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1

Cation geothermometry in oil field waters  

SciTech Connect (OSTI)

The assumptions used in the development of cation ratio geothermometers are: (1) the ratios of the cations are controlled by cation exchange between solid silicate phases, (2) aluminum is conserved in the solid phases, and (3) neither hydrogen ions nor CO[sub 2] enter into the net reactions. These assumptions do not apply to oilfield waters where organic species are present and commonly abundant. Nine different published cation geothermometers of Na/K, Na-K-Ca, Na-K-Ca-Mg, and Mg/Li were applied to 309 water samples from both oilfield and geothermal wells. None of the cation geothermometers predicted consistent or accurate temperatures for the oilfield waters. Plots of measured v. predicted temperature for oilfield water samples gave correlation coefficients of less than 0.35. In contrast, those same plots for geothermal water samples within the same temperature range gave correlation coefficients between 0.45 and 0.95. This analysis suggests that the presence of organic species exerts a strong control on the cation ratios. Organic species form complexes of varying stability with the cations. This, in turn, changes the relative concentrations of the cations in solution over that which is expected when cation exchange between silicate phases controls the ratios. Organic complexes also strongly affect pH and P[sub CO[sub 2

Smith, L.K.; Dunn, T.L.; Surdam, R.C. (Univ. of Wyoming, Laramie, WY (United States))

1992-01-01T23:59:59.000Z

2

Category:Liquid Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to: navigation,AreasFluidGeothermometry Jump

3

Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -InformationGeothermometry Details

4

Multicomponent Equilibrium Models for Testing Geothermometry Approaches  

SciTech Connect (OSTI)

Geothermometry is an important tool for estimating deep reservoir temperature from the geochemical composition of shallower and cooler waters. The underlying assumption of geothermometry is that the waters collected from shallow wells and seeps maintain a chemical signature that reflects equilibrium in the deeper reservoir. Many of the geothermometers used in practice are based on correlation between water temperatures and composition or using thermodynamic calculations based a subset (typically silica, cations or cation ratios) of the dissolved constituents. An alternative approach is to use complete water compositions and equilibrium geochemical modeling to calculate the degree of disequilibrium (saturation index) for large number of potential reservoir minerals as a function of temperature. We have constructed several “forward” geochemical models using The Geochemist’s Workbench to simulate the change in chemical composition of reservoir fluids as they migrate toward the surface. These models explicitly account for the formation (mass and composition) of a steam phase and equilibrium partitioning of volatile components (e.g., CO2, H2S, and H2) into the steam as a result of pressure decreases associated with upward fluid migration from depth. We use the synthetic data generated from these simulations to determine the advantages and limitations of various geothermometry and optimization approaches for estimating the likely conditions (e.g., temperature, pCO2) to which the water was exposed in the deep subsurface. We demonstrate the magnitude of errors that can result from boiling, loss of volatiles, and analytical error from sampling and instrumental analysis. The estimated reservoir temperatures for these scenarios are also compared to conventional geothermometers. These results can help improve estimation of geothermal resource temperature during exploration and early development.

Cooper, D. Craig; Carl D. Palmer; Robert W. Smith; Travis L. McLing

2013-02-01T23:59:59.000Z

5

Integrated Chemical Geothermometry System for Geothermal Exploration  

Broader source: Energy.gov (indexed) [DOE]

interpretations) * Reduce exploration and development costs Innovation * Numerical optimization of multicomponent chemical geothermometry at multiple locations * Integration with...

6

Liquid Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey,(Monaster And Coolbaugh, 2007)is 109.Lindley,Lipscomb County,

7

Improvements in geothermometry. Final technical report  

SciTech Connect (OSTI)

The following are covered: the basis of the Na-K-Ca geothermometer, geothermometry via model calculations, non ideality and complexing, and experimental calibration.

Potter, J.; Dibble, W.; Parks, G.; Nur, A.

1982-07-01T23:59:59.000Z

8

Geothermometry At Central Nevada Seismic Zone Region (Shevenell...  

Open Energy Info (EERE)

ENERGYGeothermal Home Exploration Activity: Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De Rocher, 2005) Exploration Activity Details Location...

9

Geothermometry At Long Valley Caldera Geothermal Area (Farrar...  

Open Energy Info (EERE)

Home Exploration Activity: Geothermometry At Long Valley Caldera Geothermal Area (Farrar, Et Al., 2003) Exploration Activity Details Location Long Valley Caldera Geothermal...

10

Geothermometry At Nevada Test And Training Range Area (Sabin...  

Open Energy Info (EERE)

Nevada Test And Training Range Area (Sabin, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Nevada Test And...

11

Radiation induced redox reactions and fragmentation of constituent ions in ionic liquids II. Imidazolium cations.  

SciTech Connect (OSTI)

In part 1 of this study, radiolytic degradation of constituent anions in ionic liquids (ILs) was examined. The present study continues the themes addressed in part 1 and examines the radiation chemistry of 1,3-dialkyl substituted imidazolium cations, which currently comprise the most practically important and versatile class of ionic liquid cations. For comparison, we also examined 1,3-dimethoxy- and 2-methyl-substituted imidazolium and 1-butyl-4-methylpyridinium cations. In addition to identification of radicals using electron paramagnetic resonance spectroscopy (EPR) and selective deuterium substitution, we analyzed stable radiolytic products using {sup 1}H and {sup 13}C nuclear magnetic resonance (NMR) and tandem electrospray ionization mass spectrometry (ESMS). Our EPR studies reveal rich chemistry initiated through 'ionization of the ions': oxidation and the formation of radical dications in the aliphatic arms of the parent cations (leading to deprotonation and the formation of alkyl radicals in these arms) and reduction of the parent cation, yielding 2-imidazolyl radicals. The subsequent reactions of these radicals depend on the nature of the IL. If the cation is 2-substituted, the resulting 2-imidazolyl radical is relatively stable. If there is no substitution at C(2), the radical then either is protonated or reacts with the parent cation forming a C(2)-C(2) {sigma}{sigma}*-bound dimer radical cation. In addition to these reactions, when methoxy or C{sub {alpha}}-substituted alkyl groups occupy the N(1,3) positions, their elimination is observed. The elimination of methyl groups from N(1,3) was not observed. Product analyses of imidazolium liquids irradiated in the very-high-dose regime (6.7 MGy) reveal several detrimental processes, including volatilization, acidification, and oligomerization. The latter yields a polymer with m/z of 650 {+-} 300 whose radiolytic yield increases with dose (0.23 monomer units per 100 eV for 1-methyl-3-butylimidazolium trifluorosulfonate). Gradual generation of this polymer accounts for the steady increase in the viscosity of the ILs upon irradiation. Previous studies at lower dose have missed this species due to its wide mass distribution (stretching out to m/z 1600) and broad NMR lines, which make it harder to detect at lower concentrations. Among other observed changes is the formation of water immiscible fractions in hydrophilic ILs and water miscible fractions in hydrophobic ILs. The latter is due to anion fragmentation. The import of these observations for use of ILs as extraction solvents in nuclear cycle separations is discussed.

Shkrob, I. A.; Marin, T. W.; Chemerisov, S. D.; Hatcher, J.; Wishart, J. (Chemical Sciences and Engineering Division); (BNL)

2011-04-14T23:59:59.000Z

12

Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl...  

Open Energy Info (EERE)

Basis Temperature estimation of valley-fill hydrothermal reservoir Notes Si, Na-K, & Na-K-Ca geothermometry estimates yielded a reservoir temperature range of 97 to 188...

13

Microbial impacts on geothermometry temperature predictions  

SciTech Connect (OSTI)

Conventional geothermometry approaches assume that the composition of a collected water sample originating in a deep geothermal reservoir still reflects chemical equilibration of the water with the deep reservoir rocks. However, for geothermal prospecting samples whose temperatures have dropped to <120°C, temperature predictions may be skewed by the activity of microorganisms; microbial metabolism can drastically and rapidly change the water’s chemistry. We hypothesize that knowledge of microbial impacts on exploration sample geochemistry can be used to constrain input into geothermometry models and thereby improve the reliability of reservoir temperature predictions. To evaluate this hypothesis we have chosen to focus on sulfur cycling, because of the significant changes in redox state and pH associated with sulfur chemistry. Redox and pH are critical factors in defining the mineral-fluid equilibria that form the basis of solute geothermometry approaches. Initially we are developing assays to detect the process of sulfate reduction, using knowledge of genes specific to sulfate reducing microorganisms. The assays rely on a common molecular biological technique known as quantitative polymerase chain reaction (qPCR), which allows estimation of the number of target organisms in a particular sample by enumerating genes specific to the organisms rather than actually retrieving and characterizing the organisms themselves. For quantitation of sulfate reducing genes using qPCR, we constructed a plasmid (a piece of DNA) containing portions of two genes (known as dsrA and dsrB) that are directly involved with sulfate reduction and unique to sulfate reducing microorganisms. Using the plasmid as well as DNA from other microorganisms known to be sulfate reducers or non-sulfate reducers, we developed qPCR protocols and showed the assay’s specificity to sulfate reducers and that a qPCR standard curve using the plasmid was linear over >5 orders of magnitude. As a first test with actual field samples, the assay was applied to DNA extracted from water collected at springs located in and around the town of Soda Springs, Idaho. Soda Springs is located in the fold and thrust belt on the eastern boundary of the track of the Yellowstone Hotspot, where a deep carbon dioxide source believed to originate from Mississippian limestone contacts acidic hydrothermal fluids at depth. Both sulfate and sulfide have been measured in samples collected previously at Soda Springs. Preliminary results indicate that sulfate reducing genes were present in each of the samples tested. Our work supports evaluation of the potential for microbial processes to have altered water chemistry in geothermal exploration samples.

Yoshiko Fujita; David W. Reed; Kaitlyn R. Nowak; Vicki S. Thompson; Travis L. McLing; Robert W. Smith

2013-02-01T23:59:59.000Z

14

Geothermometry At Neal Hot Springs Geothermal Area (U.S. Geothermal...  

Open Energy Info (EERE)

DOE-funding Unknown Exploration Basis Geothermometry analysis was done on geothermal fluids from the first production well to estimate the reservoirs temperature at deeper...

15

Improvements in geothermometry. Final technical report. Rev  

SciTech Connect (OSTI)

Alkali and alkaline earth geothermometers are useful for estimating geothermal reservoir temperatures, though a general theoretical basis has yet to be established and experimental calibration needs improvement. Equilibrium cation exchange between feldspars provided the original basis for the Na-K and Na-K-Ca geothermometers (Fournier and Truesdell, 1973), but theoretical, field and experimental evidence prove that neither equilibrium nor feldspars are necessary. Here, evidence is summarized in support of these observations, concluding that these geothermometers can be expected to have a surprisingly wide range of applicability, but that the reasons behind such broad applicability are not yet understood. Early experimental work proved that water-rock interactions are slow at low temperatures, so experimental calibration at temperatures below 150/sup 0/ is impractical. Theoretical methods and field data were used instead for all work at low temperatures. Experimental methods were emphasized for temperatures above 150/sup 0/C, and the simplest possible solid and solution compositions were used to permit investigation of one process or question at a time. Unexpected results in experimental work prevented complete integration of the various portions of the investigation.

Potter, J.; Dibble, W.; Parks, G.; Nur, A.

1982-08-01T23:59:59.000Z

16

Selectivity Control in Synergistic Liquid-Liquid Anion Exchange of Univalent Anions via Structure-Specific Cooperativity between Quaternary Ammonium Cations and Anion Receptors  

SciTech Connect (OSTI)

Two anion receptors enhance liquid-liquid anion exchange when added to quaternary alkylammonium chloride anion exchangers, but with a striking dependence upon the structure of the alkylammonium cation. Two anion receptors were investigated, meso-octamethylcalix[4]pyrrole (C4P) and the bisthiourea tweezer 1,1'-(propane-1,3-diyl)bis(3-(4-sec-butylphenyl)thiourea (BTU). C4P has the unique ability in its cone anion-binding conformation to accept an appropriately sized electropositive species in the resulting cup formed by its four electron-rich pyrrole groups, while BTU is not expected to be predisposed for a specific host-guest interaction with the quaternary ammonium cations. It was therefore hypothesized that synergism between C4P and methyltri(C8,10)alkylammonium chloride (Aliquat 336) would be uniquely pronounced owing to insertion of the methyl group of the Aliquat cation into the C4P cup, and we present herein data supporting this expectation. While synergism is comparatively weak for both exchangers with the BTU receptor, synergism between C4P and Aliquat 336 is indeed so strong that anion exchange prefers chloride over more extractable nitrate and trifluoroacetate, effectively overcoming the ubiquitous Hofmeister bias. A thermochemical analysis of synergistic anion exchange has been provided for the first time, unraveling the observed selectivity behavior and resulting in the estimation of binding constants for C4P with the ion pairs of A336+ with Cl , Br , OAcF3 , NO3 , and I . The uniquely strong positive cooperativity between A336 and C4P underscores the advantage of a supramolecular approach in the design of synergistic anion exchange systems.

Borman, Christopher J [ORNL; Bonnesen, Peter V [ORNL; Moyer, Bruce A [ORNL

2012-01-01T23:59:59.000Z

17

Investigation of gamma induced degradation of Amberlite 200 cation resin by mass spectrometer and liquid chromatograph  

E-Print Network [OSTI]

, provisions were made for collecting samples of any gas produced. The irradiated resin was exposed to total 7 8 8 accumulations of 1. 0129X10 , 1. 0215XIO , and 5. 0168X10 Rads in three separate runs. It should be noted that the same amount of demineral.... (December 1977) Albert Antonio Freitag, B. S. , Texas A&M University Chairman of Advisory Committee: Dr. James 8. Smathers Amberlite 200 cation exchange resin was irradiated by gamma 7 8 radiation to doses of 10 to 5X10 Rads. Results of the analysis...

Freitag, Albert Antonio

1977-01-01T23:59:59.000Z

18

Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy of liquid microjets  

E-Print Network [OSTI]

of the interaction of the carboxylate with lithium; this isinteraction strengths of the monovalent cations of sodium, potassium, and lithiumlithium acetate revealing distinct shifts between the cations, indicative of preferential interactions.

Uejio, Janel S.

2008-01-01T23:59:59.000Z

19

Lubricants or lubricant additives composed of ionic liquids containing ammonium cations  

DOE Patents [OSTI]

A lubricant or lubricant additive is an ionic liquid alkylammonium salt. The alkylammonium salt has the structure R.sub.xNH.sub.(4-x).sup.+,[F.sub.3C(CF.sub.2).sub.yS(O).sub.2].sub.2N.sup- .- where x is 1 to 3, R is independently C.sub.1 to C.sub.12 straight chain alkyl, branched chain alkyl, cycloalkyl, alkyl substituted cycloalkyl, cycloalkyl substituted alkyl, or, optionally, when x is greater than 1, two R groups comprise a cyclic structure including the nitrogen atom and 4 to 12 carbon atoms, and y is independently 0 to 11. The lubricant is effective for the lubrication of many surfaces including aluminum and ceramics surfaces.

Qu, Jun (Knoxville, TN) [Knoxville, TN; Truhan, Jr.,; John J. (Cookeville, TN) [Cookeville, TN; Dai, Sheng (Knoxville, TN) [Knoxville, TN; Luo, Huimin (Knoxville, TN) [Knoxville, TN; Blau, Peter J. (Knoxville, TN) [Knoxville, TN

2010-07-13T23:59:59.000Z

20

Geothermometry At Lassen Volcanic National Park Area (Janik ...  

Open Energy Info (EERE)

sample taken had a pH of 8.35 and contained 2100 ppm Cl and 0.55 ppm NH3. Ratios of Na+K+ and Na+Cl remained nearly constant throughout the flow test. Cation geothermometers...

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

An experimental investigation into the effects of fluid composition on certain geothermometry methods  

E-Print Network [OSTI]

at the lower temperatures, and 5) thermal waters do not mix with shallower, cooler ground water. Silica geothermometer The dissolved silica content of geothermal water is used in geothermometry because silica is present in most geologic settings... that the time required to attain equilibrium was 100 hours at 200 C and from four to sixteen hours at 0 360 C. Work at lower temperatures (25 C, 60 -100 C) was done by van Lier, de Bruyn, and Overbeek (1960) using finely ground quartz particles...

Pope, Leslie Anne

1985-01-01T23:59:59.000Z

22

Effect of electrolytes and temperature on dications and radical cations of carotenoids: Electrochemical, optical absorption, and high-performance liquid chromatography studies  

SciTech Connect (OSTI)

The effect of supporting electrolytes and temperature on the behavior of dications and radical cations of carotenoids is studied. Cyclic voltammograms (CVs) of canthaxanthin (I) at 23 and {minus}25 C show that Car{sup sm{underscore}bullet+} of I has similar stability during the time of the CV scan, when using tetrabutylammonium perchlorate (TBAPC), tetrabutylammonium tetrafluoroborate (TBATFB), or tetrabutylammonium hexafluorophosphate (TBAHFP) as supporting electrolyte. However, the stability of Car{sup 2+} decreases when using TBAPC or TBATFB; {beta}-carotene (II) shows similar behavior. The CV of I at {minus}25 C shows a strong cathodic wave (wave 6) near {minus}0.15 V (vs Ag) with an intensity about half that of the neutral oxidation wave when TBAPC or TBATFB is the supporting electrolyte. When TBAHFP is used, wave 6 (ca. {minus}0.05 V vs Ag) is ca. 8 times weaker than when TBAPC or TBATFB is used. This wave results from the reduction of a species that may be a decay product of Car{sup 2+} of I. Results show that these electrolytes commonly used in electrochemical studies may affect the studied systems to different extents. In simultaneous bulk electrolysis (BE) and optical absorption spectroscopic measurements, the absorption band of Car{sup 2+} of I in the presence of 0.1 M TBAHFP can be observed by lowering the BE temperature to {minus}20 C. In the presence of 0.1 M TBAPC or TBATFB, this band is not observed, even at {minus}50 C. Isomerization of neutral I (as shown by HPLC and its blue absorption band shift) is observed only when the Car{sup 2+} absorption band is absent during BE. This observation, along with an increase of the neutral absorption band after stopping BE, suggests that the equilibrium Car + Car{sup 2+} {r{underscore}equilibrium} 2Car{sup {sm{underscore}bullet}+} is shifted to the left because Car{sup 2+} decays more quickly than Car{sup {sm{underscore}bullet}+} in the presence of electrolyte and this is a major path for formation of cis neutral species from cis Car{sup {sm{underscore}bullet}+}. The optical absorption of Car{sup 2+} of I at 18 C in the presence of 0.1 M TBAHFP is obtained, which suggests that Car{sup 2+} of I is not as unstable at room temperature in the presence of TBAHFP as was thought before.

He, Z.; Kispert, L.D.

1999-11-25T23:59:59.000Z

23

Method for the chromatographic separation of cations from aqueous samples  

DOE Patents [OSTI]

An extraction chromatographic material is described for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support. 7 figs.

Horwitz, E.P.; Chiarizia, R.; Dietz, M.L.

1997-07-29T23:59:59.000Z

24

Method for the chromatographic separation of cations from aqueous samples  

DOE Patents [OSTI]

An extraction chromatographic material is described for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methane-diphosphonic acid on an inert particulate support. 7 figs.

Horwitz, E.P.; Chiarizia, R.; Dietz, M.L.

1998-12-22T23:59:59.000Z

25

Cation Uptake and Allocation by Red Pine Seedlings under Cation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Uptake and Allocation by Red Pine Seedlings under Cation-Nutrient Stress in a Column Growth Experiment. Cation Uptake and Allocation by Red Pine Seedlings under Cation-Nutrient...

26

Plant rhamnogalacturonan II complexation of heavy metal cations  

DOE Patents [OSTI]

The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations.

O'Neill, Malcolm A. (Winterville, GA); Pellerin, Patrice J. M. (Montpellier, FR); Warrenfeltz, Dennis (Athens, GA); Vidal, Stephane (Combaillaux, FR); Darvill, Alan G. (Athens, GA); Albersheim, Peter (Athens, GA)

1999-01-01T23:59:59.000Z

27

Plant rhamnogalacturonan II complexation of heavy metal cations  

DOE Patents [OSTI]

The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations. 15 figs.

O`Neill, M.A.; Pellerin, P.J.M.; Warrenfeltz, D.; Vidal, S.; Darvill, A.G.; Albersheim, P.

1999-03-02T23:59:59.000Z

28

Synthesis of ionic liquids  

DOE Patents [OSTI]

Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic liqand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

Dai, Sheng [Knoxville, TN; Luo, Huimin [Knoxville, TN

2008-09-09T23:59:59.000Z

29

Low cation coordination in oxide melts  

SciTech Connect (OSTI)

The complete set of Faber-Ziman partial pair distribution functions for a rare earth oxide liquid were measured for the first time by combining aerodynamic levitation, neutron diffraction, high energy x-ray diffraction and isomorphic substitution using Y2 O3 and Ho2 O3 melts. The average Y- O coordination is measured to be 5.5(2), which is significantly less than the octahedral coordination of crystalline Y2 O3 (or Ho2 O3 ). Investigation of high temperature La2 O3 , ZrO2 , SiO2 , and Al2 O3 melts by x-ray diffraction and molecular dynamics simulations also show lower-than-crystal cation- oxygen coordination. These measurements suggest a general trend towards lower M-O coordination compared to their crystalline counterparts. It is found that this coordination number drop is larger for lower field strength, larger radius cations and is negligible for high field strength (network forming) cations. These findings have broad implications for predicting the local structure and related physical properties of metal-oxide melts and oxide glasses.

Skinner, Lawrie [State University of New York, Stony Brook] [State University of New York, Stony Brook; Benmore, Chris J [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Du, Jincheng [University of North Texas] [University of North Texas; Weber, Richard [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Neuefeind, Joerg C [ORNL] [ORNL; Tumber, Sonia [Materials Development, Inc., Evanston, IL] [Materials Development, Inc., Evanston, IL; Parise, John B [Stony Brook University (SUNY)] [Stony Brook University (SUNY)

2014-01-01T23:59:59.000Z

30

Comproportionation of Cationic and Anionic Tungsten Complexes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comproportionation of Cationic and Anionic Tungsten Complexes Having an N-Heterocyclic Carbene Ligand to Give the Isolable 17 Comproportionation of Cationic and Anionic Tungsten...

31

Cationic electrodepositable coating composition comprising lignin  

SciTech Connect (OSTI)

A cationic electrodepositable coating composition is disclosed. The present invention in directed to a cationic electrodepositable coating composition comprising a lignin-containing cationic salt resin, that comprises (A) the reaction product of: lignin, an amine, and a carbonyl compound; (B) the reaction product of lignin, epichlorohydrin, and an amine; or (C) combinations thereof.

Fenn, David; Bowman, Mark P; Zawacky, Steven R; Van Buskirk, Ellor J; Kamarchik, Peter

2013-07-30T23:59:59.000Z

32

Geology, hydrothermal petrology, stable isotope geochemistry, and fluid inclusion geothermometry of LASL geothermal test well C/T-1 (Mesa 31-1), East Mesa, Imperial Valley, California, USA  

SciTech Connect (OSTI)

Borehole Mesa 31-1 (LASL C/T-1) is an 1899-m (6231-ft) deep well located in the northwestern part of the East Mesa Geothermal Field. Mesa 31-1 is the first Calibration/Test Well (C/T-1) in the Los Alamos Scientific Laboratory (LASL), Geothermal Log Interpretation Program. The purpose of this study is to provide a compilation of drillhole data, drill cuttings, well lithology, and formation petrology that will serve to support the use of well LASL C/T-1 as a calibration/test well for geothermal logging. In addition, reviews of fluid chemistry, stable isotope studies, isotopic and fluid inclusion geothermometry, and the temperature log data are presented. This study provides the basic data on the geology and hydrothermal alteration of the rocks in LASL C/T-1 as background for the interpretation of wireline logs.

Miller, K.R.; Elders, W.A.

1980-08-01T23:59:59.000Z

33

Liquid-Liquid Extraction Processes  

E-Print Network [OSTI]

Liquid-liquid extraction is the separation of one or more components of a liquid solution by contact with a second immiscible liquid called the solvent. If the components in the original liquid solution distribute themselves differently between...

Fair, J. R.; Humphrey, J. L.

1983-01-01T23:59:59.000Z

34

Cation Geothermometers | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV Economics By BuildingCategory: Wind,000Cation

35

TETRAALKYLPHOSPHONIUM POLYOXOMETALATES AS NOVEL IONIC LIQUIDS.  

SciTech Connect (OSTI)

The pairing of a Lindqvist or Keggin polyoxometalate (POM) anion with an appropriate tetraalkylphosphonium cation, [R{sub 3}R{prime}P]{sup +}, has been shown to yield an original family of ionic liquids (POM-ILs), among them salts liquid at or near ambient temperature. The physicochemical properties of several such 'inorganic liquids', in particular their thermal properties, suggests the possible application of these compounds as robust, thermally-stable solvents for liquid-liquid extraction. A preliminary evaluation of the potential of POM-ILs in this application is presented.

DIETZ,M.L.; RICKERT, P.G.; ANTONIO, M.R.; FIRESTONE, M.A.; WISHART, J.F.; SZREDER, T.

2007-11-30T23:59:59.000Z

36

Polyelectrolyte Condensation Induced by Linear Cations  

E-Print Network [OSTI]

We examine the role of the condensing agent in the formation of polyelectrolyte bundles, via grand-canonical Monte Carlo simulations. Following recent experiments we use linear, rigid divalent cations of various lengths to induce condensation. Our results clarify and explain the experimental results for short cations. For longer cations we observe novel condensation behavior owing to alignment of the cations. We also study the role of the polyelectrolyte surface charge density, and find a nonmonotonic variation in bundle stability. This nonmonotonicity captures two trends that have been observed in separate experiments.

Camilo Guáqueta; Erik Luijten

2007-09-21T23:59:59.000Z

37

Gas Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6TheoreticalFuelCell Energy IncFORTechnologyGammaGary2008)

38

Isotope Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpInc Place: EdenOverview OfIowa/Incentives < IowaOpen

39

Automatically generating information from a Z speci cation to support the Classi cation Tree  

E-Print Network [OSTI]

Automatically generating information from a Z speci#12;cation to support the Classi#12;cation Tree, Brunel University, Uxbridge, Middlesex, UB8 3PH, UK 2 DaimlerChrysler AG, Research Information. The Classi#12;cation Tree Method provides a exible basis for systematic testing. Traditionally

Singer, Jeremy

40

Method for encapsulating and isolating hazardous cations, medium for encapsulating and isolating hazardous cations  

DOE Patents [OSTI]

A method for encapsulating hazardous cations is provided comprising supplying a pretreated substrate containing the cations; contacting the substrate with an organo-silane compound to form a coating on the substrate; and allowing the coating to cure. A medium for containing hazardous cations is also provided, comprising a substrate having ion-exchange capacity and a silane-containing coating on the substrate.

Wasserman, Stephen R. (Darien, IL); Anderson, Kenneth B. (Lisle, IL); Song, Kang (Woodridge, IL); Yuchs, Steven E. (Naperville, IL); Marshall, Christopher L. (Naperville, IL)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Hybrid Automata: An Algorithmic Approach to the Speci cation and Veri cation of  

E-Print Network [OSTI]

Hybrid Automata: An Algorithmic Approach to the Speci cation and Veri cation of Hybrid Systems1 of hybrid automata as a model and speci cation language for hybrid systems. Hybrid automatacan be viewed erential equations. We show that many of the examples considered in the workshop can be de ned by hybrid

Henzinger, Thomas A.

42

Speci cation and Veri cation of a Steam-Boiler with Signal-Coq Micka l Kerb uf1  

E-Print Network [OSTI]

Speci cation and Veri cation of a Steam-Boiler with Signal-Coq Micka l Kerb uf1 , David Nowak2 assistant, Coq, for the speci cation and the veri cation of co-inductive properties of the well-known steam cation tools. Keywords: synchronous programming, theorem proving, the steam- boiler problem. 1

Boyer, Edmond

43

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed Acid Based Redox Flow Battery Electrolytes. Abstract: The Vanadium (V) cation structures in mixed acid based...

44

Are the Radical Centers in Peptide Radical Cations Mobile? The...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Radical Centers in Peptide Radical Cations Mobile? The Generation, Tautomerism, and Dissociation of Isomeric ? Are the Radical Centers in Peptide Radical Cations Mobile?...

45

Cationic Ruthenium Catalysts for Olefin Hydrovinylation  

E-Print Network [OSTI]

CATIONIC RUTHENIUM CATALYSTS FOR OLEFIN HYDROVINYLATION A Thesis by RICHARD P. SANCHEZ, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 2009 Major Subject: Chemistry CATIONIC RUTHENIUM CATALYSTS FOR OLEFIN HYDROVINYLATION A Thesis by RICHARD P. SANCHEZ, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Sanchez, Richard P., Jr

2010-01-14T23:59:59.000Z

46

Method for encapsulating and isolating hazardous cations, medium for encapsulating and isolating hazardous cations  

DOE Patents [OSTI]

A method for encapsulating hazardous cations is provided comprising supplying a pretreated substrate containing the cations; contacting the substrate with an organo-silane compound to form a coating on the substrate; and allowing the coating to cure. A medium for containing hazardous cations is also provided, comprising a substrate having ion-exchange capacity and a silane-containing coating on the substrate. 3 figs.

Wasserman, S.R.; Anderson, K.B.; Song, K.; Yuchs, S.E.; Marshall, C.L.

1998-04-28T23:59:59.000Z

47

1,2,3-triazolium ionic liquids  

DOE Patents [OSTI]

The present invention relates to compositions of matter that are ionic liquids, the compositions comprising substituted 1,2,3-triazolium cations combined with any anion. Compositions of the invention should be useful in the separation of gases and, perhaps, as catalysts for many reactions.

Luebke, David; Nulwala, Hunaid; Tang, Chau

2014-12-09T23:59:59.000Z

48

Cationic Hyperbranched Poly(amino ester): A Novel Class of DNA Condensing Molecule with Cationic  

E-Print Network [OSTI]

molecules.3 It is generally accepted that the high transfection efficiency of PEI or PAMAM comparedCationic Hyperbranched Poly(amino ester): A Novel Class of DNA Condensing Molecule with Cationic to utilize these highly branched molecules in a variety of applications involving combinatorial chemistry

Park, Jong-Sang

49

Cationically polymerizable monomers derived from renewable sources  

SciTech Connect (OSTI)

The objective of this project is to make use of products obtained from renewable plant sources as monomers for the direct production of polymers which can be used for a wide range of plastic applications. In this report is described progress in the synthesis and polymerization of cationically polymerizable monomers and oligomers derived from botanical oils, terpenes, natural rubber, and lignin. Nine different botanical oils were obtained from various sources, characterized and then epoxidized. Their photopolymerization was carried out using cationic photoinitiators and the mechanical properties of the resulting polymers characterized. Preliminary biodegradation studies are being conducted on the photopolymerized films from several of these oils. Limonene was cationically polymerized to give dimers and the dimers epoxidized to yield highly reactive monomers suitable for coatings, inks and adhesives. The direct phase transfer epoxidation of squalene and natural rubber was carried out. The modified rubbers undergo facile photocrosslinking in the presence of onium salts to give crosslinked elastomers. 12 refs., 3 figs., 10 tabs.

Crivello, J.V.

1991-10-01T23:59:59.000Z

50

Cationically polymerizable monomers derived from renewable sources  

SciTech Connect (OSTI)

The objectives of this project are to design and synthesize novel monomers which orginate from renewable biological sources and to carry out their rapid, efficient, pollution-free and energy efficient cationic polymerization to useful products under the influence of ultraviolet light or heat. A summary of the results of the past year's research on cationically polymerizable monomers derived from renewable sources is presented. Three major areas of investigation corresponding to the different classes of naturally occurring starting materials were investigated; epoxidized terpenes and natural rubber and vinyl ethers from alcohols and carbohydrates.

Crivello, J.V.

1992-10-01T23:59:59.000Z

51

Process and apparatus for the production of Bi-213 cations  

DOE Patents [OSTI]

A process for producing substantially impurity-free Bi-213 cations is disclosed. An aqueous acid feed solution containing Ac-225 cations is contacted with an ion exchange medium to bind the Ac-225 cations and form an Ac-225-laden ion exchange medium. The bound Ac-225 incubates on the ion exchange medium to form Bi-213 cations by radioactive decay. The Bi-213 cations are then recovered from the Ac-225-laden ion exchange medium to form a substantially impurity-free aqueous Bi-213 cation acid solution. An apparatus for carrying out this process is also disclosed. 7 figs.

Horwitz, E.P.; Hines, J.J.; Chiarizia, R.; Dietz, M.

1998-12-29T23:59:59.000Z

52

Distributed Controller Synthesis for Local Speci cations  

E-Print Network [OSTI]

| and a speci#12;cation, say, a temporal logic formula. The plant is viewed as an existing program which speci Institute of Technology, Atlanta, USA (On leave from Chennai Mathematical Institute, Chennai, India) thiagu as a temporal logic formula, whether there exists a program for the system such that no matter how

Parthasarathy, Madhusudan

53

E-Print Network 3.0 - alkaline earth cations Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the cation (alkaline, rare earth... to the cation size. Knowing that the size of rare earth elements and alkaline cations decreases in the following... of results on tungstate...

54

Functional and Structural Characterization of Cation/H+ Antiporters  

E-Print Network [OSTI]

are important elements in mediating the intracellular sequestration of these cations. CAXs (for CAtion eXchanger) are members of a multigene family and appear to predominately reside on vacuoles. Defining CAX regulation and substrate specificity have been aided...

Manohar, Murli

2012-07-16T23:59:59.000Z

55

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

56

Specific Cation Effects in Biological Systems: Thermodynamic and Spectroscopic Insights  

E-Print Network [OSTI]

. More polarizable cations, however, can solvate the hydrophobic moieties and somewhat counter the salting-out effect of the chloride anion. More charged and hydrated ions like lithium and divalent cations showed a weak interaction to the amide moiety...

Kherb, Jaibir

2012-02-14T23:59:59.000Z

57

The effect of various cropping systems upon organic matter, total nitrogen, cation exchange capacity, exchangeable cations, conductivity and reaction  

E-Print Network [OSTI]

&IBRARY A 4 N COLLEGE OF TEXAS THE EFFECT OF VARIOUS CROPPING SYSTEMS UPON ORGANIC MATTER, TOTAL NITROGEN, CATION EXCHANGE CAPACITY, EXCHANGEABLE CATIONS, CONDUCTIVITY AND REACTION. A Thesis By MOHAMMAD ABDUL MANNAN Submitted...

Mannan, Mohammad Abdul

1958-01-01T23:59:59.000Z

58

Alkaline earth cation extraction from acid solution  

DOE Patents [OSTI]

An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

Dietz, Mark (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

2003-01-01T23:59:59.000Z

59

active cation transport: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of hexadecyltrimethylammonium (HDTMA into surface water is a major cause of lake Eutrophication 2. Removal of surfactants from waste water Li, Zhaohui 7 Cationic Amino Acid...

60

Aprotic Heterocyclic Anion Triazolide Ionic Liquids - A New Class of Ionic Liquid Anion Accessed by the Huisgen Cycloaddition Reaction  

SciTech Connect (OSTI)

The triazole core is a highly versatile heterocyclic ring which can be accessed easily with the Cu(I)-catalyzed Huisgen cycloaddition reaction. Herein we present the preparation of ionic liquids that incorporate a 1,2,3-triazolide anion. These ionic liquids were prepared by a facile procedure utilizing a base-labile pivaloylmethyl group at the 1-position, which can act as precursors to 1H- 4-substituted 1,2,3-triazole. These triazoles were then subsequently converted into ionic liquids after deprotonation using an appropriate ionic liquid cation hydroxide. The densities and thermal decompositions of these ionic liquids were measured. These novel ionic liquids have potential applications in gas separations and in metal-free catalysis.

Thompson, Robert L.; Damodaran, Krishnan; Luebke, David; Nulwala, Hunaid

2013-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Diffusion and selective transport of alkali cations on cation-exchange membrane  

SciTech Connect (OSTI)

The diffusion coefficients and selective transport for alkali metal cations through a charged polysulfonated ICE-450 ion-exchange membrane were measured as a function of pH at 25{degrees}C. The permeability and diffusion coefficients were found to increase in the sequence Cs{sup +} {ge} K{sup +} {ge} Na{sup +} {ge} Li{sup +}. The relationship between the permeability and the diffusion coefficients, and the hydrated radii of cations in the membrane were shown. This sequence was also explained by considering the hydration of ions in the membrane. The selectivity transport of K-Na and K-Li binary systems at various pH gradients through the membrane were also investigated under various conditions. In the selective transport of metal ions, the selectivity depended on both the hydrated ionic size and the interaction between the fixed groups in the membrane and the metal ions.

Ersoez, M. [Selcuk Univ., Konya (Turkey)

1995-11-01T23:59:59.000Z

62

CSE647: Testing and Veri cation (Fall 2000) Scott Stoller  

E-Print Network [OSTI]

CSE647: Testing and Veri#12;cation (Fall 2000) Scott Stoller Exam For every problem, you must whether it is possible, based only on the given information about S, to conclude that the speci#12;ed set is persistent in the speci#12;ed state. Your answer must be yes or no, followed by a justi#12;cation. Use

Stoller, Scott

63

Charge Density of Divalent Metal Cations Determines RNA Stability  

E-Print Network [OSTI]

determined by a combination of counterion charge and the packing efficiency of condensed cations that depends RNAs that have regions of high negative potential interact even more strongly with counterions than of the phosphate charge arises from nonspecific condensation of counterions.4,10 The ionic radius of a metal cation

Thirumalai, Devarajan

64

Functional Speci cation of Real-Time and Hybrid Systems ?  

E-Print Network [OSTI]

of embedded real-time systems in a physical environment. Recently, a number of description and spec- i cationSys" and by BMW (Bay- erische Motoren Werke AG). #12;slight modi cations must be carried through, so, or sent to, the environment. Therefore, every channel re ects an input or output communication history

65

Integrated Chemical Geothermometry System for Geothermal Exploration...  

Broader source: Energy.gov (indexed) [DOE]

geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids. tracersspycherintegratedchemical.pdf More Documents & Publications Integrated...

66

Integrated Chemical Geothermometry System for Geothermal Exploration  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. Develop practical and reliable system to predict geothermal reservoir temperatures from integrated chemical analyses of spring and well fluids.

67

Geothermometry (Klein, 2007) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJump

68

Geothermal: Sponsored by OSTI -- Improved Geothermometry Through  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite--FORRemarks IGPPS Days Program

69

Category:Gas Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascade SierraStatusGeothermalpower.jpgGas Flux

70

Category:Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to: navigation,Areas Jump to:

71

Category:Isotope Geothermometry | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to: navigation,Areas

72

Classi cation of Carbide Distributions using Scale-Space Methods Classi cation of Carbide Distributions using Scale  

E-Print Network [OSTI]

Classi cation of Carbide Distributions using Scale-Space Methods #12;Classi cation of Carbide-structure of the steel, which in turn in uences the mechanical properties. Speci - cally, the distribution of carbide is essential, since cracks propagate within the carbide agglomerations. In current quality control

Lindeberg, Tony

73

Acetonitrile Drastically Boosts Conductivity of Ionic Liquids  

E-Print Network [OSTI]

We apply a new methodology in the force field generation (PCCP 2011, 13, 7910) to study the binary mixtures of five imidazolium-based room-temperature ionic liquids (RTILs) with acetonitrile (ACN). The investigated RTILs are composed of tetrafluoroborate (BF4) anion and dialkylimidazolium cations, where one of the alkyl groups is methyl for all RTILs, and the other group is different for each RTILs, being ethyl (EMIM), butyl (BMIM), hexyl (HMIM), octyl (OMIM), and decyl (DMIM). Specific densities, radial distribution functions, ionic cluster distributions, heats of vaporization, diffusion constants, shear viscosities, ionic conductivities, and their correlations are discussed. Upon addition of ACN, the ionic conductivity of RTILs is found to increase by more than 50 times, that significantly exceeds an impact of most known solvents. Remarkably, the sharpest conductivity growth is found for the long-tailed imidazolium-based cations. This new fact motivates to revisit an application of these binary systems as a...

Chaban, Vitaly V; Kalugin, Oleg N; Prezhdo, Oleg V

2012-01-01T23:59:59.000Z

74

Characterization of Selective Binding of Alkali Cations with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

comprises a main chamber, detector, liquid microjet, skimmer, liquid nitrogen traps, turbo pumps, and a differential pump section (not shown here). A density functional theory...

75

Effects of Cesium Cations in Lithium Deposition via Self-Healing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cesium Cations in Lithium Deposition via Self-Healing Electrostatic Shield Mechanism. Effects of Cesium Cations in Lithium Deposition via Self-Healing Electrostatic Shield...

76

Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrolytes. Structure and Stability of Hexa-Aqua V(III) Cations in Vanadium Redox Flow Battery Electrolytes. Abstract: The Vanadium (III) cation structure in mixed acid based...

77

Cation Transport in Polymer Electrolytes: A Microscopic Approach  

E-Print Network [OSTI]

A microscopic theory for cation diffusion in polymer electrolytes is presented. Based on a thorough analysis of molecular dynamics simulations on PEO with LiBF$_4$ the mechanisms of cation dynamics are characterised. Cation jumps between polymer chains can be identified as renewal processes. This allows us to obtain an explicit expression for the lithium ion diffusion constant D_{Li} by invoking polymer specific properties such as the Rouse dynamics. This extends previous phenomenological and numerical approaches. In particular, the chain length dependence of D_{Li} can be predicted and compared with experimental data. This dependence can be fully understood without referring to entanglement effects.

A. Maitra; A. Heuer

2007-05-11T23:59:59.000Z

78

Durable electrooptic devices comprising ionic liquids  

DOE Patents [OSTI]

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF3SO3-), bis(trifluoromethylsulfonyl)imide ((CF3SO2)2N-), bis(perfluoroethylsulfonyl)imide ((CF3CF2SO2)2N-) and tris(trifluoromethylsulfonyl)methide ((CF3SO2)3C-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

Agrawal, Anoop (Tucson, AZ); Cronin, John P. (Tucson, AZ); Tonazzi, Juan C. L. (Tucson, AZ); Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM); Burrell, Anthony K. (Los Alamos, NM)

2005-11-01T23:59:59.000Z

79

Liquid electrode  

DOE Patents [OSTI]

A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

Ekechukwu, A.A.

1994-07-05T23:59:59.000Z

80

Liquid foams of graphene  

E-Print Network [OSTI]

Liquid foams are dispersions of bubbles in a liquid. Bubbles are stabilized by foaming agents that position at the interface between the gas and the liquid. Most foaming agents, such as the commonly used sodium dodecylsulfate, ...

Alcazar Jorba, Daniel

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

In situ remediation process using divalent metal cations  

DOE Patents [OSTI]

An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

2004-12-14T23:59:59.000Z

82

Binary inorganic salt mixtures as high conductivity liquid electrolytes for .100 uC fuel cells{  

E-Print Network [OSTI]

Binary inorganic salt mixtures as high conductivity liquid electrolytes for .100 uC fuel cells cations (e.g. ammonium) as electrolytes in fuel cells operating in the temperature range 100­200 uC, where cell operating with optimized electrodes in the same temperature range, while open circuit voltages

Angell, C. Austen

83

Comparison of Cation Adsorption by Isostructural Rutile and Cassiterite  

SciTech Connect (OSTI)

Macroscopic net proton charging curves for powdered rutile and cassiterite specimens with the (110) Crystal face predominant, as a function of pH in RbCl and NaCl solutions, trace SrCl2 in NaCl, and trace ZnCl2 in NaCl and Na Triflate solutions, are compared to corresponding molecular-level information obtained from static DFT optimizations and classical MD simulations, as well as synchrotron X-ray methods. The similarities and differences in the macroscopic charging behavior of rutile and cassiterite largely reflect the cation binding modes observed at the molecular level. Cation adsorption is primarily inner-sphere on both isostructural (110) surfaces, despite predictions that outer-sphere binding should predominate on low bulk dielectric constant oxides such as cassiterite ( bulk 11). Inner-sphere adsorption is also significant for Rb and Na on neutral surfaces, whereas Cl- binding is predominately outer-sphere. As negative surface charge increases, relatively more Rb , Na , and especially Sr2 are bound in highly desolvated tetradentate fashion on the rutile (110) surface, largely accounting for enhanced negative charge development relative to cassiterite. Charging curves in the presence of Zn2 are very steep but similar for both oxides, reflective of Zn2 hydrolysis (and accompanying proton release) during the adsorption process, and the similar binding modes for ZnOH on both surfaces. These results suggest that differences in cation adsorption between high and low bulk dielectric constant oxides are more subtly related to the relative degree of cation desolvation accompanying inner-sphere binding (i.e., more tetradentate binding on rutile), rather than distinct inner- and outer-sphere adsorption modes. Cation desolvation may be favored at the rutile (110) surface in part because inner-sphere water molecules are bound further from and less tightly than on the cassiterite (110) surface. Hence, their removal upon inner-sphere cation binding is relatively more favorable.

Machesky, Michael L. [Illinois State Water Survey, Champaign, IL; Wesolowski, David J [ORNL; Rosenqvist, Jorgen K [ORNL; Predota, M. [University of South Bohemia, Czech Republic; Vlcek, Lukas [ORNL; Ridley, Moira K [ORNL; Kohli, V [Oak Ridge National Laboratory (ORNL); Zhang, Zhan [Argonne National Laboratory (ANL); Fenter, Paul [Argonne National Laboratory (ANL); Cummings, Peter T [ORNL; Lvov, Serguei N. [Pennsylvania State University; Fedkin, Mark V [ORNL; Rodriguez-Santiago, V [Oak Ridge National Laboratory (ORNL); Kubicki, James D. [Pennsylvania State University; Bandura, Andrei V. [St. Petersburg State University, St. Petersburg, Russia

2011-01-01T23:59:59.000Z

84

Cationically polymerizable monomers derived from renewable sources. Annual performance report  

SciTech Connect (OSTI)

The objectives of this project are to design and synthesize novel monomers which orginate from renewable biological sources and to carry out their rapid, efficient, pollution-free and energy efficient cationic polymerization to useful products under the influence of ultraviolet light or heat. A summary of the results of the past year`s research on cationically polymerizable monomers derived from renewable sources is presented. Three major areas of investigation corresponding to the different classes of naturally occurring starting materials were investigated; epoxidized terpenes and natural rubber and vinyl ethers from alcohols and carbohydrates.

Crivello, J.V.

1992-10-01T23:59:59.000Z

85

Safetygram #9- Liquid Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

86

Towards an Algebraic Speci cation of the Java Virtual Machine  

E-Print Network [OSTI]

Towards an Algebraic Speci cation of the Java Virtual Machine K Stephenson Department of Computer of the architecture of an abstract and simpli ed version of the Java Virtual Machine JVM. This concentration on the implementation-independent features of the machine allows us to build a clean and easily comprehensible model

Grant, P. W.

87

SHORT COMMUNICATION An In Situ Silver Cationization Method  

E-Print Network [OSTI]

desorption of perflu- orinated polyethers (PFPEs), and used a second laser to ablate a plume of metal ions the forma- tion of metal ion adducts by mixing metal salts into the matrix they used to perform SIMS [5 from the sample substrate to form metal cation adducts [7]. Kahr and Wilkins used a layer of silver

de Vries, Mattanjah S.

88

Steam boiler control speci cation problem: A TLA solution  

E-Print Network [OSTI]

Steam boiler control speci cation problem: A TLA solution Frank Le ke and Stephan Merz Institut fur of the state of the steam boiler, detect failures, and model message transmission. We give a more detailed between the physi- cal state of the steam boiler and the model maintained by the controller and discuss

89

Soft ionization of thermally evaporated hypergolic ionic liquid aerosols  

SciTech Connect (OSTI)

Isolated ion pairs of a conventional ionic liquid, 1-Ethyl-3-Methyl-Imidazolium Bis(trifluoromethylsulfonyl)imide ([Emim+][Tf2N?]), and a reactive hypergolic ionic liquid, 1- Butyl-3-Methyl-Imidazolium Dicyanamide ([Bmim+][Dca?]), are generated by vaporizing ionic liquid submicron aerosol particles for the first time; the vaporized species are investigated by dissociative ionization with tunable vacuum ultraviolet (VUV) light, exhibiting clear intact cations, Emim+ and Bmim+, presumably originating from intact ion pairs. Mass spectra of ion pair vapor from an effusive source of the hypergolic ionic liquid show substantial reactive decomposition due to the internal energy of the molecules emanating from the source. Photoionization efficiency curves in the near threshold ionization region of isolated ion pairs of [Emim+][Tf2N?] ionic liquid vapor are compared for an aerosol source and an effusive source, revealing changes in the appearance energy due to the amount of internal energy in the ion pairs. The aerosol source has a shift to higher threshold energy (~;;0.3 eV), attributed to reduced internal energy of the isolated ion pairs. The method of ionic liquid submicron aerosol particle vaporization, for reactive ionic liquids such as hypergolic species, is a convenient, thermally ?cooler? source of isolated intact ion pairs in the gas phase compared to effusive sources.

University of California; ERC, Incorporated, Edwards Air Force Base; Air Force Research Laboratory, Edwards Air Force Base; National Synchrotron Radiation Research Center (NSRRC); Koh, Christine J.; Liu, Chen-Lin; Harmon, Christopher W.; Strasser, Daniel; Golan, Amir; Kostko, Oleg; Chambreau, Steven D.; L.Vaghjiani, Ghanshyam; Leone, Stephen R.

2012-03-16T23:59:59.000Z

90

Compilation of quasi-destructive uni cation of type feature structures  

E-Print Network [OSTI]

on the LIGHT system concerns its extension so to achieve compilation of destructive uni#12;cation of FSs #18;a two stages. First, during uni#12;cation, modi#12;ed nodes in the two (rooted) FSs are marked so

Bennett, Brandon

91

Factors Affecting the Fragmentation of Peptide Ions: Metal Cationization and Fragmentation Timescale  

E-Print Network [OSTI]

cation and in assessing differences in the fragmentation pattern as a result of this binding site. An interesting observation from these studies reveals abundant x-type fragment ions occurring from the fragmentation of alkali-metal cationized peptides...

Kmiec, Kevin

2012-10-19T23:59:59.000Z

92

Organo-Lewis acid as cocatalyst for cationic homogeneous Ziegler-Natta olefin polymerizations  

DOE Patents [OSTI]

A cationic metallocene complex with trisperfluorobiphenyl borate is described for use as a polymerization catalyst. 7 figs.

Marks, T.J.; Chen, Y.X.

1999-01-05T23:59:59.000Z

93

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, Albert P. (Vernon, CT)

1986-01-01T23:59:59.000Z

94

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, A.P.

1984-02-21T23:59:59.000Z

95

An Algebraic Speci cation of the Steam-Boiler Control System  

E-Print Network [OSTI]

An Algebraic Speci#12;cation of the Steam-Boiler Control System Michel Bidoit 1 , Claude Chevenier describe how to derive an algebraic speci#12;cation of the Steam-Boiler Control System starting from to specify the detection of the steam-boiler fail- ures. Finally we discuss validation and veri#12;cation

Bidoit, Michel

96

PHYSICAL REVIEW B 88, 174102 (2013) Positron lifetime measurements of hydrogen passivation of cation vacancies  

E-Print Network [OSTI]

of cation vacancies in yttrium aluminum oxide garnets F. A. Selim,1,* C. R. Varney,1 M. C. Tarun,1 M. C; published 4 November 2013) A charge compensation mechanism is proposed for cation vacancy defects in complex trapping was detected in samples grown in H2. This is attributed to decoration of cation vacancies

McCluskey, Matthew

97

Liquid Hydrogen Absorber for MICE  

E-Print Network [OSTI]

REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

Ishimoto, S.

2010-01-01T23:59:59.000Z

98

Guidance Document Cryogenic Liquids  

E-Print Network [OSTI]

with air. Liquid carbon monoxide is extremely toxic and extremely flammable. #12;Cryogenic liquids connecting cylinder to lower pressure piping or systems. 6. Use a check valve or trap in the discharge line

99

Equation for liquid density  

SciTech Connect (OSTI)

Saturated liquid densities for organic chemicals are given as functions of temperature using a modified Rackett equation.

Yaws, C.L.; Yang, H.C.; Hopper, J.R.; Cawley, W.A. (Lamar Univ., Beaumont, TX (US))

1991-01-01T23:59:59.000Z

100

Liquid detection circuit  

DOE Patents [OSTI]

Herein is a circuit which is capable of detecting the presence of liquids, especially cryogenic liquids, and whose sensor will not overheat in a vacuum. The circuit parameters, however, can be adjusted to work with any liquid over a wide range of temperatures.

Regan, Thomas O. (North Aurora, IL)

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Durable Electrooptic Devices Comprising Ionic Liquids  

DOE Patents [OSTI]

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes. Some of the electrolyte solutions color to red when devices employing the solutions are powered, leading to red or neutral electrooptic devices.

Burrell, Anthony K. (Los Alamos, NM); Agrawal, Anoop (Tucson, AZ); Cronin, John P. (Tucson, AZ); Tonazzi, Juan C. L. (Tucson, AZ); Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM)

2008-11-11T23:59:59.000Z

102

Durable electrooptic devices comprising ionic liquids  

DOE Patents [OSTI]

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM); Burrell, Anthony K. (Los Alamos, NM)

2006-10-10T23:59:59.000Z

103

Durable electrooptic devices comprising ionic liquids  

DOE Patents [OSTI]

Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes. Some of the electrolyte solutions color to red when devices employing the solutions are powered, leading to red or neutral electrooptic devices.

Burrell, Anthony K. (Los Alamos, NM); Agrawal, Anoop (Tucson, AZ); Cronin; John P. (Tucson, AZ); Tonazzi, Juan C. L. (Tucson, AZ); Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM)

2009-12-15T23:59:59.000Z

104

Free ion yields in liquids: Molecular structure and track effects  

SciTech Connect (OSTI)

The signal generated in a liquid-filled ionization chamber is proporational to the ions that escape, the free ion yield or, G{sub fi}. Recent results show how molecular structure, rate of energy loss (dE/dx) and pressure affect G{sub fi} and give further insight into the ionization process in liquids. As a consequence of the passage of high energy charged particles through a liquid, molecules are ionized and excited. The electrons have kinetic energy initially which allow them to travel some distance away from their geminate cations. The electrons may lose energy to vibrational modes but a significant fraction of the separation occurs while the electrons have subvibrational (near thermal) energy. When the electron finally thermalizes it is within the coulombic field of its parent cation and the two ions constitute a geminate pair. The free ion yield is determined by the fraction of geminate pairs which separate to form free ions as against those that recombine to form excited states.

Holroyd, R.

1992-05-01T23:59:59.000Z

105

Free ion yields in liquids: Molecular structure and track effects  

SciTech Connect (OSTI)

The signal generated in a liquid-filled ionization chamber is proporational to the ions that escape, the free ion yield or, G{sub fi}. Recent results show how molecular structure, rate of energy loss (dE/dx) and pressure affect G{sub fi} and give further insight into the ionization process in liquids. As a consequence of the passage of high energy charged particles through a liquid, molecules are ionized and excited. The electrons have kinetic energy initially which allow them to travel some distance away from their geminate cations. The electrons may lose energy to vibrational modes but a significant fraction of the separation occurs while the electrons have subvibrational (near thermal) energy. When the electron finally thermalizes it is within the coulombic field of its parent cation and the two ions constitute a geminate pair. The free ion yield is determined by the fraction of geminate pairs which separate to form free ions as against those that recombine to form excited states.

Holroyd, R.

1992-01-01T23:59:59.000Z

106

Liquid Wall Chambers  

SciTech Connect (OSTI)

The key feature of liquid wall chambers is the use of a renewable liquid layer to protect chamber structures from target emissions. Two primary options have been proposed and studied: wetted wall chambers and thick liquid wall (TLW) chambers. With wetted wall designs, a thin layer of liquid shields the structural first wall from short ranged target emissions (x-rays, ions and debris) but not neutrons. Various schemes have been proposed to establish and renew the liquid layer between shots including flow-guiding porous fabrics (e.g., Osiris, HIBALL), porous rigid structures (Prometheus) and thin film flows (KOYO). The thin liquid layer can be the tritium breeding material (e.g., flibe, PbLi, or Li) or another liquid metal such as Pb. TLWs use liquid jets injected by stationary or oscillating nozzles to form a neutronically thick layer (typically with an effective thickness of {approx}50 cm) of liquid between the target and first structural wall. In addition to absorbing short ranged emissions, the thick liquid layer degrades the neutron flux and energy reaching the first wall, typically by {approx}10 x x, so that steel walls can survive for the life of the plant ({approx}30-60 yrs). The thick liquid serves as the primary coolant and tritium breeding material (most recent designs use flibe, but the earliest concepts used Li). In essence, the TLW places the fusion blanket inside the first wall instead of behind the first wall.

Meier, W R

2011-02-24T23:59:59.000Z

107

Liquid Metal Transformers  

E-Print Network [OSTI]

The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

Sheng, Lei; Liu, Jing

2014-01-01T23:59:59.000Z

108

Hydrogen Fluoride Capture by Imidazolium Acetate Ionic Liquid  

E-Print Network [OSTI]

Extraction of hydrofluoric acid (HF) from oils is a drastically important problem in petroleum industry, since HF causes quick corrosion of pipe lines and brings severe health problems to humanity. Some ionic liquids (ILs) constitute promising scavenger agents thanks to strong binding to polar compounds and tunability. PM7-MD simulations and hybrid density functional theory are employed here to consider HF capture ability of ILs. Discussing the effects and impacts of the cation and the anion separately and together, I will evaluate performance of imidazolium acetate and outline systematic search guidelines for efficient adsorption and extraction of HF.

Chaban, Vitaly

2015-01-01T23:59:59.000Z

109

Ultrasonic liquid level detector  

DOE Patents [OSTI]

An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

Kotz, Dennis M. (North Augusta, SC); Hinz, William R. (Augusta, GA)

2010-09-28T23:59:59.000Z

110

Liquid Metal Transformers  

E-Print Network [OSTI]

The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

Lei Sheng; Jie Zhang; Jing Liu

2014-01-30T23:59:59.000Z

111

Liquid Crystal Optofluidics  

SciTech Connect (OSTI)

By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

2012-10-11T23:59:59.000Z

112

(Ionization in liquids)  

SciTech Connect (OSTI)

This document describes charge transport following ionization of model liquids and how this process may be important in carcinogenesis. 15 refs., 2 figs., 4 tabs. (MHB)

Not Available

1991-01-01T23:59:59.000Z

113

E-Print Network 3.0 - activated cation currents Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Generating Test Data from SOFL Speci cations A. Je erson O utt ISSE ... Source: Offutt, Jeff - Department of Computer Science, George Washington University Collection: Computer...

114

E-Print Network 3.0 - abts radical cation Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

abts radical cation Page: << < 1 2 3 4 5 > >> 1 2-Aminobenzothiazole degradation by free and Ca-alginate immobilized cells of Rhodococcus rhodochrous Summary: , Chisinau,...

115

Ionic liquids for separation of olefin-paraffin mixtures  

DOE Patents [OSTI]

The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

2013-09-17T23:59:59.000Z

116

Ionic liquids for separation of olefin-paraffin mixtures  

DOE Patents [OSTI]

The invention is directed to an ionic liquid comprising (i) a cationic portion containing a complex of a silver (I) ion and one or more neutral ligands selected from organoamides, organoamines, olefins, and organonitriles, and (ii) an anionic portion having the chemical formula ##STR00001## wherein m and n are independently 0 or an integer of 1 or above, and p is 0 or 1, provided that when p is 0, the group --N--SO.sub.2--(CF.sub.2).sub.nCF.sub.3 subtended by p is replaced with an oxide atom connected to the shown sulfur atom. The invention is also directed to a method for separating an olefin from an olefin-paraffin mixture by passing the mixture through a layer of the ionic liquid described above.

Dai, Sheng; Luo, Huimin; Huang, Jing-Fang

2014-07-15T23:59:59.000Z

117

Absorption of sound in liquids and liquid mixtures  

E-Print Network [OSTI]

ABSORPTION OF SOUND IN LIQUIDS AND LIQUID MIXTURES A Thesis Raiq S. causa Approved as to style and content by: (Chairman of Committee) January 1955 L1BRARY A 4 M COLLEOE OF IEXAS ADSORPTION OF SOfP@ LIQUIDS AND LIQUID NIXTURES A Thesis... Introduction to the Problem Experimental Methods and Procedures Results Discussion of Results Acknowledgements Bib 1 io graphy 22 4I 42 Introduction to the Problem The study of sound absorption in liquids and liquid mixtures is of considerable...

Musa, Raiq S

2012-06-07T23:59:59.000Z

118

Carbon monoxide absorbing liquid  

SciTech Connect (OSTI)

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

119

INEEL Liquid Effluent Inventory  

SciTech Connect (OSTI)

The INEEL contractors and their associated facilities are required to identify all liquid effluent discharges that may impact the environment at the INEEL. This liquid effluent information is then placed in the Liquid Effluent Inventory (LEI) database, which is maintained by the INEEL prime contractor. The purpose of the LEI is to identify and maintain a current listing of all liquid effluent discharge points and to identify which discharges are subject to federal, state, or local permitting or reporting requirements and DOE order requirements. Initial characterization, which represents most of the INEEL liquid effluents, has been performed, and additional characterization may be required in the future to meet regulations. LEI information is made available to persons responsible for or concerned with INEEL compliance with liquid effluent permitting or reporting requirements, such as the National Pollutant Discharge Elimination System, Wastewater Land Application, Storm Water Pollution Prevention, Spill Prevention Control and Countermeasures, and Industrial Wastewater Pretreatment. The State of Idaho Environmental Oversight and Monitoring Program also needs the information for tracking liquid effluent discharges at the INEEL. The information provides a baseline from which future liquid discharges can be identified, characterized, and regulated, if appropriate. The review covered new and removed buildings/structures, buildings/structures which most likely had new, relocated, or removed LEI discharge points, and at least 10% of the remaining discharge points.

Major, C.A.

1997-06-01T23:59:59.000Z

120

Liquid heat capacity lasers  

DOE Patents [OSTI]

The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

2007-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Combined Utilization of Cation Exchanger and Neutral Receptor to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts  

SciTech Connect (OSTI)

In this report, novel approaches to the selective liquid-liquid extraction separation of sodium hydroxide and sodium nitrate from high-level alkaline tank waste will be discussed. Sodium hydroxide can be successfully separated from alkaline tank-waste supernatants by weakly acidic lipophilic hydroxy compounds via a cation-exchange mechanism referred to as pseudo hydroxide extraction. In a multi-cycle process, as sodium hydroxide in the aqueous phase becomes depleted, it is helpful to have a neutral sodium receptor in the extraction system to exploit the high nitrate concentration in the waste solution to promote sodium removal by an ion-pair extraction process. Simultaneous utilization of an ionizable organic hydroxy compound and a neutral extractant (crown ether) in an organic phase results in the synergistic enhancement of ion exchange and improved separation selectivity due to the receptor's strong and selective sodium binding. Moreover, combination of the hydroxy compound and the crown ether provides for mutually increased solubility, even in a non-polar organic solvent. Accordingly, application of Isopar{reg_sign} L, a kerosene-like alkane solvent, becomes feasible. This investigation involves examination of such dual-mechanism extraction phases for sodium extraction from simulated and actual salt cake waste solutions. Sodium salts can be regenerated upon the contact of the loaded extraction phases with water. Finally, conditions of potential extraction/strip cycling will be discussed.

Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.

2004-03-29T23:59:59.000Z

122

Ultrafast Extreme Ultraviolet Induced Isomerization of Acetylene Cations  

SciTech Connect (OSTI)

Ultrafast isomerization of acetylene cations ([HC = CH]{sup +}) in the low-lying excited A{sup 2}{Sigma}{sub g}{sup +} state, populated by the absorption of extreme ultraviolet (XUV) photons (38 eV), has been observed at the Free Electron Laser in Hamburg, (FLASH). Recording coincident fragments C{sup +} + CH{sub 2}{sup +} as a function of time between XUV-pump and -probe pulses, generated by a split-mirror device, we find an isomerization time of 52 {+-} 15 fs in a kinetic energy release (KER) window of 5.8 < KER < 8 eV, providing clear evidence for the existence of a fast, nonradiative decay channel.

Jiang, Y.; Rudenko, Artem; Herrwerth, O.; Foucar, L.; Kurka, M.; Kuhnel, K.; Lezius, M.; Kling, Matthias; van Tilborg, Jeroen; Belkacem, Ali; Ueda, K.; Dusterer, S.; Treusch, R.; Schroter, Claus-Dieter; Moshammer, Robbert; Ullrich, Joachim

2011-06-17T23:59:59.000Z

123

Lithium-cation conductivity and crystal structure of lithium diphosphate  

SciTech Connect (OSTI)

The electrical conductivity of lithium diphosphate Li{sub 4}P{sub 2}O{sub 7} has been measured and jump-like increasing of ionic conductivity at 913 K has been found. The crystal structure of Li{sub 4}P{sub 2}O{sub 7} has been refined using high temperature neutron diffraction at 300–1050 K. At 913 K low temperature triclinic form of Li{sub 4}P{sub 2}O{sub 7} transforms into high temperature monoclinic one, space group P2{sub 1}/n, a=8.8261(4) Å, b=5.2028(4) Å, c=13.3119(2) Å, ?=104.372(6)°. The migration maps of Li{sup +} cations based on experimental data implemented into program package TOPOS have been explored. It was found that lithium cations in both low- and high temperature forms of Li{sub 4}P{sub 2}O{sub 7} migrate in three dimensions. Cross sections of the migrations channels extend as the temperature rises, but at the phase transition point have a sharp growth showing a strong “crystal structure – ion conductivity” correlation. -- Graphical abstract: Crystal structure of Li{sub 4}P{sub 2}O{sub 7} at 950 K. Red balls represent oxygen atoms; black lines show Li{sup +} ion migration channels in the layers perpendicular to [001] direction. Highlights: • Structure of Li{sub 4}P{sub 2}O{sub 7} has been refined using high temperature neutron diffraction. • At 913 K triclinic form of Li{sub 4}P{sub 2}O{sub 7} transforms into high temperature monoclinic one. • The migration maps of Li{sup +} implemented into program package TOPOS have been explored. • Cross sections of the migrations channels at the phase transition have a sharp growth.

Voronin, V.I., E-mail: voronin@imp.uran.ru [Institute of Metal Physics Urals Branch RAS, S.Kovalevskoy Street 18, 620041 Ekaterinburg (Russian Federation); Sherstobitova, E.A. [Institute of Metal Physics Urals Branch RAS, S.Kovalevskoy Street 18, 620041 Ekaterinburg (Russian Federation); Blatov, V.A., E-mail: blatov@samsu.ru [Samara Center for Theoretical Materials Science (SCTMS), Samara State University, Ac.Pavlov Street 1, 443011 Samara (Russian Federation); Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah 21589 (Saudi Arabia); Shekhtman, G.Sh., E-mail: shekhtman@ihte.uran.ru [Institute of High Temperature Electrochemistry Urals Branch RAS, Akademicheskaya 20, 620990 Ekaterinburg (Russian Federation)

2014-03-15T23:59:59.000Z

124

Air Liquide - Biogas & Fuel Cells  

Broader source: Energy.gov (indexed) [DOE]

Liquide - Biogas & Fuel Cells Hydrogen Energy Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry,...

125

Liquid sampling system  

DOE Patents [OSTI]

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

Larson, L.L.

1984-09-17T23:59:59.000Z

126

Re ning Abstract Machine Speci cations of the Steam Boiler Control to Well Documented  

E-Print Network [OSTI]

Re ning Abstract Machine Speci cations of the Steam Boiler Control to Well Documented Executable the steam boiler control speci cation problem to il- lustrate how the evolving algebra approach to the speci, in June 1995, to control the Karlsruhe steam boiler simulator satisfactorily. The abstract machines

Börger, Egon

127

Composing Speci cations using Communication Helen Treharne, Steve Schneider, and Marchia Bramble  

E-Print Network [OSTI]

CSPto enable controlled interaction between B machines. This illustrates how B machines are essential abstract speci cation described in CSP. This allows safety and liveness properties to be established for combinations of communicating B machines. Keywords: B-Method, CSP, Composing Speci cations, Combining

Doran, Simon J.

128

Advanced inverse techniques for the design of directional solidi cation processes  

E-Print Network [OSTI]

Advanced inverse techniques for the design of directional solidi cation processes Nicholas Zabaras methodologies for thermal process design can be developed using inverse problem theory. Such techniques the problem of designing the mold cooling/heating conditions such that stable solidi cation growth is obtained

Zabaras, Nicholas J.

129

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1992-01-01T23:59:59.000Z

130

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

131

Liquidity facilities and signaling  

E-Print Network [OSTI]

This dissertation studies the role of signaling concerns in discouraging access to liquidity facilities like the IMF contingent credit lines (CCL) and the Discount Window (DW). In Chapter 1, I analyze the introduction of ...

Arregui, Nicolás

2010-01-01T23:59:59.000Z

132

Logic Based Approaches to Work ow Modeling and Veri cation 1 Saikat Mukherjee, Hasan Davulcu, Michael Kifer, Pinar Senkul,  

E-Print Network [OSTI]

Contents Logic Based Approaches to Work ow Modeling and Veri#12;cation 1 Saikat Mukherjee, Hasan : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 37 #12; #12; Logic-Based Approaches to Work ow Modeling and Veri#12;cation Saikat Mukherjee, 1 Hasan

Yang, Guizhen

133

Liquid crystalline composites containing phyllosilicates  

DOE Patents [OSTI]

The present invention provides phyllosilicate-polymer compositions which are useful as liquid crystalline composites. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while at the same time be transparent. Because of the ordering of the particles liquid crystalline composite, liquid crystalline composites are particularly useful as barriers to gas transport.

Chaiko, David J.

2004-07-13T23:59:59.000Z

134

Pinning lattice: Effect of rhenium doping on the microstructural evolution from Tl-2212 to Hg-1212 films during cation exchange  

E-Print Network [OSTI]

In a cation exchange process developed recently by some of us, epitaxial HgBa2CaCu2O6 films can be obtained by diffusing volatile Tl cations out of, and simultaneously diffusing Hg cations into, the crystalline lattice of ...

Wu, Judy; Zhao, H.

2004-08-15T23:59:59.000Z

135

Cation disorder in high dose neutron irradiated spinel  

SciTech Connect (OSTI)

The crystal structures of MgAl{sub 2}O{sub 4} spinel single crystals irradiated to high neutron fluences (>5{center_dot}10{sup 26} n/m{sup 2} (E{sub n}>0.1 MeV)), were examined by neutron diffraction. Crystal structure refinement of the highest dose sample indicated that the average scattering strength of the tetrahedral crystal sites decreased by {approximately}20% while increasing by {approximately}8% on octahedral sites. Since the neutron scattering length for Mg is considerably larger than for Al, this result is consistent with site exchange between Mg{sup 2+} ions on tetrahedral sites and Al{sup 3+} ions on octahedral sites. Least squares refinements also indicated that in all irradiated samples, at least 35% of Mg{sup 2+} and Al{sup 3+} ions in the crystal experienced disordering replacements. This retained dpa on the cation sublattices is the largest retained damage ever measured in an irradiated spinel material.

Sickafus, K.E.; Larson, A.C.; Yu, N.; Nastasi, M. [Los Alamos National Lab., NM (United States); Hollenberg, G.W.; Garner, F.A. [Pacific Northwest Lab., Richland, WA (United States); Bradt, R.C. [Univ. of Nevada, Reno, NV (United States)

1994-06-01T23:59:59.000Z

136

Cation disorder in high-dose, neutron-irradiated spinel  

SciTech Connect (OSTI)

The objective of this effort is to determine whether MgAl{sub 2}O{sub 4} spinel is a suitable ceramic for fusion applications. Here, the crystal structures of MgAl{sub 2}O{sub 4} spinel single crystals irradiated to high neutron fluences [>5{center_dot}10{sup 26} n/m{sup 2} (E{sub n} > 0.1 MeV)] were examined by neutron diffraction. Crystal structure refinement of the highest dose sample indicated that the average scattering strength of the tetrahedral crystal sites decreased by {approximately} 20% while increasing by {approximately} 8% on octahedral sites. Since the neutron scattering length for Mg is considerably larger than for Al, this results is consistent with site exchange between Mg{sup 2+} ions on tetrahedral sites and Al{sup 3+} ions on octahedral sites. Least-squares refinements also indicated that, in all irradiated samples, at least 35% of Mg{sup 2+} and Al{sup 3+} ions in the crystal experienced disordering replacements. This retained dpa on the cation sublattices is the largest retained damage ever measured in an irradiated spinel material.

Sickafus, K.E.; Larson, A.C.; Yu, N.; Nastasi, M. [Los Alamos National Lab., NM (United States); Hollenberg, G.W.; Garner, F.A. [Pacific Northwest Lab., Richland, WA (United States); Bradt, R.C. [Univ. of Nevada, Reno, NV (United States)

1994-08-01T23:59:59.000Z

137

Geothermometry At Long Valley Caldera Geothermal Area (Mariner...  

Open Energy Info (EERE)

L. Sorey, Robert H. Mariner, Alfred H. Truesdell (1979) Chemical and Isotopic Prediction of Aquifer Temperatures in the Geothermal System at Long Valley, California Michael...

138

Geochemistry And Geothermometry Of Spring Water From The Blackfoot...  

Open Energy Info (EERE)

for eight springs along the Corral Creek drainage. The springs along Corral Creek have Na-K-Ca temperatures that average 354C, a direct result of high potassium concentrations in...

139

Geothermometry At Long Valley Caldera Geothermal Area (McKenzie...  

Open Energy Info (EERE)

1971) prior to analysis by mass spectrometry. Water samples were analyzed for their oxygen isotope ratios using the carbon dioxide-equilibration method. Waters analyzed from the...

140

Geothermometry At Long Valley Caldera Geothermal Area (Sorey...  

Open Energy Info (EERE)

studies, and seem to prove useful in most cases (Flexser, 1991; Goff et al., 1991; Smith and Suemnicht, 1991). Results from these studies are also summarized in Sorey et al....

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Geothermometry At Roosevelt Hot Springs Geothermal Area (Ward...  

Open Energy Info (EERE)

Area. References S. H. Ward, W. T. Parry, W. P. Nash, W. R. Sill, K. L. Cook, R. B. Smith, D. S. Chapman, F. H. Brown, J. A. Whelan, J. R. Bowman (1978) A Summary of the...

142

Colorado thermal spring water geothermometry (public dataset) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreisVolcanicPowerRaft River 5Courts Jump to:Information

143

Geothermometry At Akutan Fumaroles Area (Kolker, Et Al., 2010) | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergy Information

144

Geothermometry At Blackfoot Reservoir Area (Hutsinpiller & Parry, 1985) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergy

145

Geothermometry At Blue Mountain Geothermal Area (Casteel, Et Al., 2010) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergyOpen Energy

146

Geothermometry At Buffalo Valley Hot Springs Area (Laney, 2005) | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergyOpen

147

Geothermometry At Central Nevada Seismic Zone Region (Laney, 2005) | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey ofJumpEnergyOpenEnergy

148

Geothermometry At Central Nevada Seismic Zone Region (Shevenell & De  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A Survey

149

Geothermometry At Chena Geothermal Area (Kolker, 2008) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A SurveyInformation 2008)

150

Geothermometry At Coso Geothermal Area (1978) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A SurveyInformationEnergy

151

Geothermometry At Fort Bliss Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A SurveyInformationEnergyFishFort

152

Geothermometry At Hot Springs Ranch Area (Szybinski, 2006) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot Springs Ranch

153

Geothermometry At Kawaihae Area (Thomas, 1986) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot Springs

154

Geothermometry At Kilauea East Rift Geothermal Area (Thomas, 1986) | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot SpringsEnergy

155

Geothermometry At Lahaina-Kaanapali Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot

156

Geothermometry At Lassen Volcanic National Park Area (Janik & Mclaren,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) | Open

157

Geothermometry At Lassen Volcanic National Park Area (Thompson, 1985) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) | OpenOpen

158

Geothermometry At Long Valley Caldera Geothermal Area (Farrar, Et Al.,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) |

159

Geothermometry At Long Valley Caldera Geothermal Area (Mariner & Willey,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) |1976) |

160

Geothermometry At Lualualei Valley Area (Thomas, 1986) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010)

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Geothermometry At New River Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation| Open EnergyNew

162

Geothermometry At Roosevelt Hot Springs Geothermal Area (Ward, Et Al.,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation|Open1978) | Open

163

Geothermometry At The Needles Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -Information Shevenell, Et Al.,The

164

Geothermometry At Yellowstone Region (Fournier, 1979) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -Information

165

Isotope Geothermometry At Lightning Dock Geothermal Area (Witcher, 2006) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429 Throttled (botOpen Energy Information 2006) Jump to: navigation, search

166

Improved Geothermometry Through Multivariate Reaction Path Modeling and  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S. Department-2023Department ofSmartMethod forEvaluation of

167

Geochemistry And Geothermometry Of Spring Water From The Blackfoot  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision has beenFfe2fb55-352f-473b-a2dd-50ae8b27f0a6TheoreticalFuelCellGemini SolarAssetsof Thermal

168

Geothermometry At Alum Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourage the<Geothermal/PowerUse)DOE

169

Geothermometry At Coso Geothermal Area (1980) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourage

170

Geothermometry At Raft River Geothermal Area (1980) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourageInformation Desert

171

Geothermometry At Silver Peak Area (DOE GTP) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchToInformation Edmiston & Benoit,

172

Potential Modulated Intercalation of Alkali Cations into Metal Hexacyanoferrate Coated Electrodes  

SciTech Connect (OSTI)

Nickel hexacyanoferrate is a polynuclear inorganic ion intercalation material that loads (intercalates) and elutes (deintercalates) alkali cations from its structure when electrochemically reduced and oxidized, respectively. Nickel hexacyanoferrrate (NiHCF) is known to preferentially intercalate cesium over all other alkali cations, thus providing a basis for a separation scheme that can tackle DOE's radiocesium contamination problem. This program studied fundamental issues in alkalization intercalation and deintercalation in nickel hexacyanoferrate compounds, with the goal of (1) quantifying the ion exchange selectivity properties from cation mixtures, (2) enhancing ion exchange capacities, and (3) and understanding the electrochemically-switched ion exchange process (ESIX).

Daniel T. Schwartz; Bekki Liu; Marlina Lukman; Kavita M. Jeerage; William A. Steen; Haixia Dai; Qiuming Yu; J. Antonio Medina

2002-02-18T23:59:59.000Z

173

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process  

SciTech Connect (OSTI)

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16T23:59:59.000Z

174

Influence of liquid structure on diffusive isotope separation in molten silicates and aqueous solutions  

SciTech Connect (OSTI)

Molecular diffusion in natural volcanic liquids discriminates between isotopes of major ions (e.g., Fe, Mg, Ca, and Li). Although isotope separation by diffusion is expected on theoretical grounds, the dependence on mass is highly variable for different elements and in different media. Silicate liquid diffusion experiments using simple liquid compositions were carried out to further probe the compositional dependence of diffusive isotopic discrimination and its relationship to liquid structure. Two diffusion couples consisting of the mineral constituents anorthite (CaAl{sub 2}Si{sub 2}O{sub 8}; denoted AN), albite (NaAlSi{sub 3}O{sub 8}; denoted AB), and diopside (CaMgSi{sub 2}O{sub 6}; denoted DI) were held at 1450°C for 2 h and then quenched to ambient pressure and temperature. Major-element as well as Ca and Mg isotope profiles were measured on the recovered quenched glasses. In both experiments, Ca diffuses rapidly with respect to Si. In the AB–AN experiment, D{sub Ca}/D{sub Si} ~ 20 and the efficiency of isotope separation for Ca is much greater than in natural liquid experiments where D{sub Ca}/D{sub Si} ~ 1. In the AB–DI experiment, D{sub Ca}/D{sub Si} ~ 6 and the efficiency of isotope separation is between that of the natural liquid experiments and the AB–AN experiment. In the AB–DI experiment, D{sub Mg}/D{sub Si} ~ 1 and the efficiency of isotope separation for Mg is smaller than it is for Ca yet similar to that observed for Mg in natural liquids. The results from the experiments reported here, in combination with results from natural volcanic liquids, show clearly that the efficiency of diffusive separation of Ca isotopes is systematically related to the solvent-normalized diffusivity—the ratio of the diffusivity of the cation (D{sub Ca}) to the diffusivity of silicon (D{sub Si}). The results on Ca isotopes are consistent with available data on Fe, Li, and Mg isotopes in silicate liquids, when considered in terms of the parameter D{sub cation}/D{sub Si}. Cations diffusing in aqueous solutions display a similar relationship between isotopic separation efficiency and D{sub cation} =D{sub H 2 O} , although the efficiencies are smaller than in silicate liquids. Our empirical relationship provides a tool for predicting the magnitude of diffusive isotopic effects in many geologic environments and a basis for a more comprehensive theory of isotope separation in liquid solutions. We present a conceptual model for the relationship between diffusivity and liquid structure that is consistent with available data.

Watkins, J.M.; DePaolo, D.J.; Ryerson, F.J.; Peterson, B.

2011-03-01T23:59:59.000Z

175

Cation exchange at the secondary building units of metal–organic frameworks  

E-Print Network [OSTI]

Cation exchange is an emerging synthetic route for modifying the secondary building units (SBUs) of metal–organic frameworks (MOFs). This technique has been used extensively to enhance the properties of nanocrystals and ...

Brozek, Carl Kavanaugh

176

A Reduction for Automated Veri cation of Authentication Scott D. Stoller  

E-Print Network [OSTI]

A Reduction for Automated Veri cation of Authentication Protocols Scott D. Stoller Computer Science of those case studies were not rigorously justi ed. Reduction theorems are needed, which show

Stoller, Scott

177

The effect of trivalent cations on the major lower mantle silicates  

E-Print Network [OSTI]

I have investigated the effect of composition, especially ferric iron and aluminum, on the equations of state and phase stability of perovskite and post-perovskite. The presence of trivalent cations decreases the bulk ...

Catalli, Krystle Carina

2011-01-01T23:59:59.000Z

178

NMR Studies of Heat-Induced Transitions in Structure and Cation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Structure and Cation Binding Environments of a Strontium-Saturated Swelling Mica. Abstract: In this work we combined Al, Si, F, and Na magic-angle spinning (MAS) nuclear...

179

Identi cation Tasking and Networking (ITN) Model For The FBI's Integrated Automated  

E-Print Network [OSTI]

Identi cation Tasking and Networking (ITN) Model For The FBI's Integrated Automated Fingerprint September 29, 1994 Abstract This document describes the model developed for the ITN/FBI using the SES

Murphy, John

180

Properties of Liquid Plutonium  

SciTech Connect (OSTI)

Unalloyed polycrystalline Pu displays extreme thermal expansion behavior, i.e., {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} increases by 25% in volume and {delta} {yields} {var_epsilon} {yields} liquid decreases by 4.5% in volume. Thus, making it difficult to measure density into the liquid state. Dilatometer outfitted with CaF molten metal cell offers a proven capability to measure thermal expansion in molten metals, but has yet to be proven for Pu. Historic data from the liquid nuclear fuels program will prove extremely useful as a guide to future measurements. 3.3at% Ga changes Pu molten metal properties: 50% increase in viscosity and {approx}3% decrease in density. Fe may decrease the density by a small amount assuming an averaging of densities for Pu-Ga and Pu-Fe liquids. More recent Boivineau (2009) work needs some interpretation, but technique is being employed in (U,Pu)O{sub 2} nuclear fuels program (Pu Futures, 2012).

Freibert, Franz J. [Los Alamos National Laboratory; Mitchell, Jeremy N. [Los Alamos National Laboratory; Schwartz, Daniel S. [Los Alamos National Laboratory; Saleh, Tarik A. [Los Alamos National Laboratory; Migliori, Albert [Los Alamos National Laboratory

2012-08-02T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Adsorption and desorption kinetics of cesium in an organic matter-rich soil saturated with different cations  

SciTech Connect (OSTI)

The fallout from nuclear weapons tests conducted on Bikini Atoll Island in 1954 resulted in contamination of soil with Cesium 137. To develop effective regimes for decontaminating the Bikini Atoll soil, the exchange of Cs for K, Na, and other cations on the soil must be understood. Samples of soils made homoionic with K, Na, or Ca were reacted with solutions containing Cs ions, and the quantities of Cs sorbed and the rates of exchange were measured. The samples were then reacted with solutions containing K, Na, or Ca, and the quantities of Cs desorbed and the rates of exchange were again measured. Samples made homoionic with Na had a greater ion exchange capacity than samples made homoionic with K, and, in both cases, the ion exchange capacity increased with the organic matter content of the soil. For samples pretreated with Ca, the ion exchange capacity is not related in a simple way to the organic matter content. The kinetics were assessed by plotting the rate of exchange vs. the time and vs. the quantity exchanged. A first-order equation was obeyed during most of the run in Cs desorption experiments and during a limited part of the run in Cs adsorption experiments. An increase in the rate of Cs exchange was observed at the beginning of the experiments especially for Cs adsorption. This increase is presumably due to an increase of the ionic strength of the liquid phase during the exchange process. 33 refs., 9 figs., 2 tabs.

Aharoni, C. (Technion-Israel Inst. of Technology, Haifa (Israel)); Pasricha, N.S. (Punjab Agricultural Univ., Ludihana (India)); Sparks, D.L. (Univ. of Delaware, Newark, DE (United States))

1993-10-01T23:59:59.000Z

182

Imaging Liquids Using Microfluidic Cells  

SciTech Connect (OSTI)

Chemistry occurring in the liquid and liquid surface is important in many applications. Chemical imaging of liquids using vacuum based analytical techniques is challenging due to the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface sensitive techniques such as electron microscopy and spectroscopy. Due to its small size, low cost, and flexibility in design, liquid cells based on microfluidics have been increasingly used in studying and imaging complex phenomena involving liquids. This paper presents a review of microfluidic cells that were developed to adapt to electron microscopes and various spectrometers for in situ chemical analysis and imaging of liquids. The following topics will be covered including cell designs, fabrication techniques, unique technical features for vacuum compatible cells, and imaging with electron microscopy and spectroscopy. Challenges are summarized and recommendations for future development priority are proposed.

Yu, Xiao-Ying; Liu, Bingwen; Yang, Li

2013-05-10T23:59:59.000Z

183

Counterdiffusion of liquid hydrocarbon pairs in ion-exchanged forms of zeolite X  

SciTech Connect (OSTI)

Adsorptive counterdiffusion rates of liquid benzene, ethyl benzene, 1,3,5-trimethyl benzene, and 1-methyl naphthalene into Na/sup +/, K/sup +/, Cs/sup +/, and Ca/sup 2 +/ ion exchanged forms of zeolite X saturated with cyclohexane were measured. The diffusivity of the adsorbing hydrocarbon decreases as the effective pore size of the zeolite is decreased by ion exchange. The effective pore size in CaX and CsX was so small as not to allow the adsorptive counterdiffusion of 1,3,5-trimethyl benzene and 1-methyl naphthalene. Diffusion took place only after the cations in the pore mouths were displaced to other cation sites in the structure under the influence of the adsorbing hydrocarbon molecules, and thus the rate of counterdiffusion appeared to increase with time.

Culfaz, A.; Erguen, G.

1986-01-01T23:59:59.000Z

184

Free Radical Polymerization of Styrene and Methyl Methacrylate in Various Room Temperature Ionic Liquids  

SciTech Connect (OSTI)

Conventional free radical polymerization of styrene and methyl methacrylate was carried out in various room temperature ionic liquids (RTILs). The RTILs used in this research encompass a wide range of cations and anions. Typical cations include imidazolium, phosphonium, pyridinium, and pyrrolidinium; typical anions include amide, borate, chloride, imide, phosphate, and phosphinate. Reactions are faster and polymers obtained usually have higher molecular weights when compared to polymerizations carried out in volatile organic solvents under the same conditions. This shows that rapid rates of polymerization and high molecular weights are general features of conventional radical polymerizations in RTILs. Attempts to correlate the polarities and viscosities of the RTILs with the polymerization behavior fail to yield discernible trends.

Zhang, Hongwei [University of Tennessee, Knoxville (UTK); Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

2005-01-01T23:59:59.000Z

185

Liquid metal thermal electric converter  

DOE Patents [OSTI]

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

186

Liquid crystalline composites containing phyllosilicates  

DOE Patents [OSTI]

The present invention provides barrier films having reduced gas permeability for use in packaging and coating applications. The barrier films comprise an anisotropic liquid crystalline composite layer formed from phyllosilicate-polymer compositions. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while remaining transparent. Because of the ordering of the particles in the liquid crystalline composite, barrier films comprising liquid crystalline composites are particularly useful as barriers to gas transport.

Chaiko; David J. (Naperville, IL)

2007-05-08T23:59:59.000Z

187

High temperature liquid level sensor  

DOE Patents [OSTI]

A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

Tokarz, Richard D. (West Richland, WA)

1983-01-01T23:59:59.000Z

188

Interfacial Ionic Liquids: Connecting Static and Dynamic Structures  

E-Print Network [OSTI]

It is well-known that room temperature ionic liquids (RTILs) often adopt a charge-separated layered structure, i.e., with alternating cation- and anion-rich layers, at electrified interfaces. However, the dynamic response of the layered structure to temporal variations in applied potential is not well understood. We used in situ, real-time X-ray reflectivity (XR) to study the potential-dependent electric double layer (EDL) structure of an imidazolium-based RTIL on charged epitaxial graphene during potential cycling as a function of temperature. The results suggest that the graphene-RTIL interfacial structure is bistable in which the EDL structure at any intermediate potential can be described by the combination of two extreme-potential structures whose proportions vary depending on the polarity and magnitude of the applied potential. This picture is supported by the EDL structures obtained by fully atomistic molecular dynamics (MD) simulations at various static potentials. The potential-driven transition between the two structures is characterized by an increasing width but with an approximately fixed hysteresis magnitude as a function of temperature. The results are consistent with the coexistence of distinct anion and cation adsorbed structures separated by an energy barrier (~0.15 eV).

Ahmet Uysal; Hua Zhou; Guang Feng; Sang Soo Lee; Song Li; Peter T. Cummings; Pasquale F. Fulvio; Sheng Dai; John K. McDonough; Yury Gogotsi; Paul Fenter

2014-12-06T23:59:59.000Z

189

Analysis & Simulation of Dynamics in Supercooled Liquids  

E-Print Network [OSTI]

Moreover, the heat capacity of that liquid is also higherthe intensive heat capacities of the liquid and the crystal,

Elmatad, Yael Sarah

2011-01-01T23:59:59.000Z

190

Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC  

E-Print Network [OSTI]

Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC different excess Gibbs free energy models are evaluated: the NRTL, UNIQUAC and electrolyte- NRTL (eNRTL) models. In the case of eNRTL, a new formulation of the model is used, based on a symmetric reference

Stadtherr, Mark A.

191

Uranyl coordination environment in hydrophobic ionic liquids : an in situ investigation.  

SciTech Connect (OSTI)

Different inner-sphere coordination environments are observed for the uranyl nitrate complexes formed with octyl-phenyl-N,N-diisobutylcarbamoylmethylphosphine oxide and tributyl phosphate in dodecane and in the hydrophobic ionic liquids (ILs) [C{sub 4}mim][PF{sub 6}] and [C{sub 8}mim][N(SO{sub 2}CF{sub 3}){sub 2}]. Qualitative differences in the coordination environment of the extracted uranyl species are implied by changes in peak intensity patterns and locations for uranyl UV-visible spectral bands when the solvent is changed. EXAFS data for uranyl complexes in dodecane solutions is consistent with hexagonal bipyramidal coordination and the existence of UO{sub 2}(NO{sub 3}){sub 2}(CMPO){sub 2}. In contrast, the complexes formed when uranyl is transferred from aqueous nitric acid solutions into the ILs exhibit an average equatorial coordination number of approximately 4.5. Liquid/liquid extraction results for uranyl in both ILs indicate a net stoichiometry of UO{sub 2}(NO{sub 3})(CMPO){sup +}. The concentration of the IL cation in the aqueous phase increases in proportion to the amount of UO{sub 2}(NO{sub 3})(CMPO){sup +} in the IL phase, supporting a predominantly cation exchange mechanism for partitioning in the IL systems.

Visser, A. E.; Jensen, M. P.; Laszak, I.; Nash, K. L.; Choppin, G. R.; Roers, R. D.; Chemistry; Univ. of Alabama; Flordia State Univ.

2003-01-01T23:59:59.000Z

192

Liquid filtration simulation  

SciTech Connect (OSTI)

We have a developed a computer code that simulates 3-D filtration of suspended particles in fluids in realistic filter structures. This code, being the most advanced filtration simulation package developed to date, provides LLNL and DOE with new capabilities to address problems in cleaning liquid wastes, medical fluid cleaning, and recycling liquids. The code is an integrated system of commercially available and LLNL-developed software; the most critical are the computational fluid dynamics (CFD) solver and the particle transport program. For the CFD solver, we used a commercial package based on Navier-Stokes equations and a LLNL-developed package based on Boltzman-lattice gas equations. For the particle transport program, we developed a cod based on the 3-D Langevin equation of motion and the DLVO theory of electrical interactions. A number of additional supporting packages were purchased or developed to integrate the simulation tasks and to provide visualization output.

Corey, I.; Bergman, W.

1996-06-01T23:59:59.000Z

193

Colloid Facilitated Transport of Radioactive Cations in the Vadose Zone: Field Experiments Oak Ridge  

SciTech Connect (OSTI)

The overarching goal of this study was to improve understanding of colloid-facilitated transport of radioactive cations through unsaturated soils and sediments. We conducted a suite of laboratory experiments and field experiments on the vadose-zone transport of colloids, organic matter, and associated contaminants of interest to the U.S. Department of Energy (DOE). The laboratory and field experiments, together with transport modeling, were designed to accomplish the following detailed objectives: 1. Evaluation of the relative importance of inorganic colloids and organic matter to the facilitation of radioactive cation transport in the vadose zone; 2. Assessment of the role of adsorption and desorption kinetics in the facilitated transport of radioactive cations in the vadose zone; 3. Examination of the effects of rainfall and infiltration dynamics and in the facilitated transport of radioactive cations through the vadose zone; 4. Exploration of the role of soil heterogeneity and preferential flow paths (e.g., macropores) on the facilitated transport of radioactive cations in the vadose zone; 5. Development of a mathematical model of facilitated transport of contaminants in the vadose zone that accurately incorporates pore-scale and column-scale processes with the practicality of predicting transport with readily available parameters.

James E. Saiers

2012-09-20T23:59:59.000Z

194

Ionic Liquid Pretreatment Technologies  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy Health andofIan KalinResearch,IntroducingIonic Liquid Pretreatment EERE

195

Mathematical Modeling of Cation Contamination in a Proton-exchange Membrane  

SciTech Connect (OSTI)

Transport phenomena in an ion-exchange membrane containing both H+ and K+ are described using multicomponent diffusion equations (Stefan-Maxwell). A model is developed for transport through a Nafion 112 membrane in a hydrogen-pump setup. The model results are analyzed to quantify the impact of cation contamination on cell potential. It is shown that limiting current densities can result due to a decrease in proton concentration caused by the build-up of contaminant ions. An average cation concentration of 30 to 40 percent is required for appreciable effects to be noticed under typical steady-state operating conditions.

Weber, Adam; Delacourt, Charles

2008-09-11T23:59:59.000Z

196

Supported liquid membrane electrochemical separators  

DOE Patents [OSTI]

Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

1986-01-01T23:59:59.000Z

197

Liquid monobenzoxazine based resin system  

DOE Patents [OSTI]

The present invention provides a liquid resin system including a liquid monobenzoxazine monomer and a non-glycidyl epoxy compound, wherein the weight ratio of the monobenzoxazine monomer to the non-glycidyl epoxy compound is in a range of about 25:75 to about 60:40. The liquid resin system exhibits a low viscosity and exceptional stability over an extended period of time making its use in a variety of composite manufacturing methods highly advantageous.

Tietze, Roger; Nguyen, Yen-Loan; Bryant, Mark

2014-10-07T23:59:59.000Z

198

Process for removal of mineral particulates from coal-derived liquids  

DOE Patents [OSTI]

Suspended mineral solids are separated from a coal-derived liquid containing the solids by a process comprising the steps of: (a) contacting said coal-derived liquid containing solids with a molten additive having a melting point of 100.degree.-500.degree. C. in an amount of up to 50 wt. % with respect to said coal-derived liquid containing solids, said solids present in an amount effective to increase the particle size of said mineral solids and comprising material or mixtures of material selected from the group of alkali metal hydroxides and inorganic salts having antimony, tin, lithium, sodium, potassium, magnesium, calcium, beryllium, aluminum, zinc, molybdenum, cobalt, nickel, ruthenium, rhodium or iron cations and chloride, iodide, bromide, sulfate, phosphate, borate, carbonate, sulfite, or silicate anions; and (b) maintaining said coal-derived liquid in contact with said molten additive for sufficient time to permit said mineral matter to agglomerate, thereby increasing the mean particle size of said mineral solids; and (c) recovering a coal-derived liquid product having reduced mineral solids content. The process can be carried out with less than 5 wt. % additive and in the absence of hydrogen pressure.

McDowell, William J. (Knoxville, TN)

1980-01-01T23:59:59.000Z

199

Process for preparing liquid wastes  

DOE Patents [OSTI]

A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

1997-01-01T23:59:59.000Z

200

FLARE, Fermilab Liquid Argon Experiments  

E-Print Network [OSTI]

Mature technology of Liquid Argon Time Projection Chambers in conjunction with intense neutrino beams constructed at Fermilab offer a broad program of neutrino physics for the next decade.

L. Bartoszek

2004-08-24T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Fluorohydrogenate Cluster Ions in the Gas Phase: Electrospray Ionization Mass Spectrometry of the [1-Ethyl-3-methylimidazolium+][F(HF)2.3–] Ionic Liquid  

SciTech Connect (OSTI)

Electrospray ionization of the fluorohydrogenate ionic liquid [1-ethyl-3-methylimidazolium][F(HF)2.3] ionic liquid was conducted to understand the nature of the anionic species as they exist in the gas phase. Abundant fluorohydrogenate clusters were produced; however, the dominant anion in the clusters was [FHF-], and not the fluoride-bound HF dimers or trimers that are seen in solution. Density functional theory (DFT) calculations suggest that HF molecules are bound to the clusters by about 30 kcal/mol. The DFT-calculated structures of the [FHF-]-bearing clusters show that the favored interactions of the anions are with the methynic and acetylenic hydrogen atoms on the imidazolium cation, forming planar structures similar to those observed in the solid state. A second series of abundant negative ions was also formed that contained [SiF5-] together with the imidazolium cation and the fluorohydrogenate anions that originate from reaction of the spray solution with silicate surfaces.

Gary S. Groenewold; James E. Delmore; Michael T. Benson; Tetsuya Tsuda; Rika Hagiwara

2013-12-01T23:59:59.000Z

202

Criteria for Generating Speci cation-based Tests A. Je erson O utt and Yiwei Xiong Shaoying Liu  

E-Print Network [OSTI]

- ria o er testers ways to decide what test inputs to use during testing, making it more likely presents a model for developing test in- puts from state-based speci cations, and formal crite- riaCriteria for Generating Speci cation-based Tests A. Je erson O utt and Yiwei Xiong Shaoying Liu

Offutt, Jeff

203

Bias-dependent molecular-level structure of electrical double layer in ionic liquid on graphite  

SciTech Connect (OSTI)

Bias-dependent structure of electrochemical double layers at liquid-solid interfaces underpin a multitude of phenomena in virtually all areas of scientific enquiry ranging from energy storage and conversion systems, biology, to geophysics and geochemistry. Here we report the bias-evolution of the electric double layer structure of an ionic liquid on highly ordered pyrolytic graphite as a model system for carbon-based electrodes for electrochemical supercapacitors measured by atomic force microscopy. Matching the observed structures to molecular dynamics simulations allows us to resolve steric effects due to cation and anion layers. We observe reconfiguration under applied bias and the orientational transitions in the Stern layer. The synergy between molecular dynamics simulation and experiment provides a comprehensive picture of structural phenomena and long- and short range interactions. This insight will improve understanding of the mechanism of charge storage in electrochemical capacitors on a molecular level which can be used to enhance their electrochemical performance.

Black, Jennifer M [ORNL] [ORNL; Walters, Deron [Asylum Research, Santa Barbara, CA] [Asylum Research, Santa Barbara, CA; Labuda, Aleksander [Asylum Research, Santa Barbara, CA] [Asylum Research, Santa Barbara, CA; Feng, Guang [ORNL] [ORNL; Hillesheim, Patrick C [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL; Cummings, Peter T [ORNL] [ORNL; Kalinin, Sergei V [ORNL] [ORNL; Proksch, Roger [Asylum Research, Santa Barbara, CA] [Asylum Research, Santa Barbara, CA; Balke, Nina [ORNL] [ORNL

2013-01-01T23:59:59.000Z

204

Anion effects in the extraction of lanthanide 2-thenoyltrifluoroacetone complexes into an ionic liquid  

SciTech Connect (OSTI)

The extraction of trivalent lanthanides from an aqueous phase containing 1 M NaClO{sub 4} into the room temperature ionic liquid 1-butyl-3-methylimidazolium nonafluoro-1-butane sulfonate by the beta-diketone extractant 2-thenoyltrifluoroacetone (Htta) was studied. Radiotracer distribution, absorption spectroscopy, time-resolved laser-induced fluorescence spectroscopy, and X-ray absorption fine structure measurements point to the extraction of multiple lanthanide species. At low extractant concentrations, fully hydrated aqua cations of the lanthanides are present in the ionic liquid phase. As the extractant concentration is increased 1:2 and 1:3 lanthanide:tta species are observed. In contrast, 1:4 Ln:tta complexes were observed in the extraction of lanthanides by Htta into 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide. (authors)

Jensen, Mark P.; Beitz, James V.; Rickert, Paul G. [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Borkowski, Marian [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Los Alamos Natl Lab, Earth and Environm Sci Div, Carlsbad, NM, (United States); Laszak, Ivan [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Commisariat Energie Atom, DEN DPC SERC LANIE, Gif Sur Yvette, (France); Dietz, Mark L. [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Wisconsin-Milwaukee Univ, Department of Chemistry and Biochemistry, Milwaukee, WI, (United States)

2012-07-01T23:59:59.000Z

205

FLUORINATED HYDROXYTELECHELIC POLYBUTADIENE AS ADDITIVE IN CATIONIC PHOTOPOLYMERIZATION OF AN EPOXY RESIN  

E-Print Network [OSTI]

OF AN EPOXY RESIN B. Ameduri 1 , R. Bongiovanni2 , M. Sangermano2 , A. Priola2 1 Ingénierie et Architectures in original formulations to enable the UV cationic polymerization of a telechelic diepoxy cycloaliphatic resin) values showing a surface modification of the epoxy based system. Indeed, great modifications were noted

Paris-Sud XI, Université de

206

High energy electron beam curing of epoxy resin systems incorporating cationic photoinitiators  

DOE Patents [OSTI]

A mixture of epoxy resins such as a semi-solid triglycidyl ether of tris (hydroxyphenyl) methane and a low viscosity bisphenol A glycidyl ether and a cationic photoinitiator such as a diaryliodonium salt is cured by irradiating with a dosage of electron beams from about 50 to about 150 kGy, forming a cross-linked epoxy resin polymer.

Janke, C.J.; Lopata, V.J.; Havens, S.J.; Dorsey, G.F.; Moulton, R.J.

1999-03-02T23:59:59.000Z

207

CO adsorption-desorption properties of cation-exchanged NaX zeolite and supported ruthenium  

SciTech Connect (OSTI)

The binding states of carbon monoxide over cation-exchanged NaX zeolites and over corresponding Ru-containing samples have been investigated using thermal desorption spectroscopy. Exchange of sodium with cations such as Li{sup +}, Ca{sup 2+}, Mg{sup 2+}, and La{sup 3+} gave rise to additional CO adsorption states, a higher isosteric heat of CO adsorption, an increased density of acid sites, and an increased amount of adsorbed CO, depending on the nature and ionic radius of the charge-balancing cation. The charge-balancing cations at the zeolite surface (e.g., Ca{sub 2+}, La{sup 3+}) function as additional CO adsorption sites in conjunction with surface acid centers (e.g., the Al{sup 3+} center) and metal sites. In addition to surface sites, CO is also found to be held in structural cavities and macropores of the zeolite matrix. The programmed heating of both the metal-free and Ru-containing zeolites subsequent to room temperature CO adsorption gave desorption peaks due to release of CO at temperatures less than {approximately}500 K while the higher temperature peaks were constituted mainly of CO{sub 2}. Electron spectroscopy results have revealed that the exposure of these samples to CO and subsequent thermal treatment resulted in the formation of surface carbonaceous species. The nature of CO adsorption states giving rise to CO{sub 2} formation is discussed.

Gupta, N.M.; Kamble, V.S.; Rao, K.A.; Iyer, R.M. (Bhabha Atomic Research Centre, Bombay (India))

1989-12-01T23:59:59.000Z

208

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory  

E-Print Network [OSTI]

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory Ricardo B. Metz Department of Chemistry, University of Massachusetts, Amherst, MA 01003 USA Abstract Gas such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

Metz, Ricardo B.

209

Calcium and Strontium Hexaluminates: NMR Evidence that "Pentacoordinate" Cation Sites Are Four-Coordinated  

E-Print Network [OSTI]

LETTERS Calcium and Strontium Hexaluminates: NMR Evidence that "Pentacoordinate" Cation Sites, strontium hexaluminate (SrAl12O19, "SA6") and calcium hexaluminate (CaAl12O19, "CA6," synthetic hibonite, not dynamical, disorder among these sites. Introduction Calcium and strontium hexaluminates (CaAl12O19, "CA6

Puglisi, Joseph

210

A Fuzzy Neural Network Approach Based on Dirichlet Tesselations for Nearest Neighbor Classi cation of  

E-Print Network [OSTI]

-mail: andreas@theseas.ntua.gr Abstract A neural network classi er using fuzzy set representation of pattern concerning di cult recognition problems show that the proposed approach is very successful in applying fuzzy sets to pattern classi cation. 1 Introduction Several models have been developed during the last years

Blekas, Konstantinos

211

Solidi cation of a high-Reynolds-number ow in laser percussion drilling  

E-Print Network [OSTI]

Solidi#12;cation of a high-Reynolds-number ow in laser percussion drilling W. R. Smith y and R. M laser percussion drilling. 1 Introduction Laser percussion drilling is used to machine gas turbine with conventional mechanical drills. The term percussion refers to the repeated operation of the laser in short

Eindhoven, Technische Universiteit

212

Spectroscopic signatures of proton transfer dynamics in the water dimer cation  

SciTech Connect (OSTI)

Using full dimensional EOM-IP-CCSD/aug-cc-pVTZ potential energy surfaces, the photoelectron spectrum, vibrational structure, and ionization dynamics of the water dimer radical cation, (H2O)+2, were computed. We also report an experimental photoelectron spectrum which is derived from photoionization efficiency measurements and compares favorably with the theoretical spectrum. The vibrational structure is also compared with the recent experimental work of Gardenier et al. [J. Phys. Chem. A 113, 4772 (2009)] and the recent theoretical calculations by Cheng et al. [J. Phys. Chem. A 113 13779 (2009)]. A reduced dimensionality nuclear Hamiltonian was used to compute the ionization dynamics for both the ground state and first excited state of the cation. The dynamics show markedly different behavior and spectroscopic signatures depending on which state of the cation is accessed by the ionization. Ionization to the ground-state cation surface induces a hydrogen transfer which is complete within 50 femtoseconds, whereas ionization to the first excited state results in a much slower process.

Kamarchik, Eugene; Kostko, Oleg; Bowman, Joel M.; Ahmed, Musahid; Krylov, Anna I.

2009-12-21T23:59:59.000Z

213

Synthesis and Reversible Reductive Coupling of Cationic, Dinitrogen-Derived Diazoalkane Complexes  

E-Print Network [OSTI]

A series of cationic diazoalkane complexes [4-RC6H4C(H)NNMo(N[t-Bu]Ar)3][AlCl4] 4-RC subscript 6 H subscript 4 C(H)NNMo(N[t-Bu]Ar) subscript 3] [AlCl subscript 4

Curley, John J.

214

Evaluation of cation-exchanged zeolite adsorbents for post-combustion carbon dioxide capture  

E-Print Network [OSTI]

anthro- pogenic sources.1 Carbon capture and sequestration (CCS) has been proposed as a means of limitingEvaluation of cation-exchanged zeolite adsorbents for post-combustion carbon dioxide capture Tae the impact of rising concentrations of atmo- spheric carbon dioxide on climate change continue to mount

215

The effect of paramagnetic manganese cations on 1 H MR spectroscopy of the brain  

E-Print Network [OSTI]

The effect of paramagnetic manganese cations on 1 H MR spectroscopy of the brain K. S. Madsen1 has investigated the effect of Mn on 1 H MR spectroscopy using an in vivo Mn-enhanced optic tract into a stereotactic device. Images and 1 H MR spectra were acquired using a Varian 4.7T animal scanner together

216

AMAST '96, July 1-5, 1996, Munich, Germany Formal Veri cation of Signal Programs  

E-Print Network [OSTI]

to a Power Transformer Station Controller? Michel Le Borgne, Herve Marchand, Eric Rutten IRISA / INRIA cation of the automatic circuit breaking control system of an electric power transformer station is double:protecting the components of the transformer itself, and minimizing the defect in the distribution

Paris-Sud XI, Université de

217

Syst. Biol. 49(4):617627, 2000 Quanti cation of Homoplasy for Nucleotide Transitions and  

E-Print Network [OSTI]

Syst. Biol. 49(4):617­627, 2000 Quanti cation of Homoplasy for Nucleotide Transitions Science Park, New Haven, CT 06511, USA; E-mail: s.stanley@genaissance.com Abstract.--Nucleotide used in molecular systematics, where homoplasy in nucleotide characters may be abundant because

Sorenson, Michael

218

oligomeric and polymeric DNA Large electrostatic differences in the binding thermodynamics of a cationic peptide to  

E-Print Network [OSTI]

oligomeric and polymeric DNA Large electrostatic differences in the binding thermodynamics electrostatic differences in the binding thermodynamics of a cationic peptide to oligomeric and polymeric DNA binding to polymeric and oligomeric DNA are not equivalent because of long-range electrostatic effects

Lohman, Timothy M.

219

High energy electron beam curing of epoxy resin systems incorporating cationic photoinitiators  

DOE Patents [OSTI]

A mixture of epoxy resins such as a semi-solid triglycidyl ether of tris (hydroxyphenyl) methane and a low viscosity bisphenol A glycidyl ether and a cationic photoinitiator such as a diaryliodonium salt is cured by irradiating with a dosage of electron beams from about 50 to about 150 kGy, forming a cross-linked epoxy resin polymer.

Janke, Christopher J. (Powell, TN); Lopata, Vincent J. (Manitoba, CA); Havens, Stephen J. (Knoxville, TN); Dorsey, George F. (Farragut, TN); Moulton, Richard J. (Lafayette, CA)

1999-01-01T23:59:59.000Z

220

Analysis of Mixture Models using Expected Posterior Priors, with Application to Classi cation  

E-Print Network [OSTI]

of Gamma Ray Bursts Jos#19;e M. P#19;erez and James O. Berger #3; Abstract Consider observations the number of components is unknown. An appli- cation is considered involving Gamma Ray Bursts, modeled is considered in section 4 in the determination of the number of classes of Gamma Ray Bursts (Meegan et al

West, Mike

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Correlation among electronegativity, cation polarizability, optical basicity and single bond strength of simple oxides  

SciTech Connect (OSTI)

A suitable relationship between free-cation polarizability and electronegativity of elements in different valence states and with the most common coordination numbers has been searched on the basis of the similarity in physical nature of both quantities. In general, the cation polarizability increases with decreasing element electronegativity. A systematic periodic change in the polarizability against the electronegativity has been observed in the isoelectronic series. It has been found that generally the optical basicity increases and the single bond strength of simple oxides decreases with decreasing the electronegativity. The observed trends have been discussed on the basis of electron donation ability of the oxide ions and type of chemical bonding in simple oxides. - Graphical abstract: This figure shows the single bond strength of simple oxides as a function of element electronegativity. A remarkable correlation exists between these independently obtained quantities. High values of electronegativity correspond to high values of single bond strength and vice versa. It is obvious that the observed trend in this figure is closely related to the type of chemical bonding in corresponding oxide. Highlights: Black-Right-Pointing-Pointer A suitable relationship between free-cation polarizability and electronegativity of elements was searched. Black-Right-Pointing-Pointer The cation polarizability increases with decreasing element electronegativity. Black-Right-Pointing-Pointer The single bond strength of simple oxides decreases with decreasing the electronegativity. Black-Right-Pointing-Pointer The observed trends were discussed on the basis of type of chemical bonding in simple oxides.

Dimitrov, Vesselin, E-mail: vesselin@uctm.edu [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria)] [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki, E-mail: komatsu@mst.nagaokaut.ac.jp [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)] [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

2012-12-15T23:59:59.000Z

222

Neutralization of Methyl Cation via Chemical Reactions in Low-Energy Ion-Surface  

E-Print Network [OSTI]

with Fluorocarbon and Hydrocarbon Self-Assembled Monolayer Films A´ rpa´d Somogyi, Darrin L. Smith, and Vicki H-surface collisions of methyl cation at hydrocarbon and fluorocarbon self- assembled monolayer (SAM) surfaces produce with hydrocarbon and fluorocarbon SAMs occurs by concerted chemical reactions, i.e., that neutralization

Wysocki, Vicki H.

223

Lithium-loaded liquid scintillators  

DOE Patents [OSTI]

The invention is directed to a liquid scintillating composition containing (i) one or more non-polar organic solvents; (ii) (lithium-6)-containing nanoparticles having a size of up to 10 nm and surface-capped by hydrophobic molecules; and (iii) one or more fluorophores. The invention is also directed to a liquid scintillator containing the above composition.

Dai, Sheng (Knoxville, TN); Kesanli, Banu (Mersin, TR); Neal, John S. (Knoxville, TN)

2012-05-15T23:59:59.000Z

224

Freezing of a Liquid Marble  

E-Print Network [OSTI]

In this study, we present for the first time the observations of a freezing liquid marble. In the experiment, liquid marbles are gently placed on the cold side of a Thermo-Electric Cooler (TEC) and the morphological changes are recorded and characterized thereafter. These liquid marbles are noticed to undergo a shape transition from a spherical to a flying-saucer shaped morphology. The freezing dynamics of liquid marbles is observed to be very different from that of a freezing water droplet on a superhydrophobic surface. For example, the pointy tip appearing on a frozen water drop could not be observed for a frozen liquid marble. In the end, we highlight a possible explanation for the observed morphology.

Ali Hashmi; Adam Strauss; Jie Xu

2012-07-03T23:59:59.000Z

225

Method for treating liquid wastes  

DOE Patents [OSTI]

The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

1995-12-26T23:59:59.000Z

226

Method for treating liquid wastes  

DOE Patents [OSTI]

The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

Katti, Kattesh V. (Columbia, MO); Volkert, Wynn A. (Columbia, MO); Singh, Prahlad (Columbia, MO); Ketring, Alan R. (Columbia, MO)

1995-01-01T23:59:59.000Z

227

Shearing Flows in Liquid Crystal Models  

E-Print Network [OSTI]

The liquid crystal phase is a phase of matter between the solid and liquid phase whose flow is characterized by a velocity field and a director field which describes locally the orientation of the liquid crystal. In this ...

Dorn, Timothy

2012-05-31T23:59:59.000Z

228

Method of measuring a liquid pool volume  

DOE Patents [OSTI]

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid.

Garcia, Gabe V. (Las Cruces, NM); Carlson, Nancy M. (Idaho Falls, ID); Donaldson, Alan D. (Idaho Falls, ID)

1991-01-01T23:59:59.000Z

229

Oil-Miscible and Non-Corrosive Phosphonium Ionic Liquids as Candidate Lubricant Additives  

SciTech Connect (OSTI)

Ionic liquids (ILs) have been receiving considerable attention from the lubricants industry as potential friction and wear-reducing additives, but their solubility in oils is an issue. Unlike most ionic liquids that are insoluble in non-polar hydrocarbon oils, this study reports phosphonium-based ILs (PP-ILs) that are fully miscible with both mineral oil-based and synthetic lubricants. Both the cation and anion in quaternary structures, long alkyl chains, and capability of pairing the cation and the anion via a H-O bond are hypothesized to improve the compatibility between ions and neutral oil molecules. The measured viscosities of the oil-IL blends agree well with the Refutas equation that is for solutions containing multiple components. High thermal stability and non-corrosiveness were observed for the PP-ILs. Effective friction reduction and anti-wear functionality have been demonstrated in tribological tests when adding 5 wt% of a PP-IL into a base oil, suggesting potential applications for using the oil-miscible PP-ILs as lubricant additives.

Yu, Bo [ORNL; Bansal, Dinesh G [ORNL; Qu, Jun [ORNL; Sun, Xiaoqi [ORNL; Luo, Huimin [ORNL; Dai, Sheng [ORNL; Blau, Peter Julian [ORNL; Bunting, Bruce G [ORNL; Mordukhovich, Gregory [GM R& D and Planning, Warren, Michigan; Smolenski, Donald [GM R& D and Planning, Warren, Michigan

2012-01-01T23:59:59.000Z

230

Renewable Liquid Fuels Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Renewable Liquid Fuels Reforming The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used...

231

Singular Limits in Polymer Stabilized Liquid Crystals  

E-Print Network [OSTI]

We investigate equilibrium configurations for a polymer stabilized liquid crys- tal material ... eling the cross section of the liquid crystal-polymer fiber composite.

1910-31-00T23:59:59.000Z

232

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...  

Broader source: Energy.gov (indexed) [DOE]

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

233

Determining diffusion coefficients of ionic liquids by means of field cycling nuclear magnetic resonance relaxometry  

SciTech Connect (OSTI)

Field Cycling Nuclear Magnetic Resonance (FC NMR) relaxation studies are reported for three ionic liquids: 1-ethyl-3- methylimidazolium thiocyanate (EMIM-SCN, 220–258 K), 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM-BF{sub 4}, 243–318 K), and 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF{sub 6}, 258–323 K). The dispersion of {sup 1}H spin-lattice relaxation rate R{sub 1}(?) is measured in the frequency range of 10 kHz–20 MHz, and the studies are complemented by {sup 19}F spin-lattice relaxation measurements on BMIM-PF{sub 6} in the corresponding frequency range. From the {sup 1}H relaxation results self-diffusion coefficients for the cation in EMIM-SCN, BMIM-BF{sub 4}, and BMIM-PF{sub 6} are determined. This is done by performing an analysis considering all relevant intra- and intermolecular relaxation contributions to the {sup 1}H spin-lattice relaxation as well as by benefiting from the universal low-frequency dispersion law characteristic of Fickian diffusion which yields, at low frequencies, a linear dependence of R{sub 1} on square root of frequency. From the {sup 19}F relaxation both anion and cation diffusion coefficients are determined for BMIM-PF{sub 6}. The diffusion coefficients obtained from FC NMR relaxometry are in good agreement with results reported from pulsed- field-gradient NMR. This shows that NMR relaxometry can be considered as an alternative route of determining diffusion coefficients of both cations and anions in ionic liquids.

Kruk, D. [Faculty of Mathematics and Computer Science, University of Warmia and Mazury in Olsztyn, S?oneczna 54, PL-10710 Olsztyn (Poland); Universität Bayreuth, Experimentalphysik II, 95440 Bayreuth (Germany); Meier, R.; Rössler, E. A. [Universität Bayreuth, Experimentalphysik II, 95440 Bayreuth (Germany); Rachocki, A. [Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Pozna? (Poland); Korpa?a, A. [Department of Biophysics, Jagiellonian University Medical College, ?azarza 16, 31-530 Kraków, Poland and Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Kraków (Poland); Singh, R. K. [Ionic Liquid and Solid State Ionics Laboratory, Department of Physics, Banaras Hindu University, Varanasi 221 005 (India)

2014-06-28T23:59:59.000Z

234

Haze Formation and Behavior in Liquid-Liquid Extraction Processes  

SciTech Connect (OSTI)

Aqueous haze formation and behavior was studied in the liquid-liquid system tri-n-butyl phosphate in odorless kerosene and 3M nitric acid with uranyl nitrate and cesium nitrate representing the major solute and an impurity, respectively. A pulsed column, mixer-settler and centrifugal contactor were chosen to investigate the effect of different turbulence characteristics on the manifestation of haze since these contactors exhibit distinct mixing phenomena. The dispersive processes of drop coalescence and breakage, and water precipitation in the organic phase were observed to lead to the formation of haze drops of {approx}1 um in diameter. The interaction between the haze and primary drops of the dispersion was critical to the separation efficiency of the liquid-liquid extraction equipment. Conditions of high power input and spatially homogeneous mixing enabled the haze drops to become rapidly assimilated within the dispersion to maximize the scrub performance and separation efficiency of the equipment.

Arm, Stuart T.; Jenkins, J. A.

2006-07-31T23:59:59.000Z

235

Semantics of Architectural Speci cations in CASL Lutz Schroder 1 , Till Mossakowski 1 , Andrzej Tarlecki 2;3 , Bartek Klin 4 , and  

E-Print Network [OSTI]

at various levels in an institution-independent fashion. Introduction A common feature of present-day algebraic speci#12;cation languages (see e.g. [Wir86,EM85,GHG + 93,CoFI96,SW99]) is the provision;cations at various levels. We use a simple subset of Casl architectural speci#12;cations, which

Schröder, Lutz

236

Hydrophobic ionic liquids  

DOE Patents [OSTI]

Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F--, Cl--, CF.sub.3 --, SF.sub.5 --, CF.sub.3 S--, (CF.sub.3).sub.2 CHS-- or (CF.sub.3).sub.3 CS--; and X.sup.- is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 .ANG..sup.3.

Koch, Victor R. (Lincoln, MA); Nanjundiah, Chenniah (Lynn, MA); Carlin, Richard T. (Nashua, NH)

1998-01-01T23:59:59.000Z

237

Hydrophobic ionic liquids  

DOE Patents [OSTI]

Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas shown in a diagram wherein R{sub 1}, R{sub 2}, R{sub 3}, R{sub 4}, R{sub 5}, and R{sub 6} are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F-, Cl-, CF{sub 3}-, SF{sub 5}-, CF{sub 3}S-, (CF{sub 3}){sub 2}CHS- or (CF{sub 3}){sub 3}CS-; and X{sup {minus}} is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 {angstrom}{sup 3}. 4 figs.

Koch, V.R.; Nanjundiah, C.; Carlin, R.T.

1998-10-27T23:59:59.000Z

238

Lithium Ion Transport Mechanism in Ternary Polymer Electrolyte-Ionic Liquid Mixtures - A Molecular Dynamics Simulation Study  

E-Print Network [OSTI]

The lithium transport mechanism in ternary polymer electrolytes, consisting of PEO/LiTFSI and various fractions of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethane)sulfonimide, are investigated by means of MD simulations. This is motivated by recent experimental findings [Passerini et al., Electrochim. Acta 2012, 86, 330-338], which demonstrated that these materials display an enhanced lithium mobility relative to their binary counterpart PEO/LiTFSI. In order to grasp the underlying microscopic scenario giving rise to these observations, we employ an analytical, Rouse-based cation transport model [Maitra at al., PRL 2007, 98, 227802], which has originally been devised for conventional polymer electrolytes. This model describes the cation transport via three different mechanisms, each characterized by an individual time scale. It turns out that also in the ternary electrolytes essentially all lithium ions are coordinated by PEO chains, thus ruling out a transport mechanism enhanced by the presence of ionic-liquid molecules. Rather, the plasticizing effect of the ionic liquid contributes to the increased lithium mobility by enhancing the dynamics of the PEO chains and consequently also the motion of the attached ions. Additional focus is laid on the prediction of lithium diffusion coefficients from the simulation data for various chain lengths and the comparison with experimental data, thus demonstrating the broad applicability of our approach.

Diddo Diddens; Andreas Heuer

2013-02-20T23:59:59.000Z

239

Molecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Richard J. Sadus  

E-Print Network [OSTI]

coexistence. 1. Introduction Henry's constant is a well-known measure of a solute's solubility in a particularMolecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Boundaries Richard to determine Henry's constant from the residual chemical potential at infinite dilution at the vapor-liquid

240

Communication: CO oxidation by silver and gold cluster cations: Identification of different active oxygen species  

SciTech Connect (OSTI)

The oxidation of carbon monoxide with nitrous oxide on mass-selected Au{sub 3}{sup +} and Ag{sub 3}{sup +} clusters has been investigated under multicollision conditions in an octopole ion trap experiment. The comparative study reveals that for both gold and silver cations carbon dioxide is formed on the clusters. However, whereas in the case of Au{sub 3}{sup +} the cluster itself acts as reactive species that facilitates the formation of CO{sub 2} from N{sub 2}O and CO, for silver the oxidized clusters Ag{sub 3}O{sub x}{sup +} (n= 1-3) are identified as active in the CO oxidation reaction. Thus, in the case of the silver cluster cations N{sub 2}O is dissociated and one oxygen atom is suggested to directly react with CO, whereas a second kind of oxygen strongly bound to silver is acting as a substrate for the reaction.

Popolan, Denisia M.; Bernhardt, Thorsten M. [Institute of Surface Chemistry and Catalysis, University of Ulm, Albert-Einstein-Allee 47, 89069 Ulm (Germany)

2011-03-07T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Aza Cope Rearrangement of Propargyl Enammonium Cations Catalyzed By a Self-Assembled `Nanozyme  

SciTech Connect (OSTI)

The tetrahedral [Ga{sub 4}L{sub 6}]{sup 12-} assembly (L = N,N-bis(2,3-dihydroxybenzoyl)-1,5-diaminonaphthalene) encapsulates a variety of cations, including propargyl enammonium cations capable of undergoing the aza Cope rearrangement. For propargyl enammonium substrates that are encapsulated in the [Ga{sub 4}L{sub 6}]{sup 12-} assembly, rate accelerations of up to 184 are observed when compared to the background reaction. After rearrangement, the product iminium ion is released into solution and hydrolyzed allowing for catalytic turnover. The activation parameters for the catalyzed and uncatalyzed reaction were determined, revealing that a lowered entropy of activation is responsible for the observed rate enhancements. The catalyzed reaction exhibits saturation kinetics; the rate data obey the Michaelis-Menten model of enzyme kinetics, and competitive inhibition using a non-reactive guest has been demonstrated.

Hastings, Courntey J.; Fiedler, Dorothea; Bergman, Robert G.; Raymond, Kenneth N.

2008-02-27T23:59:59.000Z

242

Metal cation/anion adsorption on calcium carbonate: Implications to metal ion concentrations in groundwater  

SciTech Connect (OSTI)

This chapter evaluates the sorption behavior of metallic ions on specimen calcite as a basis for determining the importance of calcite relative to other subsurface sorbents, such as layer silicates and oxides, in controlling metal ion concentration in calcareous groundwaters. A review of the literature shows the sorption of both metallic cations and anions on calcite over ranges in pH and CO{sub 2} partial pressure to be consistent with a surface-exchange process where cations exchange with surface Ca and anions exchange with surface CO{sub 3}. A general surface-exchange model was developed to account for the effects of Ca and CO{sub 3} concentrations, pH, and calcite surface area on cation and anion sorption onto calcite. The model was applied to recently developed experimental sorption data of Zn and SeO{sub 3} on specimen calcite in equilibrium CaCO{sub 3}(aq) suspensions. The surface-exchange model was able to describe the effects of pH on both cation and anion sorption, and provided good predictions of the effects of variable CO{sub 2}(g) pressure on Zn sorption and of PO{sub 4} on SeO{sub 3} sorption. The surface-exchange model, combined with sorption constants for other phases, was used to calculate Cd sorption to a hypothetical aquifer material containing a mixture of sorbents. The sorbent concentrations were fixed to those expected in groundwater zones. The multi-sorbent calculation documented the importance of calcite as a sorbent for metallic ions in groundwater.93 refs., 18 figs., 5 tabs.

Zachara, J.M.; Cowan, C.E.; Resch, C.T.

1990-05-01T23:59:59.000Z

243

Calculate viscosities for 355 liquids  

SciTech Connect (OSTI)

Liquid viscosities are important factors in process design and operation. The viscosity of a liquid determines its flow properties, such as velocity and pressure drop. In addition, the heat- and mass-transfer characteristics of a liquid are affected by its viscosity. An equation can be used to calculate liquid viscosities as a function of temperature. In the accompanying table, regression coefficients are included for 355 compounds with five, six or seven carbon atoms--generally the most-widely used in the chemical and petroleum industries. To calculate the viscosity of a liquid at any temperature between its melting and critical points (T[sub min] and T[sub max]), use the following equation: log[sub 10] [eta][sub liq] = A + B/T + CT + DT[sup 2] where [eta][sub liq] = viscosity, cP, A,B,C and D = regression coefficients, and T = liquid temperature, K. Insert the temperature into the equation along with the corresponding regression coefficients from the table. The chemical formulae are listed by the number of carbon atoms.

Yaws, C.L.; Lin, Xiaoyan; Li Bu (Lamar Univ., TX (United States))

1994-04-01T23:59:59.000Z

244

Adaptive Liquid Crystal Windows  

SciTech Connect (OSTI)

Energy consumption by private and commercial sectors in the U.S. has steadily grown over the last decade. The uncertainty in future availability of imported oil, on which the energy consumption relies strongly, resulted in a dramatic increase in the cost of energy. About 20% of this consumption are used to heat and cool houses and commercial buildings. To reduce dependence on the foreign oil and cut down emission of greenhouse gases, it is necessary to eliminate losses and reduce total energy consumption by buildings. To achieve this goal it is necessary to redefine the role of the conventional windows. At a minimum, windows should stop being a source for energy loss. Ideally, windows should become a source of energy, providing net gain to reduce energy used to heat and cool homes. It is possible to have a net energy gain from a window if its light transmission can be dynamically altered, ideally electronically without the need of operator assistance, providing optimal control of the solar gain that varies with season and climate in the U.S. In addition, the window must not require power from the building for operation. Resolution of this problem is a societal challenge and of national interest and will have a broad global impact. For this purpose, the year-round, allclimate window solution to provide an electronically variable solar heat gain coefficient (SHGC) with a wide dynamic range is needed. AlphaMicron, Inc. (AMI) developed and manufactured 1ft × 1ft prototype panels for the world’s first auto-adjusting Adaptive Liquid Crystal Windows (ALCWs) that can operate from sunlight without the need for external power source and demonstrate an electronically adjustable SHGC. This novel windows are based on AlphaMicron’s patented e-Tint® technology, a guesthost liquid crystal system implemented on flexible, optically clear plastic films. This technology is suitable both for OEM and aftermarket (retro-fitting) lamination to new and existing windows. Low level of power consumption by ALCWs allows for on-board power electronics for automatic matching of transmission through windows to varying climate conditions without drawing the power from the power grid. ALCWs are capable of transmitting more sunlight in winters to assist in heating and less sunlight in summers to minimize overheating. As such, they can change the window from being a source of energy loss to a source of energy gain. In addition, the scalable AMI’s roll-to-roll process, proved by making 1ft × 1ftALCW prototype panels, allows for cost-effective production of large-scale window panels along with capability to change easily their color and shape. In addition to architectural glazing in houses and commercial buildings, ALCWs can be used in other applications where control of sunlight is needed, such as green houses, used by commercial produce growers and botanical gardens, cars, aircrafts, etc.

Taheri, Bahman; Bodnar, Volodymyr

2011-12-31T23:59:59.000Z

245

PHASE CHANGE LIQUIDS  

SciTech Connect (OSTI)

Work is being performed to develop a new shipping system for frozen environmental samples (or other materials) that uses an optimal phase change liquid (PCL) formulation and an insulated shipping container with an on-board digital temperature data logger to provide a history of the temperature profile within the container during shipment. In previous work, several PCL formulations with temperatures of fusion ranging from approximately -14 to -20 C were prepared and evaluated. Both temperature of fusion and heat of fusion of the formulations were measured, and an optimal PCL formulation was selected. The PCL was frozen in plastic bags and tested for its temperature profile in a cooler using a digital temperature data logger. This testing showed that the PCL formulation can maintain freezer temperatures (< -7 to -20 C) for an extended period, such as the time for shipping samples by overnight courier. The results of the experiments described in this report provide significant information for use in developing an integrated freezer system that uses a PCL formulation to maintain freezer temperatures in coolers for shipping environmental samples to the laboratory. Experimental results show the importance of the type of cooler used in the system and that use of an insulating material within the cooler improves the performance of the freezer system. A new optimal PCL formulation for use in the system has been determined. The new formulation has been shown to maintain temperatures at < -7 to -20 C for 47 hours in an insulated cooler system containing soil samples. These results are very promising for developing the new technology.

Susan S. Sorini; John F. Schabron

2006-03-01T23:59:59.000Z

246

Extremely Correlated Fermi Liquids B. Sriram Shastry  

E-Print Network [OSTI]

Extremely Correlated Fermi Liquids B. Sriram Shastry Physics Department, University of California the theory of an extremely correlated Fermi liquid with U ! 1. This liquid has an underlying auxiliary Fermi liquid Green's function that is further caparisoned by extreme correlations. The theory leads to two

California at Santa Cruz, University of

247

Structural Consequences of Anionic Host-Cationic Guest Interactions in a Supramolecular Assembly  

SciTech Connect (OSTI)

The molecular structure of the self-assembled supramolecular assembly [M{sub 4}L{sub 6}]{sup 12-} has been explored with different metals (M = Ga{sup III}, Fe{sup III}, Ti{sup IV}) and different encapsulated guests (NEt{sub 4}{sup +}, BnNMe{sub 3}{sup +}, Cp{sub 2}Co{sup +}, Cp*{sub 2}Co{sup +}) by X-ray crystallography. While the identity of the metal ions at the vertices of the M{sub 4}L{sub 6} structure is found to have little effect on the assembly structure, encapsulated guests significantly distort the size and shape of the interior cavity of the assembly. Cations on the exterior of the assembly are found to interact with the assembly through either {pi}-{pi}, cation-{pi}, or CH-{pi} interactions. In some cases, the exterior guests interact with only one assembly, but cations with the ability to form multiple {pi}-{pi} interactions are able to interact with adjacent assemblies in the crystal lattice. The solvent accessible cavity of the assembly is modeled using the rolling probe method and found to range from 253-434 {angstrom}{sup 3}, depending on the encapsulated guest. Based on the volume of the guest and the volume of the cavity, the packing coefficient for each host-guest complex is found to range from 0.47-0.67.

Pluth, Michael D.; Johnson, Darren W.; Szigethy, Geza; Davis, Anna V.; Teat, Simon J.; Oliver, Allen G.; Bergman, Robert G.; Raymond, Kenneth N.

2008-07-09T23:59:59.000Z

248

Infrared spectroscopy of the acetyl cation and its protonated ketene isomer  

SciTech Connect (OSTI)

[C{sub 2},H{sub 3},O]{sup +} ions are generated with a pulsed discharge in a supersonic expansion containing methyl acetate or acetone. These ions are mass selected and their infrared spectra are recorded via laser photodissociation and the method of argon tagging. Computational chemistry is employed to investigate structural isomers and their spectra. The acetyl cation (CH{sub 3}CO{sup +}) is the global minimum and protonated ketene (CH{sub 2}COH{sup +}) is the next lowest energy isomer (+176.2 kJ/mol). When methyl acetate is employed as the precursor, the infrared spectrum reveals that only the acetyl cation is formed. Partially resolved rotational structure reveals rotation about the C{sub 3} axis. When acetone is used as the precursor, acetyl is still the most abundant cation, but there is also a minor component of protonated ketene. Computations reveal a significant barrier to interconversion between the two isomers (+221 kJ/mol), indicating that protonated ketene must be obtained via kinetic trapping. Both isomers may be present in interstellar environments, and their implications for astrochemistry are discussed.

Mosley, J. D.; Young, J. W.; Duncan, M. A. [Department of Chemistry, University of Georgia, Athens, Georgia 30602 (United States)

2014-07-14T23:59:59.000Z

249

Commercialization of Coal-to-Liquids Technology  

SciTech Connect (OSTI)

The report provides an overview of the current status of coal-to-liquids (CTL) commercialization efforts, including an analysis of efforts to develop and implement large-scale, commercial coal-to-liquids projects to create transportation fuels. Topics covered include: an overview of the history of coal usage and the current market for coal; a detailed description of what coal-to-liquids technology is; the history of coal-to-liquids development and commercial application; an analysis of the key business factors that are driving the increased interest in coal-to-liquids; an analysis of the issues and challenges that are hindering the commercialization of coal-to-liquids technology; a review of available coal-to-liquids technology; a discussion of the economic drivers of coal-to-liquids project success; profiles of key coal-to-liquids developers; and profiles of key coal-to-liquids projects under development.

NONE

2007-08-15T23:59:59.000Z

250

Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points  

E-Print Network [OSTI]

. INTRODUCTION Water is characterized by well-known thermodynamic and kinetic liquid-state anomalies; for examplePREPRINT Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points Evy simulations are used to examine the relationship between water-like anoma- lies and the liquid-liquid critical

Barbosa, Marcia C. B.

251

Nanophosphor composite scintillator with a liquid matrix  

DOE Patents [OSTI]

An improved nanophosphor scintillator liquid comprises nanophosphor particles in a liquid matrix. The nanophosphor particles are optionally surface modified with an organic ligand. The surface modified nanophosphor particle is essentially surface charge neutral, thereby preventing agglomeration of the nanophosphor particles during dispersion in a liquid scintillator matrix. The improved nanophosphor scintillator liquid may be used in any conventional liquid scintillator application, including in a radiation detector.

McKigney, Edward Allen (Los Alamos, NM); Burrell, Anthony Keiran (Los Alamos, NM); Bennett, Bryan L. (Los Alamos, NM); Cooke, David Wayne (Santa Fe, NM); Ott, Kevin Curtis (Los Alamos, NM); Bacrania, Minesh Kantilal (Los Alamos, NM); Del Sesto, Rico Emilio (Los Alamos, NM); Gilbertson, Robert David (Los Alamos, NM); Muenchausen, Ross Edward (Los Alamos, NM); McCleskey, Thomas Mark (Los Alamos, NM)

2010-03-16T23:59:59.000Z

252

Use of MgO doped with a divalent or trivalent metal cation for removing arsenic from water  

DOE Patents [OSTI]

Systems and methods for use of magnesium hydroxide, either directly or through one or more precursors, doped with a divalent or trivalent metal cation, for removing arsenic from drinking water, including water distribution systems. In one embodiment, magnesium hydroxide, Mg(OH).sub.2 (a strong adsorbent for arsenic) doped with a divalent or trivalent metal cation is used to adsorb arsenic. The complex consisting of arsenic adsorbed on Mg(OH).sub.2 doped with a divalent or trivalent metal cation is subsequently removed from the water by conventional means, including filtration, settling, skimming, vortexing, centrifugation, magnetic separation, or other well-known separation systems. In another embodiment, magnesium oxide, MgO, is employed, which reacts with water to form Mg(OH).sub.2. The resulting Mg(OH).sub.2 doped with a divalent or trivalent metal cation, then adsorbs arsenic, as set forth above. The method can also be used to treat human or animal poisoning with arsenic.

Moore, Robert C; Holt-Larese, Kathleen C; Bontchev, Ranko

2013-08-13T23:59:59.000Z

253

Relating the Expression of Soil Redoximorphic Features to Soil Texture, pH, and Cation Exchange Capacity  

E-Print Network [OSTI]

Three laboratory studies were performed to elucidate the influence of soil texture, pH, and cation exchange capacity (CEC) on the concentration of ferrous Fe in soil solution and the resulting expression of soil redoximorphic features...

Mersmann, Ryan S.

2010-01-14T23:59:59.000Z

254

Gas-phase energies of actinide oxides -- an assessment of neutral and cationic monoxides and dioxides from thorium to curium  

SciTech Connect (OSTI)

An assessment of the gas-phase energetics of neutral and singly and doubly charged cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium, plutonium, americium, and curium is presented. A consistent set of metal-oxygen bond dissociation enthalpies, ionization energies, and enthalpies of formation, including new or revised values, is proposed, mainly based on recent experimental data and on correlations with the electronic energetics of the atoms or cations and with condensed-phase thermochemistry.

Marcalo, Joaquim; Gibson, John K.

2009-08-10T23:59:59.000Z

255

Liquid-phase chromatography detector  

DOE Patents [OSTI]

A liquid-phase chromatography detector comprises a flow cell having an inlet tubular conduit for receiving a liquid chromatographic effluent and discharging it as a flowing columnar stream onto a vertically adjustable receiving surface spaced apart from and located vertically below and in close proximity to the discharge end of the tubular conduit; a receiver adapted to receive liquid overflowing from the receiving surface; an exit conduit for continuously removing liquid from the receiver; a light source for focusing fluorescence-producing light pulses on the flowing columnar stream as it passes from the outlet of the conduit to the receiving surface and a fluorescence detector to detect the produced fluorescence; a source of light pulse for producing acoustic waves in the columnar stream as it passes from the conduit outlet to the receiving surface; and a piezoelectric transducer adapted to detect those waves; and a source of bias voltage applied to the inlet tubular conduit and adapted to produce ionization of the liquid flowing through the flow cell so as to produce photocurrents therein and an electrical system to detect and record the photocurrents. This system is useful in separating and detecting individual chemical compounds from mixtures thereof. 5 figs.

Voigtman, E.G.; Winefordner, J.D.; Jurgensen, A.R.

1983-11-08T23:59:59.000Z

256

Fragmentation of suddenly heated liquids  

SciTech Connect (OSTI)

Fragmentation of free liquids in Inertial Confinement Fusion reactors could determine the upper bound on reactor pulse rate. The x-ray ablated materials must cool and recondense to allow driver beam propagation. The increased surface area caused by fragmentation will enhance the cooling and condensation rates. Relaxation from the suddenly heated state will move a liquid into the negative pressure region under the liquid-vapor P-V dome. The lithium equation of state was used to demonstrate that neutron-induced vaporization uses only a minor fraction of the added heat, much less than would be required to drive the expansion. A 77% expansion of the lithium is required before the rapid vaporization process of spinodal decomposition could begin, and nucleation and growth are too slow to contribute to the expansion.

Blink, J.A.

1985-03-01T23:59:59.000Z

257

Liquid soap film generates electricity  

E-Print Network [OSTI]

We have observed that a rotating liquid soap film generates electricity when placed between two non-contact electrodes with a sufficiently large potential difference. In our experiments suspended liquid film (water + soap film) is formed on the surface of a circular frame, which is forced to rotate in the $x-y$ horizontal plane by a motor. This system is located at the center of two capacitor-like vertical plates to apply an external electric voltage difference in the $x-$direction. The produced electric current is collected from the liquid film using two conducting electrodes that are separated in the $y-$direction. We previously reported that a liquid film in an external electric field rotates when an electric current passes through it, naming it the liquid film motor (LFM). In this paper we report a novel technique, in which a similar device can be used as an electric generator, converting the rotating mechanical energy to electrical energy. The liquid film electric generator (LFEG) is in stark contrast to the LFM, both of which could be designed similarly in very small scales like micro scales with different applications. Although the device is comparable to commercial electric motors or electric generators, there is a significant difference in their working principles. Usually in an electric motor or generator the magnetic field causes the driving force, while in a LFM or LFEG the Coulomb force is the driving force. This fact is also interesting from the Bio-science point of view and brings a similarity to bio motors. Here we have investigated the electrical characteristics of such a generator for the first time experimentally and modelled the phenomenon with electroconvection governing equations. A numerical simulation is performed using the local approximation for the charge-potential relation and results are in qualitative agreement with experiments.

Ahmad Amjadi; Sadegh Feiz; Reza Montazeri Namin

2014-04-24T23:59:59.000Z

258

Method of measuring a liquid pool volume  

DOE Patents [OSTI]

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools is disclosed, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figures.

Garcia, G.V.; Carlson, N.M.; Donaldson, A.D.

1991-03-19T23:59:59.000Z

259

Complex Capacitance Scaling in Ionic Liquids-Filled Nanopores  

SciTech Connect (OSTI)

Recent experiments have shown that the capacitance of subnanometer pores increases anomalously as the pore width decreases, thereby opening a new avenue for developing supercapacitors with enhanced energy density. However, this behavior is still subject to some controversy since its physical origins are not well understood. Using atomistic simulations, we show that the capacitance of slit-shaped nanopores in contact with room-temperature ionic liquids exhibits a U-shaped scaling behavior in pores with widths from 0.75 to 1.26 nm. The left branch of the capacitance scaling curve directly corresponds to the anomalous capacitance increase and thus reproduces the experimental observations. The right branch of the curve indirectly agrees with experimental findings that so far have received little attention. The overall U-shaped scaling behavior provides insights on the origins of the difficulty in experimentally observing the pore-width-dependent capacitance. We establish a theoretical framework for understanding the capacitance of electrical double layers in nanopores and provide mechanistic details into the origins of the observed scaling behavior. The framework highlights the critical role of 'ion solvation' in controlling pore capacitance and the importance of choosing anion/cation couples carefully for optimal energy storage in a given pore system.

Sumpter, Bobby G [ORNL

2011-01-01T23:59:59.000Z

260

Complex Capacitance Scaling in Ionic Liquids-filled Nanopores  

SciTech Connect (OSTI)

Recent experiments have shown that the capacitance of sub-nanometer pores increases anomalously as the pore width decreases, thereby opening a new avenue for developing supercapacitors with enhanced energy density. However, this behavior is still subject to some controversy since its physical origins are not well understood. Using atomistic simulations, we show that the capacitance of slit-shaped nanopores in contact with room-temperature ionic liquids exhibits a U-shaped scaling behavior in pores with width from 0.75 to 1.26 nm. The left branch of the capacitance scaling curve directly corresponds to the anomalous capacitance increase and thus reproduces the experimental observations. The right branch of the curve indirectly agrees with experimental findings that so far have received little attention. The overall U-shaped scaling behavior provides insights on the origins of the difficulty in experimentally observing the pore-width dependent capacitance. We establish a theoretical framework for understanding the capacitance of electrical double layers in nanopores and provide mechanistic details into the origins of the observed scaling behavior. The framework highlights the critical role of ion solvation in controlling pore capacitance and the importance of choosing anion/cation couples carefully for optimal energy storage in a given pore system.

Qiao, Rui [Clemson University; Huang, Jingsong [ORNL; Meunier, Vincent [ORNL; Sumpter, Bobby G [ORNL; Peng, Wu [Clemson University

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

An XAFS Study of Nickel Chloride in the Ionic Liquid 1-ethyl-3-methyl Imidazolium Chloride/ Aluminum Chloride  

SciTech Connect (OSTI)

The electrodeposition of metals from aqueous solutions has a successful history for many metals. However, some metals cannot be deposited from aqueous solutions because their potentials fall outside of the window of stability for water. Using ionic liquids for the electrodeposition of metals can avoid some of these difficulties because they have a larger region of stability than water. The electrochemical window can be tailored to fit a particular application by choosing appropriate anions and cations to form the melt. There is also the possibility to deposit pure metals without the oxides and hydrides that can form in aqueous solutions. The study of the structure of metal salts in ionic liquids is an important step towards achieving these goals.

Roeper, D.; Cheek, G; Pandya, K; O'Gragy, W

2008-01-01T23:59:59.000Z

262

The cation inversion and magnetization in nanopowder zinc ferrite obtained by soft mechanochemical processing  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Nano powder of ZnFe{sub 2}O{sub 4} prepared by a soft mechanochemical route after 18 h milling. • Phase formation controlled by XRD, Raman spectroscopy and magnetic measurements. • Size, strain and cation inversion degree determined by Rietveld refinement. • We were able to estimate the degree of inversion at most 0.348 and 0.4. • Obtained extremely high values of saturation magnetizations at T = 4.5 K. - Abstract: Two zinc ferrite nanoparticle materials were prepared by the same method – soft mechanochemical synthesis, but starting from different powder mixtures: (1) Zn(OH){sub 2}/?-Fe{sub 2}O{sub 3} and (2) Zn(OH){sub 2}/Fe(OH){sub 3}. In both cases a single phase system was obtained after 18 h of milling. The progress of the synthesis was controlled by X-ray diffractometry (XRD), Raman spectroscopy, TEM and magnetic measurements. Analysis of the XRD patterns by Rietveld refinement allowed determination of the cation inversion degree for both obtained single phase ZnFe{sub 2}O{sub 4} samples. The sample obtained from mixture (1) has the cation inversion degree 0.3482 and the sample obtained from mixture (2) 0.400. Magnetization measurements were confirmed that the degrees of the inversion were well estimated. Comparison with published data shows that used method of synthesis gives nano powder samples with extremely high values of saturation magnetizations: sample (1) 78.3 emu g{sup ?1} and sample (2) 91.5 emu g{sup ?1} at T = 4.5 K.

Milutinovi?, A. [Institute of Physics, University of Belgrade, Pregrevica 118, Zemun, Belgrade (Serbia); Lazarevi?, Z., E-mail: lzorica@yahoo.com [Institute of Physics, University of Belgrade, Pregrevica 118, Zemun, Belgrade (Serbia); Jovaleki?, ?. [Institute for Multidisciplinary Research, University of Belgrade, Belgrade (Serbia); Kuryliszyn-Kudelska, I. [Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668 Warsaw (Poland); Rom?evi?, M.; Kosti?, S.; Rom?evi?, N. [Institute of Physics, University of Belgrade, Pregrevica 118, Zemun, Belgrade (Serbia)

2013-11-15T23:59:59.000Z

263

Cation-Bonding and Protonation of the Fe[subscript 4]-Square Cluster  

SciTech Connect (OSTI)

The synthesis and characterization of discrete, molecular iron-oxo clusters is pursued in the interest of molecular magnets, bioinspired materials and models for the geochemical aqueous-mineral interface. Iron-oxo clusters are challenging to synthesize in water, due to the extremely acidic and reactive nature of dissolved iron species, and thus require chelating ligands to passivate and neutralize the cluster surface. The 2-hydroxy-1,3-N,N,N',N'-diamino-propanetetraacetic acid (HPDTA) ligand has been used to isolate several Al and Fe cluster geometries, including the square clusters Fe{sub 4}(HPDTA){sub 2} and Al{sub 4}(HPDTA){sub 2}. While prior reports on the Fe{sub 4}(HPDTA){sub 2} cluster have focused on the magnetic properties, no solution characterization has been carried out. Using electrospray ionization mass-spectrometry (ESI-MS) we show this anionic Fe{sub 4}(HPDTA){sub 2} cluster can be dissolved intact in water, and recrystallized with virtually any metal as a countercation. The bonding of the metal cation to the square face of the cluster trends with ionic radii of the cations, as shown by structural characterization of Fe{sub 4}(HPDTA){sub 2} with Li{sup +}, Na{sup +}, Cs{sup +}, Mg{sup 2+}, Ba{sup 2+}, La{sup 3+}, Eu{sup 3+}, and Zn{sup 2+}. This trend is similar to that observed for association of cations on metal oxide surfaces in the environment. Furthermore, protonation of the bridging oxo ligands of this series of Fe{sub 4}(HPDTA){sub 2} clusters is variable (0, 1, or 2 protons), and structures as a function of protonation is discussed. This paper, largely structural in nature, sets the foundation for future aqueous phase studies of iron-oxo molecular clusters as models for the oxide-water interface in the natural aqueous environment.

Hou, Yu; Rodriguez, Mark A.; Nyman, May (Sandia)

2012-04-30T23:59:59.000Z

264

THERMODYNAMICS OF SOLID AND LIQUID GROUP III-V ALLOYS  

E-Print Network [OSTI]

a high temperature heat capacity for liquid gallium which isthe molar heat capacity of the stoichiometric liquid and theheat capacity of the supercooled stoichiometric binary liquid

Anderson, T.J.

2011-01-01T23:59:59.000Z

265

Retention of anhydrous ammonia as influenced by clay mineral types, cations, temperature and moisture  

E-Print Network [OSTI]

to various temperature levels . . . . . ~ 20 5a 6. 70 Ammoni. a retained sxuressed as psr cent of cation-exchange capacity for olays treated with anhydrous ammonia prior to heating to various temperature levels . ~. . . . . . ~ ~ . 21 Ammonia retained... encountered in the use of anhydrous ammoni. . . REVIEW OF LITER4TURE Some of the early work with anhydx ous ammonia was done by anderson, et al. (2), and Enderson and Eattson (3). St that t1ms anhydrous ammonia as sn inorganic source of nitrogen fertiliaer...

McBee, George G

1956-01-01T23:59:59.000Z

266

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wongchang

2014-05-13T23:59:59.000Z

267

Stiffening solids with liquid inclusions  

E-Print Network [OSTI]

From bone and wood to concrete and carbon fibre, composites are ubiquitous natural and engineering materials. Eshelby's inclusion theory describes how macroscopic stress fields couple to isolated microscopic inclusions, allowing prediction of a composite's bulk mechanical properties from a knowledge of its microstructure. It has been extended to describe a wide variety of phenomena from solid fracture to cell adhesion. Here, we show experimentally and theoretically that Eshelby's theory breaks down for small liquid inclusions in a soft solid. In this limit, an isolated droplet's deformation is strongly size-dependent with the smallest droplets mimicking the behaviour of solid inclusions. Furthermore, in opposition to the predictions of conventional composite theory, we find that finite concentrations of small liquid inclusions enhance the stiffness of soft solids. A straight-forward extension of Eshelby's theory, accounting for the surface tension of the solid-liquid interface, explains our experimental observations. The counterintuitive effect of liquid-stiffening of solids is expected whenever droplet radii are smaller than an elastocapillary length, given by the ratio of the surface tension to Young's modulus of the solid matrix.

Robert W. Style; Rostislav Boltyanskiy; Benjamin Allen; Katharine E. Jensen; Henry P. Foote; John S. Wettlaufer; Eric R. Dufresne

2014-07-24T23:59:59.000Z

268

MUSHROOM WASTE MANAGEMENT PROJECT LIQUID WASTE MANAGEMENT  

E-Print Network [OSTI]

of solid and liquid wastes generated at mushroom producing facilities. Environmental guidelines#12;MUSHROOM WASTE MANAGEMENT PROJECT LIQUID WASTE MANAGEMENT PHASE I: AUDIT OF CURRENT PRACTICE The Mushroom Waste Management Project (MWMP) was initiated by Environment Canada, the BC Ministry

269

Nanopatterned anchoring layers for liquid crystals  

E-Print Network [OSTI]

This thesis describes the theory and fabrication of inhomogeneous Liquid Crystal anchoring layers. While chemical anchoring techniques have proved useful for many applications, especially Liquid Crystal Displays, they have ...

Gear, Christopher S. (Christopher Stanwood)

2014-01-01T23:59:59.000Z

270

Can hedge funds time market liquidity?  

E-Print Network [OSTI]

We explore a new dimension of fund managers' timing ability by examining whether they can time market liquidity through adjusting their portfolios' market exposure as aggregate liquidity conditions change. Using a large ...

Cao, Charles

271

Mixing in a liquid metal electrode  

E-Print Network [OSTI]

Fluid mixing has first-order importance for many engineering problems in mass transport, including design and optimization of liquid-phase energy storage devices. Liquid metal batteries are currently being commercialized ...

Kelley, Douglas H.

272

Ionic Liquids for Utilization of Geothermal Energy  

Broader source: Energy.gov [DOE]

DOE Geothermal Program Peer Review 2010 - Presentation. Project objective: to develop ionic liquids for two geothermal energy related applications.

273

Heterophase liquid states: Thermodynamics, structure, dynamics  

E-Print Network [OSTI]

An overview of theoretical results and experimental data on the thermodynamics, structure and dynamics of the heterophase glass-forming liquids is presented. The theoretical approach is based on the mesoscopic heterophase fluctuations model (HPFM) developed within the framework of the bounded partition function approach. The Fischer cluster phenomenon, glass transition, liquid-liquid transformations, parametric phase diagram, cooperative dynamics and fragility of the glass-forming liquids is considered.

A. S. Bakai

2015-01-12T23:59:59.000Z

274

Nanoparticle enhanced ionic liquid heat transfer fluids  

DOE Patents [OSTI]

A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.

Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

2014-08-12T23:59:59.000Z

275

Cooperative motions in supercooled liquids and glasses  

E-Print Network [OSTI]

P. Heat capacity and entropy of an equilibrium liquid fromliquids should correlate inversely with the con?gurational heat capacity,

Stevenson, Jacob D.

2009-01-01T23:59:59.000Z

276

Diffusion of cations in chromia layers grown on iron-base alloys  

SciTech Connect (OSTI)

Diffusion of the cations Cr, Fe, Mn, and Ni in Cr{sub 2}O{sub 3} has been investigated at 1,173 K. The diffusion measurements were performed on chromia layers grown on the model alloys Fe-20Cr and Fe-20Cr-12Ni in order to consider effects of small amounts of dissolved alien cations in Cr{sub 2}O{sub 3}. The samples were diffusion annealed in H{sub 2}-H{sub 2}O at an oxygen partial pressure close to the Cr{sub 2}O{sub 3}/Cr equilibrium. For all tracers the lattice-diffusion coefficients are 3-5 orders of magnitude smaller than the grain-boundary diffusion coefficients. The lattice diffusivity of Mn is about two orders of magnitude greater than the other lattice-diffusion coefficients, especially in Cr{sub 2}O{sub 3} grown on Fe-20Cr-12Ni. The values of the diffusion coefficients for Cr, Fe, and Ni are in the same range. Diffusion of the tracers in Cr{sub 2}O{sub 3} grown on different alloys did not show significant differences with the exception of Mn.

Lobnig, R.E.; Hennesen, K.; Grabke, H.J. (Max-Planck Inst. fur Eisenforschung, Duesseldorf (West Germany)); Schmidt, H.P.

1992-02-01T23:59:59.000Z

277

Modeling cation diffusion in compacted water-saturatedNa-bentonite at low ionic strength  

SciTech Connect (OSTI)

Sodium bentonites are used as barrier materials for the isolation of landfills and are under consideration for a similar use in the subsurface storage of high-level radioactive waste. The performance of these barriers is determined in large part by molecular diffusion in the bentonite pore space. We tested two current models of cation diffusion in bentonite against experimental data on the relative apparent diffusion coefficients of two representative cations, sodium and strontium. On the 'macropore/nanopore' model, solute molecules are divided into two categories, with unequal pore-scale diffusion coefficients, based on location: in macropores or in interlayer nanopores. On the 'surface diffusion' model, solute molecules are divided into categories based on chemical speciation: dissolved or adsorbed. The macropore/nanopore model agrees with all experimental data at partial montmorillonite dry densities ranging from 0.2 (a dilute bentonite gel) to 1.7 kg dm{sup -3} (a highly compacted bentonite with most of its pore space located in interlayer nanopores), whereas the surface diffusion model fails at partial montmorillonite dry densities greater than about 1.2 kg dm{sup -3}.

Bourg, Ian C.; Sposito, Garrison; Bourg, Alain C.M.

2007-08-28T23:59:59.000Z

278

Ionic Liquid and Supercritical Fluid Hyphenated Techniques for Dissolution and Separation of Lanthanides, Actinides, and Fission Products  

SciTech Connect (OSTI)

This project is investigating techniques involving ionic liquids (IL) and supercritical (SC) fluids for dissolution and separation of lanthanides, actinides, and fission products. The research project consists of the following tasks: Study direct dissolution of lanthanide oxides, uranium dioxide and other actinide oxides in [bmin][Tf{sub 2}N] with TBP(HNO{sub 3}){sub 1.8}(H{sub 2}O){sub 0.6} and similar types of Lewis acid-Lewis base complexing agents; Measure distributions of dissolved metal species between the IL and the sc-CO{sub 2} phases under various temperature and pressure conditions; Investigate the chemistry of the dissolved metal species in both IL and sc-CO{sub 2} phases using spectroscopic and chemical methods; Evaluate potential applications of the new extraction techniques for nuclear waste management and for other projects. Supercritical carbon dioxide (sc-CO{sub 2}) and ionic liquids are considered green solvents for chemical reactions and separations. Above the critical point, CO{sub 2} has both gas- and liquid-like properties, making it capable of penetrating small pores of solids and dissolving organic compounds in the solid matrix. One application of sc-CO{sub 2} extraction technology is nuclear waste management. Ionic liquids are low-melting salts composed of an organic cation and an anion of various forms, with unique properties making them attractive replacements for the volatile organic solvents traditionally used in liquid-liquid extraction processes. One type of room temperature ionic liquid (RTIL) based on the 1-alkyl-3-methylimidazolium cation [bmin] with bis(trifluoromethylsulfonyl)imide anion [Tf{sub 2}N] is of particular interest for extraction of metal ions due to its water stability, relative low viscosity, high conductivity, and good electrochemical and thermal stability. Recent studies indicate that a coupled IL sc-CO{sub 2} extraction system can effectively transfer trivalent lanthanide and uranyl ions from nitric acid solutions. Advantages of this technique include operation at ambient temperature and pressure, selective extraction due to tunable sc-CO{sub 2} solvation strength, no IL loss during back-extraction, and no organic solvent introduced into the IL phase.

Wai, Chien M. [Univ. of Idaho, Moscow, ID (United States); Bruce Mincher

2012-12-01T23:59:59.000Z

279

Apparatus and method for spraying liquid materials  

DOE Patents [OSTI]

A method for spraying liquids involving a flow of gas which shears the liquid. A flow of gas is introduced in a converging-diverging nozzle where it meets and shears the liquid into small particles which are of a size and uniformity which can be controlled through adjustment of pressures and gas velocity. 5 figs.

Alvarez, J.L.; Watson, L.D.

1988-01-21T23:59:59.000Z

280

Commercialization of coal to liquids technology  

SciTech Connect (OSTI)

After an overview of the coal market, technologies for producing liquids from coal are outlined. Commercialisation of coal-to-liquid fuels, the economics of coal-to-liquids development and the role of the government are discussed. Profiles of 8 key players and the profiles of 14 projects are finally given. 17 figs., 8 tabs.

NONE

2007-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Liquid Transportation Fuels from Coal and Biomass  

E-Print Network [OSTI]

Liquid Transportation Fuels from Coal and Biomass Technological Status, Costs, and Environmental Katzer #12;CHARGE TO THE ALTF PANEL · Evaluate technologies for converting biomass and coal to liquid for liquid fuels produced from coal or biomass. · Evaluate environmental, economic, policy, and social

282

Response functions near the liquid-liquid critical point of ST2 water  

E-Print Network [OSTI]

speci¿c heat capacity CP and the isothermal compressibility KT . We use two different methods: (i) fromResponse functions near the liquid-liquid critical point of ST2 water Erik Lascaris , T. A, and for four different system sizes, N = 63, 73, 83, and 93. We locate the liquid-liquid phase transition line

Stanley, H. Eugene

283

Erasing no-man's land by thermodynamically stabilizing the liquid-liquid transition in tetrahedral particles  

E-Print Network [OSTI]

compressibility KT and the isobaric heat capacity CP . In the LLCP hypothesis, the density anomalies of waterErasing no-man's land by thermodynamically stabilizing the liquid-liquid transition in tetrahedral, Sapienza, Universit´a di Roma, Piazzale Aldo Moro 2, I-00185, Roma, Italy. EFFECTS OF THE LIQUID-LIQUID

Loss, Daniel

284

Liquid/Liquid Interface Polymerized Porphyrin Membranes Displaying Size-Selective Molecular and Ionic Permeability  

E-Print Network [OSTI]

Liquid/Liquid Interface Polymerized Porphyrin Membranes Displaying Size-Selective Molecular: December 5, 2005 Thin polymeric membranes have been formed by liquid/liquid interfacial copolymerization of controllable thickness to be obtained.7 The polymerization of 1 was accomplished by condensation of porphyrin

285

Computation of liquid-liquid equilibrium in multicomponent electrolyte systems  

SciTech Connect (OSTI)

A computational algorithm for predicting liquid-liquid equilibrium (LLE) data, based on a generalization of the maximum likelihood method applied to implicit constraints, is presented. The algorithm accepts multicomponent data and binary interaction parameters. A comparative study of the models NRTL and electrolyte-NRTL, used for estimating activity coefficients in a quaternary electrolyte system, is presented and discussed. Results show that both models give accurate predictions and the algorithm presents a good performance without convergence or initialization problems. This suggests that the basic NRTL model can be used for describing phase behavior in weak electrolyte systems and the procedure can be of great use for design and optimization of processes involving multicomponent electrolyte systems. 9 refs., 1 fig., 1 tab.

Vianna, R.F.; d`Avila, S.G. [Universidade Estadual de Campinas (Brazil)

1996-12-31T23:59:59.000Z

286

Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass  

SciTech Connect (OSTI)

Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogenous catalyst for gasification.

Elliott, Douglas C; Oyler, James

2013-12-17T23:59:59.000Z

287

Methods for sulfate removal in liquid-phase catalytic hydrothermal gasification of biomass  

SciTech Connect (OSTI)

Processing of wet biomass feedstock by liquid-phase catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a pre-treatment temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent removal of soluble sulfate contaminants, or combinations thereof. Processing further includes reacting the soluble sulfate contaminants with cations present in the feedstock material to yield a sulfate-containing precipitate and separating the inorganic precipitates and/or the sulfate-containing precipitates out of the wet feedstock. Having removed much of the inorganic wastes and the sulfate contaminants that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

Elliott, Douglas C; Oyler, James R

2014-11-04T23:59:59.000Z

288

An infrared spectroscopy study of carbon monoxide adsorption on. alpha. -chromia surfaces: Probing oxidation states of coordinatively unsaturated surface cations  

SciTech Connect (OSTI)

CO adsorption on thermoevacuated, H{sub 2}-reduced and O{sub 2}-treated {alpha}-chromia surfaces was studied by IR spectroscopy in the temperature range 77-298 K. Coordinatively unsaturated (cus) Cr{sup 3+} cation sites, probably in 3-coordinate and to a much lesser extent 5-coordinate states, are the adsorption sites on H{sub 2}-reduced {alpha}-Cr{sub 2}O{sub 3}. The surface containing excess oxygen also exposes cus Cr{sup 4+} and Cr{sup 5+} sites. An empirical procedure is described which permits the determination of oxidation state and coordination number of the cus surface sites. This procedure is based on a correlation between C-O stretching frequency and electric field strength exerted by the cation. The latter is calculated from Pauling's strength of the electrostatic bond and effective ionic radii, both of which take the cation coordination into account.

Zaki, M.I.; Knoezinger, H. (Universitaet Muenchen (West Germany))

1989-10-01T23:59:59.000Z

289

Alien liquid detector and control  

SciTech Connect (OSTI)

An alien liquid detector employs a monitoring element and an energizing circuit for maintaining the temperature of the monitoring element substantially above ambient temperature. For this purpose an electronic circit controls a flow of heating current to the monitoring element. The presence of an alien liquid is detected by sensing a predetermined change in heating current flow to the monitoring element, e.g., to distinguish between water and oil. In preferred embodiments the monitoring element is a thermistor whose resistance is compared with a reference resistance and heating current through the thermistor is controlled in accordance with the difference. In one embodiment a bridge circuit senses the resistance difference; the difference may be sensed by an operational amplifier arrangement. Features of the invention include positioning the monitoring element at the surface of water, slightly immersed, so that the power required to maintain the thermistor temperature substantially above ambient temperature serves to detect presence of oil pollution at the surface.

Potter, B.M.

1980-09-02T23:59:59.000Z

290

Catalyst for hydrotreating carbonaceous liquids  

DOE Patents [OSTI]

A catalyst for denitrogenating and desulfurating carbonaceous liquid such as solvent refined coal includes catalytic metal oxides impregnated within a porous base of mostly alumina with relatively large pore diameters, surface area and pore volume. The base material includes pore volumes of 0.7-0.85 ml/g, surface areas of 200-350 m.sup.2 /g and pore diameters of 85-200 Angstroms. The catalytic metals impregnated into these base materials include the oxides of Group VI metals, molybdenum and tungsten, and the oxides of Group VIII metals, nickel and cobalt, in various combinations. These catalysts and bases in combination have effectively promoted the removal of chemically combined sulfur and nitrogen within a continuous flowing mixture of carbonaceous liquid and hydrogen gas.

Berg, Lloyd (Bozeman, MT); McCandless, Frank P. (Bozeman, MT); Ramer, Ronald J. (Idaho Falls, ID)

1982-01-01T23:59:59.000Z

291

Membrane Separations of Liquid Mixtures  

E-Print Network [OSTI]

MEMBRANE SEPARATIONS OF LIQUID MIXTURES Douglas R. Lloyd Separations Research Program Department of Chemical Engineering The University of Texas at Austin Austin, Texas In recent years considerable attention has been given to the need... for reduced energy costs in the chemical processing industry. A major portion of the energy consumed in this industry is associated with the separation and recovery of chemicals. Membrane processes offer energy-efficient, cost effective methods...

Lloyd, D. R.

292

Plasma-Surface Interactions on Liquids  

SciTech Connect (OSTI)

Liquid plasma-facing surfaces have been suggested as an option for advanced fusion devices, particularly in regions where solid materials may not survive over long operating periods. Because liquid surfaces can be replenished, they offer the possibility of tolerating intense particle bombardment and of recovering from off-normal events. As a preliminary step in understanding the nature of plasma-surface interactions on liquids, the authors consider some of the surface processes occurring in liquids undergoing irradiation by energetic particles. These include (1) sputtering, (2) segregation of liquid component species and impurities, (3) evaporation, and (4) trapping and release of incident particles. Aspects of these processes are examined for several candidate liquids, which represent three types of low-Z liquids: pure metals (Li), metallic alloys (Sn-Li), and compound insulators (Li{sub 2}BeF{sub 4}).

R. Bastasz; W. Eckstein

2000-05-01T23:59:59.000Z

293

Pysico-chemical properties of hydrophobic ionic liquids containing 1-octylpyridinium, 1-octyl-2-methylpyridinium or 1-octyl-4-methylpyridinium cations  

E-Print Network [OSTI]

respectively, in acetonitrile at 70 °C. All syntheses werepurity), and 50 mL acetonitrile. After cooling to room98 % purity), and 25 mL acetonitrile. After cooling to room

Papaiconomou, Nicolas; Salminen, Justin; Lee, Jong-Min; Prausnitz, John M.

2006-01-01T23:59:59.000Z

294

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wonchang

2010-05-18T23:59:59.000Z

295

Phenolic cation-exchange resin material for recovery of cesium and strontium. [Patent application  

DOE Patents [OSTI]

A phenolic cation exchange resin with a chelating group has been prepared by reacting resorcinol with iminodiacetic acid in the presence of formaldehyde at a molar ratio of about 1:1:6. The material is highly selective for the simultaneous recovery of both cesium and strontium from aqueous alkaline solutions, such as, aqueous alkaline nuclear wate solutions. The organic resins are condensation polymers of resorcinol and formaldehyde with attached chelating groups. The column performance of the resins compares favorably with that of commercially available resins for either cesium or strontium removal. By combining Cs/sup +/ and Sr/sup 2 +/ removal in the same bed, the resins allow significant reduction of the size and complexity of facilities for processing nuclear waste.

Ebra, M.A.; Wallace, R.M.

1982-05-05T23:59:59.000Z

296

Phenolic cation exchange resin material for recovery of cesium and strontium  

DOE Patents [OSTI]

A phenolic cation exchange resin with a chelating group has been prepared by reacting resorcinol with iminodiacetic acid in the presence of formaldehyde at a molar ratio of about 1:1:6. The material is highly selective for the simultaneous recovery of both cesium and strontium from aqueous alkaline solutions, such as, aqueous alkaline nuclear waste solutions. The organic resins are condensation polymers of resorcinol and formaldehyde with attached chelating groups. The column performance of the resins compares favorably with that of commercially available resins for either cesium or strontium removal. By combining Cs.sup.+ and Sr.sup.2+ removal in the same bed, the resins allow significant reduction of the size and complexity of facilities for processing nuclear waste.

Ebra, Martha A. (Aiken, SC); Wallace, Richard M. (Aiken, SC)

1983-01-01T23:59:59.000Z

297

Cationic quaternization of cellulose with methacryloyloxy ethyl trimethyl ammonium chloride via ATRP method  

SciTech Connect (OSTI)

The synthesis of a cationic cellulose copolymer from cellulose macro-initiator (MCC-BiB) and quaternary compound monomer (METMA) via atom transfer radical polymerization (ATRP) was studied. By using dimethylformamide (DMF), the optimum condition for successful synthesis was at the mole ratio of MCC-BIB:Catalyst:METMA = 1:1:26. The highest copolymer recovery was 93.2 % for 6 h and at 40°C. The copolymer was insoluble in weak polar solvents such as THF and DMF but soluble in methanol and water. The chemistry of cellulose copolymer was confirmed by the FTIR and TGA in which the METMA monomer was used as a reference. The absence of CC bond in the CiB-g-METMA spectrum indicated that graft copolymerization occurred.

Supeno [Cenderawasih University, Jayapura, Papua, Indonesia and School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Daik, Rusli, E-mail: rusli@ukm.edu.my [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); El-Sheikh, Said M. [Nano-Structured Materials Division, Advanced Materials Department, Central Metallurgical Research and Development Institute, Cairo (Egypt)

2014-09-03T23:59:59.000Z

298

Cation self-diffusion in Fe/sub 2/O/sub 3/  

SciTech Connect (OSTI)

Self-diffusion of /sup 59/Fe in single crystals of Fe/sub 2/O/sub 3/ parallel to the c-axis has been measured as a function of temperature (1150 to 1340/sup 0/C) and oxygen partial pressure (2 x 10/sup -3/) less than or equal to Po/sub 2/ less than or equal to 1 atm). The oxygen partial pressure dependence of the diffusivity indicates that cation self-diffusion occurs by an interstitial-type mechanism. The simultaneous diffusion of /sup 52/Fe and /sup 59/Fe has been measured in Fe/sub 2/O/sub 3/ at 1251/sup 0/C and Po/sub 2/ = 1.91 x 10/sup -2/ atm. The small value of the isotope effect (f..delta..K = 0.067 +- 0.016) is consistent with diffusion of Fe ions by an interstitially mechanism.

Hoshino, K.; Peterson, N.L.

1984-01-01T23:59:59.000Z

299

Optical and electronic properties of mixed Ag-Au tetramer cations  

SciTech Connect (OSTI)

We present experimental and theoretical studies of the optical response of mixed Ag {sub n} Au {sub 4?n}{sup +} (n=1–3) clusters in the photon energy range ?? = 1.9–3.5 eV. Absorption spectra are recorded by a newly built longitudinal molecular beam depletion spectroscopy apparatus providing lower limits to absolute photodissociation cross sections. The experimental data are compared to optical response calculations in the framework of long-range corrected time-dependent density functional theory with initial cluster geometries obtained by the unbiased Birmingham Cluster Genetic Algorithm coupled with density functional theory. Experiments and excited state calculations shed light on the structural and electronic properties of the mixed Ag-Au tetramer cations.

Shayeghi, A., E-mail: shayeghi@cluster.pc.chemie.tu-darmstadt.de; Schäfer, R. [Eduard-Zintl-Institut, Technische Universität Darmstadt, Alarich-Weiss-Straße 8, 64287 Darmstadt (Germany)] [Eduard-Zintl-Institut, Technische Universität Darmstadt, Alarich-Weiss-Straße 8, 64287 Darmstadt (Germany); Heard, C. J.; Johnston, R. L. [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)] [School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom)

2014-02-07T23:59:59.000Z

300

Ion-exchange selectivities of periderm and cuticular membranes toward alkali cations  

SciTech Connect (OSTI)

The ion-exchange selectivities of lithium, sodium, potassium, and cesium on isolated potato periderm (Solanum tuberosum) and pear fruit cuticular membranes were investigated; the general order of preference both for cation selectivities and ion-exchange capacities was lithium > sodium > potassium > cesium. The potato periderm and pear fruit cuticular membranes exhibited a behavior typical of ion-exchange resins of the weak acid type. At constant pH 7, the ion-exchange capacities of periderm and cuticular membranes increased with hydrated ionic radius, and also with increasing pH and neutral salt concentration, and decreased with crystal ionic radius. Counterion selectivities also exhibited the same behavior. The ion-exchange properties are discussed in terms of the structure and function of potato periderm and pear fruit cuticular membranes.

Ersoz, M. [Univ. of Selcuk, Konya (Turkey); Duncan, H.J. [Univ. of Glasgow, Scotland (United Kingdom)

1994-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Self-Assembly of Hexanuclear Clusters of 4f and 5f Elements with Cation Specificity  

SciTech Connect (OSTI)

Six hexanuclear clusters of 4f and 5f elements were synthesized by room-temperature slow concentration experiments. Cerium(IV), thorium(IV), and plutonium(IV) each form two different hexanuclear clusters, among which the cerium and plutonium clusters are isotypic, whereas the thorium clusters show more diversity. The change in ionic radii of approximately 0.08 Å between these different metal ions tunes the cavity size so that NH{sub 4}{sup +} (1.48 Å) has the right dimensions to assemble the cerium and plutonium clusters, whereas Cs{sup +} (1.69 Å) is necessary to assemble the thorium clusters. If these cations are not used in the reactions, only amorphous material is obtained.

Diwu, J.; Good, Justin J.; DiStefano, Victoria H.; Albrecht-Schmitt, Thomas E.

2011-01-01T23:59:59.000Z

302

Influence of relaxation transitions on radiation-initiated cationic graft polymerization. [Gamma radiation  

SciTech Connect (OSTI)

Radiation grafting of vinyl n-butyl ether (VBE) to polyvinyl chloride (PVC) over a broad temperature range was investigated. The relaxation transitions in the PVC/VBE system were also determined. Grafting of vinyl alkyl ethers proceeds entirely by a cationic mechanism in a reaction medium that has been dried to a water concentration no greater than 0.1-1.0 ppm. In this connection, the diffusion properties of water in the temperature region were studied. Commercial films of unplasticized PVC (thickness 200 M); were subjected to swelling in two systems: in a 50% solution of VBE in benzene at 25/sup 0/C, and in the pure monomer at 40/sup 0/C. The reaction mixtures were first dried over metallic sodium in a deaerated atmosphere. The specimens were irradiated in a Co gamma-radiation unit to a dose of 10 kGy at a dose rate of 3 Gy/sec. The first reaction mixture was investigated over a range of temperatures from -60/sup 0/ to +70/sup 0/C, and the second from -15/sup 0/ to +50/sup 0/C. The degree of grafting was determined from the increase in weight of the original ungrafted film. The temperature was held to within +/-1/sup 0/C. The relaxation transitions in the swollen polymer systems were determined by two methods, thermostimulated current (TSC) and thermomechanics (TM). It was found that in the region of the glass transition of a swollen PVC-VBE system, radiation-initiated cationic graft polymerization proceeds at a maximal rate, and there are changes in state of the water molecules (the agents of breaking the ion reaction chain) and in their diffusion properties within the matrix.

Kudryavtsev, V.N.; Kabanov, V.Ya.; Chalykh, A.E.; Spitsyn, V.I.

1982-05-01T23:59:59.000Z

303

Transient-Liquid-Phase and Liquid-Film-Assisted Joining ofCeramics  

SciTech Connect (OSTI)

Two joining methods, transient-liquid-phase (TLP) joining and liquid-film-assisted joining (LFAJ), have been used to bond alumina ceramics. Both methods rely on multilayer metallic interlayers designed to form thin liquid films at reduced temperatures. The liquid films either disappear by interdiffusion (TLP) or promote ceramic/metal interface formation and concurrent dewetting of the liquid film (LFAJ). Progress on extending the TLP method to lower temperatures by combining low-melting-point (<450 C) liquids and commercial reactive-metal brazes is described. Recent LFAJ work on joining alumina to niobium using copper films is presented.

Sugar, Joshua D.; McKeown, Joseph T.; Akashi, Takaya; Hong, SungM.; Nakashima, Kunihiko; Glaeser, Andreas M.

2005-02-09T23:59:59.000Z

304

Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R. Krueger, S. Vyas,a  

E-Print Network [OSTI]

Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R The nuclear magnetic resonance NMR spectra for the I=3/2 23 Na cation dissolved into filamentous bacteriophage the 23 Na nuclear quadrupole moment and the electric field gradient produced by the negatively charged Pf

Augustine, Mathew P.

305

JOURNAL DE PHYSIQUE Colloque C1, suppliment au no 4, Tome 38, Avril 1977, page C1-207 KINETICS OF THE CATION REDISTRIBUTION IN MAGNESIUM FERRITES  

E-Print Network [OSTI]

OF THE CATION REDISTRIBUTION IN MAGNESIUM FERRITES V. A. M. BRABERS and J. KLERK Department of Physics distribution des ions Mg2+et Fe3+sur les sites tetrakdriques et octakdriquesde ferrites de magnesium est Ctudi properties of ferrites. The cation distribution in magnesium ferrite has been studied by various authors

Boyer, Edmond

306

Mechanism of Cation Exchange Process for Epitaxy of Superconducting HgBa2CaCu2O6 Films and Passive Microwave Devices  

E-Print Network [OSTI]

cations into, the lattice of epitaxial Tl2Ba2CaCu2O8 (Tl-2212) or TlBa2CaCu2O7 (Tl-1212) precursor films. Aiming at the remained issues in understanding the mechanism of the cation exchange (CE) process, this thesis work has studied the reversibility of CE...

Zhao, Hua

2007-12-17T23:59:59.000Z

307

Element-and site-specific oxidation state and cation distribution in manganese ferrite films by diffraction anomalous fine structure  

E-Print Network [OSTI]

Element- and site-specific oxidation state and cation distribution in manganese ferrite films Received 2 April 2008; accepted 9 July 2008; published online 8 August 2008 Epitaxial manganese ferrite.1063/1.2969406 Spinel ferrites represent an important class of materials that provide high permeability, moderate

Haskel, Daniel

308

Changes in Sea-Level associated with Modi cations of the Mass Balance of the Greenland and Antarctic  

E-Print Network [OSTI]

Changes in Sea-Level associated with Modi cations of the Mass Balance of the Greenland and Antarctic Ice Sheets over the 21st Century V eronique Bugnion Abstract Changes in runo from Greenland for estimating melting and runo . All models are solved on 20 and 40 km grids respectively for Greenland

309

Heating-Induced Micelle to Vesicle Transition in the Cationic-Anionic Surfactant Systems: Comprehensive Study and Understanding  

E-Print Network [OSTI]

Heating-Induced Micelle to Vesicle Transition in the Cationic-Anionic Surfactant Systems, 2004; In Final Form: January 6, 2005 Heating-induced micelle to vesicle transition (MVT), which has classes: Class A and B. Heating-induced MVT was observed in Class A at certain total surfactant

Huang, Jianbin

310

An alkaline direct ethanol fuel cell with a cation exchange membrane Liang An and T. S. Zhao*  

E-Print Network [OSTI]

An alkaline direct ethanol fuel cell with a cation exchange membrane Liang An and T. S. Zhao the performance of anion exchange membrane (AEM) direct ethanol fuel cells (DEFCs) is that state-of-the-art AEMs exchange membrane direct ethanol fuel cells (AEM- DEFCs) have received ever-increasing attention, mainly

Zhao, Tianshou

311

Nuevos materiales basados en cationes alcalinotrreos, reutilizables y de muy bajo coste con un elevado poder cataltico y de sorcin  

E-Print Network [OSTI]

. Estos materiales, que respetan el medio ambiente, de bajo costo, fácil fabricación y estabilidad térmica ambiente. La alta acidez Lewis de los cationes alcalinotérreos proporciona a los catalizadores sitios muy actualmente a nivel industrial (compuestos de metales preciosos) · son reutilizables · tienen un menor impacto

312

Computational study of the energetics of charge and cation mixing in U1-xCexO?  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The formalism of electronic density-functional theory (DFT), with Hubbard-U corrections (DFT+U), is employed in a computational study of the energetics of fluorite-structured U1-xCexO? mixtures. The computational approach makes use of a procedure which facilitates convergence of the calculations to multiple self-consistent DFT+U solutions for a given cation arrangement, corresponding to different charge states for the U and Ce ions in several prototypical cation arrangements. Results indicate a significant dependence of the structural and energetic properties on the nature of both charge and cation ordering. With the effective Hubbard-U parameters that reproduce well the measured oxidation-reduction energies for urania and ceria, we find that charge transfer between U?? and Ce?? ions, leading to the formation of U?? and Ce³?, gives rise to an increase in the mixing energy in the range of 4–14 kJ/mol of the formula unit, depending on the nature of the cation ordering. The results suggest that although charge transfer between uranium and cerium ions is disfavored energetically, it is likely to be entropically stabilized at the high temperatures relevant to the processing and service of urania-based solid solutions.

Hanken, B. E.; Stanek, C. R.; Grønbech-Jensen, N.; Asta, M.

2011-08-01T23:59:59.000Z

313

Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste  

SciTech Connect (OSTI)

Various forms of general and localized corrosion represent principal threats to the integrity of DOE liquid waste storage tanks. These tanks, which are of a single wall or double wall design, depending upon their age, are fabricated from welded carbon steel and contain a complex waste-form comprised of NaOH and NaNO{sub 3}, along with trace amounts of phosphate, sulfate, carbonate, and chloride. Because waste leakage can have a profound environmental impact, considerable interest exists in predicting the accumulation of corrosion damage, so as to more effectively schedule maintenance and repair. The different tasks that are being carried out under the current program are as follows: (1) Theoretical and experimental assessment of general corrosion of iron/steel in borate buffer solutions by using electrochemical impedance spectroscopy (EIS), ellipsometry and XPS techniques; (2) Development of a damage function analysis (DFA) which would help in predicting the accumulation of damage due to pitting corrosion in an environment prototypical of DOE liquid waste systems; (3) Experimental measurement of crack growth rate, acoustic emission signals and coupling currents for fracture in carbon and low alloy steels as functions of mechanical (stress intensity), chemical (conductivity), electrochemical (corrosion potential, ECP), and microstructural (grain size, precipitate size, etc) variables in a systematic manner, with particular attention being focused on the structure of the noise in the current and its correlation with the acoustic emissions; (4) Development of fracture mechanisms for carbon and low alloy steels that are consistent with the crack growth rate, coupling current data and acoustic emissions; (5) Inserting advanced crack growth rate models for SCC into existing deterministic codes for predicting the evolution of corrosion damage in DOE liquid waste storage tanks; (6) Computer simulation of the anodic and cathodic activity on the surface of the steel samples in order to exactly predict the corrosion mechanisms; (7) Wavelet analysis of EC noise data from steel samples undergoing corrosion in an environment similar to that of the high level waste storage containers, to extract data pertaining to general, pitting and stress corrosion processes, from the overall data. The Point Defect Model (PDM) is directly applied as the theoretical assessment method for describing the passive film formed on iron/steels. The PDM is used to describe general corrosion in the passive region of iron. In addition, previous work suggests that pit formation is due to the coalescence of cation vacancies at the metal/film interface which would make it possible to use the PDM parameters to predict the onset of pitting. This previous work suggests that once the critical vacancy density is reached, the film ruptures to form a pit. Based upon the kinetic parameters derived for the general corrosion case, two parameters relating to the cation vacancy formation and annihilation can be calculated. These two parameters can then be applied to predict the transition from general to pitting corrosion for iron/mild steels. If cation vacancy coalescence is shown to lead to pitting, it can have a profound effect on the direction of future studies involving the onset of pitting corrosion. The work has yielded a number of important findings, including an unequivocal demonstration of the role of chloride ion in passivity breakdown on nickel in terms of cation vacancy generation within the passive film, the first detection and characterization of individual micro fracture events in stress corrosion cracking, and the determination of kinetic parameters for the generation and annihilation of point defects in the passive film on iron. The existence of coupling between the internal crack environment and the external cathodic environment, as predicted by the coupled environment fracture model (CEFM), has also been indisputably established for the AISI 4340/NaOH system. It is evident from the studies that analysis of coupling current noise is a very sensitive tool f

Digby D. Macdonald; Brian M. Marx; Sejin Ahn; Julio de Ruiz; Balaji Soundararaja; Morgan Smith; and Wendy Coulson

2008-01-15T23:59:59.000Z

314

Orifice mixing of immiscible liquids  

E-Print Network [OSTI]

solution (7). The present study of orif1ce mixing is a continuation of previous research on this project which yielded a relationship explaining the effect of operating conditions upon the format1on of 1nterfacial area for the system water-kerosene.... The experimental technique evolved by Helch (18), Vesselhoff (19), McNair (8), and Scott (IA) was changed only slightly. Their work on water-kerosene was repeated for the liquid pairs trichloroethylene-water, heptanol-water, 20 per oent aqueous sucrose-kerosene...

McDonough, Joseph Aloysius

1960-01-01T23:59:59.000Z

315

Mechanism of constitution liquid film migration  

SciTech Connect (OSTI)

Liquid film migration (LFM) in liquid phase sintering classically involves a large metastable liquid volume adjacent to solid, and migration occurs at an isolated solid-liquid (S-L) interface. Constitutional liquid film migration (CLFM), discovered in alloy 718, has major characteristics similar to those of LFM, except that the metastable liquid is from the constitutional liquation of precipitates on the grain boundary. The similarity between LFM and CLFM has led to the theory that coherency lattice strain responsible for LFM is also responsible for CLFM. The coherency strain hypothesis was tested in this study by evaluating whether the Hillert model of LFM would also apply for CLFM. Experimental results of CLFM in alloy 718 showed that migration velocity followed the trend predicted by the Hillert model. This indicates that the coherency strain hypothesis of LFM also applies for CLFM and that the coherency lattice strain responsible for LFM is also the driving force for CLFM.

NONE

1999-06-01T23:59:59.000Z

316

Flowing Liquid Crystal Simulating the Schwarzschild Metric  

E-Print Network [OSTI]

We show how to simulate the equatorial section of the Schwarzschild metric through a flowing liquid crystal in its nematic phase. Inside a liquid crystal in the nematic phase, a traveling light ray feels an effective metric, whose properties are linked to perpendicular and parallel refractive indexes, $n_o$ e $n_e$ respectively, of the rod-like molecule of the liquid crystal. As these indexes depend on the scalar order parameter of the liquid crystal, the Beris-Edwards hydrodynamic theory is used to connect the order parameter with the velocity of a liquid crystal flow at each point. This way we calculate a radial velocity profile that simulates the equatorial section of the Schwarzschild metric, in the region outside of Schwarzschild's radius, in the nematic phase of the liquid crystal. In our model, the higher flow velocity can be of the order of some meters per second.

Erms R. Pereira; Fernando Moraes

2010-11-21T23:59:59.000Z

317

Liquid metal cooled nuclear reactor plant system  

DOE Patents [OSTI]

A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting for fuel decay during reactor shutdown, or heat produced during a mishap. The reactor system is enhanced with sealing means for excluding external air from contact with the liquid metal coolant leaking from the reactor vessel during an accident. The invention also includes a silo structure which resists attack by leaking liquid metal coolant, and an added unique cooling means.

Hunsbedt, Anstein (Los Gatos, CA); Boardman, Charles E. (Saratoga, CA)

1993-01-01T23:59:59.000Z

318

Gas well operation with liquid production  

SciTech Connect (OSTI)

Prediction of liquid loading in gas wells is discussed in terms of intersecting tubing or system performance curves with IPR curves and by using a more simplified critical velocity relationship. Different methods of liquid removal are discussed including such methods as intermittent lift, plunger lift, use of foam, gas lift, and rod, jet, and electric submersible pumps. Advantages, disadvantages, and techniques for design and application of the methods of liquid removal are discussed.

Lea, J.F.; Tighe, R.E.

1983-02-01T23:59:59.000Z

319

Adsorptive Drying of Organic Liquids- An Update  

E-Print Network [OSTI]

reactions lowering yields and compro mising product quality. In these several situations where liquids are involved, any of the following means may be used to lower the water content: Inert Gas Purging Liquid Extraction Freeze Drying Pervaporation... Fractional Distillation Adsorption Although fractional distillation and adsorption are almost exclusively used, the others are included to complete the list. Inert Gas Purging This method can be used to dry high boiling liquids such as gear oils...

Joshi, S.; Humphrey, J. L.; Fair, J. R.

320

Early Events in Ionic Liquid Radiation Chemistry  

SciTech Connect (OSTI)

Ionic liquids are interesting and useful materials whose solvation time scales are up to thousands of times longer than in conventional solvents. The extended lifetimes of pre-solvated electrons and other energetic species in ionic liquids has profound consequences for the radiolytic product distributions and reactivity patterns. We use a newly developed, multiplexed variation of pulse-probe spectroscopy to measure the kinetics of the early dynamical and reactive events in ionic liquids.

Wishart, J.F.; Cook, A.; Rimmer, R.D.; Gohdo, M.

2010-09-14T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Hazardous Liquid Pipelines and Storage Facilities (Iowa)  

Broader source: Energy.gov [DOE]

This statute regulates the permitting, construction, monitoring, and operation of pipelines transporting hazardous liquids, including petroleum products and coal slurries. The definition used in...

322

Liquid phase sintering of silicon carbide  

DOE Patents [OSTI]

Liquid phase sintering is used to densify silicon carbide based ceramics using a compound comprising a rare earth oxide and aluminum oxide to form liquids at temperatures in excess of 1600.degree. C. The resulting sintered ceramic body has a density greater than 95% of its theoretical density and hardness in excess of 23 GPa. Boron and carbon are not needed to promote densification and silicon carbide powder with an average particle size of greater than one micron can be densified via the liquid phase process. The sintered ceramic bodies made by the present invention are fine grained and have secondary phases resulting from the liquid phase.

Cutler, Raymond A. (Bountiful, UT); Virkar, Anil V. (Salt Lake City, UT); Hurford, Andrew C. (Salt Lake City, UT)

1989-01-01T23:59:59.000Z

323

Onsite Wastewater Treatment Systems: Liquid Chlorination  

E-Print Network [OSTI]

This publication explains the process, components, legal requirements, factors affecting performance, and maintenance needs of liquid chlorination systems for onsite wastewater treatment....

Weaver, Richard; Lesikar, Bruce J.; Richter, Amanda; O'Neill, Courtney

2008-10-23T23:59:59.000Z

324

Liquid metal Flow Meter - Final Report  

SciTech Connect (OSTI)

Measuring the flow of liquid metal presents serious challenges. Current commercially-available flow meters use ultrasonic, electromagnetic, and other technologies to measure flow, but are inadequate for liquid metal flow measurement because of the high temperatures required by most liquid metals. As a result of the reactivity and high temperatures of most liquid metals, corrosion and leakage become very serious safety concerns. The purpose of this project is to develop a flow meter for Lockheed Martin that measures the flow rate of molten metal in a conduit.

Andersen C, Hoogendoom S, Hudson B, Prince J, Teichert K, Wood J, Chase K

2007-01-30T23:59:59.000Z

325

Closed-field capacitive liquid level sensor  

DOE Patents [OSTI]

A liquid level sensor based on a closed field circuit comprises a ring oscillator using a symmetrical array of plate units that creates a displacement current. The displacement current varies as a function of the proximity of a liquid to the plate units. The ring oscillator circuit produces an output signal with a frequency inversely proportional to the presence of a liquid. A continuous liquid level sensing device and a two point sensing device are both proposed sensing arrangements. A second set of plates may be located inside of the probe housing relative to the sensing plate units. The second set of plates prevent any interference between the sensing plate units.

Kronberg, J.W.

1995-01-01T23:59:59.000Z

326

Liquid composition having ammonia borane and decomposing to form hydrogen and liquid reaction product  

DOE Patents [OSTI]

Liquid compositions of ammonia borane and a suitably chosen amine borane material were prepared and subjected to conditions suitable for their thermal decomposition in a closed system that resulted in hydrogen and a liquid reaction product.

Davis, Benjamin L; Rekken, Brian D

2014-04-01T23:59:59.000Z

327

Pipe effect in viscous liquids  

E-Print Network [OSTI]

A detailed experimental and theoretical study has been performed about a phenomenon, not previously reported in the literature, occurring in highly viscous liquids: the formation of a definite pipe structure induced by the passage of a heavy body, this structure lasting for quite a long time. A very rich phenomenology (including mechanical, optical and structural effects) associated with the formation of the pipe has been observed in different liquids. Actually, the peculiar dynamical evolution of that structure does not appear as a trivial manifestation of standard relaxation or spurious effects. In particular we have revealed different time scales during the evolution of the pipe and a non-monotonous decreasing of the persistence time with decreasing viscosity (with the appearance of at least two different maxima). A microscopic model consistent with the experimental data, where the pipe behaves as a cylindrical dielectric shell, has been proposed. The general time evolution of the structure has been described in terms of a simple thermodynamical model, predicting several peculiarities effectively observed.

V. Capano; S. Esposito; G. Salesi

2008-12-23T23:59:59.000Z

328

Spiers Memorial Lecture Recent experimental advances in studies of liquid/liquid  

E-Print Network [OSTI]

complicated processes such as molecular transport across cell membranes. A variety of techniques have been on the interaction of a hydrophobic surface with water, and ion and solute transport across these and other liquid/hydrophilic properties of liquid/ liquid interfaces. In biological systems, protein folding and membrane formation rely

Richmond, Geraldine L.

329

Arrays and Cascades of Fluorescent Liquid-Liquid Waveguides: Broadband Light Sources for  

E-Print Network [OSTI]

Arrays and Cascades of Fluorescent Liquid-Liquid Waveguides: Broadband Light Sources) microchannel waveguides with liquid cores containing fluorescent dyes, excited by incident light from an external halogen bulb. Simultaneous use of multiple fluorophores in a common solution, in a single L2 light

Prentiss, Mara

330

Assessment of coal liquids as refinery feedstocks  

SciTech Connect (OSTI)

The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

Zhou, P.

1992-02-01T23:59:59.000Z

331

Assessment of coal liquids as refinery feedstocks  

SciTech Connect (OSTI)

The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

Zhou, P.

1992-02-01T23:59:59.000Z

332

AGING EFFECTS ON THE PROPERTIES OF IMIDAZOLIUM, QUATERNARY AMMONIUM, PYRIDINIUM AND PYRROLIDINIUM-BASED IONIC LIQUIDS USED IN FUEL AND ENERGY PRODUCTION  

SciTech Connect (OSTI)

Ionic liquids are often cited for their excellent thermal stability, a key property for their use as solvents and in the chemical processing of biofuels. However, there has been little supporting data on the long term aging effect of temperature on these materials. Imizadolium, quaternary ammonium, pyridinium, and pyrrolidnium-based ionic liquids with the bis(trifluoromethylsulfonyl)imide and bis(perfluoroethylsulfonyl)imide anions were aged for 2520 hours (15 weeks) at 200?C in air to determine the effects of an oxidizing environment on their chemical structure and thermal stability over time. It was found that the minor changes in the cation chemistry could greatly affect the properties of the ILs over time.

Fox, E.

2013-08-13T23:59:59.000Z

333

Fiber-optic liquid level sensor  

DOE Patents [OSTI]

A fiber-optic liquid level sensor measures the height of a column of liquid through the hydrostatic pressure it produces. The sensor employs a fiber-optic displacement sensor to detect the pressure-induced displacement of the center of a corrugated diaphragm.

Weiss, Jonathan D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

334

Liquid Biofuels Strategies and Policies in selected  

E-Print Network [OSTI]

June 2011 Liquid Biofuels Strategies and Policies in selected African Countries A review of some of the challenges, activities and policy options for liquid biofuels Prepared for PISCES by Practical Action Biofuels Strategies and Policies in selected African Countries Although this research is funded by DFID

335

CMD-3 Liquid Xenon Calorimeter's signals processing  

E-Print Network [OSTI]

CMD-3 Liquid Xenon Calorimeter's signals processing for timing measurements. Leonid Epshtein Budker connected to constitute 264 «towers»; signal of each tower is processed by electronic channel. Liquid Xenon functional channel scheme and signal's shapes in the typical point. Digital Signal Processing ADCCSALXe

336

Remarks on Liquid Wall Research Mohamed Abdou  

E-Print Network [OSTI]

Remarks on Liquid Wall Research Mohamed Abdou Professor Mechanical and Aerospace Engineering UCLA physicists and engineering scientists · Enhances synergism between IFE and MFE · Provides excellent disciplines. #12;Several "Ideas" Have Been Proposed for Liquid Walls Fluids 1) High-conductivity, low Pr

California at Los Angeles, University of

337

Atomistic Studies of Cation Transport in Tetragonal ZrO2 During Zirconium Corrosion  

SciTech Connect (OSTI)

Zirconium alloys are the major fuel cladding materials in current reactors. The water-side corrosion is one of the major degradation mechanisms of these alloys. During corrosion the transport of oxidizing species in zirconium dioxide (ZrO2) determines the corrosion kinetics. Previously it has been argued that the outward diffusion of cation ions is important for forming protective oxides. In this work, the migration of Zr defects in tetragonal ZrO2 is studied with temperature accelerated dynamics and molecular dynamics simulations. The results show that Zr interstitials have anisotropic diffusion and migrate preferentially along the [001] or c direction in tetragonal ZrO2. The compressive stresses can increase the Zr interstitial migration barrier significantly. The migration barriers of some defect clusters can be much lower than those of point defects. The migration of Zr interstitials at some special grain boundaries is much slower than in a bulk oxide. The implications of these atomistic simulation results in the Zr corrosion are discussed.

Xian-Ming Bai; Yongfeng Zhang; Michael R. Tonks

2013-10-01T23:59:59.000Z

338

Energy/structure database of all proteinogenic amino acids and dipeptides without and with divalent cations  

E-Print Network [OSTI]

We present a structural data set of the 20 proteinogenic amino acids and their amino-methylated and acetylated (capped) dipeptides. Different protonation states of the backbone (uncharged and zwitterionic) were considered for the amino acids as well as varied side chain protonation states. Furthermore, we studied amino acids and dipeptides in complex with divalent cations (Ca2+, Ba2+, Sr2+, Cd2+, Pb2+, and Hg2+). The database covers the conformational hierarchies of 280 systems in a wide relative energy range of up to 4 eV (390 kJ/mol), summing up to an overall of 45,892 stationary points on the respective potential-energy surfaces. All systems were calculated on equal first-principles footing, applying density-functional theory in the generalized gradient approximation corrected for long-range van der Waals interactions. We show good agreement to available experimental data for gas-phase ion affinities. Our curated data can be utilized, for example, for a wide comparison across chemical space of the building...

Ropo, Matti; Blum, Volker

2015-01-01T23:59:59.000Z

339

Millisecond Kinetics of Nanocrystal Cation Exchange UsingMicrofluidic X-ray Absorption Spectroscopy  

SciTech Connect (OSTI)

We describe the use of a flow-focusing microfluidic reactorto measure the kinetics of theCdSe-to-Ag2Se nanocrystal cation exchangereaction using micro-X-ray absorption spectroscopy (mu XAS). The smallmicroreactor dimensions facilitate the millisecond mixing of CdSenanocrystal and Ag+ reactant solutions, and the transposition of thereaction time onto spatial coordinates enables the in situ observation ofthe millisecond reaction with mu XAS. XAS spectra show the progression ofCdSe nanocrystals to Ag2Se over the course of 100 ms without the presenceof long-lived intermediates. These results, along with supporting stoppedflow absorption experiments, suggest that this nanocrystal cationexchange reaction is highly efficient and provide insight into how thereaction progresses in individual particles. This experiment illustratesthe value and potential of in situ microfluidic X-ray synchrotrontechniques for detailed studies of the millisecond structuraltransformations of nanoparticles and other solution-phase reactions inwhich diffusive mixing initiates changes in local bond structures oroxidation states.

Chan, Emory M.; Marcus, Matthew A.; Fakra, Sirine; Elnaggar,Mariam S.; Mathies, Richard A.; Alivisatos, A. Paul

2007-05-07T23:59:59.000Z

340

Synthesis and chemistry of cationic d sup 0 metal alkyl complexes  

SciTech Connect (OSTI)

The objective of this project is to develop new types of electrophilic metal alkyl complexes for catalytic C-H activation and olefin polymerization chemistry, and associated fundamental mechanistic studies. We have focused our efforts on four classes of early metal alkyl complexes: (1) cationic group 4 Cp{sub 2}M(R){sup +} complexes (1) which are active species in Cp{sub 2}MX{sub 2}-based Ziegler-Natta olefin polymerization catalyst systems and which catalyze productive C-H activation reactions of heterocycles, (2) neutral (dicarbollide)(Cp*)M(R) complexes (2) which are structurally are electronically very similar to 1, (3) half-sandwich complexes CpM(R){sub 2}(L){sub n}{sup +} which are highly coordinatively and electronically unsaturated, and (4) new group 5 (dicarbollide)(Cp)MR{sub 2} and (dicarbollide){sub 2} MR complexes which are more unsaturated than group 5 Cp{sub 2}M systems due to incorporation of the dicarbollide ligand.

Jordan, R.F.

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Dual liquid and gas chromatograph system  

DOE Patents [OSTI]

A chromatographic system that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a non-transparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extremely low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

Gay, Don D. (Aiken, SC)

1985-01-01T23:59:59.000Z

342

Sewage sludge dewatering using flowing liquid metals  

DOE Patents [OSTI]

A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

Carlson, Larry W. (Oswego, IL)

1986-01-01T23:59:59.000Z

343

Liquid crystal device and method thereof  

DOE Patents [OSTI]

The invention provides a liquid crystal device and method thereof. Subsequent to applying a first electrical voltage on a liquid crystal to induce a reorientation of the liquid crystal, a second electrical voltage with proper polarity is applied on the liquid crystal to assist the relaxation of the reorientation that was induced by the first electrical voltage. The "switch-off" phase of the liquid crystal can therefore be accelerated or temporally shortened, and the device can exhibit better performance such as fast response to on/off signals. The invention can be widely used LCD, LC shutter, LC lens, spatial light modulator, telecommunication device, tunable filter, beam steering device, and electrically driven LC device, among others.

Shiyanovskii, Sergij V; Gu, Mingxia; Lavrentovich, Oleg D

2012-10-23T23:59:59.000Z

344

On the Fluctuations that Order and Frustrate Liquid Water  

E-Print Network [OSTI]

Most nonpolar liquids have heat capacities that range from 8the maximum liquid state heat capacity[173]. ExperimentallyLIQUID AND SOLID WATER (a) Density (b) Compressibility (c) Heat Capacity

Limmer, David

2013-01-01T23:59:59.000Z

345

Modelling Mixed Bed Ion Exchange Kinetics for Removal of Trace Levels of Divalent Cations in Ultrapure Water  

SciTech Connect (OSTI)

Ion exchanger resin fluid film mass transfer coefficients and the ionic diffusivities from which they are derived are often measured by use of ion exchange resin columns. Such tests, usually run dynamically using short resin beds, are often performed using relatively high (ppm) concentrations of ions to accurately measure output concentrations as a function of flow rate. The testing described herein was performed to determine fluid film ionic diffusivities for cationic concentrations typical of ultrapure water ({le}ppb levels) containing ppm levels of ammonia. Effective ionic diffusivities at these low ionic concentrations and high pHs were needed to complete a computer model (SIMIX) to be used in ion exchange simulations. SIMIX is a generalized multicomponent ion exchange model designed to simulate the removal of divalent cations from ultrapure water.

B. Widman

2003-01-01T23:59:59.000Z

346

CATIONIC SHELL CROSSLINKED NANOPARTICLES AS INTRACELLULAR DELIVERY VEHICLES FOR THE DIAGNOSIS AND TREATMENT OF ACUTE LUNG INJURY  

E-Print Network [OSTI]

started in my organic chemistry classroom, as I watched Dr. David Bergbreiter talk about this intriguing subject. I would like to thank him for he was always there helping his students and encouraging us to think beyond the books. Dr. Bergbreiter... CATIONIC SHELL CROSSLINKED NANOPARTICLES AS INTRACELLULAR DELIVERY VEHICLES FOR THE DIAGNOSIS AND TREATMENT OF ACUTE LUNG INJURY Majors: Chemistry Biomedical Science April 2011 Submitted...

Florez, Stephanie

2011-08-08T23:59:59.000Z

347

Synthesis of magnetite-porphyrin nanocomposite and its application as a novel magnetic adsorbent for removing heavy cations  

SciTech Connect (OSTI)

Graphical abstract: Magnetite-porphyrin nanocomposite (MPNC) as a novel magnetic adsorbent for removing heavy cations was synthesized. - Highlights: • Nanosized Fe{sub 3}O{sub 4} was prepared by hydrothermal reaction of iron salt in alkaline media. • The synthesized magnetite and nanocomposite had soft ferromagnetic property. • Magnetic nanocomposite as a novel magnetic adsorbent for heavy cations was prepared. • Satisfactory separation from solutions in the order of Pb{sup 2+} > Cd{sup 2+} > Hg{sup 2+} was obtained. - Abstract: Magnetite-porphyrin nanocomposite (MPNC) was synthesized as a novel magnetic adsorbent for removing heavy cations. Firstly, we prepared nano-sized magnetite using a simple hydrothermal route. The synthesis of nanoscaled magnetite was carried out through reaction between iron source and various amines. In this paper, we studied effective parameters in controlling shape and size of nanoscaled magnetite. These parameters were presence of alkaline, reaction time, kind of amine and iron salt. Morphology, particle size and magnetic properties of the nanoscaled magnetite were obtained by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Fourier transform infrared (FT-IR), diffuse reflectance spectra (DRS) and vibrating sample magnetometer (VSM). Our study showed that the synthesized magnetite from reaction between FeSO{sub 4} and hydrazinum hydrate has spherical shape. The synthesized magnetite was a nanosized compound and used for preparation of magnetite-porphyrin nanocomposite. The synthesized magnetite-porphyrin hybrid material had magnetic property and was used as magnetic adsorbent for removing heavy cations of water. Satisfactory separation from solutions in the order of Pb{sup 2+} > Cd{sup 2+} > Hg{sup 2+} was obtained.

Bakhshayesh, Sara, E-mail: s_bakhshayesh@yahoo.com; Dehghani, Hossein, E-mail: dehghani@kashanu.ac.ir

2013-07-15T23:59:59.000Z

348

G en eralisation de th eor emes inductifs pour la v eri cation d'architectures r eguli eres  

E-Print Network [OSTI]

G#19;en#19;eralisation de th#19;eor#18;emes inductifs pour la v#19;eri#12;cation d'architectures r, preuve qui n#19;e- cessite fr#19;equemment une phase de g#19;en#19;eralisation de th#19;eor#18;emes. Nous proposons une m#19;ethode de g#19;en#19;eralisation qui permet de produire le th#19;eor#18;eme g#19;en#19

Pierre, Laurence

349

Technical Assessment of Organic Liquid Carrier Hydrogen Storage...  

Broader source: Energy.gov (indexed) [DOE]

and long cycle life, and that remain liquid over the working temperature range. Air Products and Chemicals Inc (APCI) investigated many candidates for potential liquid...

350

Ionic Liquid Pretreatment Process for Biomass Is Successfully...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ionic Liquid Pretreatment Process for Biomass Is Successfully Implemented at Larger Scale Ionic Liquid Pretreatment Process for Biomass Is Successfully Implemented at Larger Scale...

351

Low-Emissions Burner Technology using Biomass-Derived Liquid...  

Broader source: Energy.gov (indexed) [DOE]

Emissions Burner Technology using Biomass-Derived Liquid Fuels Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels This factsheet describes a project that developed...

352

Enabling Small-Scale Biomass Gasification for Liquid Fuel Production...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Breakout Session 2A-Conversion...

353

New lithium-based ionic liquid electrolytes that resist salt...  

Energy Savers [EERE]

lithium-based ionic liquid electrolytes that resist salt concentration polarization New lithium-based ionic liquid electrolytes that resist salt concentration polarization...

354

Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries. Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries....

355

Distributed Reforming of Renewable Liquids via Water Splitting...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport...

356

antiferroelectric liquid crystals: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of phases in antiferroelectric liquid crystals Condensed Matter (arXiv) Summary: The free energy of antiferroelectric liquid crystal which takes into account polar order...

357

antiferroelectric liquid crystal: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of phases in antiferroelectric liquid crystals Condensed Matter (arXiv) Summary: The free energy of antiferroelectric liquid crystal which takes into account polar order...

358

alcohol liquid diet: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

biodiesel. Open Access Theses and Dissertations Summary: ??The most widely used process technology for biodiesel manufacture is the base-catalysed liquid-liquid...

359

Agenda for the Derived Liquids to Hydrogen Distributed Reforming...  

Broader source: Energy.gov (indexed) [DOE]

Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review Agenda for the Derived Liquids to...

360

Formation of iron complexs from trifluoroacetic acid based liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of iron complexs from trifluoroacetic acid based liquid chromatography mobile phases as interference ions in liquid Formation of iron complexs from trifluoroacetic acid based...

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Formation of Supercooled Liquid Solutions from Nanoscale Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Supercooled Liquid Solutions from Nanoscale Amorphous Solid Films of Methanol and Ethanol. Formation of Supercooled Liquid Solutions from Nanoscale Amorphous Solid Films of...

362

Mixing it up - Measuring diffusion in supercooled liquid solutions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixing it up - Measuring diffusion in supercooled liquid solutions of methanol and ethanol at temperatures near the glass Mixing it up - Measuring diffusion in supercooled liquid...

363

Case Study: Evaluating Liquid versus Air Cooling in the Maui...  

Broader source: Energy.gov (indexed) [DOE]

Case Study: Evaluating Liquid versus Air Cooling in the Maui High Performance Computing Center Case Study: Evaluating Liquid versus Air Cooling in the Maui High Performance...

364

EECBG Creating Liquidity for Energy Efficiency Loans in Secondary...  

Broader source: Energy.gov (indexed) [DOE]

EECBG Creating Liquidity for Energy Efficiency Loans in Secondary Markets (Text Version) EECBG Creating Liquidity for Energy Efficiency Loans in Secondary Markets (Text Version)...

365

Creating Liquidity for Energy Efficiency Loans in Secondary Markets...  

Broader source: Energy.gov (indexed) [DOE]

Creating Liquidity for Energy Efficiency Loans in Secondary Markets Creating Liquidity for Energy Efficiency Loans in Secondary Markets Provides information on secondary markets in...

366

Improved peptide elution time prediction for reversed-phase liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

peptide elution time prediction for reversed-phase liquid chromatography-MS by incorporating peptide sequence Improved peptide elution time prediction for reversed-phase liquid...

367

Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Computer Simulations Indicate Calcium Carbonate Has a Dense Liquid Phase Berkeley Lab research could help...

368

Experimental and Modeling Studies of the Characteristics of Liquid...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Experimental and Modeling Studies of the Characteristics of Liquid Biofuels for Enhanced Combustion Experimental and Modeling Studies of the Characteristics of Liquid Biofuels for...

369

Elucidating graphene - Ionic Liquid interfacial region: a combined...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

graphene - Ionic Liquid interfacial region: a combined experimental and computational study. Elucidating graphene - Ionic Liquid interfacial region: a combined experimental and...

370

DOE Selects Savannah River Remediation, LLC for Liquid Waste...  

Energy Savers [EERE]

objective of the Liquid Waste contract is to achieve closure of the SRS liquid waste tanks in compliance with the Federal Facilities Agreement, utilizing the Defense Waste...

371

Dielectric liquid ionization chambers for detecting fast neutrons  

E-Print Network [OSTI]

Three ionization chambers with different geometries have been constructed and filled with dielectric liquids for detection of fast neutrons. The three dielectric liquids studied were Tetramethylsilane (TMS), Tetramethylpentane ...

Boyd, Erin M

2008-01-01T23:59:59.000Z

372

Energetics of Hydrogen Bond Network Rearrangements in Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

373

Liquid-liquid equilibria of fuel oxygenate + water + hydrocarbon mixtures. 3: Effect of temperature  

SciTech Connect (OSTI)

The authors have measured the ternary liquid-liquid equilibria of water + ethanol mixtures with, separately, 2,2,4-trimethylpentane and toluene at 5 and 40 C, water + tert-amyl alcohol (TAOH) mixtures with, separately, toluene and hexane at 5 and 40 C, and of water + TAOH + pentane mixtures at 5 C. The ethanol-containing systems exhibit type 1 liquid-liquid phase behavior, and the TAOH-containing systems exhibit type 2 behavior. These data, together with the data they have previously reported at 25 C, provide information on how the liquid-liquid equilibria of these systems change as a function of temperature. While the addition of ethanol is found to increase the solubility of hydrocarbons in the aqueous phase, the concentration of the hydrocarbon in the water-rich phase decreases with increasing temperature. With the exception of hydrocarbon in the water-rich phase, the experimental data could be correlated quite well with either the UNIQUAC or NRTL models. For most of the systems considered here the predictions of the phase behavior with the liquid-liquid UNIFAC group-contribution model are only qualitatively correct. However, the liquid-liquid UNIFAC model erroneously predicts type 2 phase behavior to occur for water + ethanol + 2,2,4-trimethylpentane system at 5 C.

Wagner, G. [Universitaet Karlsruhe (Germany). Institut fuer Thermische Verfahrenstechnik; Sandler, S.I. [Univ. of Delaware, Newark, DE (United States). Center for Molecular and Engineering Thermodynamics

1995-09-01T23:59:59.000Z

374

Novel localization of OCTN1, an organic cation/carnitine transporter, to mammalian mitochondria  

SciTech Connect (OSTI)

Carnitine is a zwitterion essential for the {beta}-oxidation of fatty acids. We report novel localization of the organic cation/carnitine transporter, OCTN1, to mitochondria. We made GFP- and RFP-human OCTN1 cDNA constructs and showed expression of hOCTN1 in several transfected mammalian cell lines. Immunostaining of GFP-hOCTN1 transfected cells with different intracellular markers and confocal fluorescent microscopy demonstrated mitochondrial expression of OCTN1. There was striking co-localization of an RFP-hOCTN1 fusion protein and a mitochondrial-GFP marker construct in transfected MEF-3T3 and no co-localization of GFP-hOCTN1 in transfected human skin fibroblasts with other intracellular markers. L-[{sup 3}H]Carnitine uptake in freshly isolated mitochondria of GFP-hOCTN1 transfected HepG2 demonstrated a K {sub m} of 422 {mu}M and Western blot with an anti-GFP antibody identified the expected GFP-hOCTN1 fusion protein (90 kDa). We showed endogenous expression of native OCTN1 in HepG2 mitochondria with anti-GST-hOCTN1 antibody. Further, we definitively confirmed intact L-[{sup 3}H]carnitine uptake (K {sub m} 1324 {mu}M), solely attributable to OCTN1, in isolated mitochondria of mutant human skin fibroblasts having <1% of carnitine acylcarnitine translocase activity (alternate mitochondrial carnitine transporter). This mitochondrial localization was confirmed by TEM of murine heart incubated with highly specific rabbit anti-GST-hOCTN1 antibody and immunogold labeled goat anti-rabbit antibody. This suggests an important yet different role for OCTN1 from other OCTN family members in intracellular carnitine homeostasis.

Lamhonwah, Anne-Marie [Division of Neurology, Department of Pediatrics, Hospital for Sick Children and Department of Laboratory Medicine and Pathobiology, University of Toronto, Toronto, Ont., M5G 1X8 (Canada); Tein, Ingrid [Division of Neurology, Department of Pediatrics, Hospital for Sick Children and Department of Laboratory Medicine and Pathobiology, University of Toronto, Toronto, Ont., M5G 1X8 (Canada)]. E-mail: ingrid.tein@sickkids.ca

2006-07-14T23:59:59.000Z

375

Rovibronically selected and resolved two-color laser photoionization and photoelectron study of nickel carbide cation  

SciTech Connect (OSTI)

We have performed a two-color laser photoionization and photoelectron study of nickel carbide (NiC) and its cation (NiC{sup +}). By preparing NiC in a single rovibronic level of an intermediate vibronic state via visible laser excitation prior to ultraviolet laser photoionization, we have measured the photoionization efficiency spectrum of NiC near its ionization threshold, covering the formation of NiC{sup +}(X {sup 2}{Sigma}{sup +};v{sup +}=0-3). We have also obtained well-resolved rotational transitions for the v{sup +}=0 and 1 vibrational bands of the NiC{sup +}(X {sup 2}{Sigma}{sup +}) ground state. The assignment of rotational transitions observed between the neutral NiC intermediate state and the NiC{sup +} ion ground state has allowed the direct determination of a highly precise value for the ionization energy of NiC, IE(NiC)=67 525.1{+-}0.5 cm{sup -1} (8.372 05{+-}0.000 06 eV). This experiment also provides reliable values for the vibrational spacing [{Delta}G(1/2)=859.5{+-}0.5 cm{sup -1}], rotational constants (B{sub e}{sup +}=0.6395{+-}0.0018 cm{sup -1} and {alpha}{sub e}{sup +}=0.0097{+-}0.0009 cm{sup -1}), and equilibrium bond distance (r{sub e}{sup +}=1.628 A) for the NiC{sup +}(X {sup 2}{Sigma}{sup +}) ground state. The experimental results presented here are valuable for benchmarking the development of more reliable ab initio quantum computation procedures for energetic and spectroscopic calculations of transition metal-containing molecules.

Chang, Yih Chung [Department of Chemistry, University of California, Davis, Davis, California 95616 (United States); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 106, Taiwan (China); Shi Xiaoyu; Ng, C. Y. [Department of Chemistry, University of California, Davis, Davis, California 95616 (United States); Lau, Kai-Chung [Department of Biology and Chemistry, City University of Hong Kong, Kowloon (Hong Kong); Yin Qingzhu [Department of Geology, University of California, Davis, Davis, California 95616 (United States); Liou, H. T. [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 106, Taiwan (China)

2010-08-07T23:59:59.000Z

376

Viscosity of a nanoconfined liquid during compression  

SciTech Connect (OSTI)

The viscous behavior of liquids under nanoconfinement is not well understood. Using a small-amplitude atomic force microscope, we found bulk-like viscosity in a nanoconfined, weakly interacting liquid. A further decrease in viscosity was observed at confinement sizes of a just few molecular layers. Overlaid over the continuum viscous behavior, we measured non-continuum stiffness and damping oscillations. The average stiffness of the confined liquid was found to scale linearly with the size of the confining tip, while the damping scales with the radius of curvature of the tip end.

Khan, Shah H. [Institute of Physics and Electronics, University of Peshawar, Peshawar 25120 (Pakistan); Kramkowski, Edward L.; Ochs, Peter J.; Wilson, David M.; Hoffmann, Peter M., E-mail: hoffmann@wayne.edu [Department of Physics and Astronomy, Wayne State University, Detroit, Michigan 48201 (United States)

2014-01-13T23:59:59.000Z

377

Fermi liquid theory for high temperature superconductors  

SciTech Connect (OSTI)

In this article the Fermi liquid theory of metals is discussed starting from Luttinger's theorem. The content of Luttinger's Theorem and its implications for microscopic theories of high temperature superconductors are discussed. A simple quasi-2d Fermi liquid theory is introduced and some of its properties are calculated. It is argued that a number of experiments on YBa/sub 2/Cu/sub 3/O/sub 6+x/, x > 0.5, strongly suggest the existence of a Fermi surface and thereby a Fermi liquid normal state. 25 refs., 1 fig.

Bedell, K.S.

1988-01-01T23:59:59.000Z

378

Light Collection in Liquid Noble Gases  

SciTech Connect (OSTI)

Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

McKinsey, Dan [Yale University

2013-05-29T23:59:59.000Z

379

Electron localization in liquid acetonitrile.  

SciTech Connect (OSTI)

Time-resolved one- and two-pulse laser dc photoconductivity has been used to observe two kinds of reducing species, anion-1 and anion-2, in liquid acetonitrile. At 25 C, the standard enthalpy of conversion from anion-1 to anion-2 is -44.3 {+-} 3.6 kJ/mol and the conversion time is 3 ns. The high-temperature form, anion-1, absorbs in the IR and migrates >3.3 times faster than any other ion in acetonitrile. This rapid migration has a low activation energy of 3.2 kJ/mol (vs 7.6 kJ/mol for other ions). Anion-1 rapidly transfers the electron to acceptors with high electron affinity, with rate constant up to 10{sup 11} M{sup -1} s{sup -1}. The low-temperature form, anion-2, absorbs in the visible and exhibits normal mobility and electron-transfer rates, ca. 1.5 x 10{sup 10} M{sup -1} s{sup -1}. It reacts, by proton transfer, with two hydrogen-bonded molecules of water and/or aliphatic alcohols. Laser photoexcitation of these two solvent anions in their respective absorption bands leads to the formation of CH{sub 3} and CN{sup -}. We present arguments indicating that anion-2 is a dimer radical anion of acetonitrile, whereas anion-1 is a multimer radical anion that may be regarded as a 'solvated electron'.

Shkrob, I. A.; Sauer, M. C.; Chemistry

2002-10-03T23:59:59.000Z

380

Liquid and liquid–gas flows at all speeds  

SciTech Connect (OSTI)

All speed flows and in particular low Mach number flow algorithms are addressed for the numerical approximation of the Kapila et al. [1] multiphase flow model. This model is valid for fluid mixtures evolving in mechanical equilibrium but out of temperature equilibrium and is efficient for material interfaces computation separating miscible and non-miscible fluids. In this context, the interface is considered as a numerically diffused zone, captured as well as all present waves (shocks, expansion waves). The same flow model can be used to solve cavitating and boiling flows [2]. Many applications occurring with liquid–gas interfaces and cavitating flows involve a very wide range of Mach number, from 10{sup ?3} to supersonic (and even hypersonic) conditions with respect to the mixture sound speed. It is thus important to address numerical methods free of restrictions regarding the Mach number. To do this, a preconditioned Riemann solver is built and embedded into the Godunov explicit scheme. It is shown that this method converges to exact solutions but needs too small time steps to be efficient. An implicit version is then derived, first in one dimension and second in the frame of 2D unstructured meshes. Two-phase flow preconditioning is then addressed in the frame of the Saurel et al. [3] algorithm. Modifications of the preconditioned Riemann solver are needed and detailed. Convergence of both single phase and two-phase numerical solutions are demonstrated with the help of single phase and two-phase steady nozzle flow solutions. Last, the method is illustrated by the computation of real cavitating flows in Venturi nozzles. Vapour pocket size and instability frequencies are reproduced by the model and method without using any adjustable parameter.

LeMartelot, S., E-mail: sebastien.lemartelot@polytech.univ-mrs.fr [Polytech'Marseille, Aix-Marseille University, UMR CNRS 7343 IUSTI, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France); Nkonga, B., E-mail: boniface.nkonga@unice.fr [RS2N, Bastidon de la Caou, 13360 Roquevaire (France); University of Nice, LJAD UMR CNRS 7351, Parc Valrose, 06108 Nice Cedex (France); Saurel, R., E-mail: richard.saurel@polytech.univ-mrs.fr [Polytech'Marseille, Aix-Marseille University, UMR CNRS 7343 IUSTI, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France); RS2N, Bastidon de la Caou, 13360 Roquevaire (France); University Institute of France, 5 rue E. Fermi, 13453 Marseille Cedex 13 (France)

2013-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Liquid metal cooled divertor for ARIES  

SciTech Connect (OSTI)

A liquid metal, Ga-cooled divertor design was completed for the double null ARIES-II divertor design. The design analysis indicated a surface heat flux removal capability of up to 15 MW/m{sup 2}, and its relative easy maintenance. Design issues of configuration, thermal hydraulics, thermal stresses, liquid metal loop and safety effects were evaluated. For coolant flow control, it was found that it is necessary to use some part of the blanket cooling ducts for the draining of liquid metal from the top divertor. In order to minimize the inventory of Ga, it was recommended that the liquid metal loop equipment should be located as close to the torus as possible. More detailed analysis of transient conditions especially under accident conditions was identified as an issue that will need to be addressed.

Muraviev, E. [Gosudarstvennyj Komitet po Ispol`zovaniyu Atomnoj Ehnergii SSSR, Moscow (Russian Federation). Inst. Atomnoj Ehnergii

1995-01-01T23:59:59.000Z

382

Liquid Lithium Experiments in CDX-U  

SciTech Connect (OSTI)

The initial results of experiments involving the use of liquid lithium as a plasma facing component in the Current Drive Experiment-Upgrade (CDX-U) are reported. Studies of the interaction of a steady-state plasma with liquid lithium in the Plasma Interaction with Surface and Components Experimental Simulator (PISCES-B) are also summarized. In CDX-U a solid or liquid lithium covered rail limiter was introduced as the primary limiting surface for spherical torus discharges. Deuterium recycling was observed to be reduced, but so far not eliminated, for glow discharge-cleaned lithium surfaces. Some lithium influx was observed during tokamak operation. The PISCES-B results indicate that the rates of plasma erosion of lithium can exceed predictions by an order of magnitude at elevated temperatures. Plans to extend the CDX-U experiments to large area liquid lithium toroidal belt limiters are also described.

R. Majeski; R. Doerner; R. Kaita; G. Antar; J. Timberlake; et al

2000-11-15T23:59:59.000Z

383

Removal of arsenic compounds from petroliferous liquids  

DOE Patents [OSTI]

Described is a process for removing arsenic from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic bound to it from contacting petroliferous liquid as described above and involves: a. treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10 and, b. separating the solids and liquids from each other. Preferably the regeneration treatment is in two steps wherein step (a) is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, steps (a) and (b) are repeated using a bicarbonate.

Fish, Richard H. (Berkeley, CA)

1985-01-01T23:59:59.000Z

384

Experimental investigation on liquid behaviors in nanopores  

E-Print Network [OSTI]

an nd as an ex xternal pressu ure is applie ed, the liquid d1–90 mm/min. Wh hen the pressu ure reached ab bout 50 MPa, ,

Lu, Weiyi

2011-01-01T23:59:59.000Z

385

Accelerated Animation of Liquid Splash Roman Durikovic  

E-Print Network [OSTI]

step and viscosity. The final liquid surface is obtained from the velocity field by rough estimation small fluid objects such as splash and spray. Our final goal is to develop a real-time system

Durikovic, Roman

386

Phosphonium-based ionic liquids and uses  

DOE Patents [OSTI]

Phosphonium-based room temperature ionic liquids ("RTILs") were prepared. They were used as matrices for Matrix-Assisted Laser Desorption Ionization (MALDI) mass spectrometry and also for preparing samples of dyes for analysis.

Del Sesto, Rico E; Koppisch, Andrew T; Lovejoy, Katherine S; Purdy, Geraldine M

2014-12-30T23:59:59.000Z

387

Future of Liquid Biofuels for APEC Economies  

SciTech Connect (OSTI)

This project was initiated by APEC Energy Working Group (EWG) to maximize the energy sector's contribution to the region's economic and social well-being through activities in five areas of strategic importance including liquid biofuels production and development.

Milbrandt, A.; Overend, R. P.

2008-05-01T23:59:59.000Z

388

Liquid--liquid equilibria by use of UNIFAC for gasohol extraction systems  

SciTech Connect (OSTI)

A synthetic naphtha cut composed of a mixture of paraffinic, aromatic, and naphthenic hydrocarbons has been studied as a solvent to directly produce gasohol. The equilibria in these highly nonideal liquid mixtures has been estimated by the UNIFAC group contribution method. The process would appear to be simple and direct to produce gasohol by liquid--liquid extraction with this naphtha and could compete with existing azeotropic distillation processes.

Furzer, I.A.

1984-04-01T23:59:59.000Z

389

Equilibration of a spinless Luttinger liquid.  

SciTech Connect (OSTI)

We study how a Luttinger liquid of spinless particles in one dimension approaches thermal equilibrium. Full equilibration requires processes of backscattering of excitations, which occur at energies of the order of the bandwidth. Such processes are not accounted for by the Luttinger-liquid theory. We treat the high-energy excitations as mobile impurities and derive an expression for the equilibration rate in terms of their spectrum. Our results apply at any interaction strength.

Matveev, K. A.; Andreev, A. V. (Materials Science Division); (Univ. Washington)

2012-01-01T23:59:59.000Z

390

Nonconventional Liquid Fuels (released in AEO2006)  

Reports and Publications (EIA)

Higher prices for crude oil and refined petroleum products are opening the door for nonconventional liquids to displace petroleum in the traditional fuel supply mix. Growing world demand for diesel fuel is helping to jump-start the trend toward increasing production of nonconventional liquids, and technological advances are making the nonconventional alternatives more viable commercially. Those trends are reflected in the Annual Energy Outlook 2006 projections.

2006-01-01T23:59:59.000Z

391

The absorption of ultrasonic waves in liquids  

E-Print Network [OSTI]

Vee ~ ~ ~ ~ a ~ ~ ~ ~ ~ ~ a ~ e ~ ~ ~ ~ a ~ ~ ea ~ ~ ~ eee ~ ~ ~ ~ ~ ~ ea ~ ~ ~ ~ 2 ~ ?easursasnt of ths Prop-:. ties of:asss and Liquids by Ultrasonicseae ~ ~ ~ ~ ~ e ~ ~ ~ ~ ~ ~ ~ ~ e ~ ~ dies Borne erscsnt Theories ConcsrrrinS the Oisorsparrcy 3e tween... ~ ~ ~ ~ ~ ~ ~ o 3Q VI, Plot of' Los A /A vs~ Sound Path Length Ital ZthoI' 1Mox' Ppoalul'oe ~ ~ a ~ y ~ ~ s ~ ~ ~ ~ ~ ~ e ~ ~ ~ e s ~ ~ ~ ~ e ~ ~ a ~ ~ 3) xxeasuraaents oa the absorption of high frequency souad. waves ia liquids axe useful ia studying...

Hudson, Paul A

2012-06-07T23:59:59.000Z

392

Photosensitive dopants for liquid noble gases  

DOE Patents [OSTI]

In an ionization type detector for high energy radiation wherein the energy of incident radiation is absorbed through the ionization of a liquid noble gas and resulting free charge is collected to form a signal indicative of the energy of the incident radiation, an improvement comprising doping the liquid noble gas with photosensitive molecules to convert scintillation light due to recombination of ions, to additional free charge.

Anderson, David F. (Wheaton, IL)

1988-01-01T23:59:59.000Z

393

Superbase-derived protic ionic liquids  

DOE Patents [OSTI]

Protic ionic liquids having a composition of formula (A.sup.-)(BH.sup.+) wherein A.sup.- is a conjugate base of an acid HA, and BH.sup.+ is a conjugate acid of a superbase B. In particular embodiments, BH.sup.+ is selected from phosphazenium species and guanidinium species encompassed, respectively, by the general formulas: ##STR00001## The invention is also directed to films and membranes containing these protic ionic liquids, with particular application as proton exchange membranes for fuel cells.

Dai, Sheng; Luo, Huimin; Baker, Gary A.

2013-09-03T23:59:59.000Z

394

Retrograde Melting and Internal Liquid Gettering in Silicon  

E-Print Network [OSTI]

XAS analysis. Solid metal-silicide phases below the binaryprevious reports of mixed-metal silicides in mc-Si systems,solidi?cation to solid metal silicide utes, both Cu and Fe

Hudelson, Steve

2012-01-01T23:59:59.000Z

395

Behavior of Supercooled Aqueous Solutions Stemming from Hidden Liquid-Liquid Transition in Water  

E-Print Network [OSTI]

A popular hypothesis that explains the anomalies of supercooled water is the existence of a metastable liquid-liquid transition hidden below the line of homogeneous nucleation. If this transition exists and if it is terminated by a critical point, the addition of a solute should generate a line of liquid-liquid critical points emanating from the critical point of pure metastable water. We have analyzed thermodynamic consequences of this scenario. In particular, we consider the behavior of two systems, H2O-NaCl and H2O-glycerol. We find the behavior of the heat capacity in supercooled aqueous solutions of NaCl, as reported by Archer and Carter, to be consistent with the presence of the metastable liquid-liquid transition. We suggest an interpretation of the liquid-liquid transition in aqueous solutions of glycerol, recently observed by Murata and Tanaka, elucidating the non-conserved nature of the order parameter, its coupling with density and concentration, and the peculiarity of "spinodal decomposition without phase separation". We also show how the shape of the critical line in a solution controls the difference in concentration of the coexisting liquid phases.

John W. Biddle; Vincent Holten; Mikhail A. Anisimov

2014-08-21T23:59:59.000Z

396

Problems of trace element ratios and geothermometry in a gravel geothermal-aquifer system  

SciTech Connect (OSTI)

A Tertiary-age, block-faulted basin in which a Pleistocene gravel bed acts as a confined aquifer and permits the lateral dispersion of the geothermal fluids is studied. Basic data on geology and trace element holes presented previously are reproduced along with fluoride data. Evaluation of the phenomena in this system was attempted using a dissolved silica-enthalpy graph. A chalcedomy curve is also plotted. An enthalpy versus chloride plot suggests that either conductive cooling occurs before mixing or that higher chloride content background waters are available for mixing. (MHR)

Sonderegger, J.L.; Donovan, J.J.; Ruscetta, C.A.; Foley, D. (eds.)

1981-05-01T23:59:59.000Z

397

Deep Geothermal Reservoir Temperatures in the Eastern Snake River Plain, Idaho using Multicomponent Geothermometry  

SciTech Connect (OSTI)

The U.S. Geological survey has estimated that there are up to 4,900 MWe of undiscovered geothermal resources and 92,000 MWe of enhanced geothermal potential within the state of Idaho. Of particular interest are the resources of the Eastern Snake River Plain (ESRP) which was formed by volcanic activity associated with the relative movement of the Yellowstone Hot Spot across the state of Idaho. This region is characterized by a high geothermal gradient and thermal springs occurring along the margins of the ESRP. Masking much of the deep thermal potential of the ESRP is a regionally extensive and productive cold-water aquifer. We have undertaken a study to infer the temperature of the geothermal system hidden beneath the cold-water aquifer of the ESRP. Our approach is to estimate reservoir temperatures from measured water compositions using an inverse modeling technique (RTEst) that calculates the temperature at which multiple minerals are simultaneously at equilibrium while explicitly accounting for the possible loss of volatile constituents (e.g., CO2), boiling and/or water mixing. In the initial stages of this study, we apply the RTEst model to water compositions measured from a limited number of wells and thermal springs to estimate the regionally extensive geothermal system in the ESRP.

Ghanashyam Neupane; Earl D. Mattson; Travis L. McLing; Carl D. Palmer; Robert W. Smith; Thomas R. Wood

2014-02-01T23:59:59.000Z

398

Geothermometry At Clear Lake Area (Thompson, Et Al., 1992) | Open Energy  

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399

Geothermometry At Columbus Salt Marsh Area (Shevenell, Et Al., 2008) | Open  

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400

Geothermometry At Fish Lake Valley Area (DOE GTP) | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A SurveyInformationEnergyFish

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) | Open  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - A

402

Geothermometry At Long Valley Caldera Geothermal Area (McKenzie &  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) |1976)

403

Geothermometry At Long Valley Caldera Geothermal Area (Sorey, Et Al., 1991)  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation Hot2010) |1976)|

404

Geothermometry At Mt St Helens Area (Shevenell & Goff, 1995) | Open Energy  

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405

Geothermometry At Nevada Test And Training Range Area (Sabin, Et Al., 2004)  

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406

Geothermometry At Northern Basin & Range Region (Cole, 1983) | Open Energy  

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407

Geothermometry At Northern Basin & Range Region (Laney, 2005) | Open Energy  

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408

Geothermometry At Nw Basin & Range Region (Laney, 2005) | Open Energy  

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409

Geothermometry At Nw Basin & Range Region (Shevenell & De Rocher, 2005) |  

Open Energy Info (EERE)

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410

Geothermometry At Reese River Area (Henkle & Ronne, 2008) | Open Energy  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation|Open

411

Geothermometry At Salt Wells Area (Henkle, Et Al., 2005) | Open Energy  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation|Open1978) |

412

Geothermometry At Socorro Mountain Area (Owens, Et Al., 2005) | Open Energy  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico - AInformation|Open1978)

413

Geothermometry At Teels Marsh Area (Coolbaugh, Et Al., 2006) | Open Energy  

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414

Geothermometry At Teels Marsh Area (Shevenell, Et Al., 2008) | Open Energy  

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415

Geothermometry At U.S. Midwest Region (Vugrinovich, 1987) | Open Energy  

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416

Geothermometry At Upper Hot Creek Ranch Area (Benoit & Blackwell, 2006) |  

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417

Geothermometry At Walker-Lane Transitional Zone Region (Laney, 2005) | Open  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -Information Shevenell,

418

Geothermometry At Walker-Lane Transitional Zone Region (Shevenell & De  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation, searchGeaugaInformation Mexico -Information Shevenell,Rocher,

419

Geothermometry At Desert Queen Area (Garchar & Arehart, 2008) | Open Energy  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourageInformation Desert Queen Area

420

Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl, Et Al.,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourageInformation Desert Queen

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Geothermometry At Neal Hot Springs Geothermal Area (U.S. Geothermal Inc.,  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourageInformation Desert Queen2008)

422

Geothermometry At Rhodes Marsh Area (Coolbaugh, Et Al., 2006) | Open Energy  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourageInformation

423

Geothermometry At Rhodes Marsh Area (Shevenell, Et Al., 2008) | Open Energy  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo encourageInformationInformation

424

Geothermometry At Salt Wells Area (Coolbaugh, Et Al., 2006) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchTo

425

Geothermometry At Salt Wells Area (Edmiston & Benoit, 1984) | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat Jump to: navigation, searchToInformation Edmiston & Benoit, 1984)

426

Liquid fuels production from biomass. Final report  

SciTech Connect (OSTI)

The current program to convert biomass into liquid hydrocarbon fuels is an extension of a previous program to ferment marine algae to acetic acid. In that study it was found that marine algae could be converted to higher aliphatic organic acids and that these acids could be readily removed from the fermentation broth by membrane or liquid-liquid extraction. It was then proposed to convert these higher organic acids via Kolbe electrolysis to aliphatic hydrocarbons, which may be used as a diesel fuel. The specific goals for the current porgram are: (1) establish conditions under which substrates other than marine algae may be converted in good yield to organic acids, here the primary task is methane suppression; (2) modify the current 300-liter fixed packed bed batch fermenter to operate in a continuous mode; (3) change from membrane extraction of organic acids to liquid-liquid extraction; (4) optimize the energy balance of the electrolytic oxidation process, the primary task is to reduce the working potential required for the electrolysis while maintaining an adequate current density; (5) scale the entire process up to match the output of the 300 liter fermenter; and (6) design pilot plant and commercial size plant (1000 tons/day) processes for converting biomass to liquid hydrocarbon fuels and perform an economic analysis for the 1000 ton/day design.

Levy, P. F.; Sanderson, J. E.; Ashare, E.; Wise, D. L.; Molyneaux, M. S.

1980-06-30T23:59:59.000Z

427

Process for stabilization of coal liquid fractions  

DOE Patents [OSTI]

Coal liquid fractions to be used as fuels are stabilized against gum formation and viscosity increases during storage, permitting the fuel to be burned as is, without further expensive treatments to remove gums or gum-forming materials. Stabilization is accomplished by addition of cyclohexanol or other simple inexpensive secondary and tertiary alcohols, secondary and tertiary amines, and ketones to such coal liquids at levels of 5-25% by weight with respect to the coal liquid being treated. Cyclohexanol is a particularly effective and cost-efficient stabilizer. Other stabilizers are isopropanol, diphenylmethanol, tertiary butanol, dipropylamine, triethylamine, diphenylamine, ethylmethylketone, cyclohexanone, methylphenylketone, and benzophenone. Experimental data indicate that stabilization is achieved by breaking hydrogen bonds between phenols in the coal liquid, thereby preventing or retarding oxidative coupling. In addition, it has been found that coal liquid fractions stabilized according to the invention can be mixed with petroleum-derived liquid fuels to produce mixtures in which gum deposition is prevented or reduced relative to similar mixtures not containing stabilizer.

Davies, Geoffrey (Boston, MA); El-Toukhy, Ahmed (Alexandria, EG)

1987-01-01T23:59:59.000Z

428

Damping of liquid sloshing by foams  

E-Print Network [OSTI]

When a container is set in motion, the free surface of the liquid starts to oscillate or slosh. Such effects can be observed when a glass of water is handled carelessly and the fluid sloshes or even spills over the rims of the container. However, beer does not slosh as readily as water, which suggests that foam could be used to damp sloshing. In this work, we study experimentally the effect on sloshing of a liquid foam placed on top of a liquid bath. We generate a monodisperse two-dimensional liquid foam in a rectangular container and track the motion of the foam. The influence of the foam on the sloshing dynamics is experimentally characterized: only a few layers of bubbles are sufficient to significantly damp the oscillations. We rationalize our experimental findings with a model that describes the foam contribution to the damping coefficient through viscous dissipation on the walls of the container. Then we extend our study to confined three-dimensional liquid foam and observe that the behavior of 2D and confined 3D systems are very similar. Thus we conclude that only the bubbles close to the walls have a significant impact on the dissipation of energy. The possibility to damp liquid sloshing using foam is promising in numerous industrial applications such as the transport of liquefied gas in tankers or for propellants in rocket engines.

Alban Sauret; François Boulogne; Jean Cappello; Emilie Dressaire; Howard A. Stone

2015-02-01T23:59:59.000Z

429

SEAPORT LIQUID NATURAL GAS STUDY  

SciTech Connect (OSTI)

The Seaport Liquid Natural Gas Study has attempted to evaluate the potential for using LNG in a variety of heavy-duty vehicle and equipment applications at the Ports of Los Angeles and Oakland. Specifically, this analysis has focused on the handling and transport of containerized cargo to, from and within these two facilities. In terms of containerized cargo throughput, Los Angeles and Oakland are the second and sixth busiest ports in the US, respectively, and together handle nearly 4.5 million TEUs per year. At present, the landside handling and transportation of containerized cargo is heavily dependent on diesel-powered, heavy-duty vehicles and equipment, the utilization of which contributes significantly to the overall emissions impact of port-related activities. Emissions from diesel units have been the subject of increasing scrutiny and regulatory action, particularly in California. In the past two years alone, particulate matter from diesel exhaust has been listed as a toxic air contaminant by CAM, and major lawsuits have been filed against several of California's largest supermarket chains, alleging violation of Proposition 65 statutes in connection with diesel emissions from their distribution facilities. CARE3 has also indicated that it may take further regulatory action relating to the TAC listing. In spite of these developments and the very large diesel emissions associated with port operations, there has been little AFV penetration in these applications. Nearly all port operators interviewed by CALSTART expressed an awareness of the issues surrounding diesel use; however, none appeared to be taking proactive steps to address them. Furthermore, while a less controversial issue than emissions, the dominance of diesel fuel use in heavy-duty vehicles contributes to a continued reliance on imported fuels. The increasing concern regarding diesel use, and the concurrent lack of alternative fuel use and vigorous emissions reduction activity at the Ports provide both the backdrop and the impetus for this study.

COOK,Z.

1999-02-01T23:59:59.000Z

430

Boiling of nuclear liquid in the micro-canonical ensemble  

E-Print Network [OSTI]

-dependence of the nuclear symmetry energy and the critical temperature of 1 #12;Boiling of nuclear liquid in the microBoiling of nuclear liquid in the micro-canonical ensemble K. Miyazaki E-mail: miyazakiro@rio.odn.ne.jp Abstract New calculus of the liquid-gas phase transition is developed for the boiling of nuclear liquid

431

ccsd00001732, Development behavior of liquid plasma produced by  

E-Print Network [OSTI]

water with a melted NaCl is used as a test liquid. The liquid plasma is produced by the fundamental waveccsd­00001732, version 2 ­ 7 Nov 2004 Development behavior of liquid plasma produced by YAG laser the hazardous material called the environment material. Then, the plasma produced in liquid by the laser light

432

Solvent-Resistant Photocurable "Liquid Teflon" for Microfluidic Device Fabrication  

E-Print Network [OSTI]

with photocurable perfluoropolyethers (PFPEs). PFPEs are a unique class of fluoropolymers that are liquids at room

Quake, Stephen R.

433

New iodocuprates(I) with N-heterocyclic molecules as the cations  

SciTech Connect (OSTI)

Under the hydrothermal conditions, the reactions between CuI, KI and bp/bpp (bp=4,4?-bipiperidine, bpp=1,3-bis(4-piperidyl)propane) in an acidic alcohol solution produced three new organically templated iodocuprates(I) as [H{sub 2}bp]{sub 2}[Cu{sub 2}I{sub 6}] 1, [tmbp][Cu{sub 2}I{sub 4}] 2 and [tmbpp] 2 [Cu{sub 4}I{sub 8}]·2H{sub 2}O 3 (tmbp{sup 2+}=N,N,N?,N?-tetramethyl-4,4?-bipiperidinium; tmbpp{sup 2+}=N,N,N?,N?-tetramethyl-1,3-bis(4-piperidyl)propane dication). X-ray analysis revealed that (i) tmbp{sup 2+} and tmbpp{sup 2+} in compounds 2 and 3 originated from the complete N-alklation of bp/bpp with CH{sub 3}OH; (ii) templated by H{sub 2}bp{sup 2+}, the inorganic anion [Cu{sub 2}I{sub 6}]{sup 2?} of 1 possesses a dinuclear structure, whereas templated by tmbp{sup 2+}, the inorganic anion [Cu{sub 2}I{sub 4}]{sup 2?} of 2 exhibits a one-dimensional (1D) chain structure; (iii) templated by tmbpp{sup 2+}, the inorganic anion [Cu{sub 4}I{sub 8}]{sup 4?} of 3 shows a cubane-like structure modified by four terminal I{sup ?} ions. The photoluminescence analysis indicates that compounds 1 and 2 emit blue light, while compound 3 emits green light. - Graphical abstract: By employing hydrothermal in situ N-alkylation of bp/bpp with CH{sub 3}OH, three new organically templated iodocuprates(I) were obtained. Display Omitted - Highlights: • Three new organically templated iodocuprates(I) were reported. • Cations tmbp{sup 2+} and tmbpp{sup 2+} originated from in situ alkylation of bp/bpp with CH{sub 3}OH. • H{sup +} and I{sup ?} play a key role in alkylation of bp/bpp with CH{sub 3}OH. • Photoluminescence emission for iodocuprates(I) is related to Cu···Cu interaction.

Zhao, Jin-Jing [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Zhang, Xiao [State Key Lab of Urban Water Resource and Environment (SKLUWRE) and Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, Heilongjiang 150080 (China); Wang, Yan-Ning; Jia, Hong-Li [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Yu, Jie-Hui, E-mail: jhyu@jlu.edu.cn [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China); Xu, Ji-Qing, E-mail: xjq@mail.jlu.edu.cn [College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130023 (China)

2013-11-15T23:59:59.000Z

434

Liquid over-feeding air conditioning system and method  

DOE Patents [OSTI]

A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant.

Mei, Viung C. (Oak Ridge, TN); Chen, Fang C. (Knoxville, TN)

1993-01-01T23:59:59.000Z

435

Liquid over-feeding air conditioning system and method  

DOE Patents [OSTI]

A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant. 1 figure.

Mei, V.C.; Chen, F.C.

1993-09-21T23:59:59.000Z

436

Collection of liquid from below-ground location  

DOE Patents [OSTI]

A method of retrieving liquid from a below-ground collection area by permitting gravity flow of the liquid from the collection area to a first closed container; monitoring the level of the liquid in the closed container; and after the liquid reaches a given level in the first closed container, transferring the liquid to a second closed container disposed at a location above the first closed container, via a conduit, by introducing into the first closed container a gas which is substantially chemically inert with respect to the liquid, the gas being at a pressure sufficient to propel the liquid from the first closed container to the second closed container.

Phillips, Steven J. (Kennewick, WA); Alexander, Robert G. (Kennewick, WA)

1995-01-01T23:59:59.000Z

437

Fuel gas production by microwave plasma in liquid  

SciTech Connect (OSTI)

We propose to apply plasma in liquid to replace gas-phase plasma because we expect much higher reaction rates for the chemical deposition of plasma in liquid than for chemical vapor deposition. A reactor for producing microwave plasma in a liquid could produce plasma in hydrocarbon liquids and waste oils. Generated gases consist of up to 81% hydrogen by volume. We confirmed that fuel gases such as methane and ethylene can be produced by microwave plasma in liquid.

Nomura, Shinfuku; Toyota, Hiromichi; Tawara, Michinaga; Yamashita, Hiroshi; Matsumoto, Kenya [Graduate School of Science and Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577 (Japan); Shikoku Industry and Technology Promotion Center, 2-5 Marunouchi, Takamatsu, Kagawa 760-0033 (Japan)

2006-06-05T23:59:59.000Z

438

Rotor for processing liquids using movable capillary tubes  

DOE Patents [OSTI]

A rotor assembly for processing liquids, especially whole blood samples, is disclosed. The assembly includes apparatus for separating non-liquid components of whole blood samples from liquid components, apparatus for diluting the separated liquid component with a diluent and apparatus for transferring the diluted sample to an external apparatus for analysis. The rotor assembly employs several movable capillary tubes to handle the sample and diluents. A method for using the rotor assembly to process liquids is also described. 5 figs.

Johnson, W.F.; Burtis, C.A.; Walker, W.A.

1987-07-17T23:59:59.000Z

439

Gram-scale separation of curium from americium using alpha-hydroxyisobutyric acid in high-pressure cation columns  

SciTech Connect (OSTI)

Quantities of heavy element (americium and curium) up to 2.3 g have been successfully separated by chromatographic elution from cation resin using alpha-hydroxyisobutyrate in equipment originally designed for decigram-scale separations of /sup 252/Cf and heavier elements. The high-pressure ion exchange process was reliable and relatively easy to operate. Overall curium recoveries of 80 to 90% were readily achieved with decontamination from americium by factors of 400 to 500. The product and waste streams are both in forms readily coupled to further processing steps.

Bigelow, J.E.; Benker, D.E.; Chattin, F.R.; King, L.J.; Knauer, J.B.; Ross, R.G.; Stacy, R.G.; Wiggins, J.T.

1984-01-01T23:59:59.000Z

440

Influence of Heteroanion and Ammonium Cation Size on the Composition and Gas-Phase Fragmentation of Polyoxovanadates  

SciTech Connect (OSTI)

This paper describes the results of a systematic experimental investigation of the influence of different size cationic ammonium ligands and heteroanions on the composition, ionic charge state and gas-phase fragmentation pathways of anionic polyoxovanadates synthesized in solution. Four separate solutions of olyoxometalates (POMs) were prepared using all possible combinations of the tetraethylammonium [(C2H5)4N+] ligand, chloride (Cl-) heteroanion, tetrabutylammonium [(C4H9)4N+] ligand and acetate (CH3CO2-) heteroanion. Employing electrospray ionization combined with high-resolution mass spectrometry (ESI-MS) we demonstrate that POM solutions synthesized using the small [(C2H5)4N+] ligand and Cl-heteroanion are composed predominately of large doubly and triply charged chlorine containing clusters with a size distribution centered at fourteen vanadium atoms. POM solutions prepared using the Cl- anion and [(C4H9)4N+] ligand are shown to contain slightly larger clusters with fifteen and sixteen vanadium atoms, thereby indicating that the size of the cationic ammonium ligand exerts only a weak influence on the polymerization of polyoxovanadates. POM solutions prepared using (C2H5)4NCl and (C4H9)4NCl also produced peaks consistent with the attachment of one and two ammonium cations to the larger clusters. Solutions prepared using the large CH3CO2 - heteroanion, in contrast, are demonstrated to contain much smaller singly and doubly *Manuscript Click here to view linked References 2 charged clusters with a size distribution centered at six vanadium atoms. In addition, while incorporation of one and two ammonium ligands into the smaller clusters was observed, no POMs containing the CH3CO2 - heteroanion were identified. The gas-phase fragmentation pathways of representative POMs containing one and two ammonium ligands were examined using collision induced dissociation (CID) and mass spectrometry. Similar primary fragmentation pathways involving partial loss of a ligand -[(CxHy)3N+ x = 2,4; y = 5,9] were observed for clusters containing both one and two ligands largely independent of the size, composition and charge state of the precursor ion. The [(C4H9)4N+] ligand was found to exhibit stronger interactions with the core of the POMs resulting in higher abundances of fragment ions containing (C4H9) units compared to (C2H5) units from [(C2H5)4N+]. These results provide fundamental insight into the interactions between anionic metal oxide clusters, heteroanions and cationic ammonium ligands that are responsible for the size and composition controlled synthesis of POMs in solution.

Johnson, Grant E.; Al Hasan, Naila M.; Laskin, Julia

2013-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Liquid-Liquid Partitioning Methods for Bioseparations," Chapter 7 in the Handbook of  

E-Print Network [OSTI]

investigated in a book edited by Sekine and ~asegawa" entitled "Solvent Extraction Chemistry: Fundamentals The International Union of Pure and Applied Chemistry (IUPAC) recom- mends the use of liquid-liquid distribution pipette. The organic phase (solvent ~hase)is usually the top phase and the aqueous phase bottom phase

Gu, Tingyue

442

Images reveal that atmospheric particles can undergo liquid-liquid phase separations  

SciTech Connect (OSTI)

A large fraction of submicron atmospheric particles contains both organic material and inorganic salts. As the relative humidity cycles in the atmosphere, these mixed particles can undergo a range of phase transitions, possibly including liquid-liquid phase separation. If liquid-liquid phase separation occurs, the gas-particle partitioning of atmospheric semi-volatile organic compounds, the scattering and absorption of solar radiation, and the uptake of reactive gas species on atmospheric particles will be affected, with important implications for climate predictions. The actual occurrence of these types of phase transitions within individual atmospheric particles has been considered uncertain, in large part because of the absence of observations for real-world samples. Here, using optical and fluorescence microscopy, we observe the coexistence of two non-crystalline phases in particles generated from real-world samples collected on multiple days in Atlanta, Georgia, and in particles generated in the laboratory using atmospheric conditions. These results reveal that atmospheric particles can undergo liquid-liquid phase separations. Using a box model, we show that liquid-liquid phase separation can result in increased concentrations of gas-phase NO3 and N2O5 in the Atlanta region, due to decreased particle uptake of N2O5.

You, Yuan; Renbaum-Wolff, Lindsay; Carreras-Sospedra, Marc; Hanna, Sarah; Hiranuma, Naruki; Kamal, Saeid; Smith, Mackenzie L.; Zhang, Xiaolu; Weber, Rodney; Shilling, John E.; Dabdub, Donald; Martin, Scot T.; Bertram, Allan K.

2012-07-30T23:59:59.000Z

443

Quaternary liquid-liquid equilibrium of n-heptane-toluene-o-xylene-propylene carbonate  

SciTech Connect (OSTI)

Liquid-liquid equilibrium data for the system n-heptane/toluene/o-xylene/propylene carbonate were obtained at 25 OC. Experimental tie line data were measured by gas chromatographic analysis. The UNIQUAC and NRTL models were used to predict the quaternary data from the corresponding ternary data. Agreement between the predictions and the experimental data was satisfactory.

Salem, A.B.S.H.; Hamad, E.Z.; Al-Naafa, M.A. (King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia). Chemical Engineering Dept.)

1994-03-01T23:59:59.000Z

444

Liquid-liquid equilibria for ternary systems containing hydrocarbons and propylene carbonate  

SciTech Connect (OSTI)

Experimental data of liquid-liquid equillibrium at 20/sup 0/C are reported for six ternary systems containing propylene carbonate with n-hexane-benzene, n-hexane-ethylbenzene, n-heptane-toluene, n-heptane-ethylbenzene, n-octane-o-xylene, and n-octane-ethylbenzene. The data are correlated by means of NRTL and UNIQUAC models and relative parameters are given.

Annesini, M.C.; Gironi, F.; Marrelli, L.

1985-04-01T23:59:59.000Z

445

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces  

E-Print Network [OSTI]

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces allowed to self-assemble at the perfluorodecalin/water interface. These plates were fabricated from, the designs of hydrophobic edges necessary to generate menisci useful in self-assembly were different for 100

Prentiss, Mara

446

Continuous transitions between composite Fermi liquid and Landau Fermi liquid: A route to fractionalized Mott insulators  

E-Print Network [OSTI]

One of the most successful theories of a non-Fermi-liquid metallic state is the composite Fermi-liquid (CFL) theory of the half-filled Landau level. In this paper, we study continuous quantum phase transitions out of the ...

Barkeshli, Maissam

447

Liquid-absorption preconcentrator sampling instrument  

DOE Patents [OSTI]

A system for detecting trace concentrations of an analyte in air and includes a preconcentrator for the analyte and an analyte detector. The preconcentrator includes an elongated tubular container in which is disposed a wettable material extending substantially the entire length of the container. One end of the wettable material is continuously wetted with an analyte-sorbing liquid, which flows to the other end of the container. Sample air is flowed through the container in contact with the wetted material for trapping and preconcentrating the traces of analyte in the sorbing liquid, which is then collected at the other end of the container and discharged to the detector. The wetted material may be a wick comprising a bundle of fibers, one end of which is immersed in a reservoir of the analyte-sorbing liquid, or may be a liner disposed on the inner surface of the container, with the sorbing liquid being centrifugally dispersed onto the liner at one end thereof. The container is preferably vertically oriented so that gravity effects the liquid flow.

Zaromb, Solomon (Hinsdale, IL)

1990-01-01T23:59:59.000Z

448

Removal of arsenic compounds from petroliferous liquids  

DOE Patents [OSTI]

The present invention in one aspect comprises a process for removing arsenic from petroliferous-derived liquids by contacting said liquid with a divinylbenzene-crosslinked polystyrene polymer (i.e. PS-DVB) having catechol ligands anchored to said polymer, said contacting being at an elevated temperature. In another aspect, the invention is a process for regenerating spent catecholated polystyrene polymer by removal of the arsenic bound to it from contacting petroliferous liquid in accordance with the aspect described above which regenerating process comprises: (a) treating said spent catecholated polystyrene polymer with an aqueous solution of at least one member selected from the group consisting of carbonates and bicarbonates of ammonium, alkali metals, and alkaline earth metals, said solution having a pH between about 8 and 10, and said treating being at a temperature in the range of about 20/sup 0/ to 100/sup 0/C; (b) separating the solids and liquids from each other. In a preferred embodiment the regeneration treatment is in two steps wherein step: (a) is carried out with an aqueous alcoholic carbonate solution which includes at least one lower alkyl alcohol, and, steps (c) and (d) are added. Steps (c) and (d) comprise: (c) treating the solids with an aqueous alcoholic solution of at least one ammonium, alkali or alkaline earth metal bicarbonate at a temperature in the range of about 20 to 100/sup 0/C; and (d) separating the solids from the liquids.

Fish, R.H.

1984-04-06T23:59:59.000Z

449

Process for the production of liquid hydrocarbons  

DOE Patents [OSTI]

The present invention concerns a process for the preparation of liquid hydrocarbons which process comprises contacting synthesis gas with a slurry of solid catalyst particles and a liquid in a reactor vessel by introducing the synthesis gas at a low level into the slurry at conditions suitable for conversion of the synthesis gas into liquid hydrocarbons, the solid catalyst particles comprising a catalytic active metal selected from cobalt or iron on a porous refractory oxide carrier, preferably selected from silica, alumina, titania, zirconia or mixtures thereof, the catalyst being present in an amount between 10 and 40 vol. percent based on total slurry volume liquids and solids, and separating liquid material from the solid catalyst particles by using a filtration system comprising an asymmetric filtration medium (the selective side at the slurry side), in which filtration system the average pressure differential over the filtration medium is at least 0.1 bar, in which process the particle size distribution is such that at least a certain amount of the catalyst particles is smaller than the average pore size of the selective layer of the filtration medium. The invention also comprises an apparatus to carry out the process described above.

Bhatt, Bharat Lajjaram; Engel, Dirk Coenraad; Heydorn, Edward Clyde; Senden, Matthijis Maria

2006-06-27T23:59:59.000Z

450

Charge transfer reactions in nematic liquid crystals  

SciTech Connect (OSTI)

Ultrafast transient absorption studies of intramolecular photoinduced charge separation and thermal charge recombination were carried out on a molecule consisting of a 4-(N-pyrrolidino)naphthalene-1,8-imide donor (PNI) covalently attached to a pyromellitimide acceptor (PI) dissolved in the liquid crystal 4{prime}-(n-pentyl)-4-cyanobiphenyl (5CB). The temperature dependencies of the charge separation and recombination rates were obtained at temperatures above the nematic-isotropic phase transition of 5CB, where ordered microdomains exist and scattering of visible light by these domains is absent. The authors show that excited state charge separation is dominated by molecular reorientation of 5CB perpendicular to the director within the liquid crystal microdomains. They also show that charge recombination is adiabatic and is controlled by the comparatively slow collective reorientation of the liquid crystal microdomains relative to the orientation of PNI{sup +}-PI{sup {minus}}. They also report the results of time resolved electron paramagnetic resonance (TREPR) studies of photoinduced charge separation in a series of supramolecular compounds dissolved in oriented liquid crystal solvents. These studies permit the determination of the radical pair energy levels as the solvent reorganization energy increases from the low temperature crystalline phase, through the soft glass phase, to the nematic phase of the liquid crystal.

Wiederrecht, G.P. [Argonne National Lab., IL (United States). Chemistry Div.; Wasielewski, M.R. [Argonne National Lab., IL (United States). Chemistry Div.; [Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; Galili, T.; Levanon, H. [Hebrew Univ. of Jerusalem (Israel). Dept. of Physical Chemistry

1998-07-01T23:59:59.000Z

451

Double-duct liquid metal magnetohydrodynamic engine  

DOE Patents [OSTI]

An internal combustion, liquid metal (LM) magnetohydrodynamic (MHD) engine and an alternating current (AC) magnetohydrodynamic generator, are used in combination to provide useful AC electric energy output. The engine design has four pistons and a double duct configuration, with each duct containing sodium potassium liquid metal confined between free pistons located at either end of the duct. The liquid metal is forced to flow back and forth in the duct by the movement of the pistons, which are alternatively driven by an internal combustion process. In the MHD generator, the two LM-MHD ducts pass in close proximity through a Hartmann duct with output transformer. AC power is produced by operating the engine with the liquid metal in the two generator ducts always flowing in counter directions. The amount of liquid metal maintained in the ducts may be varied. This provides a variable stroke length for the pistons. The engine/generator provides variable AC power at variable frequencies that correspond to the power demands of the vehicular propulsion. Also the engine should maintain nearly constant efficiency throughout the range of power usage. Automobiles and trucks could be powered by the invention, with no transmission or power converter devices being required.

Haaland, Carsten M. (Oak Ridge, TN)

1997-01-01T23:59:59.000Z

452

Double-duct liquid metal magnetohydrodynamic engine  

DOE Patents [OSTI]

An internal combustion, liquid metal (LM) magnetohydrodynamic (MHD) engine and an alternating current (AC) magnetohydrodynamic generator, are used in combination to provide useful AC electric energy output. The engine design has-four pistons and a double duct configuration, with each duct containing sodium potassium liquid metal confined between free pistons located at either end of the duct. The liquid metal is forced to flow back and forth in the duct by the movement of the pistons, which are alternatively driven by an internal combustion process. In the MHD generator, the two LM-MHD ducts pass in close proximity through a Hartmann duct with output transformer. AC power is produced by operating the engine with the liquid metal in the two generator ducts always flowing in counter directions. The amount of liquid metal maintained in the ducts may be varied. This provides a variable stroke length for the pistons. The engine/generator provides variable AC power at variable frequencies that correspond to the power demands of the vehicular propulsion. Also the engine should maintain nearly constant efficiency throughout the range of power usage. Automobiles and trucks could be powered by the invention, with no transmission or power converter devices being required.

Haaland, Carsten M. (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

453

High throughput liquid absorption preconcentrator sampling instrument  

DOE Patents [OSTI]

A system for detecting trace concentrations of an analyte in air includes a preconcentrator for the analyte and an analyte detector. The preconcentrator includes an elongated tubular container comprising a wettable material. The wettable material is continuously wetted with an analyte-sorbing liquid which flows from one part of the container to a lower end. Sampled air flows through the container in contact with the wetted material with a swirling motion which results in efficient transfer of analyte vapors or aerosol particles to the sorbing liquid and preconcentration of traces of analyte in the liquid. The preconcentrated traces of analyte may be either detected within the container or removed therefrom for injection into a separate detection means or for subsequent analysis. 12 figs.

Zaromb, S.; Bozen, R.M.

1992-12-22T23:59:59.000Z

454

DOE studies on coal-to-liquids  

SciTech Connect (OSTI)

The US DOE National Energy Technology Laboratory has issued reports that examine the feasibility of coal-to-liquids (CTL) facilities, both general and site specific, which are available at www.netl.gov/energy-analyses/ref-shelf.html. The US Department of Defence has been investigating use of Fischer-Tropsch fuels. Congress is considering various CTL proposals while the private sector is building pilot plants and performing feasibility studies for proposed plants. The article includes a table listing 14 coal-to-liquids plants under consideration. The private sector has formed the coal-to-liquids coalition (www.futurecoalfuels.org). The article mentions other CTL projects in South Africa, China, Indonesia, the Philippines and New Zealand. 1 tab.

NONE

2007-07-01T23:59:59.000Z

455

Liquid injection plasma deposition method and apparatus  

DOE Patents [OSTI]

A liquid injection plasma torch deposition apparatus for depositing material onto a surface of a substrate may comprise a plasma torch for producing a jet of plasma from an outlet nozzle. A plasma confinement tube having an inlet end and an outlet end and a central bore therethrough is aligned with the outlet nozzle of the plasma torch so that the plasma jet is directed into the inlet end of the plasma confinement tube and emerges from the outlet end of the plasma confinement tube. The plasma confinement tube also includes an injection port transverse to the central bore. A liquid injection device connected to the injection port of the plasma confinement tube injects a liquid reactant mixture containing the material to be deposited onto the surface of the substrate through the injection port and into the central bore of the plasma confinement tube.

Kong, Peter C. (Idaho Falls, ID); Watkins, Arthur D. (Idaho Falls, ID)

1999-01-01T23:59:59.000Z

456

Combined Quantum Chemical/Raman Spectroscopic Analyses of Li+ Cation Solvation: Cyclic Carbonate Solvents - Ethylene Carbonate and Propylene Earbonate  

SciTech Connect (OSTI)

Combined computational/Raman spectroscopic analyses of ethylene carbonate (EC) and propylene carbonate (PC) solvation interactions with lithium salts are reported. It is proposed that previously reported Raman analyses of (EC)n-LiX mixtures have utilized faulty assumptions. In the present studies, density functional theory (DFT) calculations have provided corrections in terms of both the scaling factors for the solvent's Raman band intensity variations and information about band overlap. By accounting for these factors, the solvation numbers obtained from two different EC solvent bands are in excellent agreement with one another. The same analysis for PC, however, was found to be quite challenging. Commercially available PC is a racemic mixture of (S)- and (R)-PC isomers. Based upon the quantum chemistry calculations, each of these solvent isomers may exist as multiple conformers due to a low energy barrier for ring inversion, making deconvolution of the Raman bands daunting and inherently prone to significant error. Thus, Raman spectroscopy is able to accurately determine the extent of the EC...Li+ cation solvation interactions using the provided methodology, but a similar analysis of PC...Li+ cation solvation results in a significant underestimation of the actual solvation numbers.

Allen, Joshua L.; Borodin, Oleg; Seo, D. M.; Henderson, Wesley A.

2014-12-01T23:59:59.000Z

457

Self-Assembly of Nanostructured, Complex, Multi-cation Films via Spontaneous Phase Separation and Strain-driven Ordering  

SciTech Connect (OSTI)

Spontaneous self-assembly of a multi-cation nanophase in another multi-cation matrix phase is a promising bottom-up approach to fabricate novel, nanocomposite structures for a range of applications. In an effort to understand the mechanisms for such self-assembly, we report on complimentary experimental and theoretical studies to first understand and then control or guide the self-assembly of insulating BaZrO3 (BZO) nanodots within REBa2Cu3O7- (RE=rare earth elements including Y, REBCO) superconducting films. It was determined that the strain field developed around BZO nanodots embedded in REBCO matrix is a key driving force dictating the self-assembly of BZO nanodots along REBCO c-axis. The size selection and spatial ordering of BZO self-assembly were simulated using thermodynamic and kinetic models. The BZO self-assembly was controllable by tuning the interphase strain field. REBCO superconducting films with BZO defects arrays self-assembled to align in both vertical (REBCO c-axis) and horizontal (REBCO ab-planes) directions, resulted in the maximized pinning and Jc performance for all field angles with smaller angular Jc anisotropy. The work has broad implications for fabrication of controlled self-assembled nanostructures for a range of applications via strain-tuning.

Goyal, Amit [ORNL; Wee, Sung Hun [ORNL; Stocks, George Malcolm [ORNL; Zuev, Yuri L [ORNL; More, Karren Leslie [ORNL; Meng, Jianyong [ORNL; Zhong, Jianxin [ORNL

2013-01-01T23:59:59.000Z

458

Liquid Water Oceans in Ice Giants  

E-Print Network [OSTI]

Aptly named, ice giants such as Uranus and Neptune contain significant amounts of water. While this water cannot be present near the cloud tops, it must be abundant in the deep interior. We investigate the likelihood of a liquid water ocean existing in the hydrogen-rich region between the cloud tops and deep interior. Starting from an assumed temperature at a given upper tropospheric pressure (the photosphere), we follow a moist adiabat downward. The mixing ratio of water to hydrogen in the gas phase is small in the photosphere and increases with depth. The mixing ratio in the condensed phase is near unity in the photosphere and decreases with depth; this gives two possible outcomes. If at some pressure level the mixing ratio of water in the gas phase is equal to that in the deep interior, then that level is the cloud base. Alternately, if the mixing ratio of water in the condensed phase reaches that in the deep interior, then the surface of a liquid ocean will occur. We find that Neptune is both too warm (photospheric temperature too high) and too dry (mixing ratio of water in the deep interior too low) for liquid oceans to exist at present. To have a liquid ocean, Neptune's deep interior water to gas ratio would have to be higher than current models allow, and the density at 19 kbar would have to be ~ 0.8 g/cm^3. Such a high density is inconsistent with gravitational data obtained during the Voyager flyby. As Neptune cools, the probability of a liquid ocean increases. Extrasolar "hot Neptunes," which presumably migrate inward toward their parent stars, cannot harbor liquid water oceans unless they have lost almost all of the hydrogen and helium from their deep interiors.

Sloane J. Wiktorowicz; Andrew P. Ingersoll

2006-09-26T23:59:59.000Z

459

ICARUS and Status of Liquid Argon Technology  

E-Print Network [OSTI]

ICARUS is the largest liquid argon TPC detector ever built (~600 ton LAr mass). It operates underground at the LNGS laboratory in Gran Sasso. It has been smoothly running since summer 2010, collecting data with the CNGS beam and with cosmics. Liquid argon TPCs are really "electronic bubble chamber" providing a completely uniform imaging and calorimetry with unprecedented accuracy on massive volumes. ICARUS is internationally considered as a milestone towards the realization of the next generation of massive detectors (~tens of ktons) for neutrino and rare event physics. Results will be presented on the data collected during 2010 with the detector at LNGS.

Dorota Stefan

2011-10-07T23:59:59.000Z

460

Liquid additives for particulate emissions control  

DOE Patents [OSTI]

The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Hyatt, David E. (Denver, CO); Bustard, Cynthia Jean (Littleton, CO); Sjostrom, Sharon (Denver, CO)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

A priori estimates for relativistic liquid bodies  

E-Print Network [OSTI]

We demonstrate that a sufficiently smooth solution of the relativistic Euler equations that represents a dynamical compact liquid body, when expressed in Lagrangian coordinates, determines a solution to a system of non-linear wave equations with acoustic boundary conditions. Using this wave formulation, we prove that these solutions satisfy energy estimates without loss of derivatives. Importantly, our wave formulation does not require the liquid to be irrotational, and the energy estimates do not rely on divergence and curl type estimates employed in previous works.

Oliynyk, Todd A

2015-01-01T23:59:59.000Z

462

Anisotropic wave propagation in nematic liquid crystals  

E-Print Network [OSTI]

Despite the fact that quantitative experimental data have been available for more than forty years now, nematoacoustics still poses intriguing theoretical and experimental problems. In this paper, we prove that the main observed features of acoustic wave propagation through a nematic liquid crystal cell -- namely, the anisotropy of sound velocity and its frequency dependence -- may be plausibly explained by a first-gradient continuum theory characterized by a hyperelastic anisotropic response from an evolving relaxed configuration. We compare and contrast our proposal with a competing theory where the liquid crystal is modeled as an isotropically compressible, anisotropic second-gradient fluid.

Paolo Biscari; Antonio DiCarlo; Stefano S. Turzi

2014-05-10T23:59:59.000Z

463

Liquid Propane Injection Applications | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe10IO1OP001 LetterLight-Duty11.2.13 Liquid FuelsLiquid propane

464

A method of measuring a molten metal liquid pool volume  

DOE Patents [OSTI]

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figs.

Garcia, G.V.; Carlson, N.M., Donaldson, A.D.

1990-12-12T23:59:59.000Z

465

Charge transfer effects of ions at the liquid water/vapor interface  

SciTech Connect (OSTI)

Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 Å away from the surface.

Soniat, Marielle; Rick, Steven W., E-mail: srick@uno.edu [Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148 (United States)

2014-05-14T23:59:59.000Z

466

Tribological characteristics of aluminum alloys against steel lubricated by ammonium and imidazolium ionic liquids  

SciTech Connect (OSTI)

Sliding friction and wear characteristics of aluminum alloys against AISI 52100 steel lubricated by ionic liquids (ILs) were investigated at both room and elevated temperatures. The tested aluminum alloys include a commercially pure aluminum Al 1100, a wrought alloy Al 6061-T6511, and a cast alloy Al 319-T6. The lubricating performance of two ILs with the same anion, one ammonium-based [C8H17]3NH.Tf2N and one imidazolium-based C10mim.Tf2N, were compared each other and benchmarked against that of a conventional fully-formulated engine oil. Significant friction (up to 35%) and wear (up to 55%) reductions were achieved by the ammonium IL when lubricating the three aluminum alloys compared to the engine oil. The imidazolium IL performed better than the oil but not as well as the ammonium IL for Al 1100 and 319 alloys. However, accelerated wear was unexpectedly observed for Al 6061 alloy when lubricated by C10mim.Tf2N. Surface chemical analyses implied complex tribochemical reactions between the aluminum surfaces and ILs during the wear testing, which has been demonstrated either beneficial by forming a protective boundary film or detrimental by causing severe tribo-corrosion. The effects of the IL cation structure, aluminum alloy composition, and tribo-testing condition on the friction and wear results have been discussed.

Qu, Jun [ORNL; Blau, Peter Julian [ORNL; Dai, Sheng [ORNL; Luo, Huimin [ORNL; Meyer III, Harry M [ORNL; Truhan, John J. [Caterpillar Inc.

2009-01-01T23:59:59.000Z

467

Liquid-liquid extraction as the means of refining cottonseed oil  

E-Print Network [OSTI]

LIBRARY A 4 AI CvLLEGE OF TEXAS LIOVID-LIQUID EXTRACTION AS THE MEANS OI REFINING CCTTONSEFZ OIL A Thesis By 1'RVUBHAI CHIINIBHAI PATEL a 0 U z A R 0 Submitted to the Graduate School of the Agricultural and Mechanical College of Texas... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Auuust 1996 Major Subject Chemical ineeri LIQUID-LIQUID EXTRACTION AS THE MEANS OF REFINING COTTONSEED OIL A Thesis By MANUBHAI CHUNIBHAI PATEL Approved as to style...

Patel, Manubhai Chunibhai

1956-01-01T23:59:59.000Z

468

Effects of In{sub 3+} substitution on structural properties, cation distribution and Mössbauer spectra of CoFe{sub 2}O{sub 4} ferrite  

SciTech Connect (OSTI)

The use of non-destructive, high resolution technique namely Mössbauer spectroscopy is discussed in detail for the investigation of structural and magnetic properties of Fe based indium substituted cobalt ferrites. The polycrystalline samples of CoFe{sub 2?x}In{sub x}O{sub 4} (x = 0.2, 0.6) were prepared by double sintering solid state reaction method. To ensure a single phase formation of the as prepared samples the X-ray diffraction (XRD) data of the powdered samples was Rietveld refined using Fd3m space group. An excellent agreement is obtained between the integrated intensity ratios of 57 Fe spectra at A- and B-sites and those calculated on the basis of cation distribution the cation distribution obtained data analysis. The results of Mössbauer spectra and cation distribution are also correlated well with magnetization versus applied field (M-H) study.

Kumar, Ravi, E-mail: ranade65@gmail.com [Centre for Material Science and Engineering, National Institute of Technology Hamirpur (H.P.)-177005 (India); Pandit, Rabia; Sharma, K. K.; Kaur, Pawanpreet [Department of Physics, National Institute of Technology Hamirpur (H.P.)-177005 (India)

2014-04-24T23:59:59.000Z

469

Liquid uranium alloy-helium fission reactor  

DOE Patents [OSTI]

This invention teaches a nuclear fission reactor having a core vessel and at least one tandem heat exchanger vessel coupled therewith across upper and lower passages to define a closed flow loop. Nuclear fuel such as a uranium alloy in its liquid phase fills these vessels and flow passages. Solid control elements in the reactor core vessel are adapted to be adjusted relative to one another to control fission reaction of the liquid fuel therein. Moderator elements in the other vessel and flow passages preclude fission reaction therein. An inert gas such as helium is bubbled upwardly through the heat exchanger vessel operable to move the liquid fuel upwardly therein and unidirectionally around the closed loop and downwardly through the core vessel. This helium gas is further directed to heat conversion means outside of the reactor vessels to utilize the heat from the fission reaction to generate useful output. The nuclear fuel operates in the 1200.degree.-1800.degree. C. range, and even higher to 2500.degree. C., limited only by the thermal effectiveness of the structural materials, increasing the efficiency of power generation from the normal 30-35% with 300.degree.-500.degree. C. upper limit temperature to 50-65%. Irradiation of the circulating liquid fuel, as contrasted to only localized irradiation of a solid fuel, provides improved fuel utilization.

Minkov, Vladimir (Skokie, IL)

1986-01-01T23:59:59.000Z

470

Improved liquid-film electron stripper  

DOE Patents [OSTI]

An improved liquid-film electron stripper particularly for high intensity heavy ion beams which produces constant regenerated, stable, free-standing liquid films having an adjustable thickness between 0.3 to 0.05 microns. The improved electron stripper is basically composed of at least one high speed, rotating disc with a very sharp, precision-like, ground edge on one side of the disc's periphery and with highly polished, flat, radial surface adjacent the sharp edge. A fine stream of liquid, such as oil, impinges at a 90/sup 0/ angle adjacent the disc's sharp outer edge. Film terminators, located at a selected distance from the disc perimeter are positioned approximately perpendicular to the film. The terminators support, shape, and stretch the film and are arranged to assist in the prevention of liquid droplet formation by directing the collected film to a reservoir below without breaking or interfering with the film. One embodiment utilizes two rotating discs and associated terminators, with the discs rotating so as to form films in opposite directions, and with the second disc being located down beam-line relative to the first disc.

Gavin, B.F.

1984-11-01T23:59:59.000Z

471

Liquid Fuels from Lignins: Annual Report  

SciTech Connect (OSTI)

This task was initiated to assess the conversion of lignins into liquid fuels, primarily of lignins relevant to biomass-to-ethanol conversion processes. The task was composed of a literature review of this area and an experimental part to obtain pertinent data on the conversion of lignins germane to biomass-to-ethanol conversion processes.

Chum, H. L.; Johnson, D. K.

1986-01-01T23:59:59.000Z

472

UV STABILITY OF HIGH BIREFIRNGENCE LIQUID CRYSTALS  

E-Print Network [OSTI]

nm, the major UV light used for curing sealant. The material degradation is believed to originate experimental results indicate that the UV degradation not only depends on the absorption wavelength but alsoUV STABILITY OF HIGH BIREFIRNGENCE LIQUID CRYSTALS Pao-Tai Lin and Shin-Tson Wu School of Optics

Wu, Shin-Tson

473

Local Energy Landscape in a Simple Liquid  

E-Print Network [OSTI]

It is difficult to relate the properties of liquids and glasses directly to their structure because of complexity in the structure which defies precise definition. The potential energy landscape (PEL) approach is a very insightful way to conceptualize the structure-property relationship in liquids and glasses, particularly on the effect of temperature and history. However, because of the highly multi-dimensional nature of the PEL it is hard to determine, or even visualize, the actual details of the energy landscape. In this article we introduce a modified concept of the local energy landscape (LEL) which is limited in phase space, and demonstrate its usefulness using molecular dynamics simulation on a simple liquid at high temperatures. The local energy landscape is given as a function of the local coordination number, the number of the nearest neighbor atoms. The excitations in the LEL corresponds to the so-called beta-relaxation process. The LEL offers a simple but useful starting point to discuss complex phenomena in liquids and glasses.

Takuya Iwashita; Takeshi Egami

2014-10-31T23:59:59.000Z

474

Organizing Carbon Nanotubes with Liquid Crystals  

E-Print Network [OSTI]

Organizing Carbon Nanotubes with Liquid Crystals Michael D. Lynch and David L. Patrick* Department, 2002; Revised Manuscript Received September 13, 2002 ABSTRACT Single- and multiwalled carbon nanotubes- and multiwalled carbon nanotubes (SWCNT and MWCNT) are of particular interest because these materials

Patrick, David L.

475

Laser Micromachining: Advantages of Liquid Environments  

E-Print Network [OSTI]

Laser Micromachining: Advantages of Liquid Environments Marc J. Palmeri Princeton University Arnold Lab #12;Outline · Motivation ­ Applications of laser micromachining ­ Problems with laser micromachining · How do lasers work? · What is laser micromachining? · Micromachining assembly · Methods

Petta, Jason

476

Natural gas liquids remain strong petrochemical feedstock  

SciTech Connect (OSTI)

The supply of petrochemical feedstocks in the USA are discussed. The US petrochemical network starts with three main sources, i.e., olefins, aromatics, and natural gas. Petrochemical technology has been pushed to lower costs and improve yields in the face of a determined market drive from new petrochemical producing regions with vast supplies of low-cost gas liquids.

Greek, B.F.

1984-03-12T23:59:59.000Z

477

Supporting Information Liquid Crystalline Peptide Nanowires**  

E-Print Network [OSTI]

1 Supporting Information Liquid Crystalline Peptide Nanowires** Tae Hee Han, Jangbae Kim, Ji Sun Park, Chan Beum Park, Hyotcherl Ihee,* and Sang Ouk Kim* #12;2 Figure S1. Size distribution of as orientation effect was also considered by using the March-Dollase function. The global isotropic temperature

Ihee, Hyotcherl

478

Extremely correlated quantum liquids B. Sriram Shastry  

E-Print Network [OSTI]

Extremely correlated quantum liquids B. Sriram Shastry Physics Department, University of California; published 20 January 2010 Extreme correlations arise as the limit of strong correlations, when the local-J model, embodying such extreme correlations. We formulate the picture of an extremely correlated electron

California at Santa Cruz, University of

479

Engineering-Scale Liquid Cadmium Cathode Experiments  

SciTech Connect (OSTI)

Recovery of transuranic actinides (TRU) using electrorefining is a process being investigated as part of the Department of Energy (DOE) Advanced Fuel Cycle Initiative (AFCI). TRU recovery via electrorefining onto a solid cathode is very difficult as the thermodynamic properties of transuranics are not favourable for them to remain in the metal phase while significant quantities of uranium trichloride exist in the electrolyte. Theoretically, the concentration of transuranics in the electrolyte must be approximately 106 greater than the uranium concentration in the electrolyte to produce a transuranic deposit on a solid cathode. Using liquid cadmium as a cathode contained within a LiCl-KCl eutectic salt, the co-deposition of uranium and transuranics is feasible because the activity of the transuranics in liquid cadmium is very small. Depositing transuranics and uranium in a liquid cadmium cathode (LCC) theoretically requires the concentration of transuranics to be two to three times the uranium concentration in the electrolyte. Three LCC experiments were performed in an Engineering scale elecdtrorefiner, which is located in the argon hot cell of the Fuel Conditioning Facility at the Materials and Fuels Complex on the Idaho National Laboratory. Figure 1 contains photographs of the LCC assembly in the hot cell prior to the experiment and a cadmium ingot produced after the first LCC test. Figure 1. Liquid Cadmium Cathode (left) and Cadmium Ingot (right) The primary goal of the engineering-scale liquid cadmium cathode experiments was to electrochemically collect kilogram quantities of uranium and plutonium via a LCC. The secondary goal was to examine fission product contaminations in the materials collected by the LCC. Each LCC experiment used chopped spent nuclear fuel from the blanket region of the Experimental Breeder Reactor II loaded into steel baskets as the anode with the LCC containing 26 kg of cadmium metal. In each experiment, between one and two kilograms of heavy metal was collected in the LCC after passing an integrated current over 500 amp hours. Analysis of samples from the liquid cadmium cathode ingots showed detectable amounts of transuranics and rare-earth elements. Acknowledgements K. B. Davies and D. M. Pace for the mechanical and electrical engineering needed to prepare the equipment for the engineering-scale liquid cadmium cathode experiments.

D Vaden; B. R. Westphal; S. X. Li; T. A. Johnson; K. B. Davies; D. M. Pace

2006-08-01T23:59:59.000Z

480

Modeling the operating voltage of liquid metal battery cells  

E-Print Network [OSTI]

A one-dimensional, integrative model of the voltage during liquid metal battery operation has been developed to enhance the understanding of performance at the cell level. Two liquid metal batteries were studied: Mg-Sb for ...

Newhouse, Jocelyn Marie

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid geothermometry cation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Liquid Nitrogen Ice Cream (1st Grade) Lesson Plan  

E-Print Network [OSTI]

substance. Materials: 5 or more Liters of liquid nitrogen (gloves, goggles, and lab coat recommended the liquid nitrogen and safety gear you wear have fun with it!) 4. Mix heavy cream, half & half, and sugar

482

Performance Characteristics of Coal-to-Liquids (CTL) Diesel in...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Characteristics of Coal-to-Liquids (CTL) Diesel in a 50-State Emissions Compliant Passenger Car Performance Characteristics of Coal-to-Liquids (CTL) Diesel in a 50-State Emissions...

483

Process to upgrade coal liquids by extraction prior to hydrodenitrogenation  

DOE Patents [OSTI]

Oxygen compounds are removed, e.g., by extraction, from a coal liquid prior to its hydrogenation. As a result, compared to hydrogenation of such a non-treated coal liquid, the rate of nitrogen removal is increased.

Schneider, Abraham (Overbrook Hills, PA); Hollstein, Elmer J. (Wilmington, DE); Janoski, Edward J. (Havertown, PA); Scheibel, Edward G. (Media, PA)

1982-01-01T23:59:59.000Z

484

System for removing liquid waste from a tank  

DOE Patents [OSTI]

A tank especially suited for nuclear applications is disclosed. The tank comprises a tank shell for protectively surrounding the liquid contained therein; an inlet positioned on the tank for passing a liquid into the tank; a sump positioned in an interior portion of the tank for forming a reservoir of the liquid; a sloped incline for resting the tank thereon and for creating a natural flow of the liquid toward the sump; a pump disposed adjacent the tank for pumping the liquid; and a pipe attached to the pump and extending into the sump for passing the liquid therethrough. The pump pumps the liquid in the sump through the pipe and into the pump for discharging the liquid out of the tank.

Meneely, Timothy K. (Penn Hills, PA); Sherbine, Catherine A. (N. Versailles Township, Allegheny County, PA)

1994-01-01T23:59:59.000Z

485

Systems and methods for monitoring a solid-liquid interface  

DOE Patents [OSTI]

Systems and methods are provided for monitoring a solid-liquid interface during a casting process. The systems and methods enable determination of the location of a solid-liquid interface during the casting process.

Stoddard, Nathan G; Lewis, Monte A.; Clark, Roger F

2013-06-11T23:59:59.000Z

486

Sandia National Laboratories: "Bionic" Liquids from Lignin: Joint...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy and ClimateECEnergyRenewable EnergyBiofuels"Bionic" Liquids from Lignin: Joint BioEnergy Institute Results Pave the Way for Closed-Loop Biofuel Refineries "Bionic" Liquids...

487

System for removing liquid waste from a tank  

DOE Patents [OSTI]

A tank especially suited for nuclear applications is disclosed. The tank comprises a tank shell for protectively surrounding the liquid contained therein; an inlet positioned on the tank for passing a liquid into the tank; a sump positioned in an interior portion of the tank for forming a reservoir of the liquid; a sloped incline for resting the tank thereon and for creating a natural flow of the liquid toward the sump; a pump disposed adjacent the tank for pumping the liquid; and a pipe attached to the pump and extending into the sump for passing the liquid there through. The pump pumps the liquid in the sump through the pipe and into the pump for discharging the liquid out of the tank. 2 figures.

Meneely, T.K.; Sherbine, C.A.

1994-04-26T23:59:59.000Z

488

Dependence of solid-liquid interface free energy on liquid structure  

SciTech Connect (OSTI)

The Turnbull relation is widely believed to enable prediction of solid–liquid interface (SLI) free energies from measurements of the latent heat and the solid density. Ewing proposed an additional contribution to the SLI free energy to account for variations in liquid structure near the interface. In the present study, molecular dynamics (MD) simulations were performed to investigate whether SLI free energy depends on liquid structure. Analysis of the MD simulation data for 11 fcc metals demonstrated that the Turnbull relation is only a rough approximation for highly ordered liquids, whereas much better agreement is observed with Ewing’s theory. A modification to Ewing’s relation is proposed in this study that was found to provide excellent agreement with MD simulation data.

Wilson, S R [Ames Laboratory; Mendelev, M I [Ames Laboratory

2014-09-01T23:59:59.000Z

489

Laser capillary spectrophotometric acquisition of bivariate drop size and concentration data for liquid-liquid dispersion  

DOE Patents [OSTI]

A laser capillary spectrophotometric technique measures real time or near real time bivariate drop size and concentration distribution for a reactive liquid-liquid dispersion system. The dispersion is drawn into a precision-bore glass capillary and an appropriate light source is used to distinguish the aqueous phase from slugs of the organic phase at two points along the capillary whose separation is precisely known. The suction velocity is measured, as is the length of each slug from which the drop free diameter is calculated. For each drop, the absorptivity at a given wavelength is related to the molar concentration of a solute of interest, and the concentration of given drops of the organic phase is derived from pulse heights of the detected light. This technique permits on-line monitoring and control of liquid-liquid dispersion processes. 17 figures.

Tavlarides, L.L.; Bae, J.H.

1991-12-24T23:59:59.000Z

490

Study of liquid retention in fixed-bed reactors with upward flow of gas and liquid  

SciTech Connect (OSTI)

A literature survey of the measurement techniques for the determination of liquid retention in cocurrent upward gas and liquid flow in fixed-bed reactors is presented. A number of these techniques were used in this work in columns of different diameters (Dc = 0.05 m, 0.10 m, and 0.15 m). Porous alumina particles of two different diameters (dp = 0.002 m and 0.0028 m) with both nonfoaming (water, cyclohexane, heptane, and propanol) and foaming liquids (kerosene, LCO, and diesel fuel) have been investigated. The gas used was either air or N[sub 2]. The methods investigated include volumetry, gravimetry, gammametry, and determination of residence-time distribution by tracer technique. A simple correlation for the prediction of total gas and liquid retention for bubble and pulsed flow is proposed and verified.

Yang, X.L.; Euzen, J.P. (Inst. Francais du Petrole, Vernaison (France)); Wild, G. (Lab. des Sciences du Genie Chimique, Nancy (France))

1993-01-01T23:59:59.000Z

491

MagViz Bottled Liquid Scanner at Albuquerque International Sunport  

ScienceCinema (OSTI)

The next-generation bottled liquid scanner, MagViz BLS, is demonstrated at the Albuquerque International Sunport, New Mexico

Surko, Stephen; Dennis, Steve; Espy, Michelle

2014-08-12T23:59:59.000Z

492

Metal-air low temperature ionic liquid cell  

DOE Patents [OSTI]

The present application relates to an electrochemical metal-air cell in which a low temperature ionic liquid is used.

Friesen, Cody A; Buttry, Daniel A

2014-11-25T23:59:59.000Z

493

Plasmas in Multiphase Media: Bubble Enhanced Discharges in Liquids and Plasma/Liquid Phase Boundaries  

SciTech Connect (OSTI)

In this research project, the interaction of atmospheric pressure plasmas with multi-phase media was computationally investigated. Multi-phase media includes liquids, particles, complex materials and porous surfaces. Although this investigation addressed fundamental plasma transport and chemical processes, the outcomes directly and beneficially affected applications including biotechnology, medicine and environmental remediation (e.g., water purification). During this project, we made advances in our understanding of the interaction of atmospheric pressure plasmas in the form of dielectric barrier discharges and plasma jets with organic materials and liquids. We also made advances in our ability to use computer modeling to represent these complex processes. We determined the method that atmospheric pressure plasmas flow along solid and liquid surfaces, and through endoscopic like tubes, deliver optical and high energy ion activation energy to organic and liquid surfaces, and produce reactivity in thin liquid layers, as might cover a wound. We determined the mechanisms whereby plasmas can deliver activation energy to the inside of liquids by sustaining plasmas in bubbles. These findings are important to the advancement of new technology areas such as plasma medicine

Kushner, Mark Jay [University of Michigan] [University of Michigan

2014-07-10T23:59:59.000Z

494

Liquid Lithium Limiter Effects on Tokamak Plasmas and Plasma-Liquid Surface Interactions  

SciTech Connect (OSTI)

We present results from the first experiments with a large area liquid lithium limiter in a magnetic fusion device, and its effect on improving plasma performance by reducing particle recycling. Using large area liquid metal surfaces in any major fusion device is unlikely before a test on a smaller scale. This has motivated its demonstration in the CDX-U spherical torus with a unique, fully toroidal lithium limiter. The highest current discharges were obtained with a liquid lithium limiter. There was a reduction in recycling, as indicated by a significant decrease in the deuterium-alpha emission and oxygen radiation. How these results might extrapolate to reactors is suggested in recycling/retention experiments with liquid lithium surfaces under high-flux deuterium and helium plasma bombardment in PISCES-B. Data on deuterium atoms retained in liquid lithium indicate retention of all incident ions until full volumetric conversion to lithium deuteride. The PISCES-B results also show a material loss mechanism that lowers the maximum operating temperature compared to that for the liquid surface equilibrium vapor pressure. This may restrict the lithium temperature in reactors.

R. Kaita; R. Majeski; R. Doerner; G. Antar; M. Baldwin; R. Conn; P. Efthimion; M. Finkenthal; D. Hoffman; B. Jones; S. Krashenninikov; H. Kugel; S. Luckhardt; R. Maingi; J. Menard; T. Munsat; D. Stutman; G. Taylor; J. Timberlake; V. Soukhanovskii; D. Whyte; R. Woolley; L. Zakharov

2002-10-15T23:59:59.000Z

495

Liquid crystals and Q-tensors The free energy  

E-Print Network [OSTI]

Liquid crystals and Q-tensors The free energy A temperature-dependent model Mathematical results #12;Liquid crystals and Q-tensors The free energy A temperature-dependent model Mathematical results, Non-isothermal nematic liquid crystals flows with the Ball-Majumdar free energy, Ann. Mat. Pura Appl

Segatti, Antonio

496

(Electron transfer rates at semiconductor/liquid interfaces)  

SciTech Connect (OSTI)

Work has focused on several aspects of the fundamental chemistry and physics semiconductor/liquid junction behavior. These projects have been directed primarily towards GaAs/liquid contacts, because GaAs/liquid systems provide high energy conversion efficiencies and offer an opportunity to gain mechanistic understanding of the factors that are important to control in an efficient photoelectrochemical energy conversion system.

Lewis, N.S.

1992-01-01T23:59:59.000Z

497

[Electron transfer rates at semiconductor/liquid interfaces]. Progress report  

SciTech Connect (OSTI)

Work has focused on several aspects of the fundamental chemistry and physics semiconductor/liquid junction behavior. These projects have been directed primarily towards GaAs/liquid contacts, because GaAs/liquid systems provide high energy conversion efficiencies and offer an opportunity to gain mechanistic understanding of the factors that are important to control in an efficient photoelectrochemical energy conversion system.

Lewis, N.S.

1992-08-01T23:59:59.000Z

498

RF cavity using liquid dielectric for tuning and cooling  

DOE Patents [OSTI]

A system for accelerating particles includes an RF cavity that contains a ferrite core and a liquid dielectric. Characteristics of the ferrite core and the liquid dielectric, among other factors, determine the resonant frequency of the RF cavity. The liquid dielectric is circulated to cool the ferrite core during the operation of the system.

Popovic, Milorad (Warrenville, IL); Johnson, Rolland P. (Newport News, VA)

2012-04-17T23:59:59.000Z

499

Energy Landscape Diversity and Supercooled Liquid Properties Frank H. Stillingera  

E-Print Network [OSTI]

typically exhibit little difference between liquid and crystal heat capacities Cp , and tend to have of the latter have liquid heat capacities that are significantly larger than the corresponding crystal values of the so-called "Kauzmann paradox". 5 The supercooled-liquid versus crystal heat capacity discrepancy, when

Stillinger, Frank

500

The physics of liquid water Bernard Cabane1  

E-Print Network [OSTI]

with extraordinary properties: it has unusually high melting and boiling temperatures, a huge heat capacity, oneThe physics of liquid water Bernard Cabane1 , Rodolphe Vuilleumier2 1 PMMH, ESPCI, 10 rue Vauquelin, France Abstract Liquid water is a liquid with extraordinary properties: it has a very high cohesion

Paris-Sud XI, Université de