National Library of Energy BETA

Sample records for liquid crystal displays

  1. Recovery of valuable materials from waste liquid crystal display panel

    SciTech Connect (OSTI)

    Li Jinhui Gao Song; Duan Huabo; Liu Lili

    2009-07-15

    Associated with the rapid development of the information and electronic industry, liquid crystal displays (LCDs) have been increasingly sold as displays. However, during the discarding at their end-of-life stage, significant environmental hazards, impacts on health and a loss of resources may occur, if the scraps are not managed in an appropriate way. In order to improve the efficiency of the recovery of valuable materials from waste LCDs panel in an environmentally sound manner, this study presents a combined recycling technology process on the basis of manual dismantling and chemical treatment of LCDs. Three key processes of this technology have been studied, including the separation of LCD polarizing film by thermal shock method the removal of liquid crystals between the glass substrates by the ultrasonic cleaning, and the recovery of indium metal from glass by dissolution. The results show that valuable materials (e.g. indium) and harmful substances (e.g. liquid crystals) could be efficiently recovered or separated through above-mentioned combined technology. The optimal conditions are: (1) the peak temperature of thermal shock to separate polarizing film, ranges from 230 to 240 deg. C, where pyrolysis could be avoided; (2) the ultrasonic-assisted cleaning was most efficient at a frequency of 40 KHz (P = 40 W) and the exposure of the substrate to industrial detergents for 10 min; and (3) indium separation from glass in a mix of concentrated hydrochloric acid at 38% and nitric acid at 69% (HCl:HNO{sub 3}:H{sub 2}O = 45:5:50, volume ratio). The indium separation process was conducted with an exposure time of 30 min at a constant temperature of 60 deg. C.

  2. Development of Polymer Cholesteric Liquid Crystal Flake Technology for Electro-Optic Devices and Particle Displays

    SciTech Connect (OSTI)

    Kosc, T.Z.; Marshall, K.L.; Trajkovska-Petkoska, A.; Coon, C.J.; Hasman, K.; Babcock, G.V.; Howe, R.; Leitch, M.; Jacobs, S.J.

    2007-04-05

    Liquid crystals have had a large presence in the display industry for several decades, and they continue to remain at the forefront of development as the industry delves into flexible displays and electronic paper. Among the emerging technologies trying to answer this call are polymer cholesteric liquid crystal (PCLC) flakes.

  3. Plastic substrates for active matrix liquid crystal display incapable of withstanding processing temperature of over 200.degree. C and method of fabrication

    DOE Patents [OSTI]

    Carey, Paul G.; Smith, Patrick M.; Havens, John; Jones, Phil

    1999-01-01

    Bright-polarizer-free, active-matrix liquid crystal displays (AMLCDs) are formed on plastic substrates. The primary components of the display are a pixel circuit fabricated on one plastic substrate, an intervening liquid-crystal material, and a counter electrode on a second plastic substrate. The-pixel circuit contains one or more thin-film transistors (TFTs) and either a transparent or reflective pixel electrode manufactured at sufficiently low temperatures to avoid damage to the plastic substrate. Fabrication of the TFTs can be carried out at temperatures less than 100.degree. C. The liquid crystal material is a commercially made nematic curvilinear aligned phase (NCAP) film. The counter electrode is comprised of a plastic substrate coated with a transparent conductor, such as indium-doped tin oxide (ITO). By coupling the active matrix with NCAP, a high-information content can be provided in a bright, fully plastic package. Applications include any low cost portable electronics containing flat displays where ruggedization of the display is desired.

  4. Plastic substrates for active matrix liquid crystal display incapable of withstanding processing temperature of over 200 C and method of fabrication

    DOE Patents [OSTI]

    Carey, P.G.; Smith, P.M.; Havens, J.H.; Jones, P.

    1999-01-05

    Bright-polarizer-free, active-matrix liquid crystal displays (AMLCDs) are formed on plastic substrates. The primary components of the display are a pixel circuit fabricated on one plastic substrate, an intervening liquid-crystal material, and a counter electrode on a second plastic substrate. The-pixel circuit contains one or more thin-film transistors (TFTs) and either a transparent or reflective pixel electrode manufactured at sufficiently low temperatures to avoid damage to the plastic substrate. Fabrication of the TFTs can be carried out at temperatures less than 100 C. The liquid crystal material is a commercially made nematic curvilinear aligned phase (NCAP) film. The counter electrode is comprised of a plastic substrate coated with a transparent conductor, such as indium-doped tin oxide (ITO). By coupling the active matrix with NCAP, a high-information content can be provided in a bright, fully plastic package. Applications include any low cost portable electronics containing flat displays where ruggedization of the display is desired. 12 figs.

  5. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  6. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  7. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  8. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Watching a Liquid-Crystal Helix Unwind Print Wednesday, 09 December 2015 00:00 Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can

  9. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Watching a Liquid-Crystal Helix Unwind Print Liquid crystals have many versatile applications but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting in

  10. Liquid Crystal Optofluidics

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

    2012-10-11

    By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

  11. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    but are best known for the liquid-crystal displays that drive the billion-dollar smartphone and flat-screen industries. Chirality, the absence of inversion symmetry, plays an...

  12. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the equilibrium state usually observed in liquid crystals, resulting...

  13. Adaptive Liquid Crystal Windows

    SciTech Connect (OSTI)

    Taheri, Bahman; Bodnar, Volodymyr

    2011-12-31

    Energy consumption by private and commercial sectors in the U.S. has steadily grown over the last decade. The uncertainty in future availability of imported oil, on which the energy consumption relies strongly, resulted in a dramatic increase in the cost of energy. About 20% of this consumption are used to heat and cool houses and commercial buildings. To reduce dependence on the foreign oil and cut down emission of greenhouse gases, it is necessary to eliminate losses and reduce total energy consumption by buildings. To achieve this goal it is necessary to redefine the role of the conventional windows. At a minimum, windows should stop being a source for energy loss. Ideally, windows should become a source of energy, providing net gain to reduce energy used to heat and cool homes. It is possible to have a net energy gain from a window if its light transmission can be dynamically altered, ideally electronically without the need of operator assistance, providing optimal control of the solar gain that varies with season and climate in the U.S. In addition, the window must not require power from the building for operation. Resolution of this problem is a societal challenge and of national interest and will have a broad global impact. For this purpose, the year-round, allclimate window solution to provide an electronically variable solar heat gain coefficient (SHGC) with a wide dynamic range is needed. AlphaMicron, Inc. (AMI) developed and manufactured 1ft 1ft prototype panels for the worlds first auto-adjusting Adaptive Liquid Crystal Windows (ALCWs) that can operate from sunlight without the need for external power source and demonstrate an electronically adjustable SHGC. This novel windows are based on AlphaMicrons patented e-Tint technology, a guesthost liquid crystal system implemented on flexible, optically clear plastic films. This technology is suitable both for OEM and aftermarket (retro-fitting) lamination to new and existing windows. Low level of power

  14. Liquid crystal polyester thermosets

    DOE Patents [OSTI]

    Benicewicz, Brian C.; Hoyt, Andrea E.

    1992-01-01

    The present invention provides (1) curable liquid crystalline polyester monomers represented by the formula: R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2 where R.sup.1 and R.sup.2 are radicals selected from the group consisting of maleimide, substituted maleimide, nadimide, substituted naimide, ethynyl, and (C(R.sup.3).sub.2).sub.2 where R.sup.3 is hydrogen with the proviso that the two carbon atoms of (C(R.sup.3).sub.2).sub.2 are bound on the aromatic ring of A.sup.1 or A.sup.3 to adjacent carbon atoms, A.sup.1 and A.sup.3 are 1,4-phenylene and the same where said group contains one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro lower alkyl, e.g., methyl, ethyl, or propyl, alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl, e.g., trifluoromethyl, pentafluoroethyl and the like, A.sup.2 is selected from the group consisting of 1,4-phenylene, 4,4'-biphenyl, 2,6-naphthylene and the same where said groups contain one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro, lower alkyl, e.g., methyl, ethyl, and propyl, lower alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl or fluoroalkoxy, e.g., trifluoromethyl, pentafluoroethyl and the like, and B.sup.1 and B.sup.2 are selected from the group consisting of --C(O)--O-- and --O--C(O)--, (2) thermoset liquid crystalline polyester compositions comprised of heat-cured segments derived from monomers represented by the formula: R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2 as described above, (3) curable blends of at least two of the polyester monomers and (4) processes of preparing the curable liquid crystalline polyester monomers.

  15. Bent core liquid crystal elastomers

    SciTech Connect (OSTI)

    Verduzco, R.; DiMasi, E.; Luchette, P.; Ho Hong, S.; Harden, J.; Palffy-Muhoray, P.; Kilbey II, S.M.; Sprunt, S.; Gleeson, G.T. Jakli, A.

    2010-07-28

    Liquid crystal (LC) elastomers with bent-core side-groups incorporate the properties of bent-core liquid crystals in a flexible and self-supporting polymer network. Bent-core liquid crystal elastomers (BCEs) with uniform alignment were prepared by attaching a reactive bent-core LC to poly(hydrogenmethylsiloxane) and crosslinking with a divinyl crosslinker. Phase behavior studies indicate a nematic phase over a wide temperature range that approaches room temperature, and thermoelastic measurements show that these BCEs can reversibly change their length by more than a factor of two upon heating and cooling. Small-angle X-ray scattering studies reveal multiple, broad low-angle peaks consistent with short-range smectic C order of the bent-core side groups. A comparison of these patterns with predictions of a Landau model for short-range smectic C order shows that the length scale for smectic ordering in BCEs is similar to that seen in pure bent-core LCs. The combination of rubber elasticity and smectic ordering of the bent-core side groups suggests that BCEs may be promising materials for sensing, actuating, and other advanced applications.

  16. Nanoscopic Manipulation and Imaging of Liquid Crystals

    SciTech Connect (OSTI)

    Rosenblatt, Charles S.

    2014-02-04

    This is the final project report. The project’s goals centered on nanoscopic imaging and control of liquid crystals and surfaces. We developed and refined techniques to control liquid crystal orientation at surfaces with resolution as small as 25 nm, we developed an optical imaging technique that we call Optical Nanotomography that allows us to obtain images inside liquid crystal films with resolution of 60 x 60 x 1 nm, and we opened new thrust areas related to chirality and to liquid crystal/colloid composites.

  17. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may lead to a twisting force that can modify the...

  18. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chirality, the absence of inversion symmetry, plays an important role in chemistry, biology, and materials science. Introducing molecular chirality into a liquid crystal may...

  19. Liquid crystal-templated conducting organic polymers

    DOE Patents [OSTI]

    Stupp, Samuel I.; Hulvat, James F.

    2004-01-20

    A method of preparing a conductive polymeric film, includes providing a liquid crystal phase comprising a plurality of hydrophobic cores, the phase on a substrate, introducing a hydrophobic component to the phase, the component a conductive polymer precursor, and applying an electric potential across the liquid crystal phase, the potential sufficient to polymerize the said precursor.

  20. Liquid crystal device and method thereof

    DOE Patents [OSTI]

    Shiyanovskii, Sergij V; Gu, Mingxia; Lavrentovich, Oleg D

    2012-10-23

    The invention provides a liquid crystal device and method thereof. Subsequent to applying a first electrical voltage on a liquid crystal to induce a reorientation of the liquid crystal, a second electrical voltage with proper polarity is applied on the liquid crystal to assist the relaxation of the reorientation that was induced by the first electrical voltage. The "switch-off" phase of the liquid crystal can therefore be accelerated or temporally shortened, and the device can exhibit better performance such as fast response to on/off signals. The invention can be widely used LCD, LC shutter, LC lens, spatial light modulator, telecommunication device, tunable filter, beam steering device, and electrically driven LC device, among others.

  1. Photoluminescence analysis of self induced planer alignment in azo dye dispersed nematic liquid crystal complex

    SciTech Connect (OSTI)

    Kumar, Rishi Sood, Srishti Raina, K. K.

    2014-04-24

    We have developed azo dye doped nematic liquid crystal complex for advanced photonic liquid crystal display technology aspects. Disperse orange azo dye self introduced planer alignment in the nematic liquid crystal without any surface anchoring treatment. Planer alignment was characterized by optical polarizing microscopy. The electro-optical switching response of dye disperse planer aligned nematic cell was investigated as a function of applied voltage with the help of photoluminescence spectrophotometer for the tuning of photoluminescence contrast.

  2. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In a chiral liquid crystal, stacked molecular layers form a twist-a useful property in LCD technology. NOBOW transforms from the B4 (helical) phase to the B2 (flat) phase at 142...

  3. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of why the development, by Zhu et al., of a technique allowing direct measurement and control of liquid-crystal properties is important. The NOBOW molecular structure and a...

  4. Semiconductor liquid crystal composition and methods for making the same

    DOE Patents [OSTI]

    Alivisatos, A. Paul; Li, Liang-shi

    2005-04-26

    Semiconductor liquid crystal compositions and methods for making such compositions are disclosed. One embodiment of the invention is directed to a liquid crystal composition including a solvent and semiconductor particles in the solvent. The solvent and the semiconductor particles are in an effective amount in the liquid crystal composition to form a liquid crystal phase.

  5. LG Display | Open Energy Information

    Open Energy Info (EERE)

    Zip: 150-721 Product: Korea Republic-based manufacturer and merchant supplier of thin-film transistor liquid crystal displays. Manufacturer of thin-film PV. Coordinates:...

  6. Lyotropic Liquid Crystal (LLC) Nanofiltration Membranes - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Lyotropic Liquid Crystal (LLC) Nanofiltration Membranes Applications in biofuels and bio-process mixture separations University of Colorado Contact CU About This Technology Publications: PDF Document Publication CU2412B (Advanced LLC Membranes) Marketing Summary.pdf (154 KB) Lyotropic Liquid Crystal (LLC) Nanofiltration Membranes Lyotropic Liquid Crystal (LLC)

  7. Electric field effects in liquid crystals with dielectric dispersion

    SciTech Connect (OSTI)

    Lavrentovich, Oleg D.

    2014-11-29

    The project is focused on the experimental and theoretical exploration of the coupling of an externally applied electric field and a nematic liquid crystal.

  8. Pulsed zero field NMR of solids and liquid crystals

    SciTech Connect (OSTI)

    Thayer, A.M.

    1987-02-01

    This work describes the development and applications to solids and liquid crystals of zero field nuclear magnetic resonance (NMR) experiments with pulsed dc magnetic fields. Zero field NMR experiments are one approach for obtaining high resolution spectra of amorphous and polycrystalline materials which normally (in high field) display broad featureless spectra. The behavior of the spin system can be coherently manipulated and probed in zero field with dc magnetic field pulses which are employed in a similar manner to radiofrequency pulses in high field NMR experiments. Nematic phases of liquid crystalline systems are studied in order to observe the effects of the removal of an applied magnetic field on sample alignment and molecular order parameters. In nematic phases with positive and negative magnetic susceptibility anisotropies, a comparison between the forms of the spin interactions in high and low fields is made. High resolution zero field NMR spectra of unaligned smectic samples are also obtained and reflect the symmetry of the liquid crystalline environment. These experiments are a sensitive measure of the motionally induced asymmetry in biaxial phases. Homonuclear and heteronuclear solute spin systems are compared in the nematic and smectic phases. Nonaxially symmetric dipolar couplings are reported for several systems. The effects of residual fields in the presence of a non-zero asymmetry parameter are discussed theoretically and presented experimentally. Computer programs for simulations of these and other experimental results are also reported. 179 refs., 75 figs.

  9. Methods of making composite optical devices employing polymer liquid crystal

    DOE Patents [OSTI]

    Jacobs, Stephen D.; Marshall, Kenneth L.; Cerqua, Kathleen A.

    1991-01-01

    Composite optical devices using polymer liquid crystal materials both as optical and adhesive elements. The devices are made by assembling a heated polymer liquid crystal compound, while in a low viscosity form between optically transparent substrates. The molecules of the polymer are oriented, while in the liquid crystalline state and while above the glass transition temperature (T.sub.g) of the polymer, to provide the desired optical effects, such as polarization, and selective reflection. The liquid crystal polymer cements the substrates together to form an assembly providing the composite optical device.

  10. Methods of making composite optical devices employing polymer liquid crystal

    DOE Patents [OSTI]

    Jacobs, S.D.; Marshall, K.L.; Cerqua, K.A.

    1991-10-08

    Composite optical devices are disclosed using polymer liquid crystal materials both as optical and adhesive elements. The devices are made by assembling a heated polymer liquid crystal compound, while in a low viscosity form between optically transparent substrates. The molecules of the polymer are oriented, while in the liquid crystalline state and while above the glass transition temperature (T[sub g]) of the polymer, to provide the desired optical effects, such as polarization, and selective reflection. The liquid crystal polymer cements the substrates together to form an assembly providing the composite optical device. 7 figures.

  11. Liquid crystal devices especially for use in liquid crystal point diffraction interferometer systems

    DOE Patents [OSTI]

    Marshall, Kenneth L.

    2009-02-17

    Liquid crystal point diffraction interferometer (LCPDI) systems that can provide real-time, phase-shifting interferograms that are useful in the characterization of static optical properties (wavefront aberrations, lensing, or wedge) in optical elements or dynamic, time-resolved events (temperature fluctuations and gradients, motion) in physical systems use improved LCPDI cells that employ a "structured" substrate or substrates in which the structural features are produced by thin film deposition or photo resist processing to provide a diffractive element that is an integral part of the cell substrate(s). The LC material used in the device may be doped with a "contrast-compensated" mixture of positive and negative dichroic dyes.

  12. Flexoelectricity of a Calamitic Liquid Crystal Elastomer Swollen with a Bent-core Liquid Crystal

    SciTech Connect (OSTI)

    Chambers, M.; Verduzco, R; Gleeson, J; Sprunt, S; Jakli, A

    2009-01-01

    We have measured the electric current induced by mechanical distortion of a calamitic liquid crystal elastomer (LCE) swollen with a low molecular weight bent-core nematic (BCN) liquid crystal, and have determined, for the first time, the bend flexoelectric coefficient e{sub 3} of such a BCN-LCE composite. In one method, we utilize air-pressure to induce a mechanical bend deformation and flexoelectric polarization in a BCN-LCE film, and then measure the polarization current as a function of time. An alternative technique uses a rotary-motor driven scotch yoke to periodically flex the BCN-LCE; in this case, the magnitude and phase of the induced current are recorded via a lock-in amplifier. The flexoelectric coefficient, e{sub 3}, was found to be {approx}20 nC/cm{sup 2}, and is stable in magnitude from room temperature to {approx}65 C. It is about one third the value measured in samples of the pure BCN; this fraction corresponds closely to the molar concentration of BCN in the LCE. The flexoelectric current increases linearly with the magnitude of the bend deformation and decays with frequency. These observations indicate a promising way forward towards producing very low-cost, self-standing, rugged electromechanical energy conversion devices.

  13. Electro-optical and dielectric properties of CdSe quantum dots and 6CHBT liquid crystals composites

    SciTech Connect (OSTI)

    Singh, U. B.; Pandey, M. B.; Dhar, R; Pandey, A. S.; Kumar, S.; Dabrowski, R.

    2014-11-15

    We have prepared the composites of a room temperature nematic liquid crystal namely 4-(trans-4-n-hexylcyclohexyl) isothiocyanatobenzoate (6CHBT) and Cadmium Selenide Quantum Dots (CdSe-QDs) and investigated their electro-optical and dielectric properties. Effect of dispersion of CdSe-QDs on various electro-optical and display parameters of host liquid crystalline material have been studied. Physical parameters, such as switching threshold voltage and splay elastic constant have been altered drastically for composites. Dispersion of QDs in a liquid crystals medium destabilizes nematic ordering of the host and decreases the nematic-to-isotropic transition temperature.

  14. Defect topologies in chiral liquid crystals confined to mesoscopic channels

    SciTech Connect (OSTI)

    Schlotthauer, Sergej Skutnik, Robert A.; Stieger, Tillmann; Schoen, Martin

    2015-05-21

    We present Monte Carlo simulations in the grand canonical and canonical ensembles of a chiral liquid crystal confined to mesochannels of variable sizes and geometries. The mesochannels are taken to be quasi-infinite in one dimension but finite in the two other directions. Under thermodynamic conditions chosen and for a selected value of the chirality coupling constant, the bulk liquid crystal exhibits structural characteristics of a blue phase II. This is established through the tetrahedral symmetry of disclination lines and the characteristic simple-cubic arrangement of double-twist helices formed by the liquid-crystal molecules along all three axes of a Cartesian coordinate system. If the blue phase II is then exposed to confinement, the interplay between its helical structure, various anchoring conditions at the walls of the mesochannels, and the shape of the mesochannels gives rise to a broad variety of novel, qualitative disclination-line structures that are reported here for the first time.

  15. Gradient index liquid crystal devices and method of fabrication thereof

    DOE Patents [OSTI]

    Lee, J.C.; Jacobs, S.

    1991-10-29

    Laser beam apodizers using cholesteric liquid crystals provides soft edge profile by use of two separate cholesteric liquid crystal mixtures with different selective reflection bands which in an overlap region have a gradient index where reflectivity changes as a function of position. The apodizers can be configured as a one-dimensional beam apod INTRODUCTION The U.S. government has rights in the invention under Contract No. DE-FC03-85DP40200 between the University of Rochester and the Department of Energy.

  16. Gradient index liquid crystal devices and method of fabrication thereof

    DOE Patents [OSTI]

    Lee, Jae-Cheul; Jacobs, Stephen

    1991-01-01

    Laser beam apodizers using cholesteric liquid crystals provides soft edge profile by use of two separate cholesteric liquid crystal mixtures with different selective reflection bands which in an overlap region have a gradient index where reflectivity changes as a function of position. The apodizers can be configured as a one-dimensional beam apod INTRODUCTION The U.S. government has rights in the invention under Contract No. DE-FC03-85DP40200 between the University of Rochester and the Department of Energy.

  17. Polarization Studies of Resonant Forbidden Reflections in Liquid Crystals

    SciTech Connect (OSTI)

    Fernandes, P.; Barois, P.; Nguyen, H. T.; Wang, S. T.; Liu, Z. Q.; McCoy, B. K.; Huang, C. C.; Pindak, R.; Caliebe, W.

    2007-11-30

    We report the results of resonant x-ray diffraction experiments performed on thick films of a biaxial liquid crystal made of achiral bent-core molecules. Polarization properties of forbidden reflections are observed as a function of the sample rotation angle {phi} about the scattering vector Q for the first time on a fluid material. The experimental data are successfully analyzed within a tensor structure factor model by taking the nonperfect alignment of the liquid crystal into account. The local structure of the B{sub 2} mesophase is hence determined to be SmC{sub S}P{sub A}.

  18. Large Flow Birefringence of Nematogenic Bent-Core Liquid Crystals

    SciTech Connect (OSTI)

    Bailey, C.; Fodor-Csorba, K; Verduzco, R; Gleeson, J; Sprunt, S; Jakli, A

    2009-01-01

    We have found that bent-core liquid crystalline materials show exceptionally large intrinsic flow birefringence in their isotropic liquid phase. This effect is more than 100 times larger than typical values measured for low molecular weight liquid crystals. The specific flow birefringence (i.e., normalized by the flow viscosity) is an order of magnitude larger than in both side-chain polymeric as well as low molecular weight liquid crystals. We propose that this large enhancement for bent-core compounds may be attributed to nanoscale smecticlike clusters that persist above the nematic-isotropic transition temperature, and shear align under shear flow; however, this mechanism has not yet been definitively confirmed.

  19. Ultra-fast solid state electro-optical modulator based on liquid crystal polymer and liquid crystal composites

    SciTech Connect (OSTI)

    Ouskova, Elena; Sio, Luciano De Vergara, Rafael; Tabiryan, Nelson; White, Timothy J.; Bunning, Timothy J.

    2014-12-08

    A different generation of polymer-dispersed liquid crystals (PDLCs) based on a liquid crystalline polymer host is reported wherein the fluid behavior of the reactive mesogenic monomer is an enabler to concentration windows (liquid crystal polymer/liquid crystal) (and subsequent morphologies) not previously explored. These liquid crystal (LC) polymer/LC composites, LCPDLCs, exhibit excellent optical and electro-optical properties with negligible scattering losses in both the ON and OFF states. These systems thus have application in systems where fast phase modulation of optical signal instead of amplitude control is needed. Polarized optical microscopy and high resolution scanning electron microscopy confirm a bicontinuous morphology composed of aligned LC polymer coexisting with a phase separated LC fluid. Operating voltages, switching times, and spectra of LCPDLCs compare favourably to conventional PDLC films. The LCPDLCs exhibit a low switching voltage (4–5 V/μm), symmetric and submillisecond (200 μs) on/off response times, and high transmission in both the as formed and switched state in a phase modulation geometry.

  20. Electrically tunable zero dispersion wavelengths in photonic crystal fibers filled with a dual frequency addressable liquid crystal

    SciTech Connect (OSTI)

    Wahle, Markus Kitzerow, Heinz-Siegfried

    2015-11-16

    We present a liquid crystal (LC) infiltrated photonic crystal fiber, which enables the electrical tuning of the position of zero dispersion wavelengths (ZDWs). A dual frequency addressable liquid crystal is aligned perpendicular on the inclusion walls of a photonic crystal fiber, which results in an escaped radial director field. The orientation of the LC is controlled by applying an external electric field. Due to the high index of the liquid crystal the fiber guides light by the photonic band gap effect. Multiple ZDWs exist in the visible and near infrared. The positions of the ZDWs can be either blue or red shifted depending on the frequency of the applied voltage.

  1. Crystallization in supercooled liquid Cu: Homogeneous nucleation and growth

    SciTech Connect (OSTI)

    E, J. C.; Wang, L.; Luo, S. N.; Cai, Y.; Wu, H. A.

    2015-02-14

    Homogeneous nucleation and growth during crystallization of supercooled liquid Cu are investigated with molecular dynamics simulations, and the microstructure is characterized with one- and two-dimensional x-ray diffraction. The resulting solids are single-crystal or nanocrystalline, containing various defects such as stacking faults, twins, fivefold twins, and grain boundaries; the microstructure is subject to thermal fluctuations and extent of supercooling. Fivefold twins form via sequential twinning from the solid-liquid interfaces. Critical nucleus size and nucleation rate at 31% supercooling are obtained from statistical runs with the mean first-passage time and survival probability methods, and are about 14 atoms and 10{sup 32} m{sup −3}s{sup −1}, respectively. The bulk growth dynamics are analyzed with the Johnson-Mehl-Avrami law and manifest three stages; the Avrami exponent varies in the range of 1–19, which also depends on thermal fluctuations and supercooling.

  2. Electrically tuned photoluminescence in large pitch cholesteric liquid crystal

    SciTech Connect (OSTI)

    Middha, Manju Kumar, Rishi Raina, K. K.

    2014-04-24

    Cholesteric liquid crystals are known as 1-D photonic band gap materials due to their periodic helical supramolecular structure and larger birefringence. Depending upon the helical twisted pitch length, they give the characteristic contrast due to selective Bragg reflections when viewed through the polarizing optical microscope and hence affect the electro-optic properties. So the optimization of chiral dopant concentration in nematic liquid crystal leads to control the transmission of polarized light through the microscope. Hence transmission based polarizing optical microscope is used for the characterization of helical pitch length in the optical texture. The unwinding of helical pitch was observed with the application of electric field which affects the intensity of photoluminescence.

  3. Spontaneous liquid crystal and ferromagnetic ordering of colloidal magnetic nanoplates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shuai, M.; Klittnick, A.; Shen, Y.; Smith, G. P.; Tuchband, M. R.; Zhu, C.; Petschek, R. G.; Mertelj, A.; Lisjak, D.; Čopič, M.; et al

    2016-01-28

    Ferrofluids are familiar as colloidal suspensions of ferromagnetic nanoparticles in aqueous or organic solvents. The dispersed particles are randomly oriented but their moments become aligned if a magnetic field is applied, producing a variety of exotic and useful magnetomechanical effects. A longstanding interest and challenge has been to make such suspensions macroscopically ferromagnetic, that is having uniform magnetic alignment in the absence of a field. Here we report a fluid suspension of magnetic nanoplates that spontaneously aligns into an equilibrium nematic liquid crystal phase that is also macroscopically ferromagnetic. We find Its zero-field magnetization produces distinctive magnetic self-interaction effects, includingmore » liquid crystal textures of fluid block domains arranged in closed flux loops, and makes this phase highly sensitive, with it dramatically changing shape even in the Earth’s magnetic field.« less

  4. Photochemical switching behavior of azofunctionalized polymer liquid crystal/SiO{sub 2} composite photonic crystal

    SciTech Connect (OSTI)

    Moritsugu, M.; Kim, S. N.; Ogata, T.; Nonaka, T.; Kurihara, S.; Kubo, S.; Segawa, H.; Sato, O.

    2006-10-09

    A photochemically tunable photonic crystal was prepared by infiltrating azopolymer liquid crystal in a SiO{sub 2} inverse opal structure. The SiO{sub 2} inverse opal film obtained reflected a light corresponding to the periodicity as well as the refractive indices of the inverse opal structure. Linearly polarized light irradiation shifted the reflection band to longer wavelength more than 15 nm. This is caused by the formation of anisotropic molecular orientation of the azopolymer. The switched state was stable in the dark, and the reversible switching of the reflection band can be achieved by the linearly and circularly polarized light irradiations.

  5. A roadmap to uranium ionic liquids: Anti-crystal engineering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yaprak, Damla; Spielberg, Eike T.; Bäcker, Tobias; Richter, Mark; Mallick, Bert; Klein, Axel; Mudring, Anja -Verena

    2014-04-15

    In the search for uranium-based ionic liquids, tris(N,N-dialkyldithiocarbamato)uranylates have been synthesized as salts of the 1-butyl-3-methylimidazolium (C4mim) cation. As dithiocarbamate ligands binding to the UO22+ unit, tetra-, penta-, hexa-, and heptamethylenedithiocarbamates, N,N-diethyldithiocarbamate, N-methyl-N-propyldithiocarbamate, N-ethyl-N-propyldithiocarbamate, and N-methyl-N-butyldithiocarbamate have been explored. X-ray single-crystal diffraction allowed unambiguous structural characterization of all compounds except N-methyl-N-butyldithiocarbamate, which is obtained as a glassy material only. In addition, powder X-ray diffraction as well as vibrational and UV/Vis spectroscopy, supported by computational methods, were used to characterize the products. Differential scanning calorimetry was employed to investigate the phase-transition behavior depending on the N,N-dialkyldithiocarbamato ligand with the aim tomore » establish structure–property relationships regarding the ionic liquid formation capability. Compounds with the least symmetric N,N-dialkyldithiocarbamato ligand and hence the least symmetric anions, tris(N-methyl-N-propyldithiocarbamato)uranylate, tris(N-ethyl-N-propyldithiocarbamato)uranylate, and tris(N-methyl-N-butyldithiocarbamato)uranylate, lead to the formation of (room-temperature) ionic liquids, which confirms that low-symmetry ions are indeed suitable to suppress crystallization. As a result, these materials combine low melting points, stable complex formation, and hydrophobicity and are therefore excellent candidates for nuclear fuel purification and recovery.« less

  6. Exploring Motion Reversal in Polymer Cholesteric-Liquid-Crystal Devices

    SciTech Connect (OSTI)

    Kosc, T.Z.; Coon, C.J.; Babcock, G.V.; Marshall, K.L.; Trajkovska-Petkoska, Jacobs, S.D.

    2006-12-13

    Polymer cholesteric-liquid-crystal (PCLC) flakes suspended in a fluid are used as the active medium in a novel particle-based, electro-optic technology. The motion of PCLC flakes is controlled with an electric field so that PCLC flake devices are brightly reflective in their “off” state and appear dark when an electric field is applied, causing the flakes to reorient 90º. We seek to control flake orientation by designing waveforms that follow the initial drive voltage. Shaped pulses were investigated to accelerate flake relaxation.

  7. Ultra-high-resolution time projection chambers with liquid crystal backplanes

    SciTech Connect (OSTI)

    Monreal, Benjamin

    2014-10-15

    We investigated the possibility of incorporating a liquid-crystal device into a gas ionization detector. After extensive R&D on several candidate liquid-crystal technologies, we developed some novel materials allowing twisted nematic liquid-crystal layers to be coupled directly to gas ionization counters. However, the resulting structures were unsuitable for large-scale or practical use. We tested several technologies known to result in mechanically-robust liquid crystal electrooptic layers, but found poor behavior in the detector context.

  8. Crystallization upon thermal annealing of a glass-forming liquid crystal in the nematic regime

    SciTech Connect (OSTI)

    Mastrangelo, J.C.; Blanton, T.N.; Chen, S.H.

    1995-04-24

    As an example of a novel class of glass-forming liquid crystals, compound (I) was synthesized and characterized to possess a nematic mesophase between {ital T}{sub {ital g}} and {ital T}{sub {ital c}} as the pristine crystal was heated beyond its {ital T}{sub {ital m}} followed by quenching to below room temperature. Differential scanning calorimetry (DSC) and x-ray diffraction techniques were employed to investigate its morphological stability. It was found that the nematic mesophase persists upon annealing for a period of up to 22 h without the appearance of new phases. However, after annealing in the nematic regime over a longer period of time, thermally activated phase transformations were observed, resulting in a new crystalline phase plus the pristine crystalline phase based on DSC thermal transition data and x-ray diffraction patterns.

  9. IBM's New Flat Panel Displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by J. Stöhr (SSRL), M. Samant (IBM), J. Lüning (SSRL) Today's laptop computers utilize flat panel displays where the light transmission from the back to the front of the display is modulated by orientation changes in liquid crystal (LC) molecules. Details are discussed in Ref. 2 below. One of the key steps in the manufacture of the displays is the alignment of the LC molecules in the display. Today this is done by mechanical rubbing of two polymer surfaces and then sandwiching the LC between

  10. Switching and intrinsic position bistability of soliton beams in chiral nematic liquid crystals

    SciTech Connect (OSTI)

    Beeckman, Jeroen; Madani, Abbas; Vanbrabant, Pieter J. M.; Henneaux, Pierre; Gorza, Simon-Pierre; Haelterman, Marc

    2011-03-15

    We study theoretically and experimentally the propagation of light beams in chiral nematic liquid crystals. Despite the rather complex refractive index distribution of these crystals, their reorientational nonlinearity can compensate for diffraction, leading to robust solitonlike beams propagating along helical trajectories. We demonstrate that, due to a symmetry-breaking instability of the liquid crystal structure, these beams undergo abrupt switching and bistability, features that are of potential interest for applications to all-optical signal processing.

  11. Triazolium based ionic liquid crystals: Effect of asymmetric substitution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stappert, K.; Mudring, A. -V.

    2015-01-27

    A new series of ten different asymmetrical 1-dodecyl-3-alkyl-triazolium bromides, [C12CnTr][Br], has been synthesized and their mesomorphic behavior studied by DSC (differential scanning calorimetry), POM (polarizing optical microscopy) and SAXS (small angle X-ray scattering). The influence of the chain length of the triazolium salts is investigated to explore the effect of asymmetric substitution on the phase behaviour of these compounds. For that reason, the length of one alkyl chain was varied from 14 to 1 carbon atoms (n = 14, 12, 10, 8–4, 2, 1) while the other alkyl chain was kept at 12 carbon. Single crystal X-ray structure analysis ofmore » compounds [C12C12Tr][Br] and [C12C5Tr][Br] reveal that the cations adopt a U-shaped conformation with head-to-head arranged triazolium cores. In contrast, for [C12C1Tr][Br], a rod like shape of the cation with interdigitated alkyl chains is found. All investigated compounds are thermotropic liquid crystals. Higher ordered smectic phases, smectic C as well as smectic A phases were found depending on the chain length of the cation. Moreover, the clearing point temperature decreases with decreasing chain length with exception for the n-dodecyl-3-alkyltrizoliumbromides with the two shortest alkyl chains, [C12C2Tr][Br] and [C12C1Tr][Br], which present higher clearing temperatures (86 and 156 °C) and are structurally distinctly different.« less

  12. Optical apparatus using liquid crystals for shaping the spatial intensity of optical beams having designated wavelengths

    DOE Patents [OSTI]

    Jacobs, S.D.; Cerqua, K.A.

    1987-07-14

    The spatial intensity profile of an optical beam of designated wavelengths, such as a laser beam, is shaped (the beam is apodized) by means of cholesteric liquid crystals of opposite chirality disposed successively along the path of the beam. The crystals have curved surfaces, which may be defined by a lens which defines the thickness of the liquid crystal fluid gap in a liquid crystal cell, so as to vary the selective reflection of the designated wavelength across the aperture of the beam. In this way, a soft aperture is provided. By using tandem cell pairs having liquid crystals of opposite chirality, but of different pitch, and with lenses of different curvature, beams of different wavelengths which are projected colinearly along the path may be individually tailored in spatial intensity profile. 11 figs.

  13. Optical apparatus using liquid crystals for shaping the spatial intensity of optical beams having designated wavelengths

    DOE Patents [OSTI]

    Jacobs, Stephen D.; Cerqua, Kathleen A.

    1987-01-01

    The spatial intensity profile of an optical beam of designated wavelengths, such as a laser beam, is shaped (the beam is apodized) by means of cholesteric liquid crystals of opposite chirality disposed successively along the path of the beam. The crystals have curved surfaces, which may be defined by a lens which defines the thickness of the liquid crystal fluid gap in a liquid crystal cell, so as to vary the selective reflection of the designated wavelength across the aperture of the beam. In this way, a soft aperture is provided. By using tandem cell pairs having liquid crystals of opposite chirality, but of different pitch, and with lenses of different curvature, beams of different wavelengths which are projected colinearly along the path may be individually tailored in spatial intensity profile.

  14. Method for monitoring the crystallization of an organic material from a liquid

    DOE Patents [OSTI]

    Asay, Blaine W.; Henson, Bryan F.; Sander, Robert K.; Robinson, Jeanne M.; Son, Steven F.; Dickson, Peter M.

    2004-10-05

    Method for monitoring the crystallization of at least one organic material from a liquid. According to the method, a liquid having at least one organic material capable of existing in at least one non-centrosymmetric phase is prepared. The liquid is interrogated with a laser beam at a chosen wavelength. As at least a portion of the at least one organic material crystallizes from the liquid, the intensity of any light scattered by the crystallized material at a wavelength equal to one-half the chosen wavelength of the interrogating laser beam is monitored. If the intensity of this scattered light, increases, then the crystals that form include at least one non-cetrosymmetric phase.

  15. Deterministically Polarized Fluorescence from Single Dye Molecules Aligned in Liquid Crystal Host

    SciTech Connect (OSTI)

    Lukishova, S.G.; Schmid, A.W.; Knox, R.; Freivald, P.; Boyd, R. W.; Stroud, Jr., C. R.; Marshall, K.L.

    2005-09-30

    We demonstrated for the first time to our konwledge deterministically polarized fluorescence from single dye molecules. Planar aligned nematic liquid crystal hosts provide deterministic alignment of single dye molecules in a preferred direction.

  16. All-Optically Prepared and Controlled Nematic Liquid Crystal Light Valve -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal All-Optically Prepared and Controlled Nematic Liquid Crystal Light Valve Colorado School of Mines Contact CSM About This Technology Technology Marketing SummaryThis device acts as an optical switch that controls the intensity of a light beam through the action of a second control beam. This behavior is achieved through photo-induced anisotropy that develops in a monomolecular layer coating the inside surfaces of a liquid crystal cell.DescriptionOne of these surfaces

  17. Speckle noise suppression using a helix-free ferroelectric liquid crystal cell

    SciTech Connect (OSTI)

    Andreev, A L; Andreeva, T B; Kompanets, I N; Zalyapin, N V

    2014-12-31

    We have studied the method for suppressing speckle noise in patterns produced by a laser based on a fast-response electro-optical cell with a ferroelectric liquid crystal (FLC) in which helicoid is absent, i.e., compensated for. The character of smectic layer deformation in an electric field is considered along with the mechanism of spatially inhomogeneous phase modulation of a laser beam passing through the cell which is accompanied by the destruction of phase relations in the beam. Advantages of a helix-free FLC cell are pointed out as compared to helical crystal cells studied previously. (liquid crystal devices)

  18. Optofluidic-Tunable Color Filters And Spectroscopy Based On Liquid-Crystal Microflows

    SciTech Connect (OSTI)

    Cuennet, J. G.; Vasdekis, Andreas E.; Psaltis, D.

    2013-05-24

    The integration of color filters with microfluidics has attracted substantial attention in recent years, for on-chip absorption, fluorescence, or Raman analysis. We describe such tunable filters based on the micro-flow of liquid crystals. The filter operation is based on the wavelength dependent liquid crystal birefringence that can be tuned by modifying the flow velocity field in the microchannel. The latter is possible both temporally and spatially by varying the inlet pressure and the channel geometry respectively. We explored the use of these optofluidic filters for on-chip absorption spectroscopy; by integrating the distance dependent color filter with a dye-filled micro-channel, the absorption spectrum of a dye could be measured. Liquid crystal microflows simplify substantially the optofluidic integration, actuation and tuning of color filters for lab-on-a-chip spectroscopic applications.

  19. Light-controlled electric Freedericksz threshold in dye doped liquid crystals

    SciTech Connect (OSTI)

    Lucchetti, L.; Catani, L.; Simoni, F.

    2014-05-28

    We report the results of measurements of the threshold of Freedericksz transition in a nematic liquid crystal doped by Methyl-red. We show that in case of dc field the threshold voltage can decrease or increase depending on the light dose, due to the light-induced desorption and adsorption of charge complexes from and on the irradiated surface, that has been recently demonstrated. This effect has the potential to be exploited in optical devices such as liquid crystal microlenses and spatial light modulators.

  20. Optical Manipulation of Shape-Morphing Elastomeric Liquid Crystal Microparticles Doped with Gold Nanocrystals

    SciTech Connect (OSTI)

    Sun, Y. R.; Evans, J. S.; Lee, T.; Senyuk, B.; Keller, P.; He, S. L.; Smalyukh, I. I.

    2012-06-11

    We demonstrate facile optical manipulation of shape of birefringent colloidal microparticles made from liquid crystal elastomers. Using soft lithography and polymerization, we fabricate elastomeric microcylinders with weakly undulating director oriented on average along their long axes. These particles are infiltrated with gold nanospheres acting as heat transducers that allow for an efficient localized transfer of heat from a focused infrared laser beam to a submicrometer region within a microparticle. Photothermal control of ordering in the liquid crystal elastomer using scanned beams allows for a robust control of colloidal particles, enabling both reversible and irreversible changes of shape. Possible applications include optomechanics, microfluidics, and reconfigurable colloidal composites with shape-dependent self-assembly.

  1. Surface relief gratings on polymer dispersed liquid crystals by polarization holography

    SciTech Connect (OSTI)

    Mazzulla, A.; Pagliusi, P.; Provenzano, C.; Russo, G.; Carbone, G.; Cipparrone, G.

    2004-09-27

    We report the observation of surface relief gratings (SRGs) on polymer dispersed liquid crystal films after polarization holographic recording, demonstrating the formation of SRGs in systems without azo compounds, where photoisomerization and chromophore reorientation processes do not occur. Permanent SRGs, several hundred nanometers deep, are recorded on the surface of a polymeric material containing oriented liquid crystal droplets. The results suggest that SRG growth under uniform intensity irradiation is not exclusively related to the photoisomerization, but is a more general phenomenon which can involve different photoinduced chemical and physical mechanisms sensitive to the light polarization state. These effects contribute to the formation of anisotropic structures during the recording process.

  2. Crystal Genes’ in Metallic Liquids and Glasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Yang; Zhang, Feng; Ye, Zhuo; Zhang, Yue; Fang, Xiaowei; Ding, Zejun; Wang, Cai-Zhuang; Mendelev, Mikhail I.; Ott, Ryan T.; Kramer, Matthew J.; et al

    2016-03-31

    We analyze the underlying structural order that transcends liquid, glass and crystalline states in metallic systems. A genetic algorithm is applied to search for the most common energetically favorable packing motifs in crystalline structures. These motifs are in turn compared to the observed packing motifs in the actual liquid or glass structures using a cluster-alignment method. Using this method, we have revealed the nature of the short-range order in Cu64Zr36 glasses. More importantly, we identified a novel structural order in the Al90Sm10 system. In addition, our approach brings new insight into understanding the origin of vitrification and describing mesoscopic order-disordermore » transitions in condensed matter systems.« less

  3. Theoretically informed Monte Carlo simulation of liquid crystals by sampling of alignment-tensor fields.

    SciTech Connect (OSTI)

    Armas-Perez, Julio C.; Londono-Hurtado, Alejandro; Guzman, Orlando; Hernandez-Ortiz, Juan P.; de Pablo, Juan J.

    2015-07-27

    A theoretically informed coarse-grained Monte Carlo method is proposed for studying liquid crystals. The free energy functional of the system is described in the framework of the Landau-de Gennes formalism. The alignment field and its gradients are approximated by finite differences, and the free energy is minimized through a stochastic sampling technique. The validity of the proposed method is established by comparing the results of the proposed approach to those of traditional free energy minimization techniques. Its usefulness is illustrated in the context of three systems, namely, a nematic liquid crystal confined in a slit channel, a nematic liquid crystal droplet, and a chiral liquid crystal in the bulk. It is found that for systems that exhibit multiple metastable morphologies, the proposed Monte Carlo method is generally able to identify lower free energy states that are often missed by traditional approaches. Importantly, the Monte Carlo method identifies such states from random initial configurations, thereby obviating the need for educated initial guesses that can be difficult to formulate.

  4. Nematicons deflection through interaction with disclination lines in chiral nematic liquid crystals

    SciTech Connect (OSTI)

    Laudyn, Urszula A.; Karpierz, Miroslaw A.

    2013-11-25

    In this work, we study experimentally the interaction of spatial optical soliton in chiral nematic liquid crystals with disclination line created in a wedge shaped cell. We show that in most cases the self-confined beam preserves this interaction. We demonstrate that this interaction can be employed for efficient bending of the soliton trajectory, as a result of reflection and refraction.

  5. Distant optical detection of small rotations and displacements by means of chiral liquid crystals

    SciTech Connect (OSTI)

    Shibaev, Petr V. E-mail: shibayev@fordham.edu; Troisi, Juliana; Reddy, Kathryn; Iljin, Andrey

    2014-01-15

    The paper describes novel chiral viscoelastic liquid crystalline mixtures and their application for the detection of small rotational displacements of two plates confining cholesteric liquid crystals (CLC). The mixtures are characterized by extremely high viscosities and stability of the selective reflection band (SRB) at ambient temperatures. Even a small rotation applied to the chiral liquid crystal (CLC) cell results in dramatic changes of the reflective properties of sandwiched CLC films. The angle and direction of rotation as well as the magnitude of CLC's shear deformation can be determined for a variety of experimental geometries, each of which is characterized by its own response function. The proposed model explains changes in the reflection spectra for different experimental geometries and relates them to the angle of rotation and magnitude of shear. The method was tested for a detection of small rotations from a distance of up to 50 m and allows for resolving small rotations of the order of fractions of degrees.

  6. Application of pyroelectric crystal and ionic liquid to the production of metal compounds

    SciTech Connect (OSTI)

    Imashuku, Susumu; Imanishi, Akira; Kawai, Jun

    2013-04-19

    Zinc fluoride (ZnF{sub 2}) was deposited on a silicon substrate by changing temperature of a pyroelectric crystal of LiTaO{sub 3} on which ionic liquid (EMI-Tf{sub 2}N) containing zinc ions was dripped at 1 Pa. ZnF{sub 2} was also obtained by bombarding argon ions on EMI-Tf{sub 2}N containing zinc ions. From these results, it is concluded that EMI-Tf{sub 2}N containing zinc ions on the LiTaO{sub 3} crystal was evaporated on the silicon substrate by changing temperature of the LiTaO{sub 3} crystal in vacuum and that the evaporated EMI-Tf{sub 2}N containing metal zinc ions was decomposed to ZnF{sub 2} by the bombardment of electrons accelerated by the electric field between the LiTaO{sub 3} crystal and the silicon substrate.

  7. Balance of optical, structural, and electrical properties of textured liquid phase crystallized Si solar cells

    SciTech Connect (OSTI)

    Preidel, V. Amkreutz, D.; Haschke, J.; Wollgarten, M.; Rech, B.; Becker, C.

    2015-06-14

    Liquid phase crystallized Si thin-film solar cells on nanoimprint textured glass substrates exhibiting two characteristic, but distinct different surface structures are presented. The impact of the substrate texture on light absorption, the structural Si material properties, and the resulting solar cell performance is analyzed. A pronounced periodic substrate texture with a vertical feature size of about 1 μm enables excellent light scattering and light trapping. However, it also gives rise to an enhanced Si crystal defect formation deteriorating the solar cell performance. In contrast, a random pattern with a low surface roughness of 45 nm allows for the growth of Si thin films being comparable to Si layers on planar reference substrates. Amorphous Si/crystalline Si heterojunction solar cells fabricated on the low-roughness texture exhibit a maximum open circuit voltage of 616 mV and internal quantum efficiency peak values exceeding 90%, resulting in an efficiency potential of 13.2%. This demonstrates that high quality crystalline Si thin films can be realized on nanoimprint patterned glass substrates by liquid phase crystallization inspiring the implementation of tailor-made nanophotonic light harvesting concepts into future liquid phase crystallized Si thin film solar cells on glass.

  8. Formation of H-type liquid crystal dimer at air-water interface

    SciTech Connect (OSTI)

    Karthik, C. Gupta, Adbhut Joshi, Aditya Manjuladevi, V. Gupta, Raj Kumar; Varia, Mahesh C.; Kumar, Sandeep

    2014-04-24

    We have formed the Langmuir monolayer of H-shaped Azo linked liquid crystal dimer molecule at the air-water interface. Isocycles of the molecule showed hysteresis suggesting the ir-reversible nature of the monolayer formed. The thin film deposited on the silicon wafer was characterized using Atomic Force Microscopy (AFM) and Field Emission Scanning Electron Microscopy (FESEM). The images showed uniform domains of the dimer molecule. We propose that these molecules tend to take book shelf configuration in the liquid phase.

  9. Optical phase conjugation in azo-dye doped chiral liquid crystal

    SciTech Connect (OSTI)

    Karpinski, Pawel; Miniewicz, Andrzej

    2012-10-15

    We report on optical phase conjugation phenomenon observed in chiral nematic liquid crystal showing band gap type Bragg reflection. The phase conjugate to the signal beam is observable only in the small temperature interval when the Bragg condition is fulfilled and only for circularly polarized light. The optical phase conjugation signals were observed at low cw laser light intensities (<100 mW/cm{sup 2}, {lambda} = 532 nm). Estimated value of third order optical susceptibility {chi}{sup (3)} = 2.8 Multiplication-Sign 10{sup -17} m{sup 2}/V{sup 2} is attributed to enhancement due to photoisomerisation of azo-dye (disperse red 1) inducing molecular reorientation process of liquid crystal molecules.

  10. Dynamics of photoinduced processes in liquid-crystal polymer films containing azo compounds

    SciTech Connect (OSTI)

    Simonov, A N; Larichev, A V

    1999-07-31

    The photoinduced processes in azo-compound-containing side-chain polymer films with liquid-crystal properties are examined theoretically. A model is proposed whereby it is possible to consider the dynamics of the optical response of a medium taking into account the anisotropic saturation in the angular distribution of the azo-dye isomers as well as the intermolecular interaction. The influence of the liquid-crystal ordering in the polymer is taken into account by introducing a phenomenological mean-field factor. Analytical solutions describing changes in the optical properties of a polymer film during the initial illumination stages are in good agreement with experimental data. (this issue is dedicated to the memory of s a akhmanov)

  11. Technique for compressing light intensity ranges utilizing a specifically designed liquid crystal notch filter

    DOE Patents [OSTI]

    Rushford, Michael C.

    1988-01-01

    A pin hole camera assembly for use in viewing an object having a relatively large light intensity range, for example a crucible containing molten metal in an atomic vapor laser isotope separation (AVLIS) system is disclosed herein. The assembly includes means for optically compressing the light intensity range appearing at its input sufficient to make it receivable and decipherable by a standard video camera. To accomplish this, the assembly utilizes the combination of interference filter and a liquid crystal notch filter. The latter which preferably includes a cholesteric liquid crystal arrangement is configured to pass light at all wavelengths, except a relatively narrow wavelength band which defines the filter's notch, and includes means for causing the notch to vary to at least a limited extent with the intensity of light at its light incidence surface.

  12. Photoluminescence properties of cadmium-selenide quantum dots embedded in a liquid-crystal polymer matrix

    SciTech Connect (OSTI)

    Tselikov, G. I. Timoshenko, V. Yu.; Plenge, J.; Ruehl, E.; Shatalova, A. M.; Shandryuk, G. A.; Merekalov, A. S.; Tal'roze, R. V.

    2013-05-15

    The photoluminescence properties of cadmium-selenide (CdSe) quantum dots with an average size of {approx}3 nm, embedded in a liquid-crystal polymer matrix are studied. It was found that an increase in the quantum-dot concentration results in modification of the intrinsic (exciton) photoluminescence spectrum in the range 500-600 nm and a nonmonotonic change in its intensity. Time-resolved measurements show the biexponential decay of the photoluminescence intensity with various ratios of fast and slow components depending on the quantum-dot concentration. In this case, the characteristic lifetimes of exciton photoluminescence are 5-10 and 35-50 ns for the fast and slow components, respectively, which is much shorter than the times for colloidal CdSe quantum dots of the same size. The observed features of the photoluminescence spectra and kinetics are explained by the effects of light reabsorption, energy transfer from quantum dots to the liquid-crystal polymer matrix, and the effect of the electronic states at the CdSe/(liquid crystal) interface.

  13. Mesophase stabilization in ionic liquid crystals through pairing equally shaped mesogenic cations and anions

    SciTech Connect (OSTI)

    Stappert, Kathrin; Lipinski, Gregor; Kopiec, Gabriel; Spielberg, Eike T.; Mudring, Anja -Verena

    2015-07-23

    The synthesis and properties of a set of novel ionic liquid crystals with congruently shaped cations and anions are reported to check whether pairing mesogenic cations with mesogenic anions leads to a stabilization of a liquid crystalline phase. To that avail 1-alkyl-3-methyl-triazolium cations with an alkyl chain length of 10, 12, and 14 carbon atoms have been combined with p-alkyloxy-benzenesulfonate anions with different alkyl chain lengths (n = 10, 12, and 14). The corresponding triazolium iodides have been synthesized as reference compounds where the cation and anion have strong size and shape mismatch. The mesomorphic behavior of all compounds is studied by differential scanning calorimetry and polarizing optical microscopy. All compounds except 1-methyl-3-decyltriazolium iodide, which qualifies as an ionic liquid, are thermotropic ionic liquid crystals. All other compounds adopt smectic A phases. As a result, a comparison of the thermal phase behavior of the 1-methyl-3-decyltriazolium bromides to the corresponding p-alkoxy-benzensulfonates reveals that definitely the mesophase is stabilized by pairing the rod-shaped 1-alkyl-3-methyltriazolium cation with a rod-like anion of similar size.

  14. Mesophase stabilization in ionic liquid crystals through pairing equally shaped mesogenic cations and anions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stappert, Kathrin; Lipinski, Gregor; Kopiec, Gabriel; Spielberg, Eike T.; Mudring, Anja -Verena

    2015-07-23

    The synthesis and properties of a set of novel ionic liquid crystals with congruently shaped cations and anions are reported to check whether pairing mesogenic cations with mesogenic anions leads to a stabilization of a liquid crystalline phase. To that avail 1-alkyl-3-methyl-triazolium cations with an alkyl chain length of 10, 12, and 14 carbon atoms have been combined with p-alkyloxy-benzenesulfonate anions with different alkyl chain lengths (n = 10, 12, and 14). The corresponding triazolium iodides have been synthesized as reference compounds where the cation and anion have strong size and shape mismatch. The mesomorphic behavior of all compounds ismore » studied by differential scanning calorimetry and polarizing optical microscopy. All compounds except 1-methyl-3-decyltriazolium iodide, which qualifies as an ionic liquid, are thermotropic ionic liquid crystals. All other compounds adopt smectic A phases. As a result, a comparison of the thermal phase behavior of the 1-methyl-3-decyltriazolium bromides to the corresponding p-alkoxy-benzensulfonates reveals that definitely the mesophase is stabilized by pairing the rod-shaped 1-alkyl-3-methyltriazolium cation with a rod-like anion of similar size.« less

  15. Ligand-assisted liquid crystal templating in mesoporous niobium oxide molecular sieves

    SciTech Connect (OSTI)

    Antonelli, D.M.; Nakahira, A.; Ying, J.Y.

    1996-05-22

    A systematic study of the factors governing the formation of Nb-TMS1, a niobium-based mesoporous hexagonally-packed transition metal oxide molecular sieve, is reported. The synthesis of this material was achieved through a novel ligand-assisted liquid crystal templating mechanism in which a discrete covalent bond is used to direct the templating interaction between the organic and inorganic phases. In general, the synthesis of Nb-TMS1 is more strongly affected by starting conditions such as temperature, surfactant-to-metal ratio, pH, and solvent than by temperature and time of aging after the initial hydrolysis step. The results also show that Nb-TMS1 can be synthesized under conditions which strongly disfavor the formation of micelles. This suggests that Nb-TMS1 is formed via a mechanism involving self-assembly with concomitant condensation. It was found that with increasing surfactant-to-metal ratios, new hexagonal P63/mmc (Nb-TMS2) and layered (Nb-TMS4) phases could be formed, while increasing the surfactant chain length led to a new cubic phase (Nb-TMS3). Crystals of Nb-TMS1 of up to several mm in dimensions were also grown. These crystals are larger than the biggest mesoporous crystals reported by a factor of 3 orders of magnitude. These crystals retain their structure on micelle removal by acid treatment and are thus of great interest as hosts for quantum wires.

  16. Spontaneous Ferroelectric Order in a Bent-Core Smectic Liquid Crystal of Fluid Orthorhombic Layers

    SciTech Connect (OSTI)

    R Reddy; C Zhu; R Shao; E Korblova; T Gong; Y Shen; M Glaser; J Maclennan; D Walba; N Clark

    2011-12-31

    Macroscopic polarization density, characteristic of ferroelectric phases, is stabilized by dipolar intermolecular interactions. These are weakened as materials become more fluid and of higher symmetry, limiting ferroelectricity to crystals and to smectic liquid crystal stackings of fluid layers. We report the SmAP{sub F}, the smectic of fluid polar orthorhombic layers that order into a three-dimensional ferroelectric state, the highest-symmetry layered ferroelectric possible and the highest-symmetry ferroelectric material found to date. Its bent-core molecular design employs a single flexible tail that stabilizes layers with untilted molecules and in-plane polar ordering, evident in monolayer-thick freely suspended films. Electro-optic response reveals the three-dimensional orthorhombic ferroelectric structure, stabilized by silane molecular terminations that promote parallel alignment of the molecular dipoles in adjacent layers.

  17. Liquid-crystal alignment on a-C:H films by nitrogen plasma beam scanning

    SciTech Connect (OSTI)

    Wu, K.Y.; Chen, C.-H.; Yeh, C.-M.; Hwang, J.; Liu, P.-C.; Lee, C.-Y.; Chen, C.-W.; Wei, H.K.; Kou, C.S.; Lee, C.-D.

    2005-10-15

    A plasma beam scanning treatment has been developed to modify the surface of the hydrogenated amorphous carbon (a-C:H) film on the indium tin oxide glass. The plasma beam scanning treatment makes the a-C:H film an excellent layer for liquid-crystal alignment. The qualities of a-C:H films were characterized by using atomic force microscope, micro-Raman spectroscopy, and field-emission scanning electron microscope. The ultrathin a-C:H films were deposited at 50% CH{sub 4}/(H{sub 2}+CH{sub 4}) gas ratio, 100 W radio-frequency power, and a gas pressure of 10 mtorr for 15 min by capacitive-coupled plasma chemical-vapor deposition method. The twist nematic cells were filled with liquid crystal (ZLI-2293) on the a-C:H film treated with different nitrogen plasma beam scanning time. The grooving mechanism is considered not responsible for the liquid-crystal (LC) alignment. Raman spectra suggest that a bond-breaking process of aromatic rings occurs in the a-C:H film. The O{sub 1s}, C{sub 1s}, and N{sub 1s} core-level spectra support that the nitrogen plasma beam scanning treatment induces a bond-breaking process of aromatic rings to create available carbon dangling bonds for the formation of C-O bonds. The newly formed C-O bonds are 'directional', which favor the LC alignment on the a-C:H film.

  18. Liquid crystal terahertz phase shifters with functional indium-tin-oxide nanostructures for biasing and alignment

    SciTech Connect (OSTI)

    Yang, Chan-Shan; Tang, Tsung-Ta; Pan, Ru-Pin; Yu, Peichen; Pan, Ci-Ling

    2014-04-07

    Indium Tin Oxide (ITO) nanowhiskers (NWhs) obliquely evaporated by electron-beam glancing-angle deposition can serve simultaneously as transparent electrodes and alignment layer for liquid crystal (LC) devices in the terahertz (THz) frequency range. To demonstrate, we constructed a THz LC phase shifter with ITO NWhs. Phase shift exceeding ?/2 at 1.0 THz was achieved in a ?517??m-thick cell. The phase shifter exhibits high transmittance (?78%). The driving voltage required for quarter-wave operation is as low as 5.66?V (rms), compatible with complementary metal-oxide-semiconductor (CMOS) and thin-film transistor (TFT) technologies.

  19. Fine golden rings: Tunable surface plasmon resonance from assembled nanorods in topological defects of liquid crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lee, Elaine; Xia, Yu; Ferrier, Jr., Robert C.; Kim, Hye -Na; Gharbi, Mohamed A.; Stebe, Kathleen J.; Kamien, Randall D.; Composto, Russell J.; Yang, Shu

    2016-02-08

    Unprecedented, reversible, and dynamic control over an assembly of gold nanorods dispersed in liquid crystals (LC) is demonstrated. The LC director field is dynamically tuned at the nanoscale using microscale ring confinement through the interplay of elastic energy at different temperatures, thus fine-tuning its core replacement energy to reversibly sequester nanoscale inclusions at the microscale. As a result, this leads to shifts of 100 nm or more in the surface plasmon resonance peak, an order of magnitude greater than any previous work with AuNR composites.

  20. Effects of graphene on electro-optic switching and spontaneous polarization of a ferroelectric liquid crystal

    SciTech Connect (OSTI)

    Basu, Rajratan, E-mail: basu@usna.edu [Department of Physics, Soft-matter and Nanomaterials Laboratory, The United States Naval Academy, Annapolis, Maryland 21402 (United States)

    2014-09-15

    A small quantity of graphene flakes was doped in a ferroelectric liquid crystal (FLC), and the field-induced ferroelectric electro-optic switching was found to be significantly faster in the FLC + graphene hybrid than that of the pure FLC. Further studies revealed that the suspended graphene flakes enhanced the FLC's spontaneous polarization by improving smectic-C ordering resulting from the ?? electron stacking, and reduced rotation viscosity by trapping some of the free ions of the FLC media. These effects coherently impacted the FLC-switching phenomenon, enabling the FLC molecules to switch faster on reversing an external electric field.

  1. Transient self-interaction of light in a liquid-crystal polymer film containing azodye molecules

    SciTech Connect (OSTI)

    Simonov, A N

    1999-07-31

    Transient self-interaction of low-power He - Ne laser radiation (1 < 50 mW cm{sup -2} ) in a liquid-crystal polymer film containing chemically bound azodye molecules was observed experimentally. The self-interaction occurred in the region of a temperature-induced phase transition in the polymer film and was accompanied by the formation of quasi-periodic ring-shaped structures in the distribution of the transmitted light intensity. (this issue is dedicated to the memory of s a akhmanov)

  2. Transflective spatial filter based on azo-dye-doped cholesteric liquid crystal films

    SciTech Connect (OSTI)

    Lin, T.-H.; Fuh, Andy Y.-G.

    2005-07-04

    This work demonstrates the feasibility of exploiting the photoisomerization effect in azo-dye-doped cholesteric liquid crystal (DDCLC) films with a concomitant decline of the phase transition temperature from the cholesteric to an isotropic phase (T{sub Ch-I}) as a spatial filter. The fabrication depends on the fact that the various intensities of the diffracted orders are responsible for the various degrees of transparency associated with the photoisomerized DDCLC film. High- and low-pass images in the Fourier optical signal process can be simultaneously observed via reflected and transmitted signals, respectively. A simulation is also performed, and the results are consistent closely with experimental data.

  3. Exploring the alignment of carbon nanotubes dispersed in a liquid crystal matrix using coplanar electrodes

    SciTech Connect (OSTI)

    Volpati, D.; Massey, M. K.; Kotsialos, A.; Qaiser, F.; Pearson, C.; Tiburzi, G.; Zeze, D. A.; Petty, M. C.; Johnson, D. W.; Coleman, K. S.

    2015-03-28

    We report on the use of a liquid crystalline host medium to align single-walled carbon nanotubes in an electric field using an in-plane electrode configuration. Electron microscopy reveals that the nanotubes orient in the field with a resulting increase in the DC conductivity in the field direction. Current versus voltage measurements on the composite show a nonlinear behavior, which was modelled by using single-carrier space-charge injection. The possibility of manipulating the conductivity pathways in the same sample by applying the electrical field in different (in-plane) directions has also been demonstrated. Raman spectroscopy indicates that there is an interaction between the nanotubes and the host liquid crystal molecules that goes beyond that of simple physical mixing.

  4. Imaging sensors and displays. SPIE volume 765

    SciTech Connect (OSTI)

    Freeman, C.F.

    1987-01-01

    This book discusses the following contents: HUMAN FACTORS FOR IMAGING SYSTEMS. Analysis of electroluminescent display devices for stereographic display of video images. Field of view, resolution, and brightness parameters for eye-limited displays. Helmet-mounted display for tank applications. Temporal aspects of electro-optical imaging systems. Helmet-mounted display for infantry applications. Image quality: two current issues. ADVANCED IMAGING SENSOR TECHNOLOGY. New color coding method with quasi-field integration mode for solid-state color imaging equipment. One-half inch CCD imager with 510 X 492 pixels. Solid-state imager implementing sensitivity control function on chip. Color laser microscope. A channel stop defined, barrier and drain antiblooming structure for virtual phase CCD image sensors. ADVANCED IMAGING DISPLAYS. Ultrahigh resolution 7 in. round monochrome CRT. High resolution MIM-diode LCD addressed by storage capacitor matrix. IMAGE DISPLAY TECHNOLOGY FOR INFRARED PROJECTORS. IR transducer technology: an overview. IT emitting CRT. IR simulation using the liquid crystal light valve (LCLV). Infrared display array. IR image generation by thermoelectric elements. IR simulation with diffusion image transfer film. Dynamic RAM imaging display technology utilizing silicon blackbody emitters. Thermal target projector for MRTD testing and vehicle identification training.

  5. Photomechanical bending mechanics of polydomain azobenzene liquid crystal polymer network films

    SciTech Connect (OSTI)

    Cheng Liang; Torres, Yanira; Oates, William S.; Lee, Kyung Min; McClung, Amber J.; Baur, Jeffery; White, Timothy J.

    2012-07-01

    Glassy, polydomain azobenzene liquid crystal polymer networks (azo-LCNs) have been synthesized, characterized, and modeled to understand composition dependence on large amplitude, bidirectional bending, and twisting deformation upon irradiation with linearly polarized blue-green (440-514 nm) light. These materials exhibit interesting properties for adaptive structure applications in which the shape of the photoresponsive material can be rapidly reconfigured with light. The basis for the photomechanical output observed in these materials is absorption of actinic light by azobenzene, which upon photoisomerization dictates an internal stress within the local polymer network. The photoinduced evolution of the underlying liquid crystal microstructure is manifested as macroscopic deformation of the glassy polymer film. Accordingly, this work examines the polarization-controlled bidirectional bending of highly concentrated azo-LCN materials and correlates the macroscopic output (observed as bending) to measured blocked stresses upon irradiation with blue-green light of varying polarization. The resulting photomechanical output is highly dependent on the concentration of crosslinked azobenzene mesogens employed in the formulation. Experiments that quantify photomechanical bending and photogenerated stress are compared to a large deformation photomechanical shell model to quantify the effect of polarized light interactions with the material during static and dynamic polarized light induced deformation. The model comparisons illustrate differences in internal photostrain and deformation rates as a function of composition and external mechanical constraints.

  6. Kinetics of liquid-mediated crystallization of amorphous Ge from multi-frame dynamic transmission electron microscopy

    SciTech Connect (OSTI)

    Santala, M. K. Campbell, G. H.; Raoux, S.

    2015-12-21

    The kinetics of laser-induced, liquid-mediated crystallization of amorphous Ge thin films were studied using multi-frame dynamic transmission electron microscopy (DTEM), a nanosecond-scale photo-emission transmission electron microscopy technique. In these experiments, high temperature gradients are established in thin amorphous Ge films with a 12-ns laser pulse with a Gaussian spatial profile. The hottest region at the center of the laser spot crystallizes in ∼100 ns and becomes nano-crystalline. Over the next several hundred nanoseconds crystallization continues radially outward from the nano-crystalline region forming elongated grains, some many microns long. The growth rate during the formation of these radial grains is measured with time-resolved imaging experiments. Crystal growth rates exceed 10 m/s, which are consistent with crystallization mediated by a very thin, undercooled transient liquid layer, rather than a purely solid-state transformation mechanism. The kinetics of this growth mode have been studied in detail under steady-state conditions, but here we provide a detailed study of liquid-mediated growth in high temperature gradients. Unexpectedly, the propagation rate of the crystallization front was observed to remain constant during this growth mode even when passing through large local temperature gradients, in stark contrast to other similar studies that suggested the growth rate changed dramatically. The high throughput of multi-frame DTEM provides gives a more complete picture of the role of temperature and temperature gradient on laser crystallization than previous DTEM experiments.

  7. Kinetics of liquid-mediated crystallization of amorphous Ge from multi-frame dynamic transmission electron microscopy

    SciTech Connect (OSTI)

    Santala, M. K.; Raoux, S.; Campbell, G. H.

    2015-12-24

    The kinetics of laser-induced, liquid-mediated crystallization of amorphous Ge thin films were studied using multi-frame dynamic transmission electron microscopy (DTEM), a nanosecond-scale photo-emission transmission electron microscopy technique. In these experiments, high temperature gradients are established in thin amorphous Ge films with a 12-ns laser pulse with a Gaussian spatial profile. The hottest region at the center of the laser spot crystallizes in ~100 ns and becomes nano-crystalline. Over the next several hundred nanoseconds crystallization continues radially outward from the nano-crystalline region forming elongated grains, some many microns long. The growth rate during the formation of these radial grains is measured with time-resolved imaging experiments. Crystal growth rates exceed 10 m/s, which are consistent with crystallization mediated by a very thin, undercooled transient liquid layer, rather than a purely solid-state transformation mechanism. The kinetics of this growth mode have been studied in detail under steady-state conditions, but here we provide a detailed study of liquid-mediated growth in high temperature gradients. Unexpectedly, the propagation rate of the crystallization front was observed to remain constant during this growth mode even when passing through large local temperature gradients, in stark contrast to other similar studies that suggested the growth rate changed dramatically. As a result, the high throughput of multi-frame DTEM provides gives a more complete picture of the role of temperature and temperature gradient on laser crystallization than previous DTEM experiments.

  8. Effect of the annealing temperature and ion-beam bombardment on the properties of solution-derived HfYGaO films as liquid crystal alignment layers

    SciTech Connect (OSTI)

    Park, Hong-Gyu; Lee, Yun-Gun; Jang, Sang Bok; Lee, Ju Hwan; Jeong, Hae-Chang; Seo, Dae-Shik; Oh, Byeong-Yun

    2015-11-15

    Hafnium yttrium gallium oxide (HfYGaO) films were applied to liquid crystal displays (LCDs) as liquid crystal (LC) alignment layers, replacing conventional polyimide (PI) layers. The HfYGaO alignment layers were prepared by fabricating solution-processed HfYGaO films, annealing them, and treating them with ion-beam (IB) irradiation. The authors studied the effects of annealing temperature and IB irradiation of the solution-derived HfYGaO films on the orientation of LC molecules. The LC molecules on the solution-derived HfYGaO films were homogeneously and uniformly aligned by IB irradiation, irrespective of the annealing temperature. Atomic force microscopy analyses revealed that the surface reformation of the HfYGaO films induced by IB irradiation strengthened the van der Waals force between the LC molecules and the HfYGaO films, leading to uniform LC alignment. Enhanced electro-optical characteristics were observed in the twisted-nematic (TN) LCDs based on IB-irradiated HfYGaO films compared with those of TN-LCDs based on PI layers, demonstrating the high application potential of the proposed solution-derived HfYGaO films as LC alignment layers.

  9. Optical data recording by laser pulses in liquid-crystal cells with an azo-modified surface

    SciTech Connect (OSTI)

    Serak, S V; Agashkov, A V; Reshetnyak, V Yu

    2001-03-31

    The effect of trans-cis photoisomerisation of azofragments of a polymer film on the molecular reorientation of a liquid crystal is studied. It is shown that, using nanosecond laser pulses, one can perform both the reversible and static data recording in liquid-crystal cells with an azo-modified surface. The rise time of the reorientation is measured by the methods of dynamic holography to be about {approx} 30 {mu}s, and the grating efficiency achieves 15 %. (laser applications and other topics in quantum electronics)

  10. An electrically tunable plenoptic camera using a liquid crystal microlens array

    SciTech Connect (OSTI)

    Lei, Yu; Tong, Qing; Zhang, Xinyu; Sang, Hongshi; Ji, An; Xie, Changsheng

    2015-05-15

    Plenoptic cameras generally employ a microlens array positioned between the main lens and the image sensor to capture the three-dimensional target radiation in the visible range. Because the focal length of common refractive or diffractive microlenses is fixed, the depth of field (DOF) is limited so as to restrict their imaging capability. In this paper, we propose a new plenoptic camera using a liquid crystal microlens array (LCMLA) with electrically tunable focal length. The developed LCMLA is fabricated by traditional photolithography and standard microelectronic techniques, and then, its focusing performance is experimentally presented. The fabricated LCMLA is directly integrated with an image sensor to construct a prototyped LCMLA-based plenoptic camera for acquiring raw radiation of targets. Our experiments demonstrate that the focused region of the LCMLA-based plenoptic camera can be shifted efficiently through electrically tuning the LCMLA used, which is equivalent to the extension of the DOF.

  11. Use of image processing techniques for heat transfer measurements using thermochromic liquid crystals

    SciTech Connect (OSTI)

    Crabtree, J.A.

    1994-06-01

    A Macintosh-based image processing code has been developed for use in making continuous temperature profile measurements using thermochromic liquid crystals. This software is the result of extensive modifications to the public domain software, NIH Image developed by the National Institutes of Health. These modifications primarily include routines to quantify the TLC color changes as temperature measurements while providing a simple user interface. Using these techniques, one can perform literally thousands of temperature measurements over a small area (307,200 temperature measurements in a 640*480 image), thus making continuous profile measurement possible. This technique was developed in support of the Advanced Neutron Source Reactor (a new nuclear fission research reactor being developed at Oak Ridge National Lab.) for use in experiments designed to study the impact of a flow blockage at the inlet to the reactor core.

  12. Amplification of interference color by using liquid crystal for protein detection

    SciTech Connect (OSTI)

    Zhu, Qingdi; Yang, Kun-Lin

    2013-12-09

    Micrometer-sized, periodic protein lines printed on a solid surface cause interference color which is invisible to the naked eye. However, the interference color can be amplified by using a thin layer of liquid crystal (LC) covered on the surface to form a phase diffraction grating. Strong interference color can thus be observed under ambient light. By using the LC-amplified interference color, we demonstrate naked-eye detection of a model proteinimmunoglobulin G (IgG). Limit of detection can reach 20??g/ml of IgG without using any instrumentation. This detection method is potentially useful for the development of low-cost and portable biosensors.

  13. Motion of Doped-Polymer-Cholesteric Liquid Crystal Flakes in a Direct-Current Electric Field

    SciTech Connect (OSTI)

    Trajkovska Petkoska, A.; Kosc, T.Z.; Marshall, K.L.; Hasman, K.; Jacobs, S.D.

    2008-05-02

    The behavior of polymer cholesteric liquid crystal (PCLC) flakes suspended in silicone oil host fluids has been explored in the presence of a direct-current electric field. In addition to neat (undoped) flakes, the PCLC material was doped with either conductive, carbon-based particles or highly dielectric inorganic particles to modify the dielectric properties of the resulting PCLC flakes. Doping with conductive particles produced flakes with a net charge, and they exhibited either translational or rotational motion depending on both the distribution of dopant within the flake and the dielectric characteristics of the host fluid. Flakes doped with titania (TiO2) particles reoriented 90 when suspended in a host fluid with a differing dielectric permittivity

  14. Nano-electromechanical rotation of graphene and giant enhancement in dielectric anisotropy in a liquid crystal

    SciTech Connect (OSTI)

    Basu, Rajratan Kinnamon, Daniel; Garvey, Alfred

    2015-05-18

    A nematic liquid crystal (LC) is doped with dilute concentrations of pristine monolayer graphene (GP) flakes, and the LC + GP hybrids are found to exhibit a dramatic increase in the dielectric anisotropy. Electric field-dependent conductance studies reveal that the graphene flakes follow the nematic director that mechanically rotates on increasing an applied electric field. Further studies show that the ?? electron stacking, between the graphene's honeycomb structure and the LC's benzene rings, stabilizes pseudo-nematic domains that collectively amplify the dielectric anisotropy by improving the orientational order parameter in the nematic phase. These anisotropic domains interact with the external electric field, resulting in a nonzero dielectric anisotropy in the isotropic phase as well. The enhancement in dielectric anisotropy, due to the LCgraphene coupling, is found to have subsequent positive impacts on the LC's orientational threshold field and elasticity that allows the nematic director to respond quicker on switching the electric field off.

  15. Characterization of submillisecond response optical addressing phase modulator based on low light scattering polymer network liquid crystal

    SciTech Connect (OSTI)

    Xiangjie, Zhao E-mail: zxjdouble@gmail.com; Cangli, Liu; Jiazhu, Duan; Dayong, Zhang; Yongquan, Luo

    2015-01-07

    Optically addressed conventional nematic liquid crystal spatial light modulator has attracted wide research interests. But the slow response speed limited its further application. In this paper, polymer network liquid crystal (PNLC) was proposed to replace the conventional nematic liquid crystal to enhance the response time to the order of submillisecond. The maximum light scattering of the employed PNLC was suppressed to be less than 2% at 1.064 μm by optimizing polymerization conditions and selecting large viscosity liquid crystal as solvent. The occurrence of phase ripple phenomenon due to electron diffusion and drift in photoconductor was found to deteriorate the phase modulation effect of the optical addressed PNLC phase modulator. The wavelength effect and AC voltage frequency effect on the on state dynamic response of phase change was investigated by experimental methods. These effects were interpreted by electron diffusion and drift theory based on the assumption that free electron was inhomogeneously distributed in accordance with the writing beam intensity distribution along the incident direction. The experimental results indicated that the phase ripple could be suppressed by optimizing the wavelength of the writing beam and the driving AC voltage frequency when varying the writing beam intensity to generate phase change in 2π range. The modulation transfer function was also measured.

  16. Kinetics of liquid-mediated crystallization of amorphous Ge from multi-frame dynamic transmission electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Santala, M. K.; Raoux, S.; Campbell, G. H.

    2015-12-24

    The kinetics of laser-induced, liquid-mediated crystallization of amorphous Ge thin films were studied using multi-frame dynamic transmission electron microscopy (DTEM), a nanosecond-scale photo-emission transmission electron microscopy technique. In these experiments, high temperature gradients are established in thin amorphous Ge films with a 12-ns laser pulse with a Gaussian spatial profile. The hottest region at the center of the laser spot crystallizes in ~100 ns and becomes nano-crystalline. Over the next several hundred nanoseconds crystallization continues radially outward from the nano-crystalline region forming elongated grains, some many microns long. The growth rate during the formation of these radial grains is measuredmore » with time-resolved imaging experiments. Crystal growth rates exceed 10 m/s, which are consistent with crystallization mediated by a very thin, undercooled transient liquid layer, rather than a purely solid-state transformation mechanism. The kinetics of this growth mode have been studied in detail under steady-state conditions, but here we provide a detailed study of liquid-mediated growth in high temperature gradients. Unexpectedly, the propagation rate of the crystallization front was observed to remain constant during this growth mode even when passing through large local temperature gradients, in stark contrast to other similar studies that suggested the growth rate changed dramatically. As a result, the high throughput of multi-frame DTEM provides gives a more complete picture of the role of temperature and temperature gradient on laser crystallization than previous DTEM experiments.« less

  17. Frustrated smectic layer structures in bent-shaped dimer liquid crystals studied by x-ray microbeam diffraction

    SciTech Connect (OSTI)

    Takanishi, Yoichi; Toshimitsu, Megumi; Nakata, Michi; Takada, Naoki; Izumi, Tatsuya; Ishikawa, Ken; Takezoe, Hideo; Watanabe, Junji; Takahashi, Yumiko; Iida, Atsuo

    2006-11-15

    The layer structures in bent-shaped liquid crystal dimers mOAM5AMOm (m=6-16) have been investigated by x-ray microbeam diffraction. These liquid crystal molecules have two rodlike mesogens connected with an odd-numbered alkylene spacer and form a bent shape. In these compounds it is found that the structure changes from the single (m=6) to frustrated-layer structures (m=8, 10, and 12) and switchable frustrated-layer structures (m=14 and 16) with increasing terminal chain length. An anticlinic antiferroelectric structure is suggested in the compound with m=16, based on the different electric-field-induced reorientation behavior from those in the other dimers.

  18. Effect of surface viscosity, anchoring energy, and cell gap on the response time of nematic liquid crystals

    SciTech Connect (OSTI)

    Souza, R.F. de; Yang, D.-Ke; Lenzi, E.K.; Evangelista, L.R.; Zola, R.S.

    2014-07-15

    An analytical expression for the relaxation time of a nematic liquid crystal is obtained for the first time by considering the influence of surface viscosity, anchoring energy strength and cell gap, validated numerically by using the so-called relaxation method. This general equation for the molecular response time (?{sub 0}) was derived for a vertical aligned cell and by solving an eigenvalue equation coming from the usual balance of torque equation in the Derzhanskii and Petrov formulation, recovering the usual equations in the appropriate limit. The results show that ??d{sup b}, where b=2 is observed only for strongly anchored cells, while for moderate to weak anchored cells, the exponent lies between 1 and 2, depending on both, surface viscosity and anchoring strength. We found that the surface viscosity is important when calculating the response time, specially for thin cells, critical for liquid crystal devices. The surface viscositys effect on the optical response time with pretilt is also explored. Our results bring new insights about the role of surface viscosity and its effects in applied physics. - Highlights: The relaxation of nematic liquid crystals is calculated by taking the surface viscosity into account. An analytical expression for the relaxation time depending on surface viscosity, anchoring strength and cell gap is obtained. The results are numerically verified. Surface viscosity is crucial for thin and weak anchored cells. The effect on optical time and pretilt angle is also studied.

  19. Beam coupling in hybrid photorefractive inorganic-cholesteric liquid crystal cells: Impact of optical rotation

    SciTech Connect (OSTI)

    Reshetnyak, V. Yu.; Pinkevych, I. P.; Sluckin, T. J.; Cook, G.; Evans, D. R.

    2014-03-14

    We develop a theoretical model to describe two-beam energy exchange in a hybrid photorefractive inorganic-cholesteric cell. A cholesteric layer is placed between two inorganic substrates. One of the substrates is photorefractive (Ce:SBN). Weak and strong light beams are incident on the hybrid cell. The interfering light beams induce a periodic space-charge field in the photorefractive window. This penetrates into the cholesteric liquid crystal (LC), inducing a diffraction grating written on the LC director. In the theory, the flexoelectric mechanism for electric field-director coupling is more important than the LC static dielectric anisotropy coupling. The LC optics is described in the Bragg regime. Each beam induces two circular polarized waves propagating in the cholesteric cell with different velocities. The model thus includes optical rotation in the cholesteric LC. The incident light beam wavelength can fall above, below, or inside the cholesteric gap. The theory calculates the energy gain of the weak beam, as a result of its interaction with the pump beam within the diffraction grating. Theoretical results for exponential gain coefficients are compared with experimental results for hybrid cells filled with cholesteric mixture BL038/CB15 at different concentrations of chiral agent CB15. Reconciliation between theory and experiment requires the inclusion of a phenomenological multiplier in the magnitude of the director grating. This multiplier is cubic in the space-charge field, and we provide a justification of the q-dependence of the multiplier. Within this paradigm, we are able to fit theory to experimental data for cholesteric mixtures with different spectral position of cholesteric gap relative to the wavelength of incident beams, subject to the use of some fitting parameters.

  20. Method of forming single crystals of beta silicon carbide using liquid lithium as a solvent

    DOE Patents [OSTI]

    Lundberg, Lynn B.

    1982-01-01

    A method of growing single crystals of beta SiC from solution using molten lithium as a solvent for polycrystalline SiC feed material. Reasonable growth rates are accomplished at temperatures in the range of about 1330.degree. C. to about 1500.degree. C.

  1. Electrically switchable polymer liquid crystal and polymer birefringent flake in fluid host systems and optical devices utilizing same

    DOE Patents [OSTI]

    Marshall, Kenneth L.; Kosc, Tanya Z.; Jacobs, Stephen D.; Faris, Sadeg M.; Li, Le

    2003-12-16

    Flakes or platelets of polymer liquid crystals (PLC) or other birefringent polymers (BP) suspended in a fluid host medium constitute a system that can function as the active element in an electrically switchable optical device when the suspension is either contained between a pair of rigid substrates bearing transparent conductive coatings or dispersed as microcapsules within the body of a flexible host polymer. Optical properties of these flake materials include large effective optical path length, different polarization states and high angular sensitivity in their selective reflection or birefringence. The flakes or platelets of these devices need only a 3-20.degree. rotation about the normal to the cell surface to achieve switching characteristics obtainable with prior devices using particle rotation or translation.

  2. Quantitative analysis of the x-ray diffraction intensities of undulated smectic phases in bent-core liquid crystals

    SciTech Connect (OSTI)

    Folcia, C. L.; Etxebarria, J.; Ortega, J.

    2007-07-15

    X-ray diffraction diagrams of undulated smectic phases in bent-core liquid crystals have been theoretically studied. The intensities of the reflections have been obtained for different layer modulations, and a general expression has been deduced for orthogonal cells in terms of the different harmonics of the distortion. The case of sinusoidal modulation is especially simple and has been studied also in oblique cells. High-quality x-ray measurements of three compounds reported in the literature have been analyzed as examples. In all cases it has been deduced that the modulation is sinusoidal and its amplitude has been easily obtained by fitting the experimental intensities. Equatorial (h0) reflections have been also considered to obtain information about the structure of defects at the maxima and minima of the undulation.

  3. Nanophase Segregation in Binary Mixtures of a Bent-Core and a Rodlike Liquid-Crystal Molecule

    SciTech Connect (OSTI)

    Zhu, C.; Chen, D; Shen, Y; Jones, C; Glaser, M; Maclennan, J; Clark, N

    2010-01-01

    We studied mixtures of the achiral bent-core mesogen NOBOW 1,3-phenylene bis[4-(4-9-alkoxyphenyliminonetyl)benzoates] (P-9-O-PIMB) and the small, rodlike liquid crystal 8CB using high-resolution synchrotron x-ray diffraction, freeze fracture transmission electron microscopy, and differential scanning calorimetry. NOBOW and 8CB mix in an isotropic state at high temperatures but phase separate at lower temperatures when NOBOW transforms into the B4 phase and forms chiral helical nanofilaments. In pure NOBOW, the nanofilaments are close packed but at moderate 8CB concentrations, they are separated by nanosized gaps filled by 8CB. At higher concentrations of 8CB, macroscopic phase separation occurs.

  4. Structural study of a bent-core liquid crystal showing the B{sub 1}-B{sub 2} transition

    SciTech Connect (OSTI)

    Folcia, Cesar Luis; Etxebarria, J.; Ortega, J.; Ros, M. B.

    2006-09-15

    An experimental study of the B{sub 1}-B{sub 2} transition is carried out in a bent-core liquid crystal. The study is essentially based on x-ray measurements as a function of temperature. The B{sub 1}-B{sub 2} transition is extremely unusual and implies a deep structural change from a columnar phase to a lamellar phase. We have found that the B{sub 1} phase in our compound is similar to the so-called B{sub 1} reversed phase, with an additional splay of the polarization in the columns. On approaching the B{sub 2} phase the width of the cross section of the columns increases. The transition is clearly first order, with a large hysteresis though the enthalpy content is very small. A possible mechanism for the transition is briefly sketched.

  5. Order-parameter-aided temperature-accelerated sampling for the exploration of crystal polymorphism and solid-liquid phase transitions

    SciTech Connect (OSTI)

    Yu, Tang-Qing Vanden-Eijnden, Eric; Chen, Pei-Yang; Chen, Ming; Samanta, Amit; Tuckerman, Mark

    2014-06-07

    The problem of predicting polymorphism in atomic and molecular crystals constitutes a significant challenge both experimentally and theoretically. From the theoretical viewpoint, polymorphism prediction falls into the general class of problems characterized by an underlying rough energy landscape, and consequently, free energy based enhanced sampling approaches can be brought to bear on the problem. In this paper, we build on a scheme previously introduced by two of the authors in which the lengths and angles of the supercell are targeted for enhanced sampling via temperature accelerated adiabatic free energy dynamics [T. Q. Yu and M. E. Tuckerman, Phys. Rev. Lett. 107, 015701 (2011)]. Here, that framework is expanded to include general order parameters that distinguish different crystalline arrangements as target collective variables for enhanced sampling. The resulting free energy surface, being of quite high dimension, is nontrivial to reconstruct, and we discuss one particular strategy for performing the free energy analysis. The method is applied to the study of polymorphism in xenon crystals at high pressure and temperature using the Steinhardt order parameters without and with the supercell included in the set of collective variables. The expected fcc and bcc structures are obtained, and when the supercell parameters are included as collective variables, we also find several new structures, including fcc states with hcp stacking faults. We also apply the new method to the solid-liquid phase transition in copper at 1300 K using the same Steinhardt order parameters. Our method is able to melt and refreeze the system repeatedly, and the free energy profile can be obtained with high efficiency.

  6. Quenched crystal-field disorder and magnetic liquid ground states in Tb₂Sn2-xTixO₇

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaulin, B. D.; Kermarrec, E.; Dahlberg, M. L.; Matthews, M. J.; Bert, F.; Zhang, J.; Mendels, P.; Fritsch, K.; Granroth, G. E.; Jiramongkolchai, P.; et al

    2015-06-18

    Solid solutions of the “soft” quantum spin ice pyrochlore magnets Tb₂B₂O₇ with B = Ti and Sn display a novel magnetic ground state in the presence of strong B-site disorder, characterized by a low susceptibility and strong spin fluctuations to temperatures below 0.1 K. These materials have been studied using ac susceptibility and μSR techniques to very low temperatures, and time-of-flight inelastic neutron scattering techniques to 1.5 K. Remarkably, neutron spectroscopy of the Tb³⁺ crystal-field levels appropriate to high B-site mixing (0.5 < x < 1.5 in Tb₂Sn2-xTixO₇) reveal that the doublet ground and first excited states present as continuamore » in energy, while transitions to singlet excited states at higher energies simply interpolate between those of the end members of the solid solution. The resulting ground state suggests an extreme version of a random-anisotropy magnet, with many local moments and anisotropies, depending on the precise local configuration of the six B sites neighboring each magnetic Tb³⁺ ion.« less

  7. Magnetic field induced quantum dot brightening in liquid crystal synergized magnetic and semiconducting nanoparticle composite assemblies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Amaral, Jose Jussi; Wan, Jacky; Rodarte, Andrea L.; Ferri, Christopher; Quint, Makiko T.; Pandolfi, Ronald J.; Scheibner, Michael; Hirst, Linda S.; Ghosh, Sayantani

    2014-10-22

    The design and development of multifunctional composite materials from artificial nano-constituents is one of the most compelling current research areas. This drive to improve over nature and produce ‘meta-materials’ has met with some success, but results have proven limited with regards to both the demonstration of synergistic functionalities and in the ability to manipulate the material properties post-fabrication and in situ. Here, magnetic nanoparticles (MNPs) and semiconducting quantum dots (QDs) are co-assembled in a nematic liquid crystalline (LC) matrix, forming composite structures in which the emission intensity of the quantum dots is systematically and reversibly controlled with a small appliedmore » magnetic field (<100 mT). This magnetic field-driven brightening, ranging between a two- to three-fold peak intensity increase, is a truly cooperative effect: the LC phase transition creates the co-assemblies, the clustering of the MNPs produces LC re-orientation at atypical low external field, and this re-arrangement produces compaction of the clusters, resulting in the detection of increased QD emission. These results demonstrate a synergistic, reversible, and an all-optical process to detect magnetic fields and additionally, as the clusters are self-assembled in a fluid medium, they offer the possibility for these sensors to be used in broad ranging fluid-based applications.« less

  8. Magnetic field induced quantum dot brightening in liquid crystal synergized magnetic and semiconducting nanoparticle composite assemblies

    SciTech Connect (OSTI)

    Amaral, Jose Jussi; Wan, Jacky; Rodarte, Andrea L.; Ferri, Christopher; Quint, Makiko T.; Pandolfi, Ronald J.; Scheibner, Michael; Hirst, Linda S.; Ghosh, Sayantani

    2014-10-22

    The design and development of multifunctional composite materials from artificial nano-constituents is one of the most compelling current research areas. This drive to improve over nature and produce meta-materials has met with some success, but results have proven limited with regards to both the demonstration of synergistic functionalities and in the ability to manipulate the material properties post-fabrication and in situ. Here, magnetic nanoparticles (MNPs) and semiconducting quantum dots (QDs) are co-assembled in a nematic liquid crystalline (LC) matrix, forming composite structures in which the emission intensity of the quantum dots is systematically and reversibly controlled with a small applied magnetic field (<100 mT). This magnetic field-driven brightening, ranging between a two- to three-fold peak intensity increase, is a truly cooperative effect: the LC phase transition creates the co-assemblies, the clustering of the MNPs produces LC re-orientation at atypical low external field, and this re-arrangement produces compaction of the clusters, resulting in the detection of increased QD emission. These results demonstrate a synergistic, reversible, and an all-optical process to detect magnetic fields and additionally, as the clusters are self-assembled in a fluid medium, they offer the possibility for these sensors to be used in broad ranging fluid-based applications.

  9. Electronic and vibronic properties of a discotic liquid-crystal and its charge transfer complex

    SciTech Connect (OSTI)

    Haverkate, Lucas A.; Mulder, Fokko M.; Zbiri, Mohamed Johnson, Mark R.; Carter, Elizabeth; Kotlewski, Arek; Picken, S.

    2014-01-07

    Discotic liquid crystalline (DLC) charge transfer (CT) complexes combine visible light absorption and rapid charge transfer characteristics, being favorable properties for photovoltaic (PV) applications. We present a detailed study of the electronic and vibrational properties of the prototypic 1:1 mixture of discotic 2,3,6,7,10,11-hexakishexyloxytriphenylene (HAT6) and 2,4,7-trinitro-9-fluorenone (TNF). It is shown that intermolecular charge transfer occurs in the ground state of the complex: a charge delocalization of about 10{sup ?2} electron from the HAT6 core to TNF is deduced from both Raman and our previous NMR measurements [L. A. Haverkate, M. Zbiri, M. R. Johnson, B. Deme, H. J. M. de Groot, F. Lefeber, A. Kotlewski, S. J. Picken, F. M. Mulder, and G. J. Kearley, J. Phys. Chem. B 116, 13098 (2012)], implying the presence of permanent dipoles at the donor-acceptor interface. A combined analysis of density functional theory calculations, resonant Raman and UV-VIS absorption measurements indicate that fast relaxation occurs in the UV region due to intramolecular vibronic coupling of HAT6 quinoidal modes with lower lying electronic states. Relatively slower relaxation in the visible region the excited CT-band of the complex is also indicated, which likely involves motions of the TNF nitro groups. The fast quinoidal relaxation process in the hot UV band of HAT6 relates to pseudo-Jahn-Teller interactions in a single benzene unit, suggesting that the underlying vibronic coupling mechanism can be generic for polyaromatic hydrocarbons. Both the presence of ground state CT dipoles and relatively slow relaxation processes in the excited CT band can be relevant concerning the design of DLC based organic PV systems.

  10. Photovoltaic properties and morphology of organic solar cells based on liquid-crystal semiconducting polymer with additive

    SciTech Connect (OSTI)

    Suzuki, Atsushi; Zushi, Masahito; Suzuki, Hisato; Ogahara, Shinichi; Akiyama, Tsuyoshi; Oku, Takeo

    2014-02-20

    Bulk heterojunction organic solar cell based on liquid crystal semiconducting polymers of poly[9,9-dioctylfluorene-co-bithiophene] (F8T2) as p-type semiconductors and fullerenes (C{sub 60}) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as electron donor and acceptor has been fabricated and characterized for improving photovoltaic and optical properties. The photovoltaic performance including current voltage curves in the dark and illumination of the F8T2/C{sub 60} conventional and inverted bulk heterojunction solar cells were investigated. Relationship between the photovoltaic properties and morphological behavior was focused on tuning for optimization of photo-voltaic performance under annealing condition near glass transition temperature. Additive-effect of diiodooctane (DIO) and poly(3-hexylthiophene-2,5-diyl) (P3HT) on the photovoltaic performance and optical properties was investigated. Mechanism of the photovoltaic properties of the conventional and inverted solar cells will be discussed by the experimental results.

  11. A model-free temperature-dependent conformational study of n-pentane in nematic liquid crystals

    SciTech Connect (OSTI)

    Burnell, E. Elliott; Weber, Adrian C. J.; Dong, Ronald Y.; Meerts, W. Leo; Lange, Cornelis A. de

    2015-01-14

    The proton NMR spectra of n-pentane orientationally ordered in two nematic liquid-crystal solvents are studied over a wide temperature range and analysed using covariance matrix adaptation evolutionary strategy. Since alkanes possess small electrostatic moments, their anisotropic intermolecular interactions are dominated by short-range size-and-shape effects. As we assumed for n-butane, the anisotropic energy parameters of each n-pentane conformer are taken to be proportional to those of ethane and propane, independent of temperature. The observed temperature dependence of the n-pentane dipolar couplings allows a model-free separation between conformer degrees of order and conformer probabilities, which cannot be achieved at a single temperature. In this way for n-pentane 13 anisotropic energy parameters (two for trans trans, tt, five for trans gauche, tg, and three for each of gauche{sub +} gauche{sub +}, pp, and gauche{sub +} gauche{sub −}, pm), the isotropic trans-gauche energy difference E{sub tg} and its temperature coefficient E{sub tg}{sup ′} are obtained. The value obtained for the extra energy associated with the proximity of the two methyl groups in the gauche{sub +} gauche{sub −} conformers (the pentane effect) is sensitive to minute details of other assumptions and is thus fixed in the calculations. Conformer populations are affected by the environment. In particular, anisotropic interactions increase the trans probability in the ordered phase.

  12. Role of Molecular Structure on X-ray Diffraction in Thermotropic Uniaxial and Biaxial Nematic Liquid Crystal Phases

    SciTech Connect (OSTI)

    Acharya, Bharat R.; Kang, Shin-Woong; Prasad, Veena; Kumar, Satyendra

    2009-08-27

    X-ray diffraction is one of the most definitive methods to determine the structure of condensed matter phases, and it has been applied to unequivocally infer the structures of conventional calamitic and lyotropic liquid crystals. With the advent of bent-core and tetrapodic mesogens and the discovery of the biaxial nematic phase in them, the experimental results require more careful interpretation and analysis. Here, we present ab-initio calculations of X-ray diffraction patterns in the isotropic, uniaxial nematic, and biaxial nematic phases of bent-core mesogens. A simple Meier-Saupe-like molecular distribution function is employed to describe both aligned and unaligned mesophases. The distribution function is decomposed into two, polar and azimuthal, distribution functions to calculate the effect of the evolution of uniaxial and biaxial nematic orientational order. The calculations provide satisfactory semiquantitative interpretations of experimental results. The calculations presented here should provide a pathway to more refined and quantitative analysis of X-ray diffraction data from the biaxial nematic phase.

  13. Role of Molecular Structure on X-ray Diffraction in Uniaxial and Biaxial Phases of Thermotropic Liquid Crystals

    SciTech Connect (OSTI)

    Acharya, Bharat R.; Kang, Shin-Woong; Prasad, Veena; Kumar, Satyendra

    2009-04-29

    X-ray diffraction is one of the most definitive methods to determine the structure of condensed matter phases, and it has been applied to unequivocally infer the structures of conventional calamitic and lyotropic liquid crystals. With the advent of bent-core and tetrapodic mesogens and the discovery of the biaxial nematic phase in them, the experimental results require more careful interpretation and analysis. Here, we present ab-initio calculations of X-ray diffraction patterns in the isotropic, uniaxial nematic, and biaxial nematic phases of bent-core mesogens. A simple Meier-Saupe-like molecular distribution function is employed to describe both aligned and unaligned mesophases. The distribution function is decomposed into two, polar and azimuthal, distribution functions to calculate the effect of the evolution of uniaxial and biaxial nematic orientational order. The calculations provide satisfactory semiquantitative interpretations of experimental results. The calculations presented here should provide a pathway to more refined and quantitative analysis of X-ray diffraction data from the biaxial nematic phase.

  14. A simple technique to reduce evaporation of crystallization droplets by using plate lids with apertures for adding liquids

    SciTech Connect (OSTI)

    Zipper, Lauren E.; Aristide, Xavier; Bishop, Dylan P.; Joshi, Ishita; Kharzeev, Julia; Patel, Krishna B.; Santiago, Brianna M.; Joshi, Karan; Dorsinvil, Kahille; Sweet, Robert M.; Soares, Alexei S.

    2014-11-28

    A method is described for using plate lids to reduce evaporation in low-volume vapor-diffusion crystallization experiments. The plate lids contain apertures through which the protein and precipitants were added to different crystallization microplates (the reservoir was filled before fitting the lids). Plate lids were designed for each of these commonly used crystallization microplates. This system minimizes the dehydration of crystallization droplets containing just a few nanolitres of protein and precipitant, and results in more reproducible diffraction from the crystals. For each lid design, changes in the weight of the plates were used to deduce the rate of evaporation under different conditions of temperature, air movement, droplet size and precipitant. For comparison, the state of dehydration was also visually assessed throughout the experiment. Finally, X-ray diffraction methods were used to compare the diffraction of protein crystals that were conventionally prepared against those that were prepared on plates with plate lids. The measurements revealed that the plate lids reduced the rate of evaporation by 63–82%. Crystals grown in 5 nl drops that were set up with plate lids diffracted to higher resolution than similar crystals from drops that were set up without plate lids. Ultimately, the results demonstrate that plate lids can be instrumental for improving few-nanolitre crystallizations.

  15. A simple technique to reduce evaporation of crystallization droplets by using plate lids with apertures for adding liquids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zipper, Lauren E.; Aristide, Xavier; Bishop, Dylan P.; Joshi, Ishita; Kharzeev, Julia; Patel, Krishna B.; Santiago, Brianna M.; Joshi, Karan; Dorsinvil, Kahille; Sweet, Robert M.; et al

    2014-11-28

    A method is described for using plate lids to reduce evaporation in low-volume vapor-diffusion crystallization experiments. The plate lids contain apertures through which the protein and precipitants were added to different crystallization microplates (the reservoir was filled before fitting the lids). Plate lids were designed for each of these commonly used crystallization microplates. This system minimizes the dehydration of crystallization droplets containing just a few nanolitres of protein and precipitant, and results in more reproducible diffraction from the crystals. For each lid design, changes in the weight of the plates were used to deduce the rate of evaporation under differentmore » conditions of temperature, air movement, droplet size and precipitant. For comparison, the state of dehydration was also visually assessed throughout the experiment. Finally, X-ray diffraction methods were used to compare the diffraction of protein crystals that were conventionally prepared against those that were prepared on plates with plate lids. The measurements revealed that the plate lids reduced the rate of evaporation by 63–82%. Crystals grown in 5 nl drops that were set up with plate lids diffracted to higher resolution than similar crystals from drops that were set up without plate lids. Ultimately, the results demonstrate that plate lids can be instrumental for improving few-nanolitre crystallizations.« less

  16. A simple technique to reduce evaporation of crystallization droplets by using plate lids with apertures for adding liquids

    SciTech Connect (OSTI)

    Zipper, Lauren E.; Aristide, Xavier; Bishop, Dylan P.; Joshi, Ishita; Kharzeev, Julia; Patel, Krishna B.; Santiago, Brianna M.; Joshi, Karan; Dorsinvil, Kahille; Sweet, Robert M.; Soares, Alexei S.

    2014-11-28

    This article describes the use of evaporation control lids that are fitted to crystallization plates to improve the reproducibility of trials using as little as 5 nl. The plate lids contain apertures which are large enough for the transfer of protein containing droplets, but small enough to greatly reduce the rate of evaporation during the time needed to prepare the plate. A method is described for using plate lids to reduce evaporation in low-volume vapor-diffusion crystallization experiments. The plate lids contain apertures through which the protein and precipitants were added to different crystallization microplates (the reservoir was filled before fitting the lids). Plate lids were designed for each of these commonly used crystallization microplates. This system minimizes the dehydration of crystallization droplets containing just a few nanolitres of protein and precipitant, and results in more reproducible diffraction from the crystals. For each lid design, changes in the weight of the plates were used to deduce the rate of evaporation under different conditions of temperature, air movement, droplet size and precipitant. For comparison, the state of dehydration was also visually assessed throughout the experiment. Finally, X-ray diffraction methods were used to compare the diffraction of protein crystals that were conventionally prepared against those that were prepared on plates with plate lids. The measurements revealed that the plate lids reduced the rate of evaporation by 63–82%. Crystals grown in 5 nl drops that were set up with plate lids diffracted to higher resolution than similar crystals from drops that were set up without plate lids. The results demonstrate that plate lids can be instrumental for improving few-nanolitre crystallizations.

  17. Supercritical-assistant liquid crystal template approach to synthesize mesoporous titania/multiwalled carbon nanotube composites with high visible-light driven photocatalytic performance

    SciTech Connect (OSTI)

    Liu, Chen; Li, Youji Xu, Peng; Li, Ming; Huo, Pingxiang

    2014-12-15

    Graphical abstract: We investigate the influence of mesoporous titania content upon the visible-light driven photocatalytic performance of MPT/MWCNTs in phenol degradation. - Highlights: • MPT/MWCNTs were fabricated by liquid-crystal template in supercritical CO{sub 2}. • MPT/MWCNTs show high visible-light driven photoactivity for phenol degradation. • MPT/MWCNTs also show high reusable photoactivity under visible irradiation. • MPT content can control visible-light driven photoactivity of MPT/MWCNTs. • MPT is not easily broken away from from MPT/MWCNT composites. - Abstract: Mesoporous titania (MPT) was deposited onto multiwalled carbon nanotubes (MWCNTs) by deposition of titanium sol containing liquid-crystal template with assistant of supercritical CO{sub 2}. The products were characterized with various analytical techniques to determine their structural, morphological, optical absorption and photocatalytic properties. The results indicate that in photocatalytic degradation of phenol under visible light, the mixtures or composites of MPT and MWCNT show the high efficiency because of synergies between absorbing visible light, releasing electrons and facilitating transfer of charge carriers of MWCNTs and providing activated centers of MPT. Because of the mutual constraint between MPT and MWCNTs on the photocatalytic efficiency, the optimal loading of MPT in MPT/MWCNT-3 for phenol degradation is 48%. Because the intimate contact between MWCNTs and MPT is more beneficial to electron transformation, photoactivity of mixture is lower than that of composites with high reusable performance. The optimum conditions of phenol degradation were obtained.

  18. ELECTROLUMINESCENT MATERIAL FOR FLAT PANEL DISPLAY

    SciTech Connect (OSTI)

    Smith, D.B.

    2000-11-13

    The purpose of this Cooperative Research and Development Agreement (CRADA) was to develop a new-generation electroluminescent (EL) material for flat panel displays and related applications by using unique and complementary research capabilities at Oak Ridge National Laboratory and OSRAM Sylvania, Inc. The goal was to produce an EL material with a luminance 10 times greater than conventional EL phosphors. An EL material with this increased luminance would have immediate applications for flat panel display devices (e.g., backlighting for liquid-crystal diodes) and for EL lamp technology. OSRAM Sylvania proposed that increased EL phosphor luminance could be obtained by creating composite EL materials capable of alignment under an applied electric field and capable of concentrating the applied electric field. Oak Ridge National Laboratory used pulsed laser deposition as a method for making these composite EL materials. The materials were evaluated for electroluminescence at laboratory facilities at OSRAM Sylvania, Inc. Many composite structures were thus made and evaluated, and it was observed that a composite structure based on alternating layers of a ferroelectric and a phosphor yielded electroluminescence. An enabling step that was not initially proposed but was conceived during the cooperative effort was found to be crucial to the success of the composite structure. The CRADA period expired before we were able to make quantitative measurements of the luminance and efficiency of the composite EL material. Future cooperative work, outside the scope of the CRADA, will focus on making these measurements and will result in the production of a prototype composite EL device.

  19. Thin optical display panel

    DOE Patents [OSTI]

    Veligdan, James Thomas

    1997-01-01

    An optical display includes a plurality of optical waveguides each including a cladding bound core for guiding internal display light between first and second opposite ends by total internal reflection. The waveguides are stacked together to define a collective display thickness. Each of the cores includes a heterogeneous portion defining a light scattering site disposed longitudinally between the first and second ends. Adjacent ones of the sites are longitudinally offset from each other for forming a longitudinal internal image display over the display thickness upon scattering of internal display light thereagainst for generating a display image. In a preferred embodiment, the waveguides and scattering sites are transparent for transmitting therethrough an external image in superposition with the display image formed by scattering the internal light off the scattering sites for defining a heads up display.

  20. Cytoplasmic bacteriophage display system

    DOE Patents [OSTI]

    Studier, F.W.; Rosenberg, A.H.

    1998-06-16

    Disclosed are display vectors comprising DNA encoding a portion of a structural protein from a cytoplasmic bacteriophage, joined covalently to a protein or peptide of interest. Exemplified are display vectors wherein the structural protein is the T7 bacteriophage capsid protein. More specifically, in the exemplified display vectors the C-terminal amino acid residue of the portion of the capsid protein is joined to the N-terminal residue of the protein or peptide of interest. The portion of the T7 capsid protein exemplified comprises an N-terminal portion corresponding to form 10B of the T7 capsid protein. The display vectors are useful for high copy number display or lower copy number display (with larger fusion). Compositions of the type described herein are useful in connection with methods for producing a virus displaying a protein or peptide of interest. 1 fig.

  1. Cytoplasmic bacteriophage display system

    DOE Patents [OSTI]

    Studier, F. William; Rosenberg, Alan H.

    1998-06-16

    Disclosed are display vectors comprising DNA encoding a portion of a structural protein from a cytoplasmic bacteriophage, joined covalently to a protein or peptide of interest. Exemplified are display vectors wherein the structural protein is the T7 bacteriophage capsid protein. More specifically, in the exemplified display vectors the C-terminal amino acid residue of the portion of the capsid protein is joined to the N-terminal residue of the protein or peptide of interest. The portion of the T7 capsid protein exemplified comprises an N-terminal portion corresponding to form 10B of the T7 capsid protein. The display vectors are useful for high copy number display or lower copy number display (with larger fusion). Compositions of the type described herein are useful in connection with methods for producing a virus displaying a protein or peptide of interest.

  2. Crystallization process

    SciTech Connect (OSTI)

    Adler, Robert J.; Brown, William R.; Auyang, Lun; Liu, Yin-Chang; Cook, W. Jeffrey

    1986-01-01

    An improved crystallization process is disclosed for separating a crystallizable material and an excluded material which is at least partially excluded from the solid phase of the crystallizable material obtained upon freezing a liquid phase of the materials. The solid phase is more dense than the liquid phase, and it is separated therefrom by relative movement with the formation of a packed bed of solid phase. The packed bed is continuously formed adjacent its lower end and passed from the liquid phase into a countercurrent flow of backwash liquid. The packed bed extends through the level of the backwash liquid to provide a drained bed of solid phase adjacent its upper end which is melted by a condensing vapor.

  3. Characterization of a chiral phase in an achiral bent-core liquid crystal by polarization studies of resonant x-ray forbidden reflections

    SciTech Connect (OSTI)

    Ponsinet, V.; Pindak, R.; Barois, P.; Pan, L.; Wang, S.; Huang, C.C.; Wang, S.T.; Baumeister, U. and Weissflog, W.

    2011-07-15

    The chiral antiferroelectric structure of an achiral bent-core liquid crystal is characterized by resonant x-ray scattering at chlorine K edge. The 'forbidden' reflections resulting from the glide or screw symmetry elements are restored by the anisotropy of the tensor structure factor, which we calculate for two possible structural models. A careful analysis of the polarization states of the restored 'forbidden' reflections enables an unambiguous identification of a chiral structure (i.e., the so-called anticlinic, antiferroelectric smectic-C or Sm-C{sub A}P{sub A}) coexisting with the achiral synclinic antiferroelectric smectic-C or Sm-C{sub S}P{sub A}. The method proves to be quite powerful as it identifies the chiral structure within coexisting phases despite an imperfect orientation of the sample. The volume fraction of the chiral phase and the distribution of alignment are extracted from the data.

  4. Detection of a new 'nematic-like' phase in liquid crystal-amphiphile mixture by differential scanning calorimetry

    SciTech Connect (OSTI)

    Dan, Kaustabh Roy, Madhusudan Datta, Alokmay

    2014-04-24

    Differential Scanning Calorimetry (DSC) studies on phase transitions of the pure liquid crystalline material N-4-methoxybenzylidene-4-butylaniline (MBBA) and mixtures of MBBA and the amphiphile Stearic Acid (StA) show significant changes in the behavior of mixture from pure MBBA, as regards the nematic-isotropic (N-I) transition temperature (T{sub c}) and other thermodynamic parameters like enthalpy, specific heat and activation energy with concentration of StA. In particular, the convexity of the Arrhenius plot in pure MBBA vanishes with StA concentration pointing to the formation of a new, perhaps 'nematic-like', phase in the mixtures.

  5. Split image optical display

    DOE Patents [OSTI]

    Veligdan, James T.

    2005-05-31

    A video image is displayed from an optical panel by splitting the image into a plurality of image components, and then projecting the image components through corresponding portions of the panel to collectively form the image. Depth of the display is correspondingly reduced.

  6. Split image optical display

    DOE Patents [OSTI]

    Veligdan, James T.

    2007-05-29

    A video image is displayed from an optical panel by splitting the image into a plurality of image components, and then projecting the image components through corresponding portions of the panel to collectively form the image. Depth of the display is correspondingly reduced.

  7. Public Displays of Efficiency

    Broader source: Energy.gov [DOE]

    Imagine if an electronic billboard displayed how much energy you used this morning, or you stepped outside to see your energy savings painted on the street for passersby to see. For some Better Buildings neighborhoods, these public displays are popping up—and they're helping call attention to saving energy.

  8. Polyplanar optical display electronics

    SciTech Connect (OSTI)

    DeSanto, L.; Biscardi, C.

    1997-07-01

    The Polyplanar Optical Display (POD) is a unique display screen which can be used with any projection source. The prototype ten inch display is two inches thick and has a matte black face which allows for high contrast images. The prototype being developed is a form, fit and functional replacement display for the B-52 aircraft which uses a monochrome ten-inch display. In order to achieve a long lifetime, the new display uses a 100 milliwatt green solid-state laser (10,000 hr. life) at 532 nm as its light source. To produce real-time video, the laser light is being modulated by a Digital Light Processing (DLP{trademark}) chip manufactured by Texas Instruments. In order to use the solid-state laser as the light source and also fit within the constraints of the B-52 display, the Digital Micromirror Device (DMD{trademark}) circuit board is removed from the Texas Instruments DLP light engine assembly. Due to the compact architecture of the projection system within the display chassis, the DMD{trademark} chip is operated remotely from the Texas Instruments circuit board. The authors discuss the operation of the DMD{trademark} divorced from the light engine and the interfacing of the DMD{trademark} board with various video formats (CVBS, Y/C or S-video and RGB) including the format specific to the B-52 aircraft. A brief discussion of the electronics required to drive the laser is also presented.

  9. Integrated display scanner

    DOE Patents [OSTI]

    Veligdan, James T.

    2004-12-21

    A display scanner includes an optical panel having a plurality of stacked optical waveguides. The waveguides define an inlet face at one end and a screen at an opposite end, with each waveguide having a core laminated between cladding. A projector projects a scan beam of light into the panel inlet face for transmission from the screen as a scan line to scan a barcode. A light sensor at the inlet face detects a return beam reflected from the barcode into the screen. A decoder decodes the return beam detected by the sensor for reading the barcode. In an exemplary embodiment, the optical panel also displays a visual image thereon.

  10. Method of fabrication of display pixels driven by silicon thin film transistors

    DOE Patents [OSTI]

    Carey, Paul G.; Smith, Patrick M.

    1999-01-01

    Display pixels driven by silicon thin film transistors are fabricated on plastic substrates for use in active matrix displays, such as flat panel displays. The process for forming the pixels involves a prior method for forming individual silicon thin film transistors on low-temperature plastic substrates. Low-temperature substrates are generally considered as being incapable of withstanding sustained processing temperatures greater than about 200.degree. C. The pixel formation process results in a complete pixel and active matrix pixel array. A pixel (or picture element) in an active matrix display consists of a silicon thin film transistor (TFT) and a large electrode, which may control a liquid crystal light valve, an emissive material (such as a light emitting diode or LED), or some other light emitting or attenuating material. The pixels can be connected in arrays wherein rows of pixels contain common gate electrodes and columns of pixels contain common drain electrodes. The source electrode of each pixel TFT is connected to its pixel electrode, and is electrically isolated from every other circuit element in the pixel array.

  11. Automated High Throughput Protein Crystallization Screening at Nanoliter Scale and Protein Structural Study on Lactate Dehydrogenase

    SciTech Connect (OSTI)

    Fenglei Li

    2006-08-09

    The purposes of our research were: (1) To develop an economical, easy to use, automated, high throughput system for large scale protein crystallization screening. (2) To develop a new protein crystallization method with high screening efficiency, low protein consumption and complete compatibility with high throughput screening system. (3) To determine the structure of lactate dehydrogenase complexed with NADH by x-ray protein crystallography to study its inherent structural properties. Firstly, we demonstrated large scale protein crystallization screening can be performed in a high throughput manner with low cost, easy operation. The overall system integrates liquid dispensing, crystallization and detection and serves as a whole solution to protein crystallization screening. The system can dispense protein and multiple different precipitants in nanoliter scale and in parallel. A new detection scheme, native fluorescence, has been developed in this system to form a two-detector system with a visible light detector for detecting protein crystallization screening results. This detection scheme has capability of eliminating common false positives by distinguishing protein crystals from inorganic crystals in a high throughput and non-destructive manner. The entire system from liquid dispensing, crystallization to crystal detection is essentially parallel, high throughput and compatible with automation. The system was successfully demonstrated by lysozyme crystallization screening. Secondly, we developed a new crystallization method with high screening efficiency, low protein consumption and compatibility with automation and high throughput. In this crystallization method, a gas permeable membrane is employed to achieve the gentle evaporation required by protein crystallization. Protein consumption is significantly reduced to nanoliter scale for each condition and thus permits exploring more conditions in a phase diagram for given amount of protein. In addition

  12. Photonic crystal light source

    DOE Patents [OSTI]

    Fleming, James G.; Lin, Shawn-Yu; Bur, James A.

    2004-07-27

    A light source is provided by a photonic crystal having an enhanced photonic density-of-states over a band of frequencies and wherein at least one of the dielectric materials of the photonic crystal has a complex dielectric constant, thereby producing enhanced light emission at the band of frequencies when the photonic crystal is heated. The dielectric material can be a metal, such as tungsten. The spectral properties of the light source can be easily tuned by modification of the photonic crystal structure and materials. The photonic crystal light source can be heated electrically or other heating means. The light source can further include additional photonic crystals that exhibit enhanced light emission at a different band of frequencies to provide for color mixing. The photonic crystal light source may have applications in optical telecommunications, information displays, energy conversion, sensors, and other optical applications.

  13. Microgap flat panel display

    DOE Patents [OSTI]

    Wuest, Craig R.

    1998-01-01

    A microgap flat panel display which includes a thin gas-filled display tube that utilizes switched X-Y "pixel" strips to trigger electron avalanches and activate a phosphor at a given location on a display screen. The panel utilizes the principal of electron multiplication in a gas subjected to a high electric field to provide sufficient electron current to activate standard luminescent phosphors located on an anode. The X-Y conductive strips of a few micron widths may for example, be deposited on opposite sides of a thin insulating substrate, or on one side of the adjacent substrates and function as a cathode. The X-Y strips are separated from the anode by a gap filled with a suitable gas. Electrical bias is selectively switched onto X and Y strips to activate a "pixel" in the region where these strips overlap. A small amount of a long-lived radioisotope is used to initiate an electron avalanche in the overlap region when bias is applied. The avalanche travels through the gas filled gap and activates a luminescent phosphor of a selected color. The bias is adjusted to give a proportional electron multiplication to control brightness for given pixel.

  14. Microgap flat panel display

    DOE Patents [OSTI]

    Wuest, C.R.

    1998-12-08

    A microgap flat panel display is disclosed which includes a thin gas-filled display tube that utilizes switched X-Y ``pixel`` strips to trigger electron avalanches and activate a phosphor at a given location on a display screen. The panel utilizes the principal of electron multiplication in a gas subjected to a high electric field to provide sufficient electron current to activate standard luminescent phosphors located on an anode. The X-Y conductive strips of a few micron widths may for example, be deposited on opposite sides of a thin insulating substrate, or on one side of the adjacent substrates and function as a cathode. The X-Y strips are separated from the anode by a gap filled with a suitable gas. Electrical bias is selectively switched onto X and Y strips to activate a ``pixel`` in the region where these strips overlap. A small amount of a long-lived radioisotope is used to initiate an electron avalanche in the overlap region when bias is applied. The avalanche travels through the gas filled gap and activates a luminescent phosphor of a selected color. The bias is adjusted to give a proportional electron multiplication to control brightness for given pixel. 6 figs.

  15. Black optic display

    DOE Patents [OSTI]

    Veligdan, James T.

    1997-01-01

    An optical display includes a plurality of stacked optical waveguides having first and second opposite ends collectively defining an image input face and an image screen, respectively, with the screen being oblique to the input face. Each of the waveguides includes a transparent core bound by a cladding layer having a lower index of refraction for effecting internal reflection of image light transmitted into the input face to project an image on the screen, with each of the cladding layers including a cladding cap integrally joined thereto at the waveguide second ends. Each of the cores is beveled at the waveguide second end so that the cladding cap is viewable through the transparent core. Each of the cladding caps is black for absorbing external ambient light incident upon the screen for improving contrast of the image projected internally on the screen.

  16. Signal Processing, Analysis, & Display

    Energy Science and Technology Software Center (OSTI)

    1986-06-01

    SIG is a general-purpose signal processing, analysis, and display program. Its main purpose is to perform manipulations on time- and frequency-domain signals. However, it has been designed to ultimately accommodate other representations for data such as multiplexed signals and complex matrices. Two user interfaces are provided in SIG - a menu mode for the unfamiliar user and a command mode for more experienced users. In both modes errors are detected as early as possible andmoreare indicated by friendly, meaningful messages. An on-line HELP package is also included. A variety of operations can be performed on time- and frequency-domain signals including operations on the samples of a signal, operations on the entire signal, and operations on two or more signals. Signal processing operations that can be performed are digital filtering (median, Bessel, Butterworth, and Chebychev), ensemble average, resample, auto and cross spectral density, transfer function and impulse response, trend removal, convolution, Fourier transform and inverse window functions (Hamming, Kaiser-Bessel), simulation (ramp, sine, pulsetrain, random), and read/write signals. User definable signal processing algorithms are also featured. SIG has many options including multiple commands per line, command files with arguments,commenting lines, defining commands, and automatic execution for each item in a repeat sequence. Graphical operations on signals and spectra include: x-y plots of time signals; real, imaginary, magnitude, and phase plots of spectra; scaling of spectra for continuous or discrete domain; cursor zoom; families of curves; and multiple viewports.less

  17. Signal Processing, Analysis, & Display

    Energy Science and Technology Software Center (OSTI)

    1986-06-01

    SIG is a general-purpose signal processing, analysis, and display program. Its main purpose is to perform manipulations on time- and frequency-domain signals. However, it has been designed to ultimately accommodate other representations for data such as multiplexed signals and complex matrices. Two user interfaces are provided in SIG - a menu mode for the unfamiliar user and a command mode for more experienced users. In both modes errors are detected as early as possible andmore » are indicated by friendly, meaningful messages. An on-line HELP package is also included. A variety of operations can be performed on time- and frequency-domain signals including operations on the samples of a signal, operations on the entire signal, and operations on two or more signals. Signal processing operations that can be performed are digital filtering (median, Bessel, Butterworth, and Chebychev), ensemble average, resample, auto and cross spectral density, transfer function and impulse response, trend removal, convolution, Fourier transform and inverse window functions (Hamming, Kaiser-Bessel), simulation (ramp, sine, pulsetrain, random), and read/write signals. User definable signal processing algorithms are also featured. SIG has many options including multiple commands per line, command files with arguments,commenting lines, defining commands, and automatic execution for each item in a repeat sequence. Graphical operations on signals and spectra include: x-y plots of time signals; real, imaginary, magnitude, and phase plots of spectra; scaling of spectra for continuous or discrete domain; cursor zoom; families of curves; and multiple viewports.« less

  18. DOE - NNSA/NFO -- Exhibits and Displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exhibits and Displays NNSANFO Language Options U.S. DOENNSA - Nevada Field Office Exhibits and Displays Educational exhibits and displays are available for loan to libraries, ...

  19. Segmented nanowires displaying locally controllable properties

    DOE Patents [OSTI]

    Sutter, Eli Anguelova; Sutter, Peter Werner

    2013-03-05

    Vapor-liquid-solid growth of nanowires is tailored to achieve complex one-dimensional material geometries using phase diagrams determined for nanoscale materials. Segmented one-dimensional nanowires having constant composition display locally variable electronic band structures that are determined by the diameter of the nanowires. The unique electrical and optical properties of the segmented nanowires are exploited to form electronic and optoelectronic devices. Using gold-germanium as a model system, in situ transmission electron microscopy establishes, for nanometer-sized Au--Ge alloy drops at the tips of Ge nanowires (NWs), the parts of the phase diagram that determine their temperature-dependent equilibrium composition. The nanoscale phase diagram is then used to determine the exchange of material between the NW and the drop. The phase diagram for the nanoscale drop deviates significantly from that of the bulk alloy.

  20. MicroEmissive Displays | Open Energy Information

    Open Energy Info (EERE)

    Edinburgh, United Kingdom Zip: EH9 3JF Product: MicroEmissive Displays makes P-OLED (polymer light emitting diode) displays. Specific interests are head mounted displays and...

  1. Universal Display Corp | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Universal Display Corp. Place: New Jersey Product: OLED (Organic Light Emitting Device) Developer References: Universal Display Corp.1 This...

  2. Ultrasonic liquid-in-line detector for tubes

    DOE Patents [OSTI]

    Piper, Thomas C.

    1991-01-01

    An apparatus and method for detecting the presence of liquid in pipes or tubes using ultrasonic techniques A first piezoelectric crystal is coupled to the outside of the pipe or tube at the location where liquid in the tube is to be detected. A second piezoelectric crystal is coupled to the outside of the pipe or tube at the same location along the tube but circumferentially displaced from the first crystal by an angle around the pipe or tube of less than 180.degree.. Liquid in the pipe or tube is detected by measuring the attenuation of an ultrasonic signal sent by the first piezoelectric crystal and received by the second piezoelectric crystal.

  3. 2011 JSA Postdoctoral Research Grant Winner Plans New Spin on Liquid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Crystals | Jefferson Lab 1 JSA Postdoctoral Research Grant Winner Plans New Spin on Liquid Crystals 2011 JSA Postdoctoral Research Grant Winner Plans New Spin on Liquid Crystals 2011 JSA Postdoctoral Research Grant Recipient Users Group Board of Directors Chairman Zein-Eddine Meziani (left) with JSA President and Jefferson Lab Director Hugh Montgomery (right) congratulate Mark Dalton, the 2011 JSA Postdoctoral Research Grant Recipient. NEWPORT NEWS, VA, January 27, 2011 - Liquid crystals,

  4. Method for harvesting single crystals from a peritectic melt

    DOE Patents [OSTI]

    Todt, Volker R.; Sengupta, Suvankar; Shi, Donglu

    1996-01-01

    A method of preparing single crystals. The method of preparation involves preparing precursor materials of a particular composition, heating the precursor material to achieve a peritectic mixture of peritectic liquid and crystals, cooling the peritectic mixture to quench directly the mixture on a porous, wettable inert substrate to wick off the peritectic liquid, leaving single crystals on the porous substrate. Alternatively, the peritectic mixture can be cooled to a solid mass and reheated on a porous, inert substrate to melt the matrix of peritectic fluid while leaving the crystals unmelted, allowing the wicking away of the peritectic liquid.

  5. Method for harvesting single crystals from a peritectic melt

    DOE Patents [OSTI]

    Todt, V.R.; Sengupta, S.; Shi, D.

    1996-08-27

    A method of preparing single crystals is disclosed. The method of preparation involves preparing precursor materials of a particular composition, heating the precursor material to achieve a peritectic mixture of peritectic liquid and crystals, cooling the peritectic mixture to quench directly the mixture on a porous, wettable inert substrate to wick off the peritectic liquid, leaving single crystals on the porous substrate. Alternatively, the peritectic mixture can be cooled to a solid mass and reheated on a porous, inert substrate to melt the matrix of peritectic fluid while leaving the crystals unmelted, allowing the wicking away of the peritectic liquid. 2 figs.

  6. Method for harvesting rare earth barium copper oxide single crystals

    DOE Patents [OSTI]

    Todt, Volker R.; Sengupta, Suvankar; Shi, Donglu

    1996-01-01

    A method of preparing high temperature superconductor single crystals. The method of preparation involves preparing precursor materials of a particular composition, heating the precursor material to achieve a peritectic mixture of peritectic liquid and crystals of the high temperature superconductor, cooling the peritectic mixture to quench directly the mixture on a porous, wettable inert substrate to wick off the peritectic liquid, leaving single crystals of the high temperature superconductor on the porous substrate. Alternatively, the peritectic mixture can be cooled to a solid mass and reheated on a porous, inert substrate to melt the matrix of peritectic fluid while leaving the crystals melted, allowing the wicking away of the peritectic liquid.

  7. Crystal growth under external electric fields

    SciTech Connect (OSTI)

    Uda, Satoshi; Koizumi, Haruhiko; Nozawa, Jun; Fujiwara, Kozo

    2014-10-06

    This is a review article concerning the crystal growth under external electric fields that has been studied in our lab for the past 10 years. An external field is applied electrostatically either through an electrically insulating phase or a direct injection of an electric current to the solid-interface-liquid. The former changes the chemical potential of both solid and liquid and controls the phase relationship while the latter modifies the transport and partitioning of ionic solutes in the oxide melt during crystallization and changes the solute distribution in the crystal.

  8. Controlled release liquid dosage formulation

    DOE Patents [OSTI]

    Benton, Ben F.; Gardner, David L.

    1989-01-01

    A liquid dual coated dosage formulation sustained release pharmaceutic having substantial shelf life prior to ingestion is disclosed. A dual coating is applied over controlled release cores to form dosage forms and the coatings comprise fats melting at less than approximately 101.degree. F. overcoated with cellulose acetate phthalate or zein. The dual coated dosage forms are dispersed in a sugar based acidic liquid carrier such as high fructose corn syrup and display a shelf life of up to approximately at least 45 days while still retaining their release profiles following ingestion. Cellulose acetate phthalate coated dosage form cores can in addition be dispersed in aqueous liquids of pH <5.

  9. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Our CO2 Drop Watch Our CO2 Drop January 14, 2016 - 4:55pm Addthis Daniel Wood Daniel Wood Data Visualization and Cartographic Specialist, Office of Public Affairs Learn More About Climate Change If you want to learn more about the importance of reducing our carbon pollution, read our recent report about how climate change threatens our energy infrastructure. Curious about the total amount of carbon we emit into the atmosphere? Compare countries from around the globe using this tool. On Tuesday,

  10. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Temperature dependence of the helical half-pitch scattering profile. Top: Heating from room temperature (RT) to the B4-phase critical temperature (TC 142 C). The peak...

  11. Watching a Liquid-Crystal Helix Unwind

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    architecture with potential as an efficient charge-transport system for organic photovoltaics. It also forms porous networks that could be used for the synthesis and separation...

  12. Changes in mobility of plastic crystal ethanol during its transformation into the monoclinic crystal state

    SciTech Connect (OSTI)

    Sanz, Alejandro Nogales, Aurora; Ezquerra, Tiberio A.; Puente-Orench, Inés; Instituto de Ciencia de Materiales de Aragón, ICMA-CSIC, Pedro Cerbuna 12, 50009 Zaragoza ; Jiménez-Ruiz, Mónica

    2014-02-07

    Transformation of deuterated ethanol from the plastic crystal phase into the monoclinic one is investigated by means of a singular setup combining simultaneously dielectric spectroscopy with neutron diffraction. We postulate that a dynamic transition from plastic crystal to supercooled liquid-like configuration through a deep reorganization of the hydrogen-bonding network must take place as a previous step of the crystallization process. Once these precursor regions are formed, subsequent crystalline nucleation and growth develop with time.

  13. Polyplanar optic display for cockpit application

    SciTech Connect (OSTI)

    Veligdan, J.; Biscardi, C.; Brewster, C.; DeSanto, L.; Freibott, W.

    1998-04-01

    The Polyplanar Optical Display (POD) is a high contrast display screen being developed for cockpit applications. This display screen is 2 inches thick and has a matte black face which allows for high contrast images. The prototype being developed is a form, fit and functional replacement display for the B-52 aircraft which uses a monochrome ten-inch display. The new display uses a long lifetime, (10,000 hour), 200 mW green solid-state laser (532 nm) as its optical source. In order to produce real-time video, the laser light is being modulated by a Digital Light Processing (DLP{trademark}) chip manufactured by Texas Instruments, Inc. A variable astigmatic focusing system is used to produce a stigmatic image on the viewing face of the POD. In addition to the optical design and speckle reduction, the authors discuss the electronic interfacing to the DLP{trademark} chip, the opto-mechanical design and viewing angle characteristics.

  14. Covered Product Category: Displays | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Displays Covered Product Category: Displays The Federal Energy Management Program (FEMP) provides acquisition guidance for displays, a product category covered by the ENERGY STAR program. Federal laws and requirements mandate that agencies buy ENERGY STAR qualified products in all product categories covered by this program and any acquisition actions that are not specifically exempted by law. MEETING EFFICIENCY REQUIREMENTS FOR FEDERAL PURCHASES The U.S. Environmental Protection Agency (EPA)

  15. DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES...

    Open Energy Info (EERE)

    DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES ON MUDLOG GRAPHS Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings:...

  16. Flywheel energy storage system focus of display

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flywheel Energy Storage System Focus of Display Demonstration to feature advanced, solar-powered replacement for batteries For more information contact: e:mail: Public Affairs ...

  17. Critical function and success path summary display

    DOE Patents [OSTI]

    Scarola, Kenneth; Jamison, David S.; Manazir, Richard M.; Rescorl, Robert L.; Harmon, Daryl L.

    1995-01-01

    The content of and hierarchical access to three levels of display pages containing information on critical function monitoring and success path monitoring.

  18. LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Thornton, J.D.

    1957-12-31

    This patent relates to liquid-liquid extraction columns having a means for pulsing the liquid in the column to give it an oscillatory up and down movement, and consists of a packed column, an inlet pipe for the dispersed liquid phase and an outlet pipe for the continuous liquid phase located in the direct communication with the liquid in the lower part of said column, an inlet pipe for the continuous liquid phase and an outlet pipe for the dispersed liquid phase located in direct communication with the liquid in the upper part of said column, a tube having one end communicating with liquid in the lower part of said column and having its upper end located above the level of said outlet pipe for the dispersed phase, and a piston and cylinder connected to the upper end of said tube for applying a pulsating pneumatic pressure to the surface of the liquid in said tube so that said surface rises and falls in said tube.

  19. Commercial Display Systems: Order (2013-CE-5350)

    Broader source: Energy.gov [DOE]

    DOE ordered Commercial Display Systems, LLC to pay a $8,000 civil penalty after finding Commercial Display Systems had failed to certify that any basic models of walk-in cooler and freezer components comply with the applicable energy conservation standards.

  20. Properties of Liquid Plutonium

    SciTech Connect (OSTI)

    Freibert, Franz J.; Mitchell, Jeremy N.; Schwartz, Daniel S.; Saleh, Tarik A.; Migliori, Albert

    2012-08-02

    Unalloyed polycrystalline Pu displays extreme thermal expansion behavior, i.e., {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} increases by 25% in volume and {delta} {yields} {var_epsilon} {yields} liquid decreases by 4.5% in volume. Thus, making it difficult to measure density into the liquid state. Dilatometer outfitted with CaF molten metal cell offers a proven capability to measure thermal expansion in molten metals, but has yet to be proven for Pu. Historic data from the liquid nuclear fuels program will prove extremely useful as a guide to future measurements. 3.3at% Ga changes Pu molten metal properties: 50% increase in viscosity and {approx}3% decrease in density. Fe may decrease the density by a small amount assuming an averaging of densities for Pu-Ga and Pu-Fe liquids. More recent Boivineau (2009) work needs some interpretation, but technique is being employed in (U,Pu)O{sub 2} nuclear fuels program (Pu Futures, 2012).

  1. Real time speech formant analyzer and display

    DOE Patents [OSTI]

    Holland, G.E.; Struve, W.S.; Homer, J.F.

    1987-02-03

    A speech analyzer for interpretation of sound includes a sound input which converts the sound into a signal representing the sound. The signal is passed through a plurality of frequency pass filters to derive a plurality of frequency formants. These formants are converted to voltage signals by frequency-to-voltage converters and then are prepared for visual display in continuous real time. Parameters from the inputted sound are also derived and displayed. The display may then be interpreted by the user. The preferred embodiment includes a microprocessor which is interfaced with a television set for displaying of the sound formants. The microprocessor software enables the sound analyzer to present a variety of display modes for interpretive and therapeutic used by the user. 19 figs.

  2. Real time speech formant analyzer and display

    DOE Patents [OSTI]

    Holland, George E.; Struve, Walter S.; Homer, John F.

    1987-01-01

    A speech analyzer for interpretation of sound includes a sound input which converts the sound into a signal representing the sound. The signal is passed through a plurality of frequency pass filters to derive a plurality of frequency formants. These formants are converted to voltage signals by frequency-to-voltage converters and then are prepared for visual display in continuous real time. Parameters from the inputted sound are also derived and displayed. The display may then be interpreted by the user. The preferred embodiment includes a microprocessor which is interfaced with a television set for displaying of the sound formants. The microprocessor software enables the sound analyzer to present a variety of display modes for interpretive and therapeutic used by the user.

  3. Density functional theory for carbon dioxide crystal

    SciTech Connect (OSTI)

    Chang, Yiwen; Mi, Jianguo Zhong, Chongli

    2014-05-28

    We present a density functional approach to describe the solid?liquid phase transition, interfacial and crystal structure, and properties of polyatomic CO{sub 2}. Unlike previous phase field crystal model or density functional theory, which are derived from the second order direct correlation function, the present density functional approach is based on the fundamental measure theory for hard-sphere repulsion in solid. More importantly, the contributions of enthalpic interactions due to the dispersive attractions and of entropic interactions arising from the molecular architecture are integrated in the density functional model. Using the theoretical model, the predicted liquid and solid densities of CO{sub 2} at equilibrium triple point are in good agreement with the experimental values. Based on the structure of crystal-liquid interfaces in different planes, the corresponding interfacial tensions are predicted. Their respective accuracies need to be tested.

  4. Segmented Nanowires Displaying Locally Controllable Properties...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vapor-liquid-solid growth of nanowires is tailored to achieve complex one-dimensional material geometries using phase diagrams determined for nanoscale materials. Segmented...

  5. LIQUID TARGET

    DOE Patents [OSTI]

    Martin, M.D.; Salsig, W.W. Jr.

    1959-01-13

    A liquid handling apparatus is presented for a liquid material which is to be irradiated. The apparatus consists essentially of a reservoir for the liquid, a target element, a drain tank and a drain lock chamber. The target is in the form of a looped tube, the upper end of which is adapted to be disposed in a beam of atomic particles. The lower end of the target tube is in communication with the liquid in the reservoir and a means is provided to continuously circulate the liquid material to be irradiated through the target tube. Means to heat the reservoir tank is provided in the event that a metal is to be used as the target material. The apparatus is provided with suitable valves and shielding to provide maximum safety in operation.

  6. DOE - NNSA/NFO -- Exhibits and Displays Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exhibits and Displays Request U.S. DOE/NNSA - Nevada Field Office Exhibits and Displays Request Form Educational exhibits and displays are available for loan to libraries, schools and for conferences and other special events. To request an exhibit or display, please fill out and submit the form below. Exhibit and Display Request Form Name: Organization: Email Address: Phone: Select an Exhibit: Select an Exhibit/Display Operation Clean Desert (EM Kids Display) Groundwater at the NTS Display

  7. Beacon data acquisition and display system

    DOE Patents [OSTI]

    Skogmo, David G.; Black, Billy D.

    1991-01-01

    A system for transmitting aircraft beacon information received by a secondary surveillance radar through telephone lines to a remote display includes a digitizer connected to the radar for preparing a serial file of data records containing position and identification information of the beacons detected by each sweep of the radar. This information is transmitted through the telephone lines to a remote computer where it is displayed.

  8. Multi-clad black display panel

    SciTech Connect (OSTI)

    Veligdan, James T.; Biscardi, Cyrus; Brewster, Calvin

    2002-01-01

    A multi-clad black display panel, and a method of making a multi-clad black display panel, are disclosed, wherein a plurality of waveguides, each of which includes a light-transmissive core placed between an opposing pair of transparent cladding layers and a black layer disposed between transparent cladding layers, are stacked together and sawed at an angle to produce a wedge-shaped optical panel having an inlet face and an outlet face.

  9. Beacon data acquisition and display system

    DOE Patents [OSTI]

    Skogmo, D.G.; Black, B.D.

    1991-12-17

    A system for transmitting aircraft beacon information received by a secondary surveillance radar through telephone lines to a remote display includes a digitizer connected to the radar for preparing a serial file of data records containing position and identification information of the beacons detected by each sweep of the radar. This information is transmitted through the telephone lines to a remote computer where it is displayed. 6 figures.

  10. Electronic Structure of Cobalt Nanocrystals Suspended in Liquid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ligand, layer (in this case, oleic acid) and are suspended in a liquid solvent (in this case, 1,2-dichlorobenzene). Cobalt nanocrystals display a wealth of size-dependent...

  11. Structural characterization of thin film photonic crystals

    SciTech Connect (OSTI)

    Subramania, G.; Biswas, R.; Constant, K.; Sigalas, M. M.; Ho, K. M.

    2001-06-15

    We quantitatively analyze the structure of thin film inverse-opal photonic crystals composed of ordered arrays of air pores in a background of titania. Ordering of the sphere template and introduction of the titania background were performed simultaneously in the thin film photonic crystals. Nondestructive optical measurements of backfilling with high refractive index liquids, angle-resolved reflectivity, and optical spectroscopy were combined with band-structure calculations. The analysis reveals a thin film photonic crystal structure with a very high filling fraction (92{endash}94%) of air and a substantial compression along the c axis ({similar_to}22{endash}25%).

  12. Stable and metastable nanowires displaying locally controllable properties

    DOE Patents [OSTI]

    Sutter, Eli Anguelova; Sutter, Peter Werner

    2014-11-18

    Vapor-liquid-solid growth of nanowires is tailored to achieve complex one-dimensional material geometries using phase diagrams determined for nanoscale materials. Segmented one-dimensional nanowires having constant composition display locally variable electronic band structures that are determined by the diameter of the nanowires. The unique electrical and optical properties of the segmented nanowires are exploited to form electronic and optoelectronic devices. Using gold-germanium as a model system, in situ transmission electron microscopy establishes, for nanometer-sized Au--Ge alloy drops at the tips of Ge nanowires (NWs), the parts of the phase diagram that determine their temperature-dependent equilibrium composition. The nanoscale phase diagram is then used to determine the exchange of material between the NW and the drop. The phase diagram for the nanoscale drop deviates significantly from that of the bulk alloy.

  13. Meteorological Towers Display for Windows NT

    Energy Science and Technology Software Center (OSTI)

    1999-05-20

    The Towers Display Program provides a convenient means of graphically depicting current wind speed and direction from a network of meteorological monitoring stations. The program was designed primarily for emergency response applications and, therefore, plots observed wind directions as a transport direction, i.e., the direction toward which the wind would transport a release of an atmospheric contaminant. Tabular summaries of wind speed and direction as well as temperature, relative humidity, and atmospheric turbulence measured atmore » each monitoring station can be displayed. The current implementation of the product at SRS displays data from eight Weather INformation and Display (WIND) System meteorological towers at SRS, meteorological stations established jointly by SRS/WSRC and the Augusta/Richmond County Emergency Management Agency in Augusta, GA, and National Weather Service stations in Augusta, GA. Wind speed and direction are plotted in a Beaufort scale format at the location of the station on a geographic map of the area. A GUI provides for easy specification of a desired date and time for the data to be displayed.« less

  14. Image display device in digital TV

    DOE Patents [OSTI]

    Choi, Seung Jong

    2006-07-18

    Disclosed is an image display device in a digital TV that is capable of carrying out the conversion into various kinds of resolution by using single bit map data in the digital TV. The image display device includes: a data processing part for executing bit map conversion, compression, restoration and format-conversion for text data; a memory for storing the bit map data obtained according to the bit map conversion and compression in the data processing part and image data inputted from an arbitrary receiving part, the receiving part receiving one of digital image data and analog image data; an image outputting part for reading the image data from the memory; and a display processing part for mixing the image data read from the image outputting part and the bit map data converted in format from the a data processing part. Therefore, the image display device according to the present invention can convert text data in such a manner as to correspond with various resolution, carry out the compression for bit map data, thereby reducing the memory space, and support text data of an HTML format, thereby providing the image with the text data of various shapes.

  15. Method of monitoring crystal growth

    DOE Patents [OSTI]

    Sachs, Emanual M.

    1982-01-01

    A system and method are disclosed for monitoring the growth of a crystalline body from a liquid meniscus in a furnace. The system provides an improved human/machine interface so as to reduce operator stress, strain and fatigue while improving the conditions for observation and control of the growing process. The system comprises suitable optics for forming an image of the meniscus and body wherein the image is anamorphic so that the entire meniscus can be viewed with good resolution in both the width and height dimensions. The system also comprises a video display for displaying the anamorphic image. The video display includes means for enhancing the contrast between any two contrasting points in the image. The video display also comprises a signal averager for averaging the intensity of at least one preselected portions of the image. The value of the average intensity, can in turn be utilized to control the growth of the body. The system and method are also capable of observing and monitoring multiple processes.

  16. Apparatus for monitoring crystal growth

    DOE Patents [OSTI]

    Sachs, Emanual M.

    1981-01-01

    A system and method are disclosed for monitoring the growth of a crystalline body from a liquid meniscus in a furnace. The system provides an improved human/machine interface so as to reduce operator stress, strain and fatigue while improving the conditions for observation and control of the growing process. The system comprises suitable optics for forming an image of the meniscus and body wherein the image is anamorphic so that the entire meniscus can be viewed with good resolution in both the width and height dimensions. The system also comprises a video display for displaying the anamorphic image. The video display includes means for enhancing the contrast between any two contrasting points in the image. The video display also comprises a signal averager for averaging the intensity of at least one preselected portions of the image. The value of the average intensity, can in turn be utilized to control the growth of the body. The system and method are also capable of observing and monitoring multiple processes.

  17. Liquid metal cooling of synchrotron optics

    SciTech Connect (OSTI)

    Smither, R.K.

    1992-09-01

    The installation of insertion devices at existing synchrotron facilities around the world has stimulated the development of new ways to cool the optical elements in the associated x-ray beamlines. Argonne has been a leader in the development of liquid metal cooling for high heat load x-ray optics for the next generation of synchrotron facilities. The high thermal conductivity, high volume specific heat, low kinematic viscosity, and large working temperature range make liquid metals a very efficient heat transfer fluid. A wide range of liquid metals were considered in the initial phase of this work. The most promising liquid metal cooling fluid identified to date is liquid gallium, which appears to have all the desired properties and the fewest number of undesired features of the liquid metals examined. Besides the special features of liquid metals that make them good heat transfer fluids, the very low vapor pressure over a large working temperature range make liquid gallium an ideal cooling fluid for use in a high vacuum environment. A leak of the liquid gallium into the high vacuum and even into very high vacuum areas will not result in any detectable vapor pressure and may even improve the vacuum environment as the liquid gallium combines with any water vapor or oxygen present in the system. The practical use of a liquid metal for cooling silicon crystals and other high heat load applications depends on having a convenient and efficient delivery system. The requirements for a typical cooling system for a silicon crystal used in a monochromator are pumping speeds of 2 to 5 gpm (120 cc per sec to 600 cc per sec) at pressures up to 100 psi.

  18. Epitaxial strengthening of crystals

    DOE Patents [OSTI]

    Morris, Robert C.; Marion II, Ohn E.; Gaultieri, Devlin M.

    1988-12-06

    An epitaxial layer is used to place the surface of a crystal in compression o as to greatly increase the durability of the crystal such as a laser medium crystal.

  19. Epitaxial strengthening of crystals

    DOE Patents [OSTI]

    Morris, Robert C.; Marion, II, John E.; Gaultieri, Devlin M.

    1988-01-01

    An epitaxial layer is used to place the surface of a crystal in compression o as to greatly increase the durability of the crystal such as a laser medium crystal.

  20. Method for harvesting rare earth barium copper oxide single crystals

    DOE Patents [OSTI]

    Todt, V.R.; Sengupta, S.; Shi, D.

    1996-04-02

    A method of preparing high temperature superconductor single crystals is disclosed. The method of preparation involves preparing precursor materials of a particular composition, heating the precursor material to achieve a peritectic mixture of peritectic liquid and crystals of the high temperature superconductor, cooling the peritectic mixture to quench directly the mixture on a porous, wettable inert substrate to wick off the peritectic liquid, leaving single crystals of the high temperature superconductor on the porous substrate. Alternatively, the peritectic mixture can be cooled to a solid mass and reheated on a porous, inert substrate to melt the matrix of peritectic fluid while leaving the crystals melted, allowing the wicking away of the peritectic liquid. 2 figs.

  1. Controlled growth of semiconductor crystals

    DOE Patents [OSTI]

    Bourret-Courchesne, E.D.

    1992-07-21

    A method is disclosed for growth of III-V, II-VI and related semiconductor single crystals that suppresses random nucleation and sticking of the semiconductor melt at the crucible walls. Small pieces of an oxide of boron B[sub x]O[sub y] are dispersed throughout the comminuted solid semiconductor charge in the crucible, with the oxide of boron preferably having water content of at least 600 ppm. The crucible temperature is first raised to a temperature greater than the melt temperature T[sub m1] of the oxide of boron (T[sub m1]=723 K for boron oxide B[sub 2]O[sub 3]), and the oxide of boron is allowed to melt and form a reasonably uniform liquid layer between the crucible walls and bottom surfaces and the still-solid semiconductor charge. The temperature is then raised to approximately the melt temperature T[sub m2] of the semiconductor charge material, and crystal growth proceeds by a liquid encapsulated, vertical gradient freeze process. About half of the crystals grown have a dislocation density of less than 1000/cm[sup 2]. If the oxide of boron has water content less than 600 ppm, the crucible material should include boron nitride, a layer of the inner surface of the crucible should be oxidized before the oxide of boron in the crucible charge is melted, and the sum of thicknesses of the solid boron oxide layer and liquid boron oxide layer should be at least 50 [mu]m. 7 figs.

  2. Controlled growth of semiconductor crystals

    DOE Patents [OSTI]

    Bourret-Courchesne, Edith D.

    1992-01-01

    A method for growth of III-V, II-VI and related semiconductor single crystals that suppresses random nucleation and sticking of the semiconductor melt at the crucible walls. Small pieces of an oxide of boron B.sub.x O.sub.y are dispersed throughout the comminuted solid semiconductor charge in the crucible, with the oxide of boron preferably having water content of at least 600 ppm. The crucible temperature is first raised to a temperature greater than the melt temperature T.sub.m1 of the oxide of boron (T.sub.m1 =723.degree. K. for boron oxide B.sub.2 O.sub.3), and the oxide of boron is allowed to melt and form a reasonably uniform liquid layer between the crucible walls and bottom surfaces and the still-solid semiconductor charge. The temperature is then raised to approximately the melt temperature T.sub.m2 of the semiconductor charge material, and crystal growth proceeds by a liquid encapsulated, vertical gradient freeze process. About half of the crystals grown have a dislocation density of less than 1000/cm.sup.2. If the oxide of boron has water content less than 600 ppm, the crucible material should include boron nitride, a layer of the inner surface of the crucible should be oxidized before the oxide of boron in the crucible charge is melted, and the sum of thicknesses of the solid boron oxide layer and liquid boron oxide layer should be at least 50 .mu.m.

  3. SECTION I

    National Nuclear Security Administration (NNSA)

    ... tube (CRT), liquid crystal display (LCD), plasma display, or other display technology. ... for activities associated with Princeton Plasma Physics Laboratory; (6) The Associated ...

  4. High power laser having a trivalent liquid host

    DOE Patents [OSTI]

    Ault, Earl R.

    2005-08-16

    A laser having a lasing chamber and a semiconductor pumping device with trivalent titanium ions dissolved in a liquid host within the lasing chamber. Since the host is a liquid, it can be removed from the optical cavity when it becomes heated avoiding the inevitable optical distortion and birefringence common to glass and crystal hosts.

  5. Micro-valve pump light valve display

    DOE Patents [OSTI]

    Yeechun Lee.

    1993-01-19

    A flat panel display incorporates a plurality of micro-pump light valves (MLV's) to form pixels for recreating an image. Each MLV consists of a dielectric drop sandwiched between substrates, at least one of which is transparent, a holding electrode for maintaining the drop outside a viewing area, and a switching electrode from accelerating the drop from a location within the holding electrode to a location within the viewing area. The sustrates may further define non-wetting surface areas to create potential energy barriers to assist in controlling movement of the drop. The forces acting on the drop are quadratic in nature to provide a nonlinear response for increased image contrast. A crossed electrode structure can be used to activate the pixels whereby a large flat panel display is formed without active driver components at each pixel.

  6. Micro-valve pump light valve display

    DOE Patents [OSTI]

    Lee, Yee-Chun

    1993-01-01

    A flat panel display incorporates a plurality of micro-pump light valves (MLV's) to form pixels for recreating an image. Each MLV consists of a dielectric drop sandwiched between substrates, at least one of which is transparent, a holding electrode for maintaining the drop outside a viewing area, and a switching electrode from accelerating the drop from a location within the holding electrode to a location within the viewing area. The sustrates may further define non-wetting surface areas to create potential energy barriers to assist in controlling movement of the drop. The forces acting on the drop are quadratic in nature to provide a nonlinear response for increased image contrast. A crossed electrode structure can be used to activate the pixels whereby a large flat panel display is formed without active driver components at each pixel.

  7. Monochromator Crystal Glitch Library

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    SSRL's Monochromator Crystal Glitch Library allows users to view glitch spectra online, list specific crystal orientations, and download PDF files of the glitch spectra. (Specialized Interface)

  8. Neutron detection with single crystal organic scintillators

    SciTech Connect (OSTI)

    Zaitseva, N; Newby, J; Hamel, S; Carman, L; Faust, M; Lordi, V; Cherepy, N; Stoeffl, W; Payne, S

    2009-07-15

    Detection of high-energy neutrons in the presence of gamma radiation background utilizes pulse-shape discrimination (PSD) phenomena in organics studied previously only with limited number of materials, mostly liquid scintillators and single crystal stilbene. The current paper presents the results obtained with broader varieties of luminescent organic single crystals. The studies involve experimental tools of crystal growth and material characterization in combination with the advanced computer modeling, with the final goal of better understanding the relevance between the nature of the organic materials and their PSD properties. Special consideration is given to the factors that may diminish or even completely obscure the PSD properties in scintillating crystals. Among such factors are molecular and crystallographic structures that determine exchange coupling and exciton mobility in organic materials and the impurity effect discussed on the examples of trans-stilbene, bibenzyl, 9,10-diphenylanthracene and diphenylacetylene.

  9. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  10. Information Display: Considerations for Designing Modern Computer-Based Display Systems

    SciTech Connect (OSTI)

    J.O'Hara, D.Pirus, L.Beltracchi

    2003-10-01

    OAK- B135 To help nuclear utilities and suppliers design and implement plant information management systems and displays that provide accurate and timely information and require minimal navigation and interface management.

  11. DOE - NNSA/NFO -- Photo Library Exhibits and Displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Exhibits and Displays NNSA/NFO Language Options U.S. DOE/NNSA - Nevada Field Office Photo Library - Exhibits and Displays Educational exhibits and displays are available for loan to libraries, schools and for conferences and other special events. To request an exhibit or display, please fill out and submit the Exhibits and Display Request Form. Instructions: Click the photograph THUMBNAIL to view the photograph details Thumbnail Title ER-Banner-Stand17 Groundwater Poster Groundwater Poster Kids

  12. Mixed crystal organic scintillators

    DOE Patents [OSTI]

    Zaitseva, Natalia P; Carman, M Leslie; Glenn, Andrew M; Hamel, Sebastien; Hatarik, Robert; Payne, Stephen A; Stoeffl, Wolfgang

    2014-09-16

    A mixed organic crystal according to one embodiment includes a single mixed crystal having two compounds with different bandgap energies, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source, wherein the signal response signature does not include a significantly-delayed luminescence characteristic of neutrons interacting with the organic crystal relative to a luminescence characteristic of gamma rays interacting with the organic crystal. According to one embodiment, an organic crystal includes bibenzyl and stilbene or a stilbene derivative, the organic crystal having a physical property of exhibiting a signal response signature for neutrons from a radioactive source.

  13. CRYSTAL COLLIMATION AT RHIC.

    SciTech Connect (OSTI)

    FLILLER,R.P.,III.DREES,A.GASSNER,D.HAMMONS,L.MCINTYRE,G.PEGGS,S.TRBOJEVIC,D.BIRYUKOV,V.CHESNOKOV,Y.TEREKHOV,V.

    2003-06-19

    Crystal Channeling occurs when an ion enters a crystal with a small angle with respect to the crystal planes. The electrostatic interaction between the incoming ion and the lattice causes the ion to follow the crystal planes. By mechanically bending a crystal, it is possible to use a crystal to deflect ions. One novel use of a bent crystal is to use it to channel beam halo particles into a collimator downstream. By deflecting the halo particles into a collimator with a crystal it may be possible to improve collimation efficiency as compared to a single collimator. A bent crystal is installed in the yellow ring of the Relativistic Heavy Ion Collider (RHIC). In this paper we discuss our experience with the crystal collimator, and compare our results to previous data, simulation, and theoretical prediction.

  14. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  15. Pressure cryocooling protein crystals

    DOE Patents [OSTI]

    Kim, Chae Un; Gruner, Sol M.

    2011-10-04

    Preparation of cryocooled protein crystal is provided by use of helium pressurizing and cryocooling to obtain cryocooled protein crystal allowing collection of high resolution data and by heavier noble gas (krypton or xenon) binding followed by helium pressurizing and cryocooling to obtain cryocooled protein crystal for collection of high resolution data and SAD phasing simultaneously. The helium pressurizing is carried out on crystal coated to prevent dehydration or on crystal grown in aqueous solution in a capillary.

  16. Graphlocons: Large dendritic graphene crystals and their electronic properties

    SciTech Connect (OSTI)

    Massicotte, Mathieu; Yu, Victor; Whiteway, Eric; Hilke, Michael

    2013-12-04

    Submillimeter dendritic-shaped crystals were synthesized by low pressure vapor chemical vapor deposition inside a copper enclosure. With their sixfold symmetry and fractal-like shape, the resulting crystals resemble snowflakes. The electronic properties of the devices were investigated down to sub-Kelvin temperatures, showing mobilities over 5000 cm{sup 2}/Vs and the quantum Hall effect at 8T. The magnetoresistance also displayed a sharp peak at zero field which we attribute to weak localization.

  17. Home Energy Displays: Consumer Adoption and Response

    SciTech Connect (OSTI)

    LaMarche, J.; Cheney, K.; Akers, C.; Roth, K.; Sachs, O.

    2012-12-01

    The focus of this project was to investigate the factors influencing consumer adoption of Home Energy Displays (HEDs) and to evaluate electricity consumption in households with basic HEDs versus enhanced feedback methods - web portals or alerts. We hypothesized that providing flexible and relatable information to users, in addition to a basic HED, would make feedback more effective and achieve persistent energy savings. In Phase I, we conducted three user research studies and found preferences for aesthetically pleasing, easy to understand feedback that is accessible through multiple media and offered free of charge. The deployment of HEDs in 150 households planned for Phase II encountered major recruitment and HED field deployment problems. First, after extensive outreach campaigns to apartment complexes with 760 units, only 8% of building's tenants elected to receive a free HED in their homes as part of the field study. Second, the HED used, a leading market model, had a spectrum of problems, including gateway miscommunications, failure to post to a data-hosting third party, and display malfunctions. In light of these challenges, we are pursuing a modified study investigating the energy savings of a web portal versus alert-based energy feedback instead of a physical HED.

  18. Thin film polycrystalline silicon: Promise and problems in displays and solar cells

    SciTech Connect (OSTI)

    Fonash, S.J.

    1995-08-01

    Thin film polycrystalline Si (poly-Si) with its carrier mobilities, potentially good stability, low intragrain defect density, compatibility with silicon processing, and ease of doping activation is an interesting material for {open_quotes}macroelectronics{close_quotes} applications such as TFTs for displays and solar cells. The poly-Si films needed for these applications can be ultra-thin-in the 500{Angstrom} to 1000{Angstrom} thickness range for flat panel display TFTs and in the 4{mu}m to 10{mu}m thickness range for solar cells. Because the films needed for these microelectronics applications can be so thin, an effective approach to producing the films is that of crystallizing a-Si precursor material. Unlike cast materials, poly-Si films made this way can be produced using low temperature processing. Unlike deposited poly-Si films, these crystallized poly-Si films can have grain widths that are much larger than the film thickness and almost atomically smooth surfaces. This thin film poly-Si crystallized from a-Si precursor films, and its promise and problems for TFTs and solar cells, is the focus of this discussion.

  19. Home Energy Displays. Consumer Adoption and Response

    SciTech Connect (OSTI)

    LaMarche, Janelle; Cheney, K.; Akers, C.; Roth, K.; Sachs, O.

    2012-12-01

    The focus of this project was to investigate the factors influencing consumer adoption of Home Energy Displays (HEDs) and to evaluate electricity consumption in households with basic HEDs versus enhanced feedback methods - web portals or alerts. The team hypothesized that providing flexible and relatable information to users, in addition to a basic HED, would make feedback more effective and achieve persistent energy savings. In Phase I, Fraunhofer conducted three user research studies and found preferences for aesthetically pleasing, easy to understand feedback that is accessible through multiple media and offered free of charge. The deployment of HEDs in 150 households planned for Phase II encountered major recruitment and HED field deployment problems. In light of these challenges, the team is pursuing a modified study investigating the energy savings of a web portal versus alert-based energy feedback instead of a physical HED.

  20. Growing Giant Crystals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    crystals Growing Giant Crystals A new process similar to making rock candy was developed at NIF to rapidly grow very large crystals that are about 2 cubic feet in size and weigh up to 800 pounds-about the weight of a large grizzly bear! The crystals are made of potassium dihydrogen phosphate (or KDP), a naturally occurring chemical. In crystal form, KDP has good optical properties. Crystal plates have special optical properties, like prisms, that transmit, bend, and break light up into the

  1. CRYSTAL COLLIMATION AT RHIC.

    SciTech Connect (OSTI)

    FLILLER,III, R.P.; DREES,A.; GASSNER,D.; HAMMONS,L.; MCINTYRE,G.; PEGGS,S.; TRBOJEVIC,D.; BIRYUKOV,V.; CHESNKOV,Y.; TEREKHOV,V.

    2002-06-02

    For the year 2001 run, a bent crystal was installed in the yellow ring of the Relativistic Heavy Ion Collider (RHIC). The crystal forms the first stage of a two stage collimation system. By aligning the crystal to the beam, halo particles are channeled through the crystal and deflected into a copper scraper. The purpose is to reduce beam halo with greater efficiency than with a scraper alone. In this paper we present the first results from the use of the crystal collimator. We compare the crystal performance under various conditions, such as different particle species, and beta functions.

  2. Crystal Systems | Open Energy Information

    Open Energy Info (EERE)

    is located in Salem, Massachusetts. Crystal Systems produces sapphire crystals for optics and electronics, and silicon for photovoltaics. References Crystal Systems...

  3. Sandia National Laboratories: Better flat-panel displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facebook Twitter YouTube Flickr RSS News Better, brighter, cheaper flat-panel displays By ... colors and better images for flat-panel displays built from less expensive ...

  4. LM Completes the Grand Junction, Colorado, Site Historical Wall Display

    Broader source: Energy.gov [DOE]

    On Wednesday, October 8, a new display was unveiled at DOE Headquarters in Washington, DC, by DOE Deputy Under Secretary David Klaus. The display celebrates more than 70 years of operations at the...

  5. Methods and apparatus for transparent display using scattering nanoparticles

    DOE Patents [OSTI]

    Hsu, Chia Wei; Qiu, Wenjun; Zhen, Bo; Shapira, Ofer; Soljacic, Marin

    2016-05-10

    Transparent displays enable many useful applications, including heads-up displays for cars and aircraft as well as displays on eyeglasses and glass windows. Unfortunately, transparent displays made of organic light-emitting diodes are typically expensive and opaque. Heads-up displays often require fixed light sources and have limited viewing angles. And transparent displays that use frequency conversion are typically energy inefficient. Conversely, the present transparent displays operate by scattering visible light from resonant nanoparticles with narrowband scattering cross sections and small absorption cross sections. More specifically, projecting an image onto a transparent screen doped with nanoparticles that selectively scatter light at the image wavelength(s) yields an image on the screen visible to an observer. Because the nanoparticles scatter light at only certain wavelengths, the screen is practically transparent under ambient light. Exemplary transparent scattering displays can be simple, inexpensive, scalable to large sizes, viewable over wide angular ranges, energy efficient, and transparent simultaneously.

  6. REDISTRIBUTOR FOR LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Bradley, J.G.

    1957-10-29

    An improved baffle plate construction to intimately mix immiscible liquid solvents for solvent extraction processes in a liquid-liquid pulse column is described. To prevent the light and heavy liquids from forming separate continuous homogeneous vertical channels through sections of the column, a baffle having radially placed rectangular louvers with deflection plates opening upon alternate sides of the baffle is placed in the column, normal to the axis. This improvement substantially completely reduces strippiig losses due to poor mixing.

  7. Apparatus for mounting crystal

    DOE Patents [OSTI]

    Longeway, Paul A.

    1985-01-01

    A thickness monitor useful in deposition or etching reactor systems comprising a crystal-controlled oscillator in which the crystal is deposited or etched to change the frequency of the oscillator. The crystal rests within a thermally conductive metallic housing and arranged to be temperature controlled. Electrode contacts are made to the surface primarily by gravity force such that the crystal is substantially free of stress otherwise induced by high temperature.

  8. Scientific Graphical Displays on the Macintosh

    SciTech Connect (OSTI)

    Grotch, S.

    1994-11-15

    In many organizations scientists have ready access to more than one computer, often both a workstation (e.g., SUN, HP, SGI) as well as a Macintosh or other PC. The scientist commonly uses the work station for `number-crunching` and data analysis whereas the Macintosh is relegated to either word processing or serves as a `dumb terminal` to a larger main-frame computer. In an informal poll of my colleagues, very few of them used their Macintoshes for either statistical analysis or for graphical data display. I believe that this state of affairs is particularly unfortunate because over the last few years both the computational capability, and even more so, the software availability for the Macintosh have become quite formidable. In some instances, very powerful tools are now available on the Macintosh that may not exist (or be far too costly) on the so-called `high end` workstations. Many scientists are simply unaware of the wealth of extremely useful, `off-the-shelf` software that already exists on the Macintosh for scientific graphical and statistical analysis.

  9. Light redirective display panel and a method of making a light redirective display panel

    SciTech Connect (OSTI)

    Veligdan, James T.

    2002-01-01

    An optical display panel which provides improved light intensity at a viewing angle by redirecting light emitting from the viewing screen, and a method of making a light redirective display panel, are disclosed. The panel includes an inlet face at one end for receiving light, and an outlet screen at an opposite end for displaying the light. The inlet face is defined at one end of a transparent body, which body may be formed by a plurality of waveguides, and the outlet screen is defined at an opposite end of the body. The screen includes light redirective elements at the outlet screen for re-directing light emitting from the outlet screen. The method includes stacking a plurality of glass sheets, with a layer of adhesive or epoxy between each sheet, curing the adhesive to form a stack, placing the stack against a saw and cutting the stack at two opposite ends to form a wedge-shaped panel having an inlet face and an outlet face, and forming at the outlet face a plurality of light redirective elements which direct light incident on the outlet face into a controlled light cone.

  10. Light Redirective Display Panel And A Method Of Making A Light Redirective Display Panel

    SciTech Connect (OSTI)

    Veligdan, James T.

    2005-07-26

    An optical display panel which provides improved light intensity at a viewing angle by redirecting light emitting from the viewing screen, and a method of making a light redirective display panel, are disclosed. The panel includes an inlet face at one end for receiving light, and an outlet screen at an opposite end for displaying the light. The inlet face is defined at one end of a transparent body, which body may be formed by a plurality of waveguides, and the outlet screen is defined at an opposite end of the body. The screen includes light redirective elements at the outlet screen for re-directing light emitting from the outlet screen. The method includes stacking a plurality of glass sheets, with a layer of adhesive or epoxy between each sheet, curing the adhesive to form a stack, placing the stack against a saw and cutting the stack at two opposite ends to form a wedge-shaped panel having an inlet face and an outlet face, and forming at the outlet face a plurality of light redirective elements which direct light incident on the outlet face into a controlled light cone.

  11. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  12. Growing intermetallic single crystals using in situ decanting

    SciTech Connect (OSTI)

    Petrovic, Cedomir; Canfield, Paul; Mellen, Jonathan

    2012-05-16

    High temperature metallic solution growth is one of the most successful and versatile methods for single crystal growth, and is particularly suited for exploratory synthesis. The method commonly utilizes a centrifuge at room temperature and is very successful for the synthesis of single crystal phases that can be decanted from the liquid below the melting point of the silica ampoule. In this paper, we demonstrate the extension of this method that enables single crystal growth and flux decanting inside the furnace at temperatures above 1200C. This not only extends the number of available metallic solvents that can be used in exploratory crystal growth but also can be particularly well suited for crystals that have a rather narrow exposed solidification surface in the equilibrium alloy phase diagram.

  13. The CNG process: Acid gas removal with liquid carbon dioxide

    SciTech Connect (OSTI)

    Liu, Y.C.; Auyang, L.; Brown, W.R.

    1987-01-01

    The CNG acid gas removal process has two unique features: the absorption of sulfur-containing compounds and other trace contaminants with liquid carbon dioxide, and the regeneration of pure liquid carbon dioxide by triple-point crystallization. The process is especially suitable for treating gases which contain large amounts of carbon dioxide and much smaller amounts (relative to carbon dioxide) of hydrogen sulfide. Capital and energy costs are lower than conventional solvent processes. Further, products of the CNG process meet stringent purity specifications without undue cost penalties. A process demonstration unit has been constructed and operated to demonstrate the two key steps of the CNG process. Hydrogen sulfide and carbonyl sulfide removal from gas streams with liquid carbon dioxide absorbent to sub-ppm concentrations has been demonstrated. The production of highly purified liquid carbon dioxide (less than 0.1 ppm total contaminant) by triple-point crystallization also has been demonstrated.

  14. Lighted display devices for producing static or animated visual displays, including animated facial features

    DOE Patents [OSTI]

    Heilbron, Valerie J; Clem, Paul G; Cook, Adam Wade

    2014-02-11

    An illuminated display device with a base member with a plurality of cavities therein. Illumination devices illuminate the cavities and emit light through an opening of the cavities in a pattern, and a speaker can emit sounds in synchronization with the pattern. A panel with translucent portions can overly the base member and the cavities. An animated talking character can have an animated mouth cavity complex with multiple predetermined mouth lighting configurations simulative of human utterances. The cavities can be open, or optical waveguide material or positive members can be disposed therein. Reflective material can enhance internal reflectance and light emission.

  15. Electronic Structure of Cobalt Nanocrystals Suspended in Liquid

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Wednesday, 30 April 2008 00:00 Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface

  16. REA Refrigerated Display Case LED Lighting Performance Specification |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy REA Refrigerated Display Case LED Lighting Performance Specification REA Refrigerated Display Case LED Lighting Performance Specification A Retailer Energy Alliances (REA) Project rea_refrig_display_spec.pdf (300.24 KB) More Documents & Publications CBEA LED Site Lighting Specification - Version 1.3, Released 2/15/2012 Model Specification for LED Roadway Luminaires, V2.0 CBEA High-Efficiency Parking Structure Lighting Specification

  17. Automated macromolecular crystallization screening

    DOE Patents [OSTI]

    Segelke, Brent W.; Rupp, Bernhard; Krupka, Heike I.

    2005-03-01

    An automated macromolecular crystallization screening system wherein a multiplicity of reagent mixes are produced. A multiplicity of analysis plates is produced utilizing the reagent mixes combined with a sample. The analysis plates are incubated to promote growth of crystals. Images of the crystals are made. The images are analyzed with regard to suitability of the crystals for analysis by x-ray crystallography. A design of reagent mixes is produced based upon the expected suitability of the crystals for analysis by x-ray crystallography. A second multiplicity of mixes of the reagent components is produced utilizing the design and a second multiplicity of reagent mixes is used for a second round of automated macromolecular crystallization screening. In one embodiment the multiplicity of reagent mixes are produced by a random selection of reagent components.

  18. NNSA's Cutting Edge Science and Research on Display at Annual...

    National Nuclear Security Administration (NNSA)

    NNSA's Cutting Edge Science and Research on Display at Annual AAAS Meeting February 17, ... newly elected fellows at the American Association for the Advancement of Science (AAAS). ...

  19. Cambridge Display Technology Ltd CDT | Open Energy Information

    Open Energy Info (EERE)

    Technology Ltd CDT Jump to: navigation, search Name: Cambridge Display Technology Ltd (CDT) Place: Cambridgeshire, United Kingdom Zip: CB3 6DW Product: A major player in the...

  20. LG Display Everlight Electronics JV | Open Energy Information

    Open Energy Info (EERE)

    China Product: China-based joint venture focused on the production of LED backlight packaging. References: LG Display & Everlight Electronics JV1 This article is a stub. You...

  1. Health monitoring display system for a complex plant

    DOE Patents [OSTI]

    Ridolfo, Charles F.; Harmon, Daryl L.; Colin, Dreyfuss

    2006-08-08

    A single page enterprise wide level display provides a comprehensive readily understood representation of the overall health status of a complex plant. Color coded failure domains allow rapid intuitive recognition of component failure status. A three-tier hierarchy of displays provide details on the health status of the components and systems displayed on the enterprise wide level display in a manner that supports a logical drill down to the health status of sub-components on Tier 1 to expected faults of the sub-components on Tier 2 to specific information relative to expected sub-component failures on Tier 3.

  2. High Efficiency Motors for Refrigerated Open Display Cases

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Efficiency Motors for Refrigerated Open Display Cases 2015 Building Technologies Office Peer Review PJ Piper, pjpiper@qmpower.com CEO, QM Power, Inc. Project Summary Timeline: ...

  3. Non-intrusive ultrasonic liquid-in-line detector for small diameter tubes. [Patent application

    DOE Patents [OSTI]

    Piper, T.C.

    1980-09-24

    An arrangement for detecting liquids in a line, using non-intrusive ultrasonic techniques is disclosed. In this arrangement, four piezoelectric crystals are arranged in pairs about a 0.078 inch o.d. pipe. An ultrasonic tone burst is transmitted along the pipe, between crystal pairs, and the amplitude of the received tone burst indicates the absence/presence of liquid in the pipe.

  4. Non-intrusive ultrasonic liquid-in-line detector for small diameter tubes

    DOE Patents [OSTI]

    Piper, Thomas C.

    1982-01-01

    An arrangement for deleting liquid in a line, using non-intrusive ultrasonic techniques is disclosed. In this arrangement, four piezoelectric crystals are arranged in pairs about a 0.072 inch o.d. pipe. An ultrasonic tone burst is transmitted along the pipe, between crystal pairs, and the amplitude of the received tone burst indicates the absence/presence of liquid in the pipe.

  5. Phononic crystal devices

    SciTech Connect (OSTI)

    El-Kady, Ihab F.; Olsson, Roy H.

    2012-01-10

    Phononic crystals that have the ability to modify and control the thermal black body phonon distribution and the phonon component of heat transport in a solid. In particular, the thermal conductivity and heat capacity can be modified by altering the phonon density of states in a phononic crystal. The present invention is directed to phononic crystal devices and materials such as radio frequency (RF) tags powered from ambient heat, dielectrics with extremely low thermal conductivity, thermoelectric materials with a higher ratio of electrical-to-thermal conductivity, materials with phononically engineered heat capacity, phononic crystal waveguides that enable accelerated cooling, and a variety of low temperature application devices.

  6. Tunable plasmonic crystal

    DOE Patents [OSTI]

    Dyer, Gregory Conrad; Shaner, Eric A.; Reno, John L.; Aizin, Gregory

    2015-08-11

    A tunable plasmonic crystal comprises several periods in a two-dimensional electron or hole gas plasmonic medium that is both extremely subwavelength (.about..lamda./100) and tunable through the application of voltages to metal electrodes. Tuning of the plasmonic crystal band edges can be realized in materials such as semiconductors and graphene to actively control the plasmonic crystal dispersion in the terahertz and infrared spectral regions. The tunable plasmonic crystal provides a useful degree of freedom for applications in slow light devices, voltage-tunable waveguides, filters, ultra-sensitive direct and heterodyne THz detectors, and THz oscillators.

  7. Liquid level detector

    DOE Patents [OSTI]

    Grasso, Albert P.

    1986-01-01

    A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  8. Liquid level detector

    DOE Patents [OSTI]

    Grasso, A.P.

    1984-02-21

    A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

  9. Electronic displays using optically pumped luminescent semiconductor nanocrystals

    DOE Patents [OSTI]

    Weiss, Shimon; Schlamp, Michael C.; Alivisatos, A. Paul

    2005-03-08

    A multicolor electronic display is based on an array of luminescent semiconductor nanocrystals. Nanocrystals which emit light of different colors are grouped into pixels. The nanocrystals are optically pumped to produce a multicolor display. Different sized nanocrystals are used to produce the different colors. A variety of pixel addressing systems can be used.

  10. Electronic displays using optically pumped luminescent semiconductor nanocrystals

    DOE Patents [OSTI]

    Weiss, Shimon; Schlamp, Michael C.; Alivisatos, A. Paul

    2011-09-27

    A multicolor electronic display is based on an array of luminescent semiconductor nanocrystals. Nanocrystals which emit light of different colors are grouped into pixels. The nanocrystals are optically pumped to produce a multicolor display. Different sized nanocrystals are used to produce the different colors. A variety of pixel addressing systems can be used.

  11. Electronic displays using optically pumped luminescent semiconductor nanocrystals

    DOE Patents [OSTI]

    Weiss, Shimon; Schlamp, Michael C; Alivisatos, A. Paul

    2014-02-11

    A multicolor electronic display is based on an array of luminescent semiconductor nanocrystals. Nanocrystals which emit light of different colors are grouped into pixels. The nanocrystals are optically pumped to produce a multicolor display. Different sized nanocrystals are used to produce the different colors. A variety of pixel addressing systems can be used.

  12. Electronic displays using optically pumped luminescent semiconductor nanocrystals

    DOE Patents [OSTI]

    Weiss, Shimon; Schlamp, Michael C.; Alivisatos, A. Paul

    2010-04-13

    A multicolor electronic display is based on an array of luminescent semiconductor nanocrystals. Nanocrystals which emit light of different colors are grouped into pixels. The nanocrystals are optically pumped to produce a multicolor display. Different sized nanocrystals are used to produce the different colors. A variety of pixel addressing systems can be used.

  13. Electronic displays using optically pumped luminescent semiconductor nanocrystals

    SciTech Connect (OSTI)

    Weiss, Shimon; Schlam, Michael C; Alivisatos, A. Paul

    2014-03-25

    A multicolor electronic display is based on an array of luminescent semiconductor nanocrystals. Nanocrystals which emit tight of different colors are grouped into pixels. The nanocrystals are optically pumped to produce a multicolor display. Different sized nanocrystals are used to produce the different colors. A variety of pixel addressing systems can be used.

  14. Electronic displays using optically pumped luminescent semiconductor nanocrystals

    SciTech Connect (OSTI)

    Weiss, Shimon; Schlamp, Michael C.; Alivisatos, Paul A.

    2015-11-10

    A multicolor electronic display is based on an array of luminescent semiconductor nanocrystals. Nanocrystals which emit tight of different colors are grouped into pixels. The nanocrystals are optically pumped to produce a multicolor display. Different sized nanocrystals are used to produce the different colors. A variety of pixel addressing systems can be used.

  15. Electronic displays using optically pumped luminescent semiconductor nanocrystals

    SciTech Connect (OSTI)

    Weiss, Shimon; Schlamp, Michael C.; Alivisatos, A. Paul

    2015-06-23

    A multicolor electronic display is based on an array of luminescent semiconductor nanocrystals. Nanocrystals which emit light of different colors are grouped into pixels. The nanocrystals are optically pumped to produce a multicolor display. Different sized nanocrystals are used to produce the different colors. A variety of pixel addressing systems can be used.

  16. Liquid-Phase Quartz Crystal Microbalance for Photovoltaics Research: Preprint

    SciTech Connect (OSTI)

    Perkins, C. L.; Li, X.

    2008-05-01

    This paper describes the new low-cost tool, its capabilities, potential pitfalls with its use, initial results, and possible future research directions.

  17. Laser beam remodels liquid crystals on the fly

    SciTech Connect (OSTI)

    Smart, Ashley G.

    2015-06-15

    The laser can be used like a stylus to imprint microdomains of arbitrary shape and prescribed orientation.

  18. Electro-optical switching and memory display device

    DOE Patents [OSTI]

    Skotheim, T.A.; O'Grady, W.E.; Linkous, C.A.

    1983-12-29

    An electro-optical display device having a housing with wall means including one transparent wall and at least one other wall. Counter electrodes are positioned on the transparent wall and display electrodes are positioned on the other wall with both electrodes in electrically conductive relationship with an electrolyte. Circuits means are connected to the display and counter electrodes to apply different predetermined control potentials between them. The display electrodes are covered with a thin electrically conductive polymer film that is characterized according to the invention by having embedded in it pigment molecules as counter ions. The display device is operable to be switched to a plurality of different visual color states at an exceptionally rapid switching rate while each of the color states is characterized by possessing good color intensity and definition.

  19. Electro-optical switching and memory display device

    DOE Patents [OSTI]

    Skotheim, Terje A.; O'Grady, William E.; Linkous, Clovis A.

    1986-01-01

    An electro-optical display device having a housing with wall means including one transparent wall and at least one other wall. Counter electrodes are positioned on the transparent wall and display electrodes are positioned on the other wall with both electrodes in electrically conductive relationship with an electrolyte. Circuit means are connected to the display and counter electrodes to apply different predetermined control potentials between them. The display electrodes are covered with a thin electrically conductive polymer film that is characterized according to the invention by having embedded in it pigment molecules as counter ions. The display device is operable to be switched to a plurality of different visual color states at an exceptionally rapid switching rate while each of the color states is characterized by possessing good color intensity and definition.

  20. Interactive display system having a digital micromirror imaging device

    DOE Patents [OSTI]

    Veligdan, James T.; DeSanto, Leonard; Kaull, Lisa; Brewster, Calvin

    2006-04-11

    A display system includes a waveguide optical panel having an inlet face and an opposite outlet face. A projector cooperates with a digital imaging device, e.g. a digital micromirror imaging device, for projecting an image through the panel for display on the outlet face. The imaging device includes an array of mirrors tiltable between opposite display and divert positions. The display positions reflect an image light beam from the projector through the panel for display on the outlet face. The divert positions divert the image light beam away from the panel, and are additionally used for reflecting a probe light beam through the panel toward the outlet face. Covering a spot on the panel, e.g. with a finger, reflects the probe light beam back through the panel toward the inlet face for detection thereat and providing interactive capability.

  1. Precision liquid level sensor

    DOE Patents [OSTI]

    Field, M.E.; Sullivan, W.H.

    A precision liquid level sensor utilizes a balanced bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

  2. Renewable liquid reflection grating

    DOE Patents [OSTI]

    Ryutov, Dmitri D.; Toor, Arthur

    2003-10-07

    A renewable liquid reflection grating. Electrodes are operatively connected to a conducting liquid in an arrangement that produces a reflection grating and driven by a current with a resonance frequency. In another embodiment, the electrodes create the grating by a resonant electrostatic force acting on a dielectric liquid.

  3. Liquid detection circuit

    DOE Patents [OSTI]

    Regan, Thomas O.

    1987-01-01

    Herein is a circuit which is capable of detecting the presence of liquids, especially cryogenic liquids, and whose sensor will not overheat in a vacuum. The circuit parameters, however, can be adjusted to work with any liquid over a wide range of temperatures.

  4. Enzyme Activity and Biomolecule Templating at Liquid and Solid Interfaces

    SciTech Connect (OSTI)

    Harvey W. Blanch

    2004-12-01

    There are two main components of this research program. The first involves studies of the adsorption and catalytic activity of proteins at fluid-fluid and fluid-solid interfaces; the second employs biological macromolecules as templates at the solid-liquid interface for controlled crystallization of inorganic materials, to provide materials with specific functionality.

  5. Quartz crystal growth

    DOE Patents [OSTI]

    Baughman, Richard J.

    1992-01-01

    A process for growing single crystals from an amorphous substance that can undergo phase transformation to the crystalline state in an appropriate solvent. The process is carried out in an autoclave having a lower dissolution zone and an upper crystallization zone between which a temperature differential (.DELTA.T) is maintained at all times. The apparatus loaded with the substance, solvent, and seed crystals is heated slowly maintaining a very low .DELTA.T between the warmer lower zone and cooler upper zone until the amorphous substance is transformed to the crystalline state in the lower zone. The heating rate is then increased to maintain a large .DELTA.T sufficient to increase material transport between the zones and rapid crystallization. .alpha.-Quartz single crystal can thus be made from fused quartz in caustic solvent by heating to 350.degree. C. stepwise with a .DELTA.T of 0.25.degree.-3.degree. C., increasing the .DELTA.T to about 50.degree. C. after the fused quartz has crystallized, and maintaining these conditions until crystal growth in the upper zone is completed.

  6. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, James E.; Bolton, Richard D.

    1999-01-01

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans.

  7. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, J.E.; Bolton, R.D.

    1999-03-02

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans. 4 figs.

  8. Paducah Wall Display Unveiled at DOE Headquarters | Department of Energy

    Energy Savers [EERE]

    Wall Display Unveiled at DOE Headquarters Paducah Wall Display Unveiled at DOE Headquarters September 11, 2015 - 3:48pm Addthis Federal, state and local Kentucky officials joined Secretary of Energy Dr. Ernest Moniz (third from left) and Senate Majority Mitch McConnell on September 10, 2015 as they cut the ribbon introducing the new Paducah Site wall display on the Fifth Floor of DOE’s Forrestal Building in Washington, D.C. Pictured (left-right) are: U.S. Rep. Ed Whitfield, Sen. McConnell,

  9. Selective posttranslational modification of phage-displayed polypeptides

    DOE Patents [OSTI]

    Tsao, Meng-Lin; Tian, Feng; Schultz, Peter

    2013-02-05

    The invention relates to posttranslational modification of phage-displayed polypeptides. These displayed polypeptides comprise at least one unnatural amino acid, e.g., an aryl-azide amino acid such as p-azido-L-phenylalanine, or an alkynyl-amino acid such as para-propargyloxyphenylalanine, which are incorporated into the phage-displayed fusion polypeptide at a selected position by using an in vivo orthogonal translation system comprising a suitable orthogonal aminoacyl-tRNA synthetase and a suitable orthogonal tRNA species. These unnatural amino acids advantageously provide targets for posttranslational modifications such as azide-alkyne [3+2]cycloaddition reactions and Staudinger modifications.

  10. Selective posttranslational modification of phage-displayed polypeptides

    DOE Patents [OSTI]

    Tsao, Meng-Lin; Tian, Feng; Schultz, Peter

    2013-11-19

    The invention relates to posttranslational modification of phage-displayed polypeptides. These displayed polypeptides comprise at least one unnatural amino acid, e.g., an aryl-azide amino acid such as p-azido-L-phenylalanine, or an alkynyl-amino acid such as para-propargyloxyphenylalanine, which are incorporated into the phage-displayed fusion polypeptide at a selected position by using an in vivo orthogonal translation system comprising a suitable orthogonal aminoacyl-tRNA synthetase and a suitable orthogonal tRNA species. These unnatural amino acids advantageously provide targets for posttranslational modifications such as azide-alkyne [3+2] cycloaddition reactions and Staudinger modifications.

  11. Large single domain 123 material produced by seeding with single crystal rare earth barium copper oxide single crystals

    DOE Patents [OSTI]

    Todt, Volker; Miller, Dean J.; Shi, Donglu; Sengupta, Suvankar

    1998-01-01

    A method of fabricating bulk YBa.sub.2 Cu.sub.3 O.sub.x where compressed powder oxides and/or carbonates of Y and Ba and Cu present in mole ratios to form YBa.sub.2 Cu.sub.3 O.sub.x are heated in the presence of a Nd.sub.1+x Ba.sub.2-x Cu.sub.3 O.sub.y seed crystal to a temperature sufficient to form a liquid phase in the YBa.sub.2 Cu.sub.3 O.sub.x while maintaining the seed crystal solid. The materials are slowly cooled to provide a YBa.sub.2 Cu.sub.3 O.sub.x material having a predetermined number of domains between 1 and 5. Crack-free single domain materials can be formed using either plate shaped seed crystals or cube shaped seed crystals with a pedestal of preferential orientation material.

  12. Commercial Display Systems: Proposed Penalty (2013-CE-5350)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Commercial Display Systems, LLC failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

  13. Property:Integrated Display/Graphics | Open Energy Information

    Open Energy Info (EERE)

    DisplayGraphics" Showing 22 pages using this property. A Alden Large Flume + Lab View, Test Point Alden Small Flume + Lab View, Test Point Alden Tow Tank + Lab View, Test Point...

  14. Renormalization Group Flows, Cycles, anddisplay='inline...

    Office of Scientific and Technical Information (OSTI)

    Group Flows, Cycles, anddisplay'inline'>c-Theorem Folklore Curtright, Thomas L.; Jin, Xiang; Zachos, Cosmas K. Not Available American Physical Society None...

  15. High Efficiency Motors for Refrigerated Open Display Cases

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Motors for Refrigerated Open Display Cases 2016 Building Technologies Office Peer Review PJ Piper, pjpiper@qmpower.com CEO, QM Power, Inc. 2 Project Summary Budget: Total DOE to ...

  16. Interactive display system having a matrix optical detector

    DOE Patents [OSTI]

    Veligdan, James T.; DeSanto, Leonard

    2007-01-23

    A display system includes a waveguide optical panel having an inlet face and an opposite outlet face. An image beam is projected across the inlet face laterally and transversely for display on the outlet face. An optical detector including a matrix of detector elements is optically aligned with the inlet face for detecting a corresponding lateral and transverse position of an inbound light spot on the outlet face.

  17. Parade of Homes Display Features Energy-Saving Ideas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Parade of Homes Display Features Energy-Saving Ideas For more information contact: George Douglas (303) 275-4096 e:mail: george_douglas@nrel.gov Golden, Colo., July 29, 1998 — The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory will showcase energy efficient and solar energy ideas for homebuyers and homebuilders during the Denver-area Parade of Homes. NREL's exhibit features information on energy-efficient lighting, building design, windows and insulation. The display

  18. Multifunctional recombinant phycobiliprotein-based fluorescent constructs and phycobilisome display

    DOE Patents [OSTI]

    Glazer, Alexander N.; Cai, Yuping

    2007-01-30

    The invention provides multifunctional fusion constructs which are rapidly incorporated into a macromolecular structure such as a phycobilisome such that the fusion proteins are separated from one another and unable to self-associate. The invention provides methods and compositions for displaying a functional polypeptide domain on an oligomeric phycobiliprotein, including fusion proteins comprising a functional displayed domain and a functional phycobiliprotein domain incorporated in a functional oligomeric phycobiliprotein. The fusion proteins provide novel specific labeling reagents.

  19. Multifunctional recombinant phycobiliprotein-based fluorescent constructs and phycobilisome display

    DOE Patents [OSTI]

    Glazer, Alexander N.; Cai, Yuping

    2003-11-18

    The invention provides multifunctional fusion constructs which are rapidly incorporated into a macromolecular structure such as a phycobilisome such that the fusion proteins are separated from one another and unable to self-associate. The invention provides methods and compositions for displaying a functional polypeptide domain on an oligomeric phycobiliprotein, including fusion proteins comprising a functional displayed domain and a functional phycobiliprotein domain incorporated in a functional oligomeric phycobiliprotein. The fusion proteins provide novel specific labeling reagents.

  20. Multifunctional recombinant phycobiliprotein-based fluorescent constructs and phycobilisome display

    DOE Patents [OSTI]

    Glazer, Alexander N.; Cai, Yuping

    2007-02-13

    The invention provides multifunctional fusion constructs which are rapidly incorporated into a macromolecular structure such as a phycobilisome such that the fusion proteins are separated from one another and unable to self-associate. The invention provides methods and compositions for displaying a functional polypeptide domain on an oligomeric phycobiliprotein. including fusion proteins comprising a functional displayed domain and a functional phycobiliprotein domain incorporated in a functional oligomeric phycobiliprotein. The fusion proteins provide novel specific labeling reagents.

    1. Display of Hi-Res Data | Princeton Plasma Physics Lab

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Display of Hi-Res Data This invention enables plotting a very large number of data points relative to the number of display pixels without losing significant information about the data. A user operating the system can set the threshold for highlighting locations on the plot that exceed a specific variance or range. Highlighted areas can be dynamically explored at the full resolution of the data. No.: M-874 Inventor(s): Eliot A Feibush

    2. Durable electrooptic devices comprising ionic liquids

      DOE Patents [OSTI]

      Agrawal, Anoop; Cronin, John P.; Tonazzi, Juan C. L.; Warner, Benjamin P.; McCleskey, T. Mark; Burrell, Anthony K.

      2005-11-01

      Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF3SO3-), bis(trifluoromethylsulfonyl)imide ((CF3SO2)2N-), bis(perfluoroethylsulfonyl)imide ((CF3CF2SO2)2N-) and tris(trifluoromethylsulfonyl)methide ((CF3SO2)3C-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

    3. Liquid level detector

      DOE Patents [OSTI]

      Tshishiku, Eugene M.

      2011-08-09

      A liquid level detector for conductive liquids for vertical installation in a tank, the detector having a probe positioned within a sheath and insulated therefrom by a seal so that the tip of the probe extends proximate to but not below the lower end of the sheath, the lower end terminating in a rim that is provided with notches, said lower end being tapered, the taper and notches preventing debris collection and bubble formation, said lower end when contacting liquid as it rises will form an airtight cavity defined by the liquid, the interior sheath wall, and the seal, the compression of air in the cavity preventing liquid from further entry into the sheath and contact with the seal. As a result, the liquid cannot deposit a film to form an electrical bridge across the seal.

    4. Method of forming a spacer for field emission flat panel displays

      SciTech Connect (OSTI)

      Bernhardt, A.F.; Contolini, R.J.

      1997-08-19

      Spacers are disclosed for applications such as field emission flat panel displays and vacuum microelectronics, and which involves the application of aerogel/xerogel technology to the formation of the spacer. In a preferred approach the method uses a mold and mold release agent wherein the gel precursor is a liquid which can be applied to the mold filling holes which expose the substrate (either the baseplate or the faceplate). A release agent is applied to the mold prior to precursor application to ease removal of the mold after formation of the dielectric spacer. The shrinkage of the gel during solvent extraction also improves mold removal. The final spacer material is a good dielectric, such as silica, secured to the substrate. 3 figs.

    5. Method of forming a spacer for field emission flat panel displays

      SciTech Connect (OSTI)

      Bernhardt, Anthony F.; Contolini, Robert J.

      1997-01-01

      Spacers for applications such as field emission flat panel displays and vacuum microelectronics, and which involves the application of aerogel/xerogel technology to the formation of the spacer. In a preferred approach the method uses a mold and mold release agent wherein the gel precursor is a liquid which can be applied to the mold filling holes which expose the substrate (either the baseplate or the faceplate). A release agent is applied to the mold prior to precursor application to ease removal of the mold after formation of the dielectric spacer. The shrinkage of the gel during solvent extraction also improves mold removal. The final spacer material is a good dielectric, such as silica, secured to the substrate.

    6. LIQUID CYCLONE CONTACTOR

      DOE Patents [OSTI]

      Whatley, M.E.; Woods, W.M.

      1962-09-01

      This invention relates to liquid-liquid extraction systems. The invention, an improved hydroclone system, comprises a series of serially connected, axially aligned hydroclones, each of which is provided with an axially aligned overflow chamber. The chambers are so arranged that rotational motion of a fluid being passed through the system is not lost in passing from chamber to chamber; consequently, this system is highly efficient in contacting and separating two immiscible liquids. (AEC)

    7. Gas scrubbing liquids

      DOE Patents [OSTI]

      Lackey, Walter J.; Lowrie, Robert S.; Sease, John D.

      1981-01-01

      Fully chlorinated and/or fluorinated hydrocarbons are used as gas scrubbing liquids for preventing noxious gas emissions to the atmosphere.

    8. HV in Noble Liquids

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      in Noble Liquids 8 Nov 2013 High Voltage Tests for MicroBooNE Byron Lundberg Fermilab presenting for the Collaboration & Task Force 4 1 Friday, November 8, 13 HV in Noble Liquids MicroBooNE Experiment  A liquid argon time projection chamber (LAr TPC) containing 170 tons of liquid argon, and located on the Booster Neutrino Beamline.  MiniBooNE  MicroBooNE 8,#256#wires;#U,V,Y#planes;#3#mm#spacing# 32#PMTs#for#fast#light#collec?ons# @ L A r T F 2 Friday, November 8, 13 HV in Noble

    9. RENEWABLE LIQUID GETTERING PUMP

      DOE Patents [OSTI]

      Batzer, T.H.

      1962-08-21

      A method and structure were developed for pumping gases by simple absorption into a liquid gettering material. The invention comprises means ror continuously pumping a liquid getterrng material from a reservoir to the top of a generally vertical surface disposed in a vacuum pumping chamber to receive gaseous and other particles in the liquid gettering material which continuously flows downward over the vertical suiface. Means are provided for continuous removal, degassing, and return of a portion of the liquid gettering material from the reservoir connected with collectrng means at the base of the generally vertical plate. (AEC)

    10. Ultrasonic liquid level detector

      DOE Patents [OSTI]

      Kotz, Dennis M.; Hinz, William R.

      2010-09-28

      An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

    11. Chiral Isotropic Liquids from Achiral Molecules

      SciTech Connect (OSTI)

      L Hough; M Spannuth; M Nakata; D Coleman; C Jones; G Dantlgraber; C Tschierske; J Watanabe; N Clark; et al.

      2011-12-31

      A variety of simple bent-core molecules exhibit smectic liquid crystal phases of planar fluid layers that are spontaneously both polar and chiral in the absence of crystalline order. We found that because of intralayer structural mismatch, such layers are also only marginally stable against spontaneous saddle splay deformation, which is incompatible with long-range order. This results in macroscopically isotropic fluids that possess only short-range orientational and positional order, in which the only macroscopically broken symmetry is chirality - even though the phases are formed from achiral molecules. Their conglomerate domains exhibit optical rotatory powers comparable to the highest ever found for isotropic fluids of chiral molecules.

    12. Graphical User Interface Color Display Animation Interaction Tool

      Energy Science and Technology Software Center (OSTI)

      1999-10-05

      The Nuclear Plant Analyzer (NPA) is a highly flexible graphical user interface for displaying the results of a calculation, typically generated by RELAP5 or other code. This display consists of one or more picture, called masks, that mimic the host code input. This mask can be animated to display user-specified code output information mapped as colors, dials, moving arrows, etc., on the mask. The user can also interact with the control systems of the hostmore » input file as the execution progresses, thereby controlling aspects of the calculation. The Computer Visual System (CVS) creates, edits, and animates the the masks for use in the NPA.« less

    13. Junction-based field emission structure for field emission display

      DOE Patents [OSTI]

      Dinh, Long N.; Balooch, Mehdi; McLean, II, William; Schildbach, Marcus A.

      2002-01-01

      A junction-based field emission display, wherein the junctions are formed by depositing a semiconducting or dielectric, low work function, negative electron affinity (NEA) silicon-based compound film (SBCF) onto a metal or n-type semiconductor substrate. The SBCF can be doped to become a p-type semiconductor. A small forward bias voltage is applied across the junction so that electron transport is from the substrate into the SBCF region. Upon entering into this NEA region, many electrons are released into the vacuum level above the SBCF surface and accelerated toward a positively biased phosphor screen anode, hence lighting up the phosphor screen for display. To turn off, simply switch off the applied potential across the SBCF/substrate. May be used for field emission flat panel displays.

    14. Frequency doubling crystals

      DOE Patents [OSTI]

      Wang, Francis; Velsko, Stephan P.

      1989-01-01

      A systematic approach to the production of frequency conversion crystals is described in which a chiral molecule has attached to it a "harmonic generating unit" which contributes to the noncentrosymmetry of the molecule. Certain preferred embodiments of such harmonic generating units include carboxylate, guanadyly and imidazolyl units. Certain preferred crystals include L-arginine fluoride, deuterated L-arginine fluoride, L-arginine chloride monohydrate, L-arginine acetate, dithallium tartrate, ammonium N-acetyl valine, N-acetyl tyrosine and N-acetyl hydroxyproline. Chemical modifications of the chiral molecule, such as deuteration, halogenation and controlled counterion substitution are available to adapt the dispersive properties of a crystal in a particular wavelength region.

    15. Precision liquid level sensor

      DOE Patents [OSTI]

      Field, M.E.; Sullivan, W.H.

      1985-01-29

      A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge. 2 figs.

    16. Precision liquid level sensor

      DOE Patents [OSTI]

      Field, Michael E.; Sullivan, William H.

      1985-01-01

      A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

    17. Synthesis of ionic liquids

      DOE Patents [OSTI]

      Dai, Sheng [Knoxville, TN; Luo, Huimin [Knoxville, TN

      2008-09-09

      Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic liqand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

    18. Synthesis of ionic liquids

      DOE Patents [OSTI]

      Dai, Sheng (Knoxville, TN); Luo, Huimin (Knoxville, TN)

      2011-11-01

      Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic ligand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

    19. Liquid heat capacity lasers

      DOE Patents [OSTI]

      Comaskey, Brian J.; Scheibner, Karl F.; Ault, Earl R.

      2007-05-01

      The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

    20. Interactive display system having a scaled virtual target zone

      DOE Patents [OSTI]

      Veligdan, James T.; DeSanto, Leonard

      2006-06-13

      A display system includes a waveguide optical panel having an inlet face and an opposite outlet face. A projector and imaging device cooperate with the panel for projecting a video image thereon. An optical detector bridges at least a portion of the waveguides for detecting a location on the outlet face within a target zone of an inbound light spot. A controller is operatively coupled to the imaging device and detector for displaying a cursor on the outlet face corresponding with the detected location of the spot within the target zone.

    1. University of Nevada Las Vegas LED Display Engineering

      SciTech Connect (OSTI)

      2010-08-31

      The primary objective of this part of the project is to develop and implement a method that compensates for the inefficiency of the green LED. The proposed engineering solution which will be the backbone of this project will be to use RGBW combination in every pixel to save energy. Two different RGBW geometrical pixel configurations will be implemented and compared against traditional LED configurations. These configurations will be analyzed for energy efficiency while keeping the quality of the display the same. Cost of the addition of white LEDs to displays along with energy cost savings will be presented and analyzed.

    2. FRACTIONAL CRYSTALLIZATION FEED ENVELOPE

      SciTech Connect (OSTI)

      HERTING DL

      2008-03-19

      Laboratory work was completed on a set of evaporation tests designed to establish a feed envelope for the fractional crystallization process. The feed envelope defines chemical concentration limits within which the process can be operated successfully. All 38 runs in the half-factorial design matrix were completed successfully, based on the qualitative definition of success. There is no feed composition likely to be derived from saltcake dissolution that would cause the fractional crystallization process to not meet acceptable performance requirements. However, some compositions clearly would provide more successful operation than other compositions.

    3. FRACTIONAL CRYSTALLIZATION FLOWSHEET TESTS WITH ACTUAL TANK WASTE

      SciTech Connect (OSTI)

      HERTING, D.L.

      2007-04-13

      Laboratory-scale flowsheet tests of the fractional crystallization process were conducted with actual tank waste samples in a hot cell at the 2224 Laboratory. The process is designed to separate medium-curie liquid waste into a low-curie stream for feeding to supplemental treatment and a high-curie stream for double-shell tank storage. Separations criteria (for Cesium-137 sulfate and sodium) were exceeded in all three of the flowsheet tests that were performed.

    4. FRACTIONAL CRYSTALLIZATION FLOWSHEET TESTS WITH ACTUAL TANK WASTE

      SciTech Connect (OSTI)

      HERTING, D.L.

      2006-10-18

      Laboratory-scale flowsheet tests of the fractional crystallization process were conducted with actual tank waste samples in a hot cell at the 222-S Laboratory. The process is designed to separate medium-curie liquid waste into a low-curie stream for feeding to supplemental treatment and a high-curie stream for double-shell tank storage. Separations criteria (for Cs-137 sulfate, and sodium) were exceeded in all three of the flowsheet tests that were performed.

    5. Renewable liquid reflecting zone plate

      DOE Patents [OSTI]

      Toor, Arthur; Ryutov, Dmitri D.

      2003-12-09

      A renewable liquid reflecting zone plate. Electrodes are operatively connected to a dielectric liquid in a circular or other arrangement to produce a reflecting zone plate. A system for renewing the liquid uses a penetrable substrate.

    6. Epitaxial thin film growth of LiH using a liquid-Li atomic template

      SciTech Connect (OSTI)

      Oguchi, Hiroyuki; Ikeshoji, Tamio; Orimo, Shin-ichi; Ohsawa, Takeo; Shiraki, Susumu; Hitosugi, Taro; Kuwano, Hiroki

      2014-11-24

      We report on the synthesis of lithium hydride (LiH) epitaxial thin films through the hydrogenation of a Li melt, forming abrupt LiH/MgO interface. Experimental and first-principles molecular dynamics studies reveal a comprehensive microscopic picture of the crystallization processes, which sheds light on the fundamental atomistic growth processes that have remained unknown in the vapor-liquid-solid method. We found that the periodic structure that formed, because of the liquid-Li atoms at the film/MgO-substrate interface, serves as an atomic template for the epitaxial growth of LiH crystals. In contrast, films grown on the Al{sub 2}O{sub 3} substrates indicated polycrystalline films with a LiAlO{sub 2} secondary phase. These results and the proposed growth process provide insights into the preparation of other alkaline metal hydride thin films on oxides. Further, our investigations open the way to explore fundamental physics and chemistry of metal hydrides including possible phenomena that emerge at the heterointerfaces of metal hydrides.

    7. Real-time graphic displays in Mars. [AVLIS process

      SciTech Connect (OSTI)

      Treadway, T.

      1985-12-01

      Real-time diagnostic data of the AVLIS process is displayed in the form of a two-dimensional plot on selected monitors in the Mars Control Room. Each Mars workstation contains a HP2622 terminal for computer interface to the experiment and a Raster Technologies graphic controller driving a Conrac high resolution color monitor for graphics output.

    8. Flat panel display development activities at Sandia National Laboratories

      SciTech Connect (OSTI)

      DiBello, E.G.; Worobey, W.; Burchett, S.; Hareland, W.; Felter, T.; Mays, B.

      1994-12-31

      The flat panel display development activities underway at Sandia National Laboratories are described. Research is being conducted in the areas of glass substrates, phosphors, large area processes, and electron emissions. Projects are focused on improving process yield, developing large area processes, and using modeling techniques to predict design performance.

    9. Liquid sampling system

      DOE Patents [OSTI]

      Larson, L.L.

      1984-09-17

      A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

    10. Liquid sampling system

      DOE Patents [OSTI]

      Larson, Loren L.

      1987-01-01

      A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

    11. Universally oriented renewable liquid mirror

      DOE Patents [OSTI]

      Ryutov, Dmitri D.; Toor, Arthur

      2004-07-20

      A universally oriented liquid mirror. A liquid and a penetrable unit are operatively connected to provide a mirror that can be universally oriented.

    12. Liquid metal electric pump

      DOE Patents [OSTI]

      Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

      1992-01-14

      An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

    13. Liquid-level detector

      DOE Patents [OSTI]

      Not Available

      1981-01-29

      Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

    14. Liquid metal electric pump

      DOE Patents [OSTI]

      Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

      1992-01-01

      An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

    15. Direct flow crystal growth system

      DOE Patents [OSTI]

      Montgomery, Kenneth E.; Milanovich, Fred P.

      1992-01-01

      A crystal is grown in a constantly filtered solution which is flowed directly into the growing face of a crystal. In a continuous flow system, solution at its saturation temperature is removed from a crystal growth tank, heated above its saturation temperature, filtered, cooled back to its saturation temperature, and returned to the tank.

    16. Direct liquid injection of liquid petroleum gas

      SciTech Connect (OSTI)

      Lewis, D.J.; Phipps, J.R.

      1984-02-14

      A fuel injector and injection system for injecting liquified petroleum gas (LPG) into at least one air/fuel mixing chamber from a storage means that stores pressurized LPG in its liquid state. The fuel injector (including a body), adapted to receive pressurized LPG from the storage means and for selectively delivering the LPG to the air/fuel mixing chamber in its liquified state. The system including means for correcting the injector activation signal for pressure and density variations in the fuel.

    17. Crystal Field Disorder in the Quantum Spin Ice Ground State of Tb2Sn2 xTixO7

      SciTech Connect (OSTI)

      Gaulin, Bruce D.; Zhang, J.; Dahlberg, M. L.; Matthews, Maria J.; Bert, F.; Kermarrec, E.; Fritsch, Katharina; Granroth, Garrett E; Jiramongkolchai, P.; Amato, A.; Baines, C.; Cava, R. J.; Mendels, P.; Schiffer, P

      2015-01-01

      Spin ice physics marries that of hydrogen disorder in water ice, first discussed almost 60 years ago by Pauling, and that of low temperature magnetism on certain networks of connected tetrahedra. Recently the classical spin ice mag- nets Ho2Ti2O7 and Dy2Ti2O7 have shown an emergent artificial magneto- statics , which manifests itself as Coulombic spin correlations and excitations behaving as diffusive magnetic monopoles. The related pyrochlore magnet, Tb2Ti2O7, has been proposed as a quantum variant of spin ice, stabilized by 1 virtual excitations between the crystal field (CF) ground state doublet appro- priate to Tb3+, and its low lying excited state doublet. Isostructural Tb2Sn2O7 displays soft spin ice order, and its Tb3+ ground and excited CF eigenstates are known to differ relative to those of Tb2Ti2O7. We present a comprehensive study of Tb2Sn2 xTixO7 showing a novel, dynamic spin liquid state for all x other than the end members (0, 2). This state is the result of disorder in the low lying Tb3+ CF environments which de-stabilizes the mechanism by which quantum fluctuations contribute to ground state selection in Tb2Sn2 xTixO7.

    18. Liquid level controller

      DOE Patents [OSTI]

      Mangus, J.D.; Redding, A.H.

      1975-07-15

      A system for maintaining two distinct sodium levels within the shell of a heat exchanger having a plurality of J-shaped modular tube bundles each enclosed in a separate shell which extends from a common base portion. A lower liquid level is maintained in the base portion and an upper liquid level is maintained in the shell enwrapping the long stem of the J-shaped tube bundles by utilizing standpipes with a notch at the lower end which decreases in open area the distance from the end of the stand pipe increases and a supply of inert gas fed at a constant rate to produce liquid levels, which will remain generally constant as the flow of liquid through the vessel varies. (auth)

    19. Liquid blocking check valve

      DOE Patents [OSTI]

      Merrill, John T.

      1984-01-01

      A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

    20. Silicon crystal growing by oscillating crucible technique

      DOE Patents [OSTI]

      Schwuttke, G.H.; Kim, K.M.; Smetana, P.

      1983-08-03

      A process for growing silicon crystals from a molten melt comprising oscillating the container during crystal growth is disclosed.

    1. Plenum type crystal growth process

      DOE Patents [OSTI]

      Montgomery, Kenneth E.

      1992-01-01

      Crystals are grown in a tank which is divided by a baffle into a crystal growth region above the baffle and a plenum region below the baffle. A turbine blade or stirring wheel is positioned in a turbine tube which extends through the baffle to generate a flow of solution from the crystal growing region to the plenum region. The solution is pressurized as it flows into the plenum region. The pressurized solution flows back to the crystal growing region through return flow tubes extending through the baffle. Growing crystals are positioned near the ends of the return flow tubes to receive a direct flow of solution.

    2. Dose factor entry and display tool for BNCT radiotherapy

      DOE Patents [OSTI]

      Wessol, Daniel E.; Wheeler, Floyd J.; Cook, Jeremy L.

      1999-01-01

      A system for use in Boron Neutron Capture Therapy (BNCT) radiotherapy planning where a biological distribution is calculated using a combination of conversion factors and a previously calculated physical distribution. Conversion factors are presented in a graphical spreadsheet so that a planner can easily view and modify the conversion factors. For radiotherapy in multi-component modalities, such as Fast-Neutron and BNCT, it is necessary to combine each conversion factor component to form an effective dose which is used in radiotherapy planning and evaluation. The Dose Factor Entry and Display System is designed to facilitate planner entry of appropriate conversion factors in a straightforward manner for each component. The effective isodose is then immediately computed and displayed over the appropriate background (e.g. digitized image).

    3. Electronic Structure of Cobalt Nanocrystals Suspended in Liquid

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of

    4. Electronic Structure of Cobalt Nanocrystals Suspended in Liquid

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of

    5. Electronic Structure of Cobalt Nanocrystals Suspended in Liquid

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of

    6. Electronic Structure of Cobalt Nanocrystals Suspended in Liquid

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of

    7. Electronic Structure of Cobalt Nanocrystals Suspended in Liquid

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of

    8. Electronic Structure of Cobalt Nanocrystals Suspended in Liquid

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of

    9. Tonopah Test Range EGS graphics tracking display system: HP370

      SciTech Connect (OSTI)

      Meyer, R.H.; Bauhs, K.C.

      1994-08-01

      This report describes the HP370 component of the Enhanced Graphics System (EGS) used at Tonopah Test Range (TTR). Selected Radar data is fed into the computer systems and the resulting tracking symbols are displayed on high-resolution video monitors in real time. These tracking symbols overlay background maps and are used for monitoring/controlling various flight vehicles. This report discusses both the operational aspects and the internal configuration of the HP370 Workstation portion of the EGS system.

    10. SLAC Large Detector (SLD) Image and Event Display Collections

      DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

      Perl, Joseph; Cowan, Ray; Johnson, Tony

      The SLD makes use of the unique capabilities of the Stanford Linear Collider (SLC) to perform studies of polarized Z particles produced in collisions between electrons and positrons. The SLD Event Display Collection shows computer generated pictures of a number of Z particle decays as reconstructed by the SLD detector. More than 90 images, each in several formats, captured from 1991 - 1996 events, are archived here. There are also figures and data plots available.

    11. Los Alamos Quantum Dots for Solar, Display Technology

      SciTech Connect (OSTI)

      Klimov, Victor

      2015-04-13

      Quantum dots are ultra-small bits of semiconductor matter that can be synthesized with nearly atomic precision via modern methods of colloidal chemistry. Their emission color can be tuned by simply varying their dimensions. Color tunability is combined with high emission efficiencies approaching 100 percent. These properties have recently become the basis of a new technology – quantum dot displays – employed, for example, in the newest generation of e-readers and video monitors.

    12. Aerogels: A new material for emissive display applications

      SciTech Connect (OSTI)

      Glauser, S.A.C. [California Univ., Davis, CA (United States); Lee, H.W.H. [Lawrence Livermore National Lab., CA (United States)

      1997-03-01

      The remarkable optical and electronic properties of doped and undoped silica aerogels establish their utility as unique, multifunctional host materials for fluorescent dyes and other luminescent materials for display and imaging applications. We present results on the photoluminescence and absorption of undoped silica aerogels and aerogels doped with Er{sup 3+}, rhodamine 6G (R6G), and fluorescein. We also demonstrate evidence of Fowler-Nordheim tunneling of electrons in aerogels. 4 refs., 10 figs.

    13. Liquid crystalline composites containing phyllosilicates

      DOE Patents [OSTI]

      Chaiko, David J.

      2004-07-13

      The present invention provides phyllosilicate-polymer compositions which are useful as liquid crystalline composites. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while at the same time be transparent. Because of the ordering of the particles liquid crystalline composite, liquid crystalline composites are particularly useful as barriers to gas transport.

    14. Effect of medium range order on pulsed laser crystallization of amorphous germanium thin films

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Li, T. T.; Bayu Aji, L. B.; Heo, T. W.; Santala, M. K.; Kucheyev, S. O.; Campbell, G. H.

      2016-06-03

      Sputter deposited amorphous Ge thin films had their nanostructure altered by irradiation with high-energy Ar+ ions. The change in the structure resulted in a reduction in medium range order (MRO) characterized using fluctuation electron microscopy. The pulsed laser crystallization kinetics of the as-deposited versus irradiated materials were investigated using the dynamic transmission electron microscope operated in the multi-frame movie mode. In conclusion, the propagation rate of the crystallization front for the irradiated material was lower; the changes were correlated to the MRO difference and formation of a thin liquid layer during crystallization.

    15. Batch crystallization of rhodopsin for structural dynamics using an X-ray free-electron laser

      SciTech Connect (OSTI)

      Wu, Wenting; Nogly, Przemyslaw; Rheinberger, Jan; Kick, Leonhard M.; Gati, Cornelius; Nelson, Garrett; Deupi, Xavier; Standfuss, Jrg; Schertler, Gebhard; Panneels, Valrie

      2015-06-27

      A new batch preparation method is presented for high-density micrometre-sized crystals of the G protein-coupled receptor rhodopsin for use in time-resolved serial femtosecond crystallography at an X-ray free-electron laser using a liquid jet. Rhodopsin is a membrane protein from the G protein-coupled receptor family. Together with its ligand retinal, it forms the visual pigment responsible for night vision. In order to perform ultrafast dynamics studies, a time-resolved serial femtosecond crystallography method is required owing to the nonreversible activation of rhodopsin. In such an approach, microcrystals in suspension are delivered into the X-ray pulses of an X-ray free-electron laser (XFEL) after a precise photoactivation delay. Here, a millilitre batch production of high-density microcrystals was developed by four methodical conversion steps starting from known vapour-diffusion crystallization protocols: (i) screening the low-salt crystallization conditions preferred for serial crystallography by vapour diffusion, (ii) optimization of batch crystallization, (iii) testing the crystal size and quality using second-harmonic generation (SHG) imaging and X-ray powder diffraction and (iv) production of millilitres of rhodopsin crystal suspension in batches for serial crystallography tests; these crystals diffracted at an XFEL at the Linac Coherent Light Source using a liquid-jet setup.

    16. In vacuo X-ray data collection from graphene-wrapped protein crystals

      SciTech Connect (OSTI)

      Warren, Anna J.; Crawshaw, Adam D.; Trincao, Jose; Aller, Pierre; Alcock, Simon; Nistea, Ioana; Salgado, Paula S.; Evans, Gwyndaf

      2015-09-26

      A method is reported for collecting room-temperature data from protein crystals under vacuum by protecting them with a thin graphene layer. The measurement of diffraction data from macromolecular crystal samples held in vacuo holds the promise of a very low X-ray background and zero absorption of incident and scattered beams, leading to better data and the potential for accessing very long X-ray wavelengths (>3 ) for native sulfur phasing. Maintaining the hydration of protein crystals under vacuum is achieved by the use of liquid jets, as with serial data collection at free-electron lasers, or is side-stepped by cryocooling the samples, as implemented at new synchrotron beamlines. Graphene has been shown to protect crystals from dehydration by creating an extremely thin layer that is impermeable to any exchanges with the environment. Furthermore, owing to its hydrophobicity, most of the aqueous solution surrounding the crystal is excluded during sample preparation, thus eliminating most of the background caused by liquid. Here, it is shown that high-quality data can be recorded at room temperature from graphene-wrapped protein crystals in a rough vacuum. Furthermore, it was observed that graphene protects crystals exposed to different relative humidities and a chemically harsh environment.

    17. Properties of salt-grown uranium single crystals.

      SciTech Connect (OSTI)

      Cooley, J. C.; Hanrahan, R. J.; Hults, W. L.; Lashley, J. C.; Manley, M. E.; Mielke, C. H.; Smith, J. L.; Thoma, D. J.; Clark, R. G.; Hamilton, A. R.; O'Brien, J. L.; Gay, E. C.; Lumpkin, N. E.; McPheeters, C. C.; Willit, J.; Schmiedeshoff, G. M.; Touton, S.; Woodfield, B. F.; Lang, B. E.; Boerio-Goates, Juliana

      2001-01-01

      Recently single crystals of {alpha}-uranium were grown from a liquid salt bath. The electrical, magnetic and thermal properties of these crystals have been surveyed. The ratio of the room temperature resistivity of these crystals to the saturation value at low temperature is three times larger than any previously reported demonstrating that the crystals are of higher purity and quality than those in past work. The resistive signatures of the CDW transitions at 43, 37 and 22 K are obvious to the naked eye. The transition at 22 K exhibits temperature hysteresis that increases with magnetic field. In addition the superconducting transition temperature from resistivity is 820 mK and the critical field is 80 mT. Contrary to earlier work where the Debye temperature ranged from 186 to 218 K, the Debye temperature extracted from the heat capacity is 254 K in good agreement with the predicted value of 250 K. Magnetoresistance, Hall effect and magnetic susceptibility measurements are underway. In time, measurements made on these crystals may help us to understand the origin of superconductivity and its relation to the CDW transitions in pure uranium.

    18. Growth and properties of Lithium Salicylate single crystals

      SciTech Connect (OSTI)

      Zaitseva, N; Newby, J; Hull, G; Saw, C; Carman, L; Cherepy, N; Payne, S

      2009-02-13

      An attractive feature of {sup 6}Li containing fluorescence materials that determines their potential application in radiation detection is the capture reaction with slow ({approx}< 100 keV) neutrons: {sup 6}Li + n = {sup 4}He + {sup 3}H + 4.8MeV. The use of {sup 6}Li-salicylate (LiSal, LiC{sub 6}H{sub 5}O{sub 3}) for thermal neutron detection was previously studied in liquid and polycrystalline scintillators. The studies showed that both liquid and polycrystalline LiSal scintillators could be utilized in pulse shape discrimination (PSD) techniques that enable separation of neutrons from the background gamma radiation. However, it was found that the efficiency of neutron detection using LiSal in liquid solutions was severely limited by its low solubility in commonly used organic solvents like, for example, toluene or xylene. Better results were obtained with neutron detectors containing the compound in its crystalline form, such as pressed pellets, or microscopic-scale (7-14 micron) crystals dispersed in various media. The expectation drown from these studies was that further improvement of pulse height, PSD, and efficiency characteristics could be reached with larger and more transparent LiSal crystals, growth of which has not been reported so far. In this paper, we present the first results on growth and characterization of relatively large, a cm-scale size, single crystals of LiSal with good optical quality. The crystals were grown both from aqueous and anhydrous (methanol) media, mainly for neutron detection studies. However, the results on growth and structural characterization may be interesting for other fields where LiSal, together with other alkali metal salicylates, is used for biological, medical, and chemical (as catalyst) applications.

    19. Real-time graphic display utility for nuclear safety applications

      SciTech Connect (OSTI)

      Yang, S.; Huang, X.; Taylor, J.; Stevens, J.; Gerardis, T.; Hsu, A.; McCreary, T.

      2006-07-01

      With the increasing interests in the nuclear energy, new nuclear power plants will be constructed and licensed, and older generation ones will be upgraded for assuring continuing operation. The tendency of adopting the latest proven technology and the fact of older parts becoming obsolete have made the upgrades imperative. One of the areas for upgrades is the older CRT display being replaced by the latest graphics displays running under modern real time operating system (RTOS) with safety graded modern computer. HFC has developed a graphic display utility (GDU) under the QNX RTOS. A standard off-the-shelf software with a long history of performance in industrial applications, QNX RTOS used for safety applications has been examined via a commercial dedication process that is consistent with the regulatory guidelines. Through a commercial survey, a design life cycle and an operating history evaluation, and necessary tests dictated by the dedication plan, it is reasonably confirmed that the QNX RTOS was essentially equivalent to what would be expected in the nuclear industry. The developed GDU operates and communicates with the existing equipment through a dedicated serial channel of a flat panel controller (FPC) module. The FPC module drives a flat panel display (FPD) monitor. A touch screen mounted on the FPD serves as the normal operator interface with the FPC/FPD monitor system. The GDU can be used not only for replacing older CRTs but also in new applications. The replacement of the older CRT does not disturb the function of the existing equipment. It not only provides modern proven technology upgrade but also improves human ergonomics. The FPC, which can be used as a standalone controller running with the GDU, is an integrated hardware and software module. It operates as a single board computer within a control system, and applies primarily to the graphics display, targeting, keyboard and mouse. During normal system operation, the GDU has two sources of data

    20. Characterization of Epitaxial Film Silicon Solar Cells Grown on Seeded Display Glass: Preprint

      SciTech Connect (OSTI)

      Young, D. L.; Grover, S.; Teplin, C.; Stradins, P.; LaSalvia, V.; Chuang, T. K.; Couillard, J. G.; Branz, H. M.

      2012-06-01

      We report characterizations of epitaxial film crystal silicon (c-Si) solar cells with open-circuit voltages (Voc) above 560 mV. The 2-um absorber cells are grown by low-temperature (<750 degrees C) hot-wire CVD (HWCVD) on Corning EAGLE XG display glass coated with a layer-transferred (LT) Si seed. The high Voc is a result of low-defect epitaxial Si (epi-Si) growth and effective hydrogen passivation of defects. The quality of HWCVD epitaxial growth on seeded glass substrates depends on the crystallographic quality of the seed and the morphology of the epitaxial growth surface. Heterojunction devices consist of glass/c-Si LT seed/ epi n+ Si:P/epi n- Si:P/intrinsic a-Si:H/p+ a-Si:H/ITO. Similar devices grown on electronically 'dead' n+ wafers have given Voc {approx}630 mV and {approx}8% efficiency with no light trapping features. Here we study the effects of the seed surface polish on epi-Si quality, how hydrogenation influences the device character, and the dominant junction transport physics.

    1. Liquid metal pump

      DOE Patents [OSTI]

      Pennell, William E.

      1982-01-01

      The liquid metal pump comprises floating seal rings and attachment of the pump diffuser to the pump bowl for isolating structural deflections from the pump shaft bearings. The seal rings also eliminate precision machining on large assemblies by eliminating the need for a close tolerance fit between the mounting surfaces of the pump and the seals. The liquid metal pump also comprises a shaft support structure that is isolated from the pump housing for better preservation of alignment of shaft bearings. The shaft support structure also allows for complete removal of pump internals for inspection and repair.

    2. Diffractive optics for compact flat panel displays. Final report

      SciTech Connect (OSTI)

      Sweeney, D.; DeLong, K.

      1997-04-29

      Three years ago LLNL developed a practical method to dramatically reduce the chromatic aberration in single element diffractive imaging lenses. High efficiency, achromatic imaging lenses have been fabricated for human vision correction. This LDRD supported research in applying our new methods to develop a unique, diffraction-based optical interface with solid state, microelectronic imaging devices. Advances in microelectronics have led to smaller, more efficient components for optical systems. There have, however, been no equivalent advances in the imaging optics associated with these devices. The goal of this project was to replace the bulky, refractive optics in typical head-mounted displays with micro-thin diffractive optics to directly image flat-panel displays into the eye. To visualize the system think of the lenses of someone`s eyeglasses becoming flat-panel displays. To realize this embodiment, we needed to solve the problems of large chromatic aberrations and low efficiency that are associated with diffraction. We have developed a graceful tradeoff between chromatic aberrations and the diffractive optic thickness. It turns out that by doubling the thickness of a micro-thin diffractive lens we obtain nearly a two-times improvement in chromatic performance. Since the human eye will tolerate one diopter of chromatic aberration, we are able to achieve an achromatic image with a diffractive lens that is only 20 microns thick, versus 3 mm thickness for the comparable refractive lens. Molds for the diffractive lenses are diamond turned with sub-micron accuracy; the final lenses are cast from these molds using various polymers. We thus retain both the micro- thin nature of the diffractive optics and the achromatic image quality of refractive optics. During the first year of funding we successfully extended our earlier technology from 1 cm diameter optics required for vision applications up to the 5 cm diameter optics required for this application. 3 refs., 6 figs.

    3. Systems and methods for displaying data in split dimension levels

      DOE Patents [OSTI]

      Stolte, Chris; Hanrahan, Patrick

      2015-07-28

      Systems and methods for displaying data in split dimension levels are disclosed. In some implementations, a method includes: at a computer, obtaining a dimensional hierarchy associated with a dataset, wherein the dimensional hierarchy includes at least one dimension and a sub-dimension of the at least one dimension; and populating information representing data included in the dataset into a visual table having a first axis and a second axis, wherein the first axis corresponds to the at least one dimension and the second axis corresponds to the sub-dimension of the at least one dimension.

    4. Heating-induced glass-glass and glass-liquid transformations in computer simulations of water

      SciTech Connect (OSTI)

      Chiu, Janet; Giovambattista, Nicolas; Starr, Francis W.

      2014-03-21

      Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related

    5. Method for simultaneous measurement of mass loading and fluid property changes using a quartz crystal microbalance

      DOE Patents [OSTI]

      Granstaff, V.E.; Martin, S.J.

      1993-04-13

      A method is described, using a quartz crystal microbalance, to obtain simultaneous measurement of solid mass accumulation and changes in liquid density-viscosity product. The simultaneous real-time measurements of electrical parameters yields that changes in surface mass can be differentiated from changes in solution properties. Two methods to obtain the admittance/frequency data are employed.

    6. Method for simultaneous measurement of mass loading and fluid property changes using a quartz crystal microbalance

      DOE Patents [OSTI]

      Granstaff, Victoria E.; Martin, Stephen J.

      1993-01-01

      A method, using a quartz crystal microbalance, to obtain simultaneous measurement of solid mass accumulation and changes in liquid density-viscosity product. The simultaneous real-time measurements of electrical parameters yields that changes in surface mass can be differentiated from changes in solution properties. Two methods to obtain the admittance/frequency data are employed.

    7. Durable Electrooptic Devices Comprising Ionic Liquids

      DOE Patents [OSTI]

      Burrell, Anthony K.; Agrawal, Anoop; Cronin, John P.; Tonazzi, Juan C. L.; Warner, Benjamin P.; McCleskey, T. Mark

      2008-11-11

      Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes. Some of the electrolyte solutions color to red when devices employing the solutions are powered, leading to red or neutral electrooptic devices.

    8. Durable electrooptic devices comprising ionic liquids

      DOE Patents [OSTI]

      Burrell, Anthony K.; Agrawal, Anoop; Cronin; John P.; Tonazzi, Juan C. L.; Warner, Benjamin P.; McCleskey, T. Mark

      2009-12-15

      Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes. Some of the electrolyte solutions color to red when devices employing the solutions are powered, leading to red or neutral electrooptic devices.

    9. Durable electrooptic devices comprising ionic liquids

      DOE Patents [OSTI]

      Warner, Benjamin P.; McCleskey, T. Mark; Burrell, Anthony K.

      2006-10-10

      Electrolyte solutions for electrochromic devices such as rear view mirrors and displays with low leakage currents are prepared using inexpensive, low conductivity conductors. Preferred electrolytes include bifunctional redox dyes and molten salt solvents with enhanced stability toward ultraviolet radiation. The solvents include lithium or quaternary ammonium cations, and perfluorinated sulfonylimide anions selected from trifluoromethylsulfonate (CF.sub.3SO.sub.3.sup.-), bis(trifluoromethylsulfonyl)imide ((CF.sub.3SO.sub.2).sub.2N.sup.-), bis(perfluoroethylsulfonyl)imide ((CF.sub.3CF.sub.2SO.sub.2).sub.2N.sup.-) and tris(trifluoromethylsulfonyl)methide ((CF.sub.3SO.sub.2).sub.3C.sup.-). Electroluminescent, electrochromic and photoelectrochromic devices with nanostructured electrodes include ionic liquids with bifunctional redox dyes.

    10. Crystal face temperature determination means

      DOE Patents [OSTI]

      Nason, D.O.; Burger, A.

      1994-11-22

      An optically transparent furnace having a detection apparatus with a pedestal enclosed in an evacuated ampule for growing a crystal thereon is disclosed. Temperature differential is provided by a source heater, a base heater and a cold finger such that material migrates from a polycrystalline source material to grow the crystal. A quartz halogen lamp projects a collimated beam onto the crystal and a reflected beam is analyzed by a double monochromator and photomultiplier detection spectrometer and the detected peak position in the reflected energy spectrum of the reflected beam is interpreted to determine surface temperature of the crystal. 3 figs.

    11. Flowmeter for determining average rate of flow of liquid in a conduit

      DOE Patents [OSTI]

      Kennerly, J.M.; Lindner, G.M.; Rowe, J.C.

      1981-04-30

      This invention is a compact, precise, and relatively simple device for use in determining the average rate of flow of a liquid through a conduit. The liquid may be turbulent and contain bubbles of gas. In a preferred embodiment, the flowmeter includes an electrical circuit and a flow vessel which is connected as a segment of the conduit conveying the liquid. The vessel is provided with a valved outlet and is partitioned by a vertical baffle into coaxial chambers whose upper regions are vented to permit the escape of gas. The inner chamber receives turbulent downflowing liquid from the conduit and is sized to operate at a lower pressure than the conduit, thus promoting evolution of gas from the liquid. Lower zones of the two chambers are interconnected so that the downflowing liquid establishes liquid levels in both chambers. The liquid level in the outer chamber is comparatively calm, being to a large extent isolated from the turbulence in the inner chamber once the liquid in the outer chamber has risen above the liquid-introduction zone for that chamber. Lower and upper probes are provided in the outer chamber for sensing the liquid level therein at points above its liquid-introduction zone. An electrical circuit is connected to the probes to display the time required for the liquid level in the outer chamber to successively contact the lower and upper probes. The average rate of flow through the conduit can be determined from the above-mentioned time and the vessel volume filled by the liquid during that time.

    12. Flowmeter for determining average rate of flow of liquid in a conduit

      DOE Patents [OSTI]

      Kennerly, John M. (Knoxville, TN); Lindner, Gordon M. (Oak Ridge, TN); Rowe, John C. (Oak Ridge, TN)

      1982-01-01

      This invention is a compact, precise, and relatively simple device for use in determining the average rate of flow of a liquid through a conduit. The liquid may be turbulent and contain bubbles of gas. In a preferred embodiment, the flowmeter includes an electrical circuit and a flow vessel which is connected as a segment of the conduit conveying the liquid. The vessel is provided with a valved outlet and is partitioned by a vertical baffle into coaxial chambers whose upper regions are vented to permit the escape of gas. The inner chamber receives turbulent downflowing liquid from the conduit and is sized to operate at a lower pressure than the conduit, thus promoting evolution of gas from the liquid. Lower zones of the two chambers are interconnected so that the downflowing liquid establishes liquid levels in both chambers. The liquid level in the outer chamber is comparatively calm, being to a large extent isolated from the turbulence in the inner chamber once the liquid in the outer chamber has risen above the liquid-introduction zone for that chamber. Lower and upper probes are provided in the outer chamber for sensing the liquid level therein at points above its liquid-introduction zone. An electrical circuit is connected to the probes to display the time required for the liquid level in the outer chamber to successively contact the lower and upper probes. The average rate of flow through the conduit can be determined from the above-mentioned time and the vessel volume filled by the liquid during that time.

    13. Vibrational spectroscopy of liquid mixtures and solid/liquid | Argonne

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Leadership Computing Facility spectroscopy of liquid mixtures and solid/liquid PI Name: Giulia Galli PI Email: gagalli@ucdavis.edu Institution: University of California, Davis Allocation Program: INCITE Allocation Hours at ALCF: 15,000,000 Year: 2011 Research Domain: Materials Science We propose to use first principle molecular dynamics (MD) simulations using semi-local and hybrid functionals to compute vibrational properties of liquid mixtures and liquid/solid interfaces, with the goal of

    14. Liquid metal thermoacoustic engine

      SciTech Connect (OSTI)

      Swift, G.W.; Migliori, A.; Wheatley, J.C.

      1986-01-01

      We are studying a liquid metal thermoacoustic engine both theoretically and experimentally. This type of engine promises to produce large quantities of electrical energy from heat at modest efficiency with no moving parts. A sound wave is usually thought of as consisting of pressure oscillations, but always attendant to the pressure oscillation are temperature oscillations. The combination produces a rich variety of ''thermoacoustic'' effects. These effects are usually so small that they are never noticed in everyday life; nevertheless under the right circumstances they can be harnessed to produce powerful heat engines, heat pumps, and refrigerators. In our liquid metal thermoacoustic engine, heat flow from a high temperature source to a low temperature sink generates a high-amplitude standing acoustic wave in liquid sodium. This acoustic power is converted to electric power by a simple magnetohydrodynamic effect at the acoustic oscillation frequency. We have developed a detailed thermoacoustic theory applicable to this engine, and find that a reasonably designed liquid sodium engine operating between 700/sup 0/C and 100/sup 0/C should generate about 60 W/cm/sup 2/ of acoustic power at about 1/3 of Carnot's efficiency. Construction of a 3000 W-thermal laboratory model engine has just been completed, and we have exciting preliminary experimental results as of the time of preparation of this manuscript showing, basically, that the engine works. We have also designed and built a 1 kHz liquid sodium magnetohydrodynamic generator and have extensive measurements on it. It is now very well characterized both experimentally and theoretically. The first generator of its kind, it already converts acoustic power to electric power with 40% efficiency. 16 refs., 5 figs.

    15. Optics of globular photonic crystals

      SciTech Connect (OSTI)

      Gorelik, V S

      2007-05-31

      The results of experimental and theoretical studies of the optical properties of globular photonic crystals - new physical objects having a crystal structure with the lattice period exceeding considerably the atomic size, are presented. As globular photonic crystals, artificial opal matrices consisting of close-packed silica globules of diameter {approx}200 nm were used. The reflection spectra of these objects characterising the parameters of photonic bands existing in these crystals in the visible spectral region are presented. The idealised models of the energy band structure of photonic crystals investigated in the review give analytic dispersion dependences for the group velocity and the effective photon mass in a globular photonic crystal. The characteristics of secondary emission excited in globular photonic crystals by monochromatic and broadband radiation are presented. The results of investigations of single-photon-excited delayed scattering of light observed in globular photonic crystals exposed to cw UV radiation and radiation from a repetitively pulsed copper vapour laser are presented. The possibilities of using globular photonic crystals as active media for lasing in different spectral regions are considered. It is proposed to use globular photonic crystals as sensitive sensors in optoelectronic devices for molecular analysis of organic and inorganic materials by the modern methods of laser spectroscopy. The results of experimental studies of spontaneous and stimulated globular scattering of light are discussed. The conditions for observing resonance and two-photon-excited delayed scattering of light are found. The possibility of accumulation and localisation of the laser radiation energy inside a globular photonic crystal is reported. (review)

    16. Entropic description of gas hydrate ice/liquid equilibrium via enhanced sampling of coexisting phases

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Malolepsza, Edyta; Kim, Jaegil; Keyes, Tom

      2015-04-28

      Metastable β ice holds small guest molecules in stable gas hydrates, so its solid/liquid equilibrium is of interest. However, aqueous crystal/liquid transitions are very difficult to simulate. A new MD algorithm generates trajectories in a generalized NPT ensemble and equilibrates states of coexisting phases with a selectable enthalpy. Furthermore, with replicas spanning the range between β ice and liquid water we find the statistical temperature from the enthalpy histograms and characterize the transition by the entropy, introducing a general computational procedure for first-order transitions.

    17. Air Liquide- Biogas & Fuel Cells

      Broader source: Energy.gov [DOE]

      Presentation about Air Liquide's biogas technologies and integration with fuel cells. Presented by Charlie Anderson, Air Liquide, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

    18. Imaging Liquids Using Microfluidic Cells

      SciTech Connect (OSTI)

      Yu, Xiao-Ying; Liu, Bingwen; Yang, Li

      2013-05-10

      Chemistry occurring in the liquid and liquid surface is important in many applications. Chemical imaging of liquids using vacuum based analytical techniques is challenging due to the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface sensitive techniques such as electron microscopy and spectroscopy. Due to its small size, low cost, and flexibility in design, liquid cells based on microfluidics have been increasingly used in studying and imaging complex phenomena involving liquids. This paper presents a review of microfluidic cells that were developed to adapt to electron microscopes and various spectrometers for in situ chemical analysis and imaging of liquids. The following topics will be covered including cell designs, fabrication techniques, unique technical features for vacuum compatible cells, and imaging with electron microscopy and spectroscopy. Challenges are summarized and recommendations for future development priority are proposed.

    19. Liquid metal thermal electric converter

      DOE Patents [OSTI]

      Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

      1989-01-01

      A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

    20. Liquid crystalline composites containing phyllosilicates

      DOE Patents [OSTI]

      Chaiko; David J.

      2007-05-08

      The present invention provides barrier films having reduced gas permeability for use in packaging and coating applications. The barrier films comprise an anisotropic liquid crystalline composite layer formed from phyllosilicate-polymer compositions. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while remaining transparent. Because of the ordering of the particles in the liquid crystalline composite, barrier films comprising liquid crystalline composites are particularly useful as barriers to gas transport.

    1. Lamella settler crystallizer

      DOE Patents [OSTI]

      Maimoni, A.

      1990-12-18

      A crystallizer is described which incorporates a lamella settler and which is particularly applicable for use in batteries and power cells for electric vehicles or stationary applications. The lamella settler can be utilized for coarse particle separation or for agglomeration, and is particularly applicable to aluminum-air batteries or power cells for solving the hydrargillite (aluminum-hydroxide) removal problems from such batteries. This invention provides the advantages of very low energy consumption, turbulence, shear, cost and maintenance. Thus, due to the low shear and low turbulence of this invention, it is particularly effective in the control of aluminum hydroxide particle size distribution in the various sections of an aluminum-air system, as well as in other electrochemical systems requiring separation for phases of different densities. 3 figs.

    2. Lamella settler crystallizer

      DOE Patents [OSTI]

      Maimoni, Arturo

      1990-01-01

      A crystallizer which incorporates a lamella settler and which is particularly applicable for use in batteries and power cells for electric vehicles or stationary applications. The lamella settler can be utilized for coarse particle separation or for agglomeration, and is particularly applicable to aluminum-air batteries or power cells for solving the hydrargillite (aluminum-hydroxide) removal problems from such batteries. This invention provides the advantages of very low energy consumption, turbulence, shear, cost and maintenance. Thus, due to the low shear and low turbulence of this invention, it is particularly effective in the control of aluminum hydroxide particle size distribution in the various sections of an aluminum-air system, as well as in other electrochemical systems requiring separation for phases of different densities.

    3. Frequency mixing crystal

      DOE Patents [OSTI]

      Ebbers, Christopher A.; Davis, Laura E.; Webb, Mark

      1992-01-01

      In a laser system for converting infrared laser light waves to visible light comprising a source of infrared laser light waves and means of harmoic generation associated therewith for production of light waves at integral multiples of the frequency of the original wave, the improvement of said means of harmonic generation comprising a crystal having the chemical formula X.sub.2 Y(NO.sub.3).sub.5 .multidot.2 nZ.sub.2 o wherein X is selected from the group consisting of Li, Na, K, Rb, Cs, and Tl; Y is selected from the group consisting of Sc, Y, La, Ce, Nd, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Al, Ga, and In; Z is selected from the group consisting of H and D; and n ranges from 0 to 4.

    4. Demonstration of single crystal growth via solid-solid transformation of a glass

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Savytskii, Dmytro; Knorr, Brian; Dierolf, Volkmar; Jain, Himanshu

      2016-03-18

      Many advanced technologies have relied on the availability of single crystals of appropriate material such as silicon for microelectronics or superalloys for turbine blades. Similarly, many promising materials could unleash their full potential if they were available in a single crystal form. However, the current methods are unsuitable for growing single crystals of these oftentimes incongruently melting, unstable or metastable materials. Here we demonstrate a strategy to overcome this hurdle by avoiding the gaseous or liquid phase, and directly converting glass into a single crystal. Specifically, Sb2S3 single crystals are grown in Sb-S-I glasses as an example of this approach.more » In this first unambiguous demonstration of an all-solid-state glass → crystal transformation, extraneous nucleation is avoided relative to crystal growth via spatially localized laser heating and inclusion of a suitable glass former in the composition. Lastly, the ability to fabricate patterned single-crystal architecture on a glass surface is demonstrated, providing a new class of micro-structured substrate for low cost epitaxial growth, active planar devices, etc.« less

    5. High temperature liquid level sensor

      DOE Patents [OSTI]

      Tokarz, Richard D. (West Richland, WA)

      1983-01-01

      A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

    6. Azobenzene-based organic salts with ionic liquid and liquid crystalline properties

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Stappert, Kathrin; Muthmann, Johanna; Spielberg, Eike T.; Mudring, Anja -Verena

      2015-07-23

      Two sets of new azobenzene-based bromide salts are synthesized, and their thermal photochromic properties are studied. Both sets are based on the imidazolium cation. The first set (1) features a symmetric biscation where two imidazolium head groups (Im) with different alkyl chains (Cn) are connected to a central azobenzene unit (Azo): [Azo(C1-Im-Cn)2]; n = 6, 8, 10, 12, 14. The other one contains an n-alkyl-imidazolium cation (Cn-Im) bearing a terminal azobenzene unit (C1-Azo) substituted with an alkoxy chain (O-Cm) of either two (2) or six (3) carbon atoms: [C1-Azo-O-Cm-Im-Cn]; m = 2, n = 8, 10, 12 and m =more » 6, n = 8, 10, 12, 14, 16. For both cation classes, the influence of alkyl chains of varying length on the thermal phase behavior was investigated by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). For five compounds (Azo(-C1-Im-C12)2 (1d), Azo(-C1-Im-C12)2 (1e), C1-Azo-O-C2-Im-C10 (2b), C1-Azo-O-C2-Im-C12 (2c), and C1-Azo-O-C6-Im-C16 (3e)), the formation of a liquid crystalline phase was observed. The biscationic salts (1) are all comparatively high melting organic salts (180–240 °C), and only the two representatives with long alkylchains (C12 and C14) exhibit liquid crystallinity. The monocationic salts with an O–C2 bridge (2) melt between 140 and 170 °C depending on the alkyl chain length, but from an alkyl chain of 10 and more carbon atoms on they form a smectic A liquid crystalline phase. The representatives of the third set with a O–C6 bridge qualify as ionic liquids with melting points less than 100 °C. However, only the representative with a hexadecyl chain forms a liquid crystalline phase. Representative single crystals for all sets of cations could be grown that allowed for single crystal structure analysis. Together with small-angle X-ray scattering experiments they allow for a more detailed understanding of the thermal properties. As a result, through irradiation with UV-light (320–366 nm) all

    7. Azobenzene-based organic salts with ionic liquid and liquid crystalline properties

      SciTech Connect (OSTI)

      Stappert, Kathrin; Muthmann, Johanna; Spielberg, Eike T.; Mudring, Anja -Verena

      2015-07-23

      Two sets of new azobenzene-based bromide salts are synthesized, and their thermal photochromic properties are studied. Both sets are based on the imidazolium cation. The first set (1) features a symmetric biscation where two imidazolium head groups (Im) with different alkyl chains (Cn) are connected to a central azobenzene unit (Azo): [Azo(C1-Im-Cn)2]; n = 6, 8, 10, 12, 14. The other one contains an n-alkyl-imidazolium cation (Cn-Im) bearing a terminal azobenzene unit (C1-Azo) substituted with an alkoxy chain (O-Cm) of either two (2) or six (3) carbon atoms: [C1-Azo-O-Cm-Im-Cn]; m = 2, n = 8, 10, 12 and m = 6, n = 8, 10, 12, 14, 16. For both cation classes, the influence of alkyl chains of varying length on the thermal phase behavior was investigated by differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). For five compounds (Azo(-C1-Im-C12)2 (1d), Azo(-C1-Im-C12)2 (1e), C1-Azo-O-C2-Im-C10 (2b), C1-Azo-O-C2-Im-C12 (2c), and C1-Azo-O-C6-Im-C16 (3e)), the formation of a liquid crystalline phase was observed. The biscationic salts (1) are all comparatively high melting organic salts (180–240 °C), and only the two representatives with long alkylchains (C12 and C14) exhibit liquid crystallinity. The monocationic salts with an O–C2 bridge (2) melt between 140 and 170 °C depending on the alkyl chain length, but from an alkyl chain of 10 and more carbon atoms on they form a smectic A liquid crystalline phase. The representatives of the third set with a O–C6 bridge qualify as ionic liquids with melting points less than 100 °C. However, only the representative with a hexadecyl chain forms a liquid crystalline phase. Representative single crystals for all sets of cations could be grown that allowed for single crystal structure analysis. Together with small-angle X-ray scattering experiments they allow for a more detailed understanding of the thermal properties. As a result, through irradiation with UV

    8. Fabrics coated with lubricated nanostructures display robust omniphobicity

      SciTech Connect (OSTI)

      Shillingford, Cicely; MacCallum, Noah; Wong, Tak -Sing; Kim, Philseok; Aizenberg, Joanna

      2013-12-11

      The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e.g., rain), and when exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. However we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.

    9. Fabrics coated with lubricated nanostructures display robust omniphobicity

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Shillingford, Cicely; MacCallum, Noah; Wong, Tak -Sing; Kim, Philseok; Aizenberg, Joanna

      2013-12-11

      The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e.g., rain), and whenmore » exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. However we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.« less

    10. Fabrics coated with lubricated nanostructures display robust omniphobicity

      SciTech Connect (OSTI)

      Shillingford, C; MacCallum, N; Wong, TS; Kim, P; Aizenberg, J

      2013-12-11

      The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e. g., rain), and when exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. Herein we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.

    11. Improving the diversity of manufacturing electroluminescent flat panel displays

      SciTech Connect (OSTI)

      Moss, T.S.; Samuels, J.A.; Smith, D.C.

      1995-09-01

      Crystalline calcium thiogallate with a cerium dopant has been deposited by metal-organic chemical vapor deposition (MOCVD) at temperatures below 600{degrees}C on a low cost glass substrate. An EL luminance of 1.05 fL was observed 40 volts above threshold at 60 Hz. This is more than an order of magnitude improvement over earlier crystalline-as-deposited thiogallate materials. These results pave the way for the use of MOCVD as a potential method for processing full color thin-film electroluminescent (TFEL) flat panel displays. The formation of the CaGa{sub 2}S{sub 4}:Ce phosphor requires precise control over a number of deposition parameters including flow rates, substrate temperature, and reactor pressure. The influence of these parameters will be discussed in terms of structure, uniformity, and TFEL device performance.

    12. Plasmids and packaging cell lines for use in phage display

      DOE Patents [OSTI]

      Bradbury, Andrew M.

      2012-07-24

      The invention relates to a novel phagemid display system for packaging phagemid DNA into phagemid particles which completely avoids the use of helper phage. The system of the invention incorporates the use of bacterial packaging cell lines which have been transformed with helper plasmids containing all required phage proteins but not the packaging signals. The absence of packaging signals in these helper plasmids prevents their DNA from being packaged in the bacterial cell, which provides a number of significant advantages over the use of both standard and modified helper phage. Packaged phagemids expressing a protein or peptide of interest, in fusion with a phage coat protein such as g3p, are generated simply by transfecting phagemid into the packaging cell line.

    13. Cyclic olefin homopolymer-based microfluidics for protein crystallization and in situ X-ray diffraction

      SciTech Connect (OSTI)

      Emamzadah, Soheila [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Petty, Tom J. [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Biomedical Graduate Studies Genomics and Computational Biology Group, University of Pennsylvania, Philadelphia, PA 19104 (United States); De Almeida, Victor [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland); Nishimura, Taisuke [Department of Plant Biology, University of Geneva, CH-1205 Geneva (Switzerland); Joly, Jacques; Ferrer, Jean-Luc [Institut de Biologie Structurale J.-P. Ebel, CEA-CNRS-University J. Fourier, 38027 Grenoble CEDEX 1 (France); Halazonetis, Thanos D., E-mail: thanos.halazonetis@unige.ch [Department of Molecular Biology, University of Geneva, CH-1205 Geneva (Switzerland); Department of Biochemistry, University of Geneva, CH-1205 Geneva (Switzerland)

      2009-09-01

      A cyclic olefin homopolymer-based microfluidics system has been established for protein crystallization and in situ X-ray diffraction. Microfluidics is a promising technology for the rapid identification of protein crystallization conditions. However, most of the existing systems utilize silicone elastomers as the chip material which, despite its many benefits, is highly permeable to water vapour. This limits the time available for protein crystallization to less than a week. Here, the use of a cyclic olefin homopolymer-based microfluidics system for protein crystallization and in situ X-ray diffraction is described. Liquid handling in this system is performed in 2 mm thin transparent cards which contain 500 chambers, each with a volume of 320 nl. Microbatch, vapour-diffusion and free-interface diffusion protocols for protein crystallization were implemented and crystals were obtained of a number of proteins, including chicken lysozyme, bovine trypsin, a human p53 protein containing both the DNA-binding and oligomerization domains bound to DNA and a functionally important domain of Arabidopsis Morpheus molecule 1 (MOM1). The latter two polypeptides have not been crystallized previously. For X-ray diffraction analysis, either the cards were opened to allow mounting of the crystals on loops or the crystals were exposed to X-rays in situ. For lysozyme, an entire X-ray diffraction data set at 1.5 resolution was collected without removing the crystal from the card. Thus, cyclic olefin homopolymer-based microfluidics systems have the potential to further automate protein crystallization and structural genomics efforts.

    14. RHIC The Perfect Liquid

      ScienceCinema (OSTI)

      BNL

      2009-09-01

      Evidence to date suggests that gold-gold collisions the Relativistic Heavy Ion Collider at Brookhaven are indeed creating a new state of hot, dense matter, but one quite different and even more remarkable than had been predicted. Instead of behaving like a gas of free quarks and gluons, as was expected, the matter created in RHIC's heavy ion collisions appears to be more like a "perfect" liquid.

    15. A novel inert crystal delivery medium for serial femtosecond crystallography

      SciTech Connect (OSTI)

      Conrad, Chelsie E.; Basu, Shibom; James, Daniel; Wang, Dingjie; Schaffer, Alexander; Roy-Chowdhury, Shatabdi; Zatsepin, Nadia A.; Aquila, Andrew; Coe, Jesse; Gati, Cornelius; Hunter, Mark S.; Koglin, Jason E.; Kupitz, Christopher; Nelson, Garrett; Subramanian, Ganesh; White, Thomas A.; Zhao, Yun; Zook, James; Boutet, Sébastien; Cherezov, Vadim; Spence, John C. H.; Fromme, Raimund; Weierstall, Uwe; Fromme, Petra

      2015-06-30

      Serial femtosecond crystallography (SFX) has opened a new era in crystallography by permitting nearly damage-free, room-temperature structure determination of challenging proteins such as membrane proteins. In SFX, femtosecond X-ray free-electron laser pulses produce diffraction snapshots from nanocrystals and microcrystals delivered in a liquid jet, which leads to high protein consumption. A slow-moving stream of agarose has been developed as a new crystal delivery medium for SFX. It has low background scattering, is compatible with both soluble and membrane proteins, and can deliver the protein crystals at a wide range of temperatures down to 4°C. Using this crystal-laden agarose stream, the structure of a multi-subunit complex, phycocyanin, was solved to 2.5 Å resolution using 300 µg of microcrystals embedded into the agarose medium post-crystallization. The agarose delivery method reduces protein consumption by at least 100-fold and has the potential to be used for a diverse population of proteins, including membrane protein complexes.

    16. A novel inert crystal delivery medium for serial femtosecond crystallography

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Conrad, Chelsie E.; Basu, Shibom; James, Daniel; Wang, Dingjie; Schaffer, Alexander; Roy-Chowdhury, Shatabdi; Zatsepin, Nadia A.; Aquila, Andrew; Coe, Jesse; Gati, Cornelius; et al

      2015-06-30

      Serial femtosecond crystallography (SFX) has opened a new era in crystallography by permitting nearly damage-free, room-temperature structure determination of challenging proteins such as membrane proteins. In SFX, femtosecond X-ray free-electron laser pulses produce diffraction snapshots from nanocrystals and microcrystals delivered in a liquid jet, which leads to high protein consumption. A slow-moving stream of agarose has been developed as a new crystal delivery medium for SFX. It has low background scattering, is compatible with both soluble and membrane proteins, and can deliver the protein crystals at a wide range of temperatures down to 4°C. Using this crystal-laden agarose stream, themore » structure of a multi-subunit complex, phycocyanin, was solved to 2.5 Å resolution using 300 µg of microcrystals embedded into the agarose medium post-crystallization. The agarose delivery method reduces protein consumption by at least 100-fold and has the potential to be used for a diverse population of proteins, including membrane protein complexes.« less

    17. Mobile interfaces: Liquids as a perfect structural material for multifunctional, antifouling surfaces

      DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

      Grinthal, Alison; Aizenberg, Joanna

      2013-10-14

      Life creates some of its most robust, extreme surface materials not from solids but from liquids: a purely liquid interface, stabilized by underlying nanotexture, makes carnivorous plant leaves ultraslippery, the eye optically perfect and dirt-resistant, our knees lubricated and pressure-tolerant, and insect feet reversibly adhesive and shape-adaptive. Novel liquid surfaces based on this idea have recently been shown to display unprecedented omniphobic, self-healing, anti-ice, antifouling, optical, and adaptive properties. In this Perspective, we present a framework and a path forward for developing and designing such liquid surfaces into sophisticated, versatile multifunctional materials. Drawing on concepts from solid materials design andmore » fluid dynamics, we outline how the continuous dynamics, responsiveness, and multiscale patternability of a liquid surface layer can be harnessed to create a wide range of unique, active interfacial functions-able to operate in harsh, changing environments-not achievable with static solids. We discuss how, in partnership with the underlying substrate, the liquid surface can be programmed to adaptively and reversibly reconfigure from a defect-free, molecularly smooth, transparent interface through a range of finely tuned liquid topographies in response to environmental stimuli. In conclusion, with nearly unlimited design possibilities and unmatched interfacial properties, liquid materials-as long-term stable interfaces yet in their fully liquid state-may potentially transform surface design everywhere from medicine to architecture to energy infrastructure.« less

    18. Mobile interfaces: Liquids as a perfect structural material for multifunctional, antifouling surfaces

      SciTech Connect (OSTI)

      Grinthal, Alison; Aizenberg, Joanna

      2013-10-14

      Life creates some of its most robust, extreme surface materials not from solids but from liquids: a purely liquid interface, stabilized by underlying nanotexture, makes carnivorous plant leaves ultraslippery, the eye optically perfect and dirt-resistant, our knees lubricated and pressure-tolerant, and insect feet reversibly adhesive and shape-adaptive. Novel liquid surfaces based on this idea have recently been shown to display unprecedented omniphobic, self-healing, anti-ice, antifouling, optical, and adaptive properties. In this Perspective, we present a framework and a path forward for developing and designing such liquid surfaces into sophisticated, versatile multifunctional materials. Drawing on concepts from solid materials design and fluid dynamics, we outline how the continuous dynamics, responsiveness, and multiscale patternability of a liquid surface layer can be harnessed to create a wide range of unique, active interfacial functions-able to operate in harsh, changing environments-not achievable with static solids. We discuss how, in partnership with the underlying substrate, the liquid surface can be programmed to adaptively and reversibly reconfigure from a defect-free, molecularly smooth, transparent interface through a range of finely tuned liquid topographies in response to environmental stimuli. In conclusion, with nearly unlimited design possibilities and unmatched interfacial properties, liquid materials-as long-term stable interfaces yet in their fully liquid state-may potentially transform surface design everywhere from medicine to architecture to energy infrastructure.

    19. Liquid film target impingement scrubber

      DOE Patents [OSTI]

      McDowell, William J.; Coleman, Charles F.

      1977-03-15

      An improved liquid film impingement scrubber is provided wherein particulates suspended in a gas are removed by jetting the particle-containing gas onto a relatively small thin liquid layer impingement target surface. The impingement target is in the form of a porous material which allows a suitable contacting liquid from a pressurized chamber to exude therethrough to form a thin liquid film target surface. The gas-supported particles collected by impingement of the gas on the target are continuously removed and flushed from the system by the liquid flow through each of a number of pores in the target.

    20. NREL: MIDC/NWTC M2 Real-Time Weather Display

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      NWTC M2 Real-Time Weather Display This page should automatically refresh every minute. A text based weather display for PDAs is also available. NREL MIDC NWTC M2

    1. Kondo behavior, ferromagnetic correlations, and crystal fields...

      Office of Scientific and Technical Information (OSTI)

      and crystal fields in the heavy Fermion compounds Ce3X (XIn, Sn) Citation Details In-Document Search Title: Kondo behavior, ferromagnetic correlations, and crystal fields in ...

    2. Liquid chromatography/Fourier transform IR spectrometry interface flow cell

      DOE Patents [OSTI]

      Johnson, C.C.; Taylor, L.T.

      1985-01-04

      A zero dead volume (ZDV) microbore high performance liquid chromatography (..mu.. HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a ..mu.. HPLC column end fitting to minimize the transfer volume of the effluents exiting the ..mu.. HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF/sub 2/), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

    3. Liquid chromatography/Fourier transform IR spectrometry interface flow cell

      DOE Patents [OSTI]

      Johnson, Charles C.; Taylor, Larry T.

      1986-01-01

      A zero dead volume (ZDV) microbore high performance liquid chromatography (.mu.HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a .mu.HPLC column end fitting to minimize the transfer volume of the effluents exiting the .mu.HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF.sub.2), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

    4. Large single domain 123 material produced by seeding with single crystal rare earth barium copper oxide single crystals

      DOE Patents [OSTI]

      Todt, V.; Miller, D.J.; Shi, D.; Sengupta, S.

      1998-07-07

      A method of fabricating bulk YBa{sub 2}Cu{sub 3}O{sub x} where compressed powder oxides and/or carbonates of Y and Ba and Cu present in mole ratios to form YBa{sub 2}Cu{sub 3}O{sub x} are heated in the presence of a Nd{sub 1+x}Ba{sub 2{minus}x}Cu{sub 3}O{sub y} seed crystal to a temperature sufficient to form a liquid phase in the YBa{sub 2}Cu{sub 3}O{sub x} while maintaining the seed crystal solid. The materials are slowly cooled to provide a YBa{sub 2}Cu{sub 3}O{sub x} material having a predetermined number of domains between 1 and 5. Crack-free single domain materials can be formed using either plate shaped seed crystals or cube shaped seed crystals with a pedestal of preferential orientation material. 7 figs.

    5. Multicolor photonic crystal laser array

      DOE Patents [OSTI]

      Wright, Jeremy B; Brener, Igal; Subramania, Ganapathi S; Wang, George T; Li, Qiming

      2015-04-28

      A multicolor photonic crystal laser array comprises pixels of monolithically grown gain sections each with a different emission center wavelength. As an example, two-dimensional surface-emitting photonic crystal lasers comprising broad gain-bandwidth III-nitride multiple quantum well axial heterostructures were fabricated using a novel top-down nanowire fabrication method. Single-mode lasing was obtained in the blue-violet spectral region with 60 nm of tuning (or 16% of the nominal center wavelength) that was determined purely by the photonic crystal geometry. This approach can be extended to cover the entire visible spectrum.

    6. Crystal growth and annealing method and apparatus

      DOE Patents [OSTI]

      Gianoulakis, Steven E.; Sparrow, Robert

      2001-01-01

      A method and apparatus for producing crystals that minimizes birefringence even at large crystal sizes, and is suitable for production of CaF.sub.2 crystals. The method of the present invention comprises annealing a crystal by maintaining a minimal temperature gradient in the crystal while slowly reducing the bulk temperature of the crystal. An apparatus according to the present invention includes a thermal control system added to a crystal growth and annealing apparatus, wherein the thermal control system allows a temperature gradient during crystal growth but minimizes the temperature gradient during crystal annealing. An embodiment of the present invention comprises a secondary heater incorporated into a conventional crystal growth and annealing apparatus. The secondary heater supplies heat to minimize the temperature gradients in the crystal during the annealing process. The secondary heater can mount near the bottom of the crucible to effectively maintain appropriate temperature gradients.

    7. Thiogallate Blue Phosphors for Thin Film Electroluminescent Flat Panel Displays

      SciTech Connect (OSTI)

      Dye, Robert C.; Tuenge, Richard T.

      1997-04-03

      This project helped to develop a metal-organic chemical vapor deposition (MOCVD) method that could improve the efficiency of the blue phosphor for full color thin-film electroluminescent (TFEL) flat panel displays. High quality SrS and SrS:Ce thin films were deposited from Sr(thd)2, Ce(thd)4 and H2S via a low pressure MOCVD process. Film characteristics were found to be insensitive to the presence of the cerium dopant in the concn. range investigated. Depositions were carried out for a wide temp. range (250-550°C). Deposition rates were found to be relatively insensitive for the temp. range investigated. The films produced were found to be highly cryst. at all temps. investigated. Deposited material showed texturing as a function of substrate material and temp. FWHM of the a 111 ii reflections were found to have a 2Q values of 0.15-0.18 deg. for all temps. RBS and AES shows stoichiometric 1 : 1 SrS with less than 2% carbon and oxygen contaminates. ERO indicates the films to have 1- 2.5% hydrogen. Films doped with 0.019-0.043 atom % Ce showed weak blue-green to green PL with increasing dopant concn. Doped films yielded up to 3.2 cd/m2 EL emission with CIE coordinates of x = 0.22 and y = 0.32 and turn-on voltages of 150-250 V.

    8. Liquid class predictor for liquid handling of complex mixtures

      DOE Patents [OSTI]

      Seglke, Brent W.; Lekin, Timothy P.

      2008-12-09

      A method of establishing liquid classes of complex mixtures for liquid handling equipment. The mixtures are composed of components and the equipment has equipment parameters. The first step comprises preparing a response curve for the components. The next step comprises using the response curve to prepare a response indicator for the mixtures. The next step comprises deriving a model that relates the components and the mixtures to establish the liquid classes.

    9. Vibrational spectroscopy of liquid mixtures and solid/liquid interfaces |

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Argonne Leadership Computing Facility Molecular orbital representation of the electronic states in the first solvation shell in water. The inset shows different contributions (total, inter- and intra-molecular) to the IR stretching band of liquid water. Vibrational spectroscopy of liquid mixtures and solid/liquid interfaces PI Name: Giulia Galli PI Email: gagalli@ucdavis.edu Institution: University of California, Davis Allocation Program: INCITE Allocation Hours at ALCF: 1 Million Year: 2010

    10. Acquisition of Single Crystal Growth and Characterization Equipment

      SciTech Connect (OSTI)

      Maple, M. Brian; Zocco, Diego A.

      2008-12-09

      Final Report for DOE Grant No. DE-FG02-04ER46178 'Acquisition of Single Crystal Growth and Characterization Equipment'. There is growing concern in the condensed matter community that the need for quality crystal growth and materials preparation laboratories is not being met in the United States. It has been suggested that there are too many researchers performing measurements on too few materials. As a result, many user facilities are not being used optimally. The number of proficient crystal growers is too small. In addition, insufficient attention is being paid to the enterprise of finding new and interesting materials, which is the driving force behind much of condensed matter research and, ultimately, technology. While a detailed assessment of this situation is clearly needed, enough evidence of a problem already exists to compel a general consensus that the situation must be addressed promptly. This final report describes the work carried out during the last four years in our group, in which a state-of-the-art single crystal growth and characterization facility was established for the study of novel oxides and intermetallic compounds of rare earth, actinide and transition metal elements. Research emphasis is on the physics of superconducting (SC), magnetic, heavy fermion (HF), non-Fermi liquid (NFL) and other types of strongly correlated electron phenomena in bulk single crystals. Properties of these materials are being studied as a function of concentration of chemical constituents, temperature, pressure, and magnetic field, which provide information about the electronic, lattice, and magnetic excitations at the root of various strongly correlated electron phenomena. Most importantly, the facility makes possible the investigation of material properties that can only be achieved in high quality bulk single crystals, including magnetic and transport phenomena, studies of the effects of disorder, properties in the clean limit, and spectroscopic and scattering

    11. PREPARATION OF REFRACTORY OXIDE CRYSTALS

      DOE Patents [OSTI]

      Grimes, W.R.; Shaffer, J.H.; Watson, G.M.

      1962-11-13

      A method is given for preparing uranium dioxide, thorium oxide, and beryllium oxide in the form of enlarged individual crystals. The surface of a fused alkali metal halide melt containing dissolved uranium, thorium, or beryllium values is contacted with a water-vapor-bearing inert gas stream at a rate of 5 to 10 cubic centimeters per minute per square centimeter of melt surface area. Growth of individual crystals is obtained by prolonged contact. Beryllium oxide-coated uranium dioxide crystals are prepared by disposing uranium dioxide crystals 5 to 20 microns in diameter in a beryllium-containing melt and contacting the melt with a water-vapor-bearing inert gas stream in the same manner. (AEC)

    12. Crystal face temperature determination means

      DOE Patents [OSTI]

      Nason, Donald O.; Burger, Arnold

      1994-01-01

      An optically transparent furnace (10) having a detection apparatus (29) with a pedestal (12) enclosed in an evacuated ampule (16) for growing a crystal (14) thereon. Temperature differential is provided by a source heater (20), a base heater (24) and a cold finger (26) such that material migrates from a polycrystalline source material (18) to grow the crystal (14). A quartz halogen lamp (32) projects a collimated beam (30) onto the crystal (14) and a reflected beam (34) is analyzed by a double monochromator and photomultiplier detection spectrometer (40) and the detected peak position (48) in the reflected energy spectrum (44) of the reflected beam (34) is interpreted to determine surface temperature of the crystal (14).

    13. Versatile microbial surface-display for environmental remediation and biofuels production

      SciTech Connect (OSTI)

      Wu, Cindy H.; Mulchandani, Ashok; Chen, wilfred

      2008-02-14

      Surface display is a powerful technique that utilizes natural microbial functional components to express proteins or peptides on the cell exterior. Since the reporting of the first surface-display system in the mid-1980s, a variety of new systems have been reported for yeast, Gram-positive and Gram-negative bacteria. Non-conventional display methods are emerging, eliminating the generation of genetically modified microorganisms. Cells with surface display are used as biocatalysts, biosorbents and biostimulants. Microbial cell-surface display has proven to be extremely important for numerous applications ranging from combinatorial library screening and protein engineering to bioremediation and biofuels production.

    14. Portable liquid collection electrostatic precipitator

      DOE Patents [OSTI]

      Carlson, Duane C.; DeGange, John J.; Halverson, Justin E.

      2005-10-18

      A portable liquid collection electrostatic collection precipitator for analyzing air is provided which is a relatively small, self-contained device. The device has a tubular collection electrode, a reservoir for a liquid, and a pump. The pump pumps the liquid into the collection electrode such that the liquid flows down the exterior of the collection electrode and is recirculated to the reservoir. An air intake is provided such that air to be analyzed flows through an ionization section to ionize analytes in the air, and then flows near the collection electrode where ionized analytes are collected. A portable power source is connected to the air intake and the collection electrode. Ionizable constituents in the air are ionized, attracted to the collection electrode, and precipitated in the liquid. The precipitator may also have an analyzer for the liquid and may have a transceiver allowing remote operation and data collection.

    15. Electron Bubbles in Liquid Helium

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Electron Bubbles in Liquid Helium and Quantum Mechanics Humphrey J. Maris Brown University September 16, 2015 4:00 p.m. An electron entering liquid helium forces open a cavity referred to as an electron bubble. These objects have been studied in many past experiments and appear to be well understood. However, experiments have revealed that in addition to these normal electron bubbles there are other negatively charged objects in liquid helium. Despite much effort the structure of these so-called

    16. LIQUID METAL COMPOSITIONS CONTAINING URANIUM

      DOE Patents [OSTI]

      Teitel, R.J.

      1959-04-21

      Liquid metal compositions containing a solid uranium compound dispersed therein is described. Uranium combines with tin to form the intermetallic compound USn/sub 3/. It has been found that this compound may be incorporated into a liquid bath containing bismuth and lead-bismuth components, if a relatively small percentage of tin is also included in the bath. The composition has a low thermal neutron cross section which makes it suitable for use in a liquid metal fueled nuclear reactor.

    17. Liquid monobenzoxazine based resin system

      DOE Patents [OSTI]

      Tietze, Roger; Nguyen, Yen-Loan; Bryant, Mark

      2014-10-07

      The present invention provides a liquid resin system including a liquid monobenzoxazine monomer and a non-glycidyl epoxy compound, wherein the weight ratio of the monobenzoxazine monomer to the non-glycidyl epoxy compound is in a range of about 25:75 to about 60:40. The liquid resin system exhibits a low viscosity and exceptional stability over an extended period of time making its use in a variety of composite manufacturing methods highly advantageous.

    18. Supercooled liquid water Estimation Tool

      Energy Science and Technology Software Center (OSTI)

      2012-05-04

      The Cloud Supercooled liquid water Estimation Tool (SEET) is a user driven Graphical User Interface (GUI) that estimates cloud supercooled liquid water (SLW) content in terms of vertical column and total mass from Moderate resolution Imaging Supercooled liquid water Estimation Tool Spectroradiometer (MODIS) spatially derived cloud products and realistic vertical cloud parameterizations that are user defined. It also contains functions for post-processing of the resulting data in tabular and graphical form.

    19. Supported liquid membrane electrochemical separators

      DOE Patents [OSTI]

      Pemsler, J. Paul; Dempsey, Michael D.

      1986-01-01

      Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

    20. Minimizing radiation damage in nonlinear optical crystals

      DOE Patents [OSTI]

      Cooke, D. Wayne; Bennett, Bryan L.; Cockroft, Nigel J.

      1998-01-01

      Methods are disclosed for minimizing laser induced damage to nonlinear crystals, such as KTP crystals, involving various means for electrically grounding the crystals in order to diffuse electrical discharges within the crystals caused by the incident laser beam. In certain embodiments, electrically conductive material is deposited onto or into surfaces of the nonlinear crystals and the electrically conductive surfaces are connected to an electrical ground. To minimize electrical discharges on crystal surfaces that are not covered by the grounded electrically conductive material, a vacuum may be created around the nonlinear crystal.

    1. Minimizing radiation damage in nonlinear optical crystals

      DOE Patents [OSTI]

      Cooke, D.W.; Bennett, B.L.; Cockroft, N.J.

      1998-09-08

      Methods are disclosed for minimizing laser induced damage to nonlinear crystals, such as KTP crystals, involving various means for electrically grounding the crystals in order to diffuse electrical discharges within the crystals caused by the incident laser beam. In certain embodiments, electrically conductive material is deposited onto or into surfaces of the nonlinear crystals and the electrically conductive surfaces are connected to an electrical ground. To minimize electrical discharges on crystal surfaces that are not covered by the grounded electrically conductive material, a vacuum may be created around the nonlinear crystal. 5 figs.

    2. Microsoft Word - cover

      Office of Scientific and Technical Information (OSTI)

      ... materials have attracted steadily growing interest from both academia and industry, ... their advantages in comparison to liquid crystal displays and white OLEDs (WOLEDs) may ...

    3. Search for: All records | SciTech Connect

      Office of Scientific and Technical Information (OSTI)

      motors, computers, batteries, liquid-crystal displays (LCDs), TVs and monitors, mobile ... them internally to meet the growing demand as the Chinese standard of living increases. ...

    4. OSTI, US Dept of Energy, Office of Scientific and Technical Informatio...

      Office of Scientific and Technical Information (OSTI)

      to the breakthrough technologies of magnetic storage drives, lithium-ion batteries, and the liquid crystal display, which came together in the development of MP3 devices. ...

    5. All Ring Tech Co Ltd | Open Energy Information

      Open Energy Info (EERE)

      equipment, passive element equipment, thin film transistor liquid crystal display (TFT-LCD) equipment, optoelectronic products and venturing into thin-film PV manufacturing...

    6. National Clean Energy Business Plan Competition | Department...

      Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

      Navillum Nanotechnologies developed a process to fabricate quantum dots and other types of semiconducting nanocrystals. When used in liquid crystal displays (LCD), quantum dots ...

    7. Process for preparing liquid wastes

      DOE Patents [OSTI]

      Oden, Laurance L.; Turner, Paul C.; O'Connor, William K.; Hansen, Jeffrey S.

      1997-01-01

      A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

    8. Historical Liquid Discharges and Outfalls

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      liquids were discharged to Pueblo and Los Alamos Canyons. August 1, 2013 Contamination from the Acid Canyon outfall has been clean up to below residential levels...

    9. EXPERIMENTAL LIQUID METAL FUEL REACTOR

      DOE Patents [OSTI]

      Happell, J.J.; Thomas, G.R.; Denise, R.P.; Bunts, J.L. Jr.

      1962-01-23

      A liquid metal fuel nuclear fission reactor is designed in which the fissionable material is dissolved or suspended in a liquid metal moderator and coolant. The liquid suspension flows into a chamber in which a critical amount of fissionable material is obtained. The fluid leaves the chamber and the heat of fission is extracted for power or other utilization. The improvement is in the support arrangement for a segrnented graphite core to permit dif ferential thermal expansion, effective sealing between main and blanket liquid metal flows, and avoidance of excessive stress development in the graphite segments. (AEC)

    10. Ionic liquids, electrolyte solutions including the ionic liquids, and energy storage devices including the ionic liquids

      SciTech Connect (OSTI)

      Gering, Kevin L.; Harrup, Mason K.; Rollins, Harry W.

      2015-12-08

      An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. One pendant group of the at least one pendant group comprises a positively charged pendant group. Additional embodiments of ionic liquids are disclosed, as are electrolyte solutions and energy storage devices including the embodiments of the ionic liquid.

    11. Liquid-permeable electrode

      DOE Patents [OSTI]

      Folser, George R.

      1980-01-01

      Electrodes for use in an electrolytic cell, which are liquid-permeable and have low electrical resistance and high internal surface area are provided of a rigid, porous, carbonaceous matrix having activated carbon uniformly embedded throughout. The activated carbon may be catalyzed with platinum for improved electron transfer between electrode and electrolyte. Activated carbon is mixed with a powdered thermosetting phenolic resin and compacted to the desired shape in a heated mold to melt the resin and form the green electrode. The compact is then heated to a pyrolyzing temperature to carbonize and volatilize the resin, forming a rigid, porous structure. The permeable structure and high internal surface area are useful in electrolytic cells where it is necessary to continuously remove the products of the electrochemical reaction.

    12. Method of foaming a liquid metal

      DOE Patents [OSTI]

      Fischer, Albert K.; Johnson, Carl E.

      1980-01-01

      The addition of a small quantity of barium to liquid metal NaK or sodium has been found to promote foam formation and improve bubble retention in the liquid metal. A stable liquid metal foam will provide a more homogeneous liquid metal flow through the channel of a two-phase liquid metal MHD power generator to improve operating efficiency.

    13. Lithium-loaded liquid scintillators

      DOE Patents [OSTI]

      Dai, Sheng; Kesanli, Banu; Neal, John S.

      2012-05-15

      The invention is directed to a liquid scintillating composition containing (i) one or more non-polar organic solvents; (ii) (lithium-6)-containing nanoparticles having a size of up to 10 nm and surface-capped by hydrophobic molecules; and (iii) one or more fluorophores. The invention is also directed to a liquid scintillator containing the above composition.

    14. Taylor Instability of Incompressible Liquids

      DOE R&D Accomplishments [OSTI]

      Fermi, E.; von Neumann, J.

      1955-11-01

      A discussion is presented in simplified form of the problem of the growth of an initial ripple on the surface of an incompressible liquid in the presence of an acceleration, g, directed from the outside into the liquid. The model is that of a heavy liquid occupying at t = 0 the half space above the plane z = 0, and a rectangular wave profile is assumed. The theory is found to represent correctly one feature of experimental results, namely the fact that the half wave of the heavy liquid into the vacuum becomes rapidly narrower while the half wave pushing into the heavy liquid becomes more and more blunt. The theory fails to account for the experimental results according to which the front of the wave pushing into the heavy liquid moves with constant velocity. The case of instability at the boundary of 2 fluids of different densities is also explored. Similar results are obtained except that the acceleration of the heavy liquid into the light liquid is reduced.

    15. Magnetically focused liquid drop radiator

      DOE Patents [OSTI]

      Botts, Thomas E. (Fairfax, VA); Powell, James R. (Shoreham, NY); Lenard, Roger (Redondo Beach, CA)

      1986-01-01

      A magnetically focused liquid drop radiator for application in rejecting rgy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

    16. Magnetically focused liquid drop radiator

      DOE Patents [OSTI]

      Botts, T.E.; Powell, J.R.; Lenard, R.

      1984-12-10

      A magnetically focused liquid drop radiator for application in rejecting energy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

    17. Method for treating liquid wastes

      DOE Patents [OSTI]

      Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

      1995-12-26

      The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

    18. Method for treating liquid wastes

      DOE Patents [OSTI]

      Katti, Kattesh V.; Volkert, Wynn A.; Singh, Prahlad; Ketring, Alan R.

      1995-01-01

      The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

    19. Crystal structure determination of Efavirenz

      SciTech Connect (OSTI)

      Popeneciu, Horea Dumitru, Ristoiu; Tripon, Carmen Borodi, Gheorghe Pop, Mihaela Maria

      2015-12-23

      Needle-shaped single crystals of the title compound, C{sub 14}H{sub 9}ClF{sub 3}NO{sub 2}, were obtained from a co-crystallization experiment of Efavirenz with maleic acid in a (1:1) ratio, using methanol as solvent. Crystal structure determination at room temperature revealed a significant anisotropy of the lattice expansion compared to the previously reported low-temperature structure. In both low- and room temperature structures the cyclopropylethynyl fragment in one of the asymmetric unit molecules is disordered. While at low-temperature only one C atom exhibits positional disorder, at room temperature the disorder is present for two C atoms of the cyclopropane ring.

    20. Preparation and purification of ionic liquids and precursors

      DOE Patents [OSTI]

      Burrell, Anthony K.; Warner, Benjamin P.; McCleskey, T. Mark; Agrawal, Anoop

      2010-07-27

      Substantially pure ionic liquids and ionic liquid precursors were prepared. The substantially pure ionic liquid precursors were used to prepare substantially pure ionic liquids.

    1. Apparatus for measuring the local void fraction in a flowing liquid containing a gas

      DOE Patents [OSTI]

      Dunn, P.F.

      1979-07-17

      The local void fraction in liquid containing a gas is measured by placing an impedance-variation probe in the liquid, applying a controlled voltage or current to the probe, and measuring the probe current or voltage. A circuit for applying the one electrical parameter and measuring the other includes a feedback amplifier that minimizes the effect of probe capacitance and a digitizer to provide a clean signal. Time integration of the signal provides a measure of the void fraction, and an oscilloscope display also shows bubble size and distribution.

    2. Apparatus for measuring the local void fraction in a flowing liquid containing a gas

      DOE Patents [OSTI]

      Dunn, Patrick F.

      1981-01-01

      The local void fraction in liquid containing a gas is measured by placing an impedance-variation probe in the liquid, applying a controlled voltage or current to the probe, and measuring the probe current or voltage. A circuit for applying the one electrical parameter and measuring the other includes a feedback amplifier that minimizes the effect of probe capacitance and a digitizer to provide a clean signal. Time integration of the signal provides a measure of the void fraction, and an oscilloscope display also shows bubble size and distribution.

    3. Manufacturing method of photonic crystal

      DOE Patents [OSTI]

      Park, In Sung; Lee, Tae Ho; Ahn, Jin Ho; Biswas, Rana; Constant, Kristen P.; Ho, Kai-Ming; Lee, Jae-Hwang

      2013-01-29

      A manufacturing method of a photonic crystal is provided. In the method, a high-refractive-index material is conformally deposited on an exposed portion of a periodic template composed of a low-refractive-index material by an atomic layer deposition process so that a difference in refractive indices or dielectric constants between the template and adjacent air becomes greater, which makes it possible to form a three-dimensional photonic crystal having a superior photonic bandgap. Herein, the three-dimensional structure may be prepared by a layer-by-layer method.

    4. Fuel Cell Electric Vehicles (FCEVs) to Be Displayed on June 22...

      Energy Savers [EERE]

      Fuel Cell Electric Vehicles (FCEVs) to Be Displayed on June 22 During Sustainable ... Comparable to today's gas prices, hydrogen can be produced from low-cost natural gas ...

    5. Energy Efficiency on Display: Using Demonstration Projects to Showcase Home Performance Opportunities (201)

      Broader source: Energy.gov [DOE]

      Better Buildings Residential Network Peer Exchange Call Series: Energy Efficiency on Display: Using Demonstration Projects to Showcase Home Performance Opportunities (201), call slides and discussion summary.

    6. Real-time sub-display='inline'>ngstrom...

      Office of Scientific and Technical Information (OSTI)

      Real-time sub-display'inline'>ngstrom imaging of reversible and irreversible conformations in rhodium catalysts and graphene Kisielowski, Christian; Wang,...

    7. Calibrating Curved Crystals Used for Plasma Spectroscopy

      SciTech Connect (OSTI)

      Haugh, M. J., Jacoby, K. D., Ross, P. W., Rochau, G. Wu, M., Regan, S. P., Barrios, M. A.

      2012-10-29

      The throughput and resolving power of an X-ray spectrometer that uses a curved crystal as the diffraction element is determined primarily by the crystal X-ray reflectivity properties. This poster presents a measurement technique for these crystal parameters using a simple diode source to produce a narrow spectral band. The results from measurements on concave elliptical polyethylene terephthalate (PET) crystals and convex potassium acid phthalate (KAP) crystals show large variations in the key parameters compared to those from the flat crystal.

    8. Precision Crystal Calorimeters in High Energy Physics

      ScienceCinema (OSTI)

      Ren-Yuan Zhu

      2010-01-08

      Precision crystal calorimeters traditionally play an important role in high energy physics experiments. In the last two decades, it faces a challenge to maintain its precision in a hostile radiation environment. This paper reviews the performance of crystal calorimeters constructed for high energy physics experiments and the progress achieved in understanding crystal?s radiation damage as well as in developing high quality scintillating crystals for particle physics. Potential applications of new generation scintillating crystals of high density and high light yield, such as LSO and LYSO, in particle physics experiments is also discussed.

    9. Liquid sodium dip seal maintenance system

      DOE Patents [OSTI]

      Briggs, Richard L.; Meacham, Sterling A.

      1980-01-01

      A system for spraying liquid sodium onto impurities associated with liquid dip seals of nuclear reactors. The liquid sodium mixing with the impurities dissolves the impurities in the liquid sodium. The liquid sodium having dissolved and diluted the impurities carries the impurities away from the site thereby cleaning the liquid dip seal and surrounding area. The system also allows wetting of the metallic surfaces of the dip seal thereby reducing migration of radioactive particles across the wetted boundary.

    10. Method of measuring a liquid pool volume

      DOE Patents [OSTI]

      Garcia, Gabe V.; Carlson, Nancy M.; Donaldson, Alan D.

      1991-01-01

      A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid.

    11. Hydrophobic ionic liquids

      DOE Patents [OSTI]

      Koch, Victor R.; Nanjundiah, Chenniah; Carlin, Richard T.

      1998-01-01

      Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F--, Cl--, CF.sub.3 --, SF.sub.5 --, CF.sub.3 S--, (CF.sub.3).sub.2 CHS-- or (CF.sub.3).sub.3 CS--; and X.sup.- is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 .ANG..sup.3.

    12. Hydrophobic ionic liquids

      DOE Patents [OSTI]

      Koch, V.R.; Nanjundiah, C.; Carlin, R.T.

      1998-10-27

      Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas shown in a diagram wherein R{sub 1}, R{sub 2}, R{sub 3}, R{sub 4}, R{sub 5}, and R{sub 6} are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F-, Cl-, CF{sub 3}-, SF{sub 5}-, CF{sub 3}S-, (CF{sub 3}){sub 2}CHS- or (CF{sub 3}){sub 3}CS-; and X{sup {minus}} is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 {angstrom}{sup 3}. 4 figs.

    13. Molecular catalytic coal liquid conversion. Quarterly status...

      Office of Scientific and Technical Information (OSTI)

      Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. ... organic base catalysts for arene hydrogenation and the hydrotreating of the coal liquids. ...

    14. Molecular catalytic coal liquid conversion. Quarterly report...

      Office of Scientific and Technical Information (OSTI)

      Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. ... organic base catalysts for arene hydrogenation and the hydrotreating of the coal liquids. ...

    15. Molecular catalytic coal liquid conversion. Quarterly report...

      Office of Scientific and Technical Information (OSTI)

      Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. ... Task 2, organic base-catalyzed arene hydrogenation and hydrotreating of the coal liquids. ...

    16. Dielectric liquid pulsed-power switch

      DOE Patents [OSTI]

      Christophorou, Loucas G.; Faidas, Homer

      1990-01-01

      This disclosure identifies dielectric liquids for use as opening and closing switching media in pulsed power technology, and describes a dielectric-liquid-pulsed-power switch empolying flashlamps.

    17. LiquidMaize LLC | Open Energy Information

      Open Energy Info (EERE)

      Name: LiquidMaize, LLC Place: Denver, Colorado Zip: 80237 Product: LiquidMaize is an ethanol development and management company that builds, owns, and operates ethanol plants...

    18. Air Liquide Hydrogen Energy | Open Energy Information

      Open Energy Info (EERE)

      Hydrogen Energy Jump to: navigation, search Logo: Air Liquide Hydrogen Energy Name: Air Liquide Hydrogen Energy Address: 6, Rue Cognacq-Jay Place: Paris, France Zip: 75321 Sector:...

    19. "Radiative Liquid Lithium (metal) Divertor" Inventor..-- Masayuki...

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      "Radiative Liquid Lithium (metal) Divertor" Inventor..-- Masayuki Ono The invention utilizes liquid lithium as a radiative material. The radiative process greatly reduces the ...

    20. Synthesis of Ionic Liquids - Energy Innovation Portal

      Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

      Synthesis of Ionic Liquids Ionic Liquids for Chemical Separation Processes Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing Summary Chemical ...

      1. Liquid Transportation Fuels from Coal and Biomass

        Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

        Liquid Tr anspor tation Fuels from Coal and Biomass Technological Status, Costs, and ... technologies for converting biomass and coal to liquid fuels that are deployable by ...

      2. Historical Liquid Discharges and Outfalls

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        This drop-down provides the most current six months and six years of data for the table below. For complete history do one of the following: Click on a cell value in the table for the history of an individual data series. Click on the "Download All History" link for all data series shown in the table. Close Window

        Historical Liquid Discharges and Outfalls Historical Liquid Discharges and Outfalls During the 1940s and 1950s, untreated radioactive liquids were discharged to Pueblo and

      3. Vibrational Spectroscopy of Liquid Mixtures and Solid/Liquid Interfaces |

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        Argonne Leadership Computing Facility Simulations were carried out with the Qbox code Square modulus ( blue surface) of the highest occupied orbital (HOMO) of a chloride anion (green sphere) in liquid water (oxygen and hydrogen atoms are represented by red and white spheres, respectively), as obtained with ab initio molecular dynamics simulations using hybrid functionals. The relative positions of the anion HOMO and the valence band maximum (VBM) and conduction band minimum (CBM) of liquid

      4. Strings of liquid beads for gas-liquid contact operations

        SciTech Connect (OSTI)

        Hattori, Kenji; Ishikawa, Mitsukuni; Mori, Y.H. . Dept. of Mechanical Engineering)

        1994-12-01

        Energy recovery from hot gases exhausted from power plants, garbage incineration facilities, and many industrial processes has been growing due to demands for saving the primary-energy consumption. A novel device for gas-liquid contact operations is proposed to feed a liquid onto wires (or threads) hanging down in a gas stream is proposed. The liquid disintegrates into beads strung on each wire at regular intervals; if the wire is moderately wettable, a thin film forms to sheathe the wire, thereby interconnecting the beads. Since the beads fall down slowly, which possibly renews the film flowing down even more slowly, a sufficient gas-liquid contact time is available even in a contactor with considerably limited height. An approximate calculation method is developed for predicting the variation in the temperature effectiveness for the liquid (the fractional approach of the liquid exit temperature to the gas inlet temperature) with the falling distance, assuming an applicability of strings-of-beads contactors to thermal energy recovery from hot gas streams.

      5. Photonic crystal surface-emitting lasers

        DOE Patents [OSTI]

        Chua, Song Liang; Lu, Ling; Soljacic, Marin

        2015-06-23

        A photonic-crystal surface-emitting laser (PCSEL) includes a gain medium electromagnetically coupled to a photonic crystal whose energy band structure exhibits a Dirac cone of linear dispersion at the center of the photonic crystal's Brillouin zone. This Dirac cone's vertex is called a Dirac point; because it is at the Brillouin zone center, it is called an accidental Dirac point. Tuning the photonic crystal's band structure (e.g., by changing the photonic crystal's dimensions or refractive index) to exhibit an accidental Dirac point increases the photonic crystal's mode spacing by orders of magnitudes and reduces or eliminates the photonic crystal's distributed in-plane feedback. Thus, the photonic crystal can act as a resonator that supports single-mode output from the PCSEL over a larger area than is possible with conventional PCSELs, which have quadratic band edge dispersion. Because output power generally scales with output area, this increase in output area results in higher possible output powers.

      6. Charge Transport and Glassy Dynamics in Ionic Liquids

        SciTech Connect (OSTI)

        Sangoro, Joshua R; Kremer, Friedrich

        2012-01-01

        Ionic liquids (ILs) exhibit unique features such as low melting points, low vapor pressures, wide liquidus temperature ranges, high thermal stability, high ionic conductivity, and wide electrochemical windows. As a result, they show promise for use in variety of applications: as reaction media, in batteries and supercapacitors, in solar and fuel cells, for electrochemical deposition of metals and semiconductors, for protein extraction and crystallization, and many others. Because of the ease with which they can be supercooled, ionic liquids offer new opportunities to investigate long-standing questions regarding the nature of the dynamic glass transition and its possible link to charge transport. Despite the significant steps achieved from experimental and theoretical studies, no generally accepted quantitative theory of dynamic glass transition to date has been capable of reproducing all the experimentally observed features. In this Account, we discuss recent studies of the interplay between charge transport and glassy dynamics in ionic liquids as investigated by a combination of several experimental techniques including broadband dielectric spectroscopy, pulsed field gradient nuclear magnetic resonance, dynamic mechanical spectroscopy, and differential scanning calorimetry. Based on EinsteinSmoluchowski relations, we use dielectric spectra of ionic liquids to determine diffusion coefficients in quantitative agreement with independent pulsed field gradient nuclear magnetic resonance measurements, but spanning a broader range of more than 10 orders of magnitude. This approach provides a novel opportunity to determine the electrical mobility and effective number density of charge carriers as well as their types of thermal activation from the measured dc conductivity separately. We also unravel the origin of the remarkable universality of charge transport in different classes of glass-forming ionic liquids.

      7. Multicomponent liquid ion exchange with chabazite zeolites

        SciTech Connect (OSTI)

        Robinson, S.M.; Arnold, W.D. Jr.; Byers, C.W.

        1993-10-01

        In spite of the increasing commercial use of zeolites for binary and multicomponent sorption, the understanding of the basic mass-transfer processes associated with multicomponent zeolite ion-exchange systems is quite limited. This study was undertaken to evaluate Na-Ca-Mg-Cs-Sr ion exchange from an aqueous solution using a chabazite zeolite. Mass-transfer coefficients and equilibrium equations were determined from experimental batch-reactor data for single and multicomponent systems. The Langmuir isotherm was used to represent the equilibrium relationship for binary systems, and a modified Dubinin-Polyani model was used for the multicomponent systems. The experimental data indicate that diffusion through the microporous zeolite crystals is the primary diffusional resistance. Macropore diffusion also significantly contributes to the mass-transfer resistance. Various mass-transfer models were compared to the experimental data to determine mass-transfer coefficients. Effective diffusivities were obtained which accurately predicted experimental data using a variety of models. Only the model which accounts for micropore and macropore diffusion occurring in series accurately predicted multicomponent data using single-component diffusivities. Liquid and surface diffusion both contribute to macropore diffusion. Surface and micropore diffusivities were determined to be concentration dependent.

      8. Flipping crystals improves solar-cell performance

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        Flipping crystals improves solar-cell performance Flipping crystals improves solar-cell performance Perovskite research team spin-casts crystals for efficient and resilient optoelectronic devices. July 6, 2016 Perovskite research team spin-casts crystals for efficient and resilient optoelectronic devices. Three types of large-area solar cells made out of two-dimensional perovskites. At left, a room-temperature cast film; upper middle is a sample with the problematic band gap, and at right is the

      9. Crystal of GTP Cyclohydrolase Type IB

        DOE Patents [OSTI]

        Swairjo, Manal A.; Iwata-Reuyl, Dirk; de Crecy-Lagard, Valerie

        2012-12-11

        This invention relates to a novel, bacterial GTP Cyclohydrolase Type IB enzyme, and the crystal structure thereof.

      10. Ames Lab 101: Growing Crystals in Space

        ScienceCinema (OSTI)

        Trivedi, Rohit

        2012-08-29

        Rohit Trivedi, distinguished professor of materials science and engineering, discusses his research with NASA to grow crystals in space.

      11. Ames Lab 101: Growing Crystals in Space

        SciTech Connect (OSTI)

        Trivedi, Rohit

        2011-01-01

        Rohit Trivedi, distinguished professor of materials science and engineering, discusses his research with NASA to grow crystals in space.

      12. Crystal Structures of Lipoglycopeptide Antibiotic Deacetylases...

        Office of Scientific and Technical Information (OSTI)

        pseudoaglycone deacetylase with a fatty acid product provides further insights ... Subject: 60 APPLIED LIFE SCIENCES; ANTIBIOTICS; BIOSYNTHESIS; CARBOXYLIC ACIDS; CRYSTAL ...

      13. Shock compression of liquid hydrazine

        SciTech Connect (OSTI)

        Garcia, B.O.; Chavez, D.J.

        1995-01-01

        Liquid hydrazine (N{sub 2}H{sub 4}) is a propellant used by the Air Force and NASA for aerospace propulsion and power systems. Because the propellant modules that contain the hydrazine can be subject to debris impacts during their use, the shock states that can occur in the hydrazine need to be characterized to safely predict its response. Several shock compression experiments have been conducted in an attempt to investigate the detonability of liquid hydrazine; however, the experiments results disagree. Therefore, in this study, we reproduced each experiment numerically to evaluate in detail the shock wave profiles generated in the liquid hydrazine. This paper presents the results of each numerical simulation and compares the results to those obtained in experiment. We also present the methodology of our approach, which includes chemical kinetic experiments, chemical equilibrium calculations, and characterization of the equation of state of liquid hydrazine.

      14. Fluorescent optical liquid level sensor

        DOE Patents [OSTI]

        Weiss, Jonathan D. (Albuquerque, NM)

        2001-01-01

        A liquid level sensor comprising a transparent waveguide containing fluorescent material that is excited by light of a first wavelength and emits at a second, longer wavelength. The upper end of the waveguide is connected to a light source at the first wavelength through a beveled portion of the waveguide such that the input light is totally internally reflected within the waveguide above an air/liquid interface in a tank but is transmitted into the liquid below this interface. Light is emitted from the fluorescent material only in those portions of the waveguide that are above the air/liquid interface, to be collected at the upper end of the waveguide by a detector that is sensitive only to the second wavelength. As the interface moves down in the tank, the signal strength from the detector will increase.

      15. Liquid Hydrogen Absorber for MICE

        SciTech Connect (OSTI)

        Ishimoto, S.; Suzuki, S.; Yoshida, M.; Green, Michael A.; Kuno, Y.; Lau, Wing

        2010-05-30

        Liquid hydrogen absorbers for the Muon Ionization Cooling Experiment (MICE) have been developed, and the first absorber has been tested at KEK. In the preliminary test at KEK we have successfully filled the absorber with {approx}2 liters of liquid hydrogen. The measured hydrogen condensation speed was 2.5 liters/day at 1.0 bar. No hydrogen leakage to vacuum was found between 300 K and 20 K. The MICE experiment includes three AFC (absorber focusing coil) modules, each containing a 21 liter liquid hydrogen absorber made of aluminum. The AFC module has safety windows to separate its vacuum from that of neighboring modules. Liquid hydrogen is supplied from a cryocooler with cooling power 1.5 W at 4.2 K. The first absorber will be assembled in the AFC module and installed in MICE at RAL.

      16. Crystal McDonald | Department of Energy

        Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

        Crystal McDonald About Us Crystal McDonald - Project Officer, Department of Energy. Crystal McDonald is a Project Officer at the Department of Energy. Most Recent Small Towns Achieve Big Savings with Lighting Upgrades August 28 A Former "Most Wanted" Building Gets a Reprieve March 1

      17. Robotic CCD microscope for enhanced crystal recognition

        DOE Patents [OSTI]

        Segelke, Brent W.; Toppani, Dominique

        2007-11-06

        A robotic CCD microscope and procedures to automate crystal recognition. The robotic CCD microscope and procedures enables more accurate crystal recognition, leading to fewer false negative and fewer false positives, and enable detection of smaller crystals compared to other methods available today.

      18. ARM - Measurement - Liquid water content

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        content ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water content The concentration (mass/vol) of liquid water droplets in a cloud. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded

      19. Liquid-blocking check valve

        DOE Patents [OSTI]

        Merrill, J.T.

        1982-09-27

        A liquid blocking check valve useful particularly in a pneumatic system utilizing a pressurized liquid fill chamber. The valve includes a floatable ball disposed within a housing defining a chamber. The housing is provided with an inlet aperture disposed in the top of said chamber, and an outlet aperture disposed in the bottom of said chamber in an offset relation to said inlet aperture and in communication with a cutaway side wall section of said housing.

      20. High-density grids for efficient data collection from multiple crystals

        SciTech Connect (OSTI)

        Baxter, Elizabeth L.; Aguila, Laura; Alonso-Mori, Roberto; Barnes, Christopher O.; Bonagura, Christopher A.; Brehmer, Winnie; Brunger, Axel T.; Calero, Guillermo; Caradoc-Davies, Tom T.; Chatterjee, Ruchira; Degrado, William F.; Fraser, James S.; Ibrahim, Mohamed; Kern, Jan; Kobilka, Brian K.; Kruse, Andrew C.; Larsson, Karl M.; Lemke, Heinrik T.; Lyubimov, Artem Y.; Manglik, Aashish; McPhillips, Scott E.; Norgren, Erik; Pang, Siew S.; Soltis, S. M.; Song, Jinhu; Thomaston, Jessica; Tsai, Yingssu; Weis, William I.; Woldeyes, Rahel A.; Yachandra, Vittal; Yano, Junko; Zouni, Athina; Cohen, Aina E.

        2016-01-01

        Higher throughput methods to mount and collect data from multiple small and radiation-sensitive crystals are important to support challenging structural investigations using microfocus synchrotron beamlines. Furthermore, efficient sample-delivery methods are essential to carry out productive femtosecond crystallography experiments at X-ray free-electron laser (XFEL) sources such as the Linac Coherent Light Source (LCLS). To address these needs, a high-density sample grid useful as a scaffold for both crystal growth and diffraction data collection has been developed and utilized for efficient goniometer-based sample delivery at synchrotron and XFEL sources. A single grid contains 75 mounting ports and fits inside an SSRL cassette or uni-puck storage container. The use of grids with an SSRL cassette expands the cassette capacity up to 7200 samples. Grids may also be covered with a polymer film or sleeve for efficient room-temperature data collection from multiple samples. New automated routines have been incorporated into theBlu-Ice/DCSSexperimental control system to support grids, including semi-automated grid alignment, fully automated positioning of grid ports, rastering and automated data collection. Specialized tools have been developed to support crystallization experiments on grids, including a universal adaptor, which allows grids to be filled by commercial liquid-handling robots, as well as incubation chambers, which support vapor-diffusion and lipidic cubic phase crystallization experiments. Experiments in which crystals were loaded into grids or grown on grids using liquid-handling robots and incubation chambers are described. Crystals were screened at LCLS-XPP and SSRL BL12-2 at room temperature and cryogenic temperatures.

      1. High-density grids for efficient data collection from multiple crystals

        SciTech Connect (OSTI)

        Baxter, Elizabeth L.; Aguila, Laura; Alonso-Mori, Roberto; Barnes, Christopher O.; Bonagura, Christopher A.; Brehmer, Winnie; Brunger, Axel T.; Calero, Guillermo; Caradoc-Davies, Tom T.; Chatterjee, Ruchira; Degrado, William F.; Fraser, James S.; Ibrahim, Mohamed; Kern, Jan; Kobilka, Brian K.; Kruse, Andrew C.; Larsson, Karl M.; Lemke, Heinrik T.; Lyubimov, Artem Y.; Manglik, Aashish; McPhillips, Scott E.; Norgren, Erik; Pang, Siew S.; Soltis, S. M.; Song, Jinhu; Thomaston, Jessica; Tsai, Yingssu; Weis, William I.; Woldeyes, Rahel A.; Yachandra, Vittal; Yano, Junko; Zouni, Athina; Cohen, Aina E.

        2015-11-03

        Higher throughput methods to mount and collect data from multiple small and radiation-sensitive crystals are important to support challenging structural investigations using microfocus synchrotron beamlines. Furthermore, efficient sample-delivery methods are essential to carry out productive femtosecond crystallography experiments at X-ray free-electron laser (XFEL) sources such as the Linac Coherent Light Source (LCLS). To address these needs, a high-density sample grid useful as a scaffold for both crystal growth and diffraction data collection has been developed and utilized for efficient goniometer-based sample delivery at synchrotron and XFEL sources. A single grid contains 75 mounting ports and fits inside an SSRL cassette or uni-puck storage container. The use of grids with an SSRL cassette expands the cassette capacity up to 7200 samples. Grids may also be covered with a polymer film or sleeve for efficient room-temperature data collection from multiple samples. New automated routines have been incorporated into theBlu-Ice/DCSSexperimental control system to support grids, including semi-automated grid alignment, fully automated positioning of grid ports, rastering and automated data collection. Specialized tools have been developed to support crystallization experiments on grids, including a universal adaptor, which allows grids to be filled by commercial liquid-handling robots, as well as incubation chambers, which support vapor-diffusion and lipidic cubic phase crystallization experiments. Experiments in which crystals were loaded into grids or grown on grids using liquid-handling robots and incubation chambers are described. As a result, crystals were screened at LCLS-XPP and SSRL BL12-2 at room temperature and cryogenic temperatures.

      2. High-density grids for efficient data collection from multiple crystals

        DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

        Baxter, Elizabeth L.; Aguila, Laura; Alonso-Mori, Roberto; Barnes, Christopher O.; Bonagura, Christopher A.; Brehmer, Winnie; Brunger, Axel T.; Calero, Guillermo; Caradoc-Davies, Tom T.; Chatterjee, Ruchira; et al

        2015-11-03

        Higher throughput methods to mount and collect data from multiple small and radiation-sensitive crystals are important to support challenging structural investigations using microfocus synchrotron beamlines. Furthermore, efficient sample-delivery methods are essential to carry out productive femtosecond crystallography experiments at X-ray free-electron laser (XFEL) sources such as the Linac Coherent Light Source (LCLS). To address these needs, a high-density sample grid useful as a scaffold for both crystal growth and diffraction data collection has been developed and utilized for efficient goniometer-based sample delivery at synchrotron and XFEL sources. A single grid contains 75 mounting ports and fits inside an SSRL cassettemore » or uni-puck storage container. The use of grids with an SSRL cassette expands the cassette capacity up to 7200 samples. Grids may also be covered with a polymer film or sleeve for efficient room-temperature data collection from multiple samples. New automated routines have been incorporated into theBlu-Ice/DCSSexperimental control system to support grids, including semi-automated grid alignment, fully automated positioning of grid ports, rastering and automated data collection. Specialized tools have been developed to support crystallization experiments on grids, including a universal adaptor, which allows grids to be filled by commercial liquid-handling robots, as well as incubation chambers, which support vapor-diffusion and lipidic cubic phase crystallization experiments. Experiments in which crystals were loaded into grids or grown on grids using liquid-handling robots and incubation chambers are described. As a result, crystals were screened at LCLS-XPP and SSRL BL12-2 at room temperature and cryogenic temperatures.« less

      3. Atomizer with liquid spray quenching

        DOE Patents [OSTI]

        Anderson, I.E.; Osborne, M.G.; Terpstra, R.L.

        1998-04-14

        Method and apparatus are disclosed for making metallic powder particles wherein a metallic melt is atomized by a rotating disk or other atomizer at an atomizing location in a manner to form molten droplets moving in a direction away from said atomizing location. The atomized droplets pass through a series of thin liquid quenching sheets disposed in succession about the atomizing location with each successive quenching sheet being at an increasing distance from the atomizing location. The atomized droplets are incrementally cooled and optionally passivated as they pass through the series of liquid quenching sheets without distorting the atomized droplets from their generally spherical shape. The atomized, cooled droplets can be received in a chamber having a collection wall disposed outwardly of the series of liquid quenching sheets. A liquid quenchant can be flowed proximate the chamber wall to carry the cooled atomized droplets to a collection chamber where atomized powder particles and the liquid quenchant are separated such that the liquid quenchant can be recycled. 6 figs.

      4. Atomizer with liquid spray quenching

        DOE Patents [OSTI]

        Anderson, Iver E.; Osborne, Matthew G.; Terpstra, Robert L.

        1998-04-14

        Method and apparatus for making metallic powder particles wherein a metallic melt is atomized by a rotating disk or other atomizer at an atomizing location in a manner to form molten droplets moving in a direction away from said atomizing location. The atomized droplets pass through a series of thin liquid quenching sheets disposed in succession about the atomizing location with each successive quenching sheet being at an increasing distance from the atomizing location. The atomized droplets are incrementally cooled and optionally passivated as they pass through the series of liquid quenching sheets without distorting the atomized droplets from their generally spherical shape. The atomized, cooled droplets can be received in a chamber having a collection wall disposed outwardly of the series of liquid quenching sheets. A liquid quenchant can be flowed proximate the chamber wall to carry the cooled atomized droplets to a collection chamber where atomized powder particles and the liquid quenchant are separated such that the liquid quenchant can be recycled.

      5. Multidimensional display controller for displaying to a user an aspect of a multidimensional space visible from a base viewing location along a desired viewing orientation

        DOE Patents [OSTI]

        Davidson, George S.; Anderson, Thomas G.

        2001-01-01

        A display controller allows a user to control a base viewing location, a base viewing orientation, and a relative viewing orientation. The base viewing orientation and relative viewing orientation are combined to determine a desired viewing orientation. An aspect of a multidimensional space visible from the base viewing location along the desired viewing orientation is displayed to the user. The user can change the base viewing location, base viewing orientation, and relative viewing orientation by changing the location or other properties of input objects.

      6. Understanding the impact of ionic liquid pretreatment on eucalyptus

        SciTech Connect (OSTI)

        Centikol, Ozgul; Dibble, Dean; Cheng, Gang; Kent, Michael S; Knierim, Manfred; Melnichenko, Yuri B

        2010-01-01

        The development of cost-competitive biofuels necessitates the realization of advanced biomass pretreatment technologies. Ionic liquids provide a basis for one of the most promising pretreatment technologies and are known to allow effective processing of cellulose and some biomass species. Here, we demonstrate that the ionic liquid 1-ethyl-3-methyl imidazolium acetate, [C2mim][OAc], induces structural changes at the molecular level in the cell wall of Eucalyptus globulus. Deacetylation of xylan, acetylation of the lignin units, selective removal of guaiacyl units (increasing the syringyl:guaiacyl ratio) and decreased {beta}-ether content were the most prominent changes observed. Scanning electron microscopy images of the plant cell wall sections reveal extensive swelling during [C2mim][OAc] pretreatment. X-ray diffraction measurements indicate a change in cellulose crystal structure from cellulose I to cellulose II after [C2mim][OAc] pretreatment. Enzymatic saccharification of the pretreated material produced increased sugar yields and improved hydrolysis kinetics after [C2mim][OAc] pretreatment. These results provide new insight into the mechanism of ionic liquid pretreatment and reaffirm that this approach may be promising for the production of cellulosic biofuels from woody biomass.

      7. NEW RESULTS FROM CRYSTAL COLLIMATION AT RHIC.

        SciTech Connect (OSTI)

        FLILLER,R.P.,IIIDREES,A.GASSNER,D.HAMMONS,L.MCINTYRE,G.PEGGS,S.TRBOJEVIC,D.BIRYUKOV,V.CHESNOKOV,Y.TEREKHOV,V.

        2003-05-12

        In this paper, we discuss new results from the use of the crystal collimator from the 2003 run. The yellow ring of the Relativistic Heavy Ion Collider (RHIC) has a bent crystal collimator. By properly aligning the crystal to the beam halo, particles entering the crystal are deflected away from the beam and intercepted downstream in a copper scraper. The purpose of a bent crystal is to improve the collimation efficiency as compared to a scraper alone. We compare these results to previous data, simulation, and theoretical predictions.

      8. Photocatalytic activity of glass ceramics containing Nasicon-type crystals

        SciTech Connect (OSTI)

        Fu, Jie

        2013-01-15

        Graphical abstract: Display Omitted Highlights: ? Glass ceramics containing Nasicon-type crystals were prepared. ? The glass ceramics showed photocatalytic activity under UV irradiation. ? Higher activity was observed in the MgTi{sub 4}(PO{sub 4}){sub 6}- and CaTi{sub 4}(PO{sub 4}){sub 6}-containing glass ceramics. -- Abstract: Glass ceramics were prepared by heat-treating MOTiO{sub 2}P{sub 2}O{sub 5} (M = Mg, Ca, Sr and Ba) and R{sub 2}OTiO{sub 2}P{sub 2}O{sub 5}SiO{sub 2} (R = Li, Na and K) glasses, and their photocatalytic activity was investigated. The crystalline phases precipitated in the glasses were only Nasicon-type crystals, MTi{sub 4}(PO{sub 4}){sub 6} or RTi{sub 2}(PO{sub 4}){sub 3}. Decomposition experiments of both methylene blue (MB) and acetaldehyde showed that the glass ceramics exhibited effective photocatalytic activity. The activity did not depend on the radius of the M{sup 2+} or R{sup +} ion, and higher activity was observed in the MgTi{sub 4}(PO{sub 4}){sub 6} and CaTi{sub 4}(PO{sub 4}){sub 6} precipitated glass ceramics.

      9. Crystal structure refinement with SHELXL

        SciTech Connect (OSTI)

        Sheldrick, George M., E-mail: gsheldr@shelx.uni-ac.gwdg.de [Department of Structural Chemistry, Georg-August Universitt Gttingen, Tammannstrae 4, Gttingen 37077 (Germany)

        2015-01-01

        New features added to the refinement program SHELXL since 2008 are described and explained. The improvements in the crystal structure refinement program SHELXL have been closely coupled with the development and increasing importance of the CIF (Crystallographic Information Framework) format for validating and archiving crystal structures. An important simplification is that now only one file in CIF format (for convenience, referred to simply as a CIF) containing embedded reflection data and SHELXL instructions is needed for a complete structure archive; the program SHREDCIF can be used to extract the .hkl and .ins files required for further refinement with SHELXL. Recent developments in SHELXL facilitate refinement against neutron diffraction data, the treatment of H atoms, the determination of absolute structure, the input of partial structure factors and the refinement of twinned and disordered structures. SHELXL is available free to academics for the Windows, Linux and Mac OS X operating systems, and is particularly suitable for multiple-core processors.

      10. Liquid membrane purification of biogas

        SciTech Connect (OSTI)

        Majumdar, S.; Guha, A.K.; Lee, Y.T.; Papadopoulos, T.; Khare, S. . Dept. of Chemistry and Chemical Engineering)

        1991-03-01

        Conventional gas purification technologies are highly energy intensive. They are not suitable for economic removal of CO{sub 2} from methane obtained in biogas due to the small scale of gas production. Membrane separation techniques on the other hand are ideally suited for low gas production rate applications due to their modular nature. Although liquid membranes possess a high species permeability and selectivity, they have not been used for industrial applications due to the problems of membrane stability, membrane flooding and poor operational flexibility, etc. A new hollow-fiber-contained liquid membrane (HFCLM) technique has been developed recently. This technique overcomes the shortcomings of the traditional immobilized liquid membrane technology. A new technique uses two sets of hydrophobic, microporous hollow fine fibers, packed tightly in a permeator shell. The inter-fiber space is filled with an aqueous liquid acting as the membrane. The feed gas mixture is separated by selective permeation of a species through the liquid from one fiber set to the other. The second fiber set carries a sweep stream, gas or liquid, or simply the permeated gas stream. The objectives (which were met) of the present investigation were as follows. To study the selective removal of CO{sub 2} from a model biogas mixture containing 40% CO{sub 2} (the rest being N{sub 2} or CH{sub 4}) using a HFCLM permeator under various operating modes that include sweep gas, sweep liquid, vacuum and conventional permeation; to develop a mathematical model for each mode of operation; to build a large-scale purification loop and large-scale permeators for model biogas separation and to show stable performance over a period of one month.

      11. Nanophosphor composite scintillator with a liquid matrix

        DOE Patents [OSTI]

        McKigney, Edward Allen; Burrell, Anthony Keiran; Bennett, Bryan L.; Cooke, David Wayne; Ott, Kevin Curtis; Bacrania, Minesh Kantilal; Del Sesto, Rico Emilio; Gilbertson, Robert David; Muenchausen, Ross Edward; McCleskey, Thomas Mark

        2010-03-16

        An improved nanophosphor scintillator liquid comprises nanophosphor particles in a liquid matrix. The nanophosphor particles are optionally surface modified with an organic ligand. The surface modified nanophosphor particle is essentially surface charge neutral, thereby preventing agglomeration of the nanophosphor particles during dispersion in a liquid scintillator matrix. The improved nanophosphor scintillator liquid may be used in any conventional liquid scintillator application, including in a radiation detector.

      12. Liquid Hydrogen Delivery | Department of Energy

        Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

        Hydrogen Delivery » Liquid Hydrogen Delivery Liquid Hydrogen Delivery Hydrogen is most commonly transported and delivered as a liquid when high-volume transport is needed in the absence of pipelines. To liquefy hydrogen it must be cooled to cryogenic temperatures through a liquefaction process. Trucks transporting liquid hydrogen are referred to as liquid tankers. Liquefaction Gaseous hydrogen is liquefied by cooling it to below -253°C (-423°F). Once hydrogen is liquefied it can be stored at

      13. A Liquid Layer Solution for the Grid | Department of Energy

        Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

        A Liquid Layer Solution for the Grid A Liquid Layer Solution for the Grid September 15, 2011 - 2:47pm Addthis The Liquid Metal Battery is comprised of liquid metal electrodes and a liquid electrolyte of differing densities, which allows the liquids to separate and stratify without the need for any solid separator. The Liquid Metal Battery is comprised of liquid metal electrodes and a liquid electrolyte of differing densities, which allows the liquids to separate and stratify without the need for

      14. Thermal energy storage with liquid-liquid systems

        SciTech Connect (OSTI)

        Santana, E.A.; Stiel, L.I.

        1989-03-01

        The use of liquid-liquid mixtures for heat and cool storage applications has been investigated. Suitable mixtures exhibit large changes in the heat of mixing above and below the critical solution temperature of the system. Analytical procedures have been utilized to determine potential energy storage capabilities of systems with upper or lower critical solution temperatures. It has been found that aqueous systems with lower critical solution temperatures in a suitable range can result in large increases in the effective heat capacity in the critical region. For cool storage with a system of this type, the cooling process results in a transformation from two liquid phases to a single phase. Heats of mixing have been measured with a flow calorimeter system for a number of potential mixtures, and the results are summarized.

      15. The Future of Manufacturing Takes Shape: 3D Printed Car on Display at

        Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

        Manufacturing Summit | Department of Energy The Future of Manufacturing Takes Shape: 3D Printed Car on Display at Manufacturing Summit The Future of Manufacturing Takes Shape: 3D Printed Car on Display at Manufacturing Summit September 17, 2014 - 9:50am Addthis WORLD&#039;S FIRST 1 of 6 WORLD'S FIRST The world's first 3D-printed car on display at the International Manufacturing Technology Show in Chicago last week. Arizona-based Local Motors, and Cincinnati Incorporated teamed with Oak

      16. Liquid-phase chromatography detector

        DOE Patents [OSTI]

        Voigtman, Edward G.; Winefordner, James D.; Jurgensen, Arthur R.

        1983-01-01

        A liquid-phase chromatography detector comprising a flow cell having an inlet tubular conduit for receiving a liquid chromatographic effluent and discharging it as a flowing columnar stream onto a vertically adjustable receiving surface spaced apart from and located vertically below and in close proximity to the discharge end of the tubular conduit; a receiver adapted to receive liquid overflowing from the receiving surface; an exit conduit for continuously removing liquid from the receiver; a light source for focussing fluorescence-producing light pulses on the flowing columnar stream as it passes from the outlet of the conduit to the receiving surface and a fluorescence detector to detect the produced fluorescence; a source of light pulse for producing acoustic waves in the columnar stream as it passes from the conduit outlet to the receiving surface; and a piezoelectric transducer adapted to detect those waves; and a source of bias voltage applied to the inlet tubular conduit and adapted to produce ionization of the liquid flowing through the flow cell so as to produce photocurrents therein and an electrical system to detect and record the photocurrents. This system is useful in separating and detecting individual chemical compounds from mixtures thereof.

      17. Liquid-phase chromatography detector

        DOE Patents [OSTI]

        Voigtman, E.G.; Winefordner, J.D.; Jurgensen, A.R.

        1983-11-08

        A liquid-phase chromatography detector comprises a flow cell having an inlet tubular conduit for receiving a liquid chromatographic effluent and discharging it as a flowing columnar stream onto a vertically adjustable receiving surface spaced apart from and located vertically below and in close proximity to the discharge end of the tubular conduit; a receiver adapted to receive liquid overflowing from the receiving surface; an exit conduit for continuously removing liquid from the receiver; a light source for focusing fluorescence-producing light pulses on the flowing columnar stream as it passes from the outlet of the conduit to the receiving surface and a fluorescence detector to detect the produced fluorescence; a source of light pulse for producing acoustic waves in the columnar stream as it passes from the conduit outlet to the receiving surface; and a piezoelectric transducer adapted to detect those waves; and a source of bias voltage applied to the inlet tubular conduit and adapted to produce ionization of the liquid flowing through the flow cell so as to produce photocurrents therein and an electrical system to detect and record the photocurrents. This system is useful in separating and detecting individual chemical compounds from mixtures thereof. 5 figs.

      18. FRACTIONAL CRYSTALLIZATION LABORATORY TESTING FOR INCLUSION & COPRECIPITATION WITH ACTUAL TANK WASTE

        SciTech Connect (OSTI)

        WARRANT, R.W.

        2006-12-11

        Fractional crystallization is being considered as a pretreatment method to support supplemental treatment of retrieved single-shell tank (SST) saltcake waste at the Hanford Site. The goal of the fractional crystallization process is to optimize the separation of the radioactivity (radionuclides) from the saltcake waste and send it to the Waste Treatment and Immobilization Plant and send the bulk of the saltcake to the supplemental treatment plant (bulk vitrification). The primary factors that influence the separation efficiency are (1) solid/liquid separation efficiency, (2) contaminant inclusions, and (3) co-precipitation. This is a report of testing for factors (2) and (3) with actual tank waste samples. For the purposes of this report, contaminant inclusions are defined as the inclusion of supernatant, containing contaminating radionuclides, in a pocket within the precipitating saltcake crystals. Co-precipitation is defined as the simultaneous precipitation of a saltcake crystal with a contaminating radionuclide. These two factors were tested for various potential fractional crystallization product salts by spiking the composite tank waste samples (SST Early or SST Late, external letter CH2M-0600248, ''Preparation of Composite Tank Waste Samples for ME-21 Project'') with the desired target salt and then evaporating to precipitate that salt. SST Early represents the typical composition of dissolved saltcake early in the retrieval process, and SST Late represents the typical composition during the later stages of retrieval.

      19. Vertical tube liquid pollutant separators

        SciTech Connect (OSTI)

        Lynch, W.M.

        1982-06-08

        A plurality of elongated hollow, circular, foraminous substantially vertical tubes contiguously stacked transversely to the direction flowing liquid such as waste water containing foreign matter, I.E., settable solids and free oil, in a coalescer-separator apparatus provide a filter body providing for significant surface area contact by the liquid on both inside and outside surfaces of the tubes to entrap the foreign matter but defining substantially vertical passages permitting the entrapped foreign matter to be gravity separated with the lighter matter coalescing and floating upwardly and the heavier matter settling downwardly so that substantially clarified effluent flows from the apparatus. The stacked tube filter body is contained within an insulated closed container of a sufficient capacity, and the arrays of holes in the tube walls are coordinated with respect to the intended volumetric capacity of the apparatus, so that turbulence in the liquid flowing through the filter body is minimized.

      20. Does the Utility Rates service on OpenEI return/display the latest...

        Open Energy Info (EERE)

        display the latest data or only approved data? Home > Groups > Utility Rate I'm using SAM to download OpenEI utility rates and was wondering if I'm downloading the latest rates...

      1. How do I display the Map of Wind Farms csv coordinates in ArcMap...

        Open Energy Info (EERE)

        display and how it is stored. I agree that it is not an ideal format for using with ArcGIS, but this can be easily modified using your favorite spreadsheet editor. Since Excel...

      2. The MORPHEUS II protein crystallization screen

        SciTech Connect (OSTI)

        Gorrec, Fabrice

        2015-06-27

        MORPHEUS II is a 96-condition initial crystallization screen formulated de novo. The screen incorporates reagents selected from the Protein Data Bank to yield crystals that are not observed in traditional conditions. In addition, the formulation facilitates the optimization and cryoprotection of crystals. High-quality macromolecular crystals are a prerequisite for the process of protein structure determination by X-ray diffraction. Unfortunately, the relative yield of diffraction-quality crystals from crystallization experiments is often very low. In this context, innovative crystallization screen formulations are continuously being developed. In the past, MORPHEUS, a screen in which each condition integrates a mix of additives selected from the Protein Data Bank, a cryoprotectant and a buffer system, was developed. Here, MORPHEUS II, a follow-up to the original 96-condition initial screen, is described. Reagents were selected to yield crystals when none might be observed in traditional initial screens. Besides, the screen includes heavy atoms for experimental phasing and small polyols to ensure the cryoprotection of crystals. The suitability of the resulting novel conditions is shown by the crystallization of a broad variety of protein samples and their efficiency is compared with commercially available conditions.

      3. Asymmetrically cut crystals for synchrotron radiation monochromators

        SciTech Connect (OSTI)

        Sanchez del Rio, M. ); Cerrina, F. )

        1992-01-01

        Asymmetrically cut crystals are interesting for use in synchrotron radiation monochromators because of their good energy resolution characteristics and their focusing properties. Ray tracing codes, such as SHADOW, are very efficient in the design and development of new optical devices. In order to determine the convenience of using asymmetrically cut crystals for x-ray monochromators, SHADOW has been extended to include these kinds of crystals. The physical approach to ray tracing asymmetrically cut crystals is based on the coexistence of two periodic structures. One of these is the bulk periodic structure of the Bragg planes. Such a structure determines the existence of a rocking curve near the Bragg condition, and is implemented in SHADOW following the Darwin--Prins formalism of the dynamical theory of diffraction. The second periodic structure is a one-dimensional grating on the crystal surface, formed by the truncation of the lattice planes with the surface. This grating is responsible for the focusing properties of these crystals and plays an essential role in determining the trajectory of the rays. The combination of an asymmetric crystal and a nonplanar surface can be easily achieved by bending (Johann case) to provide improved properties. More complex cases such as the ground-bent crystals (i.e., Johansson geometry) can be considered as a particular case of asymmetrical crystals in which the angle between the Bragg planes and the surface change along the crystal surface. All these cases have been implemented in SHADOW.

      4. A New Way to Display the 3-D Structure of Molecules

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        A New Way to Display the 3-D Structure of Molecules Researchers have created a sort of nanoscale display case that enables new atomic-scale views of hard-to-study chemical and biological samples. Their work could help to reveal new structural details for a range of challenging molecules, such as complex chemical compounds and potentially new drugs, by stabilizing them inside metal-organic frameworks (MOFs).

      5. Fuel Cell Electric Vehicles (FCEVs) to Be Displayed on June 22 During

        Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

        Sustainable Transportation Day | Department of Energy Electric Vehicles (FCEVs) to Be Displayed on June 22 During Sustainable Transportation Day Fuel Cell Electric Vehicles (FCEVs) to Be Displayed on June 22 During Sustainable Transportation Day June 16, 2015 - 12:40pm Addthis On June 22, the Office of Energy Efficiency and Renewable Energy's (EERE's) Fuel Cell, Bioenergy, and Vehicle Technologies Offices will host a Sustainable Transportation Day showcasing EERE's strategic investments in

      6. Ventura_E_liquids.pdf

        U.S. Energy Information Administration (EIA) Indexed Site

        Liquids Reserve Class No 2004 Proved Liquids Reserves 0.1 - 10 Mbbl 10.1 - 100 Mbbl 100.1 - 1,000 Mbbl 1,000.1 - 10,000 Mbbl > 10,000 Mbbl Study Area Outline 0 4 8 2 6 Miles ± The mapped oil and gas field boundary outlines were created by the Reserves and Production Division, Office of Oil and Gas, Energy Information Administration pursuant to studies required by Section 604 of the Energy Policy and Conservation Act Amendments of 2000 (P.L. 106-469). The boundaries are not informed by

      7. ARM - Measurement - Liquid water path

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        path ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water path A measure of the weight of the liquid water droplets in the atmosphere above a unit surface area on the earth, given in units of kg m-2. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument

      8. Liquid metal cooled nuclear reactors

        SciTech Connect (OSTI)

        Barnes, S.

        1980-10-07

        The vault of a liquid metal cooled nuclear reactor is lined with thermal insulation. The insulation is in two layers, a first layer cladding the vault surface is of solid ceramic material while a second layer cladding the first layer is of fibrous or metallic material. In the event of a breach of the vessel leakage of liquid metal is absorbed by the second layer providing a conduction path to the first layer thereby enhancing heat loss to the concrete of the vault and maintaining the internal temperature at a safe limit.

      9. A combined nanoplasmonic and electrodeless quartz crystal microbalance setup

        SciTech Connect (OSTI)

        Larsson, Elin M.; Langhammer, Christoph; Zoric, Igor; Kasemo, Bengt; Edvardsson, Malin E. M.

        2009-12-15

        We have developed an instrument combining localized surface plasmon resonance (LSPR) sensing with electrodeless quartz crystal microbalance with dissipation monitoring (QCM-D). The two techniques can be run simultaneously, on the same sensor surface, and with the same time resolution and sensitivity as for the individual techniques. The electrodeless QCM eliminates the need to fabricate electrodes on the quartz crystal and gives a large flexibility in choosing the surface structure and coating for both QCM-D and LSPR. The performance is demonstrated for liquid phase measurements of lipid bilayer formation and biorecognition events, and for gas phase measurements of hydrogen uptake/release by palladium nanoparticles. Advantages of using the combined equipment for biomolecular adsorption studies include synchronized information about structural transformations and extraction of molecular (dry) mass and degree of hydration of the adlayer, which cannot be obtained with the individual techniques. In hydrogen storage studies the combined equipment, allows for synchronized measurements of uptake/release kinetics and quantification of stored hydrogen amounts in nanoparticles and films at practically interesting hydrogen pressures and temperatures.

      10. Phonon manipulation with phononic crystals.

        SciTech Connect (OSTI)

        Kim Bongsang; Hopkins, Patrick Edward; Leseman, Zayd C.; Goettler, Drew F.; Su, Mehmet F.; El-Kady, Ihab Fathy; Reinke, Charles M.; Olsson, Roy H., III

        2012-01-01

        In this work, we demonstrated engineered modification of propagation of thermal phonons, i.e. at THz frequencies, using phononic crystals. This work combined theoretical work at Sandia National Laboratories, the University of New Mexico, the University of Colorado Boulder, and Carnegie Mellon University; the MESA fabrication facilities at Sandia; and the microfabrication facilities at UNM to produce world-leading control of phonon propagation in silicon at frequencies up to 3 THz. These efforts culminated in a dramatic reduction in the thermal conductivity of silicon using phononic crystals by a factor of almost 30 as compared with the bulk value, and about 6 as compared with an unpatterned slab of the same thickness. This work represents a revolutionary advance in the engineering of thermoelectric materials for optimal, high-ZT performance. We have demonstrated the significant reduction of the thermal conductivity of silicon using phononic crystal structuring using MEMS-compatible fabrication techniques and in a planar platform that is amenable to integration with typical microelectronic systems. The measured reduction in thermal conductivity as compared to bulk silicon was about a factor of 20 in the cross-plane direction [26], and a factor of 6 in the in-plane direction. Since the electrical conductivity was only reduced by a corresponding factor of about 3 due to the removal of conductive material (i.e., porosity), and the Seebeck coefficient should remain constant as an intrinsic material property, this corresponds to an effective enhancement in ZT by a factor of 2. Given the number of papers in literature devoted to only a small, incremental change in ZT, the ability to boost the ZT of a material by a factor of 2 simply by reducing thermal conductivity is groundbreaking. The results in this work were obtained using silicon, a material that has benefitted from enormous interest in the microelectronics industry and that has a fairly large thermoelectric power

      11. BPS States, Crystals, and Matrices

        DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

        Sułkowski, Piotr

        2011-01-01

        We review free fermion, melting crystal, and matrix model representations of wall-crossing phenomena on local, toric Calabi-Yau manifolds. We consider both unrefined and refined BPS counting of closed BPS states involving D2- and D0-branes bound to a D6-brane, as well as open BPS states involving open D2-branes ending on an additional D4-brane. Appropriate limit of these constructions provides, among the others, matrix model representation of refined and unrefined topological string amplitudes.

      12. Florida Nuclear Profile - Crystal River

        U.S. Energy Information Administration (EIA) Indexed Site

        Crystal River1" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration date" 3,860,0,"--","PWR","application/vnd.ms-excel","application/vnd.ms-excel" ,860,0,"--" "Data for 2010" "1 Unit was offline in 2010 for repairs." "-- Not applicable.

      13. Crystallization and functionality of inorganic materials

        SciTech Connect (OSTI)

        Xue, Dongfeng, E-mail: dongfeng@ciac.jl.cn [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China) [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China); Li, Keyan [School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China)] [School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China); Liu, Jun [Key Laboratory of Low Dimensional Materials and Application Technology, Ministry of Education, Faculty of Materials, Optoelectronics and Physics, Xiangtan University, 411105 (China)] [Key Laboratory of Low Dimensional Materials and Application Technology, Ministry of Education, Faculty of Materials, Optoelectronics and Physics, Xiangtan University, 411105 (China); Sun, Congting; Chen, Kunfeng [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China) [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (China)

        2012-10-15

        In this article, we briefly summarized our recent work on the studies of crystallization and functionality of inorganic materials. On the basis of the chemical bonding theory of single crystal growth, we can quantitatively simulate Cu{sub 2}O crystallization processes in solution system. We also kinetically controlled Cu{sub 2}O crystallization process in the reduction solution route. Lithium ion battery and supercapacitor performances of some oxides such as Co{sub 3}O{sub 4} and MnO{sub 2} were shown to elucidate the important effect of crystallization on functionality of inorganic materials. This work encourages us to create novel functionalities through the study of crystallization of inorganic materials, which warrants more chances in the field of functional materials.

      14. Method of measuring a liquid pool volume

        DOE Patents [OSTI]

        Garcia, G.V.; Carlson, N.M.; Donaldson, A.D.

        1991-03-19

        A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools is disclosed, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid. 3 figures.

      15. Edge rotational magnons in magnonic crystals

        SciTech Connect (OSTI)

        Lisenkov, Ivan Kalyabin, Dmitry; Moscow Institute of Physics and Technology, 9 Instituskij per., Dolgoprudny, 141700 Moscow Region ; Nikitov, Sergey; Moscow Institute of Physics and Technology, 9 Instituskij per., Dolgoprudny, 141700 Moscow Region; Saratov State University, 112 Bol'shaya Kazach'ya, Saratov 410012

        2013-11-11

        It is predicted that in 2D magnonic crystals the edge rotational magnons of forward volume magnetostatic spin waves can exist. Under certain conditions, locally bounded magnons may appear within the crystal consisting of the ferromagnetic matrix and periodically inserted magnetic/non-magnetic inclusions. It is also shown that interplay of different resonances in 2D magnonic crystal may provide conditions for spin wave modes existence with negative group velocity.

      16. Liquid-film electron stripper

        DOE Patents [OSTI]

        Gavin, Basil F.

        1986-01-01

        An improved liquid-film electron stripper particularly for high intensity heavy ion beams which produces constant regenerated, stable, free-standing liquid films having an adjustable thickness between 0.3 to 0.05 microns. The improved electron stripper is basically composed of at least one high speed, rotating disc with a very sharp, precision-like, ground edge on one said of the disc's periphery and with a highly polished, flat, radial surface adjacent the sharp edge. A fine stream of liquid, such as oil, impinges at a 90.degree. angle adjacent the disc's sharp outer edge. Film terminators, located at a selected distance from the disc perimeter are positioned approximately perpendicular to the film. The terminators support, shape, and stretch the film and are arranged to assist in the prevention of liquid droplet formation by directing the collected film to a reservoir below without breaking or interfering with the film. One embodiment utilizes two rotating discs and associated terminators, with the discs rotating so as to form films in opposite directions, and with the second disc being located down beam-line relative to the first disc.

      17. Ribosome engineering to promote new crystal forms

        SciTech Connect (OSTI)

        Selmer, Maria; Gao, Yong-Gui; Weixlbaumer, Albert; Ramakrishnan, V.

        2012-05-01

        Truncation of ribosomal protein L9 in T. thermophilus allows the generation of new crystal forms and the crystallization of ribosomeGTPase complexes. Crystallographic studies of the ribosome have provided molecular details of protein synthesis. However, the crystallization of functional complexes of ribosomes with GTPase translation factors proved to be elusive for a decade after the first ribosome structures were determined. Analysis of the packing in different 70S ribosome crystal forms revealed that regardless of the species or space group, a contact between ribosomal protein L9 from the large subunit and 16S rRNA in the shoulder of a neighbouring small subunit in the crystal lattice competes with the binding of GTPase elongation factors to this region of 16S rRNA. To prevent the formation of this preferred crystal contact, a mutant strain of Thermus thermophilus, HB8-MRCMSAW1, in which the ribosomal protein L9 gene has been truncated was constructed by homologous recombination. Mutant 70S ribosomes were used to crystallize and solve the structure of the ribosome with EF-G, GDP and fusidic acid in a previously unobserved crystal form. Subsequent work has shown the usefulness of this strain for crystallization of the ribosome with other GTPase factors.

      18. Silicon Crystals Inc | Open Energy Information

        Open Energy Info (EERE)

        Zip: 95742 Product: Supplier of semi-conductor grade silicon for applications that demand unusual shapes and sizes. References: Silicon Crystals Inc1 This article is a stub....

      19. Method For Screening Microcrystallizations For Crystal Formation

        DOE Patents [OSTI]

        Santarsiero, Bernard D. , Stevens, Raymond C. , Schultz, Peter G. , Jaklevic, Joseph M. , Yegian, Derek T. , Cornell, Earl W. , Nordmeyer, Robert A.

        2003-10-07

        A method is provided for performing array microcrystallizations to determine suitable crystallization conditions for a molecule, the method comprising: forming an array of microcrystallizations, each microcrystallization comprising a drop comprising a mother liquor solution whose composition varies within the array and a molecule to be crystallized, the drop having a volume of less than 1 microliter; storing the array of microcrystallizations under conditions suitable for molecule crystals to form in the drops in the array; and detecting molecule crystal formation in the drops by taking images of the drops.

      20. ARM - Field Campaign - CRYSTAL-FACE

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        govCampaignsCRYSTAL-FACE Campaign Links CRYSTAL-FACE Website ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : CRYSTAL-FACE 2002.06.26 - 2002.08.01 Lead Scientist : James Mather Data Availability Data is available to the general public at the ARM Archive. Questions regarding CRYSTAL-FACE or the PARSL data set may be directed to Jim Mather at the Pacific Northwest National Laboratory (Jim.Mather@pnl.gov) or

      1. Crystallization of Enantiomerically Pure Proteins from Quasi...

        Office of Scientific and Technical Information (OSTI)

        Crystallization of Enantiomerically Pure Proteins from Quasi-Racemic Mixtures: Structure Determination by X-Ray Diffraction of Isotope-Labeled Ester Insulin and Human Insulin ...

      2. Membrane Protein Crystallization in Lipidic Mesophases. Hosting...

        Office of Scientific and Technical Information (OSTI)

        Unexpectedly, all lipids produced high-quality, structure-grade crystals with gramicidin ... Subject: 59 BASIC BIOLOGICAL SCIENCES; 60 APPLIED LIFE SCIENCES; ANTIBIOTICS; CATIONS; ...

      3. Crystal Structures of Phosphite Dehydrogenase Provide Insights...

        Office of Scientific and Technical Information (OSTI)

        Country of Publication: United States Language: ENGLISH Subject: 59 BASIC BIOLOGICAL SCIENCES; 60 APPLIED LIFE SCIENCES; CATALYSTS; CRYSTAL STRUCTURE; ENZYMES; NICOTINAMIDE; ...

      4. Epitaxial Single Crystal Nanostructures for Batteries & PVs ...

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

      5. JX Crystals Inc | Open Energy Information

        Open Energy Info (EERE)

        Solar Product: JX Crystals designs and manufactures thermophotovoltaic gallium-antimonide cells for solar applications. Coordinates: 47.530095, -122.033799 Show Map Loading...

      6. Crystal Solar Inc | Open Energy Information

        Open Energy Info (EERE)

        Solar Inc Jump to: navigation, search Name: Crystal Solar Inc. Place: Santa Clara, California Zip: 94054 Sector: Solar Product: California-based developer of silicon solar cells....

      7. Automated macromolecular crystal detection system and method

        DOE Patents [OSTI]

        Christian, Allen T.; Segelke, Brent; Rupp, Bernard; Toppani, Dominique

        2007-06-05

        An automated macromolecular method and system for detecting crystals in two-dimensional images, such as light microscopy images obtained from an array of crystallization screens. Edges are detected from the images by identifying local maxima of a phase congruency-based function associated with each image. The detected edges are segmented into discrete line segments, which are subsequently geometrically evaluated with respect to each other to identify any crystal-like qualities such as, for example, parallel lines, facing each other, similarity in length, and relative proximity. And from the evaluation a determination is made as to whether crystals are present in each image.

      8. New Mexico Natural Gas Plant Liquids, Proved Reserves (Million...

        Gasoline and Diesel Fuel Update (EIA)

        Proved Reserves (Million Barrels) New Mexico Natural Gas Plant Liquids, Proved Reserves ... Natural Gas Liquids Proved Reserves as of Dec. 31 New Mexico Natural Gas Liquids Proved ...

      9. Crystal growth and annealing for minimized residual stress

        DOE Patents [OSTI]

        Gianoulakis, Steven E.

        2002-01-01

        A method and apparatus for producing crystals that minimizes birefringence even at large crystal sizes, and is suitable for production of CaF.sub.2 crystals. The method of the present invention comprises annealing a crystal by maintaining a minimal temperature gradient in the crystal while slowly reducing the bulk temperature of the crystal. An apparatus according to the present invention includes a thermal control system added to a crystal growth and annealing apparatus, wherein the thermal control system allows a temperature gradient during crystal growth but minimizes the temperature gradient during crystal annealing.

      10. Alternative Liquid Fuels (ALF) | Open Energy Information

        Open Energy Info (EERE)

        Liquid Fuels (ALF) Jump to: navigation, search Name: Alternative Liquid Fuels (ALF) Address: P.O. Box 76 Place: McArthur, Ohio Zip: 45651 Sector: Biofuels, Renewable Energy,...

      11. Waste Treatment Plant Liquid Effluent Treatability Evaluation

        SciTech Connect (OSTI)

        LUECK, K.J.

        2001-06-07

        Bechtel National, Inc. (BNI) provided a forecast of the radioactive, dangerous liquid effluents expected to be generated by the Waste Treatment Plant (WTP). The forecast represents the liquid effluents generated from the processing of 25 distinct batches of tank waste through the WTP. The WTP liquid effluents will be stored, treated, and disposed of in the Liquid Effluent Retention Facility (LERF) and the Effluent Treatment Facility (ETF). Fluor Hanford, Inc. (FH) evaluated the treatability of the WTP liquid effluents in the LERFIETF. The evaluation was conducted by comparing the forecast to the LERFIETF treatability envelope, which provides information on the items that determine if a liquid effluent is acceptable for receipt and treatment at the LERFIETF. The WTP liquid effluent forecast is outside the current LERFlETF treatability envelope. There are several concerns that must be addressed before the WTP liquid effluents can be accepted at the LERFIETF.

      12. Coal and Coal-Biomass to Liquids

        Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

        and Coal-Biomass to Liquids Turning coal into liquid fuels like gasoline, diesel and jet fuel, with biomass to reduce carbon dioxide emissions, is the main goal of the Coal and ...

      13. Solid-state syntheses and single-crystal characterizations of three tetravalent thorium and uranium silicates

        SciTech Connect (OSTI)

        Jin, Geng Bang Soderholm, L.

        2015-01-15

        Colorless crystals of ThSiO{sub 4} (huttonite) (1) and (Ca{sub 0.5}Na{sub 0.5}){sub 2}NaThSi{sub 8}O{sub 20} (2) have been synthesized by the solid-state reactions of ThO{sub 2}, CaSiO{sub 3}, and Na{sub 2}WO{sub 4} at 1073 K. Green crystals of (Ca{sub 0.5}Na{sub 0.5}){sub 2}NaUSi{sub 8}O{sub 20} (3) have been synthesized by the solid-state reactions of UO{sub 2}, CaSiO{sub 3}, and Na{sub 2}WO{sub 4} at 1003 K. All three compounds have been characterized by single-crystal X-ray diffraction. Compound 1 adopts a monazite-type three-dimensional condensed structure, which is built from edge- and corner-shared ThO{sub 9} polyhedra and SiO{sub 4} tetrahedra. Compounds 2 and 3 are isostructural and they crystallize in a steacyite-type structure. The structure consists of discrete pseudocubic [Si{sub 8}O{sub 20}]{sup 8−} polyanions, which are connected by An{sup 4+} cations into a three-dimensional framework. Each An atom coordinates to eight monodentate [Si{sub 8}O{sub 20}]{sup 8−} moieties in a square antiprismatic geometry. Na{sup +} and Ca{sup 2+} ions reside in the void within the framework. Raman spectra of 1, 2, and 3 were collected on single crystal samples. 1 displays more complex vibrational bands than thorite. Raman spectra of 2 and 3 are analogous with most of vibrational bands located at almost the same regions. - Graphical abstract: A Raman spectrum and crystal structures of (Ca{sub 0.5}Na{sub 0.5}){sub 2}NaAnSi{sub 8}O{sub 20} (An=Th, U), which contain pseudocubic [Si{sub 8}O{sub 20}]{sup 8−} polyanions and eight-coordinate An{sup 4+} cations. - Highlights: • Single crystal growth of three tetravalent actinide silicates from melts. • Single-crystal structures and Raman spectra of (Ca{sub 0.5}Na{sub 0.5}){sub 2}NaAnSi{sub 8}O{sub 20} (An=Th, U). • First report of Raman spectrum of huttonite on single crystal samples.

      14. Importance of hydrophobic traps for proton diffusion in lyotropic liquid crystals

        DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

        McDaniel, Jesse G.; Yethiraj, Arun

        2016-03-04

        The diffusion of protons in self-assembled systems is potentially important for the design of efficient proton exchange membranes. In this work, we study proton dynamics in a low-water content, lamellar phase of an sodium-carboxylate gemini surfactant/water system using computer simulations. The hopping of protons via the Grotthuss mechanism is explicity allowed through the multi-state empirical valence bond (MS-EVB) method. We find that the hydronium ion is trapped on the hydrophobic side of the surfactant-water interface, and proton diffusion then proceeds by hopping between surface sites. The importance of hydrophobic traps is surprising, because one would expect the hydronium ions tomore » be trapped at the charged head-groups. Finally, the physics illustrated in this system should be relevant to the proton dynamics in other amphiphilic membrane systems, whenever there exists exposed hydrophobic surface regions.« less

      15. Nanostructures of Liquid Crystal Phases in Mixtures of Bent-core and Rod-shaped Molecules

        SciTech Connect (OSTI)

        S Hong; R Verduzco; J Gleeson; S Sprunt; A Jakli

        2011-12-31

        We report small angle x-ray scattering (SAXS) studies of isotropic, nematic, and smectic mesophases formed by binary mixtures of bent-core (BC) and rod-shaped (RS) molecules. While optical studies indicate that the components are fully miscible, SAXS reveals fascinating structures that are consistent with segregation on a nanoscopic scale. We find that tilted smectic clusters, which have been previously reported in both the nematic and isotropic states of the pure BC materials, are also present in mixtures with up to 50 wt% of the RS compound; this is consistent with previous dielectric and flexoelectric studies on such mixtures. Unexpectedly in this concentration range the clusters are present in the isotropic and in the induced smectic phase range, as well as throughout the nematic phase. The results in the smectic phase also reveal complex layering phenomena, providing important insight into the interaction between bent and rod-shaped molecules. These studies will be crucial in the design of promising new functional nanomaterials.

      16. Nanostructures of liquid crystal phases in mixtures of bent-core and rod-shaped molecules

        SciTech Connect (OSTI)

        Hong, S. H.; Gleeson, J. T.; Sprunt, S.; Verduzco, R.; Jakli, A.

        2011-06-15

        We report small angle x-ray scattering (SAXS) studies of isotropic, nematic, and smectic mesophases formed by binary mixtures of bent-core (BC) and rod-shaped (RS) molecules. While optical studies indicate that the components are fully miscible, SAXS reveals fascinating structures that are consistent with segregation on a nanoscopic scale. We find that tilted smectic clusters, which have been previously reported in both the nematic and isotropic states of the pure BC materials, are also present in mixtures with up to 50 wt% of the RS compound; this is consistent with previous dielectric and flexoelectric studies on such mixtures. Unexpectedly in this concentration range the clusters are present in the isotropic and in the induced smectic phase range, as well as throughout the nematic phase. The results in the smectic phase also reveal complex layering phenomena, providing important insight into the interaction between bent and rod-shaped molecules. These studies will be crucial in the design of promising new functional nanomaterials.

      17. Early Career: Templating of Liquid Crystal Microstructures by Reversible Addition-Fragmentation Chain Transfer Polymerization

        SciTech Connect (OSTI)

        Heinen, Jennifer M

        2014-12-31

        This research has shown that the microstructure of self-assembled copolymers can be decoupled from the polymer chemistry. The simplest polymer architecture, linear block copolymers, is valuable for a broad range of applications, including adhesives and coatings, medical devices, electronics and energy storage, because these block copolymers reproducibly self-assemble into microphase separated nanoscale domains. Unfortunately, the self-assembled microstructure is tuned by polymer composition, thus limiting the potential to simultaneously optimize chemical, mechanical, and transport properties for desired applications. To this end, much work was been put into manipulating block copolymer self-assembly independently of polymer composition. These efforts have included the use of additives or solvents to alter polymer chain conformation, the addition of a third monomer to produce ABC triblock terpolymers, architectures with mixed blocks, such as tapered/gradient polymers, and the synthesis of other nonlinear molecular architectures. This work has shown that the microstructures formed by linear ABC terpolymers can be altered by controlling the architecture of the polymer molecules at a constant monomer composition, so that the microstructure is tuned independently from the chemical properties.

      18. Simultaneous sensing of light and sound velocities of fluids in a two-dimensional phoXonic crystal with defects

        SciTech Connect (OSTI)

        Amoudache, Samira; Pennec, Yan Djafari Rouhani, Bahram; Khater, Antoine; Lucklum, Ralf; Tigrine, Rachid

        2014-04-07

        We theoretically investigate the potentiality of dual phononic-photonic (the so-called phoxonic) crystals for liquid sensing applications. We study the transmission through a two-dimensional (2D) crystal made of infinite cylindrical holes in a silicon substrate, where one row of holes oriented perpendicular to the propagation direction is filled with a liquid. The infiltrated holes may have a different radius than the regular holes. We show, in the defect structure, the existence of well-defined features (peaks or dips) in the transmission spectra of acoustic and optical waves and estimate their sensitivity to the sound and light velocity of the analyte. Some of the geometrical requirements behave in opposite directions when searching for an efficient sensing of either sound or light velocities. Hence, a compromise in the choice of the parameters may become necessary in making the phoxonic sensor.

      19. Method for enhanced atomization of liquids

        DOE Patents [OSTI]

        Thompson, Richard E.; White, Jerome R.

        1993-01-01

        In a process for atomizing a slurry or liquid process stream in which a slurry or liquid is passed through a nozzle to provide a primary atomized process stream, an improvement which comprises subjecting the liquid or slurry process stream to microwave energy as the liquid or slurry process stream exits the nozzle, wherein sufficient microwave heating is provided to flash vaporize the primary atomized process stream.

      20. Nanoparticle enhanced ionic liquid heat transfer fluids

        DOE Patents [OSTI]

        Fox, Elise B.; Visser, Ann E.; Bridges, Nicholas J.; Gray, Joshua R.; Garcia-Diaz, Brenda L.

        2014-08-12

        A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.