazardous (governed by the Resource Conservation and Recovery Act) and radioactive species [governed by US Department of Energy (DOE) orders]. The Mixed Waste Integrated Program (MWIP) is responding to the need for DOE mixed waste treatment technologies that meet these dual regulatory requirements. MWIP is developing emerging and innovative treatment technologies to determine process feasibility. Technology demonstrations will be used to determine whether processes are superior to existing technologies in reducing risk, minimizing life-cycle cost, and improving process performance. The Program also provides a forum for stakeholder and customer involvement in the technology development process. MWIP is composed of six technical areas that support a mixed-waste treatment system: (1) systems analysis, (2) materials handling, (3) chemical/physical separation, (4) waste destruction and stabilization, (5) off-gas treatment, and (6) final waste form stabilization. The status of the technical initiatives and the current research, development, and demonstration in each of these areas is described in this paper.

Berry, J.B.; Bloom, G.A. [Oak Ridge National Lab., TN (United States); Kuchynka, D.J. [Science Applications International Corp., Gaithersburg, MD (United States)

1994-06-01T23:59:59.000Z

372

Secondary Waste Forms and Technetium Management  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Secondary Waste Forms and Secondary Waste Forms and Technetium Management Joseph H. Westsik, Jr. Pacific Northwest National Laboratory EM HLW Corporate Board Meeting November 18, 2010 What are Secondary Wastes? Process condensates and scrubber and/or off-gas treatment liquids from the pretreatment and ILAW melter facilities at the Hanford WTP. Sent from WTP to the Effluent Treatment Facility (ETF) for treatment and disposal Treated liquid effluents under the ETF State Wastewater Discharge Permit Solidified liquid effluents under the Dangerous Waste Permit for disposal at the Integrated Disposal Facility (IDF) Solidification Treatment Unit to be added to ETF to provide capacity for WTP secondary liquid wastes 2 Evaporator Condensate Solution Evaporator Pretreatment Melter SBS/ WESP Secondary

373

Characterization and monitoring of 300 Area facility liquid waste streams: 1994 Annual report  

Science Conference Proceedings (OSTI)

This report summarizes the results of characterizing and monitoring the following sources during calendar year 1994: liquid waste streams from Buildings 306, 320, 324, 326, 331, and 3720 in the 300 Area of Hanford Site and managed by the Pacific Northwest Laboratory; treated and untreated Columbia River water (influent); and water at the confluence of the waste streams (that is, end-of-pipe). Data were collected from March to December before the sampling system installation was completed. Data from this initial part of the program are considered tentative. Samples collected were analyzed for chemicals, radioactivity, and general parameters. In general, the concentrations of chemical and radiological constituents and parameters in building wastewaters which were sampled and analyzed during CY 1994 were similar to historical data. Exceptions were the occasional observances of high concentrations of chloride, nitrate, and sodium that are believed to be associated with excursions that were occurring when the samples were collected. Occasional observances of high concentrations of a few solvents also appeared to be associated with infrequent building r eases. During calendar year 1994, nitrate, aluminum, copper, lead, zinc, bis(2-ethylhexyl) phthalate, and gross beta exceeded US Environmental Protection Agency maximum contaminant levels.

Riley, R.G.; Ballinger, M.Y.; Damberg, E.G.; Evans, J.C.; Julya, J.L.; Olsen, K.B.; Ozanich, R.M.; Thompson, C.J.; Vogel, H.R.

1995-04-01T23:59:59.000Z

374

DNFSB Recommendation 2010-2, Pulse Jet Mixing at the Waste Treatment and Immobilization Plant WTP  

NLE Websites -- All DOE Office Websites (Extended Search)

DNFSB Rec. 2010-2, Rev.0, Nov.10, 2011 DNFSB Rec. 2010-2, Rev.0, Nov.10, 2011 i Department of Energy Plan to Address Waste Treatment and Immobilization Plant Vessel Mixing Issues Revision 0 Implementation Plan for Defense Nuclear Safety Board Recommendation 2010-2 November 10, 2011 DNFSB Rec. 2010-2, Rev.0, Nov.10, 2011 ii EXECUTIVE SUMMARY On December 17, 2010, the Defense Nuclear Facilities Safety Board (DNFSB) issued Recommendation 2010-2, Pulse Jet Mixing at the Waste Treatment and Immobilization Plant. The recommendation addressed the need for the U.S. Department of Energy (DOE) to ensure that the Hanford Waste Treatment and Immobilization Plant (WTP), in conjunction with the Hanford tank farm waste feed delivery system, will operate safely and effectively during a

375

Hanford Facility Dangerous Waste Permit Application, 200 Area Effluent Treatment Facility  

Science Conference Proceedings (OSTI)

The 200 Area Effluent Treatment Facility Dangerous Waste Permit Application documentation consists of both Part A and a Part B permit application documentation. An explanation of the Part A revisions associated with this treatment and storage unit, including the current revision, is provided at the beginning of the Part A section. Once the initial Hanford Facility Dangerous Waste Permit is issued, the following process will be used. As final, certified treatment, storage, and/or disposal unit-specific documents are developed, and completeness notifications are made by the US Environmental Protection Agency and the Washington State Department of Ecology, additional unit-specific permit conditions will be incorporated into the Hanford Facility Dangerous Waste Permit through the permit modification process. All treatment, storage, and/or disposal units that are included in the Hanford Facility Dangerous Waste Permit Application will operate under interim status until final status conditions for these units are incorporated into the Hanford Facility Dangerous Waste Permit. The Hanford Facility Dangerous Waste Permit Application, 200 Area Effluent Treatment Facility contains information current as of May 1, 1993.

Not Available

1993-08-01T23:59:59.000Z

376

Surveillance and maintenance plan for the inactive liquid low-level waste tanks at Oak Ridge National Laboratory  

Science Conference Proceedings (OSTI)

ORNL has a total of 54 inactive liquid low-level waste (ILLLW) tanks. In the past, these tanks were used to contain radioactive liquid wastes from various research programs, decontamination operations, and reactor operations. The tanks have since been removed from service for various reasons; the majority were retired because of their age, some due to integrity compromises, and others because they did not meet the current standards set by the Federal Facilities Agreement (FFA). Many of the tanks contain residual radioactive liquids and/or sludges. Plans are to remediate all tanks; however, until remediation of each tank, this Surveillance and Maintenance (S&M) Plan will be used to monitor the safety and inventory containment of these tanks.

Not Available

1994-11-01T23:59:59.000Z

377

Electrolytic Treatment of ICPP Sodium-Bearing Waste Simulant  

SciTech Connect

Two proof-of-principle tests were conducted to determine if nitrate can be destroyed electrochemically in a simulated Idaho Chemical Processing Plant (ICPP) Sodium-Bearing waste. Both tests demonstrated the destruction of nitrate as well as the removal of other metals in the simulant. Metals removal is believed to be due to precipitation as a result of a change in the pH of the waste solution from strongly acidic to highly alkaline and reduction to a metal or metal oxide. Although gas evolution at the cathode was visible during each test, there were no visible signs of NO{sub x} formation in either test.

Hobbs, D.T.

1995-02-02T23:59:59.000Z

378

Treatment plan for aqueous/organic/decontamination wastes under the Oak Ridge Reservation FFCA Development, Demonstration, Testing, and Evaluation Program  

SciTech Connect

The U.S. Department of Energy (DOE) Oak Ridge Operations Office and the U.S. Environmental Protection Agency (EPA)-Region IV have entered into a Federal Facility Compliance Agreement (FFCA) which seeks to facilitate the treatment of low-level mixed wastes currently stored at the Oak Ridge Reservation (ORR) in violation of the Resource, Conservation and Recovery Act Land Disposal Restrictions. The FFCA establishes schedules for DOE to identify treatment for wastes, referred to as Appendix B wastes, that current have no identified or existing capacity for treatment. A development, demonstration, testing, and evaluation (DDT&E) program was established to provide the support necessary to identify treatment methods for mixed was meeting the Appendix B criteria. The Program has assembled project teams to address treatment development needs for major categories of the Appendix B wastes based on the waste characteristics and possible treatment technologies. The Aqueous, Organic, and Decontamination (A/O/D) project team was established to identify pretreatment options for aqueous and organic wastes which will render the waste acceptable for treatment in existing waste treatment facilities and to identify the processes to decontaminate heterogeneous debris waste. In addition, the project must also address the treatment of secondary waste generated by other DDT&E projects. This report details the activities to be performed under the A/O/D Project in support of the identification, selection, and evaluation of treatment processes. The goals of this plan are (1) to determine the major aqueous and organic waste streams requiring treatment, (2) to determine the treatment steps necessary to make the aqueous and organic waste acceptable for treatment in existing treatment facilities on the ORR or off-site, and (3) to determine the processes necessary to decontaminate heterogeneous wastes that are considered debris.

Backus, P.M.; Benson, C.E.; Gilbert, V.P.

1994-08-01T23:59:59.000Z

379

Understanding Cement Waste Forms  

Science Conference Proceedings (OSTI)

Oct 29, 2009 ... Ongoing nuclear operations, decontamination and decommissioning, salt waste disposal, and closure of liquid waste tanks result in ...

380

Use of the Environmental Simulation Program (ESP) to Simulate Complex Waste Treatment Processes  

Science Conference Proceedings (OSTI)

The Environmental Simulation Program is a process simulator designed for aqueous based chemical processes. ESP, which is produced by OLI Systems, Inc., utilizes sophisticated activity coefficient models and predictive equations that result in the ability to simulate very complex electrolyte systems (OLI, 2002). The software comes with databanks of regressed parameters for a large number of aqueous, vapor, and solid species covering most of the elements. ESP has been used extensively at the U. S. Department of Energy Hanford Site to predict nuclear waste slurry vapor-liquid-solid equilibrium. It has and is being used to model leaching and washing of nuclear waste sludges, evaporation of nuclear waste solutions, crystallization of salts, precipitation of plutonium and other metals from waste solutions, and other processing of dilute and concentrated aqueous solutions, sludges, and slurries. The software is also used extensively to rationalize the characterization of nuclear wastes using limited data from analyses of waste samples. The OLI provided databanks suffer from a legacy interaction model that limits the accuracy when neutral solutes are important. Also, the nitrate-nitrite systems typically found in nuclear wastes are not properly parameterized in ESP databases because of the existence of sodium nitrate and nitrite ion pairs. Properties databanks for ESP have been developed at Flour Federal Services that eliminate the legacy model and provide more accurate simulation results than the OLI supplied databases for such concentrated solutions and slurries.

MacLean, G. T.; Ho, Q. T.; Berger, S. R. K.

2003-02-26T23:59:59.000Z

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381

Advanced Mixed Waste Treatment Project melter system preliminary design technical review meeting  

SciTech Connect

The Idaho National Engineering Laboratory Advanced Mixed Waste Treatment Project sponsored a plasma are melter technical design review meeting to evaluate high-temperature melter system configurations for processing heterogeneous alpha-contaminated low-level radioactive waste (ALLW). Thermal processing experts representing Department of Energy contractors, the Environmental Protection Agency, and private sector companies participated in the review. The participants discussed issues and evaluated alternative configurations for three areas of the melter system design: plasma torch melters and graphite arc melters, offgas treatment options, and overall system configuration considerations. The Technical Advisory Committee for the review concluded that graphite arc melters are preferred over plasma torch melters for processing ALLW. Initiating involvement of stakeholders was considered essential at this stage of the design. For the offgas treatment system, the advisory committee raised the question whether to a use wet-dry or a dry-wet system. The committee recommended that the waste stream characterization, feed preparation, and the control system are essential design tasks for the high-temperature melter treatment system. The participants strongly recommended that a complete melter treatment system be assembled to conduct tests with nonradioactive surrogate waste material. A nonradioactive test bed would allow for inexpensive design and operational changes prior to assembling a system for radioactive waste treatment operations.

Eddy, T.L.; Raivo, B.D.; Soelberg, N.R.; Wiersholm, O.

1995-02-01T23:59:59.000Z

382

Integrated demonstration of molten salt oxidation with salt recycle for mixed waste treatment  

Science Conference Proceedings (OSTI)

Molten Salt Oxidation (MSO) is a thermal, nonflame process that has the inherent capability of completely destroying organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. Lawrence Livermore National Laboratory (LLNL) has prepared a facility and constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are performed under carefully controlled (experimental) conditions. The system consists of a MSO processor with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. This integrated system was designed and engineered based on laboratory experience with a smaller engineering-scale reactor unit and extensive laboratory development on salt recycle and final forms preparation. In this paper we present design and engineering details of the system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is identification of the most suitable waste streams and waste types for MSO treatment.

Hsu, P.C.

1997-11-01T23:59:59.000Z

383

Activated carbon: Utilization excluding industrial waste treatment. (Latest citations from the Compendex database). Published Search  

SciTech Connect

The bibliography contains citations concerning the commercial use and theoretical studies of activated carbon. Topics include performance evaluations in water treatment processes, preparation and regeneration techniques, materials recovery, and pore structure studies. Adsorption characteristics for specific materials are discussed. Studies pertaining specifically to industrial waste treatment are excluded. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1993-06-01T23:59:59.000Z

384

HWMA/RCRA Closure Plan for the CPP-648 Radioactive Solid and Liquid Waste Storage Tank System (VES-SFE-106)  

Science Conference Proceedings (OSTI)

This Hazardous Waste Management Act/Resource Conservation and Recovery Act closure plan for the Radioactive Solid and Liquid Waste Storage Tank System located in the adjacent to the Sludge Tank Control House (CPP-648), Idaho Nuclear Technology and Engineering Center, Idaho National Laboratory, was developed to meet the interim status closure requirements for a tank system. The system to be closed includes a tank and associated ancillary equipment that were determined to have managed hazardous waste. The CPP-648 Radioactive Solid and Liquid Waste Storage Tank System will be "cleaned closed" in accordance with the requirements of the Hazardous Waste Management Act/Resource Conservation and Recovery Act as implemented by the Idaho Administrative Procedures Act and 40 Code of Federal Regulations 265. This closure plan presents the closure performance standards and methods of acheiving those standards for the CPP-648 Radioactive Solid and Liquid Waste Storage Tank System.

S. K. Evans

2006-08-15T23:59:59.000Z

385

Advanced Mixed Waste Treatment Project, Design, Construction and Start-up  

Science Conference Proceedings (OSTI)

The Advanced Mixed Waste Treatment Project (AMWTP) was awarded to BNG America in December of 1996. In 2005, following discussions between the United States (US) Department of Energy (DOE) and the United Kingdom (UK) Department of Trade and Industry (DTi) the DOE purchased the facilities. DOE awarded Bechtel B and W Idaho (BBWI) a contract to operate the facilities for one year, commencing 1 May 2005. The hand-over of AMWTP included the facility to repackage and super-compact waste (Advanced Mixed Waste Treatment Facility) and the retrieval, characterization, storage and Transuranic Package Transporter (TRUPACT) loading facility. This poster updates the progress of AMWTP from the previous presentations to Waste Management (WM) [1 and 2] to completion of the transition to BBWI in May 2005. (authors)

Dobson, A. [BNG America, 2345 Stevens Drive Suite no. 240, Richland, WA 99354 (United States); Harrop, G.; Holmes, R.G.G. [BNG America, 1920 E. 17th Street Suite no. 200, Idaho Falls, ID 83404 (United States)

2006-07-01T23:59:59.000Z

386

Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form  

SciTech Connect

The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

2011-09-12T23:59:59.000Z

387

TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS  

Science Conference Proceedings (OSTI)

Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

James T. Cobb, Jr.

2003-09-12T23:59:59.000Z

388

Integrated process analysis of treatment systems for mixed low level waste  

SciTech Connect

Selection of technologies to be developed for treatment of DOE`s mixed low level waste (MLLW) requires knowledge and understanding of the expected costs, schedules, risks, performance, and reliability of the total engineered systems that use these technologies. Thus, an integrated process analysis program was undertaken to identify the characteristics and needs of several thermal and nonthermal systems. For purposes of comparison, all systems were conceptually designed for a single facility processing the same amount of waste at the same rate. Thirty treatment systems were evaluated ranging from standard incineration to innovative thermal systems and innovative nonthermal chemical treatment. Treating 236 million pounds of waste in 20 years through a central treatment was found to be the least costly option with total life cycle cost ranging from $2.1 billion for a metal melting system to $3.9 billion for a nonthermal acid digestion system. Little cost difference exists among nonthermal systems or among thermal systems. Significant cost savings could be achieved by working towards maximum on line treatment time per year; vitrifying the final waste residue; decreasing front end characterization segregation and sizing requirements; using contaminated soil as the vitrifying agent; and delisting the final vitrified waste form from Resource Conservation and Recovery Act (RCRA) Land Disposal Restriction (LDR) requirements.

Cooley, C.R. [Dept. of Energy, Washington, DC (United States); Schwinkendorf, W.E. [Lockheed Martin Idaho Technology Co., Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.]|[Sandia National Labs., Albuquerque, NM (United States); Bechtold, T.E. [Lockheed Martin Idaho Technology Co., Idaho Falls, ID (United States). Idaho National Engineering and Environmental Lab.

1997-10-01T23:59:59.000Z

389

INITIAL SELECTION OF SUPPLEMENTAL TREATMENT TECHNOLOGIES FOR HANFORDS LOW ACTIVITY TANK WASTE  

SciTech Connect

In 2002, the U.S. Department of Energy (DOE) documented a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified specific technologies to be evaluated for supplemental treatment of as much as 70% of the low-activity waste (LAW). In concert with this acceleration plan, DOE, the U.S. Environmental Protection Agency, and the Washington State Department of Ecology proposed to accelerate--from 2014 to 2006--the Hanford Federal Facility Agreement and Consent Order milestone (M-62-11) associated with a final decision on the balance of tank waste that is beyond the capacity of the WTP. The DOE Office of River Protection tank farm contractor, CH2M HILL Hanford Group, Inc. (CH2M HILL), was tasked with testing and evaluating selected supplemental technologies to support final decisions on tank waste treatment. Three technologies and corresponding vendors were selected to support an initial technology selection in 2003. The three technologies were containerized grout called cast stone (Fluor Federal Services); bulk vitrification (AMEC Earth and Environmental, Inc.); and steam reforming (THOR Treatment Technologies, LLC.). The cast stone process applies an effective grout waste formulation to the LAW and places the cement-based product in a large container for solidification and disposal. Unlike the WTP LAW treatment, which applies vitrification within continuous-fed joule-heated ceramic melters, bulk vitrification produces a glass waste form using batch melting within the disposal container. Steam reforming produces a granular denitrified mineral waste form using a high-temperature fluidized bed process. An initial supplemental technology selection was completed in December 2003, enabling DOE and CH2M HILL to focus investments in 2004 on the testing and production-scale demonstrations needed to support the 2006 milestone.

RAYMOND, R.E.

2004-02-20T23:59:59.000Z

390

High Level Waste Remote Handling Equipment in the Melter Cave Support Handling System at the Hanford Waste Treatment Plant  

SciTech Connect

Cold war plutonium production led to extensive amounts of radioactive waste stored in tanks at the Department of Energy's (DOE) Hanford site. Bechtel National, Inc. is building the largest nuclear Waste Treatment Plant in the world located at the Department of Energy's Hanford site to immobilize the millions of gallons of radioactive waste. The site comprises five main facilities; Pretreatment, High Level Waste vitrification, Low Active Waste vitrification, an Analytical Lab and the Balance of Facilities. The pretreatment facilities will separate the high and low level waste. The high level waste will then proceed to the HLW facility for vitrification. Vitrification is a process of utilizing a melter to mix molten glass with radioactive waste to form a stable product for storage. The melter cave is designated as the High Level Waste Melter Cave Support Handling System (HSH). There are several key processes that occur in the HSH cell that are necessary for vitrification and include: feed preparation, mixing, pouring, cooling and all maintenance and repair of the process equipment. Due to the cell's high level radiation, remote handling equipment provided by PaR Systems, Inc. is required to install and remove all equipment in the HSH cell. The remote handling crane is composed of a bridge and trolley. The trolley supports a telescoping tube set that rigidly deploys a TR 4350 manipulator arm with seven degrees of freedom. A rotating, extending, and retracting slewing hoist is mounted to the bottom of the trolley and is centered about the telescoping tube set. Both the manipulator and slewer are unique to this cell. The slewer can reach into corners and the manipulator's cross pivoting wrist provides better operational dexterity and camera viewing angles at the end of the arm. Since the crane functions will be operated remotely, the entire cell and crane have been modeled with 3-D software. Model simulations have been used to confirm operational and maintenance functional and timing studies throughout the design process. Since no humans can go in or out of the cell, there are several recovery options that have been designed into the system including jack-down wheels for the bridge and trolley, recovery drums for the manipulator hoist, and a wire rope cable cutter for the slewer jib hoist. If the entire crane fails in cell, the large diameter cable reel that provides power, signal, and control to the crane can be used to retrieve the crane from the cell into the crane maintenance area. (authors)

Bardal, M.A. [PaR Systems, Inc., Shoreview, MN (United States); Darwen, N.J. [Bechtel National, Inc., Richland, WA (United States)

2008-07-01T23:59:59.000Z

391

Land Disposal Restrictions Treatment Standards: Compliance Strategies for Four Types of Mixed Wastes  

Science Conference Proceedings (OSTI)

This paper describes the unique challenges involved in achieving compliance with the Resource Conservation and Recovery Act (Public Law 94-580) Land Disposal Restrictions (LDR) treatment standards for four types of mixed wastes generated throughout the U.S. Department of Energy (DOE) complex: (1) radioactively contaminated lead acid batteries; (2) radioactively contaminated cadmium-, mercury-, and silver-containing batteries; (3) mercury-bearing mixed wastes; and (4) radioactive lead solids. For each of these mixed waste types, the paper identifies the strategy pursued by DOE's Office of Pollution Prevention and Resource Conservation Policy and Guidance (EH-43) in coordination with other DOE elements and the U.S. Environmental Protection Agency (EPA) to meet the compliance challenge. Specifically, a regulatory interpretation was obtained from EPA agreeing that the LDR treatment standard for wastes in the D008 'Radioactive Lead Solids' sub-category applies to radioactively contaminated lead acid batteries. For cadmium-, mercury-, and silver-containing batteries, generically applicable treatability variances were obtained from EPA approving macro-encapsulation as the alternative LDR treatment standard for all three battery types. Joint DOE/EPA technology demonstrations were pursued for mercury-bearing mixed wastes in an effort to justify revising the LDR treatment standards, which focus on thermal recovery of mercury for reuse. Because the demonstrations failed to produce enough supporting data for a rulemaking, however, EPA has recommended site-specific treatability variances for particular mercury-bearing mixed waste streams. Finally, DOE has filed an application for a determination of equivalent treatment requesting approval of container-based macro-encapsulation technologies as an alternative LDR treatment standard for radioactive lead solids. Information is provided concerning the length of time required to implement each of these strategies, and suggestions for obtaining variances from the LDR treatment standards at the site-specific level are also discussed. (authors)

Fortune, W.B. [U.S, Department of Energy, Office of Pollution Prevention and Resource Conservation (EH-43), 1000 Independence Ave., S.W., Washington, DC 20585 (United States); Ranek, N.L. [Argonne National Laboratory, Environmental Science Division, 955 L'Enfant Plaza North, Suite 6000, Washington, DC 20024 (United States)

2006-07-01T23:59:59.000Z

392

The Treatment of Mixed Waste with GeoMelt In-Container Vitrification  

SciTech Connect

AMEC's GeoMelt{sup R} In-Container Vitrification (ICV){sup TM} has been used to treat diverse types of mixed low-level radioactive waste. ICV is effective in the treatment of mixed wastes containing polychlorinated biphenyls (PCBs) and other semi-volatile organic compounds, volatile organic compounds (VOCs) and heavy metals. The GeoMelt vitrification process destroys organic compounds and immobilizes metals and radionuclides in an extremely durable glass waste form. The process is flexible allowing for treatment of aqueous, oily, and solid mixed waste, including contaminated soil. In 2004, ICV was used to treat mixed radioactive waste sludge containing PCBs generated from a commercial cleanup project regulated by the Toxic Substances Control Act (TSCA), and to treat contaminated soil from Rocky Flats Environmental Technology Site. The Rocky Flats soil contained cadmium, PCBs, and depleted uranium. In 2005, AMEC completed a treatability demonstration of the ICV technology on Mock High Explosive from Sandia National Laboratories. This paper summarizes results from these mixed waste treatment projects. (authors)

Finucane, K.G.; Campbell, B.E. [AMEC Earth and Environmental, Inc., 1135 Jadwin Avenue, Richland, Washington 99352 (United States)

2006-07-01T23:59:59.000Z

393

Characterizing the transformation and transfer of nitrogen during the aerobic treatment of organic wastes and digestates  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Ammonia emissions varied depending on the nature of wastes and the treatment conditions. Black-Right-Pointing-Pointer Nitrogen losses resulted from ammonia emissions and nitrification-denitrification. Black-Right-Pointing-Pointer Ammonification can be estimated from biodegradable carbon and carbon/nitrogen ratio. Black-Right-Pointing-Pointer Ammonification was the main process contributing to N losses. Black-Right-Pointing-Pointer Nitrification rate was negatively correlated to stripping rate of ammonia nitrogen. - Abstract: The transformation and transfer of nitrogen during the aerobic treatment of seven wastes were studied in ventilated air-tight 10-L reactors at 35 Degree-Sign C. Studied wastes included distinct types of organic wastes and their digestates. Ammonia emissions varied depending on the kind of waste and treatment conditions. These emissions accounted for 2-43% of the initial nitrogen. Total nitrogen losses, which resulted mainly from ammonia emissions and nitrification-denitrification, accounted for 1-76% of the initial nitrogen. Ammonification was the main process responsible for nitrogen losses. An equation which allows estimating the ammonification flow of each type of waste according to its biodegradable carbon and carbon/nitrogen ratio was proposed. As a consequence of the lower contribution of storage and leachate rates, stripping and nitrification rates of ammonia nitrogen were negatively correlated. This observation suggests the possibility of promotingnitrification in order to reduce ammonia emissions.

Zeng Yang, E-mail: yang.zeng@irstea.fr [Irstea, UR GERE, 17 avenue de Cucille, CS 64427, F-35044 Rennes Cedex (France); Universite Europeenne de Bretagne, F-35000 Rennes (France); Guardia, Amaury de; Daumoin, Mylene; Benoist, Jean-Claude [Irstea, UR GERE, 17 avenue de Cucille, CS 64427, F-35044 Rennes Cedex (France)

2012-12-15T23:59:59.000Z

394

Mixed-waste treatment -- What about the residuals? A comparative analysis of MSO and incineration  

SciTech Connect

This report examines the issues concerning final waste forms, or residuals, that result from the treatment of mixed waste in molten salt oxidation (MSO) and incinerator systems. MSO is a technology with the potential to treat a certain segment of the waste streams at US Department of Energy (DOE) sites. MSO was compared with incineration because incineration is the best demonstrated available technology (BDAT) for the same waste streams. The Grand Junction Projects Office (GJPO) and Oak Ridge National Laboratory (ORNL) prepared this report for the DOE Office of Environmental Restoration (OER). The goals of this study are to objectively evaluate the anticipated residuals from MSO and incineration, examine regulatory issues for these final waste forms, and determine secondary treatment options. This report, developed to address concerns that MSO residuals present unique disposal difficulties, is part of a larger effort to successfully implement MSO as a treatment technology for mixed and hazardous waste. A Peer Review Panel reviewed the MSO technology in November 1991, and the implementation effort is ongoing under the guidance of the MSO Task Force.

NONE

1993-06-01T23:59:59.000Z

395

Environmental assessment for the Waste Water Treatment Facility at the West Valley Demonstration Project and finding of no significant impact  

SciTech Connect

The possible environmental impacts from the construction and operation of a waste water treatment facility for the West Valley Demonstration Project are presented. The West Valley Project is a demonstration project on the solidification of high-level radioactive wastes. The need for the facility is the result of a rise in the work force needed for the project which rendered the existing sewage treatment plant incapable of meeting the nonradioactive waste water treatment needs.

1992-12-31T23:59:59.000Z

396

Independent peer review panel report on the integrated nonthermal treatment systems study and the comparison of integrated thermal and integrated nonthermal treatment systems for mixed low level waste  

SciTech Connect

The US Department of Energy`s (DOE) Office of Environmental Management (EM) Office of Science and Technology (OST) has conducted studies of integrated thermal treatment systems and integrated nonthermal treatment systems (INTS) for treating contact handled, alpha and non-alpha mixed low level radioactive waste (MLLW). The MLLW in the DOE complex consists of a wide variety of organic and inorganic solids and liquids contaminated with radioactive substances. Treatment systems are needed to destroy organic material and stabilize residues prior to land disposal. In May 1996 the Deputy Assistant Secretary for OST appointed an Independent Peer Review Panel to: (1) review and comment on the INTS Study; (2) make recommendations on the most promising thermal and nonthermal treatment systems; (3) make recommendations on research and development necessary to prove the performance of nonthermal and thermal technologies; and (4) review and comment on the preliminary draft of the ITTS/INTS Comparison Report. This report presents the primary conclusions and recommendations based on the review of the INTS study and the comparison report. System selection, overviews, comparisons, cost estimations and sensitivity analyses, and recommended R and D engineering needs are then described and discussed.

1996-08-01T23:59:59.000Z

397

Progress and Lessons Learned in Transuranic Waste Disposition at The Department of Energy's Advanced Mixed Waste Treatment Project  

SciTech Connect

This paper provides an overview of the Department of Energy's (DOE) Advanced Mixed Waste Treatment Project (AMWTP) located at the Idaho National Laboratory (INL) and operated by Bechtel BWXT Idaho, LLC(BBWI) It describes the results to date in meeting the 6,000-cubic-meter Idaho Settlement Agreement milestone that was due December 31, 2005. The paper further describes lessons that have been learned from the project in the area of transuranic (TRU) waste processing and waste certification. Information contained within this paper would be beneficial to others who manage TRU waste for disposal at the Waste Isolation Pilot Plant (WIPP).

J.D. Mousseau; S.C. Raish; F.M. Russo

2006-05-18T23:59:59.000Z

398

The Department of Energy's $12.2 Billion Waste Treatment and Immobilization Plant - Quality Assurance Issues  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

The Department of Energy's $12.2 Billion The Department of Energy's $12.2 Billion Waste Treatment and Immobilization Plant - Quality Assurance Issues - Black Cell Vessels DOE/IG-0863 April 2012 U.S. Department of Energy Office of Inspector General Office of Audits and Inspections Department of Energy Washington, DC 20585 April 25, 2012 MEMORANDUM FOR THE SECRETARY FROM: Gregory H. Friedman Inspector General SUBJECT: INFORMATION: Audit Report on "The Department of Energy's $12.2 Billion Waste Treatment and Immobilization Plant - Quality Assurance Issues - Black Cell Vessels" INTRODUCTION The Office of Inspector General received allegations concerning aspects of the quality assurance program at the Department of Energy's $12.2 billion Waste Treatment and Immobilization Plant

399

Membrane filtration waste treatment technology comes of age in battery manufacturing plants  

SciTech Connect

A new waste treatment system from MEMTEK Corporation incorporates membrane filtration, and makes possible the effective treatment of waste streams containing a number of toxic heavy metals. Using this membrane technology, MEMTEK is capable of treating the wastewater in battery manufacturing plants to meet even the strictest limits imposed by local regulatory agencies and the Environmental Protection Agency (EPA). Lead and zinc in the treated effluent are typically below 0.1 ppm. The typical battery manufacturing processes introduce metals, primarily lead, into plant effluents, especially from formation, battery wash, and laundry operation. Due to the high usage of acid in the plant, the wastewater is also usually of a low pH, typically 2