National Library of Energy BETA

Sample records for lime kiln alumina

  1. Wood Residues as Fuel Source for Lime Kilns 

    E-Print Network [OSTI]

    Azarniouch, M. K.; Philp, R. J.

    1984-01-01

    One of the main obstacles to total energy self sufficiency of kraft mills appears to be the fossil fuel requirements of the lime kilns. If an economical technology can be developed which allows fossil fuel to be replaced in whole or in part by wood...

  2. Design of Refractory Linings for Balanced Energy Efficiency, Uptime, and Capacity in Lime Kilns

    SciTech Connect (OSTI)

    Gorog, John Peter; Hemrick, James Gordon; Walker, Harold; Leary, William R; Ellis, Murray

    2014-01-01

    The rotary kilns used by the pulp and paper industry to regenerate lime in the Kraft process are very energy intensive. Throughout the 90 s, in response to increasing fuel prices, the industry used back up insulation in conjunction with the high alumina brick used to line the burning zones of their kilns. While this improved energy efficiency, the practice of installing insulating brick behind the working lining increased the inner wall temperatures. In the worst case, due to the increased temperatures, rapid brick failures occurred causing unscheduled outages and expensive repairs. Despite these issues, for the most part, the industry continued to use insulating refractory linings in that the energy savings were large enough to offset any increase in the cost of maintaining the refractory lining. Due to the dramatic decline in the price of natural gas in some areas combined with mounting pressures to increasing production of existing assets, over the last decade, many mills are focusing more on increasing the uptime of their kilns as opposed to energy savings. To this end, a growing number of mills are using basic (magnesia based) brick instead of high alumina brick to line the burning zone of the kiln since the lime mud does not react with these bricks at the operating temperatures of the burning zone of the kiln. In the extreme case, a few mills have chosen to install basic brick in the front end of the kiln running a length equivalent to 10 diameters. While the use of basic brick can increase the uptime of the kiln and reduce the cost to maintain the refractory lining, it does dramatically increase the heat losses resulting from the increased operating temperatures of the shell. Also, over long periods of time operating at these high temperatures, damage can occur in the shell. There are tradeoffs between energy efficiency, capacity and uptime. When fuel prices are very high, it makes sense to insulate the lining. When fuel prices are lower, trading some thermal efficiency for increased uptime and capacity seems reasonable. This paper considers a number of refractory linings in an effort to develop optimized operating strategies that balance these factors. In addition to considering a range of refractory materials, the paper examines other factors such as the chain area, discharge dams and other operating variables that impact the service life of the refractory lining. The paper provides recommendations that will help mill personnel develop a strategy to select a refractory lining that is optimized for their specific situation.

  3. Cement kiln flue dust as a source of lime and potassium in four East Texas soils 

    E-Print Network [OSTI]

    Poole, Warren David

    1975-01-01

    (18) a 5. 3 (84) a 4. 8 (76) a 4. 2 (66) a 3. 8 (61) a 5. 2 (82) a 4. 1 (64) a 5. 0 (80) a *Duncan's Multiple Range Test. ? = . 05. Differences in yield due to rate of applied lime material followed by the same letter are not significantly...CEMENT KILN FLUE DUST AS A SOURCE OF LIME AND POTASSIUM IN FOUR EAST TEXAS SOILS A Thesis by WARREN DAVID POOLE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER...

  4. Control of Lime Kiln Heat Balance is Key to Reduced Fuel Consumption 

    E-Print Network [OSTI]

    Kramm, D. J.

    1982-01-01

    kiln, it is possible to save hundreds of thousands of dollars in fuel annually by paying attention to the proper operating details....

  5. A cement kiln flue-dust evaluated as a soil liming material 

    E-Print Network [OSTI]

    Stacha, Raimund

    1973-01-01

    production. The present lime study includes several of the predominate acid soil types in Texas. They should aid in furnishing soil testing laboratories with information which would facilitate better lime recommendations to Texas farmers as well... not determined. The present studies which include several of the predominate acid soil types in Texas should evaluate the usefulness of this local material as well as to further lime research in Texas to benefit soil test recommendations. 14 MATERIALS...

  6. Use of RDF as a kiln fuel. Final report

    SciTech Connect (OSTI)

    1980-10-01

    Refuse derived fuel (RDF) has been experimented with and/or proposed for use in kilns for the production of portland cement, lime, and expanded shale (a form of lightweight aggregate). Technological issues affecting the use of RDF in kilns are reviewed as are the results of trials in which RDF has been used as a kiln fuel. Three future research/demonstration projects for addressing the major unresolved issues are discussed. These projects are: a lime plant trial; a trial in a pre-calcining furnace; and an extended trial in a cement kiln.

  7. Solar heated rotary kiln

    DOE Patents [OSTI]

    Shell, Pamela K. (Tracy, CA)

    1984-01-01

    A solar heated rotary kiln utilized for decomposition of materials, such as zinc sulfate. The rotary kiln has an open end and is enclosed in a sealed container having a window positioned for directing solar energy into the open end of the kiln. The material to be decomposed is directed through the container into the kiln by a feed tube. The container is also provided with an outlet for exhaust gases and an outlet for spent solids, and rests on a tiltable base. The window may be cooled and kept clear of debris by coolant gases.

  8. Kilns and Firing Structures

    E-Print Network [OSTI]

    Nicholson, Paul

    2010-01-01

    obviating the problem of fly ash is to use a downdraft kiln.surface might be damaged by fly ash, or blackened by sootthe reaction between the “fly ash” (literally, particles of

  9. Rotary kiln seal

    DOE Patents [OSTI]

    Drexler, Robert L. (Idaho Falls, ID)

    1992-01-01

    A rotary seal used to prevent the escape of contaminates from a rotating kiln incinerator. The rotating seal combines a rotating disc plate which is attached to the rotating kiln shell and four sets of non-rotating carbon seal bars housed in a primary and secondary housing and which rub on the sides of the disc. A seal air system is used to create a positive pressure in a chamber between the primary and secondary seals to create a positive air flow into the contaminated gas chamber. The seal air system also employs an air inlet located between the secondary and tertiary seals to further insure that no contaminates pass the seal and enter the external environment and to provide makeup air for the air which flows into the contaminated gas chamber. The pressure exerted by the seal bars on the rotating disc is controlled by means of a preload spring. The seal is capable of operating in a thermally changing environment where the both radial expansion and axial movement of the rotating kiln do not result in the failure of the seal.

  10. Solar-heated rotary kiln

    DOE Patents [OSTI]

    Shell, P.K.

    1982-04-14

    A solar heated rotary kiln utilized for decomposition of materials, such as zinc sulfate is disclosed. The rotary kiln has an open end and is enclosed in a sealed container having a window positioned for directing solar energy into the open end of the kiln. The material to be decomposed is directed through the container into the kiln by a feed tube. The container is also provided with an outlet for exhaust gases and an outlet for spent solids, and rests on a tiltable base. The window may be cooled and kept clear of debris by coolant gases.

  11. Process for the recovery of alumina from fly ash

    DOE Patents [OSTI]

    Murtha, M.J.

    1983-08-09

    An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

  12. Analysis of Energy Savings by Painting a Rotary Kiln Surface 

    E-Print Network [OSTI]

    Li, X.; Wang, T.; Tonti, R. T.; Edwards, L.

    2007-01-01

    Rotary Kilns has been widely used for processing minerals, producing cement, calcining petroleum cokes, or drying biomass and wastes. Most of rotary kilns consume energy intensively. Therefore it is desired to assess the thermal losses from the kiln...

  13. Influence of the composition of cement kiln dust on its interaction with fly ash and slag

    SciTech Connect (OSTI)

    Chaunsali, Piyush; Peethamparan, Sulapha

    2013-12-15

    Cement kiln dust (CKD), a by-product of the cement industry, contains significant amounts of alkali, free lime, chloride and sulfate. Wide variation reported in the chemical composition of CKDs limits their potential application as a sustainable binder component in concrete. In the current study, the performance of two different CKDs as components in a novel binder is evaluated. Several binders are developed by blending CKDs with fly ash or slag. Binders with 70% CKD were prepared at a water-to-binder ratio of 0.4, and heat-cured at 75 °C to accelerate the strength development. The hydration progress was monitored using X-ray diffraction, and morphological examination was performed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Ettringite and calcium aluminosilicate hydrate (C-A-S-H) were identified as the main hydration products in the hardened binder system. Strength development of CKD-based binder was found to be significantly influenced by its free lime and sulfate contents. -- Highlights: •Interaction of cement kiln dust with fly ash and slag was explored. •CKD with higher free lime and sulfate content increased the strength of binder. •C-S-H like reaction gel with fibrillar morphology is observed in CKD-based binders.

  14. Energy Efficient Microwave Hybrid Processing of Lime for Cement, Steel, and Glass Industries

    SciTech Connect (OSTI)

    Fall, Morgana L; Yakovlev, Vadim; Sahi, Catherine; Baranova, Inessa; Bowers, Johnney G; Esquenazi , Gibran L

    2012-02-10

    In this study, the microwave materials interactions were studied through dielectric property measurements, process modeling, and lab scale microwave hybrid calcination tests. Characterization and analysis were performed to evaluate material reactions and energy usage. Processing parameters for laboratory scale and larger scale calcining experiments were developed for MAT limestone calcination. Early stage equipment design concepts were developed, with a focus on microwave post heating treatment. The retrofitting of existing rotary calcine equipment in the lime industry was assessed and found to be feasible. Ceralink sought to address some of the major barriers to the uptake of MAT identified as the need for (1) team approach with end users, technology partners, and equipment manufacturers, (2) modeling that incorporates kiln materials and variations to the design of industrial microwave equipment. This project has furthered the commercialization effort of MAT by working closely with an industrial lime manufacturer to educate them regarding MAT, identifying equipment manufacturer to supply microwave equipment, and developing a sophisticated MAT modeling with WPI, the university partner. MAT was shown to enhance calcining through lower energy consumption and faster reaction rates compared to conventional processing. Laboratory testing concluded that a 23% reduction in energy was possible for calcining small batches (5kg). Scale-up testing indicated that the energy savings increased as a function of load size and 36% energy savings was demonstrated (22 kg). A sophisticated model was developed which combines simultaneous microwave and conventional heating. Continued development of this modeling software could be used for larger scale calcining simulations, which would be a beneficial low-cost tool for exploring equipment design prior to actual building. Based on these findings, estimates for production scale MAT calcining benefits were calculated, assuming uptake of MAT in the US lime industry. This estimate showed that 7.3 TBTU/year could be saved, with reduction of 270 MMlbs of CO2 emissions, and $29 MM/year in economic savings. Taking into account estimates for MAT implementation in the US cement industry, an additional 39 TBTU/year, 3 Blbs of CO2 and $155 MM/year could be saved. One of the main remaining barriers to commercialization of MAT for the lime and cement industries is the sheer size of production. Through this project, it was realized that a production size MAT rotary calciner was not feasible, and a different approach was adapted. The concept of a microwave post heat section located in the upper portion of the cooler was devised and appears to be a more realistic approach for MAT implementation. Commercialization of this technology will require (1) continued pilot scale calcining demonstrations, (2) involvement of lime kiln companies, and (3) involvement of an industrial microwave equipment provider. An initial design concept for a MAT post-heat treatment section was conceived as a retrofit into the cooler sections of existing lime rotary calciners with a 1.4 year payback. Retrofitting will help spur implementation of this technology, as the capital investment will be minimal for enhancing the efficiency of current rotary lime kilns. Retrofits would likely be attractive to lime manufacturers, as the purchase of a new lime kiln is on the order of a $30 million dollar investment, where as a MAT retrofit is estimated on the order of $1 million. The path for commercialization lies in partnering with existing lime kiln companies, who will be able to implement the microwave post heat sections in existing and new build kilns. A microwave equipment provider has been identified, who would make up part of the continued development and commercialization team.

  15. Coal desulfurization in a rotary kiln combustor

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.

    1992-09-11

    The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

  16. Use of hazardous waste in cement kilns backed

    SciTech Connect (OSTI)

    Krieger, J.

    1993-07-19

    Cement kiln operators who are making use of hazardous waste as a partial substitute for fossil fuel now have a better engineering foundation for determining what is going on in the kilns and how to optimize their operations. A just-released study by a scientific advisory board of experts commissioned by the Cement Kiln Recycling Coalition (CKRC) in Washington, DC, has provided an in-depth look, at such operations and finds the practice to be a fundamentally sound' technology. Long residence times and high temperatures in cement kilns maximize the combustion efficiency for waste-derived fuels, according to the study report. The scientific advisory board notes that all organic compounds can be destroyed in a kiln at 99.9999% efficiency. Also, the behavior of metals in cement kilns can be readily measured, predicted, and controlled. Cement kilns are extremely efficient in reducing metals emissions.

  17. Microporous alumina ceramic membranes

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI); Sheng, Guangyao (Madison, WI)

    1993-01-01

    Several methods are disclosed for the preparation microporous alumina ceramic membranes. For the first time, porous alumina membranes are made which have mean pore sizes less than 100 Angstroms and substantially no pores larger than that size. The methods are based on improved sol-gel techniques.

  18. Microporous alumina ceramic membranes

    DOE Patents [OSTI]

    Anderson, M.A.; Guangyao Sheng.

    1993-05-04

    Several methods are disclosed for the preparation microporous alumina ceramic membranes. For the first time, porous alumina membranes are made which have mean pore sizes less than 100 Angstroms and substantially no pores larger than that size. The methods are based on improved sol-gel techniques.

  19. Reuse of activated alumina

    SciTech Connect (OSTI)

    Hobensack, J.E. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States)

    1991-12-31

    Activated alumina is used as a trapping media to remove trace quantities of UF{sub 6} from process vent streams. The current uranium recovery method employs concentrated nitric acid which destroys the alumina pellets and forms a sludge which is a storage and disposal problem. A recently developed technique using a distilled water rinse followed by three dilute acid rinses removes on average 97% of the uranium, and leaves the pellets intact with crush strength and surface area values comparable with new material. Trapping tests confirm the effectiveness of the recycled alumina as UF{sub 6} trapping media.

  20. HLB Progress on Tahiti acid lime grafted onto eight rootstocks

    E-Print Network [OSTI]

    Stuchi, E. S.; Reiff, E. T.; Sempionato, O. R.; Parolin, L. G.; Bassanezi, R. B.

    2014-01-01

    Progress on Tahiti acid lime grafted onto eight rootstocksthe main Tahiti (Persian) lime producer in Brazil with 65%the performance of Tahiti acid lime grafted onto eight

  1. Effects of Lime and Carbonate of Lime on Acid Phosphate. 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1917-01-01

    question whether part of the readion does not take place in the filter paper, when the fertilizer is being washed with water to re- move the water-soluble phosphoric acid. To test this, we mixed carbonate of lime with acid phosphate and determined... EXPERIMENTS. We made some pot experiments to test the effect of lime on acid phosphate, but we are not altogether ea'tisfied with the mgy some of these crops grew. Details: Soils 3653, 4643, 4580, 4596, 4581, 4589, 4591. Additions : Ac 1 gram acid...

  2. Community Geothermal Technology Program: Experimental lumber drying kiln. Final report

    SciTech Connect (OSTI)

    Leaman, D.; Irwin, B.

    1989-10-01

    Goals were to demonstrate feasibility of using the geothermal waste effluent from the HGP-A well as a heat source for a kiln operation to dry hardwoods, develop drying schedules, and develop automatic systems to monitor/control the geothermally heated lumber dry kiln systems. The feasibility was demonstrated. Lumber was dried in periods of 2 to 6 weeks in the kiln, compared to 18 months air drying and 6--8 weeks using a dehumidified chamber. Larger, plate-type heat exchangers between the primary fluid and water circulation systems may enable the kiln to reach the planned temperatures (180--185 F). However, the King Koa partnership cannot any longer pursue the concept of geothermal lumber kilns.

  3. Sulfate induced heave in lime stabilized soil 

    E-Print Network [OSTI]

    Bredenkamp, Sanet

    1994-01-01

    The addition of hydrated lime to clay soils is one of the most common methods of soil stabilization. However, when sulfates are present in the soil, the calcium in the lime reacts with the sulfates to form ettringite, an ...

  4. Incinerators and cement kilns face off

    SciTech Connect (OSTI)

    Kim, I.

    1994-04-01

    For the past few years, US incinerators have been at odds with thermal waste processors such as cement kilns. Originally, there was enough room in the industrial waste treatment market for both types of treatment. As waste generators turned to pollution prevention and onsite treatment, however, the volume of waste decreased and its composition changed. Now, each sees the other crowding it out of a tightening market, and the fight between them is growing increasingly bitter. At the center of this battle are the products of alternative thermal processes--for cement kilns, the dust formed after processing, and for other processes, a variety of materials, many of which can be used for construction. Currently, these materials are exempted from regulation under the US Resource Conservation and Recovery Act (RCRA). In addition, the alternative processes offer generators a significant cost advantage over incineration. The question that US regulators are now grappling with is whether these materials are safe enough to justify this preferential treatment. So far, the answer seems to be a qualified yes. The paper discusses these issues.

  5. Analysis of Energy-Efficiency Opportunities for the Pulp and Paper Industry in China

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01

    chemical reactions in the lime kiln and wastewater treatmentliquor concentration Lime kiln modifications Mechanicalblack liquor concentration, and lime kiln modifications, the

  6. Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry

    E-Print Network [OSTI]

    Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

    2000-01-01

    M. 1999. “Gulf States Improves Lime Kiln Performance with1998. Lewko, L. 1996. "Lime Kiln Upgrade Project at Prince27 Lime kiln

  7. Alumina Technology Roadmap

    SciTech Connect (OSTI)

    2002-02-01

    The Alumina Technology Roadmap outlines a comprehensive long-term research and development plan that defines the industry's collective future and establishes a clear pathway forward. It emphasizes twelve high-priority R&D areas deemed most significant in addressing the strategic goals. (PDF 316 KB).

  8. Fly ash chemical classification based on lime

    SciTech Connect (OSTI)

    Fox, J.

    2007-07-01

    Typically, total lime content (CaO) of fly ash is shown in fly ash reports, but its significance is not addressed in US specifications. For certain applications a low lime ash is preferred. When a class C fly ash must be cementitious, lime content above 20% is required. A ternary S-A-C phase diagram pilot is given showing the location of fly ash compositions by coal rank and source in North America. Fly ashes from subbituminous coal from the Powder River Basin usually contain sufficient lime to be cementitious but blending with other coals may result in calcium being present in phases other than tricalcium aluminate. 9 refs., 1 fig.

  9. ITP Aluminum: Alumina Technology Roadmap

    Broader source: Energy.gov [DOE]

    The Alumina Technology Roadmap outlines a comprehensive long-term research and development plan that defines the industry’s collective future and establishes a clear pathway forward.

  10. Controlling Mechanical Properties of Porous Mullite/Alumina Mixtures Via Precursor-Derived Alumina

    E-Print Network [OSTI]

    Zok, Frank

    Controlling Mechanical Properties of Porous Mullite/Alumina Mixtures Via Precursor-Derived Alumina- ity of a precursor-derived alumina (PDA) in controlling both the modulus and the toughness of mullite on porous mullite/alumina compacts with varying amounts of precursor-derived alumina (PDA) and com- parisons

  11. Arsenic removal in conjunction with lime softening

    DOE Patents [OSTI]

    Khandaker, Nadim R.; Brady, Patrick V.; Teter, David M.; Krumhansl, James L.

    2004-10-12

    A method for removing dissolved arsenic from an aqueous medium comprising adding lime to the aqueous medium, and adding one or more sources of divalent metal ions other than calcium and magnesium to the aqueous medium, whereby dissolved arsenic in the aqueous medium is reduced to a lower level than possible if only the step of adding lime were performed. Also a composition of matter for removing dissolved arsenic from an aqueous medium comprising lime and one or more sources of divalent copper and/or zinc metal ions.

  12. Waste tires as auxiliary fuel for cement kilns

    SciTech Connect (OSTI)

    Dodds, J.

    1987-01-01

    The subject I have been asked to speak about is the utilization of scrap tires as an auxiliary fuel for cement kilns. My experience with scrap tires began five years ago when we performed a technical and economic evaluation for tire pyrolysis. I work for the Idaho National Engineering Laboratory which is supported by the Department of Energy. My interest in scrap tires continued; in 1984 the Department of Energy and the Portland Cement Association jointly sponsored a conference on the utilization of scrap tires in cement kilns. Most of my remarks today are based upon that conference along with some current information in the US. Mr. Sladek requested that I speak on the combustion process, the progress to date, and the factors that impede or encourage implementation of using scrap tires in cement kilns. For discussion purposes it would help if we had a common understanding of the cement manufacturing process. Cement is made by heating a mixture of finely ground limestone and silica from clay or sand to about 1450/degree/C in a large rotating kiln. The heat causes the limestone to decarbonate and subsequently react with the silica to form calcium silicates. 5 figs.

  13. The use of scrap tires in rotary cement kilns

    SciTech Connect (OSTI)

    Blumenthal, M.

    1996-12-31

    The use of scrap tires as a supplemental fuel in the United States Portland cement industry has increased significantly in the past six years. In 1990, there were two kilns using tire-derived fuel (TDF), today 30 kilns use TDF. The outlook for continued and expanded use of TDF in the U.S. cement industry should be considered favorable, with 15 kilns conducting tests to determine TDF`s applicability or in the permitting process. The Council`s estimates are that by the end of 1996, the cement industry could be consuming some 75-100 million of the 253 million annually generated scrap tires in the United States. This level of TDF usage will make the cement industry the largest market segments for scrap tires in the United States. While the long-term outlook is at present positive, there are a series of factors that have, and will likely continue to adversely impact the near-term usage of TDF. These issues, as well as the factors that are likely to positively impact the cement kiln TDF market are the subject of this presentation.

  14. Evaluation of cement kiln laboratories testing hazardous waste derived fuels

    SciTech Connect (OSTI)

    Nichols, R.E.

    1998-12-31

    Cement kiln operators wishing to burn hazardous waste derived fuels in their kilns must submit applications for Resource Conservation Recovery Act permits. One component of each permit application is a site-specific Waste Analysis Plan. These Plans describe the facilities` sampling and analysis procedures for hazardous waste derived fuels prior to receipt and burn. The Environmental Protection Agency has conducted on-site evaluations of several cement kiln facilities that were under consideration for Resource Conservation Recovery Act permits. The purpose of these evaluations was to determine if the on-site sampling and laboratory operations at each facility complied with their site-specific Waste Analysis Plans. These evaluations covered sampling, laboratory, and recordkeeping procedures. Although all the evaluated facilities were generally competent, the results of those evaluations revealed opportunities for improvement at each facility. Many findings were noted for more than one facility. This paper will discuss these findings, particularly those shared by several facilities (specific facilities will not be identified). Among the findings to be discussed are the ways that oxygen bombs were scrubbed and rinsed, the analytical quality control used, Burn Tank sampling, and the analysis of pH in hazardous waste derived fuels.

  15. Method and system including a double rotary kiln pyrolysis or gasification of waste material

    DOE Patents [OSTI]

    McIntosh, M.J.; Arzoumanidis, G.G.

    1997-09-02

    A method is described for destructively distilling an organic material in particulate form wherein the particulates are introduced through an inlet into one end of an inner rotating kiln ganged to and coaxial with an outer rotating kiln. The inner and outer kilns define a cylindrical annular space with the inlet being positioned in registry with the axis of rotation of the ganged kilns. During operation, the temperature of the wall of the inner rotary kiln at the inlet is not less than about 500 C to heat the particulate material to a temperature in the range of from about 200 C to about 900 C in a pyrolyzing atmosphere to reduce the particulate material as it moves from the one end toward the other end. The reduced particulates including char are transferred to the annular space between the inner and the outer rotating kilns near the other end of the inner rotating kiln and moved longitudinally in the annular space from near the other end toward the one end in the presence of oxygen to combust the char at an elevated temperature to produce a waste material including ash. Also, heat is provided which is transferred to the inner kiln. The waste material including ash leaves the outer rotating kiln near the one end and the pyrolysis vapor leaves through the particulate material inlet. 5 figs.

  16. Method and system including a double rotary kiln pyrolysis or gasification of waste material

    DOE Patents [OSTI]

    McIntosh, Michael J. (Bolingbrook, IL); Arzoumanidis, Gregory G. (Naperville, IL)

    1997-01-01

    A method of destructively distilling an organic material in particulate form wherein the particulates are introduced through an inlet into one end of an inner rotating kiln ganged to and coaxial with an outer rotating kiln. The inner and outer kilns define a cylindrical annular space with the inlet being positioned in registry with the axis of rotation of the ganged kilns. During operation, the temperature of the wall of the inner rotary kiln at the inlet is not less than about 500.degree. C. to heat the particulate material to a temperature in the range of from about 200.degree. C. to about 900.degree. C. in a pyrolyzing atmosphere to reduce the particulate material as it moves from the one end toward the other end. The reduced particulates including char are transferred to the annular space between the inner and the outer rotating kilns near the other end of the inner rotating kiln and moved longitudinally in the annular space from near the other end toward the one end in the presence of oxygen to combust the char at an elevated temperature to produce a waste material including ash. Also, heat is provided which is transferred to the inner kiln. The waste material including ash leaves the outer rotating kiln near the one end and the pyrolysis vapor leaves through the particulate material inlet.

  17. Kiln for hot-pressing compacts in a continuous manner

    DOE Patents [OSTI]

    Reynolds, Jr., Carl D. (Clinton, TN)

    1985-01-01

    The present invention is directed to a hot pressing furnace or kiln which is capable of preheating, hot pressing, and cooling a plurality of articles in a sequential and continuous manner. The hot pressing furnace of the present invention comprises an elongated, horizontally disposed furnace capable of holding a plurality of displaceable pusher plates each supporting a die body loaded with refractory or ceramic material to be hot pressed. Each of these plates and the die body supported thereby is sequentially pushed through the preheating zone, a temperature stabilizing and a hot pressing zone, and a cooling zone so as to provide a continuous hot-pressing operation of a plurality of articles.

  18. Method and apparatus for maximizing throughput of indirectly heated rotary kilns

    DOE Patents [OSTI]

    Coates, Ralph L; Smoot, L. Douglas; Hatfield, Kent E

    2012-10-30

    An apparatus and method for achieving improved throughput capacity of indirectly heated rotary kilns used to produce pyrolysis products such as shale oils or coal oils that are susceptible to decomposition by high kiln wall temperatures is disclosed. High throughput is achieved by firing the kiln such that optimum wall temperatures are maintained beginning at the point where the materials enter the heating section of the kiln and extending to the point where the materials leave the heated section. Multiple high velocity burners are arranged such that combustion products directly impact on the area of the kiln wall covered internally by the solid material being heated. Firing rates for the burners are controlled to maintain optimum wall temperatures.

  19. Effects of lime rate, lime ECCE, and B rate on rose clover and coastal bermudagrass dry matter yields 

    E-Print Network [OSTI]

    Villavicencio Batres, Rodolfo

    1990-01-01

    that soil pH was only affected by lime rate at the soil surface after 5 months, indicates that CaCO3 andior the dissolution products of CaCO3 did not readily leach through the soil profile when the lime was surface applied. Lime ECCE Effects Soil pH (0...EFFECTS OF LIME RATE, LIME ECCE, AND B RATE ON ROSE CLOVER AND COASTAL BERMUDAGRASS DRY MATTER YIELDS A Thesis by RODOLFO VILLAVICENCIO BATRES Submitted to the Office of Graduate Studies of Texas A8 M University in partial fulfiliment...

  20. An assessment of potential environmental impacts of cement kiln dust produced in kilns co-fired with hazardous waste fuels

    SciTech Connect (OSTI)

    Goad, P.T.; Millner, G.C.; Nye, A.C.

    1998-12-31

    The Keystone Cement Company (Keystone), located in Bath, Pennsylvania, produces cement in two kilns that are co-fired with hazardous waste-derived fuels. Beginning in the late 1970`s Keystone began storing cement kiln dust (CKD) in an aboveground storage pile located on company property adjacent to the cement kilns. Storm water runoff from the CKD pile is channeled into a storm water settling pond which in turn discharges into Monocacy Creek, a stream running along the eastern property boundary. Monocacy Creek sustains a thriving trout fishery and is routinely fished during the open recreational fishing season in pennsylvania. The CKD pile has a surface area of approximately 12 acres, with an average height of approximately 35 feet. The southern edge of the pile is contiguous with an adjacent company-owned field in which field corn is grown for cattle feed. Some of the corn on the edges of the field is actually grown in direct contact with CKD that comprises the edge of the storage pile. The CKD pile is located approximately 150 yards to the west of Monocacy Creek. In 1995--1996 water, sediment and fish (trout) samples were obtained from Monocacy Creek sampling stations upstream and downstream of the point of discharge of storm water runoff from the CKD pile. In addition, corn samples were obtained from the field contiguous with the CKD pile and from a control field located distant to the site. The sediment, water, fish, and corn samples were analyzed for various chemicals previously identified as chemicals of potential concern in CKD. These data indicate that chemical constituents of CKD are not contaminating surface water or sediment in the stream, and that bioaccumulation of organic chemicals and/or metals has not occurred in field corn grown in direct contact with undiluted CKD, or in fish living in the waters that receive CKD pile runoff.

  1. Method for preparing Pb-. beta. ''-alumina ceramic

    DOE Patents [OSTI]

    Hellstrom, E.E.

    1984-08-30

    A process is disclosed for preparing impermeable, polycrystalline samples of Pb-..beta..''-alumina ceramic from Na-..beta..''-alumina ceramic by ion exchange. The process comprises two steps. The first step is a high-temperature vapor phase exchange of Na by K, followed by substitution of Pb for K by immersing the sample in a molten Pb salt bath. The result is a polycrystalline Pb-..beta..''-alumina ceramic that is substantially crack-free.

  2. Synthesis of high porosity, monolithic alumina aerogels

    SciTech Connect (OSTI)

    Poco, J F; Satcher, J H; Hrubesh, L W

    2000-09-20

    Many non-silica aerogels are notably weak and fragile in monolithic form. Particularly, few monolithic aerogels with densities less than 50kg/m3 have any significant strength. It is especially difficult to prepare uncracked monoliths of pure alumina aerogels that are robust and moisture stable. In this paper, we discuss the synthesis of strong, stable, monolithic, high porosity (>98% porous) alumina aerogels, using a two-step sol-gel process. The alumina aerogels have a polycrystalline morphology that results in enhanced physical properties. Most of the measured physical properties of the alumina aerogels are superior to those for silica aerogels for equivalent densities.

  3. Coal desulfurization in a rotary kiln combustor. Final report, March 15, 1990--July 31, 1991

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.

    1992-09-11

    The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

  4. MECS 2006 - Alumina and Aluminum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    documents Manufacturing Energy and Carbon Footprint Alumina and Aluminum More Documents & Publications Alumina and Aluminum (2010 MECS) MECS 2006 - Cement MECS 2006 - Glass...

  5. Analysis of cubic and orthorhombic C3A hydration in presence of gypsum and lime

    E-Print Network [OSTI]

    Kirchheim, A. P.; Fernàndez-Altable, V.; Monteiro, P. J.; Dal Molin, D. C.; Casanova, I.

    2009-01-01

    orthorhombic C 3 A paste with no lime; no monosulfoaluminatein presence of gypsum and lime A. P. Kirchheim Æ V. Fernacubic C 3 A ? gypsum ? 10% lime ? H 2 O mixture, at 7 and 14

  6. Donald T. Clark: Early UCSC History and the Founding of the University Library

    E-Print Network [OSTI]

    Regional History Project, UCSC Library; Clark, Donald T.; Jarrell, Randall

    1993-01-01

    into being the printer for the Lime Kiln Press. He was well-later because after the Lime Kiln Press was established, these to fund a printer for the Lime Kiln Press, it certainly

  7. Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the U.S. Pulp and Paper Sector

    E-Print Network [OSTI]

    Xu, Tengfang

    2014-01-01

    black liquor evaporation Lime kiln modifications Extended black liquor evaporation Lime kiln modifications Teriary effluents ClO2 filtrate heating Lime kiln oxygen enrichement

  8. The Cowell Press and Its Legacy: 1973-2004

    E-Print Network [OSTI]

    Regional History Project, UCSC Library; Graalfs, Gregory; Reti, Irene

    2005-01-01

    Rice: Contact with The Lime Kiln Press page 158 Graalfs: Howthere for years. Graalfs: Well, Lime Kiln Press was in the61 William Everson & The Lime Kiln Press 64 Thoughts on Fine

  9. Rita Bottoms: Polyartist Librarian

    E-Print Network [OSTI]

    Bottoms, Rita; Reti, Irene; Regional History Project, UCSC Library

    2005-01-01

    William Everson and the Lime Kiln Press And the irony wasI said, “ Oh, what about Lime Kiln press? ” So I do takefor submissions for the Lime Kiln press design. If Bill had

  10. Alumina forming iron base superalloy

    DOE Patents [OSTI]

    Yamamoto, Yukinori; Muralidharan, Govindarajan; Brady, Michael P.

    2014-08-26

    An austenitic stainless steel alloy, consists essentially of, in weight percent 2.5 to 4 Al; 25 to 35 Ni; 12 to 19 Cr; at least 1, up to 4 total of at least one element selected from the group consisting of Nb and Ta; 0.5 to 3 Ti; less than 0.5 V; 0.1 to 1 of at least on element selected from the group consisting of Zr and Hf; 0.03 to 0.2 C; 0.005 to 0.1 B; and base Fe. The weight percent Fe is greater than the weight percent Ni. The alloy forms an external continuous scale including alumina, and contains coherent precipitates of .gamma.'-Ni.sub.3Al, and a stable essentially single phase FCC austenitic matrix microstructure. The austenitic matrix is essentially delta-ferrite-free and essentially BCC-phase-free.

  11. Santa Cruz and the Cowell Ranch, 1890-9641

    E-Print Network [OSTI]

    Regional History Project, UCSC Library; Cardiff, George; Calciano, Elizabeth Spedding

    1965-01-01

    tile Cardiff: Yes, cement, lime, plaster, brick -- allbasement, the foundation, is lime rock, three or four feetHe bought some additional lime quarries, lime kilns. The

  12. Study of Alumina in Austenitic Stainless Steels 

    E-Print Network [OSTI]

    Wang, Chung

    2014-12-18

    transformation through temperature, as opposed to mechanical stresses, the martensite start temperature is calculated through the Ishida model. The addition of aluminum to an austenitic stainless steel composition can alloy for the growth of alumina oxide...

  13. The effect of additives on lime dissolution rates. Final report

    SciTech Connect (OSTI)

    Khang, S.J.

    1996-07-31

    Based on the previous years` studies concerning the efficiency of SO{sub 2} removal by spray dryers with high sulfur coal flue gas, the work for year five included investigations of lime dissolution rates at different slaking conditions and with the effect of additives. The prominent additives that have significant effects on lime dissolution rates were tested with the mini pilot spray drying absorber to see their effects on spray drying desulfurization applications. The mechanisms of these additive effects along with the properties of hygroscopic additives have been discussed and incorporated into the spray drying desulfurization model ``SPRAYMOD-M.`` Slaking conditions are very important factors in producing high quality lime slurry in spray drying desulfurization processes. At optimal slaking conditions, the slaked lime particles are very fine (3-5{mu}m) and the slaked lime has high BET surface areas which are beneficial to the desulfurization. The slaked lime dissolution rate experiments in our study are designed to determine how much lime can dissolve in a unit time if the initial lime surface area is kept constant. The purpose of the dissolution rate study for different additives is to find those effective additives that can enhance lime dissolution rates and to investigate the mechanisms of the dissolution rate enhancement properties for these additives. The applications of these additives on spray drying desulfurization are to further verify the theory that dissolution rate is a rate limiting step in the whole spray drying desulfurization process as well as to test the feasibility of these additives on enhancing SO{sub 2} removal in spray dryers.

  14. Regeneration of lime from sulfates for fluidized-bed combustion

    DOE Patents [OSTI]

    Yang, Ralph T. (Middle Island, NY); Steinberg, Meyer (Huntington Station, NY)

    1980-01-01

    In a fluidized-bed combustor the evolving sulfur oxides are reacted with CaO to form calcium sulfate which is then decomposed in the presence of carbonaceous material, such as the fly ash recovered from the combustion, at temperatures of about 900.degree. to 1000.degree. C., to regenerate lime. The regenerated lime is then recycled to the fluidized bed combustor to further react with the evolving sulfur oxides. The lime regenerated in this manner is quite effective in removing the sulfur oxides.

  15. Trends in characteristics of hazardous waste-derived fuel burned for energy recovery in cement kilns

    SciTech Connect (OSTI)

    Lusk, M.G.; Campbell, C.S.

    1996-12-31

    The Cement Kiln Recycling Coalition (CKRC) is a national trade association representing virtually all the U.S. cement companies involved in the use of waste-derived fuel in the cement manufacturing process as well as those companies involved in the collection, processing, managing, and marketing of such fuel. CKRC, in conjunction with the National Association of Chemical Recyclers (NACR), completed several data collection activities over the past two years to provide the Environmental Protection Agency (EPA) and other interested parties with industry-wide trend analyses. The analyses evaluated the content of specific metals in waste fuels utilized by cement kilns, average Btu value of substitute fuels used by kilns, and provides insight into the trends of these properties. With the exception of the data collected by NACR, the study did not evaluate materials sent to hazardous waste incinerators or materials that are combusted at {open_quotes}on-site{close_quotes} facilities.

  16. Enhancement of phosphogypsum with high lime fly ash 

    E-Print Network [OSTI]

    Gregory, Chuck Alan

    1983-01-01

    ENHANCEMENT OF PHOSPHOGYPSUM WITH HIGH LIME FLY ASH A Thesis by CHUCK ALAN GREGORY Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1983 Major... Subject: Civil Engineering ENHANCEMENT OF PHOSPHOGYPSUM WITH HIGH'LIME FLY ASH A Thesis by CHUCK ALAN GREGORY Approved as to style and content by: Dr. ona d Saylak (Chairman f Committee) Dr. W. edbetter ( ember) (Member) r. Lloyd Deuel, 3...

  17. In What Form is Lime Present in Portland Cement

    E-Print Network [OSTI]

    Wright, Claude W.

    1910-01-01

    ScholarWorks | The University of Kansas Pre-1923 Dissertations and Theses Collection In What Form is Lime Present in Portland Cement 1910 by Claude W. Wright This work was digitized by the Scholarly Communications program staff in the KU Libraries...’ Center for Digital Scholarship. http://kuscholarworks.ku.edu Submitted to the School of Engineering of the University of Kansas for completion of Masters of Cheimcal Engineering. IN WHAT FORM IS LIME PRESENT IN PORTLAND CEMENT. A Dissertation...

  18. Precipitation kinetics in ultra-high lime softening 

    E-Print Network [OSTI]

    Peacock, Edward Dale

    1986-01-01

    PRECIPITATION KINETICS IN ULTRA-HIGH LIME SOFTENING A Thesis EDWARD DALE PEACOCK Submitted to the Graduate College of Texas ABM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August l986 Major... Subject: Civil Engineering PRECIPITATION KINETICS IN ULTRA-HIGH LIME SOFTENING A Thesis by EDWARD DALE PEACOCK Approved as to style and content by: Bill Batchelor (Chair of Commi e) T D. eynol s (Member) Michael T. Lo necker (Member) Donald Mc...

  19. Sorbent selection and design considerations for uranium trapping. [H-151 alumina, XF-100 alumina, F-1 alumina, sodium fluoride

    SciTech Connect (OSTI)

    Schultz, R.M.; Hobbs, W.E.; Norton, J.L.; Stephenson, M.J.

    1981-07-01

    The efficient removal of UF/sub 6/ from effluent streams can be accomplished through the selection of the best solid sorbent and the implementation of good design principles. Pressure losses, sorbent capacity, reaction kinetics, sorbent regeneration/uranium recovery requirements and the effects of other system components are the performance factors which are summarized. The commonly used uranium trapping materials highlighted are sodium fluoride, H-151 alumina, XF-100 alumina, and F-1 alumina. Sorbent selection and trap design have to be made on a case-by-case basis but the theoretical modeling studies and the evaluation of the performance factors presented can be used as a guide for other chemical trap applications.

  20. Effect of Alumina Source on the Rate of Melting Demonstrated...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Effect of Alumina Source on the Rate of Melting Demonstrated with Nuclear Waste Glass Batch Citation Details In-Document Search Title: Effect of Alumina Source on...

  1. Electrolytic Cell For Production Of Aluminum From Alumina

    DOE Patents [OSTI]

    Bradford, Donald R (Underwood, WA); Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR)

    2004-11-02

    An electrolytic cell for producing aluminum from alumina having a reservoir for collecting molten aluminum remote from the electrolysis.

  2. Steinway & Sons Upgrades Its Turn-of-the-Century Brick Kilns to a Quick-Dry Partial Vacuum System 

    E-Print Network [OSTI]

    Bossis, R.

    2015-01-01

    Street, Suite 350, North Andover, MA 01845 With offices in: CA, CT, ME, NY, OR, TX, VT www.ers-inc.com PRESENTATION BY RYAN BOSSIS June 3, 2015 Steinway & Sons Upgrades Its Turn-of-the-Century Brick Kilns to a Quick-Dry Partial Vacuum System ESL...-IE-15-06-17 Proceedings of the Thrity-Seventh Industrial Energy Technology Conference New Orleans, LA. June 2-4, 2015 ?History of Steinway & Sons and manufacturing process ?Current wood-drying process ?Data collection and measurement of existing kiln’s...

  3. Degradation of alumina and zirconia toughened alumina (ZTA) hip prostheses tested under microseparation conditions in a shock device

    E-Print Network [OSTI]

    Uribe, Juliana; Gremillard, Laurent; Reynard, Bruno

    2013-01-01

    This paper considers the degradation of alumina and zirconia toughened alumina vs. alumina for hip implants. The materials are as assumed to be load bearing surfaces subjected to shocks in wet conditions. The load is a peak of force; 9 kN was applied over 15 ms at 2 Hz for 800,000 cycles. The volumetric wear and roughness are lower for ZTA than for alumina. The long ZTA ageing did not seem to have a direct influence on the roughness. The ageing increased the wear volumes of ZTA and it was found to have a higher wear resistance compared to alumina.

  4. Rheological Properties of Aqueous Nanometric Alumina Suspensions

    SciTech Connect (OSTI)

    Chuanping Li

    2004-12-19

    Colloidal processing is an effective and reliable approach in the fabrication of the advanced ceramic products. Successful colloidal processing of fine ceramic powders requires accurate control of the rheological properties. The accurate control relies on the understanding the influences of various colloidal parameters on the rheological properties. Almost all research done on the rheology paid less attention to the interactions of particle and solvent. However, the interactions of the particles are usually built up through the media in which the particles are suspended. Therefore, interactions of the particle with the media, the adsorbed layers on the particle surface, and chemical and physical properties of media themselves must influence the rheology of the suspension, especially for the dense suspensions containing nanosized particles. Relatively little research work has been reported in this area. This thesis addresses the rheological properties of nanometric alumina aqueous suspensions, and paying more attention to the interactions between particle and solvent, which in turn influence the particle-particle interactions. Dense nanometric alumina aqueous suspensions with low viscosity were achieved by environmentally-benign fructose additives. The rheology of nanometric alumina aqueous suspensions and its variation with the particle volume fraction and concentration of fructose were explored by rheometry. The adsorptions of solute (fructose) and solvent (water) on the nanometric alumina particle surfaces were measured and analyzed by TG/DSC, TOC, and NMR techniques. The mobility of water molecules in the suspensions and its variation with particle volume fractions and fructose additive were determined by the {sup 17}O NMR relaxation method. The interactions between the nanometric alumina particles in water and fructose solutions were investigated by AFM. The results indicated that a large number of water layers were physically bound on the particles' surfaces in the aqueous suspension. The viscosity of the suspension increases dramatically when the solid volume fraction exceeds 30 vol.%. The overlap of physically adsorbed water layers at this level causes the sharp increase in viscosity. Fructose molecules can weaken the interactions between the particle surfaces and water molecules, as a consequence, they release some bound water layers from the surfaces to the bulk medium. It is believed that fraction of the water that is bound by the solid surface is reduced hence becoming available for flow. The oxygen-17 relaxation time decreased with the increase of particle volume fractions in the suspension. Fructose addition increased the overall water mobility in the suspension. Only part of the alumina particle surfaces was covered with fructose molecules. This adsorption of fructose molecules on the particle surfaces increased the pH of the suspension with a concomitant decrease in {zeta}-potential of the alumina nanoparticles. The interactions between the nanometric alumina particles in water to a large extent can be explained by the DLVO theory. However, the interactions between particles in fructose solutions cannot be well described by the DLVO theory. The interaction forces (magnitude and range) as well as adhesive force and surface tension between nanometric alumina particles were decreased with the fructose concentration.

  5. Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion

    DOE Patents [OSTI]

    Shen, Ming-Shing (Rocky Point, NY); Yang, Ralph T. (Middle Island, NY)

    1980-01-01

    Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

  6. Validation of the new mixture design and testing protocol for lime stabilization 

    E-Print Network [OSTI]

    Yusuf, Fateh Ul Anam Muhammad Shafee

    2001-01-01

    The Mississippi Department of Transportation (MDOT) has used hydrated lime for over 30 years to stabilize subgrades. In 1998 a project was initiated to assess material properties and performance derived from lime treated subgrades (LTS). This thesis...

  7. Hydrolysis of carbonyl sulfide over alumina

    SciTech Connect (OSTI)

    Polleck, R. E.; Ledley, R. E.; Scott, K. A.

    1985-01-01

    The reaction rate for the hydrolysis of carbonyl sulfide in liquid petroleum hydrocarbons over alumina, such as propylene, is greatly increased by maintaining water in the hydrocarbons in an amount of one mole of water per mole of carbonyl sulfide to an upper limit of about ten moles of water per mole of carbonyl sulfide or about 30% of saturation of the hydrocarbons, whichever upper limit provides the lesser amount of water.

  8. A simple procedure to prepare spherical {alpha}-alumina powders

    SciTech Connect (OSTI)

    Liu Hongyu [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China); Ning Guiling [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China)], E-mail: ninggl@dlut.edu.cn; Gan Zhihong; Lin Yuan [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China)

    2009-04-02

    Spherical {alpha}-alumina powders were prepared by the controlled hydrolysis of aluminum isopropoxide in a hydrolysis system consisting of octanol and acetonitrile. Diverse solvents to dissolve reactant formed diverse hydrolysis systems and affected particle shape of {alpha}-alumina powders. The precursors crystallized to {gamma}-alumina at 1000 deg. C and converted to {alpha}-alumina at 1150 deg. C without intermediate phases. The particle morphology of precursor was retained after it crystallized to {alpha}-alumina. The heating rate influenced the particle shape and the state of agglomeration during calcination process. The thermal properties of the precursors were characterized by thermal gravimetric and differential thermal analysis. X-ray diffraction technique was used to confirm the conversion of crystalline phase of alumina powders from amorphous to {alpha}-phase. Transmission electron microscopy was used to investigate the morphologies and size of the precursors and products.

  9. The necessity for a practical approach to address organic emissions from cement kilns

    SciTech Connect (OSTI)

    Yonley, C.; Schreiber, B.; Kellerman, S.; Kellett, C.

    1998-12-31

    There is an inherent difficulty in monitoring organic emissions from hazardous waste combustion in the cement process. Data gathered by the EPA and the industry indicate that organic emissions at the main stack of cement kilns are principally from process characteristics and/or the desorption of organic constituents contained in the raw materials. Organic emissions are primarily based on the facility design and origin of the raw materials. One would generally conclude that organic emissions from fuels are essentially non-existent. To understand alternatives for monitoring organic emissions, this paper reviews some of the historical background behind the issue and reviews trends of characteristic organic emissions data. Based on this discussion and review, some approaches are presented to address organic emissions testing and monitoring when utilizing hazardous waste fuel in a cement kiln.

  10. Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry

    E-Print Network [OSTI]

    Kong, Lingbo

    2014-01-01

    greenhouse gas emissions from lime kilns at kraft pulpIn this trial, the total lime requirement has been reducedreactions instead of just lime causticizing and may cause

  11. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2012-01-01

    2006 Minerals Yearbook- Lime. http://minerals.usgs.gov/iron (DRI), pellets, lime, oxygen, and ingots, blooms,Export sinter pellet, etc Lime Kiln Slab Treatment Purchased

  12. Alumina-alumina and mullite-mullite joining by reaction sintering process

    SciTech Connect (OSTI)

    Torrecillas, R. (CSIC, Llanera (Spain). Inst. Tecnologico de Materiales de Asturias); Sainz, M.A.; Moya, J.S. (CSIC, Madrid (Spain). Inst. de Ceramica y Vidrio)

    1994-10-15

    Joining of simple ceramic shapes to form complex ceramic parts can be considered as an alternative route to the difficult and expensive methods associated with fabrication of near-net-shape ceramic components. The ability to reliably joint ceramic parts to form large systems is considered nowadays as a key technology in enhancing the use of ceramics in high temperature structural applications and in dirty environments. However, as has been pointed out elsewhere, the joining of ceramics is not yet a very high developed art. Most scientific and engineering efforts have been devoted to ceramic to metal joining. Alumina and mullite are two oxides ceramics largely considered for functional as well as structural applications. The purpose of the present investigation is to join alumina-alumina and mullite-mullite ceramics through reaction sintering with zircon.

  13. Electrolytic cell for production of aluminum from alumina

    DOE Patents [OSTI]

    Bradford, Donald R; Barnett, Robert J.; Mezner, Michael B.

    2005-03-15

    Electrolysis of alumina dissolved in a molten salt electrolyte employing inert anode and cathodes, the anode having a box shape with slots for the cathodes.

  14. PERFORMANCE OF SODIUM-BETA ALUMINA SOLID ELECTROLYTE IN Na/S CELLS

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2014-01-01

    SODIUM-BETA ALUMINA SOLID ELECTROLYTE IN Na/S CELLS Lutgardium-be ta alumina type solid electrolytes i s limit ed by

  15. Full-Depth Pavement Reclamation with Foamed Asphalt: Final Report

    E-Print Network [OSTI]

    Jones, David; Fu, P.; Harvey, John T; Halles, F.

    2008-01-01

    cement, lime) and/or inert (fly ash, mineral fines) fillershydrated lime, Class-C fly ash, and cement kiln dust.lime), semi-active (e.g. , fly-ash and kiln dust), and inert

  16. Porosity in plasma sprayed alumina coatings

    SciTech Connect (OSTI)

    Ilavsky, J.; Herman, H.; Berndt, C.C.; Goland, A.N.; Long, G.G.; Krueger, S.; Allen, A.J.

    1994-03-01

    Small-angle neutron scattering (SANS) was used to study the porosity of plasma sprayed deposits of alumina in as-sprayed and heat-treated conditions. SANS results were compared with mercury intrusion porosimetry (MIP) and water immersion techniques. Multiple small-angle neutron scattering yields a volume-weighted effective pore radius (R{sub eff}), for pores with sizes between 0.08 and 10{mu}m, the pore volume in this size region, and from the Porod region, the surface area of pores of all sizes.

  17. ORIGINAL PAPER Tunability of Propane Conversion over Alumina Supported

    E-Print Network [OSTI]

    ORIGINAL PAPER Tunability of Propane Conversion over Alumina Supported Pt and Rh Catalysts William Propane conversion over alumina supported Pt and Rh (1 wt% metals loading) was examined under fuel rich conversion and almost complete propane conversion) so long as the metal particle size was sufficiently low

  18. High-surface-area hydrated lime for SO2 control

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Moran, D.L. (Illinois State Geological Survey, Champaign, IL (United States). Minerals Engineering Section)

    1993-03-01

    Since 1986, the Illinois State Geological Survey (ISGS), has been developing a process to produce high-surface-area hydrated lime (HSAHL) with more activity for adsorbing SO2 than commercially available hydrated lime. HSAHL prepared by the ISGS method as considerably higher surface area and porosity, and smaller mean particle diameter and crystallite size than commercial hydrated lime. The process has been optimized in a batch, bench-scale reactor and has been scaled-up to a 20--100 lb/hr process optimization unit (POU). Experiments have been conducted to optimize the ISGS hydration process and identify key parameters influencing hydrate properties for SO2 capture (surface area, porosity, particle size, and crystallite size). The known how is available to tailor properties of hydrated limes for specific SO2 removal applications. Pilot-scale tests conducted with the HSAHL under conditions typical of burning high-sulfur coals have achieved up to 90% SO2 capture in various DSI systems. The removal results are enough to bring most high-sulfur coals into compliance with acid rain legislation goals for the year 2000. The focus of the POU program is to generate critical engineering data necessary for the private sector to scale-up the process to a commercial level and provide estimates of the optimal cost of construction and operation of a commercial plant. ISGS is currently participating in a clean coal technology program (CCT-1) by providing 50 tons of HSAHL for a demonstration test at Illinois Power's Hennepin station in January 1993.

  19. Kinetic Modeling and Assessment of Lime Pretreatment of Poplar Wood 

    E-Print Network [OSTI]

    Sierra Ramirez, Rocio

    2012-02-14

    , industrial, and agricultural). 5. Appropriate selection of feedstock and conversion technology. 6. Improved efficiency of the production technology obtained through intensive research and development. 7. More efficient use of energy, including vehicle...-1 KINETIC MODELING AND ASSESSMENT OF LIME PRETREATMENT OF POPLAR WOOD A Dissertation by ROCIO SIERRA RAMIREZ Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree...

  20. Atomic Scale Mechanism of the Transformation of -Alumina to -Alumina Shu-Hui Cai,1,2

    E-Print Network [OSTI]

    Pantelides, Sokrates T.

    of the conversion rate is in excellent agreement with the experimental transformation temperature. DOI: 10.1103/Phys -alumina [4]. Second, the unit cell of -alumina is a defect-free struc- ture, whereas the unit cell rate of the thermal conversion is in ex- cellent agreement with the well-established experi- mental

  1. Optimized alumina coagulants for water treatment

    DOE Patents [OSTI]

    Nyman, May D. (Albuquerque, NM); Stewart, Thomas A. (Albuquerque, NM)

    2012-02-21

    Substitution of a single Ga-atom or single Ge-atom (GaAl.sub.12 and GeAl.sub.12 respectively) into the center of an aluminum Keggin polycation (Al.sub.13) produces an optimal water-treatment product for neutralization and coagulation of anionic contaminants in water. GaAl.sub.12 consistently shows .about.1 order of magnitude increase in pathogen reduction, compared to Al.sub.13. At a concentration of 2 ppm, GaAl.sub.12 performs equivalently to 40 ppm alum, removing .about.90% of the dissolved organic material. The substituted GaAl.sub.12 product also offers extended shelf-life and consistent performance. We also synthesized a related polyaluminum chloride compound made of pre-hydrolyzed dissolved alumina clusters of [GaO.sub.4Al.sub.12(OH).sub.24(H.sub.2O).sub.12].sup.7+.

  2. Compositional characterization of atomic layer deposited alumina

    SciTech Connect (OSTI)

    Philip, Anu; Thomas, Subin; Kumar, K. Rajeev [Department of Instrumentation, Cochin University of Science and Technology, Cochin-22, Kerala (India)

    2014-01-28

    As the microelectronic industry demands feature size in the order of few and sub nanometer regime, the film composition and other film properties become critical issues and ALD has emerged as the choice of industry. Aluminum oxide is a material with wide applications in electronic and optoelectronic devices and protective and ion barrier layers. Al{sub 2}O{sub 3} is an excellent dielectric because of its large band gap (8.7eV), large band offsets with silicon. We have deposited thin layers of alumina on silicon wafer (p-type) for gate dielectric applications by ALD technique and compositional characterizations of the deposited thin films were done using EDS, XPS and FTIR spectra.

  3. Porous Alumina Based Capacitive MEMS RH Sensor

    E-Print Network [OSTI]

    Juhasz, L; Timar-Horvath, Veronika; Desmulliez, Marc; Dhariwal, Resh

    2008-01-01

    The aim of a joint research and development project at the BME and HWU is to produce a cheap, reliable, low-power and CMOS-MEMS process compatible capacitive type relative humidity (RH) sensor that can be incorporated into a state-of-the-art, wireless sensor network. In this paper we discuss the preparation of our new capacitive structure based on post-CMOS MEMS processes and the methods which were used to characterize the thin film porous alumina sensing layer. The average sensitivity is approx. 15 pF/RH% which is more than a magnitude higher than the values found in the literature. The sensor is equipped with integrated resistive heating, which can be used for maintenance to reduce drift, or for keeping the sensing layer at elevated temperature, as an alternative method for temperature-dependence cancellation.

  4. Fracture simulation for zirconia toughened alumina microstructure

    E-Print Network [OSTI]

    Kim, Kyungmok; Forest, Bernard

    2013-01-01

    Purpose - The purpose of this paper is to describe finite element modelling for fracture and fatigue behaviour of zirconia toughened alumina microstructures. Design/methodology/approach - A two-dimensional finite element model is developed with an actual $Al{_2}O{_3}$ - 10 vol% $ZrO{_2}$ microstructure. A bilinear, time-independent cohesive zone law is implemented for describing fracture behaviour of grain boundaries. Simulation conditions are similar to those found at contact between a head and a cup of hip prosthesis. Residual stresses arisen from the mismatch of thermal coefficient between grains are determined. Then, effects of a micro-void and contact stress magnitude are investigated with models containing residual stresses. For the purpose of simulating fatigue behaviour, cyclic loadings are applied to the models. Findings - Results show that crack density is gradually increased with increasing magnitude of contact stress or number of fatigue cycles. It is also identified that a micro-void brings about...

  5. Time-variability of NO{sub x} emissions from Portland cement kilns

    SciTech Connect (OSTI)

    Walters, L.J. Jr.; May, M.S. III [PSM International, Dallas, TX (United States)] [PSM International, Dallas, TX (United States); Johnson, D.E. [Kansas State Univ., Manhattan, KS (United States). Dept. of Statistics] [Kansas State Univ., Manhattan, KS (United States). Dept. of Statistics; MacMann, R.S. [Penta Engineering, St. Louis, MO (United States)] [Penta Engineering, St. Louis, MO (United States); Woodward, W.A. [Southern Methodist Univ., Dallas, TX (United States). Dept. of Statistics] [Southern Methodist Univ., Dallas, TX (United States). Dept. of Statistics

    1999-03-01

    Due to the presence of autocorrelation between sequentially measured nitrogen oxide (NO{sub x}) concentrations in stack gas from portland cement kilns, the determination of the average emission rates and the uncertainty of the average has been improperly calculated by the industry and regulatory agencies. Documentation of permit compliance, establishment of permit levels, and the development and testing of control techniques for reducing NO{sub x} emissions at specific cement plants requires accurate and precise statistical estimates of parameters such as means, standard deviations, and variances. Usual statistical formulas such as for the variance of the sample mean only apply if sequential measurements of NO{sub x} emissions are independent. Significant autocorrelation of NO{sub x} emission measurements revealed that NO{sub x} concentration values measured by continuous emission monitors are not independent but can be represented by an autoregressive, moving average time series. Three orders of time-variability of NO{sub x} emission rates were determined from examination of continuous emission measurements from several cement kilns.

  6. Soil Acidity and Manganese Nutrition of Corn and Soybeans as Affected by Lime and Nitrogen Applications in an Oxisol under a No-Till System

    E-Print Network [OSTI]

    Caires, Eduardo Fávero; Garbuio, Fernando José; Joris, Hélio Antonio Wood; Pereira, Paulo Roberto da Silva Filho

    2009-01-01

    control soil acidity in NT, lime is broadcast on the surfacethat examined the effect of lime and N applications soilacid loamy soil. Dolomitic lime was surface applied and N-NH

  7. Monitoring of Candidatus Liberibacter asiaticus in Citrus Seedlings at Greenhouse Conditions and Commercial Orchards of Sweet Orange and Tahiti Lime in the Northwest of Parana State, Brazil

    E-Print Network [OSTI]

    Sauer, A. V.; Barbieri, B. R.; Coletta-Filho, H. D.; Machado, M. A.; Corazza, M. J.; Nunes, W. M.C.

    2014-01-01

    of Sweet Orange and Tahiti Lime in the Northwest of Paranaand in commercial orchards of sweet orange and Tahiti lime.of sweet orange and Tahiti lime naturally infected with HLB

  8. Experimental and Numerical Studies of Aluminum-Alumina Composites 

    E-Print Network [OSTI]

    Gudlur, Pradeep

    2013-07-22

    The preliminary goal of this study is to determine the effects of processing conditions, compositions and microstructural morphologies of the constituents on the physical and thermo-mechanical properties of alumina (Al_2O_3) ...

  9. Commercial applications of nanostructures created with ordered porous alumina

    E-Print Network [OSTI]

    Wells, Brendan Christopher, 1979-

    2004-01-01

    In the drive from microfabrication to nanofabrication, porous alumina templates may play a key role in technological evolution. Under the right processing conditions, ordered pores can grow in anodic aluminum oxide, which ...

  10. Reproductive and developmental health risk from dioxin-like compounds: Insignificant risk from cement kilns burning waste-derived fuels

    SciTech Connect (OSTI)

    Holcomb, L.C.; Pedelty, J.F.

    1994-12-31

    Cement kilns burning waste-derived fuels emit low levels of dibenzodioxins and dibenzofurans and little or no PCB`s. Concern about possible effects on reproduction and development has prompted an evaluation of the research literature especially with regard to the reproductive and developmental effects of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). In sufficient doses, dioxins, furans, and PCB can cause adverse health effects in some animals or humans. Calculated doses of TCDD-EQ (dioxin equivalents) are dependent on many assumptions, but where human effects have been demonstrated, doses were 100--1,000 times higher than the usual background environmental doses. This would include those environmental doses that would be received by the most-exposed individual living near cement kilns burning WDF. There is evidence to suggest that PCB`s have had an adverse impact on some wildlife although there is no evidence that these PCB`s are associated with cement kiln emissions. There is no evidence to suggest that dioxins, at environmental levels or associated with emissions from WDF-burning cement kilns, have caused adverse effects in either wildlife or humans. 63 refs., 3 tabs.

  11. Carbon dioxide pressure swing adsorption process using modified alumina adsorbents

    DOE Patents [OSTI]

    Gaffney, T.R.; Golden, T.C.; Mayorga, S.G.; Brzozowski, J.R.; Taylor, F.W.

    1999-06-29

    A pressure swing adsorption process for absorbing CO[sub 2] from a gaseous mixture containing CO[sub 2] comprises introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100 C and 500 C to adsorb CO[sub 2] to provide a CO[sub 2] laden alumina adsorbent and a CO[sub 2] depleted gaseous mixture and contacting the CO[sub 2] laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO[sub 2] from the CO[sub 2] laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100 C and 600 C, is not degraded by high concentrations of water under process operating conditions. 1 fig.

  12. Barley seedling growth in soils amended with fly ash or agricultural lime followed by acidification

    SciTech Connect (OSTI)

    Renken, R.R.; McCallister, D.L.; Tarkalson, D.D.; Hergert, G.W.; Marx, D.B.

    2006-05-15

    Calcium-rich coal combustion fly ash can be used as an amendment to neutralize soil acidity because of its oxides and carbonate content, but its aluminum content could inhibit plant growth if soil pH values fall below optimal agronomic levels. This study measured root and shoot growth of an acid-sensitive barley (Hordeum vulgare L. 'Kearney') grown in the greenhouse on three naturally acid soils. The soils were either untreated or amended with various liming materials (dry fly ash, wet fly ash, and agricultural lime) at application rates of 0, .5, 1, and 1.5 times the recommended lime requirement, then treated with dilute acid solutions to simulate management-induced acidification. Plant growth indexes were measured at 30 days after planting. Root mass per plant and root length per plant were greater for the limed treatments than in the acidified check. Root growth in the limed treatments did not differ from root growth in the original nonacidified soils. Top mass per plant in all limed soils was either larger than or not different from that in the original nonacidified soils. Based on top mass per plant, no liming material or application rate was clearly superior. Both fly ash and agricultural lime reduced the impact of subsequent acidification on young barley plants. Detrimental effects of aluminum release on plant growth were not observed. Calcium-rich fly ash at agronomic rates is an acceptable acid-neutralizing material with no apparent negative effects.

  13. Evidence that ‘flying dragon’ trifoliate orange delays HLB symptom expression for four sweet orange cultivars, Tahiti lime and Okitsu mandarin

    E-Print Network [OSTI]

    Stuchi, E. S.; Reiff, E. T.; Sempionato, O. R.; Parolin, L. G.; Toledo, D. A.

    2014-01-01

    orange cultivars, Tahiti lime and Okitsu mandarin Stuchi,producer and has 49,000 ha cultivated with ‘Tahiti’ limeacid lime. Mandarin cultivation represents 5.5% of total

  14. A study of the effects of repeated loadings and free water on the stability of a lime stabilized clay 

    E-Print Network [OSTI]

    Jantos, Carl Thomas

    1959-01-01

    . Sere Percent Lime (Raw Soil) Triaxial Results . 9, Twe Percent Lime Triaxial Results . 10. Four Percent Lime Triaxial Results 37 37 40 LIST OF FIGURES 1. Triaxial Compression Device and Universal Testing Nachine . 2. Harvard Nlniature Compactor... Equipment 3. Typical Test Speoimens 4. Ltterberg Limits - Brasos River Clay 5. Modified JULS80 Compaction - Brasos River Clay 6. Nohr's Circles and Rupture Envelopes 7, 0 Percent Lime (Raw Soil) Triaxial Test, 15 psi 45 47 48 Lateral Pressure 49 S...

  15. Cast alumina forming austenitic stainless steels

    DOE Patents [OSTI]

    Muralidharan, Govindarajan; Yamamoto, Yukinori; Brady, Michael P

    2013-04-30

    An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.

  16. Stabilization of Oklahoma expensive soils using lime and class C fly ash

    SciTech Connect (OSTI)

    Buhler, R.L.; Cerato, A.B.

    2007-01-15

    This study uses lime and class C fly ash, an industrial byproduct of electric power production produced from burning lignite and subbituminous coal, to study the plasticity reduction in highly expensive natural clays from Idabel, Oklahoma. This study is important, especially in Oklahoma, because most of the native soils are expansive and cause seasonal damage to roadways and structures. The addition of lime or fly ash helps to arrest the shrinkage and swelling behavior of soil. Four soil samples with the same AASHTO classification were used in this study to show shrinkage variability within a soil group with the addition of lime and class C fly ash. The plasticity reduction in this study was quantified using the linear shrinkage test. It was found that soils classified within the same AASHTO group had varying shrinkage characteristics. It was also found that both lime and fly ash reduced the lienar shrinkage, however, the addition of lime reduced the linear shrinkage to a greater degree than the same percentage of class C fly ash. Even though it takes much less lime than fly ash to reduce the plasticity of a highly expansive soil, it may be less expensive to utilize fly ash, which is a waste product of electric power production. Lime also has a lower unit weight than fly ash so weight percentage results may be misleading.

  17. Evaluation of lime-fly ash stabilized bases and subgrades using static and dynamic deflection systems 

    E-Print Network [OSTI]

    Raba, Gary W.

    1982-01-01

    in Figure 56, Appendix A. A summarization of the construction control data and Table 3. Lime-Fly Ash Stabilization Data for Test Site No. 3 (FM 1604 in Bexar County) Test Section Lime/Fly Ash Percentage (X by wt. ) Actual 3/6 3/0 2/5 4/0 2/8 0... County) Test Section Lime/Fly Ash Percentage (X by wt. ) Date of Actual Construction Plasticity Index Final % Passin9 No. 4 Sieve Field Moistur~ Density Content (/) (lb/ft ) Percent of Laboratory Densityb 4/0 3/6 3/9 0/10 I/5 2...

  18. A study of the rate of gain of strength in lime stabilized soil 

    E-Print Network [OSTI]

    Nichols, Sterling Ramsdell, Jr

    1960-01-01

    0 37 ~ o ~ 4'7 APPEEDIX C. Electron Nicrographs . . . . . . . . . . . 75 LIST OF TABLES Table Page i. Cation-Exchange Capacity of Clay Minerals 15 2. Results of pH Test on Lime Treate Clay a o o o o o 3. X-Ray Diffraction Data 4... Triaxial Compressi. on Test Results 12. Triaxisl Compression Test Results 13. Triaxial Compression Test Results 14. Triaxial Compression Test Results 15. Triaxial Compression Test Results Least Squares Raw Soil. 1$ Lime Content 2$ Lime Content 4...

  19. Molecular dynamics studies of interfacial water at the alumina surface.

    SciTech Connect (OSTI)

    Argyris, Dr. Dimitrios [University of Oklahoma; Ho, Thomas [ORNL; Cole, David [Ohio State University

    2011-01-01

    Interfacial water properties at the alumina surface were investigated via all-atom equilibrium molecular dynamics simulations at ambient temperature. Al-terminated and OH-terminated alumina surfaces were considered to assess the structural and dynamic behavior of the first few hydration layers in contact with the substrates. Density profiles suggest water layering up to {approx}10 {angstrom} from the solid substrate. Planar density distribution data indicate that water molecules in the first interfacial layer are organized in well-defined patterns dictated by the atomic terminations of the alumina surface. Interfacial water exhibits preferential orientation and delayed dynamics compared to bulk water. Water exhibits bulk-like behavior at distances greater than {approx}10 {angstrom} from the substrate. The formation of an extended hydrogen bond network within the first few hydration layers illustrates the significance of water?water interactions on the structural properties at the interface.

  20. Photothermal investigation of the thermal shock behavior of alumina ceramics for engine components

    E-Print Network [OSTI]

    Mandelis, Andreas

    Photothermal investigation of the thermal shock behavior of alumina ceramics for engine components of alumina ceramic materials (96% Al2O3/3% SiO2/0.9% MgO) treated by applying high temperature and high pressure, a process known as ASPRO conversion technology. Alumina ceramics subjected to ASPRO treatment

  1. The ultra-high lime with aluminum process for removing chloride from recirculating cooling water 

    E-Print Network [OSTI]

    Abdel-wahab, Ahmed Ibraheem Ali

    2004-09-30

    Chloride is a deleterious ionic species in cooling water systems because it is important in promoting corrosion. Chloride can be removed from cooling water by precipitation as calcium chloroaluminate using ultra-high lime with aluminum process (UHLA...

  2. The effect of hydrated lime on Salmonella enteritidis survival in poultry litter and poult performance 

    E-Print Network [OSTI]

    Stanush, Deborah Denise

    2000-01-01

    The presence of Salmonella and/or Campylobacter in poultry litter may contribute to contaminated processed carcasses. Initially in our first study, we evaluated the effect of 5, 10, or 20% added lime on in vitro survival of Salmonella enteritidis...

  3. Equations for predicting the layer stiffness moduli in pavement systems containing lime-flyash stabilized materials 

    E-Print Network [OSTI]

    Alam, Shah Manzoor

    1984-01-01

    Site 3 located on FN '1604 in Bexar Count This test site consisted of six test sections constructed of a 10- inch flexible base over a 6-inch lime-flyash stabilized subbase. The sections were surfaced with a two- course bituminous surface treatment...EOUATIONS FOR PREDICTING THE LAYER STIFFNESS ' MODULI IN PAVEMENT SYSTEMS CONTAINING LIME-FLYASH STABILIZED MATERIALS A Thesis by SHAH MANZOOR ALAM Submitted to the Graduate College of Texas AN University in partial fulfillment...

  4. Liming effects on slash pine (Pinus elliottii Englm.) seedlings growing on acid soils 

    E-Print Network [OSTI]

    Elzner, John Thomas

    1978-01-01

    (treatment, exchangeable aluminum, extractable aluminum, exchangeable acidity, pH and calcium) . . . , . . . . . . . . 53 18 Correlation (r) of soil variables with potassium content in tops of slash pine seedlings on three soils . . . . . . . . . 55 LIST... fixing power that accounted for low amounts of exchange- able potassium. They postulated that the amount of potassium available was not adequate for good growth of pines on highly limed plots. Excess liming may also have detrimental effects on soil...

  5. AEC Lowman Station - coal switching and magnesium-enhanced lime scrubbing to lower operating costs

    SciTech Connect (OSTI)

    Inkenhaus, W.; Babu, M.; Smith, K. [Dravo Lime Co., Pittsburgh, PA (United States); Loper, L. [Alabama Electric Coopreative, Leroy, AL (United States)

    1997-12-31

    AEC`s Lowman Station is located in Leroy, Alabama. There are three coal-fired boilers at this station. Unit 1 is capable of generating 85 MW without a flue gas desulfurization, FGD, system. Units 2 and 3, with a total of 516 MW output capacity, are equipped with FGD systems. The FGD plant was designed for wet limestone FGD with natural oxidation. Lowman Station burned low sulfur, 1.3 to 1.8% sulfur, coal. In January of 1996 AEC switched Units 2 and 3 from limestone to magnesium-enhanced lime FGD operation. It was determined that the plant could take advantage of the higher SO{sub 2} removal efficiency of the magnesium-enhanced lime system. Major benefits resulting from this conversion were AEC`s ability to switch to a lower cost high sulfur coal while meeting the stringent SO{sub 2} emission requirements. Power cost savings resulted from the lower liquid to gas ratio required by the magnesium-enhanced lime process. Three recirculation pumps per module were reduced to a single operating pump per module, lowering the scrubber pressure drop. Significant cost reduction in the operating costs of the ball mill was realized due to modifications made to slake lime instead of grinding limestone. Prior to switching, personnel from AEC and Dravo Lime Company ran a four week test on magnesium-enhanced lime to obtain scrubber performance data including SO{sub 2} removal efficiencies on the modules while burning a 1.8% sulfur coal. This paper discusses the plant modifications that were needed to make the switch, cost justifications due to coal switching, and AEC`s operating experiences to date. AEC and Dravo Lime Company working together as a team conducted detailed cost studies, followed by extensive field tests and implemented the plant modifications. This plant continues to operate burning higher sulfur coal with the magnesium-enhanced lime FGD system.

  6. Evaluation of methods of mixing lime in bituminous paving mixtures in batch and drum plants 

    E-Print Network [OSTI]

    Button, Joseph Wade

    1984-01-01

    . Lime was added in the pugmill of the batch plant, on the cold feed belt, and through the fines feeder of the drum mix plant. The asphalt and aggregates used were characterized in the laboratory. Asphalt concrete mixture tests included laboratory... Maria Road 14 3 Laboratory Test Program for All Mixtures 17 Process by which Lime Slurry was Added to the Individual Aggregates on the Cold Feed Belt Overall Average Air Void Content of Laboratory Mixed and Compacted Samples 19 27 Resilient...

  7. An introduction to LIME 1.0 and its use in coupling codes for multiphysics simulations.

    SciTech Connect (OSTI)

    Belcourt, Noel; Pawlowski, Roger Patrick; Schmidt, Rodney Cannon; Hooper, Russell Warren

    2011-11-01

    LIME is a small software package for creating multiphysics simulation codes. The name was formed as an acronym denoting 'Lightweight Integrating Multiphysics Environment for coupling codes.' LIME is intended to be especially useful when separate computer codes (which may be written in any standard computer language) already exist to solve different parts of a multiphysics problem. LIME provides the key high-level software (written in C++), a well defined approach (with example templates), and interface requirements to enable the assembly of multiple physics codes into a single coupled-multiphysics simulation code. In this report we introduce important software design characteristics of LIME, describe key components of a typical multiphysics application that might be created using LIME, and provide basic examples of its use - including the customized software that must be written by a user. We also describe the types of modifications that may be needed to individual physics codes in order for them to be incorporated into a LIME-based multiphysics application.

  8. Colloids and Surfaces A: Physicochem. Eng. Aspects 233 (2004) 145153 Solgel transition study and pyrolysis of alumina-based gels

    E-Print Network [OSTI]

    Gulari, Erdogan

    2004-01-01

    and pyrolysis of alumina-based gels prepared from alumatrane precursor Bussarin Ksapabutra, Erdogan Gularib

  9. Distribution of arsenic and mercury in lime spray dryer ash

    SciTech Connect (OSTI)

    Panuwat Taerakul; Ping Sun; Danold W. Golightly; Harold W. Walker; Linda K. Weavers

    2006-08-15

    The partitioning of As and Hg in various components of lime spray dryer (LSD) ash samples from a coal-fired boiler was characterized to better understand the form and fate of these elements in flue gas desulfurization byproducts. LSD ash samples, collected from the McCracken Power Plant on the Ohio State University campus, were separated by a 140-mesh (106 {mu}m) sieve into two fractions: a fly-ash-/unburned-carbon-enriched fraction (> 106 {mu}m) and a calcium-enriched fraction (< 106 {mu}m). Unburned carbon and fly ash in the material > 106 {mu}m were subsequently separated by density using a lithium heteropolytungstate solution. The concentrations of As and Hg were significant in all fractions. The level of As was consistently greater in the calcium-enriched fraction, while Hg was evenly distributed in all components of LSD ash. Specific surface area was an important factor controlling the distribution of Hg in the different components of LSD ash, but not for As. Comparing the LSD ash data to samples collected from the economizer suggests that As was effectively captured by fly ash at 600{sup o}C, while Hg was not. Leaching tests demonstrated that As and Hg were more stable in the calcium-enriched fraction than in the fly-ash- or carbon-enriched fractions, potentially because of the greater pH of the leachate and subsequently greater stability of small amounts of calcium solids containing trace elements in these fractions. 37 refs., 8 figs., 2 tabs.

  10. Assessment of the percent status of burning refuse-derived fuel as a fuel supplement in the cement kiln industry

    SciTech Connect (OSTI)

    1981-09-01

    The purpose of the project was to solicit information on the use of refuse-derived fuel (RDF) in cement kilns by survey, follow up the mailed survey with telephone calls to the recipients, and assemble collected information into a report. A list of companies that had some experience with RFD was compiled and is presented in Appendix A. The procedure for conducting the survey is explained. A copy of the questionnaire is presented in Appendix B. The letters of response are reproduced in Appendix C. Two completed forms were received and clear conclusions are summarized. The effort was terminated and no final report was assembled.

  11. Conduction in alumina with atomic scale copper filaments

    SciTech Connect (OSTI)

    Xu, Xu; Liu, Jie; Anantram, M. P.

    2014-10-28

    The conductance of atomic scale filaments with three and seven Cu atoms in ?-alumina are calculated using ab initio density functional theory. We find that the filament with 3 Cu atoms is sufficient to increase the conductance of 1.3?nm thick alumina film by more than 10{sup 3} times in linear response. As the applied voltage increases, the current quickly saturates and differential resistance becomes negative. Compared to the filament with three Cu atoms, while the conductance of the filament with seven Cu atoms is comparable in linear response, they carry as much as twenty times larger current at large biases. The electron transport is analyzed based on local density of states, and the negative differential resistance in the seven Cu filaments occurs due to their narrow bandwidth.

  12. Measurements of prompt radiation induced conductivity of alumina and sapphire.

    SciTech Connect (OSTI)

    Hartman, E. Frederick; Zarick, Thomas Andrew; Sheridan, Timothy J.; Preston, Eric F.

    2011-04-01

    We performed measurements of the prompt radiation induced conductivity in thin samples of Alumina and Sapphire at the Little Mountain Medusa LINAC facility in Ogden, UT. Five mil thick samples were irradiated with pulses of 20 MeV electrons, yielding dose rates of 1E7 to 1E9 rad/s. We applied variable potentials up to 1 kV across the samples and measured the prompt conduction current. Analysis rendered prompt conductivity coefficients between 1E10 and 1E9 mho/m/(rad/s), depending on the dose rate and the pulse width for Alumina and 1E7 to 6E7 mho/m/(rad/s) for Sapphire.

  13. Protective coating for alumina-silicon carbide whisker composites

    DOE Patents [OSTI]

    Tiegs, Terry N. (Lenoir City, TN)

    1989-01-01

    Ceramic composites formed of an alumina matrix reinforced with silicon carbide whiskers homogenously dispersed therein are provided with a protective coating for preventing fracture strength degradation of the composite by oxidation during exposure to high temperatures in oxygen-containing atmospheres. The coating prevents oxidation of the silicon carbide whiskers within the matrix by sealing off the exterior of the matrix so as to prevent oxygen transport into the interior of the matrix. The coating is formed of mullite or mullite plus silicon oxide and alumina and is formed in place by heating the composite in air to a temperature greater than 1200.degree. C. This coating is less than about 100 microns thick and adequately protects the underlying composite from fracture strength degradation due to oxidation.

  14. Melt processing of Bi--2212 superconductors using alumina

    DOE Patents [OSTI]

    Holesinger, Terry G. (Los Alamos, NM)

    1999-01-01

    Superconducting articles and a method of forming them, where the superconducting phase of an article is Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.y (Bi-2212). Alumina is combined with Bi-2212 powder or Bi-2212 precursor powder and, in order to form an intimate mixture, the mixture is melted and rapidly cooled to form a glassy solid. The glassy solid is comminuted and the resulting powder is combined with a carrier. An alternative to melting is to form the mixture of nanophase alumina and material having a particle size of less than about 10 microns. The powder, with the carrier, is melt processed to form a superconducting article.

  15. Proton adsorption onto alumina: extension of multisite complexation (MUSIC) theory

    SciTech Connect (OSTI)

    Nagashima, K.; Blum, F.D.

    1999-09-01

    The adsorption isotherm of protons onto a commercial {gamma}-alumina sample was determined in aqueous nitric acid with sodium nitrate as a background electrolyte. Three discrete regions could be discerned in the log-log plots of the proton isotherm determined at the solution pH 5 to 2. The multisite complexation (MUSIC) model was modified to analyze the simultaneous adsorption of protons onto various kinds of surface species.

  16. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  17. Mild hydrotreating of heavy oils with modified alumina based catalysts

    SciTech Connect (OSTI)

    Dai, E.P.; Campbell, C.N. [Texaco Research and Development, Port Arthur, TX (United States)

    1994-12-31

    The decreasing demand for heavy fuels oils requires that refiners find ways for converting heavy hydrocarbon feedstocks to higher value mid-distillate products. To increase mid-distillate production, the refiner can choose from several processing options such as hydrocracking, fluid catalytic cracking, and coking. All of these options, however, require heavy capital investments. Because of these high investment costs, refiners are continually searching for conversion processes which may be utilized in existing units. One such process is mild hydrocracking (MHC). The general objective of this work is to identify an MHC catalyst which gives a higher conversion level for heavy hydrocarbon feedstocks, especially that fraction of the feedstock that boils above 1,000 F (538 C), while maintaining the same amount of sediment production. The conventional hydrocracking catalysts that consist of acidic cracking components such as Y zeolite, though exhibiting conversion improvements over alumina based catalysts, were not suitable for processing of heavy oils in the mild hydrocracking mode because of high sediment formation. In contrast, alumina catalysts containing basic oxides (alkali metal and alkaline earth metal) not only improve heavy oil conversion but, also maintain the sediment make at the same level as alumina based catalysts. The sediment make generally decreased with increasing macroporosity.

  18. Developing Mobile Applications: A LIME Primer Gian Pietro Picco, Amy L. Murphy, and Gruia-Catalin Roman

    E-Print Network [OSTI]

    Picco, Gian Pietro

    , algorithms, and technology must be recast in the mobile scenario. Application development requiresDeveloping Mobile Applications: A LIME Primer Gian Pietro Picco, Amy L. Murphy, and Gruia of mobile applications. In this paper, we illustrate the model underlying LIME, present the programming

  19. The Use of Lime in Fish Ponds1 Andy M. Lazur, Charles E. Cichra and Craig Watson2

    E-Print Network [OSTI]

    Hill, Jeffrey E.

    FA38 The Use of Lime in Fish Ponds1 Andy M. Lazur, Charles E. Cichra and Craig Watson2 1. There are three main purposes for liming ponds: 1) to increase the availability of nutrients, 2) to increase pH and to buffer against daily pH fluctuations and 3) to steril- ize ponds prior to stocking. While these practices

  20. EFFECTS OF COMPOST AND LIME APPLICATION ON SOIL CHEMICAL PROPERTIES, SOIL MICROBIAL COMMUNITY, AND FUSARIUM WILT IN

    E-Print Network [OSTI]

    Ma, Lena

    1 EFFECTS OF COMPOST AND LIME APPLICATION ON SOIL CHEMICAL PROPERTIES, SOIL MICROBIAL COMMUNITY compost as an antagonistic suppression approach to combat soil-borne disease effects on crop yields the effect of compost and lime on soil chemical properties, the soil microbial community (including Fusarium

  1. Alumina catalysts for reduction of NOx from methanol fueled diesel engine

    SciTech Connect (OSTI)

    Yamamoto, Toshiro; Noda, Akira; Sakamoto, Takashi; Sato, Yoshio [Ministry of Transport of Japan, Kumamoto (Japan)

    1996-09-01

    NOx selective reducing catalysts are expected to be used for lean-burn gasoline engines and diesel engines as an effective NOx reduction measure. The authors are interested in the combination of methanol, as a reducing agent, and alumina catalyst, and have considered the NOx reduction method using effectively much unburned methanol. In this report, in order to investigate the effect of NOx reduction by the alumina catalyst, the experiment was carried out by feeding the actual exhaust gas from the methanol engine into the alumina catalyst. As a result, it was confirmed that, without addition of any other reducing agents into the exhaust gas, the alumina catalyst has activity to reduce NOx.

  2. Method to produce alumina aerogels having porosities greater than 80 percent

    DOE Patents [OSTI]

    Poco, John F.; Hrubesh, Lawrence W.

    2003-09-16

    A two-step method for producing monolithic alumina aerogels having porosities of greater than 80 percent. Very strong, very low density alumina aerogel monoliths are prepared using the two-step sol-gel process. The method of preparing pure alumina aerogel modifies the prior known sol method by combining the use of substoichiometric water for hydrolysis, the use of acetic acid to control hydrolysis/condensation, and high temperature supercritical drying, all of which contribute to the formation of a polycrystalline aerogel microstructure. This structure provides exceptional mechanical properties of the alumina aerogel, as well as enhanced thermal resistance and high temperature stability.

  3. Viscosity of aqueous and cyanate ester suspensions containing alumina nanoparticles

    SciTech Connect (OSTI)

    Lawler, Katherine

    2009-08-05

    The viscosities of both aqueous and cyanate ester monomer (BECy) based suspensions of alumina nanoparticle were studied. The applications for these suspensions are different: aqueous suspensions of alumina nanoparticles are used in the production of technical ceramics made by slip casting or tape casting, and the BECy based suspensions are being developed for use in an injection-type composite repair resin. In the case of aqueous suspensions, it is advantageous to achieve a high solids content with low viscosity in order to produce a high quality product. The addition of a dispersant is useful so that higher solids content suspensions can be used with lower viscosities. For BECy suspensions, the addition of nanoparticles to the BECy resin is expected to enhance the mechanical properties of the cured composite. The addition of saccharides to aqueous suspensions leads to viscosity reduction. Through DSC measurements it was found that the saccharide molecules formed a solution with water and this resulted in lowering the melting temperature of the free water according to classic freezing point depression. Saccharides also lowered the melting temperature of the bound water, but this followed a different rule. The shear thinning and melting behaviors of the suspensions were used to develop a model based on fractal-type agglomeration. It is believed that the structure of the particle flocs in these suspensions changes with the addition of saccharides which leads to the resultant viscosity decrease. The viscosity of the BECy suspensions increased with solids content, and the viscosity increase was greater than predicted by the classical Einstein equation for dilute suspensions. Instead, the Mooney equation fits the viscosity behavior well from 0-20 vol% solids. The viscosity reduction achieved at high particle loadings by the addition of benzoic acid was also investigated by NMR. It appears that the benzoic acid interacts with the surface of the alumina particle which may be the cause of the viscosity reduction. The flow behavior of alumina particles in water and BECy is markedly different. Aqueous alumina suspensions are shear thinning at all alumina loadings and capable of 50 vol% loading before losing fluidity whereas BECy/alumina suspensions show Newtonian behavior up to 5 vol%, and above 5 vol% show shear thinning at all shear rates. Highly loaded suspensions (i.e. 20vol% alumina) exhibit shear thinning at low and moderate shear rates and shear thickening at higher shear rates. The maximum particle loading for a fluid suspension, in this case, appears to be about 20 vol%. The difference in the viscosity of these suspensions must be related to the solvent-particle interactions for each system. The reason is not exactly known, but there are some notable differences between BECy and water. Water molecules are {approx}0.28 nm in length and highly hydrogen bonded with a low viscosity (1 mPa's) whereas in the cyanate ester (BECy) system, the solvent molecule is about 1.2 nm, in the largest dimension, with surfaces of varied charge distribution throughout the molecule. The viscosity of the monomer is also reasonably low for organic polymer precursor, about 7 mPa's. Nanoparticles in water tend to agglomerate and form flocs which are broken with the shear force applied during viscosity measurement. The particle-particle interaction is very important in this system. In BECy, the particles appear to be well dispersed and not as interactive. The solvent-particle interaction appears to be most important. It is not known exactly how the alumina particles interact with the monomer, but NMR suggests hydrogen bonding. These hydrogen bonds between the particle and monomer could very well affect the viscosity. A conclusion that can be reached in this work is that the presence of hydroxyl groups on the surface of the alumina particles is significant and seems to affect the interactions between other particles and the solvent. Thus, the hydrogen bonding between particles, particle/additive and/or particle/solvent dictates the behavior of nanos

  4. RETENTION OF Cd, Cu, Pb AND Zn BY WOOD ASH, LIME AND FUME DUST

    E-Print Network [OSTI]

    Ma, Lena

    RETENTION OF Cd, Cu, Pb AND Zn BY WOOD ASH, LIME AND FUME DUST TAIT CHIRENJE1 , LENA Q. MA2 and ecosystem health. This study investigated the effectiveness of wood ash in immobilizing the heavy metals Pb, Cd, Cu and Zn from aqueous solutions. The effects of initial metal concentrations, solution pH, ash

  5. Low-temperature magnetron sputter-deposition, hardness, and electrical resistivity of amorphous and crystalline alumina thin films

    E-Print Network [OSTI]

    Marks, Laurence D.

    have many properties that are useful for applications in optical electronics, and cutting tool be coated with alumina. Therefore, low-temperature synthesis of crystalline alumina is of great

  6. Functionally graded alumina-based thin film systems

    DOE Patents [OSTI]

    Moore, John J.; Zhong, Dalong

    2006-08-29

    The present invention provides coating systems that minimize thermal and residual stresses to create a fatigue- and soldering-resistant coating for aluminum die casting dies. The coating systems include at least three layers. The outer layer is an alumina- or boro-carbide-based outer layer that has superior non-wettability characteristics with molten aluminum coupled with oxidation and wear resistance. A functionally-graded intermediate layer or "interlayer" enhances the erosive wear, toughness, and corrosion resistance of the die. A thin adhesion layer of reactive metal is used between the die substrate and the interlayer to increase adhesion of the coating system to the die surface.

  7. Method for thermal processing alumina-enriched spinel single crystals

    DOE Patents [OSTI]

    Jantzen, C.M.

    1995-05-09

    A process for age-hardening alumina-rich magnesium aluminum spinel to obtain the desired combination of characteristics of hardness, clarity, flexural strength and toughness comprises selection of the time-temperature pair for isothermal heating followed by quenching. The time-temperature pair is selected from the region wherein the precipitate groups have the characteristics sought. The single crystal spinel is isothermally heated and will, if heated long enough pass from its single phase through two pre-precipitates and two metastable precipitates to a stable secondary phase precipitate within the spinel matrix. Quenching is done slowly at first to avoid thermal shock, then rapidly. 12 figs.

  8. Silicon carbide whisker-zirconia reinforced mullite and alumina ceramics

    DOE Patents [OSTI]

    Becher, Paul F. (Oak Ridge, TN); Tiegs, Terry N. (Lenoir City, TN)

    1987-01-01

    The flexural strength and/or fracture toughness of SiC whisker-reinforced composites utilizing mullite or alumina as the matrix material for the composite are increased by the addition of zirconia in a monoclinic or tetragonal phase to the matrix. The zirconia addition also provides for a lower hot-pressing temperature and increases the flexural strength and/or fracture toughness of the SiC whisker-reinforced composites over SiC whisker-reinforced composites of the similar matrix materials reinforced with similar concentrations of SiC whiskers.

  9. Piperidine Adsorption on Hydrated r-Alumina (0001) Surface Studied by Vibrational Sum Frequency Generation

    E-Print Network [OSTI]

    the alumina (0001) surface through protonation by surface hydroxyl groups. The O-H stretching region the decrease of the surface number density of alumina surface hydroxyl groups. Introduction It is well known is a secondary amine. Secondary amines are common organic pollutants due to their extensive use

  10. Solvent mediated assembly of nanoparticles confined in mesoporous alumina Kyle J. Alvine,1,

    E-Print Network [OSTI]

    Pershan, Peter S.

    Solvent mediated assembly of nanoparticles confined in mesoporous alumina Kyle J. Alvine,1, * Diego solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering of solvent condensed from an under- saturated vapor. Analysis indicated that the nanoparticles self

  11. Processing and Mechanical Properties of Ti2AlC Reinforced with Alumina Fibers 

    E-Print Network [OSTI]

    Jeon, Kwonguk

    2012-10-19

    The fabrication and mechanical properties of Ti2AlC composites reinforced with the alumina oxide fibers, such as NextelTM 720 and ALBF1, were described in this thesis. Alumina fibers and Ti2AlC powders were dispersed in the water and slip cast...

  12. Testing of a Continuous Sampling Mercury CEM at the EPA-Rotary Kiln Incinerator Simulator Facility

    SciTech Connect (OSTI)

    D.P. Baldwin; S.J. Bajic; D.E. Eckels; D.S. Zamzow

    2002-04-12

    This report has been prepared to document the performance of the continuous sampling mercury monitoring system developed by Ames Laboratory for use as a continuous emission monitor (CEM). This work was funded by the U.S. Department of Energy, Office of Environmental Management, Office of Science and Technology, through the Mixed Waste Focus Area. The purpose of the project is to develop instrumentation and methods for spectroscopic field-monitoring applications. During FY01 this included continued development and testing of an echelle spectrometer system for the detection of mercury (Hg) by atomic absorption. Due to the relatively poor limits of detection for Hg by optical emission techniques, the CEM has been designed for the detection of elemental Hg by optical absorption. The sampling system allows continuous introduction of stack gas into the CEM for analysis of elemental and total Hg in the gas stream. A heated pyrolysis tube is used in this system to convert oxidized Hg compounds to elemental Hg prior to analysis for total Hg. The pyrolysis tube is bypassed to measure elemental Hg. The CEM is designed to measure the elemental Hg concentration of the gas sample, measure the total Hg concentration, perform a zero check (analysis of room air), and then re-zero the system (to correct for any instrumental drift that occurs over time). This is done in an automated, sequential measurement cycle to provide continuous monitoring of Hg concentrations in the stack gas. The continuous sampling Hg CEM was tested at the EPA-Rotary Kiln in Durham, NC at the beginning of FY02. This report describes the characteristics and performance of the system and the results of the field tests performed at EPA. The Hg CEM system was developed in response to the need of DOE and other organizations to monitor Hg that may be released during the processing or combustion of hazardous or mixed-waste materials. The promulgation of regulations limiting the release of Hg and requiring continuous monitoring of stack gases from combustion and treatment processes would seriously impact the operations of DOE waste treatment facilities. Therefore, it is important to develop and validate techniques that adequately meet proposed sensitivity and accuracy requirements. The most likely form of validation for such a technique involves comparison of CEM results with a reference test method for a test combustion system. Therefore, the CEM system was tested at EPA by monitoring Hg emissions in a natural gas combustion exhaust (that was spiked with Hg) while simultaneously collecting samples using the Ontario-Hydro mercury speciation method as the reference method. The CEM results were available continuously during the on-line monitoring that was performed. The results of the reference method sampling were received a number of weeks after the testing at EPA. These results are discussed in this report, with a comparison and evaluation of the reference method and Hg CEM data.

  13. Frank Blaisdell: Santa Cruz in the Early 1900s

    E-Print Network [OSTI]

    Regional History Project, UC Santa Cruz Library

    1967-01-01

    off the timber to burn lime, and then around those redwoodDavis and Jordan who had the lime kilns. And he bought outof course, for exporting his lime; now I've heard that other

  14. Industry

    E-Print Network [OSTI]

    Bernstein, Lenny

    2008-01-01

    the solar thermal production of lime. Energy, 29, pp. 811-821. Miller, M.M. , 2003: Lime. In 2003 Minerals Yearbook,greenhouse gas emissions from lime kilns at Kraft pulp

  15. The Majors Family and Santa Cruz County Dairying

    E-Print Network [OSTI]

    Regional History Project, UCSC Library; Major, Thomas; Calciano, Elizabeth Spedding

    1965-01-01

    hauling wood into his lime kiln. And he bad all Portuguesethat rock up and made lime out of it. The Cowell Familysaid you Majors: hauled lime for the Cowells? Well Cowell

  16. Chemical durability of soda-lime-aluminosilicate glass for radioactive waste vitrification

    SciTech Connect (OSTI)

    Eppler, F.H.; Yim, M.S. [North Carolina State Univ., Raleigh, NC (United States)

    1998-09-01

    Vitrification has been identified as one of the most viable waste treatment alternatives for nuclear waste disposal. Currently, the most popular glass compositions being selected for vitrification are the borosilicate family of glasses. Another popular type that has been around in glass industry is the soda-lime-silicate variety, which has often been characterized as the least durable and a poor candidate for radioactive waste vitrification. By replacing the boron constituent with a cheaper substitute, such as silica, the cost of vitrification processing can be reduced. At the same time, addition of network intermediates such as Al{sub 2}O{sub 3} to the glass composition increases the environmental durability of the glass. The objective of this study is to examine the ability of the soda-lime-aluminosilicate glass as an alternative vitrification tool for the disposal of radioactive waste and to investigate the sensitivity of product chemical durability to variations in composition.

  17. Solid-state NMR studies of the adsorption of acetylene on platinum/alumina catalysts 

    E-Print Network [OSTI]

    Lambregts, Marsha Jo Lupher

    1991-01-01

    /y-alumina and subsequently evacuated. 25 "C Bloch Decay/MAS NMR spectra of cyclohexane adsorbed onto 10%Pt/y-alumina. 27 FT mass spectra taken at a field strength of 3-Tesla. 28 CAVERN uC CP/MAS NMR spectra of an overpressure of acetylene on 10%Pt/y-alumina adsorbed... pumped two-section ion cell, an Extrel 2001 data system, and a 3-Tesla Oxford superconducting magnet. ~~ Samples were introduced into the cell by a variable leak valve (at sample pressure of 4 x 10' torr). Ionization was performed by electron impact...

  18. Acoustic phonon spectrum and thermal transport in nanoporous alumina arrays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kargar, Fariborz; Ramirez, Sylvester; Debnath, Bishwajit; Malekpour, Hoda; Lake, Roger; Balandin, Alexander A.

    2015-10-28

    We report results of a combined investigation of thermal conductivity and acoustic phonon spectra in nanoporous alumina membranes with the pore diameter decreasing from D=180 nm to 25 nm. The samples with the hexagonally arranged pores were selected to have the same porosity Ø ?13%. The Brillouin-Mandelstam spectroscopy measurements revealed bulk-like phonon spectrum in the samples with D=180-nm pores and spectral features, which were attributed to spatial confinement, in the samples with 25-nm and 40-nm pores. The velocity of the longitudinal acoustic phonons was reduced in the samples with smaller pores. As a result, analysis of the experimental data andmore »calculated phonon dispersion suggests that both phonon-boundary scattering and phonon spatial confinement affect heat conduction in membranes with the feature sizes D« less

  19. Optical Basicity and Nepheline Crystallization in High Alumina Glasses

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

    2011-02-25

    The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

  20. Evaluation of Composite Alumina Nanoparticle and Nitrate Eutectic Materials for use in Concentrating Solar Power Plants 

    E-Print Network [OSTI]

    Malik, Darren R.

    2010-07-14

    The focus of this research was to create and characterize high temperature alumina and nitrate salt eutectic nanofluids for use in thermal energy storage (TES) systems. The nitrate eutectic was originally used in the TES system demonstrated as part...

  1. Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia

    E-Print Network [OSTI]

    Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-01-01

    h) Figure 3. Example of ethane ODH (a) reaction rates and (x /Al 2 O 3 catalysts: (a) ethane ODH, (b) propane ODH (663Oxidative Dehydrogenation of Ethane and Propane on Alumina-

  2. The Effect of Nanoparticle Concentration on Thermo-physical Properties of Alumina-nitrate Nanofluid 

    E-Print Network [OSTI]

    Shao, Qian

    2013-02-15

    The objective of this study was to determine how Al2O3 nanoparticle concentration affected the specific heat, heat of fusion, melting point, thermal diffusivity and thermal conductivity of Alumina-Nitrate nanofluids. Al2O3 nanoparticles were...

  3. Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia

    E-Print Network [OSTI]

    Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-01-01

    catalysts: (a) ethane ODH, (b) propane ODH (663 K, 14 kPa CDehydrogenation of Ethane and Propane on Alumina-Supporteddehydrogenation of ethane and propane. UV-visible and Raman

  4. Templated self-assembly of nanoporous alumina : pore formation and ordering mechanisms, methodologies, and applications

    E-Print Network [OSTI]

    Krishnan, Ramkumar, 1975-

    2005-01-01

    Porous anodic aluminum oxide (AAO), also known as porous alumina, is a self-ordered nanostructured material well-suited for use in electronic, magnetic, optical and biological applications due to its small pore size (4-200nm) ...

  5. Phenomenological study of Au and Pt nanowires grown in porous alumina scaffolds

    E-Print Network [OSTI]

    Shin, Yong Cheol, S.M. Massachusetts Institute of Technology

    2011-01-01

    Porous anodic aluminum oxide, commonly known as AAO, has been widely used as a scaffold to synthesize nanowires and nanotubes. The porous alumina structure can be obtained from a simple electrochemical oxidation process, ...

  6. Structural studies of alumina pillared hectorite using polyvinyl alcohol as a pillaring agent 

    E-Print Network [OSTI]

    Kroenig, Andrea N

    1997-01-01

    In the present work, the structures of a natural hectorite clay pillared with alumina were studied. Frequently, polyvinyl alcohol (PVA) was added as a pillaring agent to observe structural differences in the calcined ...

  7. Development and Characterization of Novel Alumina Based Ceramic Matrix Composites for Energy Efficient Sliding Applications 

    E-Print Network [OSTI]

    Paluri, Rajeshwari S. Lakshmi

    2012-10-19

    where high wear resistance is required, such as pump bearings, seal rings, valve seats, piston components, gears, cutting tool inserts and artificial joints. We propose to develop a novel alumina based ceramic composite to enhance its surface...

  8. Mechanical Properties of a Graded Alumina-Zirconia Composite Prepared by Centrifugal Slip Casting

    SciTech Connect (OSTI)

    Hara, Yasuyuki; Onda, Tetsuhiko; Hayakawa, Motozo

    2008-02-15

    Compositionally graded composite of alumina-20 vol%zirconia was fabricated by using centrifugal casting incorporated with relatively thin slip. An EPMA analysis exhibited a nearly linear variation of the alumina/zirconia ratio along the centrifugal direction; zirconia tended to accumulate in the bottom section, while alumina in the top section. Such a graded structure exhibited a considerably higher flexural strength when the alumina rich surface was subjected to a tensile stress than compositionally uniform composite of the same average composition. Fracture toughness measurement across the specimen thickness by indentation method revealed that the crack lengths along the vertical and horizontal directions were different. The anisotropy of the fracture toughness was accounted for by the variation of the residual stress across the specimen thicknesss.

  9. Laboratory evaluation of limestone and lime neutralization of acidic uranium mill tailings solution. Progress report

    SciTech Connect (OSTI)

    Opitz, B.E.; Dodson, M.E.; Serne, R.J.

    1984-02-01

    Experiments were conducted to evaluate a two-step neutralization scheme for treatment of acidic uranium mill tailings solutions. Tailings solutions from the Lucky Mc Mill and Exxon Highland Mill, both in Wyoming, were neutralized with limestone, CaCO/sub 3/, to an intermediate pH of 4.0 or 5.0, followed by lime, Ca(OH)/sub 2/, neutralization to pH 7.3. The combination limestone/lime treatment methods, CaCO/sub 3/ neutralization to pH 4 followed by neutralization with Ca(OH)/sub 2/ to pH 7.3 resulted in the highest quality effluent solution with respect to EPA's water quality guidelines. The combination method is the most cost-effective treatment procedure tested in our studies. Neutralization experiments to evaluate the optimum solution pH for contaminant removal were performed on the same two tailings solutions using only lime Ca(OH)/sub 2/ as the neutralizing agent. The data indicate solution neutralization above pH 7.3 does not significantly increase removal of pH dependent contaminants from solution. Column leaching experiments were performed on the neutralized sludge material (the precipitated solid material which forms as the acidic tailings solutions are neutralized to pH 4 or above). The sludges were contacted with laboratory prepared synthetic ground water until several effluent pore volumes were collected. Effluent solutions were analyzed for macro ions, trace metals and radionuclides in an effort to evaluate the long term effectiveness of attenuating contaminants in sludges formed during solution neutralization. Neutralized sludge leaching experiments indicate that Ca, Na, Mg, Se, Cl, and SO/sub 4/ are the only constituents which show solution concentrations significantly higher than the synthetic ground water in the early pore volumes of long-term leaching studies.

  10. A study of the durability of lime as a stabilizing agent of clay soils 

    E-Print Network [OSTI]

    Wise, Harvey Earl

    1958-01-01

    tested for their strength in a triaxLal testing 4ovioe, using lateral pressures of ths same order as those used bp the Texas Highwgr Seysrtsmnt (15), Thop mare tested for their Atterberg limits to asoertain if thep nero still ha- flienoad bp the lime... of thks factor Fox ths first ssi3. , tho yexeentagaxof kins used moxa too~ four& sirv eight, and ten, For the second soils the percentages vere tao, ~ and ton It uas shomn l8 the test of the first eamyle that the same information could be obtaLnek RF...

  11. Method for fabricating cermets of alumina-chromium systems

    DOE Patents [OSTI]

    Morgan, Chester S. (Oak Ridge, TN)

    1983-01-01

    Cermet insulators resistant to thermal and mechanical shock are prepared from alumina-chromium systems by providing an Al.sub.2 O.sub.3 material of about 0.5 to 7.0 micron size with a solid-hydrocarbon overcoating by slurring an effective amount of said solid hydrocarbon in a solvent mixture containing said Al.sub.2 O.sub.3 and thereafter evaporating said solvent, contacting said coated Al.sub.2 O.sub.3 with a solution of chromium precursor compound, heating the resulting mixture in a reducing environment to a temperature above the decomposition temperature of said chromium precursor compound but less than the melting temperature of the Al.sub.2 O.sub.3 or chromium for sufficient duration to yield a particulate compound having chromium essentially dispersed throughout the Al.sub.2 O.sub.3, and then densifying said particulate to provide said cermet characterized by a theoretical density in excess of 96% and having 0.1 to 10.0 vol.% elemental chromium metal present therein as a dispersed phase at the boundaries of the Al.sub.2 O.sub.3 material. Cermet components prepared thereby are useful in high temperature equipment, advanced heat engines, and nuclear-related equipment applications where electrical or thermal insulators are required.

  12. Solvent Mediated Assembly of Nanoparticles Confined in Mesoporous Alumina

    E-Print Network [OSTI]

    Kyle J. Alvine; Diego Pontoni; Oleg G. Shpyrko; Peter S. Pershan; David J. Cookson; Kyusoon Shin; Thomas P. Russell; Markus Brunnbauer; Francesco Stellacci; Oleg Gang

    2006-03-24

    The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent condensed from an undersaturated vapor. Analysis indicated that the nanoparticles self-assembled into cylindrical monolayers within the porous template. Nanoparticle nearest-neighbor separation within the monolayer increased and the ordering decreased with the controlled addition of solvent. The process was reversible with the removal of solvent. Isotropic clusters of nanoparticles were also observed to form temporarily during desorption of the liquid solvent and disappeared upon complete removal of liquid. Measurements of the absorption and desorption of the solvent showed strong hysteresis upon thermal cycling. In addition, the capillary filling transition for the solvent in the nanoparticle-doped pores was shifted to larger chemical potential, relative to the liquid/vapor coexistence, by a factor of 4 as compared to the expected value for the same system without nanoparticles.

  13. Analysis of volatile contaminants in US Navy fleet soda lime. Technical report, August 1992-May 1995

    SciTech Connect (OSTI)

    Lillo, R.S.; Ruby, R.; Gummin, D.D.; Porter, W.R.; Caldwell, J.M.

    1995-06-01

    Contamination was suspected of U.S. Navy Fleet soda lime (High Performance Sodasorb(R)) when an ammonia-like odor was reported during its use in August 1992. This material contained indicator dye and was used for carbon dioxide absorption during diving. This incident had a major impact on the U.S Navy diving program when the Navy temporarily banned use of Sodasorb(R) and authorized Sofnolime(R) as an interim replacement. The Naval Medical Research Institute was immediately assigned to investigate. Testing involved sampling from the headspace (gas space) inside closed buckets and from an apparatus simulating conditions during operational diving. Volatile organic compounds were analyzed by gas chromatography and mass spectrometry; ammonia and amines were measured by infrared spectroscopy. Significant amounts of ammonia (up to 30 ppm), ethyl and diethyl amines (up to several ppm), and various aliphatic hydrocarbons (up to 60 ppm) were detected during testing of both Sodasorb(R) and Sofnolime(R). Contaminants were slowly removed by gas flow and did not return. The source(s) of the ammonia and amines are unknown, although they may result from the breakdown of the indicator dye. Hydrocarbon contamination appeared to result from the materials of which the bucket is constructed. Based on these findings, the U.S. Navy is expected to phase in non-indicating soda lime that will be required to meet defined contaminant limits.

  14. An investigation of the use of lime as a soil additive to modify the detrimental effects of frost action 

    E-Print Network [OSTI]

    Earnest, Clyde Talley

    1959-01-01

    AN INVESTIGATION OF THE USE OF LIME AS A SOIL ADDITIVE TO MODIFI THE DETfEMENTAL EFFECTS OF FROST ACTION GLIDE T. EARNEST~ JR. Captain~ Corps of Engineers Submitted to the Graduate School of the Agricultural and Mechanical College of Texas... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1959 Ma)or Sub)acts Civil Engineering AN INVESTIGATION OF THE USE OF LIME AS A SOIL ADDITIVE TO MODIFY THE DETRIMENTAL EFFECTS OF FROST ACTION A Thesis CLYDE T...

  15. Carlsbad Field Office

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D80 Landfill Acre-feet; Hectares-meter; Acres; Cubic Meters; Hectares; Cubic Yards T82 Lime Kiln D81 Land Treatment Acres or Hectares T83 Aggregate Kiln D82 Ocean Disposal Gallons...

  16. Processing of alumina-niobium interfaces via liquid-film-assistedjoining

    SciTech Connect (OSTI)

    McKeown, Joseph T.; Sugar, Joshua D.; Gronsky, Ronald; Glaeser,Andreas M.

    2005-02-15

    Alumina-niobium interfaces were fabricated at 1400 C via solid-state diffusion brazing of a 127-{micro}m-thick niobium foil between alumina blocks. Prior to brazing, some of the alumina mating surfaces, both polished and unpolished, were evaporation-coated with copper films {approx}1.4 {micro}m, {approx}3.0 {micro}m, and {approx}5.5 {micro}m thick to induce liquid-film-assisted joining at the brazing temperature. The effects of copper film thickness and surface roughness on fracture characteristics and ceramic-metal interfacial microstructure were investigated by room-temperature four-point bend tests, optical microscopy, profilometry, and atomic force microscopy. The average strength of bonds between niobium and polished alumina substrates increased with the introduction of copper film interlayers, and the scatter in strength tended to decrease, with an optimum combination of strength and Weibull modulus arising for a copper film thickness of 3.0 {micro}m. The strength characteristics of niobium bonded to unpolished alumina substrates were also improved by liquid-film-assisted joining, but were unaffected by the thickness of the copper interlayers.

  17. ATOMIC LAYER DEPOSITION OF TITANIUM OXIDE THIN FILMS ONNANOPOROUS ALUMINA TEMPLATES FOR MEDICAL APPLICATIONS

    SciTech Connect (OSTI)

    Brigmon, R.

    2009-05-05

    Nanostructured materials may play a significant role in controlled release of pharmacologic agents for treatment of cancer. Many nanoporous polymer materials are inadequate for use in drug delivery. Nanoporous alumina provides several advantages over other materials for use in controlled drug delivery and other medical applications. Atomic layer deposition was used to coat all the surfaces of the nanoporous alumina membrane in order to reduce the pore size in a controlled manner. Both the 20 nm and 100 nm titanium oxide-coated nanoporous alumina membranes did not exhibit statistically lower viability compared to the uncoated nanoporous alumina membrane control materials. In addition, 20 nm pore size titanium oxide-coated nanoporous alumina membranes exposed to ultraviolet light demonstrated activity against Escherichia coli and Staphylococcus aureus bacteria. Nanostructured materials prepared using atomic layer deposition may be useful for delivering a pharmacologic agent at a precise rate to a specific location in the body. These materials may serve as the basis for 'smart' drug delivery devices, orthopedic implants, or self-sterilizing medical devices.

  18. Hydrogen and the Structure of the Transition Aluminas Karl Sohlberg,*, Stephen J. Pennycook,, and Sokrates T. Pantelides,

    E-Print Network [OSTI]

    Pennycook, Steve

    , catalytic reduction of automotive pollutants such as nitric oxide (NOx), as well as oxidation of carbon in the behavior of aluminas in catalytic systems. 1. Introduction -Alumina is without question an enormously for such processes as olefin isomerization,11,12 alcohol dehydra- tion,13,14 and oxidation of organics15 are also

  19. Soil Acidity and Liming L. A. Redmon, M. L. McFarland, V. A. Haby, and D. H. Bade

    E-Print Network [OSTI]

    Soil Acidity and Liming L. A. Redmon, M. L. McFarland, V. A. Haby, and D. H. Bade Department of Soil and Crop Sciences The Agriculture Program The Texas A&M University System SCS-2001-06 What Causes SoilAcidity? Various environmental, climatic, and cultural factors can af- fect formation of acid soils

  20. Oxygen-Enriched Combustion; Industrial Technologies Program ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reheat, soaking pits, ladles Aluminum Melting Copper Smelting and melting Glass Melting Pulp and Paper Lime kilns, black liquor boilers Petroleum Process heaters, crackers Power...

  1. Energy Efficiency Improvement and Cost Saving Opportunities for the U.S. Iron and Steel Industry An ENERGY STAR(R) Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2011-01-01

    and Trends in the Pulp and Paper Industry. American Councilpulp and paper (paper stock, lime kiln), petroleum refineries (process, site), and steel industries (

  2. Energy Efficiency Improvement Opportunities for the Cement Industry

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01

    Lime Institute. 2001. Energy Efficiency Opportunity Guide inIndustry, Office of Energy Efficiency, Natural Resourcesof a Cement Kiln, Energy Efficiency Demonstration Scheme,

  3. Adsorption of carbonyl sulfide from liquid hydrocarbons with activated alumina and other adsorbents

    SciTech Connect (OSTI)

    Liu, P.K.T. (Alcoa Separations Technology Div., Aluminum Co. of America, Warrendale, PA (US))

    1988-01-01

    Contamination of Liquid hydrocarbon streams with carbonyl sulfide (COS) is not desirable; particularly in propylene. COS may poison the down stream polymerization catalyst. Thus, it is usually required to reduce the COS concentration to an extremely low level, e.g. 1 ppm or less, for polymer grade propylene. Many technologies generally available for sulfur removal, such as scrubbing and distillation are not applicable to the removal of COS from propylene. The former is not suitable for a low level removal. With the boiling point of COS (-50{sup 0}C) very close to that of propylene (-48{sup 0}C) it is difficult to achieve a very efficient separation with distillation. Adsorption technology provides a very energy efficient process in addition to its ability of the low level removal. Adsorbents selected in this study include activated carbon, molecular sieves, zinc oxide and activated alumina. The results show that activated alumina is far superior in both adsorption capacity and rate. An adsorption mechanism with activated alumina is proposed. It is believed that adsorption of COS takes place simultaneously with the hydrolysis of COS on the alumina surface. Adsorption isotherms of COS up to 100 ppm and the effect of moisture content are also addressed in this study.

  4. Materials Science and Engineering A 458 (2007) 101107 Fluxless silicon-to-alumina bonding using electroplated

    E-Print Network [OSTI]

    Chen, Zhongping

    2007-01-01

    electroplated Au­Sn­Au structure at eutectic composition Jong S. Kima, Won S. Choia,1, Dongwook Kima,2, Andrei successfully bonded to alumina substrates with electroplated Au/Sn/Au structure at the eutectic composition. Keywords: Fluxless bonding; Fluxless soldering; Soldering; Eutectic Au­Sn alloys; Electroplating 1

  5. Strong blue emission from anodic alumina membranes with ordered nanopore array

    E-Print Network [OSTI]

    Chen, Haydn H.

    Strong blue emission from anodic alumina membranes with ordered nanopore array G. S. Huang, X. L by anodization in oxalic acid showed a strong PL peak in the blue. Due to an obvious asymmetry, the PL peak can that the two blue PL bands originate from optical transitions in two kinds of different oxygen-deficient defect

  6. Molecular Dynamics Study of Silica-Alumina Interfaces Slawomir Blonski and Stephen H. Garofalini*

    E-Print Network [OSTI]

    Garofalini, Stephen H.

    production as well as from impurities present in the raw materials. Although the boundary phase occupies only* Department of Ceramics and Interfacial Molecular Science Laboratory, Institute for Engineered Materials ceramic materials today.1,2 Many of alumina properties are controlled by structure and stability of its

  7. Deformation Mechanisms in Compression-Loaded, Stand-Alone Plasma-Sprayed Alumina Coatings

    E-Print Network [OSTI]

    Trice, Rodney W.

    Deformation Mechanisms in Compression-Loaded, Stand-Alone Plasma-Sprayed Alumina Coatings Rodney W. It is proposed that the numerous defects in plasma- sprayed coatings, including porosity and microcracks, serve-SPRAYED coatings are frequently used as thermal-barrier coatings (TBCs) or wear-resistant coatings. Mechanical

  8. Electrical conductivity and current-voltage characteristics of alumina with or without neutron and electron irradiation

    E-Print Network [OSTI]

    Howlader, Matiar R

    irradiation. Radiation induced conductivity (RIC) was observed for all speci- mens under neutron and electron of the leading candidates for insula- tor and radiofrequency window/feedthrough applica- tions in magnetic fusion of alumina. Radiation induced conductivity (RIC) and radiation induced electrical de- gradation (RIED

  9. WRINKLING OF a-ALUMINA FILMS GROWN BY OXIDATIONII. OXIDE SEPARATION AND FAILURE

    E-Print Network [OSTI]

    Clarke, David R.

    of thermal cycling on these modes of separation and how they may lead to oxide spalling are discussed. # 1998WRINKLING OF a-ALUMINA FILMS GROWN BY OXIDATIONÐII. OXIDE SEPARATION AND FAILURE V. K. TOLPYGO oxidation and cooling to room temperature. One type is a form of buckling where the size of the detached

  10. Cuprous-chloride-modified nanoporous alumina membranes for ethylene-ethane separation

    SciTech Connect (OSTI)

    Lin, Y.S.; Wang, Y.; Ji, W.; Higgins, R.J.

    1999-06-01

    This paper reports an attempt to synthesize a CuCl-modified {gamma}-alumina membrane for separation of ethylene from ethane. CuCl was effectively coated in the 4 nm pore {gamma}-alumina top layers of disk-shaped and tubular alumina membranes by the reservoir method. Permeation of a single gas and binary mixture of ethylene and ethane was measured to characterize separation properties of the modified membranes. Pure ethylene permeance of the CuCl-modified membrane is 10--40% lower than that predicted from the pure ethane permeance by the Knudsen theory. This result is explained by a model based on the adsorbed layer of ethylene via {pi}-complexation. Such an adsorbed layer hinders the diffusion of ethylene in the nanopores of CuCl-modified {gamma}-alumina. Multiple gas permeation measurements on the CuCl-modified membranes show a separation factor for ethylene over ethane larger than the Knudsen value. This confirms a positive contribution of the surface flow of ethylene to the permeance of ethylene in the multiple gas permeation system. A maximum separation factor for ethylene over ethane of 1.4 is obtained for the CuCl-modified membrane at 60 C.

  11. STRESS-DENSITY VARIATIONS IN ALUMINA SEDIMENTS: EFFECTS OF POLYMER CHEMISTRY

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    present a novel approach for analyzing sediments by gamma-ray densitometry 1 and a fluid mechanics model151 STRESS-DENSITY VARIATIONS IN ALUMINA SEDIMENTS: EFFECTS OF POLYMER CHEMISTRY C. H. SCHILLING modification of interparticle forces by changing the chemistry of surface-adsorbed polymers or ions

  12. High-temperature hydroxylation of alumina crystalline surfaces Ramesh Chandrasekharan a

    E-Print Network [OSTI]

    High-temperature hydroxylation of alumina crystalline surfaces Ramesh Chandrasekharan a , Luning- talline surfaces (a, c and r) and subsequent hydroxylation. Samples heat-treated at a higher temperature spectra showed clearer spectral features of hydroxylation and higher degree of hydroxylation for heat

  13. Beryllium Adsorption at Transition Aluminas: Implications for Environmental Science and Oxidation of Aluminum Alloys

    SciTech Connect (OSTI)

    Sergey N. Rashkeev; Michael V. Glazoff

    2010-08-01

    It is demonstrated that?gamma- and?eta- aluminas (transition Al2O3 polytypes with defect spinel structure) can effectively capture beryllium atoms. Although the bulk crystal structures of these two oxides are characterized only by slight differences in cation vacancy distributions, the interaction of Be with the two polytypes are different. For gamma- Al2O3, the Be adsorption energy is high (~ 5 eV per atom), and all Be atoms are captured and trapped at the surface - all attempts to move Be in the subsurface region result in its expulsion back to the surface. On the other hand, for ?eta- alumina Be atoms can be captured both at the surface and in octahedrally-coordinated subsurface cation vacancies. This result implies that both alumina oxides could be successfully used for Be capture out of wastewater streams related to industrial processes of aluminum and alumina production. Also, the surface adsorption mechanism of Be at?gamma- Al2O3 explains why very small additions of Be (of the order of several ppm) to Al-Mg and Al-Mg-Si casting and wrought alloys prevent run-away oxidation of these materials in molten state, as well as ingot cracking. We also discuss possibilities to use other additives (e.g., Ca and Sr) yielding the same protective effect for aluminum alloys but which are less toxic than beryllium.

  14. Effect of testing conditions and doping on superplastic creep of alumina

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    716 Effect of testing conditions and doping on superplastic creep of alumina P. Gruffel, P. Carry. pressive creep tests at 1450 °C [3]. It was un- ambiguously established that: - normal grain growth took superplastic deformation. Fig. 1. Strain rate variations during creep tests in compression C and tension

  15. Surface preparation for high purity alumina ceramics enabling direct brazing in hydrogen atmospheres

    DOE Patents [OSTI]

    Cadden, Charles H. (Danville, CA); Yang, Nancy Yuan Chi (Lafayette, CA); Hosking, Floyd M. (Albuquerque, NM)

    2001-01-01

    The present invention relates to a method for preparing the surface of a high purity alumina ceramic or sapphire specimen that enables direct brazing in a hydrogen atmosphere using an active braze alloy. The present invention also relates to a method for directly brazing a high purity alumina ceramic or sapphire specimen to a ceramic or metal member using this method of surface preparation, and to articles produced by this brazing method. The presence of silicon, in the form of a SiO.sub.2 -containing surface layer, can more than double the tensile bond strength in alumina ceramic joints brazed in a hydrogen atmosphere using an active Au-16Ni-0.75 Mo-1.75V filler metal. A thin silicon coating applied by PVD processing can, after air firing, produce a semi-continuous coverage of the alumina surface with a SiO.sub.2 film. Room temperature tensile strength was found to be proportional to the fraction of air fired surface covered by silicon-containing films. Similarly, the ratio of substrate fracture versus interface separation was also related to the amount of surface silicon present prior to brazing. This process can replace the need to perform a "moly-manganese" metallization step.

  16. Synthesis of High Surface Area Alumina Aerogels without the Use of Alkoxide Precursors

    SciTech Connect (OSTI)

    Baumann, T F; Gash, A E; Chinn, S C; Sawvel, A M; Maxwell, R S; Satcher Jr., J H

    2004-06-25

    Alumina aerogels were prepared through the addition of propylene oxide to aqueous or ethanolic solutions of hydrated aluminum salts, AlCl{sub 3} {center_dot} 6H{sub 2}O or Al(NO{sub 3}){sub 3} {center_dot} 9H{sub 2}O, followed by drying with supercritical CO{sub 2}. This technique affords low-density (60-130 kg/m{sup 3}), high surface area (600-700 m{sup 2}/g) alumina aerogel monoliths without the use of alkoxide precursors. The dried alumina aerogels were characterized using elemental analysis, high-resolution transmission electron microscopy, powder X-ray diffraction, solid state NMR, acoustic measurements and nitrogen adsorption/desorption analysis. Powder X-ray diffraction and TEM analysis indicated that the aerogel prepared from hydrated AlCl{sub 3} in water or ethanol possessed microstructures containing highly reticulated networks of pseudoboehmite fibers, 2-5 nm in diameter and of varying lengths, while the aerogels prepared from hydrated Al(NO{sub 3}){sub 3} in ethanol were amorphous with microstructures comprised of interconnected spherical particles with diameters in the 5-15 nm range. The difference in microstructure resulted in each type of aerogel displaying distinct physical and mechanical properties. In particular, the alumina aerogels with the weblike microstructure were far more mechanically robust than those with the colloidal network, based on acoustic measurements. Both types of alumina aerogels can be transformed to {gamma}-Al{sub 2}O{sub 3} through calcination at 800 C without a significant loss in surface area or monolithicity.

  17. Investigation of the benefits of carbonate cementation due to addition of low percentage of hydrated lime in the base courses of pavements 

    E-Print Network [OSTI]

    Bhuiyan, Jasim Uddin

    1994-01-01

    Texas, limestone and caliche soil, were tested extensively to examine the effect of carbonate cementation due to the addition of small percentages of lime. Testing included mineralogical analysis of the two materials, strength analysis in terms of texas...

  18. The Drink Menu Admiral Nelson 1 oz rum, 1 oz gin, 2 tsp triple sec, dash of lime juice.

    E-Print Network [OSTI]

    Tuba, Imre

    or Sprite to fill. Gin and Tonic 1.5 oz gin, tonic water to fill, lime wedge. Green Mamba ***** Named after the green mamba whose poison is so powerful it has to worry about its victim falling on it. The recipe Collins 1.5 oz bourbon, 1 oz sour mix, and seltzer water to fill. Long Island Iced Tea 1/3 oz gin, 1 oz

  19. Comparison of lime and iron oxide for high temperature sulfur removal. Final technical report, September 1, 1989--December 31, 1991

    SciTech Connect (OSTI)

    Reid, K.J.; Hepworth, M.T.; Reindl, W.

    1994-05-01

    Slagging combustors with injected lime or limestone are being considered as replacements for conventional coal burners. They have advantages in that they can be staged to reduce NO{sub X} and SO{sub X} emissions. Lime and limestone are the currently preferred sorbent materials but iron oxide, as an alternative to lime or limestone may be effective not only as a desulfurization agent, but, under the right conditions of oxygen potential, it can act as a flux to produce a glassy slag. This glassy slag should be dense and environmentally inert. This project aimed to compare the sorption characteristic of lime and iron based sorbents in a novel double vortex combustor. The first phase of the project was the design installation and commissioning of the combustor test rig following which sorbent test work could be carried out. Due to a variety of unknown factors in the combustor design/performance characteristics, it was not possible to complete all aspects of the sorbent test work as originally planned. A considerable amount of experience has been gained in the operation of the combustor and in understanding the importance of key design factors. It was found that a narrow conical design for the combustor body gave significant improvement in combustion performance and in solids entrainment compared to a cylindrical form. Tests with a glass combustor were used extensively to obtain visual insights into flame flow patterns, structural stability and general operating characteristics. Due to time pressure and termination of the project no material balance was possible on the final sulfur run. Visual examination of the solids product did however, indicate that surface modification of the taconite particles had occurred and that an Fe-O-S phase had formed. The project has stimulated the interest of the local power utilities and it is planned to move the system to a local power plant for continuing test work.

  20. Chemically sensitive polymer-mediated nanoporous alumina SAW sensors for the detection of vapor-phase analytes 

    E-Print Network [OSTI]

    Perez, Gregory Paul

    2005-08-29

    We have investigated the chemical sensitivity of nanoporous (NP) alumina-coated surface acoustic wave (SAW) devices that have been surface-modified with polymeric mediating films. The research in this dissertation covers the refinement of the NP...

  1. The effect of competition by chloride and sulfate anions on the adsorption of arsenate ion onto activated alumina 

    E-Print Network [OSTI]

    Janis, Patrick John

    2000-01-01

    Interactions of arsenate ions with sulfate and chloride anions in aqueous solutions containing various amounts of activated alumina were studied in the laboratory on a batch mode basis with the goal of understanding the competition of the anions...

  2. Thermal cycling effect on the nanoparticle distribution and specific heat of a carbonate eutectic with alumina nanoparticles 

    E-Print Network [OSTI]

    Shankar, Sandhya

    2011-08-08

    The objective of this research was to measure the effect of thermal cycling on the nanoparticle distribution and specific heat of a nanocomposite material consisting of a eutectic of lithium carbonate and potassium carbonate and 1% by mass alumina...

  3. Consolidation Behavior of Flocculated Alumina Suspensions Lennart Bergstrom,*~+Christopher H. Schilling,*,iand Ilhan A. Aksay*,+

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    . Schilling,*,iand Ilhan A. Aksay*,+ 98195 99352 Department of Materials Science and Engineering, LJniversity alumina-zirconia slurry took place during centrifugal consolidation. However, when a flocculated suspen

  4. Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts

    DOE Patents [OSTI]

    Singleton, Alan H. (Baden, PA); Oukaci, Rachid (Gibsonia, PA); Goodwin, James G. (Gibsonia, PA)

    2001-01-01

    Cobalt catalysts, and processes employing these inventive catalysts, for hydrocarbon synthesis. The inventive catalyst comprises cobalt on an alumina support and is not promoted with any noble or near noble metals. In one aspect of the invention, the alumina support preferably includes a dopant in an amount effective for increasing the activity of the inventive catalyst. The dopant is preferably a titanium dopant. In another aspect of the invention, the cobalt catalyst is preferably reduced in the presence of hydrogen at a water vapor partial pressure effective to increase the activity of the cobalt catalyst for hydrocarbon synthesis. The water vapor partial pressure is preferably in the range of from 0 to about 0.1 atmospheres.

  5. Direct visualization of the hydration layer on alumina nanoparticles with the fluid cell STEM in situ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Firlar, Emre; Ç?nar, Simge; Kashyap, Sanjay; Akinc, Mufit; Prozorov, Tanya

    2015-05-21

    Rheological behavior of aqueous suspensions containing nanometer-sized powders is of relevance to many branches of industry. Unusually high viscosities observed for suspensions of nanoparticles compared to those of micron size powders cannot be explained by current viscosity models. Formation of so-called hydration layer on alumina nanoparticles in water was hypothesized, but never observed experimentally. We report here on the direct visualization of aqueous suspensions of alumina with the fluid cell in situ. We observe the hydration layer formed over the particle aggregates and show that such hydrated aggregates constitute new particle assemblies and affect the flow behavior of the suspensions.more »We discuss how these hydrated nanoclusters alter the effective solid content and the viscosity of nanostructured suspensions. Our findings elucidate the source of high viscosity observed for nanoparticle suspensions and are of direct relevance to many industrial sectors including materials, food, cosmetics, pharmaceutical among others employing colloidal slurries with nanometer-scale particles.« less

  6. The Effect of Excimer Laser Treatment on the Surface Roughness and Fracture Strength of Alumina Substrates

    SciTech Connect (OSTI)

    Smoot, J.E.

    1998-05-13

    The microelectronics industry requires alumina substrates with exceptionally smooth surfaces and few surface defects to allow successful deposition of metallic films for reliable electronic performance. Irradiation by a 248-nm wavelength excimer laser beam (KrF) at a fluence of 125 mJ/mm{sup 2} and at various angles of incidence is shown to significantly reduce the surface roughness of alumina substrates. However, irradiation also creates a fine particulate deposit of alumina that only partially adheres to the substrate and impedes deposition of metal films. Annealing in air between 1350 C and 1450 C was found to remove the particles by sintering. As-received material showed surface roughness average (R{sub a}) mean values of 457 nm, which was reduced to 60 nm (mean) following irradiation and 71 nm (mean) following irradiation and annealing at 1350 C. Irradiation also produced a decrease in the number and severity of surface defects. The flexural strength and Weibull modulus were both increased by laser irradiation and thermal treatment. Flexural strength went from an as-received value of 450 MPa to 560 MPa following irradiation/sintering, measured at 10% probability of failure. The Weibull modulus was increased from the as-received value of about 9, to about 13 following irradiation/sintering. It was concluded that irradiation at an angle of incidence of 60{degree} from perpendicular was most effective in producing a low surface roughness.

  7. Hydrogen Selective Thin Palladium-Copper Composite Membranes on Alumina Supports

    SciTech Connect (OSTI)

    Lim, Hankwon; Oyama, S. Ted

    2011-08-15

    Thin and defect-free Pd–Cu composite membranes with high hydrogen permeances and selectivities were prepared by electroless plating of palladium and copper on porous alumina supports with pore sizes of 5 and 100 nm coated with intermediate layers. The intermediate layers on the 100 nm supports were prepared by the deposition of boehmite sols of different particle sizes, and provided a graded, uniform substrate for the formation of defect-free, ultra-thin palladium composite layers. The dependence of hydrogen flux on pressure difference was studied to understand the dominant mechanism of hydrogen transport through a Pd–Cu composite membrane plated on an alumina support with a pore size of 5 nm. The order in hydrogen pressure was 0.98, and indicated that bulk diffusion through the Pd–Cu layer was fast and the overall process was limited by external mass-transfer or a surface process. Scanning electron microscopy (SEM) images of the Pd–Cu composite membrane showed a uniform substrate created after depositing one intermediate layer on top of the alumina support and a dense Pd–Cu composite layer with no visible defects. Cross-sectional views of the membrane showed that the Pd–Cu composite layer had a top layer thickness of 160 nm (0.16 ?m), which is much thinner than previously reported.

  8. Resources, Conservation and Recycling 54 (2010) 878892 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Aydilek, Ahmet

    2010-01-01

    stabilization Lime kiln dust Base course a b s t r a c t Fly ashes produced by power plants in the United StatesResources, Conservation and Recycling 54 (2010) 878­892 Contents lists available at Science with another recycled material, lime kiln dust (LKD). California bearing ratio (CBR) and resilient modulus

  9. Time-resolved measurement of photon emission during fast crack propagation in three-point bending fracture of silica glass and soda lime glass

    SciTech Connect (OSTI)

    Shiota, Tadashi, E-mail: tshiota@ceram.titech.ac.jp; Sato, Yoshitaka; Yasuda, Kouichi [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1-S7-13 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan)] [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1-S7-13 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan)

    2014-03-10

    Simultaneous time-resolved measurements of photon emission (PE) and fast crack propagation upon bending fracture were conducted in silica glass and soda lime glass. Observation of fracture surfaces revealed that macroscopic crack propagation behavior was similar between the silica glass and soda lime glass when fracture loads for these specimens were comparable and cracks propagated without branching. However, a large difference in the PE characteristics was found between the two glasses. In silica glass, PE (645–655?nm) was observed during the entire crack propagation process, whereas intense PE (430–490?nm and 500–600?nm) was observed during the initial stages of propagation. In contrast, only weak PE was detected in soda lime glass. These results show that there is a large difference in the atomic processes involved in fast crack propagation between these glasses, and that PE can be used to study brittle fracture on the atomic scale.

  10. Numerical simulation of alumina spraying in argon-helium plasma jet

    SciTech Connect (OSTI)

    Chang, C.H.

    1992-01-01

    A new numerical model is described for simulating thermal plasmas containing entrained particles, with emphasis on plasma spraying applications. The plasma is represented as a continuum multicomponent chemically reacting ideal gas, while the particles are tracked as discrete Lagrangian entities coupled to the plasma. Computational results are presented from a transient simulation of alumina spraying in a turbulent argon-helium plasma jet in air environment, including torch geometry, substrate, and multiple species with chemical reactions. Particle-plasma interactions including turbulent dispersion have been modeled in a fully self-consistent manner. Interactions between the plasma and the torch and substrate walls are modeled using wall functions. (15 refs.)

  11. Numerical simulation of alumina spraying in argon-helium plasma jet

    SciTech Connect (OSTI)

    Chang, C.H.

    1992-08-01

    A new numerical model is described for simulating thermal plasmas containing entrained particles, with emphasis on plasma spraying applications. The plasma is represented as a continuum multicomponent chemically reacting ideal gas, while the particles are tracked as discrete Lagrangian entities coupled to the plasma. Computational results are presented from a transient simulation of alumina spraying in a turbulent argon-helium plasma jet in air environment, including torch geometry, substrate, and multiple species with chemical reactions. Particle-plasma interactions including turbulent dispersion have been modeled in a fully self-consistent manner. Interactions between the plasma and the torch and substrate walls are modeled using wall functions. (15 refs.)

  12. Response of rice to ammonium and nitrate nitrogen applied at various stages of plant growth on limed and unlimed Beaumont and Lake Charles clays 

    E-Print Network [OSTI]

    Gay, William Blalock, III

    1962-01-01

    and Patna1k (1 ) partially support th1s explanation. They found that lime at ths rate of one percent of the weight of the so11 increased mineralisat1on of nitrogen, but most of the n1trogen in their tests accumulated as ammonia rather than nitrate under...RESPONSE OF RICE TO AMMONIUM AND NITRATE NITROGEN APPLIED AT VARIOUS STAGES OF PLANT GROWTH ON LIMED AND UNLINED BEAUNONT AND LAKE CHARLES CLAYS A Thesis By William B. Gay, III Submitted to the Graduate Sohool of the Agricultural...

  13. Hydrodesulfurization of dibenzothiophene catalyzed by alumina-supported ruthenium carbonyl complexes in a pressurized flow system

    SciTech Connect (OSTI)

    NONE

    1994-11-01

    Ruthenium sulfide has been found to be most active for hydrodesulfurization (HDS) of thiophenes as well as hydrogenation and hydrodenitrogenation among transition metal sulfides. When ruthenium sulfide is supported on alumina, silica, or zeolite with high surface area, highly dispersed ruthenium sulfide formed on the supports would increase the catalytic activity per a ruthenium atom. Several researchers have already reported HDS using supported ruthenium sulfides. In these works [Ru(NH{sub 3}){sub 6}]{sup +}, Ru{sub 3}(CO){sub 12}, RuCl{sub 3}, and Ru(III) acetate supported on alumina, zeoliate, carbon, etc., were used as catalyst precursors in HDS of thiophene, benzothiophene, or dibenzothiophene. Although these HDS reactions were performed under an atmospheric pressure, the activity of the catalysts derived from supported ruthenium in a pressurized flow system have not yet been understood. In the present study, HDS of DBT catalyzed by ruthenium catalysts is investigated in a pressurized flow reactor. 17 refs., 2 figs., 2 tabs.

  14. Direct visualization of the hydration layer on alumina nanoparticles with the fluid cell STEM in situ

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Firlar, Emre; Ç?nar, Simge; Kashyap, Sanjay; Akinc, Mufit; Prozorov, Tanya

    2015-05-21

    Rheological behavior of aqueous suspensions containing nanometer-sized powders is of relevance to many branches of industry. Unusually high viscosities observed for suspensions of nanoparticles compared to those of micron size powders cannot be explained by current viscosity models. Formation of so-called hydration layer on alumina nanoparticles in water was hypothesized, but never observed experimentally. We report here on the direct visualization of aqueous suspensions of alumina with the fluid cell in situ. We observe the hydration layer formed over the particle aggregates and show that such hydrated aggregates constitute new particle assemblies and affect the flow behavior of the suspensions.more »We discuss how these hydrated nanoclusters alter the effective solid content and the viscosity of nanostructured suspensions. As a result, our findings elucidate the source of high viscosity observed for nanoparticle suspensions and are of direct relevance to many industrial sectors including materials, food, cosmetics, pharmaceutical among others employing colloidal slurries with nanometer-scale particles.« less

  15. Characterization of the alumina-zirconia ceramic system by ultrasonic velocity measurements

    SciTech Connect (OSTI)

    Carreon, Hector; Ruiz, Alberto; Medina, Ariosto; Barrera, Gerardo; Zarate, Juan

    2009-08-15

    In this work an alumina-zirconia ceramic composites have been prepared with {alpha}-Al{sub 2}O{sub 3} contents from 10 to 95 wt.%. The alumina-zirconia ceramic system was characterized by means of precise ultrasonic velocity measurements. In order to find out the factors affecting the variation in wave velocity, the ceramic composite have been examined by X-ray diffraction (XRD) and (SEM) scanning electron microscopy. It was found that the ultrasonic velocity measurements changed considerably with respect to the ceramic composite composition. In particular, we studied the behavior of the physical material property hardness, an important parameter of the ceramic composite mechanical properties, with respect to the variation in the longitudinal and shear wave velocities. Shear wave velocities exhibited a stronger interaction with microstructural and sub-structural features as compared to that of longitudinal waves. In particular, this phenomena was observed for the highest {alpha}-Al{sub 2}O{sub 3} content composite. Interestingly, an excellent correlation between ultrasonic velocity measurements and ceramic composite hardness was observed.

  16. A High Temperature Electrochemical Energy Storage System Based on Sodium Beta-Alumina Solid Electrolyte (Base)

    SciTech Connect (OSTI)

    Anil Virkar

    2008-03-31

    This report summarizes the work done during the period September 1, 2005 and March 31, 2008. Work was conducted in the following areas: (1) Fabrication of sodium beta{double_prime} alumina solid electrolyte (BASE) using a vapor phase process. (2) Mechanistic studies on the conversion of {alpha}-alumina + zirconia into beta{double_prime}-alumina + zirconia by the vapor phase process. (3) Characterization of BASE by X-ray diffraction, SEM, and conductivity measurements. (4) Design, construction and electrochemical testing of a symmetric cell containing BASE as the electrolyte and NaCl + ZnCl{sub 2} as the electrodes. (5) Design, construction, and electrochemical evaluation of Na/BASE/ZnCl{sub 2} electrochemical cells. (6) Stability studies in ZnCl{sub 2}, SnCl{sub 2}, and SnI{sub 4} (7) Design, assembly and testing of planar stacks. (8) Investigation of the effect of porous surface layers on BASE on cell resistance. The conventional process for the fabrication of sodium ion conducting beta{double_prime}-alumina involves calcination of {alpha}-alumina + Na{sub 2}CO{sub 3} + LiNO{sub 3} at 1250 C, followed by sintering powder compacts in sealed containers (platinum or MgO) at {approx}1600 C. The novel vapor phase process involves first sintering a mixture of {alpha}-alumina + yttria-stabilized zirconia (YSZ) into a dense ceramic followed by exposure to soda vapor at {approx}1450 C to convert {alpha}-alumina into beta{double_prime}-alumina. The vapor phase process leads to a high strength BASE, which is also resistant to moisture attack, unlike BASE made by the conventional process. The PI is the lead inventor of the process. Discs and tubes of BASE were fabricated in the present work. In the conventional process, sintering of BASE is accomplished by a transient liquid phase mechanism wherein the liquid phase contains NaAlO{sub 2}. Some NaAlO{sub 2} continues to remain at grain boundaries; and is the root cause of its water sensitivity. In the vapor phase process, NaAlO{sub 2} is never formed. Conversion occurs by a coupled transport of Na{sup +} through BASE formed and of O{sup 2-} through YSZ to the reaction front. Transport to the reaction front is described in terms of a chemical diffusion coefficient of Na{sub 2}O. The conversion kinetics as a function of microstructure is under investigation. The mechanism of conversion is described in this report. A number of discs and tubes of BASE have been fabricated by the vapor phase process. The material was investigated by X-ray diffraction (XRD), optical microscopy and scanning electron microscopy (SEM), before and after conversion. Conductivity (which is almost exclusively due to sodium ion transport at the temperatures of interest) was measured. Conductivity was measured using sodium-sodium tests as well as by impedance spectroscopy. Various types of both planar and tubular electrochemical cells were assembled and tested. In some cases the objective was to determine if there was any interaction between the salt and BASE. The interaction of interest was mainly ion exchange (possible replacement of sodium ion by the salt cation). It was noted that Zn{sup 2+} did not replace Na+ over the conditions of interest. For this reason much of the work was conducted with ZnCl{sub 2} as the cathode salt. In the case of Sn-based, Sn{sup 2+} did ion exchange, but Sn{sup 4+} did not. This suggests that Sn{sup 4+} salts are viable candidates. These results and implications are discussed in the report. Cells made with Na as the anode and ZnCl{sub 2} as the cathode were successfully charged/discharged numerous times. The key advantages of the batteries under investigation here over the Na-S batteries are: (1) Steel wool can be used in the cathode compartment unlike Na-S batteries which require expensive graphite. (2) Planar cells can be constructed in addition to tubular, allowing for greater design flexibility and integration with other devices such as planar SOFC. (3) Comparable or higher open circuit voltage (OCV) than the Na-S battery. (4) Wider operating temperature range and higher temper

  17. Method for preparing configured silicon carbide whisker-reinforced alumina ceramic articles

    DOE Patents [OSTI]

    Tiegs, Terry N. (Lenoir City, TN)

    1987-01-01

    A ceramic article of alumina reinforced with silicon carbide whiskers suitable for the fabrication into articles of complex geometry are provided by pressureless sintering and hot isostatic pressing steps. In accordance with the method of the invention a mixture of 5 to 10 vol. % silicon carbide whiskers 0.5 to 5 wt. % of a sintering aid such as yttria and the balance alumina powders is ball-milled and pressureless sintered in the desired configuration in the desired configuration an inert atmosphere at a temperature of about 1800.degree. C. to provide a self-supporting configured composite of a density of at least about 94% theoretical density. The composite is then hot isostatically pressed at a temperature and pressure adequate to provide configured articles of at least about 98% of theoretical density which is sufficient to provide the article with sufficient strength and fracture toughness for use in most structural applications such as gas turbine blades, cylinders, and other components of advanced heat engines.

  18. Materials Science and Engineering A252 (1998) 117132 Optimization of 316 stainless steel/alumina functionally graded

    E-Print Network [OSTI]

    Grujicic, Mica

    1998-01-01

    Materials Science and Engineering A252 (1998) 117­132 Optimization of 316 stainless steel/alumina functionally graded material for reduction of damage induced by thermal residual stresses M. Grujicic *, H. Zhao Program in Materials Science and Engineering, Department of Mechanical Engineering, 241 Flour

  19. Electrical conductivity of Wesgo AL995 alumina under fast electron irradiation in a high voltage electron microscope

    E-Print Network [OSTI]

    Howlader, Matiar R

    of magnitude than its requirement for the magnetic coils in the international thermonuclear experimental to be a potential insulating mate- rial for numerous applications in fusion devices for heating and current drive degradation RIED 2 of alumina under irradiation are the critical issues for its application to fusion devices

  20. Signicance of sample thickness and surface segregation on the electrical conductivity of Wesgo AL995 alumina under ITER

    E-Print Network [OSTI]

    Howlader, Matiar R

    are expected to be used in fusion reactors like international thermonuclear experimental reactor (ITER insulating material in fusion reactors [1] because of its high thermal conductivity [2], high resistance of alumina are to be used in fusion reactors, no studies have ever been done on the thickness dependence

  1. Neutron Reflection Study of the Adsorption of the Phosphate Surfactant NaDEHP onto Alumina from Water

    E-Print Network [OSTI]

    Welbourn, Rebecca J. L.; Lee, Seung Yeon; Gutfreund, Philipp; Hughes, Arwel; Zarbakhsh, Ali; Clarke, Stuart M.

    2015-03-11

    The adsorption of a phosphorus analogue of the surfactant AOT, sodium bis(2-ethylhexyl) phosphate (NaDEHP), at the water/alumina interface is described. The material is found to adsorb as an essentially water-free bilayer from neutron reflection...

  2. Fracture and Fatigue Behavior at Ambient and Elevated Temperatures of Alumina Bonded with Copper/Niobium/Copper Interlayers

    E-Print Network [OSTI]

    Ritchie, Robert

    Fracture and Fatigue Behavior at Ambient and Elevated Temperatures of Alumina Bonded with Copper and Engineering, University of California, Berkeley, California 94720 Interfacial fracture toughness and cyclic temperatures, and assessed in terms of interfacial chemistry and microstructure. The mean interfacial fracture

  3. Effects of Adsorbed Pyridine Derivatives and Ultrathin Atomic-Layer-Deposited Alumina Coatings on the Conduction Band-Edge Energy

    E-Print Network [OSTI]

    Effects of Adsorbed Pyridine Derivatives and Ultrathin Atomic-Layer- Deposited Alumina Coatings the adsorption of t-butylpyridine and the atomic- layer deposition of ultrathin conformal coatings of insulators and the concomitant suppression of dark current does not require the coordination of surface Ti(IV) or Al(III) atoms

  4. Materials Science and Engineering A 435436 (2006) 468473 Fabrication of transparent alumina (Al2O3) nanofibers by electrospinning

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    2006-01-01

    3) nanofibers by electrospinning Abdul-Majeed Azad Department of Chemical and Environmental B.V. All rights reserved. Keywords: Alumina; Nanofibers; Electrospinning; Electron microscopy 1. Introduction Electrospinning (e-spinning) is one of bottom-up approaches that are gaining increasing attention

  5. Materials Science and Engineering A 493 (2008) 256260 In situ bend testing of niobium-reinforced alumina nanocomposites

    E-Print Network [OSTI]

    Ritchie, Robert

    2008-01-01

    pathways [5]. If the frac- ture toughness can be improved, ceramic matrix composites (CMCs) hold great the stress field around the crack tip. The addition of fibers to a brittle ceramic matrix can improve of carbon nanotubes to nanocrystalline alumina (Al2O3) bene- fits the brittle ceramic's mechanical

  6. Mechanical and Electrical Properties of Multiwalled CNT-Alumina Nanocomposites Prepared by a Sequential Two-Step Processing of Ultrasonic

    E-Print Network [OSTI]

    Hong, Soon Hyung

    improve the brittleness and electrical properties of ceramic materials; however, the agglomeration of CNTs during in the synthetic process and the poor interfacial bonding between CNTs and matrix materials still present challenges. Herein, multiwalled carbon nanotube (MWNT)-alumina composites were prepared

  7. Oxidation Reaction Induced Structural Changes in Sub-Nanometer Platinum Supported on Alumina

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    DeBusk, Melanie Moses; Allard, Jr, Lawrence Frederick; Blom, Douglas Allen; Narula, Chaitanya Kumar

    2015-06-26

    Platinum supported on alumina is an essential component of emission treatment catalysts used in transportation. Theoretical, experimental, and mechanistic aspects of platinum particles supported on a variety of supports have been extensively studied; however, available experimental information on the behavior of single vs. sub-nanometer platinum is extremely limited. To bridge the knowledge gap between single supported platinum and well-formed supported platinum nanoparticles, we have carried out synthesis, characterization, and CO and NO oxidation studies of sub-nanometer platinum supported on ?, ?, and ?-Al2O3 and monitored changes in structure upon exposure to CO and NO oxidation conditions. We find that sub-nanometermore »Pt is highly effective for CO oxidation due to high platinum dispersion but is not very efficient as NO oxidation catalyst. Furthermore, sub-nanometer platinum agglomerates rapidly under CO or NO oxidation conditions to form nanoparticles.« less

  8. Structure, Stoichiometry and Stability in Magnetoplumbite and {beta}-Alumina Structured Type Ceramics. Final Report

    SciTech Connect (OSTI)

    Cormack, A. N.

    2004-03-01

    Work has been completed on the atomistic simulation of hexa-aluminate ceramics with the magnetoplumbite and beta-alumina type structures. In this report, three aspects of the work are highlighted. One is the simulation of surface structures. The second concerns details of the interstitially mechanisms observed in molecular dynamics simulations. The novel result here is the observation that the lattice ion always leaves its Beevers-Ross site before the aBR interstitial begins to move towards the lattice site. It is also found that, as expected, the interstitial mechanism is the most common mechanism in the heavily disordered nonstoichiometric structure, as well as in the stoichiometric material. Finally, the disposition of trivalent europium in the phosphor material BAM has been elucidated.

  9. EXPERIMENTAL STUDY OF CRITICAL HEAT FLUX WITH ALUMINA-WATER NANOFLUIDS IN DOWNWARD-FACING CHANNELS FOR IN-VESSEL RETENTION APPLICATIONS

    E-Print Network [OSTI]

    Park, R.J.

    The Critical Heat Flux (CHF) of water with dispersed alumina nanoparticles was measured for the geometry and flow conditions relevant to the In-Vessel Retention (IVR) situation which can occur during core melting sequences ...

  10. Experimental study of alumina-water and zirconia-water nanofluids convective heat transfer and viscous pressure loss in Laminar regime

    E-Print Network [OSTI]

    Rea, Ulzie L

    2008-01-01

    The objective of this study is to evaluate experimentally the convective heat transfer and viscous pressure loss characteristics of alumina-water and zirconia-water nanofluids. Nanofluids are colloidal dispersions of ...

  11. Table 2 -Lime use and practices on Corn, major producing states, 2001 CO GA IL IN IA KS KY MI MN MO NE NY NC ND OH PA SD TX WI Area

    E-Print Network [OSTI]

    Kammen, Daniel M.

    MO NE NY NC ND OH PA SD TX WI Area Lime applied NR 85 81 85 67 16 72 55 27 65 10 57 53 NR 70 95 3 1 50 51 Lime (tons treated acre) NR 1.0 2.1 1.9 2.5 2.1 2.4 2.0 2.6 2.8 1.5 1.9 1.1 NR 1.9 1.7 NR 0.5 2 NC ND OH PA SD TX WI Area Lime applied NR 95 90 69 18 69 71 14 77 16 76 99 NR 82 80 NR 5 58 54 Lime

  12. The Effect of Braze Interlayer Thickness on the Mechanical Strength of Alumina Brazed with Ag-CuO Braze Alloys

    SciTech Connect (OSTI)

    Erskine, Kevin M.; Meier, Alan; Joshi, Vineet V.; Pilgrim, Steven M.

    2014-12-01

    The effect of braze interlayer thickness on the strength of alumina brazed with silver-copper oxide reactive air braze (RAB) alloys was evaluated using a four point bend test configuration. The brazed samples had an average fracture strength of 180 MPa or approximately 60 percent of the average monolithic alumina strength. The joint strength values obtained exceeded the yield strength and ultimate tensile strength of the silver interlayer indicating strong ceramic to metal adhesion and the development of a triaxial stress state in the braze interlayer. The average fracture strength was relatively constant (190 ± 60 MPa) in the thickness range of 0.030 mm to 0.230 mm for all test conditions. The braze fracture strength then decreased down to 100 ± 30 MPa as the braze thickness increased from 0.230 mm to 0.430 mm indicating a loss of triaxial constraint with increasing interlayer thickness. In addition, four different fracture modes were observed.

  13. The origin of slow electron recombination processes in dye-sensitized solar cells with alumina barrier coatings

    SciTech Connect (OSTI)

    Fabregat-Santiago, Francisco; Garcia-Canadas, Jorge; Palomares, Emilio; Clifford, John N.; Haque, Saif A.; Durrant, James R.; Garcia-Belmonte, Germa; Bisquert, Juan [Departament de Ciencies Experimentals, Universitat Jaume I, 12080 Castello (Spain); Department of Chemistry, Imperial College, London SW7 2AY (United Kingdom); Institut de Ciencia Molecular Universitat de Valencia, C. P. 46100, Dr. Moliner 50, Burjassot, Valencia (Spain); Department of Chemistry, Imperial College, London SW7 2AY (United Kingdom); Departament de Ciencies Experimentals, Universitat Jaume I, 12080 Castello (Spain)

    2004-12-01

    We investigate the effect of a thin alumina coating of nanocrystalline TiO{sub 2} films on recombination dynamics of dye-sensitized solar cells. Both coated and uncoated cells were measured by a combination of techniques: transient absorption spectroscopy, electrochemical impedance spectroscopy, and open-circuit voltage decay. It is found that the alumina barrier reduces the recombination of photoinjected electrons to both dye cations and the oxidized redox couple. It is proposed that this observed retardation can be attributed primarily to two effects: almost complete passivation of surface trap states in TiO{sub 2} that are able to inject electrons to acceptor species, and slowing down by a factor of 3-4 the rate of interfacial charge transfer from conduction-band states.

  14. Rotary Kiln for Synthetic Aggregate 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    for the outdoor heat exchanger of ASHP system [1]. When ambient temperature is very low, the fan works with high rotary speed to increase the air flow rate through the heat exchanger, and to improve evaporating temperature and the refrigerant mass flow rate..., an intercooler, two throttling devices, a four-way valve, and a solenoid valve. Three work conditions including the single-stage compression cooling, single-stage compression heating and two-stage compression heating can be carried out by controlling four...

  15. Rheology and microstructure of concentrated zirconia-alumina suspensions for gelcasting composites

    SciTech Connect (OSTI)

    Bleier, A.; Omatete, O.O.

    1992-12-31

    The relations among colloidal stability, suspension rheology, and solids loading are elucidated for zirconia-alumina mixtures containing 20 volt ZrO{sub 2}, based on solids. The lower colloidal stability of ZrO{sub 2} limits the rheological properties of this system. If the zeta potential of ZrO{sub 2} is less than 49 mV, high degrees of pseudoplasticity, high yield stress, high viscosity, and long relaxation times characterize the binary suspensions. These effects occur, despite the fact that ZrO{sub 2} is the minor ceramic constituent. If the zeta potential of ZrO{sub 2} is maintained above 49 mV, suspensions with high solids loading (55 vol%) can be prepared which behave as Newtonian fluids over the 0-to-200 s-1 shear rate range and as an elastic solid at higher rates. As the solids loading of a highly stable binary suspension is increased, the rheological properties change. They evolve from those of a near Newtonian-like fluid with nearly independent particles (40 vol%) to those of a pseudoplastic fluid with a weakly interacting particle network (50 vol%) to those of an elastic-like solid composed of crowded, strongly repulsive particles (55 vol%). Low-shear conditions for suspension-transport and mold-filling operations that ensure a homogeneous arrangement of ZrO{sub 2} and Al{sub 2}O{sub 3} particles in a gelcast ceramic seem promising.

  16. Method for fabricating cermets of alumina-chromium systems. [Patent application

    DOE Patents [OSTI]

    Morgan, C.S.

    1981-10-05

    Cermet insulators resistant to thermal and mechanical shock are prepared from alumina-chromium systems in the following way: by providing an Al/sub 2/O/sub 3/ material of about 0.5 to 7.0 micron size with a solid-hydrocarbon overcoating by slurrying an effective amount of said solid hydrocarbon in a solvent mixture containing said Al/sub 2/O/sub 3/ and thereafter evaporating said solvent, contacting said coated Al/sub 2/O/sub 3/ with a solution of chromium precursor compound, heating the resulting mixture in a reducing environment to a temperature above the decomposition temperature of said chromium precursor compound but less than the melting temperature of the Al/sub 2/O/sub 3/ or chromium for sufficient duration to yield a particulate compound having chromium essentially dispersed throughout the Al/sub 2/O/sub 3/, and then densifying said particulate to provide said cermet characterized by a theoretical density in excess of 96% and having 0.1 to 10.0 vol. % elemental chromium metal present therein as a dispersed phase at the boundaries of the Al/sub 2/O/sub 3/ material. Cermet components prepared thereby are useful in high temperature equipment, advanced heat engines, and nuclear-related equipment applications where electrical or thermal insulators are required.

  17. Manufacture of Alumina-Forming Austenitic Steel Alloys by Conventional Casting and Hot-Working Methods

    SciTech Connect (OSTI)

    Brady, M.P.; Yamamoto, Y.; Magee, J.H.

    2009-03-10

    Oak Ridge National Laboratory (ORNL) and Carpenter Technology Corporation (CarTech) participated in an in-kind cost share cooperative research and development agreement (CRADA) effort under the auspices of the Energy Efficiency and Renewable Energy (EERE) Technology Maturation Program to explore the feasibility for scale up of developmental ORNL alumina-forming austenitic (AFA) stainless steels by conventional casting and rolling techniques. CarTech successfully vacuum melted 301b heats of four AFA alloy compositions in the range of Fe-(20-25)Ni-(12-14)Cr-(3-4)Al-(l-2.5)Nb wt.% base. Conventional hot/cold rolling was used to produce 0.5-inch thick plate and 0.1-inch thick sheet product. ORNL subsequently successfully rolled the 0.1-inch sheet to 4 mil thick foil. Long-term oxidation studies of the plate form material were initiated at 650, 700, and 800 C in air with 10 volume percent water vapor. Preliminary results indicated that the alloys exhibit comparable (good) oxidation resistance to ORNL laboratory scale AFA alloy arc casting previously evaluated. The sheet and foil material will be used in ongoing evaluation efforts for oxidation and creep resistance under related CRADAs with two gas turbine engine manufacturers. This work will be directed to evaluation of AFA alloys for use in gas turbine recuperators to permit higher-temperature operating conditions for improved efficiencies and reduced environmental emissions. AFA alloy properties to date have been obtained from small laboratory scale arc-castings made at ORNL. The goal of the ORNL-CarTech CRADA was to establish the viability for producing plate, sheet and foil of the AFA alloys by conventional casting and hot working approaches as a first step towards scale up and commercialization of the AFA alloys. The AFA alloy produced under this effort will then be evaluated in related CRADAs with two gas turbine engine manufacturers for gas turbine recuperator applications.

  18. Department of Energy Awards $2.2 Million to Save Energy in the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    approximately 100,000 to examine new techniques for eliminating the energy intensive lime kiln from the pulping process. Georgia Tech will contribute a 20 percent cost share to...

  19. Density dependence of the room temperature thermal conductivity of atomic layer deposition-grown amorphous alumina (Al{sub 2}O{sub 3})

    SciTech Connect (OSTI)

    Gorham, Caroline S.; Gaskins, John T.; Hopkins, Patrick E.; Parsons, Gregory N.; Losego, Mark D.

    2014-06-23

    We report on the thermal conductivity of atomic layer deposition-grown amorphous alumina thin films as a function of atomic density. Using time domain thermoreflectance, we measure the thermal conductivity of the thin alumina films at room temperature. The thermal conductivities vary ?35% for a nearly 15% change in atomic density and are substrate independent. No density dependence of the longitudinal sound speeds is observed with picosecond acoustics. The density dependence of the thermal conductivity agrees well with a minimum limit to thermal conductivity model that is modified with a differential effective-medium approximation.

  20. Deformation Behavior of Sub-micron and Micron Sized Alumina Particles in Compression.

    SciTech Connect (OSTI)

    Sarobol, Pylin; Chandross, Michael E.; Carroll, Jay; Mook, William; Boyce, Brad; Kotula, Paul G.; McKenzie, Bonnie B.; Bufford, Daniel Charles; Hall, Aaron Christopher.

    2014-09-01

    The ability to integrate ceramics with other materials has been limited due to high temperature (>800degC) ceramic processing. Recently, researchers demonstrated a novel process , aerosol deposition (AD), to fabricate ceramic films at room temperature (RT). In this process, sub - micro n sized ceramic particles are accelerated by pressurized gas, impacted on the substrate, plastically deformed, and form a dense film under vacuum. This AD process eliminates high temperature processing thereby enabling new coatings and device integration, in which ceramics can be deposited on metals, plastics, and glass. However, k nowledge in fundamental mechanisms for ceramic particle s to deform and form a dense ceramic film is still needed and is essential in advancing this novel RT technology. In this wo rk, a combination of experimentation and atomistic simulation was used to determine the deformation behavior of sub - micron sized ceramic particle s ; this is the first fundamental step needed to explain coating formation in the AD process . High purity, singl e crystal, alpha alumina particles with nominal size s of 0.3 um and 3.0 um were examined. Particle characterization, using transmission electron microscopy (TEM ), showed that the 0.3 u m particles were relatively defect - free single crystals whereas 3.0 u m p articles were highly defective single crystals or particles contained low angle grain boundaries. Sub - micron sized Al 2 O 3 particles exhibited ductile failure in compression. In situ compression experiments showed 0.3um particles deformed plastically, fractured, and became polycrystalline. Moreover, dislocation activit y was observed within the se particles during compression . These sub - micron sized Al 2 O 3 particles exhibited large accum ulated strain (2 - 3 times those of micron - sized particles) before first fracture. I n agreement with the findings from experimentation , a tomistic simulation s of nano - Al 2 O 3 particles showed dislocation slip and significant plastic deformation during compressi on . On the other hand, the micron sized Al 2 O 3 particles exhibited brittle f racture in compression. In situ compression experiments showed 3um Al 2 O 3 particles fractured into pieces without observable plastic deformation in compression. Particle deformation behaviors will be used to inform Al 2 O 3 coating deposition parameters and particle - particle bonding in the consolidated Al 2 O 3 coatings.

  1. Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst

    SciTech Connect (OSTI)

    Pihl, Josh A; Toops, Todd J; Fisher, Galen; West, Brian H

    2014-01-01

    Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

  2. Combined SO{sub 2}/NO{sub x} control using ferrous{center_dot}EDTA and a secondary additive in a lime-based aqueous scrubber system

    SciTech Connect (OSTI)

    Mendelsohn, M.H.; Livengood, C.D.; Harkness, J.B.L.

    1991-12-01

    Integration of NO{sub x} control into existing flue-gas desulfurization (FGD) systems addresses site-specific control requirements while minimizing retrofit difficulties. Argonne has studied the use of the metal-chelate additives, such as ferrous{center_dot}EDTA in various wet FGD chemistries, to promote combined SO{sub 2}/NO{sub x} scrubbing. A major process problem is oxidation of the iron to the ferric species, leading to a significant decrease in NO{sub x}-removal capability. Argonne discovered a class of organic compounds that, when used with ferrous{center_dot}EDTA in a sodium carbonate chemistry, could maintain high levels of NO{sub x} removal. However, those antioxidant/reducing agents are not effective in a lime-based chemistry, and a broader investigation of antioxidants was initiated. This paper discusses results of that investigation, which found a practical antioxidant/reducing agent capable of maintaining NO{sub x} removals of about 50% (compared with about 15% without the agent) in a lime-based FGD chemistry with FE(II){center_dot}EDTA. 5 refs., 10 figs.

  3. Combined SO sub 2 /NO sub x control using ferrouster dot EDTA and a secondary additive in a lime-based aqueous scrubber system. [Sodium ascorbate

    SciTech Connect (OSTI)

    Mendelsohn, M.H.; Livengood, C.D.; Harkness, J.B.L.

    1991-01-01

    Integration of NO{sub x} control into existing flue-gas desulfurization (FGD) systems addresses site-specific control requirements while minimizing retrofit difficulties. Argonne has studied the use of the metal-chelate additives, such as ferrous{center dot}EDTA in various wet FGD chemistries, to promote combined SO{sub 2}/NO{sub x} scrubbing. A major process problem is oxidation of the iron to the ferric species, leading to a significant decrease in NO{sub x}-removal capability. Argonne discovered a class of organic compounds that, when used with ferrous{center dot}EDTA in a sodium carbonate chemistry, could maintain high levels of NO{sub x} removal. However, those antioxidant/reducing agents are not effective in a lime-based chemistry, and a broader investigation of antioxidants was initiated. This paper discusses results of that investigation, which found a practical antioxidant/reducing agent capable of maintaining NO{sub x} removals of about 50% (compared with about 15% without the agent) in a lime-based FGD chemistry with FE(II){center dot}EDTA. 5 refs., 10 figs.

  4. Obtaining aluminas from the thermal decomposition of their different precursors: An {sup 27}Al MAS NMR and X-ray powder diffraction studies

    SciTech Connect (OSTI)

    Chagas, L.H.; De Carvalho, G.S.G.; San Gil, R.A.S.; Chiaro, S.S.X.; Leitão, A.A.; Diniz, R.

    2014-01-01

    Graphical abstract: - Highlights: • We synthesized three precursors of alumina from different methods. • The calcination of the precursors generated several alumina polymorphs. • XRD and NMR were used for structural investigation of the polymorphs. • The synthesis route determines the structural and textural properties of the solids. - Abstract: A commercial sample of Boehmite was used as precursor of alumina polymorphs. For comparison, three other precursors were synthesized from different methods. Particularly, the use of excess of urea promoted a very crystalline form of basic aluminum carbonate. The characteristics of the four precursors were investigated by thermal, vibrational and X-ray powder diffraction (XRD) analysis. Additionally, the nuclear magnetic resonance, with magic angle spinning ({sup 27}Al MAS NMR), was used to verify the coordination of aluminum cations. Each precursor was calcined at various temperatures generating alumina polymorphs, which were structurally analyzed by XRD and {sup 27}Al MAS NMR. Due to interest in catalysis supports, special attention was given to the ?-Al{sub 2}O{sub 3} phase, which in addition to structural investigation was subjected to textural analysis. The results showed that, from different synthesis procedures and common route of calcination, one can obtain materials with the same composition but with different structural and textural properties, which in turn can significantly influence the performance of a supported catalyst.

  5. Parameters identification in strain-rate and thermal sensitive visco-plastic material model for an alumina dispersion strengthened copper

    E-Print Network [OSTI]

    Scapin, M; Peroni, M

    2011-01-01

    The main objective of this paper is getting strain-hardening, thermal and strain-rate parameters for a material model in order to correctly reproduce the deformation process that occurs in high strain-rate scenario, in which the material reaches also high levels of plastic deformation and temperature. In particular, in this work the numerical inverse method is applied to extract material strength parameters from experimental data obtained via mechanical tests at different strain-rates (from quasi-static loading to high strain-rate) and temperatures (between 20 C and 1000 C) for an alumina dispersion strengthened copper material, which commercial name is GLIDCOP. Thanks to its properties GLIDCOP finds several applications in particle accelerator technologies, where problems of thermal management, combined with structural requirements, play a key role. Currently, it is used for the construction of structural and functional parts of the particle beam collimation system. Since the extreme condition in which the m...

  6. Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents

    SciTech Connect (OSTI)

    Baltrus, John P.; Granite, Evan J.; Rupp, Erik C.; Stanko, Dennis C.; Howard, Bret; Pennline, Henry W.

    2011-05-01

    The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur, and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide, but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur, resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium.

  7. Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Rupp, E.C.; Stanko, D.C.; Howard, B.; Pennline, H.W.

    2011-01-01

    The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur. and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide. but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur. resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium.

  8. Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

    2014-08-01

    Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of ?"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200°C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150°C. The cells can even operate at 95°C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

  9. Manufacture of Alumina-Forming Austenitic Stainless Steel Alloys by Conventional Casting and Hot-Working Methods

    SciTech Connect (OSTI)

    Brady, M.P.; Yamamoto, Y.; Magee, J.H. (Carpenter Technol. Corp.)

    2009-03-23

    Oak Ridge National Laboratory (ORNL) and Carpenter Technology Corporation (CarTech) participated in an in-kind cost share cooperative research and development agreement (CRADA) effort under the auspices of the Energy Efficiency and Renewable Energy (EERE) Technology Maturation program to explore the feasibility for scale up of developmental ORNL alumina-forming austenitic (AFA) stainless steels by conventional casting and rolling techniques. CarTech successfully vacuum melted 30lb heats of four AFA alloy compositions in the range of Fe-(20-25)Ni-(12-14)Cr-(3-4)Al-(1-2.5)Nb wt.% base. Conventional hot/cold rolling was used to produce 0.5-inch thick plate and 0.1-inch thick sheet product. ORNL subsequently successfully rolled the 0.1-inch sheet to 4 mil thick foil. Long-term oxidation studies of the plate form material were initiated at 650, 700, and 800 C in air with 10 volume percent water vapor. Preliminary results indicated that the alloys exhibit comparable (good) oxidation resistance to ORNL laboratory scale AFA alloy arc casting previously evaluated. The sheet and foil material will be used in ongoing evaluation efforts for oxidation and creep resistance under related CRADAs with two gas turbine engine manufacturers. This work will be directed to evaluation of AFA alloys for use in gas turbine recuperators to permit higher-temperature operating conditions for improved efficiencies and reduced environmental emissions.

  10. X-ray Absorption Measurements on Nickel Cathode of Sodium-beta Alumina batteries: Fe-Ni-CI Chemical Associations

    SciTech Connect (OSTI)

    Bowden, Mark E.; Alvine, Kyle J.; Fulton, John L.; Lemmon, John P.; Lu, Xiaochuan; Webb-Robertson, Bobbie-Jo M.; Heald, Steve M.; Balasubramanian, Mahalingam; Mortensen, Devon R.; Seidler, Gerald T.; Hess, Nancy J.

    2014-02-01

    Sections of Na-Al-NiCl2 cathodes from sodium-beta alumina ZEBRA batteries have been characterized with X-ray fluorescence mapping, and XANES measurements to probe the microstructure, elemental correlation, and chemical speciation after voltage cycling. Cycling was performed under identical load conditions at either 240 or 280 °C operating temperature and subsequently quenched in either the charged or discharged state. X-ray fluorescence mapping and XANES measurements were made adjacent to the current collector and ?"-Al2O3 solid electrolyte interfaces to detect possible gradients in chemical properties across the cathode. An FeS additive, introduced during battery synthesis, was found to be present as either Fe metal or an Fe(II) chloride in all cathode samples. X-ray fluorescence mapping reveals an operating temperature and charge-state dependent spatial correlation between Fe, Ni, and Cl concentration. XANES measurements indicate that both Ni and Fe are chemically reactive and shift between metallic and chloride phases in the charged and discharged states, respectively. However the percentage of chemically active Ni and Fe is significantly less in the cell operated at lower temperature. Additionally, the cathode appeared chemically homogeneous at the scale of our X-ray measurements.

  11. Generation of alkali-free and high-proton concentration layer in a soda lime glass using non-contact corona discharge

    SciTech Connect (OSTI)

    Ikeda, Hiroshi; Sakai, Daisuke; Nishii, Junji [Research Institute for Electronic Science, Hokkaido University, N20 W10, Kita-ku, Sapporo, Hokkaido 001-0020 (Japan)] [Research Institute for Electronic Science, Hokkaido University, N20 W10, Kita-ku, Sapporo, Hokkaido 001-0020 (Japan); Funatsu, Shiro [Production Technology Center, Asahi Glass Co., Ltd., 1-1 Suehiro-cyo, Tsurumiku, Yokohama, Kanagawa 230-0045 (Japan)] [Production Technology Center, Asahi Glass Co., Ltd., 1-1 Suehiro-cyo, Tsurumiku, Yokohama, Kanagawa 230-0045 (Japan); Yamamoto, Kiyoshi; Suzuki, Toshio [Research Center, Asahi Glass Co., Ltd., 1150 Hazawa-cho, Kanagawa-ku, Yokohama, Kanagawa 221-8755 (Japan)] [Research Center, Asahi Glass Co., Ltd., 1150 Hazawa-cho, Kanagawa-ku, Yokohama, Kanagawa 221-8755 (Japan); Harada, Kenji [Department of Computer Science, Kitami Institute of Technology, 165 Koen-cho, Kitami, Hokkaido 090-8507 (Japan)] [Department of Computer Science, Kitami Institute of Technology, 165 Koen-cho, Kitami, Hokkaido 090-8507 (Japan)

    2013-08-14

    Formation mechanisms of alkali-free and high-proton concentration surfaces were investigated for a soda lime glass using a corona discharge treatment under an atmospheric pressure. Protons produced by high DC voltage around an anode needle electrode were incorporated into a sodium ion site in the anode side glass. The sodium ion was swept away to the cathode side as a charge carrier. Then it was discharged. The precipitated sodium was transformed to a Na{sub 2}CO{sub 3} powder when the surface contacted with air. The sodium ion in the glass surface layer of the anode side was replaced completely by protons. The concentration of OH groups in the layer was balanced with the amount of excluded sodium ions. The substitution reaction of sodium ions with protons tends to be saturated according to a square root function of time. The alkali depletion layer formation rate was affected by the large difference in mobility between sodium ions and protons in the glass.

  12. Partially sulfated lime-fly ash sorbents activated by water or steam for SO{sub 2} removal at a medium temperature

    SciTech Connect (OSTI)

    Liming Shi; Xuchang Xu

    2005-12-01

    Laboratory experiments were conducted to investigate the reactivity of partially sulfated lime-fly ash sorbents activated by water or steam for SO{sub 2} removal. Sulfation tests were performed at 550{sup o}C using a fixed bed reactor under conditions simulating economizer zone injection flue gas desulfurization. Activation experiments were conducted with water or steam using a range of temperatures between 100 and 550{sup o}C. The results showed that the reactivity of the sorbents was closely related to the content of Ca(OH){sub 2} formed in the activation process, which varied with the water or steam temperature. The sulfur dioxide capture capacity of Ca(OH){sub 2} in the sorbent is higher than that of CaO at a medium temperature. Water or steam temperatures in the range of 100-200{sup o}C are favorable to the formation of Ca(OH){sub 2} from CaO. 15 refs., 8 figs., 2 tabs.

  13. An examination of the role of plasma treatment for lean NOx reduction over sodium zeolite Y and gamma alumina Part 2. Formation of nitrogen

    SciTech Connect (OSTI)

    Yoon, Steven; Panov, Alexander G.; Tonkyn, Russell G.; Ebeling, Ana C.; Barlow, Stephan E.; Balmer, Mari Lou

    2002-03-15

    NOx reduction with NO2 as the NOx gas in the absence of plasma was compared to plasma treated lean NOx exhaust where NO is converted to NO2 in the plasma. Product nitrogen was measured to prove true chemical reduction of NOx to N2. With plasma treatment, NO as the NOx gas, and a NaY catalyst, the maximum conversion to nitrogen was 50% between 180-230?C. The activity decreased at higher and lower temperatures. At 130?C a complete nitrogen balance could be obtained, however between 164-227?C less than 20% of the NOx is converted to a nitrogen-containing compound or compounds not readily detected by GC or FTIR analysis. With plasma treatment, NO2 as the NOx gas, and a NaY catalyst, a complete nitrogen balance is obtained with a maximum conversion to nitrogen of 55% at 225?C. For gamma alumina, with plasma treatment and NO2 as the NOx gas, 59% of the NOx is converted to nitrogen at 340?C. A complete nitrogen balance was obtained at these conditions. As high as 80% NOx removal over gamma alumina was measured by a chemiluminescent NOx meter with plasma treatment and NO as the NOx gas. When NO is replaced with NO2 and the simulated exhaust gases are not plasma treated, the maximum NOx reduction activity of NaY and gamma alumina decreases to 26% and 10%, respectively. This is a large reduction in activity compared to similar conditions where the simulated exhaust was plasma treated. Therefore, in addition to NO2, other plasma-generated species are required to maximize NOx reduction.

  14. Ceramic Technology Project database: September 1990 summary report. [SiC, SiN, whisker-reinforced SiN, ZrO-toughened aluminas, zirconias, joints

    SciTech Connect (OSTI)

    Keyes, B.L.P.

    1992-06-01

    Data generated within the Ceramic Technology Project (CTP) represent a valuable resource for both research and industry. The CTP database was created to provide easy access to this information in electronic and hardcopy forms by using a computerized database and by issuing periodic hardcopy reports on the database contents. This report is the sixth in a series of semiannual database summaries and covers recent additions to the database, including joined brazed specimen test data. It covers 1 SiC, 34 SiN, 10 whisker-reinforced SiN, 2 zirconia-toughened aluminas, 8 zirconias, and 34 joints.

  15. Method and system for the combination of non-thermal plasma and metal/metal oxide doped .gamma.-alumina catalysts for diesel engine exhaust aftertreatment system

    DOE Patents [OSTI]

    Aardahl, Christopher L. (Richland, WA); Balmer-Miller, Mari Lou (West Richland, WA); Chanda, Ashok (Peoria, IL); Habeger, Craig F. (West Richland, WA); Koshkarian, Kent A. (Peoria, IL); Park, Paul W. (Peoria, IL)

    2006-07-25

    The present disclosure pertains to a system and method for treatment of oxygen rich exhaust and more specifically to a method and system that combines non-thermal plasma with a metal doped .gamma.-alumina catalyst. Current catalyst systems for the treatment of oxygen rich exhaust are capable of achieving only approximately 7 to 12% NO.sub.x reduction as a passive system and only 25 40% reduction when a supplemental hydrocarbon reductant is injected into the exhaust stream. It has been found that treatment of an oxygen rich exhaust initially with a non-thermal plasma and followed by subsequent treatment with a metal doped .gamma.-alumina prepared by the sol gel method is capable of increasing the NO.sub.x reduction to a level of approximately 90% in the absence of SO.sub.2 and 80% in the presence of 20 ppm of SO.sub.2. Especially useful metals have been found to be indium, gallium, and tin.

  16. SOIL INFORMATION Last Lime Application

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    production. Send samples, forms, and payment to Virginia Tech Soil Testing Lab, 145 Smyth Hall (MC 0465), 185 Industrial Lawns - Bermudagrass Routine (soil pH, P, K, Ca, Mg, Zn, Mn, Cu, Fe, B, and estimated CEC) $10, Virginia Tech." COST PER SAMPLE IN-STATE OUT-OF-STATE SOIL TEST DESIRED AND FEES SAMPLE IDENTIFICATION Your

  17. Lime Wind | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History ViewInformationWinds JumpOxiranchem IncLighthouseLignin JumpLihue,Wind

  18. Temperature dependent dielectric function in the near-infrared to vacuum-ultraviolet ultraviolet spectral range of alumina and yttria stabilized zirconia thin films

    SciTech Connect (OSTI)

    Schmidt-Grund, R. Lühmann, T.; Böntgen, T.; Franke, H.; Lorenz, M.; Grundmann, M.; Opper, D.

    2013-12-14

    The dielectric function of nano-/polycrystalline alumina and yttria stabilised zirconia thin films has been investigated in a wide spectral range from 1.0?eV to 7.5?eV and temperatures between 10?K and room temperature. In the near band-edge spectral range, we found a broad distribution of optical transitions within the band gap, the so-called Urbach absorption tail which is typical for amorphous or polycrystalline materials due to the lack of long range order in the crystal structure. The coupling properties of the electronic system to the optical phonon bath and thermal lattice vibrations strongly depend on the ratio of the spectral extent of these disorder states to the main phonon energy, which we correlate with the different crystalline structure of our samples. The films have been grown at room temperature and 650?°C by pulsed laser deposition.

  19. An examination of the role of plasma treatment for lean NOx reduction over sodium zeolite Y and gamma alumina: Part 1. Plasma assisted NOx reduction over NaY and Al2O3

    SciTech Connect (OSTI)

    Yoon, Ilsop S.; Panov, Alexander G.; Tonkyn, Russell G.; Ebeling, Ana C.; Barlow, Stephan E.; Balmer, Mari Lou

    2002-03-15

    The role of plasma processing on NOx reduction over gammma-alumina and a basic zeolite, NaY was examined. During the plasma treatment NO is oxidized to NO2 and propylene is partially oxidized to CO, CO2, acetaldehyde, and formaldehyde. With plasma treatment, NO as the NOx gas, and a NaY catalyst, the maximum NOx conversion was 70% between 180 and 230?C. The activity decreased at higher and lower temperatures. As high as 80% NOx removal over gamma alumina was measured by a chemiluminescent NOx meter with plasma treatment and NO as the NOx gas. For both catalysts a simultaneous decrease in NOx and aldehydes concentrations was observed, which suggests that aldehyde may be important components for NOx reduction in plasma-treated exhaust.

  20. Development of Surface Complexation Models of Cr(VI) Adsorption on Soils, Sediments and Model Mixtures of Kaolinite, Montmorillonite, ?-Alumina, Hydrous Manganese and Ferric Oxides and Goethite

    SciTech Connect (OSTI)

    Koretsky, Carla [Western Michigan University] [Western Michigan University

    2013-11-29

    Hexavalent chromium is a highly toxic contaminant that has been introduced into aquifers and shallow sediments and soils via many anthropogenic activities. Hexavalent chromium contamination is a problem or potential problem in the shallow subsurface at several DOE sites, including Hanford, Idaho National Laboratory, Los Alamos National Laboratory and the Oak Ridge Reservation (DOE, 2008). To accurately quantify the fate and transport of hexavalent chromium at DOE and other contaminated sites, robust geochemical models, capable of correctly predicting changes in chromium chemical form resulting from chemical reactions occurring in subsurface environments are needed. One important chemical reaction that may greatly impact the bioavailability and mobility of hexavalent chromium in the subsurface is chemical binding to the surfaces of particulates, termed adsorption or surface complexation. Quantitative thermodynamic surface complexation models have been derived that can correctly calculate hexavalent chromium adsorption on well-characterized materials over ranges in subsurface conditions, such pH and salinity. However, models have not yet been developed for hexavalent chromium adsorption on many important constituents of natural soils and sediments, such as clay minerals. Furthermore, most of the existing thermodynamic models have been developed for relatively simple, single solid systems and have rarely been tested for the complex mixtures of solids present in real sediments and soils. In this study, the adsorption of hexavalent chromium was measured as a function of pH (3-10), salinity (0.001 to 0.1 M NaNO3), and partial pressure of carbon dioxide(0-5%) on a suite of naturally-occurring solids including goethite (FeOOH), hydrous manganese oxide (MnOOH), hydrous ferric oxide (Fe(OH)3), ?-alumina (Al2O3), kaolinite (Al2Si2O5(OH)4), and montmorillonite (Na3(Al, Mg)2Si4O10(OH)2?nH2O). The results show that all of these materials can bind substantial quantities of hexavalent chromium, especially at low pH. Unexpectedly, experiments with the clay minerals kaolinite and montmorillonite suggest that hexavalent chromium may interact with these solids over much longer periods of time than expected. Furthermore, hexavalent chromium may irreversibly bind to these solids, perhaps because of oxidation-reduction reactions occurring on the surfaces of the clay minerals. More work should be done to investigate and quantify these chemical reactions. Experiments conducted with mixtures of goethite, hydrous manganese oxide, hydrous ferric oxide, ?-alumina, montmorillonite and kaolinite demonstrate that it is possible to correctly predict hexavalent chromium binding in the presence of multiple minerals using thermodynamic models derived for the simpler systems. Further, these models suggest that of the six solid considered in this study, goethite is typically the solid to which most of the hexavalent chromium will bind. Experiments completed with organic-rich and organic-poor natural sediments demonstrate that in organic-rich substrates, organic matter is likely to control uptake of the hexavalent chromium. The models derived and tested in this study for hexavalent chromium binding to ?-alumina, hydrous manganese oxide, goethite, hydrous ferric oxide and clay minerals can be used to better predict changes in hexavalent chromium bioavailability and mobility in contaminated sediments and soils.

  1. Laser damage by ns and sub-ps pulses on hafnia/silica anti-reflection coatings on fused silica double-sided polished using zirconia or ceria and washed with or without an alumina wash step.

    SciTech Connect (OSTI)

    Bellum, John Curtis; Rambo, Patrick K.; Schwarz, Jens; Kletecka, Damon; Atherton, Briggs W.; Kimmel, Mark W.; Smith, Ian Craig; Smith, Douglas; Hobbs, Zachary

    2010-10-01

    Sandia's Large Optics Coating Operation has extensive results of laser induced damage threshold (LIDT) testing of its anti-reflection (AR) and high reflection coatings on substrates pitch polished using ceria and washed in a process that includes an alumina wash step. The purpose of the alumina wash step is to remove residual polishing compound to minimize its role in laser damage. These LIDT tests are for multi longitudinal mode, ns class pulses at 1064 nm and 532 nm (NIF-MEL protocol) and mode locked, sub-ps class pulses at 1054 nm (Sandia measurements), and show reasonably high and adequate laser damage resistance for coatings in the beam trains of Sandia's Z-Backlighter terawatt and petawatt lasers. An AR coating in addition to coatings of our previous reports confirms this with LIDTs of 33.0 J/cm{sup 2} for 3.5 ns pulses and 1.8 J/cm{sup 2} for 350 fs pulses. In this paper, we investigate both ceria and zirconia in doublesided polishing (common for large flat Z-Backlighter laser optics) as they affect LIDTs of an AR coating on fused silica substrates washed with or without the alumina wash step. For these AR coated, double-sided polished surfaces, ceria polishing in general affords better resistance to laser damage than zirconia polishing and laser damage is less likely with the alumina wash step than without it. This is supported by specific results of laser damage tests with 3.5 ns, multi longitudinal mode, single shot pulses at 1064 nm and 532 nm, with 7.0 ns, single and multi longitudinal mode, single and multi shot pulses at 532 nm, and with 350 fs, mode-locked, single shot pulses at 1054 nm.

  2. Texas Soils: A Study of Chemical Composition. 

    E-Print Network [OSTI]

    Harrington, H. H. (Henry Hill)

    1892-01-01

    suils, are examples of the benefit act ing from a full supply of lime. Or, let US take sulphuric acid. ? is of course combined as some salt. For example, sulphate of pot2 sulphate of lime (gypsum), snlphate of ammonia (in fertilizers), sulphate... ..................... Alumina Oxide.. Calcium Oxide ....................... .................... Magnesium Oxide. ....................... Aulphuric Arid. .................... Phusphoric Acid. ............................. Potash Soda...

  3. Small-Angle Neutron Scattering and Electron Microscopy Study of the Wet and Dry High-Temperature Oxidation of Alumina- and Chromia- Forming Stainless Steels

    SciTech Connect (OSTI)

    Rother, Gernot [ORNL; Keiser, James R [ORNL; Brady, Michael P [ORNL; Unocic, Kinga A [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Littrell, Ken [ORNL; Meisner, Roberta Ann [ORNL; Santella, Michael L [ORNL; Wesolowski, David J [ORNL; Cole, David R [ORNL

    2012-01-01

    Foils of T347 stainless steel and a developmental alumina-forming austenitic (AFA) stainless steel were oxidized at 800 C in dry air, air with 10% H2O, and air with 10% D2O. The T347 foils exhibited a transition to rapid Fe-base oxide formation between 24 and 72 h of exposure in H2O and D2O, but exhibited protective Cr-rich oxide formation in dry air. In contrast, only thin, protective Al-rich oxide surfaces were observed for the AFA alloy foils under all conditions studied. Changes in the small angle neutron scattering (SANS) signal were observed for the T347 stainless steel as a function of oxidation time in dry air, attributed to oxide grain growth and porosity formation/partial scale detachment associated with spinel phase at the scale/gas interface. For the AFA alloy, only minor changes in scattering as a result of oxidation time were observed. For both T347 and AFA, similar scattering was observed in dry and wet air (H2O and D2O) exposure. This finding indicates that water vapor exposure did not induce significant morphological changes in the oxide scales (such as increased porosity) in the 5-300 nm size regime accessed by SANS.

  4. Initial activity of reduced chromia/alumina catalyst in n-butane dehydrogenation monitored by on-line FT-IR gas analysis

    SciTech Connect (OSTI)

    Hakuli, A.; Kytoekivi, A.; Suntola, T.

    1996-06-01

    The initial activity of chromia/alumina catalyst (13 wt% Cr) in n-butane dehydrogenation was studied in a flow reactor at 853 K. The initial activity was determined by on-line FT-IR gas analysis, which enabled sampling of the gaseous product mixture at a time resolution of seconds. The catalysts were processed in repeated cycles of oxidation, reduction, and dehydrogenation using n-butane, methane, hydrogen, or carbon monoxide as reducing agents. With n-butane, methane, and hydrogen and dehydrogenation activity was associated with Cr{sup 3+} species apparently formed in the reduction of high-valence Cr species. The catalyst reduced with carbon monoxide at 853 K showed poor initial selectivity for butenes and, relative to the other catalysts. Simultaneous data relating the initial activity, coke content, and some of the physicochemical properties of the catalyst indicated that the surfaces of all catalysts were modified to some extent by the successive reaction cycles. 33 refs., 7 figs., 2 tabs.

  5. The effect of rhenium, sulfur and alumina on the conversion of hydrocarbons over platinum single crystals: Surface science and catalytic studies

    SciTech Connect (OSTI)

    Kim, C.

    1992-04-01

    Conversion reactions of hydrocarbons over Pt-Re model catalyst surfaces modified by sulfur and alumina have been studied. A plasma deposition source has been developed to deposit Pt, Re, and Al on metal substrates variable coverage in ultrahigh vacuum without excessive heating. Conversion of n-hexane was performed over the Re-covered Pt and Pt-covered Re surfaces. The presence of the second metal increased hydrogenolysis activity of both Pt-Re surfaces. Addition of sulfur on the model Catalyst surfaces suppressed hydrogenolysis activity and increased the cyclization rate of n-hexane to methylcyclopentane over Pt-Re surfaces. Sulfiding also increased the dehydrogenation rate of cyclohexane to benzene Over Pt-Re surfaces. It has been proposed that the PtRe bimetallic catalysts show unique properties when combined with sulfur, and electronic interactions exist between platinum, rhenium and sulfur. Decomposition of hydrocarbons on the sulfur-covered Pt-Re surfaces supported that argument. For the conversion of 1-butene over the planar Pt/AlO[sub x], the addition of Pt increased the selectivity of hydrogenation over isomerization.

  6. The effect of rhenium, sulfur and alumina on the conversion of hydrocarbons over platinum single crystals: Surface science and catalytic studies

    SciTech Connect (OSTI)

    Kim, C.

    1992-04-01

    Conversion reactions of hydrocarbons over Pt-Re model catalyst surfaces modified by sulfur and alumina have been studied. A plasma deposition source has been developed to deposit Pt, Re, and Al on metal substrates variable coverage in ultrahigh vacuum without excessive heating. Conversion of n-hexane was performed over the Re-covered Pt and Pt-covered Re surfaces. The presence of the second metal increased hydrogenolysis activity of both Pt-Re surfaces. Addition of sulfur on the model Catalyst surfaces suppressed hydrogenolysis activity and increased the cyclization rate of n-hexane to methylcyclopentane over Pt-Re surfaces. Sulfiding also increased the dehydrogenation rate of cyclohexane to benzene Over Pt-Re surfaces. It has been proposed that the PtRe bimetallic catalysts show unique properties when combined with sulfur, and electronic interactions exist between platinum, rhenium and sulfur. Decomposition of hydrocarbons on the sulfur-covered Pt-Re surfaces supported that argument. For the conversion of 1-butene over the planar Pt/AlO{sub x}, the addition of Pt increased the selectivity of hydrogenation over isomerization.

  7. Research and Development of a New Silica-Alumina Based Cementitious Material Largely Using Coal Refuse for Mine Backfill, Mine Sealing and Waste Disposal Stabilization

    SciTech Connect (OSTI)

    Henghu Sun; Yuan Yao

    2012-06-29

    Coal refuse and coal combustion byproducts as industrial solid waste stockpiles have become great threats to the environment. To activate coal refuse is one practical solution to recycle this huge amount of solid waste as substitute for Ordinary Portland Cement (OPC). The central goal of this project is to investigate and develop a new silica-alumina based cementitious material largely using coal refuse as a constituent that will be ideal for durable construction, mine backfill, mine sealing and waste disposal stabilization applications. This new material is an environment-friendly alternative to Ordinary Portland Cement. The main constituents of the new material are coal refuse and other coal wastes including coal sludge and coal combustion products (CCPs). Compared with conventional cement production, successful development of this new technology could potentially save energy and reduce greenhouse gas emissions, recycle vast amount of coal wastes, and significantly reduce production cost. A systematic research has been conducted to seek for an optimal solution for enhancing pozzolanic reactivity of the relatively inert solid waste-coal refuse in order to improve the utilization efficiency and economic benefit as a construction and building material.

  8. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: the effect of protective alumina coating on electrical stability in dual environment

    SciTech Connect (OSTI)

    Chou, Y. S.; Choi, Jung-Pyung; Stevenson, Jeffry W.

    2012-12-01

    An alkali-containing silicate glass was recently proposed as a potential sealant for solid oxide fuel cells (SOFC). The glass contains appreciable amount of alkalis and retains its glassy microstructure at elevated temperatures over time. It is more compliant as compared to conventional glass-ceramics sealants and could potentially heal cracks during thermal cycling. In previous papers the thermal cycle stability, thermal stability and chemical compatibility were reported with yttria-stabilized zirconia (YSZ) electrolyte and YSZ-coated ferritic stainless steel interconnect. In this paper, we report the electrical stability of the compliant glass with aluminized AISI441 interconnect material under DC load in dual environment at 700-800oC. Apparent electrical resistivity was measured with a 4-point method for the glass sealed between two aluminized AISI441 metal coupons as well as plain AISI441 substrates. The results showed good electrical stability with the aluminized AISI441 substrate, while unstable behavior was observed for un-coated substrates. In addition, interfacial microstructure was examined with scanning electron microscopy and correlated with the measured resistivity results. Overall, the alumina coating demonstrated good chemical stability with the alkali-containing silicate sealing glass under DC loading.

  9. Selective Catalytic Reduction of Oxides of Nitrogen with Ethanol/Gasoline Blends over a Silver/Alumina Catalyst on Lean Gasoline Engine

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Pihl, Josh A; Toops, Todd J; Thomas, John F; Parks, II, James E; West, Brian H

    2015-01-01

    Ethanol is a very effective reductant of nitrogen oxides (NOX) over silver/alumina (Ag/Al2O3) catalysts in lean exhaust environment. With the widespread availability of ethanol/gasoline-blended fuel in the USA, lean gasoline engines equipped with an Ag/Al2O3 catalyst have the potential to deliver higher fuel economy than stoichiometric gasoline engines and to increase biofuel utilization while meeting exhaust emissions regulations. In this work a pre-commercial 2 wt% Ag/Al2O3 catalyst was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine for the selective catalytic reduction (SCR) of NOX with ethanol/gasoline blends. The ethanol/gasoline blends were delivered via in-pipe injection upstream of the Ag/Al2O3 catalyst with the engine operating under lean conditions. A number of engine conditions were chosen to provide a range of temperatures and space velocities for the catalyst performance evaluations. High NOX conversions were achieved with ethanol/gasoline blends containing at least 50% ethanol; however, higher C1/N ratio was needed to achieve greater than 90% NOX conversion, which also resulted in significant HC slip. Temperature and HC dosing were important in controlling selectivity to NH3 and N2O. At high temperatures, NH3 and N2O yields increased with increased HC dosing. At low temperatures, NH3 yield was very low, however, N2O levels became significant. The ability to generate NH3 under lean conditions has potential for application of a dual SCR approach (HC SCR + NH3 SCR) to reduce fuel consumption needed for NOX reduction and/or increased NOX conversion, which is discussed in this work.

  10. Alumina-based ceramic composite

    DOE Patents [OSTI]

    Alexander, K.B.; Tiegs, T.N.; Becher, P.F.; Waters, S.B.

    1996-07-23

    An improved ceramic composite comprising oxide ceramic particulates, nonoxide ceramic particulates selected from the group consisting of carbides, borides, nitrides of silicon and transition metals and mixtures thereof, and a ductile binder selected from the group consisting of metallic, intermetallic alloys and mixtures thereof is described. The ceramic composite is made by blending powders of the ceramic particulates and the ductile to form a mixture and consolidating the mixture of under conditions of temperature and pressure sufficient to produce a densified ceramic composite. 5 figs.

  11. Alumina-based ceramic composite

    DOE Patents [OSTI]

    Alexander, Kathleen B. (Oak Ridge, TN); Tiegs, Terry N. (Lenoir City, TN); Becher, Paul F. (Oak Ridge, TN); Waters, Shirley B. (Knoxville, TN)

    1996-01-01

    An improved ceramic composite comprising oxide ceramic particulates, nonoxide ceramic particulates selected from the group consisting of carbides, borides, nitrides of silicon and transition metals and mixtures thereof, and a ductile binder selected from the group consisting of metallic, intermetallic alloys and mixtures thereof is described. The ceramic composite is made by blending powders of the ceramic particulates and the ductile to form a mixture and consolidating the mixture of under conditions of temperature and pressure sufficient to produce a densified ceramic composite.

  12. Lime and Phosphoric Acid Requirements for Chicks. 

    E-Print Network [OSTI]

    Sherwood, R. M. (Ross Madison)

    1932-01-01

    . D., Genetics D. Scoates, A. E., Agricultural Engineering J. H. Knox, M. S., Animal Husbandry A. K. Mackey, M. S., Animal Husbandry A. L. Darndl, M. A., Dairy Husbandry *Dean School of Veterinary Medicine. +As of September 1, 1932. . **In...

  13. The Needs of Texas Soils for Lime

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1919-01-01

    .. 9758 Pine ashes (leached) 47 per cent water. ... 9775 Peanut hull ashes.. ..................... 9776 Mesquite wood ashes. .................. ....................... 11227 Ashes of cactus.. 11272 Pine wood ashes..... ...................... ...................... 11273 Rice straw ashes. 11413 Pine ashes (not exposed) 16.7 per cent water 11414 Pine ashes cxposed to weather, 29.3 per cent water.. ........................ ..................... 11429 Peanut hull ashes.. 13809 Ashes from mesquite wood...

  14. LimeAmps | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EAInvervarLeeds, UnitedLiberty Power Corp.Lilliputian Systems

  15. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    SciTech Connect (OSTI)

    Cetin, Bora; Aydilek, Ahmet H.; Li, Lin

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer This study is the evaluation of leaching potential of fly ash-lime mixed soils. Black-Right-Pointing-Pointer This objective is met with experimental and numerical analysis. Black-Right-Pointing-Pointer Zn leaching decreases with increase in fly ash content while Ba, B, Cu increases. Black-Right-Pointing-Pointer Decrease in lime content promoted leaching of Ba, B and Cu while Zn increases. Black-Right-Pointing-Pointer Numerical analysis predicted lower field metal concentrations. - Abstract: A study was conducted to evaluate the leaching potential of unpaved road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater impacts of barium, boron, copper, and zinc leaching. This objective was met by a combination of batch water leach tests, column leach tests, and computer modeling. The laboratory tests were conducted on soil alone, fly ash alone, and URM-fly ash-lime kiln dust mixtures. The results indicated that an increase in fly ash and lime content has significant effects on leaching behavior of heavy metals from URM-fly ash mixture. An increase in fly ash content and a decrease in lime content promoted leaching of Ba, B and Cu whereas Zn leaching was primarily affected by the fly ash content. Numerically predicted field metal concentrations were significantly lower than the peak metal concentrations obtained in laboratory column leach tests, and field concentrations decreased with time and distance due to dispersion in soil vadose zone.

  16. NUCLEAR POWERED CO2 CAPTURE FROM THE ATMOSPHERE

    SciTech Connect (OSTI)

    Sherman, S

    2008-09-22

    A process for capturing CO{sub 2} from the atmosphere was recently proposed. This process uses a closed cycle of sodium and calcium hydroxide, carbonate, and oxide transformations to capture dilute CO{sub 2} from the atmosphere and to generate a concentrated stream of CO{sub 2} that is amenable to sequestration or subsequent chemical transformations. In one of the process steps, a fossil-fueled lime kiln is needed, which reduces the net CO{sub 2} capture of the process. It is proposed to replace the fossil-fueled lime kiln with a modified kiln heated by a high-temperature nuclear reactor. This will have the effect of eliminating the use of fossil fuels for the process and increasing the net CO{sub 2} capture. Although the process is suitable to support sequestration, the use of a nuclear power source for the process provides additional capabilities, and the captured CO{sub 2} may be combined with nuclear-produced hydrogen to produce liquid fuels via Fischer-Tropsch synthesis or other technologies. Conceivably, such plants would be carbon-neutral, and could be placed virtually anywhere without being tied to fossil fuel sources or geological sequestration sites.

  17. Lime pretreatment and enzymatic hydrolysis of corn stover 

    E-Print Network [OSTI]

    Kim, Se Hoon

    2005-08-29

    Department of Agriculture (USDA), including Dartmouth College, Auburn University, Purdue University, Michigan State University, the National Renewable Energy Laboratory (NREL). Working with other people from various institutes provided a great opportunity... of carbon-carbon bonds. O O H-C C O H+ H+ H2C C OCH3 C O- C O O- OCH3 15 Agriculture (USDA) including Dartmouth College, Auburn University, Purdue University, Michigan State University, National Renewable Energy Laboratory (NREL), and Texas...

  18. Long-term lime pretreatment of poplar wood 

    E-Print Network [OSTI]

    Sierra Ramirez, Rocio

    2006-04-12

    wide variety of fuels and chemicals. With this purpose, many processes have been developed. These include the following: fermentation of sugars and starches, fast pyrolysis, direct liquefaction of biomass by thermal processes, and indirect... liquefaction of biomass- derived syngas. The full range is shown in Fig. 1 (Double, 1987). A major emphasis in the fermentation industry is ethanol production (Chadha et al., 1995; Holtzapple et al., 1999). Fermentation is a biological process in which...

  19. Saturn's emitted power Liming Li,1,2

    E-Print Network [OSTI]

    depends on precise measurements of the emitted thermal energy and the absorbed solar energy. We here energy and absorbed solar energy for a planet is generally called the energy balance [Conrath et al., 1989]. An internal heat source is inferred for the planet if the emitted thermal energy exceeds

  20. Lime Energy formerly Electric City Corporation | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas:Montezuma, Arizona: EnergyLebanonTexas:Hill,Photovoltaic Jump to:Lima,Energy formerly

  1. For building and construction. Technical notes

    SciTech Connect (OSTI)

    Bansal, G.D.; Sharma, D.; Prakash, C.; Rao, K.R.; Jain, S.P.

    1981-01-01

    Sixteen technical notes are compiled coveering: Apertures other than Northlights; Design of pile caps; thermal insulation of roofs of industrial buildings; room heating by solar energy; charging device for small capacity lime kilns; waste water disposal system for rural areas; low cost sound absorbing materials; solar space heating system; pedestal piles for low cost houses; solar timber seasoning kiln; design of cold storage for fruits and vegetables; techniques for improved thatch roofs; resilient floors for structural noise reduction; plastic composite panels for partition claddings and flush doors; chimney design for domestic kitchens; and a cheap and effective fire retardant treatment for paddy thatch/coconut leaves/palmyrah thatch. The notes give brief descriptions of the design and use of the materials and techniques covered.

  2. Wood Gasification: Where It's At, Where It's Going 

    E-Print Network [OSTI]

    Murphy, M. L.

    1981-01-01

    the proven combustion system. With other applications such as the firing of lime kilns in the pul p and pape r indus try where the opti ons, other than fossil fuel s and gasification, are non existent and the economics for gasification are very similar... in biomass gasifi cation. As early as 1839, processes were in operation on coal, wood or other residues in which a combustible off-gas, or producer gas as it was aptly dubbed, was generated by the incomplete fuel oxidatior, \

  3. Design of fuel efficient brick kiln for ceramic water filter firing in Ghana

    E-Print Network [OSTI]

    Adjorlolo, Eric (Eric James Kofi)

    2007-01-01

    Ceramic water filters are currently produced in Ghana in order to provide a household solution to contaminated water. These filters, locally branded with the name Kosim filter by originating from Potters for Peace-Nicaragua, ...

  4. Indirect-Fired Kiln Conserves Scrap Aluminum and Cuts Costs | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide toIMPROVEMENT OF DESIGNEmergency2013AlaskaDepartment of

  5. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Bejing, CN); Yan, Naiqiang (Burkeley, CA)

    2010-07-13

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  6. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, Shou-Heng (Kaohsiung, TW); Liu, Zhao-Rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

    2011-08-30

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  7. Method for scavenging mercury

    DOE Patents [OSTI]

    Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

    2009-01-20

    Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

  8. SUNY/Albany Glass Study Group 1980-1981 annual report

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    Contents: Summary: Development of Techniques for Measuring Elemental Profiles Near Glass Surfaces Using Nuclear Reaction Analysis and Rutherford Backscattering Spectrometry; Studies of Ionic Interdiffusion in Water-Glass Reactions; Electromigration Experiments: Varying Anode Conditions; Dissolution of Glasses: The Effects of Salt and Radiation Damage; Reaction Between Water and Tektites; Permeation Kinetics of Water in SiO2 Films; Hydrogen Isotope Experiments; Reaction Between Water and Beta-Alumina; and Study of SO3 Treatment of Soda-Lime Glass.

  9. Manufacturing Energy and Carbon Footprint - Sector: Alumina and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Export 10 Combustion Emissions (MMT CO 2 e Million Metric Tons Carbon Dioxide Equivalent) Total Emissions Offsite Emissions + Onsite Emissions Energy (TBtu ...

  10. Improved Alumina Loading in High-Level Waste Glasses

    SciTech Connect (OSTI)

    Kim, D.; Vienna, J.D. [Pacific Northwest National Laboratory, Richland, WA (United States); Peeler, D.K.; Fox, K.M. [Savannah River National Laboratory, Aiken, SC (United States); Aloy, A.; Trofimenko, A.V. [V.G. Khlopin Radium Institute, St. Petersburg (Russian Federation); Gerdes, K.D. [EM-21, Office of Waste Processing, U.S. Department of Energy, Washington, DC (United States)

    2008-07-01

    Recent tank retrieval, blending, and treatment strategies at both the Savannah River Site (SRS) and Hanford have identified increased amounts of high-Al{sub 2}O{sub 3} waste streams that are scheduled to be processed through their respective high-level waste (HLW) vitrification facilities. It is well known that the addition of small amounts of Al{sub 2}O{sub 3} to borosilicate glasses generally enhances the durability of the waste glasses. However, at higher Al{sub 2}O{sub 3} concentrations nepheline (NaAlSiO{sub 4}) formation can result in a severe deterioration of the chemical durability of the slowly cooled glass near the center of the canister. Additionally, higher concentrations of Al{sub 2}O{sub 3} generally increase the liquidus temperature of the melt and decrease the processing rate. Pacific Northwest National Laboratory (PNNL), Savannah River National Laboratory (SRNL), and Khlopin Radium Institute (KRI) are jointly performing laboratory and scaled-melter tests, through US Department of Energy, EM-21 Office of Waste Processing program, to develop glass formulations with increased Al{sub 2}O{sub 3} concentrations. These glasses are formulated for specific DOE waste compositions at Hanford and Savannah River Site. The objectives are to avoid nepheline formation while maintaining or meeting waste loading and/or waste throughput expectations as well as satisfying critical process and product performance related constraints such as viscosity, liquidus temperature, and glass durability. This paper summarizes the results of recent tests of simulated Hanford HLW glasses containing up to 26 wt% Al{sub 2}O{sub 3} in glass. In summary: Glasses with Al{sub 2}O{sub 3} loading ranging from 25 to 27 wt% were formulated and tested at a crucible scale. Successful glass formulations with up to 26 wt% Al{sub 2}O{sub 3} that do not precipitate nepheline during CCC treatment and had spinel crystals 1 vol% or less after 24 hr heat treatment at 950 deg. C were obtained. The selected glass, HAL-17 with 26 wt% Al{sub 2}O{sub 3}, had viscosity and electrical conductivity within the boundaries for adequate processing in the Joule heated melters operated at 1150 deg. C. This HAL-17 glass was successfully processed using small-scale (SMK) and larger scale (EP-5) melters. There was no indication of spinel settling during processing. The product glass samples from these melter tests contained 1 to 4 vol% spinel crystals that are likely formed during cooling. The PCT tests on the product glasses are underway. The present study demonstrated that it is possible to formulate the glasses with up to 26 wt% Al{sub 2}O{sub 3} that satisfy the property requirements and is processable with Joule-heated melters operated at 1150 deg. C. The 'nepheline discriminator' for HAL-17 glass is 0.45, which supports that claim that the current rule ('nepheline discriminator' < 0.62) is too restrictive. Considering that the cost of HLW treatment is highly dependent on loading of waste in glass, this result provides a potential for significant cost saving for Hanford. The maximum Al{sub 2}O{sub 3} loading that can be achieved will also depend on concentrations of other components in wastes. For example, the loading of waste used in this study was also limited by the spinel crystallization after 950 deg. C 24 hr heat treatment, which suggests that the concentrations of spinel-forming components such as Fe{sub 2}O{sub 3}, Cr{sub 2}O{sub 3}, NiO, ZnO, and MnO would be critical in addition to Al{sub 2}O{sub 3} for the maximum Al{sub 2}O{sub 3} loading achievable. The observed glass production rate per unit melter surface area of 0.75 MT/(d.m{sup 2}) for SMK test is comparable to the design capacity of WTP HLW melters at 0.8 MT/(d.m{sup 2}). However, the test with EP-5 melter achieved 0.38 MT/(d.m{sup 2}), which is roughly a half of the WTP design capacity. This result may imply that the glass with 26 wt% Al{sub 2}O{sub 3} may not achieve the WTP design production rate. However, this hypothesis is not conclusive because of unknown effects of melter size and operation

  11. Development of Alumina-Forming Austenitic (AFA) Stainless Steels

    E-Print Network [OSTI]

    Pennycook, Steve

    Power Steam Turbine, Boiler Tubing Initial target(s) Tubing in chemical/process industry, etc. also resistance Solar Turbines 4.6 MW Mercury 50 recuperated low NOx gas turbine engine Recuperator, Casing Fossil

  12. Reactive Spreading of a Lead-Free Solder on Alumina

    E-Print Network [OSTI]

    Gremillard, L.; Saiz, E.; Radmilovic, V.R.; Tomsia, A.P.

    2008-01-01

    below 550°C, a solid oxide layer encapsulates the liquidoxidation of tin, a tin oxide layer around the metallic dropto the formation of an oxide layer encapsulating the metal.

  13. CO2-selective, Hybrid Membranes by Silation of Alumina

    SciTech Connect (OSTI)

    Luebke, D.R.; Pennline, H.W.

    2007-09-01

    Hybrid membranes are feasible candidates for the separation of CO2 from gas produced in coal-based power generation since they have the potential to combine the high selectivity of polymer membranes and the high permeability of inorganic membranes. An interesting method for producing hybrid membranes is the silation of an inorganic membrane. In this method, trichloro- or alkoxy-silanes interact with hydroxyl groups on the surface of ?-AlO3 or TiO2, binding organic groups to that surface. By varying the length of these organic groups on the organosilane, it should be possible to tailor the effective pore size of the membrane. Similarly, the addition of “CO2-phillic” groups to the silating agent allows for the careful control of surface affinity and the enhancement of surface diffusion mechanisms. This method of producing hybrid membranes selective to CO2 was first attempted by Hyun [1] who silated TiO2 with phenyltriethoxysilane. Later, Way [2] silated ?-AlO3 with octadecyltrichlorosilane. Both researchers were successful in producing membranes with improved selectivity toward CO2, but permeability was not maintained at a commercially applicable level. XPS data indicated that the silating agent did not penetrate into the membrane pores and separation actually occurred in a thin “polymer-like” surface layer. The present study attempts to overcome the mass transfer problems associated with this technique by producing the desired monolayer coverage of silane, and thus develop a highly-permeable CO2-selective hybrid membrane.

  14. Nanotube fracture during the failure of carbon nanotube/ alumina composites

    E-Print Network [OSTI]

    -based ceramic composites, leading to improved fracture toughness. Ó 2011 Elsevier Ltd. All rights reserved. 1 problem, incorporation of particulates, flakes and short/long fibers into ceramics matrix, as a second, chemical and electrical properties [3­7], motivating their use in ceramic composite materials as a fibrous

  15. Microfluidic Investigation of Tracer Dye Diffusion in Alumina Nanofluids 

    E-Print Network [OSTI]

    Ozturk, Serdar 1979-

    2012-10-05

    on enhanced mass diffusion and the possibility of tailoring mass transport by direct manipulation of molecular diffusion. Therefore, a microfluidic approach capable of directly probing tracer diffusion between nanoparticle-laden fluid streams was developed...

  16. The calcined macroporous alumina was amorphous, exhibiting a considerably high-

    E-Print Network [OSTI]

    than the zirconia or titania samples. The walls of this sample appeared to be amorphous films by ED and TEM (Fig. 3), yet the 3D packing of the macro- pores in this sample was similar to that for zirconia Engineering (CIE) at the University of Minnesota for a CIE-NSF graduate fellowship. 7 April 1998; accepted 5

  17. Behavior of alumina particles in atmospheric pressure plasma jets

    SciTech Connect (OSTI)

    Fincke, J.R.; Swank, W.D.

    1990-01-01

    The distribution of Al{sub 2}O{sub 3} particle size, velocity and temperature was mapped over the flow field of a 31.5 kW plasma torch. The effects of varying the powder loading were studied. The powder feed rate was varied between .45 and 2.05 kg/hr independent of the carrier gas flow rate. The particle flow field was non-symmetric due to the method of particle injection. The data indicate that powder feed rate does not significantly affect either the temperature or velocity of the particles, for typical plasma spray conditions, and that the assumption of a dilute particle flow field is valid. 1 ref., 7 figs.

  18. Lithium battery electrodes with ultra-thin alumina coatings

    DOE Patents [OSTI]

    Se-Hee, Lee; George, Steven M.; Cavanagh, Andrew S.; Yoon Seok, Jung; Dillon, Anne C.

    2015-11-24

    Electrodes for lithium batteries are coated via an atomic layer deposition process. The coatings can be applied to the assembled electrodes, or in some cases to particles of electrode material prior to assembling the particles into an electrode. The coatings can be as thin as 2 .ANG.ngstroms thick. The coating provides for a stable electrode. Batteries containing the electrodes tend to exhibit high cycling capacities.

  19. Value recovery from spent alumina-base catalyst

    DOE Patents [OSTI]

    Hyatt, David E. (Northglenn, CO)

    1987-01-01

    A process for the recovery of aluminum and at least one other metal selected from the group consisting of molybdenum, nickel and cobalt from a spent hydrogenation catalyst comprising (1) adding about 1 to 3 parts H.sub.2 SO.sub.4 to each part of spent catalyst in a reaction zone of about 20.degree. to 200.degree. C. under sulfide gas pressure between about 1 and about 35 atmospheres, (2) separating the resultant Al.sub.2 (SO.sub.4).sub.3 solution from the sulfide precipitate in the mixture, (3) oxidizing the remaining sulfide precipitate as an aqueous slurry at about 20.degree. to 200.degree. C. in an oxygen-containing atmosphere at a pressure between about 1 and about 35 atmospheres, (4) separating the slurry to obtain solid molybdic acid and a sulfate liquor containing said at least one metal, and (5) recovering said at least one metal from the sulfate liquor in marketable form.

  20. Comment on ``Capillary Filling of Anodized Alumina Nanopore Arrays''

    E-Print Network [OSTI]

    Caupin, Frédéric

    partial with a contact angle , Tm is lowered [2]. The hysteresis width is multiplied by 2 cos ÿ 1; 53, this Comment questions some conclusions of Ref. [1]. Adsorption is usually measured at constant temperature the liquid volume fraction V as a function of p P=PsatT. Alvine et al. measure V as a function

  1. Optimized Alumina Coagulants for Water Purification - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access toOctober 1996TechnologiesDistribution, andSpectroscopy

  2. Alumina and Aluminum (2010 MECS) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y AEfficiency RebateFederal Energy

  3. A study of a lime-free calcium arsenate and lime-free calcium arsenate mixed with organic insecticides for cotton insect control 

    E-Print Network [OSTI]

    Roussel, John Severin

    1950-01-01

    Precipitation is an important element in the hydrological cycle. To predict and simulate large-scale precipitation, Global Circulation Models (GCMs) are widely used. However, their grid scale is too big to apply to local ...

  4. Teaching Organic Farming and Gardening: Resources for Instructors, 3rd Edition. Part 2 - Applied Soil Science

    E-Print Network [OSTI]

    2015-01-01

    minerals, such as iron, lime (calcium carbonate), and4. Acid soils and liming Lime (calcium carbonate) is addedhigh in calcium (such as lime, gypsum, or dolomite) or by

  5. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    http://www.wbcsd.ch/web/projects/cement/pop-report.pdfShui Ni 1 and Shui Ni 2 cement plants in Shangdong ProvinceReferences Ash Grove Cement, n.d. , “Cement Manufacturing

  6. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    also used for drying coal in heat recovery boilers to raiseheat recovery components (boilers, raw meal dryer, coal feedheat recovery, exhaust gases include flue products from coal

  7. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    coal ash analysis The chemical composition analysis of raw meal, clinker, and the physical properties

  8. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    combustion products such as carbon dioxide (CO 2 ), carbon monoxide (combustion decreased. The concentration of carbon monoxidecombustion products that now include primarily carbon dioxide (CO 2 ) and nitrogen (N 2 ) with small amounts of carbon monoxide (

  9. Improvement of kiln design and combustion/carbonization timing to produce charcoal from agricultural waste in Developing countries

    E-Print Network [OSTI]

    Martinez, Jason A. (Jason Alexander)

    2006-01-01

    Current economic conditions in third world countries like Haiti are so poor that the majority of the population has no access to energy sources that people in the first world take for granted. In Haiti the last two percent ...

  10. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    system that uses steam and turbine generators to produce upwater to cooling towers Steam Turbine Generator Waste Heatcombustion (CO gas) ? Steam turbine condenser cooling water

  11. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    recovery systems such as a cogeneration plant and the heatedplant has installed a cogeneration system that uses steamequipment as well as the cogeneration system. The data were

  12. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    dryer that uses heat from boiler exhaust gases to reduce thedrying coal in heat recovery boilers to raise steam, and forup to 6 MW power. The boilers use the heat of exhaust gases

  13. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    heat, based on 60% heat recovery, is approximately 12.5 GJ/Illustration of Reburn and Heat Recovery System Arrangementto this, it also uses heat recovery systems such as a

  14. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    to this, it also uses heat recovery systems such as afor drying coal in heat recovery boilers to raise steam, andWith this degree of heat recovery, exhaust gases include

  15. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    values are represented in pie chart (Figure 3) format toin the system. The pie chart indicates that major users ofof coal. The following pie-chart (Figure 13) and Sankey

  16. Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2013-01-01

    systems such as a cogeneration plant and the heated air togenerated from the cogeneration plant and take credit forequivalent heat. The cogeneration plant produces 6 MW

  17. Follow that mercury!

    SciTech Connect (OSTI)

    Linero, A.A.

    2008-07-01

    The article discusses one technology option for avoiding release of mercury captured by power plant pollution control equipment in order to render it usable in concrete. This is the use of selective catalytic reduction for NOx control and lime spray dryer absorbers (SDA) for SO{sub 2} control prior to particulate collection by fabric filters. In this scenario all mercury removed is trapped in the fabric filter baghouse. The US EPA did not establish mercury emission limits for existing cement plants in the latest regulation 40 CFR 63, Subpart LLL (December 2006) and was sued by the Portland Cement Association because of the Hg limits established for new kilns and by several states and environmental groups for the lack of limits on existing ones. A full version of this article is available on www.acaa-usa.org/AshatWork.htm. 2 figs.

  18. Lemon: an MPI parallel I/O library for data encapsulation using LIME

    E-Print Network [OSTI]

    Albert Deuzeman; Siebren Reker; Carsten Urbach; for the ETM Collaboration

    2011-06-21

    We introduce Lemon, an MPI parallel I/O library that is intended to allow for efficient parallel I/O of both binary and metadata on massively parallel architectures. Motivated by the demands of the Lattice Quantum Chromodynamics community, the data is stored in the SciDAC Lattice QCD Interchange Message Encapsulation format. This format allows for storing large blocks of binary data and corresponding metadata in the same file. Even if designed for LQCD needs, this format might be useful for any application with this type of data profile. The design, implementation and application of Lemon are described. We conclude with presenting the excellent scaling properties of Lemon on state of the art high performance computers.

  19. In-situ synchrotron microtomography reveals multiple reaction pathways during soda-lime glass synthesis

    E-Print Network [OSTI]

    Emmanuelle Gouillart; Michael J. Toplis; Julien Grynberg; Marie. -Helene Chopinet; Elin Sondergard; Luc Salvo; Michel Suéry; Marco Di Michiel; Gael Varoquaux

    2012-01-11

    Ultrafast synchrotron microtomography has been used to study in-situ and in real time the initial stages of silicate glass melt formation from crystalline granular raw materials. Significant and unexpected rearrangements of grains occur below the nominal eutectic temperature, and several drastically different solid-state reactions are observed to take place at different types of intergranular contacts. These reactions have a profound influence on the formation and the composition of the liquids produced, and control the formation of defects.

  20. The effects of lime and amines on the aging of asphalts and recycling agents 

    E-Print Network [OSTI]

    Wisneski, Mary Luvola

    1995-01-01

    , and AAF-F3. The experiments were designed and performed to study the oxidation rates, the hardening rates, the hardening susceptibilities, and if possible, the prediction of the critical times for pavement failure due to the hardening of the asphalt...

  1. Sulfate Induced Heave: Addressing Ettringite Behavior in Lime Treated Soils and in Cementitious Materials 

    E-Print Network [OSTI]

    Kochyil Sasidharan Nair, Syam Kumar

    2012-02-14

    were monitored simultaneously for mixtures subjected to different environmental conditions. The observations verified the role of water in causing expansion when ettringite mineral is present. Sorption of water by the ettringite molecule was found...

  2. Volatile fatty acid fermentation of lime-treated bagasse by rumen microorganisms 

    E-Print Network [OSTI]

    Lee, Chang-Ming

    1993-01-01

    raw substrate (or 0.82 g VFA/g dry ash-free substrate or 0.94 g VFA/g dry ash-free, lignin- free substrate). This is greater than yields previously reported in the literature using lignocellulosic substrates, and hence demonstrates the superiority...

  3. The Relation of Lime and Phosphoric Acid to the Growth and Bone Development of White Rats. 

    E-Print Network [OSTI]

    Blum, J. K. (Joseph Kelly)

    1931-01-01

    KNOX M S. AnzmalNusbandry L. MACKEY, M. S., Anzmal Husbandry A. L: DARN~LL, M: A., Dairy Husbandry - Dean School of Veterinary Medicine. ?As of January 1. 1932. :In cooperation with U. S. Department of Agriculture. The importance of a sufficient...

  4. Development and evaluation of lime enhanced refuse-derived fuel (RDF) pellets

    SciTech Connect (OSTI)

    Ohlsson, O.O.

    1996-12-31

    The disposal of municipal solid waste (MSW) is of increasing concern for municipalities and state governments throughout the US. There are two technologies currently in use for the combustion of MSW: (1) mass burning in which unprocessed MSW is burned in a heat recovery furnace, and (2) a refuse-derived fuel (RDF) product, which consists of the organic (combustible) fraction of MSW which has been processed to produce a more homogeneous fuel product than raw MSW. The RDF is either marketed to outside users or combusted on-site in a dedicated or existing furnace. In an attempt to alleviate the problems encountered with RDF as a feedstock, Argonne National Laboratory (ANL) and the University of North Texas (UNT) under the sponsorship of the US Department of Energy (DOE) began a multi-phase research study to investigate the development of a low-cost binder that would improve the quality of RDF pellets.

  5. Spring 2010 Anders Plejdrup Houmller, CEO, BlueLime Consulting, Karetmagervej 21 A, DK-7000 Fredericia

    E-Print Network [OSTI]

    market and a retail market and there are the three usual players: the producers, the retailers Electricity Market 1. The market When the electricity market is liberalised, electricity becomes a commodity and the end users. However, for electricity, a more advanced trading pattern quickly develops. New players

  6. Sugarcane juice extraction and preservation, and long-term lime pretreatment of bagasse 

    E-Print Network [OSTI]

    Granda Cotlear, Cesar Benigno

    2005-02-17

    of bagasse showed two delignification phases: bulk (rapid) and residual (slow). These were modeled by two simultaneous first-order reactions. Treatments with air purging and higher temperatures (50 ? 57oC) delignified more effectively, especially during...

  7. Impacts of ocean acidification and mitigative hydrated lime addition on Pacific oyster larvae

    E-Print Network [OSTI]

    aquaculture; Pacific Northwest #12;v Dedication Tomymother,Ann.Throughlifeyouhaveshownmewhat realstrengthis.......................................................................................................................... iv Dedication...............

  8. DOE - Office of Legacy Management -- New England Lime Co - CT 10

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth Dakota Edgemont,Manufacturing -Nevada Test Site - 023

  9. Fried Green Tomatoes with Marinara................................ 7 Homemade Guacamole ........................................................... 6

    E-Print Network [OSTI]

    Arnold, Jonathan

    Key Lime Pie...................... 5 Lime tart with made from scratch graham cracker crust Flourless

  10. International Best Practices for Pre-Processing and Co-Processing Municipal Solid Waste and Sewage Sludge in the Cement Industry

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    Asia Pacific Partnership Cement Task Force (APP). 2010.07(3) Utilizing Biosolids in Cement Kilns. (November). Asia-Utilising Biosolids in Cement Kilns. Final Report. Available

  11. EA-0405: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Innovative Sulfur Dioxide Scrubbing System for Coal Burning Cement Kilns, Passamaquoddy Tribe Thomaston, Maine

  12. EFFICACY AND TIMING OF FUNGICIDES, BACTERICIDES, AND BIOLOGICALS for DECIDUOUS TREE FRUIT, NUT, STRAWBERRY, AND VINE CROPS 2010

    E-Print Network [OSTI]

    Adaskaveg, James E; Gubler, W D; Michailides, Themis J.; Holtz, Brent A.

    2010-01-01

    Ziram Copper 14 Copper + oil 14 Lime sulfur 12 Sulfur 4,12Dormant treatment with liquid lime sulfur improves efficacychemistry. Use liquid lime sulfur in dormant applications

  13. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Harvey, John T; Lu, Qing

    2005-01-01

    25. Admixtures used (lime, liquid anti- strip, etc. ) Mixuse of anti-strip additive (lime or liquid), and pavementeffectiveness of both hydrated lime and liquid anti-strip

  14. Bubble Transport in Three-Dimensional Gravity Driven Flow, Part I. Mathematical Formulation

    E-Print Network [OSTI]

    Pilon, Laurent; Fedorov, Andrei G.; Ramkrishna, D; Viskanta, Raymond

    2004-01-01

    rising gas bubble in a soda-lime silicate glass melt”,Optical properties of soda-lime silicate”, Solar Energyof characteristics. Keywords: soda-lime silicate glass,

  15. Effect of submergence on alleviation of soil acidity and availability of nutrients in a rice-rice ecosystem

    E-Print Network [OSTI]

    Bhaskaran, Usha Pankajam Dr.; Varghese, Thomas Dr

    2009-01-01

    with manganese dioxide and lime. Proc. Bankok Symp. Acidsubmergence, application of lime @ 1000 kgha -1 and washingrice without addition of lime. Fig. 1 Kinetics of av ailable

  16. Dictionary of Upriver Halkomelem, Volume I

    E-Print Network [OSTI]

    Galloway, Brent Douglas

    2009-01-01

    + fruit juice) lemon-lime juice:: t’át’ets’em qwíyqwòyèlsyellowish fruit] + and + the + lime fruit [itself lime:: t’át’ets’em tsqwáyqwòyèls (

  17. EFFICACY AND TIMING OF FUNGICIDES, BACTERICIDES, AND BIOLOGICALS for DECIDUOUS TREE FRUIT, NUT, STRAWBERRY, AND VINE CROPS 2010 (updated 5/1/10)

    E-Print Network [OSTI]

    Adaskaveg, James E; Gubler, W D; Michailides, Themis J.; Holtz, Brent A.

    2010-01-01

    Ziram Copper 14 Copper + oil 14 Lime sulfur 12 Sulfur 4,12Dormant treatment with liquid lime sulfur improves efficacychemistry. Use liquid lime sulfur in dormant applications

  18. Coping with Congestion: Understanding the Gap Between Policy Assumptions and Behavior

    E-Print Network [OSTI]

    Salomon, Ilan; Mokhtarian, Patricia L.

    1997-01-01

    An integrated model of lime estimation. In Time.md HumanThe rational locator Why travel limes have remained viablefor classification. The lime horizon to which individuals

  19. Evaluating the effectiveness of calcium hydroxide nanoparticle dispersions for the consolidation of painted earthen architectural surfaces

    E-Print Network [OSTI]

    Lohnas, Dawn Elise

    2012-01-01

    conservation: nanometric slaked lime saves architectonic and1960. Reactions of hydrated lime with pure clay minerals inbased on dispersions of lime in alcohol. Studies in

  20. Interactions of pod-zone pH and Ca concentrations on reproductive growth of groundnut (Arachis hypogaea L.)

    E-Print Network [OSTI]

    Murata, Monica R; Zharare, Godfrey Elijah; Hammes, Piet S

    2009-01-01

    Davis, 1994). Thus, both lime and gypsum applications areapplication of both lime and gypsum, which necessitates afor groundnut production. Lime applications in groundnut

  1. Effects of fertilization on the vascular ground vegetation of European beech (Fagus sylvatica L.) and sessile oak (Quercus petraea (Matt.) Lieb.) stands

    E-Print Network [OSTI]

    Misson, Laurent

    2001-01-01

    F. , Impact of dolomite lime on the ground vegetation and ontreatment were applied next to control plots (dolomite lime,dolomite lime + natural phosphate + potassium sulphate).

  2. Faience Technology

    E-Print Network [OSTI]

    Nicholson, Paul

    2009-01-01

    a mixture of silica, soda, and lime reacted together duringquartz), alkali (soda), and lime reacted together duringtimes, when a soda-lime-silicate glaze was applied over the

  3. An Evaluation of Ethyl Silicate-Based Grouts for Weathered Silicate Stones

    E-Print Network [OSTI]

    Dolph, Brittany Helen

    2014-01-01

    evaluation of hydraulic lime grouts for the strengthening ofAnalysis of Hydraulic Lime Grouts for Masonry Repair. ”are almost exclusively lime- and cement- based products.

  4. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Lu, Qing

    2005-01-01

    effectiveness of both hydrated lime and liquid antistripping25. Admixtures used (lime, liquid anti- strip, etc. ) Mixeffectiveness of both hydrated lime and liquid antistripping

  5. Agricultural and Resource Economics Update

    E-Print Network [OSTI]

    Lee, Hyunok; Sumner, Daniel A.; Martin, Philip; Hochman, Gal; Rajagopal, Deepak; Zilberman, David

    2011-01-01

    fresh grapefruit, lemons, and limes is growing. Other fruitsbeef offal, lemons and limes, grapefruit (fresh & juice),grape, apple, lemon, lime, peach, strawberry), walnuts (in

  6. Crossing Borders: The UCSC Women's Center, 1985-2005

    E-Print Network [OSTI]

    2005-01-01

    operation involving both lime production and cattle raising,much larger Henry Cowell Lime and Cement Company based inof the Henry Cowell Lime and Cement Company headquartered in

  7. Radiation Characteristics of Glass Containing Gas Bubbles

    E-Print Network [OSTI]

    Pilon, Laurent; Viskanta, Raymond

    2003-01-01

    Optical properties of soda-lime silicate”, Solar Energye?ciency factors of the soda-lime silicate containing gasscattering albedo of soda-lime silicate glass containing

  8. EFFICACY AND TIMING OF FUNGICIDES, BACTERICIDES, AND BIOLOGICALS for DECIDUOUS TREE FRUIT, NUT, STRAWBERRY, AND VINE CROPS 2011

    E-Print Network [OSTI]

    Adaskaveg, J E; Gubler, W D; Michailides, Themis J.; Holtz, Brent A.

    2011-01-01

    Copper 14 Copper + oil 14 Lime sulfur 12 Sulfur 4,12 ND NDDormant treatment with liquid lime sulfur improves efficacychemistry. Use liquid lime sulfur in dormant applications

  9. Life Cycle Regulation of Transportation Fuels: Uncertainty and its Policy Implications

    E-Print Network [OSTI]

    Plevin, Richard Jay

    2010-01-01

    4.4.7. Agricultural lime . . . . . . . . .for the contribution of lime to CO 2 release from managedand CO 2 emissions from lime and urea application. Technical

  10. Spent Shale Grouting of Abandoned In-Situ Oil Shale Retorts

    E-Print Network [OSTI]

    Fox, J.P.; Persoff, P.

    1980-01-01

    and L. L. Morriss, "Free Lime in Retorted Oil Shale," Energystrength hydraulic cement by lime addition to Lurgi spentcompounds are formed from lime and silica produced by the

  11. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01

    1969. "Scrubber Survey: a Lime/Limestone Trend," ElectricalMills/Kwh Process Limestone Lime Magnesia Cat-Ox Sodium Tonsto Unsaturated Operation of Lime and Limestone Scrubbers,"

  12. EFFICACY AND TIMING OF FUNGICIDES,BACTERICIDES, AND BIOLOGICALS for DECIDUOUS TREE FRUIT, NUT, STRAWBERRY, AND VINE CROPS 2010 (rev. April 1, 2010)

    E-Print Network [OSTI]

    Adaskaveg, J E; Gubler, W D; Michailides, Themis J.; Holtz, Brent A.

    2010-01-01

    Ziram Copper 14 Copper + oil 14 Lime sulfur 12 Sulfur 4,12Dormant treatment with liquid lime sulfur improves efficacychemistry. Use liquid lime sulfur in dormant applications

  13. A Molecular Genetic Approach to Evaluate a Novel Seedless Phenotype Found in Tango, a New Variety of Mandarin Developed From Gamma-Irradiated W. Murcott

    E-Print Network [OSTI]

    Crowley, Jennifer Robyn

    2011-01-01

    relationships among lemons, limes and citron: a chromosomalrelationships among lemons, limes and citron: a chromosomalbp B. HindIII-? 1 kb Abhay. Lime EcoRI Abhay. Lime control

  14. Citrus Offers Year-Round Options

    E-Print Network [OSTI]

    Martin, Orin

    2008-01-01

    are somewhere between a lemon and a lime. Great in lemonade-like drinks. A good lime substitute in cool growing areas.Etrog, Buddha’s Hand Fruit Limes: Mexican, Bearss, Key Lime,

  15. Hydrolysis of COS and CS{sub 2} over alumina catalysts at lower temperature

    SciTech Connect (OSTI)

    Shangguan Ju; Li Chunhu; Guo Hanxian [Taiyuan Univ. of Technology, Shanxi (China). Research Inst. of Chemical Engineering for Coal

    1997-12-31

    Carbonyl sulfide (COS) and carbon disulfide (CS{sub 2}) widely exist in chemical processing gases from natural gas, coal, Claus tail gas, and petroleum. Those sulfur compound are a major factor of deactivation of synthesis catalysts. Since it is difficult to remove COS and CS{sub 2} completely by the conventional desulfurization, a hydrolysis process has been developed in recent years. The activity of COS and CS{sub 2} hydrolysis was measured in a fixed bed reactor and the surface basicity was studied by CO{sub 2}-TPD. The results showed that the apparent reaction activation energies of COS over three catalysts are 57.80, 52.50 and 44.71 kJ/mol at lower temperature, and those of CS{sub 2}, 55.53, 38.70 and 35.30 kJ/mol, respectively. The apparent activation energies of desorption for weak type basic center over three catalysts were 25.97, 27.92 and 29.77kJ/mol respectively. The surface basicity on catalysts played an important role in the hydrolysis of COS and CS{sub 2}.The weak basic center was the catalytic active center of COS hydrolysis, while the weak and the weaker basic centers took part in catalytic reaction of CS{sub 2} hydrolysis. The K{sub 2}O and Pt loaded on active {gamma}-Al{sub 2}O{sub 3} could greatly change the distribution of surface basicity over catalysts and increase organic sulfide catalytic hydrolysis.

  16. Refractory Materials based on Magnesia-Alumina Spinel for Improved Performance in Coal Gasification Environments

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Armstrong, Beth L [ORNL; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla

    2013-01-01

    As part of a larger project to develop novel refractory systems and techniques to reduce energy consumption of refractory lined vessels, a team composed of Oak Ridge National Laboratory, refractory manufacturer Minteq International, Inc., and academic partner Missouri University of Science and Technology have developed new refractory materials and coating systems specifically for application in coal gasification environments. Materials were developed under this U.S. DOE funded project to address the need for innovative refractory compositions by developing MgO-Al2O3 spinel gunnable refractory compositions utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. Work was conducted to develop and deploy these new materials and to develop and apply low cost coatings using a colloidal approach for protection against attack of the refractory brick by the serviced environment. Additionally, a light-weight back-up refractory system was developed to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the efforts involved in the development of these materials, along with the laboratory testing and evaluation of these materials leading to relevant results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment though compositional and processing modifications.

  17. NMR studies of superionic 03B2-aluminas J. L. Bjorkstam

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    importance as the ion conduction medium in high energy density electrical storage systems and the unusual fluctuations responsible for relaxa- tion. A minimum in T1 is expected when mo i - 1 (where mo is the NMR measuring frequency). In this case, T 1 vs. T measurements in solid electrolytes provide a way

  18. Effect of heat treatment on the catalytic activity of activated alumina 

    E-Print Network [OSTI]

    Farrar, Gerald Leland

    1950-01-01

    and constant feed com- position: to dxc Iko f(xc) ko' f'(xc)j a s L 8f fraction reactant converted k ~ forward reaction rate constant k a L s k'~ reverse reaction rate constant ko' a L s Wc weight of catalyst nt mole of feed ner unit time a ~ area per... unit mass of catalyst L active spots per unit area s ~ number of equidistant~ active spots ad)acent to each spot, needed by and available for reaction (assumed constant in this case) Let [ko f(xc) k ' f'(x )] 15(xc) Separating variables...

  19. Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application

    E-Print Network [OSTI]

    Kasagi, Nobuhide

    . A heat exchanger with a temperature efficiency of 0.78 is assumed for heat recirculation. Thus as high as 850 o C and extremely high heat generation density of 2-5x108 W/m3 has been achieved been made for radial-flow-type combustors using Fluent 6 (Fluent Inc.). Figure 1 shows a radial-flow-type

  20. Method And Reactor For Production Of Aluminum By Carbothermic Reduction Of Alumina

    DOE Patents [OSTI]

    Aune, Jan Arthur (Ytre Enebakk, NO); Johansen, Kai (Kristiansand, NO)

    2004-10-19

    A hollow partition wall is employed to feed carbon material to an underflow of a carbothermic reduction furnace used to make aluminum. The partition wall divides a low temperature reaction zone where aluminum oxide is reacted with carbon to form aluminum carbide and a high temperature reaction zone where the aluminum carbide and remaining aluminum oxide are reacted to form aluminum and carbon monoxide.

  1. Hybrid Filtration Membranes incorporating Nanoporous Silica within a Nanoscale Alumina Fibre Scaffold

    E-Print Network [OSTI]

    Su, Veronica Mei Tiing; Clyne, Trevor William

    2015-06-11

    peristaltic pump. The pressure drop across the membrane was approximately 0.1-0.7 bar. Corresponding volumetric flow rates were measured. Fig.1 Schematic depiction of the set-up employed for measurement of the membrane permeability and the filtration... thoroughly with DI water. A vacuum pump was used to draw out trapped air within the bundles and promote water penetration. Excess water was removed with a pipette and the samples were dried at 80?C overnight. The volume fraction of fibre in the assembly...

  2. Ordered mesoporous crystalline aluminas from self-assembly of ABC triblock terpolymer

    E-Print Network [OSTI]

    Gruner, Sol M.

    of metal oxide a Department of Materials Science and Engineering, Cornell University, Ithaca, New York for various high temperature catalysis, separation, and energy- related applications. Introduction Porous-b-PPO-b-PEO) triblock copolymers and Al2O3 sol precursors with controlled hydrolysis rates.21 An alternative route

  3. ORNL's alumina-forming austenitic alloy family licensed to Carpenter Technology Corp.

    E-Print Network [OSTI]

    Pennycook, Steve

    exchangers for CHP (Combined Heat and Power) turbines able to operate reliably at higher temperature, thereby with excellent high temperature oxidation resistance. Increased deployment of AFA steels can lead to heat-walled heat exchangers (recuperators) which is an especially demanding application for creep and corrosion

  4. Alumina-Supported Trirhenium Clusters: Stable High-Temperature Catalysts for Methylcyclohexane Conversion

    SciTech Connect (OSTI)

    Lobo-Lapidus, R.J.; McCall, M.J.; Lanuza, M.; Tonnesen, S.; Bare, S.R.; Gates, B.C.

    2009-05-19

    Samples prepared from H{sub 3}Re{sub 3}(CO){sub 12} adsorbed on porous {gamma}-Al{sub 2}O{sub 3} were decarbonylated at 773 K in flowing H{sub 2} and characterized by X-ray absorption spectroscopy (XAS). X-ray absorption near-edge spectra show that rhenium in the treated sample was cationic, and extended X-ray absorption fine structure spectra show a Re-Re first-shell coordination number of approximately 2, consistent with trirhenium clusters bonded to the support. The samples were tested as catalysts for the conversion of methylcyclohexane in the presence of H{sub 2} at atmospheric pressure and at 723 and at 773 K in a flow reactor. A range of hydrocarbon products was observed, indicating the occurrence of dehydrogenation, isomerization, ring opening, and hydrocracking reactions. The catalyst used at 723 K underwent deactivation over a period of several hours, during which the selectivity for the major dehydrogenation product (toluene) increased significantly. At 773 K, the catalyst underwent activation, during which the product distribution changed. This increase in activity was retained when the temperature was reduced to 723 K, resulting in higher activity and different selectivity relative to what had been observed before at this temperature. The fresh and used catalyst samples were characterized by X-ray absorption spectroscopy, which showed that the trirhenium framework remained intact after catalysis, although changes in the rhenium coordination were observed. The catalytically active species are inferred to be trirhenium.

  5. Strains in Thermally Growing Alumina Films Measured in-situ usingSynchrotron X-rays

    SciTech Connect (OSTI)

    Hou, P.Y.; Paulikas, A.P.; Veal, B.W.

    2006-01-02

    Strains in thermally grown oxides have been measured in-situ, as the oxides develop and evolve. Extensive data have been acquired from oxides grown in air at elevated temperatures on different model alloys that form Al{sub 2}O{sub 3}. Using synchrotron x-rays at the Advanced Photon Source (Beamline 12BM, Argonne National Laboratory), Debye-Scherrer diffraction patterns from the oxidizing specimen were recorded every 5 minutes during oxidation and subsequent cooling. The diffraction patterns were analyzed to determine strains in the oxides, as well as phase changes and the degree of texture. To study a specimen's response to stress perturbation, the oxidizing temperature was quickly cooled from 1100 to 950 C to impose a compressive thermal stress in the scale. This paper describes this new experimental approach and gives examples from oxidized {beta}-NiAl, Fe-20Cr-10Al, Fe-28Al-5Cr and H{sub 2}-annealed Fe-28Al-5Cr (all at. %) alloys to illustrate some current understanding of the development and relaxation of growth stresses in Al{sub 2}O{sub 3}.

  6. Alumina Nanoparticle Pre-coated Tubing Ehancing Subcooled Flow Boiling Cricital Heat Flux

    E-Print Network [OSTI]

    Truong, Bao H.

    Nanofluids are engineered colloidal dispersions of nano-sized particle in common base fluids. Previous pool boiling studies have shown that nanofluids can improve critical heat flux (CHF) up to 200% for pool boiling and ...

  7. On characterisation of wire-arc-plasma-sprayed Ni on alumina substrate

    SciTech Connect (OSTI)

    Laik, A.; Chakravarthy, D.P.; Kale, G.B. . E-mail: gbkale@apsara.barc.ernet.in

    2005-08-15

    A study was carried out on metal-ceramic bonding produced by the technique of wire-arc-plasma spraying of Ni on Al{sub 2}O{sub 3} substrate. The Ni layer and the Ni/Al{sub 2}O{sub 3} interface were characterised using optical and electro-optic techniques. The plasma-deposited Ni layer shows a uniform lamellar microstructure throughout the cross-section. The metal-ceramic interface was found to be well bonded with no pores, flaws or cracks in the as-sprayed condition. The optical metallography and concentration profiles established with the help of an electron probe microanalyser confirmed the absence of any intermediate phase at the interface. An annealing treatment at 1273 K for 24 h on the plasma-coated samples did not result in formation of any intermetallic compound or spinel at the Ni/Al{sub 2}O{sub 3} interface. This indicates that the oxygen picked up by Ni during the spraying operation is less than the threshold value required to form the spinel NiAl{sub 2}O{sub 4}.

  8. Why ion-doped, PZC-altered silica and alumina fail to influence platinum adsorption

    E-Print Network [OSTI]

    Regalbuto, John R.

    the adsorption of either cationic amine or anionic chloride complexes of Pt(IV) [1]. This follow-up work explored]. The hydroxyl groups that populate oxide surfaces become protonated and so positively charged or depro- tonated

  9. Electrodeposition of Indium Antimonide Nanowires in Porous Anodic Alumina Asaduzzaman Mohammad1

    E-Print Network [OSTI]

    Chen, Yong P.

    uses a reverse anodization technique to penetrate the hemispherical pore bottom barrier oxide layer to break through the pore bottom barrier oxide layer including chemical or plasma etching processes [5, 9

  10. Effects of specimen thickness and impurity on the conductivity of alumina under electron irradiation

    E-Print Network [OSTI]

    Howlader, Matiar R

    windows in the International Thermonuclear Experimental Reactor (ITER), where the electrical conductivity believed to be critical issues for the application of a-Al2O3 to insulators in fusion reac- tors. The RIC

  11. Acidity and catalytic activity of zeolite catalysts bound with silica and alumina 

    E-Print Network [OSTI]

    Wu, Xianchun

    2004-09-30

    . The acidities of the bound catalysts and the zeolite powder are determined by NH3-TPD and FTIR. The textures of these catalysts are analyzed on a BET machine with nitrogen as a probe molecule. The micropore surface area and micropore volume are determined by t...

  12. SubstrateSubstrate Commercially available high density -alumina plate (14x14 mm2)

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    440 450 460 470 480 490 500 510 520 530 540 OHM SubstrateSubstrate Commercially available high followed by oxidation in a well-defined pO2 regime near the M-MOx proximity line by a suitable buffer gas Model. Fig. 4. Thermodynamic criteria for several M/MOx coexistence and practical pO2 regimes for phase

  13. Chemical bath method to grow precipitated nanorods of iridium oxide on alumina membranes

    E-Print Network [OSTI]

    Chiao, Jung-Chih

    and chemical stability, such as ZnO, OsO2, RuO2, TiO2 and IrO2 have been used as materials for durableO2 on high-density carbon nanotubes (CNTs) to form IrO2/CNT nanocomposites. Although the growth

  14. Epoxy-based carbon films with high electrical conductivity attached to an alumina substrate

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    of nanotubes. The carbon film with 2.5 vol.% nickel showed resistivity 6 · 10À3 X cm. Ó 2008 Elsevier Ltd. All, and multiwalled carbon nanotube (MWCNT) were used as conductive fillers. Nickel nanoparticle (Inco 210 H, Inco Ltd gave crack-free and scratch resistant carbon films. Interconnected filamentary nickel nanoparticles

  15. Strengthening and toughening of carbon nanotube reinforced alumina nanocomposite fabricated by

    E-Print Network [OSTI]

    Hong, Soon Hyung

    rights reserved. Keywords: Carbon nanotube; Ceramic matrix composite; Molecular level mixing; Spark: one is the weak bonding between CNTs and ceramic matrix and the other is the inhomogeneous distribution of CNTs within the ceramic matrix. Recently, CNTs have been homoge- neously dispersed within

  16. Mullite/Alumina Mixtures for Use as Porous Matrices in Oxide Fiber Composites

    E-Print Network [OSTI]

    Zok, Frank

    ceramic composites. Conditions for the deflection of a matrix crack at a fiber-matrix interface are used to enable damage tolerance in continuous-fiber ceramic composites (CFCCs) has emerged as a new paradigm between matrix structure and composite performance are understood presently at only a rudimentary level

  17. Analysis of the Temporal Evolution of Thermal Conductivity in Alumina-Water Nanofluid 

    E-Print Network [OSTI]

    Fortenberry, Stephen

    2009-09-30

    of several months. This corresponded to a change in the thermal conductivity enhancement realized due to the suspension of nanoparticles in fluid from an initial value of 11.2% to a final value of 7.2%. Temporal evolution of the nanofluid’s thermal...

  18. 1/2 CREEP FRACTURE IN CERAMIC POLYCRYSTALS I. CREEP CAVITATION EFFECTS IN POLYCRYSTALLINE ALUMINA

    E-Print Network [OSTI]

    Porter, J.R.

    2013-01-01

    Met. , 28: ilure Mechanisms in Ceramics J. M. Dynys et al. ,Deformation Mechanisms in Ceramics, 11 R. C. Bradt and R. LEvans, Creep Fracture in Ceramic Polycrystals II. Effect of

  19. 1/2 CREEP FRACTURE IN CERAMIC POLYCRYSTALS I. CREEP CAVITATION EFFECTS IN POLYCRYSTALLINE ALUMINA

    E-Print Network [OSTI]

    Porter, J.R.

    2013-01-01

    non-linearity of creep in the test is found to be minimal.creep deformation under various conditions of stress and temperature. RESULTS AND OBSERVAT Deformation tests

  20. DOI: 10.1002/cphc.200600060 Cu2O Nanowires in an Alumina Template

    E-Print Network [OSTI]

    Okamoto, Koichi

    performed to estimate the optical band gap of Cu2O [a] Dr. J. Lee Fuel Cell Research Center, Korea Institute] Dr. J. Choi Nanomaterials Application Division Korea Institute of Ceramic Engineering and Technology, attractive properties, as well as their unique applications compared with bulk materi- als.[1

  1. Preparation of ceramic matrix and alumina fiber composites for use as solid electrolytes

    DOE Patents [OSTI]

    Dudney, N.J.

    1987-04-30

    A process for making solid electrolytes using a fibrous stabilizing dispersed second phase for enhanced conductivity of the electrolyte after deformation and annealing. 1 tab.

  2. Effects of Slurry Chemistry on the Rate of Agglomeration of Alumina Nanoparticles for Chemical Mechanical Planarization /

    E-Print Network [OSTI]

    Brahma, Neil Anjan

    2013-01-01

    A, 85, 19-27 13. P. H. Tewari and A. W. McLean, J. ColloidA, 85, 19-27 15. P. H. Tewari and A. W. McLean, J. Colloidwith increasing temperature [14]. Tewari and McLean reported

  3. Effect of Alumina Source on the Rate of Melting Demonstrated with Nuclear

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) | SciTech ConnectExperimentsGAMMA-RAY ATTENUATION UPWaste Glass

  4. Speciation and Mobility of Arsenic in Agricultural Lime Gerald T. Schmidt, Ka Hei Lui, and Michael Kersten

    E-Print Network [OSTI]

    -1161Goethite29-713 Ferrihydrite29-712browndendritescrapedoff residueoffirstextractionstep #12;S5 Supplemental reference samples. 7110 7130 7150 Energy [eV] µnorm. brown dendrite in situ goethite 2l ferrihydrite 6l ferrihydrite 7110 7130 7150 Energy [eV] dµ/dE brown dendrite in situ goethite 2l ferrihydrite 6l ferrihydrite

  5. Failure mode analysis for lime/limestone FGD system. Volume III. Plant profiles. Part 1 of 3

    SciTech Connect (OSTI)

    Kenney, S.M.; Rosenberg, H.S.; Nilsson, L.I.O.; Oxley, J.H.

    1984-08-01

    This volume contains plant profiles for: Petersburg 3; Hawthorn 3, 4; La Cygne 1; Jeffry 1, 2; Lawrence 4, 5; Green River 1-3; Cane Run 4, 5; Mill Creek 1, 3; Paddy's Run 6; Clay Boswell 4; Milton R. Young 2; Pleasants 1, 2; and Colstrip 1, 2. (DLC)

  6. Development of Oxidative Lime Pretreatment and Shock Treatment to Produce Highly Digestible Lignocellulose for Biofuel and Ruminant Feed Applications 

    E-Print Network [OSTI]

    Falls, Matthew David

    2011-10-21

    digestibilities (g glucan hydrolyzed/100 g glucan in raw biomass; 15 filter paper units/g raw glucan) of 85.2 and 88.5 were achieved for Dacotah and Alamo, respectively. Adding ball milling to OLP further enhanced glucan digestibility to 91.1 (Dacotah) and 90...

  7. Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants 

    E-Print Network [OSTI]

    Schwartz, M. H.

    1979-01-01

    Over the past decade increasing concern over the potential environmental impact associated with the emissions of both gaseous and particulate pollutants has resulted in the promulgation of strict regulatory standards ...

  8. Disposal techniques with energy recovery for scrapped vehicle tires

    SciTech Connect (OSTI)

    Sladek, T.A.; Demos, E.K.

    1987-06-01

    The scrap tire disposal problem is serious and widespread. However there are a number of promising management options, especially using the rubber as a supplemental fuel for existing combustors. The most cost-effective approach to dealing with Denver's tire stockpile appears to be shredding to a coarse size range, storing the shreds in a secure area, and marketing the rubber to nearby cement kilns, lime kilns, and boilers. This interim step would greatly reduce the volume of the pile, facilitate the Superfund evaluation, reduce fire and disease hazards, and simplify subsequent materials handling. Further processing to obtain rubber chips or crumbs may also be practical. However the industry and the markets would have to emerge over time. New power plants or pyrolysis facilities would be impeded by the low energy prices in Denver and the need for elaborate pollution controls. Landfilling could be considered as a last resort. Landfilling costs would be minimized if the tires are shredded. Chapter 2 discusses the tire disposal problem and the general options for tire management. Chapter 3 describes the methodology used to analyze Denver's situation and presents the results and conclusions obtained. This includes evaluation of strategies to implement the more promising resource recovery options in the Denver area. Chapter 4 summarizes the lessons learned and identifies impediments and uncertainties that need to be addressed in any future studies. The Appendix contains additional acknowledgments, a list of references, definitions for the acronyms and units used in the text, the agenda for the tire workshop, and a brief description of a stockpile fire near Denver in June 1987. 111 refs., 6 tabs.

  9. HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING

    SciTech Connect (OSTI)

    Lucia, Lucian A

    2013-04-19

    Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

  10. Effects of channel morphology and sensor spatial resolution on image-derived depth estimates

    E-Print Network [OSTI]

    Legleiter, Carl J.; Roberts, D A

    2005-01-01

    was observed when the pure lime- stone substrate end memberat all wavelengths if lime- stone were assumed and would be

  11. Oil shale retort apparatus

    DOE Patents [OSTI]

    Reeves, Adam A. (Grand Junction, CO); Mast, Earl L. (Norman, OK); Greaves, Melvin J. (Littleton, CO)

    1990-01-01

    A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.

  12. Nanolithographic Fabrication and Heterogeneous Reaction Studies of Two-Dimensional Platinum Model Catalyst Systems

    E-Print Network [OSTI]

    Contreras, A.M.

    2006-01-01

    of silica, alumina, zirconia, and ceria. These nanowirea) alumina support; (b) zirconia-support; (c) ceria-are silica, alumina, zirconia and ceria…………………109 Table 5.1

  13. 34 JOM May 2001 Inert Anodes

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    nobler than alumina (and almost every- thing is nobler than alumina) will be electrolyzed along with it

  14. Integrated methods for production of clean char and its combustion properties. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    DeBarr, J.A.; Rostam-Abadi, M. [Illinois State Geological Survey, Champaign, IL (United States); Gullett, B.K. [Environmental Protection Agency, Research Triangle, NC (United States); Benson, S.A.; Toman, D.L. [Univ. of North Dakota Energy and Environmental Research Center, Grand Forks (United States)

    1992-08-01

    The overall objective of this two-year program is to produce low sulfur char using an integrated process scheme which combines physical coal cleaning, mild gasification and char desulfurization. The goal of the project is to produce chars with 50% or more lower sulfur emissions than that of the parent coal, and at minimum meet 1995 emission standards of 2.5 lbs S0{sub 2}/MMBtu. This project is a cooperative effort between the ISGS, UNDEERC and the US EPA and is cost-shared with the US EPA and the US DOE through UNDEERC. Mild gasification and char desulfurization studies are conducted with six coals selected from the Illinois Basin Coal (IBC) Sample Program in a batch fluidized-bed reactor at the ISGS. Pound quantities of chars for combustion testing are prepared in a continuous rotary kiln reactor under optimized conditions of mild gasification and char desulfurization. Burning characteristics and ash deposition behaviors of desulfurized chars are determined at the US EPA in a 14 kill pilot-scale combustor and at UNDEERC in a drop tube furnace (DTF). In some tests, methane is examined as an auxiliary fuel, and high-surface-area hydrated lime developed at ISGS is used to further reduce S0{sub 2} emissions. Complete analyses of the fuels are obtained to aid char desulfurization studies and help explain combustion and S0{sub 2} emission characteristics of the char.

  15. Alternative Energy Development and China's Energy Future

    E-Print Network [OSTI]

    Zheng, Nina

    2012-01-01

    Fuel Cycle Processes Thermal Energy Intensity Electricityprocess uses less energy than the dry kiln, and an average of reported thermal

  16. Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    continuous kiln operation (Perkins 2000). For example, Texas Industries has licensed its patented CemStar cement production process

  17. Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases

    E-Print Network [OSTI]

    Rheaume, Jonathan Michael

    2010-01-01

    material has refractory properties that make it also useful for kiln furniture and for thermal barrier coatings for gas turbine

  18. Measurement and Model Correlation of Specific Heat Capacity of Water-Based Nanofluids With Silica, Alumina and Copper Oxide Nanoparticles

    E-Print Network [OSTI]

    O’Hanley, Harry

    Nanofluids are being considered for heat transfer applications. However, their thermo-physical properties are poorly known. Here we focus on nanofluid specific heat capacity. Currently, there exist two models to predict a ...

  19. The effects of chemistry on the colloidal behavior of alumina slurries and copper nanohardness for copper chemical mechanical planarization

    E-Print Network [OSTI]

    Ihnfeldt, Robin Veronica

    2008-01-01

    Int. J. Manufacturing Technology and Management, 7 (5),Journal of Manufacturing Technology and Management, 7 , (Int. J. Manufacturing Technology and Management, 7 (5),

  20. Integration of Self-Assembled Porous Alumina and Distributed Bragg Reflector for Light Trapping in Si Photovoltaic Devices

    E-Print Network [OSTI]

    Sheng, Xing

    Light trapping is an important issue for thin film silicon photovoltaic cells due to the limited absorption coefficient for near infrared light. In this letter, we present a photonic structure that combines porous anodic ...

  1. Oxidation of Pdn (n=17, 10) clusters supported on alumina/NiAl(110) R. Robles and S. N. Khanna*

    E-Print Network [OSTI]

    Rodriguez, Roberto

    .5 One could thus regard the oxide layer as consider- ably reduced. A realistic model of atomic positions selected clusters were deposited on the oxide layer and they measured the shift in the XPS levels

  2. ELSEVIER Journal of Nuclear Materials 239 (1996) 245-252 In situ measurement of electrical conductivity of alumina under

    E-Print Network [OSTI]

    Howlader, Matiar R

    1996-01-01

    the effects of flux, electric field and temperature and may lessen their performance in fusion reactors affect the performance of ct-A1203 in fusion reactors. A significant surface conductivity is confirmed, it is emphasized that RIC and RIED of et-A1203 are not severe for insulators in the International Thermonuclear

  3. Synthesis of silver-zeolite films on micropatterned porous alumina and its application as an antimicrobial substrate

    E-Print Network [OSTI]

    Dutta, Prabir K.

    into a variety of systems, including fabrics, biomaterials, filters and thus can serve a wide range of uses. Ó, crystalline solids with well-defined structure [1,2]. Ion exchange, thermal stability, catalytic properties is not possible with conventional methods of ceramic forming such as dry pressing, whereas with soft lithography

  4. Ballistic impact response of an UHMWPE fiber reinforced laminate encasing of an aluminum-alumina hybrid panel

    E-Print Network [OSTI]

    O'Masta, MR; Compton, BG; Gamble, EA; Zok, FW; Deshpande, VS; Wadley, HNG

    2015-01-01

    response of hybridized thermoplastic laminates. Aberdeenbers are combined with thermoplastic polymer matrices to

  5. Surface characterization of palladium–alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas

    SciTech Connect (OSTI)

    Baltrus, John P. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Granite, Evan J. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Pennline, Henry W. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Stanko, Dennis [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Hamilton, Hugh [Johnson Matthey Plc, Technology Centre, Reading (United Kingdom); Rowsell, Liz [Johnson Matthey Plc, Technology Centre, Reading (United Kingdom); Poulston, Stephen [Johnson Matthey Plc, Technology Centre, Reading (United Kingdom); Smith, Andrew [Johnson Matthey Plc, Technology Centre, Reading (United Kingdom); Chu, Wilson [Johnson Matthey, Malvern, PA (United States)

    2010-06-01

    Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production. The interactions of mercury and arsenic with Pd/Al2O3 model thin film sorbents and Pd/Al2O3 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

  6. Aluminium doped ceria–zirconia supported palladium-alumina catalyst with high oxygen storage capacity and CO oxidation activity

    SciTech Connect (OSTI)

    Dong, Qiang; Yin, Shu Guo, Chongshen; Wu, Xiaoyong; Kimura, Takeshi; Sato, Tsugio

    2013-12-15

    Graphical abstract: Ce{sub 0.5}Zr{sub 0.3}Al{sub 0.2}O{sub 1.9}/Pd/?-Al{sub 2}O{sub 3} possessed high OSC and CO oxidation activity at low temperature. - Highlights: • A new OSC material of Ce{sub 0.5}Zr{sub 0.3}Al{sub 0.2}O{sub 1.9}/Pd/?-Al{sub 2}O{sub 3} is prepared via a mechanochemical method. • Ce{sub 0.5}Zr{sub 0.3}Al{sub 0.2}O{sub 1.9}/Pd/?-Al{sub 2}O{sub 3} showed high OSC even after calcination at 1000 °C for 20 h. • Ce{sub 0.5}Zr{sub 0.3}Al{sub 0.2}O{sub 1.9}/Pd/?-Al{sub 2}O{sub 3} exhibited the highest CO oxidation activity at low temperature correlates with enhanced OSC. - Abstract: The Ce{sub 0.5}Zr{sub 0.3}Al{sub 0.2}O{sub 1.9}/Pd-?-Al{sub 2}O{sub 3} catalyst prepared by a mechanochemical route and calcined at 1000 °C for 20 h in air atmosphere to evaluate the thermal stability. The prepared Ce{sub 0.5}Zr{sub 0.3}Al{sub 0.2}O{sub 1.9}/Pd-?-Al{sub 2}O{sub 3} catalyst was characterized for the oxygen storage capacity (OSC) and CO oxidation activity in automotive catalysis. For the characterization, X-ray diffraction, transmission electron microscopy and the Brunauer–Emmet–Teller (BET) technique were employed. The OSC values of all samples were measured at 600 °C using thermogravimetric-differential thermal analysis. Ce{sub 0.5}Zr{sub 0.3}Al{sub 0.2}O{sub 1.9}/Pd-?-Al{sub 2}O{sub 3} catalyst calcined at 1000 °C for 20 h with a BET surface area of 41 m{sup 2} g{sup ?1} exhibited the considerably high OSC of 583 ?mol-O g{sup ?1} and good OSC performance stability. The same synthesis route was employed for the preparation of the CeO{sub 2}/Pd-?-Al{sub 2}O{sub 3} and Ce{sub 0.5}Zr{sub 0.5}O{sub 2}/Pd-?-Al{sub 2}O{sub 3} for comparison.

  7. Novel High Strength Ceria-Zirconia Toughened Alumina Ceramic with Superior High Temperature Corrosion and Erosion Resistance. Final Report

    SciTech Connect (OSTI)

    Giulio, R.; Butcher, K.

    2004-01-13

    Composite CeTZP/A1{sub 2}O{sub 3} (CeZTA) foams were developed and tested to determine their suitability as particulate filters in hot gaseous conditions generated by coal combustion in electric power plants. Exposure to these extreme corrosive conditions did not cause significant degradation in strength. Superior properties of these foams suggests they could be used for a variety of applications in environment, energy and chemical fields.

  8. Effect of design on the performance of steel-alumina bilayers and trilayers subject to ballistic impact

    E-Print Network [OSTI]

    2015-01-01

    of penetration and perforation. Int. J. Eng. Sci. 16, 793–absorbed during ballistic perforation of composite armours.

  9. Ballistic impact response of an UHMWPE fiber reinforced laminate encasing of an aluminum-alumina hybrid panel

    E-Print Network [OSTI]

    O'Masta, MR; Compton, BG; Gamble, EA; Zok, FW; Deshpande, VS; Wadley, HNG

    2015-01-01

    residual velocities after perforation are also shown. Fig.Plate bulging prior to perforation pre-accelerates the reara prism apex resulted in full perforation with a debris exit

  10. Effect of design on the performance of steel-alumina bilayers and trilayers subject to ballistic impact

    E-Print Network [OSTI]

    2015-01-01

    Inelastic deformation and energy dissipation in ceramics: aAn investigation into the energy absorbed during ballisticresistance Impact Trilayer Energy absorption Damage a b s t

  11. Alumina-Forming Austenitics: A New Approach to Thermal and Degradation Resistant Stainless Steels for Industrial Use

    SciTech Connect (OSTI)

    David A Helmick; John H Magee; Michael P Brady

    2012-05-31

    A series of developmental AFA alloys was selected for study based on: 25 Ni wt.% (alloys A-F), 20 wt% Ni (alloys G-H), and 12 Ni wt.% (alloys I-L). An emphasis in this work was placed on the lower alloy content direction for AFA alloys to reduce alloy raw material cost, rather than more highly alloyed and costly AFA alloys for higher temperature performance. Alloys A-D explored the effects of Al (3-4 wt.%) and C (0.05-0.2 wt.%) in the Fe-25Ni-14Cr-2Mn-2Mo-1W-1Nb wt.% base range; alloys E and F explored the effects of removing costly Mo and W additions in a Fe-25Ni-14Cr-4Al-2.5Nb-2Mn-0.2C base, alloys G and H examined Nb (1-2.5wt.%) and removal of Mo, W in a Fe-20Ni-14Cr-3Al-2Mn-0.2 C wt.% base; and alloys I-L examined effects of C (0.1-0.2 wt.%) and Mn (5-10 wt.%) on a low cost Fe-14Cr-12Ni-3Cu-2.5Al wt.% base (no Mo, W additions). Creep testing resulted in elemental trends that included the beneficial effect of higher carbon and lower niobium in 20-25%Ni AFA alloys and, the beneficial of lower Mn in 12%Ni AFA alloys. Corrosion tests in steam and sulfidation-oxidation environments showed, in general, these alloys were capable of a ten-fold improvement in performance when compared to conventional austenitic stainless steels. Also, corrosion test results in metal-dusting environments were promising and, warrant further investigation.

  12. The effects of chemistry on the colloidal behavior of alumina slurries and copper nanohardness for copper chemical mechanical planarization

    E-Print Network [OSTI]

    Ihnfeldt, Robin Veronica

    2008-01-01

    9 , 64 (2005). M. Pourbaix, Atlas of ElectrochemicalYork, New York (1993). M. Pourbaix, Atlas of Electrochemical389 , 254 (2001). M. Pourbaix, Atlas of Electrochemical

  13. Surface characterizatin of palladium-alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Pennline, H.W.; Stanko, D.; Hamilton, H.; Rowsell, L.; Poulston, S.; Smith, A.; Chu, W.

    2010-01-01

    Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production, The interactions of mercury and arsenic with PdlAl2D3 model thin film sorbents and PdlAh03 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

  14. Radiative Heat Transfer in Enhanced Hydrogen Outgassing of Glass

    E-Print Network [OSTI]

    Kitamura, Rei; Pilon, Laurent

    2009-01-01

    reduction of iron in soda-lime-silicate glasses by reactionand solubility [13]. In soda-lime silicate glass, Johnston0.4 and 0.8 µm for soda-lime silicate. Rapp [9] con?rmed

  15. Nano-structured self-cleaning superhydrophobic glass

    E-Print Network [OSTI]

    Kim, Jin Yeol

    2010-01-01

    images of water droplet on AAO coating on soda lime glass. (a) with as- made AAO on soda lime glass (CA = 54 o ), (b)Al 2 O 3 nanowires on soda lime glass after 65 min pore-

  16. THE CORROSION OF SILICATE MATERIALS BY HYDROGEN GAS AND HYDROFLUORIC ACID SOLUTION

    E-Print Network [OSTI]

    Tso, Stephen T.

    2011-01-01

    Si02 glasses with different lime contents. Fig. 51. ReactionPseudowollosloni Ie Ronkinile Lime I Corundum MuiliteIn the silicate glasses with lime addition, in which the

  17. Communication Paradigms for Mobile Ad Hoc Networks

    E-Print Network [OSTI]

    Collins, Justin Scott

    2014-01-01

    Mur06] Amy L. Murphy et al. “Lime: A Coordination Middlewareof mobile devices using the LIME II tuple-space framework. ”Bogdan Carbunar and et al. “Lime revisited. ” In Mobile

  18. Phosphonate controls sudden oak death pathogen for up to 2 years

    E-Print Network [OSTI]

    Garbelotto, Matteo; Schmidt, Doug

    2009-01-01

    soil amend- ment and bark lime wash was always ineffective,efficacy. Azomite and lime wash. Several un- registered andand using a bark lime wash (see www. suddenoaklife.com).

  19. Some Thoughts on a Teacher, Father Figure, and Mentor

    E-Print Network [OSTI]

    Achebe, Nwando

    2002-01-01

    Ans 10 Hislory and as many limes as I have been asked thaiBoniface Obichere. From lhe lime Ihall was a liule girl. IthaI I was al vari- ous limes a member of my primary school

  20. Control Strategies for Abandoned in situ Oil Shale Retorts

    E-Print Network [OSTI]

    Persoff, P.; Fox, J.P.

    1979-01-01

    suggests cementing lime process, economic required. nicallyand are discussed Pozzolanic lime to [CaO reactions, or Ca(e.g. , to with activity free lime gel. has ability hydrates,

  1. UPTAKE AND REDISTRIBUTION OF PHOSPHORUS (32P) IN CITRUS IS AFFECTED BY ROOTSTOCK VARIETIES

    E-Print Network [OSTI]

    Mattos, Dirceu Jr.; Zambrosi, Fernando C.B.; Boaretto, Rodrigo M.; Quaggio, José A.; Muraoka, Takashi

    2009-01-01

    sweet orange on Rangpur lime (RL) or Cleopatra mandarin (CL)to those either on Rangpur lime or Swingle citrumelo (Mattossweet orange on Rangpur lime [Citrus limonia (L. ) Osb. ] =

  2. INVESTIGATIONS ON HYDRAULIC CEMENTS FROM SPENT OIL SHALE

    E-Print Network [OSTI]

    Mehta, P.K.

    2012-01-01

    MgO, CaO, and silicates of lime and magnesia, show that thecementitious) with no free lime present. Since the presencesilicates or a mixture of free lime ~nd reactive silica is

  3. A Strategy for the Abandonment of Modified In-Situ Oil Shale Retorts

    E-Print Network [OSTI]

    Fox, J.P.; Persoff, P.; Moody, M.M.; Sisemore, C.J.

    1978-01-01

    use spent shale to create a hydraulic lime-pozzolan mortar.is a mixture containing active lime (CaO) and pozzolanicallybelow clinkering on site be- lime- temperatures. Pozzolans

  4. Effect of application of molybdenum in maize-niger cropping System grown on acid soils of high altitude zone of Andhra Pradesh in India

    E-Print Network [OSTI]

    Bhupal, G Raj; Patnaik, M C; Singh, M V; Khadke, K M; Jagannadham, G

    2009-01-01

    cauliflower to molybdenum,lime and their residue on an acidto maize and niger,75% lime Requirement + soil Applicationha -1 to maize and niger,75% lime requirement + foliar Spray

  5. Heat-tolerant Asian HLB meets heat-sensitive African HLB in the Arabian Peninsula! Why?

    E-Print Network [OSTI]

    Bové, Josy

    2014-01-01

    with witches’ broom disease of lime and proposition of aWitches’ broom disease of lime. FAO Plant Prot. Bull. 34:Witches’ broom disease of lime (WBDL) in Iran. In: Proc. 14

  6. Adalbert Wolff: The Cowell Ranch, 1915

    E-Print Network [OSTI]

    Regional History Project, UCSC Library; Wolff, Adalbert; Calciano, Elizabeth Spedding

    1971-01-01

    that. RANCH OPERATIONS Lime Production Calciano: What wereoperations? Was it mostly lime, or were they doing a numberCalciano: Okay. Hauling the Lime Calciano: How did they take

  7. Building Stones

    E-Print Network [OSTI]

    2012-01-01

    UEE 2012 “Concrete” or “lime plaster” made from limestoneto reduce (calcine) calcite (CaCO 3 ) to “quick lime” (CaO).When powdered quick lime is mixed with water (a process

  8. Evaluation of High Solids Alkaline Pretreatment of Rice Straw

    E-Print Network [OSTI]

    Cheng, Yu-Shen; Zheng, Yi; Yu, Chao Wei; Dooley, Todd M.; Jenkins, Bryan M.; VanderGheynst, Jean S.

    2010-01-01

    19. Oates, J. A. H. (2007). Lime and Limestone 207–211. 20.1–28. 41. Kim, S. H. (2005). Lime pretreatment and enzymaticunwashed biomass. Keywords Lime . Calcium hydroxide . Sodium

  9. Where have all the flowers gone? Postbloom fruit drop of citrus in the Americas.

    E-Print Network [OSTI]

    Timmer, L. W.; Peres, N. A.

    2015-01-01

    of slow-growing orange and Key lime anthracnose strains offruit drop of citrus and Key lime anthracnose are caused bycausing wither-tip disease of limes in Zanzibar. Trans Brit

  10. Effect of furnace atmosphere on E-glass foaming

    E-Print Network [OSTI]

    Kim, D. S.; Dutton, Bryan C.; Hrma, Pavel R.; Pilon, Laurent

    2006-01-01

    on soda-silicate or soda-lime- silicate melts [2-5,9], or on6]. However, even for soda- lime glasses and metallurgicalon the foaming of soda-lime glass batch in air atmospheres

  11. Materials collected by the southern branch of the UC Africa Expedition with a report on previously unpublished Plio-Pleistocene fossil localities

    E-Print Network [OSTI]

    Monson, Tesla A; Brasil, Marianne F; Hlusko, Leslea J

    2015-01-01

    Fig. 1 V4738 Pit # Iscor Lime Boetsap Witkrans 2 WitkransGladysvale * Boetsap Iscor Lime Total Grey Bird Pit Witkransin an unroofed cave carved out in lime built out from the

  12. Fred Wagner: Blacksmithing and Life in the Santa Cruz Area, 1890-1930

    E-Print Network [OSTI]

    Wagner, Fred; Calciano, Elizabeth Spedding

    1966-01-01

    Yes, it was. Calciano: For the lime burning or? Wagner: Wellused to watch them make lime up here on the ranch? Wagner:to make the hoops for the lime barrels. Calciano: I see.

  13. Teaching Organic Farming and Gardening: Resources for Instructors, 3rd Edition. Part 1 - Skills and Practices

    E-Print Network [OSTI]

    2015-01-01

    of amendments such as compost and lime d) Allows soil to dryFertilizers such as gypsum/lime can improve soil structure;magnesium carbonate – dolomitic lime: added to acidic soils

  14. Three-Dimensional Flow and Thermal Structure in Glass Melting Furnaces. Part I: Effect of the Net Heat Flux Distribution

    E-Print Network [OSTI]

    Pilon, Laurent; Zhao, Guochang; Viskanta, Raymond

    2002-01-01

    the available data concerning soda-lime silicate glass.Soda-lime silicate glass is the most widespread andO-10 CaO (mol. %)] soda-lime silicate glass or very similar

  15. Malio J. Stagnaro: The Santa Cruz Genovese

    E-Print Network [OSTI]

    Regional History Project, UCSC Library; Stagnaro, Malio; Jarrell, Randall

    1975-01-01

    Cowell's up there with the lime, and I can remember theynever did for hauling the lime; then he kind of closed theseFelton there where they made lime up there. Then I presume

  16. CHEMISTRY OF SILICA IN CERRO PRIETO BRINES

    E-Print Network [OSTI]

    Weres, O.

    2012-01-01

    tank, add 20 to 30 ppm lime (CaO), stir for 5 ! Qinutes, andience. In practice, lime (calcium oxide or hydroxide) wouldadding a large amount of lime to them {up to 700 ppm CaO).

  17. Teaching Direct Marketing and Small Farm Viability, 2nd Edition. Unit 3 - Community Supported Agriculture (CSA)

    E-Print Network [OSTI]

    2015-01-01

    varieties of citrus (lemons, limes, oranges, tangerines, andremoved and sliced juice of 1 lime 2 T grapeseed oil saltpitted and diced juice of 1 lime salt and pepper Tortillas

  18. High Recovery Desalination of Brackish Water by Chemically-Enhanced Seeded Precipitation

    E-Print Network [OSTI]

    McCool, Brian Carey

    2012-01-01

    organic contaminants by lime softening. Water Research,of alkaline material (e.g. , lime) and gypsum powder intothe alkaline material (e.g. , lime) to form a slurry. 4. The

  19. Jim Rider: Bruce Rider & Sons

    E-Print Network [OSTI]

    Rabkin, Sarah

    2010-01-01

    mildew, which we can control with lime sulfur and micronizeddeveloped a resistance to lime sulfur, so it’s not totallyquestion that we could have lime-sulfur-resistant scab at

  20. CONTROL STRATEGIES FOR ABANDONED IN-SITU OIL SHALE RETORTS

    E-Print Network [OSTI]

    Persoff, P.

    2011-01-01

    No. 12, 260 (Feb. 1966). Soil~Lime Stabilization," Public H.and L. L. Harriss, "Free Lime ln Retorted Oil Shale," Eners;may be formed by placing lime in an abandoned retort and

  1. Thin Film Deposition of Conducting Polymers and Carbon Allotropes via Interfacial Solution Processing and Evaporative Vapor Phase Polymerization

    E-Print Network [OSTI]

    D'Arcy, Julio Marcelo

    2012-01-01

    temperature and soda lime glass possesses the greatestNumber of peels (55 o C) Soda lime glass Borosilicate glasswas investigated using soda lime glass (i.e. a microscope

  2. A MEASUREMENT OF ANISOTROPY IN THE COSMIC BACKGROUND RADIATION ON A LARGE ANGULAR SCALE AT 33 GHz

    E-Print Network [OSTI]

    Gorenstein, M.V.

    2011-01-01

    o l a l o i . and antenna* lime. I/,, iiV. \\ the -A *a. T Ithe radiation or the space-lime through which the radiationradiation must at the same lime allow inho- mogeneities on a

  3. Regional scale effects of base cation fertilization on Norway spruce and European beech stands situated on acid brown soils: soil and foliar chemistry

    E-Print Network [OSTI]

    Misson, Laurent

    2001-01-01

    M.R. , Nys C. , Effects of lime-induced differences in siteF. , Impact of dolomite lime on the ground vegetation and onof limestone and of limes- tone plus NPK fertilization on

  4. Xyloporosis: A history of the emergence and eradication of a citrus viroid disease

    E-Print Network [OSTI]

    Bar-Joseph, M.

    2015-01-01

    seeds of Palestine sweet lime. In: Proceedings of the 3rdEtrog citron and Rangpur lime by infection with the citrusonto Palestinian sweet lime rootstocks. The take-home

  5. Efficacy and Timing of Fungicides, Bactericides, and Biologicals for Decidous Tree Fruit, Nut, Strawberry, and Vine Crops

    E-Print Network [OSTI]

    Adaskaveg, Jim; Gubler, Doug; Michailides, Themis; Holtz, Brent

    2008-01-01

    Maneb Ph-D Rally 13 Ziram Copper 14 Lime sulfur 12 Sulfur 12Dormant treatment with liquid lime sulfur improves efficacychemistry. Use liquid lime sulfur in dormant applications

  6. Influence of Ancient Settlement in the Contemporary Maya Forest: Investigating Land Use at El Pilar

    E-Print Network [OSTI]

    Ford, Anabel; Larios, Rudy; Normark, Johan; Morales, Paulino; Ramos, Carmen

    2001-01-01

    Total Str. 53/22 Masons Laborers Lime Cement Total Str.19 Masons Laborers Lime Cement Total Faisan/Gumbo Masons Laborers Lime Cement Total Str. EP3 Masons

  7. Advancing Cellulosic Ethanol for Large Scale Sustainable Transportation

    E-Print Network [OSTI]

    Wyman, C

    2007-01-01

    Mike Ladisch, Purdue University • Lime pretreatment - MarkControlled pH AFEX ARP Lime *Cumulative soluble sugars asStage 2 Stage 1 Maximum possible Lime ARP AFEX Controlled pH

  8. Relation of Olfactory EEG to Behavior: Spatial Analysis

    E-Print Network [OSTI]

    Freeman, Walter J III; Baird, Bill

    1987-01-01

    rms) average of the ensemble lime average of the 64 timesin radians/s (radians = 2 limes frequency, in c/mm or c/s) (The procedure was repeated 40 limes for the data set of each

  9. Harold A. Hyde: Recollections of Santa Cruz County

    E-Print Network [OSTI]

    Hyde, Harold A.; Jarrell, Randall; Regional History Project, UCSC Library

    2002-01-01

    such as Salz Tannery, Cowell Lime and Cement, and the powderHealth Center 3 Cowell Lime and Cement Company 42 Cowell

  10. Three-Dimensional Flow and Thermal Structure in Glass Melting Furnaces. Part II: Effect of Batch and Bubbles

    E-Print Network [OSTI]

    Pilon, Laurent; Zhao, Guochang; Viskanta, Raymond

    2002-01-01

    properties of soda-lime solicate glass of composition 74 SiOwas retained for ?H melt for soda-lime silicate glass having

  11. The significance of crack-resistance curves to the mixed-mode fracture toughness of human cortical bone

    E-Print Network [OSTI]

    Zimmermann, Elizabeth A.

    2010-01-01

    36], alumina [16], and zirconia [16]. The G c toughnessand wood, alumina, and zirconia, and the mode II toughness,36], alumina [16], and zirconia [16]. The G c toughness

  12. Material and Energy Flows in the Materials Production, Assembly, and End-of-Life Stages of the Automotive Lithium-Ion Battery Life Cycle

    SciTech Connect (OSTI)

    Dunn, Jennifer B.; Gaines, Linda; Barnes, Matthew; Sullivan, John L.; Wang, Michael

    2014-01-01

    This document contains material and energy flows for lithium-ion batteries with an active cathode material of lithium manganese oxide (LiMn?O?). These data are incorporated into Argonne National Laboratory’s Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, replacing previous data for lithium-ion batteries that are based on a nickel/cobalt/manganese (Ni/Co/Mn) cathode chemistry. To identify and determine the mass of lithium-ion battery components, we modeled batteries with LiMn?O? as the cathode material using Argonne’s Battery Performance and Cost (BatPaC) model for hybrid electric vehicles, plug-in hybrid electric vehicles, and electric vehicles. As input for GREET, we developed new or updated data for the cathode material and the following materials that are included in its supply chain: soda ash, lime, petroleum-derived ethanol, lithium brine, and lithium carbonate. Also as input to GREET, we calculated new emission factors for equipment (kilns, dryers, and calciners) that were not previously included in the model and developed new material and energy flows for the battery electrolyte, binder, and binder solvent. Finally, we revised the data included in GREET for graphite (the anode active material), battery electronics, and battery assembly. For the first time, we incorporated energy and material flows for battery recycling into GREET, considering four battery recycling processes: pyrometallurgical, hydrometallurgical, intermediate physical, and direct physical. Opportunities for future research include considering alternative battery chemistries and battery packaging. As battery assembly and recycling technologies develop, staying up to date with them will be critical to understanding the energy, materials, and emissions burdens associated with batteries.

  13. Material and energy flows in the materials production, assembly, and end-of-life stages of the automotive lithium-ion battery life cycle

    SciTech Connect (OSTI)

    Dunn, J.B.; Gaines, L.; Barnes, M.; Wang, M.; Sullivan, J.

    2012-06-21

    This document contains material and energy flows for lithium-ion batteries with an active cathode material of lithium manganese oxide (LiMn{sub 2}O{sub 4}). These data are incorporated into Argonne National Laboratory's Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, replacing previous data for lithium-ion batteries that are based on a nickel/cobalt/manganese (Ni/Co/Mn) cathode chemistry. To identify and determine the mass of lithium-ion battery components, we modeled batteries with LiMn{sub 2}O{sub 4} as the cathode material using Argonne's Battery Performance and Cost (BatPaC) model for hybrid electric vehicles, plug-in hybrid electric vehicles, and electric vehicles. As input for GREET, we developed new or updated data for the cathode material and the following materials that are included in its supply chain: soda ash, lime, petroleum-derived ethanol, lithium brine, and lithium carbonate. Also as input to GREET, we calculated new emission factors for equipment (kilns, dryers, and calciners) that were not previously included in the model and developed new material and energy flows for the battery electrolyte, binder, and binder solvent. Finally, we revised the data included in GREET for graphite (the anode active material), battery electronics, and battery assembly. For the first time, we incorporated energy and material flows for battery recycling into GREET, considering four battery recycling processes: pyrometallurgical, hydrometallurgical, intermediate physical, and direct physical. Opportunities for future research include considering alternative battery chemistries and battery packaging. As battery assembly and recycling technologies develop, staying up to date with them will be critical to understanding the energy, materials, and emissions burdens associated with batteries.

  14. Integrated methods for production of clean char and its combustion properties

    SciTech Connect (OSTI)

    DeBarr, J.A.

    1991-01-01

    The overall objective of this two-year program is to produce clean char using an integrated process scheme which combines physical coal cleaning, mild gasification and char oxydesulfurization. Low sulfur chars which could be used in utility boilers to meet 1995 emission standards of 2.5 lbs DO{sub 2}/MMBtu are produced from Illinois coals having emissions of >5 lbs SO{sub 2}/MMBtu. Mild gasification and low temperature oxidation studies for sulfur removal are conducted with selected coals from the Illinois Basin Coal (IBC) Sample Program in a batch fixed-bed reactor at the ISGS. Pound quantities of chars for combustion testing are prepared in a continuous rotary kiln reactor under optimized conditions of mild gasification and oxydesulfurization. Burning characteristics and ash deposition behaviors of desulfurized chars are determined to ensure that a useable fuel is produced. These tests are done at the University of North Dakota Energy and Environmental Research Center (UNDEERC) in a drop tube furnace (DTF), and at the US EPA in a 14 kW pilot-scale combustor. In some tests, methane is examined as an auxiliary fuel, and high-surface-area hydrated lime developed at ISGS is used to further reduce SO{sub 2} emissions. Complete analyses of the fuels are obtained to aid char desulfurization studies and help explain combustion and SO{sub 2} emission characteristics of the char. This project is a cooperative effort between the ISGS, UNDEERC and the US EPA and is cost-shared with US EPA and the US DOE through UNDEERC.

  15. Integrated methods for production of clean char and its combustion properties. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    DeBarr, J.A.

    1991-12-31

    The overall objective of this two-year program is to produce clean char using an integrated process scheme which combines physical coal cleaning, mild gasification and char oxydesulfurization. Low sulfur chars which could be used in utility boilers to meet 1995 emission standards of 2.5 lbs DO{sub 2}/MMBtu are produced from Illinois coals having emissions of >5 lbs SO{sub 2}/MMBtu. Mild gasification and low temperature oxidation studies for sulfur removal are conducted with selected coals from the Illinois Basin Coal (IBC) Sample Program in a batch fixed-bed reactor at the ISGS. Pound quantities of chars for combustion testing are prepared in a continuous rotary kiln reactor under optimized conditions of mild gasification and oxydesulfurization. Burning characteristics and ash deposition behaviors of desulfurized chars are determined to ensure that a useable fuel is produced. These tests are done at the University of North Dakota Energy and Environmental Research Center (UNDEERC) in a drop tube furnace (DTF), and at the US EPA in a 14 kW pilot-scale combustor. In some tests, methane is examined as an auxiliary fuel, and high-surface-area hydrated lime developed at ISGS is used to further reduce SO{sub 2} emissions. Complete analyses of the fuels are obtained to aid char desulfurization studies and help explain combustion and SO{sub 2} emission characteristics of the char. This project is a cooperative effort between the ISGS, UNDEERC and the US EPA and is cost-shared with US EPA and the US DOE through UNDEERC.

  16. WarWar && PeacePeace && WarWar: The Life: The Life Cycles of Imperial NationsCycles of Imperial Nations

    E-Print Network [OSTI]

    White, Douglas R.

    as limites (singular limes), a path between fields. · Rome wanted German land for protection. · Different

  17. The Quadrangle Club The Quadrangle Club 1155 E. 57th Street Chicago, IL 60637 773.702.7221

    E-Print Network [OSTI]

    with Cilantro-Lime Mayo Vegetable Wonton, Hoisin Sauce, Green Onion Crisp Ravioli with Tomato Caponata

  18. Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite

    E-Print Network [OSTI]

    Rochelle, Gary T.

    oxidation in limestone slurry scrubbing. Introduction Limestone (CaCO3) slurry scrubbing and lime (Ca

  19. On Concept and [This paper was first published in 1892 in the Vierteljahrsschrift fur

    E-Print Network [OSTI]

    Fitelson, Branden

    referred to my Grundlagen ihr Arithmetik and other works of mine, sometimes agreeing and some- limes

  20. Draft (8 April 2007) submitted for Copenhagen Consensus 2008. Comments welcome Land Degradation

    E-Print Network [OSTI]

    Coxhead, Ian

    or fertilizer; reduce acidity by adding lime; and optimize water availability through drainage or irrigation

  1. ONA REPORTS published in

    E-Print Network [OSTI]

    Ma, Lena

    limed sludge. Other contaminants that may be regulated soon include dioxin-like compounds, brominated

  2. SAND2010-5901

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    onto fluorinated alumina surface. ..... 50 10 Tables Table 1- BET surface area, pore volume, and pore size of synthesized nanoporous alumina ...... 21 Table 2- Sorption...

  3. Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Cement Industry in China

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    Economic Output in Chinese Cement Kilns,” Proceedings of thereduction of China’s cement industry. Energy Policy 45 (751. Kong, Xiangzhong (China Cement Association, CCA), 2009.

  4. Life-Cycle Evaluation of Concrete Building Construction as a Strategy for Sustainable Cities

    E-Print Network [OSTI]

    Stadel, Alexander

    2013-01-01

    of scrap tires, solvents, and waste oils show considerablySolid waste: other Water emissions: oils, phenols, COD, N, Pdiesel) oil preheater kiln Natural gas Petcoke Wastes

  5. Advanced Organic Vapor Cycles for Improving Thermal Conversion Efficiency in Renewable Energy Systems

    E-Print Network [OSTI]

    Ho, Tony

    2012-01-01

    d Nark Mirolli. “The Kalina Cycle for Cement Kiln Waste Heatthermodynamic analysis on Kalina cycle," Frontiers of EnergyAn Introduction to the Kalina Cycle," Proceedings of the

  6. Industry

    E-Print Network [OSTI]

    Bernstein, Lenny

    2008-01-01

    A.T, 2001: Prospects for biogas harvesting at Sungunn WongseRenewables Biomass, Biogas, PV, Wind turbines, Hydropowermill, fluidized bed kiln Biogas, Biomass Cullet preheating

  7. Largest Producer of Steel Products in the United States Achieves...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    large capital costs and demonstrated the value of similar measures. * By upgrading burners in a kiln serving an important process line, the Minntac plant achieved significant...

  8. Largest Producer of Steel Products in the United States Achieves...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    opportunities. The assessment confirmed the energy savings from recently installed burners and determined the potential savings from retrofitting the kilns in the plant's other...

  9. International Best Practices for Pre-Processing and Co-Processing Municipal Solid Waste and Sewage Sludge in the Cement Industry

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2013-01-01

    burners ..before adding it to the main burner of a cement kiln. Thiscoarse fuels in the main burner is very high and the

  10. Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01

    Birch, E. , 1990. “Energy Savings in Cement Kiln Systems”Engineering and Energy Savings” Energy Efficiency in theGomes, A. S. , 1990. “Energy Saving and Environmental Impact

  11. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01

    Banerjee, R. , 2005. Energy Efficiency and Demand SideKiln Systems,” Energy Efficiency in the Cement Industry (Ed.for Improving Energy Efficiency, Reducing Pollution and

  12. Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China

    E-Print Network [OSTI]

    Price, Lynn

    2010-01-01

    Banerjee, R. , 2005. Energy Efficiency and Demand SideKiln Systems,” Energy Efficiency in the Cement Industry (Ed.of Industrial Energy Efficiency Measures,” Proceedings of

  13. Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry

    E-Print Network [OSTI]

    Galitsky, Christina

    2009-01-01

    pre- crushing needed) and coal types with a higher humidityfor more abrasive coal types. • Electricity consumption forby kiln type; the amount of raw materials, coal and clinker

  14. bia-cemkiln | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1990) Comprehensive Report to Congress Comprehensive Report to Congress on the Clean Coal Technology Program: Cement Kiln Flue Gas Recovery Scrubber PDF-1.5MB (Nov 1989)...

  15. Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry

    E-Print Network [OSTI]

    Galitsky, Christina

    2009-01-01

    waste heat recovery on dioxin emissions from cement kilns (low-temperature, catalytic dioxin formation reactions. Heattime for the flue gas at the dioxin formation temperature

  16. Life-Cycle Environmental and Economic Assessment of Using Recycled Materials for Asphalt Pavements

    E-Print Network [OSTI]

    Horvath, Arpad

    2003-01-01

    1993] MOEE. Spent Foundry Sand - Alternative Uses Study.Flue Gas Scrubber Material Foundry Sands Kiln Dusts Mineralin highway construction is foundry sand. Silica sand coated

  17. EA-1769: Draft Environmental Assessment | Department of Energy

    Office of Environmental Management (EM)

    proposed project involves installation of a specifically designed waste heat recovery boiler on the existing kiln afterburner of an incineration unit at the CHDP facility. This...

  18. National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China

    E-Print Network [OSTI]

    Zhou, Nan

    2013-01-01

    Jinan 7.5MW Waste Heat Recovery and Power Generation Projectfor kiln fan Optimize heat recovery/upgrade clinker coolertemperature waste heat recovery power generation Efficient

  19. Advanced Organic Vapor Cycles for Improving Thermal Conversion Efficiency in Renewable Energy Systems

    E-Print Network [OSTI]

    Ho, Tony

    2012-01-01

    for Industrial Waste Heat Recovery. c Daniel Duffy. “Betterfor Cement Kiln Waste Heat Recovery Power Plants. ” Cementoptimization of heat recovery steam generators operating

  20. Atmos. Chem. Phys., 15, 43174337, 2015 www.atmos-chem-phys.net/15/4317/2015/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    ) precalciner kilns with fabric filters (FF) in cement production; (3) mechanized coking ovens gas desulfuriza- tion (FGD) and selective catalyst reduction (SCR) systems in power generation; (2

  1. Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers

    E-Print Network [OSTI]

    Worrell, Ernst

    2008-01-01

    11 Cogeneration systems can either be direct gas turbinesCogeneration. Waste gas discharged from the kiln exit gases, the clinker cooler system,

  2. Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Cement Sector

    E-Print Network [OSTI]

    Sathaye, J.

    2011-01-01

    2 Cogeneration systems can either be direct gas turbinesCogeneration. Waste gas discharged from the kiln exit gases, the clinker cooler system,

  3. Energy efficiency and carbon dioxide emissions reduction opportunities in the U.S. cement industry

    E-Print Network [OSTI]

    Martin, Nathan; Worrell, Ernst; Price, Lynn

    1999-01-01

    into power. Cogeneration systems can either be direct gasCogeneration. Waste gas discharged from the kiln exit gases, the clinker cooler system,

  4. Advanced Organic Vapor Cycles for Improving Thermal Conversion Efficiency in Renewable Energy Systems

    E-Print Network [OSTI]

    Ho, Tony

    2012-01-01

    for Industrial Waste Heat Recovery. c Daniel Duffy. “Betterfor Cement Kiln Waste Heat Recovery Power Plants. ” CementRankine cycle for waste heat recovery," Energy, vol. 29, pp.

  5. Fixed bed trapping for gaseous fluoride effluent control

    SciTech Connect (OSTI)

    Otey, M.G.; Bayne, C.K.

    1980-06-14

    To comply with future air quality standards for gaseous fluoride emissions at the PGDP, studies are being made to evaluate the most feasible and efficient method of trapping fluorides from the effluents of the different processes. Although this work is in direct support of environmental projects, its results are applicable in other areas. Throughout the diffusion plants there are several areas where fluorides, either single or multiple species, are controlled and/or processed. The solid sorbent studies represent new, promising technology which could have significant impact on the gaseous diffusion plants. Scoping studies of solid sorbents and reaction conditions have been conducted. In a series of statistically designed experiments, the effects of total gas flow, temperature, and fluoride gas flow were studied for eight dry chemicals in a 1-in. diameter fixed bed designed to remove three separate fluoride gas species (hydrogen fluoride (HF), fluorine (F/sub 2/), and chlorine trifluoride (ClF/sub 3/)) from an air stream. The trapping materials selected for the test include two brands of four different material types: soda lime, oolitic calcium carbonate (CaCO/sub 3/), calcium oxide (CaO), and activated alumina (Al/sub 2/O/sub 3/). Additionally, loading factors and material utilization were determined to allow an economic comparison to be made between bed materials.

  6. Alumina nanoparticle/polymer nanocomposite dielectric for flexible amorphous indium-gallium-zinc oxide thin film transistors on plastic substrate with superior stability

    SciTech Connect (OSTI)

    Lai, Hsin-Cheng [Department of Electrical Engineering, National Chung Hsing University, Taichung 40227, Taiwan (China); Pei, Zingway, E-mail: zingway@dragon.nchu.edu.tw [Department of Electrical Engineering, National Chung Hsing University, Taichung 40227, Taiwan (China); Graduate Institute of Optoelectronic Engineering, National Chung Hsing University, Taichung 40227, Taiwan (China); Center of Nanoscience and Nanotechnology, National Chung Hsing University, Taichung 40227, Taiwan (China); Jian, Jyun-Ruri; Tzeng, Bo-Jie [Graduate Institute of Optoelectronic Engineering, National Chung Hsing University, Taichung 40227, Taiwan (China)

    2014-07-21

    In this study, the Al{sub 2}O{sub 3} nanoparticles were incorporated into polymer as a nono-composite dielectric for used in a flexible amorphous Indium-Gallium-Zinc Oxide (a-IGZO) thin-film transistor (TFT) on a polyethylene naphthalate substrate by solution process. The process temperature was well below 100?°C. The a-IGZO TFT exhibit a mobility of 5.13?cm{sup 2}/V s on the flexible substrate. After bending at a radius of 4?mm (strain?=?1.56%) for more than 100 times, the performance of this a-IGZO TFT was nearly unchanged. In addition, the electrical characteristics are less altered after positive gate bias stress at 10?V for 1500?s. Thus, this technology is suitable for use in flexible displays.

  7. Investigation of porous alumina as a self-assembled diffractive element to facilitate light trapping in thin film silicon solar cells

    E-Print Network [OSTI]

    Coronel, Naomi (Naomi Cristina)

    2009-01-01

    Thin film solar cells are currently being investigated as an affordable alternative energy source because of the reduced material cost. However, these devices suffer from low efficiencies, compared to silicon wafer solar ...

  8. Martha L. Mecartney, Ph.D. Outreach and Highlights of Research for

    E-Print Network [OSTI]

    Mease, Kenneth D.

    different compositions - alumina/zirconia/mullite (aluminosilicate) and alumina/zirconia/nickel spinel to as superplasticity. By dispersing a nanometer scale second phase in yttria stabilized cubic zirconia, this ceramic Deformation of Alumina-based Composites (Alumina-Zirconia-Mullite) 0 20 40 60 80 100 1E-5 1E-4 1E-3 0.01 1425

  9. Science Arts & Mtiers (SAM) is an open access repository that collects the work of Arts et Mtiers ParisTech

    E-Print Network [OSTI]

    Boyer, Edmond

    .03.024 #12;Model and simulation of a solar kiln with energy storage D. Luna a , J.-P. Nadeau a,*, Y. Jannot b storage Modeling Quality a b s t r a c t A solar kiln with energy storage can be used for continuous. Introduction Solar systems are currently evolving towards integrating energy storage [1], so as to resolve

  10. POSTSORTING OF HEM-FIR: A MILL STUDY MICHAEL R. MILOTA

    E-Print Network [OSTI]

    in a separate kiln, The results indicate that 14 percent less total kiln time is required at a given production (presort- ing) have been only marginally success- ful, particularly with automated equipment. Presorting density. Sorting after drying (postsorting) (Fig. 1) with an in-line electric moisture meter has been

  11. Charcoal production in the Argentine Dry Chaco: Where, how and who? Carla V. Rueda a,b,

    E-Print Network [OSTI]

    Nacional de San Luis, Universidad

    Bioenergy Forest development Charcoal production has been widespread in the past and is still common where); together with existing environmental (forest cover/biomass), social (population density, poverty), and infrastructure (roads) data. While most of the region has low kiln densities (b1 kiln every 1000 km2 ), foci

  12. Light weight concrete: 226 K contents and dose

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    Yu, Peter K.N.

    ) commonly used in Hong Kong, namely, autoclave aerated concrete (plus lime), autoclave aerated concrete.N. Yu). #12;in Hong Kong, namely, autoclave aerated concrete (plus lime), autoclave aerated concrete

  13. Our Ocean Backyard Santa Cruz Sentinel columns by Gary Griggs, Director, Institute of Marine Sciences, UC Santa Cruz.

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    Street was the primary access to the chute so that all of the lumber, lime and other cargo didn't have, where lime was stored prior to shipping. Cowell's Beach probably originally received its name from

  14. Your name Your TA's name MA 16500 EXAM I INSTRUCTIONS ...

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    Sep 23, 2014 ... limxng m - sin (i) = [liming re] - [lime—m Si“ (in. Since limxngx : 0, the limit we want to compute is also equal to 0. . limmng a: - sin (i) = [limmqo rt] ...

  15. CE NTE R FOR AG ROECOLOGY & SUSTAI NAB LE FOOD SYSTE M S Raising a Barn, Building Community

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    California at Santa Cruz, University of

    buildings in the Cowell Lime Works Historic District, and will be the future headquarters for the Center of the Cowell Lime Works enterprise in the late 1800s was the Cowell Ranch, home now to the UC Santa Cruz campus

  16. Water softening using microbial desalination cell technology Kristen S. Brastad a,b

    E-Print Network [OSTI]

    softening process in the U.S. is based on ion ex- change, which requires charged polymer resin beads known as lime softening, adds lime to hard water to precipitate calcium ions as calcium carbonate

  17. Conversion of Waste Biomass into Useful Products 

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    Holtzapple, M.

    1998-01-01

    Waste biomass includes municipal solid waste (MSW), municipal sewage sludge (SS), industrial biosludge, manure, and agricultural residues. When treated with lime, biomass is highly digestible by a mixed culture of acid-forming microorganisms. Lime...

  18. An integrated approach to predict ettringite formation in sulfate soils and identifying sulfate damage along SH 130 

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    Sachin, Kunagalli Natarajan

    2005-02-17

    Expansive soils are treated with anhydrous or hydrated lime. The use of calcium-based stabilizers such as calcium oxide (lime) in sulfate-bearing clay soils has historically led to distress due to the formation of an ...

  19. Alternate stabilizers: solution towards reducing sulfate swell in expansive clay subgrades in Dallas district 

    E-Print Network [OSTI]

    Rajendran, Deepa

    1997-01-01

    The practice of using lime as a stabilizer during construction of pavements is widespread and is considered economical. However under certain conditions, the beneficial effects of lime stabilization is overridden. Proximity ...

  20. Patrick Maher Curriculum Vitae

    E-Print Network [OSTI]

    Maher, Patrick

    ­216. · Probabilities for Two Properties. Erkenntnis 52 (2000), 63­91. · The Confirmation of Black's Theory of Lime

  1. Publications 1997-1999 Department of Soil Sciences

    E-Print Network [OSTI]

    Research 12, 321-327. Andersson, S., Nilsson, S. I. & Valeur, I. 1999. Influence of dolomitic lime on DOC

  2. pubs.acs.org/JAFCPublished on Web 06/15/2009 2009 American Chemical Society J. Agric. Food Chem. 2009, 57, 56735679 5673

    E-Print Network [OSTI]

    Hammock, Bruce D.

    are tradedinternationally. Lemon,lime, and orange oilsrepresent the largest segment of U.S. essential oil imports in both

  3. Fluid&ParticulateSystems 424514/2010

    E-Print Network [OSTI]

    Zevenhoven, Ron

    of hydrocarbon and coke - burning solid fuels (with SO2-capturing lime stone) - polymerisation januari 2014 Ro

  4. Alphabetical List of Classes with Course Codes Access Advanced ( CPT049)

    E-Print Network [OSTI]

    Vermont, University of

    in Student Employment (STU011) LGBTQA* Vocabulary and Identity 101 (DEI002) Lime Survey Basics ( CPT027

  5. Ideo Population: how much do numbers count?____~ _il_l_a_ss_i,_n(_)!~ivi Bacc,: Fra~Jle number th~()reJJ'--___________ :10

    E-Print Network [OSTI]

    Cohen, Joel E.

    population, even though those of liS \\vho lived through it did not recognize it at the lime. Seeond

  6. PHYSICS BEFORE AND AFTER EINSTEIN This page intentionally left blank

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    Mamone Capria, Marco

    /Lavis Marketing 73 Lime Walk Headington Oxford OX3 7AD England fax: +44 1865 750079 Distributor in the USA

  7. PUBLIKATIONER PRODUCERADE vid gamla institutionen fr Radioekologi 1958-1968

    E-Print Network [OSTI]

    of Lime and Phosphate Fertilizer on the Accumulation of 89 Sr in Red Clover Grown in 29 Different Swedish

  8. Our Ocean Backyard Santa Cruz Sentinel columns by Gary Griggs, Director, Institute of Marine Sciences, UC Santa Cruz.

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    , an eastern cement entrepreneur, to develop the Santa Cruz Lime Company along the Coast Road at San Vicente

  9. Environ. Scl. Technol. 1994, 28, 277-283 Effects of Salts on Preparation and Use of Calcium Silicates for Flue Gas

    E-Print Network [OSTI]

    Rochelle, Gary T.

    areacalciumsilicatehydratesthat arehighly reactive with SO2 can be made by slurrying fly ash and lime in water at elevated

  10. ~Soup of the Day~ Broadway Basil & Tomato Bisque

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    Arnold, Jonathan

    simmered with cilantro, smoky chipotles, finished with a twist of lime. Cup: $2.75 Bowl: $3.75 ~Sandwich

  11. The Quadrangle Club The Quadrangle Club 1155 E. 57th Street Chicago, IL 60637 773.702.7221

    E-Print Network [OSTI]

    with Cilantro-Lime Mayo Vegetable Wonton, Hoisin Sauce, Green Onion Crisp Ravioli with Tomato Caponata Menu Hors

  12. PROOF COPY [2006-0114] 050606GPY Gassmann fluid substitution and shear modulus variability in carbonates

    E-Print Network [OSTI]

    .8 MHz to estimate the validity of Gassmann's equations for lime- stones and dolomites Wang et al., 1991

  13. Peach Leaf CurlPeach Leaf Curl Peach leaf curl is a fungal disease that

    E-Print Network [OSTI]

    Ishida, Yuko

    to increase effectiveness. Bordeaux mixture is a home-made copper sulfate and lime mixture that must

  14. CCured Type-Safe Retrofitting of Legacy Code George C. Necula Scott McPeak Westley Weimer

    E-Print Network [OSTI]

    Weimer, Westley

    I>. The remaining poiniers are insiru- menied wiih efficieni run-lime checks lo ensure lhai lhey are used sai

  15. 2015 Testing Form Home Grounds & Garden Instructions

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    New Hampshire, University of

    recently applied (within the past year) lime or wood ash, please specify the date and rate applied to each

  16. 2015 Soil Testing Form -Commercial Plant Tissue Test Instructions

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    New Hampshire, University of

    TOTAL COST: If you have recently applied fertilizer, lime or wood ash, please specify the type, date

  17. Effect of Zinc (Zn (II)) on the Adsorption Mechanisms of Arsenate (As (V)) at the

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    Sparks, Donald L.

    -Water Interface. (S02-grafe092408- Oral) Abstract: In acid mine drainage and in lime amended metal contaminated

  18. Report on the scientific results of the voyage of H.M.S. Challenger during the years 1873-76. Physics and chemistry - Vol. 1

    E-Print Network [OSTI]

    Thomson, C Wyville; Murray, John

    1911-01-01

    as oxalate, reduced to lime, ami weighed i u this purifiedh e water o f magnesia a n d lime salts. T h e f o l l o w ii n c h l o r i n e , lime, a n d magnesia, to I t.e. o f

  19. Bubble Transport in Three-Dimensional Gravity Driven Flow, Part II. Numerical Results

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    Pilon, Laurent; Viskanta, Raymond

    2004-01-01

    The re?ning of a soda-lime-silica glass with antimony”,di?usion of oxygen in soda-lime silicate glass”, Glastech-O-10 CaO (mol. %)] of soda-lime silicate glass or simi- lar

  20. New Measurements of Magnetic Field Decay in 1 Meter SSC-Type Dipoles

    E-Print Network [OSTI]

    Gilber, W.S.

    2011-01-01

    0-1__ - 1- ' - ' -- S INH liME II AtJG 1989 12:39:13 o w L0 -'- ' - ' - 1" El APSE! ) liME (MIN) Figure 6. 1)ccay BathURE SENSOR C9568 SlAR T liME 31 SEPT 9013:56 : 12 4 .350 .