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Sample records for liquefaction solutions lavaca

  1. EIS-0494: Excelerate Liquefaction Solutions Lavaca Bay LNG Project, Calhoun

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Jackson Counties, Texas | Department of Energy EIS-0494: Excelerate Liquefaction Solutions Lavaca Bay LNG Project, Calhoun and Jackson Counties, Texas EIS-0494: Excelerate Liquefaction Solutions Lavaca Bay LNG Project, Calhoun and Jackson Counties, Texas SUMMARY The Federal Energy Regulatory Commission (FERC) is preparing, with DOE as a cooperating agency, an EIS to analyze the potential environmental impacts of a proposal to construct and operate a liquefied natural gas terminal

  2. EIS-0494: Excelerate Liquefaction Solutions Lavaca Bay LNG Project, Calhoun and Jackson Counties, Texas

    Broader source: Energy.gov [DOE]

    The Federal Energy Regulatory Commission (FERC) is preparing, with DOE as a cooperating agency, an EIS to analyze the potential environmental impacts of a proposal to construct and operate a liquefied natural gas terminal consisting of two floating liquefaction, storage and offloading units and a 29-mile pipeline header system to transport natural gas from existing pipeline systems to the LNG terminal facilities.

  3. SEMI-ANNUAL REPORTS FOR EXCELERATE LIQUEFACTION SOLUTIONS I, LLC - DK. NO.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    12-61-LNG - ORDER 3128 (Vacated by Order 3128-A) | Department of Energy EXCELERATE LIQUEFACTION SOLUTIONS I, LLC - DK. NO. 12-61-LNG - ORDER 3128 (Vacated by Order 3128-A) SEMI-ANNUAL REPORTS FOR EXCELERATE LIQUEFACTION SOLUTIONS I, LLC - DK. NO. 12-61-LNG - ORDER 3128 (Vacated by Order 3128-A) PDF icon April 2013 PDF icon October 2013 PDF icon April 2014 PDF icon October 2014 More Documents & Publications SEMI-ANNUAL REPORTS FOR Louisiana LNG Energy LLC - FE DKT. NO 14-19-LNG - ORDER

  4. Highly Dispersed Pseudo-Homogeneous and Heterogeneous Catalysts Synthesized via Inverse Micelle Solutions for the Liquefaction of Coal

    SciTech Connect (OSTI)

    Hampden-Smith, M.; Kawola, J.S.; Martino, A.; Sault, A.G.; Yamanaka, S.A.

    1999-01-05

    The mission of this project was to use inverse micelle solutions to synthesize nanometer sized metal particles and test the particles as catalysts in the liquefaction of coal and other related reactions. The initial focus of the project was the synthesis of iron based materials in pseudo-homogeneous form. The frost three chapters discuss the synthesis, characterization, and catalyst testing in coal liquefaction and model coal liquefaction reactions of iron based pseudo-homogeneous materials. Later, we became interested in highly dispersed catalysts for coprocessing of coal and plastic waste. Bifunctional catalysts . to hydrogenate the coal and depolymerize the plastic waste are ideal. We began studying, based on our previously devised synthesis strategies, the synthesis of heterogeneous catalysts with a bifunctional nature. In chapter 4, we discuss the fundamental principles in heterogeneous catalysis synthesis with inverse micelle solutions. In chapter 5, we extend the synthesis of chapter 4 to practical systems and use the materials in catalyst testing. Finally in chapter 6, we return to iron and coal liquefaction now studied with the heterogeneous catalysts.

  5. Coal liquefaction

    DOE Patents [OSTI]

    Schindler, Harvey D.

    1985-01-01

    In a two-stage liquefaction wherein coal, hydrogen and liquefaction solvent are contacted in a first thermal liquefaction zone, followed by recovery of an essentially ash free liquid and a pumpable stream of insoluble material, which includes 850.degree. F.+ liquid, with the essentially ash free liquid then being further upgraded in a second liquefaction zone, the liquefaction solvent for the first stage includes the pumpable stream of insoluble material from the first liquefaction stage, and 850.degree. F.+ liquid from the second liquefaction stage.

  6. Liquefaction with microencapsulated catalysts

    DOE Patents [OSTI]

    Weller, Sol W. (Williamsville, NY)

    1985-01-01

    A method of dispersing a liquefaction catalyst within coal or other carbonaceous solids involves providing a suspension in oil of microcapsules containing the catalyst. An aqueous solution of a catalytic metal salt is emulsified in the water-immiscible oil and the resulting minute droplets microencapsulated in polymeric shells by interfacial polycondensation. The catalyst is subsequently blended and dispersed throughout the powdered carbonaceous material to be liquefied. At liquefaction temperatures the polymeric microcapsules are destroyed and the catalyst converted to minute crystallites in intimate contact with the carbonaceous material.

  7. Liquefaction process

    DOE Patents [OSTI]

    Gorbaty, Martin L. (Westfield, NJ); Stone, John B. (Houston, TX); Poddar, Syamal K. (Houston, TX)

    1982-01-01

    Scale formation during the liquefaction of lower ranking coals and similar carbonaceous materials is significantly reduced and/or prevented by pretreatment with a combination of pretreating agents comprising SO.sub.2 and an oxidizing agent. The pretreatment is believed to convert at least a portion of the scale-forming components and particularly calcium, to the corresponding sulfate prior to liquefaction. The pretreatment may be accomplished with the combination of pretreating agents either simultaneously by using a mixture comprising SO.sub.2 and an oxidizing agent or sequentially by first treating with SO.sub.2 and then with an oxidizing agent.

  8. Liquefaction process

    DOE Patents [OSTI]

    Poddar, Syamal K. (Baytown, TX)

    1981-01-01

    Scale formation during the liquefaction of lower ranking coals and similar carbonaceous materials is significantly reduced and/or prevented by pretreatment with a combination of pretreating agents comprising SO.sub.2 and an oxidizing agent. It is essential to effective operation that the moisture content of the solid carbonaceous material be within the range from about 10 to about 25 wt %, based on dry solid carbonaceous material, during the pretreatment. The pretreatment is believed to convert at least a portion of the scale-forming components and particularly calcium, to the corresponding sulfate prior to liquefaction. The pretreatment may be accomplished with the combination of pretreating agents either simultaneously by using a mixture comprising SO.sub.2 and a gaseous oxidizing agent or sequentially by first treating with SO.sub.2 and then with an oxidizing agent.

  9. Liquefaction Triggering Evaluations at DOE Sites - An Update | Department

    Office of Environmental Management (EM)

    of Energy Liquefaction Triggering Evaluations at DOE Sites - An Update Liquefaction Triggering Evaluations at DOE Sites - An Update Liquefaction Triggering Evaluations at DOE Sites - An Update 2014 Natural Phenomena Hazards Meeting October 21-22, 2014 Germantown, Maryland Michael R. Lewis, Bechtel Corporation Michael D. Boone, Bechtel Corporation Rucker J. Williams, Savannah River Nuclear Solutions, LLC Brent Gutierrez, U.S. Department of Energy, Savannah River Site PDF icon Liquefaction

  10. Coal liquefaction quenching process

    DOE Patents [OSTI]

    Thorogood, Robert M. (Macungie, PA); Yeh, Chung-Liang (Bethlehem, PA); Donath, Ernest E. (St. Croix, VI)

    1983-01-01

    There is described an improved coal liquefaction quenching process which prevents the formation of coke with a minimum reduction of thermal efficiency of the coal liquefaction process. In the process, the rapid cooling of the liquid/solid products of the coal liquefaction reaction is performed without the cooling of the associated vapor stream to thereby prevent formation of coke and the occurrence of retrograde reactions. The rapid cooling is achieved by recycling a subcooled portion of the liquid/solid mixture to the lower section of a phase separator that separates the vapor from the liquid/solid products leaving the coal reactor.

  11. Cooperative research program in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.

    1991-01-01

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  12. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  13. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D.

    1985-01-01

    The coal liquefaction process disclosed uses three stages. The first stage is a liquefaction. The second and third stages are hydrogenation stages at different temperatures and in parallel or in series. One stage is within 650.degree.-795.degree. F. and optimizes solvent production. The other stage is within 800.degree.-840.degree. F. and optimizes the C.sub.5 -850.degree. F. product.

  14. LIQUEFACTION EVALUATIONS AT DOE SITES

    Broader source: Energy.gov [DOE]

    Liquefaction Evaluations at DOE Sites M. Lewis, M. McHood, R. Williams, B. Gutierrez October 25, 2011

  15. Liquefaction Evaluations at DOE Sites

    Office of Environmental Management (EM)

    LIQUEFACTION EVALUATIONS AT DOE SITES M. Lewis, M. McHood, R. Williams, B. Gutierrez October 25, 2011 Agenda  Background  Purpose and Objective  Liquefaction Methods  Site Evaluations  Aging  Conclusions 2 Background 3 Liquefaction at DOE Sites Background  Liquefaction evaluations are required at all DOE sites  Methods have evolved over the years, but there is currently only one consensus methodology;  Youd et al., 2001  Two other methods have emerged in the last

  16. Which route to coal liquefaction

    SciTech Connect (OSTI)

    Nene, R.G.

    1981-11-01

    Two main methods for producing liquid fuels from coal are currently undergoing intensive evaluation. One, direct liquefaction (e.g., SRC-II, Exxon Donor Solvent (EDS), and H-Coal) produces liquid fuels directly from coal; the other, indirect liquefaction (e.g., Lurgi gasifier followed by Fischer-Tropsch, and Shell-Koppers gasifier followed by methanol synthesis and Mobil's MTG process) first gasifies coal and then converts the gaseous material into liquid products. This paper compares both routes basing its assessment on yields, thermal efficiencies, elemental balances, investment, complexity, and state of development. It is shown that direct liquefaction is more efficient and produces more product per investment dollar. Higher efficiency for direct liquefaction is verified bY stoichiometric and thermodynamic analysis. All approaches require about the same capital investment per unit of feed. Indirect liquefaction can be either more or less complex than direct liquefaction, depending upon the process. Direct liquefaction is least developed. 8 refs.

  17. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, Wendell H. (Kaysville, UT); Oblad, Alex G. (Salt Lake City, UT); Shabtai, Joseph S. (Salt Lake City, UT)

    1994-01-01

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400.degree. C. at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1.

  18. Coal liquefaction process

    DOE Patents [OSTI]

    Carr, Norman L. (Allison Park, PA); Moon, William G. (Cheswick, PA); Prudich, Michael E. (Pittsburgh, PA)

    1983-01-01

    A C.sub.5 -900.degree. F. (C.sub.5 -482.degree. C.) liquid yield greater than 50 weight percent MAF feed coal is obtained in a coal liquefaction process wherein a selected combination of higher hydrogen partial pressure, longer slurry residence time and increased recycle ash content of the feed slurry are controlled within defined ranges.

  19. Zinc sulfide liquefaction catalyst

    DOE Patents [OSTI]

    Garg, Diwakar

    1984-01-01

    A process for the liquefaction of carbonaceous material, such as coal, is set forth wherein coal is liquefied in a catalytic solvent refining reaction wherein an activated zinc sulfide catalyst is utilized which is activated by hydrogenation in a coal derived process solvent in the absence of coal.

  20. Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LLC and FLNG Liquefaction 3, LLC - 14-005-CIC | Department of Energy Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC and FLNG Liquefaction 3, LLC - 14-005-CIC Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC and FLNG Liquefaction 3, LLC - 14-005-CIC Application of Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC and FLNG Liquefaction 3, LLC to Transfer Control of Long-term Authorization to Export LNG

  1. Production of Advanced Biofuels via Liquefaction - Hydrothermal

    Office of Scientific and Technical Information (OSTI)

    Liquefaction Reactor Design: April 5, 2013 (Technical Report) | SciTech Connect Production of Advanced Biofuels via Liquefaction - Hydrothermal Liquefaction Reactor Design: April 5, 2013 Citation Details In-Document Search Title: Production of Advanced Biofuels via Liquefaction - Hydrothermal Liquefaction Reactor Design: April 5, 2013 This report provides detailed reactor designs and capital costs, and operating cost estimates for the hydrothermal liquefaction reactor system, used for

  2. Corpus Christi Liquefaction Terminal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Terminal Corpus Christi Liquefaction Terminal Corpus Christi Liquefaction Terminal Long-Term Contract Information and Registrations at U.S. LNG Export Facilities Filing Date Type...

  3. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, W.H.; Oblad, A.G.; Shabtai, J.S.

    1994-05-03

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400 C at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1. 1 figures.

  4. Coal Liquefaction desulfurization process

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

  5. Coal liquefaction process

    DOE Patents [OSTI]

    Maa, Peter S.

    1978-01-01

    A process for liquefying a particulate coal feed to produce useful petroleum-like liquid products which comprises contacting; in a series of two or more coal liquefaction zones, or stages, graded with respect to temperature, an admixture of a polar compound; or compounds, a hydrogen donor solvent and particulate coal, the total effluent being passed in each instance from a low temperature zone, or stage to the next succeeding higher temperature zone, or stage, of the series. The temperature within the initial zone, or stage, of the series is maintained about 70.degree. F and 750.degree. F and the temperature within the final zone, or stage, is maintained between about 750.degree. F and 950.degree. F. The residence time within the first zone, or stage, ranges, generally, from about 20 to about 150 minutes and residence time within each of the remaining zones, or stages, of the series ranges, generally, from about 10 minutes to about 70 minutes. Further steps of the process include: separating the product from the liquefaction zone into fractions inclusive of a liquid solvent fraction; hydrotreating said liquid solvent fraction in a hydrogenation zone; and recycling the hydrogenated liquid solvent mixture to said coal liquefaction zones.

  6. Cooperative research in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.; Sendlein, L.V.A. (eds.)

    1991-05-28

    Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.

  7. Whole Algae Hydrothermal Liquefaction | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Process Design and Economics for Whole Algae Hydrothermal Liquefaction, a paper from Pacific Northwest National Laboratory. PDF icon pnnl_whole_algae_liquefaction.pdf More Documents & Publications Pathways for Algal Biofuels Bioenergy Technologies Office Conversion R&D Pathway: Whole Algae Hydrothermal Liquefaction Whole Algae Hydrothermal Liquefaction Technology Pathway

  8. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, Charles H. (Overland Park, KS)

    1986-01-01

    A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

  9. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, C.H.

    1986-02-11

    A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

  10. Hydrothermal Liquefaction of Biomass

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2010-12-10

    Hydrothermal liquefaction technology is describes in its relationship to fast pyrolysis of biomass. The scope of work at PNNL is discussed and some intial results are presented. HydroThermal Liquefaction (HTL), called high-pressure liquefaction in earlier years, is an alternative process for conversion of biomass into liquid products. Some experts consider it to be pyrolysis in solvent phase. It is typically performed at about 350 C and 200 atm pressure such that the water carrier for biomass slurry is maintained in a liquid phase, i.e. below super-critical conditions. In some applications catalysts and/or reducing gases have been added to the system with the expectation of producing higher yields of higher quality products. Slurry agents ('carriers') evaluated have included water, various hydrocarbon oils and recycled bio-oil. High-pressure pumping of biomass slurry has been a major limitation in the process development. Process research in this field faded away in the 1990s except for the HydroThermal Upgrading (HTU) effort in the Netherlands, but has new resurgence with other renewable fuels in light of the increased oil prices and climate change concerns. Research restarted at Pacific Northwest National Laboratory (PNNL) in 2007 with a project, 'HydroThermal Liquefaction of Agricultural and Biorefinery Residues' with partners Archer-Daniels-Midland Company and ConocoPhillips. Through bench-scale experimentation in a continuous-flow system this project investigated the bio-oil yield and quality that could be achieved from a range of biomass feedstocks and derivatives. The project was completed earlier this year with the issuance of the final report. HydroThermal Liquefaction research continues within the National Advanced Biofuels Consortium with the effort focused at PNNL. The bench-scale reactor is being used for conversion of lignocellulosic biomass including pine forest residue and corn stover. A complementary project is an international collaboration with Canada to investigate kelp (seaweed) as a biomass feedstock. The collaborative project includes process testing of the kelp in HydroThermal Liquefaction in the bench-scale unit at PNNL. HydroThermal Liquefaction at PNNL is performed in the hydrothermal processing bench-scale reactor system. Slurries of biomass are prepared in the laboratory from whole ground biomass materials. Both wet processing and dry processing mills can be used, but the wet milling to final slurry is accomplished in a stirred ball mill filled with angle-cut stainless steel shot. The PNNL HTL system, as shown in the figure, is a continuous-flow system including a 1-litre stirred tank preheater/reactor, which can be connected to a 1-litre tubular reactor. The product is filtered at high-pressure to remove mineral precipitate before it is collected in the two high-pressure collectors, which allow the liquid products to be collected batchwise and recovered alternately from the process flow. The filter can be intermittently back-flushed as needed during the run to maintain operation. By-product gas is vented out the wet test meter for volume measurement and samples are collected for gas chromatography compositional analysis. The bio-oil product is analyzed for elemental content in order to calculate mass and elemental balances around the experiments. Detailed chemical analysis is performed by gas chromatography-mass spectrometry and 13-C nuclear magnetic resonance is used to evaluate functional group types in the bio-oil. Sufficient product is produced to allow subsequent catalytic hydroprocessing to produce liquid hydrocarbon fuels. The product bio-oil from hydrothermal liquefaction is typically a more viscous product compared to fast pyrolysis bio-oil. There are several reasons for this difference. The HTL bio-oil contains a lower level of oxygen because of more extensive secondary reaction of the pyrolysis products. There are less amounts of the many light oxygenates derived from the carbohydrate structures as they have been further reacted to phenolic Aldol condensation products. The bio-oil

  11. Two stage liquefaction of coal

    DOE Patents [OSTI]

    Neuworth, Martin B. (Chevy Chase, MD)

    1981-01-01

    A two stage coal liquefaction process and apparatus comprising hydrogen donor solvent extracting, solvent deashing, and catalytic hydrocracking. Preferrably, the catalytic hydrocracking is performed in an ebullating bed hydrocracker.

  12. Environmental development plan: coal liquefaction

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    This Environmental Development plan (EDP) examines environmental concerns that are being evaluated for the technologies in DOE's Coal Liquefaction Program. It identifies the actions that are planned or underway to resolve these concerns while the technologies are being developed. Research is scheduled on the evaluation and mitigation of potential environmental impacts. This EDP updates the FY 1977 Coal Liquefaction Program EDP. Chapter II describes the DOE Coal Liquefaction Program and focuses on the Solvent Refined Coal (SRC), H-Coal, and Exxon donor solvent (EDS) processes because of their relatively advanced R and D stages. The major unresolved environmental concerns associated with the coal liquefaction subactivities and projects are summarized. The concerns were identified in the 1977 EDP's and research was scheduled to lead to the resolution of the concerns. Much of this research is currently underway. The status of ongoing and planned research is shown in Table 4-1.

  13. Coal liquefaction and gasification technologies

    SciTech Connect (OSTI)

    Mangold, E.C.; Muradaz, M.A.; Ouellette, R.P.; Farah, O.G.; Cheremisinoff, P.N.

    1982-01-01

    The state-of-the-art of selected coal liquefaction and gasification processes developed with support from the United States are reviewed. The Exxon Donor Solvent, H-Coal, SRC-I, SRC-II, Mobile Gasoline Synthesis, Fischer-Tropsch Synthesis, and Zinc Halide Hydrocracking liquefaction processes and the Slagging Lurgi, Texaco, Combustion Engineering, COGAS, and Shell-Koppers gasification processes are covered. Separate abstracts were prepared for 5 chapters.

  14. Direct coal liquefaction process

    DOE Patents [OSTI]

    Rindt, J.R.; Hetland, M.D.

    1993-10-26

    An improved multistep liquefaction process for organic carbonaceous mater which produces a virtually completely solvent-soluble carbonaceous liquid product. The solubilized product may be more amenable to further processing than liquid products produced by current methods. In the initial processing step, the finely divided organic carbonaceous material is treated with a hydrocarbonaceous pasting solvent containing from 10% and 100% by weight process-derived phenolic species at a temperature within the range of 300 C to 400 C for typically from 2 minutes to 120 minutes in the presence of a carbon monoxide reductant and an optional hydrogen sulfide reaction promoter in an amount ranging from 0 to 10% by weight of the moisture- and ash-free organic carbonaceous material fed to the system. As a result, hydrogen is generated via the water/gas shift reaction at a rate necessary to prevent condensation reactions. In a second step, the reaction product of the first step is hydrogenated.

  15. Direct coal liquefaction process

    DOE Patents [OSTI]

    Rindt, John R. (Grand Forks, ND); Hetland, Melanie D. (Grand Forks, ND)

    1993-01-01

    An improved multistep liquefaction process for organic carbonaceous mater which produces a virtually completely solvent-soluble carbonaceous liquid product. The solubilized product may be more amenable to further processing than liquid products produced by current methods. In the initial processing step, the finely divided organic carbonaceous material is treated with a hydrocarbonaceous pasting solvent containing from 10% and 100% by weight process-derived phenolic species at a temperature within the range of 300.degree. C. to 400.degree. C. for typically from 2 minutes to 120 minutes in the presence of a carbon monoxide reductant and an optional hydrogen sulfide reaction promoter in an amount ranging from 0 to 10% by weight of the moisture- and ash-free organic carbonaceous material fed to the system. As a result, hydrogen is generated via the water/gas shift reaction at a rate necessary to prevent condensation reactions. In a second step, the reaction product of the first step is hydrogenated.

  16. Liquefaction of calcium-containing subbituminous coals and coals of lower rank

    DOE Patents [OSTI]

    Gorbaty, Martin L. (Sanwood, NJ); Taunton, John W. (Seabrook, TX)

    1980-01-01

    A process for the treatment of a calcium-containing subbituminous coal and coals of lower rank to form insoluble, thermally stable calcium salts which remain within the solids portions of the residue on liquefaction of the coal, thereby suppressing the formation scale, made up largely of calcium carbonate deposits, e.g., vaterite, which normally forms within the coal liquefaction reactor (i.e., coal liquefaction zone), e.g., on reactor surfaces, lines, auxiliary equipment and the like. A solution of a compound or salt characterized by the formula MX, where M is a Group IA metal of the Periodic Table of the Elements, and X is an anion which is capable of forming water-insoluble, thermally stable calcium compounds, is maintained in contact with a particulate coal feed sufficient to impregnate said salt or compound into the pores of the coal. On separation of the impregnated particulate coal from the solution, the coal can be liquefied in a coal liquefaction reactor (reaction zone) at coal liquefaction conditions without significant formation of vaterite or other forms of calcium carbonate on reactor surfaces, auxiliary equipment and the like; and the Group IA metal which remains within the liquefaction bottoms catalyzes the reaction when the liquefaction bottoms are subjected to a gasification reaction.

  17. DOE indirect liquefaction program

    SciTech Connect (OSTI)

    Schehl, R.R.

    1985-01-01

    Processes for the hydrogenation of carbon monoxide have had commercial importance since about 1920, when the commercial production of methanol and higher alcohols on oxide catalysts began. Soon thereafter Fischer and Tropsch discovered that liquid hydrocarbons could be synthesized from carbon monoxide and hydrogen over Group VIII metal catalysts. Following extensive catalyst and process development efforts, this technology provided Germany with a source of liquid fuels during World War II. The period following the war saw an acceleration in research and development on the Fischer-Tropsch process, but the only commercial application that was to emerge was the SASOL process in the Union of South Africa. The oil crises of the 1970s have rekindled worldwide interest in indirect liquefaction technologies for the production of clean, high-quality motor fuels from coal. The development of more efficient coal gasification processes and the advent of molecular sieve catalysts that allow tailoring of product distributions have set the stage for revolutionary improvements in process designs over state-of-the-art technology. This paper reviews, in brief, the research and development projects that the Department of Energy is sponsoring in the area of synthesis gas conversion to liquid fuels. These projects range from pilot-plant-scale operations, such as the fluidized-bed MTG plant in Wesseling, FRG, to basic research into reaction mechanisms at universities and government laboratories. 23 refs., 1 fig., 2 tabs.

  18. Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC and FLNG Liquefaction 3, LLC- 14-005-CIC

    Broader source: Energy.gov [DOE]

    Application of Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC and FLNG Liquefaction 3, LLC to Transfer Control of Long-term Authorization to Export LNG to Free Trade...

  19. Long Term Environment and Economic Impacts of Coal Liquefaction...

    Office of Scientific and Technical Information (OSTI)

    Long Term Environment and Economic Impacts of Coal Liquefaction in China Citation Details In-Document Search Title: Long Term Environment and Economic Impacts of Coal Liquefaction ...

  20. Liquefaction Reactor Design: April 5, 2013 Knorr, D.; Lukas,...

    Office of Scientific and Technical Information (OSTI)

    Production of Advanced Biofuels via Liquefaction - Hydrothermal Liquefaction Reactor Design: April 5, 2013 Knorr, D.; Lukas, J.; Schoen, P. 09 BIOMASS FUELS BIOFUELS CONVERSION;...

  1. Biomass Indirect Liquefaction Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Indirect Liquefaction Workshop Biomass Indirect Liquefaction Workshop To support research and development (R&D) planning efforts within the Thermochemical Conversion Program, the Bioenergy Technologies Office hosted the Biomass Indirect Liquefaction (IDL) Workshop. This workshop discussed and detailed the R&D needs for biomass IDL. Discussions focused on pathways that convert biomass-based syngas (or any carbon monoxide, hydrogen gaseous stream) to liquid intermediates (alcohols

  2. Biomass Indirect Liquefaction Strategy Workshop: Summary Report...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report Biomass Indirect Liquefaction Strategy Workshop: Summary Report This report is based on the proceedings of the U.S. DOE's Bioenergy Technologies Office Biomass Indirect ...

  3. Order 3638: Corpus Christi Liquefaction Project | Department...

    Broader source: Energy.gov (indexed) [DOE]

    TO EXPORT LIQUEFIED NATURAL GAS BY VESSEL FROM THE PROPOSED CORPUS CHRISTI LIQUEFACTION PROJECT IN CORPUS CHRISTI, TEXAS TO NON-FREE TRADE AGREEMENT NATIONS Based on a...

  4. Production of Advanced Biofuels via Liquefaction - Hydrothermal...

    Office of Scientific and Technical Information (OSTI)

    This report provides detailed reactor designs and capital costs, and operating cost estimates for the hydrothermal liquefaction reactor system, used for biomass-to-biofuels ...

  5. Corpus Christi Liquefaction Terminal | Department of Energy

    Office of Environmental Management (EM)

    Corpus Christi Liquefaction Terminal Corpus Christi Liquefaction Terminal Corpus Christi Liquefaction Terminal Long-Term Contract Information and Registrations at U.S. LNG Export Facilities Filing Date Type (1) Description 06/10/15 C (LNG) In the Matter of Cheniere Marketing, LLC and Corpus Christi Liquefaction, LLC FE Docket Nos. 12-97-LNG and 12-99-LNG DOE/FE Order Nos. 3164, 3164-A and 3638 Long-Term Contracts 08/21/15 C (LNG) In the Matter of Cheniere Marketing, LLC and Corpus Christi

  6. Whole Algae Hydrothermal Liquefaction Technology Pathway | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Whole Algae Hydrothermal...

  7. Complete liquefaction methods and apparatus

    DOE Patents [OSTI]

    Turner, Terry D.; Wilding, Bruce M.

    2013-10-15

    A method and apparatus are described to provide complete gas utilization in the liquefaction operation from a source of gas without return of natural gas to the source thereof from the process and apparatus. The mass flow rate of gas input into the system and apparatus may be substantially equal to the mass flow rate of liquefied product output from the system, such as for storage or use.

  8. Solvent treatment of coal for improved liquefaction

    DOE Patents [OSTI]

    Appell, Herbert R. (Pitcairn, PA); Narain, Nand K. (Bethel Park, PA); Utz, Bruce R. (Pittsburgh, PA)

    1986-05-06

    Increased liquefaction yield is obtained by pretreating a slurry of solid carbonaceous material and a liquid hydrocarbonaceous solvent at a temperature above 200.degree. C. but below 350.degree. C. for a period of 10 minutes to four hours prior to exposure to liquefaction temperatures.

  9. Hydrogen-donor coal liquefaction process

    DOE Patents [OSTI]

    Wilson, Jr., Edward L. (Baytown, TX); Mitchell, Willard N. (Baytown, TX)

    1980-01-01

    Improved liquid yields are obtained during the hydrogen-donor solvent liquefaction of coal and similar carbonaceous solids by maintaining a higher concentration of material having hydrogenation catalytic activity in the downstream section of the liquefaction reactor system than in the upstream section of the system.

  10. Biomass Indirect Liquefaction Presentation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation Biomass Indirect Liquefaction Presentation TRI Technology Update & IDL R&D Needs PDF icon burciaga_tri.pdf More Documents & Publications ClearFuels-Rentech Pilot-Scale Biorefinery Biomass Indirect Liquefaction Presentation Range Fuels Commercial-Scale Biorefinery

  11. Coal liquefaction with preasphaltene recycle

    DOE Patents [OSTI]

    Weimer, Robert F.; Miller, Robert N.

    1986-01-01

    A coal liquefaction system is disclosed with a novel preasphaltene recycle from a supercritical extraction unit to the slurry mix tank wherein the recycle stream contains at least 90% preasphaltenes (benzene insoluble, pyridine soluble organics) with other residual materials such as unconverted coal and ash. This subject process results in the production of asphaltene materials which can be subjected to hydrotreating to acquire a substitute for No. 6 fuel oil. The preasphaltene-predominant recycle reduces the hydrogen consumption for a process where asphaltene material is being sought.

  12. EIS-0494: Notice of Intent to Prepare an Environmental Impact Statement |

    Office of Environmental Management (EM)

    Department of Energy 4: Notice of Intent to Prepare an Environmental Impact Statement EIS-0494: Notice of Intent to Prepare an Environmental Impact Statement Excelerate Liquefaction Solutions Lavaca Bay LNG Project, Calhoun and Jackson Counties, Texas The Federal Energy Regulatory Commission (FERC) is preparing, with DOE as a cooperating agency, an EIS to analyze the potential environmental impacts of a proposal to construct and operate a liquefied natural gas terminal consisting of two

  13. Coal liquefaction with subsequent bottoms pyrolysis

    DOE Patents [OSTI]

    Walchuk, George P. (Queens, NY)

    1978-01-01

    In a coal liquefaction process wherein heavy bottoms produced in a liquefaction zone are upgraded by coking or a similar pyrolysis step, pyrolysis liquids boiling in excess of about 1000.degree. F. are further reacted with molecular hydrogen in a reaction zone external of the liquefaction zone, the resulting effluent is fractionated to produce one or more distillate fractions and a bottoms fraction, a portion of this bottoms fraction is recycled to the reaction zone, and the remaining portion of the bottoms fraction is recycled to the pyrolysis step.

  14. Cooperative research program in coal liquefaction. Quarterly report, August 1, 1991--October 31, 1991

    SciTech Connect (OSTI)

    Huffman, G.P.

    1991-12-31

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  15. Cooperative Research Program in coal liquefaction. Technical report, May 1, 1994--October 31, 1994

    SciTech Connect (OSTI)

    1994-12-31

    Progress reports are presented for the following tasks: coliquefaction of coal with waste materials; catalysts for coal liquefaction to clean transportation fuels; fundamental research in coal liquefaction; and in situ analytical techniques for coal liquefaction and coal liquefaction catalysts.

  16. Evaluation of liquefaction potential for building code

    SciTech Connect (OSTI)

    Nunziata, C.; De Nisco, G.; Panza, G. F.

    2008-07-08

    The standard approach for the evaluation of the liquefaction susceptibility is based on the estimation of a safety factor between the cyclic shear resistance to liquefaction and the earthquake induced shear stress. Recently, an updated procedure based on shear-wave velocities (V{sub s}) has been proposed which could be more easily applied.These methods have been applied at La Plaja beach of Catania, that experienced liquefaction because of the 1693 earthquake. The detailed geotechnical and V{sub s} information and the realistic ground motion computed for the 1693 event let us compare the two approaches. The successful application of the V{sub s} procedure, slightly modified to fit historical and safety factor information, even if additional field performances are needed, encourages the development of a guide for liquefaction potential analysis, based on well defined V{sub s} profiles to be included in the italian seismic code.

  17. Energy Department Authorizes Corpus Christi Liquefaction Project...

    Office of Environmental Management (EM)

    ...LNG) to countries that do not have a Free Trade Agreement (FTA) with the United States. The Corpus Christi Liquefaction Project in Corpus Christi, Texas is authorized to export LNG ...

  18. Biomass Indirect Liquefaction Strategy Workshop: Summary Report |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Strategy Workshop: Summary Report Biomass Indirect Liquefaction Strategy Workshop: Summary Report This report is based on the proceedings of the U.S. DOE's Bioenergy Technologies Office Biomass Indirect Liquefaction Strategy Workshop. PDF icon idl_workshop_summary_report_july_2014 More Documents & Publications Bioenergy Technologies Office Conversion R&D Pathway: Syngas Upgrading to Hydrocarbon Fuels ITP Chemicals: Industrial Feedstock Flexibility Workshop

  19. Iron catalyzed coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

  20. SEMI-ANNUAL REPORT - GULF LNG LIQUEFACTION COMPANY, LLC - FE...

    Energy Savers [EERE]

    GULF LNG LIQUEFACTION COMPANY, LLC - FE DKT. NO. 12-47-LNG - ORDER 3104 SEMI-ANNUAL REPORT - GULF LNG LIQUEFACTION COMPANY, LLC - FE DKT. NO. 12-47-LNG - ORDER 3104 PDF icon ...

  1. Coal liquefaction and gas conversion: Proceedings. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  2. Coal liquefaction and gas conversion: Proceedings. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    Volume II contains papers presented at the following sessions: Indirect Liquefaction (oxygenated fuels); and Indirect Liquefaction (Fischer-Tropsch technology). Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  3. Whole Algae Hydrothermal Liquefaction Technology Pathway | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Liquefaction Technology Pathway Whole Algae Hydrothermal Liquefaction Technology Pathway This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks. PDF icon Whole Algae Hydrothermal

  4. Whole Algae Hydrothermal Liquefaction Technology Pathway (Technical Report)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Technical Report: Whole Algae Hydrothermal Liquefaction Technology Pathway Citation Details In-Document Search Title: Whole Algae Hydrothermal Liquefaction Technology Pathway This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with

  5. Whole Algae Hydrothermal Liquefaction Technology Pathway (Technical Report)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Whole Algae Hydrothermal Liquefaction Technology Pathway Citation Details In-Document Search Title: Whole Algae Hydrothermal Liquefaction Technology Pathway This technology pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline-,

  6. DIRECT LIQUEFACTION PROOF OF CONCEPT

    SciTech Connect (OSTI)

    1998-09-01

    The eighth bench scale test of POC program, Run PB-08, was successfully completed from August 8 to August 26, 1997. A total of five operating conditions were tested aiming at evaluating the reactivity of different pyrolysis oils in liquefaction of a Wyoming sub-bituminous coal (Black Thunder coal). For the first time, water soluble promoters were incorporated into the iron-based GelCat to improve the dispersion of the promoter metals in the feed blend. The concentration of the active metals, Mo and Fe, was 100 and 1000 ppm of moisture-free coal, respectively. Black Thunder coal used in this run was the same batch as tested in HTI?s Run POC-02. Similar to Runs PB-01 through 7, this run employed two back mixed slurry reactors, an interstage gas/slurry separator and a direct-coupled hydrotreater. In addition to the hot vapor from the second stage separator, the first stage separator overhead liquid was also fed to the hydrotreater, which was packed with Criterion C-411 hydrotreating catalyst. Pyrolysis oil was produced off-line from a pyrolysis unit acquired from University of Wyoming. Solids rejection was achieved by purging out pressure filter solid. The recycle solvents consisted of O-6 separator bottoms and pressure filter liquid (PFL). The Run PB-08 proceeded very smoothly without any interruptions. Coal conversion consistently above 90W% was achieved. High resid conversion and distillate yield have been obtained from co-processing of coal and 343C+ (650F+) pyrolysis oil. Light gas (C1-C3 ) yield was minimized and hydrogen consumption was reduced due to the introduction of pyrolysis oil, compared with conventional coal-derived solvent. Catalytic activity was improved by incorporating a promoter metal into the iron-based GelCat. It seemed that lowering the first stage temperature to 435C might increase the hydrogenation function of the promoter metal. In comparison with previous coal-waste coprocessing run (PB-06), significant improvements in the process performance were achieved due to catalyst modification and integration of pyrolysis technique into liquefaction.

  7. BIOMASS TO BIO-OIL BY LIQUEFACTION

    SciTech Connect (OSTI)

    Wang, Huamin; Wang, Yong

    2013-01-10

    Significant efforts have been devoted to develop processes for the conversion of biomass, an abundant and sustainable source of energy, to liquid fuels and chemicals, in order to replace diminishing fossil fuels and mitigate global warming. Thermochemical and biochemical methods have attracted the most attention. Among the thermochemical processes, pyrolysis and liquefaction are the two major technologies for the direct conversion of biomass to produce a liquid product, often called bio-oil. This chapter focuses on the liquefaction, a medium-temperature and high-pressure thermochemical process for the conversion of biomass to bio-oil. Water has been most commonly used as a solvent and the process is known as hydrothermal liquefaction (HTL). Fundamentals of HTL process, key factors determining HTL behavior, role of catalyst in HTL, properties of produced bio-oil, and the current status of the technology are summarized. The liquefaction of biomass by using organic solvents, a process called solvolysis, is also discussed. A wide range of biomass feedstocks have been tested for liquefaction including wood, crop residues, algae, food processing waste, and animal manure.

  8. Biomass Indirect Liquefaction Strategy Workshop Summary Report

    SciTech Connect (OSTI)

    none,

    2014-07-01

    This report is based on the proceedings of the U.S. Department of Energy Bioenergy Technologies Office Biomass Indirect Liquefaction Strategy Workshop. The workshop, held March 2021, 2014, in Golden, Colorado, discussed and detailed the research and development needs for biomass indirect liquefaction. Discussions focused on pathways that convert biomass-based syngas (or any carbon monoxide, hydrogen gaseous stream) to liquid intermediates (alcohols or acids) and further synthesize those intermediates to liquid hydrocarbons that are compatible as either a refinery feed or neat fuel.

  9. Quantification of progress in indirect coal liquefaction

    SciTech Connect (OSTI)

    Gray, D.; ElSawy, A.; Tomlinson, G.

    1991-01-01

    The objective of this study is to quantify the economic and technical impact of incorporating various advanced technologies into the indirect coal liquefaction system. These advanced technologies include entrained flow Shell gasification and slurry-phase Fischer-Tropsch (F-T) synthesis. This objective was accomplished by substituting the Shell entrained goal gasifier system for the Lurgi and the advanced slurry F-T reactor for the Synthol and ARGE F-T systems in a SASOL-type indirect liquefaction facility. 4 refs., 3 figs., 2 tabs.

  10. Two-stage coal liquefaction process

    DOE Patents [OSTI]

    Skinner, Ronald W.; Tao, John C.; Znaimer, Samuel

    1985-01-01

    An improved SRC-I two-stage coal liquefaction process which improves the product slate is provided. Substantially all of the net yield of 650.degree.-850.degree. F. heavy distillate from the LC-Finer is combined with the SRC process solvent, substantially all of the net 400.degree.-650.degree. F. middle distillate from the SRC section is combined with the hydrocracker solvent in the LC-Finer, and the initial boiling point of the SRC process solvent is increased sufficiently high to produce a net yield of 650.degree.-850.degree. F. heavy distillate of zero for the two-stage liquefaction process.

  11. Catalyst for coal liquefaction process

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Kang, Chia-Chen C. (Princeton, NJ)

    1984-01-01

    An improved catalyst for a coal liquefaction process; e.g., the H-Coal Process, for converting coal into liquid fuels, and where the conversion is carried out in an ebullated-catalyst-bed reactor wherein the coal contacts catalyst particles and is converted, in addition to liquid fuels, to gas and residual oil which includes preasphaltenes and asphaltenes. The improvement comprises a catalyst selected from the group consisting of the oxides of nickel molybdenum, cobalt molybdenum, cobalt tungsten, and nickel tungsten on a carrier of alumina, silica, or a combination of alumina and silica. The catalyst has a total pore volume of about 0.500 to about 0.900 cc/g and the pore volume comprises micropores, intermediate pores and macropores, the surface of the intermediate pores being sufficiently large to convert the preasphaltenes to asphaltenes and lighter molecules. The conversion of the asphaltenes takes place on the surface of micropores. The macropores are for metal deposition and to prevent catalyst agglomeration. The micropores have diameters between about 50 and about 200 angstroms (.ANG.) and comprise from about 50 to about 80% of the pore volume, whereas the intermediate pores have diameters between about 200 and 2000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume, and the macropores have diameters between about 2000 and about 10,000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume. The catalysts are further improved where they contain promoters. Such promoters include the oxides of vanadium, tungsten, copper, iron and barium, tin chloride, tin fluoride and rare earth metals.

  12. Methods of natural gas liquefaction and natural gas liquefaction plants utilizing multiple and varying gas streams

    DOE Patents [OSTI]

    Wilding, Bruce M; Turner, Terry D

    2014-12-02

    A method of natural gas liquefaction may include cooling a gaseous NG process stream to form a liquid NG process stream. The method may further include directing the first tail gas stream out of a plant at a first pressure and directing a second tail gas stream out of the plant at a second pressure. An additional method of natural gas liquefaction may include separating CO.sub.2 from a liquid NG process stream and processing the CO.sub.2 to provide a CO.sub.2 product stream. Another method of natural gas liquefaction may include combining a marginal gaseous NG process stream with a secondary substantially pure NG stream to provide an improved gaseous NG process stream. Additionally, a NG liquefaction plant may include a first tail gas outlet, and at least a second tail gas outlet, the at least a second tail gas outlet separate from the first tail gas outlet.

  13. Coal liquefaction process with enhanced process solvent

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Kang, Dohee (Macungie, PA)

    1984-01-01

    In an improved coal liquefaction process, including a critical solvent deashing stage, high value product recovery is improved and enhanced process-derived solvent is provided by recycling second separator underflow in the critical solvent deashing stage to the coal slurry mix, for inclusion in the process solvent pool.

  14. Fired heater for coal liquefaction process

    DOE Patents [OSTI]

    Ying, David H. S. (Macungie, PA)

    1984-01-01

    A fired heater for a coal liquefaction process is constructed with a heat transfer tube having U-bends at regular intervals along the length thereof to increase the slug frequency of the multi-phase mixture flowing therethrough to thereby improve the heat transfer efficiency.

  15. Liquefaction of sub-bituminous coal

    DOE Patents [OSTI]

    Schindler, Harvey D.; Chen, James M.

    1986-01-01

    Sub-bituminous coal is directly liquefied in two stages by use of a liquefaction solvent containing insoluble material as well as 850.degree. F.+ material and 850.degree. F.- material derived from the second stage, and controlled temperature and conversion in the second stage. The process is in hydrogen balance.

  16. Two-stage coal liquefaction without gas-phase hydrogen

    DOE Patents [OSTI]

    Stephens, H.P.

    1986-06-05

    A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

  17. EA-1963: Elba Liquefaction Project, Savannah, Georgia | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 3: Elba Liquefaction Project, Savannah, Georgia EA-1963: Elba Liquefaction Project, Savannah, Georgia SUMMARY The Federal Energy Regulatory Commission (FERC) is preparing, with DOE as a cooperating agency, an environmental assessment (EA) that will analyze the potential environmental impacts of a proposal to add natural gas liquefaction and export capabilities at the existing Elba Liquefied Natural Gas Terminal near Savannah, Georgia. Additional information is available at FERC's

  18. Order 3638: Corpus Christi Liquefaction Project | Department of Energy

    Energy Savers [EERE]

    38: Corpus Christi Liquefaction Project Order 3638: Corpus Christi Liquefaction Project ORDER GRANTING LONG-TERM MULTI-CONTRACT AUTHORIZATION TO EXPORT LIQUEFIED NATURAL GAS BY VESSEL FROM THE PROPOSED CORPUS CHRISTI LIQUEFACTION PROJECT IN CORPUS CHRISTI, TEXAS TO NON-FREE TRADE AGREEMENT NATIONS Based on a review of the complete record and for the reasons set forth below, DOE/FE has concluded that the opponents of the Corpus Christi Project Application have not demonstrated that the requested

  19. Order 3669: Sabine Pass Liquefaction, LLC | Department of Energy

    Energy Savers [EERE]

    69: Sabine Pass Liquefaction, LLC Order 3669: Sabine Pass Liquefaction, LLC FINAL OPINION AND ORDER GRANTING LONG-TERM, MULTI-CONTRACT AUTHORIZATION TO EXPORT LIQUEFIED NATURAL GAS BY VESSEL FROM THE SABINE PASS LNG TERMINAL LOCATED IN THE CAMERON PARISH, LOUISIANA, TO NON-FREE TRADE AGREEMENT NATIONS Based on a review of the complete record and for the reasons set forth below, DOE/FE has concluded that the opponents of Sabine Pass Liquefaction, LLC's applications to export LNG from its

  20. Energy Department Authorizes Corpus Christi Liquefaction Project to Export

    Office of Environmental Management (EM)

    Liquefied Natural Gas | Department of Energy Corpus Christi Liquefaction Project to Export Liquefied Natural Gas Energy Department Authorizes Corpus Christi Liquefaction Project to Export Liquefied Natural Gas May 12, 2015 - 5:00pm Addthis News Media Contact 202-586-4940 DOENews@hq.doe.gov WASHINGTON - The Energy Department announced today that it has issued a final authorization for the Corpus Christi Liquefaction Project (Corpus Christi) to export domestically produced liquefied natural

  1. Energy Department Authorizes Sabine Pass Liquefaction's Expansion Project

    Office of Environmental Management (EM)

    to Export Liquefied Natural Gas | Department of Energy Sabine Pass Liquefaction's Expansion Project to Export Liquefied Natural Gas Energy Department Authorizes Sabine Pass Liquefaction's Expansion Project to Export Liquefied Natural Gas June 26, 2015 - 1:01pm Addthis News Media Contact 202-586-4940 WASHINGTON - The Energy Department announced today that it has issued a final authorization for Sabine Pass Liquefaction, LLC's Expansion Project (Sabine Pass) to export domestically produced

  2. EIS-0491: Lake Charles Liquefaction Project; Calcasieu Parish, Louisiana |

    Office of Environmental Management (EM)

    Department of Energy 1: Lake Charles Liquefaction Project; Calcasieu Parish, Louisiana EIS-0491: Lake Charles Liquefaction Project; Calcasieu Parish, Louisiana Summary The Federal Energy Regulatory Commission (FERC) prepared, with DOE as a cooperating agency, an EIS to analyze the potential environmental impacts of a proposal to expand an existing liquefied natural gas (LNG) import terminal in Calcasieu Parish, Louisiana, by constructing and operating natural gas liquefaction and exportation

  3. EIS-0517: Port Arthur Liquefaction Project and Port Arthur Pipeline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Texas, and Cameron Parish, Louisiana EIS-0517: Port Arthur Liquefaction Project and Port Arthur Pipeline Project; Jefferson and Orange Counties, Texas, and Cameron Parish, ...

  4. EIS-0489: Jordan Cove Liquefaction Project (Coos County, OR)...

    Energy Savers [EERE]

    to construct and operate the Jordan Cove Liquefaction and Pacific Connector Pipeline Projects, respectively a proposed new liquefied natural gas (LNG) export terminal and ...

  5. Process development studies of two-stage liquefaction at Wilsonville

    SciTech Connect (OSTI)

    Lamb, C.W.; Nalitham, R.V.; Johnson, T.W.

    1986-09-01

    The Advanced Coal Liquefaction R and D Facility at Wilsonville, Alabama, has been in operation for over 12 years. It is the largest direct coal liquefaction pilot plant still in operation in the United States. Process investigations have evolved from the original study of the Solvent Refined Coal Process for making a clean solid fuel to the recent investigation of two-stage liquefaction processes for making clean distillate fuels. This paper presents results from the current study of various processing schemes designed to reduce the cost of fuels produced by two-stage liquefaction plants.

  6. Long Term Environment and Economic Impacts of Coal Liquefaction...

    Office of Scientific and Technical Information (OSTI)

    Long Term Environment and Economic Impacts of Coal Liquefaction in China Fletcher, Jerald 01 COAL, LIGNITE, AND PEAT The project currently is composed of six specific tasks - three...

  7. liquefaction applications Prakash, A.; Bendale, P.G. 01 COAL...

    Office of Scientific and Technical Information (OSTI)

    reactor costs for indirect liquefaction applications Prakash, A.; Bendale, P.G. 01 COAL, LIGNITE, AND PEAT; CHEMICAL REACTORS; COST; COMPARATIVE EVALUATIONS; METHANOL;...

  8. Whole Algae Hydrothermal Liquefaction Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Davis, Ryan; Jones, Susanne B.; Zhu, Yunhua

    2013-03-31

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the feasibility of using whole wet microalgae as a feedstock for conversion via hydrothermal liquefaction. Technical barriers and key research needs have been assessed in order for the hydrothermal liquefaction of microalgae to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  9. EA-1963: Elba Liquefaction Project, Savannah, Georgia

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Federal Energy Regulatory Commission (FERC) is preparing, with DOE as a cooperating agency, an EA to analyze the potential environmental impacts of a proposal to add natural gas liquefaction and export capabilities at the existing Elba Liquefied Natural Gas Terminal near Savannah, Georgia. Additional information is available at FERCs eLibrary website, elibrary.ferc.gov/idmws/docket_search.asp; search for docket number PF13-3.

  10. Fired heater for coal liquefaction process

    DOE Patents [OSTI]

    Ying, David H. S. (Macungie, PA); McDermott, Wayne T. (Allentown, PA); Givens, Edwin N. (Bethlehem, PA)

    1985-01-01

    A fired heater for a coal liquefaction process is operated under conditions to maximize the slurry slug frequency and thereby improve the heat transfer efficiency. The operating conditions controlled are (1) the pipe diameter and pipe arrangement, (2) the minimum coal/solvent slurry velocity, (3) the maximum gas superficial velocity, and (4) the range of the volumetric flow velocity ratio of gas to coal/solvent slurry.

  11. Whole Algae Hydrothermal Liquefaction Technology Pathway

    Broader source: Energy.gov (indexed) [DOE]

    Whole Algae Hydrothermal Liquefaction Technology Pathway Mary Biddy and Ryan Davis National Renewable Energy Laboratory Susanne Jones and Yunhua Zhu Pacific Northwest National Laboratory NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC, under contract DE-AC36-08GO28308. Pacific Northwest National Laboratory is operated by Battelle for the United States Department of Energy

  12. EXPLORATORY RESEARCH ON NOVEL COAL LIQUEFACTION CONCEPT

    SciTech Connect (OSTI)

    Brandes, S.D.; Winschel, R.A.

    1998-11-30

    The report presents a summary the work performed under DOE Contract No. DE-AC22-95PC95050. Investigations performed under Task 4--Integrated Flow Sheet Testing are detailed. In this program, a novel direct coal liquefaction technology was investigated by CONSOL Inc. with the University of Kentucky Center for Applied Energy Research and LDP Associates. The process concept explored consists of a first-stage coal dissolution step in which the coal is solubilized by hydride ion donation. In the second stage, the products are catalytically upgraded to refinery feedstocks. Integrated first-stage and solids-separation steps were used to prepare feedstocks for second-stage catalytic upgrading. An engineering and economic evaluation was conducted concurrently with experimental work throughout the program. Approaches to reduce costs for a conceptual commercial plant were recommended at the conclusion of Task 3. These approaches were investigated in Task 4. The economic analysis of the process as it was defined at the conclusion of Task 4, indicates that the production of refined product (gasoline) via this novel direct liquefaction technology is higher than the cost associated with conventional two-stage liquefaction technologies.

  13. Coal liquefaction process with increased naphtha yields

    DOE Patents [OSTI]

    Ryan, Daniel F. (Friendswood, TX)

    1986-01-01

    An improved process for liquefying solid carbonaceous materials wherein the solid carbonaceous material is slurried with a suitable solvent and then subjected to liquefaction at elevated temperature and pressure to produce a normally gaseous product, a normally liquid product and a normally solid product. The normally liquid product is further separated into a naphtha boiling range product, a solvent boiling range product and a vacuum gas-oil boiling range product. At least a portion of the solvent boiling-range product and the vacuum gas-oil boiling range product are then combined and passed to a hydrotreater where the mixture is hydrotreated at relatively severe hydrotreating conditions and the liquid product from the hydrotreater then passed to a catalytic cracker. In the catalytic cracker, the hydrotreater effluent is converted partially to a naphtha boiling range product and to a solvent boiling range product. The naphtha boiling range product is added to the naphtha boiling range product from coal liquefaction to thereby significantly increase the production of naphtha boiling range materials. At least a portion of the solvent boiling range product, on the other hand, is separately hydrogenated and used as solvent for the liquefaction. Use of this material as at least a portion of the solvent significantly reduces the amount of saturated materials in said solvent.

  14. Hydrogen donor solvent coal liquefaction process

    DOE Patents [OSTI]

    Plumlee, Karl W.

    1978-01-01

    An indigenous hydrocarbon product stream boiling within a range of from about C.sub.1 -700.degree. F., preferably C.sub.1 -400.degree. F., is treated to produce an upgraded hydrocarbon fuel component and a component which can be recycled, with a suitable donor solvent, to a coal liquefaction zone to catalyze the reaction. In accordance therewith, a liquid hydrocarbon fraction with a high end boiling point range up to about 700.degree. F., preferably up to about 400.degree. F., is separated from a coal liquefaction zone effluent, the separated fraction is contacted with an alkaline medium to provide a hydrocarbon phase and an aqueous extract phase, the aqueous phase is neutralized, and contacted with a peroxygen compound to convert indigenous components of the aqueous phase of said hydrocarbon fraction into catalytic components, such that the aqueous stream is suitable for recycle to the coal liquefaction zone. Naturally occurring phenols and alkyl substituted phenols, found in the aqueous phase, are converted, by the addition of hydroxyl constituents to phenols, to dihydroxy benzenes which, as disclosed in copending Application Ser. Nos. 686,813 now U.S. Pat. No. 4,049,536; 686,814 now U.S. Pat. No. 4,049,537; 686,827 now U.S. Pat. No. 4,051,012 and 686,828, K. W. Plumlee et al, filed May 17, 1976, are suitable hydrogen transfer catalysts.

  15. A Characterization and Evaluation of Coal Liquefaction Process Streams

    SciTech Connect (OSTI)

    G. A. Robbins; R. A. Winschel; S. D. Brandes

    1998-06-09

    CONSOL characterized 38 process strea m samples from HTI Run PB- 04, in which Black Thunder Mine Coal, Hondo vacuum resid, autom obile shredder residue (ASR), and virgin plastics were used as liquefaction feedstocks with dispersed catalyst. A paper on kinetic modeling of resid reactivity was presented at the DOE Coal Lique -faction and Solid Fuels Contractors Review Conference, September 3- 4, 1997, i n Pittsburgh, PA. The paper, "The Reactivity of Direct Coal Liquefaction Resids", i s appended (Appendix 1). Three papers on characterization of samples from coal/ resid/ waste p lastics co- liquefaction were presented or submitted for presen tation at conferences. Because of their similarity, only one of the papers is appended to this report. The paper, "Characterization o f Process Samples From Co- Liquefaction of Coal and Waste Polymers", (Appendix 2) was presented at the DOE Coal Liquefaction and Solid Fuels C ontractors Review Conference, September 3- 4, 1997, in Pittsburgh, PA. The paper, "Characterization of Process Stream Samples From Bench- Scale Co -Liquefaction Runs That Utilized Waste Polymers as Feedstocks" was presented at the 214th National Meeting of the Ameri can Chemical Society, September 7- 11, 1997, in Las Vegas, NV. The paper, "Characterization of Process Oils from Coal/ Waste Co- Liquefaction" wa s submitted for presentation at the 14th Japan/ U. S. Joint Technical Meeting on Coa l Liquefaction and Materials for Coal Liquefaction on October 28, 1997, in Tokyo, Japan. A joint Burns and Roe Services Corp. and CONSOL pap er on crude oil assays of product oils from HTI Run PB- 03 was presented at the DOE Coal Liquefaction and Solid Fuel s Contractors Review Conference, September 3- 4, 1997, in Pittsburgh, PA. The paper , "Characterization of Liquid Products from All- Slurry Mode Liquefaction", is appende d (Appendix 3).

  16. Prevention of deleterious deposits in a coal liquefaction system

    DOE Patents [OSTI]

    Carr, Norman L. (Allison Park, PA); Prudich, Michael E. (Pittsburgh, PA); King, Jr., William E. (Gibsonia, PA); Moon, William G. (Cheswick, PA)

    1984-07-03

    A process for preventing the formation of deleterious coke deposits on the walls of coal liquefaction reactor vessels involves passing hydrogen and a feed slurry comprising feed coal and recycle liquid solvent to a coal liquefaction reaction zone while imparting a critical mixing energy of at least 3500 ergs per cubic centimeter of reaction zone volume per second to the reacting slurry.

  17. Hydrothermal Liquefaction Treatment Preliminary Hazard Analysis Report

    SciTech Connect (OSTI)

    Lowry, Peter P.; Wagner, Katie A.

    2015-08-31

    A preliminary hazard assessment was completed during February 2015 to evaluate the conceptual design of the modular hydrothermal liquefaction treatment system. The hazard assessment was performed in 2 stages. An initial assessment utilizing Hazard Identification and Preliminary Hazards Analysis (PHA) techniques identified areas with significant or unique hazards (process safety-related hazards) that fall outside of the normal operating envelope of PNNL and warranted additional analysis. The subsequent assessment was based on a qualitative What-If analysis. This analysis was augmented, as necessary, by additional quantitative analysis for scenarios involving a release of hazardous material or energy with the potential for affecting the public.

  18. Process for coal liquefaction using electrodeposited catalyst

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA)

    1978-01-01

    A process for the liquefaction of solid hydrocarbonaceous materials is disclosed. Particles of such materials are electroplated with a metal catalyst and are then suspended in a hydrocarbon oil and subjected to hydrogenolysis to liquefy the solid hydrocarbonaceous material. A liquid product oil is separated from residue solid material containing char and the catalyst metal. The catalyst is recovered from the solid material by electrolysis for reuse. A portion of the product oil can be employed as the hydrocarbon oil for suspending additional particles of catalyst coated solid carbonaceous material for hydrogenolysis.

  19. Direct liquefaction proof-of-concept facility

    SciTech Connect (OSTI)

    Alfred G. Comolli; Peizheng Zhou; HTI Staff

    2000-01-01

    The main objective of the U.S. DOE, Office of Fossil Energy, is to ensure the US a secure energy supply at an affordable price. An integral part of this program was the demonstration of fully developed coal liquefaction processes that could be implemented if market and supply considerations so required, Demonstration of the technology, even if not commercialized, provides a security factor for the country if it is known that the coal to liquid processes are proven and readily available. Direct liquefaction breaks down and rearranges complex hydrocarbon molecules from coal, adds hydrogen, and cracks the large molecules to those in the fuel range, removes hetero-atoms and gives the liquids characteristics comparable to petroleum derived fuels. The current processes being scaled and demonstrated are based on two reactor stages that increase conversion efficiency and improve quality by providing the flexibility to adjust process conditions to accommodate favorable reactions. The first stage conditions promote hydrogenation and some oxygen, sulfur and nitrogen removal. The second stage hydrocracks and speeds the conversion to liquids while removing the remaining sulfur and nitrogen. A third hydrotreatment stage can be used to upgrade the liquids to clean specification fuels.

  20. EA-1845: Sabine Pass Liquefaction Project, Cameron County, LA

    Broader source: Energy.gov [DOE]

    DOE participated as a cooperating agency with the Federal Energy Regulatory Commission (FERC) in preparing an EA for the Sabine Pass Liquefaction Project to analyze the potential environmental impacts associated with applications submitted by Sabine Pass Liquefaction, LLC, and Sabine Pass LNG, L.P., to FERC and to DOE’s Office of Fossil Energy (FE) seeking authorization to site, construct, and operate liquefaction and export facilities at the existing Sabine Pass LNG Terminal in Cameron Parish, Louisiana. DOE adopted FERC’s EA and issued a finding of no significant impact on August 7, 2012.

  1. Recent two-stage coal liquefaction results from Wilsonville, Alabama

    SciTech Connect (OSTI)

    Rao, A.K.; Udani, L.H.; Nalitham, R.V.

    1985-01-01

    This paper presents results from two recent runs conducted at the Advanced Coal Liquefaction R and D facility of Wilsonville, Alabama. The first run was an extended demonstration of sub-bituminous coal liquefaction using an integrated two-stage liquefaction (ITSL) process. The second run employed a bituminous coal in a reconfigured two-stage process (RITLS) wherein the undeashed products from the first stage were hydrotreated prior to separation of coal ash. Good operability and satisfactory yield structure were demonstrated in both the runs.

  2. Sabine Pass Liquefaction, LLC- Dkt. No 15-63-LNG

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy gives notice of receipt of an Application filed on April 20, 2015, by Sabine Pass Liquefaction, LLC (SPL), seeking long-term multi-contract authorization to export...

  3. Whole Algae Hydrothermal Liquefaction: 2014 State of Technology

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Snowden-Swan, Lesley J.; Anderson, Daniel; Hallen, Richard T.; Schmidt, Andrew J.; Albrecht, Karl O.; Elliott, Douglas C.

    2014-07-30

    This report describes the base case yields and operating conditions for converting whole microalgae via hydrothermal liquefaction and upgrading to liquid fuels. This serves as the basis against which future technical improvements will be measured.

  4. Design of slurry reactor for indirect liquefaction applications (Technical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Report) | SciTech Connect Design of slurry reactor for indirect liquefaction applications Citation Details In-Document Search Title: Design of slurry reactor for indirect liquefaction applications × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology.

  5. EA-1963: Elba Liquefaction Project; Chatham, Hart, Jefferson, and Effingham

    Office of Environmental Management (EM)

    Counties, Georgia, and Jasper County, South Carolina | Department of Energy 3: Elba Liquefaction Project; Chatham, Hart, Jefferson, and Effingham Counties, Georgia, and Jasper County, South Carolina EA-1963: Elba Liquefaction Project; Chatham, Hart, Jefferson, and Effingham Counties, Georgia, and Jasper County, South Carolina SUMMARY The Federal Energy Regulatory Commission (FERC) is preparing, with DOE as a cooperating agency, an environmental assessment (EA) that will analyze the potential

  6. EIS-0504: Gulf LNG Liquefaction Project, Jackson County, Mississippi |

    Office of Environmental Management (EM)

    Department of Energy 4: Gulf LNG Liquefaction Project, Jackson County, Mississippi EIS-0504: Gulf LNG Liquefaction Project, Jackson County, Mississippi SUMMARY The Federal Energy Regulatory Commission (FERC) announced its intent to prepare an EIS to analyze the potential environmental impacts of a proposal to expand an existing liquefied natural gas (LNG) import terminal in Jackson County Mississippi and modify related facilities to enable the terminal to liquefy natural gas for export. DOE

  7. EIS-0517: Port Arthur Liquefaction Project and Port Arthur Pipeline

    Office of Environmental Management (EM)

    Project; Jefferson and Orange Counties, Texas, and Cameron Parish, Louisiana | Department of Energy 7: Port Arthur Liquefaction Project and Port Arthur Pipeline Project; Jefferson and Orange Counties, Texas, and Cameron Parish, Louisiana EIS-0517: Port Arthur Liquefaction Project and Port Arthur Pipeline Project; Jefferson and Orange Counties, Texas, and Cameron Parish, Louisiana SUMMARY The Federal Energy Regulatory Commission (FERC), with DOE as a cooperating agency, is preparing an EIS

  8. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  9. Process for coal liquefaction in staged dissolvers

    DOE Patents [OSTI]

    Roberts, George W. (Emmaus, PA); Givens, Edwin N. (Bethlehem, PA); Skinner, Ronald W. (Allentown, PA)

    1983-01-01

    There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a pasting oil, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. In accordance with the improved process, the first dissolver is operated at a higher temperature than the second dissolver. This temperature sequence produces improved product selectivity and permits the incorporation of sufficient hydrogen in the solvent for adequate recycle operations.

  10. Advanced progress concepts for direct coal liquefaction

    SciTech Connect (OSTI)

    Anderson, R.; Derbyshire, F.; Givens, E.

    1995-09-01

    Given the low cost of petroleum crude, direct coal liquefaction is still not an economically viable process. The DOE objectives are to further reduce the cost of coal liquefaction to a more competitive level. In this project the primary focus is on the use of low-rank coal feedstocks. A particular strength is the use of process-derived liquids rather than model compound solvents. The original concepts are illustrated in Figure 1, where they are shown on a schematic of the Wilsonville pilot plant operation. Wilsonville operating data have been used to define a base case scenario using run {number_sign}263J, and Wilsonville process materials have been used in experimental work. The CAER has investigated: low severity CO pretreatment of coal for oxygen rejection, increasing coal reactivity and mg inhibiting the propensity for regressive reactions; the application of more active. Low-cost Fe and Mo dispersed catalysts; and the possible use of fluid coking for solids rejection and to generate an overhead product for recycle. CONSOL has investigated: oil agglomeration for coal ash rejection, for the possible rejection of ash in the recycled resid, and for catalyst addition and recovery; and distillate dewaxing to remove naphthenes and paraffins, and to generate an improved quality feed for recycle distillate hydrogenation. At Sandia, research has been concerned with the production of active hydrogen donor distillate solvent fractions produced by the hydrogenation of dewaxed distillates and by fluid coking via low severity reaction with H{sub 2}/CO/H{sub 2}O mixtures using hydrous metal oxide and other catalysts.

  11. SEMI-ANNUAL REPORTS - FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION...

    Energy Savers [EERE]

    - FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. 10-161-LNG - ORDER 3282 SEMI-ANNUAL REPORTS - FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT....

  12. Coal liquefaction technology. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-09-01

    The bibliography contains citations concerning the technologies and processes for converting coal to liquid chemicals and fuels. Topics include materials characterization of liquefaction processes, catalysis, pyrolysis, depolymerization, coprocessing, and integrated liquefaction. Also discussed are liquid fuel use in automobiles and power generation, low-temperature carbonization technology, multi-stage liquefaction, cost benefit analysis, and commercialization of liquefaction technology. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  13. Coal liquefaction process streams characterization and evaluation

    SciTech Connect (OSTI)

    Brandes, S.D.; Lancet, M.S.; Robbins, G.A.; Winschel, R.A.; Burke, F.P.

    1992-11-01

    This is the eleventh Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: (1) The results of a study designed to determine the effects of the conditions employed at the Wilsonville slurry preheater vessel on coal conversion is described. (2) Stable carbon isotope ratios were determined and used to source the carbon of three product samples from Period 49 of UOP bench-scale coprocessing Run 37. The results from this coprocessing run agree with the general trends observed in other coprocessing runs that we have studied. (3) Microautoclave tests and chemical analyses were performed to calibrate'' the reactivity of the standard coal used for determining donor solvent quality of process oils in this contract. (4) Several aspects of Wilsonville Close-Coupled Integrated Two-Stage Liquefaction (CC-ITSL) resid conversion kinetics were investigated; results are presented. Error limits associated with calculations of deactivation rate constants previously reported for Runs 258 and 261 are revised and discussed. A new procedure is described that relates the conversions of 850[degrees]F[sup +] , 1050[degrees]F[sup +], and 850 [times] 1050[degrees]F material. Resid conversions and kinetic constants previously reported for Run 260 were incorrect; corrected data and discussion are found in Appendix I of this report.

  14. Catalytic multi-stage liquefaction (CMSL)

    SciTech Connect (OSTI)

    Comolli, A.G.; Ganguli, P.; Karolkiewicz, W.F.; Lee, T.L.K.; Pradhan, V.R.; Popper, G.; Smith, T.; Stalzer, R.H.

    1996-11-01

    Reported herein are the details and the results of laboratory and bench scale experiments that were conducted at Hydrocarbon Technologies, Inc. under DOE Contract No. DE-AC22-93PC92147 during the period of October 1, 1992, to December 31, 1995. The program results described herein build on the previous technology base and investigating additional methods to improve the economics of producing transportation fuels from coal. This included purely physical parameters, coal treatment and variation in solvent to coal ratio, the use of syngas to replace part of the hydrogen as the reducing gas, the use of dispersed catalyst in addition to and replacing the supported catalyst, and the co-processing of coal with plastic waste material. The overall objective of this program is to produce liquid fuels from direct coal liquefaction at a cost that is competitive with conventional fuels. The report includes the results of an economic assessment of the various process strategies that were evaluated during this program. A summary of the technical/economic evaluations is given in Volume I, Section II of this report. The experimental details of the eleven run of the program are given in Volume I, Section III and Volume II of this report. The details of the technical evaluations are given in the Volume III of the report.

  15. Donor solvent coal liquefaction with bottoms recycle at elevated pressure

    DOE Patents [OSTI]

    Bauman, Richard F.; Taunton, John W.; Anderson, George H.; Trachte, Ken L.; Hsia, Steve J.

    1982-01-01

    An improved process for liquefying solid carbonaceous materials wherein increased naphtha yields are achieved by effecting the liquefaction at a pressure within the range from about 1750 to about 2800 psig in the presence of recycled bottoms and a hydrogen-donor solvent containing at least 0.8 wt % donatable hydrogen. The liquefaction is accomplished at a temperature within the range from about 700.degree. to about 950.degree. F. The coal:bottoms ratio in the feed to liquefaction will be within the range from about 1:1 to about 5:1 and the solvent or diluent to total solids ratio will be at least 1.5:1 and preferably within the range from about 1.6:1 to about 3:1. The yield of naphtha boiling range materials increases as the pressure increases but generally reaches a maximum at a pressure within the range from about 2000 to about 2500 psig.

  16. Liquefaction process for solid carbonaceous materials containing alkaline earth metal humates

    DOE Patents [OSTI]

    Epperly, William R. (Summit, NJ); Deane, Barry C. (East Brunswick, NJ); Brunson, Roy J. (Buffalo Grove, IL)

    1982-01-01

    An improved liquefaction process wherein wall scale and particulate agglomeration during the liquefaction of solid carbonaceous materials containing alkaline earth metal humates is reduced and/or eliminated by subjecting the solid carbonaceous materials to controlled cyclic cavitation during liquefaction. It is important that the solid carbonaceous material be slurried in a suitable solvent or diluent during liquefaction. The cyclic cavitation may be imparted via pressure cycling, cyclic agitation and the like. When pressure cycling or the like is employed an amplitude equivalent to at least 25 psia is required to effectively remove scale from the liquefaction vessel walls.

  17. Liquefaction of solid carbonaceous material with catalyst recycle

    DOE Patents [OSTI]

    Gupta, Avinash (Bloomfield, NJ); Greene, Marvin I. (Oradell, NJ)

    1992-01-01

    In the two stage liquefaction of a carbonaceous solid such as coal wherein coal is liquefied in a first stage in the presence of a liquefaction solvent and the first stage effluent is hydrogenated in the presence of a supported hydrogenation catalyst in a second stage, catalyst which has been previously employed in the second stage and comminuted to a particle size distribution equivalent to 100% passing through U.S. 100 Mesh, is passed to the first stage to improve the overall operation.

  18. Sabine Pass Liquefaction, LLC DOE Semi-Annual Report

    Energy Savers [EERE]

    Sabine Pass Liquefaction, LLC DOE Semi-Annual Report DOE/FE Order Nos. 2833, 2961, 3384, and 3442 FE Docket Nos. 10-85-LNG, 10-111-LNG, 13-121-LNG, and 14-31-LNG Attachment A (part 2) By via email at 2:09 pm, Oct 01, 2014 EMAIL TO DOE/FE 09/29/14 J u l y 2 1 , 2 0 1 4 Ms. Kimberly D. Bose, Secretary Federal Energy Regulatory Commission 888 First Street, N.E. Washington, D.C. 20426 Re: Sabine Pass LNG, L.P. and Sabine Pass Liquefaction, LLC Monthly Construction Progress Report for Sabine Pass

  19. Lake Charles Liquefaction Project Final Environmental Impact Statement

    Office of Environmental Management (EM)

    Lake Charles Liquefaction Project Final Environmental Impact Statement Trunkline Gas Company, LLC, Lake Charles LNG Company, LLC, and Lake Charles LNG Export Company, LLC FERC Docket Nos. CP14-119-000, CP14-120-000, and CP14-122-000 DOE Docket Nos. 11-59-LNG and 13-04-LNG FERC/EIS-0258F, DOE/EIS-0491 Cooperating Agencies: U.S. Coast Guard U.S. Department of Energy U.S. Department of Transportation Lake Charles Liquefaction Project Final Environmental Impact Statement FERC/EIS-0258F Docket Nos.

  20. Cooperative research in coal liquefaction. Technical progress report, May 1, 1993--April 30, 1994

    SciTech Connect (OSTI)

    Huffman, G.P.

    1994-10-01

    Accomplishments for the past year are presented for the following tasks: coliquefaction of coal with waste materials; catalysts for coal liquefaction to clean transportation fuels; fundamental research in coal liquefaction; and in situ analytical techniques for coal liquefaction and coal liquefaction catalysts some of the highlights are: very promising results have been obtained from the liquefaction of plastics, rubber tires, paper and other wastes, and the coliquefaction of wastes with coal; a number of water soluble coal liquefaction catalysts, iron, cobalt, nickel and molybdenum, have been comparatively tested; mossbauer spectroscopy, XAFS spectroscopy, TEM and XPS have been used to characterize a variety of catalysts and other samples from numerous consortium and DOE liquefaction projects and in situ ESR measurements of the free radical density have been conducted at temperatures from 100 to 600{degrees}C and H{sub 2} pressures up to 600 psi.

  1. Probability of Liquefaction for H-Area Savannah River Site

    SciTech Connect (OSTI)

    Lee, R.C.

    2000-09-27

    In 1995 WSRC completed the geotechnical assessment for the In-Tank Precipitation Facility and the H-Tank Farm at the Savannah River Site. As part of that assessment, a probabilistic liquefaction evaluation for the Tobacco Road soils was completed.

  2. Coal liquefaction. Quarterly report, July-September 1979

    SciTech Connect (OSTI)

    1980-07-01

    The status of coal liquefaction pilot plants supported by US DOE is reviewed under the following headings: company involved, location, contract, funding, process name, process description, flowsheet, history and progress during the July-September 1979 quarter. Supporting projects such as test facilities, refining and upgrading coal liquids, catalyst development, and gasification of residues from coal gasification plants are discussed similarly. (LTN)

  3. Recent developments in two-stage coal liquefaction at Wilsonville

    SciTech Connect (OSTI)

    Lee, J.M.; Nalitham, R.V.; Lamb, C.W.

    1986-04-01

    This paper presents results from the Advanced Coal Liquefaction R and D Facility at Wilsonville, Alabama. The primary sponsors are the US Department of Energy (DOE) and the Electric Power Research Institute (EPRI). Amoco Corporation became a sponsor in 1984 through an agreement with EPRI. The facility is operated by Catalytic, Inc., under the management of Southern Company Services, Inc.

  4. The latest developments and outlook for hydrogen liquefaction technology

    SciTech Connect (OSTI)

    Ohlig, K.; Decker, L.

    2014-01-29

    Liquefied hydrogen is presently mainly used for space applications and the semiconductor industry. While clean energy applications, for e.g. the automotive sector, currently contribute to this demand with a small share only, their demand may see a significant boost in the next years with the need for large scale liquefaction plants exceeding the current plant sizes by far. Hydrogen liquefaction for small scale plants with a maximum capacity of 3 tons per day (tpd) is accomplished with a Brayton refrigeration cycle using helium as refrigerant. This technology is characterized by low investment costs but lower process efficiency and hence higher operating costs. For larger plants, a hydrogen Claude cycle is used, characterized by higher investment but lower operating costs. However, liquefaction plants meeting the potentially high demand in the clean energy sector will need further optimization with regard to energy efficiency and hence operating costs. The present paper gives an overview of the currently applied technologies, including their thermodynamic and technical background. Areas of improvement are identified to derive process concepts for future large scale hydrogen liquefaction plants meeting the needs of clean energy applications with optimized energy efficiency and hence minimized operating costs. Compared to studies in this field, this paper focuses on application of new technology and innovative concepts which are either readily available or will require short qualification procedures. They will hence allow implementation in plants in the close future.

  5. Highly dispersed catalysts for coal liquefaction. Phase 1 final report, August 23--November 22, 1994

    SciTech Connect (OSTI)

    Hirschon, A.S.; Wilson, R.B.; Ghaly, O.

    1995-03-22

    The ultimate goal of this project is to develop novel processes for making the conversion of coal into distillable liquids competitive to that of petroleum products in the range of $25/bbl. The objectives of Phase 1 were to determine the utility of new precursors to highly dispersed catalysts for use of syngas atmospheres in coal liquefaction, and to estimate the effect of such implementation on the cost of the final product. The project is divided into three technical tasks. Tasks 1 and 2 are the analyses and liquefaction experiments, respectively, and Task 3 deals with the economic effects of using these methods during coal liquefaction. Results are presented on the following: Analytical Support--screening tests and second-stage conversions; Laboratory-Scale Operations--catalysts, coal conversion in synthetic solvents, Black Thunder screening studies, and two-stage liquefaction experiments; and Technical and economic Assessment--commercial liquefaction plant description, liquefaction plant cost; and economic analysis.

  6. Economic feasibility study: CFR advanced direct coal liquefaction process. Volume 4

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    Preliminary technical and economic data are presented on the CFR Advanced Coal Liquefaction Process. Operating cost estimates and material balances are given.

  7. Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, January 1993--March 1993

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    Progress in a number of laboratory projects supporting direct liquefaction are described. There are too many different topics to be accommodated in a single abstract.

  8. Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE...

    Broader source: Energy.gov (indexed) [DOE]

    (FLEX II Conditional Order) to Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, ... PDF icon Order 3357-B - Final Opinion and Order Granting LNG Export Authorization More ...

  9. SEMI-ANNUAL REPORTS FOR - CORPUS CHRISTI LIQUEFACTION, LLC - FE DKT. NO.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    15-97-LNG - ORDER 3699 | Department of Energy CORPUS CHRISTI LIQUEFACTION, LLC - FE DKT. NO. 15-97-LNG - ORDER 3699 SEMI-ANNUAL REPORTS FOR - CORPUS CHRISTI LIQUEFACTION, LLC - FE DKT. NO. 15-97-LNG - ORDER 3699 PDF icon October 2015 More Documents & Publications SEMI-ANNUAL REPORTS FOR CHENIERE MARKETING, LLC AND CORPUS CHRISTI LIQUEFACTION, LLC (NFTA) - FE DKT. NO. 12-97-LNG - ORDER 3638 SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT.

  10. SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO.

    Energy Savers [EERE]

    13-131-LNG - ORDER 3384 | Department of Energy SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 13-131-LNG - ORDER 3384 SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 13-131-LNG - ORDER 3384 PDF icon April 2014 More Documents & Publications SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-85-LNG; 10-111-LNG; 13-121-LNG; 14-31-LNG; 13-30-LNG; 13-42-LNG; 14-92-LNG SEMI-ANNUAL REPORTS FOR CHENIERE MARKETING, LLC AND CORPUS CHRISTI LIQUEFACTION, LLC

  11. Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No.

    Office of Environmental Management (EM)

    11-161-LNG | Department of Energy 1-161-LNG Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No. 11-161-LNG On November 15, 2013, the Office of Fossil Energy of the Department of Energy (DOE/FE) issued Order No. 3357 (FLEX II Conditional Order) to Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, FLNG Liquefaction 2, LLC, and FLNG Liquefaction 3, LLC (collectively, FLEX) pursuant to section 3(a) of the Natural Gas Act (NGA). As discussed in the PDF below, DOE/FE

  12. Process for coal liquefaction employing selective coal feed

    DOE Patents [OSTI]

    Hoover, David S. (New Tripoli, PA); Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogen-rich gases at elevated temperatures and pressures, following which solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. The selected feed coals comprise washed coals having a substantial amount of mineral matter, preferably from about 25-75%, by weight, based upon run-of-mine coal, removed with at least 1.0% by weight of pyritic sulfur remaining and exhibiting vitrinite reflectance of less than about 0.70%.

  13. Nitrogen expander cycles for large capacity liquefaction of natural gas

    SciTech Connect (OSTI)

    Chang, Ho-Myung; Park, Jae Hoon; Gwak, Kyung Hyun; Choe, Kun Hyung

    2014-01-29

    Thermodynamic study is performed on nitrogen expander cycles for large capacity liquefaction of natural gas. In order to substantially increase the capacity, a Brayton refrigeration cycle with nitrogen expander was recently added to the cold end of the reputable propane pre-cooled mixed-refrigerant (C3-MR) process. Similar modifications with a nitrogen expander cycle are extensively investigated on a variety of cycle configurations. The existing and modified cycles are simulated with commercial process software (Aspen HYSYS) based on selected specifications. The results are compared in terms of thermodynamic efficiency, liquefaction capacity, and estimated size of heat exchangers. The combination of C3-MR with partial regeneration and pre-cooling of nitrogen expander cycle is recommended to have a great potential for high efficiency and large capacity.

  14. Development of an extruder-feeder biomass direct liquefaction process

    SciTech Connect (OSTI)

    White, D.H.; Wolf, D. . Dept. of Chemical Engineering)

    1991-10-01

    As an abundant, renewable, domestic energy resource, biomass could help the United States reduce its dependence on imported oil. Biomass is the only renewable energy technology capable of addressing the national need for liquid transportation fuels. Thus, there is an incentive to develop economic conversion processes for converting biomass, including wood, into liquid fuels. Through research sponsored by the US DOE's Biomass Thermochemical Conversion Program, the University of Arizona has developed a unique biomass direct liquefaction system. The system features a modified single-screw extruder capable of pumping solid slurries containing as high as 60 wt% wood flour in wood oil derived vacuum bottoms at pressures up to 3000 psi. The extruder-feeder has been integrated with a unique reactor by the University to form a system which offers potential for improving high pressure biomass direct liquefaction technology. The extruder-feeder acts simultaneously as both a feed preheater and a pumping device for injecting wood slurries into a high pressure reactor in the biomass liquefaction process. An experimental facility was constructed and following shakedown operations, wood crude oil was produced by mid-1985. By July 1988, a total of 57 experimental continuous biomass liquefaction runs were made using White Birch wood feedstock. Good operability was achieved at slurry feed rates up to 30 lb/hr, reactor pressures from 800 to 3000 psi and temperatures from 350{degree}C to 430{degree}C under conditions covering a range of carbon monoxide feed rates and sodium carbonate catalyst addition. Crude wood oils containing as little as 6--10 wt% residual oxygen were produced. 38 refs., 82 figs., 26 tabs.

  15. STUDY OF SOLVENT AND CATALYST INTERACTIONS IN DIRECT COAL LIQUEFACTION

    SciTech Connect (OSTI)

    Michael T. Klein

    1998-10-01

    Major objectives of the present project are to develop a better understanding of the roles of the catalyst and the liquefaction solvent in the coal liquefaction process. An open question concerning the role of the catalyst is whether intimate contact between the catalyst and the coal particles is important or required. To answer this question, it had been planned to coat an active catalyst with a porous silica coating which was found to retain catalyst activity while preventing actual contact between catalyst and coal. Consultation with people in DuPont who coat catalysts for increasing abrasion resistance have indicated that only portions of the catalyst are coated by their process (spray drying) and that sections of uncoated catalyst remain. For that reason, it was decided to suspend the catalyst in a basket separated from the coal in the reactor. The basket walls were to be permeable to the liquefaction solvent but not to the coal particles. Several such baskets were constructed of stainless steel with holes which would not permit passage of coal particles larger than 30 mesh. Liquefactions run with the coal of greater than 30 mesh size gave normal conversion of coal to liquid in the absence of catalyst in the basket, but substantially increased conversion when Ni/Mo on alumina catalyst was in the basket. While this result is interesting and suggestive of some kind of mass transfer of soluble material occurring between the catalyst and the coal, it does not eliminate the possibility of breakdown of the coal particle into particle sizes permeable to the basket. Indeed, a small amount of fine coal has been found inside the basket. To determine whether fine coal from breakdown of the coal particles is responsible for the conversion, a new basket is being prepared with 0.5{micro}m pore size.

  16. Control of pyrite addition in coal liquefaction process

    DOE Patents [OSTI]

    Schmid, Bruce K. (Englewood, CO); Junkin, James E. (Englewood, CO)

    1982-12-21

    Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the C.sub.5 --900.degree. F. (482.degree. C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and thus reduce pyrite contribution to the slurry pumping load and disposal problems connected with pyrite produced slag.

  17. Advanced coal liquefaction. Final project report

    SciTech Connect (OSTI)

    1996-12-02

    Molecular level liquid phase separation was explored using modified microporous ceramic membranes with pore size reduced from 40{Angstrom} via chemical vapor deposition. At room temperature, membranes with pore sizes <30{Angstrom} were sufficient to achieve >97% rejection of naphthyl-bibenzyl-methane (NBBM) in toluene, likely attributed to the hindrance effect of NBBM through the porous avenue of the membrane. The rejection diminished dramatically as the temperature was increased. The permeance of the mixture was substantially lower than that of the solvent resulted from the interference by the solute through the transport avenue. Also, it was found that the rejection increases along with the transmembrane pressure increase, probably attributed to the pore size distribution of the membrane. The smaller pore sizes become accessible to the solvent while rejecting the solute at the higher pressure. In addition to size-based separation, active transport of molecules through an appropriate pore size at 300-400{degrees}C was observed, as a result of interaction with the surface. Decomposition of NBBM took place at 400{degrees}C in a modified membrane packed with the catalyst synthesized using the similar protocol as membranes. The separation property of this membrane at 400{degrees}C was analyzed indirectly based upon the reaction product distribution.

  18. Liquefaction and storage of thermal treatment off-gases

    SciTech Connect (OSTI)

    Stull, D.M. . Rocky Flats Plant); Golden, J.O. )

    1992-09-08

    A fluidized bed catalytic oxidation unit is being developed for use in the destruction of mixed waste at the Rocky Flats Plant. Cyclones, filters, in situ neutralization of acid gases, and a catalytic converter are used to meet emission standards. Because there is concern by the public that these measures may not be adequate, two off-gas capture systems were evaluated. Both systems involve liquefaction of carbon dioxide produced in the oxidation process. The carbon dioxide would be released only after analysis proved that all appropriate emission standards are met.

  19. EIS-0487: Freeport LNG Liquefaction Project, Brazoria County, Texas

    Broader source: Energy.gov [DOE]

    Federal Energy Regulatory Commission (FERC) prepared an EIS to analyze the potential environmental impacts of a proposal to construct and operate the Freeport Liquefied Natural Gas (LNG) Liquefaction Project, which would expand an existing LNG import terminal and associated facilities in Brazoria County, Texas, to enable the terminal to liquefy and export LNG. DOE, Office of Fossil Energy a cooperating agency in preparing the EIS has an obligation under Section 3 of the Natural Gas Act to authorize the import and export of natural gas, including LNG, unless it finds that the import or export is not consistent with the public interest.

  20. Coal liquefaction in an inorganic-organic medium

    DOE Patents [OSTI]

    Vermeulen, Theodore (Berkeley, CA); Grens, II, Edward A. (Danville, CA); Holten, Ronald R. (El Cerrito, CA)

    1982-01-01

    Improved process for liquefaction of coal by contacting pulverized coal in an inorganic-organic medium solvent system containing a ZnCl.sub.2 catalyst, a polar solvent with the structure RX where X is one of the elements O, N, S or P, and R is hydrogen or a lower hydrocarbon radical; the solvent system can contain a hydrogen donor solvent (and must when RX is water) which is immiscible in the ZnCl.sub.2 and is a hydroaromatic hydrocarbon, selected from tetralin, dihydrophenanthrene, dihydroanthracene or a hydrogenated coal derived hydroaromatic hydrocarbon distillate fraction.

  1. EA-1942: Cove Point Liquefaction Project, Lusby, Maryland

    Broader source: Energy.gov [DOE]

    The Federal Energy Regulatory Commission (FERC) prepared an EA that examined the potential environmental impacts of a proposal to add natural gas liquefaction and exportation capabilities to the existing Cove Point LNG Terminal. DOE, Office of Fossil Energy, was a cooperating agency because it had an obligation under Section 3 of the Natural Gas Act to authorize the import and export of natural gas, including LNG, unless it found that the import or export is not consistent with the public interest. DOE adopted FERCs EA and issued a Finding of No Significant Impact.

  2. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction

    SciTech Connect (OSTI)

    Song, C.; Saini, A.K.; Wenzel, K.; Huang, L.; Hatcher, P.G.; Schobert, H.H.

    1993-04-01

    This work is a fundamental study of catalytic pretreatments as a potential preconversion step to low-severity liquefaction. The ultimate goal of this work is to provide the basis for the design of an improved liquefaction process and to facilitate our understanding of those processes that occur when coals are initially dissolved. The main objectives of this project are to study the effects of low-temperature pretreatments on coal structure and their impacts on the subsequent liquefaction. The effects of pretreatment temperatures, catalyst type, coal rank and influence of solvent will be examined. We have made significant progress in the following four aspects during this quarterly period: (1) influence of drying and oxidation of coal on the conversion and product distribution in catalytic liquefaction of Wyodak subbituminous coal using a dispersed catalyst; (2) spectroscopic characterization of dried and oxidized Wyodak coal and the insoluble residues from catalytic and thermal liquefaction; (3) the structural alteration of low-rank coal in low-severity liquefaction with the emphasis on the oxygen-containing functional groups; and (4) effects of solvents and catalyst dispersion methods in temperature-programmed and non-programmed liquefaction of three low-rank coals.

  3. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report

    SciTech Connect (OSTI)

    Chunshan Song; Schobert, H.H.; Parfitt, D.P.

    1997-11-01

    Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

  4. Subtask 3.9 - Direct Coal Liquefaction Process Development

    SciTech Connect (OSTI)

    Aulich, Ted; Sharma, Ramesh

    2012-07-01

    The Energy and Environmental Research Center (EERC), in partnership with the U.S. Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask 3.9 to design, build, and preliminarily operate a bench-scale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried coal to a liquid suitable for upgrading to fuels and/or chemicals. Fabrication and installation of the DCL system and an accompanying distillation system for off-line fractionation of raw coal liquids into 1) a naphtha�middle distillate stream for upgrading and 2) a recycle stream was completed in May 2012. Shakedown of the system was initiated in July 2012. In addition to completing fabrication of the DCL system, the project also produced a 500-milliliter sample of jet fuel derived in part from direct liquefaction of Illinois No. 6 coal, and submitted the sample to the Air Force Research Laboratory (AFRL) at Wright� Patterson Air Force Base, Dayton, Ohio, for evaluation. The sample was confirmed by AFRL to be in compliance with all U.S. Air Force-prescribed alternative aviation fuel initial screening criteria.

  5. Low severity coal liquefaction promoted by cyclic olefins

    SciTech Connect (OSTI)

    Curtis, C.W.

    1992-07-27

    Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

  6. Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

    SciTech Connect (OSTI)

    Hoffman, G.P.

    1994-07-01

    This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

  7. Coal liquefaction: investigation of reactor performance, role of catalysts, and PCT properties. Technical progress report

    SciTech Connect (OSTI)

    Brainard, A.; Shah, Y.; Tierney, J.; Wender, I.; Albal, R.; Bhattacharjee, S.; Joseph, S.; Seshadri, K.

    1984-10-01

    This report presents the findings of a research effort directed to three tasks summarized below: Task 1: To develop a computer simulator for a direct coal liquefaction reactor. Task 2: To conduct a comprehensive review of indirect liquefaction for the production of fuels and, to a lesser extent, of chemicals. Task 3: To conduct a literature review and analysis of the physical, chemical, and thermodynamic properties (PCT) of the products from direct coal liquefaction processes. Appendix I-D has been entered individually into EDB and ERA.

  8. Sabine Pass Liquefaction, LLC - FE Dkt. No. 14-92-LNG | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Sabine Pass Liquefaction, LLC - FE Dkt. No. 14-92-LNG Sabine Pass Liquefaction, LLC - FE Dkt. No. 14-92-LNG The Office of Fossil Energy gives notice of receipt of an Application filed on July 11, 2014, by Sabine Pass Liquefaction, LLC (SPL), seeking long-term multi-contract authorization to export domestically produced liquefied natural gas (LNG) in an amount up to the equivalent of 203 billion standard cubic feet (Bcf) of natural gas per year. SPL proposes to export LNG from the

  9. SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LLC - FE DKT. 10-160-LNG - ORDER 2913 | Department of Energy LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. 10-160-LNG - ORDER 2913 SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. 10-160-LNG - ORDER 2913 No report submitted at this time. More Documents & Publications SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. NO. 12-06-LNG - ORDER 3066 SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION, L.P.

  10. SEMI-ANNUAL REPORTS - FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC

    Energy Savers [EERE]

    - FE DKT. 10-161-LNG - ORDER 3282 | Department of Energy - FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. 10-161-LNG - ORDER 3282 SEMI-ANNUAL REPORTS - FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. 10-161-LNG - ORDER 3282 PDF icon October 2013 PDF icon April 2014 PDF icon October 2014 PDF icon April 2015 PDF icon October 2015 More Documents & Publications SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT.

  11. SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION,

    Energy Savers [EERE]

    LLC - FE DKT. NO. 12-06-LNG - ORDER 3066 | Department of Energy EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. NO. 12-06-LNG - ORDER 3066 SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. NO. 12-06-LNG - ORDER 3066 PDF icon April 2013 PDF icon April 2014 PDF icon October 2014 PDF icon April 2015 PDF icon October 2015 More Documents & Publications SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION, L.P. & FLNG LIQUEFACTION, LLC - FE DKT. NO.

  12. SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION, L.P. & FLNG LIQUEFACTION,

    Energy Savers [EERE]

    LLC - FE DKT. NO. 11-161-LNG - ORDER 3357 | Department of Energy EXPANSION, L.P. & FLNG LIQUEFACTION, LLC - FE DKT. NO. 11-161-LNG - ORDER 3357 SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION, L.P. & FLNG LIQUEFACTION, LLC - FE DKT. NO. 11-161-LNG - ORDER 3357 PDF icon April 2014 PDF icon October 2014 PDF icon April 2015 PDF icon October 2015 More Documents & Publications SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. NO. 12-06-LNG -

  13. Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No.

    Office of Environmental Management (EM)

    10-161-LNG | Department of Energy 0-161-LNG Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No. 10-161-LNG On May 17, 2013, the Office of Fossil Energy of the Department of Energy (DOE/FE) issued Order No. 3282 (FLEX I Conditional Order) to Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC, pursuant to section 3(a) of the Natural Gas Act (NGA). As discussed in the below PDF, DOE/FE subsequently amended Order No. 3282 to add FLNG Liquefaction 2, LLC and FLNG

  14. Applied research and evaluation of process concepts for liquefaction and gasification of western coals. Final report

    SciTech Connect (OSTI)

    Wiser, W. H.

    1980-09-01

    Fourteen sections, including five subsections, of the final report covering work done between June 1, 1975 to July 31, 1980 on research programs in coal gasification and liquefaction have been entered individually into EDB and ERA. (LTN)

  15. Sabine Pass Liquefaction, LLC FE Dkt. No 15-171-LNG

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an application (Application), filed on November 6, 2015, by Sabine Pass Liquefaction, LLC (Sabine Pass)...

  16. SEMI-ANNUAL REPORTS - FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications SEMI-ANNUAL REPORTS FOR FREEPORT LNG EXPANSION L.P. & FLNG LIQUEFACTION, LLC - FE DKT. NO. 12-06-LNG - ORDER 3066 SEMI-ANNUAL REPORTS FOR FREEPORT LNG ...

  17. Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE...

    Office of Environmental Management (EM)

    0-161-LNG Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No. 10-161-LNG On May 17, 2013, the Office of Fossil Energy of the Department of Energy (DOEFE) issued ...

  18. Corpus Christi Liquefaction, LLC- FE Dkt. No 15-97-LNG

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy gives notice of receipt of an Application filed June 1, 2015, by Corpus Christi Liquefaction, LLC (Corpus Christi), seeking a long-term multi-contract authorization to...

  19. Subtask 3.3 - Feasibility of Direct Coal Liquefaction in the Modern Economic Climate

    SciTech Connect (OSTI)

    Benjamin Oster; Joshua Strege; Marc Kurz; Anthony Snyder; Melanie Jensen

    2009-06-15

    Coal liquefaction provides an alternative to petroleum for the production of liquid hydrocarbon-based fuels. There are two main processes to liquefy coal: direct coal liquefaction (DCL) and indirect coal liquefaction (ICL). Because ICL has been demonstrated to a greater extent than DCL, ICL may be viewed as the lower-risk option when it comes to building a coal liquefaction facility. However, a closer look, based on conversion efficiencies and economics, is necessary to determine the optimal technology. This report summarizes historical DCL efforts in the United States, describes the technical challenges facing DCL, overviews Shenhua's current DCL project in China, provides a DCL conceptual cost estimate based on a literature review, and compares the carbon dioxide emissions from a DCL facility to those from an ICL facility.

  20. Freeport LNG Expansion, L.P., FLNG Liquefaction, LLC, FLNG Liquefactio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Liquefaction 3, LLC to Transfer Control of Long-term Authorization to Export LNG to Free Trade Agreement Nations and Non-free Trade Agreement Nations in FE Dkts. 10-160-LNG;...

  1. Coal liquefaction: A research and development needs assessment: Final report, Volume II

    SciTech Connect (OSTI)

    Schindler, H.D.; Burke, F.P.; Chao, K.C.; Davis, B.H.; Gorbaty, M.L.; Klier, K.; Kruse, C.W.; Larsen, J.W.; Lumpkin, R.E.; McIlwain, M.E.; Wender, I.; Stewart, N.

    1989-03-01

    Volume II of this report on an assessment of research needs for coal liquefaction contains reviews of the five liquefaction technologies---direct, indirect, pyrolysis, coprocessing, and bioconversion. These reviews are not meant to be encyclopedic; several outstanding reviews of liquefaction have appeared in recent years and the reader is referred to these whenever applicable. Instead, these chapters contain reviews of selected topics that serve to support the panel's recommendations or to illustrate recent accomplishments, work in progress, or areas of major research interest. At the beginning of each of these chapters is a brief introduction and a summary of the most important research recommendations brought out during the panel discussions and supported by the material presented in the review. A review of liquefaction developments outside the US is included. 594 refs., 100 figs., 60 tabs.

  2. Hydrothermal pretreatment to prevent scale during liquefaction of certain solid carbonaceous materials

    DOE Patents [OSTI]

    Stone, John B. (Houston, TX); Floyd, Frank M. (Baytown, TX)

    1984-01-01

    Scale formation during the liquefaction of lower ranking coals and similar carbonaceous materials is significantly reduced and/or prevented by hydrothermal pretreatment. The said pretreatment is believed to convert the scale-forming components to the corresponding carbonate prior to liquefaction. The said pretreatment is accomplished at a total pressure within the range from about 1000 to about 4400 psia. Temperature during said pretreatment will generally be within the range from about 500.degree. to about 700.degree. F.

  3. Assessment of Long-Term Research Needs for Coal-Liquefaction Technologies

    SciTech Connect (OSTI)

    Penner, S.S.

    1980-03-01

    The Fossil Energy Research Working Group (FERWG), at the request of J.M. Deutch (Under Secretary of DOE), E. Frieman (Director, Office of Energy Research) and G. Fumich, Jr. (Assistant Secretary for Fossil Fuels), has studied and reviewed currently funded coal-liquefaction technologies. These studies were performed in order to provide an independent assessment of critical research areas that affect the long-term development of coal-liquefaction technologies. This report summarizes the findings and research recommendations of FERWG.

  4. Long Term Environment and Economic Impacts of Coal Liquefaction in China

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Long Term Environment and Economic Impacts of Coal Liquefaction in China Citation Details In-Document Search Title: Long Term Environment and Economic Impacts of Coal Liquefaction in China The project currently is composed of six specific tasks - three research tasks, two outreach and training tasks, and one project management and communications task. Task 1 addresses project management and communication. Research activities focused on Task 2 (Describe

  5. Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Technical Report: Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction Citation Details In-Document Search Title: Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction Under the cooperative agreement program of DOE and funding from Wyoming State's Clean Coal Task Force, Western Research Institute and Thermosolv LLC studied the direct conversion of Wyoming coals and coal-lignin mixed feeds into liquid fuels in

  6. Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Technical Report: Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction Citation Details In-Document Search Title: Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional

  7. Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Technical Report) | SciTech Connect Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction Citation Details In-Document Search Title: Conversion of Low-Rank Wyoming Coals into Gasoline by Direct Liquefaction Under the cooperative agreement program of DOE and funding from Wyoming State's Clean Coal Task Force, Western Research Institute and Thermosolv LLC studied the direct conversion of Wyoming coals and coal-lignin mixed feeds into liquid fuels in conditions highly

  8. Long Term Environment and Economic Impacts of Coal Liquefaction in China

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Technical Report) | SciTech Connect Long Term Environment and Economic Impacts of Coal Liquefaction in China Citation Details In-Document Search Title: Long Term Environment and Economic Impacts of Coal Liquefaction in China The project currently is composed of six specific tasks - three research tasks, two outreach and training tasks, and one project management and communications task. Task 1 addresses project management and communication. Research activities focused on Task 2 (Describe

  9. FINDING OF NO SIGNIFICANT IMPACT FOR SABINE PASS LIQUEFACTION EXPANSION PROJECT REGARDING

    Office of Environmental Management (EM)

    FINDING OF NO SIGNIFICANT IMPACT FOR SABINE PASS LIQUEFACTION EXPANSION PROJECT REGARDING SABINE PASS LIQUEFACTION, LLC, APPLICATIONS SEEKING DEPARTMENT OF ENERGY AUTHORIZATION TO EXPORT LIQUEFIED NATURAL GAS FROM SABINE PASS LNG TERMINAL TO NON-FREE TRADE AGREEMENT NATIONS AGENCY: U.S. Department of Energy, Office of Fossil Energy ACTION: Finding of No Significant Impact SUMMARY: Pursuant to section 1501.6 of the regulations of the Council on Environmental Quality (CEQ), 40 CFR 1501.6, the U.S.

  10. EIS-0489: Jordan Cove Liquefaction Project (Coos County, OR) and Pacific

    Office of Environmental Management (EM)

    Connector Pipeline Project (Coos, Klamath, Jackson, and Douglas Counties, OR) | Department of Energy 9: Jordan Cove Liquefaction Project (Coos County, OR) and Pacific Connector Pipeline Project (Coos, Klamath, Jackson, and Douglas Counties, OR) EIS-0489: Jordan Cove Liquefaction Project (Coos County, OR) and Pacific Connector Pipeline Project (Coos, Klamath, Jackson, and Douglas Counties, OR) SUMMARY Federal Energy Regulatory Commission (FERC), with DOE as a cooperating agency, prepared an

  11. Hydrothermal liquefaction of biomass: Developments from batch to continuous process

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Biller, Patrick; Ross, Andrew; Schmidt, Andrew J.; Jones, Susanne B.

    2015-02-01

    This review describes the recent results in hydrothermal liquefaction (HTL) of biomass in continuous-flow processing systems. Although much has been published about batch reactor tests of biomass HTL, there is only limited information yet available on continuous-flow tests, which can provide a more reasonable basis for process design and scale-up for commercialization. High-moisture biomass feedstocks are the most likely to be used in HTL. These materials are described and results of their processing are discussed. Engineered systems for HTL are described however they are of limited size and do not yet approach a demonstration scale of operation. With the results available process models have been developed and mass and energy balances determined. From these models process costs have been calculated and provide some optimism as to the commercial likelihood of the technology.

  12. Low-Cost Methane Liquefaction Plant and Vehicle Refueling Station

    SciTech Connect (OSTI)

    B. Wilding; D. Bramwell

    1999-01-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is currently negotiating a collaborative effort with Pacific Gas and Electric (PG&E) that will advance the use of liquefied natural gas (LNG) as a vehicle fuel. We plan to develop and demonstrate a small-scale methane liquefaction plant (production of 5,000 to 10,000 gallons per day) and a low-cost ($150,000) LNG refueling station to supply fuel to LNG-powered transit buses and other heavy-duty vehicles. INEEL will perform the research and development work. PG&E will deploy the new facilities commercially in two demonstration projects, one in northern California, and one in southern California.

  13. Direct coal liquefaction baseline design and system analysis

    SciTech Connect (OSTI)

    Not Available

    1991-04-01

    The primary objective of the study is to develop a computer model for a base line direct coal liquefaction design based on two stage direct coupled catalytic reactors. This primary objective is to be accomplished by completing the following: a base line design based on previous DOE/PETC results from Wilsonville pilot plant and other engineering evaluations; a cost estimate and economic analysis; a computer model incorporating the above two steps over a wide range of capacities and selected process alternatives; a comprehensive training program for DOE/PETC Staff to understand and use the computer model; a thorough documentation of all underlying assumptions for baseline economics; and a user manual and training material which will facilitate updating of the model in the future.

  14. Direct coal liquefaction baseline design and system analysis

    SciTech Connect (OSTI)

    Not Available

    1991-07-01

    The primary objective of the study is to develop a computer model for a base line direct coal liquefaction design based on two stage direct coupled catalytic reactors. This primary objective is to be accomplished by completing the following: a base line design based on previous DOE/PETC results from Wilsonville pilot plant and other engineering evaluations; a cost estimate and economic analysis; a computer model incorporating the above two steps over a wide range of capacities and selected process alternatives; a comprehensive training program for DOE/PETC Staff to understand and use the computer model; a thorough documentation of all underlying assumptions for baseline economics; and a user manual and training material which will facilitate updating of the model in the future.

  15. Coal liquefaction: Investigation of reactor performance, role of catalysts and PCT properties: Final report

    SciTech Connect (OSTI)

    Shah, Y.; Tierney, J.; Wender, I.; Joseph, S.; Wen, C.

    1987-02-01

    In the first section of this report, a mathematical model for the Wilsonville Integrated Two-Stage Liquefaction Process is presented. The first stage is a bubble column slurry reactor and has been modeled previously. The second stage is an ebullated bed catalytic reactor designed to improve product quality, process flexibility, and hydrogen utilization efficiency. The basic equations for the second stage are developed. Supplementary information, a user manual, a sample problem, and a complete computer code in FORTRAN are given in Appendices. The second, third and fourth sections deal with the role of three types of catalysts in direct coal liquefaction. The second section contains an overview of the advantages, limitations, and significance of using homogeneous catalysts such as transition metal complexes for direct coal liquefaction. These catalysts have the potential for hydroliquefaction of coal at relatively mild conditions and with good liquid yields. Emphasis is on review of the large body of published literature and on obtaining a perspective for where future developments using these types of catalysts will occur. The third section is concerned with the conversion of coal to liquids using very strong acids known as superacids as catalysts in direct coal liquefaction. The study of the direct liquefaction of coal with superacids promises to yield new approaches to both coal conversion and to elucidation of the constitution of coal. Background information on the use of liquid clathrates as catalysts for coal liquefaction is presented in Section IV. Liquid clathrates can aid in the liquefaction of coal at or near room temperature and require neither application of heat nor consumption of hydrogen. Unfortunately, yields are low, and further developments are needed to justify commercial exploitation. 120 refs.

  16. Design of slurry reactor for indirect liquefaction applications

    SciTech Connect (OSTI)

    Prakash, A.; Bendale, P.G.

    1991-01-01

    The objective of this project is to design and model a conceptual slurry reactor for two indirect liquefaction applications; (1) production of methanol and (2) production of hydrocarbon fuels via Fischer-Tropsch route. A slurry reactor is defined here as a three-phase bubble column reactor using a fine catalyst particle suspension in a high molecular weight liquid. The feed gas is introduced through spargers. It then bubbles through the column providing the agitation necessary for catalyst suspension and mass transfer. The reactor models for the two processes have been formulated using computer simulation. Process data, kinetic and thermodynamic data, heat and mass transfer data and hydrodynamic data have been used in the mathematical models to describe the slurry reactor for each of the two processes. Available data from process development units and demonstration units were used to test and validate the models. Commercial size slurry reactors for methanol and Fischer-Tropsch synthesis were sized using reactor models developed in this report.

  17. Design of slurry reactor for indirect liquefaction applications. Final report

    SciTech Connect (OSTI)

    Prakash, A.; Bendale, P.G.

    1991-12-31

    The objective of this project is to design and model a conceptual slurry reactor for two indirect liquefaction applications; (1) production of methanol and (2) production of hydrocarbon fuels via Fischer-Tropsch route. A slurry reactor is defined here as a three-phase bubble column reactor using a fine catalyst particle suspension in a high molecular weight liquid. The feed gas is introduced through spargers. It then bubbles through the column providing the agitation necessary for catalyst suspension and mass transfer. The reactor models for the two processes have been formulated using computer simulation. Process data, kinetic and thermodynamic data, heat and mass transfer data and hydrodynamic data have been used in the mathematical models to describe the slurry reactor for each of the two processes. Available data from process development units and demonstration units were used to test and validate the models. Commercial size slurry reactors for methanol and Fischer-Tropsch synthesis were sized using reactor models developed in this report.

  18. Biomass Direct Liquefaction Options. TechnoEconomic and Life Cycle Assessment

    SciTech Connect (OSTI)

    Tews, Iva J.; Zhu, Yunhua; Drennan, Corinne; Elliott, Douglas C.; Snowden-Swan, Lesley J.; Onarheim, Kristin; Solantausta, Yrjo; Beckman, David

    2014-07-31

    The purpose of this work was to assess the competitiveness of two biomass to transportation fuel processing routes, which were under development in Finland, the U.S. and elsewhere. Concepts included fast pyrolysis (FP), and hydrothermal liquefaction (HTL), both followed by hydrodeoxygenation, and final product refining. This work was carried out as a collaboration between VTT (Finland), and PNNL (USA). The public funding agents for the work were Tekes in Finland and the Bioenergy Technologies Office of the U.S. Department of Energy. The effort was proposed as an update of the earlier comparative technoeconomic assessment performed by the IEA Bioenergy Direct Biomass Liquefaction Task in the 1980s. New developments in HTL and the upgrading of the HTL biocrude product triggered the interest in reinvestigating this comparison of these biomass liquefaction processes. In addition, developments in FP bio-oil upgrading had provided additional definition of this process option, which could provide an interesting comparison.

  19. SUMMARY REPORT OF THE DOE DIRECT LIQUEFACTION PROCESS DEVELOPMENT CAMPAIGN OF THE LATE TWENTIETH CENTURY

    SciTech Connect (OSTI)

    F.P. Burke; S.D. Brandes; D.C. McCoy; R.A. Winschel; D. Gray; G. Tomlinson

    2001-07-01

    Following the petroleum price and supply disruptions of 1973, the U.S. government began a substantial program to fund the development of alternative fuels. Direct coal liquefaction was one of the potential routes to alternative fuels. The direct coal liquefaction program was funded at substantial levels through 1982, and at much lower levels thereafter. Those processes that were of most interest during this period were designed to produce primarily distillate fuels. By 1999, U.S. government funding for the development of direct coal liquefaction ended. Now that the end of this campaign has arrived, it is appropriate to summarize the process learnings derived from it. This report is a summary of the process learnings derived from the DOE direct coal liquefaction process development campaign of the late twentieth century. The report concentrates on those process development programs that were designed to produce primarily distillate fuels and were largely funded by DOE and its predecessors in response to the petroleum supply and price disruptions of the 1970s. The report is structured as chapters written by different authors on most of the major individual DOE-funded process development programs. The focus of the report is process learnings, as opposed to, say, fundamental coal liquefaction science or equipment design. As detailed in the overview (Chapter 2), DOE's direct coal liquefaction campaign made substantial progress in improving the process yields and the quality of the distillate product. Much of the progress was made after termination by 1983 of the major demonstration programs of the ''first generation'' (SRC-II, H-Coal, EDS) processes.

  20. Catalyst system and process for benzyl ether fragmentation and coal liquefaction

    DOE Patents [OSTI]

    Zoeller, Joseph Robert (Kingsport, TN)

    1998-04-28

    Dibenzyl ether can be readily cleaved to form primarily benzaldehyde and toluene as products, along with minor amounts of bibenzyl and benzyl benzoate, in the presence of a catalyst system comprising a Group 6 metal, preferably molybdenum, a salt, and an organic halide. Although useful synthetically for the cleavage of benzyl ethers, this cleavage also represents a key model reaction for the liquefaction of coal; thus this catalyst system and process should be useful in coal liquefaction with the advantage of operating at significantly lower temperatures and pressures.

  1. The Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect (OSTI)

    Not Available

    1990-05-01

    This reports presents the operating results for Run 252 at the Advanced Coal Liquefaction R D Facility in Wilsonville, Alabama. This run operated in the Close-Coupled Integrated Two-Stage Liquefaction mode (CC-ITSL) using Illinois No. 6 bituminous coal. The primary run objective was demonstration of unit and system operability in the CC-ITSL mode with catalytic-catalytic reactors and with ash recycle. Run 252 began on 26 November 1986 and continued through 3 February 1987. During this period 214.4 MF tons of Illinois No. 6 coal were fed in 1250 hours of operation. 3 refs., 29 figs., 18 tabs.

  2. SEMI-ANNUAL REPORT - GULF LNG LIQUEFACTION COMPANY, LLC - FE DKT. NO.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    12-47-LNG - ORDER 3104 | Department of Energy REPORT - GULF LNG LIQUEFACTION COMPANY, LLC - FE DKT. NO. 12-47-LNG - ORDER 3104 SEMI-ANNUAL REPORT - GULF LNG LIQUEFACTION COMPANY, LLC - FE DKT. NO. 12-47-LNG - ORDER 3104 PDF icon October 2012 PDF icon April 2013 PDF icon October 2013 PDF icon April 2014 PDF icon October 2014 PDF icon April 2015 PDF icon October 2015 More Documents & Publications SEMI-ANNUAL REPORTS FOR SOUTHERN LNG COMPANY - FE DKT. NO. 12-54-LNG - ORDER 3106 SEMI-ANNUAL

  3. Cooperative Research Program in Coal-Waste Liquefaction

    SciTech Connect (OSTI)

    Gerald Huffman

    2000-03-31

    The results of a feasibility study for a demonstration plant for the liquefaction of waste plastic and tires and the coprocessing of these waste polymers with coal are presented. The study was conducted by a committee that included nine representatives from the CFFS, six from the U.S. Department of Energy - Federal Energy Technology Center (FETC), and four from Burns and Roe, Inc. The study included: (1) An assessment of current recycling practices, particularly feedstock recycling in Germany; (2) A review of pertinent research, and a survey of feedstock availability for various types of waste polymers; and (3) A conceptual design for a demonstration plant was developed and an economic analysis for various feedstock mixes. The base case for feedstock scenarios was chosen to be 200 tons per day of waste plastic and 100 tons per day of waste tires. For this base case with oil priced at $20 per barrel, the return on investment (ROI) was found to range from 9% to 20%, using tipping fees for waste plastic and tires typical of those existing in the U.S. The most profitable feedstock appeared to waste plastic alone, with a plant processing 300 t/d of plastic yielding ROI's from 13 to 27 %, depending on the tipping fees for waste plastic. Feedstock recycling of tires was highly dependent on the price that could be obtained for recovered carbon. Addition of even relatively small amounts (20 t/d) of coal to waste plastic and/or coal feeds lowered the ROI's substantially. It should also be noted that increasing the size of the plant significantly improved all ROI's. For example, increasing plant size from 300 t/d to1200 t/d approximately doubles the estimated ROI's for a waste plastic feedstock.

  4. The Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama

    SciTech Connect (OSTI)

    Not Available

    1990-05-01

    The investigation of various Two-Stage Liquefaction (TSL) process configurations was conducted at the Wilsonville Advanced Coal Liquefaction R D Facility between July 1982 and September 1986. The facility combines three process units. There are the liquefaction unit, either thermal (TLU) or catalytic, for the dissolution of coal, the Critical Solvent Deashing unit (CSD) for the separation of ash and undissolved coal, and a catalytic hydrogenation unit (HTR) for product upgrading and recycle process solvent replenishment. The various TSL process configurations were created by changing the process sequence of these three units and by recycling hydrotreated solvents between the units. This report presents a description of the TSL configurations investigated and an analysis of the operating and performance data from the period of study. Illinois No. 6 Burning Star Mine coal Wyodak Clovis Point Mine coal were processed. Cobalt-molybdenum and disposable iron-oxide catalysts were used to improve coal liquefaction reactions and nickel-molybdenum catalysts were used in the hydrotreater. 28 refs., 31 figs., 13 tabs.

  5. Low-rank coal research: Volume 1, Control technology, liquefaction, and gasification: Final report

    SciTech Connect (OSTI)

    Weber, G.F.; Collings, M.E.; Schelkoph, G.L.; Steadman, E.N.; Moretti, C.J.; Henke, K.R.; Rindt, J.R.; Hetland, M.D.; Knudson, C.L.; Willson, W.G.

    1987-04-01

    Volume I contains articles on SO/sub x//NO/sub x/ control, waste management, low-rank direct liquefaction, hydrogen production from low-rank coals, and advanced wastewater treatment. These articles have been entered individually into EDB and ERA. (LTN)

  6. Prediction of microalgae hydrothermal liquefaction products from feedstock biochemical composition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leow, Shijie; Witter, John R.; Vardon, Derek R.; Sharma, Brajendra K.; Guest, Jeremy S.; Strathmann, Timothy J.

    2015-05-11

    Hydrothermal liquefaction (HTL) uses water under elevated temperatures and pressures (200–350 °C, 5–20 MPa) to convert biomass into liquid “biocrude” oil. Despite extensive reports on factors influencing microalgae cell composition during cultivation and separate reports on HTL products linked to cell composition, the field still lacks a quantitative model to predict HTL conversion product yield and qualities from feedstock biochemical composition; the tailoring of microalgae feedstock for downstream conversion is a unique and critical aspect of microalgae biofuels that must be leveraged upon for optimization of the whole process. This study developed predictive relationships for HTL biocrude yield and othermore » conversion product characteristics based on HTL of Nannochloropsis oculata batches harvested with a wide range of compositions (23–59% dw lipids, 58–17% dw proteins, 12–22% dw carbohydrates) and a defatted batch (0% dw lipids, 75% dw proteins, 19% dw carbohydrates). HTL biocrude yield (33–68% dw) and carbon distribution (49–83%) increased in proportion to the fatty acid (FA) content. A component additivity model (predicting biocrude yield from lipid, protein, and carbohydrates) was more accurate predicting literature yields for diverse microalgae species than previous additivity models derived from model compounds. FA profiling of the biocrude product showed strong links to the initial feedstock FA profile of the lipid component, demonstrating that HTL acts as a water-based extraction process for FAs; the remainder non-FA structural components could be represented using the defatted batch. These findings were used to introduce a new FA-based model that predicts biocrude oil yields along with other critical parameters, and is capable of adjusting for the wide variations in HTL methodology and microalgae species through the defatted batch. Lastly, the FA model was linked to an upstream cultivation model (Phototrophic Process Model), providing for the first time an integrated modeling framework to overcome a critical barrier to microalgae-derived HTL biofuels and enable predictive analysis of the overall microalgal-to-biofuel process.« less

  7. Status of health and environmental research relative to direct coal liquefaction: 1976 to the present

    SciTech Connect (OSTI)

    Gray, R.H.; Cowser, K.E.

    1982-06-01

    This document describes the status of health and environmental research efforts, supported by the US Department of Energy (DOE), to assist in the development of environmentally acceptable coal liquefaction processes. Four major direct coal liquefaction processes are currently in (or have been investigated at) the pilot plant stage of development. Two solvent refined coal processes (SRC-I and -II), H-coal (a catalytic liquefaction process) and Exxon donor solvent (EDS). The Pacific Northwest Laboratory was assigned responsibility for evaluating SRC process materials and prepared comprehensive health and environmental effects research program plans for SRC-I and -II. A similar program plan was prepared for H-coal process materials by the Oak Ridge National Laboratory. A program has been developed for EDS process materials by Exxon Research and Engineering Co. The program includes short-term screening of coal-derived materials for potential health and ecological effects. Longer-term assays are used to evaluate materials considered most representative of potential commercial practice and with greatest potential for human exposure or release to the environment. Effects of process modification, control technologies and changing operational conditions on potential health and ecological effects are also being evaluated. These assessments are being conducted to assist in formulating cost-effective environmental research programs and to estimate health and environmental risks associated with a large-scale coal liquefaction industry. Significant results of DOE's health and environmental research efforts relative to coal liquefaction include the following: chemical characterization, health effects, ecological fate and effects, amelioration and risk assessment.

  8. Process for the liquefaction of solid carbonaceous materials wherein nitrogen is separated from hydrogen via ammonia synthesis

    DOE Patents [OSTI]

    Stetka, Steven S. (Fleetwood, PA); Nazario, Francisco N. (Parsippany, NJ)

    1982-01-01

    In a process for the liquefaction of solid carbonaceous materials wherein bottoms residues are upgraded with a process wherein air is employed, the improvement wherein nitrogen buildup in the system is avoided by ammonia synthesis. In a preferred embodiment hydrogen from other portions of the liquefaction process will be combined with hydrogen produced as a result of the bottoms upgrading to increase the H.sub.2 :N.sub.2 ratio in the ammonia reactor.

  9. Liquefaction of Forest Biomass to Drop-inŽ Hydrocarbon Biofuels Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Liquefaction of Forest Biomass to "Drop-in" Hydrocarbon Biofuels Contract EE0005974 March 26, 2015 Robert C. Brown Iowa State University This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement * Project Goal: Demonstrate solvent liquefaction as a viable pathway to stable intermediates that can be upgraded to fuel blendstocks * Funding Opportunity Announcement DE-FOA-00005100 * R&D, demonstration, and life-cycle evaluation

  10. Fractional Multistage Hydrothermal Liquefaction of Biomass and Catalytic Conversion into Hydrocarbons Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March, 2015 Technology Area Review: Thermochemical Conversion Randy Cortright PhD Virent, Inc WBS: 2.5.5.401 Fractional Multistage Hydrothermal Liquefaction of Biomass and Catalytic Conversion into Hydrocarbons © Virent 2015 Slide 2 Goal Statement Project Goal - Develop a novel Multistage Hydrothermal Liquefaction (HTL) of biomass and integrate with Virent's Catalytic BioForming® Process to efficiently produce cost effective "drop-in" fuels from woody biomass and corn stover, with

  11. Status of coal liquefaction in the United States and related research and development at the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Salmon, R.; Cochran, H.D. Jr.; McNeese, L.E.

    1982-10-05

    We divide coal liquefaction processes into four categories: (1) indirect liquefaction, such as Fischer-Tropsch and methanol synthesis, in which coal is fist gasified to produce a synthesis gas which is then recombined to produce liquids; (2) direct liquefaction processes, typified by H-Coal, Exxon Donor Solvent (EDS), and SRC-I and II, in which a slurry of coal and solvent is subjected to high severity liquefaction conditions, either with or without added catalyst; (3) two-stage liquefaction, such as Conoco's CSF process, in which an initial dissolution at mild conditions is followed by a more severe catalytic hydrogenation-hydrocracking step; or the short contact time two-stage liquefaction processes being developed currently by groups which include Chevron, Electric Power Research Institute (EPRI), Department of Energy/Fossil Energy (DOE/FE); and (4) pyrolysis and hydropyrolysis processes, such as COED and Cities Service-Rockewell, in which coal is carbonized to produce liquids, gases, and char. Pilot plant experience with the various processes is reviewed (including equipment problems, corrosion and abrasion, refractory life, heat recovery, coke deposits, reactor kinetics, scale-up problems, health hazards, environmental impacts, upgrading products, economics, etc.). Commercialization possibilities are discussed somewhat pessimistically in the light of reduction of US Oil imports, weakening oil prices, conversion to coal, smaller automobiles, economics and finally, some uncertainty about SFC goals and policies. (LTN)

  12. Coal liquefaction: investigation of reactor performance, role of catalysts and PCT properties. Quarterly progress report, October 1, 1984-December 31, 1984

    SciTech Connect (OSTI)

    Brainard, A.J.; Shah, Y.T.; Tierney, J.W.; Wender, I.; Badgujar, M.; Joseph, S.; Kerkar, A.; Ozturk, S.

    1984-01-01

    The objective of this work is to investigate areas of science and technology that have been defined as being of prime interest to coal processing technology development. These areas include properties of coal liquids and slurries, reactor design, and performance in relation to reaction mechanisms. The work comprises the following tasks: (1) reaction kinetics and reactor performance in direct coal liquefaction; (2) role of catalysts in indirect liquefaction and direct coal liquefaction; and (3) physical, chemical, and thermodynamic properties of coal liquefaction products. This report summarizes work done during the period October 1, 1984 through December 31, 1984. A detailed description of work in each of the three tasks is presented.

  13. EA-2036: Sabine Pass Liquefaction Project (design optimization); Cameron Parish, Louisiana

    Broader source: Energy.gov [DOE]

    In January 2014, the Federal Energy Regulatory Commission (FERC) issued an EA to analyze the potential environmental impacts associated with an application to amend FERC’s April 2012 authorization of the Sabine Pass Liquefaction Project in order to optimize its design and operation. In April 2015, Sabine Pass Liquefaction, LLC, and Sabine Pass LNG, L.P., applied to DOE’s Office of Fossil Energy (FE) seeking authorization to increase the amount of liquefied natural gas (LNG) to be exported from the facility above the level that FE authorized in August 2012. DOE adopted FERC’s EA for the optimization and issued a finding of no significant impact on March 11, 2016.

  14. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships. 3 figs.

  15. SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO.

    Energy Savers [EERE]

    10-85-LNG; 10-111-LNG; 13-121-LNG; 14-31-LNG; 13-30-LNG; 13-42-LNG; 14-92-LNG | Department of Energy SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-85-LNG; 10-111-LNG; 13-121-LNG; 14-31-LNG; 13-30-LNG; 13-42-LNG; 14-92-LNG SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-85-LNG; 10-111-LNG; 13-121-LNG; 14-31-LNG; 13-30-LNG; 13-42-LNG; 14-92-LNG PDF icon April 2011 PDF icon October 2011 PDF icon April 2012 PDF icon October 2012 PDF icon April 2013

  16. SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10-85-LNG; 10-111-LNG; 13-121-LNG; 14-31-LNG; 13-30-LNG; 13-42-LNG; 14-92-LNG | Department of Energy SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-85-LNG; 10-111-LNG; 13-121-LNG; 14-31-LNG; 13-30-LNG; 13-42-LNG; 14-92-LNG SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-85-LNG; 10-111-LNG; 13-121-LNG; 14-31-LNG; 13-30-LNG; 13-42-LNG; 14-92-LNG PDF icon April 2011 PDF icon October 2011 PDF icon April 2012 PDF icon October 2012 PDF icon April 2013 PDF icon October 2013

  17. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, Raymond P. (Overland Park, KS); Schmalzer, David K. (Englewood, CO); Wright, Charles H. (Overland Park, KS)

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships.

  18. Catalyst dispersion and activity under conditions of temperature-staged liquefaction

    SciTech Connect (OSTI)

    Davis, A.; Schobert, H.H.; Mitchell, G.D.; Artok, L.

    1993-02-01

    This research program involves the investigation of the use of highly dispersed catalyst precursors for the pretreatment of coals by mild hydrogenation. During the course of this effort solvent preswelling of the coal was evaluated as a means of deeply impregnating catalysts into coal, active phases of catalysts under reaction conditions were studied and the impact of these techniques were evaluated during pretreatment and temperature-staged liquefaction. Two coals, a Texas subbituminous and a Utah high volatile A bituminous, were used to examine the effects of solvent swelling pretreatment and catalyst impregnation on conversion behavior at 275[degrees]C, representative of the first, low-temperature stage in a temperature-staged liquefaction reaction. Ferrous sulfate, iron pentacarbonyl, ammonium tetrathiomolybdate, and molybdenum hexacarbonyl were used as catalyst precursors. Without swelling pretreatment, impregnation of both coals increased conversion, mainly through increased yields of preasphaltenes.

  19. Catalyst dispersion and activity under conditions of temperature-staged liquefaction. Final report

    SciTech Connect (OSTI)

    Davis, A.; Schobert, H.H.; Mitchell, G.D.; Artok, L.

    1993-02-01

    This research program involves the investigation of the use of highly dispersed catalyst precursors for the pretreatment of coals by mild hydrogenation. During the course of this effort solvent preswelling of the coal was evaluated as a means of deeply impregnating catalysts into coal, active phases of catalysts under reaction conditions were studied and the impact of these techniques were evaluated during pretreatment and temperature-staged liquefaction. Two coals, a Texas subbituminous and a Utah high volatile A bituminous, were used to examine the effects of solvent swelling pretreatment and catalyst impregnation on conversion behavior at 275{degrees}C, representative of the first, low-temperature stage in a temperature-staged liquefaction reaction. Ferrous sulfate, iron pentacarbonyl, ammonium tetrathiomolybdate, and molybdenum hexacarbonyl were used as catalyst precursors. Without swelling pretreatment, impregnation of both coals increased conversion, mainly through increased yields of preasphaltenes.

  20. Advanced direct liquefaction concepts for PETC generic units. Final report, Phase I

    SciTech Connect (OSTI)

    1995-03-01

    The Advanced Concepts for Direct Coal Liquefaction program was initiated by the Department of Energy in 1991 to develop technologies that could significantly reduce the cost of producing liquid fuels by the direct liquefaction of coal. The advanced 2-stage liquefaction technology that was developed at Wilsonville over the past 10 years has contributed significantly toward decreasing the cost of producing liquids from coal to about $33/bbl. It remains, however, the objective of DOE to further reduce this cost to a level more competitive with petroleum based products. This project, among others, was initiated to investigate various alternative approaches to develop technologies that might ultimately lead to a 25 % reduction in cost of product. In this project a number of novel concepts were investigated, either individually or in a coupled configuration that had the potential to contribute toward meeting the DOE goal. The concepts included mature technologies or ones closely related to them, such as coal cleaning by oil agglomeration, fluid coking and distillate hydrotreating and dewaxing. Other approaches that were either embryonic or less developed were chemical pretreatment of coal to remove oxygen, and dispersed catalyst development for application in the 2-stage liquefaction process. This report presents the results of this project. It is arranged in four sections which were prepared by participating organizations responsible for that phase of the project. A summary of the overall project and the principal results are given in this section. First, however, an overview of the process economics and the process concepts that were developed during the course of this program is presented.

  1. Coal liquefaction and hydrogenation: Processes and equipment. (Latest citations from the US Patent database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    The bibliography contains citations of selected patents concerning methods, processes, and apparatus for coal liquefaction and hydrogenation. Included are patents for catalytic two-stage, catalytic single-step, fixed-bed, hydrogen-donor, internal heat transfer, and multi-phase processes. Topics also include catalyst production, catalyst recovery, desulfurization, pretreatment of coals, energy recovery processes, solvent product separation, hydrogenating gases, and pollution control. (Contains 250 citations and includes a subject term index and title list.)

  2. Coal liquefaction: investigation of reactor performance, role of catalysts, and PCT properties. Technical progress report

    SciTech Connect (OSTI)

    Brainard, A.; Shah, Y.; Tierney, J.; Wender, I.; Joseph, S.; Kerkar, A.; Ozturk, S.; Sayari, A.

    1985-11-01

    This report is divided into two sections plus an appendix. The first section reports on computer simulations which were developed for three important coal liquefaction processes - the Mobil Methanol to Gasoline (MTG) process, the Fischer-Tropsch (F-T) process, and the synthesis of methanol. The models are designed to be general and information such as new kinetic equations or new physical property information can be readily added. Each of the models also provides for alternate reactor configurations. A comparison of results obtained using the models and results reported in the literature is included to verify the model. Comparisons of alternate processing methods are also included to provide guidance in the selection of a reactor configuration for a specific process. Complete program listings are given in the Appendix, and sample problems with inputs and outputs are provided for the user. The programs are written in the FORTRAN language. It is ultimately desirable to make these models available in a form which can be used in ASPEN, the process simulator developed for DOE. As a first step, the use of ASPEN PLUS to predict thermodynamic and transport properties of systems of interest to coal liquefaction was studied. In the second section, five areas of potential importance to indirect and direct coal liquefaction are reviewed. They are the synthesis of methanol via methyl formate, the role of carbon dioxide in methanol synthesis, the synthesis of methanol using noble metal catalysts, the catalytic synthesis of higher alcohols from a new, high-yield sulfur-tolerant catalyst, and the direct liquefaction of coal mixed with heavy oils - so-called coprocessing. Seven papers in the two sections have been processed for inclusion in the Energy Data Base.

  3. Research Summary: Corrosion Considerations for Thermochemical Biomass Liquefaction Process Systems in Biofuel Production

    SciTech Connect (OSTI)

    Brady, Michael P; Keiser, James R; Leonard, Donovan N; Whitmer, Lysle; Thomson, Jeffery K

    2014-01-01

    Thermochemical liquifaction processing of biomass to produce bio-derived fuels (e.g. gasoline, jet fuel, diesel, home heating oil, etc.) is of great recent interest as a renewable energy source. Approaches under investigation include direct liquefaction, hydrothermal liquefaction, hydropyrolysis, fast pyrolysis, etc. to produce energy dense liquids that can be utilized as produced or further processed to provide products of higher value. An issue with bio-oils is that they tend to contain significant concentrations of organic compounds, which make the bio-oil acidic and a potential source of corrosion issues in in transport, storage, and use. Efforts devoted to modified/further processing of bio-oils to make them less corrosive are currently being widely pursued. Another aspect that must also be addressed is potential corrosion issues in the bio-oil liquefaction process equipment itself. Depending on the specific process, bio-oil liquefaction production temperatures can reach up to 400-600 C, and involve the presence of aggressive sulfur, and halide species from both the biomass used and/or process additives. Detailed knowledge of the corrosion resistance of candidate process equipment alloys in these bio-oil production environments is currently lacking. This paper summarizes our recent, ongoing efforts to assess the extent to which corrosion of bio-oil process equipment may be an issue, with the ultimate goal of providing the basis to select the lowest cost alloy grades capable of providing the long-term corrosion resistance needed for future bio-oil production plants.

  4. Research Summary: Corrosion Considerations for Thermochemical Biomass Liquefaction Process Systems in Biofuel Production

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brady, Michael P; Keiser, James R; Leonard, Donovan N; Whitmer, Lysle; Thomson, Jeffery K

    2014-01-01

    Thermochemical liquifaction processing of biomass to produce bio-derived fuels (e.g. gasoline, jet fuel, diesel, home heating oil, etc.) is of great recent interest as a renewable energy source. Approaches under investigation include direct liquefaction, hydrothermal liquefaction, hydropyrolysis, fast pyrolysis, etc. to produce energy dense liquids that can be utilized as produced or further processed to provide products of higher value. An issue with bio-oils is that they tend to contain significant concentrations of organic compounds, which make the bio-oil acidic and a potential source of corrosion issues in in transport, storage, and use. Efforts devoted to modified/further processing of bio-oilsmore » to make them less corrosive are currently being widely pursued. Another aspect that must also be addressed is potential corrosion issues in the bio-oil liquefaction process equipment itself. Depending on the specific process, bio-oil liquefaction production temperatures can reach up to 400-600 C, and involve the presence of aggressive sulfur, and halide species from both the biomass used and/or process additives. Detailed knowledge of the corrosion resistance of candidate process equipment alloys in these bio-oil production environments is currently lacking. This paper summarizes our recent, ongoing efforts to assess the extent to which corrosion of bio-oil process equipment may be an issue, with the ultimate goal of providing the basis to select the lowest cost alloy grades capable of providing the long-term corrosion resistance needed for future bio-oil production plants.« less

  5. Coal liquefaction process streams characterization and evaluation: Application of liquid chromatographic separation methods to THF-soluble portions of integrated two-stage coal liquefaction resids

    SciTech Connect (OSTI)

    Green, J.B.; Pearson, C.D.; Young, L.L.; Green, J.A. )

    1992-05-01

    This study demonstrated the feasibility of using non-aqueous ion exchange liquid chromatography (NIELC) for the examination of the tetrahydrofuran (THF)-soluble distillation resids and THF-soluble whole oils derived from direct coal liquefaction. The technique can be used to separate the material into a number of acid, base, and neutral fractions. Each of the fractions obtained by NIELC was analyzed and then further fractionated by high-performance liquid chromatography (HPLC). The separation and analysis schemes are given in the accompanying report. With this approach, differences can be distinguished among samples obtained from different process streams in the liquefaction plant and among samples obtained at the same sampling location, but produced from different feed coals. HPLC was directly applied to one THF-soluble whole process oil without the NIELC preparation, with limited success. The direct HPLC technique used was directed toward the elution of the acid species into defined classes. The non-retained neutral and basic components of the oil were not analyzable by the direct HPLC method because of solubility limitations. Sample solubility is a major concern in the application of these techniques.

  6. Coal liquefaction process wherein jet fuel, diesel fuel and/or ASTM No. 2 fuel oil is recovered

    DOE Patents [OSTI]

    Bauman, Richard F.; Ryan, Daniel F.

    1982-01-01

    An improved process for the liquefaction of coal and similar solid carbonaceous materials wherein a hydrogen donor solvent or diluent derived from the solid carbonaceous material is used to form a slurry of the solid carbonaceous material and wherein the naphthenic components from the solvent or diluent fraction are separated and used as jet fuel components. The extraction increases the relative concentration of hydroaromatic (hydrogen donor) components and as a result reduces the gas yield during liquefaction and decreases hydrogen consumption during said liquefaction. The hydrogenation severity can be controlled to increase the yield of naphthenic components and hence the yield of jet fuel and in a preferred embodiment jet fuel yield is maximized while at the same time maintaining solvent balance.

  7. Direct liquefaction proof-of-concept program: Bench Run 05 (227-97). Final report

    SciTech Connect (OSTI)

    Comolli, A.G.; Pradhan, V.R.; Lee, T.L.K.; Karolkiewicz, W.F.; Popper, G.

    1997-04-01

    This report presents the results Bench Run PB-05, conducted under the DOE Proof of Concept - Bench Option Program in direct coal liquefaction at Hydrocarbon Technologies, Inc. in Lawrenceville, New Jersey. Bench Run PB-05 was the fifth of the nine runs planned in the POC Bench Option Contract between the U.S. DOE and included the evaluation of the effect of using dispersed slurry catalyst in direct liquefaction of a high volatile bituminous Illinois No. 6 coal and in combined coprocessing of coal with organic wastes, such as heavy petroleum resid, MSW plastics, and auto-shredder residue. PB-05 employed a two-stage, back-mixed, slurry reactor system with an interstage V/L separator and an in-line fixed-bed hydrotreater. Coprocessing of waste plastics with Illinois No. 6 coal did not result in the improvement observed earlier with a subbituminous coal. In particular, decreases in light gas yield and hydrogen consumption were not observed with Illinois No. 6 coal as they were with Black Thunder Mine coal. The higher thermal severity during PB-05 is a possible reason for this discrepancy, plastics being more sensitive to temperatures (cracking) than either coal or heavy resid. The ASR material was poorer than MSW plastics in terms of increasing conversions and yields. HTI`s new dispersed catalyst formulation, containing phosphorus-promoted iron gel, was highly effective for the direct liquefaction of Illinois No. 6 coal under the reaction conditions employed; over 95% coal conversion was obtained, along with over 85% residuum conversion and over 73% distillate yields.

  8. Effect of coal rank and process conditions on temperature distribution in a liquefaction reactor

    SciTech Connect (OSTI)

    Nalitham, R.V.; Moniz, M.

    1986-04-01

    The temperature distribution in a liquefaction reactor in the integrated TSL process is studied. The effects of gas and slurry superficial velocities, process solvent characteristics, reactor length, and catalyst sulfiding agent on the exotherm and temperature difference in the reactor are studied. A substantial temperature difference is observed with subbituminous coal as compared with bituminous coal, at comparable reactor conditions. Some of the factors that are believed to have contributed to the large exotherm and temperature difference in the reactor are slow kinetics and high reaction heat for subbituminous coal conversion and pyrrhotite catalysis.

  9. Automated apparatus for solvent separation of a coal liquefaction product stream

    DOE Patents [OSTI]

    Schweighardt, Frank K. (Upper Macungie, PA)

    1985-01-01

    An automated apparatus for the solvent separation of a coal liquefaction product stream that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In use of the apparatus, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control means. The mixture in the filter is agitated by means of ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

  10. Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction. Technical progress report, December 1992--March 1993

    SciTech Connect (OSTI)

    Song, C.; Saini, A.K.; Wenzel, K.; Huang, L.; Hatcher, P.G.; Schobert, H.H.

    1993-04-01

    This work is a fundamental study of catalytic pretreatments as a potential preconversion step to low-severity liquefaction. The ultimate goal of this work is to provide the basis for the design of an improved liquefaction process and to facilitate our understanding of those processes that occur when coals are initially dissolved. The main objectives of this project are to study the effects of low-temperature pretreatments on coal structure and their impacts on the subsequent liquefaction. The effects of pretreatment temperatures, catalyst type, coal rank and influence of solvent will be examined. We have made significant progress in the following four aspects during this quarterly period: (1) influence of drying and oxidation of coal on the conversion and product distribution in catalytic liquefaction of Wyodak subbituminous coal using a dispersed catalyst; (2) spectroscopic characterization of dried and oxidized Wyodak coal and the insoluble residues from catalytic and thermal liquefaction; (3) the structural alteration of low-rank coal in low-severity liquefaction with the emphasis on the oxygen-containing functional groups; and (4) effects of solvents and catalyst dispersion methods in temperature-programmed and non-programmed liquefaction of three low-rank coals.

  11. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID); Bingham, Dennis N. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID); Turner, Terry D. (Ammon, ID); Raterman, Kevin T. (Idaho Falls, ID); Palmer, Gary L. (Shelley, ID); Klingler, Kerry M. (Idaho Falls, ID); Vranicar, John J. (Concord, CA)

    2007-05-22

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through a turbo expander creating work output. A compressor is driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream. Additional features and techniques may be integrated with the liquefaction process including a water clean-up cycle and a carbon dioxide (CO.sub.2) clean-up cycle.

  12. Low severity coal liquefaction promoted by cyclic olefins. Quarterly report, April--June 1992

    SciTech Connect (OSTI)

    Curtis, C.W.

    1992-07-27

    Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

  13. Process Design and Economics for the Conversion of Algal Biomass to Hydrocarbons: Whole Algae Hydrothermal Liquefaction and Upgrading

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Anderson, Daniel B.; Hallen, Richard T.; Elliott, Douglas C.; Schmidt, Andrew J.; Albrecht, Karl O.; Hart, Todd R.; Butcher, Mark G.; Drennan, Corinne; Snowden-Swan, Lesley J.; Davis, Ryan; Kinchin, Christopher

    2014-03-20

    This report provides a preliminary analysis of the costs associated with converting whole wet algal biomass into primarily diesel fuel. Hydrothermal liquefaction converts the whole algae into an oil that is then hydrotreated and distilled. The secondary aqueous product containing significant organic material is converted to a medium btu gas via catalytic hydrothermal gasification.

  14. Short contact time direct coal liquefaction using a novel batch reactor. Quarterly technical progress report, September 15, 1995--January 15, 1996

    SciTech Connect (OSTI)

    Klein, M.T.; Calkins, W.H.; Huang, He

    1996-01-26

    The objective of this research is to optimize the design and operation of the bench scale batch reactor (SCTBR) f or coal liquefaction at short contact times (0.01 to 10 minutes or longer). Additional objectives are to study the kinetics of direct coal liquefaction particularly at short reaction times, and to investigate the role of the organic oxygen components of coal and their reaction pathways during liquefaction. Many of those objectives have already been achieved and others are still in progress. This quarterly report covers further progress toward those objectives.

  15. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, October 1--December 31, 1994

    SciTech Connect (OSTI)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-05-01

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. During this quarter, analyses were completed on 65 process samples from representative periods of HRI Run POC-2 in which coal, coal/plastics, and coal/rubber were the feedstocks. A sample of the oil phase of the oil/water separator from HRI Run POC-1 was analyzed to determine the types and concentrations of phenolic compounds. Chemical analyses and microautoclave tests were performed to monitor the oxidation and measure the reactivity of the standard coal (Old Ben Mine No. 1) which has been used for the last six years to determine solvent quality of process oils analyzed in this and previous DOE contracts.

  16. Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Topical report No. 14. Catalyst activity trends in two-stage coal liquefaction

    SciTech Connect (OSTI)

    Not Available

    1984-02-01

    The Two Stage Coal Liquefaction process became operational at Wilsonville in May 1981, with the inclusion of an H-OIL ebullated-bed catalytic reactor. The two stage process was initially operated in a nonintegrated mode and has recently been reconfigurated to fully integrate the thermal and the catalytic stages. This report focuses on catalyst activity trends observed in both modes of operation. A literature review of relevant catalyst screening studies in bench-scale and PDU units is presented. Existing kinetic and deactivation models were used to analyze process data over an extensive data base. Based on the analysis, three separate, application studies have been conducted. The first study seeks to elucidate the dependence of catalyst deactivation rate on type of coal feedstock used. A second study focuses on the significance of catalyst type and integration mode on SRC hydrotreatment. The third study presents characteristic deactivation trends observed in integrated operation with different first-stage thermal severities. In-depth analytical work was conducted at different research laboratories on aged catalyst samples from Run 242. Model hydrogenation and denitrogenation activity trends are compared with process activity trends and with changes observed in catalyst porosimetric properties. The accumulation of metals and coke deposits with increasing catalyst age, as well as their distribution across a pellet cross-section, are discussed. The effect of catalyst age and reactor temperature on the chemical composition of flashed bottoms product is addressed. Results from regenerating spent catalysts are also presented. 35 references, 31 figures, 18 tables.

  17. Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oils Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mild Biomass Liquefaction Process for Economic Production of Stabilized Refinery-Ready Bio-oils March 23-27, 2015 Thermochemical Conversion Principal Investigator: Santosh Gangwal Technical Leaders: August Meng and Kevin McCabe Southern Research January 5 th , 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement  Project Goal - Develop a mild thermochemical liquefaction process to convert woody biomass to stabilized

  18. Characterization and Valorization of Aqueous Phases Derived from Liquefaction and Upgrading of Bio-oils Presentations for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Characterization and Valorization of Aqueous Phases Derived from Liquefaction and Upgrading of Bio-oils WBS: 2.3.1.310 March 27, 2015 Thermochemical Conversion Technology Area Review Karl O. Albrecht, Robert A. Dagle (co-PI) and Daniel T. Howe (co-PI) Pacific Northwest National Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information PNNL-SA-108318 Goal Statement Challenge: Direct liquefaction processes produce aqueous streams 1. The

  19. A characterization and evaluation of coal liquefaction process streams. Quarterly report, January 1--March 31, 1997

    SciTech Connect (OSTI)

    Robbins, G.A.; Brandes, S.D.; Heunisch, G.W.; Winschel, R.A.

    1998-08-01

    Described in this report are the following activities: CONSOL characterized process stream samples from HTI Run ALC-2, in which Black Thunder Mine coal was liquefied using four combinations of dispersed catalyst precursors. Oil assays were completed on the HTI Run PB-05 product blend. Fractional distillation of the net product oil of HTI Run POC-1 was completed. CONSOL completed an evaluation of the potential for producing alkylphenyl ethers from coal liquefaction phenols. At the request of DOE, various coal liquid samples and relevant characterization data were supplied to the University of West Virginia and the Federal Energy Technology Center. The University of Delaware is conducting resid reactivity tests and is completing the resid reaction computer model. The University of Delaware was instructed on the form in which the computer model is to be delivered to CONSOL.

  20. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Turner, Terry D. (Ammon, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2009-09-22

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates a vapor from the liquid natural gas. A portion of the liquid gas is used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line or recirculation within the system for further processing.

  1. Apparatus for the liquefaction of a gas and methods relating to same

    DOE Patents [OSTI]

    Turner, Terry D. (Idaho Falls, ID) [Idaho Falls, ID; Wilding, Bruce M. (Idaho Falls, ID) [Idaho Falls, ID; McKellar, Michael G. (Idaho Falls, ID) [Idaho Falls, ID

    2009-12-29

    Apparatuses and methods are provided for producing liquefied gas, such as liquefied natural gas. In one embodiment, a liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream may be sequentially pass through a compressor and an expander. The process stream may also pass through a compressor. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. A portion of the liquid gas may be used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line.

  2. Apparatus for the liquefaction of natural gas and methods relating to same

    DOE Patents [OSTI]

    Wilding, Bruce M. (Idaho Falls, ID) [Idaho Falls, ID; McKellar, Michael G. (Idaho Falls, ID) [Idaho Falls, ID; Turner, Terry D. (Ammon, ID) [Ammon, ID; Carney, Francis H. (Idaho Falls, ID) [Idaho Falls, ID

    2009-09-29

    An apparatus and method for producing liquefied natural gas. A liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream passes through an expander creating work output. A compressor may be driven by the work output and compresses the process stream. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is divided into first and second portions with the first portion being expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. The second portion of the cooled, compressed process stream is also expanded and used to cool the compressed process stream.

  3. Cooperative research in coal liquefaction. Final report, May 1, 1992--April 30, 1993

    SciTech Connect (OSTI)

    Huffman, G.P.

    1996-03-01

    Research on sulfate and metal (Mo, Sn) promoted Fe{sub 2}O{sub 3} catalysts in the current year focused on optimization of conditions. Parameters varied included temperature, solvent, solvent-to-coal ratio, and the effect of presulfiding versus in situ sulfiding. Oil yields were found to increase approximately proportionately with both temperature and solvent-to-coal ratio. The donor solvent, tetralin, proved to give better total conversion and oil yields than either 1-methylnaphthalene or Wilsonville recycle oil. A significant enhancement of both total liquefaction yields and oil yields from lignites and subbituminous coals has been achieved by incorporating iron into the coal matrix by cation exchange. A study has been conducted on the synthesis of iron, molybdenum, and tungsten catalysts using a laser pyrolysis technique.

  4. Process for coal liquefaction by separation of entrained gases from slurry exiting staged dissolvers

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Ying, David H. S. (Macungie, PA)

    1983-01-01

    There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a solvent, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals are separated from the condensed dissolver effluent. In accordance with the improved process, fresh hydrogen is fed to each dissolver and the entrained gas from each dissolver is separated from the slurry phase and removed from the reactor system before the condensed phase is passed to the next dissolver in the series. In accordance with another process, the feeds to the dissolvers are such that the top of each downstream dissolver is used as a gas-liquid separator.

  5. Technical and economic evaluation of selected coal-liquefaction processes. Phase O. Preliminary screening evaluations

    SciTech Connect (OSTI)

    Salmon, R.; Forrester, R.C. III; Singh, S.P.N.; Fisher, J.F.; Wham, R.M.; Thiel, S.W.; Meyer, J.P.

    1981-04-01

    Preliminary scoping evaluations of ten conceptual coal liquefaction processes were made for the Department of Energy using available published information. Production costs calculated under a consistent set of economic criteria varied from $0.78 to $1.47/gal for gasoline in constant 1979 dollars. However, existing design documents showed little consistency as to status of process development, credibility of process design basis, completeness of design, or conservatism of cost estimation. We concluded that a more complete and thorough design study of each process would be necessary to achieve any degree of technical and economic consistency, and that it was therefore not possible to satisfy DOE's desire for consistent technical and economic comparisons in this type of preliminary scoping study.

  6. Catalytic two-stage coal liquefaction process having improved nitrogen removal

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA)

    1991-01-01

    A process for catalytic multi-stage hydrogenation and liquefaction of coal to produce high yields of low-boiling hydrocarbon liquids containing low concentrations of nitogen compounds. First stage catalytic reaction conditions are 700.degree.-800.degree. F. temperature, 1500-3500 psig hydrogen partial pressure, with the space velocity maintained in a critical range of 10-40 lb coal/hr ft.sup.3 catalyst settled volume. The first stage catalyst has 0.3-1.2 cc/gm total pore volume with at least 25% of the pore volume in pores having diameters of 200-2000 Angstroms. Second stage reaction conditions are 760.degree.-870.degree. F. temperature with space velocity exceeding that in the first stage reactor, so as to achieve increased hydrogenation yield of low-boiling hydrocarbon liquid products having at least 75% removal of nitrogen compounds from the coal-derived liquid products.

  7. Design of generic coal conversion facilities: Indirect coal liquefaction, Fischer-Tropsch synthesis

    SciTech Connect (OSTI)

    Not Available

    1991-10-01

    A comprehensive review of Fischer-Tropsch (F-T) technology, including fixed, fluidized, and bubble column reactors, was undertaken in order to develop an information base before initiating the design of the Fischer-Tropsch indirect liquefaction PDU as a part of the Generic Coal Conversion Facilities to be built at the Pittsburgh Energy Technology Center (PETC). The pilot plant will include a fixed bed and slurry bubble column reactor for the F-T mode of operation. The review encompasses current status of both these technologies, their key variables, catalyst development, future directions, and potential improvement areas. However, more emphasis has been placed on the slurry bubble column reactor since this route is likely to be the preferred technology for commercialization, offering process advantages and, therefore, better economics than fixed and fluidized bed approaches.

  8. Liquefaction/solubilization of low-rank Turkish coals by white-rot fungus (Phanerochaete chrysosporium)

    SciTech Connect (OSTI)

    Elbeyli, I.Y.; Palantoken, A.; Piskin, S.; Kuzu, H.; Peksel, A.

    2006-08-15

    Microbial coal liquefaction/solubilization of three low-rank Turkish coals (Bursa-Kestelek, Kutahya-Seyitomer and Mugla-Yatagan lignite) was attempted by using a white-rot fungus (Phanerochaete chrysosporium DSM No. 6909); chemical compositions of the products were investigated. The lignite samples were oxidized by nitric acid under moderate conditions and then oxidized samples were placed on the agar medium of Phanerochaete chrysosporium. FTIR spectra of raw lignites, oxidized lignites and liquid products were recorded, and the acetone-soluble fractions of these samples were identified by GC-MS technique. Results show that the fungus affects the nitro and carboxyl/carbonyl groups in oxidized lignite sample, the liquid products obtained by microbial effects are the mixture of water-soluble compounds, and show limited organic solubility.

  9. Laboratory verification of blast-induced liquefaction mechanism. Final report Jan-Jul 81

    SciTech Connect (OSTI)

    Fragaszy, R.J.; Voss, M.E.

    1981-10-01

    A mechanism for blast-induced liquefaction was tested in a series of high pressure undrained, isotropic compression tests on saturated samples of Eniwetok beach sand and Ottawa sand. Theory, based on inelastic volume compressibility of sand, was shown to be valid for the case of quasi-static, isotropic loading. Specimens of Eniwetok sand subjected to an initial effective stress of 1 MPa were liquefied by a single cycle of loading of 34 MPa. Specimens of Ottawa sand, tested in the same manner, generated excess pore pressure but not enough to completely liquefy the soil. The errors introduced by flexibility of the testing systems were analyzed and found to be insignificant. Suggestions for future research were made.

  10. Investigation on the two-stage active magnetic regenerative refrigerator for liquefaction of hydrogen

    SciTech Connect (OSTI)

    Park, Inmyong; Park, Jiho; Jeong, Sangkwon; Kim, Youngkwon

    2014-01-29

    An active magnetic regenerative refrigerator (AMRR) is expected to be useful for hydrogen liquefaction due to its inherent high thermodynamic efficiency. Because the temperature of the cold end of the refrigerator has to be approximately liquid temperature, a large temperature span of the active magnetic regenerator (AMR) is indispensable when the heat sink temperature is liquid nitrogen temperature or higher. Since magnetic refrigerants are only effective in the vicinity of their own transition temperatures, which limit the temperature span of the AMR, an innovative structure is needed to increase the temperature span. The AMR must be a layered structure and the thermophysical matching of magnetic field and flow convection effects is very important. In order to design an AMR for liquefaction of hydrogen, the implementation of multi-layered AMR with different magnetic refrigerants is explored with multi-staging. In this paper, the performance of the multi-layered AMR using four rare-earth compounds (GdNi{sub 2}, Gd{sub 0.1}Dy{sub 0.9}Ni{sub 2}, Dy{sub 0.85}Er{sub 0.15}Al{sub 2}, Dy{sub 0.5}Er{sub 0.5}Al{sub 2}) is investigated. The experimental apparatus includes two-stage active magnetic regenerator containing two different magnetic refrigerants each. A liquid nitrogen reservoir connected to the warm end of the AMR maintains the temperature of the warm end around 77 K. High-pressure helium gas is employed as a heat transfer fluid in the AMR and the maximum magnetic field of 4 T is supplied by the low temperature superconducting (LTS) magnet. The temperature span with the variation of parameters such as phase difference between magnetic field and mass flow rate of magnetic refrigerants in AMR is investigated. The maximum temperature span in the experiment is recorded as 50 K and several performance issues have been discussed in this paper.

  11. Hydrogen Liquefaction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Internationally 4-7 European Installations 4-6 Japanese Installations India Program ESA French Guiana (South America) 4 Satisfies ASME J-2719 (hydrogen ...

  12. Development of an extruder-feeder biomass direct liquefaction process. Volume 2, Parts 4--8: Final report

    SciTech Connect (OSTI)

    White, D.H.; Wolf, D.

    1991-10-01

    As an abundant, renewable, domestic energy resource, biomass could help the United States reduce its dependence on imported oil. Biomass is the only renewable energy technology capable of addressing the national need for liquid transportation fuels. Thus, there is an incentive to develop economic conversion processes for converting biomass, including wood, into liquid fuels. Through research sponsored by the US DOE`s Biomass Thermochemical Conversion Program, the University of Arizona has developed a unique biomass direct liquefaction system. The system features a modified single-screw extruder capable of pumping solid slurries containing as high as 60 wt% wood flour in wood oil derived vacuum bottoms at pressures up to 3000 psi. The extruder-feeder has been integrated with a unique reactor by the University to form a system which offers potential for improving high pressure biomass direct liquefaction technology. The extruder-feeder acts simultaneously as both a feed preheater and a pumping device for injecting wood slurries into a high pressure reactor in the biomass liquefaction process. An experimental facility was constructed and following shakedown operations, wood crude oil was produced by mid-1985. By July 1988, a total of 57 experimental continuous biomass liquefaction runs were made using White Birch wood feedstock. Good operability was achieved at slurry feed rates up to 30 lb/hr, reactor pressures from 800 to 3000 psi and temperatures from 350{degree}C to 430{degree}C under conditions covering a range of carbon monoxide feed rates and sodium carbonate catalyst addition. Crude wood oils containing as little as 6--10 wt% residual oxygen were produced. 38 refs., 82 figs., 26 tabs.

  13. Liquefaction process wherein solvents derived from the material liquefied and containing increased concentrations of donor species are employed

    DOE Patents [OSTI]

    Fant, B. T. (Kingwood, TX); Miller, John D. (Baytown, TX); Ryan, D. F. (Friendswood, TX)

    1982-01-01

    An improved process for the liquefaction of solid carbonaceous materials wherein a solvent or diluent derived from the solid carbonaceous material being liquefied is used to form a slurry of the solid carbonaceous material and wherein the solvent or diluent comprises from about 65 to about 85 wt. % hydroaromatic components. The solvent is prepared by first separating a solvent or diluent distillate fraction from the liquefaction product, subjecting this distillate fraction to hydrogenation and then extracting the naphthenic components from the hydrogenated product. The extracted naphthenic components are then dehydrogenated and hydrotreated to produce additional hydroaromatic components. These components are combined with the solvent or diluent distillate fraction. The solvent may also contain hydroaromatic constituents prepared by extracting naphthenic components from a heavy naphtha, dehydrogenating the same and then hydrotreating the dehydrogenated product. When the amount of solvent produced in this manner exceeds that required for steady state operation of the liquefaction process a portion of the solvent or diluent distillated fraction will be withdrawn as product.

  14. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 1, Final technical report, October 1, 1991--September 30, 1994

    SciTech Connect (OSTI)

    Curtis, C.W.; Gutterman, C.; Chander, S.

    1994-12-31

    The overall objective of this project was to develop a new approach for the direct liquefaction of coal to produce an all-distillate product slate at a sizable cost reduction over current technology. The approach integrated coal selection, pretreatment, coal swelling with catalyst impregnation, liquefaction, product recovery with characterization, alternate bottoms processing, and a technical assessment including an economic evaluation. Heterofunctional solvents were the most effective in swelling coals. Also solvent blends such as isopropanol/water were more effective than pure solvents alone. Impregnating slurry catalysts simultaneously during coal swelling showed that better uptake was achieved with nonswelling solvent and higher impregnation temperature. Some enhancement in initial coal conversion was seen liquefying SO{sub 2}-treated Black Thunder coal with slurry catalysts, and also when hydrogen donor liquefaction solvents were used. Noncatalytic reactions showed no benefit from SO{sub 2} treatment. Coupling coal swelling and SO{sub 2} treatment with slurry catalysts was also not beneficial, although high conversion was seen with continuous operation and long residence time, however, similar high conversion was observed with untreated coal. SO{sub 2} treatment is not economically attractive unless it provides about 17% increase in coal reactivity. In most cases, the best results were obtained when the coal was untreated and the slurry catalyst was added directly into the reactor. Foster Wheeler`s ASCOT process had better average liquid yields than either Wilsonville`s vacuum tower/ROSE combination or delayed coking process. This liquid product also had good quality.

  15. Selection of components for the IDEALHY preferred cycle for the large scale liquefaction of hydrogen

    SciTech Connect (OSTI)

    Quack, H.; Seemann, I.; Klaus, M.; Haberstroh, Ch.; Berstad, D.; Walnum, H. T.; Neksa, P.; Decker, L.

    2014-01-29

    In a future energy scenario, in which storage and transport of liquid hydrogen in large quantities will be used, the efficiency of the liquefaction of hydrogen will be of utmost importance. The goal of the IDEALHY working party is to identify the most promising process for a 50 t/d plant and to select the components, with which such a process can be realized. In the first stage the team has compared several processes, which have been proposed or realized in the past. Based on this information a process has been selected, which is thermodynamically most promising and for which it could be assumed that good components already exist or can be developed in the foreseeable future. Main features of the selected process are the compression of the feed stream to a relatively high pressure level, o-p conversion inside plate-fin heat exchangers and expansion turbines in the supercritical region. Precooling to a temperature between 150 and 100 K will be obtained from a mixed refrigerant cycle similar to the systems used successfully in natural gas liquefaction plants. The final cooling will be produced by two Brayton cycles, both having several expansion turbines in series. The selected overall process has still a number of parameters, which can be varied. The optimum, i.e. the final choice will depend mainly on the quality of the available components. Key components are the expansion turbines of the two Brayton cycles and the main recycle compressor, which may be common to both Brayton cycles. A six-stage turbo-compressor with intercooling between the stages is expected to be the optimum choice here. Each stage may consist of several wheels in series. To make such a high efficient and cost-effective compressor feasible, one has to choose a refrigerant, which has a higher molecular weight than helium. The present preferred choice is a mixture of helium and neon with a molecular weight of about 8 kg/kmol. Such an expensive refrigerant requires that the whole refrigeration loop is extremely tight.

  16. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    SciTech Connect (OSTI)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  17. Coal liquefaction process utilizing coal/CO.sub.2 slurry feedstream

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (S. Somerville, NJ)

    1989-01-01

    A coal hydrogenation and liquefaction process in which particulate coal feed is pressurized to an intermediate pressure of at least 500 psig and slurried with CO.sub.2 liquid to provide a flowable coal/CO.sub.2 slurry feedstream, which is further pressurized to at least 1000 psig and fed into a catalytic reactor. The coal particle size is 50-375 mesh (U.S. Sieve Series) and provides 50-80 W % coal in the coal/CO.sub.2 slurry feedstream. Catalytic reaction conditions are maintained at 650.degree.-850.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and coal feed rate of 10-100 lb coal/hr ft.sup.3 reactor volume to produce hydrocarbon gas and liquid products. The hydrogen and CO.sub.2 are recovered from the reactor effluent gaseous fraction, hydrogen is recycled to the catalytic reactor, and CO.sub.2 is liquefied and recycled to the coal slurrying step. If desired, two catalytic reaction stages close coupled together in series relation can be used. The process advantageously minimizes the recycle and processing of excess hydrocarbon liquid previously needed for slurrying the coal feed to the reactor(s).

  18. Coal liquefaction process streams characterization and evaluation. Quarterly technical progress report, April 1--June 30, 1992

    SciTech Connect (OSTI)

    Brandes, S.D.; Lancet, M.S.; Robbins, G.A.; Winschel, R.A.; Burke, F.P.

    1992-11-01

    This is the eleventh Quarterly Technical Progress Report under DOE Contract DE-AC22-89PC89883. Major topics reported are: (1) The results of a study designed to determine the effects of the conditions employed at the Wilsonville slurry preheater vessel on coal conversion is described. (2) Stable carbon isotope ratios were determined and used to source the carbon of three product samples from Period 49 of UOP bench-scale coprocessing Run 37. The results from this coprocessing run agree with the general trends observed in other coprocessing runs that we have studied. (3) Microautoclave tests and chemical analyses were performed to ``calibrate`` the reactivity of the standard coal used for determining donor solvent quality of process oils in this contract. (4) Several aspects of Wilsonville Close-Coupled Integrated Two-Stage Liquefaction (CC-ITSL) resid conversion kinetics were investigated; results are presented. Error limits associated with calculations of deactivation rate constants previously reported for Runs 258 and 261 are revised and discussed. A new procedure is described that relates the conversions of 850{degrees}F{sup +} , 1050{degrees}F{sup +}, and 850 {times} 1050{degrees}F material. Resid conversions and kinetic constants previously reported for Run 260 were incorrect; corrected data and discussion are found in Appendix I of this report.

  19. Process Development for Hydrothermal Liquefaction of Algae Feedstocks in a Continuous-Flow Reactor

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Schmidt, Andrew J.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.; Albrecht, Karl O.; Hallen, Richard T.; Holladay, Johnathan E.

    2013-10-01

    Wet algae slurries can be converted into an upgradeable biocrude by hydrothermal liquefaction (HTL). High levels of carbon conversion to gravity-separable biocrude product were accomplished at relatively low temperature (350 ?C) in a continuous-flow, pressurized (sub-critical liquid water) environment (20 MPa). As opposed to earlier work in batch reactors reported by others, direct oil recovery was achieved without the use of a solvent and biomass trace components were removed by processing steps so that they did not cause process difficulties. High conversions were obtained even with high slurry concentrations of up to 35 wt% of dry solids. Catalytic hydrotreating was effectively applied for hydrodeoxygenation, hydrodenitrogenation, and hydrodesulfurization of the biocrude to form liquid hydrocarbon fuel. Catalytic hydrothermal gasification was effectively applied for HTL byproduct water cleanup and fuel gas production from water soluble organics, allowing the water to be considered for recycle of nutrients to the algae growth ponds. As a result, high conversion of algae to liquid hydrocarbon and gas products was found with low levels of organic contamination in the byproduct water. All three process steps were accomplished in bench-scale, continuous-flow reactor systems such that design data for process scale-up was generated.

  20. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect (OSTI)

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  1. Development of Hydrothermal Liquefaction and Upgrading Technologies for Lipid-Extracted Algae Conversion to Liquid Fuels

    SciTech Connect (OSTI)

    Zhu, Yunhua; Albrecht, Karl O.; Elliott, Douglas C.; Hallen, Richard T.; Jones, Susanne B.

    2013-10-01

    Bench-scale tests were performed for lipid-extracted microalgae (LEA) conversion to liquid fuels via hydrotreating liquefaction (HTL) and upgrading processes. Process simulation and economic analysis for a large-scale LEA HTL and upgrading system were developed based on the best available test results. The system assumes an LEA feed rate of 608 dry metric ton/day and that the feedstock is converted to a crude HTL bio-oil and further upgraded via hydrotreating and hydrocracking to produce liquid hydrocarbon fuels, mainly alkanes. Performance and cost results demonstrate that HTL would be an effective option to convert LEA to liquid fuel. The liquid fuels annual yield was estimated to be 26.9 million gallon gasoline-equivalent and the overall energy efficiency at higher heating value basis was estimated to be 69.5%. The minimum fuel selling price (MFSP) was estimated to be $0.75/L with LEA feedstock price at $33.1 metric ton at dry basis and 10% internal rate of return. A sensitivity analysis indicated that the largest effects to production cost would come from the final products yields and the upgrading equipments cost. The impact of plant scale on MFSP was also investigated.

  2. Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2002-01-01

    A process for the separation and liquefaction of component gasses from a pressurized mix gas stream is disclosed. The process involves cooling the pressurized mixed gas stream in a heat exchanger so as to condensing one or more of the gas components having the highest condensation point; separating the condensed components from the remaining mixed gas stream in a gas-liquid separator; cooling the separated condensed component stream by passing it through an expander; and passing the cooled component stream back through the heat exchanger such that the cooled component stream functions as the refrigerant for the heat exchanger. The cycle is then repeated for the remaining mixed gas stream so as to draw off the next component gas and further cool the remaining mixed gas stream. The process continues until all of the component gases are separated from the desired gas stream. The final gas stream is then passed through a final heat exchanger and expander. The expander decreases the pressure on the gas stream, thereby cooling the stream and causing a portion of the gas stream to liquify within a tank. The portion of the gas which is hot liquefied is passed back through each of the heat exchanges where it functions as a refrigerant.

  3. Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2000-01-01

    A process for the separation and liquefaction of component gasses from a pressurized mix gas stream is disclosed. The process involves cooling the pressurized mixed gas stream in a heat exchanger so as to condense one or more of the gas components having the highest condensation point; separating the condensed components from the remaining mixed gas stream in a gas-liquid separator; cooling the separated condensed component stream by passing it through an expander; and passing the cooled component stream back through the heat exchanger such that the cooled component stream functions as the refrigerant for the heat exchanger. The cycle is then repeated for the remaining mixed gas stream so as to draw off the next component gas and further cool the remaining mixed gas stream. The process continues until all of the component gases are separated from the desired gas stream. The final gas stream is then passed through a final heat exchanger and expander. The expander decreases the pressure on the gas stream, thereby cooling the stream and causing a portion of the gas stream to liquify within a tank. The portion of the gas which is not liquefied is passed back through each of the heat exchanges where it functions as a refrigerant.

  4. Effect of product upgrading on Fischer-Tropsch indirect coal liquefaction economics

    SciTech Connect (OSTI)

    Choi, G.N.; Kramer, S.J.; Tam, S.S.; Fox, J.M. III

    1995-12-31

    Conceptual plant designs with cost estimates for indirect coal liquefaction technology to produce environmentally acceptable transportation liquid fuels meeting the Clear Air Act requirements were developed for the US Department of Energy (DOE). The designs incorporate the latest development in coal gasification technology and advanced Fischer-Tropsch (F-T) slurry reactor design. ASPEN process simulation models were developed to provide detailed plant material and energy balances, utility requirements, operating and capital costs. A linear programming model based on a typical PADD II refinery was developed to assess the values of the produced F-T products. The results then were used in a discounted cash flow spreadsheet model to examine the effect of key process variables on the overall F-T economics. Different models were developed to investigate the various routes of upgrading the F-T products. The effects of incorporating a close-coupled ZSM-5 reactor to upgrade the vapor stream leaving the Fischer-Tropsch reactor have been reported previously. This paper compares two different schemes of F-T was upgrading, namely fluidized bed catalytic cracking verse mild hydrocracking.

  5. Some Important Aspects of Physical Modelling of Liquefaction in 1-g Shaking Table

    SciTech Connect (OSTI)

    Alam, Md. Jahangir; Towhata, Ikuo

    2008-07-08

    Physical modeling of liquefaction in 1-g shaking table and dynamic centrifuge test become very popular to simulate the ground behavior during earthquake motion. 1-g shaking table tests require scaled down model ground which can be prepared in three methods; water sedimentation, moist tamping and dry deposition method. Moist tamping and dry deposition method need saturation of model ground which is expensive and very difficult to achieve. Some model tests were performed in 1-g shaking table to see the influence of preparation method of model ground. Wet tamping and water sedimentation method of ground preparation were compared in these tests. Behavior of level ground and slope were also examined. Slope and level ground model test increased the understanding of excess pore pressure generation in both cases. Wet tamping method has a possibility of not being fully saturated. Pore pressure transducers should be fixed vertically so that it can not settle down during shaking but can move with ground. There was insignificant difference in acceleration and excess pore pressure responses between wet tamping and water sedimentation method in case of level ground. Spiky accelerations were prominent in slope prepared by water sedimentation method. Spiky accelerations were the result of lateral displacement induced dilatancy of soil.

  6. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Technical progress report, October--December 1993

    SciTech Connect (OSTI)

    Schmidt, E.; Kirby, S.; Song, Chunshan; Schobert, H.H.

    1994-04-01

    Development of new catalysts is a promising approach to more, efficient coal liquefaction. It has been recognized that dispersed catalysts can be superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires infinite contact between the catalyst and coal. The primary objective of this research is to explore the potential of bimetallic dispersed catalysts from heterometallic molecular precursors in their use in model compound liquefaction reactions. This quarterly report describes the use of three precursors in model compound reactions. The first catalyst is a heterometallic complex consisting of two transition metals, Mo and Ni, and sulfur in a single molecule. The second is a thiocubane type complex consisting of cobalt, molybdenum and sulfur. The third is a thiocubane type cluster consisting of iron and sulfur and the fourth, the pure inorganic salt ammonium tetrathiomolybdate (ATM). It was found that the structure and the ligands in the model complexes affect the activity of the resulting catalyst significantly. The optimum reaction at a pressure of 6.9 MPa hydrogen gas varied for different catalysts. The bimetallic catalysts generated in situ from the organometallic precursor are more active than monometallic catalysts like ATTM and the thiocubane type cluster Fe{sub 4}. Main products are hydrogenated phenanthrene derivatives, like DBP, THP, sym-OHP, cis- and trans-unsym-OHP with minor isomerization products such as sym-OHA. Our results indicate that other transition metal and ligand combinations in the organometallic precursors and the use of another model compound could result in substantially higher conversion activity.

  7. New technology concept for two-stage liquefaction of coal. Final summary report, 1 July 1983-30 September 1985

    SciTech Connect (OSTI)

    Comolli, A.G.; Duddy, J.E.; Koziel, M.L.; MacArthur, J.B.; McLean, J.B.; Smith, T.O.

    1986-02-01

    Hydrocarbon Research, Inc. (HRI) has completed a series of studies for the evaluation of a ''New Technology Concept for Two-Stage Liquefaction of Coal''. The time period of studies covered May 26, 1983 to November 25, 1985, a total of thirty months, with the major effort devoted to Illinois No. 6 bituminous coal and the balance devoted to Wyodak sub-bituminous coal. A two-stage coal liquefaction process, based on two close-coupled catalytic ebullated-bed reactors with the first stage operating at low temperature for maximum hydrogenation, has been developed and demonstrated on Illinois No. 6 and Wyodak coals. This final report presents an executive summary of the program and completes the reporting requirements of Contract No. DE-AC22-83PC60017. A summary of the studies and process demonstrations is presented along with references to the Topical Reports on Illinois No. 6 coal, Wyodak coal, Conceptual Commercial Plant Design and Economics and reports by DOE sponsored support contractors. Experimental details are contained in the referenced reports. The accomplishments of this program and recommendations for a follow-on program are presented. By application of this new hydrogenation concept in this study, distillate yields of greater than 65 W % of M.A.F. Coal or 4.2 barrels per ton of M.A.F. coal were demonstrated on both Illinois No. 6 and Wyodak coals. This was accompanied by a ten-fold reduction in bottoms viscosity and the production of low sulfur environmentally clean fuels. As reported by Conoco, Inc. and Battelle Pacific Northwest Laboratories, a higher level of hydrogenation is evident and the liquids produced are more petroleum-like than coal liquids derived from other liquefaction processes. Upgrading studies on the Wyodak products are being performed by Chevron. 7 figs., 14 tabs.

  8. Process Design and Economics for the Conversion of Algal Biomass to Hydrocarbons: Whole Algae Hydrothermal Liquefaction and Upgrading

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PNNL-23227 Process Design and Economics for the Conversion of Algal Biomass to Hydrocarbons: Whole Algae Hydrothermal Liquefaction and Upgrading S Jones R Davis Y Zhu C Kinchin D Anderson R Hallen D Elliott A Schmidt K Albrecht T Hart M Butcher C Drennan L Snowden-Swan March 2014 NOTICE This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor the Alliance for Sustainable Energy, LLC,

  9. Reassessment of liquefaction potential and estimation of earthquake- induced settlements at Paducah Gaseous Diffusion Plant, Paducah, Kentucky. Final report

    SciTech Connect (OSTI)

    Sykora, D.W.; Yule, D.E.

    1996-04-01

    This report documents a reassessment of liquefaction potential and estimation of earthquake-induced settlements for the U.S. Department of Energy (DOE), Paducah Gaseous Diffusion Plant (PGDP), located southwest of Paducah, KY. The U.S. Army Engineer Waterways Experiment Station (WES) was authorized to conduct this study from FY91 to FY94 by the DOE, Oak Ridge Operations (ORO), Oak Ridge, TN, through Inter- Agency Agreement (IAG) No. DE-AI05-91OR21971. The study was conducted under the Gaseous Diffusion Plant Safety Analysis Report (GDP SAR) Program.

  10. Supply Chain Sustainability Analysis of Indirect Liquefaction of Blended Biomass to Produce High Octane Gasoline

    SciTech Connect (OSTI)

    Cai, Hao; Canter, Christina E.; Dunn, Jennifer B.; Tan, Eric; Biddy, Mary; Talmadge, Michael; Hartley, Damon S.; Snowden-Swan, Lesley

    2015-09-01

    The Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) aims at developing and deploying technologies to transform renewable biomass resources into commercially viable, high-performance biofuels, bioproducts and biopower through public and private partnerships (DOE, 2015). BETO also performs a supply chain sustainability analysis (SCSA). This report describes the SCSA of the production of renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of lignocellulosic biomass. This SCSA was developed for the 2017 design case for feedstock logistics (INL, 2014) and for the 2022 target case for HOG production via IDL (Tan et al., 2015). The design includes advancements that are likely and targeted to be achieved by 2017 for the feedstock logistics and 2022 for the IDL conversion process. The 2017 design case for feedstock logistics demonstrated a delivered feedstock cost of $80 per dry U.S. short ton by the year 2017 (INL, 2014). The 2022 design case for the conversion process, as modeled in Tan et al. (2015), uses the feedstock 2017 design case blend of biomass feedstocks consisting of pulpwood, wood residue, switchgrass, and construction and demolition waste (C&D) with performance properties consistent with a sole woody feedstock type (e.g., pine or poplar). The HOG SCSA case considers the 2017 feedstock design case (the blend) as well as individual feedstock cases separately as alternative scenarios when the feedstock blend ratio varies as a result of a change in feedstock availability. These scenarios could be viewed as bounding SCSA results because of distinctive requirements for energy and chemical inputs for the production and logistics of different components of the blend feedstocks.

  11. Polymer solutions

    DOE Patents [OSTI]

    Krawczyk, Gerhard Erich (Bremen, DE); Miller, Kevin Michael (West Dundee, IL)

    2011-07-26

    There is provided a method of making a polymer solution comprising polymerizing one or more monomer in a solvent, wherein said monomer comprises one or more ethylenically unsaturated monomer that is a multi-functional Michael donor, and wherein said solvent comprises 40% or more by weight, based on the weight of said solvent, one or more multi-functional Michael donor.

  12. Westergaard Solutions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Westergaard Solutions - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  13. Advanced direct liquefaction concepts for PETC generic units phase II. Quarterly technical progress report, April--June 1996

    SciTech Connect (OSTI)

    1996-08-01

    A catalyst screening test (CST) was developed to evaluate the activity of various catalyst precursors for their liquefaction activity in a solvent comprising the solids-free components of a recycle solvent generated at Wilsonville, namely a ROSE SR V-130 deashed resid from period A and V-1074 heavy distillate from period B. Since the deashed resid has an elemental composition very nearly the same distillate from period B. Since the deashed resid has an elemental composition very nearly the same as in the solids-free fraction of the recycle solvent, the reactivity of these two resid and dry coal are nearly the same as in Run 263J, the overall composition should approximate the feed stream used in the Wilsonville pilot plant except for the absence of the solids component. Removing the solids from the reaction mixture should simplify the interpretation of the results since normally a considerable amount or recycled catalyst is contained in this fraction.

  14. Low-severity catalytic two-stage liquefaction process: Illinois coal conceptual commercial plant design and economics

    SciTech Connect (OSTI)

    Abrams, L.M.; Comolli, A.G.; Popper, G.A.; Wang, C.; Wilson, G.

    1988-09-01

    Hydrocarbon Research, Inc. (HRI) is conducting a program for the United States Department of Energy (DOE) to evaluate a Catalytic Two-Stage Liquefaction (CTSL) Process. This program which runs through 1987, is a continuation of an earlier DOE sponsored program (1983--1985) at HRI to develop a new technology concept for CTSL. The earlier program included bench-scale testing of improved operating conditions for the CTSL Process on Illinois No. 6 bituminous coal and Wyoming sub-bituminous coal, and engineering screening studies to identify the economic incentive for CTSL over the single-stage H-Coal/reg sign/ Process for Illinois No. 6 coal. In the current program these engineering screening studies are extended to deep-cleaned Illinois coal and use of heavy recycle. The results from this comparison will be used as a guide for future experiments with respect to selection of coal feedstocks and areas for further process optimization. A preliminary design for CTSL of Illinois deep-cleaned coal was developed based on demonstrated bench-scale performance in Run No. 227-47(I-27), and from HRI's design experience on the Breckinridge Project and H-Coal/reg sign/ Process pilot plant operations at Catlettsburg. Complete conceptual commercial plant designs were developed for a grassroots facility using HRI's Process Planning Model. Product costs were calculated and economic sensitivities analyzed. 14 refs., 11 figs., 49 tabs.

  15. Catalytic Two-Stage Liquefaction (CTSL) process bench studies with bituminous coal. Final report, [October 1, 1988--December 31, 1992

    SciTech Connect (OSTI)

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.; Stalzer, R.H.; Smith, T.O.

    1993-03-01

    Reported herein are the details and results of Laboratory and Bench-Scale experiments using bituminous coal concluded at Hydrocarbon Research, Inc., under DOE contract during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with the application of coal cleaning methods and solids separation methods to the Catalytic Two-Stage Liquefaction (CTSL) Process. Additionally a predispersed catalyst was evaluated in a thermal/catalytic configuration, and an alternative nickel molybdenum catalyst was evaluated for the CTSL process. Three coals were evaluated in this program: Bituminous Illinois No. 6 Burning Star and Sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The tests involving the Illinois coal are reported herein, and the tests involving the Wyoming and New Mexico coals are described in Topical Report No. 1. On the laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO{sub 2} addition and sulfur compound effects are reported in Topical Report No. 3. Other microautoclave tests, such as tests on rejuvenated catalyst, coker liquids, and cleaned coals, are described in the Bench Run sections to which they refer. The microautoclave tests conducted for modelling the CTSL process are described in the CTSL Modelling section of Topical Report No. 3 under this contract.

  16. Bio-liquefaction/solubilization of lignitic humic acids by white-rot fungus (Phanerochaete chrysosporium)

    SciTech Connect (OSTI)

    Elbeyli, I.Y.; Palantoken, A.; Piskin, S.; Peksel, A.; Kuzu, H.

    2006-08-15

    Humic acid samples obtained from lignite were liquefied/solubilized by using white-rot fungus, and chemical characterization of the products was investigated by FTIR and GC-MS techniques. Prior to the microbial treatment, raw lignite was oxidized with hydrogen peroxide and nitric acid separately, and then humic acids were extracted by alkali solution. The prepared humic acid samples were placed on the agar surface of the fungus and liquid products formed by microbial affects were collected. The products were analyzed and the chemical properties were compared. The results show that oxidation agent and oxidation degree affect composition of the liquid products formed by microbial attack.

  17. Dependence of liquefaction behavior on coal characteristics. Part VI. Relationship of liquefaction behavior of a set of high sulfur coals to chemical structural characteristics. Final technical report, March 1981 to February 1984

    SciTech Connect (OSTI)

    Neill, P. H.; Given, P. H.

    1984-09-01

    The initial aim of this research was to use empirical mathematical relationships to formulate a better understanding of the processes involved in the liquefaction of a set of medium rank high sulfur coals. In all, just over 50 structural parameters and yields of product classes were determined. In order to gain a more complete understanding of the empirical relationships between the various properties, a number of relatively complex statistical procedures and tests were applied to the data, mostly selected from the field of multivariate analysis. These can be broken down into two groups. The first group included grouping techniques such as non-linear mapping, hierarchical and tree clustering, and linear discriminant analyses. These techniques were utilized in determining if more than one statistical population was present in the data set; it was concluded that there was not. The second group of techniques included factor analysis and stepwise multivariate linear regressions. Linear discriminant analyses were able to show that five distinct groups of coals were represented in the data set. However only seven of the properties seemed to follow this trend. The chemical property that appeared to follow the trend most closely was the aromaticity, where a series of five parallel straight lines was observed for a plot of f/sub a/ versus carbon content. The factor patterns for each of the product classes indicated that although each of the individual product classes tended to load on factors defined by specific chemical properties, the yields of the broader product classes, such as total conversion to liquids + gases and conversion to asphaltenes, tended to load largely on factors defined by rank. The variance explained and the communalities tended to be relatively low. Evidently important sources of variance have still to be found.

  18. EDS coal liquefaction process development. Phase V. EDS commercial plant study design update. Illinois coal. Volume 1. Main report

    SciTech Connect (OSTI)

    Epperly, W. R.

    1981-03-01

    The objectives of the Study Design Update (SDU) were to identify the technical issues facing a potential commercial-size EDS plant design; to provide a reliable basis for estimating the cost of EDS products; and to furnish research guidance to the EDS Project. The SDU consists of two distinct studies in which different processing schemes are used to produce the hydrogen and fuel gas required by the plant. These studies are referred to as the Base Case and the Market Flexibility Sensitivity Case. In the Base Case, hydrogen is generated by steam reforming of the light hydrocarbon gases produced in the plant. Fuel gas is generated by feeding the bottoms stream from the liquefaction section vacuum pipestill to a FLEXICOKING unit. In the FLEXICOKING unit reactor, the bottoms stream is converted to coke; additional liquid product is also recovered. The coke is converted to low-Btu fuel gas in the FLEXICOKING unit gasifier. In the Market Flexibility Sensitivity (MFS) Case, the bottoms stream from the vacuum pipestill is split, and about half is sent to the FLEXICOKING unit for recovery of additional liquid product and production of fuel gas. The remainder of the bottoms stream is converted to hydrogen in a Partial Oxidation Unit. Hence the MFS Case does not consume light hydrocarbon gases produced and they are available for sale. The study of these two cases has demonstrated the importance of bottoms process selection to the economics and thermal efficiency of an EDS plant. Volume 1 - Main Report has been developed to be a stand-alone document. Both the Base Case and Market Flexibility Sensitivity (MFS) Case are covered. This volume includes an overview and detailed case summaries. It also covers economics, product recovery factors, material and energy balances, cost estimates and enviromental considerations.

  19. Techno-Economic Analysis of Liquid Fuel Production from Woody Biomass via Hydrothermal Liquefaction (HTL) and Upgrading

    SciTech Connect (OSTI)

    Zhu, Yunhua; Biddy, Mary J.; Jones, Susanne B.; Elliott, Douglas C.; Schmidt, Andrew J.

    2014-09-15

    A series of experimental work was conducted to convert woody biomass to gasoline and diesel range products via hydrothermal liquefaction (HTL) and catalytic hydroprocessing. Based on the best available test data, a techno-economic analysis (TEA) was developed for a large scale woody biomass based HTL and upgrading system to evaluate the feasibility of this technology. In this system, 2000 dry metric ton per day woody biomass was assumed to be converted to bio-oil in hot compressed water and the bio-oil was hydrotreated and/or hydrocracked to produce gasoline and diesel range liquid fuel. Two cases were evaluated: a stage-of-technology (SOT) case based on the tests results, and a goal case considering potential improvements based on the SOT case. Process simulation models were developed and cost analysis was implemented based on the performance results. The major performance results included final products and co-products yields, raw materials consumption, carbon efficiency, and energy efficiency. The overall efficiency (higher heating value basis) was 52% for the SOT case and 66% for the goal case. The production cost, with a 10% internal rate of return and 2007 constant dollars, was estimated to be $1.29 /L for the SOT case and $0.74 /L for the goal case. The cost impacts of major improvements for moving from the SOT to the goal case were evaluated and the assumption of reducing the organics loss to the water phase lead to the biggest reduction in the production cost. Sensitivity analysis indicated that the final products yields had the largest impact on the production cost compared to other parameters. Plant size analysis demonstrated that the process was economically attractive if the woody biomass feed rate was over 1,500 dry tonne/day, the production cost was competitive with the then current petroleum-based gasoline price.

  20. Review and Assessment of Commercial Vendors/Options for Feeding and Pumping Biomass Slurries for Hydrothermal Liquefaction

    SciTech Connect (OSTI)

    Berglin, Eric J.; Enderlin, Carl W.; Schmidt, Andrew J.

    2012-11-01

    The National Advanced Biofuels Consortium is working to develop improved methods for producing high-value hydrocarbon fuels. The development of one such method, the hydrothermal liquefaction (HTL) process, is being led by the Pacific Northwest National Laboratory (PNNL). The HTL process uses a wet biomass slurry at elevated temperatures (i.e., 300 to 360C [570 to 680F]) and pressures above the vapor pressure of water (i.e., 15 to 20 MPa [2200 to 3000 psi] at these temperatures) to facilitate a condensed-phase reaction medium. The process has been successfully tested at bench-scale and development and testing at a larger scale is required to prove the viability of the process at production levels. Near-term development plans include a pilot-scale system on the order of 0.5 to 40 gpm, followed by a larger production-scale system on the order of 2000 dry metric tons per day (DMTPD). A significant challenge to the scale-up of the HTL process is feeding a highly viscous fibrous biomass wood/corn stover feedstock into a pump system that provides the required 3000 psi of pressure for downstream processing. In October 2011, PNNL began investigating commercial feed and pumping options that would meet these HTL process requirements. Initial efforts focused on generating a HTL feed and pump specification and then providing the specification to prospective vendors to determine the suitability of their pumps for the pilot-scale and production-scale plants. Six vendors were identified that could provide viable equipment to meet HTL feed and/or pump needs. Those six vendors provided options consisting three types of positive displacement pumps (i.e., diaphragm, piston, and lobe pumps). Vendors provided capabilities and equipment related to HTL application. This information was collected, assessed, and summarized and is provided as appendices to this report.

  1. Randa Energy Solutions LLC R A Energy Solutions | Open Energy...

    Open Energy Info (EERE)

    LLC R A Energy Solutions Jump to: navigation, search Name: Randa Energy Solutions, LLC (R&A Energy Solutions) Place: North Ridgeville, Ohio Zip: 44039 Product: String...

  2. High resolution FT-ICR mass spectral analysis of bio-oil and residual water soluble organics produced by hydrothermal liquefaction of the marine microalga Nannochloropsis salina

    SciTech Connect (OSTI)

    Sudasinghe, Nilusha; Dungan, Barry; Lammers, Peter; Albrecht, Karl O.; Elliott, Douglas C.; Hallen, Richard T.; Schaub, Tanner

    2014-03-01

    We report a detailed compositional characterization of a bio-crude oil and aqueous by-product from hydrothermal liquefaction of Nannochloropsis salina by direct infusion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) in both positive- and negative-ionization modes. The FT-ICR MS instrumentation approach facilitates direct assignment of elemental composition to >7000 resolved mass spectral peaks and three-dimensional mass spectral images for individual heteroatom classes highlight compositional diversity of the two samples and provide a baseline description of these materials. Aromatic nitrogen compounds and free fatty acids are predominant species observed in both the bio-oil and aqueous fraction. Residual organic compounds present in the aqueous fraction show distributions that are slightly lower in both molecular ring and/or double bond value and carbon number relative to those found in the bio-oil, albeit with a high degree of commonality between the two compositions.

  3. Close-coupled Catalytic Two-Stage Liquefaction (CTSL{trademark}) process bench studies. Final report, [October 1, 1988--July 31, 1993

    SciTech Connect (OSTI)

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.; Popper, G.A.; Stalzer, R.H.; Smith, T.O.

    1993-06-01

    This is the final report of a four year and ten month contract starting on October 1, 1988 to July 31, 1993 with the US Department of Energy to study and improve Close-Coupled Catalytic Two-Stage Direct Liquefaction of coal by producing high yields of distillate with improved quality at lower capital and production costs in comparison to existing technologies. Laboratory, Bench and PDU scale studies on sub-bituminous and bituminous coals are summarized and referenced in this volume. Details are presented in the three topical reports of this contract; CTSL Process Bench Studies and PDU Scale-Up with Sub-Bituminous Coal-DE-88818-TOP-1, CTSL Process Bench Studies with Bituminous Coal-DE-88818-TOP-2, and CTSL Process Laboratory Scale Studies, Modelling and Technical Assessment-DE-88818-TOP-3. Results are summarized on experiments and studies covering several process configurations, cleaned coals, solid separation methods, additives and catalysts both dispersed and supported. Laboratory microautoclave scale experiments, economic analysis and modelling studies are also included along with the PDU-Scale-Up of the CTSL processing of sub-bituminous Black Thunder Mine Wyoming coal. During this DOE/HRI effort, high distillate yields were maintained at higher throughput rates while quality was markedly improved using on-line hydrotreating and cleaned coals. Solid separations options of filtration and delayed coking were evaluated on a Bench-Scale with filtration successfully scaled to a PDU demonstration. Directions for future direct coal liquefaction related work are outlined herein based on the results from this and previous programs.

  4. Solution deposition assembly

    DOE Patents [OSTI]

    Roussillon, Yann; Scholz, Jeremy H; Shelton, Addison; Green, Geoff T; Utthachoo, Piyaphant

    2014-01-21

    Methods and devices are provided for improved deposition systems. In one embodiment of the present invention, a deposition system is provided for use with a solution and a substrate. The system comprises of a solution deposition apparatus; at least one heating chamber, at least one assembly for holding a solution over the substrate; and a substrate curling apparatus for curling at least one edge of the substrate to define a zone capable of containing a volume of the solution over the substrate. In another embodiment of the present invention, a deposition system for use with a substrate, the system comprising a solution deposition apparatus; at heating chamber; and at least assembly for holding solution over the substrate to allow for a depth of at least about 0.5 microns to 10 mm.

  5. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  6. TVA- Solar Solutions Initiative

    Broader source: Energy.gov [DOE]

    Solar Solutions Initiative (SSI) is a pilot program that offers additional financial incentives for Solar PV systems participating in the Renewable Standard Offer program. Applications for new...

  7. Coal liquefaction model compounds

    SciTech Connect (OSTI)

    Gajewski, J.J.; Gilbert, K.E.

    1992-01-01

    This progress report is divided into sections dealing with tetralin pyrolysis, chroman pyrolysis, solvent effects on reactions, pi conjugated biradical, and molecular mechanics of organometallic systems. Proposals are given as well as current progress.

  8. Coal liquefaction process

    DOE Patents [OSTI]

    Skinner, Ronald W. (Allentown, PA); Tao, John C. (Perkiomenville, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01

    This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

  9. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, D.; Sunder, S.

    1986-12-02

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

  10. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Sunder, Swaminathan (Allentown, PA)

    1986-01-01

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

  11. Liquefaction and Pipeline Costs

    Broader source: Energy.gov [DOE]

    Presentation by Bruce Kelly of Nexant at the Joint Meeting on Hydrogen Delivery Modeling and Analysis, May 8-9, 2007

  12. Solvent wash solution

    DOE Patents [OSTI]

    Neace, James C. (Blackville, SC)

    1986-01-01

    Process for removing diluent degradation products from a solvent extraction solution, which has been used to recover uranium and plutonium from spent nuclear fuel. A wash solution and the solvent extraction solution are combined. The wash solution contains (a) water and (b) up to about, and including, 50 volume percent of at least one-polar water-miscible organic solvent based on the total volume of the water and the highly-polar organic solvent. The wash solution also preferably contains at least one inorganic salt. The diluent degradation products dissolve in the highly-polar organic solvent and the organic solvent extraction solvent do not dissolve in the highly-polar organic solvent. The highly-polar organic solvent and the extraction solvent are separated.

  13. Solvent wash solution

    DOE Patents [OSTI]

    Neace, J.C.

    1984-03-13

    A process is claimed for removing diluent degradation products from a solvent extraction solution, which has been used to recover uranium and plutonium from spent nuclear fuel. A wash solution and the solvent extraction solution are combined. The wash solution contains (a) water and (b) up to about, and including, 50 vol % of at least one-polar water-miscible organic solvent based on the total volume of the water and the highly-polar organic solvent. The wash solution also preferably contains at least one inorganic salt. The diluent degradation products dissolve in the highly-polar organic solvent and the organic solvent extraction solvent do not dissolve in the highly-polar organic solvent. The highly-polar organic solvent and the extraction solvent are separated.

  14. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, Richard L. (Clinton, TN)

    1997-01-01

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  15. Dispersant solutions for dispersing hydrocarbons

    DOE Patents [OSTI]

    Tyndall, R.L.

    1997-03-11

    A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

  16. Solution mass measurement

    SciTech Connect (OSTI)

    Ford, W.; Marshall, R.S.; Osborn, L.C.; Picard, R.; Thomas, C.C. Jr.

    1982-07-01

    This report describes the efforts to develop and demonstrate a solution mass measurement system for use at the Los Alamos Plutonium Facility. Because of inaccuracy of load cell measurements, our major effort was directed towards the pneumatic bubbler tube. The differential pressure between the air inlet to the bubbler tube and the glovebox interior is measured and is proportional to the solution mass in the tank. An inexpensive, reliable pressure transducer system for measuring solution mass in vertical, cylindrical tanks was developed, tested, and evaluated in a laboratory test bed. The system can withstand the over- and underpressures resulting from solution transfer operations and can prevent solution backup into the measurement pressure transducer during transfers. Drifts, noise, quantization error, and other effects limit the accuracy to 30 g. A transportable calibration system using a precision machined tank, pneumatic bubbler tubes, and a Ruska DDR 6000 electromanometer was designed, fabricated, tested, and evaluated. Resolution of the system is +-3.5 g out of 50 kg. The calibration error is 5 g, using room-temperature water as the calibrating fluid. Future efforts will be directed towards in-plant test and evaluation of the tank measurement systems. 16 figures, 3 tables.

  17. Fissile solution measurement apparatus

    DOE Patents [OSTI]

    Crane, T.W.; Collinsworth, P.R.

    1984-06-11

    An apparatus for determining the content of a fissile material within a solution by detecting delayed fission neutrons emitted by the fissile material after it is temporarily irradiated by a neutron source. The apparatus comprises a container holding the solution and having a portion defining a neutron source cavity centrally disposed within the container. The neutron source cavity temporarily receives the neutron source. The container has portions defining a plurality of neutron detector ports that form an annular pattern and surround the neutron source cavity. A plurality of neutron detectors count delayed fission neutrons emitted by the fissile material. Each neutron detector is located in a separate one of the neutron detector ports.

  18. Studies in coal liquefaction with application to the SRC and related processes. Quarterly report, August 1981-October 1981. [Using model compounds

    SciTech Connect (OSTI)

    Tarrer, A. R.; Guin, J. A.; Curtis, C. W.

    1981-01-01

    Model compound reactions were studied to evaluate the effects of mass transfer, solvent type, solvent blending, hydrogen partial pressure, temperature, reactant concentration, additive loading and its preparation, etc. Naphthalene hydrogenation and benzothiophene hydrodesulfurization were investigated under the conditions comparable to commercial coal liquefaction and related processes. Both of these reaction systems were observed to be surface reaction controlled under the reaction conditions used in this work. Certain aromatic compounds were observed to cause a reduction in the reaction rates of naphthalene and benzothiophene. Single stage coal dissolution was investigated using tetralin as a hydrogen donor solvent and a commercial cobalt-molybdate catalyst. A spinning basket system was developed to allow injection of the catalyst at a desired time in the reaction cycle. This catalyst injection technique proved to be reliable for the exploratory work done here. The degree of catalyst deactivation was rated by comparing the activities of the spent catalyst for model compound (naphthalene and cumene) reactivities relative to those of the fresh catalyst. No substantial reduction in deactivation was observed to result with delayed contacting of the catalyst with the coal-tetralin reaction mixture. The effect of reaction temperature on the initial rate of catalyst deactivation was also studied.

  19. Building Solutions | Open Energy Information

    Open Energy Info (EERE)

    Building Solutions Jump to: navigation, search Name: Building Solutions Place: California Sector: Efficiency Product: California-based energy efficiency contractor and consultancy....

  20. Soy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: Soy Solutions Place: Milford, Iowa Zip: 51351 Product: Manufacturer and distributor of 100 percent Soy-Based Biodiesel References: Soy...

  1. Enspiria Solutions | Open Energy Information

    Open Energy Info (EERE)

    Page Edit with form History Enspiria Solutions Jump to: navigation, search Name: Enspiria Solutions Place: Greenwood Village, Colorado Sector: Services Product: Greenwood...

  2. Powerit Solutions | Open Energy Information

    Open Energy Info (EERE)

    Powerit Solutions Jump to: navigation, search Name: Powerit Solutions Address: 568 First Ave South Place: Seattle, Washington Zip: 98104 Region: Pacific Northwest Area Sector:...

  3. Building America Solution Center Webinar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building America Solution Center Webinar July 22, 2015 Put New Tools and Content on the Building America Solution Center to Work for You CHRISSI ANTONOPOULOS Pacific NW National ...

  4. Sol Solution | Open Energy Information

    Open Energy Info (EERE)

    Solution Jump to: navigation, search Name: Sol Solution Place: Los Gatos, California Zip: 95030 Region: Bay Area Sector: Solar Product: Rainbow Concentrator, Current matching...

  5. SCADA Engineering Solutions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Solutions - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  6. Building America Solution Center

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solution Center 2014 Building Technologies Office Peer Review Michael Baechler, michael.baechler@pnnl.gov Pacific Northwest National Laboratory Project Summary Timeline: Start date: October 2011 Planned end date: Ongoing Key Milestones 1. Launch supporting Energy Star, January 2013 2. Zero Energy Ready Home launch, June 2014 3. Existing home launch, winter 2015 Budget: Total DOE $ to date: $2,604,000 Total future DOE $: $4,500,000 (2 additional years development - 3 years of app and content

  7. Conceptual process design and economics for the production of high-octane gasoline blendstock via indirect liquefaction of biomass through methanol/dimethyl ether intermediates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Snowden-Swan, Lesley J.; Humbird, David; Schaidle, Joshua; Biddy, Mary

    2015-10-28

    This paper describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas via indirect gasification, gas clean-up via reforming of tars and other hydrocarbons, catalytic conversion of syngas to methanol, methanol dehydration to dimethyl ether (DME), and the homologation of DME over a zeolite catalyst to high-octane gasoline-range hydrocarbon products. The current process configuration has similarities to conventional methanol-to-gasoline (MTG) technologies, but there are key distinctions, specifically regarding the product slate, catalysts, and reactor conditions. A techno-economicmore » analysis is performed to investigate the production of high-octane gasoline blendstock. The design features a processing daily capacity of 2000 tonnes (2205 short tons) of dry biomass. The process yields 271 liters of liquid fuel per dry tonne of biomass (65 gal/dry ton), for an annual fuel production rate of 178 million liters (47 MM gal) at 90% on-stream time. The estimated total capital investment for an nth-plant is $438 million. The resulting minimum fuel selling price (MFSP) is $0.86 per liter or $3.25 per gallon in 2011 US dollars. A rigorous sensitivity analysis captures uncertainties in costs and plant performance. Sustainability metrics for the conversion process are quantified and assessed. The potential premium value of the high-octane gasoline blendstock is examined and found to be at least as competitive as fossil-derived blendstocks. A simple blending strategy is proposed to demonstrate the potential for blending the biomass-derived blendstock with petroleum-derived intermediates. Published 2015. This article is a U.S. Government work and is in the public domain in the USA. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd.« less

  8. Hydrothermal Liquefaction Oil and Hydrotreated Product from Pine Feedstock Characterized by Heteronuclear Two-Dimensional NMR Spectroscopy and FT-ICR Mass Spectrometry

    SciTech Connect (OSTI)

    Sudasinghe, Nilusha; Cort, John R.; Hallen, Richard T.; Olarte, Mariefel V.; Schmidt, Andrew J.; Schaub, Tanner

    2014-12-01

    Hydrothermal liquefaction (HTL) crude oil and hydrotreated product from pine tree farm waste (forest product residual, FPR) have been analyzed by direct infusion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) in both positive- and negative-ionization modes and high-resolution twodimensional heteronuclear 1H-13C NMR spectroscopy. FT-ICR MS resolves thousands of compounds in complex oils and provides unparalleled compositional details for individual molecules for identification of compound class (heteroatom content), type (number of rings plus double bonds to carbon or double bond equivalents (DBE) and carbon number (degree of alkylation). Heteronuclear 1H-13C NMR spectroscopy provides one-bond and multiple-bond correlations between pairs of 1H and 13C chemical shifts that are characteristic of different organic functional groups. Taken together this information provides a picture of the chemical composition of these oils. Pyrolysis crude oil product from pine wood was characterized for comparison. Generally, pyrolysis oil is comprised of a more diverse distribution of heteroatom classes with higher oxygen number relative to HTL oil as shown by both positive- and negative-ion ESI FT-ICR MS. A total of 300 N1, 594 O1 and 267 O2 compounds were observed as products of hydrotreatment. The relative abundance of N1O1, N1O2, N1O3, N2, N2O1, N2O2 and O3 compounds are reduced to different degrees after hydrotreatment and other higher heteroatom containing species (O4-O10, N1O4, N1O5 and N2O3) are completely removed by hydrotreatment.

  9. Catalytic Two-Stage Liquefaction (CTSL{trademark}) process bench studies and PDU scale-up with sub-bituminous coal. Final report

    SciTech Connect (OSTI)

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.T.; Stalzer, R.H.; Smith, T.O.

    1993-03-01

    Reported are the details and results of Laboratory and Bench-Scale experiments using sub-bituminous coal conducted at Hydrocarbon Research, Inc., under DOE Contract No. DE-AC22-88PC88818 during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with testing of the baseline Catalytic Two-Stage Liquefaction (CTSL{trademark}) process with comparisons with other two stage process configurations, catalyst evaluations and unit operations such as solid separation, pretreatments, on-line hydrotreating, and an examination of new concepts. In the overall program, three coals were evaluated, bituminous Illinois No. 6, Burning Star and sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The runs (experiments) concern process variables, variable reactor volumes, catalysts (both supported, dispersed and rejuvenated), coal cleaned by agglomeration, hot slurry treatments, reactor sequence, on-line hydrotreating, dispersed catalyst with pretreatment reactors and CO{sub 2}/coal effects. The tests involving the Wyoming and New Mexico Coals are reported herein, and the tests involving the Illinois coal are described in Topical Report No. 2. On a laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO{sub 2} addition and sulfur compound effects were conducted and reported in Topical Report No. 3. Other microautoclave tests are described in the Bench Run sections to which they refer such as: rejuvenated catalyst, coker liquids and cleaned coals. The microautoclave tests conducted for modelling the CTSL{trademark} process are described in the CTSL{trademark} Modelling section of Topical Report No. 3 under this contract.

  10. A National-Scale Comparison of Resource and Nutrient Demands for Algae-Based Biofuel Production by Lipid Extraction and Hydrothermal Liquefaction

    SciTech Connect (OSTI)

    Venteris, Erik R.; Skaggs, Richard; Wigmosta, Mark S.; Coleman, Andre M.

    2014-03-01

    Algae’s high productivity provides potential resource advantages over other fuel crops. However, demand for land, water, and nutrients must be minimized to avoid impacts on food production. We apply our national-scale, open-pond, growth and resource models to assess several biomass to fuel technological pathways based on Chlorella. We compare resource demands between hydrothermal liquefaction (HTL) and lipid extraction (LE) to meet 1.89E+10 and 7.95E+10 L yr-1 biofuel targets. We estimate nutrient demands where post-fuel biomass is consumed as co-products and recycling by anaerobic digestion (AD) or catalytic hydrothermal gasification (CHG). Sites are selected through prioritization based on fuel value relative to a set of site-specific resource costs. The highest priority sites are located along the Gulf of Mexico coast, but potential sites exist nationwide. We find that HTL reduces land and freshwater consumption by up to 46% and saline groundwater by around 70%. Without recycling, nitrogen (N) and phosphorous (P) demand is reduced 33%, but is large relative to current U.S. agricultural consumption. The most nutrient-efficient pathways are LE+CHG for N and HTL+CHG for P (by 42%). Resource gains for HTL+CHG are offset by a 344% increase in N consumption relative to LE+CHG (with potential for further recycling). Nutrient recycling is essential to effective use of alternative nutrient sources. Modeling of utilization availability and costs remains, but we find that for HTL+CHG at the 7.95E+10 L yr-1 production target, municipal sources can offset 17% of N and 40% of P demand and animal manures can generally meet demands.

  11. Conceptual process design and economics for the production of high-octane gasoline blendstock via indirect liquefaction of biomass through methanol/dimethyl ether intermediates

    SciTech Connect (OSTI)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Snowden-Swan, Lesley J.; Humbird, David; Schaidle, Joshua; Biddy, Mary

    2015-10-28

    This paper describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas via indirect gasification, gas clean-up via reforming of tars and other hydrocarbons, catalytic conversion of syngas to methanol, methanol dehydration to dimethyl ether (DME), and the homologation of DME over a zeolite catalyst to high-octane gasoline-range hydrocarbon products. The current process configuration has similarities to conventional methanol-to-gasoline (MTG) technologies, but there are key distinctions, specifically regarding the product slate, catalysts, and reactor conditions. A techno-economic analysis is performed to investigate the production of high-octane gasoline blendstock. The design features a processing daily capacity of 2000 tonnes (2205 short tons) of dry biomass. The process yields 271 liters of liquid fuel per dry tonne of biomass (65 gal/dry ton), for an annual fuel production rate of 178 million liters (47 MM gal) at 90% on-stream time. The estimated total capital investment for an nth-plant is $438 million. The resulting minimum fuel selling price (MFSP) is $0.86 per liter or $3.25 per gallon in 2011 US dollars. A rigorous sensitivity analysis captures uncertainties in costs and plant performance. Sustainability metrics for the conversion process are quantified and assessed. The potential premium value of the high-octane gasoline blendstock is examined and found to be at least as competitive as fossil-derived blendstocks. A simple blending strategy is proposed to demonstrate the potential for blending the biomass-derived blendstock with petroleum-derived intermediates. Published 2015. This article is a U.S. Government work and is in the public domain in the USA. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd.

  12. Dirac solutions for quaternionic potentials

    SciTech Connect (OSTI)

    De Leo, Stefano Giardino, Sergio

    2014-02-15

    The Dirac equation is solved for quaternionic potentials, i?V{sub 0} + j?W{sub 0} (V{sub 0}?R , W{sub 0}?C). The study shows two different solutions. The first one contains particle and anti-particle solutions and leads to the diffusion, tunneling, and Klein energy zones. The standard solution is recovered taking the complex limit of this solution. The second solution, which does not have a complex counterpart, can be seen as a V{sub 0}-antiparticle or |W{sub 0}|-particle solution.

  13. Sandia Energy - SCADA Engineering Solutions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Solutions Home Stationary Power Safety, Security & Resilience of Energy Infrastructure Grid Modernization Cyber Security for Electric Infrastructure National...

  14. Suntech Energy Solutions Formerly EI Solutions | Open Energy...

    Open Energy Info (EERE)

    Place: Pasadena, California Zip: 91103 Sector: Solar Product: A California-based solar power systems integrator and installer. References: Suntech Energy Solutions...

  15. Better Buildings Residential Program Solution Center Demonstration |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Residential Program Solution Center Demonstration Better Buildings Residential Program Solution Center Demonstration Better Buildings Residential Program Solution Center Demonstration from the U.S. Department of Energy. PDF icon Solution Center Demo More Documents & Publications Building Science Solutions … Faster and Better Presentation: Better Buildings Residential Program Solution Center Presentation: Better Buildings Residential Program Solution Center

  16. Financing Solutions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing Solutions Financing Solutions Transitioning to a clean energy economy requires innovative financing solutions that enable state, local, and tribal governments to invest in clean energy technologies. However, the clean energy puzzle can be daunting, especially when it comes to financing. With that in mind this website aims to provide an overview of financing as it pertains to state, local, and tribal governments who are designing and implementing clean energy financing programs. Learn

  17. Extraordinary vacuum black string solutions

    SciTech Connect (OSTI)

    Kim, Hyeong-Chan; Lee, Jungjai

    2008-01-15

    In addition to the boosted static solution there are two other classes of stationary stringlike solutions of the vacuum Einstein equation in (4+1) dimensions. Each class is characterized by three parameters of mass, tension, and momentum flow along the fifth coordinate. We analyze the metric properties of one of the two classes, which was previously assumed to be naked singular, and show that the solution spectrum contains black string and wormhole in addition to the known naked singularity as the momentum flow to mass ratio increases. Interestingly, there does not exist new zero momentum solution in these cases.

  18. Biofuel Solutions | Open Energy Information

    Open Energy Info (EERE)

    developer, which had been developing one plant in Fairmont, Minnesota and another in Wood River, Biofuel Energy LLC took over plant development of Biofuel Solutions' projects in...

  19. MPower Solutions | Open Energy Information

    Open Energy Info (EERE)

    Dundee,, United Kingdom Zip: DD2 4UH Product: MPower Solutions is one Europe's largest battery manufacturers supplying over 500,000 batteries every month. MPower provides optimised...

  20. Employment Solutions Division (HC-13)

    Broader source: Energy.gov [DOE]

    This division develops and implements innovative HCM business solutions relating to corporate recruiting, organizational and workforce development, workforce and succession planning, talent...

  1. SBY Solutions | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: SBY Solutions Place: Israel Zip: 42836 Sector: Solar Product: Solar panel installer, mainly focusing on rooftops. References: SBY...

  2. Extracting alcohols from aqueous solutions

    DOE Patents [OSTI]

    Compere, Alicia L.; Googin, John M.; Griffith, William L.

    1984-01-01

    Hydrocarbon and surfactants are contacted with a solution of alcohol and water to extract the alcohol into the hydrocarbon-surfactant mixture.

  3. DEVELOPMENT Solutions | Open Energy Information

    Open Energy Info (EERE)

    Product: DEVELOPMENT Solutions (DS) supports investors to realise projects with sustainable applications, including in the areas of environment, energy efficiency, water...

  4. Cleantech Solutions | Open Energy Information

    Open Energy Info (EERE)

    New York Zip: 10023 Region: Northeast - NY NJ CT PA Area Sector: Efficiency Product: Energy efficiency solutions and consumption monitoring systems for buildings Website:...

  5. RWE Solutions | Open Energy Information

    Open Energy Info (EERE)

    RWE Solutions Place: Neu-Isenburg, Germany Zip: 63263 Sector: Solar Product: Germany-based, subsidiary of RWE AG plans, builds and manages energy infrastructure for utilities...

  6. High conductivity electrolyte solutions and rechargeable cells incorporating such solutions

    DOE Patents [OSTI]

    Angell, Charles Austen (Mesa, AZ); Zhang, Sheng-Shui (Tucson, AZ); Xu, Kang (Tempe, AZ)

    1998-01-01

    This invention relates generally to electrolyte solvents for use in liquid or rubbery polymer electrolyte solutions as are used, for example, in electrochemical devices. More specifically, this invention relates to sulfonyl/phospho-compound electrolyte solvents and sulfonyl/phospho-compound electrolyte solutions incorporating such solvents.

  7. High conductivity electrolyte solutions and rechargeable cells incorporating such solutions

    DOE Patents [OSTI]

    Angell, C.A.; Zhang, S.S.; Xu, K.

    1998-10-20

    This invention relates generally to electrolyte solvents for use in liquid or rubbery polymer electrolyte solutions as are used, for example, in electrochemical devices. More specifically, this invention relates to sulfonyl/phospho-compound electrolyte solvents and sulfonyl/phospho-compound electrolyte solutions incorporating such solvents. 9 figs.

  8. Dow Building Solutions | Open Energy Information

    Open Energy Info (EERE)

    Dow Building Solutions Jump to: navigation, search Name: Dow Building Solutions Place: Midland, MI Website: www.dowbuildingsolutions.com References: Dow Building Solutions1...

  9. Future Energy Solutions | Open Energy Information

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    Solutions Jump to: navigation, search Name: Future Energy Solutions Place: Didcot, United Kingdom Zip: OX11 0QR Product: Future Energy Solutions is a sustainable energy...

  10. Carbon Solutions Group | Open Energy Information

    Open Energy Info (EERE)

    Solutions Group Jump to: navigation, search Name: Carbon Solutions Group Place: Chicago, Illinois Zip: 60601 Sector: Carbon Product: Carbon Solutions Group collaborates with...

  11. Solar Choice Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Choice Solutions Inc Jump to: navigation, search Name: Solar Choice Solutions Inc. Place: Calabasas, California Zip: 91302 Sector: Solar Product: Solar Choice Solutions Inc. is an...

  12. Mechanical Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Mechanical Solutions Inc Jump to: navigation, search Name: Mechanical Solutions Inc Place: New York Product: New York-based contractor. References: Mechanical Solutions Inc1 This...

  13. Chevron Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Chevron Energy Solutions Jump to: navigation, search Logo: Chevron Energy Solutions Name: Chevron Energy Solutions Address: 345 California Street, 18th Floor Place: San Francisco,...

  14. Wind Park Solutions Arcadia | Open Energy Information

    Open Energy Info (EERE)

    Park Solutions Arcadia Jump to: navigation, search Name: Wind Park Solutions Arcadia Place: Big Sandy, Montana Sector: Wind energy Product: JV between Wind Park Solutions America...

  15. Institute for Environmental Solutions | Open Energy Information

    Open Energy Info (EERE)

    Environmental Solutions Jump to: navigation, search Logo: Institute for Environmental Solutions Name: Institute for Environmental Solutions Address: 761 Newport St. Place: Denver,...

  16. ECO Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    ECO Solutions LLC Jump to: navigation, search Name: ECO Solutions, LLC Place: Chatsworth, Georgia Zip: 30705 Product: ECO Solutions operates a biodiesel plant in Georgia with a...

  17. AFV Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Solutions Inc Place: Mesa, Arizona Zip: 85210 Product: AFV Solutions is a manufacturer of electric-hybrid buses and energy conversion systems for cars. References: AFV Solutions...

  18. Energy Capital Solutions | Open Energy Information

    Open Energy Info (EERE)

    Capital Solutions Jump to: navigation, search Logo: Energy Capital Solutions Name: Energy Capital Solutions Address: 2651 North Harwood Street, Suite 410 Place: Dallas, Texas Zip:...

  19. Biomass Indirect Liquefaction Workshop Presentation

    Broader source: Energy.gov [DOE]

    Wood to green gasoline using Carbona gasification and Topsoe TIGAS processes - DOE Project DE-EE0002874

  20. Biomass Indirect Liquefaction Workshop Presentation

    Broader source: Energy.gov [DOE]

    Integrated Biorefinery for the Direct Production of Synthetic Fuel from Waste Carbonaceous Feedstocks

  1. Catalysts for coal liquefaction processes

    DOE Patents [OSTI]

    Garg, D.

    1986-10-14

    Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

  2. Catalysts for coal liquefaction processes

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA)

    1986-01-01

    Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

  3. Sunflower Solutions | Open Energy Information

    Open Energy Info (EERE)

    tracking systems maker for PV modules targeted at installations in the developing world. References: Sunflower Solutions1 This article is a stub. You can help OpenEI by...

  4. Cold Climate Building Enclosure Solutions

    Office of Scientific and Technical Information (OSTI)

    Enclosure Solutions Jan Kosny, Ali Fallahi, and Nitin Shukla Fraunhofer CSE January 2013 NOTICE This report was prepared as an account of work sponsored by an agency of the...

  5. Comprehensive Water-Efficiency Solutions

    SciTech Connect (OSTI)

    McMordie Stoughton, Kate

    2015-07-15

    Energy performance contracts can be an effective way to integrate comprehensive water-efficient technologies and solutions into energy efficiency projects. Current practices often miss key opportunities to incorporate a full suite of water measures primarily because a comprehensive approach is not taken in the assessment. This article provides information on how to develop a comprehensive water project that leads to innovative solutions and potential for large water reduction.

  6. Cosmological solution moduli of bigravity

    SciTech Connect (OSTI)

    Yılmaz, Nejat Tevfik

    2015-09-29

    We construct the complete set of metric-configuration solutions of the ghost-free massive bigravity for the scenario in which the g−metric is the Friedmann-Lemaitre-Robertson-Walker (FLRW) one, and the interaction Lagrangian between the two metrics contributes an effective ideal fluid energy-momentum tensor to the g-metric equations. This set corresponds to the exact background cosmological solution space of the theory.

  7. Cesium recovery from aqueous solutions

    DOE Patents [OSTI]

    Goodhall, C. A.

    1960-09-13

    A process for recovering cesium from aqueous solutions is given in which precipitation on zinc ferricyanide is used. The precipitation is preferably carried out in solutions containing at least 0.0004M zinc ferricyanide, an acidity ranging from 0.2N mineral acid to 0.61N acid deficiency, and 1 to 2.5M aluminum nitrate. (D.L.C.)

  8. New Solutions Require New Thinking

    Office of Environmental Management (EM)

    Solutions Require New Thinking America's demand for power threatens to overburden an already congested electric system. The U.S. Department of Energy is addressing these energy challenges with innovative solutions to energy generation. Its Renewable and Distributed Systems Integration (RDSI) Program is helping to alleviate congestion, reduce greenhouse gas emissions, and improve reliability by investigating answers such as * Microgrid technologies * Distributed generation * Two-way communication

  9. Electrodialysis operation with buffer solution

    DOE Patents [OSTI]

    Hryn, John N. (Naperville, IL); Daniels, Edward J. (Orland Park, IL); Krumdick, Greg K. (Crete, IL)

    2009-12-15

    A new method for improving the efficiency of electrodialysis (ED) cells and stacks, in particular those used in chemical synthesis. The process entails adding a buffer solution to the stack for subsequent depletion in the stack during electrolysis. The buffer solution is regenerated continuously after depletion. This buffer process serves to control the hydrogen ion or hydroxide ion concentration so as to protect the active sites of electrodialysis membranes. The process enables electrodialysis processing options for products that are sensitive to pH changes.

  10. TrueWind Solutions | Open Energy Information

    Open Energy Info (EERE)

    TrueWind Solutions Jump to: navigation, search Name: TrueWind Solutions Place: Albany, NY Website: www.awstruepower.com References: TrueWind Solutions1 Information About...

  11. PowerIt Solutions | Open Energy Information

    Open Energy Info (EERE)

    Place: Seattle, Washington Zip: 98104 Product: Powerit Solutions provides energy demand response and demand control solutions for industrial and commercial applications....

  12. Blueprint for Sustainability - Sustainable Solutions for Every...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blueprint for Sustainability - Sustainable Solutions for Every Consumer Blueprint for Sustainability - Sustainable Solutions for Every Consumer Highlights of Ford's near, mid, and ...

  13. Reaction Engineering Solutions Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ltd Jump to: navigation, search Name: Reaction Engineering Solutions Ltd. Place: Cambridge, United Kingdom Zip: CB4 3QG Product: PUk-based, provider of computational solutions...

  14. Bio Solutions Manufacturing Inc | Open Energy Information

    Open Energy Info (EERE)

    Solutions Manufacturing Inc Jump to: navigation, search Name: Bio Solutions Manufacturing Inc Place: Las Vegas, Nevada Zip: 89103 Product: Waste-to-energy bioremediation developer....

  15. First Carbon Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: First Carbon Solutions Place: Bethesda, Maryland Product: To be completed... Coordinates: 40.020185, -81.073819 Show Map Loading...

  16. AG Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: AG Solutions Inc. Place: Gladstone, Michigan Product: 10Mgpy biodiesel producer in Gladstone, Michigan. References: AG Solutions Inc.1 This article is a...

  17. Biodiesel Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Solutions Inc Jump to: navigation, search Name: Biodiesel Solutions Inc Place: Sparks, Nevada Zip: 89431 Product: Designs and manufactures processing equipment and accessories to...

  18. Guardian Energy Management Solutions | Open Energy Information

    Open Energy Info (EERE)

    Guardian Energy Management Solutions Jump to: navigation, search Name: Guardian Energy Management Solutions Address: 753 Forest Street, Suite 110 Place: Marlborough, Massachusetts...

  19. Duke Energy Generation Services formerly Cinergy Solutions |...

    Open Energy Info (EERE)

    Generation Services formerly Cinergy Solutions Jump to: navigation, search Name: Duke Energy Generation Services (formerly Cinergy Solutions) Place: Cincinatti, Ohio Zip: 45202...

  20. Building America Technologies Solutions Case Study: Ventilation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies Solutions Case Study: Ventilation System Effectiveness and Tested Indoor Air Quality Impacts Building America Technologies Solutions Case Study: Ventilation System ...

  1. Island Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    search Name: Island Energy Solutions Place: Kailua, Hawaii Zip: 96734 Product: Island Energy Solutions, Inc. is an electrical contracting company, based out of Kailua, Oahu,...

  2. Eco Alternative Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: Eco Alternative Energy Solutions Place: Puerto Rico Product: Puerto Rico-based majority owner of joint venture Pevafersa America, which...

  3. Energy Options Solutions | Open Energy Information

    Open Energy Info (EERE)

    Energy Options & Solutions Place: Ann Arbor, Michigan Zip: 48103 Product: Michigan-based alternative energy consultant. References: Energy Options & Solutions1 This article is a...

  4. Technology Market Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: Technology & Market Solutions Place: Fairfax Station, Virginia Zip: 22039 Product: A consulting practice concentrating on technological,...

  5. Tribal Renewable Energy Solutions and Partnerships: Collaborating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Energy Solutions and Partnerships: Collaborating Through the Headwinds of Change Tribal Renewable Energy Solutions and Partnerships: Collaborating Through the Headwinds ...

  6. Clean Energy Solutions Center | Open Energy Information

    Open Energy Info (EERE)

    Center Jump to: navigation, search Logo: Clean Energy Solutions Center Name Clean Energy Solutions Center AgencyCompany Organization Clean Energy Ministerial Sector Energy Focus...

  7. Atlas Material Testing Solutions | Open Energy Information

    Open Energy Info (EERE)

    Atlas Material Testing Solutions Jump to: navigation, search Name: Atlas Material Testing Solutions Place: Chicago, IL Zip: 60613 Website: atlas-mts.com Coordinates: 41.9529209,...

  8. Conservation Resource Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: Conservation Resource Solutions Place: Cumming, Georgia Zip: 30040 Sector: Services Product: String representation "Conservation Re ......

  9. Global Power Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    Global Power Solutions LLC Jump to: navigation, search Name: Global Power Solutions LLC Place: Colorado Zip: CO 80401 Sector: Geothermal energy Product: String representation...

  10. Ebony Solutions UK | Open Energy Information

    Open Energy Info (EERE)

    Ebony Solutions UK Jump to: navigation, search Name: Ebony Solutions UK Place: Northwich, Cheshire, United Kingdom Zip: CW8 2SX Product: A UK biodiesel manufacturer. References:...

  11. Solar Electric Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    Electric Solutions LLC Jump to: navigation, search Name: Solar Electric Solutions, LLC Place: Woodland Hills, California Zip: 91364 Sector: Solar Product: California-based...

  12. Energy Solutions Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Energy Solutions Co Ltd Jump to: navigation, search Name: Energy Solutions Co Ltd Place: Seoul, Korea (Republic) Sector: Efficiency Product: A Korean builderengineering contractor...

  13. BFC Solutions Limited | Open Energy Information

    Open Energy Info (EERE)

    BFC Solutions Limited Jump to: navigation, search Name: BFC Solutions Limited Place: Taunton, England, United Kingdom Zip: TA1 PEJ Sector: Carbon Product: Somerset-based...

  14. PNE Renewable Solutions JV | Open Energy Information

    Open Energy Info (EERE)

    PNE Renewable Solutions JV Jump to: navigation, search Name: PNE & Renewable Solutions JV Place: Delaware Sector: Wind energy Product: Delaware-based limited liability company and...

  15. EQuilibrium Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    EQuilibrium Solutions Inc Jump to: navigation, search Name: eQuilibrium Solutions Inc Place: Boston, Massachusetts Zip: 2215 Sector: Carbon, Efficiency Product: Boston-based...

  16. Solargen Solutions UK | Open Energy Information

    Open Energy Info (EERE)

    Solargen Solutions UK Jump to: navigation, search Name: Solargen Solutions UK Place: United Kingdom Zip: NP 44 3AS Sector: Renewable Energy, Solar Product: String representation...

  17. Washington TRU Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Washington TRU Solutions Inc Jump to: navigation, search Name: Washington TRU Solutions, Inc. Place: Carlsbad, New Mexico Zip: 88220 Product: New Mexico-based managing and...

  18. Enisolar Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: Enisolar Energy Solutions Place: Istanbul, Turkey Sector: Wind energy Product: Turkey-based wind, PV, and hybrid system integrator; also...

  19. Solar amp Electric Solutions | Open Energy Information

    Open Energy Info (EERE)

    Electric Solutions Jump to: navigation, search Name: Solar & Electric Solutions Place: Santa Cruz, California Zip: 95062 Sector: Solar Product: Small solar installation firm in...

  20. Global Warming Solutions Inc previously Southern Investments...

    Open Energy Info (EERE)

    Solutions Inc previously Southern Investments Inc Jump to: navigation, search Name: Global Warming Solutions Inc (previously Southern Investments Inc) Place: Houston, Texas...

  1. Quantum Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: Quantum Energy Solutions Place: Rancho Cordova, California Zip: 95742 Product: California-based energy management company that was...

  2. Econic Renewable Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Econic Renewable Energy Solutions Jump to: navigation, search Name: Econic Renewable Energy Solutions Place: Norfolk, United Kingdom Zip: NR 105PQ Sector: Renewable Energy Product:...

  3. Renewable Energy Solutions, LLC | Open Energy Information

    Open Energy Info (EERE)

    Solutions, LLC Jump to: navigation, search Name: Renewable Energy Solutions, LLC Place: Fairfield, California Zip: 94534 Region: Bay Area Sector: Services Year Founded: 2008...

  4. International Environmental Solutions IES | Open Energy Information

    Open Energy Info (EERE)

    Environmental Solutions IES Jump to: navigation, search Name: International Environmental Solutions (IES) Place: Romoland, California Zip: 92585 Product: It is an environmentally...

  5. M S Solutions | Open Energy Information

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    Solutions Jump to: navigation, search Name: MS Solutions Place: Burdwan, West Bengal, India Sector: Biomass Product: Burdwan-based biomass cogenration project developer....

  6. Smarter Grid Solutions | Open Energy Information

    Open Energy Info (EERE)

    Smarter Grid Solutions Jump to: navigation, search Name: Smarter Grid Solutions Place: United Kingdom Product: String representation "The SGS technol ... the technology." is too...

  7. Eco Power Solutions | Open Energy Information

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    Power Solutions Jump to: navigation, search Name: Eco Power Solutions Place: Quincy, Massachusetts Zip: 2169 Product: Massachusetts-based, energy recovery and emission control...

  8. Eco Sustainable Solutions Ltd | Open Energy Information

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    Sustainable Solutions Ltd Jump to: navigation, search Name: Eco Sustainable Solutions Ltd Place: Dorset, United Kingdom Zip: BH23 6BG Sector: Biomass Product: Focused on organics...

  9. Presentation: Better Buildings Residential Program Solution Center...

    Broader source: Energy.gov (indexed) [DOE]

    Presentation: Better Buildings Residential Program Solution Center, from the U.S. Department of Energy's Better Buildings Neighborhood Program, April 2014. Solution Center Overview...

  10. Solution Capital Partners | Open Energy Information

    Open Energy Info (EERE)

    Solution Capital Partners Jump to: navigation, search Name: Solution Capital Partners Place: New York Zip: NY 10036 Product: A New York-based investment firm active in the...

  11. Nextreme Thermal Solutions Inc | Open Energy Information

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    Nextreme Thermal Solutions Inc Jump to: navigation, search Name: Nextreme Thermal Solutions Inc Place: North Carolina Zip: 27709-3981 Product: String representation "Manufactures...

  12. Atlantic Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Atlantic Energy Solutions Place: Foxboro, Massachusetts Sector: Efficiency, Renewable Energy Product: Atlantic Energy Solutions provides energy auditing for its customers and...

  13. Webinar Presentation: Energy Storage Solutions for Microgrids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation: Energy Storage Solutions for Microgrids (November 2012) Webinar Presentation: Energy Storage Solutions for Microgrids (November 2012) On November 7, 2012, Clean ...

  14. Freedom Energy Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    Energy Solutions LLC Jump to: navigation, search Name: Freedom Energy Solutions LLC Place: Westminster, Maryland Zip: 21157 Sector: Geothermal energy, Solar Product: Retailer and...

  15. Consolidated Edison Solutions, Inc. ESCO Qualification Sheet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consolidated Edison Solutions, Inc. ESCO Qualification Sheet Consolidated Edison Solutions, Inc. ESCO Qualification Sheet Document outlines the energy service company (ESCO)...

  16. Advanced Hydro Solutions | Open Energy Information

    Open Energy Info (EERE)

    Hydro Solutions Jump to: navigation, search Name: Advanced Hydro Solutions Place: Fairlawn, Ohio Zip: 44333 Sector: Hydro Product: Ohio-based company seeking to develop...

  17. 2016 Midwest Energy Solutions Conference

    Broader source: Energy.gov [DOE]

    The Midwest Energy Efficiency Alliance invites all energy stakeholders to gather at the annual Midwest Energy Solutions Conference to raise awareness and reinforce the importance of energy efficiency in the Midwest. This annual conference is about celebrating accomplishments and inspirations in energy efficiency, as well as laying out the efficiency program and policy landscape for the coming year.

  18. 2016 Midwest Energy Solutions Conference

    Broader source: Energy.gov [DOE]

    Once a year, MEEA invites all energy stakeholders to gather at our annual Midwest Energy Solutions Conference to raise awareness and reinforce the importance of energy efficiency in the Midwest. MES is about celebrating accomplishments in energy efficiency, as well as laying out the efficiency program and policy landscape for the coming year.

  19. Analysis of the Fisher solution

    SciTech Connect (OSTI)

    Abdolrahimi, Shohreh; Shoom, Andrey A.

    2010-01-15

    We study the d-dimensional Fisher solution which represents a static, spherically symmetric, asymptotically flat spacetime with a massless scalar field. The solution has two parameters, the mass M and the 'scalar charge' {Sigma}. The Fisher solution has a naked curvature singularity which divides the spacetime manifold into two disconnected parts. The part which is asymptotically flat we call the Fisher spacetime, and another part we call the Fisher universe. The d-dimensional Schwarzschild-Tangherlini solution and the Fisher solution belong to the same theory and are dual to each other. The duality transformation acting in the parameter space (M,{Sigma}) maps the exterior region of the Schwarzschild-Tangherlini black hole into the Fisher spacetime which has a naked timelike singularity, and interior region of the black hole into the Fisher universe, which is an anisotropic expanding-contracting universe and which has two spacelike singularities representing its 'big bang' and 'big crunch'. The big bang singularity and the singularity of the Fisher spacetime are radially weak in the sense that a 1-dimensional object moving along a timelike radial geodesic can arrive to the singularities intact. At the vicinity of the singularity the Fisher spacetime of nonzero mass has a region where its Misner-Sharp energy is negative. The Fisher universe has a marginally trapped surface corresponding to the state of its maximal expansion in the angular directions. These results and derived relations between geometric quantities of the Fisher spacetime, the Fisher universe, and the Schwarzschild-Tangherlini black hole may suggest that the massless scalar field transforms the black hole event horizon into the naked radially weak disjoint singularities of the Fisher spacetime and the Fisher universe which are 'dual to the horizon'.

  20. REMOVAL OF CHLORIDE FROM AQUEOUS SOLUTIONS

    DOE Patents [OSTI]

    Schulz, W.W.

    1959-08-01

    The removal of chlorides from aqueons solutions is described. The process involves contacting the aqueous chloride containing solution with a benzene solution about 0.005 M in phenyl mercuric acetate whereby the chloride anions are taken up by the organic phase and separating the organic phase from the aqueous solutions.

  1. Energy solutions?Director Eric Isaacs

    ScienceCinema (OSTI)

    Eric ISaacs

    2013-06-05

    Argonne's Director Eric Isaacs talks about the laboratory's efforts for creating new, clean energy solutions.

  2. Energy solutionsDirector Eric Isaacs

    SciTech Connect (OSTI)

    Eric ISaacs

    2012-08-08

    Argonne's Director Eric Isaacs talks about the laboratory's efforts for creating new, clean energy solutions.

  3. Electrochromic salts, solutions, and devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky,7,064,212 T. Mark (Los Alamos, NM)

    2006-06-20

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  4. Clean Energy Solutions Center (Presentation)

    SciTech Connect (OSTI)

    Reategui, S.

    2012-07-01

    The Clean Energy Ministerial launched the Clean Energy Solutions Center in April, 2011 for major economy countries, led by Australia and U.S. with other CEM partners. Partnership with UN-Energy is extending scope to support all developing countries: 1. Enhance resources on policies relating to energy access, small to medium enterprises (SMEs), and financing programs; 2. Offer expert policy assistance to all countries; 3. Expand peer to peer learning, training, and deployment and policy data for developing countries.

  5. Electrochromic Salts, Solutions, and Devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

    2008-10-14

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  6. Electrochromic Salts, Solutions, and Devices

    DOE Patents [OSTI]

    Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

    2008-11-11

    Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

  7. Functionalized polymers for binding to solutes in aqueous solutions

    DOE Patents [OSTI]

    Smith, Barbara F.; Robison, Thomas W.

    2006-11-21

    A functionalized polymer for binding a dissolved molecule in an aqueous solution is presented. The polymer has a backbone polymer to which one or more functional groups are covalently linked. The backbone polymer can be such polymers as polyethylenimine, polyvinylamine, polyallylamine, and polypropylamine. These polymers are generally water-soluble, but can be insoluble when cross-linked. The functional group can be for example diol derivatives, polyol derivatives, thiol and dithiol derivatives, guest-host groups, affinity groups, beta-diphosphonic acids, and beta-diamides

  8. Commercial Lighting Solutions Webtool Peer Review Report, Office Solutions

    SciTech Connect (OSTI)

    Beeson, Tracy A.; Jones, Carol C.

    2010-02-01

    The Commercial Lighting Solutions (CLS) project directly supports the U.S. Department of Energys Commercial Building Energy Alliance efforts to design high performance buildings. CLS creates energy efficient best practice lighting designs for widespread use, and they are made available to users via an interactive webtool that both educates and guides the end user through the application of the Lighting Solutions. This report summarizes the peer review of the CLS webtool for offices. The methodology for the peer review process included data collection (stakeholder input), analysis of the comments, and organization of the input into categories for prioritization of the comments against a set of criteria. Based on this process, recommendations were developed for the release of version 2.0 of the webtool at the Lightfair conference in Las Vegas in May 2010. The report provides a list of the top ten most significant and relevant improvements that will be made within the webtool for version 2.0 as well as appendices containing the comments and short-term priorities in additional detail. Peer review comments that are considered high priority by the reviewers and the CLS team but cannot be completed for Version 2.0 are listed as long-term recommendations.

  9. Ultrafast studies of solution dynamics

    SciTech Connect (OSTI)

    Woodruff, W.H.; Dyer, R.B.; Callender, R.H.

    1997-10-01

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Fast chemical dynamics generally must be initiated photochemically. This limits the applicability of modern laser methods for following the structural changes that occur during chemical and biological reactions to those systems that have an electronic chromophore that has a significant yield of photoproduct when excited. This project has developed a new and entirely general approach to ultrafast initiation of reactions in solution: laser-induced temperature jump (T-jump). The results open entire new fields of study of ultrafast molecular dynamics in solution. The authors have demonstrated the T-jump technique on time scales of 50 ps and longer, and have applied it to study of the fast events in protein folding. They find that a general lifetime of alpha-helix formation is ca 100 ns, and that tertiary folds (in apomyoglobin) form in ca 100 {mu}s.

  10. Eco Green Solutions | Open Energy Information

    Open Energy Info (EERE)

    Eco Green Solutions Place: Brazil Product: Brazil-based Ecodiesel creditor. References: Eco Green Solutions1 This article is a stub. You can help OpenEI by expanding it. Eco...

  11. Battery Wireless Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Solutions Inc Jump to: navigation, search Name: Battery & Wireless Solutions Inc Place: New Westminster, British Columbia, Canada Zip: V3M 5V9 Product: Distributor of battery and...

  12. Solar Project Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Place: California Sector: Solar Product: US-based JV to build solar-power plants in California. References: Solar Project Solutions1 This article is a stub. You can...

  13. EM Energy Solutions Ltd | Open Energy Information

    Open Energy Info (EERE)

    EM Energy Solutions Ltd Jump to: navigation, search Name: EM Energy Solutions Ltd Place: London, United Kingdom Zip: NW3 5QY Product: Consultant specialising in the development and...

  14. Westinghouse TRU Solutions Launches New Web Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRU Solutions LLC Launches New Web Site CARLSBAD, N.M., February 2, 2001 - Westinghouse TRU Solutions LLC (WTS) today launched its new Web site. WTS is the new management and ...

  15. Washington River Protection Solutions - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contracting Washington River Protection Solutions Contracting ORP Contracts and Procurements RL Contracts and Procurements CH2M HILL Plateau Remediation Company Mission Support Alliance Washington Closure Hanford HPM Corporation (HPMC) Wastren Advantage, Inc. Bechtel National, Inc. Washington River Protection Solutions Washington River Protection Solutions Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size Washington River Protection Solutions, LLC logo The operation

  16. Presentation: Better Buildings Residential Program Solution Center

    Broader source: Energy.gov [DOE]

    Presentation: Better Buildings Residential Program Solution Center, from the U.S. Department of Energy, Better Buildings Neighborhood Program.

  17. Cleantech Solutions (Massachusetts) | Open Energy Information

    Open Energy Info (EERE)

    Massachusetts Zip: 02108 Region: Greater Boston Area Sector: Efficiency Product: Energy efficiency solutions and consumption monitoring systems for buildings Website:...

  18. Building America Solution Center | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building America Solution Center Building America Solution Center World-Class Research At Your Fingertips The Building America Solution Center provides residential building professionals with access to expert information on hundreds of high-performance design and construction topics, including air sealing and insulation, HVAC components, windows, indoor air quality, and much more. Explore the Building America Solution Center. The user-friendly interface delivers a variety of resources for each

  19. Clean Energy Solutions Center Services (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-04-01

    The Clean Energy Solutions Center (Solutions Center) helps governments, advisors and analysts create policies and programs that advance the deployment of clean energy technologies. The Solutions Center partners with international organizations to provide online training, expert assistance, and technical resources on clean energy policy.

  20. NOPR EnergySolutions | Department of Energy

    Office of Environmental Management (EM)

    EnergySolutions NOPR EnergySolutions PDF icon NOPR EnergySolutions More Documents & Publications Meeting Notes re NOI for Convention on Supplementary Compensation Enforcement Letter, NEL-2011-03 - October 24, 2011 EIS-0359: DOE Notice of Availability of the Draft Supplement Analysis

  1. Solution synthesis of germanium nanocrystals

    DOE Patents [OSTI]

    Gerung, Henry (Albuquerque, NM); Boyle, Timothy J. (Kensington, MD); Bunge, Scott D. (Cuyahoga Falls, OH)

    2009-09-22

    A method for providing a route for the synthesis of a Ge(0) nanometer-sized material from. A Ge(II) precursor is dissolved in a ligand heated to a temperature, generally between approximately 100.degree. C. and 400.degree. C., sufficient to thermally reduce the Ge(II) to Ge(0), where the ligand is a compound that can bond to the surface of the germanium nanomaterials to subsequently prevent agglomeration of the nanomaterials. The ligand encapsulates the surface of the Ge(0) material to prevent agglomeration. The resulting solution is cooled for handling, with the cooling characteristics useful in controlling the size and size distribution of the Ge(0) materials. The characteristics of the Ge(II) precursor determine whether the Ge(0) materials that result will be nanocrystals or nanowires.

  2. Regional Transmission Projects: Finding Solutions

    SciTech Connect (OSTI)

    The Keystone Center

    2005-06-15

    The Keystone Center convened and facilitated a year-long Dialogue on "Regional Transmission Projects: Finding Solutions" to develop recommendations that will help address the difficult and contentious issues related to expansions of regional electric transmission systems that are needed for reliable and economic transmission of power within and across regions. This effort brought together a cross-section of affected stakeholders and thought leaders to address the problem with the collective wisdom of their experience and interests. Transmission owners sat at the table with consumer advocates and environmental organizations. Representatives from regional transmission organizations exchanged ideas with state and federal regulators. Generation developers explored common interests with public power suppliers. Together, the Dialogue participants developed consensus solutions about how to begin unraveling some of the more intractable issues surrounding identification of need, allocation of costs, and reaching consensus on siting issues that can frustrate the development of regional transmission infrastructure. The recommendations fall into three broad categories: 1. Recommendations on appropriate institutional arrangements and processes for achieving regional consensus on the need for new or expanded transmission infrastructure 2. Recommendations on the process for siting of transmission lines 3. Recommendations on the tools needed to support regional planning, cost allocation, and siting efforts. List of Dialogue participants: List of Dialogue Participants: American Electric Power American Transmission Company American Wind Energy Association California ISO Calpine Corporation Cinergy Edison Electric Institute Environmental Defense Federal Energy Regulatory Commission Great River Energy International Transmission Company ISO-New England Iowa Public Utility Board Kanner & Associates Midwest ISO National Association of Regulatory Utility Commissioners National Association of State Utility Consumer Advocates National Grid Northeast Utilities PA Office of Consumer Advocates Pacific Gas & Electric Corporation Pennsylvania Public Utility Commission PJM Interconnection The Electricity Consumers Resource Council U.S. Department of Energy US Department of the Interior Van Ness Feldman Western Interstate Energy Board Wind on the Wires Wisconsin Public Service Commission Xcel Energy

  3. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons via Indirect Liquefaction. Thermochemical Research Pathway to High-Octane Gasoline Blendstock Through Methanol/Dimethyl Ether Intermediates

    SciTech Connect (OSTI)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Schaidle, Josh; Biddy, Mary; Humbird, David; Snowden-Swan, Lesley J.; Ross, Jeff; Sexton, Danielle; Yap, Raymond; Lukas, John

    2015-03-01

    This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s (BETO’s) efforts to enable the development of technologies for the production of infrastructure-compatible, cost-competitive liquid hydrocarbon fuels from lignocellulosic biomass feedstocks. The research funded by BETO is designed to advance the state of technology of biomass feedstock supply and logistics, conversion, and overall system sustainability. It is expected that these research improvements will be made within the 2022 timeframe. As part of their involvement in this research and development effort, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory investigate the economics of conversion pathways through the development of conceptual biorefinery process models and techno-economic analysis models. This report describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas or syngas via indirect gasification, gas cleanup, catalytic conversion of syngas to methanol intermediate, methanol dehydration to dimethyl ether (DME), and catalytic conversion of DME to high-octane, gasoline-range hydrocarbon blendstock product. The conversion process configuration leverages technologies previously advanced by research funded by BETO and demonstrated in 2012 with the production of mixed alcohols from biomass. Biomass-derived syngas cleanup via reforming of tars and other hydrocarbons is one of the key technology advancements realized as part of this prior research and 2012 demonstrations. The process described in this report evaluates a new technology area for the downstream utilization of clean biomass-derived syngas for the production of high-octane hydrocarbon products through methanol and DME intermediates. In this process, methanol undergoes dehydration to DME, which is subsequently converted via homologation reactions to high-octane, gasoline-range hydrocarbon products.

  4. Coupled Fluid Energy Solute Transport

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    CFEST is a Coupled Fluid, Energy, and Solute Transport code for the study of a multilayered, nonisothermal ground-water system. It can model discontinuous as well as continuous layers, time-dependent and constant source/sinks, and transient as well as steady-state flow. The finite element method is used for analyzing isothermal and nonisothermal events in a confined aquifer system. Only single-phase Darcian flow is considered. In the Cartesian coordinate system, flow in a horizontal plane, in a verticalmore » plane, or in a fully three-dimensional region can be simulated. An option also exists for the axisymmetric analysis of a vertical cross section. The code employs bilinear quadrilateral elements in all two dimensional analyses and trilinear quadrilateral solid elements in three dimensional simulations. The CFEST finite element formulation can approximate discontinuities, major breaks in slope or thickness, and fault zones in individual hydrogeologic units. The code accounts for heterogeneity in aquifer permeability and porosity and accommodates anisotropy (collinear with the Cartesian coordinates). The variation in the hydraulic properties is described on a layer-by-layer basis for the different hydrogeologic units. Initial conditions can be prescribed hydraulic head or pressure, temperature, or concentration. CFEST can be used to support site, repository, and waste package subsystem assessments. Some specific applications are regional hydrologic characterization; simulation of coupled transport of fluid, heat, and salinity in the repository region; consequence assessment due to natural disruption or human intrusion scenarios in the repository region; flow paths and travel-time estimates for transport of radionuclides; and interpretation of well and tracer tests.« less

  5. Technical solutions to nonproliferation challenges

    SciTech Connect (OSTI)

    Satkowiak, Lawrence

    2014-05-09

    The threat of nuclear terrorism is real and poses a significant challenge to both U.S. and global security. For terrorists, the challenge is not so much the actual design of an improvised nuclear device (IND) but more the acquisition of the special nuclear material (SNM), either highly enriched uranium (HEU) or plutonium, to make the fission weapon. This paper provides two examples of technical solutions that were developed in support of the nonproliferation objective of reducing the opportunity for acquisition of HEU. The first example reviews technologies used to monitor centrifuge enrichment plants to determine if there is any diversion of uranium materials or misuse of facilities to produce undeclared product. The discussion begins with a brief overview of the basics of uranium processing and enrichment. The role of the International Atomic Energy Agency (IAEA), its safeguard objectives and how the technology evolved to meet those objectives will be described. The second example focuses on technologies developed and deployed to monitor the blend down of 500 metric tons of HEU from Russia's dismantled nuclear weapons to reactor fuel or low enriched uranium (LEU) under the U.S.-Russia HEU Purchase Agreement. This reactor fuel was then purchased by U.S. fuel fabricators and provided about half the fuel for the domestic power reactors. The Department of Energy established the HEU Transparency Program to provide confidence that weapons usable HEU was being blended down and thus removed from any potential theft scenario. Two measurement technologies, an enrichment meter and a flow monitor, were combined into an automated blend down monitoring system (BDMS) and were deployed to four sites in Russia to provide 24/7 monitoring of the blend down. Data was downloaded and analyzed periodically by inspectors to provide the assurances required.

  6. EA-306 MAG Energy Solutions, Inc. | Department of Energy

    Energy Savers [EERE]

    MAG Energy Solutions, Inc. EA-306 MAG Energy Solutions, Inc. Order authorizing MAG Energy Solutions, Inc. to export electric energy to Canada PDF icon EA-306 MAG Energy Solutions, Inc. More Documents & Publications EA-306-B MAG Energy Solutions, Inc. EA-306-A MAG Energy Solutions, Inc. Application to Export Electric Energy OE Docket No. EA-306-A MAG Energy Solutions

  7. Supergravity solutions without triholomorphic U(1) isometries

    SciTech Connect (OSTI)

    Ghezelbash, A. M.

    2008-12-15

    We investigate the construction of five-dimensional supergravity solutions that do not have any triholomorphic U(1) isometries. We construct a class of solutions that in various limits of parameters reduces to many of previously constructed five-dimensional supergravity solutions based on both hyper-Kaehler base spaces that can be put into a Gibbons-Hawking form and hyper-Kaehler base spaces that cannot be put into a Gibbons-Hawking form. We find a new solution which is over triaxial Bianchi type IX Einstein-hyper-Kaehler base space with no triholomorphic U(1) symmetry. One special case of this solution corresponds to a five-dimensional solution based on Eguchi-Hanson type II geometry.

  8. Energy Solutions Conference | Department of Energy

    Energy Savers [EERE]

    Energy Solutions Conference Energy Solutions Conference March 23, 2016 9:00AM EDT to March 24, 2016 4:00PM EDT Online The virtual Energy Solutions Conference will be held March 23-24, 2016. Bioenergy Technologies Office Director Jonathan Male will be giving a virtual presentation on the Office's activities supporting the federal bioeconomy as part of the renewable energy portion of the program.

  9. Integrated Engineering, Construction, and Management Solutions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrated Engineering, Construction, and Management Solutions Washington Group International Contact: Susan Scott Public Affairs (505) 234-7204 http://www.wipp.ws Washington TRU Solutions LLC Washington TRU Solutions LLC Waste Isolation Pilot Plant Waste Isolation Pilot Plant P.O. Box 2078 P.O. Box 2078 Carlsbad, New Mexico 88221 Carlsbad, New Mexico 88221 For immediate release For immediate release Firm Awarded WIPP Records Demonstration Contract CARLSBAD, N.M., February 17, 2005 - Washington

  10. RECOVERY OF TETRAVALENT CATIONS FROM AQUEOUS SOLUTIONS

    DOE Patents [OSTI]

    Moore, R.L.

    1958-05-01

    The recovery of plutonium, zirconium, and tetravalent cerium values from aqueous solutions is described. It consists of adding an alkyl phosphate to a nnineral acid aqueous solution containing the metal to be recovered, whereby a precipitate forms with the tetravalent values, and separating the precipitate from the solution. All alkyl phosphates, if water-soluble, are suitable for the process; however, monobutyl phosphate has been found best.

  11. Energy Technology Solutions | Department of Energy

    Office of Environmental Management (EM)

    Technology Solutions Energy Technology Solutions Public-private partnerships transforming industry and list of commercialized technologies, knowledge-based results, and promising technologies PDF icon itp_successes.pdf More Documents & Publications Energy Technology Solutions: Public-Private Partnerships Transforming Industry, November 2010 ITP Energy Intensive Processes: Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry Energy-Intensive Processes

  12. Tangent Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Tangent Energy Solutions Place: Pennsylvania Zip: PA 19348 Product: Pennsylvania-based company developing and implementing sustainable energy...

  13. DG Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    92101 Product: Develops owns and operates industrial, commercial and institutional cogeneration plants from 2-50MW. References: DG Energy Solutions1 This article is a stub. You...

  14. Building America Technology Solutions Case Study: Combustion...

    Energy Savers [EERE]

    Combustion Safety Simplified Test Protocol Building America Technology Solutions Case Study: Combustion Safety Simplified Test Protocol Two U.S. Department of Energy Building ...

  15. Building America Technology Solutions Case Study: Ventilation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Case Study: Ventilation System Effectiveness and Tested Indoor Air Quality Impacts Building America Technology Solutions Case Study: Ventilation System Effectiveness and Tested ...

  16. EnergySolutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Salt Lake City, Utah Zip: 84101 Sector: Services Product: Utah-based international nuclear services company that provides services and solutions to the nuclear industry....

  17. Better Buildings Residential Program Solution Center Demonstration...

    Office of Environmental Management (EM)

    Program Solution Center Vehicle Technologies Office Merit Review 2014: A Combined Experimental and Modeling Approach for the Design of High Coulombic Efficiency Si Electrodes...

  18. Miniaturized Turbine Offers Desalination Solution | GE Global...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from ice New solution draws from the GE Store, integrating GE's experience with steam turbine, oil & gas compressors, 3D printing and water processing NISKAYUNA, NY, November 10,...

  19. Energy Solutions S A | Open Energy Information

    Open Energy Info (EERE)

    Solutions S.A. Place: PERNIK, Bulgaria Zip: 2304 Sector: Solar Product: produces photovoltaic modules using mono- and poly-crystalline Si solar cells. Crystalline Si...

  20. Enterprise Solar Solutions | Open Energy Information

    Open Energy Info (EERE)

    Sector: Solar Product: New York-based company that specializes in commercial solar photovoltaic applications for businesses. References: Enterprise Solar Solutions1 This article...

  1. TVA- Energy Right Solutions for Business

    Broader source: Energy.gov [DOE]

    TVA offers the Energy Right Solutions Program to commercial and industrial facilities. In addition to prescriptive rebates for lighting, motors, HVAC, and kitchen equipment, administrators take a...

  2. TVA- Energy Right Solutions for Business

    Broader source: Energy.gov [DOE]

    The Tennessee Valley Authority (TVA) offers the Energy Right Solutions Program for commercial and industrial facilities.  Prescriptive rebates are available for lighting, motors, HVAC, and kitchen...

  3. Mobile Power Solutions | Open Energy Information

    Open Energy Info (EERE)

    laboratory focused on United NationsDepartment of Transportation compliance and battery performance testing. References: Mobile Power Solutions1 This article is a stub....

  4. Advanced Combustion Concepts - Enabling Systems and Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (ACCESS) for High Efficiency Light Duty Vehicles Vehicle Technologies Office Merit Review 2014: Advanced Combustion Concepts - Enabling Systems and Solutions (ACCESS) for ...

  5. SMECO- Small Business/Non-Profit Solutions

    Broader source: Energy.gov [DOE]

    Southern Maryland Electric Cooperative (SMECO) offers Small Business Solutions program, which provides incentives up to 80% of the cost of retrofit projects for qualified small business and non...

  6. Better Buildings Residential Program Solution Center Demonstration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transcript The Better Buildings Residential Program Solution Center is a robust online collection of nearly 1,000 examples, strategies, and resources from Better Buildings...

  7. Independent Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Independent Energy Solutions Address: 1090 Joshua Way Place: Vista, California Zip: 92081 Region: Southern CA Area Sector: Solar Product: Renewable...

  8. Infinite Power Solutions | Open Energy Information

    Open Energy Info (EERE)

    Colorado Zip: 80127 Product: Littleton-based solid-state, rechargeable thin-film micro-energy storage device manufacturer. References: Infinite Power Solutions1 This article...

  9. Community Renewable Solutions LLC | Open Energy Information

    Open Energy Info (EERE)

    LLC Jump to: navigation, search Name: Community Renewable Solutions LLC Place: Santa Barbara, California Phone Number: 805 284 9028 Website: www.communityrenewables.biz...

  10. Process for extracting technetium from alkaline solutions

    DOE Patents [OSTI]

    Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN)

    1995-01-01

    A process for extracting technetium values from an aqueous alkaline solution containing at least one alkali metal hydroxide and at least one alkali metal nitrate, the at least one alkali metal nitrate having a concentration of from about 0.1 to 6 molar. The solution is contacted with a solvent consisting of a crown ether in a diluent for a period of time sufficient to selectively extract the technetium values from the aqueous alkaline solution. The solvent containing the technetium values is separated from the aqueous alkaline solution and the technetium values are stripped from the solvent.

  11. Innovative Energy Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Innovative Energy Solutions Inc Place: Las Vegas, Nevada Zip: 89101 Sector: Hydro, Hydrogen Product: Holds serveral patents related to waste heat recovery, heat generating...

  12. NCRC Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    search Name: NCRC Energy Solutions Place: Plano, Texas Zip: 75093 Sector: Hydro, Hydrogen Product: Developed and controls all rights to a proprietary software application...

  13. New Energy Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Energy Solutions Inc Place: Pittsfield, Massachusetts Zip: MA 01201 Sector: Hydro, Hydrogen Product: Small private new energy company active in the fuel cell, hydrogen and wave...

  14. ECO2 Asset Solutions | Open Energy Information

    Open Energy Info (EERE)

    Asset Solutions Place: Tampa, Florida Sector: Carbon, Services Product: Florida-based provider of advisory services to both buyers and sellers on the Carbon Markets. They serve a...

  15. Stellar Energy Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    California Zip: 95448 Sector: Renewable Energy, Solar Product: Turn-key renewable energy solutions provider specializing in solar electric roofing. References: Stellar...

  16. Basic energy properties of electrolytic solutions database. ...

    Office of Scientific and Technical Information (OSTI)

    Basic energy properties of electrolytic solutions database. Viscosity, thermal conductivity, density, enthalpy Citation Details In-Document Search Title: Basic energy properties...

  17. New Grid Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Energy Solutions Address: 3704 Macomb St Place: Washington DC Zip: 20016 Sector: Biomass, Buildings, Efficiency, Geothermal energy, Services, Solar Product: Renewable Energy and...

  18. Solar India Solutions | Open Energy Information

    Open Energy Info (EERE)

    Visakhapatnam, Andhra Pradesh, India Zip: 530016 Sector: Efficiency Product: Andhra-based energy efficiency consultant. References: Solar India Solutions1 This article is a stub....

  19. Natural Solutions Pvt Ltd | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Natural Solutions Pvt. Ltd. Place: Mumbai, Maharashtra, India Sector: Renewable Energy Product: Mumbai-based IT consultant. The firm plans to set...

  20. ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solutions for a Dynamic World PDF icon alumvision.pdf More Documents & Publications ITP Aluminum: Alumina Technology Roadmap U.S. Energy Requirements for Aluminum Production...

  1. El Paso Electric Company- Residential Solutions Program

    Broader source: Energy.gov [DOE]

    The El Paso Electric Residential Solutions Program offers El Paso Electric customers and participating contractors cash and non-cash incentives for implementing energy efficiency improvements in...

  2. Removal of radioisotopes from waste solutions

    DOE Patents [OSTI]

    Kirby, H.W.

    1973-10-01

    The invention comprises removing radioisotopes from waste liquids or solutions by passing these through filters and through a column containing a suitable salt of phosphoric acid. (Official Gazette)

  3. Energy Solutions International | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Energy Solutions International Place: St. Paul, Minnesota Zip: 55107 Product: For the last decade, ESI has been creating fluorescent...

  4. Bringing Solutions to the Developing World

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    low-cost, sustainable solutions to the problem accompanied by an innovative business model that is informed by culturally relevant data, lessons from failed technologies and...

  5. Presentation: Better Buildings Residential Program Solution Center

    Broader source: Energy.gov [DOE]

    Presentation: Better Buildings Residential Program Solution Center, from the U.S. Department of Energy's Better Buildings Neighborhood Program, April 2014.

  6. Cleantech Solutions (Colorado) | Open Energy Information

    Open Energy Info (EERE)

    Place: Boulder, Colorado Zip: 80301 Region: Rockies Area Sector: Efficiency Product: Energy efficiency solutions and consumption monitoring systems for buildings Website:...

  7. H I Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Zip: 30144-1299 Product: Building Management Systems solutions company, providing computer based automation systems for industrial, commercial, office, retail, educational and...

  8. Engineered Solutions: Order (2010-CE-2112)

    Broader source: Energy.gov [DOE]

    DOE issued an Order after entering into a Compromise Agreement with Engineered Solutions, Inc. to resolve a case involving the failure to certify dehumidifier basic model SD109.

  9. Engineered Solutions: Proposed Penalty (2010-CE-2112)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Engineered Solutions, Inc. failed to certify a dehumidifier as compliant with the applicable energy conservation standards.

  10. Green Heat Solutions Limited | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: Green Heat Solutions Limited Region: Scotland Sector: Marine and Hydrokinetic Website: http: This company is listed in the Marine and Hydrokinetic...

  11. Building America Technology Solutions for New and Existing Homes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Solutions for New Manufactured Homes - Washington, Oregon, and Idaho Building America Technology Solutions for New and Existing Homes: Technology Solutions for New ...

  12. CO2 Global Solutions International | Open Energy Information

    Open Energy Info (EERE)

    Global Solutions International Jump to: navigation, search Name: CO2 Global Solutions International Place: Madrid, Spain Zip: 28001 Sector: Carbon Product: CO2 Global Solutions is...

  13. Clean Energy Solutions Centers Fact Sheet | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    A fact sheet describing the mission of the Clean Energy Solution Center. Clean Energy Solutions Centers Fact Sheet More Documents & Publications Clean-Energy-Solutions-Centers-Fact...

  14. Soleil Energy Solutions Greensboro North Carolina | Open Energy...

    Open Energy Info (EERE)

    Soleil Energy Solutions Greensboro North Carolina Jump to: navigation, search Logo: Soleil Energy Solutions Greensboro North Carolina Name: Soleil Energy Solutions Greensboro North...

  15. Calhoun County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Number 2 Climate Zone Subtype A. Places in Calhoun County, Texas Point Comfort, Texas Port Lavaca, Texas Seadrift, Texas Retrieved from "http:en.openei.orgw...

  16. GE Lighting Solutions: Order (2013-SE-4901)

    Broader source: Energy.gov [DOE]

    DOE ordered General Electric Lighting Solutions, LLC to pay a $5,360 civil penalty after finding GE Lighting Solutions had manufactured and distributed in commerce in the U.S. 30 units of basic model DR4-RTFB-23B and 177 units (of which 85 units remain in inventory) of basic model DR4-RTFB-77A-002, noncompliant traffic signal modules.

  17. Zinc Bromide Waste Solution Treatment Options

    SciTech Connect (OSTI)

    Langston, C.A.

    2001-01-16

    The objective of this effort was to identify treatment options for 20,000 gallons of low-level radioactively contaminated zinc bromide solution currently stored in C-Area. These options will be relevant when the solutions are declared waste.

  18. Novel Nanostructured Interface Solution for Automotive Thermoelectric

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modules Application | Department of Energy Nanostructured Interface Solution for Automotive Thermoelectric Modules Application Novel Nanostructured Interface Solution for Automotive Thermoelectric Modules Application Presents nanostructured thermal/electrical interface tapeŽ concept involving carbon nanotube and metal nanowire films to improve thermomechanical cycling behavior of automotive TEGs PDF icon asheghi.pdf More Documents & Publications Thermoelectrics Partnership: Automotive

  19. Conference Agenda: Residential Energy Efficiency Solutions 2012 |

    Office of Environmental Management (EM)

    Department of Energy Conference Agenda: Residential Energy Efficiency Solutions 2012 Conference Agenda: Residential Energy Efficiency Solutions 2012 Presents conference agenda including a general overview and detailed breakouts. PDF icon Conference Agenda More Documents & Publications Draft Agenda for U.S.-Africa Energy Ministerial Biomass 2009 Conference Agenda Biomass 2011 Conference Agenda

  20. PROCESSES OF RECLAIMING URANIUM FROM SOLUTIONS

    DOE Patents [OSTI]

    Zumwalt, L.R.

    1959-02-10

    A process is described for reclaiming residual enriched uranium from calutron wash solutions containing Fe, Cr, Cu, Ni, and Mn as impurities. The solution is adjusted to a pH of between 2 and 4 and is contacted with a metallic reducing agent, such as iron or zinc, in order to reduce the copper to metal and thereby remove it from the solution. At the same time the uranium present is reduced to the uranous state The solution is then contacted with a precipitate of zinc hydroxide or barium carbonate in order to precipitate and carry uranium, iron, and chromium away from the nickel and manganese ions in the solution. The uranium is then recovered fronm this precipitate.

  1. SEPARATION OF RUTHENIUM FROM AQUEOUS SOLUTIONS

    DOE Patents [OSTI]

    Callis, C.F.; Moore, R.L.

    1959-09-01

    >The separation of ruthenium from aqueous solutions containing uranium plutonium, ruthenium, and fission products is described. The separation is accomplished by providing a nitric acid solution of plutonium, uranium, ruthenium, and fission products, oxidizing plutonium to the hexavalent state with sodium dichromate, contacting the solution with a water-immiscible organic solvent, such as hexone, to extract plutonyl, uranyl, ruthenium, and fission products, reducing with sodium ferrite the plutonyl in the solvent phase to trivalent plutonium, reextracting from the solvent phase the trivalent plutonium, ruthenium, and some fission products with an aqueous solution containing a salting out agent, introducing ozone into the aqueous acid solution to oxidize plutonium to the hexavalent state and ruthenium to ruthenium tetraoxide, and volatizing off the ruthenium tetraoxide.

  2. Reference electrode for strong oxidizing acid solutions

    DOE Patents [OSTI]

    Rigdon, Lester P. (Livermore, CA); Harrar, Jackson E. (Castro Valley, CA); Bullock, Sr., Jack C. (Pleasanton, CA); McGuire, Raymond R. (Brentwood, CA)

    1990-01-01

    A reference electrode for the measurement of the oxidation-reduction potentials of solutions is especially suitable for oxidizing solutions such as highly concentrated and fuming nitric acids, the solutions of nitrogen oxides, N.sub.2 O.sub.4 and N.sub.2 O.sub.5, in nitric acids. The reference electrode is fabricated of entirely inert materials, has a half cell of Pt/Ce(IV)/Ce(III)/70 wt. % HNO.sub.3, and includes a double-junction design with an intermediate solution of 70 wt. % HNO.sub.3. The liquid junctions are made from Corning No. 7930 glass for low resistance and negligible solution leakage.

  3. Microbial Activity and Precipitation at Solution-Solution Mixing Zones in

    Office of Scientific and Technical Information (OSTI)

    Porous Media -- Subsurface Biogeochemical Research (Technical Report) | SciTech Connect Microbial Activity and Precipitation at Solution-Solution Mixing Zones in Porous Media -- Subsurface Biogeochemical Research Citation Details In-Document Search Title: Microbial Activity and Precipitation at Solution-Solution Mixing Zones in Porous Media -- Subsurface Biogeochemical Research The goal for this research was to understand how best to add compounds to receptive microbial communities in porous

  4. Energy Technology Solutions: Public-Private Partnerships Transforming...

    Energy Savers [EERE]

    Energy Technology Solutions: Public-Private Partnerships Transforming Industry, November 2010 Energy Technology Solutions: Public-Private Partnerships Transforming Industry,...

  5. Environmental Management and Planning Solutions, Inc | Open Energy...

    Open Energy Info (EERE)

    Environmental Management and Planning Solutions, Inc Jump to: navigation, search Name: Environmental Management and Planning Solutions, Inc Abbreviation: EMPSi Website:...

  6. WIPP Weatherization: Common Errors and Innovative Solutions Presentati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    WIPP Weatherization: Common Errors and Innovative Solutions Presentation WIPP Weatherization: Common Errors and Innovative Solutions Presentation This presentation contains...

  7. EA-284-A Sempra Energy Solutions: Temporary Extension | Department of

    Energy Savers [EERE]

    Energy A Sempra Energy Solutions: Temporary Extension EA-284-A Sempra Energy Solutions: Temporary Extension Temporary extension of order authorizing Sempra Energy Solutions to export electric energy to mexico. PDF icon EA-284-A Sempra Energy Solutions More Documents & Publications EA-284-A Sempra Energy Solutions EA-406 Sempra Generation, LLC EA-284-C NOBLE AMERICAS ENERGY SOLUTIONS LLC

  8. EA-284-A Sempra Energy Solutions | Department of Energy

    Office of Environmental Management (EM)

    4-A Sempra Energy Solutions EA-284-A Sempra Energy Solutions Order authorizing Sempra Energy Solutions to export electric energy to Mexico. PDF icon EA-284-A Sempra Energy Solutions More Documents & Publications EA-284-A Sempra Energy Solutions: Temporary Extension EA-406 Sempra Generation, LLC EA-284-C NOBLE AMERICAS ENERGY SOLUTIONS LLC

  9. Stabilization of polyaniline solutions through additives

    DOE Patents [OSTI]

    Wrobleski, Debra A. (Los Alamos, NM); Benicewicz, Brian C. (Los Alamos, NM)

    1996-01-01

    A stabilized non-conductive polyaniline solution comprising from about 1 to bout 10 percent by weight polyaniline or a polyaniline derivative, from about 90 to about 99 percent by weight N-methylpyrrolidone, and from about 0.5 percent by weight to about 15 percent by weight of a solution stabilizing additive selected from the group consisting of hindered amine light stabilizers, polymeric amines, and dialkylamines, percent by weight of additive based on the total weight of polyaniline or polyaniline derivative is provided together with a method for stabilizing a polyaniline solution.

  10. Stabilization of polyaniline solutions through additives

    DOE Patents [OSTI]

    Wrobleski, D.A.; Benicewicz, B.C.

    1996-12-10

    A stabilized non-conductive polyaniline solution comprising from about 1 to about 10 percent by weight polyaniline or a polyaniline derivative, from about 90 to about 99 percent by weight N-methylpyrrolidone, and from about 0.5 percent by weight to about 15 percent by weight of a solution stabilizing additive selected from the group consisting of hindered amine light stabilizers, polymeric amines, and dialkylamines, percent by weight of additive based on the total weight of polyaniline or polyaniline derivative is provided together with a method for stabilizing a polyaniline solution. 4 figs.

  11. Supersymmetric Kerr-anti-de Sitter solutions

    SciTech Connect (OSTI)

    Cvetic, Mirjam; Gao Peng; Simon, Joan

    2005-07-15

    We prove the existence of one quarter supersymmetric type IIB configurations that arise as nontrivial scaling solutions of the standard five-dimensional Kerr-anti-de Sitter black holes by the explicit construction of its Killing spinors. This neutral, spinning solution is asymptotic to the static anti-de Sitter space-time with cosmological constant -(1/l{sup 2}), it has two finite equal angular momenta J{sub 1}={+-}J{sub 2}, mass M=(1/l)(|J{sub 1}|+|J{sub 2}|) and a naked singularity. We also address the scaling limit associated with one-half supersymmetric solution with only one angular momentum.

  12. Membrane separation of ionic liquid solutions

    DOE Patents [OSTI]

    Campos, Daniel; Feiring, Andrew Edward; Majumdar, Sudipto; Nemser, Stuart

    2015-09-01

    A membrane separation process using a highly fluorinated polymer membrane that selectively permeates water of an aqueous ionic liquid solution to provide dry ionic liquid. Preferably the polymer is a polymer that includes polymerized perfluoro-2,2-dimethyl-1,3-dioxole (PDD). The process is also capable of removing small molecular compounds such as organic solvents that can be present in the solution. This membrane separation process is suitable for drying the aqueous ionic liquid byproduct from precipitating solutions of biomass dissolved in ionic liquid, and is thus instrumental to providing usable lignocellulosic products for energy consumption and other industrial uses in an environmentally benign manner.

  13. Separation of metal ions from aqueous solutions

    DOE Patents [OSTI]

    Almon, Amy C. (Augusta, GA)

    1994-01-01

    A process and apparatus for quantitatively and selectively separating metal ions from mixtures thereof in aqueous solution. The apparatus includes, in combination, a horizontal electrochemical flow cell containing flow bulk electrolyte solution and an aqueous, metal ion-containing solution, the cell containing a metal mesh working electrode, a counter electrode positioned downstream from the working electrode, an independent variable power supply/potentiostat positioned outside of the flow cell and connected to the electrodes, and optionally a detector such as a chromatographic detector, positioned outside the flow cell. This apparatus and its operation has significant application where trace amounts of metal ions are to be separated.

  14. Concentration of perrhenate and pertechnetate solutions

    DOE Patents [OSTI]

    Knapp, F.F.; Beets, A.L.; Mirzadeh, S.; Guhlke, S.

    1998-03-17

    A method is described for preparing a concentrated solution of a carrier-free radioisotope which includes the steps of: (a) providing a generator column loaded with a composition containing a parent radioisotope; (b) eluting the generator column with an eluent solution which includes a salt of a weak acid to elute a target daughter radioisotope from the generator column in a first eluate; (c) eluting a cation-exchange column with the first eluate to exchange cations of the salt for hydrogen ions and to elute the target daughter radioisotope and a weak acid in a second eluate; (d) eluting an anion-exchange column with the second eluate to trap and concentrate the target daughter radioisotope and to elute the weak acid solution therefrom; and (e) eluting the concentrated target daughter radioisotope from the anion-exchange column with a saline solution. 1 fig.

  15. TVA- Energy Right Solutions for Business

    Broader source: Energy.gov [DOE]

    TVA offers the Energy Right Solutions Program to commercial and industrial facilities.  In addition to prescriptive rebates for lighting, motors, HVAC, and kitchen equipment, administrators take a...

  16. WM Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    Los Angeles, California Product: Owns and operates a landfill gas plant located at Bradley Landfill. References: WM Solutions Inc1 This article is a stub. You can help OpenEI...

  17. Glendale Water and Power- Solar Solutions Program

    Broader source: Energy.gov [DOE]

    The Solar Solutions program provides all customer groups with an incentive to install photovoltaic (PV) systems on their homes and buildings. Rebate levels will decrease over time on an annual...

  18. Lightweight Steel Solutions for Automotive Industry

    SciTech Connect (OSTI)

    Lee, Hong Woo; Kim, Gyosung; Park, Sung Ho

    2010-06-15

    Recently, improvement in fuel efficiency and safety has become the biggest issue in worldwide automotive industry. Although the regulation of environment and safety has been tightened up more and more, the majority of vehicle bodies are still manufactured from stamped steel components. This means that the optimized steel solutions enable to demonstrate its ability to reduce body weight with high crashworthiness performance instead of expensive light weight materials such as Al, Mg and composites. To provide the innovative steel solutions for automotive industry, POSCO has developed AHSS and its application technologies, which is directly connected to EVI activities. EVI is a technical cooperation program with customer covering all stages of new car project from design to mass production. Integrated light weight solutions through new forming technologies such as TWB, hydroforming and HPF are continuously developed and provided for EVI activities. This paper will discuss the detailed status of these technologies especially light weight steel solutions based on innovative technologies.

  19. Concentration of perrhenate and pertechnetate solutions

    DOE Patents [OSTI]

    Knapp, Furn F. (Oak Ridge, TN); Beets, Arnold L. (Clinton, TN); Mirzadeh, Saed (Knoxville, TN); Guhlke, Stefan (Bonn, DE)

    1998-01-01

    A method of preparing a concentrated solution of a carrier-free radioisotope which includes the steps of: a. providing a generator column loaded with a composition containing a parent radioisotope; b. eluting the generator column with an eluent solution which includes a salt of a weak acid to elute a target daughter radioisotope from the generator column in a first eluate. c. eluting a cation-exchange column with the first eluate to exchange cations of the salt for hydrogen ions and to elute the target daughter radioisotope and a weak acid in a second eluate; d. eluting an anion-exchange column with the second eluate to trap and concentrate the target daughter radioisotope and to elute the weak acid solution therefrom; and e. eluting the concentrated target daughter radioisotope from the anion-exchange column with a saline solution.

  20. Agri Energy Funding Solutions | Open Energy Information

    Open Energy Info (EERE)

    Place: Omaha, Nebraska Zip: 68137-2495 Sector: Biomass, Wind energy Product: AGRI-ENERGY FUNDING SOLUTIONS is a market consultant for BioDiesel, Ethanol as well as Biomass...

  1. E3 Regenesis Solutions | Open Energy Information

    Open Energy Info (EERE)

    Foster City, California Zip: 94404 Product: A California-based company developing waste-to-energy projects in the southern US. References: E3 Regenesis Solutions1 This article...

  2. EIS-0219: F-Canyon Plutonium Solutions

    Broader source: Energy.gov [DOE]

    This EIS evaluates the potential environmental impacts of processingthe plutonium solutions to metal form using the F-Canyon and FB-Line facilities at the Savannah River Site.

  3. IID Energy- PV Solutions Rebate Program

    Broader source: Energy.gov [DOE]

    IID accepted applications for the 2015 PV Solutions Program from Jan. 3, 2015 – Jan. 31, 2015. Winners were determined via lottery. The program is now closed for the remainder of 2015, but another...

  4. SolSolution | Open Energy Information

    Open Energy Info (EERE)

    Boston Area Sector: Solar Year Founded: 2007 Phone Number: 805-813-4418 Website: www.sol-solution.org Coordinates: 42.363951, -71.10122 Show Map Loading map......

  5. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (both Los Alamos, NM); Delhaize, Emmanuel (both Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-11-13

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  6. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (Los Alamos, NM); Delhaize, Emmanuel (Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-01-01

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  7. Prime BioSolutions | Open Energy Information

    Open Energy Info (EERE)

    search Name: Prime BioSolutions Place: Omaha, Nebraska Zip: 68137 Product: Ethanol and biogas producer using the closed-loop system. Coordinates: 33.180954, -94.743294 Show Map...

  8. Missing solution in a Cornell potential

    SciTech Connect (OSTI)

    Castro, L.B.; Castro, A.S. de

    2013-11-15

    Missing bound-state solutions for fermions in the background of a Cornell potential consisting of a mixed scalarvectorpseudoscalar coupling is examined. Charge-conjugation operation, degeneracy and localization are discussed. -- Highlights: The Dirac equation with scalarvectorpseudoscalar Cornell potential is investigated. The isolated solution from the SturmLiouville problem is found. Charge-conjugation operation, degeneracy and localization are discussed.

  9. SEPARATION OF SCANDIUM FROM AQUEOUS SOLUTIONS

    DOE Patents [OSTI]

    Peppard, D.F.; Nachtman, E.S.

    1958-02-25

    This patent relates to a process for the separation of scandium from yttrium, thorium, and trivalent rare earths and with their separation from each other. It has been found that scandium and yttrium can be separated from trivalent rare earths in acidic solution, for example, a solution 6 M in HCl, by contacting with tributyl phosphate, whereupon the scandum is preferentially extracted into the organic phase, leaving the yttrium and trivalent rare earths in the aqueous phase.

  10. Solution dewatering with concomitant ion removal

    DOE Patents [OSTI]

    Peterson, Eric S.; Marshall, Douglas W.; Stone, Mark L.

    2003-08-05

    One of the biggest needs in the separations and waste handling and reduction area is a method for dewatering ion-containing solutions. Unexpectedly, it has been found that phosphazene polymers can discriminate between water and metal ions, allowing water to pass through the membrane while retaining the ions. This unexpected result, along with the inherent chemical and thermal stability of the phosphazene polymers, yields a powerful tool for separating and dewatering metal-ion-containing solutions.

  11. Marchetti New CEO of Washington TRU Solutions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For Immediate Release Marchetti New CEO of Washington TRU Solutions CARLSBAD, N.M., July 31, 2003 - Stephen Marchetti, Executive Vice President of Operations for the Energy and Environment unit of Washington Group International, has been chosen to replace Pres Rahe as Chairman and CEO of Washington TRU Solutions LLC (WTS). WTS, the prime contractor for the U.S. Department of Energy (DOE) at the Waste Isolation Pilot Plant (WIPP) near Carlsbad, NM, is responsible for cleanup and disposal of the

  12. Better Buildings Residential Program Solution Center Demonstration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Webinar Better Buildings Residential Program Solution Center Demonstration Amanda Chiu: My name is Amanda Chiu, and I'm with Energetics, Incorporated, on behalf of the U.S. Department of Energy (DOE) Better Buildings Residential Program. Thank you for joining us today, and welcome to a demonstration of the Better Buildings Residential Program's Solution Center. We have with us today Danielle Byrnett with the U.S. Department of Energy. Danielle is the supervisor for the Better Buildings

  13. GSA Solutions for Federally Recognized Tribes

    Office of Environmental Management (EM)

    Service U.S. General Services Administration GSA Solutions for Federally- Recognized Tribes Federal Acquisition Service U.S. General Services Administration 2 Overview  Customer Service Office Alaska  Support to Federally-Recognized Tribes  Additional Resources  Questions Federal Acquisition Service U.S. General Services Administration 3 GSA - Our Mission GSA's mission is to use expertise to provide innovative solutions for our customers in support of their missions and by so doing

  14. Sodium Hydroxide Extraction From Caustic Leaching Solutions

    SciTech Connect (OSTI)

    Lumetta, Gregg J.; Garza, Priscilla A.; Levitskaia, Tatiana G.; Brown, Gilbert M.

    2002-09-18

    This report describes experiments conducted to demonstrate the proof-of-principle of a method to recover NaOH from Hanford tank sludge leaching solutions. Aqueous solutions generated from leaching actual Hanford tank waste solids were used. The process involves neutralization of a lipophilic weak acid (t-octylphenol was used in these experiments) by reaction with NaOH in the aqueous phase. This results in the transfer of Na into the organic phase. Contacting with water reverses this process, reprotonating the lipophilic weak acid and transferring Na back into the aqueous phase as NaOH. The work described here confirms the potential application of solvent extraction to recover and recycle NaOH from solutions generated by leaching Hanford tank sludges. Solutions obtained by leaching sludges from tanks S-110 and T-110 were used in this work. It was demonstrated that Na+ is transferred from caustic leaching solution to the organic phase when contacted with t-octylphenol solutions. This was accompanied by a concomitant decrease in the aqueous-phase hydroxide ion concentration. Seventy to 80 % of the extracted Na was recovered by 3 to 4 sequential contacts of the organic phase with water. Cesium was co-extracted by the procedure, but Al and Cr remained in the feed stream.

  15. Clean Energy Solutions Centers Fact Sheet | Department of Energy

    Office of Environmental Management (EM)

    Clean Energy Solutions Centers Fact Sheet Clean Energy Solutions Centers Fact Sheet A fact sheet describing the mission of the Clean Energy Solution Center. PDF icon Clean Energy Solutions Centers Fact Sheet More Documents & Publications Clean-Energy-Solutions-Centers-Fact-Sheet.pdf Clean Energy Ministerial Press Fact Sheet SLED-Fact-Sheet.pdf

  16. Integrated two-stage coal liquefaction process

    DOE Patents [OSTI]

    Bronfenbrenner, James C. (Allentown, PA); Skinner, Ronald W. (Allentown, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01

    This invention relates to an improved two-stage process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal.

  17. Whole Algae Hydrothermal Liquefaction Technology Pathway (Technical...

    Office of Scientific and Technical Information (OSTI)

    (NREL), Golden, CO. Sponsoring Org: USDOE Office of Energy Efficiency and Renewable Energy Biomass Program Country of Publication: United States Language: English Subject: 09...

  18. Coal liquefaction model compounds. Progress report

    SciTech Connect (OSTI)

    Gajewski, J.J.; Gilbert, K.E.

    1992-12-31

    This progress report is divided into sections dealing with tetralin pyrolysis, chroman pyrolysis, solvent effects on reactions, pi conjugated biradical, and molecular mechanics of organometallic systems. Proposals are given as well as current progress.

  19. Energy Department Authorizes Sabine Pass Liquefaction's Expansion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Sabine Pass LNG Terminal in Cameron Parish, Louisiana is authorized to export additional volumes of LNG up to the equivalent of 1.38 billion standard cubic feet per day (Bcfd) ...

  20. Solvolytic liquefaction of wood under mild conditions

    SciTech Connect (OSTI)

    Yu, S.M.

    1982-04-01

    Conversion of wood to liquid products requires cleavage of bonds which crosslink the wood structure. This study examines a low-severity wood solubilization process utilizing a solvent medium consisting of a small amount of sulfuric acid and a potentially wood-derivable alcohol. In one half hour of reaction time at 250/sup 0/C under 15 psia starting nitrogen pressure, over 95% of the wood (maf) was rendered acetone-soluble. The product is a soft, black, bitumen-like solid at room temperature but readily softens at 140/sup 0/C. Between 25 and 50% of the original wood oxygen, depending on alcohol used, was removed as water. Approximately 2 to 17% of the alcohols were retained in the product. Gel permeation chromatography showed that the product's median molecular weight is around 300. Based on experimental and literature results, a mechanism for wood solubilization is proposed. This involves protonation of the etheric oxygen atoms, leading to subsequent bond scission to form carbonium ions which are stabilized by solvent alkoxylation. At severe conditions, polymerization and condensation reactions result in acetone-insoluble materials.