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Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Charge transfer kinetics at the solid–solid interface in porous electrodes  

E-Print Network [OSTI]

Interfacial charge transfer is widely assumed to obey the Butler–Volmer kinetics. For certain liquid–solid interfaces, the Marcus–Hush–Chidsey theory is more accurate and predictive, but it has not been applied to porous ...

Bai, Peng

2

Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries. Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries....

3

Systems and methods for monitoring a solid-liquid interface  

DOE Patents [OSTI]

Systems and methods are provided for monitoring a solid-liquid interface during a casting process. The systems and methods enable determination of the location of a solid-liquid interface during the casting process.

Stoddard, Nathan G; Lewis, Monte A.; Clark, Roger F

2013-06-11T23:59:59.000Z

4

Interface for liquid chromatograph-mass spectrometer  

DOE Patents [OSTI]

A moving belt interface for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer.

Andresen, Brian D. (Pleasanton, CA); Fought, Eric R. (Livermore, CA)

1989-01-01T23:59:59.000Z

5

Interface for liquid chromatograph-mass spectrometer  

DOE Patents [OSTI]

A moving belt interface is described for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer. 8 figs.

Andresen, B.D.; Fought, E.R.

1989-09-19T23:59:59.000Z

6

A SHARP INTERFACE REDUCTION FOR MULTIPHASE TRANSPORT IN A POROUS FUEL CELL ELECTRODE  

E-Print Network [OSTI]

A SHARP INTERFACE REDUCTION FOR MULTIPHASE TRANSPORT IN A POROUS FUEL CELL ELECTRODE KEITH exchange membrane fuel cell is a highly porous material which acts to distribute reactant gases uniformly perturbation, fuel cell electrodes, free surface. AMS subject classifications. 35B40, 35K55, 76R99, 76S05 1

Stockie, John

7

The acoustical flows of the hydrophobic and anticeptic liquids in porous media  

E-Print Network [OSTI]

of the acoustical flows in the porous or microcrum- bling media. Concrete and brick walls being porous media absorbThe acoustical flows of the hydrophobic and anticeptic liquids in porous media V. Tsaplev North effect. Just the same, if the protective covering of the concrete or brick wall is damaged, they begin

Boyer, Edmond

8

INTERFACE CRACK PROPAGATION IN POROUS AND TIME-DEPENDENT MATERIALS ANALYZED WITH  

E-Print Network [OSTI]

INTERFACE CRACK PROPAGATION IN POROUS AND TIME-DEPENDENT MATERIALS ANALYZED WITH DISCRETE MODELS and the FPZ. From the point of view of design of structures, e.g. reinforced concrete structures, this size size, size effects, creep, ageing, fracture, viscoelastic- ity, time effect, concrete failure, discrete

Boyer, Edmond

9

MATHEMATICAL MODELING OF CHANNEL POROUS LAYER INTERFACES IN PEM FUEL CELLS  

E-Print Network [OSTI]

two types of PEM fuel cells: H2 PEM fuel cells (H2PEMFC) driven by gaseous hydrogen, and directMATHEMATICAL MODELING OF CHANNEL ­ POROUS LAYER INTERFACES IN PEM FUEL CELLS M. EHRHARDT, J, Germany ABSTRACT In proton exchange membrane (PEM) fuel cells, the transport of the fuel to the active

Ehrhardt, Matthias

10

Liquid/Liquid Interface Polymerized Porphyrin Membranes Displaying Size-Selective Molecular and Ionic Permeability  

E-Print Network [OSTI]

Liquid/Liquid Interface Polymerized Porphyrin Membranes Displaying Size-Selective Molecular: December 5, 2005 Thin polymeric membranes have been formed by liquid/liquid interfacial copolymerization of controllable thickness to be obtained.7 The polymerization of 1 was accomplished by condensation of porphyrin

11

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces  

E-Print Network [OSTI]

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces allowed to self-assemble at the perfluorodecalin/water interface. These plates were fabricated from, the designs of hydrophobic edges necessary to generate menisci useful in self-assembly were different for 100

Prentiss, Mara

12

Novel Fluctuations at a Constrained Liquid-Solid Interface  

E-Print Network [OSTI]

We study the interface between a solid trapped within a bath of liquid by a suitably shaped non-uniform external potential. Such a potential may be constructed using lasers, external electric or magnetic fields or a surface template. We study a two dimensional case where a thin strip of solid, created in this way, is surrounded on either side by a bath of liquid with which it can easily exchange particles. Since height fluctuations of the interface cost energy, this interface is constrained to remain flat at all length scales. However, when such a solid is stressed by altering the depth of the potential; beyond a certain limit, it responds by relieving stress by novel interfacial fluctuations which involve addition or deletion of entire lattice layers of the crystal. This ``layering'' transition is a generic feature of the system regardless of the details of the interaction potential. We show how such interfacial fluctuations influence mass, momentum and energy transport across the interface. Tiny momentum impulses produce weak shock waves which travel through the interface and cause the spallation of crystal layers into the liquid. Kinetic and energetic constraints prevent spallation of partial layers from the crystal, a fact which may be of some practical use. We also study heat transport through the liquid-solid interface and obtain the resistances in liquid, solid and interfacial regions (Kapitza resistance) as the solid undergoes such layering transitions. Heat conduction, which shows strong signatures of the structural transformations, can be understood using a free volume calculation.

Abhishek Chaudhuri; Debasish Chaudhuri; Surajit Sengupta

2007-03-19T23:59:59.000Z

13

Nanoparticles at liquid interfaces: Rotational dynamics and angular locking  

SciTech Connect (OSTI)

Nanoparticles with different surface morphologies that straddle the interface between two immiscible liquids are studied via molecular dynamics simulations. The methodology employed allows us to compute the interfacial free energy at different angular orientations of the nanoparticle. Due to their atomistic nature, the studied nanoparticles present both microscale and macroscale geometrical features and cannot be accurately modeled as a perfectly smooth body (e.g., spheres and cylinders). Under certain physical conditions, microscale features can produce free energy barriers that are much larger than the thermal energy of the surrounding media. The presence of these energy barriers can effectively “lock” the particle at specific angular orientations with respect to the liquid-liquid interface. This work provides new insights on the rotational dynamics of Brownian particles at liquid interfaces and suggests possible strategies to exploit the effects of microscale features with given geometric characteristics.

Razavi, Sepideh; Kretzschmar, Ilona [Department of Chemical Engineering, City College of City University of New York, New York, New York 10031 (United States)] [Department of Chemical Engineering, City College of City University of New York, New York, New York 10031 (United States); Koplik, Joel [Department of Physics and The Benjamin Levich Institute for Physico-chemical Hydrodynamics, City College of City University of New York, New York, New York 10031 (United States)] [Department of Physics and The Benjamin Levich Institute for Physico-chemical Hydrodynamics, City College of City University of New York, New York, New York 10031 (United States); Colosqui, Carlos E., E-mail: carlos.colosqui@stonybrook.edu [Department of Mechanical Engineering, Stony Brook University, Stony Brook, New York 11794 (United States)

2014-01-07T23:59:59.000Z

14

Structure and Depletion at Fluoro- and Hydro-carbon/Water Liquid/Liquid Interfaces  

E-Print Network [OSTI]

The results of x-ray reflectivity studies of two oil/water (liquid/liquid) interfaces are inconsistent with recent predictions of the presence of a vapor-like depletion region at hydrophobic/aqueous interfaces. One of the oils, perfluorohexane, is a fluorocarbon whose super-hydrophobic interface with water provides a stringent test for the presence of a depletion layer. The other oil, heptane, is a hydrocarbon and, therefore, is more relevant to the study of biomolecular hydrophobicity. These results are consistent with the sub-angstrom proximity of water to soft hydrophobic materials.

Kaoru Kashimoto; Jaesung Yoon; Binyang Hou; Chiu-hao Chen; Binhua Lin; Makoto Aratono; Takanori Takiue; Mark L. Schlossman

2008-07-18T23:59:59.000Z

15

E-Print Network 3.0 - aux interfaces solide-liquide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

at the solid- liquid interface.2,3 The reason is the historical... diffusing, at the solid-liquid ... Source: Granick, Steve - Departments of Physics & Materials Science and...

16

E-Print Network 3.0 - air-liquid interface cell Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

film's air-liquid interface has a significant effect on the lung's mechanical... , is the surface tension and is the mean curvature of the air-liquid interface. For the uni-...

17

E-Print Network 3.0 - aux interfaces liquide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

film's air-liquid interface has a significant effect on the lung's mechanical... , is the surface tension and is the mean curvature of the air-liquid interface. For the uni-...

18

Dependence of solid-liquid interface free energy on liquid structure  

SciTech Connect (OSTI)

The Turnbull relation is widely believed to enable prediction of solid–liquid interface (SLI) free energies from measurements of the latent heat and the solid density. Ewing proposed an additional contribution to the SLI free energy to account for variations in liquid structure near the interface. In the present study, molecular dynamics (MD) simulations were performed to investigate whether SLI free energy depends on liquid structure. Analysis of the MD simulation data for 11 fcc metals demonstrated that the Turnbull relation is only a rough approximation for highly ordered liquids, whereas much better agreement is observed with Ewing’s theory. A modification to Ewing’s relation is proposed in this study that was found to provide excellent agreement with MD simulation data.

Wilson, S R [Ames Laboratory; Mendelev, M I [Ames Laboratory

2014-09-01T23:59:59.000Z

19

Methods and systems for monitoring a solid-liquid interface  

DOE Patents [OSTI]

Methods and systems are provided for monitoring a solid-liquid interface, including providing a vessel configured to contain an at least partially melted material; detecting radiation reflected from a surface of a liquid portion of the at least partially melted material; providing sound energy to the surface; measuring a disturbance on the surface; calculating at least one frequency associated with the disturbance; and determining a thickness of the liquid portion based on the at least one frequency, wherein the thickness is calculated based on L=(2m-1)v.sub.s/4f, where f is the frequency where the disturbance has an amplitude maximum, v.sub.s is the speed of sound in the material, and m is a positive integer (1, 2, 3, . . . ).

Stoddard, Nathan G. (Gettysburg, PA); Clark, Roger F. (Frederick, MD)

2011-10-04T23:59:59.000Z

20

Sudden structural change at ati air/binary liquid interface: Sum frequency study of the air/acetonitrile-water interface  

E-Print Network [OSTI]

Sudden structural change at ati air/binary liquid interface: Sum frequency study of the air/acetonitrile change in an air/acetonitrile-water interface as the solution composition varies; the abruptness of which and in the polarization of the signal from the acetonitrile molecules in the interface observed using infrared + visible

Eisenthal, Kenneth B.

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

First evidence of anisotropic quenched disorder effects on a smectic liquid crystal confined in porous silicon  

E-Print Network [OSTI]

We present a neutron scattering analysis of the structure of the smectic liquid crystal octylcyanobiphenyl (8CB) confined in one-dimensional nanopores of porous silicon films (PS). The smectic transition is completely suppressed, leading to the extension of a short-range ordered smectic phase aligned along the pore axis. It evolves reversibly over an extended temperature range, down to 50 K below the \\textit{N-SmA} transition in pure 8CB. This behavior strongly differs from previous observations of smectics in different one-dimensional porous materials. A coherent picture of this striking behavior requires that quenched disorder effects are invoked. The strongly disordered nature of the inner surface of PS acts as random fields coupling to the smectic order. The one-dimensionality of PS nano-channels offers new perspectives on quenched disorder effects, which observation has been restricted to homogeneous random porous materials so far.

Régis Guégan; Denis Morineau; Claude Loverdo; Wilfried Béziel; Mohammed Guendouz

2005-11-08T23:59:59.000Z

22

Ethylenediamine at Air/Liquid and Air/Silica Interfaces: Protonation  

E-Print Network [OSTI]

surface and EDA protonated products at air/liquid interfaces. The SFG spectra of EDA adsorbedEthylenediamine at Air/Liquid and Air/Silica Interfaces: Protonation Versus Hydrogen BondingKa (HOSit)) is between the two pKa values of EDA (in the range of 7.56-10.71) at the air/silica interface

23

Liquid chromatography/Fourier transform IR spectrometry interface flow cell  

DOE Patents [OSTI]

A zero dead volume (ZDV) microbore high performance liquid chromatography (..mu.. HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a ..mu.. HPLC column end fitting to minimize the transfer volume of the effluents exiting the ..mu.. HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF/sub 2/), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

Johnson, C.C.; Taylor, L.T.

1985-01-04T23:59:59.000Z

24

Dynamical instabilities of two-fluid interfaces in a porous medium: A three-dimensional video imaging study  

E-Print Network [OSTI]

Two-fluid interfaces in porous media, an example of driven disordered systems, were studied by a real time three-dimensional imaging technique with pore scale resolution for a less viscous fluid displacing a more viscous one. With increasing flow rate the interface transforms from flat to fingers and thence to droplets for both drainage and imbibition. The results compare and contrast the effects of randomness, both physical (geometry of the pore space) and chemical (wettability of the fluids), on the dynamical instability and identify the origin of the pore-scale processes that govern them.

Prerna Sharma; P. Aswathi; Anit Sane; Shankar Ghosh; S. Bhattacharya

2011-03-22T23:59:59.000Z

25

Reduced graphene oxide based silver sulfide hybrid films formed at a liquid/liquid interface  

SciTech Connect (OSTI)

Free-standing, ultra-thin films of silver sulfide and reduced graphene oxide (RGO) based silver sulfide hybrids are prepared at a liquid/liquid interface employing in situ chemical reaction strategy. Ag{sub 2}S and RGO?Ag{sub 2}S hybrid films are characterized by various techniques such as UV-visible and photo luminescence spectroscopy, X-ray diffraction and scanning electron microscopy. The morphology of hybrid films consists of Ag{sub 2}S nanocrystals on RGO surface while Ag{sub 2}S films contains branched network of dendritic structures. RGO?Ag{sub 2}S exhibit interesting optical and electrical properties. The hybrid films absorb in the region 500–650 nm and show emission in the red region. A higher conductance is observed for the hybrid films arising from the RGO component. This simple low cost method can be extended to prepare other RGO based metal sulfides.

Bramhaiah, K., E-mail: jsneena@csmr.res.in; John, Neena S., E-mail: jsneena@csmr.res.in [Centre for Soft Matter Research, P.B. No.1329, Jalahalli, Bangalore-560013 (India)

2014-04-24T23:59:59.000Z

26

E-Print Network 3.0 - air-liquid interface biofilms Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

, B. Purvedorj y , P. Stoodley yz Summary: and the velocity of the ripples at the biofilmbulk liquid interface. wg 5:09 Nm 2 . 21 12; Strain Source... A Viscoelastic Fluid...

27

Control and ultrasonic actuation of a gas-liquid interface in a microfluidic chip  

E-Print Network [OSTI]

This article describes the design and manufacturing of a microfluidic chip, allowing for the actuation of a gas-liquid interface and of the neighboring fluid. A first way to control the interface motion is to apply a pressure difference across it. In this case, the efficiency of three different micro-geometries at anchoring the interface is compared. Also, the critical pressures needed to move the interface are measured and compared to theoretical result. A second way to control the interface motion is by ultrasonic excitation. When the excitation is weak, the interface exhibits traveling waves, which follow a dispersion equation. At stronger ultrasonic levels, standing waves appear on the interface, with frequencies that are half integer multiple of the excitation frequency. An associated microstreaming flow field observed in the vicinity of the interface is characterized. The meniscus and associated streaming flow have the potential to transport particles and mix reagents.

Jie Xu; Daniel Attinger

2009-12-15T23:59:59.000Z

28

(Electron transfer rates at semiconductor/liquid interfaces)  

SciTech Connect (OSTI)

Work has focused on several aspects of the fundamental chemistry and physics semiconductor/liquid junction behavior. These projects have been directed primarily towards GaAs/liquid contacts, because GaAs/liquid systems provide high energy conversion efficiencies and offer an opportunity to gain mechanistic understanding of the factors that are important to control in an efficient photoelectrochemical energy conversion system.

Lewis, N.S.

1992-01-01T23:59:59.000Z

29

[Electron transfer rates at semiconductor/liquid interfaces]. Progress report  

SciTech Connect (OSTI)

Work has focused on several aspects of the fundamental chemistry and physics semiconductor/liquid junction behavior. These projects have been directed primarily towards GaAs/liquid contacts, because GaAs/liquid systems provide high energy conversion efficiencies and offer an opportunity to gain mechanistic understanding of the factors that are important to control in an efficient photoelectrochemical energy conversion system.

Lewis, N.S.

1992-08-01T23:59:59.000Z

30

A mean field approach for computing solid-liquid surface tension for nanoscale interfaces  

E-Print Network [OSTI]

A mean field approach for computing solid-liquid surface tension for nanoscale interfaces Chi are largely determined by the solid-liquid surface tension. This is especially true for nanoscale systems with high surface area to volume ratios. While experimental techniques can only measure surface tension

Nielsen, Steven O.

31

Capillary waves and the inherent density profile for the liquid-vapor interface  

E-Print Network [OSTI]

. This approach in turn allows: (1) identification of an "outermost layer" of particles on the liquid. (2). is a nonmonotonic function of normal distance through the interface. and is expected to reflect the diverging bulk distribution for the system in a state of liquid-vapor phase coexistence. This leads to identification

Stillinger, Frank

32

Effects of liquid pore water on acoustic wave propagation in snow as a Biot-type porous material  

E-Print Network [OSTI]

A method to estimate phase velocity and attenuation of acoustic waves in the presence of liquid water in a snowpack is presented. The method is based on Biot's theory of wave propagation in porous materials. Empirical relations and a priori information is used to characterize snow as a porous material as a function of porosity. Plane wave theory and an equivalent pore fluid are used to solve Biot's differential equations and to asses the impact of the air and water in the pore space. The liquid water in the pore space of a snow pack reduces the velocity of the first compressional wave by roughly 300 m/s for every 0.1 increase in liquid water saturation. Also the attenuation of the compressional waves is increased with increasing liquid water content. Two end member models for compaction are evaluated to asses the importance of an independent density measurement for an estimate of liquid pore water saturation in snow with acoustic waves. The two end members correspond to no compaction at all and to a melting s...

Sidler, Rolf

2015-01-01T23:59:59.000Z

33

Investigations of amino acid-based surfactants at liquid interfaces  

E-Print Network [OSTI]

at the air/water interface by epifluorescence microscopy. Anisotropic feather-like domains were observed in L-enantiomeric monolayers while symmetric circular domains were found in racemic N-SGA monolayers. At a surface pressure of 30 mN/m the enantiomeric...

Yang, Dengliang

2005-11-01T23:59:59.000Z

34

Molecular Structure and Ordering of Phospholipids at a Liquid-Liquid Interface  

E-Print Network [OSTI]

stretching region of several different phosphocholines adsorbed to the D2O- carbon tetrachloride interface the molecular structure of phosphocholine monolayers adsorbed to the interface between D2O and carbon tetrachloride. Monolayers form from breakup at the interface of aqueous phase phosphocholine vesicles

Richmond, Geraldine L.

35

Dual harmonic Kelvin probe force microscopy at the graphene–liquid interface  

SciTech Connect (OSTI)

Kelvin probe force microscopy (KPFM) is a powerful technique for the determination of the contact potential difference (CPD) between an atomic force microscope tip and a sample under ambient and vacuum conditions. However, for many energy storage and conversion systems, including graphene-based electrochemical capacitors, understanding electrochemical phenomena at the solid–liquid interface is paramount. Despite the vast potential to provide fundamental insight for energy storage materials at the nanoscale, KPFM has found limited applicability in liquid environments to date. Here, using dual harmonic (DH)-KPFM, we demonstrate CPD imaging of graphene in liquid. We find good agreement with measurements performed in air, highlighting the potential of DH-KPFM to probe electrochemistry at the graphene–liquid interface.

Collins, Liam; Rodriguez, Brian J., E-mail: brian.rodriguez@ucd.ie [School of Physics, University College Dublin, Belfield, Dublin 4 (Ireland); Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Belfield, Dublin 4 (Ireland); Kilpatrick, Jason I.; Weber, Stefan A. L. [Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Belfield, Dublin 4 (Ireland); Vlassiouk, Ivan V. [Energy and Transportation Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Tselev, Alexander; Jesse, Stephen; Kalinin, Sergei V. [Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2014-03-31T23:59:59.000Z

36

Economizer Based Data Center Liquid Cooling with Advanced Metal Interfaces  

SciTech Connect (OSTI)

A new chiller-less data center liquid cooling system utilizing the outside air environment has been shown to achieve up to 90% reduction in cooling energy compared to traditional chiller based data center cooling systems. The system removes heat from Volume servers inside a Sealed Rack and transports the heat using a liquid loop to an Outdoor Heat Exchanger which rejects the heat to the outdoor ambient environment. The servers in the rack are cooled using a hybrid cooling system by removing the majority of the heat generated by the processors and memory by direct thermal conduction using coldplates and the heat generated by the remaining components using forced air convection to an air- to- liquid heat exchanger inside the Sealed Rack. The anticipated benefits of such energy-centric configurations are significant energy savings at the data center level. When compared to a traditional 10 MW data center, which typically uses 25% of its total data center energy consumption for cooling this technology could potentially enable a cost savings of up to $800,000-$2,200,000/year (assuming electricity costs of 4 to 11 cents per kilowatt-hour) through the reduction in electrical energy usage.

Timothy Chainer

2012-11-30T23:59:59.000Z

37

Two--Phase Flow Problems in Porous Media for Sharp Interface Problems  

E-Print Network [OSTI]

. A control volume finite element method (CVFEM) is applied to the solution of the governing equations using hand by sharp interfaces between different fluids, such as these problems occur e.g. by DNAPL infiltration or saltwater intrusion. For the simulation of such processes, a two--dimensional model for two

Cirpka, Olaf Arie

38

Cu-Bi as a Model System For Liquid Phase Sintered Thermal Interface Management Materials  

E-Print Network [OSTI]

relates electrical resistivity to thermal conductivity for materials where electrons are principleCu-Bi as a Model System For Liquid Phase Sintered Thermal Interface Management Materials P to produce composite materials. A high melting phase (HMP) and low melting phase (LMP) are mixed

Collins, Gary S.

39

Modeling of ultrasound transmission through a solid-liquid interface comprising a network of gas pockets  

SciTech Connect (OSTI)

Ultrasonic inspection of sodium-cooled fast reactor requires a good acoustic coupling between the transducer and the liquid sodium. Ultrasonic transmission through a solid surface in contact with liquid sodium can be complex due to the presence of microscopic gas pockets entrapped by the surface roughness. Experiments are run using substrates with controlled roughness consisting of a network of holes and a modeling approach is then developed. In this model, a gas pocket stiffness at a partially solid-liquid interface is defined. This stiffness is then used to calculate the transmission coefficient of ultrasound at the entire interface. The gas pocket stiffness has a static, as well as an inertial component, which depends on the ultrasonic frequency and the radiative mass.

Paumel, K.; Baque, F. [CEA, DEN, Nuclear Technology Department, F-13108 Saint-Paul-lez-Durance (France); Moysan, J.; Corneloup, G. [Laboratoire de Caracterisation Non Destructive, Universite de la Mediterranee, IUT Aix-en-Provence, Avenue Gaston Berger, 13625 Aix-en-Provence (France); Chatain, D. [CNRS, Aix-Marseille Universite, CINAM-UPR3118, Campus de Luminy, Case 913, 13288 Marseille cedex 09 (France)

2011-08-15T23:59:59.000Z

40

Ionic liquid ion source emitter arrays fabricated on bulk porous substrates for spacecraft propulsion  

E-Print Network [OSTI]

Ionic Liquid Ion Sources (ILIS) are a subset of electrospray capable of producing bipolar beams of pure ions from ionic liquids. Ionic liquids are room temperature molten salts, characterized by negligible vapor pressures, ...

Courtney, Daniel George

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Interface for the rapid analysis of liquid samples by accelerator mass spectrometry  

DOE Patents [OSTI]

An interface for the analysis of liquid sample having carbon content by an accelerator mass spectrometer including a wire, defects on the wire, a system for moving the wire, a droplet maker for producing droplets of the liquid sample and placing the droplets of the liquid sample on the wire in the defects, a system that converts the carbon content of the droplets of the liquid sample to carbon dioxide gas in a helium stream, and a gas-accepting ion source connected to the accelerator mass spectrometer that receives the carbon dioxide gas of the sample in a helium stream and introduces the carbon dioxide gas of the sample into the accelerator mass spectrometer.

Turteltaub, Kenneth; Ognibene, Ted; Thomas, Avi; Daley, Paul F; Salazar Quintero, Gary A; Bench, Graham

2014-02-04T23:59:59.000Z

42

Density Profiles of Liquid/Vapor Interfaces Away from Their Critical Point  

E-Print Network [OSTI]

We examine the applicability of various model profiles for the liquid/vapor interface by X-ray reflectivities on water and ethanol and their mixtures at room temperature. Analysis of the X-ray reflecivities using various density profiles shows an error-function like profile is the most adequate within experimental error. Our finding, together with recent observations from simulation studies on liquid surfaces, strongly suggest that the capillary-wave dynamics shapes the interfacial density profile in terms of the error function.

Wei Bu; Doseok Kim; David Vaknin

2014-04-28T23:59:59.000Z

43

A flexible, highly stable electrochemical scanning probe microscope for nanoscale studies at the solid-liquid interface  

E-Print Network [OSTI]

low-noise measurements in ambient, in situ, and electrochemical environments. II. DESIGNA flexible, highly stable electrochemical scanning probe microscope for nanoscale studies at the solid-liquid interface, specifically in electrolyte environments. Quantification of system noise limits

Gimzewski, James

44

Charge transfer effects of ions at the liquid water/vapor interface  

SciTech Connect (OSTI)

Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 Å away from the surface.

Soniat, Marielle; Rick, Steven W., E-mail: srick@uno.edu [Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148 (United States)

2014-05-14T23:59:59.000Z

45

Trapping energy of a spherical particle on a curved liquid interface  

E-Print Network [OSTI]

We derive the trapping energy of a colloidal particle at a liquid interface with contact angle h and principal curvatures c1 and c2. The boundary conditions at the particle surface are significantly simplified by introducing the shift e of its vertical position. We discuss the undulating contact line and the curvatureinduced lateral forces for a single particle and a pair of nearby particles. The single-particle trapping energy is found to decrease with the square of both the total curvature c1 + c2 and the anisotropy c1 ? c2. In the case of non-uniform curvatures, the resulting lateral force pushes particles toward more strongly curved regions.

Joseph Léandri; Alois Würger

2014-01-29T23:59:59.000Z

46

Determination of the pressure at the gas-liquid interface using acoustic speed measurements  

E-Print Network [OSTI]

. The density can be expressed with the use of the real gas law. This yields BP = ? (g/gc) *dz*P*M/(144*Z*R*T) BP = ? (g/gc) *dz*P*SG*MAIR/(144*Z*R*T) (26) 21 where: SG MAIR specific gravity of gas. (air= 1. 0), Molecular weight of air, 28. 966...DETERMINATION OF THE PRESSURE AT THE GAS-LIQUID INTERFACE USING ACOUSTIC SPEED MEASUREMENTS A Thesis by DAG GUSTAV HEGGELUND Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree...

Heggelund, Dag Gustav

1988-01-01T23:59:59.000Z

47

Improving liquid chromatography-mass spectrometry sensitivity using a subambient pressure ionization with nanoelectrospray (SPIN) interface  

SciTech Connect (OSTI)

In this work the Subambient Pressure Ionization with Nanoelectrospray (SPIN) ion source and interface which operates at ~15-30 Torr is demonstrated to be compatible with gradient reversed-phase liquid chromatography-MS applications, exemplified here with the analysis of complex samples (a protein tryptic digest and a whole cell lysate). A low liquid chromatographic flow rate (100-400 nL/min) allowed stable electrospray to be established while avoiding electrical breakdown. Efforts to increase the operating pressure of the SPIN source relative to previously reported designs prevented solvent freezing and enhanced charged cluster/droplet desolvation. A 5-12-fold improvement in sensitivity relative to a conventional atmospheric pressure nanoelectrospray ionization (ESI) source was obtained for detected peptides.

Tang, Keqi; Page, Jason S.; Marginean, Ioan; Kelly, Ryan T.; Smith, Richard D.

2011-04-22T23:59:59.000Z

48

Smouldering Combustion of Organic Liquids in Porous Media for Remediating NAPL-contaminated Soils   

E-Print Network [OSTI]

This research investigated the potential of smouldering combustion to be employed as a remediation approach for soil contaminated by non-aqueous phase liquids (NAPLs). Small-scale (~15 cm), proof-of-concept experiments ...

Pironi, Paolo

2010-01-01T23:59:59.000Z

49

Porous Materials Porous Materials  

E-Print Network [OSTI]

1 Porous Materials x Porous Materials · Physical properties * Characteristic impedance p = p 0 e -jk xa- = vej[ ] p x - j ; Zc= p ve = c ka 0k = c 1-j #12;2 Porous Materials · Specific acoustic impedance Porous Materials · Finite thickness ­ blocked p e + -jk (x-d)a p e - jk (x-d)a d x #12

Berlin,Technische Universität

50

Liquid-Air Interface Corrosion Testing Simulating The Environment Of Hanford Double Shell Tanks  

SciTech Connect (OSTI)

Coupon tests on A537 carbon steel materials were conducted to evaluate the Liquid-Air Interface (LAI) corrosion susceptibility in a series of solutions designed to simulate conditions in the radioactive waste tanks located at the Hanford Nuclear Facility. The new stress corrosion cracking requirements and the impact of ammonia on LAI corrosion were the primary focus. The minimum R value (i.e., molar ratio of nitrite to nitrate) of 0.15 specified by the new stress corrosion cracking requirements was found to be insufficient to prevent pitting corrosion at the LAI. The pH of the test solutions was 10, which was actually less than the required pH 11 defined by the new requirements. These tests examined the effect of the variation of the pH due to hydroxide depletion at the liquid air interface. The pits from the current testing ranged from 0.001 to 0.008 inch in solutions with nitrate concentrations of 0.4 M and 2.0 M. The pitting and general attack that occurred progressed over the four-months. No significant pitting was observed, however, for a solution with a nitrate concentration of 4.5 M. The pitting depths observed in these partial immersion tests in unevaporated condensates ranged from 0.001 to 0.005 inch after 4 months. The deeper pits were in simulants with low R values. Simulants with R values of approximately 0.6 to 0.8 appeared to significantly reduce the degree of attack. Although, the ammonia did not completely eliminate attack at the LAI, the amount of corrosion in an extremely corrosive solution was significantly reduced. Only light general attack (< 1 mil) occurred on the coupon in the vicinity of the LAI. The concentration of ammonia (i.e., 50 ppm or 500 ppm) did not have a strong effect.

Wiersma, B.; Gray, J. R.; Garcia-Diaz, B. L.; Murphy, T. H.; Hicks, K. R.

2014-01-30T23:59:59.000Z

51

Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy  

SciTech Connect (OSTI)

Design and performance of a reactor set-up for attenuated total reflection infrared (ATR-IR) spectroscopy suitable for simultaneous reaction monitoring of bulk liquid and catalytic solid-liquid-gas interfaces under working conditions are presented. As advancement of in situ spectroscopy an operando methodology for gas-liquid-solid reaction monitoring was developed that simultaneously combines catalytic activity and molecular level detection at the catalytically active site of the same sample. Semi-batch reactor conditions are achieved with the analytical set-up by implementing the ATR-IR flow-through cell in a recycle reactor system and integrating a specifically designed gas feeding system coupled with a bubble trap. By the use of only one spectrometer the design of the new ATR-IR reactor cell allows for simultaneous detection of the bulk liquid and the catalytic interface during the working reaction. Holding two internal reflection elements (IRE) the sample compartments of the horizontally movable cell are consecutively flushed with reaction solution and pneumatically actuated, rapid switching of the cell (<1 s) enables to quasi simultaneously follow the heterogeneously catalysed reaction at the catalytic interface on a catalyst-coated IRE and in the bulk liquid on a blank IRE. For a complex heterogeneous reaction, the asymmetric hydrogenation of 2,2,2-trifluoroacetophenone on chirally modified Pt catalyst the elucidation of catalytic activity/enantioselectivity coupled with simultaneous monitoring of the catalytic solid-liquid-gas interface is shown. Both catalytic activity and enantioselectivity are strongly dependent on the experimental conditions. The opportunity to gain improved understanding by coupling measurements of catalytic performance and spectroscopic detection is presented. In addition, the applicability of modulation excitation spectroscopy and phase-sensitive detection are demonstrated.

Meemken, Fabian; Müller, Philipp; Hungerbühler, Konrad; Baiker, Alfons, E-mail: baiker@chem.ethz.ch [Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Switzerland)

2014-08-15T23:59:59.000Z

52

The crystal–liquid interface of a body?centered?cubic?forming substance: Computer simulations of the r ? 6 potential  

E-Print Network [OSTI]

(the bulk density change).27 For the (100) interface this 10--90 width is measured to be about 5.7a (just over 8 lattice planes). The variation of the diffusion constant through the in­ terface was calculated by dividing the z direction into 30 bins..., and were found not to differ measurably. The limiting liquid value of D (0.011 59 ± 0.000 01) was obtained in a separate 686 parti­ cle simulation of the bulk liquid. Note that bulk liquid diffu­ sion constants are known to be somewhat system size depen...

Laird, Brian Bostian; Haymet, A. D. J.

1989-09-01T23:59:59.000Z

53

A combined droplet train and ambient pressure photoemission spectrometer for the investigation of liquid/vapor interfaces  

SciTech Connect (OSTI)

We describe a combined ambient pressure photoelectron spectroscopy/droplet train apparatus for investigating the nature and heterogeneous chemistry of liquid/vapor interfaces. In this instrument a liquid droplet train with typical droplet diameters from 50...150 {micro}m is produced by a vibrating orifice aerosol generator (VOAG). The droplets are irradiated by soft X-rays (100...1500 eV) in front of the entrance aperture of a differentially pumped electrostatic lens system that transfers the emitted electrons into a conventional hemispherical electron analyzer. The photoemission experiments are performed at background pressures of up to several Torr, which allows the study of environmentally important liquid/vapor interfaces, in particular aqueous solutions, under equilibrium conditions. The exposure time of the droplet surface to the background gases prior to the XPS measurement can be varied, which will allow future kinetic measurements of gas uptake on liquid surfaces. As an example, a measurement of the surface composition of a {chi} = 0.21 aqueous methanol solution is presented. The concentration of methanol at the vapor/liquid interface is enhanced by a factor of about 3 over the bulk value, while the expected bulk value is recovered at depths larger than about 1.5 nm.

Starr, David E.; Wong, Ed K.; Worsnop, Douglas R.; Wilson, Kevin R.; Bluhm, Hendrik

2008-05-01T23:59:59.000Z

54

Sum frequency generation study on the orientation of room-temperature ionic liquid at the grapheneionic liquid interface  

E-Print Network [OSTI]

such as dye-sensitized solar cells and super capacitors, room-temperature ionic liquids are considered

Bao, Jiming

55

Gas Bubbles and Gas Pancakes at Liquid/Solid Interface: A Continuum Theory Incorporated with Molecular Interactions  

E-Print Network [OSTI]

The states of gas accumulated at the liquid-solid interface are analyzed based on the continuum theory where the Hamaker constant is used to describe the long-range interaction at the microscopic scale. The Hamaker constant is always negative, whereas the gas spreading coefficient can be either sign. Despite the complexity of gas, including that the density profile may not be uniform due to absorption on both solid and liquid surfaces, we predict three possible gas states at the liquid-solid interface, i.e. complete wetting, partial wetting and pseudopartial wetting. These possible gas states correspond respectively to a gas pancake (or film) surrounded by a wet solid, a gas bubble with a finite contact angle, and a gas bubble(s) coexisting with a gas pancake. Typical thickness of the gas pancakes is at the nanoscale within the force range of the long-range interaction, whereas the radius of the gas bubbles can be large. The state of gas bubble(s) coexisting with a gas film is predicted theoretically for the first time. Our theoretical results can contribute to the development of a unified picture of gas nucleation at the liquid-solid interface.

Zhaoxia Li; Xuehua Zhang; Lijuan Zhang; Xiaocheng Zeng; Jun Hu; Haiping Fang

2007-10-27T23:59:59.000Z

56

Structure of gas-liquid interface and hydrophobic interface for urea aqueous solution: a computer simulation study  

E-Print Network [OSTI]

near the interfacial areas are analyzed in terms of density, orientation and number of hydrogen bonds. For each kind of interface, systems with four different urea concentrations are included, ranging from 0M to 8M. The results show slight change...

Yu, Meng

2009-05-15T23:59:59.000Z

57

LIQUID CRYSTAL THERMOGRAPHY ON THE FLUID SOLID INTERFACE OF ROTATING SYSTEMS  

E-Print Network [OSTI]

= Aluminum c = centrifugal lc = liquid crystal o = aerodynamic wall friction related p = at constant pressu

Camci, Cengiz

58

Adsorption Trajectories and Free-Energy Separatrices for Colloidal Particles in Contact with a Liquid-Liquid Interface  

E-Print Network [OSTI]

We apply the recently developed triangular tessellation technique as presented in [J. de Graaf et al., Phys. Rev. E 80, 051405 (2009)] to calculate the free energy associated with the adsorption of anisotropic colloidal particles at a flat interface. From the free-energy landscape, we analyze the adsorption process, using a simplified version of Langevin dynamics. The present result is a first step to understand the time-dependent behavior of colloids near interfaces. This study shows a wide range of adsorption trajectories, where the emphasis lies on a strong dependence of the dynamics on the orientation of the colloid at initial contact with the interface. We believe that the observed orientational dependence in our simple model can be recovered in suitable experimental systems.

J. de Graaf; M. Dijkstra; R. van Roij

2010-02-18T23:59:59.000Z

59

Sink Flow Deforms the Interface Between a Viscous Liquid and Air into a Tip Singularity S. Courrech du Pont and J. Eggers  

E-Print Network [OSTI]

further, the opening angle of the cone vanishes like h2. No evidence for air entrainment was found, exceptSink Flow Deforms the Interface Between a Viscous Liquid and Air into a Tip Singularity S. Courrech between a viscous liquid and air is deformed by a sink flow of constant flow rate to form a sharp tip

Eggers, Jens

60

Nonaqueous Phase Liquid Dissolution in Porous Media: Multi-Scale Effects of Multi-Component Dissolution Kinetics on Cleanup Time  

SciTech Connect (OSTI)

Industrial organic solvents such as trichloroethylene (TCE) and tetrachloroethylene (PCE) constitute a principal class of groundwater contaminants. Cleanup of groundwater plume source areas associated with these compounds is problematic, in part, because the compounds often exist in the subsurface as dense nonaqueous phase liquids (DNAPLs). Ganglia (or 'blobs') of DNAPL serve as persistent sources of contaminants that are difficult to locate and remediate (e.g. Fenwick and Blunt, 1998). Current understanding of the physical and chemical processes associated with dissolution of DNAPLs in the subsurface is incomplete and yet is critical for evaluating long-term behavior of contaminant migration, groundwater cleanup, and the efficacy of source area cleanup technologies. As such, a goal of this project has been to contribute to this critical understanding by investigating the multi-phase, multi-component physics of DNAPL dissolution using state-of-the-art experimental and computational techniques. Through this research, we have explored efficient and accurate conceptual and numerical models for source area contaminant transport that can be used to better inform the modeling of source area contaminants, including those at the LLNL Superfund sites, to re-evaluate existing remediation technologies, and to inspire or develop new remediation strategies. The problem of DNAPL dissolution in natural porous media must be viewed in the context of several scales (Khachikian and Harmon, 2000), including the microscopic level at which capillary forces, viscous forces, and gravity/buoyancy forces are manifested at the scale of individual pores (Wilson and Conrad, 1984; Chatzis et al., 1988), the mesoscale where dissolution rates are strongly influenced by the local hydrodynamics, and the field-scale. Historically, the physico-chemical processes associated with DNAPL dissolution have been addressed through the use of lumped mass transfer coefficients which attempt to quantify the dissolution rate in response to local dissolved-phase concentrations distributed across the source area using a volume-averaging approach (Figure 1). The fundamental problem with the lumped mass transfer parameter is that its value is typically derived empirically through column-scale experiments that combine the effects of pore-scale flow, diffusion, and pore-scale geometry in a manner that does not provide a robust theoretical basis for upscaling. In our view, upscaling processes from the pore-scale to the field-scale requires new computational approaches (Held and Celia, 2001) that are directly linked to experimental studies of dissolution at the pore scale. As such, our investigation has been multi-pronged, combining theory, experiments, numerical modeling, new data analysis approaches, and a synthesis of previous studies (e.g. Glass et al, 2001; Keller et al., 2002) aimed at quantifying how the mechanisms controlling dissolution at the pore-scale control the long-term dissolution of source areas at larger scales.

McNab, W; Ezzedine, S; Detwiler, R

2007-02-26T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

(Fundamental electron transfer processes at the single crystal semiconductor/liquid interface)  

SciTech Connect (OSTI)

The last year's work has focused on several aspects of the fundamental chemistry and physics semiconductor/liquid junction behavior. These projects have been directed primarily towards GaAs/liquid contacts, because GaAs/liquid systems provide high energy conversion efficiencies and offer an opportunity to gain mechanistic understanding of the factors that are important to control in an efficient photoelectrochemical energy conversion system.

Lewis, N.S.

1991-01-01T23:59:59.000Z

62

[Fundamental electron transfer processes at the single crystal semiconductor/liquid interface]. Progress report  

SciTech Connect (OSTI)

The last year`s work has focused on several aspects of the fundamental chemistry and physics semiconductor/liquid junction behavior. These projects have been directed primarily towards GaAs/liquid contacts, because GaAs/liquid systems provide high energy conversion efficiencies and offer an opportunity to gain mechanistic understanding of the factors that are important to control in an efficient photoelectrochemical energy conversion system.

Lewis, N.S.

1991-12-31T23:59:59.000Z

63

Adsorption at Liquid Interfaces Induces Amyloid Fibril Bending and Ring Formation  

E-Print Network [OSTI]

Protein fibril accumulation at interfaces is an important step in many physiological processes and neurodegenerative diseases as well as in designing materials. Here we show, using $\\beta$-lactoglobulin fibrils as a model, that semiflexible fibrils exposed to a surface do not possess the Gaussian distribution of curvatures characteristic for wormlike chains, but instead exhibit a spontaneous curvature, which can even lead to ring-like conformations. The long-lived presence of such rings is confirmed by atomic force microscopy, cryogenic scanning electron microscopy and passive probe particle tracking at air- and oil-water interfaces. We reason that this spontaneous curvature is governed by structural characteristics on the molecular level and is to be expected when a chiral and polar fibril is placed in an inhomogeneous environment such as an interface. By testing $\\beta$-lactoglobulin fibrils with varying average thicknesses, we conclude that fibril thickness plays a determining role in the propensity to form rings.

Sophia Jordens; Emily E. Riley; Ivan Usov; Lucio Isa; Peter D. Olmsted; Raffaele Mezzenga

2014-10-29T23:59:59.000Z

64

Thermal conductance of solid-liquid interfaces Scott Huxtable, Zhenbin Ge, David G. Cahill  

E-Print Network [OSTI]

thermal conductivity in nanostructured materials ­ improved thermoelectric energy conversion improved/surfactant/water PMMA/Al2O3 nanotube/alkane #12;Modulated pump-probe apparatus f=10 MHz rf lock-in #12;Solid · Cooling rate (RC time constant) gives interface conductance G = 12 MW m-2 K-1G = 12 MW m K #12;Application

Braun, Paul

65

Characterization of Thermal Properties and Interface Development in Cu-In Liquid Phase  

E-Print Network [OSTI]

and thermal resistance in order to determine the relative importance of interfacial resistance and material number DMR-1062898 and Intel Corporation. ApparatusObjectives ·Measure the effective thermal resistance of next generation Copper-Indium composite thermal interface materials ·Adapt the ASTM D5470-06 standard

Collins, Gary S.

66

In Situ Immobilization of Uranium in Structured Porous Media via Biomineralization at the Fracture/Matrix Interface – Subproject to Co-PI Eric E. Roden  

SciTech Connect (OSTI)

Although the biogeochemical processes underlying in situ bioremediation technologies are increasingly well understood, field-scale heterogeneity (both physical and biogeochemical) remains a major obstacle to successful field-scale implementation. In particular, slow release of contamination from low-permeability regions (primarily by diffusive/dispersive mass transfer) can hinder the effectiveness of remediation. The research described in this report was conducted in conjunction with a project entitled “In Situ Immobilization of Uranium in Structured Porous Media via Biomineralization at the Fracture/Matrix Interface”, which was funded through the Field Research element of the former NABIR Program (now the Environmental Remediation Sciences Program) within the Office of Biological and Environmental Research. Dr. Timothy Scheibe (Pacific Northwest National Laboratory) was the overall PI/PD for the project, which included Scott Brooks (Oak Ridge National Laboratory) and Eric Roden (formerly at The University of Alabama, now at the University of Wisconsin) as separately-funded co-PIs. The overall goal of the project was to evaluate strategies that target bioremediation at interfaces between high- and low-permeability regions of an aquifer in order to minimize the rate of contaminant transfer into high-permeability/high fluid flow zones. The research was conducted at the Area 2 site of the Field Research Center (FRC) at Oak Ridge National Laboratory (ORNL). Area 2 is a shallow pathway for migration of contaminated groundwater to seeps in the upper reach of Bear Creek at ORNL, mainly through a ca. 1 m thick layer of gravel located 4-5 m below the ground surface. Hydrological tracer studies indicate that the gravel layer receives input of uranium from both upstream sources and from diffusive mass transfer out of highly contaminated fill and saprolite materials above and below the gravel layer. We sought to test the hypothesis that injection of electron donor into this layer would induce formation of a redox barrier in the less conductive materials above and below the gravel, resulting in decreased mass transfer of uranium out these materials and attendant declines in groundwater U(VI) concentration. Details regarding the planning, execution, and results of the in situ biostimulation experiment will be provided in separate peer-reviewed publications by the project PIs and colleagues. This report summarizes research activities conducted at The University of Alabama (2002-2005) and the University of Wisconsin (2005-2007) in support of the field experiment, which included (1) chemical and microbiological characterization of sediment cores from Area 2; (2) sediment slurry experiments with Area 2 materials which evaluated the biogeochemical response to ethanol amendment and the potential for U(VI) reduction; (3) analysis of the response of groundwater microbial communities to in situ biostimulation. In addition, biogeochemical reaction models of microbial metabolism in ethanol-stimulated sediments, developed based on sediment slurry experiments, are described.

Eric E. Roden

2007-11-02T23:59:59.000Z

67

US Liquid Metal Fast Breeder Reactor man-machine interface program  

SciTech Connect (OSTI)

The US LMFBR Man-Machine Interface Program is supportive to and an integral part of the LMFBR Safety Program. This paper describes the goal and objectives of the program, and the necessary research and development efforts with a logical structure for the orderly and timely implementation of the prgoram. Current status and near-term and long-term priority activities are also summarized.

Vaurio, J.K.; Change, S.A.

1982-01-01T23:59:59.000Z

68

TESTING VAPOR SPACE AND LIQUID-AIR INTERFACE CORROSION IN SIMULATED ENVIRONMENTS OF HANFORD DOUBLE-SHELLED TANKS  

SciTech Connect (OSTI)

Electrochemical coupon testing were performed on 6 Hanford tank solution simulants and corresponding condensate simulants to evaluate the susceptibility of vapor space and liquid/air interface corrosion. Additionally, partial-immersion coupon testing were performed on the 6 tank solution simulants to compliment the accelerated electrochemical testing. Overall, the testing suggests that the SY-102 high nitrate solution is the most aggressive of the six solution simulants evaluated. Alternatively, the most passive solution, based on both electrochemical testing and coupon testing, was AY-102 solution. The presence of ammonium nitrate in the simulants at the lowest concentration tested (0.001 M) had no significant effect. At higher concentrations (0.5 M), ammonium nitrate appears to deter localized corrosion, suggesting a beneficial effect of the presence of the ammonium ion. The results of this research suggest that there is a threshold concentration of ammonium ions leading to inhibition of corrosion, thereby suggesting the need for further experimentation to identify the threshold.

Hoffman, E.

2013-05-30T23:59:59.000Z

69

Structure and phase transitions into ionic adsorption layers on liquid interfaces  

E-Print Network [OSTI]

The structure of ionic adsorption layers is studied via a proper thermodynamic treatment of the electrostatic and non-electrostatic interactions between the surfactant ions as well as of the effect of thermodynamic non-locality. The analysis is also applied to phase transitions into the ionic adsorption layer, which interfere further with the oscillatory-diffusive structure of the electric double layer and hydrodynamic stability of squeezing waves in thin liquid films.

R. Tsekov

2014-10-25T23:59:59.000Z

70

JOURNAL DE PHYSIQUE CoZZoque C8, suppZ6ment au n08, Tome 41, aoct 1980, page C8-803 KGLECULAR DYNAMICS STUDIES OF SOLID-LIQUID INTERFACE OF SOFT-CORE MODEL  

E-Print Network [OSTI]

DYNAMICS STUDIES OF SOLID-LIQUID INTERFACE OF SOFT-CORE MODEL A. Ueda, J. Takada and Y. ~ ~ w a t a r i. Abstract.- The (100) solid-liquid interface of the soft-core system is studied with a molecular dynamics fluctuations. Our values of the coexistence densities and pressure are in agreement with the other works within

Paris-Sud XI, Université de

71

ILASS Americas 17th Annual Conference on Liquid Atomization and Spray Systems, Arlington, VA, May 2004 Optimal Disturbance Structure and Development on a Sheared Interface  

E-Print Network [OSTI]

ILASS Americas 17th Annual Conference on Liquid Atomization and Spray Systems, Arlington, VA, May, viscosity and mean velocity all change. In the immediate vicinity of the interface, boundary layer flow thickness), density ratio r = 0.02 and viscosity ratio m = 0.025. The OD of this two-phase flow show some

Yecko, Philip

72

Study of Hydrophobic and Ionizable Hydrophilic Copolymers at Polymer/Solid and Polymer/Liquid Interfaces  

SciTech Connect (OSTI)

Joint experimental-computational efforts were set to characterize the interfacial effects on the structure and dynamics of polymers consisting of highly rigid hydrophilic-ionizable and hydrophobic sub-units within one polymeric chain casted into thin films of several molecular dimensions. Focusing on the ultra thin film region we separate out the interfacial effects from bulk characteristics. Specifically, the study sought to: identify the parameters that control the formation of a stable polymer-solid interface. The study consists of two components, experimental investigations and computational efforts. The experimental component was designed to derive empirical trends that can be used to correlate the set of coupled polymer molecular parameters with the interfacial characteristics of these polymers, and their response to presence of solvents. The computational study was designed to provide molecular insight into the ensemble averages provided by the experimental efforts on multiple length scales from molecular dimensions, to the nanometer lengths to a macroscopic understanding of solvent interactions with structured polymers. With the ultimate goal of correlating molecular parameters to structure, dynamics and properties of ionic polymers, the first stage of the research began with the study of two systems, one which allowed tailoring the flexibility of the backbone without the presence of ionic groups, but with a potential to sulfonate groups at a later stage, and a polymer whose backbone is rigid and the density of the ionic group can be varied. The combined experimental and computational studies significantly extended the understanding of polymers at interfaces from model systems to polydispersed copolymers with blocks of varying nature and complexity. This new insight directly affects the design of polymers for sustainable energy applications from batteries and fuel cells to solar energy.

Perahia, Dvora

2011-11-01T23:59:59.000Z

73

Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries  

SciTech Connect (OSTI)

Li-S battery is a complicated system with many challenges existing before its final market penetration. While most of the reported work for Li-S batteries is focused on the cathode design, we demonstrate in this work that the anode consumption accelerated by corrosive polysulfide solution also critically determines the Li-S cell performance. To validate this hypothesis, ionic liquid (IL) N-methyl-N-butylpyrrolidinium bis(trifluoromethylsulfonyl)imide (Py14TFSI) has been employed to modify the properties of SEI layer formed on Li metal surface in Li-S batteries. It is found that the IL-enhanced passivation film on the lithium anode surface exhibits much different morphology and chemical compositions, effectively protecting lithium metal from continuous attack by soluble polysulfides. Therefore, both cell impedance and the irreversible consumption of polysulfides on lithium metal are reduced. As a result, the Coulombic efficiency and the cycling stability of Li-S batteries have been greatly improved. After 120 cycles, Li-S battery cycled in the electrolyte containing IL demonstrates a high capacity retention of 94.3% at 0.1 C rate. These results unveil another important failure mechanism for Li-S batteries and shin the light on the new approaches to improve Li-S battery performances.

Zheng, Jianming; Gu, Meng; Chen, Honghao; Meduri, Praveen; Engelhard, Mark H.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

2013-05-16T23:59:59.000Z

74

Low energy electron diffraction (LEED) and sum frequency generation (SFG) vibrational spectroscopy studies of solid-vacuum, solid-air and solid-liquid interfaces  

SciTech Connect (OSTI)

Electron based surface probing techniques can provide detailed information about surface structure or chemical composition in vacuum environments. The development of new surface techniques has made possible in situ molecular level studies of solid-gas interfaces and more recently, solid-liquid interfaces. The aim of this dissertation is two-fold. First, by using novel sample preparation, Low Energy Electron Diffraction (LEED) and other traditional ultra high vacuum (UHV) techniques are shown to provide new information on the insulator/vacuum interface. The surface structure of the classic insulator NaCl has been determined using these methods. Second, using sum frequency generation (SFG) surface specific vibrational spectroscopy studies were performed on both the biopolymer/air and electrode/electrolyte interfaces. The surface structure and composition of polyetherurethane-silicone copolymers were determined in air using SFG, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). SFG studies of the electrode (platinum, gold and copper)/electrolyte interface were performed as a function of applied potential in an electrochemical cell.

Hoffer, Saskia

2002-08-19T23:59:59.000Z

75

Review of enhanced vapor diffusion in porous media  

SciTech Connect (OSTI)

Vapor diffusion in porous media in the presence of its own liquid has often been treated similar to gas diffusion. The gas diffusion rate in porous media is much lower than in free space due to the presence of the porous medium and any liquid present. However, enhanced vapor diffusion has also been postulated such that the diffusion rate may approach free-space values. Existing data and models for enhanced vapor diffusion, including those in TOUGH2, are reviewed in this paper.

Webb, S.W.; Ho, C.K.

1998-08-01T23:59:59.000Z

76

A combined droplet train and ambient pressure photoemission spectrometer for the investigation of liquid/vapor interfaces  

E-Print Network [OSTI]

A combined droplet train and ambient pressure photoemissionspectroscopy/droplet train apparatus for investigating thethis instrument a liquid droplet train with typical droplet

Starr, David E.

2008-01-01T23:59:59.000Z

77

Gravity-induced reorientation of the interface between two liquids of different densities flowing laminarly through a microchannel  

E-Print Network [OSTI]

or membraneless fuel cells;10 and the creation of axisymmetric microscale polymeric struc- tures.11 of mammalian and microbial cells;5 liquid­ liquid extractions;6 crystallization of proteins7 or inorganic salts in membrane- less fuel cells.9,10 Understanding the interplay of forces that dictates the reorientation

Kenis, Paul J. A.

78

Effects of interfaces on dynamics in micro-fluidic devices: slip-boundaries' impact on rotation characteristics of polar liquid film motors  

E-Print Network [OSTI]

Slip-boundary effects on the polar liquid film motor (PLFM) -- a novel micro-fluidic device with important implications for advancing knowledge on liquid micro-film's structure, dynamics, modeling and technology -- are studied. We develop a mathematical model, under slip boundary conditions, describing electro-hydro-dynamical rotations in the PLFMs induced either by direct current (DC) or alternating current (AC) fields. Our main results are: (i) rotation characteristics depend on the ratio $k=l_{s}/D$ ($l_{s}$ denotes the slip length, resulting from the interface's impact on the structure of the liquid and $D$ denotes the film's diameter). (ii) As $k$ ($k>-1/2$) increases: (a) PLFMs subsequently exhibit rotation characteristics under "negative-", "no-", "partial-" and "perfect-" slip boundary conditions; (b) the maximum value of the linear velocity of the steady rotating liquid film increases and its location approaches the film's border; (c) the decay of the angular velocities' dependency on the distance from the center of the film slows down, resulting in a macroscopic flow near the boundary. (iii) In addition to $k$, the rotation characteristics of the AC PLFM depend on the magnitudes, the frequencies, and the phase difference of the AC fields. (iv) Our analytical derived rotation speed distributions are consistent with the existing experimental ones.

Zhong-Qiang Liu; Su-Rong Jiang; Tamar A. Yinnon; Xiang-Mu Kong; Ying-Jun Li

2014-04-21T23:59:59.000Z

79

Liquid foams of graphene  

E-Print Network [OSTI]

Liquid foams are dispersions of bubbles in a liquid. Bubbles are stabilized by foaming agents that position at the interface between the gas and the liquid. Most foaming agents, such as the commonly used sodium dodecylsulfate, ...

Alcazar Jorba, Daniel

2012-01-01T23:59:59.000Z

80

Method to prepare nanoparticles on porous mediums  

DOE Patents [OSTI]

A method to prepare porous medium decorated with nanoparticles involves contacting a suspension of nanoparticles in an ionic liquid with a porous medium such that the particles diffuse into the pores of the medium followed by heating the resulting composition to a temperature equal to or greater than the thermal decomposition temperature of the ionic liquid resulting in the removal of the liquid portion of the suspension. The nanoparticles can be a metal, an alloy, or a metal compound. The resulting compositions can be used as catalysts, sensors, or separators.

Vieth, Gabriel M. (Knoxville, TN) [Knoxville, TN; Dudney, Nancy J. (Oak Ridge, TN) [Oak Ridge, TN; Dai, Sheng (Knoxville, TN) [Knoxville, TN

2010-08-10T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

PUBLISHED ONLINE: 7 APRIL 2013 | DOI: 10.1038/NMAT3598 Adaptive fluid-infused porous films with tunable  

E-Print Network [OSTI]

LETTERS PUBLISHED ONLINE: 7 APRIL 2013 | DOI: 10.1038/NMAT3598 Adaptive fluid-infused porous films for malleable surfaces. As we have recently shown, a liquid infused in a rigid porous substrate develops 1School

Mahadevan, L.

82

Porous material and process development for electrospray propulsion applications  

E-Print Network [OSTI]

Ion electrospray propulsion devices rely on the transportation of ionic liquid propellant to emission regions where ions are extracted at high velocities. One such method involves the use of porous substrates to passively ...

Arestie, Steven Mark

2014-01-01T23:59:59.000Z

83

Curvature Effect on the Capacitance of Electric Double Layers at Ionic Liquid/Onion-Like Carbon Interfaces  

SciTech Connect (OSTI)

Recent experiments have revealed that onion-like carbons (OLCs) offer high energy density and charging/discharging rates when used as the electrodes in supercapacitors. To understand the physical origin of this phenomenon, molecular dynamics simulations were performed for a room-temperature ionic liquid near idealized spherical OLCs with radii ranging from 0.356 to 1.223 nm. We find that the surface charge density increases almost linearly with the potential applied on electric double layers (EDLs) near OLCs. This leads to a nearly flat shape of the differential capacitance versus the potential, unlike the bell or camel shape observed on planar electrodes. Moreover, our simulations reveal that the capacitance of EDLs on OLCs increases with the curvature or as the OLC size decreases, in agreement with experimental observations. The curvature effect is explained by dominance of charge overscreening over a wide potential range and increased ion density per unit area of electrode surface as the OLC becomes smaller.

Feng, Guang [ORNL; Jiang, Deen [ORNL; Cummings, Peter T [ORNL

2012-01-01T23:59:59.000Z

84

Porous silicon membranes as ultrafiltration devices: a feasibility study  

E-Print Network [OSTI]

and several liquids, and the experimental results are compared to model predictions. Hexane, ethanol, and ethanol-water mixtures permeated the porous silicon membranes as liquids at pressure differentials greater than 100 psig. The membranes exhibited much... % HNOs and 4 parts water. However, the porous silicon layers became fragile during the etching and were easy to break. Experimental results for flow tests on selected samples after chemical etching are shown in the next section. 14 GAS FLOW TESTING...

Hong, Xiangrong

1993-01-01T23:59:59.000Z

85

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1992-01-01T23:59:59.000Z

86

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

87

Capture of particles in soft porous media , R. Hhler and O. Pitois  

E-Print Network [OSTI]

-height in the foam sample, using a thin glass capillary. The solid particles that we use are green fluorescent Cedex 2, France We investigate the capture of particles in soft porous media. Liquid foam constitutes foams can be considered as soft porous materials, exhibiting fine liquid channels between gas bubbles

Paris-Sud XI, Université de

88

HUMAN MACHINE INTERFACE (HMI) EVALUATION OF ROOMS TA-50-1-60/60A AT THE RADIOACTIVE LIQUID WASTE TREATMENT FACILITY (RLWTF)  

SciTech Connect (OSTI)

This effort addressed an evaluation of human machine interfaces (HMIs) in Room TA-50-1-60/60A of the Radioactive Liquid Waste Treatment Facility (RLWTF). The evaluation was performed in accordance with guidance outlined in DOE-STD-3009, DOE Standard Preparation Guide for U.S. Department of Energy Nonreactor Nuclear Facility Documented Safety Analyses, 2006 [DOE 2006]. Specifically, Chapter 13 of DOE 2006 highlights the 10 CFR 830, Nuclear Safety Management, 2012, [CFR 2012] and DOE G 421.1-2 [DOE 2001a] requirements as they relate to the human factors process and, in this case, the safety of the RLWTF. The RLWTF is a Hazard Category 3 facility and, consequently, does not have safety-class (SSCs). However, safety-significant SSCs are identified. The transuranic (TRU) wastewater tanks and associated piping are the only safety-significant SSCs in Rooms TA-50-1-60/60A [LANL 2010]. Hence, the human factors evaluation described herein is only applicable to this particular assemblage of tanks and piping.

Gilmore, Walter E. [Los Alamos National Laboratory; Stender, Kerith K. [Los Alamos National Laboratory

2012-08-29T23:59:59.000Z

89

4/28/2010 1Porous Pavements Porous Pavements  

E-Print Network [OSTI]

-- Sturdy, attractive & reliable · Porous concrete -- Quality depends on installer · Porous asphalt Park parking lot (2008) ·! Shoreview Porous Concrete Street project (2009) ·! Troy Burne Golf Course4/28/2010 1Porous Pavements Porous Pavements for Stormwater Restoration in Urban Environments Cliff

Minnesota, University of

90

Nanocrystals Grow from Liquid Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the Contributions andData andFleet TestAccounts andThe RoleAmes

91

Liquid Wall Chambers  

SciTech Connect (OSTI)

The key feature of liquid wall chambers is the use of a renewable liquid layer to protect chamber structures from target emissions. Two primary options have been proposed and studied: wetted wall chambers and thick liquid wall (TLW) chambers. With wetted wall designs, a thin layer of liquid shields the structural first wall from short ranged target emissions (x-rays, ions and debris) but not neutrons. Various schemes have been proposed to establish and renew the liquid layer between shots including flow-guiding porous fabrics (e.g., Osiris, HIBALL), porous rigid structures (Prometheus) and thin film flows (KOYO). The thin liquid layer can be the tritium breeding material (e.g., flibe, PbLi, or Li) or another liquid metal such as Pb. TLWs use liquid jets injected by stationary or oscillating nozzles to form a neutronically thick layer (typically with an effective thickness of {approx}50 cm) of liquid between the target and first structural wall. In addition to absorbing short ranged emissions, the thick liquid layer degrades the neutron flux and energy reaching the first wall, typically by {approx}10 x x, so that steel walls can survive for the life of the plant ({approx}30-60 yrs). The thick liquid serves as the primary coolant and tritium breeding material (most recent designs use flibe, but the earliest concepts used Li). In essence, the TLW places the fusion blanket inside the first wall instead of behind the first wall.

Meier, W R

2011-02-24T23:59:59.000Z

92

Hollow porous-wall glass microspheres for hydrogen storage  

DOE Patents [OSTI]

A porous wall hollow glass microsphere is provided having a diameter range of between 1 to 200 microns, a density of between 1.0 to 2.0 gm/cc, a porous-wall structure having wall openings defining an average pore size of between 10 to 1000 angstroms, and which contains therein a hydrogen storage material. The porous-wall structure facilitates the introduction of a hydrogen storage material into the interior of the porous wall hollow glass microsphere. In this manner, the resulting hollow glass microsphere can provide a membrane for the selective transport of hydrogen through the porous walls of the microsphere, the small pore size preventing gaseous or liquid contaminants from entering the interior of the hollow glass microsphere.

Heung, Leung K. (Aiken, SC); Schumacher, Ray F. (Aiken, SC); Wicks, George G. (Aiken, SC)

2010-02-23T23:59:59.000Z

93

Open-cell glass crystalline porous material  

DOE Patents [OSTI]

An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

Anshits, Alexander G. (Krasnoyarsk, RU); Sharonova, Olga M. (Krasnoyarsk, RU); Vereshchagina, Tatiana A. (Krasnoyarsk, RU); Zykova, Irina D. (Krasnoyarsk, RU); Revenko, Yurii A. (Zheleznogorsk, RU); Tretyakov, Alexander A. (Zheleznogorsk, RU); Aloy, Albert S. (Saint-Petersburg, RU); Lubtsev, Rem I. (Saint-Petersburg, RU); Knecht, Dieter A. (Idaho Falls, ID); Tranter, Troy J. (Idaho Falls, ID); Macheret, Yevgeny (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

94

668 / JOURNAL OF ENVIRONMENTAL ENGINEERING / JULY 1999 BACTERIAL TRANSPORT IN GAS-SPARGED POROUS MEDIUM  

E-Print Network [OSTI]

sparging a saturated porous medium produces a mobile water interface that was hypothesized to facilitate-aquifer remediation using bioaugmentation, more efficient meth- ods are needed to widely disperse pollutant-degrading bacteria in porous media. Under water-saturated condi- tions, bacteria readily adhere to soil particles

95

Ventilation of porous media  

DOE Patents [OSTI]

Methods are presented for distributing gases throughout the interstices of porous materials and removing volatile substances from the interstices of porous materials. Continuous oscillation of pressures and flows results in increased penetration of the interstices by flowing gases and increased transport of gaseous components out of the interstices. The invention is particularly useful in soil vapor extraction. 10 figures.

Neeper, D.A.

1994-02-22T23:59:59.000Z

96

Study of the simultaneous heat and mass transfer in two-dimensional porous media  

E-Print Network [OSTI]

in an unsaturated porous medium. A chronological discussion of the details of the review follows. Philip and De Vries[1] were the early investigators of the general topic of moisture migration in porous media with temperature gradients. The analysis revealed... for drying in a porous medium. The model accounted for the ca, pillary flow of the liquid phs, se and the diffusion of the vapor phase, including heat-conduction through the solid matrix. The coupled, non-linear governing equations, together...

Suh, Young Bae

1988-01-01T23:59:59.000Z

97

Water Rock Interaction [WRI 14] Macroscopic thermodynamics of interfaces at the water pore  

E-Print Network [OSTI]

they should be relevant. 2. Liquid-air interfacial curvature Capillary water in non-saturated porous system 7327, BP 36009, 45060 Orléans, France Abstract The possible role of liquid-air and solid-liquid (liquid-air concave curvature toward air), and curved solid as a function of pore sizes (solid-liquid

Boyer, Edmond

98

Preparation of asymmetric porous materials  

DOE Patents [OSTI]

A method for preparing an asymmetric porous material by depositing a porous material film on a flexible substrate, and applying an anisotropic stress to the porous media on the flexible substrate, where the anisotropic stress results from a stress such as an applied mechanical force, a thermal gradient, and an applied voltage, to form an asymmetric porous material.

Coker, Eric N. (Albuquerque, NM)

2012-08-07T23:59:59.000Z

99

Fabrication of porous silicon membranes  

E-Print Network [OSTI]

OF THE FILTER APPLICATION OF POROUS SILICON A. Density of Porous Silicon B. Stabilization of Porous Silicon Membranes C. Flow Test D. Porous Polycrystalline Silicon 54 58 62 65 vn TABLE OF CONTENTS (Continued) CHAPTER VI EXTENSIONS AND CONCLUSIONS... Membranes 13. Density Change of Porous Silicon at 125'C 14. Density Change oi' Porous Silicon at 250 C 15. Nitrogen Flow on a Porous Silicon Membrane Page 15 16 33 39 39 44 46 54 59 59 62 LIST OF FIGURES Figure 10. 12. 14. 17. 18. 19...

Yue, Wing Kong

1988-01-01T23:59:59.000Z

100

Surfactant Aggregates at Rough Solid-Liquid Interfaces Hannes C. Schniepp, Ho C. Shum, Dudley A. Saville, and Ilhan A. Aksay*  

E-Print Network [OSTI]

of surfactants at interfaces is important for many technical applications and industrial processes. The best approach so far to obtain detailed morphological information on surface aggregates-37,42-45 and mica.36,40,42 Amorphous silica that forms as a native oxide on highly smooth silicon has been the third

Aksay, Ilhan A.

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Porous material neutron detector  

DOE Patents [OSTI]

A neutron detector employs a porous material layer including pores between nanoparticles. The composition of the nanoparticles is selected to cause emission of electrons upon detection of a neutron. The nanoparticles have a maximum dimension that is in the range from 0.1 micron to 1 millimeter, and can be sintered with pores thereamongst. A passing radiation generates electrons at one or more nanoparticles, some of which are scattered into a pore and directed toward a direction opposite to the applied electrical field. These electrons travel through the pore and collide with additional nanoparticles, which generate more electrons. The electrons are amplified in a cascade reaction that occurs along the pores behind the initial detection point. An electron amplification device may be placed behind the porous material layer to further amplify the electrons exiting the porous material layer.

Diawara, Yacouba (Oak Ridge, TN); Kocsis, Menyhert (Venon, FR)

2012-04-10T23:59:59.000Z

102

Foams in porous media  

SciTech Connect (OSTI)

In 1978 a literature search on selective blocking of fluid flow in porous media was done by Professor S.S. Marsden and two of his graduate students, Tom Elson and Kern Huppy. This was presented as SUPRI Report No. TR-3 entitled ''Literature Preview of the Selected Blockage of Fluids in Thermal Recovery Projects.'' Since then a lot of research on foam in porous media has been done on the SUPRI project and a great deal of new information has appeared in the literature. Therefore we believed that a new, up-to-date search should be done on foam alone, one which would be helpful to our students and perhaps of interest to others. This is a chronological survey showing the development of foam flow, blockage and use in porous media, starting with laboratory studies and eventually getting into field tests and demonstrations. It is arbitrarily divided into five-year time periods. 81 refs.

Marsden, S.S.

1986-07-01T23:59:59.000Z

103

A model for enhanced fluid percolation in porous media by application of low-frequency elastic waves  

E-Print Network [OSTI]

, primarily in connection with the appli- cations to enhanced oil recovery (EOR) and remediation of nonaqueousA model for enhanced fluid percolation in porous media by application of low-frequency elastic can significantly enhance transport of nonaqueous phase liquids (NAPLs) in porous media. Our analyses

Beresnev, Igor

104

Excitations of superfluid 4 He in porous media: Aerogel and Vycor  

E-Print Network [OSTI]

Excitations of superfluid 4 He in porous media: Aerogel and Vycor O. Plantevin and B. Fa structure factor S(Q, ) and the elementary excitations of liquid 4 He immersed in aerogel and Vycor. In both and superfluid density, S(T), of liquid 4 He in aerogel and Vycor have been made over the past 30 years.1

Glyde, Henry R.

105

Novel fluctuations at constrained interfaces  

E-Print Network [OSTI]

In this study we try to answer the qustion : What happens when explicit constraints are introduced such that the low energy, long wavelength modes of a system are unavailable ? This question has assumed some importance in recent years due to the advent of nano technology and the growing use of nanometer scale devices and structures. In a small system, the size limits the scale of the fluctuations and makes it imperative for us to understand how the response of the system is altered in such a situation. In this thesis, this question is answered for the special case of interfacial fluctuations in two dimensions (2d). The energy of an interface between two phases in equilibrium is invariant with respect to translations perpendicular to the plane (or line in 2d) of the interface. We study the consequence of breaking this symmetry explicity using an external field gradient. One expects that since low energy excitations are suppressed, the interface would be flat and inert at all times. We show that surprisingly there are novel fluctuations and phenomena associated with such constrained interfaces which have static as well as dynamic consequences. The Ising interface on a square lattice is shown to undergo a multitude of structural transitions as a function of velocity and the orientation. Liquid solid interfaces show coherent addition and removal of atomic layers providing novel mechanisms of stress relaxation in a nanosized single crystal without defects. We study momentum and energy transfer across the liquid solid interface in the presence of this ``layering'' transition.

Abhishek Chaudhuri

2006-01-25T23:59:59.000Z

106

Lithium-based surfaces controlling fusion plasma behavior at the plasma-material interface  

SciTech Connect (OSTI)

The plasma-material interface and its impact on the performance of magnetically confined thermonuclear fusion plasmas are considered to be one of the key scientific gaps in the realization of nuclear fusion power. At this interface, high particle and heat flux from the fusion plasma can limit the material's lifetime and reliability and therefore hinder operation of the fusion device. Lithium-based surfaces are now being used in major magnetic confinement fusion devices and have observed profound effects on plasma performance including enhanced confinement, suppression and control of edge localized modes (ELM), lower hydrogen recycling and impurity suppression. The critical spatial scale length of deuterium and helium particle interactions in lithium ranges between 5-100 nm depending on the incident particle energies at the edge and magnetic configuration. Lithium-based surfaces also range from liquid state to solid lithium coatings on a variety of substrates (e.g., graphite, stainless steel, refractory metal W/Mo/etc., or porous metal structures). Temperature-dependent effects from lithium-based surfaces as plasma facing components (PFC) include magnetohydrodynamic (MHD) instability issues related to liquid lithium, surface impurity, and deuterium retention issues, and anomalous physical sputtering increase at temperatures above lithium's melting point. The paper discusses the viability of lithium-based surfaces in future burning-plasma environments such as those found in ITER and DEMO-like fusion reactor devices.

Allain, Jean Paul; Taylor, Chase N. [School of Nuclear Engineering, Purdue University, 400 Central Avenue, West Lafayette, Indiana 47907 (United States)

2012-05-15T23:59:59.000Z

107

Progress in Creating Stabilized Gas Layers in Flowing Liquid Mercury  

SciTech Connect (OSTI)

The Spallation Neutron Source (SNS) facility in Oak Ridge, Tennessee uses a liquid mercury target that is bombarded with protons to produce a pulsed neutron beam for materials research and development. In order to mitigate expected cavitation damage erosion (CDE) of the containment vessel, a two-phase flow arrangement of the target has been proposed and was earlier proven to be effective in significantly reducing CDE in non-prototypical target bodies. This arrangement involves covering the beam "window", through which the high-energy proton beam passes, with a protective layer of gas. The difficulty lies in establishing a stable gas/liquid interface that is oriented vertically with the window and holds up to the strong buoyancy force and the turbulent mercury flow field. Three approaches to establishing the gas wall have been investigated in isothermal mercury/gas testing on a prototypical geometry and flow: (1) free gas layer approach, (2) porous wall approach, and (3) surface-modified approach. The latter two of these approaches show success in that a stabilized gas layer is produced. Both of these successful approaches capitalize on the high surface energy of liquid mercury by increasing the surface area of the solid wall, thus increasing gas hold up at the wall. In this paper, a summary of these experiments and findings is presented as well as a description of the path forward toward incorporating the stabilized gas layer approach into a feasible gas/mercury SNS target design.

Wendel, Mark W [ORNL; Felde, David K [ORNL; Riemer, Bernie [ORNL; Abdou, Ashraf A [ORNL; D'Urso, Brian R [ORNL; West, David L [ORNL

2009-01-01T23:59:59.000Z

108

Nanoscale thermal transport and the thermal conductance of interfaces  

E-Print Network [OSTI]

-8 2008 #12;Er-fiber laser system, UIUC Nov. 2007 #12;Solid-liquid interfaces: Two approaches · Transient-wide: ­ thermal interface materials ­ so-called "nanofluids" (suspensions in liquids) ­ polymer composites absorption depends on temperature of the nanotube · Assume heat capacity is comparable to graphite · Cooling

Braun, Paul

109

Radiative heat transfer in porous uranium dioxide  

SciTech Connect (OSTI)

Due to low thermal conductivity and high emissivity of UO{sub 2}, it has been suggested that radiative heat transfer may play a significant role in heat transfer through pores of UO{sub 2} fuel. This possibility was computationally investigated and contribution of radiative heat transfer within pores to overall heat transport in porous UO{sub 2} quantified. A repeating unit cell was developed to model approximately a porous UO{sub 2} fuel system, and the heat transfer through unit cells representing a wide variety of fuel conditions was calculated using a finite element computer program. Conduction through solid fuel matrix as wekk as pore gas, and radiative exchange at pore surface was incorporated. A variety of pore compositions were investigated: porosity, pore size, shape and orientation, temperature, and temperature gradient. Calculations were made in which pore surface radiation was both modeled and neglected. The difference between yielding the integral contribution of radiative heat transfer mechanism to overall heat transport. Results indicate that radiative component of heat transfer within pores is small for conditions representative of light water reactor fuel, typically less than 1% of total heat transport. It is much larger, however, for conditions present in liquid metal fast breeder reactor fuel; during restructuring of this fuel type early in life, the radiative heat transfer mode was shown to contribute as much as 10-20% of total heat transport in hottest regions of fuel.

Hayes, S.L. [Texas A and M Univ., College Station, TX (United States)] [Texas A and M Univ., College Station, TX (United States)

1992-12-01T23:59:59.000Z

110

Liquid-Liquid Extraction Processes  

E-Print Network [OSTI]

Liquid-liquid extraction is the separation of one or more components of a liquid solution by contact with a second immiscible liquid called the solvent. If the components in the original liquid solution distribute themselves differently between...

Fair, J. R.; Humphrey, J. L.

1983-01-01T23:59:59.000Z

111

Fabricating solid carbon porous electrodes from powders  

DOE Patents [OSTI]

Fabrication of conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive dionization, and waste treatment. Electrodes fabricated from low surface area (<50 m.sup.2 /gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon compositives with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to be high surface area carbons, fuel cell electrodes can be produced.

Kaschmitter, James L. (Pleasanton, CA); Tran, Tri D. (Livermore, CA); Feikert, John H. (Livermore, CA); Mayer, Steven T. (San Leandro, CA)

1997-01-01T23:59:59.000Z

112

Fabricating solid carbon porous electrodes from powders  

DOE Patents [OSTI]

Fabrication is described for conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive deionization, and waste treatment. Electrodes fabricated from low surface area (<50 m{sup 2}/gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon composites with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to high surface area carbons, fuel cell electrodes can be produced. 1 fig.

Kaschmitter, J.L.; Tran, T.D.; Feikert, J.H.; Mayer, S.T.

1997-06-10T23:59:59.000Z

113

Experimental and Modeling Studies of Two-Phase Flow in Porous Media and Its Effects on the Performance of a PEM Fuel Cell  

E-Print Network [OSTI]

An experimental investigation was conducted to study the two-phase flow properties of porous media used in proton exchange membrane (PEM) fuel cells. The liquid and gas phase relative permeability of porous media used in PEM fuel cells was measured...

Wang, Xuhai

2010-01-01T23:59:59.000Z

114

Mullite/Alumina Mixtures for Use as Porous Matrices in Oxide Fiber Composites  

E-Print Network [OSTI]

ceramic composites. Conditions for the deflection of a matrix crack at a fiber-matrix interface are used particle mixtures of mullite and alumina are assessed as candidate matrixes for use in porous matrix to identify the combinations of modulus and toughness of the fibers and the matrix for which damage

Zok, Frank

115

Nonequilibrium Thermodynamics of Porous Electrodes  

E-Print Network [OSTI]

We reformulate and extend porous electrode theory for non-ideal active materials, including those capable of phase transformations. Using principles of non-equilibrium thermodynamics, we relate the cell voltage, ionic ...

Ferguson, Todd Richard

116

Porous substrates filled with nanomaterials  

DOE Patents [OSTI]

A composition comprising: at least one porous carbon monolith, such as a carbon aerogel, comprising internal pores, and at least one nanomaterial, such as carbon nanotubes, disposed uniformly throughout the internal pores. The nanomaterial can be disposed in the middle of the monolith. In addition, a method for making a monolithic solid with both high surface area and good bulk electrical conductivity is provided. A porous substrate having a thickness of 100 microns or more and comprising macropores throughout its thickness is prepared. At least one catalyst is deposited inside the porous substrate. Subsequently, chemical vapor deposition is used to uniformly deposit a nanomaterial in the macropores throughout the thickness of the porous substrate. Applications include electrical energy storage, such as batteries and capacitors, and hydrogen storage.

Worsley, Marcus A.; Baumann, Theodore F.; Satcher, Jr., Joe H.; Stadermann, Michael

2014-08-19T23:59:59.000Z

117

Filter casting nanoscale porous materials  

DOE Patents [OSTI]

A method of producing nanoporous material includes the steps of providing a liquid, providing nanoparticles, producing a slurry of the liquid and the nanoparticles, removing the liquid from the slurry, and producing monolith.

Hayes, Joel Ryan; Nyce, Gregory Walker; Kuntz, Jushua David

2013-12-10T23:59:59.000Z

118

Scaling of bubble growth in a porous medium. Topical report  

SciTech Connect (OSTI)

Processes involving liquid-to-gas phase change in porous media are routinely encountered, for example in the recovery of oil, geothermal processes, nuclear waste disposal or enhanced heat transfer. They involve diffusion (and convection) in the pore space, driven by an imposed supersaturation in pressure or temperature. Phase change proceeds by nucleation and phase growth. Depending on pore surface roughness, a number of nucleation centers exist, thus phase growth occurs from a multitude of clusters. Contrary to growth in the bulk or in a Hele-Shaw cell, however, growth patterns in porous media are disordered and not compact. As in immiscible displacements, they reflect the underlying pore microstructure. The competition between multiple clusters is also different from the bulk. For example, cluster growth may be controlled by a combination of diffusion (e.g. Laplace equation in the quasi-static case) with percolation. Novel growth patterns axe expected from this competition. While multiple cluster growth is important, the simpler problem of single-bubble growth is still not well understood. In this section, we focus on the growth of a single bubble, subject to a fixed far-field supersaturation (e.g. by lowering the pressure in a supersaturated solution or by raising the temperature in a. superheated liquid). Our emphasis is on deriving a scaling theory for growth at conditions of quasi-static diffusion, guided by recent experimental observations. Visualization of bubble growth in model porous media was recently conducted using 2-D etched-glass micromodels.

Satik, C.; Yortsos, Y.; Li, X. [Univ. of Southern California, Los Angeles, CA (United States). Dept. of Chemical Engineering

1995-07-01T23:59:59.000Z

119

Photophysics and photoredox processes at liquid-liquid interfaces  

SciTech Connect (OSTI)

This report is divided into four sections: (1) Recent work on polymers with covalently bound chromophores, primarily involving triplet state electron transfer quenching; (2) Pyrene and pyrene butyric acid adsorbed onto polystyrene latexes (microspheres); (3) Adsorption and micellization of amphiphilic block polymers with chromophores at the junction between the hydrophobic and hydrophilic part; (4) Adsorption of alternating polymers with grafted combs'' to improve adsorption onto a hydrophobic surface.

Webber, S.E.

1992-09-01T23:59:59.000Z

120

Experimentally Determined Interfacial Area Between Immiscible Fluids in Porous Media  

SciTech Connect (OSTI)

When multiple fluids flow through a porous medium, the interaction between the fluid interfaces can be of great importance. While this is widely recognized in practical applications, numerical models often disregard interactios between discrete fluid phases due to the computational complexity. And rightly so, for this level of detail is well beyond most extended Darcy Law relationships. A new model of two-phase flow including the interfacial area has been proposed by Hassarizadeh and Gray based upon thermodynamic principles. A version of this general equation set has been implemented by Nessner and Hassarizadeh. Many of the interfacial parameters required by this equation set have never been determined from experiments. The work presented here is a description of how the interfacial area, capillary pressure, interfacial velocity and interfacial permeability from two-phase flow experiments in porous media experiments can be used to determine the required parameters. This work, while on-going, has shown the possibility of digitizing images within translucent porous media and identifying the location and behavior of interfaces under dynamic conditions. Using the described methods experimentally derived interfacial functions to be used in larger scale simulations are currently being developed. In summary, the following conclusions can be drawn: (1) by mapping a pore-throat geometry onto an image of immiscible fluid flow, the saturation of fluids and the individual interfaces between the fluids can be identified; (2) the resulting saturation profiles of the low velocity drainage flows used in this study are well described by an invasion percolation fractal scaling; (3) the interfacial area between fluids has been observed to increase in a linear fashion during the initial invasion of the non-wetting fluid; and (4) the average capillary pressure within the entire cell and representative elemental volumes were observed to plateau after a small portion of the volume was invaded.

Crandall, Dustin; Niessner, J; Hassanizadeh, S.M; Smith, Duane

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Foam Transport in Porous Media - A Review  

SciTech Connect (OSTI)

Amendment solutions with or without surfactants have been used to remove contaminants from soil. However, it has drawbacks such that the amendment solution often mobilizes the plume, and its movement is controlled by gravity and preferential flow paths. Foam is an emulsion-like, two-phase system in which gas cells are dispersed in a liquid and separated by thin liquid films called lamellae. Potential advantages of using foams in sub-surface remediation include providing better control on the volume of fluids injected, uniformity of contact, and the ability to contain the migration of contaminant laden liquids. It is expected that foam can serve as a carrier of amendments for vadose zone remediation, e.g., at the Hanford Site. As part of the U.S. Department of Energy’s EM-20 program, a numerical simulation capability will be added to the Subsurface Transport Over Multiple Phases (STOMP) flow simulator. The primary purpose of this document is to review the modeling approaches of foam transport in porous media. However, as an aid to understanding the simulation approaches, some experiments under unsaturated conditions and the processes of foam transport are also reviewed. Foam may be formed when the surfactant concentration is above the critical micelle concentration. There are two main types of foams – the ball foam (microfoam) and the polyhedral foam. The characteristics of bulk foam are described by the properties such as foam quality, texture, stability, density, surface tension, disjoining pressure, etc. Foam has been used to flush contaminants such as metals, organics, and nonaqueous phase liquids from unsaturated soil. Ball foam, or colloidal gas aphrons, reportedly have been used for soil flushing in contaminated site remediation and was found to be more efficient than surfactant solutions on the basis of weight of contaminant removed per gram of surfactant. Experiments also indicate that the polyhedral foam can be used to enhance soil remediation. The transport of foam in porous media is complicated in that the number of lamellae present governs flow characteristics such as viscosity, relative permeability, fluid distribution, and interactions between fluids. Hence, foam is a non-Newtonian fluid. During transport, foam destruction and formation occur. The net result of the two processes determines the foam texture (i.e., bubble density). Some of the foam may be trapped during transport. According to the impacts of the aqueous and gas flow rates, foam flow generally has two regimes – weak and strong foam. There is also a minimum pressure gradient to initiate foam flow and a critical capillary for foam to be sustained. Similar to other fluids, the transport of foam is described by Darcy’s law with the exception that the foam viscosity is variable. Three major approaches to modeling foam transport in porous media are the empirical, semi-empirical, and mechanistic methods. Mechanistic approaches can be complete in principal but may be difficult to obtain reliable parameters, whereas empirical and semi-empirical approaches can be limited by the detail used to describe foam rheology and mobility. Mechanistic approaches include the bubble population-balance model, the network/percolation theory, the catastrophe theory, and the filtration theory. Among these methods, all were developed for modeling polyhedral foam with the exception that the method based on the filtration theory was for the ball foam (microfoam).

Zhang, Z. F.; Freedman, Vicky L.; Zhong, Lirong

2009-11-11T23:59:59.000Z

122

Spiers Memorial Lecture Recent experimental advances in studies of liquid/liquid  

E-Print Network [OSTI]

complicated processes such as molecular transport across cell membranes. A variety of techniques have been on the interaction of a hydrophobic surface with water, and ion and solute transport across these and other liquid/hydrophilic properties of liquid/ liquid interfaces. In biological systems, protein folding and membrane formation rely

Richmond, Geraldine L.

123

Deformation of acoustically transparent fluid interfaces by the acoustic radiation pressure  

E-Print Network [OSTI]

in v/c, (v is the fluid velocity amplitude, c the sound speed), the time-averaged Lagrangian pressure.g., Rayleigh-Taylor) Abstract ­ We experimentally study the deformations of liquid-liquid interfaces induced

Paris-Sud XI, Université de

124

Process of preparing tritiated porous silicon  

DOE Patents [OSTI]

A process of preparing tritiated porous silicon is described in which porous silicon is equilibrated with a gaseous vapor containing HT/T{sub 2} gas in a diluent for a time sufficient for tritium in the gas phase to replace hydrogen present in the pore surfaces of the porous silicon. 1 fig.

Tam, S.W.

1997-02-18T23:59:59.000Z

125

Process of preparing tritiated porous silicon  

DOE Patents [OSTI]

A process of preparing tritiated porous silicon in which porous silicon is equilibrated with a gaseous vapor containing HT/T.sub.2 gas in a diluent for a time sufficient for tritium in the gas phase to replace hydrogen present in the pore surfaces of the porous silicon.

Tam, Shiu-Wing (Downers Grove, IL)

1997-01-01T23:59:59.000Z

126

Metal recovery from porous materials  

DOE Patents [OSTI]

A method for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF.sub.4 and HNO.sub.3 and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200.degree. C. The porous material can be pulverized before immersion to further increase the leach rate.

Sturcken, Edward F. (P.O. Box 900, Isle of Palms, SC 29451)

1992-01-01T23:59:59.000Z

127

Method of preparing thin porous sheets of ceramic material  

DOE Patents [OSTI]

A method of forming thin porous sheets of ceramic material for use as electrodes or other components in a molten carbonate fuel cell is disclosed. The method involves spray drying a slurry of fine ceramic particles in liquid carrier to produce generally spherical agglomerates of high porosity and a rough surface texture. The ceramic particles may include the electrode catalyst and the agglomerates can be calcined to improve mechanical strength. After slurrying with suitable volatile material and binder tape casting is used to form sheets that are sufficiently strong for further processing and handling in the assembly of a high temperature fuel cell.

Swarr, Thomas E. (South Windsor, CT); Nickols, Richard C. (East Hartford, CT); Krasij, Myron (Avon, CT)

1987-03-24T23:59:59.000Z

128

ON A PRIORI ERROR ESTIMATES FOR A TWO-PHASE MOVING-INTERFACE PROBLEM WITH KINETIC CONDITION  

E-Print Network [OSTI]

reaction-slow transport scenarios in porous media is to employ a so-called moving-interface model-interface model with kinetic condition arising in the modeling of concrete carbonation. CO2 and humidity attack concrete samples and reduce their protection to corrosion (i.e. the alkalinity) via the apparently harmless

Eindhoven, Technische Universiteit

129

Metal recovery from porous materials  

DOE Patents [OSTI]

The present invention relates to recovery of metals. More specifically, the present invention relates to the recovery of plutonium and other metals from porous materials using microwaves. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

Sturcken, E.F.

1991-01-01T23:59:59.000Z

130

Water Dynamics at Rough Interfaces  

E-Print Network [OSTI]

We use molecular dynamics computer simulations and nuclear magnetic resonance experiments to investigate the dynamics of water at interfaces of molecular roughness and low mobility. We find that, when approaching such interfaces, the structural relaxation of water, i.e., the $\\alpha$ process, slows down even when specific attractive interactions are absent. This prominent effect is accompanied by a smooth transition from Vogel to Arrhenius temperature dependence and by a growing importance of jump events. Consistently, at protein surfaces, deviations from Arrhenius behavior are weak when free water does not exist. Furthermore, in nanoporous silica, a dynamic crossover of liquid water occurs when a fraction of solid water forms near 225 K and, hence, the liquid dynamics changes from bulk-like to interface-dominated. At sufficiently low temperatures, water exhibits a quasi-universal $\\beta$ process, which is characterized by an activation energy of $E_a\\!=\\!0.5$ eV and involves anisotropic reorientation about large angles. As a consequence of its large amplitude, the faster $\\beta$ process destroys essentially all orientational correlation, rendering observation of a possible slower $\\alpha$ process difficult in standard experiments. Nevertheless, we find indications for the existence of structural relaxation down to a glass transition of interfacial water near 185 K. Hydrated proteins show a highly restricted backbone motion with an amplitude, which decreases upon cooling and vanishes at comparable temperatures, providing evidence for a high relevance of water rearrangements in the hydration shell for secondary protein relaxations.

Markus Rosenstihl; Kerstin Kämpf; Felix Klameth; Matthias Sattig; Michael Vogel

2014-07-21T23:59:59.000Z

131

Web Browser Interface (WBUI)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OSCARS and Future Tech OSCARS Standard and Open Grid Forum OSCARS Developers Community Web Browser Interface (WBUI) Web Service Interface (API) Read More... Fasterdata IPv6...

132

Web Service Interface (API)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OSCARS and Future Tech OSCARS Standard and Open Grid Forum OSCARS Developers Community Web Browser Interface (WBUI) Web Service Interface (API) Read More... Fasterdata IPv6...

133

Drying by Cavitation and Poroelastic Relaxations in Porous Media with Macroscopic Pores Connected by Nanoscale Throats  

E-Print Network [OSTI]

We investigate the drying dynamics of porous media with two pore diameters separated by several orders of magnitude. Nanometer-sized pores at the edge of our samples prevent air entry, while drying proceeds by heterogeneous nucleation of vapor bubbles (cavitation) in the liquid in micrometer-sized voids within the sample. We show that the dynamics of cavitation and drying are set by the interplay of the deterministic poroelastic mass transport in the porous medium and the stochastic nucleation process. Spatio-temporal patterns emerge in this unusual reaction-diffusion system, with temporal oscillations in the drying rate and variable roughness of the drying front.

Olivier Vincent; David A. Sessoms; Erik J. Huber; Jules Guioth; Abraham D. Stroock

2014-09-30T23:59:59.000Z

134

Interface deformations affect the orientation transition of magnetic ellipsoidal particles adsorbed at fluid-fluid interfaces  

E-Print Network [OSTI]

Manufacturing new soft materials with specific optical, mechanical and magnetic properties is a significant challenge. Assembling and manipulating colloidal particles at fluid interfaces is a promising way to make such materials. We use lattice-Boltzmann simulations to investigate the response of magnetic ellipsoidal particles adsorbed at liquid-liquid interfaces to external magnetic fields. We provide further evidence for the first-order orientation phase transition predicted by Bresme and Faraudo [Journal of Physics: Condensed Matter 19 (2007), 375110]. We show that capillary interface deformations around the ellipsoidal particle significantly affect the tilt-angle of the particle for a given dipole-field strength, altering the properties of the orientation transition. We propose scaling laws governing this transition, and suggest how to use these deformations to facilitate particle assembly at fluid-fluid interfaces.

Gary B. Davies; Timm Krüger; Peter V. Coveney; Jens Harting; Fernando Bresme

2014-10-28T23:59:59.000Z

135

19 APRIL 2002 VOL 296 SCIENCE www.sciencemag.org478 the structure of the liquid could be gained  

E-Print Network [OSTI]

from the liquid at the solid-liquid alumina interface. The work by Donnelly et al. (1) follows of TEM in the study of liquids in contact with solids. To- gether with the works by Howe (15) and Sasaki. Experimental elucidation of the atomic structure of the liquid-solid interface is in- herently difficult

Reif, John H.

136

COMPARISON OF SINGLE AND MULTI GEOSYNTHETIC AND SOIL INTERFACE TESTS  

E-Print Network [OSTI]

, geosynthetic clay liner (GCL)/geomembrane, and soil/geosynthetic interfaces. This comparison shows an agreement and Choi 2004). A composite liner system consisting of multiple geosynthetic components, Liquid CollectionCOMPARISON OF SINGLE AND MULTI GEOSYNTHETIC AND SOIL INTERFACE TESTS Timothy D. Stark1 , Fawad S

137

Corrosion protected, multi-layer fuel cell interface  

DOE Patents [OSTI]

An improved interface configuration for use between adjacent elements of a fuel cell stack. The interface is impervious to gas and liquid and provides resistance to corrosion by the electrolyte of the fuel cell. The multi-layer configuration for the interface comprises a non-cupreous metal-coated metallic element to which is film-bonded a conductive layer by hot pressing a resin therebetween. The multi-layer arrangement provides bridging electrical contact.

Feigenbaum, Haim (Ramat Ilan, IL); Pudick, Sheldon (Sayreville, NJ); Wang, Chiu L. (Edison, NJ)

1986-01-01T23:59:59.000Z

138

Centrifuge Techniques and Apparatus for Transport Experiments in Porous Media  

SciTech Connect (OSTI)

This paper describes experimental approaches and apparatus that we have developed to study solute and colloid transport in porous media using Idaho National Laboratory's 2-m radius centrifuge. The ex-perimental techniques include water flux scaling with applied acceleration at the top of the column and sub-atmospheric pressure control at the column base, automation of data collection, and remote experimental con-trol over the internet. These apparatus include a constant displacement piston pump, a custom designed liquid fraction collector based on switching valve technology, and modified moisture monitoring equipment. Suc-cessful development of these experimental techniques and equipment is illustrated through application to transport of a conservative tracer through unsaturated sand column, with centrifugal acceleration up to 40 gs. Development of such experimental equipment that can withstand high accelerations enhances the centrifuge technique to conduct highly controlled unsaturated solute/colloid transport experiments and allows in-flight liquid sample collection of the effluent.

Earl D. Mattson; Carl D. Paler; Robert W. Smith; Markus Flury

2010-06-01T23:59:59.000Z

139

Web Interface Call Simulator  

E-Print Network [OSTI]

Web Interface Call Simulator Stage Description Web Interface for VoIP Call Simulator Net) Version 1.0 ­ 3/09/2012 Page 1 of 6 #12;Web Interface Call Simulator Version 1.0 ­ 3/09/2012 Page 2 of 6 #12;Web Interface Call Simulator Document Control Version Date Notes 1.0 25/8/2012 Reviewed

Ernst, Damien

140

POROUS WALL, HOLLOW GLASS MICROSPHERES  

SciTech Connect (OSTI)

Hollow Glass Microspheres (HGM) is not a new technology. All one has to do is go to the internet and Google{trademark} HGM. Anyone can buy HGM and they have a wide variety of uses. HGM are usually between 1 to 100 microns in diameter, although their size can range from 100 nanometers to 5 millimeters in diameter. HGM are used as lightweight filler in composite materials such as syntactic foam and lightweight concrete. In 1968 a patent was issued to W. Beck of the 3M{trademark} Company for 'Glass Bubbles Prepared by Reheating Solid Glass Particles'. In 1983 P. Howell was issued a patent for 'Glass Bubbles of Increased Collapse Strength' and in 1988 H. Marshall was issued a patent for 'Glass Microbubbles'. Now Google{trademark}, Porous Wall, Hollow Glass Microspheres (PW-HGMs), the key words here are Porous Wall. Almost every article has its beginning with the research done at the Savannah River National Laboratory (SRNL). The Savannah River Site (SRS) where SRNL is located has a long and successful history of working with hydrogen and its isotopes for national security, energy, waste management and environmental remediation applications. This includes more than 30 years of experience developing, processing, and implementing special ceramics, including glasses for a variety of Department of Energy (DOE) missions. In the case of glasses, SRS and SRNL have been involved in both the science and engineering of vitreous or glass based systems. As a part of this glass experience and expertise, SRNL has developed a number of niches in the glass arena, one of which is the development of porous glass systems for a variety of applications. These porous glass systems include sol gel glasses, which include both xerogels and aerogels, as well as phase separated glass compositions, that can be subsequently treated to produce another unique type of porosity within the glass forms. The porous glasses can increase the surface area compared to 'normal glasses of a 1 to 2 order of magnitude, which can result in unique properties in areas such as hydrogen storage, gas transport, gas separations and purifications, sensors, global warming applications, new drug delivery systems and so on. One of the most interesting porous glass products that SRNL has developed and patented is Porous Wall, Hollow Glass Microspheres (PW-HGMs) that are being studied for many different applications. The European Patent Office (EPO) just recently notified SRS that the continuation-in-part patent application for the PW-HGMs has been accepted. The original patent, which was granted by the EPO on June 2, 2010, was validated in France, Germany and the United Kingdom. The microspheres produced are generally in the range of 2 to 100 microns, with a 1 to 2 micron wall. What makes the SRNL microspheres unique from all others is that the team in Figure 1 has found a way to induce and control porosity through the thin walls on a scale of 100 to 3000 {angstrom}. This is what makes the SRNL HW-HGMs one-of-a-kind, and is responsible for many of their unique properties and potential for various applications, including those in tritium storage, gas separations, H-storage for vehicles, and even a variety of new medical applications in the areas of drug delivery and MRI contrast agents. SRNL Hollow Glass Microspheres, and subsequent, Porous Wall, Hollow Glass Microspheres are fabricated using a flame former apparatus. Figure 2 is a schematic of the apparatus.

Sexton, W.

2012-06-30T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Metal recovery from porous materials  

DOE Patents [OSTI]

A method is described for recovering plutonium and other metals from materials by leaching comprising the steps of incinerating the materials to form a porous matrix as the residue of incineration, immersing the matrix into acid in a microwave-transparent pressure vessel, sealing the pressure vessel, and applying microwaves so that the temperature and the pressure in the pressure vessel increase. The acid for recovering plutonium can be a mixture of HBF[sub 4] and HNO[sub 3] and preferably the pressure is increased to at least 100 PSI and the temperature to at least 200 C. The porous material can be pulverized before immersion to further increase the leach rate.

Sturcken, E.F.

1992-10-13T23:59:59.000Z

142

Transient-Liquid-Phase and Liquid-Film-Assisted Joining ofCeramics  

SciTech Connect (OSTI)

Two joining methods, transient-liquid-phase (TLP) joining and liquid-film-assisted joining (LFAJ), have been used to bond alumina ceramics. Both methods rely on multilayer metallic interlayers designed to form thin liquid films at reduced temperatures. The liquid films either disappear by interdiffusion (TLP) or promote ceramic/metal interface formation and concurrent dewetting of the liquid film (LFAJ). Progress on extending the TLP method to lower temperatures by combining low-melting-point (<450 C) liquids and commercial reactive-metal brazes is described. Recent LFAJ work on joining alumina to niobium using copper films is presented.

Sugar, Joshua D.; McKeown, Joseph T.; Akashi, Takaya; Hong, SungM.; Nakashima, Kunihiko; Glaeser, Andreas M.

2005-02-09T23:59:59.000Z

143

Activation of porous MOF materials  

DOE Patents [OSTI]

A method for the treatment of solvent-containing MOF material to increase its internal surface area involves introducing a liquid into the MOF in which liquid the solvent is miscible, subjecting the MOF to supercritical conditions for a time to form supercritical fluid, and releasing the supercritical conditions to remove the supercritcal fluid from the MOF. Prior to introducing the liquid into the MOF, occluded reaction solvent, such as DEF or DMF, in the MOF can be exchanged for the miscible solvent.

Hupp, Joseph T; Farha, Omar K

2014-04-01T23:59:59.000Z

144

Activation of porous MOF materials  

DOE Patents [OSTI]

A method for the treatment of solvent-containing MOF material to increase its internal surface area involves introducing a liquid into the MOF in which liquid the solvent is miscible, subjecting the MOF to supercritical conditions for a time to form supercritical fluid, and releasing the supercritical conditions to remove the supercritical fluid from the MOF. Prior to introducing the liquid into the MOF, occluded reaction solvent, such as DEF or DMF, in the MOF can be exchanged for the miscible solvent.

Hupp, Joseph T; Farha, Omar K

2013-04-23T23:59:59.000Z

145

Three-Dimensional Reconstruction of Porous LSCF Cathodes D. Gostovic,*,z  

E-Print Network [OSTI]

Three-Dimensional Reconstruction of Porous LSCF Cathodes D. Gostovic,*,z J. R. Smith,* D. P In this initial study the electrochemically active region of a La0.8Sr0.2Co0.2Fe0.8O3- LSCF cathode an actual three-dimensional 3D model of a La0.8Sr0.2Co0.2Fe0.8O3- LSCF cathode and its interface

Florida, University of

146

Gas sensor incorporating a porous framework  

DOE Patents [OSTI]

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

Yaghi, Omar M; Czaja, Alexander U; Wang, Bo; Galatsis, Kosmas; Wang, Kang L; Furukawa, Hiroyasu

2014-05-27T23:59:59.000Z

147

Gas sensor incorporating a porous framework  

SciTech Connect (OSTI)

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; Furukawa, Hiroyasu; Galatsis, Kosmas; Wang, Kang L.

2013-07-09T23:59:59.000Z

148

Monte Carlo simulation methodology of the ghost interface theory for the planar surface tension  

E-Print Network [OSTI]

Monte Carlo simulation methodology of the ghost interface theory for the planar surface tension October 2003 A novel ``ghost interface'' expression for the surface tension of a planar liquid coexisting phases. Results generated from the ghost interface theory for the surface tension are presented

Attard, Phil

149

Infrared Spectroscopy and Optical Constants of Porous Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Spectroscopy and Optical Constants of Porous Amorphous Solid Water. Infrared Spectroscopy and Optical Constants of Porous Amorphous Solid Water. Abstract: Reflection-absorption...

150

Determination of Water Saturation in Relatively Dry Porous Media...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water Saturation in Relatively Dry Porous Media Using Gas-phase Tracer Tests. Determination of Water Saturation in Relatively Dry Porous Media Using Gas-phase Tracer Tests....

151

Removal of Carbon Tetrachloride from a Layered Porous Medium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Tetrachloride from a Layered Porous Medium by Means of Soil Vapor Extraction Enhanced by Desiccation and Water Removal of Carbon Tetrachloride from a Layered Porous Medium...

152

Removal of carbon tetrachloride from a layered porous medium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carbon tetrachloride from a layered porous medium by means of soil vapor extraction enhanced by desiccation and water Removal of carbon tetrachloride from a layered porous medium...

153

Hierarchically Porous Graphene as a Lithium-Air Battery Electrode...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hierarchically Porous Graphene as a Lithium-Air Battery Electrode. Hierarchically Porous Graphene as a Lithium-Air Battery Electrode. Abstract: Functionalized graphene sheets (FGS)...

154

ZnO/porous-Si and TiO{sub 2}/porous-Si nanocomposite nanopillars  

SciTech Connect (OSTI)

Porous Si nanopillar arrays are used as templates for atomic layer deposition of ZnO and TiO{sub 2}, and thus, ZnO/porous-Si and TiO{sub 2}/porous-Si nanocomposite nanopillars are fabricated. The diffusion of the precursor molecules into the inside of the porous structure occurs via Knudsen diffusion and is strongly limited by the small pore size. The luminescence of the ZnO/porous-Si nanocomposite nanopillars is also investigated, and the optical emission can be changed and even quenched after a strong plasma treatment. Such nanocomposite nanopillars are interesting for photocatalysis and sensors.

Wang, Dong, E-mail: dong.wang@tu-ilmenau.de; Yan, Yong; Schaaf, Peter [Chair Materials for Electronics, Institute of Materials Engineering and Institute of Micro- and Nanotechnologies MacroNano, TU Ilmenau, Gustav-Kirchhoff-Str. 5, 98693 Ilmenau (Germany); Sharp, Thomas [Oxford Instruments Plasma Technology Ltd., Yatton, Bristol BS49 4AP (United Kingdom); Schönherr, Sven; Ronning, Carsten [Institute for Solid State Physics, Friedrich Schiller University Jena, Max-Wien-Platz 1, 07743 Jena (Germany); Ji, Ran [SUSS MicroTec Lithography GmbH, Schleissheimer Str. 90, 85748 Garching (Germany)

2015-01-01T23:59:59.000Z

155

Basic research needs and opportunities on interfaces in solar materials  

SciTech Connect (OSTI)

The workshop on research needs and recommended research programs on interfaces in solar energy conversion devices was held June 30-July 3, 1980. The papers deal mainly with solid-solid, solid-liquid, and solid-gas interfaces, sometimes involving multilayer solid-solid interfaces. They deal mainly with instrumental techniques of studying these interfaces so they can be optimized, so they can be fabricated with quality control and so changes with time can be forecast. The latter is required because a long lifetime (20 yrs is suggested) is necessary for economic reasons. Fifteen papers have been entered individually into EDB and ERA. (LTN)

Czanderna, A.W.; Gottschall, R.J. (eds.)

1981-04-01T23:59:59.000Z

156

NONLINEAR OPTICS AT INTERFACES  

E-Print Network [OSTI]

N. Bloembergen, Nonlinear Optics (W. A. Benjamin, 1977) p.Research Division NONLINEAR OPTICS AT INTERFACES Chenson K.ED LBL-12084 NONLINEAR OPTICS AT INTERFACES Chenson K. Chen

Chen, Chenson K.

2010-01-01T23:59:59.000Z

157

Microelectromechanical pump utilizing porous silicon  

DOE Patents [OSTI]

A microelectromechanical (MEM) pump is disclosed which includes a porous silicon region sandwiched between an inlet chamber and an outlet chamber. The porous silicon region is formed in a silicon substrate and contains a number of pores extending between the inlet and outlet chambers, with each pore having a cross-section dimension about equal to or smaller than a mean free path of a gas being pumped. A thermal gradient is provided along the length of each pore by a heat source which can be an electrical resistance heater or an integrated circuit (IC). A channel can be formed through the silicon substrate so that inlet and outlet ports can be formed on the same side of the substrate, or so that multiple MEM pumps can be connected in series to form a multi-stage MEM pump. The MEM pump has applications for use in gas-phase MEM chemical analysis systems, and can also be used for passive cooling of ICs.

Lantz, Jeffrey W. (Albuquerque, NM); Stalford, Harold L. (Norman, OK)

2011-07-19T23:59:59.000Z

158

Catalyst for hydrotreating carbonaceous liquids  

DOE Patents [OSTI]

A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

Berg, Lloyd (Bozeman, MT); McCandless, Frank P. (Bozeman, MT); Ramer, Ronald J. (Idaho Falls, ID)

1982-01-01T23:59:59.000Z

159

Winter Performance and Maintenance of Porous Asphalt Pavements  

E-Print Network [OSTI]

Concrete (HSG-B)Porous Asphalt (HSG-C) #12;Cold Climate Performance Results #12;12 Porous Asphalt SurfaceWinter Performance and Maintenance of Porous Asphalt Pavements Robert M. Roseen, Ph.D., P.E., D impacts for new development and reverse impacts in areas with redevelopment. #12;Porous Asphalt Design

160

Porous Pavement in Cold Climates Part: Performance and Cost  

E-Print Network [OSTI]

90 80 70 60 50 40 30 20 10 0 %RemovalEfficiency Porous Asphalt Pervious Concrete Retention Pond ` #12;17 Hydrrologic Performance of Porous Pavements Pervious Concrete (HSG-B)Porous Asphalt (HSG-C) #12;0 10 20 30 40Porous Pavement in Cold Climates Part: Performance and Cost Onondaga Environmental Institute 17

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Diffuse charge and Faradaic reactions in porous electrodes  

E-Print Network [OSTI]

Porous electrodes instead of flat electrodes are widely used in electrochemical systems to boost storage

Biesheuvel, P. M.

162

Forced dewetting on porous media  

E-Print Network [OSTI]

We study the dewetting of a porous plate withdrawn from a bath of fluid. The microscopic contact angle is fixed to zero and the flow is assumed to be parallel to the plate (lubrication approximation). The ordinary differential equation involving the position of the water surface is analysed in phase space by means of numerical integration. We show the existence of a critical value of the capillary number $\\eta U / \\gamma$, above which no stationary contact line can exist. An analytical model, based on asymptotic matching is developed, that reproduces the dependence of the critical capillary number on the angle of the plate with respect to the horizontal for large control parameters (3/2 power law).

Olivier Devauchelle; Christophe Josserand; Stephane Zaleski

2005-09-13T23:59:59.000Z

163

Laboratory experiments on dispersive transport across interfaces: The role of flow direction  

SciTech Connect (OSTI)

We present experimental evidence of asymmetrical dispersive transport of a conservative tracer across interfaces between different porous materials. Breakthrough curves are measured for tracer pulses that migrate in a steady state flow field through a column that contains adjacent segments of coarse and fine porous media. The breakthrough curves show significant differences in behavior, with tracers migrating from fine medium to coarse medium arriving significantly faster than those from coarse medium to fine medium. As the flow rate increases, the differences between the breakthrough curves diminish. We argue that this behavior indicates the occurrence of significant, time-dependent tracer accumulation in the resident concentration profile across the heterogeneity interface. Conventional modeling using the advection-dispersion equation is demonstrated to be unable to capture this asymmetric behavior. However, tracer accumulation at the interface has been observed in particle-tracking simulations, which may be related to the asymmetry in the observed breakthrough curves.

Berkowitz, B.; Cortis, A.; Dror, I.; Scher, H.

2009-04-01T23:59:59.000Z

164

X-rays at Solid-Liquid Surfaces  

SciTech Connect (OSTI)

Solid-liquid interfaces play an important role in many areas of current and future technologies, and in our biosphere. They play a key role in the development of nanofluidics and nanotribology, which sensitively depend on our knowledge of the microscopic structures and phenomena at the solid-liquid interface. The detailed understanding of how a fluid meets a wall is also a theoretical challenge. In particular, the phenomena at repulsive walls are of interest, since they affect many different phenomena, such as water-repellent surfaces or the role of the hydrophobic interaction in protein folding. Recent x-ray reflectivity studies of various solid-liquid interfaces have disclosed rather intriguiing phenomena, which will be discussed in this lecture: premelting of ice in contact with silica; liquid Pb in contact with Si; water in contact with hydrophobic surfaces. These experiments, carried out with high-energy x-ray microbeams, reveal detailed insight into the liquid density profile closest to the wall. A detailed insight into atomistic phenomena at solid-liquid interfaces is also a prerequisite in the microscopic control of electrochemical reactions at interfaces. Recent x-ray studies show the enormous future potential of such non-destructive analytical tools for the in situ observation of (electro-)chemical surface reactions. This lecture will review recent x-ray experiments on solid-liquid interfaces.

Dosch, Helmut (Max Planck Institute for Metals Research) [Max Planck Institute for Metals Research

2007-05-02T23:59:59.000Z

165

Influence of contact angle on slow evaporation in 2D porous media. H.Chrabi1,2  

E-Print Network [OSTI]

the invasion percolation model with the computation of the diffusive transport in the gas phase. The overall, cooperative smoothing mechanisms of the interface become important and the width of the liquid gas interface fingers that form during the evaporation process increases. The mean overall drying time increases

Boyer, Edmond

166

Multiphase flow in fractured porous media  

SciTech Connect (OSTI)

The major goal of this research project was to improve the understanding of the gas-oil two-phase flow in fractured porous media. In addition, miscible displacement was studied to evaluate its promise for enhanced recovery.

Firoozabadi, A.

1995-02-01T23:59:59.000Z

167

Anomalous transport through porous and fractured media  

E-Print Network [OSTI]

Anomalous transport, understood as the nonlinear scaling with time of the mean square displacement of transported particles, is observed in many physical processes, including contaminant transport through porous and fractured ...

Kang, Peter Kyungchul

2014-01-01T23:59:59.000Z

168

Modelling and characterisation of porous materials.  

E-Print Network [OSTI]

??Porous materials possessing random microstructures exist in both organic (e.g. polymer foam, bone) and in-organic (e.g. silica aerogels) forms. Foams and aerogels are two such… (more)

Alsayednoor, Jafar

2013-01-01T23:59:59.000Z

169

Brain-Computer Interfaces  

E-Print Network [OSTI]

I \\ November 16, 2008). CNN. ’Brain’ in a dish ?ies ?ightREFERENCES Adams, Ray. Brain Computer Interfaces: Psychologyaccessed Biever, Celeste. Brain cells in a dish ?y ?ghter

Aggarwal, Khushbu

2009-01-01T23:59:59.000Z

170

Characterization of naturally occurring porous media  

E-Print Network [OSTI]

characteristics of natural occur- ring porous media, The gR /K dimensionless ratio is related to the minimum water saturation in the reverse manner as is permeability. REFERENCES Wyllie, M. R. J. and M. B. Spangler: Application of Electrical Resistivity...: Resistivity of Brine-Saturated Sands in Relation to Pore Seometry. Cornell, D. snd D. L. Kstz: Flow of Sases through Consolidated Porous Media. Industrial and En ineeri hemietr (October 1953) Vo . 5, p. 21 5. Leverett, N, C. : Capillary Behavior...

Riley, Robert Daniel

1965-01-01T23:59:59.000Z

171

Method for preparing porous metal hydride compacts  

DOE Patents [OSTI]

A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

Ron, M.; Gruen, D.M.; Mendelsohn, M.H.; Sheft, I.

1980-01-21T23:59:59.000Z

172

Porous polymeric materials for hydrogen storage  

DOE Patents [OSTI]

A porous polymer, poly-9,9'-spirobifluorene and its derivatives for storage of H.sub.2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Yu, Luping; Liu, Di-Jia; Yuan, Shengwen; Yang, Junbing

2013-04-02T23:59:59.000Z

173

Method for preparing porous metal hydride compacts  

DOE Patents [OSTI]

A method for preparing porous metallic-matrix hydride compacts which can be repeatedly hydrided and dehydrided without disintegration. A mixture of a finely divided metal hydride and a finely divided matrix metal is contacted with a poison which prevents the metal hydride from dehydriding at room temperature and atmospheric pressure. The mixture of matrix metal and poisoned metal hydride is then compacted under pressure at room temperature to form porous metallic-matrix hydride compacts.

Ron, Moshe (Haifa, IL); Gruen, Dieter M. (Downers Grove, IL); Mendelsohn, Marshall H. (Woodridge, IL); Sheft, Irving (Oak Park, IL)

1981-01-01T23:59:59.000Z

174

Derivation of effective macroscopic Stokes-Cahn-Hilliard equations for periodic immiscible flows in porous media  

E-Print Network [OSTI]

Using thermodynamic and variational principles we examine a basic phase field model for a mixture of two incompressible fluids in strongly perforated domains. With the help of the multiple scale method with drift and our recently introduced splitting strategy for Ginzburg-Landau/Cahn-Hilliard-type equations [Schmuck et al., Proc. R. Soc. A 468:3705-3724, 2012.], we rigorously derive an effective macroscopic phase field formulation under the assumption of periodic flow and a sufficiently large P\\'eclet number. As for classical convection-diffusion problems, we obtain systematically diffusion-dispersion relations (including Taylor-Aris-dispersion). Our results also provide a convenient analytical and computational framework to macroscopically track interfaces in porous media. In view of the well-known versatility of phase field models, our study proposes a promising model for many engineering and scientific applications such as multiphase flows in porous media, microfluidics, and fuel cells.

Markus Schmuck; Marc Pradas; Gregorios A. Pavliotis; Serafim Kalliadasis

2013-10-19T23:59:59.000Z

175

Molecular Dynamics Simulations of Heat Transfer In Nanoscale Liquid Films  

E-Print Network [OSTI]

is almost a constant for ??f /? parabolic temperature profiles in the domain with temperature jumps due to the Kapitza resistance at the liquid/solid interfaces. Using the energy dissipation rates predicted by MD simulations...

Kim, Bo Hung

2010-07-14T23:59:59.000Z

176

Smart Interfaces superhydrophobe Oberflchen  

E-Print Network [OSTI]

forschen 24 Smart Interfaces ­ superhydrophobe Oberflächen Superhydrophobe, selbstreinigende-Silica-Hybridteilchen ermöglichen, lang- zeitstabile superhydrophobe Oberflächen einfach herzustellen. Smart Interfaces unten). Blattes runter. Neben der Struktur auf der Mikro- meter-Skala muss das Material, aus dem die

Kohlenbach, Ulrich

177

Mechanism of constitution liquid film migration  

SciTech Connect (OSTI)

Liquid film migration (LFM) in liquid phase sintering classically involves a large metastable liquid volume adjacent to solid, and migration occurs at an isolated solid-liquid (S-L) interface. Constitutional liquid film migration (CLFM), discovered in alloy 718, has major characteristics similar to those of LFM, except that the metastable liquid is from the constitutional liquation of precipitates on the grain boundary. The similarity between LFM and CLFM has led to the theory that coherency lattice strain responsible for LFM is also responsible for CLFM. The coherency strain hypothesis was tested in this study by evaluating whether the Hillert model of LFM would also apply for CLFM. Experimental results of CLFM in alloy 718 showed that migration velocity followed the trend predicted by the Hillert model. This indicates that the coherency strain hypothesis of LFM also applies for CLFM and that the coherency lattice strain responsible for LFM is also the driving force for CLFM.

NONE

1999-06-01T23:59:59.000Z

178

SRNL POROUS WALL GLASS MICROSPHERES  

SciTech Connect (OSTI)

The Savannah River National Laboratory (SRNL) has developed a new medium for storage of hydrogen and other gases. This involves fabrication of thin, Porous Walled, Hollow Glass Microspheres (PW-HGMs), with diameters generally in the range of 1 to several hundred microns. What is unique about the glass microballons is that porosity has been induced and controlled within the thin, one micron thick walls, on the scale of 10 to several thousand Angstroms. This porosity results in interesting properties including the ability to use these channels to fill the microballons with special absorbents and other materials, thus providing a contained environment even for reactive species. Gases can now enter the microspheres and be retained on the absorbents, resulting in solid-state and contained storage of even reactive species. Also, the porosity can be altered and controlled in various ways, and even used to filter mixed gas streams within a system. SRNL is involved in about a half dozen different programs involving these PW-HGMs and an overview of some of these activities and results emerging are presented.

Wicks, G; Leung Heung, L; Ray Schumacher, R

2008-04-15T23:59:59.000Z

179

Study of liquid retention in fixed-bed reactors with upward flow of gas and liquid  

SciTech Connect (OSTI)

A literature survey of the measurement techniques for the determination of liquid retention in cocurrent upward gas and liquid flow in fixed-bed reactors is presented. A number of these techniques were used in this work in columns of different diameters (Dc = 0.05 m, 0.10 m, and 0.15 m). Porous alumina particles of two different diameters (dp = 0.002 m and 0.0028 m) with both nonfoaming (water, cyclohexane, heptane, and propanol) and foaming liquids (kerosene, LCO, and diesel fuel) have been investigated. The gas used was either air or N[sub 2]. The methods investigated include volumetry, gravimetry, gammametry, and determination of residence-time distribution by tracer technique. A simple correlation for the prediction of total gas and liquid retention for bubble and pulsed flow is proposed and verified.

Yang, X.L.; Euzen, J.P. (Inst. Francais du Petrole, Vernaison (France)); Wild, G. (Lab. des Sciences du Genie Chimique, Nancy (France))

1993-01-01T23:59:59.000Z

180

Methods of forming and using porous structures for energy efficient separation of light gases by capillary condensation  

DOE Patents [OSTI]

The present invention relates to an improved method and apparatus for separating one or more condensable compounds from a mixture of two or more gases of differing volatilities by capillary fractionation in a membrane-type apparatus, and a method of forming porous structures therefor. More particularly, the invention includes methods of forming and using an apparatus consisting, at least in part, of a porous structure having capillary-type passages extending between a plurality of small openings on the first side and larger openings on a second side of the structure, the passages being adapted to permit a condensed liquid to flow therethrough substantially by capillary forces, whereby vapors from the mixture are condensed, at least in part, and substantially in and adjacent to the openings on the first side, and are caused to flow in a condensed liquid state, substantially in the absence of vapor, from the openings on the first side to the openings on the second side.

Calamur, Narasimhan (Lemont, IL); Carrera, Martin E. (Naperville, IL); Devlin, David J. (Los Alamos, NM); Archuleta, Tom (Espanola, NM)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Fabrication and characterization of porous shape memory alloys  

E-Print Network [OSTI]

This work details an investigation into the production of porous shape memory alloys (SMAs) via hot isostatic press (HIP) from prealloyed powders. HIPing is one of three main methods for producing porous SMAs, the other two are conventional...

Penrod, Luke Edward

2004-09-30T23:59:59.000Z

182

PHASE TRANSITION NEAR A LIQUID-GAS COEXISTENCE EQUILIBRIUM  

E-Print Network [OSTI]

, are the states in which gas and liquid can stay in equilibrium. We denote c± = -p (±), the speed of sound) in general in a oscillatory manner with fre- quency determined in part by the speeds of sound in gas, the time needed for the sound wave to travel in liquid from the interface to the tube boundary

Wang, Xiao-Ping

183

On the interface instability during rapid evaporation in microgravity  

SciTech Connect (OSTI)

The rapid evaporation of a superheated liquid (vapor explosion) under microgravity conditions is studied by direct numerical simulation. The time-dependent Navier-Stokes and energy equations coupled to the interface dynamics are solved using a two-dimensional finite-difference/front-tracking method. Large interface deformations, topology change, latent heat, surface tension and unequal material properties between the liquid and vapor phases are included in the simulations. A comparison of numerical results to the exact solution of a one-dimensional test problem shows excellent agreement. For the two-dimensional rapid evaporation problem, the vapor volume growth rate and unstable interface dynamics are studied for increasing levels of initial liquid superheat. As the superheat is increased the liquid-vapor interface experiences increasingly unstable energetic growth. These results indicate that heat transfer plays a very important role in the instability mechanism leading to vapor explosions. It is suggested that the Mullins-Sekerka instability could play a role in the instability initiation mechanism.

Juric, D. [Los Alamos National Lab., NM (United States). Theoretical Div.

1997-05-01T23:59:59.000Z

184

Materials and interfaces for catalysis, separation, storage, and environmental applications  

E-Print Network [OSTI]

and interfaces for a host of sustainable chemical processes that provide renewable (or cleaner) fuels the next generation of catalysts, separation processes, gas and liquid storage technologies, and environmental remediation methods. These materials and technologies are at the heart of industrial processes

Li, Mo

185

SRS Interface Input  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Interface Input 1. MOA's: The contractor has no MOA's in effect at the Tritium Operations (SRTO) level. 2. AIP's: The contractor has no AIP's in effect at the SRTO level. 3....

186

Joining of porous silicon carbide bodies  

DOE Patents [OSTI]

A method of joining two porous bodies of silicon carbide is disclosed. It entails utilizing an aqueous slip of a similar silicon carbide as was used to form the porous bodies, including the sintering aids, and a binder to initially join the porous bodies together. Then the composite structure is subjected to cold isostatic pressing to form a joint having good handling strength. Then the composite structure is subjected to pressureless sintering to form the final strong bond. Optionally, after the sintering the structure is subjected to hot isostatic pressing to further improve the joint and densify the structure. The result is a composite structure in which the joint is almost indistinguishable from the silicon carbide pieces which it joins.

Bates, Carl H. (Worcester, MA); Couhig, John T. (Worcester, MA); Pelletier, Paul J. (Thompson, CT)

1990-05-01T23:59:59.000Z

187

Investigation of porous media structures using NMR restricted diffusion measurements  

E-Print Network [OSTI]

coefficient which produces a new description of molecule diffusion in porous media. Experimental Details Model porous media chosen for investigation are water saturated glass bead packs of different bead sizes from 50 to 300 microns. First the glass beads... is accessible with the aid of sufficiently developed analysis procedures, NMR techniques can be applied to porous structure analysis. For the hypothesis that water saturated in porous media consists of two phases: water removed from domain boundaries...

Miao, Peizhi

1993-01-01T23:59:59.000Z

188

Instabilities during liquid migration into superheated hydrothermal systems  

SciTech Connect (OSTI)

Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor interface may become unstable and break up into fingers.

Fitzgerald, Shaun D.; Woods, Andrew W.

1995-01-26T23:59:59.000Z

189

Mechanical Properties of Porous-Matrix Ceramic Composites**  

E-Print Network [OSTI]

REVIEWS Mechanical Properties of Porous- Matrix Ceramic Composites** By Frank W. Zok* and Carlos G/Mechanical Properties of Porous-Matrix Ceramic Composites REVIEWS The porous matrix concept has been developed primarily. Levi 1. Introduction Damage tolerance can be enabled in continuous fiber-rein- forced ceramic

Zok, Frank

190

Porous polymeric materials for hydrogen storage  

DOE Patents [OSTI]

Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, poly-tetraphenyl methane and their derivatives for storage of H.sub.2 prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Yu, Luping (Hoffman Estates, IL); Liu, Di-Jia (Naperville, IL); Yuan, Shengwen (Chicago, IL); Yang, Junbing (Westmont, IL)

2011-12-13T23:59:59.000Z

191

Propagation of polymer slugs through porous media  

SciTech Connect (OSTI)

This paper describes an experimental and theoretical study of the mechanisms governing polymer slug propagation through porous media. An analytical model taking into account the macromolecule exclusion from pore walls is proposed to predict rodlike polymer velocity in porous media and thus the spreading out of polydispersed polymer slugs. Under conditions where this wall exclusion is maximum, i.e. at low shear rates and polymer concentrations, the experiments show that xanthan propagation is effectively predicted by this model. At higher flow rates and polymer concentrations, the effects of hydrodynamic dispersion and viscous fingering are analyzed. A new fractionation method for determining molecular weight distribution of polymers used in EOR is proposed.

Lecourtier, J.; Chauveteau, G.

1984-09-01T23:59:59.000Z

192

Micro-engineered cathode interface studies  

SciTech Connect (OSTI)

The aim of this work is to increase the performance of the cathode in solid oxide fuel cells (SOFCs) operating at 1,000 C by decreasing the polarization resistance from 0.2 {Omega}-cm{sup 2} at 300 mA/cm{sup 2}. Decreased polarization resistance will allow operation at higher current densities. This work is in support of the Westinghouse tubular SOFC technology using YSZ electrolyte and strontium doped lanthanum manganite (LSM) cathode. As a result of work performed last year at Argonne National Laboratory and information derived from the literature, the limitations at the cathode/electrolyte interface can be classified into two main areas. First, the ionic conductivity of the LSM cathode material is low which limits the reaction zone to an area very close to the interface, while the rest of the cathode thickness acts essentially as current collector with channels for gas access. Second, the electronic conductivity in YSZ is very low which limits the reaction zone to areas that are the boundaries between LSM and YSZ rather than the YSZ surface away from LSM at the interface. Possible solutions to this problem being pursued are: (1) introducing an ionic conducting YSZ phase in LSM to form a porous two-phase mixture of LSM and YSZ; (2) applying a thin interlayer between the electrolyte and the cathode where the interlayer has high ionic and electronic conductivity and high catalytic activity for reduction of O{sub 2}; (3) increasing the ionic conductivity in the LSM by suitable doping; and (4) increasing the electronic conductivity in the electrolyte by doping or by depositing an appropriate mixed conducting layer on the YSZ before applying the cathode.

Doshi, R.; Kueper, T.; Nagy, Z.; Krumpelt, M.

1997-08-01T23:59:59.000Z

193

A model for reactive porous transport during re-wetting of hardened concrete  

E-Print Network [OSTI]

We develop a mathematical model that captures the transport of liquid water in hardened concrete, as well as the chemical reactions that occur between the infiltrating water and the residual calcium silicate compounds that reside in the porous concrete matrix. We investigate the hypothesis that the reaction product -- calcium silicate hydrate gel -- clogs the pores within the concrete thereby hindering water transport. Using numerical simulations, we determine the sensitivity of the model solution to changes in various physical parameters, and compare to experimental results available in the literature.

Chapwanya, Michael; Stockie, John M

2008-01-01T23:59:59.000Z

194

Surface layering of liquids: The role of surface tension Oleg Shpyrko,1  

E-Print Network [OSTI]

Surface layering of liquids: The role of surface tension Oleg Shpyrko,1 Masafumi Fukuto,1 Peter and alloys are always layered, regardless of composition and surface tension; a result supported by three, for the liquid-vapor interface it is tempting to think that the large surface tension of liquid metals such as Hg

Ocko, Ben

195

Porous ceramics and method for making  

SciTech Connect (OSTI)

The fabrication of a porous ceramic composite is described. Fumed silica particles are coated with a nitrate, preferably aluminum nitrate. Next the nitrate is converted to an oxide and formed into a desired configuration. This configuration is heated to convert the oxide to an oxide silicate which is then react with HF, resulting in the fluoride ceramic, preferably aluminum fluoride.

Reiner, R.H.; Holcombe, C.E.

1989-06-08T23:59:59.000Z

196

Method of making porous ceramic fluoride  

SciTech Connect (OSTI)

A process is disclosed for making a porous ceramic composite where fumed silica particles are coated with a nitrate, preferably aluminum nitrate. Next the nitrate is converted to an oxide and formed into a desired configuration. This configuration is heated to convert the oxide to an oxide silicate which is then react with HF, resulting in the fluoride ceramic, preferably aluminum fluoride.

Reiner, R.H.; Holcombe, C.E.

1990-11-13T23:59:59.000Z

197

Porous radiant burners having increased radiant output  

DOE Patents [OSTI]

Means and methods for enhancing the output of radiant energy from a porous radiant burner by minimizing the scattering and increasing the adsorption, and thus emission of such energy by the use of randomly dispersed ceramic fibers of sub-micron diameter in the fabrication of ceramic fiber matrix burners and for use therein.

Tong, Timothy W. (Tempe, AZ); Sathe, Sanjeev B. (Tempe, AZ); Peck, Robert E. (Tempe, AZ)

1990-01-01T23:59:59.000Z

198

Method of making porous ceramic fluoride  

DOE Patents [OSTI]

A process for making a porous ceramic composite where fumed silica particles are coated with a nitrate, preferably aluminum nitrate. Next the nitrate is converted to an oxide and formed into a desired configuration. This configuration is heated to convert the oxide to an oxide silicate which is then react with HF, resulting in the fluoride ceramic, preferably aluminum fluoride.

Reiner, Robert H. (Knoxville, TN); Holcombe, Cressie E. (Farragut, TN)

1990-01-01T23:59:59.000Z

199

Carbon films produced from ionic liquid carbon precursors  

DOE Patents [OSTI]

The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ionic liquid has the general formula (X.sup.+a).sub.x(Y.sup.-b).sub.y, wherein the variables a and b are, independently, non-zero integers, and the subscript variables x and y are, independently, non-zero integers, such that ax=by, and at least one of X.sup.+ and Y.sup.- possesses at least one carbon-nitrogen unsaturated bond. The invention is also directed to a composition comprising a porous carbon film possessing a nitrogen content of at least 10 atom %.

Dai, Sheng; Luo, Huimin; Lee, Je Seung

2013-11-05T23:59:59.000Z

200

Process for the production of liquid hydrocarbons  

DOE Patents [OSTI]

The present invention concerns a process for the preparation of liquid hydrocarbons which process comprises contacting synthesis gas with a slurry of solid catalyst particles and a liquid in a reactor vessel by introducing the synthesis gas at a low level into the slurry at conditions suitable for conversion of the synthesis gas into liquid hydrocarbons, the solid catalyst particles comprising a catalytic active metal selected from cobalt or iron on a porous refractory oxide carrier, preferably selected from silica, alumina, titania, zirconia or mixtures thereof, the catalyst being present in an amount between 10 and 40 vol. percent based on total slurry volume liquids and solids, and separating liquid material from the solid catalyst particles by using a filtration system comprising an asymmetric filtration medium (the selective side at the slurry side), in which filtration system the average pressure differential over the filtration medium is at least 0.1 bar, in which process the particle size distribution is such that at least a certain amount of the catalyst particles is smaller than the average pore size of the selective layer of the filtration medium. The invention also comprises an apparatus to carry out the process described above.

Bhatt, Bharat Lajjaram; Engel, Dirk Coenraad; Heydorn, Edward Clyde; Senden, Matthijis Maria

2006-06-27T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Experimental Investigation of the Effective Foam Viscosity in Unsaturated Porous Media  

SciTech Connect (OSTI)

Foam has the potential to effectively carry and distribute either aqueous or gaseous amendments to the deep vadose zone for contaminant remediation. However, the transport of foam in porous media is complicated because flow characteristics such as the effective viscosity are affected not only by foam properties but also by the sediment properties and flow conditions. We determined the average effective foam viscosity via a series of laboratory experiments and found that the effective foam viscosity increased with the liquid fraction in foam, the injection rate, and sediment permeability. These impacts are quantified with an empirical expression, which is further demonstrated with data from literature. The results show that the liquid fraction in foam and sediment permeability are two primary factors affecting effective foam viscosity. These results suggest that, when foam is used in deep vadose zone remediation, foam flow will not suffer from gravitational drainage and can distribute amendments uniformly in heterogeneous sediments.

Zhang, Z. F.; Zhong, Lirong; White, Mark D.; Szecsody, James E.

2012-11-01T23:59:59.000Z

202

Dynamics of DNAPL penetration into fractured porous media  

SciTech Connect (OSTI)

Dense nonaqueous phase liquids (DNAPLs) that pool above stratigraphic contacts as a result of capillary forces can migrate downward through fractures in the underlying fine-grained layer. Although the DNAPL in the fracture is excluded from the surrounding porous matrix by capillary forces, the DNAPL constituent will dissolve and migrate by diffusion into the matrix. As a front of moderately soluble DNAPL advances into a fracture, the flux of dissolved material into the matrix increases until it becomes comparable to the rate of flow into the fracture, reducing the pressure in the DNAPL phase and slowing its advance. If the DNAPL front encounters a constriction with sufficiently large entry pressure, its advance will halt temporarily. But as the concentration gradients driving diffusion into the matrix decrease, there will be less DNAPL lost by diffusion and the DNAPL pressure at the constriction will increase until it exceeds the entry pressure, causing the downward advance of the front to suddenly resume. Because the time scales of diffusion are much slower than those of density flow, this analysis suggests that under certain circumstances a DNAPL can suddenly resume its downward advance after a long period of apparent immobility. In one plausible example, a dichloromethane front passes through 5 m of fractured clay in 16 days, is immobile for more than four years, and then suddenly moves again. Where this phenomenon is possible, removal of DNAPL to protect underlying aquifers becomes more important as a remediation goal.

Ross, B. [Disposal Safety Inc., Washington, DC (United States); Lu, N. [Colorado School of Mines, Golden, CO (United States). Div. of Engineering

1999-01-01T23:59:59.000Z

203

Rate constants for charge transfer across semiconductor-liquid interfaces  

SciTech Connect (OSTI)

Interfacial charge-transfer rate constants have been measured for n-type Si electrodes in contact with a series of viologen-based redox couples in methanol through analyses of the behavior of these junctions with respect to their current density versus potential and differential capacitance versus potential properties. The data allow evaluation of the maximum rate constant (and therefore the electronic coupling) for majority carriers in the solid as well as of the dependence of the rate constant on the driving force for transfer of delocalized electrons from the n-Si semiconducting electrode into the localized molecular redox species in the solution phase. The data are in good agreement with existing models of this interfacial electron transfer process and provide insight into the fundamental kinetic events underlying the use of semiconducting photoelectrodes in applications such as solar energy conversion. 23 refs., 3 figs.

Fajardo, A.M.; Lewis, N.S. [California Institute of Technology, Pasadena, CA (United States)

1996-11-08T23:59:59.000Z

204

A Magnetomechanical Thermal Energy Harvester With A Reversible Liquid Interface  

E-Print Network [OSTI]

illustrated in figure 4.1. Two Peltier devices are stackedThe hot side of the top Peltier device is attached to aand prevent burning of the Peltier devices. The temperature

He, Hong

2012-01-01T23:59:59.000Z

205

X-rays at Solid-Liquid Interfaces  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and MaterialsWenjun1of EnergyX-rayNew

206

A Magnetomechanical Thermal Energy Harvester With A Reversible Liquid Interface  

E-Print Network [OSTI]

and Mechanical Model of a Thermal Energy Harvesting Device”,M, and Ferrari V. , “Thermal energy harvesting throughand G. P. Carman, “Thermal energy harvesting device using

He, Hong

2012-01-01T23:59:59.000Z

207

THIN LIQUID WALL BEHAVIOR UNDER IFE CYCLIC OPERATION A. R. Raffray  

E-Print Network [OSTI]

to the requirements imposed by the driver and target thermal and injection control. I. INTRODUCTION A wetted wall relative to the requirements imposed by the driver and target thermal and injection control. In determining of thin liquid film protection systems with either radial injection through a porous first wall (hereafter

Najmabadi, Farrokh

208

Plasmas in Multiphase Media: Bubble Enhanced Discharges in Liquids and Plasma/Liquid Phase Boundaries  

SciTech Connect (OSTI)

In this research project, the interaction of atmospheric pressure plasmas with multi-phase media was computationally investigated. Multi-phase media includes liquids, particles, complex materials and porous surfaces. Although this investigation addressed fundamental plasma transport and chemical processes, the outcomes directly and beneficially affected applications including biotechnology, medicine and environmental remediation (e.g., water purification). During this project, we made advances in our understanding of the interaction of atmospheric pressure plasmas in the form of dielectric barrier discharges and plasma jets with organic materials and liquids. We also made advances in our ability to use computer modeling to represent these complex processes. We determined the method that atmospheric pressure plasmas flow along solid and liquid surfaces, and through endoscopic like tubes, deliver optical and high energy ion activation energy to organic and liquid surfaces, and produce reactivity in thin liquid layers, as might cover a wound. We determined the mechanisms whereby plasmas can deliver activation energy to the inside of liquids by sustaining plasmas in bubbles. These findings are important to the advancement of new technology areas such as plasma medicine

Kushner, Mark Jay [University of Michigan] [University of Michigan

2014-07-10T23:59:59.000Z

209

VAPOR SPACE AND LIQUID/AIR INTERFACECORROSION TESTS  

SciTech Connect (OSTI)

The phenomena of vapor space corrosion and liquid/air interface corrosion of carbon steel in simulated liquid waste environments have been investigated. Initial experiments have explored the hypothesis that vapor space corrosion may be accelerated by the formation of a corrosive electrolyte on the tank wall by a process of evaporation of relatively warmer waste and condensation of the vapor on the relatively cooler tank wall. Results from initial testing do not support the hypothesis of electrolyte transport by evaporation and condensation. The analysis of the condensate collected by a steel specimen suspended over a 40 C simulated waste solution showed no measurable concentrations of the constituents of the simulated solution and a decrease in pH from 14 in the simulant to 5.3 in the condensate. Liquid/air interface corrosion was studied as a galvanic corrosion system, where steel at the interface undergoes accelerated corrosion while steel in contact with bulk waste is protected. The zero-resistance-ammeter technique was used to measure the current flow between steel specimens immersed in solutions simulating (1) the high-pH bulk liquid waste and (2) the expected low-pH meniscus liquid at the liquid/air interface. Open-circuit potential measurements of the steel specimens were not significantly different in the two solutions, with the result that (1) no consistent galvanic current flow occurred and (2) both the meniscus specimen and bulk specimen were subject to pitting corrosion.

Zapp, P.; Hoffman, E.

2009-11-09T23:59:59.000Z

210

Stiffening solids with liquid inclusions  

E-Print Network [OSTI]

From bone and wood to concrete and carbon fibre, composites are ubiquitous natural and engineering materials. Eshelby's inclusion theory describes how macroscopic stress fields couple to isolated microscopic inclusions, allowing prediction of a composite's bulk mechanical properties from a knowledge of its microstructure. It has been extended to describe a wide variety of phenomena from solid fracture to cell adhesion. Here, we show experimentally and theoretically that Eshelby's theory breaks down for small liquid inclusions in a soft solid. In this limit, an isolated droplet's deformation is strongly size-dependent with the smallest droplets mimicking the behaviour of solid inclusions. Furthermore, in opposition to the predictions of conventional composite theory, we find that finite concentrations of small liquid inclusions enhance the stiffness of soft solids. A straight-forward extension of Eshelby's theory, accounting for the surface tension of the solid-liquid interface, explains our experimental observations. The counterintuitive effect of liquid-stiffening of solids is expected whenever droplet radii are smaller than an elastocapillary length, given by the ratio of the surface tension to Young's modulus of the solid matrix.

Robert W. Style; Rostislav Boltyanskiy; Benjamin Allen; Katharine E. Jensen; Henry P. Foote; John S. Wettlaufer; Eric R. Dufresne

2014-07-24T23:59:59.000Z

211

Fundamental Studies of Fluid Mechanics: Stability in Porous Media  

SciTech Connect (OSTI)

This work has been concerned with theoretical, computational and experimental studies of a variety of flow and transport problems that are of generic interest and applicability in energy-related and energy-intensive processes. These include the following. (1) Problems associated with oil recovery: the global economy continues to be dependent on the stable and predictable supply of oil and fossil fuels. This will remain the case for the near term, as current estimates are that world production of oil will peak between 2025 and 2100, depending on assumptions regarding growth. Most of these resources reside in porous rocks and other naturally occurring media. Studies of flow-induced instabilities are relevant to the areas of secondary and enhanced oil recovery. (2) Small scale and Stokes flows: flows in microgeometries and involving interfaces and surfactants are of interest in a myriad of energy-related contexts. These include: pore-level modeling of the fundamental processes by which oil held in porous materials is mobilized and produced; heating and cooling energy cycles involving significant expenditure of energy in conditioning of human environments, heat pipes, and compact heat exchangers; and energy efficiency in large scale separation processes such as distillation and absorption-processes that underlie the chemical process industries. (3) Coating flows: these are of interest in information technologies, including the manufacture of integrated circuits and data storage and retrieval devices. It is estimated that 50-70% of the starting raw materials and intermediate devices in information technology processes must be discarded as a result of imperfections and failure to meet specifications. These in turn are often the result of the inability to control fluid-mechanical processes and flow instabilities. Our work over the grant period is primarily fundamental in nature. We are interested in establishing general principles and behaviors that relate to a variety of processes in a variety of contexts. Our work has focused and will continue to focus on fluid mechanical phenomena that are of interest in energy-related technologies, with an emphasis on interfacial flows.

George M. Homsy

2005-04-28T23:59:59.000Z

212

Liquid electrode  

DOE Patents [OSTI]

A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

Ekechukwu, A.A.

1994-07-05T23:59:59.000Z

213

Virtual button interface  

DOE Patents [OSTI]

An apparatus and method of issuing commands to a computer by a user interfacing with a virtual reality environment are disclosed. To issue a command, the user directs gaze at a virtual button within the virtual reality environment, causing a perceptible change in the virtual button, which then sends a command corresponding to the virtual button to the computer, optionally after a confirming action is performed by the user, such as depressing a thumb switch. 4 figs.

Jones, J.S.

1999-01-12T23:59:59.000Z

214

Standard interface file handbook  

SciTech Connect (OSTI)

This handbook documents many of the standard interface file formats that have been adopted by the US Department of Energy to facilitate communications between and portability of, various large reactor physics and radiation transport software packages. The emphasis is on those files needed for use of the VENTURE/PC diffusion-depletion code system. File structures, contents and some practical advice on use of the various files are provided.

Shapiro, A.; Huria, H.C. (Cincinnati Univ., OH (United States))

1992-10-01T23:59:59.000Z

215

Heat transfer enhancement in a channel with porous baffles  

E-Print Network [OSTI]

with staggered positioned porous baffles. A numerical procedure was implemented, in conjunction with a commercially available Navier-Stokes solver, to model the turbulent flow in porous media. The Brinkman-Forchheimer-Extended Darcy model was used for modeling... fluid flow through the porous baffles. Conventional, one- equation, and two-equation models were used for heat transfer modeling. The accuracy and characteristics of each model were investigated and discussed. The results were compared...

Ko, Kang-Hoon

2005-02-17T23:59:59.000Z

216

Desiccation of unsaturated porous media: Intermediate-scale experiment...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with the multifluid flow simulator STOMP, using independently obtained hydraulic and thermal porous medium properties. In all the experiments, the injection of dry air proved...

217

Living Bacterial Sacrificial Porogens to Engineer Decellularized Porous Scaffolds  

E-Print Network [OSTI]

Decellularization and cellularization of organs have emerged as disruptive methods in tissue engineering and regenerative medicine. Porous hydrogel scaffolds have widespread applications in tissue engineering, regenerative ...

Xu, Feng

218

multiscale flow and transport in porous media - Department of ...  

E-Print Network [OSTI]

Multiphase ow and transport in heterogeneous porous media is typically ... we discuss two model problems: contaminant transport in aquifers and water ooding

219

Transport in Porous Media ISSN 0169-3913  

E-Print Network [OSTI]

-011-9720-2 Applicability of the Linearized Governing Equation of Gas Flow in Porous Media Jian Li · Hongbin Zhan · Guanhua

Zhan, Hongbin

220

Fast, Low Cost Method for Manufacturing Porous Structures for...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Materials Advanced Materials Find More Like This Return to Search Fast, Low Cost Method for Manufacturing Porous Structures for Fuel Cells, Catalysts and Filtration...

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Etch-free Formation of Porous Silicon by High-energy Ion Irradiation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Etch-free Formation of Porous Silicon by High-energy Ion Irradiation. Etch-free Formation of Porous Silicon by High-energy Ion Irradiation. Abstract: In this study, porous silicon...

222

Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous Silica Material Low-Cost, Haziness-Free, Transparent Insulation Based On a Porous Silica Material Image of porous...

223

Interface scaling in a two-dimensional porous medium under combined viscous, gravity, and capillary effects  

E-Print Network [OSTI]

of the model. Viscous forces tend to destabilize the displacement front into narrow fingers against the stabilizing effect of gravity. Subsequently, a viscous instability is observed for sufficiently large in geological engineering, including ground water flow modeling and oil recovery, where an increase

Schmittbuhl, Jean

224

Effects of Monolayer Density and Bulk Ionic Strength on Acid-Base Equilibria at the Air/Water Interface  

E-Print Network [OSTI]

using the method of second harmonic generation. If it is assumed that the amphiphiles are uniformly distributed at the interface, the application of the Gouy-Chapman model yields pKa values ranging from 10 of the interface, i.e., there are amphiphiles islands of "liquid phase" density immersed in a "gas phase" of very

Eisenthal, Kenneth B.

225

Multiple network interface core apparatus and method  

DOE Patents [OSTI]

A network interface controller and network interface control method comprising providing a single integrated circuit as a network interface controller and employing a plurality of network interface cores on the single integrated circuit.

Underwood, Keith D. (Albuquerque, NM); Hemmert, Karl Scott (Albuquerque, NM)

2011-04-26T23:59:59.000Z

226

Curved and diffuse interface effects on the nuclear surface tension  

E-Print Network [OSTI]

We redefine the surface tension coefficient for a nuclear Fermi-liquid drop with a finite diffuse layer. Following Gibbs-Tolman concept, we introduce the equimolar radius R_e of sharp surface droplet at which the surface tension is applied and the radius of tension surface R_s which provides the minimum of the surface tension coefficient \\sigma. This procedure allows us to derive both the surface tension and the corresponding curvature correction (Tolman length) correctly for the curved and diffuse interface. We point out that the curvature correction depends significantly on the finite diffuse interface. This fact is missed in traditional nuclear considerations of curvature correction to the surface tension. We show that Tolman's length \\xi is negative for nuclear Fermi-liquid drop. The value of the Tolman length is only slightly sensitive to the Skyrme force parametrization and equals \\xi=-0.36 fm.

V. M. Kolomietz; S. V. Lukyanov; A. I. Sanzhur

2012-01-30T23:59:59.000Z

227

Porous, sintered metal filter recovers 100% of catalyst in H/sub 2/O/sub 2/ process  

SciTech Connect (OSTI)

Recovery of catalyst and prevention of catalyst from entering the oxidizer were plant problems for the Interox America process for production of H/sub 2/O/sub 2/ by the catalyzed alternative hydrogenation and oxidation of anthraquinone. A porous metal filter element was inserted in the filter unit following the hydrogenation stage to collect the catalyst which forms a permeable cake that is recovered by backwashing on a timer cycle. The porous metal filters consisting of a rigid matrix containing small pores applicable for the collection of very small particles (> 0.5 ..mu.. in liquids and 0.05 ..mu.. in gases) have been in use in plants in UK for 25 years with 75% of the original filter elements still in use. (BLM)

Hall, G.L.; Isaacs, M.

1982-01-01T23:59:59.000Z

228

Characteristics of the weld interface in dissimilar austenitic-pearlitic steel welds  

SciTech Connect (OSTI)

The weld interface in dissimilar alloy welds between austenitic and pearlitic steels was observed directly by using scanning and transmission electron microscopy, and energy-dispersive x-ray spectrometry. Two types of weld interface were found in the joints. One was the austenite/martensite-like interface that formed the boundary between the mixed weld metal zone and the partially mixed transitional zone. The other is the martensite-like/ferrite interface that is the true liquid-solid boundary of the joint. These interfaces can exist independently in different joints and can also coexist in one joint, depending on the Cr and Ni contents of the filler metals and alloy in the base metals. The formation mechanism of the weld interface and its effect on the mechanical properties of the welded joint are discussed.

Pan, C.; Zhang, Z. (Wuhan Transportation Univ. (China). Dept. of Marine Mechanical Engineering)

1994-09-01T23:59:59.000Z

229

In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High Performance Supercapacitors. In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High...

230

High-throughput Characterization of Porous Materials Using Graphics Processing Units  

E-Print Network [OSTI]

A.E. ; Purcell, T. Computer Graphics Forum 2007, 26(1), 80-of Porous Materials Using Graphics Processing Units Jihanof Porous Materials Using Graphics Processing Units Jihan

Kim, Jihan

2013-01-01T23:59:59.000Z

231

Characterizing unsaturated diffusion in porous tuff gravel  

SciTech Connect (OSTI)

Evaluation of solute diffusion in unsaturated porous gravel is very important for investigations of contaminant transport and remediation, risk assessment, and waste disposal (for example, the potential high-level nuclear waste repository at Yucca Mountain, Nevada). For a porous aggregate medium such as granular tuff, the total water content is comprised of surface water and interior water. The surface water component (water film around grains and pendular water between the grain contacts) could serve as a predominant diffusion pathway. To investigate the extent to which surface water films and contact points affect solute diffusion in unsaturated gravel, we examined the configuration of water using x-ray computed tomography in partially saturated gravel, and made quantitative measurements of diffusion at multiple water contents using two different techniques. In the first, diffusion coefficients of potassium chloride in 2-4 mm granular tuff at multiple water contents were calculated from electrical conductivity measurements using the Nernst-Einstein equation. In the second, we used laser ablation with inductively coupled plasma-mass spectrometry to perform micro-scale mapping, allowing the measurement of diffusion coefficients for a mixture of chemical tracers for tuff cubes and tetrahedrons having two contact geometries (cube-cube and cube-tetrahedron). The x-ray computed tomography images show limited contact between grains, and this could hinder the pathways for diffusive transport. Experimental results show the critical role of surface water in controlling transport pathways and hence the magnitude of diffusion. Even with a bulk volumetric water content of 1.5%, the measured solute diffusion coefficient is as low as 1.5 x 10{sup -14} m{sup 2}/s for tuff gravel. Currently used diffusion models relating diffusion coefficients to total volumetric water content inadequately describe unsaturated diffusion behavior in porous gravel at very low water contents.

Hu, Qinhong; Kneafsey, Timothy J.; Roberts, Jeffery J.; Tomutsa, Liviu; Wang, Joseph, S.Y.

2003-11-12T23:59:59.000Z

232

Molecular Design of Branched and Binary Molecules at Ordered Interfaces  

SciTech Connect (OSTI)

This study examined five different branched molecular architectures to discern the effect of design on the ability of molecules to form ordered structures at interfaces. Photochromic monodendrons formed kinked packing structures at the air-water interface due to the cross-sectional area mismatch created by varying number of alkyl tails and the hydrophilic polar head group. The lower generations formed orthorhombic unit cell with long range ordering despite the alkyl tails tilted to a large degree. Favorable interactions between liquid crystalline terminal groups and the underlying substrate were observed to compel a flexible carbosilane dendrimer core to form a compressed elliptical conformation which packed stagger within lamellae domains with limited short range ordering. A twelve arm binary star polymer was observed to form two dimensional micelles at the air-water interface attributed to the higher polystyrene block composition. Linear rod-coil molecules formed a multitude of packing structures at the air-water interface due to the varying composition. Tree-like rod-coil molecules demonstrated the ability to form one-dimensional structures at the air-water interface and at the air-solvent interface caused by the preferential ordering of the rigid rod cores. The role of molecular architecture and composition was examined and the influence chemically competing fragments was shown to exert on the packing structure. The amphiphilic balance of the different molecular series exhibited control on the ordering behavior at the air-water interface and within bulk structures. The shell nature and tail type was determined to dictate the preferential ordering structure and molecular reorganization at interfaces with the core nature effect secondary.

Kirsten Larson Genson

2005-12-27T23:59:59.000Z

233

Effect of Adsorption on the Surface Tensions of Solid-Fluid Interfaces C. A. Ward* and Jiyu Wu  

E-Print Network [OSTI]

Effect of Adsorption on the Surface Tensions of Solid-Fluid Interfaces C. A. Ward* and Jiyu Wu is proposed for determining the surface tensions of a solid in contact with either a liquid or a vapor. Only to obtain the expressions for the solid-vapor and the solid-liquid surface tensions, [1] SV and [1] SL

Ward, Charles A.

234

Protein separations using porous silicon membranes  

E-Print Network [OSTI]

charge or as the absence of an electron in the crystal structure of silicon. The properties of boron doped siTicon are exploited experimentally by setting up an etch cell in which one surface of the silicon serves as the anode and by using... terminals located on the top surface of the etch cell. The current to be used in the experiment and the total time were previously calculated to produce the desired average pore size and porous silicon film thickness, respectively. The power source...

Pass, Shannon Marie

1992-01-01T23:59:59.000Z

235

A rigid porous filter and filtration method  

SciTech Connect (OSTI)

The present invention involves a porous rigid filter comprising a plurality of concentric filtration elements having internal flow passages and forming external flow passages there between. The present invention also involves a pressure vessel containing the filter for the removal of particulate from high pressure particulate containing gases, and further involves a method for using the filter to remove such particulate. The present filter has the advantage of requiring fewer filter elements due to the high surface area- to-volume ratio provided by the filter, requires a reduced pressure vessel size, and exhibits enhanced mechanical design properties, improved cleaning properties, configuration options, modularity and ease of fabrication.

Chiang, Ta-Kuan; Straub, Douglas, Straub L.; Dennis, Richard A.

1998-12-01T23:59:59.000Z

236

TERMINATION OF THE POROUS WALL CONCEPT To: APEX GROUP  

E-Print Network [OSTI]

TERMINATION OF THE POROUS WALL CONCEPT To: APEX GROUP From: Anter El-Azab (anter@seas.ucla.edu) Re with Lithium will can not work and this concept should be terminated. For the case of vanadium alloy on this concept should be terminated. #12;TERMINATION OF THE POROUS WALL CONCEPT Best Regards, Anter #12;

California at Los Angeles, University of

237

Nitrogen modification of highly porous carbon for improved supercapacitor performance  

E-Print Network [OSTI]

Nitrogen modification of highly porous carbon for improved supercapacitor performance Stephanie L for supercapacitor applications. Surface modification increases the amount of nitrogen by four times when compared elements in highly porous carbon used for electric double-layer supercapacitors.1 These elements modify

Cao, Guozhong

238

Development of an oxidized porous silicon vacuum microtriode  

E-Print Network [OSTI]

the requirements for a gigatron cathode. In the present work, a porous sihcon-based approach is evaluated. The use of porous silicon reduces the size of a single emitter to the manometer scale, and a true two-dimensional array geometry can be approached. A wide...

Smith, Don Deewayne

1994-01-01T23:59:59.000Z

239

Diffusion with dissolution and precipitation in a porous media  

E-Print Network [OSTI]

Diffusion with dissolution and precipitation in a porous media approximation by a finite volume. Quelques tests numériques sont ensuite montrés. KEYWORDS: diffusion, dissolution­precipitation, porous­ ficiency of such disposals relies on material barriers. For such a use, cement concrete offers

Herbin, Raphaèle

240

Diffusion with dissolution and precipitation in a porous media  

E-Print Network [OSTI]

Diffusion with dissolution and precipitation in a porous media approximation by a finite volume numériques sont ensuite montrés. KEYWORDS: diffusion, dissolution-precipitation, porous media, finite volumes barriers. For such a use, cement concrete offers the advantage of having a weak porosity. However, disposal

Herbin, Raphaèle

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

MATHEMATICAL MODELING AND SIMULATION FOR FLUID FLOW IN POROUS MEDIA  

E-Print Network [OSTI]

1 MATHEMATICAL MODELING AND SIMULATION FOR FLUID FLOW IN POROUS MEDIA Ewing, Richard Texas A is to understand the complex chemical, physical, and fluid flow processes occurring in an underground porous medium with one pass through these four steps. Once a computer code has been developed which gives concrete

Ewing, Richard E.

242

Invariant measures for a stochastic porous medium equation  

E-Print Network [OSTI]

Invariant measures for a stochastic porous medium equation Giuseppe Da Prato (Scuola Normale AMS :76S05,35J25, 37L40 . 1 Introduction The porous medium equation X t = (Xm ), m N, (1 Brownian motion in H and C is a positive definite bounded operator on H of trace class. To be more concrete

Röckner, Michael

243

Fundamental studies of fluid mechanics and stability in porous media  

SciTech Connect (OSTI)

This report summarizes accomplished and proposed work for the fundamental studies of fluid mechanics and stability in porous media. Topics discussed include: viscous fingering in miscible displacements; polymer flow interactions in free shear layers of viscoelastic fluids; effect of nonmonotonic viscosity profiles on the stability of miscible displacements in porous media; and references. (JL)

Homsy, G.M.

1991-08-01T23:59:59.000Z

244

Stability of Miscible Displacements Across Stratified Porous Media  

SciTech Connect (OSTI)

This report studied macro-scale heterogeneity effects. Reflecting on their importance, current simulation practices of flow and displacement in porous media were invariably based on heterogeneous permeability fields. Here, it was focused on a specific aspect of such problems, namely the stability of miscible displacements in stratified porous media, where the displacement is perpendicular to the direction of stratification.

Shariati, Maryam; Yortsos, Yanis C.

2000-09-11T23:59:59.000Z

245

Combustion fronts in porous media with two layers Steve Schecter  

E-Print Network [OSTI]

Combustion fronts in porous media with two layers layer 1 layer 2 Steve Schecter North Carolina Subject: Propagation of a combustion front through a porous medium with two parallel layers having different properties. · Each layer admits a traveling combustion wave. · The layers are coupled by heat

Schecter, Stephen

246

Numerical Computation of Multiphase Flows in Porous Media  

E-Print Network [OSTI]

Preface iii Notation ix Introduction 1 1 Modeling Immiscible Fluid Flow in Porous Media 7 1.1 Porous Media legendi im Fachgebiet Informatik (Wissenschaftliches Rechnen) #12;ii #12;Preface Groundwater is a precious resource that is important for all forms of life on earth. The quality of groundwater is impaired

Bastian, Peter

247

Characterization of the microdialysis junction interface for capillary electrophoresis/microelectrospray ionization mass spectrometry  

SciTech Connect (OSTI)

A capillary electrophoresis/electrospray ionization mass spectrometry (CE/ESI-MS) interface, based on an electric circuit across a microdialysis membrane surrounding a short capillary segment closely connected to the separation capillary terminus, is demonstrated to be sensitive, efficient, and rugged. A microspray type ionization emitter produces a stable electrospray at the low flow rates provided by CE and thus avoids both the need for a makeup liquid flow provided by liquid junction or sheath flow interfaces and the subsequent dilution and reduction in sensitivity. Reproducibility studies and comparisons with CE/UV and the CE/sheath flow interface with ESI-MS are presented. Additionally, postrun acidification via the microdialysis junction interface is demonstrated and shown to be capable of denaturing the holomyoglobin protein noncovalent complex while maintaining separation efficiency. 21 refs., 7 figs., 1 tab.

Severs, J.C.; Smith, R.D. [Pacific Northwest National Lab., Richland, WA (United States)] [Pacific Northwest National Lab., Richland, WA (United States)

1997-06-01T23:59:59.000Z

248

Heat exchangers comprising at least one porous member positioned within a casing  

DOE Patents [OSTI]

A heat exchanger and associated methods for sublimating solid particles therein, for conveying fluids therethrough, or both. The heat exchanger includes a chamber, and a porous member having a porous wall having pores in communication with the chamber and an interior of the porous member. A first fluid is conveyed into the porous member while a second fluid is conveyed into the porous member through the porous wall. The second fluid may form a positive flow boundary layer along the porous wall to reduce or eliminate substantial contact between the first fluid and the interior of the porous wall. The combined first and second fluids are conveyed out of the porous member. Additionally, the first fluid and the second fluid may each be conveyed into the porous member at different temperatures and may exit the porous member at substantially the same temperature.

Turner, Terry D. (Idaho Falls, ID); Wilding, Bruce M (Idaho Falls, ID)

2011-11-22T23:59:59.000Z

249

Microwave impregnation of porous materials with thermal energy storage materials  

DOE Patents [OSTI]

A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

Benson, David K. (Golden, CO); Burrows, Richard W. (Conifer, CO)

1993-01-01T23:59:59.000Z

250

Microwave impregnation of porous materials with thermal energy storage materials  

DOE Patents [OSTI]

A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

Benson, D.K.; Burrows, R.W.

1993-04-13T23:59:59.000Z

251

Porous Elasticity: Lectures on the elasticity of porous materials as an application of the theory of mixtures  

E-Print Network [OSTI]

of classical porous media models. Chapter 2 introduces the essentials of the theory of mixtures. Chapters 3,4 and 5 exploit the theory of mixtures to formulate various models of porous elastic materials. Chapter 6 is concerned with establishing connections...

Bowen, Ray M.

2014-01-22T23:59:59.000Z

252

Multicomponent Gas Diffusion in Porous Electrodes  

E-Print Network [OSTI]

Multicomponent gas transport is investigated with unprecedented precision by AC impedance analysis of porous YSZ anode-supported solid oxide fuel cells. A fuel gas mixture of H2-H2O-N2 is fed to the anode, and impedance data are measured across the range of hydrogen partial pressure (10-100%) for open circuit conditions at three temperatures (800C, 850C and 900C) and for 300mA applied current at 800C. For the first time, analytical formulae for the diffusion resistance (Rb) of three standard models of multicomponent gas transport (Fick, Stefan-Maxwell, and Dusty Gas) are derived and tested against the impedance data. The tortuosity is the only fitting parameter since all the diffusion coefficients are known. Only the Dusty Gas model leads to a remarkable data collapse for over twenty experimental conditions, using a constant tortuosity consistent with permeability measurements and the Bruggeman relation. These results establish the accuracy of the Dusty Gas model for multicomponent gas diffusion in porous med...

Fu, Yeqing; Dutta, Abhijit; Mohanram, Aravind; Pietras, John D; Bazant, Martin Z

2014-01-01T23:59:59.000Z

253

Surface tension of a Lennard-Jones liquid under supersaturation Songnian He and Phil Attard*  

E-Print Network [OSTI]

Surface tension of a Lennard-Jones liquid under supersaturation Songnian He and Phil Attard* School A formally exact Kirkwood­Buff virial formula for the surface tension of a supersaturated interface-vapor interface. The Kirkwood­Buff results for the supersaturated surface tension are found to be in reasonable

Attard, Phil

254

Human-computer interface  

DOE Patents [OSTI]

The present invention provides a method of human-computer interfacing. Force feedback allows intuitive navigation and control near a boundary between regions in a computer-represented space. For example, the method allows a user to interact with a virtual craft, then push through the windshield of the craft to interact with the virtual world surrounding the craft. As another example, the method allows a user to feel transitions between different control domains of a computer representation of a space. The method can provide for force feedback that increases as a user's locus of interaction moves near a boundary, then perceptibly changes (e.g., abruptly drops or changes direction) when the boundary is traversed.

Anderson, Thomas G.

2004-12-21T23:59:59.000Z

255

Safetygram #9- Liquid Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

256

Quantification of Liquid Water Saturation in a PEM Fuel Cell Diffusion Medium Using X-ray Microtomography  

E-Print Network [OSTI]

Quantification of Liquid Water Saturation in a PEM Fuel Cell Diffusion Medium Using X understanding of the two-phase flow and flooding occurrence in proton exchange membrane PEM fuel cells. We have as ice formation during cold start of PEM fuel cells. The water present in these porous layers

257

Wetting and strength issues at Al/alpha-alumina interfaces  

SciTech Connect (OSTI)

The wetting behavior and strength at aluminum/alumina interfaces has been an active subject of research. Al/alumina applications include ceramic-metal composites and several applications for electronic industries. In this paper the interface strength and microstructure of Al/alpha-alumina was investigated. We discovered that in a solid-state joining, the strength of the joint increases with increasing joining temperature. In a liquid-state joining, the strength of the joint gradually decreases due to the formation of unbonded areas. The strength, sigma sub b, is expressed by the following equation as a function of unbonded area, A: sigma sub b = 2.22 A + 143 (70 percent {le} A {le} 100 percent). The highest strength reached 400 MPa when the interface was formed at around the melting temperature of aluminum. An aluminum layer close to the interface became a single crystal when it was bonded to a sapphire. The following crystallographic orientation relationship is established: (1{bar 1}1){sub Al}//(001){sub {alpha}}-Al{sub 2} O{sub 3}, (110){sub Al}//<100>{sub {alpha}}-Al{sub 2}O{sub 3}. Amorphous alumina islands were formed at the interface. In the amorphous alumina, gamma-alumina nanocrystals grew from the sapphire, with the same orientation relationship to sapphire as above.

Saiz, Eduardo; Tomsia, Antoni P.; Suganuma, Katsuaki

2003-04-15T23:59:59.000Z

258

A Semi-Empirical Model for Porous Media Heat Exchanger Design Richard A. Wirtz1  

E-Print Network [OSTI]

and the effectiveness of the porous wall are always maximum when it is operated with the number of transfer units of the porous matrix greater than two (ntu 2). Furthermore, if the porous matrix is composed of a packed bed matrix is minimum when ntu 2. This suggest that for many design requirements, the porous media exchanger

Wirtz, Richard A.

259

Macrodispersivity tensor for nonreactive solute transport in isotropic and anisotropic fractal porous media  

E-Print Network [OSTI]

porous media: Analytical solutions Hongbin Zhan1 and Stephen W. Wheatcraft Hydrology/Hydrogeology Program

Zhan, Hongbin

260

AIDP -Apple Interface Design Project  

E-Print Network [OSTI]

AIDP - Apple Interface Design Project AIDP - Apple Interface Design Project m 92-95 m Joy Mountford m Design Centre, Advanced Technology Group m Apple's Industrial Design Group "Encourage ProjectThe Project m Bridge the gulf between the physical and virtual worlds - Apple m Design a new way

Tollmar, Konrad

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Interface physics in microporous media : LDRD final report.  

SciTech Connect (OSTI)

This document contains a summary of the work performed under the LDRD project entitled 'Interface Physics in Microporous Media'. The presence of fluid-fluid interfaces, which can carry non-zero stresses, distinguishes multiphase flows from more readily understood single-phase flows. In this work the physics active at these interfaces has been examined via a combined experimental and computational approach. One of the major difficulties of examining true microporous systems of the type found in filters, membranes, geologic media, etc. is the geometric uncertainty. To help facilitate the examination of transport at the pore-scale without this complication, a significant effort has been made in the area of fabrication of both two-dimensional and three-dimensional micromodels. Using these micromodels, multiphase flow experiments have been performed for liquid-liquid and liquid-gas systems. Laser scanning confocal microscopy has been utilized to provide high resolution, three-dimensional reconstructions as well as time resolved, two-dimensional reconstructions. Computational work has focused on extending lattice Boltzmann (LB) and finite element methods for probing the interface physics at the pore scale. A new LB technique has been developed that provides over 100x speed up for steady flows in complex geometries. A new LB model has been developed that allows for arbitrary density ratios, which has been a significant obstacle in applying LB to air-water flows. A new reduced order model has been developed and implemented in finite element code for examining non-equilibrium wetting in microchannel systems. These advances will enhance Sandia's ability to quantitatively probe the rich interfacial physics present in microporous systems.

Yaklin, Melissa A.; Knutson, Chad E.; Noble, David R.; Aragon, Alicia R.; Chen, Ken Shuang; Giordano, Nicholas J. (Purdue University, West Lafayette, IN); Brooks, Carlton, F.; Pyrak-Nolte, Laura J. (Purdue University, West Lafayette, IN); Liu, Yihong (Purdue University, West Lafayette, IN)

2008-09-01T23:59:59.000Z

262

Photophysics and photoredox processes at liquid-liquid interfaces. Progress report, April 1, 1990--September 1992  

SciTech Connect (OSTI)

This report is divided into four sections: (1) Recent work on polymers with covalently bound chromophores, primarily involving triplet state electron transfer quenching; (2) Pyrene and pyrene butyric acid adsorbed onto polystyrene latexes (microspheres); (3) Adsorption and micellization of amphiphilic block polymers with chromophores at the junction between the hydrophobic and hydrophilic part; (4) Adsorption of alternating polymers with grafted ``combs`` to improve adsorption onto a hydrophobic surface.

Webber, S.E.

1992-09-01T23:59:59.000Z

263

Ultrathin Polypeptide Multilayer Films for the Fabrication of Model Liquid/Liquid Electrochemical Interfaces  

E-Print Network [OSTI]

in ion selective electrodes, and the mechanisms of phase transfer catalysis reactions.1-3 Electrochemical/L electrochemical research has been performed previously in which one of the two phases was replaced by either agar on a graphite electrode immersed in an aqueous solution for the study of electron transfer across this L/L (film

264

Towards improved methods for determining porous media multiphase flow functions  

E-Print Network [OSTI]

to the empirical relation by using the three-dimensional saturation and relaxation data. 7 CHAPTER II ESTIMATION OF POROUS MEDIA FLOW FUNCTIONS Multiphase flow functions are required to simulate the flow of multiple fluid phases through porous media....3) Snw + Sw = 1: (2.4) Together with boundary and initial conditions, Eqs. (2.1)-(2.4) provide a mathemat- ical model of three-dimensional, two-phase fluid flow in porous media. Several properties have to be specified in the above model. The densities...

Xue, Song

2004-09-30T23:59:59.000Z

265

Rapid process for producing transparent, monolithic porous glass  

DOE Patents [OSTI]

A process for making transparent porous glass monoliths from gels. The glass is produced much faster and in much larger sizes than present technology for making porous glass. The process reduces the cost of making large porous glass monoliths because: 1) the process does not require solvent exchange nor additives to the gel to increase the drying rates, 2) only moderate temperatures and pressures are used so relatively inexpensive equipment is needed, an 3) net-shape glass monoliths are possible using this process. The process depends on the use of temperature to control the partial pressure of the gel solvent in a closed vessel, resulting in controlled shrinking during drying.

Coronado, Paul R. (Livermore, CA)

2006-02-14T23:59:59.000Z

266

Theory of Sound Propagation in Superfluid Solutions Filled Porous Media  

E-Print Network [OSTI]

A theory of the propagation of acoustic waves in a porous medium filled with superfluid solution is developed. The elastic coefficients in the system of equations are expressed in terms of physically measurable quantities. The equations obtained describe all volume modes that can propagate in a porous medium saturated with superfluid solution. Finally, derived equations are applied to the most important particular case when the normal fluid component is locked inside a highly porous media (aerogel) by viscous forces and the velocities of two longitudinal sound modes are calculated.

Sh. E. Kekutia; N. D. Chkhaidze

2005-02-10T23:59:59.000Z

267

The porous atmosphere of eta Carinae  

E-Print Network [OSTI]

We analyze the wind generated by the great 20 year long super-Eddington outburst of eta-Carinae. We show that using classical stellar atmospheres and winds theory, it is impossible to construct a consistent wind model in which a sufficiently small amount of mass, like the one observed, is shed. One expects the super-Eddington luminosity to drive a thick wind with a mass loss rate substantially higher than the observed one. The easiest way to resolve the inconsistency is if we alleviate the implicit notion that atmospheres are homogeneous. An inhomogeneous atmosphere, or "porous", allows more radiation to escape while exerting a smaller average force. Consequently, such an atmosphere yields a considerably lower mass loss rate for the same total luminosity. Moreover, all the applications of the Eddington Luminosity as a strict luminosity limit should be revised, or at least reanalyzed carefully.

Nir J. Shaviv

2000-02-09T23:59:59.000Z

268

Flow in porous media, phase and ultralow interfacial tensions: Mechanisms of enhanced petroleum recovery  

SciTech Connect (OSTI)

A major program of university research, longer-ranged and more fundamental in approach than industrial research, into basic mechanisms of enhancing petroleum recovery and into underlying physics, chemistry, geology, applied mathematics, computation, and engineering science has been built at Minnesota. The original focus was surfactant-based chemical flooding, but the approach taken was sufficiently fundamental that the research, longer-ranged than industrial efforts, has become quite multidirectional. Topics discussed are volume controlled porosimetry; fluid distribution and transport in porous media at low wetting phase saturation; molecular dynamics of fluids in ultranarrow pores; molecular dynamics and molecular theory of wetting and adsorption; new numerical methods to handle initial and boundary conditions in immiscible displacement; electron microscopy of surfactant fluid microstructure; low cost system for animating liquid crystallites viewed with polarized light; surfaces of constant mean curvature with prescribed contact angle.

Davis, H.T.; Scriven, L.E.

1991-07-01T23:59:59.000Z

269

Subgrid analysis of liquid jet atomization J. Chesnel a,  

E-Print Network [OSTI]

viscosity scale similarity models are tested against the prevalent ones. It appears that, contrary and Sprays November 29, 2010 hal-00573786,version1-4Mar2011 #12;Nomenclature Roman letters n Normal vector Liquid/gas interface curvature µ Local dynamic viscosity ls Level-set function vof Volume Of Fluid (VOF

Paris-Sud XI, Université de

270

Liquid and liquid–gas flows at all speeds  

SciTech Connect (OSTI)

All speed flows and in particular low Mach number flow algorithms are addressed for the numerical approximation of the Kapila et al. [1] multiphase flow model. This model is valid for fluid mixtures evolving in mechanical equilibrium but out of temperature equilibrium and is efficient for material interfaces computation separating miscible and non-miscible fluids. In this context, the interface is considered as a numerically diffused zone, captured as well as all present waves (shocks, expansion waves). The same flow model can be used to solve cavitating and boiling flows [2]. Many applications occurring with liquid–gas interfaces and cavitating flows involve a very wide range of Mach number, from 10{sup ?3} to supersonic (and even hypersonic) conditions with respect to the mixture sound speed. It is thus important to address numerical methods free of restrictions regarding the Mach number. To do this, a preconditioned Riemann solver is built and embedded into the Godunov explicit scheme. It is shown that this method converges to exact solutions but needs too small time steps to be efficient. An implicit version is then derived, first in one dimension and second in the frame of 2D unstructured meshes. Two-phase flow preconditioning is then addressed in the frame of the Saurel et al. [3] algorithm. Modifications of the preconditioned Riemann solver are needed and detailed. Convergence of both single phase and two-phase numerical solutions are demonstrated with the help of single phase and two-phase steady nozzle flow solutions. Last, the method is illustrated by the computation of real cavitating flows in Venturi nozzles. Vapour pocket size and instability frequencies are reproduced by the model and method without using any adjustable parameter.

LeMartelot, S., E-mail: sebastien.lemartelot@polytech.univ-mrs.fr [Polytech'Marseille, Aix-Marseille University, UMR CNRS 7343 IUSTI, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France); Nkonga, B., E-mail: boniface.nkonga@unice.fr [RS2N, Bastidon de la Caou, 13360 Roquevaire (France); University of Nice, LJAD UMR CNRS 7351, Parc Valrose, 06108 Nice Cedex (France); Saurel, R., E-mail: richard.saurel@polytech.univ-mrs.fr [Polytech'Marseille, Aix-Marseille University, UMR CNRS 7343 IUSTI, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France); RS2N, Bastidon de la Caou, 13360 Roquevaire (France); University Institute of France, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France)

2013-12-15T23:59:59.000Z

271

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, Albert P. (Vernon, CT)

1986-01-01T23:59:59.000Z

272

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, A.P.

1984-02-21T23:59:59.000Z

273

Uncertainty quantification using multiscale methods for porous media flows  

E-Print Network [OSTI]

numerical models. When solving the flow and transport through heterogeneous porous media some type of upscaling or coarsening is needed due to scale disparity. We describe multiscale techniques used for solving the spatial component of the stochastic flow...

Dostert, Paul Francis

2009-05-15T23:59:59.000Z

274

Colloid-facilitated radionuclide transport in fractured porous rock  

E-Print Network [OSTI]

Numerical methods have been applied for the prediction of colloid-facilitated radionuclide transport through water-saturated fractured porous rock. The presence of colloids may enhance the transport of radionuclides in groundwater by reducing...

Baek, Inseok

1994-01-01T23:59:59.000Z

275

Effective hydraulic conductivity of bounded, strongly heterogeneous porous media  

E-Print Network [OSTI]

Effective hydraulic conductivity of bounded, strongly heterogeneous porous media Evangelos K of Arizona, Tucson Abstract. We develop analytical expressions for the effective hydraulic conductivity Ke boundaries. The log hydraulic conductivity Y forms a Gaussian, statistically homogeneous and anisotropic

Tartakovsky, Daniel M.

276

Ultrasonic measurement of porous medium in an aqueous environment  

E-Print Network [OSTI]

The use of a medical ultrasonic scanning device was studied as a measuring tool for determining the physical characteristics of soft porous media in an turbid aqueous environment. Three different sponge types were used as the soft objects. A method...

Daubon, Jose C

1995-01-01T23:59:59.000Z

277

Gasification and combustion modeling for porous char particles  

E-Print Network [OSTI]

Gasification and combustion of porous char particles occurs in many industrial applications. Reactor-scale outputs of importance depend critically on processes that occur at the particle-scale. Because char particles often ...

Singer, Simcha Lev

2012-01-01T23:59:59.000Z

278

Overlimiting Current and Shock Electrodialysis in Porous Media  

E-Print Network [OSTI]

Most electrochemical processes, such as electrodialysis, are limited by diffusion, but in porous media, surface conduction and electroosmotic flow also contribute to ionic flux. In this article, we report experimental ...

Deng, Daosheng

279

Functionalization/passivation of porous graphitic carbon with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

data are also presented. Citation: Jensen DS, V Gupta, RE Olsen, AT Miller, RC Davis, D Ess, Z Zhu, MA Vail, A Dadson, and MR Linford.2011."Functionalizationpassivation of porous...

280

Carbide-derived carbons - From porous networks to nanotubes and...  

Office of Scientific and Technical Information (OSTI)

Carbide-derived carbons - From porous networks to nanotubes and graphene Re-direct Destination: Carbide-derived carbons (CDCs) are a large family of carbon materials derived from...

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Field emission study of cobalt ion implanted porous silicon  

E-Print Network [OSTI]

Porous silicon has become potentially important material for microelectronics applications. By using low energy implantation and energy scan implantation, a stable silicide with good electrical conductivity can be formed, and can be used...

Liu, Hongbiao

1995-01-01T23:59:59.000Z

282

Simulation of filtration for suspension transport in porous media  

E-Print Network [OSTI]

This thesis describes the development and application of a novel method for analyzing the filtration of particles transported through a granular porous medium. The proposed analysis considers the deposition of particles ...

Kim, Yun Sung, 1974-

2005-01-01T23:59:59.000Z

283

The evolution of miscible gravity currents in horizontal porous layers  

E-Print Network [OSTI]

Gravity currents of miscible fluids in porous media are important to understand because they occur in important engineering projects, such as enhanced oil recovery and geologic CO[subscript 2] sequestration. These flows ...

Szulczewski, Michael Lawrence

284

Vortex development behind a finite porous obstruction in a channel  

E-Print Network [OSTI]

This experimental study describes the turbulent wake behind a two-dimensional porous obstruction, consisting of a circular array of cylinders. The cylinders extend from the channel bed through the water surface, mimicking ...

Zong, Lijun

285

Experimental design for study of nucleate boiling in porous structures  

E-Print Network [OSTI]

The superheat required to initiate nucleate boiling inside porous wicks is not well understood in practice. This thesis reports the design of an experimental setup for investigating the onset of vapor nucleation in sintered ...

Kelley, Mitchell Joseph

2011-01-01T23:59:59.000Z

286

Liquid Hydrogen Absorber for MICE  

E-Print Network [OSTI]

REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

Ishimoto, S.

2010-01-01T23:59:59.000Z

287

Chemistry & Physics at Interfaces | Advanced Materials | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Materials Home | Science & Discovery | Advanced Materials | Research Areas | Chemistry and Physics at Interfaces SHARE Chemistry and Physics at Interfaces Chemical...

288

Porous solid ion exchange wafer for immobilizing biomolecules  

DOE Patents [OSTI]

A porous solid ion exchange wafer having a combination of a biomolecule capture-resin and an ion-exchange resin forming a charged capture resin within said wafer. Also disclosed is a porous solid ion exchange wafer having a combination of a biomolecule capture-resin and an ion-exchange resin forming a charged capture resin within said wafer containing a biomolecule with a tag. A separate bioreactor is also disclosed incorporating the wafer described above.

Arora, Michelle B. (Woodridge, IL); Hestekin, Jamie A. (Morton Grove, IL); Lin, YuPo J. (Naperville, IL); St. Martin, Edward J. (Libertyville, IL); Snyder, Seth W. (Lincolnwood, IL)

2007-12-11T23:59:59.000Z

289

Nuclear magnetic resonance study of methane adsorbed on porous silicon  

E-Print Network [OSTI]

NUCLEAR MAGNETIC RESONANCE STUDY OF METHANE ADSORBED ON POROUS SILICON A Thesis by FENG I I Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... May 1992 Major Subject: Physics NUCLEAR MAGNETIC RESONANCE STUDY OF METHANE ADSORBED ON POROUS SILICON A Thesis by FENG LI Approved as to style and content by: . P. Kirk (Chair of Committee) i G. Agnolet (Member) J. H. Ross, r (Member) M...

Li, Feng

1992-01-01T23:59:59.000Z

290

The study of methane adsorbed on porous silicon by NMR  

E-Print Network [OSTI]

THE STUDY OF METHANE ADSORBED ON POROUS SILICON BY NMR A Thesis by ADAM KAZIMIERZ CZERMAK Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1986... Major Subject: Physics THE STUDY OF METHANE ADSORBED ON POROUS SILICON BY NMR A Thesis by ADAM KAZIMIERZ CZERMAK Approved as to style and content by: e Wile . Kirk (Chairman of Committee) J eevak M. Par pi a (Member) Randall L. Geiger...

Czermak, Adam Kazimierz

1986-01-01T23:59:59.000Z

291

Two dimensional properties of methane adsorbed on porous silicon  

E-Print Network [OSTI]

TWO DIMENSIONAL PROPERTIES OF METHANE ADSORBED ON POROUS SILICON A Thesis by RICHARD FRANKLIN TENNIS Submitted to the Office of Graduate Studies of Texas ASM University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 1989 Major Subject: Physics TWO DIMENSIONAL PROPERTIES OF METHANE ADSORBED ON POROUS SILICON A Thesis by RICHARD FRANKLIN TENNIS Approved as to style and content by: P. Kirk (C ir of Committee) Glenn olet (M er) Da J. Ernst...

Tennis, Richard Franklin

1989-01-01T23:59:59.000Z

292

An overview of instability and fingering during immiscible fluid flow in porous and fractured media  

SciTech Connect (OSTI)

Wetting front instability is an important phenomenon affecting fluid flow and contaminant transport in unsaturated soils and rocks. It causes the development of fingers which travel faster than would a uniform front and thus bypass much of the medium. Water saturation and solute concentration in such fingers tend to be higher than in the surrounding medium. During infiltration, fingering may cause unexpectedly rapid arrival of water and solute at the water-table. This notwithstanding, most models of subsurface flow and transport ignore instability and fingering. In this report, we survey the literature to assess the extent to which this may or may not be justified. Our overview covers experiments, theoretical studies, and computer simulations of instability and fingering during immiscible two-phase flow and transport, with emphasis on infiltration into soils and fractured rocks. Our description of instability in an ideal fracture (Hele-Shaw cell) includes an extension of existing theory to fractures and interfaces having arbitrary orientations in space. Our discussion of instability in porous media includes a slight but important correction of existing theory for the case of an inclined interface. We conclude by outlining some potential directions for future research. Among these, we single out the effect of soil and rock heterogeneities on instability and preferential flow as meriting special attention in the context of nuclear waste storage in unsaturated media.

Chen, G.; Neuman, S.P. [Univ. of Arizona, Tucson, AZ (United States). Dept. of Hydrology and Water Resources; Taniguchi, M. [Nara Univ. of Education (Japan). Dept. of Earth Sciences

1995-04-01T23:59:59.000Z

293

Journal of Colloid and Interface Science 257 (2003) 8592 www.elsevier.com/locate/jcis  

E-Print Network [OSTI]

,a Jacob Masliyah,b and Dongqing Li a, a Department of Mechanical and Industrial Engineering, University to obtain the current­time relationship, which is used in the model to predict the location of the interface were used as the testing liquids. Polyamide-coated silica capillary tubes of internal diameter 100 µm

Le Roy, Robert J.

294

On the physics of moisture-induced cracking in metal-glass ,,copper-silica... interfaces  

E-Print Network [OSTI]

September 2007 Environmentally dependent subcritical crack growth, or stress-corrosion cracking, along on the moisture content in gaseous environments. Water and several organic liquids, namely n-butanol, methanol, additionally, subcritical crack growth17 and cyclically induced fracture18 at or near these interfaces when

Ritchie, Robert

295

Interfacing to the Programmer's Apprentice  

E-Print Network [OSTI]

In this paper, we discuss the design of a user interface to the Knowledge Based Editor (KBE), a prototype implementation of the Programmer's Apprentice. Although internally quite sophisticated, the KBE hides most of its ...

Pitman, Kent

296

Guidance Document Cryogenic Liquids  

E-Print Network [OSTI]

with air. Liquid carbon monoxide is extremely toxic and extremely flammable. #12;Cryogenic liquids connecting cylinder to lower pressure piping or systems. 6. Use a check valve or trap in the discharge line

297

Monodisperse porous polymer particles containing macrocyclic ether as a new class of sorbent for SR(II) separation  

SciTech Connect (OSTI)

Strontium{sup 90} is one of the typical fission products that may be found in high level liquid waste (HLLW). Separation of Sr{sup 90} prior to the vitrification is beneficial to the final treatment of solid radioactive waste. In this study, a new class of sorbent for Sr(II) was developed by loading the macrocyclic ether DtBuCH18C6 into the monodisperse porous polymer particles (MPPPs). The MPPPs are well-known as a promising chromatographic material due to the uniform particle size, porous morphology, good compatibility with organic extractants, and rigid matrix. The structure and micro-morphology of the sorbent particles were characterized. The adsorption behavior towards Sr(II) in HNO{sub 3} media was investigated by both batch and column experiments. High adsorption efficiency and selective separation of Sr(II) was obtained. The sorbent particles can be recycled for at least several times before obvious lose of the adsorption ability. This kind of sorbent possesses the potential to be used for strontium separation in radioactive liquid waste.

Leng, Yuxiao; Bai, Feifei [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Faculty of Chemical Science and Engineering, China University of Petroleum, Beijing 100084 (China); Ye, Gang; Wei, Jichao; Wang, Jianchen; Chen, Jing [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China)

2013-07-01T23:59:59.000Z

298

Equation for liquid density  

SciTech Connect (OSTI)

Saturated liquid densities for organic chemicals are given as functions of temperature using a modified Rackett equation.

Yaws, C.L.; Yang, H.C.; Hopper, J.R.; Cawley, W.A. (Lamar Univ., Beaumont, TX (US))

1991-01-01T23:59:59.000Z

299

Liquid detection circuit  

DOE Patents [OSTI]

Herein is a circuit which is capable of detecting the presence of liquids, especially cryogenic liquids, and whose sensor will not overheat in a vacuum. The circuit parameters, however, can be adjusted to work with any liquid over a wide range of temperatures.

Regan, Thomas O. (North Aurora, IL)

1987-01-01T23:59:59.000Z

300

Surfactant-induced rigidity of interfaces: a unified approach to free and dip-coated films  

E-Print Network [OSTI]

The behavior of thin liquid films is known to be strongly affected by the presence of surfactants at the interfaces. The detailed mechanism by which the latter enhance film stability is still a matter of debate, in particular concerning the influence of surface elastic effects on the hydrodynamic boundary condition at the liquid/air interfaces. In the present work, "twin" hydrodynamic models neglecting surfactant transport to the interfaces are proposed to describe the coating of films onto a solid plate (Landau-Levich-Derjaguin configuration) as well as soap film pulling (Frankel configuration). Experimental data on the entrained film thickness in both configurations can be fitted very well using a single value of the surface elasticity, which is in good agreement with independent measurements by mean of surface expansion experiments in a Langmuir through. The analysis shows how and when the soap films or dip coating experiments may be used to precisely and sensitively measure the surface elasticity of surfactant solutions.

Lorène Champougny; Benoit Scheid; Frédéric Restagno; Jan Vermant; Emmanuelle Rio

2014-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Liquid Metal Transformers  

E-Print Network [OSTI]

The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

Sheng, Lei; Liu, Jing

2014-01-01T23:59:59.000Z

302

Hybrid user interfaces : design guidelines and implementation examples  

E-Print Network [OSTI]

A hybrid user interface is a new type of computer user interface that achieves high usability by combining features of graphical user interfaces and command line interfaces. The main goal of a hybrid user interface is to ...

Ahn, Sehyun

2006-01-01T23:59:59.000Z

303

Porous platinum-based catalysts for oxygen reduction  

DOE Patents [OSTI]

A porous metal that comprises platinum and has a specific surface area that is greater than 5 m.sup.2/g and less than 75 m.sup.2/g. A fuel cell includes a first electrode, a second electrode spaced apart from the first electrode, and an electrolyte arranged between the first and the second electrodes. At least one of the first and second electrodes is coated with a porous metal catalyst for oxygen reduction, and the porous metal catalyst comprises platinum and has a specific surface area that is greater than 5 m.sup.2/g and less than 75 m.sup.2/g. A method of producing a porous metal according to an embodiment of the current invention includes producing an alloy consisting essentially of platinum and nickel according to the formula Pt.sub.xNi.sub.1-x, where x is at least 0.01 and less than 0.3; and dealloying the alloy in a substantially pH neutral solution to reduce an amount of nickel in the alloy to produce the porous metal.

Erlebacher, Jonah D; Snyder, Joshua D

2014-11-25T23:59:59.000Z

304

On the multi-physics of mass-transfer across fluid interfaces  

E-Print Network [OSTI]

Mass transfer of gaseous components from rising bubbles to the ambient liquid can be described based on continuum mechanical sharp-interface balances of mass, momentum and species mass. In this context, the standard model consists of the two-phase Navier-Stokes equations for incompressible fluids with constant surface tension, complemented by reaction-advection-diffusion equations for all constituents, employing Fick's law. This standard model is inconsistent with the continuity equation, the momentum balance and the second law of thermodynamics. The present paper reports on the details of these severe shortcomings and provides thermodynamically consistent model extensions which are required to capture various phenomena which occur due to the multi-physics of interfacial mass transfer. In particular, we provide a simple derivation of the interface Maxwell-Stefan equations which does not require a time scale separation, while the main contribution is to show how interface concentrations and interface chemical ...

Bothe, Dieter

2015-01-01T23:59:59.000Z

305

PinBus Interface Design  

SciTech Connect (OSTI)

On behalf of the U.S. Department of Energy, PNNL has explored and expanded upon a simple control interface that might have merit for the inexpensive communication of smart grid operational objectives (demand response, for example) to small electric end-use devices and appliances. The approach relies on bi-directional communication via the electrical voltage states of from one to eight shared interconnection pins. The name PinBus has been suggested and adopted for the proposed interface protocol. The protocol is defined through the presentation of state diagrams and the pins’ functional definitions. Both simulations and laboratory demonstrations are being conducted to demonstrate the elegance and power of the suggested approach. PinBus supports a very high degree of interoperability across its interfaces, allowing innumerable pairings of devices and communication protocols and supporting the practice of practically any smart grid use case.

Hammerstrom, Donald J.; Adgerson, Jewel D.; Sastry, Chellury; Pratt, Richard M.; Pratt, Robert G.

2009-12-30T23:59:59.000Z

306

Multi-robot control interface  

DOE Patents [OSTI]

Methods and systems for controlling a plurality of robots through a single user interface include at least one robot display window for each of the plurality of robots with the at least one robot display window illustrating one or more conditions of a respective one of the plurality of robots. The user interface further includes at least one robot control window for each of the plurality of robots with the at least one robot control window configured to receive one or more commands for sending to the respective one of the plurality of robots. The user interface further includes a multi-robot common window comprised of information received from each of the plurality of robots.

Bruemmer, David J. (Idaho Falls, ID); Walton, Miles C. (Idaho Falls, ID)

2011-12-06T23:59:59.000Z

307

An experimental measurement of the thermal conductivity and diffusivity of a porous solid-liquid system  

E-Print Network [OSTI]

to contain the sample for the flow rate measurement. 1. Air Supply 2 ~ Vacuun Line 3. Waste Line 4 ~ Surge Tank 5. Water Reservoir 6. Oil Reservoir Test Specinsn 8. Pressure Regulator Valve SATURATION APPARATUS FCR SATURATI?l SARDSTONR TXSP... the system can be described by' the one h dimensional form of Fouriers dT Equation: Q ~ -!:. A ? . ds The quantity of heat flowing through the oil and water in the pore dT space is OCk! ~ K A& ( ? ) + Kp AC (~)C ~ Based on the unidirectional W & d...

Dunn, James Elliott

1959-01-01T23:59:59.000Z

308

Syngas production from heavy liquid fuel reforming in inert porous media  

E-Print Network [OSTI]

-up), but it will still show a significant efficiency advantage [2]. Eventually, when fuel cells and hydrogen demand will build up, a switch can be made to central hydrogen production, by using fossil sources with CO2 sequestration and finally by the use of low carbon... requirements: • Hydrogen production levels smaller than those in chemical plants; • Severe constraints on size and weight; • Ability to cycle through frequent start-ups and shutdowns; • Hydrogen production rate should be responsive to changes in demand...

Pastore, Andrea

2010-11-16T23:59:59.000Z

309

Physically and chemically stable ionic liquid-infused textured surfaces showing excellent dynamic omniphobicity  

SciTech Connect (OSTI)

A fluorinated and hydrophobic ionic liquid (IL), 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide, effectively served as an advantageous lubricating liquid for the preparation of physically and chemically stable omniphobic surfaces based on slippery liquid-infused porous surfaces. Here, we used particulate microstructures as supports, prepared by the chemical vapor deposition of 1,3,5,7-tetramethylcyclotetrasiloxane and subsequent surface modification with (3-aminopropyl)triethoxysilane. Confirmed by SEM and contact angle measurements, the resulting IL-infused microtextured surfaces are smooth and not only water but also various low surface tension liquids can easily slide off at low substrate tilt angles of <5°, even after exposure to high temperature, vacuum, and UV irradiation.

Miranda, Daniel F.; Urata, Chihiro; Masheder, Benjamin; Dunderdale, Gary J.; Hozumi, Atsushi, E-mail: a.hozumi@aist.go.jp [National Institute of Advanced Industrial Science and Technology (AIST), 2266-98, Anagahora, Shimo-Shidami, Moriyama-ku, Nagoya, Aichi 463-8560 (Japan); Yagihashi, Makoto [Nagoya Municipal Industrial Research Institute, Rokuban, Atsuta-ku, Nagoya 456-0058 (Japan)

2014-05-01T23:59:59.000Z

310

User interfaces to expert systems  

SciTech Connect (OSTI)

Expert Systems are becoming increasingly popular in environments where the user is not well versed in computers or the subject domain. They offer expert advice and can also explain their lines of reasoning. As these systems are applied to highly technical areas, they become complex and large. Therefore, User Systems Interfaces (USIs) become critical. This paper discusses recent technologies that can be applied to improved user communication. In particular, bar menus/graphics, mouse interfaces, touch screens, and voice links will be highlighted. Their applications in the context of SOFTMAN (The Software Manager Apprentice) a knowledge-based system are discussed. 18 refs., 2 figs.

Agarwal, A.; Emrich, M.L.

1988-10-01T23:59:59.000Z

311

Interface Compilation: Steps toward Compiling Program Interfaces as Languages  

E-Print Network [OSTI]

systems, programmers are limited to writing code, while the power to transform the code has been reserved Magik gives to programmers enables a broad class of optimization and code transformations. This paper's data structures and internally), operations on this state (defined by the interface's procedures

Engler, Dawson

312

Flow adjustment and interior flow associated with a rectangular porous obstruction  

E-Print Network [OSTI]

The flow at the leading edge and in the interior of a rectangular porous obstruction is described through experiments and scaling. The porous obstruction consists of an emergent, rectangular array of cylinders in shallow ...

Rominger, Jeffrey Tsaros

313

Discrete particle transport in porous media : discrete observations of physical mechanisms influencing particle behavior  

E-Print Network [OSTI]

An understanding of how discrete particles in the micron to submicron range behave in porous media is important to a number of environmental problems. Discrete particle behavior in the interior of a porous medium is complex ...

Yoon, Joon Sik, 1973-

2005-01-01T23:59:59.000Z

314

NERSC Analysis of Void Space of Porous Materials Used in Energy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Porous Materials Analysis of Void Space of Porous Materials Used in Energy-related Applications fmm-smmaciek.jpg We have developed partial differential equations-based tools that...

315

Phenomenological study of Au and Pt nanowires grown in porous alumina scaffolds  

E-Print Network [OSTI]

Porous anodic aluminum oxide, commonly known as AAO, has been widely used as a scaffold to synthesize nanowires and nanotubes. The porous alumina structure can be obtained from a simple electrochemical oxidation process, ...

Shin, Yong Cheol, S.M. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

316

Highly porous chemically modified carbon cryogels and their coherent nanocomposites for energy applications  

E-Print Network [OSTI]

the pores, porous media for natural gas (methane) storage at reduced pressure, and scaffolds for hydride the pores, porous media for natural gas (m of Mechanical Science and Engineering, Huazhong University of Science & Technology, Wuhan, 430074, China d

Cao, Guozhong

317

Thin Porous Metal Sheet-Supported NaA Zeolite Membrane for Water...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thin Porous Metal Sheet-Supported NaA Zeolite Membrane for WaterEthanol Separation. Thin Porous Metal Sheet-Supported NaA Zeolite Membrane for WaterEthanol Separation. Abstract:...

318

Study of gas flow dynamics in porous and granular media with laser-polarized ¹²?Xe NMR  

E-Print Network [OSTI]

This thesis presents Nuclear Magnetic Resonance (NMR) studies of gas flow dynamics in porous and granular media by using laser-polarized ¹²?Xe . Two different physical processes, the gas transport in porous rock cores and ...

Wang, Ruopeng, 1972-

2005-01-01T23:59:59.000Z

319

Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li-Ion Battery Anodes. Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li-Ion Battery Anodes. Abstract:...

320

Sum Frequency Generation Vibrational Spectroscopy of Adsorbed Amino Acids, Peptides and Proteins of Hydrophilic and Hydrophobic Solid-Water Interfaces  

SciTech Connect (OSTI)

Sum frequency generation (SFG) vibrational spectroscopy was used to investigate the interfacial properties of several amino acids, peptides, and proteins adsorbed at the hydrophilic polystyrene solid-liquid and the hydrophobic silica solid-liquid interfaces. The influence of experimental geometry on the sensitivity and resolution of the SFG vibrational spectroscopy technique was investigated both theoretically and experimentally. SFG was implemented to investigate the adsorption and organization of eight individual amino acids at model hydrophilic and hydrophobic surfaces under physiological conditions. Biointerface studies were conducted using a combination of SFG and quartz crystal microbalance (QCM) comparing the interfacial structure and concentration of two amino acids and their corresponding homopeptides at two model liquid-solid interfaces as a function of their concentration in aqueous solutions. The influence of temperature, concentration, equilibration time, and electrical bias on the extent of adsorption and interfacial structure of biomolecules were explored at the liquid-solid interface via QCM and SFG. QCM was utilized to quantify the biological activity of heparin functionalized surfaces. A novel optical parametric amplifier was developed and utilized in SFG experiments to investigate the secondary structure of an adsorbed model peptide at the solid-liquid interface.

Holinga IV, G.H.

2010-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Porous siliconformation and etching process for use in silicon micromachining  

DOE Patents [OSTI]

A reproducible process for uniformly etching silicon from a series of micromechanical structures used in electrical devices and the like includes providing a micromechanical structure having a silicon layer with defined areas for removal thereon and an electrochemical cell containing an aqueous hydrofluoric acid electrolyte. The micromechanical structure is submerged in the electrochemical cell and the defined areas of the silicon layer thereon are anodically biased by passing a current through the electrochemical cell for a time period sufficient to cause the defined areas of the silicon layer to become porous. The formation of the depth of the porous silicon is regulated by controlling the amount of current passing through the electrochemical cell. The micromechanical structure is then removed from the electrochemical cell and submerged in a hydroxide solution to remove the porous silicon. The process is subsequently repeated for each of the series of micromechanical structures to achieve a reproducibility better than 0.3%.

Guilinger, Terry R. (Albuquerque, NM); Kelly, Michael J. (Albuquerque, NM); Martin, Jr., Samuel B. (Albuquerque, NM); Stevenson, Joel O. (Albuquerque, NM); Tsao, Sylvia S. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

322

An electrochemical route for making porous nickel oxide electrochemical capacitors  

SciTech Connect (OSTI)

Porous nickel oxide films were prepared by electrochemically precipitating nickel hydroxide and heating the hydroxide in air at 300 C. The resulting nickel oxide films behave as an electrochemical capacitor with a specific capacitance of 59 F/g electrode material. These nickel oxide films maintain high utilization at high rates of discharge (i.e., high power density) and have excellent cycle life. Porous cobalt oxide films were also synthesized. Although the specific capacitances of these films are approximately one-fifth that of the nickel oxide films, the results demonstrate the versatility of fabricating a wide range of porous metal oxide films using this electrochemical route for use in capacitor applications. Electrochemical capacitors have generated wide interest in recent years for use in high power applications (e.g., in a hybrid electric vehicle, where they are expected to work in conjunction with a conventional battery).

Srinivasan, V.; Weidner, J.W. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering

1997-08-01T23:59:59.000Z

323

Method for dialysis on microchips using thin porous polymer membrane  

DOE Patents [OSTI]

Laser-induced phase-separation polymerization of a porous acrylate polymer is used for in-situ fabrication of dialysis membranes inside glass microchannels. A shaped 355 nm laser beam is used to produce a porous polymer membrane with a thickness of about 15 .mu.m, which bonds to the glass microchannel and forms a semi-permeable membrane. Differential permeation through a membrane formed with pentaerythritol triacrylate was observed and quantified by comparing the response of the membrane to fluorescein and fluorescently tagging 200 nm latex microspheres. Differential permeation was observed and quantified by comparing the response to rhodamine 560 and lactalbumin protein in a membrane formed with SPE-methylene bisacrylamide. The porous membranes illustrate the capability for the present technique to integrate sample cleanup into chip-based analysis systems.

Singh, Anup K. (San Francisco, CA); Kirby, Brian J. (San Francisco, CA); Shepodd, Timothy J. (Livermore, CA)

2009-05-19T23:59:59.000Z

324

Dialysis on microchips using thin porous polymer membranes  

DOE Patents [OSTI]

Laser-induced phase-separation polymerization of a porous acrylate polymer is used for in-situ fabrication of dialysis membranes inside glass microchannels. A shaped 355 nm laser beam is used to produce a porous polymer membrane with a thickness of about 15 .mu.m, which bonds to the glass microchannel and form a semi-permeable membrane. Differential permeation through a membrane formed with pentaerythritol triacrylate was observed and quantified by comparing the response of the membrane to fluorescein and fluorescently tagging 200 nm latex microspheres. Differential permeation was observed and quantified by comparing the response to rhodamine 560 and lactalbumin protein in a membrane formed with SPE-methylene bisacrylamide. The porous membranes illustrate the capability for the present technique to integrate sample cleanup into chip-based analysis systems.

Singh, Anup K. (San Francisco, CA); Kirby, Brian J. (San Francisco, CA); Shepodd, Timothy J. (Livermore, CA)

2007-09-04T23:59:59.000Z

325

Anisotropy of flow in stochastically generated porous media  

E-Print Network [OSTI]

Models of porous media are often applied to relatively small systems, which leads not only to system-size-dependent results, but also to phenomena that would be absent in larger systems. Here we investigate one such finite-size effect: anisotropy of the permeability tensor. We show that a non-zero angle between the external body force and macroscopic flux vector exists in three-dimensional periodic models of sizes commonly used in computer simulations and propose a criterion, based on the system size to the grain size ratio, for this phenomenon to be relevant or negligible. The finite-size anisotropy of the porous matrix induces a pressure gradient perpendicular to the axis of a porous duct and we analyze how this effect scales with the system and grain sizes.

Matyka, Maciej; Go?embiewski, Jaros?aw; Kostur, Marcin; Januszewski, Micha?

2013-01-01T23:59:59.000Z

326

Technique for converting non-conforming hexahedral-to-hexahedral interfaces into conforming interfaces  

DOE Patents [OSTI]

A technique for conforming an interface between a first mesh and a second mesh is disclosed. A first interface surface in the first mesh and a second interface surface in the second mesh residing along the interface are identified. The first and second interface surfaces are initially non-conforming along the interface. Chords within the first and second interface surfaces that fall within a threshold separation distance of each other are paired. Sheets having chords that reside within the first or second interface surfaces are recursively inserted into or extracted from one or both of the first and second meshes until all remaining chords within the first interface surface are paired with corresponding chords in the second interface surface and all remaining chords within the second interface surface are paired with corresponding chords in the first interface surface.

Staten, Matthew L.; Shepherd, Jason F.; Ledoux, Frank; Shimada, Kenji; Merkley, Karl G.; Carbonera, Carlos

2013-03-05T23:59:59.000Z

327

Low-frequency dilatational wave propagation through unsaturated porous media containing two immiscible fluids  

E-Print Network [OSTI]

of elastic waves in unconsolidated unsaturated granularfrequency in both unconsolidated and consolidated materialsboth consolidated and unconsolidated porous media, and the

Lo, W.-C.

2009-01-01T23:59:59.000Z

328

Transport in Porous Media 52: 185211, 2003. 2003 Kluwer Academic Publishers. Printed in the Netherlands.  

E-Print Network [OSTI]

in the Netherlands. 185 Wettability Alteration to Intermediate Gas-Wetting in Porous Media at Elevated Temperatures

Firoozabadi, Abbas

329

Transport in Porous Media 57: 125152, 2004. 2004 Kluwer Academic Publishers. Printed in the Netherlands.  

E-Print Network [OSTI]

in the Netherlands. 125 Relative Permeabilities for Strictly Hyperbolic Models of Three-Phase Flow in Porous Media

Patzek, Tadeusz W.

330

Structural and phonon transmission study of Ge-Au-Ge eutectically bonded interfaces  

SciTech Connect (OSTI)

This thesis presents a structural analysis and phonon transparency investigation of the Ge-Au-Ge eutectic bond interface. Interface development was intended to maximize the interfacial ballistic phonon transparency to enhance the detection of the dark matter candidate WIMPs. The process which was developed provides an interface which produces minimal stress, low amounts of impurities, and insures Ge lattice continuity through the interface. For initial Au thicknesses of greater than 1,000 {angstrom} Au per substrate side, eutectic epitaxial growth resulted in a Au dendritic structure with 95% cross sectional and 90% planar Au interfacial area coverages. In sections in which Ge bridged the interface, lattice continuity across the interface was apparent. Epitaxial solidification of the eutectic interface with initial Au thicknesses < 500 A per substrate side produced Au agglomerations thereby reducing the Au planar interfacial area coverage to as little as 30%. The mechanism for Au coalescence was attributed to lateral diffusion of Ge and Au in the liquid phase during solidification. Phonon transmission studies were performed on eutectic interfaces with initial Au thicknesses of 1,000 {angstrom}, 500 {angstrom}, and 300 {angstrom} per substrate side. Phonon imaging of eutectically bonded samples with initial Au thicknesses of 300 {angstrom}/side revealed reproducible interfacial percent phonon transmissions from 60% to 70%. Line scan phonon imaging verified the results. Phonon propagation TOF spectra distinctly showed the predominant phonon propagation mode was ballistic. This was substantiated by phonon focusing effects apparent in the phonon imaging data. The degree of interface transparency to phonons and resulting phonon propagation modes correlate with the structure of the interface following eutectic solidification. Structural studies of samples with initial Au thickness of 1,000 {angstrom}/side appear to correspond with the phonon transmission study.

Knowlton, W.B. [Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Mineral Engineering]|[Lawrence Berkeley Lab., CA (United States). Materials Sciences Div.

1995-07-01T23:59:59.000Z

331

Ultrasonic liquid level detector  

DOE Patents [OSTI]

An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

Kotz, Dennis M. (North Augusta, SC); Hinz, William R. (Augusta, GA)

2010-09-28T23:59:59.000Z

332

Liquid Metal Transformers  

E-Print Network [OSTI]

The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

Lei Sheng; Jie Zhang; Jing Liu

2014-01-30T23:59:59.000Z

333

Liquid Crystal Optofluidics  

SciTech Connect (OSTI)

By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

2012-10-11T23:59:59.000Z

334

(Ionization in liquids)  

SciTech Connect (OSTI)

This document describes charge transport following ionization of model liquids and how this process may be important in carcinogenesis. 15 refs., 2 figs., 4 tabs. (MHB)

Not Available

1991-01-01T23:59:59.000Z

335

Water Quality and Hydrologic Performance of a Porous Asphalt Pavement as a Storm-Water  

E-Print Network [OSTI]

examined the functionality of a porous pavement storm-water management system in coastal New Hampshire headings: Stormwater management; Runoff; Porous media; Pavements; Cold regions; Best Management Practice; Water quality; Water treatment. Author keywords: Storm-water management; Runoff; Porous pavements; Cold

336

Porous silicon with embedded tritium as a stand-alone prime power source for optoelectronic applications  

DOE Patents [OSTI]

Disclosed is an illumination source comprising a porous silicon having a source of electrons on the surface and/or interstices thereof having a total porosity in the range of from about 50 v/o to about 90 v/o. Also disclosed are a tritiated porous silicon and a photovoltaic device and an illumination source of tritiated porous silicon. 1 fig.

Tam, S.W.

1997-02-25T23:59:59.000Z

337

Porous silicon with embedded tritium as a stand-alone prime power source for optoelectronic applications  

DOE Patents [OSTI]

An illumination source comprising a porous silicon having a source of electrons on the surface and/or interticies thereof having a total porosity in the range of from about 50 v/o to about 90 v/o. Also disclosed are a tritiated porous silicon and a photovoltaic device and an illumination source of tritiated porous silicon.

Tam, Shiu-Wing (Downers Grove, IL)

1997-01-01T23:59:59.000Z

338

Porous silicon with embedded tritium as a stand-alone prime power source for optoelectronic applications  

DOE Patents [OSTI]

An illumination source comprising a porous silicon having a source of electrons on the surface and/or interticies thereof having a total porosity in the range of from about 50 v/o to about 90 v/o. Also disclosed are a tritiated porous silicon and a photovoltaic device and an illumination source of tritiated porous silicon.

Tam, Shiu-Wing (Downers Grove, IL)

1998-01-01T23:59:59.000Z

339

Porous silicon with embedded tritium as a stand-alone prime power source for optoelectronic applications  

DOE Patents [OSTI]

An illumination source is disclosed comprising a porous silicon having a source of electrons on the surface and/or interstices thereof having a total porosity in the range of from about 50 v/o to about 90 v/o. Also disclosed are a tritiated porous silicon and a photovoltaic device and an illumination source of tritiated porous silicon. 1 fig.

Tam, S.W.

1998-06-16T23:59:59.000Z

340

On the Effect of Porous Layers on Melting Heat Transfer in an Enclosure  

E-Print Network [OSTI]

On the Effect of Porous Layers on Melting Heat Transfer in an Enclosure E. A. Ellinger* and C. To enhance heat transfer, the porous layers are located in regions where the melting rates for a pure the porous layer and the pure fluid layer cause strong variations in heat transfer, melt convection

Beckermann, Christoph

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

DYNAMICS OF FREE SURFACES IN RANDOM POROUS MEDIA DANIEL M. TARTAKOVSKY AND C. L. WINTER  

E-Print Network [OSTI]

media to be concrete. Predicting flow through natural porous media is complicated by their high degreeDYNAMICS OF FREE SURFACES IN RANDOM POROUS MEDIA DANIEL M. TARTAKOVSKY AND C. L. WINTER SIAM J­1876 Abstract. We consider free surface flow in random porous media by treating hydraulic conduc- tivity

Tartakovsky, Daniel M.

342

A model for reactive porous transport during re-wetting of hardened concrete  

E-Print Network [OSTI]

A model for reactive porous transport during re-wetting of hardened concrete Michael Chapwanya residing in the porous concrete matrix. The main hypothesis in this model is that the reaction product hydration; Porous media; Reaction-diffusion equations; Vari- able porosity. 1. Introduction Concrete

Stockie, John

343

Asymptotical Computations for a Model of Flow in Saturated Porous Media  

E-Print Network [OSTI]

a variably saturated porous medium with exponential diffusivity, such as soil, rock or concrete is given by uAsymptotical Computations for a Model of Flow in Saturated Porous Media P. Amodio a , C.J. Budd b for an implicit second order ordinary differential equation which arises in models of flow in saturated porous

Weinmüller, Ewa B.

344

Imaging biofilm architecture within porous media using synchrotron-based X-ray computed microtomography  

E-Print Network [OSTI]

Imaging biofilm architecture within porous media using synchrotron-based X-ray computed. Wildenschild (2011), Imaging biofilm architecture within porous media using synchrotron-based X-ray computed synchrotron-based X-ray computed microtomography (CMT) has been developed. Imaging biofilms in porous media

Wildenschild, Dorthe

345

Electrochimica Acta 52 (2007) 43174324 Porous current collectors for passive direct methanol fuel cells  

E-Print Network [OSTI]

Electrochimica Acta 52 (2007) 4317­4324 Porous current collectors for passive direct methanol fuel methanol fuel cell (DMFC) with its cathode current collector made of porous metal foam was investigated that the passive DMFC having the porous current collector yielded much higher and much more stable performance than

Zhao, Tianshou

2007-01-01T23:59:59.000Z

346

Fabrication and testing of oxidized porous silicon field emitter strips  

E-Print Network [OSTI]

mechanism. Formation by Local Dissolution of Silicon Unagami proposed [29] that the formation of porous silicon occurs due to the dissolution of silicon at places restricted by a surface porous film and silicic acid formed during the dissolution reaction... anodized in the presence of HF electmlyte. The silicon wafer divides the electrochemical cell into front and rear half cells. Each of the cells was filled with the electrolyte which is a mixture of 1. 5:1 hydroflouric acid and ethanol. Ethanol is used...

Madduri, Vasanta Bhanu

1992-01-01T23:59:59.000Z

347

Human-computer interface design  

SciTech Connect (OSTI)

Modern military forces assume that computer-based information is reliable, timely, available, usable, and shared. The importance of computer-based information is based on the assumption that {open_quotes}shared situation awareness, coupled with the ability to conduct continuous operations, will allow information age armies to observe, decide, and act faster, more correctly and more precisely than their enemies.{close_quotes} (Sullivan and Dubik 1994). Human-Computer Interface (HCI) design standardization is critical to the realization of the previously stated assumptions. Given that a key factor of a high-performance, high-reliability system is an easy-to-use, effective design of the interface between the hardware, software, and the user, it follows logically that the interface between the computer and the military user is critical to the success of the information-age military. The proliferation of computer technology has resulted in the development of an extensive variety of computer-based systems and the implementation of varying HCI styles on these systems. To accommodate the continued growth in computer-based systems, minimize HCI diversity, and improve system performance and reliability, the U.S. Department of Defense (DoD) is continuing to adopt interface standards for developing computer-based systems.

Bowser, S.E.

1995-04-01T23:59:59.000Z

348

ATLAS Tile Calorimeter Interface Card  

E-Print Network [OSTI]

-1- ATLAS Tile Calorimeter Interface Card K. Anderson, A. Gupta, J. Pilcher, H. Sanders, F. Tang, R. Teuscher, H. Wu The University of Chicago ABSTRACT This paper describes the ATLAS Tile Calorimeter. OVERVIEW The ATLAS Tile Calorimeter (Tilecal) [1] [Figure 1] front end electronics consists of 4 parts, 3in

349

Interface Control Document for the Interface between the Central Solenoid Insert Coil and the Test Facility  

SciTech Connect (OSTI)

This document provides the interface definition and interface control between the Central Solenoid Insert Coil and the Central Solenoid Model Coil Test Facility in Japan.

Smirnov, Alexandre [ORNL; Martovetsky, Nicolai N [ORNL; Nunoya, Yoshihiko [Japan Atomic Energy Agency (JAEA), Naka

2011-06-01T23:59:59.000Z

350

Noninvasive method for determining the liquid level and density inside of a container  

DOE Patents [OSTI]

Noninvasive method for determining the liquid level and density inside of a container having arbitrary dimension and shape. By generating a flexural acoustic wave in the container shell and measuring the phase difference of the detected flexural wave from that of the originally generated wave a small distance from the generated wave, while moving the generation and detection means through the liquid/vapor interface, this interface can be detected. Both the wave generation and wave detection may be achieved by transducers on the surface of the container. A change in the phase difference over the outer surface of the vessel signifies that a liquid/vapor interface has been crossed, while the magnitude of the phase difference can be related to fluid density immediately opposite the measurement position on the surface of the vessel.

Sinha, Dipen N. (Los Alamos, NM)

2000-01-01T23:59:59.000Z

351

Absorption of sound in liquids and liquid mixtures  

E-Print Network [OSTI]

ABSORPTION OF SOUND IN LIQUIDS AND LIQUID MIXTURES A Thesis Raiq S. causa Approved as to style and content by: (Chairman of Committee) January 1955 L1BRARY A 4 M COLLEOE OF IEXAS ADSORPTION OF SOfP@ LIQUIDS AND LIQUID NIXTURES A Thesis... Introduction to the Problem Experimental Methods and Procedures Results Discussion of Results Acknowledgements Bib 1 io graphy 22 4I 42 Introduction to the Problem The study of sound absorption in liquids and liquid mixtures is of considerable...

Musa, Raiq S

2012-06-07T23:59:59.000Z

352

Carbon monoxide absorbing liquid  

SciTech Connect (OSTI)

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

353

INEEL Liquid Effluent Inventory  

SciTech Connect (OSTI)

The INEEL contractors and their associated facilities are required to identify all liquid effluent discharges that may impact the environment at the INEEL. This liquid effluent information is then placed in the Liquid Effluent Inventory (LEI) database, which is maintained by the INEEL prime contractor. The purpose of the LEI is to identify and maintain a current listing of all liquid effluent discharge points and to identify which discharges are subject to federal, state, or local permitting or reporting requirements and DOE order requirements. Initial characterization, which represents most of the INEEL liquid effluents, has been performed, and additional characterization may be required in the future to meet regulations. LEI information is made available to persons responsible for or concerned with INEEL compliance with liquid effluent permitting or reporting requirements, such as the National Pollutant Discharge Elimination System, Wastewater Land Application, Storm Water Pollution Prevention, Spill Prevention Control and Countermeasures, and Industrial Wastewater Pretreatment. The State of Idaho Environmental Oversight and Monitoring Program also needs the information for tracking liquid effluent discharges at the INEEL. The information provides a baseline from which future liquid discharges can be identified, characterized, and regulated, if appropriate. The review covered new and removed buildings/structures, buildings/structures which most likely had new, relocated, or removed LEI discharge points, and at least 10% of the remaining discharge points.

Major, C.A.

1997-06-01T23:59:59.000Z

354

Synthesis of ionic liquids  

DOE Patents [OSTI]

Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic liqand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

Dai, Sheng [Knoxville, TN; Luo, Huimin [Knoxville, TN

2008-09-09T23:59:59.000Z

355

Liquid heat capacity lasers  

DOE Patents [OSTI]

The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

2007-05-01T23:59:59.000Z

356

MDCF Tutorial Device Interface and App Development  

E-Print Network [OSTI]

-generated Device Interface (ICE Device Model) Vision: IDE for Driver Development & Validation Vision: IntegratedMDCF Tutorial Device Interface and App Development Acknowledgements: Funding provided by US National Science Foundation awards 0734204, 0930647 Clinical documentation and hardware provided by CIMIT

Huth, Michael

357

Kuali Financial System Implementation Collector Interface Meeting  

E-Print Network [OSTI]

Kuali Financial System Implementation Collector Interface Meeting December 17, 2008 Presenters of the Kuali Financial System (KFS) Collector Interface Format Differences from FRS Answer your questions #12 Collector File collector

Stephens, Graeme L.

358

Simulations of strongly phase-separated liquid-gas systems  

E-Print Network [OSTI]

Lattice Boltzmann simulations of liquid-gas systems are believed to be restricted to modest density ratios of less than 10. In this article we show that reducing the speed of sound and, just as importantly, the interfacial contributions to the pressure allows lattice Boltzmann simulations to achieve high density ratios of 1000 or more. We also present explicit expressions for the limits of the parameter region in which the method gives accurate results. There are two separate limiting phenomena. The first is the stability of the bulk liquid phase. This consideration is specific to lattice Boltzmann methods. The second is a general argument for the interface discretization that applies to any diffuse interface method.

A. J. Wagner; C. M. Pooley

2006-08-22T23:59:59.000Z

359

Perceptual and Context Aware Interfaces on Mobile Devices  

E-Print Network [OSTI]

Cell phone interfaces for Voice. 5.8.1 Initial interfaceCell phone interfaces for Map. After pressing the ok button,collection. . . . . . . . . . . . . . . . Cell phone

Wang, Jingtao

2010-01-01T23:59:59.000Z

360

Atomistic modeling of dislocation-interface interactions  

SciTech Connect (OSTI)

Using atomic scale models and interface defect theory, we first classify interface structures into a few types with respect to geometrical factors, then study the interfacial shear response and further simulate the dislocation-interface interactions using molecular dynamics. The results show that the atomic scale structural characteristics of both heterophases and homophases interfaces play a crucial role in (i) their mechanical responses and (ii) the ability of incoming lattice dislocations to transmit across them.

Wang, Jian [Los Alamos National Laboratory; Valone, Steven M [Los Alamos National Laboratory; Beyerlein, Irene J [Los Alamos National Laboratory; Misra, Amit [Los Alamos National Laboratory; Germann, T. C. [Los Alamos National Laboratory

2011-01-31T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Electric and Magnetic Walls on Dielectric Interfaces  

E-Print Network [OSTI]

Sufficient conditions of the existence of electric or magnetic walls on dielectric interfaces are given for a multizone uniform dielectric waveguiding system. If one of two adjacent dielectric zones supports a TEM field distribution while the other supports a TM (TE) field distribution, then the common dielectric interface behaves as an electric (magnetic) wall, that is, the electric (magnetic) field line is perpendicular to the interface while the magnetic (electric) field line is parallel to the interface.

Changbiao Wang

2010-07-20T23:59:59.000Z

362

Novel Nanostructured Interface Solution for Automotive Thermoelectric...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Partnership: Automotive Thermoelectric Modules with Scalable Thermo- and Electro-Mechanical Interfaces Thermoelectrics Partnership: Automotive Thermoelectric Modules with...

363

Acoustic wave propagation in two-phase heterogeneous porous media  

E-Print Network [OSTI]

The propagation of an acoustic wave through two-phase porous media with spatial variation in porosity is studied. The evolutionary wave equation is derived, and the propagation of an acoustic wave is numerically analyzed in application to marine sediments with various physical parameters.

J. I. Osypik; N. I. Pushkina; Ya. M. Zhileikin

2015-03-19T23:59:59.000Z

364

Numerical simulation of transpiration cooling through porous , T. Gotzen1  

E-Print Network [OSTI]

55, 52056 Aachen SUMMARY Transpiration cooling using ceramic matrix composite (CMC) materials to facilitate such numerical simulations for a carbon/carbon material mounted in the side wall of a hot gasNumerical simulation of transpiration cooling through porous material W. Dahmen1 , T. Gotzen1 and S

365

ORIGINAL PAPER Conditional simulations of wateroil flow in heterogeneous porous  

E-Print Network [OSTI]

water standards. Thus, a small amount of NAPL can contaminate large volumes of groundwater over a long period of time. Therefore, it is very important to understand the processes associated with contaminant is a complicated mixture of hydrocarbon fluids, brine, porous rock and fractures. The structure of the void space

Lu, Zhiming

366

Elastic properties of saturated porous rocks with aligned fractures  

E-Print Network [OSTI]

Several treatments of the porous media with aligned fractures have been ...... a function of background porosity /p for water-satu- rated rock (Kf = 2.25 ? 109 Pa). .... that are in hydraulic equilibrium with the fractures, the fluid will squeeze from ...

2003-12-02T23:59:59.000Z

367

Numerical simulation of fluid flow in porous/fractured media  

SciTech Connect (OSTI)

Theoretical models of fluid flow in porous/fractured media can help in the design of in situ fossil energy and mineral extraction technologies. Because of the complexity of these processes, numerical solutions are usually required. Sample calculations illustrate the capabilities of present day computer models.

Travis B.J.; Cook, T.L.

1981-01-01T23:59:59.000Z

368

Method for the preparation of ferrous low carbon porous material  

SciTech Connect (OSTI)

A method for preparing a porous metal article using a powder metallurgy forming process is provided which eliminates the conventional steps associated with removing residual carbon. The method uses a feedstock that includes a ferrous metal powder and a polycarbonate binder. The polycarbonate binder can be removed by thermal decomposition after the metal article is formed without leaving a carbon residue.

Miller, Curtis Jack

2014-05-27T23:59:59.000Z

369

High-strength porous carbon and its multifunctional applications  

DOE Patents [OSTI]

High-strength porous carbon and a method of its manufacture are described for multifunctional applications, such as ballistic protection, structural components, ultracapacitor electrodes, gas storage, and radiation shielding. The carbon is produced from a polymer precursor via carbonization, and optionally by surface activation and post-treatment.

Wojtowicz, Marek A; Rubenstein, Eric P; Serio, Michael A; Cosgrove, Joseph E

2013-12-31T23:59:59.000Z

370

Pyrolytic carbon electrodes Lithographically Defined Porous Carbon Electrodes**  

E-Print Network [OSTI]

to the intrinsic material properties of carbon, functionalized films can be produced through chemical modification fabrication method capable of producing large area (%100 s cm2 ) submicrometer porous carbon films. In our methodology. The palladium-modified electrodes exhibit a catalytic response for methanol oxidation

New Mexico, University of

371

Exponential decay in one-dimensional porous-thermo-elasticity  

E-Print Network [OSTI]

is the equilibrated stress, g is the equilibrated body force and q is the heat flux. The variables u" (BFM2003- 00309) of the Spanish Ministry of Science and Technology. Keywords: porous energy density is a positive definite form. Thus, the constitutive coefficients satisfy the conditions: µ

Politècnica de Catalunya, Universitat

372

Integrating Structure Control over Multiple Length Scales in Porous High  

E-Print Network [OSTI]

temperature catalytic applications for their high surface area and low flow resistance in combination with thermal and chemical stability. We have developed a bottom-up approach to functional, porous, high results in three-dimensionally interconnected, high-temperature ceramic materials functionalized with well

Gruner, Sol M.

373

COMPARISON OF VARIOUS FORMULATIONS OF THREEPHASE FLOW IN POROUS MEDIA  

E-Print Network [OSTI]

permeability and capillary pressure curves satisfy a so­called total differential condition, the pseudo­global, oil, and gas) flow in porous media, including phase, global, and pseudo­global pressure and numerically presented for the first time. It is shown that the global pressure­saturation formulation

374

A MULTI-LENGTH SCALE APPROACH TO CORRELATING SOLID OXIDE FUEL CELL POROUS CATHODE MICROSTRUCTURE TO ELECTROCHEMICAL PERFORMANCE  

E-Print Network [OSTI]

........................................................................................................27 3 COMPREHENSIVE QUANTIFICATION OF POROUS LSCF CATHODE MICROSTRUCTURE AND ELECTROCHEMICAL IMPEDANCE

Florida, University of

375

Liquid-liquid interfacial nanoparticle assemblies  

DOE Patents [OSTI]

Self-assembly of nanoparticles at the interface between two fluids, and methods to control such self-assembly process, e.g., the surface density of particles assembling at the interface; to utilize the assembled nanoparticles and their ligands in fabrication of capsules, where the elastic properties of the capsules can be varied from soft to tough; to develop capsules with well-defined porosities for ultimate use as delivery systems; and to develop chemistries whereby multiple ligands or ligands with multiple functionalities can be attached to the nanoparticles to promote the interfacial segregation and assembly of the nanoparticles. Certain embodiments use cadmium selenide (CdSe) nanoparticles, since the photoluminescence of the particles provides a convenient means by which the spatial location and organization of the particles can be probed. However, the systems and methodologies presented here are general and can, with suitable modification of the chemistries, be adapted to any type of nanoparticle.

Emrick, Todd S. (South Deerfield, MA); Russell, Thomas P. (Amherst, MA); Dinsmore, Anthony (Amherst, MA); Skaff, Habib (Amherst, MA); Lin, Yao (Amherst, MA)

2008-12-30T23:59:59.000Z

376

Compacted Soil Liner Interface Strength Importance  

E-Print Network [OSTI]

Case Study Compacted Soil Liner Interface Strength Importance Timothy D. Stark, F.ASCE1 ; Hangseok interface is not the geomembrane (GM)/compacted low-permeability soil liner (LPSL) but a soil­soil interface placing the cover soil from bottom to top. DOI: 10.1061/(ASCE)GT.1943-5606 .0000556. © 2012 American

377

The ATLAS METADATA INTERFACE Solveig Albrand1  

E-Print Network [OSTI]

The ATLAS METADATA INTERFACE Solveig Albrand1 , Thomas Doherty2 , Jerome Fulachier1 and Fabian was chosen as the ATLAS dataset selection interface in July 2006. It is the main interface for searching for ATLAS data using physics metadata criteria. AMI has been implemented as a generic database management

Paris-Sud XI, Université de

378

CollageMachine: Model of ``Interface Ecology''  

E-Print Network [OSTI]

CollageMachine: Model of ``Interface Ecology'' By Andruid Kerne dissertation submitted partial addresses browsing creatively, been co­developed with the metadisciplinary framework interface ecology, in addition inside them, open process without definite bounds. a metadiscipline, interface ecology brings

Mohri, Mehryar

379

BREATH Version 1.1, Coupled flow and energy transport in porous media: Simulator description and user guide  

SciTech Connect (OSTI)

This document describes the BREATH computer code, including the mathematical and numerical formulation for the simulator, usage description, and sample input files with corresponding output files. The BREATH computer code is designed to simulate one-dimensional flow of a liquid phase and dispersive transport of the corresponding vapor species, coupled with energy transfer, in a heterogeneous porous medium. The BREATH simulator has been developed for use in auxiliary analyses which are a part of the Nuclear Regulatory Commission Iterative Performance Assessment program. The simulator was developed in response to the observation from Total System Performance Assessments by both the Nuclear Regulatory Commission and the US Department of Energy that total-system performance at the Yucca Mountain site in Nevada is highly sensitive to the infiltration rate. Accordingly, this first version of the code is primarily intended to simulate processes important to infiltration and evaporation in climatic and hydrologic near-surface environments representative of the Yucca Mountain site. The simulation model assumes that there is an immobile solid phase, a mobile liquid phase, and an optional infinitely mobile gas phase. The liquid may have an associated vapor species, assumed to be in equilibrium with the liquid phase. The vapor phase may only move via diffusion within the gas phase. Energy may be transported in the form of enthalpy, thermal conduction, and latent heat. The temperature range is assumed to be between 0 and 100{degree}C. Available boundary conditions include six liquid-phase conditions, four vapor-species conditions, and three energy conditions, all of which may be applied independently to either end of the domain. Meteorological conditions may also be input, thereby providing additional control over boundary fluxes. Boundary conditions may be updated as often as desired.

Stothoff, S.A.

1995-07-01T23:59:59.000Z

380

Microscopic Motion of Liquid Metal Plasma Facing Components In A Diverted Plasma  

SciTech Connect (OSTI)

Liquid metal plasma facing components (PFCs) have been identified as an alternative material for fusion plasma experiments. The use of a liquid conductor where significant magnetic fields are present is considered risky, with the possibility of macroscopic fluid motion and possible ejection into the plasma core. Analysis is carried out on thermoelectric magnetohydrodynamic (TEMHD) forces caused by temperature gradients in the liquid-container system itself in addition to scrape-off-layer currents interacting with the PFC from a diverted plasma. Capillary effects at the liquid-container interface will be examined which govern droplet ejection criteria. Stability of the interface is determined using linear stability methods. In addition to application to liquidmetal PFCs, thin film liquidmetal effects have application to current and future devices where off-normal events may liquefy portions of the first wall and other plasma facing components.

Jaworski, M A; Morley, N B; Abrams, T; Kaita, R; Kallman, J; Kugel, H; Majeski, R

2010-09-22T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Crystal growth from a supersaturated melt: relaxation of the solid-liquid dynamic stiffness  

E-Print Network [OSTI]

We discuss the growth process of a crystalline phase out of a metastable over-compressed liquid that is brought into contact with a crystalline substrate. The process is modeled by means of molecular dynamics. The particles interact via the Lennard-Jones potential and their motion is locally thermalized by Langevin dynamics. We characterize the relaxation process of the solid-liquid interface, showing that the growth speed is maximal for liquid densities above the solid coexistence density, and that the structural properties of the interface rapidly converge to equilibrium-like properties. In particular, we show that the off-equilibrium dynamic stiffness can be extracted using capillary wave theory arguments, even if the growth front moves fast compared to the typical diffusion time of the compressed liquid, and that the dynamic stiffness converges to the equilibrium stiffness in times much shorter than the diffusion time.

Francesco Turci; Tanja Schilling

2014-05-20T23:59:59.000Z

382

Influences of Flow Transients and Porous Medium Heterogeneity on Colloid-Associated Contaminant Transport in the Vadose Zone  

SciTech Connect (OSTI)

Radionuclides, metals, and dense non-aqueous phase liquids have contaminated about six billion cubic meters of soil at Department of Energy (DOE) sites. The subsurface transport of many of these contaminants is facilitated by colloids (i.e., microscopic, waterborne particles). The first step in the transport of contaminants from their sources to off-site surface water and groundwater is migration through the vadose zone. Developing our understanding of the migration of colloids and colloid-associated contaminants through the vadose zone is critical to assessing and controlling the release of contaminants from DOE sites. In this study, we examined the mobilization, transport, and filtration (retention) of mineral colloids and colloidassociated radionuclides within unsaturated porous media. This investigation involved laboratory column experiments designed to identify properties that affect colloid mobilization and retention and pore-scale visualization experiments designed to elucidate mechanisms that govern these colloid-mass transfer processes. The experiments on colloid mobilization and retention were supplemented with experiments on radionuclide transport through porous media and on radionuclide adsorption to mineral colloids. Observations from all of these experiments – the column and visualization experiments with colloids and the experiments with radionuclides – were used to guide the development of mathematical models appropriate for describing colloids and colloid-facilitated radionuclide transport through the vadose zone.

James Saiers; Joseph Ryan

2006-07-02T23:59:59.000Z

383

Influences of Flow Transients and Porous Medium Heterogeneity on Colloid-Associated Contaminant Transport in the Vadose Zone  

SciTech Connect (OSTI)

Radionuclides, metals, and dense non-aqueous phase liquids have contaminated about six billion cubic meters of soil at Department of Energy (DOE) sites. The subsurface transport of many of these contaminants is facilitated by colloids (i.e., microscopic, waterborne particles). The first step in the transport of contaminants from their sources to off-site surface water and groundwater is migration through the vadose zone. Developing our understanding of the migration of colloids and colloid-associated contaminants through the vadose zone is critical to assessing and controlling the release of contaminants from DOE sites. In this study, we examined the mobilization, transport, and filtration (retention) of mineral colloids and colloid-associated radionuclides within unsaturated porous media. This investigation involved laboratory column experiments designed to identify properties that affect colloid mobilization and retention and pore-scale visualization experiments designed to elucidate mechanisms that govern these colloid-mass transfer processes. The experiments on colloid mobilization and retention were supplemented with experiments on radionuclide transport through porous media and on radionuclide adsorption to mineral colloids. Observations from all of these experiments – the column and visualization experiments with colloids and the experiments with radionuclides – were used to guide the development of mathematical models appropriate for describing colloids and colloid-facilitated radionuclide transport through the vadose zone.

James Saiers

2006-06-28T23:59:59.000Z

384

Heat transfer in soft nanoscale interfaces: the influence of interface curvature  

E-Print Network [OSTI]

Heat transfer in soft nanoscale interfaces: the influence of interface curvature Anders Lervik transient non-equilibrium molecular-dynamics simulations, heat-transfer through nanometer-scale interfaces processes. We show that the modeling of heat transfer across a nanodroplet/fluid interface requires

Kjelstrup, Signe

385

Adaptive Brain-Computer Interface Passive brain-computer interfaces are designed to use  

E-Print Network [OSTI]

Adaptive Brain-Computer Interface Abstract Passive brain-computer interfaces are designed to use brain activity as an additional input, allowing the adaptation of the interface in real time according to the user's mental state. While most current brain computer interface research (BCI) is designed for direct

Boetticher, Gary D.

386

Air Liquide - Biogas & Fuel Cells  

Broader source: Energy.gov (indexed) [DOE]

Liquide - Biogas & Fuel Cells Hydrogen Energy Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry,...

387

Initial mechanical stability of cementless highly-porous titanium tibial components  

SciTech Connect (OSTI)

Cementless fixation in total knee replacement has seen limited use since reports of early failure surfaced in the late 80s and early 90s. However the emergence of improved biomaterials, particularly porous titanium and tantalum, has led to a renewed interest in developing a cementless tibial component to enhance long-term survivorship of the implants. Cement is commonly employed to minimize micromotion in new implants but represents a weak interface between the implant and bone. The elimination of cement and application of these new biomaterials, which theoretically provide improved stability and ultimate osseointegration, would likely result in greater knee replacement success. Additionally, the removal of cement from the procedure would help minimize surgical durations and get rid of the time needed for curing, thereby the chance of infection. The purpose of this biomechanical study was twofold. The first goal was to assess whether vibration analysis techniques can be used to evaluate and characterize initial mechanical stability of cementless implants more accurately than the traditional method of micromotion determination, which employs linear variable differential transducers (LVDTs). Second, an evaluative study was performed to determine the comparative mechanical stability of five designs of cementless tibial components under mechanical loading designed to simulate in vivo forces. The test groups will include a cemented Triathlon Keeled baseplate control group, three different 2-peg cementless baseplates with smooth, mid, and high roughnesses and a 4-peg cement/ess baseplate with mid-roughness.

Stone, Timothy Brandon [Los Alamos National Laboratory; Amer, Luke D [Los Alamos National Laboratory; Warren, Christopher P [Los Alamos National Laboratory; Cornwell, Phillip [Los Alamos National Laboratory; Meneghini, R Michael [UNIV OF CONNECTICUT HEALTH CENTER

2008-01-01T23:59:59.000Z

388

Long-time evolution of sequestered CO$_2$ in porous media  

E-Print Network [OSTI]

CO$_2$ sequestration in subsurface reservoirs is important for limiting atmospheric CO$_2$ concentrations. However, a complete physical picture able to predict the structure developing within the porous medium is lacking. We investigate theoretically reactive transport in the long-time evolution of carbon in the brine-rock environment. As CO$_2$ is injected into a brine-rock environment, a carbonate-rich region is created amid brine. Within the carbonate-rich region minerals dissolve and migrate from regions of high concentration to low concentration, along with other dissolved carbonate species. This causes mineral precipitation at the interface between the two regions. We argue that precipitation in a small layer reduces diffusivity, and eventually causes mechanical trapping of the CO$_2$. Consequently, only a small fraction of the CO$_2$ is converted to solid mineral; the remainder either dissolves in water or is trapped in its original form. We also study the case of a pure CO$_2$ bubble surrounded by bri...

Cohen, Yossi

2014-01-01T23:59:59.000Z

389

XRCT characterisation of Ti particles inside porous Al{sub 2}O{sub 3}  

SciTech Connect (OSTI)

Computed X-ray tomography was used to characterise distribution and sphericity of Ti granules within highly porous (> 35%) Al{sub 2}O{sub 3} powder compacts, as they are key parameters for a successful infiltration by Fe-based alloys. Setting of reconstruction constraints, image editing as well as data processing are the most challenging parts of computed X-ray tomography and principal sources of errors that bias the generated data. Thus, corrective measures have to be applied and the reliability of generated data has to be proved with respect to statistical, stereological and volumetric aspects. Combining an adapted Interface Particle Treatment Algorithm with the Marching Cube Method, Equilibrium Random State Model, cluster splitting and conventional laser diffraction measurements a significant improvement of the three-dimensional reconstructed data was achieved. This study points out the need of the applied algorithms for the proof and improvement of generated data by computed X-ray tomography and gives a short survey of methods that can be applied.

Vasic, S., E-mail: srdan.vasic@unifr.ch [Technical Mineralogy Group, Institute of Mineralogy and Petrography, University of Fribourg, CH-1700 Fribourg (Switzerland); Empa, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for High Performance Ceramics, Ueberlandstrasse 129, CH-8600 Duebendorf (Switzerland); Grobety, B. [Technical Mineralogy Group, Institute of Mineralogy and Petrography, University of Fribourg, CH-1700 Fribourg (Switzerland); Kuebler, J., E-mail: jakob.kuebler@empa.ch [Empa, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for High Performance Ceramics, Ueberlandstrasse 129, CH-8600 Duebendorf (Switzerland); Graule, T. [Empa, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for High Performance Ceramics, Ueberlandstrasse 129, CH-8600 Duebendorf (Switzerland); Baumgartner, L. [Institute of Mineralogy and Petrography, Earth Science, University of Lausanne, CH-1100 Lausanne (Switzerland)

2010-06-15T23:59:59.000Z

390

Influence of interface compounds on interface bonding characteristics of aluminium and silicon carbide  

SciTech Connect (OSTI)

The interface plays an important role in improving the mechanical properties of metal matrix composites. Hence, it is essential to evaluate interface bonding of Aluminium/Silicon carbide. The interface bonding of Aluminum/Silicon carbide samples were prepared by various processing temperatures at constant holding time. The interface compounds at the interface were evaluated by an energy dispersive spectroscope and diffusion length of compounds was calculated by Arrhenius equation. The interface structure was analyzed by a scanning electron microscope. The interface characteristics were evaluated by tensile test and microhardness test.

Sozhamannan, G.G., E-mail: sozhan30@yahoo.co.in [Department of Mechanical Engineering, College of Engineering, Anna University Chennai, Chennai-600025 (India); Prabu, S. Balasivanandha [Department of Mechanical Engineering, College of Engineering, Anna University Chennai, Chennai-600025 (India)

2009-09-15T23:59:59.000Z

391

Liquid sampling system  

DOE Patents [OSTI]

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

Larson, L.L.

1984-09-17T23:59:59.000Z

392

Density distribution for the molecules of a liquid in a semi-infinite space  

E-Print Network [OSTI]

The Sutherland approximation to the van der Waals forces is applied to the derivation of a self-consistent Vlasov-type field in a liquid filling a half space, bordering vacuum. The ensuing Vlasov equation is then derived, and solved to predict the behavior of the density at and in the vicinity of the liquid-vacuum interface. A numerical solution to the Vlasov equation is also produced and the density profile shown and discussed.

V. Molinari; B. D. Ganapol; D. Mostacci

2015-03-04T23:59:59.000Z

393

Plastic flow in solids with interfaces  

E-Print Network [OSTI]

A non-equilibrium theory of isothermal and diffusionless evolution of incoherent interfaces within a plastically deforming solid is developed. The irreversible dynamics of the interface are driven by its normal motion, incoherency (slip and misorientation), and an intrinsic plastic flow; and purely by plastic deformation in the bulk away from the interface. Using the continuum theory for defect distribution (in bulk and over the interface) we formulate a general kinematical framework, derive relevant balance laws and jump conditions, and prescribe a thermodynamically consistent constitutive/kinetic structure for interface evolution.

Anurag Gupta; David Steigmann

2011-11-25T23:59:59.000Z

394

Anomalous magneto-transport at the superconducting interface between LaAlO3 and SrTiO3  

E-Print Network [OSTI]

be controlled by solely varying the number of charge carriers at the interface using a gate volt- age [4). The resistance was measured in a dilution refrigerator using Lakeshore 370 AC resistance bridge and at liquid He temperatures using a standard four wire DC resis- tivity method. In Fig. 1 we present the number of charge

Palevski, Alexander

395

Liquidity facilities and signaling  

E-Print Network [OSTI]

This dissertation studies the role of signaling concerns in discouraging access to liquidity facilities like the IMF contingent credit lines (CCL) and the Discount Window (DW). In Chapter 1, I analyze the introduction of ...

Arregui, Nicolás

2010-01-01T23:59:59.000Z

396

Surface rheology and interface stability.  

SciTech Connect (OSTI)

We have developed a mature laboratory at Sandia to measure interfacial rheology, using a combination of home-built, commercially available, and customized commercial tools. An Interfacial Shear Rheometer (KSV ISR-400) was modified and the software improved to increase sensitivity and reliability. Another shear rheometer, a TA Instruments AR-G2, was equipped with a du Nouey ring, bicone geometry, and a double wall ring. These interfacial attachments were compared to each other and to the ISR. The best results with the AR-G2 were obtained with the du Nouey ring. A Micro-Interfacial Rheometer (MIR) was developed in house to obtain the much higher sensitivity given by a smaller probe. However, it was found to be difficult to apply this technique for highly elastic surfaces. Interfaces also exhibit dilatational rheology when the interface changes area, such as occurs when bubbles grow or shrink. To measure this rheological response we developed a Surface Dilatational Rheometer (SDR), in which changes in surface tension with surface area are measured during the oscillation of the volume of a pendant drop or bubble. All instruments were tested with various surfactant solutions to determine the limitations of each. In addition, foaming capability and foam stability were tested and compared with the rheology data. It was found that there was no clear correlation of surface rheology with foaming/defoaming with different types of surfactants, but, within a family of surfactants, rheology could predict the foam stability. Diffusion of surfactants to the interface and the behavior of polyelectrolytes were two subjects studied with the new equipment. Finally, surface rheological terms were added to a finite element Navier-Stokes solver and preliminary testing of the code completed. Recommendations for improved implementation were given. When completed we plan to use the computations to better interpret the experimental data and account for the effects of the underlying bulk fluid.

Yaklin, Melissa A.; Cote, Raymond O.; Moffat, Harry K.; Grillet, Anne Mary; Walker, Lynn; Koehler, Timothy P.; Reichert, Matthew D. (Carnegie Mellon University, Pittsburgh, PA); Castaneda, Jaime N.; Mondy, Lisa Ann; Brooks, Carlton, F.

2010-11-01T23:59:59.000Z

397

Liquid crystalline composites containing phyllosilicates  

DOE Patents [OSTI]

The present invention provides phyllosilicate-polymer compositions which are useful as liquid crystalline composites. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while at the same time be transparent. Because of the ordering of the particles liquid crystalline composite, liquid crystalline composites are particularly useful as barriers to gas transport.

Chaiko, David J.

2004-07-13T23:59:59.000Z

398

Biological Interfaces | Clean Energy | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAboutScienceCareers Apply for aCouldBiofuelHelp TableBiological Interfaces

399

VOLUME 85, NUMBER 18 P H Y S I C A L R E V I E W L E T T E R S 30 OCTOBER 2000 Phonons, Rotons, and Layer Modes of Liquid 4He in Aerogel  

E-Print Network [OSTI]

, and Layer Modes of Liquid 4He in Aerogel B. Fåk* and O. Plantevin Département de Recherche Fondamentale sur filled aerogel. Using complementary high-energy resolution and high statistical precision neutron scattering instruments, and two different 87% porous aerogel samples, we show that the three-dimensional (3D

Glyde, Henry R.

400

Nonlinear Dynamics of Capacitive Charging and Desalination by Porous Electrodes  

E-Print Network [OSTI]

The rapid and efficient exchange of ions between porous electrodes and aqueous solutions is important in many applications, such as electrical energy storage by super-capacitors, water desalination and purification by capacitive deionization (or desalination), and capacitive extraction of renewable energy from a salinity difference. Here, we present a unified mean-field theory for capacitive charging and desalination by ideally polarizable porous electrodes (without Faradaic reactions or specific adsorption of ions) in the limit of thin double layers (compared to typical pore dimensions). We illustrate the theory in the case of a dilute, symmetric, binary electrolyte using the Gouy-Chapman-Stern (GCS) model of the double layer, for which simple formulae are available for salt adsorption and capacitive charging of the diffuse part of the double layer. We solve the full GCS mean-field theory numerically for realistic parameters in capacitive deionization, and we derive reduced models for two limiting regimes wi...

Biesheuvel, P M

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Methods for removing contaminant matter from a porous material  

DOE Patents [OSTI]

Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

Fox, Robert V. (Idaho Falls, ID) [Idaho Falls, ID; Avci, Recep (Bozeman, MT) [Bozeman, MT; Groenewold, Gary S. (Idaho Falls, ID) [Idaho Falls, ID

2010-11-16T23:59:59.000Z

402

Rounding of the localization transition in model porous media  

E-Print Network [OSTI]

The generic mechanisms of anomalous transport in porous media are investigated by computer simulations of two-dimensional model systems. In order to bridge the gap between the strongly idealized Lorentz model and realistic models of porous media, two models of increasing complexity are considered: a cherry-pit model with hard-core correlations as well as a soft-potential model. An ideal gas of tracer particles inserted into these structures is found to exhibit anomalous transport which extends up to several decades in time. Also, the self-diffusion of the tracers becomes suppressed upon increasing the density of the systems. These phenomena are attributed to an underlying percolation transition. In the soft potential model the transition is rounded, since each tracer encounters its own critical density according to its energy. Therefore, the rounding of the transition is a generic occurrence in realistic, soft systems.

Simon K. Schnyder; Markus Spanner; Felix Höfling; Thomas Franosch; Jürgen Horbach

2014-11-07T23:59:59.000Z

403

Methods for making a porous nuclear fuel element  

DOE Patents [OSTI]

Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

Youchison, Dennis L; Williams, Brian E; Benander, Robert E

2014-12-30T23:59:59.000Z

404

Self-assembled porous media from particle-stabilized emulsions  

E-Print Network [OSTI]

We propose a new mechanism to create self-assembled porous media with highly tunable geometrical properties and permeabilities: We first allow a particle-stabilized emulsion to form from a mixture of two fluids and colloidal particles. Then, either one fluid phase or the particle layer is solidified, which can be achieved by techniques such as polymerization or freezing. Based on computer simulations we demonstrate that modifying only the particle wettability or concentration results in porous structures with a wide range of pore sizes and a permeability that can be varied by up to three orders of magnitude. We then discuss optimization of these properties for self-assembled filters or reactors and conclude that structures based on so-called "bijels" are most suitable candidates.

Stefan Frijters; Jens Harting

2014-08-13T23:59:59.000Z

405

Two-phase flow in a chemically active porous medium  

E-Print Network [OSTI]

We study the problem of the transformation of a given reactant species into an immiscible product species, as they flow through a chemically active porous medium. We derive the equation governing the evolution of the volume fraction of the species -- in a one-dimensional macroscopic description --, identify the relevant dimensionless numbers, and provide simple models for capillary pressure and relative permeabilities, which are quantities of crucial importance when tackling multiphase flows in porous media. We set the domain of validity of our models and discuss the importance of viscous coupling terms in the extended Darcy's law. We investigate numerically the steady regime and demonstrate that the spatial transformation rate of the species along the reactor is non-monotonous, as testified by the existence of an inflection point in the volume fraction profiles. We obtain the scaling of the location of this inflection point with the dimensionless lengths of the problem. Eventually, we provide key elements for optimization of the reactor.

Alexandre Darmon; Michael Benzaquen; Thomas Salez; Olivier Dauchot

2014-11-20T23:59:59.000Z

406

The Uniaxial Tensile Response of Porous and Microcracked Ceramic Materials  

SciTech Connect (OSTI)

The uniaxial tensile stress-strain behavior of three porous ceramic materials was determined at ambient conditions. Test specimens in the form of thin beams were obtained from the walls of diesel particulate filter honeycombs and tested using a microtesting system. A digital image correlation technique was used to obtain full-field 2D in-plane surface displacement maps during tensile loading, and in turn, the 2D strains obtained from displacement fields were used to determine the Secant modulus, Young s modulus and initial Poisson s ratio of the three porous ceramic materials. Successive unloading-reloading experiments were performed at different levels of stress to decouple the linear elastic, anelastic and inelastic response in these materials. It was found that the stress-strain response of these materials was non-linear and that the degree of nonlinearity is related to the initial microcrack density and evolution of damage in the material.

Pandey, Amit [ORNL; Shyam, Amit [ORNL; Watkins, Thomas R [ORNL; Lara-Curzio, Edgar [ORNL; Lara-Curzio, Edgar [ORNL; Stafford, Randall [Cummins, Inc; Hemker, Kevin J [Johns Hopkins University

2014-01-01T23:59:59.000Z

407

Porous coatings from wire mesh for bone implants  

DOE Patents [OSTI]

A method of coating areas of bone implant elements and the resulting implant having a porous coating are described. Preselected surface areas are covered by a preform made from continuous woven lengths of wire. The preform is compressed and heated to assure that diffusion bonding occurs between the wire surfaces and between the surface boundaries of the implant element and the wire surfaces in contact with it. Porosity is achieved by control of the resulting voids between the bonded wire portions.

Sump, Kenneth R. (Richland, WA)

1986-01-01T23:59:59.000Z

408

ENCAPSULATION OF PALLADIUM IN POROUS WALL HOLLOW GLASS MICROSPHERES  

SciTech Connect (OSTI)

A new encapsulation method was investigated in an attempt to develop an improved palladium packing material for hydrogen isotope separation. Porous wall hollow glass microspheres (PWHGMs) were produced by using a flame former, heat treating and acid leaching. The PWHGMs were then filled with palladium salt using a soak-and-dry process. The palladium salt was reduced at high temperature to leave palladium inside the microspheres.

Heung, L; George Wicks, G; Ray Schumacher, R

2008-04-09T23:59:59.000Z

409

Phase Diagram of Fully Developed Drainage in Porous Media  

SciTech Connect (OSTI)

Using concepts of invasion percolation in a gradient, we develop a phase diagram of fully developed drainage in porous media. The transition between stabilized displacement (where the conventional continuum applies) and fingering is controlled by the change of the sign of the gradient of the percolation probability (from stabilizing to destabilizing). The transition boundary is described by scaling laws. {copyright} {ital 1997} {ital The American Physical Society}

Yortsos, Y.C.; Xu, B. [Petroleum Engineering Program, Department of Chemical Engineering, University of Southern California, Los Angeles, California 90089-1211 (United States)] [Petroleum Engineering Program, Department of Chemical Engineering, University of Southern California, Los Angeles, California 90089-1211 (United States); Salin, D. [Laboratoire Fluides, Automatique et Systemes Thermiques, Universite Paris VI and XI, associated with C.N.R.S. (URA 871), Batiment 502, Campus Universitaire, 91405 Orsay Cedex (France)] [Laboratoire Fluides, Automatique et Systemes Thermiques, Universite Paris VI and XI, associated with C.N.R.S. (URA 871), Batiment 502, Campus Universitaire, 91405 Orsay Cedex (France)

1997-12-01T23:59:59.000Z

410

Experimental and theoretical study of polymer flow in porous media  

SciTech Connect (OSTI)

In this paper, an extensive study is presented on the single-phase flow of xanthum/tracer slugs in a consolidated sandstone. The phenomena studied include polymer/tracer dispersion, excluded/inaccessible-volume effects, polymer adsorption, and viscous fingering. In some floods, there is also evidence of nonequilibrium effects. Macroscopic flow equations are derived that include terms to model all the behaviors listed above. A microscopic approach is also developed that describes certain features of polymer flow in porous media semiquantitatively.

Sorbie, K.S.; Parker, A.; Clifford, P.J.

1987-08-01T23:59:59.000Z

411

Theoretical Studies of Solid-Liquid Interfaces: Molecular Interactions at the MgO(001)-Water Interface  

E-Print Network [OSTI]

as these compounds are major components of rocks, soils, and airborne dust particles. In addition, metal oxides often groups.2-6 Recently, classical molecular mechanical models appeared which can address the structural chemistry are needed. A few quantum mechanical calculations concerning the properties of water and hydroxyl

Truong, Thanh N.

412

Investigation of redox processes at semiconductor electrode liquid junctions  

SciTech Connect (OSTI)

Research in fundamental aspects of photoelectrochemical cells has been in the following areas: chemical probes for hot carrier processes, electrostatic theory for describing electrical interactions at interfaces, and kinetics of electron transfer at ideal semiconductor solution interfaces. Our goal is to achieve a better understanding of dark and photo-induced current flow at the semiconductor electrode/redox electrolyte interface (SEI) so that devices and processes utilizing this interface for solar energy conversion can be developed or improved. Our most important accomplishment has been the development of a redox system capable of detecting hot electrons at the p-InP/acetonitrile interface. Also, we have examined electrostatic theory for the image potential of an ion as a function of distance from the SEI. Finally, our group was one of the first to realize that the 2-dimensional metal chalcogenides (MC) are excellent materials for fundamental studies of electron transfer at the SEI. One of the chief potential advantages for use of MC's is the formation of semiconductor/liquid junctions with nearly ideal electrochemical properties. 27 refs., 1 fig.

Koval, C.A.

1990-08-01T23:59:59.000Z

413

Formation of multiple levels of porous silicon for buried insulators and conductors in silicon device technologies  

DOE Patents [OSTI]

A method of forming a multiple level porous silicon substrate for semiconductor integrated circuits including anodizing non-porous silicon layers of a multi-layer silicon substrate to form multiple levels of porous silicon. At least one porous silicon layer is then oxidized to form an insulating layer and at least one other layer of porous silicon beneath the insulating layer is metallized to form a buried conductive layer. Preferably the insulating layer and conductive layer are separated by an anodization barrier formed of non-porous silicon. By etching through the anodization barrier and subsequently forming a metallized conductive layer, a fully or partially insulated buried conductor may be fabricated under single crystal silicon.

Blewer, Robert S. (Albuquerque, NM); Gullinger, Terry R. (Albuquerque, NM); Kelly, Michael J. (Albuquerque, NM); Tsao, Sylvia S. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

414

High-performance porous silicon solar cell development. Final report, October 1, 1993--September 30, 1995  

SciTech Connect (OSTI)

The goal of the program was to demonstrate use of porous silicon in new solar cell structures. Porous silicon technology has been developed at Spire for producing visible light-emitting diodes (LEDs). The major aspects that they have demonstrated are the following: porous silicon active layers have been made to show photovoltaic action; porous silicon surface layers can act as antireflection coatings to improve the performance of single-crystal silicon solar cells; and porous silicon surface layers can act as antireflection coatings on polycrystalline silicon solar cells. One problem with the use of porous silicon is to achieve good lateral conduction of electrons and holes through the material. This shows up in terms of poor blue response and photocurrents which increase with increasing reverse bias applied to the diode.

Maruska, P. [Spire Corp., Bedford, MA (United States)] [Spire Corp., Bedford, MA (United States)

1996-09-01T23:59:59.000Z

415

Modification of Deeply Buried Hydrophobic Interfaces by Ionic Surfactants  

SciTech Connect (OSTI)

Hydrophobicity, the spontaneous segregation of oil and water, can be modified by surfactants. The way this modification occurs is studied at the oil-water interface for a range of alkanes and two ionic surfactants. A liquid interfacial monolayer, consisting of a mixture of alkane molecules and surfactant tails, is found. Upon cooling, it freezes at T{sub s}, well above the alkane's bulk freezing temperature, T{sub b}. The monolayer's phase diagram, derived by surface tensiometry, is accounted for by a mixtures-based theory. The monolayer's structure is measured by high-energy X-ray reflectivity above and below T{sub s}. A solid-solid transition in the frozen monolayer, occurring approximately 3 C below T{sub s}, is discovered and tentatively suggested to be a rotator-to-crystal transition.

Ocko, B.M.; Tamam, L.; Pontoni, D.; Sapir, Z.; Yefet, S.; Sloutskin, E.; Reichert, H.; Deutsch, M.

2011-04-05T23:59:59.000Z

416

Modification of Deeply Buried Hydrophobic Interfaces by Ionic Surfactants  

SciTech Connect (OSTI)

Hydrophobicity, the spontaneous segregation of oil and water, can be modified by surfactants. The way this modification occurs is studied at the oil-water interface for a range of alkanes and two ionic surfactants. A liquid interfacial monolayer, consisting of a mixture of alkane molecules and surfactant tails, is found. Upon cooling, it freezes at T{sub s}, well above the alkane's bulk freezing temperature, T{sub b}. The monolayer's phase diagram, derived by surface tensiometry, is accounted for by a mixtures-based theory. The monolayer's structure is measured by high-energy X-ray reflectivity above and below T{sub s}. A solid-solid transition in the frozen monolayer, occurring approximately 3 C below T{sub s}, is discovered and tentatively suggested to be a rotator-to-crystal transition.

L Tamam; D Pontoni Z Sapir; S Yefet; S Sloutskin; B Ocko; H Reichert; M Deutsch

2011-12-31T23:59:59.000Z

417

The Orientation Distributions of Lines, Surfaces, and Interfaces Around Three-Phase Boundaries in Solid Oxide Fuel Cell Cathodes  

SciTech Connect (OSTI)

Three-dimensional electron backscatter diffraction was used to measure the crystallographic distribution of the electrochemically relevant triple phase boundary lines and surfaces near them in SOFC cathodes made up of a porous mixture of yttria-stabilized zirconia and lanthanum strontium manganese oxide, both before and after mild electrochemical loading. All distributions were observed to be nearly isotropic, but non-random textures above the detection threshold were observed. The distributions differ between the two cells, as do the phase fractions and the electrochemical history. The different distributions are interpreted as evidence that steady-state distributions vary locally with phase fractions or that they evolve during the initial operation of the fuel cell. The rates at which triple lines, pore surfaces, and interface boundaries in the porous mixture approach a steady-state value appear to decrease with the average amount of mass transport required to reorient that specific feature. This work provides initial insights into the crystallography of interfaces in a multiphase ceramic material.

Dillon, Shen; Helmick, Lam; Miller, Herbert M.; Johnson, Christopher; Wilson, Lane; Gemmen, Randall; Petrova, Rumyana; Barmak, Katayun; Gerdes, Kirk; Rohrer, Gregory S.; Salvador, Paul A.

2011-11-01T23:59:59.000Z

418

High Performance Thermal Interface Technology Overview  

E-Print Network [OSTI]

An overview on recent developments in thermal interfaces is given with a focus on a novel thermal interface technology that allows the formation of 2-3 times thinner bondlines with strongly improved thermal properties at lower assembly pressures. This is achieved using nested hierarchical surface channels to control the particle stacking with highly particle-filled materials. Reliability testing with thermal cycling has also demonstrated a decrease in thermal resistance after extended times with longer overall lifetime compared to a flat interface.

R. Linderman; T. Brunschwiler; B. Smith; B. Michel

2008-01-07T23:59:59.000Z

419

High Performance Thermal Interface Technology Overview  

E-Print Network [OSTI]

An overview on recent developments in thermal interfaces is given with a focus on a novel thermal interface technology that allows the formation of 2-3 times thinner bondlines with strongly improved thermal properties at lower assembly pressures. This is achieved using nested hierarchical surface channels to control the particle stacking with highly particle-filled materials. Reliability testing with thermal cycling has also demonstrated a decrease in thermal resistance after extended times with longer overall lifetime compared to a flat interface.

Linderman, R; Smith, B; Michel, B

2008-01-01T23:59:59.000Z

420

Modeling of Taylor bubble rising in a vertical mini noncircular channel filled with a stagnant liquid  

E-Print Network [OSTI]

of the liquid phase coupled with the equations of the force balance at the bubble interface. The predicted drift by the interfacial curvature variations along bubble length, gravity, and viscous force. The interfacial profiles gas reservoir during gas production, in chemical and nuclear reactors, and numerous heat transport

Zhao, Tianshou

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Adhesion and nonwetting-wetting transition in the Al -Al2O3 interface Qing Zhang, Tahir C agin, Adri van Duin, and William A. Goddard III  

E-Print Network [OSTI]

Adhesion and nonwetting-wetting transition in the Al� -Al2O3 interface Qing Zhang, Tahir C¸ agin properties, of both solid and liquid Al/ -Al2O3 interfaces. The ReaxFF was developed solely with ab initio calculations on various phases of Al and Al2O3 and Al-O-H clusters. Our computed lattice constants, elastic

422

Multiscale Modeling of Interface Phenomena in Biology  

E-Print Network [OSTI]

-chemical processes occurring across cellular membranes. Applications will include the study of ion transport across protein membrane channels, the electrical propagation in neurons and neuro-electronic interfaces

423

A MATLAB Interface to the GPU.  

E-Print Network [OSTI]

??This thesis delves into the field of general purpose computation on graphics processing units (GPGPU). A MATLAB interface for solving numerical linear algebra on the… (more)

Brodtkorb, Bernt

2007-01-01T23:59:59.000Z

424

Elastic Wave Behavior Across Linear Slip Interfaces  

E-Print Network [OSTI]

plane waves incident at arbitrary angles upon a plane linear slip interface are computed ... Also included in these sections is an analysis ... ish, Ut is of the form.

Schoenberg, M.

425

NETL Research: Energy and Water Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water and Energy Interface Power Plant Water Management Systems Analysis & Policy Support Regulatory Drivers In-house Watershed Science & Technology R&D Water and energy are...

426

Interface conditions for Biot's equations of poroelasticity  

E-Print Network [OSTI]

Technip, Paris, 1987. 2588. 2588. J. Acoust. Soc. Am., Vol. 105, No. 5, May 1999. B. Gurevich and M. Schoenberg: Interface conditions for poroelasiticity ...

1999-04-20T23:59:59.000Z

427

Atomistic simulation of CdTe solid-liquid coexistence equilibria  

SciTech Connect (OSTI)

Atomistic simulations of CdTe using a Stillinger-Weber (S-W) interatomic potential were undertaken to model the solid-liquid phase equilibria of this important compound semiconductor. Although this potential has been used by others to study liquid CdTe and vapor-liquid interface, it is based on fitting parameters optimized only for the zincblende solid. It has not been fully explored as a potential for solid-liquid phase equilibria until this work. This research reports an accurate determination of the melting temperature, TM=1305K near P=0, the heat of fusion at melting and as a function of temperature up to 1700K, and on the relative phase densities with a particular emphasis on the melting line. The S-W potential for CdTe predicts a liquid with a density slightly less than that of the solid and, hence, the pressure-temperature melting line has a positive slope. The pair correlation structure of the liquid is determined and favorably compared to neutron scattering data. The liquid-solid interface is discussed using density profiles and a short-range order parameter for models having principal orientations along <100>, <110>, and <111> crystallographic directions.

Henager, Charles H.; Morris, James R.

2009-12-07T23:59:59.000Z

428

E-Print Network 3.0 - anisotropic porous medium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mathematics Page: << < 1 2 3 4 5 > >> Page: << < 1 2 3 4 5 > >> 21 Generalized radiative transfer equation for porous medium upscaling: application to the radiative Fourier...

429

High Performance Computing linear algorithms for two-phase flow in porous media  

E-Print Network [OSTI]

High Performance Computing linear algorithms for two-phase flow in porous media Robert Eymard High Performance Computing techniques. This implies to handle the difficult problem of solving

Paris-Sud XI, Université de

430

Additive Manufacturing Methodology and System for Fabrication of Porous Structures with Functionally Graded Properties.  

E-Print Network [OSTI]

??The focus of this dissertation is on the development of an additive manufacturing system and methodology for fabricating structures with functionally graded porous internal properties… (more)

Vlasea, Mihaela

2014-01-01T23:59:59.000Z

431

Design and manipulation of 1-D rugate photonic crystals of porous silicon for chemical sensing applications  

E-Print Network [OSTI]

Porous Si Sensor on an Arduino Platform 311phototransistor sensor mounted on an Arduino microcontrollerscheme of the low-power Arduino-mounted sensor ..313

King, Brian Henry

2010-01-01T23:59:59.000Z

432

Interactions of Plasma-Generated Species on Porous Dielectric Thin Films  

E-Print Network [OSTI]

results in high interconnectivity of the pores, called “openleading to high pore interconnectivity and high diffusivity.porous-ULK has high pore interconnectivity, which allows for

Lee, Joe

2013-01-01T23:59:59.000Z

433

Transverserly Isotropic Saturated Porous Formations: II. Wave Propagation And Application To Multipole Logging  

E-Print Network [OSTI]

The wavefields generated by monopole and dipole sources in a fluid filled borehole embedded in multilayered transversely isotropic saturated porous formations are studied.

Schmitt, D. P.

1988-01-01T23:59:59.000Z

434

Numerical Simulation of Liquid-Solid, Solid-Liquid Phase Change Using Finite Element Method in h,p,k Framework with Space-Time Variationally Consistent Integral Forms  

E-Print Network [OSTI]

: cp@T@t r (krTs) = 0 8(x;t) 2 sxt = sx t = sx (0; ) (2.1) Liquid Phase: cp@T@t r (krTl) = 0 8(x;t) 2 lxt = lx t = lx (0; ) (2.2) At the interface: Lfvn = [( krTs) ( krTl)] n 8(x;t) 2 x;t = x t (2.3) 10 in which sx and lx are solid... and liquid spatial domains, x(t) = sxT lx is the interface between the two phases, Lf is the latent heat of fusion,n is the unit exterior normal from the solid phase at the interface, and vn is the normal velocity of the interface. Subscripts s and l...

Truex, Michael

2010-07-21T23:59:59.000Z

435

Interface dynamics for layered structures  

E-Print Network [OSTI]

We investigate dynamics of large scale and slow deformations of layered structures. Starting from the respective model equations for a non-conserved system, a conserved system and a binary fluid, we derive the interface equations which are a coupled set of equations for deformations of the boundaries of each domain. A further reduction of the degrees of freedom is possible for a non-conserved system such that internal motion of each domain is adiabatically eliminated. The resulting equation of motion contains only the displacement of the center of gravity of domains, which is equivalent to the phase variable of a periodic structure. Thus our formulation automatically includes the phase dynamics of layered structures. In a conserved system and a binary fluid, however, the internal motion of domains turns out to be a slow variable in the long wavelength limit because of concentration conservation. Therefore a reduced description only involving the phase variable is not generally justified.

Takao Ohta; David Jasnow

1997-07-17T23:59:59.000Z

436

Nanofluidics, from bulk to interfaces  

E-Print Network [OSTI]

Nanofluidics has emerged recently in the footsteps of microfluidics, following the quest of scale reduction inherent to nanotechnologies. By definition, nanofluidics explores transport phenomena of fluids at the nanometer scales. Why is the nanometer scale specific ? What fluid properties are probed at nanometric scales ? In other words, why 'nanofluidics' deserves its own brand name ? In this critical review, we will explore the vast manifold of length scales emerging for the fluid behavior at the nanoscales, as well as the associated mechanisms and corresponding applications. We will in particular explore the interplay between bulk and interface phenomena. The limit of validity of the continuum approaches will be discussed, as well as the numerous surface induced effects occuring at these scales, from hydrodynamic slippage to the various electro-kinetic phenomena originating from the couplings between hydrodynamics and electrostatics. An enlightening analogy between ion transport in nanochannels and transport in doped semi-conductors will be discussed.

Lyderic Bocquet; Elisabeth Charlaix

2009-09-03T23:59:59.000Z

437

A focused liquid jet formed by a water hammer in a test tube  

E-Print Network [OSTI]

We investigate motion of a gas-liquid interface in a test tube induced by a large acceleration via impulsive force. We conduct simple experiments in which the tube partially filled with a liquid falls under gravity and impacts a rigid floor. A curved gas-liquid interface inside the tube reverses and eventually forms an elongated jet (i.e. the so-called a focused jet). In our experiments, there arises either vibration of the interface or increment in the velocity of a liquid jet accompanied by the onset of cavitation in the liquid column. These phenomena cannot be explained by considering pressure impulse in a classical potential flow analysis, which does not account for finite speeds of sound as well as phase change. Here we model such water-hammer events as a result of one-dimensional pressure wave propagation and its interaction with boundaries through acoustic impedance mismatching. The method of characteristics is applied to describe pressure wave interactions and the subsequent cavitation. The proposed m...

Kiyama, Akihito; Ando, Keita; Kameda, Masaharu

2015-01-01T23:59:59.000Z

438

Gelled Ionic Liquid-Based Membranes: Achieving a 10,000 GPU Permeance for Post-Combustion Carbon Capture with Gelled Ionic Liquid-Based Membranes  

SciTech Connect (OSTI)

IMPACCT Project: Alongside Los Alamos National Laboratory and the Electric Power Research Institute, CU-Boulder is developing a membrane made of a gelled ionic liquid to capture CO2 from the exhaust of coal-fired power plants. The membranes are created by spraying the gelled ionic liquids in thin layers onto porous support structures using a specialized coating technique. The new membrane is highly efficient at pulling CO2 out of coal-derived flue gas exhaust while restricting the flow of other materials through it. The design involves few chemicals or moving parts and is more mechanically stable than current technologies. The team is now working to further optimize the gelled materials for CO2 separation and create a membrane layer that is less than 1 micrometer thick.

None

2011-02-02T23:59:59.000Z

439

A diffuse interface model with immiscibility preservation  

SciTech Connect (OSTI)

A new, simple, and computationally efficient interface capturing scheme based on a diffuse interface approach is presented for simulation of compressible multiphase flows. Multi-fluid interfaces are represented using field variables (interface functions) with associated transport equations that are augmented, with respect to an established formulation, to enforce a selected interface thickness. The resulting interface region can be set just thick enough to be resolved by the underlying mesh and numerical method, yet thin enough to provide an efficient model for dynamics of well-resolved scales. A key advance in the present method is that the interface regularization is asymptotically compatible with the thermodynamic mixture laws of the mixture model upon which it is constructed. It incorporates first-order pressure and velocity non-equilibrium effects while preserving interface conditions for equilibrium flows, even within the thin diffused mixture region. We first quantify the improved convergence of this formulation in some widely used one-dimensional configurations, then show that it enables fundamentally better simulations of bubble dynamics. Demonstrations include both a spherical-bubble collapse, which is shown to maintain excellent symmetry despite the Cartesian mesh, and a jetting bubble collapse adjacent a wall. Comparisons show that without the new formulation the jet is suppressed by numerical diffusion leading to qualitatively incorrect results.

Tiwari, Arpit, E-mail: atiwari2@illinois.edu [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States)] [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Freund, Jonathan B., E-mail: jbfreund@illinois.edu [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Department of Aerospace Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States); Pantano, Carlos [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States)] [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States)

2013-11-01T23:59:59.000Z

440

Models for MetaVCeramic Interface Fracture  

E-Print Network [OSTI]

ChaDter 12 Models for MetaVCeramic Interface Fracture ZHIGANG SUO C. FONG SHIH Metal shortcomingthat haslimited their wide- spread use-their tendency to fracture easily. In many systems, the low on interface fracture are reviewed in this chapter. With few exceptions, attention is limited to continuum

Suo, Zhigang

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Internal and Interface Shear Strength of  

E-Print Network [OSTI]

1 Internal and Interface Shear Strength of Geosynthetic Clay Liners (GCLs): Additional Data by John Liners (GCLs): Additional Data Geosynthetic Clay Liners (GCLs) are prefabricated geocomposite materials., Zornberg, Jorge G., and Swan, Jr., Robert H. Internal and Interface Shear Strength of Geosynthetic Clay

Zornberg, Jorge G.

442

Physical barriers formed from gelling liquids: 1. numerical design of laboratory and field experiments  

SciTech Connect (OSTI)

The emplacement of liquids under controlled viscosity conditions is investigated by means of numerical simulations. Design calculations are performed for a laboratory experiment on a decimeter scale, and a field experiment on a meter scale. The purpose of the laboratory experiment is to study the behavior of multiple gout plumes when injected in a porous medium. The calculations for the field trial aim at designing a grout injection test from a vertical well in order to create a grout plume of a significant extent in the subsurface.

Finsterle, S.; Moridis, G.J.; Pruess, K.; Persoff, P.

1994-01-01T23:59:59.000Z

443

Properties of Liquid Plutonium  

SciTech Connect (OSTI)

Unalloyed polycrystalline Pu displays extreme thermal expansion behavior, i.e., {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} increases by 25% in volume and {delta} {yields} {var_epsilon} {yields} liquid decreases by 4.5% in volume. Thus, making it difficult to measure density into the liquid state. Dilatometer outfitted with CaF molten metal cell offers a proven capability to measure thermal expansion in molten metals, but has yet to be proven for Pu. Historic data from the liquid nuclear fuels program will prove extremely useful as a guide to future measurements. 3.3at% Ga changes Pu molten metal properties: 50% increase in viscosity and {approx}3% decrease in density. Fe may decrease the density by a small amount assuming an averaging of densities for Pu-Ga and Pu-Fe liquids. More recent Boivineau (2009) work needs some interpretation, but technique is being employed in (U,Pu)O{sub 2} nuclear fuels program (Pu Futures, 2012).

Freibert, Franz J. [Los Alamos National Laboratory; Mitchell, Jeremy N. [Los Alamos National Laboratory; Schwartz, Daniel S. [Los Alamos National Laboratory; Saleh, Tarik A. [Los Alamos National Laboratory; Migliori, Albert [Los Alamos National Laboratory

2012-08-02T23:59:59.000Z

444

Device for detecting the specific gravity of a liquid. [Patent application  

DOE Patents [OSTI]

A device for detecting the specific gravity of a liquid and a device for detecting the state of charge of a liquid phase electrolyte battery are described. In one embodiment of the present invention, a change in the critical angle of total internal reflection is utilized to determine the index of refraction of the liquid to be measured. It is shown that the index of refraction of the liquid is a function of the specific gravity of the liquid. In applications for measuring the state of charge of a battery, the specific gravity is proportional to the state of charge of the battery. A change in intensity of rays intersecting an interface surface indicates the critical angle which is a direct indication of the specific gravity of the liquid and the state of charge of a battery. In another embodiment, a light beam is projected through a transparent medium and then through a portion of the liquid to be measured. A change in refraction due to a change in the index of refraction of the liquid produces a deflection of the beam which is measured by a detector. The magnitude of deflection of the beam is directly proportional to the specific gravity of the liquid and the state of charge of a battery.

Derouin, C.R.; Kerwin, W.J.; McCormick, J.B.; Bobbett, R.E.

1980-11-18T23:59:59.000Z

445

Intelligent interface for design and simulation  

SciTech Connect (OSTI)

We are developing a system composed of intelligent interfaces, expert systems, and databases that uses artificial intelligence techniques to simplify the use of large simulation codes and to help design complicated physical devices. The simulation codes are used in analyzing and designing weapons, and the devices are themselves parts of weapon systems. From a designer's point of view, the simulation process is the same no matter what is being simulated. In the course of developing two intelligent interfaces for the design of nuclear weapons, we have found that data-driven programming is a useful technique for implementing an open-ended user interface to assist the designer. We discuss the simulation process as it is done now and as it could be done with intelligent interfaces. We then discuss the use of data-driven programming in a database environment to support an interface for an arbitrary number of simulation codes. 3 figs.

Draisin, W.; Peter, E.

1986-01-01T23:59:59.000Z

446

Imaging Liquids Using Microfluidic Cells  

SciTech Connect (OSTI)

Chemistry occurring in the liquid and liquid surface is important in many applications. Chemical imaging of liquids using vacuum based analytical techniques is challenging due to the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface sensitive techniques such as electron microscopy and spectroscopy. Due to its small size, low cost, and flexibility in design, liquid cells based on microfluidics have been increasingly used in studying and imaging complex phenomena involving liquids. This paper presents a review of microfluidic cells that were developed to adapt to electron microscopes and various spectrometers for in situ chemical analysis and imaging of liquids. The following topics will be covered including cell designs, fabrication techniques, unique technical features for vacuum compatible cells, and imaging with electron microscopy and spectroscopy. Challenges are summarized and recommendations for future development priority are proposed.

Yu, Xiao-Ying; Liu, Bingwen; Yang, Li

2013-05-10T23:59:59.000Z

447

Liquid metal thermal electric converter  

DOE Patents [OSTI]

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

448

Liquid crystalline composites containing phyllosilicates  

DOE Patents [OSTI]

The present invention provides barrier films having reduced gas permeability for use in packaging and coating applications. The barrier films comprise an anisotropic liquid crystalline composite layer formed from phyllosilicate-polymer compositions. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while remaining transparent. Because of the ordering of the particles in the liquid crystalline composite, barrier films comprising liquid crystalline composites are particularly useful as barriers to gas transport.

Chaiko; David J. (Naperville, IL)

2007-05-08T23:59:59.000Z

449

Bacteria transport through porous media. Annual report, December 31, 1984  

SciTech Connect (OSTI)

The following five chapters in this report have been processed separately for inclusion in the Energy Data Base: (1) theoretical model of convective diffusion of motile and non-motile bacteria toward solid surfaces; (2) interfacial electrochemistry of oxide surfaces in oil-bearing sands and sandstones; (3) effects of sodium pyrophosphate additive on the ''huff and puff''/nutrient flooding MEOR process; (4) interaction of Escherichia coli B, B/4, and bacteriophage T4D with Berea sandstone rock in relation to enhanced oil recovery; and (5) transport of bacteria in porous media and its significance in microbial enhanced oil recovery.

Yen, T.F.

1986-09-01T23:59:59.000Z

450

Method for forming gold-containing catalyst with porous structure  

DOE Patents [OSTI]

A method for forming a gold-containing catalyst with porous structure according to one embodiment of the present invention includes producing a starting alloy by melting together of gold and at least one less noble metal that is selected from the group consisting of silver, copper, rhodium, palladium, and platinum; and a dealloying step comprising at least partial removal of the less noble metal by dissolving the at least one less noble metal out of the starting alloy. Additional methods and products thereof are also presented.

Biener, Juergen; Hamza, Alex V; Baeumer, Marcus; Schulz, Christian; Jurgens, Birte; Biener, Monika M.

2014-07-22T23:59:59.000Z

451

High temperature liquid level sensor  

DOE Patents [OSTI]

A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

Tokarz, Richard D. (West Richland, WA)

1983-01-01T23:59:59.000Z

452

Brinkmann Model and Double Penalization Method for the Flow Around a Porous Thin  

E-Print Network [OSTI]

the flow of a viscous fluid around a thin layer of porous material. Using a BKW method, we perform Keywords: Navier-Stokes equations, BKW method, penalization, porous ma- terial, thin layer. 1 Introduction . These asymptotic expansions are obtained with a BKW method. With these two asymptotic expansions, we will compare

Carbou, Gilles

453

Brinkmann Model and Double Penalization Method for the Flow Around a Porous Thin  

E-Print Network [OSTI]

the flow of a viscous fluid around a thin layer of porous material. Using a BKW method, we perform Keywords: Navier-Stokes equations, BKW method, penalization, porous ma- terial, thin layer. 1 Introduction are obtained with a BKW method. With these two asymptotic expansions, we will compare both models. We

Paris-Sud XI, Université de

454

Behaviour of oil ganglia displaced by a surfactant solution in a porous medium  

E-Print Network [OSTI]

L-97 Behaviour of oil ganglia displaced by a surfactant solution in a porous medium J. C. Moulu'importance relative des forces de viscosité et des forces capillaires. Abstract. 2014 The velocity of oil ganglia residual oil phase by water injection in a porous medium [1, 2]. These studies have demonstrated

Boyer, Edmond

455

Macroscale Properties of Porous Media from a Network Model of Bio lm Processes  

E-Print Network [OSTI]

Macroscale Properties of Porous Media from a Network Model of Bio#12;lm Processes Brian J. Suchomel porosity and permeability changes in a porous medium as a result of bio#12;lm buildup in the pore spaces. A bio#12;lm consists of bacteria and extracellular polymeric substances (EPS) bonded together

456

A dual approach to tuning the porosity of porous organic polymers: controlling the porogen size and  

E-Print Network [OSTI]

. Consequently, the majority of POPs are interpenetrating networks with rela- tively low total pore volumesA dual approach to tuning the porosity of porous organic polymers: controlling the porogen size. Weston, Omar K. Farha,* Joseph T. Hupp* and SonBinh T. Nguyen* Porous organic polymers (POPs

457

Fabrication of adherent porous diamond films on sintered WC-13 wt.%Co  

E-Print Network [OSTI]

and lower threshold voltages for field emission [10]. Conductive polycrystalline diamond films are alsoFabrication of adherent porous diamond films on sintered WC-13 wt.%Co substrates by bias enhanced 2011, accepted 3 May 2011 Published online 10 August 2011 Keywords diamond films, HFCVD, porous, WC

Bristol, University of

458

DOI: 10.1002/chem.200901982 Template-Synthesized Porous Silicon Carbide as an Effective Host  

E-Print Network [OSTI]

DOI: 10.1002/chem.200901982 Template-Synthesized Porous Silicon Carbide as an Effective Host, especially those that can work more du- rably under harsh conditions. Silicon carbide (SiC) is a promising has been de- veloped for the fabrication of porous silicon carbide (SiC) by means of sin- tering

Bao, Xinhe

459

Equidimensional modelling of ow and transport processes in fractured porous systems I  

E-Print Network [OSTI]

decomposition into a fracture problem and a matrix problem. This decoupled treatment of fracture and matrix;erent hydraulic properties of fractures and the porous matrix lead to very heterogeneous ow and trans1 Equidimensional modelling of ow and transport processes in fractured porous systems I Susanna

Cirpka, Olaf Arie

460

Effects of Thermal Aging on the Mechanical Properties of a Porous-Matrix Ceramic Composite  

E-Print Network [OSTI]

Effects of Thermal Aging on the Mechanical Properties of a Porous-Matrix Ceramic Composite Eric A properties of an all-oxide fiber-reinforced composite following long-term exposure (1000 h) at temperatures of 1000­1200°C in air. The composite of interest derives its damage tolerance from a highly porous matrix

Zok, Frank

Note: This page contains sample records for the topic "liquid porous interfaces" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

The mathematical structure of multiphase thermal models of flow in porous media  

E-Print Network [OSTI]

The mathematical structure of multiphase thermal models of flow in porous media By Daniel E.A. van with the formulation and numerical solution of equations for modelling multicomponent, two-phase, thermal fluid flow typical flow behaviour that occurs during fluid injection into a reservoir. Keywords: porous media flow

462

Transp Porous Med DOI 10.1007/s11242-010-9584-x  

E-Print Network [OSTI]

Transp Porous Med DOI 10.1007/s11242-010-9584-x Thermal Analysis of Flow in a Porous Medium Over. Keywords Similarity solution · Wall suction/injection · Stretching surface · Entropy generation · Boundary Injection parameter, fw = -vwL/u0 K K Permeability, m2 L Stretching surface length, m n Power

Bahrami, Majid

463

Numerical study of natural convection in a vertical porous annulus with discrete heating  

E-Print Network [OSTI]

­10]. Among the finite enclosures, free convective heat transfer in a differentially heated vertical porous in a vertical annular enclosure for a wide range of radius and aspect ratios, and also used an approximateNumerical study of natural convection in a vertical porous annulus with discrete heating M. Sankar

Lopez, John M.

464

Mathematical Modeling and Simulation for Applications of Fluid Flow in Porous Media \\Lambda  

E-Print Network [OSTI]

Mathematical Modeling and Simulation for Applications of Fluid Flow in Porous Media \\Lambda Richard descriptions at various length scales, modeling the effects of this heterogeneity of the porous medium a computer code has been developed which gives concrete quantitative results for the total model, this out

Ewing, Richard E.

465

Investigation of water to ice phase change in porous media by ultrasonic and dielectric measurements  

E-Print Network [OSTI]

Investigation of water to ice phase change in porous media by ultrasonic and dielectric objective of this paper is to study the evolution of the ice content of porous media submitted to sub upon concrete structures is a source of main concern in cold climates (Pigeon 1984; Dash et al. 1995

Paris-Sud XI, Université de

466

UNCORRECTEDPROOF 2 Compression behavior of porous NiTi shape memory alloy  

E-Print Network [OSTI]

Ti by self-propagating 41high temperature synthesis (SHS), and again the porous 42NiTi fabricated. The compression behavior of the 11 porous NiTi was examined with the aim of using it possibly as a high energy for possible application 30 in medical implant devices and as high energy absorp- 31 tion structural material

Taya, Minoru

467

Studying colloid transport in porous media using a geocentrifuge Prabhakar Sharma,1,2,3  

E-Print Network [OSTI]

Studying colloid transport in porous media using a geocentrifuge Prabhakar Sharma,1,2,3 Markus enhance the transport of contaminants. The excessive time required to conduct flow and transport experiments in porous media led to the use of centrifuges to evaluate subsurface transport processes

Flury, Markus

468

ENS'05 Paris, France, 14-16 December 2005 CONTROL POROUS PATTERN OF ANODIC ALUMINUM OXIDE  

E-Print Network [OSTI]

ENS'05 Paris, France, 14-16 December 2005 CONTROL POROUS PATTERN OF ANODIC ALUMINUM OXIDE BY FOILS simpler, and low cost method to fabricate porous pattern of the anodic aluminum oxide (AAO) based on the aluminum foils laminate approach were carried out. During our experiments, it was found that the pores

Paris-Sud XI, Université de

469

Fundamental studies of fluid mechanics and stability in porous media. Progress report  

SciTech Connect (OSTI)

This report summarizes accomplished and proposed work for the fundamental studies of fluid mechanics and stability in porous media. Topics discussed include: viscous fingering in miscible displacements; polymer flow interactions in free shear layers of viscoelastic fluids; effect of nonmonotonic viscosity profiles on the stability of miscible displacements in porous media; and references. (JL)

Homsy, G.M.

1991-08-01T23:59:59.000Z

470

Study of Gas Flow Dynamics in Porous and Granular Media with Laser-Polarized 129  

E-Print Network [OSTI]

Abstract This thesis presents Nuclear Magnetic Resonance (NMR) studies of gas flow dynamics in porous in porous rock cores and the mass exchanges between different phases in fluidized granular systems, were-emulsion exchange and emulsion-adsorption exchange in a fluidized bed are two processes crucial to the efficiency

Walsworth, Ronald L.

471

Mathematical model and simulation of gas ow through a porous medium in high breaking capacity  

E-Print Network [OSTI]

Mathematical model and simulation of gas #29;ow through a porous medium in high breaking capacity, France. Abstract. A one-dimensional model is introduced to describe the gas #29;ow and the heat transfer model coupled with a porous medium model taking into account the mechanical interaction gas-silica sand

Sart, Remi

472

Separation of gas mixtures using Co(II) carborane-based porous coordination polymersw  

E-Print Network [OSTI]

to their inherent robustness, which results in porous materials with thermal stability and resistance towards with coordinated pyridine. Unusual selectivity for O2 over N2 (as high as 6.5) was demonstrated in the materials of materials.3 An attractive feature of porous coordination polymers lies in the rational and highly versatile

473

Recent Advances in Computational Techniques for Simulation of Flow in Porous Media  

E-Print Network [OSTI]

are also addressed. Introduction Modeling porous media flow processes is required in many science and engineering applications. Oil recovery, environmental hydrology and groundwater flow are a few drivers in the development of porous media simulation tools. Nowadays high resolution models are constructed as a result

Coutinho, Alvaro L. G. A.

474

RPM-2: A recyclable porous material with unusual adsorption capability: self assembly via structural transformations  

E-Print Network [OSTI]

-assembly of molecular electronics and smart materials will bring a new era in the field of material science.1 HoweverRPM-2: A recyclable porous material with unusual adsorption capability: self assembly via, fully recyclable porous material (RPM-2) with a very high sorption capability. Self

Li, Jing

475

BEHAVIOR OF SURFACTANT MIXTURES AT SOLID/LIQUID AND OIL/LIQUID INTERFACES IN CHEMICAL FLOODING SYSTEMS  

SciTech Connect (OSTI)

The aim of the project is to develop a knowledge base to help the design of enhanced processes for mobilizing and extracting untrapped oil. We emphasize evaluation of novel surfactant mixtures and obtaining optimum combinations of the surfactants for efficient chemical flooding EOR processes. In this regard, an understanding of the aggregate shape, size and structure is crucial since these properties govern the crude oil removal efficiency. During the three-year period, the adsorption and aggregation behavior of sugar-based surfactants and their mixtures with other types of surfactants have been studied. Sugar-based surfactants are made from renewable resources, nontoxic and biodegradable. They are miscible with water and oil. These environmentally benign surfactants feature high surface activity, good salinity, calcium and temperature tolerance, and unique adsorption behavior. They possess the characteristics required for oil flooding surfactants and have the potential for replacing currently used surfactants in oil recovery. A novel analytical ultracentrifugation technique has been successfully employed for the first time, to characterize the aggregate species present in mixed micellar solution due to its powerful ability to separate particles based on their size and shape and monitor them simultaneously. Analytical ultracentrifugation offers an unprecedented opportunity to obtain important information on mixed micelles, structure-performance relationship for different surfactant aggregates in solution and their role in interfacial processes. Initial sedimentation velocity investigations were conducted using nonyl phenol ethoxylated decyl ether (NP-10) to choose the best analytical protocol, calculate the partial specific volume and obtain information on sedimentation coefficient, aggregation mass of micelles. Four softwares: OptimaTM XL-A/XL-I data analysis software, DCDT+, Svedberg and SEDFIT, were compared for the analysis of sedimentation velocity experimental data. The results have been compared to that from Light Scattering. Based on the tests, Svedberg and SEDFIT analysis were chosen for further studies.

P. Somasundaran

2004-11-20T23:59:59.000Z

476

BEHAVIOR OF SURFACTANT MIXTURE AT SOLID/LIQUID AND OIL/LIQUID INTERFACE IN CHEMICAL FLOODING SYSTEMS  

SciTech Connect (OSTI)

The aim of the project is to develop and evaluate efficient novel surfactant mixtures for enhanced oil recovery. Preliminary ultra-filtration tests suggest that two kinds of micelles may exist in binary surfactant mixtures at different concentrations. Due to the important role played in interfacial processes by micelles as determined by their structures, focus of the current work is on the delineation of the relationship between such aggregate structures and chemical compositions of the surfactants. A novel analytical centrifuge application is explored to generate information on structures of different surfactants aggregates. In this report, optical systems, typical output of the analytical ultracentrifuge results and four basic experiments are discussed. Initial sedimentation velocity investigations were conducted using nonyl phenol ethoxylated decyl ether (NP-10) to choose the best analytical protocol, calculate the partial specific volume and obtain information on sedimentation coefficient, aggregation mass of micelles. The partial specific volume was calculated to be 0.920. Four softwares: Optima{trademark} XL-A/XL-I data analysis software, DCDT+, Svedberg and SEDFIT, were compared for the analysis of sedimentation velocity experimental data. The sedimentation coefficient and aggregation number of NP-10 micelles obtained using the first three softwares at 25 C are 209, 127, and 111, respectively. The last one is closest to the result from Light Scattering. The reason for the differences in numbers obtained using the three softwares is discussed. Based on these tests, Svedberg and SEDFIT analysis are chosen for further studies. This approach using the analytical ultracentrifugation offers an unprecedented opportunity now to obtain important information on mixed micelles and their role in interfacial processes.

Prof. P. Somasundaran

2002-03-01T23:59:59.000Z

477

Method and apparatus for electrokinetic co-generation of hydrogen and electric power from liquid water microjets  

DOE Patents [OSTI]

A method and apparatus for producing both a gas and electrical power from a flowing liquid, the method comprising: a) providing a source liquid containing ions that when neutralized form a gas; b) providing a velocity to the source liquid relative to a solid material to form a charged liquid microjet, which subsequently breaks up into a droplet spay, the solid material forming a liquid-solid interface; and c) supplying electrons to the charged liquid by contacting a spray stream of the charged liquid with an electron source. In one embodiment, where the liquid is water, hydrogen gas is formed and a streaming current is generated. The apparatus comprises a source of pressurized liquid, a microjet nozzle, a conduit for delivering said liquid to said microjet nozzle, and a conductive metal target sufficiently spaced from said nozzle such that the jet stream produced by said microjet is discontinuous at said target. In one arrangement, with the metal nozzle and target electrically connected to ground, both hydrogen gas and a streaming current are generated at the target as it is impinged by the streaming, liquid spray microjet.

Saykally, Richard J; Duffin, Andrew M; Wilson, Kevin R; Rude, Bruce S

2013-02-12T23:59:59.000Z

478

Analysis & Simulation of Dynamics in Supercooled Liquids  

E-Print Network [OSTI]

Moreover, the heat capacity of that liquid is also higherthe intensive heat capacities of the liquid and the crystal,

Elmatad, Yael Sarah

2011-01-01T23:59:59.000Z

479

Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC  

E-Print Network [OSTI]

Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC different excess Gibbs free energy models are evaluated: the NRTL, UNIQUAC and electrolyte- NRTL (eNRTL) models. In the case of eNRTL, a new formulation of the model is used, based on a symmetric reference

Stadtherr, Mark A.

480

X-ray standing waves and surface EXAFS studies of electrochemical interfaces  

SciTech Connect (OSTI)

Because of their penetrative power, X-rays are ideally suited for in-situ studies of interfaces in general and solid/liquid interfaces in particular. The recent advent of powerful X-ray synchrotron sources has made experiments of this type feasible. Synchrotron sources offer a broad spectral range of polarized, highly collimated X-rays with intensities that are 10{sup 3}-10{sup 6} higher than those of conventional sources. Moreover, third-generation synchrotron sources, with their projected increase in brightness on the order of 10{sup 4}, will allow for new types of experiments, including the study of dynamic processes in real time. There are a number of X-ray-based surface-sensitive techniques that can be employed in the study of solid/liquid interfaces, including surface EXAFS, X-ray standing waves (XSW), grazing incidence X-ray diffraction (GIXD), and others. In this Account the authors focus on the use of XSW and surface EXAFS. The authors begin with a brief theoretical description followed by experimental aspects of these techniques. The authors then discuss specific examples with emphasis on the underpotential deposition of copper on platinum in the presence and absence of coadsorbates, the potential dependent distribution of interfacial species, and potential dependent structural changes of a redox-active self-assembling monolayer. 33 refs., 7 figs.

Abruna, H.D.; Bommarito, G.M.; Yee, H.S. [Cornell Univ., Ithaca, NY (United States)

1995-06-01T23:59:59.000Z

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481

Kelvin-Helmholtz instability for flow in porous media under the influence of oblique magnetic fields: A viscous potential flow analysis  

SciTech Connect (OSTI)

In this paper, the Kelvin-Helmholtz instability of viscous incompressible magnetic fluid fully saturated porous media is achieved through the viscous potential theory. The flow is considered to be through semi-permeable boundaries above and below the fluids through which the fluid may either be blown in or sucked out, in a direction normal to the main streaming direction of the fluid flow. An oblique magnetic field, mass, heat transfer, and surface tension are present across the interface. Through the linear stability analysis, a general dispersion relation is derived and the natural curves are plotted. Therefore, the linear stability condition is discussed in some depth. In view of the multiple time scale technique, the Ginzburg–Landau equation, which describes the behavior of the system in the nonlinear approach, is obtained. The effects of the orientation of the magnetic fields on the stability configuration in linear, as well as nonlinear approaches, are discussed. It is found that the Darcy's coefficient for the porous layers plays a stabilizing role. The injection of the fluids at both boundaries has a stabilizing effect, in contrast with the suction at both boundaries.

Moatimid, Galal M. [Department of Mathematics, Faculty of Science, University of Tabuk, Tabuk, P.O. Box 741 (Saudi Arabia)] [Department of Mathematics, Faculty of Science, University of Tabuk, Tabuk, P.O. Box 741 (Saudi Arabia); Obied Allah, M. H. [Department of Mathematics, Faculty of Science, Assiut University, Assiut (Egypt)] [Department of Mathematics, Faculty of Science, Assiut University, Assiut (Egypt); Hassan, Mohamed A. [Department of Mathematics, Faculty of Education, Ain Shams University, Roxy, Cairo (Egypt)] [Department of Mathematics, Faculty of Education, Ain Shams University, Roxy, Cairo (Egypt)

2013-10-15T23:59:59.000Z

482

Liquid filtration simulation  

SciTech Connect (OSTI)

We have a developed a computer code that simulates 3-D filtration of suspended particles in fluids in realistic filter structures. This code, being the most advanced filtration simulation package developed to date, provides LLNL and DOE with new capabilities to address problems in cleaning liquid wastes, medical fluid cleaning, and recycling liquids. The code is an integrated system of commercially available and LLNL-developed software; the most critical are the computational fluid dynamics (CFD) solver and the particle transport program. For the CFD solver, we used a commercial package based on Navier-Stokes equations and a LLNL-developed package based on Boltzman-lattice gas equations. For the particle transport program, we developed a cod based on the 3-D Langevin equation of motion and the DLVO theory of electrical interactions. A number of additional supporting packages were purchased or developed to integrate the simulation tasks and to provide visualization output.

Corey, I.; Bergman, W.

1996-06-01T23:59:59.000Z

483

Electrode/electrolyte interface. A status report  

SciTech Connect (OSTI)

This is a report of a workshop on the [open quotes]state of the art[close quotes] and potential future directions in the study of the electrode/electrolyte interface. Recent advances in experimental capabilities of characterizing the structure of the interface, e.g., through the use of such techniques as scanning tunneling microscopy and X-ray methods, are described. New approaches to studies of interfacial dynamics and materials aspects of the electrode/electrolyte interface are also discussed. 346 refs., 17 figs.

Bard, A.J. (Univ. of Texas, Austin (United States)); Abruna, H.D. (Cornell Univ., Ithaca, NY (United States)); Chidsey, C.E. (Stanford Univ., CA (United States)); Faulkner, L.R. (Univ. of Illinois, Urbana-Champaign (United States)); Feldberg, S.W. (Brookhaven National Lab., Upton, NY (United States)); Itaya, Kingo (Tohoku Univ., Sendai (Japan)); Majda, M. (Univ. of California, Berkeley (United States)); Melroy, O. (IBM Almaden Research Center, San Jose, CA (United States)); Murray, R.W. (Univ. of North Carolina, Chapel Hill (United States)); Porter, M.D. (Iowa State Univ., Ames (United States)); Soriaga, M.P. (Texas A M Univ., College Station (United States)); White, H.S. (Univ. of Utah, Salt Lake City (United States))

1993-07-15T23:59:59.000Z

484

200 Area TEDF interface control document  

SciTech Connect (OSTI)

Because the TEDF does not have any treatment or retention capacity, strict control at the generator interface is essential to operate the TEDF in compliance with good engineering practices, Hanford site requirements, and the 216 Discharge Permit. The information in the Interface Control Document (ICD) forms the basis of understanding between all parties involved in the TEDF; DOE, WHC, and the generating facilities. The ICD defines the controlling document hierarchy; LEF, and generator responsibilities; monitoring and sampling requirements; and specifies the TEDF/Generator Interface points.

Brown, M.J.; Hildebrand, R.A.

1994-11-15T23:59:59.000Z

485

Latent heat fluxes through nano-engineered porous materials  

E-Print Network [OSTI]

Micro- and nano-scale truss architectures provide mechanical strength, light weight, and breatheability in polymer barriers. Liquid evaporation and transport of resulting vapor through truss voids (pores) cools surfaces ...

Traum, Matthew J. (Matthew Jason), 1977-

2007-01-01T23:59:59.000Z

486

X-ray and synchrotron studies of porous silicon  

SciTech Connect (OSTI)

The results of comprehensive studies of layers of porous silicon of different conductivity types, grown by anodizing standard Si(111) substrates in an electrolyte based on fluoric acid and ethanol with the addition of 5% of iodine and kept in air for a long time, are discussed. Measurements are performed by scanning electron microscopy, high-resolution X-ray diffraction, and ultrasoft X-ray spectroscopy using synchrotron radiation. The structural parameters of the layers (thickness, strain, and porosity) and atomic and chemical composition of the porous-silicon surface are determined. It is found that an oxide layer 1.5-2.3-nm thick is formed on the surface of the silicon skeleton. The near-edge fine structure of the Si 2p absorption spectrum of this layer corresponds to the fine structure of the 2p spectrum of well coordinated SiO{sub 2}. In this case, the fine structure in the Si 2p-edge absorption region of the silicon skeleton is identical to that of the 2p absorption spectrum of crystalline silicon.

Sivkov, V. N., E-mail: svn@dm.komisc.ru [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation); Lomov, A. A. [Russian Academy of Sciences, Physical-Technological Institute (Russian Federation)] [Russian Academy of Sciences, Physical-Technological Institute (Russian Federation); Vasil'ev, A. L. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Nekipelov, S. V. [Komi State Pedagogical Institute (Russian Federation)] [Komi State Pedagogical Institute (Russian Federation); Petrova, O. V. [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation)] [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation)

2013-08-15T23:59:59.000Z

487

Hydraulic properties of adsorbed water films in unsaturated porous media  

SciTech Connect (OSTI)

Adsorbed water films strongly influence residual water saturations and hydraulic conductivities in porous media at low saturations. Hydraulic properties of adsorbed water films in unsaturated porous media were investigated through combining Langmuir's film model with scaling analysis, without use of any adjustable parameters. Diffuse double layer influences are predicted to be important through the strong dependence of adsorbed water film thickness (f) on matric potential ({Psi}) and ion charge (z). Film thickness, film velocity, and unsaturated hydraulic conductivity are predicted to vary with z{sup -1}, z{sup -2}, and z{sup -3}, respectively. In monodisperse granular media, the characteristic grain size ({lambda}) controls film hydraulics through {lambda}{sup -1} scaling of (1) the perimeter length per unit cross sectional area over which films occur, (2) the critical matric potential ({Psi}{sub c}) below which films control flow, and (3) the magnitude of the unsaturated hydraulic conductivity when {Psi} < {Psi}{sub c}. While it is recognized that finer textured sediments have higher unsaturated hydraulic conductivities than coarser sands at intermediate {Psi}, the {lambda}{sup -1} scaling of hydraulic conductivity predicted here extends this understanding to very low saturations where all pores are drained. Extremely low unsaturated hydraulic conductivities are predicted under adsorbed film-controlled conditions (generally < 0.1 mm y{sup -1}). On flat surfaces, the film hydraulic diffusivity is shown to be constant (invariant with respect to {Psi}).

Tokunaga, Tetsu K.

2009-03-01T23:59:59.000Z

488

Emergent Phenomena at Oxide Interfaces  

SciTech Connect (OSTI)

Transition metal oxides (TMOs) are an ideal arena for the study of electronic correlations because the s-electrons of the transition metal ions are removed and transferred to oxygen ions, and hence the strongly correlated d-electrons determine their physical properties such as electrical transport, magnetism, optical response, thermal conductivity, and superconductivity. These electron correlations prohibit the double occupancy of metal sites and induce a local entanglement of charge, spin, and orbital degrees of freedom. This gives rise to a variety of phenomena, e.g., Mott insulators, various charge/spin/orbital orderings, metal-insulator transitions, multiferroics, and superconductivity. In recent years, there has been a burst of activity to manipulate these phenomena, as well as create new ones, using oxide heterostructures. Most fundamental to understanding the physical properties of TMOs is the concept of symmetry of the order parameter. As Landau recognized, the essence of phase transitions is the change of the symmetry. For example, ferromagnetic ordering breaks the rotational symmetry in spin space, i.e., the ordered phase has lower symmetry than the Hamiltonian of the system. There are three most important symmetries to be considered here. (i) Spatial inversion (I), defined as r {yields} -r. In the case of an insulator, breaking this symmetry can lead to spontaneous electric polarization, i.e. ferroelectricity, or pyroelectricity once the point group belongs to polar group symmetry. (ii) Time-reversal symmetry (T) defined as t {yields} -t. In quantum mechanics, the time-evolution of the wave-function {Psi} is given by the phase factor e{sup -iEt/{h_bar}} with E being the energy, and hence time-reversal basically corresponds to taking the complex conjugate of the wave-function. Also the spin, which is induced by the 'spinning' of the particle, is reversed by time-reversal. Broken T-symmetry is most naturally associated with magnetism, since the spin operator changes sign with T-operation. (iii) Gauge symmetry (G), which is associated with a change in the phase of the wave-function as {Psi} {yields} e{sup i{theta}}{Psi}. Gauge symmetry is connected to the law of charge conservation, and broken G-symmetry corresponds to superconductivity/superfluidity. To summarize, the interplay among these electronic degrees of freedom produces various forms of symmetry breaking patterns of I, T, and G, leading to novel emergent phenomena, which can appear only by the collective behavior of electrons and cannot be expected from individual electrons. Figure 1 shows this schematically by means of several representative phenomena. From this viewpoint, the interfaces of TMOs offer a unique and important laboratory because I is already broken by the structure itself, and the detailed form of broken I-symmetry can often be designed. Also, two-dimensionality usually enhances the effects of electron correlations by reducing their kinetic energy. These two features of oxide interfaces produce many novel effects and functions that cannot be attained in bulk form. Given that the electromagnetic responses are a major source of the physical properties of solids, and new gauge structures often appear in correlated electronic systems, we put 'emergent electromagnetism' at the center of Fig. 1.

Hwang, H.Y.

2012-02-16T23:59:59.000Z

489

Ionic liquid assisted hydrothermal fabrication of hierarchically organized ?-AlOOH hollow sphere  

SciTech Connect (OSTI)

Highlights: ? The ?-AlOOH hollow spheres were synthesized via an ionic liquid-assisted hydrothermal treatment. ? Ionic liquid plays an important role in the morphology of the product. ? Ionic liquid can be easily removed from the product and reused in next experiment. ? A “aggregation–solution–recrystallization” formation mechanism may occur in the system. -- Abstract: Hierarchically organized ?-AlOOH hollow spheres with nanoflake-like porous surface texture have been successfully synthesized via an ionic liquid-assisted hydrothermal synthesis method in citric acid monohydrate (CAMs). It was found that ionic liquid [bmim]{sup +}Cl{sup ?} played an important role in the morphology of the product due to its strong interactions with reaction particles. The samples were characterized by X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscope (SEM) and Transmission Electron Microscopy (TEM). The results show that the product has narrow particle size distribution (500–900 nm particle diameter range), high specific surface area (240.5 m{sup 2}/g) and large pore volume (0.61 cm{sup 3}/g). The corresponding ?-Al{sub 2}O{sub 3} hollow spheres can be obtained by calcining it at 550 °C for 3 h. The proposed formation mechanism and other influencing factors of the ?-AlOOH hollow sphere material, such as reaction temperature, reaction duration, CAMs and urea, have also been investigated.

Tang, Zhe, E-mail: tangzhe1983@163.com [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China)] [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China); Liu, Yunqi, E-mail: liuyq@upc.edu.cn [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China)] [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China); Li, Guangci, E-mail: liguangci1984@yahoo.com.cn [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China)] [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China); Hu, Xiaofu, E-mail: hjj19850922@126.cn [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China)] [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China); Liu, Chenguang, E-mail: cgliu@upc.edu.cn [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China)] [State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis, China National Petroleum Corporation (CNPC), China University of Petroleum (East China), Qingdao 266555 (China)

2012-11-15T23:59:59.000Z

490

Microsoft Word - 51-9105936-001 NHS boundaries and interfaces...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

System Included components Boundaries Physical interfaces Other interfaces the detector wells for the sensing device of the external neutron flux detectors 11) Component Handling...

491

Interface-induced magnetism in perovskite quantum wells  

E-Print Network [OSTI]

INTERFACE-INDUCED MAGNETISM IN PEROVSKITE . . . PHYSICALR) (2013) Interface-induced magnetism in perovskite quantumelectron gases, and magnetism can all be found in a single

Jackson, Clayton A; Stemmer, Susanne

2013-01-01T23:59:59.000Z

492

Integration of Advanced Materials and Interfaces for Durable...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advanced Materials and Interfaces for Durable Thermoelectric Automobile Exhaust Waste Heat Harvesting Devices Integration of Advanced Materials and Interfaces for Durable...

493

Methodology and Techniques for Building Modular Brain-Computer Interfaces.  

E-Print Network [OSTI]

??Commodity brain-computer interfaces (BCI) are beginning to accompany everything from toys and games to sophisticated health care devices. These contemporary interfaces allow for varying levels… (more)

Cummer, Jason

2015-01-01T23:59:59.000Z

494

Is the Calcite-Water Interface Understood? Direct Comparisons...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Is the Calcite-Water Interface Understood? Direct Comparisons of Molecular Dynamics Simulations with Specular X-ray Reflectivity Is the Calcite-Water Interface Understood? Direct...

495

Advanced Thermal Interface Materials (TIMs) for Power Electronics...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermal Interface Materials (TIMs) for Power Electronics Advanced Thermal Interface Materials (TIMs) for Power Electronics 2009 DOE Hydrogen Program and Vehicle Technologies...

496

Liquid Chromatograph | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and Interfaces Sample6, 2011Liisa O'Neill AboutLiquefied

497

Millisecond time resolution neutron reflection from a nematic liquid crystal  

SciTech Connect (OSTI)

The director reorientation of the liquid crystal 4,4' octyl cyanobiphenyl in the nematic phase under application of bursts of ac field have been observed using time-resolved neutron scattering in reflection geometry. The relaxation of the director has been shown to agree with existing theory, as determined by material and cell parameters. This result shows that it is possible to use neutron reflection measurements from buried interfaces to follow kinetic processes on a time scale comparable with the pulse length of the ISIS neutron source (20 ms)

Dalgliesh, R.M.; Lau, Y.G.J.; Richardson, R.M.; Riley, D.J. [ISIS Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 0QX (United Kingdom); H.H. Wills Physics Laboratory, University of Bristol, Tyndall Avenue, Bristol BS8 1TL (United Kingdom); School of Chemistry, University of Bristol, Cantocks Close, Bristol BS8 1TS (United Kingdom)

2004-09-01T23:59:59.000Z

498

Low Frequency Acoustic Resonance Studies of the Liquid-Vapor Transition in Silica Aerogel  

E-Print Network [OSTI]

Fluid phase transitions in porous media are a powerful probe of the effect of confinement and disorder on phase transitions. Aerogel may provide a model system in which to study the effect of dilute impurities on a variety of phase transitions. In this paper we present a series of low frequency acoustic experiments on the effect of aerogel on the liquid-vapor phase transition. Acoustic resonators were used to study the liquid-vapor transition in two fluids (helium and neon) and in two different porosity aerogels (95% and 98%). While effective coexistence curves could be mapped out, the transition was sometimes difficult to pinpoint, leading to doubt as to whether this transition can be treated as an equilibrium macroscopic phase transition at all.

Tobias Herman; John Beamish

2005-06-30T23:59:59.000Z

499

Liquid–solid phase transition of hydrogen and deuterium in silica aerogel  

SciTech Connect (OSTI)

Behavior of hydrogen isotopes confined in disordered low-density nanoporous solids remains essentially unknown. Here, we use relaxation calorimetry to study freezing and melting of H{sub 2} and D{sub 2} in an ?85%-porous base-catalyzed silica aerogel. We find that liquid–solid transition temperatures of both isotopes inside the aerogel are depressed. The phase transition takes place over a wide temperature range of ?4?K and non-trivially depends on the liquid filling fraction, reflecting the broad pore size distribution in the aerogel. Undercooling is observed for both H{sub 2} and D{sub 2} confined inside the aerogel monolith. Results for H{sub 2} and D{sub 2} are extrapolated to tritium-containing hydrogens with the quantum law of corresponding states.

Van Cleve, E.; Worsley, M. A.; Kucheyev, S. O., E-mail: kucheyev@llnl.gov [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

2014-10-28T23:59:59.000Z

500

Vibrational Sum Frequency Spectroscopy and Molecular Dynamics Simulation of the Carbon Tetrachloride-Water and 1,2-Dichloroethane-Water Interfaces  

E-Print Network [OSTI]

and bonding at the carbon tetrachloride-water (CCl4-H2O) and the 1,2-dichloroethane-water (DCE-H2O) liquidVibrational Sum Frequency Spectroscopy and Molecular Dynamics Simulation of the Carbon Tetrachloride-Water and 1,2-Dichloroethane-Water Interfaces Dave S. Walker, Fred G. Moore, and Geraldine L

Richmond, Geraldine L.