National Library of Energy BETA

Sample records for liquid hydrocarbon stream

  1. An integrated process for simultaneous desulfurization, dehydration, and recovery of hydrocarbon liquids from natural gas streams

    SciTech Connect (OSTI)

    Sciamanna, S.F. ); ))

    1988-01-01

    Conventional processing schemes for desulfurizing, drying, and separation of natural gas liquids from natural gas streams require treating the gas by a different process for each separation step. In a simpler process, based on the University of California, Berkeley Sulfur Recovery Process (UCBSRP) technology, hydrogen sulfide, propane and heavier hydrocarbons, and water are absorbed simultaneously by a polyglycol ether solvent containing a homogenous liquid phase catalyst. The catalyst promotes the subsequent reaction of hydrogen sulfide with added sulfur dioxide to produce a high quality sulfur product. Hydrocarbons are separated as two product streams with the split between propane and butane. This new process offers an overall reduction in both capital and energy costs.

  2. Removal of carbonyl sulfide from liquid hydrocarbon streams

    SciTech Connect (OSTI)

    Damron, E.; Mick, M.B.; Woodall, R.M.

    1981-09-22

    Carbonyl sulfide is removed from propane and other similar liquefied petroleum gas products by mixing liquid methanol with the untreated liquefied gas and then contacting the liquid mixture with solid potassium hydroxide.

  3. Process for removing carbonyl-sulfide from liquid hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Debras, G.L.G.; DeClippeleir, G.E.M.J.; Cahen, R.M.

    1986-09-23

    A process is described for removing carbonyl sulfide from a liquid olefinic hydrocarbon feedstock comprising: (a) passing the hydrocarbon feedstock over an absorbent material comprising zinc oxide and a promoter selected from the group consisting of alumina, silico-aluminas and any combination thereof wherein the promoter is present in amounts from about 3 to about 15 percent by weight of the absorbent material; and (b) recovering a liquid olefinic hydrocarbon stream having a substantially reduced carbonyl sulfide content.

  4. Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

    2009-09-01

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

  5. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    SciTech Connect (OSTI)

    Mahajan, Devinder

    2004-12-28

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  6. Conversion method for gas streams containing hydrocarbons

    DOE Patents [OSTI]

    Mallinson, Richard G. (Norman, OK); Lobban, Lance (Norman, OK); Liu, Chang-jun (Tianjin, CN)

    2000-01-01

    An apparatus and a method of using the apparatus are provided for converting a gas stream containing hydrocarbons to a reaction product containing effluent molecules having at least one carbon atom, having at least one interior surface and at least one exterior surface, a first electrode and a second electrode with the first and second electrodes being selectively movable in relation to each other and positioned within the housing so as to be spatially disposed a predetermined distance from each other, a plasma discharge generator between the first and second electrodes, gas stream introducer and a collector for collecting the reaction product effluent produced by the reaction of the gas stream containing hydrocarbons with the plasma discharge between the first and second electrodes.

  7. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization...

  8. Recovering hydrocarbons from hydrocarbon-containing vapors

    DOE Patents [OSTI]

    Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

    1980-09-30

    Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

  9. Process for the production of liquid hydrocarbons

    DOE Patents [OSTI]

    Bhatt, Bharat Lajjaram; Engel, Dirk Coenraad; Heydorn, Edward Clyde; Senden, Matthijis Maria Gerardus

    2006-06-27

    The present invention concerns a process for the preparation of liquid hydrocarbons which process comprises contacting synthesis gas with a slurry of solid catalyst particles and a liquid in a reactor vessel by introducing the synthesis gas at a low level into the slurry at conditions suitable for conversion of the synthesis gas into liquid hydrocarbons, the solid catalyst particles comprising a catalytic active metal selected from cobalt or iron on a porous refractory oxide carrier, preferably selected from silica, alumina, titania, zirconia or mixtures thereof, the catalyst being present in an amount between 10 and 40 vol. percent based on total slurry volume liquids and solids, and separating liquid material from the solid catalyst particles by using a filtration system comprising an asymmetric filtration medium (the selective side at the slurry side), in which filtration system the average pressure differential over the filtration medium is at least 0.1 bar, in which process the particle size distribution is such that at least a certain amount of the catalyst particles is smaller than the average pore size of the selective layer of the filtration medium. The invention also comprises an apparatus to carry out the process described above.

  10. Methods of hydrotreating a liquid stream to remove clogging compounds

    DOE Patents [OSTI]

    Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

    2009-09-22

    A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

  11. Matthew Evan Thrasher A Liquid Stream Bouncing off a Moving Liquid Bath

    E-Print Network [OSTI]

    for the bouncing stream. When the stream contacts the surface, a thin layer of air separates the jet and the bathCopyright by Matthew Evan Thrasher 2005 #12;A Liquid Stream Bouncing off a Moving Liquid Bath THE UNIVERSITY OF TEXAS AT AUSTIN August 2005 #12;A Liquid Stream Bouncing off a Moving Liquid Bath APPROVED

  12. HYDROCARBON LIQUID FLOW CALIBRATION SERVICE NIST Special Publication 250-1039

    E-Print Network [OSTI]

    Magee, Joseph W.

    HYDROCARBON LIQUID FLOW CALIBRATION SERVICE NIST Special Publication 250-1039 T. T. Yeh, Jesús and Technology Laboratory National Institute of Standards and Technology Gaithersburg, MD 20899 #12;Hydrocarbon......................................... 3 4.0 Description of the Hydrocarbon Liquid Flow Standard

  13. Apparatus and method for rapid separation and detection of hydrocarbon fractions in a fluid stream

    DOE Patents [OSTI]

    Sluder, Charles S.; Storey, John M.; Lewis, Sr., Samuel A.

    2013-01-22

    An apparatus and method for rapid fractionation of hydrocarbon phases in a sample fluid stream are disclosed. Examples of the disclosed apparatus and method include an assembly of elements in fluid communication with one another including one or more valves and at least one sorbent chamber for removing certain classifications of hydrocarbons and detecting the remaining fractions using a detector. The respective ratios of hydrocarbons are determined by comparison with a non separated fluid stream.

  14. Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

    DOE Patents [OSTI]

    Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

    1999-05-25

    This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

  15. Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

    DOE Patents [OSTI]

    Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

    1999-01-01

    This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

  16. A study of the solubility of mercury in liquid hydrocarbons 

    E-Print Network [OSTI]

    McFarlane, David Larimer

    1991-01-01

    A STUDY OF THE SOLUBILITY OF MERCURY IN LIQUID HYDROCARBONS A Thesis by DAVID LARIhKR MCFARLANE Submitted to the Oflice of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 1991 Major Subject: Nuclear Engineering A STUDY OF THE SOLUBILITY OF MERCURY IN LIQUID HYDROCARBONS A Thesis by DAVID LARI1VKR MCFARLANE Approved as to style and content by: W. H. Marlow (Chair of Committee) . W. Bevan (Member) . A...

  17. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, J.L.

    1987-07-07

    A continuous thermochemical indirect liquefaction process is described to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C[sub 7]-C[sub 17] paraffinic hydrocarbons having cetane indices of 50+. 1 fig.

  18. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, James L. (Scottsdale, AZ)

    1987-07-07

    A continuous thermochemical indirect liquefaction process to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C.sub.7 -C.sub.17 paraffinic hydrocarbons having cetane indices of 50+.

  19. Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues

    Reports and Publications (EIA)

    2014-01-01

    Over the past five years, rapid growth in U.S. onshore natural gas and oil production has led to increased volumes of natural gas plant liquids (NGPL) and liquefied refinery gases (LRG). The increasing economic importance of these volumes, as a result of their significant growth in production, has revealed the need for better data accuracy and transparency to improve the quality of historical data and projections for supply, demand, and prices of these liquids, co-products, and competing products. To reduce confusion in terminology and improve its presentation of data, EIA has worked with industry and federal and state governments to clarify gas liquid terminology and has developed the term Hydrocarbon Gas Liquids, or HGL.

  20. Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See full Hydrocarbon Gas Liquids (HGL):

  1. Adsorption of carbonyl sulfide from liquid hydrocarbons with activated alumina and other adsorbents

    SciTech Connect (OSTI)

    Liu, P.K.T. (Alcoa Separations Technology Div., Aluminum Co. of America, Warrendale, PA (US))

    1988-01-01

    Contamination of Liquid hydrocarbon streams with carbonyl sulfide (COS) is not desirable; particularly in propylene. COS may poison the down stream polymerization catalyst. Thus, it is usually required to reduce the COS concentration to an extremely low level, e.g. 1 ppm or less, for polymer grade propylene. Many technologies generally available for sulfur removal, such as scrubbing and distillation are not applicable to the removal of COS from propylene. The former is not suitable for a low level removal. With the boiling point of COS (-50{sup 0}C) very close to that of propylene (-48{sup 0}C) it is difficult to achieve a very efficient separation with distillation. Adsorption technology provides a very energy efficient process in addition to its ability of the low level removal. Adsorbents selected in this study include activated carbon, molecular sieves, zinc oxide and activated alumina. The results show that activated alumina is far superior in both adsorption capacity and rate. An adsorption mechanism with activated alumina is proposed. It is believed that adsorption of COS takes place simultaneously with the hydrolysis of COS on the alumina surface. Adsorption isotherms of COS up to 100 ppm and the effect of moisture content are also addressed in this study.

  2. Short-Term Energy Outlook Model Documentation: Hydrocarbon Gas Liquids Supply and Demand

    Reports and Publications (EIA)

    2015-01-01

    The hydrocarbon gas liquids (ethane, propane, butanes, and natural gasoline) module of the Short-Term Energy Outlook (STEO) model is designed to provide forecasts of U.S. production, consumption, refinery inputs, net imports, and inventories.

  3. Method of purifying a gas stream using 1,2,3-triazolium ionic liquids

    DOE Patents [OSTI]

    Luebke, David; Nulwala, Hunald; Tang, Chau

    2014-12-09

    A method for separating a target gas from a gaseous mixture using 1,2,3-triazolium ionic liquids is presented. Industrial effluent streams may be cleaned by removing carbon dioxide from the stream by contacting the effluent stream with a 1,2,3-triazolium ionic liquid compound.

  4. Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects

    E-Print Network [OSTI]

    Chickos, James S.

    Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor pressures as a function of temperature and enthalpies of vaporization of a series of both liquid and solid. The applicability of this technique is first demonstrated by reproducing the vapor pressure isotope effect

  5. The effect of chemical dispersants on the solution of volatile liquid hydrocarbons from spilled crude oil 

    E-Print Network [OSTI]

    McDonald, Thomas Joseph

    1982-01-01

    THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE August 1982 Major Subject: Oceanography THE EFFECT OF CHEMICAL DISPERSANTS ON THE SOLUTION OF VOLATILE LIQUID HYDROCARBONS FROM SPILLED CRUDE OIL A Thesis by THOMAS JOSEPH McDONALD Approved as to style and content by...

  6. Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream

    DOE Patents [OSTI]

    Berry, David A; Shekhawat, Dushyant; Smith, Mark; Haynes, Daniel

    2013-07-16

    The disclosure relates to a method of utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream with a mitigation of carbon accumulation. The system is comprised of a catalytically active phase deposited onto an oxygen conducting phase, with or without supplemental support. The catalytically active phase has a specified crystal structure where at least one catalytically active metal is a cation within the crystal structure and coordinated with oxygen atoms within the crystal structure. The catalyst system employs an optimum coverage ratio for a given set of oxidation conditions, based on a specified hydrocarbon conversion and a carbon deposition limit. Specific embodiments of the catalyst system are disclosed.

  7. Dripping to Jetting Transitions in Coflowing Liquid Streams Andrew S. Utada,1

    E-Print Network [OSTI]

    Dripping to Jetting Transitions in Coflowing Liquid Streams Andrew S. Utada,1 Alberto Fernandez dripping to jetting is not understood for coflowing fluid streams, unlike the case of drop formation in air a microcapillary device to study the transition between dripping and jetting in a two-phase coflowing stream

  8. Process for refractory compound conversion in a hydrocracker recycle liquid

    SciTech Connect (OSTI)

    Gruia, A.J.

    1992-08-18

    This patent describes a catalytic hydrocracking process. It comprises contacting a hydrocarbonaceous feedstock; partially condensing the hydrocarbon effluent from the hydrocracking zone; introducing at least a portion of the unconverted hydrocarbon stream boiling above about 400{degrees} F and comprising trace quantities of 11{sup +} ring heavy polynuclear aromatic compounds into a 11{sup +} ring heavy polynuclear aromatic compound conversion zone; admixing at least a portion of the effluent from the conversion zone with the lower boiling hydrocarbon stream and partially condensing the resulting admixture; separating the partially condensed admixture to provide a hydrogen-rich gaseous stream and a liquid stream; separating the liquid stream comprising unconverted hydrocarbons boiling above about 400{degrees} F and lower boiling hydrocarbon products; and recycling at least a portion of the unconverted hydrocarbon stream boiling above about 400{degrees} F to the hydrocracking zone as at least a portion of the liquid recycle stream.

  9. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P; West, Brian H

    2013-01-01

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon blend stock does impact engine performance, there remains a significant opportunity for engine optimization when considering even the lowest octane fuels that are in compliance with the current revision of ASTM D5798 compared to premium-grade gasoline.

  10. Plasma Processing Of Hydrocarbon

    SciTech Connect (OSTI)

    Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

    2007-05-01

    The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

  11. Method for direct conversion of gaseous hydrocarbons to liquids

    DOE Patents [OSTI]

    Kong, Peter C.; Lessing, Paul A.

    2006-03-07

    A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.

  12. Catalysts and process for liquid hydrocarbon fuel production

    DOE Patents [OSTI]

    White, Mark G; Liu, Shetian

    2014-12-09

    The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

  13. Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture

    DOE Patents [OSTI]

    Rao, V. Udaya S. (Monroeville, PA); Gormley, Robert J. (Pittsburgh, PA)

    1987-01-01

    Synthesis gas containing CO and H.sub.2 is converted to a high-octane hydrocarbon liquid in the gasoline boiling point range by bringing the gas into contact with a heterogeneous catalyst including, in physical mixture, a zeolite molecular sieve, cobalt at 6-20% by weight, and thoria at 0.5-3.9% by weight. The contacting occurs at a temperature of 250.degree.-300.degree. C., and a pressure of 10-30 atmospheres. The conditions can be selected to form a major portion of the hydrocarbon product in the gasoline boiling range with a research octane of more than 80 and less than 10% by weight aromatics.

  14. Hydroconversion of liquid hydrocarbons in a staged autothermal reactor

    SciTech Connect (OSTI)

    Blass, SD; Bhan, A; Schmidt, LD

    2013-01-31

    An autothermal staged reactor was assembled containing a top stage of Rh-Ce/alpha-Al2O3 which generated heat and H-2 by reacting CH4 and air that passed through a downstream stage containing 0.5 wt% Pt/gamma-Al2O3 mixed with either HBEA, HZSM-5, or USY in a heat-integrated non-isothermal reactor. The H-2 produced subsequently reacts in a 20:1 ratio with a co-feed of hexane or decane or 2-decanone fed to the reactor between the stages. The large-sized pores of HBEA and USY allowed deoxygenation of 2-decanone to form decene isomers which can crack or cyclize to form up to a 36% yield of methylated and ethylated monoaromatics. The medium-sized pores of HZSM-5 restricted decene formation from 2-decanone by catalyzing cracking reactions to C2-6 compounds which can cyclize to form aromatics. By contrast, the reactor effluent from non-oxygenated reactants decane and hexane contained less than 5% aromatics. Thus, we extend the scope of staged autothermal reactor functionality to hydrocracking and hydroisomerization of higher saturated and oxygenated hydrocarbons. (C) 2012 Elsevier B.V. All rights reserved.

  15. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA); Zielke, Clyde W. (McMurray, PA)

    1981-01-01

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  16. Modular bioreactor for the remediation of liquid streams and methods for using the same

    DOE Patents [OSTI]

    Noah, K.S.; Sayer, R.L.; Thompson, D.N.

    1998-06-30

    The present invention is directed to a bioreactor system for the remediation of contaminated liquid streams. The bioreactor system is composed of at least one and often a series of sub-units referred to as bioreactor modules. The modular nature of the system allows bioreactor systems be subdivided into smaller units and transported to waste sites where they are combined to form bioreactor systems of any size. The bioreactor modules further comprises reactor fill materials in the bioreactor module that remove the contaminants from the contaminated stream. To ensure that the stream thoroughly contacts the reactor fill materials, each bioreactor module comprises means for directing the flow of the stream in a vertical direction and means for directing the flow of the stream in a horizontal direction. In a preferred embodiment, the reactor fill comprises a sulfate reducing bacteria which is particularly useful for precipitating metals from acid mine streams. 6 figs.

  17. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    SciTech Connect (OSTI)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-01-01

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen ranged from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.

  18. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    SciTech Connect (OSTI)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen ranged from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.

  19. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (more »from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.« less

  20. Nonionic diethanolamide amphiphiles with isoprenoid-type hydrocarbon chains: thermotropic and lyotropic liquid crystalline phase behaviour

    SciTech Connect (OSTI)

    Sagnella, Sharon M.; Conn, Charlotte E.; Krodkiewska, Irena; Drummond, Calum J. (CSIRO/MSE)

    2014-09-24

    The thermotropic and lyotropic liquid crystalline phase behaviour of a series of diethanolamide amphiphiles with isoprenoid-type hydrocarbon chains (geranoyl, H-farnesoyl, and phytanoyl) has been investigated. When neat, both H-farnesoyl and phytanoyl diethanolamide form a smectic liquid crystalline structure at sub-zero temperatures. In addition, all three diethanolamides exhibit a glass transition temperature at around -73 C. Geranoyl diethanolamide forms a lamellar crystalline phase with a lattice parameter of 17.4 {angstrom} following long term storage accompanied by the loss of the glass transition. In the presence of water, H-farnesoyl and phytanoyl diethanolamide form lyotropic liquid crystalline phases, whilst geranoyl diethanolamide forms an L{sub 2} phase. H-farnesoyl diethanolamide forms a fluid lamellar phase (L{sub {alpha}}) at room temperature and up to {approx} 40 C. Phytanoyl diethanolamide displays a rich mesomorphism forming the inverse diamond (Q{sub II}{sup D}) and gyroid (Q{sub II}{sup G}) bicontinuous cubic phases in addition to an L{sub {alpha}} phase.

  1. jet-compressible-gas-july25.tex 1 Liquid jet in a high Mach number air stream

    E-Print Network [OSTI]

    Joseph, Daniel D.

    jet-compressible-gas-july25.tex 1 Liquid jet in a high Mach number air stream T.Funada, D, Minneapolis, MN 55455, USA Abstract The instability of circular liquid jet immersed in a coflowing high growth rate for n = 1 modes exceeds n = 0 when the viscosity of the liquid jet is large. The effects

  2. Process for refractory compound conversion in a hydrocracker recycle liquid

    SciTech Connect (OSTI)

    Gruia, A.J.

    1991-04-16

    This patent describes a catalytic hydrocracking process. It includes contacting a hydrocarbonaceous feedstock having a propensity to form 11{sup +} ring heavy polynuclear aromatic compounds and a liquid recycle stream in a hydrocracking zone with added hydrogen and a metal promoted hydrocracking catalyst at elevated temperature and pressure sufficient to gain a substantial conversion to lower boiling products; partially condensing the hydrocarbon effluent from the hydrocracking zone and separating the same into a hydrocarbonaceous stream comprising lower boiling hydrocarbons, unconverted hydrocarbons boiling above about 400{degrees} F (204{degrees} C) and trace quantities of 11{sup +} ring heavy polynuclear aromatic compounds, and a vaporous hydrocarbonaceous stream comprising the lower boiling hydrocarbons.

  3. The sweet spot of forward osmosis: Treatment of produced water, drilling wastewater, and other complex and difficult liquid streams

    E-Print Network [OSTI]

    for nearly 45% of the natural gas produced in the U.S. by 2035 [6,7]. As production in- creases and new complex and difficult liquid streams Bryan D. Coday a , Pei Xu b , Edward G. Beaudry c , Jack Herron c Oasys Water, Boston, MA, USA H I G H L I G H T S · Highly impaired liquid streams can be sustainably

  4. Conversion of associated natural gas to liquid hydrocarbons. Final report, June 1, 1995--January 31, 1997

    SciTech Connect (OSTI)

    1997-12-31

    The original concept envisioned for the use of Fischer-Tropsch processing (FTP) of United States associated natural gas in this study was to provide a way of utilizing gas which could not be brought to market because a pipeline was not available or for which there was no local use. Conversion of gas by FTP could provide a means of utilizing offshore associated gas which would not require installation of a pipeline or re-injection. The premium quality F-T hydrocarbons produced by conversion of the gas can be transported in the same way as the crude oil or in combination (blended) with it, eliminating the need for a separate gas transport system. FTP will produce a synthetic crude oil, thus increasing the effective size of the resource. The two conventional approaches currently used in US territory for handling of natural gas associated with crude petroleum production are re-injection and pipelining. Conversion of natural gas to a liquid product which can be transported to shore by tanker can be accomplished by FTP to produce hydrocarbons, or by conversion to chemical products such as methanol or ammonia, or by cryogenic liquefaction (LNG). This study considers FTP and briefly compares it to methanol and LNG. The Energy International Corporation cobalt catalyst, ratio adjusted, slurry bubble column F-T process was used as the basis for the study and the comparisons. An offshore F-T plant can best be accommodated by an FPSO (Floating Production, Storage, Offloading vessel) based on a converted surplus tanker, such as have been frequently used around the world recently. Other structure types used in deep water (platforms) are more expensive and cannot handle the required load.

  5. Ethanol Conversion to Hydrocarbons on HZSM-5: Effect of Reaction Conditions and Si/Al Ratio on the Product Distributions

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2014-11-17

    The Conversion of ethanol to hydrocarbon over HZSM-5 zeolite with different Si/Al ratios was investigated under various reaction conditions. The catalyst with a higher Si/Al ratio (low acid density) deactivated faster and generated more unsaturated compounds at a similar time-on-stream. Temperature affects the catalytic activity with respect to liquid hydrocarbon generation and the hydrocarbon product composition. At lower temperatures (~300°C), the catalyst deactivated faster with respect to the liquid hydrocarbon formation. Higher temperatures (~400°C) reduced the formation of liquid range hydrocarbons and formed more gaseous fractions. Weight hourly space velocity was also found to affect product selectivity with higher weight hourly space velocity leading to a higher extent of ethylene formation. The experimental results were analyzed in terms of the product composition and the coke content with respect to catalyst time-on-stream and compared with the catalyst lifetime with respect to the variables tested on the conversion of ethanol to hydrocarbon.

  6. Thermal hydrocracking of heavy hydrocarbon oils with heavy oil recycle

    SciTech Connect (OSTI)

    Denis, J.D.; Khulbe, C.P.; Pruden, B.B.

    1981-02-24

    An improved process is described for the hydrocracking of heavy hydrocarbon oils, such as oils extracted from tar sands. The heavy hydrocarbon oil feedstock in the presence of an excess of hydrogen is passed through a confined hydrocracking zone under upflow liquid conditions, and the effluent emerging from the top of the hydrocracking zone is passed into a hot separator where it is separated into a gaseous stream containing hydrogen and vaporous hydrocarbons and a liquid stream containing heavy hydrocarbons. The hot separator is maintained near the temperature of the hydrocracking zone and the effluent from the hydrocracking zone enters the separator in a lower region below the liquid level in the separator. The gaseous stream containing hydrogen and vaporous hydrocarbons is withdrawn from the top of the separator while a portion of the liquid phase in the separator is recycled to the hydrocracking zone without further treatment and in quantities sufficient to increase the superficial liquid flow velocity in the hydrocracking zone such that deposition of coke in the hydrocracking zone is substantially eliminated.

  7. Review of Potential Candidate Stabilization Technologies for Liquid and Solid Secondary Waste Streams

    SciTech Connect (OSTI)

    Pierce, Eric M.; Mattigod, Shas V.; Westsik, Joseph H.; Serne, R. Jeffrey; Icenhower, Jonathan P.; Scheele, Randall D.; Um, Wooyong; Qafoku, Nikolla

    2010-01-30

    Pacific Northwest National Laboratory has initiated a waste form testing program to support the long-term durability evaluation of a waste form for secondary wastes generated from the treatment and immobilization of Hanford radioactive tank wastes. The purpose of the work discussed in this report is to identify candidate stabilization technologies and getters that have the potential to successfully treat the secondary waste stream liquid effluent, mainly from off-gas scrubbers and spent solids, produced by the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Down-selection to the most promising stabilization processes/waste forms is needed to support the design of a solidification treatment unit (STU) to be added to the Effluent Treatment Facility (ETF). To support key decision processes, an initial screening of the secondary liquid waste forms must be completed by February 2010.

  8. Optical reflectivity of solid and liquid methane: Application to spectroscopy of Titan's hydrocarbon lakes

    E-Print Network [OSTI]

    Jacobsen, Steven D.

    's hydrocarbon lakes Kimberly A. Adams,1 Steven D. Jacobsen,1 Zhenxian Liu,2 Sylvia-Monique Thomas,1,3 Maddury revealed dark patches in the surface reflectance at 2 and 5 mm, interpreted as hydrocarbon lakes forming) on dynamic planetary surfaces requires laboratory reflectance ratio measurements at relevant temperatures

  9. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 31 for fourth quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  10. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 19 for first quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  11. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 23 for second quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  12. Using benchmarking to minimize common DOE waste streams. Volume 1, Methodology and liquid photographic waste

    SciTech Connect (OSTI)

    Levin, V.

    1994-04-01

    Finding innovative ways to reduce waste streams generated at Department of Energy (DOE) sites by 50% by the year 2000 is a challenge for DOE`s waste minimization efforts. This report examines the usefulness of benchmarking as a waste minimization tool, specifically regarding common waste streams at DOE sites. A team of process experts from a variety of sites, a project leader, and benchmarking consultants completed the project with management support provided by the Waste Minimization Division EM-352. Using a 12-step benchmarking process, the team examined current waste minimization processes for liquid photographic waste used at their sites and used telephone and written questionnaires to find ``best-in-class`` industrv partners willing to share information about their best waste minimization techniques and technologies through a site visit. Eastman Kodak Co., and Johnson Space Center/National Aeronautics and Space Administration (NASA) agreed to be partners. The site visits yielded strategies for source reduction, recycle/recovery of components, regeneration/reuse of solutions, and treatment of residuals, as well as best management practices. An additional benefit of the work was the opportunity for DOE process experts to network and exchange ideas with their peers at similar sites.

  13. Direct production of fractionated and upgraded hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

    2014-08-26

    Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

  14. Apparatus and methods for direct conversion of gaseous hydrocarbons to liquids

    DOE Patents [OSTI]

    Kong, Peter C.; Lessing, Paul A.

    2006-04-25

    A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.

  15. Molecular catalytic hydrogenation of aromatic hydrocarbons and...

    Office of Scientific and Technical Information (OSTI)

    hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Citation Details In-Document Search Title: Molecular catalytic hydrogenation of aromatic hydrocarbons and...

  16. Supplementary Material A comparison of atomic-level and coarse-grained models for liquid hydrocarbons from

    E-Print Network [OSTI]

    Simons, Jack

    hydrocarbons from molecular dynamics configurational entropy estimates Riccardo Baron, Alex H. de Vries hydrocarbons. Entropies are calculated using 800 configurations collected over simulation periods of different contribution ( )r chs ch (Eq. (3)) of rotational entropy to the total entropy for hydrocarbon chains

  17. Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; French, Richard; Deutch, Steve; Iisa, Kristiina

    2014-08-14

    Hot-vapor filtered bio-oils were produced from two different biomass feedstocks, oak and switchgrass, and the oils were evaluated in hydroprocessing tests for production of liquid hydrocarbon products. Hot-vapor filtering reduced bio-oil yields and increased gas yields. The yields of fuel carbon as bio-oil were reduced by ten percentage points by hot-vapor filtering for both feedstocks. The unfiltered bio-oils were evaluated alongside the filtered bio-oils using a fixed bed catalytic hydrotreating test. These tests showed good processing results using a two-stage catalytic hydroprocessing strategy. Equal-sized catalyst beds, a sulfided Ru on carbon catalyst bed operated at 220°C and a sulfided CoMo on alumina catalyst bed operated at 400°C were used with the entire reactor at 100 atm operating pressure. The products from the four tests were similar. The light oil phase product was fully hydrotreated so that nitrogen and sulfur were below the level of detection, while the residual oxygen ranged from 0.3 to 2.0%. The density of the products varied from 0.80 g/ml up to 0.86 g/ml over the period of the test with a correlated change of the hydrogen to carbon atomic ratio from 1.79 down to 1.57, suggesting some loss of catalyst activity through the test. These tests provided the data needed to assess the suite of liquid fuel products from the process and the activity of the catalyst in relationship to the existing catalyst lifetime barrier for the technology.

  18. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-04-13

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreating the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.

  19. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elliott, Douglas C. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Wang, Huamin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Rover, Majorie [Iowa State University, Ames, IA (United States); Whitmer, Lysle [Iowa State University, Ames, IA (United States); Smith, Ryan [Iowa State University, Ames, IA (United States); Brown, Robert C. [Iowa State University, Ames, IA (United States)

    2015-05-04

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreating the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.

  20. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-04-13

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreatingmore »the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.« less

  1. Molecular catalytic hydrogenation of aromatic hydrocarbons and

    Office of Scientific and Technical Information (OSTI)

    catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. 01 COAL, LIGNITE, AND PEAT; 40 CHEMISTRY; COAL LIQUIDS;...

  2. Process for refractory compound rejection from a hydrocracker recycle liquid

    SciTech Connect (OSTI)

    Kalnes, T.N.

    1990-06-05

    This patent describes a catalytic hydrocracking process. It comprises: contacting a hydrocarbonaceous feedstock having a propensity to form heavy polynuclear aromatic compounds and a liquid recycle stream in a hydrocracking zone with added hydrogen and a metal promoted hydrocracking catalyst at elevated temperature and pressure sufficient to convert a substantial portion of the hydrocarbonaceous components in the feedstock to lower boiling products; and recovering a hydrocarbon effluent from the hydrocracking zone and partially condensing the hydrocarbon effluent from the hydrocracking zone and separating the same into a lower boiling hydrocarbon product stream and an unconverted hydrocarbon stream having at least a portion boiling above about 400{degrees} F. and comprising trace quantities of heavy polynuclear aromatic compounds.

  3. Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas

    DOE Patents [OSTI]

    Durai-Swamy, Kandaswamy (Culver City, CA)

    1982-01-01

    In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

  4. Effect of in-cylinder liquid fuel films on engine-out unburned hydrocarbon emissions for SI engines

    E-Print Network [OSTI]

    Costanzo, Vincent S. (Vincent Stanley), 1979-

    2011-01-01

    Nearly all of the hydrocarbon emissions from a modern gasoline-fueled vehicle occur when the engine is first started. One important contributing factor to this is the fact that, during this time, temperatures throughout ...

  5. High Performance Liquid Chromatography

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    HPLC MEASUREMENT OF POLYCYCLIC AROMATIC HYDROCARBONS IN CIGARETTE SMOKE INTRODUCTION Even thoughHPLC - 1 High Performance Liquid Chromatography HPLC MEASUREMENT OF POLYCYCLIC AROMATIC HYDROCARBONS IN CIGARETTE SMOKE Last updated: June 17, 2014 #12;HPLC - 2 High Performance Liquid Chromatography

  6. Process for minimizing solids contamination of liquids from coal pyrolysis

    DOE Patents [OSTI]

    Wickstrom, Gary H. (Yorba Linda, CA); Knell, Everett W. (Los Alamitos, CA); Shaw, Benjamin W. (Costa Mesa, CA); Wang, Yue G. (West Covina, CA)

    1981-04-21

    In a continuous process for recovery of liquid hydrocarbons from a solid carbonaceous material by pyrolysis of the carbonaceous material in the presence of a particulate source of heat, particulate contamination of the liquid hydrocarbons is minimized. This is accomplished by removing fines from the solid carbonaceous material feed stream before pyrolysis, removing fines from the particulate source of heat before combining it with the carbonaceous material to effect pyrolysis of the carbonaceous material, and providing a coarse fraction of reduced fines content of the carbon containing solid residue resulting from the pyrolysis of the carbonaceous material before oxidizing carbon in the carbon containing solid residue to form the particulate source of heat.

  7. Jet Streams Jet Streams

    E-Print Network [OSTI]

    Hennon, Christopher C.

    ATMS 310 Jet Streams Jet Streams A jet stream is an intense (30+ m/s in upper troposphere, 15+ m of air associated with strong (at least 5-10 ms-1 km-1 ) vertical wind shear. A Jet Streak is an isotach maximum embedded within a jet stream. Jet streams are mesoscale in the cross-flow direction and synoptic

  8. Comparative Study on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Hydrocarbon Fuel

    SciTech Connect (OSTI)

    Xie, Chao; Chen, Yongsheng; Engelhard, Mark H.; Song, Chunshan

    2012-04-18

    This work was conducted to clarify the influence of the type of metal and support on the sulfur tolerance and carbon resistance of supported noble metal catalysts in steam reforming of liquid hydrocarbons. Al2O3-supported noble metal catalysts (Rh, Ru, Pt, and Pd), Rh catalysts on different supports (Al2O3, CeO2, SiO2, and MgO), and Pt catalyst supported on CeO2 and Al2O3, were examined for steam reforming of a liquid hydrocarbon fuel (Norpar13 from Exxon Mobil) at 800 C for 55 h. The results indicate that (1) Rh/Al2O3 shows higher sulfur tolerance than the Ru, Pt, and Pd catalysts on the same support; (2) both Al2O3 and CeO2 are promising supports for Rh catalyst to process sulfur-containing hydrocarbons; and (3) Pt/CeO2 exhibits better catalytic performance than Pt/Al2O3 in the reaction with sulfur. TEM results demonstrate that the metal particles in Rh/Al2O3 were better dispersed (mostly in 1-3 nm) compared with the other catalysts after reforming the sulfur-containing feed. As revealed by XPS, the binding energy of Rh 3d for Rh/Al2O3 is notably higher than that for Rh/CeO2, implying the formation of electron-deficient Rh particles in the former. The strong sulfur tolerance of Rh/Al2O3 may be related to the formation of well-dispersed electron-deficient Rh particles on the Al2O3 support. Sulfur K-edge XANES illustrates the preferential formation of sulfonate and sulfate on Rh/Al2O3, which is believed to be beneficial for improving its sulfur tolerance as their oxygen-shielded sulfur structure may hinder direct Rh-S interaction. Due to its strong sulfur tolerance, the carbon deposition on Rh/Al2O3 was significantly lower than that on the Al2O3-supported Ru, Pt, and Pd catalysts after the reaction with sulfur. The superior catalytic performance of CeO2-supported Rh and Pt catalysts in the presence of sulfur can be ascribed mainly to the promotion effect of CeO2 on carbon gasification, leading to much lower carbon deposition compared with the Rh/Al2O3, Rh/MgO, Rh/SiO2 and Pt/Al2O3 catalysts.

  9. Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

    2012-08-19

    The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

  10. Analysis of Ultrasonic Velocities in Hydrocarbon Mixtures

    E-Print Network [OSTI]

    of measurements on ultrasonic velocities of liquid hydrocarbons and mixtures. They found that their dataAnalysis of Ultrasonic Velocities in Hydrocarbon Mixtures James G. Berryman Lawrence Livermore on hydrocarbon mixtures was shown by Wang and Nur [JASA 89, 2725 (1991)] to agree quite well with the predictions

  11. Hydrocarbon conversion

    SciTech Connect (OSTI)

    Koepke, J.W.; Abdo, S.F.

    1989-10-03

    This patent describes a hydrocracking process. It comprises: catalyzing a hydrocracking reaction by contacting a hydrocarbon feedstock with a hydrocracking catalyst under hydrocracking conditions to produce a product hydrocarbon having an increased octane number than the hydrocarbon feedstock. The hydrocracking catalyst consists essentially of at least one niobium component, at least one Group VIII metal component and at least one cracking component.

  12. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA); Lee, Lap-Keung (Cranbury, NJ)

    2001-01-01

    A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

  13. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, E.

    1995-05-23

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

  14. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  15. Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation 

    E-Print Network [OSTI]

    Adegoke, Adesola Ayodeji

    2006-10-30

    provides middle distillates to an unsaturated global market and offers opportunities to generate power for commercial purposes from waste by-product streams, which normally are associated with increased expenses incurred from additional...

  16. Inventory of miscellaneous streams

    SciTech Connect (OSTI)

    Lueck, K.J.

    1995-09-01

    On December 23, 1991, the US Department of Energy, Richland Operations Office (RL) and the Washington State Department of Ecology (Ecology) agreed to adhere to the provisions of the Department of Ecology Consent Order. The Consent Order lists the regulatory milestones for liquid effluent streams at the Hanford Site to comply with the permitting requirements of Washington Administrative Code. The RL provided the US Congress a Plan and Schedule to discontinue disposal of contaminated liquid effluent into the soil column on the Hanford Site. The plan and schedule document contained a strategy for the implementation of alternative treatment and disposal systems. This strategy included prioritizing the streams into two phases. The Phase 1 streams were considered to be higher priority than the Phase 2 streams. The actions recommended for the Phase 1 and 2 streams in the two reports were incorporated in the Hanford Federal Facility Agreement and Consent Order. Miscellaneous Streams are those liquid effluents streams identified within the Consent Order that are discharged to the ground but are not categorized as Phase 1 or Phase 2 Streams. This document consists of an inventory of the liquid effluent streams being discharged into the Hanford soil column.

  17. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

    DOE Patents [OSTI]

    Dumesic, James A. (Verona, WI); Ruiz, Juan Carlos Serrano (Madison, WI); West, Ryan M. (Madison, WI)

    2012-04-03

    Described is a method to make liquid chemicals, such as functional intermediates, solvents, and liquid fuels from biomass-derived cellulose. The method is cascading; the product stream from an upstream reaction can be used as the feedstock in the next downstream reaction. The method includes the steps of deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be converted to a mixture of n-butenes. The pentanoic acid so formed can be further reacted to yield a host of valuable products. For example, the pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes. Alternatively, the nonene may be isomerized to yield a mixture of branched olefins, which can be hydrogenated to yield a mixture of branched alkanes. The mixture of n-butenes formed from .gamma.-valerolactone can also be subjected to isomerization and oligomerization to yield olefins in the gasoline, jet and Diesel fuel ranges.

  18. The fluorescence action spectra of some saturated hydrocarbon liquids for excitation energies above and below their ionization thresholds

    SciTech Connect (OSTI)

    Ostafin, A.E.; Lipsky, S. )

    1993-04-01

    Fluorescence action spectra have been obtained for the neat liquids, [ital cis]-decalin, [ital trans]-decalin, bicyclohexyl, cyclohexane, methylcyclohexane, isobutylcyclohexane, 2,3,4-trimethylpentane, 2,3-dimethylbutane, 3-methylhexane, 3-methylpentane, [ital n]-decane, [ital n]-dodecane, and [ital n]-pentadecane at excitation energies, [epsilon], ranging from their absorption onsets (at ca. 7 eV) to 10.3 eV. For all compounds, with the exception of [ital cis]-decalin, the fluorescence quantum yield is observed to monotonically decline with increasing [epsilon], reaching a minimum value at an energy, [epsilon][sub [ital m

  19. Enrichment of light hydrocarbon mixture

    DOE Patents [OSTI]

    Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

    2011-11-29

    Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

  20. Enrichment of light hydrocarbon mixture

    DOE Patents [OSTI]

    Yang; Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

    2010-08-10

    Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

  1. Assessment of natural and anthropogenic hydrocarbon inputs using PAHs as tracers.

    E-Print Network [OSTI]

    amounts of hydrocarbon compounds though combustion (liquid fuels, coal and wood), discharge of petroleum hydrocarbon sources from human activities including oil and refined oil products, burning of coal, liquid

  2. Proceedings of waste stream minimization and utilization innovative concepts: An experimental technology exchange. Volume 2, Industrial liquid waste processing, industrial gaseous waste processing

    SciTech Connect (OSTI)

    Lee, V.E. [ed.; Watts, R.L.

    1993-04-01

    This two-volume proceedings summarize the results of fifteen innovations that were funded through the US Department of Energy`s Innovative Concept Program. The fifteen innovations were presented at the sixth Innovative Concepts Fair, held in Austin, Texas, on April 22--23, 1993. The concepts in this year`s fair address innovations that can substantially reduce or use waste streams. Each paper describes the need for the proposed concept, the concept being proposed, and the concept`s economics and market potential, key experimental results, and future development needs. The papers are divided into two volumes: Volume 1 addresses innovations for industrial solid waste processing and municipal waste reduction/recycling, and Volume 2 addresses industrial liquid waste processing and industrial gaseous waste processing. Individual reports are indexed separately.

  3. Conversion of cellulosic wastes to liquid fuels

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-09-01

    The current status and future plans for a project to convert waste cellulosic (biomass) materials to quality liquid hydrocarbon fuels is described. The basic approach is indirect liquefaction, i.e., thermal gasification followed by catalytic liquefaction. The indirect approach results in separation of the oxygen in the biomass feedstock, i.e., oxygenated compounds do not appear in the liquid hydrocarbon fuel product. The process is capable of accepting a wide variety of feedstocks. Potential products include medium quality gas, normal propanol, diesel fuel and/or high octane gasoline. A fluidized bed pyrolysis system is used for gasification. The pyrolyzer can be fluidized with recycle pyrolysis gas, steam or recycle liquefaction system off gas or some combination thereof. Tars are removed in a wet scrubber. Unseparated pyrolysis gases are utilized as feed to a modified Fischer-Tropsch reactor. The liquid condensate from the reactor consists of a normal propanol-water phase and a paraffinic hydrocarbon phase. The reactor can be operated to optimize for either product. The following tasks were specified in the statement of work for the contract period: (1) feedstock studies; (2) gasification system optimization; (3) waste stream characterization; and (4) liquid fuels synthesis. In addition, several equipment improvements were implemented.

  4. Method for producing viscous hydrocarbons

    DOE Patents [OSTI]

    Poston, Robert S. (Winter Park, FL)

    1982-01-01

    A method for recovering viscous hydrocarbons and synthetic fuels from a subterranean formation by drilling a well bore through the formation and completing the well by cementing a casing means in the upper part of the pay zone. The well is completed as an open hole completion and a superheated thermal vapor stream comprised of steam and combustion gases is injected into the lower part of the pay zone. The combustion gases migrate to the top of the pay zone and form a gas cap which provides formation pressure to produce the viscous hydrocarbons and synthetic fuels.

  5. Development of a Conceptual Process for Selective CO{sub 2} Capture from Fuel Gas Streams Using [hmim][Tf2N] Ionic Liquid as a Physical Solvent

    SciTech Connect (OSTI)

    Basha, Omar M.; Keller, Murphy J.; Luebke, David R.; Resnik, Kevin; P Morsi, Badie I.

    2013-07-01

    The Ionic Liquid (IL) [hmim][Tf2N] was used as a physical solvent in an Aspen Plus simulation, employing the Peng-Robinson Equation of State (P-R EOS) with Boston-Mathias (BM) alpha function and standard mixing rules, to develop a conceptual process for CO{sub 2} capture from a shifted warm fuel gas stream produced from Pittsburgh # 8 coal for a 400 MWe power plant. The physical properties of the IL, including density, viscosity, surface tension, vapor pressure and heat capacity were obtained from literature and modeled as a function of temperature. Also, available experimental solubility values for CO{sub 2}, H{sub 2}, H{sub 2}S, CO, and CH{sub 4} in this IL were compiled and their binary interaction parameters ({delta}{sub ij} and l{sub ij}) were optimized and correlated as functions of temperature. The Span-Wager Equation-of-State EOS was also employed to generate CO{sub 2} solubilities in [hmim][Tf2N] at high pressures (up to 10 MPa) and temperatures (up to 510 K). The conceptual process developed consisted of 4 adiabatic absorbers (2.4 m ID, 30 m high) arranged in parallel and packed with Plastic Pall Rings of 0.025 m for CO{sub 2} capture; 3 flash drums arranged in series for solvent (IL) regeneration with the pressure-swing option; and a pressure-intercooling system for separating and pumping CO{sub 2} up to 153 bar to the sequestration sites. The compositions of all process streams, CO{sub 2} capture efficiency, and net power were calculated using Aspen Plus simulator. The results showed that, based on the composition of the inlet gas stream to the absorbers, 95.67 mol% of CO{sub 2} was captured and sent to sequestration sites; 99.5 mol% of H{sub 2} was separated and sent to turbines; the solvent exhibited a minimum loss of 0.31 mol%; and the net power balance of the entire system was 30.81 MW. These results indicated that [hmim][Tf2N] IL could be used as a physical solvent for CO{sub 2} capture from warm shifted fuel gas streams with high efficiency.

  6. Coal liquefaction process streams characterization and evaluation: Application of liquid chromatographic separation methods to THF-soluble portions of integrated two-stage coal liquefaction resids

    SciTech Connect (OSTI)

    Green, J.B.; Pearson, C.D.; Young, L.L.; Green, J.A. )

    1992-05-01

    This study demonstrated the feasibility of using non-aqueous ion exchange liquid chromatography (NIELC) for the examination of the tetrahydrofuran (THF)-soluble distillation resids and THF-soluble whole oils derived from direct coal liquefaction. The technique can be used to separate the material into a number of acid, base, and neutral fractions. Each of the fractions obtained by NIELC was analyzed and then further fractionated by high-performance liquid chromatography (HPLC). The separation and analysis schemes are given in the accompanying report. With this approach, differences can be distinguished among samples obtained from different process streams in the liquefaction plant and among samples obtained at the same sampling location, but produced from different feed coals. HPLC was directly applied to one THF-soluble whole process oil without the NIELC preparation, with limited success. The direct HPLC technique used was directed toward the elution of the acid species into defined classes. The non-retained neutral and basic components of the oil were not analyzable by the direct HPLC method because of solubility limitations. Sample solubility is a major concern in the application of these techniques.

  7. Apparatus for hydrocarbon extraction

    DOE Patents [OSTI]

    Bohnert, George W.; Verhulst, Galen G.

    2013-03-19

    Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

  8. Method for enhanced atomization of liquids

    DOE Patents [OSTI]

    Thompson, Richard E. (27121 Puerta del Oro, Mission Viejo, CA 92691); White, Jerome R. (44755 Wyandotte, Hemet, CA 92544)

    1993-01-01

    In a process for atomizing a slurry or liquid process stream in which a slurry or liquid is passed through a nozzle to provide a primary atomized process stream, an improvement which comprises subjecting the liquid or slurry process stream to microwave energy as the liquid or slurry process stream exits the nozzle, wherein sufficient microwave heating is provided to flash vaporize the primary atomized process stream.

  9. Syngas Conversion to Gasoline-Range Hydrocarbons over Pd/ZnO/Al2O3 and ZSM-5 Composite Catalyst System

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lizarazo Adarme, Jair A.; Lebarbier, Vanessa MC; Gray, Michel J.; White, James F.; King, David L.; Palo, Daniel R.

    2014-07-01

    A composite Pd/ZnO/Al2O3-HZSM-5 (Si/Al=40) catalytic system was evaluated for the synthesis of gasoline-range hydrocarbons directly from synthesis gas. Bifunctional catalyst comprising PdZn metal and acid sites present the required catalytically active sites necessary for the methanol synthesis, methanol dehydration, and methanol-to-gasoline reactions. This system provides a unique catalytic pathway for the production of liquid hydrocarbons directly from syngas. However, selectivity control is difficult and poses many challenges. The composite catalytic system was evaluated under various process conditions. Investigated were the effects of temperature (310-375oC), pressure (300-1000 psig), time-on-stream (50 hrs), and gas-hour space velocity (740-2970 hr-1), using a H2/CO molar syngas ratio of 2.0. By operating at the lower end of the temperature range investigated, liquid hydrocarbon formation was favored, as was decreased amounts of undesirable light hydrocarbons. However, lower operating temperatures also facilitated undesirable CO2 formation via the water-gas shift reaction. Higher operating pressures slightly favored liquid synthesis. Operating at relatively low pressures (e.g. 300 psig) was made possible, whereas for methanol synthesis alone higher pressure are usually required to achieve similar conversion levels (e.g. 1000 psig). Thermodynamic constraints on methanol synthesis are eased by pushing the equilibrium through hydrocarbon formation. Catalytic performance was also evaluated by altering Pd and Zn composition of the Pd/ZnO/Al2O3 catalyst. Of the catalysts and conditions tested, selectivity toward liquid hydrocarbon was highest when using a 5% Pd metal loading and Pd/Zn molar ratio of 0.25 and mixed with HZMS-5, operating at 310oC and 300 psig, CO conversion was 43 % and selectivity (carbon weight basis) to hydrocarbons was 49 wt. %. Of the hydrocarbon fraction, 44wt. % was in the C5-C12 liquid product range and consisted primarily of aromatic polymethylbenzenes. However, as syngas conversion increases with increasing temperature, selectivity to liquid product diminished. This is attributed, in large part, to increased saturation of the olefinic intermediates over PdZn metal sites. Under all the conditions and catalysts evaluated in this study, generating liquid product in high yield was challenging (<10 wt. % C5+ yield).

  10. Reduction of Hydrocarbon Losses to Flare Systems 

    E-Print Network [OSTI]

    Page, J.

    1979-01-01

    action to minimize hydrocarbon releases, 2) install flare gas recovery systems, and 3) recover or reduce process streams which have to be continuous1y vented to the flare system. This report discusses alternate designs for flare gas monitoring and flare...

  11. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01

    LBL-8596 itr-t C,d.. HYDROCARBONS & ENERGY FROM PLANTS jmethods of isolating the hydrocarbon-like material from I.privatelyownedrights. HYDROCARBONS AND ENERGY FROM PLANTS

  12. Partial oxidation process for producing a stream of hot purified gas

    DOE Patents [OSTI]

    Leininger, Thomas F. (Chino Hills, CA); Robin, Allen M. (Anaheim, CA); Wolfenbarger, James K. (Torrance, CA); Suggitt, Robert M. (Wappingers Falls, NY)

    1995-01-01

    A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.

  13. Partial oxidation process for producing a stream of hot purified gas

    DOE Patents [OSTI]

    Leininger, T.F.; Robin, A.M.; Wolfenbarger, J.K.; Suggitt, R.M.

    1995-03-28

    A partial oxidation process is described for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H{sub 2}, CO, CO{sub 2}, H{sub 2}O, CH{sub 4}, NH{sub 3}, HCl, HF, H{sub 2}S, COS, N{sub 2}, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N{sub 2} and H{sub 2}. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000 F. 1 figure.

  14. Removing sulphur oxides from a fluid stream

    DOE Patents [OSTI]

    Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

    2014-04-08

    A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

  15. Single-reactor process for producing liquid-phase organic compounds from biomass

    DOE Patents [OSTI]

    Dumesic, James A.; Simonetti, Dante A.; Kunkes, Edward L.

    2015-12-08

    Disclosed is a method for preparing liquid fuel and chemical intermediates from biomass-derived oxygenated hydrocarbons. The method includes the steps of reacting in a single reactor an aqueous solution of a biomass-derived, water-soluble oxygenated hydrocarbon reactant, in the presence of a catalyst comprising a metal selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Mo, Tc, Ru, Rh, Pd, Ag, W, Re, Os, Ir, Pt, and Au, at a temperature, and a pressure, and for a time sufficient to yield a self-separating, three-phase product stream comprising a vapor phase, an organic phase containing linear and/or cyclic mono-oxygenated hydrocarbons, and an aqueous phase.

  16. Single-reactor process for producing liquid-phase organic compounds from biomass

    DOE Patents [OSTI]

    Dumesic, James A. (Verona, WI); Simonetti, Dante A. (Middleton, WI); Kunkes, Edward L. (Madison, WI)

    2011-12-13

    Disclosed is a method for preparing liquid fuel and chemical intermediates from biomass-derived oxygenated hydrocarbons. The method includes the steps of reacting in a single reactor an aqueous solution of a biomass-derived, water-soluble oxygenated hydrocarbon reactant, in the presence of a catalyst comprising a metal selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Mo, Tc, Ru, Rh, Pd, Ag, W, Re, Os, Ir, Pt, and Au, at a temperature, and a pressure, and for a time sufficient to yield a self-separating, three-phase product stream comprising a vapor phase, an organic phase containing linear and/or cyclic mono-oxygenated hydrocarbons, and an aqueous phase.

  17. Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

    1981-02-19

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  18. ADHESION FORCES BETWEEN MICA SURFACES IN UNDERSATURATED VAPORS OF HYDROCARBONS

    E-Print Network [OSTI]

    Matsuoka, Hiroshige

    ADHESION FORCES BETWEEN MICA SURFACES IN UNDERSATURATED VAPORS OF HYDROCARBONS H. MATSUOKA1 , T] or meniscus force [3], which have been neglected in the conventional and relatively large mechani- cal systems forces between mica surfaces in under- saturated vapors of several kind of hydrocarbon liquids are mea

  19. Process for removing carbonyl sulfide from hydrocarbon feedstreams

    SciTech Connect (OSTI)

    Holmes, E.S.; Kosseim, A.J.

    1992-04-14

    This patent describes a process for removing carbon dioxide, hydrogen sulfide and carbonyl sulfide from a feedstream containing carbon dioxide, hydrogen sulfide and carbonyl sulfide and hydrocarbons. It comprises: contacting the feedstream in a hydrolysis zone with a first portion of a lean solution stream comprising an aqueous alkaline solution at an effective hydrolysis temperature to convert at least a portion of the carbonyl sulfide to carbon dioxide and hydrogen sulfide, withdrawing a first effluent stream containing a reduced concentration of carbonyl sulfide relative to the feedstream, and withdrawing a first rich solution stream comprising the aqueous alkaline solution, carbon dioxide and hydrogen sulfide; contacting the first effluent stream in an absorption zone with a second portion of the lean solution stream at an effective absorption temperature to absorb carbon dioxide and hydrogen sulfide, and withdrawing a second rich solution stream comprising the aqueous alkaline solution, carbon dioxide and hydrogen sulfide; combining at least a portion of the first rich solution stream and the second rich solution stream and contacting the combined rich solution stream in a regeneration zone at effective conditions to desorb carbon dioxide and hydrogen sulfide, withdrawing a vent gas stream comprising carbon dioxide and hydrogen sulfide, and withdrawing the lean solution stream; separating the lean solution stream into the first and second portions; and recycling the first portion of the lean solution stream to the hydrolysis zone and the second portion of the lean solution stream to the absorption zone.

  20. Recovery of co-adsorbed hydrocarbons from molecular sieve adsorption units

    SciTech Connect (OSTI)

    Clark, K.R.

    1990-11-20

    This patent describes a process for removing carbonyl sulfide from a hydrocarbon feedstock. It comprises: providing a feedstock of hydrocarbons; passing the feedstock in the liquid phase; terminating the passage; draining the bed; concurrently to the direction of flow into the bed; recovering the hydrocarbon; and regenerating the adsorption bed.

  1. Hydrocarbon in Catalyst in

    E-Print Network [OSTI]

    Ladkin, Peter B.

    #12;Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure controller Computer;#12;Vent 1 Vent 2 Product outHydrocarbon in Steam in Catalyst in light Warning Computer controller Tank

  2. Hydrocarbon in Catalyst in

    E-Print Network [OSTI]

    Ladkin, Peter B.

    Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure #12;#12;#12;#12;#12;#12;#12;#12;Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure controller Computer operator

  3. Conversion of cellulosic wastes to liquid hydrocarbon fuels: Vol. 6, The modeling and design of a staged indirect liquefaction reactor: Final report

    SciTech Connect (OSTI)

    Kuester, J.L.

    1986-11-01

    A staged reactor was designed to convert biomass to useful fuels. The reactor consists of three stages. The first stage is a concentric combustor/pyrolyzer system where the biomass is gasified in a fluidized bed at high temperatures in the absence of oxygen. The second stage is a cyclonic scrubber where particulates and condensable materials are removed from the gas stream while the gas is cooled. In the final stage the gas undergoes a Fischer-Tropsch synthesis in a fluidized bed or slurry reactor. Mathematical models of the system were developed and used to create computer programs that would predict the behavior of the bed. The models were based on fundamental phenomena and were used to predict key dimensions of the staged reactor system. A transparent plastic, full-scale, cold flow reactor simulator was built using the models' predictions. The simulator was used to refine the models and determine the operating characteristics of the reactor. The design was determined to be workable and potentially useful. The reactor was, however, difficult to operate and would require extensive automated control systems.

  4. Continuous removal of polynuclear aromatics from hydrocarbon recycle oil

    SciTech Connect (OSTI)

    Bosserman, P.J.; Taniguchi, V.T.

    1992-06-23

    This patent describes an oil refining process. It comprises forming a liquid capable of solubilizing aromatic compounds having at least about 5 fused aromatic rings; and catalytically hydrocracking a hydrocarbon feedstock by: contacting the feedstock in a hydrocracking zone with added hydrogen and a hydrocracking zone with added hydrogen and a hydrocracking catalyst at a temperature and pressure sufficient to give a substantial conversion to lower boiling products; and condensing a hydrocarbon effluent from the hydrocracking zone and separating the condensed effluent into (AA) a low boiling hydrocarbon product and (BB) an unconverted hydrocarbon oil containing one or more fused polynuclear aromatic compounds.

  5. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

    DOE Patents [OSTI]

    Dumesic, James A [Verona, WI; Ruiz, Juan Carlos Serrano [Madison, WI; West, Ryan M [Madison, WI

    2014-01-07

    Described is a method to make liquid chemicals. The method includes deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be conveted to a mixture of n-butenes. The pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes.

  6. NATURAL MARINE HYDROCARBON SEEPAGE

    E-Print Network [OSTI]

    Luyendyk, Bruce

    oil and gas (Fischer, 1977).The offshore gaseous seepage is controlled Geology; November 1999; v. 27; no. 11; p. 1047­1050; 4 figures. 1047 Decrease in natural marine hydrocarbon seepage near Coal OilNATURAL MARINE HYDROCARBON SEEPAGE Hydrocarbon seepage from the world's conti- nental shelves

  7. 2, 16451664, 2005 Hydrocarbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 2, 1645­1664, 2005 Hydrocarbon emissions from a boreal fen S. Haapanala et al. Title Page Discussions is the access reviewed discussion forum of Biogeosciences Measurements of hydrocarbon emissions Hydrocarbon emissions from a boreal fen S. Haapanala et al. Title Page Abstract Introduction Conclusions

  8. Is cyclobutane a hydrocarbon?

    E-Print Network [OSTI]

    Martin, Ralph R.

    Is cyclobutane a hydrocarbon? Biologically interesting entities possibly > 1,000,000 Does cyclobutane have a four- membered ring? Is cyclobutane a hydrocarbon? Expressive and decidable formalism needs to be classified under chemical classes: Is dinitrogen inorganic? Is acetylene a hydrocarbon

  9. Anaerobic Hydrocarbon Degradation in

    E-Print Network [OSTI]

    Bruns, Tom

    Anaerobic Hydrocarbon Degradation in Petroleum-Contaminated Harbor Sediments under Sulfate of iron(III) oxide to stimulate in- situ hydrocarbon degradation in anaerobic petroleum- contaminated did not stimulate anaerobic hydrocarbon oxidation. Exposure of the sediment to air [to reoxidize Fe

  10. Hydrocracking and recovering polynuclear aromatic compounds in slop wax stream

    SciTech Connect (OSTI)

    Gruia, A.J.

    1987-10-06

    This patent describes a catalytic hydrocracking process which comprises: (a) introducing a reduced crude into a fractionation zone to produce a vacuum gas oil stream having a propensity to form polynuclear aromatic compounds in a hydrocracking zone and a slop wax stream; (b) contacting the vacuum gas oil stream in a hydrocracking zone with added hydrogen and a metal promoted hydrocracking catalyst at elevated temperature and pressure sufficient to gain a substantial conversion to lower boiling products; (c) partially condensing the hydrocarbon effluent from the hydrocracking zone and separating the same into a low boiling hydrocarbon product stream and an unconverted hydrocarbon stream boiling above about 650/sup 0/F (343/sup 0/C) and containing trace quantities of polynuclear aromatic compounds; and (d) introducing at least a portion of the unconverted hydrocarbon stream containing polynuclear aromatic compounds into the fractionation zone thereby recovering a substantial portion of the polynuclear aromatic compounds in the slop wax stream which significantly minimizes the introduction of the polynuclear aromatic compounds into the hydrocracking zone.

  11. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Hyatt, David E. (Denver, CO); Bustard, Cynthia Jean (Littleton, CO); Sjostrom, Sharon (Denver, CO)

    1998-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  12. Engineering Chlorinated hydrocarbons such as

    E-Print Network [OSTI]

    Chemical Engineering Abstract Chlorinated hydrocarbons such as trichloroethylene (TCE) form a class carriers/supports for NZVI particles to address the in situ remediation of chlorinated hydrocarbons. We

  13. Microplasma Ball Reactor for Liquid Hydrocarbon Conversion 

    E-Print Network [OSTI]

    Slavens, Stephen M

    2014-04-24

    As the world’s light oil reserves diminish, the use of alternative fuels is becoming more of a necessity. In order to make use of alternative fuels, alternative processes must be developed. The goal of this research is to convert long, complex chain...

  14. Effective Viscosity of Confined Hydrocarbons

    E-Print Network [OSTI]

    I. M. Sivebaek; V. N. Samoilov; B. N. J. Persson

    2012-01-24

    We present molecular dynamics friction calculations for confined hydrocarbon films with molecular lengths from 20 to 1400 carbon atoms. We find that the logarithm of the effective viscosity \\mu eff for nanometer-thin films depends linearly on the logarithm of the shear rate: log(effective viscosity) = C - n log (shear rate), where n varies from 1 (solidlike friction) at very low temperatures to 0 (Newtonian liquid) at very high temperatures, following an inverse sigmoidal curve. Only the shortest chain molecules melt, whereas the longer ones only show a softening in the studied temperature interval 0 < T < 900 K. The results are important for the frictional properties of very thin (nanometer) films and to estimate their thermal durability.

  15. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Funk, Edward W. (Highland Park, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Des Plaines, IL)

    1986-01-01

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture over a polymeric membrane which comprises a polymer capable of maintaining its integrity in the presence of hydrocarbon compounds at temperature ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psi. The membranes which possess pore sizes ranging from about 10 to about 500 Angstroms are cast from a solvent solution and recovered.

  16. Process for removal of carbonyl sulfide in liquified hydrocarbon gases with absorption of acid gases

    SciTech Connect (OSTI)

    Beavon, D.K.; Mackles, M.

    1980-11-11

    Liquified hydrocarbon gases containing at least carbonyl sulfide as an impurity are purified by intimately mixing the liquified hydrocarbon gas with an aqueous absorbent for hydrogen sulfide in a hydrolysis zone maintained at a temperature and a pressure sufficient to maintain the liquified hydrocarbon gas in the liquid state and hydrolyze the carbonyl sulfide to hydrogen sulfide and carbon dioxide. The liquified hydrocarbon gas containing at least a portion of the formed carbonyl sulfide and carbon dioxide is separated from the liquid absorbent and passed to an absorption zone where it is contacted with a liquid hydrogen sulfide absorbent where at least the formed hydrogen sulfide is separated from the liquified petroleum gas. A stage of absorption of at least hydrogen sulfide may proceed mixing of the liquified hydrocarbon gas with the absorbent in the hydrolysis reaction zone. The absorbent employed does not combine irreversibly with carbonyl sulfide, hydrogen sulfide, and carbon dioxide, and preferably is an aqueous solution of diethanolamine.

  17. Method of purifying a gas stream using 1,2,3-triazolium ionic...

    Office of Scientific and Technical Information (OSTI)

    Method of purifying a gas stream using 1,2,3-triazolium ionic liquids Citation Details In-Document Search Title: Method of purifying a gas stream using 1,2,3-triazolium ionic...

  18. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    molecular weights of various hydrocarbon materials for fuelof oil and alcohol from hydrocarbon-producing plants. Into Die Naturwissenschaften HYDROCARBONS FROM PLANTS: METHODS

  19. Secondary Organic Aerosol Formation From Aromatic Hydrocarbon

    E-Print Network [OSTI]

    Tang, Ping

    2013-01-01

    Jimenez, J.L. , 2005. Hydrocarbon- like and oxygenatedoxidation of aromatic hydrocarbons in the presence of drySummary of aromatic hydrocarbon photooxidation experiments

  20. Hydrocarbon characterization experiments in fully turbulent fires.

    SciTech Connect (OSTI)

    Ricks, Allen; Blanchat, Thomas K.

    2007-05-01

    As the capabilities of numerical simulations increase, decision makers are increasingly relying upon simulations rather than experiments to assess risks across a wide variety of accident scenarios including fires. There are still, however, many aspects of fires that are either not well understood or are difficult to treat from first principles due to the computational expense. For a simulation to be truly predictive and to provide decision makers with information which can be reliably used for risk assessment the remaining physical processes must be studied and suitable models developed for the effects of the physics. The model for the fuel evaporation rate in a liquid fuel pool fire is significant because in well-ventilated fires the evaporation rate largely controls the total heat release rate from the fire. A set of experiments are outlined in this report which will provide data for the development and validation of models for the fuel regression rates in liquid hydrocarbon fuel fires. The experiments will be performed on fires in the fully turbulent scale range (> 1 m diameter) and with a number of hydrocarbon fuels ranging from lightly sooting to heavily sooting. The importance of spectral absorption in the liquid fuels and the vapor dome above the pool will be investigated and the total heat flux to the pool surface will be measured. The importance of convection within the liquid fuel will be assessed by restricting large scale liquid motion in some tests. These data sets will provide a sound, experimentally proven basis for assessing how much of the liquid fuel needs to be modeled to enable a predictive simulation of a fuel fire given the couplings between evaporation of fuel from the pool and the heat release from the fire which drives the evaporation.

  1. Effect of the Composition of Hydrocarbon Streams on HCCI Performance

    Broader source: Energy.gov [DOE]

    §To apply an advanced statistical analysis technique to 2D-GC data for 17 oil sands derived fuels and correlate results to measured fuel chemical / physical properties, and then to HCCI engine performance

  2. Hydrocarbon Reservoir Parameter Estimation Using

    E-Print Network [OSTI]

    van Vliet, Lucas J.

    Hydrocarbon Reservoir Parameter Estimation Using Production Data and Time-Lapse Seismic #12;#12;Hydrocarbon Reservoir Parameter Estimation Using Production Data and Time-Lapse Seismic PROEFSCHRIFT ter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 Recovery process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.3 Field

  3. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop: Agenda and Objectives Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop:...

  4. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, R.L.

    1997-03-11

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  5. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1997-01-01

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  6. Development of Advanced Membranes Technology Platform for Hydrocarbon Separations

    SciTech Connect (OSTI)

    Kalthod, Dr Dilip

    2010-03-01

    Virtually all natural gas is dehydrated during its production, transmission and storage, mostly by absorption processes. Membranes offer many potential advantages over absorption, including smaller footprints, lighter-weight packages, packaging flexibility, minimal electrical power duty, amenability to expansion due to system modularity, reduced maintenance costs, reduced emissions of heavy hydrocarbons, no liquid waste streams, and amenability to unmanned operation. The latter is particularly valuable because new natural gas sources are generally located in remote onshore and offshore sites. Most commercially-available membranes for natural gas upgrading involve high capital costs, high methane loss and performance degradation from operational upsets – all of which are barriers to their widespread adoption by the industry. The original focus of the project was to develop and demonstrate robust, high-performance membranes for natural gas dehydration. The first task completed was a user needs-and-wants study to 1) clarify the expectations of system fabricators and end users of the new separations equipment, and 2) establish the required technical and commercial targets for the membrane products. Following this, membrane system modeling and membrane development in the lab proceeded in parallel. Membrane module diameter and length, as well as and the fiber outer and inner fiber diameter, were optimized from a mathematical model that accounts for the relevant fluid dynamics and permeation phenomena. Module design was evaluated in the context of overall system design, capital costs and energy consumption, including the process scheme (particularly sweep generation), feed pretreatment, system layout, and process control. This study provided targets for membrane permeation coefficients and membrane geometry in a commercial offering that would be competitive with absorption systems. A commercially-available polymer with good tensile strength and chemical resistance was selected for membrane development. A novel dope composition and spinning process were developed, which provide a new approach to controlling membrane porosity and wall and skin morphology. A hollow-fiber membrane with an external dense “skin” was produced that has a high water vapor permeation coefficient and selectivity, durability when in operation at 1000 psig and 70°C, and the ability to withstand aromatic and aliphatic hydrocarbon vapors for an extended period. The fiber meets the technical requirements for a commercial product offering in gas dehydration. It can be readily manufactured with some changes in process equipment and process conditions, and is an excellent candidate for scale-up to full-size membrane modules.

  7. Liquid additives for particulate emissions control

    DOE Patents [OSTI]

    Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Hyatt, David E. (Denver, CO); Bustard, Cynthia Jean (Littleton, CO); Sjostrom, Sharon (Denver, CO)

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  8. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Jones, Susanne B.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

  9. Method and apparatus for producing oxygenates from hydrocarbons

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Lessing, Paul A. (Idaho Falls, ID)

    1995-01-01

    A chemical reactor for oxygenating hydrocarbons includes: a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed.

  10. Optrode for sensing hydrocarbons

    DOE Patents [OSTI]

    Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

    1987-05-19

    A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 6 figs.

  11. Hydrocarbonization research: completion report

    SciTech Connect (OSTI)

    Youngblood, E.L.; Cochran, H.D. Jr.; Westmoreland, P.R.; Brown, C.H. Jr.; Oswald, G.E.; Barker, R.E.

    1981-01-01

    Hydrocarbonization is a relatively simple process used for producing oil, substitute natural gas, and char by heating coal under a hydrogen-rich atmosphere. This report describes studies that were performed in a bench-scale hydrocarbonization system at Oak Ridge National Laboratory (ORNL) during the period 1975 to 1978. The results of mock-up studies, coal metering valve and flowmeter development, and supporting work in an atmospheric hydrocarbonization system are also described. Oil, gas, and char yields were determined by hydrocarbonization of coal in a 0.1-m-diam fluidized-bed reactor operated at a pressure of 2170 kPa and at temperatures ranging from 694 to 854 K. The nominal coal feed rate was 4.5 kg/h. Wyodak subbituminous coal was used for most of the experiments. A maximum oil yield of approx. 21% based on moisture- and ash-free (maf) coal was achieved in the temperature range of 810 to 840 K. Recirculating fluidized-bed, uniformly fluidized-bed, and rapid hydropyrolysis reactors were used. A series of operability tests was made with Illinois No. 6 coal to determine whether caking coal could be processed in the recirculating fluidized-bed reactor. These tests were generally unsuccessful because of agglomeration and caking problems; however, these problems were eliminated by the use of chemically pretreated coal. Hydrocarbonization experiments were carried out with Illinois No. 6 coal that had been pretreated with CaO-NaOH, Na/sub 2/CO/sub 3/, and CaO-Na/sub 2/CO/sub 3/. Oil yields of 14, 24, and 21%, respectively, were obtained from the runs with treated coal. Gas and char yield data and the composition of the oil, gas, and char products are presented.

  12. Method for cracking hydrocarbon compositions using a submerged reactive plasma system

    DOE Patents [OSTI]

    Kong, P.C.

    1997-05-06

    A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

  13. Method for cracking hydrocarbon compositions using a submerged reactive plasma system

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID)

    1997-01-01

    A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

  14. Stabilization of tokamak plasma by lithium streams L. E. Zakharov,

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    -boundary magnetohydrodynamic instabilities in tokamaks by liquid lithium streams driven by magnetic propulsion is formulated proposed a mechanism of magnetic propulsion for driving fast lithium streams along the plasma facing by an external power source and B is the tokamak magnetic #12;eld. The magnetic pressure, created in the uid

  15. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    DOE Patents [OSTI]

    Wilding, Bruce M; Turner, Terry D

    2014-12-02

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  16. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Chang, Y. Alice (Des Plaines, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

    1986-01-01

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture through a polymeric membrane. The membrane which is utilized to effect the separation comprises a polymer which is capable of maintaining its integrity in the presence of hydrocarbon compounds and which has been modified by being subjected to the action of a sulfonating agent. Sulfonating agents which may be employed will include fuming sulfuric acid, chlorosulfonic acid, sulfur trioxide, etc., the surface or bulk modified polymer will contain a degree of sulfonation ranging from about 15 to about 50%. The separation process is effected at temperatures ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psig.

  17. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  18. Ambient aromatic hydrocarbon measurements at Welgegund, South Africa

    E-Print Network [OSTI]

    2014-01-01

    Ambient aromatic hydrocarbon measurements at Welgegund,Ambient aromatic hydrocarbon measurements at Welgegund,Ambient aromatic hydrocarbon measurements at Welgegund,

  19. Low-Temperature Catalytic Process To Produce Hydrocarbons From Sugars

    DOE Patents [OSTI]

    Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

    2005-11-15

    Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as methanol, glycerol, sugars (e.g. glucose and xylose), or sugar alcohols (e.g. sorbitol). The method takes place in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.

  20. Method for determining processability of a hydrocarbon containing feedstock

    DOE Patents [OSTI]

    Schabron, John F.; Rovani, Jr., Joseph F.

    2013-09-10

    Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

  1. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Bustard, Cynthia Jean (Littleton, CO)

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  2. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1998-11-10

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  3. Separation, characterization and instrumental analysis of polynuclear aromatic hydrocarbon ring classes in petroleum

    SciTech Connect (OSTI)

    Chmielowiec, J.; Beshai, J.E.; George, A.E.

    1980-08-01

    To develop effective utilization technology for heavy streams from conventional fuels and unconventional resources such as heavy oils and oilsand bitumens, detailed information on the chemical composition of the feedstocks is needed. Attempts were made during the seventies to modify the API Project 60 scheme of analysis or to develop chemically more efficient, and less time-consuming, separation and characterization methods. These attempts aimed to improve characterization by separating the samples into concentrates of different structural types. Samples throughput was increased by using pressure and higher performance chromatographic systems. Other valuable contributions, such as coal-liquid characterization in terms of different chemical functionalities have also been made. The separation of aromatic ring classes and characterization or identification of their major components was our primary objective in this study. A silica-R(NH/sub 2/)/sub 2/-based HPLC system was used in our laboratory to study the analytical potential of this approach; the work was described in a previous publication. In the present study, the applicability of HPLC separation by this system and instrumental spectrometric characterization of 3- and 4-ring PAHs isolated from two Canadian oils were investigated. The oils used, Medicine River and Lloydminster, are examples of hydrocarbon-dominated materials representing light and heavy processing feedstocks, respectively.

  4. HYDROCARBON FORMATION ON POLYMER-SUPPORTED COBALT

    E-Print Network [OSTI]

    Benner, Linda S.

    2013-01-01

    NV~ August 25-29, 1980 HYDROCARBON FORMATION ON POLYMER-catalyzed reduction of CO to hydrocarbons Tropscb. Among theof CO to saturated linear hydrocarbons and appears to retain

  5. Engineering Chlorinated hydrocarbons such as trichloroethylene

    E-Print Network [OSTI]

    Chemical Engineering Abstract Chlorinated hydrocarbons such as trichloroethylene (TCE) form a class carriers/supports for NZVI particles to address the in situ remediation of chlorinated hydrocarbons. We Remediation of Chlorinated Hydrocarbons Dr. Vijay John Department of Chemical & Biomolecular Engineering

  6. HYDROCARBON CONSTITUENTS OF ICELAND LEAF FOSSIL

    E-Print Network [OSTI]

    Han, Jerry; Calvin, Melvin.

    2008-01-01

    L.S. (1962) Isoprenoid hydrocarbons in petroleum. Anal.and EVANS E. D. (1965) Hydrocarbons in non-reservo; r-rockVI. Distribution of wax hydrocarbons in plants at different

  7. Reclamation of potable water from mixed gas streams

    DOE Patents [OSTI]

    Judkins, Roddie R; Bischoff, Brian L; Debusk, Melanie Moses; Narula, Chaitanya

    2013-08-20

    An apparatus for separating a liquid from a mixed gas stream can include a wall, a mixed gas stream passageway, and a liquid collection assembly. The wall can include a first surface, a second surface, and a plurality of capillary condensation pores. The capillary condensation pores extend through the wall, and have a first opening on the first surface of the wall, and a second opening on the second surface of the wall. The pore size of the pores can be between about 2 nm to about 100 nm. The mixed gas stream passageway can be in fluid communication with the first opening. The liquid collection assembly can collect liquid from the plurality of pores.

  8. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop March 18, 2015 8:00AM EDT to...

  9. Biological Conversion of Sugars To Hydrocarbons | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Conversion of Sugars To Hydrocarbons Biological Conversion of Sugars To Hydrocarbons PDF explaining the biological process of bioenergy Biological Conversion of Sugars...

  10. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workshop held March 18-19, 2015. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production More Documents & Publications Enhanced Anaerobic Digestion and Hydrocarbon...

  11. MULTIPHOTON DISSOCIATION PRODUCTS FROM HALOGENATED HYDROCARBONS

    E-Print Network [OSTI]

    Sudbo, Aa. S.

    2011-01-01

    FROM HALOGENATED HYDROCARBONS RECE1VED Aa. S. Sudbo, P. A.FROM HALOGENATED HYDROCARBONS LBL-6966 Aa. S. Sudbo, t P. A.

  12. Hydrocarbon sensors and materials therefor

    DOE Patents [OSTI]

    Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

    2000-01-01

    An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

  13. Biofuel from Bacteria and Sunlight: Shewanella as an Ideal Platform for Producing Hydrocarbons

    SciTech Connect (OSTI)

    None

    2010-01-01

    Broad Funding Opportunity Announcement Project: The University of Minnesota is developing clean-burning, liquid hydrocarbon fuels from bacteria. The University is finding ways to continuously harvest hydrocarbons from a type of bacteria called Shewanella by using a photosynthetic organism to constantly feed Shewanella the sugar it needs for energy and hydrocarbon production. The two organisms live and work together as a system. Using Shewanella to produce hydrocarbon fuels offers several advantages over traditional biofuel production methods. First, it eliminates many of the time-consuming and costly steps involved in growing plants and harvesting biomass. Second, hydrocarbon biofuels resemble current petroleum-based fuels and would therefore require few changes to the existing fuel refining and distribution infrastructure in the U.S.

  14. Production of valuable hydrocarbons by flash pyrolysis of oil shale

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.T.

    1985-04-01

    A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

  15. Streams and Drainage Systems Stream Channel: natural passageway

    E-Print Network [OSTI]

    Gung, Yuancheng

    ;Base Level The stream's potential energy decreases as it flows downslope, and falls to zeroStreams and Drainage Systems #12; - / - - #12; - - - - #12; (Stream) #12;Stream Channel: natural passageway A stream's discharge may vary along the channel and through the time because

  16. CONFORMATION OF LIQUID N-ALKANES F. GOODSAID-ZALDUONDO AND D.M. ENGELMAN, Department ofMolecular

    E-Print Network [OSTI]

    be tested using changes in a measured parameter. THEORETICAL RESULTS A single hydrocarbon chain can the conformational forces present in membrane lipid interiors. We have studied hydrocarbon chains having lengths of packing in the liquid state do not change the conformational distributions of hydrocarbon chains from

  17. Characterization of industrial process waste heat and input heat streams

    SciTech Connect (OSTI)

    Wilfert, G.L.; Huber, H.B.; Dodge, R.E.; Garrett-Price, B.A.; Fassbender, L.L.; Griffin, E.A.; Brown, D.R.; Moore, N.L.

    1984-05-01

    The nature and extent of industrial waste heat associated with the manufacturing sector of the US economy are identified. Industry energy information is reviewed and the energy content in waste heat streams emanating from 108 energy-intensive industrial processes is estimated. Generic types of process equipment are identified and the energy content in gaseous, liquid, and steam waste streams emanating from this equipment is evaluated. Matchups between the energy content of waste heat streams and candidate uses are identified. The resultant matrix identifies 256 source/sink (waste heat/candidate input heat) temperature combinations. (MHR)

  18. Process for the production of ethylene and other hydrocarbons from coal

    DOE Patents [OSTI]

    Steinberg, Meyer (Huntington Station, NY); Fallon, Peter (East Moriches, NY)

    1986-01-01

    A process for the production of economically significant amounts of ethyl and other hydrocarbon compounds, such as benzene, from coal is disclosed wherein coal is reacted with methane at a temperature in the approximate range of 500.degree. C. to 1100.degree. C. at a partial pressure less than about 200 psig for a period of less than 10 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

  19. HYDROCARBONS FROM AUSTRALIAN OIL, 200 MILLION YEARS OLD

    E-Print Network [OSTI]

    Van Hoeven, William; Haug, Pat; Burlingame, A.L.; Calvin, Kelvin.

    1966-01-01

    of Moonie Oil "Branched- Cyclic" Hydrocarbon FractionNo. W -7405 -eng -48 HYDROCARBONS FROM AUSTRALIAN OIL, 200and Melvin Calvin July HYDROCARBONS FROM AUSTRALIAN OIL, 200

  20. Parenteral Hydrocarbon Injection and Associated Toxicities: Two Case Reports

    E-Print Network [OSTI]

    Nelson, Michael E.; Nasr, Isam

    2013-01-01

    Products Containing Hydrocarbons. JAMA. 1981;246:840–843.Tissue Injection of Hydrocarbons: A Case Report and Reviewand Nasr Parenteral Hydrocarbon Injection and Associated

  1. Name: ____________________ Stream Profile Lab 1

    E-Print Network [OSTI]

    exclusively to the stream 4) Hydraulic width (w): measure of the width of the wetted channel 5) Grain diameter (D): empirically measured diameter of stream bed grain (cobble, gravel, sand, etc.); equations.e., a stream with ample capacity--it's just that the stuff it's eroding is tough). 8) Unit stream power

  2. Thermal Regimes of Northeast Streams

    E-Print Network [OSTI]

    Thermal Loading (USGS) Stormwater and Streams ­ Optimizing Stormwater Management to Protect the Thermal

  3. Simultaneous demetalization and hydrocracking of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Belinko, K.; Packwood, R.H.; Patmore, D.J.; Ranganathan, R.

    1983-03-15

    A process is described for the simultaneous demetalization and hydrocracking of heavy hydrocarbon oils. The process permits the recovery of metals such as vanadium and nickel in an economic manner by passing a slurry of a heavy hydrocarbon oil and carbonaceous additive particles, such as coal, in the presence of hydrogen through a confined vertical hydrocracking zone at high temperatures and pressures. A mixed effluent containing a gaseous phase and a liquid phase is removed from the top of a hydrocracking zone, while there is removed from the bottom of the hydrocracking zone a portion of the hydrocracking zone contents containing carbonaceous remains of the additive particles to which is adsorbed the metal residues from the feedstock. The effluent removed from the top of the hydrocracking zone can be subsequently fed directly to a catalytic hydrocracking unit.

  4. Liquid additives for particulate emissions control

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1999-01-05

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  5. Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases

    DOE Patents [OSTI]

    Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

    2001-01-01

    Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

  6. Biological enhancement of hydrocarbon extraction

    DOE Patents [OSTI]

    Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

    2009-01-06

    A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

  7. Power extraction from a hot stream in the presence of phase change

    E-Print Network [OSTI]

    Ordonez, Juan C.

    divides itself into three sections: liquid preheating, boiling and vapor superheating. Numerical results which the m . w stream boils, and ®nally, the surface As that superheats the steam. The simplicity

  8. Equilibrium composition between liquid and clathrate reservoirs on Titan

    E-Print Network [OSTI]

    Mousis, Olivier; Lunine, Jonathan I; Sotin, Christophe

    2015-01-01

    Hundreds of lakes and a few seas of liquid hydrocarbons have been observed by the Cassini spacecraft to cover the polar regions of Titan. A significant fraction of these lakes or seas could possibly be interconnected with subsurface liquid reservoirs of alkanes. In this paper, we investigate the interplay that would happen between a reservoir of liquid hydrocarbons located in Titan's subsurface and a hypothetical clathrate reservoir that progressively forms if the liquid mixture diffuses throughout a preexisting porous icy layer. To do so, we use a statistical-thermodynamic model in order to compute the composition of the clathrate reservoir that forms as a result of the progressive entrapping of the liquid mixture. This study shows that clathrate formation strongly fractionates the molecules between the liquid and the solid phases. Depending on whether the structure I or structure II clathrate forms, the present model predicts that the liquid reservoirs would be mainly composed of either propane or ethane, r...

  9. Transformation of Acetone and Isopropanol to Hydrocarbons using HZSM-5 Catalyst 

    E-Print Network [OSTI]

    Taco Vasquez, Sebastian

    2010-07-14

    .2 i-Butane ? ? 0.1 3.9 n-Butane ? ? ? 1.7 i-Butene 19.1 31.3 83.3 3.6 n-Butene ? ? butane, isobutene, butane, isobutylene), carbon monoxide, and carbon dioxide. The liquid products are hydrocarbons...

  10. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

    2007-12-25

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  11. Magnetic Propulsion of Intense Lithium Streams in a Tokamak Magnetic Field

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    Magnetic Propulsion of Intense Lithium Streams in a Tokamak Magnetic Field Leonid E. Zakharov the theory of magnetic propulsion of liquid lithium streams and their stability in tokamaks takes into account the propulsion e#11;ect, viscosity and the drag force due to magnetic pumping

  12. Aromaticity of Polycyclic Conjugated Hydrocarbons Milan Randic*

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    Aromaticity of Polycyclic Conjugated Hydrocarbons Milan Randic´* National Institute of Chemistry Chemistry 3462 G. Clar 6n Rule versus Hu¨ckel 4n + 2 Rule 3464 H. Hydrocarbons versus Heteroatomic Systems Ordering 3476 VI. On Enumeration of Benzenoid Hydrocarbons 3477 VII. Kekule´ Valence Structures Count 3479

  13. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi Klavzara, , Petra Zigerta , Ivan Gutmanb sextets in any of the Clar formulae) of a catacondensed benzenoid hydrocarbon: CL is equal to the minimum; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within the theory that was formulated [1, 2

  14. Polycyclic Aromatic Hydrocarbon Biodegradation Rates: A

    E-Print Network [OSTI]

    Peters, Catherine A.

    Polycyclic Aromatic Hydrocarbon Biodegradation Rates: A Structure-Based Study K R I S T I N E H . W structure in determining the biodegradation rates of polycyclic aromatic hydrocarbons (PAHs). Laboratory. Introduction Polycyclic aromatic hydrocarbons (PAHs) are a class of organic pollutants that are commonly found

  15. Cuticular Hydrocarbon Research1 Marion Page2

    E-Print Network [OSTI]

    Cuticular Hydrocarbon Research1 Marion Page2 We have been studying existing taxonomies of forest in the utility of cuticular (surface) hydrocarbons as taxonomic characters (Haverty and others 1988, 1989, Page to be genetically fixed. Because the insects studied so far synthesize all or most of their hydrocarbon components

  16. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi KlavŸzar a,# , Petra Ÿ Zigert a , Ivan hydrocarbon: CL is equal to the minimum number of straight lines required to intersect all hexagons theory; Clar formula; Clar number; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within

  17. Magnetic propulsion of liquid Li in tokamaks 1

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    Magnetic propulsion of liquid Li in tokamaks 1 Leonid E. Zakharov, Princeton University, Princeton of liquid lithium, with the tokamak magnetic field is discussed as a mechanism a) for creating fast moving (plasma facing) Li streams along the inner wall of tokamak and b) for mixing the liquid in a closed volume

  18. Liquidity-Sensitive Automated Market Makers via Homogeneous Risk Measures

    E-Print Network [OSTI]

    stream of research in au- tomated market making is the design of liquidity-sensitive automated marketLiquidity-Sensitive Automated Market Makers via Homogeneous Risk Measures Abraham Othman and Tuomas. Automated market makers are algorithmic agents that pro- vide liquidity in electronic markets. A recent

  19. Hydrocarbon Effect on a Fe-zeolite Urea-SCR Catalyst: An Experimental and Modeling Study

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Tonkyn, Russell G.; Herling, Darrell R.

    2010-04-14

    Synergies between various catalytic converters such as SCR and DPF are vital to the success of an integrated aftertreatment system for simultaneous NOx and particulate matter control in diesel engines. Several issues such as hydrocarbon poisoning, thermal aging and other coupled aftertreatment dynamics need to be addressed to develop an effective emission control system. This paper reports an experimental and modeling study to understand the effect of hydrocarbons on a Fe-zeolite urea-SCR bench reactor. Several bench-reactor tests to understand the inhibition of NOx oxidation, to characterize hydrocarbon storage and to investigate the impact of hydrocarbons on SCR reactions were conducted. Toluene was chosen as a representative hydrocarbon in diesel exhaust and various tests using toluene reveal its inhibition of NO oxidation at low temperatures and its oxidation to CO and CO2 at high temperatures. Surface isotherm tests were conducted to characterize the adsorption-desorption equilibrium of toluene through Langmuir isotherms. Using the rate parameters, a toluene storage model was developed and validated in simulation. With toluene in the stream, controlled SCR tests were run on the reactor and performance metrics such as NOx conversion and NH3 slip were compared to a set of previously run tests with no toluene in the stream. Tests indicate a significant effect of toluene on NOx and NH3 conversion efficiencies even at temperatures greater than 300oC. A kinetic model to address the toluene inhibition during NO oxidation reaction was developed and is reported in the paper. This work is significant especially in an integrated DPF-SCR aftertreatment scenario where the SCR catalyst on the filter substrate is exposed to un-burnt diesel hydrocarbons during active regeneration of the particulate filter.

  20. Liquid mixing device

    SciTech Connect (OSTI)

    O'Leary, R. P.

    1985-08-06

    A mixing device for mixing at least two liquids to produce a homogenous mixture. The device includes an elongated chamber in which a vertically oriented elongated mixing cavity is located. The cavity is sealed at its lower end and it is open at its upper end and in communication with the interior of the chamber. An elongated conduit extends the length of the cavity and is adapted to receive liquids to be mixed. The conduit includes a plurality of ports located at longitudinally spaced positions therealong and which ports are directed in different directions. The ports create plural streams of liquid which interact and mix with one another within the cavity. The mixed liquids overflow the cavity and out its top end into the chamber 24. The chamber 24 includes an outlet from which the mixed liquids are withdrawn. In accordance with the preferred embodiment gas eductor means are provided in the inlet to the conduit to introduce gas bubbles within the cavity. Gas vent means are also provided in the device to vent any introduced gases from the device so that only the mixed liquids flow out the outlet.

  1. Glasshouses Ilam Stream

    E-Print Network [OSTI]

    Hickman, Mark

    91 93 7 79 77 75 29-F1 29-F2 4 27 10 24 50 54 Ilam Stream Maidstone Road Bickerton Block D Jean Library Entrance Engineering and Physical Sciences Library Special Purposes Laboratory Creyke Road Alice Tension Lab Electrical Engineering Electrical Link Block Chemical and Process Engineering Engineering Core

  2. Representing Vapor-Liquid Equilibrium for an Aqueous MEA-CO2 System Using the Electrolyte Nonrandom-Two-Liquid Model

    E-Print Network [OSTI]

    Zhang, Luzheng

    for processing to-be-liquefied natural gas, syn- thesis gas, and hydrogen stream, which require low CO2 leakage processing the natural gas and refinery gas streams. The disadvantages of aqueous MEA include the followingRepresenting Vapor-Liquid Equilibrium for an Aqueous MEA-CO2 System Using the Electrolyte Nonrandom-Two-Liquid

  3. Volumes of liquid hydrocarbons at high temperatures and pressures 

    E-Print Network [OSTI]

    Alani, Ghalib H.

    1959-01-01

    (0m a, & i r * W o & cl ? S V *? s o s a 4-3 ' d 8 8 0 o o S, o LC vO r- O VH? ? o d * o ?o (VJ ^ Sr- ??*H ? ? 43 ? * * . u &f\\l 00 00 sO O O O o in m o o o ? o oin o oo o O' o o m co oo O... ? ? ? ? ? ? ? ? 0) in o ? + ft)rj $ iI rsj CO in in vO 00 O' o M0 u U U O u O U U U O U U ft ?H a ?H ti ? ? ?3 o> ?3 *- ? ?CL 0f ? h8 *H 5 *CO 'd0) r-l 13 hU M Tj? w ?S 3 . ?g 2 9 S | 2 a ig 2 I...

  4. Removal of basic nitrogen compounds from hydrocarbon liquids

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Hoover, David S. (New Tripoli, PA)

    1985-01-01

    A method is provided for reducing the concentration of basic nitrogen compounds in hydrocarbonaceous feedstock fluids used in the refining industry by providing a solid particulate carbonaceous adsorbent/fuel material such as coal having active basic nitrogen complexing sites on the surface thereof and the coal with a hydrocarbonaceous feedstock containing basic nitrogen compounds to facilitate attraction of the basic nitrogen compounds to the complexing sites and the formation of complexes thereof on the surface of the coal. The adsorbent coal material and the complexes formed thereon are from the feedstock fluid to provide a hydrocarbonaceous fluid of reduced basic nitrogen compound concentration. The coal can then be used as fuel for boilers and the like.

  5. Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillion Cubic Feet) Havre,1

  6. Dry reforming of hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Shah, Yatish T.; Gardner, Todd H.

    2014-09-25

    Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

  7. Catalytic method for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Sapienza, Richard S. (Shoreham, NY); Sansone, Michael J. (Summit, NJ); Slegeir, William A. R. (Hampton Bays, NY)

    1984-01-01

    A method for synthesizing hydrocarbons from carbon monoxide and hydrogen by contacting said gases with a slurry of a catalyst composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants.

  8. Deep desulfurization of hydrocarbon fuels

    DOE Patents [OSTI]

    Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

    2012-04-17

    The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

  9. Design and Applications of Anti Albumin-Adduct Antibodies to Assess Human Exposure to Aromatic Hydrocarbons

    E-Print Network [OSTI]

    Chung, Ming Kei

    2013-01-01

    measurement  of  polycyclic  aromatic  hydrocarbon-­?before  measurement  of  hydrocarbon-­?HSA  adducts   with  measurement  of  polycyclic  aromatic  hydrocarbon-­?

  10. Stream Cipher Criteria Erik Zenner

    E-Print Network [OSTI]

    Zenner, Erik

    given us a number of insights into design criteria for stream ciphers. Some of them were disputedStream Cipher Criteria Erik Zenner CRYPTICO A/S info@cryptico.com Abstract. The eStream project has, on others everyone seemed to agree. This text tries to collect these criteria into one comprehensive

  11. STREAM CATALOG OF SOUTHEASTERN ALASKA

    E-Print Network [OSTI]

    465 STREAM CATALOG OF SOUTHEASTERN ALASKA REGULATORY DISTRICT No. 3 AND 4 SPECIAL SaENTIFIC REPORT area of each stream. Available records of weather, water temperatures, and information useful to ground. Pautzke, Commissioner Bureau of Commercial Fisheries, Donald L. McKernan, Director STREAM CATALOG

  12. STREAM CATALOG OF SOUTHEASTERN ALASKA

    E-Print Network [OSTI]

    453 STREAM CATALOG OF SOUTHEASTERN ALASKA REGULATORY DISTRICT No. 2 SPECIAL SCIENTIFIC REPORT and the upstream area of each stream. Available records of weather, water temperatures, and information use- ful, Commissioner Bureau of Commercial Fisheries, Donald L. McKernan, Director STREAM CATALOG OF SOUTHEASTERN ALASKA

  13. Method for predicting fouling tendency of a hydrocarbon-containing feedstock

    DOE Patents [OSTI]

    Schabron, John F; Rovani, Jr., Joseph F

    2013-07-23

    Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock fouling tendency for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

  14. New flow boiling heat transfer model for hydrocarbons evaporating inside horizontal tubes

    SciTech Connect (OSTI)

    Chen, G. F.; Gong, M. Q.; Wu, J. F.; Zou, X.; Wang, S.

    2014-01-29

    Hydrocarbons have high thermodynamic performances, belong to the group of natural refrigerants, and they are the main components in mixture Joule-Thomson low temperature refrigerators (MJTR). New evaluations of nucleate boiling contribution and nucleate boiling suppression factor in flow boiling heat transfer have been proposed for hydrocarbons. A forced convection heat transfer enhancement factor correlation incorporating liquid velocity has also been proposed. In addition, the comparisons of the new model and other classic models were made to evaluate its accuracy in heat transfer prediction.

  15. Process for the selective removal of hydrogen sulphide and carbonyl sulfide from light hydrocarbon gases containing carbon dioxide

    SciTech Connect (OSTI)

    Bush, W.V.

    1988-06-07

    A process for the selective removal of H/sub 2/S and COS from a gas containing light hydrocarbons, H/sub 2/S, COS and CO/sub 2/, is described which comprises in a one step absorption, at treatment conditions, contacting the gas stream with a solvent stream consisting essentially of: (i) water, (ii) a bridgehead amine comprising a bicyclo tertiary amine or a bicyclo amidine to selectively hydrolyze the COS to H/sub 2/S and CO/sub 2/, (iii) a tertiary amine to selectively absorb the H/sub 2/S and to selectively exclude from absorption the CO/sub 2/ in the gas stream and the CO/sub 2/ produced by the hydrolysis of the COS, and (iv) a physical solvent acceptable for COS absorption wherein two streams are formed comprising: (1) a light hydrocarbon and CO/sub 2/-containing stream having 1 ppm to about 200 ppm H/sub 2/S and having 1 ppm COS to about 10 ppm COS and (2) a solvent stream rich in H/sub 2/S, water, tertiary amine and the bridgehead amine.

  16. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Bustard, C.J.

    1999-04-13

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 5 figs.

  17. Enhanced catalyst for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K. (Yorktown Heights, NY); Rabo, Jule A. (Armonk, NY)

    1985-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  18. Enhanced catalyst for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, P.K.; Rabo, J.A.

    1985-12-03

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C[sub 5][sup +] hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising a SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  19. Enhanced conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K. (Yorktown Heights, NY); Rabo, Jule A. (Armonk, NY)

    1986-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  20. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  1. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

    1988-06-14

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  2. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  3. Nox reduction system utilizing pulsed hydrocarbon injection

    DOE Patents [OSTI]

    Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

    2001-01-01

    Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

  4. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Hydrocarbon Precursor Production from Sewage Sludge Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste...

  5. Manifold to uniformly distribute a solid-liquid slurry

    DOE Patents [OSTI]

    Kern, Kenneth C. (Lake Hiawatha, NJ)

    1983-01-01

    This invention features a manifold that divides a stream of coal particles and liquid into several smaller streams maintaining equal or nearly equal mass compositions. The manifold consists of a horizontal, variable area header having sharp-edged, right-angled take-offs which are oriented on the bottom of the header.

  6. Apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons

    SciTech Connect (OSTI)

    Agee, K.L.

    1990-11-27

    This patent describes apparatus for producing heavier hydrocarbons from one or more gaseous light hydrocarbons. It comprises a partial oxidation burner means; a synthesis gas generation vessel; a hydrocarbon synthesis reactor; first conduit means; separating means; second conduit means; catalytic combustion means; third conduit means; carbon dioxide separating means; fourth conduit means; and fifth conduit means.

  7. Catalysts, systems and methods to reduce NOX in an exhaust gas stream

    DOE Patents [OSTI]

    Castellano, Christopher R. (Ringoes, NJ); Moini, Ahmad (Princeton, NJ); Koermer, Gerald S. (Basking Ridge, NJ); Furbeck, Howard (Hamilton, NJ)

    2010-07-20

    Catalysts, systems and methods are described to reduce NO.sub.x emissions of an internal combustion engine. In one embodiment, an emissions treatment system for an exhaust stream is provided having an SCR catalyst comprising silver tungstate on an alumina support. The emissions treatment system may be used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines. An emissions treatment system may further comprise an injection device operative to dispense a hydrocarbon reducing agent upstream of the catalyst.

  8. A Neutron Monitor for In-Situ Real-Time Determination of Transuranics in a Processed Waste Effluent Stream

    SciTech Connect (OSTI)

    Brodzinski, Ronald L.; Craig, Richard A.; Hensley, Walter K.; Lepel, Elwood A.; Seymour, R.; Smart, John E.

    2001-05-01

    A pilot plant operation at the Savannah River Site will demonstrate the removal of 90Sr, 137Cs, and transuranics from a high-level liquid waste stream prior to encapsulation in a Saltstone Facility.

  9. Chlorinated Hydrocarbon Levels in Fishes and Shellfishes of the

    E-Print Network [OSTI]

    measurements. /n contrast, correlations were often significant between chlorinated hydrocarbons. such as DDEChlorinated Hydrocarbon Levels in Fishes and Shellfishes of the Northeastern Pacific Ocean Introduction Reports of excessive amounts of chlorinated hydrocarbons in fishery products have threatened

  10. Hydrocarbon-free resonance transition 795 nm rubidium laser

    E-Print Network [OSTI]

    Wu, Sheldon Shao Quan

    2009-01-01

    and R. J. Beach, "Hydrocarbon-free resonance transition 795-a Reliable Diode-Pumped Hydrocarbon-Free 795-nm Rubidiumand R. J. Beach, "Hydrocarbon-free resonance transition 795-

  11. Enhanced metabolism of halogenated hydrocarbons in transgenic plants containing mammalian

    E-Print Network [OSTI]

    Doty, Sharon Lafferty

    Enhanced metabolism of halogenated hydrocarbons in transgenic plants containing mammalian efficient remediation of many sites contaminated with haloge- nated hydrocarbons. Trichloroethylene (TCE hydrocarbon, ethylene dibromide (EDB; dibromoeth- ane), was used as a soil fumigant to kill nematodes

  12. Methods of making transportation fuel

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

    2012-04-10

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation. The alkylated hydrocarbons may be blended with one or more components to produce transportation fuel.

  13. Polynuclear aromatic hydrocarbons for fullerene synthesis in flames

    DOE Patents [OSTI]

    Alford, J. Michael; Diener, Michael D.

    2006-12-19

    This invention provides improved methods for combustion synthesis of carbon nanomaterials, including fullerenes, employing multiple-ring aromatic hydrocarbon fuels selected for high carbon conversion to extractable fullerenes. The multiple-ring aromatic hydrocarbon fuels include those that contain polynuclear aromatic hydrocarbons. More specifically, multiple-ring aromatic hydrocarbon fuels contain a substantial amount of indene, methylnapthalenes or mixtures thereof. Coal tar and petroleum distillate fractions provide low cost hydrocarbon fuels containing polynuclear aromatic hydrocarbons, including without limitation, indene, methylnapthalenes or mixtures thereof.

  14. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Energy Savers [EERE]

    HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Presentation from the...

  15. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

  16. Scaling and dimensional analysis of acoustic streaming jets

    SciTech Connect (OSTI)

    Moudjed, B.; Botton, V.; Henry, D.; Ben Hadid, H.

    2014-09-15

    This paper focuses on acoustic streaming free jets. This is to say that progressive acoustic waves are used to generate a steady flow far from any wall. The derivation of the governing equations under the form of a nonlinear hydrodynamics problem coupled with an acoustic propagation problem is made on the basis of a time scale discrimination approach. This approach is preferred to the usually invoked amplitude perturbations expansion since it is consistent with experimental observations of acoustic streaming flows featuring hydrodynamic nonlinearities and turbulence. Experimental results obtained with a plane transducer in water are also presented together with a review of the former experimental investigations using similar configurations. A comparison of the shape of the acoustic field with the shape of the velocity field shows that diffraction is a key ingredient in the problem though it is rarely accounted for in the literature. A scaling analysis is made and leads to two scaling laws for the typical velocity level in acoustic streaming free jets; these are both observed in our setup and in former studies by other teams. We also perform a dimensional analysis of this problem: a set of seven dimensionless groups is required to describe a typical acoustic experiment. We find that a full similarity is usually not possible between two acoustic streaming experiments featuring different fluids. We then choose to relax the similarity with respect to sound attenuation and to focus on the case of a scaled water experiment representing an acoustic streaming application in liquid metals, in particular, in liquid silicon and in liquid sodium. We show that small acoustic powers can yield relatively high Reynolds numbers and velocity levels; this could be a virtue for heat and mass transfer applications, but a drawback for ultrasonic velocimetry.

  17. Comments on Relaying Information Streams Relaying Information Streams

    E-Print Network [OSTI]

    California at Berkeley, University of

    to rigorously formalize the back-of-the-envelope reasoning given here. Some work appears in Tunc's thesis that builds on it, but that is it. #12;Comments on Relaying Information Streams ' & $ % The Goal that works much better for the one-shot non-streaming context: all data to be sent is known in advance

  18. Catalytic conversion of hydrocarbons to hydrogen and high-value carbon

    DOE Patents [OSTI]

    Shah, Naresh; Panjala, Devadas; Huffman, Gerald P.

    2005-04-05

    The present invention provides novel catalysts for accomplishing catalytic decomposition of undiluted light hydrocarbons to a hydrogen product, and methods for preparing such catalysts. In one aspect, a method is provided for preparing a catalyst by admixing an aqueous solution of an iron salt, at least one additional catalyst metal salt, and a suitable oxide substrate support, and precipitating metal oxyhydroxides onto the substrate support. An incipient wetness method, comprising addition of aqueous solutions of metal salts to a dry oxide substrate support, extruding the resulting paste to pellet form, and calcining the pellets in air is also discloses. In yet another aspect, a process is provided for producing hydrogen from an undiluted light hydrocarbon reactant, comprising contacting the hydrocarbon reactant with a catalyst as described above in a reactor, and recovering a substantially carbon monoxide-free hydrogen product stream. In still yet another aspect, a process is provided for catalytic decomposition of an undiluted light hydrocarbon reactant to obtain hydrogen and a valuable multi-walled carbon nanotube coproduct.

  19. Evaluation of open pit incineration for the disposal of hydrocarbon wastes 

    E-Print Network [OSTI]

    Bell, Stuart Ray

    1981-01-01

    filtration or the additional other fuel may also be easily incinerated. The third category is a sludge. This sludge contains a high solid or sand content suspended in a heavy lubricating oil. The oil is barely liquid in nature and methods of pumping... of hydrocarbon wastes using an open pit air curtain destructor (ACD) type incinerator was investigated. A prototype experi- mental incinerator was designed and constructed, and experiments were performed with it to determine the relationships among various...

  20. Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    SciTech Connect (OSTI)

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2000-01-01

    A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

  1. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two aromatic hydrocarbons, 17 nitrated PAHs (NPAHs) and 8 oxygenated PAHs (OPAHs) were carried out during hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons

  2. Process for the production of ethylene and other hydrocarbons from coal

    SciTech Connect (OSTI)

    Steinberg, M.; Fallon, P.

    1982-02-16

    A process is claimed for the production of substantial amounts of ethylene and other hydrocarbon compounds, such as benzene from coal. Coal is reacted with methane at a temperature in the approximate range of 500/sup 0/C to 1100/sup 0/C at a partial pressure less than about 200 psig for a period of less than 10 seconds, and preferably at a temperature of approximately 850/sup 0/C, and a partial pressure of 50 psig for a period of approximately 2 seconds. Ethylene and other hydrocarbon compounds may be separated from the product stream so produced, and the methane recycled for further production of ethylene. In another embodiment, other compounds produced, such as by-product tars, may be burned to heat the recycled methane.

  3. Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2001-03-27

    A hydrocarbon fuel reforming method is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first mixture of an oxygen-containing gas and a first fuel is directed into a first tube 108 to produce a first reaction reformate. A second mixture of steam and a second fuel is directed into a second tube 116 annularly disposed about the first tube 108 to produce a second reaction reformate. The first and second reaction reformates are then directed into a reforming zone 144 and subject to a catalytic reforming reaction. In another aspect of the method, a first fuel is combusted with an oxygen-containing gas in a first zone 108 to produce a reformate stream, while a second fuel under steam reforming in a second zone 116. Heat energy from the first zone 108 is transferred to the second zone 116.

  4. Dynamical modeling of tidal streams

    SciTech Connect (OSTI)

    Bovy, Jo, E-mail: bovy@ias.edu [Institute for Advanced Study, Einstein Drive, Princeton, NJ 08540 (United States)

    2014-11-01

    I present a new framework for modeling the dynamics of tidal streams. The framework consists of simple models for the initial action-angle distribution of tidal debris, which can be straightforwardly evolved forward in time. Taking advantage of the essentially one-dimensional nature of tidal streams, the transformation to position-velocity coordinates can be linearized and interpolated near a small number of points along the stream, thus allowing for efficient computations of a stream's properties in observable quantities. I illustrate how to calculate the stream's average location (its 'track') in different coordinate systems, how to quickly estimate the dispersion around its track, and how to draw mock stream data. As a generative model, this framework allows one to compute the full probability distribution function and marginalize over or condition it on certain phase-space dimensions as well as convolve it with observational uncertainties. This will be instrumental in proper data analysis of stream data. In addition to providing a computationally efficient practical tool for modeling the dynamics of tidal streams, the action-angle nature of the framework helps elucidate how the observed width of the stream relates to the velocity dispersion or mass of the progenitor, and how the progenitors of 'orphan' streams could be located. The practical usefulness of the proposed framework crucially depends on the ability to calculate action-angle variables for any orbit in any gravitational potential. A novel method for calculating actions, frequencies, and angles in any static potential using a single orbit integration is described in the Appendix.

  5. The Phoenix stream: a cold stream in the Southern hemisphere

    E-Print Network [OSTI]

    Balbinot, E; Li, T S; Santiago, B; Marshall, J L; Finley, D A; Pieres, A; Abbott, T M C; Abdalla, F B; Allam, S; Benoit-Lévy, A; Bernstein, G M; Bertin, E; Brooks, D; Burke, D L; Rosell, A Carnero; Kind, M Carrasco; Carretero, J; Cunha, C E; da Costa, L N; DePoy, D L; Desai, S; Diehl, H T; Doel, P; Estrada, J; Flaugher, B; Frieman, J; Gerdes, D W; Gruen, D; Gruendl, R A; Honscheid, K; James, D J; Kuehn, K; Kuropatkin, N; Lahav, O; March, M; Martini, P; Miquel, R; Nichol, R C; Ogando, R; Romer, A K; Sanchez, E; Schubnell, M; Sevilla-Noarbe, I; Smith, R C; Soares-Santos, M; Sobreira, F; Suchyta, E; Tarle, G; Thomas, D; Tucker, D; Walker, A R

    2015-01-01

    We report the discovery of a stellar stream in the Dark Energy Survey (DES) Year 1 (Y1A1) data. The discovery was made through simple color-magnitude filters and visual inspection of the Y1A1 data. We refer to this new object as the Phoenix stream, after its residing constellation. Through the subtraction of the background stellar population we detect a clear signal of a simple stellar population. By fitting the ridge line of the stream in color-magnitude space, we find that a stellar population with age $\\tau=11.5\\pm0.5$ Gyr and ${\\rm [Fe/H]}an adequate description of the stream stellar population. The stream is detected over an extension of 8$^{\\circ}$.1 (2.5 kpc) and has a width of $\\sim$54 pc assuming a Gaussian profile, indicating that a globular cluster is a probable progenitor. There is no known globular cluster within 5 kpc compatible with being the progenitor of the stream, assuming that the stream traces its orbit. We examined overdensities along...

  6. Method for removal and stabilization of mercury in mercury-containing gas streams

    DOE Patents [OSTI]

    Broderick, Thomas E.

    2005-09-13

    The present invention is directed to a process and apparatus for removing and stabilizing mercury from mercury-containing gas streams. A gas stream containing vapor phase elemental and/or speciated mercury is contacted with reagent, such as an oxygen-containing oxidant, in a liquid environment to form a mercury-containing precipitate. The mercury-containing precipitate is kept or placed in solution and reacts with one or more additional reagents to form a solid, stable mercury-containing compound.

  7. Magnetic Propulsion of Intense Lithium Streams in a Tokamak Magnetic Field

    SciTech Connect (OSTI)

    Leonid E. Zakharov

    2002-03-13

    The paper gives the theory of magnetic propulsion of liquid lithium streams and their stability in tokamaks. In the approximation of a thin flowing layer the MHD equations are reduced to one integro-differential equation which takes into account the propulsion effect, viscosity and the drag force due to magnetic pumping and other interactions with the magnetic field. A criterion is obtained for the stabilization of the ''sausage'' instability of the streams by centrifugal force.

  8. Production of hydrocarbon fractions by hydrocracking

    SciTech Connect (OSTI)

    Degnan, T.F.; Kirker, G.W.; Socha, R.F.; Stapleton, M.R.; Johnson, I.D.

    1991-05-14

    This patent describes a process which comprises hydrocracking a hydrocarbon feedstock having an initial boiling point about 343{degrees} C. in the presence of a catalyst having cracking and hydrogenating activity. It comprises: catalyst comprising a layered silicate containing interspathic polymeric silica, in order to produce a hydrocarbon product having at least 35 percent by weight of hydrocarbons having a boiling point below 343{degrees} c., the catalyst further comprising at least one metal selected from the group consisting of Cr, Mo, W, Fe, Co, and Ni, wherein the hydrocracking occurs at conversions to product having a boiling point of less than 343{degrees} C. of greater than 70 percent volume of charge.

  9. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2015-06-09

    A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

  10. Coarse-grained interaction potentials for polyaromatic hydrocarbons

    E-Print Network [OSTI]

    O. Anatole von Lilienfeld; Denis Andrienko

    2005-12-09

    Using Kohn-Sham density functional theory (KS-DFT), we have studied the interaction between various polyaromatic hydrocarbon molecules. The systems range from mono-cyclic benzene up to hexabenzocoronene (hbc). For several conventional exchange-correlation functionals potential energy curves of interaction of the $\\pi$-$\\pi$ stacking hbc dimer are reported. It is found that all pure local density or generalized gradient approximated functionals yield qualitatively incorrect predictions regarding structure and interaction. Inclusion of a non-local, atom-centered correction to the KS-Hamiltonian enables quantitative predictions. The computed potential energy surfaces of interaction yield parameters for a coarse-grained potential, which can be employed to study discotic liquid-crystalline mesophases of derived polyaromatic macromolecules.

  11. Solubilization of petroleum hydrocarbons using biosurfactants 

    E-Print Network [OSTI]

    Kanga, Shahrukh

    1995-01-01

    that bioavailability of the crude oil to the microorganisms limited the degradation rates (Mills, 1994). Preliminary experiments at our laboratories have also indicated enhanced solubilities of petroleum hydrocarbons due to the effects of biosurfactants (Kanga et al...

  12. Nano Sensor Networks for Tailored Operation of Highly Efficient Gas-To-Liquid Fuels Catalysts

    E-Print Network [OSTI]

    New South Wales, University of

    for converting natural gas to the liquid hydrocarbons [1]. However, the reaction is a complex network of manyNano Sensor Networks for Tailored Operation of Highly Efficient Gas-To-Liquid Fuels Catalysts Eisa 2052, Australia #12;Abstract Fischer-Tropsch synthesis, a major process for converting natural gas

  13. Method for extracting metals from aqueous waste streams for long term storage

    DOE Patents [OSTI]

    Chaiko, David J. (Woodridge, IL)

    1995-01-01

    A liquid--liquid extraction method for removing metals and hydrous metal colloids from waste streams is provided wherein said waste streams are contacted with a solvent system containing a water-in-oil microemulsion wherein the inverted micelles contain the extracted metal. A silicon alkoxide, either alone or in combination with other metal alkoxide compounds is added to the water-in-oil microemulsion, thereby allowing encapsulation of the extracted metal within a silicon oxide network. Lastly, the now-encapsulated metal is precipitated from the water-in-oil microemulsion phase to yield aggregates of metal-silicate particles having average individual particle sizes of approximately 40 nanometers.

  14. Method for extracting metals from aqueous waste streams for long term storage

    DOE Patents [OSTI]

    Chaiko, D.J.

    1995-03-07

    A liquid-liquid extraction method for removing metals and hydrous metal colloids from waste streams is provided wherein said waste streams are contacted with a solvent system containing a water-in-oil microemulsion wherein the inverted micelles contain the extracted metal. A silicon alkoxide, either alone or in combination with other metal alkoxide compounds is added to the water-in-oil microemulsion, thereby allowing encapsulation of the extracted metal within a silicon oxide network. Lastly, the now-encapsulated metal is precipitated from the water-in-oil microemulsion phase to yield aggregates of metal-silicate particles having average individual particle sizes of approximately 40 nanometers. 2 figs.

  15. Method for extracting metals from aqueous waste streams for long term storage

    DOE Patents [OSTI]

    Chaiko, D.J.

    1993-01-01

    A liquid-liquid extraction method for removing metals and hydrous metal colloids from waste streams is provided wherein said waste streams are contacted with a solvent system containing a water-in-oil microemulsion wherein the inverted micelles contain the extracted metal. A silicon alkoxide, either alone or in combination with other metal alkoxide compounds is added to the water-in-oil microemulsion, thereby allowing encapsulation of the extracted metal within a silicon oxide network. Lastly, the now-encapsulated metal is precipitated from the water-in-oil microemulsion phase to yield aggregates of metal-silicate particles having average. individual particle sizes of approximately 40 manometers.

  16. Hydrocarbon zeolite catalyst employed in hydrocracking process

    SciTech Connect (OSTI)

    Ward, J.W.

    1987-05-12

    A hydrocracking process is described which comprises contacting a hydrocarbon feedstock under hydrocracking conditions with hydrogen in the presence of a catalyst comprising at least one hydrogenation component, a crystalline aluminosilicate zeolite having catalytic activity for cracking hydrocarbons, and a dispersion of silica-alumina in a matrix consisting essentially of alumina, wherein the catalyst comprises particles in the shape of a three-leaf clover.

  17. Waste control alternatives for chlorinated hydrocarbons 

    E-Print Network [OSTI]

    Pearce, Terry Allan

    1975-01-01

    WASTE CONTROL ALTERNATIVES FOR CHLORINATED HYDROCARBONS A Thesis by TERRY ALLAN PEARCE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1975 Major... Subject: Chemical Engineering WASTE CONTROL ALTERNATIVES FOR CHLORINATED HYDROCARBONS A Thesis by TERRY ALLAN PEARCE Approved as to style and content by: , ~ I ' p Chairman of Committee ead of Departmen em er Member May 1975 ABSTRACT Waste...

  18. Hydrocarbon habitat of the west Netherlands basin

    SciTech Connect (OSTI)

    De Jager, J. (Nederlandse Aardolie Maatschappij, Assen (Netherlands)); Doyle, M. (Petroleum Development Oman, Muscat (Oman)); Grantham, P. (KSEPL/Shell Research, Rijswijk (Netherlands)); Mabillard, J. (Shell Nigeria, Port Harcourt (Nigeria))

    1993-09-01

    The complex West Netherlands Basin contains oil and gas in Triassic and Upper Jurassic to Cretaceous clastic reservoir sequences. The understanding has always been that the Carboniferous coal measures have generated only gas and the Jurassic marine Posidonia Shale only oil. However, detailed geochemical analyses show that both source rocks have generated oil and gas. Geochemical fingerprinting established a correlation of the hydrocarbons with the main source rocks. The occurrence of these different hydrocarbons is consistent with migration routes. Map-based charge modeling shows that the main phase of hydrocarbon generation occurred prior to the Late Cretaceous inversion of the West Netherlands Basin. However, along the southwest flank of the basin and in lows between the inversion highs, significant charge continued during the Tertiary. Biodegradation of oils in Jurassic and Cretaceous reservoirs occurred during the earliest Tertiary, but only in reservoirs that were at that time at temperatures of less then 70 to 80[degrees]C, where bacteria could survive. This study shows that also in a mature hydrocarbon province an integrated hydrocarbon habitat study with modern analyses and state-of-the-art technology can lead to a much improved understanding of the distribution of oil and gas in the subsurface. The results of this study will allow a better risk assessment for remaining prospects, and an improved prediction of the type of trapped hydrocarbons in terms of gas, oil, and biodegraded oil.

  19. Stream aquifer interactions: analytical solution to estimate stream depletions caused by stream stage fluctuations and pumping wells near streams 

    E-Print Network [OSTI]

    Intaraprasong, Trin

    2009-05-15

    This dissertation is composed of three parts of contributions. Systems of a fully penetrating pumping well in a confined aquifer near a fully penetrating stream with and without streambeds are discussed in Chapter II. In ...

  20. Direct Conversion of Syngas-to-Hydrocarbons over Higher Alcohols Synthesis Catalysts Mixed with HZSM-5

    SciTech Connect (OSTI)

    Lebarbier Dagel, Vanessa M.; Dagle, Robert A.; Li, Jinjing; Deshmane, Chinmay A.; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2014-09-10

    The synthesis of hydrocarbon fuels directly from synthesis gas (i.e. one step process) was investigated with a catalytic system comprised of HZSM-5 physically mixed with either a methanol synthesis catalyst or a higher alcohols synthesis (HAS) catalyst. The metal sites of the methanol or HAS synthesis catalyst enable the conversion of syngas to alcohols, whereas HZSM-5 provides acid sites required for methanol dehydration, and dimethyl ether-to-hydrocarbons reactions. Catalytic performance for HZSM-5 when mixed with either a 5 wt.% Pd/ZnO/Al2O3 methanol synthesis catalyst or a HAS catalyst was evaluated at 300°C, 70 bars, GHSV=700 h-1 and H2/CO=1 using a HZSM-5: alcohols synthesis catalyst weight ratio of 3:1. The major difference observed between the methanol synthesis and HAS catalyst mixtures was found in the production of durene which is an undesirable byproduct. While durene formation is negligible with any of the HAS catalysts mixed with the HZSM-5 evaluated in this study, it represents almost 50% of the C5+ fraction for the methanol synthesis catalyst (5 wt.% Pd/ZnO/Al2O3 ) mixed with HZSM-5. This presents an advantage for using HAS catalysts over the methanol synthesis catalyst to minimize the durene by-product. The yield toward the desired C5+ hydrocarbons is thus twice higher with selected HAS catalysts as compared to when HZSM-5 is mixed with 5 wt.% Pd/ZnO/Al2O3. Among all the HAS catalysts evaluated in this study, a catalyst with 0.5 wt.% Pd/FeCoCu catalyst was found the most promising due to higher production of C5+ hydrocarbons and low durene formation. The efficiency of the one-step process was thus further evaluated using the HZSM-5: 0.5 wt.% Pd/FeCoCu catalyst mixture under a number of process conditions to maximize liquid hydrocarbons product yield. At 300oC, 70 bars, GHSV = 700 h-1 and HZSM-5: 0.5 wt.% Pd/FeCoCu = 3:1 (wt.), the C5+ fraction represents 48.5% of the hydrocarbons. Unfortunately, it is more difficult to achieve higher selectivity to desired C5+ hydrocarbons as the formation of CO2, CH4, and other light hydrocarbons is challenging to suppress in the presence of mixed metal and acid sites. When the 0.5 wt.% Pd/FeCoCu and HZSM-5 are operated sequentially by way of a two-step process the C5+ hydrocarbons fraction is lower and represents 30.4% of the hydrocarbons under comparable conditions. The yield toward the C5+ hydrocarbons is twice higher for the one-step process due to an improved CO conversion and higher C5+ hydrocarbons fraction. The main advantage of the one-step process is that higher syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed since they are intermediates to the final hydrocarbons product.

  1. STUDIES OF WALL FLAME QUENCHING AND HYDROCARBON EMISSIONS IN A MODEL SPARK IGNITION ENGINE

    E-Print Network [OSTI]

    Ishikawa, Nobuhiko

    2011-01-01

    1 'Exhaust Hydrocarbon Measurement for Tuneup Diagnosis?"Methane Measurements Hydrocarbon measurements have been madealso induced. The hydrocarbon measurements reveal a general

  2. Measurement of Hydrocarbon Fluxes due to Natural Seepage in the Northern Santa Barbara Channel

    E-Print Network [OSTI]

    Washburn, Libe; Clark, Jordan F.

    2002-01-01

    of Energy 001 "MEASUREMENT OF HYDROCARBON FLUXES DUE TOauthors directly. Measurement of Hydrocarbon Fluxes due toflux measurements been obtained in the region of hydrocarbon

  3. On the use of hydrocarbons for the determination of tropospheric OH concentrations

    E-Print Network [OSTI]

    Ehhalt, D. H; Rohrer, F.; Wahner, A.; Prather, M. J; Blake, D. R

    1998-01-01

    ET AL. : USING HYDROCARBONS chemical and heterogeneous datade- cay of many reactive hydrocarbons in well-defined urbanseasonality of selected hydrocarbons and halocarbons over

  4. Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer

    E-Print Network [OSTI]

    2008-01-01

    CONDUCTIVITY IMAGING OF HYDROCARBONS USING THE BLUE GENE/Lidentification of hydrocarbon filled layers in deepwater,”Remote sensing of hydrocarbon layers by seabed logging (

  5. Variability of gas composition and flux intensity in natural marine hydrocarbon seeps

    E-Print Network [OSTI]

    Clark, Jordan F.; Washburn, Libe; Schwager Emery, Katherine

    2010-01-01

    in natural marine hydrocarbon seeps Jordan F. Clark & Libeenters, and CO 2 and hydrocarbon gases leave the bubbles.Introduction Natural hydrocarbon seeps are important

  6. Isolation, Determination of Absolute Stereochemistry, and Asymmetric Synthesis of Insect Methyl-Branched Hydrocarbons

    E-Print Network [OSTI]

    Bello, Jan Edgar

    2014-01-01

    d’Ettore, P. In Insect Hydrocarbons: Biology, Biochemistry,A.G. In Insect Hydrocarbons: Biology, Biochemistry, ChemicalMillar, J.G. In Insect Hydrocarbons: Biology, Biochemistry,

  7. THE DYNAMICS OF STAR STREAM GAPS

    SciTech Connect (OSTI)

    Carlberg, R. G., E-mail: carlberg@astro.utoronto.ca [Department of Astronomy and Astrophysics, University of Toronto, Toronto, ON M5S 3H4 (Canada)

    2013-10-01

    A massive object crossing a narrow stream of stars orbiting in the halo of the galaxy induces velocity changes both along and transverse to the stream that can lead to the development of a visible gap. For a stream narrow relative to its orbital radius, the stream crossing time is sufficiently short that the impact approximation can be used to derive the changes in angular momenta and radial actions along the star stream. The epicyclic approximation is used to calculate the evolution of the density of the stream as it orbits around in a galactic potential. Analytic expressions are available for a point mass, however, the general expressions are easily numerically evaluated for perturbing objects with arbitrary density profiles. With a simple allowance for the velocity dispersion of the stream, moderately warm streams can be modeled. The predicted evolution agrees well with the outcomes of simulations of stellar streams for streams with widths up to 1% of the orbital radius of the stream. The angular momentum distribution within the stream shears out gaps with time, further reducing the visibility of streams, although the size of the shear effect requires more detailed simulations that account for the creation of the stream. An illustrative model indicates that shear will set a lower limit of a few times the stream width for the length of gaps that persist. In general, the equations are useful for dynamical insights into the development of stream gaps and their measurement.

  8. The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs,Department of Energy The Final 40%:TheThe

  9. The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaicsState of Pennsylvania U.S.The FirstEnergy The

  10. Fuel-cell engine stream conditioning system

    DOE Patents [OSTI]

    DuBose, Ronald Arthur (Marietta, GA)

    2002-01-01

    A stream conditioning system for a fuel cell gas management system or fuel cell engine. The stream conditioning system manages species potential in at least one fuel cell reactant stream. A species transfer device is located in the path of at least one reactant stream of a fuel cell's inlet or outlet, which transfer device conditions that stream to improve the efficiency of the fuel cell. The species transfer device incorporates an exchange media and a sorbent. The fuel cell gas management system can include a cathode loop with the stream conditioning system transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell related to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

  11. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (‘syngas’) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  12. Method and apparatus for electrokinetic co-generation of hydrogen and electric power from liquid water microjets

    DOE Patents [OSTI]

    Saykally, Richard J; Duffin, Andrew M; Wilson, Kevin R; Rude, Bruce S

    2013-02-12

    A method and apparatus for producing both a gas and electrical power from a flowing liquid, the method comprising: a) providing a source liquid containing ions that when neutralized form a gas; b) providing a velocity to the source liquid relative to a solid material to form a charged liquid microjet, which subsequently breaks up into a droplet spay, the solid material forming a liquid-solid interface; and c) supplying electrons to the charged liquid by contacting a spray stream of the charged liquid with an electron source. In one embodiment, where the liquid is water, hydrogen gas is formed and a streaming current is generated. The apparatus comprises a source of pressurized liquid, a microjet nozzle, a conduit for delivering said liquid to said microjet nozzle, and a conductive metal target sufficiently spaced from said nozzle such that the jet stream produced by said microjet is discontinuous at said target. In one arrangement, with the metal nozzle and target electrically connected to ground, both hydrogen gas and a streaming current are generated at the target as it is impinged by the streaming, liquid spray microjet.

  13. Structure and Depletion at Fluoro- and Hydro-carbon/Water Liquid/Liquid Interfaces

    E-Print Network [OSTI]

    Kaoru Kashimoto; Jaesung Yoon; Binyang Hou; Chiu-hao Chen; Binhua Lin; Makoto Aratono; Takanori Takiue; Mark L. Schlossman

    2008-07-18

    The results of x-ray reflectivity studies of two oil/water (liquid/liquid) interfaces are inconsistent with recent predictions of the presence of a vapor-like depletion region at hydrophobic/aqueous interfaces. One of the oils, perfluorohexane, is a fluorocarbon whose super-hydrophobic interface with water provides a stringent test for the presence of a depletion layer. The other oil, heptane, is a hydrocarbon and, therefore, is more relevant to the study of biomolecular hydrophobicity. These results are consistent with the sub-angstrom proximity of water to soft hydrophobic materials.

  14. Low NOx combustion

    DOE Patents [OSTI]

    Kobayashi; Hisashi (Putnam Valley, NY), Bool, III; Lawrence E. (Aurora, NY)

    2007-06-05

    Combustion of hydrocarbon liquids and solids is achieved with less formation of NOx by feeding a small amount of oxygen into the fuel stream.

  15. Simple rules help select best hydrocarbon distillation scheme

    SciTech Connect (OSTI)

    Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del )

    1993-12-06

    Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

  16. Methods for dispersing hydrocarbons using autoclaved bacteria

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1996-01-01

    A method of dispersing a hydrocarbon includes the steps: providing a bacterium selected from the following group: ATCC 85527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures thereof; autoclaving the bacterium to derive a dispersant solution therefrom; and contacting the dispersant solution with a hydrocarbon to disperse the hydrocarbon. Moreover, a method for preparing a dispersant solution includes the following steps: providing a bacterium selected from the following group: ATCC 75527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures thereof; and autoclaving the bacterium to derive a dispersant solution therefrom.

  17. Methods for dispersing hydrocarbons using autoclaved bacteria

    DOE Patents [OSTI]

    Tyndall, R.L.

    1996-11-26

    A method of dispersing a hydrocarbon includes the following steps: providing a bacterium selected from the following group: ATCC 85527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures; autoclaving the bacterium to derive a dispersant solution; and contacting the dispersant solution with a hydrocarbon to disperse the hydrocarbon. Moreover, a method for preparing a dispersant solution includes the following steps: providing a bacterium selected from the following group: ATCC 75527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures; and autoclaving the bacterium to derive a dispersant solution.

  18. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  19. Method for estimating processability of a hydrocarbon-containing feedstock for hydroprocessing

    DOE Patents [OSTI]

    Schabron, John F; Rovani, Jr., Joseph F

    2014-01-14

    Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitates asphaltenes. Determined parameters and processabilities for a plurality of feedstocks can be used to generate a mathematical relationship between parameter and processability; this relationship can be used to estimate the processability for hydroprocessing for a feedstock of unknown processability.

  20. The StreamIt development tool : a programming environment for StreamIt

    E-Print Network [OSTI]

    Kuo, Kimberly Sue, 1981-

    2004-01-01

    StreamIt [28] is a high-level programming language intended for the development of large-scale and high-performance streaming applications that are characterized by the processing of data streams by modular structures. The ...

  1. Dynamic visualization of data streams

    DOE Patents [OSTI]

    Wong, Pak Chung (Richalnd, WA); Foote, Harlan P. (Richland, WA); Adams, Daniel R. (Kennewick, WA); Cowley, Wendy E. (Richland, WA); Thomas, James J. (Richland, WA)

    2009-07-07

    One embodiment of the present invention includes a data communication subsystem to receive a data stream, and a data processing subsystem responsive to the data communication subsystem to generate a visualization output based on a group of data vectors corresponding to a first portion of the data stream. The processing subsystem is further responsive to a change in rate of receipt of the data to modify the visualization output with one or more other data vectors corresponding to a second portion of the data stream as a function of eigenspace defined with the group of data vectors. The system further includes a display device responsive to the visualization output to provide a corresponding visualization.

  2. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    solid fuels (such as coal) to liquid fuels (petroleum) orliquid~ asked to transform our power plants from coal (liquid fuel. We have been using the green plants' stored energy in the form of coal,

  3. Catalysts for synthesizing various short chain hydrocarbons

    DOE Patents [OSTI]

    Colmenares, Carlos (Alamo, CA)

    1991-01-01

    Method and apparatus (10), including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO.sub.2 aerogels doped with photochemically active uranyl ions (18) are fluidized in a fluidized-bed reactor (12) having a transparent window (16), by hydrogen and CO, C.sub.2 H.sub.4 or C.sub.2 H.sub.6 gas mixtures (20), and exposed to radiation (34) from a light source (32) external to the reactor (12), to produce the short chain hydrocarbons (36).

  4. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two;2 Abstract The size distribution of polycyclic aromatic hydrocarbons (PAHs) and PAH derivatives of compounds. Keywords: Polycyclic aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated

  5. Sustainable treatment of hydrocarbon-contaminated industrial land 

    E-Print Network [OSTI]

    Cunningham, Colin John

    2012-06-25

    Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

  6. Conversion of methane and acetylene into gasoline range hydrocarbons 

    E-Print Network [OSTI]

    Alkhawaldeh, Ammar

    2000-01-01

    Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene...

  7. A Parametric Study of the Effect of Temperature and Hydrocarbon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Temperature and Hydrocarbon Species on the Product Distribution from a Non-Thermal Plasma Reactor A Parametric Study of the Effect of Temperature and Hydrocarbon Species on the...

  8. Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons

    E-Print Network [OSTI]

    Chickos, James S.

    values for these thermochemical properties and for the enthalpies of formation in the gas state at T=298Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons María Victoria Experimental thermochemical properties of benzene, toluene, and 63 polycyclic aro- matic hydrocarbons

  9. Seismic Analysis Using Wavelet Transform for Hydrocarbon Detection 

    E-Print Network [OSTI]

    Cai, Rui

    2012-02-14

    result in successful hydrocarbon finds because abnormal seismic amplitude variations can sometimes be caused by other factors, such as alternative lithology and residual hydrocarbons in certain depositional environments. Furthermore, not all gas fields...

  10. Calculating the hyper--Wiener index of benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Calculating the hyper--Wiener index of benzenoid hydrocarbons Petra Ÿ Zigert 1 , Sandi KlavŸ zar 1. (1) is not easy, especially in the case of large polycyclic molecules, such as benzenoid hydrocarbons

  11. Calculating the hyperWiener index of benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Calculating the hyper­Wiener index of benzenoid hydrocarbons Petra Zigert1 , Sandi Klavzar1) is not easy, especially in the case of large polycyclic molecules, such as benzenoid hydrocarbons. Some time

  12. Improving Catalyst Efficiency in Bio-Based Hydrocarbon Fuels; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    2015-06-01

    This article investigates upgrading biomass pyrolysis vapors to form hydrocarbon fuels and chemicals using catalysts with different concentrations of acid sites. It shows that greater separation of acid sites makes catalysts more efficient at producing hydrocarbon fuels and chemicals. The conversion of biomass into liquid transportation fuels has attracted significant attention because of depleting fossil fuel reserves and environmental concerns resulting from the use of fossil fuels. Biomass is a renewable resource, which is abundant worldwide and can potentially be exploited to produce transportation fuels that are less damaging to the environment. This renewable resource consists of cellulose (40–50%), hemicellulose (25–35%), and lignin (16–33%) biopolymers in addition to smaller quantities of inorganic materials such as silica and alkali and alkaline earth metals (calcium and potassium). Fast pyrolysis is an attractive thermochemical technology for converting biomass into precursors for hydrocarbon fuels because it produces up to 75 wt% bio-oil,1 which can be upgraded to feedstocks and/or blendstocks for further refining to finished fuels. Bio-oil that has not been upgraded has limited applications because of the presence of oxygen-containing functional groups, derived from cellulose, hemicellulose and lignin, which gives rise to high acidity, high viscosity, low heating value, immiscibility with hydrocarbons and aging during storage. Ex situ catalytic vapor phase upgrading is a promising approach for improving the properties of bio-oil. The goal of this process is to reject oxygen and produce a bio-oil with improved properties for subsequent downstream conversion to hydrocarbons.

  13. Liquid hydrogen - An alternative aviation fuel

    SciTech Connect (OSTI)

    Price, R.O.

    1991-02-01

    This paper examines the past and current activities concerning the development of liquid hydrogen as an alternative turbine engine aviation fuel, and also provides a look at the technical and market requirements that determine the viability of substitutes for conventional jet fuel. Alternative aviation fuels must address the following issues: availability, distribution, energy density, compatibility, economics, safety, handling, and quality control. Preliminary hardware demonstrations and analyses have shown that liquid hydrogen seems to be technically feasible, and may be eventually superior to petroleum-based jet fuel. Disadvantages include low ignition energy and a high flame velocity. From the environmental standpoint, hydrogen combustion in aircraft turbine engines can be expected to eliminate smoke emissions, hydrocarbon, and carbon monoxide. As to the marketing perspective, liquid hydrogen has broad applicability as a fuel in other transportation sectors that could allow multiindustry involvement in its development and commercialization.

  14. Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...

    Office of Scientific and Technical Information (OSTI)

    MICROALGAE; ALGAL BIOMASS; HYDROCARBON BIOFUELS; BIOMASS TECHNOLOGIES OFFICE; NATIONAL RENEWABLE ENERGY LABORATORY; PACIFIC NORTHWEST NATIONAL LABORATORY; Bioenergy BIOMASS...

  15. Method and apparatus for low temperature destruction of halogenated hydrocarbons

    DOE Patents [OSTI]

    Reagen, William Kevin (Stillwater, MN); Janikowski, Stuart Kevin (Idaho Falls, ID)

    1999-01-01

    A method and apparatus for decomposing halogenated hydrocarbons are provided. The halogenated hydrocarbon is mixed with solvating agents and maintained in a predetermined atmosphere and at a predetermined temperature. The mixture is contacted with recyclable reactive material for chemically reacting with the recyclable material to create dehalogenated hydrocarbons and halogenated inorganic compounds. A feature of the invention is that the process enables low temperature destruction of halogenated hydrocarbons.

  16. RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART I: ALLENE developed in our laboratory for the reactions of C3-C4 unsaturated hydrocarbons. The main reaction pathways2007 #12;3 INTRODUCTION Soots and polyaromatic hydrocarbons (PAH), which are present in the exhaust gas

  17. The Production of Non-Methane Hydrocarbons by Marine Plankton

    E-Print Network [OSTI]

    The Production of Non-Methane Hydrocarbons by Marine Plankton Stephanie Lyn Shaw Center for Global://web.mit.edu/cgcs/ Printed on recycled paper #12;1 The Production of Non-Methane Hydrocarbons by Marine Plankton by Stephanie of Non-Methane Hydrocarbons by Marine Plankton by Stephanie Lyn Shaw Submitted to the Department of Earth

  18. 2004-01-2299 Elevated Carbon Dioxide Alters Hydrocarbon

    E-Print Network [OSTI]

    Paré, Paul W.

    2004-01-2299 Elevated Carbon Dioxide Alters Hydrocarbon Emissions and Flavor in Onion P. W. Paré, R of low-molecular-weight hydrocarbons and sulfur derivatives. Odd-chain ketones are emitted from onion-through chambers, volatile hydrocarbons from undamaged plants can be collected under different environmental

  19. Production of hydrocarbons from hydrates. [DOE patent application

    DOE Patents [OSTI]

    McGuire, P.L.

    1981-09-08

    An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

  20. Method for removing chlorine compounds from hydrocarbon mixtures

    DOE Patents [OSTI]

    Janoski, E.J.; Hollstein, E.J.

    1984-09-29

    A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

  1. Binary coding of Kekule structures of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Binary coding of Kekulâ??e structures of catacondensed benzenoid hydrocarbons Sandi KlavŸzar, aâ??e structures of benzenoids Key words: benzenoid hydrocarbons, benzenoid graph, resonance graph, Kekul easily be recovered from its binary code. Key words: benzenoid hydrocarbons, benzenoid graph, resonance

  2. Hydrocarbon Formation in Metallic Iron/Water Systems

    E-Print Network [OSTI]

    Deng, Baolin

    Hydrocarbon Formation in Metallic Iron/Water Systems B A O L I N D E N G , , § T I M O T H Y J . C-labeled hydrocarbons are produced. In the absence of chlorinated ethenes, however, lower con- centrations of many of the same hydrocarbons (methane and C2-C6 alkanes and alkenes) are also produced. Hardy and Gillham (1996

  3. Binary coding of Kekule structures of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Binary coding of Kekul´e structures of catacondensed benzenoid hydrocarbons Sandi Klavzar of benzenoids Key words: benzenoid hydrocarbons, benzenoid graph, resonance graph, Kekul´e structure, algorithm easily be recovered from its binary code. Key words: benzenoid hydrocarbons, benzenoid graph, resonance

  4. Wiener Numbers of Pericondensed Benzenoid Hydrocarbons Sandi Klav zar

    E-Print Network [OSTI]

    Klavzar, Sandi

    Wiener Numbers of Pericondensed Benzenoid Hydrocarbons Sandi Klav#20;zar Department of Mathematics expressions for W for several homologous series of pericondensed benzenoid hydrocarbons. An elementary proof polycyclic systems studied were catacondensed benzenoid hydrocarbons. 11{14 Few years ago the situation

  5. Atomic displacements due to spinspin repulsion in conjugated alternant hydrocarbons

    E-Print Network [OSTI]

    Benzi, Michele

    Atomic displacements due to spin­spin repulsion in conjugated alternant hydrocarbons Ernesto-induced atomic displacements in conjugated alt- ernant hydrocarbons. It appears to be responsible alternant hydrocarbons (CAHs) have played a fun- damental role in the development of theoretical chemistry

  6. UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices

    E-Print Network [OSTI]

    UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices: Production of Alcohols, Quinones. Clemett,3 Richard N. Zare3 Polycyclic aromatic hydrocarbons (PAHs) in water ice were exposed to ultra, and ethers, and reduced, producing partially hydrogenated aromatic hydrocarbons, molecules that account

  7. Mass Transfer of Polynuclear Aromatic Hydrocarbons from

    E-Print Network [OSTI]

    Peters, Catherine A.

    ). Many PAHs are only sparingly soluble, and large volumes of water can therefore be contaminated by smallMass Transfer of Polynuclear Aromatic Hydrocarbons from Complex DNAPL Mixtures S U P A R N A M U K . * , Environmental and Water Resources Engineering, Department of Civil and Environmental Engineering, The University

  8. Method of dispersing a hydrocarbon using bacteria

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1996-01-01

    New protozoan derived microbial consortia and method for their isolation are provided. Consortia and bacteria isolated therefrom are useful for treating wastes such as trichloroethylene and trinitrotoluene. Consortia, bacteria isolated therefrom, and dispersants isolated therefrom are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

  9. Method of dispersing a hydrocarbon using bacteria

    DOE Patents [OSTI]

    Tyndall, R.L.

    1996-09-24

    A new protozoan derived microbial consortia and method for their isolation are provided. The isolated consortia and bacteria are useful for treating wastes such as trichloroethylene and trinitrotoluene. The isolated consortia, bacteria, and dispersants are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

  10. Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard reference material 1649a (urban dust) and

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard nitrated polycylic aromatic hydrocarbons (NPAHs) and 9 oxygenated polycylic aromatic hydrocarbons (OPAHs aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic

  11. Water-Efficient Technology Opportunity: Multi-Stream Rotational...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Multi-Stream Rotational Sprinkler Heads Water-Efficient Technology Opportunity: Multi-Stream Rotational Sprinkler Heads Multi-stream rotational sprinkler heads can be used for...

  12. THE ROLE OF POLYCYCLIC AROMATIC HYDROCARBONS IN ULTRAVIOLET EXTINCTION. I. PROBING SMALL MOLECULAR POLYCYCLIC AROMATIC HYDROCARBONS1

    E-Print Network [OSTI]

    THE ROLE OF POLYCYCLIC AROMATIC HYDROCARBONS IN ULTRAVIOLET EXTINCTION. I. PROBING SMALL MOLECULAR POLYCYCLIC AROMATIC HYDROCARBONS1 Geoffrey C. Clayton,2 Karl D. Gordon,3 F. Salama,4 L. J. Allamandola,4, with particular emphasis on a search for absorp- tion features produced by polycyclic aromatic hydrocarbons (PAHs

  13. Modeling the scalability of acrylic stream programs

    E-Print Network [OSTI]

    Wong, Jeremy Ng, 1981-

    2004-01-01

    Despite the fact that the streaming application domain is becoming increasingly widespread, few studies have focused specifically on the performance characteristics of stream programs. We introduce two models by which the ...

  14. Reaction Dynamics at Liquid Interfaces

    E-Print Network [OSTI]

    Benjamin, Ilan

    2015-01-01

    dielectric semiconductor-liquid interfaces. J. Phys. Chem.rates across liquid-liquid interfaces. J. Phys. Chem.rates across liquid-liquid interfaces. 2. Relationships and

  15. Formation of carbon black as a byproduct of pyrolysis of light hydrocarbons in plasma jet

    SciTech Connect (OSTI)

    Chen, H.G.; Zhang, X.B.; Li, F.; Xie, K.C.; Dai, B.; Fan, Y.S.

    1997-12-31

    The light hydrocarbons undergo a complex reaction of flash hydropyrolysis in a DC arc H{sub 2}/Ar plasma jet at atmospheric pressure and average temperatures between 1,500 K and 4,000 K. The raw material was LPG. Acetylene is the major product. Carbon black is a byproduct. Carbon black is characterized with XRD, TEM, and adsorption-and-desorption of liquid nitrogen, respectively. The present work proposes to use the plasma process to replace the classical thermal process in order to produce acetylene directly from LPG with carbon black being a byproduct.

  16. Financial Institution-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop, Summary of Revenue Streams from Breakout Sessions (11/20/11).

  17. Local Government-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop, Summary of Revenue Streams from Breakout Sessions (11/20/11).

  18. Customer-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop, Summary of Revenue Streams from Breakout Sessions (11/20/11).

  19. Contractor-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop, Summary of Revenue Streams from Breakout Sessions (11/20/11).

  20. Utility-Based Revenue Streams-- Notes

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program October 2011 Workshop Summary of Revenue Streams from Breakout Sessions (11/20/11).

  1. Hydrocracking process with integrated distillate product hydrogenation reactor

    SciTech Connect (OSTI)

    Hoehn, R.K.; Reno, M.E.

    1991-06-25

    This patent describes a hydrocracking process. It comprises passing a feed stream which comprises an admixture of hydrocarbons boiling above 240 degrees Centigrade and hydrogen through a hydrocracking reaction zone maintained at hydrocracking conditions and producing a mixed-phase hydrocracking reaction zone effluent stream; separating the mixed-phase hydrocracking reaction zone effluent stream into a first vapor stream, which comprises hydrogen, light hydrocarbons and distillate hydrocarbons, and a first liquid stream, which comprises distillate hydrocarbons; forming a second vapor stream and a second liquid, stream by partially condensing the first vapor stream, with the second liquid stream comprising distillate hydrocarbons and having a lower average boiling point than the first liquid stream; passing the second liquid stream and added hydrogen through a hydrogenation reaction zone maintained at hydrogenation conditions and producing a hydrogenation zone effluent stream; and, passing distillate hydrocarbons present in the hydrogenation zone effluent stream and the first liquid stream into a fractionation zone, and recovering a hydrocracking zone product stream.

  2. Liquid-film electron stripper

    DOE Patents [OSTI]

    Gavin, Basil F. (Albion, CA)

    1986-01-01

    An improved liquid-film electron stripper particularly for high intensity heavy ion beams which produces constant regenerated, stable, free-standing liquid films having an adjustable thickness between 0.3 to 0.05 microns. The improved electron stripper is basically composed of at least one high speed, rotating disc with a very sharp, precision-like, ground edge on one said of the disc's periphery and with a highly polished, flat, radial surface adjacent the sharp edge. A fine stream of liquid, such as oil, impinges at a 90.degree. angle adjacent the disc's sharp outer edge. Film terminators, located at a selected distance from the disc perimeter are positioned approximately perpendicular to the film. The terminators support, shape, and stretch the film and are arranged to assist in the prevention of liquid droplet formation by directing the collected film to a reservoir below without breaking or interfering with the film. One embodiment utilizes two rotating discs and associated terminators, with the discs rotating so as to form films in opposite directions, and with the second disc being located down beam-line relative to the first disc.

  3. Process for hydrocracking carbonaceous material in liquid carrier

    DOE Patents [OSTI]

    Duncan, Dennis A. (Downers Grove, IL)

    1980-01-01

    Solid carbonaceous material is hydrocracked to provide aliphatic and aromatic hydrocarbons for use as gaseous and liquid fuels or chemical feed stock. Particulate carbonaceous material such as coal in slurry with recycled product oil is preheated in liquid state to a temperature of 600.degree.-1200.degree. F. in the presence of hydrogen gas. The product oil acts as a sorbing agent for the agglomerating bitumins to minimize caking within the process. In the hydrocracking reactor, the slurry of oil and carbonaceous particles is heated within a tubular passageway to vaporize the oil and form a gas-solid mixture which is further heated to a hydropyrolysis temperature in excess of 1200.degree. F. The gas-solid mixture is quenched by contact with additional oil to condense normally liquid hydrocarbons for separation from the gases. A fraction of the hydrocarbon liquid product is recycled for quenching and slurrying with the carbonaceous feed. Hydrogen is recovered from the gas for recycle and additional hydrogen is produced by gasification of residual char.

  4. Stream Temperatu Timing of Coho Sa

    E-Print Network [OSTI]

    McMahon, Thomas E.

    and the ini- tiation of feeding involves leaving secure?low energy environ- ments in the interstices of stream bed gravels and entering the high energy environment of the stream, Among populationssf coho salmon (0Stream Temperatu Timing of Coho Sa from Carnation Creek, British L. Blair Holtby, Thomas E. Mc

  5. MEMORY HIERARCHY DESIGN FOR STREAM A DISSERTATION

    E-Print Network [OSTI]

    Dally, William J.

    . Prior research has shown that stream processors provide an energy-efficient, programmable approachMEMORY HIERARCHY DESIGN FOR STREAM COMPUTING A DISSERTATION SUBMITTED TO THE DEPARTMENT of memory and bandwidth hierarchy utilization in stream processors. We first evaluate the appropriate

  6. Data Stream Warehousing in Tidalrace Marios Hadjieleftheriou

    E-Print Network [OSTI]

    Greenberg, Albert

    feeds, financial data, and industrial application monitoring. Making effective use of these data streams can be challenging. While Data Stream Management Systems can provide support for real- time alerting a next-generation data stream warehousing system. In this paper we describe the Tidalrace system, our

  7. FireStream: Sensor Stream Processing for Monitoring Fire Spread Venkatesh Raghavan1

    E-Print Network [OSTI]

    locations required for spatial analysis, the Sen- sor Store, a collection of metadata pertinent to sensorsFireStream: Sensor Stream Processing for Monitoring Fire Spread Venkatesh Raghavan1 , ElkeStream, a sensor stream processing system which provides services for run-time de- tection, monitoring

  8. Aggregation and Degradation in JetStream: Streaming analytics in the wide area

    E-Print Network [OSTI]

    Singh, Jaswinder Pal

    Aggregation and Degradation in JetStream: Streaming analytics in the wide area Ariel Rabkin, Matvey JetStream, a system that allows real-time analysis of large, widely-distributed changing data sets is scarce and it is infeasible to collect all potentially useful data. JetStream addresses bandwidth limits

  9. UpStream: A Storage-centric Load Management System for Real-time Update Streams

    E-Print Network [OSTI]

    UpStream: A Storage-centric Load Management System for Real-time Update Streams Alexandru Moga, Switzerland tatbul@inf.ethz.ch ABSTRACT UpStream is a framework for load management over data streams, security monitoring and location tracking systems. Various load management tech- niques have been proposed

  10. Plasma-assisted conversion of solid hydrocarbon to diamond

    DOE Patents [OSTI]

    Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

    1996-01-01

    A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

  11. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2006-03-30

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe-M (M=Ni, Mo, Pd) catalysts exhibit excellent activity for dehydrogenation of gaseous alkanes, yielding pure hydrogen and carbon nanotubes in one reaction. A fluidized-bed/fixed-bed methane reactor was developed for continuous hydrogen and nanotube production. (6) A process for co-production of hydrogen and methyl formate from methanol has been developed. (7) Pt nanoparticles on stacked-cone carbon nanotubes easily strip hydrogen from liquids such as cyclohexane, methylcyclohexane, tetralin and decalin, leaving rechargeable aromatic phases. (8) Hydrogen volume percentages produced during reforming of methanol in supercritical water in the output stream are {approx}98%, while CO and CO2 percentages are <2 %.

  12. Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil

    DOE Patents [OSTI]

    Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

    2000-01-01

    In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

  13. A hybrid static/dynamic approach to scheduling stream programs

    E-Print Network [OSTI]

    Tan, Ceryen (Ceryen C.)

    2009-01-01

    Streaming languages such as Streamlt are often utilized to write stream programs that execute on multicore processors. Stream programs consist of actors that operate on streams of data. To execute on multiple cores, actors ...

  14. Separation of technetium from nuclear waste stream simulants. Final report

    SciTech Connect (OSTI)

    Strauss, S.H. [Colorado State Univ., Fort Collins, CO (United States). Dept. of Chemistry

    1995-09-11

    The author studied liquid anion exchangers, such as Aliquat-336 nitrate, various pyridinium nitrates, and related salts, so that they may be applied toward a specific process for extracting (partitioning) and recovering {sup 99}TcO{sub 4}{sup {minus}} from nuclear waste streams. Many of the waste streams are caustic and contain a variety of other ions. For this reason, the author studied waste stream simulants that are caustic and contain appropriate concentrations of selected, relevant ions. Methods of measuring the performance of the exchangers and extractant systems included contact experiments. Batch contact experiments were used to determine the forward and reverse extraction parameters as a function of temperature, contact time, phase ratio, concentration, solvent (diluent), and other physical properties. They were also used for stability and competition studies. Specifically, the author investigated the solvent extraction behavior of salts of perrhenate (ReO{sub 4}{sup {minus}}), a stable (non-radioactive) chemical surrogate for {sup 99}TcO{sub 4}{sup {minus}}. Results are discussed for alternate organic solvents; metalloporphyrins, ferrocenes, and N-cetyl pyridium nitrate as alternate extractant salts; electroactive polymers; and recovery of ReO{sub 4}{sup {minus}} and TcO{sub 4}{sup {minus}}.

  15. Method and apparatus for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1983-06-21

    A method and apparatus for synthesizing a mixture of hydrocarbons having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further includes Na present as a substitutional cation in an amount of about 5 to 10 atom %. At a temperature of about 340 to 360/sup 0/C, and at pressures of about 20 to 50 atm, CH/sub 3/OH is produced in an amount of about 90 wt % of the total hydrocarbon mixture, and comprised 1 mole % of the effluent gas.

  16. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  17. Assessment of simulation predictions of hydrocarbon pool fire tests.

    SciTech Connect (OSTI)

    Luketa-Hanlin, Anay Josephine

    2010-04-01

    An uncertainty quantification (UQ) analysis is performed on the fuel regression rate model within SIERRA/Fuego by comparing to a series of hydrocarbon tests performed in the Thermal Test Complex. The fuels used for comparison for the fuel regression rate model include methanol, ethanol, JP8, and heptane. The recently implemented flamelet combustion model is also assessed with a limited comparison to data involving measurements of temperature and relative mole fractions within a 2-m diameter methanol pool fire. The comparison of the current fuel regression rate model to data without UQ indicates that the model over predicts the fuel regression rate by 65% for methanol, 63% for ethanol, 95% for JP8, and 15% for heptane. If a UQ analysis is performed incorporating a range of values for transmittance, reflectance, and heat flux at the surface the current model predicts fuel regression rates within 50% of measured values. An alternative model which uses specific heats at inlet and boiling temperatures respectively and does not approximate the sensible heat is also compared to data. The alternative model with UQ significantly improves the comparison to within 25% for all fuels except heptane. Even though the proposed alternative model provides better agreement to data, particularly for JP8 and ethanol (within 15%), there are still outstanding issues regarding significant uncertainties which include heat flux gauge measurement and placement, boiling at the fuel surface, large scale convective motion within the liquid, and semi-transparent behavior.

  18. Process for mild hydrocracking of hydrocarbon feeds

    SciTech Connect (OSTI)

    Nevitt, T.D.; Hopkins, P.D.; Tait, A.M.

    1984-02-14

    A process for mild hydrocracking of hydrocarbon feeds comprising contacting the feed with hydrogen under mild hydrocracking conditions in the presence of a catalytic composition comprising an active metallic component comprising at least one metal having hydrogenation activity and at least one oxygenated phosphorus component, and a support component comprising at least one non-zeolitic, porous refractory inorganic oxide matrix component and at least one shape selective crystalline molecular sieve zeolite component.

  19. Characterization and quantitative analyses of polychlorinated hydrocarbons 

    E-Print Network [OSTI]

    Richardson, Robert Leary

    1974-01-01

    and quantitativ' analyses of certain poly- chlorinated hydrocarbons (PCB, !iDT and its metabolites in marine biota) were investigated. The occurence ot these compounds were expected at such low concentrations the use of the elec, tron capt gas... of contamination improved the sensitivity of detection of these chlorinated hydro- carbons to the parts per bi'!lion range. A variety of samples from the Gulf of Nexi co and Northern Caribbean were analyzed. The analytical procedure consisted of macerating...

  20. Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons

    DOE Patents [OSTI]

    Kung, H.H.; Chaar, M.A.

    1988-10-11

    Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

  1. Getter pump for hydrogen and hydrocarbon gases

    DOE Patents [OSTI]

    Hsu, Wen Ling

    1987-10-14

    A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

  2. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A. (Augusta, GA)

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  3. Auxiliary reactor for a hydrocarbon reforming system

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Dorson, Matthew H.; Mitchell, William L.; Nowicki, Brian J.; Bentley, Jeffrey M.; Davis, Robert; Rumsey, Jennifer W.

    2006-01-17

    An auxiliary reactor for use with a reformer reactor having at least one reaction zone, and including a burner for burning fuel and creating a heated auxiliary reactor gas stream, and heat exchanger for transferring heat from auxiliary reactor gas stream and heat transfer medium, preferably two-phase water, to reformer reaction zone. Auxiliary reactor may include first cylindrical wall defining a chamber for burning fuel and creating a heated auxiliary reactor gas stream, the chamber having an inlet end, an outlet end, a second cylindrical wall surrounding first wall and a second annular chamber there between. The reactor being configured so heated auxiliary reactor gas flows out the outlet end and into and through second annular chamber and conduit which is disposed in second annular chamber, the conduit adapted to carry heat transfer medium and being connectable to reformer reaction zone for additional heat exchange.

  4. Hydrocarbon Fouling of SCR during PCCI combustion

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y [ORNL; Pihl, Josh A [ORNL; Lewis Sr, Samuel Arthur [ORNL; Parks, II, James E [ORNL

    2012-01-01

    The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust. The Fe-zeolite NOX conversion efficiency was significantly degraded, especially at low temperatures (<250 C), after the catalyst was exposed to the raw engine exhaust. The degradation of the Fe-zeolite performance was similar for both combustion modes. The Cu-zeolite showed better tolerance to HC fouling at low temperatures compared to the Fe-zeolite but PCCI exhaust had a more significant impact than the exhaust from conventional combustion on the NOX conversion efficiency. Furthermore, chemical analysis of the hydrocarbons trapped on the SCR cores was conducted to better determine chemistry specific effects.

  5. Physically-based Models for Liquid Sounds Kees van den Doel

    E-Print Network [OSTI]

    van den Doel, Kees

    of complex liquid sounds such as produced by streams, pouring water, rivers, rain, and breaking waves: Water 1. INTRODUCTION The sounds made by liquids, especially those of water, are prevalent in our such as dripping water are more deterministic in their time domain structure. A "brute force" approach

  6. Georgia Institute ofTechnology | Milwaukee School of Engineering | North Carolina A&T State University | Purdue University | University of Illinois, Urbana-Champaign | University of Minnesota |Vanderbilt University Project 2B: Free Liquid-Piston Engine Co

    E-Print Network [OSTI]

    Barth, Eric J.

    |Vanderbilt University Project 2B: Free Liquid-Piston Engine Compressor with Separated Combustion Chamber · Convert chemically stored energy of a hydrocarbon fuel (propane) into pneumatic potential energy of cool Combustion Pressure (Simulation) Combustion Pressure (Experimental) Valve Displacement (Simulation) Ferrous

  7. STREAM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) byMultidayAlumni > The2/01/12 PageInformation DoE Pages DoE

  8. STREAM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) byMultidayAlumni > The2/01/12 PageInformation DoE Pages DoESTREAM

  9. Selective catalytic reduction system and process for control of NO.sub.x emissions in a sulfur-containing gas stream

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly

    2015-08-11

    An exhaust gas treatment process, apparatus, and system for reducing the concentration of NOx, CO and hydrocarbons in a gas stream, such as an exhaust stream (29), via selective catalytic reduction with ammonia is provided. The process, apparatus and system include a catalytic bed (32) having a reducing only catalyst portion (34) and a downstream reducing-plus-oxidizing portion (36). Each portion (34, 36) includes an amount of tungsten. The reducing-plus-oxidizing catalyst portion (36) advantageously includes a greater amount of tungsten than the reducing catalyst portion (36) to markedly limit ammonia salt formation.

  10. Enhanced catalyst for converting synthesis gas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K. (Yorktown Heights, NY)

    1986-01-01

    The conversion of synthesis gas to liquid molar fuels by means of a cobalt Fischer-Tropsch catalyst composition is enhanced by the addition of molybdenum, tungsten or a combination thereof as an additional component of said composition. The presence of the additive component increases the olefinic content of the hydrocarbon products produced. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

  11. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  12. Waste Stream Approval - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout /Two0Photos and Videos/01/2012 Page 1 of 10SamplingStream

  13. An investigation of the thermal degradation mechanisms of a waste tire through chemical analysis including hydrocarbons, benzene derivatives, and Polycyclic

    E-Print Network [OSTI]

    including hydrocarbons, benzene derivatives, and Polycyclic Aromatic Hydrocarbons (PAHs) at high temperature-to-Energy, Volatile Organic Carbons (VOCs), Polycyclic Aromatic Hydrocarbons (PAHs), Hetero-N containing PAH

  14. Polycyclic Aromatic Hydrocarbons in Indoor Air and Environmental Tobacco Smoke Measured with a New Integrated Organic Vapor-Particle Sampler

    E-Print Network [OSTI]

    Gundel, L.A.; Daisey, J.M.; Mahanama, K.R.R.; Lee, C.C.; Stevens, R.K.

    1993-01-01

    of polycyclic aromatic hydrocarbons in environmental tobaccoof polycyclic aromatic hydrocarbons. Indoor Air 1991;1:497-NK. Polycyclic aromatic hydrocarbons and their derivatives

  15. Applications of contaminant fate and bioaccumulation models in assessing ecological risks of chemicals: A case study for gasoline hydrocarbons

    E-Print Network [OSTI]

    MacLeod, Matthew; McKone, Thomas E.; Foster, Karen L.; Maddalena, Randy L.; Parkerton, Thomas F.; Mackay, Don

    2004-01-01

    A Case Study for Gasoline Hydrocarbons Matthew MacLeod 1 ,since the component hydrocarbons comprising this complexthat the component hydrocarbons comprising this complex

  16. Real-time characterization of particle-bound polycyclic aromatic hydrocarbons in ambient aerosols and from motor-vehicle exhaust

    E-Print Network [OSTI]

    Polidori, A.; Hu, S.; Biswas, S.; Delfino, R. J; Sioutas, C.

    2008-01-01

    of polycyclic aromatic hydrocarbons in coupled out- door/polycyclic aromatic hydrocarbon concentration in combustionbound polycyclic aromatic hydrocarbons K. A. , Morris, J. ,

  17. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  18. Toxicity cutoff of aromatic hydrocarbons for luminescence inhibition of Vibrio fischeri

    E-Print Network [OSTI]

    McFall-Ngai, Margaret

    Toxicity cutoff of aromatic hydrocarbons for luminescence inhibition of Vibrio fischeri So Polycyclic aromatic hydrocarbons a b s t r a c t Effects of individual petroleum hydrocarbons hydrocarbons, including benzene and its derivatives and polycyclic aromatic hydrocarbons (PAHs), were chosen

  19. Hydrocarbon analysis of shrimp from oil polluted waters 

    E-Print Network [OSTI]

    DeWitt, Bernard John

    1982-01-01

    but ubiquitous compounds in the marine environment (Clark and Finley, 1973). They occur in marine organisms, in sediments and in seawater according to Clark and Blumer (1967). To determine oil pollution, a means of differentiating petroleum hydrocarbons from... in the marine environment for long periods. They enter the environment from fossil fuels and decaying marine organisms (Clark and Blumer, 1967). Therefore pollution and biogenic hydrocarbons contain the same hydrocarbons, although from different sources...

  20. Use of once-through treat gas to remove the heat of reaction in solvent hydrogenation processes

    DOE Patents [OSTI]

    Nizamoff, Alan J. (Convent Station, NJ)

    1980-01-01

    In a coal liquefaction process wherein feed coal is contacted with molecular hydrogen and a hydrogen-donor solvent in a liquefaction zone to form coal liquids and vapors and coal liquids in the solvent boiling range are thereafter hydrogenated to produce recycle solvent and liquid products, the improvement which comprises separating the effluent from the liquefaction zone into a hot vapor stream and a liquid stream; cooling the entire hot vapor stream sufficiently to condense vaporized liquid hydrocarbons; separating condensed liquid hydrocarbons from the cooled vapor; fractionating the liquid stream to produce coal liquids in the solvent boiling range; dividing the cooled vapor into at least two streams; passing the cooling vapors from one of the streams, the coal liquids in the solvent boiling range, and makeup hydrogen to a solvent hydrogenation zone, catalytically hydrogenating the coal liquids in the solvent boiling range and quenching the hydrogenation zone with cooled vapors from the other cooled vapor stream.

  1. Systems and methods for producing hydrocarbons from tar sands formations

    DOE Patents [OSTI]

    Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

    2009-07-21

    A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

  2. Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization...

    Energy Savers [EERE]

    and enable production of drop-in hydrocarbon fuels more quickly, in addition to expanding production of jet fuel, diesel, and renewable commodity chemicals. In addition, Oak...

  3. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Ken Rapp, Liyu Li, Jonathan Male, Dave King Pacific Northwest National...

  4. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  5. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  6. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (OFCVT). deer07rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Selectlive Catalytic Reducution of...

  7. ILENR/RE-AQ-ON-ROAD CARBON MONOXIDE AND HYDROCARBON

    E-Print Network [OSTI]

    Denver, University of

    #12;ILENR/RE-AQ- Printed: Contract: Project: ON-ROAD CARBON MONOXIDE AND HYDROCARBON REMOTE SENSING. Repeat Measurements of the Same Vehicle. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 F

  8. Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst

    Broader source: Energy.gov [DOE]

    Understanding what reactions and which catalytic functions are affected by hydrocarbons can lead to improved tolerances for selective catalytic reduction performance

  9. Methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Nelson, Lee O. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

    2009-02-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  10. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Lean NOx Catalysis Research and Development...

  11. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production from Sewage Sludge

    Office of Energy Efficiency and Renewable Energy (EERE)

    Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste FeedstocksEnhanced Anaerobic Digestion and Hydrocarbon Precursor Production from Sewage...

  12. Performance of a Thermally Stable Polyaromatic Hydrocarbon in...

    Office of Scientific and Technical Information (OSTI)

    Performance of a Thermally Stable Polyaromatic Hydrocarbon in a Simulated Concentrating Solar Power Loop Citation Details In-Document Search Title: Performance of a Thermally...

  13. Ozone production and hydrocarbon reactivity in Hong Kong, Southern China

    E-Print Network [OSTI]

    2007-01-01

    Middleton, P. , and Wang, T. : Ozone precursor relationshipsJ. Zhang et al. : Ozone production and hydrocarbonKiang, C. S. : Ground- level ozone pollution in Hong Kong,

  14. Fuel Cell Technologies Office Overview: 2015 Hydrogen, Hydrocarbons...

    Broader source: Energy.gov (indexed) [DOE]

    Introductory presentation by Sunita Satyapal, U.S. Department of Energy Fuel Cell Technologies Office Director, at the Hydrogen, Hydrocarbons, and Bioproduct Precursors from...

  15. Sandia Energy - ECIS-Automotive Fuel Cell Corporation: Hydrocarbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ECIS-Automotive Fuel Cell Corporation: Hydrocarbon Membrane Fuels the Success of Future Generation Vehicles Home Energy Transportation Energy CRF Partnership Energy Efficiency...

  16. Process for making unsaturated hydrocarbons using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

    2011-04-12

    The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

  17. Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to simultaneously reduce NOx and PM. Ex: HC poisoninginhibition on zeolites1, catalyst aging, etc. deer09devarakonda.pdf More Documents & Publications The Effects of Hydrocarbons...

  18. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathway This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion...

  19. Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Algal Lipid Extraction and...

  20. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified....

  1. Biological Conversion of Sugars to Hydrocarbons Technology Pathway...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathway This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and...

  2. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    valve~ allowing the energy of the sun in, but not letting itwe used the stored energy of the sun in the form of wood (awhich could use the energy of the sun to create liquid fuel

  3. Fundamental measure theory of hydrated hydrocarbons

    E-Print Network [OSTI]

    Victor F. Sokolov; Gennady N. Chuev

    2006-04-13

    To calculate the solvation of hydrophobic solutes we have developed the method based on the fundamental measure treatment of the density functional theory. This method allows us to carry out calculations of density profiles and the solvation energy for various hydrophobic molecules with a high accuracy. We have applied the method to the hydration of various hydrocarbons (linear, branched and cyclic). The calculations of the entropic and the enthalpic parts are also carried out. We have examined a question about temperature dependence of the entropy convergence. Finally, we have calculated the mean force potential between two large hydrophobic nanoparticles immersed in water.

  4. Hydrocarbon synthesis catalyst and method of preparation

    DOE Patents [OSTI]

    Sapienza, Richard S. (Shoreham, NY); Sansone, Michael J. (Summit, NJ); Slegeir, William A. R. (Hampton Bays, NY)

    1983-08-02

    A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

  5. Hydrocarbon synthesis catalyst and method of preparation

    DOE Patents [OSTI]

    Sapienza, R.S.; Sansone, M.J.; Slegeir, W.A.R.

    1983-08-02

    A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint. 9 figs.

  6. Plasma-Hydrocarbon conversion - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access| DepartmentPeerFederal FleetUpSmallHydrocarbon conversion Idaho

  7. Gulf Hydrocarbon Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam: Energy Resources Jump to: navigation,LowGuinea:Hydrocarbon

  8. Selection of Controlled Variables for a Natural Gas to Liquids Process Mehdi Panahi and Sigurd Skogestad*

    E-Print Network [OSTI]

    Skogestad, Sigurd

    variables (CVs) for a natural gas to hydrocarbon liquids (GTL) process based on the idea of self,393 USD/h. Adding one, two, and three measurements and controlling measurement combinations decrease to the case when RTO is used. By using measurement combinations, the loss can often be decreased significantly

  9. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, James B. (Denville, NJ); Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (Somerville, NJ)

    1989-01-01

    A process for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600.degree.-750.degree. F. to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650.degree. F. and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-90 lb/hr per ft.sup.3 catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760.degree.-860.degree. F. temperature for further hydrogenation and hydroconversion reactions. A 600.degree.-750.degree. F..sup.+ fraction containing 0-20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials.

  10. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

    1989-10-17

    A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

  11. Streaming Currents in a Single Nanofluidic Channel Frank H. J. van der Heyden, Derek Stein, and Cees Dekker

    E-Print Network [OSTI]

    Dekker, Cees

    differences into electrical energy [11], and that this process becomes particularly efficient in the nano, The Netherlands (Received 4 May 2005; published 8 September 2005) We report measurements of the streaming current properties of the solid-liquid interface as they result from the transport of counterions in the electric

  12. Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources

    SciTech Connect (OSTI)

    Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

    2008-10-01

    Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

  13. Effects of chemical additives on hydrocarbon disappearance and biodegradation in freshwater marsh microcosms

    E-Print Network [OSTI]

    Nyman, John

    determined the concentration of four total petroleum hydrocarbon (TPH) measures and 43 target hydro- carbonsEffects of chemical additives on hydrocarbon disappearance and biodegradation in freshwater marsh 2006 Hydrocarbon disappearance and biodegradation were insensitive to common commercial additives

  14. Stimulating the anaerobic degradation of aromatic hydrocarbons in contaminated sediments by providing

    E-Print Network [OSTI]

    Lovley, Derek

    Stimulating the anaerobic degradation of aromatic hydrocarbons in contaminated sediments to simulate the degradation of aromatic hydrocarbons in anaerobic contaminated sediments was investigated as the sole electron acceptor. Providing graphite electrodes as an electron acceptor in hydrocarbon

  15. Field metabolomics and laboratory assessments of anaerobic intrinsic bioremediation of hydrocarbons

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Field metabolomics and laboratory assessments of anaerobic intrinsic bioremediation of hydrocarbons the in situ anaerobic attenuation of hydrocarbons in a contaminated aquifer underly- ing a former refinery. Metabolite profiles associated with anaerobic hydrocarbon decay revealed the microbial utilization

  16. Lasius niger ants discriminate aphids based on their cuticular hydrocarbons Corsin Langa,1

    E-Print Network [OSTI]

    Richner, Heinz

    Lasius niger ants discriminate aphids based on their cuticular hydrocarbons Corsin Langa,1 chemical communication cuticular hydrocarbon interspecific communication Lasius niger mutualism species covered with aphid cuticular hydrocarbons. Neutral control objects were antennated, but the ants quickly

  17. HYDROCARBONS OF BIOLOGICAL ORIGIN FROM A ONE-BILLION YEAR OLD SEDIMENT

    E-Print Network [OSTI]

    Eglinton, Geoffrey.; Scott, P.M.; Belsky, Ted.; Burlingame, A.L.; Calvin, Melvin.; Cloud Jr., Preston E.

    1964-01-01

    Contract No. W-7405-eng-48 HYDROCARBONS OF BIOLOGICAL ORIGINAbstract The isoprenoid hydrocarbons, phytane (C 20H4Z) andThe identification of these hydrocarbons augurs well for the

  18. Heterogeneous OH Oxidation of Motor Oil Particles Causes Selective Depletion of Branched and Less Cyclic Hydrocarbons

    E-Print Network [OSTI]

    Goldstein, Allen

    Cyclic Hydrocarbons Gabriel Isaacman,, * Arthur W. H. Chan, Theodora Nah, David R. Worton,,§ Chris R of hydrocarbon mixtures typical of anthropogenic atmospheric particulate matter, but its complexity often reaction rates of observed hydrocarbon classes: alkanes, cycloalkanes, bicycloalkanes, tricycloalkanes

  19. The Hydrophobic Effect Drives the Recognition of Hydrocarbons by an Anionic Metal-Ligand Cluster

    E-Print Network [OSTI]

    Biros, Shannon

    2009-01-01

    Drives the Recognition of Hydrocarbons by an Anionic Metal-Drives the Recognition of Hydrocarbons by an Anionic Metal-including saturated hydrocarbons, 11,12 in aqueous solution,

  20. Cyclic Versus Linear Isomers Produced by Reaction of the Methylidyne Radical (CH) with Small Unsaturated Hydrocarbons

    E-Print Network [OSTI]

    Goulay, Fabien

    2010-01-01

    with Small Unsaturated Hydrocarbons Fabien Goulay, 1, †,‡react with the selected hydrocarbon in a helium gas flow.Small cyclic unsaturated hydrocarbons such as c-C 3 H, c-C 3

  1. Isomeric differentiation of polycyclic aromatic hydrocarbons using silver nitrate reactive desorption electrospray ionization

    E-Print Network [OSTI]

    Zare, Richard N.

    Isomeric differentiation of polycyclic aromatic hydrocarbons using silver nitrate reactive hydrocarbons (PAHs) are nonpolar and difficult to detect by desorption electrospray ionization. We present. Polycyclic aromatic hydrocarbons (PAHs) are one of the most prevalent forms of aquatic environmental

  2. Adsorption of unsaturated hydrocarbons on zeolites: the eects of the zeolite framework on adsorption

    E-Print Network [OSTI]

    Truong, Thanh N.

    Adsorption of unsaturated hydrocarbons on zeolites: the eects of the zeolite framework industrially important reactions, namely the polymerization and hydrocarbon cracking processes [9 as a starting point for a more comprehensive study on hydrocarbon cracking and ethylene epoxidation reactions

  3. State Waste Discharge Permit application for industrial discharge to land: 200 East Area W-252 streams

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    This document constitutes the WAC 173-216 State Waste Discharge Permit application for six W-252 liquid effluent streams at the Hanford Site. Appendices B through H correspond to Section B through H in the permit application form. Within each appendix, sections correspond directly to the respective questions on the application form. The appendices include: Product or service information; Plant operational characteristics; Water consumption and waterloss; Wastewater information; Stormwater; Other information; and Site assessment.

  4. Liquid Hydrogen Bubble Chambers

    E-Print Network [OSTI]

    Alvarez, Luis W.

    1956-01-01

    t No. W - 7 4 0 5 -eng-48 ,LIQUID HYDROGEN EUSBLE CHA,MBEEZSand 3erkeley to iind if liquid hydrogen could be used as thethat supezheated 'liquid hydrogen could be made to boil

  5. Liquid foams of graphene

    E-Print Network [OSTI]

    Alcazar Jorba, Daniel

    2012-01-01

    Liquid foams are dispersions of bubbles in a liquid. Bubbles are stabilized by foaming agents that position at the interface between the gas and the liquid. Most foaming agents, such as the commonly used sodium dodecylsulfate, ...

  6. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2001-01-01

    A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  7. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, H.; Blatter, F.; Sun, H.

    1999-06-22

    A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

  8. Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE and to install heat pumps in unoccupied spaces. Nevertheless manufacturers keep working on components for hydrocarbons. In the frame of a research project on heat pumps for simultaneous heating and cooling, an R407C

  9. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    1999-01-01

    A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  10. Selective thermal oxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2000-01-01

    A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  11. Conundrum of the Large Scale Streaming

    E-Print Network [OSTI]

    T. M. Malm

    1999-09-12

    The etiology of the large scale peculiar velocity (large scale streaming motion) of clusters would increasingly seem more tenuous, within the context of the gravitational instability hypothesis. Are there any alternative testable models possibly accounting for such large scale streaming of clusters?

  12. THE PAL 5 STAR STREAM GAPS

    SciTech Connect (OSTI)

    Carlberg, R. G.; Hetherington, Nathan [Department of Astronomy and Astrophysics, University of Toronto, Toronto, ON M5S 3H4 (Canada); Grillmair, C. J., E-mail: carlberg@astro.utoronto.ca, E-mail: hetherington@astro.utoronto.ca, E-mail: carl@ipac.caltech.edu [Spitzer Science Center, 1200 E. California Blvd., Pasadena, CA 91125 (United States)

    2012-11-20

    Pal 5 is a low-mass, low-velocity-dispersion, globular cluster with spectacular tidal tails. We use the Sloan Digital Sky Survey Data Release 8 data to extend the density measurements of the trailing star stream to 23 deg distance from the cluster, at which point the stream runs off the edge of the available sky coverage. The size and the number of gaps in the stream are measured using a filter which approximates the structure of the gaps found in stream simulations. We find 5 gaps that are at least 99% confidence detections with about a dozen gaps at 90% confidence. The statistical significance of a gap is estimated using bootstrap resampling of the control regions on either side of the stream. The density minimum closest to the cluster is likely the result of the epicyclic orbits of the tidal outflow and has been discounted. To create the number of 99% confidence gaps per unit length at the mean age of the stream requires a halo population of nearly a thousand dark matter sub-halos with peak circular velocities above 1 km s{sup -1} within 30 kpc of the galactic center. These numbers are a factor of about three below cold stream simulation at this sub-halo mass or velocity but, given the uncertainties in both measurement and more realistic warm stream modeling, are in substantial agreement with the LCDM prediction.

  13. GAPS IN THE GD-1 STAR STREAM

    SciTech Connect (OSTI)

    Carlberg, R. G. [Department of Astronomy and Astrophysics, University of Toronto, Toronto, ON M5S 3H4 (Canada); Grillmair, C. J., E-mail: carlberg@astro.utoronto.ca, E-mail: carl@ipac.caltech.edu [Spitzer Science Center, 1200 East California Boulevard, Pasadena, CA 91125 (United States)

    2013-05-10

    GD-1 is a long, thin, Milky Way star stream that has readily visible density variations along its length. We quantify the locations, sizes, and statistical significance of the density structure, i.e., gaps, using a set of scaled filters. The shapes of the filters are based on the gaps that develop in simulations of dark matter sub-halos crossing a star stream. The high Galactic latitude 8.4 kpc long segment of GD-1 that we examine has 8 {+-} 3 gaps of 99% significance or greater, with the error estimated on the basis of tests of the gap-filtering technique. The cumulative distribution of gaps more than three times the width of the stream is in good agreement with predictions for dark matter sub-halo encounters with cold star streams. The number of gaps narrower than three times the width of the GD-1 stream falls well below the cold stream prediction which is taken into account for the gap creation rate integrated over all sizes. Simple warm stream simulations scaled to GD-1 show that the falloff in gaps is expected for sub-halos below a mass of 10{sup 6} M{sub Sun }. The GD-1 gaps requires 100 sub-halos >10{sup 6} M{sub Sun} within 30 kpc, the apocenter of GD-1 orbit. These results are consistent with LCDM sub-halo predictions but further improvements in stream signal-to-noise and gap modeling will be welcome.

  14. Mining Sequential Patterns from Temporal Streaming Data

    E-Print Network [OSTI]

    Malerba, Donato

    Mining Sequential Patterns from Temporal Streaming Data A. Marascu and F. Masseglia INRIA Sophia.Marascu,Florent.Masseglia}@sophia.inria.fr Abstract. In recent years, emerging applications introduced new con- straints for data mining methods of our knowledge, no method has been proposed for mining sequential patterns in data streams. We argue

  15. Heating hydrocarbon containing formations in a line drive staged process

    DOE Patents [OSTI]

    Miller, David Scott (Katy, TX)

    2009-07-21

    Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

  16. Cogeneration systems and processes for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

    2009-12-29

    A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

  17. Application of Metagenomics for Identification of Novel Petroleum Hydrocarbon Degrading Enzymes in Natural Asphalts from the Rancho La Brea Tar Pits

    E-Print Network [OSTI]

    Baquiran, Jean-Paul Mendoza

    2010-01-01

    of petroleum hydrocarbon-contaminated ground water: Theof petroleum hydrocarbon-contaminated ground water: The

  18. Quantitative measurement of binary liquid distributions using multiple-tracer x-ray fluorescence and radiography

    SciTech Connect (OSTI)

    Halls, Benjamin R.; Meyer, Terrence R.; Kastengren, Alan L.

    2015-01-01

    The complex geometry and large index-of-refraction gradients that occur near the point of impingement of binary liquid jets present a challenging environment for optical interrogation. A simultaneous quadruple-tracer x-ray fluorescence and line-of-sight radiography technique is proposed as a means of distinguishing and quantifying individual liquid component distributions prior to, during, and after jet impact. Two different pairs of fluorescence tracers are seeded into each liquid stream to maximize their attenuation ratio for reabsorption correction and differentiation of the two fluids during mixing. This approach for instantaneous correction of x-ray fluorescence reabsorption is compared with a more time-intensive approach of using stereographic reconstruction of x-ray attenuation along multiple lines of sight. The proposed methodology addresses the need for a quantitative measurement technique capable of interrogating optically complex, near-field liquid distributions in many mixing systems of practical interest involving two or more liquid streams.

  19. Quantitative measurement of binary liquid distributions using multiple-tracer x-ray fluorescence and radiography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Halls, Benjamin R.; Meyer, Terrence R.; Kastengren, Alan L.

    2015-01-23

    The complex geometry and large index-of-refraction gradients that occur near the point of impingement of binary liquid jets present a challenging environment for optical interrogation. A simultaneous quadruple-tracer x-ray fluorescence and line-of-sight radiography technique is proposed as a means of distinguishing and quantifying individual liquid component distributions prior to, during, and after jet impact. Two different pairs of fluorescence tracers are seeded into each liquid stream to maximize their attenuation ratio for reabsorption correction and differentiation of the two fluids during mixing. This approach for instantaneous correction of x-ray fluorescence reabsorption is compared with a more time-intensive approach of usingmore »stereographic reconstruction of x-ray attenuation along multiple lines of sight. The proposed methodology addresses the need for a quantitative measurement technique capable of interrogating optically complex, near-field liquid distributions in many mixing systems of practical interest involving two or more liquid streams.« less

  20. Phase-Changing Ionic Liquids: CO2 Capture with Ionic Liquids Involving Phase Change

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: Notre Dame is developing a new CO2 capture process that uses special ionic liquids (ILs) to remove CO2 from the gas exhaust of coal-fired power plants. ILs are salts that are normally liquid at room temperature, but Notre Dame has discovered a new class of ILs that are solid at room temperature and change to liquid when they bind to CO2. Upon heating, the CO2 is released for storage, and the ILs re-solidify and donate some of the heat generated in the process to facilitate further CO2 release. These new ILs can reduce the energy required to capture CO2 from the exhaust stream of a coal-fired power plant when compared to state-ofthe- art technology.

  1. Microbial hydrocarbons: back to the future

    SciTech Connect (OSTI)

    Work, Victoria H.; Beliaev, Alex S.; Konopka, Allan; Posewitz, Matthew C.

    2012-03-01

    The defining challenge of energy research in the 21st century is the development and deployment of technologies for large-scale reconfiguration of global energy infrastructure. Modern society is built upon a concentrated yet finite reservoir of diverse hydrocarbons formed through the photosynthetic transformation of several hundred million years of solar energy. In human history, the fossil energy era will be short lived and never repeated. Although the timing of peak oil is extensively debated, it is an eventuality. It is, therefore, imperative that projections for both when it will occur and the degree to which supply will fall short of demand be taken into serious consideration, especially in the sectors of energy technology development, political and economic decision making, and societal energy usage. The requirement for renewable energy systems is no longer a point for discussion, and swift advances on many fronts are vital to counteract current and impending crises in both energy and the environment.

  2. Method and apparatus for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1985-04-16

    A method and apparatus for synthesizing a mixture of aliphatic alcohols having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further optionally includes Na ions present as substitutional cations in an amount of about 5 to 10 atom %. At a temperature of about 570 to 630/sup 0/K, and at pressures of about 20 to 50 atm, methanol and isobutanol are the predominant products and are produced in amounts of about 90 wt % of the total hydrocarbon mixture. 6 figs.

  3. System and process for upgrading hydrocarbons

    SciTech Connect (OSTI)

    Bingham, Dennis N.; Klingler, Kerry M.; Smith, Joseph D.; Turner, Terry D.; Wilding, Bruce M.

    2015-08-25

    In one embodiment, a system for upgrading a hydrocarbon material may include a black wax upgrade subsystem and a molten salt gasification (MSG) subsystem. The black wax upgrade subsystem and the MSG subsystem may be located within a common pressure boundary, such as within a pressure vessel. Gaseous materials produced by the MSG subsystem may be used in the process carried out within the black wax upgrade subsystem. For example, hydrogen may pass through a gaseous transfer interface to interact with black wax feed material to hydrogenate such material during a cracking process. In one embodiment, the gaseous transfer interface may include one or more openings in a tube or conduit which is carrying the black wax material. A pressure differential may control the flow of hydrogen within the tube or conduit. Related methods are also disclosed.

  4. Pyrochlore catalysts for hydrocarbon fuel reforming

    DOE Patents [OSTI]

    Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

    2012-08-14

    A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

  5. Safetygram #9- Liquid Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE)

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  6. Guidance Document Cryogenic Liquids

    E-Print Network [OSTI]

    . Liquid hydrogen, liquid methane or liquefied natural gas could form an extremely flammable mixtureGuidance Document Cryogenic Liquids [This is a brief and general summary. Read the full MSDS for more details before handling.] Introduction: All cryogenic liquids are gases at normal temperature

  7. A Literature Review on Value Stream Mapping with a Case Study of Applying Value Stream Mapping on Research Process 

    E-Print Network [OSTI]

    Li, Xiaoqi

    2014-04-23

    has two main objectives. The first is an in-depth literature review on value stream mapping, especially concerning useful value stream mapping tools and the application of value stream mapping in construction industry. The literature review of value...

  8. Hydrocarbon characterization experiments in fully turbulent fires : results and data analysis.

    SciTech Connect (OSTI)

    Suo-Anttila, Jill Marie; Blanchat, Thomas K.

    2011-03-01

    As the capabilities of numerical simulations increase, decision makers are increasingly relying upon simulations rather than experiments to assess risks across a wide variety of accident scenarios including fires. There are still, however, many aspects of fires that are either not well understood or are difficult to treat from first principles due to the computational expense. For a simulation to be truly predictive and to provide decision makers with information which can be reliably used for risk assessment the remaining physical processes must be studied and suitable models developed for the effects of the physics. The model for the fuel evaporation rate in a liquid fuel pool fire is significant because in well-ventilated fires the evaporation rate largely controls the total heat release rate from the fire. This report describes a set of fuel regression rates experiments to provide data for the development and validation of models. The experiments were performed with fires in the fully turbulent scale range (> 1 m diameter) and with a number of hydrocarbon fuels ranging from lightly sooting to heavily sooting. The importance of spectral absorption in the liquid fuels and the vapor dome above the pool was investigated and the total heat flux to the pool surface was measured. The importance of convection within the liquid fuel was assessed by restricting large scale liquid motion in some tests. These data sets provide a sound, experimentally proven basis for assessing how much of the liquid fuel needs to be modeled to enable a predictive simulation of a fuel fire given the couplings between evaporation of fuel from the pool and the heat release from the fire which drives the evaporation.

  9. Evaluation of Side Stream Filtration Technology at Oak Ridge...

    Office of Environmental Management (EM)

    ssfevaluation.pdf More Documents & Publications Side Stream Filtration for Cooling Towers Technical Evaluation of Side Stream Filtration for Cooling Towers Cooling...

  10. Interpretation of ageostrophic winds and implications for jet stream maintenance

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Interpretation of ageostrophic winds and implications for jet stream maintenance Article Published Version Blackburn, M. (1985) Interpretation of ageostrophic winds and implications for jet stream

  11. Tracking and Using Data to Support Revenue Streams | Department...

    Energy Savers [EERE]

    Tracking and Using Data to Support Revenue Streams Tracking and Using Data to Support Revenue Streams Better Buildings Neighborhood Program Data and Evaluation Peer Exchange Call:...

  12. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  13. High pressure liquid chromatographic gradient mixer

    DOE Patents [OSTI]

    Daughton, Christian G. (San Pablo, CA); Sakaji, Richard H. (El Cerrito, CA)

    1985-01-01

    A gradient mixer which effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum "band-broadening".

  14. High-pressure liquid chromatographic gradient mixer

    DOE Patents [OSTI]

    Daughton, C.G.; Sakaji, R.H.

    1982-09-08

    A gradient mixer effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum band-broadening.

  15. Method for making hydrogen rich gas from hydrocarbon fuel

    DOE Patents [OSTI]

    Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

    1999-01-01

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

  16. Method for making hydrogen rich gas from hydrocarbon fuel

    DOE Patents [OSTI]

    Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

    1999-07-27

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

  17. Non-Sticking of Helium Buffer Gas to Hydrocarbons

    E-Print Network [OSTI]

    Croft, James F E

    2014-01-01

    Lifetimes of complexes formed during helium-hydrocarbon collisions at low temperature are estimated for symmetric top hydrocarbons. The lifetimes are obtained using a density-of-states approach. In general the lifetimes are less than 10-100 ns, and are found to decrease with increasing hydrocarbon size. This suggests that clustering will not limit precision spectroscopy in helium buffer gas experiments. Lifetimes are computed for noble-gas benzene collisions and are found to be in reasonable agreement with lifetimes obtained from classical trajectories as reported by Cui {\\it et al}.

  18. Iraq`s significant hydrocarbon potential remains relatively undeveloped

    SciTech Connect (OSTI)

    AL-Gailani, M. [GeoDesign Ltd., Kingston-upon-Thames (United Kingdom)

    1996-07-29

    Iraq is probably one of the least explored countries in the Middle East, despite the fact that it possesses one of the richest hydrocarbon basins in the world almost on a par to Saudi Arabia`s potential, if not more. The aim of this article is to state the facts about Iraq and focus on the huge but untapped and undeveloped hydrocarbon resources to the international oil community. Perhaps it is best to start by describing briefly the sedimentary and tectonic elements responsible for accumulating such large hydrocarbon resources. The paper describes the basin, tectonic elements, structural anomalies, deep drilling, source rocks, reservoir rocks, characteristics, and new reserves.

  19. Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

    E-Print Network [OSTI]

    Dennis, J A

    1971-01-01

    Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

  20. Hydrocarbons on Harvester Ant (Pogonomyrmex barbatus) Middens Guide Foragers to the Nest

    E-Print Network [OSTI]

    Gordon, Deborah

    Hydrocarbons on Harvester Ant (Pogonomyrmex barbatus) Middens Guide Foragers to the Nest Shelby J hydrocarbons are used by social insects in nestmate recognition. Here, we showed that hydrocarbons found-specific hydrocarbons, which ants use to distinguish nestmates from non-nestmates, are found on the midden pebbles

  1. Language design for distributed stream processing

    E-Print Network [OSTI]

    Newton, Ryan Rhodes, 1980-

    2009-01-01

    Applications that combine live data streams with embedded, parallel, and distributed processing are becoming more commonplace. WaveScript is a domain-specific language that brings high-level, type-safe, garbage-collected ...

  2. Directional detection of dark matter streams

    E-Print Network [OSTI]

    Ciaran A. J. O'Hare; Anne M. Green

    2014-11-11

    Directional detection of WIMPs, in which the energies and directions of the recoiling nuclei are measured, currently presents the only prospect for probing the local velocity distribution of Galactic dark matter. We investigate the extent to which future directional detectors would be capable of probing dark matter substructure in the form of streams. We analyse the signal expected from a Sagittarius-like stream and also explore the full parameter space of stream speed, direction, dispersion and density. Using a combination of non-parametric directional statistics, a profile likelihood ratio test and Bayesian parameter inference we find that within acceptable exposure times (O(10) kg yr for cross sections just below the current exclusion limits) future directional detectors will be sensitive to a wide range of stream velocities and densities. We also examine and discuss the importance of the energy window of the detector.

  3. A dynamically reconfigurable data stream processing system

    SciTech Connect (OSTI)

    Nogiec, J.M.; Trombly-Freytag, K.; /Fermilab

    2004-11-01

    This paper describes a component-based framework for data stream processing that allows for configuration, tailoring, and runtime system reconfiguration. The system's architecture is based on a pipes and filters pattern, where data is passed through routes between components. A network of pipes and filters can be dynamically reconfigured in response to a preplanned sequence of processing steps, operator intervention, or a change in one or more data streams. This framework provides several mechanisms supporting dynamic reconfiguration and can be used to build static data stream processing applications such as monitoring or data acquisition systems, as well as self-adjusting systems that can adapt their processing algorithm, presentation layer, or data persistency layer in response to changes in input data streams.

  4. Online Spectral Clustering on Network Streams

    E-Print Network [OSTI]

    Jia, Yi

    2012-12-31

    Graph is an extremely useful representation of a wide variety of practical systems in data analysis. Recently, with the fast accumulation of stream data from various type of networks, significant research interests have arisen on spectral clustering...

  5. Optimizations in stream programming for multimedia applications

    E-Print Network [OSTI]

    Wong, Eric, M. Eng. Massachusetts Institute of Technology

    2012-01-01

    Multimedia applications are the most dominant workload in desktop and mobile computing. Such applications regularly process continuous sequences of data and can be naturally represented under the stream programming domain ...

  6. Improving the Software Upgrade Value Stream

    E-Print Network [OSTI]

    Ippolito, Brian

    This paper reports findings from a two-year study to identify Lean practices for deriving software requirements from aerospace system level requirements, with a goal towards improving the software upgrade value stream.

  7. Transcript of the movie "Bouncing of a Jet off a Newtonian Liquid Surface" 2007 Gallery of Fluid Motion, http://pof.aip.org/pof/gallery

    E-Print Network [OSTI]

    twice. The stream is perturbed by a plastic cable tie and the disturbance starts the jet bouncing. If the stream is perturbed again, it can bounce a second time. As the bath velocity is decreased, the jetTranscript of the movie "Bouncing of a Jet off a Newtonian Liquid Surface" 2007 Gallery of Fluid

  8. Micro-column plasma emission liquid chromatograph

    DOE Patents [OSTI]

    Gay, Don D. (Aiken, SC)

    1984-01-01

    In a direct current plasma emission spectrometer for use in combination with a micro-column liquid chromatograph, an improved plasma source unit. The plasma source unit includes a quartz capillary tube having an inlet means, outlet off gas means and a pair of spaced electrodes defining a plasma region in the tube. The inlet means is connected to and adapted to receive eluant of the liquid chromatograph along with a stream of plasma-forming gas. There is an opening through the wall of the capillary tube penetrating into the plasma region. A soft glass capillary light pipe is disposed at the opening, is connected to the spectrometer, and is adapted to transmit light passing from the plasma region to the spectrometer. There is also a source of electromotive force connected to the electrodes sufficient to initiate and sustain a plasma in the plasma region of the tube.

  9. Ultrasonic characterization of single drops of liquids

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM)

    1998-01-01

    Ultrasonic characterization of single drops of liquids. The present invention includes the use of two closely spaced transducers, or one transducer and a closely spaced reflector plate, to form an interferometer suitable for ultrasonic characterization of droplet-size and smaller samples without the need for a container. The droplet is held between the interferometer elements, whose distance apart may be adjusted, by surface tension. The surfaces of the interferometer elements may be readily cleansed by a stream of solvent followed by purified air when it is desired to change samples. A single drop of liquid is sufficient for high-quality measurement. Examples of samples which may be investigated using the apparatus and method of the present invention include biological specimens (tear drops; blood and other body fluid samples; samples from tumors, tissues, and organs; secretions from tissues and organs; snake and bee venom, etc.) for diagnostic evaluation, samples in forensic investigations, and detection of drugs in small quantities.

  10. Digital image processing of coal stream combustion 

    E-Print Network [OSTI]

    Gopalakrishnan, Chengappalli Periyasamy

    1994-01-01

    DIGITAL IMAGE PROCESSING OF COAL STREAM COMBUSTION A Thesis by CHENGAPPALLI PERIYASAMY GOPALAKRISHNAN Submitted to Texas A k M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style... and content by: a yan Annama at (Chair of Committee) en (Member) Norman C. Gris old (Member) George Peterson (Head of Department) May 1994 Major Subject: Mechanical Engineering ABSTRACT Digital Image Processing of Coal Stream Combustion. (May 1994...

  11. Side Stream Filtration for Cooling Towers

    SciTech Connect (OSTI)

    2012-10-20

    This technology evaluation assesses side stream filtration options for cooling towers, with an objective to assess key attributes that optimize energy and water savings along with providing information on specific technology and implementation options. This information can be used to assist Federal sites to determine which options may be most appropriate for their applications. This evaluation provides an overview of the characterization of side stream filtration technology, describes typical applications, and details specific types of filtration technology.

  12. Process for conversion of lignin to reformulated hydrocarbon gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    1999-09-28

    A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

  13. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. acep03rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation...

  14. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop

    Broader source: Energy.gov [DOE]

    The Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop was held March 18–19, 2015, hosted at the U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory's Washington D.C. offices.

  15. Subcontinuum mass transport of condensed hydrocarbons in nanoporous media

    E-Print Network [OSTI]

    Falk, Kerstin

    Although hydrocarbon production from unconventional reservoirs, the so-called shale gas, has exploded recently, reliable predictions of resource availability and extraction are missing because conventional tools fail to ...

  16. Vertimass licenses ORNL biofuel-to-hydrocarbon conversion technology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    McCorkle Communications and Media Relations 865.574.7308 Vertimass licenses ORNL biofuel-to-hydrocarbon conversion technology Vertimass LLC, a California-based start-up...

  17. Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis

    SciTech Connect (OSTI)

    Ekechukwu, A.A.

    2002-05-10

    Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

  18. Process for converting light alkanes to higher hydrocarbons

    DOE Patents [OSTI]

    Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA)

    1988-01-01

    A process is disclosed for the production of aromatic-rich, gasoline boiling range hydrocarbons from the lower alkanes, particularly from methane. The process is carried out in two stages. In the first, alkane is reacted with oxygen and hydrogen chloride over an oxyhydrochlorination catalyst such as copper chloride with minor proportions of potassium chloride and rare earth chloride. This produces an intermediate gaseous mixture containing water and chlorinated alkanes. The chlorinated alkanes are contacted with a crystalline aluminosilicate catalyst in the hydrogen or metal promoted form to produce gasoline range hydrocarbons with a high proportion of aromatics and a small percentage of light hydrocarbons (C.sub.2 -C.sub.4). The light hydrocarbons can be recycled for further processing over the oxyhydrochlorination catalyst.

  19. Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels

    E-Print Network [OSTI]

    Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

    2012-01-01

    Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

  20. The CNG process: Acid gas removal with liquid carbon dioxide

    SciTech Connect (OSTI)

    Liu, Y.C.; Auyang, L.; Brown, W.R.

    1987-01-01

    The CNG acid gas removal process has two unique features: the absorption of sulfur-containing compounds and other trace contaminants with liquid carbon dioxide, and the regeneration of pure liquid carbon dioxide by triple-point crystallization. The process is especially suitable for treating gases which contain large amounts of carbon dioxide and much smaller amounts (relative to carbon dioxide) of hydrogen sulfide. Capital and energy costs are lower than conventional solvent processes. Further, products of the CNG process meet stringent purity specifications without undue cost penalties. A process demonstration unit has been constructed and operated to demonstrate the two key steps of the CNG process. Hydrogen sulfide and carbonyl sulfide removal from gas streams with liquid carbon dioxide absorbent to sub-ppm concentrations has been demonstrated. The production of highly purified liquid carbon dioxide (less than 0.1 ppm total contaminant) by triple-point crystallization also has been demonstrated.

  1. Liquid level detector

    DOE Patents [OSTI]

    Grasso, A.P.

    1984-02-21

    A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  2. Liquid level detector

    DOE Patents [OSTI]

    Grasso, Albert P. (Vernon, CT)

    1986-01-01

    A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  3. Hydrocarbon-enhanced particulate filter regeneration via microwave ignition

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

    2010-02-02

    A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

  4. Petroleum hydrocarbon-degrading bacteria in the Galveston Bay system 

    E-Print Network [OSTI]

    Schropp, Steven James

    1979-01-01

    activities and shipping may all release petroleum hydrocarbons into the marine environment (83), which are potentially detrimental to the estuarine system. Estuaries have been found to be one of the most active types of water in terms of microbial... bacteria to oil inpiit might be used as an indicator or petroleuin pollution (6, 43, 44). To evaluate the effects of ) vllutant hydrocarbons ozi the bacterial populations of estuarine systems, information on the distribution and abundance...

  5. Process for removing metal carbonyls from gaseous streams

    SciTech Connect (OSTI)

    Heyd, R.L.; Pignet, T.P.

    1988-04-26

    A process for removing metal carbonyl contaminates from a gaseous stream is described containing such contaminates and which is free from sulfur contaminates, which process comprises contacting the gaseous stream with a zinc sulfide absorbent to thereby remove metal carbonyl contaminates from the gaseous stream, and separating the gaseous stream from the zinc sulfide absorbent.

  6. Mean stream coordinates structure of the Subantarctic Front: Temperature, salinity,

    E-Print Network [OSTI]

    Luther, Douglas S.

    . The cross-stream structure of along-stream velocity is very nearly symmetric about the jet axisMean stream coordinates structure of the Subantarctic Front: Temperature, salinity, and absolute southwest of Tasmania, at the Subantarctic Front (SAF), is estimated by a stream coordinates analysis

  7. Hierarchical Sampling from Sketches: Estimating Functions over Data Streams

    E-Print Network [OSTI]

    Ganguly, Sumit

    - timating frequency moments of data streams", Lakshminath Bhuvanagiri, Sumit Ganguly, Deepanjan Kesh

  8. Efficient Instance-Based Learning on Data Streams Jurgen Beringer

    E-Print Network [OSTI]

    Hüllermeier, Eyke

    Efficient Instance-Based Learning on Data Streams J¨urgen Beringer Department of Computer Science applicable to streams with different characteristics. Keywords: data streams, classification, instance-based the context of data streams and propose an efficient instance-based learning algorithm. The remainder

  9. Liquid Hydrogen Absorber for MICE

    E-Print Network [OSTI]

    Ishimoto, S.

    2010-01-01

    REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

  10. Bio-crude transcriptomics: Gene discovery and metabolic network reconstruction for the biosynthesis of the terpenome of the hydrocarbon oil-producing green alga, Botryococcus braunii race B (Showa)*

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Molnár, István; Lopez, David; Wisecaver, Jennifer H.; Devarenne, Timothy P.; Weiss, Taylor L.; Pellegrini, Matteo; Hackett, Jeremiah D.

    2012-10-30

    Microalgae hold promise for yielding a biofuel feedstock that is sustainable, carbon-neutral, distributed, and only minimally disruptive for the production of food and feed by traditional agriculture. Amongst oleaginous eukaryotic algae, the B race of Botryococcus braunii is unique in that it produces large amounts of liquid hydrocarbons of terpenoid origin. These are comparable to fossil crude oil, and are sequestered outside the cells in a communal extracellular polymeric matrix material. The biosynthetic engineering of terpenoid bio-crude production requires identification of genes and reconstruction of metabolic pathways responsible for production of both hydrocarbons and other metabolites of the alga thatmore »compete for photosynthetic carbon and energy.« less

  11. Bio-crude transcriptomics: Gene discovery and metabolic network reconstruction for the biosynthesis of the terpenome of the hydrocarbon oil-producing green alga, Botryococcus braunii race B (Showa)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Molnár, István [Univ. of Arizona, Tucson, AZ (United States). Natural Products Center and Bio5 Institute; Lopez, David [Univ. of California, Los Angeles, CA (United States). Dept. of Molecular, Cell and Developmental Biology; Wisecaver, Jennifer H. [Univ. of Arizona, Tucson, AZ (United States). Dept. of Ecology and Evolutionary Biology; Devarenne, Timothy P. [Texas A & M Univ., College Station, TX (United States). Dept. of Biochemistry and Biophysics; Weiss, Taylor L. [Texas A & M Univ., College Station, TX (United States). Dept. of Biochemistry and Biophysics; Pellegrini, Matteo [Univ. of California, Los Angeles, CA (United States). Dept. of Molecular, Cell and Developmental Biology; Hackett, Jeremiah D. [Univ. of Arizona, Tucson, AZ (United States). Bio5 Institute and Dept. of Ecology and Evolutionary Biology

    2012-01-01

    Microalgae hold promise for yielding a biofuel feedstock that is sustainable, carbon-neutral, distributed, and only minimally disruptive for the production of food and feed by traditional agriculture. Amongst oleaginous eukaryotic algae, the B race of Botryococcus braunii is unique in that it produces large amounts of liquid hydrocarbons of terpenoid origin. These are comparable to fossil crude oil, and are sequestered outside the cells in a communal extracellular polymeric matrix material. Biosynthetic engineering of terpenoid bio-crude production requires identification of genes and reconstruction of metabolic pathways responsible for production of both hydrocarbons and other metabolites of the alga that compete for photosynthetic carbon and energy.

  12. Integrated hydrocarbon reforming system and controls

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Dorson, Matthew H.; Mitchell, William L.; Nowicki, Brian J.; Thijssen, Johannes; Davis, Robert; Papile, Christopher; Rumsey, Jennifer W.; Longo, Nathan; Cross, III, James C.; Rizzo, Vincent; Kleeburg, Gunther; Rindone, Michael; Block, Stephen G.; Sun, Maria; Morriseau, Brian D.; Hagan, Mark R.; Bowers, Brian

    2003-11-04

    A hydrocarbon reformer system including a first reactor configured to generate hydrogen-rich reformate by carrying out at least one of a non-catalytic thermal partial oxidation, a catalytic partial oxidation, a steam reforming, and any combinations thereof, a second reactor in fluid communication with the first reactor to receive the hydrogen-rich reformate, and having a catalyst for promoting a water gas shift reaction in the hydrogen-rich reformate, and a heat exchanger having a first mass of two-phase water therein and configured to exchange heat between the two-phase water and the hydrogen-rich reformate in the second reactor, the heat exchanger being in fluid communication with the first reactor so as to supply steam to the first reactor as a reactant is disclosed. The disclosed reformer includes an auxiliary reactor configured to generate heated water/steam and being in fluid communication with the heat exchanger of the second reactor to supply the heated water/steam to the heat exchanger.

  13. Emission of polycyclic aromatic hydrocarbons in China

    SciTech Connect (OSTI)

    Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-02-01

    Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

  14. Ionic Liquids with Ammonium Cations as Lubricants or Additives

    SciTech Connect (OSTI)

    Qu, Jun; Blau, Peter Julian; Dai, Sheng; Luo, Huimin; Truhan, Jr., John J

    2006-01-01

    Friction and wear are estimated to cost 6% of the US gross national product, or around $700 billion annually. A new class of more effective lubricants could lead to huge energy savings. Limited recent literature has suggested potential for using room-temperature ionic liquids as lubricants, however only a few out of millions (or more) of species have been evaluated. Recent ORNL work discovered a new category of ionic liquids with ammonium cations that have demonstrated promising lubricating properties as net lubricants or lubricant additives, particularly in lubricating difficult-to-lubricate metals like aluminum. More than 30% friction reduction has been observed on ammonium-based ionic liquids compared to conventional hydrocarbon oils. The inherent polarity of ionic liquids is believed to provide strong adhesion to contact surfaces and form a boundary lubricating film leading to friction and wear reductions. Other advantages of ionic liquids include (1) negligible volatility, (2) high thermal stability, (3) non-flammability, and (4) better intrinsic properties that eliminate the necessity of many expensive lubricant additives. With very flexible molecular structures, this new class of lubricants, particularly ammonium-based ionic liquids, can be tailored to fit a big variety of applications including but not limited to bearings, combustion engines, MEMS, and metal forming.

  15. Improved liquid-film electron stripper

    DOE Patents [OSTI]

    Gavin, B.F.

    1984-11-01

    An improved liquid-film electron stripper particularly for high intensity heavy ion beams which produces constant regenerated, stable, free-standing liquid films having an adjustable thickness between 0.3 to 0.05 microns. The improved electron stripper is basically composed of at least one high speed, rotating disc with a very sharp, precision-like, ground edge on one side of the disc's periphery and with highly polished, flat, radial surface adjacent the sharp edge. A fine stream of liquid, such as oil, impinges at a 90/sup 0/ angle adjacent the disc's sharp outer edge. Film terminators, located at a selected distance from the disc perimeter are positioned approximately perpendicular to the film. The terminators support, shape, and stretch the film and are arranged to assist in the prevention of liquid droplet formation by directing the collected film to a reservoir below without breaking or interfering with the film. One embodiment utilizes two rotating discs and associated terminators, with the discs rotating so as to form films in opposite directions, and with the second disc being located down beam-line relative to the first disc.

  16. Theoretical Aspects of Liquid Crystals and Liquid Crystalline Polymers

    E-Print Network [OSTI]

    Feng, James J.

    Theoretical Aspects of Liquid Crystals and Liquid Crystalline Polymers James J. Feng Department theories and mole- cular theories separately. In addition, a theory for liquid crystalline materials has, Vancouver, British Columbia, Canada INTRODUCTION Liquid crystallinity refers to an intermediate state

  17. Conversion of olefins to liquid motor fuels

    DOE Patents [OSTI]

    Rabo, Jule A. (Armonk, NY); Coughlin, Peter K. (Yorktown Heights, NY)

    1988-01-01

    Linear and/or branched claim C.sub.2 to C.sub.12 olefins are converted to hydrocarbon mixtures suitable for use as liquid motor fuels by contact with a catalyst capable of ensuring the production of desirable products with only a relatively minor amount of heavy products boiling beyond the diesel oil range. The catalyst having desirable stability during continuous production operations, comprises a steam stabilized zeolite Y catalyst of hydrophobic character, desirably in aluminum-extracted form. The olefins such as propylene, may be diluted with inerts, such as paraffins or with water, the latter serving to moderate the acidity of the catalyst, or to further moderate the activity of the aluminum-extracted catalyst, so as to increase the effective life of the catalyst.

  18. WATER QUALITY EFFECTS OF ABOVE-STREAM FISH FEEDERS IN LOW-NUTRIENT NORTH CAROLINA MOUNTAIN STREAMS

    E-Print Network [OSTI]

    Buckel, Jeffrey A.

    WATER QUALITY EFFECTS OF ABOVE-STREAM FISH FEEDERS IN LOW- NUTRIENT NORTH CAROLINA MOUNTAIN STREAMS EFFECTS OF ABOVE-STREAM FISH FEEDERS IN LOW- NUTRIENT NORTH CAROLINA MOUNTAIN STREAMS James F. Gilliam and Thomas A. Cady Department of Zoology College of Agriculture and Life Sciences North Carolina State

  19. Solids precipitation and polymerization of asphaltenes in coal-derived liquids

    DOE Patents [OSTI]

    Kydd, Paul H. (Lawrenceville, NJ)

    1984-01-01

    The precipitation and removal of particulate solids from coal-derived liquids by adding a process-derived anti-solvent liquid fraction and continuing the precipitation process at a temperature above the melting point of the mixed liquids for sufficient time to allow the asphaltenes to polymerize and solids to settle at atmospheric pressure conditions. The resulting clarified light hydrocarbon overflow liquid contains less than about 0.02 W % ash and is suitable as turbine fuel or as boiler fuel for burning without particulate emission control equipment. An underflow liquid fraction containing less than about 0.1 W % solids along with low sulfur and nitrogen concentrations is suitable as a boiler fuel with emission control equipment.

  20. Energy Recovery By Direct Contact Gas-Liquid Heat Exchange 

    E-Print Network [OSTI]

    Fair, J. R.; Bravo, J. L.

    1988-01-01

    , would be those relatively few cases where heat has been recovered from pyrolysis furnace gases (in ethylene 78712 manufacture) via a quench liquid that provides intennedia level heat for process purposes. In the present paper we shall concentrate... pyrolysis furnace are cooled in oil- and water-quench towers, and higher-boiling oils are condensed from the gases. While not always used for heat recovery, the exit process water stream is hot enough for process heat exchange. For the examples shown...

  1. Interface for the rapid analysis of liquid samples by accelerator mass spectrometry

    DOE Patents [OSTI]

    Turteltaub, Kenneth; Ognibene, Ted; Thomas, Avi; Daley, Paul F; Salazar Quintero, Gary A; Bench, Graham

    2014-02-04

    An interface for the analysis of liquid sample having carbon content by an accelerator mass spectrometer including a wire, defects on the wire, a system for moving the wire, a droplet maker for producing droplets of the liquid sample and placing the droplets of the liquid sample on the wire in the defects, a system that converts the carbon content of the droplets of the liquid sample to carbon dioxide gas in a helium stream, and a gas-accepting ion source connected to the accelerator mass spectrometer that receives the carbon dioxide gas of the sample in a helium stream and introduces the carbon dioxide gas of the sample into the accelerator mass spectrometer.

  2. Indirect evaporative cooler using membrane-contained, liquid desiccant for dehumidification

    DOE Patents [OSTI]

    Kozubal, Eric Joseph; Slayzak, Steven Joseph

    2014-07-08

    An indirect evaporative cooler for cooling inlet supply air from a first temperature to a second, lower temperature using a stream of liquid coolant and a stream of exhaust or purge air. The cooler includes a first flow channel for inlet supply air and a second flow channel adjacent the first for exhaust air. The first and second flow channels are defined in part by sheets of a membrane permeable to water vapor such that mass is transferred as a vapor through the membrane from the inlet supply air to a contained liquid desiccant for dehumidification and also to the exhaust air as heat is transferred from the inlet supply air to the liquid coolant. A separation wall divides the liquid desiccant and the coolant but allows heat to be transferred from the supply air to the coolant which releases water vapor to the counter or cross flowing exhaust air.

  3. Capture and release of mixed acid gasses with binding organic liquids

    DOE Patents [OSTI]

    Heldebrant, David J. (Richland, WA); Yonker, Clement R. (Kennewick, WA)

    2010-09-21

    Reversible acid-gas binding organic liquid systems that permit separation and capture of one or more of several acid gases from a mixed gas stream, transport of the liquid, release of the acid gases from the ionic liquid and reuse of the liquid to bind more acid gas with significant energy savings compared to current aqueous systems. These systems utilize acid gas capture compounds made up of strong bases and weak acids that form salts when reacted with a selected acid gas, and which release these gases when a preselected triggering event occurs. The various new materials that make up this system can also be included in various other applications such as chemical sensors, chemical reactants, scrubbers, and separators that allow for the specific and separate removal of desired materials from a gas stream such as flue gas.

  4. Corrective Action Investigation Plan for Corrective Action Unit 543: Liquid Disposal Units, Nevada Test Site, Nevada: Revision 0

    SciTech Connect (OSTI)

    U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office

    2004-05-03

    The general purpose of this Corrective Action Investigation Plan is to ensure that adequate data are collected to provide sufficient and reliable information to identify, evaluate, and select technically viable corrective action alternatives (CAAs) for Corrective Action Unit (CAU) 543: Liquid Disposal Units, Nevada Test Site (NTS), Nevada. Located in Areas 6 and 15 on the NTS, CAU 543 is comprised of a total of seven corrective action sites (CASs), one in Area 6 and six in Area 15. The CAS in Area 6 consists of a Decontamination Facility and its components which are associated with decontamination of equipment, vehicles, and materials related to nuclear testing. The six CASs in Area 15 are located at the U.S. Environmental Protection Agency Farm and are related to waste disposal activities at the farm. Sources of possible contamination at Area 6 include potentially contaminated process waste effluent discharged through a process waste system, a sanitary waste stream generated within buildings of the Decon Facility, and radiologically contaminated materials stored within a portion of the facility yard. At Area 15, sources of potential contamination are associated with the dairy operations and the animal tests and experiments involving radionuclide uptake. Identified contaminants of potential concern include volatile organic compounds, semivolatile organic compounds, petroleum hydrocarbons, pesticides, herbicides, polychlorinated biphenyls, metals, and radionuclides. Three corrective action closure alternatives - No Further Action, Close in Place, or Clean Closure - will be recommended for CAU 543 based on an evaluation of all the data quality objective-related data. Field work will be conducted following approval of the plan. The results of the field investigation will support a defensible evaluation of CAAs that will be presented in the Corrective Action Decision Document.

  5. Cardiac toxicity of 5-ring polycyclic aromatic hydrocarbons is differentially dependent on the aryl hydrocarbon receptor 2 isoform during zebrafish development

    E-Print Network [OSTI]

    Cardiac toxicity of 5-ring polycyclic aromatic hydrocarbons is differentially dependent on the aryl hydrocarbon receptor 2 isoform during zebrafish development John P. Incardona , Tiffany L. Linbo, Nathaniel L aromatic hydrocarbons (PAHs), commonly occur as com- plex mixtures in the environment. Recent studies using

  6. IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater Revised and Updated. Part 7. C8H12C8H18 Hydrocarbons

    E-Print Network [OSTI]

    IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater Revised and Updated. Part 7. C8H12­C8H18 Hydrocarbons with Water Volume Editors David G. Shawa... University of Alaska on the evaluation of the all experimental data for a given homologous series of aliphatic and aromatic hydrocarbons

  7. Reforming Pyrolysis Aqueous Waste Streams to Process Hydrogen and Hydrocarbons Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7,DOERTI |Service ofConditioning1: Reforming Pyrolysis

  8. The Magellanic Stream: Circumnavigating the Galaxy

    E-Print Network [OSTI]

    D'Onghia, Elena

    2015-01-01

    The Magellanic Clouds are surrounded by an extended network of gaseous structures. Chief among these is the Magellanic Stream, an interwoven tail of filaments trailing the Clouds in their orbit around the Milky Way. When considered in tandem with its Leading Arm, the Stream stretches over 200 degrees on the sky. Thought to represent the result of tidal interactions between the Clouds and ram-pressure forces exerted by the Galactic corona, its kinematic properties reflect the dynamical history of the closest pair of dwarf galaxies to the Milky Way. The Stream is a benchmark for hydrodynamical simulations of accreting gas and cloud/corona interactions. If the Stream survives these interactions and arrives safely in the Galactic disk, its cargo of over a billion solar masses of gas has the potential to maintain or elevate the Galactic star formation rate. In this article, we review the current state of knowledge of the Stream, including its chemical composition, physical conditions, origin, and fate. We also rev...

  9. ORGANIC GEOCHEMICAL STUDIES. II. THE DISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA, AND IN A RECENT LAKE SEDIMENT: A PRELIMINARY REPORT

    E-Print Network [OSTI]

    Han, Jerry; McCarthy, E.D.; Van Hoeven Jr., William; Calvin, Melvin; Bradley, W. H.

    2008-01-01

    significantly to the hydrocarbons of higher molecular weightDISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA,T E DISTRIBUTION O ALIPHATIC HYDROCARBONS H F A PRELIMINARY

  10. Hydrocarbon Seeps of the Mesozoic Great Valley Group Forearc Strata and Franciscan Complex, Northern and Central California, U.S.A.

    E-Print Network [OSTI]

    Keenan, Kristin Euphrat

    2010-01-01

    and Cretaceous Gastropods from Hydrocarbon Seeps in ForearcPeregrinella-Dominated Hydrocarbon-Seep Deposit on the1999. Signatures of Hydrocarbon Venting in a Middle Devonian

  11. Long-range transport of particulate polycyclic aromatic hydrocarbons at Cape Hedo remote island site in the East China Sea between 2005 and 2008

    E-Print Network [OSTI]

    2008-01-01

    of polycyclic aromatic hydrocarbons (PAHs) for 2004. Atmos.of polynuclear aromatic hydrocarbons in ambient air throughpolycyclic aromatic hydrocarbons in urban air of Hong Kong.

  12. Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

    E-Print Network [OSTI]

    2010-01-01

    Bohrmann, G. , 2007. In situ hydrocarbon concentrations fromM. , Bohrmann, G. , 2003. Hydrocarbon gases in deposits fromMethane and other hydrocarbon gases in marine sediment.

  13. Spray process for the recovery of CO.sub.2 from a gas stream and a related apparatus

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev; Perry, Robert James; Wood, Benjamin Rue; Genovese, Sarah Elizabeth

    2014-02-11

    A method for recovering carbon dioxide (CO.sub.2) from a gas stream is disclosed. The method includes the step of reacting CO.sub.2 in the gas stream with fine droplets of a liquid absorbent, so as to form a solid material in which the CO.sub.2 is bound. The solid material is then transported to a desorption site, where it is heated, to release substantially pure CO.sub.2 gas. The CO.sub.2 gas can then be collected and used or transported in any desired way. A related apparatus for recovering carbon dioxide (CO.sub.2) from a gas stream is also described herein.

  14. An improved equation of state for molal volumes of liquid hydrocarbons at high temperatures and pressure 

    E-Print Network [OSTI]

    Latimer, James K

    1964-01-01

    for these reservoirs requires the use of a composltional material balance. This method takes Into ac- count the constantly changing compositions of the phases. In turn, a method calculating the phase and volumetric behavior of oil and gas phases in equilibrium... are correlation coeffic- ients for the pure materials. The effective values of the aC and the 7+ bC7+ are determined us ing the temperature, molecular weight&and the density of the heptanes-plus. The correlation presented by Alanl and Kennedy was the first...

  15. Effect of Temperature on Carbon-Black Agglomeration in Hydrocarbon Liquid with Adsorbed Dispersant

    E-Print Network [OSTI]

    . Introduction The effect of temperature on the stability of colloidal suspensions is important in many Suspensions of carbon black in oil, stabilized with adsorbed polyisobutylene succinimide (PIBSI) dispersant temperature has an effect on the stabilization of colloidal particles and, hence, an enormous impact on flow

  16. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, J.E.; Bolton, R.D.

    1999-03-02

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans. 4 figs.

  17. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, James E. (Los Alamos, NM); Bolton, Richard D. (Los Alamos, NM)

    1999-01-01

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans.

  18. Programmable stream prefetch with resource optimization

    DOE Patents [OSTI]

    Boyle, Peter; Christ, Norman; Gara, Alan; Mawhinney, Robert; Ohmacht, Martin; Sugavanam, Krishnan

    2013-01-08

    A stream prefetch engine performs data retrieval in a parallel computing system. The engine receives a load request from at least one processor. The engine evaluates whether a first memory address requested in the load request is present and valid in a table. The engine checks whether there exists valid data corresponding to the first memory address in an array if the first memory address is present and valid in the table. The engine increments a prefetching depth of a first stream that the first memory address belongs to and fetching a cache line associated with the first memory address from the at least one cache memory device if there is not yet valid data corresponding to the first memory address in the array. The engine determines whether prefetching of additional data is needed for the first stream within its prefetching depth. The engine prefetches the additional data if the prefetching is needed.

  19. On the genealogy of the Orphan Stream

    E-Print Network [OSTI]

    L. V. Sales; A. Helmi; E. Starkenburg; H. L. Morrison; E. Engle; P. Harding; M. Mateo; E. W. Olszewski; T. Sivarani

    2008-07-30

    We use N-body simulations to explore the origin and a plausible orbit for the Orphan Stream, one of the faintest substructures discovered so far in the outer halo of our Galaxy. We are able to reproduce its position, velocity and distance measurements by appealing to a single wrap of a double-component satellite galaxy. We find that the progenitor of the Orphan Stream could have been an object similar to today's Milky Way dwarfs, such as Carina, Draco, Leo II or Sculptor; and unlikely to be connected to Complex A or Ursa Major II. Our models suggest that such progenitors, if accreted on orbits with apocenters smaller than ~35 kpc, are likely to give rise to very low surface brightness streams, which may be hiding in the outer halo and remain largely undetected with current techniques. The systematic discovery of these ghostly substructures may well require wide field spectroscopic surveys of the Milky Way's outer stellar halo.

  20. On the genealogy of the Orphan Stream

    E-Print Network [OSTI]

    Sales, L V; Starkenburg, E; Morrison, H L; Engle, E; Harding, P; Mateo, M; Olszewski, E W; Sivarani, T

    2008-01-01

    We use N-body simulations to explore the origin and a plausible orbit for the Orphan Stream, one of the faintest substructures discovered so far in the outer halo of our Galaxy. We are able to reproduce its position, velocity and distance measurements by appealing to a single wrap of a double-component satellite galaxy. We find that the progenitor of the Orphan Stream could have been an object similar to today's Milky Way dwarfs, such as Carina, Draco, Leo II or Sculptor; and unlikely to be connected to Complex A or Ursa Major II. Our models suggest that such progenitors, if accreted on orbits with apocenters smaller than ~35 kpc, are likely to give rise to very low surface brightness streams, which may be hiding in the outer halo and remain largely undetected with current techniques. The systematic discovery of these ghostly substructures may well require wide field spectroscopic surveys of the Milky Way's outer stellar halo.

  1. Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (PHB) from a Process Relevant Lignocellulosic Derived Sugar (Poster)

    SciTech Connect (OSTI)

    Wang, W.; Mittal, A.; Mohagheghi, A.; Johnson, D. K.

    2014-04-01

    PHAs are synthesized by many microorganisms to serve as intracellular carbon storage molecules. In some bacterial strains, PHB can account for up to 80% of cell mass. In addition to its application in the packaging sector, PHB also has great potential as an intermediate in the production of hydrocarbon fuels. PHB can be thermally depolymerized and decarboxylated to propene which can be upgraded to hydrocarbon fuels via commercial oligomerization technologies. Cupriavidus necator is the microorganism that has been most extensively studied and used for PHB production on an industrial scale; However the substrates used for producing PHB are mainly fructose, glucose, sucrose, fatty acids, glycerol, etc., which are expensive. In this study, we demonstrate production of PHB from a process relevant lignocellulosic derived sugar stream, i.e., saccharified slurry from pretreated corn stover. The strain was first investigated in shake flasks for its ability to utilize glucose, xylose and acetate. In addition, the strain was also grown on pretreated lignocellulose hydrolyzate slurry and evaluated in terms of cell growth, sugar utilization, PHB accumulation, etc. The mechanism of inhibition in the toxic hydrolysate generated by the pretreatment and saccharification process of biomass, was also studied.

  2. Catalysts for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Rabo, Jule A. (Armonk, NY); Coughlin, Peter K. (Yorktown Heights, NY)

    1987-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst composition capable of ensuring the production of only relatively minor amounts of heavy products boiling beyond the diesel oil range. The catalyst composition, having desirable stability during continuous production operation, employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component. The latter component is a steam-stabilized zeolite Y catalyst of hydrophobic character, desirably in acid-extracted form.

  3. Liquid Metal Transformers

    E-Print Network [OSTI]

    Sheng, Lei; Liu, Jing

    2014-01-01

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

  4. Methane-derived hydrocarbons produced under upper-mantle conditions

    SciTech Connect (OSTI)

    Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.

    2009-08-13

    There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

  5. Method and apparatus for cutting, abrading, and drilling with sublimable particles and vaporous liquids

    DOE Patents [OSTI]

    Bingham, D.N.; Swainston, R.C.; Palmer, G.L.

    1998-03-31

    A gas delivery system provides a first gas which is in a liquid state under extreme pressure and in a gaseous state under intermediate pressure. A particle delivery system provides a slurry comprising the first gas in a liquid state and a second gas in a solid state. The second gas is selected so that it will solidify at a temperature at or above the temperature of the first gas in a liquid state. A nozzle assembly connected to the gas delivery system and to the particle delivery system produces a stream having a high velocity central jet comprising the slurry, a liquid sheath surrounding the central jet comprising the first gas in a liquid state and an outer jacket surrounding the liquid sheath comprising the first gas in a gas state. 19 figs.

  6. Method and apparatus for cutting, abrading, and drilling with sublimable particles and vaporous liquids

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Swainston, Richard C. (Shelley, ID); Palmer, Gary L. (Shelley, ID)

    1998-01-01

    A gas delivery system provides a first gas which is in a liquid state under extreme pressure and in a gaseous state under intermediate pressure. A particle delivery system provides a slurry comprising the first gas in a liquid state and a second gas in a solid state. The second gas is selected so that it will solidify at a temperature at or above the temperature of the first gas in a liquid state. A nozzle assembly connected to the gas delivery system and to the particle delivery system produces a stream having a high velocity central jet comprising the slurry, a liquid sheath surrounding the central jet comprising the first gas in a liquid state and an outer jacket surrounding the liquid sheath comprising the first gas in a gas state.

  7. Proceedings of ICAD 04-Tenth Meeting of the International Conference on Auditory Display, Sydney, Australia, July 6-9, 2004 PHYSICALLY-BASED MODELS FOR LIQUID SOUNDS

    E-Print Network [OSTI]

    van den Doel, Kees

    liquid sounds such as produced by streams, pouring water, rivers, rain, and breaking waves is based be synthesized in this manner. 1. INTRODUCTION Figure 1: A photograph of a water drop falling in water. Photo courtesy of Andrew Davidhazy. The sounds made by liquids, especially those of water, are prevalent in our

  8. THE UNUSUAL HYDROCARBON EMISSION FROM THE EARLY CARBON STAR HD 100764: THE CONNECTION BETWEEN AROMATICS AND ALIPHATICS

    E-Print Network [OSTI]

    Sloan, Gregory C.

    THE UNUSUAL HYDROCARBON EMISSION FROM THE EARLY CARBON STAR HD 100764: THE CONNECTION BETWEEN disk. The spectrum shows emission features from polycyclic aro- matic hydrocarbons (PAHs shifts are consistent with hydrocarbon mixtures containing both aromatic and aliphatic bonds. We propose

  9. Quantitative Changes in Hydrocarbons over Time in Fecal Pellets of Incisitermes minor May Predict Whether Colonies Are Alive or Dead

    E-Print Network [OSTI]

    Lewis, Vernard R.; Nelson, Lori J.; Haverty, Michael I.; Baldwin, James A.

    2010-01-01

    termite species by the hydrocarbons in their feces. J. Chem.effects on the cuticular hydrocarbons of the host-specificG. J. 1990. Cuticular hydrocarbons of eight species of North

  10. Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2000-09-26

    A method is disclosed for synthesizing hydrogen gas from hydrocarbon fuel. A first mixture of steam and a first fuel is directed into a first tube 208 to subject the first mixture to a first steam reforming reaction in the presence of a first catalyst 214. A stream of oxygen-containing gas is pre-heated by transferring heat energy from product gases. A second mixture of the pre-heated oxygen-containing gas and a second fuel is directed into a second tube 218 disposed about the first tube 208 to subject the second mixture to a partial oxidation reaction and to provide heat energy for transfer to the first tube 208. A first reaction reformate from the first tube 208 and a second reaction reformate from the second tube 218 are directed into a third tube 224 disposed about the second tube 218 to subject the first and second reaction reformates to a second steam reforming reaction, wherein heat energy is transferred to the third tube 224 from the second tube 218.

  11. Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels

    SciTech Connect (OSTI)

    Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

    2013-01-01

    Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

  12. Nutrient-stimulated biodegradation of aged refinery hydrocarbons in soil

    SciTech Connect (OSTI)

    Drake, E.N.; Stokley, K.E.; Calcavecchio, P.; Bare, R.E.; Rothenburger, S.J.; Prince, R.C. [Exxon Research and Engineering, Annandale, NJ (United States); Douglas, G.S. [Arthur D. Little, Inc., Cambridge, MA (United States)

    1995-12-31

    Aged hydrocarbon-contaminated refinery soil was amended with water and nutrients and tilled weekly for 1 year to stimulate biodegradation. Gas chromatography/mass spectrometry (GC/MS) analysis of polycyclic aromatic compounds (PAHs) and triterpane biomarkers, and Freon IR analysis of total petroleum hydrocarbons (TPH), were used to determine the extent of biodegradation. There was significant degradation of extractable hydrocarbon (up to 60%), but neither hopane, oleanane, nor the amount of polars decreased during this period of bioremediation, allowing them to be used as conserved internal markers for estimating biodegradation. Significant degradation of the more alkylated two- and three-ring compounds, and of the four-ring species pyrene and chrysene and their alkylated congeners, was seen. Substantial degradation (> 40%) of benzo(b)fluoranthene, benzo(k)fluoranthene, and benzo(a)pyrene also was seen. The results show that bioremediation can be a useful treatment in the cleanup of contaminated refinery sites.

  13. Process for light-driven hydrocarbon oxidation at ambient temperatures

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM)

    1990-01-01

    A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

  14. Hydrocarbon anions in interstellar clouds and circumstellar envelopes

    E-Print Network [OSTI]

    T. J. Millar; C. Walsh; M. A. Cordiner; R. Ní Chuimín; Eric Herbst

    2007-05-07

    The recent detection of the hydrocarbon anion C6H- in the interstellar medium has led us to investigate the synthesis of hydrocarbon anions in a variety of interstellar and circumstellar environments. We find that the anion/neutral abundance ratio can be quite large, on the order of at least a few percent, once the neutral has more than five carbon atoms. Detailed modeling shows that the column densities of C6H- observed in IRC+10216 and TMC-1 can be reproduced. Our calculations also predict that other hydrocarbon anions, such as C4H- and C8H-, are viable candidates for detection in IRC+10216, TMC-1 and photon-dominated regions such as the Horsehead Nebula.

  15. Semantic Web Research anno 2006: main streams,

    E-Print Network [OSTI]

    van Harmelen, Frank

    Semantic Web Research anno 2006: main streams, popular fallacies, current status and future. In this topical1 paper we try to give an analysis and overview of the current state of Semantic Web research. We point to different in- terpretations of the Semantic Web as the reason underlying many contro- versies

  16. Region Streams: Functional Macroprogramming for Sensor Networks

    E-Print Network [OSTI]

    of computational power, communication bandwidth, and energy de- mand new approaches to programming that shield the developer from low-level details of resource management, concurrency, and in-network pro- cessing. We argue. The essential data model in Regiment is based on region streams, which represent spatially distributed, time

  17. Finding Hierarchical Heavy Hitters in Data Streams

    E-Print Network [OSTI]

    Cormode, Graham

    . The problem we study in this paper is that of finding Hierarchical Heavy Hitters (HHH): given a hierarchy and a fraction , we want to find all HHH nodes that have a total num- ber of descendants in the data stream that are HHH nodes. The resulting summary gives a topological "cartogram" of the hierarchical data. We present

  18. A primeval Magellanic Stream and others

    SciTech Connect (OSTI)

    Peebles, P. J. E. [Joseph Henry Laboratories, Princeton University, Princeton, NJ 08544 (United States); Tully, R. Brent [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States)

    2013-12-01

    The Magellanic Stream (MS) might have grown out of tidal interactions at high redshift, when the young galaxies were close together, rather than from later interactions among the Magellanic Clouds and Milky Way (MW). This is illustrated in solutions for the orbits of Local Group (LG) galaxies under the cosmological condition of growing peculiar velocities at high redshift. Massless test particles initially near and moving with the Large Magellanic Cloud in these solutions end up with distributions in angular position and redshift similar to the MS, though with the usual overly prominent leading component that the MW corona might have suppressed. Another possible example of the effect of conditions at high redshift is a model primeval stream around the LG galaxy NGC 6822. Depending on the solution for LG dynamics, this primeval stream can end up with a position angle similar to the H I around this galaxy and a redshift gradient in the observed direction. The gradient is much smaller than observed but might have been increased by dissipative contraction. Presented also is an even more speculative illustration of the possible effect of initial conditions, primeval stellar streams around M31.

  19. HYBRID COSMOLOGICAL SIMULATIONS WITH STREAM VELOCITIES

    SciTech Connect (OSTI)

    Richardson, Mark L. A.; Scannapieco, Evan [School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85287 (United States); Thacker, Robert J. [Department of Astronomy and Physics, Saint Mary's University, Halifax, B3H 3C3 (Canada)

    2013-07-10

    In the early universe, substantial relative ''stream'' velocities between the gas and dark matter arise due to radiation pressure and persist after recombination. To assess the impact of these velocities on high-redshift structure formation, we carry out a suite of high-resolution adaptive mesh refinement (AMR) cosmological simulations, which use smoothed particle hydrodynamic data sets as initial conditions, converted using a new tool developed for this work. These simulations resolve structures with masses as small as a few 100 M{sub Sun }, and we focus on the 10{sup 6} M{sub Sun} ''mini-halos'' in which the first stars formed. At z Almost-Equal-To 17, the presence of stream velocities has only a minor effect on the number density of halos below 10{sup 6} M{sub Sun }, but it greatly suppresses gas accretion onto all halos and the dark matter structures around them. Stream velocities lead to significantly lower halo gas fractions, especially for Almost-Equal-To 10{sup 5} M{sub Sun} objects, an effect that is likely to depend on the orientation of a halo's accretion lanes. This reduction in gas density leads to colder, more compact radial profiles, and it substantially delays the redshift of collapse of the largest halos, leading to delayed star formation and possibly delayed reionization. These many differences suggest that future simulations of early cosmological structure formation should include stream velocities to properly predict gas evolution, star formation, and the epoch of reionization.

  20. Disc valve for sampling erosive process streams

    DOE Patents [OSTI]

    Mrochek, J.E.; Dinsmore, S.R.; Chandler, E.W.

    1984-08-16

    This is a patent for a disc-type, four-port sampling valve for service with erosive high temperature process streams. Inserts and liners of ..cap alpha..-silicon carbide respectively, in the faceplates and in the sampling cavities, limit erosion while providing lubricity for a smooth and precise operation. 1 fig.