National Library of Energy BETA

Sample records for liquefiable hydrocarbon portion

  1. Moving hydrocarbons through portions of tar sands formations with a fluid

    DOE Patents [OSTI]

    Stegemeier, George Leo; Mudunuri, Ramesh Raju; Vinegar, Harold J.; Karanikas, John Michael; Jaiswal, Namit; Mo, Weijian

    2010-05-18

    A method for treating a tar sands formation is disclosed. The method includes heating a first portion of a hydrocarbon layer in the formation from one or more heaters located in the first portion. The heat is controlled to increase a fluid injectivity of the first portion. A drive fluid and/or an oxidizing fluid is injected and/or created in the first portion to cause at least some hydrocarbons to move from a second portion of the hydrocarbon layer to a third portion of the hydrocarbon layer. The second portion is between the first portion and the third portion. The first, second, and third portions are horizontally displaced from each other. The third portion is heated from one or more heaters located in the third portion. Hydrocarbons are produced from the third portion of the formation. The hydrocarbons include at least some hydrocarbons from the second portion of the formation.

  2. Method and apparatus for pressurizing a liquefied gas

    DOE Patents [OSTI]

    Bingham, Dennis N.

    2005-07-26

    Apparatus providing at least one thermoelectric device for pressurizing a liquefied gas container and methods employing same are disclosed. A thermoelectric device including a heating surface and a cooling surface is used for pressurizing a container by vaporizing liquefied gas within the container by transferring heat energy from a portion of the liquefied gas in contact with the cooling surface to another portion of the liquefied gas in contact with the heating surface of the thermoelectric device to convert some of the liquefied gas to a vapor state. Liquefied gas vapor and/or liquid phase may be supplied by disclosed apparatus and methods. The apparatus may also be used as a vapor pump or a liquid pump, or fluid pump. Methods of operation are also disclosed.

  3. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.W.

    1995-06-01

    In collaboration with Cryenco Inc. and NIST-Boulder, we intend to develop a natural gas-powered natural-gas liquefier which has absolutely no moving parts and requires no electrical power. It will have high efficiency, remarkable reliability, and low cost. Progress on the liquefier to be constructed at Cryenco continues satisfactorily. The thermoacoustic driver is still ahead of the pulse tube refrigerator, because of NIST`s schedule. We completed the thermoacoustics design in the fall of 1994, with Los Alamos providing physics input and checks of all aspects, and Cryenco providing engineering to ASME code, drafting, etc. Completion of this design represents a significant amount of work, especially in view of the many unexpected problems encountered. Meanwhile, Cryenco and NIST have almost completed the design of the pulse tube refrigerator. At Los Alamos, we have assembled a half-size scale model of the thermoacoustic portion of the 500 gal/day TANGL. This scale model will enable easy experimentation in harmonic suppression techniques, new stack geometries, new heat-exchanger geometries, resonator coiling, and other areas. As of March 1995, the scale model is complete and we are performing routine debugging tests and modifications.

  4. Recovering hydrocarbons from hydrocarbon-containing vapors

    DOE Patents [OSTI]

    Mirza, Zia I. (La Verne, CA); Knell, Everett W. (Los Alamitos, CA); Winter, Bruce L. (Danville, CA)

    1980-09-30

    Values are recovered from a hydrocarbon-containing vapor by contacting the vapor with quench liquid consisting essentially of hydrocarbons to form a condensate and a vapor residue, the condensate and quench fluid forming a combined liquid stream. The combined liquid stream is mixed with a viscosity-lowering liquid to form a mixed liquid having a viscosity lower than the viscosity of the combined liquid stream to permit easy handling of the combined liquid stream. The quench liquid is a cooled portion of the mixed liquid. Viscosity-lowering liquid is separated from a portion of the mixed liquid and cycled to form additional mixed liquid.

  5. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.; Gardner, D.; Hayden, M.; Radebaugh, R.; Wollan, J.

    1996-07-01

    This is the final report of a two-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project sought to develop a natural-gas-powered natural-gas liquefier that has absolutely no moving parts and requires no electrical power. It should have high efficiency, remarkable reliability, and low cost. The thermoacoustic natural-gas liquefier (TANGL) is based on our recent invention of the first no-moving-parts cryogenic refrigerator. In short, our invention uses acoustic phenomena to produce refrigeration from heat, with no moving parts. The required apparatus comprises nothing more than heat exchangers and pipes, made of common materials, without exacting tolerances. Its initial experimental success in a small size lead us to propose a more ambitious application: large-energy liquefaction of natural gas, using combustion of natural gas as the energy source. TANGL was designed to be maintenance-free, inexpensive, portable, and environmentally benign.

  6. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.W.

    1997-05-01

    Cryenco and Los Alamos are collaborating to develop a natural-gas-powered natural-gas liquefier that will have no moving parts and require no electrical power. It will have useful efficiency, remarkable reliability, and low cost. The liquefaction of natural gas, which occurs at only 115 Kelvin at atmospheric pressure, has previously required rather sophisticated refrigeration machinery. The 1990 invention of the thermoacoustically driven orifice pulse-tube refrigerator (TA-DOPTR) provides cryogenic refrigeration with no moving parts for the first time. In short, this invention uses acoustic phenomena to produce refrigeration from heat. The required apparatus consists of nothing more than helium-filled heat exchangers and pipes, made of common materials, without exacting tolerances. In the Cryenco-Los Alamos collaboration, the authors are developing a version of this invention suitable for use in the natural-gas industry. The project is known as acoustic liquefier for short. The present program plans call for a two-phase development. Phase 1, with capacity of 500 gallon per day (i.e., approximately 40,000 scfd, requiring a refrigeration power of about 7 kW), is large enough to illuminate all the issues of large-scale acoustic liquefaction without undue cost, and to demonstrate the liquefaction of 60--70% of input gas, while burning 30--40%. Phase 2 will target versions of approximately 10{sup 6} scfd = 10,000 gallon per day capacity. In parallel with both, they continue fundamental research on the technology, directed toward increased efficiency, to build scientific foundations and a patent portfolio for future acoustic liquefiers.

  7. Cogeneration systems and processes for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

    2009-12-29

    A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

  8. Hydrocarbon conversion

    SciTech Connect (OSTI)

    Koepke, J.W.; Abdo, S.F.

    1989-10-03

    This patent describes a hydrocracking process. It comprises: catalyzing a hydrocracking reaction by contacting a hydrocarbon feedstock with a hydrocracking catalyst under hydrocracking conditions to produce a product hydrocarbon having an increased octane number than the hydrocarbon feedstock. The hydrocracking catalyst consists essentially of at least one niobium component, at least one Group VIII metal component and at least one cracking component.

  9. LIQUEFIED NATURAL GAS IN CALIFORNIA

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION LIQUEFIED NATURAL GAS IN CALIFORNIA: HISTORY, RISKS, AND SITING Tyler Contributors Dave Maul Manager NATURAL GAS & SPECIAL PROJECTS OFFICE Terrence O'Brien, Deputy Commissioner and Leader of the Governor's Natural Gas Working Group #12;This paper was prepared as the result

  10. Urban leakage of liquefied petroleum gas and its impact on Mexico City air quality

    SciTech Connect (OSTI)

    Blake, D.R.; Rowland, F.S.

    1995-08-18

    Alkane hydrocarbons (propane, isobutane, and n-butane) from liquefied petroleum gas (LPG) are present in major quantities throughout Mexico City air because of leakage of the unburned gas from numerous urban sources. These hydrocarbons, together with olefinic minor LPG components, furnish substantial amounts of hydroxyl radical reactivity, a major precursor to formation of the ozone component of urban smog. The combined processes of unburned leakage and incomplete combustion of LPG play significant role in causing the excessive ozone characteristic of Mexico City. Reductions in ozone levels should be possible through changes in LPG composition and lowered rates of leakage. 23 refs., 3 tabs.

  11. Energy Department Authorizes Freeport LNG to Export Liquefied...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department Authorizes Freeport LNG to Export Liquefied Natural Gas Energy Department Authorizes Freeport LNG to Export Liquefied Natural Gas November 14, 2014 - 2:00pm Addthis News...

  12. Method for making hydrogen rich gas from hydrocarbon fuel

    DOE Patents [OSTI]

    Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

    1999-01-01

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

  13. Method for making hydrogen rich gas from hydrocarbon fuel

    DOE Patents [OSTI]

    Krumpelt, M.; Ahmed, S.; Kumar, R.; Doshi, R.

    1999-07-27

    A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400 C for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide. 4 figs.

  14. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2015-06-09

    A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

  15. Time sequenced heating of multiple layers in a hydrocarbon containing formation

    DOE Patents [OSTI]

    Goldberg, Bernard (Houston, TX); Hale, Arthur Herman (Houston, TX); Miller, David Scott (Katy, TX); Vinegar, Harold J. (Bellaire, TX)

    2009-12-22

    A method for treating a hydrocarbon containing formation may include providing heat to a first hydrocarbon layer in the formation from a first heater located in an opening in the formation. The opening and the first heater may have a horizontal or inclined portion located in the first hydrocarbon layer and at least one connecting portion extending between the horizontal or inclined portion and the surface. Isolation material is placed in the opening such that the isolation material partially isolates the layer in which the horizontal or inclined portion of the first heater is located. An additional horizontal or inclined opening portion that extends from at least one of the connecting portions of the opening is formed in a second hydrocarbon layer. A second heater to provide heat the second hydrocarbon formation is placed in the additional substantially horizontal opening portion.

  16. Apparatus for hydrocarbon extraction

    DOE Patents [OSTI]

    Bohnert, George W.; Verhulst, Galen G.

    2013-03-19

    Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

  17. Global Liquefied Natural Gas Market: Status and Outlook, The

    Reports and Publications (EIA)

    2003-01-01

    The Global Liquefied Natural Gas Market: Status & Outlook was undertaken to characterize the global liquefied natural gas (LNG) market and to examine recent trends and future prospects in the LNG market.

  18. Capturing, Purifying, and Liquefying Landfill Gas for Transportation Fuel

    E-Print Network [OSTI]

    landfill biomethane to liquefied natural gas for use as transportation fuel. The aim is to develop, and liquefaction of biomethane. The resulting liquefied natural gas will consist of cryogenically liquefied. This project will also serve as a model for similar facilities in California to use native biogas resources

  19. Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates

    DOE Patents [OSTI]

    Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

    1981-02-19

    A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

  20. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  1. Using geothermal energy to heat a portion of a formation for an in situ heat treatment process

    DOE Patents [OSTI]

    Pieterson, Roelof; Boyles, Joseph Michael; Diebold, Peter Ulrich

    2010-06-08

    Methods of using geothermal energy to treat subsurface formations are described herein. Methods for using geothermal energy to treat a subsurface treatment area containing or proximate to hydrocarbons may include producing geothermally heated fluid from at least one subsurface region. Heat from at least a portion of the geothermally heated fluid may be transferred to the subsurface treatment area to heat the subsurface treatment area. At least some hydrocarbon fluids may be produced from the formation.

  2. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01

    LBL-8596 itr-t C,d.. HYDROCARBONS & ENERGY FROM PLANTS jmethods of isolating the hydrocarbon-like material from I.privatelyownedrights. HYDROCARBONS AND ENERGY FROM PLANTS

  3. Solution mining and heating by oxidation for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Stegemeier, George Leo (Houston, TX)

    2009-06-23

    A method for treating an oil shale formation comprising nahcolite includes providing a first fluid to a portion of the formation. A second fluid is produced from the portion. The second fluid includes at least some nahcolite dissolved in the first fluid. A controlled amount of oxidant is provided to the portion of the formation. Hydrocarbon fluids are produced from the formation.

  4. Impacts of Imported Liquefied Natural Gas on Residential Appliance Components: Literature Review

    E-Print Network [OSTI]

    Lekov, Alex

    2010-01-01

    Gas Quality and Liquefied Natural Gas Research Study. LosGas Quality and Liquefied Natural Gas Research Study. LosGas Quality and Liquefied Natural Gas Research Study. Los

  5. Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device

    DOE Patents [OSTI]

    Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

    2014-05-06

    A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

  6. Impacts of Imported Liquefied Natural Gas on Residential Appliance Components: Literature Review

    E-Print Network [OSTI]

    Lekov, Alex

    2010-01-01

    impacted by a shift in natural gas quality. Fuel/Air Mixtureal. (2005). Gas Quality and Liquefied Natural Gas Researchal. (2005). Gas Quality and Liquefied Natural Gas Research

  7. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Sinclair, B.W.

    1984-07-31

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a wellhead; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; separating LPG from gas vapors of the refrigerated natural gas; storing the separated LPG in a storage tank with a vapor space therein; and recirculating a portion of the LPG vapors in the storage tank with the natural gas exiting the wellhead to enhance recovery of LPG. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for refrigerating the compressed gases therefrom; at least one product separator downstream of the refrigerator unit for receiving refrigerated and compressed gases discharged from the refrigerator unit and separating LPG therein from gases remaining in vapor form; and a storage tank for receiving and storing the separated LPG therein, the storage tank having a vapor space therein connected upstream of the gas compressor through a pressure regulator allowing recirculation of some LPG vapors with the natural gases through said system.

  8. Safety issues relating to the liquefied petroleum gas, compressed natural gas and liquefied natural gas

    SciTech Connect (OSTI)

    Petru, T.D.

    1995-12-31

    The Railroad Commission of Texas, LP-Gas Division, is statutorily responsible for the safety aspects of liquefied petroleum gas (LPG) most commonly known as LP-gas or propane, compressed natural gas (CNG) and liquefied natural gas (LNG). This presentation will address the safety issues relating to their use as alternative fuels. The paper discusses the safety of pressure vessels used for storage of the fuels at refueling facilities and the containers mounted in vehicles. Other topics include the lack of odorants in LNG, the use of protective clothing when handling cryogenic fluids, and where to obtain a copy of the safety regulations for handling these three fuels.

  9. Hydrocarbon-enhanced particulate filter regeneration via microwave ignition

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

    2010-02-02

    A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

  10. Texas Bi-Fuel Liquefied Petroleum Gas Pickup Study: Final Report

    SciTech Connect (OSTI)

    Huang, Y.; Matthews, R. D.; Popova, E. T.

    1999-05-24

    Alternative fuels may be an effective means for decreasing America's dependence on imported oil; creating new jobs; and reducing emissions of greenhouse gases, exhaust toxics, and ozone-forming hydrocarbons. However, data regarding in-use fuel economy and maintenance characteristics of alternative fuel vehicles (AFVs) have been limited in availability. This study was undertaken to compare the operating and maintenance characteristics of bi-fuel vehicles (which use liquefied petroleum gas, or propane, as the primary fuel) to those of nominally identical gasoline vehicles. In Texas, liquefied petroleum gas is one of the most widely used alternative fuels. The largest fleet in Texas, operated by the Texas Department of Transportation (TxDOT), has hundred of bi-fuel (LPG and gasoline) vehicles operating in normal daily service. The project was conducted over a 2-year period, including 18 months (April 1997-September 1998) of data collection on operations, maintenance, and fuel consumption of the vehicles under study. This report summarizes the project and its results.

  11. Hydrocarbon in Catalyst in

    E-Print Network [OSTI]

    Ladkin, Peter B.

    #12;Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure controller Computer;#12;Vent 1 Vent 2 Product outHydrocarbon in Steam in Catalyst in light Warning Computer controller Tank

  12. Hydrocarbon in Catalyst in

    E-Print Network [OSTI]

    Ladkin, Peter B.

    Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure #12;#12;#12;#12;#12;#12;#12;#12;Hydrocarbon in Steam in Catalyst in Vent 1 Vent 2 Product out Tank Pressure controller Computer operator

  13. NATURAL MARINE HYDROCARBON SEEPAGE

    E-Print Network [OSTI]

    Luyendyk, Bruce

    oil and gas (Fischer, 1977).The offshore gaseous seepage is controlled Geology; November 1999; v. 27; no. 11; p. 1047­1050; 4 figures. 1047 Decrease in natural marine hydrocarbon seepage near Coal OilNATURAL MARINE HYDROCARBON SEEPAGE Hydrocarbon seepage from the world's conti- nental shelves

  14. 2, 16451664, 2005 Hydrocarbon

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 2, 1645­1664, 2005 Hydrocarbon emissions from a boreal fen S. Haapanala et al. Title Page Discussions is the access reviewed discussion forum of Biogeosciences Measurements of hydrocarbon emissions Hydrocarbon emissions from a boreal fen S. Haapanala et al. Title Page Abstract Introduction Conclusions

  15. Is cyclobutane a hydrocarbon?

    E-Print Network [OSTI]

    Martin, Ralph R.

    Is cyclobutane a hydrocarbon? Biologically interesting entities possibly > 1,000,000 Does cyclobutane have a four- membered ring? Is cyclobutane a hydrocarbon? Expressive and decidable formalism needs to be classified under chemical classes: Is dinitrogen inorganic? Is acetylene a hydrocarbon

  16. Anaerobic Hydrocarbon Degradation in

    E-Print Network [OSTI]

    Bruns, Tom

    Anaerobic Hydrocarbon Degradation in Petroleum-Contaminated Harbor Sediments under Sulfate of iron(III) oxide to stimulate in- situ hydrocarbon degradation in anaerobic petroleum- contaminated did not stimulate anaerobic hydrocarbon oxidation. Exposure of the sediment to air [to reoxidize Fe

  17. Heating hydrocarbon containing formations in a line drive staged process

    DOE Patents [OSTI]

    Miller, David Scott (Katy, TX)

    2009-07-21

    Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

  18. Liquefied Natural Gas for Trucks and Buses

    SciTech Connect (OSTI)

    James Wegrzyn; Michael Gurevich

    2000-06-19

    Liquefied natural gas (LNG) is being developed as a heavy vehicle fuel. The reason for developing LNG is to reduce our dependency on imported oil by eliminating technical and costs barriers associated with its usage. The U.S. Department of Energy (DOE) has a program, currently in its third year, to develop and advance cost-effective technologies for operating and refueling natural gas-fueled heavy vehicles (Class 7-8 trucks). The objectives of the DOE Natural Gas Vehicle Systems Program are to achieve market penetration by reducing vehicle conversion and fuel costs, to increase consumer acceptance by improving the reliability and efficiency, and to improve air quality by reducing tailpipe emissions. One way to reduce fuel costs is to develop new supplies of cheap natural gas. Significant progress is being made towards developing more energy-efficient, low-cost, small-scale natural gas liquefiers for exploiting alternative sources of natural gas such as from landfill and remote gas sites. In particular, the DOE program provides funds for research and development in the areas of; natural gas clean up, LNG production, advanced vehicle onboard storage tanks, improved fuel delivery systems and LNG market strategies. In general, the program seeks to integrate the individual components being developed into complete systems, and then demonstrate the technology to establish technical and economic feasibility. The paper also reviews the importance of cryogenics in designing LNG fuel delivery systems.

  19. Conceptual Liquefied Natural Gas (LNG) terminal design for Kuwait 

    E-Print Network [OSTI]

    Aljeeran, Fares

    2006-08-16

    This research study investigated a new conceptual design for a modular structural configuration incorporating storage for Liquefied Natural Gas (LNG) within the base of the platform structure. The structure, referred to as a modified gravity base...

  20. Freeport, TX Liquefied Natural Gas Exports to Mexico (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Mexico (Million Cubic Feet) Freeport, TX Liquefied Natural Gas Exports to Mexico (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 2,725 - No Data...

  1. An economic analysis of Floating Liquefied Natural Gas (FLNG)

    E-Print Network [OSTI]

    Marmolejo, Phillip Christian

    2014-01-01

    This report includes a discussion of the potential production of stranded natural gas reserves through the implementation of Floating Liquefied Natural Gas (FLNG) in a world of growing energy demand followed by an analysis ...

  2. The liquefied natural gas pipeline: a system study 

    E-Print Network [OSTI]

    Hazel, Thomas Ray

    1972-01-01

    THE LIQUEFIED NATURAL GAS PIPELINE: A SYSTEM STUDY A Thesis by THOMAS RAY HAZEL Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1972 Major Subject...: Mechanical Engineering THE LIQUEFIED NATURAL GAS PIPELINE: A SYSTEM STUDY A Thesis by THOMAS RAY HAZEL Approved as to style and content by: Chairman o 'Committee) (Head of Department) (Member) (Member) (Member) (Member) (Member) May 1972 ABSTRACT...

  3. Urban leakage of liquefied petroleum gas and its potential impact of Mexico City air quality

    SciTech Connect (OSTI)

    Blake, D.R.; Rowland, F.S.

    1995-12-01

    Seventy eight whole air samples were collected at various park locations throughout Mexico City and later assayed for methane, carbon monoxide, 20 halocarbons and 40 C{sub 2}-C{sub 10} hydrocarbons. Propane had the highest median mixing ratio value of all assayed non-methane hydrocarbon compounds (NMHCs) with a concentration as high as 0.1 ppmv. The concentration of n-butane, i-butane, n-pentane and i-pentane were all notably elevated as well. The only significant identified source of propane in Mexico City is liquefied petroleum gas (LPG), which also has a strong component of C{sub 4} and C{sub 5} alkanes. All of these alkanes were present at concentrations well above those observed in other cities where LPG is not the main domestic fuel. Data strongly suggest that as much as 50% of total Mexico City NMHCs is a result of losses associated with the transfer, storage and delivery of LPG. Additionally, using median concentrations and laboratory determined hydroxyl reaction rate constants, LPG emissions account for about 20% of initial reactivities. This suggests that LPG losses may significantly impact photochemical oxidant levels in Mexico City.

  4. Engineering Chlorinated hydrocarbons such as

    E-Print Network [OSTI]

    Chemical Engineering Abstract Chlorinated hydrocarbons such as trichloroethylene (TCE) form a class carriers/supports for NZVI particles to address the in situ remediation of chlorinated hydrocarbons. We

  5. Development of a thermoacoustic natural gas liquefier.

    SciTech Connect (OSTI)

    Wollan, J. J.; Swift, G. W.; Backhaus, S. N.; Gardner, D. L.

    2002-01-01

    Praxair, in conjunction with the Los Alamos National Laboratory, is developing a new technology, thermoacoustic heat engines and refrigerators, for liquefaction of natural gas. This is the only technology capable of producing refrigeration power at cryogenic temperatures with no moving parts. A prototype, with a projected natural gas liquefaction capacity of 500 gallons/day, has been built and tested. The power source is a natural gas burner. Systems will be developed with liquefaction capacities up to 10,000 to 20,000 gallons per day. The technology, the development project, accomplishments and applications are discussed. In February 2001 Praxair, Inc. purchased the acoustic heat engine and refrigeration development program from Chart Industries. Chart (formerly Cryenco, which Chart purchased in 1997) and Los Alamos had been working on the technology development program since 1994. The purchase included assets and intellectual property rights for thermoacoustically driven orifice pulse tube refrigerators (TADOPTR), a new and revolutionary Thermoacoustic Stirling Heat Engine (TASHE) technology, aspects of Orifice Pulse Tube Refrigeration (OPTR) and linear motor compressors as OPTR drivers. Praxair, in cooperation with Los Alamos National Laboratory (LANL), the licensor of the TADOPTR and TASHE patents, is continuing the development of TASHE-OPTR natural gas powered, natural gas liquefiers. The liquefaction of natural gas, which occurs at -161 C (-259 F) at atmospheric pressure, has previously required rather sophisticated refrigeration machinery. The 1990 TADOPTR invention by Drs. Greg Swift (LANL) and Ray Radebaugh (NIST) demonstrated the first technology to produce cryogenic refrigeration with no moving parts. Thermoacoustic engines and refrigerators use acoustic phenomena to produce refrigeration from heat. The basic driver and refrigerator consist of nothing more than helium-filled heat exchangers and pipes, made of common materials, without exacting tolerances. The liquefier development program is divided into two components: Thermoacoustically driven refrigerators and linear motor driven refrigerators (LOPTRs). LOPTR technology will, for the foreseeable future, be limited to natural gas liquefaction capacities on the order of hundreds of gallons per day. TASHE-OPTR technology is expected to achieve liquefaction capacities of tens of thousands of gallons per day. This paper will focus on the TASHE-OPTR technology because its natural gas liquefaction capacity has greater market opportunity. LOPTR development will be mentioned briefly. The thermoacoustically driven refrigerator development program is now in the process of demonstrating the technology at a capacity of about 500 gallon/day (gpd) i.e., approximately 42,000 standard cubic feet/day, which requires about 7 kW of refrigeration power. This capacity is big enough to illuminate the issues of large-scale acoustic liquefaction at reasonable cost and to demonstrate the liquefaction of about 70% of an input gas stream, while burning about 30%. Subsequent to this demonstration a system with a capacity of approximately 10{sup 6} standard cubic feet/day (scfd) = 10,000 gpd with a projected liquefaction rate of about 85% of the input gas stream will be developed. When commercialized, the TASHE-OPTRs will be a totally new type of heat-driven cryogenic refrigerator, with projected low manufacturing cost, high reliability, long life, and low maintenance. A TASHE-OPTR will be able to liquefy a broad range of gases, one of the most important being natural gas (NG). Potential NG applications range from distributed liquefaction of pipeline gas as fuel for heavy-duty fleet and long haul vehicles to large-scale liquefaction at on-shore and offshore gas wellheads. An alternative to the thermoacoustic driver, but with many similar technical and market advantages, is the linear motor compressor. Linear motors convert electrical power directly into oscillating linear, or axial, motion. Attachment of a piston to the oscillator results in a direct drive compressor. Such a compressor

  6. Plasma Processing Of Hydrocarbon

    SciTech Connect (OSTI)

    Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

    2007-05-01

    The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

  7. Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues

    Reports and Publications (EIA)

    2014-01-01

    Over the past five years, rapid growth in U.S. onshore natural gas and oil production has led to increased volumes of natural gas plant liquids (NGPL) and liquefied refinery gases (LRG). The increasing economic importance of these volumes, as a result of their significant growth in production, has revealed the need for better data accuracy and transparency to improve the quality of historical data and projections for supply, demand, and prices of these liquids, co-products, and competing products. To reduce confusion in terminology and improve its presentation of data, EIA has worked with industry and federal and state governments to clarify gas liquid terminology and has developed the term Hydrocarbon Gas Liquids, or HGL.

  8. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  9. Relocation and freezing of liquefied fuel-rod material. [PWR

    SciTech Connect (OSTI)

    Moore, R.L.; Broughton, J.M.

    1982-01-01

    Severe degraded core cooling accidents, such as occurred at TMI-2 can potentially reach temperatures in excess of cladding melting. When the molten cladding is in contact with UO/sub 2/ fuel, the UO/sub 2/ will be dissolved contributing significantly to the total amount of liquefied material flowing down the rod and eventually freezing in a lower, cooler region of the core. The primary objectives of this paper are to evaluate the relocation and freezing characteristics of liquefied fuel rod material over a wide range of system conditions, physical characteristics of the fuel rod and liquefied material, and material thermo-physical properties to determine the relative influence of the controlling parameters. First the analytical model used in the analysis is briefly reviewed. The results of the analyses are then presented and discussed, and this is followed by the conclusions.

  10. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Funk, Edward W. (Highland Park, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Des Plaines, IL)

    1986-01-01

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture over a polymeric membrane which comprises a polymer capable of maintaining its integrity in the presence of hydrocarbon compounds at temperature ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psi. The membranes which possess pore sizes ranging from about 10 to about 500 Angstroms are cast from a solvent solution and recovered.

  11. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    molecular weights of various hydrocarbon materials for fuelof oil and alcohol from hydrocarbon-producing plants. Into Die Naturwissenschaften HYDROCARBONS FROM PLANTS: METHODS

  12. Secondary Organic Aerosol Formation From Aromatic Hydrocarbon

    E-Print Network [OSTI]

    Tang, Ping

    2013-01-01

    Jimenez, J.L. , 2005. Hydrocarbon- like and oxygenatedoxidation of aromatic hydrocarbons in the presence of drySummary of aromatic hydrocarbon photooxidation experiments

  13. Process for removing carbonyl sulfide from hydrocarbon feedstreams

    SciTech Connect (OSTI)

    Holmes, E.S.; Kosseim, A.J.

    1992-04-14

    This patent describes a process for removing carbon dioxide, hydrogen sulfide and carbonyl sulfide from a feedstream containing carbon dioxide, hydrogen sulfide and carbonyl sulfide and hydrocarbons. It comprises: contacting the feedstream in a hydrolysis zone with a first portion of a lean solution stream comprising an aqueous alkaline solution at an effective hydrolysis temperature to convert at least a portion of the carbonyl sulfide to carbon dioxide and hydrogen sulfide, withdrawing a first effluent stream containing a reduced concentration of carbonyl sulfide relative to the feedstream, and withdrawing a first rich solution stream comprising the aqueous alkaline solution, carbon dioxide and hydrogen sulfide; contacting the first effluent stream in an absorption zone with a second portion of the lean solution stream at an effective absorption temperature to absorb carbon dioxide and hydrogen sulfide, and withdrawing a second rich solution stream comprising the aqueous alkaline solution, carbon dioxide and hydrogen sulfide; combining at least a portion of the first rich solution stream and the second rich solution stream and contacting the combined rich solution stream in a regeneration zone at effective conditions to desorb carbon dioxide and hydrogen sulfide, withdrawing a vent gas stream comprising carbon dioxide and hydrogen sulfide, and withdrawing the lean solution stream; separating the lean solution stream into the first and second portions; and recycling the first portion of the lean solution stream to the hydrolysis zone and the second portion of the lean solution stream to the absorption zone.

  14. Visual Simulation of Offshore Liquefied Natural Gas (LNG) Terminals

    E-Print Network [OSTI]

    Visual Simulation of Offshore Liquefied Natural Gas (LNG) Terminals in a Decision-Making Context1 potential offshore Liquified Natural Gas (LNG) sites and the types of terminals that might occupy those sites. The study had to evaluate the engineering feasibility of siting an LNG receiving terminal

  15. In situ recovery from residually heated sections in a hydrocarbon containing formation

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Karanikas, John Michael (Houston, TX); Ryan, Robert Charles (Houston, TX)

    2010-12-14

    Methods of treating a tar sands formation is described herein. The methods may include providing heat to a first section of a hydrocarbon layer in the formation from a plurality of heaters located in the first section of the formation. Heat is transferred from the heaters so that at least a first section of the formation reaches a selected temperature. At least a portion of residual heat from the first section transfers from the first section to a second section of the formation. At least a portion of hydrocarbons in the second section are mobilized by providing a solvation fluid and/or a pressurizing fluid to the second section of the formation.

  16. Hydrocarbon Reservoir Parameter Estimation Using

    E-Print Network [OSTI]

    van Vliet, Lucas J.

    Hydrocarbon Reservoir Parameter Estimation Using Production Data and Time-Lapse Seismic #12;#12;Hydrocarbon Reservoir Parameter Estimation Using Production Data and Time-Lapse Seismic PROEFSCHRIFT ter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 Recovery process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.3 Field

  17. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop: Agenda and Objectives Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop:...

  18. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, R.L.

    1997-03-11

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  19. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1997-01-01

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  20. Methods of producing alkylated hydrocarbons from an in situ heat treatment process liquid

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria (Houston, TX); Mo, Weijian (Sugar Land, TX); Muylle, Michel Serge Marie (Houston, TX); Mandema, Remco Hugo (Houston, TX); Nair, Vijay (Katy, TX)

    2009-09-01

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation.

  1. Process for removal of carbonyl sulfide in liquified hydrocarbon gases with absorption of acid gases

    SciTech Connect (OSTI)

    Beavon, D.K.; Mackles, M.

    1980-11-11

    Liquified hydrocarbon gases containing at least carbonyl sulfide as an impurity are purified by intimately mixing the liquified hydrocarbon gas with an aqueous absorbent for hydrogen sulfide in a hydrolysis zone maintained at a temperature and a pressure sufficient to maintain the liquified hydrocarbon gas in the liquid state and hydrolyze the carbonyl sulfide to hydrogen sulfide and carbon dioxide. The liquified hydrocarbon gas containing at least a portion of the formed carbonyl sulfide and carbon dioxide is separated from the liquid absorbent and passed to an absorption zone where it is contacted with a liquid hydrogen sulfide absorbent where at least the formed hydrogen sulfide is separated from the liquified petroleum gas. A stage of absorption of at least hydrogen sulfide may proceed mixing of the liquified hydrocarbon gas with the absorbent in the hydrolysis reaction zone. The absorbent employed does not combine irreversibly with carbonyl sulfide, hydrogen sulfide, and carbon dioxide, and preferably is an aqueous solution of diethanolamine.

  2. Optrode for sensing hydrocarbons

    DOE Patents [OSTI]

    Miller, H.; Milanovich, F.P.; Hirschfeld, T.B.; Miller, F.S.

    1987-05-19

    A two-phase system employing the Fujiwara reaction is provided for the fluorometric detection of halogenated hydrocarbons. A fiber optic is utilized to illuminate a column of pyridine trapped in a capillary tube coaxially attached at one end to the illuminating end of the fiber optic. A strongly alkaline condition necessary for the reaction is maintained by providing a reservoir of alkali in contact with the column of pyridine, the surface of contact being adjacent to the illuminating end of the fiber optic. A semipermeable membrane caps the other end of the capillary tube, the membrane being preferentially permeable to the halogenated hydrocarbon but preferentially impermeable to water and pyridine. As the halogenated hydrocarbon diffuses through the membrane and into the column of pyridine, fluorescent reaction products are formed. Light propagated by the fiber optic from a light source, excites the fluorescent products. Light from the fluorescence emission is also collected by the same fiber optic and transmitted to a detector. The intensity of the fluorescence gives a measure of the concentration of the halogenated hydrocarbons. 6 figs.

  3. Hydrocarbonization research: completion report

    SciTech Connect (OSTI)

    Youngblood, E.L.; Cochran, H.D. Jr.; Westmoreland, P.R.; Brown, C.H. Jr.; Oswald, G.E.; Barker, R.E.

    1981-01-01

    Hydrocarbonization is a relatively simple process used for producing oil, substitute natural gas, and char by heating coal under a hydrogen-rich atmosphere. This report describes studies that were performed in a bench-scale hydrocarbonization system at Oak Ridge National Laboratory (ORNL) during the period 1975 to 1978. The results of mock-up studies, coal metering valve and flowmeter development, and supporting work in an atmospheric hydrocarbonization system are also described. Oil, gas, and char yields were determined by hydrocarbonization of coal in a 0.1-m-diam fluidized-bed reactor operated at a pressure of 2170 kPa and at temperatures ranging from 694 to 854 K. The nominal coal feed rate was 4.5 kg/h. Wyodak subbituminous coal was used for most of the experiments. A maximum oil yield of approx. 21% based on moisture- and ash-free (maf) coal was achieved in the temperature range of 810 to 840 K. Recirculating fluidized-bed, uniformly fluidized-bed, and rapid hydropyrolysis reactors were used. A series of operability tests was made with Illinois No. 6 coal to determine whether caking coal could be processed in the recirculating fluidized-bed reactor. These tests were generally unsuccessful because of agglomeration and caking problems; however, these problems were eliminated by the use of chemically pretreated coal. Hydrocarbonization experiments were carried out with Illinois No. 6 coal that had been pretreated with CaO-NaOH, Na/sub 2/CO/sub 3/, and CaO-Na/sub 2/CO/sub 3/. Oil yields of 14, 24, and 21%, respectively, were obtained from the runs with treated coal. Gas and char yield data and the composition of the oil, gas, and char products are presented.

  4. Hanford facility dangerous waste permit application, general information portion

    SciTech Connect (OSTI)

    Hays, C.B.

    1998-05-19

    The Hanford Facility Dangerous Waste Permit Application is considered to be a single application organized into a General Information Portion (document number DOE/RL-91-28) and a Unit-Specific Portion. Both the General Information and Unit-Specific portions of the Hanford Facility Dangerous Waste Permit Application address the content of the Part B permit application guidance prepared by the Washington State Department of Ecology (Ecology 1996) and the U.S. Environmental Protection Agency (40 Code of Federal Regulations 270), with additional information needed by the Hazardous and Solid Waste Amendments and revisions of Washington Administrative Code 173-303. Documentation contained in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units (e.g., the glossary provided in this report).

  5. Thermal hydrocracking of heavy hydrocarbon oils with heavy oil recycle

    SciTech Connect (OSTI)

    Denis, J.D.; Khulbe, C.P.; Pruden, B.B.

    1981-02-24

    An improved process is described for the hydrocracking of heavy hydrocarbon oils, such as oils extracted from tar sands. The heavy hydrocarbon oil feedstock in the presence of an excess of hydrogen is passed through a confined hydrocracking zone under upflow liquid conditions, and the effluent emerging from the top of the hydrocracking zone is passed into a hot separator where it is separated into a gaseous stream containing hydrogen and vaporous hydrocarbons and a liquid stream containing heavy hydrocarbons. The hot separator is maintained near the temperature of the hydrocracking zone and the effluent from the hydrocracking zone enters the separator in a lower region below the liquid level in the separator. The gaseous stream containing hydrogen and vaporous hydrocarbons is withdrawn from the top of the separator while a portion of the liquid phase in the separator is recycled to the hydrocracking zone without further treatment and in quantities sufficient to increase the superficial liquid flow velocity in the hydrocracking zone such that deposition of coke in the hydrocracking zone is substantially eliminated.

  6. Removal of carbonyl sulfide from liquid hydrocarbon streams

    SciTech Connect (OSTI)

    Damron, E.; Mick, M.B.; Woodall, R.M.

    1981-09-22

    Carbonyl sulfide is removed from propane and other similar liquefied petroleum gas products by mixing liquid methanol with the untreated liquefied gas and then contacting the liquid mixture with solid potassium hydroxide.

  7. Membrane separation of hydrocarbons

    DOE Patents [OSTI]

    Chang, Y. Alice (Des Plaines, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

    1986-01-01

    Mixtures of heavy oils and light hydrocarbons may be separated by passing the mixture through a polymeric membrane. The membrane which is utilized to effect the separation comprises a polymer which is capable of maintaining its integrity in the presence of hydrocarbon compounds and which has been modified by being subjected to the action of a sulfonating agent. Sulfonating agents which may be employed will include fuming sulfuric acid, chlorosulfonic acid, sulfur trioxide, etc., the surface or bulk modified polymer will contain a degree of sulfonation ranging from about 15 to about 50%. The separation process is effected at temperatures ranging from about ambient to about 100.degree. C. and pressures ranging from about 50 to about 1000 psig.

  8. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  9. Ambient aromatic hydrocarbon measurements at Welgegund, South Africa

    E-Print Network [OSTI]

    2014-01-01

    Ambient aromatic hydrocarbon measurements at Welgegund,Ambient aromatic hydrocarbon measurements at Welgegund,Ambient aromatic hydrocarbon measurements at Welgegund,

  10. HYDROCARBON FORMATION ON POLYMER-SUPPORTED COBALT

    E-Print Network [OSTI]

    Benner, Linda S.

    2013-01-01

    NV~ August 25-29, 1980 HYDROCARBON FORMATION ON POLYMER-catalyzed reduction of CO to hydrocarbons Tropscb. Among theof CO to saturated linear hydrocarbons and appears to retain

  11. Engineering Chlorinated hydrocarbons such as trichloroethylene

    E-Print Network [OSTI]

    Chemical Engineering Abstract Chlorinated hydrocarbons such as trichloroethylene (TCE) form a class carriers/supports for NZVI particles to address the in situ remediation of chlorinated hydrocarbons. We Remediation of Chlorinated Hydrocarbons Dr. Vijay John Department of Chemical & Biomolecular Engineering

  12. HYDROCARBON CONSTITUENTS OF ICELAND LEAF FOSSIL

    E-Print Network [OSTI]

    Han, Jerry; Calvin, Melvin.

    2008-01-01

    L.S. (1962) Isoprenoid hydrocarbons in petroleum. Anal.and EVANS E. D. (1965) Hydrocarbons in non-reservo; r-rockVI. Distribution of wax hydrocarbons in plants at different

  13. Simultaneous demetalization and hydrocracking of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Belinko, K.; Packwood, R.H.; Patmore, D.J.; Ranganathan, R.

    1983-03-15

    A process is described for the simultaneous demetalization and hydrocracking of heavy hydrocarbon oils. The process permits the recovery of metals such as vanadium and nickel in an economic manner by passing a slurry of a heavy hydrocarbon oil and carbonaceous additive particles, such as coal, in the presence of hydrogen through a confined vertical hydrocracking zone at high temperatures and pressures. A mixed effluent containing a gaseous phase and a liquid phase is removed from the top of a hydrocracking zone, while there is removed from the bottom of the hydrocracking zone a portion of the hydrocracking zone contents containing carbonaceous remains of the additive particles to which is adsorbed the metal residues from the feedstock. The effluent removed from the top of the hydrocracking zone can be subsequently fed directly to a catalytic hydrocracking unit.

  14. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop March 18, 2015 8:00AM EDT to...

  15. Biological Conversion of Sugars To Hydrocarbons | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biological Conversion of Sugars To Hydrocarbons Biological Conversion of Sugars To Hydrocarbons PDF explaining the biological process of bioenergy Biological Conversion of Sugars...

  16. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workshop held March 18-19, 2015. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production More Documents & Publications Enhanced Anaerobic Digestion and Hydrocarbon...

  17. Molecular catalytic hydrogenation of aromatic hydrocarbons and...

    Office of Scientific and Technical Information (OSTI)

    hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Citation Details In-Document Search Title: Molecular catalytic hydrogenation of aromatic hydrocarbons and...

  18. MULTIPHOTON DISSOCIATION PRODUCTS FROM HALOGENATED HYDROCARBONS

    E-Print Network [OSTI]

    Sudbo, Aa. S.

    2011-01-01

    FROM HALOGENATED HYDROCARBONS RECE1VED Aa. S. Sudbo, P. A.FROM HALOGENATED HYDROCARBONS LBL-6966 Aa. S. Sudbo, t P. A.

  19. Hydrocarbon sensors and materials therefor

    DOE Patents [OSTI]

    Pham, Ai Quoc (San Jose, CA); Glass, Robert S. (Livermore, CA)

    2000-01-01

    An electrochemical hydrocarbon sensor and materials for use in sensors. A suitable proton conducting electrolyte and catalytic materials have been found for specific application in the detection and measurement of non-methane hydrocarbons. The sensor comprises a proton conducting electrolyte sandwiched between two electrodes. At least one of the electrodes is covered with a hydrocarbon decomposition catalyst. Two different modes of operation for the hydrocarbon sensors can be used: equilibrium versus non-equilibrium measurements and differential catalytic. The sensor has particular application for on-board monitoring of automobile exhaust gases to evaluate the performance of catalytic converters. In addition, the sensor can be utilized in monitoring any process where hydrocarbons are exhausted, for instance, industrial power plants. The sensor is low cost, rugged, sensitive, simple to fabricate, miniature, and does not suffer cross sensitivities.

  20. Solution mining systems and methods for treating hydrocarbon containing formations

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); de Rouffignac, Eric Pierre (Rijswijk, NL); Schoeling, Lanny Gene (Katy, TX)

    2009-07-14

    A method for treating an oil shale formation comprising nahcolite is disclosed. The method includes providing a first fluid to a portion of the formation through at least two injection wells. A second fluid is produced from the portion through at least one injection well until at least two injection wells are interconnected such that fluid can flow between the two injection wells. The second fluid includes at least some nahcolite dissolved in the first fluid. The first fluid is injected through one of the interconnected injection wells. The second fluid is produced from at least one of the interconnected injection wells. Heat is provided from one or more heaters to the formation to heat the formation. Hydrocarbon fluids are produced from the formation.

  1. Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture

    DOE Patents [OSTI]

    Rao, V. Udaya S. (Monroeville, PA); Gormley, Robert J. (Pittsburgh, PA)

    1987-01-01

    Synthesis gas containing CO and H.sub.2 is converted to a high-octane hydrocarbon liquid in the gasoline boiling point range by bringing the gas into contact with a heterogeneous catalyst including, in physical mixture, a zeolite molecular sieve, cobalt at 6-20% by weight, and thoria at 0.5-3.9% by weight. The contacting occurs at a temperature of 250.degree.-300.degree. C., and a pressure of 10-30 atmospheres. The conditions can be selected to form a major portion of the hydrocarbon product in the gasoline boiling range with a research octane of more than 80 and less than 10% by weight aromatics.

  2. AIR QUALITY IMPACTS OF LIQUEFIED NATURAL GAS IN THE SOUTH COAST AIR BASIN OF CALIFORNIA

    E-Print Network [OSTI]

    Carerras-Sospedra, Marc

    2012-01-01

    4: Modeling Emissions from Natural Gas-Related Sources 4.1Penetration of Liquefied Natural Gas Table ES2: Impacts ontypical summer demand of natural gas in the South Coast Air

  3. Liquefied Natural Gas (LNG) Vapor Dispersion Modeling with Computational Fluid Dynamics Codes 

    E-Print Network [OSTI]

    Qi, Ruifeng

    2012-10-19

    Federal regulation 49 CFR 193 and standard NFPA 59A require the use of validated consequence models to determine the vapor cloud dispersion exclusion zones for accidental liquefied natural gas (LNG) releases. For modeling purposes, the physical...

  4. Price of Liquefied U.S. Natural Gas Exports by Vessel to China...

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquefied U.S. Natural Gas Exports by Vessel to China (Dollars per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2012 -- -- -- -- -- -- -- -- -- -- --...

  5. Code of practice for the storage of liquefied petroleum gas at fixed installations 

    E-Print Network [OSTI]

    Anonymous

    1971-01-01

    This Code provides a general guide to safe practice in storing and handling liquefied petroleum gas (LPG) at fixed storage installations where tanks are filled on site. It has been prepared primarily as a guide for any ...

  6. Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    The Assistant Secretary for Environment has responsibility for identifying, characterizing, and ameliorating the environmental, health, and safety issues and public concerns associated with commercial operation of specific energy systems. The need for developing a safety and environmental control assessment for liquefied gaseous fuels was identified by the Environmental and Safety Engineering Division as a result of discussions with various governmental, industry, and academic persons having expertise with respect to the particular materials involved: liquefied natural gas, liquefied petroleum gas, hydrogen, and anhydrous ammonia. This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in Fiscal Year (FY)-1979 and early FY-1980. Volume 1 (Executive Summary) describes the background, purpose and organization of the LGF Program and contains summaries of the 25 reports presented in Volumes 2 and 3. Annotated bibliographies on Liquefied Natural Gas (LNG) Safety and Environmental Control Research and on Fire Safety and Hazards of Liquefied Petroleum Gas (LPG) are included in Volume 1.

  7. Legal nature of LPG (liquefied petroleum gas) regulation

    SciTech Connect (OSTI)

    Liddell, G.

    1986-08-01

    The commercial exploitation of Liquefied Petroleum Gas (LPG) in New Zealand has occurred without a particular and comprehensive concern for any legal implications. The paper in Part I examines definitional questions, assesses in Part II the ability of courts and quasi-courts to evaluate risks associated with the product, examines in Part III the utility of common law remedies for injuries or associated with or arising from LPG, analyzes in Part IV the statutory regulation of LPG, concentrating particularly on the Dangerous Goods (Class 2 - Gases) Regulations 1980, discusses in Part V recent planning case-law concerning LPG development, and concludes that some reform is necessary to produce a more-coherent and precise regulatory regime that takes into account both the needs of developers and those affected by the development of LPG.

  8. Compressed natural gas and liquefied petroleum gas as alternative fuels

    SciTech Connect (OSTI)

    Moussavi, M.; Al-Turk, M. . Civil Engineering Dept.)

    1993-12-01

    The use of alternative fuels in the transportation industry has gained a strong support in recent years. In this paper an attempt was made to evaluate the use of liquefied petroleum gas (LPG) and compressed natural gas (NG) by 25 LPG-bifuel and 14 NG-bifuel vehicles that are operated by 33 transit systems throughout Nebraska. A set of performance measures such as average fuel efficiency in kilometers per liter, average fuel cost per kilometer, average oil consumption, and average operation and maintenance cost for alternatively fueled vehicles were calculated and compared with similar performance measures of gasoline powered vehicles. The results of the study showed that the average fuel efficiency of gasoline is greater than those of LPG and NG, and the average fuel costs (dollars per kilometer) for LPG and NG are smaller than those for gasoline for most of the vehicles under this study.

  9. Liquefied Natural Gas: Global Challenges (released in AEO2008)

    Reports and Publications (EIA)

    2008-01-01

    U.S. imports of liquefied natural gas (LNG) in 2007 were more than triple the 2000 total, and they are expected to grow in the long term as North Americas conventional natural gas production declines. With U.S. dependence on LNG imports increasing, competitive forces in the international markets for natural gas in general and LNG in particular will play a larger role in shaping the U.S. market for LNG. Key factors currently shaping the future of the global LNG market include the evolution of project economics, worldwide demand for natural gas, government policies that affect the development and use of natural resources in countries with LNG facilities, and changes in seasonal patterns of LNG trade.

  10. HYDROCARBONS FROM AUSTRALIAN OIL, 200 MILLION YEARS OLD

    E-Print Network [OSTI]

    Van Hoeven, William; Haug, Pat; Burlingame, A.L.; Calvin, Kelvin.

    1966-01-01

    of Moonie Oil "Branched- Cyclic" Hydrocarbon FractionNo. W -7405 -eng -48 HYDROCARBONS FROM AUSTRALIAN OIL, 200and Melvin Calvin July HYDROCARBONS FROM AUSTRALIAN OIL, 200

  11. Parenteral Hydrocarbon Injection and Associated Toxicities: Two Case Reports

    E-Print Network [OSTI]

    Nelson, Michael E.; Nasr, Isam

    2013-01-01

    Products Containing Hydrocarbons. JAMA. 1981;246:840–843.Tissue Injection of Hydrocarbons: A Case Report and Reviewand Nasr Parenteral Hydrocarbon Injection and Associated

  12. Emission of polycyclic aromatic hydrocarbons in China

    SciTech Connect (OSTI)

    Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-02-01

    Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

  13. Enrichment of light hydrocarbon mixture

    DOE Patents [OSTI]

    Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

    2011-11-29

    Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

  14. Enrichment of light hydrocarbon mixture

    DOE Patents [OSTI]

    Yang; Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

    2010-08-10

    Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

  15. Biological enhancement of hydrocarbon extraction

    DOE Patents [OSTI]

    Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

    2009-01-06

    A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

  16. Method for producing viscous hydrocarbons

    DOE Patents [OSTI]

    Poston, Robert S. (Winter Park, FL)

    1982-01-01

    A method for recovering viscous hydrocarbons and synthetic fuels from a subterranean formation by drilling a well bore through the formation and completing the well by cementing a casing means in the upper part of the pay zone. The well is completed as an open hole completion and a superheated thermal vapor stream comprised of steam and combustion gases is injected into the lower part of the pay zone. The combustion gases migrate to the top of the pay zone and form a gas cap which provides formation pressure to produce the viscous hydrocarbons and synthetic fuels.

  17. Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost and equipment

    E-Print Network [OSTI]

    Fuel switch could bring big savings for HECO Liquefied natural gas beats low-sulfur oil in cost gas instead of continuing to burn low-sulfur fuel oil, a report said. Switching to liquefied natural who switch from gasoline-powered vehicles to ones fueled by compressed natural gas could save as much

  18. Analysis of Ultrasonic Velocities in Hydrocarbon Mixtures

    E-Print Network [OSTI]

    of measurements on ultrasonic velocities of liquid hydrocarbons and mixtures. They found that their dataAnalysis of Ultrasonic Velocities in Hydrocarbon Mixtures James G. Berryman Lawrence Livermore on hydrocarbon mixtures was shown by Wang and Nur [JASA 89, 2725 (1991)] to agree quite well with the predictions

  19. Aromaticity of Polycyclic Conjugated Hydrocarbons Milan Randic*

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    Aromaticity of Polycyclic Conjugated Hydrocarbons Milan Randic´* National Institute of Chemistry Chemistry 3462 G. Clar 6n Rule versus Hu¨ckel 4n + 2 Rule 3464 H. Hydrocarbons versus Heteroatomic Systems Ordering 3476 VI. On Enumeration of Benzenoid Hydrocarbons 3477 VII. Kekule´ Valence Structures Count 3479

  20. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi Klavzara, , Petra Zigerta , Ivan Gutmanb sextets in any of the Clar formulae) of a catacondensed benzenoid hydrocarbon: CL is equal to the minimum; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within the theory that was formulated [1, 2

  1. Polycyclic Aromatic Hydrocarbon Biodegradation Rates: A

    E-Print Network [OSTI]

    Peters, Catherine A.

    Polycyclic Aromatic Hydrocarbon Biodegradation Rates: A Structure-Based Study K R I S T I N E H . W structure in determining the biodegradation rates of polycyclic aromatic hydrocarbons (PAHs). Laboratory. Introduction Polycyclic aromatic hydrocarbons (PAHs) are a class of organic pollutants that are commonly found

  2. Cuticular Hydrocarbon Research1 Marion Page2

    E-Print Network [OSTI]

    Cuticular Hydrocarbon Research1 Marion Page2 We have been studying existing taxonomies of forest in the utility of cuticular (surface) hydrocarbons as taxonomic characters (Haverty and others 1988, 1989, Page to be genetically fixed. Because the insects studied so far synthesize all or most of their hydrocarbon components

  3. Clar number of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Clar number of catacondensed benzenoid hydrocarbons Sandi KlavŸzar a,# , Petra Ÿ Zigert a , Ivan hydrocarbon: CL is equal to the minimum number of straight lines required to intersect all hexagons theory; Clar formula; Clar number; Resonance graph; Benzenoid hydrocarbons 1. Introduction Within

  4. Control method for mixed refrigerant based natural gas liquefier

    DOE Patents [OSTI]

    Kountz, Kenneth J. (Palatine, IL); Bishop, Patrick M. (Chicago, IL)

    2003-01-01

    In a natural gas liquefaction system having a refrigerant storage circuit, a refrigerant circulation circuit in fluid communication with the refrigerant storage circuit, and a natural gas liquefaction circuit in thermal communication with the refrigerant circulation circuit, a method for liquefaction of natural gas in which pressure in the refrigerant circulation circuit is adjusted to below about 175 psig by exchange of refrigerant with the refrigerant storage circuit. A variable speed motor is started whereby operation of a compressor is initiated. The compressor is operated at full discharge capacity. Operation of an expansion valve is initiated whereby suction pressure at the suction pressure port of the compressor is maintained below about 30 psig and discharge pressure at the discharge pressure port of the compressor is maintained below about 350 psig. Refrigerant vapor is introduced from the refrigerant holding tank into the refrigerant circulation circuit until the suction pressure is reduced to below about 15 psig, after which flow of the refrigerant vapor from the refrigerant holding tank is terminated. Natural gas is then introduced into a natural gas liquefier, resulting in liquefaction of the natural gas.

  5. Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report

    SciTech Connect (OSTI)

    1980-10-01

    This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in fiscal Year (FY)-1979 and early FY-1980. Volume 3 contains reports from 6 government contractors on LPG, anhydrous ammonia, and hydrogen energy systems. Report subjects include: simultaneous boiling and spreading of liquefied petroleum gas (LPG) on water; LPG safety research; state-of-the-art of release prevention and control technology in the LPG industry; ammonia: an introductory assessment of safety and environmental control information; ammonia as a fuel, and hydrogen safety and environmental control assessment.

  6. Dry reforming of hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Shah, Yatish T.; Gardner, Todd H.

    2014-09-25

    Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

  7. Catalytic method for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Sapienza, Richard S. (Shoreham, NY); Sansone, Michael J. (Summit, NJ); Slegeir, William A. R. (Hampton Bays, NY)

    1984-01-01

    A method for synthesizing hydrocarbons from carbon monoxide and hydrogen by contacting said gases with a slurry of a catalyst composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants.

  8. Deep desulfurization of hydrocarbon fuels

    DOE Patents [OSTI]

    Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

    2012-04-17

    The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

  9. Design and Applications of Anti Albumin-Adduct Antibodies to Assess Human Exposure to Aromatic Hydrocarbons

    E-Print Network [OSTI]

    Chung, Ming Kei

    2013-01-01

    measurement  of  polycyclic  aromatic  hydrocarbon-­?before  measurement  of  hydrocarbon-­?HSA  adducts   with  measurement  of  polycyclic  aromatic  hydrocarbon-­?

  10. Impact of Liquefied Natural Gas usage and payload size on Hybrid Wing Body aircraft fuel efficiency

    E-Print Network [OSTI]

    Mody, Pritesh (Pritesh Chetan)

    2010-01-01

    This work assessed Hybrid Wing Body (HWB) aircraft in the context of Liquefied Natural Gas (LNG) fuel usage and payload/range scalability at three scales: H1 (B737), H2 (B787) and H3 (B777). The aircraft were optimized for ...

  11. Control of Vapor Dispersion and Pool Fire of Liquefied Natural Gas (LNG) with Expansion Foam 

    E-Print Network [OSTI]

    Yun, Geun Woong

    2011-10-21

    Liquefied Natural Gas (LNG) is flammable when it forms a 5 – 15 percent volumetric concentration mixture with air at atmospheric conditions. When the LNG vapor comes in contact with an ignition source, it may result in fire and/or explosion. Because...

  12. Efficient Longitudinal Seismic Fragility Assessment of a Multispan Continuous Steel Bridge on Liquefiable Soils

    E-Print Network [OSTI]

    Padgett, Jamie Ellen

    on Liquefiable Soils Bayram Aygün, S.M.ASCE1 ; Leonardo Dueñas-Osorio, A.M.ASCE2 ; Jamie E. Padgett, A.M.ASCE3 even more important when considering complex phenomena such as soil liquefaction under seismic hazards. Currently, two approaches are widely used for bridge reliability estimation under soil failure conditions

  13. Paper No. 9.06 1 NEWMARKIAN ANALYSIS OF LIQUEFIED FLOW IN CENTRIFUGE MODEL

    E-Print Network [OSTI]

    Haigh, Stuart

    Paper No. 9.06 1 NEWMARKIAN ANALYSIS OF LIQUEFIED FLOW IN CENTRIFUGE MODEL EARTHQUAKES S.K. Haigh S-pressure history either predicted using a suitable constitutive model, or measured during a centrifuge or shaking displacements using this procedure and displacements measured in centrifuge model tests with the same pore

  14. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  15. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

    1988-06-14

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  16. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  17. Nox reduction system utilizing pulsed hydrocarbon injection

    DOE Patents [OSTI]

    Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

    2001-01-01

    Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

  18. Molecular catalytic hydrogenation of aromatic hydrocarbons and

    Office of Scientific and Technical Information (OSTI)

    catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. 01 COAL, LIGNITE, AND PEAT; 40 CHEMISTRY; COAL LIQUIDS;...

  19. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Hydrocarbon Precursor Production from Sewage Sludge Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste...

  20. Image portion identification methods, image parsing methods, image parsing systems, and articles of manufacture

    DOE Patents [OSTI]

    Lassahn, Gordon D.; Lancaster, Gregory D.; Apel, William A.; Thompson, Vicki S.

    2013-01-08

    Image portion identification methods, image parsing methods, image parsing systems, and articles of manufacture are described. According to one embodiment, an image portion identification method includes accessing data regarding an image depicting a plurality of biological substrates corresponding to at least one biological sample and indicating presence of at least one biological indicator within the biological sample and, using processing circuitry, automatically identifying a portion of the image depicting one of the biological substrates but not others of the biological substrates.

  1. Apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons

    SciTech Connect (OSTI)

    Agee, K.L.

    1990-11-27

    This patent describes apparatus for producing heavier hydrocarbons from one or more gaseous light hydrocarbons. It comprises a partial oxidation burner means; a synthesis gas generation vessel; a hydrocarbon synthesis reactor; first conduit means; separating means; second conduit means; catalytic combustion means; third conduit means; carbon dioxide separating means; fourth conduit means; and fifth conduit means.

  2. The application of expansion foam on liquefied natural gas (LNG) to suppress LNG vapor and LNG pool fire thermal radiation 

    E-Print Network [OSTI]

    Suardin, Jaffee Arizon

    2009-05-15

    Liquefied Natural Gas (LNG) hazards include LNG flammable vapor dispersion and LNG pool fire thermal radiation. A large LNG pool fire emits high thermal radiation thus preventing fire fighters from approaching and extinguishing the fire. One...

  3. Chlorinated Hydrocarbon Levels in Fishes and Shellfishes of the

    E-Print Network [OSTI]

    measurements. /n contrast, correlations were often significant between chlorinated hydrocarbons. such as DDEChlorinated Hydrocarbon Levels in Fishes and Shellfishes of the Northeastern Pacific Ocean Introduction Reports of excessive amounts of chlorinated hydrocarbons in fishery products have threatened

  4. Hydrocarbon-free resonance transition 795 nm rubidium laser

    E-Print Network [OSTI]

    Wu, Sheldon Shao Quan

    2009-01-01

    and R. J. Beach, "Hydrocarbon-free resonance transition 795-a Reliable Diode-Pumped Hydrocarbon-Free 795-nm Rubidiumand R. J. Beach, "Hydrocarbon-free resonance transition 795-

  5. Enhanced metabolism of halogenated hydrocarbons in transgenic plants containing mammalian

    E-Print Network [OSTI]

    Doty, Sharon Lafferty

    Enhanced metabolism of halogenated hydrocarbons in transgenic plants containing mammalian efficient remediation of many sites contaminated with haloge- nated hydrocarbons. Trichloroethylene (TCE hydrocarbon, ethylene dibromide (EDB; dibromoeth- ane), was used as a soil fumigant to kill nematodes

  6. Polynuclear aromatic hydrocarbons for fullerene synthesis in flames

    DOE Patents [OSTI]

    Alford, J. Michael; Diener, Michael D.

    2006-12-19

    This invention provides improved methods for combustion synthesis of carbon nanomaterials, including fullerenes, employing multiple-ring aromatic hydrocarbon fuels selected for high carbon conversion to extractable fullerenes. The multiple-ring aromatic hydrocarbon fuels include those that contain polynuclear aromatic hydrocarbons. More specifically, multiple-ring aromatic hydrocarbon fuels contain a substantial amount of indene, methylnapthalenes or mixtures thereof. Coal tar and petroleum distillate fractions provide low cost hydrocarbon fuels containing polynuclear aromatic hydrocarbons, including without limitation, indene, methylnapthalenes or mixtures thereof.

  7. Conversion of organic solids to hydrocarbons

    DOE Patents [OSTI]

    Greenbaum, E.

    1995-05-23

    A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

  8. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Energy Savers [EERE]

    HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Presentation from the...

  9. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions Poster presented at the 16th Directions...

  10. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two aromatic hydrocarbons, 17 nitrated PAHs (NPAHs) and 8 oxygenated PAHs (OPAHs) were carried out during hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons

  11. Effective Viscosity of Confined Hydrocarbons

    E-Print Network [OSTI]

    I. M. Sivebaek; V. N. Samoilov; B. N. J. Persson

    2012-01-24

    We present molecular dynamics friction calculations for confined hydrocarbon films with molecular lengths from 20 to 1400 carbon atoms. We find that the logarithm of the effective viscosity \\mu eff for nanometer-thin films depends linearly on the logarithm of the shear rate: log(effective viscosity) = C - n log (shear rate), where n varies from 1 (solidlike friction) at very low temperatures to 0 (Newtonian liquid) at very high temperatures, following an inverse sigmoidal curve. Only the shortest chain molecules melt, whereas the longer ones only show a softening in the studied temperature interval 0 < T < 900 K. The results are important for the frictional properties of very thin (nanometer) films and to estimate their thermal durability.

  12. In situ method for recovering hydrocarbon from subterranean oil shale deposits

    SciTech Connect (OSTI)

    Friedman, R.H.

    1987-11-03

    This patent describes in situ method for recovering hydrocarbons from subterranean oil shale deposits, the deposits comprising mineral rock and kerogen, comprising (a) penetrating the oil shale deposit with at least one well; (b) forming a zone of fractured and/or rubbilized oil shale material adjacent the well by hydraulic or explosive fracturing; (c) introducing a hydrogen donor solvent including tetralin into the portion of the oil shale formation treated in step (b) in a volume sufficient to fill substantially all of the void space created by the fracturing and rubbilizing treatment; (d) applying hydrogen to the tetralin and maintaining a predetermined pressure for a predetermined period of time sufficient to cause disintegration of the oil shale material; (e) thereafter introducing an oxidative environment into the portion of the oil shale deposit (f) producing the solvent in organic fragments to the surface of the earth, and (g) separating the organic fragments from the solvent.

  13. Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report

    SciTech Connect (OSTI)

    1980-10-01

    Volume 2 consists of 19 reports describing technical effort performed by Government Contractors in the area of LNG Safety and Environmental Control. Report topics are: simulation of LNG vapor spread and dispersion by finite element methods; modeling of negatively buoyant vapor cloud dispersion; effect of humidity on the energy budget of a liquefied natural gas (LNG) vapor cloud; LNG fire and explosion phenomena research evaluation; modeling of laminar flames in mixtures of vaporized liquefied natural gas (LNG) and air; chemical kinetics in LNG detonations; effects of cellular structure on the behavior of gaseous detonation waves under transient conditions; computer simulation of combustion and fluid dynamics in two and three dimensions; LNG release prevention and control; the feasibility of methods and systems for reducing LNG tanker fire hazards; safety assessment of gelled LNG; and a four band differential radiometer for monitoring LNG vapors.

  14. Liquefied natural gas as a transportation fuel for heavy-duty trucks: Volume I

    SciTech Connect (OSTI)

    1997-12-01

    This document contains Volume 1 of a three-volume manual designed for use with a 2- to 3-day liquefied natural gas (LNG) training course. Transportation and off-road agricultural, mining, construction, and industrial applications are discussed. This volume provides a brief introduction to the physics and chemistry of LNG; an overview of several ongoing LNG projects, economic considerations, LNG fuel station technology, LNG vehicles, and a summary of federal government programs that encourage conversion to LNG.

  15. Production of hydrocarbon fractions by hydrocracking

    SciTech Connect (OSTI)

    Degnan, T.F.; Kirker, G.W.; Socha, R.F.; Stapleton, M.R.; Johnson, I.D.

    1991-05-14

    This patent describes a process which comprises hydrocracking a hydrocarbon feedstock having an initial boiling point about 343{degrees} C. in the presence of a catalyst having cracking and hydrogenating activity. It comprises: catalyst comprising a layered silicate containing interspathic polymeric silica, in order to produce a hydrocarbon product having at least 35 percent by weight of hydrocarbons having a boiling point below 343{degrees} c., the catalyst further comprising at least one metal selected from the group consisting of Cr, Mo, W, Fe, Co, and Ni, wherein the hydrocracking occurs at conversions to product having a boiling point of less than 343{degrees} C. of greater than 70 percent volume of charge.

  16. Process for forming a chromium diffusion portion and articles made therefrom

    DOE Patents [OSTI]

    Helmick, David Andrew; Cavanaugh, Dennis William; Feng, Ganjiang; Bucci, David Vincent

    2012-09-11

    In one embodiment, a method for forming an article with a diffusion portion comprises: forming a slurry comprising chromium and silicon, applying the slurry to the article, and heating the article to a sufficient temperature and for a sufficient period of time to diffuse chromium and silicon into the article and form a diffusion portion comprising silicon and a microstructure comprising .alpha.-chromium. In one embodiment, a gas turbine component comprises: a superalloy and a diffusion portion having a depth of less than or equal to 60 .mu.m measured from the superalloy surface into the gas turbine component. The diffusion portion has a diffusion surface having a microstructure comprising greater than or equal to 40% by volume .alpha.-chromium.

  17. Process for forming a chromium diffusion portion and articles made therefrom

    DOE Patents [OSTI]

    Helmick, David Andrew; Cavanaugh, Dennis William; Feng, Ganjiang; Bucci, David Vincent

    2015-12-29

    In one embodiment, a method for forming an article with a diffusion portion comprises: forming a slurry comprising chromium and silicon, applying the slurry to the article, and heating the article to a sufficient temperature and for a sufficient period of time to diffuse chromium and silicon into the article and form a diffusion portion comprising silicon and a microstructure comprising .alpha.-chromium. In one embodiment, a gas turbine component comprises: a superalloy and a diffusion portion having a depth of less than or equal to 60 .mu.m measured from the superalloy surface into the gas turbine component. The diffusion portion has a diffusion surface having a microstructure comprising greater than or equal to 40% by volume .alpha.-chromium.

  18. The petrous portion of the human temporal bone: potential for forensic individuation 

    E-Print Network [OSTI]

    Wiersema, Jason Matthew

    2009-06-02

    are threefold: (1) To investigate variability in the shape of the petrous portion of the human temporal bone using two-dimensional morphometric analysis; (2) to evaluate the reliability of the resultant method in forensic identification; and (3) to consider...

  19. Solubilization of petroleum hydrocarbons using biosurfactants 

    E-Print Network [OSTI]

    Kanga, Shahrukh

    1995-01-01

    that bioavailability of the crude oil to the microorganisms limited the degradation rates (Mills, 1994). Preliminary experiments at our laboratories have also indicated enhanced solubilities of petroleum hydrocarbons due to the effects of biosurfactants (Kanga et al...

  20. Hydrocarbon zeolite catalyst employed in hydrocracking process

    SciTech Connect (OSTI)

    Ward, J.W.

    1987-05-12

    A hydrocracking process is described which comprises contacting a hydrocarbon feedstock under hydrocracking conditions with hydrogen in the presence of a catalyst comprising at least one hydrogenation component, a crystalline aluminosilicate zeolite having catalytic activity for cracking hydrocarbons, and a dispersion of silica-alumina in a matrix consisting essentially of alumina, wherein the catalyst comprises particles in the shape of a three-leaf clover.

  1. Waste control alternatives for chlorinated hydrocarbons 

    E-Print Network [OSTI]

    Pearce, Terry Allan

    1975-01-01

    WASTE CONTROL ALTERNATIVES FOR CHLORINATED HYDROCARBONS A Thesis by TERRY ALLAN PEARCE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1975 Major... Subject: Chemical Engineering WASTE CONTROL ALTERNATIVES FOR CHLORINATED HYDROCARBONS A Thesis by TERRY ALLAN PEARCE Approved as to style and content by: , ~ I ' p Chairman of Committee ead of Departmen em er Member May 1975 ABSTRACT Waste...

  2. Hydrocarbon habitat of the west Netherlands basin

    SciTech Connect (OSTI)

    De Jager, J. (Nederlandse Aardolie Maatschappij, Assen (Netherlands)); Doyle, M. (Petroleum Development Oman, Muscat (Oman)); Grantham, P. (KSEPL/Shell Research, Rijswijk (Netherlands)); Mabillard, J. (Shell Nigeria, Port Harcourt (Nigeria))

    1993-09-01

    The complex West Netherlands Basin contains oil and gas in Triassic and Upper Jurassic to Cretaceous clastic reservoir sequences. The understanding has always been that the Carboniferous coal measures have generated only gas and the Jurassic marine Posidonia Shale only oil. However, detailed geochemical analyses show that both source rocks have generated oil and gas. Geochemical fingerprinting established a correlation of the hydrocarbons with the main source rocks. The occurrence of these different hydrocarbons is consistent with migration routes. Map-based charge modeling shows that the main phase of hydrocarbon generation occurred prior to the Late Cretaceous inversion of the West Netherlands Basin. However, along the southwest flank of the basin and in lows between the inversion highs, significant charge continued during the Tertiary. Biodegradation of oils in Jurassic and Cretaceous reservoirs occurred during the earliest Tertiary, but only in reservoirs that were at that time at temperatures of less then 70 to 80[degrees]C, where bacteria could survive. This study shows that also in a mature hydrocarbon province an integrated hydrocarbon habitat study with modern analyses and state-of-the-art technology can lead to a much improved understanding of the distribution of oil and gas in the subsurface. The results of this study will allow a better risk assessment for remaining prospects, and an improved prediction of the type of trapped hydrocarbons in terms of gas, oil, and biodegraded oil.

  3. STUDIES OF WALL FLAME QUENCHING AND HYDROCARBON EMISSIONS IN A MODEL SPARK IGNITION ENGINE

    E-Print Network [OSTI]

    Ishikawa, Nobuhiko

    2011-01-01

    1 'Exhaust Hydrocarbon Measurement for Tuneup Diagnosis?"Methane Measurements Hydrocarbon measurements have been madealso induced. The hydrocarbon measurements reveal a general

  4. Measurement of Hydrocarbon Fluxes due to Natural Seepage in the Northern Santa Barbara Channel

    E-Print Network [OSTI]

    Washburn, Libe; Clark, Jordan F.

    2002-01-01

    of Energy 001 "MEASUREMENT OF HYDROCARBON FLUXES DUE TOauthors directly. Measurement of Hydrocarbon Fluxes due toflux measurements been obtained in the region of hydrocarbon

  5. On the use of hydrocarbons for the determination of tropospheric OH concentrations

    E-Print Network [OSTI]

    Ehhalt, D. H; Rohrer, F.; Wahner, A.; Prather, M. J; Blake, D. R

    1998-01-01

    ET AL. : USING HYDROCARBONS chemical and heterogeneous datade- cay of many reactive hydrocarbons in well-defined urbanseasonality of selected hydrocarbons and halocarbons over

  6. Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer

    E-Print Network [OSTI]

    2008-01-01

    CONDUCTIVITY IMAGING OF HYDROCARBONS USING THE BLUE GENE/Lidentification of hydrocarbon filled layers in deepwater,”Remote sensing of hydrocarbon layers by seabed logging (

  7. Variability of gas composition and flux intensity in natural marine hydrocarbon seeps

    E-Print Network [OSTI]

    Clark, Jordan F.; Washburn, Libe; Schwager Emery, Katherine

    2010-01-01

    in natural marine hydrocarbon seeps Jordan F. Clark & Libeenters, and CO 2 and hydrocarbon gases leave the bubbles.Introduction Natural hydrocarbon seeps are important

  8. Isolation, Determination of Absolute Stereochemistry, and Asymmetric Synthesis of Insect Methyl-Branched Hydrocarbons

    E-Print Network [OSTI]

    Bello, Jan Edgar

    2014-01-01

    d’Ettore, P. In Insect Hydrocarbons: Biology, Biochemistry,A.G. In Insect Hydrocarbons: Biology, Biochemistry, ChemicalMillar, J.G. In Insect Hydrocarbons: Biology, Biochemistry,

  9. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (‘syngas’) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  10. Striped Bass Spawning in Non-Estuarine Portions of the Savannah River

    SciTech Connect (OSTI)

    Martin, D.; Paller, M.

    2007-04-17

    Historically, the estuarine portions of the Savannah River have been considered to be the only portion of the river in which significant amounts of striped bass (Morone saxatilis) spawning normally occur. A reexamination of data from 1983 through 1985 shows a region between River Kilometers 144 and 253 where significant numbers of striped bass eggs and larvae occur with estimated total egg production near that currently produced in the estuarine reaches. It appears possible that there are two separate spawning populations of striped bass in the Savannah River.

  11. On the application of computational fluid dynamics codes for liquefied natural gas dispersion.

    SciTech Connect (OSTI)

    Luketa-Hanlin, Anay Josephine; Koopman, Ronald P.; Ermak, Donald

    2006-02-01

    Computational fluid dynamics (CFD) codes are increasingly being used in the liquefied natural gas (LNG) industry to predict natural gas dispersion distances. This paper addresses several issues regarding the use of CFD for LNG dispersion such as specification of the domain, grid, boundary and initial conditions. A description of the k-{var_epsilon} model is presented, along with modifications required for atmospheric flows. Validation issues pertaining to the experimental data from the Burro, Coyote, and Falcon series of LNG dispersion experiments are also discussed. A description of the atmosphere is provided as well as discussion on the inclusion of the Coriolis force to model very large LNG spills.

  12. Development of a Small-Scale Natural Gas Liquefier. Final Report

    SciTech Connect (OSTI)

    Kountz, K.; Kriha, K.; Liss, W.; Perry, M.; Richards, M.; Zuckerman, D.

    2003-04-30

    This final report describes the progress during the contract period March 1, 1998 through April 30, 2003, on the design, development, and testing of a novel mixed-refrigerant-based 1000 gal/day natural gas liquefier, together with the associated gas cleanup equipment. Based on the work, it is concluded that a cost-effective 1000 gal/day liquefaction system is technically and economically feasible. A unit based on the same developed technology, with 5000 gal/day capacity, would have much improved economics.

  13. Breach and safety analysis of spills over water from large liquefied natural gas carriers.

    SciTech Connect (OSTI)

    Hightower, Marion Michael; Luketa-Hanlin, Anay Josephine; Attaway, Stephen W.

    2008-05-01

    In 2004, at the request of the Department of Energy, Sandia National Laboratories (Sandia) prepared a report, ''Guidance on the Risk and Safety Analysis of Large Liquefied Natural Gas (LNG) Spills Over Water''. That report provided framework for assessing hazards and identifying approaches to minimize the consequences to people and property from an LNG spill over water. The report also presented the general scale of possible hazards from a spill from 125,000 m3 o 150,000 m3 class LNG carriers, at the time the most common LNG carrier capacity.

  14. U.S. Liquefied Natural Gas Imports From Algeria (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015"Separation, Proved Reserves(Million Barrels)1973-2015 Liquefied

  15. U.S. Liquefied Natural Gas Imports From Australia (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015"Separation, Proved Reserves(Million Barrels)1973-2015 LiquefiedDecade Year-0

  16. U.S. Liquefied Natural Gas Imports From Brunei (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015"Separation, Proved Reserves(Million Barrels)1973-2015 LiquefiedDecade

  17. U.S. Liquefied Natural Gas Imports From Canada (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015"Separation, Proved Reserves(Million Barrels)1973-2015 LiquefiedDecadeDecade

  18. U.S. Liquefied Natural Gas Imports From Egypt (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015"Separation, Proved Reserves(Million Barrels)1973-2015 LiquefiedDecadeDecadeDecade

  19. Liquefied U.S. Natural Gas Re-Exports to Portugal (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012 2013 2014Thousand343Decade Year-0Liquefied U.S.

  20. Liquefied U.S. Natural Gas Re-Exports to Russia (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012 2013 2014Thousand343Decade Year-0Liquefied

  1. Liquefied U.S. Natural Gas Re-Exports to South Korea (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012 2013 2014Thousand343Decade Year-0LiquefiedDecade

  2. Liquefied U.S. Natural Gas Re-Exports to China (Million Cubic Feet)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and-E CChina (Million Cubic Feet) Liquefied

  3. Sumas, WA Liquefied Natural Gas Imports from Canada (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYearbyWithdrawalsHome Page Welcome to(EIA)Liquefied

  4. Methods for dispersing hydrocarbons using autoclaved bacteria

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1996-01-01

    A method of dispersing a hydrocarbon includes the steps: providing a bacterium selected from the following group: ATCC 85527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures thereof; autoclaving the bacterium to derive a dispersant solution therefrom; and contacting the dispersant solution with a hydrocarbon to disperse the hydrocarbon. Moreover, a method for preparing a dispersant solution includes the following steps: providing a bacterium selected from the following group: ATCC 75527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures thereof; and autoclaving the bacterium to derive a dispersant solution therefrom.

  5. Methods for dispersing hydrocarbons using autoclaved bacteria

    DOE Patents [OSTI]

    Tyndall, R.L.

    1996-11-26

    A method of dispersing a hydrocarbon includes the following steps: providing a bacterium selected from the following group: ATCC 85527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures; autoclaving the bacterium to derive a dispersant solution; and contacting the dispersant solution with a hydrocarbon to disperse the hydrocarbon. Moreover, a method for preparing a dispersant solution includes the following steps: providing a bacterium selected from the following group: ATCC 75527, ATCC 75529, and ATCC 55638, a mutant of any one of these bacteria possessing all the identifying characteristics of any one of these bacteria, and mixtures; and autoclaving the bacterium to derive a dispersant solution.

  6. Hanford facility dangerous waste permit application, general information portion. Revision 3

    SciTech Connect (OSTI)

    Sonnichsen, J.C.

    1997-08-21

    For purposes of the Hanford facility dangerous waste permit application, the US Department of Energy`s contractors are identified as ``co-operators`` and sign in that capacity (refer to Condition I.A.2. of the Dangerous Waste Portion of the Hanford Facility Resource Conservation and Recovery Act Permit). Any identification of these contractors as an ``operator`` elsewhere in the application is not meant to conflict with the contractors` designation as co-operators but rather is based on the contractors` contractual status with the U.S. Department of Energy, Richland Operations Office. The Dangerous Waste Portion of the initial Hanford Facility Resource Conservation and Recovery Act Permit, which incorporated five treatment, storage, and/or disposal units, was based on information submitted in the Hanford Facility Dangerous Waste Permit Application and in closure plan and closure/postclosure plan documentation. During 1995, the Dangerous Waste Portion was modified twice to incorporate another eight treatment, storage, and/or disposal units; during 1996, the Dangerous Waste Portion was modified once to incorporate another five treatment, storage, and/or disposal units. The permit modification process will be used at least annually to incorporate additional treatment, storage, and/or disposal units as permitting documentation for these units is finalized. The units to be included in annual modifications are specified in a schedule contained in the Dangerous Waste Portion of the Hanford Facility Resource Conservation and Recovery Act Permit. Treatment, storage, and/or disposal units will remain in interim status until incorporated into the Permit. The Hanford Facility Dangerous Waste Permit Application is considered to be a single application organized into a General Information Portion (this document, DOE/RL-91-28) and a Unit-Specific Portion. The scope of the Unit-Specific Portion is limited to individual operating treatment, storage, and/or disposal units for which Part B permit application documentation has been, or is anticipated to be, submitted. Documentation for treatment, storage, and/or disposal units undergoing closure, or for units that are, or are anticipated to be, dispositioned through other options, will continue to be submitted by the Permittees in accordance with the provisions of the Hanford Federal Facility Agreement and Consent Order. However, the scope of the General Information Portion includes information that could be used to discuss operating units, units undergoing closure, or units being dispositioned through other options. Both the General Information and Unit-Specific portions of the Hanford Facility Dangerous Waste Permit Application address the contents of the Part B permit application guidance documentation prepared by the Washington State Department of Ecology and the U.S. Environmental Protection Agency, with additional information needs defined by revisions of Washington Administrative Code 173-303 and by the Hazardous and Solid Waste Amendments. Documentation contained in the General Information Portion is broader in nature and could be used by multiple treatment, storage, and/or disposal units (i.e., either operating units, units undergoing closure, or units being dispositioned through other options).

  7. Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas

    DOE Patents [OSTI]

    Durai-Swamy, Kandaswamy (Culver City, CA)

    1982-01-01

    In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

  8. Catalysts for synthesizing various short chain hydrocarbons

    DOE Patents [OSTI]

    Colmenares, Carlos (Alamo, CA)

    1991-01-01

    Method and apparatus (10), including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO.sub.2 aerogels doped with photochemically active uranyl ions (18) are fluidized in a fluidized-bed reactor (12) having a transparent window (16), by hydrogen and CO, C.sub.2 H.sub.4 or C.sub.2 H.sub.6 gas mixtures (20), and exposed to radiation (34) from a light source (32) external to the reactor (12), to produce the short chain hydrocarbons (36).

  9. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two;2 Abstract The size distribution of polycyclic aromatic hydrocarbons (PAHs) and PAH derivatives of compounds. Keywords: Polycyclic aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated

  10. DOE Award # DE-SC0008085 Close-Out Report for UIUC Portion of Grant

    SciTech Connect (OSTI)

    Teixeira, Kristina Anderson; DeLucia, Evan H

    2014-11-20

    This is the final technical report for the University of Illinois (UIUC) portion of grant # SC0008085 (CARBON DYNAMICS OF FOREST RECOVERY UNDER A CHANGING CLIMATE: FORCINGS, FEEDBACKS, AND IMPLICATIONS FOR EARTH SYSTEM MODELING), which closed June 14, 2014. The grant remains active at the Smithsonian.

  11. Household Hazardous Waste Household hazardous waste is the discarded, unused, or leftover portion of household products

    E-Print Network [OSTI]

    de Lijser, Peter

    over a larger area and releases them into the air. Pouring hazardous liquids on the ground can poisonHousehold Hazardous Waste Household hazardous waste is the discarded, unused, or leftover portion should be considered hazardous. You cannot treat hazardous wastes like other kinds of garbage

  12. Semiconductor structures having electrically insulating and conducting portions formed from an AlSb-alloy layer

    DOE Patents [OSTI]

    Spahn, Olga B. (Albuquerque, NM); Lear, Kevin L. (Albuquerque, NM)

    1998-01-01

    A semiconductor structure. The semiconductor structure comprises a plurality of semiconductor layers formed on a substrate including at least one layer of a III-V compound semiconductor alloy comprising aluminum (Al) and antimony (Sb), with at least a part of the AlSb-alloy layer being chemically converted by an oxidation process to form superposed electrically insulating and electrically conducting portions. The electrically insulating portion formed from the AlSb-alloy layer comprises an oxide of aluminum (e.g. Al.sub.2 O.sub.3), while the electrically conducting portion comprises Sb. A lateral oxidation process allows formation of the superposed insulating and conducting portions below monocrystalline semiconductor layers for forming many different types of semiconductor structures having particular utility for optoelectronic devices such as light-emitting diodes, edge-emitting lasers, vertical-cavity surface-emitting lasers, photodetectors and optical modulators (waveguide and surface normal), and for electronic devices such as heterojunction bipolar transistors, field-effect transistors and quantum-effect devices. The invention is expected to be particularly useful for forming light-emitting devices for use in the 1.3-1.6 .mu.m wavelength range, with the AlSb-alloy layer acting to define an active region of the device and to effectively channel an electrical current therein for efficient light generation.

  13. Preservation and Dissemination of the Hardcopy Documentation Portion of the NCSP Nuclear Criticality Bibliographic Database

    SciTech Connect (OSTI)

    Koponen, B L; Heinrichs, D

    2009-05-18

    The U.S. Department of Energy supports a nuclear criticality safety bibliographic internet database that contains approximately 15,000 records. We are working to ensure that a substantial portion of the corresponding hardcopy documents are preserved, digitized, and made available to criticality safety practitioners via the Nuclear Criticality Safety Program web site.

  14. 12:41 PM 6/18/99 Page 1 GENERATING TESTS FOR CONTROL PORTION OF

    E-Print Network [OSTI]

    von Bochmann, Gregor

    12:41 PM 6/18/99 Page 1 GENERATING TESTS FOR CONTROL PORTION OF SDL SPECIFICATIONS WITH SAVE1 Gang.A, Montreal, P.Q., H3C 3J7, Canada E-mail:luo@iro.umontreal.ca, Fax: (514) 343 ABSTRACT The signal SAVE consisting of the foll SDL specifications are first abstracted into finite state machines with save

  15. Sustainable treatment of hydrocarbon-contaminated industrial land 

    E-Print Network [OSTI]

    Cunningham, Colin John

    2012-06-25

    Land contamination by petroleum hydrocarbons is a widespread and global environmental pollution issue from recovery and refining of crude oil and the ubiquitous use of hydrocarbons in industrial processes and applications. ...

  16. Conversion of methane and acetylene into gasoline range hydrocarbons 

    E-Print Network [OSTI]

    Alkhawaldeh, Ammar

    2000-01-01

    Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene...

  17. A Parametric Study of the Effect of Temperature and Hydrocarbon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Temperature and Hydrocarbon Species on the Product Distribution from a Non-Thermal Plasma Reactor A Parametric Study of the Effect of Temperature and Hydrocarbon Species on the...

  18. Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons

    E-Print Network [OSTI]

    Chickos, James S.

    values for these thermochemical properties and for the enthalpies of formation in the gas state at T=298Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons María Victoria Experimental thermochemical properties of benzene, toluene, and 63 polycyclic aro- matic hydrocarbons

  19. Seismic Analysis Using Wavelet Transform for Hydrocarbon Detection 

    E-Print Network [OSTI]

    Cai, Rui

    2012-02-14

    result in successful hydrocarbon finds because abnormal seismic amplitude variations can sometimes be caused by other factors, such as alternative lithology and residual hydrocarbons in certain depositional environments. Furthermore, not all gas fields...

  20. Calculating the hyper--Wiener index of benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Calculating the hyper--Wiener index of benzenoid hydrocarbons Petra Ÿ Zigert 1 , Sandi KlavŸ zar 1. (1) is not easy, especially in the case of large polycyclic molecules, such as benzenoid hydrocarbons

  1. Calculating the hyperWiener index of benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Calculating the hyper­Wiener index of benzenoid hydrocarbons Petra Zigert1 , Sandi Klavzar1) is not easy, especially in the case of large polycyclic molecules, such as benzenoid hydrocarbons. Some time

  2. Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...

    Office of Scientific and Technical Information (OSTI)

    MICROALGAE; ALGAL BIOMASS; HYDROCARBON BIOFUELS; BIOMASS TECHNOLOGIES OFFICE; NATIONAL RENEWABLE ENERGY LABORATORY; PACIFIC NORTHWEST NATIONAL LABORATORY; Bioenergy BIOMASS...

  3. Method and apparatus for low temperature destruction of halogenated hydrocarbons

    DOE Patents [OSTI]

    Reagen, William Kevin (Stillwater, MN); Janikowski, Stuart Kevin (Idaho Falls, ID)

    1999-01-01

    A method and apparatus for decomposing halogenated hydrocarbons are provided. The halogenated hydrocarbon is mixed with solvating agents and maintained in a predetermined atmosphere and at a predetermined temperature. The mixture is contacted with recyclable reactive material for chemically reacting with the recyclable material to create dehalogenated hydrocarbons and halogenated inorganic compounds. A feature of the invention is that the process enables low temperature destruction of halogenated hydrocarbons.

  4. Clean air program: Design guidelines for bus transit systems using liquefied petroleum gas (LPG) as an alternative fuel. Final report, July 1995-April 1996

    SciTech Connect (OSTI)

    Raj, P.K.; Hathaway, W.T.; Kangas, R.

    1996-09-01

    The Federal Transit Administration (FTA) has initiated the development of `Design Guidelines for Bus Transit Systems Using Alternative Fuels.` This report provides design guidelines for the safe uses of Liquefied Petroleum Gas (LPG). It forms a part of the series of individual monographs being published by the FTA on (the guidelines for the safe use of) Compressed Natural Gas (CNG), Liquefied Natural Gas (LNG), Liquefied Petroleum Gas (LPG) and alcohol fuels (Methanol and Ethanol). Each report in this series describes for the subject fuel the important fuel properties, guidelines for the design and operation of bus fueling, storage and maintenance facilities, issues on personnel training and emergency preparedness.

  5. RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART I: ALLENE developed in our laboratory for the reactions of C3-C4 unsaturated hydrocarbons. The main reaction pathways2007 #12;3 INTRODUCTION Soots and polyaromatic hydrocarbons (PAH), which are present in the exhaust gas

  6. The Production of Non-Methane Hydrocarbons by Marine Plankton

    E-Print Network [OSTI]

    The Production of Non-Methane Hydrocarbons by Marine Plankton Stephanie Lyn Shaw Center for Global://web.mit.edu/cgcs/ Printed on recycled paper #12;1 The Production of Non-Methane Hydrocarbons by Marine Plankton by Stephanie of Non-Methane Hydrocarbons by Marine Plankton by Stephanie Lyn Shaw Submitted to the Department of Earth

  7. 2004-01-2299 Elevated Carbon Dioxide Alters Hydrocarbon

    E-Print Network [OSTI]

    Paré, Paul W.

    2004-01-2299 Elevated Carbon Dioxide Alters Hydrocarbon Emissions and Flavor in Onion P. W. Paré, R of low-molecular-weight hydrocarbons and sulfur derivatives. Odd-chain ketones are emitted from onion-through chambers, volatile hydrocarbons from undamaged plants can be collected under different environmental

  8. Production of hydrocarbons from hydrates. [DOE patent application

    DOE Patents [OSTI]

    McGuire, P.L.

    1981-09-08

    An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

  9. Method for removing chlorine compounds from hydrocarbon mixtures

    DOE Patents [OSTI]

    Janoski, E.J.; Hollstein, E.J.

    1984-09-29

    A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

  10. Binary coding of Kekule structures of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Binary coding of Kekulâ??e structures of catacondensed benzenoid hydrocarbons Sandi KlavŸzar, aâ??e structures of benzenoids Key words: benzenoid hydrocarbons, benzenoid graph, resonance graph, Kekul easily be recovered from its binary code. Key words: benzenoid hydrocarbons, benzenoid graph, resonance

  11. Hydrocarbon Formation in Metallic Iron/Water Systems

    E-Print Network [OSTI]

    Deng, Baolin

    Hydrocarbon Formation in Metallic Iron/Water Systems B A O L I N D E N G , , § T I M O T H Y J . C-labeled hydrocarbons are produced. In the absence of chlorinated ethenes, however, lower con- centrations of many of the same hydrocarbons (methane and C2-C6 alkanes and alkenes) are also produced. Hardy and Gillham (1996

  12. Binary coding of Kekule structures of catacondensed benzenoid hydrocarbons

    E-Print Network [OSTI]

    Klavzar, Sandi

    Binary coding of Kekul´e structures of catacondensed benzenoid hydrocarbons Sandi Klavzar of benzenoids Key words: benzenoid hydrocarbons, benzenoid graph, resonance graph, Kekul´e structure, algorithm easily be recovered from its binary code. Key words: benzenoid hydrocarbons, benzenoid graph, resonance

  13. Wiener Numbers of Pericondensed Benzenoid Hydrocarbons Sandi Klav zar

    E-Print Network [OSTI]

    Klavzar, Sandi

    Wiener Numbers of Pericondensed Benzenoid Hydrocarbons Sandi Klav#20;zar Department of Mathematics expressions for W for several homologous series of pericondensed benzenoid hydrocarbons. An elementary proof polycyclic systems studied were catacondensed benzenoid hydrocarbons. 11{14 Few years ago the situation

  14. Atomic displacements due to spinspin repulsion in conjugated alternant hydrocarbons

    E-Print Network [OSTI]

    Benzi, Michele

    Atomic displacements due to spin­spin repulsion in conjugated alternant hydrocarbons Ernesto-induced atomic displacements in conjugated alt- ernant hydrocarbons. It appears to be responsible alternant hydrocarbons (CAHs) have played a fun- damental role in the development of theoretical chemistry

  15. UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices

    E-Print Network [OSTI]

    UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices: Production of Alcohols, Quinones. Clemett,3 Richard N. Zare3 Polycyclic aromatic hydrocarbons (PAHs) in water ice were exposed to ultra, and ethers, and reduced, producing partially hydrogenated aromatic hydrocarbons, molecules that account

  16. Air Quality Impacts of Liquefied Natural Gas in the South Coast Air Basin of California Marc Carerras-Sospedra1

    E-Print Network [OSTI]

    Dabdub, Donald

    Air Quality Impacts of Liquefied Natural Gas in the South Coast Air Basin of California Marc. These volumes contribute to the total natural gas supply to the SoCalGas/SDG&E system of 76 million Nm3 /day for a typical summer demand in 2023, and 91 million Nm3 /day for the estimated maximum demand. b) Natural Gas

  17. Mass Transfer of Polynuclear Aromatic Hydrocarbons from

    E-Print Network [OSTI]

    Peters, Catherine A.

    ). Many PAHs are only sparingly soluble, and large volumes of water can therefore be contaminated by smallMass Transfer of Polynuclear Aromatic Hydrocarbons from Complex DNAPL Mixtures S U P A R N A M U K . * , Environmental and Water Resources Engineering, Department of Civil and Environmental Engineering, The University

  18. Method of dispersing a hydrocarbon using bacteria

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1996-01-01

    New protozoan derived microbial consortia and method for their isolation are provided. Consortia and bacteria isolated therefrom are useful for treating wastes such as trichloroethylene and trinitrotoluene. Consortia, bacteria isolated therefrom, and dispersants isolated therefrom are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

  19. Method of dispersing a hydrocarbon using bacteria

    DOE Patents [OSTI]

    Tyndall, R.L.

    1996-09-24

    A new protozoan derived microbial consortia and method for their isolation are provided. The isolated consortia and bacteria are useful for treating wastes such as trichloroethylene and trinitrotoluene. The isolated consortia, bacteria, and dispersants are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

  20. Reduction of Hydrocarbon Losses to Flare Systems 

    E-Print Network [OSTI]

    Page, J.

    1979-01-01

    action to minimize hydrocarbon releases, 2) install flare gas recovery systems, and 3) recover or reduce process streams which have to be continuous1y vented to the flare system. This report discusses alternate designs for flare gas monitoring and flare...

  1. Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard reference material 1649a (urban dust) and

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Simultaneous analysis of oxygenated and nitrated polycylic aromatic hydrocarbons on standard nitrated polycylic aromatic hydrocarbons (NPAHs) and 9 oxygenated polycylic aromatic hydrocarbons (OPAHs aromatic hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic

  2. THE ROLE OF POLYCYCLIC AROMATIC HYDROCARBONS IN ULTRAVIOLET EXTINCTION. I. PROBING SMALL MOLECULAR POLYCYCLIC AROMATIC HYDROCARBONS1

    E-Print Network [OSTI]

    THE ROLE OF POLYCYCLIC AROMATIC HYDROCARBONS IN ULTRAVIOLET EXTINCTION. I. PROBING SMALL MOLECULAR POLYCYCLIC AROMATIC HYDROCARBONS1 Geoffrey C. Clayton,2 Karl D. Gordon,3 F. Salama,4 L. J. Allamandola,4, with particular emphasis on a search for absorp- tion features produced by polycyclic aromatic hydrocarbons (PAHs

  3. 12:41 PM 6/18/99 Page 1 GENERATING TESTS FOR CONTROL PORTION OF

    E-Print Network [OSTI]

    von Bochmann, Gregor

    12:41 PM 6/18/99 Page 1 GENERATING TESTS FOR CONTROL PORTION OF SDL SPECIFICATIONS WITH SAVE 1 Gang.A, Montreal, P.Q., H3C 3J7, Canada E­mail:luo@iro.umontreal.ca, Fax: (514) 343­5834. ABSTRACT The signal SAVE are first abstracted into finite state machines with save constructs; next the resulting machines

  4. Plasma-assisted conversion of solid hydrocarbon to diamond

    DOE Patents [OSTI]

    Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

    1996-01-01

    A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

  5. Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil

    DOE Patents [OSTI]

    Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

    2000-01-01

    In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

  6. Method and apparatus for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1983-06-21

    A method and apparatus for synthesizing a mixture of hydrocarbons having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further includes Na present as a substitutional cation in an amount of about 5 to 10 atom %. At a temperature of about 340 to 360/sup 0/C, and at pressures of about 20 to 50 atm, CH/sub 3/OH is produced in an amount of about 90 wt % of the total hydrocarbon mixture, and comprised 1 mole % of the effluent gas.

  7. Monitoring of vapor phase polycyclic aromatic hydrocarbons

    DOE Patents [OSTI]

    Vo-Dinh, Tuan; Hajaligol, Mohammad R.

    2004-06-01

    An apparatus for monitoring vapor phase polycyclic aromatic hydrocarbons in a high-temperature environment has an excitation source producing electromagnetic radiation, an optical path having an optical probe optically communicating the electromagnetic radiation received at a proximal end to a distal end, a spectrometer or polychromator, a detector, and a positioner coupled to the first optical path. The positioner can slidably move the distal end of the optical probe to maintain the distal end position with respect to an area of a material undergoing combustion. The emitted wavelength can be directed to a detector in a single optical probe 180.degree. backscattered configuration, in a dual optical probe 180.degree. backscattered configuration or in a dual optical probe 90.degree. side scattered configuration. The apparatus can be used to monitor an emitted wavelength of energy from a polycyclic aromatic hydrocarbon as it fluoresces in a high temperature environment.

  8. Conversion method for gas streams containing hydrocarbons

    DOE Patents [OSTI]

    Mallinson, Richard G. (Norman, OK); Lobban, Lance (Norman, OK); Liu, Chang-jun (Tianjin, CN)

    2000-01-01

    An apparatus and a method of using the apparatus are provided for converting a gas stream containing hydrocarbons to a reaction product containing effluent molecules having at least one carbon atom, having at least one interior surface and at least one exterior surface, a first electrode and a second electrode with the first and second electrodes being selectively movable in relation to each other and positioned within the housing so as to be spatially disposed a predetermined distance from each other, a plasma discharge generator between the first and second electrodes, gas stream introducer and a collector for collecting the reaction product effluent produced by the reaction of the gas stream containing hydrocarbons with the plasma discharge between the first and second electrodes.

  9. Process for mild hydrocracking of hydrocarbon feeds

    SciTech Connect (OSTI)

    Nevitt, T.D.; Hopkins, P.D.; Tait, A.M.

    1984-02-14

    A process for mild hydrocracking of hydrocarbon feeds comprising contacting the feed with hydrogen under mild hydrocracking conditions in the presence of a catalytic composition comprising an active metallic component comprising at least one metal having hydrogenation activity and at least one oxygenated phosphorus component, and a support component comprising at least one non-zeolitic, porous refractory inorganic oxide matrix component and at least one shape selective crystalline molecular sieve zeolite component.

  10. Characterization and quantitative analyses of polychlorinated hydrocarbons 

    E-Print Network [OSTI]

    Richardson, Robert Leary

    1974-01-01

    and quantitativ' analyses of certain poly- chlorinated hydrocarbons (PCB, !iDT and its metabolites in marine biota) were investigated. The occurence ot these compounds were expected at such low concentrations the use of the elec, tron capt gas... of contamination improved the sensitivity of detection of these chlorinated hydro- carbons to the parts per bi'!lion range. A variety of samples from the Gulf of Nexi co and Northern Caribbean were analyzed. The analytical procedure consisted of macerating...

  11. Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons

    DOE Patents [OSTI]

    Kung, H.H.; Chaar, M.A.

    1988-10-11

    Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

  12. Getter pump for hydrogen and hydrocarbon gases

    DOE Patents [OSTI]

    Hsu, Wen Ling

    1987-10-14

    A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm/sup 2/. The graphite may be heated to a temperature greater than 1000/degree/C. The new device offers high capacity, low noise, and gas species selectivity. 2 figs.

  13. Impacts of Imported Liquefied Natural Gas on Residential Appliance Components: Literature Review

    SciTech Connect (OSTI)

    Lekov, Alex; Sturges, Andy; Wong-Parodi, Gabrielle

    2009-12-09

    An increasing share of natural gas supplies distributed to residential appliances in the U.S. may come from liquefied natural gas (LNG) imports. The imported gas will be of a higher Wobbe number than domestic gas, and there is concern that it could produce more pollutant emissions at the point of use. This report will review recently undertaken studies, some of which have observed substantial effects on various appliances when operated on different mixtures of imported LNG. While we will summarize findings of major studies, we will not try to characterize broad effects of LNG, but describe how different components of the appliance itself will be affected by imported LNG. This paper considers how the operation of each major component of the gas appliances may be impacted by a switch to LNG, and how this local impact may affect overall safety, performance and pollutant emissions.

  14. Characterization of liquefied natural gas tanker steel from cryogenic to fire temperatures.

    SciTech Connect (OSTI)

    Dempsey, J. Franklin; Wellman, Gerald William; Antoun, Bonnie R.; Connelly, Kevin; Kalan, Robert J.

    2010-03-01

    The increased demand for Liquefied Natural Gas (LNG) as a fuel source in the U.S. has prompted a study to improve our capability to predict cascading damage to LNG tankers from cryogenic spills and subsequent fire. To support this large modeling and simulation effort, a suite of experiments were conducted on two tanker steels, ABS Grade A steel and ABS Grade EH steel. A thorough and complete understanding of the mechanical behavior of the tanker steels was developed that was heretofore unavailable for the span of temperatures of interest encompassing cryogenic to fire temperatures. This was accomplished by conducting several types of experiments, including tension, notched tension and Charpy impact tests at fourteen temperatures over the range of -191 C to 800 C. Several custom fixtures and special techniques were developed for testing at the various temperatures. The experimental techniques developed and the resulting data will be presented, along with a complete description of the material behavior over the temperature span.

  15. Upgrading Fischer-Tropsch LPG (liquefied petroleum gas) with the Cyclar process

    SciTech Connect (OSTI)

    Gregor, J.H.; Gosling, C.D.; Fullerton, H.E.

    1989-04-28

    The use of the UOP/BP Cyclar{reg sign} process for upgrading Fischer-Tropsch (F-T) liquefied petroleum gas (LPG) was studied at UOP{reg sign}. The Cyclar process converts LPG into aromatics. The LPG derived from F-T is highly olefinic. Two routes for upgrading F-T LPG were investigated. In one route, olefinic LPG was fed directly to a Cyclar unit (Direct Cyclar). The alternative flow scheme used the Huels CSP process to saturate LPG olefins upstream of the Cyclar unit (Indirect Cyclar). An 18-run pilot plant study verified that each route is technically feasible. An economic evaluation procedure was designed to choose between the Direct and Indirect Cyclar options for upgrading LPG. Four situations involving three different F-T reactor technologies were defined. The main distinction between the cases was the degree of olefinicity, which ranged between 32 and 84 wt % of the fresh feed. 8 refs., 80 figs., 44 tabs.

  16. Liquefied gaseous fuels safety and environmental control assessment program: third status report

    SciTech Connect (OSTI)

    Not Available

    1982-03-01

    This Status Report contains contributions from all contractors currently participating in the DOE Liquefied Gaseous Fuels (LG) Safety and Environmental Control Assessment Program and is presented in two principal sections. Section I is an Executive Summary of work done by all program participants. Section II is a presentation of fourteen individual reports (A through N) on specific LGF Program activities. The emphasis of Section II is on research conducted by Lawrence Livermore National Laboratory (Reports A through M). Report N, an annotated bibliography of literature related to LNG safety and environmental control, was prepared by Pacific Northwest Laboratory (PNL) as part of its LGF Safety Studies Project. Other organizations who contributed to this Status Report are Aerojet Energy Conversion Company; Applied Technology Corporation; Arthur D. Little, Incorporated; C/sub v/ International, Incorporated; Institute of Gas Technology; and Massachusetts Institute of Technology. Separate abstracts have been prepared for Reports A through N for inclusion in the Energy Data Base.

  17. Hydrocarbon Fouling of SCR during PCCI combustion

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y [ORNL; Pihl, Josh A [ORNL; Lewis Sr, Samuel Arthur [ORNL; Parks, II, James E [ORNL

    2012-01-01

    The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust. The Fe-zeolite NOX conversion efficiency was significantly degraded, especially at low temperatures (<250 C), after the catalyst was exposed to the raw engine exhaust. The degradation of the Fe-zeolite performance was similar for both combustion modes. The Cu-zeolite showed better tolerance to HC fouling at low temperatures compared to the Fe-zeolite but PCCI exhaust had a more significant impact than the exhaust from conventional combustion on the NOX conversion efficiency. Furthermore, chemical analysis of the hydrocarbons trapped on the SCR cores was conducted to better determine chemistry specific effects.

  18. Neutron absorbers and methods of forming at least a portion of a neutron absorber

    DOE Patents [OSTI]

    Guillen, Donna P; Porter, Douglas L; Swank, W David; Erickson, Arnold W

    2014-12-02

    Methods of forming at least a portion of a neutron absorber include combining a first material and a second material to form a compound, reducing the compound into a plurality of particles, mixing the plurality of particles with a third material, and pressing the mixture of the plurality of particles and the third material. One or more components of neutron absorbers may be formed by such methods. Neutron absorbers may include a composite material including an intermetallic compound comprising hafnium aluminide and a matrix material comprising pure aluminum.

  19. Precambrian geology of a portion of the Purdy Hill quadrangle, Mason County, Texas 

    E-Print Network [OSTI]

    Mutis-Duplat, Emilio

    1969-01-01

    ) (Head of Department) (Membe r) A ust 1969 ABS TRAC T Precambrian Geology of a Portion of the Purdy Hill Quadrangle, Mason County, Texas. (August 1969) Emilio Mutis-Duplat, Geologist and Geophysicist, Unive re idad Nacional de Colombia; Directed by...'s understanding of the geology of the area. Dr. Robert R. Berg, Head of the Department of Geology, who was a permanent source of encouragement. The members of the Awards Committee of the Department of Geology, for the award that provided financial support...

  20. Geology of a portion of the northern Kings Mountain belt, North Carolina 

    E-Print Network [OSTI]

    Michie, Joanna

    1985-01-01

    GEOLOGY OF A PORTrON OP THE NORTHERN RINGS YOUNTAIN BELT NO&TH CAROLINA A Thesis by JOANNA NICHIF Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Hay... lep5 Yaior Subiect: Geology GEOLOGY OF A PORTION OF THE NORTHERN KINGS MOUNTAIN BELT, NORTH CAROLINA A Thesis by JOANNA MICHIE Approved as to style and content by: David W. Mohr (Chairman of Committee) J. Robert Butler (Member) John H. pang...

  1. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  2. An investigation of the thermal degradation mechanisms of a waste tire through chemical analysis including hydrocarbons, benzene derivatives, and Polycyclic

    E-Print Network [OSTI]

    including hydrocarbons, benzene derivatives, and Polycyclic Aromatic Hydrocarbons (PAHs) at high temperature-to-Energy, Volatile Organic Carbons (VOCs), Polycyclic Aromatic Hydrocarbons (PAHs), Hetero-N containing PAH

  3. Polycyclic Aromatic Hydrocarbons in Indoor Air and Environmental Tobacco Smoke Measured with a New Integrated Organic Vapor-Particle Sampler

    E-Print Network [OSTI]

    Gundel, L.A.; Daisey, J.M.; Mahanama, K.R.R.; Lee, C.C.; Stevens, R.K.

    1993-01-01

    of polycyclic aromatic hydrocarbons in environmental tobaccoof polycyclic aromatic hydrocarbons. Indoor Air 1991;1:497-NK. Polycyclic aromatic hydrocarbons and their derivatives

  4. Applications of contaminant fate and bioaccumulation models in assessing ecological risks of chemicals: A case study for gasoline hydrocarbons

    E-Print Network [OSTI]

    MacLeod, Matthew; McKone, Thomas E.; Foster, Karen L.; Maddalena, Randy L.; Parkerton, Thomas F.; Mackay, Don

    2004-01-01

    A Case Study for Gasoline Hydrocarbons Matthew MacLeod 1 ,since the component hydrocarbons comprising this complexthat the component hydrocarbons comprising this complex

  5. Real-time characterization of particle-bound polycyclic aromatic hydrocarbons in ambient aerosols and from motor-vehicle exhaust

    E-Print Network [OSTI]

    Polidori, A.; Hu, S.; Biswas, S.; Delfino, R. J; Sioutas, C.

    2008-01-01

    of polycyclic aromatic hydrocarbons in coupled out- door/polycyclic aromatic hydrocarbon concentration in combustionbound polycyclic aromatic hydrocarbons K. A. , Morris, J. ,

  6. Toxicity cutoff of aromatic hydrocarbons for luminescence inhibition of Vibrio fischeri

    E-Print Network [OSTI]

    McFall-Ngai, Margaret

    Toxicity cutoff of aromatic hydrocarbons for luminescence inhibition of Vibrio fischeri So Polycyclic aromatic hydrocarbons a b s t r a c t Effects of individual petroleum hydrocarbons hydrocarbons, including benzene and its derivatives and polycyclic aromatic hydrocarbons (PAHs), were chosen

  7. Process for removing carbonyl-sulfide from liquid hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Debras, G.L.G.; DeClippeleir, G.E.M.J.; Cahen, R.M.

    1986-09-23

    A process is described for removing carbonyl sulfide from a liquid olefinic hydrocarbon feedstock comprising: (a) passing the hydrocarbon feedstock over an absorbent material comprising zinc oxide and a promoter selected from the group consisting of alumina, silico-aluminas and any combination thereof wherein the promoter is present in amounts from about 3 to about 15 percent by weight of the absorbent material; and (b) recovering a liquid olefinic hydrocarbon stream having a substantially reduced carbonyl sulfide content.

  8. Hydrocarbon analysis of shrimp from oil polluted waters 

    E-Print Network [OSTI]

    DeWitt, Bernard John

    1982-01-01

    but ubiquitous compounds in the marine environment (Clark and Finley, 1973). They occur in marine organisms, in sediments and in seawater according to Clark and Blumer (1967). To determine oil pollution, a means of differentiating petroleum hydrocarbons from... in the marine environment for long periods. They enter the environment from fossil fuels and decaying marine organisms (Clark and Blumer, 1967). Therefore pollution and biogenic hydrocarbons contain the same hydrocarbons, although from different sources...

  9. Systems and methods for producing hydrocarbons from tar sands formations

    DOE Patents [OSTI]

    Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

    2009-07-21

    A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

  10. Ethanol-to-Hydrocarbon Technology Moves Closer to Commercialization...

    Energy Savers [EERE]

    and enable production of drop-in hydrocarbon fuels more quickly, in addition to expanding production of jet fuel, diesel, and renewable commodity chemicals. In addition, Oak...

  11. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Ken Rapp, Liyu Li, Jonathan Male, Dave King Pacific Northwest National...

  12. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  13. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  14. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (OFCVT). deer07rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Selectlive Catalytic Reducution of...

  15. ILENR/RE-AQ-ON-ROAD CARBON MONOXIDE AND HYDROCARBON

    E-Print Network [OSTI]

    Denver, University of

    #12;ILENR/RE-AQ- Printed: Contract: Project: ON-ROAD CARBON MONOXIDE AND HYDROCARBON REMOTE SENSING. Repeat Measurements of the Same Vehicle. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 F

  16. Mechanisms of Hydrocarbon Poisoning of A Urea SCR Catalyst

    Broader source: Energy.gov [DOE]

    Understanding what reactions and which catalytic functions are affected by hydrocarbons can lead to improved tolerances for selective catalytic reduction performance

  17. Continuous removal of polynuclear aromatics from hydrocarbon recycle oil

    SciTech Connect (OSTI)

    Bosserman, P.J.; Taniguchi, V.T.

    1992-06-23

    This patent describes an oil refining process. It comprises forming a liquid capable of solubilizing aromatic compounds having at least about 5 fused aromatic rings; and catalytically hydrocracking a hydrocarbon feedstock by: contacting the feedstock in a hydrocracking zone with added hydrogen and a hydrocracking zone with added hydrogen and a hydrocracking catalyst at a temperature and pressure sufficient to give a substantial conversion to lower boiling products; and condensing a hydrocarbon effluent from the hydrocracking zone and separating the condensed effluent into (AA) a low boiling hydrocarbon product and (BB) an unconverted hydrocarbon oil containing one or more fused polynuclear aromatic compounds.

  18. Methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Nelson, Lee O. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

    2009-02-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  19. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Lean NOx Catalysis Research and Development...

  20. Enhanced Anaerobic Digestion and Hydrocarbon Precursor Production from Sewage Sludge

    Office of Energy Efficiency and Renewable Energy (EERE)

    Breakout Session 2-C: Biogas and Beyond: Challenges and Opportunities for Advanced Biofuels from Wet-Waste FeedstocksEnhanced Anaerobic Digestion and Hydrocarbon Precursor Production from Sewage...

  1. Performance of a Thermally Stable Polyaromatic Hydrocarbon in...

    Office of Scientific and Technical Information (OSTI)

    Performance of a Thermally Stable Polyaromatic Hydrocarbon in a Simulated Concentrating Solar Power Loop Citation Details In-Document Search Title: Performance of a Thermally...

  2. Ozone production and hydrocarbon reactivity in Hong Kong, Southern China

    E-Print Network [OSTI]

    2007-01-01

    Middleton, P. , and Wang, T. : Ozone precursor relationshipsJ. Zhang et al. : Ozone production and hydrocarbonKiang, C. S. : Ground- level ozone pollution in Hong Kong,

  3. Fuel Cell Technologies Office Overview: 2015 Hydrogen, Hydrocarbons...

    Broader source: Energy.gov (indexed) [DOE]

    Introductory presentation by Sunita Satyapal, U.S. Department of Energy Fuel Cell Technologies Office Director, at the Hydrogen, Hydrocarbons, and Bioproduct Precursors from...

  4. Sandia Energy - ECIS-Automotive Fuel Cell Corporation: Hydrocarbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ECIS-Automotive Fuel Cell Corporation: Hydrocarbon Membrane Fuels the Success of Future Generation Vehicles Home Energy Transportation Energy CRF Partnership Energy Efficiency...

  5. Process for making unsaturated hydrocarbons using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Yuschak, Thomas (Lewis Center, OH); LaPlante, Timothy J. (Columbus, OH); Rankin, Scott (Columbus, OH); Perry, Steven T. (Galloway, OH); Fitzgerald, Sean Patrick (Columbus, OH); Simmons, Wayne W. (Dublin, OH); Mazanec, Terry (Solon, OH) Daymo, Eric (Dublin, OH)

    2011-04-12

    The disclosed invention relates to a process for converting a feed composition comprising one or more hydrocarbons to a product comprising one or more unsaturated hydrocarbons, the process comprising: flowing the feed composition and steam in contact with each other in a microchannel reactor at a temperature in the range from about 200.degree. C. to about 1200.degree. C. to convert the feed composition to the product, the process being characterized by the absence of catalyst for converting the one or more hydrocarbons to one or more unsaturated hydrocarbons. Hydrogen and/or oxygen may be combined with the feed composition and steam.

  6. Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to simultaneously reduce NOx and PM. Ex: HC poisoninginhibition on zeolites1, catalyst aging, etc. deer09devarakonda.pdf More Documents & Publications The Effects of Hydrocarbons...

  7. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathway This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion...

  8. Algal Lipid Extraction and Upgrading to Hydrocarbons Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Algal Lipid Extraction and...

  9. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified....

  10. Biological Conversion of Sugars to Hydrocarbons Technology Pathway...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pathway This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and...

  11. Fundamental measure theory of hydrated hydrocarbons

    E-Print Network [OSTI]

    Victor F. Sokolov; Gennady N. Chuev

    2006-04-13

    To calculate the solvation of hydrophobic solutes we have developed the method based on the fundamental measure treatment of the density functional theory. This method allows us to carry out calculations of density profiles and the solvation energy for various hydrophobic molecules with a high accuracy. We have applied the method to the hydration of various hydrocarbons (linear, branched and cyclic). The calculations of the entropic and the enthalpic parts are also carried out. We have examined a question about temperature dependence of the entropy convergence. Finally, we have calculated the mean force potential between two large hydrophobic nanoparticles immersed in water.

  12. Hydrocarbon synthesis catalyst and method of preparation

    DOE Patents [OSTI]

    Sapienza, Richard S. (Shoreham, NY); Sansone, Michael J. (Summit, NJ); Slegeir, William A. R. (Hampton Bays, NY)

    1983-08-02

    A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

  13. Hydrocarbon synthesis catalyst and method of preparation

    DOE Patents [OSTI]

    Sapienza, R.S.; Sansone, M.J.; Slegeir, W.A.R.

    1983-08-02

    A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint. 9 figs.

  14. Plasma-Hydrocarbon conversion - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access| DepartmentPeerFederal FleetUpSmallHydrocarbon conversion Idaho

  15. Gulf Hydrocarbon Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam: Energy Resources Jump to: navigation,LowGuinea:Hydrocarbon

  16. Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources

    SciTech Connect (OSTI)

    Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

    2008-10-01

    Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

  17. Effects of chemical additives on hydrocarbon disappearance and biodegradation in freshwater marsh microcosms

    E-Print Network [OSTI]

    Nyman, John

    determined the concentration of four total petroleum hydrocarbon (TPH) measures and 43 target hydro- carbonsEffects of chemical additives on hydrocarbon disappearance and biodegradation in freshwater marsh 2006 Hydrocarbon disappearance and biodegradation were insensitive to common commercial additives

  18. Stimulating the anaerobic degradation of aromatic hydrocarbons in contaminated sediments by providing

    E-Print Network [OSTI]

    Lovley, Derek

    Stimulating the anaerobic degradation of aromatic hydrocarbons in contaminated sediments to simulate the degradation of aromatic hydrocarbons in anaerobic contaminated sediments was investigated as the sole electron acceptor. Providing graphite electrodes as an electron acceptor in hydrocarbon

  19. Field metabolomics and laboratory assessments of anaerobic intrinsic bioremediation of hydrocarbons

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Field metabolomics and laboratory assessments of anaerobic intrinsic bioremediation of hydrocarbons the in situ anaerobic attenuation of hydrocarbons in a contaminated aquifer underly- ing a former refinery. Metabolite profiles associated with anaerobic hydrocarbon decay revealed the microbial utilization

  20. Lasius niger ants discriminate aphids based on their cuticular hydrocarbons Corsin Langa,1

    E-Print Network [OSTI]

    Richner, Heinz

    Lasius niger ants discriminate aphids based on their cuticular hydrocarbons Corsin Langa,1 chemical communication cuticular hydrocarbon interspecific communication Lasius niger mutualism species covered with aphid cuticular hydrocarbons. Neutral control objects were antennated, but the ants quickly

  1. HYDROCARBON LIQUID FLOW CALIBRATION SERVICE NIST Special Publication 250-1039

    E-Print Network [OSTI]

    Magee, Joseph W.

    HYDROCARBON LIQUID FLOW CALIBRATION SERVICE NIST Special Publication 250-1039 T. T. Yeh, Jesús and Technology Laboratory National Institute of Standards and Technology Gaithersburg, MD 20899 #12;Hydrocarbon......................................... 3 4.0 Description of the Hydrocarbon Liquid Flow Standard

  2. HYDROCARBONS OF BIOLOGICAL ORIGIN FROM A ONE-BILLION YEAR OLD SEDIMENT

    E-Print Network [OSTI]

    Eglinton, Geoffrey.; Scott, P.M.; Belsky, Ted.; Burlingame, A.L.; Calvin, Melvin.; Cloud Jr., Preston E.

    1964-01-01

    Contract No. W-7405-eng-48 HYDROCARBONS OF BIOLOGICAL ORIGINAbstract The isoprenoid hydrocarbons, phytane (C 20H4Z) andThe identification of these hydrocarbons augurs well for the

  3. Heterogeneous OH Oxidation of Motor Oil Particles Causes Selective Depletion of Branched and Less Cyclic Hydrocarbons

    E-Print Network [OSTI]

    Goldstein, Allen

    Cyclic Hydrocarbons Gabriel Isaacman,, * Arthur W. H. Chan, Theodora Nah, David R. Worton,,§ Chris R of hydrocarbon mixtures typical of anthropogenic atmospheric particulate matter, but its complexity often reaction rates of observed hydrocarbon classes: alkanes, cycloalkanes, bicycloalkanes, tricycloalkanes

  4. The Hydrophobic Effect Drives the Recognition of Hydrocarbons by an Anionic Metal-Ligand Cluster

    E-Print Network [OSTI]

    Biros, Shannon

    2009-01-01

    Drives the Recognition of Hydrocarbons by an Anionic Metal-Drives the Recognition of Hydrocarbons by an Anionic Metal-including saturated hydrocarbons, 11,12 in aqueous solution,

  5. Cyclic Versus Linear Isomers Produced by Reaction of the Methylidyne Radical (CH) with Small Unsaturated Hydrocarbons

    E-Print Network [OSTI]

    Goulay, Fabien

    2010-01-01

    with Small Unsaturated Hydrocarbons Fabien Goulay, 1, †,‡react with the selected hydrocarbon in a helium gas flow.Small cyclic unsaturated hydrocarbons such as c-C 3 H, c-C 3

  6. Isomeric differentiation of polycyclic aromatic hydrocarbons using silver nitrate reactive desorption electrospray ionization

    E-Print Network [OSTI]

    Zare, Richard N.

    Isomeric differentiation of polycyclic aromatic hydrocarbons using silver nitrate reactive hydrocarbons (PAHs) are nonpolar and difficult to detect by desorption electrospray ionization. We present. Polycyclic aromatic hydrocarbons (PAHs) are one of the most prevalent forms of aquatic environmental

  7. Adsorption of unsaturated hydrocarbons on zeolites: the eects of the zeolite framework on adsorption

    E-Print Network [OSTI]

    Truong, Thanh N.

    Adsorption of unsaturated hydrocarbons on zeolites: the eects of the zeolite framework industrially important reactions, namely the polymerization and hydrocarbon cracking processes [9 as a starting point for a more comprehensive study on hydrocarbon cracking and ethylene epoxidation reactions

  8. Process for the production of liquid hydrocarbons

    DOE Patents [OSTI]

    Bhatt, Bharat Lajjaram; Engel, Dirk Coenraad; Heydorn, Edward Clyde; Senden, Matthijis Maria Gerardus

    2006-06-27

    The present invention concerns a process for the preparation of liquid hydrocarbons which process comprises contacting synthesis gas with a slurry of solid catalyst particles and a liquid in a reactor vessel by introducing the synthesis gas at a low level into the slurry at conditions suitable for conversion of the synthesis gas into liquid hydrocarbons, the solid catalyst particles comprising a catalytic active metal selected from cobalt or iron on a porous refractory oxide carrier, preferably selected from silica, alumina, titania, zirconia or mixtures thereof, the catalyst being present in an amount between 10 and 40 vol. percent based on total slurry volume liquids and solids, and separating liquid material from the solid catalyst particles by using a filtration system comprising an asymmetric filtration medium (the selective side at the slurry side), in which filtration system the average pressure differential over the filtration medium is at least 0.1 bar, in which process the particle size distribution is such that at least a certain amount of the catalyst particles is smaller than the average pore size of the selective layer of the filtration medium. The invention also comprises an apparatus to carry out the process described above.

  9. A STEADY-STATE FEL: PARTICLE DYNAMICS IN THE FEL PORTION OF A TWO-BEAM ACCELERATOR

    E-Print Network [OSTI]

    Sternbach, E.

    2008-01-01

    September 8-13, 1985 A STEADY-STATE FEL: PARTICLE DYNAMICSIN THE FEL PORTION OF A TWO-BEAM ACCELERATOR E. SternbachLBL-19939 A STEADY-STATE FEL: PARTICLE DYNAMICS IN THE FEL

  10. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2001-01-01

    A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  11. ADHESION FORCES BETWEEN MICA SURFACES IN UNDERSATURATED VAPORS OF HYDROCARBONS

    E-Print Network [OSTI]

    Matsuoka, Hiroshige

    ADHESION FORCES BETWEEN MICA SURFACES IN UNDERSATURATED VAPORS OF HYDROCARBONS H. MATSUOKA1 , T] or meniscus force [3], which have been neglected in the conventional and relatively large mechani- cal systems forces between mica surfaces in under- saturated vapors of several kind of hydrocarbon liquids are mea

  12. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, H.; Blatter, F.; Sun, H.

    1999-06-22

    A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

  13. Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE and to install heat pumps in unoccupied spaces. Nevertheless manufacturers keep working on components for hydrocarbons. In the frame of a research project on heat pumps for simultaneous heating and cooling, an R407C

  14. Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    1999-01-01

    A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  15. Selective thermal oxidation of hydrocarbons in zeolites by oxygen

    DOE Patents [OSTI]

    Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

    2000-01-01

    A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

  16. The Impact of Low Octane Hydrocarbon Blending Streams on "E85...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization...

  17. Application of Metagenomics for Identification of Novel Petroleum Hydrocarbon Degrading Enzymes in Natural Asphalts from the Rancho La Brea Tar Pits

    E-Print Network [OSTI]

    Baquiran, Jean-Paul Mendoza

    2010-01-01

    of petroleum hydrocarbon-contaminated ground water: Theof petroleum hydrocarbon-contaminated ground water: The

  18. An investigation of the use of odorants in liquefied natural gas used as a vehicle fuel

    SciTech Connect (OSTI)

    Green, T.; Williams, T.

    1994-12-31

    Interest in liquefied natural gas (LNG) as an alternative vehicle fuel has increased significantly. Its greater storage density relative to compressed natural gas makes it an attractive option for both volume and weight constrained vehicle applications. The public transportation market, specifically transit bus properties, have been very aggressive in pursuing LNG as an alternative vehicle fuel. Naturally, when dealing with the general public and a new transportation fuel, the issue of safety must be addressed. With this in mind, the Gas Research Institute has initiated a number of safety related studies including an investigation of the use of odorants in LNG. This paper presents the preliminary results of an investigation performed by the Institute of Gas Technology to determine both the applicability and effectiveness of odorizing LNG. This includes an overview of the current state-of-the-art in LNG vehicle fueling and safety systems as well as a discussion of an LNG odorization program conducted by San Diego Gas & Electric in the mid 70`s. Finally, the paper discusses the results of the modeling effort to determine whether conventional odorants used in natural gas can be injected and remain soluble in LNG at temperatures and pressures encountered in LNG fueling and on-board storage systems.

  19. LNG plants in the US and abroad. [Liquefied Natural Gas (LNG)

    SciTech Connect (OSTI)

    Blazek, C.F.; Biederman, R.T.

    1992-01-01

    The Institute of Gas Technology recently conducted a comprehensive survey of LNG production and storage facilities in North America. This survey was performed as part of IGT's LNG Observer newsletter which covers both domestic and international LNG news, reports on LNG related economics and statistics, and routinely conducts interviews with key industry leaders. In addition to providing consulting services to the LNG industry, IGT has cosponsored the International Conference on Liquefied Natural Gas for the part 20 years. The objective of this paper is to present a summary of our recent survey results as well as provide an overview of world LNG trade. This information is important in assessing the potential near term availability of LNG for transportation applications. The IGT LNG Survey appraised the capacity and current market activity of LNG peak shaving, satellite storage, and import receiving facilities in the United States and Canada. Information was requested from facilities on three main topics: liquefaction, storage, and regasification. Additional questions were posed regarding the year of operation, designer/contractor for liquefaction cycle and storage, source of LNG (for storage-only facilities), plans for expansion, and level of interest in providing LNG as a vehicle fuel. The IGT LNG Survey has to date received information on 56 LNG peak shaving facilities, 28 satellite storage facilities, and 4 LNG import receiving terminals.

  20. Report on issues regarding the existing New York liquefied natural gas moratorium

    SciTech Connect (OSTI)

    1998-11-01

    The New York Energy Planning Board has prepared this study to provide the Governor and the Legislature with information necessary to determine the need for further extension or modification of the existing State moratorium on the siting of new liquefied natural gas (LNG) facilities and intrastate transportation routes as required by Chapter 385 of the laws of 1997. The report examines existing laws and regulations that would affect new LNG facilities in New York and government initiatives in other states. It reviews existing use of LNG in New York, including safety issues and potential public concerns that may arise with lifting the moratorium. It also discusses the economic and environmental effects of increased LNG usage for New York State. The study concludes that there are economic and environmental advantages for allowing the construction of new LNG facilities as well as the intrastate transportation of LNG over new routes. Additionally, it concludes that safety concerns associated with these facilities are adequately addressed by existing Federal, State and local statutes and regulations.

  1. Compressed natural gas and liquefied petroleum gas conversions: The National Renewable Energy Laboratory`s experience

    SciTech Connect (OSTI)

    Motta, R.C.; Kelly, K.J.; Warnock, W.W.

    1996-04-01

    The National Renewable Energy Laboratory (NREL) contracted with conversion companies in six states to convert approximately 900 light-duty Federal fleet vehicles to operate on compressed natural gas (CNG) or liquefied petroleum gas (LPG). The contracts were initiated in order to help the Federal government meet the vehicle acquisition requirements of the Energy Policy Act of 1992 (EPACT) during a period of limited original equipment manufacturer (OEM) model availability. Approximately 90% of all conversions were performed on compact of full-size vans and pickups, and 90% of the conversions were to bi-fuel operation. With a positive response from the fleet managers, this program helped the Federal government meet the vehicle acquisition requirements of EPACT for fiscal years 1993 and 1994, despite limited OEM model availability. The conversions also helped to establish the infrastructure needed to support further growth in the use of alternative fuel vehicles. In conclusion, the program has been successful in helping the Federal government meet the vehicle acquisition requirements of EPACT, establishing infrastructure, increasing the displacement of imported oil, and evaluating the emissions performance of converted vehicles. With the relatively widespread availability of OEM vehicles in the 1996 model year, the program is now being phased out.

  2. Microbial hydrocarbons: back to the future

    SciTech Connect (OSTI)

    Work, Victoria H.; Beliaev, Alex S.; Konopka, Allan; Posewitz, Matthew C.

    2012-03-01

    The defining challenge of energy research in the 21st century is the development and deployment of technologies for large-scale reconfiguration of global energy infrastructure. Modern society is built upon a concentrated yet finite reservoir of diverse hydrocarbons formed through the photosynthetic transformation of several hundred million years of solar energy. In human history, the fossil energy era will be short lived and never repeated. Although the timing of peak oil is extensively debated, it is an eventuality. It is, therefore, imperative that projections for both when it will occur and the degree to which supply will fall short of demand be taken into serious consideration, especially in the sectors of energy technology development, political and economic decision making, and societal energy usage. The requirement for renewable energy systems is no longer a point for discussion, and swift advances on many fronts are vital to counteract current and impending crises in both energy and the environment.

  3. Method and apparatus for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1985-04-16

    A method and apparatus for synthesizing a mixture of aliphatic alcohols having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further optionally includes Na ions present as substitutional cations in an amount of about 5 to 10 atom %. At a temperature of about 570 to 630/sup 0/K, and at pressures of about 20 to 50 atm, methanol and isobutanol are the predominant products and are produced in amounts of about 90 wt % of the total hydrocarbon mixture. 6 figs.

  4. System and process for upgrading hydrocarbons

    SciTech Connect (OSTI)

    Bingham, Dennis N.; Klingler, Kerry M.; Smith, Joseph D.; Turner, Terry D.; Wilding, Bruce M.

    2015-08-25

    In one embodiment, a system for upgrading a hydrocarbon material may include a black wax upgrade subsystem and a molten salt gasification (MSG) subsystem. The black wax upgrade subsystem and the MSG subsystem may be located within a common pressure boundary, such as within a pressure vessel. Gaseous materials produced by the MSG subsystem may be used in the process carried out within the black wax upgrade subsystem. For example, hydrogen may pass through a gaseous transfer interface to interact with black wax feed material to hydrogenate such material during a cracking process. In one embodiment, the gaseous transfer interface may include one or more openings in a tube or conduit which is carrying the black wax material. A pressure differential may control the flow of hydrogen within the tube or conduit. Related methods are also disclosed.

  5. Pyrochlore catalysts for hydrocarbon fuel reforming

    DOE Patents [OSTI]

    Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

    2012-08-14

    A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A2B2-y-zB'yB"zO7-.DELTA., where y>0 and z.gtoreq.0. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H2+CO) for fuel cells, among other uses.

  6. This article was published in the above mentioned Springer issue. The material, including all portions thereof, is protected by copyright;

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    gasoline is likely to interfere with naturally occur- ring microorganisms from fully expressing their aerobic catabolic potential towards hydrocarbons bioremediation. Keywords Bioremediation Á Ethanol Á pollutants can be inhibited or slowed by the presence of easily degradable substrates (Duetz et al. 1994a, b

  7. Hydrocarbon characterization experiments in fully turbulent fires.

    SciTech Connect (OSTI)

    Ricks, Allen; Blanchat, Thomas K.

    2007-05-01

    As the capabilities of numerical simulations increase, decision makers are increasingly relying upon simulations rather than experiments to assess risks across a wide variety of accident scenarios including fires. There are still, however, many aspects of fires that are either not well understood or are difficult to treat from first principles due to the computational expense. For a simulation to be truly predictive and to provide decision makers with information which can be reliably used for risk assessment the remaining physical processes must be studied and suitable models developed for the effects of the physics. The model for the fuel evaporation rate in a liquid fuel pool fire is significant because in well-ventilated fires the evaporation rate largely controls the total heat release rate from the fire. A set of experiments are outlined in this report which will provide data for the development and validation of models for the fuel regression rates in liquid hydrocarbon fuel fires. The experiments will be performed on fires in the fully turbulent scale range (> 1 m diameter) and with a number of hydrocarbon fuels ranging from lightly sooting to heavily sooting. The importance of spectral absorption in the liquid fuels and the vapor dome above the pool will be investigated and the total heat flux to the pool surface will be measured. The importance of convection within the liquid fuel will be assessed by restricting large scale liquid motion in some tests. These data sets will provide a sound, experimentally proven basis for assessing how much of the liquid fuel needs to be modeled to enable a predictive simulation of a fuel fire given the couplings between evaporation of fuel from the pool and the heat release from the fire which drives the evaporation.

  8. Non-Sticking of Helium Buffer Gas to Hydrocarbons

    E-Print Network [OSTI]

    Croft, James F E

    2014-01-01

    Lifetimes of complexes formed during helium-hydrocarbon collisions at low temperature are estimated for symmetric top hydrocarbons. The lifetimes are obtained using a density-of-states approach. In general the lifetimes are less than 10-100 ns, and are found to decrease with increasing hydrocarbon size. This suggests that clustering will not limit precision spectroscopy in helium buffer gas experiments. Lifetimes are computed for noble-gas benzene collisions and are found to be in reasonable agreement with lifetimes obtained from classical trajectories as reported by Cui {\\it et al}.

  9. Iraq`s significant hydrocarbon potential remains relatively undeveloped

    SciTech Connect (OSTI)

    AL-Gailani, M. [GeoDesign Ltd., Kingston-upon-Thames (United Kingdom)

    1996-07-29

    Iraq is probably one of the least explored countries in the Middle East, despite the fact that it possesses one of the richest hydrocarbon basins in the world almost on a par to Saudi Arabia`s potential, if not more. The aim of this article is to state the facts about Iraq and focus on the huge but untapped and undeveloped hydrocarbon resources to the international oil community. Perhaps it is best to start by describing briefly the sedimentary and tectonic elements responsible for accumulating such large hydrocarbon resources. The paper describes the basin, tectonic elements, structural anomalies, deep drilling, source rocks, reservoir rocks, characteristics, and new reserves.

  10. Petroleum potential of lower and middle Paleozoic rocks in Nebraska portion of Mid-Continent

    SciTech Connect (OSTI)

    Carlson, M.P. )

    1989-08-01

    Central North America during the Paleozoic was characterized by northern (Williston) and southern (Anadarko) depositional regimes separated by a stable Transcontinental arch. Nebraska lies on the southern flank of this arch and contains the northern zero edges of the lower and middle Paleozoic rocks of the southern regime. Most of these rocks are secondary dolomites with zones of excellent intercrystalline porosity. The Reagan-LaMotte Sandstones and the overlying Arbuckle dolomites are overlapped by Middle Ordovician rocks toward the Transcontinental arch. Rocks equivalent to the Simpson consist of a basal sand (St. Peter) and overlying interbedded gray-green shales and dolomitic limestones. An uppermost shale facies is present in the Upper Ordovician (Viola-Maquoketa) eastward and southward across Nebraska. The dolomite facies extends northward into the Williston basin. The Silurian dolomites, originally more widely deposited, are overlapped by Devonian dolomites in southeastern Nebraska. Upper Devonian rocks exhibit a regional facies change from carbonate to green-gray shale to black shale southeastward across the Mid-Continent. Mississippian carbonates overlap the Devonian westward and northward across the Transcontinental arch. Pennsylvanian uplift and erosion were widespread, producing numerous stratigraphic traps. Sands related to the basal Pennsylvanian unconformity produce along the Cambridge arch. Arbuckle, Simpson, Viola, and Hunton production is present in the Forest City basin and along the Central Kansas uplift. Although source rocks are scarce and the maturation is marginal, current theories of long-distance oil migration encourage exploration in the extensive lower and middle Paleozoic reservoirs in this portion of the Mid-Continent.

  11. Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

    E-Print Network [OSTI]

    Dennis, J A

    1971-01-01

    Energy loss characteristics of heavy ions in nitrogen, carbon dioxide, argon, hydrocarbon gases and tradescantia tissue

  12. Hydrocarbons on Harvester Ant (Pogonomyrmex barbatus) Middens Guide Foragers to the Nest

    E-Print Network [OSTI]

    Gordon, Deborah

    Hydrocarbons on Harvester Ant (Pogonomyrmex barbatus) Middens Guide Foragers to the Nest Shelby J hydrocarbons are used by social insects in nestmate recognition. Here, we showed that hydrocarbons found-specific hydrocarbons, which ants use to distinguish nestmates from non-nestmates, are found on the midden pebbles

  13. Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

    DOE Patents [OSTI]

    Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

    1999-05-25

    This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

  14. Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream

    DOE Patents [OSTI]

    Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

    1999-01-01

    This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

  15. AIR QUALITY IMPACTS OF LIQUEFIED NATURAL GAS IN THE SOUTH COAST AIR BASIN OF CALIFORNIA

    SciTech Connect (OSTI)

    Carerras-Sospedra, Marc; Brouwer, Jack; Dabdub, Donald; Lunden, Melissa; Singer, Brett

    2011-07-01

    The effects of liquefied natural gas (LNG) on pollutant emission inventories and air quality in the South Coast Air Basin of California were evaluated using recent LNG emission measurements by Lawrence Berkeley National Laboratory and the Southern California Gas Company (SoCalGas), and with a state-of-the-art air quality model. Pollutant emissions can be affected by LNG owing to differences in composition and physical properties, including the Wobbe index, a measure of energy delivery rate. This analysis uses LNG distribution scenarios developed by modeling Southern California gas flows, including supplies from the LNG receiving terminal in Baja California, Mexico. Based on these scenarios, the projected penetratino of LNG in the South Coast Air Basin is expected to be limited. In addition, the increased Wobbe index of delivered gas (resulting from mixtures of LNG and conventional gas supplies) is expected to cause increases smaller than 0.05 percent in overall (area-wide) emissions of nitrogen oxides (NOx). BAsed on the photochemical state of the South Coast Air Basin, any increase in NOx is expected to cause an increase in the highest local ozone concentrations, and this is reflected in model results. However, the magnitude of the increase is well below the generally accepted accuracy of the model and would not be discernible with the existing monitoring network. Modeling of hypothetical scenarios indicates that discernible changes to ambient ozone and particulate matter concentrations would occur only at LNG distribution rates that are not achievable with current or planned infrastructure and with Wobbe index vlaues that exceed current gas quality tariffs. Results of these hypothetical scenarios are presented for consideration of any proposed substantial expansion of LNG supply infrastructure in Southern California.

  16. Process for conversion of lignin to reformulated hydrocarbon gasoline

    DOE Patents [OSTI]

    Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

    1999-09-28

    A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

  17. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. acep03rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation...

  18. Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop

    Broader source: Energy.gov [DOE]

    The Hydrogen, Hydrocarbons, and Bioproduct Precursors from Wastewaters Workshop was held March 18–19, 2015, hosted at the U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory's Washington D.C. offices.

  19. Subcontinuum mass transport of condensed hydrocarbons in nanoporous media

    E-Print Network [OSTI]

    Falk, Kerstin

    Although hydrocarbon production from unconventional reservoirs, the so-called shale gas, has exploded recently, reliable predictions of resource availability and extraction are missing because conventional tools fail to ...

  20. Vertimass licenses ORNL biofuel-to-hydrocarbon conversion technology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    McCorkle Communications and Media Relations 865.574.7308 Vertimass licenses ORNL biofuel-to-hydrocarbon conversion technology Vertimass LLC, a California-based start-up...

  1. Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis

    SciTech Connect (OSTI)

    Ekechukwu, A.A.

    2002-05-10

    Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

  2. Process for converting light alkanes to higher hydrocarbons

    DOE Patents [OSTI]

    Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA)

    1988-01-01

    A process is disclosed for the production of aromatic-rich, gasoline boiling range hydrocarbons from the lower alkanes, particularly from methane. The process is carried out in two stages. In the first, alkane is reacted with oxygen and hydrogen chloride over an oxyhydrochlorination catalyst such as copper chloride with minor proportions of potassium chloride and rare earth chloride. This produces an intermediate gaseous mixture containing water and chlorinated alkanes. The chlorinated alkanes are contacted with a crystalline aluminosilicate catalyst in the hydrogen or metal promoted form to produce gasoline range hydrocarbons with a high proportion of aromatics and a small percentage of light hydrocarbons (C.sub.2 -C.sub.4). The light hydrocarbons can be recycled for further processing over the oxyhydrochlorination catalyst.

  3. Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels

    E-Print Network [OSTI]

    Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

    2012-01-01

    Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

  4. Petroleum hydrocarbon-degrading bacteria in the Galveston Bay system 

    E-Print Network [OSTI]

    Schropp, Steven James

    1979-01-01

    activities and shipping may all release petroleum hydrocarbons into the marine environment (83), which are potentially detrimental to the estuarine system. Estuaries have been found to be one of the most active types of water in terms of microbial... bacteria to oil inpiit might be used as an indicator or petroleuin pollution (6, 43, 44). To evaluate the effects of ) vllutant hydrocarbons ozi the bacterial populations of estuarine systems, information on the distribution and abundance...

  5. Integrated hydrocarbon reforming system and controls

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Dorson, Matthew H.; Mitchell, William L.; Nowicki, Brian J.; Thijssen, Johannes; Davis, Robert; Papile, Christopher; Rumsey, Jennifer W.; Longo, Nathan; Cross, III, James C.; Rizzo, Vincent; Kleeburg, Gunther; Rindone, Michael; Block, Stephen G.; Sun, Maria; Morriseau, Brian D.; Hagan, Mark R.; Bowers, Brian

    2003-11-04

    A hydrocarbon reformer system including a first reactor configured to generate hydrogen-rich reformate by carrying out at least one of a non-catalytic thermal partial oxidation, a catalytic partial oxidation, a steam reforming, and any combinations thereof, a second reactor in fluid communication with the first reactor to receive the hydrogen-rich reformate, and having a catalyst for promoting a water gas shift reaction in the hydrogen-rich reformate, and a heat exchanger having a first mass of two-phase water therein and configured to exchange heat between the two-phase water and the hydrogen-rich reformate in the second reactor, the heat exchanger being in fluid communication with the first reactor so as to supply steam to the first reactor as a reactant is disclosed. The disclosed reformer includes an auxiliary reactor configured to generate heated water/steam and being in fluid communication with the heat exchanger of the second reactor to supply the heated water/steam to the heat exchanger.

  6. Comparative analysis of liquefied natural gas (LNG) and compressed natural gas (CNG) used by transit agencies in Texas. Research report

    SciTech Connect (OSTI)

    Lede, N.W.

    1997-09-01

    This study is a detailed comparative analysis of liquefied natural gas (LNG) and compressed natural gas (CNG). The study provides data on two alternative fuels used by transit agencies in Texas. First, we examine the `state-of-the- art` in alternative fuels to established a framework for the study. Efforts were made to examine selected characteristics of two types of natural gas demonstrations in terms of the following properties: energy source characteristics, vehicle performance and emissions, operations, maintenance, reliability, safety costs, and fuel availability. Where feasible, two alternative fuels were compared with conventional gasoline and diesel fuel. Environmental considerations relative to fuel distribution and use are analyzed, with a focus on examining flammability an other safety-related issues. The objectives of the study included: (1) assess the state-of-the-art and document relevant findings pertaining to alternative fuels; (2) analyze and synthesize existing databases on two natural gas alternatives: liquefied natural gas (LNG) and compressed natural gas (CNG): and (3) compare two alterative fuels used by transit properties in Texas, and address selected aspects of alternative fuels such as energy source characteristics, vehicle performance and emissions, safety, costs, maintenance and operations, environmental and related issues.

  7. This article was published in the above mentioned Springer issue. The material, including all portions thereof, is protected by copyright;

    E-Print Network [OSTI]

    Kotiaho, Janne S.

    portions thereof, is protected by copyright; all rights are held exclusively by Springer Science + Business Received: 6 March 2009 / Accepted: 14 October 2009 / Published online: 31 October 2009 Ó Springer Science+Business locating the male in the wild is obvi- ously beneficial (e.g. Hack 1998; Kokko and Rankin 2006), most

  8. Ultra-High Performance Concrete with Tailored Properties Cementitious materials comprise a large portion of domestic structures and

    E-Print Network [OSTI]

    Nair, Sankar

    Ultra-High Performance Concrete with Tailored Properties Cementitious materials comprise a large portion of domestic structures and infrastructure. The development of ultra-high performance concrete control the performance of these materials. A nano- micro-meso scale cohesive finite element method (CFEM

  9. Cardiac toxicity of 5-ring polycyclic aromatic hydrocarbons is differentially dependent on the aryl hydrocarbon receptor 2 isoform during zebrafish development

    E-Print Network [OSTI]

    Cardiac toxicity of 5-ring polycyclic aromatic hydrocarbons is differentially dependent on the aryl hydrocarbon receptor 2 isoform during zebrafish development John P. Incardona , Tiffany L. Linbo, Nathaniel L aromatic hydrocarbons (PAHs), commonly occur as com- plex mixtures in the environment. Recent studies using

  10. IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater Revised and Updated. Part 7. C8H12C8H18 Hydrocarbons

    E-Print Network [OSTI]

    IUPAC-NIST Solubility Data Series. 81. Hydrocarbons with Water and Seawater Revised and Updated. Part 7. C8H12­C8H18 Hydrocarbons with Water Volume Editors David G. Shawa... University of Alaska on the evaluation of the all experimental data for a given homologous series of aliphatic and aromatic hydrocarbons

  11. ORGANIC GEOCHEMICAL STUDIES. II. THE DISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA, AND IN A RECENT LAKE SEDIMENT: A PRELIMINARY REPORT

    E-Print Network [OSTI]

    Han, Jerry; McCarthy, E.D.; Van Hoeven Jr., William; Calvin, Melvin; Bradley, W. H.

    2008-01-01

    significantly to the hydrocarbons of higher molecular weightDISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA,T E DISTRIBUTION O ALIPHATIC HYDROCARBONS H F A PRELIMINARY

  12. Hydrocarbon Seeps of the Mesozoic Great Valley Group Forearc Strata and Franciscan Complex, Northern and Central California, U.S.A.

    E-Print Network [OSTI]

    Keenan, Kristin Euphrat

    2010-01-01

    and Cretaceous Gastropods from Hydrocarbon Seeps in ForearcPeregrinella-Dominated Hydrocarbon-Seep Deposit on the1999. Signatures of Hydrocarbon Venting in a Middle Devonian

  13. Long-range transport of particulate polycyclic aromatic hydrocarbons at Cape Hedo remote island site in the East China Sea between 2005 and 2008

    E-Print Network [OSTI]

    2008-01-01

    of polycyclic aromatic hydrocarbons (PAHs) for 2004. Atmos.of polynuclear aromatic hydrocarbons in ambient air throughpolycyclic aromatic hydrocarbons in urban air of Hong Kong.

  14. Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

    E-Print Network [OSTI]

    2010-01-01

    Bohrmann, G. , 2007. In situ hydrocarbon concentrations fromM. , Bohrmann, G. , 2003. Hydrocarbon gases in deposits fromMethane and other hydrocarbon gases in marine sediment.

  15. Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids

    SciTech Connect (OSTI)

    Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

    2012-03-14

    Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X? = Cl?, Br?) generates ethyl halides via halogen atom abstraction from FeXn3?n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ?0.05 M X?. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 ± 0.5) × 106 M?1 s?1) and with FeBr2+ (k = (3.0 ± 0.5) × 107 M?1 s?1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

  16. Methane-derived hydrocarbons produced under upper-mantle conditions

    SciTech Connect (OSTI)

    Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.

    2009-08-13

    There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

  17. THE UNUSUAL HYDROCARBON EMISSION FROM THE EARLY CARBON STAR HD 100764: THE CONNECTION BETWEEN AROMATICS AND ALIPHATICS

    E-Print Network [OSTI]

    Sloan, Gregory C.

    THE UNUSUAL HYDROCARBON EMISSION FROM THE EARLY CARBON STAR HD 100764: THE CONNECTION BETWEEN disk. The spectrum shows emission features from polycyclic aro- matic hydrocarbons (PAHs shifts are consistent with hydrocarbon mixtures containing both aromatic and aliphatic bonds. We propose

  18. Quantitative Changes in Hydrocarbons over Time in Fecal Pellets of Incisitermes minor May Predict Whether Colonies Are Alive or Dead

    E-Print Network [OSTI]

    Lewis, Vernard R.; Nelson, Lori J.; Haverty, Michael I.; Baldwin, James A.

    2010-01-01

    termite species by the hydrocarbons in their feces. J. Chem.effects on the cuticular hydrocarbons of the host-specificG. J. 1990. Cuticular hydrocarbons of eight species of North

  19. Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels

    SciTech Connect (OSTI)

    Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

    2013-01-01

    Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

  20. Nutrient-stimulated biodegradation of aged refinery hydrocarbons in soil

    SciTech Connect (OSTI)

    Drake, E.N.; Stokley, K.E.; Calcavecchio, P.; Bare, R.E.; Rothenburger, S.J.; Prince, R.C. [Exxon Research and Engineering, Annandale, NJ (United States); Douglas, G.S. [Arthur D. Little, Inc., Cambridge, MA (United States)

    1995-12-31

    Aged hydrocarbon-contaminated refinery soil was amended with water and nutrients and tilled weekly for 1 year to stimulate biodegradation. Gas chromatography/mass spectrometry (GC/MS) analysis of polycyclic aromatic compounds (PAHs) and triterpane biomarkers, and Freon IR analysis of total petroleum hydrocarbons (TPH), were used to determine the extent of biodegradation. There was significant degradation of extractable hydrocarbon (up to 60%), but neither hopane, oleanane, nor the amount of polars decreased during this period of bioremediation, allowing them to be used as conserved internal markers for estimating biodegradation. Significant degradation of the more alkylated two- and three-ring compounds, and of the four-ring species pyrene and chrysene and their alkylated congeners, was seen. Substantial degradation (> 40%) of benzo(b)fluoranthene, benzo(k)fluoranthene, and benzo(a)pyrene also was seen. The results show that bioremediation can be a useful treatment in the cleanup of contaminated refinery sites.

  1. Process for light-driven hydrocarbon oxidation at ambient temperatures

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM)

    1990-01-01

    A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

  2. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Jones, Susanne B.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

  3. Method and apparatus for producing oxygenates from hydrocarbons

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Lessing, Paul A. (Idaho Falls, ID)

    1995-01-01

    A chemical reactor for oxygenating hydrocarbons includes: a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed.

  4. Hydrocarbon anions in interstellar clouds and circumstellar envelopes

    E-Print Network [OSTI]

    T. J. Millar; C. Walsh; M. A. Cordiner; R. Ní Chuimín; Eric Herbst

    2007-05-07

    The recent detection of the hydrocarbon anion C6H- in the interstellar medium has led us to investigate the synthesis of hydrocarbon anions in a variety of interstellar and circumstellar environments. We find that the anion/neutral abundance ratio can be quite large, on the order of at least a few percent, once the neutral has more than five carbon atoms. Detailed modeling shows that the column densities of C6H- observed in IRC+10216 and TMC-1 can be reproduced. Our calculations also predict that other hydrocarbon anions, such as C4H- and C8H-, are viable candidates for detection in IRC+10216, TMC-1 and photon-dominated regions such as the Horsehead Nebula.

  5. Guidance on risk analysis and safety implications of a large liquefied natural gas (LNG) spill over water.

    SciTech Connect (OSTI)

    Wellman, Gerald William; Melof, Brian Matthew; Luketa-Hanlin, Anay Josephine; Hightower, Marion Michael; Covan, John Morgan; Gritzo, Louis Alan; Irwin, Michael James; Kaneshige, Michael Jiro; Morrow, Charles W.

    2004-12-01

    While recognized standards exist for the systematic safety analysis of potential spills or releases from LNG (Liquefied Natural Gas) storage terminals and facilities on land, no equivalent set of standards or guidance exists for the evaluation of the safety or consequences from LNG spills over water. Heightened security awareness and energy surety issues have increased industry's and the public's attention to these activities. The report reviews several existing studies of LNG spills with respect to their assumptions, inputs, models, and experimental data. Based on this review and further analysis, the report provides guidance on the appropriateness of models, assumptions, and risk management to address public safety and property relative to a potential LNG spill over water.

  6. Method and apparatus for production of subsea hydrocarbon formations

    DOE Patents [OSTI]

    Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

    1995-01-01

    A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

  7. Low-Temperature Catalytic Process To Produce Hydrocarbons From Sugars

    DOE Patents [OSTI]

    Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

    2005-11-15

    Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as methanol, glycerol, sugars (e.g. glucose and xylose), or sugar alcohols (e.g. sorbitol). The method takes place in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.

  8. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, J.L.

    1987-07-07

    A continuous thermochemical indirect liquefaction process is described to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C[sub 7]-C[sub 17] paraffinic hydrocarbons having cetane indices of 50+. 1 fig.

  9. Manufacture of aromatic hydrocarbons from coal hydrogenation products

    SciTech Connect (OSTI)

    A.S. Maloletnev; M.A. Gyul'malieva [Institute for Fossil Fuels, Moscow (Russian Federation)

    2007-08-15

    The manufacture of aromatic hydrocarbons from coal distillates was experimentally studied. A flow chart for the production of benzene, ethylbenzene, toluene, and xylenes was designed, which comprised the hydrogen treatment of the total wide-cut (or preliminarily dephenolized) fraction with FBP 425{sup o}C; fractional distillation of the hydrotreated products into IBP-60, 60-180, 180-300, and 300-425{sup o}C fractions; the hydro-cracking of middle fractions for increasing the yield of gasoline fractions whenever necessary; the catalytic reform of the fractions with bp up to 180{sup o}C; and the extraction of aromatic hydrocarbons.

  10. Method for determining processability of a hydrocarbon containing feedstock

    DOE Patents [OSTI]

    Schabron, John F.; Rovani, Jr., Joseph F.

    2013-09-10

    Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

  11. Electrically heated particulate filter regeneration using hydrocarbon adsorbents

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-02-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material selectively heats exhaust passing through the upstream end to initiate combustion of particulates within the PF. A hydrocarbon adsorbent coating applied to the PF releases hydrocarbons into the exhaust to increase a temperature of the combustion of the particulates within the PF.

  12. Method and apparatus for production of subsea hydrocarbon formations

    DOE Patents [OSTI]

    Blandford, J.W.

    1995-01-17

    A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

  13. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, James L. (Scottsdale, AZ)

    1987-07-07

    A continuous thermochemical indirect liquefaction process to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C.sub.7 -C.sub.17 paraffinic hydrocarbons having cetane indices of 50+.

  14. Phase equilibria of polydisperse hydrocarbons: moment free energy method analysis

    E-Print Network [OSTI]

    Alessandro Speranza; Francesca Di Patti; Alessandro Terenzi

    2010-12-14

    We analyze the phase equilibria of systems of polydisperse hydrocarbons by means of the recently introduced moment method. Hydrocarbons are modelled with the Soave-Redlick-Kwong and Peng-Robinson equations of states. Numerical results show no particular qualitative difference between the two equations of states. Furthermore, in general the moment method proves to be an excellent method for solving phase equilibria of polydisperse systems, showing excellent agreement with previous results and allowing a great improvement in generality of the numerical scheme and speed of computation.

  15. A study of the solubility of mercury in liquid hydrocarbons 

    E-Print Network [OSTI]

    McFarlane, David Larimer

    1991-01-01

    A STUDY OF THE SOLUBILITY OF MERCURY IN LIQUID HYDROCARBONS A Thesis by DAVID LARIhKR MCFARLANE Submitted to the Oflice of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 1991 Major Subject: Nuclear Engineering A STUDY OF THE SOLUBILITY OF MERCURY IN LIQUID HYDROCARBONS A Thesis by DAVID LARI1VKR MCFARLANE Approved as to style and content by: W. H. Marlow (Chair of Committee) . W. Bevan (Member) . A...

  16. Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer

    E-Print Network [OSTI]

    2008-01-01

    areas of exploration geophysics including seismic imaging,seismic and electromagnetic modeling and inversion applied to hydrocarbon exploration.Seismic methods have a long and established history in hydrocarbon, i.e. oil and gas, exploration,

  17. Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon flamesq

    E-Print Network [OSTI]

    Senkan, Selim M.

    Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon classical light scattering measurement techniques. The experimental data revealed that the soot properties rights reserved. Keywords: Soot; Hydrocarbon flames; Artificial neural networks 1. Introduction

  18. Compositional differences in biomarker constituents of the hydrocarbon, resin, asphaltene and kerogen fractions

    E-Print Network [OSTI]

    Mills, Allen P.

    Compositional differences in biomarker constituents of the hydrocarbon, resin, asphaltene fraction, so biomarker parameters measured for different fractions are not directly comparable. The samples- tion are of equal magnitude to the quantities that are present in the extractable aliphatic hydrocarbon

  19. Assessment of natural and anthropogenic hydrocarbon inputs using PAHs as tracers.

    E-Print Network [OSTI]

    amounts of hydrocarbon compounds though combustion (liquid fuels, coal and wood), discharge of petroleum hydrocarbon sources from human activities including oil and refined oil products, burning of coal, liquid

  20. Light hydrocarbon geochemistry of brines and sediments of the red sea 

    E-Print Network [OSTI]

    Burke, Roger Allen

    1979-01-01

    -induced hydzccarbon po!. lution in the oceans [Bi"oaks and Sockett, 1973]; "sniffing" of light hydrocarbons to evaluate the oil producing potential of an area !Sackett, 1977]; and determination of light hydrocarbons in anoxic. waters [Bunt, 1974; Vtesenbpnp, 1975...

  1. An investigation of the thermal degradation mechanisms of a waste tire through chemical analysis including hydrocarbons, benzene derivatives, and Polycyclic

    E-Print Network [OSTI]

    Columbia University

    including hydrocarbons, benzene derivatives, and Polycyclic Aromatic Hydrocarbons (PAHs) at high temperature a GC/MS. Significant Volatile Organic Carbons (VOCs) including benzene derivatives, PAHs, and Hetero

  2. Recovery of co-adsorbed hydrocarbons from molecular sieve adsorption units

    SciTech Connect (OSTI)

    Clark, K.R.

    1990-11-20

    This patent describes a process for removing carbonyl sulfide from a hydrocarbon feedstock. It comprises: providing a feedstock of hydrocarbons; passing the feedstock in the liquid phase; terminating the passage; draining the bed; concurrently to the direction of flow into the bed; recovering the hydrocarbon; and regenerating the adsorption bed.

  3. UV absorption of CO2 for temperature diagnostics of hydrocarbon combustion applications

    E-Print Network [OSTI]

    Lee, Tonghun

    CO2 LIF [8], which for hydrocarbon combustion effluent can interfere with NO-LIF measurements [9UV absorption of CO2 for temperature diagnostics of hydrocarbon combustion applications J and 320 nm. Because CO2 is a major product of hydrocarbon combustion and because both the magnitude

  4. First detection of an ultraviolet transition in an ionized polycyclic aromatic hydrocarbon

    E-Print Network [OSTI]

    ; accepted 3 May 1999 We report the first measurement of a polycyclic aromatic hydrocarbon cation electronicFirst detection of an ultraviolet transition in an ionized polycyclic aromatic hydrocarbon Xavier D of Physics. S0021-9606 99 02226-6 I. INTRODUCTION Polycyclic aromatic hydrocarbon PAH ions are prom- ising

  5. A hydrocarbon ruler measures palmitate in the enzymatic acylation of endotoxin

    E-Print Network [OSTI]

    Bishop, Russell

    A hydrocarbon ruler measures palmitate in the enzymatic acylation of endotoxin Victoria E Ahn1 involve molecular measuring devices termed hydrocarbon rulers, but the molecular basis for acyl the hydrocarbon ruler mechanism for palmitate recognition. A striking structural similarity between Pag

  6. Chemical and isotopic analysis of hydrocarbon gas at trace levels Methodology and results

    E-Print Network [OSTI]

    Chappellaz, Jérôme

    -C-IRMS) permits measurement of relative proportions of gaseous hydrocarbon (CH4 to C4H10) and CO2 of hydrocarbons (from 1 ppm to 1000 ppm), accurate measurement of isotope ratios is often impossible dueChemical and isotopic analysis of hydrocarbon gas at trace levels Methodology and results Yvon

  7. Isomer discrimination of polycyclic aromatic hydrocarbons in the Murchison meteorite by resonant ionization

    E-Print Network [OSTI]

    de Vries, Mattanjah S.

    Isomer discrimination of polycyclic aromatic hydrocarbons in the Murchison meteorite by resonant between isomers of polycyclic aromatic hydrocarbons in the Murchison meteorite. We measured the 2C-R2PI: Resonant ionization; Jet cooling; Mass spectrometry; Polycyclic aromatic hydrocarbons; Murchison meteorite

  8. Rapid uplift of nonmethane hydrocarbons in a cold front over central Europe

    E-Print Network [OSTI]

    Hoskins, Brian

    Rapid uplift of nonmethane hydrocarbons in a cold front over central Europe R. M. Purvis,1 A. C of 21 C2­C7 nonmethane hydrocarbons (NMHCs) has been determined in planetary boundary layer (PBL between the PBL and FT was observed for all short and medium lifetime hydrocarbons (e.g., average iso

  9. Hydrocarbon Signatures of Egg Maternity, Caste Membership and Reproductive Status in the Common Wasp

    E-Print Network [OSTI]

    Wenseleers, Tom

    Hydrocarbon Signatures of Egg Maternity, Caste Membership and Reproductive Status in the Common-laid and worker-laid eggs has never been investigated. Our aim, therefore, was to investigate if hydrocarbons on the surface of newly-laid eggs, and that there are pronounced quantitative differences in the hydrocarbon

  10. Hydrocarbons emitted by waggle-dancing honey bees stimulate colony foraging activity by causing experienced

    E-Print Network [OSTI]

    Hydrocarbons emitted by waggle-dancing honey bees stimulate colony foraging activity by causing of the hydrocarbons emitted by waggle-dancing bees are investigated in this study. First, we test the hypothesis itself. waggle dance / cuticular hydrocarbon / nectar foraging / semiochemical / pheromone 1

  11. Polycyclic Aromatic Hydrocarbons (PAHs), nitrated PAHs and oxygenated PAHs in ambient air of the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Polycyclic Aromatic Hydrocarbons (PAHs), nitrated PAHs and oxygenated PAHs in ambient air + particle phases) of 16 polycyclic aromatic hydrocarbons (PAHs), 17 nitrated PAHs (NPAHs) and 9 oxygenated when (before or during the sampling) the OPAHs are formed. Keywords: Polycyclic aromatic hydrocarbons

  12. Author's personal copy Temporal and spatial trends of total petroleum hydrocarbons in the seawater

    E-Print Network [OSTI]

    Ma, Lena

    Author's personal copy Temporal and spatial trends of total petroleum hydrocarbons in the seawater hydrocarbons Bohai Bay Temporal and spatial trends Seawater a b s t r a c t The temporal and spatial distribution of total petroleum hydrocarbons (TPH) in the seawater of Tianjin Bohai Bay during 1996

  13. Research article The role of cuticular hydrocarbons as chemical cues for nestmate recognition in

    E-Print Network [OSTI]

    Tsutsui, Neil Durie

    Research article The role of cuticular hydrocarbons as chemical cues for nestmate recognition of cuticular hydrocarbons (CHCs) in nestmate recognition of this highly damaging invasive ant using three super of hydrocarbons trans- ferred to individual ants and performed gas chromatogra- phy-mass spectrometry (GC

  14. Hydrocarbon Characteristics in Fusion Edge Plasmas from Electron-Molecule and Ion-Surface Collision Experiments

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 EX/P4-1 Hydrocarbon Characteristics in Fusion Edge Plasmas from Electron- Molecule and Ion proceeding in the volume before and at the wall. Surface processes involving hydrocarbons and their ions, which are probable vacuum contaminants in plasma devices, and the role of hydrocarbon chemistry

  15. Influence of Hydrocarbons Exposure on Survival, Growth and Condition of Juvenile Flatfish: A Mesocosm Experiment

    E-Print Network [OSTI]

    Boyer, Edmond

    Influence of Hydrocarbons Exposure on Survival, Growth and Condition of Juvenile Flatfish experiments were conducted to determine whether short (24 h) but high exposure to petroleum hydrocarbons (1 to petroleum hydro- carbons and in particular Polycyclic Aromatic Hydrocarbons (PAHs). PAHs are regarded

  16. Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of

    E-Print Network [OSTI]

    Canberra, University of

    Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Port Phillip Bay of aromatic hydrocarbons in coastal waters, using solvent extraction and fluorescence emission analysis, shows and the Yarra River estuary. Introduction Pollution of the marine environment by petroleum hydrocarbons

  17. Selective oxidation of hydrocarbons in a catalytic dense membrane reactor: Catalytic properties of BIMEVOX (Me = Ta)

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Selective oxidation of hydrocarbons in a catalytic dense membrane reactor: Catalytic properties for syngas or H2 production from light hydrocarbons. #12;2 Keywords: Dense membrane reactor, BIMEVOX, BITAVOX to decouple the two steps of the redox mechanism that prevails in selective oxidation of hydrocarbons [1

  18. Quantitative traits loci (QTL) involved in body colour, wing morphometry, cuticular hydrocarbons

    E-Print Network [OSTI]

    Quantitative traits loci (QTL) involved in body colour, wing morphometry, cuticular hydrocarbons for wing morphometry, 12 for cuticular hydrocarbons and five for venom components. We detected 50 QTL / cuticular hydrocarbons / venom 1. INTRODUCTION The first genetic map built from RAPD markers (Hunt and Page

  19. EIGENVALUES OF SATURATED HYDROCARBONS D. J. KLEIN AND C. E. LARSON

    E-Print Network [OSTI]

    Larson, Craig E.

    EIGENVALUES OF SATURATED HYDROCARBONS D. J. KLEIN AND C. E. LARSON Abstract. A simplified H¨uckel-type molecular-orbital (MO) model for the valence electrons of saturated hydrocarbons is proposed and half negative. Keywords: saturated hydrocarbons, alkanes, stellation, para-line graph. 1. Saturated

  20. Prediction of Solid Polycyclic Aromatic Hydrocarbons Solubility in Water with the NRTL-PR Model

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Prediction of Solid Polycyclic Aromatic Hydrocarbons Solubility in Water with the NRTL-PR Model of solid polycyclic aromatic hydrocarbons in water. For this purpose, we first validate our methodology for fluid phase equilibria predictions of aromatic hydrocarbons and gas (CO2, C2H6) mixtures. Finally, we

  1. Quantification of OH and HO2 radicals during the lowtemperature oxidation of hydrocarbons by

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Quantification of OH and HO2 radicals during the lowtemperature oxidation of hydrocarbons of hydrocarbons and biofuels is of critical importance to allow the development of new combustion) but has never been applied to real hydrocarbons and lowtemperature oxidation. H atoms (10

  2. UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS

    E-Print Network [OSTI]

    UPTAKE AND LOSS OF PETROLEUM HYDROCARBONS BY THE MUSSEL, MYTILUS EDULIS, IN LABORATORY EXPERIMENTS ROBERT C. CLARK, JR., AND JOHN S. FINLEY' ABSTRACT Petroleum paraffin hydrocarbons (n-CI4H30 to n-C37H76 system that simulated tides. The mussels were exposed to levels of petroleum hydrocarbons from a surface

  3. Author's personal copy The sedimentary fluxes of polycyclic aromatic hydrocarbons in the

    E-Print Network [OSTI]

    Zheng, Mei

    Author's personal copy The sedimentary fluxes of polycyclic aromatic hydrocarbons in the Yangtze aromatic hydrocarbons (PAHs) in two 210 Pb dated sediment cores from the coastal East China Sea, strongly flux; Source; Yangtze River Estuary coastal sea 1. Introduction Polycyclic aromatic hydrocarbons (PAHs

  4. Identification and Characterization of Cuticular Hydrocarbons from a Rapid Species Radiation of Hawaiian

    E-Print Network [OSTI]

    Mullen, Sean P.

    Identification and Characterization of Cuticular Hydrocarbons from a Rapid Species Radiation Island taxa represents the loss of ancestral hydrocarbons found on Maui. To test this hypothesis, we characterized and identified the structures of cuticular hydrocarbons for seven species of Hawaiian Laupala, two

  5. Cuticular hydrocarbons mediate discrimination of reproductives and nonreproductives in the ant

    E-Print Network [OSTI]

    Danchin, Etienne

    Cuticular hydrocarbons mediate discrimination of reproductives and nonreproductives in the ant Contributed by Bert Ho¨ lldobler, July 9, 2003 In many species of social insects, the cuticular hydrocarbons of long-chained hydrocarbons present both on the cuticle and in the postpharyngeal gland. The purified

  6. The Aryl Hydrocarbon Receptor sans Xenobiotics: Endogenous Function in Genetic Model Systems

    E-Print Network [OSTI]

    Bradfield, Christopher A.

    MINIREVIEW The Aryl Hydrocarbon Receptor sans Xenobiotics: Endogenous Function in Genetic Model, 2007 ABSTRACT For more than 30 years, the aryl hydrocarbon receptor [Ah receptor (AHR)] has been. The aryl hydrocarbon receptor [Ah receptor (AHR)] is a founding member of the basic-helix-loop-helix (b

  7. Computational Physics (Computational) : Oral Atomistic Simulation of Di#usion of Hydrocarbons in

    E-Print Network [OSTI]

    Adler, Joan

    Computational Physics (Computational) : Oral Atomistic Simulation of Di#usion of Hydrocarbons, due to their unique structure and stability. This project deals with the transport of hydrocarbons to animate di#usion of hydrocarbons inside the carbon nanotube, in order to observe typical features

  8. Received 21 Dec 2013 | Accepted 3 Apr 2014 | Published 8 May 2014 Subfemtosecond steering of hydrocarbon

    E-Print Network [OSTI]

    Kling, Matthias

    of hydrocarbon deprotonation through superposition of vibrational modes A.S. Alnaser1,2,3, M. Ku¨bel4, R pathways for the laser-driven synthesis of chemical products. The break-up of the C-H bond in hydrocarbons is an ubiquitous process during laser-induced dissociation. While the yield of the deprotonation of hydrocarbons

  9. DEUTERATED INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS1 E. Peeters,2,3

    E-Print Network [OSTI]

    DEUTERATED INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS1 E. Peeters,2,3 L. J. Allamandola,3 C. W aromatic hydrocarbons (PAHs). Two bands are detected in the infrared emission from the ionization bar fluorescence from UV-pumped, large polycyclic aromatic hydrocarbon molecules (PAHs; Allamandola, Tielens

  10. Comparison of bond character in hydrocarbons and fullerenes D. W. Snoke

    E-Print Network [OSTI]

    Snoke, David

    Comparison of bond character in hydrocarbons and fullerenes D. W. Snoke Department of Physics a comparison of the bond polarizabilities for carbon-carbon bonds in hydrocarbons and fullerenes, using two and ethylene. We find that the polarizabilities for single bonds in fullerenes and hydrocarbons compare well

  11. Journal of Chemical Ecology, Vol. 28, No. 5, May 2002 (C 2002) EVALUATION OF SYNTHETIC HYDROCARBONS

    E-Print Network [OSTI]

    Hanks, Lawrence M.

    Journal of Chemical Ecology, Vol. 28, No. 5, May 2002 (C 2002) EVALUATION OF SYNTHETIC HYDROCARBONS of five straight-chain hydrocarbons (C24, C25, C26, C28, C30) to detached elytra of the red milkweed, and placed them in an exposed location outdoors. The amount of hydrocarbons on the elytra did not change over

  12. Cuticular Hydrocarbons: Species and Population-Level Discrimination in Termites1

    E-Print Network [OSTI]

    Cuticular Hydrocarbons: Species and Population-Level Discrimination in Termites1 Michael I. Haverty Marion Page Barbara L. Thorne Pierre Escoubas2 Abstract: Hydrocarbons in the cuticle of insects and the apparent species-specificity of cuticular hydrocarbon mixtures make them excellent taxo nomic characters

  13. Interfacial effects in a two-phase partitioning bioreactor: degradation of polycyclic aromatic hydrocarbons (PAHs)

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    hydrocarbons (PAHs) by a hydrophobic Mycobacterium Carolan T. MacLeod, Andrew J. Daugulis* Department 18 June 2004 Abstract The growth of Mycobacterium PYR-1 on polycyclic aromatic hydrocarbons (PAHs Bioreactor; Hydrophobicity 1. Introduction Polycyclic aromatic hydrocarbons (PAHs), many of which possess

  14. A second-generation reactive empirical bond order (REBO) potential energy expression for hydrocarbons

    E-Print Network [OSTI]

    Zhigilei, Leonid V.

    for hydrocarbons This article has been downloaded from IOPscience. Please scroll down to see the full text article-generation reactive empirical bond order (REBO) potential energy expression for hydrocarbons Donald W Brenner1 , Olga, lengths, and force constants for hydrocarbon molecules, as well as elastic properties, interstitial defect

  15. FT-ICR reaction study of bimetallic clusters with alcohol and hydrocarbon

    E-Print Network [OSTI]

    Maruyama, Shigeo

    FT-ICR reaction study of bimetallic clusters with alcohol and hydrocarbon Satoshi Yoshinaga beam source [1]. In order to investigate the initial reaction of alcohol or hydrocarbon with a metal reaction of catalysts with carbon containing molecules, such as alcohol and hydrocarbon. Fig. 1 shows mass

  16. Obstacles and Call to Action as a result of the Sept. 22nd and 23rd Biofuels Sustainability portion of the conference.

    E-Print Network [OSTI]

    Kyte, Michael

    Group 1 Obstacles and Call to Action as a result of the Sept. 22nd and 23rd Biofuels Sustainability. 22nd and 23rd Biofuels Sustainability portion of the confer- ence. #12;Group 3 Obstacles and Call to Action as a result of the Sept. 22nd and 23rd Biofuels Sustainability portion of the conference

  17. Fundamental spectroscopic studies of carbenes and hydrocarbon radicals

    SciTech Connect (OSTI)

    Gottlieb, C.A.; Thaddeus, P. [Harvard Univ., Cambridge, MA (United States)

    1993-12-01

    Highly reactive carbenes and carbon-chain radicals are studied at millimeter wavelengths by observing their rotational spectra. The purpose is to provide definitive spectroscopic identification, accurate spectroscopic constants in the lowest vibrational states, and reliable structures of the key intermediates in reactions leading to aromatic hydrocarbons and soot particles in combustion.

  18. Formation mechanism for polycyclic aromatic hydrocarbons in methane flames

    E-Print Network [OSTI]

    Sattler, Klaus

    applications including heating systems and gas turbines for electric power generation.62­64 The combustion of natural gas methane is a clean and efficient process. While gas turbines operating with methane pollution than other hydrocarbon fuels. Therefore, gas turbines pow- ered by methane are promising

  19. Original article Hydrocarbons and monoesters of propolis waxes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Hydrocarbons and monoesters of propolis waxes from Brazil Giuseppina Negri* Maria; accepted 20 April 1998) Abstract - Waxes of 23 samples of propolis of Apis mellifera mostly from Brazil of propolis wax is similar to that of comb wax, which suggests that propolis waxes are probably secreted

  20. Whole Ecosystem Measurements of Biogenic Hydrocarbon Emissions Final Report

    E-Print Network [OSTI]

    Goldstein, Allen

    Whole Ecosystem Measurements of Biogenic Hydrocarbon Emissions Final Report ARB Award No. 98 the automated in-situ gas chromatograph system for measuring volatile organic compound mixing ratios. Other and Outlook at the Beginning of This Study............... 4 2.0 Field Measurement Site........................................................

  1. Modeling the biodegradability and physicochemical properties of polycyclic aromatic hydrocarbons 

    E-Print Network [OSTI]

    Dimitriou-Christidis, Petros

    2006-10-30

    .67c a From Howard and Meylan (1997). b From SRC (2005). c From Mackay et al. (1992). logK = aRI + b (2.1) where K is a... Bill Batchelor Kirby C. Donnelly Thomas J. McDonald David V. Rosowsky August 2005 Major Subject: Civil Engineering iii ABSTRACT Modeling the Biodegradability and Physicochemical Properties of Polycyclic Aromatic Hydrocarbons...

  2. Hydrocarbon Processing`s process design and optimization `96

    SciTech Connect (OSTI)

    NONE

    1996-06-01

    This paper compiles information on hydrocarbon processes, describing the application, objective, economics, commercial installations, and licensor. Processes include: alkylation, ammonia, catalytic reformer, crude fractionator, crude unit, vacuum unit, dehydration, delayed coker, distillation, ethylene furnace, FCCU, polymerization, gas sweetening, hydrocracking, hydrogen, hydrotreating (naphtha, distillate, and resid desulfurization), natural gas processing, olefins, polyethylene terephthalate, refinery, styrene, sulfur recovery, and VCM furnace.

  3. Hydrocarbon saturation determination using acoustic velocities obtained through casing

    DOE Patents [OSTI]

    Moos, Daniel (Houston, TX)

    2010-03-09

    Compressional and shear velocities of earth formations are measured through casing. The determined compressional and shear velocities are used in a two component mixing model to provides improved quantitative values for the solid, the dry frame, and the pore compressibility. These are used in determination of hydrocarbon saturation.

  4. Enhanced reactive metal wall for dehalogenation of hydrocarbons

    DOE Patents [OSTI]

    Howson, P.E.; Mackenzie, P.D.; Horney, D.P.

    1996-08-06

    A method is provided for remediation of contaminated solutions using a tiered metal wall or column. The tiered metal wall or column has at least three zones with graduated sizes of reducing metal particles. Contaminated solutions pass through the tiered wall or column to dehalogenate contaminant halogenated hydrocarbons. 3 figs.

  5. Aryl hydrocarbon receptor-dependent liver development and hepatotoxicity are

    E-Print Network [OSTI]

    Bradfield, Christopher A.

    ,3,7,8-tetrachlorod- ibenzo-p-dioxin (dioxin), and vascular remodeling of the develop- ing embryo. To test of the liver in response to dioxin exposure. Taken together, these data illustrate the importance of cell recombinase ductus venosus endothelial cell hepatocyte dioxin The aryl hydrocarbon receptor (AHR) is a basic

  6. The toxicity of certain new chlorinated hydrocarbons to cotton pests 

    E-Print Network [OSTI]

    Merkl, Marvin Eugene

    1953-01-01

    THE TOXICITY OF CERTAIN NEW CHLORINATED HYDROCARBONS TO COTTON PESTS A Dissertation 5y MARVIN EUGENE MERKL Approved as to style and content by: Chairman of CouBlttee Head of Departnent May 19*3 THE TOXICITY OF CERTAIN NEW CHLORINATED... .....................................................78 CONCLUSIONS............................................... ..81 BIBLIOGRAPHI .............................................. ..82 Pag? FIGURES 1* Dosage-?ortality curve for the toxicity of endrin to aphids...

  7. Biodegradation of Bicyclic and Polycyclic Aromatic Hydrocarbons in

    E-Print Network [OSTI]

    Rockne, Karl J.

    Biodegradation of Bicyclic and Polycyclic Aromatic Hydrocarbons in Anaerobic Enrichments K A R L J contaminated sediments are anaerobic. With recent results demonstrating that some bicyclics and PAHs can for aerobic cultures. These results show that bicyclics and PAHs can be biodegraded under nitrate- and sulfate

  8. Ethanol Distribution, Dispensing, and Use: Analysis of a Portion of the Biomass-to-Biofuels Supply Chain Using System Dynamics

    SciTech Connect (OSTI)

    Vimmerstedt, L. J.; Bush, B.; Peterson, S.

    2012-05-01

    The Energy Independence and Security Act of 2007 targets use of 36 billion gallons of biofuels per year by 2022. Achieving this may require substantial changes to current transportation fuel systems for distribution, dispensing, and use in vehicles. The U.S. Department of Energy and the National Renewable Energy Laboratory designed a system dynamics approach to help focus government action by determining what supply chain changes would have the greatest potential to accelerate biofuels deployment. The National Renewable Energy Laboratory developed the Biomass Scenario Model, a system dynamics model which represents the primary system effects and dependencies in the biomass-to-biofuels supply chain. The model provides a framework for developing scenarios and conducting biofuels policy analysis. This paper focuses on the downstream portion of the supply chain-represented in the distribution logistics, dispensing station, and fuel utilization, and vehicle modules of the Biomass Scenario Model. This model initially focused on ethanol, but has since been expanded to include other biofuels. Some portions of this system are represented dynamically with major interactions and feedbacks, especially those related to a dispensing station owner's decision whether to offer ethanol fuel and a consumer's choice whether to purchase that fuel. Other portions of the system are modeled with little or no dynamics; the vehicle choices of consumers are represented as discrete scenarios. This paper explores conditions needed to sustain an ethanol fuel market and identifies implications of these findings for program and policy goals. A large, economically sustainable ethanol fuel market (or other biofuel market) requires low end-user fuel price relative to gasoline and sufficient producer payment, which are difficult to achieve simultaneously. Other requirements (different for ethanol vs. other biofuel markets) include the need for infrastructure for distribution and dispensing and widespread use of high ethanol blends in flexible-fuel vehicles.

  9. Process for preparing a liquid fuel composition

    DOE Patents [OSTI]

    Singerman, Gary M. (Monroeville, PA)

    1982-03-16

    A process for preparing a liquid fuel composition which comprises liquefying coal, separating a mixture of phenols from said liquefied coal, converting said phenols to the corresponding mixture of anisoles, subjecting at least a portion of the remainder of said liquefied coal to hydrotreatment, subjecting at least a portion of said hydrotreated liquefied coal to reforming to obtain reformate and then combining at least a portion of said anisoles and at least a portion of said reformate to obtain said liquid fuel composition.

  10. Gas turbine engine adapted for use in combination with an apparatus for separating a portion of oxygen from compressed air

    DOE Patents [OSTI]

    Bland, Robert J. (Oviedo, FL); Horazak, Dennis A. (Orlando, FL)

    2012-03-06

    A gas turbine engine is provided comprising an outer shell, a compressor assembly, at least one combustor assembly, a turbine assembly and duct structure. The outer shell includes a compressor section, a combustor section, an intermediate section and a turbine section. The intermediate section includes at least one first opening and at least one second opening. The compressor assembly is located in the compressor section to define with the compressor section a compressor apparatus to compress air. The at least one combustor assembly is coupled to the combustor section to define with the combustor section a combustor apparatus. The turbine assembly is located in the turbine section to define with the turbine section a turbine apparatus. The duct structure is coupled to the intermediate section to receive at least a portion of the compressed air from the compressor apparatus through the at least one first opening in the intermediate section, pass the compressed air to an apparatus for separating a portion of oxygen from the compressed air to produced vitiated compressed air and return the vitiated compressed air to the intermediate section via the at least one second opening in the intermediate section.

  11. Process for coal liquefaction using electrodeposited catalyst

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA)

    1978-01-01

    A process for the liquefaction of solid hydrocarbonaceous materials is disclosed. Particles of such materials are electroplated with a metal catalyst and are then suspended in a hydrocarbon oil and subjected to hydrogenolysis to liquefy the solid hydrocarbonaceous material. A liquid product oil is separated from residue solid material containing char and the catalyst metal. The catalyst is recovered from the solid material by electrolysis for reuse. A portion of the product oil can be employed as the hydrocarbon oil for suspending additional particles of catalyst coated solid carbonaceous material for hydrogenolysis.

  12. Sensing behaviour of nanosized zinc-tin composite oxide towards liquefied petroleum gas and ethanol

    SciTech Connect (OSTI)

    Singh, Ravi Chand; Singh, Onkar; Singh, Manmeet Pal; Chandi, Paramdeep Singh; Thangaraj, R.

    2010-09-15

    A chemical route has been used to synthesize composite oxides of zinc and tin. An ammonia solution was added to equal amounts of zinc and tin chloride solutions of same molarities to obtain precipitates. Three portions of these precipitates were annealed at 400, 600 and 800 {sup o}C, respectively. Results of X-ray diffraction and transmission electron microscopy clearly depicted coexistence of phases of nano-sized SnO{sub 2}, ZnO, Zn{sub 2}SnO{sub 4} and ZnSnO{sub 3}. The effect of annealing on structure, morphology and sensing has been observed as well. It has been observed that annealing promoted growth of Zn{sub 2}SnO{sub 4} and ZnSnO{sub 3} at the expense of zinc. The sensing response of fabricated sensors from these materials to 250 ppm LPG and ethanol has been investigated. The sensor fabricated from powder annealed at 400 {sup o}C responded better to LPG than ethanol.

  13. Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot-scale

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot ethanol release (E100, 76 l) onto residual hydrocarbons in sandy soil was evaluated in a continuous-flow 8 hydrocarbons mobilized by ethanol. Growth of hydrocarbon degrad- ers was corroborated by denaturing gradient

  14. QSAR model of the phototoxicity of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro, Marcia Miguel Castro Ferreira*

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    QSAR model of the phototoxicity of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro of 67 polycyclic aromatic hydrocarbons (PAHs) is performed and a prediction rule for the phototoxicity be produced from saturated hydrocarbons under oxygen-deficient conditions. Hydrocarbons with very low

  15. Hydrocarbon reaction with HF-cleaned Si(lOQ) and effects on metal-oxide-semiconductor device quality

    E-Print Network [OSTI]

    Rubloff, Gary W.

    Hydrocarbon reaction with HF-cleaned Si(lOQ) and effects on metal-oxide-semiconductor device-cleaned Si( 100) towards hydrocarbon adsorption is examined by surface analysis; most hydrocarbons adsorb oxidation after HF treatment.4'5 In this letter, passivation against hydrocarbon contamination is studied

  16. Ambient aromatic hydrocarbon measurements at Welgegund, South Africa

    SciTech Connect (OSTI)

    Jaars, K.; Beukes, J. P.; van Zyl, P. G.; Venter, A. D.; Josipovic, M.; Pienaar, J. J.; Vakkari, Ville; Aaltonen, H.; Laakso, H.; Kulmala, M.; Tiitta, P.; Guenther, Alex B.; Hellen, H.; Laakso, L.; Hakola, H.

    2014-07-11

    Aromatic hydrocarbons are associated with direct adverse human health effects and can have negative impacts on ecosystems due to their toxicity, as well as indirect negative effects through the formation of tropospheric ozone and secondary organic aerosol that affect human health, crop production and regional climate. Measurements were conducted at the Welgegund measurement station (South Africa) that is considered to be a regionally representative background site. However, the site is occasionally impacted by plumes from major anthropogenic source regions in the interior of South Africa, which include the western Bushveld Igneous Complex (e.g. platinum, base metal and ferrochrome smelters), the eastern Bushveld Igneous Complex (platinum and ferrochrome smelters), the Johannesburg-Pretoria metropolitan conurbation (>10 million people), the Vaal Triangle (e.g. petrochemical and industries), the Mpumalanga Highveld (e.g. coal-fired power plants and petrochemical industry) and also a region of anti-cyclonic recirculation of air mass over the interior of South Africa. The aromatic hydrocarbon measurements were conducted with an automated sampler on Tenax-TA and Carbopack-B adsorbent tubes with heated inlet for one year. Samples were collected twice a week for two hours during daytime and two hours 1 during night-time. A thermal desorption unit, connected to a gas chromatograph and a mass 2 selective detector was used for sample preparation and analysis. Results indicated that the 3 monthly median total aromatic hydrocarbon concentrations ranged between 0.01 to 3.1 ppb. 4 Benzene levels did not exceed local air quality standards. Toluene was the most abundant 5 species, with an annual median concentration of 0.63 ppb. No statistically significant 6 differences in the concentrations measured during daytime and night-time were found and no distinct seasonal patterns were observed. Air mass back trajectory analysis proved that the lack of seasonal cycles could be attributed to patterns determining the origin of the air masses sampled. Aromatic hydrocarbon concentrations were in general significantly higher in air masses that passed over anthropocentrically impacted regions. Interspecies correlations and ratios gave some indications of the possible sources for the different aromatic hydrocarbons in the source regions defined in the paper. The highest contribution of aromatic hydrocarbon concentrations to ozone formation potential was also observed in plumes passing over anthropocentrically impacted regions.

  17. Comparison of hydrocarbon production trends in Middle and Upper members of Minnelusa formation

    SciTech Connect (OSTI)

    Reel, C.L.; Horne, J.C.; Kelly, A.O.

    1985-05-01

    The main reservoir rocks in the upper and middle members of the Minnelusa Formation consist of wind blown dunal sands in the area surrounding the Lusk embayment. Changes in the local depositional setting, tectonic framework, and eustatic sea level controlled the distribution and reservior quality of these sandstones. The middle member exhibits two production trends. Age-equivalent Tensleep rocks deposited along the western margin of the embayment produce from sandstones accumulated in a sand sea paleoenvironment. Structure is atnececessary for trapping owing to permeability continuity. Along the eastern margin of the embayment, production comes from isolated accumulations of sandstone deposited as dunes on broad coastal sabkhas. Fields in these sandstones define a linear trend due to the coast-parallel alignment of these dunes. Production from the upper member defines four major trends. Upper member sandstones in the southern part of the basin, similar to Leo reservoirs, produce from sediments deposited as coast-parallel dunes in a northwest-southeast alignment. In the northern portion of the basin, production is from sandstones deposited in broad, flat eolian sand seas. Because of the permeability continuity of these sandstones, structural closure is necessary for trapping hydrocarbons. Upper member production has been influenced by the unconformity developed at the top of the Minnelusa. Movement along the Rosebud arch resulted in a southwest-northeast production trend apparent in each sandstone unit reflecting their northwestward erosional limits. The last, and most apparent, production trend, results from the Opeche Shale infilling of northwest-southeast-oriented stream valleys. Most production to date has been from sandstones following this alignment juxta-posed downdip of these impermeable shales.

  18. Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Davis, Ryan; Biddy, Mary J.; Jones, Susanne B.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

  19. Apparatus for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, G.A.; Thomas, C.P.

    1996-02-13

    A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

  20. Method for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

    1995-01-01

    A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

  1. Apparatus for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

    1996-01-01

    A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

  2. Catalysts for conversion of methane to higher hydrocarbons

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1993-01-01

    Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

  3. Biological Conversion of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Davis, Ryan; Biddy, Mary J.; Tan, Eric; Tao, Ling; Jones, Susanne B.

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the biological conversion of biomass derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

  4. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, W.; Flytzani-Stephanopoulos, M.

    1996-03-19

    A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  5. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

    1996-01-01

    A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  6. Method for direct conversion of gaseous hydrocarbons to liquids

    DOE Patents [OSTI]

    Kong, Peter C.; Lessing, Paul A.

    2006-03-07

    A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.

  7. Method for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, G.A.; Thomas, C.P.

    1995-10-03

    A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

  8. Process for forming a long gas turbine engine blade having a main wall with a thin portion near a tip

    SciTech Connect (OSTI)

    Campbell, Christian X; Thomaidis, Dimitrios

    2014-05-13

    A process is provided for forming an airfoil for a gas turbine engine involving: forming a casting of a gas turbine engine airfoil having a main wall and an interior cavity, the main wall having a wall thickness extending from an external surface of the outer wall to the interior cavity, an outer section of the main wall extending from a location between a base and a tip of the airfoil casting to the tip having a wall thickness greater than a final thickness. The process may further involve effecting movement, using a computer system, of a material removal apparatus and the casting relative to one another such that a layer of material is removed from the casting at one or more radial portions along the main wall of the casting.

  9. THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS

    SciTech Connect (OSTI)

    Ricca, Alessandra; Bauschlicher, Charles W. Jr.; Allamandola, Louis J. E-mail: Charles.W.Bauschlicher@nasa.gov

    2013-10-10

    The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

  10. SEISMIC EVALUATION OF HYDROCARBON SATURATION IN DEEP-WATER RESERVOIRS

    SciTech Connect (OSTI)

    Michael Batzle; D-h Han; R. Gibson; Huw James

    2005-01-22

    During this last quarter of the ''Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs'' project (Grant/Cooperative Agreement DE-FC26-02NT15342), we have moved forward on several fronts, including data acquisition as well as analysis and application. During this quarter we have: (1) Completed our site selection (finally); (2) Measured fluid effects in Troika deep water sand sample; (3) Applied the result to Ursa ''fizz gas'' zone; (4) Compared thin layer property averaging on AVO response; (5) Developed target oriented NMO stretch correction; (6) Examined thin bed effects on A-B crossplots; and (7) Begun incorporating outcrop descriptive models in seismic forward models. Several factors can contribute to limit our ability to extract accurate hydrocarbon saturations in deep water environments. Rock and fluid properties are one factor, since, for example, hydrocarbon properties will be considerably different with great depths (high pressure) when compared to shallow properties. Significant over pressure, on the other hand will make the rocks behave as if they were shallower. In addition to the physical properties, the scale and tuning will alter our hydrocarbon indicators. Reservoirs composed of thin bed effects will broaden the reflection amplitude distribution with incident angle. Normal move out (NMO) stretch corrections based on frequency shifts can be applied to offset this effect. Tuning will also disturb the location of extracted amplitudes on AVO intercept and gradient (A-B) plots. Many deep water reservoirs fall this tuning thickness range. Our goal for the remaining project period is to systematically combine and document these various effects for use in deep water exploration.

  11. Hydrocarbon Processing`s Advanced control and information systems `95

    SciTech Connect (OSTI)

    NONE

    1995-09-01

    This special report presents control strategies and information systems for most hydrocarbon processes and plants. Each summary (76 in all) contains information on application, control strategy, economics, commercial installations, and licensor. The processes include NGL recovery, alkylation, blending, catalytic reforming, caustic treating, cryogenic separation, delayed coking, fractionation, hydrocracking, hydrogen production, isomerization, lube oil extraction, oil transport and storage, pipeline management, information management, sulfur recovery, waste water treatments, and others.

  12. Irregular spacing of heat sources for treating hydrocarbon containing formations

    SciTech Connect (OSTI)

    Miller, David Scott; Uwechue, Uzo Philip

    2012-06-12

    A method for treating a hydrocarbon containing formation includes providing heat input to a first section of the formation from one or more heat sources located in the first section. Fluids are produced from the first section through a production well located at or near the center of the first section. The heat sources are configured such that the average heat input per volume of formation in the first section increases with distance from the production well.

  13. Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons

    DOE Patents [OSTI]

    Fliermans, Carl B. (Augusta, GA)

    1989-01-01

    A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

  14. Production of valuable hydrocarbons by flash pyrolysis of oil shale

    DOE Patents [OSTI]

    Steinberg, M.; Fallon, P.T.

    1985-04-01

    A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

  15. Method and apparatus for production of subsea hydrocarbon formations

    SciTech Connect (OSTI)

    Blandford, Joseph W.

    1992-01-01

    A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and expert riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

  16. Method and apparatus for production of subsea hydrocarbon formations

    DOE Patents [OSTI]

    Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

    1994-01-01

    A well tender system for controlling, separating, storing and offloading well fluids produced from subsea hydrocarbon formations. The system comprises a vertically aligned series of tethered cylindrical tanks which are torsionally stabilized by flexible catenary production riser and export riser bundles, and serviced by separate catenary pipe bundles. Piles are secured to the seabed, each pile assembly being pivotally connected to a lower rigid tendon, which is in turn connected to tendons arranged about the periphery of the interconnected cylindrical tanks.

  17. Direct production of fractionated and upgraded hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Felix, Larry G.; Linck, Martin B.; Marker, Terry L.; Roberts, Michael J.

    2014-08-26

    Multistage processing of biomass to produce at least two separate fungible fuel streams, one dominated by gasoline boiling-point range liquids and the other by diesel boiling-point range liquids. The processing involves hydrotreating the biomass to produce a hydrotreatment product including a deoxygenated hydrocarbon product of gasoline and diesel boiling materials, followed by separating each of the gasoline and diesel boiling materials from the hydrotreatment product and each other.

  18. Polycyclic aromatic hydrocarbon distributions in Mississippi Fan sediments 

    E-Print Network [OSTI]

    Sandberg, William Allan

    1986-01-01

    on fractionation of carbon in phytoplankton; 3) the alteration of organic matter's isotopic composition during degradation and diagenesis; 4) upward and/or lateral migration of petrogenic hydrocarbons into shallower sediments; 5) anomalous isotopic compositions... ? acenaphthene fluorene phenanthrene/anthracene Gr-3 rings fluoranthene, pyr'ene benz(a)anthracene, chrysene benzopyrenes, perylene ?drz-perylene dibenzanthracenes (*internal standards) Gas GhromatograIrhv Injector: 300 C, splitless mode Total Run...

  19. Finding hydrocarbons in the classroom using "free" seismic interpretation software

    E-Print Network [OSTI]

    Engineering and Sciences at MTU has a large number of Sun workstations in research labs and undergraduate and graduate computer lab rooms. The processing portion of this course used the Sun network as it stood Macintoshes and PCs already existed in a variety of locations). Instead, we purchased a powerful dual

  20. Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels

    SciTech Connect (OSTI)

    University of Central Florida

    2004-01-30

    The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

  1. SEISMIC EVALUATION OF HYDROCARBON SATURATION IN DEEP-WATER RESERVOIRS

    SciTech Connect (OSTI)

    M. Batzle; D-h Han; R. Gibson; O. Djordjevic

    2003-03-20

    The ''Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs'' (Grant/Cooperative Agreement DE-FC26-02NT15342) began September 1, 2002. During this second quarter: A Direct Hydrocarbon Indicator (DHI) symposium was held at UH; Current DHI methods were presented and forecasts made on future techniques; Dr. Han moved his laboratory from HARC to the University of Houston; Subcontracts were re-initiated with UH and TAMU; Theoretical and numerical modeling work began at TAMU; Geophysical Development Corp. agreed to provide petrophysical data; Negotiations were begun with Veritas GDC to obtain limited seismic data; Software licensing and training schedules were arranged with Paradigm; and Data selection and acquisition continues. The broad industry symposium on Direct Hydrocarbon Indicators was held at the University of Houston as part of this project. This meeting was well attended and well received. A large amount of information was presented, not only on application of the current state of the art, but also on expected future trends. Although acquisition of appropriate seismic data was expected to be a significant problem, progress has been made. A 3-D seismic data set from the shelf has been installed at Texas A&M University and analysis begun. Veritas GDC has expressed a willingness to provide data in the deep Gulf of Mexico. Data may also be available from TGS.

  2. Hydrocarbon reforming catalyst material and configuration of the same

    DOE Patents [OSTI]

    Singh, Prabhakar (Export, PA); Shockling, Larry A. (Plum Borough, PA); George, Raymond A. (Pittsburgh, PA); Basel, Richard A. (Plub Borough, PA)

    1996-01-01

    A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall.

  3. Hydrocarbon reforming catalyst material and configuration of the same

    DOE Patents [OSTI]

    Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

    1996-06-18

    A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

  4. Simultaneous boiling and spreading of liquefied petroleum gas on water. Final report, December 12, 1978-March 31, 1981

    SciTech Connect (OSTI)

    Chang, H.R.; Reid, R.C.

    1981-04-01

    An experimental and theoretical investigation was carried out to study the boiling and spreading of liquid nitrogen, liquid methane and liquefied petroleum gas (LPG) on water in a one-dimensional configuration. Primary emphasis was placed on the LPG studies. Experimental work involved the design and construction of a spill/spread/boil apparatus which permitted the measurement of spreading and local boil-off rates. With the equations of continuity and momentum transfer, a mathematical model was developed to describe the boiling-spreading phenomena of cryogens spilled on water. The model accounted for a decrease in the density of the cryogenic liquid due to bubble formation. The boiling and spreading rates of LPG were found to be the same as those of pure propane. An LPG spill was characterized by the very rapid and violent boiling initially and highly irregular ice formation on the water surface. The measured local boil-off rates of LPG agreed reasonably well with theoretical predictions from a moving boundary heat transfer model. The spreading velocity of an LPG spill was found to be constant and determined by the size of the distributor opening. The maximum spreading distance was found to be unaffected by the spilling rate. These observations can be explained by assuming that the ice formation on the water surface controls the spreading of LPG spills. While the mathematical model did not predict the spreading front adequately, it predicted the maximum spreading distance reasonably well.

  5. Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs

    SciTech Connect (OSTI)

    Michael Batzle

    2006-04-30

    During this last period of the ''Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs'' project (Grant/Cooperative Agreement DE-FC26-02NT15342), we finalized integration of rock physics, well log analysis, seismic processing, and forward modeling techniques. Most of the last quarter was spent combining the results from the principal investigators and come to some final conclusions about the project. Also much of the effort was directed towards technology transfer through the Direct Hydrocarbon Indicators mini-symposium at UH and through publications. As a result we have: (1) Tested a new method to directly invert reservoir properties, water saturation, Sw, and porosity from seismic AVO attributes; (2) Constrained the seismic response based on fluid and rock property correlations; (3) Reprocessed seismic data from Ursa field; (4) Compared thin layer property distributions and averaging on AVO response; (5) Related pressures and sorting effects on porosity and their influence on DHI's; (6) Examined and compared gas saturation effects for deep and shallow reservoirs; (7) Performed forward modeling using geobodies from deepwater outcrops; (8) Documented velocities for deepwater sediments; (9) Continued incorporating outcrop descriptive models in seismic forward models; (10) Held an open DHI symposium to present the final results of the project; (11) Relations between Sw, porosity, and AVO attributes; (12) Models of Complex, Layered Reservoirs; and (14) Technology transfer Several factors can contribute to limit our ability to extract accurate hydrocarbon saturations in deep water environments. Rock and fluid properties are one factor, since, for example, hydrocarbon properties will be considerably different with great depths (high pressure) when compared to shallow properties. Significant over pressure, on the other hand will make the rocks behave as if they were shallower. In addition to the physical properties, the scale and tuning will alter our hydrocarbon indicators. Gas saturated reservoirs change reflection amplitudes significantly. The goal for the final project period was to systematically combine and document these various effects for use in deep water exploration and transfer this knowledge as clearly and effectively as possible.

  6. Thermochemistry for Hydrocarbon Intermediates Chemisorbed on Metal Surfaces: CHn-m(CH3)m with n ) 1, 2, 3 and m e n on Pt, Ir,

    E-Print Network [OSTI]

    Goddard III, William A.

    Thermochemistry for Hydrocarbon Intermediates Chemisorbed on Metal Surfaces: CHn-m(CH3)m with n ) 1 hydrocarbon rearrangements on transition metal surfaces, we report systematic studies of hydrocarbon radicals for hydrocarbons on metal surfaces similar to the Benson scheme so useful for gas-phase hydrocarbons. This is used

  7. Apparatus and method for rapid separation and detection of hydrocarbon fractions in a fluid stream

    DOE Patents [OSTI]

    Sluder, Charles S.; Storey, John M.; Lewis, Sr., Samuel A.

    2013-01-22

    An apparatus and method for rapid fractionation of hydrocarbon phases in a sample fluid stream are disclosed. Examples of the disclosed apparatus and method include an assembly of elements in fluid communication with one another including one or more valves and at least one sorbent chamber for removing certain classifications of hydrocarbons and detecting the remaining fractions using a detector. The respective ratios of hydrocarbons are determined by comparison with a non separated fluid stream.

  8. Overcoming Hydrocarbon Inhibition on Pd-based Diesel Oxidation Catalysts with Rational Catalyst Design Approach

    Broader source: Energy.gov [DOE]

    Discusses results of a project focused on overcoming hydrocarbon inhibition on Pd-based diesel oxidation catalysts by using a rational catalyst design approach.

  9. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support of HCCI Emission Control

    Broader source: Energy.gov [DOE]

    Development of catalyst materials to facilitate the low-temperature oxidation of hydrocarbons and CO in homogeneous charge compression ignition (HCCI) emissions.

  10. Nonthermal plasma systems and methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C.; Nelson, Lee O.; Detering, Brent A.

    2005-05-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  11. Variability of gas composition and flux intensity in natural marine hydrocarbon seeps

    E-Print Network [OSTI]

    Clark, Jordan F.; Washburn, Libe; Schwager Emery, Katherine

    2010-01-01

    and the fallout plume of heavy oil from strong petroleumCH 4 ) and other heavy hydrocarbons including oil, to the

  12. Origin of gaseous hydrocarbons in east-central Texas groundwaters 

    E-Print Network [OSTI]

    Coffman, Bryan Keith

    1988-01-01

    in flow direction due to pumping at the Bryan well fields (after Follett, 1974). 13 6 Structure map on the top of the Queen City Formation and approximate thickness of sand containing fresh to slightly saline water in Brazos and Burleson Counties... The approximate ' C/ C ratios produced from or associated with different sources (1-4) and sinks (5) of COs . 41 5 Well owners, location of sample outlet, head gas abundance and casing material for wells sampled in this study. 53 6 Hydrocarbon concentration...

  13. Catalysts and process for liquid hydrocarbon fuel production

    DOE Patents [OSTI]

    White, Mark G; Liu, Shetian

    2014-12-09

    The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.

  14. Hydrocarbon Gas Liquids (HGL): Recent Market Trends and Issues

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See full Hydrocarbon Gas Liquids (HGL):

  15. Preliminary Economics for Hydrocarbon Fuel Production from Cellulosic Sugars

    SciTech Connect (OSTI)

    Collett, James R.; Meyer, Pimphan A.; Jones, Susanne B.

    2014-05-18

    Biorefinery process and economic models built in CHEMCAD and a preliminary, genome-scale metabolic model for the oleaginous yeast Lipomyces starkeyi were used to simulate the bioconversion of corn stover to lipids, and the upgrading of these hydrocarbon precursors to diesel and jet fuel. The metabolic model was based on the recently released genome sequence for L. starkeyi and on metabolic pathway information from the literature. The process model was based on bioconversion, lipid extraction, and lipid oil upgrading data found in literature, on new laboratory experimental data, and on yield predictions from the preliminary L. starkeyi metabolic model. The current plant gate production cost for a distillate-range hydrocarbon fuel was estimated by the process model Base Case to be $9.5/gallon ($9.0 /gallon of gasoline equivalent) with assumptions of 2011$, 10% internal return on investment, and 2205 ton/day dry feed rate. Opportunities for reducing the cost to below $5.0/gallon, such as improving bioconversion lipid yield and hydrogenation catalyst selectivity, are presented in a Target Case. The process and economic models developed for this work will be updated in 2014 with new experimental data and predictions from a refined metabolic network model for L. starkeyi. Attaining a production cost of $3.0/gallon will require finding higher value uses for lignin other than power generation, such as conversion to additional fuel or to a co-product.

  16. SEISMIC EVALUATION OF HYDROCARBON SATURATION IN DEEP-WATER RESERVOIRS

    SciTech Connect (OSTI)

    Michael Batzle; D-h Han; R. Gibson; Huw James

    2005-08-12

    We are now entering the final stages of our ''Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs'' project (Grant/Cooperative Agreement DE-FC26-02NT15342). We have now developed several techniques to help distinguish economic hydrocarbon deposits from false ''Fizz'' gas signatures. These methods include using the proper in situ rock and fluid properties, evaluating interference effects on data, and doing better constrained inversions for saturations. We are testing these techniques now on seismic data from several locations in the Gulf of Mexico. In addition, we are examining the use of seismic attenuation as indicated by frequency shifts below potential reservoirs. During this quarter we have: Began our evaluation of our latest data set over the Neptune Field; Developed software for computing composite reflection coefficients; Designed and implemented stochastic turbidite reservoir models; Produced software & work flow to improve frequency-dependent AVO analysis; Developed improved AVO analysis for data with low signal-to-noise ratio; and Examined feasibility of detecting fizz gas using frequency attenuation. Our focus on technology transfer continues, both by generating numerous presentations for the upcoming SEG annual meeting, and by beginning our planning for our next DHI minisymposium next spring.

  17. Reaction of Si(111) Surface with Saturated Hydrocarbon

    SciTech Connect (OSTI)

    Suryana, Risa; Nakahara, Hitoshi; Saito, Yahachi; Ichimiya, Ayahiko

    2011-12-10

    Reaction of Si(111) surface with saturated hydrocarbon such as methane (CH{sub 4}) and ethane (C{sub 2}H{sub 6}) was carried out in a gas source molecular beam epitaxy (GSMBE). After carbonization, structures formed on the surface were observed by in situ reflection high-energy electron diffraction (RHEED). Structures transition formed on the surface were 7x7, {delta}-7x7, 1x1, and SiC structures. In the case of CH{sub 4}, the Si surfaces were carbonized at 800 deg. C for 120 min (7.2x10{sup 4} L) with a W-filament of 2800 deg. C, and SiC layers were obtained. In the case of C{sub 2}H{sub 6}, the mixture of 7x7 and SiC structure was observed. Decomposition of hydrocarbon was characterized in quadrupole mass spectroscopy (QMS) measurements. An atomic force microscopy (AFM) image of the mixture of 7x7 and SiC shows a wandering shape. Whereas, the SiC layer shows a regular step. This result seems to be related to the different in the amount of CH{sub 3} molecules on the surface.

  18. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOE Patents [OSTI]

    Ruka, R.J.; Basel, R.A.

    1996-03-12

    A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

  19. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

    2007-12-25

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  20. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

    1996-01-01

    A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

  1. aliphatic hydrocarbons constitute the largest fraction of cuticular wax in bees and cover

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    aliphatic hydrocarbons constitute the largest fraction of cuticular wax in bees and cover a highly hydrocarbons in the cuticular waxes of bees are widely assumed to func- tion as recognition cues (for nestmate discriminate cuticular waxes based on esters and polar components Birgit FRÖHLICHa, Markus RIEDERERa, Jürgen

  2. Modeling and History Matching Hydrocarbon Production from Marcellus Shale using Data Mining and Pattern Recognition Technologies

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    SPE 161184 Modeling and History Matching Hydrocarbon Production from Marcellus Shale using Data. The abstract must contain conspicuous acknowledgment of SPE copyright. Abstract The Marcellus Shale play has a novel approach to modeling, history matching of hydrocarbon production from a Marcellus shale asset

  3. The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil Point, California

    E-Print Network [OSTI]

    Washburn, Libe

    The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil pollution sources. A field of strong hydrocarbon seepage offshore of Coal Oil Point near Santa Barbara in the Coal Oil Point field to measure directly the atmospheric gas flux from three seeps of varying size

  4. Hydrocarbon contamination in waters and sediments of the Pertusillo freshwater reservoir, Val d'Agri,

    E-Print Network [OSTI]

    D'Orsogna, Maria Rita

    Hydrocarbon contamination in waters and sediments of the Pertusillo freshwater reservoir, Val d contamination of drinking water in the Southern Italian region of Basilicata and to identify its source, we to determine temporal variability of water quality. In the present study, metals and hydrocarbons were

  5. Author's personal copy Temporal and spatial trends of total petroleum hydrocarbons in the seawater

    E-Print Network [OSTI]

    Ma, Lena

    (Zhou et al., 2004). Petroleum hydrocarbons as priority organic contaminants are extremely complexAuthor's personal copy Temporal and spatial trends of total petroleum hydrocarbons in the seawater-Environmental Protection Institute, Ministry of Agriculture, Tianjin 300191, China c Soil and Water Science Department

  6. 2007-01-0472 Particulate and Hydrocarbon Emissions from a Spray Guided

    E-Print Network [OSTI]

    1 2007-01-0472 Particulate and Hydrocarbon Emissions from a Spray Guided Direct Injection Spark-out emissions. In this work, the effect of blending methanol and ethanol with gasoline on unburned hydrocarbon number concentration and size distribution were measured using a Cambustion DMS500. These data

  7. Characterization of hydrocarbon and mixed layers in TEXTOR by laser induced ablation spectroscopy

    E-Print Network [OSTI]

    Giesen, Thomas

    Characterization of hydrocarbon and mixed layers in TEXTOR by laser induced ablation spectroscopy) 014026 (4pp) doi:10.1088/0031-8949/2011/T145/014026 Characterization of hydrocarbon and mixed layers systematic laser-induced ablation spectroscopy (LIAS) measurements carried out on various surface layers

  8. SPE 159255-PP Rock Classification from Conventional Well Logs in Hydrocarbon-Bearing

    E-Print Network [OSTI]

    Torres-Verdín, Carlos

    SPE 159255-PP Rock Classification from Conventional Well Logs in Hydrocarbon-Bearing Shale Andrew C typing method for application in hydrocarbon-bearing shale (specifically source rock) reservoirs using-hoc correlations where the interpretation becomes a core matching exercise. Scale effects on measurements

  9. Z .Marine Chemistry 64 1999 8597 Chlorinated hydrocarbon pesticides and polychlorinated biphenyls

    E-Print Network [OSTI]

    van Geen, Alexander

    Z .Marine Chemistry 64 1999 85­97 Chlorinated hydrocarbon pesticides and polychlorinated biphenyls Richardson and San Pablo Bays in San Francisco Bay, CA, were analyzed for a suite of chlorinated hydrocarbon of 1969­1974. The first measurable DDT levels are found in sediment deposited in the late 1930's

  10. Optical reflectivity of solid and liquid methane: Application to spectroscopy of Titan's hydrocarbon lakes

    E-Print Network [OSTI]

    Jacobsen, Steven D.

    's hydrocarbon lakes Kimberly A. Adams,1 Steven D. Jacobsen,1 Zhenxian Liu,2 Sylvia-Monique Thomas,1,3 Maddury revealed dark patches in the surface reflectance at 2 and 5 mm, interpreted as hydrocarbon lakes forming) on dynamic planetary surfaces requires laboratory reflectance ratio measurements at relevant temperatures

  11. Value of information in parameter identification and optimization of hydrocarbon reservoirs

    E-Print Network [OSTI]

    Van den Hof, Paul

    Value of information in parameter identification and optimization of hydrocarbon reservoirs E-based optimization and model-parameter identification applied to large-scale models of subsurface hydrocarbon with water injection. The results are compared with previous work on other measures of information valuation

  12. Rapid uplift of nonmethane hydrocarbons in a cold front over central Europe

    E-Print Network [OSTI]

    Arnold, Steve

    Rapid uplift of nonmethane hydrocarbons in a cold front over central Europe R. M. Purvis,1 A. C of a cold front, a rapid uplift of reactive carbon from the boundary layer to the mid free troposphere, convection Citation: Purvis, R. M., et al., Rapid uplift of nonmethane hydrocarbons in a cold front over

  13. Experimental Studies of Hydroxyl Radical Initiated Tropospheric Oxidation of Unsaturated Hydrocarbons 

    E-Print Network [OSTI]

    Ghosh, Buddhadeb

    2011-10-21

    -1 EXPERIMENTAL STUDIES OF HYDROXYL RADICAL INITIATED TROPOSPHERIC OXIDATION OF UNSATURATED HYDROCARBONS A Dissertation by BUDDHADEB GHOSH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY August 2010 Major Subject: Chemistry EXPERIMENTAL STUDIES OF HYDROXYL RADICAL INITIATED TROPOSPHERIC OXIDATION OF UNSATURATED HYDROCARBONS A Dissertation...

  14. Structures and Topological Transitions of Hydrocarbon Films on Quasicrystalline Surfaces Wahyu Setyawan,1

    E-Print Network [OSTI]

    Curtarolo, Stefano

    Setyawan,1 Renee D. Diehl,2 and Stefano Curtarolo1,* 1 Department of Mechanical Engineering and Materials adsorbed hydrocarbons on a quasicrystalline surface: methane, propane, and benzene on decagonal Al by evaluating the nature of hydrocarbon adsorption (methane, propane, and benzene) on a quasicrystalline

  15. Tenax as sorption sink for in vitro bioaccessibility measurement of polycyclic aromatic hydrocarbons in soils

    E-Print Network [OSTI]

    Ma, Lena

    hydrocarbons in soils Chao Li a , XinÀYi Cui a, * , YingÀYing Fan a , Ying Teng b , ZhongÀRen Nan c , Lena Q and maintain the desorption gradient between soil and GI solution. Polycyclic aromatic hydrocarbons (PAHs) were

  16. Quantifying Desorption of Saturated Hydrocarbons from Silicon with Quantum Calculations and Scanning Tunneling Microscopy

    E-Print Network [OSTI]

    Seideman, Tamar

    Quantifying Desorption of Saturated Hydrocarbons from Silicon with Quantum Calculations hydrocarbon on silicon, desorption is observed at bias magnitudes as low as 2.5 V, albeit the desorption with conventional silicon microelectronic tech- nology [17­22]. A detailed understanding of both the electronic

  17. Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient air

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Sampling precautions for the measurement of nitrated polycyclic aromatic hydrocarbons in ambient of polycyclic aromatic hydrocarbons (PAHs) and of their oxidation products, such as nitrated and oxygenated PAHs samplers (cascade impactor and conventional high volume sampler) installed in parallel during several field

  18. Solid hydrocarbon: a migration-of-fines problem in carbonate reservoirs

    SciTech Connect (OSTI)

    Lomando, A.J.

    1986-05-01

    The most familiar example of a migration-of-fines problem is authigenic kaolinite, which can detach, migrate through a pore system, and bridge pore throats, thus reducing permeability. under certain conditions, a similar problem is caused by solid hydrocarbon, independent of a mode of origin, which has precipitated in carbonate pore systems. Cores from several reservoirs in the Lower Cretaceous of east Texas were used as the data base in this study. Three morphotypes of solid hydrocarbon have been identified from thin-section and scanning electron microscope observations: droplets, peanut brittle, and carpets. Droplets are small, individual, rounded particles scattered on pore walls. Peanut brittle ranges from a continuous to discontinuous thin coating with random rounded lumps that probably have droplet precursors. Carpets are thick, continuous coatings and, at the extreme, can effectively occlude whole pores. Initially, solid hydrocarbon reduces permeability without necessarily decreasing porosity significantly. Likewise, solid hydrocarbon cannot be detected directly from wireline logs. Acidizing to enhance communication to the well bore is a common completion procedure in limestone and calcareous sandstone reservoirs. In reservoirs containing solid hydrocarbon, acid etches the substrate and releases solid hydrocarbon, which migrates in the pore system and bridges pore throats. Differential well-bore pressure also may cause solid hydrocarbon to migrate. Therefore, wettability, which controls hydrocarbon adhesion to the pore walls, and the dominant morphotype are important factors in the extent of reservoir damage.

  19. Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs: W. Scott Phillips

    E-Print Network [OSTI]

    Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs: A Review W. Scott or production of fluids can induce microseismic events in hydrocarbon and geothermal reservoirs. By deploying Patterns in Reservoirs Key Words: induced microseismicity, geothermal, oil and gas, fluid flow, location

  20. Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs W. Scott Phillips

    E-Print Network [OSTI]

    Induced Microearthquake Patterns in Hydrocarbon and Geothermal Reservoirs W. Scott Phillips James T microseismic events in hydrocarbon and geothermal reservoirs. By deploying sensors downhole, data sets have Key Words: induced microseismicity, geothermal, oil and gas, fluid flow, location #12;2 Introduction

  1. Synthesis of condensed phases containing polycyclic aromatic hydrocarbons fullerenes and nanotubes

    DOE Patents [OSTI]

    Reilly, Peter T. A.

    2004-10-19

    The invention relates to methods for producing polycyclic aromatic hydrocarbons, fullerenes, and nanotubes, comprising: a. heating at least one carbon-containing material to form a condensed phase comprising at least one polycyclic aromatic hydrocarbon; b. collecting at least some of the condensed phase; c. reacting the condensed phase to form fullerenes and/or nanotubes.

  2. Measurement of organophosphate pesticides, organochlorine pesticides, and polycyclic aromatic hydrocarbons in household dust from two rural villages in Nepal 

    E-Print Network [OSTI]

    Cizmas, Leslie; Ackerman, Lani; Donnelly, Danielle A.; Donnelly, Kirby C.; McDonald, Thomas J.

    2015-01-16

    to polycyclic aromatic hydrocarbons from wood smoke. This study measured the levels of four organophosphate pesticides, 22 organochlorine pesticides, and over thirty polycyclic aromatic hydrocarbons in house dust from two rural Nepali villages. Floor dust...

  3. Flammability Characteristics of Hydrogen and Its Mixtures with Light Hydrocarbons at Atmospheric and Sub-atmospheric Pressures 

    E-Print Network [OSTI]

    Le, Thuy Minh Hai

    2013-07-13

    /vapor. This research focuses on the flammability limits of hydrogen and its binary mixtures with light hydrocarbons (methane, ethane, n-butane, and ethylene) at sub-atmospheric pressures. The flammability limits of hydrogen, light hydrocarbons, and binary mixtures...

  4. Application of Metagenomics for Identification of Novel Petroleum Hydrocarbon Degrading Enzymes in Natural Asphalts from the Rancho La Brea Tar Pits

    E-Print Network [OSTI]

    Baquiran, Jean-Paul Mendoza

    2010-01-01

    Bioremediation of petroleum hydrocarbon-contaminated ground water:Bioremediation of petroleum hydrocarbon-contaminated ground water:dioxide and water (Heitzer and Sayler, 1993). Bioremediation

  5. Method for cracking hydrocarbon compositions using a submerged reactive plasma system

    DOE Patents [OSTI]

    Kong, P.C.

    1997-05-06

    A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

  6. Method for cracking hydrocarbon compositions using a submerged reactive plasma system

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID)

    1997-01-01

    A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

  7. Biofuel from Bacteria and Sunlight: Shewanella as an Ideal Platform for Producing Hydrocarbons

    SciTech Connect (OSTI)

    None

    2010-01-01

    Broad Funding Opportunity Announcement Project: The University of Minnesota is developing clean-burning, liquid hydrocarbon fuels from bacteria. The University is finding ways to continuously harvest hydrocarbons from a type of bacteria called Shewanella by using a photosynthetic organism to constantly feed Shewanella the sugar it needs for energy and hydrocarbon production. The two organisms live and work together as a system. Using Shewanella to produce hydrocarbon fuels offers several advantages over traditional biofuel production methods. First, it eliminates many of the time-consuming and costly steps involved in growing plants and harvesting biomass. Second, hydrocarbon biofuels resemble current petroleum-based fuels and would therefore require few changes to the existing fuel refining and distribution infrastructure in the U.S.

  8. Envlron. Sci. Technol. 1993, 27, 1885-1891 On-Road Hydrocarbon Remote Sensing in the Denver Area

    E-Print Network [OSTI]

    Denver, University of

    of Denver's remote sensor for on-road motor vehicle carbon monoxide (CO) and hydrocarbon (HC thecarbonmonoxidetocarbon dioxide ratio (CO/COz) and the hydrocarbon to carbon dioxide ratio (HC/C02) in the exhaust of anyEnvlron. Sci. Technol. 1993, 27, 1885-1891 On-Road Hydrocarbon Remote Sensing in the Denver Area Yi

  9. Relationship between hydrocarbon measurements and toxicity to a chironomid, fish larva and daphnid for oils and oil spill chemical

    E-Print Network [OSTI]

    Nyman, John

    Relationship between hydrocarbon measurements and toxicity to a chironomid, fish larva and daphnid the extent to which various common hydrocarbon measures can be used to predict toxicity to fresh- water measures used were TPHg, TPHFID, TPHMS, TTAH (sum of 41 target aromatic hydrocarbons), principal components

  10. BOND LENGTH IN BENZENOID HYDROCARBONS Mrcia M. C. Fereira and Rudolf Kiralj, Universidade Estadual de Campinas, Campinas, SP, 13084-

    E-Print Network [OSTI]

    Ferreira, Márcia M. C.

    1 BOND LENGTH IN BENZENOID HYDROCARBONS Márcia M. C. Fereira and Rudolf Kiralj, Universidade-carbon bond length in organic compounds, especially in aromatic hydrocarbons, is a tradicional subject calculation in planar benzenoid hydrocarbons, we must first to explain concepts like benzenoid system, data

  11. THE IN VITRO INFLUENCE OF THE BURROWING POLYCHAETE NEREIS DIVERSICOLOR ON THE FATE OF PETROLEUM HYDROCARBONS IN MARINE SEDIMENTS.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    HYDROCARBONS IN MARINE SEDIMENTS. F. GILBERT a, L. RIVET b and J-C. BERTRAND a a Centre d'Océanologie de, Boite 312, 13397 Marseille Cedex 20 Abstract : The in vitro fate of the saturated hydrocarbon fraction to stimulate both downard and outward transfers of hydrocarbons from sediment reservoirs. In non

  12. Supplementary Material A comparison of atomic-level and coarse-grained models for liquid hydrocarbons from

    E-Print Network [OSTI]

    Simons, Jack

    hydrocarbons from molecular dynamics configurational entropy estimates Riccardo Baron, Alex H. de Vries hydrocarbons. Entropies are calculated using 800 configurations collected over simulation periods of different contribution ( )r chs ch (Eq. (3)) of rotational entropy to the total entropy for hydrocarbon chains

  13. Polycyclic Aromatic Hydrocarbons and n-alkanes in sediments of the Upper Scheldt River Basin: contamination levels and source apportionment

    E-Print Network [OSTI]

    Boyer, Edmond

    Polycyclic Aromatic Hydrocarbons and n-alkanes in sediments of the Upper Scheldt River Basin hydrocarbons (PAHs). Total n-alkane and PAH concentrations in all the sampled cores ranged from 2.8 to 29 mg kg European Research Program for trace metals in river sediments 6,7 , but data on hydrocarbon contamination

  14. Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [TpRh(CNneopentyl)] Complex

    E-Print Network [OSTI]

    Jones, William D.

    Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp activation of fluorinated aromatic hydrocarbons by [TpRh(CNneopentyl)] resulted in the formation of products of homogeneous transition-metal catalysts to activate and functionalize C-H bonds of hydrocarbons for industrial

  15. doi:10.1016/j.gca.2004.09.009 Alkylation of polycyclic aromatic hydrocarbons in carbonaceous chondrites

    E-Print Network [OSTI]

    Zare, Richard N.

    doi:10.1016/j.gca.2004.09.009 Alkylation of polycyclic aromatic hydrocarbons in carbonaceous hydrocarbons (PAHs) in the free organic material of 20 carbonaceous chondrites. These meteorites represent, is in a solvent-extractable form containing aromatic and aliphatic hydrocarbons, amino acids, and other compounds

  16. Unique gas and hydrocarbon adsorption in a highly porous metal-organic framework made of extended aliphatic ligandsw

    E-Print Network [OSTI]

    Li, Jing

    Unique gas and hydrocarbon adsorption in a highly porous metal-organic framework made of extended as an Advance Article on the web 15th October 2008 DOI: 10.1039/b814498b High and unique gas and hydrocarbon the corresponding carboxylates). Due to the aliphatic nature of these ligands, the gas and hydrocarbon adsorption

  17. Gas-phase study of the reactivity of optical coating materials with hydrocarbons by use of a

    E-Print Network [OSTI]

    Rocca, Jorge J.

    Gas-phase study of the reactivity of optical coating materials with hydrocarbons by use with hydrocarbons is studied in the gas phase by use of mass spectroscopy of metal-oxide clusters. We report-layer materials with hydrocarbons. An increased understanding of these reactions could lead to the development

  18. THE MID-INFRARED ABSORPTION SPECTRA OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBONS IN CONDITIONS RELEVANT TO DENSE INTERSTELLAR CLOUDS

    E-Print Network [OSTI]

    THE MID-INFRARED ABSORPTION SPECTRA OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBONS IN CONDITIONS; accepted 2005 June 17 ABSTRACT Polycyclic aromatic hydrocarbons (PAHs) are common throughout the universe. INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs) and related aro- matic materials are thought to be present

  19. Origin and significance of aromatic hydrocarbons in giant iron ore deposits of the late Archean Hamersley Basin,

    E-Print Network [OSTI]

    Brocks, Jochen J.

    Origin and significance of aromatic hydrocarbons in giant iron ore deposits of the late Archean extractable saturated and aromatic hydrocarbons. The host rocks belong to the $2.5 billion years (Ga) old Mt and Newman (Mt Whaleback). The saturated hydrocarbons in the rock extracts have the composition of highly

  20. Chemisorption of (CHx and C2Hy) Hydrocarbons on Pt(111) Clusters and Surfaces from DFT Studies

    E-Print Network [OSTI]

    Goddard III, William A.

    Chemisorption of (CHx and C2Hy) Hydrocarbons on Pt(111) Clusters and Surfaces from DFT Studies Timo that these hydrocarbons all bind covalently (-bonds) to the surface, in agreement with the studies by Kua and Goddard on small Pt clusters. In nearly every case the structure of the adsorbed hydrocarbon achieves a saturated

  1. Ultrafast UV Pump/IR Probe Studies of C-H Activation in Linear, Cyclic, and Aryl Hydrocarbons

    E-Print Network [OSTI]

    Harris, Charles B.

    Ultrafast UV Pump/IR Probe Studies of C-H Activation in Linear, Cyclic, and Aryl Hydrocarbons, cyclic, and aromatic hydrocarbon solvents on a femtosecond to microsecond time scale. These results have revealed that the structure of the hydrocarbon substrate affects the final C-H bond activation step, which

  2. Effect of Hydrocarbon Parts of the Polar Headgroup on Surfactant Aggregates in Gemini and Bola Surfactant Solutions

    E-Print Network [OSTI]

    Huang, Jianbin

    Effect of Hydrocarbon Parts of the Polar Headgroup on Surfactant Aggregates in Gemini and Bola of these gemini and bola surfactants, which can be attributed to the increase of the hydrocarbon parts of the hydrocarbon part of the headgroup is still rare. As to the conventional single-chain cationic quaternary

  3. Hydrocarbon-free resonance transition 795-nm rubidium laser

    SciTech Connect (OSTI)

    Wu, S Q; Soules, T F; Page, R H; Mitchell, S C; Kanz, V K; Beach, R J

    2008-01-09

    An optical resonance transition rubidium laser (5{sup 2}P{sub 1/2} {yields} 5{sup 2}S{sub 1/2}) is demonstrated with a hydrocarbon-free buffer gas. Prior demonstrations of alkali resonance transition lasers have used ethane as either the buffer gas or a buffer gas component to promote rapid fine-structure mixing. However, our experience suggests that the alkali vapor reacts with the ethane producing carbon as one of the reaction products. This degrades long term laser reliability. Our recent experimental results with a 'clean' helium-only buffer gas system pumped by a Ti:sapphire laser demonstrate all the advantages of the original alkali laser system, but without the reliability issues associated with the use of ethane.

  4. Heating hydrocarbon containing formations in a spiral startup staged sequence

    DOE Patents [OSTI]

    Vinegar, Harold J. (Bellaire, TX); Miller, David Scott (Katy, TX)

    2009-12-15

    Methods for treating a hydrocarbon containing formation are described herein. Methods may include treating a first zone of the formation. Treatment of a plurality of zones of the formation may be begun at selected times after the treatment of the first zone begins. The treatment of at least two successively treated zones may begin at a selected time after treatment of the previous zone begins. At least two of the successively treated zones may be adjacent to the zone treated previously. The successive treatment of the zones proceeds in an outward, substantially spiral sequence from the first zone so that the treatment of the zones may move substantially spirally outwards towards a boundary of the treatment area.

  5. Method and apparatus for hydrocarbon recovery from tar sands

    DOE Patents [OSTI]

    Westhoff, James D. (Laramie, WY); Harak, Arnold E. (Laramie, WY)

    1989-01-01

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000.degree. F. in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs.

  6. Method and apparatus for hydrocarbon recovery from tar sands

    DOE Patents [OSTI]

    Westhoff, J.D.; Harak, A.E.

    1988-05-04

    A method and apparatus for utilizing tar sands having a broad range of bitumen content is disclosed. More particularly, tar sands are pyrolyzed in a cyclone retort with high temperature gases recycled from the cyclone retort to produce oil and hydrocarbon products. The spent tar sands are then burned at 2000/degree/F in a burner to remove residual char and produce a solid waste that is easily disposable. The process and apparatus have the advantages of being able to utilize tar sands having a broad range of bitumen content and the advantage of producing product gases that are free from combustion gases and thereby have a higher heating value. Another important advantage is rapid pyrolysis of the tar sands in the cyclone so as to effectively utilize smaller sized reactor vessels for reducing capitol and operating costs. 1 fig., 1 tab.

  7. Distribution of polycyclic aromatic hydrocarbons (PAH's) in marsh sediments, Iraq

    SciTech Connect (OSTI)

    Al-Saad, H.T.; Al-Timari, A.A. (Univ. of Basrah (Iraq))

    1989-12-01

    Recently there has been a growing concern in the release of harmful organics into the environment. Carcinogenic polycyclic aromatic hydrocarbons (PAH's) are a class of compounds of interset due to their possible harmful effects to man as well as organisms. Anthropogenic PAH's may reach aquatic environment as a result of both industrial and domestic effluents, deposition of airborne particles, surface runoff and oil spillage. Having a relatively low water solubility and high affinity to sorb to the suspended particulate matter, most of the PAH's introduced to the aquatic environment tend to accumulate in bottom sediments. Sedimentary PAH's may thus provide a record of the input and history of these pollutants. Consequently, the distribution of PAH's in aquatic sediments have received considerable attention. The purpose of the present work was to establish the distribution of PAH's in the sediments of the marsh region located in southern Iraq.

  8. An experimental and mathematical investigation of hydrocarbon steam distillation 

    E-Print Network [OSTI]

    Langhoff, John Allan

    1984-01-01

    I LIJ D D CO D CIC D P1a L), OOLQLI [ [ LQS LQ WP8Q$ ?7) I/I I?I hl m ~ III O I?I I/I O & P) ?I- 0 O nj (Z) 4J Q O E III ID Cl ?I ?I Q ?/ ??: PJ Cl C C I?l ICl E ?J ??I I III 0 az I? I W K Q3 Ctl IQ C) PV... decreases near the end of the run. Th1s occurs when the volume of hydrocarbon 1n the 11quid phase of the distillation cell becomes small and cannot support 1ts vapor pressure. 07 C5 0 III QI 5- I/I QI 5- 0- 5- 0 CL IQ ) 0 CQ Ol O 0 4J Itl...

  9. Coarse-grained interaction potentials for polyaromatic hydrocarbons

    E-Print Network [OSTI]

    O. Anatole von Lilienfeld; Denis Andrienko

    2005-12-09

    Using Kohn-Sham density functional theory (KS-DFT), we have studied the interaction between various polyaromatic hydrocarbon molecules. The systems range from mono-cyclic benzene up to hexabenzocoronene (hbc). For several conventional exchange-correlation functionals potential energy curves of interaction of the $\\pi$-$\\pi$ stacking hbc dimer are reported. It is found that all pure local density or generalized gradient approximated functionals yield qualitatively incorrect predictions regarding structure and interaction. Inclusion of a non-local, atom-centered correction to the KS-Hamiltonian enables quantitative predictions. The computed potential energy surfaces of interaction yield parameters for a coarse-grained potential, which can be employed to study discotic liquid-crystalline mesophases of derived polyaromatic macromolecules.

  10. Pyrochlore-type catalysts for the reforming of hydrocarbon fuels

    DOE Patents [OSTI]

    Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

    2012-03-13

    A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

  11. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    SciTech Connect (OSTI)

    Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

    2011-03-15

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  12. Method for reducing the sulfur content of a sulfur-containing hydrocarbon stream

    SciTech Connect (OSTI)

    Mahajan, Devinder

    2004-12-28

    The sulfur content of a liquid hydrocarbon stream is reduced under mild conditions by contracting a sulfur-containing liquid hydrocarbon stream with transition metal particles containing the transition metal in a zero oxidation state under conditions sufficient to provide a hydrocarbon product having a reduced sulfur content and metal sulfide particles. The transition metal particles can be produced in situ by adding a transition metal precursor, e.g., a transition metal carbonyl compound, to the sulfur-containing liquid feed stream and sonicating the feed steam/transition metal precursor combination under conditions sufficient to produce the transition metal particles.

  13. Method for silicon carbide production by reacting silica with hydrocarbon gas

    DOE Patents [OSTI]

    Glatzmaier, Gregory C. (Boulder, CO)

    1994-01-01

    A method is described for producing silicon carbide particles using a silicon source material and a hydrocarbon. The method is efficient and is characterized by high yield. Finely divided silicon source material is contacted with hydrocarbon at a temperature of 400.degree. C. to 1000.degree. C. where the hydrocarbon pyrolyzes and coats the particles with carbon. The particles are then heated to 1100.degree. C. to 1600.degree. C. to cause a reaction between the ingredients to form silicon carbide of very small particle size. No grinding of silicon carbide is required to obtain small particles. The method may be carried out as a batch process or as a continuous process.

  14. Fuel-flexible partial oxidation reforming of hydrocarbons for automotive applications.

    SciTech Connect (OSTI)

    Ahmed, S.; Carter, J. D.; Kopasz, J. P.; Krumpelt, M.; Wilkenhoener, R.

    1999-06-07

    Micro-reactor tests indicate that our partial oxidation catalyst is fuel-flexible and can reform conventional (gasoline and diesel) and alternative (ethanol, methanol, natural gas) fuels to hydrogen rich product gases with high hydrogen selectivity. Alcohols are reformed at lower temperatures (< 600 C) while alkanes and unsaturated hydrocarbons require slightly higher temperatures. Cyclic hydrocarbons and aromatics have also been reformed at relatively low temperatures, however, a different mechanism appears to be responsible for their reforming. Complex fuels like gasoline and diesel, which are mixtures of a broad range of hydrocarbons, require temperatures of > 700 C for maximum hydrogen production.

  15. Method for silicon carbide production by reacting silica with hydrocarbon gas

    DOE Patents [OSTI]

    Glatzmaier, G.C.

    1994-06-28

    A method is described for producing silicon carbide particles using a silicon source material and a hydrocarbon. The method is efficient and is characterized by high yield. Finely divided silicon source material is contacted with hydrocarbon at a temperature of 400 C to 1000 C where the hydrocarbon pyrolyzes and coats the particles with carbon. The particles are then heated to 1100 C to 1600 C to cause a reaction between the ingredients to form silicon carbide of very small particle size. No grinding of silicon carbide is required to obtain small particles. The method may be carried out as a batch process or as a continuous process. 5 figures.

  16. Method of treating emissions of a hybrid vehicle with a hydrocarbon absorber and a catalyst bypass system

    DOE Patents [OSTI]

    Roos, Bryan Nathaniel; Gonze, Eugene V; Santoso, Halim G; Spohn, Brian L

    2014-01-14

    A method of treating emissions from an internal combustion engine of a hybrid vehicle includes directing a flow of air created by the internal combustion engine when the internal combustion engine is spinning but not being fueled through a hydrocarbon absorber to collect hydrocarbons within the flow of air. When the hydrocarbon absorber is full and unable to collect additional hydrocarbons, the flow of air is directed through an electrically heated catalyst to treat the flow of air and remove the hydrocarbons. When the hydrocarbon absorber is not full and able to collect additional hydrocarbons, the flow of air is directed through a bypass path that bypasses the electrically heated catalyst to conserve the thermal energy stored within the electrically heated catalyst.

  17. Two-stage Catalytic Reduction of NOx with Hydrocarbons

    SciTech Connect (OSTI)

    Umit S. Ozkan; Erik M. Holmgreen; Matthew M. Yung; Jonathan Halter; Joel Hiltner

    2005-12-21

    A two-stage system for the catalytic reduction of NO from lean-burn natural gas reciprocating engine exhaust is investigated. Each of the two stages uses a distinct catalyst. The first stage is oxidation of NO to NO{sub 2} and the second stage is reduction of NO{sub 2} to N{sub 2} with a hydrocarbon. The central idea is that since NO{sub 2} is a more easily reduced species than NO, it should be better able to compete with oxygen for the combustion reaction of hydrocarbon, which is a challenge in lean conditions. Early work focused on demonstrating that the N{sub 2} yield obtained when NO{sub 2} was reduced was greater than when NO was reduced. NO{sub 2} reduction catalysts were designed and silver supported on alumina (Ag/Al{sub 2}O{sub 3}) was found to be quite active, able to achieve 95% N{sub 2} yield in 10% O{sub 2} using propane as the reducing agent. The design of a catalyst for NO oxidation was also investigated, and a Co/TiO{sub 2} catalyst prepared by sol-gel was shown to have high activity for the reaction, able to reach equilibrium conversion of 80% at 300 C at GHSV of 50,000h{sup -1}. After it was shown that NO{sub 2} could be more easily reduced to N{sub 2} than NO, the focus shifted on developing a catalyst that could use methane as the reducing agent. The Ag/Al{sub 2}O{sub 3} catalyst was tested and found to be inactive for NOx reduction with methane. Through iterative catalyst design, a palladium-based catalyst on a sulfated-zirconia support (Pd/SZ) was synthesized and shown to be able to selectively reduce NO{sub 2} in lean conditions using methane. Development of catalysts for the oxidation reaction also continued and higher activity, as well as stability in 10% water, was observed on a Co/ZrO{sub 2} catalyst, which reached equilibrium conversion of 94% at 250 C at the same GHSV. The Co/ZrO{sub 2} catalyst was also found to be extremely active for oxidation of CO, ethane, and propane, which could potential eliminate the need for any separate oxidation catalyst. At every stage, catalyst synthesis was guided by the insights gained through detailed characterization of the catalysts using many surface and bulk analysis techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, Temperature-programmed Reduction, Temperature programmed Desorption, and Diffuse Reflectance InfraRed Fourier Transform Spectroscopy as well as steady state reaction experiments. Once active catalysts for each stage had been developed, a physical mixture of the two catalysts was tested for the reduction of NO with methane in lean conditions. These experiments using a mixture of the catalysts produced N2 yields as high as 90%. In the presence of 10% water, the catalyst mixture produced 75% N{sub 2} yield, without any optimization. The dual catalyst system developed has the potential to be implemented in lean-burn natural gas engines for reducing NOx in lean exhaust as well as eliminating CO and unburned hydrocarbons without any fuel penalty or any system modifications. If funding continues, future work will focus on improving the hydrothermal stability of the system to bring the technology closer to application.

  18. Development of Advanced Membranes Technology Platform for Hydrocarbon Separations

    SciTech Connect (OSTI)

    Kalthod, Dr Dilip

    2010-03-01

    Virtually all natural gas is dehydrated during its production, transmission and storage, mostly by absorption processes. Membranes offer many potential advantages over absorption, including smaller footprints, lighter-weight packages, packaging flexibility, minimal electrical power duty, amenability to expansion due to system modularity, reduced maintenance costs, reduced emissions of heavy hydrocarbons, no liquid waste streams, and amenability to unmanned operation. The latter is particularly valuable because new natural gas sources are generally located in remote onshore and offshore sites. Most commercially-available membranes for natural gas upgrading involve high capital costs, high methane loss and performance degradation from operational upsets – all of which are barriers to their widespread adoption by the industry. The original focus of the project was to develop and demonstrate robust, high-performance membranes for natural gas dehydration. The first task completed was a user needs-and-wants study to 1) clarify the expectations of system fabricators and end users of the new separations equipment, and 2) establish the required technical and commercial targets for the membrane products. Following this, membrane system modeling and membrane development in the lab proceeded in parallel. Membrane module diameter and length, as well as and the fiber outer and inner fiber diameter, were optimized from a mathematical model that accounts for the relevant fluid dynamics and permeation phenomena. Module design was evaluated in the context of overall system design, capital costs and energy consumption, including the process scheme (particularly sweep generation), feed pretreatment, system layout, and process control. This study provided targets for membrane permeation coefficients and membrane geometry in a commercial offering that would be competitive with absorption systems. A commercially-available polymer with good tensile strength and chemical resistance was selected for membrane development. A novel dope composition and spinning process were developed, which provide a new approach to controlling membrane porosity and wall and skin morphology. A hollow-fiber membrane with an external dense “skin” was produced that has a high water vapor permeation coefficient and selectivity, durability when in operation at 1000 psig and 70°C, and the ability to withstand aromatic and aliphatic hydrocarbon vapors for an extended period. The fiber meets the technical requirements for a commercial product offering in gas dehydration. It can be readily manufactured with some changes in process equipment and process conditions, and is an excellent candidate for scale-up to full-size membrane modules.

  19. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01

    Mar Lett (2010) 30:331–338 Fig. 3 Coal Oil Point seep field,hydrocarbon seeps near Coal Oil Point, California. Marhydrocarbon seep emissions, Coal Oil Point seep field,

  20. From upstream to downstream: Megatrends and latest developments in Latin America`s hydrocarbons sector

    SciTech Connect (OSTI)

    Wu, Kang; Pezeshki, S.; McMahon, J.

    1995-08-01

    In recent years, Latin America`s hydrocarbons sector has been characterized by reorganization, revitalization, regional cooperation, environmental awakening, and steady expansion. The pattern of these changes, which appear to be the megatrends of the region`s hydrocarbons sector development, will continue during the rest of the 1990s. To further study the current situation and future prospects of Latin America`s hydrocarbons sector, we critically summarize in this short article the key issues in the region`s oil and gas development. These megatrends in Latin America`s hydrocarbons sector development will impact not only the future energy demand and supply in the region, but also global oil flows in the North American market and across the Pacific Ocean. Each country is individually discussed; pipelines to be constructed are discussed also.