National Library of Energy BETA

Sample records for liquid refinery gases

  1. Refinery Yield of Liquefied Refinery Gases

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Liquefied Refinery Gases Finished Motor Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Residual Fuel Oil Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Still Gas Miscellaneous Products Processing Gain(-) or Loss(+) Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources

  2. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  3. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  4. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  5. Emission factors for leaks in refinery components in heavy liquid service

    SciTech Connect (OSTI)

    Taback, H.; Godec, M.

    1996-12-31

    The objective of this program was to provide sufficient screening data so that EPA can develop an official set of emission factors (expressed in lb/hr/component) for refinery components (valves, flanged connectors, non-flanged connectors, pumps, open-ended lines, and other) in heavy liquid (BL) service. To accomplish this, 211,000 existing HL screening values from Southern California refineries were compiled and compared with 2,500 new HL screening measurements taken at two refineries in the state of Washington. Since Southern California is an area in extreme non-attainment of the National Ambient Air Quality Standards (NAAQS) and therefore has tight emission control regulations, it was felt that its screening data may not be representative of refineries without tight emission controls. Thus, the Southern California screening data were compared to screening measurements at refineries in an area that is in attainment of the NAAQS and without emissions control, which is the case for those refineries in Washington. It was found that statistically there was no significant difference in emission factors between the two areas and, therefore, there appears to be no difference in emissions from heavy liquid components in areas with and without leak detection and repair (LDAR) programs. The new emission factors range from 1/7 to 1/3 times the current EPA emission factors. This program was sponsored by the American Petroleum Institute (API) and an API report will soon be released providing complete details.

  6. Refining and end use study of coal liquids. Topical report: Petroleum Refinery; Linear Programming Model; and Design Basis

    SciTech Connect (OSTI)

    1995-03-01

    A model was developed for use in the Bechtel PIMS (Process Industry Modeling System) linear programming software to simulate a generic Midwest (PADD II) petroleum refinery of the future. This ``petroleum-only`` version of the model establishes the size and complexity of the refinery after the year 2000 and prior to the introduction of coal liquids. It should be noted that no assumption has been made on when a plant can be built to produce coal liquids except that it will be after the year 2000. The year 2000 was chosen because it is the latest year where fuel property and emission standards have been set by the Environmental Protection Agency. It assumes the refinery has been modified to accept crudes that are heavier in gravity and higher in sulfur than today`s average crude mix. In addition, the refinery has also been modified to produce a product slate of transportation fuels of the future (i.e. 40% reformulated gasolines). This model will be used as a basis for determining the optimum scheme for processing coal liquids in a petroleum refinery. This report summarizes the design basis for this ``petroleum only`` LP refinery model. A report detailing the refinery configuration when coal liquids are processed will be provided at a later date.

  7. Energetic Materials for EGS Well Stimulation (solids, liquids, gases)

    Broader source: Energy.gov [DOE]

    Energetic Materials for EGS Well Stimulation (solids, liquids, gases) presentation at the April 2013 peer review meeting held in Denver, Colorado.

  8. Separation of petroleum refinery wastes from a landfill by liquid chromatography

    SciTech Connect (OSTI)

    Mazzocco, D.L.; Willis, W.V.

    1995-12-01

    Large amounts of acidic petroleum refinery wastes (PRW) have been buried in landfills during the period 1930-1950. Many of the compounds IN PRW have not identified. Organosulfur compounds constitute an important fraction of these wastes, and are significant in site closure planning and cleanup operations. Some are difficult analytes because they undergo facile conversions during standard methods of sample preparation and analysis. A mild liquid chromatographic method using cyanopropyl and octadecyl stationary phases and a modified hexane mobile phase was found to separate PRW into five major groups, two of which contain sulfur compounds. GC/MS analysis of collected HPLC fractions identified over 80% of the compounds present. Wastes from three different landfills used in the period 1940-1950 show major similarities, but differ in relative composition. Implications for remediation of PRW in these and similar landfills designated as Superfund sites are discussed.

  9. Refinery & Blenders Net Input of Crude Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils,

  10. Photosensitive dopants for liquid noble gases

    DOE Patents [OSTI]

    Anderson, David F.

    1988-01-01

    In an ionization type detector for high energy radiation wherein the energy of incident radiation is absorbed through the ionization of a liquid noble gas and resulting free charge is collected to form a signal indicative of the energy of the incident radiation, an improvement comprising doping the liquid noble gas with photosensitive molecules to convert scintillation light due to recombination of ions, to additional free charge.

  11. Photoelectron spectrometer for attosecond spectroscopy of liquids and gases

    SciTech Connect (OSTI)

    Jordan, I.; Huppert, M.; Wörner, H. J.; Brown, M. A.; Bokhoven, J. A. van

    2015-12-15

    A new apparatus for attosecond time-resolved photoelectron spectroscopy of liquids and gases is described. It combines a liquid microjet source with a magnetic-bottle photoelectron spectrometer and an actively stabilized attosecond beamline. The photoelectron spectrometer permits venting and pumping of the interaction chamber without affecting the low pressure in the flight tube. This pressure separation has been realized through a sliding skimmer plate, which effectively seals the flight tube in its closed position and functions as a differential pumping stage in its open position. A high-harmonic photon spectrometer, attached to the photoelectron spectrometer, exit port is used to acquire photon spectra for calibration purposes. Attosecond pulse trains have been used to record photoelectron spectra of noble gases, water in the gas and liquid states as well as solvated species. RABBIT scans demonstrate the attosecond resolution of this setup.

  12. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  13. Refinery Integration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mary Biddy Sue Jones NREL PNNL This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Refinery Integration 4.1.1.31 NREL 4.1.1.51 PNNL Goal Statement GOALS: Model bio-intermediates insertion points to better define costs & ID opportunities, technical risks, information gaps, research needs Publish results Review with stakeholders 2 Leveraging existing refining infrastructure

  14. Improved Laser Induced Breakdown Spectroscopy (LIBS) Elemental Composition Detection System: A device to measure subsurface gases, liquids, and solids at subsurface conditions

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2016-02-23

    This device can measure subsurface gases, liquids, and solids at subsurface conditions. Atomic identification and concentration measurements can be made on solids, liquids, and gases at down hole pressure and temperature conditions....

  15. U.S. Refinery Yield

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquefied Refinery Gases 2.8 2.0 2.0 2.1 2.6 4.0 1993-2016 Finished Motor Gasoline 45.7 46.7 47.3 49.3 47.5 46.0 1993-2016 Finished Aviation Gasoline 0.1 0.1 0.1 0.0 0.1 0.1 ...

  16. Storage tracking refinery trends

    SciTech Connect (OSTI)

    Saunders, J.

    1996-05-01

    Regulatory and marketplace shakeups have made the refining and petrochemical industries highly competitive. The fight to survive has forced refinery consolidations, upgrades and companywide restructurings. Bulk liquid storage terminals are following suit. This should generate a flurry of engineering and construction by the latter part of 1997. A growing petrochemical industry translates into rising storage needs. Industry followers forecasted flat petrochemical growth in 1996 due to excessive expansion in 1994 and 1995. But expansion is expected to continue throughout this year on the strength of several products.

  17. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Commodity PAD Districts I II III IV V United States Table 10a. Fuel Consumed at Refineries by PAD District, 2015 (Thousand Barrels, Except Where Noted) Crude Oil 0 0 0 0 0 0 Liquefied Petroleum Gases 0 1,834 309 20 846 3,009 Distillate Fuel Oil 0 26 220 8 110 364 Residual Fuel Oil 20 18 22 2 333 395 Still Gas 15,955 50,290 112,346 8,842 44,613 232,046 Marketable Petroleum Coke 0 0 0 520 90 610 Catalyst Petroleum Coke 8,229 17,001 43,013 2,876 10,891 82,010 Natural Gas (million cubic feet) 48,181

  18. U.S. Refinery & Blender Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Total 545,351 529,373 583,548 564,902 593,799 590,222 1981-2016 Crude Oil 495,806 460,629 499,255 478,254 504,549 492,960 1981-2016 Natural Gas Plant Liquids and Liquefied Refinery Gases 20,717 16,455 15,101 13,489 13,196 12,892 1981-2016 Pentanes Plus 4,878 3,963 4,345 4,213 4,959 4,630 1981-2016 Liquefied Petroleum Gases 15,839 12,492 10,756 9,276 8,237 8,262 1981-2016 Ethane 1981-1992 Normal Butane 9,502 6,776 4,226 2,929 1,957 1,967

  19. U.S. Refinery & Blender Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 6,345,372 6,422,710 6,406,693 6,577,077 6,779,342 6,882,105 1981-2015 Crude Oil 5,374,094 5,404,347 5,489,516 5,589,006 5,784,637 5,915,532 1981-2015 Natural Gas Plant Liquids and Liquefied Refinery Gases 161,479 178,884 186,270 181,112 186,601 188,270 1981-2015 Pentanes Plus 56,686 63,385 63,596 60,394 56,037 53,404 1981-2015 Liquefied Petroleum Gases 104,793 115,499 122,674 120,718 130,564 134,866 1981-2015 Ethane 1981-1992 Normal Butane 43,802

  20. Refinery Capacity Report

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Storage Capacity at Operable Refineries by PAD District as of January 1, 2006 PDF 9 Shell Storage Capacity at Operable Refineries by PAD District as of January 1, 2006 PDF 10...

  1. Elimination of alkanes from off-gases using biotrickling filters containing two liquid phases

    SciTech Connect (OSTI)

    Groenestijn, J.W. van; Lake, M.E.

    1999-09-30

    Biological techniques are highly cost-effective for the treatment of off-gases containing low concentrations of pollutants. They may also be attractive for the elimination of higher concentrations of explosive hydrocarbons. Conventional techniques such as biofilters have low elimination capacities for hydrophobic compounds caused by a poor mass transfer from the gas to the aqueous phase. To overcome solubility problems, a novel biotrickling filter was developed and is characterized by the use of an organic solvent. In such a biotrickling filter, a mixture of an organic solvent and water is continuously trickled over a packed bed, while the polluted gas passes counter-current to the liquid. The microorganisms exist on the packing material and in the circulating liquid. The alkanes are absorbed in the oil phase of the liquid, transferred to the microorganisms and biodegraded. Laboratory-scale experiments at 20 l scale with hexane as a model pollutant and silicon oil as a solvent revealed that a 90% elimination efficiency can be reached at a volumetric loading rate of 100 g hexane per m{sup 3} and had a temperature of 29 C. The method described in this paper can be a cost-effective was to treat gases containing hexane, other alkanes or other strongly hydrophobic compounds. Biological co-oxidation of other biodegradable pollutants from the gas is to be expected.

  2. U.S. Refinery Net Production

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    12,813 12,516 12,287 12,009 12,148 11,916 2005-2014 Liquefied Refinery Gases 623 659 619 630 623 653 2005-2014 EthaneEthylene 19 20 20 18 7 6 2005-2014 Ethane 14 14 14 13 7 5...

  3. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Refinery Capacity Report With Data as of January 1, 2016 | Release Date: June 22, 2016 | Next Release Date: June 23, 2017 Previous Issues Year: 2016 2015 2014 2013 2012 2011 2010 2009 2008 2007 2006 prior issues Go Data series include fuel, electricity, and steam purchased for consumption at the refinery; refinery receipts of crude oil by method of transportation; and current and projected atmospheric crude oil distillation, downstream charge, and production capacities. Respondents are operators

  4. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Former Corporation/Refiner Total Atmospheric Crude Oil Distillation Capacity (bbl/cd) New Corporation/Refiner Date of Sale Table 12. Refinery Sales During 2015 CHS Inc./CHS McPherson Refinery Inc. CHS Inc./NCRA 9/15 McPherson, KS 86,000 PBF Energy Co LLC/Chalmette Refining LLC Chalmette Refining LLC 11/15 Chalmette, LA 192,500 bbl/cd= Barrels per calendar day Sources: Energy Information Administration (EIA) Form EIA-810, "Monthly Refinery Report" and Form EIA-820, "Annual Refinery

  5. Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues

    U.S. Energy Information Administration (EIA) Indexed Site

    Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues Release date: November 25, 2014 Executive summary Over the past five years, rapid growth in U.S. onshore natural gas and oil production has led to increased volumes of natural gas plant liquids (NGPL) and liquefied refinery gases (LRG). The increasing economic importance of these volumes, as a result of their significant growth in production, has revealed the need for better data accuracy and transparency to improve the quality of

  6. Refinery Capacity Report - Explanatory Notes

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration/Refinery Capacity Report 1 Explanatory Notes Survey Methodology Description of Survey Form The Form EIA-820, "Annual Refinery Report," is the primary source of data in the "Refinery Capacity Report" tables. The form collects data on the consumption of purchased steam, electricity, coal, and natural gas; refinery receipts of crude oil by method of transportation; operable capacity for atmospheric crude oil distillation units and downstream

  7. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30

    of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained

  8. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30

    of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in

  9. Hydrogen Generation for Refineries

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ADVANCED MANUFACTURING OFFICE PEER REVIEW MEETING May 5-6, 2014 DE-FG02-08ER85135 Hydrogen Generation for Refineries DOE Phase II SBIR Dr. Girish Srinivas P.I. gsrinivas@tda.com 303-940-2321 Dr. Steven Gebhard, P.E. Dr. Robert Copeland Mr. Jeff Martin TDA Research Inc. 1 This presentation does not contain any proprietary, confidential, or otherwise restricted information This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Overview *

  10. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Idle Operating Total Stream Day Barrels per Idle Operating Total Calendar Day Barrels per Atmospheric Crude Oil Distillation Capacity Idle Operating Total Operable Refineries Number of State and PAD District a b b 9 9 0 1,277,500 1,245,500 32,000 1,353,000 1,318,000 35,000 ............................................................................................................................................... PAD District I 1 1 0 182,200 182,200 0 190,200 190,200 0

  11. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Vacuum State/Refiner/Location Barrels per Atmospheric Crude Oil Distillation Capacity Barrels per Operating Idle Operating Idle Downstream Charge Capacity Thermal Cracking Delayed Fluid Coking Visbreaking Other/Gas Calendar Day Stream Day Distillation Coking Oil Table 3. Capacity of Operable Petroleum Refineries by State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) ......................................................... Alabama 131,675 0 140,500 0 47,000 32,000 0 0 0

  12. Refinery Upgrading of Hydropyrolysis Oil From Biomass

    SciTech Connect (OSTI)

    Roberts, Michael; Marker, Terry; Ortiz-Toral, Pedro; Linck, Martin; Felix, Larry; Wangerow, Jim; Swanson, Dan; McLeod, Celeste; Del Paggio, Alan; Urade, Vikrant; Rao, Madhusudhan; Narasimhan, Laxmi; Gephart, John; Starr, Jack; Hahn, John; Stover, Daniel; Parrish, Martin; Maxey, Carl; Shonnard, David; Handler, Robert; Fan, Jiquig

    2015-08-31

    Cellulosic and woody biomass can be converted to bio-oils containing less than 10% oxygen by a hydropyrolysis process. Hydropyrolysis is the first step in Gas Technology Institute’s (GTI) integrated Hydropyrolysis and Hydroconversion IH2®. These intermediate bio-oils can then be converted to drop-in hydrocarbon fuels using existing refinery hydrotreating equipment to make hydrocarbon blending components, which are fully compatible with existing fuels. Alternatively, cellulosic or woody biomass can directly be converted into drop-in hydrocarbon fuels containing less than 0.4% oxygen using the IH2 process located adjacent to a refinery or ethanol production facility. Many US oil refineries are actually located near biomass resources and are a logical location for a biomass to transportation fuel conversion process. The goal of this project was to work directly with an oil refinery partner, to determine the most attractive route and location for conversion of biorenewables to drop in fuels in their refinery and ethanol production network. Valero Energy Company, through its subsidiaries, has 12 US oil refineries and 11 ethanol production facilities, making them an ideal partner for this analysis. Valero is also part of a 50- 50 joint venture with Darling Ingredients called Diamond Green Diesel. Diamond Green Diesel’s production capacity is approximately 11,000 barrels per day of renewable diesel. The plant is located adjacent to Valero’s St Charles, Louisiana Refinery and converts recycled animal fats, used cooking oil, and waste corn oil into renewable diesel. This is the largest renewable diesel plant in the U.S. and has successfully operated for over 2 years For this project, 25 liters of hydropyrolysis oil from wood and 25 liters of hydropyrolysis oils from corn stover were produced. The hydropyrolysis oil produced had 4-10% oxygen. Metallurgical testing of hydropyrolysis liquids was completed by Oak Ridge National Laboratories (Oak Ridge) and showed the

  13. Outlook for Refinery Outages and Available Refinery Capacity...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    level of refinery outages outlined in this report. This report does not consider the impacts of refined product logistics and distribution, which could affect the movement of...

  14. U.S. Refinery Yield

    U.S. Energy Information Administration (EIA) Indexed Site

    2011 2012 2013 2014 2015 2016 View History Liquefied Refinery Gases 4.0 4.0 3.9 4.0 3.7 3.7 1993-2016 Finished Motor Gasoline 45.6 45.7 45.7 45.7 46.0 47.5 1993-2016 Finished Aviation Gasoline 0.1 0.1 0.1 0.1 0.1 0.1 1993-2016 Kerosene-Type Jet Fuel 9.3 9.4 9.4 9.4 9.5 9.6 1993-2016 Kerosene 0.1 0.1 0.1 0.1 0.1 0.1 1993-2016 Distillate Fuel Oil 28.6 28.7 29.1 29.5 29.4 28.1 1993-2016 Residual Fuel Oil 3.4 3.1 2.9 2.6 2.5 2.5 1993-2016 Naphtha for Petrochemical Feedstock Use 1.3 1.3 1.5 1.2 1.1

  15. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2006-09-30

    syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40

  16. Total Number of Operable Refineries

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Total Number of Operable Refineries Number of Operating Refineries Number of Idle Refineries Atmospheric Crude Oil Distillation Operable Capacity (B/CD) Atmospheric Crude Oil Distillation Operating Capacity (B/CD) Atmospheric Crude Oil Distillation Idle Capacity (B/CD) Atmospheric Crude Oil Distillation Operable Capacity (B/SD) Atmospheric Crude Oil Distillation Operating Capacity (B/SD) Atmospheric Crude Oil Distillation Idle Capacity (B/SD) Vacuum Distillation Downstream Charge

  17. Recent advances in the speciation of selenium in petroleum refinery and municipal waste using ICP-MS and ICP-MS coupled with liquid chromatography

    SciTech Connect (OSTI)

    Roehl, R.

    1996-09-01

    An analytical scheme for the speciation of selenium in petroleum refinery waste waters reported at the 1994 Winter Plasma Conference included methods for the determination of total, dissolved, particulate and volatile selenium, as well as for the separate quantitation of dissolved selenite, selenate and selenocyanate. Several of those methods have been improved significantly. Determinations of total, dissolved, and particulate selenium are based on the ICP-MS quantitation of the {sup 82}Se isotope in waste water samples or sample fractions digested with hydrogen peroxide and nitric acid. These analyses now include corrections for potential isobaric interferences are minimized by monitoring the signals for Br{sup +} and m/z 79 and SO{sub 3}H{sup +} at m/z 83 and correcting the apparent {sup 82}Se{sup +} signal using appropriate equations with correction factors derived from the analysis of calibration solutions containing sulfate and bromide. The correction factors used in those equations relate ionic species of different composition to each other (e.g., Br{sup +} and HBr{sup +}). To help ensure that the relative rate of formation of those ions in the plasma is not sample dependent, high concentrations of sodium and other easily ionized elements are removed from the sample digests by cation-exchange.

  18. Catalytic conversion of solar thermal produced pyrolysis gases to liquid fuels

    SciTech Connect (OSTI)

    Hanley, T.R.; Benham, C.B.

    1981-01-01

    The conversion of a simulated pyrolysis gas and synthesis gas using a Fischer-Tropsch catalyst system in a fluidized-bed reactor is investigated. Liquid fuels were produced between 550 and 660/sup 0/F (288 and 349/sup 0/C) for the simulated pyrolysis gas feed. An analysis of both liquid and gaseous product streams is performed. This investigation indicates a need for more extensive research with respect to hydrogen-to-carbon-monoxide usage ratios and with respect to the role of alkenes in fuel production.

  19. Virginia Biodiesel Refinery | Open Energy Information

    Open Energy Info (EERE)

    Refinery Jump to: navigation, search Name: Virginia Biodiesel Refinery Place: West Point, Virginia Zip: 23180 Product: Biodiesel producer based in Virginia References: Virginia...

  20. ,"U.S. Refinery Net Input"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...petpnpinpt2dcnusmbbla.htm" ,"Source:","Energy Information Administration" ,"For Help, ... Barrels)","U.S. Refinery Net Input of Hydrogen (Thousand Barrels)","U.S. Refinery Net ...

  1. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Operable Date of Last Operation Date Shutdown Table 11. New, Shutdown and Reactivated Refineries During 2015 a b NEW PAD District III 71,250 Buckeye Texas Processing LLC Corpus Christi, TX 46,250 11/15 Petromax Refining Co LLC Houston, TX 25,000 07/15 SHUTDOWN PAD District III 0 12,000 Pelican Refining Company LLC Lake Charles, LA 0 12,000 12/14 01/15 a b bbl/cd=Barrels per calendar day. bbl/sd=Barrels per stream day. Sources: Energy Information Administration (EIA) Form EIA-810, "Monthly

  2. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    District and State Production Capacity Alkylates Aromatics Asphalt and Road Oil Isomers Lubricants Marketable Petroleum Coke Sulfur (short tons/day) Hydrogen (MMcfd) Table 2. Production Capacity of Operable Petroleum Refineries by PAD District and State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) a 83,429 10,111 26,500 92,765 21,045 21,120 69 1,159 PAD District I Delaware 11,729 5,191 0 6,000 0 13,620 40 596 New Jersey 29,200 0 70,000 4,000 12,000 7,500 26 280 Pennsylvania

  3. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    State/Refiner/Location Alkylates Aromatics Isobutane Lubricants Isomers Isopentane and Isohexane Asphalt and Road Oil Marketable Petroleum Coke Hydrogen (MMcfd) Sulfur (short tons per day) Table 4. Production Capacity of Operable Petroleum Refineries by State as of January 1, 2016 (Barrels per Stream Day, Except Where Noted) Isooctane a ..................................................................... Alabama 0 0 15,000 1,150 4,200 0 7,120 40 228 0 Hunt Refining Co 0 0 15,000 0 4,200 0 7,120

  4. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillation Crude Oil Atmospheric Distillation Vacuum Cracking Thermal Catalytic Cracking Fresh Recycled Catalytic Hydro- Cracking Catalytic Reforming Desulfurization Hydrotreating/ Fuels Solvent Deasphalting Downstream Charge Capacity Table 6. Operable Crude Oil and Downstream Charge Capacity of Petroleum Refineries, January 1, 1987 to (Thousand Barrels per Stream Day, Except Where Noted) January 1, 2016 JAN 1, 1987 16,460 6,935 1,928 5,251 466 1,189 3,805 9,083 230 JAN 1, 1988 16,825 7,198

  5. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Alkylates Aromatics Road Oil and Lubricants Petroleum Coke (MMcfd) Hydrogen Sulfur (short tons/day) Production Capacity Asphalt Isomers Marketable Table 7. Operable Production Capacity of Petroleum Refineries, January 1, 1987 to January 1, 2016 (Thousand Barrels per Stream Day, Except Where Noted) a JAN 1, 1987 974 287 788 326 250 364 2,569 23,806 JAN 1, 1988 993 289 788 465 232 368 2,418 27,639 JAN 1, 1989 1,015 290 823 469 230 333 2,501 28,369 JAN 1, 1990 1,030 290 844 456 232 341 2,607 24,202

  6. Withdrawal of gases and liquids from an in situ oil shale retort

    DOE Patents [OSTI]

    Siegel, Martin M.

    1982-01-01

    An in situ oil shale retort is formed within a subterranean formation containing oil shale. The retort contains a fragmented permeable mass of formation particles containing oil shale. A production level drift extends below the fragmented mass, leaving a lower sill pillar of unfragmented formation between the production level drift and the fragmented mass. During retorting operations, liquid and gaseous products are recovered from a lower portion of the fragmented mass. A liquid outlet line extends from a lower portion of the fragmented mass through the lower sill pillar for conducting liquid products to a sump in the production level drift. Gaseous products are withdrawn from the fragmented mass through a plurality of gas outlet lines distributed across a horizontal cross-section of a lower portion of the fragmented mass. The gas outlet lines extend from the fragmented mass through the lower sill pillar and into the production level drift. The gas outlet lines are connected to a gas withdrawal manifold in the production level drift, and gaseous products are withdrawn from the manifold separately from withdrawal of liquid products from the sump in the production level drift.

  7. Refinery, petrochemical plant injuries decline

    SciTech Connect (OSTI)

    Not Available

    1994-07-25

    The National Petroleum Refiners Association (NPRA) reports a 7% reduction in workplace injury and illness incidence rates for refineries in 1993, and a 21% decrease for petrochemical plants. The report summarizes data from 135 of the 162 US member refineries, and 117 of the 172 US member petrochemical plants. This paper summarizes the report findings.

  8. Reformulated Gasoline Foreign Refinery Rules

    Gasoline and Diesel Fuel Update (EIA)

    Reformulated Gasoline Foreign Refinery Rules Contents * Introduction o Table 1. History of Foreign Refiner Regulations * Foreign Refinery Baseline * Monitoring Imported Conventional Gasoline * Endnotes Related EIA Short-Term Forecast Analysis Products * Areas Participating in the Reformulated Gasoline Program * Environmental Regulations and Changes in Petroleum Refining Operations * Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model * Refiners Switch to Reformulated

  9. Ionic liquid-functionalized mesoporous sorbents and their use in the capture of polluting gases

    DOE Patents [OSTI]

    Lee, Jong Suk; Koros, William J.; Bhuwania, Nitesh; Hillesheim, Patrick C.; Dai, Sheng

    2016-01-12

    A composite structure for capturing a gaseous electrophilic species, the composite structure comprising mesoporous refractory sorbent particles on which an ionic liquid is covalently attached, wherein said ionic liquid includes an accessible functional group that is capable of binding to said gaseous electrophilic species. In particular embodiments, the mesoporous sorbent particles are contained within refractory hollow fibers. Also described is a method for capturing a gaseous electrophilic species by use of the above-described composite structure, wherein the gaseous electrophilic species is contacted with the composite structure. In particular embodiments thereof, cooling water is passed through the refractory hollow fibers containing the IL-functionalized sorbent particles in order to facilitate capture of the gaseous electrophilic species, and then steam is passed through the refractory hollow fibers to facilitate release of the gaseous electrophilic species such that the composite structure can be re-used to capture additional gas.

  10. Refinery & Blender Net Production of Total Finished Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Finished Petroleum Products Liquefied Refinery Gases Ethane/Ethylene Ethane Ethylene Propane/Propylene Propane Propylene Normal Butane/Butylene Normal Butane Butylene Isobutane/Isobutylene Isobutane Isobutylene Finished Motor Gasoline Reformulated Gasoline Reformulated Blended w/ Fuel Ethanol Reformulated Other Gasoline Conventional Gasoline Conventional Blended w/ Fuel Ethanol Conventional Blended w/ Fuel Ethanol, Ed55 and Lower Conventional Blended w/ Fuel Ethanol, Greater than

  11. Refinery Net Production of Total Finished Petroleum Products

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Finished Petroleum Products Liquefied Refinery Gases Ethane/Ethylene Ethane Ethylene Propane/Propylene Propane Propylene Normal Butane/Butylene Normal Butane Butylene Isobutane/Isobutylene Isobutane Isobutylene Finished Motor Gasoline Reformulated Gasoline Reformulated Blended w/ Fuel Ethanol Reformulated Other Conventional Gasoline Conventional Blended w/ Fuel Ethanol Conventional Blended w/ Fuel Ethanol, Ed55 and Lower Conventional Blended w/ Fuel Ethanol, Greater than Ed55

  12. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    of Last Operation Date Shutdown Table 13. Refineries Permanently Shutdown By PAD District Between January 1, 1990 and January 1, 2016 PAD District I 570,450 Primary Energy Corp Richmond, VA 6,100 0 a GNC Energy Corp Greensboro, NC 3,000 0 a Saint Mary's Refining Co Saint Mary's, WV 4,000 4,480 02/93 03/93 Cibro Refining Albany, NY 41,850 27,000 07/93 09/93 Calumet Lubricants Co LP Rouseville, PA 12,800 26,820 03/00 06/00 Young Refining Corp. Douglasville, GA 5,400 0 07/04 07/04 Sunoco Inc

  13. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Cokers Catalytic Crackers Hydrocrackers Capacity Inputs Capacity Inputs Capacity Inputs Table 8. Capacity and Fresh Feed Input to Selected Downstream Units at U.S. Refineries, 2014 - 2016 (Barrels per Calendar Day) Reformers Capacity Inputs 2014 2,686,917 5,616,015 2,034,689 2,337,425 4,884,975 1,662,603 2,591,992 3,419,407 74,900 475,800 41,500 47,633 407,342 29,849 PADD I 175,036 240,550 520,521 1,213,427 310,950 444,060 1,023,877 267,016 PADD II 645,874 837,754 1,479,496 2,916,764 1,118,239

  14. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Method PAD Districts I II III IV V United States Table 9. Refinery Receipts of Crude Oil by Method of Transportation by PAD District, 2015 (Thousand Barrels) a Pipeline 25,319 1,270,581 1,894,658 178,448 290,577 3,659,583 Domestic 2,766 679,552 1,624,647 86,978 222,419 2,616,362 Foreign 22,553 591,029 270,011 91,470 68,158 1,043,221 Tanker 305,663 0 941,152 0 513,584 1,760,399 Domestic 119,833 0 28,324 0 180,353 328,510 Foreign 185,830 0 912,828 0 333,231 1,431,889 Barge 22,367 4,569 227,383 0

  15. U.S. Refinery Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Total 337,235 321,406 357,855 343,444 362,961 360,498 2005-2016 Liquefied Refinery Gases 10,719 12,130 20,317 24,640 27,574 26,382 2005-2016 Ethane/Ethylene 165 114 141 146 170 25 2005-2016 Ethane 142 96 120 130 139 8 2005-2016 Ethylene 23 18 21 16 31 17 2005-2016 Propane/Propylene 17,998 16,402 18,157 17,729 18,884 17,690 2005-2016 Propane 8,571 8,208 9,095 9,011 10,066 9,549 2005-2016 Propylene 9,427 8,194 9,062 8,718 8,818 8,141 2005-2016

  16. Grupo Maris Capital ethanol refinery | Open Energy Information

    Open Energy Info (EERE)

    Maris Capital ethanol refinery Jump to: navigation, search Name: Grupo Maris (Capital ethanol refinery) Place: Nuporanga, Brazil Product: 32,000 m3 ethanol refinery owner...

  17. ,"U.S. Refinery Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    11:34:24 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...NUS1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  18. ,"U.S. Refinery Net Input"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...RONUS1","MO9RONUS1","MBARONUS1" "Date","U.S. Refinery Net Input of Crude Oil and Petroleum Products (Thousand Barrels)","U.S. Refinery Net Input of Crude Oil (Thousand ...

  19. ,"U.S. Refinery Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    10:25:07 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...US1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  20. ,"U.S. Refinery Net Production"

    U.S. Energy Information Administration (EIA) Indexed Site

    10:25:08 PM" "Back to Contents","Data 1: U.S. Refinery Net Production" ...US1","MMNRXNUS1","MPGRXNUS1" "Date","U.S. Refinery Net Production of Crude Oil and ...

  1. Motiva Refinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refinery Motiva Refinery May 18, 2006 - 10:45am Addthis Remarks Prepared for Energy Secretary Bodman Much of my time lately has been devoted to explaining why the price of gasoline has risen so sharply. President Bush understands the pinch this is creating for American consumers and has come forward with a variety of steps to address the problem. Rapid economic growth in emerging economies like China and India-and the growth here in the U.S.-have pushed up demand. Political unrest in some

  2. U.S. Refinery Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 4,568,301 4,484,600 4,395,128 4,433,893 4,349,316 4,273,291 2005-2015 Liquefied Refinery Gases 240,454 225,992 230,413 227,349 238,485 223,448 2005-2015 Ethane/Ethylene 7,228 7,148 6,597 2,626 2,038 2,134 2005-2015 Ethane 5,200 5,105 4,835 2,439 1,777 1,835 2005-2015 Ethylene 2,028 2,043 1,762 187 261 299 2005-2015 Propane/Propylene 204,223 201,492 202,309 206,038 214,378 203,954 2005-2015 Propane 102,913 98,508 100,933 103,568 111,813 103,253

  3. Opportunities for Biorenewables in Petroleum Refineries

    SciTech Connect (OSTI)

    Holmgren, Jennifer; Marinangelli, Richard; Marker, Terry; McCall, Michael; Petri, John; Czernik, Stefan; Elliott, Douglas C.; Shonnard, David

    2007-02-01

    A presentation by UOP based on collaborative work from FY05 using some results from PNNL for upgrading biomass pyrolysis oil to petroleum refinery feedstock

  4. Inorganic Membranes for Refinery Gas Separations

    SciTech Connect (OSTI)

    2009-02-01

    This factsheet describes a research project whose goal is to push the performance limits of inorganic membranes for large-scale gas separations in refinery applications.

  5. Opportunities for Biorenewables in Petroleum Refineries

    SciTech Connect (OSTI)

    Holmgren, Jennifer; Arena, Blaise; Marinangelli, Richard; McCall, Michael; Marker, Terry; Petri, John; Czernik, Stefan; Elliott, Douglas C.; Shonnard, David

    2006-10-11

    a summary of our collaborative 2005 project Opportunities for Biorenewables in Petroleum Refineries at the Rio Oil and Gas Conference this September.

  6. Kidney cancer and hydrocarbon exposures among petroleum refinery workers

    SciTech Connect (OSTI)

    Poole, C.; Dreyer, N.A.; Satterfield, M.H.; Levin, L.

    1993-12-01

    To evaluate the hypothesis of increased kidney cancer risk after exposure to hydrocarbons, especially those present in gasoline, we conducted a case-control study in a cohort of approximately 100,000 male refinery workers from five petroleum companies. A review of 18,323 death certificates identified 102 kidney cancer cases, to each of whom four controls were matched by refinery location and decade of birth. Work histories, containing an average of 15.7 job assignments per subject, were found for 98% of the cases and 94% of the controls. Tb each job, industrial hygienists assigned semiquantitative ratings for the intensity and frequency of exposures to three hydrocarbon categories: nonaromatic liquid gasoline distillates, aromatic hydrocarbons, and the more volatile hydrocarbons. Ratings of {open_quotes}present{close_quotes} or {open_quotes}absent{close_quotes} were assigned for seven additional exposures: higher boiling hydrocarbons, polynuclear aromatic hydrocarbons, asbestos, chlorinated solvents, ionizing radiation, and lead. Each exposure had either no association or a weak association with kidney cancer. For the hydrocarbon category of principal a priori interest, the nonaromatic liquid gasoline distillates, the estimated relative risk (RR) for any exposure above refinery background was 1.0 (95% confidence interval [CI] 0.5-1.9). Analyses of cumulative exposures and of exposures in varying time periods before kidney cancer occurrence also produced null or near-null results. In an analysis of the longest job held by each subject (average duration 9.2 years or 40% of the refiner&y work history), three groups appeared to be at increased risk: laborers (RR = 1.9,95% CI 1.0-3.9); workers in receipt, storage, and movements (RR = 2.5,95% CI 0.9-6.6); and unit cleaners (RR = 2.3, 95% CI 0.5-9.9). 53 refs., 7 tabs.

  7. ,"Finished Motor Gasoline Refinery, Bulk Terminal, and Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    AM" "Back to Contents","Data 1: Finished Motor Gasoline Refinery, Bulk Terminal, and ... "Date","U.S. Finished Motor Gasoline Stocks at Refineries, Bulk ...

  8. NREL Refinery Process Shows Increased Effectiveness of Producing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae NREL Refinery Process Shows Increased Effectiveness of Producing Ethanol from Algae February 11, 2016 ...

  9. Potential Vulnerability of US Petroleum Refineries to Increasing...

    Energy Savers [EERE]

    Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature andor Reduced Water Availability Potential Vulnerability of US Petroleum Refineries to ...

  10. Refinery burner simulation design architecture summary.

    SciTech Connect (OSTI)

    Pollock, Guylaine M.; McDonald, Michael James; Halbgewachs, Ronald D.

    2011-10-01

    This report describes the architectural design for a high fidelity simulation of a refinery and refinery burner, including demonstrations of impacts to the refinery if errors occur during the refinery process. The refinery burner model and simulation are a part of the capabilities within the Sandia National Laboratories Virtual Control System Environment (VCSE). Three components comprise the simulation: HMIs developed with commercial SCADA software, a PLC controller, and visualization software. All of these components run on different machines. This design, documented after the simulation development, incorporates aspects not traditionally seen in an architectural design, but that were utilized in this particular demonstration development. Key to the success of this model development and presented in this report are the concepts of the multiple aspects of model design and development that must be considered to capture the necessary model representation fidelity of the physical systems.

  11. Innovative filter polishes oil refinery wastewater

    SciTech Connect (OSTI)

    Irwin, J.; Finkler, M.

    1982-07-01

    Describes how, after extensive testing of 4 different treatment techniques, a Hydro Clear rapid sand filter was installed at the Sohio oil refinery in Toledo, Ohio. This filtration system has proven to be more cost-effective than conventional approaches. The system handles the refinery's wastewater flow of 10.3 mgd. With the aid of the polishing filter, readily meets the NPDES permit limitations. The Toledo refinery is a highly integrated petroleum processing complex. It processes 127,000 barrels per day of crude oil, including 40,000 barrels per day of sour crude. Tables give dissolved air flotation performance data; biological system performance data; filter performance data; and refinery waste treatment unit compared with NPDES-BPT limitations. Diagram shows the Sohio refinery wastewater treatment facility. Through a separate backwash treatment system complete control is brought to the suspended solids in the effluent which also tends to control chemical oxygen demand and oil/grease levels.

  12. Former Soviet refineries face modernization, restructuring

    SciTech Connect (OSTI)

    Not Available

    1993-11-29

    A massive modernization and restructuring program is under way in the refining sector of Russia and other former Soviet republics. Economic reforms and resulting economic dislocation following the collapse of the Soviet Union has left refineries in the region grappling with a steep decline and changes in product demand. At the same time, rising oil prices and an aging, dilapidated infrastructure promise a massive shakeout. Even as many refineries in the former Soviet Union (FSU) face possible closure because they are running at a fraction of capacity, a host of revamps, expansions, and grass roots refineries are planned or under way. The paper discusses plans.

  13. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 31 for fourth quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  14. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 19 for first quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  15. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 23 for second quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  16. Hydrotreating Pyrolytic Lignin to Produce a Refinery Feedstock (Poster)

    SciTech Connect (OSTI)

    French, R. J.

    2013-09-01

    Fast pyrolysis of biomass followed by water separation to produce pyrolytic lignin and hydrotreating of the lignin could be used to produce a stable volatile low-oxygen intermediate liquid. Such a liquid could be converted into a finished motor-fuel in a refinery, taking advantage of the existing infrastructure and economies of scale of refineries. Hydrotreating just the lignin would consume less hydrogen while preserving about half of the energy of the original oil. The aqueous by-products could be reformed to produce the needed hydrogen and would contain much of the unwanted acids and unstable oxygenates. To assess such intermediate liquids, several pyrolytic lignins were prepared by mixing pyrolysis oil with water at 1:1 and 3:1 ratios. The carboxylic acidity in the pyrolytic lignin was reduced to 24 and 10 mg-KOH/g-lignin compared to 81 in the whole oil. These lignins were hydrotreated using Ni-Mo(S)/alumina, Pt/char, or Pd/C(activated) in a semi-batch 1 L stirred autoclave. The oil was stabilized under hydrogen at 150-280 degrees C, then water and light organics were removed by partial depressurization. Hydrodeoxygenation was then performed at 340-400 degrees C. Total pressure was controlled at 70 or 170 bar with hydrogen gas. Organic liquid yields of 39-56% were obtained. For many experiments the organic oxygen content was <7%, acidity was < 7 mg-KOH/g-oil, the volatility was greater than or equal to 94% and, on a carbon basis, the total yield of organic products miscible in hydrocarbons at a 1:10 ratio was over 50%. These properties are probably acceptable to a refinery.The residual liquids left in the reactor at the end of the experiment comprised 60-85% of the organic-phase product while the rest was condensate. 13C-NMR of the residual liquids showed that they were 50-80% aliphatic. 13C-NMR coupled with GC-MS identified phenolic compounds as the main oxygenates in most residual liquids.

  17. From the Woods to the Refinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Woods to the Refinery CORRIM Life Cycle Analyses of Woody Feedstocks Dr. Steve Kelley ... composition, sugar types, residue fuel value * TC models are sensitive to MC, much less ...

  18. Motiva Enterprises Refinery Expansion Groundbreaking | Department...

    Office of Environmental Management (EM)

    of the preeminent refineries on the Gulf Coast will become the largest in the United States and one of the largest in ... help America meet its petroleum needs well into the future. ...

  19. From the Woods to the Refinery

    Broader source: Energy.gov [DOE]

    Breakout Session 2D—Building Market Confidence and Understanding II: Carbon Accounting and Woody Biofuels From the Woods to the Refinery Stephen S. Kelley, Principal and Department Head, Department of Forest Biomaterials, North Carolina State University

  20. Iran to build new refinery at Arak

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This paper reports Iranian plans to construct a grassroots 150,000-b/d refinery in Arak. The plant, to be completed in early 1993, will be capable of producing unleaded gasoline and other light products.

  1. Myriant Succinic Acid BioRefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    or otherwise restricted information Myriant Succinic Acid BioRefinery DOE Bioenergy Technologies Office (BETO) 2015 Project Peer Review Mark Shmorhun, Principal Investigator March 25, 2015 2 Goal Statement * Renewable Succinic Acid Production * A high value bio based chemical derived from renewable feedstocks * Validate proposed technology at a demonstration plant located in Lake Providence, LA. * Nameplate Capacity: 30 million lbs/year 3 Myriant's Succinic Acid BioRefinery (MySAB) Lake

  2. Refinery siting workbook: appendices A and B

    SciTech Connect (OSTI)

    Not Available

    1980-07-01

    The objective of this effort is to develop and provide basic refinery-related information for use by state and local government officials as a basis for establishing responsible refinery siting requirements and policies consistent with the federal clean air and water standards and socio-economic concerns. The report will be organized into two volumes. The main text comprises the basic topics of physical concerns, regulatory requirements, and permitting activities, while the second volume includes the detailed appendix materials such as the applicable laws, and the necessary permits, as available and a glossary of pertinent terms. As a means to this objective, three refinery sizes, 200,000, 100,000 and 30,000 barrels per day crude charge will be discussed in technical terms. Process unit configuration will be presented which will maximize either gasoline or heating oil production with either sweet or sour crude oil feedstocks. The major issues affecting the socio-economic impact of siting the refinery in a given locale will be presented. These data will review the factors affecting the human environment and the issues that must be addressed to assess the impact that a refinery will have on a community. The key federal registrations which impact upon a refinery siting decision shall be reviewed. Summaries of these regulations and a simplified decision diagram for the air and water acts shall be presented to assist both government and refinery officials in understanding the scope of regulatory impact. All pertinent procedures required for refinery permitting shall be reviewed under the generalized headings of air, water, health and safety, land use, and miscellaneous permits. This categorization at the federal, state and local levels of government shall be used as a basis for establishing degrees of emphasis.

  3. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Total 579,640 560,048 615,821 596,893 629,128 623,399 1981-2016 Liquefied Refinery Gases 10,719 12,130 20,317 24,640 27,574 26,382 1981-2016 Ethane/Ethylene 165 114 141 146 170 25 1981-2016 Ethane 142 96 120 130 139 8 1993-2016 Ethylene 23 18 21 16 31 17 1993-2016 Propane/Propylene 17,998 16,402 18,157 17,729 18,884 17,690 1981-2016 Propane 8,571 8,208 9,095 9,011 10,066 9,549 1995-2016 Propylene 9,427 8,194 9,062 8,718 8,818 8,141 1993-2016

  4. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 18,452 18,673 18,564 19,106 19,654 19,893 1983-2015 Liquefied Refinery Gases 659 619 630 623 653 612 1984-2015 Ethane/Ethylene 20 20 18 7 6 6 1985-2015 Ethane 14 14 13 7 5 5 1993-2015 Ethylene 6 6 5 1 1 1 1993-2015 Propane/Propylene 560 552 553 564 587 559 1985-2015 Propane 282 270 276 284 306 283 2004-2015 Propylene 278 282 277 281 281 276 1993-2015 Normal Butane/Butylene 83 48 56 57 70 55 1985-2015 Normal Butane 88 53 63 64 76 64 1993-2015

  5. Independent quality assurance of refinery fugitives testing by western states petroleum association. Final audit report

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    Research Triangle Institute (RTI) undertook this task for the U.S. Environmental Protection Agency's (EPA's) Office of Air Quality Planning and Standards to provide third-party Quality Assurance (QA) support to a Western States' Petroleum Association (WSPA) program to measure fugitive emissions at petroleum refineries. The primary objectives of the WSPA study were to determine the correlation between screening values and true mass emission rates and to develop a relationship between liquid and gas composition. EPA's QA effort, however, focused only on the correlation objective because the number of leaking components in the California refineries cannot be expected to be representative of refineries in general. The number of components leaking at a given screening value is used in conjunction with the mass correlations to derive the average emission factors.

  6. Phased Array Approach To Retrieve Gases, Liquids, Or Solids From Subsurface And Subaqueous Geologic Or Man-Made Formations

    DOE Patents [OSTI]

    Rynne, Timothy M.; Spadaro, John F.; Iovenitti, Joe L.; Dering, John P.; Hill, Donald G.

    1998-10-27

    A method of enhancing the remediation of contaminated soils and ground water, production of oil and gas, and production of any solid, gas, and/or liquid from subsurface geologic and man-made formations including the steps of estimating the geometric boundaries of the region containing the material to be recovered, drilling a recovery well(s) into subsurface in a strategic location to recover the material of interest, establishing multiple sources of acoustical power in an array about and spaced-apart from the surface or at various depths below the surface in a borehole(s) and/or well(s), directing a volume of acoustical excitation from the sources into the region containing the material to be recovered, the excitation in the form of either controllable sinusoidal, square, pulsed, or various combinations of these three waveforms, and controlling the phasing, frequency, power, duration, and direction of these waveforms from the sources to increase and control the intensity of acoustical excitation in the region of the material to be recovered to enhance. the recovery of said material from the recovery well(s). The invention will augment any technology affecting the removal of materials from the subsurface.

  7. U.S. Refinery Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 4,178,588 4,091,601 4,007,375 4,037,265 3,954,862 3,894,471 2005-2015 Crude Oil 5,374,094 5,404,347 5,489,516 5,589,006 5,784,637 5,915,532 2005-2015 Natural Gas Plant Liquids 154,941 171,074 175,607 168,808 172,563 171,936 2005-2015 Pentanes Plus 54,697 61,059 59,432 56,153 52,853 50,850 2005-2015 Liquefied Petroleum Gases 100,244 110,015 116,175 112,655 119,710 121,086 2005-2015 Normal Butane 39,253 42,087 45,747 42,461 45,916 47,870 2005-2015

  8. Where do California's greenhouse gases come from?

    SciTech Connect (OSTI)

    Fischer, Marc

    2009-01-01

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  9. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  10. ,"U.S. Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Content (Weighted Average) of Crude Oil Input to Refineries (Percent)","U.S. API Gravity (Weighted Average) of Crude Oil Input to Refineries (Degrees)" 31062,0.88,32.64 ...

  11. ,"U.S. Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Content (Weighted Average) of Crude Oil Input to Refineries (Percent)","U.S. API Gravity (Weighted Average) of Crude Oil Input to Refineries (Degrees)" 31228,0.91,32.46 ...

  12. GreenHunter Biodiesel Refinery Grand Opening | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GreenHunter Biodiesel Refinery Grand Opening GreenHunter Biodiesel Refinery Grand Opening June 2, 2008 - 12:51pm Addthis Remarks as Prepared for (Acting) Deputy Secretary Kupfer ...

  13. ,"U.S. Downstream Charge Capacity of Operable Petroleum Refineries...

    U.S. Energy Information Administration (EIA) Indexed Site

    as of January 1 (Barrels per Stream Day)","U.S. Refinery Thermal Cracking Downstream Charge Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Thermal ...

  14. ,"U.S. Production Capacity of Operable Petroleum Refineries"

    U.S. Energy Information Administration (EIA) Indexed Site

    Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Aromatics Production Capacity as of January 1 (Barrels per Stream Day)","U.S. Refinery Asphalt and Road Oil ...

  15. Crude oil as refinery feed stock

    SciTech Connect (OSTI)

    Boduszynski, M.M.; Farrell, T.R.

    1995-12-31

    This paper gives a brief overview of the integrated oil refinery. It illustrates that crude oil refining involves {open_quotes}molecular tailoring,{close_quotes} where feed stock molecules are {open_quotes}tailored{close_quotes} through catalytic processing to make products with the most desirable composition. Chemical composition of crude oil as refinery feed stock is discussed. The emphasis is on the understanding of molecular transformations which occur in refinery processes to manufacture light transportation fuels. Diesel fuel manufacturing is used as an example. Recent environmental legislation in the United States has necessitated a significant upgrade in the quality of diesel fuel used for highway transportation. Examples are given to illustrate the impact that petroleum chemistry may have on the industry`s response to government regulations.

  16. Refinery Input by PADD - Petroleum Supply Annual (2004)

    SciTech Connect (OSTI)

    2009-01-18

    Table showing refinery input of crude oil and petroleum products by Petroleum Administration for Defense Districts (PADD).

  17. Exergoeconomic analysis of a refinery`s utilities plant: Part II-improvement proposals

    SciTech Connect (OSTI)

    Rivero, R.; Hernandez, R.

    1996-12-31

    A crude oil refinery normally consumes a large amount of energy, not only in the form of the combustion of fossil fuels in the process units, but also in the associated Utilities Plant which produces process steam at different pressure levels and electricity. Energy losses of the utilities plant represent some 40 % of the total refinery`s energy losses. It is then extremely important to evaluate the performance of this plant and the costs to be assigned to the production of steam and electricity as a supplier of energy to the process units. This paper presents the improvement proposals generated by the application of an exergoeconomic analysis to the Utilities Plant of an existing 150,000 BPD crude oil refinery. 2 refs., 7 figs.

  18. Refinery siting workbook: appendices C to O

    SciTech Connect (OSTI)

    Not Available

    1980-07-01

    Applicable laws and permits available for the selection and building of petroleum refineries are enclosed. A glossary of pertinent terms is also included. References related to the National Environmental Policy Act, the Clean Air Act, the Federal Water Pollution Control Act, Resource Conservation and Recovery Act, Toxic Substance Control Act, and Wetlands and Coastal Zone are included. Permit information is also presented. (DC)

  19. Energetic Materials for EGS Well Stimulation (solids, liquids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well Stimulation (solids, liquids, gases) Energetic Materials for EGS Well ...

  20. U.S. Refineries Competitive Positions

    U.S. Energy Information Administration (EIA) Indexed Site

    Refineries Competitive Positions 2014 EIA Energy Conference July 14, 2014 Joanne Shore American Fuel & Petrochemical Manufacturers Refiners competitive positions Function of optimizing feedstock costs, operating costs, and revenues through mix of products sold 2 Propane/butane Chemicals Gasoline Jet Fuel Diesel/heating oil Lubes Fuel for ships Asphalt FEEDSTOCKS Qualities: - Heavy/Light - Sweet/Sour Location (Distance) - Domestic - International PROCESSING Size Complexity Treating (sulfur)

  1. Opportunities for Biorenewables in Oil Refineries

    SciTech Connect (OSTI)

    Marker, T.L.

    2005-12-19

    Abstract: The purpose of this study was to evaluate the potential for using biorenewable feedstocks in oil refineries. Economic analyses were conducted, with support from process modeling and proof of principle experiments, to assess a variety of potential processes and configurations. The study considered two primary alternatives: the production of biodiesel and green diesel from vegetable oils and greases and opportunities for utilization of pyrolysis oil. The study identified a number of promising opportunities for biorenewables in existing or new refining operations.

  2. U.S. Refinery Net Input

    U.S. Energy Information Administration (EIA) Indexed Site

    Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History Total 302,955 290,718 325,588 311,454 327,623 327,323 2005-2016 Crude Oil 495,806 460,629 499,255 478,254 504,549 492,960 2005-2016 Natural Gas Plant Liquids 18,673 14,924 13,318 12,174 12,857 12,478 2005-2016 Pentanes Plus 4,389 3,616 3,922 4,036 4,765 4,354 2005-2016 Liquefied Petroleum Gases 14,284 11,308 9,396 8,138 8,092 8,124 2005-2016 Normal Butane 7,947 5,592 2,866 1,791 1,812 1,829 2005-2016 Isobutane 6,337 5,716 6,530 6,347 6,280

  3. Ranking environmental liabilities at a petroleum refinery

    SciTech Connect (OSTI)

    Lupo, M.

    1995-12-31

    A new computer model is available to allow the management of a petroleum refinery to prioritize environmental action and construct a holistic approach to remediation. A large refinery may have numerous solid waste management units regulated by the Resource Conservation and Recovery Act (RCRA), as well as process units that emit hazardous chemicals into the environment. These sources can impact several environmental media, potentially including the air, the soil, the groundwater, the unsaturated zone water, and surface water. The number of chemicals of concern may be large. The new model is able to rank the sources by considering the impact of each chemical in each medium from each source in terms of concentration, release rate, and a weighted index based on toxicity. In addition to environmental impact, the sources can be ranked in three other ways: (1) by cost to remediate, (2) by environmental risk reduction caused by the remediation in terms of the decreases in release rate, concentration, and weighted index, and (3) by cost-benefit, which is the environmental risk reduction for each source divided by the cost of the remedy. Ranking each unit in the refinery allows management to use its limited environmental resources in a pro-active strategic manner that produces long-term results, rather than in reactive, narrowly focused, costly, regulatory-driven campaigns that produce only short-term results.

  4. U.S. Refinery and Blender Net Production

    U.S. Energy Information Administration (EIA) Indexed Site

    2010 2011 2012 2013 2014 2015 View History Total 6,735,067 6,815,590 6,794,407 6,973,710 7,173,730 7,260,943 1981-2015 Liquefied Refinery Gases 240,454 225,992 230,413 227,349 238,485 223,448 1981-2015 Ethane/Ethylene 7,228 7,148 6,597 2,626 2,038 2,134 1981-2015 Ethane 5,200 5,105 4,835 2,439 1,777 1,835 1993-2015 Ethylene 2,028 2,043 1,762 187 261 299 1993-2015 Propane/Propylene 204,223 201,492 202,309 206,038 214,378 203,954 1981-2015 Propane 102,913 98,508 100,933 103,568 111,813 103,253

  5. Economic impact analysis for the petroleum refineries NESHAP. Final report

    SciTech Connect (OSTI)

    1995-08-01

    An economic analysis of the industries affected by the Petroleum Refineries National Emmissions Standard for Hazardous Air Pollutants (NESHAP) was completed in support of this standard. The industry for which economic impacts was computed was the petroleum refinery industry. Affected refineries must reduce HAP emissions by the level of control required in the standard. Several types of economic impacts, among them price product changes, output changes, job impacts, and effects on foriegn trade, were computed for the selected regulatory alternative.

  6. Integrating NABC bio-oil intermediates into the petroleum refinery |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Integrating NABC bio-oil intermediates into the petroleum refinery Integrating NABC bio-oil intermediates into the petroleum refinery Breakout Session 2: Frontiers and Horizons Session 2-D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies Thomas Foust, Director, National Bioenergy Center, National Renewable Energy Laboratory biomass13_foust_2-d.pdf (713.06 KB) More Documents & Publications NABC Webinar Opportunities for Biomass-Based Fuels

  7. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    capable of automatic, safe, reliable, efficient, and low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. ...

  8. Market Assessment of Refinery Outages Planned for October 2010...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    average values for 2002-2009 excluding months in 2005, 2006, and 2008 affected by hurricanes & refinery closures. Similarly, typical historical values are average planned...

  9. ,"Finished Motor Gasoline Refinery, Bulk Terminal, and Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    and Natural Gas Plants (Thousand Barrels)","East Coast (PADD 1) Finished Motor Gasoline Stocks at Refineries, Bulk Terminals, and Natural Gas Plants (Thousand ...

  10. Saudi Aramco Mobile Refinery Company (SAMREF) | Open Energy Informatio...

    Open Energy Info (EERE)

    Company (SAMREF) Name: Saudi Aramco Mobile Refinery Company (SAMREF) Address: P.O. Box 30078 Place: Yanbu, Saudi Arabia Sector: Oil and Gas Product: Crude Oil Refining Phone...

  11. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. PDF icon Displacing Natural Gas Consumption and...

  12. Refinery Outages: First-Half 2016

    U.S. Energy Information Administration (EIA) Indexed Site

    Outages: First-Half 2016 March 2016 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Refinery Outages: First-Half 2016 i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States

  13. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO conversion into carbon-neutral fuels and chemicals November ...

  14. Vanadium removal from petroleum refinery wastewater

    SciTech Connect (OSTI)

    Nurdogan, Y.; Meyer, C.L.

    1996-11-01

    Although a numerical effluent limit has not been proposed for vanadium, San Francisco Bay Area refineries have been investigating reasonable source control and treatment measures to limit the discharge of vanadium as part of their National Pollution Discharge Elimination System (NPDES) permit requirements because vanadium may contribute to aquatic toxicity. The NPDES permit issued for the Shell Martinez Manufacturing Complex (MMC) by the Regional Water Quality Control Board (CRWQCB) required that in the investigation of control strategies for vanadium, consideration must be given to source control measures that would reduce the discharge to the extent practicable. This paper summarizes the results of bench- and pilot-scale studies to remove vanadium from process effluent of the Shell MMC. This study has resulted in the following conclusions: vanadium in the Shell MMC refinery wastewater is generated by two major sources--the Flexicoker and Stretford processes; ferric and ferrous salts are both effective in removing vanadium from wastewaters; there are tradeoffs between the initial vanadium concentration, the final pH, and the final dissolved vanadium concentration, for both ferrous and ferric reagents; recycle of iron hydroxide sludge can reduce the amount of reagent needed to attain a given vanadium concentration; other things being equal, less ferric than ferrous reagent is required to produce the same removal of vanadium; the dewatered sludge from the pilot plant was tested for its hazardous waste characteristics; a high pH sludge regeneration and reuse process appears to be a promising method of cleaning up the hazardous iron sludge.

  15. Coal-fired boiler for petroleum refinery

    SciTech Connect (OSTI)

    Ketterman, W.R.; Heinzmann, D.A.

    1982-01-01

    There has been a significant amount of interest in conversion from oil/gas fired boilers to coal-fired equipment since the Arab oil embargo of 1973. The CRA Incorporated Coffeyville Refinery decided in 1977 to proceed with the installation of a 86.183 Kg/h coal fired boiler to generate process steam at 650 psig (4,482 k Pa) 596/sup 0/F (313/sup 0/C). A significant portion of this steam is passed through steam turbines to obtain mechanical power. Building and operating a coal-fired steam plant is a ''Different Kettle of Fish'' from building and operating an oil/gas-fired steam plant. The intention of this paper is to deal with some of the ''Why's and Wherefores'' of the conversion to coal-fired equipment.

  16. Saber's heavy oil cracking refinery project

    SciTech Connect (OSTI)

    Benefield, C.S.; Glasscock, W.L.

    1983-03-01

    Perhaps more than any other industry, petroleum refining has been subjected to the radical swings in business and political climates of the past several decades. Because of the huge investments and long lead times to construct refining facilities, stable government policies, predictable petroleum prices, secure feedstock supplies and markets, and reliable cost estimates are necessary ingredients to effectively plan new refinery projects. However, over the past ten years the political and economic climates have provided anything but these conditions. Yet, refiners have demonstrated a willingness to undertake risks by continuing to expand and modernize their refineries. The refining business -- just as most businesses -- responds to economic incentives. These incentives, when present, result in new technology and capacity additions. In the 1940's, significant technology advances were commercialized to refine higher-octane motor gasolines. Such processes as continuous catalytic cracking (Houdry Process Corporation), fluid catalytic cracking (Standard Oil Development Company), HF alkylation (UOP and Phillips Petroleum Company), and catalytic reforming (UOP) began to supply a growing gasoline market, generated from the war effort and the ever increasing numbers of automobiles on the road. The post-war economy of the 1950's and 1960's further escalated demand for refined products, products which had to meet higher performance specifications and be produced from a wider range of raw materials. The refining industry met the challenge by introducing hydro-processing technology, such as hydrocracking developed in 1960. But, the era must be characterized by the large crude processing capacity additions, required to meet demand from the rapidly expanding U.S. economy. In 1950, refining capacity was 6.2 million BPD. By 1970, capacity had grown to 11.9 million BPD, an increase of 91%.

  17. Regulatory impact analysis for the petroleum refineries neshap. Draft report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    The report analyzes the regulatory impacts of the Petroleum Refinery National Emission Standard for Hazardous Air Pollutants (NESHAP), which is being promulgated under Section 112 of the Clean Air Act Amendments of 1990 (CCA). This emission standard would regulate the emissions of certain hazardous air pollutants (HAPs) from petroleum refineries. The petroleum refineries industry group includes any facility engaged in the production of motor gasoline, naphthas, kerosene, jet fuels, distillate fuel oils, residual fuel oils, lubricants, or other products made from crude oil or unfinished petroleum derivatives. The report analyzes the impact that regulatory action is likely to have on the petroleum refining industry.

  18. Effective Fouling Minimization Increases the Efficiency and Productivity of Refineries

    Broader source: Energy.gov [DOE]

    This factsheet details a project to improve operating procedures, including physical and chemical methods and the use of high-temperature coatings, to allow refineries to operate equipment below threshold fouling conditions and use the most effective minimization techniques.

  19. World Energy Projection System Plus Model Documentation: Refinery Model

    Reports and Publications (EIA)

    2016-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Refinery Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  20. World Energy Projection System Plus Model Documentation: Refinery Model

    Reports and Publications (EIA)

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Refinery Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  1. Combined-cycle cogeneration to power oil refinery

    SciTech Connect (OSTI)

    Broeker, R.J.

    1986-11-01

    A cogeneration plant now under construction at an oil refinery in Martinez, California, is an example of how the energy industry has been responding to the fundamental economic and technological challenges it has been facing over the past ten years. The industry is re-examining cogeneration as one way of meeting the requirements of the Public Utilities Regulatory Policy Act. The new plant is located at Tosco Corporation's Avon Oil Refinery, 45 miles northeast of San Francisco. It was designed by Foster Wheeler to supply process steam for the refinery as well as for a water-treatment installation that will benefit the Contra Costa Water District. Electric power produced will be used primarily by the refinery, with the balance purchased by the Pacific Gas and Electric Company.

  2. FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA...

    Office of Scientific and Technical Information (OSTI)

    The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The ...

  3. Investigation of sulfur-tolerant catalysts for selective synthesis of hydrocarbon liquids from coal-derived gases. Quarterly technical progress report, March 19-June 18, 1980

    SciTech Connect (OSTI)

    Bartholomew, C H

    1980-07-10

    A 15% Fe-3% K/sub 2/O on SiO/sub 2/ catalyst, a 15% Co-3% K/sub 2/O on SiO catalyst and a 15% CoB/SiO/sub 2/ catalyst were prepared. H/sub 2/ and CO chemisorption uptakes were measured for the catalysts prepared to date. It was noted that calcining the iron catalysts in air before reduction in flowing H/sub 2/ aided in increasing metal dispersion. Liquid and wax traps for use in the reactor system were completed as were plans for chromatographic product analysis.

  4. DOE - Office of Legacy Management -- International Rare Metals Refinery Inc

    Office of Legacy Management (LM)

    - NY 38 Rare Metals Refinery Inc - NY 38 Site ID (CSD Index Number): NY.38 Site Name: International Rare Metals Refinery, Inc. Site Summary: Site Link: External Site Link: Alternate Name(s): Canadian Radium and Uranium Corporation Alternate Name Documents: NY.38-1 Location: 69 Kisco Avenue, Mt. Kisco, New York Location Documents: NY.38-1 NY.38-3 Historical Operations (describe contaminants): Manufactured and distributed radium and polonium products. Historical Operations Documents: NY.38-5

  5. U.S. Fuel Consumed at Refineries

    Gasoline and Diesel Fuel Update (EIA)

    Liquefied Petroleum Gases 2,404 1,291 1,521 1,311 2,305 3,009 1986-2015 Distillate Fuel Oil 440 483 539 475 309 364 1986-2015 Residual Fuel Oil 980 759 540 443 413 395 1986-2015 ...

  6. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  7. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  8. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi

    1986-01-01

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  9. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi; Kulkarni, Sudhir S.

    1986-01-01

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  10. Greenhouse Gases into Gold

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turning Greenhouse Gases into Gold Greenhouse Gases into Gold NERSC simulations reveal reaction mechanism behind CO₂ conversion into carbon-neutral fuels and chemicals November 6, 2013 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Environmentalists have long lamented the destructive effects of greenhouse gases, with carbon dioxide (CO2) often accused of being the primary instigator of global climate change. As a result, numerous efforts are under way to find ways to prevent,

  11. ,"U.S. Refinery, Bulk Terminal, and Natural Gas Plant Stocks...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Refinery, Bulk Terminal, and Natural Gas ... 10:27:55 PM" "Back to Contents","Data 1: U.S. Refinery, Bulk Terminal, and Natural Gas ...

  12. EIA-820, Annual Refinery Report Page 1 U. S. ENERGY INFORMATION...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    crude oil that first traveled 5,000 miles by tanker and then traveled 105 miles by pipeline to the refinery, report pipeline as the method of transportation. * If the refinery...

  13. Alternative multimedia regulatory programs for next-generation refineries

    SciTech Connect (OSTI)

    Elcock, D.; Gasper, J.; Arguerro, R.; Emerson, D.

    2000-06-22

    The 25-year-old command-and-control environmental regulatory structure in the US has resulted in significant environmental improvements. Recently, however, its limitations (e.g., rigid application regardless of site-specific conditions, disregard of cross-media and multimedia impacts, limited incentives for new technology development and use) have become increasingly apparent. New regulatory approaches that recognize current and anticipated economic constraints, new knowledge of environmental processes and impacts, and the benefits of new technologies are needed. Such approaches could be especially important for the US petroleum refining industry. This industry operates under thin profit margins, releases chemicals that can produce adverse health and environmental impacts, and must meet the technological challenges of producing more highly refined fuels from poorer quality feedstocks. Under a grant from the Environmental Technology Initiative (ETI), Argonne National Laboratory and its subcontractor, Analytical Services, Inc. developed two alternative environmental regulatory programs for next-generation petroleum refineries. (In this report, next-generation refineries refers to the refineries of today as they operate in the next 20 or more years rather than to fully reengineered future refineries.) The objective of the ETI refinery project was to develop future-oriented regulatory programs for next-generation refineries that will expand the use of innovative technologies, encourage pollution prevention, demonstrate environmental responsibility, and maintain refinery economic performance. Rather than suggesting targeted, short-term modifications to existing media-specific command-and-control regulations, the ETI project suggests the use of new approaches that are broader and more flexible. It recognizes that giving refineries flexibility in meeting environmental protection goals can stimulate new technology development and use. Unlike most US Environmental

  14. Mazheikiai refinery modernization study. Executive summary. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. The volume contains the Executive Summary.

  15. Monitoring near refineries or airborne chemicals on the SARA Title 3 section 313 list

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    In this volume, detailed procedures recommended for the measurement of selected petroleum refinery emissions in ambient air are presented.

  16. Monitoring near refineries or airborne chemicals on the SARA Title 3 Section 313 list

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    This volume identifies publications and databases that address ambient air concentrations measured near petroleum refineries for the selected target chemicals.

  17. Monitoring near refineries for airborne chemicals on the SARA Title 3 Section 313 list

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This study provides an ambient air concentration perspective to the engineering estimates of petroleum refinery emissions required under SARA Title III Section 313. It presents and discusses ambient air concentrations of 25 selected target chemicals measured at and near the perimeter (fenceline) of three refineries. Measurements were made over three consecutive 24-hour sampling periods at each refinery. The extent to which the concentrations of the target chemicals were due to fugitive emissions from the refineries is estimated.

  18. Regulatory impact analysis for the petroleum refineries NESHAP. Final report

    SciTech Connect (OSTI)

    1995-08-01

    A regulatory impact analysis (RIA) of the industries affected by the Petroleum Refineries National Emissions Standard for Hazardous Air Pollutants (NESHAP) was completed in support of this regulation. This (RIA) was required because the proposal is economically significant according to Executive Order 12866. The industry for which these impacts was computed was the petroleum refinery industry. Several different impact analyses were included in total or summarized in different chapters in the document. Those analyses were: the compliance cost analysis, the economic impact analysis, and the benefits analysis. Benefits and costs were then compared and discussed in the document`s last chapter.

  19. Short-Term Energy Outlook Model Documentation: Hydrocarbon Gas Liquids Supply and Demand

    Reports and Publications (EIA)

    2015-01-01

    The hydrocarbon gas liquids (ethane, propane, butanes, and natural gasoline) module of the Short-Term Energy Outlook (STEO) model is designed to provide forecasts of U.S. production, consumption, refinery inputs, net imports, and inventories.

  20. Control of benzene waste NESHAP emissions from a petroleum refinery

    SciTech Connect (OSTI)

    Truelove, R.D. )

    1992-02-01

    This paper discusses the control of benzene emissions from a petroleum refinery as regulated by the National Emission Standards for Hazardous Air Pollutants (NESHAO) Subpart FF - National Standard for Benzene Waste Operations. This regulation is complex and confusing, but it provides flexibility to achieve compliance through various strategies to control benzene emissions. The first step to achieve compliance with the benzene waste NESHAP is understanding the regulation itself. Therefore, this paper summarizes the regulation to provide the reader with sufficient background to understand why specific controls are required for specific processes. The flexibility provided by the regulation to achieve compliance is not always readily apparent. This paper summarizes some of these subtleties. The author's involvement with an industry trade association in meetings with the Environmental Protection Agency during the development of the regulation allows some of EPA's expressions of their intent and internal interpretation to also be contained in the summary. The second step to achieve compliance with the benzene waste NESHAP is to actually design and operate a cost effective solution for a specific set of existing conditions within a refinery. This paper provides a case study of the equipment necessary to achieve compliance with the substantive requirements of the regulation at a large, integrated refinery. The retrofit requirements are very specific to the circumstances of this facility. Therefore, they will not be a universal, cost effective means of compliance for other refineries.

  1. Low temperature thermal treatment for petroleum refinery waste sludges

    SciTech Connect (OSTI)

    Ayen, R.J.; Swanstrom, C.P. )

    1992-05-01

    Treatment requirements for waste sludges generated by petroleum refinery operations and designated as waste codes K048, K049, K050, K051 and K052 under the Resource Conservation and Recovery Act (RCRA) became effective in November, 1990 under the Landban regulations. An experimental program evaluated low temperature thermal treatment of filter cakes produced from these sludges using laboratory and pilot-scale equipment. One set of experiments on waste samples from two different refineries demonstrated the effective removal of organics of concern from the sludges to meet the RCRA Best Demonstrated Available Technology (BDAT) treatment standards. Cyanides were also within the acceptable limit. Combined with stabilization of heavy metals in the treatment residues, low temperature thermal treatment therefore provides an effective and efficient means of treating refinery sludges, with most hydrocarbons recovered and recycled to the refinery. A milder thermal treatment was used to remove the bulk of the water from a previously filtered waste sludge, providing effective waste minimization through a 40% decrease in the mass of sludge to be disposed. The heating value of the sludge was increased simultaneously by one-third, thereby producing a residue of greater value in an alternative fuels program. A process based on this approach was successfully designed and commercialized.

  2. Energy Efficiency Roadmap for Petroleum Refineries in California

    SciTech Connect (OSTI)

    none,

    2004-04-01

    Through the California State IOF initiative, the California Energy Commission PIER Program developed a petroleum refining roadmap to identify energy issues and priorities unique to the refining industry in California and create a plan for future R&D that could help California refineries implement energy efficient technologies.

  3. Refinery Outages: Description and Potential Impact on Petroleum Product Prices

    Reports and Publications (EIA)

    2007-01-01

    This report responds to a July 13, 2006 request from Chairman Jeff Bingaman of the Senate Committee on Energy and Natural Resources requested that the Energy Information Administration conduct a study of the impact that refinery shutdowns have had on the price of oil and gasoline.

  4. Energy efficiency improvement and cost saving opportunities forpetroleum refineries

    SciTech Connect (OSTI)

    Worrell, Ernst; Galitsky, Christina

    2005-02-15

    The petroleum refining industry in the United States is the largest in the world, providing inputs to virtually any economic sector,including the transport sector and the chemical industry. The industry operates 146 refineries (as of January 2004) around the country,employing over 65,000 employees. The refining industry produces a mix of products with a total value exceeding $151 billion. Refineries spend typically 50 percent of cash operating costs (i.e., excluding capital costs and depreciation) on energy, making energy a major cost factor and also an important opportunity for cost reduction. Energy use is also a major source of emissions in the refinery industry making energy efficiency improvement an attractive opportunity to reduce emissions and operating costs. Voluntary government programs aim to assist industry to improve competitiveness through increased energy efficiency and reduced environmental impact. ENERGY STAR (R), a voluntary program managed by the U.S. Environmental Protection Agency, stresses the need for strong and strategic corporate energy management programs. ENERGY STAR provides energy management tools and strategies for successful corporate energy management programs. This Energy Guide describes research conducted to support ENERGY STAR and its work with the petroleum refining industry.This research provides information on potential energy efficiency opportunities for petroleum refineries. This Energy Guide introduces energy efficiency opportunities available for petroleum refineries. It begins with descriptions of the trends, structure, and production of the refining industry and the energy used in the refining and conversion processes. Specific energy savings for each energy efficiency measure based on case studies of plants and references to technical literature are provided. If available, typical payback periods are also listed. The Energy Guide draws upon the experiences with energy efficiency measures of petroleum refineries worldwide

  5. Carbon Bearing Trace Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon bearing trace gases Carbon Bearing Trace Gases A critical scientific and policy oriented question is what are the present day sources and sinks of carbon dioxide (CO2) in the natural environment and how will these sinks evolve under rising CO2 concentrations and expected climate change and ecosystem response. Sources and sinks of carbon dioxide impart their signature on the distribution, concentration, and isotopic composition of CO2. Spatial and temporal trends (variability) provide

  6. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for

  7. Alternative future environmental regulatory approaches for petroleum refineries.

    SciTech Connect (OSTI)

    Elcock, D.; Gasper, J.; Moses, D. O.; Emerson, D.; Arguerro, R.; Environmental Assessment; DOE; Analytical Services, Inc.

    2000-01-01

    Recently, many industrial, regulatory, and community leaders have expressed concern that the current environmental regulatory structure disregards multimedia environmental impacts, provides few incentives to develop and use new technologies, and fails to consider site-specific conditions. For the US petroleum refining industry, faced with the need to produce higher-quality fuels from poorer-quality feedstocks, such criticisms are expected to increase. This article offers two alternative environmental regulatory approaches for existing petroleum refineries to use in the future. These alternative approaches are multimedia in scope, provide for new technology development and use, and allow flexibility in the means for meeting environmental goals. They have been reviewed and critiqued by various stakeholders, including industry representatives, regulators, and local and national community and environmental organizations. The integration of stakeholder comments and findings of ongoing national and international regulatory reinvention efforts in the development of these approaches positions them for potential use by other industries in addition to petroleum refineries.

  8. Congested site challenges designers of refinery IPP plant

    SciTech Connect (OSTI)

    Collins, S.

    1993-09-01

    This article describes a new IPP plant which has successfully met the challenges of an extremely congested site--including overcoming physical space constraints, meeting low air-emissions regulations, and minimizing water consumption--located next to a busy highway and near a major airport. The 650-MW Linden cogeneration plant is located on a 13.5-acre plot within the confines of Bayway Refinery Co's facility near Newark, NJ. Since starting operation one year ago, the plant has been reliably supplying steam for the refinery's process heating and mechanical drive needs and efficiently generating steam and electricity with minimal environmental impact. To achieve these goals, designers chose a combined-cycle configuration/generators, five supplementary-fired heat-recovery steam generators (HRSGs), and three 90-MW steam turbine/generators. Thus far, the facility has operated with an average availability above 90%.

  9. Martinez Refinery Completes Plant-Wide Energy Assessment

    SciTech Connect (OSTI)

    2002-11-01

    This OIT BestPractices Case Study describes how the Equilon Enterprises oil refinery in Martinez, California undertook a plant-wide energy assessment that focused on three key areas: waste minimization, process debottlenecking, and operations optimization. The assessment yielded recommendations, which, if implemented, can save more than 6,000,000 MMBtu per year and an estimated $52,000,000 per year, plus improve process control and reduce waste.

  10. Renewable Fuels from Algae Boosted by NREL Refinery Process | Bioenergy |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Renewable Fuels from Algae Boosted by NREL Refinery Process February 9, 2016 A new biorefinery process developed by scientists at the Energy Department's National Renewable Energy Laboratory (NREL) has proven to be significantly more effective at producing ethanol from algae than previous research. The process, dubbed Combined Algal Processing (CAP), is detailed in a new paper by NREL's Tao Dong, Eric Knoshaug, Ryan Davis, Lieve Laurens, Stefanie Van Wychen, Philip Pienkos, and Nick

  11. University of Maine Integrated Forest Product Refinery (IFPR) Technology Research

    SciTech Connect (OSTI)

    Pendse, Hemant P.

    2010-11-23

    This project supported research on science and technology that forms a basis for integrated forest product refinery for co-production of chemicals, fuels and materials using existing forest products industry infrastructure. Clear systems view of an Integrated Forest Product Refinery (IFPR) allowed development of a compelling business case for a small scale technology demonstration in Old Town ME for co-production of biofuels using cellulosic sugars along with pulp for the new owners of the facility resulting in an active project on Integrated Bio-Refinery (IBR) at the Old Town Fuel & Fiber. Work on production of advanced materials from woody biomass has led to active projects in bioplastics and carbon nanofibers. A lease for 40,000 sq. ft. high-bay space has been obtained to establish a Technology Research Center for IFPR technology validation on industrially relevant scale. UMaine forest bioproducts research initiative that began in April 2006 has led to establishment of a formal research institute beginning in March 2010.

  12. Application of x-ray imaging to oil refinery processes

    SciTech Connect (OSTI)

    Gamblin, B.R.; Newton, D.; Smith, G.B.

    1996-12-31

    X-ray imaging is a non-intrusive method of visualizing the flow patterns of rapidly changing multiphase systems and is based on the variation in the absorbance of X-rays by the different phases. BP has applied the X-ray technique to a variety of problems encountered within the oil and petrochemical industries in which two or three phases are present e.g. Fluid Catalytic Cracking (riser, stripper, regenerator) and three phase systems such as slurry bubble column reactors. In general, to obtain the maximum productivity from these units it is essential to optimize the contacting between a catalyst and a process fluid or fluids. This work reports on laboratory experimental work in which full scale refinery components were visualized in order to characterize the existing designs. Modified designs were then tested and evaluated before implementation on the refinery unit. Economic assessments of some of the benefits which can be realized in an oil refinery as a result of such design improvements are also presented. 3 refs., 1 fig.

  13. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO

  14. Air Liquide Group | Open Energy Information

    Open Energy Info (EERE)

    search Name: Air Liquide Group Place: Paris, France Zip: 75321 Sector: Hydro, Hydrogen Product: Paris-based manufacturer of industrial and medical gases. The company is...

  15. Table 5.9 Refinery Capacity and Utilization, 1949-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Energy Information Administration (EIA), Energy Data Reports, Petroleum Refineries in the United States, annual reports. * 1981-2005EIA, Petroleum Supply Annual (PSA), ...

  16. Initial Assessment of U.S. Refineries for Purposes of Potential...

    Office of Scientific and Technical Information (OSTI)

    U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions Freeman, Charles J.; Jones, Susanne B.; Padmaperuma, Asanga B.; Santosa, Daniel M.; Valkenburg, Corinne; Shinn,...

  17. Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature and/or Reduced Water Availability

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report discusses potential impacts of increased water temperature and reductions in water availability on petroleum refining and presents case studies related to refinery water use. Report...

  18. US DOE Refinery Water Study 01-19-16 PublicE_docx

    Office of Environmental Management (EM)

    Potential Vulnerability of US Petroleum Refineries to Increasing Water Temperature andor Reduced Water Availability Executive Summary of Final Report Prepared for US Department of ...

  19. Aspects of Holly Corporation's Acquisition of Sunoco Inc.'s Tulsa, Oklahoma Refinery

    Reports and Publications (EIA)

    2009-01-01

    The Energy Information Administration has produced a review of aspects of the Holly's acquisition of Sunoco's 85,000-barrels-per-day Tulsa refinery.

  20. Updated estimation of energy efficiencies of U.S. petroleum refineries.

    SciTech Connect (OSTI)

    Palou-Rivera, I.; Wang, M. Q.

    2010-12-08

    Evaluation of life-cycle (or well-to-wheels, WTW) energy and emission impacts of vehicle/fuel systems requires energy use (or energy efficiencies) of energy processing or conversion activities. In most such studies, petroleum fuels are included. Thus, determination of energy efficiencies of petroleum refineries becomes a necessary step for life-cycle analyses of vehicle/fuel systems. Petroleum refinery energy efficiencies can then be used to determine the total amount of process energy use for refinery operation. Furthermore, since refineries produce multiple products, allocation of energy use and emissions associated with petroleum refineries to various petroleum products is needed for WTW analysis of individual fuels such as gasoline and diesel. In particular, GREET, the life-cycle model developed at Argonne National Laboratory with DOE sponsorship, compares energy use and emissions of various transportation fuels including gasoline and diesel. Energy use in petroleum refineries is key components of well-to-pump (WTP) energy use and emissions of gasoline and diesel. In GREET, petroleum refinery overall energy efficiencies are used to determine petroleum product specific energy efficiencies. Argonne has developed petroleum refining efficiencies from LP simulations of petroleum refineries and EIA survey data of petroleum refineries up to 2006 (see Wang, 2008). This memo documents Argonne's most recent update of petroleum refining efficiencies.

  1. Cryogenic method for measuring nuclides and fission gases

    DOE Patents [OSTI]

    Perdue, P.T.; Haywood, F.F.

    1980-05-02

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  2. EIA-815

    U.S. Energy Information Administration (EIA) Indexed Site

    Other Oxygenates 445 Natural Gas Plant Liquids and Liquefied Refinery Gases, TOTAL 242 EthaneEthylene, TOTAL 108 Ethylene 631 PropanePropylene, TOTAL 246 Propylene (nonfuel use) ...

  3. EIA-800

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Other Oxygenates 445 Natural Gas Plant Liquids (NGPL) and Liquefied Refinery Gases (LRG): EthaneEthylene, TOTAL 108 Ethane - LRG 641 Ethylene 631 PropanePropylene, TOTAL 246 ...

  4. EIA-800

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Liquids (NGPL) and Liquefied Refinery Gases (LRG):" "EthaneEthylene, TOTAL",108,,,... "Ethane - LRG",641 "Ethylene",631 "PropanePropylene, TOTAL",246,,,... "Propane - ...

  5. Evaluation audit report. Romanian petroleum refinery, Petrobrazi, Ploiesti. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Petrobrazi refinery which is located 12 kilometers southwest of Ploiesti, Romania. Other defined and specified goals of the study include a consideration of the refinery's operating flexibility; an evaluation of fuel switching including the use of coal as a substitute for energy supply; and an observation of the refinery's general condition and its maintenance practice for its effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and the capital requirements anticipated.

  6. Greenhouse Gases Converted to Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gases Converted to Fuel Greenhouse Gases Converted to Fuel carbon-conversion-fig-1.jpg Key Challenges: An important strategy for reducing global CO2 emissions calls for...

  7. Refining and end use study of coal liquids II - linear programming analysis

    SciTech Connect (OSTI)

    Lowe, C.; Tam, S.

    1995-12-31

    A DOE-funded study is underway to determine the optimum refinery processing schemes for producing transportation fuels that will meet CAAA regulations from direct and indirect coal liquids. The study consists of three major parts: pilot plant testing of critical upgrading processes, linear programming analysis of different processing schemes, and engine emission testing of final products. Currently, fractions of a direct coal liquid produced form bituminous coal are being tested in sequence of pilot plant upgrading processes. This work is discussed in a separate paper. The linear programming model, which is the subject of this paper, has been completed for the petroleum refinery and is being modified to handle coal liquids based on the pilot plant test results. Preliminary coal liquid evaluation studies indicate that, if a refinery expansion scenario is adopted, then the marginal value of the coal liquid (over the base petroleum crude) is $3-4/bbl.

  8. Clean air amendments put big burden on refinery planners

    SciTech Connect (OSTI)

    Scherr, R.C.; Smalley, G.A. Jr.; Norman, M.E. )

    1991-06-10

    The Clean Air Act Amendments of 1990 will not only require the production of reformulated gasoline but also have significant impact on other refinery-related construction. This must be considered when developing sound planning strategy. The three titles of the Clean Air Act Amendments that will have the greatest effect on refining are: Title I: Nonattainment; Title III: Air toxics; Title V: Permitting. To understand the ramifications of these amendments, it is necessary to review the interactions of new requirements with the permitting and construction schedule shown.

  9. Economic impact analysis for the petroleum refineries NESHAP. Draft report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    The purpose of this economic impact analysis (EIA) is to evaluate the effect of the control costs associated with the Petroleum Refining National Emission Standard for Hazardous Air Pollutants (NESHAP) on the behavior of the regulated petroleum refiners. The EIA was conducted based on the cost estimates for one hybrid regulatory option above the maximum achievable control technology (MACT) 'floor' (or minimum standard). This analysis compares the quantitative economic impacts of regulation to baseline industry conditions which would occur in the absence of regulation. The economic impacts of regulation are estimated for the industry, using costs which were supplied on both a national and a refinery level.

  10. Raman Scattering Sensor for On-Line Monitoring of Amines and Acid Gases

    SciTech Connect (OSTI)

    Uibel, Rory; Smith, Lee

    2010-05-20

    Sulfur and CO2 removal from hydrocarbon streams and power plant effluents are a major problem. The sulfur is normally in the form of H2S. These two acid gases are scrubbed using aqueous amine solutions that are difficult to control with conventional technology. Process Instruments Inc. developed Raman scattering technology for on-line, real-time monitoring of amine streams to improve their efficiency in scrubbing H2S and CO2 from hydrocarbon streams and power plant effluents. Improved control of amine and acid gas concentrations will allow refineries, natural gas processes and power plants to more efficiently scrub Sulfur and CO2, saving energy, time and financial resources.

  11. Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project is economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.

  12. "Bionic" Liquids from Lignin: Joint BioEnergy Institute Results Pave

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Way for Closed-Loop Biofuel Refineries Bionic" Liquids from Lignin: Joint BioEnergy Institute Results Pave the Way for Closed-Loop Biofuel Refineries - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure

  13. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect (OSTI)

    2009-12-01

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

  14. Biodegradation of oil refinery wastes under OPA and CERCLA

    SciTech Connect (OSTI)

    Gamblin, W.W.; Banipal, B.S.; Myers, J.M.

    1995-12-31

    Land treatment of oil refinery wastes has been used as a disposal method for decades. More recently, numerous laboratory studies have been performed attempting to quantify degradation rates of more toxic polycyclic aromatic hydrocarbon compounds (PAHs). This paper discusses the results of the fullscale aerobic biodegradation operations using land treatment at the Macmillan Ring-Free Oil refining facility. The tiered feasibility approach of evaluating biodegradation as a treatment method to achieve site-specific cleanup criteria, including pilot biodegradation operations, is discussed in an earlier paper. Analytical results of biodegradation indicate that degradation rates observed in the laboratory can be met and exceeded under field conditions and that site-specific cleanup criteria can be attained within a proposed project time. Also prevented are degradation rates and half-lives for PAHs for which cleanup criteria have been established. PAH degradation rates and half-life values are determined and compared with the laboratory degradation rates and half-life values which used similar oil refinery wastes by other in investigators (API 1987).

  15. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial

  16. REFINING AND END USE STUDY OF COAL LIQUIDS

    SciTech Connect (OSTI)

    Unknown

    2002-01-01

    This document summarizes all of the work conducted as part of the Refining and End Use Study of Coal Liquids. There were several distinct objectives set, as the study developed over time: (1) Demonstration of a Refinery Accepting Coal Liquids; (2) Emissions Screening of Indirect Diesel; (3) Biomass Gasification F-T Modeling; and (4) Updated Gas to Liquids (GTL) Baseline Design/Economic Study.

  17. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Breakout Session 2A-Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Santosh Gangwal, Director-Business Development, Energy Technologies, Southern Research Institute gangwal_biomass_2014.pdf (1.36

  18. Method for detecting trace impurities in gases

    DOE Patents [OSTI]

    Freund, Samuel M.; Maier, II, William B.; Holland, Redus F.; Beattie, Willard H.

    1981-01-01

    A technique for considerably improving the sensitivity and specificity of infrared spectrometry as applied to quantitative determination of trace impurities in various carrier or solvent gases is presented. A gas to be examined for impurities is liquefied and infrared absorption spectra of the liquid are obtained. Spectral simplification and number densities of impurities in the optical path are substantially higher than are obtainable in similar gas-phase analyses. Carbon dioxide impurity (.about.2 ppm) present in commercial Xe and ppm levels of Freon 12 and vinyl chloride added to liquefied air are used to illustrate the method.

  19. Method for detecting trace impurities in gases

    DOE Patents [OSTI]

    Freund, S.M.; Maier, W.B. II; Holland, R.F.; Beattie, W.H.

    A technique for considerably improving the sensitivity and specificity of infrared spectrometry as applied to quantitative determination of trace impurities in various carrier or solvent gases is presented. A gas to be examined for impurities is liquefied and infrared absorption spectra of the liquid are obtained. Spectral simplification and number densities of impurities in the optical path are substantially higher than are obtainable in similar gas-phase analyses. Carbon dioxide impurity (approx. 2 ppM) present in commercial Xe and ppM levels of Freon 12 and vinyl chloride added to liquefied air are used to illustrate the method.

  20. ARM - What are Greenhouse Gases?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans What are Greenhouse Gases? Carbon Dioxide Methane Gas Oxides of Nitrogen Halocarbons Ozone Water Vapor Greenhouse gases are atmospheric gases that trap infrared radiation emitted from the earth, lower atmosphere, or clouds or aerosols and, as

  1. Investigating and Using Biomass Gases

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Investigating and Using Biomass Gases Grades: 9-12 Topic: Biomass Authors: Eric Benson and Melissa Highfill Owner: National Renewable Energy Laboratory This educational material is...

  2. Method for introduction of gases into microspheres

    DOE Patents [OSTI]

    Hendricks, C.D.; Koo, J.C.; Rosencwaig, A.

    A method is described for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500..mu.. with both thin walls (0.5 to 4/sub ..mu../) and thick walls (5 to 20/sub ..mu../) that contain various fill gases, such as Ar, Kr, Xe, Br, D, H/sub 2/, DT, He, N/sub 2/, Ne, CO/sub 2/, etc., in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-form-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace.

  3. Opportunities for Biomass-Based Fuels and Products in a Refinery |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Opportunities for Biomass-Based Fuels and Products in a Refinery Opportunities for Biomass-Based Fuels and Products in a Refinery Breakout Session 2: Frontiers and Horizons Session 2-D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies Corinne Valkenburg, Staff Engineer, Pacific Northwest National Laboratory biomass13_male_2-d.pdf (891.45 KB) More Documents & Publications FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds 2013

  4. Improved oil refinery operations and cheaper crude oil to help reduce gasoline prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Improved oil refinery operations and cheaper crude oil to help reduce gasoline prices U.S. gasoline prices are expected to fall as more oil refineries come back on line and crude oil prices decline. In its new monthly forecast, the U.S. Energy Information Administration expects pump prices will average $3.38 a gallon during the second half of this year. That's down from the current weekly price of $3.50. A recovery in oil refinery fuel production, particularly from facilities that were temporary

  5. Process for removal of carbonyl sulfide in liquified hydrocarbon gases with absorption of acid gases

    SciTech Connect (OSTI)

    Beavon, D.K.; Mackles, M.

    1980-11-11

    Liquified hydrocarbon gases containing at least carbonyl sulfide as an impurity are purified by intimately mixing the liquified hydrocarbon gas with an aqueous absorbent for hydrogen sulfide in a hydrolysis zone maintained at a temperature and a pressure sufficient to maintain the liquified hydrocarbon gas in the liquid state and hydrolyze the carbonyl sulfide to hydrogen sulfide and carbon dioxide. The liquified hydrocarbon gas containing at least a portion of the formed carbonyl sulfide and carbon dioxide is separated from the liquid absorbent and passed to an absorption zone where it is contacted with a liquid hydrogen sulfide absorbent where at least the formed hydrogen sulfide is separated from the liquified petroleum gas. A stage of absorption of at least hydrogen sulfide may proceed mixing of the liquified hydrocarbon gas with the absorbent in the hydrolysis reaction zone. The absorbent employed does not combine irreversibly with carbonyl sulfide, hydrogen sulfide, and carbon dioxide, and preferably is an aqueous solution of diethanolamine.

  6. Method for introduction of gases into microspheres

    DOE Patents [OSTI]

    Hendricks, Charles D.; Koo, Jackson C.; Rosencwaig, Allan

    1981-01-01

    A method for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500.mu. with both thin walls (0.5 to 4.mu.) and thick walls (5 to 20.mu.) that contain various fill gases, such as Ar, Kr, Xe, Br, DT, H.sub.2, D.sub.2, He, N.sub.2, Ne, CO.sub.2, etc. in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace. Almost any gas can be introduced into the inner cavity of a glass microsphere by this method during the formation of the microsphere provided that the gas is diffused into the gel membrane or microsphere prior to its transformation into glass. The process of this invention provides a significant savings of time and related expense of filling glass microspheres with various gases. For example, the time for filling a glass microballoon with 1 atmosphere of DT is reduced from about two hours to a few seconds.

  7. Voluntary Reporting of Greenhouse Gases

    Reports and Publications (EIA)

    2011-01-01

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  8. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, M.

    1995-02-07

    A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

  9. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, Michael

    1995-01-01

    A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

  10. Valero: Houston Refinery Uses Plant-Wide Assessment to Develop an Energy Optimization and Management System

    SciTech Connect (OSTI)

    2005-08-01

    This Industrial Technologies Program case study describes an energy assessment team's recommendations for saving $5 million in energy, water, and other costs at an oil refinery in Houston, Texas.

  11. RENEWABLE LIQUID GETTERING PUMP

    DOE Patents [OSTI]

    Batzer, T.H.

    1962-08-21

    A method and structure were developed for pumping gases by simple absorption into a liquid gettering material. The invention comprises means ror continuously pumping a liquid getterrng material from a reservoir to the top of a generally vertical surface disposed in a vacuum pumping chamber to receive gaseous and other particles in the liquid gettering material which continuously flows downward over the vertical suiface. Means are provided for continuous removal, degassing, and return of a portion of the liquid gettering material from the reservoir connected with collectrng means at the base of the generally vertical plate. (AEC)

  12. Assuring Mechanical Integrity of Refinery Equipment Through Global ON-Stream Inspection

    SciTech Connect (OSTI)

    John W. Berthold

    2006-02-22

    The development of global on-stream inspection technology will have a dramatic effect on how refinery operations are managed in the U.S. in the future. Global on-stream inspection will provide assurance of the mechanical integrity of critical plant equipment and will allow refineries to operate more efficiently with less impact on our environment and with an increased margin of safety.

  13. Refinery Upgrading of Hydropyrolysis Oil from Biomass Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refinery Upgrading of Hydropyrolysis Oil from Biomass March 25,2015 Technology Area Review PI - Terry Marker Gas Technology Institute This presentation does not contain any proprietary, confidential, or otherwise restricted information Goals * Develop a cost-effective route for converting biomass to transportation fuels by first converting biomass to hydropyrolysis oil and then upgrading the hydropyrolysis oil in existing refinery equipment - Study properties and corrosion characteristics of

  14. Waste minimization and recycling of listed hazardous wastes in petroleum refineries

    SciTech Connect (OSTI)

    Koopersmith, C.A.

    1995-09-01

    Refiners have many options available to optimize hazardous waste programs. The Scalfuel{trademark} process is one such program for effectively transforming various types of refinery oily sludges into a high solids content, high Btu, low water content waste-derived fuel. This waste-derived fuel is widely accepted by permitted cement kilns. Five hundred thirty four truckloads from eight refineries have been successfully recycled at seven different cement kilns.

  15. Potential Impacts of Reductions in Refinery Activity on Northeast Petroleum Product Markets

    Gasoline and Diesel Fuel Update (EIA)

    .PDF 1. TABLE1.PDF Table 1. U.S. Supply, Disposition, and Ending Stocks of Crude Oil and Petroleum Products, January 2014 (Thousand Barrels) Commodity Supply Disposition Ending Stocks Field Production Renewable Fuels and Oxygenate Plant Net Production Refinery and Blender Net Production Imports Adjust- ments 1 Stock Change 2 Refinery and Blender Net Inputs Exports Products Supplied 3 Crude Oil 4 ............................................................ 248,959 - - - - 235,269 8,443 10,330

  16. Evaluation audit report. Bulgarian petroleum refinery, Neftochim, Bourgas. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Adams, N.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Neftochim refinery in Bourgas, Bulgaria. Other defined and specified goals include a consideration of refinery operating flexibility, an observation of the plants general condition, and comments on maintenance practices for their effect on operations. It is a further objective to characterize modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated. The report details the results of an Evaluation and Audit Study performed on selected process units. The conclusions of the study are a series of recommendations.

  17. Evaluation audit report. Czechoslovakian petroleum refinery, Slovnaft, Bratislava. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Slovnaft refinery in Bratislava, Czechoslovakia. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. It is a further objective to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  18. Evaluation audit report. Polish petroleum refinery, Plock, Poland. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and the reduction of emissions for the Mazovian refinery in Plock, Poland. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of their maintenance practices with their effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of the effort and the capital requirements anticipated.

  19. Evaluation audit report. Polish petroleum refinery, Gdansk, Poland. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    The primary objective of the report is to present opportunities for energy improvement and reduction of emissions for the Gdansk Refinery. A secondary objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated. Other goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching, including the use of coal as a substitute energy supply, and an observation of the plant's general condition and of its maintenance practices for their effect on operations.

  20. Evaluation audit report. Czechoslovakian petroleum refinery, Chemopetrol, Litvinov. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Chemopetrol Refinery in Litvinov, CSFR. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, an observation of the plants' general condition and the effect of its maintenance practice on operations. It is a further objective to characterize modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  1. Evaluation audit report. Romanian petroleum refinery, Petrotel, Ploiesti. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The objective of the report is to present opportunities for energy improvement and reduction of emissions for the Petrotel Refinery in Brazi near Ploiesti, Romania. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching opportunities, including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. A further objective is to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  2. Evaluation audit report. Czechoslovakian petroleum refinery, Kaucuk, Kralupy. A selective refinery analysis for operation, energy use, environmental impacts, and improvement opportunities, May 1992. Export trade information

    SciTech Connect (OSTI)

    Jurish, R.A.

    1992-05-01

    It is the objective of the report to present opportunities for energy improvement and reduction of emissions for the Kaucuk refinery in Kralupy, Czechoslovakia. Other defined and specified goals of the study include a consideration of refinery operating flexibility, an evaluation of fuel switching including the use of coal as a substitute for energy supply, and an observation of the plants general condition and of its maintenance practice for its effect on operations. It is a further objective to characterize the modifications for achieving expected benefits in accordance with the magnitude of effort and capital requirements anticipated.

  3. The sublethal effects of petroleum refinery effluents: Mixed function oxygenase (MFO) induction in rainbow trout

    SciTech Connect (OSTI)

    Sherry, J.; Scott, B.; Parrott, J.; Hodson, P.; Rao, S.

    1995-12-31

    Canada uses a single biological parameter which is based on the ability of rainbow trout (Oncorhynchus mykiss) to survive a 24 hour exposure to assess and regulate the toxicity of refinery effluents. The acute toxicity of Canadian refinery effluents is generally well controlled. Long term exposures to sublethal toxicants, which are not covered by the current regulations, could have adverse ecological effects. Since PAHs, such as benzo(a)pyrene, can occur in refinery effluents, the authors tested the hypothesis that refinery effluents can induce mixed-function oxygenase measured as ethoxyresorufin-O-deethylase activity (EROD) activity in fish. Two end of pipe effluent samples were collected from each of four Ontario refineries. All effluents induced EROD activity in young trout in a dose dependent manner. The EROD parameter has potential as a bioindicator of exposure to refinery effluents. The samples were also tested for toxicity to fathead minnow (Pimephales promelas) larvae and to a fish cell line (Ictalurus nebulosus). Fathead minnow growth was significantly reduced by six out of eight samples, and larval survival was affected by one sample. The in vitro data were less consistent: weak toxicity was detected in some samples but the dose response relationship was poor. Direct acting mutagens were detected in two effluents using the Ames Fluctuation assay.

  4. Petroleum Refinery Jobs and Economic Development Impact (JEDI) Model User Reference Guide

    SciTech Connect (OSTI)

    Goldberg, M.

    2013-12-31

    The Jobs and Economic Development Impact (JEDI) models, developed through the National Renewable Energy Laboratory (NREL), are user-friendly tools utilized to estimate the economic impacts at the local level of constructing and operating fuel and power generation projects for a range of conventional and renewable energy technologies. The JEDI Petroleum Refinery Model User Reference Guide was developed to assist users in employing and understanding the model. This guide provides information on the model's underlying methodology, as well as the parameters and references used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features, operation of the model, and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the model estimates job creation, earning and output (total economic activity) for a given petroleum refinery. This includes the direct, indirect and induced economic impacts to the local economy associated with the refinery's construction and operation phases. Project cost and job data used in the model are derived from the most current cost estimations available. Local direct and indirect economic impacts are estimated using economic multipliers derived from IMPLAN software. By determining the regional economic impacts and job creation for a proposed refinery, the JEDI Petroleum Refinery model can be used to field questions about the added value refineries may bring to the local community.

  5. Refining and end use of coal liquids. Quarterly report, January--March 1994

    SciTech Connect (OSTI)

    Not Available

    1994-08-01

    A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An intregral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. To enhance management of the study, the work has been divided into two parts, the Basic Program and Option 1. The objectives of the Basic Program are to: characterize the coal liquids; develop, an optimized refinery configuration for processing indirect and direct coal liquids; and develop a LP refinery model with the Process Industry Modeling System (PICS) software. The objectives of Option 1 are to: confirm the validity of the optimization work of the Basic Program; produce large quantities of liquid transportation fuel blending stocks; conduct engine emission tests; and determine the value and the processing costs of the coal liquids. The major efforts conducted during the first quarter of 1994 were in the areas of: subcontract preparation and negotiation; and linear programming modeling.

  6. ,"Virginia Natural Gas Nonhydrocarbon Gases Removed (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Virginia Natural Gas Nonhydrocarbon Gases Removed ... 2:52:09 AM" "Back to Contents","Data 1: Virginia Natural Gas Nonhydrocarbon Gases Removed ...

  7. Advanced bioreactor systems for gaseous substrates: Conversion of synthesis gas to liquid fuels and removal of SO{sub X} and NO{sub X} from coal combustion gases

    SciTech Connect (OSTI)

    Selvaraj, P.T.; Kaufman, E.N.

    1996-06-01

    The purpose of this research program is the development and demonstration of a new generation of gaseous substrate based bioreactors for the production of liquid fuels from coal synthesis gas and the removal of NO{sub x} and SO{sub x} species from combustion flue gas. This R&D program is a joint effort between the staff of the Bioprocessing Research and Development Center (BRDC) of ORNL and the staff of Bioengineering Resources, Inc. (BRI) under a Cooperative Research and Development Agreement (CRADA). The Federal Coordinating Council for Science, Engineering, and Technology report entitled {open_quotes}Biotechnology for the 21st Century{close_quotes} and the recent Energy Policy Act of 1992 emphasizes research, development, and demonstration of the conversion of coal to gaseous and liquid fuels and the control of sulfur and nitrogen oxides in effluent streams. This R&D program presents an innovative approach to the use of bioprocessing concepts that will have utility in both of these identified areas.

  8. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett; Zielke, Clyde W.

    1981-01-01

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  9. Assessment of the potential for refinery applications of inorganic membrane technology: An identification and screening analysis. Final report

    SciTech Connect (OSTI)

    Johnson, H.E.; Schulman, B.L.

    1993-05-01

    Commercial application of membrane technology in the separation of gas, liquid, and solid streams has grown to a business with worldwide revenues exceeding $1 billion annually. Use of organic membranes for industrial gas separation, particularly in the refining industry, is one of the major growth areas. However, organic membranes based on polymeric separation barriers, are susceptible to damage by liquids, and careful precautions must be taken to retain the system integrity. Researchers are currently developing small pore sized inorganic membranes which may substantially increase the efficiency and economics in selected refinery separation applications. Expected advantages of these advanced inorganic membranes include high permeability, high selectivity, and low manufacturing cost. SFA Pacific conducted a screening analysis to identify applications for inorganic membrane technology in the petroleum refining industry and their potential cost advantages over competing separation systems. Two meetings were held in connection with this project. Copies of Viewgraphs presented by SFA Pacific at these meetings are attached in Appendices A and C. Potential high priority applications and market impacts of advanced inorganic membrane technology in the refining industry are addressed in this report, and include the following areas: Competitive separation technologies; application of those technologies; incentives for inorganic membranes; market benefits and impacts of inorganic membranes.

  10. FEASIBILITY STUDY FOR A PETROLEUM REFINERY FOR THE JICARILLA APACHE TRIBE

    SciTech Connect (OSTI)

    John D. Jones

    2004-10-01

    A feasibility study for a proposed petroleum refinery for the Jicarilla Apache Indian Reservation was performed. The available crude oil production was identified and characterized. There is 6,000 barrels per day of crude oil production available for processing in the proposed refinery. The proposed refinery will utilize a lower temperature, smaller crude fractionation unit. It will have a Naphtha Hydrodesulfurizer and Reformer to produce high octane gasoline. The surplus hydrogen from the reformer will be used in a specialized hydrocracker to convert the heavier crude oil fractions to ultra low sulfur gasoline and diesel fuel products. The proposed refinery will produce gasoline, jet fuel, diesel fuel, and a minimal amount of lube oil. The refinery will require about $86,700,000 to construct. It will have net annual pre-tax profit of about $17,000,000. The estimated return on investment is 20%. The feasibility is positive subject to confirmation of long term crude supply. The study also identified procedures for evaluating processing options as a means for American Indian Tribes and Native American Corporations to maximize the value of their crude oil production.

  11. Probabilistic ecological risk assessment of selected PAH`s in sediments near a petroleum refinery

    SciTech Connect (OSTI)

    Arnold, W.R.; Biddinger, G.R.

    1995-12-31

    Sediment samples were collected and analyzed for a number of polynuclear aromatic hydrocarbons (PAHs) along a gradient from a petroleum refinery`s wastewater diffuser. These data were used to calculate the potential risk to aquatic organisms using probabilistic modeling and Monte Carlo sampling procedures. Sediment chemistry data were used in conjunction with estimates of Biota-Sediment Accumulation Factors and Non-Polar Narcosis Theory to predict potential risk to bivalves. Bivalves were the receptors of choice because of their lack of a well-developed enzymatic system for metabolizing PAHs. Thus, they represent a species of higher inherent risk of adverse impact. PAHs considered in this paper span a broad range of octanol-water partition coefficients. Results indicate negligible risk of narcotic effects from PAHs existing near the refinery wastewater discharge.

  12. Characterization study of Hungary's petroleum refinery industry: A sector in transition. Phase 1 final report

    SciTech Connect (OSTI)

    Not Available

    1991-08-01

    Part of a USAID effort to assist Hungary's oil refinery sector during a period of transition, the report reviews the sector, with emphasis on the two major refineries -- DKV and TIPO. Key findings are as follows: (1) DKV and TIPO staffs are superbly qualified and up to date and have aggressively promoted energy conservation for a decade. Environmental compliance lags considerably behind the West; (2) Refinery managers are facing serious problems as the country moves from a command to a market economy; (3) There is a need for new criteria for evaluating the best use of limited investment resources during the austere period of transition. Replacing petroleum hydrocarbon fuels with indigenous coal does not seem viable at present.

  13. Correcting systematic bias and instrument measurement drift with mzRefinery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-08-04

    Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. In conclusion, we report on availability; the mzRefinery tool is part of msConvert, availablemore » with the ProteoWizard open source package at http://proteowizard.sourceforge.net/« less

  14. Correcting systematic bias and instrument measurement drift with mzRefinery

    SciTech Connect (OSTI)

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-08-04

    Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. In conclusion, we report on availability; the mzRefinery tool is part of msConvert, available with the ProteoWizard open source package at http://proteowizard.sourceforge.net/

  15. Mazheikiai refinery modernization study. Final report. Volume 2. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 2 of the study.

  16. Mazheikiai refinery modernization study. Final report. Volume 3. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 3 of the study.

  17. Mazheikiai refinery modernization study. Final report. Volume 1. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The study, conducted by Foster Wheeler Corporation, was funded by the U.S. Trade and Development Agency on behalf of Lithuania's Ministry of Energy. The Mazheikiai Oil Refinery is the only one in the Baltic Region and serves the needs of Lithuania, Latvia, Estonia, and Kaliningrad. Before Lithuania's independence in 1990, the refinery was assured of crude supplies from Russia. However, since then the need has arisen to secure alternate sources of crude oil and the ability to process them. The purpose of the report is to provide recommendations to the Ministry of Energy for process improvements, environmental control measures, physical rehabilitation and energy conservation plans for the Mazheikiai Oil Refinery. This is Volume 1 of the study.

  18. Correcting systematic bias and instrument measurement drift with mzRefinery

    SciTech Connect (OSTI)

    Gibbons, Bryson C.; Chambers, Matthew C.; Monroe, Matthew E.; Tabb, David L.; Payne, Samuel H.

    2015-12-01

    MOTIVATION: Systematic bias in mass measurement adversely affects data quality and negates the advantages of high precision instruments. RESULTS: We introduce the mzRefinery tool into the ProteoWizard package for calibration of mass spectrometry data files. Using confident peptide spectrum matches, three different calibration methods are explored and the optimal transform function is chosen. After calibration, systematic bias is removed and the mass measurement errors are centered at zero ppm. Because it is part of the ProteoWizard package, mzRefinery can read and write a wide variety of file formats. AVAILABILITY: The mzRefinery tool is part of msConvert, available with the ProteoWizard open source package at http://proteowizard.sourceforge.net/

  19. Investigating and Using Biomass Gases

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Students will be introduced to biomass gasification and will generate their own biomass gases. Students generate these everyday on their own and find it quite amusing, but this time they’ll do it by heating wood pellets or wood splints in a test tube. They will collect the resulting gases and use the gas to roast a marshmallow. Students will also evaluate which biomass fuel is the best according to their own criteria or by examining the volume of gas produced by each type of fuel.

  20. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","6/2016","1/15/1985" ,"Release Date:","8/31/2016" ,"Next Release

  1. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    2010-06-01

    Funded by the American Recovery and Reinvestment Act of 2009 ENVIRON International Corporation, in collaboration with Callidus Technologies by Honeywell and Shell Global Solutions, Inc., will develop and demonstrate a full-scale fuel blending and combustion system. This system will allow a broad range of opportunity fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas, to be safely, cost-effectively, and efficiently utilized while generating minimal emissions of criteria pollutants. The project will develop a commercial technology for application in refinery and chemical plant process heaters where opportunity fuels are used.

  2. Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based

    Office of Scientific and Technical Information (OSTI)

    Oil Insertions (Technical Report) | SciTech Connect Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions Citation Details In-Document Search Title: Initial Assessment of U.S. Refineries for Purposes of Potential Bio-Based Oil Insertions In order to meet U.S. biofuel objectives over the coming decade the conversion of a broad range of biomass feedstocks, using diverse processing options, will be required. Further, the production of both gasoline and diesel

  3. Method of removing oxides of sulfur and oxides of nitrogen from exhaust gases

    DOE Patents [OSTI]

    Walker, Richard J.

    1986-01-01

    A continuous method is presented for removing both oxides of sulfur and oxides of nitrogen from combustion or exhaust gases with the regeneration of the absorbent. Exhaust gas is cleaned of particulates and HCl by a water scrub prior to contact with a liquid absorbent that includes an aqueous solution of bisulfite and sulfite ions along with a metal chelate, such as, an iron or zinc aminopolycarboxylic acid. Following contact with the combustion gases the spent absorbent is subjected to electrodialysis to transfer bisulfite ions into a sulfuric acid solution while splitting water with hydroxide and hydrogen ion migration to equalize electrical charge. The electrodialysis stack includes alternate layers of anion selective and bipolar membranes. Oxides of nitrogen are removed from the liquid absorbent by air stripping at an elevated temperature and the regenerated liquid absorbent is returned to contact with exhaust gases for removal of sulfur oxides and nitrogen oxides.

  4. Improving energy usage at the Borger Refinery and NGL Process Center

    SciTech Connect (OSTI)

    Haage, P.R.

    1982-05-01

    The Phillips Petroleum Company's Borger Refinery and NGL Process Center energy conservation program began prior to the 1973 oil embargo and was greatly intensified after that event. This paper describes recent progress made in the reduction of energy use at the facility, with emphasis on the furnace and boiler efficiency control program, computer control of fractionation columns, and the steam-trap survey program.

  5. Allocation of energy use in petroleum refineries to petroleum products : implications for life-cycle energy use and emission inventory of petroleum transportation fuels.

    SciTech Connect (OSTI)

    Wang, M.; Lee, H.; Molburg, J.

    2004-01-01

    Studies to evaluate the energy and emission impacts of vehicle/fuel systems have to address allocation of the energy use and emissions associated with petroleum refineries to various petroleum products because refineries produce multiple products. The allocation is needed in evaluating energy and emission effects of individual transportation fuels. Allocation methods used so far for petroleum-based fuels (e.g., gasoline, diesel, and liquefied petroleum gas [LPG]) are based primarily on mass, energy content, or market value shares of individual fuels from a given refinery. The aggregate approach at the refinery level is unable to account for the energy use and emission differences associated with producing individual fuels at the next sub-level: individual refining processes within a refinery. The approach ignores the fact that different refinery products go through different processes within a refinery. Allocation at the subprocess level (i.e., the refining process level) instead of at the aggregate process level (i.e., the refinery level) is advocated by the International Standard Organization. In this study, we seek a means of allocating total refinery energy use among various refinery products at the level of individual refinery processes. We present a petroleum refinery-process-based approach to allocating energy use in a petroleum refinery to petroleum refinery products according to mass, energy content, and market value share of final and intermediate petroleum products as they flow through refining processes within a refinery. The results from this study reveal that product-specific energy use based on the refinery process-level allocation differs considerably from that based on the refinery-level allocation. We calculated well-to-pump total energy use and greenhouse gas (GHG) emissions for gasoline, diesel, LPG, and naphtha with the refinery process-based allocation approach. For gasoline, the efficiency estimated from the refinery-level allocation

  6. Mining machinery/equipment/parts/services. Oil and gas field equipment/machinery/parts/supplies (Ecuador). Refinery equipment, parts, and accessories, March 1991. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1991-03-01

    The petroleum sector in Ecuador brings in about 65 percent of the country's revenue. Three of the refineries are located in the coastal region. The other two, plus the Liquified Petroleum Gas Plant (LPG), are located in the Oriente region (Amazon jungle). The refineries operate at about 85% of their installation capacity. The Petroindustrial and Petropeninsula investment plan for 1991 comtemplates the expansion of the Esmeraldas refinery to 110,000 barrels a day, and the up-grading of the Shushufindi and Libertad refineries located near the city of Guayaquil. The United States is by far the largest supplier of refinery equipment, parts and accessories, controlling about 90% of the total market.

  7. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coordination. Gases are stored either in the racks between buildings 6 and 7; toxic and corrosive gases are stored in Building 6, room 6C across the walkway from beamline...

  8. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the...

  9. Green House Gases | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Green House Gases Did You Know? If it were not for naturally occurring greenhouse gases, the Earth would be too cold to support life as we know it. Without the greenhouse effect,...

  10. Energy Efficiency and Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program, as ...

  11. EIA-Voluntary Reporting of Greenhouse Gases Program

    U.S. Energy Information Administration (EIA) Indexed Site

    of Greenhouse Gases Program Voluntary Reporting of Greenhouse Gases Program ***THE VOLUNTARY REPORTING OF GREENHOUSE GASES ("1605(b)") PROGRAM HAS BEEN SUSPENDED.*** This affects ...

  12. EIA-Voluntary Reporting of Greenhouse Gases Program - What are...

    U.S. Energy Information Administration (EIA) Indexed Site

    What are Greenhouse Gases? Voluntary Reporting of Greenhouse Gases Program What are Greenhouse Gases? Many chemical compounds found in the Earth's atmosphere act as "greenhouse ...

  13. Program development to identify and characterize potential emergency situations at a petroleum refinery and determination of industrial hygiene emergency responses

    SciTech Connect (OSTI)

    Oransky, J.J.; Delp, S.N.; Deppen, E.A.; Barrett, D.

    1995-12-31

    In the modern world the field of industrial hygiene continues to grow beyond the traditional definition of the profession. This case study documents the problem solving approach used to identify potential exposures and evaluate industrial hygiene preparedness to handle emergencies due to fire or major spill at a complex multi-process petroleum refinery. In the recent past an environmental engineer and industrial hygiene consulting firm was retained by a mature, multi-process petroleum refinery to assist in the program development to identify and characterize potential emergency situations due to a fire, major release, or spill. This study would assist the refinery in compliance with the process safety and emergency response standards and to protect refinery operations and fire fighting personnel by minimizing potential exposures and risk when responding to such a major incident.

  14. Evaluating the need and feasibility of cathodically protecting above ground storage tanks in a petroleum refinery

    SciTech Connect (OSTI)

    Barrien, P.; Solomon, I.

    1994-12-31

    Managing soil-side corrosion problems on Above Ground Storage Tanks (AGSTs) presents an important challenge to refinery corrosion engineers. Cathodic protection and periodic internal inspection are two methods of managing soil-side corrosion. Mobil Oil Australia conducted a study into the need and feasibility of cathodically protecting up to 120 tanks at its Altona refinery in Melbourne, Australia. The need was determined by assessing the corrosivity of the environment under the tanks from soil samples and inspection data, and the feasibility determined by conducting current drainage testing on representative tanks. Results indicated that the tanks can be cathodically protected at less than 10mA/m{sup 2} current density, using perimeter anodes. They also showed that there is little correlation between bulk foundation or surrounding soil properties, and soil-side corrosion. The paper also demonstrates how the extension of intervals between internal inspections can economically justify the application of cathodic protection.

  15. LPG recovery from refinery flare by waste heat powered absorption refrigeration

    SciTech Connect (OSTI)

    Erickson, D.C.; Kelly, F.

    1998-07-01

    A waste heat powered ammonia Absorption Refrigeration Unit (ARU) has commenced operation at the Colorado Refining Company in Commerce City, Colorado. The ARU provides 85 tons of refrigeration at 30 F to refrigerate the net gas/treat gas stream, thereby recovering 65,000 barrels per year of LPG which formerly was flared or burned as fuel. The ARU is powered by the 290 F waste heat content of the reform reactor effluent. An additional 180 tons of refrigeration is available at the ARU to debottleneck the FCC plant wet gas compressors by cooling their inlet vapor. The ARU is directly integrated into the refinery processes, and uses enhanced, highly compact heat and mass exchange components. The refinery's investment will pay back in less than two years from increased recovery of salable product, and CO{sub 2} emissions are decreased by 10,000 tons per year in the Denver area.

  16. U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Refinery Gas (Million Cubic Feet) U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 10,243 11,231 12,001 12,021 8,782 13,405 12,734 14,373 14,999 14,661 1990's 14,973 18,055 16,732 16,724 8,935 7,568 9,354 9,746 10,900 6,781 2000's 8,684 13,085 3,817 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  17. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  18. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  19. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  20. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  1. Evaluating electric-resistance-welded tubing for refinery and chemical plant applications

    SciTech Connect (OSTI)

    Polk, C.J.; Hotaling, A.C. )

    1993-02-01

    A laboratory technique was developed to assess the potential for preferential attack along the longitudinal seam of electric-resistance-welded (ERW) carbon steel tubing exposed to refinery and chemical plant process streams. Used in conjunction with an evaluation of mill fabrication practices, the test procedure can identify high-quality ERW products that can be used in many applications in place of seamless components at significant cost savings.

  2. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  3. Gas-liquid separator and method of operation

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev; Whitt, David Brandon

    2009-07-14

    A system for gas-liquid separation in electrolysis processes is provided. The system includes a first compartment having a liquid carrier including a first gas therein and a second compartment having the liquid carrier including a second gas therein. The system also includes a gas-liquid separator fluidically coupled to the first and second compartments for separating the liquid carrier from the first and second gases.

  4. Who lives near coke plants and oil refineries An exploration of the environmental inequity hypothesis

    SciTech Connect (OSTI)

    Graham, J.D.; Beaulieu, N.D.; Sussman, D.; Sadowitz, M.; Li, Y.C. )

    1999-04-01

    Facility-specific information on pollution was obtained for 36 coke plants and 46 oil refineries in the US and matched with information on populations surrounding these 82 facilities. These data were analyzed to determine whether environmental inequities were present, whether they were more economic or racial in nature, and whether the racial composition of nearby communities has changed significantly since plants began operations. The Census tracts near coke plants have a disproportionate share of poor and nonwhite residents. Multivariate analyses suggest that existing inequities are primarily economic in nature. The findings for oil refineries are not strongly supportive of the environmental inequity hypothesis. Rank ordering of facilities by race, poverty, and pollution produces limited (although not consistent) evidence that the more risky facilities tend to be operating in communities with above-median proportions of nonwhite residents (near coke plants) and Hispanic residents (near oil refineries). Over time, the radical makeup of many communities near facilities has changed significantly, particularly in the case of coke plants sited in the early 1900s. Further risk-oriented studies of multiple manufacturing facilities in various industrial sectors of the economy are recommended.

  5. The Use of Oil Refinery Wastes as a Dust Suppression Surfactant for Use in Mining

    SciTech Connect (OSTI)

    Dixon-Hardy, D.W.; Beyhan, S.; Ediz, I.G.; Erarslan, K.

    2008-10-15

    In this research, the suitability of a selection of petroleum refinery wastes as a dust suppressant were examined. Dust is a significant problem in surface and underground mining mainly because of its adverse effects on human health and machinery. Hence, dust control and suppression is a vital part of mine planning for mining engineers. Water is the oldest and the cheapest suppressant in dealing with the mine dusts. However, surfactant use has recently been used for a wider range of applications in the mining industry. In order to carry out laboratory experiments, a dust chamber was designed and manufactured. The chamber has an inlet for coal dust entrance and a nozzle for spraying water and the oil refinery wastes. Water and the surfactants were mixed at various ratios and then sprayed onto the coal dusts within the cell. Dust concentration was measured systematically to determine the effects of surfactant containing solution on the coal dust and the data obtained by the measurements were analyzed. The results showed that the oil refinery wastes could be used as a dust suppressant, which may create an economical utilization for the wastes concerned.

  6. APPARATUS FOR CATALYTICALLY COMBINING GASES

    DOE Patents [OSTI]

    Busey, H.M.

    1958-08-12

    A convection type recombiner is described for catalytically recombining hydrogen and oxygen which have been radiolytically decomposed in an aqueous homogeneous nuclear reactor. The device is so designed that the energy of recombination is used to circulate the gas mixture over the catalyst. The device consists of a vertical cylinder having baffles at its lower enda above these coarse screens having platinum and alumina pellets cemented thereon, and an annular passage for the return of recombined, condensed water to the reactor moderator system. This devicea having no moving parts, provides a simple and efficient means of removing the danger of accumulated hot radioactive, explosive gases, and restoring them to the moderator system for reuse.

  7. Refining and end use study of coal liquids. Quarterly report, October--December 1996

    SciTech Connect (OSTI)

    1996-12-31

    Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M.W. Kellog Co. as subcontractors, initiated a study on November 1, 1993 for the US Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. The work has been divided into two parts, the Basic Program and Option 1. The objectives of the Basic Program are to characterize the coal liquids, develop an optimized refinery configuration for processing indirect and direct coal liquids, and develop a LP refinery model with the Process Industry Modeling System (PIMS) software. The objectives of Option 1 are to confirm the validity of the optimization work of the Basic Program, produce large quantities of liquid transportation fuel blending stocks, conduct engine emission tests, and determine the value and the processing costs of the coal liquids. The major efforts during the reporting period, October through December 1996, were in the areas of Option 1 blending and Option 1 FCC production run.

  8. Refining and end use study of coal liquids. Quarterly report, October--December 1995

    SciTech Connect (OSTI)

    1995-12-31

    Bechtel, with South west research Institute, Amoco Oil R&D, and the M. W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the US Department of Energy`s Pittsburgh Energy Technology Center to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. To enhance management of the study, the work has been divided into two parts, the Basic Program and Option 1. The objectives of the Basic Program are to: characterize the coal liquids; develop an optimized refinery configuration for processing indirect and direct coal liquids; and develop a LP refinery model with Process Industry Modeling System software. The objective of Option 1 are to: confirm the validity of the optimization work of the Basic Program; produce large quantities of liquid transportation fuel blending stocks; conduct engine emission tests; and determine the value and the processing costs of the coal liquids. The major effort conducted during the fourth quarter of 1995 were in the areas of: IL catalytic cracking--microactivity tests were conducted on various wax blends; IL wax hydrocracking--a pilot plant run was conducted on a wax/petroleum blend; and DL2 characterization and fractionation.

  9. Refining and end use study of coal liquids. Quarterly report, July - September 1996

    SciTech Connect (OSTI)

    1996-12-31

    Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M. W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the U.S. Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. This 47-month study, with an approved budget of $4.4 million dollars, is being performed under DOE Contract Number DE-AC22-93PC91029. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. The major efforts conducted during the third quarter of 1996 were in the areas of hydrotreating production runs and FCC production run. 3 figs., 8 tabs.

  10. Refining and end use study of coal liquids. Quarterly report, January--March 1996

    SciTech Connect (OSTI)

    1996-09-01

    Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M. W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the US Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. The major efforts conducted during the first quarter of 1996 were in the areas of: DL2 light distillate hydrotreating; and DL2 heave distillate catalytic cracking.

  11. Solubilities of heavy fossil fuels in compressed gases

    SciTech Connect (OSTI)

    Monge, A. Jr.

    1982-01-01

    Design of processes for upgrading heavy fossil fuels such as coal-derived liquids, heavy petroleum fractions, tar sands, and shale oil, requires quantitative information for equilibrium properties of the fossil fuel in the presence of compressed light gases at elevated temperatures. Presented here are methods to predict and measure solubilities of heavy fossil fuels in compressed gases in the region ambient to 100 bar and 600 K. A molecular-thermodynamic model is used to predict heavy fossil-fuel solubilities. The heavy fuel is fractionated ina spinning-band column at low pressure and high reflux; each fraction is considered to be a pseudo-component. Each fraction is characterized by one vapor-pressure datum (obtained during fractionation), elemental analysis, and proton-NMR spectra (to determine aromaticity). Liquid-phase properties are obtained from the SWAP equation for vapor pressure and from a density correlation. Vapor-phase properties are obtained using the virial equation of state with virial coefficients from Kaul's correlation. The molecular-thermodynamic model has been used to establish a design-oriented computer program for calculating heavy, fossil-fuel solubility for general application in process design and, in particular, for isobaric condensation as a function of temperature as required for design of a continuous-flow heat exchanger. A total-vaporization technique is used to measure the solubilities of narrow-boiling, heavy fossil-fuel fractions in compressed gases. The solubility of a heavy fraction is determined from the volume of gas required to vaporize completely a small, measured mass of fossil-fuel sample. To test the molecular-thermodynamic model, the total-vaporization technique has been used to measure the solubilities of two Lurgi coal-tar fractions in compressed methane. Predicted and experimental solubilities agree well.

  12. Method of concurrently filtering particles and collecting gases

    SciTech Connect (OSTI)

    Mitchell, Mark A; Meike, Annemarie; Anderson, Brian L

    2015-04-28

    A system for concurrently filtering particles and collecting gases. Materials are be added (e.g., via coating the ceramic substrate, use of loose powder(s), or other means) to a HEPA filter (ceramic, metal, or otherwise) to collect gases (e.g., radioactive gases such as iodine). The gases could be radioactive, hazardous, or valuable gases.

  13. Method of concurrently filtering particles and collecting gases (Patent) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Patent: Method of concurrently filtering particles and collecting gases Citation Details In-Document Search Title: Method of concurrently filtering particles and collecting gases A system for concurrently filtering particles and collecting gases. Materials are be added (e.g., via coating the ceramic substrate, use of loose powder(s), or other means) to a HEPA filter (ceramic, metal, or otherwise) to collect gases (e.g., radioactive gases such as iodine). The gases could be

  14. Method and apparatus for separating mixtures of gases using an...

    Office of Scientific and Technical Information (OSTI)

    Method and apparatus for separating mixtures of gases using an acoustic wave Title: Method and apparatus for separating mixtures of gases using an acoustic wave A thermoacoustic ...

  15. New model more accurately tracks gases for underground nuclear...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model tracks gases for underground nuclear explosion detection New model more accurately tracks gases for underground nuclear explosion detection Scientists have developed a new, ...

  16. EPA's Recent Advance Notice on Greenhouse Gases | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EPA's Recent Advance Notice on Greenhouse Gases EPA's Recent Advance Notice on Greenhouse Gases Summary EPA's advanced notice of proposed rulemaking on mobile sources of greenhouse ...

  17. OSTIblog Articles in the greenhouse gases Topic | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    greenhouse gases Topic Carbon Sequestration - Helping to Save Our Beautiful World by Kathy ... Related Topics: carbon dioxide, carbon sequestration, climate change, greenhouse gases

  18. EIA-Voluntary Reporting of Greenhouse Gases Program - About the...

    U.S. Energy Information Administration (EIA) Indexed Site

    of Greenhouse Gases Program About the 1605(b) Program History Established by Section 1605(b) of the Energy Policy Act of 1992, the Voluntary Reporting of Greenhouse Gases ...

  19. EIA-Voluntary Reporting of Greenhouse Gases Program - Under Constructi...

    U.S. Energy Information Administration (EIA) Indexed Site

    of Greenhouse Gases Program This Page is Currently Under Construction Please check back at a later time For more information on the Voluntary Reporting of Greenhouse Gases ...

  20. EIA-Voluntary Reporting of Greenhouse Gases Program -Data and...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data and Reports Voluntary Reporting of Greenhouse Gases Program Data and Reports The first reporting cycle under the revised Voluntary Reporting of Greenhouse Gases Program closed ...

  1. EIA-Voluntary Reporting of Greenhouse Gases Program - Getting...

    U.S. Energy Information Administration (EIA) Indexed Site

    Getting Started Voluntary Reporting of Greenhouse Gases Program Getting Started Form ... The Voluntary Reporting of Greenhouse Gases Program suggests that prospective reporters ...

  2. EIA-Voluntary Reporting of Greenhouse Gases Program - Contact

    U.S. Energy Information Administration (EIA) Indexed Site

    Contact Voluntary Reporting of Greenhouse Gases Program Contact For more information on the Voluntary Reporting of Greenhouse Gases Program, contact us via e-mail, phone, fax, or ...

  3. Voluntary reporting of greenhouse gases, 1995

    SciTech Connect (OSTI)

    1996-07-01

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  4. Denitrification of combustion gases. [Patent application

    DOE Patents [OSTI]

    Yang, R.T.

    1980-10-09

    A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

  5. Case history of a toxicity identification/reduction evaluation (TI/RE) at a petroleum refinery

    SciTech Connect (OSTI)

    Arnold, W.R.; Zaleski, R.T.; Biddinger, G.R.; Simmerman, J.J.; Stewart, J.D.

    1994-12-31

    During an operational turn-around at a high conversion petroleum refinery, the final wastewater effluent became toxic to three fish species used in continuous on-line flow-through acute toxicity tests. Discharge of effluent to the receiving bay was promptly halted. Wastewater treatment continued and the treated effluent was diverted to a series of holding ponds with limited capacity. A refinery team was formed to coordinate toxicity identification studies as well as to facilitate modifications of waste disposal practices and treatment operations. A test program was conducted, consisting of one rainbow trout Phase 1 TIE and 84 strategic acute toxicity tests. As a result, a treatment methodology was identified within three days and within eight days of first observing toxicity a cationic water treatment polymer was identified as the primary toxicant. The toxicity was due to increased bioavailability of the polymer when suspended solids loads dropped during turn-around. Use of the polymer was immediately stopped and discharge to the bay was resumed with 100% survival of all three monitoring species. The authors present an overview of the studies and decisions leading to the successful identification and management of this situation.

  6. Lead exposure in a petroleum refinery during maintenance and repair activities

    SciTech Connect (OSTI)

    Booher, L.E.; Zampello, F.C.

    1994-02-01

    Exposure to inorganic lead (Pb) may result in a petroleum refinery when paints that contain Pb are disturbed. Frequently performed activities that disturb paint include welding, burning, cutting, abrasive blasting, sanding, grinding, and needle gun chipping. The purpose of the study reported in this article was: to determine the Pb content of paint on metal surfaces in a petroleum refinery; to measure air Pb concentrations during abrasive blasting, torch cutting and burning, and power disk sanding/grinding on surfaces coated with Pb paint; and to evaluate the effectiveness of worker exposure controls by monitoring worker blood Pb (PbB) levels. Pb levels on representative metal surfaces were measured, and most painted surfaces were found to contain significant amounts of Pb. Personal air samples collected indicated that abrasive blasting and torch burning/cutting resulted in elevated air Pb levels, while short duration power disk sanding (less than 30 minutes duration) did not result in elevated air Pb levels as compared to the Occupational Safety and Health Administration permissible exposure limit. Despite these elevated air Pb levels, exposure controls including personal protective equipment, housekeeping, showering, work area isolation, and training effectively prevented elevated worker PbB levels. 6 refs., 4 figs., 3 tabs.

  7. Achieving very low mercury levels in refinery wastewater by membrane filtration.

    SciTech Connect (OSTI)

    Urgun Demirtas, M.; Benda, P.; Gillenwater, P. S.; Negri, M. C.; Xiong, H.; Snyder, S. W.

    2012-05-15

    Microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes were evaluated for their ability to achieve the world's most stringent Hg discharge criterion (<1.3 ng/L) in an oil refinery's wastewater. The membrane processes were operated at three different pressures to demonstrate the potential for each membrane technology to achieve the targeted effluent mercury concentrations. The presence of mercury in the particulate form in the refinery wastewater makes the use of MF and UF membrane technologies more attractive in achieving very low mercury levels in the treated wastewater. Both NF and RO were also able to meet the target mercury concentration at lower operating pressures (20.7 bar). However, higher operating pressures ({ge}34.5 bar) had a significant effect on NF and RO flux and fouling rates, as well as on permeate quality. SEM images of the membranes showed that pore blockage and narrowing were the dominant fouling mechanisms for the MF membrane while surface coverage was the dominant fouling mechanism for the other membranes. The correlation between mercury concentration and particle size distribution was also investigated to understand mercury removal mechanisms by membrane filtration. The mean particle diameter decreased with filtration from 1.1 {+-} 0.0 {micro}m to 0.74 {+-} 0.2 {micro}m after UF.

  8. Biological production of products from waste gases

    DOE Patents [OSTI]

    Gaddy, James L.

    2002-01-22

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  9. EIAs Proposed NGL Realignment Statement

    Gasoline and Diesel Fuel Update (EIA)

    Statement 1 June 7, 2013 EIA's Proposed NGL Realignment Statement Over the past five years, liquids produced by natural gas processing plants (Natural Gas Plant Liquids, NGPL) and the gas liquids produced in refineries (Liquefied Refinery Gases, LRG) have increased by more than 20 percent. These increases resulted from the development of shale gas and tight oil, as well as growth in production of liquids-rich natural gas, driven by relatively high oil prices. This growth in supply of NGPL and

  10. Device for accurately measuring mass flow of gases

    DOE Patents [OSTI]

    Hylton, J.O.; Remenyik, C.J.

    1994-08-09

    A device for measuring mass flow of gases which utilizes a substantially buoyant pressure vessel suspended within a fluid/liquid in an enclosure is disclosed. The pressure vessel is connected to a weighing device for continuously determining weight change of the vessel as a function of the amount of gas within the pressure vessel. In the preferred embodiment, this pressure vessel is formed from inner and outer right circular cylindrical hulls, with a volume between the hulls being vented to the atmosphere external the enclosure. The fluid/liquid, normally in the form of water typically with an added detergent, is contained within an enclosure with the fluid/liquid being at a level such that the pressure vessel is suspended beneath this level but above a bottom of the enclosure. The buoyant pressure vessel can be interconnected with selected valves to an auxiliary pressure vessel so that initial flow can be established to or from the auxiliary pressure vessel prior to flow to or from the buoyant pressure vessel. 5 figs.

  11. Device for accurately measuring mass flow of gases

    DOE Patents [OSTI]

    Hylton, James O.; Remenyik, Carl J.

    1994-01-01

    A device for measuring mass flow of gases which utilizes a substantially buoyant pressure vessel suspended within a fluid/liquid in an enclosure. The pressure vessel is connected to a weighing device for continuously determining weight change of the vessel as a function of the amount of gas within the pressure vessel. In the preferred embodiment, this pressure vessel is formed from inner and outer right circular cylindrical hulls, with a volume between the hulls being vented to the atmosphere external the enclosure. The fluid/liquid, normally in the form of water typically with an added detergent, is contained within an enclosure with the fluid/liquid being at a level such that the pressure vessel is suspended beneath this level but above a bottom of the enclosure. The buoyant pressure vessel can be interconnected with selected valves to an auxiliary pressure vessel so that initial flow can be established to or from the auxiliary pressure vessel prior to flow to or from the buoyant pressure vessel.

  12. Refinery Integration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mary Biddy Sue Jones NREL PNNL This presentation does not contain any proprietary, confidential, or otherwise restricted information DOE Bioenergy Technologies Office (BETO) 2015 ...

  13. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C.J.; Mackenzie, P.D.

    1982-09-03

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  14. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C. Judson; MacKenzie, Patricia D.

    1985-01-01

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  15. 1,2,3-triazolium ionic liquids

    DOE Patents [OSTI]

    Luebke, David; Nulwala, Hunaid; Tang, Chau

    2014-12-09

    The present invention relates to compositions of matter that are ionic liquids, the compositions comprising substituted 1,2,3-triazolium cations combined with any anion. Compositions of the invention should be useful in the separation of gases and, perhaps, as catalysts for many reactions.

  16. Reformulated Gasoline Foreign Refinery Rules (Released in the STEO January 1998)

    Reports and Publications (EIA)

    1998-01-01

    On August 27, 1997, the Environmental Protection Agency (EPA) promulgated revised the rules that allow foreign refiners to establish and use individual baselines, but it would not be mandatory (the optional use of an individual refinery baseline is not available to domestic refiners.) If a foreign refiner did not establish and use an individual baseline, the gasoline they export to the United States would be regulated through the importer, and subject to the importer's baseline (most likely the statutory baseline). Specific regulatory provisions are implemented to ensure that the option to use an individual baseline would not lead to adverse environmental impacts. This involves monitoring the average quality of imported gasoline, and if a specified benchmark is exceeded, remedial action would be taken by adjusting the requirements applicable to imported gasoline.

  17. Oxidation of ultrathin GaSe

    SciTech Connect (OSTI)

    Thomas Edwin Beechem; McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; Kalugin, Nikolai G.; Kowalski, Brian M.; Brumbach, Michael T.; Spataru, Catalin D.; Pask, Jesse A.

    2015-10-26

    Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga2Se3 and amorphous Se. Furthermore, photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

  18. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  19. Managing biogeochemical cycles to reduce greenhouse gases

    SciTech Connect (OSTI)

    Post, Wilfred M; Venterea, Rodney

    2012-01-01

    This special issue focuses on terrestrial biogeochemical cycles as they relate to North America-wide budgeting and future projection of biogenic greenhouse gases (GHGs). Understanding the current magnitude and providing guidance on the future trajectories of atmospheric concentrations of these gases requires investigation of their (i) biogeochemical origins, (ii) response to climate feedbacks and other environmental factors, and (iii) susceptibility to management practices. This special issue provides a group of articles that present the current state of continental scale sources and sinks of biogenic GHGs and the potential to better manage them in the future.

  20. Oxidation of ultrathin GaSe

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thomas Edwin Beechem; McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; Kalugin, Nikolai G.; Kowalski, Brian M.; Brumbach, Michael T.; Spataru, Catalin D.; Pask, Jesse A.

    2015-10-26

    Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga2Se3 and amorphous Se. Furthermore, photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

  1. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  2. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  3. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab

  4. Optimizing Co-Processing of Bio-Oil in Refinery Unit Operations Using a Davison Criculating Riser Presentatio for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimizing Co-Processing of Bio-Oil in Refinery Unit Operations Using a Davison Circulating Riser (DCR) 2.4.2.402 March 25, 2015 Bio-Oil Technology Area Alan Zacher Pacific Northwest National Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement Develop a process to produce sustainable bio-fuels through co- processing biomass into a petroleum refinery unit operation. There is a need to know: How much stabilization is

  5. Strings of liquid beads for gas-liquid contact operations

    SciTech Connect (OSTI)

    Hattori, Kenji; Ishikawa, Mitsukuni; Mori, Y.H. . Dept. of Mechanical Engineering)

    1994-12-01

    Energy recovery from hot gases exhausted from power plants, garbage incineration facilities, and many industrial processes has been growing due to demands for saving the primary-energy consumption. A novel device for gas-liquid contact operations is proposed to feed a liquid onto wires (or threads) hanging down in a gas stream is proposed. The liquid disintegrates into beads strung on each wire at regular intervals; if the wire is moderately wettable, a thin film forms to sheathe the wire, thereby interconnecting the beads. Since the beads fall down slowly, which possibly renews the film flowing down even more slowly, a sufficient gas-liquid contact time is available even in a contactor with considerably limited height. An approximate calculation method is developed for predicting the variation in the temperature effectiveness for the liquid (the fractional approach of the liquid exit temperature to the gas inlet temperature) with the falling distance, assuming an applicability of strings-of-beads contactors to thermal energy recovery from hot gas streams.

  6. Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect (OSTI)

    Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra; Kumar, Ravi; Mehlman, Stewart

    2010-06-21

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

  7. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    Benson, Charles; Wilson, Robert

    2014-04-30

    This project culminated in the demonstration of a full-scale industrial burner which allows a broad range of “opportunity” gaseous fuels to be cost-effectively and efficiently utilized while generating minimal emissions of criteria air pollutants. The burner is capable of maintaining a stable flame when the fuel composition changes rapidly. This enhanced stability will contribute significantly to improving the safety and reliability of burner operation in manufacturing sites. Process heating in the refining and chemicals sectors is the primary application for this burner. The refining and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion of this project, an enabling technology did not exist that would allow these energy-intensive industries to take full advantage of opportunity fuels and thereby reduce their natural gas consumption. Opportunity gaseous fuels include biogas (from animal and agricultural wastes, wastewater plants, and landfills) as well as syngas (from the gasification of biomass, municipal solid wastes, construction wastes, and refinery residuals). The primary challenge to using gaseous opportunity fuels is that their composition and combustion performance differ significantly from those of conventional fuels such as natural gas and refinery fuel gas. An effective fuel-flexible burner must accept fuels that range widely in quality and change in composition over time, often rapidly. In Phase 1 of this project, the team applied computational fluid dynamics analysis to optimize the prototype burner’s aerodynamic, combustion, heat transfer, and emissions performance. In Phase 2, full-scale testing and refinement of two prototype burners were conducted in test furnaces at Zeeco’s offices in Broken Arrow, OK. These tests demonstrated that the full range of conventional and opportunity fuels could be utilized by the project’s burner while achieving robust flame stability and very low levels of

  8. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 2: Appendixes A--S

    SciTech Connect (OSTI)

    DeLuchi, M.A. |

    1993-11-01

    This volume contains the appendices to the report on Emission of Greenhouse Gases from the Use of Transportation Fuels and Electricity. Emissions of methane, nitrous oxide, carbon monoxide, and other greenhouse gases are discussed. Sources of emission including vehicles, natural gas operations, oil production, coal mines, and power plants are covered. The various energy industries are examined in terms of greenhouse gas production and emissions. Those industries include electricity generation, transport of goods via trains, trucks, ships and pipelines, coal, natural gas and natural gas liquids, petroleum, nuclear energy, and biofuels.

  9. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, Charles E. (Idaho Falls, ID)

    1997-01-01

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

  10. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, C.E.

    1997-06-10

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.

  11. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E.; Kenyon, Brian E.

    2001-05-15

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  12. LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Thornton, J.D.

    1957-12-31

    This patent relates to liquid-liquid extraction columns having a means for pulsing the liquid in the column to give it an oscillatory up and down movement, and consists of a packed column, an inlet pipe for the dispersed liquid phase and an outlet pipe for the continuous liquid phase located in the direct communication with the liquid in the lower part of said column, an inlet pipe for the continuous liquid phase and an outlet pipe for the dispersed liquid phase located in direct communication with the liquid in the upper part of said column, a tube having one end communicating with liquid in the lower part of said column and having its upper end located above the level of said outlet pipe for the dispersed phase, and a piston and cylinder connected to the upper end of said tube for applying a pulsating pneumatic pressure to the surface of the liquid in said tube so that said surface rises and falls in said tube.

  13. Gasification of refinery sludge in an updraft reactor for syngas production

    SciTech Connect (OSTI)

    Ahmed, Reem; Eldmerdash, Usama; Sinnathambi, Chandra M.

    2014-10-24

    The study probes into the investigation on gasification of dry refinery sludge. The details of the study includes; influence of operation time, oxidation temperature and equivalence ratios on carbon gas conversion rate, gasification efficiency, heating value and fuel gas yield are presented. The results show that, the oxidation temperature increased sharply up to 858°C as the operating time increased up to 36 min then bridging occurred at 39 min which cause drop in reaction temperature up to 819 °C. This bridging was found to affect also the syngas compositions, meanwhile as the temperature decreased the CO, H{sub 2}, CH{sub 4} compositions are also found to be decreases. Higher temperature catalyzed the reduction reaction (CO{sub 2}+C = 450 2CO), and accelerated the carbon conversion and gasification efficiencies, resulted in more solid fuel is converted to a high heating value gas fuel. The equivalence ratio of 0.195 was found to be the optimum value for carbon conversion and cold gas efficiencies, high heating value of gas, and fuel gas yield to reach their maximum values of 96.1 % and 53.7 %, 5.42 MJ Nm{sup −3} of, and 2.5 Nm{sup 3} kg{sup −1} respectively.

  14. Sensitivity of screening-level toxicity tests using soils from a former petroleum refinery

    SciTech Connect (OSTI)

    Pauwels, S.; Bureau, J.; Roy, Y.; Allen, B.; Robidoux, P.Y.; Soucy, M.

    1995-12-31

    The authors tested five composite soil samples from a former refinery. The samples included a reference soil (Mineral Oil and Grease, MO and G < 40 ppm), thermally-treated soil, biotreated soil, and two untreated soils. They evaluated toxicity using the earthworm E. foetida, lettuce, cress, barley, Microtox, green algae, fathead minnow, and D. magna. The endpoints measured were lethality, seed germination, root elongation, growth, and bioluminescence. Toxicity, as measured by the number of positive responses, increased as follows: biotreated soil < untreated soil No. 1 < reference soil < thermally-treated soil and untreated soil No. 2. The biotreated soil generated only one positive response, whereas the thermally-treated soil and untreated soil No. 2 generated five positive responses. The most sensitive and discriminant terrestrial endpoint was lettuce root elongation which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was barley seed germination for which no toxicity was detected. The most sensitive and discriminant aquatic endpoint was green algae growth which responded to untreated soil No. 1, thermally-treated soil, and reference soil. The least sensitive was D. magna for which no toxicity was detected. Overall, soil and aqueous extract toxicity was spotty and no consistent patterns emerged to differentiate the five soils. Biotreatment significantly reduced the effects of the contamination. Aqueous toxicity was measured in the reference soil, probably because of the presence of unknown dissolved compounds in the aqueous extract. Finally, clear differences in sensitivity existed among the test species.

  15. Optimization of ferric hydroxide coprecipitation process for selenium removal from petroleum refinery stripped four water

    SciTech Connect (OSTI)

    Gerhardt, M.B.; Marrs, D.R.; Roehl, R.

    1996-12-31

    Iron coprecipitation was used in bench-scale tests to remove selenium from stripped sour water generated by two petroleum refineries. Chlorine dioxide and hydrogen peroxide were found to convert selenocyanate in the stripped sour water to selenite, which can be removed by iron coprecipitation. An iodometric titration procedure was developed to determine the required oxidant dose. Iron coprecipitation reduced selenium concentrations by 40 to 99 percent in stripped sour water after chlorine dioxide pretreatment Removal was less effective with hydrogen peroxide as the oxidant: total selenium concentrations were reduced by 28 to 92 percent in stripped sour water after hydrogen peroxide pretreatment. Highest removals were obtained at the highest oxidant and iron doses. Sludges produced in coprecipitation tests were hazardous under California regulations. Ozone oxidized selenocyanate but prevented ferric hydroxide precipitation or coagulation. Air was ineffective at selenocyanate oxidation. Repeatedly contacting iron hydroxide with stripped sour water pretreated with hydrogen peroxide, in a simulation of a countercurrent adsorption process, increased the selenium adsorbed on the solids from 32 to 147 pg selenium per mg of iron, but some of the adsorbed selenite was oxidized to selenate and desorbed back into solution.

  16. Identification of the cause of weak acute toxicity to rainbow trout at a petroleum refinery

    SciTech Connect (OSTI)

    Arnold, W.R.; Zaleski, R.T.; Biddinger, G.R.

    1995-12-31

    The refinery in question performs flow through acute toxicity tests on its effluent four times per month using three fish species: fathead minnows (Pimephales promelas), threespine sticklebacks (Gasterosteus oculeatus) and rainbow trout (Oncorhynchus mykiss). Several months of monitoring data indicated a transient low level acute toxicity to rainbow trout. In most cases, several days were required for mortality to occur in the flow through tests and numerous attempts to reproduce toxicity in static and static renewal tests were unsuccessful. A decision was made to manipulate the effluent in an attempt to enhance the toxic effect in the static mode so that conventional methods could be used to identify the cause. these tests indicated that toxicity was pH dependent. Additional testing, using EPA`s Phase 1 Toxicity Identification Evaluation methods suggested that the cause of toxicity was probably an organic acid. Experiments were subsequently begun to identify the specific cause and source of toxicity. This paper reviews the problems confronted during the various phases of the study and the decisions that were made that eventually led to an understanding of the basis of toxicity.

  17. Biofacts: Fueling a stronger economy. Renewable fuel solutions for petroleum refineries

    SciTech Connect (OSTI)

    1995-07-01

    The DOE Biofuels Program is investigating processes to condition synthesis gas (syngas) produced from the gasification of biomass, coke, waste oils, and other inexpensive feedstocks and low-cost by-products. Syngas technologies offer refiners economical, flexible solutions to the challenges presented by today`s market forces and regulatory environment, such as: increasingly stringent environmental regulations that dictate the composition of petroleum products; increasingly sour crudes; increased coke production and hydrogen use resulting from heavier crude; increased disposal cost for coke and residuals oils; and decreasing hydrogen supply resulting from decreased catalytic reforming severity--a necessity to comply with requirements for reduced aromatic content. Most importantly, refiners can use the DOE syngas processes to upgrade refinery residuals and coke, which minimizes environmental problems and maximizes profitability. DOE`s solution also offers refiners the flexibility to economically supplement petroleum feedstocks with a wide variety of locally available renewable feedstocks that can be fed into the gasifier--feedstocks such as energy crops, municipal solid wastes, many industrial wastes, and agricultural by-products.

  18. A perimeter-based groundwater protection strategy for waste management units at a petroleum refinery

    SciTech Connect (OSTI)

    Wenzlau, R.K.

    1996-12-01

    This article presents a groundwater management strategy and its application to regulatory compliance for the Shell Oil Company Martinez Manufacturing Complex, a refinery located within northern California. The purpose of the strategy is to protect the beneficial uses of groundwater which are present beyond the facility boundary while recognizing the occurrence of limited degradation of groundwater upgradient of the perimeter. The strategy applies perimeter-based groundwater monitoring and control to two general sources of groundwater quality degradation: historic spill and leak sites and inactive waste management units. To regulate the groundwater contaminant plumes originating form historic spill and leak sites the California Regional Water Quality Control Board (Regional Board) has issued Site Cleanup Requirements (SCR). To satisfy the SCR Shell developed in 1989 a Basin Boundary Control Plan as the first implementation of the groundwater strategy. To regulate groundwater quality impacts from solid waste management units, the Regional Board issues Waste Discharge Requirements (WDR). In 1995 the Regional Board issued revised WDR that established consistency between waste management unit regulation and the facility groundwater management strategy. The Regional Board made two findings that allowed this consistency. The first finding was that the Points of Compliance for all 23 solid waste management units are at the down-gradient perimeter of the facility. The second finding was that all waste management units were within corrective action, regardless of whether a known release of waste constituents occurred from a given waste unit.

  19. Utilization and results of hazard and operability studies in a petroleum refinery

    SciTech Connect (OSTI)

    Pully, A.S. )

    1993-04-01

    The petroleum refining industry has been performing hazard analyses in process units to some extent since at least 1988 and in earnest since 1990, when the American Petroleum Institute published Recommended Practice No. 750, [open quotes]Process Hazards Management.[close quotes] The Hazard and Operability Study (HAZOPS) is the most widely used of the various analysis techniques available, in part because this highly structured technique is easy to teach and well-suited for continuous process units. The results of HAZOPS fall into two broad categories, tangible and intangible. The tangible results are obvious: worksheets which detail event scenarios for potential process deviations, and action items, or recommendations for changes to process equipment of procedures. In many cases, the action items address issues which have a purely economic impact or which are procedural in nature, involving little or no capital investment. The intangible results or products of a HAZOPS include: the training and knowledge gained by the team participants, and better utilization of limited capital funds resulting from more detailed up-front engineering when a HAZOPS is required prior to funding. An aggressive HAZOPS schedule also aids facilities in planning resources for process safety information updates where the necessary P ID's or PFD's are out-of-date. This paper details the experiences with HAZOPS at Chevron USA Products Company's Pascagoula, Mississippi Refinery. The manner in which HAZOPS are performed, the types of results obtained, and the benefits of the HAZOPS program are discussed. 8 refs., 1 fig., 1 tab.

  20. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  1. New process technology already existing in your refinery: Hydroprocessing-FCC Synergy

    SciTech Connect (OSTI)

    Stanger, C.W. Jr.; Fletcher, R.; Johnson, C.; Reid, T.

    1996-12-01

    New processing technology is now available to improve refinery operating margins. The cost of this technology is minor if a refiner has a VGO or Resid hydrotreater and an FCCU. The primary requirement is changing the way work is done. Addition of new capital can be an optional step. The New technology is Hydroprocessing-FCC Synergy. Redirecting the work effort to operate, optimize, and budget the FCC pretreater, the FCC and any FCC post-treaters as one unit can optimize margins. Calculating the unit operating margins on the difference of FCC final product value minus the pretreater and FCC operating costs highlights the new technology`s enhanced profitability. The synergy connectiveness is made through the hydrocarbon flow and properties. Selecting the proper conditions and catalyst to complement each other`s performance is the technical key. This paper discusses the techniques for catalyst and operating condition selection. The concept of changing formulations with processing age is discussed. Finally a case study comparing Hydroprocessing-FCC Synergy versus classical non-synergistic approaches is presented, including the effect of new Hydroprocessing and FCC catalysts on the profitability increase.

  2. Summary of the proceedings of the workshop on the refinery of the future

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This report on the Workshop on the Refinery of the Future has been prepared for participants to provide them with a succinct summary of the presentations, deliberations, and discussions. In preparing the summary, we have striven to capture the key findings (conclusions) and highlight the issues and concerns raised during the plenary and breakout sessions. The presentation of the summary of the proceedings follows the final workshop agenda, which is given in Section I; each section is tabbed to facilitate access to specific workshop topics. The material presented relies heavily on the outline summaries prepared and presented by the Plenary Session Chairman and the Facilitators for each breakout group. These summaries are included essentially as presented. In addition, individuals were assigned to take notes during each session; these notes were used to reconstruct critical issues that were discussed in more detail. The key comments made by the participants, which tended to represent the range of views expressed relative to the issues, are presented immediately following the facilitator`s summary outline in order to convey the flavor of the discussions. The comments are not attributed to individuals, since in many instances they represent a composite of several similar views expressed during the discussion. The facilitators were asked to review the writeups describing the outcomes of their sessions for accuracy and content; their suggested changes were incorporated. Every effort has thus been made to reconstruct the views expressed as accurately as possible; however, errors and/or misinterpretations undoubtedly have occurred.

  3. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect (OSTI)

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  4. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H.; Stegen, Gary E.

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  5. LIQUID TARGET

    DOE Patents [OSTI]

    Martin, M.D.; Salsig, W.W. Jr.

    1959-01-13

    A liquid handling apparatus is presented for a liquid material which is to be irradiated. The apparatus consists essentially of a reservoir for the liquid, a target element, a drain tank and a drain lock chamber. The target is in the form of a looped tube, the upper end of which is adapted to be disposed in a beam of atomic particles. The lower end of the target tube is in communication with the liquid in the reservoir and a means is provided to continuously circulate the liquid material to be irradiated through the target tube. Means to heat the reservoir tank is provided in the event that a metal is to be used as the target material. The apparatus is provided with suitable valves and shielding to provide maximum safety in operation.

  6. Traveling dark solitons in superfluid Fermi gases

    SciTech Connect (OSTI)

    Liao Renyuan; Brand, Joachim

    2011-04-15

    Families of dark solitons exist in superfluid Fermi gases. The energy-velocity dispersion and number of depleted particles completely determine the dynamics of dark solitons on a slowly varying background density. For the unitary Fermi gas, we determine these relations from general scaling arguments and conservation of local particle number. We find solitons to oscillate sinusoidally at the trap frequency reduced by a factor of 1/{radical}(3). Numerical integration of the time-dependent Bogoliubov-de Gennes equation determines spatial profiles and soliton-dispersion relations across the BEC-BCS crossover, and proves consistent with the scaling relations at unitarity.

  7. Study of electron transport in hydrocarbon gases

    SciTech Connect (OSTI)

    Hasegawa, H.; Date, H.

    2015-04-07

    The drift velocity and the effective ionization coefficient of electrons in the organic gases, C{sub 2}H{sub 2}, C{sub 2}H{sub 4}, C{sub 2}H{sub 6}, CH{sub 3}OH, C{sub 2}H{sub 5}OH, C{sub 6}H{sub 6}, and C{sub 6}H{sub 5}CH{sub 3}, have been measured over relatively wide ranges of density-reduced electric fields (E/N) at room temperature (around 300?K). The drift velocity was measured, based on the arrival-time spectra of electrons by using a double-shutter drift tube over the E/N range from 300 to 2800 Td, and the effective ionization coefficient (?????) was determined by the steady-state Townsend method from 150 to 3000 Td. Whenever possible, these parameters were compared with those available in the literature. It has been shown that the swarm parameters for these gases have specific tendencies, depending on their molecular configurations.

  8. Economic impacts of oil spills: Spill unit costs for tankers, pipelines, refineries, and offshore facilities. [Task 1, Final report

    SciTech Connect (OSTI)

    Not Available

    1993-10-15

    The impacts of oil spills -- ranging from the large, widely publicized Exxon Valdez tanker incident to smaller pipeline and refinery spills -- have been costly to both the oil industry and the public. For example, the estimated costs to Exxon of the Valdez tanker spill are on the order of $4 billion, including $2.8 billion (in 1993 dollars) for direct cleanup costs and $1.125 billion (in 1992 dollars) for settlement of damages claims caused by the spill. Application of contingent valuation costs and civil lawsuits pending in the State of Alaska could raise these costs appreciably. Even the costs of the much smaller 1991 oil spill at Texaco`s refinery near Anacortes, Washington led to costs of $8 to 9 million. As a result, inexpensive waming, response and remediation technologies could lower oil spin costs, helping both the oil industry, the associated marine industries, and the environment. One means for reducing the impact and costs of oil spills is to undertake research and development on key aspects of the oil spill prevention, warming, and response and remediation systems. To target these funds to their best use, it is important to have sound data on the nature and size of spills, their likely occurrence and their unit costs. This information could then allow scarce R&D dollars to be spent on areas and activities having the largest impact. This report is intended to provide the ``unit cost`` portion of this crucial information. The report examines the three key components of the US oil supply system, namely, tankers and barges; pipelines and refineries; and offshore production facilities. The specific purpose of the study was to establish the unit costs of oil spills. By manipulating this key information into a larger matrix that includes the size and frequency of occurrence of oil spills, it will be possible` to estimate the likely future impacts, costs, and sources of oil spills.

  9. Options for U.S. Petroleum Refineries to Process Additional Light Tight Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    - Energy Information Administration Petroleum & Other Liquids Glossary › FAQS › Overview Data Summary Prices Crude reserves and production Refining and processing Imports/exports & movements Stocks Consumption/sales All petroleum & other liquids data reports Analysis & Projections Major Topics Most popular Consumption & sales Crude reserves & production Imports/exports & movements Prices Projections Recurring Refining & processing Stocks All reports Browse

  10. Polycyclic aromatic hydrocarbons (PAHs): a possible cause of lung cancer mortality among nickel/copper smelter and refinery workers

    SciTech Connect (OSTI)

    Verma, D.K.; Julian, J.A.; Roberts, R.S.; Muir, D.C.; Jadon, N.; Shaw, D.S. )

    1992-05-01

    A retrospective industrial hygiene investigation was undertaken to explain the cause of a statistically significant excess lung cancer mortality observed in a subset of a large cohort of nickel workers involved in mining, smelting, and refining of nickel and copper in Ontario. The focus of this paper is to demonstrate how an industrial hygiene follow-up assessment of an epidemiologic finding can help to identify a likely cause. Polycyclic aromatic hydrocarbons (PAHs) alone or in association with particulate and gaseous contaminants (e.g., SO2) were likely the causative agents of the excess lung cancer observed among the lead welders, cranemen, and arc furnace workers of the copper refinery.

  11. Greenhouse Gases - Energy Explained, Your Guide To Understanding Energy -

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Environment > Greenhouse Gases Energy Explained - Home What Is Energy? Forms of Energy Sources of Energy Laws of Energy Units and Calculators Energy Conversion Calculators British Thermal Units (Btu) Degree-Days U.S. Energy Facts State and U.S. Territory Data Use of Energy In Industry For Transportation In Homes In Commercial Buildings Efficiency and Conservation Energy and the Environment Greenhouse Gases Effect on the Climate Where Greenhouse Gases Come

  12. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S.; Krajicek, Richard W.

    1981-01-01

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  13. Test Results For Physical Separation Of Tritium From Noble Gases...

    Office of Environmental Management (EM)

    Test Results For Physical Separation Of Tritium From Noble Gases And It's Implications For Sensitivity And Accuracy In Air And Stack Monitoring Test Results For Physical Separation ...

  14. EIA - Greenhouse Gas Emissions - High-GWP gases

    Gasoline and Diesel Fuel Update (EIA)

    5. High-GWP gases 5.1. Total emissions Greenhouse gases with high global warming potential (high-GWP gases) are hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6), which together represented 3 percent of U.S. greenhouse gas emissions in 2009. Emissions estimates for the high-GWP gases are provided to EIA by the EPA's Office of Air and Radiation. The estimates for emissions of HFCs not related to industrial processes or electric transmission are derived from the EPA

  15. EIA-Voluntary Reporting of Greenhouse Gases Program - Original...

    U.S. Energy Information Administration (EIA) Indexed Site

    Schedule Voluntary Reporting of Greenhouse Gases Program Revised Launch Schedule EIA will begin accepting both Start Year and Reporting Year reports using the Workbook Form on ...

  16. EIA-Voluntary Reporting of Greenhouse Gases Program - Section...

    U.S. Energy Information Administration (EIA) Indexed Site

    Section 1605 Text Voluntary Reporting of Greenhouse Gases Program Section 1605 Text Energy ... national aggregate emissions of each greenhouse gas for each calendar year of the ...

  17. EIA-Voluntary Reporting of Greenhouse Gases Program - Original...

    U.S. Energy Information Administration (EIA) Indexed Site

    Program Voluntary Reporting of Greenhouse Gases Program Original 1605(b) Program Section 1605(b) of the Energy Policy Act of 1992 established the Voluntary Reporting of Greenhouse ...

  18. EIA-Voluntary Reporting of Greenhouse Gases Program - Emission...

    U.S. Energy Information Administration (EIA) Indexed Site

    Emission Factors Voluntary Reporting of Greenhouse Gases Program Emission Factors and Global Warming Potentials The greenhouse gas emission factors and global warming potentials ...

  19. EIA-Voluntary Reporting of Greenhouse Gases Program - Original...

    U.S. Energy Information Administration (EIA) Indexed Site

    of Greenhouse Gases Program Original 1605(b) Program Calculation Tools The workbooks below were developed to assist participants in the original Voluntary Reporting of Greenhouse ...

  20. Federal Offshore--Gulf of Mexico Nonhydrocarbon Gases Removed...

    U.S. Energy Information Administration (EIA) Indexed Site

    Release Date: 06302016 Next Release Date: 07292016 Referring Pages: Nonhydrocarbon Gases Removed from Natural Gas Federal Offshore Gulf of Mexico Natural Gas Gross Withdrawals ...

  1. Deviation from the Knudsen law on quantum gases

    SciTech Connect (OSTI)

    Babac, Gulru

    2014-12-09

    Gas flow in micro/nano scale systems has been generally studied for the Maxwell gases. In the limits of very low temperature and very confined domains, the Maxwellian approximation can break down and the quantum character of the gases becomes important. In these cases, Knudsen law, which is one of the important equations to analyze rarefied gas flows is invalid and should be reanalyzed for quantum gases. In this work, the availability of quantum gas conditions in the high Knudsen number cases is discussed and Knudsen law is analyzed for quantum gases.

  2. BOC Lienhwa Industrial Gases BOCLH | Open Energy Information

    Open Energy Info (EERE)

    Lienhwa Industrial Gases (BOCLH) Place: Taipei, Taiwan Sector: Solar Product: BOCLH is a joint venture between the Lien Hwa Industrial Corporation and the BOC Group in the United...

  3. Removal of mercury from waste gases

    SciTech Connect (OSTI)

    Muster, U.; Marr, R.; Pichler, G.; Kremshofer, S.; Wilferl, R.; Draxler, J.

    1996-12-31

    Waste and process gases from thermal power, incineration and metallurgical plants or those from cement and alkali chloride industries contain metallic, inorganic and organic mercury. Widespread processes to remove the major amount of mercury are absorption and adsorption. Caused by the lowering of the emission limit from 200 to 50 {mu}g/m{sup 3} [STP] by national and European legislators, considerable efforts were made to enhance the efficiency of the main separation units of flue gas cleaning plants. Specially impregnated ceramic carriers can be used for the selective separation of metallic, inorganic and organic mercury. Using the ceramic reactor removal rates lower than 5 {mu}g/m{sup 3} [STP] of gaseous mercury and its compounds can be achieved. The ceramic reactor is active, regenerable and stable for a long term operation. 4 refs., 7 figs.

  4. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    1999-05-01

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  5. Capture and release of mixed acid gasses with binding organic liquids

    DOE Patents [OSTI]

    Heldebrant, David J. (Richland, WA); Yonker, Clement R. (Kennewick, WA)

    2010-09-21

    Reversible acid-gas binding organic liquid systems that permit separation and capture of one or more of several acid gases from a mixed gas stream, transport of the liquid, release of the acid gases from the ionic liquid and reuse of the liquid to bind more acid gas with significant energy savings compared to current aqueous systems. These systems utilize acid gas capture compounds made up of strong bases and weak acids that form salts when reacted with a selected acid gas, and which release these gases when a preselected triggering event occurs. The various new materials that make up this system can also be included in various other applications such as chemical sensors, chemical reactants, scrubbers, and separators that allow for the specific and separate removal of desired materials from a gas stream such as flue gas.

  6. Greenhouse gases: What is their role in climate change

    SciTech Connect (OSTI)

    Edmonds, J.A.; Chandler, W.U. ); Wuebbles, D. )

    1990-12-01

    This paper summarizes information relevant to understanding the role of greenhouse gases in the atmosphere. It examines the nature of the greenhouse effect, the Earth's radiation budget, the concentrations of these gases in the atmosphere, how these concentrations have been changing, natural processes which regulate these concentrations of greenhouse gases, residence times of these gases in the atmosphere, and the rate of release of gases affecting atmospheric composition by human activities. We address the issue of the greenhouse effect itself in the first section. In the second section we examine trends in atmospheric concentration of greenhouse gases and emissions sources. In the third section, we examine the natural carbon cycle and its role in determining the atmospheric residence time of carbon dioxide (CO{sub 2}). In the fourth section, we examine the role atmospheric chemistry plays in the determining the concentrations of greenhouse gases. This paper is not intended to be an exhaustive treatment of these issues. Exhaustive treatments can be found in other volumes, many of which are cited throughout this paper. Rather, this paper is intended to summarize some of the major findings, unknowns, and uncertainties associated with the current state of knowledge regarding the role of greenhouse gases in the atmosphere. 57 refs., 11 figs., 11 tabs.

  7. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, Larry W.; Herman, Harold

    1989-01-01

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases absorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel.

  8. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, L.W.; Herman, H.

    1988-05-05

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  9. Single particle density of trapped interacting quantum gases

    SciTech Connect (OSTI)

    Bala, Renu; Bosse, J.; Pathak, K. N.

    2015-05-15

    An expression for single particle density for trapped interacting gases has been obtained in first order of interaction using Greens function method. Results are easily simplified for homogeneous quantum gases and are found to agree with famous results obtained by Huang-Yang-Luttinger and Lee-Yang.

  10. National emission standards for hazardous air pollutants petroleum refineries. Background information for final standards. Summary of public comments and responses. Final report

    SciTech Connect (OSTI)

    1995-07-01

    National emission standards for hazardous air pollutants (NESHAP) are promulgated for the petroleum refinery industry under authority of section 112 of the Clean Air Act. This background information document provides technical information and analyses used in the development of the final NESHAP and Agency reponses to public comments on the proposed rule.

  11. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure Steam Reforming of Bio-Derived Liquids S. Ahmed, S. Lee, D. Papadias, and R. Kumar November 6, 2007 Laurel, MD Research sponsored by the Hydrogen, Fuel Cells, and Infrastructure Technologies Program of DOE's Office of Energy Efficiency and Renewable Energy Rationale and objective Rationale „ Steam reforming of liquid fuels at high pressures can reduce hydrogen compression costs - Much less energy is needed to pressurize liquids (fuel and water) than compressing gases (reformate or

  12. Fluidized bed pyrolysis to gases containing olefins

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-01-01

    Recent gasification data are presented for a system designed to produce liquid hydrocarbon fuel from various biomass feedstocks. The factors under investigation were feedstock type, fluidizing gas type, residence time, temperature and catalyst usage. The response was gas phase composition. A fluidized bed system was utilized with a separate regenerator-combustor. An olefin content as high as 39 mole % was achieved. Hydrogen/carbon monoxide ratios were easily manipulated via steam addition over a broad range with an autocatalytic effect apparent for most feedstocks.

  13. Regional respiratory tract absorption of inhaled reactive gases

    SciTech Connect (OSTI)

    Miller, F.J.; Overton, J.H.; Kimbell, J.S.; Russell, M.L.

    1992-06-29

    Highly reactive gases present unique problems due to the number of factors which must be taken into account to determine regional respiratory tract uptake. The authors reviewed some of the physical, chemical, and biological factors that affect dose and that must be understood to interpret toxicological data, to evaluate experimental dosimetry studies, and to develop dosimetry models. Selected dosimetry experiments involving laboratory animals and humans were discussed, showing the variability and uptake according to animal species and respiratory tract region for various reactive gases. New experimental dosimetry approaches, such as those involving isotope ratio mass spectroscopy and cyclotron generation reactive gases, were discussed that offer great promise for improving the ability to study regional respiratory tract absorption of reactive gases. Various dosimetry modeling applications were discussed which demonstrate: the importance of airflow patterns for site-specific dosimetry in the upper respiratory tract, the influence of the anatomical model used to make inter- and intraspecies dosimetric comparisons, the influence of tracheobronchial path length on predicted dose curves, and the implications of ventilatory unit structure and volume on dosimetry and response. Collectively, these examples illustrate important aspects of regional respiratory tract absorption of inhaled reactive gases. Given the complex nature of extent and pattern of injury in the respiratory tract from exposure to reactive gases, understanding interspecies differences in the absorption of reactive gases will continue to be an important area for study.

  14. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  15. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, Shih-Ger; Liu, David K.

    1992-01-01

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. are attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO and SO.sub.2 can be removed in an economic fashion.

  16. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, S.G.; Liu, D.K.

    1992-11-17

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  17. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, Claude R.; Ernstberger, Harold G.

    1988-01-01

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  18. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  19. Method of producing pyrolysis gases from carbon-containing materials

    DOE Patents [OSTI]

    Mudge, Lyle K.; Brown, Michael D.; Wilcox, Wayne A.; Baker, Eddie G.

    1989-01-01

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  20. World Energy Projection System Plus Model Documentation: Greenhouse Gases Model

    Reports and Publications (EIA)

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Greenhouse Gases Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  1. EIA-Voluntary Reporting of Greenhouse Gases Program - Why Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Reporting of Greenhouse Gases Program Why Report What Is the Purpose of Form EIA-1605? Form EIA-1605 provides the means for the voluntary reporting of greenhouse gas emissions, ...

  2. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  3. METHOD FOR PUMPING GASES AT LOW VACUUM PRESSURES

    DOE Patents [OSTI]

    Milleron, N.

    1962-06-01

    A method is given for pumping overpressure "pulses" or "bursts" of gases without a significant rise in base pressure within a "gettering-type" vacuum pump having surfaces within the pumping cavity coated with or comprising clean gettering metal, e.g., Mo or Ta. The cavity is first pumped down by any convenient means to an equilibrium base pressure in the range desired, generally below 10/sup -6/ mm Hg. At this pressure, the metal immediately adsorbs overpressures or "bursts" of gases striking same with thermal motion without raising the base pressure significantiy. Desorption takes place at an equilibrium rate which, of course, is dependent upon the equilibrium pressure, and such desorbed gases are continuously removed by diffuaion pump or other pumping, whereby said overpressures or "bursts" of gases are removed without a rise in the equilibrium pressure and/or back diffusion of the gaseous pulse from the pumping cavity. (AEC)

  4. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    isotope ratios in gases of thirty hot springs and geothermal wells and of five natural gas wells in the western United States show no relationship to regional conductive heat...

  5. New model more accurately tracks gases for underground nuclear explosion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    detection Model tracks gases for underground nuclear explosion detection New model more accurately tracks gases for underground nuclear explosion detection Scientists have developed a new, more thorough method for detecting underground nuclear explosions by coupling two fundamental elements-seismic models with gas-flow models. December 17, 2015 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and

  6. EIA - Emissions of Greenhouse Gases in the United States 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) This report-the eighteenth annual report-presents the U.S. Energy Information Administration's latest estimates of emissions for carbon dioxide, methane, nitrous oxide, and other greenhouse gases. Download the GHG Report Introduction For this report, activity data on coal and natural gas consumption and electricity sales and losses

  7. Where Greenhouse Gases Come From | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Where Greenhouse Gases Come From In the United States, greenhouse gas emissions come primarily from the burning of fossil fuels in energy use. Carbon Dioxide Carbon Dioxide is the main greenhouse gas. In 2013, 82% of human-caused greenhouse gas emissions were carbon dioxide emissions, resulting from the burning of fossil fuels, solid waste, trees, wood, and other chemical reactions. Methane and Other Gases Another greenhouse gas, methane, comes from landfills, coal mines, oil and natural gas

  8. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L.

    2000-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  9. EIA - Emissions of Greenhouse Gases in the United States 2009

    Gasoline and Diesel Fuel Update (EIA)

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) This report-the eighteenth annual report-presents the U.S. Energy Information Administration's latest estimates of emissions for carbon dioxide, methane, nitrous oxide, and other greenhouse gases. Download the GHG Report Introduction For this report, activity data on coal and natural gas consumption and electricity sales and losses

  10. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  11. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  12. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C.; Markun, Francis; Zawadzki, Mary T.

    1998-01-01

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  13. Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid

    DOE Patents [OSTI]

    Chang, Shih-Ger; Liu, David K.

    1992-01-01

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.

  14. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small

  15. Process for coal liquefaction by separation of entrained gases from slurry exiting staged dissolvers

    DOE Patents [OSTI]

    Givens, Edwin N.; Ying, David H. S.

    1983-01-01

    There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a solvent, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals are separated from the condensed dissolver effluent. In accordance with the improved process, fresh hydrogen is fed to each dissolver and the entrained gas from each dissolver is separated from the slurry phase and removed from the reactor system before the condensed phase is passed to the next dissolver in the series. In accordance with another process, the feeds to the dissolvers are such that the top of each downstream dissolver is used as a gas-liquid separator.

  16. Low-Pressure Solubility of Gases in Liquid Water | Open Energy...

    Open Energy Info (EERE)

    Water Abstract Abstract unavailable. Authors Emmerich Wilhelm, Rubin Battino and Robert J. Wilcock Published Journal Chemical reviews, 1977 DOI Not Provided Check for DOI...

  17. Carbon Capture and Sequestration (via Enhanced Oil Recovery) from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect (OSTI)

    Stewart Mehlman

    2010-06-16

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE’s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities

  18. Total Crude Oil and Petroleum Products Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Unfinished Oils Naphthas and Lighter Kerosene and

  19. Total Crude Oil and Petroleum Products Imports by Area of Entry

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Ethylene Propane Propylene Normal Butane Butylene Isobutane Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Fuel Other Renewable Diesel Fuel Other Renewable

  20. TABLE29.CHP:Corel VENTURA

    Gasoline and Diesel Fuel Update (EIA)

    9. Refinery Net Production of Finished Petroleum Products by PAD and Refining Districts, July 2004 Liquefied Refinery Gases ... 2,082 70...

  1. FAQs for Survey Forms 800, 810, and 820

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Liquefied Refinery Gases (LRG) are products of refinery processing (distillation, cracking, etc.) of crude oil and unfinished oils and include the following product Codes: - 641 ...

  2. Emissions of greenhouse gases in the United States 1997

    SciTech Connect (OSTI)

    1998-10-01

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  3. Hard probes of strongly-interacting atomic gases

    SciTech Connect (OSTI)

    Nishida, Yusuke

    2012-06-18

    We investigate properties of an energetic atom propagating through strongly interacting atomic gases. The operator product expansion is used to systematically compute a quasiparticle energy and its scattering rate both in a spin-1/2 Fermi gas and in a spinless Bose gas. Reasonable agreement with recent quantum Monte Carlo simulations even at a relatively small momentum k/kF > 1.5 indicates that our large-momentum expansions are valid in a wide range of momentum. We also study a differential scattering rate when a probe atom is shot into atomic gases. Because the number density and current density of the target atomic gas contribute to the forward scattering only, its contact density (measure of short-range pair correlation) gives the leading contribution to the backward scattering. Therefore, such an experiment can be used to measure the contact density and thus provides a new local probe of strongly interacting atomic gases.

  4. Influence of a combustion-driven oscillation on global mixing in the flame from a refinery flare

    SciTech Connect (OSTI)

    Langman, A.S.; Nathan, G.J.

    2011-01-15

    An assessment of the influence of strong combustion-driven oscillations on mixing rates and visible radiation in the flame from a full-scale refinery flare is reported. Importantly, the oscillations were generated naturally, with no external forcing, and at a high Reynolds number of 4 x 10{sup 6}. These conditions differentiate this study from those of previous investigations, which all involved some external forcing and were at a Re too low to ensure fully turbulent flow within the flame. A frame-by-frame analysis of video footage, providing good resolution of the instantaneous edge of each flame, was used to assess flame dimensions, and so to determine a global residence time. Since the flames are in the fast-chemistry regime, the visual imagers can be used to determine a global mixing rate. The analysis reveals a consistent picture that the combustion-driven oscillations do not result in a significant change to the global mixing rate, but do increase the visible radiation. This is in contrast to previous investigations, using externally forced jets, where forcing at the preferred mode has been found to increase mixing rates and reduce radiation. (author)

  5. Strategic planning for and implementation of reclaimed municipal waste water as make-up to a refinery cooling system

    SciTech Connect (OSTI)

    Francis, W.R.; Mazur, J.J.; Rao, N.M.

    1996-08-01

    This paper discusses the successful use of treated municipal plant waste water effluent (Title 22) in a refinery cooling water system. Conversion from well water to this make-up water source was preceded by developing a carefully crafted transition plan. Steps were taken to identify key system performance indicators, establish desired performance goals, and implement stringent monitoring and control protocols. In addition, all possible contingencies were considered and solutions developed. Treating Title 22 waters is very challenging and entails risks not associated with normal makeup waters. Several novel on-line monitoring and control tools are available which help minimize these risks while enhancing tower operation. Performance monitoring of critical system parameters is essential in order to provide early warning of problems so that corrective measures can be implemented. In addition, a high level of system automation enhances reliable operation. Corrosion, scaling and microbiological performance of the system with Title 22 water is discussed in comparison to previous well water make-up.

  6. Methanol production from eucalyptus wood chips. Attachment III. Florida's eucalyptus energy farm and methanol refinery: the background environment

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-04-01

    A wide array of general background information is presented on the Central Florida area in which the eucalyptus energy plantation and methanol refinery will be located. Five counties in Central Florida may be affected by the project, DeSoto, Hardee, Hillsborough, Manatee, and Polk. The human resources of the area are reviewed. Included are overviews of population demographic and economic trends. Land use patterns and the transportation are system described, and the region's archeological and recreational resources are evaluated. The region's air quality is emphasized. The overall climate is described along with noise and air shed properties. An analysis of the region's water resources is included. Ground water is discussed first followed by an analysis of surface water. Then the overall quality and water supply/demand balance for the area is evaluated. An overview of the region's biota is presented. Included here are discussions of the general ecosystems in Central Florida, and an analysis of areas with important biological significance. Finally, land resources are examined.

  7. REDISTRIBUTOR FOR LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Bradley, J.G.

    1957-10-29

    An improved baffle plate construction to intimately mix immiscible liquid solvents for solvent extraction processes in a liquid-liquid pulse column is described. To prevent the light and heavy liquids from forming separate continuous homogeneous vertical channels through sections of the column, a baffle having radially placed rectangular louvers with deflection plates opening upon alternate sides of the baffle is placed in the column, normal to the axis. This improvement substantially completely reduces strippiig losses due to poor mixing.

  8. Radiolytic and thermal generation of gases from Hanford grout samples

    SciTech Connect (OSTI)

    Meisel, D.; Jonah, C.D.; Kapoor, S.; Matheson, M.S.; Mulac, W.A.

    1993-10-01

    Gamma irradiation of WHC-supplied samples of grouted Tank 102-AP simulated nonradioactive waste has been carried out at three dose rates, 0.25, 0.63, and 130 krad/hr. The low dose rate corresponds to that in the actual grout vaults; with the high dose rate, doses equivalent to more than 40 years in the grout vault were achieved. An average G(H{sub 2}) = 0.047 molecules/100 eV was found, independent of dose rate. The rate of H2 production decreases above 80 Mrad. For other gases, G(N{sub 2}) = 0.12, G(O{sub 2}) = 0.026, G(N{sub 2}O) = 0.011 and G(CO) = 0.0042 at 130 krad/hr were determined. At lower dose rates, N{sub 2} and O{sub 2} could not be measured because of interference by trapped air. The value of G(H{sub 2}) is higher than expected, suggesting segregation of water from nitrate and nitrite salts in the grout. The total pressure generated by the radiolysis at 130 krad/h has been independently measured, and total amounts of gases generated were calculated from this measurement. Good agreement between this measurement and the sum of all the gases that were independently determined was obtained. Therefore, the individual gas measurements account for most of the major components that are generated by the radiolysis. At 90 {degree}C, H{sub 2}, N{sub 2}, and N{sub 2}O were generated at a rate that could be described by exponential formation of each of the gases. Gases measured at the lower temperatures were probably residual trapped gases. An as yet unknown product interfered with oxygen determinations at temperatures above ambient. The thermal results do not affect the radiolytic findings.

  9. Oklahoma Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring Pages: Nonhydrocarbon Gases Removed from Natural Gas Oklahoma Natural Gas Gross Withdrawals and Production

  10. Other States Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Other States Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 NA NA NA NA NA NA NA NA NA NA NA NA 1997 513 491 515 539 557 534 541 579 574 585 558 573 1998 578 536 591 581 517 456 486 486 471 477 457 468 1999 466 438 489 495 499 510 547 557 544 555 541 579 2000 587 539 605 587 615 570 653 629 591 627 609 611 2001 658 591 677 690 718 694 692 679

  11. Michigan Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring Pages: Nonhydrocarbon Gases Removed from Natural Gas Michigan Natural Gas Gross Withdrawals and Production

  12. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I.

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  13. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I.; Dietz, Russell N.

    1994-01-01

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  14. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  15. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  16. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu; King, David L.; Liu, Jun; Huo, Qisheng

    2012-04-17

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  17. Methods of forming and using porous structures for energy efficient separation of light gases by capillary condensation

    DOE Patents [OSTI]

    Calamur, Narasimhan; Carrera, Martin E.; Devlin, David J.; Archuleta, Tom

    2000-01-01

    The present invention relates to an improved method and apparatus for separating one or more condensable compounds from a mixture of two or more gases of differing volatilities by capillary fractionation in a membrane-type apparatus, and a method of forming porous structures therefor. More particularly, the invention includes methods of forming and using an apparatus consisting, at least in part, of a porous structure having capillary-type passages extending between a plurality of small openings on the first side and larger openings on a second side of the structure, the passages being adapted to permit a condensed liquid to flow therethrough substantially by capillary forces, whereby vapors from the mixture are condensed, at least in part, and substantially in and adjacent to the openings on the first side, and are caused to flow in a condensed liquid state, substantially in the absence of vapor, from the openings on the first side to the openings on the second side.

  18. The CNG process: Acid gas removal with liquid carbon dioxide

    SciTech Connect (OSTI)

    Liu, Y.C.; Auyang, L.; Brown, W.R.

    1987-01-01

    The CNG acid gas removal process has two unique features: the absorption of sulfur-containing compounds and other trace contaminants with liquid carbon dioxide, and the regeneration of pure liquid carbon dioxide by triple-point crystallization. The process is especially suitable for treating gases which contain large amounts of carbon dioxide and much smaller amounts (relative to carbon dioxide) of hydrogen sulfide. Capital and energy costs are lower than conventional solvent processes. Further, products of the CNG process meet stringent purity specifications without undue cost penalties. A process demonstration unit has been constructed and operated to demonstrate the two key steps of the CNG process. Hydrogen sulfide and carbonyl sulfide removal from gas streams with liquid carbon dioxide absorbent to sub-ppm concentrations has been demonstrated. The production of highly purified liquid carbon dioxide (less than 0.1 ppm total contaminant) by triple-point crystallization also has been demonstrated.

  19. First AEO2015 Liquid Fuels Markets Working Group Meeting

    U.S. Energy Information Administration (EIA) Indexed Site

    AEO2016: revise refinery process units costs; non-petroleum process study to inform ... Factors influencing crude oil or condensate exports include logistics and the different ...

  20. ionic liquids biological-ly derived from lignin and hemicellulose

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Predictive Simulation of Engines Transportation Energy Consortiums Engine Combustion ... Results Pave the Way for Closed-Loop Biofuel Refineries Biofuels, Biomass, ...

  1. Use of low temperature blowers for recirculation of hot gases

    DOE Patents [OSTI]

    Maru, H.C.; Forooque, M.

    1982-08-19

    An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

  2. OPTIONS FOR ABATING GREENHOUSE GASES FROM EXHAUST STREAMS.

    SciTech Connect (OSTI)

    FTHENAKIS,V.

    2001-12-01

    This report examines different alternatives for replacing, treating, and recycling greenhouse gases. It is concluded that treatment (abatement) is the only viable short-term option. Three options for abatement that were tested for use in semiconductor facilities are reviewed, and their performance and costs compared. This study shows that effective abatement options are available to the photovoltaic (PV) industry, at reasonable cost.

  3. Habitat of natural gases in Papua New Guinea

    SciTech Connect (OSTI)

    Schoell, M.; Beeunas, M.A. Baskin, D.K.; Monnier, F. ); Eisenberg, L.I.; Valenti, G.L. )

    1996-01-01

    Thermogenic natural gases in Papua New Guinea occur in hanging wall anticlines and related structures along a 160 mile section of the Papuan fold and thrust belt between S.E. Hedinia in the SE and Pnyang in the NW. Isotopic compositions of the oil associated gases in the SE between Hedinia and Mananda varies little ([delta][sup l3]C[sub CH4]=-44[+-]2[per thousand] and [delta]D[sub CH4]=-200[+-]20[per thousand]). However, subtle isotopic and compositional patterns in these gases are structurally controlled and indicate primary differences in the filling history of the individual structures. In addition, secondary redistribution of the gases between the Agogo and Iagifu structure can be traced through isotopic similarities. In S.E. Mananda, however, gas isotope patterns are affected by bacterial degradation of the gas. Tire concentration of CO[sub 2] in the oil associated gases in the SE is low (0.6-3.0 %) and the carbon isotope values ([delta][sup 13]C[sub CO2]=-10 to -19[per thousand]) suggest an organic origin with minor inorganic contributions. Gas in the Juha structure ([delta][sup 13]C[sub CH4]=-36.8[per thousand]) is likely from a more mature source and has a CO[sub 2] concentration of 9.6% with a [delta][sup 13]C[sub CO2]=-5.9[per thousand], indicating additional CO[sub 2] generating processes in this area, likely related to magmatic activity in the vicinity of the Juha structure. The Pnyang structure in the NW of the area holds a gas ([delta][sup 13]C[sub CH4]-40.5[per thousand]) which is isotopically intermediate between the Juha gas and the oil associated gases in the SE. The low CO[sub 2] concentration of 0.2% suggests that Pnyang is sourced from a gas kitchen similar to, but more mature than, the kitchen for the oil associated gases in the SE of the province. This is consistent with the high GOR in this structure and the association of the gas with a high API gravity condensate.

  4. Habitat of natural gases in Papua New Guinea

    SciTech Connect (OSTI)

    Schoell, M.; Beeunas, M.A. Baskin, D.K.; Monnier, F.; Eisenberg, L.I.; Valenti, G.L.

    1996-12-31

    Thermogenic natural gases in Papua New Guinea occur in hanging wall anticlines and related structures along a 160 mile section of the Papuan fold and thrust belt between S.E. Hedinia in the SE and Pnyang in the NW. Isotopic compositions of the oil associated gases in the SE between Hedinia and Mananda varies little ({delta}{sup l3}C{sub CH4}=-44{+-}2{per_thousand} and {delta}D{sub CH4}=-200{+-}20{per_thousand}). However, subtle isotopic and compositional patterns in these gases are structurally controlled and indicate primary differences in the filling history of the individual structures. In addition, secondary redistribution of the gases between the Agogo and Iagifu structure can be traced through isotopic similarities. In S.E. Mananda, however, gas isotope patterns are affected by bacterial degradation of the gas. Tire concentration of CO{sub 2} in the oil associated gases in the SE is low (0.6-3.0 %) and the carbon isotope values ({delta}{sup 13}C{sub CO2}=-10 to -19{per_thousand}) suggest an organic origin with minor inorganic contributions. Gas in the Juha structure ({delta}{sup 13}C{sub CH4}=-36.8{per_thousand}) is likely from a more mature source and has a CO{sub 2} concentration of 9.6% with a {delta}{sup 13}C{sub CO2}=-5.9{per_thousand}, indicating additional CO{sub 2} generating processes in this area, likely related to magmatic activity in the vicinity of the Juha structure. The Pnyang structure in the NW of the area holds a gas ({delta}{sup 13}C{sub CH4}-40.5{per_thousand}) which is isotopically intermediate between the Juha gas and the oil associated gases in the SE. The low CO{sub 2} concentration of 0.2% suggests that Pnyang is sourced from a gas kitchen similar to, but more mature than, the kitchen for the oil associated gases in the SE of the province. This is consistent with the high GOR in this structure and the association of the gas with a high API gravity condensate.

  5. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  6. Conversion of cellulosic wastes to liquid fuels

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-09-01

    The current status and future plans for a project to convert waste cellulosic (biomass) materials to quality liquid hydrocarbon fuels is described. The basic approach is indirect liquefaction, i.e., thermal gasification followed by catalytic liquefaction. The indirect approach results in separation of the oxygen in the biomass feedstock, i.e., oxygenated compounds do not appear in the liquid hydrocarbon fuel product. The process is capable of accepting a wide variety of feedstocks. Potential products include medium quality gas, normal propanol, diesel fuel and/or high octane gasoline. A fluidized bed pyrolysis system is used for gasification. The pyrolyzer can be fluidized with recycle pyrolysis gas, steam or recycle liquefaction system off gas or some combination thereof. Tars are removed in a wet scrubber. Unseparated pyrolysis gases are utilized as feed to a modified Fischer-Tropsch reactor. The liquid condensate from the reactor consists of a normal propanol-water phase and a paraffinic hydrocarbon phase. The reactor can be operated to optimize for either product. The following tasks were specified in the statement of work for the contract period: (1) feedstock studies; (2) gasification system optimization; (3) waste stream characterization; and (4) liquid fuels synthesis. In addition, several equipment improvements were implemented.

  7. Quantum fluctuations in the BCS-BEC crossover of two-dimensional Fermi gases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, Lianyi; Lu, Haifeng; Cao, Gaoqing; Hu, Hui; Liu, Xia -Ji

    2015-08-14

    We present a theoretical study of the ground state of the BCS-BEC crossover in dilute two-dimensional Fermi gases. While the mean-field theory provides a simple and analytical equation of state, the pressure is equal to that of a noninteracting Fermi gas in the entire BCS-BEC crossover, which is not consistent with the features of a weakly interacting Bose condensate in the BEC limit and a weakly interacting Fermi liquid in the BCS limit. The inadequacy of the two-dimensional mean-field theory indicates that the quantum fluctuations are much more pronounced than those in three dimensions. In this work, we show thatmore » the inclusion of the Gaussian quantum fluctuations naturally recovers the above features in both the BEC and the BCS limits. In the BEC limit, the missing logarithmic dependence on the boson chemical potential is recovered by the quantum fluctuations. Near the quantum phase transition from the vacuum to the BEC phase, we compare our equation of state with the known grand canonical equation of state of two-dimensional Bose gases and determine the ratio of the composite boson scattering length aB to the fermion scattering length a2D. We find aB ≃ 0.56a2D, in good agreement with the exact four-body calculation. As a result, we compare our equation of state in the BCS-BEC crossover with recent results from the quantum Monte Carlo simulations and the experimental measurements and find good agreements.« less

  8. Adaptive Liquid Crystal Windows

    SciTech Connect (OSTI)

    Taheri, Bahman; Bodnar, Volodymyr

    2011-12-31

    Energy consumption by private and commercial sectors in the U.S. has steadily grown over the last decade. The uncertainty in future availability of imported oil, on which the energy consumption relies strongly, resulted in a dramatic increase in the cost of energy. About 20% of this consumption are used to heat and cool houses and commercial buildings. To reduce dependence on the foreign oil and cut down emission of greenhouse gases, it is necessary to eliminate losses and reduce total energy consumption by buildings. To achieve this goal it is necessary to redefine the role of the conventional windows. At a minimum, windows should stop being a source for energy loss. Ideally, windows should become a source of energy, providing net gain to reduce energy used to heat and cool homes. It is possible to have a net energy gain from a window if its light transmission can be dynamically altered, ideally electronically without the need of operator assistance, providing optimal control of the solar gain that varies with season and climate in the U.S. In addition, the window must not require power from the building for operation. Resolution of this problem is a societal challenge and of national interest and will have a broad global impact. For this purpose, the year-round, allclimate window solution to provide an electronically variable solar heat gain coefficient (SHGC) with a wide dynamic range is needed. AlphaMicron, Inc. (AMI) developed and manufactured 1ft 1ft prototype panels for the worlds first auto-adjusting Adaptive Liquid Crystal Windows (ALCWs) that can operate from sunlight without the need for external power source and demonstrate an electronically adjustable SHGC. This novel windows are based on AlphaMicrons patented e-Tint technology, a guesthost liquid crystal system implemented on flexible, optically clear plastic films. This technology is suitable both for OEM and aftermarket (retro-fitting) lamination to new and existing windows. Low level of power

  9. Petroleum Supply Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    0.PDF Table 20. Blender Net Inputs of Petroleum Products by PAD Districts, January 2014 (Thousand Barrels) Commodity PAD District 1 - East Coast PAD District 2 - Midwest East Coast Appalachian No. 1 Total Indiana, Illinois, Kentucky Minnesota, Wisconsin, North and South Dakota Oklahoma, Kansas, Missouri Total Natural Gas Plant Liquids and Liquefied Refinery Gases ....................................................... 358 2 360 69 38 259 366 Pentanes Plus

  10. Petroleum Supply Monthly

    U.S. Energy Information Administration (EIA) Indexed Site

    1 June 2016 Table 32. Blender Net Inputs of Petroleum Products by PAD District, June 2016 (Thousand Barrels) Commodity PAD District 1 - East Coast PAD District 2 - Midwest East Coast Appalachian No. 1 Total Indiana, Illinois, Kentucky Minnesota, Wisconsin, North and South Dakota Oklahoma, Kansas, Missouri Total Natural Gas Plant Liquids and Liquefied Refinery Gases ....................................................... 21 - 21 - 10 85 95 Pentanes Plus

  11. Chevron: Refinery Identifies $4.4 Million in Annual Savings by Using Process Simulation Models to Perform Energy-Efficiency Assessment

    SciTech Connect (OSTI)

    2004-05-01

    In an energy-efficiency study at its refinery near Salt Lake City, Utah, Chevron focused on light hydrocarbons processing. The company found it could recover hydrocarbons from its fuel gas system and sell them. By using process simulation models of special distillation columns and associated reboilers and condensers, Chevron could predict the performance of potential equipment configuration changes and process modifications. More than 25,000 MMBtu in natural gas could be saved annually if a debutanizer upgrade project and a new saturated gas plant project were completed. Together, these projects would save $4.4 million annually.

  12. Conceptual design assessment for the co-firing of bio-refinery supplied lignin project. Quarterly report, June 23--July 1, 2000

    SciTech Connect (OSTI)

    Berglund, T.; Ranney, J.T.; Babb, C.L.

    2000-07-27

    The Conceptual Design Assessment for the Co-Firing of Bio-Refinery Supplied Lignin Project was successfully kicked off on July 23, 2000 during a meeting at the TVA-PPI facility in Muscle Shoals, AL. An initial timeline for the study was distributed, issues of concern were identified and a priority actions list was developed. Next steps include meeting with NETL to discuss de-watering and lignin fuel testing, the development of the mass balance model and ethanol facility design criteria, providing TVA-Colbert with preliminary lignin fuel analysis and the procurement of representative feed materials for the pilot and bench scale testing of the hydrolysis process.

  13. Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gases Plus Nitrogen Oxide Emission Standards, Model Years 2017-2025 Fact 825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus Nitrogen Oxide Emission Standards, Model Years ...

  14. Changing the Way We Fly: Biofuels Made from Waste Gases Reaching...

    Energy Savers [EERE]

    Changing the Way We Fly: Biofuels Made from Waste Gases Reaching New Heights with Airline Industry Changing the Way We Fly: Biofuels Made from Waste Gases Reaching New Heights with ...

  15. ARM Carbon Cycle Gases Flasks at SGP Site (Dataset) | Data Explorer

    Office of Scientific and Technical Information (OSTI)

    Carbon Cycle Gases Flasks at SGP Site Title: ARM Carbon Cycle Gases Flasks at SGP Site Data from flasks are sampled at the Atmospheric Radiation Measurement Program ARM, Southern ...

  16. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  17. System for trapping and storing gases for subsequent chemical reduction to solids

    DOE Patents [OSTI]

    Vogel, John S.; Ognibene, Ted J.; Bench, Graham S.; Peaslee, Graham F.

    2009-11-03

    A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

  18. Clostridium stain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, James L.

    1997-01-01

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  19. Flash pyrolysis of biomass with reactive and nonreactive gases

    SciTech Connect (OSTI)

    Sundaram, M.S.; Steinberg, M.; Fallon, P.

    1982-10-01

    Studies were done on the flash pyrolysis of Douglas fir wood in the presence of reactive and nonreactive gases including hydrogen, methane, and helium. Pyrolysis and gasification of the wood particles was done in one step, without catalysts. Almost complete (98%) gasification of the carbon in Douglas fir wood was achieved at 1000/sup 0/C and 500-psi hydrogen pressure. The reaction products were methane, ethane, ethylene, carbon monoxide, BTX, and water. Flash hydropyrolysis produced a large yield of hydrocarbon gases (up to 78% C) comprising methane and ethane. High yields of ethylene (up to 21% C) and BTX (up to 12% C) were obtained via methane pyrolysis of fir wood; a free-radical mechanism is proposed to explain the enhanced yield of ethylene in a methane atmosphere.

  20. Clostridium strain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, J.L.

    1997-01-14

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  1. Decontamination of combustion gases in fluidized bed incinerators

    DOE Patents [OSTI]

    Leon, Albert M.

    1982-01-01

    Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

  2. Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2,813 3,440 3,591 7,549 6,265 8,763 9,872 18,776 13,652 9,971 1990's 9,981 - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date:

  3. Nanostructured carbon materials for adsorption of methane and other gases

    DOE Patents [OSTI]

    Stadie, Nicholas P.; Fultz, Brent T.; Ahn, Channing; Murialdo, Maxwell

    2015-06-30

    Provided are methods for storing gases on porous adsorbents, methods for optimizing the storage of gases on porous adsorbents, methods of making porous adsorbents, and methods of gas storage of optimized compositions, as in systems containing porous adsorbents and gas adsorbed on the surface of the porous adsorbent. The disclosed methods and systems feature a constant or increasing isosteric enthalpy of adsorption as a function of uptake of the gas onto the exposed surface of a porous adsorbent. Adsorbents with a porous geometry and surface dimensions suited to a particular adsorbate are exposed to the gas at elevated pressures in the specific regime where n/V (density) is larger than predicted by the ideal gas law by more than several percent.

  4. Apparatus for hot-gas desulfurization of fuel gases

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV)

    1992-01-01

    An apparatus for removing sulfur values from a hot fuel gas stream in a fdized bed contactor containing particulate sorbent material by employing a riser tube regeneration arrangement. Sulfur-laden sorbent is continuously removed from the fluidized bed through a stand pipe to the riser tube and is rapidly regenerated in the riser tube during transport of the sorbent therethrough by employing an oxygen-containing sorbent regenerating gas stream. The riser tube extends from a location below the fluidized bed to an elevation above the fluidized bed where a gas-solid separating mechanism is utilized to separate the regenerated particulate sorbent from the regeneration gases and reaction gases so that the regenerated sorbent can be returned to the fluidized bed for reuse.

  5. Liquid level detector

    DOE Patents [OSTI]

    Grasso, Albert P.

    1986-01-01

    A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  6. Liquid level detector

    DOE Patents [OSTI]

    Grasso, A.P.

    1984-02-21

    A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  7. APPARATUS FOR CLEANING GASES WITH ELECTROSTATICALLY CHARGED PARTICLES

    DOE Patents [OSTI]

    Johnstone, H.F.

    1960-02-01

    An apparatus is described for cleaning gases with the help of electrostatically charged pellets. The pellets are blown past baffles in a conduit and into the center of a rotuting body of the gas to be cleaned. The pellets are charged electrostatically by impinging on the baffles. The pellets collect the particles suspended in the gas in their passage from the center of the rotating body to its edge.

  8. Flask Samplers for Carbon Cycle Gases and Isotopes (FLASK) Handbook

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Flask Samplers for Carbon Cycle Gases and Isotopes (FLASK) Handbook S Biraud March 2016 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not

  9. Extraction of uranium from spent fuels using liquefied gases

    SciTech Connect (OSTI)

    Sawada, Kayo; Hirabayashi, Daisuke; Enokida, Youichi

    2007-07-01

    For reprocessing of spent nuclear fuels, a novel method to extract actinides from spent fuel using highly compressed gases, nitrogen dioxide and carbon dioxide was proposed. As a fundamental study, the nitrate conversion with liquefied nitrogen dioxide and the nitrate extraction with supercritical carbon dioxide were demonstrated by using uranium dioxide powder, uranyl nitrate and tri-n-butylphosphate complex in the present study. (authors)

  10. Simulations of Deflagration-to-Detonation Transition in Reactive Gases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Simulations of Deflagration-to-Detonation Transition in Reactive Gases PI Name: Alexei Khokhlov PI Email: ajk@oddjob.uchicago.edu Institution: University of Chicago Allocation Program: INCITE Allocation Hours at ALCF: 20,000,000 Year: 2012 Research Domain: Chemistry First-principles direct numerical simulations explain and predict high-speed combustion and deflagration-to-detonation transition (DDT) in hydrogen-oxygen gaseous mixtures. DDT and the

  11. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    1997-10-01

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  12. Emission of reduced malodorous sulfur gases from wastewater treatment plants

    SciTech Connect (OSTI)

    Devai, I.; DeLaune, R.D.

    1999-03-01

    The emission of malodorous gaseous compounds from wastewater collection and treatment facilities is a growing maintenance and environmental problem. Numerous gaseous compounds with low odor detection thresholds are emitted from these facilities. Sulfur-bearing gases represent compounds with the lowest odor detection threshold. Using solid adsorbent preconcentration and gas chromatographic methods, the quantity and composition of reduced malodorous sulfur gases emitted from various steps of the treatment process were determined in wastewater treatment plants in Baton Rouge, Louisiana. Hydrogen sulfide, which is a malodorous, corrosive, and potentially toxic gas, was the most dominant volatile reduced sulfur (S) compound measured. Concentrations were not only more than the odor detection threshold of hydrogen sulfide, but above levels that may affect health during long-term exposure. The concentrations of methanethiol, dimethyl sulfide, carbon disulfide, and carbonyl sulfide were significantly less than hydrogen sulfide. However, even though emissions of reduced sulfur gases other than hydrogen sulfide were low, previous studies suggested that long-term exposure to such levels may cause respiratory problems and other symptoms.

  13. Greenhouse gases mitigation options and strategies for Tanzania

    SciTech Connect (OSTI)

    Mwandosya, M.J.; Meena, H.E.

    1996-12-31

    Tanzania became a party to the United Nations Framework on Climate Change (UN FCCC) when she ratified the Convention in March, 1996. Now that Tanzania and other developing countries are Parties to the UN FCCC, compliance with its provisions is mandatory. The legal requirements therefore provide a basis for their participation in climate change studies and policy formulation. All parties to the Convention are required by Article 4.1 of the United Nations Convention on Climate Change (UN FCCC) to develop, periodically update, publish, and make available national inventories of anthropogenic emissions and removal of greenhouse gases that are not controlled by the Montreal Protocol. This study on possible options for the mitigation of greenhouse gases in Tanzania is a preliminary effort towards the fulfilment of the obligation. In order to fulfil their obligations under the UN FCCC and have a meaningful mitigation assessment, identification and quantification of anthropogenic sources of atmospheric emissions of greenhouse gases in the country was undertaken. In this respect, the study of anthropogenic emissions by source and removals by sink of GHGs in Tanzania was done with the main objective of increasing the quantity and quality of base-line data available in order to further scientific understanding of the relationship of greenhouse gas emissions to climate change. Furthermore, the study facilitated identification of national policy and technological options that could reduce the level of emissions in the country.

  14. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  15. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, M.E.; Sullivan, W.H.

    A precision liquid level sensor utilizes a balanced bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

  16. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    SciTech Connect (OSTI)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen ranged from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.

  17. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen rangedmore » from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.« less

  18. Renewable liquid reflection grating

    DOE Patents [OSTI]

    Ryutov, Dmitri D.; Toor, Arthur

    2003-10-07

    A renewable liquid reflection grating. Electrodes are operatively connected to a conducting liquid in an arrangement that produces a reflection grating and driven by a current with a resonance frequency. In another embodiment, the electrodes create the grating by a resonant electrostatic force acting on a dielectric liquid.

  19. Liquid detection circuit

    DOE Patents [OSTI]

    Regan, Thomas O.

    1987-01-01

    Herein is a circuit which is capable of detecting the presence of liquids, especially cryogenic liquids, and whose sensor will not overheat in a vacuum. The circuit parameters, however, can be adjusted to work with any liquid over a wide range of temperatures.

  20. Plasma-chemical waste treatment of acid gases

    SciTech Connect (OSTI)

    Harkness, J.B.L.; Doctor, R.D.; Daniels, E.J.

    1993-09-01

    The research to date has shown that a H{sub 2}S waste-treatment process based on plasma-chemical dissociation technology is compatible with refinery and high-carbon-oxide acid-gas streams. The minor amounts of impurities produced in the plasma-chemical reactor should be treatable by an internal catalytic reduction step. Furthermore, the plasma-chemical technology appears to be more efficient and more economical than the current technology. The principal key to achieving high conversions with relatively low energies of dissociation is the concept of the high-velocity, cyclonic-flow pattern in the plasma reaction zone coupled with the recycling of unconverted hydrogen sulfide. Future work will include testing the effects of components that might be carried over to the plasma reactor by ``upset`` conditions in the amine purification system of a plant and testing the plasma-chemical process on other industrial wastes streams that contain potentially valuable chemical reagents. The strategy for the commercialization of this technology is to form a Cooperative Research and Development Agreement with the Institute of Hydrogen Energy and Plasma Technology of the Russian Scientific Center/Kurchatov Institute and with an American start-up company to develop an ``American`` version of the process and to build a commercial-scale demonstration unit in the United States. The timetable proposed would involve building a ``field test`` facility which would test the plasma-chemical reactor and sulfur recovery unit operations on an industrial hydrogen sulfide waste s at a scale large enough to obtain the energy and material balance data required for a final analysis of the commercial potential of this technology. The field test would then be followed by construction of a commercial demonstration unit in two to three years. The commercial demonstration unit would be a fully integrated plant consisting of one commercial-scale module.

  1. Alaska coal gasification feasibility studies - Healy coal-to-liquids plant

    SciTech Connect (OSTI)

    Lawrence Van Bibber; Charles Thomas; Robert Chaney

    2007-07-15

    The Alaska Coal Gasification Feasibility Study entailed a two-phase analysis of the prospects for greater use of Alaska's abundant coal resources in industrial applications. Phase 1, Beluga Coal Gasification Feasibility Study (Report DOE/NETL 2006/1248) assessed the feasibility of using gasification technology to convert the Agrium fertilizer plant in Nikiski, Alaska, from natural gas to coal feedstock. The Phase 1 analysis evaluated coals from the Beluga field near Anchorage and from the Usibelli Coal Mine near Healy, both of which are low in sulfur and high in moisture. This study expands the results of Phase 1 by evaluating a similar sized gasification facility at the Usibelli Coal mine to supply Fischer-Tropsch (F-T) liquids to central Alaska. The plant considered in this study is small (14,640 barrels per day, bbl/d) compared to the recommended commercial size of 50,000 bbl/d for coal-to-liquid plants. The coal supply requirements for the Phase 1 analysis, four million tons per year, were assumed for the Phase 2 analysis to match the probable capacity of the Usibelli mining operations. Alaska refineries are of sufficient size to use all of the product, eliminating the need for F-T exports out of the state. The plant could produce marketable by-products such as sulfur as well as electric power. Slag would be used as backfill at the mine site and CO{sub 2} could be vented, captured or used for enhanced coalbed methane recovery. The unexpected curtailment of oil production from Prudhoe Bay in August 2006 highlighted the dependency of Alaskan refineries (with the exception of the Tesoro facility in Nikiski) on Alaska North Slope (ANS) crude. If the flow of oil from the North Slope declines, these refineries may not be able to meet the in-state needs for diesel, gasoline, and jet fuel. Additional reliable sources of essential fuel products would be beneficial. 36 refs., 14 figs., 29 tabs., 3 apps.

  2. U.S. Refinery

    U.S. Energy Information Administration (EIA) Indexed Site

    Leases Alaskan in Transit Bulk Terminal Pipeline Natural Gas Processing Plant Download ... Nov-15 Dec-15 Jan-16 Feb-16 Mar-16 Apr-16 View History Crude Oil and Petroleum Products ...

  3. Refinery Outages: Fall 2014

    Gasoline and Diesel Fuel Update (EIA)

    gasoline supply in a particular region because pipeline infrastructure, geography and marine shipping regulations constrain the amount of product that can flow among the different...

  4. The ultimate biomass refinery

    SciTech Connect (OSTI)

    Bungay, H.R. )

    1988-01-01

    Bits and pieces of refining schemes and both old and new technology have been integrated into a complete biomass harvesting, processing, waste recycle, and marketing complex. These choices are justified with economic estimates and technology assessments.

  5. Hydrogen Generation for Refineries

    Broader source: Energy.gov (indexed) [DOE]

    ADVANCED MANUFACTURING OFFICE PEER REVIEW MEETING May 5-6, 2014 DE-FG02-08ER85135 Hydrogen ... or otherwise restricted information 2 Hydrogen from Heavy, Renewable and Waste Oils - ...

  6. Refinery Capacity Report

    Gasoline and Diesel Fuel Update (EIA)

    ... Nevada...... 5 5 0 631,700 631,700 0 657,500 657,500 0 ... Nevada 294,700 82,800 148,400 3,000 65,000 137,900 460,900 24,300 ......

  7. U.S. Refinery

    U.S. Energy Information Administration (EIA) Indexed Site

    Oxygenates (excluding Fuel Ethanol) 24 58 112 65 76 104 2009-2015 MTBE 24 58 112 65 76 104 1993-2015 Other Oxygenates 1993-2005 Renewables (including Fuel Ethanol) 454 562 750 773 ...

  8. Refinery Outages: Fall 2014

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    some Libyan crude oil production to the market, and increasing U.S. crude production. Economic growth in 2014 outside of the United States has been slow, and some recent data...

  9. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Idle Operating Total Stream Day Barrels per Idle Operating Total Calendar Day Barrels ... Catalytic Cracking Downstream Charge Capacity (Barrels per Stream Day) Cracking Thermal ...

  10. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    Capacity Report June 2016 With Data as of January 1, 2016 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States Government. The views in this report therefore should not be

  11. Refinery Capacity Report

    U.S. Energy Information Administration (EIA) Indexed Site

    CORPORATION / Refiner / Location Table 5. Refiners' Total Operable Atmospheric Crude Oil Distillation Capacity as of January 1, 2016 Calendar Day Barrels per CORPORATION / Refiner / Location Calendar Day Barrels per Companies with Capacity Over 100,000 bbl/cd .............................................................................................................................. VALERO ENERGY CORP 2,062,300 Valero Refining Co Texas LP

  12. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, James E.; Bolton, Richard D.

    1999-01-01

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans.

  13. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, J.E.; Bolton, R.D.

    1999-03-02

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans. 4 figs.

  14. Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity

    DOE Patents [OSTI]

    Bingham, Dennis N.; Wilding, Bruce M.; McKellar, Michael G.

    2000-01-01

    A process for the separation and liquefaction of component gasses from a pressurized mix gas stream is disclosed. The process involves cooling the pressurized mixed gas stream in a heat exchanger so as to condense one or more of the gas components having the highest condensation point; separating the condensed components from the remaining mixed gas stream in a gas-liquid separator; cooling the separated condensed component stream by passing it through an expander; and passing the cooled component stream back through the heat exchanger such that the cooled component stream functions as the refrigerant for the heat exchanger. The cycle is then repeated for the remaining mixed gas stream so as to draw off the next component gas and further cool the remaining mixed gas stream. The process continues until all of the component gases are separated from the desired gas stream. The final gas stream is then passed through a final heat exchanger and expander. The expander decreases the pressure on the gas stream, thereby cooling the stream and causing a portion of the gas stream to liquify within a tank. The portion of the gas which is not liquefied is passed back through each of the heat exchanges where it functions as a refrigerant.

  15. Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity

    DOE Patents [OSTI]

    Bingham, Dennis N.; Wilding, Bruce M.; McKellar, Michael G.

    2002-01-01

    A process for the separation and liquefaction of component gasses from a pressurized mix gas stream is disclosed. The process involves cooling the pressurized mixed gas stream in a heat exchanger so as to condensing one or more of the gas components having the highest condensation point; separating the condensed components from the remaining mixed gas stream in a gas-liquid separator; cooling the separated condensed component stream by passing it through an expander; and passing the cooled component stream back through the heat exchanger such that the cooled component stream functions as the refrigerant for the heat exchanger. The cycle is then repeated for the remaining mixed gas stream so as to draw off the next component gas and further cool the remaining mixed gas stream. The process continues until all of the component gases are separated from the desired gas stream. The final gas stream is then passed through a final heat exchanger and expander. The expander decreases the pressure on the gas stream, thereby cooling the stream and causing a portion of the gas stream to liquify within a tank. The portion of the gas which is hot liquefied is passed back through each of the heat exchanges where it functions as a refrigerant.

  16. Liquefaction and storage of thermal treatment off-gases

    SciTech Connect (OSTI)

    Stull, D.M. . Rocky Flats Plant); Golden, J.O. )

    1992-09-08

    A fluidized bed catalytic oxidation unit is being developed for use in the destruction of mixed waste at the Rocky Flats Plant. Cyclones, filters, in situ neutralization of acid gases, and a catalytic converter are used to meet emission standards. Because there is concern by the public that these measures may not be adequate, two off-gas capture systems were evaluated. Both systems involve liquefaction of carbon dioxide produced in the oxidation process. The carbon dioxide would be released only after analysis proved that all appropriate emission standards are met.

  17. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  18. PPPL wins Department of Energy award for reducing greenhouse gases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab wins Department of Energy award for reducing greenhouse gases By Jeanne Jackson DeVoe October 2, 2012 Tweet Widget Google Plus One Share on Facebook PPPL engineer Tim Stevenson checks for possible leaks of sulfur hexafluoride (SF6), the gas used to insulate electronic equipment that has the potential to cause global warming at many times the rate of carbon dioxide. PPPL reduced leaks of SF6 by 65 percent over three years - reducing overall greenhouse gas

  19. MAGNETIC METHOD FOR PRODUCING HIGH VELOCITY SHOCK WAVES IN GASES

    DOE Patents [OSTI]

    Josephson, V.

    1960-01-26

    A device is described for producing high-energy plasmas comprising a tapered shock tube of dielectric material and having a closed small end, an exceedingly low-inductance coll supported about and axially aligned with the small end of the tapered tube. an elongated multiturn coil supported upon the remninder of the exterior wall of the shock tube. a potential source and switch connected in series with the low-inductance coil, a potential source and switch connected in series with the elongated coil, means for hermetically sealing the large end of the tube, means for purging the tube of gases, and means for admitting a selected gas into the shock tube.

  20. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, Raymond J.; Kurek, Paul R.

    1988-01-01

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  1. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, R.J.; Kurek, P.R.

    1988-07-19

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  2. Nonperturbative Predictions for Cold Atom Bose Gases with Tunable Interactions

    SciTech Connect (OSTI)

    Cooper, Fred; Chien, Chih-Chun; Mihaila, Bogdan; Timmermans, Eddy; Dawson, John F.

    2010-12-10

    We derive a theoretical description for dilute Bose gases as a loop expansion in terms of composite-field propagators by rewriting the Lagrangian in terms of auxiliary fields related to the normal and anomalous densities. We demonstrate that already in leading order this nonperturbative approach describes a large interval of coupling-constant values, satisfies Goldstone's theorem, yields a Bose-Einstein transition that is second order, and is consistent with the critical temperature predicted in the weak-coupling limit by the next-to-leading-order large-N expansion.

  3. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    1996-10-01

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  4. Influence of impurity gases and operating conditions on PAFC performance

    SciTech Connect (OSTI)

    Hirai, K.; Iwasa, N.; Suzuki, M.; Okada, O.

    1996-12-31

    On-site Phosphoric Acid Fuel Cell (PAFC) Cogeneration system is installed at various test sites, such as at underground parking lot, within chemical plant premises and near urban streets. Since in the current PAFC system, cathode air is supplied to the cell with no particular pretreatment, impurity gases in the air might influence on cell performance. We have investigated the influence of various impurity gases in the cathode gas, on sub-scale single cells, and have found that NO{sub 2}, SO{sub 2} and toluene affect negatively on cell performance. The results of these experiments and the conceivable mechanism of these effects on cell degradation are reported. We have also investigated the influence of other operating parameters, such as temperature, current density, fuel utilization on cell performance. From these experiments, we have found that operating temperature is a significant factor, which mainly determines cell voltage decline rate. The results of sub-scale single cell tests and a short-stack verification test are also reported.

  5. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P.; Lynn, Scott

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  6. Liquid level detector

    DOE Patents [OSTI]

    Tshishiku, Eugene M.

    2011-08-09

    A liquid level detector for conductive liquids for vertical installation in a tank, the detector having a probe positioned within a sheath and insulated therefrom by a seal so that the tip of the probe extends proximate to but not below the lower end of the sheath, the lower end terminating in a rim that is provided with notches, said lower end being tapered, the taper and notches preventing debris collection and bubble formation, said lower end when contacting liquid as it rises will form an airtight cavity defined by the liquid, the interior sheath wall, and the seal, the compression of air in the cavity preventing liquid from further entry into the sheath and contact with the seal. As a result, the liquid cannot deposit a film to form an electrical bridge across the seal.

  7. Table E2.1. Nonfuel (Feedstock) Use of Combustible Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... by petroleum" "refineries (e.g., crude oil ... ,"Total United States" "RSE Column ... Examples of Liquefied Petroleum Gases '(LPG)' are ...

  8. LIQUID CYCLONE CONTACTOR

    DOE Patents [OSTI]

    Whatley, M.E.; Woods, W.M.

    1962-09-01

    This invention relates to liquid-liquid extraction systems. The invention, an improved hydroclone system, comprises a series of serially connected, axially aligned hydroclones, each of which is provided with an axially aligned overflow chamber. The chambers are so arranged that rotational motion of a fluid being passed through the system is not lost in passing from chamber to chamber; consequently, this system is highly efficient in contacting and separating two immiscible liquids. (AEC)

  9. Gas scrubbing liquids

    DOE Patents [OSTI]

    Lackey, Walter J.; Lowrie, Robert S.; Sease, John D.

    1981-01-01

    Fully chlorinated and/or fluorinated hydrocarbons are used as gas scrubbing liquids for preventing noxious gas emissions to the atmosphere.

  10. HV in Noble Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Noble Liquids 8 Nov 2013 High Voltage Tests for MicroBooNE Byron Lundberg Fermilab presenting for the Collaboration & Task Force 4 1 Friday, November 8, 13 HV in Noble Liquids MicroBooNE Experiment  A liquid argon time projection chamber (LAr TPC) containing 170 tons of liquid argon, and located on the Booster Neutrino Beamline.  MiniBooNE  MicroBooNE 8,#256#wires;#U,V,Y#planes;#3#mm#spacing# 32#PMTs#for#fast#light#collec?ons# @ L A r T F 2 Friday, November 8, 13 HV in Noble

  11. Liquid Crystal Optofluidics

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

    2012-10-11

    By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

  12. Ultrasonic liquid level detector

    DOE Patents [OSTI]

    Kotz, Dennis M.; Hinz, William R.

    2010-09-28

    An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

  13. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J.; Berman, Samuel M.

    1988-01-01

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  14. Natural Gas Plant Field Production: Natural Gas Liquids

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Natural Gas Liquids Pentanes Plus Liquefied Petroleum Gases Ethane Propane Normal Butane Isobutane Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area Jan-16 Feb-16 Mar-16 Apr-16 May-16 Jun-16 View History U.S. 102,401 96,538 108,784 105,106 111,388 108,530 1981-2016 PADD 1

  15. About the statistical description of gas-liquid flows

    SciTech Connect (OSTI)

    Sanz, D.; Guido-Lavalle, G.; Carrica, P.

    1995-09-01

    Elements of the probabilistic geometry are used to derive the bubble coalescence term of the statistical description of gas liquid flows. It is shown that the Boltzmann`s hypothesis, that leads to the kinetic theory of dilute gases, is not appropriate for this kind of flows. The resulting integro-differential transport equation is numerically integrated to study the flow development in slender bubble columns. The solution remarkably predicts the transition from bubbly to slug flow pattern. Moreover, a bubbly bimodal size distribution is predicted, which has already been observed experimentally.

  16. Coal and Coal-Biomass to Liquids FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal and Coal-Biomass to Liquids FAQs faq-header-big.jpg BASICS Q: How are gasoline and diesel fuel made from coal? A: Gasoline and diesel fuels can be produced from coal in two distinct processes: Indirect Liquefaction and Direct Liquefaction. In Indirect Liquefaction, coal is first gasified to produce synthesis gas (syngas for short), which is a mixture containing primarily hydrogen (H2) and carbon monoxide (CO) gases. The Fischer-Tropsch (FT) synthesis is a commercial process that can be used

  17. Process for the cooling and separating of small particle-containing gases

    SciTech Connect (OSTI)

    Mink, B.H.

    1984-11-13

    Process for the cooling and separating of small particle-containing gases comprising fine, very fine and coarser particles and having a temperature in the range of from 800/sup 0/-1400/sup 0/ C. and a pressure in the range of from 3-60 bar in which the gases are first cooled in a heat exchanger for producing superheated steam, and then the coarser particles are separated from the gases in a cyclone whereafter the gases are further cooled by passing them into a helically coiled tube(s) which is (are) cooled with a cooling medium.

  18. Liquid-phase compositions from vapor-phase analyses

    SciTech Connect (OSTI)

    Davis, W. Jr. ); Cochran, H.D. )

    1990-02-01

    Arsenic normally is not considered to be a contaminant. However, because arsenic was found in many cylinders of UF{sub 6}, including in corrosion products, a study was performed of the distribution of the two arsenic fluorides, AsF{sub 3} and AsF{sub 5}, between liquid and vapor phases. The results of the study pertain to condensation or vaporization of liquid UF{sub 6}. This study includes use of various experimental data plus many extrapolations necessitated by the meagerness of the experimental data. The results of this study provide additional support for the vapor-liquid equilibrium model of J.M. Prausnitz and his coworkers as a means of describing the distribution of various impurities between vapor and liquid phases of UF{sub 6}. Thus, it is concluded that AsF{sub 3} will tend to concentrate in the liquid phase but that the concentration of AsF{sub 5} in the vapor phase will exceed its liquid-phase concentration by a factor of about 7.5, which is in agreement with experimental data. Because the weight of the liquid phase in a condensation operation may be in the range of thousands of times that of the vapor phase, most of any AsF{sub 5} will be in the liquid phase in spite of this separation factor of 7.5. It may also be concluded that any arsenic fluorides fed into a uranium isotope separation plant will either travel with other low-molecular-weight gases or react with materials present in the plant. 25 refs., 3 figs., 6 tabs.

  19. Noble gases and cosmogenic radionuclides in the Eltanin Pacific meteorite

    SciTech Connect (OSTI)

    Bogard, D D; Garrison, D H; Caffee, M W; Kyte, F; Nishiizumi, K

    2000-01-14

    A 1.5 cm long, 1.2 g specimen of the Eltanin meteorite was found at 10.97 m depth in Polarstern piston core PS2704-1. The early studies indicated that the small fragments of the Eltanin meteorite was debris from a km-sized asteroid which impacted into the deep-ocean basin. In this study, the authors measured {sup 39}Ar-{sup 40}Ar age, noble gases, and cosmogenic radionuclides in splits of specimen as a part of consortium studies of Eltanin meteorite. They concluded that the specimen was about 3 m deep from the asteroid surface. The exposure age of the Eltanin asteroid was about 20 Myr.

  20. Loschmidt echo in one-dimensional interacting Bose gases

    SciTech Connect (OSTI)

    Lelas, K.; Seva, T.; Buljan, H.

    2011-12-15

    We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.

  1. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, A.W.

    1983-10-12

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  2. Nuclear magnetic resonance imaging with hyper-polarized noble gases

    SciTech Connect (OSTI)

    Schmidt, D.M.; George, J.S.; Penttila, S.I.; Caprihan, A.

    1997-10-01

    This is the final report of a six-month, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The nuclei of noble gases can be hyper polarized through a laser-driven spin exchange to a degree many orders of magnitude larger than that attainable by thermal polarization without requiring a strong magnetic field. The increased polarization from the laser pumping enables a good nuclear magnetic resonance (NMR) signal from a gas. The main goal of this project was to demonstrate diffusion-weighted imaging of such hyper-polarized noble gas with magnetic resonance imaging (MRI). Possible applications include characterizing porosity of materials and dynamically imaging pressure distributions in biological or acoustical systems.

  3. Wave speeds in the macroscopic extended model for ultrarelativistic gases

    SciTech Connect (OSTI)

    Borghero, F.; Demontis, F.; Pennisi, S.

    2013-11-15

    Equations determining wave speeds for a model of ultrarelativistic gases are investigated. This model is already present in literature; it deals with an arbitrary number of moments and it was proposed in the context of exact macroscopic approaches in Extended Thermodynamics. We find these results: the whole system for the determination of the wave speeds can be divided into independent subsystems which are expressed by linear combinations, through scalar coefficients, of tensors all of the same order; some wave speeds, but not all of them, are expressed by square roots of rational numbers; finally, we prove that these wave speeds for the macroscopic model are the same of those furnished by the kinetic model.

  4. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, Arthur W. (Schenectady, NY)

    1985-01-01

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  5. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, M.E.; Sullivan, W.H.

    1985-01-29

    A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge. 2 figs.

  6. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, Michael E.; Sullivan, William H.

    1985-01-01

    A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

  7. Synthesis of ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng [Knoxville, TN; Luo, Huimin [Knoxville, TN

    2008-09-09

    Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic liqand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

  8. Synthesis of ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Luo, Huimin (Knoxville, TN)

    2011-11-01

    Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic ligand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

  9. Liquid heat capacity lasers

    DOE Patents [OSTI]

    Comaskey, Brian J.; Scheibner, Karl F.; Ault, Earl R.

    2007-05-01

    The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

  10. Catalytic process for removing toxic gases from gas streams

    SciTech Connect (OSTI)

    Baglio, J.A.; Gaudet, G.G.; Palilla, F.C.

    1983-02-22

    A multi-stage process for reducing the content of sulfurcontaining gases-notably hydrogen sulfide, sulfur dioxide, carbonyl sulfide and carbon disulfide-in waste gas streams is provided. In the first stage, the gas stream is passed through a reaction zone at a temperature between about 150 and 350/sup 0/C in the presence of a pretreated novel catalyst of the formula xLn/sub 2/O/sub 3/ in which Ln is yttrium or a rare earth element and T is cobalt, iron or nickel, and each of x and y is independently a number from 0 to 3, said catalyst being substantially non-crystalline and having a surface area of from about 10 m/sup 2//g to about 40 m/sup 2//g. The preferred catalyst is one in which Ln is lanthanum, T is cobalt, and x and y range from 1 to 3, including non-integers. The first stage yields a product stream having a reduced content of sulfur-containing gases, including specifically, substantial reduction of carbonyl sulfide and virtual elimination of carbon disulfide. An intermediate stage is a claus reaction, which may take place in one or more reaction zones, at temperatures less than about 130/sup 0/ C, in the presence of known catalysts such as bauxite, alumina or cobalt molybdates. The final stage is the air oxidation of hydrogen sulfide at a temperature between about 150 and 300/sup 0/ C in the presence of a catalyst usable in first stage.

  11. Electrical detection of liquid lithium leaks from pipe joints

    SciTech Connect (OSTI)

    Schwartz, J. A. Jaworski, M. A.; Mehl, J.; Kaita, R.; Mozulay, R.

    2014-11-15

    A test stand for flowing liquid lithium is under construction at Princeton Plasma Physics Laboratory. As liquid lithium reacts with atmospheric gases and water, an electrical interlock system for detecting leaks and safely shutting down the apparatus has been constructed. A defense in depth strategy is taken to minimize the risk and impact of potential leaks. Each demountable joint is diagnosed with a cylindrical copper shell electrically isolated from the loop. By monitoring the electrical resistance between the pipe and the copper shell, a leak of (conductive) liquid lithium can be detected. Any resistance of less than 2 kΩ trips a relay, shutting off power to the heaters and pump. The system has been successfully tested with liquid gallium as a surrogate liquid metal. The circuit features an extensible number of channels to allow for future expansion of the loop. To ease diagnosis of faults, the status of each channel is shown with an analog front panel LED, and monitored and logged digitally by LabVIEW.

  12. Renewable liquid reflecting zone plate

    DOE Patents [OSTI]

    Toor, Arthur; Ryutov, Dmitri D.

    2003-12-09

    A renewable liquid reflecting zone plate. Electrodes are operatively connected to a dielectric liquid in a circular or other arrangement to produce a reflecting zone plate. A system for renewing the liquid uses a penetrable substrate.

  13. Liquid sampling system

    DOE Patents [OSTI]

    Larson, L.L.

    1984-09-17

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

  14. Liquid sampling system

    DOE Patents [OSTI]

    Larson, Loren L.

    1987-01-01

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

  15. The modelling of wall condensation with noncondensable gases for the containment codes

    SciTech Connect (OSTI)

    Leduc, C.; Coste, P.; Barthel, V.; Deslandes, H.

    1995-09-01

    This paper presents several approaches in the modelling of wall condensation in the presence of noncondensable gases for containment codes. The lumped-parameter modelling and the local modelling by 3-D codes are discussed. Containment analysis codes should be able to predict the spatial distributions of steam, air, and hydrogen as well as the efficiency of cooling by wall condensation in both natural convection and forced convection situations. 3-D calculations with a turbulent diffusion modelling are necessary since the diffusion controls the local condensation whereas the wall condensation may redistribute the air and hydrogen mass in the containment. A fine mesh modelling of film condensation in forced convection has been in the developed taking into account the influence of the suction velocity at the liquid-gas interface. It is associated with the 3-D model of the TRIO code for the gas mixture where a k-{xi} turbulence model is used. The predictions are compared to the Huhtiniemi`s experimental data. The modelling of condensation in natural convection or mixed convection is more complex. As no universal velocity and temperature profile exist for such boundary layers, a very fine nodalization is necessary. More simple models integrate equations over the boundary layer thickness, using the heat and mass transfer analogy. The model predictions are compared with a MIT experiment. For the containment compartments a two node model is proposed using the lumped parameter approach. Heat and mass transfer coefficients are tested on separate effect tests and containment experiments. The CATHARE code has been adapted to perform such calculations and shows a reasonable agreement with data.

  16. Universally oriented renewable liquid mirror

    DOE Patents [OSTI]

    Ryutov, Dmitri D.; Toor, Arthur

    2004-07-20

    A universally oriented liquid mirror. A liquid and a penetrable unit are operatively connected to provide a mirror that can be universally oriented.

  17. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  18. Liquid-level detector

    DOE Patents [OSTI]

    Not Available

    1981-01-29

    Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

  19. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1992-01-01

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  20. Reversible Acid Gas Capture Using CO2-Binding Organic Liquids

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Yonker, Clement R.; Rainbolt, James E.; Zheng, Feng

    2010-08-31

    Acid gas scrubbing technology is predominantly aqueous alkanolamine based. Of the acid gases, CO2, H2S and SO2 have been shown to be reversible, however there are serious disadvantages with corrosion and high regeneration costs. The primary scrubbing system composed of monoethanolamine is limited to 30% by weight because of the highly corrosive solution. This gravimetric limitation limits the CO2 volumetric (?108 g/L) and gravimetric capacity (?7 wt%) of the system. Furthermore the scrubbing system has a large energy penalty from pumping and heating the excess water required to dissolve the MEA bicarbonate salt. Considering the high specific heat of water (4 j/g-1K-1), low capacities and the high corrosion we set out to design a fully organic solvent that can chemically bind all acid gases i.e. CO2 as reversible alkylcarbonate ionic liquids or analogues thereof. Having a liquid acid gas carrier improves process economics because there is no need for excess solvent to pump and to heat. We have demonstrated illustrated in Figure 1, that CO2-binding organic liquids (CO2BOLs) have a high CO2 solubility paired with a much lower specific heat (<1.5 J/g-1K-1) than aqueous systems. CO2BOLs are a subsection of a larger class of materials known as Binding Organic Liquids (BOLs). Our BOLs have been shown to reversibly bind and release COS, CS2, and SO2, which we denote COSBOLS, CS2BOLs and SO2BOLs. Our BOLs are highly tunable and can be designed for post or pre-combustion gas capture. The design and testing of the next generation zwitterionic CO2BOLs and SO2BOLs are presented.

  1. NREL to Help Convert Methane to Liquid Diesel - News Releases...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is enormous - equal to one-third of the amount of petroleum used in the United States each year. ... along with the petroleum to refineries where it can be turned into ...

  2. Direct liquid injection of liquid petroleum gas

    SciTech Connect (OSTI)

    Lewis, D.J.; Phipps, J.R.

    1984-02-14

    A fuel injector and injection system for injecting liquified petroleum gas (LPG) into at least one air/fuel mixing chamber from a storage means that stores pressurized LPG in its liquid state. The fuel injector (including a body), adapted to receive pressurized LPG from the storage means and for selectively delivering the LPG to the air/fuel mixing chamber in its liquified state. The system including means for correcting the injector activation signal for pressure and density variations in the fuel.

  3. Liquid level controller

    DOE Patents [OSTI]

    Mangus, J.D.; Redding, A.H.

    1975-07-15

    A system for maintaining two distinct sodium levels within the shell of a heat exchanger having a plurality of J-shaped modular tube bundles each enclosed in a separate shell which extends from a common base portion. A lower liquid level is maintained in the base portion and an upper liquid level is maintained in the shell enwrapping the long stem of the J-shaped tube bundles by utilizing standpipes with a notch at the lower end which decreases in open area the distance from the end of the stand pipe increases and a supply of inert gas fed at a constant rate to produce liquid levels, which will remain generally constant as the flow of liquid through the vessel varies. (auth)

  4. Liquid blocking check valve

    DOE Patents [OSTI]

    Merrill, John T.

    1984-01-01

    A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

  5. On flame kernel formation and propagation in premixed gases

    SciTech Connect (OSTI)

    Eisazadeh-Far, Kian; Metghalchi, Hameed [Northeastern University, Mechanical and Industrial Engineering Department, Boston, MA 02115 (United States); Parsinejad, Farzan [Chevron Oronite Company LLC, Richmond, CA 94801 (United States); Keck, James C. [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

    2010-12-15

    Flame kernel formation and propagation in premixed gases have been studied experimentally and theoretically. The experiments have been carried out at constant pressure and temperature in a constant volume vessel located in a high speed shadowgraph system. The formation and propagation of the hot plasma kernel has been simulated for inert gas mixtures using a thermodynamic model. The effects of various parameters including the discharge energy, radiation losses, initial temperature and initial volume of the plasma have been studied in detail. The experiments have been extended to flame kernel formation and propagation of methane/air mixtures. The effect of energy terms including spark energy, chemical energy and energy losses on flame kernel formation and propagation have been investigated. The inputs for this model are the initial conditions of the mixture and experimental data for flame radii. It is concluded that these are the most important parameters effecting plasma kernel growth. The results of laminar burning speeds have been compared with previously published results and are in good agreement. (author)

  6. Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Colorado Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0

  7. Sorption of atmospheric gases by bulk lithium metal

    SciTech Connect (OSTI)

    Hart, C. A.; Skinner, C. H.; Capece, A. M.; Koel, B. E.

    2016-01-01

    Lithium conditioning of plasma facing components has enhanced the performance of several fusion devices. Elemental lithium will react with air during maintenance activities and with residual gases (H2O, CO, CO2) in the vacuum vessel during operations. We have used a mass balance (microgram sensitivity) to measure the mass gain of lithium samples during exposure of a similar to 1 cm(2) surface to ambient and dry synthetic air. For ambient air, we found an initial mass gain of several mg/h declining to less than 1 mg/h after an hour and decreasing by an order of magnitude after 24 h. A 9 mg sample achieved a final mass gain corresponding to complete conversion to Li2CO3 after 5 days. Exposure to dry air resulted in a 30 times lower initial rate of mass gain. The results have implications for the chemical state of lithium plasma facing surfaces and for safe handling of lithium coated components. (C) 2015 Elsevier B.V. All rights reserved.

  8. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  9. Sorption of atmospheric gases by bulk lithium metal

    SciTech Connect (OSTI)

    Hart, C. A.; Skinner, C. H.; Capece, A. M.; Koel, B. E.

    2016-01-01

    Lithium conditioning of plasma facing components has enhanced the performance of several fusion devices. Elemental lithium will react with air during maintenance activities and with residual gases (H2O, CO, CO2) in the vacuum vessel during operations. We have used a mass balance (microgram sensitivity) to measure the mass gain of lithium samples during exposure of a ~1 cm2 surface to ambient and dry synthetic air. For ambient air, we found an initial mass gain of several mg/h declining to less than 1 mg/h after an hour and decreasing by an order of magnitude after 24 h. A 9 mg sample achieved a final mass gain corresponding to complete conversion to Li2CO3 after 5 days. Exposure to dry air resulted in a 30 times lower initial rate of mass gain. The results have implications for the chemical state of lithium plasma facing surfaces and for safe handling of lithium coated components.

  10. Glass surface deactivants for sulfur-containing gases

    SciTech Connect (OSTI)

    Farwell, S.O.; Gluck, S.J.

    1980-10-01

    In gas chromatographic technique for measuring reduced sulfur-containing gases in biogenic air fluxes, the major problem seemed to be the irreversible adsorption of the polar sulfur compounds on the glass surfaces of the cryogenic sampling traps. This article discusses the comparative degrees of Pyrex glass surface passivation for over 25 chemical deactivants and their related pretreatment procedures. Since H/sub 2/S was discovered to be the sulfur compound with a consistently lower recovery efficiency than COS, CH/sub 3/SH, CH/sub 3/SCH, CS/sub 2/ or CH/sub 3/SSCH/sub 3/, the percent recovery for H/sub 2/S was employed as the indicator of effectiveness for the various deactivation treatments. Tables are presented summarizing the mean H/sub 2/S recoveries for chlorosilane deactivants and for the mean H/sub 2/S recoveries for different pyrex surface pretreatments with an octadecyltrialkoxysilane deactivation. The general conclusion of this investigation is that the relative degree of passivation for glass surfaces by present deactivation techniques is dependent on the types of analyzed compounds and the nature of the glass surface.

  11. Liquid precursor inks for deposition of In--Se, Ga--Se and In--Ga--Se

    SciTech Connect (OSTI)

    Curtis, Calvin J.; Hersh, Peter A.; Miedaner, Alexander; Habas, Susan; van Hest, Maikel; Ginley, David S.

    2015-08-11

    An ink includes a solution of selenium in ethylene diamine solvent and a solution of at least one metal salt selected from the group consisting of an indium salt or a gallium salt in at least one solvent including an organic amide. The organic amide can include dimethylformamide. The organic amide can include N-methylpyrrolidone.

  12. Liquid crystalline composites containing phyllosilicates

    DOE Patents [OSTI]

    Chaiko, David J.

    2004-07-13

    The present invention provides phyllosilicate-polymer compositions which are useful as liquid crystalline composites. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while at the same time be transparent. Because of the ordering of the particles liquid crystalline composite, liquid crystalline composites are particularly useful as barriers to gas transport.

  13. Mass transfer apparatus and method for separation of gases

    DOE Patents [OSTI]

    Blount, Gerald C.

    2015-10-13

    A process and apparatus for separating components of a source gas is provided in which more soluble components of the source gas are dissolved in an aqueous solvent at high pressure. The system can utilize hydrostatic pressure to increase solubility of the components of the source gas. The apparatus includes gas recycle throughout multiple mass transfer stages to improve mass transfer of the targeted components from the liquid to gas phase. Separated components can be recovered for use in a value added application or can be processed for long-term storage, for instance in an underwater reservoir.

  14. Carbon dioxide capture from power or process plant gases

    DOE Patents [OSTI]

    Bearden, Mark D; Humble, Paul H

    2014-06-10

    The present invention are methods for removing preselected substances from a mixed flue gas stream characterized by cooling said mixed flue gas by direct contact with a quench liquid to condense at least one preselected substance and form a cooled flue gas without substantial ice formation on a heat exchanger. After cooling additional process methods utilizing a cryogenic approach and physical concentration and separation or pressurization and sorbent capture may be utilized to selectively remove these materials from the mixed flue gas resulting in a clean flue gas.

  15. Process for hydrocracking carbonaceous material in liquid carrier

    DOE Patents [OSTI]

    Duncan, Dennis A.

    1980-01-01

    Solid carbonaceous material is hydrocracked to provide aliphatic and aromatic hydrocarbons for use as gaseous and liquid fuels or chemical feed stock. Particulate carbonaceous material such as coal in slurry with recycled product oil is preheated in liquid state to a temperature of 600.degree.-1200.degree. F. in the presence of hydrogen gas. The product oil acts as a sorbing agent for the agglomerating bitumins to minimize caking within the process. In the hydrocracking reactor, the slurry of oil and carbonaceous particles is heated within a tubular passageway to vaporize the oil and form a gas-solid mixture which is further heated to a hydropyrolysis temperature in excess of 1200.degree. F. The gas-solid mixture is quenched by contact with additional oil to condense normally liquid hydrocarbons for separation from the gases. A fraction of the hydrocarbon liquid product is recycled for quenching and slurrying with the carbonaceous feed. Hydrogen is recovered from the gas for recycle and additional hydrogen is produced by gasification of residual char.

  16. Plant for producing an oxygen-containing additive as an ecologically beneficial component for liquid motor fuels

    DOE Patents [OSTI]

    Siryk, Yury Paul; Balytski, Ivan Peter; Korolyov, Volodymyr George; Klishyn, Olexiy Nick; Lnianiy, Vitaly Nick; Lyakh, Yury Alex; Rogulin, Victor Valery

    2013-04-30

    A plant for producing an oxygen-containing additive for liquid motor fuels comprises an anaerobic fermentation vessel, a gasholder, a system for removal of sulphuretted hydrogen, and a hotwell. The plant further comprises an aerobic fermentation vessel, a device for liquid substance pumping, a device for liquid aeration with an oxygen-containing gas, a removal system of solid mass residue after fermentation, a gas distribution device; a device for heavy gases utilization; a device for ammonia adsorption by water; a liquid-gas mixer; a cavity mixer, a system that serves superficial active and dispersant matters and a cooler; all of these being connected to each other by pipelines. The technical result being the implementation of a process for producing an oxygen containing additive, which after being added to liquid motor fuels, provides an ecologically beneficial component for motor fuels by ensuring the stability of composition fuel properties during long-term storage.

  17. Production of greenhouse gases in the former Soviet Union

    SciTech Connect (OSTI)

    Kolchugina, T.P.; Vinson, T.S. . Civil Engineering Dept.)

    1994-09-01

    The former Soviet Union (FSU) was the largest country in the world and was one of the greatest emitters of greenhouse gases to the atmosphere. At the end of the 1980s and the beginning of the 1990s the CO[sub 2] emissions for the FSU amounted to 1.46 Pg C yr[sup [minus]1] (Pg = 10[sup 15] g). Total CH[sub 4] emissions for the FSU were 55.8 Tg C yr[sup [minus]1] (Tg = 10[sup 12] g) or approximately one-third of the global CH[sub 4] emissions; 53% of the FSU CH[sub 4] emissions was contributed by peatlands. Emissions of CFCs were 67 Gg yr[sup [minus]1] (Gg = 10[sup 9] g) and comprised 12% of the global CFCs emissions. The forest sector was a net sink for 0.48 Pg C yr[sup [minus]1] of atmospheric carbon, offsetting approximately one-half of the CO[sub 2] emissions from industrial processes. FSU peatlands accumulated 52 Tg C yr[sup [minus]1], but overall they were a net source of 48 Tg C yr[sup [minus]1] to the atmosphere considering utilization of peat. The net CO[sub 2] emissions of the FSU were 0.68 Pg C yr[sup [minus]1]. The FSU and China shared the fifth and sixth places in the world ranking of net CO[sub 2] emissions. The FSU and European countries shared the fourth and fifth places in the world ranking of net CO[sub 2] emissions per capita.

  18. Surface interactions involved in flashover with high density electronegative gases.

    SciTech Connect (OSTI)

    Hodge, Keith Conquest; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wallace, Zachariah Red; Lehr, Jane Marie

    2010-01-01

    This report examines the interactions involved with flashover along a surface in high density electronegative gases. The focus is on fast ionization processes rather than the later time ionic drift or thermalization of the discharge. A kinetic simulation of the gas and surface is used to examine electron multiplication and includes gas collision, excitation and ionization, and attachment processes, gas photoionization and surface photoemission processes, as well as surface attachment. These rates are then used in a 1.5D fluid ionization wave (streamer) model to study streamer propagation with and without the surface in air and in SF6. The 1.5D model therefore includes rates for all these processes. To get a better estimate for the behavior of the radius we have studied radial expansion of the streamer in air and in SF6. The focus of the modeling is on voltage and field level changes (with and without a surface) rather than secondary effects, such as, velocities or changes in discharge path. An experiment has been set up to carry out measurements of threshold voltages, streamer velocities, and other discharge characteristics. This setup includes both electrical and photographic diagnostics (streak and framing cameras). We have observed little change in critical field levels (where avalanche multiplication sets in) in the gas alone versus with the surface. Comparisons between model calculations and experimental measurements are in agreement with this. We have examined streamer sustaining fields (field which maintains ionization wave propagation) in the gas and on the surface. Agreement of the gas levels with available literature is good and agreement between experiment and calculation is good also. Model calculations do not indicate much difference between the gas alone versus the surface levels. Experiments have identified differences in velocity between streamers on the surface and in the gas alone (the surface values being larger).

  19. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2000-01-01

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  20. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.