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Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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1

Cation Geothermometers | Open Energy Information  

Open Energy Info (EERE)

Cation Geothermometers Cation Geothermometers Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Cation Geothermometers Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Liquid Geothermometry Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Used to estimate reservoir temperatures. Dictionary.png Cation Geothermometers: No definition has been provided for this term. Add a Definition Introduction Some experts have stated that the factor that changes the risk assessment of a geothermal prospect the fastest is obtaining attractive chemical confirmation (geothermometry, gas analyses) that a thermal resource exists

2

Geothermometry At Akutan Fumaroles Area (Kolker, Et Al., 2010) | Open  

Open Energy Info (EERE)

Akutan Fumaroles Area (Kolker, Et Al., 2010) Akutan Fumaroles Area (Kolker, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Akutan Fumaroles Area (Kolker, Et Al., 2010) Exploration Activity Details Location Akutan Fumaroles Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes The chemistry of the hot springs strongly suggests the existence of a neutral chloride reservoir with economically developable temperature. The fluid geothermometry tells a consistent story, with cation geothermometry detecting a >210degrees C reservoir temperature, probably near the fumarole, and silica geothermometry and presence of sinter suggesting that 160 to 180degrees C exists close to hot spring B. References

3

Isotope Geothermometry | Open Energy Information  

Open Energy Info (EERE)

Isotope Geothermometry Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Isotope Geothermometry Details Activities (0) Areas (0) Regions (0)...

4

Category:Geothermometry | Open Energy Information  

Open Energy Info (EERE)

following 2 subcategories, out of 2 total. G Gas Geothermometry 1 pages I Isotope Geothermometry 1 pages Pages in category "Geothermometry" The following 4 pages...

5

Definition: Geothermometry | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Geothermometry Jump to: navigation, search Dictionary.png Geothermometry Chemical geothermometers are used to estimate reservoir temperatures for most of the systems. The geothermometers are based on temperature- dependent, water-rock reactions which control the chemical and isotopic composition of the thermal water. This method is applicable only to hot-water systems because the common chemical constituents of thermal water (SiO2, Na, K, Ca, Mg, Cl, HCO3, and CO3) are soluble in liquid water but lack significant solubility in steam.[1] View on Wikipedia Wikipedia Definition Geothermobarometry is the science of measuring the previous pressure and temperature history of a metamorphic or intrusive igneous rocks.

6

Geothermometry | Open Energy Information  

Open Energy Info (EERE)

Geothermometry Geothermometry Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Geothermometry Details Activities (65) Areas (48) Regions (5) NEPA(0) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geochemical Data Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: used to estimate reservoir temperatures Cost Information Low-End Estimate (USD): 30.003,000 centUSD 0.03 kUSD 3.0e-5 MUSD 3.0e-8 TUSD / sample Median Estimate (USD): 30.003,000 centUSD 0.03 kUSD 3.0e-5 MUSD 3.0e-8 TUSD / sample High-End Estimate (USD): 30.003,000 centUSD 0.03 kUSD 3.0e-5 MUSD 3.0e-8 TUSD / sample Dictionary.png Geothermometry:

7

Geothermometry At Lassen Volcanic National Park Area (Janik & Mclaren,  

Open Energy Info (EERE)

Geothermometry At Lassen Volcanic National Park Area (Janik & Mclaren, Geothermometry At Lassen Volcanic National Park Area (Janik & Mclaren, 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Lassen Volcanic National Park Area (Janik & Mclaren, 2010) Exploration Activity Details Location Lassen Volcanic National Park Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Analyses of eight well samples taken consecutively during the flow test showed an inverse correlation between NH3 and Cl_ concentrations. The last sample taken had a pH of 8.35 and contained 2100 ppm Cl_ and 0.55 ppm NH3. Ratios of Na+/K+ and Na+/Cl_ remained nearly constant throughout the flow test. Cation geothermometers (with inherent uncertainties of at least

8

Category:Gas Geothermometry | Open Energy Information  

Open Energy Info (EERE)

navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Gas Geothermometry page? For detailed information on Gas Geothermometry as exploration...

9

Gas Geothermometry | Open Energy Information  

Open Energy Info (EERE)

Gas Geothermometry Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group:...

10

Geothermometry At Columbus Salt Marsh Area (Shevenell, Et Al., 2008) | Open  

Open Energy Info (EERE)

Geothermometry At Columbus Salt Marsh Area (Shevenell, Et Al., 2008) Geothermometry At Columbus Salt Marsh Area (Shevenell, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Columbus Salt Marsh Area (Shevenell, Et Al., 2008) Exploration Activity Details Location Columbus Salt Marsh Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Borate crusts that were partially mined during the 1800s were identified and mapped at Rhodes, Teels, and Columbus Marshes (playas), all in western Nevada (Figure 1). Subsequent field verification and chemical analyses of well, spring and groundwater samples indicated the presence of hidden subsurface geothermal reservoirs. Cation and quartz geothermometry indicate subsurface reservoir temperatures between 118°C and 162°C at all three

11

Geothermometry At Coso Geothermal Area (1980) | Open Energy Information  

Open Energy Info (EERE)

Geothermometry At Coso Geothermal Area (1980) Geothermometry At Coso Geothermal Area (1980) Exploration Activity Details Location Coso Geothermal Area Exploration Technique Geothermometry Activity Date 1980 Usefulness useful DOE-funding Unknown Exploration Basis Fluid temperature of feed water Notes Cation and sulfate isotope geothermometers indicate that the reservoir feeding water to the Coso Hot Spring well has a temperature of about 240 -250 C, and the reservoir feeding the CGEH well has a temperature of about 205 C. The variation in the chemical composition of water from the two wells suggests a model in which water-rock chemical equilibrium is maintained as a convecting solution cools from about 245-205 C by conductive heat loss. References Fournier, R.O.; Thompson, J.M.; Austin, C.F. (10 May 1980)

12

Multicomponent Equilibrium Models for Testing Geothermometry Approaches  

SciTech Connect (OSTI)

Geothermometry is an important tool for estimating deep reservoir temperature from the geochemical composition of shallower and cooler waters. The underlying assumption of geothermometry is that the waters collected from shallow wells and seeps maintain a chemical signature that reflects equilibrium in the deeper reservoir. Many of the geothermometers used in practice are based on correlation between water temperatures and composition or using thermodynamic calculations based a subset (typically silica, cations or cation ratios) of the dissolved constituents. An alternative approach is to use complete water compositions and equilibrium geochemical modeling to calculate the degree of disequilibrium (saturation index) for large number of potential reservoir minerals as a function of temperature. We have constructed several forward geochemical models using The Geochemists Workbench to simulate the change in chemical composition of reservoir fluids as they migrate toward the surface. These models explicitly account for the formation (mass and composition) of a steam phase and equilibrium partitioning of volatile components (e.g., CO2, H2S, and H2) into the steam as a result of pressure decreases associated with upward fluid migration from depth. We use the synthetic data generated from these simulations to determine the advantages and limitations of various geothermometry and optimization approaches for estimating the likely conditions (e.g., temperature, pCO2) to which the water was exposed in the deep subsurface. We demonstrate the magnitude of errors that can result from boiling, loss of volatiles, and analytical error from sampling and instrumental analysis. The estimated reservoir temperatures for these scenarios are also compared to conventional geothermometers. These results can help improve estimation of geothermal resource temperature during exploration and early development.

Cooper, D. Craig; Carl D. Palmer; Robert W. Smith; Travis L. McLing

2013-02-01T23:59:59.000Z

13

Radiation Stability of Cations in Ionic Liquids. 2. Charge Delocalization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stability of Cations in Ionic Liquids. 2. Improved Radiation Stability of Cations in Ionic Liquids. 2. Improved Radiation Resistance Through Charge Delocalization in 1-Benzylpyridinium Ilya A. Shkrob, Timothy W. Marin, Jasmine L. Hatcher, Andrew R. Cook, Tomasz Szreder and James F. Wishart J. Phys. Chem. B 117, Just Accepted (2013). [Find paper at ACS Publications]. Abstract: Hydrophobic room-temperature ionic liquids (ILs) hold promise as replacements for molecular diluents for processing of used nuclear fuel as well as for the development of alternative separations processes, provided that the solvent can be made resistant to ionizing radiation. We demonstrate that 1-benzylpyridinium cations are uniquely suited as radiation resistant cations due to the occurrence of charge delocalization both in their reduced and oxidized form in the ILs. It is suggested that

14

Geothermometry At Rhodes Marsh Area (Shevenell, Et Al., 2008) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Rhodes Marsh Area (Shevenell, Et Geothermometry At Rhodes Marsh Area (Shevenell, Et Al., 2008) Exploration Activity Details Location Rhodes Marsh Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Borate crusts that were partially mined during the 1800s were identified and mapped at Rhodes, Teels, and Columbus Marshes (playas), all in western Nevada (Figure 1). Subsequent field verification and chemical analyses of well, spring and groundwater samples indicated the presence of hidden subsurface geothermal reservoirs. Cation and quartz geothermometry indicate subsurface reservoir temperatures between 118°C and 162°C at all three areas based on results from waters sampled proximal to borate crusts. References Lisa Shevenell, Mark Coolbaugh, Chris Sladek, Rick Zehner, Chris

15

Geothermometry At Nevada Test And Training Range Area (Sabin...  

Open Energy Info (EERE)

Geothermometry At Nevada Test And Training Range Area (Sabin, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At...

16

Geothermometry At Blackfoot Reservoir Area (Hutsinpiller & Parry...  

Open Energy Info (EERE)

Activity Date Usefulness useful DOE-funding Unknown References Amy Hutsinpiller, W. T. Parry (1985) Geochemistry And Geothermometry Of Spring Water From The Blackfoot...

17

Colorado thermal spring water geothermometry (public dataset...  

Open Energy Info (EERE)

dataset) Jump to: navigation, search OpenEI Reference LibraryAdd to library General: Colorado thermal spring water geothermometry (public dataset) Abstract The zipped Excel file...

18

Category:Isotope Geothermometry | Open Energy Information  

Open Energy Info (EERE)

Login | Sign Up Search Category Edit History Facebook icon Twitter icon Category:Isotope Geothermometry Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

19

Geothermometry At Teels Marsh Area (Shevenell, Et Al., 2008) | Open Energy  

Open Energy Info (EERE)

Shevenell, Et Al., 2008) Shevenell, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Teels Marsh Area (Shevenell, Et Al., 2008) Exploration Activity Details Location Teels Marsh Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Borate crusts that were partially mined during the 1800s were identified and mapped at Rhodes, Teels, and Columbus Marshes (playas), all in western Nevada (Figure 1). Subsequent field verification and chemical analyses of well, spring and groundwater samples indicated the presence of hidden subsurface geothermal reservoirs. Cation and quartz geothermometry indicate subsurface reservoir temperatures between 118°C and 162°C at all three areas based on results from waters sampled proximal to borate crusts.

20

Geothermometry At Honokowai Area (Thomas, 1986) | Open Energy Information  

Open Energy Info (EERE)

Geothermometry At Honokowai Area (Thomas, 1986) Geothermometry At Honokowai Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Honokowai Area (Thomas, 1986) Exploration Activity Details Location Honokowai Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Temperature and groundwater chemistry analyses were performed on three wells along the alluvial fan above Honokowai. Water temperatures were approximately 20degrees C and normal basal aquifer water chemistry was observed (Table 4). References Donald M. Thomas (1 January 1986) Geothermal Resources Assessment In Hawaii Retrieved from "http://en.openei.org/w/index.php?title=Geothermometry_At_Honokowai_Area_(Thomas,_1986)&oldid=387033"

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Geothermometry At Fish Lake Valley Area (DOE GTP) | Open Energy...  

Open Energy Info (EERE)

Fish Lake Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Fish Lake Valley Area (DOE GTP) Exploration...

22

Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al., 2008...  

Open Energy Info (EERE)

Alkali Flat Area (Kratt, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al.,...

23

Geothermometry At Teels Marsh Area (Coolbaugh, Et Al., 2006)...  

Open Energy Info (EERE)

Coolbaugh, Et Al., 2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Teels Marsh Area (Coolbaugh, Et Al., 2006) Exploration...

24

Geothermometry At Rhodes Marsh Area (Coolbaugh, Et Al., 2006...  

Open Energy Info (EERE)

Coolbaugh, Et Al., 2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Rhodes Marsh Area (Coolbaugh, Et Al., 2006)...

25

Geothermometry At Fort Bliss Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

Fort Bliss Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Fort Bliss Area (DOE GTP) Exploration Activity...

26

Geothermometry At Coso Geothermal Area (1978) | Open Energy Information  

Open Energy Info (EERE)

Geothermometry At Coso Geothermal Area (1978) Geothermometry At Coso Geothermal Area (1978) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Coso Geothermal Area (1978) Exploration Activity Details Location Coso Geothermal Area Exploration Technique Geothermometry Activity Date 1978 Usefulness useful DOE-funding Unknown Exploration Basis Determine fluid origin in two exploratory wells Notes Collected water from original coso hot springs well (1967) and CGEH No. 1. and completed chemical analysis to determine fluid origin. The surface expression of fumarole and acid sulfate pools and shallow steam wells gives a false indication of an extensive vapor dominated system because upward convecting, boiling alkaline-chloride waters do not reach the surface.

27

Geothermometry At Haleakala Volcano Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Haleakala Volcano Area (Thomas, 1986) Geothermometry At Haleakala Volcano Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Haleakala Volcano Area (Thomas, 1986) Exploration Activity Details Location Haleakala Volcano Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes The field survey program on the northwest rift zone consisted of soil mercury and radon emanometry surveys, groundwater temperature and chemistry studies, Schlumberger resistivity soundings and self-potential profiles. Geophysical and geochemical surveys along this rift (southwest) were limited by difficult field conditions and access limitations. The geophysical program consisted of one Schlumberger sounding, one

28

Geothermometry At Socorro Mountain Area (Armstrong, Et Al., 1995) | Open  

Open Energy Info (EERE)

Geothermometry At Socorro Mountain Area (Armstrong, Et Al., 1995) Geothermometry At Socorro Mountain Area (Armstrong, Et Al., 1995) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Socorro Mountain Area (Armstrong, Et Al., 1995) Exploration Activity Details Location Socorro Mountain Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Corresponding Socorro caldera Carboniferous rocks were studied in the field in 1988-1992-Renault later completed geochemistry and silica-crystallite geothermometry, Armstrong petrographic analysis and cathodoluminescence, Oscarson SEM studies, and John Repetski (USGS, Reston, Virgina) conodont stratigraphy and color and textural alteration as guides to the carbonate rocks' thermal history. The carbonate-rock classification used in this

29

Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De  

Open Energy Info (EERE)

Region (Shevenell & De Region (Shevenell & De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De Rocher, 2005) Exploration Activity Details Location Central Nevada Seismic Zone Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown References Lisa Shevenell, Ted De Rocher (2005) Evaluation Of Chemical Geothermometers For Calculating Reservoir Temperatures At Nevada Geothermal Power Plants Retrieved from "http://en.openei.org/w/index.php?title=Geothermometry_At_Central_Nevada_Seismic_Zone_Region_(Shevenell_%26_De_Rocher,_2005)&oldid=401374" Category: Exploration Activities What links here

30

Geothermometry At Kawaihae Area (Thomas, 1986) | Open Energy Information  

Open Energy Info (EERE)

Geothermometry At Kawaihae Area (Thomas, 1986) Geothermometry At Kawaihae Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Kawaihae Area (Thomas, 1986) Exploration Activity Details Location Kawaihae Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Groundwater chemical data are limited due to the small number of wells near Kawaihae; however, the data that are available strongly substantiate the presence of a thermal resource. A measured water temperature of 31 degrees C in one well is clearly above normal ambient temperatures, and the chloride/magnesium ion ratio in the same well is elevated substantially above the normal range (Table 8). Both of these data provide strong evidence that at least a low-level thermal anomaly is present in the area.

31

Geothermometry At Mauna Loa Northeast Rift Area (Thomas, 1986) | Open  

Open Energy Info (EERE)

Geothermometry At Mauna Loa Northeast Rift Area (Thomas, 1986) Geothermometry At Mauna Loa Northeast Rift Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Mauna Loa Northeast Rift Area (Thomas, 1986) Exploration Activity Details Location Mauna Loa Northeast Rift Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes A reexamination of all groundwater sources in the Keaau area was undertaken in an effort to confirm the chemical and temperature anomalies that formed the primary basis on which the Keaau area was identified during the preliminary assessment survey. The data generated by this survey (Table 9) determined that all of the anomalous data present in the earlier data base were spurious and that the groundwater chemistry and temperatures in this

32

Geothermometry At Lualualei Valley Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Lualualei Valley Area (Thomas, 1986) Geothermometry At Lualualei Valley Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Lualualei Valley Area (Thomas, 1986) Exploration Activity Details Location Lualualei Valley Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Yhe extensive set of groundwater chemical data compiled for the wells in the valley (Table 1) showed that two of the primary indicators that have been commonly used in Hawaii for identifying geothermal potential (i.e. silica concentration and chloride to magnesium ion ratios) were anomalous in the groundwater of this survey area (Cox and Thomas, 1979). Several wells located on the caldera boundaries were found to have both

33

Radiation induced redox reactions and fragmentation of constituent ions in ionic liquids II. Imidazolium cations.  

SciTech Connect (OSTI)

In part 1 of this study, radiolytic degradation of constituent anions in ionic liquids (ILs) was examined. The present study continues the themes addressed in part 1 and examines the radiation chemistry of 1,3-dialkyl substituted imidazolium cations, which currently comprise the most practically important and versatile class of ionic liquid cations. For comparison, we also examined 1,3-dimethoxy- and 2-methyl-substituted imidazolium and 1-butyl-4-methylpyridinium cations. In addition to identification of radicals using electron paramagnetic resonance spectroscopy (EPR) and selective deuterium substitution, we analyzed stable radiolytic products using {sup 1}H and {sup 13}C nuclear magnetic resonance (NMR) and tandem electrospray ionization mass spectrometry (ESMS). Our EPR studies reveal rich chemistry initiated through 'ionization of the ions': oxidation and the formation of radical dications in the aliphatic arms of the parent cations (leading to deprotonation and the formation of alkyl radicals in these arms) and reduction of the parent cation, yielding 2-imidazolyl radicals. The subsequent reactions of these radicals depend on the nature of the IL. If the cation is 2-substituted, the resulting 2-imidazolyl radical is relatively stable. If there is no substitution at C(2), the radical then either is protonated or reacts with the parent cation forming a C(2)-C(2) {sigma}{sigma}*-bound dimer radical cation. In addition to these reactions, when methoxy or C{sub {alpha}}-substituted alkyl groups occupy the N(1,3) positions, their elimination is observed. The elimination of methyl groups from N(1,3) was not observed. Product analyses of imidazolium liquids irradiated in the very-high-dose regime (6.7 MGy) reveal several detrimental processes, including volatilization, acidification, and oligomerization. The latter yields a polymer with m/z of 650 {+-} 300 whose radiolytic yield increases with dose (0.23 monomer units per 100 eV for 1-methyl-3-butylimidazolium trifluorosulfonate). Gradual generation of this polymer accounts for the steady increase in the viscosity of the ILs upon irradiation. Previous studies at lower dose have missed this species due to its wide mass distribution (stretching out to m/z 1600) and broad NMR lines, which make it harder to detect at lower concentrations. Among other observed changes is the formation of water immiscible fractions in hydrophilic ILs and water miscible fractions in hydrophobic ILs. The latter is due to anion fragmentation. The import of these observations for use of ILs as extraction solvents in nuclear cycle separations is discussed.

Shkrob, I. A.; Marin, T. W.; Chemerisov, S. D.; Hatcher, J.; Wishart, J. (Chemical Sciences and Engineering Division); (BNL)

2011-04-14T23:59:59.000Z

34

Geochemistry And Geothermometry Of Spring Water From The Blackfoot  

Open Energy Info (EERE)

Geothermometry Of Spring Water From The Blackfoot Geothermometry Of Spring Water From The Blackfoot Reservoir Region, Southeastern Idaho Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Geochemistry And Geothermometry Of Spring Water From The Blackfoot Reservoir Region, Southeastern Idaho Details Activities (3) Areas (1) Regions (0) Abstract: The Blackfoot Reservoir region in southeastern Idaho is recognized as a potential geothermal area because of the presence of several young rhyolite domes (50,000 years old), Quaternary basalt flows, and warm springs. North- to northwest-trending high-angle normal faults of Tertiary to Holocene age appear to be the dominant structural control of spring activity. Surface spring-water temperatures average 14°C except for a group of springs west of the Reservoir Mountains which average 33°C.

35

Geothermometry At Raft River Geothermal Area (1980) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Raft River Geothermal Area (1980) Geothermometry At Raft River Geothermal Area (1980) Exploration Activity Details Location Raft River Geothermal Area Exploration Technique Geothermometry Activity Date 1980 Usefulness not indicated DOE-funding Unknown Notes Geothermometer temperatures of shallow samples suggest significant re-equilibration at temperatures below those found in the deep wells. Silica geothermometer temperatures of water samples from the deep wells are in reasonable agreement with measured temperatures, whereas Na-K-Ca temperatures are significantly higher than measured temperatures. The chemical characteristics of the water, as indicated by chloride concentration, are extremely variable in shallow and deep samples. Chloride concentrations of the deep samples range from 580 to 2200 mg/kg.

36

Geothermometry At Lahaina-Kaanapali Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

Lahaina-Kaanapali Area (Thomas, 1986) Lahaina-Kaanapali Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Lahaina-Kaanapali Area (Thomas, 1986) Exploration Activity Details Location Lahaina-Kaanapali Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Groundwater temperature and chemistry surveys were similarly unable to identify any detectable thermal influence on the basal groundwaters. Silica concentrations and water temperatures (Table 4) were within the normal range expected for basal groundwaters receiving a limited amount of irrigation return water; chloride/magnesium ratios ranged downward from normal seawater values. References Donald M. Thomas (1 January 1986) Geothermal Resources Assessment In

37

Geothermometry At Long Valley Caldera Area (Sorey, Et Al., 1991) | Open  

Open Energy Info (EERE)

Long Valley Caldera Area (Sorey, Et Long Valley Caldera Area (Sorey, Et Al., 1991) Exploration Activity Details Location Long Valley Caldera Area Exploration Technique Geothermometry Activity Date Usefulness could be useful with more improvements DOE-funding Unknown Notes Silica-geothermometer temperature estimates for the Casa Diablo and RDO-8 well samples ( 196-202 degrees C) are lower than the corresponding cation-geothermometer temperature estimates, indicating loss of silica with declining reservoir temperature or dilution with low-silica waters. At shallow depths in the caldera References Michael L. Sorey, Gene A. Suemnicht, Neil C. Sturchio, Gregg A. Nordquist (1991) New Evidence On The Hydrothermal System In Long Valley Caldera, California, From Wells, Fluid Sampling, Electrical Geophysics, And

38

Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators  

Broader source: Energy.gov [DOE]

Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators presentation at the April 2013 peer review meeting held in Denver, Colorado.

39

Geothermometry At Hot Springs Ranch Area (Szybinski, 2006) | Open Energy  

Open Energy Info (EERE)

Hot Springs Ranch Area (Szybinski, 2006) Hot Springs Ranch Area (Szybinski, 2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Hot Springs Ranch Area (Szybinski, 2006) Exploration Activity Details Location Hot Springs Ranch Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes The brine from the drill holes, hot springs, seepages, and irrigation wells was sampled, as well as water from two nearby creeks, (total of 13 samples) and sent for analysis to Thermochem Inc. For sample locations refer to Figure 35; the geochemical data are presented in Appendix C. Geochemical results indicate the presence of two distinct waters in this group of samples (Tom Powell of Thermochem Inc., personal communication, 2005).

40

Geothermometry At Buffalo Valley Hot Springs Area (Laney, 2005) | Open  

Open Energy Info (EERE)

Buffalo Valley Hot Springs Area (Laney, 2005) Buffalo Valley Hot Springs Area (Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Buffalo Valley Hot Springs Area (Laney, 2005) Exploration Activity Details Location Buffalo Valley Hot Springs Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical Sampling of Thermal and Non-thermal Waters in Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which the analyses are incomplete, poor, or nonexistent. With these data, geothermometers are being calculated and a preliminary assessment of the geothermal potential and ranking of the sampled areas is being

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Geothermometry At Socorro Mountain Area (Owens, Et Al., 2005) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Socorro Mountain Area (Owens, Et Al., 2005) Geothermometry At Socorro Mountain Area (Owens, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Socorro Mountain Area (Owens, Et Al., 2005) Exploration Activity Details Location Socorro Mountain Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Pre-existing evidence includes heat gradients of upwards of 490mW/m2 from thermal-gradient wells, tepid spring waters (32oC) and silica geochemistry indicating thermal waters with a minimum of 82oC at depth References Lara Owens, Richard Baars, David Norman, Harold Tobin (2005) New Methods In Exploration At The Socorro Peak Kgra- A Gred Iii Project Retrieved from "http://en.openei.org/w/index.php?title=Geothermometry_At_Socorro_Mountain_Area_(Owens,_Et_Al.,_2005)&oldid=389518

42

Geothermometry At Walker-Lane Transitional Zone Region (Shevenell & De  

Open Energy Info (EERE)

Shevenell & De Shevenell & De Rocher, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Walker-Lane Transitional Zone Region (Shevenell & De Rocher, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown References Lisa Shevenell, Ted De Rocher (2005) Evaluation Of Chemical Geothermometers For Calculating Reservoir Temperatures At Nevada Geothermal Power Plants Retrieved from "http://en.openei.org/w/index.php?title=Geothermometry_At_Walker-Lane_Transitional_Zone_Region_(Shevenell_%26_De_Rocher,_2005)&oldid=399607" Category: Exploration Activities What links here Related changes

43

Geothermometry At Salt Wells Area (Henkle, Et Al., 2005) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Salt Wells Area (Henkle, Et Al., 2005) Geothermometry At Salt Wells Area (Henkle, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Salt Wells Area (Henkle, Et Al., 2005) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Geothermometry Activity Date 2004 - 2005 Usefulness useful DOE-funding Unknown Exploration Basis Adsorbed mercury soil geochemical surveys and radiometric geophysical surveys were carried out in conjunction with geologic mapping to test the application of these ground-based techniques to geothermal exploration at three prospects in Nevada by Henkle Jr. et al. in 2005. Mercury soil vapor surveys were not widely used in geothermal exploration in the western US at the time, although the association of mercury vapors with geothermal

44

Geothermometry At Upper Hot Creek Ranch Area (Benoit & Blackwell, 2006) |  

Open Energy Info (EERE)

Geothermometry At Upper Hot Creek Ranch Area (Benoit & Blackwell, 2006) Geothermometry At Upper Hot Creek Ranch Area (Benoit & Blackwell, 2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Upper Hot Creek Ranch Area (Benoit & Blackwell, 2006) Exploration Activity Details Location Upper Hot Creek Ranch Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Ten water samples were collected for chemical analysis and interpretation. Analyses of three samples of the UHCR thermal give predicted subsurface temperatures ranging from 317 to 334 oF from the Na-K-Ca, silica (quartz), and Na-Li geothermometers. The fact that all three thermometers closely agree gives the predictions added credibility. References Dick Benoit, David Blackwell (2006) Exploration Of The Upper Hot

45

Geothermometry At Northern Basin & Range Region (Laney, 2005) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Northern Basin & Range Region (Laney, 2005) Geothermometry At Northern Basin & Range Region (Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Northern Basin & Range Region (Laney, 2005) Exploration Activity Details Location Northern Basin and Range Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical Sampling of Thermal and Non-thermal Waters in Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which the analyses are incomplete, poor, or nonexistent. With these data, geothermometers are being calculated and a preliminary assessment of

46

Geothermometry At U.S. Midwest Region (Vugrinovich, 1987) | Open Energy  

Open Energy Info (EERE)

Geothermometry At U.S. Midwest Region (Vugrinovich, 1987) Geothermometry At U.S. Midwest Region (Vugrinovich, 1987) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At U.S. Midwest Region (Vugrinovich, 1987) Exploration Activity Details Location U.S. Midwest Region Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Michigan "The silica heat flow estimator does provide estimates of surface heat flow which appear to be in good agreement with conventional estimates, but which are not entirely free from disturbances caused by groundwater movements. The technique should be more widely applied to areas where conventional heat flow measurements are lacking." References Raymond Vugrinovich (1987) Regional Heat Flow Variations In The

47

Geothermometry At Reese River Area (Henkle & Ronne, 2008) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Reese River Area (Henkle & Ronne, 2008) Geothermometry At Reese River Area (Henkle & Ronne, 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Reese River Area (Henkle & Ronne, 2008) Exploration Activity Details Location Reese River Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Four formation water samples were collected from well 56-4, during an airlift test which took place between November 11 and November 14, 2007. One sample was taken from the Steiner Well which was the source for drilling water for the drilling of 56-4 and for the short injection test. The samples were analyzed by Thermochem for chemical constituents and by Rafter Lab at GNS for isotope analysis. References

48

Geothermometry At Fish Lake Valley Area (Deymonaz, Et Al., 2008) | Open  

Open Energy Info (EERE)

Geothermometry At Fish Lake Valley Area (Deymonaz, Et Al., 2008) Geothermometry At Fish Lake Valley Area (Deymonaz, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Fish Lake Valley Area (Deymonaz, Et Al., 2008) Exploration Activity Details Location Fish Lake Valley Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes There are no thermal springs within the Emigrant prospect area, but unambiguously indigenous hotwater samples were collected from boreholes 211 (see above) and 112 (Fig. 3). These samples were analyzed for major and selected minor chemical components (Table 1; Pilkington, 1984). Hot water at 96degrees C from borehole 211 was collected by airlifting from a depth of 123 m (water level) at a rate of 240 liters per minute. The

49

Geothermometry At Central Nevada Seismic Zone Region (Laney, 2005) | Open  

Open Energy Info (EERE)

Region Region (Laney, 2005) Exploration Activity Details Location Central Nevada Seismic Zone Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical Sampling of Thermal and Non-thermal Waters in Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which the analyses are incomplete, poor, or nonexistent. With these data, geothermometers are being calculated and a preliminary assessment of the geothermal potential and ranking of the sampled areas is being conducted using the new geochemical data. Objectives changed slightly in 2004. Samples are now being collected at sites identified by other

50

Selectivity Control in Synergistic Liquid-Liquid Anion Exchange of Univalent Anions via Structure-Specific Cooperativity between Quaternary Ammonium Cations and Anion Receptors  

SciTech Connect (OSTI)

Two anion receptors enhance liquid-liquid anion exchange when added to quaternary alkylammonium chloride anion exchangers, but with a striking dependence upon the structure of the alkylammonium cation. Two anion receptors were investigated, meso-octamethylcalix[4]pyrrole (C4P) and the bisthiourea tweezer 1,1'-(propane-1,3-diyl)bis(3-(4-sec-butylphenyl)thiourea (BTU). C4P has the unique ability in its cone anion-binding conformation to accept an appropriately sized electropositive species in the resulting cup formed by its four electron-rich pyrrole groups, while BTU is not expected to be predisposed for a specific host-guest interaction with the quaternary ammonium cations. It was therefore hypothesized that synergism between C4P and methyltri(C8,10)alkylammonium chloride (Aliquat 336) would be uniquely pronounced owing to insertion of the methyl group of the Aliquat cation into the C4P cup, and we present herein data supporting this expectation. While synergism is comparatively weak for both exchangers with the BTU receptor, synergism between C4P and Aliquat 336 is indeed so strong that anion exchange prefers chloride over more extractable nitrate and trifluoroacetate, effectively overcoming the ubiquitous Hofmeister bias. A thermochemical analysis of synergistic anion exchange has been provided for the first time, unraveling the observed selectivity behavior and resulting in the estimation of binding constants for C4P with the ion pairs of A336+ with Cl , Br , OAcF3 , NO3 , and I . The uniquely strong positive cooperativity between A336 and C4P underscores the advantage of a supramolecular approach in the design of synergistic anion exchange systems.

Borman, Christopher J [ORNL; Bonnesen, Peter V [ORNL; Moyer, Bruce A [ORNL

2012-01-01T23:59:59.000Z

51

Investigation of gamma induced degradation of Amberlite 200 cation resin by mass spectrometer and liquid chromatograph  

E-Print Network [OSTI]

, provisions were made for collecting samples of any gas produced. The irradiated resin was exposed to total 7 8 8 accumulations of 1. 0129X10 , 1. 0215XIO , and 5. 0168X10 Rads in three separate runs. It should be noted that the same amount of demineral.... (December 1977) Albert Antonio Freitag, B. S. , Texas A&M University Chairman of Advisory Committee: Dr. James 8. Smathers Amberlite 200 cation exchange resin was irradiated by gamma 7 8 radiation to doses of 10 to 5X10 Rads. Results of the analysis...

Freitag, Albert Antonio

1977-01-01T23:59:59.000Z

52

Geothermometry At Salt Wells Area (Edmiston & Benoit, 1984) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Salt Wells Area (Edmiston & Benoit, Geothermometry At Salt Wells Area (Edmiston & Benoit, 1984) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Geothermometry Activity Date 1980 - 1984 Usefulness useful DOE-funding Unknown Exploration Basis The blind Salt Wells geothermal system was first identified when Anadarko Petroleum Corporation drilled slim hole and geothermal exploration wells at the site in 1980. Two reports detail the results of this drilling activity. This paper seeks to (1) describe several moderate-temperature (150-200°C) geothermal systems discovered and drilled during the early 1980's that had not been documented previously in the literature, (2) summarize and compare chemical and temperature data from known moderate- to high-temperature (>200°C) in the region, and (3) to comment on the

53

Geothermometry At Salt Wells Area (Coolbaugh, Et Al., 2006) | Open Energy  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » Geothermometry At Salt Wells Area (Coolbaugh, Et Al., 2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Salt Wells Area (Coolbaugh, Et Al., 2006) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Geothermometry Activity Date 2005 - 2005 Usefulness useful DOE-funding Unknown Exploration Basis Geochemical water sampling, mineral distribution mapping, and shallow (30 cm) temperature probe measurements were conducted to expand on a previous field mapping study of surface geothermal features at Salt Wells, in order

54

Geothermometry At Nw Basin & Range Region (Laney, 2005) | Open Energy  

Open Energy Info (EERE)

Geothermometry At Nw Basin & Range Region (Laney, Geothermometry At Nw Basin & Range Region (Laney, 2005) Exploration Activity Details Location Northwest Basin and Range Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical Sampling of Thermal and Non-thermal Waters in Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which the analyses are incomplete, poor, or nonexistent. With these data, geothermometers are being calculated and a preliminary assessment of the geothermal potential and ranking of the sampled areas is being conducted using the new geochemical data. Objectives changed slightly in 2004. Samples are now being collected at sites identified by other

55

Geothermometry At Nevada Test And Training Range Area (Sabin, Et Al., 2004)  

Open Energy Info (EERE)

2004) 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Nevada Test And Training Range Area (Sabin, Et Al., 2004) Exploration Activity Details Location Nevada Test And Training Range Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Groundwater data are limited to a portion of NAFR; data are more plentiful beyond the range boundaries. Geothermometry yields calculated groundwater temperatures generally ranging from 30 to 105degrees C, with a rough correlation between the SiO2-chalcedony and the Na-K-Na (Mg-corrected) geothermometers. References A. E. Sabin, J. D. Walker, J. Unruh, F. C. Monastero (2004) Toward The Development Of Occurrence Models For Geothermal Resources In The

56

Geothermometry At Lassen Volcanic National Park Area (Janik ...  

Open Energy Info (EERE)

but are within the 220-240 degrees C range calculated using cation, sulfate-water isotope, and mixing model geothermometers (Muffler et al., 1982). References (Unknown)...

57

Isotopic mass-dependence of metal cation diffusion coefficients in liquid water  

SciTech Connect (OSTI)

Isotope distributions in natural systems can be highly sensitive to the mass (m) dependence of solute diffusion coefficients (D) in liquid water. Isotope geochemistry studies routinely have assumed that this mass dependence either is negligible (as predicted by hydrodynamic theories) or follows a kinetic-theory-like inverse square root relationship (D {proportional_to} m{sup -0.5}). However, our recent experimental results and molecular dynamics (MD) simulations showed that the mass dependence of D is intermediate between hydrodynamic and kinetic theory predictions (D {proportional_to} m{sup -{beta}} with 0 {<=} {beta} < 0.2 for Li{sup +}, Cl{sup -}, Mg{sup 2+}, and the noble gases). In this paper, we present new MD simulations and experimental results for Na{sup +}, K{sup +}, Cs{sup +}, and Ca{sup 2+} that confirm the generality of the inverse power-law relation D {proportional_to} m{sup -{beta}}. Our new findings allow us to develop a general description of the influence of solute valence and radius on the mass dependence of D for monatomic solutes in liquid water. This mass dependence decreases with solute radius and with the magnitude of solute valence. Molecular-scale analysis of our MD simulation results reveals that these trends derive from the exponent {beta} being smallest for those solutes whose motions are most strongly coupled to solvent hydrodynamic modes.

Bourg, I.C.; Richter, F.M.; Christensen, J.N.; Sposito, G.

2009-01-11T23:59:59.000Z

58

Properties of some ionic liquids based on 1-methyl-3-octylimidazolium and 4-methyl-N-butylpyridinium cations.  

E-Print Network [OSTI]

Ionic liquids as green solvents: progress and prospects.ionic liquids are green solvents, i.e. , environmentally

Papaiconomou, Nicolas; Yakelis, Neal; Salminen, Justin; Bergman, Robert; Prausnitz, John M.

2005-01-01T23:59:59.000Z

59

Geothermometry At Walker-Lane Transitional Zone Region (Laney, 2005) | Open  

Open Energy Info (EERE)

Laney, 2005) Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Walker-Lane Transitional Zone Region (Laney, 2005) Exploration Activity Details Location Walker-Lane Transition Zone Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Geochemical Sampling of Thermal and Non-thermal Waters in Nevada, Shevenell and Garside. The objective of this project is to obtain geochemical data from springs (and some wells) for which data are not publicly available, or for which the analyses are incomplete, poor, or nonexistent. With these data, geothermometers are being calculated and a preliminary assessment of the geothermal potential and ranking of the sampled areas is being

60

Geothermometry At Northern Basin & Range Region (Cole, 1983) | Open Energy  

Open Energy Info (EERE)

Northern Basin & Range Region Northern Basin & Range Region (Cole, 1983) Exploration Activity Details Location Northern Basin and Range Geothermal Region Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Wstern Utah hot springs: Antelope, Fish (Deadman), Fish (Wilson), Twin Peak, Cudahy, Laverkin, Grantsville, Crystal Prison, Arrowhead, Red Hill, Monroe, Joseph, Castilla, Saratoga, Thermo, Crater, Wasatch, Beck, Deseret, Big Spring, Blue Warm, Crystal Madsen, Udy, Cutler, Garland, Utah, Ogden, Hooper, Newcastle Area References David R. Cole (1983) Chemical And Isotopic Investigation Of Warm Springs Associated With Normal Faults In Utah Retrieved from "http://en.openei.org/w/index.php?title=Geothermometry_At_Northern_Basin_%26_Range_Region_(Cole,_1983)&oldid=4014

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Geothermometry At Clear Lake Area (Thompson, Et Al., 1992) | Open Energy  

Open Energy Info (EERE)

Clear Lake Area (Thompson, Et Al., 1992) Clear Lake Area (Thompson, Et Al., 1992) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Clear Lake Area (Thompson, Et Al., 1992) Exploration Activity Details Location Clear Lake Area Exploration Technique Geothermometry Activity Date Usefulness useful DOE-funding Unknown Notes Based on the above discussion, we favor a model in which thermal water rises somewhere between Howard and Seigler Springs. At Howard Springs we see evidence for the most representative deep thermal water because the C1 is elevated (highest measured C1 concentrations occur at Howard Springs). Moreover, the Na-Li, Na-K and Na-K-Ca geothermometers suggest temperatures greater than 240 degrees C. References J. M. Thompson, R. H. Mariner, L. D. White, T. S. Presser, W. C.

62

Geothermometry At Desert Queen Area (Garchar & Arehart, 2008) | Open Energy  

Open Energy Info (EERE)

Queen Area (Garchar & Arehart, 2008) Queen Area (Garchar & Arehart, 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Desert Queen Area (Garchar & Arehart, 2008) Exploration Activity Details Location Desert Queen Area Exploration Technique Geothermometry Activity Date Usefulness not indicated DOE-funding Unknown Notes Temperatures of the reservoir at depth are estimated to be between 92-141 degrees C and were calculated using the δ18O(SO4-H2O) geothermometer. It is unclear whether these temperatures reflect waters from the outflow zone of the Desert Peak geothermal system, or waters from a different reservoir at Desert Queen. Quartz, chalcedony, amorphous silica, Na-K-Ca, and δ18O(SO4-H2O) geothermometer calculations were performed.

63

An experimental investigation into the effects of fluid composition on certain geothermometry methods  

E-Print Network [OSTI]

at the lower temperatures, and 5) thermal waters do not mix with shallower, cooler ground water. Silica geothermometer The dissolved silica content of geothermal water is used in geothermometry because silica is present in most geologic settings... This presents a real problem in evaluation of the geo- thermal potential of the area; one method gives reservoir temperatures high enough for potential geothermal energy use but another gives temperatures that are too low. The waters studied by Henry can...

Pope, Leslie Anne

2012-06-07T23:59:59.000Z

64

Actinide cation-cation complexes  

SciTech Connect (OSTI)

The +5 oxidation state of U, Np, Pu, and Am is a linear dioxo cation (AnO{sub 2}{sup +}) with a formal charge of +1. These cations form complexes with a variety of other cations, including actinide cations. Other oxidation states of actinides do not form these cation-cation complexes with any cation other than AnO{sub 2}{sup +}; therefore, cation-cation complexes indicate something unique about AnO{sub 2}{sup +} cations compared to actinide cations in general. The first cation-cation complex, NpO{sub 2}{sup +}{center_dot}UO{sub 2}{sup 2+}, was reported by Sullivan, Hindman, and Zielen in 1961. Of the four actinides that form AnO{sub 2}{sup +} species, the cation-cation complexes of NpO{sub 2}{sup +} have been studied most extensively while the other actinides have not. The only PuO{sub 2}{sup +} cation-cation complexes that have been studied are with Fe{sup 3+} and Cr{sup 3+} and neither one has had its equilibrium constant measured. Actinides have small molar absorptivities and cation-cation complexes have small equilibrium constants; therefore, to overcome these obstacles a sensitive technique is required. Spectroscopic techniques are used most often to study cation-cation complexes. Laser-Induced Photacoustic Spectroscopy equilibrium constants for the complexes NpO{sub 2}{sup +}{center_dot}UO{sub 2}{sup 2+}, NpO{sub 2}{sup +}{center_dot}Th{sup 4+}, PuO{sub 2}{sup +}{center_dot}UO{sub 2}{sup 2+}, and PuO{sub 2}{sup +}{center_dot}Th{sup 4+} at an ionic strength of 6 M using LIPAS are 2.4 {plus_minus} 0.2, 1.8 {plus_minus} 0.9, 2.2 {plus_minus} 1.5, and {approx}0.8 M{sup {minus}1}.

Stoyer, N.J. [Lawrence Berkeley Lab., CA (United States); Seaborg, G.T. [Lawrence Livermore National Lab., CA (United States)

1994-12-01T23:59:59.000Z

65

Optimized multicomponent vs. classical geothermometry: Insights from modeling studies at the Dixie Valley geothermal area  

Science Journals Connector (OSTI)

Abstract A new geothermometry approach is explored, incorporating multicomponent geothermometry coupled with numerical optimization to provide more confident estimates of geothermal reservoir temperatures when results of classical geothermometers are inconsistent. This approach is applied to geothermal well and spring waters from the Dixie Valley geothermal area (Nevada), to evaluate the influence of salt brines mixing and dilution of geothermal fluids on calculated temperatures. The main advantage of the optimized multicomponent method over classical geothermometers is its ability to quantify the extent of dilution and gas loss experienced by a geothermal fluid, and to optimize other poorly constrained or unknown parameters (such as Al and Mg concentrations), allowing the reconstruction of the deep reservoir fluid composition and therefore gaining confidence in reservoir temperatures estimations. Because the chemical evolution of deep geothermal fluids is a combination of multiple time-dependent processes that take place when these fluids ascend to the surface, reactive transport modeling is used to assess constraints on the application of solute geothermometers. Simulation results reveal that Al and Mg concentrations of ascending fluids are sensitive to mineral precipitationdissolution affecting reservoir temperatures inferred with multicomponent geothermometry. In contrast, simulations show that the concentrations of major elements such as Na, K, and SiO2 are less sensitive to re-equilibration. Geothermometers based on these elements give reasonable reservoir temperatures in many cases, except when dilution or mixing with saline waters has taken place. Optimized multicomponent geothermometry yields more representative temperatures for such cases. Taking into account differences in estimated temperatures, and chemical compositions of the Dixie Valley thermal waters, a conceptual model of two main geothermal reservoirs is proposed. The first reservoir is located along the Stillwater range normal fault system and has an estimated temperature of 240260C. It covers the area corresponding to the geothermal field but could extend towards the south-west where deep temperatures of 200225C are estimated. The second reservoir has an estimated temperature of 175190C and extends from well 62-21 to northeastern Hyder, Lower Ranch, Fault Line, and Jersey springs.

L. Peiffer; C. Wanner; N. Spycher; E.L. Sonnenthal; B.M. Kennedy; J. Iovenitti

2014-01-01T23:59:59.000Z

66

Pysico-chemical properties of hydrophobic ionic liquids containing 1-octylpyridinium, 1-octyl-2-methylpyridinium or 1-octyl-4-methylpyridinium cations  

E-Print Network [OSTI]

Ionic liquids as green solvents: progress and prospects,in ionic liquid solvents. Green Chem. 2004, 6, 245-249. Xu,solvent structural variations on the mechanism of facilitated ion transfer into room-temperature ionic liquids. Green

Papaiconomou, Nicolas; Salminen, Justin; Lee, Jong-Min; Prausnitz, John M.

2006-01-01T23:59:59.000Z

67

Geochemical Techniques | Open Energy Information  

Open Energy Info (EERE)

Geochemical Techniques Geochemical Techniques Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Geochemical Techniques Details Activities (0) Areas (0) Regions (0) NEPA(1) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group: None Parent Exploration Technique: Exploration Techniques Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Dictionary.png Geochemical Techniques: No definition has been provided for this term. Add a Definition Related Techniques Geochemical Techniques Geochemical Data Analysis Geothermometry Gas Geothermometry Isotope Geothermometry Liquid Geothermometry Cation Geothermometers Multicomponent Geothermometers Silica Geothermometers Thermal Ion Dispersion

68

Increased Radical Cation Yields: Arenes in DCE  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Increased Yields of Radical Cations by Arene Addition to Irradiated Increased Yields of Radical Cations by Arene Addition to Irradiated 1,2-Dichloroethane Alison M. Funston and John R. Miller Radiat. Phys. Chem., 72, 601-611 (2005). [Find paper at Elsevier Science Direct] Abstract: Pulse radiolysis in chlorinated hydrocarbon liquids such as 1,2-dichloroethane is a versatile and effective method for the generation of solute radical cations. The addition of a large concentration of toluene or benzene to solutions of 1,2-dichloroethane is found to increase the yield of solute radical cations (G = 0.68 molecules/100 eV in 1,2-dichloroethane (Wang et al., 1979) by a factor of 2.5. The increased yield is found for solutes which have a potential of ~ 1.1 V (vs SCE) or below for the S+·/S couple and is due to reaction of the chlorine

69

Method for the chromatographic separation of cations from aqueous samples  

DOE Patents [OSTI]

An extraction chromatographic material is described for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support. 7 figs.

Horwitz, E.P.; Chiarizia, R.; Dietz, M.L.

1997-07-29T23:59:59.000Z

70

Method for the chromatographic separation of cations from aqueous samples  

DOE Patents [OSTI]

An extraction chromatographic material is described for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methane-diphosphonic acid on an inert particulate support. 7 figs.

Horwitz, E.P.; Chiarizia, R.; Dietz, M.L.

1998-12-22T23:59:59.000Z

71

EMSL - cation migration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cation-migration en Diffusional Motion of Redox Centers in Carbonate Electrolytes . http:www.emsl.pnl.govemslwebpublicationsdiffusional-motion-redox-centers-carbonate-electrol...

72

Cation Uptake and Allocation by Red Pine Seedlings under Cation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Uptake and Allocation by Red Pine Seedlings under Cation-Nutrient Stress in a Column Growth Experiment. Cation Uptake and Allocation by Red Pine Seedlings under Cation-Nutrient...

73

Plant rhamnogalacturonan II complexation of heavy metal cations  

DOE Patents [OSTI]

The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations.

O'Neill, Malcolm A. (Winterville, GA); Pellerin, Patrice J. M. (Montpellier, FR); Warrenfeltz, Dennis (Athens, GA); Vidal, Stephane (Combaillaux, FR); Darvill, Alan G. (Athens, GA); Albersheim, Peter (Athens, GA)

1999-01-01T23:59:59.000Z

74

Plant rhamnogalacturonan II complexation of heavy metal cations  

DOE Patents [OSTI]

The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations. 15 figs.

O`Neill, M.A.; Pellerin, P.J.M.; Warrenfeltz, D.; Vidal, S.; Darvill, A.G.; Albersheim, P.

1999-03-02T23:59:59.000Z

75

Physical Properties of Ionic Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Physical Properties of Ionic Liquids Consisting of the Physical Properties of Ionic Liquids Consisting of the 1-Butyl-3-Methylimidazolium Cation with Various Anions and the Bis(trifluoromethylsulfonyl)imide Anion with Various Cations Hui Jin, Bernie O'Hare, Jing Dong, Sergei Arzhantsev, Gary A. Baker, James F. Wishart, Alan J. Benesi, and Mark Maroncelli J. Phys. Chem. B 112, 81-92 (2008). [Find paper at ACS Publications] Abstract: Physical properties of 4 room-temperature ionic liquids consisting of the 1-butyl-3-methylimidazolium cation with various perfluorinated anions and the bis(trifluoromethylsulfonyl)imide (Tf2N-) anion with 12 pyrrolidinium-, ammonium-, and hydroxyl-containing cations are reported. Electronic structure methods are used to calculate properties related to the size, shape, and dipole moment of individual ions. Experimental measurements of

76

Physical Chemistry of Ionic Liquids Symposium Schedule  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(Tentative Schedule, locations and times to be determined) (Tentative Schedule, locations and times to be determined) Sunday Morning Structure and Heterogeneity of Ionic Liquids I. James Wishart and Edward Castner Introductory Remarks Andre Pinkert Hydroxyamine ionic liquids and their properties Thomas Strassner TAAILs - Tunable Aryl-Alkyl Ionic Liquids: A new generation of ionic liquids Laura Sprunger Grubbs Thermodynamic Properties of New Generation Ionic Liquids Christopher Hardacre Prediction methods for physical properties of ionic liquids BREAK Patricia Hunt What happens when you functionalise an ionic liquid with a "silicone" side chain? Edward L Quitevis Effect of cation symmetry and nanoscale segregation on the morphology, physical properties, and low-frequency vibrational dynamics of 1,3-dialkylimidazolium cation ionic liquids

77

Cationic electrodepositable coating composition comprising lignin  

DOE Patents [OSTI]

A cationic electrodepositable coating composition is disclosed. The present invention in directed to a cationic electrodepositable coating composition comprising a lignin-containing cationic salt resin, that comprises (A) the reaction product of: lignin, an amine, and a carbonyl compound; (B) the reaction product of lignin, epichlorohydrin, and an amine; or (C) combinations thereof.

Fenn, David; Bowman, Mark P; Zawacky, Steven R; Van Buskirk, Ellor J; Kamarchik, Peter

2013-07-30T23:59:59.000Z

78

TETRAALKYLPHOSPHONIUM POLYOXOMETALATES AS NOVEL IONIC LIQUIDS.  

SciTech Connect (OSTI)

The pairing of a Lindqvist or Keggin polyoxometalate (POM) anion with an appropriate tetraalkylphosphonium cation, [R{sub 3}R{prime}P]{sup +}, has been shown to yield an original family of ionic liquids (POM-ILs), among them salts liquid at or near ambient temperature. The physicochemical properties of several such 'inorganic liquids', in particular their thermal properties, suggests the possible application of these compounds as robust, thermally-stable solvents for liquid-liquid extraction. A preliminary evaluation of the potential of POM-ILs in this application is presented.

DIETZ,M.L.; RICKERT, P.G.; ANTONIO, M.R.; FIRESTONE, M.A.; WISHART, J.F.; SZREDER, T.

2007-11-30T23:59:59.000Z

79

Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite Sodium Natrolite Thursday, October 31, 2013 Structural changes leading to disordering of the cation-water arrangement within the pores of zeolite natrolite while exchanging sodium (Na+) with potassium (K+) have been investigated using x-ray diffraction (XRD) and oxygen K-edge x-ray absorption spectroscopy (XAS). cation in zeolite sodium natrolite fig1 Figure 1) Artistic representation of the natrolite channel, which opens progressively as a function of the exchanging cation's size. The small golf ball represents ordered sodium cations in a closed elliptical channel, whereas the large baseball represents a disordered cesium cation in an open circular channel. The most fundamental chemical property of zeolites is ion exchange. A

80

Hybrid Automata: An Algorithmic Approach to the Speci cation and Veri cation of  

E-Print Network [OSTI]

Hybrid Automata: An Algorithmic Approach to the Speci cation and Veri cation of Hybrid Systems1 of hybrid automata as a model and speci cation language for hybrid systems. Hybrid automatacan be viewed erential equations. We show that many of the examples considered in the workshop can be de ned by hybrid

Henzinger, Thomas A.

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Automatically generating information from a Z speci cation to support the Classi cation Tree  

E-Print Network [OSTI]

Automatically generating information from a Z speci#12;cation to support the Classi#12;cation Tree, Brunel University, Uxbridge, Middlesex, UB8 3PH, UK 2 DaimlerChrysler AG, Research Information. The Classi#12;cation Tree Method provides a exible basis for systematic testing. Traditionally

Singer, Jeremy

82

Speci cation and Veri cation of a Steam-Boiler with Signal-Coq Micka l Kerb uf1  

E-Print Network [OSTI]

Speci cation and Veri cation of a Steam-Boiler with Signal-Coq Micka l Kerb uf1 , David Nowak2 assistant, Coq, for the speci cation and the veri cation of co-inductive properties of the well-known steam-boiler cation tools. Keywords: synchronous programming, theorem proving, the steam- boiler problem. 1

Boyer, Edmond

83

Cationic phospholipids: structure?transfection activity relationships  

SciTech Connect (OSTI)

Synthetic cationic lipids are presently the most widely used non-viral gene carriers. Examined here is a particularly attractive cationic lipid class, triester phosphatidylcholines (PCs) exhibiting low toxicities and good transfection efficiency. Similarly to other cationic lipids, they form stable complexes (lipoplexes) with the polyanionic nucleic acids. A summary of studies on a set of {approx}30 cationic PCs reveals the existence of a strong, systematic dependence of their transfection efficiency on the lipid hydrocarbon chain structure: transfection activity increases with increase of chain unsaturation from 0 to 2 double bonds per lipid and decreases with increase of chain length in the range {approx}30-50 total number of chain carbon atoms. Maximum transfection was observed for ethyl phosphate PCs (EPCs) with monounsaturated 14:1 chains (total of 2 double bonds and 30 chain carbon atoms). Lipid phase behavior is known to depend strongly on the chain molecular structure and the above relationships thus substantiate a view that cationic PC phase propensities are an important determinant of their activity. Indeed, X-ray structural studies show that the rate of DNA release from lipoplexes as well as transfection activity well correlate with non-lamellar phase progressions observed in cationic PC mixtures with membrane lipids. These findings appear to be of considerable interest because, according to current views, key processes in lipid-mediated transfection such as lipoplex disassembly and DNA release within the cells are believed to take place upon cationic lipid mixing with cellular lipids.

Koynova, Rumiana; Tenchov, Boris; (NWU)

2010-01-18T23:59:59.000Z

84

Are the Radical Centers in Peptide Radical Cations Mobile? The...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Radical Centers in Peptide Radical Cations Mobile? The Generation, Tautomerism, and Dissociation of Isomeric ? Are the Radical Centers in Peptide Radical Cations Mobile?...

85

1,2,3-triazolium ionic liquids  

DOE Patents [OSTI]

The present invention relates to compositions of matter that are ionic liquids, the compositions comprising substituted 1,2,3-triazolium cations combined with any anion. Compositions of the invention should be useful in the separation of gases and, perhaps, as catalysts for many reactions.

Luebke, David; Nulwala, Hunaid; Tang, Chau

2014-12-09T23:59:59.000Z

86

Can Ionic Liquids Be Used As Templating Agents For Controlled Design of Uranium-Containing Nanomaterials?  

SciTech Connect (OSTI)

Nanostructured uranium oxides have been prepared in ionic liquids as templating agents. Using the ionic liquids as reaction media for inorganic nanomaterials takes advantage of the pre-organized structure of the ionic liquids which in turn controls the morphology of the inorganic nanomaterials. Variation of ionic liquid cation structure was investigated to determine the impact on the uranium oxide morphologies. For two ionic liquid cations, increasing the alkyl chain length increases the aspect ratio of the resulting nanostructured oxides. Understanding the resulting metal oxide morphologies could enhance fuel stability and design.

Visser, A.; Bridges, N.; Tosten, M.

2013-04-09T23:59:59.000Z

87

Intermolecular vibrations and fast relaxations in supercooled ionic liquids  

Science Journals Connector (OSTI)

Short-time dynamics of ionic liquids has been investigated by low-frequency Raman spectroscopy (4 < ? < 100 cm?1) within the supercooled liquid range. Raman spectra are reported for ionic liquids with the same anion bis(trifluoromethylsulfonyl)imide and different cations: 1-butyl-3-methylimidazolium 1-hexyl-3-methylimidazolium 1-butyl-1-methylpiperidinium trimethylbutylammonium and tributylmethylammonium. It is shown that low-frequency Raman spectroscopy provides similar results as optical Kerr effect (OKE) spectroscopy which has been used to study intermolecular vibrations in ionic liquids. The comparison of ionic liquids containing aromatic and non-aromatic cations identifies the characteristic feature in Raman spectra usually assigned to librational motion of the imidazolium ring. The strength of the fast relaxations (quasi-elastic scattering QES) and the intermolecular vibrational contribution (boson peak) of ionic liquids with non-aromatic cations are significantly lower than imidazolium ionic liquids. A correlation length assigned to the boson peak vibrations was estimated from the frequency of the maximum of the boson peak and experimental data of sound velocity. The correlation length related to the boson peak (?19 ) does not change with the length of the alkyl chain in imidazolium cations in contrast to the position of the first-sharp diffraction peak observed in neutron and X-ray scattering measurements of ionic liquids. The rate of change of the QES intensity in the supercooled liquid range is compared with data of excess entropy free volume and mean-squared displacement recently reported for ionic liquids. The temperature dependence of the QES intensity in ionic liquids illustrates relationships between short-time dynamics and long-time structural relaxation that have been proposed for glass-forming liquids.

Mauro C. C. Ribeiro

2011-01-01T23:59:59.000Z

88

Survey on ionic liquids effect based on metal anions over the thermal stability of heavy oil  

Science Journals Connector (OSTI)

A survey on the effect of ionic liquids (ILs) over the thermal stability of a heavy Mexican oil was performed. ILs used were based on [Cnim]+ and [Cnpyr]+ organic cations with FeCl 4 ...

J. A. Murillo-Hernndez; S. Lpez-Ramrez

2009-01-01T23:59:59.000Z

89

Cationically polymerizable monomers derived from renewable sources  

SciTech Connect (OSTI)

The objective of this project is to make use of products obtained from renewable plant sources as monomers for the direct production of polymers which can be used for a wide range of plastic applications. In this report is described progress in the synthesis and polymerization of cationically polymerizable monomers and oligomers derived from botanical oils, terpenes, natural rubber, and lignin. Nine different botanical oils were obtained from various sources, characterized and then epoxidized. Their photopolymerization was carried out using cationic photoinitiators and the mechanical properties of the resulting polymers characterized. Preliminary biodegradation studies are being conducted on the photopolymerized films from several of these oils. Limonene was cationically polymerized to give dimers and the dimers epoxidized to yield highly reactive monomers suitable for coatings, inks and adhesives. The direct phase transfer epoxidation of squalene and natural rubber was carried out. The modified rubbers undergo facile photocrosslinking in the presence of onium salts to give crosslinked elastomers. 12 refs., 3 figs., 10 tabs.

Crivello, J.V.

1991-10-01T23:59:59.000Z

90

Cationically polymerizable monomers derived from renewable sources  

SciTech Connect (OSTI)

The objectives of this project are to design and synthesize novel monomers which orginate from renewable biological sources and to carry out their rapid, efficient, pollution-free and energy efficient cationic polymerization to useful products under the influence of ultraviolet light or heat. A summary of the results of the past year's research on cationically polymerizable monomers derived from renewable sources is presented. Three major areas of investigation corresponding to the different classes of naturally occurring starting materials were investigated; epoxidized terpenes and natural rubber and vinyl ethers from alcohols and carbohydrates.

Crivello, J.V.

1992-10-01T23:59:59.000Z

91

Effect of cationic monomer on properties of cationic fluorocarbon emulsifier-free emulsion  

Science Journals Connector (OSTI)

Cationic fluorocarbon emulsifier-free emulsion (CFE) was prepared by a novel method, ... to emulsion. The stability mechanism of the CFE system was proposed. The pre-copolymer prepared ... it had disadvantages to...

Chen Wang; Xiaorui Li; Biao Du; Peizhi Li; Xiaohui Mi

2013-02-01T23:59:59.000Z

92

E-Print Network 3.0 - alkaline earth cations Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the cation (alkaline, rare earth... to the cation size. Knowing that the size of rare earth elements and alkaline cations decreases in the following... of results on tungstate...

93

Cation Exchange and A1 Mobilization in Soils  

Science Journals Connector (OSTI)

Predicting the equilibria of cations distributed between soil solutions and exchange sites is a classical soil chemistry problem. Interest in such cation distribution problems has been motivated by a need to i...

D. D. Richter; D. W. Johnson; K. H. Dai

1992-01-01T23:59:59.000Z

94

EMSL - liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquids en Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. http:www.emsl.pnl.govemslwebpublicationsiodine-solubility-low-activity-waste-borosilicate...

95

Microsoft Word - cation-in-zeolite-natrolite  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite Sodium Natrolite Structural changes leading to disordering of the cationwater arrangement within the pores of zeolite natrolite while exchanging sodium (Na + ) with potassium (K + ) have been investigated using X-ray diffraction (XRD) and oxygen K-edge X-ray absorption spectroscopy (XAS). The most fundamental chemical property of zeolites is ion exchange. A detailed understanding of why and how ion exchange occurs is of tremendous importance for many industrial processes ranging from well-known water softening to environmental cleanup such as radionuclide storage. In the case of sodium natrolite, rubidium- or cesium- containing natrolites can only be made if Na + is first

96

Alkaline earth cation extraction from acid solution  

DOE Patents [OSTI]

An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

Dietz, Mark (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

2003-01-01T23:59:59.000Z

97

N-Methyl-N-Allylpyrrolidinium Based Ionic Liquids for Solvent-Free Dye-Sensitized Solar Cells  

Science Journals Connector (OSTI)

We prepared four new ionic liquids consisting of N-methyl-N-allylpyrrolidinium cation in conjunction with anions including iodide, nitrate, thiocyanate, and dicyanamide, respectively, and measured their physical properties of density, viscosity, and ...

Ning Cai; Jing Zhang; Difei Zhou; Zhihui Yi; Jin Guo; Peng Wang

2009-02-16T23:59:59.000Z

98

Integrated Chemical Geothermometry System for Geothermal Exploration  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. Develop practical and reliable system to predict geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids.

99

LNG liquid-liquid immiscibility  

SciTech Connect (OSTI)

Although natural gas species rarely exhibit liquid-liquid immiscibility in binary systems, the presence of additional components can extend the domain of immiscibility in those few binary systems where it already exists or produce immiscibility in binary systems where it had not existed. If the solute has the proper molecular relation to the solvent mixture background, liquid-liquid-vapor (LLV) behavior will occur; such phenomena greatly complicate the design of LNG processing equipment. To aid LNG engineers, researchers mapped the thermodynamic behavior of four ternary LLV systems and examined the effects of the second solvents - ethane, propane, n-butane, and CO/sub 2/ - on the binary methane + n-octane system.

Luks, K.D.; Kohn, J.P.

1981-09-01T23:59:59.000Z

100

The Effect of Temperature, Cations, and Number of Acyl Chains...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(i.e., number of acyl chains), cation type, and temperature influence the phase transition, aggregate structure, and endotoxic activity of Lipid-A. We have applied an...

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Charge trapping in imidazolium ionic liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

trapping in imidazolium ionic liquids trapping in imidazolium ionic liquids I. A. Shkrob and J. F. Wishart J. Phys. Chem. B 113, 5582-5592 (2009). [Find paper at ACS Publications] or use ACS Articles on Request Abstract: Room-temperature ionic liquids (ILs) are a promising class of solvents for applications ranging from photovoltaics to solvent extractions. Some of these applications involve the exposure of the ILs to ionizing radiation, which stimulates interest in their radiation and photo- chemistry. In the case of ILs consisting of 1,3-dialkylimidazolium cations and hydrophobic anions, ionization, charge transfer and redox reactions yield charge-trapped species thought to be radicals resulting from neutralization of the constituent ions. Using computational chemistry methods and the recent results on electron spin resonance (ESR) and transient absorption

102

Charge Density of Divalent Metal Cations Determines RNA Stability  

E-Print Network [OSTI]

determined by a combination of counterion charge and the packing efficiency of condensed cations that depends RNAs that have regions of high negative potential interact even more strongly with counterions than of the phosphate charge arises from nonspecific condensation of counterions.4,10 The ionic radius of a metal cation

Thirumalai, Devarajan

103

CSE647: Testing and Veri cation (Fall 2000) Scott Stoller  

E-Print Network [OSTI]

CSE647: Testing and Veri#12;cation (Fall 2000) Scott Stoller Exam For every problem, you must whether it is possible, based only on the given information about S, to conclude that the speci#12;ed set is persistent in the speci#12;ed state. Your answer must be yes or no, followed by a justi#12;cation. Use

Stoller, Scott

104

Classi cation of Carbide Distributions using Scale-Space Methods Classi cation of Carbide Distributions using Scale  

E-Print Network [OSTI]

Classi cation of Carbide Distributions using Scale-Space Methods #12;Classi cation of Carbide-structure of the steel, which in turn in uences the mechanical properties. Speci - cally, the distribution of carbide is essential, since cracks propagate within the carbide agglomerations. In current quality control

Lindeberg, Tony

105

Intermolecular Dynamics, Interactions and Solvation in Ionic Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dynamics, Interactions and Solvation in Ionic Liquids Dynamics, Interactions and Solvation in Ionic Liquids Edward W. Castner, Jr., James F. Wishart, and Hideaki Shirota Acc. Chem. Res. 40, 1217-1227 (2007). [Find paper at ACS Publications] Abstract: Ionic liquids can simultaneously assume multiple solvent roles, because they are strongly polar and polarizable solvents and binary solutions and frequently contain very hydrophobic components. When the cation and anion functional groups are tuned appropriately, ionic liquids can be used as designer solvents for a broad range of applications. In this Account, we discuss our spectroscopic studies on the intermolecular interactions, dynamics, solvation, transport, and friction in ionic liquids, as compared with information obtained from macroscopic experiments including viscometry

106

Cation Defects and Conductivity in Transparent Oxides  

SciTech Connect (OSTI)

High quality doped zinc oxide and mixed transition metal spinel oxide films have been deposited by means of sputter deposition from metal and metal oxide targets, and by spin casting from aqueous or alcoholic precursor solutions. Deposition conditions and post-deposition processing are found to alter cation oxidation states and their distributions in both oxide materials resulting in marked changes to both optical transmission and electrical response. For ZnO, partial reduction of the neat or doped material by hydrogen treatment of the heated film or by electrochemical processing renders the oxide n-type conducting. Continued reduction was found to diminish conductivity. In contrast, oxidation of the infrared transparent p-type spinel conductors typified by NiCo2O4 was found to increase conductivity. The disparate behavior of these two materials is caused in part by the sign of the charge carrier and by the existence of two different charge transport mechanisms that are identified as free carrier conduction and polaron hopping. While much work has been reported concerning structure/property relationships in the free carrier conducting oxides, there is a significantly smaller body of information on transparent polaron conductors. In this paper, we identify key parameters that promote conductivity in mixed metal spinel oxides and compare their behavior with that of the free carrier TCOs.

Exarhos, Gregory J.; Windisch, Charles F.; Ferris, Kim F.; Owings, Robert R.

2007-10-24T23:59:59.000Z

107

Radical cations of sulfides and disulfides: An ESR study  

SciTech Connect (OSTI)

Exposure of dilute solutions of dimethylsulfide, methanethiol, tetrahydrothiophene, terbutyl and diterbutyl-sulfides, dimethyl-disulfide, and diterbutyldisulfide, in freon at 77 K to /sup 60/Co ..gamma.. rays gave the corresponding cations. From the reported ESR spectra, g tensors were obtained. It was found that both sulfide and disulfide cations exhibit the same g tensor: (g/sub max/ = 2.034 +- 0.002, g/sub int/ = 2.017 +- 0.001, g/sub min/ = 2.001 +- 0.005). From this result it has been shown that the disulfide cation is planar. This finding was supported by fully optimized geometry ab initio calculations.

Bonazzola, L.; Michaut, J.P.; Roncin, J.

1985-09-15T23:59:59.000Z

108

Cation Transport in Polymer Electrolytes: A Microscopic Approach  

E-Print Network [OSTI]

A microscopic theory for cation diffusion in polymer electrolytes is presented. Based on a thorough analysis of molecular dynamics simulations on PEO with LiBF$_4$ the mechanisms of cation dynamics are characterised. Cation jumps between polymer chains can be identified as renewal processes. This allows us to obtain an explicit expression for the lithium ion diffusion constant D_{Li} by invoking polymer specific properties such as the Rouse dynamics. This extends previous phenomenological and numerical approaches. In particular, the chain length dependence of D_{Li} can be predicted and compared with experimental data. This dependence can be fully understood without referring to entanglement effects.

A. Maitra; A. Heuer

2007-05-11T23:59:59.000Z

109

Durable electrooptic devices comprising ionic liquids  

DOE Patents [OSTI]

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF3SO3-), bis(trifluoromethylsulfonyl)imide ((CF3SO2)2N-), bis(perfluoroethylsulfonyl)imide ((CF3CF2SO2)2N-) and tris(trifluoromethylsulfonyl)methide ((CF3SO2)3C-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

Agrawal, Anoop (Tucson, AZ); Cronin, John P. (Tucson, AZ); Tonazzi, Juan C. L. (Tucson, AZ); Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM); Burrell, Anthony K. (Los Alamos, NM)

2005-11-01T23:59:59.000Z

110

Liquid electrode  

DOE Patents [OSTI]

A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

Ekechukwu, A.A.

1994-07-05T23:59:59.000Z

111

Synthesis of Cationic Extended Frameworks for Anion-Based Applications  

E-Print Network [OSTI]

cationic layer derives from brucite Mg(OH) 2 , with edge-layer (Figure 1.1). Unlike brucite [Mg(OH) 2 ] forming aof structures based on brucite with a general formula [M 2+

Fei, Honghan

2012-01-01T23:59:59.000Z

112

Cation and Anion Exchange Properties of Pillared Clays  

Science Journals Connector (OSTI)

Cation and anion pH dependent exchange processes on an Aluminium Pillared Clay (Al-PILC) and Zirconium Pillared Clay (Zr-PILC) were studied by titrating the PILCS with...

A. Dyer; T. Gallardo

1990-01-01T23:59:59.000Z

113

Role of cation choice in the radiation tolerance of pyrochlores...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

volume swelling of the track is 4%, which suggests that it is partially amorphous. Gd vacancies and Ti interstitials along with cation exchange play a role in damage accumulation...

114

Layered inorganic/organic mercaptopropyl pendant chain hybrid for chelating heavy cations  

SciTech Connect (OSTI)

Graphical abstract: Crystalline lamellar silicate RUB-18 was immobilized with mercaptopropyl groups at the surface and then used as support for cadmium and lead removal from aqueous solutions. Highlights: Black-Right-Pointing-Pointer Synthetic methodology requires intercalation. Black-Right-Pointing-Pointer Organofunctionalized ilerite compound as sorbent. Black-Right-Pointing-Pointer Active mercaptopropyl groups remove cations. Black-Right-Pointing-Pointer High maximum sorption capacity for cadmium. -- Abstract: Heavy metal sorbents with uptake capacities for divalent cadmium and lead cation removal from aqueous solutions have been synthesized by grafting mercaptopropyltrimethoxysilane onto the surface of two different precursors obtained from lamellar ilerite, its acidic and the cetyltrimethylammonium exchanged forms. The organofunctionalization was carried out by two different procedures: reflux and solvent evaporation methodologies. Elemental analysis data based on carbon content gave 1.37 and 3.53 mmol of organic pendant groups per gram of hybrid by the reflux method, when starting from acidic ilerite and the surfactant form. X-ray diffraction corroborated the maintenance of the original crystallinity. Infrared spectroscopy and nuclear magnetic resonance for {sup 29}Si and {sup 13}C nuclei are in agreement with the success of the proposed method. The sulfur basic centers attached to the lamellar structure are used to coordinate both cations at the solid/liquid interface. The isotherms were obtained through the batchwise process and the experimental data were adjusted to the Freundlich model. The maximum sorption capacities of 5.55 and 5.12 mmol g{sup -1} for lead and 6.10 and 7.10 mmol g{sup -1} for cadmium were obtained for organofunctionalized ilerite and its surfactant form, synthesized by reflux methodology. This behavior suggested that these hybrids could be employed as promising sorbents with a polluted system.

Macedo, Thais R. [Institute of Chemistry, University of Campinas, UNICAMP, P.O. Box 6154, 13084-71 Campinas, SP (Brazil)] [Institute of Chemistry, University of Campinas, UNICAMP, P.O. Box 6154, 13084-71 Campinas, SP (Brazil); Petrucelli, Giovanni C. [Institute of Chemistry, Federal University of Goias, Jatai, P.O. Box 03, 75805-190 Jatai, GO (Brazil)] [Institute of Chemistry, Federal University of Goias, Jatai, P.O. Box 03, 75805-190 Jatai, GO (Brazil); Pinto, Alane A. [Institute of Chemistry, University of Campinas, UNICAMP, P.O. Box 6154, 13084-71 Campinas, SP (Brazil) [Institute of Chemistry, University of Campinas, UNICAMP, P.O. Box 6154, 13084-71 Campinas, SP (Brazil); Institute of Chemistry, Federal University of Goias, Jatai, P.O. Box 03, 75805-190 Jatai, GO (Brazil); Airoldi, Claudio, E-mail: airoldi@iqm.unicamp.br [Institute of Chemistry, University of Campinas, UNICAMP, P.O. Box 6154, 13084-71 Campinas, SP (Brazil)] [Institute of Chemistry, University of Campinas, UNICAMP, P.O. Box 6154, 13084-71 Campinas, SP (Brazil)

2011-12-15T23:59:59.000Z

115

Hydroxide Degradation Pathways for Substituted Trimethylammonium Cations: A DFT Study  

SciTech Connect (OSTI)

Substituted trimethylammonium cations serve as small molecule analogues for tetherable cations in anion exchange membranes. In turn, these membranes serve as the basis for alkaline membrane fuel cells by allowing facile conduction of hydroxide. As these cations are susceptible to hydroxide attack, they degrade over time and greatly limit the lifetime of the fuel cell. In this research, we performed density functional theory calculations to investigate the degradation pathways of substituted trimethylammonium cations to probe the relative durability of cation tethering strategies in alkyl and aromatic tethers. Our results show that significant changes in calculated energy barriers occur when substitution groups change. Specifically, we have found that, when available, the Hofmann elimination pathway is the most vulnerable pathway for degradation; however, this barrier is also found to depend on the carbon chain length and number of hydrogens susceptible to Hofmann elimination. S{sub N}2 barriers were also investigated for both methyl groups and substitution groups. The reported findings give important insight into potential tethering strategies for trimethylammonium cations in anion exchange membranes.

Long, H.; Kim, K.; Pivovar, B. S.

2012-05-03T23:59:59.000Z

116

Guidance Document Cryogenic Liquids  

E-Print Network [OSTI]

Guidance Document Cryogenic Liquids [This is a brief and general summary. Read the full MSDS for more details before handling.] Introduction: All cryogenic liquids are gases at normal temperature liquefies them. Cryogenic liquids are kept in the liquid state at very low temperatures. Cryogenic liquids

117

A liquid film motor  

Science Journals Connector (OSTI)

It is well known that electro-hydrodynamical effects in freely suspended liquid films can force liquids to flow. Here, we report a purely electrically driven rotation in water and some other liquid suspended film...

A. Amjadi; R. Shirsavar; N. Hamedani Radja

2009-05-01T23:59:59.000Z

118

Effects of Structural Modification on Ionic Liquid Physical Properties  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Effect of Structural Modification on the Physical Properties Effect of Structural Modification on the Physical Properties of Various Ionic Liquids S. I. Lall-Ramnarine, J. L. Hatcher, A. Castano, M. F. Thomas, and J. F. Wishart in "ECS Transactions - Las Vegas, NV, Vol. 33, Molten Salts and Ionic Liquids 17" D. Fox et al., Eds.; The Electrochemical Society, Pennington, NJ, (2010) pp 659 - 665. [Find paper at ECS] Abstract: A few classes of ionic liquids were synthesized and investigated for their physical properties as a function of structural variation. Bis(oxalato)borate (BOB) and bis(trifluoromethylsulfonyl)imide (NTf2) ionic liquids (ILs) containing pyridinium, 4-dimethylaminopyridinium (DMAP) and pyrrolidinium cations bearing alkyl, benzyl, hydroxyalkyl and alkoxy substituents, were prepared from the corresponding halide salts. The

119

Low-frequency Raman spectra and fragility of imidazolium ionic liquids  

SciTech Connect (OSTI)

Raman spectra within the 5-200 cm{sup -1} range have been recorded as a function of temperature for different ionic liquids based on imidazolium cations. A correlation has been found between fragility and the temperature dependence of the strength of fast relaxational motions. Understanding quasielastic scattering as the relaxational contribution to ionic mean-squared displacement elucidates some effects on ionic liquids' fragility resulting from modifications in the chemical structure.

Ribeiro, Mauro C. C. [Laboratorio de Espectroscopia Molecular, Instituto de Quimica, Universidade de Sao Paulo, CP 26077, CEP 05513-970 Sao Paulo, Sao Paulo (Brazil)

2010-07-14T23:59:59.000Z

120

Low-frequency Raman spectra and fragility of imidazolium ionic liquids  

Science Journals Connector (OSTI)

Raman spectra within the 5 200 ? cm ? 1 range have been recorded as a function of temperature for different ionic liquids based on imidazolium cations. A correlation has been found between fragility and the temperature dependence of the strength of fast relaxational motions. Understanding quasielastic scattering as the relaxational contribution to ionic mean-squared displacement elucidates some effects on ionic liquids fragility resulting from modifications in the chemical structure.

Mauro C. C. Ribeiro

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

New methods and materials for solid phase extraction and high performance liquid chromatography  

SciTech Connect (OSTI)

This paper describes methods for solid phase extraction and high performance liquid chromatography (HPLC). The following are described: Effects of Resin Sulfonation on the Retention of Polar Organic Compounds in Solid Phase Extraction; Ion-Chromatographic Separation of Alkali Metals In Non-Aqueous Solvents; Cation-Exchange Chromatography in Non-Aqueous Solvents; and Silicalite As a Stationary Phase For HPLC.

Dumont, P.J.

1996-04-23T23:59:59.000Z

122

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

123

Poly(3-decylthiophene) Radical Anions and Cations in Solution  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Poly(3-decylthiophene) Radical Anions and Cations in Solution: Single and Poly(3-decylthiophene) Radical Anions and Cations in Solution: Single and Multiple Polarons and Their Delocalization Lengths in Conjugated Polymers N. Takeda and J. R. Miller J. Phys. Chem. B 116, 14715-14723 (2012). [Find paper at ACS Publications] Abstract: Optical absorption spectra of anions and cations of poly(3-decylthiophene) (P3DT) in solution were identified as single polarons. Pulse radiolysis of P3DT in THF determined the spatial extent of one negative polaron to be similar to 11.5 thiophene units by observing transient absorption of P3DT(-dot) radical ions, which are prinicpally free ions, at 850 nm with epsilon = (7.25 ± 0.47) x 104 M-1 cm-1 and bleaching of the neutral absorption band at 450 nm. P3DT(-dot) was formed in a combination of diffusive reactions and fast "step" processes. Similarly, a positive

124

Comparison of Cation Adsorption by Isostructural Rutile and Cassiterite  

SciTech Connect (OSTI)

Macroscopic net proton charging curves for powdered rutile and cassiterite specimens with the (110) Crystal face predominant, as a function of pH in RbCl and NaCl solutions, trace SrCl2 in NaCl, and trace ZnCl2 in NaCl and Na Triflate solutions, are compared to corresponding molecular-level information obtained from static DFT optimizations and classical MD simulations, as well as synchrotron X-ray methods. The similarities and differences in the macroscopic charging behavior of rutile and cassiterite largely reflect the cation binding modes observed at the molecular level. Cation adsorption is primarily inner-sphere on both isostructural (110) surfaces, despite predictions that outer-sphere binding should predominate on low bulk dielectric constant oxides such as cassiterite ( bulk 11). Inner-sphere adsorption is also significant for Rb and Na on neutral surfaces, whereas Cl- binding is predominately outer-sphere. As negative surface charge increases, relatively more Rb , Na , and especially Sr2 are bound in highly desolvated tetradentate fashion on the rutile (110) surface, largely accounting for enhanced negative charge development relative to cassiterite. Charging curves in the presence of Zn2 are very steep but similar for both oxides, reflective of Zn2 hydrolysis (and accompanying proton release) during the adsorption process, and the similar binding modes for ZnOH on both surfaces. These results suggest that differences in cation adsorption between high and low bulk dielectric constant oxides are more subtly related to the relative degree of cation desolvation accompanying inner-sphere binding (i.e., more tetradentate binding on rutile), rather than distinct inner- and outer-sphere adsorption modes. Cation desolvation may be favored at the rutile (110) surface in part because inner-sphere water molecules are bound further from and less tightly than on the cassiterite (110) surface. Hence, their removal upon inner-sphere cation binding is relatively more favorable.

Machesky, Michael L. [Illinois State Water Survey, Champaign, IL; Wesolowski, David J [ORNL; Rosenqvist, Jorgen K [ORNL; Predota, M. [University of South Bohemia, Czech Republic; Vlcek, Lukas [ORNL; Ridley, Moira K [ORNL; Kohli, V [Oak Ridge National Laboratory (ORNL); Zhang, Zhan [Argonne National Laboratory (ANL); Fenter, Paul [Argonne National Laboratory (ANL); Cummings, Peter T [ORNL; Lvov, Serguei N. [Pennsylvania State University; Fedkin, Mark V [ORNL; Rodriguez-Santiago, V [Oak Ridge National Laboratory (ORNL); Kubicki, James D. [Pennsylvania State University; Bandura, Andrei V. [St. Petersburg State University, St. Petersburg, Russia

2011-01-01T23:59:59.000Z

125

Safetygram #9- Liquid Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

126

Cationically polymerizable monomers derived from renewable sources. Annual performance report  

SciTech Connect (OSTI)

The objectives of this project are to design and synthesize novel monomers which orginate from renewable biological sources and to carry out their rapid, efficient, pollution-free and energy efficient cationic polymerization to useful products under the influence of ultraviolet light or heat. A summary of the results of the past year`s research on cationically polymerizable monomers derived from renewable sources is presented. Three major areas of investigation corresponding to the different classes of naturally occurring starting materials were investigated; epoxidized terpenes and natural rubber and vinyl ethers from alcohols and carbohydrates.

Crivello, J.V.

1992-10-01T23:59:59.000Z

127

Synergism by co-assembly at the origin of ion selectivity in liquid-liquid extraction  

SciTech Connect (OSTI)

In liquid-liquid extraction, synergism emerges when for a defined formulation of the solvent phase, there is an increase of distribution coefficients for some cations in a mixture. To characterize the synergistic mechanisms, we determine the free energy of mixed co-assembly in aggregates. Aggregation in any point of a phase diagram can be followed not only structurally by SANS, SAXS, and SLS, but also thermodynamically by determining the concentration of monomers coexisting with reverse aggregates. Using the industrially used couple HDEHP/TOPO forming mixed reverse aggregates, and the representative couple U/Fe, we show that there is no peculiarity in the aggregates microstructure at the maximum of synergism. Nevertheless, the free energy of aggregation necessary to form mixed aggregates containing extracted ions in their polar core is comparable to the transfer free energy difference between target and nontarget ions, as deduced from the synergistic selectivity peak. (authors)

Dourdain, S.; Hofmeister, I.; Dufreche, J.F.; Turgis, R.; Pellet-Rostaing, S.; Zemb, T. [CEA CNRS UM2 ENSCM UMR5257, ICSM LTSM, F-30207 Bagnols Sur Ceze, (France); Pecheur, O.; Leydier, A. [CEA, Nucl Energy Div, RadioChem and Proc Dept, F-30207 Bagnols Sur Ceze, (France); Jestin, J. [CEA Saclay, Lab Leon Brillouin CEA CNRS, F-91191 Gif Sur Yvette, (France); Testard, F. [CEA Saclay, DSM IRAMIS LIONS SIS2M, F-91191 Gif Sur Yvette, (France)

2012-08-15T23:59:59.000Z

128

Steam boiler control speci cation problem: A TLA solution  

E-Print Network [OSTI]

Steam boiler control speci cation problem: A TLA solution Frank Le ke and Stephan Merz Institut fur of the state of the steam boiler, detect failures, and model message transmission. We give a more detailed between the physi- cal state of the steam boiler and the model maintained by the controller and discuss

129

Verifying SCR Requirements Speci cations Using State Exploration  

E-Print Network [OSTI]

Verifying SCR Requirements Speci cations Using State Exploration In Proc. First ACM SIGPLAN as the SCR Software Cost Reduction method, to specify the requirements of software systems using ta- bles. NRL has developed a formal state machine model de ning the SCR semantics and support tools for anal

130

SHORT COMMUNICATION An In Situ Silver Cationization Method  

E-Print Network [OSTI]

desorption of perflu- orinated polyethers (PFPEs), and used a second laser to ablate a plume of metal ions the forma- tion of metal ion adducts by mixing metal salts into the matrix they used to perform SIMS [5 from the sample substrate to form metal cation adducts [7]. Kahr and Wilkins used a layer of silver

de Vries, Mattanjah S.

131

ORBIT -Operating-Regime-Based Modeling and Identi cation Toolkit  

E-Print Network [OSTI]

projects. The MATLAB-based software tool is called ORBIT (Operating-Regime-Based modeling and Identi cation, Norway. ORBIT is a MATLAB-based toolkit for black-box and grey-box mod- eling of non-linear dynamic feature of ORBIT, compared for example to the MATLAB Fuzzy Logic Toolbox, is the strong focus

Foss, Bjarne A.

132

Towards an Algebraic Speci cation of the Java Virtual Machine  

E-Print Network [OSTI]

Towards an Algebraic Speci cation of the Java Virtual Machine K Stephenson Department of Computer of the architecture of an abstract and simpli ed version of the Java Virtual Machine JVM. This concentration on the implementation-independent features of the machine allows us to build a clean and easily comprehensible model

Grant, P. W.

133

Webbi cation of Network Karim El Guemhioui and Raouf Boutaba  

E-Print Network [OSTI]

Webbi cation of Network Management Karim El Guemhioui and Raouf Boutaba Computer Science Research) 840 - 1235 Ext. 5736, Fax: (514) 840 - 1244 e-mail: kelguemh@crim.ca ABSTRACT| Network management to the success of many organizations. The existing heterogeneity of platforms and the proliferation of approaches

El Guemhioui, Karim

134

Effect of Cations on Activation of Bacillus popilliae Spores  

Science Journals Connector (OSTI)

...not affected by so- dium, cesium, or lithium. Divalent cations may be required for...tors was also compared by adding an excess of either compound to suspensions of spores...Effect on the viable count ofadding excess KCI or EDTA to spores being heated in...

D. F. Splittstoesser; D. F. Farkas

1966-10-01T23:59:59.000Z

135

Diffusion in single crystals of melilite: 2. Cations  

SciTech Connect (OSTI)

Diffusion coefficients of divalent cations, Ni, Co, Fe, Mn, Ca, Sr, and Ba, in synthetic akermanite were determined by tracer-diffusion experiments. Diffusion coefficients of cation paris, Al + Al-Mg + Si, Al + Al-Co + Si, and Mg-Co in melilite solid-solution systems, were determined by coupled annealing of synthetic melilites of endmember compositions. Cobalt tracer diffuses slower along the c-crystallographic axis than along the a-axis by a factor of about three, possibly due to the anisotropic sheet-like arrangement of oxygen ions parallel to the (001) plane which is perpendicular to the c-axis in the crystal structure of melilite. In the coupled diffusion experiments, the cation pairs interdiffuse complementary, as expected for conservation of material and ionic charge balance in the substitution. The observed trend in the inter-diffusion coefficient vs. melting temperature relations is similar to those observed for alloys and consistent with an empirical rule for self-diffusion coefficient-melting temperature relation. In the diffusion coefficient vs. ionic radius diagram for divalent cation diffusion in akermanite, smooth curves were observed as in the case of olivine systems. However, the shapes of the curves were significantly different from those observed in olivine systems. The observed trend of diffusion coefficients with ionic radius can be explained on the basis of crystal structure-controlled diffusion in akermanite.

Morioka, Masana (Univ. of Tokyo Yayoi (Japan)); Nagasawa, Hiroshi (Gakushiun Univ. Mejiro, Tokyo (Japan))

1991-03-01T23:59:59.000Z

136

Soft ionization of thermally evaporated hypergolic ionic liquid aerosols  

SciTech Connect (OSTI)

Isolated ion pairs of a conventional ionic liquid, 1-Ethyl-3-Methyl-Imidazolium Bis(trifluoromethylsulfonyl)imide ([Emim+][Tf2N?]), and a reactive hypergolic ionic liquid, 1- Butyl-3-Methyl-Imidazolium Dicyanamide ([Bmim+][Dca?]), are generated by vaporizing ionic liquid submicron aerosol particles for the first time; the vaporized species are investigated by dissociative ionization with tunable vacuum ultraviolet (VUV) light, exhibiting clear intact cations, Emim+ and Bmim+, presumably originating from intact ion pairs. Mass spectra of ion pair vapor from an effusive source of the hypergolic ionic liquid show substantial reactive decomposition due to the internal energy of the molecules emanating from the source. Photoionization efficiency curves in the near threshold ionization region of isolated ion pairs of [Emim+][Tf2N?] ionic liquid vapor are compared for an aerosol source and an effusive source, revealing changes in the appearance energy due to the amount of internal energy in the ion pairs. The aerosol source has a shift to higher threshold energy (~;;0.3 eV), attributed to reduced internal energy of the isolated ion pairs. The method of ionic liquid submicron aerosol particle vaporization, for reactive ionic liquids such as hypergolic species, is a convenient, thermally ?cooler? source of isolated intact ion pairs in the gas phase compared to effusive sources.

University of California; ERC, Incorporated, Edwards Air Force Base; Air Force Research Laboratory, Edwards Air Force Base; National Synchrotron Radiation Research Center (NSRRC); Koh, Christine J.; Liu, Chen-Lin; Harmon, Christopher W.; Strasser, Daniel; Golan, Amir; Kostko, Oleg; Chambreau, Steven D.; L.Vaghjiani, Ghanshyam; Leone, Stephen R.

2012-03-16T23:59:59.000Z

137

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, Albert P. (Vernon, CT)

1986-01-01T23:59:59.000Z

138

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, A.P.

1984-02-21T23:59:59.000Z

139

Compilation of quasi-destructive uni cation of type feature structures  

E-Print Network [OSTI]

on the LIGHT system concerns its extension so to achieve compilation of destructive uni#12;cation of FSs #18;a two stages. First, during uni#12;cation, modi#12;ed nodes in the two (rooted) FSs are marked so

Bennett, Brandon

140

Hydrogel with high laponite content as nanoclay: swelling and cationic dye adsorption properties  

Science Journals Connector (OSTI)

For the removal of cationic dyes, polymer hydrogels and their composites have been employed because of their unique ... Recently, some researchers used clay-filled hydrogel composites for the removal of cationic ...

Gholam Bagheri Marandi; Maryam Baharloui

2014-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Two different cationic positions in Cu-SSZ-13? . | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Design Instruments: Radiological XPS Tags: soil organic matter NOM SOM CO2 sequestration 2H NMR quadrupolar nuclei In situ catalysis radiological biology catalysis solids liquids...

142

Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations  

DOE Patents [OSTI]

A cationic metallocene complex with trisperfluorobiphenyl borate is described for use as a polymerization catalyst. 7 figs.

Marks, T.J.; Chen, Y.X.

1999-01-05T23:59:59.000Z

143

Viscosity, specific (for liquids)  

Science Journals Connector (OSTI)

n. The ratio between the viscosity of a liquid and the viscosity of water at the same temperature. Specific viscosity is sometimes used interchangeably with relative viscosity for liquids.

2007-01-01T23:59:59.000Z

144

An Algebraic Speci cation of the Steam-Boiler Control System  

E-Print Network [OSTI]

An Algebraic Speci#12;cation of the Steam-Boiler Control System Michel Bidoit 1 , Claude Chevenier describe how to derive an algebraic speci#12;cation of the Steam-Boiler Control System starting from to specify the detection of the steam-boiler fail- ures. Finally we discuss validation and veri#12;cation

Bidoit, Michel

145

PHYSICAL REVIEW B 88, 174102 (2013) Positron lifetime measurements of hydrogen passivation of cation vacancies  

E-Print Network [OSTI]

of cation vacancies in yttrium aluminum oxide garnets F. A. Selim,1,* C. R. Varney,1 M. C. Tarun,1 M. C; published 4 November 2013) A charge compensation mechanism is proposed for cation vacancy defects in complex trapping was detected in samples grown in H2. This is attributed to decoration of cation vacancies

McCluskey, Matthew

146

Liquid Piston Stirling Engines  

Science Journals Connector (OSTI)

The Fluidyne liquid piston engine is a simple free-piston Stirling engine that can be made from nothing more...

Graham Walker Ph. D.; J. R. Senft Ph.D.

1985-01-01T23:59:59.000Z

147

Characterization of Selective Binding of Alkali Cations with Carboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of Selective Characterization of Selective Binding of Alkali Cations with Carboxylate Characterization of Selective Binding of Alkali Cations with Carboxylate Print Wednesday, 24 September 2008 00:00 During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions has been known since the early 20th century, when Franz Hofmeister observed that some salts (ionic compounds) aided the solution of proteins in egg, some caused proteins to destabilize and precipitate, and others ranged in activity between the two extremes. Hofmeister then ranked "salt-out" (destabilizing) ions versus "salt-in" (stabilizing) ions according to the magnitude of their effects (the "Hofmeister effects"). However, despite enormous effort, why certain interactions are preferred over others is not completely understood. Recently, a team of researchers from UC Berkeley used the model systems of acetate and formate (two simple carboxylic acids) with a series of cations to test predictions made in the literature for preferential interactions. Near-edge x-ray absorption fine structure (NEXAFS) spectroscopy was used as this technique is highly sensitive to the chemical environments around a molecule. Experiments at ALS Beamline 8.0.1 confirmed strengthening of the interaction between the cations and the carboxylate group in the following order: potassium, sodium, and lithium.

148

Durable electrooptic devices comprising ionic liquids  

DOE Patents [OSTI]

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM); Burrell, Anthony K. (Los Alamos, NM)

2006-10-10T23:59:59.000Z

149

Polarization versus Temperature in Pyridinium Ionic Liquids  

E-Print Network [OSTI]

Electronic polarization and charge transfer effects play a crucial role in thermodynamic, structural and transport properties of room-temperature ionic liquids (RTILs). These non-additive interactions constitute a useful tool for tuning physical chemical behavior of RTILs. Polarization and charge transfer generally decay as temperature increases, although their presence should be expected over an entire condensed state temperature range. For the first time, we use three popular pyridinium-based RTILs to investigate temperature dependence of electronic polarization in RTILs. Atom-centered density matrix propagation molecular dynamics, supplemented by a weak coupling to an external bath, is used to simulate the temperature impact on system properties. We show that, quite surprisingly, non-additivity in the cation-anion interactions changes negligibly between 300 and 900 K, while the average dipole moment increases due to thermal fluctuations of geometries. Our results contribute to the fundamental understanding...

Chaban, Vitaly V

2014-01-01T23:59:59.000Z

150

NETL: IEP – Post-Combustion CO2 Emissions Control - Ionic Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ionic Liquids Ionic Liquids Project No.: FC26-07NT43091 Model of CO2 absorption by an ionic liquid. Model of CO2 absorption by an IL. The model shows that the anions are controlling absorption in ILs. The green units represent anions and the grey units represent cations. The University of Notre Dame is conducting the Ionic Liquids: Breakthrough Absorption Technology for Post-Combustion CO2 Capture project (FC26-07NT43091), that builds on the work of its earlier project (FG26-04NT42122), to provide a comprehensive evaluation of the feasibility of using a novel class of compounds - ionic liquids (ILs) - for the capture of carbon dioxide (CO2) from the flue gas of coal-fired power plants. Initial efforts focused on "proof-of-concept" exploration, followed by a laboratory-/bench-scale effort. ILs include a broad category

151

Liquid Wall Chambers  

SciTech Connect (OSTI)

The key feature of liquid wall chambers is the use of a renewable liquid layer to protect chamber structures from target emissions. Two primary options have been proposed and studied: wetted wall chambers and thick liquid wall (TLW) chambers. With wetted wall designs, a thin layer of liquid shields the structural first wall from short ranged target emissions (x-rays, ions and debris) but not neutrons. Various schemes have been proposed to establish and renew the liquid layer between shots including flow-guiding porous fabrics (e.g., Osiris, HIBALL), porous rigid structures (Prometheus) and thin film flows (KOYO). The thin liquid layer can be the tritium breeding material (e.g., flibe, PbLi, or Li) or another liquid metal such as Pb. TLWs use liquid jets injected by stationary or oscillating nozzles to form a neutronically thick layer (typically with an effective thickness of {approx}50 cm) of liquid between the target and first structural wall. In addition to absorbing short ranged emissions, the thick liquid layer degrades the neutron flux and energy reaching the first wall, typically by {approx}10 x x, so that steel walls can survive for the life of the plant ({approx}30-60 yrs). The thick liquid serves as the primary coolant and tritium breeding material (most recent designs use flibe, but the earliest concepts used Li). In essence, the TLW places the fusion blanket inside the first wall instead of behind the first wall.

Meier, W R

2011-02-24T23:59:59.000Z

152

Sliding Luttinger liquid phases  

Science Journals Connector (OSTI)

We study systems of coupled spin-gapped and gapless Luttinger liquids. First, we establish the existence of a sliding Luttinger liquid phase for a system of weakly coupled parallel quantum wires, with and without disorder. It is shown that the coupling can stabilize a Luttinger liquid phase in the presence of disorder. We then extend our analysis to a system of crossed Luttinger liquids and establish the stability of a non-Fermi-liquid state: the crossed sliding Luttinger liquid phase. In this phase the system exhibits a finite-temperature, long-wavelength, isotropic electric conductivity that diverges as a power law in temperature T as T?0. This two-dimensional system has many properties of a true isotropic Luttinger liquid, though at zero temperature it becomes anisotropic. An extension of this model to a three-dimensional stack exhibits a much higher in-plane conductivity than the conductivity in a perpendicular direction.

Ranjan Mukhopadhyay; C. L. Kane; T. C. Lubensky

2001-07-09T23:59:59.000Z

153

Hydrogen Fluoride Capture by Imidazolium Acetate Ionic Liquid  

E-Print Network [OSTI]

Extraction of hydrofluoric acid (HF) from oils is a drastically important problem in petroleum industry, since HF causes quick corrosion of pipe lines and brings severe health problems to humanity. Some ionic liquids (ILs) constitute promising scavenger agents thanks to strong binding to polar compounds and tunability. PM7-MD simulations and hybrid density functional theory are employed here to consider HF capture ability of ILs. Discussing the effects and impacts of the cation and the anion separately and together, I will evaluate performance of imidazolium acetate and outline systematic search guidelines for efficient adsorption and extraction of HF.

Chaban, Vitaly

2015-01-01T23:59:59.000Z

154

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for conductive liquids for vertical installation in a tank, the detector having a probe positioned within a sheath and insulated therefrom by a seal so that the tip of the probe extends proximate to but not below the lower end of the sheath, the lower end terminating in a rim that is provided with notches, said lower end being tapered, the taper and notches preventing debris collection and bubble formation, said lower end when contacting liquid as it rises will form an airtight cavity defined by the liquid, the interior sheath wall, and the seal, the compression of air in the cavity preventing liquid from further entry into the sheath and contact with the seal. As a result, the liquid cannot deposit a film to form an electrical bridge across the seal.

Tshishiku, Eugene M. (Augusta, GA)

2011-08-09T23:59:59.000Z

155

Ultrasonic liquid level detector  

DOE Patents [OSTI]

An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

Kotz, Dennis M. (North Augusta, SC); Hinz, William R. (Augusta, GA)

2010-09-28T23:59:59.000Z

156

EXAFS Determination of Cation Local Order in Layered Perovskites  

SciTech Connect (OSTI)

EXAFS analysis of Bi{sub 6}Ti{sub 3}Fe{sub 2}O{sub 18} Aurivillius ceramic was performed to elucidate the local environment of Fe cations. Experiments were performed at Stanford Synchrotron Radiation Laboratory, at T = 10, 30, 50, 75, 100 and 298 K, in fluorescence regime. EXAFS spectra were processed using the ab initio multiple scattering program FEFF6. Distances among representative atomic pairs were refined. As a basic result, the previous hypothesis suggested by X-ray diffraction experiments, regarding a preference of iron atoms for the centered perovskite layer of the unit cell, was confirmed.

Montero-Cabrera, M.E.; Garcia-Guaderrama, M.; Mehta, A.; Webb, S.; Fuentes-Montero, L.; Moller, J.A.D.; Fuentes-Cobas, L.; /Autonoma U., Chihuahua /SLAC, SSRL

2009-06-05T23:59:59.000Z

157

Controlled Doping of Transition Metal Cations in Alumina Pillared Clays  

Science Journals Connector (OSTI)

First, calcined Al-PILC was dispersed into an aqueous solution of sodium or ammonium ions. ... The ion-doped Al-PILC was then exchanged with an aqueous solution of transition metal salt at a pH of ?4.5 to replace Na+ or NH4+ ions by transition metal cations. ... Analytical techniques such as atomic absorption spectroscopy, X-ray diffraction, diffuse reflectance?ultraviolet?visible spectroscopy, as well as N2 adsorption were used to characterize the PILC products with and without the loading of metal ions. ...

H. Y. Zhu; Z. H. Zhu; G. Q. Lu

2000-05-31T23:59:59.000Z

158

Ionic liquids for separation of olefin-paraffin mixtures  

DOE Patents [OSTI]

The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

2013-09-17T23:59:59.000Z

159

Ionic liquids for separation of olefin-paraffin mixtures  

DOE Patents [OSTI]

The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

2014-07-15T23:59:59.000Z

160

Liquid heat capacity lasers  

DOE Patents [OSTI]

The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

2007-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Carbon monoxide absorbing liquid  

SciTech Connect (OSTI)

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

162

Precision liquid level sensor  

DOE Patents [OSTI]

A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

Field, Michael E. (Albuquerque, NM); Sullivan, William H. (Albuquerque, NM)

1985-01-01T23:59:59.000Z

163

Liquid Fuels Market Module  

U.S. Energy Information Administration (EIA) Indexed Site

Liquid Fuels Market Module Liquid Fuels Market Module This page inTenTionally lefT blank 145 U.S. Energy Information Administration | Assumptions to the Annual Energy Outlook 2013 Liquid Fuels Market Module The NEMS Liquid Fuels Market Module (LFMM) projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil (both domestic and imported), petroleum product imports, unfinished oil imports, other refinery inputs (including alcohols, ethers, esters, corn, biomass, and coal), natural gas plant liquids production, and refinery processing gain. In addition, the LFMM projects capacity expansion and fuel consumption at domestic refineries. The LFMM contains a linear programming (LP) representation of U.S. petroleum refining

164

Reading Comprehension - Liquid Nitrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquid Nitrogen Liquid Nitrogen Nitrogen is the most common substance in Earth's _________ crust oceans atmosphere trees . In the Earth's atmosphere, nitrogen is a gas. The particles of a gas move very quickly. They run around and bounce into everyone and everything. The hotter a gas is, the _________ slower faster hotter colder the particles move. When a gas is _________ cooled warmed heated compressed , its particles slow down. If a gas is cooled enough, it can change from a gas to a liquid. For nitrogen, this happens at a very _________ strange warm low high temperature. If you want to change nitrogen from a gas to a liquid, you have to bring its temperature down to 77 Kelvin. That's 321 degrees below zero _________ Kelvin Celsius Centigrade Fahrenheit ! Liquid nitrogen looks like water, but it acts very differently. It

165

E-Print Network 3.0 - a-site cation deficiency Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Mathematics 2 Cation non-stoichiometry in yttrium-doped barium zirconate: phase behavior, microstructure, and proton conductivity Summary: -site. The alternative...

166

E-Print Network 3.0 - abts radical cation Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

abts radical cation Page: << < 1 2 3 4 5 > >> 1 2-Aminobenzothiazole degradation by free and Ca-alginate immobilized cells of Rhodococcus rhodochrous Summary: , Chisinau,...

167

Combined Utilization of Cation Exchanger and Neutral Receptor to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect (OSTI)

In this report, novel approaches to the selective liquid-liquid extraction separation of sodium hydroxide and sodium nitrate from high-level alkaline tank waste will be discussed. Sodium hydroxide can be successfully separated from alkaline tank-waste supernatants by weakly acidic lipophilic hydroxy compounds via a cation-exchange mechanism referred to as pseudo hydroxide extraction. In a multi-cycle process, as sodium hydroxide in the aqueous phase becomes depleted, it is helpful to have a neutral sodium receptor in the extraction system to exploit the high nitrate concentration in the waste solution to promote sodium removal by an ion-pair extraction process. Simultaneous utilization of an ionizable organic hydroxy compound and a neutral extractant (crown ether) in an organic phase results in the synergistic enhancement of ion exchange and improved separation selectivity due to the receptor's strong and selective sodium binding. Moreover, combination of the hydroxy compound and the crown ether provides for mutually increased solubility, even in a non-polar organic solvent. Accordingly, application of Isopar{reg_sign} L, a kerosene-like alkane solvent, becomes feasible. This investigation involves examination of such dual-mechanism extraction phases for sodium extraction from simulated and actual salt cake waste solutions. Sodium salts can be regenerated upon the contact of the loaded extraction phases with water. Finally, conditions of potential extraction/strip cycling will be discussed.

Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.

2004-03-29T23:59:59.000Z

168

Air Liquide - Biogas & Fuel Cells  

Broader source: Energy.gov (indexed) [DOE]

Liquide - Biogas & Fuel Cells Hydrogen Energy Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry,...

169

Sandia National Laboratories: ionic liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquid Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks On February 26, 2013, in Biofuels, Biomass, Energy,...

170

Liquid sampling system  

DOE Patents [OSTI]

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

Larson, L.L.

1984-09-17T23:59:59.000Z

171

Liquid sampling system  

DOE Patents [OSTI]

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

Larson, Loren L. (Idaho Falls, ID)

1987-01-01T23:59:59.000Z

172

Geothermometry At Long Valley Caldera Geothermal Area (Mariner...  

Open Energy Info (EERE)

California Michael L. Sorey, Gene A. Suemnicht, Neil C. Sturchio, Gregg A. Nordquist (December 1991) New Evidence On The Hydrothermal System In Long Valley Caldera, California,...

173

Geothermometry At Long Valley Caldera Geothermal Area (Farrar...  

Open Energy Info (EERE)

each water sample were measured in the field within minutes following collection. Field processing of water samples was conducted in accordance with standard USGS protocols...

174

Geothermometry At Long Valley Caldera Geothermal Area (Sorey...  

Open Energy Info (EERE)

studies, and seem to prove useful in most cases (Flexser, 1991; Goff et al., 1991; Smith and Suemnicht, 1991). Results from these studies are also summarized in Sorey et al....

175

Geothermometry At Roosevelt Hot Springs Geothermal Area (Ward...  

Open Energy Info (EERE)

Area. References S. H. Ward, W. T. Parry, W. P. Nash, W. R. Sill, K. L. Cook, R. B. Smith, D. S. Chapman, F. H. Brown, J. A. Whelan, J. R. Bowman (1978) A Summary of the...

176

Geothermometry At Lassen Volcanic National Park Area (Thompson...  

Open Energy Info (EERE)

Usefulness not indicated DOE-funding Unknown References J. Michael Thompson (1985) Chemistry Of Thermal And Nonthermal Springs In The Vicinity Of Lassen Volcanic National Park...

177

Isotope Geothermometry At Lightning Dock Geothermal Area (Witcher...  

Open Energy Info (EERE)

Number DE-FC07-00AL66977 Notes This project deepened a well and took 4 samples from wells around the Lightning Docks KGRA and performed extensive chamical and isotope analysis...

178

Geothermometry At Mt St Helens Area (Shevenell & Goff, 1995)...  

Open Energy Info (EERE)

Fraser Goff (1995) Evolution Of Hydrothermal Waters At Mount St Helens, Washington, Usa Additional References Retrieved from "http:en.openei.orgwindex.php?titleGeothermom...

179

Liquid-level detector  

DOE Patents [OSTI]

Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

Not Available

1981-01-29T23:59:59.000Z

180

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

ENERGY COMMISSION APPL.lCATION FOR SOURCE MATERIAL LICENSE  

Office of Legacy Management (LM)

COMMISSION COMMISSION APPL.lCATION FOR SOURCE MATERIAL LICENSE Pursuant to the rcgu!ations in Title 10, Code of Federal Regulations, Chapter 1, Part 40, application is hereby made for a license to receive, possess, use, transfer, deliver or import into the United Stat-, source material for the activity or activities described. 1. (check ooa) 2. NAME OF APPLICANT W. R. GRACE 6 Co. 0 (a) New Iicense 0 (b) Amendment to License No.- Davison Chemical Division STA-422 3. Q (c) Renewal of Licensr No. 0 (d) Previous License No. Pompton Plains, N. J. 4. ST,.TE THE AOORESS(ES) AT WHICH SOURCE MATERIAL WILL BE POSSESSED OR USED 868 Black Oak Ridge Road, Wayne, fi. J. a*ocY s up/'l File IF 5. BUSINESS OR OCCUPATION I 6. (a) IF APPLICANT IS AN INDIVIDUAL. STATE CITIZENSHIP

182

Lithium-cation conductivity and crystal structure of lithium diphosphate  

SciTech Connect (OSTI)

The electrical conductivity of lithium diphosphate Li{sub 4}P{sub 2}O{sub 7} has been measured and jump-like increasing of ionic conductivity at 913 K has been found. The crystal structure of Li{sub 4}P{sub 2}O{sub 7} has been refined using high temperature neutron diffraction at 3001050 K. At 913 K low temperature triclinic form of Li{sub 4}P{sub 2}O{sub 7} transforms into high temperature monoclinic one, space group P2{sub 1}/n, a=8.8261(4) , b=5.2028(4) , c=13.3119(2) , ?=104.372(6). The migration maps of Li{sup +} cations based on experimental data implemented into program package TOPOS have been explored. It was found that lithium cations in both low- and high temperature forms of Li{sub 4}P{sub 2}O{sub 7} migrate in three dimensions. Cross sections of the migrations channels extend as the temperature rises, but at the phase transition point have a sharp growth showing a strong crystal structure ion conductivity correlation. -- Graphical abstract: Crystal structure of Li{sub 4}P{sub 2}O{sub 7} at 950 K. Red balls represent oxygen atoms; black lines show Li{sup +} ion migration channels in the layers perpendicular to [001] direction. Highlights: Structure of Li{sub 4}P{sub 2}O{sub 7} has been refined using high temperature neutron diffraction. At 913 K triclinic form of Li{sub 4}P{sub 2}O{sub 7} transforms into high temperature monoclinic one. The migration maps of Li{sup +} implemented into program package TOPOS have been explored. Cross sections of the migrations channels at the phase transition have a sharp growth.

Voronin, V.I., E-mail: voronin@imp.uran.ru [Institute of Metal Physics Urals Branch RAS, S.Kovalevskoy Street 18, 620041 Ekaterinburg (Russian Federation); Sherstobitova, E.A. [Institute of Metal Physics Urals Branch RAS, S.Kovalevskoy Street 18, 620041 Ekaterinburg (Russian Federation); Blatov, V.A., E-mail: blatov@samsu.ru [Samara Center for Theoretical Materials Science (SCTMS), Samara State University, Ac.Pavlov Street 1, 443011 Samara (Russian Federation); Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia); Shekhtman, G.Sh., E-mail: shekhtman@ihte.uran.ru [Institute of High Temperature Electrochemistry Urals Branch RAS, Akademicheskaya 20, 620990 Ekaterinburg (Russian Federation)

2014-03-15T23:59:59.000Z

183

Renewable Liquid Fuels Reforming  

Broader source: Energy.gov [DOE]

The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used in the mid- and long-term time frames.

184

Re ning Abstract Machine Speci cations of the Steam Boiler Control to Well Documented  

E-Print Network [OSTI]

Re ning Abstract Machine Speci cations of the Steam Boiler Control to Well Documented Executable the steam boiler control speci cation problem to il- lustrate how the evolving algebra approach to the speci, in June 1995, to control the Karlsruhe steam boiler simulator satisfactorily. The abstract machines

Börger, Egon

185

Veri cation Techniques for LOTOS U. Martin, University of St. Andrews, Scotland, U.K.  

E-Print Network [OSTI]

to safety-critical case studies, determined the veri cation needs of real life applications, and developed of the veri cation and validation requirements which were considered in the project. Software de- velopment in safety-critical application areas in collab- oration with researchers from end user organisations

Calder, Muffy

186

Gas-phase ion/ion reactions of transition metal complex cations with multiply charged oligodeoxynucleotide anions  

Science Journals Connector (OSTI)

Multiply deprotonated hexadeoxyadenylate anions, (A6?nH)n?, where n...=35, have been subjected to reaction with a range of divalent transition-metal complex cations in the gas phase. The cations studied included...

Christopher K. Barlow; Brittany D. M. Hodges

2008-02-01T23:59:59.000Z

187

Logic Based Approaches to Work ow Modeling and Veri cation 1 Saikat Mukherjee, Hasan Davulcu, Michael Kifer, Pinar Senkul,  

E-Print Network [OSTI]

Contents Logic Based Approaches to Work ow Modeling and Veri#12;cation 1 Saikat Mukherjee, Hasan : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 37 #12; #12; Logic-Based Approaches to Work ow Modeling and Veri#12;cation Saikat Mukherjee, 1 Hasan

Yang, Guizhen

188

Exploratory Studies on Reactions of Cobaloxime ?-Cations with C-Nucleophiles:? Irreversible Alkene Decomplexation versus Nucleophilic Capture  

Science Journals Connector (OSTI)

(?-Hydroxyalkyl)- and (?-acetoxyalkyl)cobaloximes can undergo facile acid-catalyzed ?-heteroatom exchange with oxygen and nitrogen nucleophiles in an SN1-like mechanism via cationic metal?alkene ?-complex intermediates (cobaloxime ?-cations). The reaction ...

Jennifer L. Gage; Bruce P. Branchaud

1996-02-09T23:59:59.000Z

189

Frostbite Theater - Liquid Nitrogen Experiments - Dry Ice vs. Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Egg + Liquid Nitrogen + Time-lapse! Egg + Liquid Nitrogen + Time-lapse! Previous Video (Egg + Liquid Nitrogen + Time-lapse!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Cooled Dry Ice in Water!) Liquid Nitrogen Cooled Dry Ice in Water! Dry Ice vs. Liquid Nitrogen! Dry ice is cold. Liquid nitrogen is cold, too. What happens when the two are mixed together? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Have you ever wondered what happens when you mix dry ice and liquid nitrogen? Steve: Well, we just happen to have a chunk of dry ice left over from when we filmed 'How to Make a Cloud Chamber,' and here at Jefferson Lab, liquid nitrogen flows like water, so we're going to find out!

190

Pinning lattice: Effect of rhenium doping on the microstructural evolution from Tl-2212 to Hg-1212 films during cation exchange  

E-Print Network [OSTI]

In a cation exchange process developed recently by some of us, epitaxial HgBa2CaCu2O6 films can be obtained by diffusing volatile Tl cations out of, and simultaneously diffusing Hg cations into, the crystalline lattice of ...

Wu, Judy; Zhao, H.

2004-08-15T23:59:59.000Z

191

Cation disorder in high dose neutron irradiated spinel  

SciTech Connect (OSTI)

The crystal structures of MgAl{sub 2}O{sub 4} spinel single crystals irradiated to high neutron fluences (>5{center_dot}10{sup 26} n/m{sup 2} (E{sub n}>0.1 MeV)), were examined by neutron diffraction. Crystal structure refinement of the highest dose sample indicated that the average scattering strength of the tetrahedral crystal sites decreased by {approximately}20% while increasing by {approximately}8% on octahedral sites. Since the neutron scattering length for Mg is considerably larger than for Al, this result is consistent with site exchange between Mg{sup 2+} ions on tetrahedral sites and Al{sup 3+} ions on octahedral sites. Least squares refinements also indicated that in all irradiated samples, at least 35% of Mg{sup 2+} and Al{sup 3+} ions in the crystal experienced disordering replacements. This retained dpa on the cation sublattices is the largest retained damage ever measured in an irradiated spinel material.

Sickafus, K.E.; Larson, A.C.; Yu, N.; Nastasi, M. [Los Alamos National Lab., NM (United States); Hollenberg, G.W.; Garner, F.A. [Pacific Northwest Lab., Richland, WA (United States); Bradt, R.C. [Univ. of Nevada, Reno, NV (United States)

1994-06-01T23:59:59.000Z

192

Cation disorder in high-dose, neutron-irradiated spinel  

SciTech Connect (OSTI)

The objective of this effort is to determine whether MgAl{sub 2}O{sub 4} spinel is a suitable ceramic for fusion applications. Here, the crystal structures of MgAl{sub 2}O{sub 4} spinel single crystals irradiated to high neutron fluences [>5{center_dot}10{sup 26} n/m{sup 2} (E{sub n} > 0.1 MeV)] were examined by neutron diffraction. Crystal structure refinement of the highest dose sample indicated that the average scattering strength of the tetrahedral crystal sites decreased by {approximately} 20% while increasing by {approximately} 8% on octahedral sites. Since the neutron scattering length for Mg is considerably larger than for Al, this results is consistent with site exchange between Mg{sup 2+} ions on tetrahedral sites and Al{sup 3+} ions on octahedral sites. Least-squares refinements also indicated that, in all irradiated samples, at least 35% of Mg{sup 2+} and Al{sup 3+} ions in the crystal experienced disordering replacements. This retained dpa on the cation sublattices is the largest retained damage ever measured in an irradiated spinel material.

Sickafus, K.E.; Larson, A.C.; Yu, N.; Nastasi, M. [Los Alamos National Lab., NM (United States); Hollenberg, G.W.; Garner, F.A. [Pacific Northwest Lab., Richland, WA (United States); Bradt, R.C. [Univ. of Nevada, Reno, NV (United States)

1994-08-01T23:59:59.000Z

193

Adsorption of Ethylene on Neutral, Anionic and Cationic Gold Clusters  

E-Print Network [OSTI]

The adsorption of ethylene molecule on neutral, anionic and cationic gold clusters consisting of up to 10 atoms has been investigated using density-functional theory. It is demonstrated that C2H4 can be adsorbed on small gold clusters in two different configurations, corresponding to the pi- and di-sigma-bonded species. Adsorption in the pi-bonded mode dominates over the di-sigma mode over all considered cluster sizes n, with the exception of the neutral C2H4-Au5 system. A striking difference is found in the size-dependence of the adsorption energy of C2H4 bonded to the neutral gold clusters in the pi and di-sigma configurations. The important role of the electronic shell effects in the di-sigma mode of ethylene adsorption on neutral gold clusters is demonstrated. It is shown that the interaction of C2H4 with small gold clusters strongly depends on their charge. The typical shift in the vibrational frequencies of C2H4 adsorbed in the pi- and the di-sigma configurations gives a guidance to experimentally disti...

Lyalin, Andrey

2009-01-01T23:59:59.000Z

194

Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy of liquid microjets  

E-Print Network [OSTI]

sodium acetate, and lithium acetate revealing distinctpotassium, and lithium with acetate and formate anions informate and acetate solutions containing lithium, sodium,

Uejio, Janel S.

2008-01-01T23:59:59.000Z

195

Liquid Scintillator Purification  

SciTech Connect (OSTI)

The KamLAND collaboration has studied background requirements and purification methods needed to observe the 7Be neutrino from the sun. First we will discuss the present background situation in KamLAND where it is found that the main background components are 210Pb and 85Kr. It is then described how to purify the liquid scintillator. The present status and results on how to remove 210Pb from the liquid scintillator are discussed. Specifically, the detailed analysis of the effects of distillation and adsorption techniques are presented.

Kishimoto, Y. [Research Center for Neutrino Science, Tohoku University (Japan)

2005-09-08T23:59:59.000Z

196

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process  

SciTech Connect (OSTI)

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16T23:59:59.000Z

197

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen in a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freeze Liquid Nitrogen! Freeze Liquid Nitrogen! Previous Video (Let's Freeze Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Freeze the Rainbow!) Freeze the Rainbow! Liquid Nitrogen in a Microwave! What happens when the world's most beloved cryogenic liquid meets one of the most common household appliances? Find out when we try to microwave liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A little while ago we received an email from Star of the Sea Catholic School in Virginia Beach, Virginia, asking what happens when you place liquid nitrogen in a microwave. Well, I just happen to have some liquid nitrogen! Steve: And I just happen to have a microwave!

198

Lyophilic liquid porosimetry and a new liquid autoporosimeter  

SciTech Connect (OSTI)

Lyophilic liquid porosimetry determines the volumes of different size pores by measuring the amount of liquid in these pores, thus, providing pore volume distribution (PVD) data for porous structures. Any liquid that wets the sample may be used. This opens unique opportunities for porous structure evaluation. It provides realistic PVD analysis when the liquid of interest changes the porous structure. It determines uptake/drainage hysteresis of real liquids. It allows direct measurements of uptake and retention capillary pressures with different amounts of liquid in a sample. Lyophilic liquid porosimetry determines liquid/solid contact angles of different size pores within the sample. It can also be used for PVD analysis of both soft, brittle materials and porous metal materials.

Tyomkin, I. [TRI/Princeton, NJ (United States)

1998-12-31T23:59:59.000Z

199

Influence of liquid structure on diffusive isotope separation in molten silicates and aqueous solutions  

SciTech Connect (OSTI)

Molecular diffusion in natural volcanic liquids discriminates between isotopes of major ions (e.g., Fe, Mg, Ca, and Li). Although isotope separation by diffusion is expected on theoretical grounds, the dependence on mass is highly variable for different elements and in different media. Silicate liquid diffusion experiments using simple liquid compositions were carried out to further probe the compositional dependence of diffusive isotopic discrimination and its relationship to liquid structure. Two diffusion couples consisting of the mineral constituents anorthite (CaAl{sub 2}Si{sub 2}O{sub 8}; denoted AN), albite (NaAlSi{sub 3}O{sub 8}; denoted AB), and diopside (CaMgSi{sub 2}O{sub 6}; denoted DI) were held at 1450C for 2 h and then quenched to ambient pressure and temperature. Major-element as well as Ca and Mg isotope profiles were measured on the recovered quenched glasses. In both experiments, Ca diffuses rapidly with respect to Si. In the ABAN experiment, D{sub Ca}/D{sub Si} ~ 20 and the efficiency of isotope separation for Ca is much greater than in natural liquid experiments where D{sub Ca}/D{sub Si} ~ 1. In the ABDI experiment, D{sub Ca}/D{sub Si} ~ 6 and the efficiency of isotope separation is between that of the natural liquid experiments and the ABAN experiment. In the ABDI experiment, D{sub Mg}/D{sub Si} ~ 1 and the efficiency of isotope separation for Mg is smaller than it is for Ca yet similar to that observed for Mg in natural liquids. The results from the experiments reported here, in combination with results from natural volcanic liquids, show clearly that the efficiency of diffusive separation of Ca isotopes is systematically related to the solvent-normalized diffusivitythe ratio of the diffusivity of the cation (D{sub Ca}) to the diffusivity of silicon (D{sub Si}). The results on Ca isotopes are consistent with available data on Fe, Li, and Mg isotopes in silicate liquids, when considered in terms of the parameter D{sub cation}/D{sub Si}. Cations diffusing in aqueous solutions display a similar relationship between isotopic separation efficiency and D{sub cation} =D{sub H 2 O} , although the efficiencies are smaller than in silicate liquids. Our empirical relationship provides a tool for predicting the magnitude of diffusive isotopic effects in many geologic environments and a basis for a more comprehensive theory of isotope separation in liquid solutions. We present a conceptual model for the relationship between diffusivity and liquid structure that is consistent with available data.

Watkins, J.M.; DePaolo, D.J.; Ryerson, F.J.; Peterson, B.

2011-03-01T23:59:59.000Z

200

Viscosity of Liquids  

Science Journals Connector (OSTI)

6 November 1952 research-article Viscosity of Liquids E. N. da C. Andrade The Royal Society is collaborating with JSTOR to digitize, preserve, and extend access to Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences. www.jstor.org

1952-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

The Viscosity of Liquids  

Science Journals Connector (OSTI)

... of momentum between them. In the case of a gas, Maxwell showed how the viscosity can be derived by considering this momentum as being communicated by molecules transferring themselves bodily ... fulfilment of the conditions postulated in Maxwell's treatment, and the fact that while gas viscosity goes up with temperature liquid ...

E. N. DA C. ANDRADE

1930-04-12T23:59:59.000Z

202

Detonation in Liquid Explosives  

Science Journals Connector (OSTI)

... Laboratory, on the initiative of Dr. A. H. Davis, into the process of detonation in explosives, the programme including a photographic study of the ... in explosives, the programme including a photographic study of the detonation Waves in transparent liquid explosivesthe sensitivity of some of which can be varied by ...

D. CRONEY

1948-09-25T23:59:59.000Z

203

Liquid Natural Gas  

Science Journals Connector (OSTI)

Liquid Natural Gas ... IN A new technique for storing natural gas at the East Ohio Gas Co. plant, Cleveland, Ohio, the gas is liquefied before passing to the gas holders. ... Natural gas contains moisture and carbon dioxide, both of which liquefy before the natural gas and are somewhat of a nuisance because upon solidification they clog the pipes. ...

W. F. SCHAPHORST

1941-04-25T23:59:59.000Z

204

Factors Affecting the Fragmentation of Peptide Ions: Metal Cationization and Fragmentation Timescale  

E-Print Network [OSTI]

The factors affecting peptide fragmentation have been extensively studied in the literature in order to better predict the fragment ion spectra of peptides and proteins. While there are countless influences to consider, metal cation binding...

Kmiec, Kevin

2012-10-19T23:59:59.000Z

205

Synthesis and Evaluation of a New Cationic Surfactant for Oil-Well Drilling Fluid  

Science Journals Connector (OSTI)

A new additive cationic surfactant for drilling fluid was synthesized by alkylation of coal ... results when utilized in the formulation of both oil-based mud and synthetic-based mud as...

Soad A. Mahmoud; Mona M. Dardir

2011-01-01T23:59:59.000Z

206

Synthesis and Properties of Novel Cationic, Temperature-Sensitive Block-Copolymers  

E-Print Network [OSTI]

Facile, one-step synthesis of self-assembling, cationic block copolymers of poly(2-N-(dimethylaminoethyl) methacrylate) (pDMAEMA) and PEO-PPO-PEO (Pluronic) is developed. The copolymers are obtained via free-radical ...

Deshmukh, Smeet

207

The effect of trivalent cations on the major lower mantle silicates  

E-Print Network [OSTI]

I have investigated the effect of composition, especially ferric iron and aluminum, on the equations of state and phase stability of perovskite and post-perovskite. The presence of trivalent cations decreases the bulk ...

Catalli, Krystle Carina

2011-01-01T23:59:59.000Z

208

Cation exchange at the secondary building units of metalorganic frameworks  

E-Print Network [OSTI]

Cation exchange is an emerging synthetic route for modifying the secondary building units (SBUs) of metalorganic frameworks (MOFs). This technique has been used extensively to enhance the properties of nanocrystals and ...

Brozek, Carl Kavanaugh

209

A Reduction for Automated Veri cation of Authentication Scott D. Stoller  

E-Print Network [OSTI]

A Reduction for Automated Veri cation of Authentication Protocols Scott D. Stoller Computer Science of those case studies were not rigorously justi ed. Reduction theorems are needed, which show

Stoller, Scott

210

Adsorption and viscoelastic properties of cationic xylan on cellulose film using QCM-D  

Science Journals Connector (OSTI)

The adsorption and viscoelastic properties of cationic xylan layers adsorbed from an aqueous electrolyte solution ... 10, 100mM) on a cellulose model surface were studied using quartz crystal microbalance with ....

Sang Hoon Lee; Hak Lae Lee; Hye Jung Youn

2014-06-01T23:59:59.000Z

211

Mucoadhesive Sustained Drug Delivery System Based on Cationic Polymer and Anionic Cyclodextrin/Triclosan Complex  

Science Journals Connector (OSTI)

In this study the interactions between a cationic polymer and an anionic cyclodextrin were investigated. The system has the potential for use in a sustained release dosage forms for use on mucous membranes. As mu...

Hakon H. Sigurdsson; Elin Knudsen

2002-12-01T23:59:59.000Z

212

Determining the Mechanisms of Cationic Contamination Affecting PEMFCs Using a Strip Cell Configuration  

SciTech Connect (OSTI)

Cationic contamination of polymer electrolyte fuel cells has been shown to cause serious performance degradation but the exact mechanisms of this degradation are not fully understood. A strip cell configuration was devised to study the mechanisms of performance degradation due to cationic contamination by changing the time and length scales of traditional fuel cells while providing a suitable reference electrode. This 'strip cell' configuration utilizes traditional Nafion{reg_sign} membranes in an in-plane configuration with electrodes painted on each end. Using this cell it was determined that cationic contaminants collect near the cathode of the fuel cell under load and that this profile leads to increased losses primarily in the cathode region. These results can be directly related to performance losses in a typical PEMFC contaminated by foreign cations.

Kienitz, B. L.; Zawodzinski, T. A.; Pivovar, B. S.; Garzon, F. H.

2008-01-01T23:59:59.000Z

213

Relationships between Structure and Alkaline Stability of Imidazolium Cations for Fuel Cell Membrane Applications  

Science Journals Connector (OSTI)

Relationships between Structure and Alkaline Stability of Imidazolium Cations for Fuel Cell Membrane Applications ... Samuel C. Price *, Kristen S. Williams , and Frederick L. Beyer ... membranes (fueled with H or MeOH) and also to identify candidate alk. ...

Samuel C. Price; Kristen S. Williams; Frederick L. Beyer

2014-01-16T23:59:59.000Z

214

NMR Studies of Heat-Induced Transitions in Structure and Cation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Structure and Cation Binding Environments of a Strontium-Saturated Swelling Mica. Abstract: In this work we combined Al, Si, F, and Na magic-angle spinning (MAS) nuclear...

215

Effect of cosolvent NMP on properties of cationic fluorocarbon emulsifier-free emulsion  

Science Journals Connector (OSTI)

In order to supplement the general way of preparing CFE, this paper was dedicated to a novel ... methodthe cationic fluorocarbon emulsifier-free emulsion (CFE)an organic cosolvent method, which is...12]. Genera...

Chen Wang; Xiaorui Li; Peizhi Li

2013-05-01T23:59:59.000Z

216

Air Liquide- Biogas & Fuel Cells  

Broader source: Energy.gov [DOE]

Presentation about Air Liquide's biogas technologies and integration with fuel cells. Presented by Charlie Anderson, Air Liquide, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

217

The temperature dependence of diffusion for several electroactive cations in nafion films at electrode surfaces  

E-Print Network [OSTI]

that the ratio n+ (n-1)+ D /D can be used to indicate the types of interactions app app occuring between the electroactive cation and the Nafion matrix (hydrophobic or hydrophilic interactions). +3 + 2 Activation Parameters for Charge Transfer of Ruf... that the ratio n+ (n-1)+ D /D can be used to indicate the types of interactions app app occuring between the electroactive cation and the Nafion matrix (hydrophobic or hydrophilic interactions). +3 + 2 Activation Parameters for Charge Transfer of Ruf...

Dollard, Kathleen

2012-06-07T23:59:59.000Z

218

Interactions between acidic polysaccharides and trivalent cations: their effect on intestinal dietary cholesterol absorption  

E-Print Network [OSTI]

INTERACTIONS BETHEL? ACIDIC POLYSACCHARIDES AND TRIVALPKT CATIONS) THEIR EFFECT ON INTVSTINAL DIETARY CHOLESTEROL ABSORPTION A Thesis Elizabeth Louise Bradbury Submitted to the Graduate College of' Texas AAM University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1978 Eager Subgeotz Biochemistry &TERACTIONS BETWEEN ACIDIC POLYSACCHARIDES AND TRIVALENT CATIONS t THEIR EFFECT ON INTESTINAL DIETARY CHOLESTEROL kM~ORPTION A Thesis Elisabeth louise Bradbury...

Bradbury, Elizabeth Louise

2012-06-07T23:59:59.000Z

219

Liquid metal thermal electric converter  

DOE Patents [OSTI]

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

220

High temperature liquid level sensor  

DOE Patents [OSTI]

A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

Tokarz, Richard D. (West Richland, WA)

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Adsorption and desorption kinetics of cesium in an organic matter-rich soil saturated with different cations  

SciTech Connect (OSTI)

The fallout from nuclear weapons tests conducted on Bikini Atoll Island in 1954 resulted in contamination of soil with Cesium 137. To develop effective regimes for decontaminating the Bikini Atoll soil, the exchange of Cs for K, Na, and other cations on the soil must be understood. Samples of soils made homoionic with K, Na, or Ca were reacted with solutions containing Cs ions, and the quantities of Cs sorbed and the rates of exchange were measured. The samples were then reacted with solutions containing K, Na, or Ca, and the quantities of Cs desorbed and the rates of exchange were again measured. Samples made homoionic with Na had a greater ion exchange capacity than samples made homoionic with K, and, in both cases, the ion exchange capacity increased with the organic matter content of the soil. For samples pretreated with Ca, the ion exchange capacity is not related in a simple way to the organic matter content. The kinetics were assessed by plotting the rate of exchange vs. the time and vs. the quantity exchanged. A first-order equation was obeyed during most of the run in Cs desorption experiments and during a limited part of the run in Cs adsorption experiments. An increase in the rate of Cs exchange was observed at the beginning of the experiments especially for Cs adsorption. This increase is presumably due to an increase of the ionic strength of the liquid phase during the exchange process. 33 refs., 9 figs., 2 tabs.

Aharoni, C. (Technion-Israel Inst. of Technology, Haifa (Israel)); Pasricha, N.S. (Punjab Agricultural Univ., Ludihana (India)); Sparks, D.L. (Univ. of Delaware, Newark, DE (United States))

1993-10-01T23:59:59.000Z

222

Ion Distributions Near a Liquid-Liquid Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ion Distributions Near a Liquid-Liquid Interface Ion Distributions Near a Liquid-Liquid Interface Researchers from the University of Illinois at Chicago; Northern Illinois University; the University of California, Santa Cruz; and ChemMatCARS (sector 15 at the APS) used x-ray reflectivity from ion distributions at the liquid-liquid interface to provide strong evidence that the interfacial structure of a liquid alters the ion distributions near a charged interface, contrary to earlier theories about ions at charged surfaces. Coulomb's Law describes the interaction between two, otherwise isolated, point charges. If many charges are present in the region between these two charges, the net interaction between them is modified. This is commonly found in real systems, such as a plasma gas of electrons and ionized

223

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freeze the Rainbow! Freeze the Rainbow! Previous Video (Freeze the Rainbow!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Fire!) Liquid Nitrogen and Fire! Liquid Nitrogen and Antifreeze! What happens when the freezing power of liquid nitrogen meets the antifreezing power of ethylene glycol? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: What happens when the freezing power of liquid nitrogen... Steve: ...meets the antifreezing power of ethylene glycol! Joanna: While a mix of 70 percent ethylene glycol and 30 percent water doesn't freeze until 60 degrees below zero, it's still no match for liquid nitrogen. At 321 degrees below zero, liquid nitrogen easily freezes

224

Frostbite Theater - Liquid Nitrogen Experiments - Let's Freeze Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Shattering Pennies! Shattering Pennies! Previous Video (Shattering Pennies!) Frostbite Theater Main Index Next Video (Liquid Nitrogen in a Microwave!) Liquid Nitrogen in a Microwave! Let's Freeze Liquid Nitrogen! By removing the hottest molecules, we're able to freeze liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Today, we're going to freeze liquid nitrogen! Joanna and Steve: Yeah! Joanna: The obvious way to do this is to put the liquid nitrogen into something colder. Something that we have lots of around here! Something like... liquid helium! Steve: Yes! Joanna: Yeah, but we're not going to do that. Instead, we're going to freeze the nitrogen by removing the hottest molecules!

225

Interfacial Ionic Liquids: Connecting Static and Dynamic Structures  

E-Print Network [OSTI]

It is well-known that room temperature ionic liquids (RTILs) often adopt a charge-separated layered structure, i.e., with alternating cation- and anion-rich layers, at electrified interfaces. However, the dynamic response of the layered structure to temporal variations in applied potential is not well understood. We used in situ, real-time X-ray reflectivity (XR) to study the potential-dependent electric double layer (EDL) structure of an imidazolium-based RTIL on charged epitaxial graphene during potential cycling as a function of temperature. The results suggest that the graphene-RTIL interfacial structure is bistable in which the EDL structure at any intermediate potential can be described by the combination of two extreme-potential structures whose proportions vary depending on the polarity and magnitude of the applied potential. This picture is supported by the EDL structures obtained by fully atomistic molecular dynamics (MD) simulations at various static potentials. The potential-driven transition between the two structures is characterized by an increasing width but with an approximately fixed hysteresis magnitude as a function of temperature. The results are consistent with the coexistence of distinct anion and cation adsorbed structures separated by an energy barrier (~0.15 eV).

Ahmet Uysal; Hua Zhou; Guang Feng; Sang Soo Lee; Song Li; Peter T. Cummings; Pasquale F. Fulvio; Sheng Dai; John K. McDonough; Yury Gogotsi; Paul Fenter

2014-12-06T23:59:59.000Z

226

Determinants of Hospital's Financial Liquidity  

Science Journals Connector (OSTI)

Abstract The purpose of the articles is to identify key factors that may affect the level of hospital's liquidity ratio. Weve posed four research hypotheses, assuming that, the level of financial liquidity in hospitals depends on several factors (number of beds, annual income per bed, profitability ratios, debt ratio). Weve found that: 1) there is a positive relationship between debt ratio and liquidity and profitability ratio and liquidity 2) the relationship between the size of the hospital and the financial liquidity is not statistically significant. In the study weve use statistical tools: Pearson's correlation coefficient, T-Student's test with Cohran-Cox's correction.

Agnieszka Bem; Katarzyna Pr?dkiewicz; Pawe? Pr?dkiewicz; Paulina Ucieklak-Je?

2014-01-01T23:59:59.000Z

227

Quantal Ising Liquid  

Science Journals Connector (OSTI)

An example is presented of a model of an amorphous quantum mechanical system, a liquid of quantal Ising spins, which can be solved exactly within certain many-body theories. Analytical solutions of the model in mean-field theory are shown to reveal a decrease in the extent of the ferromagnetic region (compared to an equivalent classical system) and the occurrence of some degree of quantum localization. Both phenomena are analyzed as a competition between quantum mechanics and the condensed phase.

Richard M. Stratt

1984-10-01T23:59:59.000Z

228

RHIC The Perfect Liquid  

ScienceCinema (OSTI)

Evidence to date suggests that gold-gold collisions the Relativistic Heavy Ion Collider at Brookhaven are indeed creating a new state of hot, dense matter, but one quite different and even more remarkable than had been predicted. Instead of behaving like a gas of free quarks and gluons, as was expected, the matter created in RHIC's heavy ion collisions appears to be more like a "perfect" liquid.

BNL

2009-09-01T23:59:59.000Z

229

Theory of fermion liquids  

Science Journals Connector (OSTI)

We develop a general theory of fermion liquids in spatial dimensions greater than 1. The principal method, bosonization, is applied to the cases of short- and long-range longitudinal interactions and to transverse gauge interactions. All the correlation funtions of the system may be obtained with the use of a generating functional. Short-range and Coulomb interactions do not destroy the Landau-Fermi fixed point. Non-Fermi liquid fixed points are found, however, in the cases of a super-long-range longitudinal interaction in two dimensions and transverse gauge interactions in two and three spatial dimensions. We consider in some detail the (2+1)-dimensional problem of a Chern-Simons gauge action combined with a longitudinal two-body interaction V(q)??q?y-1, which controls the density, and hence gauge, fluctuations. For y0 the interaction is relevant and the fixed point cannot be accessed by bosonization. Of special importance is the case y=0 (Coulomb interaction), which describes the Halperin-Lee-Read theory of the half-filled Landau level. We obtain the full quasiparticle propagator, which is of a marginal Fermi-liquid form. Using Ward identities, we show that neither the inclusion of nonlinear terms in the fermion dispersion nor vertex corrections alters our results: the fixed point is accessible by bosonization. As the two-point fermion Greens function is not gauge invariant, we also invetigate the gauge-invariant density response function. Near momentum Q=2kF, in addition to the Kohn anomaly we find other nonanalytic behavior. In the appendies we present a numerical calculation of the spectral function for a Fermi liquid with Landau parameter f0?0. We also show how Kohns theorem is satisfied within the bosonization framework.

H.-J. Kwon; A. Houghton; J. B. Marston

1995-09-15T23:59:59.000Z

230

What constitutes a simple liquid?  

E-Print Network [OSTI]

Simple liquids are traditionally defined as many-body systems of classical particles interacting via radially symmetric pair potentials. We suggest that a simple liquid should be defined instead by the property of having strong correlation between virial and potential energy equilibrium fluctuations in the NVT ensemble. There is considerable overlap between the two definitions, but also some notable differences. For instance, in the new definition simplicity is not a property of the intermolecular potential only because a liquid is usually only strongly correlating in part of its phase diagram. Moreover, according to the new definition not all simple liquids are atomic (i.e., with radially symmetric pair potentials) and not all atomic liquids are simple. The main part of the paper motivates the new definition of liquid simplicity by presenting evidence that a liquid is strongly correlating if and only if its intermolecular interactions may be ignored beyond the first coordination shell (FCS). This is demonstrated by NVT simulations of structure and dynamics of 15 atomic and molecular model liquids with a shifted-forces cutoff placed at the first minimum of the radial distribution function. No proof is given that the chemical characterization follows from the strong correlation property, but it is shown to be consistent with the existence of isomorphs in strongly correlating liquids' phase diagram. Finally, we note that the FCS characterization of simple liquids calls into question the basis for standard perturbation theory, according to which the repulsive and attractive forces play fundamentally different roles for the physics of liquids.

Trond S. Ingebrigtsen; Thomas B. Schrder; Jeppe C. Dyre

2011-11-15T23:59:59.000Z

231

Liquid fossil fuel technology  

SciTech Connect (OSTI)

Progress reports are presented under the following headings: (1) extraction (technology assessment, oil research, gas research); (2) liquid processing (characterization, thermodynamics, processing technology); (3) utilization (energy conservation); and (4) project integration and technology transfer. BETC publications are also listed. Some of the highlights for this period are: the Bartlesville Energy Technology Center was converted into NIPER, the National Institute for Petroleum and Energy Research on October 1, 1983; modelling of enthalpies, heat capacities and volumes of aqueous surfactant solutions began using a mass action model; a series of experiments were run on upgrading by hydrogenation SRC-II coal liquid at different degrees of severity and the products have been analyzed; heavy crude oil extracts were separated into fraction with high performance liquid chromatography by Lawrence Berkeley Laboratory and the mass spectra and electron spin resonance were determin ed; and particulates from exhaust gases of diesel engines using fire fuel types are being collected and will be analyzed by chemical methods and results will be compared with those obtained by biological assay. (ATT)

Not Available

1983-01-01T23:59:59.000Z

232

Uranyl coordination environment in hydrophobic ionic liquids : an in situ investigation.  

SciTech Connect (OSTI)

Different inner-sphere coordination environments are observed for the uranyl nitrate complexes formed with octyl-phenyl-N,N-diisobutylcarbamoylmethylphosphine oxide and tributyl phosphate in dodecane and in the hydrophobic ionic liquids (ILs) [C{sub 4}mim][PF{sub 6}] and [C{sub 8}mim][N(SO{sub 2}CF{sub 3}){sub 2}]. Qualitative differences in the coordination environment of the extracted uranyl species are implied by changes in peak intensity patterns and locations for uranyl UV-visible spectral bands when the solvent is changed. EXAFS data for uranyl complexes in dodecane solutions is consistent with hexagonal bipyramidal coordination and the existence of UO{sub 2}(NO{sub 3}){sub 2}(CMPO){sub 2}. In contrast, the complexes formed when uranyl is transferred from aqueous nitric acid solutions into the ILs exhibit an average equatorial coordination number of approximately 4.5. Liquid/liquid extraction results for uranyl in both ILs indicate a net stoichiometry of UO{sub 2}(NO{sub 3})(CMPO){sup +}. The concentration of the IL cation in the aqueous phase increases in proportion to the amount of UO{sub 2}(NO{sub 3})(CMPO){sup +} in the IL phase, supporting a predominantly cation exchange mechanism for partitioning in the IL systems.

Visser, A. E.; Jensen, M. P.; Laszak, I.; Nash, K. L.; Choppin, G. R.; Roers, R. D.; Chemistry; Univ. of Alabama; Flordia State Univ.

2003-01-01T23:59:59.000Z

233

Frostbite Theater - Liquid Nitrogen Experiments - Let's Pour Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Shattering Flowers! Shattering Flowers! Previous Video (Shattering Flowers!) Frostbite Theater Main Index Next Video (Giant Koosh Ball!) Giant Koosh Ball! Let's Pour Liquid Nitrogen on the Floor! Liquid nitrogen?! On the floor?! Who's going to clean that mess up?! See what really happens when one of the world's most beloved cryogenic liquids comes into contact with a room temperature floor. [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: From time to time, we spill a little liquid nitrogen! The reaction we sometimes get is.... Shannon: Did they just pour LIQUID NITROGEN on the FLOOR?!?! Joanna: Yes. Yes we did. Steve: One thing people seem to have a problem with is the mess that liquid

234

Colloid Facilitated Transport of Radioactive Cations in the Vadose Zone: Field Experiments Oak Ridge  

SciTech Connect (OSTI)

The overarching goal of this study was to improve understanding of colloid-facilitated transport of radioactive cations through unsaturated soils and sediments. We conducted a suite of laboratory experiments and field experiments on the vadose-zone transport of colloids, organic matter, and associated contaminants of interest to the U.S. Department of Energy (DOE). The laboratory and field experiments, together with transport modeling, were designed to accomplish the following detailed objectives: 1. Evaluation of the relative importance of inorganic colloids and organic matter to the facilitation of radioactive cation transport in the vadose zone; 2. Assessment of the role of adsorption and desorption kinetics in the facilitated transport of radioactive cations in the vadose zone; 3. Examination of the effects of rainfall and infiltration dynamics and in the facilitated transport of radioactive cations through the vadose zone; 4. Exploration of the role of soil heterogeneity and preferential flow paths (e.g., macropores) on the facilitated transport of radioactive cations in the vadose zone; 5. Development of a mathematical model of facilitated transport of contaminants in the vadose zone that accurately incorporates pore-scale and column-scale processes with the practicality of predicting transport with readily available parameters.

James E. Saiers

2012-09-20T23:59:59.000Z

235

Equilibrium Model for Ion Exchange Between Multivalent Cations and Zeolite-A in a Molten Salt  

SciTech Connect (OSTI)

A two-site equilibrium model that previously only accommodated monovalent cations has been extended to include divalent and trivalent cations for ion exchange between zeolite-A and molten chloride salts, a process being considered for concentrating nuclear fission products into high level waste forms. Equilibrium constants were determined by fitting the model to equilibrium data sets for ion exchange between zeolite-A and Cs ternary salt (CsCl-LiCl-KCl), Rb ternary salt (RbCl-LiCl-KCl), Na ternary salt (NaCl-LiCl-KCl), Sr ternary salt (SrCl2-LiCl-KCl), and U ternary salt (UCl3-LiCl-KCl). The results reveal a good fit between the experimental data sets and the model. The two ion exchange sites, framework sites and occluded sites, demonstrate different relative selectivities for the cations. It was found that Sr2_ is the preferred cation in the ion exchange site, and Cs_ is the preferred cation in the occlusion site. Meanwhile, Li_ has the highest combined selectivity when both ion exchange and occlusion sites are considered. Interestingly, divalent and trivalent species are more preferred in the ion exchange site than the monovalent species with the exception of Li_.

Supathorn Phongikaroon; Michael Simpson

2005-10-01T23:59:59.000Z

236

Radiation Chemistry of Ionic Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquids Liquids James F. Wishart, Alison M. Funston, and Tomasz Szreder in "Molten Salts XIV" Mantz, R. A., et al., Eds.; The Electrochemical Society, Pennington, NJ, (2006) pp. 802-813. [Information about the volume (look just above this link)] Abstract: Ionic liquids have potentially important applications in nuclear fuel and waste processing, energy production, improving the efficiency and safety of industrial chemical processes, and pollution prevention. Successful use of ionic liquids in radiation-filled environments will require an understanding of ionic liquid radiation chemistry. For example, characterizing the primary steps of ionic liquid radiolysis will reveal radiolytic degradation pathways and suggest ways to prevent them or mitigate their effects on the properties of the material

237

One Water Molecule Stabilizes the Cationized Arginine Matthew F. Bush, James S. Prell, Richard J. Saykally, and Evan R. Williams*  

E-Print Network [OSTI]

One Water Molecule Stabilizes the Cationized Arginine Zwitterion Matthew F. Bush, James S. Prell, Richard J. Saykally, and Evan R. Williams* Contribution from the Department of Chemistry, Uni

Cohen, Ronald C.

238

Process for preparing liquid wastes  

DOE Patents [OSTI]

A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

1997-01-01T23:59:59.000Z

239

FLARE, Fermilab Liquid Argon Experiments  

E-Print Network [OSTI]

Mature technology of Liquid Argon Time Projection Chambers in conjunction with intense neutrino beams constructed at Fermilab offer a broad program of neutrino physics for the next decade.

L. Bartoszek

2004-08-24T23:59:59.000Z

240

Ionic Liquids as Novel Lubricants and Additives for Diesel Engine Applications  

SciTech Connect (OSTI)

The lubricating properties of two ionic liquids with the same anion but different cations, one ammonium IL [C8H17]3NH.Tf2N and one imidazolium IL C10mim.Tf2N, were evaluated both in neat form and as oil additives. Experiments were conducted using a standardized reciprocating sliding test using a segment of a Cr-plated diesel engine piston ring against a grey cast iron flat specimen with simulated honing marks as on the engine cylinder liner. The selected ionic liquids were benchmarked against conventional hydrocarbon oils. Substantial friction and wear reductions, up to 55% and 34%, respectively, were achieved for the neat ionic liquids compared to a fully-formulated 15W40 engine oil. Adding 5 vol% ILs into mineral oil has demonstrated significant improvement in the lubricity. One blend even outperformed the 15W40 engine oil with 9% lower friction and 34% less wear. Lubrication regime modeling, worn surface morphology examination, and surface chemical analysis were conducted to help understand the lubricating mechanisms for ionic liquids. Results suggest great potential for using ionic liquids as base lubricants or lubricant additives for diesel engine applications.

Qu, Jun [ORNL; Blau, Peter Julian [ORNL; Dai, Sheng [ORNL; Luo, Huimin [ORNL; Meyer III, Harry M [ORNL

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Process for removal of mineral particulates from coal-derived liquids  

DOE Patents [OSTI]

Suspended mineral solids are separated from a coal-derived liquid containing the solids by a process comprising the steps of: (a) contacting said coal-derived liquid containing solids with a molten additive having a melting point of 100.degree.-500.degree. C. in an amount of up to 50 wt. % with respect to said coal-derived liquid containing solids, said solids present in an amount effective to increase the particle size of said mineral solids and comprising material or mixtures of material selected from the group of alkali metal hydroxides and inorganic salts having antimony, tin, lithium, sodium, potassium, magnesium, calcium, beryllium, aluminum, zinc, molybdenum, cobalt, nickel, ruthenium, rhodium or iron cations and chloride, iodide, bromide, sulfate, phosphate, borate, carbonate, sulfite, or silicate anions; and (b) maintaining said coal-derived liquid in contact with said molten additive for sufficient time to permit said mineral matter to agglomerate, thereby increasing the mean particle size of said mineral solids; and (c) recovering a coal-derived liquid product having reduced mineral solids content. The process can be carried out with less than 5 wt. % additive and in the absence of hydrogen pressure.

McDowell, William J. (Knoxville, TN)

1980-01-01T23:59:59.000Z

242

Mathematical Modeling of Cation Contamination in a Proton-exchange Membrane  

SciTech Connect (OSTI)

Transport phenomena in an ion-exchange membrane containing both H+ and K+ are described using multicomponent diffusion equations (Stefan-Maxwell). A model is developed for transport through a Nafion 112 membrane in a hydrogen-pump setup. The model results are analyzed to quantify the impact of cation contamination on cell potential. It is shown that limiting current densities can result due to a decrease in proton concentration caused by the build-up of contaminant ions. An average cation concentration of 30 to 40 percent is required for appreciable effects to be noticed under typical steady-state operating conditions.

Weber, Adam; Delacourt, Charles

2008-09-11T23:59:59.000Z

243

Cationic and ThiolEne Photopolymerization upon Red Lights Using Anthraquinone Derivatives as Photoinitiators  

Science Journals Connector (OSTI)

One of them (Oil Blue N) that is particularly efficient for cationic, IPN, and thiolene polymerization upon red lights (laser diode at 635 nm or household red LED bulb at 630 nm) belongs to the very few systems available at this long wavelength in such experimental conditions (low light intensity in the 10100 mW/cm2 range). ... The photochemical mechanisms are studied by steady state photolysis, fluorescence, cyclic voltammetry, and electron spin resonance spin trapping techniques. ... Copper Complexes in Radical Photoinitiating Systems: Applications to Free Radical and Cationic Polymerization upon Visible LEDs ...

Pu Xiao; Frdric Dumur; Bernadette Graff; Jean Pierre Fouassier; Didier Gigmes; Jacques Laleve

2013-08-22T23:59:59.000Z

244

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and Fire!  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Antifreeze! Antifreeze! Previous Video (Liquid Nitrogen and Antifreeze!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and the Tea Kettle Mystery!) Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and Fire! A burning candle is placed in a container of liquid nitrogen! Filmed in front of a live studio audience. Well, they were live when we started... [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Steve: Now, then. I'm a little bit afraid to ask this next question because I think I already know the answer, but is anyone in here feeling a little... dangerous? You're willing to take a chance? Because I am willing to do an experiment they haven't let me do since 'The Incident.' Now, because of the danger, I cannot have a volunteer. I must do this on my

245

A new Diffractometer for Studies of Liquid-Liquid Interfaces  

SciTech Connect (OSTI)

We have designed a novel, dedicated diffractometer for surface x-ray scattering studies of liquid-liquid and liquid-gas interfaces for the PETRA III High Resolution Diffraction Beamline. Using a double crystal beam-tilter in Bragg geometry this new instrument enables reflectivity and grazing incidence diffraction investigations without moving the sample, which is mechanically decoupled from the rest of the diffractometer. This design minimizes external excitation of surface vibrations, a key prerequisite for studies of liquid interfaces. The instrument operates over the energy range 6.4 keV to 30 keV, the higher energy range being optimal for penetration through liquid sample environments. Vertical momentum transfer up to q{sub z} 2.5 A{sup -1} and lateral q{sub ||} up to 4 A{sup -1}will be available.

Murphy, B. M.; Greve, M.; Runge, B.; Koops, C. T.; Elsen, A.; Stettner, J.; Magnussen, O. M. [IEAP, Christian-Albrechts-Universitaet zu Kiel, D-24098 Kiel (Germany); Seeck, O. H. [PETRA III at DESY, Notkestr. 85, D-22603 Hamburg (Germany)

2010-06-23T23:59:59.000Z

246

Frostbite Theater - Liquid Nitrogen Experiments - Cells vs. Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Superconductors! Superconductors! Previous Video (Superconductors!) Frostbite Theater Main Index Next Video (Liquid Oxygen and Fire!) Liquid Oxygen and Fire! Cells vs. Liquid Nitrogen! Let's say you've carelessly dunked your hand into a vat of liquid nitrogen and let it freeze solid. Every movie you've seen where this happens tells you that your hand will shatter like fine china should you bump it into something. If you're extremely careful, will your hand be okay once it thaws out? We'll explore this issue, using flower and onion cells rather than our hands! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: By now, we all know what happens when you place a flower in liquid

247

Anion effects in the extraction of lanthanide 2-thenoyltrifluoroacetone complexes into an ionic liquid  

SciTech Connect (OSTI)

The extraction of trivalent lanthanides from an aqueous phase containing 1 M NaClO{sub 4} into the room temperature ionic liquid 1-butyl-3-methylimidazolium nonafluoro-1-butane sulfonate by the beta-diketone extractant 2-thenoyltrifluoroacetone (Htta) was studied. Radiotracer distribution, absorption spectroscopy, time-resolved laser-induced fluorescence spectroscopy, and X-ray absorption fine structure measurements point to the extraction of multiple lanthanide species. At low extractant concentrations, fully hydrated aqua cations of the lanthanides are present in the ionic liquid phase. As the extractant concentration is increased 1:2 and 1:3 lanthanide:tta species are observed. In contrast, 1:4 Ln:tta complexes were observed in the extraction of lanthanides by Htta into 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide. (authors)

Jensen, Mark P.; Beitz, James V.; Rickert, Paul G. [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Borkowski, Marian [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Los Alamos Natl Lab, Earth and Environm Sci Div, Carlsbad, NM, (United States); Laszak, Ivan [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Commisariat Energie Atom, DEN DPC SERC LANIE, Gif Sur Yvette, (France); Dietz, Mark L. [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Wisconsin-Milwaukee Univ, Department of Chemistry and Biochemistry, Milwaukee, WI, (United States)

2012-07-01T23:59:59.000Z

248

SOLIEX: A Novel Solid-Liquid Method of Radionuclides Extraction from Radioactive Waste Solutions - 13486  

SciTech Connect (OSTI)

This paper describes recent developments in new solid-liquid extraction method, called SOLIEX, to remove cesium from alkaline solutions. SOLIEX relies on the use of a reversible complexing system comprising a carbon felt bearing molecular traps (calixarenes). This complexing system exhibits a high selectivity for Cs, and is thus expected to be helpful for the treatment of highly diluted cesium wastes even with a high concentration of competing alkali metal cations. As additional advantage, this complexing system can be adapted by molecular engineering to capture other radionuclides, such as Sr, Eu, Am. Finally, this complexing system can be easily and efficiently regenerated by using a cost effective stripping procedure, which limits further generation of waste to meet 'zero liquid' discharge requirements for nuclear facilities. (authors)

Shilova, E.; Viel, P. [CEA Saclay, DSM/IRAMIS/SPCSI, 91191Gif sur Yvette (France)] [CEA Saclay, DSM/IRAMIS/SPCSI, 91191Gif sur Yvette (France); Fournel, B.; Barre, Y. [CEA Marcoule, DTCD, BP17171, 30207 Bagnols sur Ceze (France)] [CEA Marcoule, DTCD, BP17171, 30207 Bagnols sur Ceze (France); Huc, V. [ICMMO - UMR CNRS 8182 - Bat. 420 Universite Paris-Sud (France)] [ICMMO - UMR CNRS 8182 - Bat. 420 Universite Paris-Sud (France)

2013-07-01T23:59:59.000Z

249

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for recovering liquid hydrocarbons. It comprises: injecting into a fractured subterranean formation a polymer enhanced foam comprising a polymer selected from a synthetic polymer or a biopolymer, a surfactant, an aqueous solvent and a gas, recovering liquid hydrocarbons from the formation.

Sydansk, R.D.

1992-07-14T23:59:59.000Z

250

Laboratory solvent reuse -- Liquid chromatography  

SciTech Connect (OSTI)

The objective of this work was to develop a method for reduction of waste solvent in the Process Engineering Chemistry Laboratory. The liquid chromatographs are the largest generators of explosive-contaminated waste in the laboratory. We developed a successful process for the reuse of solvents from the liquid chromatographs and demonstrated the utility of the process in the assay of hexanitrostilbene.

Quinlin, W.T.; Schaffer, C.L.

1992-11-01T23:59:59.000Z

251

Orifice mixing of immiscible liquids  

E-Print Network [OSTI]

measured with an Ostwald Viscosimeter relative to tap water also, All of these physical measurements were made at 83c F, the average tempera- ture noted during the runs. The liquid upon which these measurements were made were samples of the liquids...

McDonough, Joseph Aloysius

1960-01-01T23:59:59.000Z

252

Liquid-permeable electrode  

DOE Patents [OSTI]

Electrodes for use in an electrolytic cell, which are liquid-permeable and have low electrical resistance and high internal surface area are provided of a rigid, porous, carbonaceous matrix having activated carbon uniformly embedded throughout. The activated carbon may be catalyzed with platinum for improved electron transfer between electrode and electrolyte. Activated carbon is mixed with a powdered thermosetting phenolic resin and compacted to the desired shape in a heated mold to melt the resin and form the green electrode. The compact is then heated to a pyrolyzing temperature to carbonize and volatilize the resin, forming a rigid, porous structure. The permeable structure and high internal surface area are useful in electrolytic cells where it is necessary to continuously remove the products of the electrochemical reaction.

Folser, George R. (Lower Burrell, PA)

1980-01-01T23:59:59.000Z

253

Magnetically focused liquid drop radiator  

DOE Patents [OSTI]

A magnetically focused liquid drop radiator for application in rejecting energy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

Botts, T.E.; Powell, J.R.; Lenard, R.

1984-12-10T23:59:59.000Z

254

Freezing of a Liquid Marble  

E-Print Network [OSTI]

In this study, we present for the first time the observations of a freezing liquid marble. In the experiment, liquid marbles are gently placed on the cold side of a Thermo-Electric Cooler (TEC) and the morphological changes are recorded and characterized thereafter. These liquid marbles are noticed to undergo a shape transition from a spherical to a flying-saucer shaped morphology. The freezing dynamics of liquid marbles is observed to be very different from that of a freezing water droplet on a superhydrophobic surface. For example, the pointy tip appearing on a frozen water drop could not be observed for a frozen liquid marble. In the end, we highlight a possible explanation for the observed morphology.

Ali Hashmi; Adam Strauss; Jie Xu

2012-07-03T23:59:59.000Z

255

Cation sorption on the muscovite (001) surface in chloride solutions using high-resolution X-ray reflectivity  

E-Print Network [OSTI]

Cation sorption on the muscovite (001) surface in chloride solutions using high-resolution X of cation sorption at the (001) muscovite-water interface were investigated in 0.01 and 0.5 m KCl, Cs negative charge arising from structural heteroionic substitutions. This charge is balanced by the sorption

Jacobsen, Steven D.

256

Criteria for Generating Speci cation-based Tests A. Je erson O utt and Yiwei Xiong Shaoying Liu  

E-Print Network [OSTI]

- ria o er testers ways to decide what test inputs to use during testing, making it more likely presents a model for developing test in- puts from state-based speci cations, and formal crite- riaCriteria for Generating Speci cation-based Tests A. Je erson O utt and Yiwei Xiong Shaoying Liu

Offutt, Jeff

257

Evaluation of cation-exchanged zeolite adsorbents for post-combustion carbon dioxide capture  

E-Print Network [OSTI]

Evaluation of cation-exchanged zeolite adsorbents for post-combustion carbon dioxide capture Tae anthro- pogenic sources.1 Carbon capture and sequestration (CCS) has been proposed as a means of limiting evaluated for potential application in post-combustion CO2 capture using a new high-throughput gas

258

Non-Leaky Vesicle Fusion and Enhanced Cell Transfection Using a Cationic Facial Amphiphile  

E-Print Network [OSTI]

the interpreta- tion of results. In addition, there is the potential of discovering new types of fusion promotersNon-Leaky Vesicle Fusion and Enhanced Cell Transfection Using a Cationic Facial Amphiphile Yvonne R Dublin 2, Ireland ReceiVed December 23, 1999 Membrane fusion is an essential feature in many cellular

Smith, Bradley D.

259

Ionomer-Like Structures and ?-Cation Interactions in Argonne Premium Coals  

Science Journals Connector (OSTI)

Ionomer-Like Structures and ?-Cation Interactions in Argonne Premium Coals ... The increase in the amount of pyridine-soluble material obtained from Argonne Premium coals after acid treatment is examined. ... Accordingly, here we present results obtained from studies of the Argonne Premium coals before and after acid treatment. ...

Pakorn Opaprakasit; Alan W. Scaroni; Paul C. Painter

2002-02-28T23:59:59.000Z

260

Intermediate-range order and collective dynamics in an aqueous solution of trivalent cations  

Science Journals Connector (OSTI)

Molecular dynamics (MD) simulations of a concentrated aqueous solution of high-valence cations M3+ demonstrate the occurrence of intermediate-range order (IRO) by a pronounced prepeak at k?1.0?1 in the static structure factor. The IRO effect on the high-frequency collective dynamics of acoustic modes is investigated in a model system which mimics a 2.8M EuCl3 aqueous solution. A single branch in the dispersion relation of longitudinal acoustic (LA) modes in solution is obtained up to k?0.5?1, and then it splits into two branches for higher wave vectors. The low-frequency branch of LA modes in solution is not the well-known transverselike branch seen in MD simulation of pure water. It is assigned instead to a subsystem of M3+ cations plus water molecules belonging to the cations first hydration shell. The excitation energy of the low-frequency branch reaches a maximum in a k range half of the prepeak value, so that IRO plays the role of a pseudoBrillouin zone for the cation subsystem. The high-frequency branch of the LA modes in solution follows the corresponding one in pure water, and in fact a subsystem of bulk water molecules is identified in solution showing high-frequency short-range structural relaxation similar to that of pure water.

Mauro C. C. Ribeiro

2006-01-10T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Applying Practical Formal Methods to the Speci cation and Analysis of Security Properties  

E-Print Network [OSTI]

: chacs.nrl.navy.mil SCR Abstract. The SCR Software Cost Reduction toolset contains tools for specifying tabular notation for writing speci cations. Part of the SCR Software Cost Reduction requirements method system 7 , the shutdown system for the Darlington nuclear power plant 21 , and the ight program

262

Modelling and Veri cation of Automated Transit Systems, using Timed Automata, Invariants and  

E-Print Network [OSTI]

Modelling and Veri cation of Automated Transit Systems, using Timed Automata, Invariants in automated transit systems. The problems we consider are in- spired by design work in the Personal Rapid and Simulations Nancy Lynch ? Laboratory for Computer Science, Massachusetts Institute of Technology, Cambridge

Lynch, Nancy

263

UVA-visible photo-excitation of guanine radical cations produces sugar radicals in DNA and  

E-Print Network [OSTI]

UVA-visible photo-excitation of guanine radical cations produces sugar radicals in DNA and model, 2005; Revised and Accepted September 6, 2005 ABSTRACT This work presents evidence that photo- nucleosides and deoxyribonucleotides. In dsDNA at low temperatures, formation of C10 is observed from photo

Simons, Jack

264

CO adsorption-desorption properties of cation-exchanged NaX zeolite and supported ruthenium  

SciTech Connect (OSTI)

The binding states of carbon monoxide over cation-exchanged NaX zeolites and over corresponding Ru-containing samples have been investigated using thermal desorption spectroscopy. Exchange of sodium with cations such as Li{sup +}, Ca{sup 2+}, Mg{sup 2+}, and La{sup 3+} gave rise to additional CO adsorption states, a higher isosteric heat of CO adsorption, an increased density of acid sites, and an increased amount of adsorbed CO, depending on the nature and ionic radius of the charge-balancing cation. The charge-balancing cations at the zeolite surface (e.g., Ca{sub 2+}, La{sup 3+}) function as additional CO adsorption sites in conjunction with surface acid centers (e.g., the Al{sup 3+} center) and metal sites. In addition to surface sites, CO is also found to be held in structural cavities and macropores of the zeolite matrix. The programmed heating of both the metal-free and Ru-containing zeolites subsequent to room temperature CO adsorption gave desorption peaks due to release of CO at temperatures less than {approximately}500 K while the higher temperature peaks were constituted mainly of CO{sub 2}. Electron spectroscopy results have revealed that the exposure of these samples to CO and subsequent thermal treatment resulted in the formation of surface carbonaceous species. The nature of CO adsorption states giving rise to CO{sub 2} formation is discussed.

Gupta, N.M.; Kamble, V.S.; Rao, K.A.; Iyer, R.M. (Bhabha Atomic Research Centre, Bombay (India))

1989-12-01T23:59:59.000Z

265

The effect of paramagnetic manganese cations on 1 H MR spectroscopy of the brain  

E-Print Network [OSTI]

The effect of paramagnetic manganese cations on 1 H MR spectroscopy of the brain K. S. Madsen1 has investigated the effect of Mn on 1 H MR spectroscopy using an in vivo Mn-enhanced optic tract into a stereotactic device. Images and 1 H MR spectra were acquired using a Varian 4.7T animal scanner together

266

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory  

E-Print Network [OSTI]

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory Ricardo B. Metz Department of Chemistry, University of Massachusetts, Amherst, MA 01003 USA Abstract Gas such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

Metz, Ricardo B.

267

Correlation among electronegativity, cation polarizability, optical basicity and single bond strength of simple oxides  

SciTech Connect (OSTI)

A suitable relationship between free-cation polarizability and electronegativity of elements in different valence states and with the most common coordination numbers has been searched on the basis of the similarity in physical nature of both quantities. In general, the cation polarizability increases with decreasing element electronegativity. A systematic periodic change in the polarizability against the electronegativity has been observed in the isoelectronic series. It has been found that generally the optical basicity increases and the single bond strength of simple oxides decreases with decreasing the electronegativity. The observed trends have been discussed on the basis of electron donation ability of the oxide ions and type of chemical bonding in simple oxides. - Graphical abstract: This figure shows the single bond strength of simple oxides as a function of element electronegativity. A remarkable correlation exists between these independently obtained quantities. High values of electronegativity correspond to high values of single bond strength and vice versa. It is obvious that the observed trend in this figure is closely related to the type of chemical bonding in corresponding oxide. Highlights: Black-Right-Pointing-Pointer A suitable relationship between free-cation polarizability and electronegativity of elements was searched. Black-Right-Pointing-Pointer The cation polarizability increases with decreasing element electronegativity. Black-Right-Pointing-Pointer The single bond strength of simple oxides decreases with decreasing the electronegativity. Black-Right-Pointing-Pointer The observed trends were discussed on the basis of type of chemical bonding in simple oxides.

Dimitrov, Vesselin, E-mail: vesselin@uctm.edu [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria)] [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki, E-mail: komatsu@mst.nagaokaut.ac.jp [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)] [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

2012-12-15T23:59:59.000Z

268

Calcium and Strontium Hexaluminates: NMR Evidence that "Pentacoordinate" Cation Sites Are Four-Coordinated  

E-Print Network [OSTI]

LETTERS Calcium and Strontium Hexaluminates: NMR Evidence that "Pentacoordinate" Cation Sites, strontium hexaluminate (SrAl12O19, "SA6") and calcium hexaluminate (CaAl12O19, "CA6," synthetic hibonite, not dynamical, disorder among these sites. Introduction Calcium and strontium hexaluminates (CaAl12O19, "CA6

Puglisi, Joseph

269

High energy electron beam curing of epoxy resin systems incorporating cationic photoinitiators  

DOE Patents [OSTI]

A mixture of epoxy resins such as a semi-solid triglycidyl ether of tris (hydroxyphenyl) methane and a low viscosity bisphenol A glycidyl ether and a cationic photoinitiator such as a diaryliodonium salt is cured by irradiating with a dosage of electron beams from about 50 to about 150 kGy, forming a cross-linked epoxy resin polymer.

Janke, Christopher J. (Powell, TN); Lopata, Vincent J. (Manitoba, CA); Havens, Stephen J. (Knoxville, TN); Dorsey, George F. (Farragut, TN); Moulton, Richard J. (Lafayette, CA)

1999-01-01T23:59:59.000Z

270

Method of measuring a liquid pool volume  

DOE Patents [OSTI]

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid.

Garcia, Gabe V. (Las Cruces, NM); Carlson, Nancy M. (Idaho Falls, ID); Donaldson, Alan D. (Idaho Falls, ID)

1991-01-01T23:59:59.000Z

271

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...  

Broader source: Energy.gov (indexed) [DOE]

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

272

Frostbite Theater - Liquid Nitrogen Experiments - Instant Liquid Nitrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freezing Balloons! Freezing Balloons! Previous Video (Freezing Balloons!) Frostbite Theater Main Index Next Video (Shattering Flowers!) Shattering Flowers! Instant Liquid Nitrogen Balloon Party! Need a bunch of balloons blown-up quickly? Liquid nitrogen to the rescue! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: We've been making videos for a while now and we've learned that people like balloons and liquid nitrogen! Steve: So... Here you go! Balloon: Crackling... Balloon: Pop! Joanna: Ooh! Balloon: Pop! Balloon: Pop! Steve: If you'd like to know the science of what's going on behind this, please one of our first videos, "Liquid Nitrogen Experiments: The Balloon."

273

Haze Formation and Behavior in Liquid-Liquid Extraction Processes  

SciTech Connect (OSTI)

Aqueous haze formation and behavior was studied in the liquid-liquid system tri-n-butyl phosphate in odorless kerosene and 3M nitric acid with uranyl nitrate and cesium nitrate representing the major solute and an impurity, respectively. A pulsed column, mixer-settler and centrifugal contactor were chosen to investigate the effect of different turbulence characteristics on the manifestation of haze since these contactors exhibit distinct mixing phenomena. The dispersive processes of drop coalescence and breakage, and water precipitation in the organic phase were observed to lead to the formation of haze drops of {approx}1 um in diameter. The interaction between the haze and primary drops of the dispersion was critical to the separation efficiency of the liquid-liquid extraction equipment. Conditions of high power input and spatially homogeneous mixing enabled the haze drops to become rapidly assimilated within the dispersion to maximize the scrub performance and separation efficiency of the equipment.

Arm, Stuart T.; Jenkins, J. A.

2006-07-31T23:59:59.000Z

274

Molecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Richard J. Sadus  

E-Print Network [OSTI]

coexistence. 1. Introduction Henry's constant is a well-known measure of a solute's solubility in a particularMolecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Boundaries Richard to determine Henry's constant from the residual chemical potential at infinite dilution at the vapor-liquid

275

Lithium Ion Transport Mechanism in Ternary Polymer Electrolyte-Ionic Liquid Mixtures - A Molecular Dynamics Simulation Study  

E-Print Network [OSTI]

The lithium transport mechanism in ternary polymer electrolytes, consisting of PEO/LiTFSI and various fractions of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethane)sulfonimide, are investigated by means of MD simulations. This is motivated by recent experimental findings [Passerini et al., Electrochim. Acta 2012, 86, 330-338], which demonstrated that these materials display an enhanced lithium mobility relative to their binary counterpart PEO/LiTFSI. In order to grasp the underlying microscopic scenario giving rise to these observations, we employ an analytical, Rouse-based cation transport model [Maitra at al., PRL 2007, 98, 227802], which has originally been devised for conventional polymer electrolytes. This model describes the cation transport via three different mechanisms, each characterized by an individual time scale. It turns out that also in the ternary electrolytes essentially all lithium ions are coordinated by PEO chains, thus ruling out a transport mechanism enhanced by the presence of ionic-liquid molecules. Rather, the plasticizing effect of the ionic liquid contributes to the increased lithium mobility by enhancing the dynamics of the PEO chains and consequently also the motion of the attached ions. Additional focus is laid on the prediction of lithium diffusion coefficients from the simulation data for various chain lengths and the comparison with experimental data, thus demonstrating the broad applicability of our approach.

Diddo Diddens; Andreas Heuer

2012-11-14T23:59:59.000Z

276

The Viscosity of Liquid Helium  

Science Journals Connector (OSTI)

2 September 1935 research-article The Viscosity of Liquid Helium J. O. Wilhelm A. D. Misener A. R. Clark The Royal Society is collaborating with JSTOR to digitize, preserve...

1935-01-01T23:59:59.000Z

277

Liquid Oxygen and its Uses  

Science Journals Connector (OSTI)

... of the liquid. At present, however, there is no known method of rendering them flameless, and their use in the majority of coal-mines is therefore inadmissible. If this ...

HENRY BRIGGS

1924-02-02T23:59:59.000Z

278

Gaseous and Liquid Hydrogen Storage  

Broader source: Energy.gov [DOE]

Today's state of the art for hydrogen storage includes 5,000- and 10,000-psi compressed gas tanks and cryogenic liquid hydrogen tanks for on-board hydrogen storage.

279

Liquid helium cryo TEM | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cryo TEM Liquid helium cryo TEM The JEOL JEM-3000SFF was designed for high-resolution cryogenic transmission electron microscopy (cryo-EM) of biological samples and expands EMSL...

280

Essays on liquidity and information  

E-Print Network [OSTI]

This dissertation studies the interaction of liquidity and incomplete or asymmetric information. In Chapter 1, I study a dynamic economy with illiquidity due to adverse selection in financial markets. Investment is undertaken ...

Kurlat, Pablo (Pablo Daniel)

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Physical Chemistry of Ionic Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ionic liquids are experiencing explosive growth in many areas of research Ionic liquids are experiencing explosive growth in many areas of research and practical applications. They present a wide range of complex physical and chemical behaviors, including ambient vapor pressures ranging from UHV to weakly volatile, a substantial variety of distinct condensed phases, including multiple crystal isomorphs, glasses, amorphous plastic and liquid crystal phases, deep supercooling, and interesting dynamical and transport phenomena. Experiments and simulations have shown that their intrinsic self-organization at the nanoscale is responsible for several of these properties. The symposium will assemble an international array of speakers to discuss ionic liquids in the context of their heterogeneous environments, solvation, dynamics and transport, interfacial properties,

282

Electrophoresis of DNA Adsorbed to a Cationic Supported David J. Olson, Joseph M. Johnson, Prateek D. Patel, Eric S. G. Shaqfeh,  

E-Print Network [OSTI]

Electrophoresis of DNA Adsorbed to a Cationic Supported Bilayer David J. Olson, Joseph M. Johnson of individual DNA molecules electrostatically adsorbed to a cationic supported lipid bilayer. Obstacles,22 in their recent work on DNA electrostatically adsorbed to a fluid cationic lipid bilayer, found that the chains

Shaqfeh, Eric

283

Semantics of Architectural Speci cations in CASL Lutz Schroder 1 , Till Mossakowski 1 , Andrzej Tarlecki 2;3 , Bartek Klin 4 , and  

E-Print Network [OSTI]

at various levels in an institution-independent fashion. Introduction A common feature of present-day algebraic speci#12;cation languages (see e.g. [Wir86,EM85,GHG + 93,CoFI96,SW99]) is the provision;cations at various levels. We use a simple subset of Casl architectural speci#12;cations, which

Schröder, Lutz

284

SRS - Programs - Liquid Waste Disposition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquid Waste Disposition Liquid Waste Disposition This includes both the solidification of highly radioactive liquid wastes stored in SRS's tank farms and disposal of liquid low-level waste generated as a by-product of the separations process and tank farm operations. This low-level waste is treated in the Effluent Treatment Facility. High-activity liquid waste is generated at SRS as by-products from the processing of nuclear materials for national defense, research and medical programs. The waste, totaling about 36 million gallons, is currently stored in 49 underground carbon-steel waste tanks grouped into two "tank farms" at SRS. While the waste is stored in the tanks, it separates into two parts: a sludge that settles on the bottom of the tank, and a liquid supernate that resides on top of the sludge. The waste is reduced to about 30 percent of its original volume by evaporation. The condensed evaporator "overheads" are transferred to the Effluent Treatment Project for final cleanup prior to release to the environment. As the concentrate cools a portion of it crystallizes forming solid saltcake. The concentrated supernate and saltcake are less mobile and therefore less likely to escape to the environment in the event of a tank crack or leak.

285

PHASE CHANGE LIQUIDS  

SciTech Connect (OSTI)

Work is being performed to develop a new shipping system for frozen environmental samples (or other materials) that uses an optimal phase change liquid (PCL) formulation and an insulated shipping container with an on-board digital temperature data logger to provide a history of the temperature profile within the container during shipment. In previous work, several PCL formulations with temperatures of fusion ranging from approximately -14 to -20 C were prepared and evaluated. Both temperature of fusion and heat of fusion of the formulations were measured, and an optimal PCL formulation was selected. The PCL was frozen in plastic bags and tested for its temperature profile in a cooler using a digital temperature data logger. This testing showed that the PCL formulation can maintain freezer temperatures (< -7 to -20 C) for an extended period, such as the time for shipping samples by overnight courier. The results of the experiments described in this report provide significant information for use in developing an integrated freezer system that uses a PCL formulation to maintain freezer temperatures in coolers for shipping environmental samples to the laboratory. Experimental results show the importance of the type of cooler used in the system and that use of an insulating material within the cooler improves the performance of the freezer system. A new optimal PCL formulation for use in the system has been determined. The new formulation has been shown to maintain temperatures at < -7 to -20 C for 47 hours in an insulated cooler system containing soil samples. These results are very promising for developing the new technology.

Susan S. Sorini; John F. Schabron

2006-03-01T23:59:59.000Z

286

Extremely Correlated Fermi Liquids B. Sriram Shastry  

E-Print Network [OSTI]

Extremely Correlated Fermi Liquids B. Sriram Shastry Physics Department, University of California the theory of an extremely correlated Fermi liquid with U ! 1. This liquid has an underlying auxiliary Fermi liquid Green's function that is further caparisoned by extreme correlations. The theory leads to two

California at Santa Cruz, University of

287

Commercialization of Coal-to-Liquids Technology  

SciTech Connect (OSTI)

The report provides an overview of the current status of coal-to-liquids (CTL) commercialization efforts, including an analysis of efforts to develop and implement large-scale, commercial coal-to-liquids projects to create transportation fuels. Topics covered include: an overview of the history of coal usage and the current market for coal; a detailed description of what coal-to-liquids technology is; the history of coal-to-liquids development and commercial application; an analysis of the key business factors that are driving the increased interest in coal-to-liquids; an analysis of the issues and challenges that are hindering the commercialization of coal-to-liquids technology; a review of available coal-to-liquids technology; a discussion of the economic drivers of coal-to-liquids project success; profiles of key coal-to-liquids developers; and profiles of key coal-to-liquids projects under development.

NONE

2007-08-15T23:59:59.000Z

288

Communication: CO oxidation by silver and gold cluster cations: Identification of different active oxygen species  

SciTech Connect (OSTI)

The oxidation of carbon monoxide with nitrous oxide on mass-selected Au{sub 3}{sup +} and Ag{sub 3}{sup +} clusters has been investigated under multicollision conditions in an octopole ion trap experiment. The comparative study reveals that for both gold and silver cations carbon dioxide is formed on the clusters. However, whereas in the case of Au{sub 3}{sup +} the cluster itself acts as reactive species that facilitates the formation of CO{sub 2} from N{sub 2}O and CO, for silver the oxidized clusters Ag{sub 3}O{sub x}{sup +} (n= 1-3) are identified as active in the CO oxidation reaction. Thus, in the case of the silver cluster cations N{sub 2}O is dissociated and one oxygen atom is suggested to directly react with CO, whereas a second kind of oxygen strongly bound to silver is acting as a substrate for the reaction.

Popolan, Denisia M.; Bernhardt, Thorsten M. [Institute of Surface Chemistry and Catalysis, University of Ulm, Albert-Einstein-Allee 47, 89069 Ulm (Germany)

2011-03-07T23:59:59.000Z

289

Multicolor Photoinitiators for Radical and Cationic Polymerization: Monofunctional vs Polyfunctional Thiophene Derivatives  

Science Journals Connector (OSTI)

Their abilities to initiate, when combined with an iodonium salt (and optionally N-vinylcarbazole), a ring-opening cationic photopolymerization of epoxides and radical photopolymerization of acrylates under various different irradiation sources (i.e., very soft halogen lamp irradiation, laser diode at 405, 457, 473, 532, and 635 nm and blue LED bulb at 462 nm) have been investigated. ... They are also particularly efficient for the cationic and radical photopolymerization of an epoxide/acrylate blend in a one-step hybrid cure and lead to the formation of an interpenetrated polymer network IPN (30 s for getting tack-free coatings). ... The photochemical mechanisms are studied by steady state photolysis, fluorescence, cyclic voltammetry, electron spin resonance spin trapping, and laser flash photolysis techniques. ...

Pu Xiao; Frdric Dumur; Damien Thirion; Sbastien Fagour; Antoine Vacher; Xavier Sallenave; Fabrice Morlet-Savary; Bernadette Graff; Jean Pierre Fouassier; Didier Gigmes; Jacques Laleve

2013-08-20T23:59:59.000Z

290

Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points  

E-Print Network [OSTI]

. INTRODUCTION Water is characterized by well-known thermodynamic and kinetic liquid-state anomalies; for examplePREPRINT Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points Evy simulations are used to examine the relationship between water-like anoma- lies and the liquid-liquid critical

Barbosa, Marcia C. B.

291

Oxygen isotope fractionation effects in soil water via interaction with cations (Mg, Ca, K, Na) adsorbed to phyllosilicate clay minerals  

E-Print Network [OSTI]

) adsorbed to phyllosilicate clay minerals Erik Oerter a, , Kari Finstad a , Justin Schaefer b , Gregory R approaches to the measurement of the d18 O value of soil water. The adsorbed cation isotope effect may bear

Goldsmith, Greg

292

An Ounce of Prevention is Worth a Pound of Cure Towards Physically-Correct Speci cations of  

E-Print Network [OSTI]

ed reliability and timeliness requirements { is a crucial, highly desirable property of responsive. Examplesinclude commandand con- trol systems, nuclear reactors, process-control plants, robotics, avionics, formalveri cation, fault-tolerance, safety analysis, programming languages, development tools, scheduling

293

Compound and Elemental Analysis At Akutan Fumaroles Area (Kolker, Et Al.,  

Open Energy Info (EERE)

Akutan Fumaroles Area (Kolker, Et Al., Akutan Fumaroles Area (Kolker, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Akutan Fumaroles Area (Kolker, Et Al., 2010) Exploration Activity Details Location Akutan Fumaroles Area Exploration Technique Compound and Elemental Analysis Activity Date Usefulness useful DOE-funding Unknown Notes The chemistry of the hot springs strongly suggests the existence of a neutral chloride reservoir with economically developable temperature. The fluid geothermometry tells a consistent story, with cation geothermometry detecting a >210degrees C reservoir temperature, probably near the fumarole, and silica geothermometry and presence of sinter suggesting that 160 to 180degrees C exists close to hot spring B.

294

Modeling the Interaction between Integrin-Binding Peptide (RGD) and Rutile Surface: The Effect of Cation Mediation on Asp Adsorption  

SciTech Connect (OSTI)

The binding of a negatively charged residue, aspartic acid (Asp) in tripeptide arginine-glycine-aspartic acid, onto a negatively charged hydroxylated rutile (110) surface in aqueous solution, containing divalent (Mg{sup 2+}, Ca{sup 2+}, or Sr{sup 2+}) or monovalent (Na{sup +}, K{sup +}, or Rb{sup +}) cations, was studied by molecular dynamics (MD) simulations. The results indicate that ionic radii and charges will significantly affect the hydration, adsorption geometry, and distance of cations from the rutile surface, thereby regulating the Asp/rutile binding mode. The adsorption strength of monovalent cations on the rutile surface in the order Na{sup +} > K{sup +} > Rb{sup +} shows a 'reverse' lyotropic trend, while the divalent cations on the same surface exhibit a 'regular' lyotropic behavior with decreasing crystallographic radii (the adsorption strength of divalent cations: Sr{sup 2+} > Ca{sup 2+} > Mg{sup 2+}). The Asp side chain in NaCl, KCl, and RbCl solutions remains stably H-bonded to the surface hydroxyls and the inner-sphere adsorbed compensating monovalent cations act as a bridge between the COO{sup -} group and the rutile, helping to 'trap' the negatively charged Asp side chain on the negatively charged surface. In contrast, the mediating divalent cations actively participate in linking the COO{sup -} group to the rutile surface; thus the Asp side chain can remain stably on the rutile (110) surface, even if it is not involved in any hydrogen bonds with the surface hydroxyls. Inner- and outer-sphere geometries are all possible mediation modes for divalent cations in bridging the peptide to the rutile surface.

Wu, Chunya [Harbin Institute of Technology; Skelton, Adam [Vanderbilt University; Chen, Mingjun [Harbin Institute of Technology; Vlcek, Lukas [ORNL; Cummings, Peter T [ORNL

2012-01-01T23:59:59.000Z

295

Liquid soap film generates electricity  

E-Print Network [OSTI]

We have observed that a rotating liquid soap film generates electricity when placed between two non-contact electrodes with a sufficiently large potential difference. In our experiments suspended liquid film (water + soap film) is formed on the surface of a circular frame, which is forced to rotate in the $x-y$ horizontal plane by a motor. This system is located at the center of two capacitor-like vertical plates to apply an external electric voltage difference in the $x-$direction. The produced electric current is collected from the liquid film using two conducting electrodes that are separated in the $y-$direction. We previously reported that a liquid film in an external electric field rotates when an electric current passes through it, naming it the liquid film motor (LFM). In this paper we report a novel technique, in which a similar device can be used as an electric generator, converting the rotating mechanical energy to electrical energy. The liquid film electric generator (LFEG) is in stark contrast to the LFM, both of which could be designed similarly in very small scales like micro scales with different applications. Although the device is comparable to commercial electric motors or electric generators, there is a significant difference in their working principles. Usually in an electric motor or generator the magnetic field causes the driving force, while in a LFM or LFEG the Coulomb force is the driving force. This fact is also interesting from the Bio-science point of view and brings a similarity to bio motors. Here we have investigated the electrical characteristics of such a generator for the first time experimentally and modelled the phenomenon with electroconvection governing equations. A numerical simulation is performed using the local approximation for the charge-potential relation and results are in qualitative agreement with experiments.

Ahmad Amjadi; Sadegh Feiz; Reza Montazeri Namin

2014-04-24T23:59:59.000Z

296

Application of Ionic Liquids in Liquid Chromatography and Electrodriven Separation  

Science Journals Connector (OSTI)

......processing (5), solvent extraction (6, 7), electrolytes in batteries (8), metal deposition (9, 10) and gas treatment (11...Polymerized ionic liquid sorbents for CO2 separation. Energy and Fuels (2010) 24:5797-5804. 13 Ho T.D. , Canestraro A......

Yi Huang; Shun Yao; Hang Song

2013-08-01T23:59:59.000Z

297

Method of measuring a liquid pool volume  

DOE Patents [OSTI]

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools is disclosed, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figures.

Garcia, G.V.; Carlson, N.M.; Donaldson, A.D.

1991-03-19T23:59:59.000Z

298

E-Print Network 3.0 - aqueous solution cation Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

au no 4, Tome 40, Avril 1979,page C3-438 THE EFFECT OF AMPHIPHILIC LIQUID CRYSTALLINE SOLVENTS Summary: media. The organization of amphiphilic molecules in aqueous solution...

299

Stiffening solids with liquid inclusions  

E-Print Network [OSTI]

From bone and wood to concrete and carbon fibre, composites are ubiquitous natural and engineering materials. Eshelby's inclusion theory describes how macroscopic stress fields couple to isolated microscopic inclusions, allowing prediction of a composite's bulk mechanical properties from a knowledge of its microstructure. It has been extended to describe a wide variety of phenomena from solid fracture to cell adhesion. Here, we show experimentally and theoretically that Eshelby's theory breaks down for small liquid inclusions in a soft solid. In this limit, an isolated droplet's deformation is strongly size-dependent with the smallest droplets mimicking the behaviour of solid inclusions. Furthermore, in opposition to the predictions of conventional composite theory, we find that finite concentrations of small liquid inclusions enhance the stiffness of soft solids. A straight-forward extension of Eshelby's theory, accounting for the surface tension of the solid-liquid interface, explains our experimental observations. The counterintuitive effect of liquid-stiffening of solids is expected whenever droplet radii are smaller than an elastocapillary length, given by the ratio of the surface tension to Young's modulus of the solid matrix.

Robert W. Style; Rostislav Boltyanskiy; Benjamin Allen; Katharine E. Jensen; Henry P. Foote; John S. Wettlaufer; Eric R. Dufresne

2014-07-24T23:59:59.000Z

300

Determination of triclosan and triclocarban in environmental water samples with ionic liquid/ionic liquid dispersive liquid-liquid microextraction prior to HPLC-ESI-MS/MS  

Science Journals Connector (OSTI)

A hydrophobic ionic liquid was finely dispersed in aqueous solution along with a hydrophilic ionic liquid. Following centrifugation, the two phases aggregate to form relatively large droplets. Based on this pheno...

Ru-Song Zhao; Xia Wang; Jing Sun; Cong Hu; Xi-Kui Wang

2011-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Nanopatterned anchoring layers for liquid crystals  

E-Print Network [OSTI]

This thesis describes the theory and fabrication of inhomogeneous Liquid Crystal anchoring layers. While chemical anchoring techniques have proved useful for many applications, especially Liquid Crystal Displays, they have ...

Gear, Christopher S. (Christopher Stanwood)

2014-01-01T23:59:59.000Z

302

Cation-Bonding and Protonation of the Fe[subscript 4]-Square Cluster  

SciTech Connect (OSTI)

The synthesis and characterization of discrete, molecular iron-oxo clusters is pursued in the interest of molecular magnets, bioinspired materials and models for the geochemical aqueous-mineral interface. Iron-oxo clusters are challenging to synthesize in water, due to the extremely acidic and reactive nature of dissolved iron species, and thus require chelating ligands to passivate and neutralize the cluster surface. The 2-hydroxy-1,3-N,N,N',N'-diamino-propanetetraacetic acid (HPDTA) ligand has been used to isolate several Al and Fe cluster geometries, including the square clusters Fe{sub 4}(HPDTA){sub 2} and Al{sub 4}(HPDTA){sub 2}. While prior reports on the Fe{sub 4}(HPDTA){sub 2} cluster have focused on the magnetic properties, no solution characterization has been carried out. Using electrospray ionization mass-spectrometry (ESI-MS) we show this anionic Fe{sub 4}(HPDTA){sub 2} cluster can be dissolved intact in water, and recrystallized with virtually any metal as a countercation. The bonding of the metal cation to the square face of the cluster trends with ionic radii of the cations, as shown by structural characterization of Fe{sub 4}(HPDTA){sub 2} with Li{sup +}, Na{sup +}, Cs{sup +}, Mg{sup 2+}, Ba{sup 2+}, La{sup 3+}, Eu{sup 3+}, and Zn{sup 2+}. This trend is similar to that observed for association of cations on metal oxide surfaces in the environment. Furthermore, protonation of the bridging oxo ligands of this series of Fe{sub 4}(HPDTA){sub 2} clusters is variable (0, 1, or 2 protons), and structures as a function of protonation is discussed. This paper, largely structural in nature, sets the foundation for future aqueous phase studies of iron-oxo molecular clusters as models for the oxide-water interface in the natural aqueous environment.

Hou, Yu; Rodriguez, Mark A.; Nyman, May (Sandia)

2012-04-30T23:59:59.000Z

303

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wongchang

2014-05-13T23:59:59.000Z

304

Retention of anhydrous ammonia as influenced by clay mineral types, cations, temperature and moisture  

E-Print Network [OSTI]

to various temperature levels . . . . . ~ 20 5a 6. 70 Ammoni. a retained sxuressed as psr cent of cation-exchange capacity for olays treated with anhydrous ammonia prior to heating to various temperature levels . ~. . . . . . ~ ~ . 21 Ammonia retained... encountered in the use of anhydrous ammoni. . . REVIEW OF LITER4TURE Some of the early work with anhydx ous ammonia was done by anderson, et al. (2), and Enderson and Eattson (3). St that t1ms anhydrous ammonia as sn inorganic source of nitrogen fertiliaer...

McBee, George G

1956-01-01T23:59:59.000Z

305

Nanoparticle enhanced ionic liquid heat transfer fluids  

DOE Patents [OSTI]

A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.

Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

2014-08-12T23:59:59.000Z

306

Ionic Liquids for Utilization of Geothermal Energy  

Broader source: Energy.gov [DOE]

DOE Geothermal Program Peer Review 2010 - Presentation. Project objective: to develop ionic liquids for two geothermal energy related applications.

307

Liquid Propane Injection Applications | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Liquid propane injection technology meets manufacturingassembly guidelines, maintenancerepair strategy, and regulations, with same functionality, horsepower, and torque as...

308

Heterophase liquid states: Thermodynamics, structure, dynamics  

E-Print Network [OSTI]

An overview of theoretical results and experimental data on the thermodynamics, structure and dynamics of the heterophase glass-forming liquids is presented. The theoretical approach is based on the mesoscopic heterophase fluctuations model (HPFM) developed within the framework of the bounded partition function approach. The Fischer cluster phenomenon, glass transition, liquid-liquid transformations, parametric phase diagram, cooperative dynamics and fragility of the glass-forming liquids is considered.

A. S. Bakai

2015-01-12T23:59:59.000Z

309

Remarks on Liquid Wall Research Mohamed Abdou  

E-Print Network [OSTI]

Wall Research Advances the Science and Energy Goals of Fusion in a Perfect Fit · If we can make liquidRemarks on Liquid Wall Research Mohamed Abdou Professor Mechanical and Aerospace Engineering UCLA Note For recent presentations and papers on liquid wall research by the APEX team see website: http

Abdou, Mohamed

310

Commercialization of coal to liquids technology  

SciTech Connect (OSTI)

After an overview of the coal market, technologies for producing liquids from coal are outlined. Commercialisation of coal-to-liquid fuels, the economics of coal-to-liquids development and the role of the government are discussed. Profiles of 8 key players and the profiles of 14 projects are finally given. 17 figs., 8 tabs.

NONE

2007-07-01T23:59:59.000Z

311

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen Show!  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Insulators! Insulators! Previous Video (Insulators!) Frostbite Theater Main Index Next Video (Superconductors!) Superconductors! Liquid Nitrogen Show! All of your favorite liquid nitrogen experiments all in one place! Flowers! Balloons! Racquetballs! Nothing is safe! Just sit back, relax, and enjoy the show! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Usually, every couple years, Jefferson Lab hosts an Open House. This is the one time the public and come and tour our accelerator and end stations. Steve: During the 2010 Open House, our cameraman snuck into one of the ongoing cryo shows that are held throughout the day. He missed half of it. So if you want to see the entire thing, check our website to see when the

312

Bubbles in Insulating Liquids: Stability in an Electric Field  

Science Journals Connector (OSTI)

...July 1964 research-article Bubbles in Insulating Liquids: Stability in an Electric Field C. G...Krasucki It is shown that a bubble of gas or liquid, immersed...of incompressible (liquid) bubbles immersed in an insulating liquid...

1964-01-01T23:59:59.000Z

313

Liquid Propane Injection Technology Conductive to Today's North...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection...

314

Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass  

SciTech Connect (OSTI)

Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogenous catalyst for gasification.

Elliott, Douglas C; Oyler, James

2013-12-17T23:59:59.000Z

315

Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass  

SciTech Connect (OSTI)

Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

Elliott, Douglas C; Oyler, James R

2014-11-04T23:59:59.000Z

316

Transport of copper ammines through a cation-exchange membrane during electrodialysis  

SciTech Connect (OSTI)

Extraction of copper ammine complexes from waste waters in electroplating technology and in production of cuprammonium fibers is an important problem and electrodialysis with ion-exchange membranes is the most promising method of solving it. The authors aim was to study transport of copper(II) ammines through a commercial cation-exchange membrane of the MK-40 type. The electrodialyzer consisted of five Plexiglas compartments separated in alternating order by MK-40 cation-exchange and MA-40 anion-exchange membranes. The authors studied the dependence of the transport of copper(II) ammine complexes on the current density at copper concentration 0.025 M in the desalination compartment and 0.15 M ammonia concentration. The experiments lead to the conclusion that electrodialysis of copper(II) ammine complexes is possible only at current densities below the limiting values and that the transport is accompanied by decrease of the formation function of the complexes both in the membrane and in the solution of the concentrate receiving compartment.

Kireeva, L.D.; Shaposhnik, V.A.; Sorokina, V.I.

1987-09-10T23:59:59.000Z

317

Modeling cation diffusion in compacted water-saturatedNa-bentonite at low ionic strength  

SciTech Connect (OSTI)

Sodium bentonites are used as barrier materials for the isolation of landfills and are under consideration for a similar use in the subsurface storage of high-level radioactive waste. The performance of these barriers is determined in large part by molecular diffusion in the bentonite pore space. We tested two current models of cation diffusion in bentonite against experimental data on the relative apparent diffusion coefficients of two representative cations, sodium and strontium. On the 'macropore/nanopore' model, solute molecules are divided into two categories, with unequal pore-scale diffusion coefficients, based on location: in macropores or in interlayer nanopores. On the 'surface diffusion' model, solute molecules are divided into categories based on chemical speciation: dissolved or adsorbed. The macropore/nanopore model agrees with all experimental data at partial montmorillonite dry densities ranging from 0.2 (a dilute bentonite gel) to 1.7 kg dm{sup -3} (a highly compacted bentonite with most of its pore space located in interlayer nanopores), whereas the surface diffusion model fails at partial montmorillonite dry densities greater than about 1.2 kg dm{sup -3}.

Bourg, Ian C.; Sposito, Garrison; Bourg, Alain C.M.

2007-08-28T23:59:59.000Z

318

Diffusion of cations in chromia layers grown on iron-base alloys  

SciTech Connect (OSTI)

Diffusion of the cations Cr, Fe, Mn, and Ni in Cr{sub 2}O{sub 3} has been investigated at 1,173 K. The diffusion measurements were performed on chromia layers grown on the model alloys Fe-20Cr and Fe-20Cr-12Ni in order to consider effects of small amounts of dissolved alien cations in Cr{sub 2}O{sub 3}. The samples were diffusion annealed in H{sub 2}-H{sub 2}O at an oxygen partial pressure close to the Cr{sub 2}O{sub 3}/Cr equilibrium. For all tracers the lattice-diffusion coefficients are 3-5 orders of magnitude smaller than the grain-boundary diffusion coefficients. The lattice diffusivity of Mn is about two orders of magnitude greater than the other lattice-diffusion coefficients, especially in Cr{sub 2}O{sub 3} grown on Fe-20Cr-12Ni. The values of the diffusion coefficients for Cr, Fe, and Ni are in the same range. Diffusion of the tracers in Cr{sub 2}O{sub 3} grown on different alloys did not show significant differences with the exception of Mn.

Lobnig, R.E.; Hennesen, K.; Grabke, H.J. (Max-Planck Inst. fur Eisenforschung, Duesseldorf (West Germany)); Schmidt, H.P.

1992-02-01T23:59:59.000Z

319

Panchromatic Photopolymerizable Cationic Films Using Indoline and Squaraine Dye Based Photoinitiating Systems  

Science Journals Connector (OSTI)

The development of novel dyes usable as photoinitiators (PIs) in photoinitiating systems (PISs) of polymerization working under soft visible light irradiations (e.g., household halogen lamps or fluorescent bulbs, household LEDs, sunlight, etc.) is an ongoing challenge attracting great attention in various fields ranging from radiation curing, imaging, and optic technologies to medicine, material science, or microelectronic areas. ... Interestingly, upon very soft LED bulb exposures (?10 mW cm2), the D102/Iod/NVC combination exhibits good photoinitiating abilities for the cationic polymerization of EPOX under air (Figure 3(a) and Table S1 in the Supporting Information SI; blue LED, FC = 53%; green LED, FC = 51%; tack free coatings), whereas the SQ02/Iod photoinitiating system efficiently initiates the cationic polymerization of DVE-3 in laminate (Figure 3(b) and Table S1 in the Supporting Information; yellow LED, FC = 57%; red LED, FC = 87%; tack free coating). ... Fluorescence quenching rate const. of >60 typical electron donor-acceptor systems, such as fluorescing compds. of 3-pyrenecarboxylic acid (electron acceptor), and naphthalene (electron donor), and quenching compds. of tetracyanoethylene (electron acceptor), and N,N,N',N'-tetramethyl-p-phenylenediamine (electron donor), were measured in MeCN, and are correlated with the free enthalpy change, ?G23, involved in the actual electron transfer process 1F* ... Q ? F.-+. .... Q (F* is an excited mol., and Q is a non-excited mol.) in the encounter complex, and varying between +5 and -60 kcal/mole. ...

Pu Xiao; Frdric Dumur; Thanh Tuan Bui; Fabrice Goubard; Bernadette Graff; Fabrice Morlet-Savary; Jean Pierre Fouassier; Didier Gigmes; Jacques Laleve

2013-07-29T23:59:59.000Z

320

Humic Acid Metal Cation Interaction Studied by Spectromicroscopy Techniques in Combination with Quantum Chemical Calculations  

SciTech Connect (OSTI)

Humic acids (HA) have a high binding capacity towards traces of toxic metal cations, thus affecting their transport in aquatic systems. Eu(III)-HA aggregates are studied by synchrotron-based scanning transmission X-ray microscopy (STXM) at the carbon K-edge and laser scanning luminescence microscopy (LSLM) at the {sup 5}D{sub 0} {yields} {sup 7}F{sub 1,2} fluorescence emission lines. Both methods provide the necessary spatial resolution in the sub-micrometre range to resolve characteristic aggregate morphologies: optically dense zones embedded in a matrix of less dense material in STXM images correspond to areas with increased Eu(III) luminescence yield in the LSLM micrographs. In the C 1s-NEXAFS of metal-loaded polyacrylic acid (PAA), used as a HA model compound, a distinct complexation effect is identified. This effect is similar to trends observed in the dense fraction of HA/metal cation aggregates. The strongest complexation effect is observed for the Zr(IV)-HA/PAA system. This effect is confirmed by quantum chemical calculations performed at the ab initio level for model complexes with different metal centres and complex geometries. Without the high spatial resolution of STXM and LSLM and without the combination of molecular modelling with experimental results, the different zones indicating a 'pseudo'-phase separation into strong complexing domains and weaker complexing domains of HA would never have been identified. This type of strategy can be used to study metal interaction with other organic material.

Plaschke, M.; Rothe, J; Armbruster, M; Denecke, M; Naber, A; Geckeis, H

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Viscosity of liquid Fe at high pressure  

Science Journals Connector (OSTI)

Synchrotron x-ray radiography has been used to measure the viscosity of pure liquid Fe at high pressure and temperature in a large volume press. A probe sphere rising through liquid Fe at high pressure and temperature is imaged, in situ, allowing for the derivation of sample viscosity through a modified form of Stokes equation. The effect of pressure on viscosity is fit by the semi empirical framework for transport coefficients in liquid metals, providing experimental verification of constant viscosity at the pressure-dependent melting temperature of liquid Fe where no change in liquid structure occurs.

Michael D. Rutter; Richard A. Secco; Hongjian Liu; Takeyuki Uchida; Mark L. Rivers; Stephen R. Sutton; Yanbin Wang

2002-08-14T23:59:59.000Z

322

Catalyst for hydrotreating carbonaceous liquids  

DOE Patents [OSTI]

A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

Berg, Lloyd (Bozeman, MT); McCandless, Frank P. (Bozeman, MT); Ramer, Ronald J. (Idaho Falls, ID)

1982-01-01T23:59:59.000Z

323

Alien liquid detector and control  

SciTech Connect (OSTI)

An alien liquid detector employs a monitoring element and an energizing circuit for maintaining the temperature of the monitoring element substantially above ambient temperature. For this purpose an electronic circit controls a flow of heating current to the monitoring element. The presence of an alien liquid is detected by sensing a predetermined change in heating current flow to the monitoring element, e.g., to distinguish between water and oil. In preferred embodiments the monitoring element is a thermistor whose resistance is compared with a reference resistance and heating current through the thermistor is controlled in accordance with the difference. In one embodiment a bridge circuit senses the resistance difference; the difference may be sensed by an operational amplifier arrangement. Features of the invention include positioning the monitoring element at the surface of water, slightly immersed, so that the power required to maintain the thermistor temperature substantially above ambient temperature serves to detect presence of oil pollution at the surface.

Potter, B.M.

1980-09-02T23:59:59.000Z

324

Membrane Separations of Liquid Mixtures  

E-Print Network [OSTI]

MEMBRANE SEPARATIONS OF LIQUID MIXTURES Douglas R. Lloyd Separations Research Program Department of Chemical Engineering The University of Texas at Austin Austin, Texas In recent years considerable attention has been given to the need... for reduced energy costs in the chemical processing industry. A major portion of the energy consumed in this industry is associated with the separation and recovery of chemicals. Membrane processes offer energy-efficient, cost effective methods...

Lloyd, D. R.

325

EIA - International Energy Outlook 2008-Liquid Fuels  

Gasoline and Diesel Fuel Update (EIA)

Liquid Fuels Liquid Fuels International Energy Outlook 2008 Chapter 2 - Liquid Fuels World liquids consumption increases from 84 million barrels per day in 2005 to 99 million barrels per day in 2030 in the IEO2008 high price case. In the reference case, which reflects a price path that departs significantly from prices prevailing in the first 8 months of 2008, liquids use rises to 113 million barrels per day in 2030. Figure 26. World Liquids Production in the Reference Case, 1990-2030 (Million Barrels Oil Equivalent per Day). Need help, contact the National Energy Information Center at 202-586-8800. Figure Data Figure 27. World Production of Unconventional Liquid Fuels, 2005-2030 (Million Barrels Oil Equivalent per Day). Need help, contact the National Energy Information Center at 202-586-8800.

326

An artificial neural network to calculate pure ionic liquid densities without the need for any experimental data  

Science Journals Connector (OSTI)

Abstract In this study, a feed-forward artificial neural network, with three layers and seventeen neurons, was constructed to estimate the densities of a wide range of ionic liquid families including those based on the imidazolium, ammonium, pyridinium, pyrrolidinium, and isoquinolinium cations, together with various anions, as well as varying lengths of alkyl side chain lengths. The model is a function of the molecular weight and structure of the ionic liquid, and the system condition of temperature and pressure, which covers a temperature range of (273.15 to 393.17)K and a pressure range of (0.1 to 100)MPa. Therefore, no additional experimental data on the ionic liquid is required as input parameter(s), which makes this technique quite versatile. It was observed that the estimated values of densities of pure ionic liquids have very good agreement with the experimental data. The training correlating coefficient (R), the training performance (MSE), and the average absolute error on the training dataset were 0.99997, 6.04נ10?6, and 0.019%, respectively. The average absolute error value on the test dataset is 0.014%.

Mohammad-Reza Fatehi; Sona Raeissi; Dariush Mowla

2014-01-01T23:59:59.000Z

327

An infrared spectroscopy study of carbon monoxide adsorption on. alpha. -chromia surfaces: Probing oxidation states of coordinatively unsaturated surface cations  

SciTech Connect (OSTI)

CO adsorption on thermoevacuated, H{sub 2}-reduced and O{sub 2}-treated {alpha}-chromia surfaces was studied by IR spectroscopy in the temperature range 77-298 K. Coordinatively unsaturated (cus) Cr{sup 3+} cation sites, probably in 3-coordinate and to a much lesser extent 5-coordinate states, are the adsorption sites on H{sub 2}-reduced {alpha}-Cr{sub 2}O{sub 3}. The surface containing excess oxygen also exposes cus Cr{sup 4+} and Cr{sup 5+} sites. An empirical procedure is described which permits the determination of oxidation state and coordination number of the cus surface sites. This procedure is based on a correlation between C-O stretching frequency and electric field strength exerted by the cation. The latter is calculated from Pauling's strength of the electrostatic bond and effective ionic radii, both of which take the cation coordination into account.

Zaki, M.I.; Knoezinger, H. (Universitaet Muenchen (West Germany))

1989-10-01T23:59:59.000Z

328

Transient-Liquid-Phase and Liquid-Film-Assisted Joining ofCeramics  

SciTech Connect (OSTI)

Two joining methods, transient-liquid-phase (TLP) joining and liquid-film-assisted joining (LFAJ), have been used to bond alumina ceramics. Both methods rely on multilayer metallic interlayers designed to form thin liquid films at reduced temperatures. The liquid films either disappear by interdiffusion (TLP) or promote ceramic/metal interface formation and concurrent dewetting of the liquid film (LFAJ). Progress on extending the TLP method to lower temperatures by combining low-melting-point (<450 C) liquids and commercial reactive-metal brazes is described. Recent LFAJ work on joining alumina to niobium using copper films is presented.

Sugar, Joshua D.; McKeown, Joseph T.; Akashi, Takaya; Hong, SungM.; Nakashima, Kunihiko; Glaeser, Andreas M.

2005-02-09T23:59:59.000Z

329

Optical and electronic properties of mixed Ag-Au tetramer cations  

SciTech Connect (OSTI)

We present experimental and theoretical studies of the optical response of mixed Ag {sub n} Au {sub 4?n}{sup +} (n=13) clusters in the photon energy range ?? = 1.93.5 eV. Absorption spectra are recorded by a newly built longitudinal molecular beam depletion spectroscopy apparatus providing lower limits to absolute photodissociation cross sections. The experimental data are compared to optical response calculations in the framework of long-range corrected time-dependent density functional theory with initial cluster geometries obtained by the unbiased Birmingham Cluster Genetic Algorithm coupled with density functional theory. Experiments and excited state calculations shed light on the structural and electronic properties of the mixed Ag-Au tetramer cations.

Shayeghi, A., E-mail: shayeghi@cluster.pc.chemie.tu-darmstadt.de; Schfer, R. [Eduard-Zintl-Institut, Technische Universitt Darmstadt, Alarich-Weiss-Strae 8, 64287 Darmstadt (Germany)] [Eduard-Zintl-Institut, Technische Universitt Darmstadt, Alarich-Weiss-Strae 8, 64287 Darmstadt (Germany); Heard, C. J.; Johnston, R. L. [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)] [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

2014-02-07T23:59:59.000Z

330

Self-Assembly of Hexanuclear Clusters of 4f and 5f Elements with Cation Specificity  

SciTech Connect (OSTI)

Six hexanuclear clusters of 4f and 5f elements were synthesized by room-temperature slow concentration experiments. Cerium(IV), thorium(IV), and plutonium(IV) each form two different hexanuclear clusters, among which the cerium and plutonium clusters are isotypic, whereas the thorium clusters show more diversity. The change in ionic radii of approximately 0.08 between these different metal ions tunes the cavity size so that NH{sub 4}{sup +} (1.48 ) has the right dimensions to assemble the cerium and plutonium clusters, whereas Cs{sup +} (1.69 ) is necessary to assemble the thorium clusters. If these cations are not used in the reactions, only amorphous material is obtained.

Diwu, J.; Good, Justin J.; DiStefano, Victoria H.; Albrecht-Schmitt, Thomas E.

2011-01-01T23:59:59.000Z

331

Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy  

E-Print Network [OSTI]

spectra measured for aqueous formate and acetate solutions containing lithium, sodium, and potassium simulations and other experi- ments. The carbon K-edge spectra of the acetate carbonyl feature centered near with the carboxylate groups of the model carboxylate anions formate and acetate, using liquid microjet technology

Cohen, Ronald C.

332

Intense pseudotransport of a cationic drug mediated by vacuolar ATPase: Procainamide-induced autophagic cell vacuolization  

SciTech Connect (OSTI)

Cationic drugs frequently exhibit large apparent volumes of distribution, consistent with various forms of cellular sequestration. The contributions of organelles and metabolic processes that may mimic drug transport were defined in human vascular smooth muscle cells. We hypothesized that procainamide-induced vacuolar cytopathology is driven by intense pseudotransport mediated by the vacuolar (V)-ATPase and pursued the characterization of vesicular trafficking alterations in this model. Large amounts of procainamide were taken up by intact cells (maximal in 2 h, reversible upon washout, apparent K{sub M} 4.69 mM; fluorometric determination of cell-associated drug). Procainamide uptake was extensively prevented or reversed by pharmacological inhibition of the V-ATPase with bafilomycin A1 or FR 167356, decreased at low extracellular pH and preceded vacuolar cell morphology. However, the uptake of procainamide was unaffected by mitochondrial poisons that reduced the uptake of rhodamine 6G. Large vacuoles induced by millimolar procainamide were labeled with the late endosome/lysosome markers Rab7 and CD63 and the autophagy effector LC3; their osmotic formation (but not procainamide uptake) was reduced by extracellular mannitol and parallel to LC3 II formation. Procainamide-induced vacuolization is associated with defective endocytosis of fluorophore-labeled bovine serum albumin, but not with induction of the unfolded protein response. The contents of a vacuole subset slowly ({>=} 24 h) become positive for Nile red staining (phospholipidosis-like response). V-ATPase-driven ion trapping is a form of intense cation pseudotransport that concerns the uncharged form of the drugs, and is associated with a vacuolar, autophagic and evolutive cytopathology and profound effects on vesicular trafficking.

Morissette, Guillaume [Centre de recherche en Rhumatologie et Immunologie, Centre Hospitalier Universitaire de Quebec, Quebec QC, G1V 4G2 (Canada); Centre de recherche en Rhumatologie et Immunologie, Centre Hospitalier Universitaire de Quebec, Quebec QC, G1V 4G2 (Canada); Lodge, Robert [Centre de recherche en Infectiologie, Centre Hospitalier Universitaire de Quebec, Quebec QC, G1V 4G2 (Canada); Marceau, Francois [Centre de recherche en Rhumatologie et Immunologie, Centre Hospitalier Universitaire de Quebec, Quebec QC, G1V 4G2 (Canada); Centre de recherche en Rhumatologie et Immunologie, Centre Hospitalier Universitaire de Quebec, Quebec QC, G1V 4G2 (Canada)], E-mail: francois.marceau@crchul.ulaval.ca

2008-05-01T23:59:59.000Z

333

Influence of relaxation transitions on radiation-initiated cationic graft polymerization. [Gamma radiation  

SciTech Connect (OSTI)

Radiation grafting of vinyl n-butyl ether (VBE) to polyvinyl chloride (PVC) over a broad temperature range was investigated. The relaxation transitions in the PVC/VBE system were also determined. Grafting of vinyl alkyl ethers proceeds entirely by a cationic mechanism in a reaction medium that has been dried to a water concentration no greater than 0.1-1.0 ppm. In this connection, the diffusion properties of water in the temperature region were studied. Commercial films of unplasticized PVC (thickness 200 M); were subjected to swelling in two systems: in a 50% solution of VBE in benzene at 25/sup 0/C, and in the pure monomer at 40/sup 0/C. The reaction mixtures were first dried over metallic sodium in a deaerated atmosphere. The specimens were irradiated in a Co gamma-radiation unit to a dose of 10 kGy at a dose rate of 3 Gy/sec. The first reaction mixture was investigated over a range of temperatures from -60/sup 0/ to +70/sup 0/C, and the second from -15/sup 0/ to +50/sup 0/C. The degree of grafting was determined from the increase in weight of the original ungrafted film. The temperature was held to within +/-1/sup 0/C. The relaxation transitions in the swollen polymer systems were determined by two methods, thermostimulated current (TSC) and thermomechanics (TM). It was found that in the region of the glass transition of a swollen PVC-VBE system, radiation-initiated cationic graft polymerization proceeds at a maximal rate, and there are changes in state of the water molecules (the agents of breaking the ion reaction chain) and in their diffusion properties within the matrix.

Kudryavtsev, V.N.; Kabanov, V.Ya.; Chalykh, A.E.; Spitsyn, V.I.

1982-05-01T23:59:59.000Z

334

Closed cycle liquid helium refrigerators  

Science Journals Connector (OSTI)

We have developed closed cycle liquid helium refrigerators using a Joule Thomson circuit precooled by commercially available two staged Gifford Mac Mahon cryocoolers. The Joule Thomson counterflow heat exchangers are modular and have been thermo-hydraulically characterized. Fully automatic cool down and operation are achieved by two pneumatically driven by pass and expansion valves. Several apparatus have been built or are under assembly with cooling power ranging from 100 mW up to 5 Watt, for temperature ranging from 2.8 K up to 4.5 K. A trouble free operation with several warm up and cool down cycles has been proven over 7000 hours.

G. Claudet; R. Lagnier; A. Ravex

1992-01-01T23:59:59.000Z

335

Flowing Liquid Crystal Simulating the Schwarzschild Metric  

E-Print Network [OSTI]

We show how to simulate the equatorial section of the Schwarzschild metric through a flowing liquid crystal in its nematic phase. Inside a liquid crystal in the nematic phase, a traveling light ray feels an effective metric, whose properties are linked to perpendicular and parallel refractive indexes, $n_o$ e $n_e$ respectively, of the rod-like molecule of the liquid crystal. As these indexes depend on the scalar order parameter of the liquid crystal, the Beris-Edwards hydrodynamic theory is used to connect the order parameter with the velocity of a liquid crystal flow at each point. This way we calculate a radial velocity profile that simulates the equatorial section of the Schwarzschild metric, in the region outside of Schwarzschild's radius, in the nematic phase of the liquid crystal. In our model, the higher flow velocity can be of the order of some meters per second.

Erms R. Pereira; Fernando Moraes

2010-11-21T23:59:59.000Z

336

Study of Liquid Dynamics by Neutron Scattering  

Science Journals Connector (OSTI)

This paper reviews the information about the collective motions of atoms in liquids which can be obtained from neutron scattering experiments with particular attention to the rare gases and liquid metals. The current status of the theoretical interpretation is examined. Coherent neutron scattering from a monatomic liquid gives directly the spectrum of the correlation function for density fluctuations in the system for wavelengths in the range 110 . The results have a dual interpretation. On the one hand they may be understood in terms of a viscoelastic theory which takes into account the microscopic structure of the liquid; on the other hand fluctuations at these wavelengths may be interpreted in terms of vibrational modes as in an amorphous solid. The paper attempts to reconcile these two points of view. Qualitative differences between liquidargon and the liquid metals are discussed with reference to the connection between the neutron results and the microscopic properties of these liquids.

P. Schofield

1969-01-01T23:59:59.000Z

337

Mechanism of constitution liquid film migration  

SciTech Connect (OSTI)

Liquid film migration (LFM) in liquid phase sintering classically involves a large metastable liquid volume adjacent to solid, and migration occurs at an isolated solid-liquid (S-L) interface. Constitutional liquid film migration (CLFM), discovered in alloy 718, has major characteristics similar to those of LFM, except that the metastable liquid is from the constitutional liquation of precipitates on the grain boundary. The similarity between LFM and CLFM has led to the theory that coherency lattice strain responsible for LFM is also responsible for CLFM. The coherency strain hypothesis was tested in this study by evaluating whether the Hillert model of LFM would also apply for CLFM. Experimental results of CLFM in alloy 718 showed that migration velocity followed the trend predicted by the Hillert model. This indicates that the coherency strain hypothesis of LFM also applies for CLFM and that the coherency lattice strain responsible for LFM is also the driving force for CLFM.

NONE

1999-06-01T23:59:59.000Z

338

Multicomponent Geothermometers | Open Energy Information  

Open Energy Info (EERE)

Multicomponent Geothermometers Multicomponent Geothermometers Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Multicomponent Geothermometers Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Liquid Geothermometry Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Dictionary.png Multicomponent Geothermometers: The multicomponent geothermometry method consists of using full chemical analyses of water samples to compute the saturation indices (log(Q/K)) of reservoir minerals over a range of temperatures. The saturation indices are graphed as a function of temperature, and the clustering of log(Q/K) curves

339

Silica Geothermometers | Open Energy Information  

Open Energy Info (EERE)

Silica Geothermometers Silica Geothermometers Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Silica Geothermometers Details Activities (0) Areas (0) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Liquid Geothermometry Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Used to estimate reservoir temperatures. Dictionary.png Silica Geothermometers: No definition has been provided for this term. Add a Definition Introduction Some experts have stated that the factor that changes the risk assessment of a geothermal prospect the fastest is obtaining attractive chemical confirmation (geothermometry, gas analyses) that a thermal resource exists

340

Solubility of Carbohydrates in Ionic Liquids  

Science Journals Connector (OSTI)

Laboratrio Nacional de Energia e Geologia, I.P., Unit of Bioenergy, Estrada do Pao do Lumiar 22, 1649-038, Lisboa, Portugal ... The aim of this Review is to assess the current state of knowledge regarding the solubility of carbohydrates in ionic liquids but not on modifications of carbohydrates in ionic liquids. ... We herein collect all of the available literature data about the solubility of various carbohydrates in ionic liquids and highlight their interactions with carbohydrates. ...

Ma?gorzata Ewa Zakrzewska; Ewa Bogel-?ukasik; Rafa? Bogel-?ukasik

2010-01-07T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Tokamak with liquid metal toroidal field coil  

DOE Patents [OSTI]

Tokamak apparatus includes a pressure vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within the pressure vessel defines a toroidal space within the liner. Liquid metal fills the reservoir outside said liner. Electric current is passed through the liquid metal over a conductive path linking the toroidal space to produce a toroidal magnetic field within the toroidal space about the major axis thereof. Toroidal plasma is developed within the toroidal space about the major axis thereof.

Ohkawa, Tihiro (La Jolla, CA); Schaffer, Michael J. (San Diego, CA)

1981-01-01T23:59:59.000Z

342

Liquid metal cooled nuclear reactor plant system  

DOE Patents [OSTI]

A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting for fuel decay during reactor shutdown, or heat produced during a mishap. The reactor system is enhanced with sealing means for excluding external air from contact with the liquid metal coolant leaking from the reactor vessel during an accident. The invention also includes a silo structure which resists attack by leaking liquid metal coolant, and an added unique cooling means.

Hunsbedt, Anstein (Los Gatos, CA); Boardman, Charles E. (Saratoga, CA)

1993-01-01T23:59:59.000Z

343

Gas well operation with liquid production  

SciTech Connect (OSTI)

Prediction of liquid loading in gas wells is discussed in terms of intersecting tubing or system performance curves with IPR curves and by using a more simplified critical velocity relationship. Different methods of liquid removal are discussed including such methods as intermittent lift, plunger lift, use of foam, gas lift, and rod, jet, and electric submersible pumps. Advantages, disadvantages, and techniques for design and application of the methods of liquid removal are discussed.

Lea, J.F.; Tighe, R.E.

1983-02-01T23:59:59.000Z

344

To appear in Proceedings, International Symposium on Requirements Engineering, York, England, March 26-27, 1995 1 Consistency Checking of SCR-Style Requirements Speci cations  

E-Print Network [OSTI]

26-27, 1995 1 Consistency Checking of SCR-Style Requirements Speci cations Constance Heitmeyer checking that mechanically checks requirements speci cations, expressed in the SCR tab- ular notation. As background, the SCR notation for specifying requirements is reviewed. A formal re- quirements model

345

JOURNAL DE PHYSIQUE Colloque C1, suppliment au no 4, Tome 38, Avril 1977, page C1-207 KINETICS OF THE CATION REDISTRIBUTION IN MAGNESIUM FERRITES  

E-Print Network [OSTI]

OF THE CATION REDISTRIBUTION IN MAGNESIUM FERRITES V. A. M. BRABERS and J. KLERK Department of Physics distribution des ions Mg2+et Fe3+sur les sites tetrakdriques et octakdriquesde ferrites de magnesium est Ctudi properties of ferrites. The cation distribution in magnesium ferrite has been studied by various authors

Boyer, Edmond

346

Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R. Krueger, S. Vyas,a  

E-Print Network [OSTI]

Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R The nuclear magnetic resonance NMR spectra for the I=3/2 23 Na cation dissolved into filamentous bacteriophage the 23 Na nuclear quadrupole moment and the electric field gradient produced by the negatively charged Pf

Augustine, Mathew P.

347

ReproducedfromJournalofEnvironmentalQuality.PublishedbyASA,CSSA,andSSSA.Allcopyrightsreserved. Cation Bonding: A New Perspective on the Sorption of Polycyclic  

E-Print Network [OSTI]

JournalofEnvironmentalQuality.PublishedbyASA,CSSA,andSSSA.Allcopyrightsreserved. Cation­ Bonding: A New Perspective on the Sorption of Polycyclic Aromatic Hydrocarbons to Mineral potential cation­ interactions between Potential mechanisms controlling NOC sorption to donors both spectroscopic and batch sorption methods. Quadrupolar split- primarily on batch sorption

Herbert, Bruce

348

Mechanism of Cation Exchange Process for Epitaxy of Superconducting HgBa2CaCu2O6 Films and Passive Microwave Devices  

E-Print Network [OSTI]

cations into, the lattice of epitaxial Tl2Ba2CaCu2O8 (Tl-2212) or TlBa2CaCu2O7 (Tl-1212) precursor films. Aiming at the remained issues in understanding the mechanism of the cation exchange (CE) process, this thesis work has studied the reversibility of CE...

Zhao, Hua

2007-12-17T23:59:59.000Z

349

Liquid metal Flow Meter - Final Report  

SciTech Connect (OSTI)

Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

Andersen C, Hoogendoom S, Hudson B, Prince J, Teichert K, Wood J, Chase K

2007-01-30T23:59:59.000Z

350

Exciplex Fluorescence Thermometry of Liquid Fuel  

Science Journals Connector (OSTI)

An experimental program is described that investigates the application of exciplex fluorescence to the internal thermometry of flowing liquid decane in the temperature range 24-91C....

Stufflebeam, John H

1989-01-01T23:59:59.000Z

351

,"Natural Gas Plant Liquids Proved Reserves"  

U.S. Energy Information Administration (EIA) Indexed Site

,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Natural Gas Plant Liquids Proved Reserves",49,"Annual",2012,"6301979" ,"Release...

352

Viscosity of Liquid Sodium and Potassium  

Science Journals Connector (OSTI)

2 November 1936 research-article Viscosity of Liquid Sodium and Potassium Y. S. Chiong The Royal Society is collaborating with JSTOR to digitize, preserve, and extend...

1936-01-01T23:59:59.000Z

353

,"Natural Gas Plant Liquids Proved Reserves"  

U.S. Energy Information Administration (EIA) Indexed Site

,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Natural Gas Plant Liquids Proved Reserves",49,"Annual",2013,"6301979" ,"Release...

354

Closed-field capacitive liquid level sensor  

DOE Patents [OSTI]

A liquid level sensor based on a closed field circuit comprises a ring oscillator using a symmetrical array of plate units that creates a displacement current. The displacement current varies as a function of the proximity of a liquid to the plate units. The ring oscillator circuit produces an output signal with a frequency inversely proportional to the presence of a liquid. A continuous liquid level sensing device and a two point sensing device are both proposed sensing arrangements. A second set of plates may be located inside of the probe housing relative to the sensing plate units. The second set of plates prevent any interference between the sensing plate units.

Kronberg, J.W.

1995-01-01T23:59:59.000Z

355

Seeing clearly through a liquid | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Influencing Quantitative Liquid (Scanning) Transmission Electron Microscopy." 2014. Chemical Communications 50(8):4873-4880. DOI: 10.1039c3cc48479c Related Staff: James Evans...

356

Coal and Coal-Biomass to Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Coal-Biomass to Liquids News Gasifipedia Coal-Biomass Feed Advanced Fuels Synthesis Systems Analyses International Activity Project Information Project Portfolio Publications...

357

Cryocompressed Hydrogen Storage and Liquid Delivery  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Cryocompressed Hydrogen Storage & Liquid Delivery Jacob Leachman, Ph.D. Assistant Professor DOE H 2 Transmission & Delivery Workshop 2262014 H Y P E R H drogen roperties for...

358

Onsite Wastewater Treatment Systems: Liquid Chlorination  

E-Print Network [OSTI]

This publication explains the process, components, legal requirements, factors affecting performance, and maintenance needs of liquid chlorination systems for onsite wastewater treatment....

Weaver, Richard; Lesikar, Bruce J.; Richter, Amanda; O'Neill, Courtney

2008-10-23T23:59:59.000Z

359

Hazardous Liquid Pipelines and Storage Facilities (Iowa)  

Broader source: Energy.gov [DOE]

This statute regulates the permitting, construction, monitoring, and operation of pipelines transporting hazardous liquids, including petroleum products and coal slurries. The definition used in...

360

The response of a point source in a liquid layer overlying a liquid half space  

E-Print Network [OSTI]

The response to a harmonic point source in a liquid layer overlying a liquid half space is computed as a function of frequency. Included are the contributions form all normal modes that occur, and the branch-line integral ...

Greenfield, Roy

1962-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Behavior of hydrophobic ionic liquids as liquid membranes on phenol removal: Experimental study and optimization  

E-Print Network [OSTI]

Room temperature ionic liquids show potential as an alternative to conventional organic membrane solvents mainly due to their properties of low vapor pressure, low volatility and they are often stable. In the present work, the technical feasibilities of room temperature ionic liquids as bulk liquid membranes for phenol removal were investigated experimentally. Three ionic liquids with high hydrophobicity were used and their phenol removal efficiency, membrane stability and membrane loss were studied. Besides that, the effects of several parameters, namely feed phase pH, feed concentration, NaOH concentration and stirring speeds on the performance of best ionic liquid membrane were also evaluated. Lastly, an optimization study on bulk ionic liquid membrane was conducted and the maximum phenol removal efficiency was compared with the organic liquid membranes. The preliminary study shows that high phenol extraction and stripping efficiencies of 96.21% and 98.10%, respectively can be achieved by ionic liquid memb...

Ng, Y S; Hashim, M A

2014-01-01T23:59:59.000Z

362

Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product  

DOE Patents [OSTI]

Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

Davis, Benjamin L; Rekken, Brian D

2014-04-01T23:59:59.000Z

363

Cationic triple-chain amphiphiles facilitate vesicle fusion compared to double-chain or single-chain analogues  

E-Print Network [OSTI]

-chain analogues. Two types of vesicle fusion experiments were conducted, mixing of oppositely charged vesicles-determining step for certain cell types is endosomal escape, which can occur either by a fusion or disruptionCationic triple-chain amphiphiles facilitate vesicle fusion compared to double-chain or single

Smith, Bradley D.

364

THE DETERMINATIVE ROLE OF THE EXCHANGE CATION AND LAYER-CHARGE DENSITY OF SMECTITE ON AFLATOXIN ADSORPTION  

Science Journals Connector (OSTI)

...dioxin, and atrazine reported in the literature. Yet, the types of the exchange cations...was supplied by Texas AgriLife Research Bioenergy Initiative Program, Texas Corn Producers...aflatoxin through the use of clay: A review. Food Additives Contaminants, Part...

Youjun Deng; Lian Liu; Ana Luisa Barrientos Velzquez; Joe B. Dixon

365

THE DETERMINATIVE ROLE OF THE EXCHANGE CATION AND LAYER-CHARGE DENSITY OF SMECTITE ON AFLATOXIN ADSORPTION  

Science Journals Connector (OSTI)

...more crowded exchange cation environment may have a better size-match...and atrazine reported in the literature. Yet, the types of the exchange...by Texas AgriLife Research Bioenergy Initiative Program, Texas...through the use of clay: A review. Food Additives Contaminants...

Youjun Deng; Lian Liu; Ana Luisa Barrientos Velzquez; Joe B. Dixon

366

Heating-Induced Micelle to Vesicle Transition in the Cationic-Anionic Surfactant Systems: Comprehensive Study and Understanding  

E-Print Network [OSTI]

Heating-Induced Micelle to Vesicle Transition in the Cationic-Anionic Surfactant Systems, 2004; In Final Form: January 6, 2005 Heating-induced micelle to vesicle transition (MVT), which has classes: Class A and B. Heating-induced MVT was observed in Class A at certain total surfactant

Huang, Jianbin

367

Modulation of a membrane lipid lamellar?nonlamellar phase transition by cationic lipids: A measure for transfection efficiency  

SciTech Connect (OSTI)

Synthetic cationic lipids can be used as DNA carriers and are regarded to be the most promising non-viral gene carriers. For this investigation, six novel phosphatidylcholine (PC) cationic derivatives with various hydrophobic moieties were synthesized and their transfection efficiencies for human umbilical artery endothelial cells (HUAEC) were determined. Three compounds with relatively short, myristoleoyl or myristelaidoyl 14:1 chains exhibited very high activity, exceeding by {approx}10 times that of the reference cationic derivative dioleoyl ethylPC (EDOPC). Noteworthy, cationic lipids with 14:1 hydrocarbon chains have not been tested as DNA carriers in transfection assays previously. The other three lipids, which contained oleoyl 18:1 and longer chains, exhibited moderate to weak transfection activity. Transfection efficiency was found to correlate strongly with the effect of the cationic lipids on the lamellar-to-inverted hexagonal, L{sub {alpha}} {yields} H{sub II}, phase conversion in dipalmitoleoyl phosphatidylethanolamine dispersions (DPoPE). X-ray diffraction on binary DPoPE/cationic lipid mixtures showed that the superior transfection agents eliminated the direct L{sub {alpha}} {yields} H{sub II} phase transition and promoted formation of an inverted cubic phase between the L{sub {alpha}} and H{sub II} phases. In contrast, moderate and weak transfection agents retained the direct L{sub {alpha}} {yields} H{sub II} transition but shifted to higher temperatures than that of pure DPoPE, and induced cubic phase formation at a later stage. On the basis of current models of lipid membrane fusion, promotion of a cubic phase by the high-efficiency agents may be considered as an indication that their high transfection activity results from enhanced lipoplex fusion with cellular membranes. The distinct, well-expressed correlation established between transfection efficiency of a cationic lipid and the way it modulates nonlamellar phase formation of a membrane lipid could be useful as a criterion to assess the quality of lipid carriers and for rational design of new and superior nucleotide delivery agents.

Tenchov, Boris G.; Wang, Li; Koynova, Rumiana; MacDonald, Robert C. (NWU)

2010-01-18T23:59:59.000Z

368

Spiers Memorial Lecture Recent experimental advances in studies of liquid/liquid  

E-Print Network [OSTI]

complicated processes such as molecular transport across cell membranes. A variety of techniques have been on the interaction of a hydrophobic surface with water, and ion and solute transport across these and other liquid/hydrophilic properties of liquid/ liquid interfaces. In biological systems, protein folding and membrane formation rely

Richmond, Geraldine L.

369

Arrays and Cascades of Fluorescent Liquid-Liquid Waveguides: Broadband Light Sources for  

E-Print Network [OSTI]

Arrays and Cascades of Fluorescent Liquid-Liquid Waveguides: Broadband Light Sources) microchannel waveguides with liquid cores containing fluorescent dyes, excited by incident light from an external halogen bulb. Simultaneous use of multiple fluorophores in a common solution, in a single L2 light

Prentiss, Mara

370

Specular neutron reflection at the mica/water interface - irreversible adsorption of a cationic dichain surfactant  

Science Journals Connector (OSTI)

A novel experimental method to exploit specular neutron reflection from the surface of mica at the solid/liquid interface is reported. The approach involves supporting a thin mica crystal on a silicon substrate. The applicability of this technique for mica is demonstrated by adsorption of a dichain surfactant to form a complete unhydrated bilayer at this interface and its partial removal by washing and ion exchange.

Browning, K.L.

2014-09-20T23:59:59.000Z

371

Supramolecular Structure of Pigment-Protein Complexes in Relation to the Chlorophyll a Fluorescence of Chloroplasts at 25 C or at -196 C: Cation Effect, pH Effect and Trypsinolysis  

Science Journals Connector (OSTI)

The oligomeric forms of the thylakoid pigment-protein complexes (LHCP1, LHCP2 and CPIa) are dissociated to their constituents in the presence of cations (Argyroudi-Akoyunoglou, 1980). Cations have been also found...

J. H. Argyroudi-Akoyunoglou; G. Akoyunoglou

1984-01-01T23:59:59.000Z

372

Communications Counterion Effects in Liquid Crystal  

E-Print Network [OSTI]

of nanostructured CdS templated directly with ion-doped liquid crystals.13,14 In both cases the mesoporous solidCommunications Counterion Effects in Liquid Crystal Templating of Nanostructured CdS V. Tohver, P system, nanostructured particles consisting of alternat- ing sheets of CdS and oligomeric vinyl alcohol

Braun, Paul

373

Fiber-optic liquid level sensor  

DOE Patents [OSTI]

A fiber-optic liquid level sensor measures the height of a column of liquid through the hydrostatic pressure it produces. The sensor employs a fiber-optic displacement sensor to detect the pressure-induced displacement of the center of a corrugated diaphragm.

Weiss, Jonathan D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

374

Liquid Biofuels Strategies and Policies in selected  

E-Print Network [OSTI]

June 2011 Liquid Biofuels Strategies and Policies in selected African Countries A review of some of the challenges, activities and policy options for liquid biofuels Prepared for PISCES by Practical Action Biofuels Strategies and Policies in selected African Countries Although this research is funded by DFID

375

Cholesteric Pitch of Lyotropic Polymer Liquid Crystals  

Science Journals Connector (OSTI)

Cholesteric Pitch of Lyotropic Polymer Liquid Crystals ... The cholesteric pitch P of semiflexible helical polymer solutions was formulated using a threaded equivalent freely jointed chain model. ... The structure of cholesteric liquid crystals is characterized by the cholesteric pitch P or the cholesteric wavenumber qc (?2?/P). ...

Takahiro Sato; Jun Nakamura; Akio Teramoto; Mark M. Green

1998-02-03T23:59:59.000Z

376

Dynamic nuclear polarization of liquid 3He  

Science Journals Connector (OSTI)

...March 1998 research-article Dynamic nuclear polarization of liquid 3He B. Bleaney...3PU, UK Methods of producing dynamic nuclear polarization of liquid 3He by the solid...method have been proposed using enhanced nuclear paramagnetic resonance in Van Vleck compounds...

1998-01-01T23:59:59.000Z

377

Remarks on Liquid Wall Research Mohamed Abdou  

E-Print Network [OSTI]

Remarks on Liquid Wall Research Mohamed Abdou Professor Mechanical and Aerospace Engineering UCLA physicists and engineering scientists · Enhances synergism between IFE and MFE · Provides excellent disciplines. #12;Several "Ideas" Have Been Proposed for Liquid Walls Fluids 1) High-conductivity, low Pr

California at Los Angeles, University of

378

Taylor Instability of Incompressible Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

\ UNCLASSIFIED ' ;c ,. ' UNCLASSIFIED AECU-29'79 Subject Category: PHYSICS UNITED STATES ATOMIC ENERGY COMMISSION TAYLOR INSTABILITY OF INCOMPRESSIBLE LIQUIDS BY Enrico Fermi John von Neumann , _ November 1955 [ TIS Issuance D.a&?] Los Alamos Scientific Labqratqry Los Alamos, New Mexico Technical Information Service, Ooic Ridge, Tennessee DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available document. original I , The date for Part 1 is September 4, 1951. The date for Part 2 is August 19, 1953. Work performed under Contract PTo. W-7405-Eng-36. The Atomic Energy Commission makes no representation or warranty as to the accuracy or usefulness of the lnformatlon or statements contained

379

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for the recovery of liquid hydrocarbons from a subterranean hydrocarbon-bearing formation. It comprises injecting natural gas into the formation via a well in fluid communication with the formation, the natural gas being at a temperature which is insufficient to significantly mobilize light density oil in the formation and at a pressure such that the natural gas is immiscible with the light density oil in the formation, the natural gas being injected in a volume sufficient to contact light density oil in the formation within a radius from the well of about 50 meters; shutting in the well for a period of time of about 1 to about 100 days which is sufficient to render the contacted light density oil mobile; and producing the light density oil which has been mobilized by solution of the natural gas from the well.

Haines, H.K.; Monger, T.G.; Kenyon, D.E.; Galvin, L.J.

1991-06-25T23:59:59.000Z

380

Viscosity of Liquid He II  

Science Journals Connector (OSTI)

The viscosity of liquid He4 has been measured between 1.10K and the lambda point. A new type of viscometer was used, based on the damping of the transverse vibrations of a fine wire stretched between two rigid supports. The simplicity of the hydrodynamic problem and the low nuisance damping of the wire make this technique particularly appropriate for the measurement of small viscosities. The smoothed data are presented and found to be in good agreement with the latest rotating cylinder viscometer results. In different experimental runs the vibration frequency was varied by a factor of seven and the wire diameter by a factor of three. There was no evidence of systematic trend due to mean free-path effects or geometrical corrections.

J. T. Tough; W. D. McCormick; J. G. Dash

1963-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Air Liquide - Biogas & Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquide - Biogas & Fuel Cells Liquide - Biogas & Fuel Cells ■ Hydrogen Energy ■ Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry, health and the environment Renewable H 2 to Fuel Cell, Integrated Concept Purified Biogas 3 Air Liquide, world leader in gases for industry, health and the environment Renewable H 2 to Fuel Cell, Non-Integrated Concept Landfill WWTP digester Biogas membrane Pipeline quality methane CH4 Pipeline Hydrogen Production To Fuel Cell Vehicles Stationary Fuel Cells With H2 purification Stationary Fuel Cells Direct Conversion Directed Biomethane 4 Air Liquide, world leader in gases for industry, health and the environment Biogas Sources in the US ■ Landfill gas dominates (~4,000 Nm3/h typical)

382

Frostbite Theater - Liquid Nitrogen Experiments - Insulators!  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Popping Film Canisters! Popping Film Canisters! Previous Video (Popping Film Canisters!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Show!) Liquid Nitrogen Show! Insulators! Cups full of water are placed into bowls of liquid nitrogen! Which cup will insulate the best? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And these are two plastic cups! Joanna: Let's see which cup is the better insulator! Steve: Okay! So, um, how do we do that? Joanna: Well, we'll pour water into each of the cups and then we'll pour the liquid nitrogen into each of the bowls. If we then place the cup in the bowl, the heat from the water will try to pass through the cup into the

383

Frostbite Theater - Liquid Nitrogen Experiments - Freezing Balloons!  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Season Two Bloopers Season Two Bloopers Previous Video (Season Two Bloopers) Frostbite Theater Main Index Next Video (Instant Liquid Nitrogen Balloon Party!) Instant Liquid Nitrogen Balloon Party! Freezing Balloons! What happens when a balloon full of air is plunged into a container full of liquid nitrogen? Play the video to find out! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And this is a really big balloon! Joanna: Let's see what happens when we place the balloon in the liquid nitrogen! Steve: Okay! Wait! Wait! Wait! Wait! Wait! Isn't the balloon going to pop? Joanna: We'll see! Steve: Aw, man... Huh. Okay, so the balloon didn't pop. But, there's

384

Sewage sludge dewatering using flowing liquid metals  

DOE Patents [OSTI]

A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

Carlson, Larry W. (Oswego, IL)

1986-01-01T23:59:59.000Z

385

A Liquid Layer Solution for the Grid | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

A Liquid Layer Solution for the Grid A Liquid Layer Solution for the Grid A Liquid Layer Solution for the Grid September 15, 2011 - 2:47pm Addthis The Liquid Metal Battery is comprised of liquid metal electrodes and a liquid electrolyte of differing densities, which allows the liquids to separate and stratify without the need for any solid separator. The Liquid Metal Battery is comprised of liquid metal electrodes and a liquid electrolyte of differing densities, which allows the liquids to separate and stratify without the need for any solid separator. Kristina Pflanz Writer & Contractor, Advanced Research Projects Agency - Energy What does this mean for me? With its all-liquid design, this battery is much more efficient than today's rechargeable batteries, which use 80-90% of the space to hold

386

Neutron Scattering from Liquid Helium at Large Momentum Transfer  

Science Journals Connector (OSTI)

......letter Letters to the Editor Neutron Scattering from Liquid Helium at Large...Vol. 46 (1971), No. 1 Neutron Scattering from Liquid Helium at Large...Feynman diagram for the elastic scattering of a neutron from liquid helium, where......

Sigenobu Sunakawa; Kazuo Okajima; Kiyohisa Matsuda

1971-07-01T23:59:59.000Z

387

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315)K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 710?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henrys law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

388

Deep Geothermal Reservoir Temperatures in the Eastern Snake River Plain, Idaho using Multicomponent Geothermometry  

SciTech Connect (OSTI)

The U.S. Geological survey has estimated that there are up to 4,900 MWe of undiscovered geothermal resources and 92,000 MWe of enhanced geothermal potential within the state of Idaho. Of particular interest are the resources of the Eastern Snake River Plain (ESRP) which was formed by volcanic activity associated with the relative movement of the Yellowstone Hot Spot across the state of Idaho. This region is characterized by a high geothermal gradient and thermal springs occurring along the margins of the ESRP. Masking much of the deep thermal potential of the ESRP is a regionally extensive and productive cold-water aquifer. We have undertaken a study to infer the temperature of the geothermal system hidden beneath the cold-water aquifer of the ESRP. Our approach is to estimate reservoir temperatures from measured water compositions using an inverse modeling technique (RTEst) that calculates the temperature at which multiple minerals are simultaneously at equilibrium while explicitly accounting for the possible loss of volatile constituents (e.g., CO2), boiling and/or water mixing. In the initial stages of this study, we apply the RTEst model to water compositions measured from a limited number of wells and thermal springs to estimate the regionally extensive geothermal system in the ESRP.

Ghanashyam Neupane; Earl D. Mattson; Travis L. McLing; Carl D. Palmer; Robert W. Smith; Thomas R. Wood

2014-02-01T23:59:59.000Z

389

Geothermometry At Neal Hot Springs Geothermal Area (U.S. Geothermal...  

Open Energy Info (EERE)

of 177 C. References U.S. Geothermal Inc. (2008) U.S. Geothermal Announces Successful Completion of First Well at Neal Hot Springs Additional References Retrieved from "http:...

390

Atomistic Studies of Cation Transport in Tetragonal ZrO2 During Zirconium Corrosion  

SciTech Connect (OSTI)

Zirconium alloys are the major fuel cladding materials in current reactors. The water-side corrosion is one of the major degradation mechanisms of these alloys. During corrosion the transport of oxidizing species in zirconium dioxide (ZrO2) determines the corrosion kinetics. Previously it has been argued that the outward diffusion of cation ions is important for forming protective oxides. In this work, the migration of Zr defects in tetragonal ZrO2 is studied with temperature accelerated dynamics and molecular dynamics simulations. The results show that Zr interstitials have anisotropic diffusion and migrate preferentially along the [001] or c direction in tetragonal ZrO2. The compressive stresses can increase the Zr interstitial migration barrier significantly. The migration barriers of some defect clusters can be much lower than those of point defects. The migration of Zr interstitials at some special grain boundaries is much slower than in a bulk oxide. The implications of these atomistic simulation results in the Zr corrosion are discussed.

Xian-Ming Bai; Yongfeng Zhang; Michael R. Tonks

2013-10-01T23:59:59.000Z

391

Synthesis and chemistry of cationic d sup 0 metal alkyl complexes  

SciTech Connect (OSTI)

The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp{sub 2}M(R){sup +} complexes (1) which are active species in Cp{sub 2}MX{sub 2}-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R){sub 2}(L){sub n}{sup +} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR{sub 2} and (dicarbollide){sub 2} MR complexes which are more unsaturated than group 5 Cp{sub 2}M systems due to incorporation of the dicarbollide ligand.

Jordan, R.F.

1991-01-01T23:59:59.000Z

392

A search for the sulphur hexafluoride cation with intense, few cycle laser pulses  

SciTech Connect (OSTI)

It is well established that upon ionization of sulphur hexafluoride, the SF{sub 6}{sup +} ion is never observed in mass spectra. Recent work with ultrashort intense laser pulses has offered indications that when strong optical field are used, the resulting bond hardening can induce changes in the potential energy surfaces of molecular cations such that molecular ions that are normally unstable may, indeed, become metastable enough to enable their detection by mass spectrometry. Do intense, ultrashort laser pulses permit formation of SF{sub 6}{sup +}? We have utilized intense pulses of 5 fs, 11 fs, and 22 fs to explore this possibility. Our results are negative: no evidence is discovered for SF{sub 6}{sup +}. However, multiply charged sulphur and fluorine ions from highly charged SF{sub 6}{sup q+} ions are observed that enable us to resolve the controversy regarding the kinetic energy release accompanying formation of F{sup +} fragment ions. Quantum chemical computations of field-distorted potential energy curves of SF{sub 6} and its molecular ion enable us to rationalize our non-observation of SF{sub 6}{sup +}. Our findings have implications for high harmonic generation from SF{sub 6} in the few-cycle regime.

Dota, Krithika; Mathur, Deepak, E-mail: atmol1@tifr.res.in [Tata Institute of Fundamental Research, 1 Homi Bhabha Road, Mumbai 400 005 (India) [Tata Institute of Fundamental Research, 1 Homi Bhabha Road, Mumbai 400 005 (India); Centre for Atomic and Molecular Physics, Manipal University, Manipal 576 104 (India); Dharmadhikari, Aditya K. [Tata Institute of Fundamental Research, 1 Homi Bhabha Road, Mumbai 400 005 (India)] [Tata Institute of Fundamental Research, 1 Homi Bhabha Road, Mumbai 400 005 (India); Dharmadhikari, Jayashree A. [Centre for Atomic and Molecular Physics, Manipal University, Manipal 576 104 (India)] [Centre for Atomic and Molecular Physics, Manipal University, Manipal 576 104 (India); Patra, Kaustuv; Tiwari, Ashwani K. [Indian Institute of Science Education and Research - Kolkata, Mohanpur 741 252 (India)] [Indian Institute of Science Education and Research - Kolkata, Mohanpur 741 252 (India)

2013-11-21T23:59:59.000Z

393

Silica Polyamine Composites: New Supramolecular Materials for Cation and Anion Recovery and Remediation  

SciTech Connect (OSTI)

The surface coverage of amorphous silica gels used in the synthesis of silica polyamine composites has been investigated by 29Si NMR. By diluting the polyamine anchor silane, chloropropyl trichlorosilane, with methyl trichlorosilane it was found that surface coverage could be markedly improved for a range of amine polymers after grafting to the silica surface. The commensurate decrease in the number of anchor points and increase in the number of free amines results in an increase in metal capacity and/or an improvement in capture kinetics. Solid state CPMAS-13C NMR has been employed to investigate the structure and metal ion binding of a series of these composite materials. It is reported that the highly branched polymer, poly(ethyleneimine) (PEI) exhibits much broader 13C NMR resonances than the linear polymers poly(allylamine) (PAA) and poly(vinylamine) (PVA). These results are understood in terms of the low energy conformations calculated from molecular modeling studies. Three new applications of the technology are also presented: (1) separation of lanthanides as a group from ferric ion and all other divalent ions; (2) a multi step process for recovering and concentrating the valuable metals in acid mine drainage; (3) a process for removing low level arsenic and selenium in the presence of sulfate using immobilized cations on the composite materials.

Hughes, Mark; Miranda, Paul; Nielsen, Daniel J.; Rosenberg, Edward; Gobetto, Roberto; Viale, Alessandra; Burton, Sarah D.

2006-03-01T23:59:59.000Z

394

Continuous biodiesel production from acidic oil using a combination of cation- and anion-exchange resins  

Science Journals Connector (OSTI)

Abstract A continuous process was developed to produce biodiesel from acidic oil containing soybean oil and oleic acid, which combined esterification by cation-exchange resin NKC-9, online separation and transesterification by anion-exchange resin D261. The esterification was carried out with soybean oil/oleic acid weight ratio of 5/5, methanol to oleic acid weight ratio of 1.5/1, reaction temperature of 338K and residence time of 126.6min. After the reaction, the mixture was settled to online separate into two layers, and the methanolwateroleic acid mixture at the top layer was reclaimed. The bottom layer, mainly containing soybean oil and methyl oleate, was transesterified under methanol/soybean oil weight ratio of 1/3 and n-hexane/soybean oil weight ratio of 1/2 at 323K for the residence time of 112.0min. The high conversions of oleic acid (above 98%) and soybean oil (92.3%) were achieved. The yield of biodiesel in this process reached up to 95.1%. The main parameters of the product met the Chinese Standard of biodiesel.

Benqiao He; Yixuan Shao; Yanbiao Ren; Jianxin Li; Yu Cheng

2015-01-01T23:59:59.000Z

395

Formation of Supercooled Liquid Solutions from Nanoscale Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Supercooled Liquid Solutions from Nanoscale Amorphous Solid Films of Methanol and Ethanol. Formation of Supercooled Liquid Solutions from Nanoscale Amorphous Solid Films of...

396

Mixing it up - Measuring diffusion in supercooled liquid solutions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixing it up - Measuring diffusion in supercooled liquid solutions of methanol and ethanol at temperatures near the glass Mixing it up - Measuring diffusion in supercooled liquid...

397

Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries. Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries....

398

Case Study: Evaluating Liquid versus Air Cooling in the Maui...  

Broader source: Energy.gov (indexed) [DOE]

Case Study: Evaluating Liquid versus Air Cooling in the Maui High Performance Computing Center Case Study: Evaluating Liquid versus Air Cooling in the Maui High Performance...

399

Creating Liquidity for Energy Efficiency Loans in Secondary Markets...  

Broader source: Energy.gov (indexed) [DOE]

Creating Liquidity for Energy Efficiency Loans in Secondary Markets Creating Liquidity for Energy Efficiency Loans in Secondary Markets Provides information on secondary markets in...

400

DOE Selects Savannah River Remediation, LLC for Liquid Waste...  

Energy Savers [EERE]

objective of the Liquid Waste contract is to achieve closure of the SRS liquid waste tanks in compliance with the Federal Facilities Agreement, utilizing the Defense Waste...

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Formation of iron complexs from trifluoroacetic acid based liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of iron complexs from trifluoroacetic acid based liquid chromatography mobile phases as interference ions in liquid Formation of iron complexs from trifluoroacetic acid based...

402

Oklahoma Natural Gas Plant Liquids, Expected Future Production...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plant Liquids, Expected Future Production (Million Barrels) Oklahoma Natural Gas Plant Liquids, Expected Future Production (Million Barrels) Decade Year-0 Year-1 Year-2 Year-3...

403

Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Berkeley Lab research could help...

404

Elucidating graphene - Ionic Liquid interfacial region: a combined...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

graphene - Ionic Liquid interfacial region: a combined experimental and computational study. Elucidating graphene - Ionic Liquid interfacial region: a combined experimental and...

405

New lithium-based ionic liquid electrolytes that resist salt...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New lithium-based ionic liquid electrolytes that resist salt concentration polarization New lithium-based ionic liquid electrolytes that resist salt concentration polarization...

406

Experimental and Modeling Studies of the Characteristics of Liquid...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Modeling Studies of the Characteristics of Liquid Biofuels for Enhanced Combustion Experimental and Modeling Studies of the Characteristics of Liquid Biofuels for Enhanced...

407

Ionic Liquid Pretreatment Process for Biomass Is Successfully...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ionic Liquid Pretreatment Process for Biomass Is Successfully Implemented at Larger Scale Ionic Liquid Pretreatment Process for Biomass Is Successfully Implemented at Larger Scale...

408

Low-Emissions Burner Technology using Biomass-Derived Liquid...  

Broader source: Energy.gov (indexed) [DOE]

Emissions Burner Technology using Biomass-Derived Liquid Fuels Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels This factsheet describes a project that developed...

409

Enabling Small-Scale Biomass Gasification for Liquid Fuel Production...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Breakout Session 2A-Conversion...

410

California Federal Offshore Natural Gas Plant Liquids, Proved...  

Gasoline and Diesel Fuel Update (EIA)

Gas Plant Liquids, Proved Reserves (Million Barrels) California Federal Offshore Natural Gas Plant Liquids, Proved Reserves (Million Barrels) Decade Year-0 Year-1 Year-2 Year-3...

411

California--State Offshore Natural Gas Plant Liquids, Expected...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Plant Liquids, Expected Future Production (Million Barrels) California--State Offshore Natural Gas Plant Liquids, Expected Future Production (Million Barrels) Decade Year-0 Year-1...

412

Louisiana Offshore Natural Gas Plant Liquids Production Extracted...  

U.S. Energy Information Administration (EIA) Indexed Site

Offshore Natural Gas Plant Liquids Production Extracted in Louisiana (Million Cubic Feet) Louisiana Offshore Natural Gas Plant Liquids Production Extracted in Louisiana (Million...

413

Federal Offshore--California Natural Gas Liquids Lease Condensate...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Liquids Lease Condensate, Proved Reserves (Million Barrels) Federal Offshore--California Natural Gas Liquids Lease Condensate, Proved Reserves (Million Barrels) Decade Year-0...

414

Lower 48 Federal Offshore Natural Gas Liquids Lease Condensate...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Lease Condensate, Proved Reserves (Million Barrels) Lower 48 Federal Offshore Natural Gas Liquids Lease Condensate, Proved Reserves (Million Barrels) Decade Year-0 Year-1...

415

Federal Offshore--Louisiana and Alabama Natural Gas Liquids Lease...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Lease Condensate, Proved Reserves (Million Barrels) Federal Offshore--Louisiana and Alabama Natural Gas Liquids Lease Condensate, Proved Reserves (Million Barrels) Decade...

416

California State Offshore Natural Gas Plant Liquids, Proved Reserves...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Gas Plant Liquids, Proved Reserves (Million Barrels) California State Offshore Natural Gas Plant Liquids, Proved Reserves (Million Barrels) Decade Year-0 Year-1 Year-2 Year-3...

417

California--State Offshore Natural Gas Liquids Lease Condensate...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Lease Condensate, Proved Reserves (Million Barrels) California--State Offshore Natural Gas Liquids Lease Condensate, Proved Reserves (Million Barrels) Decade Year-0 Year-1...

418

Alabama Offshore Natural Gas Plant Liquids Production Extracted...  

Gasoline and Diesel Fuel Update (EIA)

Plant Liquids Production Extracted in Alabama (Million Cubic Feet) Alabama Offshore Natural Gas Plant Liquids Production Extracted in Alabama (Million Cubic Feet) Decade Year-0...

419

California Onshore Natural Gas Plant Liquids Production Extracted...  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids Production Extracted in California (Million Cubic Feet) California Onshore Natural Gas Plant Liquids Production Extracted in California (Million Cubic Feet) Decade...

420

California Onshore Natural Gas Total Liquids Extracted in California...  

U.S. Energy Information Administration (EIA) Indexed Site

Total Liquids Extracted in California (Thousand Barrels) California Onshore Natural Gas Total Liquids Extracted in California (Thousand Barrels) Decade Year-0 Year-1 Year-2 Year-3...

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Energetics of Hydrogen Bond Network Rearrangements in Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Wednesday, 25 May 2005 00:00 The unique...

422

Technical Assessment of Organic Liquid Carrier Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for...

423

Lower 48 Federal Offshore Natural Gas Plant Liquids, Expected...  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids, Expected Future Production (Million Barrels) Lower 48 Federal Offshore Natural Gas Plant Liquids, Expected Future Production (Million Barrels) Decade Year-0 Year-1...

424

Alabama (with State Offshore) Natural Gas Plant Liquids, Expected...  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids, Expected Future Production (Million Barrels) Alabama (with State Offshore) Natural Gas Plant Liquids, Expected Future Production (Million Barrels) Decade Year-0...

425

California (with State Offshore) Natural Gas Plant Liquids, Expected...  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids, Expected Future Production (Million Barrels) California (with State Offshore) Natural Gas Plant Liquids, Expected Future Production (Million Barrels) Decade Year-0...

426

Thermal bubble behaviour in liquid nitrogen under electric fields.  

E-Print Network [OSTI]

??This thesis describes thermally induced bubble behaviour changes in liquid nitrogen (LN2) under electric fields. Cryogenic liquids such as LN2 have been used not only (more)

Wang, Ping

2008-01-01T23:59:59.000Z

427

Performance Characteristics of Coal-to-Liquids (CTL) Diesel in...  

Broader source: Energy.gov (indexed) [DOE]

Performance Characteristics of Coal-to-Liquids (CTL) Diesel in a 50-State Emissions Compliant Passenger Car Performance Characteristics of Coal-to-Liquids (CTL) Diesel in a...

428

Dielectric liquid ionization chambers for detecting fast neutrons  

E-Print Network [OSTI]

Three ionization chambers with different geometries have been constructed and filled with dielectric liquids for detection of fast neutrons. The three dielectric liquids studied were Tetramethylsilane (TMS), Tetramethylpentane ...

Boyd, Erin M

2008-01-01T23:59:59.000Z

429

Probing the Mobility of Supercooled Liquid 3-Methylpentane at...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mobility of Supercooled Liquid 3-Methylpentane at Temperatures Near the Glass Transition Using Rare Gas Permeation. Probing the Mobility of Supercooled Liquid 3-Methylpentane at...

430

Mobility of Supercooled liquid Toluene, Ethylbenzene, and Benzene...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mobility of Supercooled liquid Toluene, Ethylbenzene, and Benzene near their Glass Transition Temperatures Investigated using Mobility of Supercooled liquid Toluene, Ethylbenzene,...

431

High intensity x-ray source using liquid gallium target  

DOE Patents [OSTI]

A high intensity x-ray source that uses a flowing stream of liquid gallium as a target with the electron beam impinging directly on the liquid metal.

Smither, Robert K. (Hinsdale, IL); Knapp, Gordon S. (Cupertino, CA); Westbrook, Edwin M. (Chicago, IL); Forster, George A. (Westmont, IL)

1990-01-01T23:59:59.000Z

432

Modelling Mixed Bed Ion Exchange Kinetics for Removal of Trace Levels of Divalent Cations in Ultrapure Water  

SciTech Connect (OSTI)

Ion exchanger resin fluid film mass transfer coefficients and the ionic diffusivities from which they are derived are often measured by use of ion exchange resin columns. Such tests, usually run dynamically using short resin beds, are often performed using relatively high (ppm) concentrations of ions to accurately measure output concentrations as a function of flow rate. The testing described herein was performed to determine fluid film ionic diffusivities for cationic concentrations typical of ultrapure water ({le}ppb levels) containing ppm levels of ammonia. Effective ionic diffusivities at these low ionic concentrations and high pHs were needed to complete a computer model (SIMIX) to be used in ion exchange simulations. SIMIX is a generalized multicomponent ion exchange model designed to simulate the removal of divalent cations from ultrapure water.

B. Widman

2003-01-01T23:59:59.000Z

433

Viscosity of a nanoconfined liquid during compression  

Science Journals Connector (OSTI)

The viscous behavior of liquids under nanoconfinement is not well understood. Using a small-amplitude atomic force microscope we found bulk-like viscosity in a nanoconfined weakly interacting liquid. A further decrease in viscosity was observed at confinement sizes of a just few molecular layers. Overlaid over the continuum viscous behavior we measured non-continuum stiffness and damping oscillations. The average stiffness of the confined liquid was found to scale linearly with the size of the confining tip while the damping scales with the radius of curvature of the tip end.

Edward L. Kramkowski; Peter J. Ochs; David M. Wilson

2014-01-01T23:59:59.000Z

434

Fermi liquid theory for high temperature superconductors  

SciTech Connect (OSTI)

In this article the Fermi liquid theory of metals is discussed starting from Luttinger's theorem. The content of Luttinger's Theorem and its implications for microscopic theories of high temperature superconductors are discussed. A simple quasi-2d Fermi liquid theory is introduced and some of its properties are calculated. It is argued that a number of experiments on YBa/sub 2/Cu/sub 3/O/sub 6+x/, x > 0.5, strongly suggest the existence of a Fermi surface and thereby a Fermi liquid normal state. 25 refs., 1 fig.

Bedell, K.S.

1988-01-01T23:59:59.000Z

435

Role of the Li+ node in the Li-BH4 substructure of double-cation tetrahydroborates  

Science Journals Connector (OSTI)

The phase diagram of combined alkaline light-metal and heavy-metal borohydrides is explored and revealed to be surprisingly rich. The Li cation is revealed to be a versatile node, allowing for three- and fourfold connectivity in the same structure. Topologies of the Li-BH4 substructure range from isolated chains to three-dimensional frameworks as a function of Li content.

Schouwink, P.

2014-10-01T23:59:59.000Z

436

G en eralisation de th eor emes inductifs pour la v eri cation d'architectures r eguli eres  

E-Print Network [OSTI]

G#19;en#19;eralisation de th#19;eor#18;emes inductifs pour la v#19;eri#12;cation d'architectures r, preuve qui n#19;e- cessite fr#19;equemment une phase de g#19;en#19;eralisation de th#19;eor#18;emes. Nous proposons une m#19;ethode de g#19;en#19;eralisation qui permet de produire le th#19;eor#18;eme g#19;en#19

Pierre, Laurence

437

Temperature-controlled ionic liquid dispersive liquid phase microextraction combined with ultra-high-pressure liquid chromatography for the rapid determination of triclosan, triclocarban and methyl-triclosan in aqueous samples  

Science Journals Connector (OSTI)

As extraction solvents, ionic liquids have green characteristics. In this study, an environmentally benign analytical method termed temperature-controlled ionic liquid dispersive liquid phase microextraction (TIL...

JieHong Guo; XingHong Li; XueLi Cao; Lei Qu; DeKun Hou

2010-12-01T23:59:59.000Z

438

Neutron Scattering by Liquid Neon  

Science Journals Connector (OSTI)

A theory for neutron scattering by a semiclassical system, which is appropriate for liquid neon, is described. The theory is based on a generalized mean-field approximation involving the polarization potential and the screened response function, similarly to what has been done previously for argon and helium. The screened response function is assumed to be a sum of Gaussian functions weighted by the momentum-distribution function. The polarization potential and the width of the Gaussians are determined by the zeroth and third moments of the scattering law. The momentum distribution has the MaxwellBoltzmann form, but includes quantum corrections to order ?2. The quantum-mechanical zero-point energy is found to increase the kinetic energy per particle to a value of about 30% greater than the classical equipartition value. Calculations have been done for wave-vector transfers in the range 0.75-5.5 times the wave vector at the principal maximum in the static-structure factor, and the theoretical line shapes have been folded with the resolution function for the experiments of Buyers et al. Comparison of the position of the maximum, full width at half-maximum, and line shapes with the experimental results gives good agreement.

W. C. Kerr and K. S. Singwi

1973-03-01T23:59:59.000Z

439

Natural Gas Total Liquids Extracted  

U.S. Energy Information Administration (EIA) Indexed Site

Thousand Barrels) Thousand Barrels) Data Series: Natural Gas Processed Total Liquids Extracted NGPL Production, Gaseous Equivalent Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 2007 2008 2009 2010 2011 2012 View History U.S. 658,291 673,677 720,612 749,095 792,481 873,563 1983-2012 Alabama 13,381 11,753 11,667 13,065 1983-2010 Alaska 22,419 20,779 19,542 17,798 18,314 18,339 1983-2012 Arkansas 126 103 125 160 212 336 1983-2012 California 11,388 11,179 11,042 10,400 9,831 9,923 1983-2012 Colorado 27,447 37,804 47,705 57,924 1983-2010 Florida 103 16 1983-2008 Illinois 38 33 24 231 705 0 1983-2012

440

Interaction of the cesium cation with calix[4]arene-bis(t-octylbenzo-18-crown-6): Extraction and DFT study  

Science Journals Connector (OSTI)

From extraction experiments and ?-activity measurements, the extraction constant corresponding to the equilibrium Cs+ (aq)+I? (aq)+1 (org)?1?Cs+ (org)+I? (org) taking place in the two-phase water-phenyltrifluoromethyl sulfone (abbrev. FS 13) system (1=calix[4]arene-bis(t-octylbenzo-18-crown-6); aq=aqueous phase, org=FS 13 phase) was evaluated as logKex(1?Cs+,I?)=2.10.1. Further, the stability constant of the 1?Cs+ complex in FS 13 saturated with water was calculated for a temperature of 25C: log?org(1?Cs+)=9.90.1. Finally, by using quantum mechanical DFT calculations, the most probable structure of the cationic complex species 1?Cs+ was derived. In the resulting 1?Cs+ complex, the central cation Cs+ is bound by eight bond interactions to six oxygen atoms of the respective 18-crown-6 moiety and to two carbons of the corresponding two benzene rings of the parent ligand 1 via cation? interaction.

Emanuel Makrlk; Petr Toman; Petr Va?ura; Bruce A. Moyer

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Liquid and liquidgas flows at all speeds  

SciTech Connect (OSTI)

All speed flows and in particular low Mach number flow algorithms are addressed for the numerical approximation of the Kapila et al. [1] multiphase flow model. This model is valid for fluid mixtures evolving in mechanical equilibrium but out of temperature equilibrium and is efficient for material interfaces computation separating miscible and non-miscible fluids. In this context, the interface is considered as a numerically diffused zone, captured as well as all present waves (shocks, expansion waves). The same flow model can be used to solve cavitating and boiling flows [2]. Many applications occurring with liquidgas interfaces and cavitating flows involve a very wide range of Mach number, from 10{sup ?3} to supersonic (and even hypersonic) conditions with respect to the mixture sound speed. It is thus important to address numerical methods free of restrictions regarding the Mach number. To do this, a preconditioned Riemann solver is built and embedded into the Godunov explicit scheme. It is shown that this method converges to exact solutions but needs too small time steps to be efficient. An implicit version is then derived, first in one dimension and second in the frame of 2D unstructured meshes. Two-phase flow preconditioning is then addressed in the frame of the Saurel et al. [3] algorithm. Modifications of the preconditioned Riemann solver are needed and detailed. Convergence of both single phase and two-phase numerical solutions are demonstrated with the help of single phase and two-phase steady nozzle flow solutions. Last, the method is illustrated by the computation of real cavitating flows in Venturi nozzles. Vapour pocket size and instability frequencies are reproduced by the model and method without using any adjustable parameter.

LeMartelot, S., E-mail: sebastien.lemartelot@polytech.univ-mrs.fr [Polytech'Marseille, Aix-Marseille University, UMR CNRS 7343 IUSTI, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France); Nkonga, B., E-mail: boniface.nkonga@unice.fr [RS2N, Bastidon de la Caou, 13360 Roquevaire (France); University of Nice, LJAD UMR CNRS 7351, Parc Valrose, 06108 Nice Cedex (France); Saurel, R., E-mail: richard.saurel@polytech.univ-mrs.fr [Polytech'Marseille, Aix-Marseille University, UMR CNRS 7343 IUSTI, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France); RS2N, Bastidon de la Caou, 13360 Roquevaire (France); University Institute of France, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France)

2013-12-15T23:59:59.000Z

442

Rovibronically selected and resolved two-color laser photoionization and photoelectron study of nickel carbide cation  

SciTech Connect (OSTI)

We have performed a two-color laser photoionization and photoelectron study of nickel carbide (NiC) and its cation (NiC{sup +}). By preparing NiC in a single rovibronic level of an intermediate vibronic state via visible laser excitation prior to ultraviolet laser photoionization, we have measured the photoionization efficiency spectrum of NiC near its ionization threshold, covering the formation of NiC{sup +}(X {sup 2}{Sigma}{sup +};v{sup +}=0-3). We have also obtained well-resolved rotational transitions for the v{sup +}=0 and 1 vibrational bands of the NiC{sup +}(X {sup 2}{Sigma}{sup +}) ground state. The assignment of rotational transitions observed between the neutral NiC intermediate state and the NiC{sup +} ion ground state has allowed the direct determination of a highly precise value for the ionization energy of NiC, IE(NiC)=67 525.1{+-}0.5 cm{sup -1} (8.372 05{+-}0.000 06 eV). This experiment also provides reliable values for the vibrational spacing [{Delta}G(1/2)=859.5{+-}0.5 cm{sup -1}], rotational constants (B{sub e}{sup +}=0.6395{+-}0.0018 cm{sup -1} and {alpha}{sub e}{sup +}=0.0097{+-}0.0009 cm{sup -1}), and equilibrium bond distance (r{sub e}{sup +}=1.628 A) for the NiC{sup +}(X {sup 2}{Sigma}{sup +}) ground state. The experimental results presented here are valuable for benchmarking the development of more reliable ab initio quantum computation procedures for energetic and spectroscopic calculations of transition metal-containing molecules.

Chang, Yih Chung [Department of Chemistry, University of California, Davis, Davis, California 95616 (United States); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 106, Taiwan (China); Shi Xiaoyu; Ng, C. Y. [Department of Chemistry, University of California, Davis, Davis, California 95616 (United States); Lau, Kai-Chung [Department of Biology and Chemistry, City University of Hong Kong, Kowloon (Hong Kong); Yin Qingzhu [Department of Geology, University of California, Davis, Davis, California 95616 (United States); Liou, H. T. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 106, Taiwan (China)

2010-08-07T23:59:59.000Z

443

Definition: Liquid natural gas | Open Energy Information  

Open Energy Info (EERE)

Liquid natural gas Liquid natural gas Jump to: navigation, search Dictionary.png Liquid natural gas Natural gas (primarily methane) that has been liquefied by reducing its temperature to -260 degrees Fahrenheit at atmospheric pressure.[1] View on Wikipedia Wikipedia Definition Liquefied natural gas or LNG is natural gas that has been converted to liquid form for ease of storage or transport. Liquefied natural gas takes up about 1/600th the volume of natural gas in the gaseous state. It is odorless, colorless, non-toxic and non-corrosive. Hazards include flammability after vaporization into a gaseous state, freezing and asphyxia. The liquefaction process involves removal of certain components, such as dust, acid gases, helium, water, and heavy hydrocarbons, which could cause difficulty downstream. The natural gas is then condensed into a

444

LiquidMaize LLC | Open Energy Information  

Open Energy Info (EERE)

LiquidMaize LLC LiquidMaize LLC Jump to: navigation, search Name LiquidMaize, LLC Place Denver, Colorado Zip 80237 Product LiquidMaize is an ethanol development and management company that builds, owns, and operates ethanol plants within existing cattle feed-yards and dairy operations. Coordinates 39.74001°, -104.992259° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.74001,"lon":-104.992259,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

445

Analysis of Isocyanates by Gas Liquid Chromatography  

Science Journals Connector (OSTI)

......Liquid Chromatography Gary W. Ruth Marathon Oil Company, Denver Research Center...Chromatography by Gary W. Ruth, Marathon Oil Company, Denver Research Center...at the Denver Research Center, Marathon Oil Company, Littleton, Colorado......

Gary W. Ruth

1968-10-01T23:59:59.000Z

446

Phosphonium-based ionic liquids and uses  

DOE Patents [OSTI]

Phosphonium-based room temperature ionic liquids ("RTILs") were prepared. They were used as matrices for Matrix-Assisted Laser Desorption Ionization (MALDI) mass spectrometry and also for preparing samples of dyes for analysis.

Del Sesto, Rico E; Koppisch, Andrew T; Lovejoy, Katherine S; Purdy, Geraldine M

2014-12-30T23:59:59.000Z

447

Viscosity of Liquids and Colloidal Solutions  

Science Journals Connector (OSTI)

... conference it was decided to hold a further conference, in the following year, on "Viscosity of Liquids and Colloidal Solutions". This took place just before the German invasion and ...

G. W. SCOTT BLAIR

1945-08-04T23:59:59.000Z

448

Removal of arsenic compounds from petroliferous liquids  

DOE Patents [OSTI]

Described is a process for removing arsenic from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic bound to it from contacting petroliferous liquid as described above and involves: a. treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10 and, b. separating the solids and liquids from each other. Preferably the regeneration treatment is in two steps wherein step (a) is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, steps (a) and (b) are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1985-01-01T23:59:59.000Z

449

Analyzing Biomass Conversion into Liquid Hydrocarbons  

Science Journals Connector (OSTI)

Variants of the FischerTropsch producer-gas conversion into liquid hydrocarbons are analyzed under the ... is attained in the reactions occurring in the biomass gasification. When the raw material is wood ... th...

V. D. Meshcheryakov; V. A. Kirillov

2002-09-01T23:59:59.000Z

450

Liquid metal cooled divertor for ARIES  

SciTech Connect (OSTI)

A liquid metal, Ga-cooled divertor design was completed for the double null ARIES-II divertor design. The design analysis indicated a surface heat flux removal capability of up to 15 MW/m{sup 2}, and its relative easy maintenance. Design issues of configuration, thermal hydraulics, thermal stresses, liquid metal loop and safety effects were evaluated. For coolant flow control, it was found that it is necessary to use some part of the blanket cooling ducts for the draining of liquid metal from the top divertor. In order to minimize the inventory of Ga, it was recommended that the liquid metal loop equipment should be located as close to the torus as possible. More detailed analysis of transient conditions especially under accident conditions was identified as an issue that will need to be addressed.

Muraviev, E. [Gosudarstvennyj Komitet po Ispol`zovaniyu Atomnoj Ehnergii SSSR, Moscow (Russian Federation). Inst. Atomnoj Ehnergii

1995-01-01T23:59:59.000Z

451

Liquid Fuels from Biomass | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuels from Biomass Liquid Fuels from Biomass Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel...

452

AEO 2013 Liquid Fuels Markets Working Group  

Gasoline and Diesel Fuel Update (EIA)

last year but will be this year It is a cap and trade system for Green House Gas (GHG) It is anticipated to affect prices, production and more than just liquid fuels Carbon...

453

Photo-responsive liquid crystal block copolymers/  

E-Print Network [OSTI]

Photo-responsive liquid crystal polymers (LCP) which contain azobenzene moieties have gained interest for their ability to change properties by merely irradiating them with the correct wavelength of light in the appropriate ...

Petr, Michael Thomas

2012-01-01T23:59:59.000Z

454

SRS Liquid Waste Program Partnering Agreement  

Broader source: Energy.gov [DOE]

We the members of the SRS Liquid Waste Partnering Team do hereby mutually agree to work in a collaborative and cooperative manner through open communication and coordination with team members, and...

455

Alternative Liquid Fuels (ALF) | Open Energy Information  

Open Energy Info (EERE)

Fuels (ALF) Jump to: navigation, search Name: Alternative Liquid Fuels (ALF) Address: P.O. Box 76 Place: McArthur, Ohio Zip: 45651 Sector: Biofuels, Renewable Energy, Services...

456

Accelerated Animation of Liquid Splash Roman Durikovic  

E-Print Network [OSTI]

step and viscosity. The final liquid surface is obtained from the velocity field by rough estimation small fluid objects such as splash and spray. Our final goal is to develop a real-time system

Durikovic, Roman

457

Doppler effect in light scattering in liquids  

Science Journals Connector (OSTI)

The present work deals with the study of the state of polarisation of the three components observed in the spectrum of monochromatic light scattered by liquid formic and acetic acids, when examined with a Fabr...

B. V. Raghavendra Rao

1936-06-01T23:59:59.000Z

458

Goethite liquid crystals and magnetic field effects.  

E-Print Network [OSTI]

??In this thesis the liquid crystal phase behavior of colloidal, boardlike, goethite (alpha-FeOOH) particles is described. Apart from the nematic phase, a smectic A phase (more)

Pol, E. van den

2010-01-01T23:59:59.000Z

459

Magnetism in Heavy-Electron Liquids  

Science Journals Connector (OSTI)

......Theoretical Physics February 1992 research-article Articles Magnetism in Heavy-Electron Liquids Fusayoshi J. Ohkawa Department...d expansion to paramagnons, metamagnetism, tiny-moment magnetism, and other topics are presented. Citing Article(s......

Fusayoshi J. Ohkawa

1992-02-01T23:59:59.000Z

460

Hydrogen from Bio-Derived Liquids (Presentation)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

From Bio-Derived Liquids From Bio-Derived Liquids Hydrogen From Bio Hydrogen From Bio - - Derived Liquids Derived Liquids Dave King, Yong Wang, PNNL BILIWIG Meeting Laurel, Maryland November 6, 2007 Innovation / Overview Innovation / Overview Innovation / Overview Project comprises two components z Ethanol steam reforming z Aqueous phase reforming (APR) Importance to small scale hydrogen production for distributed reforming for hydrogen production ‹ Ethanol is rapidly becoming an infrastructure fuel and is a logical feedstock ‹ APR provides vehicle for facile reforming of a variety of bio-derived feedstocks available in the biorefinery that are not conducive to conventional vapor phase reforming Distinctive technology approach/innovation z We are investigating single step ethanol reforming with emphasis on lower

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Optical constants of liquid and solid methane  

Science Journals Connector (OSTI)

The optical constants nr + ini of liquid methane and phase I solid methane were determined over the entire spectral range by the use of various data sources published in the...

Martonchik, John V; Orton, Glenn S

1994-01-01T23:59:59.000Z

462

Liquid--liquid equilibria by use of UNIFAC for gasohol extraction systems  

SciTech Connect (OSTI)

A synthetic naphtha cut composed of a mixture of paraffinic, aromatic, and naphthenic hydrocarbons has been studied as a solvent to directly produce gasohol. The equilibria in these highly nonideal liquid mixtures has been estimated by the UNIFAC group contribution method. The process would appear to be simple and direct to produce gasohol by liquid--liquid extraction with this naphtha and could compete with existing azeotropic distillation processes.

Furzer, I.A.

1984-04-01T23:59:59.000Z

463

Bubble departure in the direct-contact boiling field with a continuous liquid-liquid interface  

SciTech Connect (OSTI)

Behavior of vapor bubbles was experimentally investigated in the boiling field where a volatile liquid layer of per-fluorocarbon PF5050 (boiling point 306K) was directly in contact with an immiscible hot liquid layer of water above it. Heat was supplied to the continuous liquid-liquid interface by the impingement of the downward hot water jet. Vapor bubbles were generated not only from this continuous interface but from a large number of PF5050 droplets floating on it. According to precise observation, incipience of boiling did not occur at the liquid-liquid interface but in the PF5050 liquid close to the interface in both cases of continuous and dispersed interfaces. As a result, the bubbles broke up the thin PF5050 liquid film above them and rose up into the water layer. This bubble departure phenomenon, which does not occur in the ordinary pool boiling field on the solid heating wall, is very important to evaluate the heat transfer performance in the present direct-contact boiling system. For modeling this behavior, sizes of the bubbles were measured at the moment just after they were released into the water pool. Volumes of the bubbles were larger in the case of departing from the continuous liquid-liquid interface than from the droplets. This tendency could be explained by taking into account the buoyancy force acting on unit area of the thin PF5050 liquid film above the bubble before departure, which was one of the most important parameters for the liquid film breakdown. (author)

Kadoguchi, Katsuhiko [Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki 305-8569 (Japan)

2007-01-15T23:59:59.000Z

464

Zeolitized tuffs in pedotechniques to improve soil resilience against the impact of treatment by municipal sewage: balance of nutrient and noxious cations  

Science Journals Connector (OSTI)

...sample; (2) the natural cationic composition of these exchangers; (3) the concentration...depending on the variability of DSW composition, with peaks at the third, seventh...Gavalova Z. (2004) Agricultural and agrochemical uses of natural zeolite of the clinoptilolite...

G. F. Capra; A. Buondonno; E. Coppola; M. G. Duras; S. Vacca; C. Colella

465

Superbase-derived protic ionic liquids  

DOE Patents [OSTI]

Protic ionic liquids having a composition of formula (A.sup.-)(BH.sup.+) wherein A.sup.- is a conjugate base of an acid HA, and BH.sup.+ is a conjugate acid of a superbase B. In particular embodiments, BH.sup.+ is selected from phosphazenium species and guanidinium species encompassed, respectively, by the general formulas: ##STR00001## The invention is also directed to films and membranes containing these protic ionic liquids, with particular application as proton exchange membranes for fuel cells.

Dai, Sheng; Luo, Huimin; Baker, Gary A.

2013-09-03T23:59:59.000Z

466

The absorption of ultrasonic waves in liquids  

E-Print Network [OSTI]

Vee ~ ~ ~ ~ a ~ ~ ~ ~ ~ ~ a ~ e ~ ~ ~ ~ a ~ ~ ea ~ ~ ~ eee ~ ~ ~ ~ ~ ~ ea ~ ~ ~ ~ 2 ~ ?easursasnt of ths Prop-:. ties of:asss and Liquids by Ultrasonicseae ~ ~ ~ ~ ~ e ~ ~ ~ ~ ~ ~ ~ ~ e ~ ~ dies Borne erscsnt Theories ConcsrrrinS the Oisorsparrcy 3e tween... ~ ~ ~ ~ ~ ~ ~ o 3Q VI, Plot of' Los A /A vs~ Sound Path Length Ital ZthoI' 1Mox' Ppoalul'oe ~ ~ a ~ y ~ ~ s ~ ~ ~ ~ ~ ~ e ~ ~ ~ e s ~ ~ ~ ~ e ~ ~ a ~ ~ 3) xxeasuraaents oa the absorption of high frequency souad. waves ia liquids axe useful ia studying...

Hudson, Paul A

2012-06-07T23:59:59.000Z

467

Elimination of liquid discharge to the environment from the TA-50 Radioactive Liquid Waste Treatment Facility  

SciTech Connect (OSTI)

Alternatives were evaluated for management of treated radioactive liquid waste from the radioactive liquid waste treatment facility (RLWTF) at Los Alamos National Laboratory. The alternatives included continued discharge into Mortandad Canyon, diversion to the sanitary wastewater treatment facility and discharge of its effluent to Sandia Canyon or Canada del Buey, and zero liquid discharge. Implementation of a zero liquid discharge system is recommended in addition to two phases of upgrades currently under way. Three additional phases of upgrades to the present radioactive liquid waste system are proposed to accomplish zero liquid discharge. The first phase involves minimization of liquid waste generation, along with improved characterization and monitoring of the remaining liquid waste. The second phase removes dissolved salts from the reverse osmosis concentrate stream to yield a higher effluent quality. In the final phase, the high-quality effluent is reused for industrial purposes within the Laboratory or evaporated. Completion of these three phases will result in zero discharge of treated radioactive liquid wastewater from the RLWTF.

Moss, D.; Williams, N.; Hall, D.; Hargis, K.; Saladen, M.; Sanders, M.; Voit, S.; Worland, P.; Yarbro, S.

1998-06-01T23:59:59.000Z

468

Hydrotreating of coal-derived liquids  

SciTech Connect (OSTI)

The objective of Sandia`s refining of coal-derived liquids project is to determine the relationship between hydrotreating conditions and Product characteristics. The coal-derived liquids used in this work were produced In HTI`s first proof-of-concept run using Illinois No. 8 coal. Samples of the whole coal liquid product, distillate fractions of this liquid, and Criterion HDN-60 catalyst were obtained from Southwest Research Inc. Hydrotreating experiments were performed using a continuous operation, unattended, microflow reactor system. A factorial experimental design with three variables (temperature, (310{degrees}C to 388{degrees}C), liquid hourly space velocity (1 to 3 g/h/cm{sup 3}(cat)), pressure (500 to 1000 psig H{sub 2}) is being used in this project. Sulfur and nitrogen contents of the hydrotreated products were monitored during the hydrotreating experiments to ensure that activity was lined out at each set of reaction conditions. Results of hydrotreating the whole coal liquid showed that nitrogen values in the products ranged from 549 ppM at 320{degrees}C, 3 g/h/cm{sup 3}(cat), 500 psig H{sub 2} to <15 ppM at 400{degrees}C, 1 g/h/ cm{sup 3}(cat), 1000 psig H{sub 2}.

Stohl, F.V.; Lott, S.E.; Diegert, K.V.; Goodnow, D.C.; Oelfke, J.B.

1995-06-01T23:59:59.000Z

469

Process for stabilization of coal liquid fractions  

DOE Patents [OSTI]

Coal liquid fractions to be used as fuels are stabilized against gum formation and viscosity increases during storage, permitting the fuel to be burned as is, without further expensive treatments to remove gums or gum-forming materials. Stabilization is accomplished by addition of cyclohexanol or other simple inexpensive secondary and tertiary alcohols, secondary and tertiary amines, and ketones to such coal liquids at levels of 5-25% by weight with respect to the coal liquid being treated. Cyclohexanol is a particularly effective and cost-efficient stabilizer. Other stabilizers are isopropanol, diphenylmethanol, tertiary butanol, dipropylamine, triethylamine, diphenylamine, ethylmethylketone, cyclohexanone, methylphenylketone, and benzophenone. Experimental data indicate that stabilization is achieved by breaking hydrogen bonds between phenols in the coal liquid, thereby preventing or retarding oxidative coupling. In addition, it has been found that coal liquid fractions stabilized according to the invention can be mixed with petroleum-derived liquid fuels to produce mixtures in which gum deposition is prevented or reduced relative to similar mixtures not containing stabilizer.

Davies, Geoffrey (Boston, MA); El-Toukhy, Ahmed (Alexandria, EG)

1987-01-01T23:59:59.000Z

470

SEAPORT LIQUID NATURAL GAS STUDY  

SciTech Connect (OSTI)

The Seaport Liquid Natural Gas Study has attempted to evaluate the potential for using LNG in a variety of heavy-duty vehicle and equipment applications at the Ports of Los Angeles and Oakland. Specifically, this analysis has focused on the handling and transport of containerized cargo to, from and within these two facilities. In terms of containerized cargo throughput, Los Angeles and Oakland are the second and sixth busiest ports in the US, respectively, and together handle nearly 4.5 million TEUs per year. At present, the landside handling and transportation of containerized cargo is heavily dependent on diesel-powered, heavy-duty vehicles and equipment, the utilization of which contributes significantly to the overall emissions impact of port-related activities. Emissions from diesel units have been the subject of increasing scrutiny and regulatory action, particularly in California. In the past two years alone, particulate matter from diesel exhaust has been listed as a toxic air contaminant by CAM, and major lawsuits have been filed against several of California's largest supermarket chains, alleging violation of Proposition 65 statutes in connection with diesel emissions from their distribution facilities. CARE3 has also indicated that it may take further regulatory action relating to the TAC listing. In spite of these developments and the very large diesel emissions associated with port operations, there has been little AFV penetration in these applications. Nearly all port operators interviewed by CALSTART expressed an awareness of the issues surrounding diesel use; however, none appeared to be taking proactive steps to address them. Furthermore, while a less controversial issue than emissions, the dominance of diesel fuel use in heavy-duty vehicles contributes to a continued reliance on imported fuels. The increasing concern regarding diesel use, and the concurrent lack of alternative fuel use and vigorous emissions reduction activity at the Ports provide both the backdrop and the impetus for this study.

COOK,Z.

1999-02-01T23:59:59.000Z

471

Retrograde Melting and Internal Liquid Gettering in Silicon  

E-Print Network [OSTI]

XAS analysis. Solid metal-silicide phases below the binaryprevious reports of mixed-metal silicides in mc-Si systems,solidi?cation to solid metal silicide utes, both Cu and Fe

Hudelson, Steve

2012-01-01T23:59:59.000Z

472

Intramolecular cationic [5 + 2] cycloaddition reactions promoted by trimethylsilyl triflate in 3.0 M lithium perchlorate-ethyl acetate: Application to a formal total synthesis of ()-isocomene  

Science Journals Connector (OSTI)

Trimethylsilyl triflate is an effective reagent in 3.0 M lithium perchlorate-ethyl acetate for promoting intramolecular cationic [5 + 2] cycloaddition reactions. A formal total synthesis of the angular triquinane isocomene (10) is detailed. Cationic [5 + 2] cycloaddition of quinone monoketal 40 gives rise to tricyclic diketone 35 which is subsequently converted into the known tricyclic ketone 33. Addition of methyl lithium followed by acid-catalyzed rearrangement employing the Pirrung protocol affords ()-isocomene (10).

Paul A. Grieco; John K. Walker

1997-01-01T23:59:59.000Z

473

Ion Transport in Nanostructured Block Copolymer/Ionic Liquid Membranes  

E-Print Network [OSTI]

E. Ionic Liquids as Green Solvents: Progress and Prospectsthem attention as green solvents for synthesis and

Hoarfrost, Megan Lane

2012-01-01T23:59:59.000Z

474

Solvent-Resistant Photocurable "Liquid Teflon" for Microfluidic Device Fabrication  

E-Print Network [OSTI]

with photocurable perfluoropolyethers (PFPEs). PFPEs are a unique class of fluoropolymers that are liquids at room

Quake, Stephen R.

475

Comparison of performance characteristics of liquid biofuels and petroleum fuels  

Science Journals Connector (OSTI)

The performance properties of different types of liquid biofuels (bioalcohols, biodiesel, etc.) are examined...

K. E. Pankin; Yu. V. Ivanova; R. I. Kuzmina

2011-05-01T23:59:59.000Z

476

ccsd00001732, Development behavior of liquid plasma produced by  

E-Print Network [OSTI]

water with a melted NaCl is used as a test liquid. The liquid plasma is produced by the fundamental waveccsd­00001732, version 2 ­ 7 Nov 2004 Development behavior of liquid plasma produced by YAG laser the hazardous material called the environment material. Then, the plasma produced in liquid by the laser light

477

Essays on Bank Optimal Portfolio Choice under Liquidity Constraint  

E-Print Network [OSTI]

that the bank securities business produces a chasm between a real liquidity of economy and market liquidity. Banks can have more liquidity by selling their securitized loans, and as our model already pointed out, a good liquidity condition makes the bank have...

Kim, Eul Jin

2012-10-19T23:59:59.000Z

478

Collection of liquid from below-ground location  

DOE Patents [OSTI]

A method of retrieving liquid from a below-ground collection area by permitting gravity flow of the liquid from the collection area to a first closed container; monitoring the level of the liquid in the closed container; and after the liquid reaches a given level in the first closed container, transferring the liquid to a second closed container disposed at a location above the first closed container, via a conduit, by introducing into the first closed container a gas which is substantially chemically inert with respect to the liquid, the gas being at a pressure sufficient to propel the liquid from the first closed container to the second closed container.

Phillips, Steven J. (Kennewick, WA); Alexander, Robert G. (Kennewick, WA)

1995-01-01T23:59:59.000Z

479

Liquid over-feeding air conditioning system and method  

DOE Patents [OSTI]

A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant. 1 figure.

Mei, V.C.; Chen, F.C.

1993-09-21T23:59:59.000Z

480

Air-Assisted Liquid LiquidMicroextraction for the Analysis of Fungicides from Environmental Water and Juice Samples  

Science Journals Connector (OSTI)

......2014 research-article Article Air-Assisted Liquid Liquid-Microextraction...work, a rapid method based on air-assisted liquid liquid microextraction...the continuous injection of air by a 20-mL glass syringe...resulting in the possible pollution of water, fruits and vegetables......

Shiju Wu; Tingting Jin; Jing Cheng; Hongbin Zhou; Min Cheng

2014-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Rotor for processing liquids using movable capillary tubes  

DOE Patents [OSTI]

A rotor assembly for processing liquids, especially whole blood samples, is disclosed. The assembly includes apparatus for separating non-liquid components of whole blood samples from liquid components, apparatus for diluting the separated liquid component with a diluent and apparatus for transferring the diluted sample to an external apparatus for analysis. The rotor assembly employs several movable capillary tubes to handle the sample and diluents. A method for using the rotor assembly to process liquids is also described. 5 figs.

Johnson, W.F.; Burtis, C.A.; Walker, W.A.

1987-07-17T23:59:59.000Z

482

Gas-liquid separator and method of operation  

DOE Patents [OSTI]

A system for gas-liquid separation in electrolysis processes is provided. The system includes a first compartment having a liquid carrier including a first gas therein and a second compartment having the liquid carrier including a second gas therein. The system also includes a gas-liquid separator fluidically coupled to the first and second compartments for separating the liquid carrier from the first and second gases.

Soloveichik, Grigorii Lev (Latham, NY); Whitt, David Brandon (Albany, NY)

2009-07-14T23:59:59.000Z

483

Scattering of Slow Neutrons by a Liquid  

Science Journals Connector (OSTI)

The differential cross section for coherent scattering of thermal neutrons by a liquid is given in general by the Fourier transform of a time-displaced radial density function. It is suggested here that, to an adequate degree of approximation, this time-displaced function can be expressed as a convolution of the ordinary radial density function with a self-diffusion function describing the wandering of an atom from an arbitrary initial position. The neutron scattering cross section then becomes the product of the Fourier transforms of these two functions. One of the transforms is the differential cross section for x-ray scattering and describes interference effects, the other governs the energy changes upon scattering. In this development the scatterer can be treated either quantum mechanically or classically. Recoil effects are not provided by the classical treatment, but this is a significant deficiency only in liquids of low atomic weight. Several models for calculating the self-diffusion function are considered, and from these it is suggested that a Gaussian function with a time-dependent width is a reasonable approximation for the case of a simple liquid. The principal features of the width are deduced. Quantization of the scatterer effects the width at small times. At large times the width depends only on the coefficient of self-diffusion of the liquid, and inelastic scattering is suggested as a means of determining this coefficient, as well as other features of atomic movement. The accuracy of the static approximation for determining liquid structures by neutron diffraction is assessed by considering the typical case of liquid lead near its melting point, and is found to be moderately good. The extension of the entire formalism to the case of polyatomic liquids is outlined.

George H. Vineyard

1958-06-01T23:59:59.000Z

484

New iodocuprates(I) with N-heterocyclic molecules as the cations  

SciTech Connect (OSTI)

Under the hydrothermal conditions, the reactions between CuI, KI and bp/bpp (bp=4,4?-bipiperidine, bpp=1,3-bis(4-piperidyl)propane) in an acidic alcohol solution produced three new organically templated iodocuprates(I) as [H{sub 2}bp]{sub 2}[Cu{sub 2}I{sub 6}] 1, [tmbp][Cu{sub 2}I{sub 4}] 2 and [tmbpp] 2 [Cu{sub 4}I{sub 8}]2H{sub 2}O 3 (tmbp{sup 2+}=N,N,N?,N?-tetramethyl-4,4?-bipiperidinium; tmbpp{sup 2+}=N,N,N?,N?-tetramethyl-1,3-bis(4-piperidyl)propane dication). X-ray analysis revealed that (i) tmbp{sup 2+} and tmbpp{sup 2+} in compounds 2 and 3 originated from the complete N-alklation of bp/bpp with CH{sub 3}OH; (ii) templated by H{sub 2}bp{sup 2+}, the inorganic anion [Cu{sub 2}I{sub 6}]{sup 2?} of 1 possesses a dinuclear structure, whereas templated by tmbp{sup 2+}, the inorganic anion [Cu{sub 2}I{sub 4}]{sup 2?} of 2 exhibits a one-dimensional (1D) chain structure; (iii) templated by tmbpp{sup 2+}, the inorganic anion [Cu{sub 4}I{sub 8}]{sup 4?} of 3 shows a cubane-like structure modified by four terminal I{sup ?} ions. The photoluminescence analysis indicates that compounds 1 and 2 emit blue light, while compound 3 emits green light. - Graphical abstract: By employing hydrothermal in situ N-alkylation of bp/bpp with CH{sub 3}OH, three new organically templated iodocuprates(I) were obtained. Display Omitted - Highlights: Three new organically templated iodocuprates(I) were reported. Cations tmbp{sup 2+} and tmbpp{sup 2+} originated from in situ alkylation of bp/bpp with CH{sub 3}OH. H{sup +} and I{sup ?} play a key role in alkylation of bp/bpp with CH{sub 3}OH. Photoluminescence emission for iodocuprates(I) is related to CuCu interaction.

Zhao, Jin-Jing [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Zhang, Xiao [State Key Lab of Urban Water Resource and Environment (SKLUWRE) and Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, Heilongjiang 150080 (China); Wang, Yan-Ning; Jia, Hong-Li [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Yu, Jie-Hui, E-mail: jhyu@jlu.edu.cn [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Xu, Ji-Qing, E-mail: xjq@mail.jlu.edu.cn [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China)

2013-11-15T23:59:59.000Z

485

A novel X-ray diffractometer for studies of liquid-liquid interfaces  

Science Journals Connector (OSTI)

A dedicated liquid surface diffractometer employing a tilting double-crystal monochromator in Bragg geometry has been designed. This diffractometer allows reflectivity and grazing-incidence scattering measurements of an immobile mechanical completely decoupled liquid sample from 6.4 to 29.4 keV.

Murphy, B.M.

2013-11-29T23:59:59.000Z

486

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces  

E-Print Network [OSTI]

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces allowed to self-assemble at the perfluorodecalin/water interface. These plates were fabricated from, the designs of hydrophobic edges necessary to generate menisci useful in self-assembly were different for 100

Prentiss, Mara

487

Liquid?Liquid Equilibria for Binary and Ternary Polymer Solutions with PC-SAFT  

Science Journals Connector (OSTI)

Liquid?Liquid Equilibria for Binary and Ternary Polymer Solutions with PC-SAFT ... The algorithms are used for investigating the correlative and predictive capabilities of the thermodynamic model PC-SAFT. ... The algorithms are used for testing of a state-of-the-art model in polymer thermodynamics, PC-SAFT, by Gross and Sadowski. ...

Thomas Lindvig; Michael L. Michelsen; Georgios M. Kontogeorgis

2004-01-21T23:59:59.000Z

488

Continuous transitions between composite Fermi liquid and Landau Fermi liquid: A route to fractionalized Mott insulators  

E-Print Network [OSTI]

One of the most successful theories of a non-Fermi-liquid metallic state is the composite Fermi-liquid (CFL) theory of the half-filled Landau level. In this paper, we study continuous quantum phase transitions out of the ...

Barkeshli, Maissam

489

Removal of arsenic compounds from petroliferous liquids  

DOE Patents [OSTI]

The present invention in one aspect comprises a process for removing arsenic from petroliferous-derived liquids by contacting said liquid with a divinylbenzene-crosslinked polystyrene polymer (i.e. PS-DVB) having catechol ligands anchored to said polymer, said contacting being at an elevated temperature. In another aspect, the invention is a process for regenerating spent catecholated polystyrene polymer by removal of the arsenic bound to it from contacting petroliferous liquid in accordance with the aspect described above which regenerating process comprises: (a) treating said spent catecholated polystyrene polymer with an aqueous solution of at least one member selected from the group consisting of carbonates and bicarbonates of ammonium, alkali metals, and alkaline earth metals, said solution having a pH between about 8 and 10, and said treating being at a temperature in the range of about 20/sup 0/ to 100/sup 0/C; (b) separating the solids and liquids from each other. In a preferred embodiment the regeneration treatment is in two steps wherein step: (a) is carried out with an aqueous alcoholic carbonate solution which includes at least one lower alkyl alcohol, and, steps (c) and (d) are added. Steps (c) and (d) comprise: (c) treating the solids with an aqueous alcoholic solution of at least one ammonium, alkali or alkaline earth metal bicarbonate at a temperature in the range of about 20 to 100/sup 0/C; and (d) separating the solids from the liquids.

Fish, R.H.

1984-04-06T23:59:59.000Z

490

Liquid-absorption preconcentrator sampling instrument  

DOE Patents [OSTI]

A system is described for detecting trace concentrations of an analyte in air and includes a preconcentrator for the analyte and an analyte detector. The preconcentrator includes an elongated tubular container in which is disposed a wettable material extending substantially the entire length of the container. One end of the wettable material is continuously wetted with an analyte-sorbing liquid, which flows to the other end of the container. Sample air is flowed through the container in contact with the wetted material for trapping and preconcentrating the traces of analyte in the sorbing liquid, which is then collected at the other end of the container and discharged to the detector. The wetted material may be a wick comprising a bundle of fibers, one end of which is immersed in a reservoir of the analyte-sorbing liquid, or may be a liner disposed on the inner surface of the container, with the sorbing liquid being centrifugally dispersed onto the liner at one end thereof. The container is preferably vertically oriented so that gravity effects the liquid flow. 4 figs.

Zaromb, S.

1990-12-11T23:59:59.000Z

491

Synthesis, structural characterization and ferrimagnetic property of MnPS{sub 3} intercalated with nickel(II) cyclopolyamine complex cations  

SciTech Connect (OSTI)

Two new intercalation compounds were prepared by the reactions of Ni(II) cyclopolyamine complex cations with a preintercalate Mn{sub 1-x}PS{sub 3}K{sub 2x}(H{sub 2}O){sub y}, respectively, through 'ion exchange' process. Their structures were characterized by elemental analysis, X-ray powder diffraction and infrared spectroscopy. The lattice spacing increased 0.567 and 1.093nm with respect to the pristine MnPS{sub 3}. Ferrimagnetism of the intercalates was confirmed by SQUID experiment with T{sub c} at 40 and 33K, respectively.

Yang Kai [Department of Chemistry, Wuhan University, Luojia Hill, Wuhan City, Hubei Province 430072 (China); Su Xu [Department of Chemistry, Wuhan University, Luojia Hill, Wuhan City, Hubei Province 430072 (China); Zhang Xuan [Department of Chemistry, Wuhan University, Luojia Hill, Wuhan City, Hubei Province 430072 (China); Chen Xingguo [Department of Chemistry, Wuhan University, Luojia Hill, Wuhan City, Hubei Province 430072 (China); Fu Enqin [Department of Chemistry, Wuhan University, Luojia Hill, Wuhan City, Hubei Province 430072 (China)]. E-mail: fueq@chem.whu.edu.cn; Qin Jingui [Department of Chemistry, Wuhan University, Luojia Hill, Wuhan City, Hubei Province 430072 (China); Inokuchi, Makoto [Faculty of Science and Engineering, Department of Materials Science and Environmental Engineering, Tokyo University of Science, Yamaguchi 1-1-1 Daigaku-dori, Onoda, Yamaguchi 756-0884 (Japan)]. E-mail: inokuchi@ed.yama.tus.ac.jp; Kinoshita, Minoru [Faculty of Science and Engineering, Department of Materials Science and Environmental Engineering, Tokyo University of Science, Yamaguchi 1-1-1 Daigaku-dori, Onoda, Yamaguchi 756-0884 (Japan)

2004-11-01T23:59:59.000Z

492

Gram-scale separation of curium from americium using alpha-hydroxyisobutyric acid in high-pressure cation columns  

SciTech Connect (OSTI)

Quantities of heavy element (americium and curium) up to 2.3 g have been successfully separated by chromatographic elution from cation resin using alpha-hydroxyisobutyrate in equipment originally designed for decigram-scale separations of /sup 252/Cf and heavier elements. The high-pressure ion exchange process was reliable and relatively easy to operate. Overall curium recoveries of 80 to 90% were readily achieved with decontamination from americium by factors of 400 to 500. The product and waste streams are both in forms readily coupled to further processing steps.

Bigelow, J.E.; Benker, D.E.; Chattin, F.R.; King, L.J.; Knauer, J.B.; Ross, R.G.; Stacy, R.G.; Wiggins, J.T.

1984-01-01T23:59:59.000Z

493

18F-Labeled Magnetic-Upconversion Nanophosphors via Rare-Earth Cation-Assisted Ligand Assembly  

Science Journals Connector (OSTI)

18F-Labeled Magnetic-Upconversion Nanophosphors via Rare-Earth Cation-Assisted Ligand Assembly ... The inset of Figure S7 shows the bright-field photo of AA-Gd-UCNPs dispersed in PBS for 0 and 48 h. ... To determine whether UCNPs coated with folic acid and aminocaproic acid (FA-AA-Gd-UCNPs, FA:AA = 1:9) could be used for cellular targeted imaging, we performed in vitro cellular studies using FR-positive [FR(+)] KB cell lines and FR-negative [FR(?)] MCF-7 cell lines. ...

Qian Liu; Yun Sun; Chenguang Li; Jing Zhou; Chunyan Li; Tianshe Yang; Xianzhong Zhang; Tao Yi; Dongmei Wu; Fuyou Li

2011-03-08T23:59:59.000Z

494

Influence of Heteroanion and Ammonium Cation Size on the Composition and Gas-Phase Fragmentation of Polyoxovanadates  

SciTech Connect (OSTI)

This paper describes the results of a systematic experimental investigation of the influence of different size cationic ammonium ligands and heteroanions on the composition, ionic charge state and gas-phase fragmentation pathways of anionic polyoxovanadates synthesized in solution. Four separate solutions of olyoxometalates (POMs) were prepared using all possible combinations of the tetraethylammonium [(C2H5)4N+] ligand, chloride (Cl-) heteroanion, tetrabutylammonium [(C4H9)4N+] ligand and acetate (CH3CO2-) heteroanion. Employing electrospray ionization combined with high-resolution mass spectrometry (ESI-MS) we demonstrate that POM solutions synthesized using the small [(C2H5)4N+] ligand and Cl-heteroanion are composed predominately of large doubly and triply charged chlorine containing clusters with a size distribution centered at fourteen vanadium atoms. POM solutions prepared using the Cl- anion and [(C4H9)4N+] ligand are shown to contain slightly larger clusters with fifteen and sixteen vanadium atoms, thereby indicating that the size of the cationic ammonium ligand exerts only a weak influence on the polymerization of polyoxovanadates. POM solutions prepared using (C2H5)4NCl and (C4H9)4NCl also produced peaks consistent with the attachment of one and two ammonium cations to the larger clusters. Solutions prepared using the large CH3CO2 - heteroanion, in contrast, are demonstrated to contain much smaller singly and doubly *Manuscript Click here to view linked References 2 charged clusters with a size distribution centered at six vanadium atoms. In addition, while incorporation of one and two ammonium ligands into the smaller clusters was observed, no POMs containing the CH3CO2 - heteroanion were identified. The gas-phase fragmentation pathways of representative POMs containing one and two ammonium ligands were examined using collision induced dissociation (CID) and mass spectrometry. Similar primary fragmentation pathways involving partial loss of a ligand -[(CxHy)3N+ x = 2,4; y = 5,9] were observed for clusters containing both one and two ligands largely independent of the size, composition and charge state of the precursor ion. The [(C4H9)4N+] ligand was found to exhibit stronger interactions with the core of the POMs resulting in higher abundances of fragment ions containing (C4H9) units compared to (C2H5) units from [(C2H5)4N+]. These results provide fundamental insight into the interactions between anionic metal oxide clusters, heteroanions and cationic ammonium ligands that are responsible for the size and composition controlled synthesis of POMs in solution.

Johnson, Grant E.; Al Hasan, Naila M.; Laskin, Julia

2013-11-15T23:59:59.000Z

495

EIA - International Energy Outlook 2007-Liquids Production Projections  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production Projection Tables (1990-2030) Liquids Production Projection Tables (1990-2030) International Energy Outlook 2007 Liquids Production Projections Tables (1990-2030) Formats Data Table Titles (1 to 19 complete) Liquids Production Projections Tables. Need help, contact the National Energy Information Center at 202-586-8800. Liquids Production Projections Tables. Need help, contact the National Energy Information Center at 202-586-8800. Table G1 World Total Liquids Production by Region and Country, Reference Case Table G1. World Total Liquids Production by Region and Country, Reference Case. Need help, contact the National Energy Information Center at 202-586-8800. Table G2 World Conventional Liquids Production by Region and Country, Reference Case Table G2. World Conventional Liquids Production by Region and Country, Reference Case. Need help, contact the National Energy Information Center at 202-586-8800.

496

LiquidPiston Inc | Open Energy Information  

Open Energy Info (EERE)

LiquidPiston Inc LiquidPiston Inc Jump to: navigation, search Name LiquidPiston Inc Address 21C Old Windsor Road Place Bloomfield, Connecticut Zip 06002 Sector Efficiency Product New combustion engine technology to drastically improve efficiency Website http://www.liquidpiston.com/ Coordinates 41.8572877°, -72.7032021° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.8572877,"lon":-72.7032021,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

497

Oil/Liquids | Open Energy Information  

Open Energy Info (EERE)

Oil/Liquids Oil/Liquids < Oil Jump to: navigation, search Click to return to AEO2011 page AEO2011 Data From AEO2011 report Full figure data for Figure 93. Reference Case Tables Table 1. Total Energy Supply, Disposition, and Price Summary Table 11. Liquid Fuels Supply and Disposition Table 12. Petroleum Product Prices Table 14. Oil and Gas Supply Table 21. Carbon Dioxide Emissions by Sector and Source - New England Table 22. Carbon Dioxide Emissions by Sector and Source- Middle Atlantic Table 23. Carbon Dioxide Emissions by Sector and Source - East North Central Table 24. Carbon Dioxide Emissions by Sector and Source - West North Central Table 25. Carbon Dioxide Emissions by Sector and Source - South Atlantic Table 26. Carbon Dioxide Emissions by Sector and Source - East South

498

Coal to Liquids | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Liquids Liquids Coal to Liquids Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in Charleston, WV, the Yeager facility was constructed and operated with support from the Office of Fossil Energy’s National Energy Technology Laboratory. Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in Charleston, WV, the Yeager facility was constructed and operated with support from the Office of Fossil Energy's National Energy Technology Laboratory. The Hydrogen and Clean Coal Fuels Program supports DOE's strategic goals of increasing energy security, reducing environmental impact of energy use,

499

DOE studies on coal-to-liquids  

SciTech Connect (OSTI)

The US DOE National Energy Technology Laboratory has issued reports that examine the feasibility of coal-to-liquids (CTL) facilities, both general and site specific, which are available at www.netl.gov/energy-analyses/ref-shelf.html. The US Department of Defence has been investigating use of Fischer-Tropsch fuels. Congress is considering various CTL proposals while the private sector is building pilot plants and performing feasibility studies for proposed plants. The article includes a table listing 14 coal-to-liquids plants under consideration. The private sector has formed the coal-to-liquids coalition (www.futurecoalfuels.org). The article mentions other CTL projects in South Africa, China, Indonesia, the Philippines and New Zealand. 1 tab.

NONE

2007-07-01T23:59:59.000Z

500

Liquid Crystal Microfluidics for Tunable Flow Shaping  

Science Journals Connector (OSTI)

We explore the flow of a nematic liquid crystal in microfluidic channels with a rectangular cross section through experiments and numerical modeling. The flow profile and the liquid crystal orientational profile show three distinct regimes of weak, medium, and strong flow as the driving pressure is varied. These are identified by comparing polarizing optical microscopy experiments and numerical solutions of the nematofluidic equations of motion. The relative stability of the regimes is related to the de Gennes characteristic shear-flow lengths e1 and e2, together with the channels aspect ratio w/d. Finally, we show that the liquid crystalline microfluidic flow can be fully steered from left to right of a simple microchannel by applying transverse temperature gradients.

Anupam Sengupta; Uro Tkalec; Miha Ravnik; Julia M. Yeomans; Christian Bahr; Stephan Herminghaus

2013-01-25T23:59:59.000Z