Sample records for liquid hydrogen methanol

  1. X-ray Absorption Spectroscopy of Liquid Methanol Microjets: Bulk Electronic Structure and Hydrogen Bonding Network

    E-Print Network [OSTI]

    Cohen, Ronald C.

    of ice,15,16 or at the liquid-gas interface.3 As expected, water in its various phases is a natural, Sweden, AdVanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720

  2. Liquid phase methanol reactor staging process for the production of methanol

    DOE Patents [OSTI]

    Bonnell, Leo W. (Macungie, PA); Perka, Alan T. (Macungie, PA); Roberts, George W. (Emmaus, PA)

    1988-01-01T23:59:59.000Z

    The present invention is a process for the production of methanol from a syngas feed containing carbon monoxide, carbon dioxide and hydrogen. Basically, the process is the combination of two liquid phase methanol reactors into a staging process, such that each reactor is operated to favor a particular reaction mechanism. In the first reactor, the operation is controlled to favor the hydrogenation of carbon monoxide, and in the second reactor, the operation is controlled so as to favor the hydrogenation of carbon dioxide. This staging process results in substantial increases in methanol yield.

  3. (Non) formation of methanol by direct hydrogenation of formate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Non) formation of methanol by direct hydrogenation of formate on copper catalysts. (Non) formation of methanol by direct hydrogenation of formate on copper catalysts. Abstract: We...

  4. Method of steam reforming methanol to hydrogen

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA)

    1990-01-01T23:59:59.000Z

    The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

  5. Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...

    Broader source: Energy.gov (indexed) [DOE]

    Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  6. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  7. Theoretical study of syngas hydrogenation to methanol on the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001) surface. Theoretical study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001)...

  8. Method for making methanol

    DOE Patents [OSTI]

    Mednick, R. Lawrence (Roslyn Heights, NY); Blum, David B. (Wayne, NJ)

    1986-01-01T23:59:59.000Z

    Methanol is made in a liquid-phase methanol reactor by entraining a methanol-forming catalyst in an inert liquid and contacting said entrained catalyst with a synthesis gas comprising hydrogen and carbon monoxide.

  9. Method for making methanol

    DOE Patents [OSTI]

    Mednick, R. Lawrence (Roslyn Heights, NY); Blum, David B. (Wayne, NJ)

    1987-01-01T23:59:59.000Z

    Methanol is made in a liquid-phase methanol reactor by entraining a methanol-forming catalyst in an inert liquid and contacting said entrained catalyst with a synthesis gas comprising hydrogen and carbon monoxide.

  10. Liquid Hydrogen Absorber for MICE

    E-Print Network [OSTI]

    Ishimoto, S.

    2010-01-01T23:59:59.000Z

    REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

  11. Environmental information volume: Liquid Phase Methanol (LPMEOH{trademark}) project

    SciTech Connect (OSTI)

    NONE

    1996-05-01T23:59:59.000Z

    The purpose of this project is to demonstrate the commercial viability of the Liquid Phase Methanol Process using coal-derived synthesis gas, a mixture of hydrogen and carbon monoxide. This report describes the proposed actions, alternative to the proposed action, the existing environment at the coal gasification plant at Kingsport, Tennessee, environmental impacts, regulatory requirements, offsite fuel testing, and DME addition to methanol production. Appendices include the air permit application, solid waste permits, water permit, existing air permits, agency correspondence, and Eastman and Air Products literature.

  12. Gaseous and Liquid Hydrogen Storage

    Broader source: Energy.gov [DOE]

    Today's state of the art for hydrogen storage includes 5,000- and 10,000-psi compressed gas tanks and cryogenic liquid hydrogen tanks for on-board hydrogen storage.

  13. Structural dynamics of hydrogen bonded methanol oligomers: Vibrational transient hole burning studies of spectral diffusion

    E-Print Network [OSTI]

    Fayer, Michael D.

    Structural dynamics of hydrogen bonded methanol oligomers: Vibrational transient hole burning resolved pump-probe experiments have been conducted on the deuterated hydroxyl stretch of methanol-d in a solution containing 0.8% methanol-d/23% methanol-h in carbon tetrachloride. Methanol-d molecules that both

  14. Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Takeda, Kouichi; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Minoura, Tsuyoshi [Mitui Engineering and Shipbuilding Co., Ltd., Tokyo (Japan)

    1995-05-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured for the ternary system methanol + ethanol + water and its constituent binary systems of methanol + water and ethanol + water at 323.15, 328.15, and 333.15 K. The apparatus that was used made it possible to control the measured temperature and total pressure by computer. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

  15. Liquid-liquid equilibrium of cyclohexane-n-hexane-methanol mixtures; Effect of water content

    SciTech Connect (OSTI)

    Alessi, P.; Fermeglia, M.; Kikic, I. (Istituto di Chimica Applicata e Industriale, University of Trieste, via Valerio 2, I-34127 Trieste (IT))

    1989-04-01T23:59:59.000Z

    Experimental liquid-liquid equilibrium data for the ternary system cyclohexane-n-hexane-methanol and for the binary systems n-hexane-methanol and cyclohexane-methanol are presented over a temperature range from 284 to 298{Kappa} at pressure of 0.1 MPa. Attention is given to the effect of the purity of methanol as far as the water content is concerned. The data are correlated by means of excess Gibbs energy models (NRTL and UNIQUAC), and the binary interaction parameters are reported.

  16. Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

  17. Advanced hydrogen/methanol utilization technology demonstration. Phase II: Hydrogen cold start of a methanol vehicle

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    This is the Phase 11 Final Report on NREL Subcontract No. XR-2-11175-1 {open_quotes}Advanced Hydrogen/Methane Utilization Demonstration{close_quotes} between the National Renewable Energy Laboratory (NREL), Alternative Fuels Utilization Program, Golden, Colorado and Hydrogen Consultants, Inc. (HCI), Littleton, Colorado. Mr. Chris Colucci was NREL`s Technical Monitor. Colorado State University`s (CSU) Engines and Energy Conversion Laboratory was HCI`s subcontractor. Some of the vehicle test work was carried out at the National Center for Vehicle Emissions Control and Safety (NCVECS) at CSU. The collaboration of the Colorado School of Mines is also gratefully acknowledged. Hydrogen is unique among alternative fuels in its ability to burn over a wide range of mixtures in air with no carbon-related combustion products. Hydrogen also has the ability to burn on a catalyst, starting from room temperature. Hydrogen can be made from a variety of renewable energy resources and is expected to become a widely used energy carrier in the sustainable energy system of the future. One way to make a start toward widespread use of hydrogen in the energy system is to use it sparingly with other alternative fuels. The Phase I work showed that strong affects could be achieved with dilute concentrations of hydrogen in methane (11). Reductions in emissions greater than the proportion of hydrogen in the fuel provide a form of leverage to stimulate the early introduction of hydrogen. Per energy unit or per dollar of hydrogen, a greater benefit is derived than simply displacing fossil-fueled vehicles with pure hydrogen vehicles.

  18. Effect of Transient Hydrogen Evolution/Oxidation Reactions on the OCV of Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Zhao, Tianshou

    Effect of Transient Hydrogen Evolution/Oxidation Reactions on the OCV of Direct Methanol Fuel Cells of a direct methanol fuel cell DMFC was observed to undergo an overshoot before it stabilized during. Available electronically August 16, 2005. Direct methanol fuel cells DMFCs are considered as a hopeful

  19. Discovery of molecular hydrogen line emission associated with methanol maser emission

    E-Print Network [OSTI]

    Ashley, Michael C. B.

    Discovery of molecular hydrogen line emission associated with methanol maser emission J.-K. Lee March 9 A B S T R AC T We report the discovery of H2 line emission associated with 6.67-GHz methanol emission was found associated with an ultracompact H II region IRAS 14567­5846 and isolated methanol maser

  20. Molecular Hydrogen from Methanol Maser Sources { Out ow from the Earliest Stage of Star Formation?

    E-Print Network [OSTI]

    Burton, Michael

    Molecular Hydrogen from Methanol Maser Sources { Out ow from the Earliest Stage of Star Formation in its natal molecular cloud. The strong methanol maser transition 5 1 { 6 0 A + at 6.7 GHz has also been that methanol maser emission usually occurs in massive star forming regions but away from the UCHII regions

  1. Three-Dimensional Simulations of Liquid Feed Direct Methanol Wenpeng Liu*,a

    E-Print Network [OSTI]

    Three-Dimensional Simulations of Liquid Feed Direct Methanol Fuel Cells Wenpeng Liu*,a and Chao that performance and design of a liquid feed direct methanol fuel cell DMFC is controlled not only by electrochemical kinetics and methanol crossover but also by water transport and by their complex interactions

  2. Development of high-power electrodes for a liquid-feed direct methanol fuel cell

    E-Print Network [OSTI]

    Development of high-power electrodes for a liquid-feed direct methanol fuel cell C. Lim, C.Y. Wang for a liquid-feed direct methanol fuel cell (DMFC) were fabricated by using a novel method of modi®ed Na.V. All rights reserved. Keywords: Direct methanol fuel cells; Membrane-electrode assembly (MEA); Polymer

  3. Multiple Time-Scale Behaviour and Network Dynamics in Liquid Methanol

    E-Print Network [OSTI]

    Ruchi Sharma; Charusita Chakravarty

    2008-11-11T23:59:59.000Z

    Canonical ensemble molecular dynamics simulations of liquid methanol, modeled using a rigid-body, pair-additive potential, are used to compute static distributions and temporal correlations of tagged molecule potential energies as a means of characterising the liquid state dynamics. The static distribution of tagged molecule potential energies shows a clear multimodal structure with three distinct peaks, similar to those observed previously in water and liquid silica. The multimodality is shown to originate from electrostatic effects, but not from local, hydrogen-bond interactions. An interesting outcome of this study is the remarkable similarity in the tagged potential energy power spectra of methanol, water and silica, despite the differences in the underlying interactions and the dimensionality of the network. All three liquids show a distinct multiple time scale (MTS) regime with a 1/f dependence with a clear positive correlation between the scaling exponent alpha and the diffusivity. The low-frequency limit of the MTS regime is determined by the frequency of crossover to white noise behaviour which occurs at approximately 0.1 cm{-1} in the case of methanol under standard temperature and pressure conditions. The power spectral regime above 200 cm{-1} in all three systems is dominated by resonances due to localised vibrations, such as librations. The correlation between $\\alpha$ and the diffusivity in all three liquids appears to be related to the strength of the coupling between the localised motions and the larger length/time-scale network reorganizations. Thus the time scales associated with network reorganization dynamics appear to be qualitatively similar in these systems, despite the fact that water and silica both display diffusional anomalies but methanol does not.

  4. Methanol Synthesis from CO2 Hydrogenation over a Pd4/In2O3 Model...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model Catalyst: A Combined DFT and Kinetic Study. Methanol Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model Catalyst: A...

  5. Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

    1993-07-01T23:59:59.000Z

    Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

  6. Vapor-liquid equilibria for methanol + tetraethylene glycol dimethyl ether

    SciTech Connect (OSTI)

    Esteve, X.; Chaudhari, S.K.; Coronas, A. [Univ. Rovira i Virgili, Tarragona (Spain). Dept. of Electrical and Mechanical Engineering

    1995-11-01T23:59:59.000Z

    Vapor-liquid equilibrium (P-T-x) for the methanol + tetraethylene glycol dimethyl ether binary system were obtained by the static method in the range of temperatures from 293.15 to 423.15 K at 10 K intervals. The modified vapor pressure apparatus used is described. The Kuczynsky method was used to calculate the liquid and vapor composition and the activity coefficients of methanol from the initial composition of the sample and the measured pressure and temperature. The results were correlated by the NRTL and UNIQUAC temperature dependent activity coefficient models. This system shows nearly ideal behavior at 323.15 K, but positive deviations from ideality at lower temperatures and negative deviations at higher temperatures are observed. The activity coefficients become more negative with the increase in temperature and mole fraction of methanol. The excess molar enthalpy using the Gibss-Helmholtz equation and the NRTL and UNIQUAC parameters were calculated at 303.15 K and compared with experimental data. This binary system shows promise as a working pair for high-temperature heat pump applications.

  7. Structure of liquid and glassy methanol confined in cylindrical pores Denis Morineau1,2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Structure of liquid and glassy methanol confined in cylindrical pores Denis Morineau1,2 , Régis scattering analysis of the density and the static structure factor of confined methanol at various and D=35 Ĺ. A change of the thermal expansivity of confined methanol at low temperature is the signature

  8. Photoelectrochemical hydrogen production from water/ methanol decomposition using Ag/TiO2 nanocomposite

    E-Print Network [OSTI]

    coal and gasoline [3]. Moreover, hydrogen can be used in fuel cells to generate electricity, or directly as a transportation fuel [4]. Hydrogen can be generated from hydrocarbons and water resourcesPhotoelectrochemical hydrogen production from water/ methanol decomposition using Ag/TiO2

  9. Agenda for the Derived Liquids to Hydrogen Distributed Reforming...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Agenda for the Derived Liquids to Hydrogen Distributed...

  10. Mechanism of Methanol Synthesis on Cu through CO2 and CO Hydrogenation

    SciTech Connect (OSTI)

    Grabow, Lars C.; Mavrikakis, Manos

    2011-03-04T23:59:59.000Z

    We present a comprehensive mean-field microkinetic model for the methanol synthesis and water-gas-shift (WGS) reactions that includes novel reaction intermediates, such as formic acid (HCOOH) and hydroxymethoxy (CH?O?) and allows for the formation of formic acid (HCOOH), formaldehyde (CH?O), and methyl formate (HCOOCH?) as byproducts. All input model parameters were initially derived from periodic, self-consistent, GGA-PW91 density functional theory calculations on the Cu(111) surface and subsequently fitted to published experimentalmethanol synthesis rate data, which were collected under realistic conditions on a commercial Cu/ZnO/Al?O? catalyst. We find that the WGS reaction follows the carboxyl (COOH)-mediated path and that both CO and CO? hydrogenation pathways are active for methanol synthesis. Under typical industrial methanol synthesis conditions, CO? hydrogenation is responsible for ?2/3 of the methanol produced. The intermediates of the CO? pathway for methanol synthesis include HCOO*, HCOOH*, CH?O?*, CH?O*, and CH?O*. The formation of formate (HCOO*) from CO?* and H* on Cu(111) does not involve an intermediate carbonate (CO?*) species, and hydrogenation of HCOO* leads to HCOOH* instead of dioxymethylene (H?CO?*). The effect of CO is not only promotional; CO* is also hydrogenated in significant amounts to HCO*, CH?O *, CH?O*, and CH?OH*. We considered two possibilities for CO promotion: (a) removal of OH* via COOH* to form CO? and hydrogen (WGS), and (b) CO-assisted hydrogenation of various surface intermediates, with HCO* being the H-donor. Only the former mechanism contributes to methanol formation, but its effect is small compared with that of direct CO hydrogenation to methanol. Overall, methanol synthesis rates are limited by methoxy (CH?O*) formation at low CO?/(CO+CO?) ratios and by CH?O* hydrogenation in CO?-rich feeds. CH?O* hydrogenation is the common slow step for both the CO and the CO? methanol synthesis routes; the relative contribution of each route is determined by their respective slow steps HCO*+H*?CH?O*+* and HCOOH*+H*?CH?O?*+* as well as by feed composition and reaction conditions. An analysis of the fitted parameters for a commercial Cu/ZnO/Al?O? catalyst suggests that a more open Cu surface, for example, Cu(110), Cu(100), and Cu(211) partially covered by oxygen, may provide a better model for the active site of methanol synthesis, but our studies cannot exclude a synergistic effect with the ZnO support.

  11. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  12. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  13. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  14. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  15. (Non) formation of methanol by direct hydrogenation of formate on copper catalysts

    SciTech Connect (OSTI)

    Yang, Yong; Mims, Charles A.; Disselkamp, Robert S.; Kwak, Ja Hun; Peden, Charles HF; Campbell, C. T.

    2010-10-14T23:59:59.000Z

    We have attempted to hydrogenate adsorbed formate species on copper catalysts to probe the importance of this postulated mechanistic step in methanol synthesis. Surface formate coverages up to 0.25 were produced at temperatures between 413K and 453K on supported (Cu/SiO2) copper and unsupported copper catalysts. The adlayers were produced by various methods including (1) steady state catalytic conditions in CO2-H2 (3:1, 6 bar) atmospheres, and (2) by exposure of the catalysts to formic acid. As reported in earlier work, the catalytic surface at steady state contains bidentate formate species with coverages up to saturation levels of ~ 0.25 at the low temperatures of this study. The reactivity of these formate adlayers was investigated at relevant reaction temperatures in atmospheres containing up to 6 bar H2 partial pressure by simultaneous mass spectrometry (MS) and infrared (IR) spectroscopy measurements. The yield of methanol during the attempted hydrogenation (“titration”) of these adlayers was insignificant (<0.2 mol % of the formate adlayer) even in dry hydrogen partial pressures up to 6 bar. Hydrogen titration of formate species produced from formic acid also failed to produce significant quantities of methanol, and attempted titration in gases consisting of CO-hydrogen mixtures or dry CO2 were also unproductive. The formate decomposition kinetics, measured by IR, were also unaffected by these changes in the gas composition. Similar experiments on unsupported copper also failed to show any methanol. From these results, we conclude that methanol synthesis on copper cannot result from the direct hydrogenation of (bidentate) formate species in simple steps involving adsorbed H species alone. Furthermore, experiments performed on both supported (Cu/SiO2) and unsupported copper catalysts gave similar results implying that the methanol synthesis reaction mechanism only involves metal surface chemistry. Pre-exposure of the bidentate formate adlayer to oxidation by O2 or N2O produces a change to a monodentate configuration. Attempted titration of this monodentate formate/O coadsorbed layer in dry hydrogen produces significant quantities of methanol, although decomposition of formate to carbon dioxide and hydrogen remains the dominant reaction pathway. Simultaneous production of water is also observed during this titration as the copper surface is re-reduced. These results indicate that co-adsorbates related to surface oxygen or water-derived species may be critical to methanol production on copper, perhaps assisting in the hydrogenation of adsorbed formate to adsorbed methoxyl.

  16. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-04-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

  17. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Working Group (BILIWG), Hydrogen Separation and Purification Working Group (PURIWG) & Hydrogen Production Technical Team Bio-Derived Liquids to Hydrogen Distributed Reforming...

  18. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

  19. Simultaneous photon absorption as a probe of molecular interaction and hydrogen-bond correlation in liquids

    E-Print Network [OSTI]

    Sander Woutersen

    2007-03-06T23:59:59.000Z

    We have investigated the simultaneous absorption of near-infrared photons by pairs of neighboring molecules in liquid methanol. Simultaneous absorption by two OH-stretching modes is found to occur at an energy higher than the sum of the two absorbing modes. This frequency shift arises from interaction between the modes, and its value has been used to determine the average coupling between neighboring methanol molecules. We find a rms coupling strength of 46+/-1 cm-1, much larger than can be explained from transition-dipole coupling, suggesting that hydrogen-bond mediated interactions between neighboring molecules play an important role in liquid methanol. The most important aspect of simultaneous vibrational absorption is that it allows for a quantitative investigation of hydrogen-bond cooperativity. We derive the extent to which the hydrogen-bond strengths of neighboring molecules are correlated by comparing the line shape of the absorption band caused by simultaneous absorption with that of the fundamental transition. Surprisingly, neighboring hydrogen bonds in methanol are found to be strongly correlated, and from the data we obtain a hydrogen-bond correlation coefficient of 0.69+/-0.12.

  20. Liquid-liquid equilibria of water + methanol + 1-octanol and water + ethanol + 1-octanol at various temperatures

    SciTech Connect (OSTI)

    Arce, A.; Blanco, A.; Souza, P.; Vidal, I. (Univ. of Santiago de Compostela (Spain). Dept. of Chemical Engineering)

    1994-04-01T23:59:59.000Z

    This study is part of a wider program of research on the recovery of light alcohols from dilute aqueous solutions using high molecular weight solvents. The authors report liquid-liquid equilibrium data and binodal curves for the systems water + methanol + 1-octanol and water + ethanol + 1-octanol at 25, 35, and 45 C. The data were fitted to the NRTL and UNIQUAC equations.

  1. Hydrogen production from methanol decomposition over Pt/Al2O3 and ceria promoted Pt/Al2O3 catalysts

    E-Print Network [OSTI]

    Gulari, Erdogan

    Hydrogen production from methanol decomposition over Pt/Al2O3 and ceria promoted Pt/Al2O3 catalysts-based catalysts in the production of hydrogen from methanol through catalytic decomposition rights reserved. Keywords: Methanol decomposition; Pt/alumina; Ceria; Hydrogen; PEM fuel cell 1

  2. Journal of Power Sources 164 (2007) 189195 Modeling water transport in liquid feed direct methanol fuel cells

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    Journal of Power Sources 164 (2007) 189­195 Modeling water transport in liquid feed direct methanol management in direct methanol fuel cells (DMFCs) is very critical and complicated because of many interacting rights reserved. Keywords: Direct methanol fuel cell; Water transport; Mathematical modeling; Three

  3. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-09-30T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  4. Computational study of ion distributions at the air/liquid methanol interface

    SciTech Connect (OSTI)

    Sun, Xiuquan; Wick, Collin D.; Dang, Liem X.

    2011-06-16T23:59:59.000Z

    Molecular dynamic simulations with polarizable potentials were performed to systematically investigate the distribution of NaCl, NaBr, NaI, and SrCl2 at the air/liquid methanol interface. The density profiles indicated that there is no substantial enhancement of anions at the interface for the NaX systems in contrast to what was observed at the air/aqueous interface. The surfactant-like shape of the larger more polarizable halide anions is compensated by the surfactant nature of methanol itself. As a result, methanol hydroxy groups strongly interacted with one side of polarizable anions, in which their induced dipole points, and methanol methyl groups were more likely to be found near the positive pole of anion induced dipoles. Furthermore, salts were found to disrupt the surface structure of methanol, reducing the observed enhancement of methyl groups at the outer edge of the air/liquid methanol interface. With the additional of salts to methanol, the computed surface potentials increased, which is in contrast to what is observed in corresponding aqueous systems, where the surface potential decreases with the addition of salts. Both of these trends have been indirectly observed with experiments. This was found to be due to the propensity of anions for the air/water interface that is not present at the air/liquid methanol interface. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  5. A Theoretical Study of Methanol Synthesis from CO(2) Hydrogenation on Metal-doped Cu(111) Surfaces

    SciTech Connect (OSTI)

    Liu P.; Yang, Y.; White, M.G.

    2012-01-12T23:59:59.000Z

    Density functional theory (DFT) calculations and Kinetic Monte Carlo (KMC) simulations were employed to investigate the methanol synthesis reaction from CO{sub 2} hydrogenation (CO{sub 2} + 3H{sub 2} {yields} CH{sub 3}OH + H{sub 2}O) on metal-doped Cu(111) surfaces. Both the formate pathway and the reverse water-gas shift (RWGS) reaction followed by a CO hydrogenation pathway (RWGS + CO-Hydro) were considered in the study. Our calculations showed that the overall methanol yield increased in the sequence: Au/Cu(111) < Cu(111) < Pd/Cu(111) < Rh/Cu(111) < Pt/Cu(111) < Ni/Cu(111). On Au/Cu(111) and Cu(111), the formate pathway dominates the methanol production. Doping Au does not help the methanol synthesis on Cu(111). Pd, Rh, Pt, and Ni are able to promote the methanol production on Cu(111), where the conversion via the RWGS + CO-Hydro pathway is much faster than that via the formate pathway. Further kinetic analysis revealed that the methanol yield on Cu(111) was controlled by three factors: the dioxomethylene hydrogenation barrier, the CO binding energy, and the CO hydrogenation barrier. Accordingly, two possible descriptors are identified which can be used to describe the catalytic activity of Cu-based catalysts toward methanol synthesis. One is the activation barrier of dioxomethylene hydrogenation, and the other is the CO binding energy. An ideal Cu-based catalyst for the methanol synthesis via CO{sub 2} hydrogenation should be able to hydrogenate dioxomethylene easily and bond CO moderately, being strong enough to favor the desired CO hydrogenation rather than CO desorption but weak enough to prevent CO poisoning. In this way, the methanol production via both the formate and the RWGS + CO-Hydro pathways can be facilitated.

  6. Liquid Hydrogen Absorber for MICE

    E-Print Network [OSTI]

    Ishimoto, S.

    2010-01-01T23:59:59.000Z

    hydrogen leakage and heat inputs to the absorber. In MICE,vacuum region. To minimize heat input from the magnet bore,To minimize radiative heat input from surrounding material,

  7. Mathematical Modeling of Liquid-Feed Direct Methanol Fuel Z. H. Wang* and C. Y. Wang*,z

    E-Print Network [OSTI]

    Mathematical Modeling of Liquid-Feed Direct Methanol Fuel Cells Z. H. Wang* and C. Y. Wang for liquid-feed direct methanol fuel cells DMFC . In addition to the anode and cathode electrochemical electronically March 4, 2003. Fuel cells promise to replace the internal combustion engine in transportation due

  8. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-04-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

  9. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-06-30T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the seventh report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 31, 2005. This quarter saw progress in these areas. These areas are: (1) Steam reformer transient response, (2) Heat transfer enhancement, (3) Catalyst degradation, (4) Catalyst degradation with bluff bodies, and (5) Autothermal reforming of coal-derived methanol. All of the projects are proceeding on or slightly ahead of schedule.

  10. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-06-30T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the third report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 30, 2004. This quarter saw progress in five areas. These areas are: (1) External evaluation of coal based methanol and the fuel cell grade baseline fuel, (2) Design, set up and initial testing of the autothermal reactor, (3) Experiments to determine the axial and radial thermal profiles of the steam reformers, (4) Catalyst degradation studies, and (5) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

  11. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2006-01-01T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  12. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets...

    Broader source: Energy.gov (indexed) [DOE]

    Development Manager, U.S. DOE Office of Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technologies Program Bio-Derived Liquids to Hydrogen...

  13. Isobaric vapor-liquid equilibria of methanol + 1-octanol and ethanol + 1-octanol mixtures

    SciTech Connect (OSTI)

    Arce, A.; Blanco, A.; Soto, A.; Tojo, J. [Univ. of Santiago de Compostela (Spain). Chemical Engineering Dept.

    1995-07-01T23:59:59.000Z

    Isobaric vapor-liquid equilibrium data for methanol + 1-octanol and ethanol + 1-octanol have been measured at 101.325 kPa. The results were checked for thermodynamic consistency using Fredenslund et al.`s test, correlated using Wilson, NRTL, and UNIQUAC equations for the liquid phase activity coefficients, and compared with the predictions of the ASOG, UNIFAC, and modified UNIFAC group contribution methods.

  14. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

  15. HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL

    SciTech Connect (OSTI)

    Paul A. Erickson

    2004-04-01T23:59:59.000Z

    Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the first such report that will be submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1--December 31, 2003. This quarter saw progress in three areas. These areas are: (1) Evaluations of coal based methanol and the fuel cell grade baseline fuel, (2) Design and set up of the autothermal reactor, as well as (3) Set up and data collection of baseline performance using the steam reformer. All of the projects are proceeding on schedule. During this quarter one conference paper was written that will be presented at the ASME Power 2004 conference in March 2004, which outlines the research direction and basis for looking at the coal to hydrogen pathway.

  16. Toward new solid and liquid phase systems for the containment, transport and delivery of hydrogen

    Broader source: Energy.gov [DOE]

    Toward new solid and liquid phase systems for the containment, transport and delivery of hydrogen.Solid and liquid hydrogen carriers for use in hydrogen storage and delivery.

  17. A High-Yield, Liquid-Phase Approach for the Partial Oxidation of Methane to Methanol using SO3 as the Oxidant

    E-Print Network [OSTI]

    Bell, Alexis T.

    A High-Yield, Liquid-Phase Approach for the Partial Oxidation of Methane to Methanol using SO3 approach for producing methanol from methane in a three-step, liquid phase process is reported is hydrolyzed in the presence of an organic solvent, to produce an organic phase con- taining methanol

  18. COMMERCIAL-SCALE DEMONSTRATION OF THE LIQUID PHASE METHANOL (LPMEOH) PROCESS

    SciTech Connect (OSTI)

    E.C. Heydorn; B.W. Diamond; R.D. Lilly

    2003-06-01T23:59:59.000Z

    This project, which was sponsored by the U.S. Department of Energy (DOE) under the Clean Coal Technology Program to demonstrate the production of methanol from coal-derived synthesis gas (syngas), has completed the 69-month operating phase of the program. The purpose of this Final Report for the ''Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process'' is to provide the public with details on the performance and economics of the technology. The LPMEOH{trademark} Demonstration Project was a $213.7 million cooperative agreement between the DOE and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The DOE's cost share was $92,708,370 with the remaining funds coming from the Partnership. The LPMEOH{trademark} demonstration unit is located at the Eastman Chemical Company (Eastman) chemicals-from-coal complex in Kingsport, Tennessee. The technology was the product of a cooperative development effort by Air Products and Chemicals, Inc. (Air Products) and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} Process is ideally suited for directly processing gases produced by modern coal gasifiers. Originally tested at the Alternative Fuels Development Unit (AFDU), a small, DOE-owned process development facility in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst, and allowing the methanol synthesis reaction to proceed at higher rates. The LPMEOH{trademark} Demonstration Project accomplished the objectives set out in the Cooperative Agreement with DOE for this Clean Coal Technology project. Overall plant availability (defined as the percentage of time that the LPMEOH{trademark} demonstration unit was able to operate, with the exclusion of scheduled outages) was 97.5%, and the longest operating run without interruption of any kind was 94 days. Over 103.9 million gallons of methanol was produced; Eastman accepted all of the available methanol for use in the production of methyl acetate, and ultimately cellulose acetate and acetic acid.

  19. Preferential oxidation of methanol and carbon monoxide for gas cleanup during methanol fuel processing

    SciTech Connect (OSTI)

    Birdsell, S.A.; Vanderborgh, N.E.; Inbody, M.A. [Los Alamos National Lab., NM (United States)

    1993-07-01T23:59:59.000Z

    Methanol fuel processing generates hydrogen for low-temperature, PEM fuel cell systems now being considered for transportation and other applications. Although liquid methanol fuel is convenient for this application, existing fuel processing techniques generate contaminants that degrade fuel cell performance. Through mathematical models and laboratory experiments chemical processing is described that removes CO and other contaminants from the anode feed stream.

  20. Mixing it up - Measuring diffusion in supercooled liquid solutions of methanol and ethanol at temperatures near the glass transition

    SciTech Connect (OSTI)

    Matthiesen, Jesper; Smith, R. Scott; Kay, Bruce D.

    2011-03-17T23:59:59.000Z

    Do liquid mixtures, cooled to temperatures below their freezing point, behave as normal liquids? We address this question using nanoscale films of methanol and ethanol supercooled liquid solutions of varying composition (7 -93% methanol) at temperatures near their glass transition,Tg. The permeation of Kr through these films is used to determine the diffusivities of the supercooled liquid mixtures. We find that the temperature dependent diffusivities of the mixtures are well-fit by a Vogel-Fulcher-Tamman equation indicating that the mixtures exhibit fragile behavior at temperatures just above their Tg. Further, for a given temperature, the composition dependent diffusivity is well-fit by a Vignes-type equation, i.e. the diffusivity of any mixture can be predicted using an exponential weighting of the diffusion of the pure methanol and ethanol diffusivities. These results show that deeply supercooled liquid mixtures can be used to provide valuable insight into the properties of normal liquid mixtures.

  1. Fundamental Studies of Methanol Synthesis from CO2 Hydrogenation on Cu(111), Cu Clusters, and Cu/ZnO(000?)

    SciTech Connect (OSTI)

    Liu, P.; Yang, Y.; Evans, J.; Rodriguez, J.A.; White, M.G.

    2010-06-21T23:59:59.000Z

    A combination of experimental and theoretical methods were employed to investigate the synthesis of methanolvia CO{sub 2}hydrogenation (CO{sub 2} + 3H{sub 2} {yields} CH{sub 3}OH + H{sub 2}O) on Cu(111) and Cunanoparticle surfaces. High pressure reactivity studies show that Cunanoparticles supported on a ZnO(000{bar 1}) single crystal exhibit a higher catalytic activity than the Cu(111) planar surface. Complementary density functional theory (DFT) calculations of methanol synthesis were also performed for a Cu(111) surface and unsupported Cu{sub 29} nanoparticles, and the results support a higher activity for Cu nanoparticles. The DFT calculations show that methanol synthesis on Cu surfaces proceeds through a formate intermediate and the overall reaction rate is limited by both formate and dioxomethylene hydrogenation. Moreover, the superior activity of the nanoparticle is associated with its fluxionality and the presence of low-coordinated Cu sites, which stabilize the key intermediates, e.g. formate and dioxomethylene, and lower the barrier for the rate-limiting hydrogenation process. The reverse water-gas-shift (RWGS) reaction (CO{sub 2} + H{sub 2} {yields} CO + H{sub 2}O) was experimentally observed to compete with methanol synthesis and was also considered in our DFT calculations. In agreement with experiment, the rate of the RWGS reaction on Cu nanoparticles is estimated to be 2 orders of magnitude faster than methanol synthesis at T = 573 K. The experiments and calculations also indicate that CO produced by the fast RWGS reaction does not undergo subsequent hydrogenation to methanol, but instead simply accumulates as a product. Methanol production from CO hydrogenation via the RWGS pathway is hindered by the first hydrogenation of CO to formyl, which is not stable and prefers to dissociate into CO and H atoms on Cu. Our calculated results suggest that the methanol yield over Cu-based catalysts could be improved by adding dopants or promoters which are able to stabilize formyl species or facilitate the hydrogenation of formate and dioxomethylene. the RWGS pathway is hindered by the first hydrogenation of CO to formyl, which is not stable and prefers to dissociate into CO and H atoms on Cu. Our calculated results suggest that the methanol yield over Cu-based catalysts could be improved by adding dopants or promoters which are able to stabilize formyl species or facilitate the hydrogenation of formate and dioxomethylene.

  2. Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol

    SciTech Connect (OSTI)

    Paul A. Erickson

    2005-09-30T23:59:59.000Z

    Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the eighth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2004-September 30, 2005 and includes an entire review of the progress for year 2 of the project. This year saw progress in eight areas. These areas are: (1) steam reformer transient response, (2) steam reformer catalyst degradation, (3) steam reformer degradation tests using bluff bodies, (4) optimization of bluff bodies for steam reformation, (5) heat transfer enhancement, (6) autothermal reforming of coal derived methanol, (7) autothermal catalyst degradation, and (8) autothermal reformation with bluff bodies. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

  3. Commercial-Scale Demonstration of the Liquid Phase methanol (LPMEOH) Process A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2003-10-27T23:59:59.000Z

    The U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Program seeks to offer the energy marketplace more efficient and environmentally benign coal utilization technology options by demonstrating them in industrial settings. This document is a DOE post-project assessment (PPA) of one of the projects selected in Round III of the CCT Program, the commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process, initially described in a Report to Congress by DOE in 1992. Methanol is an important, large-volume chemical with many uses. The desire to demonstrate a new process for the production of methanol from coal, prompted Air Products and Chemicals, Inc. (Air Products) to submit a proposal to DOE. In October 1992, DOE awarded a cooperative agreement to Air Products to conduct this project. In March 1995, this cooperative agreement was transferred to Air Products Liquid Phase Conversion Company, L.P. (the Partnership), a partnership between Air Products and Eastman Chemical Company (Eastman). DOE provided 43 percent of the total project funding of $213.7 million. Operation of the LPMEOH Demonstration Unit, which is sited at Eastman's chemicals-from-coal complex in Kingsport, Tennessee, commenced in April 1997. Although operation of the CCT project was completed in December 2002, Eastman continues to operate the LPMEOH Demonstration Unit for the production of methanol. The independent evaluation contained herein is based primarily on information from Volume 2 of the project's Final Report (Air Products Liquid Phase Conversion Co., L.P. 2003), as well as other references cited.

  4. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOTH) Process

    SciTech Connect (OSTI)

    None

    1998-12-21T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOW) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership) to produce methanol from coal-derived synthesis gas (syngas). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOI-P Process Demonstration Unit was built at a site located at the Eastman coal-to-chemicals complex in Kingsport. During this quarter, initial planning and procurement work continued on the seven project sites which have been accepted for participation in the off-site, product-use test program. Approximately 12,000 gallons of fuel-grade methanol (98+ wt% methanol, 4 wt% water) produced during operation on carbon monoxide (CO)-rich syngas at the LPMEOW Demonstration Unit was loaded into trailers and shipped off-site for Mure product-use testing. At one of the projects, three buses have been tested on chemical-grade methanol and on fhel-grade methanol from the LPMEOW Demonstration Project. During the reporting period, planning for a proof-of-concept test run of the Liquid Phase Dimethyl Ether (LPDME~ Process at the Alternative Fuels Development Unit (AFDU) in LaPorte, TX continued. The commercial catalyst manufacturer (Calsicat) has prepared the first batch of dehydration catalyst in large-scale equipment. Air Products will test a sample of this material in the laboratory autoclave. Catalyst activity, as defined by the ratio of the rate constant at any point in time to the rate constant for freshly reduced catalyst (as determined in the laborato~ autoclave), was monitored for the initial extended operation at the lower initial reactor operating temperature of 235oC. At this condition, the decrease in catalyst activity with time from the period 20 December 1997 through 27 January 1998 occurred at a rate of 1.0% per day, which represented a significant improvement over the 3.4Yi per day decline measured during the initial six weeks of operation in April and May of 1997. The deactivation rate also improved from the longer-term rate of 1.6% per day calculated throughout the summer and autumn of 1997.

  5. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2006-03-30T23:59:59.000Z

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe-M (M=Ni, Mo, Pd) catalysts exhibit excellent activity for dehydrogenation of gaseous alkanes, yielding pure hydrogen and carbon nanotubes in one reaction. A fluidized-bed/fixed-bed methane reactor was developed for continuous hydrogen and nanotube production. (6) A process for co-production of hydrogen and methyl formate from methanol has been developed. (7) Pt nanoparticles on stacked-cone carbon nanotubes easily strip hydrogen from liquids such as cyclohexane, methylcyclohexane, tetralin and decalin, leaving rechargeable aromatic phases. (8) Hydrogen volume percentages produced during reforming of methanol in supercritical water in the output stream are {approx}98%, while CO and CO2 percentages are <2 %.

  6. Vapor-liquid equilibria for the systems difluoromethane + hydrogen fluoride, dichlorodifluoromethane + hydrogen fluoride, and chlorine + hydrogen fluoride

    SciTech Connect (OSTI)

    Kang, Y.W. [KIST, Seoul (Korea, Republic of). Div. of Environmental and CFC Technology] [KIST, Seoul (Korea, Republic of). Div. of Environmental and CFC Technology

    1998-01-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria for difluoromethane + hydrogen fluoride, dichlorodifluoromethane + hydrogen fluoride, and chlorine + hydrogen fluoride have been measured. The experimental data for the binary systems are correlated with the NRTL equation with the vapor-phase association model for the mixtures containing hydrogen fluoride, and the relevant parameters are presented. The binary system difluoromethane + hydrogen fluoride forms a homogeneous liquid phase, and the others form minimum boiling heterogeneous azeotropes at the experimental conditions.

  7. Bio-Derived Liquids to Hydrogen Distributed Reforming Targets

    Broader source: Energy.gov [DOE]

    Presentation by Arlene Anderson at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  8. Liquid Hydrogen Production and Delivery from a Dedicated Wind...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Dedicated Wind Power Plant Liquid Hydrogen Production and Delivery from a Dedicated Wind Power Plant This May 2012 study assesses the costs and potential for remote renewable...

  9. Commercial-Scale Demonstration of the Liquid Phase Methanol (LOMEOH(TM)) Process

    SciTech Connect (OSTI)

    None

    1996-03-31T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOEP") Demonstration Project at K.ingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L, P. (the Partnership). The LPMEOHY Process Demonstration Unit is being built at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. On 4 October 1994, Air Products and Chemicals, Inc. (Air Products) and signed the agreements that would form the Partnership, secure the demonstration site, and provide the financial commitment and overall project management for the project. These partnership agreements became effective on 15 March 1995, when DOE authorized the commencement of Budget Period No. 2 (Mod. AO08 to the Cooperative Agreement). The Partnership has subcontracted with Air Products to provide the overall management of the project, and to act as the primary interface with DOE. As subcontractor to the Partnership, Air Products will also provide the engineering design, procurement, construction, and commissioning of the LPMEOHTM Process Demonstration Unit, and will provide the technical and engineering supervision needed to conduct the operational testing program required as part of the project. As subcontractor to Air Products, Eastman will be responsible for operation of the LPMEOHTM Process Demonstration Unit, and for the interconnection and supply of synthesis gas, utilities, product storage, and other needed sewices. The project involves the construction of an 80,000 gallons per day (260 tons-per-day (TPD)) methanol unit utilizing coal-derived synthesis gas fi-om Eastman's integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOHTM process is ideally suited for directly processing gases produced by modern day coal gasifiers. Originally tested at a small 3,200 gallons per day, DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates.

  10. Theoretical characterization of the hydrogen-bond interaction of diacetamide with water and methanol

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    and methanol Minh Tho Nguyen, Natalie Leroux and The re` se Zeegers-Huyskens* Department of Chemistry formed from interaction of diacetamide with water and methanol. In both water and methanol complexes/6-31G** level being [44 kJ mol~1 for the water complex and [48 kJ mol~1 for the methanol complex

  11. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH(TM)) Process

    SciTech Connect (OSTI)

    None

    1996-12-31T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOH(TM)) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The LPMEOIWM Process Demonstration Unit is being built at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. During this quarter, the Cooperative Agreement was modified (Mod AO11) on 8 October 1996, authorizing the transition born Budget Period No. 2 (Design and Construction) to the . final Budget Period (Commissioning, Start-up, and Operation), A draft Topical Report on Process Economics Studies concludes that methanol coproduction with integrated gasification combined cycle (IGCC) electric power utilizing the LPMEOW process technology, will be competitive in serving local market needs. Planning for a proof-of- concept test run of the liquid phase dimethyl ether (DME) process at the LaPorte Alternative Fuels Development Unit (AFDU) was recommended; and a deeision to proceed is pending. Construction (Task 2.2) is 97'Mo complete, asof31 December 1996. Completion of pipe pressure testing has taken longer than expected. This will delay completion of construction by about three weeks. Commissioning activities (Task 2.3) commenced in mid-October of 1996, and the demonstration unit is scheduled to be mechanically complete on 24 January 1997.

  12. Salt effect on the isobaric vapor-liquid equilibrium of the methyl acetate + methanol system

    SciTech Connect (OSTI)

    Iliuta, M.C.; Thyrion, F.C. [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.] [Louvain Univ., Louvain-la-Neuve (Belgium). Chemical Engineering Inst.; Landauer, O.M. [Univ. Politehnica Bucharest (Romania)] [Univ. Politehnica Bucharest (Romania)

    1996-07-01T23:59:59.000Z

    The effect of sodium thiocyanate at constant salt mole fraction from 0.01 to 0.05 and at saturation on the vapor-liquid equilibrium (VLE) of methyl acetate + methanol has been studied at 101.32 kPa using a modified Othmer equilibrium still. The salt exhibited both salting-in and salting-out effects on the methyl acetate, the azeotrope being eliminated at saturation. The results were correlated using the extended UNIQUAC model of Sander et al. and the electrolytic NRTL model of Mock et al.

  13. Electron-stimulated reactions in layered CO/H2O films: Hydrogen atom diffusion and the sequential hydrogenation of CO to methanol

    SciTech Connect (OSTI)

    Petrik, Nikolay G.; Monckton, Rhiannon J.; Koehler, Sven; Kimmel, Gregory A.

    2014-05-28T23:59:59.000Z

    Low-energy (100 eV) electron-stimulated reactions in layered H2O/CO/H2O ices are investigated. For CO trapped within approximately 50 ML of the vacuum interface in the amorphous solid water (ASW) films, both oxidation and reduction reactions are observed. However for CO buried more deeply in the film, only the reduction of CO to methanol is observed. Experiments with layered films of H2O and D2O show that the hydrogen atoms participating in the reduction of the buried CO originate in region from ~10 – 40 ML below the surface of the ASW films and subsequently diffuse through the film. For deeply buried CO layers, the CO reduction reactions quickly increase with temperature above ~60 K. We present a simple chemical kinetic model that treats the diffusion of hydrogen atoms in the ASW and sequential hydrogenation of the CO to methanol that accounts for the observations.

  14. Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product

    DOE Patents [OSTI]

    Davis, Benjamin L; Rekken, Brian D

    2014-04-01T23:59:59.000Z

    Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

  15. Communication: Towards the binding energy and vibrational red shift of the simplest organic hydrogen bond: Harmonic constraints for methanol dimer

    SciTech Connect (OSTI)

    Heger, Matthias; Suhm, Martin A.; Mata, Ricardo A., E-mail: rmata@gwdg.de [Georg-August-Universität Göttingen, Institut für Physikalische Chemie, Tammannstr. 6, 37077 Göttingen (Germany)

    2014-09-14T23:59:59.000Z

    The discrepancy between experimental and harmonically predicted shifts of the OH stretching fundamental of methanol upon hydrogen bonding to a second methanol unit is too large to be blamed mostly on diagonal and off-diagonal anharmonicity corrections. It is shown that a decisive contribution comes from post-MP2 electron correlation effects, which appear not to be captured by any of the popular density functionals. We also identify that the major deficiency is in the description of the donor OH bond. Together with estimates for the electronic and harmonically zero-point corrected dimer binding energies, this work provides essential constraints for a quantitative description of this simple hydrogen bond. The spectroscopic dissociation energy is predicted to be larger than 18 kJ/mol and the harmonic OH-stretching fundamental shifts by about ?121 cm{sup ?1} upon dimerization, somewhat more than in the anharmonic experiment (?111 cm{sup ?1})

  16. Uptake and Surface Reaction of Methanol by Sulfuric Acid Solutions Investigated by Vibrational Sum Frequency Generation and Raman Spectroscopies

    E-Print Network [OSTI]

    Uptake and Surface Reaction of Methanol by Sulfuric Acid Solutions Investigated by Vibrational SumVised Manuscript ReceiVed: June 4, 2008 The uptake of methanol at the air-liquid interface of 0-96.5 wt % sulfuric methanol and H2SO4 to form methyl hydrogen sulfate. The surface is saturated with the methyl species after

  17. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH(TM)) Process

    SciTech Connect (OSTI)

    None

    1997-09-30T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOH) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). Ak Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOITM Process Demonstration Unit was built at a site located at the Eastman complex in Kingsport. During this reporting period, DOE accepted the recommendation to continue with dimethyl ether (DME) design verification testing (DVT). DME design verification testing studies show the liquid phase DME (LPDME) process will have a significant economic advantage for the coproduction of DME for local markets. An LPDME catalyst system with reasonable long-term activity and stzibility is being developed. Planning for a proof-of-concept test run at the LaPorte Alternative Fuels Development Unit (AFDU) was recommended. DOE issued a letter dated 31 July 1997 accepting the recommendation to continue design verification testing. In order to allow for scale-up of the manufacturing technique for the dehydration catalyst from the pilot plant to the commercial scale, the time required to produce the catalyst to the AFDU has slipped. The new estimated delivery date is 01 June 1998.

  18. Insight into methanol synthesis from CO2 hydrogenation on Cu(111): Complex reaction network and the effects of H2O

    SciTech Connect (OSTI)

    Zhao, Yafan; Yang, Yong; Mims, Charles A.; Peden, Charles HF; Li, Jun; Mei, Donghai

    2011-05-31T23:59:59.000Z

    Methanol synthesis from CO2 hydrogenation on supported Cu catalysts is of considerable importance in the chemical and energy industries. Although extensive experimental and theoretical efforts have been carried out in the past decades, the most fundamental questions such as the reaction mechanisms and the key reaction intermediates are still in debate. In the present work, a comprehensive reaction network for CO2 hydrogenation to methanol on Cu(111) was studied using periodic density functional theory (DFT) calculations. All of the elementary reaction steps in the reaction network were identified in an unbiased way with the dimer method. Our calculation results show that methanol synthesis from direct hydrogenation of formate on Cu(111) is not feasible due to the high activation barriers for some of the elementary steps. Instead, we find that CO2 hydrogenation to hydrocarboxyl (trans-COOH) is kinetically more favorable than formate in the presence of H2O via a unique proton transfer mechanism. The trans-COOH is then converted into hydroxymethylidyne (COH) via dihydroxycarbene (COHOH) intermediates, followed by three consecutive hydrogenation steps to form hydroxymethylene (HCOH), hydroxymethyl (H2COH), and methanol. This is consistent with recent experimental observations [1], which indicate that direct hydrogenation of formate will not produce methanol under dry hydrogen conditions. Thus, both experiment and computational modeling clearly demonstrate the important role of trace amounts of water in methanol synthesis from CO2 hydrogenation on Cu catalysts. The proposed methanol synthesis route on Cu(111) not only provides new insights into methanol synthesis chemistry, but also demonstrates again that spectroscopically observed surface species are often not critical reaction intermediates but rather spectator species. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  19. Spectroscopic investigations of hydrogen bond dynamics in liquid water

    E-Print Network [OSTI]

    Fecko, Christopher J., 1975-

    2004-01-01T23:59:59.000Z

    Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

  20. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH(TM)) Process

    SciTech Connect (OSTI)

    None

    1997-06-30T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOHTM) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOIYM Process Demonstration Unit was built at a site located at the Eastman complex in Kingsport. During this quarter, comments from the DOE on the Topical Report "Economic Analysis - LPMEOHTM Process as an Add-on to IGCC for Coproduction" were received. A recommendation to continue with design verification testing for the coproduction of dimethyl ether (DIME) and methanol was made. DME design verification testing studies show the liquid phase DME (LPDME) process will have a significant economic advantage for the coproduction of DME for local markets. An LPDME catalyst system with reasonable long-term activity and stability is being developed. A recommendation document summarizing catalyst targets, experimental results, and the corresponding economics for a commercially successful LPDME catalyst was issued on 30 June 1997. The off-site, product-use test plan was updated in June of 1997. During this quarter, Acurex Environmental Corporation and Air Products screened proposals for this task by the likelihood of the projects to proceed and the timing for the initial methanol requirement. Eight sites from the list have met these criteria. The formal submission of the eight projects for review and concurrence by the DOE will be made during the next reporting period. The site paving and final painting were completed in May of 1997. Start-up activities were completed during the reporting period, and the initial methanol production from the demonstration unit occurred on 02 April 1997. The first extended stable operation at the nameplate capacity of 80,000 gallons per day (260 tons per day) took place on 06 April 1997. Pressure drop and resistance coefficient across the gas sparger at the bottom of the reactor increased over this initial operating period. The demonstration unit was shut down from 08 May -17 June 1997 as part of a scheduled complex outage for the Kingsport site. During this outage, the gas sparger was removed, cleaned, and reinstalled. After completion of other maintenance activities, the demonstration unit was restarted, and maintained stable operation through the remainder of the reporting period. Again, the gas sparger showed an increase in pressure drop and resistance since the restart, although not as rapidly as during the April-May operation. Fresh oil was introduced online for the first time to a new flush connection on the gas inlet line to the reactov the flush lowered the pressure drop by 1 psi. However, the effects were temporary, and the sparger resistance coefficient continued to increase. Additional flushing with both fresh oil and entrained slurry recovered in the cyclone and secondary oil knock-out drum will be attempted in order to stabilize the sparger resistance coefficient.

  1. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-03-31T23:59:59.000Z

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research.

  2. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2004-09-30T23:59:59.000Z

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

  3. Theoretical study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001) surface

    SciTech Connect (OSTI)

    Zhao, Ya-Fan; Rousseau, Roger J.; Li, Jun; Mei, Donghai

    2012-08-02T23:59:59.000Z

    Methanol synthesis from syngas (CO/CO2/H2) hydrogenation on the perfect Zn–terminated polar ZnO(0001) surface have been investigated using periodic density functional theory calculations. Our results show that direct CO2 hydrogenation to methanol on the perfect ZnO(0001) surface is unlikely because in the presence of surface atomic H and O the highly stable formate (HCOO) and carbonate (CO3) readily produced from CO2 with low barriers 0.11 and 0.09 eV will eventually accumulate and block the active sites of the ZnO(0001) surface. In contrast, methanol synthesis from CO hydrogenation is thermodynamically and kinetically feasible on the perfect ZnO(0001) surface. CO can be consecutively hydrogenated into formyl (HCO), formaldehyde (H2CO), methoxy (H3CO) intermediates, leading to the final formation of methanol (H3COH). The reaction route via hydroxymethyl (H2COH) intermediate, a previously proposed species on the defected O–terminated ZnO( ) surface, is kinetically inhibited on the perfect ZnO(0001) surface. The rate-determining step in the consecutive CO hydrogenation route is the hydrogenation of H3CO to H3COH. We also note that this last hydrogenation step is pronouncedly facilitated in the presence of water by lowering the activation barrier from 1.02 to 0.55 eV. This work was supported by the U.S. Department of Energy Office of Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences, and performed at EMSL, a national scientific user facility sponsored by the Department of Energy’s Office of Biological and Environmental Research located at Pacific Northwest National Laboratory (PNNL). Computational resources were provided at EMSL and the National Energy Research Scientific Computing Center at Lawrence Berkeley National Laboratory. J. Li and Y.-F. Zhao were also financially supported by the National Natural Science Foundation of China (Nos. 20933003 and 91026003) and the National Basic Research Program of China (No. 2011CB932400). Y.-F. Zhao acknowledges the fellowship from PNNL.

  4. Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles

    SciTech Connect (OSTI)

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1992-08-01T23:59:59.000Z

    The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

  5. Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles

    SciTech Connect (OSTI)

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1992-08-01T23:59:59.000Z

    The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

  6. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group & Hydrogen Production Technical Team Research Review

    E-Print Network [OSTI]

    -Oil Reforming, NREL, Darlene Steward o High Pressure Steam Ethanol Reforming, ANL, Romesh Kumar 12:00 - 12:30 Lunch 12:30 Research Review Continued o Investigation of Bio-ethanol Steam Reforming over Cobalt basedBio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) & Hydrogen Production

  7. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2005-03-31T23:59:59.000Z

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  8. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2004-03-31T23:59:59.000Z

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  9. Catalytic decomposition of methanol at various temperatures and several liquid hourly space velocities

    E-Print Network [OSTI]

    Gupta, Yashpal Satyapal

    1975-01-01T23:59:59.000Z

    to quantitatively analyze the products of the reactions. Based on the results obtained, a scheme is presented by which methanol can be converted to a gaseous fuel consisting of dimethyl ether (50K), carbon monoxide ( 16 . 67K) and hyrdogen (33 . 33K) . Dedicated... is produced by catalytically dehydrating methanol over a y-alumina catalyst to produce dimethyl ether and dehydrogenating methanol to CO and H& over a methanol synthesis catalyst and then mixing these gases in the proportion of 50% dimethyl ether, 33. 33K...

  10. Commercial-scale demonstration of the Liquid Phase Methanol process. Technical progress report number 8, April 1--June 30, 1996

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    The project involves the construction of an 80,000 gallon per day (260 tons per day (TPD)) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coal gasifiers. Originally tested at a small (10 TPD), DOE-owned experimental unit in LaPorte, Texas, the technology provides several improvements essential for the economic coproduction of methanol and electricity directly from gasified coal. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology is being integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading.

  11. Electron-stimulated reactions in layered CO/H{sub 2}O films: Hydrogen atom diffusion and the sequential hydrogenation of CO to methanol

    SciTech Connect (OSTI)

    Petrik, Nikolay G.; Kimmel, Greg A., E-mail: gregory.kimmel@pnnl.gov [Physical Sciences Division, Pacific Northwest National Laboratory, MSIN K8-88, P.O. Box 999, Richland, Washington 99352 (United States); Monckton, Rhiannon J.; Koehler, Sven P. K. [School of Chemistry, The University of Manchester, Manchester M13 9PL (United Kingdom); Photon Science Institute, The University of Manchester, Manchester M13 9PL (United Kingdom); UK Dalton Cumbrian Facility, The University of Manchester, Moor Row, Whitehaven CA24 3HA (United Kingdom)

    2014-05-28T23:59:59.000Z

    Low-energy (100 eV) electron-stimulated reactions in layered H{sub 2}O/CO/H{sub 2}O ices are investigated. For CO layers buried in amorphous solid water (ASW) films at depths of 50 monolayers (ML) or less from the vacuum interface, both oxidation and reduction reactions are observed. However, for CO buried more deeply in ASW films, only the reduction of CO to methanol is observed. Experiments with layered films of H{sub 2}O and D{sub 2}O show that the hydrogen atoms participating in the reduction of the buried CO originate in the region that is 10–50 ML below the surface of the ASW films and subsequently diffuse through the film. For deeply buried CO layers, the CO reduction reactions quickly increase with temperature above ?60 K. We present a simple chemical kinetic model that treats the diffusion of hydrogen atoms in the ASW and sequential hydrogenation of the CO to methanol to account for the observations.

  12. Rapid starting methanol reactor system

    DOE Patents [OSTI]

    Chludzinski, Paul J. (38 Berkshire St., Swampscott, MA 01907); Dantowitz, Philip (39 Nancy Ave., Peabody, MA 01960); McElroy, James F. (12 Old Cart Rd., Hamilton, MA 01936)

    1984-01-01T23:59:59.000Z

    The invention relates to a methanol-to-hydrogen cracking reactor for use with a fuel cell vehicular power plant. The system is particularly designed for rapid start-up of the catalytic methanol cracking reactor after an extended shut-down period, i.e., after the vehicular fuel cell power plant has been inoperative overnight. Rapid system start-up is accomplished by a combination of direct and indirect heating of the cracking catalyst. Initially, liquid methanol is burned with a stoichiometric or slightly lean air mixture in the combustion chamber of the reactor assembly. The hot combustion gas travels down a flue gas chamber in heat exchange relationship with the catalytic cracking chamber transferring heat across the catalyst chamber wall to heat the catalyst indirectly. The combustion gas is then diverted back through the catalyst bed to heat the catalyst pellets directly. When the cracking reactor temperature reaches operating temperature, methanol combustion is stopped and a hot gas valve is switched to route the flue gas overboard, with methanol being fed directly to the catalytic cracking reactor. Thereafter, the burner operates on excess hydrogen from the fuel cells.

  13. Vapor-liquid equilibrium data at 298. 15 K for binary systems containing methyl acetate or methanol with 2-methoxyethanol or 2-ethoxyethanol

    SciTech Connect (OSTI)

    Martin, M.C.; Cocero, M.J.; Mato, F.B. (Univ. de Valladolid (Spain))

    1994-07-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured at 298.15 K for the systems containing methyl acetate or methanol with 2-methoxyethanol or 2-ethoxyethanol. Mixtures containing methanol show a behavior close to ideal, while those containing methyl acetate exhibit positive deviations from ideality and satisfy the Redlich-Kister thermodynamic consistency test. The liquid-phase activity coefficients were fitted by using the van Laar, Wilson, NRTL, and NRTL-m (a modified NRTL equation) equations.

  14. Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH) Process

    SciTech Connect (OSTI)

    None

    1998-12-21T23:59:59.000Z

    he Liquid Phase Methanol (LPMEOW) Demonstration Project at Kingsport Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership) to produce methanol from coal-derived synthesis gas (syngas). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOEP Process Demonstration Unit was built at a site located at the Eastman coal-to-chemicals complex in Kingsport. The LPMEOHW Demonstration Facility completed its first year of operation on 02 April 1998. The LPMEOW Demonstration Facility also completed the longest continuous operating run (65 days) on 21 April 1998. Catalyst activity, as defined by the ratio of the rate constant at any point in time to the rate constant for freshly reduced catalyst (as determined in the laboratory autoclave), was monitored throughout the reporting period. During a six-week test at a reactor temperature of 225oC and Balanced Gas flowrate of 700 KSCFH, the rate of decline in catalyst activity was steady at 0.29-0.36% per day. During a second one-month test at a reactor temperature of 220oC and a Balanced Gas flowrate of 550-600 KSCFH, the rate of decline in catalyst activity was 0.4% per day, which matched the pefiorrnance at 225"C, as well as the 4-month proof-of-concept run at the LaPorte AFDU in 1988/89. Beginning on 08 May 1998, the LPMEOW Reactor temperature was increased to 235oC, which was the operating temperature tier the December 1997 restart with the fresh charge of catalyst (50'Yo of design loading). The flowrate of the primary syngas feed stream (Balanced Gas) was also increased to 700-750 KSCFH. During two stable operating periods between 08 May and 09 June 1998, the average catalyst deactivation rate was 0.8% per day. Due to the scatter of the statistical analysis of the results, this test was extended to better quanti& the catalyst aging behavior. During the reporting perio~ two batches of fresh catalyst were activated and transferred to the reactor (on 02 April and 20 June 1998). The weight of catalyst in the LPMEOW Reactor has reached 80% of the design value. At the end of the reporting period, a step-change in the pressure-drop profile within the LPMEOW Reactor and an increase in the pressure of the steam system which provides cooling to the LPMEOW Reactor were observed. No change in the calculated activity of the catalyst was detected during either of these transients. These parameters will be monitored closely for any additional changes.

  15. Liquid Phase Methanol LaPorte Process Development Unit: Modification, operation, and support studies

    SciTech Connect (OSTI)

    Not Available

    1990-08-31T23:59:59.000Z

    A gas phase and a slurry phase radioactive tracer study was performed on the 12 ton/day Liquid Phase Methanol (LPMEOH) Process Development Unit (PDU) in LaPorte, Texas. To study the gas phase mixing characteristics, a radioactive argon tracer was injected into the feed gas and residence time distribution was generated by measuring the response at the reactor outlet. Radioactive manganese oxide powder was independently injected into the reactor to measure the slurry phase mixing characteristics. A tanks-in-series model and an axial dispersion model were applied to the data to characterize the mixing in the reactor. From the axial dispersion model, a translation to the number of CSTR's (continuous stirred tank reactors) was made for comparison purposes with the first analysis. Dispersion correlations currently available in the literature were also compared. The tanks-in-series analysis is a simpler model whose results are easily interpreted. However, it does have a few drawbacks; among them, the lack of a reliable method for scaleup of a reactor and no direct correlation between mixing in the slurry and gas phases. The dispersion model allows the mixing in the gas and slurry phases to be characterized separately while including the effects of phase transfer. This analysis offers a means for combining the gas and slurry phase dispersion models into an effective dispersion coefficient, which, in turn, can be related to an equivalent number of tanks-in-series. The dispersion methods reported are recommended for scaleup of a reactor system. 24 refs., 18 figs., 8 tabs.

  16. Electrokinetic Hydrogen Generation from Liquid WaterMicrojets

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Saykally, Richard J.

    2007-05-31T23:59:59.000Z

    We describe a method for generating molecular hydrogen directly from the charge separation effected via rapid flow of liquid water through a metal orifice, wherein the input energy is the hydrostatic pressure times the volume flow rate. Both electrokinetic currents and hydrogen production rates are shown to follow simple equations derived from the overlap of the fluid velocity gradient and the anisotropic charge distribution resulting from selective adsorption of hydroxide ions to the nozzle surface. Pressure-driven fluid flow shears away the charge balancing hydronium ions from the diffuse double layer and carries them out of the aperture. Downstream neutralization of the excess protons at a grounded target electrode produces gaseous hydrogen molecules. The hydrogen production efficiency is currently very low (ca. 10-6) for a single cylindrical jet, but can be improved with design changes.

  17. Experimental investigation of onboard storage and refueling systems for liquid-hydrogen-fueled vehicles

    SciTech Connect (OSTI)

    Stewart, W.F.

    1982-09-01T23:59:59.000Z

    A 2-1/2-year baseline experimental hydrogen-fueled automotive vehicle project was conducted to evaluate and document state-of-the-art capabilities in engine conversion for hydrogen operation, liquid-hydrogen onboard storage, and liquid-hydrogen refueling. The engine conversion, onboard liquid-hydrogen storage tank, and liquid-hydrogen refueling system used in the project represented readily available equipment or technology when the project began. The project information documented herein can serve as a basis of comparison with which to evaluate future vehicles that are powered by hydrogen or other alternative fuels, with different engines, and different fuel-storage methods. The results of the project indicate that liquid-hydrogen storage observed an operating vehicle and routine refueling of the vehicle can be accomplished over an extended period without any major difficulty. Two different liquid-hydrogen vehicle onboard storage tanks designed for vehicular applications were tested in actual road operation: the first was an aluminum dewar with a liquid-hydrogen capacity of 110 l; the second was a Dewar with an aluminum outer vessel, two copper, vapor-cooled thermal-radiation shields, and a stainless-steel inner vessel with a liquid-hydrogen capacity of 155 l. The car was refueled with liquid hydrogen at least 65 times involving more than 8.1 kl of liquid hydrogen during the 17 months that the car was operated on liquid hydrogen. The vehicle, a 1979 Buick Century sedan with a 3.8-l-displacement turbocharged V6 engine, was driven for 3633 km over the road on hydrogen. The vehicle had a range without refueling of about 274 km with the first liquid-hydrogen tank and about 362 km with the second tank. The vehicle achieved 2.4 km/l of liquid hydrogen which corresponds to 9.4 km/l gasoline on an equivalent energy basis.

  18. Air Liquide Hydrogen Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlinPapersWindeySanta2004) |Agawam,Ahmeek,Wisconsin: EnergyAir Liquide

  19. An Analysis of Methanol and Hydrogen Production via High-Temperature Electrolysis Using the Sodium Cooled Advanced Fast Reactor

    SciTech Connect (OSTI)

    Shannon M. Bragg-Sitton; Richard D. Boardman; Robert S. Cherry; Wesley R. Deason; Michael G. McKellar

    2014-03-01T23:59:59.000Z

    Integration of an advanced, sodium-cooled fast spectrum reactor into nuclear hybrid energy system (NHES) architectures is the focus of the present study. A techno-economic evaluation of several conceptual system designs was performed for the integration of a sodium-cooled Advanced Fast Reactor (AFR) with the electric grid in conjunction with wind-generated electricity. Cases in which excess thermal and electrical energy would be reapportioned within an integrated energy system to a chemical plant are presented. The process applications evaluated include hydrogen production via high temperature steam electrolysis and methanol production via steam methane reforming to produce carbon monoxide and hydrogen which feed a methanol synthesis reactor. Three power cycles were considered for integration with the AFR, including subcritical and supercritical Rankine cycles and a modified supercritical carbon dioxide modified Brayton cycle. The thermal efficiencies of all of the modeled power conversions units were greater than 40%. A thermal efficiency of 42% was adopted in economic studies because two of the cycles either performed at that level or could potentially do so (subcritical Rankine and S-CO2 Brayton). Each of the evaluated hybrid architectures would be technically feasible but would demonstrate a different internal rate of return (IRR) as a function of multiple parameters; all evaluated configurations showed a positive IRR. As expected, integration of an AFR with a chemical plant increases the IRR when “must-take” wind-generated electricity is added to the energy system. Additional dynamic system analyses are recommended to draw detailed conclusions on the feasibility and economic benefits associated with AFR-hybrid energy system operation.

  20. Vapor-liquid equilibria for the system benzene-thiophene-methanol

    SciTech Connect (OSTI)

    Triday, J.O.; Rodriguez, P.

    1985-01-01T23:59:59.000Z

    Isothermal vapor pressure data over the whole range of composition were obtained for the system benzene-thiophene-methanol. Data were taken at temperatures of 35, 40, and 45 /sup 0/C by using a static equilibrium cell. The systems benzene-methanol and thiophene-methanol are highly nonideal, while the system benzene-thiophene shows a very small deviation from ideality. The models suggested by Wilson and by Renon and Prausnitz (NRTL) and the modified equation of Abrams and Prausnitz (UNIQUAC) were used in the reduction of data. Physical parameters of these equations obtained from the binary data were used to predict the ternary system. The Wilson equation gives the best fit for the binary as well as the ternary data. Also, this equation gives the best prediction for the ternary system.

  1. Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor

    DOE Patents [OSTI]

    Mahajan, Devinder

    2005-07-26T23:59:59.000Z

    The invention provides a homogenous catalyst for the production of methanol from purified synthesis gas at low temperature and low pressure which includes a transition metal capable of forming transition metal complexes with coordinating ligands and an alkoxide, the catalyst dissolved in a methanol solvent system, provided the transition metal complex is not transition metal carbonyl. The coordinating ligands can be selected from the group consisting of N-donor ligands, P-donor ligands, O-donor ligands, C-donor ligands, halogens and mixtures thereof.

  2. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-09-30T23:59:59.000Z

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure hydrogen and carbon nanotubes using binary Fe-based catalysts containing Mo, Ni, or Pd in a single step non-oxidative reaction. (7) Partial dehydrogenation of liquid hydrocarbons (cyclohexane and methyl cyclohexane) has been performed using catalysts consisting of Pt and other metals on stacked-cone carbon nanotubes. (8) An understanding of the catalytic reaction mechanisms of the catalysts developed in the CFFS C1 program is being achieved by structural characterization using multiple techniques, including XAFS and Moessbauer spectroscopy, XRD, TEM, NMR, ESR, and magnetometry.

  3. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-03-31T23:59:59.000Z

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the first six months of the subject contract (DE-FC26-02NT-4159), from October 1, 2002 through March 31, 2003.

  4. Hydrogen and helium entrapment in flowing liquid metal plasma-facing surfaces

    E-Print Network [OSTI]

    Harilal, S. S.

    Hydrogen and helium entrapment in flowing liquid metal plasma-facing surfaces Ahmed Hassanein the PFC surface (helium and hydrogen isotopes) while accommodating high heat loads. To study this problem. Hydrogen isotope (DT) particles are likely be trapped in the liquid metal surface (e.g., lithium) due

  5. MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897 905 Dynamics and hydrogen bonding in liquid ethanol

    E-Print Network [OSTI]

    Saiz, Leonor

    MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897± 905 Dynamics and hydrogen bonding in liquid ethanol L of liquid ethanol at three temperatures have been carried out. The hydrogen bonding states of ethanol measurements of the frequency-dependent dielectric permittivity of liquid ethanol. 1. Introduction A detailed

  6. Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications

    Fuel Cell Technologies Publication and Product Library (EERE)

    In 2007-2009, the DOE Hydrogen Program conducted a technical assessment of organic liquid carrier based hydrogen storage systems for automotive applications, consistent with the Program’s Multiyear Re

  7. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report No. 1, October 1, 1993--June 30, 1994

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOH{trademark}) Demonstration Project at Kingsport, Tennessee is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products and Chemicals, Inc. (Air Products). This document describes major accomplishments in project development for Fiscal Year 1993. The preliminary process hazards review, project safety plan, schedule, and cost management report are included as appendices. The demonstration is sited at the Eastman Chemical Company (Eastman) complex in Kingsport. Air Products and Eastman are working on a partnership agreement which will form the Air Products Liquid Phase Conversion Company, L.P. As a limited partner in the venture, Eastman will own and operate the demonstration unit. The project involves the construction of a 260 tons-per-day (TPD) or 80,000 gallon per day methanol demonstration unit utilizing an existing coal-derived synthesis gas from Eastman. The new equipment consists of synthesis gas feed preparation and compression, liquid phase reactor and auxiliaries, product distillation, and utilities. The technology to be demonstrated was developed by Air Products in a DOE sponsored program that started in 1981. Originally tested at a small, DOE-owned experimental facility in LaPorte, Texas, the LPMEOH{trademark} process offers several advantages over current methods of making methanol. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The liquid dissipates heat from the chemical reaction away from the catalyst surface, protecting the catalyst, and allowing the gas-to-methanol reaction to proceed at higher rates. The process is ideally suited to the type of gas produced by modem coal gasifiers. At the Eastman Chemical complex, the technology will be integrated with existing coal gasifiers to demonstrate the commercially important aspects of the operation of the LPMEOH{trademark} Process to produce methanol.

  8. Fuel processor for fuel cell power system. [Conversion of methanol into hydrogen

    DOE Patents [OSTI]

    Vanderborgh, N.E.; Springer, T.E.; Huff, J.R.

    1986-01-28T23:59:59.000Z

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  9. Methanol Synthesis from CO2 Hydrogenation over a Pd4/In2O3 Model Catalyst: A Combined DFT and Kinetic Study

    SciTech Connect (OSTI)

    Ye, Jingyun; Liu, Changjun; Mei, Donghai; Ge, Qingfeng

    2014-08-01T23:59:59.000Z

    Methanol synthesis from CO2 hydrogenation on Pd4/In2O3 has been investigated using density functional theory (DFT) and microkinetic modeling. In this study, three possible routes in the reaction network of CO2 + H2 ? CH3OH + H2O have been examined. Our DFT results show that the HCOO route competes with the RWGS route whereas a high activation barrier kinetically blocks the HCOOH route. DFT results also suggest that H2COO* + H* ? H2CO* +OH* and cis-COOH* + H* ?CO* + H2O* are the rate limiting steps in the HCOO route and the RWGS route, respectively. Microkinetic modeling results demonstrate that the HCOO route is the dominant reaction route for methanol synthesis from CO2 hydrogenation. We found that the activation of H adatom on the small Pd cluster and the presence of H2O on the In2O3 substrate play important roles in promoting the methanol synthesis. The hydroxyl adsorbed at the interface of Pd4/In2O3 induces the transformation of the supported Pd4 cluster from a butterfly structure into a tetrahedron structure. This important structure change not only indicates the dynamical nature of the supported nanoparticle catalyst structure during the reaction but also shifts the final hydrogenation step from H2COH to CH3O.

  10. Isothermal vapor-liquid equilibria for the systems 1-chloro-1,1-difluoroethane + hydrogen fluoride, 1,1-dichloro-1-fluoroethane + hydrogen fluoride, and chlorodifluoromethane + hydrogen fluoride

    SciTech Connect (OSTI)

    Kang, Y.W.; Lee, Y.Y. [KIST, Seoul (Korea, Republic of)] [KIST, Seoul (Korea, Republic of)

    1997-03-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria for the three binary systems (1-chloro-1,1-difluoroethane + hydrogen fluoride, 1,1-dichloro-1-fluoroethane + hydrogen fluoride, and chlorodifluoromethane + hydrogen fluoride) have been measured. The experimental data for the binary systems are correlated with the NRTL equation with the vapor-phase association model for the mixtures containing hydrogen fluoride, and the relevant parameters are presented. All of the systems form minimum boiling heterogeneous azeotropes.

  11. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 9, July 1--September 30, 1996

    SciTech Connect (OSTI)

    NONE

    1997-06-06T23:59:59.000Z

    The Liquid Phase Methanol (LPMEOH{trademark}) Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative agreement between the US Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). The LPMEOH{trademark} Process Demonstration Unit is being built at a site located at the Eastman Chemical Company (Eastman) complex in Kingsport. The project involves the construction of an 80,000 gallons per day (260 tons per day (TPD)) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface, protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology is being integrated with existing coal-gasifiers.

  12. Improved Flow-Field Structures for Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Gurau, Bogdan

    2013-05-31T23:59:59.000Z

    The direct methanol fuel cell (DMFC) is ideal if high energy-density liquid fuels are required. Liquid fuels have advantages over compressed hydrogen including higher energy density and ease of handling. Although state-of-the-art DMFCs exhibit manageable degradation rates, excessive fuel crossover diminishes system energy and power density. Although use of dilute methanol mitigates crossover, the concomitant lowering of the gross fuel energy density (GFED) demands a complex balance-of-plant (BOP) that includes higher flow rates, external exhaust recirculation, etc. An alternative approach is redesign of the fuel delivery system to accommodate concentrated methanol. NuVant Systems Inc. (NuVant) will maximize the GFED by design and assembly of a DMFC that uses near neat methanol. The approach is to tune the diffusion of highly concentrated methanol (to the anode catalytic layer) to the back-diffusion of water formed at the cathode (i.e. in situ generation of dilute methanol at the anode layer). Crossover will be minimized without compromising the GFED by innovative integration of the anode flow-field and the diffusion layer. The integrated flow-field-diffusion-layers (IFDLs) will widen the current and potential DMFC operating ranges and enable the use of cathodes optimized for hydrogen-air fuel cells.

  13. Reactivity of Hydrogen and Methanol on (001) Surfaces of WO3, ReO3, WO3/ReO3 and ReO3/WO3

    SciTech Connect (OSTI)

    Ling, Sanliang; Mei, Donghai; Gutowski, Maciej S.

    2011-05-16T23:59:59.000Z

    Bulk tungsten trioxide (WO3) and rhenium trioxide (ReO3) share very similar structures but display different electronic properties. WO3 is a wide bandgap semiconductor while ReO3 is an electronic conductor. With the advanced molecular beam epitaxy techniques, it is possible to make heterostructures comprised of layers of WO3 and ReO3. These heterostructures might display reactivity different than pure WO3 and ReO3. The interactions of two probe molecules (hydrogen and methanol) with the (001) surfaces of WO3, ReO3, and two heterostructures ReO3/WO3 and WO3/ReO3 were investigated at the density functional theory level. Atomic hydrogen prefers to adsorb at the terminal O1C sites forming a surface hydroxyl on four surfaces. Dissociative adsorption of a hydrogen molecule at the O1C site leads to formation of a water molecule adsorbed at the surface M5C site. This is thermodynamically the most stable state. A thermodynamically less stable dissociative state involves two surface hydroxyl groups O1CH and O2CH. The interaction of molecular hydrogen and methanol with pure ReO3 is stronger than with pure WO3 and the strength of the interaction substantially changes on the WO3/ReO3 and ReO3/WO3 heterostructures. The reaction barriers for decomposition and recombination reactions are sensitive to the nature of heterostructure. The calculated adsorption energy of methanol on WO3(001) of -65.6 kJ/mol is consistent with the previous experimental estimation of -67 kJ/mol. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

  14. Modeling hydrogen and helium entrapment in flowing liquid metal surfaces as plasma-facing components in

    E-Print Network [OSTI]

    Harilal, S. S.

    Modeling hydrogen and helium entrapment in flowing liquid metal surfaces as plasma the PFC surface (helium and hydrogen isotopes) while accommodating high heat loads. To study this problem rather than requiring a standard vacuum system. Hydrogen isotope (DT) particles that strike the surface

  15. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study

    SciTech Connect (OSTI)

    Ye, Jingyun; Liu, Changjun; Mei, Donghai; Ge, Qingfeng

    2013-06-03T23:59:59.000Z

    Methanol synthesis from CO2 hydrogenation on the defective In2O3(110) surface with surface oxygen vacancies has been investigated using periodic density functional theory calculations. The relative stabilities of six possible surface oxygen vacancies numbered from Ov1 to Ov6 on the perfect In2O3(110) surface were examined. The calculated oxygen vacancy formation energies show that the D1 surface with the Ov1 defective site is the most thermodynamically favorable while the D4 surface with the Ov4 defective site is the least stable. Two different methanol synthesis routes from CO2 hydrogenation over both D1 and D4 surfaces were studied and the D4 surface was found to be more favorable for CO2 activation and hydrogenation. On the D4 surface, one of the O atoms of the CO2 molecule fills in the Ov4 site upon adsorption. Hydrogenation of CO2 to HCOO on the D4 surface is both thermodynamically and kinetically favorable. Further hydrogenation of HCOO involves both forming the C-H bond and breaking the C-O bond, resulting in H2CO and hydroxyl. The HCOO hydrogenation is slightly endothermic with an activation barrier of 0.57 eV. A high barrier of 1.14 eV for the hydrogenation of H2CO to H3CO indicates that this step is the rate-limiting step in the methanol synthesis on the defective In2O3(110) surface. We gratefully acknowledge the supports from the National Natural Science Foundation of China (#20990223) and from US Department of Energy, Basic Energy Science program (DE-FG02-05ER46231). D. Mei was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. The computations were performed in part using the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), which is a U.S. Department of Energy national scientific user facility located at Pacific Northwest National Laboratory in Richland, Washington. PNNL is a multiprogram national laboratory operated for DOE by Battelle.

  16. Vibrational relaxation of the free terminal hydroxyl stretch in methanol oligomers: Indirect pathway to hydrogen bond breaking

    E-Print Network [OSTI]

    Fayer, Michael D.

    Vibrational relaxation of methanol-d MeOD in carbon tetrachloride has been investigated via ultrafast infrared such as carbon tetrachloride (CCl4) or alkanes. Unlike water, which is only sparingly soluble in nonpolar

  17. Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) process. Technical progress report number 6, October 1--December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    The project involves the construction of an 80,000 gallons per day (260 TPD) methanol unit utilizing coal-derived synthesis gas from Eastman`s integrated coal gasification facility. The new equipment consists of synthesis gas feed preparation and compression facilities, the liquid phase reactor and auxiliaries, product distillation facilities, and utilities. The technology to be demonstrated is the product of a cooperative development effort by Air Products and DOE in a program that started in 1981. Developed to enhance electric power generation using integrated gasification combined cycle (IGCC) technology, the LPMEOH{trademark} process is ideally suited for directly processing gases produced by modern-day coal gasifiers. This liquid phase process suspends fine catalyst particles in an inert liquid, forming a slurry. The slurry dissipates the heat of the chemical reaction away from the catalyst surface protecting the catalyst and allowing the methanol synthesis reaction to proceed at higher rates. At the Eastman complex, the technology will be integrated with existing coal-gasifiers. A carefully developed test plan will allow operations at Eastman to simulate electricity demand load-following in coal-based IGCC facilities. The operations will also demonstrate the enhanced stability and heat dissipation of the conversion process, its reliable on/off operation, and its ability to produce methanol as a clean liquid fuel without additional upgrading. An off-site product testing program will be conducted to demonstrate the suitability of the methanol product as a transportation fuel and as a fuel for stationary applications for small modular electric power generators for distributed power.

  18. Air Breathing Direct Methanol Fuel Cell

    DOE Patents [OSTI]

    Ren; Xiaoming (Los Alamos, NM)

    2003-07-22T23:59:59.000Z

    A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

  19. Operating experience with a liquid-hydrogen fueled Buick and refueling system

    SciTech Connect (OSTI)

    Stewart, W.F.

    1982-01-01T23:59:59.000Z

    An investigation of liquid-hydrogen storage and refueling systems for vehicular applications was made in a recently completed project. The vehicle used in the project was a 1979 Buick Century sedan with a 3.8-L displacement turbocharged V6 engine and an automatic transmission. The vehicle had a fuel economy for driving in the high altitude Los Alamos area that was equivalent to 2.4 km/L of liquid hydrogen or 8.9 km/L of gasoline on an equivalent energy basis. About 22% less energy was required using hydrogen rather than gasoline to go a given distance based on the Environmental Protection Agency estimate of 7.2 km/L of gasoline for this vehicle. At the end of the project the engine had been operated for 138 h and the car driven 3633 km during the 17 months that the vehicle was operated on hydrogen . Two types of onboard liquid-hydrogen storage tanks were tested in the vehicle: the first was an aluminum Dewar with a liquid-hydrogen capacity of 110 L; the second was a Dewar with an aluminum outer vessel, two copper vapor-cooled thermal radiation shields, and a stainless steel inner vessel with a liquid-hydrogen capacity of 155 L. The Buick had an unrefueled range of about 274 km with the first liquid-hydrogen tank and about 362 km with the second. The Buick was fueled at least 65 times involving a minimum of 8.1 kL of liquid hydrogen using various liquid-hydrogen storage Dewars at Los Alamos and a semiautomatic refueling station. A refueling time of nine minutes was achieved, and liquid hydrogen losses during refueling were measured. The project has demonstrated that liquid-hydrogen storage onboard a vehicle, and its refueling, can be accomplished over an extended period without any major difficulties; nevertheless, appropriate testing is still needed to quantitatively address the question of safety for liquid-hydrogen storage onboard a vehicle.

  20. Polymer formulation for removing hydrogen and liquid water from an enclosed space

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA)

    2006-02-21T23:59:59.000Z

    This invention describes a solution to the particular problem of liquid water formation in hydrogen getters exposed to quantities of oxygen. Water formation is usually desired because the recombination reaction removes hydrogen without affecting gettering capacity and the oxygen removal reduces the chances for a hydrogen explosion once free oxygen is essentially removed. The present invention describes a getter incorporating a polyacrylate compound that can absorb up to 500% of its own weight in liquid water without significantly affecting its hydrogen gettering/recombination properties, but that also is insensitive to water vapor.

  1. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Background Paper

    Broader source: Energy.gov [DOE]

    Paper by Arlene Anderson and Tracy Carole presented at the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group, with a focus on key drivers, purpose, and scope.

  2. Technical Assessment of Organic Liquid Carrier Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    usable hydrogen. The results were compared to DOE's 2010, 2017, and ultimate full fleet hydrogen storage targets. The off-board performance including the Well-to-Tank and...

  3. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG),

    E-Print Network [OSTI]

    ReviewReport. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 12:30ResearchReviewContinued Investigation of Bio-ethanol Steam Reforming over Cobalt based Ethanol Reforming,ANL,RomeshKumar ..................23 MeritBio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), Hydrogen

  4. Electrokinetic Hydrogen Generation from Liquid Water Microjets Andrew M. Duffin and Richard J. Saykally,*

    E-Print Network [OSTI]

    Cohen, Ronald C.

    of natural gas. These thermal methods are relatively cheap, but they do not mitigate difficulties associatedElectrokinetic Hydrogen Generation from Liquid Water Microjets Andrew M. Duffin and Richard J, 2007; In Final Form: May 31, 2007 We describe a method for generating molecular hydrogen directly from

  5. Time-resolved photoelectron imaging of large anionic methanol clusters: ,,Methanol...n

    E-Print Network [OSTI]

    Neumark, Daniel M.

    Time-resolved photoelectron imaging of large anionic methanol clusters: ,,Methanol...n - ,,nČ145; published online 27 June 2007 The dynamics of an excess electron in size-selected methanol clusters electron6­11 and its cluster counterparts,12­18 water n - . The solvated electron in liquid methanol has

  6. Produce syngas for methanol

    SciTech Connect (OSTI)

    Farina, G.L. (Foster Wheeler International Corp., Milan (IT))

    1992-03-01T23:59:59.000Z

    Combined reforming, in which an oxygen reforming reactor is added downstream from a conventional tubular reactor to produce syngas for methanol, achieves a substantial reduction in energy consumption with the least impact on the environment. This paper reports that the advantages of this process scheme are as follows: 8% to 10% reduction in the consumption of natural gas per ton of methanol, The size of the primary reformer is reduced, Reduction of syngas compression requirement due to increased syngas pressure, Reduced steam consumption, Production of syngas with the stoichiometric composition required by methanol synthesis. Synthesis gases for the production of methanol and synfuels are basically mixtures of hydrogen and carbon oxides. They have been produced from natural gas by steam reforming, autothermal reforming and noncatalytic partial oxidation.

  7. Long time fluctuation of liquid water: l/f spectrum of energy fluctuation in hydrogen bond network rearrangement dynamics

    E-Print Network [OSTI]

    Ramaswamy, Ram

    Long time fluctuation of liquid water: l/f spectrum of energy fluctuation in hydrogen bond network of the potential energy fluctuation of liquid water is examined and found to yield so-called l/f frequency of hydrogen bond network relaxations in liquid water. A simple model of cellular dynamics is proposed

  8. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07T23:59:59.000Z

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  9. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Laboratory Investigation of Reaction Networks and Active Sites in Bio-Ethanol Steam Reforming over Cobalt Based Catalysts, Umit Ozkan, Ohio State University Hydrogen...

  10. Direct methanol fuel cell and system

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    2004-10-26T23:59:59.000Z

    A fuel cell having an anode and a cathode and a polymer electrolyte membrane located between anode and cathode gas diffusion backings uses a methanol vapor fuel supply. A permeable polymer electrolyte membrane having a permeability effective to sustain a carbon dioxide flux equivalent to at least 10 mA/cm.sup.2 provides for removal of carbon dioxide produced at the anode by reaction of methanol with water. Another aspect of the present invention includes a superabsorpent polymer material placed in proximity to the anode gas diffusion backing to hold liquid methanol or liquid methanol solution without wetting the anode gas diffusion backing so that methanol vapor from the liquid methanol or liquid methanol-water solution is supplied to the membrane.

  11. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

    1989-10-17T23:59:59.000Z

    A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

  12. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, James B. (Denville, NJ); Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (Somerville, NJ)

    1989-01-01T23:59:59.000Z

    A process for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600.degree.-750.degree. F. to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650.degree. F. and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-90 lb/hr per ft.sup.3 catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760.degree.-860.degree. F. temperature for further hydrogenation and hydroconversion reactions. A 600.degree.-750.degree. F..sup.+ fraction containing 0-20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials.

  13. Design and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air or Liquid Heat Integration

    E-Print Network [OSTI]

    Berning, Torsten

    of burner temperature and the aspects of implementing advanced modeling based control approaches using], auxiliary and uninterruptible power systems [13, 14, 15, 16, 17, 18, 19]. Polymer electrolyte membrane fuelDesign and Control of High Temperature PEM Fuel Cell Systems using Methanol Reformers with Air

  14. Hydrogen Supply: Cost Estimate for Hydrogen Pathways?Scoping...

    Broader source: Energy.gov (indexed) [DOE]

    Central Methanol Methanol Forecourt Gasoline Gasoline Forecourt H 2 from ethylene or refinery Residuepitch Central The by-product source of hydrogen defined by IHIG in the...

  15. Cryogenic, compressed, and liquid hydrogen fuel storage in vehicles

    E-Print Network [OSTI]

    Reyes, Allan B

    2007-01-01T23:59:59.000Z

    Hydrogen is the viable energy carrier of future energy and transportation systems due to its clean emissions, light weight, and abundance. Its extremely low volumetric density, however, presents significant challenges to ...

  16. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source.

  17. FINAL REPORT: Room Temperature Hydrogen Storage in Nano-Confined Liquids

    SciTech Connect (OSTI)

    VAJO, JOHN

    2014-06-12T23:59:59.000Z

    DOE continues to seek solid-state hydrogen storage materials with hydrogen densities of ?6 wt% and ?50 g/L that can deliver hydrogen and be recharged at room temperature and moderate pressures enabling widespread use in transportation applications. Meanwhile, development including vehicle engineering and delivery infrastructure continues for compressed-gas hydrogen storage systems. Although compressed gas storage avoids the materials-based issues associated with solid-state storage, achieving acceptable volumetric densities has been a persistent challenge. This project examined the possibility of developing storage materials that would be compatible with compressed gas storage technology based on enhanced hydrogen solubility in nano-confined liquid solvents. These materials would store hydrogen in molecular form eliminating many limitations of current solid-state materials while increasing the volumetric capacity of compressed hydrogen storage vessels. Experimental methods were developed to study hydrogen solubility in nano-confined liquids. These methods included 1) fabrication of composites comprised of volatile liquid solvents for hydrogen confined within the nano-sized pore volume of nanoporous scaffolds and 2) measuring the hydrogen uptake capacity of these composites without altering the composite composition. The hydrogen storage capacities of these nano-confined solvent/scaffold composites were compared with bulk solvents and with empty scaffolds. The solvents and scaffolds were varied to optimize the enhancement in hydrogen solubility that accompanies confinement of the solvent. In addition, computational simulations were performed to study the molecular-scale structure of liquid solvent when confined within an atomically realistic nano-sized pore of a model scaffold. Confined solvent was compared with similar simulations of bulk solvent. The results from the simulations were used to formulate a mechanism for the enhanced solubility and to guide the experiments. Overall, the combined experimental measurements and simulations indicate that hydrogen storage based on enhanced solubility in nano-confined liquids is unlikely to meet the storage densities required for practical use. Only low gravimetric capacities of < 0.5 wt% were achieved. More importantly, solvent filled scaffolds had lower volumetric capacities than corresponding empty scaffolds. Nevertheless, several of the composites measured did show significant (>~ 5x) enhanced hydrogen solubility relative to bulk solvent solubility, when the hydrogen capacity was attributed only to dissolution in the confined solvent. However, when the hydrogen capacity was compared to an empty scaffold that is known to store hydrogen by surface adsorption on the scaffold walls, including the solvent always reduced the hydrogen capacity. For the best composites, this reduction relative to an empty scaffold was ~30%; for the worst it was ~90%. The highest capacities were obtained with the largest solvent molecules and with scaffolds containing 3- dimensionally confined pore geometries. The simulations suggested that the capacity of the composites originated from hydrogen adsorption on the scaffold pore walls at sites not occupied by solvent molecules. Although liquid solvent filled the pores, not all of the adsorption sites on the pore walls were occupied due to restricted motion of the solvent molecules within the confined pore space.

  18. Surface Studies of Aqueous Methanol Solutions by Vibrational Broad Bandwidth Sum Frequency Generation Spectroscopy

    E-Print Network [OSTI]

    Surface Studies of Aqueous Methanol Solutions by Vibrational Broad Bandwidth Sum Frequency methanol (CH3OH) and aqueous methanol solutions were investigated using broad bandwidth sum frequency of methanol molecules at the air-liquid interfaces of neat methanol and aqueous methanol solutions. However

  19. Meeting U.S. Liquid Transport Fuel Needs with a Nuclear Hydrogen Biomass System

    SciTech Connect (OSTI)

    Forsberg, Charles W [ORNL

    2007-01-01T23:59:59.000Z

    The two major energy challenges for the United States are replacing crude oil in our transportation system and eliminating greenhouse gas emissions. A domestic-source greenhouse-gas-neutral nuclear hydrogen biomass system to replace oil in the transportation sector is described. Some parts of the transportation system can be electrified with electricity supplied by nuclear energy sources that do not emit significant quantities of greenhouse gases. Other components of the transportation system require liquid fuels. Biomass can be converted to greenhouse-gas-neutral liquid fuels; however, the conversion of biomass-to-liquid fuels is energy intensive. There is insufficient biomass to meet U.S. liquid fuel demands and provide the energy required to process the biomass-to-liquid fuels. With the use of nuclear energy to provide heat, electricity, and hydrogen for the processing of biomass-to-liquid fuels, the liquid fuel production per unit of biomass is dramatically increased, and the available biomass could meet U.S. liquid fuel requirements.

  20. Modeling of Plasma-Assisted Conversion of Liquid Ethanol into Hydrogen Enriched Syngas in the Nonequilibrium Electric Discharge Plasma-Liquid System

    E-Print Network [OSTI]

    Levko, Dmitry; Naumov, Vadim; Chernyak, Valery; Yukhymenko, Vitaly; Prysiazhnevych, Irina; Olszewski, Sergey

    2008-01-01T23:59:59.000Z

    In this work we report recent results of our experimental and theoretical studies related to plasma conversion of liquid ethanol into hydrogen-enriched syngas in the plasma-liquid system with the electric discharge in a gas channel with liquid wall using available diagnostics and numerical modeling.

  1. Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Kick-Off Meeting Proceedings Hilton Garden Inn-BWI,Baltimore, MD October 24, 2006

    Broader source: Energy.gov [DOE]

    Proceedings from the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  2. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField Campaign:INEAWater UseCElizabethTwoJaniceEnerG2Energetics of Hydrogen

  3. Gaseous and Liquid Hydrogen Storage | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdf Flash2006-52.pdf0.pdfDepartment ofEnergyGE-ProlecGTO 2013Gas-FiredHydrogen

  4. Hydrogen from Bio-Derived Liquids (Presentation) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D eReviewEducationHydrogen and Fuelas afrom

  5. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    SciTech Connect (OSTI)

    Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

    2010-05-01T23:59:59.000Z

    We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

  6. Hydrogen Fluoride Capture by Imidazolium Acetate Ionic Liquid

    E-Print Network [OSTI]

    Chaban, Vitaly

    2015-01-01T23:59:59.000Z

    Extraction of hydrofluoric acid (HF) from oils is a drastically important problem in petroleum industry, since HF causes quick corrosion of pipe lines and brings severe health problems to humanity. Some ionic liquids (ILs) constitute promising scavenger agents thanks to strong binding to polar compounds and tunability. PM7-MD simulations and hybrid density functional theory are employed here to consider HF capture ability of ILs. Discussing the effects and impacts of the cation and the anion separately and together, I will evaluate performance of imidazolium acetate and outline systematic search guidelines for efficient adsorption and extraction of HF.

  7. Liquid-phase methanol process development unit: installation, operation, and support studies. Technical progress report No. 1, 28 September 1981-31 December 1981

    SciTech Connect (OSTI)

    Not Available

    1982-01-20T23:59:59.000Z

    During this period the Work Breakdown Structure Dictionary was established. Task 1 was completed with submittal of the Project Work Plan and the Quality Assurance Manual. CSI produced basic process design information and a preliminary flowsheet for the LaPorte LPMeOH PDU. APCI developed the flowsheet further and set up the process on APCI's process simulator. The flowsheet development revealed a number of major changes necessary in the existing LPM pilot plant; this has led to pursuit of a unified design concept. Approval was requested for the unified design concept as well as advanced schedule for relocation of the LPM unit and advanced procurement of long delivery equipment items. A number of preliminary heat and material balances were calculated for the LPMeOH PDU and preliminary process specifications were prepared for the equipment items. The final design basis was established. The design pressure was set at 1000 psig. Eight design operating cases were defined for the following range of reactor operating conditions: Pressure - 500 to 900 psig, Temperature - 220 to 270/sup 0/C, Liquid-Fluidized Space Velocity - 1000 to 4000 l/hr-kg catalyst, Liquid-Entrained Space Velocity - 2000 to 10,000 l/hr-kg catalyst, and Liquid-Entrained Catalyst Loading - 0.1 to 0.4 kg catalyst/l oil. The methanol production rate for these cases ranges from 0.2 to 9.7 short tons per day. Preliminary equipment arrangement and site layout drawings were prepared for the PDU. In the laboratories, CSI began autoclave testing of in-situ catalyst reduction procedures. The specification and evaluation of equipment for the CSI laboratory PDU progressed. CSI prepared and issued a Topical Report covering liquid-entrained LPMeOH lab development work accomplished under advance funding. APCI's laboratories progressed with the design of the bench scale slurry reactor.

  8. Observation of crystallization slowdown in supercooled para-hydrogen and ortho-deuterium quantum liquid mixtures

    E-Print Network [OSTI]

    Matthias Kühnel; José M. Fernández; Filippo Tramonto; Guzmán Tejeda; Elena Moreno; Anton Kalinin; Marco Nava; Davide E. Galli; Salvador Montero; Robert E. Grisenti

    2014-10-10T23:59:59.000Z

    We report a quantitative experimental study of the crystallization kinetics of supercooled quantum liquid mixtures of para-hydrogen (pH$_2$) and ortho-deuterium (oD$_2$) by high spatial resolution Raman spectroscopy of liquid microjets. We show that in a wide range of compositions the crystallization rate of the isotopic mixtures is significantly reduced with respect to that of the pure substances. To clarify this behavior we have performed path-integral simulations of the non-equilibrium pH$_2$-oD$_2$ liquid mixtures, revealing that differences in quantum delocalization between the two isotopic species translate into different effective particle sizes. Our results provide first experimental evidence for crystallization slowdown of quantum origin, offering a benchmark for theoretical studies of quantum behavior in supercooled liquids.

  9. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenati...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on...

  10. Homogeneous Hydrogenation of CO? to Methyl Formate Utilizing Switchable Ionic Liquids

    SciTech Connect (OSTI)

    Yadav, Mahendra; Linehan, John C.; Karkamkar, Abhijeet J.; Van Der Eide, Edwin F.; Heldebrant, David J.

    2014-09-15T23:59:59.000Z

    Capture of CO? and subsequent hydrogenation allows for base/alcohol-catalyzed conversion of CO? to methylformate in one pot. The conversion of CO? proceeds via alkylcarbonates, to formate salts and then formate esters, which can be catalyzed by base and alcohol with the only byproduct being water. The system operates at mild conditions (300 psi H?, 140 °C). Reactivity is strongly influenced by temperature and choice of solvent. In the presence of excess of base (DBU) formate is predominant product while in excess of methanol methyl formate is major product. 110 °C yields formate salts, 140 °C promotes methylformate. The authors acknowledge internal Laboratory Directed Re-search and Development (LDRD) funding from Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the U.S. Department of Energy.

  11. Observation of Fractional Stokes-Einstein Behavior in the Simplest Hydrogen-bonded Liquid

    SciTech Connect (OSTI)

    Herwig, Kenneth W [ORNL; Molaison, Jamie J [ORNL; Fernandez-Alonso, F. [ISIS Facility, Rutherford Appleton Laboratory; Bermejo, F. J. [CSIC - Inst. Estructura de la Materia & Dept. of Electricity and Electronics; Turner, John F. C. [University of Tennessee, Knoxville (UTK); McLain, Sylvia E. [ISIS Facility, Rutherford Appleton Laboratory

    2007-01-01T23:59:59.000Z

    Quasielastic neutron scattering has been used to investigate the single-particle dynamics of hydrogen fluoride across its entire liquid range at ambient pressure. For T > 230 K, translational diffusion obeys the celebrated Stokes-Einstein relation, in agreement with nuclear magnetic resonance studies. At lower temperatures, we find significant deviations from the above behavior in the form of a power law with exponent xi = -0.71+/-0.05. More striking than the above is a complete breakdown of the Debye-Stokes-Einstein relation for rotational diffusion. Our findings provide the first experimental verification of fractional Stokes-Einstein behavior in a hydrogen-bonded liquid, in agreement with recent computer simulations.

  12. Liquid–solid phase transition of hydrogen and deuterium in silica aerogel

    SciTech Connect (OSTI)

    Van Cleve, E.; Worsley, M. A.; Kucheyev, S. O., E-mail: kucheyev@llnl.gov [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

    2014-10-28T23:59:59.000Z

    Behavior of hydrogen isotopes confined in disordered low-density nanoporous solids remains essentially unknown. Here, we use relaxation calorimetry to study freezing and melting of H{sub 2} and D{sub 2} in an ?85%-porous base-catalyzed silica aerogel. We find that liquid–solid transition temperatures of both isotopes inside the aerogel are depressed. The phase transition takes place over a wide temperature range of ?4?K and non-trivially depends on the liquid filling fraction, reflecting the broad pore size distribution in the aerogel. Undercooling is observed for both H{sub 2} and D{sub 2} confined inside the aerogel monolith. Results for H{sub 2} and D{sub 2} are extrapolated to tritium-containing hydrogens with the quantum law of corresponding states.

  13. A high power liquid hydrogen target for the Mainz A4 parity violation experiment

    E-Print Network [OSTI]

    I. Altarev; E. Schilling; S. Baunack; L. Capozza; J. Diefenbach; K. Grimm; Th. Hammel; D. vonHarrach; Y. Imai; E. M. Kabuss; R. Kothe; J. H. Lee; A. LopesGinja; F. E. Maas; A. SanchezLorente; G. Stephan; C. Weinrich

    2005-04-25T23:59:59.000Z

    We present a new powerful liquid hydrogen target developed for the precise study of parity violating electron scattering on hydrogen and deuterium. This target has been designed to have minimal target density fluctuations under the heat load of a 20$\\mu$A CW 854.3 MeV electron beam without rastering the electron beam. The target cell has a wide aperture for scattered electrons and is axially symmetric around the beam axis. The construction is optimized to intensify heat exchange by a transverse turbulent mixing in the hydrogen stream, which is directed along the electron beam. The target is constructed as a closed loop circulating system cooled by a helium refrigerator. It is operated by a tangential mechanical pump with an optional natural convection mode. The cooling system supports up to 250 watts of the beam heating removal. Deeply subcooled liquid hydrogen is used for keeping the in-beam temperature below the boiling point. The target density fluctuations are found to be at the level 10$^{-3}$ at a beam current of 20 $\\mu$A.

  14. Liquid-liquid equilibria for hydrogen fluoride + 1,1-dichloro-1-fluoroethane + 1-chloro-1,1-difluoroethane at {minus}20 and 20 C

    SciTech Connect (OSTI)

    Kang, Y.W.; Lee, Y.Y. [KIST, Seoul (Korea, Republic of). CFC Alternatives Technology Center

    1995-03-01T23:59:59.000Z

    1,1-Dichloro-1-fluoroethane is presently under consideration as a replacement for trichlorofluoromethane, which is widely used as a foam blowing agent. 1-Chloro-1,1-difluoroethane is the major raw material for the production of poly(vinylidene fluoride). These two materials are normally manufactured by the fluorination of 1,1,1-trichloroethane or vinylidene chloride with hydrogen fluoride. A phase separator is normally used to retrieve hydrogen fluoride from the product stream. To design the phase separator, liquid-liquid equilibrium data are required. Liquid-liquid equilibria for the ternary system (hydrogen fluoride + 1,1-dichloro-1-fluoroethane + 1-chloro-1,1-difluoroethane) have been measured at {minus}20 and 20 C. The results are correlated with the NRTL model, and the relevant parameters are presented.

  15. Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte Ranga S. Jayashree, Michael Mitchell, Dilip Natarajan, Larry J. Markoski, and

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Letters Microfluidic Hydrogen Fuel Cell with a Liquid Electrolyte Ranga S. Jayashree, Michael and characterization of a microfluidic hydrogen fuel cell with a flowing sulfuric acid solution instead of a Nafion, and electrolyte flow rate on fuel cell performance to obtain a maximum power density of 191 mW/cm2. This flowing

  16. High Temperature Separation of Carbon Dioxide/Hydrogen Mixtures Using Facilitated Supported Ionic Liquid Membranes

    SciTech Connect (OSTI)

    Myers, C.R.; Pennline, H.W.; Luebke, D.R.; Ilconich, J.B.; Dixon, J.K. (Univ. of Notre Dame, Notre Dame, IN); Maginn, E.J. (Univ. of Notre Dame, Notre Dame, IN); Brennecke, J.F. (Univ. of Notre Dame, Notre Dame, IN)

    2008-09-01T23:59:59.000Z

    Efficiently separating CO2 from H2 is one of the key steps in the environmentally responsible uses of fossil fuel for energy production. A wide variety of resources, including petroleum coke, coal, and even biomass, can be gasified to produce syngas (a mixture of COand H2). This gas stream can be further reacted with water to produce CO2 and more H2. Once separated, the CO2 can be stored in a variety of geological formations or sequestered by other means. The H2 can be combusted to operate a turbine, producing electricity, or used to power hydrogen fuel cells. In both cases, onlywater is produced as waste. An amine functionalized ionic liquid encapsulated in a supported ionic liquid membrane (SILM) can separate CO2 from H2 with a higher permeability and selectivity than any known membrane system. This separation is accomplished at elevated temperatures using facilitated transport supported ionic liquid membranes.

  17. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Water loss from the cell is minimized by making the conductive cathode assembly hydrophobic and the conductive anode assembly hydrophilic.

  18. Solute retention in column liquid chromatography. X. Determination of solute infinite-dilution activity coefficients in methanol, water, and their mixtures, by combined gas-liquid and liquid-liquid chromatography

    SciTech Connect (OSTI)

    Djerki, R.A.; Laub, R.J.

    1988-01-01T23:59:59.000Z

    The Raoult's-law activity coefficients of 3- to 7-carbon aliphatic aldehyde, ketone, ester, and alcohol solutes at infinite dilution in methanol, water, and mixtures of the two and in polydimethysiloxane, all at 293-308 K, have been determined for the first time by appropriate combination of GLC and LLC retention data. The latter data are reported in terms of mole factions, while the former are given in concentration units of molality. However, interpretation of the data is difficult because of the multiplicity of the retention mechanisms. Nevertheless, the combined GLC/LLC technique, which had been applied previously only to pure solvents, is said to offer a number of advantages over static techniques for the determination of solute infinite-dilution activity coefficients with volatile solvents, especially with mixtures of solvents.

  19. Method and apparatus for electrokinetic co-generation of hydrogen and electric power from liquid water microjets

    DOE Patents [OSTI]

    Saykally, Richard J; Duffin, Andrew M; Wilson, Kevin R; Rude, Bruce S

    2013-02-12T23:59:59.000Z

    A method and apparatus for producing both a gas and electrical power from a flowing liquid, the method comprising: a) providing a source liquid containing ions that when neutralized form a gas; b) providing a velocity to the source liquid relative to a solid material to form a charged liquid microjet, which subsequently breaks up into a droplet spay, the solid material forming a liquid-solid interface; and c) supplying electrons to the charged liquid by contacting a spray stream of the charged liquid with an electron source. In one embodiment, where the liquid is water, hydrogen gas is formed and a streaming current is generated. The apparatus comprises a source of pressurized liquid, a microjet nozzle, a conduit for delivering said liquid to said microjet nozzle, and a conductive metal target sufficiently spaced from said nozzle such that the jet stream produced by said microjet is discontinuous at said target. In one arrangement, with the metal nozzle and target electrically connected to ground, both hydrogen gas and a streaming current are generated at the target as it is impinged by the streaming, liquid spray microjet.

  20. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, Meyer (Melville, NY); Grohse, Edward W. (Port Jefferson, NY)

    1995-01-01T23:59:59.000Z

    A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

  1. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, M.; Grohse, E.W.

    1995-06-27T23:59:59.000Z

    A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

  2. Structure of crystalline methanol at high pressure David R. Allan

    E-Print Network [OSTI]

    Vos, Willem L.

    Structure of crystalline methanol at high pressure David R. Allan Department of Physics structure, including all atomic positions, of methanol at high pressure and room temperature pressure of methanol is 3.5 GPa. In practice however, it is very easy to superpress the liquid phase

  3. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    E-Print Network [OSTI]

    Wen, Haidan

    2010-01-01T23:59:59.000Z

    manifesting in fewer/weaker hydrogen bonds and structuralstructures with weaker hydrogen-bonding is recorded viais characteristic of the hydrogen bond network in water. The

  4. Methanol production method and system

    DOE Patents [OSTI]

    Chen, Michael J. (Darien, IL); Rathke, Jerome W. (Bolingbrook, IL)

    1984-01-01T23:59:59.000Z

    Ethanol is selectively produced from the reaction of methanol with carbon monoxide and hydrogen in the presence of a transition metal carbonyl catalyst. Methanol serves as a solvent and may be accompanied by a less volatile co-solvent. The solution includes the transition metal carbonyl catalysts and a basic metal salt such as an alkali metal or alkaline earth metal formate, carbonate or bicarbonate. A gas containing a high carbon monoxide to hydrogen ratio, as is present in a typical gasifer product, is contacted with the solution for the preferential production of ethanol with minimal water as a byproduct. Fractionation of the reaction solution provides substantially pure ethanol product and allows return of the catalysts for reuse.

  5. Liquid Fuel From Bacteria: Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from CO2, Hydrogen, and Oxygen

    SciTech Connect (OSTI)

    None

    2010-07-15T23:59:59.000Z

    Electrofuels Project: MIT is using solar-derived hydrogen and common soil bacteria called Ralstonia eutropha to turn carbon dioxide (CO2) directly into biofuel. This bacteria already has the natural ability to use hydrogen and CO2 for growth. MIT is engineering the bacteria to use hydrogen to convert CO2 directly into liquid transportation fuels. Hydrogen is a flammable gas, so the MIT team is building an innovative reactor system that will safely house the bacteria and gas mixture during the fuel-creation process. The system will pump in precise mixtures of hydrogen, oxygen, and CO2, and the online fuel-recovery system will continuously capture and remove the biofuel product.

  6. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder (Port Jefferson, NY); Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); O'Hare, Thomas E. (Huntington Station, NY)

    1991-02-12T23:59:59.000Z

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.-), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  7. Homogeneous catalyst formulations for methanol production

    DOE Patents [OSTI]

    Mahajan, Devinder (Port Jefferson, NY); Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY); O'Hare, Thomas E. (Huntington Station, NY)

    1990-01-01T23:59:59.000Z

    There is disclosed synthesis of CH.sub.3 OH from carbon monoxide and hydrogen using an extremely active homogeneous catalyst for methanol synthesis directly from synthesis gas. The catalyst operates preferably between 100.degree.-150.degree. C. and preferably at 100-150 psia synthesis gas to produce methanol. Use can be made of syngas mixtures which contain considerable quantities of other gases, such as nitrogen, methane or excess hydrogen. The catalyst is composed of two components: (a) a transition metal carbonyl complex and (b) an alkoxide component. In the simplest formulation, component (a) is a complex of nickel tetracarbonyl and component (b) is methoxide (CH.sub.3 O.sup.13 ), both being dissolved in a methanol solvent system. The presence of a co-solvent such as p-dioxane, THF, polyalcohols, ethers, hydrocarbons, and crown ethers accelerates the methanol synthesis reaction.

  8. Hydrogen Delivery Analysis Models

    Broader source: Energy.gov (indexed) [DOE]

    insert our Research Targets to see the impact List of Delivery Components Compressed Hydrogen Gas Truck (Tube trailer) Compressed Hydrogen Gas Truck Terminal Liquid Hydrogen Truck...

  9. Challenges and design solutions of the liquid hydrogen circuit at the European Spallation Source

    SciTech Connect (OSTI)

    Gallimore, S.; Nilsson, P.; Sabbagh, P.; Takibayev, A.; Weisend II, J. G. [European Spallation Source ESS AB, SE-22100 Lund (Sweden); Beßler, Y. [Forschungzentrum Jülich, Jülich (Germany); Klaus, M. [Technische Universität Dresden, Dresden (Germany)

    2014-01-29T23:59:59.000Z

    The European Spallation Source (ESS), Lund, Sweden will be a 5MW long-pulse neutron spallation research facility and will enable new opportunities for researchers in the fields of life sciences, energy, environmental technology, cultural heritage and fundamental physics. Neutrons are produced by accelerating a high-energy proton beam into a rotating helium-cooled tungsten target. These neutrons pass through moderators to reduce their energy to an appropriate range (< 5 meV for cold neutrons); two of which will use liquid hydrogen at 17 K as the moderating and cooling medium. There are several technical challenges to overcome in the design of a robust system that will operate under such conditions, not least the 20 kW of deposited heat. These challenges and the associated design solutions will be detailed in this paper.

  10. Hydrogen Cryomagnetics

    E-Print Network [OSTI]

    Glowacki, B. A.; Hanely, E.; Nuttall, W. J.

    2014-01-01T23:59:59.000Z

    in our current approach. The liquefaction of hydrogen allows also for its use in transport applications for example BMW developed a car that utilises liquid hydrogen instead of compressed gas hydrogen making the use of cryogenic hydrogen even more... efficient. 11     Figure 13. Decentralised production of hydrogen pathways for Energy and Hydrogen Cryomagnetic solutions for a hospital environment. The shaded region in the figure represents the decentralised production of hydrogen using renewable...

  11. "Kohn-Shamification" of the classical density-functional theory of inhomogeneous polar molecular liquids with application to liquid hydrogen chloride

    E-Print Network [OSTI]

    Johannes Lischner; T. A. Arias

    2008-06-27T23:59:59.000Z

    The Gordian knot of density-functional theories for classical molecular liquids remains finding an accurate free-energy functional in terms of the densities of the atomic sites of the molecules. Following Kohn and Sham, we show how to solve this problem by considering noninteracting molecules in a set of effective potentials. This shift in perspective leads to an accurate and computationally tractable description in terms of simple three-dimensional functions. We also treat both the linear- and saturation- dielectric responses of polar systems, presenting liquid hydrogen chloride as a case study.

  12. Enhanced methanol utilization in direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2001-10-02T23:59:59.000Z

    The fuel utilization of a direct methanol fuel cell is enhanced for improved cell efficiency. Distribution plates at the anode and cathode of the fuel cell are configured to distribute reactants vertically and laterally uniformly over a catalyzed membrane surface of the fuel cell. A conductive sheet between the anode distribution plate and the anodic membrane surface forms a mass transport barrier to the methanol fuel that is large relative to a mass transport barrier for a gaseous hydrogen fuel cell. In a preferred embodiment, the distribution plate is a perforated corrugated sheet. The mass transport barrier may be conveniently increased by increasing the thickness of an anode conductive sheet adjacent the membrane surface of the fuel cell.

  13. Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils

    SciTech Connect (OSTI)

    Huber, George W; Vispute, Tushar P; Routray, Kamalakanta

    2014-06-03T23:59:59.000Z

    Disclosed herein is a method of generating hydrogen from a bio-oil, comprising hydrogenating a water-soluble fraction of the bio-oil with hydrogen in the presence of a hydrogenation catalyst, and reforming the water-soluble fraction by aqueous-phase reforming in the presence of a reforming catalyst, wherein hydrogen is generated by the reforming, and the amount of hydrogen generated is greater than that consumed by the hydrogenating. The method can further comprise hydrocracking or hydrotreating a lignin fraction of the bio-oil with hydrogen in the presence of a hydrocracking catalyst wherein the lignin fraction of bio-oil is obtained as a water-insoluble fraction from aqueous extraction of bio-oil. The hydrogen used in the hydrogenating and in the hydrocracking or hydrotreating can be generated by reforming the water-soluble fraction of bio-oil.

  14. ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS

    SciTech Connect (OSTI)

    NONE

    1998-08-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through July 1999.

  15. Engineering development of ceramic membrane reactor system for converting natural gas to hydrogen and synthesis gas for liquid transportation fuels

    SciTech Connect (OSTI)

    NONE

    1998-07-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through June 1998.

  16. ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS

    SciTech Connect (OSTI)

    NONE

    1999-12-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through November 1999.

  17. ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS

    SciTech Connect (OSTI)

    NONE

    1999-03-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through February 1999.

  18. Engineering development of ceramic membrane reactor system for converting natural gas to hydrogen and synthesis gas for liquid transportation fuels

    SciTech Connect (OSTI)

    NONE

    1998-05-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through April 1998.

  19. ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS

    SciTech Connect (OSTI)

    NONE

    1999-10-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through September 1999.

  20. ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS

    SciTech Connect (OSTI)

    NONE

    2000-02-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through January 2000.

  1. ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS

    SciTech Connect (OSTI)

    NONE

    2000-01-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through December 1999.

  2. ENGINEERING DEVELOPMENT OF CERAMIC MEMBRANE REACTOR SYSTEM FOR CONVERTING NATURAL GAS TO HYDROGEN AND SYNTHESIS GAS FOR LIQUID TRANSPORTATION FUELS

    SciTech Connect (OSTI)

    NONE

    1999-11-01T23:59:59.000Z

    The objective of this contract is to research, develop and demonstrate a novel ceramic membrane reactor system for the low-cost conversion of natural gas to synthesis gas and hydrogen for liquid transportation fuels: the ITM Syngas process. Through an eight-year, three-phase program, the technology will be developed and scaled up to obtain the technical, engineering, operating and economic data necessary for the final step to full commercialization of the Gas-to-Liquids (GTL) conversion technology. This report is a summary of activities through October 1999.

  3. Experimental Evaluation of a Pt-based Heat Exchanger Methanol Reformer for a HTPEM Fuel Cell Stack

    E-Print Network [OSTI]

    Berning, Torsten

    Experimental Evaluation of a Pt-based Heat Exchanger Methanol Reformer for a HTPEM Fuel Cell Stack as e.g. methanol as the hydrogen carrier and reforming it to a hydrogen rich gas can solve some of these storage issues. The work presented here examines the use of a heat exchanger methanol reformer for use

  4. Evaluation of reformed methanol as an automotive engine fuel

    E-Print Network [OSTI]

    McCall, David M

    1983-01-01T23:59:59.000Z

    coal, oil shale, tar sands, and renewable resources [12], of which there are abundant supplies. Also, methanol could be distributed through the present fuel distribution network with some minor modifications. Hydrogen has also be investi- gated...

  5. A Novel Combustion Synthesis Preparation of CuO/ZnO/ZrO2/Pd for Oxidative Hydrogen Production from Methanol

    E-Print Network [OSTI]

    Mukasyan, Alexander

    A Novel Combustion Synthesis Preparation of CuO/ZnO/ZrO2/Pd for Oxidative Hydrogen Production from pre- pared via three combustion synthesis routes including volume combustion, impregnated substrate combustion, and so-called second wave impregnation combustion methods. These catalysts were characterized via

  6. Activation of catalysts for synthesizing methanol from synthesis gas

    DOE Patents [OSTI]

    Blum, David B. (108 Tall Oaks Dr., Wayne, NJ 07470); Gelbein, Abraham P. (45 Headley Rd., Morristown, NJ 07960)

    1985-01-01T23:59:59.000Z

    A method for activating a methanol synthesis catalyst is disclosed. In this method, the catalyst is slurried in an inert liquid and is activated by a reducing gas stream. The activation step occurs in-situ. That is, it is conducted in the same reactor as is the subsequent step of synthesizing methanol from a methanol gas stream catalyzed by the activated catalyst still dispersed in a slurry.

  7. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  8. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  9. Is Methanol the Transportation Fuel of the Future?

    E-Print Network [OSTI]

    Sperling, Daniel; DeLuchi, Mark A.

    1989-01-01T23:59:59.000Z

    in the U.S. were coal, oil shale, and biomass. Natural gas (produced from coal and oil shale, methanol produced frommethanol was rated below oil shale and other coal-liquid

  10. In Proc of Direct Methanol Fuel Cell Symposium, 199th Electrochem.l Soc. Mtg, Washington DC, 3/01.

    E-Print Network [OSTI]

    Wang, Chao-Yang

    In Proc of Direct Methanol Fuel Cell Symposium, 199th Electrochem.l Soc. Mtg, Washington DC, 3/01. MATHEMATICAL MODELING OF LIQUID-FEED DIRECT METHANOL FUEL CELLS Z. H. Wang and C. Y. Wang Electrochemical methanol fuel cells (DMFC). Diffusion and convection of both gas and liquid phases are considered

  11. Prediction of the Size Distributions of Methanol-Ethanol Clusters Detected in VUV Laser/Time-of-Flight Mass Spectrometry

    E-Print Network [OSTI]

    Goddard III, William A.

    Prediction of the Size Distributions of Methanol-Ethanol Clusters Detected in VUV Laser distributions and geometries of vapor clusters equilibrated with methanol-ethanol (Me-Et) liquid mixtures were distributions of vapor clusters equilibrated with liquids, ranging from neat alcohols1,2 to methanol-ethanol (Me

  12. Hydrogen Delivery Mark Paster

    E-Print Network [OSTI]

    Liquids (e.g. ethanol etc.) ­ Truck: HP Gas & Liquid Hydrogen ­ Regional Pipelines ­ Breakthrough Hydrogen;Delivery Key Challenges · Pipelines ­ Retro-fitting existing NG pipeline for hydrogen ­ Utilizing existing NG pipeline for Hythane with cost effective hydrogen separation technology ­ New hydrogen pipeline

  13. A New Reference Correlation for the Viscosity of Methanol Hong Wei Xiang,a...

    E-Print Network [OSTI]

    Magee, Joseph W.

    A New Reference Correlation for the Viscosity of Methanol Hong Wei Xiang,a... Arno Laesecke for the viscosity of methanol is presented that is valid over the entire fluid region, including vapor, liquid coefficient is developed from experimental data and applied to methanol. The high-density contribution

  14. Performance modeling and cell design for high concentration methanol fuel cells

    E-Print Network [OSTI]

    Chapter 50 Performance modeling and cell design for high concentration methanol fuel cells C. E The direct methanol fuel cell (DMFC) has become a lead- ing contender to replace the lithium-ion (Li density of liquid methanol (CH3OH) fuel is 4800 Wh l-1 , whereas the theoretical energy density of Li

  15. The effect of methanol concentration on the performance of a passive DMFC

    E-Print Network [OSTI]

    Zhao, Tianshou

    The effect of methanol concentration on the performance of a passive DMFC J.G. Liu, T.S. Zhao *, R-breathing liquid feed direct methanol fuel cell (DMFC), with no external pumps or other auxiliary devices, was designed, fabricated and tested with different methanol concentrations. It was found that the cell

  16. Electronic spectroscopy of intermediates involved in the conversion of methane to methanol by FeO

    E-Print Network [OSTI]

    Metz, Ricardo B.

    Electronic spectroscopy of intermediates involved in the conversion of methane to methanol by Fe.1063/1.1448489 I. INTRODUCTION The direct oxidation of methane to an easily transport- able liquid such as methanol process and as the simplest model for alkane oxidation.1,2 Although no direct, efficient methane­methanol

  17. PEM fuel cell stack performance using dilute hydrogen mixture. Implications on electrochemical engine system performance and design

    SciTech Connect (OSTI)

    Inbody, M.A.; Vanderborgh, N.E.; Hedstrom, J.C.; Tafoya, J.I. [Los Alamos National Lab., NM (United States)

    1996-12-31T23:59:59.000Z

    Onboard fuel processing to generate a hydrogen-rich fuel for PEM fuel cells is being considered as an alternative to stored hydrogen fuel for transportation applications. If successful, this approach, contrasted to operating with onboard hydrogen, utilizes the existing fuels infrastructure and provides required vehicle range. One attractive, commercial liquid fuels option is steam reforming of methanol. However, expanding the liquid methanol infrastructure will take both time and capital. Consequently technology is also being developed to utilize existing transportation fuels, such as gasoline or diesel, to power PEM fuel cell systems. Steam reforming of methanol generates a mixture with a dry gas composition of 75% hydrogen and 25% carbon dioxide. Steam reforming, autothermal reforming, and partial oxidation reforming of C{sub 2} and larger hydrocarbons produces a mixture with a more dilute hydrogen concentration (65%-40%) along with carbon dioxide ({approx}20%) and nitrogen ({approx}10%-40%). Performance of PEM fuel cell stacks on these dilute hydrogen mixtures will affect the overall electrochemical engine system design as well as the overall efficiency. The Los Alamos Fuel Cell Stack Test facility was used to access the performance of a PEM Fuel cell stack over the range of gas compositions chosen to replicate anode feeds from various fuel processing options for hydrocarbon and alcohol fuels. The focus of the experiments was on the anode performance with dilute hydrogen mixtures with carbon dioxide and nitrogen diluents. Performance with other anode feed contaminants, such as carbon monoxide, are not reported here.

  18. Are polar liquids less simple?

    E-Print Network [OSTI]

    D. Fragiadakis; C. M. Roland

    2012-08-28T23:59:59.000Z

    Strong correlation between equilibrium fluctuations of the potential energy, U, and the virial, W, is a characteristic of a liquid that implies the presence of certain dynamic properties, such as density scaling of the relaxation times and isochronal superpositioning of the relaxation function. In this work we employ molecular dynamics simulations (mds) on methanol and two variations, lacking hydrogen bonds and a dipole moment, to assess the connection between the correlation of U and W and these dynamic properties. We show, in accord with prior results of others [T.S. Ingebrigtsen, T.B. Schroder, J.C. Dyre, Phys. Rev. X 2, 011011 (2012).], that simple van der Waals liquids exhibit both strong correlations and the expected dynamic behavior. However, for polar liquids this correspondence breaks down - weaker correlation between U and W is not associated with worse conformance to density scaling or isochronal superpositioning. The reason for this is that strong correlation between U and W only requires their proportionality, whereas the expected dynamic behavior depends primarily on constancy of the proportionality constant for all state points. For hydrogen-bonded liquids, neither strong correlation nor adherence to the dynamic properties is observed; however, this nonconformance is not directly related to the concentration of hydrogen bonds, but rather to the greater deviation of the intermolecular potential from an inverse power law (IPL). Only (hypothetical) liquids having interactions governed strictly by an IPL are perfectly correlating and exhibit the consequent dynamic properties over all thermodynamic conditions.

  19. Thermally integrated staged methanol reformer and method

    DOE Patents [OSTI]

    Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

    2001-01-01T23:59:59.000Z

    A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

  20. Hydrogen Production from Methane Using Oxygen-permeable Ceramic Membranes

    E-Print Network [OSTI]

    Faraji, Sedigheh

    2010-06-08T23:59:59.000Z

    in the production of both fuel-cell quality hydrogen and ultra-clean liquid fuels (Fischer-Tropsch Synthesis), which are easier to transport and store than natural gas [6, 7]. The Fischer-Tropsch process has received significant attention in the quest to produce...:1 ratio of H2:CO which is beneficial to Fischer–Tropsch process and methanol synthesis [4]. Also, this reaction is exothermic which can reduce the overall hydrogen production plant cost [5]. CH4 + ˝ O2 ? CO + 2 H2...

  1. Optimal Simultaneous Production of Hydrogen and Liquid Fuels from Glycerol: Integrating the

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    . Keywords: Energy, Biofuels, Hydrogen, Alternative fuels, Diesel, Fisher ­ Tropsch 1 Corresponding author of oil (vegetal, cooking oil or the one obtained from microalgae (Martín & Grossmann, 2012), glycerol, biodiesel production requires energy (Martín & Grossmann, 2012). Therefore, this is another incentive

  2. Commercializing Light-Duty Plug-In/Plug-Out Hydrogen-Fuel-Cell Vehicles: "Mobile Electricity" Technologies, Early California Household Markets, and Innovation Management

    E-Print Network [OSTI]

    Williams, Brett D

    2010-01-01T23:59:59.000Z

    R. H. Williams, Solar hydrogen: moving beyond fossil fuels.J. S. Cannon, Harnessing Hydrogen: The Key to Sustainablefuel cell power systems hydrogen vs. methanol: a comparative

  3. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    vol. ) in Methanol Furnace , 2 , . . . . . . . . , . , .Velocity Profiles in Methanol Furnace Temperature Profiles:to Pure Methanol . . . . . . . . . . . . , . . . . C02

  4. Optimizing the Design of Biomass Hydrogen Supply Chains Using Real-World Spatial Distributions: A Case Study Using California Rice Straw

    E-Print Network [OSTI]

    Parker, Nathan C

    2007-01-01T23:59:59.000Z

    Costs to Estimate Hydrogen Pipeline Costs." Research ReportHydrogen Pipelines liquid hydrogen, and hydrogen pipelines. By limiting to a

  5. Optimizing the Design of Biomass Hydrogen Supply ChainsUsing Real-World Spatial Distributions: A Case Study Using California Rice Straw

    E-Print Network [OSTI]

    Parker, Nathan

    2007-01-01T23:59:59.000Z

    Costs to Estimate Hydrogen Pipeline Costs." Research ReportHydrogen Pipelines liquid hydrogen, and hydrogen pipelines. By limiting to a

  6. Reforming of Liquid Hydrocarbons in a Novel Hydrogen-Selective Membrane-Based Fuel Processor

    SciTech Connect (OSTI)

    Shamsuddin Ilias

    2006-03-10T23:59:59.000Z

    In this work, asymmetric dense Pd/porous stainless steel composite membranes were fabricated by depositing palladium on the outer surface of the tubular support. The electroless plating method combined with an osmotic pressure field was used to deposit the palladium film. Surface morphology and microstructure of the composite membranes were characterized by SEM and EDX. The SEM and EDX analyses revealed strong adhesion of the plated pure palladium film on the substrate and dense coalescence of the Pd film. Membranes were further characterized by conducting permeability experiments with pure hydrogen, nitrogen, and helium gases at temperatures from 325 to 450 C and transmembrane pressure differences from 5 to 45 psi. The permeation results showed that the fabricated membranes have both high hydrogen permeability and selectivity. For example, the hydrogen permeability for a composite membrane with a 20 {micro}m Pd film was 3.02 x 10{sup -5} moles/m{sup 2}.s.Pa{sup 0.765} at 450 C. Hydrogen/nitrogen selectivity for this composite membrane was 1000 at 450 C with a transmembrane pressure difference of 14.7 psi. Steam reforming of methane is one of the most important chemical processes in hydrogen and syngas production. To investigate the usefulness of palladium-based composite membranes in membrane-reactor configuration for simultaneous production and separation of hydrogen, steam reforming of methane by equilibrium shift was studied. The steam reforming of methane using a packed-bed inert membrane tubular reactor (PBIMTR) was simulated. A two-dimensional pseudo-homogeneous reactor model with parallel flow configuration was developed for steam reforming of methane. The shell volume was taken as the feed and sweep gas was fed to the inside of the membrane tube. Radial diffusion was taken into account for concentration gradient in the radial direction due to hydrogen permeation through the membrane. With appropriate reaction rate expressions, a set of partial differential equations was derived using the continuity equation for the reaction system and then solved by finite difference method with appropriate boundary and initial conditions. An iterative scheme was used to obtain a converged solution. Membrane reactor performance was compared to that in a traditional non-membrane packed-bed reactor (PBR). Their performances were also compared with thermodynamic equilibrium values achievable in a conventional non-membrane reactor. Numerical results of the models show that the methane conversions in the PBIMTR are always higher than that in the PBR, as well as thermodynamic equilibrium conversions. For instance, at a reaction pressure of 6 atm, a temperature of 650 C, a space velocity of 900/16.0 SCCM/gm{sub cat}, a steam to methane molar feed ratio of 3.0, a sweep ratio of 0.15, the conversion in the membrane reactor is about 86.5%, while the conversion in the non-membrane reactor is about 50.8%. The corresponding equilibrium conversion is about 56.4%. The effects on the degree of conversion and hydrogen yield were analyzed for different parameters such as temperature, reactor pressure, feed and sweep flow rate, feed molar ratio, and space time. From the analysis of the model results, it is obvious that the membrane reactor operation can be optimized for conversion or yield through the choice of proper operating and design parameters. Comparisons with available literature data for both membrane and non-membrane reactors showed a good agreement.

  7. Methanol and hydrogen from biomass for transportation

    E-Print Network [OSTI]

    . In the light of increasing air pollution in megacitites like Mexico City and SĂŁo Paulo [UNEP/WHO, 1992 for biomass to be used for road transportation, with zero or near-zero local air pollution and very low levels

  8. The production of methanol by the Brookhaven National Laboratory process

    SciTech Connect (OSTI)

    Miller, D.B.; Williams, J.J.; Johnson, A.R.

    1990-11-01T23:59:59.000Z

    The purpose of this study was to develop a capital cost estimate and methanol production costs for a new methanol process under development at the Brookhaven National Laboratory (BNL). The cost of fuel delivered to the US Gulf Coast is compared with fuel produced by a conventional methanol process and a liquefied natural gas (LNG) process. The new methanol process is made possible by the development of a new liquid phase catalyst. The new liquid catalyst system can convert synthesis gas almost completely to methanol in a SINGLE pass through the methanol synthesis reactor. This catalyst system reduces synthesis reaction temperatures from about 260{degree}C to about 100{degree}C, permitting isothermal synthesis conditions, in contrast to the temperature gradients in currently available pelleted, solid catalysts. Natural gas feedstock can be processed at pressures under 250 psia. Since nitrogen in the synthesis gas can be tolerated, the autothermal reforming step (combination of partial oxidation and steam reforming over a nickel catalyst) uses preheated air rather than oxygen. However, even with nitrogen present, the volume of gas fed to the reactor can still be smaller than the volume of gas that must be circulated in a conventional reactor, which operates with low conversions and requires high recycle volumes. The characteristics of the BNL system permits a major improvement in methanol plant design and economics. 11 figs., 15 tabs.

  9. Formation of Supercooled Liquid Solutions from Nanoscale Amorphous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supercooled Liquid Solutions from Nanoscale Amorphous Solid Films of Methanol and Ethanol. Formation of Supercooled Liquid Solutions from Nanoscale Amorphous Solid Films of...

  10. Mixing it up - Measuring diffusion in supercooled liquid solutions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mixing it up - Measuring diffusion in supercooled liquid solutions of methanol and ethanol at temperatures near the glass Mixing it up - Measuring diffusion in supercooled liquid...

  11. MTBE/methanol supply

    SciTech Connect (OSTI)

    Simmons, R.E.

    1986-05-01T23:59:59.000Z

    U.S. methanol production has become economically competitive with imports due to de-escalation of natural gas price from $3.07 mm Btu in January 1985 to $2.07 mm Btu by December 1985. This has reversed the earlier supply outlook when it appeared that additional methanol plants would shutdown due to low cost imports. Current gas cost in conjunction with projections for continued excess supply prompted DuPont to restart their 250 mm gpy plant at Beaumont, Texas. Other former producers are contemplating restarting idle units.

  12. Liquid Hydrogen Production and Delivery from a Dedicated Wind Power Plant |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetterEconomy and EmissionsDepartment of Energy Hydrogen

  13. Hydrogen Storage Systems Analysis Working Group Meeting Held in Conjunction with the

    E-Print Network [OSTI]

    an autothermal hydrogen storage and delivery concept using an organic liquid carrier for hydrogen. Joe Reiter

  14. Lifecycle Analysis of Air Quality Impacts of Hydrogen and Gasoline Transportation Fuel Pathways

    E-Print Network [OSTI]

    Wang, Guihua

    2008-01-01T23:59:59.000Z

    SMR production with gaseous hydrogen pipeline delivery, andhydrogen: gaseous hydrogen pipeline vs. liquid hydrogenproduction with gaseous hydrogen pipeline delivery systems;

  15. 4, 125164, 2007 Methanol exchange

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 125­164, 2007 Methanol exchange between grassland and the atmosphere A. Brunner et al. Title Discussions Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Methanol (albrecht.neftel@art.admin.ch) 125 #12;BGD 4, 125­164, 2007 Methanol exchange between grassland

  16. The Development of Methanol Industry and Methanol Fuel in China

    SciTech Connect (OSTI)

    Li, W.Y.; Li, Z.; Xie, K.C. [Taiyuan University of Technology, Taiyuan (China)

    2009-07-01T23:59:59.000Z

    In 2007, China firmly established itself as the driver of the global methanol industry. The country became the world's largest methanol producer and consumer. The development of the methanol industry and methanol fuel in China is reviewed in this article. China is rich in coal but is short on oil and natural gas; unfortunately, transportation development will need more and more oil to provide the fuel. Methanol is becoming a dominant alternative fuel. China is showing the rest of the world how cleaner transportation fuels can be made from coal.

  17. Methanol Reformer System Modeling and Control using an Adaptive Neuro-Fuzzy Inference System approach

    E-Print Network [OSTI]

    Andreasen, Sřren Juhl

    Methanol Reformer System Modeling and Control using an Adaptive Neuro-Fuzzy Inference System East, Denmark Introduction This work presents a control strategy for a reformed methanol fuel cell system, which uses a reformer to produce hydrogen for a HTPEM fuel cell. Such systems can advantageously

  18. Control of a methanol reformer system using an Adaptive NeuroFuzzy Inference System approach

    E-Print Network [OSTI]

    Andreasen, Sřren Juhl

    Control of a methanol reformer system using an Adaptive NeuroFuzzy Inference System approach, Denmark Introduction This work presents a stoichiometry control strategy for a reformed methanol fuel cell system, which uses a reformer to produce hydrogen for an HTPEM fuel cell. One such system is the Serenus

  19. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26T23:59:59.000Z

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  20. Questions and Issues on Hydrogen Pipeline Transmission of Hydrogen

    E-Print Network [OSTI]

    Questions and Issues on Hydrogen Pipelines Pipeline Transmission of Hydrogen Doe Hydrogen Pipeline Working Group Meeting August 31, 2005 #12;Pipeline Transmission of Hydrogen --- 2 Copyright: Air Liquide Transmission of Hydrogen --- 3 Copyright: #12;Pipeline Transmission of Hydrogen --- 4 Copyright: 3. Special

  1. The role of biomass in California's hydrogen economy

    E-Print Network [OSTI]

    Parker, Nathan C; Ogden, Joan; Fan, Yueyue

    2009-01-01T23:59:59.000Z

    Making a Business from Biomass in Energy, Environment,2004. An assessment of biomass resources in California.methanol and hydrogen from biomass. Journal of Power Sources

  2. H-D Substitution in Interstellar Solid Methanol: A Key Route for D Enrichment

    E-Print Network [OSTI]

    Akihiro Nagaoka; Naoki Watanabe; Akira Kouchi

    2005-03-28T23:59:59.000Z

    Deuterium enrichment of interstellar methanol is reproduced experimentally for the first time via grain-surface H-D substitution in solid methanol at an atomic D/H ratio of 0.1. Although previous gas-grain models successfully reproduce the deuterium enrichments observed in interstellar methanol molecules (D/H of up to 0.4, compared to the cosmic ratio of $\\sim 10^{-5})$, the models exclusively focus on deuterium fractionation resulting from the successive addition of atomic hydrogen/deuterium on CO. The mechanism proposed here represents a key route for deuterium enrichment that reproduces the high observed abundances of deuterated methanol, including multiple deuterations.

  3. The Methanol Economy Project

    SciTech Connect (OSTI)

    Olah, George; Prakash, G.K.

    2013-12-31T23:59:59.000Z

    The Methanol Economy Project is based on the concept of replacing fossil fuels with methanol generated either from renewable resources or abundant natural (shale) gas. The full methanol cycle was investigated in this project, from production of methanol through bromination of methane, bireforming of methane to syngas, CO{sub 2} capture using supported amines, co-electrolysis of CO{sub 2} and water to formate and syngas, decomposition of formate to CO{sub 2} and H{sub 2}, and use of formic acid in a direct formic acid fuel cell. Each of these projects achieved milestones and provided new insights into their respective fields. ? Direct electrophilic bromination of methane to methyl bromide followed by hydrolysis to yield methanol was investigated on a wide variety of catalyst systems, but hydrolysis proved impractical for large-scale industrial application. ? Bireforming the correct ratio of methane, CO{sub 2}, and water on a NiO / MgO catalyst yielded the right proportion of H{sub 2}:CO (2:1) and proved to be stable for at least 250 hours of operation at 400 psi (28 atm). ? CO{sub 2} capture utilizing supported polyethyleneimines yielded a system capable of adsorbing CO{sub 2} from the air and release at nominal temperatures with negligible amine leaching. ? CO{sub 2} electrolysis to formate and syngas showed considerable increases in rate and selectivity by performing the reaction in a high pressure flow electrolyzer. ? Formic acid was shown to decompose selectively to CO{sub 2} and H{sub 2} using either Ru or Ir based homogeneous catalysts. ? Direct formic acid fuel cells were also investigated and showed higher than 40% voltage efficiency using reduced loadings of precious metals. A technoeconomic analysis was conducted to assess the viability of taking each of these processes to the industrial scale by applying the data gathered during the experiments to approximations based on currently used industrial processes. Several of these processes show significant promise for industrial scale up and use towards improving our nation’s energy independence.

  4. Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters

    E-Print Network [OSTI]

    Kostko, Oleg

    2008-01-01T23:59:59.000Z

    Table 1 Appearance energies for pure and protonated methanoland methanol-water clusters evaluated from photoionizationVUV) photoionization of small methanol and methanol-water

  5. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

    1980-08-12T23:59:59.000Z

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  6. METHANOL AS A TRACER OF FUNDAMENTAL CONSTANTS

    SciTech Connect (OSTI)

    Levshakov, S. A. [A. F. Ioffe Physical-Technical Institute, Saint Petersburg 194021 (Russian Federation); Kozlov, M. G. [Petersburg Nuclear Physics Institute, Gatchina 188300 (Russian Federation); Reimers, D., E-mail: lev@astro.ioffe.rssi.ru, E-mail: mgk@mf1309.spb.edu, E-mail: st2e101@hs.uni-hamburg.de [Hamburger Sternwarte, Universitaet Hamburg, Gojenbergsweg 112, D-21029 Hamburg (Germany)

    2011-09-01T23:59:59.000Z

    The methanol molecule CH{sub 3}OH has a complex microwave spectrum with a large number of very strong lines. This spectrum includes purely rotational transitions as well as transitions with contributions of the internal degree of freedom associated with the hindered rotation of the OH group. The latter takes place due to the tunneling of hydrogen through the potential barriers between three equivalent potential minima. Such transitions are highly sensitive to changes in the electron-to-proton mass ratio, {mu} = m{sub e}/m{sub p}, and have different responses to {mu}-variations. The highest sensitivity is found for the mixed rotation-tunneling transitions at low frequencies. Observing methanol lines provides more stringent limits on the hypothetical variation of {mu} than ammonia observation with the same velocity resolution. We show that the best-quality radio astronomical data on methanol maser lines constrain the variability of {mu} in the Milky Way at the level of |{Delta}{mu}/{mu}| < 28 x 10{sup -9} (1{sigma}) which is in line with the previously obtained ammonia result, |{Delta}{mu}/{mu}| < 29 x 10{sup -9} (1{sigma}). This estimate can be further improved if the rest frequencies of the CH{sub 3}OH microwave lines will be measured more accurately.

  7. Methanol-reinforced kraft pulping

    SciTech Connect (OSTI)

    Norman, E.; Olm, L.; Teder, A. (STFI, Stockholm (Sweden))

    1993-03-01T23:59:59.000Z

    The addition of methanol to a high-sulfidity kraft cook on Scandinavian softwood chips was studied under different process conditions. Delignification and the degradation of carbohydrates were accelerated, but the effect on delignification was greater. Thus, methanol addition improved selectivity. The positive effect of methanol could also be observed for modified kraft cooks having a leveled out alkali concentration and lower concentration of sodium ions and dissolved lignin at the end of the cook. Methanol addition had no discernible effect on pulp strength or on pulp bleachability.

  8. MTBE, methanol prices rise

    SciTech Connect (OSTI)

    Morris, G.D.L.; Cornitius, T.

    1995-12-20T23:59:59.000Z

    After several months of drifting lower in line with declining autumn gasoline prices, tabs for methyl tert-butyl ether (MTBE) have turned around. There has been no big demand surge, but consumers and traders are beginning to build up inventories in advance of a series of midwinter shutdowns and turnarounds by producers. Spot prices, which dropped as low as 75 cts/gal, have rebounded to 90 cts/gal fob. Eager for a positive glimmer, methanol producers posted a 3-cts/gal increase in contract prices this month. It marks the first upward idea since February. In that time contract prices have dropped 75% from $1.55/gal to 39 cts/gal. A hard winter has hit early in much of the US sending natural gas prices up sharply. At the same time, formaldehyde and acetic acid markets remain firm, and with MTBE rebounding, methanol producers feel entitled to a piece of the action. {open_quotes}I don`t buy into this claim that MTBE demand is up and I don`t think producers can justify even a 3-cts/gal increase,{close_quotes} says one. {open_quotes}There is nothing in the economy to warrant a run-up. Housing starts are weaker, and demand is down at least 80,000 bbl/day with the MTBE shutdown.{close_quotes}

  9. EXPERIMENTAL STUDY OF A DIRECT METHANOL FUEL CELL M. M. Mench, S. Boslet, S. Thynell, J. Scott, and C.Y. Wang

    E-Print Network [OSTI]

    Wang, Chao-Yang

    EXPERIMENTAL STUDY OF A DIRECT METHANOL FUEL CELL M. M. Mench, S. Boslet, S. Thynell, J. Scott The Pennsylvania State University University Park, PA 16802 In this investigation, two 50cm2 direct methanol fuel in this area. INTRODUCTION The liquid-fed direct methanol fuel cell (DMFC) has received enormous interest

  10. Mechanistic Studies of Methanol Synthesis over Cu from CO/CO2/H2/H2O Mixtures: the Source of C in Methanol and the Role of Water

    SciTech Connect (OSTI)

    Yang, Yong; Mims, Charles A.; Mei, Donghai; Peden, Charles HF; Campbell, Charles T.

    2013-02-01T23:59:59.000Z

    The low temperature (403 – 453K) conversions of CO:hydrogen and CO2:hydrogen mixtures (6 bar total pressure) to methanol over copper catalysts are both assisted by the presence of small amounts of water (mole fraction ~0.04%-0.5%). For CO2:hydrogen reaction mixtures, the water product from both methanol synthesis and reverse water gas shift serves to initiate both reactions in an autocatalytic manner. In the case of CO:D2 mixtures, very little methanol is produced until small amounts of water are added. The effect of water on methanol production is more immediate than in CO2:D2, yet the steady state rates are similar. Tracer experiments in 13CO:12CO2:hydrogen (with or without added water), show that the dominant source of C in the methanol product gradually shifts from CO2 to CO as the temperature is lowered. Cu-bound formate, the major IR visible surface species under CO2:hydrogen, is not visible in CO:moist hydrogen. Though formate is visible in the tracer experiments, the symmetric stretch is absent. These results, in conjunction with recent DFT calculations on Cu(111), point to carboxyl as a common intermediate for both methanol synthesis and reverse water gas shift, with formate playing a spectator co-adsorbate role.

  11. Properties of a soft-core model of methanol: An integral equation theory and computer simulation study

    SciTech Connect (OSTI)

    Huš, Matej; Urbic, Tomaz, E-mail: tomaz.urbic@fkkt.uni-lj.si [Department of Chemistry and Chemical Technology, University of Ljubljana, Chair of Physical Chemistry, Ve?na pot 113, SI-1000 Ljubljana (Slovenia); Munaň, Gianmarco [Dipartimento di Fisica e di Scienze della Terra, Universitŕ degli Studi di Messina, Viale F. Stagno d'Alcontres 31, 98166 Messina (Italy)

    2014-10-28T23:59:59.000Z

    Thermodynamic and structural properties of a coarse-grained model of methanol are examined by Monte Carlo simulations and reference interaction site model (RISM) integral equation theory. Methanol particles are described as dimers formed from an apolar Lennard-Jones sphere, mimicking the methyl group, and a sphere with a core-softened potential as the hydroxyl group. Different closure approximations of the RISM theory are compared and discussed. The liquid structure of methanol is investigated by calculating site-site radial distribution functions and static structure factors for a wide range of temperatures and densities. Results obtained show a good agreement between RISM and Monte Carlo simulations. The phase behavior of methanol is investigated by employing different thermodynamic routes for the calculation of the RISM free energy, drawing gas-liquid coexistence curves that match the simulation data. Preliminary indications for a putative second critical point between two different liquid phases of methanol are also discussed.

  12. amine methanol, ether . Amine amine CO2

    E-Print Network [OSTI]

    Hong, Deog Ki

    IP [2012] 7 C O 2 (CO2) . CO2 amine methanol, ether . Amine amine CO2 CO2 .Amine CO2 (functional group) amine amine+ +promoter .Amine CO2 CO2 . . , methanol ether methanol, ether promoter CO2 CO2 H2S, COS CO2 . Methanol rectisol process, di-methylene ether polypropylene glycol selexol (-30oC) . CO2

  13. Indirect conversion of coal to methanol and gasoline: product price vs product slate

    SciTech Connect (OSTI)

    Wham, R.M.; McCracken, D.J.; Forrester, R.C. III

    1980-01-01T23:59:59.000Z

    The Oak Ridge National Laboratory (ORNL) conducts process analysis and engineering evaluation studies for the Department of Energy to provide, on a consistent basis, technical and economic assessments of processes and systems for coal conversion and utilization. Such assessments permit better understanding of the relative technical and economic potential of these processes. The objective of the work described here was to provide an assessment of the technical feasibility, economic competitiveness, and environmental acceptability of selected indirect coal liquefaction processes on a uniform, consistent, and impartial basis. Particular emphasis is placed on production of methanol as a principal product or methanol production for conversion to gasoline. Potential uses for the methanol are combustion in peaking-type turbines or blending with gasoline to yield motor fuel. Conversion of methanol to gasoline is accomplished through the use of the Mobil methanol-to-gasoline (MTG) process. Under the guidance of ORNL, Fluor Engineers and Constructors, Houston Division, prepared four conceptual process designs for indirect conversion of a Western subbituminous coal to either methanol or gasoline. The conceptual designs are based on the use of consistent technology for the core of the plant (gasification through methanol synthesis) with additional processing as necessary for production of different liquid products of interest. The bases for the conceptual designs are given. The case designations are: methanol production for turbine-grade fuel; methanol production for gasoline blending; gasoline production with coproduction of SNG; and gasoline production maximized.

  14. Low temperature catalyst system for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.

    1984-04-20T23:59:59.000Z

    This patent discloses a catalyst and process useful at low temperatures (150/sup 0/C) and preferably in the range 80 to 120/sup 0/C used in the production of methanol from carbon monoxide and hydrogen. The catalyst components are used in slurry form and comprise (1) a complex reducing agent derived from the component structure NaH-ROH-M(OAc)/sub 2/ where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1 to 6 carbon atoms and (2) a metal carbonyl of a group VI (Mo, Cr, W) metal. For the first component, Nic is preferred (where M = Ni and R = tertiary amyl). For the second component, Mo(CO)/sub 6/ is preferred. The mixture is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  15. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1986-09-30T23:59:59.000Z

    A catalyst and process useful at low temperatures (below about 160 C) and preferably in the range 80--120 C used in the production of methanol from carbon monoxide and hydrogen are disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa-M(OAc)[sub 2] where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1--6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M = Ni and R = tertiary amyl). Mo(CO)[sub 6] is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  16. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    Predictions B. Methanol/Coal Slurry as the Fuel TemperatureMETHANOL METHANOL / COAL SLURRY j i Ali. @ i o N I. . , .PURE N METHANOL METHANOL I COAL SLURRY u o Obb~~ ~~~~~~~~~~~

  17. A flow field enabling operating direct methanol fuel cells with highly concentrated methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    A flow field enabling operating direct methanol fuel cells with highly concentrated methanol Q. Xu Available online 8 October 2010 Keywords: Fuel cells Direct methanol fuel cells Concentrated methanol Flow field a b s t r a c t In this work, an anode flow field that allows a direct methanol fuel cell (DMFC

  18. Analysis of Mass Transport of Methanol at the Anode of a Direct Methanol Fuel Cell

    E-Print Network [OSTI]

    Zhao, Tianshou

    Analysis of Mass Transport of Methanol at the Anode of a Direct Methanol Fuel Cell C. Xu,a Y. L. He transport of methanol at the anode of a direct methanol fuel cell DMFC and show that the overall mass current density of an in-house-fabricated DMFC with different flow fields for various methanol

  19. Electron-Stimulated Reactions and O-2 Production in Methanol-Covered Amorphous Solid Water Films

    SciTech Connect (OSTI)

    Akin, Minta C.; Petrik, Nikolay G.; Kimmel, Gregory A.

    2009-03-14T23:59:59.000Z

    The low-energy, electron-stimulated desorption (ESD) of molecular products from amorphous solid water (ASW) films capped with methanol is investigated versus methanol coverage (0 - 4 x 1015 cm-2) at 50 K using 100 eV incident electrons. The major ESD products from a monolayer of methanol on ASW are quite similar to the ESD products from bulk methanol film: H2, CH4, H2O, C2H6, CO, CH2O, and CH3OH. For 40 ML ASW films, the molecular oxygen, hydrogen, and water ESD yields from the ASW are suppressed with increasing methanol coverage, while the CH3OH ESD yield increases proportionally to the methanol coverage. The suppression of the water ESD products by methanol is consistent with the non-thermal reactions occurring preferentially at or near the ASW/vacuum interface and not in the interior of the film. The water and molecular hydrogen ESD yields from the water layer decrease exponentially with the methanol cap coverage with 1/e constants of ~ 0.6 x 1015 cm-2 and 1.6 x 1015 cm-2, respectively. In contrast, the O2 ESD from the water layer is very efficiently quenched by small amounts of methanol (1/e ~ 6.5 x 1013 cm-2). The rapid suppression of O2 production by small amounts of methanol is due to reactions between CH3OH and the precursors for the O2 - mainly OH radicals. A kinetic model for the O2 ESD which semi-quantitatively accounts for the observations is presented.

  20. Measuring Diffusivity in Supercooled Liquid Nanoscale Films using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas has been shown to be an effective probe of the diffusivity of supercooled liquid methanol in the experimentally challenging regime near the glass transition temperature. The...

  1. Hydrogen Delivery Analysis Amgad Elgowainy (ANL), Marianne Mintz

    E-Print Network [OSTI]

    Hydrogen Truck Liquid Hydrogen Truck Terminal H2 Transmission Compressor H2 Forecourt Compressor HydrogenHydrogen Delivery Analysis Models Amgad Elgowainy (ANL), Marianne Mintz (ANL), Jerry Gillette (ANL Components Compressed Hydrogen Gas Truck (Tube trailer) Compressed Hydrogen Gas Truck Terminal Liquid

  2. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    Spectral Intensity With 5% Coal (x ::: 86.9 cm) CalculatedPredictions B. Methanol/Coal Slurry as the Fuel TemperatureMethanol as the Fuel B. Methanol/Coal Slurry as the Fuel C.

  3. Hydrogen refueling station costs in Shanghai

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Shaojun, Liu; Ogden, Joan M; Jianxin, Ma

    2007-01-01T23:59:59.000Z

    storing and transporting hydrogen. Golden, CO: NREL; 1998. [V. Survey of the economics of hydrogen technologies. Golden,liquid or gaseous form. Hydrogen can be produced from a va-

  4. Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters

    E-Print Network [OSTI]

    Ahmed, Musahid

    2008-01-01T23:59:59.000Z

    cyclic trimer containing two methanol molecules and a waterTable 1 Appearance energies for pure and protonated methanoland methanol-water clusters evaluated from photoionization

  5. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Desorption Kinetics of Methanol, Ethanol, and Water from Graphene. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene. Abstract: The desorption kinetics of methanol,...

  6. Methanol detection in M82

    E-Print Network [OSTI]

    S. Martín; J. Martín-Pintado; R. Mauersberger

    2006-03-07T23:59:59.000Z

    We present a multilevel study of the emission of methanol, detected for the first time in this galaxy, and discuss the origin of its emission. The high observed methanol abundance of a few 10^-9 can only be explained if injection of methanol from dust grains is taken into account. While the overall [CH3OH]/[NH3] ratio is much larger than observed towards other starbursts, the dense high excitation component shows a similar value to that found in NGC 253 and Maffei 2. Our observations suggest the molecular material in M 82 to be formed by dense warm cores, shielded from the UV radiation and similar to the molecular clouds in other starbursts, surrounded by a less dense photodissociated halo. The dense warm cores are likely the location of recent and future star formation within M 82.

  7. Distances to Galactic methanol masers

    E-Print Network [OSTI]

    K. L. J. Rygl; A. Brunthaler; K. M. Menten; M. J. Reid; H. J. van Langevelde

    2008-12-09T23:59:59.000Z

    We present the first EVN parallax measurements of 6.7 GHz methanol masers in star forming regions of the Galaxy. The 6.7 GHz methanol maser transition is a very valuable astrometric tool, for its large stability and confined velocity spread, which makes it ideal to measure proper motions and parallaxes. Eight well-studied massive star forming regions have been observed during five EVN sessions of 24 hours duration each and we present here preliminary results for five of them. We achieve accuracies of up to 51 $\\mu$as, which still have the potential to be proved by more ideal observational circumstances.

  8. Total pressure measurements for pentane + methanol + ethanol at 303. 15 K

    SciTech Connect (OSTI)

    Reimers, J.L.; Bhethanabotla, V.R.; Campbell, S.W. (Dept. of Chemical Engineering, Univ. of South Florida, Tampa, FL (US))

    1992-01-01T23:59:59.000Z

    In this paper total pressure is reported as a function of liquid-phase composition for pentane + methanol + ethanol at 303.15 K. The data were reduced using Barker's method. The excess Gibbs energy of the liquid phase is represented by a rational function obtained by making an empirical modification to the nonrandom two-liquid (NRTL) equation. The resulting fit to the data is superior to that obtained using a previous representation based on a modified Margules equation.

  9. Solid evacuated microspheres of hydrogen

    DOE Patents [OSTI]

    Turnbull, Robert J. (Urbana, IL); Foster, Christopher A. (Champaign, IL); Hendricks, Charles D. (Livermore, CA)

    1982-01-01T23:59:59.000Z

    A method is provided for producing solid, evacuated microspheres comprised of hydrogen. The spheres are produced by forming a jet of liquid hydrogen and exciting mechanical waves on the jet of appropriate frequency so that the jet breaks up into drops with a bubble formed in each drop by cavitation. The drops are exposed to a pressure less than the vapor pressure of the liquid hydrogen so that the bubble which is formed within each drop expands. The drops which contain bubbles are exposed to an environment having a pressure just below the triple point of liquid hydrogen and they thereby freeze giving solid, evacuated spheres of hydrogen.

  10. An Analysis of Near-Term Hydrogen Vehicle Rollout Scenarios for Southern California

    E-Print Network [OSTI]

    Nicholas, Michael A; Ogden, J

    2010-01-01T23:59:59.000Z

    Pressure Relief Device (PRD) Liquid Hydrogen Storage TankCompressed hydrogen storage Ambient-air vaporizer Liquidreactor (PSA) Compressed hydrogen storage Feed water pump

  11. Low Crossover of Methanol and Water Through Thin Membranes in Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Low Crossover of Methanol and Water Through Thin Membranes in Direct Methanol Fuel Cells Fuqiang State University, University Park, Pennsylvania 16802, USA Low crossover of both methanol and water through a polymer membrane in a direct methanol fuel cell DMFC is essential for using high concentration

  12. A sandwich structured membrane for direct methanol fuel cells operating with neat methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    A sandwich structured membrane for direct methanol fuel cells operating with neat methanol Q.X. Wu i g h t s " A sandwich structured membrane for DMFCs operating with neat methanol is proposed. " The membrane offers better water management for DMFCs operating with neat methanol. " The sandwich structured

  13. Uranium hexafluoride liquid thermal expansion, elusive eutectic with hydrogen fluoride, and very first production using chlorine trifluoride

    SciTech Connect (OSTI)

    Rutledge, G.P. [Central Environmental, Inc., Anchorage, AK (United States)

    1991-12-31T23:59:59.000Z

    Three unusual incidents and case histories involving uranium hexafluoride in the enrichment facilities of the USA in the late 1940`s and early 1950`s are presented. The history of the measurements of the thermal expansion of liquids containing fluorine atoms within the molecule is reviewed with special emphasis upon uranium hexafluoride. A comparison is made between fluorinated esters, fluorocarbons, and uranium hexafluoride. The quantitative relationship between the thermal expansion coefficient, a, of liquids and the critical temperature, T{sub c} is presented. Uranium hexafluoride has an a that is very high in a temperature range that is used by laboratory and production workers - much higher than any other liquid measured. This physical property of UF{sub 6} has resulted in accidents involving filling the UF{sub 6} containers too full and then heating with a resulting rupture of the container. Such an incident at a uranium gaseous diffusion plant is presented. Production workers seldom {open_quotes}see{close_quotes} uranium hexafluoride. The movement of UF{sub 6} from one container to another is usually trailed by weight, not sight. Even laboratory scientists seldom {open_quotes}see{close_quotes} solid or liquid UF{sub 6} and this can be a problem at times. This inability to {open_quotes}see{close_quotes} the UF{sub 6}-HF mixtures in the 61.2{degrees}C to 101{degrees}C temperature range caused a delay in the understanding of the phase diagram of UF{sub 6}-HF which has a liquid - liquid immiscible region that made the eutectic composition somewhat elusive. Transparent fluorothene tubes solved the problem both for the UF{sub 6}-HF phase diagram as well as the UF{sub 6}-HF-CIF{sub 3} phase diagram with a miscibility gap starting at 53{degrees}C. The historical background leading to the first use of CIF{sub 3} to produce UF{sub 6} in both the laboratory and plant at K-25 is presented.

  14. Methanol Masers and Star Formation

    E-Print Network [OSTI]

    A. M. Sobolev; A. B. Ostrovskii; M. S. Kirsanova; O. V. Shelemei; M. A. Voronkov; A. V. Malyshev

    2006-01-12T23:59:59.000Z

    Methanol masers which are traditionally divided into two classes provide possibility to study important parts of the star forming regions: Class~II masers trace vicinities of the massive YSOs while class~I masers are likely to trace more distant parts of the outflows where newer stars can form. There are many methanol transitions which produce observed masers. This allows to use pumping analysis for estimation of the physical parameters in the maser formation regions and its environment, for the study of their evolution. Extensive surveys in different masing transitions allow to conclude on the values of the temperatures, densities, dust properties, etc. in the bulk of masing regions. Variability of the brightest masers is monitored during several years. In some cases it is probably caused by the changes of the dust temperature which follow variations in the brightness of the central YSO reflecting the character of the accretion process. A unified catalogue of the class II methanol masers consisting of more than 500 objects is compiled. Analysis of the data shows that: physical conditions within the usual maser source vary considerably; maser brightness is determined by parameters of some distinguished part of the object - maser formation region; class II methanol masers are formed not within the outflows but in the regions affected by their propagation. It is shown that the "near" solutions for the kinematic distances to the sources can be used for statistical analysis. The luminosity function of the 6.7 GHz methanol masers is constructed. It is shown that improvement of the sensitivity of surveys can increase number of detected maser sources considerably.

  15. 6, 39453963, 2006 Methanol inside aged

    E-Print Network [OSTI]

    ACPD 6, 3945­3963, 2006 Methanol inside aged tropical biomass burning plumes G. Dufour et al. Title Chemistry and Physics Discussions First space-borne measurements of methanol inside aged tropical biomass. Dufour (gaelle.dufour@lmd.polytechnique.fr) 3945 #12;ACPD 6, 3945­3963, 2006 Methanol inside aged

  16. Micro Fuel Cells Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Micro Fuel Cells TM Direct Methanol Fuel Cells for Portable Power A Fuel Cell System Developer-17, 2002 Phoenix, Arizona #12;Micro Fuel Cells Direct Methanol Fuel Cells for Portable Power Outline (1 Energy Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Direct Methanol Fuel Cell Technology

  17. Resonant ion-dip infrared spectroscopy of benzene(methanol)m clusters R. Nathaniel Pribble, Fredrick C. Hagemeister, and Timothy S. Zwiera)

    E-Print Network [OSTI]

    Zwier, Timothy S.

    Resonant ion-dip infrared spectroscopy of benzene­(methanol)m clusters with m 1­6 R. Nathaniel bonding between benzene and methanol. The m 2 spectrum features two strong transitions at 3506 and 3605 cm in the absence of benzene, is redshifted by 76 cm 1 due to a strengthened hydrogen bond. In benzene­ CH3OH 3

  18. Hydrogen Production From Metal-Water Reactions

    E-Print Network [OSTI]

    Barthelat, Francois

    Hydrogen Production From Metal-Water Reactions Why Hydrogen Production? Hydrogen is a critical. Current methods of hydrogen storage in automobiles are either too bulky (large storage space for gas phase) or require a high input energy (cooling or pressurization systems for liquid hydrogen), making widespread use

  19. Emissions from two methanol-powered buses

    SciTech Connect (OSTI)

    Ullman, T.L.; Hare, C.T.; Baines, T.M.

    1986-01-01T23:59:59.000Z

    Emissions from the two methanol-powered buses used in the California Methanol Bus Demonstration have been characterized. The M.A.N. SU 240 bus is powered by M.A.N.'s D2566 FMUH methanol engine, and utilizes catalytic exhaust aftertreatment. The GMC RTS II 04 bus is powered by a first-generation DDAD 6V-92TA methanol engine without exhaust aftertreatment. Emissions of HC, CO, NO/subX/, unburned methanol, aldehydes, total particulates, and the soluble fraction of particulate were determined for both buses over steady-state and transient chassis dynamometer test cycles. Emission levels from the M.A.N. bus were considerably lower than those from the GMC bus, with the exception of NO/subX/. Comparison of emission levels from methanol-and diesel-powered buses indicates that substantial reductions in emissions are possible with careful implementation of methanol fueling.

  20. High specific power, direct methanol fuel cell stack

    DOE Patents [OSTI]

    Ramsey, John C. (Los Alamos, NM); Wilson, Mahlon S. (Los Alamos, NM)

    2007-05-08T23:59:59.000Z

    The present invention is a fuel cell stack including at least one direct methanol fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt penetrations and tie-bolts are spaced evenly around the perimeter to hold the fuel cell stack together. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet manifold with an integral flow restrictor to the outlet manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold. Located between the two plates is the fuel cell active region.

  1. Author's personal copy Photoelectrochemical hydrogen production from water/

    E-Print Network [OSTI]

    Wood, Thomas K.

    coal and gasoline [3]. Moreover, hydrogen can be used in fuel cells to generate electricity, or directly as a transportation fuel [4]. Hydrogen can be generated from hydrocarbons and water resourcesAuthor's personal copy Photoelectrochemical hydrogen production from water/ methanol decomposition

  2. Renewable Hydrogen Production Using Sugars and Sugar Alcohols...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Sugars and Sugar Alcohols (Presentation) Renewable Hydrogen Production Using Sugars and Sugar Alcohols (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen...

  3. Engineering Development of Ceramic Membrane Reactor System for Converting Natural Gas to Hydrogen and Synthesis Gas for Liquid Transportation Fuels

    SciTech Connect (OSTI)

    Air Products and Chemicals

    2008-09-30T23:59:59.000Z

    An Air Products-led team successfully developed ITM Syngas technology from the concept stage to a stage where a small-scale engineering prototype was about to be built. This technology produces syngas, a gas containing carbon monoxide and hydrogen, by reacting feed gas, primarily methane and steam, with oxygen that is supplied through an ion transport membrane. An ion transport membrane operates at high temperature and oxygen ions are transported through the dense membrane's crystal lattice when an oxygen partial pressure driving force is applied. This development effort solved many significant technical challenges and successfully scaled-up key aspects of the technology to prototype scale. Throughout the project life, the technology showed significant economic benefits over conventional technologies. While there are still on-going technical challenges to overcome, the progress made under the DOE-funded development project proved that the technology was viable and continued development post the DOE agreement would be warranted.

  4. Hydrogen Delivery- Current Technology

    Broader source: Energy.gov [DOE]

    Hydrogen is transported from the point of production to the point of use via pipeline, over the road in cryogenic liquid trucks or gaseous tube trailers, or by rail or barge. Read on to learn more about current hydrogen delivery and storage technologies.

  5. Hydrogen sulfide and carbon dioxide removal from dry fuel gas streams using an ionic liquid as a physical solvent

    SciTech Connect (OSTI)

    Yannick J. Heintz; Laurent Sehabiague; Badie I. Morsi; Kenneth L. Jones; David R. Luebke; Henry W. Pennline [United States Department of Energy (U.S. DOE), Pittsburgh, PA (United States). National Energy Technology Laboratory

    2009-09-15T23:59:59.000Z

    The mole fraction solubilities (x{asterisk}) and volumetric liquid-side mass-transfer coefficients (kLa) for H{sub 2}S and CO{sub 2} in the ionic liquid, TEGO IL K5, (a quaternary ammonium polyether) were measured under different pressures (up to 30 bar) and temperatures (up to 500 K) in a 4 L ZipperClave agitated reactor. CO{sub 2} and N{sub 2}, as single gases, and a H{sub 2}S/N{sub 2} gaseous mixture were used in the experiments. The solubilities of H{sub 2}S and CO{sub 2} were found to increase with pressure and decrease with temperature within the experimental conditions used. The H{sub 2}S solubilities in the ionic liquid (IL) were greater than those of CO{sub 2} within the temperature range investigated (300-500 K) up to a H{sub 2}S partial pressure of 2.33 bar. Hence, the IL can be effectively used to capture both H{sub 2}S and CO{sub 2} from dry fuel gas stream within the temperature range from 300 to 500 K under a total pressure up to 30 bar. The presence of H{sub 2}S in the H{sub 2}S/N{sub 2} mixture created mass-transfer resistance, which decreased k{sub L}{alpha} values for N{sub 2}. The k{sub L}{alpha} and x{asterisk} values of CO{sub 2} were found to be greater than those of N{sub 2} in the IL, which highlight the stronger selectivity of this physical solvent toward CO{sub 2} than toward N{sub 2}. In addition, within the temperature range from 300 to 500 K, the solubility and k{sub L}{alpha} of H{sub 2}S in the IL were greater than those of CO{sub 2}, suggesting that not only can H{sub 2}S be more easily captured from dry fuel gas streams but also a shorter absorber can be employed for H{sub 2}S capture than that for CO{sub 2}. 56 refs., 8 figs., 4 tabs.

  6. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1985-03-12T23:59:59.000Z

    A catalyst and process useful at low temperatures (below about 160/sup 0/C) and preferably in the range 80 to 120/sup 0/C used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH-RONa-M(OAc)/sub 2/ where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1 to 6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M = Ni and R = tertiary amyl). Mo(CO)/sub 6/ is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  7. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, Richard S. (1 Miller Ave., Shoreham, NY 11786); Slegeir, William A. (7 Florence Rd., Hampton Bays, NY 11946); O'Hare, Thomas E. (11 Geiger Pl., Huntington Station, NY 11746); Mahajan, Devinder (14 Locust Ct., Selden, NY 11784)

    1986-01-01T23:59:59.000Z

    A catalyst and process useful at low temperatures (below about 160.degree. C.) and preferably in the range 80.degree.-120.degree. C. used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa--M(OAc).sub.2 where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M=Ni and R=tertiary amyl). Mo(CO).sub.6 is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  8. Low temperature catalysts for methanol production

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; O'Hare, T.E.; Mahajan, D.

    1986-10-28T23:59:59.000Z

    A catalyst and process useful at low temperatures (below about 160 C) and preferably in the range 80--120 C used in the production of methanol from carbon monoxide and hydrogen are disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa-M(OAc)[sub 2] where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is NiC (where M = Ni and R = tertiary amyl). Mo(CO)[sub 6] is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.

  9. *sja@iet.aau.dkwww.iet.aau.dk Initial experiments with a Pt based heat exchanger methanol reformer for a HTPEM fuel cell system

    E-Print Network [OSTI]

    Andreasen, Sřren Juhl

    *sja@iet.aau.dkwww.iet.aau.dk Initial experiments with a Pt based heat exchanger methanol reformer, Pontoppidanstrćde 101, 9220 Aalborg East, Denmark Motivation Methanol Reformer Test Conclusions The use of a liquid reformed hydro- carbon as fuel for fuel cells can redu- ce fuel storage volume considerably. The PBI

  10. Liguid and Solid Carriers Group- Strategic Directions for Hydrogen Delivery Workshop

    Broader source: Energy.gov [DOE]

    Targets, barriers and research and development priorities for solid and liquid hydrogen storage and delivery materials.

  11. Hydrogen energy systems studies

    SciTech Connect (OSTI)

    Ogden, J.M.; Kreutz, T.G.; Steinbugler, M. [Princeton Univ., NJ (United States)] [and others

    1996-10-01T23:59:59.000Z

    In this report the authors describe results from technical and economic assessments carried out during the past year with support from the USDOE Hydrogen R&D Program. (1) Assessment of technologies for small scale production of hydrogen from natural gas. Because of the cost and logistics of transporting and storing hydrogen, it may be preferable to produce hydrogen at the point of use from more readily available energy carriers such as natural gas or electricity. In this task the authors assess near term technologies for producing hydrogen from natural gas at small scale including steam reforming, partial oxidation and autothermal reforming. (2) Case study of developing a hydrogen vehicle refueling infrastructure in Southern California. Many analysts suggest that the first widespread use of hydrogen energy is likely to be in zero emission vehicles in Southern California. Several hundred thousand zero emission automobiles are projected for the Los Angeles Basin alone by 2010, if mandated levels are implemented. Assuming that hydrogen vehicles capture a significant fraction of this market, a large demand for hydrogen fuel could evolve over the next few decades. Refueling a large number of hydrogen vehicles poses significant challenges. In this task the authors assess near term options for producing and delivering gaseous hydrogen transportation fuel to users in Southern California including: (1) hydrogen produced from natural gas in a large, centralized steam reforming plant, and delivered to refueling stations via liquid hydrogen truck or small scale hydrogen gas pipeline, (2) hydrogen produced at the refueling station via small scale steam reforming of natural gas, (3) hydrogen produced via small scale electrolysis at the refueling station, and (4) hydrogen from low cost chemical industry sources (e.g. excess capacity in refineries which have recently upgraded their hydrogen production capacity, etc.).

  12. Methods of conditioning direct methanol fuel cells

    DOE Patents [OSTI]

    Rice, Cynthia (Newington, CT); Ren, Xiaoming (Menands, NY); Gottesfeld, Shimshon (Niskayuna, NY)

    2005-11-08T23:59:59.000Z

    Methods for conditioning the membrane electrode assembly of a direct methanol fuel cell ("DMFC") are disclosed. In a first method, an electrical current of polarity opposite to that used in a functioning direct methanol fuel cell is passed through the anode surface of the membrane electrode assembly. In a second method, methanol is supplied to an anode surface of the membrane electrode assembly, allowed to cross over the polymer electrolyte membrane of the membrane electrode assembly to a cathode surface of the membrane electrode assembly, and an electrical current of polarity opposite to that in a functioning direct methanol fuel cell is drawn through the membrane electrode assembly, wherein methanol is oxidized at the cathode surface of the membrane electrode assembly while the catalyst on the anode surface is reduced. Surface oxides on the direct methanol fuel cell anode catalyst of the membrane electrode assembly are thereby reduced.

  13. Methanol in the L1551 Circumbinary Torus

    E-Print Network [OSTI]

    Glenn J. White; C. W. M. Fridlund; P. Bergman; A. Beardsmore; Rene Liseau; R. R. Phillips

    2006-09-25T23:59:59.000Z

    We report observations of gaseous methanol in an edge-on torus surrounding the young stellar object L1551 IRS5. The peaks in the torus are separated by ~ 10,000 AU from L1551 IRS5, and contain ~ 0.03 earth masses of cold methanol. We infer that the methanol abundance increases in the outer part of the torus, probably as a result of methanol evaporation from dust grain surfaces heated by the shock luminosity associated with the shocks associated with the jets of an externally located x-ray source. Any methanol released in such a cold environment will rapidly freeze again, spreading methanol throughout the circumbinary torus to nascent dust grains, planitesimals, and primitive bodies. These observations probe the initial chemical conditions of matter infalling onto the disk.

  14. Florida Hydrogen Initiative

    SciTech Connect (OSTI)

    Block, David L

    2013-06-30T23:59:59.000Z

    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring at any facility engaged in transport, handling and use of hydrogen. Development of High Efficiency Low Cost Electrocatalysts for Hydrogen Production and PEM Fuel Cell Applications ? M. Rodgers, Florida Solar Energy Center The objective of this project was to decrease platinum usage in fuel cells by conducting experiments to improve catalyst activity while lowering platinum loading through pulse electrodeposition. Optimum values of several variables during electrodeposition were selected to achieve the highest electrode performance, which was related to catalyst morphology. Understanding Mechanical and Chemical Durability of Fuel Cell Membrane Electrode Assemblies ? D. Slattery, Florida Solar Energy Center The objective of this project was to increase the knowledge base of the degradation mechanisms for membranes used in proton exchange membrane fuel cells. The results show the addition of ceria (cerium oxide) has given durability improvements by reducing fluoride emissions by an order of magnitude during an accelerated durability test. Production of Low-Cost Hydrogen from Biowaste (HyBrTec?) ? R. Parker, SRT Group, Inc., Miami, FL This project developed a hydrogen bromide (HyBrTec?) process which produces hydrogen bromide from wet-cellulosic waste and co-produces carbon dioxide. Eelectrolysis dissociates hydrogen bromide producing recyclable bromine and hydrogen. A demonstration reactor and electrolysis vessel was designed, built and operated. Development of a Low-Cost and High-Efficiency 500 W Portable PEMFC System ? J. Zheng, Florida State University, H. Chen, Bing Energy, Inc. The objectives of this project were to develop a new catalyst structures comprised of highly conductive buckypaper and Pt catalyst nanoparticles coated on its surface and to demonstrate fuel cell efficiency improvement and durability and cell cost reductions in the buckypaper based electrodes. Development of an Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program ? J. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cel

  15. Structure and dynamics of nonaqueous mixtures of dipolar liquids. II. Molecular dynamics simulations

    E-Print Network [OSTI]

    2000 Molecular dynamics simulations have been used to study mixtures of acetone/methanol, acetonitrile/ methanol, and acetone/acetonitrile over their entire composition range. Using the effective pair potentials in these two papers is on the nonaqueous dipolar liquid mixtures of acetone/methanol, acetonitrile

  16. Alternative Fuels Data Center: Methanol

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulaseFuels and VehiclesMethanol to someone by

  17. HYDROGEN USAGE AND STORAGE

    E-Print Network [OSTI]

    It is thought that it will be useful to inform society and people who are interested in hydrogen energy. The study below has been prepared due to this aim can be accepted as an article to exchange of information between people working on this subject. This study has been presented to reader to be utilized as a “technical note”. Main Energy sources coal, petroleum and natural gas are the fossil fuels we use today. They are going to be exhausted since careless usage in last decades through out the world, and human being is going to face the lack of energy sources in the near future. On the other hand as the fossil fuels pollute the environment makes the hydrogen important for an alternative energy source against to the fossil fuels. Due to the slow progress in hydrogen’s production, storage and converting into electrical energy experience, extensive usage of Hydrogen can not find chance for applications in wide technological practices. Hydrogen storage stands on an important point in the development of Hydrogen energy Technologies. Hydrogen is volumetrically low energy concentration fuel. Hydrogen energy, to meet the energy quantity necessary for the nowadays technologies and to be accepted economically and physically against fossil fuels, Hydrogen storage technologies have to be developed in this manner. Today the most common method in hydrogen storage may be accepted as the high pressurized composite tanks. Hydrogen is stored as liquid or gaseous phases. Liquid hydrogen phase can be stored by using composite tanks under very high pressure conditions. High technology composite material products which are durable to high pressures, which should not be affected by hydrogen embrittlement and chemical conditions.[1

  18. Hydrogen vehicle fueling station

    SciTech Connect (OSTI)

    Daney, D.E.; Edeskuty, F.J.; Daugherty, M.A.; Prenger, F.C.; Hill, D.D.

    1995-09-01T23:59:59.000Z

    The authors describe a hydrogen vehicle fueling station that receives and stores hydrogen in liquid form and dispenses it either as a liquid or compressed gas. The economics that accrue from the favorable weight and volume advantages of liquid hydrogen support this concept both now and probably for some time to come. The model for liquid transfer to a 120-liter vehicle tank shows that transfer times under five minutes are feasible with pump-assisted transfer, or for pressure transfer with subcooling greater than 1 K. The model for compressed gas transfer shows that underfilling of nearly 30% can occur during rapid filling. Cooling the fill gas to 214 K completely eliminates underfilling.

  19. Recovery of methanol in an MTBE process

    SciTech Connect (OSTI)

    Whisenhunt, D.E.; Byers, G.L.; Hattiangadi, U.S.

    1988-05-31T23:59:59.000Z

    In a process for the manufacture of methyltertiarybutylether (MTBE) in which methanol and a mixture of C/sub 4/ hydrocarbons containing isobutylene are contacted in a reaction zone containing an ion-exchange resin catalyst under suitable conditions to effect the reaction of methanol and isobutylene to produce a reaction product containing MTBE, unreacted methanol, unreacted isobutylene and other C/sub 4/ hydrocarbons, the reaction product is introduced to a fractionation zone wherein it is separated into a bottoms product comprising essentially MTBE and an overhead product containing unreacted methanol, unreacted isobutylene, and other C/sub 4/ hydrocarbons, and the overhead product is introduced to an absorption zone wherein the methanol is absorbed; the improvement is described which comprises utilizing silica gel as adsorbent and regenerating the silica gel adsorbent in a closed loop by contacting the silica gel absorbent with a desorption gas stream at an elevated temperature for a sufficient period of time to remove absorbed methanol, cooling the effluent from the adsorption zone to condense desorbed methanol removing desorbed methanol from the system and recycling the desorption gas to the adsorption zone.

  20. Methanol from biomass via steam gasification

    SciTech Connect (OSTI)

    Coffman, J.A. [Wright-Malta Corp., Ballston Spa, NY (United States)

    1995-12-31T23:59:59.000Z

    R&D at Wright-Malta on gasification of biomass, and use of this gas in methanol synthesis, has now reached the stage where a demonstration plant is feasible. The gasifier has evolved into a long, slender, slightly declined, graded temperature stationary kiln, with a box beam rotor and twin piston feed. The methanol reactor is envisioned as a smaller, more declined, graded temperature, water-filled kiln, with a multi-pipe rotor. Input to the demo plant will be 100 tons/day of green (45% water) wood chips; output will be 11,000 gal/day of methanol and 7500 lbs/hr of steam. The over-all biomass to methanol system is tightly integrated in its mechanical design to take full advantage of the reactivity of biomass under a slow, steady, steamy pressurized cook, and the biomass pyrolysis and methanol synthesis exotherms. This is expected to yield good energy efficiency, environmental attractiveness, and economical operation.

  1. A Theoretical Study of Methanol Oxidation Catalyzed by Isolated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methanol Oxidation Catalyzed by Isolated Vanadia Clusters Supported on the (101) Surface of Anatase. A Theoretical Study of Methanol Oxidation Catalyzed by Isolated Vanadia...

  2. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Presented at the Department of Energy Fuel Cell...

  3. Novel Materials for High Efficiency Direct Methanol Fuel Cells...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials for High Efficiency Direct Methanol Fuel Cells Novel Materials for High Efficiency Direct Methanol Fuel Cells Presented at the Department of Energy Fuel Cell Projects...

  4. Bifunctional Anode Catalysts for Direct Methanol Fuel Cells....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Anode Catalysts for Direct Methanol Fuel Cells. Bifunctional Anode Catalysts for Direct Methanol Fuel Cells. Abstract: Using the binding energy of OH* and CO* on close-packed...

  5. Hydrogen from Biomass by Autothermal Reforming

    Broader source: Energy.gov [DOE]

    Presentation by Lanny D. Schmidt at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  6. Site Competition During Coadsorption of Acetone with Methanol and Water on TiO2(110)

    SciTech Connect (OSTI)

    Shen, Mingmin; Henderson, Michael A.

    2011-08-02T23:59:59.000Z

    The competitive interaction between acetone and two solvent molecules (methanol and water) for surface sites on rutile TiO2(110) was studied using temperature programmed desorption (TPD). On a vacuum reduced TiO2(110) surface, which possessed ~5% oxygen vacancy sites, excess methanol displaced preadsorbed acetone molecules to weakly bound and physisorbed desorption states below 200 K, whereas acetone was stabilized to 250 K against displacement by methanol on an oxidized surface through formation of an acetone-diolate species. These behaviors of acetone differ from the competitive interactions between acetone and water in that acetone is less susceptible to displacement by water. Examination of acetone+methanol and acetone+water multilayer combinations shows that acetone is more compatible in water-ice films than in methanol-ice films, presumably because water has greater potential as a hydrogen-bond donor than does methanol. Acetone molecules displaced from the TiO2(110) surface by water are more likely to be retained in the near-surface region, having a greater opportunity to revisit the surface, than when methanol is used as a coadsorbate. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  7. Capacity additions ease tight methanol supply

    SciTech Connect (OSTI)

    Greek, B.F. (C and EN, Houston, TX (US))

    1988-10-03T23:59:59.000Z

    Two menthanol plants now in operation - one in the U.S., the other in Chile - will boost global supplies of methanol more than 375 million gal annually. This large capacity addition and smaller expansions in other parts of the world will exceed demand growth during 1988 and 1989, easing the squeeze on supplies. As the result of increased supplies, methanol prices could slip slightly in the fourth quarter. They are more likely to decline next year, however. The two plants, which started up in August, are owned and operated by Tenneco Oil Co. Processing and Marketing and by Cape Horn Methanol (CHM). The Tenneco plant, located in Pasadena, Tex., was restarted after a shutdown in 1982 when prices for methanol were low. It now is running at full capacity of 125 million gal per year. The plant uses the low-pressure process technology of Lurgi, reportedly requiring for feedstock and energy between 100,000 and 125,000 cu ft of methane per gallon. Global trade in methanol smooths out the supply and demand inconsistencies. Surging methanol demand in the U.S. and in Western Europe has been met by imports from areas where methanol production is most economical - that is, where natural gas is readily available and has no other application as high in value. Canada, Chile, and Trinidad are examples of those areas.

  8. Alkyl Chlorides as Hydrogen Bond Acceptors

    SciTech Connect (OSTI)

    Nadas, Janos I [ORNL; Vukovic, Sinisa [ORNL; Hay, Benjamin [ORNL

    2012-01-01T23:59:59.000Z

    To gain an understanding of the role of an alkyl chloride as a hydrogen bond acceptor, geometries and interaction energies were calculated at the MP2/aug-cc-pVDZ level of theory for complexes between ethyl chloride and representative hydrogen donor groups. The results establish that these donors, which include hydrogen cyanide, methanol, nitrobenzene, pyrrole, acetamide, and N-methylurea, form X-H {hor_ellipsis} Cl hydrogen bonds (X = C, N, O) of weak to moderate strength, with {Delta}E values ranging from -2.8 to -5.3 kcal/mol.

  9. Role of Water in Methanol Photochemistry on Rutile TiO2(110)

    SciTech Connect (OSTI)

    Shen, Mingmin; Henderson, Michael A.

    2012-08-07T23:59:59.000Z

    Photochemistry of the molecularly and dissociatively adsorbed forms of methanol on the vacuum-annealed rutile TiO2(110) surface was explored using temperature programmed desorption (TPD), both with and without coadsorbed water. Methoxy, and not methanol, was confirmed as the photochemically active form of adsorbed methanol on this surface. UV irradiation of methoxy-covered TiO2(110) lead to depletion of the methoxy coverage and formation of formaldehyde and a surface OH group. Coadsorbed water did not promote either molecular methanol photochemistry or thermal decomposition of methanol to methoxy. However, terminal OH groups (OHt), prepared by coadsorption of water and oxygen atoms, thermally converted molecularly adsorbed methanol to methoxy at 120 K, thus enabling photoactivity. While chemisorbed water molecules had no influence on methoxy photochemistry, water molecules hydrogen-bonded in the second layer to bridging oxygen (Obr) sites inhibited the methoxy photodecomposition to formaldehyde. From this we conclude that Obr sites accept protons from the hole-mediated conversion of methoxy to formaldehyde. These results provide new fundamental understanding of the hole-scavenging role of methanol in photochemical processes on TiO2-based materials and how water influences this photochemistry. This work was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle under contract DEAC05-76RL01830. The research was performed using EMSL, a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  10. Hydrogen passivation of Se and Te in AlSb M. D. McCluskey and E. E. Haller

    E-Print Network [OSTI]

    McCluskey, Matthew

    Hydrogen passivation of Se and Te in AlSb M. D. McCluskey and E. E. Haller Lawrence Berkeley observed local vibrational modes LVM's arising from DX-hydrogen complex in AlSb. Hydrogen was diffused into bulk AlSb:Se and AlSb:Te by annealing in sealed quartz ampoules with either hydrogen gas or methanol CH

  11. Total to withdraw from Qatar methanol - MTBE?

    SciTech Connect (OSTI)

    NONE

    1996-05-01T23:59:59.000Z

    Total is rumored to be withdrawing from the $700-million methanol and methyl tert-butyl ether (MTBE) Qatar Fuel Additives Co., (Qafac) project. The French company has a 12.5% stake in the project. Similar equity is held by three other foreign investors: Canada`s International Octane, Taiwan`s Chinese Petroleum Corp., and Lee Change Yung Chemical Industrial Corp. Total is said to want Qafac to concentrate on methanol only. The project involves plant unit sizes of 610,000 m.t./year of MTBE and 825,000 m.t./year of methanol. Total declines to comment.

  12. Methanol engine conversion feasibility study: Phase 1

    SciTech Connect (OSTI)

    Not Available

    1983-03-01T23:59:59.000Z

    This report documents the selection of the surface-assisted ignition technique to convert two-stroke Diesel-cycle engines to methanol fuel. This study was the first phase of the Florida Department of Transportation methanol bus engine development project. It determined both the feasibility and technical approach for converting Diesel-cycle engines to methanol fuel. State-of-the-art conversion options, associated fuel formulations, and anticipated performance were identified. Economic considerations and technical limitations were examined. The surface-assisted conversion was determined to be feasible and was recommended for hardware development.

  13. On the Fluctuations that Order and Frustrate Liquid Water

    E-Print Network [OSTI]

    Limmer, David

    2013-01-01T23:59:59.000Z

    the forces of hydrogen bonds to the properties of liquid andhydrogen bond network couples to the dynamically heterogeneous propertiesproperties of liquid water manifest how the strength of these hydrogen

  14. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Martin Chaplin

    2007-06-10T23:59:59.000Z

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

  15. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    involves the nature of the step whereby methanol and dimethyl ether (DME), both lacking B -hydrogens, undergo dehydration to form olefins. Chang and Silvestri argued against the formation of a primary methyl carbonium ion as an intermediate based... went on to propose the formation of the primary olefins from dimethyl ether via a trimethyl oxonium ion which is illustrated in Figure 5. The Stevens type rearrangement involving the methyl shift produces the first C-0 bond and has been suggested...

  16. Methanol Maser Polarization in W3(OH)

    E-Print Network [OSTI]

    W. H. T. Vlemmings; L. Harvey-Smith; R. J. Cohen

    2006-06-13T23:59:59.000Z

    We present the first 6.7 GHz methanol maser linear polarization map of the extended filamentary maser structure around the compact HII region W3(OH). The methanol masers show linear polarization up to 8 per cent and the polarization angles indicate a magnetic field direction along the North-South maser structure. The polarization angles are consistent with those measured for the OH masers, taking into account external Faraday rotation toward W3(OH), and confirm that the OH and methanol masers are found in similar physical conditions. Additionally we discuss the Zeeman splitting of the 6.7 GHz methanol transition and present an upper limit of ~22 mG for the magnetic field strength in the maser region. The upper limit is fully consistent with the field strengths derived from OH maser Zeeman splitting.

  17. Synthesis of MTBE during CO hydrogenation: Reaction sites required

    SciTech Connect (OSTI)

    Kazi, A.M.; Goodwin, J.G. Jr.; Marcelin, G.; Oukaci, R. [Univ. of Pittsburgh, PA (United States). Dept. of Chemical and Petroleum Engineering

    1995-03-01T23:59:59.000Z

    Synthesis of methyl tert-butyl ether (MTBE) during carbon monoxide (CO) hydrogenation has been studied with the following reaction schemes: (1) the addition of isobutylene during CO hydrogenation over metal catalysts active for methanol synthesis (Pd/SiO{sub 2} and Li-Pd/SiO{sub 2}) and (2) the addition of isobutylene during CO hydrogenation over a dual bed configuration consisting of Li-Pd/SiO{sub 2} and a zeolite (H-ZSM-5 or HY). The addition of isobutylene during methanol synthesis over the supported Pd catalysts indicated that MTBE cannot be formed on metal sites from a reaction of isobutylene with methanol precursors. However, addition of isobutylene to the syngas feed over a dual bed consisting of a methanol synthesis catalyst and an acid zeolite downstream of the methanol synthesis catalyst showed that MTBE can be synthesized during CO hydrogenation provided acid sites are available. In order to get higher conversions of methanol to MTBE, optimization of the acid catalyst and/or reaction conditions would be required to minimize formation of byproduct hydrocarbons.

  18. Mit Methanol iridiumkatalysiert C-C-Bindungen knpfen

    E-Print Network [OSTI]

    Meyer, Karsten

    Mit Methanol iridiumkatalysiert C-C-Bindungen knüpfen i Die Reaktivität von Methanol (1) beruht meist auf dem nucleophilen Sauerstoffatom. Obwohl Methanol industriell im Monsanto-Prozess carbo, dass Methanol iridiumkatalysiert leicht an Allene (2) addiert. Damit entstehen 2,2-disub- stituierte

  19. Vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters

    SciTech Connect (OSTI)

    Ahmed, Musahid; Ahmed, Musahid; Wilson, Kevin R.; Belau, Leonid; Kostko, Oleg

    2008-05-12T23:59:59.000Z

    In this work we report on thevacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuumultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH + (n=1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH)n(H2O)H + (n=2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH +, (CH 3OH)2 +, (CH3OH)nH + (n=1-9), and (CH 3OH)n(H2O)H + (n=2-9 ) as a function of photon energy. With an increase in the water content in the molecular beam, there is an enhancement of photoionization intensity for methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

  20. Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol-Water Clusters

    SciTech Connect (OSTI)

    Kostko, Oleg; Belau, Leonid; Wilson, Kevin R.; Ahmed, Musahid

    2008-04-24T23:59:59.000Z

    In this work, we report on the vacuum-ultraviolet (VUV) photoionization of small methanol and methanol-water clusters. Clusters of methanol with water are generated via co-expansion of the gas phase constituents in a continuous supersonic jet expansion of methanol and water seeded in Ar. The resulting clusters are investigated by single photon ionization with tunable vacuum-ultraviolet synchrotron radiation and mass analyzed using reflectron mass spectrometry. Protonated methanol clusters of the form (CH3OH)nH+(n = 1-12) dominate the mass spectrum below the ionization energy of the methanol monomer. With an increase in water concentration, small amounts of mixed clusters of the form (CH3OH n(H2O)H+ (n = 2-11) are detected. The only unprotonated species observed in this work are the methanol monomer and dimer. Appearance energies are obtained from the photoionization efficiency (PIE) curves for CH3OH+, (CH3OH)2+, (CH3OH)nH+ (n = 1-9), and (CH3OH)n(H2O)H+ (n = 2-9) as a function of photon energy. With an increasein the water content in the molecular beam, there is an enhancement of photoionization intensity for the methanol dimer and protonated methanol monomer at threshold. These results are compared and contrasted to previous experimental observations.

  1. Methanol-tolerant cathode catalyst composite for direct methanol fuel cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-09-05T23:59:59.000Z

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of Pt.sub.3Cr/C so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  2. Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-03-21T23:59:59.000Z

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  3. Methanol plant ship: Appendix. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1988-07-30T23:59:59.000Z

    The document is an appendix to the final report on a proposed methanol plant ship off of the coast of Trinidad. The document incorporates the results of the redetermination of capital required to implement the project. It also presents a revised cost analysis, with better accuracy, for the project. The projected operating revenues and revised expenses are also given. As a continuation of the information presented in the final report, the methanol market and proposed products are discussed in the report.

  4. Methanol synthesis in a trickle bed reactor

    E-Print Network [OSTI]

    Tjandra, Sinoto

    1992-01-01T23:59:59.000Z

    chemicals, which can not be synthesized directly and in high selectivity from synthesis gas (King and Grate, 1985). Methanol synthesis was first shown to be feasible by Mittash and Schneider (1913). In the 1920s, BASF introduced the first industrial... that illustrated a significant achievement in catalyst specificity because methanol is thermodynamically the least favorable product of all other products which can be synthesized from synthesis gas. The first industrial process developed by BASF in 1920s used a...

  5. Technology and economics of gas utilization: Methanol

    SciTech Connect (OSTI)

    Seddon, D.

    1994-12-31T23:59:59.000Z

    The paper reviews the current and emerging technology for the conversion of natural gas into methanol and assesses its impact on the production economics. Technologies of potential use for offshore developments of large gas reserves or associated gas are discussed. New technologies for the production of methanol synthesis-gas, such as autothermal reforming and GHR technology, are described and the economic advantages over conventional steam reforming are quantified. New methanol synthesis technology, such as slurry phase reactors, are outlined but appear to offer little advantage over conventional technology for offshore gas utilization. The purification of methanol for fuel and chemical grade product is outlined and the cost of transport presented. The data presented gives an overview of the production costs for production of methanol from large gas reserves (> 1Tcf, 25--35PJ/a) and smaller scale reserves (10--20MMscfd, 4--10PJ/a). The variation of the production cost of methanol with gas price indicates that the gas price is the principal economic consideration. However, adoption of new technology will improve production economics by an amount equivalent to an incremental gas cost of about $0.5/GJ. For gas reserves of low development cost, the adoption of new technology is not a prerequisite to economic viability.

  6. Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation September 2003 Hydrogen bond population dynamics are extricated with exceptional detail using ultrafast ( 50 of methanol­OD oligomers in CCl4 . Hydrogen bond breaking makes it possible to acquire data for times much

  7. Pd and Pd-Cu Alloy Deposited Nafion Membranes for Reduction of Methanol Crossover in Direct Methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    Pd and Pd-Cu Alloy Deposited Nafion Membranes for Reduction of Methanol Crossover in Direct Methanol Fuel Cells J. Prabhuram, T. S. Zhao,*,z Z. X. Liang, H. Yang, and C. W. Wong Department Kong, China To reduce methanol crossover in direct methanol fuel cells DMFCs , Nafion 115 membrane

  8. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System...

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen-from- Ethanol: A Distributed Production System Presented at the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting Laurel, Maryland Tuesday,...

  9. Hydrogen production from carbonaceous material

    DOE Patents [OSTI]

    Lackner, Klaus S.; Ziock, Hans J.; Harrison, Douglas P.

    2004-09-14T23:59:59.000Z

    Hydrogen is produced from solid or liquid carbon-containing fuels in a two-step process. The fuel is gasified with hydrogen in a hydrogenation reaction to produce a methane-rich gaseous reaction product, which is then reacted with water and calcium oxide in a hydrogen production and carbonation reaction to produce hydrogen and calcium carbonate. The calcium carbonate may be continuously removed from the hydrogen production and carbonation reaction zone and calcined to regenerate calcium oxide, which may be reintroduced into the hydrogen production and carbonation reaction zone. Hydrogen produced in the hydrogen production and carbonation reaction is more than sufficient both to provide the energy necessary for the calcination reaction and also to sustain the hydrogenation of the coal in the gasification reaction. The excess hydrogen is available for energy production or other purposes. Substantially all of the carbon introduced as fuel ultimately emerges from the invention process in a stream of substantially pure carbon dioxide. The water necessary for the hydrogen production and carbonation reaction may be introduced into both the gasification and hydrogen production and carbonation reactions, and allocated so as transfer the exothermic heat of reaction of the gasification reaction to the endothermic hydrogen production and carbonation reaction.

  10. I. INTRODUCTION A lot of studies show that hydrogen has a high

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to the plasma steam-reforming of various alcohols: methanol, ethanol and phenol. The plasma reactor vegetable or ethanol) H2 yields and energetic cost in function of hydrogen sources are presented. The non alcohols diluted in water have been studied in this paper: methanol, ethanol and phenol. The mole fractions

  11. Prediction of Transport Properties by Molecular Simulation: Methanol and Ethanol and their mixture

    E-Print Network [OSTI]

    Guevara-Carrion, Gabriela; Vrabec, Jadran; Hasse, Hans

    2009-01-01T23:59:59.000Z

    Transport properties of liquid methanol and ethanol are predicted by molecular dynamics simulation. The molecular models for the alcohols are rigid, non-polarizable and of united-atom type. They were developed in preceding work using experimental vapor-liquid equilibrium data only. Self- and Maxwell-Stefan diffusion coefficients as well as the shear viscosity of methanol, ethanol and their binary mixture are determined using equilibrium molecular dynamics and the Green-Kubo formalism. Non-equilibrium molecular dynamics is used for predicting the thermal conductivity of the two pure substances. The transport properties of the fluids are calculated over a wide temperature range at ambient pressure and compared with experimental and simulation data from the literature. Overall, a very good agreement with the experiment is found. For instance, the self-diffusion coefficient and the shear viscosity are predicted with average deviations of less 8% for the pure alcohols and 12% for the mixture. The predicted thermal...

  12. Electronic Effect in Methanol Dehydrogenation on Pt Surfaces: Potential Control during Methanol Electrooxidation

    E-Print Network [OSTI]

    Park, Byungwoo

    advanced insight into the design of an optimal catalyst as the anode for direct methanol fuel cells. SECTION: Energy Conversion and Storage; Energy and Charge Transport Fuel cells are promising alternative energy conversion. Polymer electrolyte membrane fuel cells (PEMFCs) and direct methanol fuel cells (DMFCs

  13. Membrane-less hydrogen bromine flow battery William A. Braff1

    E-Print Network [OSTI]

    Bazant, Martin Z.

    refined and optimized over several decades. More recently, a laminar flow fuel cell based on borohydride batteries [23, 27], as well as methanol [25], formic acid [24], and hydrogen fuel cells [29]. However, none

  14. Autothermal hydrogen storage and delivery systems

    DOE Patents [OSTI]

    Pez, Guido Peter (Allentown, PA); Cooper, Alan Charles (Macungie, PA); Scott, Aaron Raymond (Allentown, PA)

    2011-08-23T23:59:59.000Z

    Processes are provided for the storage and release of hydrogen by means of dehydrogenation of hydrogen carrier compositions where at least part of the heat of dehydrogenation is provided by a hydrogen-reversible selective oxidation of the carrier. Autothermal generation of hydrogen is achieved wherein sufficient heat is provided to sustain the at least partial endothermic dehydrogenation of the carrier at reaction temperature. The at least partially dehydrogenated and at least partially selectively oxidized liquid carrier is regenerated in a catalytic hydrogenation process where apart from an incidental employment of process heat, gaseous hydrogen is the primary source of reversibly contained hydrogen and the necessary reaction energy.

  15. Effect of the cathode gas diffusion layer on the water transport behavior and the performance of passive direct methanol fuel cells operating with neat methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    of passive direct methanol fuel cells operating with neat methanol Q.X. Wu, T.S. Zhao , W.W. Yang Department Direct methanol fuel cell Passive operation Neat methanol operation a b s t r a c t The passive operation of a direct methanol fuel cell with neat methanol requires the water that is pro- duced at the cathode

  16. Falling MTBE demand bursts the methanol bubble

    SciTech Connect (OSTI)

    Wiesmann, G.; Cornitius, T.

    1995-03-01T23:59:59.000Z

    Methanol spot markets in Europe and the US have been hit hard by weakening demand from methyl tert-butyl ether (MTBE) producers. In Europe, spot prices for domestic T2 product have dropped to DM620-DM630/m.t. fob from early-January prices above DM800/m.t. and US spot prices have slipped to $1.05/gal fob from $1.35/gal. While chemical applications for methanol show sustained demand, sharp methanol hikes during 1994 have priced MTBE out of the gasoline-additive market. {open_quotes}We`ve learned an important lesson. We killed [MTBE] applications in the rest of the world,{close_quotes} says one European methanol producer. Even with methanol currently at DM620/m.t., another manufacturer points out, MTBE production costs still total $300/m.t., $30/m.t. more than MTBE spot prices. Since late 1994, Europe`s 3.3-million m.t./year MTBE production has been cut back 30%.

  17. Methanol from biomass via steam gasification

    SciTech Connect (OSTI)

    Coffman, J.A. [Wright-Malta Corp., Ballston Spa, NY (United States)

    1995-12-31T23:59:59.000Z

    R & D at Wright-Malta on gasification of biomass, and use of this gas in methanol synthesis, has now reached the stage where a demonstration plant is feasible. The gasifier has evolved into a long, slender, slightly declined, graded temperature series of stationary kiln sections, with box beam rotors and twin piston feed. The methanol reactor is envisioned as a smaller, more declined, graded temperature, water-filled stationary kiln, with a multi-pipe rotor. Input to the demo plant will be 100 tons/day of green (45% water) wood chips; output is projected at 11,000 gal/day of methanol and 7500 lbs/hr of steam. The over-all biomass to methanol system is tightly integrated in its mechanical design to take full advantage of the reactivity of biomass under a slow, steady, steamy pressurized cook, and the biomass pyrolysis and methanol synthesis exotherms. This is expected to yield good energy efficiency, environmental attractiveness, and economical operation.

  18. Storage, generation, and use of hydrogen

    DOE Patents [OSTI]

    McClaine, Andrew W.; Rolfe, Jonathan L.; Larsen, Christopher A.; Konduri, Ravi K.

    2006-05-30T23:59:59.000Z

    A composition comprising a carrier liquid; a dispersant; and a chemical hydride. The composition can be used in a hydrogen generator to generate hydrogen for use, e.g., as a fuel. A regenerator recovers elemental metal from byproducts of the hydrogen generation process.

  19. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01T23:59:59.000Z

    vehicles except the methanol/fuel cell vehicle and the BPEVe estimates for the methanol/fuel cell vehicle are based onbiomass-derived methanol used in fuel cell vehicles. Several

  20. Production of hydrogen in non oxygen-evolving systems: co-produced hydrogen as a bonus in the photodegradation of organic pollutants and hydrogen sulfide

    SciTech Connect (OSTI)

    Sartoretti, C. Jorand; Ulmann, M.; Augustynski, J. (Electrochemistry Laboratory, Department of Chemistry, University of Geneva (CH)); Linkous, C.A. (Florida Solar Energy Center, University of Central Florida (US))

    2000-01-01T23:59:59.000Z

    This report was prepared as part of the documentation of Annex 10 (Photoproduction of Hydrogen) of the IEA Hydrogen Agreement. Subtask A of this Annex concerned photo-electrochemical hydrogen production, with an emphasis on direct water splitting. However, studies of non oxygen-evolving systems were also included in view of their interesting potential for combined hydrogen production and waste degradation. Annex 10 was operative from 1 March 1995 until 1 October 1998. One of the collaborative projects involved scientists from the Universities of Geneva and Bern, and the Federal Institute of Technology in Laussane, Switzerland. A device consisting of a photoelectrochemical cell (PEC) with a WO{sub 3} photoanode connected in series with a so-called Grazel cell (a dye sensitized liquid junction photovoltaic cell) was developed and studied in this project. Part of these studies concerned the combination of hydrogen production with degradation of organic pollutants, as described in Chapter 3 of this report. For completeness, a review of the state of the art of organic waste treatment is included in Chapter 2. Most of the work at the University of Geneva, under the supervision of Prof. J. Augustynski, was focused on the development and testing of efficient WO{sub 3} photoanodes for the photoelectrochemical degradation of organic waste solutions. Two types of WO{sub 3} anodes were developed: non transparent bulk photoanodes and non-particle-based transparent film photoanodes. Both types were tested for degradation and proved to be very efficient in dilute solutions. For instance, a solar-to-chemical energy conversion efficiency of 9% was obtained by operating the device in a 0.01M solution of methanol (as compared to about 4% obtained for direct water splitting with the same device). These organic compounds are oxidized to CO{sub 2} by the photocurrent produced by the photoanode. The advantages of this procedure over conventional electrolytic degradation are that much (an order of magnitude) less energy is required and that sunlight can be used directly. In the case of photoproduction of hydrogen, as compared to water splitting, feeding the anodic compartment of the PEC with an organic pollutant, instead of the usual supporting electrolyte, will bring about a substantial increase of the photocurrent at a given illumination. Thus, the replacement of the photo-oxidation of water by the photodegradation of organic waste will be accompanied by a gain in solar-to-chemical conversion efficiency and hence by a decrease in the cost of the photoproduced hydrogen. Taking into account the benefits and possible revenues obtainable by the waste degradation, this would seem to be a promising approach to the photoproduction of hydrogen. Hydrogen sulfide (H{sub 2}S) is another waste effluent requiring extensive treatment, especially in petroleum refineries. The so-called Claus process is normally used to convert the H{sub 2}S to elemental sulfur. A sulfur recovery process developed at the Florida Solar Energy Center is described briefly in Chapter 4 by Dr. C. Linkous as a typical example of the photoproduction of hydrogen in a non oxygen-evolving system. The encouraging results obtained in these investigations of photoelectrochemical hydrogen production combined with organic waste degradation, have prompted a decision to continue the work under the new IEA Hydrogen Agreement Annex 14, Photoelectrolytic Hydrogen Production.

  1. Comparison of Methanol Exposure Routes Reported to Texas Poison Control Centers

    E-Print Network [OSTI]

    Givens, Melissa; Kalbfleisch, Kristine; Bryson, Scott

    2008-01-01T23:59:59.000Z

    guidelines on the treatment of methanol poisoning, J ToxicolHantson PE, Acute methanol intoxication: physiopathology,The toxicity of inhaled methanol vapors, Crit Rev Toxicol.

  2. Methanol sensor operated in a passive mode

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    A sensor outputs a signal related to a concentration of methanol in an aqueous solution adjacent the sensor. A membrane electrode assembly (MEA) is included with an anode side and a cathode side. An anode current collector supports the anode side of the MEA and has a flow channel therethrough for flowing a stream of the aqueous solution and forms a physical barrier to control access of the methanol to the anode side of the MEA. A cathode current collector supports the cathode side of the MEA and is configured for air access to the cathode side of the MEA. A current sensor is connected to measure the current in a short circuit across the sensor electrodes to provide an output signal functionally related to the concentration of methanol in the aqueous solution.

  3. Praxair extending hydrogen pipeline in Southeast Texas

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    This paper reports that Praxair Inc., an independent corporation created by the spinoff of Union Carbide Corp.'s Linde division, is extending its high purity hydrogen pipeline system from Channelview, Tex., to Port Arthur, Tex. The 70 mile, 10 in. extension begins at a new pressure swing adsorption (PSA) purification unit next to Lyondell Petrochemical Co.'s Channelview plant. The PSA unit will upgrade hydrogen offgas from Lyondell's methanol plant to 99.99% purity hydrogen. The new line, advancing at a rate of about 1 mile/day, will reach its first customer, Star Enterprise's 250,000 b/d Port Arthur refinery, in September.

  4. 37 GHz METHANOL MASERS : HORSEMEN OF THE APOCALYPSE FOR THE CLASS II METHANOL MASER PHASE?

    SciTech Connect (OSTI)

    Ellingsen, S. P.; Breen, S. L. [School of Mathematics and Physics, University of Tasmania, Private Bag 37, Hobart, TAS 7001 (Australia); Sobolev, A. M. [Astronomical Observatory, Ural Federal University, Lenin avenue 51, 620000 Ekaterinburg (Russian Federation); Voronkov, M. A.; Caswell, J. L. [CSIRO Astronomy and Space Science, Australia Telescope National Facility, P.O. Box 76, Epping, NSW 1710 (Australia); Lo, N., E-mail: Simon.Ellingsen@utas.edu.au [Departamento de Astronomia, Universidad de Chile, Camino El Observatorio 1515, Las Condes, Santiago, Casilla 36-D (Chile)

    2011-12-01T23:59:59.000Z

    We report the results of a search for class II methanol masers at 37.7, 38.3, and 38.5 GHz toward a sample of 70 high-mass star formation regions. We primarily searched toward regions known to show emission either from the 107 GHz class II methanol maser transition, or from the 6.035 GHz excited OH transition. We detected maser emission from 13 sources in the 37.7 GHz transition, eight of these being new detections. We detected maser emission from three sources in the 38 GHz transitions, one of which is a new detection. We find that 37.7 GHz methanol masers are only associated with the most luminous 6.7 and 12.2 GHz methanol maser sources, which in turn are hypothesized to be the oldest class II methanol sources. We suggest that the 37.7 GHz methanol masers are associated with a brief evolutionary phase (of 1000-4000 years) prior to the cessation of class II methanol maser activity in the associated high-mass star formation region.

  5. Methanex considers methanol, MTBE in Qatar

    SciTech Connect (OSTI)

    NONE

    1995-12-13T23:59:59.000Z

    CW has learned that Methanex Corp. is considering entering one of two methanol and methyl tert-butyl ether (MTBE) projects in Qatar. Executive v.p. Michael Wilson says that part of the company`s New Zealand plant could be moved to a site in Qatar, which would lower capital costs for the possible project by $75 million-$100 million. Both Qatar General Petroleum Corp. and Qatar Fuel Additives are developing methanol and MTBE projects at Umm Said, Qatar. Methanex says its goal is to ensure low-cost feedstocks.

  6. Electrolytic Hydrogen Evolution in DMFCs Induced by Oxygen Interruptions and Its Effect on Cell Performance

    E-Print Network [OSTI]

    Zhao, Tianshou

    - tem optimization and reliable operation of the fuel cell. Gas evolu- tion on the anode of a DMFC under flow field of a liquid-feed direct methanol fuel cell DMFC under open-circuit conditions after methanol fuel cells DMFCs are considered as one of the most competitive candidates for the future power

  7. Hydrogen sensor

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Cao, Wenqing (Katy, TX)

    2010-11-23T23:59:59.000Z

    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  8. Meeting Action Items and Highlights from the Bio-Derived Liquids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) & Hydrogen Production Technical Team Research Review Meeting Action Items and Highlights...

  9. Electron-Stimulated Reactions and O-2 Production in Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and O-2 Production in Methanol-Covered Amorphous Solid Water Films. Electron-Stimulated Reactions and O-2 Production in Methanol-Covered Amorphous Solid Water Films. Abstract: The...

  10. Experimental Investigation on the Interaction of Water and Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigation on the Interaction of Water and Methanol with Anatase-TiO2(101). Experimental Investigation on the Interaction of Water and Methanol with Anatase-TiO2(101). Abstract:...

  11. Site Competition During Coadsorption of Acetone with Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Site Competition During Coadsorption of Acetone with Methanol and Water on TiO2(110). Site Competition During Coadsorption of Acetone with Methanol and Water on TiO2(110)....

  12. Isotope effects in methanol synthesis and the reactivity of copper...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

  13. Level Alignment of a Prototypical Photocatalytic System: Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Level Alignment of a Prototypical Photocatalytic System: Methanol on TiO2(110). Level Alignment of a Prototypical Photocatalytic System: Methanol on TiO2(110). Abstract:...

  14. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts From CO2 to Methanol via Novel Nanocatalysts Print Wednesday, 03 December 2014 00:00 Researchers have found novel nanocatalysts that...

  15. Dehydrogenation of liquid fuel in microchannel catalytic reactor

    DOE Patents [OSTI]

    Toseland, Bernard Allen (Coopersburg, PA); Pez, Guido Peter (Allentown, PA); Puri, Pushpinder Singh (Emmaus, PA)

    2010-08-03T23:59:59.000Z

    The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

  16. Methanol Steam Reformer on a Silicon Wafer

    SciTech Connect (OSTI)

    Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

    2004-04-15T23:59:59.000Z

    A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

  17. Methanol emission from low mass protostars

    E-Print Network [OSTI]

    S. Maret; C. Ceccarelli; A. G. G. M. Tielens; E. Caux; B. Lefloch; A. Faure; A. Castets; D. R. Flower

    2005-07-15T23:59:59.000Z

    We present observations of methanol lines in a sample of Class 0 low mass protostars. Using a 1-D radiative transfer model, we derive the abundances in the envelopes. In two sources of the sample, the observations can only be reproduced by the model if the methanol abundance is enhanced by about two order of magnitude in the inner hot region of the envelope. Two other sources show similar jumps, although at a lower confidence level. The observations for the other three sources are well reproduced with a constant abundance, but the presence of a jump cannot be ruled out. The observed methanol abundances in the warm gas around low mass protostars are orders of magnitude higher than gas phase chemistry models predict. Hence, in agreement with other evidences, this suggest that the high methanol abundance reflects recent evaporation of ices due to the heating by the newly formed star. The observed abundance ratios of CH3 OH, H2 CO, and CO are in good agreement with grain surface chemistry models. However, the absolute abundances are more difficult to reproduce and may point towards the presence of multiple ice components in these regions.

  18. Re-Condensation and Liquefaction of Helium and Hydrogen Using Coolers

    E-Print Network [OSTI]

    Green, Michael A.

    2010-01-01T23:59:59.000Z

    AND LIQUEFACTION OF HELIUM AND HYDROGEN USING COOLERS M. A.liquefaction for helium and hydrogen can occur. KEYWORDS:each contain a liquid hydrogen absorber [4] that is cooled

  19. Methanol production from Eucalyptus wood chips. Final report

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-06-01T23:59:59.000Z

    This feasibility study includes all phases of methanol production from seedling to delivery of finished methanol. The study examines: production of 55 million, high quality, Eucalyptus seedlings through tissue culture; establishment of a Eucalyptus energy plantation on approximately 70,000 acres; engineering for a 100 million gallon-per-day methanol production facility; potential environmental impacts of the whole project; safety and health aspects of producing and using methanol; and development of site specific cost estimates.

  20. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    of NO and N02 in a Turbulent Propane/Air Di fusion Flame,"Fuel Methanol Ethanol Ethane Propane i so Octane n - Cetanestage of the secondary Propane, at A spark air line contains

  1. Dissociative recombination of protonated methanol W. D. Geppert,*a

    E-Print Network [OSTI]

    Millar, Tom

    Dissociative recombination of protonated methanol W. D. Geppert,*a M. Hamberg,a R. D. Thomas,a F. O located in Stockholm, Sweden. Analysis of the data yielded the result that formation of methanol or deuterated methanol accounted for only 3 and 6% of the total rate in CH3OH2 + and CD3OD2 + , respectively

  2. Fuel Cells Bulletin February 2005 Effect of methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    FEATURE Fuel Cells Bulletin February 2005 12 Effect of methanol concentration on passive DMFC performance The direct methanol fuel cell (DMFC) has attracted extensive interest from scientists energy density of methanol (6100 W h/kg at 25°C) is much higher than that of gaseous fuels.[1­6] Recently

  3. Competition between vitrification and crystallization of methanol at high pressure

    E-Print Network [OSTI]

    Vos, Willem L.

    Competition between vitrification and crystallization of methanol at high pressure Marco J. P methanol at high pressure up to 33 GPa at room temperature with x-ray diffraction, optical polarization and vitrification is observed when methanol is superpressed beyond the freezing pressure of 3.5 GPa: between 5

  4. Homogeneous Catalysis Selective Oxidation of Methane to Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    Homogeneous Catalysis Selective Oxidation of Methane to Methanol Catalyzed, with CŔH Activation (generated by dissolution[6] of Au2O3) react with methane at 1808C to selectively generate methanol (as a mixture of the ester and methanol) in high yield (Table 1, entries 1 and 2). As expected, the irreversible

  5. Bimetallic Cluster Provides a Higher Activity Electrocatalyst for Methanol Oxidation*

    E-Print Network [OSTI]

    Weidner, John W.

    Bimetallic Cluster Provides a Higher Activity Electrocatalyst for Methanol Oxidation* Brenda L:Ru nanoparticles on carbon (PtRu/C) for use as an electrocatalyst for methanol oxidation. This bimetallic carbonyl support particles. Cyclic voltammo- grams of methanol oxidation from the two catalysts showed

  6. Methanol maser survey using the EVN Anna Bartkiewicz

    E-Print Network [OSTI]

    van Langevelde, Huib Jan

    Methanol maser survey using the EVN Anna Bartkiewicz Centre for Astronomy, Nicolaus Copernicus-mail: langevelde@jive.nl We present the results of a five year campaign observing 6.7 GHz methanol masers towards a new type of masers. We discuss the origin of elliptically shaped methanol masers in massive star

  7. First satellite observations of lower tropospheric ammonia and methanol

    E-Print Network [OSTI]

    First satellite observations of lower tropospheric ammonia and methanol Reinhard Beer,1 Mark W) and methanol (CH3OH), well above the normal background levels. This is the first time that these molecules have. Citation: Beer, R., et al. (2008), First satellite observations of lower tropospheric ammonia and methanol

  8. Adsorption of intact methanol on Ru,,0001... Pawel Gazdzicki,1

    E-Print Network [OSTI]

    Adsorption of intact methanol on Ru,,0001... Pawel Gazdzicki,1 Per Uvdal,2 and Peter Jakob1,a 1 the adsorption of methanol on the clean Ru 0001 surface at T 80 K. Thereby, clear evidence for intact adsorption upon adsorption of methanol on Ru 0001 , even at low temperatures, as well as partial recombinative

  9. Effects of Methanol on the Retinal Function of Juvenile Rats

    E-Print Network [OSTI]

    Casanova, Christian

    Effects of Methanol on the Retinal Function of Juvenile Rats C. Plaziac1 , P. Lachapelle2 , C Received 18 April 2002; accepted 22 July 2002 Abstract We have investigated the effect of methanol exposure recorded prior to and up to 72 h after the administration of methanol. Data were compared to a control

  10. Molecular Dynamics of Methanol Monocation (CH3OH+ ) in Strong

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Molecular Dynamics of Methanol Monocation (CH3OH+ ) in Strong Laser Fields Bishnu Thapa and H surfaces of methanol neutral, monocation, and singlet and triplet dication were explored using the CBS in the presence of a 2.9 × 1014 W/cm2 800 nm laser field for methanol monocation on the ground state potential

  11. Determining the Lowest-Cost Hydrogen Delivery Mode

    E-Print Network [OSTI]

    Yang, Christopher; Ogden, Joan M

    2008-01-01T23:59:59.000Z

    liquid hydrogen pumps cost less than compressors. Further,hydrogen flow rate, though there are slight economies of scale associated with compressorhydrogen storage tanks are needed. Costs for central plant compressors

  12. Vapor-liquid equilibria prediction using a lattice theory of solutions

    E-Print Network [OSTI]

    Clinkscales, Thomas Albert

    1967-01-01T23:59:59.000Z

    OF TABLES TABLE I. Sum of the squares of the pressure residues for predicted pressures by rigid lattice solution model ?. . . . . . . . ?. . . . . . . . . . . . . . . . , . . PAGE 66 II. Types of interactions possible for alcohol- water system... function of liquid mole fraction for methanol-water at 59. 4oC. . . 12. Alcohol activity coefficient error curves for methanol-water at 59. 4 C. z=3, 12, 40. . . . . . . 13. Alcohol activity coefficient error curves for methanol-water at 59. 4 C. z=4...

  13. Site-site memory equation approach in study of density/pressure dependence of translational diffusion coefficient and rotational relaxation time of polar molecular solutions: acetonitrile in water, methanol in water, and methanol in acetonitrile

    E-Print Network [OSTI]

    Kobryn, A E; Hirata, F

    2005-01-01T23:59:59.000Z

    We present results of theoretical study and numerical calculation of the dynamics of molecular liquids based on combination of the memory equation formalism and the reference interaction site model - RISM. Memory equations for the site-site intermediate scattering functions are studied in the mode-coupling approximation for the first order memory kernels, while equilibrium properties such as site-site static structure factors are deduced from RISM. The results include the temperature-density(pressure) dependence of translational diffusion coefficients D and orientational relaxation times t for acetonitrile in water, methanol in water and methanol in acetonitrile, all in the limit of infinite dilution. Calculations are performed over the range of temperatures and densities employing the SPC/E model for water and optimized site-site potentials for acetonitrile and methanol. The theory is able to reproduce qualitatively all main features of temperature and density dependences of D and t observed in real and comp...

  14. VLE measurements of binary mixtures of methanol, ethanol, 2-methoxy-2-methylpropane, and 2-methoxy-2-methylbutane at 101.32 kPa

    SciTech Connect (OSTI)

    Arce, A.; Martinez-Ageitos, J.; Soto, A. [Univ. of Santiago de Compostela (Spain). Dept. of Chemical Engineering] [Univ. of Santiago de Compostela (Spain). Dept. of Chemical Engineering

    1996-07-01T23:59:59.000Z

    Isobaric vapor-liquid equilibrium data for 2-methoxy-2-methylpropane + methanol, 2-methoxy-2-methylpropane + ethanol, methanol + 2-methoxy-2-methylbutane, ethanol + 2-methoxy-2-methylbutane, and 2-methoxy-2-methylpropane + 2-methoxy-2-methylbutane were determined at 101.32 kPa. Fredenslund et al.`s test confirmed the results to be thermodynamically consistent. The VLE data were satisfactorily correlated using the Wilson, NRTL, and UNIQUAC equations for liquid phase activity coefficients and adequately predicted using the ASOG, UNIFAC, UNIFAC-Dortmund, and UNIFAC-Lyngby group contribution methods.

  15. Code for Hydrogen Hydrogen Pipeline

    E-Print Network [OSTI]

    #12;2 Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop Augusta, Georgia August development · Charge from BPTCS to B31 Standards Committee for Hydrogen Piping/Pipeline code development · B31.12 Status & Structure · Hydrogen Pipeline issues · Research Needs · Where Do We Go From Here? #12;4 Code

  16. Use of once-through treat gas to remove the heat of reaction in solvent hydrogenation processes

    DOE Patents [OSTI]

    Nizamoff, Alan J. (Convent Station, NJ)

    1980-01-01T23:59:59.000Z

    In a coal liquefaction process wherein feed coal is contacted with molecular hydrogen and a hydrogen-donor solvent in a liquefaction zone to form coal liquids and vapors and coal liquids in the solvent boiling range are thereafter hydrogenated to produce recycle solvent and liquid products, the improvement which comprises separating the effluent from the liquefaction zone into a hot vapor stream and a liquid stream; cooling the entire hot vapor stream sufficiently to condense vaporized liquid hydrocarbons; separating condensed liquid hydrocarbons from the cooled vapor; fractionating the liquid stream to produce coal liquids in the solvent boiling range; dividing the cooled vapor into at least two streams; passing the cooling vapors from one of the streams, the coal liquids in the solvent boiling range, and makeup hydrogen to a solvent hydrogenation zone, catalytically hydrogenating the coal liquids in the solvent boiling range and quenching the hydrogenation zone with cooled vapors from the other cooled vapor stream.

  17. Hydrogen Storage R&D Activities | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    liquid hydrogen storage, improved insulated-pressure vessels are being investigated. Materials research is focused on developing and evaluating advanced solid-state materials. In...

  18. Determining the lowest-cost hydrogen delivery mode

    E-Print Network [OSTI]

    Yang, Christopher; Ogden, Joan M

    2007-01-01T23:59:59.000Z

    liquid hydrogen pumps cost less than compressors. Further,and compressors have small-scale economies at this size range. Liquid hydrogenhydrogen ?ow rate, though there are slight economies of scale associated with compressor

  19. Direct Methanol Fuel Cell Prototype Demonstration for Consumer Electronics Applications

    SciTech Connect (OSTI)

    Carlstrom, Charles, M., Jr.

    2009-07-07T23:59:59.000Z

    This report is the final technical report for DOE Program DE-FC36-04GO14301 titled “Direct Methanol Fuel Cell Prototype Demonstration for Consumer Electronics Applications”. Due to the public nature of this report some of the content reported in confidential reports and meetings to the DOE is not covered in detail in this report and some of the content has been normalized to not show actual values. There is a comparison of the projects accomplishments with the objectives, an overview of some of the key subsystem work, and a review of the three levels of prototypes demonstrated during the program. There is also a description of the eventual commercial product and market this work is leading towards. The work completed under this program has significantly increased the understanding of how Direct Methanol Fuel Cells (DMFC) can be deployed successfully to power consumer electronic devices. The prototype testing has demonstrated the benefits a direct methanol fuel cell system has over batteries typically used for powering consumer electronic devices. Three generations of prototypes have been developed and tested for performance, robustness and life. The technologies researched and utilized in the fuel cell stack and related subsystems for these prototypes are leveraged from advances in other industries such as the hydrogen fueled PEM fuel cell industry. The work under this program advanced the state of the art of direct methanol fuel cells. The system developed by MTI micro fuel cells aided by this program differs significantly from conventional DMFC designs and offers compelling advantages in the areas of performance, life, size, and simplicity. The program has progressed as planned resulting in the completion of the scope of work and available funding in December 2008. All 18 of the final P3 prototypes builds have been tested and the results showed significant improvements over P2 prototypes in build yield, initial performance, and durability. The systems have demonstrated robust operation when tested at various orientations, temperatures, and humidity levels. Durability testing has progressed significantly over the course of the program. MEA, engine, and system level steady state testing has demonstrated degradation rates acceptable for initial product introduction. Test duration of over 5000 hrs has been achieved at both the MEA and breadboard system level. P3 level prototype life testing on engines (stacks with reactant conditioning) showed degradation rates comparable to carefully constructed lab fixtures. This was a major improvement over the P2 and P1 engine designs, which exhibited substantial reductions in life and performance between the lab cell and the actual engine. Over the course of the work on the P3 technology set, a platform approach was taken to the system design. By working in this direction, a number of product iterations with substantial market potential were identified. Although the main effort has been the development of a prototype charger for consumer electronic devices, multiple other product concepts were developed during the program showing the wide variety of potential applications.

  20. Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

  1. Hydrogen Safety

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet, intended for a non-technical audience, explains the basic properties of hydrogen and provides an overview of issues related to the safe use of hydrogen as an energy carrier.

  2. Hydrogen Analysis

    Broader source: Energy.gov (indexed) [DOE]

    A H2A: Hydrogen Analysis Margaret K. Mann DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program Systems Analysis Workshop July 28-29, 2004 Washington, D.C. H2A Charter...

  3. Photodissociation of organic molecules in star-forming regions, III. Methanol

    E-Print Network [OSTI]

    S. Pilling; R. Neves; A. C. F. Santos; H. M. Boechat-Roberty

    2006-12-15T23:59:59.000Z

    The presence of methyl alcohol or methanol (CH$_3$OH) in several astrophysical environments has been characterized by its high abundance that depends on both the production rate and the destruction rate. In the present work, the photoionization and photodissociation processes of methanol have been experimentally studied, employing soft X-ray photons (100-310 eV) from a toroidal grating monochromator (TGM) beamline of the Brazilian Synchrotron Light Laboratory (LNLS). Mass spectra were obtained using the photoelectron photoion coincidence (PEPICO) method. Kinetic energy distribution and abundances for each ionic fragment have been obtained from the analysis of the corresponding peak shapes in the mass spectra. Absolute photoionization and photodissociation cross sections were also determined. We have found, among the channels leading to ionization, about 11-16% of CH$_3$OH survive the soft X-rays photons. This behavior, together with an efficient formation pathways, may be associated with the high column density observed in star-forming regions. The three main photodissociation pathways are represented by COH$^+$ (or HCO$^+$) ion release (with ejection of H$_2$ + H), the dissociation via C-O bond rupture (with strong charge retention preferentially on the methyl fragment) and the ejection of a single energetic (2-4 eV) proton. Since methanol is very abundant in star forming regions, the produced protons could be an alternative route to molecular hydrogenation or a trigger for secondary dissociation processes or even to promote extra heating of the environment.

  4. Dynamic simulation of nuclear hydrogen production systems

    E-Print Network [OSTI]

    Ramírez Muńoz, Patricio D. (Patricio Dario)

    2011-01-01T23:59:59.000Z

    Nuclear hydrogen production processes have been proposed as a solution to rising CO 2 emissions and low fuel yields in the production of liquid transportation fuels. In these processes, the heat of a nuclear reactor is ...

  5. Integrated Short Contact Time Hydrogen Generator (SCPO)

    Broader source: Energy.gov [DOE]

    Presentation by Ke Liu, Gregg Deluga, Lanny Schmidt, and Ted Krause at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  6. Liquid-Liquid Extraction Processes

    E-Print Network [OSTI]

    Fair, J. R.; Humphrey, J. L.

    1983-01-01T23:59:59.000Z

    Liquid-liquid extraction is the separation of one or more components of a liquid solution by contact with a second immiscible liquid called the solvent. If the components in the original liquid solution distribute themselves differently between...

  7. Hydrogen Storage Technologies Hydrogen Delivery

    E-Print Network [OSTI]

    Hydrogen Storage Technologies Roadmap Hydrogen Delivery Technical Team Roadmap June 2013 #12;This). The Hydrogen Delivery Technical Team is one of 12 U.S. DRIVE technical teams ("tech teams") whose mission and clean advanced lightduty vehicles, as well as related energy infrastructure. For more information about

  8. Condensed hydrogen for thermonuclear fusion

    SciTech Connect (OSTI)

    Kucheyev, S. O.; Hamza, A. V. [Nanoscale Synthesis and Characterization Laboratory, Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)

    2010-11-15T23:59:59.000Z

    Inertial confinement fusion (ICF) power, in either pure fusion or fission-fusion hybrid reactors, is a possible solution for future world's energy demands. Formation of uniform layers of a condensed hydrogen fuel in ICF targets has been a long standing materials physics challenge. Here, we review the progress in this field. After a brief discussion of the major ICF target designs and the basic properties of condensed hydrogens, we review both liquid and solid layering methods, physical mechanisms causing layer nonuniformity, growth of hydrogen single crystals, attempts to prepare amorphous and nanostructured hydrogens, and mechanical deformation behavior. Emphasis is given to current challenges defining future research areas in the field of condensed hydrogens for fusion energy applications.

  9. Simultaneous MS-IR Studies of Surface Formate Reactivity Under Methanol Synthesis Conditions on Cu/SiO2

    SciTech Connect (OSTI)

    Yang, Yong; Mims, Charles A.; Disselkamp, Robert S.; Peden, Charles HF; Campbell, C. T.

    2009-06-09T23:59:59.000Z

    The coverages and surface lifetimes of copper-bound formates on Cu/SiO2 catalysts, and the steady-state rates of reverse water-gas shift and methanol synthesis have been measured simultaneously by mass (MS) and infrared (IR) spectroscopies under a variety of elevated pressure conditions at temperatures between 140 and 160°C. DCOO lifetimes under steady state catalytic conditions in CO2:D2 atmospheres were measured by 12C – 13C isotope transients (SSITKA). The values range from 220s at 160°C to 660s at 140°C. The catalytic rates of both reverse water gas shift (RWGS) and methanol synthesis are ~100-fold slower than this formate removal rate back to CO2+1/2 H2, and thus they do not significantly influence the formate lifetime or coverage at steady state. The formate coverage is instead determined by formate’s rapid production / decomposition equilibrium with gas phase CO2+H2. The results are consistent with formate being an intermediate in methanol synthesis, but with the rate-controlling step being after formate production (for example, its further hydrogenation to methoxy). A 2-3 fold shorter life time (faster decomposition rate) was observed for formate under reactions conditions when both D2 and CO2 are present than in pure Ar or D2+Ar alone, attributed to effects of coadsorbates (produced in D2 and CO2) on adsorbed formate reaction pathways. The carbon which appears in the methanol product spends a longer time on the surface than the formate species, 1.8 times as long at 140°C. The additional delay on the surface is attributed in part to readsorption of methanol on the catalyst, thus obscuring the mechanistic link between formate and methanol.

  10. Liquid-phase oxidation of anthracene by hydrogen peroxide in the presence of vanadium oxide bronzes Cu{sub x}V{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Men`shikov, S.Yu.; Vurasko, A.V.; Petrov, L.A.; Volkov, V.L.; Novoselova, A.A. [Inst. of Chemistry, Sverdlovsk (Russian Federation)

    1992-12-31T23:59:59.000Z

    Vanadium oxide bronzes of the general formula Cu{sub x}V{sub 2}O{sub 5}, where 0 liquid-phase oxidation of anthracene H{sub 2}O{sub 2}. The anthracene conversion and the selectivity with respect to anthraquinone are maximum within the region of {Beta}- and {Xi}-phases respectively close to the compositions Cu{sub 0.6} V{sub 2}O{sub 5} and Cu{sub 0.95}V{sub 2}O{sub 5}. This is connected with change in the electronic structure of the catalyst, which is a function of the copper content. 11 refs., 1 tab.

  11. Improved Direct Methanol Fuel Cell Stack

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM); Ramsey, John C. (Los Alamos, NM)

    2005-03-08T23:59:59.000Z

    A stack of direct methanol fuel cells exhibiting a circular footprint. A cathode and anode manifold, tie-bolt penetrations and tie-bolts are located within the circular footprint. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet and outlet cathode manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold, where the serpentine channels of the anode are orthogonal to the serpentine channels of the cathode. Located between the two plates is the fuel cell active region.

  12. advanced direct methanol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Direct Methanol Materials Science Websites Summary: increases the overall cost of the cell, reducing the fuel conversion efficiency. An alternative to H2): Application to...

  13. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse...

  14. Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    "Fuel Cells for Portable Power." Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Webinar Slides More Documents & Publications Novel Materials...

  15. Methanol Observation of IRAS 19312+1950: A Possible New Type of Class I Methanol Masers

    E-Print Network [OSTI]

    Nakashima, Jun-ichi; Salii, Svetlana V; Zhang, Yong; Yung, Bosco H K; Deguchi, Shuji

    2015-01-01T23:59:59.000Z

    We report the result of a systematic methanol observation toward IRAS 19312+1950. The properties of the SiO, H2O and OH masers of this object are consistent with those of mass-losing evolved stars, but some other properties are difficult to explain in the standard scheme of stellar evolution in its late stage. Interestingly, a tentative detection of radio methanol lines was suggested toward this object by a previous observation. To date, there are no confirmed detections of methanol emission towards evolved stars, so investigation of this possible detection is important to better understand the circumstellar physical/chemical environment of IRAS 19312+1950. In this study, we systematically observed multiple methanol lines of IRAS 19312+1950 in the lambda=3mm, 7mm, and 13mm bands, and detected 6 lines including 4 thermal lines and 2 class I maser lines. We derived basic physical parameters including kinetic temperature and relative abundances by fitting a radiative transfer model. According to the derived exci...

  16. Methanol production from eucalyptus wood chips. Attachment IV. Health and safety aspects of the eucalypt biomass to methanol energy system

    SciTech Connect (OSTI)

    Fishkind, H.H.

    1982-06-01T23:59:59.000Z

    The basic eucalyptus-to-methanol energy process is described and possible health and safety risks are identified at all steps of the process. The toxicology and treatment for exposure to these substances are described and mitigating measures are proposed. The health and safety impacts and risks of the wood gasification/methanol synthesis system are compared to those of the coal liquefaction and conversion system. The scope of this report includes the health and safety risks of workers (1) in the laboratory and greenhouse, where eucalyptus seedlings are developed, (2) at the biomass plantation, where these seedlings are planted and mature trees harvested, (3) transporting these logs and chips to the refinery, (4) in the hammermill, where the logs and chips will be reduced to small particles, (5) in the methanol synthesis plant, where the wood particles will be converted to methanol, and (6) transporting and dispensing the methanol. Finally, the health and safety risks of consumers using methanol is discussed.

  17. Improvements to Hydrogen Delivery Scenario Analysis

    E-Print Network [OSTI]

    Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM) and Results May 8, 2007 Amgad and storage are at or adjacent to Liquid Hydrogen (LH) TruckH2 Production 100 or 1500 kg/d Compressed H2 (CH) Truck H2 Production 3 or 7 kpsi 100 or 1500 kg/d H2 Production Gaseous H2 Pipeline 100 or 1500 kg

  18. Sandia National Laboratories: Hydrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Materials & Components Compatibility Hydrogen Behavior Quantitative Risk Assessment Hydrogen Infrastructure Solar Thermochemical Hydrogen Production Market Transformation...

  19. DOE Hydrogen Program Overview

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Program A Prospectus for Biological H 2 Production The Hydrogen Economy The hydrogen economy pertains to a world fundamentally different from the one we now know. Hydrogen...

  20. Shock compression of liquid helium and helium-hydrogen mixtures : development of a cryogenic capability for shock compression of liquid helium on Z, final report for LDRD Project 141536.

    SciTech Connect (OSTI)

    Lopez, Andrew J.; Knudson, Marcus D.; Shelton, Keegan P.; Hanson, David Lester

    2010-10-01T23:59:59.000Z

    This final report on SNL/NM LDRD Project 141536 summarizes progress made toward the development of a cryogenic capability to generate liquid helium (LHe) samples for high accuracy equation-of-state (EOS) measurements on the Z current drive. Accurate data on He properties at Mbar pressures are critical to understanding giant planetary interiors and for validating first principles density functional simulations, but it is difficult to condense LHe samples at very low temperatures (<3.5 K) for experimental studies on gas guns, magnetic and explosive compression devices, and lasers. We have developed a conceptual design for a cryogenic LHe sample system to generate quiescent superfluid LHe samples at 1.5-1.8 K. This cryogenic system adapts the basic elements of a continuously operating, self-regulating {sup 4}He evaporation refrigerator to the constraints of shock compression experiments on Z. To minimize heat load, the sample holder is surrounded by a double layer of thermal radiation shields cooled with LHe to 5 K. Delivery of LHe to the pumped-He evaporator bath is controlled by a flow impedance. The LHe sample holder assembly features modular components and simplified fabrication techniques to reduce cost and complexity to levels required of an expendable device. Prototypes have been fabricated, assembled, and instrumented for initial testing.

  1. Solar hydrogen energy system. Annual report, 1995--1996

    SciTech Connect (OSTI)

    Veziroglu, T.N.

    1996-12-31T23:59:59.000Z

    The paper reports progress on three tasks. Task A, System comparison of hydrogen with other alternative fuels in terms of EPACT requirements, investigates the feasibility of several alternative fuels, namely, natural gas, methanol, ethanol, hydrogen and electricity, to replace 10% of gasoline by the year 2000. The analysis was divided into two parts: analysis of vehicle technologies and analysis of fuel production, storage and distribution. Task B, Photovoltaic hydrogen production, involves this fuel production method for the future. The process uses hybrid solar collectors to generate dc electricity, as well as high temperature steam for input to the electrolyzer. During the first year, solar to hydrogen conversion efficiencies have been considered. The third task, Hydrogen safety studies, covers two topics: a review of codes, standards, regulations, recommendations, certifications, and pamphlets which address safety of gaseous fuels; and an experimental investigation of hydrogen flame impingement.

  2. Communication China's growing methanol economy and its implications for energy

    E-Print Network [OSTI]

    Jackson, Robert B.

    but scarce oil and natural gas. Adapting to such limitations, it has developed a chemical industry, with the rest coming from natural gas (Peng, 2011). Methanol is commonly used to produce formaldehyde, methylCommunication China's growing methanol economy and its implications for energy and the environment

  3. The Arecibo Methanol Maser Galactic Plane Survey--I: Data

    E-Print Network [OSTI]

    Jagadheep D. Pandian; Paul F. Goldsmith; Avinash A. Deshpande

    2007-02-06T23:59:59.000Z

    We present the results of an unbiased survey for 6.7 GHz methanol masers in the Galactic plane carried out using the 305 m Arecibo radio telescope. A total of 18.2 square degrees was surveyed with uniform sampling at 35.2 deg methanol masers are clustered, reflecting the formation of massive stars in clusters.

  4. Synthesis of Methanol and Dimethyl Ether from Syngas over Pd...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methanol and Dimethyl Ether from Syngas over PdZnOAl2O3 Catalysts. Synthesis of Methanol and Dimethyl Ether from Syngas over PdZnOAl2O3 Catalysts. Abstract: A PdZnOAl2O3...

  5. Importance of Diffusion in Methanol Photochemistry on TiO2(110...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Importance of Diffusion in Methanol Photochemistry on TiO2(110). Importance of Diffusion in Methanol Photochemistry on TiO2(110). Abstract: The photoactivity of methanol on the...

  6. Mechanistic Studies of Methanol Synthesis over Cu from CO/CO2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Methanol Synthesis over Cu from COCO2H2H2O Mixtures: the Source of C in Methanol and the Role of Water Mechanistic Studies of Methanol Synthesis over Cu from COCO2H2H2O...

  7. Understanding the effect of modifying elements in supported vanadia bilayered catalysts for methanol oxidation to formaldehyde

    E-Print Network [OSTI]

    Vining, William Collins

    2011-01-01T23:59:59.000Z

    Si Figure 1.1. Schematic of methanol oxidation over isolatedSiO 2 catalysts for methanol oxidation, 163-171, Copyright (rate constant at 550 K for methanol oxidation plotted versus

  8. Volume$3, number 3 CHEMICAL. PHYSICS LETTERS 1 Februrf 1978 INTERACTION OF METHANOL WITH RUTHENIUM

    E-Print Network [OSTI]

    Goodman, Wayne

    Volume$3, number 3 CHEMICAL. PHYSICS LETTERS 1 Februrf 1978 INTERACTION OF METHANOL WITH RUTHENIUM of methanol with a clean methods. Methanol dissociates upon adsorption at 300 K and yields Ha(g) and chemisorbed CO as the domiwt

  9. EFFECTS OF METAL-SUPPORT INTERACTIONS ON THE SYNTHESIS OF METHANOL OVER PALLADIUM

    E-Print Network [OSTI]

    Ryndin, Yu A.

    2013-01-01T23:59:59.000Z

    on the Synthesis of Methanol over Palladium by Yu. A.ABSTRACT The synthesis of methanol and other products fromThe specific activity for methanol synthesis decreased in

  10. Use of ionic liquids as coordination ligands for organometallic catalysts

    DOE Patents [OSTI]

    Li, Zaiwei (Moreno Valley, CA); Tang, Yongchun (Walnut, CA); Cheng; Jihong (Arcadia, CA)

    2009-11-10T23:59:59.000Z

    Aspects of the present invention relate to compositions and methods for the use of ionic liquids with dissolved metal compounds as catalysts for a variety of chemical reactions. Ionic liquids are salts that generally are liquids at room temperature, and are capable of dissolving a many types of compounds that are relatively insoluble in aqueous or organic solvent systems. Specifically, ionic liquids may dissolve metal compounds to produce homogeneous and heterogeneous organometallic catalysts. One industrially-important chemical reaction that may be catalyzed by metal-containing ionic liquid catalysts is the conversion of methane to methanol.

  11. Comparative costs and benefits of hydrogen vehicles

    SciTech Connect (OSTI)

    Berry, G.D. [Lawrence Livermore National Lab., CA (United States)

    1996-10-01T23:59:59.000Z

    The costs and benefits of hydrogen as a vehicle fuel are compared to gasoline, natural gas, and battery-powered vehicles. Costs, energy, efficiency, and tail-pipe and full fuel cycle emissions of air pollutants and greenhouse gases were estimated for hydrogen from a broad range of delivery pathways and scales: from individual vehicle refueling systems to large stations refueling 300 cars/day. Hydrogen production from natural gas, methanol, and ammonia, as well as water electrolysis based on alkaline or polymer electrolytes and steam electrolysis using solid oxide electrolytes are considered. These estimates were compared to estimates for competing fuels and vehicles, and used to construct oil use, air pollutant, and greenhouse gas emission scenarios for the U.S. passenger car fleet from 2005-2050. Fuel costs need not be an overriding concern in evaluating the suitability of hydrogen as a fuel for passenger vehicles. The combined emissions and oil import reduction benefits of hydrogen cars are estimated to be significant, valued at up to {approximately}$400/yr for each hydrogen car when primarily clean energy sources are used for hydrogen production. These benefits alone, however, become tenuous as the basis supporting a compelling rationale for hydrogen fueled vehicles, if efficient, advanced fossil-fuel hybrid electric vehicles (HEV`s) can achieve actual on-road emissions at or below ULEV standards in the 2005-2015 timeframe. It appears a robust rationale for hydrogen fuel and vehicles will need to also consider unique, strategic, and long-range benefits of hydrogen vehicles which can be achieved through the use of production, storage, delivery, and utilization methods for hydrogen which are unique among fuels: efficient use of intermittent renewable energy sources, (e,g, wind, solar), small-scale feasibility, fuel production at or near the point of use, electrolytic production, diverse storage technologies, and electrochemical conversion to electricity.

  12. A survey of processes for producing hydrogen fuel from different sources for automotive-propulsion fuel cells

    SciTech Connect (OSTI)

    Brown, L.F.

    1996-03-01T23:59:59.000Z

    Seven common fuels are compared for their utility as hydrogen sources for proton-exchange-membrane fuel cells used in automotive propulsion. Methanol, natural gas, gasoline, diesel fuel, aviation jet fuel, ethanol, and hydrogen are the fuels considered. Except for the steam reforming of methanol and using pure hydrogen, all processes for generating hydrogen from these fuels require temperatures over 1000 K at some point. With the same two exceptions, all processes require water-gas shift reactors of significant size. All processes require low-sulfur or zero-sulfur fuels, and this may add cost to some of them. Fuels produced by steam reforming contain {approximately}70-80% hydrogen, those by partial oxidation {approximately}35-45%. The lower percentages may adversely affect cell performance. Theoretical input energies do not differ markedly among the various processes for generating hydrogen from organic-chemical fuels. Pure hydrogen has severe distribution and storage problems. As a result, the steam reforming of methanol is the leading candidate process for on-board generation of hydrogen for automotive propulsion. If methanol unavailability or a high price demands an alternative process, steam reforming appears preferable to partial oxidation for this purpose.

  13. Mobil plans methanol plant in Nigeria

    SciTech Connect (OSTI)

    Alperowicz, N.

    1992-08-12T23:59:59.000Z

    Mobil Chemical (Houston) is in discussions with Nigerian National Petroleum Corp. (NNPC; Lagos) on a joint venture methanol plant at Port Harcourt, Nigeria. The U.S. firm has invited process owners to submit proposals for a 1-million m.t./year unit and hopes to select the technology by the end of this year. Three proposals have been submitted: Lurgi, offering its own low-pressure process; John Brown/Davy, with the ICI process; and M.W. Kellogg, proposing its own technology. Shareholding in the joint venture is yet to be decided, but it is likely to be a 50/50 tie-up. Marketing of Mobil's share or of the entire tonnage would be handled by Mobil Petrochemical International (Brussels). The plant could be onstream in late 1996.

  14. Role of Water in Methanol Photochemistry on Rutile TiO2(110)...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methanol photochemistry or thermal decomposition of methanol to methoxy. However, terminal OH groups (OHt), prepared by coadsorption of water and oxygen atoms, thermally...

  15. Geothermal hydrogen sulfide removal

    SciTech Connect (OSTI)

    Urban, P.

    1981-04-01T23:59:59.000Z

    UOP Sulfox technology successfully removed 500 ppM hydrogen sulfide from simulated mixed phase geothermal waters. The Sulfox process involves air oxidation of hydrogen sulfide using a fixed catalyst bed. The catalyst activity remained stable throughout the life of the program. The product stream composition was selected by controlling pH; low pH favored elemental sulfur, while high pH favored water soluble sulfate and thiosulfate. Operation with liquid water present assured full catalytic activity. Dissolved salts reduced catalyst activity somewhat. Application of Sulfox technology to geothermal waters resulted in a straightforward process. There were no requirements for auxiliary processes such as a chemical plant. Application of the process to various types of geothermal waters is discussed and plans for a field test pilot plant and a schedule for commercialization are outlined.

  16. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1993-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  17. Liquid chromatographic determination of water

    DOE Patents [OSTI]

    Fortier, N.E.; Fritz, J.S.

    1990-11-13T23:59:59.000Z

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present. 1 fig.

  18. Hydrogen as a fuel for fuel cell vehicles: A technical and economic comparison

    SciTech Connect (OSTI)

    Ogden, J.; Steinbugler, M.; Kreutz, T. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies

    1997-12-31T23:59:59.000Z

    All fuel cells currently being developed for near term use in vehicles require hydrogen as a fuel. Hydrogen can be stored directly or produced onboard the vehicle by reforming methanol, ethanol or hydrocarbon fuels derived from crude oil (e.g., Diesel, gasoline or middle distillates). The vehicle design is simpler with direct hydrogen storage, but requires developing a more complex refueling infrastructure. In this paper, the authors compare three leading options for fuel storage onboard fuel cell vehicles: compressed gas hydrogen storage; onboard steam reforming of methanol; onboard partial oxidation (POX) of hydrocarbon fuels derived from crude oil. Equilibrium, kinetic and heat integrated system (ASPEN) models have been developed to estimate the performance of onboard steam reforming and POX fuel processors. These results have been incorporated into a fuel cell vehicle model, allowing us to compare the vehicle performance, fuel economy, weight, and cost for various fuel storage choices and driving cycles. A range of technical and economic parameters were considered. The infrastructure requirements are also compared for gaseous hydrogen, methanol and hydrocarbon fuels from crude oil, including the added costs of fuel production, storage, distribution and refueling stations. Considering both vehicle and infrastructure issues, the authors compare hydrogen to other fuel cell vehicle fuels. Technical and economic goals for fuel cell vehicle and hydrogen technologies are discussed. Potential roles for hydrogen in the commercialization of fuel cell vehicles are sketched.

  19. Hydrogen Fueling Systems and Infrastructure

    E-Print Network [OSTI]

    ;Projects Hydrogen Infrastructure Development · Turnkey Commercial Hydrogen Fueling Station · Autothermal

  20. Novel Materials for High Efficiency Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Carson, Stephen; Mountz, David; He, Wensheng; Zhang, Tao

    2013-12-31T23:59:59.000Z

    Direct methanol fuel cell membranes were developed using blends of different polyelectrolytes with PVDF. The membranes showed complex relationships between polyelectrolyte chemistry, morphology, and processing. Although the PVDF grade was found to have little effect on the membrane permselectivity, it does impact membrane conductivity and methanol permeation values. Other factors, such as varying the polyelectrolyte polarity, using varying crosslinking agents, and adjusting the equivalent weight of the membranes impacted methanol permeation, permselectivity, and areal resistance. We now understand, within the scope of the project work completed, how these inter-related performance properties can be tailored to achieve a balance of performance.

  1. ICI and Penspen in Nigerian and Qatari methanol deals

    SciTech Connect (OSTI)

    Alperowicz, N.

    1992-03-11T23:59:59.000Z

    The U.K. consulting and engineering company Penspen Ltd. (London) has signed a second joint venture agreement in Qatar and has selected the ICI (London) methanol process. The technology will also be used in a world-scale methanol plant in Nigeria that Penspen is helping to set up. Under the first agreement, signed on January 1 with Qatar General Petroleum Corp. (QGPC), a 50/50 venture is being formed to build a $370-million, 2,000-m.t./day methanol plant at Umm Said. ICI will provide its low-pressure technology and help market 75% of the output. Completion is due late 1994.

  2. Method for low temperature catalytic production of hydrogen

    DOE Patents [OSTI]

    Mahajan, Devinder

    2003-07-22T23:59:59.000Z

    The invention provides a process for the catalytic production of a hydrogen feed by exposing a hydrogen feed to a catalyst which promotes a base-catalyzed water-gas-shift reaction in a liquid phase. The hydrogen feed can be provided by any process known in the art of making hydrogen gas. It is preferably provided by a process that can produce a hydrogen feed for use in proton exchange membrane fuel cells. The step of exposing the hydrogen feed takes place preferably from about 80.degree. C. to about 150.degree. C.

  3. Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

  4. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System

    Broader source: Energy.gov (indexed) [DOE]

    Cost Hydrogen-from- Ethanol: A Distributed Production System Presented at the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting Hilton Garden Inn...

  5. Pressure dependence of diffusion coefficient and orientational relaxation time for acetonitrile and methanol in water: DRISM/mode-coupling study

    E-Print Network [OSTI]

    Kobryn, A E; Hirata, F

    2005-01-01T23:59:59.000Z

    We present results of theoretical description and numerical calculation of the dynamics of molecular liquids based on the Reference Interaction Site Model / Mode-Coupling Theory. They include the temperature-pressure(density) dependence of the translational diffusion coefficients and orientational relaxation times for acetonitrile and methanol in water at infinite dilution. Anomalous behavior, i.e. the increase in mobility with density, is observed for the orientational relaxation time of methanol, while acetonitrile does not show any deviations from the usual. This effect is in qualitative agreement with the recent data of MD simulation and with experimental measurements, which tells us that presented theory is a good candidate to explain such kind of anomalies from the microscopical point of view and with the connection to the structure of the molecules.

  6. The Bumpy Road to Hydrogen

    E-Print Network [OSTI]

    Sperling, Dan; Ogden, Joan M

    2006-01-01T23:59:59.000Z

    gases (LPG) and compressed natural gas (CNG) have persistedbenefits from compressed natural gas, ethanol, methanol,

  7. Conceptual design study FY 1981: synfuels from fusion - using the tandem mirror reactor and a thermochemical cycle to produce hydrogen

    SciTech Connect (OSTI)

    Krikorian, O.H. (ed.)

    1982-02-09T23:59:59.000Z

    This report represents the second year's effort of a scoping and conceptual design study being conducted for the express purpose of evaluating the engineering potential of producing hydrogen by thermochemical cycles using a tandem mirror fusion driver. The hydrogen thus produced may then be used as a feedstock to produce fuels such as methane, methanol, or gasoline. The main objective of this second year's study has been to obtain some approximate cost figures for hydrogen production through a conceptual design study.

  8. Coadsorption of methanol and isobutene on HY zeolite

    SciTech Connect (OSTI)

    Kogelbauer, A.; Goodwin, J.G. Jr. [Univ. of Pittsburgh, PA (United States); Lercher, J.A. [Univ. of Twente, Enschede (Netherlands)

    1995-05-25T23:59:59.000Z

    In order to develop a better understanding of methyl tert-butyl ether (MTBE) synthesis on zeolites, the coadsorption of methanol and isobutene on HY zeolite was investigated using IR spectroscopy. Initial adsorption of isobutene alone at 35{degree}C led to rapid oligomerization yielding strongly bound oligomers. The subsequent coadsorption of methanol did not induce any changes in the zeolite-adsorbate complexes. TPD following the coadsorption showed that the Bronsted acid sites could be restored by temperature treatment above approximately 300{degree}C. When methanol was adsorbed first and isobutene was subsequently coadsorbed, MTBE was formed even at 35{degree}C on the catalyst surface. MTBE desorbed easily at a temperature of 70{degree}C, restoring a major fraction of the Bronsted acid sites. Methanol was concluded to decrease the probability of oligomerization by effectively competing for the acid sites. 34 refs., 6 figs.

  9. Methanol plant ship: implementation study. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1988-07-30T23:59:59.000Z

    The study compiled the economic, commercial and financing requirements of a floating plant ship with a production capacity of 3,000 tons of methanol a day. The raw material for the methanol production would be supplied from a natural gas reserve off the coast of Trinidad. The report has a separate section for each aspect of the plant ship project, such as methanol storage; logistics of transporting methanol to the United States; the required sub-sea installation to bring natural gas to the plant ship; and plant ship design and equipment. It gives a detailed description of a proposed organizational structure and its tax consequences. The project's financial requirements and economic impact are examined. The environmental consequences and other operator issues are analyzed. Tables and figures accompany the report.

  10. Characterization of Microexplosion Phenomena of Methanol-Glycerol Mixtures 

    E-Print Network [OSTI]

    Fan, Ge-Yi

    2014-07-17T23:59:59.000Z

    emissions even when combusting glycerol-based mixtures. In this research, microexplosion phenomena of methanol-in-glycerol mixtures have been studied using a high speed camera and an acoustic sensor system. A Fast Fourier Transform (FFT) algorithm has been...

  11. THE METHANOL MASER EMISSION IN W51 C.J. PHILLIPS1

    E-Print Network [OSTI]

    van Langevelde, Huib Jan

    THE METHANOL MASER EMISSION IN W51 C.J. PHILLIPS1 and H.J. VAN LANGEVELDE2 1 CSIRO; E-mail: chris.7-GHz methanol maser emission towards W51. In the W51 Main region, the bulk of the methanol is offset from an UCHII region. This probably indicates the methanol emission arises at the interface

  12. Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported on MCM-48

    E-Print Network [OSTI]

    Bell, Alexis T.

    Mechanistic Studies of Methanol Oxidation to Formaldehyde on Isolated Vanadate Sites Supported-1462 ReceiVed: August 16, 2006; In Final Form: October 10, 2006 The mechanism of methanol oxidation. Methanol reacts reversibly, at a ratio of approximately 1 methanol per V, with one V-O-Si to produce both V

  13. Ultrafast Carrier Dynamics in Exfoliated and Functionalized Calcium Niobate Nanosheets in Water and Methanol

    E-Print Network [OSTI]

    Osterloh, Frank

    and Methanol Elizabeth C. Carroll, Owen C. Compton, Dorte Madsen, Frank E. Osterloh, and Delmar S. Larsen-order kinetics on a sub-nanosecond time scale that depended on the nanosheet size. Methanol was used and methanol solutions. Methanol is known as an efficient sacrificial electron donor for layered metal oxide

  14. Author's personal copy Modeling of a passive DMFC operating with neat methanol

    E-Print Network [OSTI]

    Zhao, Tianshou

    Author's personal copy Modeling of a passive DMFC operating with neat methanol W.W. Yang, T.S. Zhao 2011 Keywords: Fuel cells Direct methanol fuel cells Neat methanol Mass transport Model a b s t r a c t A mathematical model is developed to simulate the fundamental transport phenomena in a passive direct methanol

  15. 6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS AND TRACERS OF GALACTIC

    E-Print Network [OSTI]

    Richardson Jr., James E.

    6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS AND TRACERS OF GALACTIC STRUCTURE A Dissertation Jagadheep Dhanasekara Pandian ALL RIGHTS RESERVED #12;6.7 GHZ METHANOL MASERS: PROPERTIES, ASSOCIATIONS transition of methanol is the strongest of methanol masers, and is the second strongest maser transition ever

  16. Design and Development of New Carbon-Based Sorbent Systems for an Effective Containment of Hydrogen

    SciTech Connect (OSTI)

    Alan C. Cooper

    2012-05-03T23:59:59.000Z

    This is a summary for work performed under cooperative agreement DE FC36 04GO14006 (Design and Development of New Carbon-based Sorbent Systems for an Effective Containment of Hydrogen). The project was directed to discover new solid and liquid materials that use reversible catalytic hydrogenation as the mechanism for hydrogen capture and storage. After a short period of investigation of solid materials, the inherent advantages of storing and transporting hydrogen using liquid-phase materials focused our attention exclusively on organic liquid hydrogen carriers (liquid carriers). While liquid carriers such as decalin and methylcyclohexane were known in the literature, these carriers suffer from practical disadvantages such as the need for very high temperatures to release hydrogen from the carriers and difficult separation of the carriers from the hydrogen. In this project, we were successful in using the prediction of reaction thermodynamics to discover liquid carriers that operate at temperatures up to 150 C lower than the previously known carriers. The means for modifying the thermodynamics of liquid carriers involved the use of certain molecular structures and incorporation of elements other than carbon into the carrier structure. The temperature decrease due to the more favorable reaction thermodynamics results in less energy input to release hydrogen from the carriers. For the first time, the catalytic reaction required to release hydrogen from the carriers could be conducted with the carrier remaining in the liquid phase. This has the beneficial effect of providing a simple means to separate the hydrogen from the carrier.

  17. Hydrogen program overview

    SciTech Connect (OSTI)

    Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

    1997-12-31T23:59:59.000Z

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  18. Low-Cost Hydrogen-from-Ethanol: A Distributed Production System

    Broader source: Energy.gov [DOE]

    Presentation by C.E. (Sandy) Thomas at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  19. The Hype About Hydrogen

    E-Print Network [OSTI]

    Mirza, Umar Karim

    2006-01-01T23:59:59.000Z

    economy based on the hydrogen fuel cell, but this cannot beus to look toward hydrogen. Fuel cell basics, simplifiedthe path to fuel cell commercialization. Hydrogen production

  20. Hydrogen Technologies Group

    SciTech Connect (OSTI)

    Not Available

    2008-03-01T23:59:59.000Z

    The Hydrogen Technologies Group at the National Renewable Energy Laboratory advances the Hydrogen Technologies and Systems Center's mission by researching a variety of hydrogen technologies.

  1. Hydrogen Transition Infrastructure Analysis

    SciTech Connect (OSTI)

    Melendez, M.; Milbrandt, A.

    2005-05-01T23:59:59.000Z

    Presentation for the 2005 U.S. Department of Energy Hydrogen Program review analyzes the hydrogen infrastructure needed to accommodate a transitional hydrogen fuel cell vehicle demand.

  2. Fuel gas production by microwave plasma in liquid

    SciTech Connect (OSTI)

    Nomura, Shinfuku; Toyota, Hiromichi; Tawara, Michinaga; Yamashita, Hiroshi; Matsumoto, Kenya [Graduate School of Science and Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577 (Japan); Shikoku Industry and Technology Promotion Center, 2-5 Marunouchi, Takamatsu, Kagawa 760-0033 (Japan)

    2006-06-05T23:59:59.000Z

    We propose to apply plasma in liquid to replace gas-phase plasma because we expect much higher reaction rates for the chemical deposition of plasma in liquid than for chemical vapor deposition. A reactor for producing microwave plasma in a liquid could produce plasma in hydrocarbon liquids and waste oils. Generated gases consist of up to 81% hydrogen by volume. We confirmed that fuel gases such as methane and ethylene can be produced by microwave plasma in liquid.

  3. Cryocompressed Hydrogen Storage and Liquid Delivery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"Wave theJuly 30,Crafty Gifts for theof EnergyRev.

  4. Liquid Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking ofOil & Gas »ofMarketing | DepartmentComputing Center | Department

  5. Liquid Hydrogen Delivery | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaeferApril 1, 1999InspectionsAnnual FinancialLignol InnovationsMay

  6. California Hydrogen Infrastructure Project

    SciTech Connect (OSTI)

    Edward C. Heydorn

    2013-03-12T23:59:59.000Z

    Air Products and Chemicals, Inc. has completed a comprehensive, multiyear project to demonstrate a hydrogen infrastructure in California. The specific primary objective of the project was to demonstrate a model of a ���¢��������real-world���¢������� retail hydrogen infrastructure and acquire sufficient data within the project to assess the feasibility of achieving the nation���¢��������s hydrogen infrastructure goals. The project helped to advance hydrogen station technology, including the vehicle-to-station fueling interface, through consumer experiences and feedback. By encompassing a variety of fuel cell vehicles, customer profiles and fueling experiences, this project was able to obtain a complete portrait of real market needs. The project also opened its stations to other qualified vehicle providers at the appropriate time to promote widespread use and gain even broader public understanding of a hydrogen infrastructure. The project engaged major energy companies to provide a fueling experience similar to traditional gasoline station sites to foster public acceptance of hydrogen. Work over the course of the project was focused in multiple areas. With respect to the equipment needed, technical design specifications (including both safety and operational considerations) were written, reviewed, and finalized. After finalizing individual equipment designs, complete station designs were started including process flow diagrams and systems safety reviews. Material quotes were obtained, and in some cases, depending on the project status and the lead time, equipment was placed on order and fabrication began. Consideration was given for expected vehicle usage and station capacity, standard features needed, and the ability to upgrade the station at a later date. In parallel with work on the equipment, discussions were started with various vehicle manufacturers to identify vehicle demand (short- and long-term needs). Discussions included identifying potential areas most suited for hydrogen fueling stations with a focus on safe, convenient, fast-fills. These potential areas were then compared to and overlaid with suitable sites from various energy companies and other potential station operators. Work continues to match vehicle needs with suitable fueling station locations. Once a specific site was identified, the necessary agreements could be completed with the station operator and expected station users. Detailed work could then begin on the site drawings, permits, safety procedures and training needs. Permanent stations were successfully installed in Irvine (delivered liquid hydrogen), Torrance (delivered pipeline hydrogen) and Fountain Valley (renewable hydrogen from anaerobic digester gas). Mobile fueling stations were also deployed to meet short-term fueling needs in Long Beach and Placerville. Once these stations were brought online, infrastructure data was collected and reported to DOE using Air Products���¢�������� Enterprise Remote Access Monitoring system. Feedback from station operators was incorporated to improve the station user���¢��������s fueling experience.

  7. Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol Fuel Cells Jeremy Kua and William A. Goddard III* Contribution from functional theory (B3LYP)], we calculated the 13 most likely intermediate species for methanol oxidation

  8. Method and apparatus for the preparation of liquid samples for determination of boron

    DOE Patents [OSTI]

    Siemer, Darryl D. (Idaho Falls, ID)

    1986-01-01T23:59:59.000Z

    A method and apparatus for the preparation of a liquid sample for the quantitative determination of boron by flame photometry. The sample is combined in a vessel with sulfuric acid, and an excess of methanol is added thereto. The methanol reacts with any boron present in the sample to form trimethyl borate which is volatilized by the heat of reaction between the excess methanol and sulfuric acid. The volatilized trimethyl borate is withdrawn from the vessel by either a partial vacuum or a positive pressure and is rapidly transferred to a standard flame photometer. The method is free of interference from typical boron concomitants.

  9. Catalytic gasification of bagasse for the production of methanol

    SciTech Connect (OSTI)

    Baker, E.G.; Brown, M.D.; Robertus, R.J.

    1985-10-01T23:59:59.000Z

    The purpose of the study was to evaluate the technical and economic feasibility of catalytic gasification of bagasse to produce methanol. In previous studies, a catalytic steam gasification process was developed which converted wood to methanol synthesis gas in one step using nickel based catalysts in a fluid-bed gasifier. Tests in a nominal 1 ton/day process development unit (PDU) gasifier with these same catalysts showed bagasse to be a good feedstock for fluid-bed gasifiers, but the catalysts deactivated quite rapidly in the presence of bagasse. Laboratory catalyst screening tests showed K/sub 2/CO/sub 3/ doped on the bagasse to be a promising catalyst for converting bagasse to methanol synthesis gas. PDU tests with 10 wt % K/sub 2/CO/sub 3/ doped on bagasse showed the technical feasibility of this type of catalyst on a larger scale. A high quality synthesis gas was produced and carbon conversion to gas was high. The gasifier was successfully operated without forming agglomerates of catalyst, ash, and char in the gasifier. There was no loss of activity throughout the runs because catalysts is continually added with the bagasse. Laboratory tests showed about 80% of the potassium carbonate could be recovered and recycled with a simple water wash. An economic evaluation of the process for converting bagasse to methanol showed the required selling price of methanol to be significantly higher than the current market price of methanol. Several factors make this current evaluaton using bagasse as a feedstock less favorable: (1) capital costs are higher due to inflation and some extra costs required to use bagasse, (2) smaller plant sizes were considered so economies of scale are lost, and (3) the market price of methanol in the US has fallen 44% in the last six months. 24 refs., 14 figs., 16 tabs.

  10. HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM

    E-Print Network [OSTI]

    HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM date ­ November 23, 2004 · Contract end date ­ March 31, 2006 #12;Hydrogen Regional Infrastructure Program in Pennsylvania Hydrogen Regional Infrastructure Program in Pennsylvania · Objectives ­ Capture

  11. Electrolytic hydrogen production infrastructure options evaluation. Final subcontract report

    SciTech Connect (OSTI)

    Thomas, C.E.; Kuhn, I.F. Jr. [Directed Technologies, Inc., Arlington, VA (United States)

    1995-09-01T23:59:59.000Z

    Fuel-cell electric vehicles have the potential to provide the range, acceleration, rapid refueling times, and other creature comforts associated with gasoline-powered vehicles, but with virtually no environmental degradation. To achieve this potential, society will have to develop the necessary infrastructure to supply hydrogen to the fuel-cell vehicles. Hydrogen could be stored directly on the vehicle, or it could be derived from methanol or other hydrocarbon fuels by on-board chemical reformation. This infrastructure analysis assumes high-pressure (5,000 psi) hydrogen on-board storage. This study evaluates one approach to providing hydrogen fuel: the electrolysis of water using off-peak electricity. Other contractors at Princeton University and Oak Ridge National Laboratory are investigating the feasibility of producing hydrogen by steam reforming natural gas, probably the least expensive hydrogen infrastructure alternative for large markets. Electrolytic hydrogen is a possible short-term transition strategy to provide relatively inexpensive hydrogen before there are enough fuel-cell vehicles to justify building large natural gas reforming facilities. In this study, the authors estimate the necessary price of off-peak electricity that would make electrolytic hydrogen costs competitive with gasoline on a per-mile basis, assuming that the electrolyzer systems are manufactured in relatively high volumes compared to current production. They then compare this off-peak electricity price goal with actual current utility residential prices across the US.

  12. Hydrogen Technology Validation

    Fuel Cell Technologies Publication and Product Library (EERE)

    This fact sheet provides a basic introduction to the DOE Hydrogen National Hydrogen Learning Demonstration for non-technical audiences.

  13. Hydrogen Analysis Group

    SciTech Connect (OSTI)

    Not Available

    2008-03-01T23:59:59.000Z

    NREL factsheet that describes the general activites of the Hydrogen Analysis Group within NREL's Hydrogen Technologies and Systems Center.

  14. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    of Fuel has carried many articles applying fluid mech- anicspulverized coal to the fuel. The fluid mechanical structureFluid-Atomizing Oil Flames and the Effect on ame Emissivity and Radiation of the Addition of Carbon Black to Liquid Fuels,"

  15. High Pressure Ethanol Reforming for Distributed Hydrogen Production

    Broader source: Energy.gov [DOE]

    Presentation by S. Ahmed and S.H.D. Lee at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

  16. Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM...

    Broader source: Energy.gov (indexed) [DOE]

    for 3 pathways with single mode. conditioning and storage are at or adjacent to Liquid Hydrogen (LH) Truck H2 Production 100 or 1500 kgd Compressed H2 (CH) Truck H2 Production...

  17. Technical Assessment: Cryo-Compressed Hydrogen Storage for Vehicular...

    Broader source: Energy.gov (indexed) [DOE]

    assuming 10.1 kg usable liquid hydrogen. 7 The two main cost contributors are the carbon fiber composite and the group of cryogenic valves and regulator, each accounting for...

  18. Bifunctional Anode Catalysts for Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Rossmeisl, Jan; Ferrin, Peter A.; Tritsaris, Georgios A.; Nilekar, Anand U.; Koh, Shirlaine; Bae, Sang Eun; Brankovic, Stanko R.; Strasser, Peter; Mavrikakis, Manos

    2012-06-13T23:59:59.000Z

    Using the binding energy of OH* and CO* on close-packed surfaces as reactivity descriptors, we screen bulk and surface alloy catalysts for methanol electro-oxidation activity. Using these two descriptors, we illustrate that a good methanol electro-oxidation catalyst must have three key properties: (1) the ability to activate methanol, (2) the ability to activate water, and (3) the ability to react off surface intermediates (such as CO* and OH*). Based on this analysis, an alloy catalyst made up of Cu and Pt should have a synergistic effect facilitating the activity towards methanol electro-oxidation. Using these two reactivity descriptors, a surface PtCu3 alloy is proposed to have the best catalytic properties of the Pt–Cu model catalysts tested, similar to those of a Pt–Ru bulk alloy. To validate the model, experiments on a Pt(111) surface modified with different amounts of Cu adatoms are performed. Adding Cu to a Pt(111) surface increases the methanol oxidation current by more than a factor of three, supporting our theoretical predictions for improved electrocatalysts.

  19. Clustering Dynamics in Water/Methanol Mixtures: A Nuclear Magnetic Resonance Study at 205 K < T < 295 K

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Clustering Dynamics in Water/Methanol Mixtures: A Nuclear Magnetic Resonance Study at 205 K functional groups in water/methanol mixtures at different methanol molar fractions (XMeOH ) 0, 0.04, 0.1, 0 in the mixtures, at all the methanol molar fractions, are faster than those of pure water and methanol because

  20. Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT)

    SciTech Connect (OSTI)

    Conocophillips

    2007-09-30T23:59:59.000Z

    The Wabash River Integrated Methanol and Power Production from Clean Coal Technologies (IMPPCCT) project was established to evaluate integrated electrical power generation and methanol production through clean coal technologies. The project was under the leadership of ConocoPhillips Company (COP), after it acquired Gasification Engineering Corporation (GEC) and the E-Gas gasification technology from Global Energy Inc. in July 2003. The project has completed both Phase 1 and Phase 2 of development. The two project phases include the following: (1) Feasibility study and conceptual design for an integrated demonstration facility at SG Solutions LLC (SGS), previously the Wabash River Energy Limited, Gasification Facility located in West Terre Haute, Indiana, and for a fence-line commercial embodiment plant (CEP) operated at the Dow Chemical Company or Dow Corning Corporation chemical plant locations. (2) Research, development, and testing (RD&T) to define any technology gaps or critical design and integration issues. Phase 1 of this project was supported by a multi-industry team consisting of Air Products and Chemicals, Inc., The Dow Chemical Company, Dow Corning Corporation, Methanex Corporation, and Siemens Westinghouse Power Corporation, while Phase 2 was supported by Gas Technology Institute, TDA Research Inc., and Nucon International, Inc. The SGS integrated gasification combined cycle (IGCC) facility was designed, constructed, and operated under a project selected and co-funded under the Round IV of the United States Department of Energy's (DOE's) Clean Coal Technology Program. In this project, coal and/or other carbonaceous fuel feedstocks are gasified in an oxygen-blown, entrained-flow gasifier with continuous slag removal and a dry particulate removal system. The resulting product synthesis gas (syngas) is used to fuel a combustion turbine generator whose exhaust is integrated with a heat recovery steam generator to drive a refurbished steam turbine generator. The gasifier uses technology initially developed by The Dow Chemical Company (the Destec Gasification Process), and now acquired and offered commercially by COP as the E-Gas technology. In a joint effort with the DOE, a Cooperative Agreement was awarded under the Early Entrance Coproduction Plant (EECP) solicitation. GEC, and later COP and the industrial partners investigated the use of syngas produced by the E-Gas technology in a coproduction environment to enhance the efficiency and productivity of solid fuel gasification combined cycle power plants. The objectives of this effort were to determine the feasibility of an EECP located at a specific site which produces some combination of electric power (or heat), fuels, and/or chemicals from syngas derived from coal, or, coal in combination with some other carbonaceous feedstock. The intended result of the project was to provide the necessary technical, economic, and environmental information that would be needed to move the EECP forward to detailed design, construction, and operation by industry. The EECP study conducted in Phase 1 of the IMPPCCT Project confirmed that the concept for the integration of gasification-based (E-Gas) electricity generation from coal and/or petroleum coke and methanol production (Liquid Phase Methanol or LPMEOH{trademark}) processes was feasible for the coproduction of power and chemicals. The results indicated that while there were minimal integration issues that impact the deployment of an IMPPCCT CEP, the major concern was the removal of sulfur and other trace contaminants, which are known methanol catalyst poisons, from the syngas. However, economic concerns in the domestic methanol market which is driven by periodic low natural gas prices and cheap offshore supplies limit the commercial viability of this more capital intensive concept. The objective of Phase 2 was to conduct RD&T as outlined in the Phase 1 RD&T Plan to enhance the development and commercial acceptance of coproduction technology. Studies were designed to address the technical concerns that would mak

  1. Direct conversion of light hydrocarbon gases to liquid fuel

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  2. Coal hydrogenation and deashing in ebullated bed catalytic reactor

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Johanson, Edwin S. (Princeton, NJ)

    1983-01-01T23:59:59.000Z

    An improved process for hydrogenation of coal containing ash with agglomeration and removal of ash from an ebullated bed catalytic reactor to produce deashed hydrocarbon liquid and gas products. In the process, a flowable coal-oil slurry is reacted with hydrogen in an ebullated catalyst bed reaction zone at elevated temperature and pressure conditions. The upward velocity and viscosity of the reactor liquid are controlled so that a substantial portion of the ash released from the coal is agglomerated to form larger particles in the upper portion of the reactor above the catalyst bed, from which the agglomerated ash is separately withdrawn along with adhering reaction zone liquid. The resulting hydrogenated hydrocarbon effluent material product is phase separated to remove vapor fractions, after which any ash remaining in the liquid fraction can be removed to produce substantially ash-free coal-derived liquid products.

  3. Perovskite anode electrocatalysis for direct methanol fuel cells

    SciTech Connect (OSTI)

    White, J.H.; Sammells, A.F. (Eltron Research, Inc., Boulder, CO (United States))

    1993-08-01T23:59:59.000Z

    This investigation explores direct methanol fuel cells incorporating perovskite anode electrocatalysts. Preliminary electrochemical performance was addressed following incorporation of electrocatalysts into polymer electrolyte (Nafion 417) fuel cells. Perovskite electrocatalysts demonstrating activity towards direct methanol oxidation during cyclic voltammetry measurements included, respectively, SrRu[sub 0.5]Pt[sub 0.5]O[sub 3], SrRu[sub 0.5]Pd[sub 0.5]O[sub 3], SrPdO[sub 3], SmCoO[sub 3], SrRuO[sub 3], La[sub 0.8]Ce[sub 0.2]CoC[sub 3],SrCo[sub 0.5]Ti[sub 0.5]O[sub 3], and La[sub 0.8]Sr[sub 0.2]CoO[sub 3] where SrRu[sub 0.5]Pt[sub 0.5]P[sub 3] gave methanol oxidation currents up to 28 mA/cm[sup 2] at 0.45 V vs. SCE. Correlations were found between electrocatalyst solid-state and thermodynamic parameters corresponding to, respectively, molecular electronic polarizability, the optical dielectric constant, the perovskite spin-only magnetic moment, the number of d-electrons in perovskite A and B lattice sites, and the average metal-oxygen binding energy for the perovskite lattice, and corresponding fuel cell performance. This may have future merit for the prediction of new electrocatalyst family members for promoting direct methanol oxidation. Methanol diffusion from anode to cathode compartments appears to be a major obstacle to the development of polymer electrolyte methanol fuel cells.

  4. Methods of using ionic liquids having a fluoride anion as solvents

    DOE Patents [OSTI]

    Pagoria, Philip (Livermore, CA); Maiti, Amitesh (San Ramon, CA); Gash, Alexander (Brentwood, CA); Han, Thomas Yong (Pleasanton, CA); Orme, Christine (Oakland, CA); Fried, Laurence (Livermore, CA)

    2011-12-06T23:59:59.000Z

    A method in one embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having a fluoride anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of about 90.degree. C. or less during the contacting. A method in another embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having an acetate or formate anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of less than about 90.degree. C. during the contacting.

  5. Single-cell protein from methanol with Enterobacter aerogenes

    SciTech Connect (OSTI)

    Gnan, S.O.; Abodreheba, A.O.

    1987-02-20T23:59:59.000Z

    An identified Enterobacter aerogenes utilizing methanol as a sole carbon source was studied for the optimization of biomass production and the reduction of its nucleic acid content. Results indicated that the highest yield and conversion were obtained at 0.5% methanol. The addition of seawater as a source of trace elements has an adverse effect. However, the addition of urea as source of nitrogen enhanced the growth of E. aerogenes. Heat shock at 60 degrees C for one minute followed by incubation at 50 degrees C for 2 hours caused 72.6% reduction in the nucleic acid. 12 references.

  6. Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrogen Vehicles and Fuels in China Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen Vehicles and Fuels in China Presentation given by Jinyang Zheng of...

  7. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bonded Arrays: The Power of Multiple Hydrogen Bonds. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds. Abstract: Hydrogen bond interactions in small covalent model...

  8. Hydrogen permeability and Integrity of hydrogen transfer pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    permeability and Integrity of hydrogen transfer pipelines Hydrogen permeability and Integrity of hydrogen transfer pipelines Presentation by 03-Babu for the DOE Hydrogen Pipeline...

  9. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties...

    Office of Environmental Management (EM)

    CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay...

  10. NREL Wind to Hydrogen Project: Renewable Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage &...

  11. Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...

    Broader source: Energy.gov (indexed) [DOE]

    Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  12. Overview of interstate hydrogen pipeline systems.

    SciTech Connect (OSTI)

    Gillette, J .L.; Kolpa, R. L

    2008-02-01T23:59:59.000Z

    The use of hydrogen in the energy sector of the United States is projected to increase significantly in the future. Current uses are predominantly in the petroleum refining sector, with hydrogen also being used in the manufacture of chemicals and other specialized products. Growth in hydrogen consumption is likely to appear in the refining sector, where greater quantities of hydrogen will be required as the quality of the raw crude decreases, and in the mining and processing of tar sands and other energy resources that are not currently used at a significant level. Furthermore, the use of hydrogen as a transportation fuel has been proposed both by automobile manufacturers and the federal government. Assuming that the use of hydrogen will significantly increase in the future, there would be a corresponding need to transport this material. A variety of production technologies are available for making hydrogen, and there are equally varied raw materials. Potential raw materials include natural gas, coal, nuclear fuel, and renewables such as solar, wind, or wave energy. As these raw materials are not uniformly distributed throughout the United States, it would be necessary to transport either the raw materials or the hydrogen long distances to the appropriate markets. While hydrogen may be transported in a number of possible forms, pipelines currently appear to be the most economical means of moving it in large quantities over great distances. One means of controlling hydrogen pipeline costs is to use common rights-of-way (ROWs) whenever feasible. For that reason, information on hydrogen pipelines is the focus of this document. Many of the features of hydrogen pipelines are similar to those of natural gas pipelines. Furthermore, as hydrogen pipeline networks expand, many of the same construction and operating features of natural gas networks would be replicated. As a result, the description of hydrogen pipelines will be very similar to that of natural gas pipelines. The following discussion will focus on the similarities and differences between the two pipeline networks. Hydrogen production is currently concentrated in refining centers along the Gulf Coast and in the Farm Belt. These locations have ready access to natural gas, which is used in the steam methane reduction process to make bulk hydrogen in this country. Production centers could possibly change to lie along coastlines, rivers, lakes, or rail lines, should nuclear power or coal become a significant energy source for hydrogen production processes. Should electrolysis become a dominant process for hydrogen production, water availability would be an additional factor in the location of production facilities. Once produced, hydrogen must be transported to markets. A key obstacle to making hydrogen fuel widely available is the scale of expansion needed to serve additional markets. Developing a hydrogen transmission and distribution infrastructure would be one of the challenges to be faced if the United States is to move toward a hydrogen economy. Initial uses of hydrogen are likely to involve a variety of transmission and distribution methods. Smaller users would probably use truck transport, with the hydrogen being in either the liquid or gaseous form. Larger users, however, would likely consider using pipelines. This option would require specially constructed pipelines and the associated infrastructure. Pipeline transmission of hydrogen dates back to late 1930s. These pipelines have generally operated at less than 1,000 pounds per square inch (psi), with a good safety record. Estimates of the existing hydrogen transmission system in the United States range from about 450 to 800 miles. Estimates for Europe range from about 700 to 1,100 miles (Mohipour et al. 2004; Amos 1998). These seemingly large ranges result from using differing criteria in determining pipeline distances. For example, some analysts consider only pipelines above a certain diameter as transmission lines. Others count only those pipelines that transport hydrogen from a producer to a customer (e.g., t

  13. Hydrogen iodide decomposition

    DOE Patents [OSTI]

    O'Keefe, Dennis R. (San Diego, CA); Norman, John H. (San Diego, CA)

    1983-01-01T23:59:59.000Z

    Liquid hydrogen iodide is decomposed to form hydrogen and iodine in the presence of water using a soluble catalyst. Decomposition is carried out at a temperature between about 350.degree. K. and about 525.degree. K. and at a corresponding pressure between about 25 and about 300 atmospheres in the presence of an aqueous solution which acts as a carrier for the homogeneous catalyst. Various halides of the platinum group metals, particularly Pd, Rh and Pt, are used, particularly the chlorides and iodides which exhibit good solubility. After separation of the H.sub.2, the stream from the decomposer is countercurrently extracted with nearly dry HI to remove I.sub.2. The wet phase contains most of the catalyst and is recycled directly to the decomposition step. The catalyst in the remaining almost dry HI-I.sub.2 phase is then extracted into a wet phase which is also recycled. The catalyst-free HI-I.sub.2 phase is finally distilled to separate the HI and I.sub.2. The HI is recycled to the reactor; the I.sub.2 is returned to a reactor operating in accordance with the Bunsen equation to create more HI.

  14. Conversion of methane to higher hydrocarbons (Biomimetic catalysis of the conversion of methane to methanol). Final report

    SciTech Connect (OSTI)

    Watkins, B.E.; Taylor, R.T.; Satcher, J.H. [and others

    1993-09-01T23:59:59.000Z

    In addition to inorganic catalysts that react with methane, it is well-known that a select group of aerobic soil/water bacteria called methanotrophs can efficiently and selectively utilize methane as the sole source of their energy and carbon for cellular growth. The first reaction in this metabolic pathway is catalyzed by the enzyme methane monooxygenase (MMO) forming methanol. Methanol is a technology important product from this partial oxidation of methane since it can be easily converted to liquid hydrocarbon transportation fuels (gasoline), used directly as a liquid fuel or fuel additive itself, or serve as a feedstock for chemicals production. This naturally occurring biocatalyst (MMO) is accomplishing a technologically important transformation (methane directly to methanol) for which there is currently no analogous chemical (non-biological) process. The authors approach has been to use the biocatalyst, MMO, as the initial focus in the development of discrete chemical catalysts (biomimetic complexes) for methane conversion. The advantage of this approach is that it exploits a biocatalytic system already performing a desired transformation of methane. In addition, this approach generated needed new experimental information on catalyst structure and function in order to develop new catalysts rationally and systematically. The first task is a comparative mechanistic, biochemical, and spectroscopic investigation of MMO enzyme systems. This work was directed at developing a description of the structure and function of the catalytically active sites in sufficient detail to generate a biomimetic material. The second task involves the synthesis, characterization, and chemical reactions of discrete complexes that mimic the enzymatic active site. These complexes were synthesized based on their best current understanding of the MMO active site structure.

  15. An Investigation of Different Methods of Fabricating Membrane Electrode Assemblies for Methanol Fuel Cells

    E-Print Network [OSTI]

    Hall, Kwame (Kwame J.)

    2009-01-01T23:59:59.000Z

    Methanol fuel cells are electrochemical conversion devices that produce electricity from methanol fuel. The current process of fabricating membrane electrode assemblies (MEAs) is tedious and if it is not sufficiently ...

  16. Imaging Adsorbate O-H Bond Cleavage: Methanol on TiO2(110). ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O-H Bond Cleavage: Methanol on TiO2(110). Abstract: We investigated methanol adsorption and dissociation on bridge-bonded oxygen vacancies of TiO2(110) (1×1) surface...

  17. A Comparative Study of the Adsorption of Water and Methanol in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the Adsorption of Water and Methanol in Zeolite BEA: A Molecular Simulation Study. A Comparative Study of the Adsorption of Water and Methanol in Zeolite BEA: A Molecular...

  18. Supplementary Information for Methanol as a sensitive probe for spatial and temporal variations of the

    E-Print Network [OSTI]

    Supplementary Information for Methanol as a sensitive probe for spatial and temporal variations.757 0.68(5) Table I. Methanol (12 CH16 3 OH) maser transitions and accurate rest frequencies taken from

  19. PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift. PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam...

  20. Table of Contents Producing Hydrogen................1

    E-Print Network [OSTI]

    , hydrogen produced from fossil fuels (like natural gas) can help to build early markets and infrastructure Natural Gas Reforming ....................8 Bio-Derived Liquids Reforming...........................9 Coal, nitrogen oxides). Economic Vitality The United States can secure a share of future global energy markets

  1. Direct Methanol Fuel Cell Experimental and Model Validation Study

    E-Print Network [OSTI]

    Wang, Chao-Yang

    Direct Methanol Fuel Cell Experimental and Model Validation Study M. Mench, J. Scott, S. Thynell boundary Fuel cell performance Current density distribution measurements Conclusions #12;3 Method, flow rate, species inlet and fuel cell temperature, and humidity. Transparent polycarbonate windows

  2. Discovery of two new methanol masers in NGC 7538

    E-Print Network [OSTI]

    M. Pestalozzi; V. Minier; F. Motte; J. Conway

    2006-01-20T23:59:59.000Z

    Context: NGC7538 is known to host a 6.7 and 12.2GHz methanol maser cospatial with a Ultra Compact (UC) HII region, IRS1. Aims: We report on the serendipitous discovery of two additional 6.7GHz methanol masers in the same region, not associated with IRS1. Methods: Interferometry maser positions are compared with recent single-dish and interferometry continuum observations. Results: The positions of the masers agree to high accuracy with the 1.2mm continuum peak emission in NGC7538 IRS9 and NGC7538 S. This clear association is also confirmed by the positional agreement of the masers with existing high resolution continuum observations at cm and/or mm wavelengths. Conclusions: Making use of the established strong relation between methanol masers and high-mass star formation, we claim that we have accurately positioned the high-mass protostars within the regions where they are detected. The variety of objects hosting a 6.7GHz methanol maser in NGC7538 shows that this emission probably traces different evolutionary stages within the protostellar phase.

  3. Methanol market slowly tightens as Brazil starts soaking up material

    SciTech Connect (OSTI)

    Young, I.

    1992-11-25T23:59:59.000Z

    Although the US methanol market's response to mandated oxygen requirements in reformulated gasoline has been disappointing, the European market has surprisingly been tightening in recent weeks and looks set for a price rise in first-quarter 1993. The tightness is being felt mainly in the Mediterranean market, where the Libyan methanol plant is running at only 70% because of problems with gas feedstock supplies. More significantly, the Brazilian government has now given the go-ahead for a yearlong extension on imports of methanol for use as an ethanol replacement in fuel blending. The new authorization sets a monthly import limit of 48,000 m.t. during that period. Libya is an important supplier of methanol to the Brazilian market and has already shipped about 20,000 m.t. since the authorization was given. Another major supplier to Brazil is Russia, from its two giant 750,000-m.t./year plants at Gubakha and Tomsk. The material is shipped from the terminal at Yuzhnyy on the Black Sea, in Ukrainian territory since the collapse of the Soviet Union.

  4. Process Design and Integration of Shale Gas to Methanol 

    E-Print Network [OSTI]

    Ehlinger, Victoria M.

    2013-02-04T23:59:59.000Z

    pathways for the production of methanol from shale gas. The composition of the shale gas feedstock is assumed to come from the Barnett Shale Play located near Fort Worth, Texas, which is currently the most active shale gas play in the US. Process...

  5. Influence of the pressure on the properties of chromatographic columns I. Measurement of the compressibility of methanol-water mixtures on a mesoporous silica adsorbent

    SciTech Connect (OSTI)

    Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

    2005-03-01T23:59:59.000Z

    The compressibilities of aqueous solutions of methanol or acetonitrile containing 0, 20, 40, 60, 80 and 100% (v/v) organic solvent were measured with a dynamic chromatographic method. The elution volumes of thiourea samples (2 {micro} L) in these solutions were measured at different average column pressures, adjusted by placing suitable capillary restrictors on-line, after the detector. The reproducibility of the measurements was better than 0.2%. In the range of average pressures studied (10-350 bar), the maximum change in elution volume of thiourea is 1.3% (in pure water) and 4.0% (in pure methanol). This difference is due to the different compressibilities of these pure solvents. For mixtures, the plots of the elution volume of thiourea versus the pressure are convex downward, which is inconsistent with the opposite curvature predicted by the classical Tait model of liquid compressibility. This difference is explained by the variation of the amount of thiourea adsorbed with the pressure. The deconvolution of the two effects, adsorption of thiourea and solvent compressibility, allows a fair and consistent determination of the compressibilities of the methanol-water mixtures. A column packed with non-porous silica particles was also used to determine the compressibility of methanol-water and acetonitrile-water mixtures. A negative deviation by respect to ideal behavior was observed.

  6. Influence of the pressure on the properties of chromatographic columns I. Measurement of the compressibility of methanol-water mixtures on a mesoporous silica adsorbent

    SciTech Connect (OSTI)

    Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

    2005-04-01T23:59:59.000Z

    The compressibilities of aqueous solutions of methanol or acetonitrile containing 0, 20, 40, 60, 80 and 100% (v/v) organic solvent were measured with a dynamic chromatographic method. The elution volumes of thiourea samples (2 {micro} L) in these solutions were measured at different average column pressures, adjusted by placing suitable capillary restrictors on-line, after the detector. The reproducibility of the measurements was better than 0.2%. In the range of average pressures studied (10-350 bar), the maximum change in elution volume of thiourea is 1.3% (in pure water) and 4.0% (in pure methanol). This difference is due to the different compressibilities of these pure solvents. For mixtures, the plots of the elution volume of thiourea versus the pressure are convex downward, which is inconsistent with the opposite curvature predicted by the classical Tait model of liquid compressibility. This difference is explained by the variation of the amount of thiourea adsorbed with the pressure. The deconvolution of the two effects, adsorption of thiourea and solvent compressibility, allows a fair and consistent determination of the compressibilities of the methanol-water mixtures. A column packed with non-porous silica particles was also used to determine the compressibility of methanol-water and acetonitrile-water mixtures. A negative deviation by respect to ideal behavior was observed.

  7. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts (Presentation)

    SciTech Connect (OSTI)

    Dinh, H.; Gennett, T.

    2010-06-11T23:59:59.000Z

    This presentation is a summary of a Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts.

  8. Ris Energy Report 3 Hydrogen is a gas at ambient temperatures and pressures,

    E-Print Network [OSTI]

    be stored as a gas, a liquid or a solid. In the case of solid storage, the hydrogen exists as a chemical. Compared to fossil fuels such as gasoline, hydrogen has a very obvious shortfall in the amount of energy.5% hydrogen by weight or 62 kg H2/m3 and several storage techniques are able to meet these requirements

  9. Solar-Hydrogen Fuel-Cell Vehicles

    E-Print Network [OSTI]

    DeLuchi, Mark A.; Ogden, Joan M.

    1993-01-01T23:59:59.000Z

    nosulfur. fA methanol/fuel-cell vehicle wouldhaveno tailpipeanalysis of fuel cell vehicles using methanol and hy- drogenused fuel-cell vehicles and (d) biomass-derived methanol

  10. Electrokinetic Power Generation from Liquid Water Microjets

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Saykally, Richard J.

    2008-02-15T23:59:59.000Z

    Although electrokinetic effects are not new, only recently have they been investigated for possible use in energy conversion devices. We have recently reported the electrokinetic generation of molecular hydrogen from rapidly flowing liquid water microjets [Duffin et al. JPCC 2007, 111, 12031]. Here, we describe the use of liquid water microjets for direct conversion of electrokinetic energy to electrical power. Previous studies of electrokinetic power production have reported low efficiencies ({approx}3%), limited by back conduction of ions at the surface and in the bulk liquid. Liquid microjets eliminate energy dissipation due to back conduction and, measuring only at the jet target, yield conversion efficiencies exceeding 10%.

  11. Complete Quantitative online Analysis of Methanol Electrooxidation Prod-ucts via Electron Impact and Electrospray Ionization Mass Spectrometry

    E-Print Network [OSTI]

    Pfeifer, Holger

    1 Complete Quantitative online Analysis of Methanol Electrooxidation Prod- ucts via Electron Impact for application in energy re- lated electrocatalysis is demonstrated using continuous methanol oxidation over

  12. Tropospheric methanol observations from space: retrieval1 evaluation and constraints on the seasonality of biogenic2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 Tropospheric methanol observations from space: retrieval1 evaluation and constraints Information1 2 3 #12; 3 1 FigureS1.Comparison of TES, IASI and airborne methanol measurements using GEOS-Chem as2 an intercomparison platform. Methanol abundance as modeled by GEOS-Chem (base-case3 simulation

  13. Journal of Power Sources 167 (2007) 265271 Simultaneous oxygen-reduction and methanol-oxidation reactions

    E-Print Network [OSTI]

    Zhao, Tianshou

    2007-01-01T23:59:59.000Z

    Journal of Power Sources 167 (2007) 265­271 Simultaneous oxygen-reduction and methanol-reduction reaction (ORR) and methanol- oxidation reaction (MOR) at the cathode of a DMFC. Good agreements between a significant poisoning effect on the ORR by the presence of methanol at the cathode. The results also indicated

  14. Department of Energy and Mineral Engineering Spring 2012 BP Methanol Separation

    E-Print Network [OSTI]

    Demirel, Melik C.

    PENNSTATE Department of Energy and Mineral Engineering Spring 2012 BP ­ Methanol Separation issues in the well heads. To counteract this problem, methanol is injected into the produced water stream at the well site. Methanol, however, is toxic to humans, animals, and plants, and must be removed before

  15. Global budget of methanol: Constraints from atmospheric observations Daniel J. Jacob,1

    E-Print Network [OSTI]

    Li, Qinbin

    Global budget of methanol: Constraints from atmospheric observations Daniel J. Jacob,1 Brendan D of atmospheric methanol to examine the consistency between observed atmospheric concentrations and current of methanol in the model is 7 days; gas-phase oxidation by OH accounts for 63% of the global sink, dry

  16. Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory

    E-Print Network [OSTI]

    Metz, Ricardo B.

    Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory-phase transition metal oxide cations can convert methane to methanol. Methane activation by MO+ is discussed such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

  17. Performance and endurance of a high temperature PEM fuel cell operated on methanol reformate

    E-Print Network [OSTI]

    Kćr, Sřren Knudsen

    Performance and endurance of a high temperature PEM fuel cell operated on methanol reformate Samuel September 2014 Available online xxx Keywords: High temperature PEM Fuel cell Methanol Impedance spectroscopy a b s t r a c t This paper analyzes the effects of methanol and water vapor on the performance

  18. PPPL-3457 PPPL-3457 Broadening and Shifting of the Methanol 119 m Gain Line

    E-Print Network [OSTI]

    PPPL-3457 PPPL-3457 UC-70 Broadening and Shifting of the Methanol 119 µm Gain Line of Linear and Shifting of the Methanol 119 mm Gain Line of Linear and Circular Polarization by Collision with Chiral handedness of a circularly polarized probe. The broadening of the 119 mm line of the methanol molecule

  19. Quantifying global terrestrial methanol emissions using1 observations from the TES satellite sensor2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    1 Quantifying global terrestrial methanol emissions using1 observations from the TES Figure S1. December-January-Febuary (DJF, top) and June-July-August (JJA, bottom) biogenic3 methanol 1 Figure S4. Regions employed for quantifying terrestrial methanol fluxes (red) and for2

  20. Methanol adsorbates on the DMFC cathode and their effect on the cell performance

    E-Print Network [OSTI]

    Zhao, Tianshou

    Methanol adsorbates on the DMFC cathode and their effect on the cell performance J. Prabhuram, T in the performance of a direct methanol fuel cell (DMFC) occurred after the cell had been operated at a higher temperature with higher methanol concentrations as compared with the polarization data collected under

  1. Methanol, acetaldehyde, and acetone in the surface waters of the Atlantic Ocean

    E-Print Network [OSTI]

    Arnold, Steve

    Methanol, acetaldehyde, and acetone in the surface waters of the Atlantic Ocean Rachael Beale,1; revised 12 June 2013; accepted 16 July 2013; published 16 October 2013. [1] Oceanic methanol, acetaldehyde to Chile (49 N to 39 S) in 2009. Methanol (48­361 nM) and acetone (2­24 nM) varied over the track

  2. Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt Nanoparticles

    E-Print Network [OSTI]

    Kik, Pieter

    Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt nanoparticles (NPs) prepared by micelle encapsulation and supported on -Al2O3 during the oxidation of methanol the pretreatment. KEYWORDS: platinum, methanol oxidation, operando, XAFS, EXAFS, XANES, alumina, nanoparticle, size

  3. PoS(IXEVNSymposium)036 Mapping the Milky Way structure with methanol and

    E-Print Network [OSTI]

    Brunthaler, Andreas

    PoS(IXEVNSymposium)036 Mapping the Milky Way structure with methanol and water masers Luca VLBA and VERA results in measuring trigonometric parallaxes of methanol and water maser sourcesS(IXEVNSymposium)036 Mapping the Milky Way structure with methanol and water masers Luca Moscadelli 1. Introduction

  4. Mechanism of O2 Activation and Methanol Production by (Di(2-pyridyl)methanesulfonate)PtII

    E-Print Network [OSTI]

    Goddard III, William A.

    Mechanism of O2 Activation and Methanol Production by (Di(2- pyridyl)methanesulfonate)PtII Me observed for the SN2 functionalization to form methanol by two isomeric (dpms)PtIV Me(OH)2 complexes, one conversion of methane to methanol at low temper- ature is crucial for transportation of shale gas produced

  5. Molecular Dynamics of Methylamine, Methanol, and Methyl Fluoride Cations in Intense 7 Micron Laser Fields

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Molecular Dynamics of Methylamine, Methanol, and Methyl Fluoride Cations in Intense 7 Micron Laser of methylamine (CH3NH2 + ), methanol (CH3OH+ ), and methyl fluoride (CH3F+ ) cations by short, intense laser 7 m laser pulses. This work is motivated by recent studies of methanol cations by Yamanouchi and co

  6. Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15

    E-Print Network [OSTI]

    Bell, Alexis T.

    Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15 C. Hessa 2005; accepted 6 August 2005 The partial oxidation of methanol to formaldehyde (FA) was studied over vanadia partly agglomerates into vanadia crystallites during methanol oxidation. KEY WORDS: supported

  7. Passive film-induced stress and mechanical properties of a-Ti in methanol solution

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Passive film-induced stress and mechanical properties of a-Ti in methanol solution Zhi Qin and film mechanical properties on a-Ti in methanol solution with varying water content was investigated. Film-induced stress in the methanol solution was measured by the flow stress differential method

  8. PoS(IXEVNSymposium)039 EVN observations of the methanol masers in Cep A

    E-Print Network [OSTI]

    van Langevelde, Huib Jan

    PoS(IXEVNSymposium)039 EVN observations of the methanol masers in Cep A Karl Torstensson Leiden observations of the 6.7 GHz methanol maser in the high mass star-forming re- gion Cepheus A. The maser emission field of the methanol masers shows an infall sig- nature rather than a rotation signature. We present

  9. Dramatic Reduction of Water Crossover in Direct Methanol Fuel Cells by Cathode Humidification

    E-Print Network [OSTI]

    concentration methanol fuel cells, the water transport coefficient through the membrane must be reducedDramatic Reduction of Water Crossover in Direct Methanol Fuel Cells by Cathode Humidification much higher than 60°C and in active air-flowing direct methanol fuel cell systems with high power

  10. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01T23:59:59.000Z

    Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September bycost than both. Solar-hydrogen fuel- cell vehicles would becost than both. Solar-hydrogen fuel- cell vehicles would be

  11. HYDROGEN IN GERMANIUM

    E-Print Network [OSTI]

    Haller, E.E.

    2011-01-01T23:59:59.000Z

    •^f-1? c^4--^ LBL-7996 HYDROGEN IN GERMANIUM E. E. HallerW-7405-ENG-48 LBL-7996 HYDROGEN IN GERMANIUM* E. E. Haller48. LBL-7996 Abstract Hydrogen is shown to form molecular

  12. President's Hydrogen Fuel Initiative

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Fuel Initiative Workshop on Manufacturing R&D for the Hydrogen Economy Washington, DC July 13, 2005 JoAnn Milliken DOE Hydrogen Program Planning U.S. Energy Dependence is...

  13. Safety Issues with Hydrogen as a Vehicle Fuel

    SciTech Connect (OSTI)

    Cadwallader, Lee Charles; Herring, James Stephen

    1999-10-01T23:59:59.000Z

    This report is an initial effort to identify and evaluate safety issues associated with the use of hydrogen as a vehicle fuel in automobiles. Several forms of hydrogen have been considered: gas, liquid, slush, and hydrides. The safety issues have been discussed, beginning with properties of hydrogen and the phenomenology of hydrogen combustion. Safety-related operating experiences with hydrogen vehicles have been summarized to identify concerns that must be addressed in future design activities and to support probabilistic risk assessment. Also, applicable codes, standards, and regulations pertaining to hydrogen usage and refueling have been identified and are briefly discussed. This report serves as a safety foundation for any future hydrogen safety work, such as a safety analysis or a probabilistic risk assessment.

  14. Safety Issues with Hydrogen as a Vehicle Fuel

    SciTech Connect (OSTI)

    L. C. Cadwallader; J. S. Herring

    1999-09-01T23:59:59.000Z

    This report is an initial effort to identify and evaluate safety issues associated with the use of hydrogen as a vehicle fuel in automobiles. Several forms of hydrogen have been considered: gas, liquid, slush, and hydrides. The safety issues have been discussed, beginning with properties of hydrogen and the phenomenology of hydrogen combustion. Safety-related operating experiences with hydrogen vehicles have been summarized to identify concerns that must be addressed in future design activities and to support probabilistic risk assessment. Also, applicable codes, standards, and regulations pertaining to hydrogen usage and refueling have been identified and are briefly discussed. This report serves as a safety foundation for any future hydrogen safety work, such as a safety analysis or a probabilistic risk assessment.

  15. Sandia Hydrogen Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Combustion Research Sandia Hydrogen Combustion Research Sebastian A. Kaiser (PI) Sandia National Laboratories Christopher M. White University of New Hampshire Sponsor: DoE...

  16. Sandia National Laboratories: Hydrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Solar Thermochemical Hydrogen Production On June 13, 2014, in SNL maintains the equipment, experts, and partnerships required to develop technology for solar...

  17. Hydrogen Permeation Barrier Coatings

    SciTech Connect (OSTI)

    Henager, Charles H.

    2008-01-01T23:59:59.000Z

    Gaseous hydrogen, H2, has many physical properties that allow it to move rapidly into and through materials, which causes problems in keeping hydrogen from materials that are sensitive to hydrogen-induced degradation. Hydrogen molecules are the smallest diatomic molecules, with a molecular radius of about 37 x 10-12 m and the hydrogen atom is smaller still. Since it is small and light it is easily transported within materials by diffusion processes. The process of hydrogen entering and transporting through a materials is generally known as permeation and this section reviews the development of hydrogen permeation barriers and barrier coatings for the upcoming hydrogen economy.

  18. Hydrogen Program Overview

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to the DOE Hydrogen Program. It describes the program mission and answers the question: “Why Hydrogen?”

  19. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Sources Hydrogen Hydrogen September 30, 2014 Developed by Sandia National Laboratories and several industry partners, the fuel cell mobile light (H2LT) offers a cleaner, quieter...

  20. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    for clean energy technology manufacturers. March 28, 2014 Sales Tax Exemption for Hydrogen Generation Facilities In North Dakota, the sale of hydrogen used to power an internal...