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1

Liquid Transportation Fuels from Coal and Biomass  

E-Print Network (OSTI)

Liquid Transportation Fuels from Coal and Biomass Technological Status, Costs, and Environmental Katzer #12;CHARGE TO THE ALTF PANEL · Evaluate technologies for converting biomass and coal to liquid for liquid fuels produced from coal or biomass. · Evaluate environmental, economic, policy, and social

2

Enzymantic Conversion of Coal to Liquid Fuels  

DOE Green Energy (OSTI)

The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time, corresponding to the consumption of aromatic intermediates as they undergo ring cleavage. The results show that this process happens within 1 hour when using extracellular enzymes, but takes several days when using live organisms. In addition, live organisms require specific culture conditions, control of contaminants and fungicides in order to effectively produce extracellular enzymes that degrade coal. Therefore, when comparing the two enzymatic methods, results show that the process of using extracellular lignin degrading enzymes, such as laccase and manganese peroxidase, appears to be a more efficient method of decomposing bituminous coal.

Richard Troiano

2011-01-31T23:59:59.000Z

3

A fresh look at coal-derived liquid fuels  

Science Conference Proceedings (OSTI)

35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

Paul, A.D. [Benham Companies LLC (USA)

2009-01-15T23:59:59.000Z

4

Production of jet fuels from coal-derived liquids  

Science Conference Proceedings (OSTI)

Samples of jet fuel (JP-4, JP-8, JP-8X) produced from the liquid by-products of the gasification of lignite coal from the Great Plains Gasification Plant were analyzed to determine the quantity and type of organo-oxygen compounds present. Results were compared to similar fuel samples produced from petroleum. Large quantities of oxygen compounds were found in the coal-derived liquids and were removed in the refining process. Trace quantities of organo-oxygenate compounds were suspected to be present in the refined fuels. Compounds were identified and quantified as part of an effort to determine the effect of these compounds in fuel instability. Results of the analysis showed trace levels of phenols, naphthols, benzofurans, hexanol, and hydrogenated naphthols were present in levels below 100 ppM. 9 figs., 3 tabs.

Knudson, C.L.

1990-06-01T23:59:59.000Z

5

Producing liquid fuels from coal: prospects and policy issues  

Science Conference Proceedings (OSTI)

The increase in world oil prices since 2003 has prompted renewed interest in producing and using liquid fuels from unconventional resources, such as biomass, oil shale, and coal. This book focuses on issues and options associated with establishing a commercial coal-to-liquids (CTL) industry within the United States. It describes the technical status, costs, and performance of methods that are available for producing liquids from coal; the key energy and environmental policy issues associated with CTL development; the impediments to early commercial experience; and the efficacy of alternative federal incentives in promoting early commercial experience. Because coal is not the only near-term option for meeting liquid-fuel needs, this book also briefly reviews the benefits and limitations of other approaches, including the development of oil shale resources, the further development of biomass resources, and increasing dependence on imported petroleum. A companion document provides a detailed description of incentive packages that the federal government could offer to encourage private-sector investors to pursue early CTL production experience while reducing the probability of bad outcomes and limiting the costs that might be required to motivate those investors. (See Rand Technical Report TR586, Camm, Bartis, and Bushman, 2008.) 114 refs., 2 figs., 16 tabs., 3 apps.

James T. Bartis; Frank Camm; David S. Ortiz

2008-07-01T23:59:59.000Z

6

NETL: Coal & Coal Biomass to Liquids - Hydrogen and Clean Fuels...  

NLE Websites -- All DOE Office Websites (Extended Search)

Strategies Central Hydrogen Production Coal Supply Regions CLICK ON IMAGE TO SEE LARGER VIEW Coal is a plentiful domestic resource, and is available in several major regions of the...

7

NETL: Coal & Coal Biomass to Liquids - Hydrogen and Clean Fuels...  

NLE Websites -- All DOE Office Websites (Extended Search)

of hydrogen and nitrogen. CLICK ON IMAGE TO SEE LARGER VIEW Hydrogen is produced from coal in a process that is similar to SMR but more complex because coal is not a single...

8

EVALUATION OF COAL-DERIVED LIQUIDS AS BOILER FUELS Volume 1  

Science Conference Proceedings (OSTI)

A combustion demonstration using six coal-derived liquid fuels indicated that these fuels are suitable for use in utility boilers. These fuels, exhibiting acceptable emissions and performance, would require only minimal fuel system modifications.

1985-09-20T23:59:59.000Z

9

EVALUATION OF COAL-DERIVED LIQUIDS AS BOILER FUELS Volume 4  

Science Conference Proceedings (OSTI)

A combustion demonstration using six coal-derived liquid fuels indicated that these fuels are suitable for use in utility boilers. These fuels, exhibiting acceptable emissions and performance, would require only minimal fuel system modifications.

1985-09-24T23:59:59.000Z

10

EVALUATION OF COAL-DERIVED LIQUIDS AS BOILER FUELS Volume 3  

Science Conference Proceedings (OSTI)

A combustion demonstration using six coal-derived liquid fuels indicated that these fuels are suitable for use in utility boilers. These fuels, exhibiting acceptable emissions and performance, would require only minimal fuel system modifications.

1985-09-24T23:59:59.000Z

11

EVALUATION OF COAL-DERIVED LIQUIDS AS BOILER FUELS Volume 5  

Science Conference Proceedings (OSTI)

A combustion demonstration using six coal-derived liquid fuels indicated that these fuels are suitable for use in utility boilers. These fuels, exhibiting acceptable emissions and performance, would require only minimal fuel system modifications.

1985-09-20T23:59:59.000Z

12

EVALUATION OF COAL-DERIVED LIQUIDS AS BOILER FUELS Volume 2  

Science Conference Proceedings (OSTI)

A combustion demonstration using six coal-derived liquid fuels indicated that these fuels are suitable for use in utility boilers. These fuels, exhibiting acceptable emissions and performance, would require only minimal fuel system modifications.

1985-09-19T23:59:59.000Z

13

NETL: Coal & Coal Biomass to Liquids - Hydrogen and Clean Fuels...  

NLE Websites -- All DOE Office Websites (Extended Search)

Deepwater Technology Enhanced Oil Recovery Gas Hydrates Natural Gas Resources Contacts Coal & Power Systems Major Demonstrations Innovations for Existing Plants Gasification...

14

Liquid Tin Anode Direct Coal Fuel Cell - CellTech Power  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Tin Anode Direct Coal Liquid Tin Anode Direct Coal Fuel Cell-CellTech Power Background Direct carbon solid oxide fuel cells (SOFCs) offer a theoretical efficiency advantage over traditional SOFCs operating on gasified carbon (syngas). CellTech Power LLC (CellTech) has been developing a liquid tin anode (LTA) SOFC that can directly convert carbonaceous fuels including coal into electricity without gasification. One of the most significant impediments

15

Production of jet fuels from coal derived liquids  

SciTech Connect

Amoco and Lummus Crest have developed seven cases for upgrading by-product liquids from the Great Plains Coal Gasification Plant to jet fuels, and in several of the cases, saleable chemicals in addition to jet fuels. The analysis shows that the various grades of jet fuel can be produced from the Great Plains tar oil, but not economically. However, the phenolic and naphtha streams do have the potential to significantly increase (on the order of $10--15 million/year) the net revenues at Great Plains by producing chemicals, especially cresylic acid, cresol, and xylenol. The amount of these chemicals, which can be marketed, is a concern, but profits can be generated even when oxygenated chemical sales are limited to 10 percent of the US market. Another concern is that while commercial processes exist to extract phenolic mixtures, these processes have not been demonstrated with the Great Plains phenolic stream. 9 refs., 24 figs., 14 tabs.

Fleming, B.A.; Fox, J.D.; Furlong, M.W.; Masin, J.G.; Sault, L.P.; Tatterson, D.F. (Amoco Oil Co., Naperville, IL (USA). Research and Development Dept.); Fornoff, L.L.; Link, M.A.; Stahlnecker, E.; Torster, K. (Lummus Crest, Inc., Bloomfield, NJ (USA))

1988-09-01T23:59:59.000Z

16

Production of jet fuel from coal-derived liquids  

DOE Green Energy (OSTI)

Amoco and Lummus Crest are evaluating the process options and economics for upgrading the naphtha, crude phenols, and tar oil by-products from the Great Plains Coal Gasification Plant to jet fuels and other salable products. Analytical characterizations of these three by-products indicate the range of products that can be manufactured from each, and potential problems which could be encountered during refining. These characterizations, along with limited experimental data and Amoco's proprietary process models, were used to design conceptual processing schemes for maximizing the production of Grades JP-4, JP-8, and high density (JP-8X) jet fuels from the by-product liquids. In addition to the maximum jet fuel schemes, conceptual designs have also been formulated for maximizing profits from refining of the Great Plains by-products. Conceptual processing schemes for profitable production of JP-4, JP-8, and JP-8X have been developed, as has a maximum profit'' case. All four of these additional cases have now been transferred to Lummus for design and integration studies. Development of these schemes required the use of linear programming technology. This technology includes not only conventional refining processes which have been adapted for use with coal-derived liquids (e.g. hydrotreating, hydrocracking), but also processes which may be uniquely suited to the Great Plains by-products such as cresylic acid extraction, hydordealkylation, and needle coking. 6 figs., 3 tabs.

Furlong, M.W.; Fox, J.D.; Masin, J.G.; Soderberg, D.J.

1987-01-01T23:59:59.000Z

17

Production of jet fuel from coal-derived liquids  

Science Conference Proceedings (OSTI)

Amoco and Lummus Crest, under a contract with the United States Department of Energy, are evaluating the process options and economics for upgrading the naphtha, crude phenols, and tar oil by-products from the Great Plains Coal Gasification Plant to jet fuels and other salable products. Conceptual processing schemes for maximizing the production of Grades JP-4, JP-8, and high-density (JP-8X) jet fuels, for maximizing profits, and for profitable production of each of the three jet fuels from the by-product liquids have been developed. Economic analyses of the designs show that jet fuel can be produced from the by-products, but not economically. However, jet fuel production could be subsidized profitably by processing the phenolic and naphtha streams to cresols, phenols, BTX, and other valuable chemical by-products. Uncertainties in the studies are marketability of the chemical by-products, replacement fuel costs, and viable schemes to process the phenol stream, among others. 8 figs., 2 tabs.

Furlong, M.W.; Fox, J.D.; Masin, J.G.; Soderberg, D.J.

1990-01-01T23:59:59.000Z

18

Process for converting coal into liquid fuel and metallurgical coke  

DOE Patents (OSTI)

A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

1994-01-01T23:59:59.000Z

19

Production of jet fuel from coal-derived liquids  

SciTech Connect

Amoco and Lummus-Crest, under a contract with the United States Department of Energy, are evaluating the process options and economics for upgrading the naphtha, crude phenols, and tar oil by-products from the Great Plains Coal Gasification Plant to jet fuels and other salable products. Analytical characterizations of these three by-products indicate the range of products that can be manufactured from each and potential problems which could be encountered during refining. These characterizations, along with limited experimental data and Amoco's proprietary process models, were used to design conceptual processing schemes for maximizing the production of Grades JP-4, JP-8, and high-density (JP-8X) jet fuels from the by-product liquids. Conceptual designs have been completed and a case for profitable production of JP-8 has been selected for experimental testing and preliminary design. Samples of JP-4, JP-8, and JP-8X aviation turbine fuels have been manufactured from the Great Plains tar oil. Larger samples of JP-8 have also been produced and shipped to the US Air Force for further testing. Lummus-Crest Inc. is now completing a preliminary process design for the profitable production of JP-8 and has made recommendations for a production run to produce larger quantities of JP-8. 2 figs., 3 tabs.

Furlong, M.W.; Fox, J.D.; Masin, J.G.

1989-01-01T23:59:59.000Z

20

Production of jet fuel from coal-derived liquids  

SciTech Connect

Amoco and Lummus-Crest, under a contract with the United States Department of Energy, are evaluating the process options and economics for upgrading the naphtha, crude phenols, and tar oil by-products from the Great Plains Coal Gasification Plant to jet fuels and other salable products. Analytical characterizations of these three by-products indicate the range of products that can be manufactured from each and potential problems which could be encountered during refining. These characterizations, along with limited experimental data and Amoco's proprietary process models, were used to design conceptual processing schemes for maximizing the production of Grades JP-4, JP-8, and high-density (JP-8X) jet fuels from the by-product liquids. Conceptual designs have been completed and a case for profitable production of JP-8 has been selected for experimental testing and preliminary design in the later phases of the contract. Samples of JP-4, JP-8, and JP-8X aviation turbine fuels have been manufactured from the Great Plains tar oil. Larger samples of JP-8 are nearly completed. Specification of a design basis for profitable production of JP-8 is under way. 5 figs., 4 tabs.

Furlong, M.W.; Fox, J.D.; Masin, J.G.

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Production of jet fuel from coal-derived liquids  

SciTech Connect

Amoco and Lummus Crest, under a contract with the United States Department of Energy, are evaluating the process options and economics for upgrading the naphtha, crude phenols, and tar oil by-products from the Great Plains Coal Gasification Plant to jet fuels and other salable products. Analytical characterizations of these three by-products indicate the range of products that can be manufactured from each, and potential problems which could be encountered during refining. These characterizations, along with limited experimental data and Amoco's proprietary process models, were used to design conceptual processing schemes for maximizing the production of Grades JP-4, JP-8, and high-density (JP-8X) jet fuels from the by-product liquids. Conceptual designs have been completed and a case for profitable production of JP-8 has been selected for experimental testing and preliminary design in the later phases of the contract. Experimental work to date has shown that the tar oil stream requires substantially more severe processing than the preliminary design estimates indicated. A new design basis is now being tested and samples of JP-4, JP-8, and JP-8X are in production, based on that new, more severe processing scheme. Six barrels of tar oil have been hydrotreated according to the first step of the processing scheme and will be used to produce barrel quantities of JP-8. 2 refs., 2 figs.

Furlong, M.W.; Fox, J.D.; Masin, J.G.

1988-01-01T23:59:59.000Z

22

Liquid Tin Anode Direct Coal Fuel Cell Final Program Report  

SciTech Connect

This SBIR program will result in improved LTA cell technology which is the fundamental building block of the Direct Coal ECL concept. As described below, ECL can make enormous efficiency and cost contributions to utility scale coal power. This program will improve LTA cells for small scale power generation. As described in the Commercialization section, there are important intermediate military and commercial markets for LTA generators that will provide an important bridge to the coal power application. The specific technical information from this program relating to YSZ electrolyte durability will be broadly applicable SOFC developers working on coal based SOFC generally. This is an area about which very little is currently known and will be critical for successfully applying fuel cells to coal power generation.

Tao, Thomas

2012-01-26T23:59:59.000Z

23

Liquid Tin Anode Direct Coal Fuel Cell Final Program Report  

DOE Green Energy (OSTI)

This program will improve LTA cells for small scale power generation. As described in the Commercialization section, there are important intermediate military and commercial markets for LTA generators that will provide an important bridge to the coal power application. The specific technical information from this program relating to YSZ electrolyte durability will be broadly applicable SOFC developers working on coal based SOFC generally. This is an area about which very little is currently known and will be critical for successfully applying fuel cells to coal power generation.

Tao, Thomas

2012-01-26T23:59:59.000Z

24

Coal-liquid fuel/diesel engine operating compatibility. Final report  

DOE Green Energy (OSTI)

This work is intended to assess the possibilities of using coal-derived liquids (CDL) represented by a specific type (SRC II) and shale-derived distillate fuel in blends of petroleum-derived fuels in medium-speed, high-output, heavy-duty diesel engines. Conclusions are as follows: (1) Blends of solvent refined coal and diesel fuel may be handled safely by experienced diesel engine mechanics. (2) A serious corrosion problem was found in the fuel pump parts when operating with solvent refined coal blended with petroleum. It is expected that a metallurgy change can overcome this problem. (3) Proper selection of materials for the fuel system is required to permit handling coal-derived liquid fuels. (4) A medium speed, high horsepower, 4-cycle diesel engine can be operated on blends of solvent refined coal and petroleum without serious consequences save the fuel system corrosion previously mentioned. This is based on a single, short durability test. (5) As represented by the product evaluated, 100% shale-derived distillate fuel may be used in a medium speed, high horsepower, 4-cycle diesel engine without significant consequences. (6) The shale product evaluated may be blended with petroleum distillate or petroleum residual materials and used as a fuel for medium speed, high horsepower, 4-cycle diesel engines. 7 references, 24 figures, 20 tables.

Hoffman, J.G.; Martin, F.W.

1983-09-01T23:59:59.000Z

25

Production of jet fuel from coal-derived liquids  

Science Conference Proceedings (OSTI)

Amoco and Lummus Crest, under a contract with the United States Department of Energy, are evaluating the process options and economics for upgrading the naphtha, crude phenols, and tar oil by-products from the Great Plains Coal Gasification Plant to jet fuels and other salable products. Task 1 of the work, in which processes to produce each of the three jet fuels, JP-4, JP-8, and JP-8X, were designed, has been completed. The formal Task 1 report should issue next quarter. Task 2 work was initiated this quarter. In Task 2, process conditions for producing jet fuel from the Great Plains tar oil stream will be verified and samples of each of the three jet fuels will be produced. Experimental work shows that the hydrotreating conditions specified in Task 1 will not convert sufficient aromatics in the tar oil to produce jet fuel. Alternative schemes have been proposed and are being tested in the laboratories at Amoco Research Center. The simplest of these schemes, in which the heavy ends from the hydrotreater are recycled to extinction, was tested and proved infeasible. A second stage, fixed bed hydrotreater will be added to the process along with the expanded bed, first-stage hydrotreater and the hydrocracker specified in the Task 1 design. Future work will include additional experiments to specify the best process configuration and production of samples of each of the three grades of jet fuel. 6 figs., 7 tabs.

Furlong, M.W.; Fox, J.D.; Masin, J.G.; Soderberg, D.J.

1988-01-01T23:59:59.000Z

26

Production of jet fuels from coal derived liquids  

Science Conference Proceedings (OSTI)

Amoco Oil Company has conducted bench- and pilot plant-scale experiments to produce jet fuels from the tar oil from the Great Plains Coal Gasification Plant in Beulah, North Dakota. Experiments show that the hydroprocessing conditions recommended in Task 1 are not severe enough to saturate the aromatics in the tar oil to meet jet fuel specifications. Alternatives were investigated. Jet fuel specifications can be achieved when the tar oil is: hydrotreated in an expanded-bed hydrotreater to lower aromatics and heteroatom content; the effluent is then hydrotreated in a second, fixed bed hydrotreater; and, finally, the 550{degree}F boiling fraction from the two hydrotreaters is hydrocracked to extinction. The process was verified by pilot-plant production of 2 barrels of JP-8 turbine fuel, which met all but the flash point specification for JP-8. In addition, small samples of JP-4, JP-8, and high-density fuel were produced as a part of Task 2. 13 figs., 21 tabs.

Furlong, M.; Fox, J.; Masin, J.

1989-06-01T23:59:59.000Z

27

Chemically authentic surrogate mixture model for the thermophysical properties of a coal-derived liquid fuel  

Science Conference Proceedings (OSTI)

We developed a surrogate mixture model to represent the physical properties of a coal-derived liquid fuel using only information obtained from a gas chromatography-mass spectrometry analysis of the fuel and a recently developed 'advanced distillation curve'. We then predicted the density, speed of sound, and viscosity of the fuel and compared them to limited experimental data. The surrogate contains five components (n-propylcyclohexane, trans-decalin, {alpha}-methyldecalin, bicyclohexane, and n-hexadecane), yet comparisons to limited experimental data demonstrate that the model is able to represent the density, sound speed, and viscosity to within 1, 4, and 5%, respectively. 102 refs., 2 figs., 5 tabs.

M.L. Huber; E.W. Lemmon; V. Diky; B.L. Smith; T.J. Bruno [National Institute of Standards and Technology (NIST), Boulder, CO (United States). Physical and Chemical Properties Division

2008-09-15T23:59:59.000Z

28

Commercialization of Coal-to-Liquids Technology  

SciTech Connect

The report provides an overview of the current status of coal-to-liquids (CTL) commercialization efforts, including an analysis of efforts to develop and implement large-scale, commercial coal-to-liquids projects to create transportation fuels. Topics covered include: an overview of the history of coal usage and the current market for coal; a detailed description of what coal-to-liquids technology is; the history of coal-to-liquids development and commercial application; an analysis of the key business factors that are driving the increased interest in coal-to-liquids; an analysis of the issues and challenges that are hindering the commercialization of coal-to-liquids technology; a review of available coal-to-liquids technology; a discussion of the economic drivers of coal-to-liquids project success; profiles of key coal-to-liquids developers; and profiles of key coal-to-liquids projects under development.

NONE

2007-08-15T23:59:59.000Z

29

Commercialization of coal to liquids technology  

SciTech Connect

After an overview of the coal market, technologies for producing liquids from coal are outlined. Commercialisation of coal-to-liquid fuels, the economics of coal-to-liquids development and the role of the government are discussed. Profiles of 8 key players and the profiles of 14 projects are finally given. 17 figs., 8 tabs.

NONE

2007-07-01T23:59:59.000Z

30

Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams  

SciTech Connect

We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

Clifford, C.E.B.; Schobert, H.H. [Pennsylvania State University, PA (United States)

2008-07-01T23:59:59.000Z

31

NETL: Coal and Coal/Biomass to Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

C&CBTL C&CBTL Coal and Power Systems Coal and Coal/Biomass to Liquids The Coal and Coal/Biomass to Liquids program effort is focused on technologies to foster the commercial adoption of coal and coal/biomass gasification and the production of affordable liquid fuels and hydrogen with excellent environmental performance. U.S. Economic Competitiveness U.S. Economic Competitiveness U.S. Economic Competitiveness U.S. Economic Competitiveness Advanced Fuels Synthesis U.S. Economic Competitiveness U.S. Economic Competitiveness U.S. Economic Competitiveness U.S. Economic Competitiveness Advanced Fuels Synthesis Systems Analyses Global Environmental Benefits Global Environmental Benefits Global Environmental Benefits Global Environmental Benefits Global Environmental Benefits Global Environmental Benefits

32

Comparative analysis of the production costs and life-cycle GHG emissions of FT liquid fuels from coal and natural gas  

SciTech Connect

Liquid transportation fuels derived from coal and natural gas could help the United States reduce its dependence on petroleum. The fuels could be produced domestically or imported from fossil fuel-rich countries. The goal of this paper is to determine the life-cycle GHG emissions of coal- and natural gas-based Fischer-Tropsch (FT) liquids, as well as to compare production costs. The results show that the use of coal- or natural gas-based FT liquids will likely lead to significant increases in greenhouse gas (GHG) emissions compared to petroleum-based fuels. In a best-case scenario, coal- or natural gas-based FT-liquids have emissions only comparable to petroleum-based fuels. In addition, the economic advantages of gas-to-liquid (GTL) fuels are not obvious: there is a narrow range of petroleum and natural gas prices at which GTL fuels would be competitive with petroleum-based fuels. CTL fuels are generally cheaper than petroleum-based fuels. However, recent reports suggest there is uncertainty about the availability of economically viable coal resources in the United States. If the U.S. has a goal of increasing its energy security, and at the same time significantly reducing its GHG emissions, neither CTL nor GTL consumption seem a reasonable path to follow. 28 refs., 2 figs., 4 tabs.

Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews [Carnegie Mellon University, Pittsburgh, PA (USA). Civil and Environmental Engineering Department

2008-10-15T23:59:59.000Z

33

Liquid Fuels Market Module  

U.S. Energy Information Administration (EIA) Indexed Site

Liquid Fuels Market Module Liquid Fuels Market Module This page inTenTionally lefT blank 145 U.S. Energy Information Administration | Assumptions to the Annual Energy Outlook 2013 Liquid Fuels Market Module The NEMS Liquid Fuels Market Module (LFMM) projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil (both domestic and imported), petroleum product imports, unfinished oil imports, other refinery inputs (including alcohols, ethers, esters, corn, biomass, and coal), natural gas plant liquids production, and refinery processing gain. In addition, the LFMM projects capacity expansion and fuel consumption at domestic refineries. The LFMM contains a linear programming (LP) representation of U.S. petroleum refining

34

Assessment of coal liquids as refinery feedstocks  

Science Conference Proceedings (OSTI)

The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

Zhou, P.

1992-02-01T23:59:59.000Z

35

Assessment of coal liquids as refinery feedstocks  

Science Conference Proceedings (OSTI)

The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

Zhou, P.

1992-02-01T23:59:59.000Z

36

Synthetic fuel production by indirect coal liquefaction  

E-Print Network (OSTI)

, the production of a synthetic crude oil product by direct contact of coal with an appropriate catalyst, with abundant domestic coal resources but lim- ited oil and gas resources, the conversion of coal into liquid in South Africa (for Fischer- Tropsch fuels). Also, the US Department of Energy an- nounced its financial

37

NETL: Coal & Coal Biomass to Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal Biomass to Liquids Hydrogen-from-Coal RD&D ENERGY ANALYSIS About Us Search Products Contacts SMART GRID ANALYSIS BASELINE STUDIES QUALITY GUIDELINES NETL-RUA About NETL-RUA...

38

NETL: Coal & Coal Biomass to Liquids - Alternate Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal and CoalBiomass to Liquids Alternate Hydrogen Production In the Alternate Production technology pathway, clean syngas from coal is converted to high-hydrogen-content liquid...

39

Pulverized coal fuel injector  

DOE Patents (OSTI)

A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

Rini, Michael J. (Hebron, CT); Towle, David P. (Windsor, CT)

1992-01-01T23:59:59.000Z

40

Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum  

DOE Green Energy (OSTI)

The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

Jain, M.K.

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Coal and Biomass to Liquids | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Coal to Liquids » Coal and Coal to Liquids » Coal and Biomass to Liquids Coal and Biomass to Liquids Over the last several decades, the Office of Fossil Energy performed RD&D activities that made significant advancements in the areas of coal conversion to liquid fuels and chemicals. Technology improvements and cost reductions that were achieved led to the construction of demonstration-scale facilities. The program is now supporting work to reduce the carbon footprint of coal derived liquids by incorporating the co-feeding of biomass and carbon capture. In the area of direct coal liquefaction, which is the process of breaking down coal to maximize the correct size of molecules for liquid products, the U.S. DOE made significant investments and advancements in technology in the 1970s and 1980s. Research enabled direct coal liquefaction to produce

42

Process for preparing a liquid fuel composition  

SciTech Connect

A process for preparing a liquid fuel composition which comprises liquefying coal, separating a mixture of phenols from said liquefied coal, converting said phenols to the corresponding mixture of anisoles, subjecting at least a portion of the remainder of said liquefied coal to hydrotreatment, subjecting at least a portion of said hydrotreated liquefied coal to reforming to obtain reformate and then combining at least a portion of said anisoles and at least a portion of said reformate to obtain said liquid fuel composition.

Singerman, Gary M. (Monroeville, PA)

1982-03-16T23:59:59.000Z

43

NETL: Coal & Coal Biomass to Liquids - Closely Aligned Programs  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > C&CBTL > Closely Aligned Programs Coal and CoalBiomass to Liquids Closely Aligned Programs The Department of Energy's (DOE) Coal & CoalBiomass to Liquids...

44

Synthetic liquid fuels development: assessment of critical factors. Volume III. Coal resource depletion  

DOE Green Energy (OSTI)

While US coal resources are known to be vast, their rate of depletion in a future based predominantly on coal has not been examined analytically heretofore. The Coal Depletion Model inventories the coal resource on a regional basis and calculates the cost of coal extraction by three technologies - strip and underground mining and in-situ combustion. A plausible coal demand scenario extending from 1975 to the year 2050 is used as a basis in applying the model. In the year 2050, plants in operation include 285 syncrude plants, each producing 100,000 B/D; 312 SNG plants, each producing 250 million SCF/D and 722 coal-fired electric power plants, each of 1000 MW capacity. In addition, there is 890 million tons per year of industrial coal consumption. Such a high level of coal use would deplete US coal resources much more rapidly than most people appreciate. Of course, the actual amount of US coal is unknown, and if the coal in the hypothetical reliability category is included, depletion is delayed. Coal in this category, however, has not been mapped; it is only presumed to exist on the basis of geological theory. The coal resource depletion model shows that unilateral imposition of a severance tax by a state tends to shift production to other coal producing regions. Boom and bust cycles are both delayed and reduced in their magnitude. When several states simultaneously impose severance taxes, the effect of each is weakened.Key policy issues that emerge from this analysis concern the need to reduce the uncertainty of the magnitude and geographic distribution of the US coal resource and the need to stimulate interaction among the parties at interest to work out equitable and acceptable coal conversion plant location strategies capable of coping with the challenges of a high-coal future.

Dickson, E.M.; Yabroff, I.W.; Kroll, C.A.; White, R.K.; Walton, B.L.; Ivory, M.E.; Fullen, R.E.; Weisbecker, L.W.; Hays, R.L.

1977-01-01T23:59:59.000Z

45

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network (OSTI)

commercial (point sources) Coal Oil Other Area sourcesSource Stationary fuel combugtion Electric utilities Coal Oil

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

46

FRAGMENTATION OF COAL AND IMPROVED DISPERSION OF LIQUEFACTION CATALYSTS USING IONIC LIQUIDS.  

E-Print Network (OSTI)

??Coal has been utilized for coal-to-liquid fuels and coal-to-chemical industries both historically in South Africa and recently in China. Abundant bituminous and low-rank coal reserves (more)

Cetiner, Ruveyda

2011-01-01T23:59:59.000Z

47

www.elsevier.com/locate/fuel Trace elements in coal derived liquids: analysis by ICP-MS and  

E-Print Network (OSTI)

Concentrations of trace elements in coal derived liquids have been investigated by inductively coupled plasma-mass spectrometry (ICP-MS) and by Mssbauer spectroscopy. Liquefaction extracts prepared from the Argonne Premium Coals and a coal tar pitch have been examined. Microwave digestion in concentrated nitric acid has been shown as a suitable method for determining trace element concentrations in coal derived liquids by ICP-MSfor sample sizes as small as 320 mg. High concentrations of Fe were found for all extract samples (?2651474 ppm). Ti, Cr, Mn, Co, Ga, Sb, Cs and Ba were measurable. Concentration distributions of trace elements found in the extracts bore little relation to the corresponding distributions in the original coals. The proportions of individual trace elements present in the original coals and found in the extracts, varied widely. Mssbauer spectroscopy of the extracts indicated that the high Fe-concentrations corresponded to the presence of organometallic-Fe compoundsand not to pyritic iron. There is evidence suggesting the presence of material derived from iron-storage proteins such as ferritin, but final proof is lacking. Our data suggest that other metallic ions detected in these coal derived liquids may be present in association with the organic material. Concentrations of paramagnetic metal species were found to be of the same order of magnitude as ESR spin-densities already found in coal liquids. Both types of paramagnetic species are suspected of causing loss of signal in

Mssbauer Spectroscopy; R. Richaud A; H. Lachas A; M. -j. Lazaro A; L. J. Clarke B; K. E. Jarvis B; A. A. Herod A; T. C. Gibb C; R. Kandiyoti A

1999-01-01T23:59:59.000Z

48

Process for stabilization of coal liquid fractions  

SciTech Connect

Coal liquid fractions to be used as fuels are stabilized against gum formation and viscosity increases during storage, permitting the fuel to be burned as is, without further expensive treatments to remove gums or gum-forming materials. Stabilization is accomplished by addition of cyclohexanol or other simple inexpensive secondary and tertiary alcohols, secondary and tertiary amines, and ketones to such coal liquids at levels of 5-25% by weight with respect to the coal liquid being treated. Cyclohexanol is a particularly effective and cost-efficient stabilizer. Other stabilizers are isopropanol, diphenylmethanol, tertiary butanol, dipropylamine, triethylamine, diphenylamine, ethylmethylketone, cyclohexanone, methylphenylketone, and benzophenone. Experimental data indicate that stabilization is achieved by breaking hydrogen bonds between phenols in the coal liquid, thereby preventing or retarding oxidative coupling. In addition, it has been found that coal liquid fractions stabilized according to the invention can be mixed with petroleum-derived liquid fuels to produce mixtures in which gum deposition is prevented or reduced relative to similar mixtures not containing stabilizer.

Davies, Geoffrey (Boston, MA); El-Toukhy, Ahmed (Alexandria, EG)

1987-01-01T23:59:59.000Z

49

Novel Fuel Cells for Coal Based Systems  

DOE Green Energy (OSTI)

The goal of this project was to acquire experimental data required to assess the feasibility of a Direct Coal power plant based upon an Electrochemical Looping (ECL) of Liquid Tin Anode Solid Oxide Fuel Cell (LTA-SOFC). The objective of Phase 1 was to experimentally characterize the interaction between the tin anode, coal fuel and cell component electrolyte, the fate of coal contaminants in a molten tin reactor (via chemistry) and their impact upon the YSZ electrolyte (via electrochemistry). The results of this work will provided the basis for further study in Phase 2. The objective of Phase 2 was to extend the study of coal impurities impact on fuel cell components other than electrolyte, more specifically to the anode current collector which is made of an electrically conducting ceramic jacket and broad based coal tin reduction. This work provided a basic proof-of-concept feasibility demonstration of the direct coal concept.

Thomas Tao

2011-12-31T23:59:59.000Z

50

Techno-economic evaluation of coal-to-liquids (CTL) plants with carbon capture and sequestration  

E-Print Network (OSTI)

Techno-economic evaluation of coal-to-liquids (CTL) plants with carbon capture and sequestration online 5 March 2011 Keywords: Coal-to-liquids Co-production Carbon capture and storage a b s t r a c t Coal-to-liquids (CTL) processes that generate synthetic liquid fuels from coal are of increasing

51

Coal-water mixture fuel burner  

DOE Patents (OSTI)

The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

Brown, T.D.; Reehl, D.P.; Walbert, G.F.

1985-04-29T23:59:59.000Z

52

Coal to Liquids | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Liquids Liquids Coal to Liquids Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in Charleston, WV, the Yeager facility was constructed and operated with support from the Office of Fossil Energy’s National Energy Technology Laboratory. Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in Charleston, WV, the Yeager facility was constructed and operated with support from the Office of Fossil Energy's National Energy Technology Laboratory. The Hydrogen and Clean Coal Fuels Program supports DOE's strategic goals of increasing energy security, reducing environmental impact of energy use,

53

NETL: Coal & Coal Biomass to Liquids - Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Reference Shelf Coal and CoalBiomass to Liquids Reference Shelf Documents Papers Presentations DOCUMENTS 2012 Technology Readiness Assessment-Analysis of Active Research Portfolio...

54

DOE studies on coal-to-liquids  

SciTech Connect

The US DOE National Energy Technology Laboratory has issued reports that examine the feasibility of coal-to-liquids (CTL) facilities, both general and site specific, which are available at www.netl.gov/energy-analyses/ref-shelf.html. The US Department of Defence has been investigating use of Fischer-Tropsch fuels. Congress is considering various CTL proposals while the private sector is building pilot plants and performing feasibility studies for proposed plants. The article includes a table listing 14 coal-to-liquids plants under consideration. The private sector has formed the coal-to-liquids coalition (www.futurecoalfuels.org). The article mentions other CTL projects in South Africa, China, Indonesia, the Philippines and New Zealand. 1 tab.

NONE

2007-07-01T23:59:59.000Z

55

Chemical and physical aspects of refining coal liquids  

Science Conference Proceedings (OSTI)

Increasing costs and declining reserves of petroleum are forcing oil importing countries to develop alternate energy sources. The direct liquefaction of coal is currently being investigated as a viable means of producing substitute liquid fuels. The coal liquids derived from such processes are typically high in nitrogen

Y. T. Shah; G. J. Stiegel; S. Krishnamurthy

1981-01-01T23:59:59.000Z

56

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network (OSTI)

Credit Extra Fuel Oil Coal to gasifier Na cost Na processoiL Replace res. with coal as gasifier feed. 543 ton/day @$

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

57

The Prospects for Coal-To-Liquid Conversion: A General Equilibrium Analysis  

E-Print Network (OSTI)

We investigate the economics of coal-to-liquid (CTL) conversion, a polygeneration technology that produces liquid fuels, chemicals, and electricity by coal gasification and Fischer-Tropsch process. CTL is more expensive ...

Chen, Y.-H. Henry

58

Refining and End Use Study of Coal Liquids.  

DOE Green Energy (OSTI)

Progress in a study to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids is reported.

NONE

1997-12-31T23:59:59.000Z

59

A pulverized coal fuel injector  

DOE Patents (OSTI)

A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO{sub 2} formation.

Rini, M.J.; Towle, D.P.

1991-12-31T23:59:59.000Z

60

Liquid fossil fuel technology  

Science Conference Proceedings (OSTI)

Progress reports are presented under the following headings: (1) extraction (technology assessment, oil research, gas research); (2) liquid processing (characterization, thermodynamics, processing technology); (3) utilization (energy conservation); and (4) project integration and technology transfer. BETC publications are also listed. Some of the highlights for this period are: the Bartlesville Energy Technology Center was converted into NIPER, the National Institute for Petroleum and Energy Research on October 1, 1983; modelling of enthalpies, heat capacities and volumes of aqueous surfactant solutions began using a mass action model; a series of experiments were run on upgrading by hydrogenation SRC-II coal liquid at different degrees of severity and the products have been analyzed; heavy crude oil extracts were separated into fraction with high performance liquid chromatography by Lawrence Berkeley Laboratory and the mass spectra and electron spin resonance were determin ed; and particulates from exhaust gases of diesel engines using fire fuel types are being collected and will be analyzed by chemical methods and results will be compared with those obtained by biological assay. (ATT)

Not Available

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The evaluation of a coal-derived liquid as a feedstock for the production of high-density aviation turbine fuel  

DOE Green Energy (OSTI)

The conversion of coal-derived liquids to transportation fuels has been the subject of many studies sponsored by the US Department of Energy and the US Department of Defense. For the most part, these studies evaluated conventional petroleum processes for the production of specification-grade fuels. Recently, however, the interest of these two departments expanded to include the evaluation of alternate fossil fuels as a feedstock for the production of high-density aviation turbine fuel. In this study, we evaluated five processes for their ability to produce intermediates from a coal-derived liquid for the production of high-density turbine fuel. These processes include acid-base extraction to reduce the heteroatom content of the middle distillate and the atmospheric and vacuum gas oils, solvent dewaxing to reduce the paraffin (alkane) content of the atmospheric and vacuum gas oils, Attapulgus clay treatment to reduce the heteroatom content of the middle distillate, coking to reduce the distillate range of the vacuum gas oil, and hydrogenation to remove heteroatoms and to saturate aromatic rings in the middle distillate and atmospheric gas oil. The chemical and physical properties that the US Air Force considers critical for the development of high-denisty aviation turbine fuel are specific gravity and net heat of combustion. The target minimum values for these properties are a specific gravity of at least 0.85 and a net heat of combustion of at least 130,000 Btu/gal. In addition, the minimum hydrogen content is 13.0 wt %, the maximum freeze point is {minus}53{degrees}F ({minus}47{degrees}C), the maximum amount of aromatics is about 25 to 30 vol %, and the maximum amount of paraffins is 10 vol %. 13 refs., 20 tabs.

Thomas, K.P.; Hunter, D.E.

1989-08-01T23:59:59.000Z

62

Coal-fueled diesel locomotive test  

DOE Green Energy (OSTI)

The biggest challenges to the development of a commercially-acceptable coal-fueled diesel-electric locomotive are integrating all systems into a working unit that can be operated in railroad service. This involves mainly the following three systems: (1) the multi-cylinder coal-fueled diesel engine, (2) the locomotive and engine controls, and (3) the CWS fuel supply system. Consequently, a workable 12-cylinder coal-fueled diesel engine was considered necessary at this stage to evolve the required locomotive support systems, in addition to gaining valuable multi-cylinder engine operating experience. The CWS fuel used during this project was obtained from Otisca, Inc. (Syracuse, NY). It was prepared from micronized and deashed Kentucky Blue Gem coal to 49.0% coal loading by weight, with less than 1% ash and 5 micron mean diameter particle size. Its higher heating value was analyzed at approximately 34630 kJ/k. Anti-agglomerating additive Triton X-114 was added to the CWS at GE Transportation Systems at 2% of coal weight. The nature of the Otisca CWS fuel makes it inherently more difficult to store, pump, and inject than diesel fuel, since concepts which govern Newtonian or normally viscous liquids do not apply entirely to CWS. Otisca CWS tends to be unstable and to settle in tanks and lines after a period of time, making it necessary to provide a means of agitation during storage. To avoid long term settling problems and to minimize losses, piping velocities were designed to be in the 60-90 m/min range.

Hsu, B.D.; McDowell, R.E.; Confer, G.L.; Basic, S.L.

1993-01-01T23:59:59.000Z

63

Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991  

DOE Green Energy (OSTI)

The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

Jain, M.K.

1991-12-31T23:59:59.000Z

64

NETL: Coal and Coal/Biomass to Liquids - Solicitations  

NLE Websites -- All DOE Office Websites (Extended Search)

by Gasification. Small-Scale Coal-biomass to Liquids Production Using Highly Selective Fischer-Tropsch Synthesis; FE0010231 Small-Scale Pilot Plant for the Gasification of Coal...

65

Clean Coal Research | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Clean Coal Research Clean Coal Research Clean Coal Turbines Gasification Fuel Cells Hydrogen from Coal Coal to Liquids Major Demonstrations Crosscutting Research Carbon Capture and...

66

NETL: Coal and Coal/Biomass to Liquids - Systems and Industry Analyses  

NLE Websites -- All DOE Office Websites (Extended Search)

C&CBTL > Systems Analyses C&CBTL > Systems Analyses Coal and Coal/Biomass to Liquids Reference Shelf – Systems and Industry Analyses Studies DOE/NETL possesses strong systems analysis and policy-support capabilities. Systems analysis in support of the Coal and Coal/Biomass to Liquids Program consists of conducting various energy analyses that provide input to decisions on issues such as national plans and programs, resource use, environmental and energy security policies, technology options for research and development programs, and paths to deployment of energy technology. Coal and Coal/Biomass to Liquids Program's Systems and Industry Analyses Studies Life Cycle Greenhouse Gas Analysis of Advanced Jet Propulsion Fuels: Fischer-Tropsch Based SPK-1 Case Study - Presentation

67

Deashing of coal liquids by sonically assisted filtration  

Science Conference Proceedings (OSTI)

This project seeks to improve the effectiveness and reduce the cost of coal liquefaction by novel applications of sonic and ultrasonic energy. The specific purpose of this project is to develop and improve means for the economical removal of dispersed solid particles of ash, unreacted coal, and spent catalyst from direct and indirect coal liquefaction resids by using sonic or ultrasonic waves. Product streams containing solids are generated in both direct and indirect coal liquefaction processes. Direct coal liquefaction processes generate liquid products which contain solids including coal-originated mineral matter, unreacted coal, and spent dispersed catalyst. The removal of these solids from a product stream is one of the most difficult problems in direct coal liquefaction processes. On this report, results are discussed for sonically assisted crossflow filtration of V-1067 resid, diluted with No. 2 fuel oil, and sonically assisted batch filtrations of solids concentrates from continuous cross-flow filtration experiments.

Slomka, B.J.

1994-10-01T23:59:59.000Z

68

NETL: Coal & Coal Biomass to Liquids - Systems Studies  

NLE Websites -- All DOE Office Websites (Extended Search)

security and a sustainable hydrogen economy by economically producing hydrogen from coal. Hydrogen represents a clean alternative fuel that can help to reduce the nation's...

69

Production of jet fuels from coal-derived liquids. Volume 7. GPGP jet-fuels production program. Evaluation of technical uncertainties for producing jet fuels from liquid by-products of the Great Plains gasification plant. Interim report, 2 October 1987-30 September 1988  

Science Conference Proceedings (OSTI)

In September 1986, the Fuels Branch of the Aero Propulsion Laboratory at Wright-Patterson Air Force Base, Ohio, began an investigation of the potential of jet-fuel production from the liquid by-product streams produced by the gasification of lignite at the Great Plains Gasification Plant (GPGP) in Beulah, North Dakota. Funding was provided by the Department of Energy (DOE) Pittsburgh Energy Technology Center (PETC) to administer the experimental portion of this effort. This document reports the results of the effort by Burns and Roe Services Corporation/Science Applications International Corporation (BRSC/SAIC) to analyze GPGP operations and develop correlations for the liquid by-products and plant operating factors such as coal feed rate and coal characteristics.

Fraser, M.D.; Rossi, R.J.; Wan, E.I.

1989-01-01T23:59:59.000Z

70

Production of jet fuels from coal-derived liquids. Volume 6. Preliminary analysis of upgrading alternatives for the Great Plains liquid by-production streams. Interim report, March 1987-February 1988  

Science Conference Proceedings (OSTI)

Amoco and Lummus Crest have developed seven cases for upgrading by-product liquids from the Great Plains Coal Gasification plant to jet fuels, and in several of the cases, saleable chemicals in addition to jet fuels. The analysis shows that the various grades of jet fuel can be produced from the Great Plains tar oil, but not economically. However the phenolic and naptha streams do have the potential to significantly increase (on the order of $10-15 million/year) the net revenues at Great Plains by producing chemicals, especially cresylic acid, cresol, and xylenol. The amount of these chemicals, which can be marketed, is a concern, but profits can be generated even when oxygenated chemical sales are limited to 10% of the U.S. market. Another concern is that while commercial processes exist to extract phenolic mixtures, these processes have not been demonstrated with the Great Plains phenolic stream.

Fleming, B.A.; Fox, J.D.; Furlong, M.W.; Masin, J.G.; Sault, L.P.

1988-09-01T23:59:59.000Z

71

Nonconventional Liquid Fuels  

Reports and Publications (EIA)

Higher prices for crude oil and refined petroleum products are opening the door for nonconventional liquids to displace petroleum in the traditional fuel supply mix. Growing world demand for diesel fuel is helping to jump-start the trend toward increasing production of nonconventional liquids, and technological advances are making the nonconventional alternatives more viable commercially. Those trends are reflected in the AEO2006 projections.

Information Center

2006-02-01T23:59:59.000Z

72

Lummus clean fuels from coal  

DOE Green Energy (OSTI)

This report compares two direct, catalytic, hydroliquefaction processes - H-Coal and Lummus Clean Fuels From Coal (LCFFC). These processes are compared for two sets of operating conditions. In the first, the reactors are operated to produce a product suitable for use as fuel oil (fuel oil mode). In the second, the operating conditions are more severe, so the resulting product slates more closely resemble crude oil (syncrude mode). The comparisons are performed using conceptual designs based on single point run data, with a design basis of 25,000 tpd (moisture-free basis) of Illinois No. 6 coal. Although all cost comparisons are well within the estimated 25% accuracy of the estimates, LCFFC shows generally lower costs. Three types of economic evaluation are performed: computation of internal rate of return (IRR) with product values set to estimated market value, computation of overall average product cost ($/MM Btu) with the discount rate set at 20%, and calculation of average product cost with naphtha credited at estimated market value and the discount rate set at 20%. H-Coal has a lower cost only in the fuel oil mode analysis with naphtha valued at market price. The processes are also compared with respect to the potential for commercialization and anticipated operability differences. It is concluded that the lower hydrogen content of LCFFC product may offset its advantage of lower cost if it is used as refinery feed, and that the design of the LCFFC reactor may make it harder to control. Suggestions for future research are presented.

Gantt, J.E.; Hefferan, J.K.; Chorba, W.F.; Schachtschneider, A.B.; Schulze, J.R.

1980-12-01T23:59:59.000Z

73

Liquid chromatographic analysis of coal surface properties  

SciTech Connect

Experiments on equilibrium adsorption loadings of various additives on 60 - 200 mesh Illinois 16 coal (DECS-2; Randolph county) were performed. The additives include n-propanol, n-butanol, 2-butanol, phenol, 2-naphthol, o-cresol and cyclohexanol. Equilibrium adsorption loadings of normal alcohols on 60 - 200 mesh Illinois No. 6 coal increase with increased numbers of carbons in their molecular formulas. Normal alcohols are more adsorbed on the coal than their branched alcohols. Adsorption loadings of single-ring compound phenol on the coal is higher than that of cyclohexanol. Adsorption loadings of double-ring compound 2-naphthol on the coal is much higher than that of single-ring compound phenol. The main objectives of this proposed research are to refine further the inverse liquid chromatography technique for the study of surface properties of raw coals, treated coals and coal minerals in water, to evaluate relatively surface properties of raw coals, treated coals and coal minerals by inverse liquid chromatography, and to evaluate floatability of various treated coals in conjunction with surface properties of coals.

Kwon, K.C.; Rigby, R.

1992-01-01T23:59:59.000Z

74

Biological upgrading of coal liquids. Final report  

SciTech Connect

A large number of bacterial enrichments have been developed for their ability to utilize nitrogen and sulfur in coal liquids and the model compound naphtha. These bacteria include the original aerobic bacteria isolated from natural sources which utilize heteroatom compounds in the presence of rich media, aerobic nitrogen-utilizing bacteria and denitrifying bacteria. The most promising isolates include Mix M, a mixture of aerobic bacteria; ER15, a pyridine-utilizing isolate; ERI6, an aniline-utilizing isolate and a sewage sludge isolate. Culture optimization experiments have led to these bacteria being able to remove up to 40 percent of the sulfur and nitrogen in naphtha and coal liquids in batch culture. Continuous culture experiments showed that the coal liquid is too toxic to the bacteria to be fed without dilution or extraction. Thus either semi-batch operation must be employed with continuous gas sparging into a batch of liquid, or acid extracted coal liquid must be employed in continuous reactor studies with continuous liquid flow. Isolate EN-1, a chemical waste isolate, removed 27 percent of the sulfur and 19 percent of the nitrogen in fed batch experiments. Isolate ERI5 removed 28 percent of the nitrogen in coal liquid in 10 days in fed batch culture. The sewage sludge isolate removed 22.5 percent of the sulfur and 6.5 percent of the nitrogen from extracted coal liquid in continuous culture, and Mix M removed 17.5 percent of the nitrogen from medium containing extracted coal liquid. An economic evaluation has been prepared for the removal of nitrogen heteroatom compounds from Wilsonville coal liquid using acid extraction followed by fermentation. Similar technology can be developed for sulfur removal. The evaluation indicates that the nitrogen heteroatom compounds can be removed for $0.09/lb of coal liquid treated.

NONE

1995-02-01T23:59:59.000Z

75

The prospects for coal-to-liquid conversion: A general equilibrium analysis Y.-H. Henry Chen a,n  

E-Print Network (OSTI)

The prospects for coal-to-liquid conversion: A general equilibrium analysis Y.-H. Henry Chen a investigate the economics of coal-to-liquid (CTL) conversion, a polygeneration technology that produces liquid fuels, chemicals, and electricity by coal gasification and Fischer­Tropsch process. CTL is more

76

Refining and End Use Study of Coal Liquids.  

DOE Green Energy (OSTI)

A study of the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g., year 2000, Clean Air Act Amendments (CAAA) standards. This report is the 12th quarterly progress report in the series covering January 1, 1997 to March 31, 1997.

NONE

1997-12-31T23:59:59.000Z

77

A novel concept for high conversion of coal to liquids  

DOE Green Energy (OSTI)

The overall objective of this work is to demonstrate conversion of coal to produce at least 70% by weight of the coal as liquids, with ratios of liquids to gases in excess of 10/1, resulting in low hydrogen consumption and a significant reduction in the cost of producing hydrocarbon liquid fuels from coal. Utilizing a small continuous-flow reactor designed and constructed for this research, the maximum possible ratio of liquids to gases will be defined, operating at short residence times of a few seconds, at the same time converting more than 70% of the carbon in the coal to liquids. The practical ability to attain coal particle center-line temperatures of 500 {degree}C in one second or less, using hot hydrogen gas in turbulent flow, will also be demonstrated. Particle heat-up rates for a few selected system pressures and particle sizes will be determined. Catalysts will be screened and selected for sufficient activity and selectivity. Particle heat-up rates for small coal particles slurried in a super-critical hydrocarbon-type fluid will be examined, using hot hydrogen gas in turbulent flow as the heat transfer medium.

Wiser, W.H.; Shabtai, J.

1990-06-01T23:59:59.000Z

78

NETL: Coal & Coal Biomass to Liquids - Utilization  

NLE Websites -- All DOE Office Websites (Extended Search)

choice for utilization of hydrogen in both of these applications. However, fuel cell technology has to overcome significant technical and economic barriers in order to...

79

Process for producing fluid fuel from coal  

DOE Patents (OSTI)

Process for producing fluid fuel from coal. Moisture-free coal in particulate form is slurried with a hydrogen-donor solvent and the heated slurry is charged into a drum wherein the pressure is so regulated as to maintain a portion of the solvent in liquid form. During extraction of the hydrocarbons from the coal, additional solvent is added to agitate the drum mass and keep it up to temperature. Subsequently, the pressure is released to vaporize the solvent and at least a portion of the hydrocarbons extracted. The temperature of the mass in the drum is then raised under conditions required to crack the hydrocarbons in the drum and to produce, after subsequent stripping, a solid coke residue. The hydrocarbon products are removed and fractionated into several cuts, one of which is hydrotreated to form the required hydrogen-donor solvent while other fractions can be hydrotreated or hydrocracked to produce a synthetic crude product. The heaviest fraction can be used to produce ash-free coke especially adapted for hydrogen manufacture. The process can be made self-sufficient in hydrogen and furnishes as a by-product a solid carbonaceous material with a useful heating value.

Hyde, Richard W. (Winchester, MA); Reber, Stephen A. (Waltham, MA); Schutte, August H. (Lexington, MA); Nadkarni, Ravindra M. (Arlington, MA)

1977-01-01T23:59:59.000Z

80

Advanced coal-fueled gas turbine systems  

SciTech Connect

Several technology advances since the early coal-fueled turbine programs that address technical issues of coal as a turbine fuel have been developed in the early 1980s: Coal-water suspensions as fuel form, improved methods for removing ash and contaminants from coal, staged combustion for reducing NO{sub x} emissions from fuel-bound nitrogen, and greater understanding of deposition/erosion/corrosion and their control. Several Advanced Coal-Fueled Gas Turbine Systems programs were awarded to gas turbine manufacturers for for components development and proof of concept tests; one of these was Allison. Tests were conducted in a subscale coal combustion facility and a full-scale facility operating a coal combustor sized to the Allison Model 501-K industrial turbine. A rich-quench-lean (RQL), low nitrogen oxide combustor design incorporating hot gas cleanup was developed for coal fuels; this should also be applicable to biomass, etc. The combustor tests showed NO{sub x} and CO emissions {le} levels for turbines operating with natural gas. Water washing of vanes from the turbine removed the deposits. Systems and economic evaluations identified two possible applications for RQL turbines: Cogeneration plants based on Allison 501-K turbine (output 3.7 MW(e), 23,000 lbs/hr steam) and combined cycle power plants based on 50 MW or larger gas turbines. Coal-fueled cogeneration plant configurations were defined and evaluated for site specific factors. A coal-fueled turbine combined cycle plant design was identified which is simple, compact, and results in lower capital cost, with comparable efficiency and low emissions relative to other coal technologies (gasification, advanced PFBC).

Wenglarz, R.A.

1994-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Fuel blending with PRB coal  

Science Conference Proceedings (OSTI)

Many methods exist to accomplish coal blending at a new or existing power plant. These range from a basic use of the secondary (emergency) stockout/reclaim system to totally automated coal handling facilities with segregated areas for two or more coals. Suitable choices for different sized coal plant are discussed, along with the major components of the coal handling facility affected by Powder River Basin coal. 2 figs.

McCartney, R.H.; Williams, R.L. Jr. [Roberts and Schaefer, Chicago, IL (United States)

2009-03-15T23:59:59.000Z

82

EIS-0357 - Gilberton Coal-to-Clean Fuels and Power Project in Giberton, PA  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7 - Gilberton Coal-to-Clean Fuels and Power Project in 7 - Gilberton Coal-to-Clean Fuels and Power Project in Giberton, PA EIS-0357 - Gilberton Coal-to-Clean Fuels and Power Project in Giberton, PA Summary This Environmental Impact Statement (EIS) assesses the potential environmental impacts that would result from a proposed Department of Energy (DOE) action to provide cost-shared funding for construction and operation of facilities near Gilberton, Pennsylvania, which have been proposed by WMPI PTY, LLC, for producing electricity, steam, and liquid fuels from anthracite coal waste (culm). The project was selected by DOE under the Clean Coal Power Initiative (CCPI) to demonstrate the integration of coal waste gasification and Fischer-Tropsch (F-T) synthesis of liquid hydrocarbon fuels at commercial scale. PUBLIC COMMENT OPPORTUNITIES

83

Hydrotreating of coal-derived liquids  

SciTech Connect

The objective of Sandia`s refining of coal-derived liquids project is to determine the relationship between hydrotreating conditions and Product characteristics. The coal-derived liquids used in this work were produced In HTI`s first proof-of-concept run using Illinois No. 8 coal. Samples of the whole coal liquid product, distillate fractions of this liquid, and Criterion HDN-60 catalyst were obtained from Southwest Research Inc. Hydrotreating experiments were performed using a continuous operation, unattended, microflow reactor system. A factorial experimental design with three variables (temperature, (310{degrees}C to 388{degrees}C), liquid hourly space velocity (1 to 3 g/h/cm{sup 3}(cat)), pressure (500 to 1000 psig H{sub 2}) is being used in this project. Sulfur and nitrogen contents of the hydrotreated products were monitored during the hydrotreating experiments to ensure that activity was lined out at each set of reaction conditions. Results of hydrotreating the whole coal liquid showed that nitrogen values in the products ranged from 549 ppM at 320{degrees}C, 3 g/h/cm{sup 3}(cat), 500 psig H{sub 2} to <15 ppM at 400{degrees}C, 1 g/h/ cm{sup 3}(cat), 1000 psig H{sub 2}.

Stohl, F.V.; Lott, S.E.; Diegert, K.V.; Goodnow, D.C.; Oelfke, J.B.

1995-06-01T23:59:59.000Z

84

Coal/biomass fuels and the gas turbine: Utilization of solid fuels and their derivatives  

Science Conference Proceedings (OSTI)

This paper discusses key design and development issues in utilizing coal and other solid fuels in gas turbines. These fuels may be burned in raw form or processed to produce liquids or gases in more or less refined forms. The use of such fuels in gas turbines requires resolution of technology issues which are of little or no consequence for conventional natural gas and refined oil fuels. For coal, these issues are primarily related to the solid form in which coal is naturally found and its high ash and contaminant levels. Biomass presents another set of issues similar to those of coal. Among the key areas discussed are effects of ash and contaminant level on deposition, corrosion, and erosion of turbine hot parts, with particular emphasis on deposition effects.

DeCorso, M. [Power Tech Associates, Inc., Paramus, NJ (United States); Newby, R. [Westinghouse Electric Corp., Pittsburgh, PA (United States); Anson, D. [Battelle, Columbus, OH (United States); Wenglarz, R. [Allison Engine Co., Indianapolis, IN (United States); Wright, I. [Oak Ridge National Lab., TN (United States)

1996-06-01T23:59:59.000Z

85

Bioconversion of coal derived synthesis gas to liquid fuels. Quarterly technical progress report, 1 April--30 June 1994  

DOE Green Energy (OSTI)

The overall objective of the project is to develop an integrated two-stage fermentation process for conversion of coal-derived synthesis gas to a mixture of alcohols. This is achieved in two steps. In the first step, Butyribacterium methylotrophicum converts carbon monoxide (CO) to butyric and acetic acids. Subsequent fermentation of the acids by Clostridium acetobutylicum leads to the production of butanol and ethanol. The tasks for this quarter were: development/isolation of superior strains for fermentation of syngas; evaluation of bioreactor configuration for improved mass transfer of syngas; recovery of carbon and electrons from H{sub 2}-CO{sub 2}; initiation of pervaporation for recovery of solvents; and selection of solid support material for trickle-bed fermentation. Technical progress included the following. Butyrate production was enhanced during H{sub 2}/CO{sub 2} (50/50) batch fermentation. Isolation of CO-utilizing anaerobic strains is in progress. Pressure (15 psig) fermentation was evaluated as a means of increasing CO availability. Polyurethane foam packing material was selected for trickle bed solid support. Cell recycle fermentation on syngas operated for 3 months. Acetate was the primary product at pH 6.8. Trickle bed and gas lift fermentor designs were modified after initial water testing. Pervaporation system was constructed. No alcohol selectivity was shown with the existing membranes during initial start-up.

Jain, M.K.; Worden, R.M.; Grethlein, A.

1994-07-18T23:59:59.000Z

86

Development of alternative fuels from coal-derived syngas  

DOE Green Energy (OSTI)

The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels development Unit (AFDU). The program will initially involve a continuation of the work performed under the Liquid Phase Methanol Program but will later draw upon information and technologies generated in current and future DOE-funded contracts, as well as test commercially available catalysts. 1 fig., 3 tabs.

Not Available

1991-03-22T23:59:59.000Z

87

Coal-fueled diesel technology development -- Fuel injection equipment for coal-fueled diesel engines  

DOE Green Energy (OSTI)

Because of the abrasive and corrosive nature of coal water slurries, the development of coal-fueled diesel engine technology by GE-Transportation Systems (GE-TS) required special fuel injection equipment. GE-Corporate Research and Development (GE-CRD) undertook the design and development of fuel injectors, piston pumps, and check valves for this project. Components were tested at GE-CRD on a simulated engine cylinder, which included a cam-actuated jerk pump, prior to delivery to GE-TS for engine testing.

Johnson, R.N.; Hayden, H.L.

1994-01-01T23:59:59.000Z

88

NETL: Coal & Coal Biomass to Liquids - Pittsburgh Coal Conference...  

NLE Websites -- All DOE Office Websites (Extended Search)

CO2 Capture PDF-211KB (June 2003) Overview of Hydrogen Production Options for Hydrogen Energy Development, Fuel-Cell Fuel Processing and Mitigation of CO2 Emissions PDF-285KB...

89

liquid fuels | OpenEI  

Open Energy Info (EERE)

dataset uses million barrels per day. The data is broken down into crude oil, other petroleum supply, other non petroleum supply and liquid fuel consumption. Source EIA Date...

90

Corn/coal fuel characterization study  

DOE Green Energy (OSTI)

Laboratory analyses and tests were conducted to determine the suitability of shelled corn as a potential supplemental fuel for pulverized coal fired utility boilers. The analyses and tests used were those routinely used for the characterization of coal. The data indicated very high volatility and very low ash. Corn by itself would not be a suitable fuel for conventional boilers, primarily because of the severe fouling and slagging potential of corn ash. Blends of corn and coal minimized the fouling and slagging problems. The blend samples contained 10% corn by BTU or 14% by weight. Approximately 1.05 pounds of this blend would provide the heat equivalent of one pound of coal. The additional fuel input would place an additional load on fuel handling and preparation equipment, but the decrease in ash quantity would reduce the load on ash handling and particulate-type flue gas clean-up equipment. (JSR)

Cioffi, P. L.

1978-08-01T23:59:59.000Z

91

CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS  

E-Print Network (OSTI)

I. Solvent Refined Coal II. Catalysts III. Purpose andSondreal, E.A. , "Viscosity of Coal Liquids - The Effect ofAnthraxylon - Kinetics of Coal Hydrogenation," Ind. and Eng.

Tanner, K.I.

2010-01-01T23:59:59.000Z

92

Air blast type coal slurry fuel injector  

SciTech Connect

A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine, and which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

Phatak, Ramkrishna G. (San Antonio, TX)

1986-01-01T23:59:59.000Z

93

Air blast type coal slurry fuel injector  

DOE Patents (OSTI)

A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine is disclosed which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

Phatak, R.G.

1984-08-31T23:59:59.000Z

94

Process to upgrade coal liquids by extraction prior to hydrodenitrogenation  

DOE Patents (OSTI)

Oxygen compounds are removed, e.g., by extraction, from a coal liquid prior to its hydrogenation. As a result, compared to hydrogenation of such a non-treated coal liquid, the rate of nitrogen removal is increased.

Schneider, Abraham (Overbrook Hills, PA); Hollstein, Elmer J. (Wilmington, DE); Janoski, Edward J. (Havertown, PA); Scheibel, Edward G. (Media, PA)

1982-01-01T23:59:59.000Z

95

Mulled coal---A beneficiated coal form for use as a fuel or fuel intermediate  

SciTech Connect

The storage, transport and handling of beneficiated coals in the form of a modified wet cake ( mulled coal'') to yield a coal water fuel having acceptable properties for atomization and combustion on industrial, commercial and/or residential scales, have been investigated. The Mulled Coal project is divided into a series of tasks designed to produce formulations and system designs suitable to convert fine coal wet cakes'' into a material that can be stored, handled, and transported to a site where it can be utilized as a fuel in existing and developing combustion devices. (VC)

Not Available

1991-05-01T23:59:59.000Z

96

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network (OSTI)

Pollutants Associated With Coal Combustion. E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal . . . . Coal Desulfurization

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

97

Assessment of Coal Handling for Fuel Flexibility  

Science Conference Proceedings (OSTI)

To reduce total generating costs, power generators may use multiple solid fuels. This study is a preliminary investigation of the methods and costs of handling multiple solid fuels. An important byproduct of the study was some of the first-ever systematic comparisons of coal handling costs at a sample of plants.

1998-09-03T23:59:59.000Z

98

High-pressure coal fuel processor development  

DOE Green Energy (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. A successful conclusion of the program will enable further component development work and full-scale system demonstrations of this potentially important technology. This paper covers the work on fuel processor rig testing completed in FY92.

Greenhalgh, M.L.; Wen, C.S.; Smith, L.

1992-12-31T23:59:59.000Z

99

High-pressure coal fuel processor development  

DOE Green Energy (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. A successful conclusion of the program will enable further component development work and full-scale system demonstrations of this potentially important technology. This paper covers the work on fuel processor rig testing completed in FY92.

Greenhalgh, M.L.; Wen, C.S.; Smith, L.

1992-01-01T23:59:59.000Z

100

High-pressure coal fuel processor development  

DOE Green Energy (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

8. Biomass-Derived Liquid Fuels  

U.S. Energy Information Administration (EIA)

8. Biomass-Derived Liquid Fuels B. Fuel Ethanol Production and Market Conditions Ethanol is consumed as fuel in the United States primarily as "gasohol"--a blend ...

102

Wear mechanism and wear prevention in coal-fueled diesel engines  

DOE Green Energy (OSTI)

Over the past several years, interest has arisen in the development of coal-fired diesel engines for the purpose of efficiently utilizing the extensive coal reserves in the United States, and therefore reducing dependence on foreign oil. One process, which is being considered for use in producing clean coal fuel products involves mild gasification. This process produces by-products which can be further refined and, when blended with neat diesel fuel, used as an engine fuel. The purpose of this task was to test a blend of this coal liquid and diesel fuel (referred to as coal-lite) in an engine, and determine if any detrimental results were observed. This was done by performing a back-to-back performance and emission test of neat diesel fuel and the coal-lite fuel, followed by a 500-hour test of the coal-lite fuel, and completed by a back-to-back performance and emission test of the coal-lite fuel and neat diesel fuel.

Wakenell, J.F.; Fritz, S.G.; Schwalb, J.A.

1991-07-01T23:59:59.000Z

103

Wear mechanism and wear prevention in coal-fueled diesel engines. Task 7, Extended wear testing  

DOE Green Energy (OSTI)

Over the past several years, interest has arisen in the development of coal-fired diesel engines for the purpose of efficiently utilizing the extensive coal reserves in the United States, and therefore reducing dependence on foreign oil. One process, which is being considered for use in producing clean coal fuel products involves mild gasification. This process produces by-products which can be further refined and, when blended with neat diesel fuel, used as an engine fuel. The purpose of this task was to test a blend of this coal liquid and diesel fuel (referred to as coal-lite) in an engine, and determine if any detrimental results were observed. This was done by performing a back-to-back performance and emission test of neat diesel fuel and the coal-lite fuel, followed by a 500-hour test of the coal-lite fuel, and completed by a back-to-back performance and emission test of the coal-lite fuel and neat diesel fuel.

Wakenell, J.F.; Fritz, S.G.; Schwalb, J.A.

1991-07-01T23:59:59.000Z

104

High-pressure coal fuel processor development  

DOE Green Energy (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. (Caterpillar, Inc., Peoria, IL (United States))

1992-12-01T23:59:59.000Z

105

Alaska coal gasification feasibility studies - Healy coal-to-liquids plant  

SciTech Connect

The Alaska Coal Gasification Feasibility Study entailed a two-phase analysis of the prospects for greater use of Alaska's abundant coal resources in industrial applications. Phase 1, Beluga Coal Gasification Feasibility Study (Report DOE/NETL 2006/1248) assessed the feasibility of using gasification technology to convert the Agrium fertilizer plant in Nikiski, Alaska, from natural gas to coal feedstock. The Phase 1 analysis evaluated coals from the Beluga field near Anchorage and from the Usibelli Coal Mine near Healy, both of which are low in sulfur and high in moisture. This study expands the results of Phase 1 by evaluating a similar sized gasification facility at the Usibelli Coal mine to supply Fischer-Tropsch (F-T) liquids to central Alaska. The plant considered in this study is small (14,640 barrels per day, bbl/d) compared to the recommended commercial size of 50,000 bbl/d for coal-to-liquid plants. The coal supply requirements for the Phase 1 analysis, four million tons per year, were assumed for the Phase 2 analysis to match the probable capacity of the Usibelli mining operations. Alaska refineries are of sufficient size to use all of the product, eliminating the need for F-T exports out of the state. The plant could produce marketable by-products such as sulfur as well as electric power. Slag would be used as backfill at the mine site and CO{sub 2} could be vented, captured or used for enhanced coalbed methane recovery. The unexpected curtailment of oil production from Prudhoe Bay in August 2006 highlighted the dependency of Alaskan refineries (with the exception of the Tesoro facility in Nikiski) on Alaska North Slope (ANS) crude. If the flow of oil from the North Slope declines, these refineries may not be able to meet the in-state needs for diesel, gasoline, and jet fuel. Additional reliable sources of essential fuel products would be beneficial. 36 refs., 14 figs., 29 tabs., 3 apps.

Lawrence Van Bibber; Charles Thomas; Robert Chaney [Research & Development Solutions, LLC (United States)

2007-07-15T23:59:59.000Z

106

Characterization and supply of coal-based fuels  

SciTech Connect

Contract objectives are as follows: Develop fuel specifications to serve combustor requirements; Select coals having appropriate compositional and quality characteristics as well as an economically attractive reserve base; Provide quality assurance for both the parent coals and the fuel forms; and deliver premium coal-based fuels to combustor developers as needed for their contract work. Progress is described.

1989-09-01T23:59:59.000Z

107

Alternative Liquid Fuels Simulation Model (AltSim).  

Science Conference Proceedings (OSTI)

The Alternative Liquid Fuels Simulation Model (AltSim) is a high-level dynamic simulation model which calculates and compares the production costs, carbon dioxide emissions, and energy balances of several alternative liquid transportation fuels. These fuels include: corn ethanol, cellulosic ethanol, biodiesel, and diesels derived from natural gas (gas to liquid, or GTL) and coal (coal to liquid, or CTL). AltSim allows for comprehensive sensitivity analyses on capital costs, operation and maintenance costs, renewable and fossil fuel feedstock costs, feedstock conversion efficiency, financial assumptions, tax credits, CO{sub 2} taxes, and plant capacity factor. This paper summarizes the preliminary results from the model. For the base cases, CTL and cellulosic ethanol are the least cost fuel options, at $1.60 and $1.71 per gallon, respectively. Base case assumptions do not include tax or other credits. This compares to a $2.35/gallon production cost of gasoline at September, 2007 crude oil prices ($80.57/barrel). On an energy content basis, the CTL is the low cost alternative, at $12.90/MMBtu, compared to $22.47/MMBtu for cellulosic ethanol. In terms of carbon dioxide emissions, a typical vehicle fueled with cellulosic ethanol will release 0.48 tons CO{sub 2} per year, compared to 13.23 tons per year for coal to liquid.

Baker, Arnold Barry; Williams, Ryan (Hobart and William Smith Colleges, Geneva, NY); Drennen, Thomas E.; Klotz, Richard (Hobart and William Smith Colleges, Geneva, NY)

2007-10-01T23:59:59.000Z

108

Development of high energy density fuels from mild gasification of coal. Final report  

SciTech Connect

METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily ``skimmed`` from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

Not Available

1991-12-01T23:59:59.000Z

109

Photodegradation of mutagens in solvent-refined coal liquids  

SciTech Connect

The purpose of this investigation was to evaluate any changes in the chemical composition and microbial mutagenicities of two representative solvent-refined coal (SRC) liquids as a function of exposure time to sunlight and air. This information was desired to assess potential health hazards arising from ground spills of these liquids during production, transport and use. Results of microbial mutagenicity assays using Salmonella typhimurium TA98, conducted after exposure, showed that the mutagenicities of both an SRC-II fuel oil blend and an SRC-I process solvent decreased continuously with exposure time to air and that the decrease was accelerated by simultaneous exposure to simulated sunlight. The liquids were exposed as thin layers supported on surfaces of glass, paper, clay or aluminum; but the type of support had little effect on the results. The contrast between these results and the reported increases of mutagenesis in organisms exposed simultaneously to coal liquids and near-ultraviolet light suggested that short-lived mutagenic intermediates, e.g., organic free radicals, were formed in the liquids during exposure to light. The highest activities of microbial mutagenicity in the SRC liquids were found in fractions rich in amino polycyclic aromatic hydrocarbons (amino PAH). After a 36-hour exposure of the fuel oil blend to air in the dark, the mutagenicity of its amine-rich fraction was reduced by 65%; whereas a 36-hour exposure in the light reduced the mutagenicity of this fraction by 92%. Similar rates of reduction in mutagenicity were achieved in exposures of the process solvent. The mutagenicities of other chemical fractions remained low during exposure.

Kalkwarf, D.R.; Stewart, D.L.; Pelroy, R.A.; Weimer, W.C.

1984-04-01T23:59:59.000Z

110

Thermodynamic and rheological properties of solid-liquid systems in coal processing. Final technical report  

Science Conference Proceedings (OSTI)

The work on this project was initiated on September 1, 1991. The project consisted of two different tasks: (1) Development of a model to compute viscosities of coal derived liquids, and (2) Investigate new models for estimation of thermodynamic properties of solid and liquid compounds of the type that exist in coal, or are encountered during coal processing. As for task 1, a model for viscosity computation of coal model compound liquids and coal derived liquids has been developed. The detailed model is presented in this report. Two papers, the first describing the pure liquid model and the second one discussing the application to coal derived liquids, are expected to be published in Energy & Fuels shortly. Marginal progress is reported on task 2. Literature review for this work included compilation of a number of data sets, critical investigation of data measurement techniques available in the literature, investigation of models for liquid and solid phase thermodynamic computations. During the preliminary stages it was discovered that for development of a liquid or solid state equation of state, accurate predictive models for a number of saturation properties, such as, liquid and solid vapor pressures, saturated liquid and solid volumes, heat capacities of liquids and solids at saturation, etc. Most the remaining time on this task was spent in developing predictive correlations for vapor pressures and saturated liquid volumes of organic liquids in general and coal model liquids in particular. All these developments are discussed in this report. Some recommendations for future direction of research in this area are also listed.

Kabadi, V.N.

1995-06-30T23:59:59.000Z

111

Liquid fuel reformer development.  

DOE Green Energy (OSTI)

At Argonne National Laboratory we are developing a process to convert hydrocarbon fuels to a clean hydrogen feed for a fuel cell. The process incorporates a partial oxidation/steam reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. We have tested the catalyst with three diesel-type fuels: hexadecane, low-sulfur diesel fuel, and a regular diesel fuel. We achieved complete conversion of the feed to products. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 800 C. For the two diesel fuels, higher temperatures, >850 C, were required to approach similar levels of hydrogen in the product stream. At 800 C, hydrogen yield of the low sulfur diesel was 32%, while that of the regular diesel was 52%. Residual products in both cases included CO, CO{sub 2}, ethane, ethylene, and methane.

Ahmed, S.; Krumpelt, M.; Pereira, C.; Wilkenhoener, R.

1999-07-30T23:59:59.000Z

112

Process for blending coal with water immiscible liquid  

DOE Patents (OSTI)

A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

Heavin, Leonard J. (Olympia, WA); King, Edward E. (Gig Harbor, WA); Milliron, Dennis L. (Lacey, WA)

1982-10-26T23:59:59.000Z

113

EIS-0432: Department of Energy Loan Guarantee for Medicine Bow Gasification and Liquefaction Coal-to-Liquids, Carbon County, Wyoming  

Energy.gov (U.S. Department of Energy (DOE))

DOE is assessing the potential environmental impacts for its proposed action of issuing a Federal loan guarantee to Medicine Bow Fuel & Power LLC (MBFP), a wholly-owned subsidiary of DKRW Advanced Fuels LLC. MBFP submitted an application to DOE under the Federal loan guarantee program pursuant to the Energy Policy Act of 2005 to support the construction and startup of the MBFP coal-to-liquids facility, a coal mine and associated coal handling facilities.

114

Adapting Fuels Management to a Changing Coal Market  

Science Conference Proceedings (OSTI)

The coal and coal transportation markets have changed significantly over the past several years. A trend that is most likely to require strategic changes in coal procurement organizations is greater commoditization, meaning that these markets will tend to become more standardized, more liquid, more volatile, and more financially driven. This report analyzes how these and other developments are likely to change the coal and coal transportation markets over the next one to three years and how coal-fired ge...

2001-08-23T23:59:59.000Z

115

Figure 51. World production of liquids from biomass, coal ...  

U.S. Energy Information Administration (EIA)

Title: Figure 51. World production of liquids from biomass, coal, and natural gas in three cases, 2011 and 2040 (million barrels per day) Subject

116

NETL: Coal & Coal Biomass to Liquids - Project Information  

NLE Websites -- All DOE Office Websites (Extended Search)

Project Information CoalBiomass Feed and Gasification Development of Biomass-Infused Coal Briquettes for Co-Gasification FE0005293 Development of Kinetics and Mathematical...

117

CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS  

E-Print Network (OSTI)

and Friedman, S. ,"Conversion of Anthraxylon - Kinetics ofiv- LBL 116807 CATALYTIC CONVERSION OF SOLVENT REFINED COALand Mechanisms of Coal Conversion to Clean Fuel,iI pre-

Tanner, K.I.

2010-01-01T23:59:59.000Z

118

Coal-fueled diesel technology development: Nozzle development for coal-fueled diesel engines  

SciTech Connect

Direct injection of a micronized coal water mixture fuel into the combustion chambers of a diesel engine requires atomizing an abrasive slurry fuel with accurately sized orifices. Five injector orifice materials were evaluated: diamond compacts, chemical vapor deposited diamond tubes, thermally stabilized diamond, tungsten carbide with cobalt binder, and tungsten carbide with nickel binder with brazed and mechanically mounted orifice inserts. Nozzle bodies were fabricated of Armco 17-4 precipitation hardening stainless steel and Stellite 6B in order to withstand cyclic injection pressures and elevated temperatures. Based on a total of approximately 200 cylinder hours of engine operation with coal water mixture fuel diamond compacts were chosen for the orifice material.

Johnson, R.N.; Lee, M.; White, R.A.

1994-01-01T23:59:59.000Z

119

NETL: Coal & Coal Biomass to Liquids - NETL H2-from-Coal Separations  

NLE Websites -- All DOE Office Websites (Extended Search)

and Coal/Biomass to Liquids - Reference Shelf and Coal/Biomass to Liquids - Reference Shelf NETL H2-from-Coal Separations Project Reviews April 29-30, 2008 National Energy Technology Laboratory Morgantown, WV Presentations NETL/ORD In-House Membrane Research Bryan Morreale - National Energy Technology Laboratory Development of Mixed-Conducting Dense Ceramic Membranes for Hydrogen Separation [PDF-1.4MB] Hydrogen Production by Water Dissociation Using Ceramic Membranes Balu Balachandran - Argonne National Laboratory High Flux Metallic Membranes for Hydrogen Recovery and Membrane Reactors [PDF-505KB] Robert Buxbaum - REB Research and Consulting Scale-Up of Hydrogen Transport Membranes for IGCC and FutureGen Plants Doug Jack - Eltron Research Sulfur and Halide Tolerance Kent Coulter - Southwest Research Institute

120

Refining and end use study of coal liquids. Quarterly report, October--December 1995  

Science Conference Proceedings (OSTI)

Bechtel, with South west research Institute, Amoco Oil R&D, and the M. W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the US Department of Energy`s Pittsburgh Energy Technology Center to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. To enhance management of the study, the work has been divided into two parts, the Basic Program and Option 1. The objectives of the Basic Program are to: characterize the coal liquids; develop an optimized refinery configuration for processing indirect and direct coal liquids; and develop a LP refinery model with Process Industry Modeling System software. The objective of Option 1 are to: confirm the validity of the optimization work of the Basic Program; produce large quantities of liquid transportation fuel blending stocks; conduct engine emission tests; and determine the value and the processing costs of the coal liquids. The major effort conducted during the fourth quarter of 1995 were in the areas of: IL catalytic cracking--microactivity tests were conducted on various wax blends; IL wax hydrocracking--a pilot plant run was conducted on a wax/petroleum blend; and DL2 characterization and fractionation.

NONE

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Development of alternative fuels from coal-derived syngas  

SciTech Connect

The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products' laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively benign'' system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE's program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

Brown, D.M.

1992-05-19T23:59:59.000Z

122

Synthetic liquid fuels development: assessment of critical factors. Volume IV. Energy/economic comparison of coal-based automotive energy supply systems  

DOE Green Energy (OSTI)

Considerable debate has occurred in recent years about the relative merits of energy analysis versus traditional economic analysis. Some economists assert that energy analysis adds no new information to that in economic analysis; energy analysts claim that the explicit consideration of energy flows is necessary for a complete understanding of the implications of energy supply and use. In comparing the cost and energy consumption figures for the various automotive energy options, certain parallels are evident. Those system components that have the highest costs also require high levels of energy consumption. This is generally due to the severity of the processing conditions required to convert one energy form (e.g., coal) to another (e.g., methanol). These conditions require the use of capital-intensive equipment as well as the consumption of large amounts of energy. For some components that have relatively high costs but low energy requirements (e.g., fuel distribution), the costs are due to the many handling and transfer requirements. Overall, the capital- and energy-intensive energy conversion processes dominate the systems we have examined. Therefore, a comparison of cost with energy consumption for all the fuels considered shows a definite trend - increasing costs imply increasing energy consumption. Thus, decision makers concerned with promoting energy conservative supply options need not worry that their choices will be unduly costly. Rather, they will tend to be the least costly for the types of systems considered here. We caution against extrapolating these results to other systems, however, because systems that do not have the same kinds of capital- and energy-intensive components as those considered here may exhibit different trends.

Steele, R.V.; Sharma, K.J.; Dickson, E.M.

1977-02-01T23:59:59.000Z

123

Coal Integrated Gasification Fuel Cell System Study  

DOE Green Energy (OSTI)

This study analyzes the performance and economics of power generation systems based on Solid Oxide Fuel Cell (SOFC) technology and fueled by gasified coal. System concepts that integrate a coal gasifier with a SOFC, a gas turbine, and a steam turbine were developed and analyzed for plant sizes in excess of 200 MW. Two alternative integration configurations were selected with projected system efficiency of over 53% on a HHV basis, or about 10 percentage points higher than that of the state-of-the-art Integrated Gasification Combined Cycle (IGCC) systems. The initial cost of both selected configurations was found to be comparable with the IGCC system costs at approximately $1700/kW. An absorption-based CO2 isolation scheme was developed, and its penalty on the system performance and cost was estimated to be less approximately 2.7% and $370/kW. Technology gaps and required engineering development efforts were identified and evaluated.

Chellappa Balan; Debashis Dey; Sukru-Alper Eker; Max Peter; Pavel Sokolov; Greg Wotzak

2004-01-31T23:59:59.000Z

124

Refining and end use of coal liquids. Quarterly report, January--March 1994  

Science Conference Proceedings (OSTI)

A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An intregral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. To enhance management of the study, the work has been divided into two parts, the Basic Program and Option 1. The objectives of the Basic Program are to: characterize the coal liquids; develop, an optimized refinery configuration for processing indirect and direct coal liquids; and develop a LP refinery model with the Process Industry Modeling System (PICS) software. The objectives of Option 1 are to: confirm the validity of the optimization work of the Basic Program; produce large quantities of liquid transportation fuel blending stocks; conduct engine emission tests; and determine the value and the processing costs of the coal liquids. The major efforts conducted during the first quarter of 1994 were in the areas of: subcontract preparation and negotiation; and linear programming modeling.

Not Available

1994-08-01T23:59:59.000Z

125

Refining and End Use Study of Coal Liquids  

SciTech Connect

This report summarizes revisions to the design basis for the linear programing refining model that is being used in the Refining and End Use Study of Coal Liquids. This revision primarily reflects the addition of data for the upgrading of direct coal liquids.

None

1997-10-01T23:59:59.000Z

126

Combustion characterization of coal-water slurry fuel  

SciTech Connect

As a result of coal cleaning operations, a substantial amount of coal is disposed as waste into the ponds, effecting and endangering the environment. This study includes a technique to recover and utilize the waste coal fines from the preparation plant effluent streams and tailing ponds. Due to the large moisture content of the recovered coal fines, this investigation is focused on the utilization of coal fines in the coal-water slurry fuel. It is our belief that a blend of plant coal and waste coal fines can be used to produce a coal-water slurry fuel with the desired combustion characteristics required by the industry. The coal blend is composed of 85% clean coal and 15% recovered coal fines. The coal-water slurry is prepared at 60% solids with a viscosity less than 500 centipose and 80-90% of solid particles passing through 200 mesh. This paper contains analysis of clean coal, recovered coal fines, and coal-water slurry fuel as well as combustion characteristics.

Masudi, Houshang; Samudrala, S.

1996-12-31T23:59:59.000Z

127

Liquid fossil fuel technology. Quarterly technical progress report, July-September 1979  

Science Conference Proceedings (OSTI)

The in-house results at Bartlesville Energy Technology Center on the liquid fossil fuel cycle are presented. The cycle covers extraction, processing, utilization, and environmental technology of the liquid fuels derived from petroleum, heavy oils, tar sands, oil shale, and coal.

Linville, B. (ed.)

1980-02-01T23:59:59.000Z

128

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network (OSTI)

of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" CEP Aug. 78. Feed

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

129

Advanced coal-fueled gas turbine systems  

DOE Green Energy (OSTI)

Westinghouse's Advanced Coal-Fueled Gas Turbine System Program (DE-AC2l-86MC23167) was originally split into two major phases - a Basic Program and an Option. The Basic Program also contained two phases. The development of a 6 atm, 7 lb/s, 12 MMBtu/hr slagging combustor with an extended period of testing of the subscale combustor, was the first part of the Basic Program. In the second phase of the Basic Program, the combustor was to be operated over a 3-month period with a stationary cascade to study the effect of deposition, erosion and corrosion on combustion turbine components. The testing of the concept, in subscale, has demonstrated its ability to handle high- and low-sulfur bituminous coals, and low-sulfur subbituminous coal. Feeding the fuel in the form of PC has proven to be superior to CWM type feed. The program objectives relative to combustion efficiency, combustor exit temperature, NO[sub x] emissions, carbon burnout, and slag rejection have been met. Objectives for alkali, particulate, and SO[sub x] levels leaving the combustor were not met by the conclusion of testing at Textron. It is planned to continue this testing, to achieve all desired emission levels, as part of the W/NSP program to commercialize the slagging combustor technology.

Not Available

1992-09-01T23:59:59.000Z

130

American Clean Coal Fuels | Open Energy Information  

Open Energy Info (EERE)

Fuels Fuels Jump to: navigation, search Name American Clean Coal Fuels Address 123 NW 12th ave Place Portland, Oregon Zip 97209 Sector Biofuels Product Uses gasification to turn carbon based feedstocks into syngas for biofuels Website http://www.cleancoalfuels.com/ Coordinates 45.5238219°, -122.6831677° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":45.5238219,"lon":-122.6831677,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

131

Hydrogenation of coal liquid utilizing a metal carbonyl catalyst  

DOE Patents (OSTI)

Coal liquid having a dissolved transition metal, catalyst as a carbonyl complex such as Co.sub.2 (CO.sub.8) is hydrogenated with hydrogen gas or a hydrogen donor. A dissociating solvent contacts the coal liquid during hydrogenation to form an immiscible liquid mixture at a high carbon monoxide pressure. The dissociating solvent, e.g. ethylene glycol, is of moderate coordinating ability, while sufficiently polar to solvate the transition metal as a complex cation along with a transition metal, carbonyl anion in solution at a decreased carbon monoxide pressure. The carbon monoxide pressure is reduced and the liquids are separated to recover the hydrogenated coal liquid as product. The dissociating solvent with the catalyst in ionized form is recycled to the hydrogenation step at the elevated carbon monoxide pressure for reforming the catalyst complex within fresh coal liquid.

Feder, Harold M. (Hinsdale, IL); Rathke, Jerome W. (Bolingbrook, IL)

1979-01-01T23:59:59.000Z

132

Superheated fuel injection for combustion of liquid-solid slurries  

DOE Patents (OSTI)

A method and device for obtaining, upon injection, flash evaporation of a liquid in a slurry fuel to aid in ignition and combustion. The device is particularly beneficial for use of coal-water slurry fuels in internal combustion engines such as diesel engines and gas turbines, and in external combustion devices such as boilers and furnaces. The slurry fuel is heated under pressure to near critical temperature in an injector accumulator, where the pressure is sufficiently high to prevent boiling. After injection into a combustion chamber, the water temperature will be well above boiling point at a reduced pressure in the combustion chamber, and flash boiling will preferentially take place at solid-liquid surfaces, resulting in the shattering of water droplets and the subsequent separation of the water from coal particles. This prevents the agglomeration of the coal particles during the subsequent ignition and combustion process, and reduces the energy required to evaporate the water and to heat the coal particles to ignition temperature. The overall effect will be to accelerate the ignition and combustion rates, and to reduce the size of the ash particles formed from the coal.

Robben, Franklin A. (Berkeley, CA)

1985-01-01T23:59:59.000Z

133

Superheated fuel injection for combustion of liquid-solid slurries  

DOE Patents (OSTI)

A method and device are claimed for obtaining, upon injection, flash evaporation of a liquid in a slurry fuel to aid in ignition and combustion. The device is particularly beneficial for use of coal-water slurry fuels in internal combustion engines such as diesel engines and gas turbines, and in external combustion devices such as boilers and furnaces. The slurry fuel is heated under pressure to near critical temperature in an injector accumulator, where the pressure is sufficiently high to prevent boiling. After injection into a combustion chamber, the water temperature will be well above boiling point at a reduced pressure in the combustion chamber, and flash boiling will preferentially take place at solid-liquid surfaces, resulting in the shattering of water droplets and the subsequent separation of the water from coal particles. This prevents the agglomeration of the coal particles during the subsequent ignition and combustion process, and reduces the energy required to evaporate the water and to heat the coal particles to ignition temperature. The overall effect will be to accelerate the ignition and combustion rates, and to reduce the size of the ash particles formed from the coal. 2 figs., 2 tabs.

Robben, F.A.

1984-10-19T23:59:59.000Z

134

Coal likely to remain most prevalent fuel for electricity ...  

U.S. Energy Information Administration (EIA)

Coal is currently the dominant fuel for electricity generation and is likely to remain so, even if additional environmental control regulations ...

135

Coal Fuels Alliance: Design and Construction of Early Lead Mini...  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal Fuels Alliance: Design and Construction of Early Lead Mini Fischer-Tropsch Refinery University of Kentucky Center for Applied Energy Research (CAER) Project Number: NT0005988...

136

NETL: Novel Oxygen Carriers for Coal-Fueled Chemical Looping...  

NLE Websites -- All DOE Office Websites (Extended Search)

Chemical Looping Combustion Project No.: DE-FE0001808 NETL has partnered with Western Kentucky University to develop a series of advanced oxygen carriers for coal-fueled...

137

Coal derived fuel gases for molten carbonate fuel cells  

DOE Green Energy (OSTI)

Product streams from state-of-the-art and future coal gasification systems are characterized to guide fuel cell program planners and researchers in establishing performance goals and developing materials for molten carbonate fuel cells that will be compatible with gasifier product gases. Results are presented on: (1) the range of gasifier raw-gas compositions available from the major classes of coal gasifiers; (2) the degree of gas clean-up achievable with state-of-the-art and future gas clean-up systems; and (3) the energy penalties associated with gas clean-up. The study encompasses fixed-bed, fluid-bed, entrained-bed, and molten salt gasifiers operating with Eastern bituminous and Western subbituminous coals. Gasifiers operating with air and oxygen blowing are evaluated, and the coal gasification product streams are characterized with respect to: (1) major gas stream constituents, e.g., CO, H/sub 2/, CO/sub 2/, CH/sub 4/, N/sub 2/, H/sub 2/O; (2) major gas stream contaminants, e.g., H/sub 2/S, COS, particulates, tars, etc.; and (3) trace element contaminants, e.g., Na, K, V, Cl, Hg, etc.

Not Available

1979-11-01T23:59:59.000Z

138

REFINING AND END USE STUDY OF COAL LIQUIDS  

DOE Green Energy (OSTI)

This document summarizes all of the work conducted as part of the Refining and End Use Study of Coal Liquids. There were several distinct objectives set, as the study developed over time: (1) Demonstration of a Refinery Accepting Coal Liquids; (2) Emissions Screening of Indirect Diesel; (3) Biomass Gasification F-T Modeling; and (4) Updated Gas to Liquids (GTL) Baseline Design/Economic Study.

Unknown

2002-01-01T23:59:59.000Z

139

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS  

DOE Green Energy (OSTI)

The following are proposed activities for quarter 1 (6/15/00-9/14/00): (1) Finalize the allocation of funds within TAMU to co-principal investigators and the final task lists; (2) Acquire 3 D computer code for coal combustion and modify for cofiring Coal:Feedlot biomass and Coal:Litter biomass fuels; (3) Develop a simple one dimensional model for fixed bed gasifier cofired with coal:biomass fuels; and (4) Prepare the boiler burner for reburn tests with feedlot biomass fuels. The following were achieved During Quarter 5 (6/15/00-9/14/00): (1) Funds are being allocated to co-principal investigators; task list from Prof. Mukhtar has been received (Appendix A); (2) Order has been placed to acquire Pulverized Coal gasification and Combustion 3 D (PCGC-3) computer code for coal combustion and modify for cofiring Coal: Feedlot biomass and Coal: Litter biomass fuels. Reason for selecting this code is the availability of source code for modification to include biomass fuels; (3) A simplified one-dimensional model has been developed; however convergence had not yet been achieved; and (4) The length of the boiler burner has been increased to increase the residence time. A premixed propane burner has been installed to simulate coal combustion gases. First coal, as a reburn fuel will be used to generate base line data followed by methane, feedlot and litter biomass fuels.

Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

2000-10-24T23:59:59.000Z

140

Advanced Coal-Fueled Gas Turbine Program  

SciTech Connect

The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

1989-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Liquid fossil fuel technology. Quarterly technical progress report, January-March 1981  

SciTech Connect

The Bartlesville Energy Technology Center's research activities are summarized under the following headings: liquid fossil fuel cycle; extraction which is subdivided into resource assessment and production; liquid processing which includes characterization of liquids from petroleum, coal, shale and other alternate sources, thermodynamics and process technology; utilization; and project integration and technology transfer. (ATT)

Not Available

1981-08-01T23:59:59.000Z

142

Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer  

NLE Websites -- All DOE Office Websites (Extended Search)

Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer Tropsch Catalyst Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer Tropsch Catalyst Southern Research Institute Project Number: FE0010231 Project Description Fischer-Tropsch (FT) process converts a mixture of carbon monoxide and hydrogen, called syngas, into liquid hydrocarbons. It is a leading technology for converting syngas derived from gasification of coal and coal-biomass mixtures to hydrocarbons in coal to liquids (CTL) and coal-biomass to liquids (CBTL) processes. However, conventional FTS catalysts produce undesirable waxes (C21+) that need to be upgraded to liquids (C5-C20) by hydrotreating. This adds significantly to the cost of FTS. The objectives of this project are (i) to demonstrate potential for CBTL cost reduction by maximizing the production of C5-C20 hydrocarbon liquids using a selective FTS catalyst and (ii) to evaluate the impacts of the addition of biomass to coal on product characteristics, carbon foot print, and economics.

143

Preconversion processing of bituminous coals: New directions to improved direct catalytic coal liquefaction. [High temperature soaking coal in coal liquids prior to liquefaction  

SciTech Connect

Soaking coal in coal liquids at 300-400[degrees]C (high-tenperature soaking) has been studied for coal dissolution prior to liquefaction in the previous task. Two high-volatile bituminous coals, Illinois No. 6 and Pittsburgh No. 8, were examined in three different coal liquids. The high-temperature soaking was effective to solubilize more than 70 wt% cf these coals. The mechanism of disintegration of coal by the high-temperature soaking was investigated under various soaking conditions. The products was also analyzed with solvent swelling. These results were rationalized that coal is solubilized primarily by physical disintegration. The derived mechanism was consistent with the new concept of coal structure: A significant portion of coal is physically associated, not three-dimensionally cross-linked. Radically-induced scission reactions were proposed to prorate breakage of coal moleculs by the combination of the high-temperature soaking before liquefaction. In this term, the effect of radical initiators were investigated under the conditions of the high-temperature soaking and liquefaction. Illinois No. 6 coal and a coal liquid derived from the same coal were used. The first section reports the effect of radical initiators on coal disintegration, and the second section reports the effect of a radical initiator on coal liquefaction. Radical initiators had a positive effect on disintegration. However, the effect was highly temperature-dependent and had a negative effect on liquefaction at high tenperatures.

1992-10-01T23:59:59.000Z

144

Liquid chromatographic analysis of coal surface properties  

SciTech Connect

Experimental procedures of obtaining experimental data on equilibrium adsorption of probe compounds on coal were developed. A computer program was developed to compute equilibrium adsorption of probe compounds on coal with experimental data. Developments of experimental procedures of obtaining experimental data on dynamic adsorption of probe compounds on coal were attempted, but not finalized. Experiments on equilibrium adsorption of various alcohols on Illinois No. 6 coal will be conducted to investigate surface properties of this coal in the presence of water.

Kwon, K.C.

1992-01-01T23:59:59.000Z

145

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production Southern Research Institute (SRI) Project Number: FE0012054 Project Description The focus of the project will be to develop, test, and optimize steam-reforming catalysts for converting tars, C2+ hydrocarbons, NH3, and CH4 in high-temperature and sulfur environments, increasing the ratio of hydrogen in syngas, as part of a modified, advanced gasification platform for the conversion of low-rank coals to syngas for coal-to-liquid and integrated gasification combined cycle applications. Project Details Program Background and Project Benefits Project Scope and Technology Readiness Level Accomplishments Contacts, Duration, and Cost Project Images Abstract Performer website: Southern Research Institute

146

REFINING AND END USE STUDY OF COAL LIQUIDS  

Science Conference Proceedings (OSTI)

Two direct coal liquids were evaluated by linear programming analysis to determine their value as petroleum refinery feedstock. The first liquid, DL1, was produced from bitiuminous coal using the Hydrocarbon Technologies, Inc.(HTI) two-stage hydrogenation process in Proof of Concept Run No.1, POC-1. The second liquid, DL2,was produced from sub-bituminous coal using a three-stage HTI process in Proof of Concept Run No. 2, POC-2; the third stage being a severe hydrogenation process. A linear programming (LP) model was developed which simulates a generic 150,000 barrel per day refinery in the Midwest U.S. Data from upgrading tests conducted on the coal liquids and related petroleum fractions in the pilot plant testing phase of the Refining and End Use Study was inputed into the model. The coal liquids were compared against a generic petroleum crude feedstock. under two scenarios. In the first scenario, it was assumed that the refinery capacity and product slate/volumes were fixed. The coal liquids would be used to replace a portion of the generic crude. The LP results showed that the DL1 material had essentially the same value as the generic crude. Due to its higher quality, the DL2 material had a value of approximately 0.60 $/barrel higher than the petroleum crude. In the second scenario, it was assumed that a market opportunity exists to increase production by one-third. This requires a refinery expansion. The feedstock for this scenario could be either 100% petroleum crude or a combination of petroleum crude and the direct coal liquids. Linear programming analysis showed that the capital cost of the refinery expansion was significantly less when coal liquids are utilized. In addition, the pilot plant testing showed that both of the direct coal liquids demonstrated superior catalytic cracking and naphtha reforming yields. Depending on the coal liquid flow rate, the value of the DL1 material was 2.5-4.0 $/barrel greater than the base petroleum crude, while the DL2 material was 3.0-4.0 /barrel higher than the crude. Co-processing the coal liquids with lower quality, less expensive petroleum crudes that have higher sulfur, resid and metals contents was also examined. The coal liquids have higher values under this scenario, but the values are dependent on the prices of the alternative crudes.

NONE

1998-08-12T23:59:59.000Z

147

Solids precipitation and polymerization of asphaltenes in coal-derived liquids  

DOE Patents (OSTI)

The precipitation and removal of particulate solids from coal-derived liquids by adding a process-derived anti-solvent liquid fraction and continuing the precipitation process at a temperature above the melting point of the mixed liquids for sufficient time to allow the asphaltenes to polymerize and solids to settle at atmospheric pressure conditions. The resulting clarified light hydrocarbon overflow liquid contains less than about 0.02 W % ash and is suitable as turbine fuel or as boiler fuel for burning without particulate emission control equipment. An underflow liquid fraction containing less than about 0.1 W % solids along with low sulfur and nitrogen concentrations is suitable as a boiler fuel with emission control equipment.

Kydd, Paul H. (Lawrenceville, NJ)

1984-01-01T23:59:59.000Z

148

NETL: Coal & Coal Biomass to Liquids - Alternate Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Deepwater Technology Enhanced Oil Recovery Gas Hydrates Natural Gas Resources Contacts Coal & Power Systems Major Demonstrations Innovations for Existing Plants Gasification...

149

NETL: Coal & Coal Biomass to Liquids - Systems Studies  

NLE Websites -- All DOE Office Websites (Extended Search)

Deepwater Technology Enhanced Oil Recovery Gas Hydrates Natural Gas Resources Contacts Coal & Power Systems Major Demonstrations Innovations for Existing Plants Gasification...

150

NETL: Coal & Coal Biomass to Liquids - Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Deepwater Technology Enhanced Oil Recovery Gas Hydrates Natural Gas Resources Contacts Coal & Power Systems Major Demonstrations Innovations for Existing Plants Gasification...

151

NETL: Coal & Coal Biomass to Liquids - H2 Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Demonstration of Pressurizing CoalBiomass Mixtures Using Posimetric Solids Pump Technology PDF-626KB (Feb 2011) Nanoporous, Metal Carbide, Surface Diffusion Membranes for...

152

Refining and end use study of coal liquids. Quarterly report, July-- September 1995  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M.W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the US Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed.

NONE

1995-12-31T23:59:59.000Z

153

Program on Technology Innovation: Liquid CO2 Coal Slurry for Feeding Coal to Gasifiers  

Science Conference Proceedings (OSTI)

Liquid CO2 (CO2(l)) has several property differences from water that make it attractive for the coal slurries used in coal-gasification-based power plants. Liquid CO2 has a heat of vaporization that is less than one-quarter of that of water, and it has lower viscosity. Since future coal-based power plants may have to control CO2 emissions by use of a CO2 capture and storage system, it may make economic sense to recycle some of the captured CO2 back to the coal feeding system where it could be used as the...

2010-06-30T23:59:59.000Z

154

ADVANCED HETEROGENEOUS REBURN FUEL FROM COAL AND HOG MANURE  

DOE Green Energy (OSTI)

This study was performed to investigate whether the nitrogen content inherent in hog manure and alkali used as a catalyst during processing could be combined with coal to produce a reburn fuel that would result in advanced reburning NO{sub x} control without the addition of either alkali or ammonia/urea. Fresh hog manure was processed in a cold-charge, 1-gal, batch autoclave system at 275 C under a reducing atmosphere in the presence of an alkali catalyst. Instead of the expected organic liquid, the resulting product was a waxy solid material. The waxy nature of the material made size reduction and feeding difficult as the material agglomerated and tended to melt, plugging the feeder. The material was eventually broken up and sized manually and a water-cooled feeder was designed and fabricated. Two reburn tests were performed in a pilot-scale combustor. The first test evaluated a reburn fuel mixture comprising lignite and air-dried, raw hog manure. The second test evaluated a reburn fuel mixture made of lignite and the processed hog manure. Neither reburn fuel reduced NO{sub x} levels in the combustor flue gas. Increased slagging and ash deposition were observed during both reburn tests. The material-handling and ash-fouling issues encountered during this study indicate that the use of waste-based reburn fuels could pose practical difficulties in implementation on a larger scale.

Melanie D. Jensen; Ronald C. Timpe; Jason D. Laumb

2003-09-01T23:59:59.000Z

155

Novel injector techniques for coal-fueled diesel engines  

DOE Green Energy (OSTI)

This report, entitled Novel Injector Techniques for Coal-Fueled Diesel Engines,'' describes the progress and findings of a research program aimed at development of a dry coal powder fuel injector in conjunction with the Thermal Ignition Combustion System (TICS) concept to achieve autoignition of dry powdered coal in a single-cylinder high speed diesel engine. The basic program consisted of concept selection, analysis and design, bench testing and single cylinder engine testing. The coal injector concept which was selected was a one moving part dry-coal-powder injector utilizing air blast injection. Adiabatics has had previous experience running high speed diesel engines on both direct injected directed coal-water-slurry (CWS) fuel and also with dry coal powder aspirated into the intake air. The Thermal Ignition Combustion System successfully ignited these fuels at all speeds and loads without requiring auxiliary ignition energy such as pilot diesel fuel, heated intake air or glow or spark plugs. Based upon this prior experience, it was shown that the highest efficiency and fastest combustion was with the dry coal, but that the use of aspiration of coal resulted in excessive coal migration into the engine lubrication system. Based upon a desire of DOE to utilize a more modern test engine, the previous naturally-aspirated Caterpillar model 1Y73 single cylinder engine was replaced with a turbocharged (by use of shop air compressor and back pressure control valve) single cylinder version of the Cummins model 855 engine.

Badgley, P.R.

1992-09-01T23:59:59.000Z

156

Refining and end use study of coal liquids. Quarterly report, October--December 1996  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M.W. Kellog Co. as subcontractors, initiated a study on November 1, 1993 for the US Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. The work has been divided into two parts, the Basic Program and Option 1. The objectives of the Basic Program are to characterize the coal liquids, develop an optimized refinery configuration for processing indirect and direct coal liquids, and develop a LP refinery model with the Process Industry Modeling System (PIMS) software. The objectives of Option 1 are to confirm the validity of the optimization work of the Basic Program, produce large quantities of liquid transportation fuel blending stocks, conduct engine emission tests, and determine the value and the processing costs of the coal liquids. The major efforts during the reporting period, October through December 1996, were in the areas of Option 1 blending and Option 1 FCC production run.

NONE

1996-12-31T23:59:59.000Z

157

Combustion and fuel characterization of coal-water fuels  

Science Conference Proceedings (OSTI)

Pittsburgh Energy Technology Center (PETC) of the Department of Energy initiated a comprehensive effort in 1982 to develop the necessary performance and cost data and to assess the commercial viability of coal-water fuels (CWFs) as applied to representative utility and industrial units. The effort comprised six tasks beginning with coal resource evaluation and culminating in the assessment of the technical and economic consequences of switching representative commercial units from oil to state-of-the-art CWF firing. Extensive bench, pilot and commercial-scale tests were performed to develop necessary CWF combustion and fireside performance data for the subsequent boiler performance analyses and retrofit cost estimates. Discussions on transport, rheology, combustion properties, and ash characterization are included. 11 refs., 9 figs., 7 tabs.

Chow, O.K.; Patel, R.L.; Levasseur, A.A.

1987-07-01T23:59:59.000Z

158

Biomass and coal into Liquid Review Page.ppt  

Title: Microsoft PowerPoint - Biomass and coal into Liquid Review Page.ppt [Compatibility Mode] Author: W2925 Created Date: 4/19/2012 11:25:13 AM

159

Combustion-Turbine Design Guidelines Based on Deposition-Corrosion Considerations, Volume 2: Coal-Derived Liquid Studies  

Science Conference Proceedings (OSTI)

Middle-distillate coal liquids test out as acceptable gas turbine fuels in terms of deposition and corrosion. Solid-liquid slurries would also be acceptable if turbine cleaning techniques were fully used.This series of tests provided design and operating guidelines that would minimize ash deposition and turbine corrosion.

1984-06-01T23:59:59.000Z

160

Air Liquide - Biogas & Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquide - Biogas & Fuel Cells Liquide - Biogas & Fuel Cells ■ Hydrogen Energy ■ Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry, health and the environment Renewable H 2 to Fuel Cell, Integrated Concept Purified Biogas 3 Air Liquide, world leader in gases for industry, health and the environment Renewable H 2 to Fuel Cell, Non-Integrated Concept Landfill WWTP digester Biogas membrane Pipeline quality methane CH4 Pipeline Hydrogen Production To Fuel Cell Vehicles Stationary Fuel Cells With H2 purification Stationary Fuel Cells Direct Conversion Directed Biomethane 4 Air Liquide, world leader in gases for industry, health and the environment Biogas Sources in the US ■ Landfill gas dominates (~4,000 Nm3/h typical)

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161

Fixed-bed gasification research using US coals. Volume 17. Gasification and liquids recovery of four US coals  

SciTech Connect

A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and government agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the seventeenth in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This report describes the gasification and pyrolysis liquids recovery test for four different coals: Illinois No. 6, SUFCO, Indianhead lignite, and Hiawatha. This test series spanned from July 15, 1985, through July 28, 1985. 4 refs., 16 figs., 19 tabs.

Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

1985-12-01T23:59:59.000Z

162

Mulled Coal: A beneficiated coal form for use as a fuel or fuel intermediate  

SciTech Connect

During the past quarter Energy International has evaluated additional mull formulations with varying reagent additives, mixing times, and particle sizes. The Environmental Review was completed and conceptual designs developed for the Mull Preparation and CWF Conversion Systems. As these technical developments move toward commercial application, the needs for coordinated efforts and integrated requirements have become increasingly apparent. Systems are vitally needed to integrate energy delivery systems from the raw resource through processing to application and end use. Problems have been encountered in the preparation of conventional coal-water fuels that mutually satisfy the requirements for storage stability, handling, preparation, atomization, combustion, and economics. Experience has been slow in evolving generic technologies or products and coal-specific requirements and specifications continue to dominate the development. Thus, prospects for commercialization remain highly specific to the coal, the processor, and the end use. Developments in advanced beneficiation of coal to meet stringent requirements for low ash and low sulfur can be anticipated to further complicate the problem areas. This is attributable to the beneficiated coal being produced in very fine particles with a high surface area, modified surface characteristics, reduced particle size distribution range, and high inherent moisture.

1991-09-01T23:59:59.000Z

163

Coal-to-liquids bill introduced in the Senate  

SciTech Connect

Of immense importance to the coal industry is the announcement, on 7 June 2006 by US Senators Barack Obama (D-IL) and Jim Bunning (R-KY) of S.3325, the 'Coal-to-Liquid Fund Promotion Act of 2006'. This legislation creates tax incentives for coal-to-liquids (CTL) technologies and construction of CTL plants. If passed, this will create the infrastructure needed to make CTL a viable energy resource throughout America. The article gives comment and background to this proposed legislation. Illinois Basin coal is well suited for CTL because of its high Btu content. If Sasol constructs a proposed plant in Illinois it would increase coal production in the state by 10 mt. 1 fig.

Buchsbaum, L.

2006-06-15T23:59:59.000Z

164

Potential for Coal-to-Liquids Conversion in the United States-Fischer-Tropsch Synthesis  

Science Conference Proceedings (OSTI)

The United States has the world's largest coal reserves and Montana the highest potential for mega-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create a major source of domestic transportation fuels from coal, and some prominent Montanans want to be at the center of that effort. We calculate that the energy efficiency of the best existing Fischer-Tropsch (FT) process applied to average coal in Montana is less than 1/2 of the corresponding efficiency of an average crude oil refining process. The resulting CO{sub 2} emissions are 20 times (2000%) higher for CTL than for conventional petroleum products. One barrel of the FT fuel requires roughly 800 kg of coal and 800 kg of water. The minimum energy cost of subsurface CO{sub 2} sequestration would be at least 40% of the FT fuel energy, essentially halving energy efficiency of the process. We argue therefore that CTL conversion is not the most valuable use for the coal, nor will it ever be, as long as it is economical to use natural gas for electric power generation. This finding results from the low efficiency inherent in FT synthesis, and is independent of the monumental FT plant construction costs, mine construction costs, acute lack of water, and the associated environmental impacts for Montana.

Patzek, Tad W. [University of Texas, Department of Petroleum and Geosystems Engineering (United States)], E-mail: patzek@mail.utexas.edu; Croft, Gregory D. [University of California, Department of Civil and Environmental Engineering (United States)

2009-09-15T23:59:59.000Z

165

Coal to Liquids | Department of Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

development, and encouraging scientific discovery and innovation by researching and developing novel technologies that convert the nation's abundant coal resources into...

166

EIA - International Energy Outlook 2008-Liquid Fuels  

Gasoline and Diesel Fuel Update (EIA)

Liquid Fuels Liquid Fuels International Energy Outlook 2008 Chapter 2 - Liquid Fuels World liquids consumption increases from 84 million barrels per day in 2005 to 99 million barrels per day in 2030 in the IEO2008 high price case. In the reference case, which reflects a price path that departs significantly from prices prevailing in the first 8 months of 2008, liquids use rises to 113 million barrels per day in 2030. Figure 26. World Liquids Production in the Reference Case, 1990-2030 (Million Barrels Oil Equivalent per Day). Need help, contact the National Energy Information Center at 202-586-8800. Figure Data Figure 27. World Production of Unconventional Liquid Fuels, 2005-2030 (Million Barrels Oil Equivalent per Day). Need help, contact the National Energy Information Center at 202-586-8800.

167

Integration of carbonate fuel cells with advanced coal gasification systems  

DOE Green Energy (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation's carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. (Energy Research Corp., Danbury, CT (United States)); Meyers, S.J. (Fluor Daniel, Inc., Irvine, CA (United States)); Hauserman, W.B. (North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center)

1992-01-01T23:59:59.000Z

168

Integration of carbonate fuel cells with advanced coal gasification systems  

DOE Green Energy (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation`s carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. [Energy Research Corp., Danbury, CT (United States); Meyers, S.J. [Fluor Daniel, Inc., Irvine, CA (United States); Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

1992-12-01T23:59:59.000Z

169

Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base  

Science Conference Proceedings (OSTI)

By applying the multi-Hubbert curve analysis to coal production in the United States, we demonstrate that anthracite production can be modeled with a single Hubbert curve that extends to the practical end of commercial production of this highest-rank coal. The production of bituminous coal from existing mines is about 80% complete and can be carried out at the current rate for the next 20 years. The production of subbituminous coal from existing mines can be carried out at the current rate for 40-45 years. Significant new investment to extend the existing mines and build new ones would have to commence in 2009 to sustain the current rate of coal production, 1 billion tons per year, in 2029. In view of the existing data, we conclude that there is no spare coal production capacity of the size required for massive coal conversion to liquid transportation fuels. Our analysis is independent of other factors that will prevent large-scale coal liquefaction projects: the inefficiency of the process and either emissions of greenhouse gases or energy cost of sequestration.

Croft, Gregory D. [University of California, Department of Civil and Environmental Engineering (United States); Patzek, Tad W. [University of Texas, Department of Petroleum and Geosystems Engineering (United States)], E-mail: patzek@mail.utexas.edu

2009-09-15T23:59:59.000Z

170

Mulled Coal: A beneficiated coal form for use as a fuel or fuel intermediate. Technical progress report No. 6, July 1, 1991--September 30, 1991  

SciTech Connect

Under the auspices of the Department of Energy and private industry, considerable progress has been made in: preparation of coal-water fuels; combustion of low-ash coal-based fuel forms; and in processes to provide deeply-cleaned coal. Since the inception of the project, we have: developed formulations for stabilizing wet filter cake into a granular free flowing material (Mulled Coal); applied the formulation to wet cake from a variety of coal sources ranging from anthracite to subbituminous coal; evaluated effects of moisture loss on mull properties; and developed design concepts for equipment for preparing the Mulled Coal and converting it into Coal Water Fuel.

1991-11-01T23:59:59.000Z

171

Combustion characterization of beneficiated coal-based fuels  

Science Conference Proceedings (OSTI)

This three-year research project at Combustion Engineering, Inc. (CE) will assess the potential economic and environmental benefits derived from coal beneficiation by various advanced cleaning processes. The objectives of this program include the development of a detailed generic engineering database, comprised of fuel combustion and ash performance data on beneficiated coal-based fuels (BCFs), which is needed to permit broad application. This technical database will provide detailed information on fundamental fuel properties influencing combustion and mineral matter behavior as well as quantitative performance data on combustion, ash deposition, ash erosion, particulate collection, and gaseous and particulate emissions. Program objectives also address the application of this technical database to predict performance impacts associated with firing BCFs in various commercial boiler designs as well as assessment of the economic implications of BCF utilization. Additionally, demonstration of this technology, with respect to large-scale fuel preparation, firing equipment operation, fuel performance, environmental impacts, and verification of prediction methodology, will be provided during field testing. Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFs, and two conventionally cleaned coals for the field test. Approximately nine BCFs will be in dry ultra fine coal (DUC) form, and six BCFs will be in coal-water fuel (CWF) form. Up to 25 additional BCFs would be characterized during optional project supplements. 9 figs., 1 tab.

Not Available

1989-12-01T23:59:59.000Z

172

Combustion characterization of beneficiated coal-based fuels  

Science Conference Proceedings (OSTI)

This three-year research project at Combustion Engineering, Inc. (CE), will assess the potential economic and environmental benefits derived from coal beneficiation by various advanced cleaning processes. The objectives of this program include the development of a detailed generic engineering data base, comprised of fuel combustion and ash performance data on beneficiated coal-based fuels (BCFs), which is needed to permit broad application. This technical data base will provide detailed information on fundamental fuel properties influencing combustion and mineral matter behavior as well as quantitative performance data on combustion, ash deposition, ash erosion, particulate collection, and gaseous and particulate emissions. Program objectives also address the application of this technical data base to predict performance impacts associated with firing BCFs in various commercial boiler designs as well as assessment of the economic implications of BCF utilization. Additionally, demonstration of this technology, with respect to large-scale fuel preparation, firing equipment operation, fuel performance, environmental impacts, and verification of prediction methodology will be provided during field testing. Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFs, and two conventionally cleaned coals for the field test. Approximately nine BCFs will be in dry ultra fine coal (DUC) form, and six BCFs will be in coal-water fuel (CWF) form. Up to 25 additional BCFs would be characterized during optional project supplements. 1 ref., 1 fig., 2 tabs.

Not Available

1989-09-01T23:59:59.000Z

173

Combustion characterization of beneficiated coal-based fuels  

Science Conference Proceedings (OSTI)

The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a three-year project on Combustion Characterization of Beneficiated Coal-Based Fuels.'' The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are being run at the cleaning facility in Homer City, Pennsylvania, to produce 20-ton batches of fuels for shipment to CE's laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CVVT) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Science, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFS, and two conventionally cleaned coals for full-scale tests. Approximately, nine BCFs will be in dry microfine coal (DMPC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

Chow, O.K.; Nsakala, N.Y.

1990-11-01T23:59:59.000Z

174

Fuel Oil Prepared by Blending Heavy Oil and Coal Tar  

Science Conference Proceedings (OSTI)

The effect of temperature, harmonic ration, surfactant and shearing to fuel oil prepared by blending heavy oil and coal tar were detailedly studied. The results show that the viscosity of the blended oil increases gradually with the increase of harmonic ... Keywords: coal tar, heavy oil, blending, surfactant

Guojie Zhang; Xiaojie Guo; Bo Tian; Yaling Sun; Yongfa Zhang

2009-10-01T23:59:59.000Z

175

Minimizing corrosion in coal liquid distillation  

DOE Patents (OSTI)

In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

1985-01-01T23:59:59.000Z

176

Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass  

SciTech Connect

This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation?s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

Huffman, Gerald

2012-12-31T23:59:59.000Z

177

Advanced coal-fueled industrial cogeneration gas turbine system  

DOE Green Energy (OSTI)

The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. This quarter, work was centered on design, fabrication, and testing of the combustor, cleanup, fuel specifications, and hot end simulation rig. 2 refs., 59 figs., 29 tabs.

LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

1990-07-01T23:59:59.000Z

178

Supersonic coal water slurry fuel atomizer  

DOE Patents (OSTI)

A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities.

Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Balsavich, John (Foxborough, MA)

1991-01-01T23:59:59.000Z

179

Combustion rates and mechanisms of pulverized coals and coal-derived fuels  

SciTech Connect

Increased use of coal, our most abundant fossil fuel resource, will be required to meet both immediate and long-term energy demands. Improvement in existing technologies of steam raising and industrial process heating through the clean, direct firing of pulverized coal will have major and immediate impact. Improvements are required because of the unacceptably high emissions from present coal combustion systems and because of the need to couple considerations of pollutant emissions and carbon conversion efficiencies. The rates and mechanisms of coal devolatilization and combustion are extremely sensitive to local details of the combustion process. Similarly, pollutants formed during the process are sensitive to the initial coal composition and local time and temperature histories of individual particles. Very little useful information is available by which the influence of combustion modifications on both the efficiency and pollutant emission characteristics can be predicted. The present understanding of the rates of coal and char combustion is summarized with the conclusion that heterogeneous chemical kinetic rates strongly influence the rates and mechanisms of coal and char combustion. If understood, adjustment and control of the rates and mechanisms by judicious adjustment of the combustion process and the initial fuel character should be possible. A proposal for a detailed theoretical and experimental study of the combustion rates of pulverized coal and coal-derived fuels is discussed.

Hardesty, D.R.

1976-06-01T23:59:59.000Z

180

Coal-fueled diesel engines for locomotive applications  

DOE Green Energy (OSTI)

GE Transportation Systems (GE/TS) completed a two and one half year study into the economic viability of a coal fueled locomotive. The coal fueled diesel engine was deemed to be one of the most attractive options. Building on the BN-NS study, a proposal was submitted to DOE to continue researching economic and technical feasibility of a coal fueled diesel engine for locomotives. The contract DE-AC21-85MC22181 was awarded to GE Corporate Research and Development (GE/CRD) for a three year program that began in March 1985. This program included an economic assessment and a technical feasibility study. The economic assessment study examined seven areas and their economic impact on the use of coal fueled diesels. These areas included impact on railroad infrastructure, expected maintenance cost, environmental considerations, impact of higher capital costs, railroad training and crew costs, beneficiated coal costs for viable economics, and future cost of money. The results of the study indicated the merits for development of a coal-water slurry (CWS) fueled diesel engine. The technical feasibility study examined the combustion of CWS through lab and bench scale experiments. The major accomplishments from this study have been the development of CWS injection hardware, the successful testing of CWS fuel in a full size, single cylinder, medium speed diesel engine, evaluation of full scale engine wear rates with metal and ceramic components, and the characterization of gaseous and particulate emissions.

Hsu, B.D.; Najewicz, D.J.; Cook, C.S.

1993-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Low contaminant formic acid fuel for direct liquid fuel cell  

Science Conference Proceedings (OSTI)

A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

Masel, Richard I. (Champaign, IL); Zhu, Yimin (Urbana, IL); Kahn, Zakia (Palatine, IL); Man, Malcolm (Vancouver, CA)

2009-11-17T23:59:59.000Z

182

Formulation and evaluation of highway transportation fuels from shale and coal oils: project identification and evaluation of optimized alternative fuels. Second annual report, March 20, 1980-March 19, 1981. [Broadcut fuel mixtures of petroleum, shale, and coal products  

DOE Green Energy (OSTI)

Project work is reported for the formulation and testing of diesel and broadcut fuels containing components from petroleum, shale oil, and coal liquids. Formulation of most of the fuels was based on refinery modeling studies in the first year of the project. Product blends were prepared with a variety of compositions for use in this project and to distribute to other, similar research programs. Engine testing was conducted in a single-cylinder CLR engine over a range of loads and speeds. Relative performance and emissions were determined in comparison with typical petroleum diesel fuel. With the eight diesel fuels tested, it was found that well refined shale oil products show only minor differences in engine performance and emissions which are related to differences in boiling range. A less refined coal distillate can be used at low concentrations with normal engine performance and increased emissions of particulates and hydrocarbons. Higher concentrations of coal distillate degrade both performance and emissions. Broadcut fuels were tested in the same engine with variable results. All fuels showed increased fuel consumption and hydrocarbon emissions. The increase was greater with higher naphtha content or lower cetane number of the blends. Particulates and nitrogen oxides were high for blends with high 90% distillation temperatures. Operation may have been improved by modifying fuel injection. Cetane and distillation specifications may be advisable for future blends. Additional multi-cylinder and durability testing is planned using diesel fuels and broadcut fuels. Nine gasolines are scheduled for testing in the next phase of the project.

Sefer, N.R.; Russell, J.A.

1981-12-01T23:59:59.000Z

183

Integrated two-stage coal liquefaction process  

DOE Patents (OSTI)

This invention relates to an improved two-stage process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal.

Bronfenbrenner, James C. (Allentown, PA); Skinner, Ronald W. (Allentown, PA); Znaimer, Samuel (Vancouver, CA)

1985-01-01T23:59:59.000Z

184

Commercialization of coal-fueled gas turbine systems  

SciTech Connect

The overall goal of this program is to develop and demonstrate the technological bases for economically attractive, commercial, coal- fired gas turbine systems. Objectives to accomplish this goal include these: identify candidate technical approaches to meet the challenges of using coal as a turbine fuel, screen the candidate technical approaches by testing their relative performance and evaluating their effects on the economic attractiveness of commercial coal-fueled systems, demonstrate the most promising technologies and associated components in proof-of-concept system tests leading up to commercialization. This paper presents background information on the project, and results on cogeneration systems, combined cycle power plants to include performance and cost.

Wilkes, C.; Wenglarz, R.A.

1992-12-01T23:59:59.000Z

185

Commercialization of coal-fueled gas turbine systems  

SciTech Connect

The overall goal of this program is to develop and demonstrate the technological bases for economically attractive, commercial, coal- fired gas turbine systems. Objectives to accomplish this goal include these: identify candidate technical approaches to meet the challenges of using coal as a turbine fuel, screen the candidate technical approaches by testing their relative performance and evaluating their effects on the economic attractiveness of commercial coal-fueled systems, demonstrate the most promising technologies and associated components in proof-of-concept system tests leading up to commercialization. This paper presents background information on the project, and results on cogeneration systems, combined cycle power plants to include performance and cost.

Wilkes, C.; Wenglarz, R.A.

1992-01-01T23:59:59.000Z

186

Advanced Fuels Synthesis  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Fuels Synthesis Advanced Fuels Synthesis Coal and Coal/Biomass to Liquids Advanced Fuels Synthesis The Advanced Fuels Synthesis Key Technology is focused on catalyst and reactor optimization for producing liquid hydrocarbon fuels from coal/biomass mixtures, supports the development and demonstration of advanced separation technologies, and sponsors research on novel technologies to convert coal/biomass to liquid fuels. Active projects within the program portfolio include the following: Fischer-Tropsch fuels synthesis Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer Tropsch Catalyst Small Scale Pilot Plant for the Gasification of Coal and Coal/Biomass Blends and Conversion of Derived Syngas to Liquid Fuels Via Fischer-Tropsch Synthesis Coal Fuels Alliance: Design and Construction of Early Lead Mini Fischer-Tropsch Refinery

187

CFBC evaluation of fuels processed from Illinois coals  

SciTech Connect

The overall objectives for this one-year project are: (1) to demonstrate that new fuels derived from Illinois high sulfur coal, namely (a) coal-sorbent pellets and (b) coal-water slurry produced from froth flotation feed can be effectively utilized in a circulating fluidized bed combustor, (2) to compare the carbon conversion efficiencies, SO{sub 2} and NO{sub x} emission levels and Ca/S ratios needed to meet EPA regulations from the above fuels with those measured under similar operating conditions with a standard IBCSP coal, and (3) to analyze ash and spent limestone residues with a view to proposing waste disposal strategies for the combustion residues resulting from these new fuel forms.

Rajan, S.

1991-01-01T23:59:59.000Z

188

Advanced coal-fueled industrial cogeneration gas turbine system  

SciTech Connect

Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

1991-07-01T23:59:59.000Z

189

Refining and end use study of coal liquids. Quarterly report, April--June 1996  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M.W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the U.S. Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. This 47-month study, with an approved budget of $4.4 million dollars, is being performed under DOE Contract Number DE-AC22-93PC91029. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards.

NONE

1997-12-31T23:59:59.000Z

190

High conversion of coal to transportation fuels for the future with low HC gas production. Progress report, October 1, 1995--December 31, 1995  

DOE Green Energy (OSTI)

Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence a small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous-flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal.

Wiser, W.H.; Oblad, A.G.

1996-01-01T23:59:59.000Z

191

High Conversion of Coal to Transportation Fuels for the Future With Low HC Gas Production  

DOE Green Energy (OSTI)

An announced objective of the Department of Energy in funding this work, and other current research in coal liquefaction, is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel (Task A). A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline- burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number (Task B).

Alex G. Oblad; Wendell H. Wiser

1996-07-01T23:59:59.000Z

192

EIA - International Energy Outlook 2009-Liquid Fuels Graphic...  

Gasoline and Diesel Fuel Update (EIA)

26. World Liquids Supply in three Cases, 2006 and 2030 Figure 27. World Production of Unconventional Liquid Fuels, 2006-2030 Figure 28. World Liquids Consumption by Sector,...

193

Refinery Integration of By-Products from Coal-Derived Jet Fuels  

Science Conference Proceedings (OSTI)

This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2007-03-17T23:59:59.000Z

194

Supersonic coal water slurry fuel atomizer  

DOE Patents (OSTI)

A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities. 3 figs.

Becker, F.E.; Smolensky, L.S.; Balsavich, J.

1989-11-01T23:59:59.000Z

195

Refining and end use study of coal liquids. Quarterly report, January--March 1996  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M. W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the US Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. The major efforts conducted during the first quarter of 1996 were in the areas of: DL2 light distillate hydrotreating; and DL2 heave distillate catalytic cracking.

NONE

1996-09-01T23:59:59.000Z

196

Refining and end use of coal liquids. Quarterly report, April--June 1994  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M.W. Kellogg Co. as subcontractors, initialed a study on November 1, 1993, for the U.S. Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. This 47-month study, with an approved budget of $4.4 million dollars, is being performed under DOE Contract Number DE-AC22-93PC91029. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An intregral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed.

Not Available

1995-01-01T23:59:59.000Z

197

Refining and end use study of coal liquids. Quarterly report, October 1994--December 1994  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M.W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the U.S. Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. This 47-month study, with an approved budget of $4.4 million dollars, is being performed under DOE Contract Number DE-AC22-93PC91029. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. To enhance management of the study, the work has been divided into two parts, the Basic Program and Option 1.

NONE

1995-05-01T23:59:59.000Z

198

Refining and end use study of coal liquids. Quarterly report, July - September 1996  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M. W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the U.S. Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. This 47-month study, with an approved budget of $4.4 million dollars, is being performed under DOE Contract Number DE-AC22-93PC91029. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. The major efforts conducted during the third quarter of 1996 were in the areas of hydrotreating production runs and FCC production run. 3 figs., 8 tabs.

NONE

1996-12-31T23:59:59.000Z

199

Coal-based Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

However there are still some unresolved problems with performance durability of SOFC when operating on coal syngas, which inherently has some undesirable...

200

Proceedings, twenty-fourth annual international Pittsburgh coal conference  

SciTech Connect

Topics covered include: gasification technologies; coal production and preparation; combustion technologies; environmental control technologies; synthesis of liquid fuels, chemicals, materials and other non-fuel uses of coal; hydrogen from coal; advanced synthesis gas cleanup; coal chemistry, geosciences and resources; Fischer-Tropsch technology; coal and sustainability; global climate change; gasification (including underground gasification); materials, instrumentation and controls; and coal utilisation byproducts.

NONE

2007-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Liquid-fossil-fuel technology. Quarterly technical progress report, July-September 1982  

SciTech Connect

Progress reports for the quarter ending September 1982 are presented for the following major tasks: liquid fossil fuel cycle; extraction (resource assessment, enhanced recovery); liquid processing (characterization of petroleum, coal liquids, thermodynamics, process technology); utilization; project integration and technology transfer. Feature articles for this quarter are: new laboratory enhances BETC capability in mass spectrometry; and BETC tests on diesel particulate extracts indicate potential health risks. (ATT)

Linville, B. (ed.)

1983-01-01T23:59:59.000Z

202

Alternative Liquid Fuels (ALF) | Open Energy Information  

Open Energy Info (EERE)

(ALF) Jump to: navigation, search Name Alternative Liquid Fuels (ALF) Address P.O. Box 76 Place McArthur, Ohio Zip 45651 Sector Biofuels, Renewable Energy, Services Phone number...

203

Coal-fueled high-speed diesel engine development  

DOE Green Energy (OSTI)

The objectives of this program are to study combustion feasibility by running Series 149 engine tests at high speeds with a fuel injection and combustion system designed for coal-water-slurry (CWS). The following criteria will be used to judge feasibility: (1) engine operation for sustained periods over the load range at speeds from 600 to 1900 rpm. The 149 engine for mine-haul trucks has a rated speed of 1900 rpm; (2) reasonable fuel economy and coal burnout rate; (3) reasonable cost of the engine design concept and CWS fuel compared to future oil prices.

Not Available

1991-11-01T23:59:59.000Z

204

NETL: Coal & Coal Biomass to Liquids - Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Documents, Papers, Presentations Documents, Papers, Presentations Documents Papers Presentations DOCUMENTS Fuels Industry Newsletter December 2013 November 2013 October 2013 September 2013 August 2013 July 2013 June 2013 May 2013 April 2013 March 2013 February 2013 January 2013 Fuels Industry Newsletter 2012 Technology Readiness Assessment-Analysis of Active Research Portfolio [PDF-7.27MB] (Dec 19, 2012) Consistent with ongoing efforts to supply policy makers with clear information in a form more amenable for them to gauge the maturity of carbon capture, utilization, and storage (CCUS) technologies, the National Energy Technology Laboratory (NETL) has undertaken an assessment of its "key technologies." The Department of Energy-Fossil Energy Technology Readiness Assessment Guide (DOE-FE Guide1) served as the basis for a

205

NETL: Coal & Coal Biomass to Liquids - Reference Shelf  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuels Papers Fuels Papers Separation/Production Storage Separation/Production Title Author(s) Abstract Evaluation and Modeling of a High-Temperature, High-Pressure, Hydrogen Separation Membrane for Enhanced Hydrogen Production from the Water-Gas Shift Reaction [PDF-939KB] R. M. Enick, et al. (NETL) Abstract Presented at: ACS Meeting, 1999 The Permeability of Hydrogen in Bulk Palladium at Elevated Temperatures and Pressures [PDF-57KB] B.D. Morreale, et al. (NETL) Abstract Presented in: Journal of Membrane Science, January 2003 Evaluation of Tantalum-Based Material for Hydrogen Separation at Elevated Temperatures and Pressures [PDF-846KB] Kurt S. Rothenberger, et al. (NETL) Abstract Presented in: Journal of Membrane Science, June 2003 Exploring the Kinetics of the Water-Gas Shift Reaction on Inconel 600: A Proof-of-Concept Test [PDF-337KB] F. Bustamante, et al. (NETL) Abstract

206

Coal-fueled diesels for modular power generation  

DOE Green Energy (OSTI)

Interest in coal-fueled heat engines revived after the sharp increase in the prices of natural gas and petroleum in the 1970`s. Based on the success of micronized coal water slurry combustion tests in an engine in the 1980`s, Morgantown Energy Technology Center (METC) of the US Department of Energy. initiated several programs for the development of advanced coal-fueled diesel and gas turbine engines for use in cogeneration, small utilities, industrial applications and transportation. Cooper-Bessemer and Arthur D. Little have been developing technology since 1985, under the sponsor of METC, to enable coal water slurry (CWS) to be utilized in large bore, medium-speed diesel engines. Modular power generation applications in the 10--100 MW size (each plant typically using from two to eight engines) are the target applications for the late 1990`s and beyond when, according to the US DOE and other projections, oil and natural gas prices are expected to escalate much more rapidly compared to the price of coal. As part of this program over 7.50 hours of prototype engine operation has been achieved on coal water slurry (CWS), including over 100 hours operation of a six-cylinder full scale engine with Integrated Emissions Control System in 1993. In this paper, the authors described the project cost of the CWS fuel used, the heat rate of the engine operating on CWS, the projected maintenance cost for various engine components, and the demonstrated low emissions characteristics of the coal diesel system.

Wilson, R.P. [Little (Arthur D.), Inc., Cambridge, MA (United States); Rao, A.K. [Cooper-Bessemer Reciprocating, Grove City, PA (United States); Smith, W.C. [Department of Energy, Morgantown, WV (United States). Morgantown Energy Technology Center

1993-11-01T23:59:59.000Z

207

Coal transportation risks for fuel switching decisions  

SciTech Connect

Coal switching costs are generally expected to be the single largest cost factor associated with switching coals to low-sulfur sources. This report analyzes the principal issues and risks involved in moving Powder River Basin coal to eastern destinations and in moving increased amounts of Central Appalachian low-sulfur coal along the Ohio River. The railroad infrastructure for Powder River Basin coal is essentially optimized for current levels of traffic, yet estimated shipments will expand by 100 million tons over the next ten years. A critical issue is the magnitude and timing of investments in the railroad system required to maintain quality of service. Costs for rail and barge transport are comparable at present, yet they have different abilities to handle increased traffic. Negotiated rates will not be uniform and will change with the dynamics of investments and the clarification of utility compliance plans. Coal traffic patterns on inland waterways will change in order to handle barge movements for both Powder River Basin and Central Appalachian low-sulfur coals. Docks serving Central Appalachian coal fields have ample capacity, but originations will take place increasingly far from the rivers. Potential bottlenecks at specific locks and dams along the Ohio River have been identified. With the barge industry coming out of a slump, future barge rates will depend critically on the Corps of Engineers' schedule to upgrade key facilities. 30 figs., 14 tabs.

Toth, S. (Fieldston Co., Inc., Washington, DC (United States))

1991-09-01T23:59:59.000Z

208

Process for particulate removal from coal liquids  

DOE Patents (OSTI)

Suspended solid particulates are removed from liquefied coal products by first subjecting such products to hydroclone action for removal in the underflow of the larger size particulates, and then subjecting the overflow from said hydroclone action, comprising the residual finer particulates, to an electrostatic field in an electrofilter wherein such finer particulates are deposited in the bed of beads of dielectric material on said filter. The beads are periodically cleaned by backwashing to remove the accumulated solids.

Rappe, Gerald C. (Macungie, PA)

1983-01-01T23:59:59.000Z

209

Liquid Fuels Market Model (LFMM) Unveiling LFMM  

Gasoline and Diesel Fuel Update (EIA)

Implementation of the Renewable Fuel Implementation of the Renewable Fuel Standard (RFS) in the Liquid Fuels Market Module (LFMM) of NEMS Michael H. Cole, PhD, PE michael.cole@eia.gov August 1, 2012 | Washington, DC LFMM / NEMS overview 2 M. Cole, EIA Advanced Biofuels Workshop August 1, 2012 | Washington, DC * LFMM is a mathematical representation of the U.S. liquid fuels market (motor gasoline, diesel, biofuels, etc.). EIA analysts use LFMM to project motor fuel prices and production approaches through 2040. * LFMM is a cost-minimization linear program (LP). For a given set of fuel demands, LFMM will find the least-cost means of satisfying those demands, subject to various constraints (such as the RFS). * LFMM is part of the National Energy Modeling System (NEMS), which is a computer model of the U.S. energy economy. EIA uses

210

INVESTIGATION INTO THE EFFECTS OF TRACE COAL SYN GAS SPECIES ON THE PERFORMANCE OF SOLID OXIDE FUEL CELL ANODES.  

E-Print Network (OSTI)

??Coal is the United States most widely used fossil fuel for the production of electric power. Coals availability and cost dictates that it will be (more)

Trembly, Jason P.

2007-01-01T23:59:59.000Z

211

EVALUATION OF BIOMSS AND COAL SLURRIES AS FUEL-LEAN REBURN FUELS  

DOE Green Energy (OSTI)

Breen Energy Solutions (BES) and Western Research Institute (WRI) tested biomass and coal slurries and other carbonaceous substances such as fuel oil/water emulsions as NO{sub x} reburn fuel in the combustion test facility (CTF). The overall goal of the project was to determine the NO{sub x} reduction potential of various biomass and coal reburn fuels, and to identify the optimum conditions for NO{sub x} control. Specific objectives were to inject biomass, biosolids, coal, biomass/coal, and biosolids/coal slurries into the upper furnace of CTF and determine the resulting NO{sub x} reductions and CO emissions, to identify optimum injection rates and injection locations for these reburn fuels, and to install a reaction zone stabilizer device in CTF and determine its effectiveness in reducing CO and further reducing NO{sub x}. Combustion tests achieved 40% to 60% NO{sub x} reductions with 10% to 20% reburn fuel heat input. The project has demonstrated the technical feasibility of in-situ gasification of slurries including pulverized coal and 75% pulverized coal/25% biosolids by weight, and the ability to utilize the gasification products as NO{sub x} reburn fuel. This work also demonstrated that pulverized coal/water slurries can be successfully gasified and used as reburn fuels, and there is no need for use of micronized coal. Very good burnout of the pulverized coal slurry was demonstrated in this work. Similarly, the project has demonstrated the technical feasibility of in-situ gasification of oil/water emulsion and the ability to utilize the associated gasification products as NO{sub x} reburn fuel.

Vijay K. Sethi

2006-11-06T23:59:59.000Z

212

Liquid Transportation Fuels from Coal and Biomass  

NLE Websites -- All DOE Office Websites (Extended Search)

Academies * National Academy of Sciences through the following endowed funds * Thomas Lincoln Casey Fund * Arthur L. Day Fund * W.K. Kellogg Foundation Fund * George and...

213

Annual book of ASTM Standards 2008. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke  

SciTech Connect

The first part covers standards for gaseous fuels. The second part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrogrpahic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

NONE

2008-09-15T23:59:59.000Z

214

EA-1870: Utah Coal and Biomass Fueled Pilot Plant, Kanab, Kane...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0: Utah Coal and Biomass Fueled Pilot Plant, Kanab, Kane County, Utah EA-1870: Utah Coal and Biomass Fueled Pilot Plant, Kanab, Kane County, Utah Summary This EA evaluates the...

215

Refining and end use study of coal liquids. Second quarter 1995 technical progress report, April--June 1995  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M.W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the U.S. Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. This 47-month study, with an approved budget of $4.4 million dollars, is being performed under DOE Contract Number DE-AC22-93PC91029. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products.

NONE

1995-12-01T23:59:59.000Z

216

Advanced turbine design for coal-fueled engines  

DOE Green Energy (OSTI)

The objective of this task is to perform a technical assessment of turbine blading for advanced second generation PFBC conditions, identify specific problems/issues, and recommend an approach for solving any problems identified. A literature search was conducted, problems associated with hot corrosion defined and limited experiments performed. Sulfidation corrosion occurs in industrial, marine and aircraft gas turbine engines and is due to the presence of condensed alkali (sodium) sulfates. The principle source of the alkali in industrial, marine and aircraft gas turbine engines is sea salt crystals. The principle source of the sulfur is not the liquid fuels, but the same ocean born crystals. Moreover deposition of the corrosive salt occurs primarily by a non-equilibrium process. Sodium will be present in the cleaned combusted gases that enter the PFBC turbine. Although equilibrium condensation is not favored, deposition via impaction is probable. Marine gas turbines operate in sodium chloride rich environments without experiencing the accelerated attack noted in coal fired boilers where condensed chlorides contact metallic surfaces. The sulfates of calcium and magnesium are the products of the reactions used to control sulfur. Based upon industrial gas turbine experience and laboratory tests, calcium and magnesium sulfates are, at temperatures up to 1500[degrees]F (815[degrees]C), relatively innocuous salts. In this study it is found that at 1650[degrees]F (900[degrees]C) and above, calcium sulfate becomes an aggressive corrodent.

Bornstein, N.S.

1992-07-17T23:59:59.000Z

217

High-pressure coal fuel processor development. Final report  

DOE Green Energy (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. [Caterpillar, Inc., Peoria, IL (United States)

1992-12-01T23:59:59.000Z

218

FUEL LEAN BIOMASS REBURNING IN COAL-FIRED BOILERS  

DOE Green Energy (OSTI)

This final technical report describes research conducted between July 1, 2000, and June 30, 2002, for the project entitled ''Fuel Lean Biomass Reburning in Coal-Fired Boilers,'' DOE Award No. DE-FG26-00NT40811. Fuel Lean Biomass Reburning is a method of staging fuel within a coal-fired utility boiler to convert nitrogen oxides (NOx) to nitrogen by creating locally fuel-rich eddies, which favor the reduction of NOx, within an overall fuel lean boiler. These eddies are created by injecting a supplemental fuel source, designated as the reburn fuel, downstream of the primary combustion zone. Chopped biomass was the reburn fuel for this project. Four parameters were explored in this research: the initial oxygen concentration ranged between 1%-6%, the amount of biomass used as the reburn fuel ranged between from 0%-23% of the total % energy input, the types of biomass used were low nitrogen switchgrass and high nitrogen alfalfa, and the types of carrier gases used to inject the biomass (nitrogen and steam). Temperature profiles and final flue gas species concentrations are presented in this report. An economic evaluation of a potential full-scale installation of a Fuel-Lean Biomass Reburn system using biomass-water slurry was also performed.

Jeffrey J. Sweterlitsch; Robert C. Brown

2002-07-01T23:59:59.000Z

219

FUEL LEAN BIOMASS REBURNING IN COAL-FIRED BOILERS  

SciTech Connect

This final technical report describes research conducted between July 1, 2000, and June 30, 2002, for the project entitled ''Fuel Lean Biomass Reburning in Coal-Fired Boilers,'' DOE Award No. DE-FG26-00NT40811. Fuel Lean Biomass Reburning is a method of staging fuel within a coal-fired utility boiler to convert nitrogen oxides (NOx) to nitrogen by creating locally fuel-rich eddies, which favor the reduction of NOx, within an overall fuel lean boiler. These eddies are created by injecting a supplemental fuel source, designated as the reburn fuel, downstream of the primary combustion zone. Chopped biomass was the reburn fuel for this project. Four parameters were explored in this research: the initial oxygen concentration ranged between 1%-6%, the amount of biomass used as the reburn fuel ranged between from 0%-23% of the total % energy input, the types of biomass used were low nitrogen switchgrass and high nitrogen alfalfa, and the types of carrier gases used to inject the biomass (nitrogen and steam). Temperature profiles and final flue gas species concentrations are presented in this report. An economic evaluation of a potential full-scale installation of a Fuel-Lean Biomass Reburn system using biomass-water slurry was also performed.

Jeffrey J. Sweterlitsch; Robert C. Brown

2002-07-01T23:59:59.000Z

220

Comparison of coal/solid recovered fuel (SRF) with coal/refuse derived fuel (RDF) in a fluidised bed reactor  

Science Conference Proceedings (OSTI)

An experimental study was undertaken to compare the differences between municipal solid waste (MSW) derived solid recovered fuel (SRF) (complying with CEN standards) and refuse derived fuel (RDF). Both fuels were co-combusted with coal in a 50 kW fluidised bed combustor and the metal emissions were compared. Synthetic SRF was prepared in the laboratory by grinding major constituents of MSW such as paper, plastic, textile and wood. RDF was obtained from a local mechanical treatment plant. Heavy metal emissions in flue gas and ash samples from the (coal + 10% SRF) fuel mixture were found to be within the acceptable range and were generally lower than that obtained for coal + 10% RDF fuel mixture. The relative distribution of heavy metals in ash components and the flue gas stream shows the presence of a large fraction (up to 98%) of most of the metals in the ash (except Hg and As). Thermo-gravimetric (TG) analysis of SRF constituents was performed to understand the behaviour of fuel mixtures in the absence and presence of air. The results obtained from the experimental study will enhance the confidence of fuel users towards using MSW-derived SRF as an alternative fuel.

Wagland, S.T.; Kilgallon, P.; Coveney, R. [School of Applied Sciences, Sustainable Systems Department, Cranfield University, Cranfield, Bedfordshire MK43 0AL (United Kingdom); Garg, A. [Centre for Environmental Science and Engineering (CESE), Indian Institute of Technology Bombay, Powai, Mumbai 400076 (India); Smith, R.; Longhurst, P.J.; Pollard, S.J.T. [School of Applied Sciences, Sustainable Systems Department, Cranfield University, Cranfield, Bedfordshire MK43 0AL (United Kingdom); Simms, N., E-mail: n.j.simms@cranfield.ac.uk [School of Applied Sciences, Sustainable Systems Department, Cranfield University, Cranfield, Bedfordshire MK43 0AL (United Kingdom)

2011-06-15T23:59:59.000Z

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221

Method of producing a colloidal fuel from coal and a heavy petroleum fraction  

DOE Patents (OSTI)

A method is provided for combining coal as a colloidal suspension within a heavy petroleum fraction. The coal is broken to a medium particle size and is formed into a slurry with a heavy petroleum fraction such as a decanted oil having a boiling point of about 300.degree.-550.degree. C. The slurry is heated to a temperature of 400.degree.-500.degree. C. for a limited time of only about 1-5 minutes before cooling to a temperature of less than 300.degree. C. During this limited contact time at elevated temperature the slurry can be contacted with hydrogen gas to promote conversion. The liquid phase containing dispersed coal solids is filtered from the residual solids and recovered for use as a fuel or feed stock for other processes. The residual solids containing some carbonaceous material are further processed to provide hydrogen gas and heat for use as required in this process.

Longanbach, James R. (Columbus, OH)

1983-08-09T23:59:59.000Z

222

Demonstration of a Carbonate Fuel Cell on Coal Derived Gas  

E-Print Network (OSTI)

Several studies indicate that carbonate fuel cell systems have the potential to offer efficient, cost competitive, and environmentally preferred power plants operating on natural gas or coal derived gas (syn-gas). To date, however, no fuel cell system has run on actual syn-gas. Consequently, the Electric Power Research Institute (EPRI) has sponsored a 20 kW carbonate fuel cell pilot plant that will begin operating in March at Destec Energys coal gasification plant in Plaquemine, Louisiana. The primary purpose of the test is to determine the effect of syn-gas contaminants on the performance and life of the carbonate fuel cell. This paper will describe the project objectives, design aspects of the pilot facility, and the status of the project.

Rastler, D. M.; Keeler, C. G.; Chi, C. V.

1993-03-01T23:59:59.000Z

223

Co-firing of coal and biomass fuel blends M. Sami, K. Annamalai*, M. Wooldridge1  

E-Print Network (OSTI)

Co-firing of coal and biomass fuel blends M. Sami, K. Annamalai*, M. Wooldridge1 Department; accepted 6 June 2000 Abstract This paper reviews literature on co-firing of coal with biomass fuels. Here of coal and biomass fuels are presented. Different classes of co-firing methods are identified

Wooldridge, Margaret S.

224

Potential for Coal-to-Liquids Conversion in the United States--FischerTropsch Synthesis  

E-Print Network (OSTI)

Potential for Coal-to-Liquids Conversion in the United States--Fischer­Tropsch Synthesis Tad W The United States has the world?s largest coal reserves and Montana the highest potential for mega-mine development. Consequently, a large-scale effort to convert coal to liquids (CTL) has been proposed to create

Patzek, Tadeusz W.

225

POWER GENERATION FROM LIQUID METAL NUCLEAR FUEL  

DOE Patents (OSTI)

A nuclear reactor system is described wherein the reactor is the type using a liquid metal fuel, such as a dispersion of fissile material in bismuth. The reactor is designed ln the form of a closed loop having a core sectlon and heat exchanger sections. The liquid fuel is clrculated through the loop undergoing flssion in the core section to produce heat energy and transferrlng this heat energy to secondary fluids in the heat exchanger sections. The fission in the core may be produced by a separate neutron source or by a selfsustained chain reaction of the liquid fuel present in the core section. Additional auxiliary heat exchangers are used in the system to convert water into steam which drives a turbine.

Dwyer, O.E.

1958-12-23T23:59:59.000Z

226

Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base  

E-Print Network (OSTI)

Potential for Coal-to-Liquids Conversion in the U.S.-Resource Base Gregory D. Croft1 and Tad W the multi-Hubbert curve analysis to coal production in the United States, we demonstrate that anthracite production of this highest-rank coal. The pro- duction of bituminous coal from existing mines is about 80

Patzek, Tadeusz W.

227

Method for providing improved solid fuels from agglomerated subbituminous coal  

SciTech Connect

A method is provided for separating agglomerated subbituminous coal and the heavy bridging liquid used to form the agglomerates. The separation is performed by contacting the agglomerates with inert gas or steam at a temperature in the range of 250.degree. to 350.degree. C. at substantially atmospheric pressure.

Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Pawlak, Wanda (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

1989-01-01T23:59:59.000Z

228

Rough cost estimates of solar thermal/coal or biomass-derived fuels. [Hybrid approach: solar thermal plus either coal or biomass  

SciTech Connect

The production of a synthetic fuel from a solar thermal resource could provide a means of replacing critical liquid and gaseous fossil fuels. The solar thermal resource is large and economics favors a southwestern site. A synthetic fuel would provide a desirable product and a means of transporting solar thermal energy to large load centers outside the southwest. This paper presents cost data for one method of producing synthetic methane. A hybrid approach was chosen, a combination of solar thermal and either coal or biomass. The magnitude of the solar thermal resource is estimated as well as projected cost. Cost projections for coal and biomass are accumulated. The cost of synthetic gas from a hybrid and a conventional fuel source are compared.

Copeland, R. J.

1979-01-01T23:59:59.000Z

229

COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal  

SciTech Connect

Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

Smith, V.E.; Merriam, N.W.

1994-10-01T23:59:59.000Z

230

Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development  

SciTech Connect

Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

Stephenson, M.

1994-03-01T23:59:59.000Z

231

Combined coal gasifier and fuel cell system and method  

DOE Patents (OSTI)

This report describes a process whereby a molten carbonate fuel cell is combined with a catalytic coal or coal char gasifier for providing the reactant gases comprising hydrogen, carbon monoxide and carbon dioxide used in the operation of the fuel cell. These reactant gases are stripped of sulfur compounds and particulate material and are then separated in discrete gas streams for conveyance to appropriate electrodes in the fuel cell. The gasifier is arranged to receive the reaction products generated at the anode of the fuel cell by the electricity-producing electrochemical reaction therein. These reaction products from the anode are formed primarily of high temperature steam and carbon dioxide to provide the steam, the atmosphere and the heat necessary to endothermically pyrolyze the coal or char in the presence of a catalyst. The reaction products generated at the cathode are substantially formed of carbon dioxide which is used to heat air being admixed with the carbon dioxide stream from the gasifier for providing the oxygen required for the reaction in the fuel cell and for driving an expansion device for energy recovery. A portion of this carbon dioxide from the cathode may be recycled into the fuel cell with the air-carbon dioxide mixture. 1 fig.

Gmeindl, F.D.; Geisbrecht, R.A.

1989-06-26T23:59:59.000Z

232

Evaluation of alternative uses of coal and coal-derived fuels: industry, government, and public viewpoints  

DOE Green Energy (OSTI)

This report covers a study by Battelle's Columbus Laboratories to identify viewpoints representative of various interest groups on alternative uses of coal and coal-derived fuels. The study was conducted for the ERDA Fossil Energy Department to provide background inputs to the R and D planning process. A series of nine structured workshops was conducted with selected representatives of the various interest groups. The individual workshops included representation of industrial and utility companies, state and federal governments, and public interest groups. Viewpoints were recorded on (1) the relative importance of five specific evaluation criteria, (2) the evaluation of seven fuel categories against the criteria, (3) a forecast of future fuel utilization by categories, and (4) suggested R and D emphasis for the fuel categories. This report, Volume I, is a summary and appraisal of workshop results. Volume II contains appendices with more detailed records from the workshops.

Locklin, D.W.; Malone, D.W.; Molnar, D.E.; Sander, L.K.; Morrison, D.L.

1975-11-17T23:59:59.000Z

233

Refinery Integration of By-Products from Coal-Derived Jet Fuels  

SciTech Connect

This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking. Investigation of coal extraction as a method to produce RCO continues; the reactor modifications to filter the products hot and to do multi-stage extraction improve extraction yields from {approx}50 % to {approx}70%. Carbon characterization of co-cokes for use as various carbon artifacts continues.

Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2006-09-17T23:59:59.000Z

234

HTGR-INTEGRATED COAL TO LIQUIDS PRODUCTION ANALYSIS  

DOE Green Energy (OSTI)

As part of the DOEs Idaho National Laboratory (INL) nuclear energy development mission, the INL is leading a program to develop and design a high temperature gas-cooled reactor (HTGR), which has been selected as the base design for the Next Generation Nuclear Plant. Because an HTGR operates at a higher temperature, it can provide higher temperature process heat, more closely matched to chemical process temperatures, than a conventional light water reactor. Integrating HTGRs into conventional industrial processes would increase U.S. energy security and potentially reduce greenhouse gas emissions (GHG), particularly CO2. This paper focuses on the integration of HTGRs into a coal to liquids (CTL) process, for the production of synthetic diesel fuel, naphtha, and liquefied petroleum gas (LPG). The plant models for the CTL processes were developed using Aspen Plus. The models were constructed with plant production capacity set at 50,000 barrels per day of liquid products. Analysis of the conventional CTL case indicated a potential need for hydrogen supplementation from high temperature steam electrolysis (HTSE), with heat and power supplied by the HTGR. By supplementing the process with an external hydrogen source, the need to shift the syngas using conventional water-gas shift reactors was eliminated. HTGR electrical power generation efficiency was set at 40%, a reactor size of 600 MWth was specified, and it was assumed that heat in the form of hot helium could be delivered at a maximum temperature of 700C to the processes. Results from the Aspen Plus model were used to perform a preliminary economic analysis and a life cycle emissions assessment. The following conclusions were drawn when evaluating the nuclear assisted CTL process against the conventional process: 11 HTGRs (600 MWth each) are required to support production of a 50,000 barrel per day CTL facility. When compared to conventional CTL production, nuclear integration decreases coal consumption by 66% using electrolysis and nuclear power as the hydrogen source. In addition, nuclear integration decreases CO2 emissions by 84% if sequestration is assumed and 96% without sequestration, when compared to conventional CTL. The preliminary economic assessment indicates that the incorporation of 11 HTGRs and the associated HTSEs impacts the expected return on investment, when compared to conventional CTL with or without sequestration. However, in a carbon constrained scenario, where CO2 emissions are taxed and sequestration is not an option, a reasonable CO2 tax would equate the economics of the nuclear assisted CTL case with the conventional CTL case. The economic results are preliminary, as they do not include economies of scale for multiple HTGRs and are based on an uncertain reactor cost estimate. Refinement of the HTGR cost estimate is currently underway. To reduce well to wheel (WTW) GHG emissions below baseline (U.S. crude mix) or imported crude derived diesel, integration of an HTGR is necessary. WTW GHG emissions decrease 8% below baseline crude with nuclear assisted CTL. Even with CO2 sequestration, conventional CTL WTW GHG emissions are 24% higher than baseline crude emissions. Current efforts are underway to investigate the incorporation of nuclear integrated steam methane reforming for the production of hydrogen, in place of HTSE. This will likely reduce the number of HTGRs required for the process.

Anastasia M Gandrik; Rick A Wood

2010-10-01T23:59:59.000Z

235

Fuel Cell Technologies Office: Bio-Derived Liquids to Hydrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

on October 24, 2006 Review of Working Group Charter & DOE RD&D Targets for Hydrogen Production from Renewable Liquid Fuels, Arlene Anderson, DOE Fuel Cell Technologies...

236

Innovative coal-fueled diesel engine injector  

DOE Green Energy (OSTI)

The purpose of this research investigation was to develop an electronic coal water slurry injection system in conjunction with the Thermal Ignition Combustion System (TICS) concept to achieve autoignition of CWS at various engine load and speed conditions without external ignition sources. The combination of the new injection system and the TICS is designed to reduce injector nozzle spray orifice wear by lowering the peak injection pressure requirements. (VC)

Badgley, P.; Doup, D.

1991-05-01T23:59:59.000Z

237

Wear mechanism and wear prevention in coal-fueled diesel engines  

DOE Green Energy (OSTI)

Coal fueled diesel engines present unique wear problems in the piston ring/cylinder liner area because of their tendency to contaminate the lube-oil with high concentrations of highly abrasive particles. This program involved a series of bench-scale wear tests and engine tests designed to investigate various aspects of the ring/liner wear problem and to make specific recommendations to engine manufacturers as to how to alleviate these problems. The program was organized into tasks, designed to accomplish the following objectives: (1) define the predominant wear mechanisms causing accelerated wear in the ring/liner area; (2) investigate the effectiveness of traditional approaches to wear prevention to prevent wear in coal-fueled engines; (3) further refine information on the most promising approaches to wear prevention; (4) present detailed information and recommendations to engine manufacturers on the most promising approach to wear prevention; (5) present a final report covering the entire program; (6)complete engine tests with a coal-derived liquid fuel, and investigate the effects of the fuel on engine wear and emissions.

Schwalb, J.A.; Ryan, T.W.

1991-10-01T23:59:59.000Z

238

Wear mechanism and wear prevention in coal-fueled diesel engines. Final report  

DOE Green Energy (OSTI)

Coal fueled diesel engines present unique wear problems in the piston ring/cylinder liner area because of their tendency to contaminate the lube-oil with high concentrations of highly abrasive particles. This program involved a series of bench-scale wear tests and engine tests designed to investigate various aspects of the ring/liner wear problem and to make specific recommendations to engine manufacturers as to how to alleviate these problems. The program was organized into tasks, designed to accomplish the following objectives: (1) define the predominant wear mechanisms causing accelerated wear in the ring/liner area; (2) investigate the effectiveness of traditional approaches to wear prevention to prevent wear in coal-fueled engines; (3) further refine information on the most promising approaches to wear prevention; (4) present detailed information and recommendations to engine manufacturers on the most promising approach to wear prevention; (5) present a final report covering the entire program; (6)complete engine tests with a coal-derived liquid fuel, and investigate the effects of the fuel on engine wear and emissions.

Schwalb, J.A.; Ryan, T.W.

1991-10-01T23:59:59.000Z

239

NETL: Coal & Coal Biomass to Liquids - Hydrogen and Clean Fuels...  

NLE Websites -- All DOE Office Websites (Extended Search)

force). The illustration at right is an artists conception of a hydrogen atom; quantum physics shows that the electron does not appear in one place, but behaves as a...

240

NETL: Coal & Coal Biomass to Liquids - Hydrogen and Clean Fuels...  

NLE Websites -- All DOE Office Websites (Extended Search)

by reacting steam with natural gas at high temperatures, a process called steam methane reforming (SMR). Pressurized hydrogen storage tank by Quantum Hydrogen has a high...

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Liquid Fuels from Lignins: Annual Report  

DOE Green Energy (OSTI)

This task was initiated to assess the conversion of lignins into liquid fuels, primarily of lignins relevant to biomass-to-ethanol conversion processes. The task was composed of a literature review of this area and an experimental part to obtain pertinent data on the conversion of lignins germane to biomass-to-ethanol conversion processes.

Chum, H. L.; Johnson, D. K.

1986-01-01T23:59:59.000Z

242

Conversion of cellulosic wastes to liquid fuels  

DOE Green Energy (OSTI)

The current status and future plans for a project to convert waste cellulosic (biomass) materials to quality liquid hydrocarbon fuels is described. The basic approach is indirect liquefaction, i.e., thermal gasification followed by catalytic liquefaction. The indirect approach results in separation of the oxygen in the biomass feedstock, i.e., oxygenated compounds do not appear in the liquid hydrocarbon fuel product. The process is capable of accepting a wide variety of feedstocks. Potential products include medium quality gas, normal propanol, diesel fuel and/or high octane gasoline. A fluidized bed pyrolysis system is used for gasification. The pyrolyzer can be fluidized with recycle pyrolysis gas, steam or recycle liquefaction system off gas or some combination thereof. Tars are removed in a wet scrubber. Unseparated pyrolysis gases are utilized as feed to a modified Fischer-Tropsch reactor. The liquid condensate from the reactor consists of a normal propanol-water phase and a paraffinic hydrocarbon phase. The reactor can be operated to optimize for either product. The following tasks were specified in the statement of work for the contract period: (1) feedstock studies; (2) gasification system optimization; (3) waste stream characterization; and (4) liquid fuels synthesis. In addition, several equipment improvements were implemented.

Kuester, J.L.

1980-09-01T23:59:59.000Z

243

Combustion characterization of beneficiated coal-based fuels  

Science Conference Proceedings (OSTI)

The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, conbustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Sciences, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFs, and two conventionally cleaned coals for the full-scale tests. Approximately nine BCFs will be in dry ultra-fine coal (DUC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

Chow, O.K.; Nsakala, N.Y.

1990-08-01T23:59:59.000Z

244

Development of an extraction process for removal of heteroatoms from coal liquids. Final report  

DOE Green Energy (OSTI)

The main goal of this contract was to develop an extraction process for upgrading coal liquids; and in doing so, to reduce the hydrogen requirement in downstream upgrading processes and to yield valuable byproducts. This goal was to be achieved by developing a novel carbon dioxide extraction process for heteroatom removal from coal-derived naphtha, diesel, and jet fuel. The research plan called for the optimization of three critical process variables using a statistically-designed experimental matrix. The commercial potential of the new process was to be evaluated by demonstrating quantitatively the effectiveness of heteroatom removal from three different feedstocks and by conducting a comparative economic analysis of alternate heteroatom removal technologies. Accomplishments are described for the following tasks: food procurement and analysis process variable screening studies; and process assessment.

Not Available

1994-04-01T23:59:59.000Z

245

C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN  

DOE Green Energy (OSTI)

The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

Gerald P. Huffman

2004-09-30T23:59:59.000Z

246

Advanced coal-fueled industrial cogeneration gas turbine system  

DOE Green Energy (OSTI)

This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

1992-06-01T23:59:59.000Z

247

Rail transportation of coal-water slurry fuels  

Science Conference Proceedings (OSTI)

In view of the anticipated near-term appearance of commercial coal-water slurry (CWS) fuels, least-cost modes of their transportation should be considered now. Unlike dilute pipeline transport slurries (typically 50 percent solids) a CWS fuel is a stable, highly-loaded (typically 70 percent or more solids) with vastly different rheological properties. The high solids loading and stabilization against settling produce effective viscosities one or more orders of magnitude greater than those of dilute slurries. Pipeline transportation of such fuels for more than a few miles thus becomes economically unattractive. In the future, further physical refinement or slight dilution of CWS fuels may permit long-range transmission by slurry pipeline once they become available. In the meantime, distribution of these fuels to serve widely dispersed industrial users will be accomplished by barge or rail. In the latter case the high flow-friction characteristics will preclude use of the unit ''Tank Train'' system designed for loading and unloading via a single connection at high rates of flow. This limitation does not rule out assembly of unit trains of individually-loaded tank cars if desired. The optimum location of CWS fuel plants relative to mine-mouth coal preparation plants and/or pipeline terminals will require modeling of multi-mode transportation networks in order to determine the least-cost combination for serving the needs of industrial as well as utility CWS users.

Green, L.

1982-12-01T23:59:59.000Z

248

Preliminary investigation of the effects of coal-water slurry fuels on the combustion in GE coal fueled diesel engine (Task 1. 1. 2. 2. 1, Fuels)  

DOE Green Energy (OSTI)

In prior work with the coal fired diesel research engine, a necessity to determine the sensitivity of the engine to a wider range of fuels was resolved and included in the R and D Test Plan submitted on 2/9/89. In general, the economic viability and universal acceptance of the commercial engine will be a factor of its ability to tolerate the widest range of source fuels with minimal fuel beneficiation. As detailed in the R and D Test Plan, a preliminary investigation on the effects of coal-water slurry (CWS) fuels on the combustion in a GE single cylinder test engine was conducted. The following conclusions are obtained from this investigation. All the test CWS fuels were successfully burned in the GE engine combustion system. They include: 3 to 15 microns mean particle size; 0.7 to 2.8% ash level; KY Blue Gem and PA Mariana bituminous coal, WY Kemmer and Spring Creek Sub-Bituminous coal; coal beneficiated with physical and chemical processes; two kinds of additives for OTISCA CWS; and burnout is not effected by ash or particle size within the test range. For each kind of CWS fuel, the detail design parameters of the fuel injection system has to be compatible. With sufficiently high fuel injection pressure, the 3 micron mean particle size OTISCA fuel burns faster than the 5 micron ones. For OTISCA fuel, the burn rate using Ammonium Lignosulfonate as additive is faster than using Ammonium Condensed Naphthalene Sulfonate. Appendices contain data on heat release, fuel characterization reports from two laboratories, general engine test data, and particulate size distribution. 3 refs.

Not Available

1990-06-01T23:59:59.000Z

249

EVALUATION OF DENSIFIED REFUSE DERIVED FUELS FOR USE IN PULVERIZED COAL-FIRED  

E-Print Network (OSTI)

EVALUATION OF DENSIFIED REFUSE DERIVED FUELS FOR USE IN PULVERIZED COAL-FIRED STEAM GENERATORS with coal. This paper discusses these successful tests and the feasibility of preparing a d-RDF which can be processed with coal using existing, unmodified coal handling equipment and fired in conventional pulverized

Columbia University

250

Mulled coal---A beneficiated coal form for use as a fuel or fuel intermediate. Final technical progress report No. 3, October 1, 1990--December 31, 1990  

SciTech Connect

The storage, transport and handling of beneficiated coals in the form of a modified wet cake (``mulled coal``) to yield a coal water fuel having acceptable properties for atomization and combustion on industrial, commercial and/or residential scales, have been investigated. The Mulled Coal project is divided into a series of tasks designed to produce formulations and system designs suitable to convert fine coal ``wet cakes`` into a material that can be stored, handled, and transported to a site where it can be utilized as a fuel in existing and developing combustion devices. (VC)

Not Available

1991-05-01T23:59:59.000Z

251

Conditions of utilization of coal mining and processing sludges as slurry fuel  

Science Conference Proceedings (OSTI)

The results of this study have shown that coal sludge can be used as slurry fuel (like coal-water fuel (CWF)) providing that its ash content does not exceed 30% and the amount in the fuel is at least 55%. The conventional CWF preparation technologies are inapplicable to the fabrication of water-sludge fuel; therefore, special technologies with allowance for the ash content, the particle size, and the water content of coal sludge are demanded.

E.G. Gorlov; A.I. Seregin; G.S. Khodakov [Institute for Fossil Fuels, Moscow (Russian Federation)

2007-12-15T23:59:59.000Z

252

NETL: News Release - Coal-Based Fuel Cells: A Giant Leap for...  

NLE Websites -- All DOE Office Websites (Extended Search)

August 11, 2005 Coal-Based Fuel Cells: A Giant Leap for Fuel Cell Technology New Program to Develop Multi-Megawatt Fuel Cell Systems WASHINGTON, DC - The Department of Energy today...

253

Co-production of electricity and alternate fuels from coal. Final report, August 1995  

DOE Green Energy (OSTI)

The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

NONE

1995-12-31T23:59:59.000Z

254

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS  

DOE Green Energy (OSTI)

The following are proposed activities for quarter 3 (12/15/00-3/14/01): (1) Conduct TGA and fuel characterization studies - Task 1; (2) Continue to perform re-burn experiments. - Task 2; (3) Design fixed bed combustor. - Task 3; and (4) Modify the PCGC2 code to include moisture evaporation model - Task 4. The following were achieved During Quarter 3 (12/15/0-3/14/01): (1) Conducted TGA and Fuel Characterization studies (Appendix I). A comparison of -fuel properties, TGA traces etc is given in Appendix I. Litter has 3 and 6 times more N compared to coal on mass and heat basis. The P of litter is almost 2 % (Task 1). Both litter biomass (LB) and feedlot biomass (FB) have been pulverized. The size distributions are similar for both litter and FB in that 75 % pass through 150 {micro}m sieve while for coal 75 % pass through 60 {micro}m sieve. Rosin Rammler curve parameters are given. The TGA characteristics of FB and LB are similar and pyrolysis starts at 100 C below that of coal; (2) Reburn experiments with litter and with FB have been performed (Appendix II) -Task 2. Litter is almost twice effective (almost 70--90 % reduction) compared to coal in reducing the NOx possibly due to presence of N in the form of NH{sub 3}; (3) Designed fixed bed gasifier/combustor (Appendix III) - Task 3; and (4) Modified PCGC2 to include moisture evaporation model in coal and biomass particles. (Appendix IV) - Task 4.

Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

2001-05-10T23:59:59.000Z

255

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS  

DOE Green Energy (OSTI)

Proposed activities for quarter 8 (3/15/2001--6/14/2002), Boiler Burner Simulation and Experiments: (1) Continue the parametric study of cofiring of pulverized coal and LB in the boiler burner, and determining the combustor performance and emissions of NO, CO, CO{sub 2}, PO{sub 2} and P{sub 4}O{sub 10}, etc. The air-fuel ratio, swirl number of the secondary air stream and moisture effects will also be investigated (Task 4). Gasification: (Task 3) (2) Measuring the temperature profile for chicken litter biomass under different operating conditions. (3) Product gas species for different operating conditions for different fuels. (4) Determining the bed ash composition for different fuels. (5) Determining the gasification efficiency for different operating conditions. Activities Achieved during quarter 8 (3/15/2001--6/14/2002), Boiler Burner Simulation and Experiments: (1) The evaporation and phosphorus combustion models have been incorporated into the PCGC-2 code. Mr. Wei has successfully defended his Ph.D. proposal on Coal: LB modeling studies (Task 4, Appendix C). (2) Reburn experiments with both low and high phosphorus feedlot biomass has been performed (Task 2, Appendix A). (3) Parametric studies on the effect of air-fuel ratio, swirl number of the secondary air stream and moisture effects have been investigated (Task 2, Appendix A). (4) Three abstracts have been submitted to the American Society of Agricultural Engineers Annual International meeting at Chicago in July 2002. Three part paper dealing with fuel properties, cofiring, large scale testing are still under review in the Journal of Fuel. Gasification: (Task 3, Appendix B) (5) Items No. 2, and 3 are 95% complete, with four more experiments yet to be performed with coal and chicken litter biomass blends. (6) Item No. 4, and 5 shall be performed after completion of all the experiments.

Unknown

2002-07-01T23:59:59.000Z

256

Integrating catalytic coal gasifiers with solid oxide fuel cells  

Science Conference Proceedings (OSTI)

A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

2010-01-01T23:59:59.000Z

257

Coal Integrated Gasification Fuel Cell System Study  

DOE Green Energy (OSTI)

The pre-baseline configuration for an Integrated Gasification Fuel Cell (IGFC) system has been developed. This case uses current gasification, clean-up, gas turbine, and bottoming cycle technologies together with projected large planar Solid Oxide Fuel Cell (SOFC) technology. This pre-baseline case will be used as a basis for identifying the critical factors impacting system performance and the major technical challenges in implementing such systems. Top-level system requirements were used as the criteria to evaluate and down select alternative sub-systems. The top choice subsystems were subsequently integrated to form the pre-baseline case. The down-selected pre-baseline case includes a British Gas Lurgi (BGL) gasification and cleanup sub-system integrated with a GE Power Systems 6FA+e gas turbine and the Hybrid Power Generation Systems planar Solid Oxide Fuel Cell (SOFC) sub-system. The overall efficiency of this system is estimated to be 43.0%. The system efficiency of the pre-baseline system provides a benchmark level for further optimization efforts in this program.

Gregory Wotzak; Chellappa Balan; Faress Rahman; Nguyen Minh

2003-08-01T23:59:59.000Z

258

Combustion characterization of beneficiated coal-based fuels  

SciTech Connect

This three-year research project at Combustion Engineering, Inc. (CE), will assess the potential economic and environmental benefits derived from coal beneficiation by various advanced cleaning processes. The objectives of this program include the development of a detailed generic engineering data base, comprised of fuel combustion and ash performance data on beneficiated coal-based fuels (BCFs), which is needed to permit broad application. This technical data base will provide detailed information on fundamental fuel properties influencing combustion and mineral matter behavior as well as quantitative performance data on combustion, ash deposition, ash erosion, particulate collection, and gaseous and particulate emissions. Program objectives also address the application of this technical data base to predict performance impacts associated with firing BCFs in various commercial boiler designs as well as assessment of the economic implications of BCF utilization. Additionally, demonstration of this technology, with respect to large-scale fuel preparation, firing equipment operation, fuel performance, environmental impacts, and verification of prediction methodology, will be provided during field testing.

Not Available

1990-03-01T23:59:59.000Z

259

Proceedings, twenty-five annual international Pittsburgh coal conference  

SciTech Connect

The conference theme was 'coal - energy, environment and sustainable development'. The topics covered energy and environmental issues, and technologies related to coal and its byproducts. These included: gasification, hydrogen from coal, combustion technologies, coal production and preparation, synthesis of liquid fuels, gas turbines and fuel cells for synthesis gas and hydrogen applications, coal chemistry and geosciences, global climate change, underground coal gasification, environmental control technologies, and coal utilization byproducts.

NONE

2008-07-01T23:59:59.000Z

260

Preparation and combustion of coal-water fuel from the Sin Pun coal deposit, southern Thailand  

SciTech Connect

In response to an inquiry by the Department of Mineral Resources in Thailand, the Energy & Environmental Research Center (EERC) prepared a program to assess the responsiveness of Sin Pun lignite to the temperature and pressure conditions of hot-water drying. The results indicate that drying made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 27 wt% for the raw coal to about 15 wt% for the hot-water-dried (HWD) coals. The energy density for a pumpable coal-water fuel (CWF) indicates an increase from 4500 to 6100 Btu/lb by hot-water drying. Approximately 650 lb of HWD Sin Pun CWF were fired in the EERC`s combustion test facility. The fuel burned extremely well, with no feed problems noted during the course of the test. Fouling and slagging deposits each indicated a very low rate of ash deposition, with only a dusty layer formed on the cooled metal surfaces. The combustor was operated at between 20% and 25% excess air, resulting in a flue gas SO{sub 2} concentration averaging approximately 6500 parts per million.

1997-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Method of producing a colloidal fuel from coal and a heavy petroleum fraction. [partial liquefaction of coal in slurry, filtration and gasification of residue  

DOE Patents (OSTI)

A method is provided for combining coal as a colloidal suspension within a heavy petroleum fraction. The coal is broken to a medium particle size and is formed into a slurry with a heavy petroleum fraction such as a decanted oil having a boiling point of about 300 to 550/sup 0/C. The slurry is heated to a temperature of 400 to 500/sup 0/C for a limited time of only about 1 to 5 minutes before cooling to a temperature of less than 300/sup 0/C. During this limited contact time at elevated temperature the slurry can be contacted with hydrogen gas to promote conversion. The liquid phase containing dispersed coal solids is filtered from the residual solids and recovered for use as a fuel or feed stock for other processes. The residual solids containing some carbonaceous material are further processed to provide hydrogen gas and heat for use as required in this process.

Longanbach, J.R.

1981-11-13T23:59:59.000Z

262

Reimagining liquid transportation fuels : sunshine to petrol.  

DOE Green Energy (OSTI)

Two of the most daunting problems facing humankind in the twenty-first century are energy security and climate change. This report summarizes work accomplished towards addressing these problems through the execution of a Grand Challenge LDRD project (FY09-11). The vision of Sunshine to Petrol is captured in one deceptively simple chemical equation: Solar Energy + xCO{sub 2} + (x+1)H{sub 2}O {yields} C{sub x}H{sub 2x+2}(liquid fuel) + (1.5x+.5)O{sub 2} Practical implementation of this equation may seem far-fetched, since it effectively describes the use of solar energy to reverse combustion. However, it is also representative of the photosynthetic processes responsible for much of life on earth and, as such, summarizes the biomass approach to fuels production. It is our contention that an alternative approach, one that is not limited by efficiency of photosynthesis and more directly leads to a liquid fuel, is desirable. The development of a process that efficiently, cost effectively, and sustainably reenergizes thermodynamically spent feedstocks to create reactive fuel intermediates would be an unparalleled achievement and is the key challenge that must be surmounted to solve the intertwined problems of accelerating energy demand and climate change. We proposed that the direct thermochemical conversion of CO{sub 2} and H{sub 2}O to CO and H{sub 2}, which are the universal building blocks for synthetic fuels, serve as the basis for this revolutionary process. To realize this concept, we addressed complex chemical, materials science, and engineering problems associated with thermochemical heat engines and the crucial metal-oxide working-materials deployed therein. By project's end, we had demonstrated solar-driven conversion of CO{sub 2} to CO, a key energetic synthetic fuel intermediate, at 1.7% efficiency.

Johnson, Terry Alan (Sandia National Laboratories, Livermore, CA); Hogan, Roy E., Jr.; McDaniel, Anthony H. (Sandia National Laboratories, Livermore, CA); Siegel, Nathan Phillip; Dedrick, Daniel E. (Sandia National Laboratories, Livermore, CA); Stechel, Ellen Beth; Diver, Richard B., Jr.; Miller, James Edward; Allendorf, Mark D. (Sandia National Laboratories, Livermore, CA); Ambrosini, Andrea; Coker, Eric Nicholas; Staiger, Chad Lynn; Chen, Ken Shuang; Ermanoski, Ivan; Kellog, Gary L.

2012-01-01T23:59:59.000Z

263

Mulled coal - a beneficiated coal form for use as a fuel or fuel intermediate. Technical progress report No. 11, October 1, 1992--December 31, 1992  

SciTech Connect

Under the auspices of the DOE and private industry, considerable progress has been made in: preparation of coal-water fuels; combustion of low-ash coal-based fuel forms; processes to provide deeply-cleaned coal. Developments in advanced beneficiation of coal to meet stringent requirements for low ash and low sulfur can be anticipated to further complicate the problem areas associated with this product. This is attributable to the beneficiated coal being procured in very fine particles with high surface areas, modified surface characteristics, reduced particle size distribution range, and high inherent moisture. Experience in the storage, handling, and transport of highly beneficiated coal has been limited. This is understandable, as quantities of such product are only now becoming available in meaningful quantities. Since the inception of the project, the authors have: developed formulations to stabilize wet filter cake into a granular free flowing material (Mulled Coal); applied the formulation to wet cake from a variety of coal sources ranging from anthracite to subbituminous coal; evaluated effects of moisture loss on mull properties; developed design concepts for equipment for preparing the Mulled Coal and converting it into Coal Water Fuel; obtained storage and handling system design data for the granular coal; completed the 74-day aging study on various mull formulations to determine the effects of time and exposure on mull properties; demonstrated the continuous production of mulled coal from wet filter cake; performed atomization studies on Mulled Coal and CWF prepared from Mulled Coal; developed a standardized set of empirical tests to evaluate handling characteristics of various mull formulations; completed integrated, continuous mulling process circuit design. During this report period they have completed coal aging studies; plant design is being reviewed; and final report preparation has begun.

1993-01-01T23:59:59.000Z

264

Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil  

Science Conference Proceedings (OSTI)

In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

2009-05-15T23:59:59.000Z

265

NEW SOLID FUELS FROM COAL AND BIOMASS WASTE  

DOE Green Energy (OSTI)

Under DOE sponsorship, McDermott Technology, Inc. (MTI), Babcock and Wilcox Company (B and W), and Minergy Corporation developed and evaluated a sludge derived fuel (SDF) made from sewage sludge. Our approach is to dry and agglomerate the sludge, combine it with a fluxing agent, if necessary, and co-fire the resulting fuel with coal in a cyclone boiler to recover the energy and to vitrify mineral matter into a non-leachable product. This product can then be used in the construction industry. A literature search showed that there is significant variability of the sludge fuel properties from a given wastewater plant (seasonal and/or day-to-day changes) or from different wastewater plants. A large sewage sludge sample (30 tons) from a municipal wastewater treatment facility was collected, dried, pelletized and successfully co-fired with coal in a cyclone-equipped pilot. Several sludge particle size distributions were tested. Finer sludge particle size distributions, similar to the standard B and W size distribution for sub-bituminous coal, showed the best combustion and slagging performance. Up to 74.6% and 78.9% sludge was successfully co-fired with pulverized coal and with natural gas, respectively. An economic evaluation on a 25-MW power plant showed the viability of co-firing the optimum SDF in a power generation application. The return on equity was 22 to 31%, adequate to attract investors and allow a full-scale project to proceed. Additional market research and engineering will be required to verify the economic assumptions. Areas to focus on are: plant detail design and detail capital cost estimates, market research into possible project locations, sludge availability at the proposed project locations, market research into electric energy sales and renewable energy sales opportunities at the proposed project location. As a result of this program, wastes that are currently not being used and considered an environmental problem will be processed into a renewable fuel. These fuels will be converted to energy while reducing CO{sub 2} emissions from power generating boilers and mitigating global warming concerns. This report describes the sludge analysis, solid fuel preparation and production, combustion performance, environmental emissions and required equipment.

Hamid Farzan

2001-09-24T23:59:59.000Z

266

Advanced coal-fueled gas turbine systems  

Science Conference Proceedings (OSTI)

Activity towards completing Advanced Turbine Systems (ATS) Phase I work was begun again in December. Effort to complete the Phase I work was temporarily suspended upon receipt of the ATS Phase II RFP the last week in August. The Westinghouse ATS team's efforts were directed at preparing the ATS Phase II proposal which was submitted November 18. It is planned to finish Phase I work and submit the topical report by the end of February 1993. The objective of the four slogging combustor tests conducted during this reporting period (i.e., tests SL3-1 through SL3-4) were to perform sulfur capture experiments using limestoneand iron oxide based sorbents and to collect exhaust vapor phase and solids bound alkali measurements using the Westinghouse and Ames Laboratory alkali probes/monitors. The most significant, if not outstanding result revealed by these tests is that the Ames alkali monitor indicates that the vapor phase sodium is approximately 23--30 ppbw and the vapor phase potassium is approximately 5--20 ppbw. For reference, alkalilevels of 20 ppbw are acceptable in Westinghouse gas turbines fueled with crude oil.

Not Available

1993-02-03T23:59:59.000Z

267

Refining and end use study of coal liquids. Sixth quarterly technical progress report, December 19, 1994--March 26, 1995  

Science Conference Proceedings (OSTI)

Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M.W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the U.S. Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. This 47-month study, with an approved budget of $4.4 million dollars, is being performed under DOE Contract Number DE-AC22-93PC91029. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed.

NONE

1995-08-01T23:59:59.000Z

268

Improved anode catalysts for coal gas-fueled phosphoric acid fuel cells  

Science Conference Proceedings (OSTI)

The feasibility of adapting phosphoric acid fuel cells to operate on coal gas fuels containing significant levels of contaminants such as CO, H{sub 2}S and COS has been investigated. The overall goal was the development of low-cost, carbon-supported anode fuel cell catalysts that can efficiently operate with a fossil fuel-derived hydrogen gas feed contaminated with carbon monoxide and other impurities. This development would reduce the cost of gas cleanup necessary in a coal gas-fueled PAFC power plant, thereby reducing the final power cost of the electricity produced. The problem to date has been that the contaminant gases typically adsorb on catalytic sites and reduce the activity for hydrogen oxidation. An advanced approach investigated was to modify these alloy catalyst systems to operate efficiently on coal gas containing higher levels of contaminants by increasing the alloy catalyst impurity tolerance and ability to extract energy from the CO present through (1) generation of additional hydrogen by promoting the CO/H{sub 2} water shift reaction or (2) direct oxidation of CO to CO{sub 2} with the same result. For operation on anode gases containing high levels of CO, a Pt-Ti-Zn and Pt-Ti-Ni anode catalyst showed better performance over a Pt baseline or G87A-17-2 catalyst. The ultimate aim of this effort was to allow PAFC-based power plants to operate on coal gas fuels containing increased contaminant concentrations, thereby decreasing the need for and cost of rigorous coal gas cleanup procedures. 4 refs., 15 figs., 10 tabs.

Kackley, N.D.; McCatty, S.A.; Kosek, J.A.

1990-07-01T23:59:59.000Z

269

Dark spreads measure returns over fuel costs of coal-fired ...  

U.S. Energy Information Administration (EIA)

The dark spread is a common metric used to estimate returns over fuel costs of coal-fired electric generators. A dark spread is the difference between ...

270

Potential Application of Coal-Derived Fuel Gases for the Glass...  

NLE Websites -- All DOE Office Websites (Extended Search)

Mitretek Technical Report Potential Application of Coal-Derived Fuel Gases for the Glass Industry: A Scoping Analysis December 2004 David Gray Salvatore Salerno Glen Tomlinson...

271

A High Temperature Planar Solid Oxide Fuel Cell Operating on Phosphine Contaminated Coal Syngas.  

E-Print Network (OSTI)

??Solid oxide fuel cells that operate on phosphine contaminated coal syngas are subject to performance degradation due to alterations of the anode microstructure. Theoretical investigations (more)

De Silva, Kandaudage Channa R.

2011-01-01T23:59:59.000Z

272

Refinery Integration of By-Products from Coal-Derived Jet Fuels  

Science Conference Proceedings (OSTI)

This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

2004-09-17T23:59:59.000Z

273

REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS  

Science Conference Proceedings (OSTI)

This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

2004-04-23T23:59:59.000Z

274

REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS  

SciTech Connect

This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2005-05-18T23:59:59.000Z

275

Liquid chromatographic analysis of coal surface properties. Quarterly progress report, October--December 1992  

SciTech Connect

Experiments on equilibrium adsorption loadings of various additives on 60 - 200 mesh Illinois 16 coal (DECS-2; Randolph county) were performed. The additives include n-propanol, n-butanol, 2-butanol, phenol, 2-naphthol, o-cresol and cyclohexanol. Equilibrium adsorption loadings of normal alcohols on 60 - 200 mesh Illinois No. 6 coal increase with increased numbers of carbons in their molecular formulas. Normal alcohols are more adsorbed on the coal than their branched alcohols. Adsorption loadings of single-ring compound phenol on the coal is higher than that of cyclohexanol. Adsorption loadings of double-ring compound 2-naphthol on the coal is much higher than that of single-ring compound phenol. The main objectives of this proposed research are to refine further the inverse liquid chromatography technique for the study of surface properties of raw coals, treated coals and coal minerals in water, to evaluate relatively surface properties of raw coals, treated coals and coal minerals by inverse liquid chromatography, and to evaluate floatability of various treated coals in conjunction with surface properties of coals.

Kwon, K.C.; Rigby, R.

1992-12-31T23:59:59.000Z

276

Advanced Coal-Fueled Gas Turbine Program. Final report  

SciTech Connect

The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

1989-02-01T23:59:59.000Z

277

Assessment of the technical and economic feasibility of converting wood residues to liquid and gaseous fuel products using state-of-the-art and advanced coal conversion technology. Third quarterly report, December 1, 1978--February 28, 1979  

DOE Green Energy (OSTI)

The approach to be used in evaluating coal gasification technologies for gasification of wood is outlined. The coal gasification technologies to be evaluated and their status are tabulated. The parameters critical to the development of wood gasification (technical risk, economics, institutional factors, and environmental impacts) are briefly discussed. (JSR)

Not Available

1979-05-01T23:59:59.000Z

278

Alternative Liquid Fuels Simulation Model (AltSim).  

DOE Green Energy (OSTI)

The Alternative Liquid Fuels Simulation Model (AltSim) is a high-level dynamic simulation model which calculates and compares the production and end use costs, greenhouse gas emissions, and energy balances of several alternative liquid transportation fuels. These fuels include: corn ethanol, cellulosic ethanol from various feedstocks (switchgrass, corn stover, forest residue, and farmed trees), biodiesel, and diesels derived from natural gas (gas to liquid, or GTL), coal (coal to liquid, or CTL), and coal with biomass (CBTL). AltSim allows for comprehensive sensitivity analyses on capital costs, operation and maintenance costs, renewable and fossil fuel feedstock costs, feedstock conversion ratio, financial assumptions, tax credits, CO{sub 2} taxes, and plant capacity factor. This paper summarizes the structure and methodology of AltSim, presents results, and provides a detailed sensitivity analysis. The Energy Independence and Security Act (EISA) of 2007 sets a goal for the increased use of biofuels in the U.S., ultimately reaching 36 billion gallons by 2022. AltSim's base case assumes EPA projected feedstock costs in 2022 (EPA, 2009). For the base case assumptions, AltSim estimates per gallon production costs for the five ethanol feedstocks (corn, switchgrass, corn stover, forest residue, and farmed trees) of $1.86, $2.32, $2.45, $1.52, and $1.91, respectively. The projected production cost of biodiesel is $1.81/gallon. The estimates for CTL without biomass range from $1.36 to $2.22. With biomass, the estimated costs increase, ranging from $2.19 per gallon for the CTL option with 8% biomass to $2.79 per gallon for the CTL option with 30% biomass and carbon capture and sequestration. AltSim compares the greenhouse gas emissions (GHG) associated with both the production and consumption of the various fuels. EISA allows fuels emitting 20% less greenhouse gases (GHG) than conventional gasoline and diesels to qualify as renewable fuels. This allows several of the CBTL options to be included under the EISA mandate. The estimated GHG emissions associated with the production of gasoline and diesel are 19.80 and 18.40 kg of CO{sub 2} equivalent per MMBtu (kgCO{sub 2}e/MMBtu), respectively (NETL, 2008). The estimated emissions are significantly higher for several alternatives: ethanol from corn (70.6), GTL (51.9), and CTL without biomass or sequestration (123-161). Projected emissions for several other alternatives are lower; integrating biomass and sequestration in the CTL processes can even result in negative net emissions. For example, CTL with 30% biomass and 91.5% sequestration has estimated production emissions of -38 kgCO{sub 2}e/MMBtu. AltSim also estimates the projected well-to-wheel, or lifecycle, emissions from consuming each of the various fuels. Vehicles fueled with conventional diesel or gasoline and driven 12,500 miles per year emit 5.72-5.93 tons of CO{sub 2} equivalents per year (tCO{sub 2}e/yr). Those emissions are significantly higher for vehicles fueled with 100% ethanol from corn (8.03 tCO{sub 2}e/yr) or diesel from CTL without sequestration (10.86 to 12.85 tCO{sub 2}/yr). Emissions could be significantly lower for vehicles fueled with diesel from CBTL with various shares of biomass. For example, for CTL with 30% biomass and carbon sequestration, emissions would be 2.21 tCO{sub 2}e per year, or just 39% of the emissions for a vehicle fueled with conventional diesel. While the results presented above provide very specific estimates for each option, AltSim's true potential is as a tool for educating policy makers and for exploring 'what if?' type questions. For example, AltSim allows one to consider the affect of various levels of carbon taxes on the production cost estimates, as well as increased costs to the end user on an annual basis. Other sections of AltSim allow the user to understand the implications of various polices in terms of costs to the government or land use requirements. AltSim's structure allows the end user to explore each of these alternatives and understand the sensitivities implications a

Williams, Ryan; Baker, Arnold Barry; Drennen, Thomas E.

2009-12-01T23:59:59.000Z

279

C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN  

DOE Green Energy (OSTI)

Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research.

Gerald P. Huffman

2003-03-31T23:59:59.000Z

280

Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report  

DOE Green Energy (OSTI)

The manufacture of liquid energy fuels from syngas (a mixture of H[sub 2] and CO, usually containing CO[sub 2]) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

Mills, G. (Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology)

1993-05-01T23:59:59.000Z

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281

Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report  

Science Conference Proceedings (OSTI)

The manufacture of liquid energy fuels from syngas (a mixture of H{sub 2} and CO, usually containing CO{sub 2}) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

Mills, G. [Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology

1993-05-01T23:59:59.000Z

282

The Iron Age & Coal-based Coke: A Neglected Case of Fossil-fuel Dependence  

E-Print Network (OSTI)

The Iron Age & Coal-based Coke: A Neglected Case of Fossil-fuel Dependence by Vaclav Smil September share of their primary energies from renewable sources. Steel & Coal-Derived Coke Here is another important: steel's fundamental dependence on coal-derived coke with no practical substitutes on any rational

Smil, Vaclav

283

Fuel Cell Technologies Office: Bio-Derived Liquids to Hydrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

Meeting - November 2007 to someone by E-mail Share Fuel Cell Technologies Office: Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting - November 2007 on...

284

Selective Removal of Thiophene from Liquid Fuels over Nickel ...  

Science Conference Proceedings (OSTI)

Presentation Title, Selective Removal of Thiophene from Liquid Fuels over Nickel -Based Nanocrystalline Zinc Oxide. Author(s), Mohammad Rafiqul Islam, Jewel...

285

Liquid Fuels from CO2, Water, and Solar Energy  

Science Conference Proceedings (OSTI)

Symposium, Energy Technologies and Carbon Dioxide Management. Presentation Title, Liquid Fuels from CO2, Water, and Solar Energy. Author(s), Aldo...

286

Catalytic conversion of cellulose to liquid hydrocarbon fuels ...  

Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

287

NETL: Coal/Biomass Feed and Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal/Biomass Feed & Gasification Coal/Biomass Feed & Gasification Coal and Coal/Biomass to Liquids Coal/Biomass Feed and Gasification The Coal/Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal and/or coal-biomass mixtures. Activities support research for handling and processing of coal/biomass mixtures, ensuring those mixtures are compatible with feed delivery systems, identifying potential impacts on downstream components, catalyst and reactor optimization, and characterizing the range of products and product quality. Active projects within the program portfolio include the following: Coal-biomass fuel preparation Development of Biomass-Infused Coal Briquettes for Co-Gasification Coal-biomass gasification modeling

288

State-of-the-art processes for manufacturing synthetic liquid fuels via the Fischer-Tropsch synthesis  

Science Conference Proceedings (OSTI)

Processes for manufacturing synthetic liquid fuels on the basis of the Fischer-Tropsch synthesis from alternative feedstock (natural gas, coal, biomass of various origins, etc.) are surveyed. State-of-the-art technology, companies that offer such processes, and the quality of products in comparison with their oil analogs, as well as economic features of the processes, are considered.

A.Y. Krylova; E.A. Kozyukov [NGK ITERA, Moscow (Russian Federation)

2007-12-15T23:59:59.000Z

289

Estimating Externalities of Coal Fuel Cycles, Report 3  

SciTech Connect

The agreement between the US DOE and the EC established the specific objectives of the study: (a) to develop a methodological framework that uses existing data and models to quantify the external costs and benefits of energy; (b) to demonstrate the application of the framework to estimate the externalities of the coal, biomass, oil, natural gas, hydro, nuclear, photovoltaic, and wind fuel cycles (by agreement with the EC, the US addressed the first six of these); and (c) to identify major gaps in the availability of information to quantify impacts, damages, benefits, and externalities of fuel cycles; and to suggest priorities for future research. The main consideration in defining these objectives was a desire to have more information about externalities, and a better method for estimating them.

Barnthouse, L.W.; Cada, G.F.; Cheng, M.-D.; Easterly, C.E.; Kroodsma, R.L.; Lee, R.; Shriner, D.S.; Tolbert, V.R.; Turner, R.S.

1994-09-01T23:59:59.000Z

290

The economical production of alcohol fuels from coal-derived synthesis gas: Case studies, design, and economics  

DOE Green Energy (OSTI)

This project is a combination of process simulation and catalyst development aimed at identifying the most economical method for converting coal to syngas to linear higher alcohols to be used as oxygenated fuel additives. There are two tasks. The goal of Task 1 is to discover, study, and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas, and to explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. The goal of Task 2 is to simulate, by computer, energy efficient and economically efficient processes for converting coal to energy (fuel alcohols and/or power). The primary focus is to convert syngas to fuel alcohols. This report contains results from Task 2. The first step for Task 2 was to develop computer simulations of alternative coal to syngas to linear higher alcohol processes, to evaluate and compare the economics and energy efficiency of these alternative processes, and to make a preliminary determination as to the most attractive process configuration. A benefit of this approach is that simulations will be debugged and available for use when Task 1 results are available. Seven cases were developed using different gasifier technologies, different methods for altering the H{sub 2}/CO ratio of the syngas to the desired 1.1/1, and with the higher alcohol fuel additives as primary products and as by-products of a power generation facility. Texaco, Shell, and Lurgi gasifier designs were used to test gasifying coal. Steam reforming of natural gas, sour gas shift conversion, or pressure swing adsorption were used to alter the H{sub 2}/CO ratio of the syngas. In addition, a case using only natural gas was prepared to compare coal and natural gas as a source of syngas.

NONE

1995-10-01T23:59:59.000Z

291

Refinery Integration of By-Products from Coal-Derived Jet Fuels  

Science Conference Proceedings (OSTI)

This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2005-11-17T23:59:59.000Z

292

Distillation of liquid fuels by thermogravimetry  

Science Conference Proceedings (OSTI)

In this paper, design and operation of a custom-built thermogravimetric apparatus for the distillation of liquid fuels are reported. Using a sensitive balance with scale of 0.001 g and ASTM distillation glassware, several petroleum and petroleum-derived samples have been analyzed by the thermogravimetric distillation method. When the ASTM distillation glassware is replaced by a micro-scale unit, sample size could be reduced from 100 g to 5-10 g. A computer program has been developed to transfer the data into a distillation plot, e.g. Weight Percent Distilled vs. Boiling Point. It also generates a report on the characteristic distillation parameters, such as, IBP (Initial Boiling Point), FBP (Final Boiling Point), and boiling point at 50 wt% distilled. Comparison of the boiling point distributions determined by TG (thermogravimetry) with those by SimDis GC (Simulated-Distillation Gas Chromatography) on two liquid fuel samples (i.e. a decanted oil and a filtered crude oil) are also discussed in this paper.

Huang, He; Wang, Keyu; Wang, Shaojie; Klein, M.T.; Calkins, W.H.

1996-12-31T23:59:59.000Z

293

Integrated Low Emissions Cleanup system for direct coal fueled turbines  

Science Conference Proceedings (OSTI)

The United States Department of.Energy, Morgantown Energy Research Center (DOE/METC), is sponsoring the development of coal-fired turbine technology in the areas of Pressurized Fluidized Bed Combustion, Integrated Gasification Combined Cycles, and Direct Coal-Fired Turbines. A major technical challenge remaining for the development of coal-fired turbine systems is high-temperature gas cleaning to meet environmental standards for sulfur oxides and particulate emissions, as well as to provide acceptable turbine life. The Westinghouse Electric Corporation, Science & Technology Center, is evaluating an Integrated Low Emissions Cleanup (ILEC) concept that has been configured to meet this technical challenge. This ceramic barrier filter, ILEC concept simultaneously controls sulfur, particulate, and alkali contaminants in high-pressure fuel gases or combustion gases, and is considering cleaning temperatures up to 2100{degrees}F. This document describes Phase II of the program, the design, construction, and shakedown of a bench-scale facility to test and confirm the feasibility of this ILEC technology.

Newby, R.A.; Alvin, M.A.; Bachovchin, D.M.; Smeltzer, E.E.; Lippert, T.E.

1993-07-01T23:59:59.000Z

294

Results Summary Investigating the Use of Liquid CO2 Coal Slurry for Feeding Low Rank Coal to the E-Gas Gasifier  

Science Conference Proceedings (OSTI)

This report summarizes the results of US Department of Energy (DOE) Award No. DE-FE0007977, Liquid CO2/Coal Slurry for Feeding Low Rank Coal to Gasifiers, which investigates the practicality of using a liquid CO2/coal slurry preparation and feed system for the E-Gas gasifier in an integrated-gasificationcombined-cycle (IGCC) electric power generation plant configuration.Liquid CO2 (LCO2) has several property differences from water that ...

2013-12-11T23:59:59.000Z

295

Tire-Derived Fuel Cofiring Test in a Pulverized Coal Utility Boiler  

Science Conference Proceedings (OSTI)

Several utilities are cofiring tire-derived fuel (TDF) with coal and other fuels in stoker, fluidized-bed, and cyclone-fired boilers. The field tests described in this report provide data on and will be of interest to utilities evaluating TDF cofiring in pulverized coal (PC) boilers.

1995-02-08T23:59:59.000Z

296

Coal-fueled high-speed diesel engine development: Task 2, Market assessment and economic analysis  

DOE Green Energy (OSTI)

Based on the preliminary coal engine design developed, this task was conducted to identify the best opportunity(s) to enter the market with the future coal-fueled, high-speed diesel engine. The results of this market and economic feasibility assessment will be used to determine what specific heavy duty engine application(s) are most attractive for coal fuel, and also define basic economic targets for the engine to be competitive.

Not Available

1991-12-01T23:59:59.000Z

297

Novel injector techniques for coal-fueled diesel engines. Final report  

DOE Green Energy (OSTI)

This report, entitled ``Novel Injector Techniques for Coal-Fueled Diesel Engines,`` describes the progress and findings of a research program aimed at development of a dry coal powder fuel injector in conjunction with the Thermal Ignition Combustion System (TICS) concept to achieve autoignition of dry powdered coal in a single-cylinder high speed diesel engine. The basic program consisted of concept selection, analysis and design, bench testing and single cylinder engine testing. The coal injector concept which was selected was a one moving part dry-coal-powder injector utilizing air blast injection. Adiabatics has had previous experience running high speed diesel engines on both direct injected directed coal-water-slurry (CWS) fuel and also with dry coal powder aspirated into the intake air. The Thermal Ignition Combustion System successfully ignited these fuels at all speeds and loads without requiring auxiliary ignition energy such as pilot diesel fuel, heated intake air or glow or spark plugs. Based upon this prior experience, it was shown that the highest efficiency and fastest combustion was with the dry coal, but that the use of aspiration of coal resulted in excessive coal migration into the engine lubrication system. Based upon a desire of DOE to utilize a more modern test engine, the previous naturally-aspirated Caterpillar model 1Y73 single cylinder engine was replaced with a turbocharged (by use of shop air compressor and back pressure control valve) single cylinder version of the Cummins model 855 engine.

Badgley, P.R.

1992-09-01T23:59:59.000Z

298

NETL: News Release - World's First Coal Mine Methane Fuel Cell Powers Up in  

NLE Websites -- All DOE Office Websites (Extended Search)

22, 2003 22, 2003 World's First Coal Mine Methane Fuel Cell Powers Up in Ohio New Technology Mitigates Coal Mine Methane Emissions, Produces Electricity HOPEDALE, OH - In a novel pairing of old and new, FuelCell Energy of Danbury, Conn., has begun operating the world's first fuel cell powered by coal mine methane. Funded by the Department of Energy, the demonstration harnesses the power of a pollutant - methane emissions from coal mines - to produce electricity in a new, 21st Century fuel cell. MORE INFO Remarks by DOE's James Slutz FuelCell Energy Web Site "We believe this technology can reduce coal mine methane emissions significantly while producing clean, efficient, and reliable high-quality power," Secretary of Energy Spencer Abraham said. "This has the dual

299

Syngas production from heavy liquid fuel reforming in inert porous media  

E-Print Network (OSTI)

with the low H2 density is the movement: the power required to pump hydrogen is around 4.5 times higher than for natural gas per unit of delivered energy [17]. Hydrogen can be stored on-board a vehicle as a compressed gas, as a liquid in cryogenic containers... and the transportation system are mainly based on the combustion of fossil fuels, generally defined as oil, coal and natural gas, as shown in Fig. 1.1. There are several issues to be considered about fossil fuel consumption. First of all, the greenhouse gas emission, due...

Pastore, Andrea

2010-11-16T23:59:59.000Z

300

Characterization and supply of coal-based fuels. Quarterly report, August 1, 1989--October 31, 1989  

SciTech Connect

Under the Department of Energy`s Combustor Technology Program, combustor contractors are developing combustor systems for use in residential, commercial, light industrial and industrial retrofit markets. Well-characterized coal based fuels possessing appropriate specifications are required by the contractors for their developmental test programs. Fuels may be dry pulverized or micronized coal or coal-water fuels. In support of these equipment development efforts, Energy International is providing such fuels. A complete list of all of the delivered fuels,the quantities and users are provided in the Appendix. Their fuel needs ranged from small sample quantities (e.g. 5 to 500 lbs.) up to 15 tons per delivery; by now most no longer need fuel. During the twelfth quarter of this contract (August 1, 1989 through October 31, 1989) the primary activities were involved with: (1) Continuation of the procurement, preparation and delivery of coal-based fuels for the combustor contractors. (2) Continuation of the interaction with combustor contractors in order to update their fuel specifications, fuel requirements and delivery schedules. (3) Continuation of the quality control activities to insure that fuel specifications are being met and to determine the cause of any problem which might occur. (4) Issuance of a request-for-bid (Procurement {number_sign}MN-01-2003) for deep cleaning of Upper Elkhorn {number_sign}3 coal to below 2% ash level, and subsequent award of purchase orders to five bidders. (5) Delivery to two separate PETC contractors coal-water slurry and dry, ground coal fuels. (5) Delivery of feed coals to three EI subcontractors who will deep-clean coal (Procurement Package {number_sign}MN-01-2003).

1989-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

ENCOAL Mild Coal Gasification Project  

DOE Green Energy (OSTI)

ENCOAL Corporation, a wholly-owned subsidiary of Shell Mining Company, is constructing a mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by Shell and SGI International, utilizes low-sulfur Powder River Basin Coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly reduce current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain.

Not Available

1992-02-01T23:59:59.000Z

302

Fuel gas production by microwave plasma in liquid  

Science Conference Proceedings (OSTI)

We propose to apply plasma in liquid to replace gas-phase plasma because we expect much higher reaction rates for the chemical deposition of plasma in liquid than for chemical vapor deposition. A reactor for producing microwave plasma in a liquid could produce plasma in hydrocarbon liquids and waste oils. Generated gases consist of up to 81% hydrogen by volume. We confirmed that fuel gases such as methane and ethylene can be produced by microwave plasma in liquid.

Nomura, Shinfuku; Toyota, Hiromichi; Tawara, Michinaga; Yamashita, Hiroshi; Matsumoto, Kenya [Graduate School of Science and Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama, Ehime 790-8577 (Japan); Shikoku Industry and Technology Promotion Center, 2-5 Marunouchi, Takamatsu, Kagawa 760-0033 (Japan)

2006-06-05T23:59:59.000Z

303

Conversion system overview assessment. Volume III. Solar thermal/coal or biomass derived fuels  

SciTech Connect

The three volumes of this report cover three distinct areas of solar energy research: solar thermoelectrics, solar-wind hybrid systems, and synthetic fuels derived with solar thermal energy. Volume III deals with the conversion of synthetic fuels with solar thermal heat. The method is a hybrid combination of solar energy with either coal or biomass. A preliminary assessment of this technology is made by calculating the cost of fuel produced as a function of the cost of coal and biomass. It is shown that within the projected ranges of coal, biomass, and solar thermal costs, there are conditions when solar synthetic fuels with solar thermal heat will become cost-competitive.

Copeland, R. J.

1980-02-01T23:59:59.000Z

304

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS  

DOE Green Energy (OSTI)

Reburn with animal waste yield NO{sub x} reduction of the order of 70-80%, which is much higher than those previously reported in the literature for natural gas, coal and agricultural biomass as reburn fuels. Further, the NO{sub x} reduction is almost independent of stoichiometry from stoichiometric to upto 10% deficient air in reburn zone. As a first step towards understanding the reburn process in a boiler burner, a simplified zero-dimensional model has been developed for estimating the NO{sub x} reduction in the reburn process using simulated animal waste based biomass volatiles. However the first model does not include the gradual heat up of reburn fuel particle, pyrolysis and char combustion. Hence there is a need for more rigorous treatment of the model with animal waste as reburn fuel. To address this issue, an improved zero-dimensional model is being developed which can handle any solid reburn fuel, along with more detailed heterogeneous char reactions and homogeneous global reactions. The model on ''NO{sub x} Reduction for Reburn Process using Feedlot Biomass,'' incorporates; (a) mixing between reburn fuel and main-burner gases, (b) gradual heat-up of reburn fuel accompanied by pyrolysis, oxidation of volatiles and char oxidation, (c) fuel-bound nitrogen (FBN) pyrolysis, and FBN including both forward and backward reactions, (d) prediction of NO{sub x} as a function of time in the reburn zone, and (e) gas phase and solid phase temperature as a function of time. The fuel bound nitrogen is assumed to be released to the gas phase by two processes, (a) FBN evolution to N{sub 2}, HCN, and NH{sub 3}, and (b) FBN oxidation to NO at the char surface. The formulation has been completed, code has been developed, and preliminary runs have been made to test the code. Note that, the current model does not incorporate the overfire air. The results of the simulation will be compared with the experimental results. During this quarter, three journal and four conference publications dealing with utilization of animal waste as fuel have been published. In addition a presentation was made to a utility company interested in the new reburn technology for NO{sub x} reduction.

Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Soyuz Priyadarsan (PhD)

2003-06-01T23:59:59.000Z

305

Synergistic routes to liquid fuel for a petroleum-deprived future  

Science Conference Proceedings (OSTI)

When compared with biomass gasification/Fischer-Tropsch synthesis, hydropyrolysis/hydrodeoxygenation (HDO)-based processes have a potential to achieve high biomass carbon conversion to liquid fuel with much lower amounts of supplementary H{sub 2}. On the basis of this observation, we suggest a Hydrogen Bio-oil (H{sub 2}Bioil) process using fast hydropyrolysis/HDO that has a potential to produce nearly double the amount of liquid fuel when compared with the existing biofuel processes while requiring only modest quantities of supplementary H{sub 2}. The optimal operating mode for the H{sub 2}Bioil process is suggested to be in an entrained bed mode in presence of H{sub 2} with gas phase HDO of hydropyrolyzed vapors. A remarkable result due to reduced need for the supplementary H{sub 2} is that it provides synergistic integration of the H(2)Bioil process with a coal gasification power plant or a small scale steam natural gas (NG) reformer leading to a dramatic increase in the liquid fuel production from biomass and coal or NG. Here, hot synthesis gas (T>500{sup o}C) from a coal gasifier or methane reformer supplies H{sub 2}/CO for hydropyrolysis and deoxygenation as well as heat for the process. This result is exciting, because it presents us with an option to build integrated H{sub 2}Bioil processes sooner rather than later when the cost effective H{sub 2}, becomes available from a carbon-free energy source such as solar or nuclear. The H{sub 2}Bioil process and its integrated version with a small scale NG reformer have strong potential to be attractive on a small scale while being more efficient than any current biomass to liquid fuel process in operation.

Agrawal, R.; Singh, N.R. [Purdue University, West Lafayette, IN (United States). School of Chemical Engineering

2009-07-15T23:59:59.000Z

306

Coal-to-Liquids in the U S Status and Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal-to-Liquids in the United States Status and Roadmap CTLtec Americas 2008 June 23 - 24, 2008 Daniel C. Cicero, Technology Manager, Hydrogen and Syngas National Energy Technology...

307

Carbon Management for a Coal/Biomass to Liquids Plant in Northeast...  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon ManageMent for a CoalbioMass to liquids Plant in northeast ohio Background This project involves the development of a carbon management plan for a proposed coal and biomass...

308

Conversion of olefins to liquid motor fuels  

DOE Patents (OSTI)

Linear and/or branched claim C.sub.2 to C.sub.12 olefins are converted to hydrocarbon mixtures suitable for use as liquid motor fuels by contact with a catalyst capable of ensuring the production of desirable products with only a relatively minor amount of heavy products boiling beyond the diesel oil range. The catalyst having desirable stability during continuous production operations, comprises a steam stabilized zeolite Y catalyst of hydrophobic character, desirably in aluminum-extracted form. The olefins such as propylene, may be diluted with inerts, such as paraffins or with water, the latter serving to moderate the acidity of the catalyst, or to further moderate the activity of the aluminum-extracted catalyst, so as to increase the effective life of the catalyst.

Rabo, Jule A. (Armonk, NY); Coughlin, Peter K. (Yorktown Heights, NY)

1988-01-01T23:59:59.000Z

309

Biological production of liquid fuels from biomass  

DOE Green Energy (OSTI)

A scheme for the production of liquid fuels from renewable resources such as poplar wood and lignocellulosic wastes from a refuse hydropulper was investigated. The particular scheme being studied involves the conversion of a cellulosic residue, resulting from a solvent delignified lignocellulosic feed, into either high concentration sugar syrups or into ethyl and/or butyl alcohol. The construction of a pilot apparatus for solvent delignifying 150 g samples of lignocellulosic feeds was completed. Also, an analysis method for characterizing the delignified product has been selected and tested. This is a method recommended in the Forage Fiber Handbook. Delignified samples are now being prepared and tested for their extent of delignification and susceptibility to enzyme hydrolysis. Work is continuing on characterizing the cellulase and cellobiase enzyme systems derived from the YX strain of Thermomonospora.

Not Available

310

AEO2011: Liquid Fuels Supply and Disposition | OpenEI  

Open Energy Info (EERE)

Liquid Fuels Supply and Disposition Liquid Fuels Supply and Disposition Dataset Summary Description This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 11, and contains only the reference case. The dataset uses million barrels per day. The data is broken down into crude oil, other petroleum supply, other non petroleum supply and liquid fuel consumption. Source EIA Date Released April 26th, 2011 (3 years ago) Date Updated Unknown Keywords 2011 AEO disposition EIA liquid fuels Supply Data application/vnd.ms-excel icon AEO2011: Liquid Fuels Supply and Disposition- Reference Case (xls, 117 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Annually

311

Combustion research related to utilization of coal as a gas turbine fuel  

SciTech Connect

A nominal 293 kw (1 MBtu/hr) atmospheric pressure, refractory-lined combustor has been used to investigate the effects of a number of combustor and fuel dependent variables on combustion efficiency and flue gas characteristics for minimally cleaned, coal-derived gas (MCG) and coal water mixtures. The variables which have been evaluated include: percent excess air, air distribution, combustion air preheat temperature, swirl number, fuel feedrate, coal particle size, coal loading in slurry, and slurry viscosity. Characterization of the flue gas included major/minor gas species, alkali levels, and particulate loading, size, and composition. These atmospheric pressure combustion studies accompanied by data from planned pressurized studies on coal-water slurries and hot, minimally cleaned, coal-derived gas will aid in the determination of the potential of these fuels for use in gas turbines.

Davis-Waltermine, D.M.; Anderson, R.J.

1984-06-01T23:59:59.000Z

312

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS  

DOE Green Energy (OSTI)

The following are proposed activities for quarter 2 (9/15/00-12/14/00): (1) Conduct TGA and fuel characterization studies--Task 1; (2) Perform re-burn experiments--Task 2; (3) Fabricate fixed bed gasifier/combustor--Task 3; and (4) Modify the 3D combustion modeling code for feedlot and litter fuels--Task 4. The following were achieved During Quarter 2 (9/15/00-12/14/00): (1) The chicken litter has been obtained from Sanderson farms in Denton, after being treated with a cyclonic dryer. The litter was then placed into steel barrels and shipped to California to be pulverized in preparation for firing. Litter samples have also been sent for ultimate/proximate laboratory analyses.--Task 1; (2) Reburn-experiments have been conducted on coal, as a base case for comparison to litter biomass. Results will be reported along with litter biomass as reburn fuel in the next report--Task 2; (3) Student has not yet been hired to perform task 3. Plans are ahead to hire him or her during quarter No. 3; and (4) Conducted a general mixture fraction model for possible incorporation in the code.

Dr. Kalyan Annamalai; Dr. John Sweeten; Dr. Sayeed Mukhtar

2001-02-05T23:59:59.000Z

313

Apparatus and method for pumping hot, erosive slurry of coal solids in coal derived, water immiscible liquid  

SciTech Connect

An apparatus for and method of pumping hot, erosive slurry of coal solids in a coal derived, water immiscible liquid to higher pressure involves the use of a motive fluid which is miscible with the liquid of the slurry. The apparatus includes a pump 12, a remote check valve 14 and a chamber 16 between and in fluid communication with the pump 12 and check valve 14 through conduits 18,20. Pump 12 exerts pressure on the motive fluid and thereby on the slurry through a concentration gradient of coal solids within chamber 16 to alternately discharge slurry under pressure from the outlet port of check valve 14 and draw slurry in through the inlet port of check valve 14.

Ackerman, Carl D. (Olympia, WA)

1983-03-29T23:59:59.000Z

314

Refinery Integration of By-Products from Coal-Derived Jet Fuels  

Science Conference Proceedings (OSTI)

This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2006-05-17T23:59:59.000Z

315

Advanced coal-fueled gas turbine systems reference system definition update  

Science Conference Proceedings (OSTI)

The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

Not Available

1991-09-01T23:59:59.000Z

316

Coal-fueled diesel emissions control technology development  

DOE Green Energy (OSTI)

The objective of this project is to develop an emissions control system for a GE locomotive powered by a Coal Water Slurry (CWS) fuel diesel engine. The development effort is directed toward reducing particulate matter, SO{sub 2} and NO{sub x} emissions from the engine exhaust gas at 700--800F and 1-2 psig. The commercial system should be economically attractive while subject to limited space constraints. After testing various alternatives, a system composed of a barrier filter with sorbent injection ups was selected for controlling particulates, SO{sub 2} and NO{sub x} emissions. In bench scale and 500 acfm slip s tests, removal efficiencies greater than 90% for SO{sub 2} and 85% for NO{sub x} were achieved. Particulate emissions from the barrier filter are within NSPS limits.

Cook, C.; Gal, E.; Mengel, M.; Van Kleunen, W.

1993-03-01T23:59:59.000Z

317

Coal-fueled diesel emissions control technology development  

DOE Green Energy (OSTI)

The objective of this project is to develop an emissions control system for a GE locomotive powered by a Coal Water Slurry (CWS) fuel diesel engine. The development effort is directed toward reducing particulate matter, SO[sub 2] and NO[sub x] emissions from the engine exhaust gas at 700--800F and 1-2 psig. The commercial system should be economically attractive while subject to limited space constraints. After testing various alternatives, a system composed of a barrier filter with sorbent injection ups was selected for controlling particulates, SO[sub 2] and NO[sub x] emissions. In bench scale and 500 acfm slip s tests, removal efficiencies greater than 90% for SO[sub 2] and 85% for NO[sub x] were achieved. Particulate emissions from the barrier filter are within NSPS limits.

Cook, C.; Gal, E.; Mengel, M.; Van Kleunen, W.

1993-01-01T23:59:59.000Z

318

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS FUELS  

DOE Green Energy (OSTI)

Proposed activities for quarter 7 (12/15/01-3/14/2002): (1) Incorporation of moisture model into PCGC2 code. Parametric study of moisture effects on flame structure and pollutants emissions in cofiring of coal and Liter Biomass (LB) (Task 4); (2) Use the ash tracer method to determine the combustion efficiency and comparison it to results from gas analysis (Task 2); (3) Effect of swirl on combustion performance (Task 2); (4) Completion of the proposed modifications to the gasifier setup (Task 3); (5) Calibration of the Gas Chromatograph (GC) used for measuring the product gas species (Task 3); and (6) To obtain temperature profiles for different fuels under different operating conditions in the fixed bed gasifier (Task 3).

Unknown

2002-03-31T23:59:59.000Z

319

U.S. coal exports on record pace in 2012, fueled by steam coal ...  

U.S. Energy Information Administration (EIA)

U.S. 2012 coal exports, supported by rising steam coal exports, are expected to break their previous record level of almost 113 million tons, set in ...

320

Vibration mills in the manufacturing technology of slurry fuel from unbeneficiated coal sludge  

Science Conference Proceedings (OSTI)

Coal-water slurry fuel (CWSF) is economically viable provided that its ash content does not exceed 30% and the amount water in the fuel is at most 45%. Two impoundments were revealed that have considerable reserves of waste coal useful for commercial manufacture of CWSF without the beneficiation step. One of the CWSF manufacture steps is the comminution of coal sludge to have a particle size required by the combustion conditions. Vibration mills, which are more compact and energy-intensive that drum mills, can be used in the CWSG manufacture process. The rheological characteristics of CWSF obtained from unbeneficiated waste coal were determined.

E.G. Gorlov; A.I. Seregin; G.S. Khodakov [Institute for Fossil Fuels, Moscow (Russia)

2008-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Coal-water slurry spray characteristics of a positive displacement fuel injection system  

DOE Green Energy (OSTI)

Experiments have been completed to characterized coal-water slurry sprays from a modified positive displacement fuel injection system of a diesel engine. The injection system includes an injection jerk pump driven by an electric motor, a specially designed diaphragm to separate the abrasive coal from the pump, and a single-hole fuel nozzle. The sprays were injected into a pressurized chamber equipped with windows. High speed movies and instantaneous fuel line pressures were obtained. For injection pressures of order 30 MPa or higher, the sprays were similar for coal-water slurry, diesel fuel and water. The time until the center core of the spray broke-up (break-up time) was determined from both the movies and from a model using the fuel line pressures. Results from these two independent procedures were in good agreement. For the base conditions, the break-up time was 0.58 and 0.50 ms for coal-water slurry and diesel fuel, respectively. The break-up times increased with increasing nozzle orifice size and with decreasing chamber density. The break-up time was not a function of coal loading for coal loadings up to 53%. Cone angles of the sprays were dependent on the operating conditions and fluid, as well as on the time and location of the measurement. For one set of cases studied, the time-averaged cone angle was 15.9{degree} and 16.3{degree} for coal-water slurry and diesel fuel, respectively.

Seshadri, A.K.; Caton, J.A.; Kihm, K.D. [Texas A and M Univ., College Station, TX (United States). Dept. of Mechanical Engineering

1992-12-31T23:59:59.000Z

322

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

DOE Green Energy (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

323

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

DOE Green Energy (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

324

Mulled coal - a beneficiation coal form for use as a fuel or fuel intermediate. Technical progress report No. 9, April 1, 1992--June 30, 1992  

SciTech Connect

Under the auspices of the DOE and private industry, considerable progress has been made in: preparation of coal-water fuels; combustion of low-ash coal-based fuel forms; processes to provide deeply-cleaned coal. Developments in advanced beneficiation of coal to meet stringent requirements for low ash and low sulfur can be anticipated to further complicate the problem areas associated with this product. This is attributable to the beneficiated coal being procured in very fine particles with high surface areas, modified surface characteristics, reduced particle size distribution range, and high inherent moisture. Experience in the storage, handling, and transport of highly beneficiated coal has been limited. This is understandable, as quantities of such product are only now becoming available in meaningful quantities. During this reporting period the authors have: developed a suite of empirical tests covering water retention, rewetting, mull stability, angle of repose, dusting, etc.; a standardized suite for testing handling properties has been developed; initiated screening studies of alternate mulling agent formulations; mulls from six different coals and coals cleaned at different levels are being prepared for evaluation.

1993-01-01T23:59:59.000Z

325

Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction  

SciTech Connect

The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

Andile B. Mzinyati [Sasol Technology Research and Development, Sasolburg (South Africa). Fischer-Tropsch Refinery Catalysis

2007-09-15T23:59:59.000Z

326

Examination of Coal Solubility and Fragmentation with Various Ionic Liquids.  

E-Print Network (OSTI)

??The organic component of coal is heterogeneous and often has a complicated networkstructure. When exposed to certain solvents, swelling and partial dissolution often occurs.However, due (more)

Pulati, Nuerxida

2011-01-01T23:59:59.000Z

327

EIA - International Energy Outlook 2008-Liquid Fuels Graphic Data  

Gasoline and Diesel Fuel Update (EIA)

Liquid Fuels Liquid Fuels International Energy Outlook 2008 Figure 26. World Liquids Production in the Reference Case, 1990-2030 Figure 26 Data. Need help, contact the National Energy Information Center at 202-586-8800. Figure 27. World Production of Unconventional Liquid Fuels, 2005-2030 Figure 27 Data. Need help, contact the National Energy Information Center at 202-586-8800. Figure 28. World Liquids Consumption by Sector, 2005-2030 Figure 28 Data. Need help, contact the National Energy Information Center at 202-586-8800. Figure 29. World Liquids Consumption by Region and Country Group, 2005 and 2030 Figure 29 Data. Need help, contact the National Energy Information Center at 202-586-8800. Figure 30. Nominal World Oil Prices in three Cases, 1980-2030 Figure 30 Data. Need help, contact the National Energy Information Center at 202-586-8800.

328

Preconversion processing of bituminous coals: New directions to improved direct catalytic coal liquefaction. [Effect of preconversion heat soak with coal liquids  

SciTech Connect

A study of the high-temperature soaking started in this quarter, following the installation of reactors in the previous quarter. Two high-volatile bituminous coals and three coal liquids, which were identified in the previous report, were used. A cross-linked, three-dimensional macromolecular model has been widely accepted f or the structure of coal, but there is no direct evidence to prove this model. The conventional coal structure model has been recently re-examined by this investigator because of the importance of relatively strong intra- and intermolecular interactions in bituminous coals. It was reasonable to deduce that significant portions were physically associated after a study of multistep extractions, associative equilibria, the irreversibility and the dependence of coal concentration on solvent swelling, and consideration of the monophase concept. Physical dissociation which may be significant above 300{degree}C should be utilized for the treatment before liquefaction. The high-temperature soaking in a recycle oil was proposed to dissociate coal complexes.

1992-07-01T23:59:59.000Z

329

Separating liquid and solid products of liquefaction of coal or like carbonaceous materials  

DOE Patents (OSTI)

Slurryform products of coal liquefaction are treated with caustic soda in presence of H.sub.2 O in an inline static mixer and then the treated product is separated into a solids fraction and liquid fractions, including liquid hydrocarbons, by gravity settling preferably effected in a multiplate settling separator with a plurality of settling spacings.

Malek, John M. (P.O. Box 71, Lomita, CA 90717)

1979-06-26T23:59:59.000Z

330

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS  

DOE Green Energy (OSTI)

Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process. Computer simulations for coal: LB blends were performed by modifying an existing computer code to include the drying and phosphorus (P) oxidation models. The gasification studies revealed that there is bed agglomeration in the case of chicken litter biomass due to its higher alkaline oxide content in the ash. Finally, the results of the economic analysis show that considerable fuel cost savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings is reduced.

Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

2003-08-28T23:59:59.000Z

331

Method for improving the sedimentation and filterability of coal-derived liquids  

SciTech Connect

An improvement in the separation of suspended solids from coal-derived liquids by a separations process in which solids size is a separations parameter is achieved by contacting the coal-derived liquid containing suspended solids with an effective amount of an additive selected from the group of sulfuric acid, phosphoric acid, phosphoric anhydride and salts of sulfuric and phosphoric acid, and maintaining the contacted liquid at a temperature within the range of about 150.degree.-400.degree. C and for a time sufficient to achieve the desired separation rate.

Katz, Sidney (Oak Ridge, TN); Rodgers, Billy R. (Concord, TN)

1979-01-02T23:59:59.000Z

332

Liquid-phase ozonation of fusainized components of SS coal  

SciTech Connect

Stepwise ozonation of leaning fusainized components of fossil coal of SS grade in acetic acid was studied. The dynamics of accumulation of oxygen-containing groups in the course of ozonation was examined, and the main pathways of the reaction of ozone with structural fragments of the coal substance were revealed.

Semenova, S.A.; Patrakov, Y.F. [Russian Academy of Sciences, Kemerovo (Russian Federation)

2007-11-15T23:59:59.000Z

333

Mixture of micronized coal powder with gaseous fuels for use in internal combustion engines  

DOE Patents (OSTI)

An improved fuel mixture for use in internal combustion engines is described. This fuel is an intimate mixture of micronized coal, having an average particle size of less than 100 microns, with a gaseous fuel selected from natural gas and coal-derived. The coal can be present from more than 0 percent to less than 100 percent, with generally the lower percentages being preferred. The addition of the coal to the gaseous fuel improves engine efficiency and power rating, and also decreases peak engine pressure allowing for higher compression ratios. An increase in the amount of the coal increases the oxides of sulfur while reducing the oxides of nitrogen in the exhaust. An increase in the amount of gas, on the other hand, increases the oxides of nitrogen but lowers oxides of sulfur. Accordingly, a preferred mixture will depend upon a particular application for the coal/gas fuel and thereby increases user fuel flexibility considerations. Modeling of the fuel mixture for use in a diesel engine is described. 3 figs., 3 tabs.

Carpenter, L.K.

1990-01-03T23:59:59.000Z

334

Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 6, July 1990--September 1990  

Science Conference Proceedings (OSTI)

The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a three-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are being run at the cleaning facility in Homer City, Pennsylvania, to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CVVT) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. Subcontractors to CE to perform parts of the test work are the Massachusetts Institute of Technology (MIT), Physical Science, Inc. Technology Company (PSIT) and the University of North Dakota Energy and Environmental Research Center (UNDEERC). Twenty fuels will be characterized during the three-year base program: three feed coals, fifteen BCFS, and two conventionally cleaned coals for full-scale tests. Approximately, nine BCFs will be in dry microfine coal (DMPC) form, and six BCFs will be in coal-water fuel (CWF) form. Additional BCFs would be characterized during optional project supplements.

Chow, O.K.; Nsakala, N.Y.

1990-11-01T23:59:59.000Z

335

Coal....  

U.S. Energy Information Administration (EIA)

DOE EIA WEEKLY COAL ... Coal Prices and Earnings (updated April 28, 2004) Spot coal prices in the East rose steadily since Labor Day 2003, with rapid escalations ...

336

Coal....  

U.S. Energy Information Administration (EIA)

DOE EIA WEEKLY COAL ... Coal Prices and Earnings (updated September 26) The average spot prices for reported coal purchases rose once again ...

337

Mulled coal - a beneficiation coal form for use as a fuel or fuel intermediate. Technical progress report No. 10, July 1, 1992--September 30, 1992  

SciTech Connect

Under the auspices of the DOE and private industry, considerable progress has been made in: preparation of coal-water fuels; combustion of low-ash coal-based fuel forms; processes to provide deeply-cleaned coal. Developments in advanced beneficiation of coal to meet stringent requirements for low ash and low sulfur can be anticipated to further complicate the problem areas associated with this product. This is attributable to the beneficiated coal being procured in very fine particles with high surface areas, modified surface characteristics, reduced particle size distribution range, and high inherent moisture. Experience in the storage, handling, and transport of highly beneficiated coal has been limited. This is understandable, as quantities of such product are only now becoming available in meaningful quantities. During this reporting period the authors have: begun weathering studies on neat mull and source fuel; completed design of integrated continuous process circuit for mull formulations; extended aging studies on various mull formulations; started cost estimates on 100 tph mulling circuit.

1993-01-01T23:59:59.000Z

338

Process for the production and recovery of fuel values from coal  

SciTech Connect

A method of pyrolyzing and desulfurizing coal in a transport reactor to recover volatile fuel values and hydrogen by heating particulate coal entrained in a carrier gas substantially free of oxygen to a pyrolysis temperature in a zone within three seconds.

Sass, Allan (Los Angeles, CA); McCarthy, Harry E. (Golden, CO); Kaufman, Paul R. (North Canton, OH); Finney, Clement S. (Claremont, CA)

1982-01-01T23:59:59.000Z

339

Evaluation of 450-MWe BGL GCC Power Plants Fueled With Pittsburgh No. 8 Coal  

Science Conference Proceedings (OSTI)

Detailed design and cost estimates have been developed for conventionally and highly integrated 450-MWe, British Gas/Lurgi (BGL) gasification-combined-cycle (GCC) power plants employing two General Electric (GE) MS-7001F gas turbines and fueled with Pittsburgh No. 8 coal. The plants have attractive heat rates and capital costs that are competitive with conventional coal-based power technology.

1992-12-01T23:59:59.000Z

340

Evaluation of a 510-MWe Destec GCC Power Plant Fueled with Illinois No. 6 Coal  

Science Conference Proceedings (OSTI)

A detailed design and cost estimate has been developed for a 510-MWe, conventionally integrated, Destec gasification-combined-cycle (GCC) power plant employing two General Electric (GE) MS-7001F gas turbines and fueled with Illinois no. 6 coal. The plant has an attractive heat rate and a capital cost that is competitive with conventional coal-based power technology.

1992-07-14T23:59:59.000Z

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341

Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction  

DOE Patents (OSTI)

A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

1989-10-17T23:59:59.000Z

342

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

DOE Green Energy (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

K. C. Kwon

2006-09-30T23:59:59.000Z

343

Investigations into coal coprocessing and coal liquefaction  

DOE Green Energy (OSTI)

The conversion of coal to liquid suitable as feedstock to a petroleum refinery is dependent upon several process variables. These variables include temperature, pressure, coal rank, catalyst type, nature of the feed to the reactor, type of process, etc. Western Research Institute (WRI) has initiated a research program in the area of coal liquefaction to address the impact of some of these variables upon the yield and quality of the coal-derived liquid. The principal goal of this research is to improve the efficiency of the coal liquefaction process. Two different approaches are currently being investigated. These include the coprocessing of a heavy liquid, such as crude oil, and coal using a dispersed catalyst and the direct liquefaction of coal using a supported catalyst. Another important consideration in coal liquefaction is the utilization of hydrogen, including both externally- and internally-supplied hydrogen. Because the incorporation of externally-supplied hydrogen during conversion of this very aromatic fossil fuel to, for example, transportation fuels is very expensive, improved utilization of internally-supplied hydrogen can lead to reducing processing costs. The objectives of this investigation, which is Task 3.3.4, Coal Coprocessing, of the 1991--1992 Annual Research Plan, are: (1) to evaluate coal/oil pretreatment conditions that are expected to improve the liquid yield through more efficient dispersion of an oil-soluble, iron-based catalyst, (2) to characterize the coke deposits on novel, supported catalysts after coal liquefaction experiments and to correlate the carbon skeletal structure parameters of the coke deposit with catalyst performance as measured by coal liquefaction product yield, and (3) to determine the modes of hydrogen utilization during coal liquefaction and coprocessing. Experimental results are discussed in this report.

Guffey, F.D.; Netzel, D.A.; Miknis, F.P.; Thomas, K.P. [Western Research Inst., Laramie, WY (United States); Zhang, Tiejun; Haynes, H.W. Jr. [Wyoming Univ., Laramie, WY (United States). Dept. of Chemical Engineering

1994-06-01T23:59:59.000Z

344

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

DOE Green Energy (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the ninth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of October 1, 2005-December 31, 2005. This quarter saw progress in four areas. These areas are: (1) reformate purification, (2) heat transfer enhancement, (3) autothermal reforming coal-derived methanol degradation test; and (4) model development for fuel cell system integration. The project is on schedule and is now shifting towards the design of an integrated PEM fuel cell system capable of using the coal-derived product. This system includes a membrane clean up unit and a commercially available PEM fuel cell.

Paul A. Erickson

2006-01-01T23:59:59.000Z

345

International Technical Conference on Coal Utilization & Fuel Systems Clearwater (FL), USA, March 4-7, 2002  

E-Print Network (OSTI)

27th International Technical Conference on Coal Utilization & Fuel Systems Clearwater (FL), USA is a legitimate demand for more base-load energy which can be covered only by additional nuclear power the USA, i.e. Los Alamos

Zevenhoven, Ron

346

Gilberton Coal-to-Clean Fuels and Power Co-Production Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Power Initiative (CCPI) Gilberton Coal-to-Clean Fuels and Power Co-ProduCtion ProjeCt Description WMPI PTY., LLC of Gilberton, Pennsylvania has assembled a leading technology and...

347

Improving the technology of creating water-coal fuel from lignites  

Science Conference Proceedings (OSTI)

This paper describes the preparation of coal-water fuel slurries from lignite. The heat of combustion as related to the preparation of the lignite was investigated. The hydrobarothermal processing of suspensions of lignites was studied in autoclaves.

Gorlov, E.G.; Golovin, G.S.; Zotova, O.V. [Rossiiskaya Akadeiya, Nauk (Russian Federation)

1994-12-31T23:59:59.000Z

348

Development of alternative fuels from coal-derived syngas. Quarterly status report No. 6, January 1--March 31, 1992  

SciTech Connect

The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products` laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively ``benign`` system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE`s program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

Brown, D.M.

1992-05-19T23:59:59.000Z

349

EIA - AEO2010 - Liquid fuels taxes and tax credits  

Gasoline and Diesel Fuel Update (EIA)

Liquid fuels taxes and tax credits Liquid fuels taxes and tax credits Annual Energy Outlook 2010 with Projections to 2035 Liquid fuels taxes and tax credits This section provides a review of the treatment of Federal fuels taxes and tax credits in AEO2010. Excise taxes on highway fuel The treatment of Federal highway fuel taxes remains unchanged from the previous year’s AEO. Gasoline is taxed at 18.4 cents per gallon, diesel fuel at 24.4 cents per gallon, and jet fuel at 4.4 cents per gallon, consistent with current laws and regulations. Consistent with Federal budgeting procedures, which dictate that excise taxes dedicated to a trust fund, if expiring, are assumed to be extended at current rates, these taxes are maintained at their present levels, without adjustment for inflation, throughout the projection [9]. State fuel taxes are calculated on the basis of a volume-weighted average for diesel, gasoline, and jet fuels. The State fuel taxes were updated as of July 2009 [10] and are held constant in real terms over the projection period, consistent with historical experience.

350

C1 CHEMISTRY FOR THE PRODUCTION OF CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN  

DOE Green Energy (OSTI)

Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this program in its third year, as briefly summarized below. (1) Nanoscale iron-based catalysts containing molybdenum, palladium, or nickel and supported on alumina have been developed that are very effective for the dehydrogenation of methane and ethane to produce pure hydrogen and carbon nanotubes, a potentially valuable byproduct. Some of the nanotube structures are being investigated as a safe storage medium for hydrogen. Dehydrogenation of higher hydrocarbons, including several liquids that are compatible with vehicular transportation under fuel cell power, is currently under investigation. (2) Operation of Fischer-Tropsch (FT) synthesis under supercritical fluid (SCF) solvent conditions increases liquid fuel yields and improves the selectivity of the process to produce desired products. (3) Small additions ({approx}1%) of organic probe molecules with carbon-carbon triple bonds to the FT reaction markedly shift the molecular weight distribution and increase the oxygenate content of the products. The goal is to develop better technology for producing cleaner burning diesel fuel and other fuels. (4) Several different types of catalyst are under investigation to develop better control of FT fuel product distributions. (5) C1 processes have been developed for producing ethylene and propylene, two high-value products, from methanol. Novel silicoaluminophosphate (SAPO) catalysts containing nickel and other metals are used. (6) Binary tungsten-cobalt carbide catalysts have been found to have excellent activities and lifetimes for reforming of methane into synthesis gas using carbon dioxide. This type of catalyst is being further investigated for synthesis gas reactions relevant to the goal of producing hydrogen from coal.

Gerald P. Huffman

2002-09-30T23:59:59.000Z

351

Nuclear tanker producing liquid fuels from air and water  

E-Print Network (OSTI)

Emerging technologies in CO? air capture, high temperature electrolysis, microchannel catalytic conversion, and Generation IV reactor plant systems have the potential to create a shipboard liquid fuel production system ...

Galle-Bishop, John Michael

2011-01-01T23:59:59.000Z

352

Coal-water slurry spray characteristics of an electronically-controlled accumulator fuel injection system  

Science Conference Proceedings (OSTI)

Experiments have been complete to characterize coal-water slurry sprays from a electronically-controlled accumulator fuel injection system of diesel engine. The sprays were injected into a pressurized chamber equipped with windows. High speed movies, fuel pressures and needle lifts were obtained as a function of time, orifice diameter, coal loading, gas density in the chamber, and accumulator fuel pressure. For the base conditions 50% (by mass) coal loading, 0.4 mm diameter nozzle hole, coal-water slurry pressure of 82 MPa (12,000 psi), and a chamber density of 25 kg/m{sup 3}, the break-up time was 0. 30 ms. An empirical correlation for both spray tip penetration and initial jet velocity was developed. For the conditions of this study, the spray tip penetration and initial jet velocity were 15% greater for coal-water slurry than for diesel fuel or water. Cone angles of the sprays were dependent on the operating conditions and fluid, as well as the time and locations of the measurement. The time-averaged cone angle for the base case conditions was 13.6{degree}. Results of this study and the correlation are specific to the tested coal-water slurry and are not general for other coal-water slurry fuels.

Caton, J.A.; Payne, S.E.; Terracina, D.P.; Kihm, K.D. [Texas A and M Univ., College Station, TX (United States). Dept. of Mechanical Engineering

1993-12-31T23:59:59.000Z

353

Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 17, April--June 1993  

SciTech Connect

Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1993, the following technical progress was made: Completed modeling calculations of coal mineral matter transformations, deposition behavior, and heat transfer impacts of six test fuels; and ran pilot-scale tests of Upper Freeport feed coal, microagglomerate product, and mulled product.

Chow, O.K.; Nsakala, N.Y.

1993-08-01T23:59:59.000Z

354

Liquid chromatographic analysis of coal surface properties. Final report, September 1991--February 1995  

SciTech Connect

Experiments on equilibrium adsorption loadings of various probe compounds on 60-200 mesh Illinois {number_sign}6 coal (PSOC-1539), Adaville {number_sign}1 coal (PSOC-1544), Wyodak coal (PSOC-1545) and Pittsburgh {number_sign}8 coal (PSOC-1549) were performed. the probe compounds include m-cresol, p-cresol, o-cresol, phenol, n-octanol, n-heptanol, n-propanol, isopropanol n-butanol, s-butanol, 2-butanol, t-butanol, 2-naphthol, cyclohexanol, 2-methyl-1-pentanol (2M1P), 4-methyl-2-pentanol (4M2P), benzene and toluene. Equilibrium adsorption of various probe compounds on the coals were measured with the inverse liquid chromatography method. Experiments on flotation of various 60-200 mesh treated coals such as Illinois {number_sign}6 coal (PSOC-1539), Adaville {number_sign}1 coal (PSOC-1544), Wyodak coal (PSOC-1545) and Pittsburgh {number_sign}8 coal (PSOC-1549) were performed. The chosen coals were treated with steam, nitrogen and air at 1 atm and 125-225{degrees}C for 24 hours. The coals were treated with water as well as 20-1000 ppm aqueous alcohol solutions for 3-24 hours at 150-225{degrees}C. The coals also were treated with 20-ppm alcohol aqueous solutions for 1-24 hours at the 0.002-g/min mass flow rate of alcohol aqueous solutions and at 225{degrees}C. Flotation experiments were conducted with a 500-cm{sup 3} batch-type micro flotation apparatus, introducing nitrogen at the bottom of the apparatus. This final report was prepared with the experimental data obtained during the period of September 1991-March 1994.

Kwon, K.C.

1996-03-01T23:59:59.000Z

355

Coal-fueled diesel technology development. Final report, March 3, 1988--January 31, 1994  

DOE Green Energy (OSTI)

Since 1979, the US Department of Energy has been sponsoring Research and Development programs to use coal as a fuel for diesel engines. In 1984, under the partial sponsorship of the Burlington Northern and Norfolk Southern Railroads, GE completed a 30-month study on the economic viability of a coal-fueled locomotive. In response to a GE proposal to continue researching the economic and technical feasibility of a coal-fueled diesel engine for locomotives, DOE awarded a contract to GE Corporate Research and Development for a three-year program that began in March 1985 and was completed in 1988. That program was divided into two parts: an Economic Assessment Study and a Technical Feasibility Study. The Economic Assessment Study evaluated the benefits to be derived from development of a coal-fueled diesel engine. Seven areas and their economic impact on the use of coal-fueled diesels were examined; impact on railroad infrastructure, expected maintenance cost, environmental considerations, impact of higher capital costs, railroad training and crew costs, beneficiated coal costs for viable economics, and future cost of money. The Technical Feasibility Study used laboratory- and bench-scale experiments to investigate the combustion of coal. The major accomplishments of this study were the development of injection hardware for coal water slurry (CWS) fuel, successful testing of CWS fuel in a full-size, single-cylinder, medium-speed diesel engine, evaluation of full-scale engine wear rates with metal and ceramic components, and the characterization of gaseous and particulate emissions. Full combustion of CWS fuel was accomplished at full and part load with reasonable manifold conditions.

Not Available

1944-01-01T23:59:59.000Z

356

Process for removal of mineral particulates from coal-derived liquids  

SciTech Connect

Suspended mineral solids are separated from a coal-derived liquid containing the solids by a process comprising the steps of: (a) contacting said coal-derived liquid containing solids with a molten additive having a melting point of 100.degree.-500.degree. C. in an amount of up to 50 wt. % with respect to said coal-derived liquid containing solids, said solids present in an amount effective to increase the particle size of said mineral solids and comprising material or mixtures of material selected from the group of alkali metal hydroxides and inorganic salts having antimony, tin, lithium, sodium, potassium, magnesium, calcium, beryllium, aluminum, zinc, molybdenum, cobalt, nickel, ruthenium, rhodium or iron cations and chloride, iodide, bromide, sulfate, phosphate, borate, carbonate, sulfite, or silicate anions; and (b) maintaining said coal-derived liquid in contact with said molten additive for sufficient time to permit said mineral matter to agglomerate, thereby increasing the mean particle size of said mineral solids; and (c) recovering a coal-derived liquid product having reduced mineral solids content. The process can be carried out with less than 5 wt. % additive and in the absence of hydrogen pressure.

McDowell, William J. (Knoxville, TN)

1980-01-01T23:59:59.000Z

357

University Coal Research | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Science & Innovation Clean Coal Crosscutting Research University Coal Research University Coal Research Clean Coal Turbines Gasification Fuel Cells Hydrogen from Coal Coal...

358

Coal liquefaction process  

DOE Patents (OSTI)

A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

Wright, C.H.

1986-02-11T23:59:59.000Z

359

Coal liquefaction process  

DOE Green Energy (OSTI)

A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

Wright, Charles H. (Overland Park, KS)

1986-01-01T23:59:59.000Z

360

NETL: Gasification Systems - Liquid Carbon Dioxide/Coal Slurry for Feeding  

NLE Websites -- All DOE Office Websites (Extended Search)

Feed Systems Feed Systems Liquid Carbon Dioxide/Coal Slurry for Feeding Low-Rank Coal to Gasifiers Project Number: DE-FE0007977 There is increased interest in carbon capture and storage (CCS) for future coal-based power plants, and in a CCS integrated gasification plant, relatively pure, high pressure CO2 stream(s) will be available within the power plant. Electric Power Research Institute (EPRI) aims to help reduce the cost and improve the efficiency of integrated gasification combined cycle (IGCC) with CCS by using a portion of the high purity CO2 product stream as the carrier fluid to feed low rank coal (LRC) into the gasifier. EPRI proposes to confirm the potential advantages of LRC/liquid carbon dioxide (LCO2) slurries by: Conducting plant-wide technical and economic simulations.

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
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361

Coal....  

U.S. Energy Information Administration (EIA)

Coal Prices and Earnings (updated August 12) According to Platts Coal Outlooks Weekly Price Survey (August 11), the ...

362

Coal....  

U.S. Energy Information Administration (EIA)

Coal Prices and Earnings (updated September 2) The average spot prices for coal traded last week were relatively ...

363

C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen  

DOE Green Energy (OSTI)

Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

Gerald P. Huffman

2005-03-31T23:59:59.000Z

364

C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN  

DOE Green Energy (OSTI)

Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

Gerald P. Huffman

2004-03-31T23:59:59.000Z

365

CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS  

E-Print Network (OSTI)

Silicides, Phosphides Molten Salts WC, PtZnC; Fe N, Ni N ,priority rating to molten Molten salts have demonstratedcatalyst coal contac- ting. Molten salts have high thermal

Tanner, K.I.

2010-01-01T23:59:59.000Z

366

NETL: Gasification Systems - Liquid Carbon Dioxide/Coal Slurry...  

NLE Websites -- All DOE Office Websites (Extended Search)

and storage (CCS) for future coal-based power plants, and in a CCS integrated gasification plant, relatively pure, high pressure CO2 stream(s) will be available within the...

367

Renewable wood fuel: Fuel feed system for a pulverized coal boiler. Final report  

DOE Green Energy (OSTI)

This report evaluates a pilot test program conducted by New York State Gas & Electric Corporation to evaluate the feasibility of co-firing a pulverized coal plant with renewable wood fuels. The goal was to establish that such a co-firing system can reduce air emissions while maintaining good operational procedures and cost controls. The test fuel feed system employed at Greenidge Station`s Boiler 6 was shown to be effective in feeding wood products. Emission results were promising and an economic analysis indicates that it will be beneficial to pursue further refinements to the equipment and systems. The report recommends further evaluation of the generation and emission impacts using woods of varied moisture contents and at varied Btu input rates to determine if a drying system would be a cost-effective option.

NONE

1996-01-01T23:59:59.000Z

368

Energy Perspectives: For most fuel sources, domestic ...  

U.S. Energy Information Administration (EIA)

More than three-quarters of this energy production came from nonrenewable fossil fuels: coal, natural gas, crude oil, and natural gas plant liquids.

369

Characterization of coal-water slurry fuel sprays generated by an electronically-controlled accumulator fuel injector  

E-Print Network (OSTI)

Experiments have been completed to characterize coal-water slurry sprays generated by an electronically-controlled accumulator fuel injection system for a diesel engine. The sprays were injected into a pressurized chamber equipped with quartz windows. High speed movies, detailed data for fuel line pressures and needle lift signals were obtained as a function of time, orifice diameter, coal loading, gas density in the chamber, and accumulator fuel pressure. For the base case conditions (50% by mass) coal loading, 0.4 mm diameter nozzle hole, coal-water slurry pressure of 82 MPa (12,000 psi), and a chamber density of 25 kg/m'), the break-up time was 0.30 msec. An empirical correlation for both spray tip penetration and initial jet velocity was developed. For the base case conditions, the spray tip penetration and initial jet velocity were 15% greater for coal water slurry than for diesel fuel or water. Results of this research and the correlation are specific to the tested coal-water slurry.

Payne, Stephen Ellis

1993-01-01T23:59:59.000Z

370

Technical and Economic Evaluation of Coal Tar Dense Non-Aqueous Phase Liquid (DNAPL) Pumping Techniques  

Science Conference Proceedings (OSTI)

The utility industry has become aware of potential environmental issues at some sites resulting from process residues or byproducts at former manufactured gas plant (MGP) sites. One of the greatest challenges utility managers face in the management of these sites is the subsurface presence of coal tar, dense-non aqueous phase liquid (DNAPL). This report, which explores the technical feasibility and life cycle costs for several coal tar DNAPL pumping alternatives, is intended to assist utilities in evalua...

2000-03-07T23:59:59.000Z

371

Advanced turbine design for coal-fueled engines  

SciTech Connect

The investigators conclude that: (1) Turbine erosion resistance was shown to be improved by a factor of 5 by varying the turbine design. Increasing the number of stages and increasing the mean radius reduces the peak predicted erosion rates for 2-D flows on the blade airfoil from values which are 6 times those of the vane to values of erosion which are comparable to those of the vane airfoils. (2) Turbine erosion was a strong function of airfoil shape depending on particle diameter. Different airfoil shapes for the same turbine operating condition resulted in a factor of 7 change in airfoil erosion for the smallest particles studied (5 micron). (3) Predicted erosion for the various turbines analyzed was a strong function of particle diameter and weaker function of particle density. (4) Three dimensional secondary flows were shown to cause increases in peak and average erosion on the vane and blade airfoils. Additionally, the interblade secondary flows and stationary outer case caused unique erosion patterns which were not obtainable with 2-D analyses. (5) Analysis of the results indicate that hot gas cleanup systems are necessary to achieve acceptable turbine life in direct-fired, coal-fueled systems. In addition, serious consequences arise when hot gas filter systems fail for even short time periods. For a complete failure of the filter system, a 0.030 in. thick corrosion-resistant protective coating on a turbine blade would be eroded at some locations within eight minutes.

Wagner, J.H.; Johnson, B.V.

1993-04-01T23:59:59.000Z

372

Coal liquefaction process wherein jet fuel, diesel fuel and/or ASTM No. 2 fuel oil is recovered  

DOE Patents (OSTI)

An improved process for the liquefaction of coal and similar solid carbonaceous materials wherein a hydrogen donor solvent or diluent derived from the solid carbonaceous material is used to form a slurry of the solid carbonaceous material and wherein the naphthenic components from the solvent or diluent fraction are separated and used as jet fuel components. The extraction increases the relative concentration of hydroaromatic (hydrogen donor) components and as a result reduces the gas yield during liquefaction and decreases hydrogen consumption during said liquefaction. The hydrogenation severity can be controlled to increase the yield of naphthenic components and hence the yield of jet fuel and in a preferred embodiment jet fuel yield is maximized while at the same time maintaining solvent balance.

Bauman, Richard F. (Houston, TX); Ryan, Daniel F. (Friendswood, TX)

1982-01-01T23:59:59.000Z

373

Transportation costs for new fuel forms produced from low rank US coals  

DOE Green Energy (OSTI)

Transportation costs are examined for four types of new fuel forms (solid, syncrude, methanol, and slurry) produced from low rank coals found in the lower 48 states of the USA. Nine low rank coal deposits are considered as possible feedstocks for mine mouth processing plants. Transportation modes analyzed include ship/barge, pipelines, rail, and truck. The largest potential market for the new fuel forms is coal-fired utility boilers without emission controls. Lowest cost routes from each of the nine source regions to supply this market are determined. 12 figs.

Newcombe, R.J.; McKelvey, D.G. (TMS, Inc., Germantown, MD (USA)); Ruether, J.A. (USDOE Pittsburgh Energy Technology Center, PA (USA))

1990-09-01T23:59:59.000Z

374

Coal liquefaction process  

DOE Patents (OSTI)

This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

Skinner, Ronald W. (Allentown, PA); Tao, John C. (Perkiomenville, PA); Znaimer, Samuel (Vancouver, CA)

1985-01-01T23:59:59.000Z

375

Coal-to-Liquids in the U S Status and Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

to-Liquids in the United States to-Liquids in the United States Status and Roadmap CTLtec Americas 2008 June 23 - 24, 2008 Daniel C. Cicero, Technology Manager, Hydrogen and Syngas National Energy Technology Laboratory CTL Tec Americas 2008 / Daniel Cicero / U.S. DOE-NETL / June 2008 * 35% of world energy consumption is from oil 2 * 96% of all world oil used for transportation * World vehicle population at 700 million; - double by 2030 to 1.5 billion; - developing countries to triple * World oil consumption is 84 MMBPD - 20% higher than 1995 - expect 120 MMBPD by 2030 * World oil supplies could peak between 2016 and 2037 3 * Increasing competition with China, India, and other growing nations for oil resources * Oil resources not equitably distributed globally; coal more wide spread 2 Ref: World Coal Institute Report "Coal-to-Liquids"

376

Molecular catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids.  

Science Conference Proceedings (OSTI)

This report presents the results of research on the development of new catalytic pathways for the hydrogenation of multiring aromatic hydrocarbons and the hydrotreating of coal liquids at The University of Chicago under DOE Contract No. DE-AC22-91PC91056. The work, which is described in three parts, is primarily concerned with the research on the development of new catalytic systems for the hydrogenation of aromatic hydrocarbons and for the improvement of the quality of coal liquids by the addition of dihydrogen. Part A discusses the activation of dihydrogen by very basic molecular reagents to form adducts that can facilitate the reduction of multiring aromatic hydrocarbons. Part B examines the hydrotreating of coal liquids catalyzed by the same base-activated dihydrogen complexes. Part C concerns studies of molecular organometallic catalysts for the hydrogenation of monocyclic aromatic hydrocarbons under mild conditions.

Yang, Shiyong; Stock, L.M.

1996-05-01T23:59:59.000Z

377

Enhanced conversion of syngas to liquid motor fuels  

DOE Green Energy (OSTI)

Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

Coughlin, Peter K. (Yorktown Heights, NY); Rabo, Jule A. (Armonk, NY)

1986-01-01T23:59:59.000Z

378

Enhanced catalyst for conversion of syngas to liquid motor fuels  

DOE Patents (OSTI)

Synthesis gas comprising carbon monoxide and hydrogen is converted to C[sub 5][sup +] hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising a SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

Coughlin, P.K.; Rabo, J.A.

1985-12-03T23:59:59.000Z

379

Enhanced catalyst for conversion of syngas to liquid motor fuels  

DOE Patents (OSTI)

Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

Coughlin, Peter K. (Yorktown Heights, NY); Rabo, Jule A. (Armonk, NY)

1985-01-01T23:59:59.000Z

380

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

DOE Green Energy (OSTI)

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991  

SciTech Connect

Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

1991-07-01T23:59:59.000Z

382

Liquid-fueled SOFC power sources for transportation  

DOE Green Energy (OSTI)

Traditionally, fuel cells have been developed for space or stationary terrestrial applications. As the first commercial 200-kW systems were being introduced by ONSI and Fuji Electric, the potentially much larger, but also more challenging, application in transportation was beginning to be addressed. As a result, fuel cell-powered buses have been designed and built, and R&D programs for fuel cell-powered passenger cars have been initiated. The engineering challenge of eventually replacing the internal combustion engine in buses, trucks, and passenger cars with fuel cell systems is to achieve much higher power densities and much lower costs than obtainable in systems designed for stationary applications. At present, the leading fuel cell candidate for transportation applications is, without question, the polymer electrolyte fuel cell (PEFC). Offering ambient temperature start-up and the potential for a relatively high power density, the polymer technology has attracted the interest of automotive manufacturers worldwide. But the difficulties of fuel handling for the PEFC have led to a growing interest in exploring the prospects for solid oxide fuel cells (SOFCs) operating on liquid fuels for transportation applications. Solid oxide fuel cells are much more compatible with liquid fuels (methanol or other hydrocarbons) and are potentially capable of power densities high enough for vehicular use. Two SOFC options for such use are discussed in this report.

Myles, K.M.; Doshi, R.; Kumar, R.; Krumpelt, M.

1994-11-01T23:59:59.000Z

383

Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 9, April--June 1991  

Science Conference Proceedings (OSTI)

The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. During the second quarter of 1991, the following technical progress was made: completed drop tube furnace devolatilization tests of the spherical oil agglomeration beneficiated products; continued analyses of samples to determine devolatilization kinetics; continued analyses of the data and samples from the CE pilot-scale tests of nine fuels; completed writing a summary topical report including all results to date on he nine fuels tested; and presented three technical papers on the project results at the 16th International Conference on Coal & Slurry Technologies.

Chow, O.K.; Nsakala, N.Y.

1991-08-01T23:59:59.000Z

384

Proceedings: Conference on Coal Gasification Systems and Synthetic Fuels for Power Generation, Volumes 1 and 2  

Science Conference Proceedings (OSTI)

The international effort to develop synthetic fuels and advanced power systems for the commercial generation of electric power from coal, oil shale, and tar sands has been an outstanding technical success. This conference highlighted the work that brought new fuels and power generation systems to reality.

1986-01-01T23:59:59.000Z

385

Major, minor and trace elements in direct coal liquefaction: effect on conversion and partitioning behavior.  

E-Print Network (OSTI)

??With current concerns of depleting oil sources and the environmental impacts of off-shore drilling, the interest in liquid transportation fuels derived from coal is increasing. (more)

Luchner, Sarah

2010-01-01T23:59:59.000Z

386

CO-FIRING COAL, FEEDLOT, AND LITTER BIOMASS (CFB AND LFB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS  

DOE Green Energy (OSTI)

Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. In this project a co-firing technology is proposed which would use manure that cannot be used for fertilizer, for power generation. Since the animal manure has economic uses as both a fertilizer and as a fuel, it is properly referred to as feedlot biomass (FB) for cow manure, or litter biomass (LB) for chicken manure. The biomass will be used a as a fuel by mixing it with coal in a 90:10 blend and firing it in existing coal fired combustion devices. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Therefore, it is the goal of the current research to develop an animal biomass cofiring technology. A cofiring technology is being developed by performing: (1) studies on fundamental fuel characteristics, (2) small scale boiler burner experiments, (3) gasifier experiments, (4) computer simulations, and (5) an economic analysis. The fundamental fuel studies reveal that biomass is not as high a quality fuel as coal. The biomass fuels are higher in ash, higher in moisture, higher in nitrogen and sulfur (which can cause air pollution), and lower in heat content than coal. Additionally, experiments indicate that the biomass fuels have higher gas content, release gases more readily than coal, and less homogeneous. Small-scale boiler experiments revealed that the biomass blends can be successfully fired, and NO{sub x} pollutant emissions produced will be similar to or lower than pollutant emissions when firing coal. This is a surprising result as the levels of N are higher in the biomass fuel than in coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process to reduce NO{sub x} emissions. Since crushing costs of biomass fuels may be prohibitive, stoker firing may be cost effective; in order simulate such a firing, future work will investigate the performance of a gasifier when fired with larger sized coal and biomass. It will be a fixed bed gasifier, and will evaluate blends, coal, and biomass. Computer simulations were performed using the PCGC-2 code supplied by BYU and modified by A&M with three mixture fractions for handling animal based biomass fuels in order to include an improved moisture model for handling wet fuels and phosphorus oxidation. Finally the results of the economic analysis show that considerable savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings will be reduced, due to increased transportation costs. A spreadsheet program was created to analyze the fuel savings for a variety of different moisture levels, ash levels, and power plant operating parameters.

Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thien; Gengsheng Wei; Soyuz Priyadarsan

2002-01-15T23:59:59.000Z

387

Refinery Integration of By-Products from Coal-Derived Jet Fuels  

SciTech Connect

The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler designed for natural gas/fuel oil, and determining the boiler performance when firing the five fuels. Two

Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2008-03-31T23:59:59.000Z

388

Study breaks tenuous truce in coal, gas fuel war  

Science Conference Proceedings (OSTI)

The long-simmering battle between the coal and gas industries for market share in the electric generation market heated up again last week with the release of a report by Energy Ventures Analysis showing that baseload coal-fired plants will cost at least 22 percent less than power from baseload gas plants after 2000.

Kaplan, D.

1994-06-03T23:59:59.000Z

389

Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 18, July--September 1993  

Science Conference Proceedings (OSTI)

The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1993, the following technical progress was made: Continued with data and sample analysis from the pilot-scale tests of Upper Freeport feed coal, air-dried and mulled microagglomerate products; air-dried Pittsburgh No. 8 as-is and mulled products for upcoming Task 3 combustion testing; and prepared two abstracts for presentation for the March 1 994 Coal Utilization and Fuel Systems Conference.

Chow, O.K.; Hargrove, M.J.

1993-11-01T23:59:59.000Z

390

Effect of Coal Contaminants on Solid Oxide Fuel System Performance and Service Life  

DOE Green Energy (OSTI)

The U.S. Department of Energy's SECA program envisions the development of high-efficiency, low-emission, CO{sub 2} sequestration-ready, and fuel-flexible technology to produce electricity from fossil fuels. One such technology is the integrated gasification-solid oxide fuel cell (SOFC) that produces electricity from the gas stream of a coal gasifier. SOFCs have high fuel-to-electricity conversion efficiency, environmental compatibility (low NO{sub x} production), and modularity. Naturally occurring coal has many impurities and some of these impurities end in the fuel gas stream either as a vapor or in the form of fine particulate matter. Establishing the tolerance limits of SOFCs for contaminants in the coal-derived gas will allow proper design of the fuel feed system that will not catastrophically damage the SOFC or allow long-term cumulative degradation. The anodes of Ni-cermet-based SOFCs are vulnerable to degradation in the presence of contaminants that are expected to be present in a coal-derived fuel gas stream. Whereas the effects of some contaminants such as H{sub 2}S, NH{sub 3} and HCl have been studied, the effects of other contaminants such as As, P, and Hg have not been ascertained. The primary objective of this study was to determine the sensitivity of the performance of solid oxide fuel cells to trace level contaminants present in a coal-derived gas stream in the temperature range 700 to 900 C. The results were used to assess catastrophic damage risk and long-term cumulative effects of the trace contaminants on the lifetime expectancy of SOFC systems fed with coal-derived gas streams.

Gopala Krishnan; P. Jayaweera; J. Bao; J. Perez; K. H. Lau; M. Hornbostel; A. Sanjurjo; J. R. Albritton; R. P. Gupta

2008-09-30T23:59:59.000Z

391

Effects of coal-derived trace species on performance of molten carbonate fuel cells. Final report  

DOE Green Energy (OSTI)

The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

Not Available

1992-05-01T23:59:59.000Z

392

Effects of coal-derived trace species on performance of molten carbonate fuel cells  

DOE Green Energy (OSTI)

The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

Not Available

1992-05-01T23:59:59.000Z

393

Coal....  

U.S. Energy Information Administration (EIA)

DOE EIA WEEKLY COAL ... Coal Prices and Earnings (updated July 7, 2004) In the trading week ended July 2, the average spot coal prices tracked by EIA were mixed.

394

Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 8, January--March 1991  

Science Conference Proceedings (OSTI)

The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coa1 (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. During the third quarter of 1991, the following technical progress was made: Calculated the kinetic characteristics of chars from the combustion of spherical oil agglomeration beneficiated products; continued drop tube devolatilization tests of the spherical oil agglomeration beneficiated products; continued analyses of the data and samples from the CE pilot-scale tests of nine fuels; and started writing a summary topical report to include all results on the nine fuels tested.

Chow, O.K.; Nsakala, N.Y.

1991-07-01T23:59:59.000Z

395

Bioprocessing of lignite coals using reductive microorganisms  

Science Conference Proceedings (OSTI)

In order to convert lignite coals into liquid fuels, gases or chemical feedstock, the macromolecular structure of the coal must be broken down into low molecular weight fractions prior to further modification. Our research focused on this aspect of coal bioprocessing. We isolated, characterized and studied the lignite coal-depolymerizing organisms Streptomyces viridosporus T7A, Pseudomonas sp. DLC-62, unidentified bacterial strain DLC-BB2 and Gram-positive Bacillus megaterium strain DLC-21. In this research we showed that these bacteria are able to solubilize and depolymerize lignite coals using a combination of biological mechanisms including the excretion of coal solublizing basic chemical metabolites and extracellular coal depolymerizing enzymes.

Crawford, D.L.

1992-03-29T23:59:59.000Z

396

Wiang Haeng coal-water fuel preparation and gasification, Thailand - task 39  

Science Conference Proceedings (OSTI)

In response to an inquiry by the Department of Mineral Resources (DMR) in Thailand, the Energy & Environmental Research Center (EERC) prepared a four-task program to assess the responsiveness of Wiang Haeng coal to the temperature and pressure conditions of hot-water drying (HWD). The results indicate that HWD made several improvements in the coal, notably increases (HWD). The results indicate that HWD made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 37.4 wt% for the raw coal to about 20 wt% for the HWD coals. The energy density for a pumpable coal-water fuel indicates an increase from 4450 to 6650 Btu/lb by hydrothermal treatment. Raw and HWD coal were then gasified at various mild gasification conditions of 700{degrees}C and 30 psig. The tests indicated that the coal is probably similar to other low-rank coals, will produce high levels of hydrogen, and be fairly reactive.

Anderson, C.M.; Musich, M.A.; Young, B.C. [and others

1996-07-01T23:59:59.000Z

397

NETL: Clean Coal Demonstrations - Coal 101  

NLE Websites -- All DOE Office Websites (Extended Search)

Clean Coal 101 Lesson 1: Cleaning Up Coal Clean Coal COAL is our most abundant fossil fuel. The United States has more coal than the rest of the world has oil. There is still...

398

EA-1850: Flambeau River BioFuels, Inc. Proposed Wood Biomass-to-Liquid Fuel  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

50: Flambeau River BioFuels, Inc. Proposed Wood 50: Flambeau River BioFuels, Inc. Proposed Wood Biomass-to-Liquid Fuel Biorefinery, Park Falls, Wisconsin EA-1850: Flambeau River BioFuels, Inc. Proposed Wood Biomass-to-Liquid Fuel Biorefinery, Park Falls, Wisconsin Summary NOTE: This EA has been cancelled. This EA will evaluate the environmental impacts of a proposal to provide federal funding to Flambeau River Biofuels (FRB) to construct and operate a biomass-to-liquid biorefinery in Park Falls, Wisconsin, on property currently used by Flambeau Rivers Paper, LLC (FRP) for a pulp and paper mill and Johnson Timber Corporation's (JTC) Summit Lake Yard for timber storage. This project would design a biorefinery which would produce up to 1,150 barrels per day (bpd) of clean syncrude. The biorefinery would also supply

399

Liquid fuel reformer development: Autothermal reforming of Diesel fuel  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing a process to convert hydrocarbon fuels to clean hydrogen feeds for a polymer electrolyte fuel cell. The process incorporates an autothermal reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. The authors have tested the catalyst with three diesel-type fuels: hexadecane, certified low-sulfur grade 1 diesel, and a standard grade 2 diesel. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 850 C, while maximum hydrogen product yields for the two diesel fuels were near 50%. Residual products in all cases included CO, CO{sub 2}, ethane, and methane. Further studies with grade 1 diesel showed improved conversion as the water:fuel ratio was increased from 1 to 2 at 850 C. Soot formation was reduced when the oxygen:carbon ratio was maintained at 1 at 850 C. There were no significant changes in hydrogen yield as the space velocity and the oxygen:fuel ratio were varied. Tests with a microchannel monolithic catalyst yielded similar or improved hydrogen levels at higher space velocities than with extruded pellets in a packed bed.

Pereira, C.; Bae, J-M.; Ahmed, S.; Krumpelt, M.

2000-07-24T23:59:59.000Z

400

High-pressure coal fuel processor development. Task 1, Proof of principle testing  

DOE Green Energy (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid fuels coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

EA-1642S: Small-Scale Pilot Plant for the Gasification of Coal...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

642S: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY...

402

C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen  

DOE Green Energy (OSTI)

Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the first six months of the subject contract (DE-FC26-02NT-4159), from October 1, 2002 through March 31, 2003.

Gerald P. Huffman

2003-03-31T23:59:59.000Z

403

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

DOE Green Energy (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the sixth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2005. This quarter saw progress in four areas. These areas are: (1) Autothermal reforming of coal derived methanol, (2) Catalyst deactivation, (3) Steam reformer transient response, and (4) Catalyst degradation with bluff bodies. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2005-04-01T23:59:59.000Z

404

Residential coal use: 1982 international solid fuel trade show and conference Atlantic City, New Jersey. [USA; 1974; By state  

Science Conference Proceedings (OSTI)

The US Department of Energy's anthracite and residential coal programs are described. The residential coal effort is an outgrowth and extension of the anthracite program, which has been, and continues to be, involved in promoting increased production and use of anthracite and the restoration of anthracite as a viable economic alternative to soft coals and to imported oil and gas now supplying the Northeast. Since anthracite is a preferred fuel for residential heating, residential coal issues comprise an important part of our anthracite activities. We have commenced a study of residential coal utilization including: overview of the residential coal market; market potential for residential coal use; analysis of the state of technology, economics, constraints to increased use of coal and coal-based fuels in residential markets, and identification of research and development activities which would serve to increase the market potential for coal-fired residential systems. A considerable amount of information is given in this report on residential coal furnaces and coal usage in 1974, prices of heating oils and coal, methods of comparing these fuels (economics), air pollution, safety, wood and wood furnaces, regulations, etc.

Pell, J.

1982-06-01T23:59:59.000Z

405

Micronized-coal-water slurry sprays from a diesel engine positive displacement fuel injection system  

DOE Green Energy (OSTI)

Experiments have been conducted to characterize the sprays from a modified positive displacement fuel injection system for a diesel engine. Diesel fuel water and three concentrations of micronized-coal-water slurry were used in these experiments. The injection system includes an injection jerk pump driven by an electric motor, a specially designed diaphragm to separate the abrasive coal slurry fuel from the pump, and a single-hole fuel nozzle. The sprays were injected into a pressurized chamber equipped with windows. High speed movies and still photographs of the sprays were obtained. In addition, instaneous fuel line pressures and needle lifts were obtained. Data were acquired as a function of fluid, nozzle orifice diameter, rack setting and chamber conditions. The high speed movies were used to determine spray penetration and spray growth.

Caton, J.A.; Kihm, K.D.; Seshadri, A.K.; Zicterman, G. [Texas A and M Univ., College Station, TX (United States). Dept. of Mechanical Engineering

1991-12-31T23:59:59.000Z

406

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the third report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 30, 2004. This quarter saw progress in five areas. These areas are: (1) External evaluation of coal based methanol and the fuel cell grade baseline fuel, (2) Design, set up and initial testing of the autothermal reactor, (3) Experiments to determine the axial and radial thermal profiles of the steam reformers, (4) Catalyst degradation studies, and (5) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-06-30T23:59:59.000Z

407

Advanced coal fueled industrial cogeneration gas turbine system. Final report, June 1986--April 1994  

SciTech Connect

Demonstration of a direct coal-fueled gas turbine system that is environmentally, technically, and economically viable depends on the satisfactory resolution of several key issues. Solar Turbines, Incorporates technical approach to these issues was to advance a complete direct coal-fueled gas turbine system that incorporated near-term technology solutions to both historically demonstrated problem areas such as deposition, erosion, and hot end corrosion, and to the emergent environmental constraints based on NO{sub x}, SO{sub x}, and particulates. Solar`s program approach was keyed to the full commercialization of the coal-fueled cogeneration gas turbine which would occur after extended field verification demonstrations conducted by the private sector. The program was structured in three phases plus an optional fourth phase: Phase 1 -- system description; Phase 2 -- component development; Phase 3 -- prototype system verification; and Phase 4 -- field evaluation.

LeCren, R.T.

1994-05-01T23:59:59.000Z