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Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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1

Wood Residues as Fuel Source for Lime Kilns  

E-Print Network [OSTI]

completed and the preliminary results indicate that our approach is potentially a very cost-effective and simple option to substantially reduce or possibly eliminate fossil-fuel usage in lime kilns....

Azarniouch, M. K.; Philp, R. J.

1984-01-01T23:59:59.000Z

2

Design of Refractory Linings for Balanced Energy Efficiency, Uptime, and Capacity in Lime Kilns  

SciTech Connect (OSTI)

The rotary kilns used by the pulp and paper industry to regenerate lime in the Kraft process are very energy intensive. Throughout the 90 s, in response to increasing fuel prices, the industry used back up insulation in conjunction with the high alumina brick used to line the burning zones of their kilns. While this improved energy efficiency, the practice of installing insulating brick behind the working lining increased the inner wall temperatures. In the worst case, due to the increased temperatures, rapid brick failures occurred causing unscheduled outages and expensive repairs. Despite these issues, for the most part, the industry continued to use insulating refractory linings in that the energy savings were large enough to offset any increase in the cost of maintaining the refractory lining. Due to the dramatic decline in the price of natural gas in some areas combined with mounting pressures to increasing production of existing assets, over the last decade, many mills are focusing more on increasing the uptime of their kilns as opposed to energy savings. To this end, a growing number of mills are using basic (magnesia based) brick instead of high alumina brick to line the burning zone of the kiln since the lime mud does not react with these bricks at the operating temperatures of the burning zone of the kiln. In the extreme case, a few mills have chosen to install basic brick in the front end of the kiln running a length equivalent to 10 diameters. While the use of basic brick can increase the uptime of the kiln and reduce the cost to maintain the refractory lining, it does dramatically increase the heat losses resulting from the increased operating temperatures of the shell. Also, over long periods of time operating at these high temperatures, damage can occur in the shell. There are tradeoffs between energy efficiency, capacity and uptime. When fuel prices are very high, it makes sense to insulate the lining. When fuel prices are lower, trading some thermal efficiency for increased uptime and capacity seems reasonable. This paper considers a number of refractory linings in an effort to develop optimized operating strategies that balance these factors. In addition to considering a range of refractory materials, the paper examines other factors such as the chain area, discharge dams and other operating variables that impact the service life of the refractory lining. The paper provides recommendations that will help mill personnel develop a strategy to select a refractory lining that is optimized for their specific situation.

Gorog, John Peter [ORNL; Hemrick, James Gordon [ORNL; Walker, Harold [Refratechnik North America, Inc.; Leary, William R [ORNL; Ellis, Murray [Australian Paper, Co.

2014-01-01T23:59:59.000Z

3

Hazardous-waste combustion in industrial processes: cement and lime kilns  

SciTech Connect (OSTI)

This report summarizes the results of several studies relating to hazardous-waste combustion in cement and lime kilns. The tests included in the study are four kilns tested by the U.S. Environmental Protection Agency, four kilns tested by State agencies or the kiln operator, two Canadian tests, and one Swedish test. The predominant types of wastes tested included chlorinated organic compounds, aromatic compounds, and metal-contaminated waste oil. The kiln types include lime kilns and cement kilns, which included the dry, wet, and preheated processes. Fabric filters and electrostatic precipitators (ESPs) were the pollution-control devices used in these processes, and the primary fuels included coal, coke, coal/coke, fuel oil, and natural gas/coke. The parameters examined in the report were Destruction and Removal Efficiency (DRE) of the Principal Organic Hazardous Constitutents, particulate and HCl emissions, metals, and the effect of burning hazardous waste on SO/sub 2/, NOx, and CO emissions. The primary conclusion of the study is that DRE's of 99.99% or greater can be obtained in properly-operated calcining kilns. Particulate matter can increase when chlorinated wastes are burned in a kiln equipped with an electrostatic precipitator. Those kilns equipped with fabric filters showed no change in emissions.

Mournighan, R.E.; Branscome, M.

1987-11-01T23:59:59.000Z

4

Control of Lime Kiln Heat Balance is Key to Reduced Fuel Consumption  

E-Print Network [OSTI]

This article discusses the various heat loads in a pulp mill lime sludge kiln, pointing out which heat loads cannot be reduced and which heat loads can, and how a reduction in energy use can be achieved. In almost any existing rotary lime sludge...

Kramm, D. J.

1982-01-01T23:59:59.000Z

5

A cement kiln flue-dust evaluated as a soil liming material  

E-Print Network [OSTI]

A CEMENT KILN FLUE-DUST EVALUATED AS A SOIl LIMING MATERIAL A Thesis by RAIMUND STACHA Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE 1973 NJSbj t...:~StlCh tt A CEMENT KILN FLUE-DUST EVALUATED AS A SOIL I IMING MATERIAL A Thesis by RAIMUND STACHA Approved as to style and content by: (Chairman of Committee) (Head of Department) (Me er) (Member) (Member) (Member) (Member) 1973 ABSTRACT A...

Stacha, Raimund

1973-01-01T23:59:59.000Z

6

Lime kiln source characterization: Lime manufacturing industry Fourier transform infrared spectroscopy. Final report  

SciTech Connect (OSTI)

The purpose of this testing program is to obtain uncontrolled and controlled hydrogen chloride (HCl) and speciated hydrocarbon Hazardous Air Pollutants (HAPs) emissions data from lime production plants to support a national emission standard for hazardous air pollutants (NESHAP). This report presents data from the Fourier Transform Infrared Spectroscopy (FTIR) measurements. FTIR source testing was conducted for the following purposes: Quantify HCl emission levels; and Gather screening (i.e., qualitative) data on other HAP emissions.

Toney, M.L.

1999-07-01T23:59:59.000Z

7

Use of RDF as a kiln fuel. Final report  

SciTech Connect (OSTI)

Refuse derived fuel (RDF) has been experimented with and/or proposed for use in kilns for the production of portland cement, lime, and expanded shale (a form of lightweight aggregate). Technological issues affecting the use of RDF in kilns are reviewed as are the results of trials in which RDF has been used as a kiln fuel. Three future research/demonstration projects for addressing the major unresolved issues are discussed. These projects are: a lime plant trial; a trial in a pre-calcining furnace; and an extended trial in a cement kiln.

None

1980-10-01T23:59:59.000Z

8

Solar heated rotary kiln  

DOE Patents [OSTI]

A solar heated rotary kiln utilized for decomposition of materials, such as zinc sulfate. The rotary kiln has an open end and is enclosed in a sealed container having a window positioned for directing solar energy into the open end of the kiln. The material to be decomposed is directed through the container into the kiln by a feed tube. The container is also provided with an outlet for exhaust gases and an outlet for spent solids, and rests on a tiltable base. The window may be cooled and kept clear of debris by coolant gases.

Shell, Pamela K. (Tracy, CA)

1984-01-01T23:59:59.000Z

9

Solar-heated rotary kiln  

DOE Patents [OSTI]

A solar heated rotary kiln utilized for decomposition of materials, such as zinc sulfate is disclosed. The rotary kiln has an open end and is enclosed in a sealed container having a window positioned for directing solar energy into the open end of the kiln. The material to be decomposed is directed through the container into the kiln by a feed tube. The container is also provided with an outlet for exhaust gases and an outlet for spent solids, and rests on a tiltable base. The window may be cooled and kept clear of debris by coolant gases.

Shell, P.K.

1982-04-14T23:59:59.000Z

10

Rotary kiln seal  

DOE Patents [OSTI]

A rotary seal used to prevent the escape of contaminates from a rotating kiln incinerator. The rotating seal combines a rotating disc plate which is attached to the rotating kiln shell and four sets of non-rotating carbon seal bars housed in a primary and secondary housing and which rub on the sides of the disc. A seal air system is used to create a positive pressure in a chamber between the primary and secondary seals to create a positive air flow into the contaminated gas chamber. The seal air system also employs an air inlet located between the secondary and tertiary seals to further insure that no contaminates pass the seal and enter the external environment and to provide makeup air for the air which flows into the contaminated gas chamber. The pressure exerted by the seal bars on the rotating disc is controlled by means of a preload spring. The seal is capable of operating in a thermally changing environment where the both radial expansion and axial movement of the rotating kiln do not result in the failure of the seal.

Drexler, Robert L. (Idaho Falls, ID)

1992-01-01T23:59:59.000Z

11

Process for the recovery of alumina from fly ash  

DOE Patents [OSTI]

An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

Murtha, M.J.

1983-08-09T23:59:59.000Z

12

Drying and first heat up of a kiln unit with cyclone heat exchangers with a lining of refractory concretes  

SciTech Connect (OSTI)

This paper describes an accelerated drying and first heatup cycle developed for a kiln unit for dry production of clinker with a capacity of 3000 tons/day with cyclone heat exchangers of refractory concretes of high-alumina cement with a chamotte aggregate. The drying of the lining and the heating of the unit were done in 4 days. The results of the work indicate the desirability of use of refractory concretes for lining the cyclone heat exchangers of kiln units for dry production of clinker.

Petrov-Denisov, V.G.; Matveev, Y.V.; Pichkov, A.M.; Pozdnyakova, N.K.; Shakhov, I.I.

1985-11-01T23:59:59.000Z

13

Acceptable approaches for beneficial use of cement kiln dust  

SciTech Connect (OSTI)

One beneficial use of cement kiln dust (CKD) is application of CKD to cropland as agricultural lime or fertilizer. However, the EPA has expressed a concern over land application of CKD when the metals constituents in the CKD are above the industry-wide median levels presented in EPA`s Report to Congress on Cement Kiln Dust. Under the Clean Water Act, EPA has established limits for metals concentrations in sewage sludge that is applied to the land for beneficial use of the nitrogen in the sludge. The limits for land application of sewage sludge were established based on the results of exposure risk assessments. A comparison of the median industry-wide metals concentrations in CKD to the metals concentration limits for land application of sewage sludge indicates that all trace metal concentrations IN CKD are below the corresponding sewage sludge land application limit, with the exception of the median level of arsenic from one data set. EPA has determined that land application of CKD with metals concentration limits at or below the industry-wide median concentrations does not pose a significant human cancer or non-cancer health risk. Therefore, with appropriate limits, CKD can be beneficially reused for land application on agricultural land in a manner that is protective of human health and the environment.

Schreiber, R.J.; Smeenk, S.D. [Schreiber, Yonley and Associates, St. Louis, MO (United States)

1998-12-31T23:59:59.000Z

14

Analysis of Energy Savings by Painting a Rotary Kiln Surface  

E-Print Network [OSTI]

Rotary Kilns has been widely used for processing minerals, producing cement, calcining petroleum cokes, or drying biomass and wastes. Most of rotary kilns consume energy intensively. Therefore it is desired to assess the thermal losses from the kiln...

Li, X.; Wang, T.; Tonti, R. T.; Edwards, L.

2007-01-01T23:59:59.000Z

15

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

and a vertical shaft kiln at another cement manufacturingrotary kiln or vertical shaft kiln in a cement plant. Baseda vertical shaft kiln (VSK) at another cement manufacturing

Price, Lynn

2013-01-01T23:59:59.000Z

16

Massachusetts Directory of Sawmills & Dry Kilns 2003  

E-Print Network [OSTI]

Massachusetts Directory of Sawmills & Dry Kilns ­ 2003 David T. Damery - University to Sawmill Listings iv Section 1 ­ Sawmill & Dry Kiln Directories Sawmills Operating in Massachusetts 1 of Sawtimber Trees by Diameter, 1972-1998 29 History of Massachusetts Sawmills Listed in Directory 30 Stumpage

Schweik, Charles M.

17

Coal desulfurization in a rotary kiln combustor  

SciTech Connect (OSTI)

The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

Cobb, J.T. Jr.

1992-09-11T23:59:59.000Z

18

Energy Efficient Microwave Hybrid Processing of Lime for Cement, Steel, and Glass Industries  

SciTech Connect (OSTI)

In this study, the microwave materials interactions were studied through dielectric property measurements, process modeling, and lab scale microwave hybrid calcination tests. Characterization and analysis were performed to evaluate material reactions and energy usage. Processing parameters for laboratory scale and larger scale calcining experiments were developed for MAT limestone calcination. Early stage equipment design concepts were developed, with a focus on microwave post heating treatment. The retrofitting of existing rotary calcine equipment in the lime industry was assessed and found to be feasible. Ceralink sought to address some of the major barriers to the uptake of MAT identified as the need for (1) team approach with end users, technology partners, and equipment manufacturers, (2) modeling that incorporates kiln materials and variations to the design of industrial microwave equipment. This project has furthered the commercialization effort of MAT by working closely with an industrial lime manufacturer to educate them regarding MAT, identifying equipment manufacturer to supply microwave equipment, and developing a sophisticated MAT modeling with WPI, the university partner. MAT was shown to enhance calcining through lower energy consumption and faster reaction rates compared to conventional processing. Laboratory testing concluded that a 23% reduction in energy was possible for calcining small batches (5kg). Scale-up testing indicated that the energy savings increased as a function of load size and 36% energy savings was demonstrated (22 kg). A sophisticated model was developed which combines simultaneous microwave and conventional heating. Continued development of this modeling software could be used for larger scale calcining simulations, which would be a beneficial low-cost tool for exploring equipment design prior to actual building. Based on these findings, estimates for production scale MAT calcining benefits were calculated, assuming uptake of MAT in the US lime industry. This estimate showed that 7.3 TBTU/year could be saved, with reduction of 270 MMlbs of CO2 emissions, and $29 MM/year in economic savings. Taking into account estimates for MAT implementation in the US cement industry, an additional 39 TBTU/year, 3 Blbs of CO2 and $155 MM/year could be saved. One of the main remaining barriers to commercialization of MAT for the lime and cement industries is the sheer size of production. Through this project, it was realized that a production size MAT rotary calciner was not feasible, and a different approach was adapted. The concept of a microwave post heat section located in the upper portion of the cooler was devised and appears to be a more realistic approach for MAT implementation. Commercialization of this technology will require (1) continued pilot scale calcining demonstrations, (2) involvement of lime kiln companies, and (3) involvement of an industrial microwave equipment provider. An initial design concept for a MAT post-heat treatment section was conceived as a retrofit into the cooler sections of existing lime rotary calciners with a 1.4 year payback. Retrofitting will help spur implementation of this technology, as the capital investment will be minimal for enhancing the efficiency of current rotary lime kilns. Retrofits would likely be attractive to lime manufacturers, as the purchase of a new lime kiln is on the order of a $30 million dollar investment, where as a MAT retrofit is estimated on the order of $1 million. The path for commercialization lies in partnering with existing lime kiln companies, who will be able to implement the microwave post heat sections in existing and new build kilns. A microwave equipment provider has been identified, who would make up part of the continued development and commercialization team.

Fall, Morgana L; Yakovlev, Vadim; Sahi, Catherine; Baranova, Inessa; Bowers, Johnney G; Esquenazi\t, Gibran L

2012-02-10T23:59:59.000Z

19

The Needs of Texas Soils for Lime.  

E-Print Network [OSTI]

Department of Agriculture. STS PAGE ............................................. What lime does 5 ............................................. Acidity of soils 7 ............................................. Sources of lime 8... of Texas soils for lime, as far as our present information permits. WHST LIME DOES Lime performs sereral functions in the soil, some of which are favor- able to increased crops and the maintenance of fertility, some favorable to certain crops...

Fraps, G. S. (George Stronach)

1919-01-01T23:59:59.000Z

20

JV Task-Long-Kiln NOx Reduction Study  

SciTech Connect (OSTI)

Field sampling was conducted by the Energy & Environmental Research Center at two Lafarge North America cement kiln locations in Canada. Emissions including SO{sub x}, NO{sub x}, and particulate were measured and reported at various locations throughout the kilns. At each site data were collected on two kilns during field sampling. However, only Kiln 1 at the Ravena site was utilized for modeling efforts. Experimental work was then conducted to estimate the effectiveness of various NO{sub x} control techniques on limiting both NO{sub x} and SO{sub x} emissions in cement kiln exhaust. Theory-based models were constructed to estimate both NO{sub x} and SO{sub x} emissions from cement kilns. These models were then applied to estimating the impact of various NO{sub x} control strategies on kiln exhaust emissions. The sulfur model constructed as part of this work was successful at predicting SO{sub 2} emissions and sulfur capture in the Alpena kiln. This model is designed to run as a postprocessing step that uses the output of a NO{sub x} model as input. With an accurate NO{sub x} model, the sulfur model may prove to be a valuable tool in estimating the impact of kiln modifications on sulfur emissions. The NO{sub x} model was also applied to model several operating scenarios on three of Lafarge's kilns: Alpena 20/21, Alpena 22/23, and Ravena 1. The predictions of the flue gas temperature at the kiln feed end, the kiln shell heat loss, the quality of clinker, and the excess O{sub 2} in the flue gas are consistent with the audit data. The developed simulation tool in this project has proven to be an effective way to investigate the NO{sub x} emissions, to optimize kiln performance, and to assess changes in operating condition on kiln performance.

Bruce Folkedahl; Joshua Strege; Darren Schmidt; Lingbu Kong

2008-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

LOW VELOCITY SHPERE IMPACT OF SODA LIME SILICATE GLASS  

SciTech Connect (OSTI)

This report summarizes TARDEC-sponsored work at Oak Ridge National Laboratory (ORNL) during the FY11 involving low velocity ( 30 m/s or 65 mph) ball impact testing of Starphire soda lime silicate glass. The intent was to better understand low velocity impact response in the Starphire for sphere densities that bracketed that of rock. Five sphere materials were used: borosilicate glass, soda-lime silicate glass, steel, silicon nitride, and alumina. A gas gun was fabricated to produce controlled velocity delivery of the spheres against Starphire tile targets. Minimum impact velocities to initiate fracture in the Starphire were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the any of the five sphere-Starphire-target combinations.

Morrissey, Timothy G [ORNL; Fox, Ethan E [ORNL; Wereszczak, Andrew A [ORNL; Vuono, Daniel J [ORNL

2012-01-01T23:59:59.000Z

22

Cement Kiln Flue Gas Recovery Scrubber Project  

SciTech Connect (OSTI)

The Cement Kiln Flue Gas Recovery Scrubber Project was a technical success and demonstrated the following: CKD can be used successfully as the sole reagent for removing SO2 from cement kiln flue gas, with removal efficiencies of 90 percent or greater; Removal efficiencies for HCl and VOCs were approximately 98 percent and 70 percent, respectively; Particulate emissions were low, in the range of 0.005 to 0.007 grains/standard cubic foot; The treated CKD sorbent can be recycled to the kiln after its potassium content has been reduced in the scrubber, thereby avoiding the need for landfilling; The process can yield fertilizer-grade K2SO4, a saleable by-product; and Waste heat in the flue gas can provide the energy required for evaporation and crystallization in the by-product recovery operation. The demonstration program established the feasibility of using the Recovery Scrubber{trademark} for desulfurization of flue gas from cement kilns, with generally favorable economics, assuming tipping fees are available for disposal of ash from biomass combustion. The process appears to be suitable for commercial use on any type of cement kiln. EPA has ruled that CKD is a nonhazardous waste, provided the facility meets Performance Standards for the Management of CKD (U.S. Environmental Protection Agency 1999d). Therefore, regulatory drivers for the technology focus more on reduction of air pollutants and pollution prevention, rather than on treating CKD as a hazardous waste. Application of the Recovery Scrubbe{trademark} concept to other waste-disposal operations, where pollution and waste reductions are needed, appears promising.

National Energy Technology Laboratory

2001-11-30T23:59:59.000Z

23

Method for firing a rotary kiln with pulverized solid fuel  

SciTech Connect (OSTI)

Disclosed is a method for firing a kiln as well as a method for producing cement clinker in which pulverized coal is initially entrained in an airflow of about 2% of the theoretical amount of air needed to combust the coal and transport it to a burner. Supplemental primary air heated sufficiently to vaporize volatiles in the coal is mixed with the coal flow in a burner, discharged into the kiln and hence ignited. Secondary combustion air heated to between 800 F to 1650 F and more is added in the kiln to effect the substantially complete combustion of the pulverized coal in the kiln.

Binasik, C.S.; Siegert, L.D.

1982-01-12T23:59:59.000Z

24

Cement kiln flue dust as a source of lime and potassium in four East Texas soils  

E-Print Network [OSTI]

design on both sites. Yield, soil pH, plant and soil concentrations of K, Ca, and Mg were determined. Soil pH and extractable Ca increased with increasing rate of flue dust or calcite. Under field conditions, flue dust compared favorably with calcite... was similar to plant uptake from corresponding calcite + KC1 treatments. Soil pH and extractable soil K, Ca, and Mg increased with increased rate of flue dust treatment equally as well as from the corresponding calcite treatments. The flue dust was equal...

Poole, Warren David

1975-01-01T23:59:59.000Z

25

Sulfate Induced Heave: Addressing Ettringite Behavior in Lime Treated Soils and in Cementitious Materials  

E-Print Network [OSTI]

, due to the formation of expansive minerals like ettringite and thaumasite, has been recognized as a problem in Portland cement concrete, stabilized soils, weathered cements, alkaline fly ashes, FGD wastes, chromite ore processing residues and cement... moles of Ca2+, 2 moles of Al3+, 3 moles of SO42-, and 32 moles of water are required. Calcium ions are provided by lime, Portland cement, or fly ash; alumina is supplied by dissolution of oxyhydroxides and phyllosilicates; and sulfates are supplied...

Kochyil Sasidharan Nair, Syam Kumar

2012-02-14T23:59:59.000Z

26

Microporous alumina ceramic membranes  

DOE Patents [OSTI]

Several methods are disclosed for the preparation microporous alumina ceramic membranes. For the first time, porous alumina membranes are made which have mean pore sizes less than 100 Angstroms and substantially no pores larger than that size. The methods are based on improved sol-gel techniques.

Anderson, M.A.; Guangyao Sheng.

1993-05-04T23:59:59.000Z

27

Burning hazardous waste in cement kilns  

SciTech Connect (OSTI)

The cement manufacturing process is one of the oldest in the world, having been in practice for over 2000 years. It is also one of the most energy intensive, with up to 65 percent of the cost of the product attributable to energy consumption. In addition to high energy demand, the process conditions include extremely high temperatures. Cement clinker forms when the correct mixture of raw materials is heated to 2650/sup 0/ F. This requires combustion temperatures exceeding 3000/sup 0/ F. under oxidizing conditions. To accomplish this, gas temperatures above 2000/sup 0/ F. occur for several seconds (typically five seconds), which is much longer than residence times in permitted hazardous waste incinerators. These conditions are extremely favorable to the destruction of organic compounds and have led to extensive investigation into the potential for burning hazardous waste in cement kilns. Cement kilns consuming hazardous wastes have been tested for air emissions under various operating conditions. The substantial body of information on the emissions and handling of hazardous wastes from these studies has demonstrated that effective destruction of wastes can be accomplished with the added benefits of energy conservation and no significant change in air emissions.

Chadbourne, J.F.; Helmsteller, A.J.

1983-06-01T23:59:59.000Z

28

Reuse of activated alumina  

SciTech Connect (OSTI)

Activated alumina is used as a trapping media to remove trace quantities of UF{sub 6} from process vent streams. The current uranium recovery method employs concentrated nitric acid which destroys the alumina pellets and forms a sludge which is a storage and disposal problem. A recently developed technique using a distilled water rinse followed by three dilute acid rinses removes on average 97% of the uranium, and leaves the pellets intact with crush strength and surface area values comparable with new material. Trapping tests confirm the effectiveness of the recycled alumina as UF{sub 6} trapping media.

Hobensack, J.E. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States)

1991-12-31T23:59:59.000Z

29

Sulfur dioxide oxidation and plume formation at cement kilns  

SciTech Connect (OSTI)

Results of source sampling at the Glens Falls cement kiln in Glens Falls, N.Y., are reported for sulfur oxides, ammonia, hydrochloric acid, oxygen, and moisture content. The origin of a detached, high-opacity, persistent plume originating from the cement kiln stack is investigated. It is proposed that this plume is due to ammonium salts of SOx and sulfuric acid that have been formed in condensed water droplets in the plume by the pseudocatalytic action of ammonia. (1 diagram, 1 graph, 22 references, 7 tables)

Dellinger, B.; Grotecloss, G.; Fortune, C.R.; Cheney, J.L.; Homolya, J.B.

1980-10-01T23:59:59.000Z

30

Sulfate induced heave in lime stabilized soil  

E-Print Network [OSTI]

The addition of hydrated lime to clay soils is one of the most common methods of soil stabilization. However, when sulfates are present in the soil, the calcium in the lime reacts with the sulfates to form ettringite, an expandable mineral...

Bredenkamp, Sanet

1994-01-01T23:59:59.000Z

31

Factors affecting the supply and demand for limes and lime oil in the U.S.: development implications for Veracruz state, Mexico.  

E-Print Network [OSTI]

??The fresh lime industry is an important economic activity in Veracruz, Mexico. In this thesis, the economic potential of the fresh lime and lime oil (more)

Abarca Orozco, Saul Julian

2007-01-01T23:59:59.000Z

32

Opacity reduction using hydrated lime injection  

SciTech Connect (OSTI)

The purpose of this investigation is to study the effects of injecting dry hydrated lime into flue gas to reduce sulfur trioxide (SO{sub 3}) concentrations and consequently stack opacity at the University of Missouri, Columbia power plant. Burning of high sulfur coal (approx. 4% by weight) at the power plant resulted in opacity violations. The opacity problem was due to sulfuric acid mist (H{sub 2}SO{sub 4}) forming at the stack from high SO{sub 3} concentrations. As a result of light scattering by the mist, a visible plume leaves the stack. Therefore, reducing high concentrations of SO{sub 3} reduces the sulfuric acid mist and consequently the opacity problem. The current hydrated lime injection system has reduced the opacity to acceptable limits. To reduce SO{sub 3} concentrations, dry hydrated lime is injected into the flue gas upstream of a particulate collection device (baghouse) and downstream of the induced draft fan. The lime is periodically injected into the flue via a pneumatic piping system. The hydrated lime is transported down the flue and deposited on the filter bags in the baghouse. As the hydrated lime is deposited on the bags a filter cake is established. The reaction between the SO{sub 3} and the hydrated lime takes place on the filter bags. The hydrated lime injection system has resulted in at least 95% reduction in the SO{sub 3} concentration. Low capital equipment requirements and operating cost coupled with easy installation and maintenance makes the system very attractive to industries with similar problems. This paper documents the hydrated lime injection system and tests the effectiveness of the system on SO{sub 3} removal and subsequent opacity reduction. Measurements Of SO{sub 3} concentrations, flue gas velocities, and temperatures have been performed at the duct work and baghouse. A complete analysis of the hydrated lime injection system is provided.

Wolf, D.E.; Seaba, J.P. [Univ. of Missouri, Columbia, MO (United States)

1993-12-31T23:59:59.000Z

33

The use of scrap tires in rotary cement kilns  

SciTech Connect (OSTI)

The use of scrap tires as a supplemental fuel in the United States Portland cement industry has increased significantly in the past six years. In 1990, there were two kilns using tire-derived fuel (TDF), today 30 kilns use TDF. The outlook for continued and expanded use of TDF in the U.S. cement industry should be considered favorable, with 15 kilns conducting tests to determine TDF`s applicability or in the permitting process. The Council`s estimates are that by the end of 1996, the cement industry could be consuming some 75-100 million of the 253 million annually generated scrap tires in the United States. This level of TDF usage will make the cement industry the largest market segments for scrap tires in the United States. While the long-term outlook is at present positive, there are a series of factors that have, and will likely continue to adversely impact the near-term usage of TDF. These issues, as well as the factors that are likely to positively impact the cement kiln TDF market are the subject of this presentation.

Blumenthal, M. [Scrap Tire Management Council, Washington, DC (United States)

1996-12-31T23:59:59.000Z

34

Low Velocity Sphere Impact of a Soda Lime Silicate Glass  

SciTech Connect (OSTI)

This report summarizes TARDEC-sponsored work at Oak Ridge National Laboratory (ORNL) during the FY11 involving low velocity (< 30 m/s or < 65 mph) ball impact testing of Starphire soda lime silicate glass. The intent was to better understand low velocity impact response in the Starphire for sphere densities that bracketed that of rock. Five sphere materials were used: borosilicate glass, soda-lime silicate glass, steel, silicon nitride, and alumina. A gas gun was fabricated to produce controlled velocity delivery of the spheres against Starphire tile targets. Minimum impact velocities to initiate fracture in the Starphire were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the any of the five sphere-Starphire-target combinations. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) Frictional effects contribute to fracture initiation. (2) Spheres with a lower elastic modulus require less force to initiate fracture in the Starphire than spheres with a higher elastic modulus. (3) Contact-induced fracture did not initiate in the Starphire SLS for impact kinetic energies < 150 mJ. Fracture sometimes initiated or kinetic energies between {approx} 150-1100 mJ; however, it tended to occur when lower elastic modulus spheres were impacting it. Contact-induced fracture would always occur for impact energies > 1100 mJ. (4) The force necessary to initiate contact-induced fracture is higher under dynamic or impact conditions than it is under quasi-static indentation conditions. (5) Among the five used sphere materials, silicon nitride was the closest match to 'rock' in terms of both density and (probably) elastic modulus.

Wereszczak, Andrew A [ORNL; Fox, Ethan E [ORNL; Morrissey, Timothy G [ORNL; Vuono, Daniel J [ORNL

2011-10-01T23:59:59.000Z

35

Method and system including a double rotary kiln pyrolysis or gasification of waste material  

DOE Patents [OSTI]

A method is described for destructively distilling an organic material in particulate form wherein the particulates are introduced through an inlet into one end of an inner rotating kiln ganged to and coaxial with an outer rotating kiln. The inner and outer kilns define a cylindrical annular space with the inlet being positioned in registry with the axis of rotation of the ganged kilns. During operation, the temperature of the wall of the inner rotary kiln at the inlet is not less than about 500 C to heat the particulate material to a temperature in the range of from about 200 C to about 900 C in a pyrolyzing atmosphere to reduce the particulate material as it moves from the one end toward the other end. The reduced particulates including char are transferred to the annular space between the inner and the outer rotating kilns near the other end of the inner rotating kiln and moved longitudinally in the annular space from near the other end toward the one end in the presence of oxygen to combust the char at an elevated temperature to produce a waste material including ash. Also, heat is provided which is transferred to the inner kiln. The waste material including ash leaves the outer rotating kiln near the one end and the pyrolysis vapor leaves through the particulate material inlet. 5 figs.

McIntosh, M.J.; Arzoumanidis, G.G.

1997-09-02T23:59:59.000Z

36

Method and system including a double rotary kiln pyrolysis or gasification of waste material  

DOE Patents [OSTI]

A method of destructively distilling an organic material in particulate form wherein the particulates are introduced through an inlet into one end of an inner rotating kiln ganged to and coaxial with an outer rotating kiln. The inner and outer kilns define a cylindrical annular space with the inlet being positioned in registry with the axis of rotation of the ganged kilns. During operation, the temperature of the wall of the inner rotary kiln at the inlet is not less than about 500.degree. C. to heat the particulate material to a temperature in the range of from about 200.degree. C. to about 900.degree. C. in a pyrolyzing atmosphere to reduce the particulate material as it moves from the one end toward the other end. The reduced particulates including char are transferred to the annular space between the inner and the outer rotating kilns near the other end of the inner rotating kiln and moved longitudinally in the annular space from near the other end toward the one end in the presence of oxygen to combust the char at an elevated temperature to produce a waste material including ash. Also, heat is provided which is transferred to the inner kiln. The waste material including ash leaves the outer rotating kiln near the one end and the pyrolysis vapor leaves through the particulate material inlet.

McIntosh, Michael J. (Bolingbrook, IL); Arzoumanidis, Gregory G. (Naperville, IL)

1997-01-01T23:59:59.000Z

37

A method and system including a double rotary kiln pyrolysis or gasification of waste material  

SciTech Connect (OSTI)

A method is described for destructively distilling an organic material in particulate form wherein the particulates are introduced through an inlet into one end of an inner rotating kiln ganged to and coaxial with an outer rotating kiln. The inner and outer kilns define a cylindrical annular space with the inlet being positioned in registry with the axis of rotation of the ganged kilns. During operation, the temperature of the wall of the inner rotary kiln at the inlet is not less than about 500 C to heat the particulate material to a temperature in the range of from about 200 C to about 900 C in a pyrolyzing atmosphere to reduce the particulate material as it moves from the one end toward the other end. The reduced particulates including char are transferred to the annular space between the inner and the outer rotating kilns near the other end of the inner rotating kiln and moved longitudinally in the annular space from near the other end toward the one end in the presence of oxygen to combust the char at an elevated temperature to produce a waste material including ash. Also, heat is provided which is transferred to the inner kiln. The waste material including ash leaves the outer rotating kiln near the one end and the pyrolysis vapor leaves through the particulate material inlet.

McIntosh, M.J.; Arzoumanidis, G.G.

1995-12-31T23:59:59.000Z

38

Gelcasting Polycrystalline Alumina  

SciTech Connect (OSTI)

OSRAM SYLVANIA INC. is a major U.S. manufacturer of high-intensity lighting. Among its products is the Lumalux TM line of high-pressure sodium vapor arc lamps, which are used for industrial, highway, and street lighting. The key to the performance of these lamps is the polycrystalline alumina (PCA) tube that is used to contain the plasma that is formed in the electric arc. That plasma consists of ionized sodium, mercury, and xenon vapors. The key attributes of the PCA tubes are their transparency ({approximately}97% total transmittance in the visible), their refractoriness (inner wall temperature can reach l2OOC), and their chemical resistance (sodium and mercury vapor are extremely corrosive). The current efficiency of the lamps is very high, up to 100 initial lumens per watt. (Compare incandescent lamps 10-20 lumens per watt, fluorescent lamps 25-90 lumens per watt.)

Janney, M.A.; Zuk, K.J.; Wei, G.C.

2000-01-01T23:59:59.000Z

39

Accepted Manuscript A wall heat transfer correlation for the baffled-rotary kilns with secondary air  

E-Print Network [OSTI]

Accepted Manuscript A wall heat transfer correlation for the baffled-rotary kilns with secondary;1 A wall heat transfer correlation for the baffled- rotary kilns with secondary air flow and recycled industrial applications suggests examining the heat transfer phenomena in order to improve the multi

Boyer, Edmond

40

Combined archaeomagnetic and thermoluminescence study of a brick kiln excavated at Fontanetto Po (Vercelli, Northern Italy)  

E-Print Network [OSTI]

: Rescue excavation Archaeomagnetism Thermoluminescence dating Kiln Italy a b s t r a c t A combined 1511 to 1614 AD, and a second one from 1768 to 1872 AD. Thermoluminescence (TL) study has been also perCombined archaeomagnetic and thermoluminescence study of a brick kiln excavated at Fontanetto Po

Demouchy, Sylvie

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Method and apparatus for maximizing throughput of indirectly heated rotary kilns  

DOE Patents [OSTI]

An apparatus and method for achieving improved throughput capacity of indirectly heated rotary kilns used to produce pyrolysis products such as shale oils or coal oils that are susceptible to decomposition by high kiln wall temperatures is disclosed. High throughput is achieved by firing the kiln such that optimum wall temperatures are maintained beginning at the point where the materials enter the heating section of the kiln and extending to the point where the materials leave the heated section. Multiple high velocity burners are arranged such that combustion products directly impact on the area of the kiln wall covered internally by the solid material being heated. Firing rates for the burners are controlled to maintain optimum wall temperatures.

Coates, Ralph L; Smoot, L. Douglas; Hatfield, Kent E

2012-10-30T23:59:59.000Z

42

The lime-soda sinter process for resource recovery from fly ash: A new look  

SciTech Connect (OSTI)

The lime-soda sinter process is one of the earliest and most thoroughly researched and evaluated of the several methods available for resource recovery from fly ash. The principle product, metallurgical grade alumina, is obtained with yields as high as 90% depending upon how much alumina needs to be left in the residue to form acceptable byproduct cement clinker. The process has the advantages of requiring a relatively low sintering temperature (1100-1200{degree}C), using conventional equipment of carbon steel construction, utilizing a variety of calcium and mineralizer raw materials, and producing only a single byproduct consisting of dicalcium silicate that has been shown to be an attractive raw material for the manufacture of portland cement. An economic feasibility study for a combined facility to produce alumina and cement from the fly ash generated by a 1000 MWe coal-fired power station shows a 10.5% return on average investment. This is increased to 14.2% when a disposal charge of $10/ton of fly ash consumed is credited to the process. Research has shown that the soda ash can be replaced by coal cleaning refuse or that the soda ash and one-fourth of the limestone can be replaced by FGD sludge with a savings in raw material cost in both cases. The return on average investment becomes 14.5% when the refuse is used and 15.2% when the sludge is used. The return could be increased further if an inexpensive fluxing agent were substituted for the alumina deliberately left in the residue. 12 refs., 2 figs., 7 tabs.

Burnet, G.

1991-01-01T23:59:59.000Z

43

Coal desulfurization in a rotary kiln combustor. Final report, March 15, 1990--July 31, 1991  

SciTech Connect (OSTI)

The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

Cobb, J.T. Jr.

1992-09-11T23:59:59.000Z

44

E-Print Network 3.0 - alumina silica-alumina etude Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

14 (2004) 681686 PII: S0960-1317(04)71691-5 Summary: for silica, alumina, and titania aerogels. Silica and alumina aerogel cantilevers are fabricated on the basis... Silica Silica...

45

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

air coefficient A summary of heat supply and use reported inmore than 25% of total heat supply to the kiln. Chemically

Price, Lynn

2013-01-01T23:59:59.000Z

46

Physical chemistry of carbothermic reduction of alumina  

SciTech Connect (OSTI)

Production of aluminium, by means of carbothermic reduction of alumina, is discussed. By employing a solvent metal bath to absorb the alumina metal, carbothermic reduction of alumina was accomplished at temperatures 300/degree/C lower than the temperatures reported in the literature. Reduction occurred without the formation of intermediate compounds and without the high volatilization of aluminum bearing species. Reduction of alumina immersed in a solvent bath appeared to be rate limited by chemical reaction control. The rates seemed to be a function of the activity of aluminum in the solvent metal bath. Reduction of alumina particles, above the surface of the bath, seemed to occur via vapor transport with carbon in the particles or in the crucible walls. Mass transport in the gas phase appeared to be rate limiting. The rates seemed to be a function of the distance separating the alumina and carbon sources. With both submerged alumina and alumina particles, increasing the surface area of the alumina increased the rate of reduction. 58 refs., 65 figs., 9 tabs.

Frank, Robert A.

1985-09-01T23:59:59.000Z

47

Synthesis of high porosity, monolithic alumina aerogels  

SciTech Connect (OSTI)

Many non-silica aerogels are notably weak and fragile in monolithic form. Particularly, few monolithic aerogels with densities less than 50kg/m3 have any significant strength. It is especially difficult to prepare uncracked monoliths of pure alumina aerogels that are robust and moisture stable. In this paper, we discuss the synthesis of strong, stable, monolithic, high porosity (>98% porous) alumina aerogels, using a two-step sol-gel process. The alumina aerogels have a polycrystalline morphology that results in enhanced physical properties. Most of the measured physical properties of the alumina aerogels are superior to those for silica aerogels for equivalent densities.

Poco, J F; Satcher, J H; Hrubesh, L W

2000-09-20T23:59:59.000Z

48

E-Print Network 3.0 - acid lime plants Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Application of Activated Carbon Enhanced Lime for Controlling Acid Gases, Mercury, and Dioxins form MWCs... PEER-REVIEW Lime Enhances Moving Bed Filters for Mercury and Dioxin...

49

Lime slurry use at the Industrial Wastewater Pretreatment Facility  

SciTech Connect (OSTI)

The use of lime slurry at the IWPF demonstrated many benefits. Hazardous chemical use was reduced, solids handling was improved, water quality was enhanced and there has been a cost savings. The lime slurry also enabled the plant to begin treating the soluble oil waste, which we were not able to do in the past.

Rice, L.E. [Allied-Signal Aerospace Co., Kansas City, MO (United States). Kansas City Div.; Hughes, R.W. [Professional Services Group, Inc., Kansas City, MO (United States); Baggett, G. [Genex/Praxair, Inc., Kansas City, MO (United States)

1996-04-01T23:59:59.000Z

50

Alumina forming iron base superalloy  

SciTech Connect (OSTI)

An austenitic stainless steel alloy, consists essentially of, in weight percent 2.5 to 4 Al; 25 to 35 Ni; 12 to 19 Cr; at least 1, up to 4 total of at least one element selected from the group consisting of Nb and Ta; 0.5 to 3 Ti; less than 0.5 V; 0.1 to 1 of at least on element selected from the group consisting of Zr and Hf; 0.03 to 0.2 C; 0.005 to 0.1 B; and base Fe. The weight percent Fe is greater than the weight percent Ni. The alloy forms an external continuous scale including alumina, and contains coherent precipitates of .gamma.'-Ni.sub.3Al, and a stable essentially single phase FCC austenitic matrix microstructure. The austenitic matrix is essentially delta-ferrite-free and essentially BCC-phase-free.

Yamamoto, Yukinori; Muralidharan, Govindarajan; Brady, Michael P.

2014-08-26T23:59:59.000Z

51

Enhancement of phosphogypsum with high lime fly ash  

E-Print Network [OSTI]

ENHANCEMENT OF PHOSPHOGYPSUM WITH HIGH LIME FLY ASH A Thesis by CHUCK ALAN GREGORY Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1983 Major... Subject: Civil Engineering ENHANCEMENT OF PHOSPHOGYPSUM WITH HIGH'LIME FLY ASH A Thesis by CHUCK ALAN GREGORY Approved as to style and content by: Dr. ona d Saylak (Chairman f Committee) Dr. W. edbetter ( ember) (Member) r. Lloyd Deuel, 3...

Gregory, Chuck Alan

1983-01-01T23:59:59.000Z

52

Electrolytic Cell For Production Of Aluminum From Alumina  

DOE Patents [OSTI]

An electrolytic cell for producing aluminum from alumina having a reservoir for collecting molten aluminum remote from the electrolysis.

Bradford, Donald R (Underwood, WA); Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR)

2004-11-02T23:59:59.000Z

53

Catalytic iron oxide for lime regeneration in carbonaceous fuel combustion  

SciTech Connect (OSTI)

Lime utilization for sulfurous oxides absorption in fluidized combustion of carbonaceous fuels is improved by impregnation of porous lime particulates with iron oxide. The impregnation is achieved by spraying an aqueous solution of mixed iron sulfate and sulfite on the limestone before transfer to the fluidized bed combustor, whereby the iron compounds react with the limestone substrate to form iron oxide at the limestone surface. It is found that iron oxide present in the spent limestone acts as a catalyst to regenerate the spent limestone in a reducing environment. With only small quantities of iron oxide the calcium can be recycled at a significantly increased rate.

Shen, M.; Yang, R.T.

1980-09-30T23:59:59.000Z

54

Impacts of ocean acidification and mitigative hydrated lime addition on Pacific oyster larvae  

E-Print Network [OSTI]

Impacts of ocean acidification and mitigative hydrated lime addition on Pacific oyster larvae, and for other species. Keywords: Ocean acidification; Pacific oyster; Larval stages; Hydrated lime; Shellfish No.: 577 Title of Project: Impacts of ocean acidification and mitigative hydrated lime addition

55

New waste based clinkers: Belite and lime formulations  

SciTech Connect (OSTI)

This work describes the formulation of new belite-based (CR2) and lime-based (CR3) cementitious materials derived from industrial wastes, such as sludges (generated in the Al-anodising and surface coating industrial processes, potable water filtration/cleaning operations and in marble sawing processes) and foundry sand. Powder mixtures were prepared and fired at different temperatures. For comparison, similar formulations were prepared with pre-treated and commercially available natural raw materials and processed in similar conditions. The thermal process was followed by differential scanning calorimetry (DSC) and high-temperature powder X-ray diffraction (HT-XRD) studies. The CR2 clinker was found to contain belite as the main cementitious phase, the main polymorph being identified by NMR. The CR3 clinker contained common cementitious phases, such as C{sub 3}A and C{sub 3}S, but free lime and calcium aluminium oxide sulphates were also identified by high temperature XRD and NMR. Then the corresponding cement was prepared and the evolution of the mechanical strength with time was evaluated. The lime-based cement obtained from wastes shows a stronger hardening character than the standard material, which tends to show dusting phenomena due to the presence of a reasonable amount of free lime (as the result of its expansive reaction with ambient moisture). Some fluxing impurities (e.g. alkalis) present in the waste materials improve the overall reactivity of the mixture and induces the combination of the lime in CR3. Raman, XPS and FIB techniques were used to fully characterise the aged cements.

Raupp-Pereira, Fabiano [Ceramics and Glass Engineering Department, CICECO, University of Aveiro, 3810-193 Aveiro (Portugal); Ball, Richard James [University of Bristol, Interface Analysis Centre, Oldbury House, 121 St Michael's Hill, Bristol, BS2 8BS (United Kingdom)], E-mail: richard.ball@bristol.ac.uk; Rocha, Joao [Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro (Portugal); Labrincha, Joao A. [Ceramics and Glass Engineering Department, CICECO, University of Aveiro, 3810-193 Aveiro (Portugal); Allen, Geoffrey C. [University of Bristol, Interface Analysis Centre, Oldbury House, 121 St Michael's Hill, Bristol, BS2 8BS (United Kingdom)

2008-04-15T23:59:59.000Z

56

A simple procedure to prepare spherical {alpha}-alumina powders  

SciTech Connect (OSTI)

Spherical {alpha}-alumina powders were prepared by the controlled hydrolysis of aluminum isopropoxide in a hydrolysis system consisting of octanol and acetonitrile. Diverse solvents to dissolve reactant formed diverse hydrolysis systems and affected particle shape of {alpha}-alumina powders. The precursors crystallized to {gamma}-alumina at 1000 deg. C and converted to {alpha}-alumina at 1150 deg. C without intermediate phases. The particle morphology of precursor was retained after it crystallized to {alpha}-alumina. The heating rate influenced the particle shape and the state of agglomeration during calcination process. The thermal properties of the precursors were characterized by thermal gravimetric and differential thermal analysis. X-ray diffraction technique was used to confirm the conversion of crystalline phase of alumina powders from amorphous to {alpha}-phase. Transmission electron microscopy was used to investigate the morphologies and size of the precursors and products.

Liu Hongyu [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China); Ning Guiling [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China)], E-mail: ninggl@dlut.edu.cn; Gan Zhihong; Lin Yuan [State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012 (China)

2009-04-02T23:59:59.000Z

57

Precipitation kinetics in ultra-high lime softening  

E-Print Network [OSTI]

. The second model used the crystal growth rate as an alternate measure of supersaturation. The growth rate obtained from a settling procedure correlated well with values for silica removal rates for experiments grouped by pH and recycie conditions... of precipitation processes specific applications to lime soFtening and silica removal can be addressed. Mechanisms oF silica raawal. Many of the processes studied for specific removal of silica From industrial water have relied on adsorption...

Peacock, Edward Dale

1986-01-01T23:59:59.000Z

58

alumina capillaries mcp: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

418 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

59

anodic alumina membranes: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

307 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

60

alumina coatings operating: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

185 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

aqueous nanometric alumina: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

H. Eugene 165 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

62

anodic porous alumina: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tsaros 388 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

63

alumina zirconia composite: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Frank 202 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

64

alumina pillared bentonite: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

214 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

65

anodic alumina membrane: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

307 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

66

anodic alumina formed: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

234 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

67

anodic alumina films: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

268 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

68

anodic alumina template: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

445 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

69

anodic alumina supported: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

240 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

70

anodic alumina templates: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

445 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

71

alumina scale spallation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

234 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

72

alumina zinc oxide: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Donald L. 420 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

73

Infiltration of nickel into alumina compact by electrodeposition  

SciTech Connect (OSTI)

Ni metal was electrodeposited into pores of an alumina compact in the aqueous solution of nickel nitrate/urea/ethylene glycol/ammonium sulfate. The Ni{sup 2+} ions in pores of the alumina compact deposited in proportion to t{sup 0.45}-t{sup 0.61} of deposition time (t) on Au electrode sputtered on the alumina surface. The deposition rate of Ni was higher for direct current than pulsed current Nickel grew dendritically in the alumina pores.

Hirata, Yoshihiro; Kyoda, Hideharu; Iwamoto, Takayuki [Kagoshima Univ. (Japan)

1995-09-01T23:59:59.000Z

74

Plasma preparation of planar models of alumina catalysts: their characterization and impregnation chemistry  

E-Print Network [OSTI]

of the films with ruthenium chloride. iv TABLE OF CONTENTS PAGE I INTRODUCTION A. Preparation of Planar Alumina Films. B. Preparation and Characteristics of Alumina C. Impregnation Chemistry of Alumina. II THEORY 2 3 10 21 A. Plasma Chemistry . B... OF FIGURES FIGURE 1 ? Transformations of aluminum oxides. 2 - Low index planes of alumina. 3 - Infrared stretching frequencies for OR on alumina. 4 - XPS Al 2p shift for aluminum and its oxides. 5 - Inorganic reactions on alumina. 6 ? Dehydration...

Halverson, Dennis Eric

1987-01-01T23:59:59.000Z

75

Zinc recovery by ultrasound acid leaching of double kiln treated electric arc furnace dust  

SciTech Connect (OSTI)

The need to convert 70,000 tons a year of electric arc furnace (EAF) dust into an environmentally safe or recyclable product has encouraged studies to reclaim zinc from this waste material. Successful characterization of a double-kiln calcine, produced from EAF dust, has shown that the calcine pellets consisted mainly of zinc oxide plates with some iron oxide particles. Preliminary leaching tests using hydrochloric and sulfuric acids indicated that this calcine is suitable for selective ultrasound leaching of zinc. A factorially designed screening test using hydrochloric acid showed that ultrasound significantly lowered iron dissolution and increased zinc dissolution, thus enhancing the selective leaching of zinc. Ultrasound, temperature, air bubbling rate and acidity increased the sulfuric acid selectivity, while fluorosilicic acid was not selective. Reactor characterization through ultrasonic field measurements led to the selection of reactor and ultrasound bath, which were utilized to enhance the selectivity of a laboratory scale sulfuric acid leaching of a double-kiln treated electric arc furnace dust. Results indicated that ultrasonic leaching of this calcine is a satisfactory technique to selectively separate zinc from iron. After further iron removal by precipitation and cementation of nickel, it was possible to electrowin zinc from the leach liquor under common industrial conditions, with current efficiencies from 86% through 92% being observed. Calcine washing showed that a substantial chloride removal is possible, but fluoride ion in the electrolyte caused deposit sticking during electrowinning.

Barrera Godinez, J.A.

1989-01-01T23:59:59.000Z

76

E-Print Network 3.0 - alumina column purification Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Materials Science 28 A New Optically Reflective Thin Layer Electrode (ORTLE) Window: Gold on a Thin Porous Alumina Film Used to Observe the Summary: Alumina Film Used...

77

E-Print Network 3.0 - alumina thin films Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

constant in RF devices. Some unique features of thin-film silica and alumina aerogels have been... aerogel thin films, silica and alumina aerogel cantilevers were...

78

Interaction potentials for alumina and molecular dynamics simulations of amorphous and liquid alumina  

E-Print Network [OSTI]

Interaction potentials for alumina and molecular dynamics simulations of amorphous and liquid for preventing crystalliza- tion and giving chemical stability and durability to a glaze, for instance. Due been identified.4 A review of these crystal structures and their pre- cursors can be found in the work

Southern California, University of

79

E-Print Network 3.0 - agricultural liming techniques Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beech and sycamore, adventitious shoots... which are especially suitable for use in coppice woodland including ash, oak, chestnut, willow, lime... when well rooted. Alder, ash,...

80

Microstructural and Mechanical Characterization of Actively Brazed Alumina Specimens  

SciTech Connect (OSTI)

Alumina (94 and 99.8% grade compositions) was brazed directly to itself with gold-based active brazing alloys (ABA's) containing vanadium additions of 1,2 and 3 weight percent. The effects of brazing conditions on the joint properties were investigated. Wetting behavior, interfacial reactions, microstructure, hermeticity and tensile strength were determined. Wetting was fair to good for the ABA and base material combinations. Microanalysis identified a discontinuous Al-V-O spinel reaction product at the alumina-braze interface. Tensile strength results for 94% alumina were uniformly good and generally not sensitive to the vanadium concentration, with tensile values of 85-105 MPa. There was more variability in the 99.8% alumina strength results, with values ranging from 25-95 MPa. The highest vanadium concentration (3 wt. %) yielded the highest joint strength for the brazed 99.8% alumina. Failures in the 99.8% alumina samples occurred at the braze-alumina interface, while the 94% alumina specimens exhibited fracture of the ceramic substrate.

Hosking, F.M.; Cadden, C.H.; Stephens, J.J.; Glass, S.J.; Yang, N.Y.C.; Vianco, P.V.; Walker, C.A.

1999-08-26T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

ORIGINAL PAPER Tunability of Propane Conversion over Alumina Supported  

E-Print Network [OSTI]

ORIGINAL PAPER Tunability of Propane Conversion over Alumina Supported Pt and Rh Catalysts William Propane conversion over alumina supported Pt and Rh (1 wt% metals loading) was examined under fuel rich conversion and almost complete propane conversion) so long as the metal particle size was sufficiently low

82

Removal of impurities from dry scrubbed fluoride enriched alumina  

SciTech Connect (OSTI)

The pot-gas from an aluminum electrolytic cell is cleaned by a dry scrubbing process using fresh alumina as a scrubbing agent. This alumina is enriched with fluorides and trace impurities in a closed loop system with the pots. The only significant removal of the impurities is due to metal tapping. An improved technique has been developed that is more effective than earlier stripper systems. The impurity-rich fine fraction (< 10 {micro}m) of the enriched alumina is partly attached to the coarser alumina. That attachment has to be broken. Selective impact milling under special moderate conditions and air classifying have shown to be a cost effective process for the removal of impurities. For iron (Fe) and phosphorus (P) about 30--70% can be removed by the separation of 0.5--1% of the alumina. Full scale tests have successfully confirmed these results.

Schuh, L. [ABB Corporate Research Center, Heidelberg (Germany); Wedde, G. [ABB Environmental, Oslo (Norway)

1996-10-01T23:59:59.000Z

83

Combination for electrolytic reduction of alumina  

DOE Patents [OSTI]

An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises molten electrolyte having the following ingredients: AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound is, a fluoride; oxide, or carbonate. The metal is nickel, iron, copper, cobalt, or molybdenum. The bath is employed in a combination including a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the instant bath during electrolytic reduction of alumina to aluminum improves the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode.

Brown, Craig W. (Seattle, WA); Brooks, Richard J. (Seattle, WA); Frizzle, Patrick B. (Lynnwood, WA); Juric, Drago D. (Bulleen, AU)

2002-04-30T23:59:59.000Z

84

The effects of lime and amines on the aging of asphalts and recycling agents  

E-Print Network [OSTI]

amounts of quick lime (CaO) and hydrated lime (Ca(OH),) on SHRP AAA-I and SHRP AAF-1. The second experiment was to determine the effects of three different amines and various amounts of CaO on aged SHRP AAA-I and SHRP AAF-I rejuvenated with ABM-F2, YBF-F2...

Wisneski, Mary Luvola

2012-06-07T23:59:59.000Z

85

Effective Thermal Conductivity of Soda-Lime Silicate Glassmelts with Different Iron Contents Between 1100C and 1500C  

E-Print Network [OSTI]

Effective Thermal Conductivity of Soda-Lime Silicate Glassmelts with Different Iron Contents collected for soda- lime silicate glasses with iron content ranging from 0.008 to 1.1 wt% and temperatures, refractory walls wear more rapidly for clear glassmelts compared with colored ones.1 Soda-lime silicate glass

Pilon, Laurent

86

Fracture simulation for zirconia toughened alumina microstructure  

E-Print Network [OSTI]

Purpose - The purpose of this paper is to describe finite element modelling for fracture and fatigue behaviour of zirconia toughened alumina microstructures. Design/methodology/approach - A two-dimensional finite element model is developed with an actual $Al{_2}O{_3}$ - 10 vol% $ZrO{_2}$ microstructure. A bilinear, time-independent cohesive zone law is implemented for describing fracture behaviour of grain boundaries. Simulation conditions are similar to those found at contact between a head and a cup of hip prosthesis. Residual stresses arisen from the mismatch of thermal coefficient between grains are determined. Then, effects of a micro-void and contact stress magnitude are investigated with models containing residual stresses. For the purpose of simulating fatigue behaviour, cyclic loadings are applied to the models. Findings - Results show that crack density is gradually increased with increasing magnitude of contact stress or number of fatigue cycles. It is also identified that a micro-void brings about...

Kim, Kyungmok; Forest, Bernard

2013-01-01T23:59:59.000Z

87

Optimized alumina coagulants for water treatment  

DOE Patents [OSTI]

Substitution of a single Ga-atom or single Ge-atom (GaAl.sub.12 and GeAl.sub.12 respectively) into the center of an aluminum Keggin polycation (Al.sub.13) produces an optimal water-treatment product for neutralization and coagulation of anionic contaminants in water. GaAl.sub.12 consistently shows .about.1 order of magnitude increase in pathogen reduction, compared to Al.sub.13. At a concentration of 2 ppm, GaAl.sub.12 performs equivalently to 40 ppm alum, removing .about.90% of the dissolved organic material. The substituted GaAl.sub.12 product also offers extended shelf-life and consistent performance. We also synthesized a related polyaluminum chloride compound made of pre-hydrolyzed dissolved alumina clusters of [GaO.sub.4Al.sub.12(OH).sub.24(H.sub.2O).sub.12].sup.7+.

Nyman, May D. (Albuquerque, NM); Stewart, Thomas A. (Albuquerque, NM)

2012-02-21T23:59:59.000Z

88

alumina nanoparticles composites: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Page Topic Index 1 Evaluation of Composite Alumina Nanoparticle and Nitrate Eutectic Materials for use in Concentrating Solar Power Plants Texas A&M University - TxSpace Summary:...

89

Experimental and Numerical Studies of Aluminum-Alumina Composites  

E-Print Network [OSTI]

The preliminary goal of this study is to determine the effects of processing conditions, compositions and microstructural morphologies of the constituents on the physical and thermo-mechanical properties of alumina (Al_2O_3) reinforced aluminum (Al...

Gudlur, Pradeep

2013-07-22T23:59:59.000Z

90

Carbon dioxide pressure swing adsorption process using modified alumina adsorbents  

DOE Patents [OSTI]

A pressure swing adsorption process for absorbing CO.sub.2 from a gaseous mixture containing CO.sub.2 comprising introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100.degree. C. and 500.degree. C. to adsorb CO.sub.2 to provide a CO.sub.2 laden alumina adsorbent and a CO.sub.2 depleted gaseous mixture and contacting the CO.sub.2 laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO.sub.2 from the CO.sub.2 laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100.degree. C. and 600.degree. C., is not degraded by high concentrations of water under process operating conditions.

Gaffney, Thomas Richard (Allentown, PA); Golden, Timothy Christopher (Allentown, PA); Mayorga, Steven Gerard (Allentown, PA); Brzozowski, Jeffrey Richard (Bethlehem, PA); Taylor, Fred William (Allentown, PA)

1999-01-01T23:59:59.000Z

91

Carbon dioxide pressure swing adsorption process using modified alumina adsorbents  

DOE Patents [OSTI]

A pressure swing adsorption process for absorbing CO[sub 2] from a gaseous mixture containing CO[sub 2] comprises introducing the gaseous mixture at a first pressure into a reactor containing a modified alumina adsorbent maintained at a temperature ranging from 100 C and 500 C to adsorb CO[sub 2] to provide a CO[sub 2] laden alumina adsorbent and a CO[sub 2] depleted gaseous mixture and contacting the CO[sub 2] laden adsorbent with a weakly adsorbing purge fluid at a second pressure which is lower than the first pressure to desorb CO[sub 2] from the CO[sub 2] laden alumina adsorbent. The modified alumina adsorbent which is formed by depositing a solution having a pH of 3.0 or more onto alumina and heating the alumina to a temperature ranging from 100 C and 600 C, is not degraded by high concentrations of water under process operating conditions. 1 fig.

Gaffney, T.R.; Golden, T.C.; Mayorga, S.G.; Brzozowski, J.R.; Taylor, F.W.

1999-06-29T23:59:59.000Z

92

Wetting and strength issues at Al/alpha-alumina interfaces  

SciTech Connect (OSTI)

The wetting behavior and strength at aluminum/alumina interfaces has been an active subject of research. Al/alumina applications include ceramic-metal composites and several applications for electronic industries. In this paper the interface strength and microstructure of Al/alpha-alumina was investigated. We discovered that in a solid-state joining, the strength of the joint increases with increasing joining temperature. In a liquid-state joining, the strength of the joint gradually decreases due to the formation of unbonded areas. The strength, sigma sub b, is expressed by the following equation as a function of unbonded area, A: sigma sub b = 2.22 A + 143 (70 percent {le} A {le} 100 percent). The highest strength reached 400 MPa when the interface was formed at around the melting temperature of aluminum. An aluminum layer close to the interface became a single crystal when it was bonded to a sapphire. The following crystallographic orientation relationship is established: (1{bar 1}1){sub Al}//(001){sub {alpha}}-Al{sub 2} O{sub 3}, (110){sub Al}//<100>{sub {alpha}}-Al{sub 2}O{sub 3}. Amorphous alumina islands were formed at the interface. In the amorphous alumina, gamma-alumina nanocrystals grew from the sapphire, with the same orientation relationship to sapphire as above.

Saiz, Eduardo; Tomsia, Antoni P.; Suganuma, Katsuaki

2003-04-15T23:59:59.000Z

93

In What Form is Lime Present in Portland Cement  

E-Print Network [OSTI]

to obtain Si02.33a0, In his conclusions Hebuffat does not consider it of importance whether alit consists of pure Si02.3CaO or a crystalline compound of Si02.2CaO with 3a0 and an aluminate. He says the aluminate in Portland dement can not be Al 203.30a..., Erd- meyer, Nev/berry's, Zulkowski, Rebuff at, Meyers, Richardson, Michaelis and Meade d. Work of the Carbegie Institute of Washington on CaO #Si0 2 series and binary compounds of Al 23> Si0 2, MgO, CaO. On the presence of free lime in cement...

Wright, Claude W.

1910-01-01T23:59:59.000Z

94

Cast alumina forming austenitic stainless steels  

DOE Patents [OSTI]

An austenitic stainless steel alloy consisting essentially of, in terms of weight percent ranges 0.15-0.5C; 8-37Ni; 10-25Cr; 2.5-5Al; greater than 0.6, up to 2.5 total of at least one element selected from the group consisting of Nb and Ta; up to 3Mo; up to 3Co; up to 1W; up to 3Cu; up to 15Mn; up to 2Si; up to 0.15B; up to 0.05P; up to 1 total of at least one element selected from the group consisting of Y, La, Ce, Hf, and Zr; <0.3Ti+V; <0.03N; and, balance Fe, where the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale comprising alumina, and a stable essentially single phase FCC austenitic matrix microstructure, the austenitic matrix being essentially delta-ferrite free and essentially BCC-phase-free. A method of making austenitic stainless steel alloys is also disclosed.

Muralidharan, Govindarajan; Yamamoto, Yukinori; Brady, Michael P

2013-04-30T23:59:59.000Z

95

The effect of hydrated lime on Salmonella enteritidis survival in poultry litter and poult performance  

E-Print Network [OSTI]

The presence of Salmonella and/or Campylobacter in poultry litter may contribute to contaminated processed carcasses. Initially in our first study, we evaluated the effect of 5, 10, or 20% added lime on in vitro survival of Salmonella enteritidis...

Stanush, Deborah Denise

2000-01-01T23:59:59.000Z

96

Validation of the new mixture design and testing protocol for lime stabilization  

E-Print Network [OSTI]

and testing protocol is presented for lime stabilized subgrades. Comparison of field test data and laboratory test data shows that laboratory design test properties were achieved in the field. These properties are used in a mechanistic analysis to assess...

Yusuf, Fateh Ul Anam Muhammad Shafee

2001-01-01T23:59:59.000Z

97

Effects of alternate fuels report No. 8: analysis of degradiation of magnesia-based refractory bricks from a residual oil-fired rotary cement kiln  

SciTech Connect (OSTI)

Residual oil was used as an alternate fuel to natural gas to supply heat in a rotary cement kiln. Principal impurities in the residual oil were Ca, Fe, Mg, Na, Ni, P.S. and V. the kiln operators were concerned about the effects of these oil impurities on observed degradation of the magnesia-based bricks used as a liner in the burning zone of the kiln. Two degraded bricks, which had been in service for six to nine months, were analyzed to determine the role of fuel impurities on the observed degradation. The maximum hot-face temperature of the refractory during service was about 1500/sup 0/C. One brick had decreased in thickness about 45%, the about 15%. Various analytical measurements on these samples failed to reveal the presence of fuel impurities at or near the hot face of the bricks, and therefore it is concluded that the relatively short service life of these refractories was not due to use of residual oil as the fuel in the kiln. The observed degradation, therefore, was attributed to other reactions and to thermal mechanical conditions in the kiln, which inevitably resulted in extensive erosion of the bricks.

Federer, J.I.; Tennery, V.J.

1980-05-01T23:59:59.000Z

98

Legume establishment, nodulation, and forage production as influenced by N, P, K fertilizers and lime  

E-Print Network [OSTI]

LEGUME ESTABLISHMEJ'JT, NODL'LATION, AND FORAGE PRODUCTION AS INFLUE. 'JCZD BY N, P, K FERTILIZERS AND LIME A thesis by EDUARDO ENRIQUZ MARTII, 0 CHA EIJ Submitted to the Graduate College of Texas ASM University in partial fulfillment... of the requirement for tne degree of MASTER OF SCIENCE December 1983 Major Subject: Agronomy LEGUME ESTABLISHMENT, NODULATION, AND FORAGE PRODUCTION AS INFLUENCED BY N, P, K FERTILIZERS AND LIME A thesis EDUARDO ENRIQUE MARTILLO CHALEN Approved as to style...

Martillo Chalen, Eduardo Enrique

1983-01-01T23:59:59.000Z

99

Evaluation of lime-fly ash stabilized bases and subgrades using static and dynamic deflection systems  

E-Print Network [OSTI]

EVALUATION OF LIME-FLY ASH STABILIZED BASFS AND SUBGRADES USING STATIC AND DYNAMIC DEFLECTION SYSTEMS A Thesis GARY W. RABA Submitted to the Graduate College of Texas AIIM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE December 1982 Major Subject: Civil Engineering EVALUATION OF LIME-FLY ASH STABILIZED BASES AND SUBGRADES USING STATIC AND DYNAMIC DEFLECTION SYSTEMS A Thesis by Gary Nl. Raba Approved as to style and content by: !Chairman...

Raba, Gary W.

1982-01-01T23:59:59.000Z

100

An introduction to LIME 1.0 and its use in coupling codes for multiphysics simulations.  

SciTech Connect (OSTI)

LIME is a small software package for creating multiphysics simulation codes. The name was formed as an acronym denoting 'Lightweight Integrating Multiphysics Environment for coupling codes.' LIME is intended to be especially useful when separate computer codes (which may be written in any standard computer language) already exist to solve different parts of a multiphysics problem. LIME provides the key high-level software (written in C++), a well defined approach (with example templates), and interface requirements to enable the assembly of multiple physics codes into a single coupled-multiphysics simulation code. In this report we introduce important software design characteristics of LIME, describe key components of a typical multiphysics application that might be created using LIME, and provide basic examples of its use - including the customized software that must be written by a user. We also describe the types of modifications that may be needed to individual physics codes in order for them to be incorporated into a LIME-based multiphysics application.

Belcourt, Noel; Pawlowski, Roger Patrick; Schmidt, Rodney Cannon; Hooper, Russell Warren

2011-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Peltier heats in cryolite melts with alumina  

SciTech Connect (OSTI)

The Seebeck coefficient was measured for cells with electrolytes of molten mixtures of sodium fluoride and aluminum fluoride saturated with alumina. The electrodes were either a pair of oxygen electrodes or a pair of aluminum electrodes. For the molar ratio NaF/AlF{sub 3} equal to 1.8, 1.2 and 1.0, the authors obtained the Seebeck coefficients {minus}1.80 mV K{sup {minus}1} at 971 C, {minus}1.63 mV K{sup {minus}1} at 813.6 C and {minus}0.583 mV K{sup {minus}1} at 758 C, respectively, for the oxygen electrodes. For the aluminum electrodes, the authors obtained the Seebeck coefficient {minus}1.23 mV K{sup {minus}1} at 962 C, for the molar ratio NaF/AlF{sub 3} equal to 1.8. The results suggest that there is a substantial reversible heat consumption at the anode during aluminum electrolysis and a large reversible heat production at the cathode. The highest temperature in the Hall-Heroult cell is then closer to the cathode than the anode. The transported entropies of Al{sup 3+} and O{sup 2{minus}} were calculated to be 77 J mol{sup {minus}1} K{sup {minus}1} and 10 J mol{sup {minus}1} K{sup {minus}1}, respectively, when the molar ratio NaF/AlF{sub 3} was equal to 1.0.

Flem, B.E.; Ratkje, S.K.; Sterten, A. [Univ. of Trondheim (Norway)

1996-10-01T23:59:59.000Z

102

E-Print Network 3.0 - alumina nanosize powders Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the specific surface area of alumina by seeding of the alumina particles and... aerogels.1-4 On the other hand, there is a great deal of interest in the preparation of...

103

E-Print Network 3.0 - alumina core fabricated Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

14 (2004) 681686 PII: S0960-1317(04)71691-5 Summary: for silica, alumina, and titania aerogels. Silica and alumina aerogel cantilevers are fabricated on the basis... aerogel thin...

104

SO2-induced stability of Ag-alumina catalysts in the SCR of NO...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SO2-induced stability of Ag-alumina catalysts in the SCR of NO with methane. SO2-induced stability of Ag-alumina catalysts in the SCR of NO with methane. Abstract: We report on a...

105

E-Print Network 3.0 - alumina Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

photolithography... , etching, and structure releasing. EXPERIMENTAL PROCEDURE Aerogel preparation Mesoporous silica and alumina Source: Kim, Chang-Jin "CJ" - Department...

106

E-Print Network 3.0 - alumina vliyanie ionnogo Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

photolithography... , etching, and structure releasing. EXPERIMENTAL PROCEDURE Aerogel preparation Mesoporous silica and alumina Source: Kim, Chang-Jin "CJ" - Department...

107

Hydrogen removal from e-beam deposited alumina thin films by oxygen ion beam  

SciTech Connect (OSTI)

Hydrogen interstitials and oxygen vacancies defects create energy levels in the band gap of alumina. This limits the application of alumina as a high-k dielectric. A low thermal budget method for removal of hydrogen from alumina is discussed. It is shown that bombardment of alumina films with low energy oxygen ion beam during electron beam evaporation deposition decreases the hydrogen concentration in the film significantly.

Das, Arijeet, E-mail: arijeet@rrcat.gov.in; Mukharjee, C., E-mail: arijeet@rrcat.gov.in; Rajiv, K., E-mail: arijeet@rrcat.gov.in; Bose, Aniruddha, E-mail: arijeet@rrcat.gov.in; Singh, S. D., E-mail: arijeet@rrcat.gov.in; Rai, S. K.; Ganguli, Tapas; Joshi, S. C.; Deb, S. K. [Raja Ramanna Centre for Advanced Technology, Indore-452013 (India); Phase, D. M. [UGC-DAE Consortium for Scientific Research, Indore-452017 (India)

2014-04-24T23:59:59.000Z

108

Characterization of boria-alumina mixed oxides prepared by a sol-gel method.  

E-Print Network [OSTI]

for hydrotreating catalysts 32-53 . Nevertheless, the structure of the boria-alumina system with high specific

Boyer, Edmond

109

Alumina-forming Austenitic Alloys for Advanced Recuperators  

SciTech Connect (OSTI)

Materials selection for thin-walled recuperators has been extensively investigated over the past decade. In the latest generation of recuperated turbine engines, type 347 stainless steel has been replaced by higher alloyed steels and Ni-base chromia-forming alloys. However, high (linear) rates of chromia evaporation in exhaust gas fundamentally limits the oxidation lifetime of these chromia-forming alloys. One solution is to use alumina-forming alloys that are more resistant to this environment. The lower scale growth kinetics and resistance to evaporation in the presence of water vapor suggests an order of magnitude increase in lifetime for alumina-forming alloys. A significant problem with this strategy was the large drop in creep strength with the addition of sufficient Al to form an external alumina scale. However, new Fe-base austenitic compositions have been developed with sufficient strength for this application above 700 C.

Pint, Bruce A [ORNL; Shingledecker, John P [ORNL; Brady, Michael P [ORNL; Maziasz, Philip J [ORNL

2007-01-01T23:59:59.000Z

110

Factors contributing to the breakdown of sodium beta-alumina  

SciTech Connect (OSTI)

Clarification of the breakdown process occurring during charge transfer in sodium beta alumina solid electrolytes was derived from: (1) studying the effects of molten sodium contact at 350/sup 0/C on single crystal sodium beta alumina and polycrystalline sodium beta alumina; (2) determination of critical current density by monitoring acoustic emissions accompanying crack growth in sodium/sodium beta alumina/sodium cells subjected to linear current ramping at 1 mA cm/sup -2/ sec/sup -1/; (3) failure analysis conducted on cycled electrolytes, some from commercial sodium/sulfur cells, which had been subjected to up to 703 Ahr cm/sup -2/ of charge transfer. Gray coloration developing in beta aluminas in contact with molten sodium was found to be a consequence of formation, through reduction by sodium, of oxygen vacancies charge compensated by electrons. Electronic conductivity of the electrolyte increases as a result. No second phase formation was detected. Colored electrolytes from sodium/sulfur cells show evidence of a newly recognized degradation mechanism in which fracture occurs when sodium is reduced and deposited internally under pressure as metal in regions where an electronic conductivity gradient exists. Heating colored beta aluminas in air produces reoxidation and bleaching. Kinetics and other properties of the coloration and bleaching processes were determined. Critical current density was found to bear an inverse relation to average electrolyte grain size. Evidence was found in the cycled electrolytes for a slow crack growth mechanism and a progressive mode of degradation advancing from the sulfur electrode interface. Implications of the findings for the construction and operation of sodium/sulfur battery systems are discussed.

Buechele, A.C.

1982-05-01T23:59:59.000Z

111

Atomistic force field for alumina fit to density functional theory  

SciTech Connect (OSTI)

We present a force field for bulk alumina (Al{sub 2}O{sub 3}), which has been parametrized by fitting the energies, forces, and stresses of a large database of reference configurations to those calculated with density functional theory (DFT). We use a functional form that is simpler and computationally more efficient than some existing models of alumina parametrized by a similar technique. Nevertheless, we demonstrate an accuracy of our potential that is comparable to those existing models and to DFT. We present calculations of crystal structures and energies, elastic constants, phonon spectra, thermal expansion, and point defect formation energies.

Sarsam, Joanne [Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom) [Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom); Thomas Young Centre, Imperial College London, London SW7 2AZ (United Kingdom); Finnis, Michael W.; Tangney, Paul, E-mail: p.tangney@imperial.ac.uk [Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom) [Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom); Thomas Young Centre, Imperial College London, London SW7 2AZ (United Kingdom); Department of Physics, Imperial College London, London SW7 2AZ (United Kingdom)

2013-11-28T23:59:59.000Z

112

Advanced mineral calciner for regeneration of lime. Final report, March 1995--May 1997  

SciTech Connect (OSTI)

There are approximately 800 pulp, paper and paperboard mills in the United States. Pulp and paper is the ninth largest industry in US, uses 2.8 quads of energy per year and ranks third among all domestic US industries in the cost of energy consumed. A significant fraction of the energy consumed in pulp and paper plants is needed to recover chemicals that are used in breaking down the wood chips into pulp. In particular, 0.1 quads of energy per year are used to regenerate lime. Furthermore, pulp and paper plant operations generate 9,870 tons of NOx per year. Additionally over two million tons of spent lime are sent to landfills each year. In addition, growth in paper demand and changes in plant processes (e.g., bleaching), as a result of environmental pressures, will continue to drive the need for more lime regeneration capacity. Unless the increased capacity can be delivered productively and inexpensively, the growth in pulp and paper may occur in overseas markets. Furthermore, if new environmental constraints cannot be met at low cost, existing US pulp and paper production capacity may also move off-shore. The advanced mineral calciner (AMC) technology was developed to address this lime regeneration need. Prior to describing the technology, and the program of work that was used to test the concept, conventional lime regeneration systems and their limitations are described.

Namazian, M.; Nickeson, R.; Lovas, B.; Miller, G.; Kelly, J.

1997-12-31T23:59:59.000Z

113

Combustion of high-sulfur coal and anthracite wastes in a rotary kiln combustor with an advanced internal air distributor  

SciTech Connect (OSTI)

Fluid bed combustors have received extensive testing with both high-sulfur coal and anthracite wastes. Rotary kilns are effective and popular devices for waste combustion. The Angelo Rotary Furnace{trademark} has been developed to improve the operation of rotary pyrolyzer/combustor systems through enhanced air distribution, which in this process is defined as staged, swirled combustion air injection. Fourteen of these new furnaces have been installed worldwide. Two units in Thailand, designed for rice hull feed with occasional lignite feed, have been recently started up. An older unit in Pennsylvania is being upgraded with a new, more advanced air distribution system for a series of tests this fall in which inexpensive high-sulfur coal and anthracite wastes will be fired with limestone. The purposes of these tests are to determine the burning characteristics of these two fuels in this system, to discover the Ca/S ratios necessary for operation of a rotary kiln combusting these fuels, and to observe the gas-borne emissions from the furnace. An extensive preliminary design study will be performed on a commercial installation for combustion of anthracite wastes. 14 refs., 5 figs., 1 tab.

Cobb, J.T. Jr. (Pittsburgh Univ., PA (USA)); Ahn, Y.K. (Gilbert/Commonwealth, Inc., Reading, PA (USA)); Angelo, J.F. (Universal Energy International, Inc., Little Rock, AR (USA))

1990-01-01T23:59:59.000Z

114

alumina nuclear waste: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alumina nuclear waste First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Nuclear magnetic resonance-based...

115

Viscosity of alumina nanoparticles dispersed in car engine coolant  

SciTech Connect (OSTI)

The present paper, describes our experimental results on the viscosity of the nanofluid prepared by dispersing alumina nanoparticles (<50 nm) in commercial car coolant. The nanofluid prepared with calculated amount of oleic acid (surfactant) was tested to be stable for more than 80 days. The viscosity of the nanofluids is measured both as a function of alumina volume fraction and temperature between 10 and 50 C. While the pure base fluid display Newtonian behavior over the measured temperature, it transforms to a non-Newtonian fluid with addition of a small amount of alumina nanoparticles. Our results show that viscosity of the nanofluid increases with increasing nanoparticle concentration and decreases with increase in temperature. Most of the frequently used classical models severely under predict the measured viscosity. Volume fraction dependence of the nanofluid viscosity, however, is predicted fairly well on the basis of a recently reported theoretical model for nanofluids that takes into account the effect of Brownian motion of nanoparticles in the nanofluid. The temperature dependence of the viscosity of engine coolant based alumina nanofluids obeys the empirical correlation of the type: log ({mu}{sub nf}) = A exp(BT), proposed earlier by Namburu et al. (author)

Kole, Madhusree; Dey, T.K. [Thermophysical Measurements Laboratory, Cryogenic Engineering Centre, Indian Institute of Technology, Kharagpur 721 302 (India)

2010-09-15T23:59:59.000Z

116

Biocompatibility of atomic layer-deposited alumina thin films  

E-Print Network [OSTI]

. These results sug- gest that patterning a substrate with hydrophilic and hydro- phobic groups can control cell and excellent dielectric properties for bio- micro electro mechanical systems (Bio-MEMS) in sensors, actuators of atomic layer-deposited (ALD) alumina (Al2O3) and hydro- phobic coatings. While these coatings

George, Steven M.

117

alumina cement concrete: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Websites Summary: O, MgO, transient metal oxides as in Y2O3, Sc2O3, Er2O3 (Ref 1), rare-earths such as CeO, Yb2O3Phase Formation and Transformation in AluminaYSZ...

118

Reduction of NO{sub x} emissions from a dry process preheater kiln with calciner through the use of the urea-based SNCR process  

SciTech Connect (OSTI)

The post combustion reduction of NO{sub x} using urea has proven to be an effective method in controlling NO{sub x} from various combustion sources. Such a reduction process has been successfully demonstrated in a week-long test at Ash Grove`s dry process cement kiln system located in Seattle. This system is equipped with planetary coolers, a 5-stage preheater and an air-through-the-kiln calciner. Testing was done under ten different kiln/calciner operating conditions. Using three to four injectors, NO{sub x} was efficiently reduced from 350--600 lb per hour lb/ton of clinker to less than 100 lb per hour. This calculates to a NO{sub x} reduction of greater than 80% for most cases. Chemical utilization was greater than 50%. A high degree of mixing and a long residence time at an appropriate temperature present in the preheater tower contributed to these excellent results. An average ammonia slip was four ppm above a baseline level at a normalized stoichiometric ratio of 1. This demonstration confirms expectations that dry process cement kilns with 4+ preheater stages are an ideal application for the selective noncatalytic reduction of NO{sub x} with urea. NO{sub x} was efficiently and effectively reduced with minimal byproduct emissions and virtually no effect on plant operations.

Steuch, H.E. [Ash Grove Cement Co., Portland, OR (United States)] [Ash Grove Cement Co., Portland, OR (United States); Hille, J.T. [Ash Grove Cement Co., Seattle, WA (United States)] [Ash Grove Cement Co., Seattle, WA (United States); Sun, W.H. [Nalco Fuel Tech, Naperville, IL (United States)] [Nalco Fuel Tech, Naperville, IL (United States); Bisnett, M.J.; Kirk, D.W. [Nalco Fuel Tech, Santa Fe Springs, CA (United States)] [Nalco Fuel Tech, Santa Fe Springs, CA (United States)

1996-07-01T23:59:59.000Z

119

A reclamation approach for mined prime farmland by adding organic wastes and lime to the subsoil  

SciTech Connect (OSTI)

Surface mined prime farmland may be reclaimed by adding organic wastes and lime to subsoil thus improving conditions in root zone. In this study, sewage sludge, poultry manure, horse bedding, and lime were applied to subsoil (15-30 cm) during reclamation. Soil properties and plant growth were measured over two years. All organic amendments tended to lower the subsoil bulk density and increase organic matter and total nitrogen. Liming raised exchangeable calcium, slightly increased pH, but decreased exchangeable magnesium and potassium. Corn ear-leaf and forage tissue nitrogen, yields, and nitrogen removal increased in treatments amended with sewage sludge and poultry manure, but not horse bedding. Subsoil application of sewage sludge or poultry manure seems like a promising method in the reclamation of surface mined prime farmland based on the improvements observed in the root zone environment.

Zhai, Qiang; Barnhisel, R.I. [Univ. of Kentucky, Lexington, KY (United States)

1996-12-31T23:59:59.000Z

120

EFFECTS OF COMPOST AND LIME APPLICATION ON SOIL CHEMICAL PROPERTIES, SOIL MICROBIAL COMMUNITY, AND FUSARIUM WILT IN  

E-Print Network [OSTI]

1 EFFECTS OF COMPOST AND LIME APPLICATION ON SOIL CHEMICAL PROPERTIES, SOIL MICROBIAL COMMUNITY compost as an antagonistic suppression approach to combat soil-borne disease effects on crop yields the effect of compost and lime on soil chemical properties, the soil microbial community (including Fusarium

Ma, Lena

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

A theory manual for multi-physics code coupling in LIME.  

SciTech Connect (OSTI)

The Lightweight Integrating Multi-physics Environment (LIME) is a software package for creating multi-physics simulation codes. Its primary application space is when computer codes are currently available to solve different parts of a multi-physics problem and now need to be coupled with other such codes. In this report we define a common domain language for discussing multi-physics coupling and describe the basic theory associated with multiphysics coupling algorithms that are to be supported in LIME. We provide an assessment of coupling techniques for both steady-state and time dependent coupled systems. Example couplings are also demonstrated.

Belcourt, Noel; Bartlett, Roscoe Ainsworth; Pawlowski, Roger Patrick; Schmidt, Rodney Cannon; Hooper, Russell Warren

2011-03-01T23:59:59.000Z

122

Direct utilization - recovery of minerals from coal fly ash. Fossil Energy Program. Technical progress report, 1 July 1984-30 September 1984 including summary of work for FY84  

SciTech Connect (OSTI)

The research discussed in this report deals with resource recovery from coal conversion solid wastes. Progress is reported on two methods (the HiChlor and Lime-Sinter processes) for extracting metal values from power plant fly ash. Preliminary work is also reported on a method of making cement from the residue of the lime-sinter process. In the HiChlor Process, metal oxides in the fly ash are converted to volatile chlorides by reaction with chlorine in the presence of a reductant. Several versions of this approach are being investigated. The Lime-Sinter Process utilizes a solid state reaction to selectively convert the alumina in fly ash to a soluble form. Fly ash is mixed with limestone and a suitable mineralizer (to reduce the temperature required for sintering and to enhance alumina recovery) and then sintered in a high temperature kiln. Alumina is recovered by leaching the resulting clinker. A complex relationship between the calcium, alumina, silica, and sulfur constituents in the feed mixture controls the formation and extraction of aluminate compounds. Alumina recovery levels are enhanced by promoting the formation of less-soluble calcium compounds and/or more-soluble aluminum compounds. A study is underway to determine the degree to which flue gas scrubber sludge can be used both as a limestone substitute and as a sulfur bearing mineralizer. Results show that 20 to 25% of the limestone can be provided by the scrubber sludges. 25 refs.,25 figs., 10 tabs.

Burnet, G.; Murtha, M.J.; Benson, J.D.

1985-03-01T23:59:59.000Z

123

Melt processing of Bi--2212 superconductors using alumina  

DOE Patents [OSTI]

Superconducting articles and a method of forming them, where the superconducting phase of an article is Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.y (Bi-2212). Alumina is combined with Bi-2212 powder or Bi-2212 precursor powder and, in order to form an intimate mixture, the mixture is melted and rapidly cooled to form a glassy solid. The glassy solid is comminuted and the resulting powder is combined with a carrier. An alternative to melting is to form the mixture of nanophase alumina and material having a particle size of less than about 10 microns. The powder, with the carrier, is melt processed to form a superconducting article.

Holesinger, Terry G. (Los Alamos, NM)

1999-01-01T23:59:59.000Z

124

Protective coating for alumina-silicon carbide whisker composites  

DOE Patents [OSTI]

Ceramic composites formed of an alumina matrix reinforced with silicon carbide whiskers homogenously dispersed therein are provided with a protective coating for preventing fracture strength degradation of the composite by oxidation during exposure to high temperatures in oxygen-containing atmospheres. The coating prevents oxidation of the silicon carbide whiskers within the matrix by sealing off the exterior of the matrix so as to prevent oxygen transport into the interior of the matrix. The coating is formed of mullite or mullite plus silicon oxide and alumina and is formed in place by heating the composite in air to a temperature greater than 1200.degree. C. This coating is less than about 100 microns thick and adequately protects the underlying composite from fracture strength degradation due to oxidation.

Tiegs, Terry N. (Lenoir City, TN)

1989-01-01T23:59:59.000Z

125

High vacuum indirectly-heated rotary kiln for the removal and recovery of mercury from air pollution control scrubber waste  

SciTech Connect (OSTI)

SepraDyne corporation (Denton, TX, US) has conducted pilot-scale treatability studies of dewatered acid plant blowdown sludge generated by a copper smelter using its recently patented high temperature and high vacuum indirectly-heated rotary retort technology. This unique rotary kiln is capable of operating at internal temperatures up to 850 C with an internal pressure of 50 torr and eliminates the use of sweep gas to transport volatile substances out of the retort. By removing non-condensables such as oxygen and nitrogen at relatively low temperatures and coupling the process with a temperature ramp-up program and low temperature condensation, virtually all of the retort off-gases produced during processing can be condensed for recovery. The combination of rotation, heat and vacuum produce the ideal environment for the rapid volatilization of virtually all organic compounds, water and low-to-moderate boiling point metals such as arsenic, cadmium and mercury.

Hawk, G.G.; Aulbaugh, R.A. [Scientific Consulting Labs., Inc., Farmers Branch, TX (United States)] [Scientific Consulting Labs., Inc., Farmers Branch, TX (United States)

1998-12-31T23:59:59.000Z

126

Directional solidification of the alumina-zirconia ceramic eutectic system  

SciTech Connect (OSTI)

It is possible to produce alumina-zirconia ceramic samples through existing solidification techniques. The resulting microstructures typically consist of rods of zirconia in an alumina matrix, although a lamellar structure has been noted in some cases. In nearly all cases, colony growth was present which may possibly result from grain size, repeated nucleation events, and lamellar oscillations. In the same vein, it appears that the amount of impurities within the system might be the underlying cause for the colony growth. Colony growth was diminished through impurity control as the higher purity samples exhibited colony free behavior. In addition to colony formations, faceted alumina dendrites or nonfaceted zirconia dendrites may result in the ceramic if the sample is solidified out of the coupled zone. In all cases, for larger-sized Bridgman samples, a lower limit in the eutectic spacing was noted. The solidification model which includes the kinetic effect has been developed, although the effect appears to be negligible under present experimental conditions. A spacing limit might also occur due to the result of heat flow problems. Heat flow out of the ceramic is difficult to control, often causing radial and not axial growth. This behavior is exaggerated in the presence of impurities. Thus, higher purity powders should always be used. Higher purity samples, in addition to yielding a more microstructurally uniform ceramic, also showed increased directionality. In the future, the kinetic model needs to be examined in more detail, and further research needs to be accomplished in the area of molten ceramics. Once better system constants are in place, the kinetic model will give a better indication of the behavior in the alumina-zirconia system.

Boldt, C.

1994-07-27T23:59:59.000Z

127

Organic removal from domestic wastewater by activated alumina adsorption  

E-Print Network [OSTI]

of the major groups of pollutants in wastewaters. Adsorption by granular activated carbon, a non-polar adsorbent, is now the primary treatment process for removal of residual organics from biologically treated wastewater. The ability of activated alumina... to human health if they exist in the water supply at relatively high concentrations. A wide variety of treatment processes are available to remove organic matter from wastewater. Biological treatment is the most cost effective method for removing oxygen...

Yang, Pe-Der

1982-01-01T23:59:59.000Z

128

Performance of lime-treated silty soil under long-term hydraulic conditions B. Le Runigoa  

E-Print Network [OSTI]

to a significant decrease in shear strength. The results also indicated that the mechanical performance of soils calcium aluminates (C-S-H and C-A-H) can be formed. As a result, an improvement in the soil mechanical1 Performance of lime-treated silty soil under long-term hydraulic conditions B. Le Runigoa , V

Paris-Sud XI, Université de

129

Predicting Classes in Need of Refactoring: An Application of Static Metrics Liming Zhao Jane Huffman Hayes  

E-Print Network [OSTI]

. In general, the following process is followed by a software team performing refactoring: Identify code1 Predicting Classes in Need of Refactoring: An Application of Static Metrics Liming Zhao Jane to predicting refactoring candidates. Using a selected set of static metrics and a weighted ranking method

Hayes, Jane E.

130

E-Print Network 3.0 - alumina physically loaded Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

constant in RF devices. Some unique features of thin-film silica and alumina aerogels have been... studied including physical properties, etching characteristics, and...

131

agglomerate-free alumina slurry: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Yuwen 168 Chemical Preparation of the Binary Compounds in the CalciaAlumina System by Self-Propagating Combustion Synthesis Materials Science Websites Summary: Chemical...

132

E-Print Network 3.0 - alumina inlay failure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Robert O. - Lawrence Berkeley National Laboratory Collection: Materials Science 4 Fracture and Fatigue Behavior at Ambient and Elevated Temperatures of Alumina Bonded with...

133

E-Print Network 3.0 - alkalized alumina process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nanosized second phases or by using a new sintering process... to increase the fracture tough- ness of alumina. Sol-gel ... Source: Hong, Soon Hyung - Department of...

134

E-Print Network 3.0 - aluminas zirconias joints Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

aux joints entre les regions cohkrentes. Cela... will be selected principally from rock salt, fluorite, perovskite and beta alumina type structures that have been... structures...

135

Method to produce alumina aerogels having porosities greater than 80 percent  

DOE Patents [OSTI]

A two-step method for producing monolithic alumina aerogels having porosities of greater than 80 percent. Very strong, very low density alumina aerogel monoliths are prepared using the two-step sol-gel process. The method of preparing pure alumina aerogel modifies the prior known sol method by combining the use of substoichiometric water for hydrolysis, the use of acetic acid to control hydrolysis/condensation, and high temperature supercritical drying, all of which contribute to the formation of a polycrystalline aerogel microstructure. This structure provides exceptional mechanical properties of the alumina aerogel, as well as enhanced thermal resistance and high temperature stability.

Poco, John F.; Hrubesh, Lawrence W.

2003-09-16T23:59:59.000Z

136

A comparison of alumina, carbon, and carbon-covered alumina as supports for Ni-Mo-F additives: Carbon deposition and model compound reaction studies  

SciTech Connect (OSTI)

Fluoride-promoted Ni-Mo catalysts supported on alumina, carbon, and carbon-coveres alumina have been investigated for their activity in cumene cracking, hydrocracking (reduced and sulfided forms), and thiophene HDS. The carbon-covered alumina was prepared by pyrolysis of cyclohexene over either {gamma}-alumina or boehmite and the carbon deposition followed adsorption isotherm-type behavior. The cumene reaction studies indicate that the resulting support system successfully merges the properties of carbon and alumina, possessing improved dehydrogenation-hydrogenation functionality due to carbon and acidic properties due to alumina, such as the generation of Broensted acidity upon fluoride impregnation. In the thiophene HDS reaction the catalyst activities followed the order Al{sub 2} > C-Al{sub 2}O{sub 3} > C, suggesting that alumina, and not carbon, is the superior HDS support at atmospheric H{sub 2} pressure and at the metal loadings used in this study. Carbon deposition onto Ni-Mo-F/Al{sub 2}O{sub 3} catalysts revealed that cyclohexene polymerization is promoted by the metal centers, resulting in multilayer islands on these sites, and not by the fluoride-associated Broensted acid sites. However, the Broensted acid sites do promote coke formation when the polymerization reaction is easier such as for {alpha}-methylstyrene.

Boorman, P.M.; Chong, K.; Kydd, R.A.; Lewis, J.M. (Univ. of Calgary, Alberta (Canada))

1991-04-01T23:59:59.000Z

137

Viscosity of aqueous and cyanate ester suspensions containing alumina nanoparticles  

SciTech Connect (OSTI)

The viscosities of both aqueous and cyanate ester monomer (BECy) based suspensions of alumina nanoparticle were studied. The applications for these suspensions are different: aqueous suspensions of alumina nanoparticles are used in the production of technical ceramics made by slip casting or tape casting, and the BECy based suspensions are being developed for use in an injection-type composite repair resin. In the case of aqueous suspensions, it is advantageous to achieve a high solids content with low viscosity in order to produce a high quality product. The addition of a dispersant is useful so that higher solids content suspensions can be used with lower viscosities. For BECy suspensions, the addition of nanoparticles to the BECy resin is expected to enhance the mechanical properties of the cured composite. The addition of saccharides to aqueous suspensions leads to viscosity reduction. Through DSC measurements it was found that the saccharide molecules formed a solution with water and this resulted in lowering the melting temperature of the free water according to classic freezing point depression. Saccharides also lowered the melting temperature of the bound water, but this followed a different rule. The shear thinning and melting behaviors of the suspensions were used to develop a model based on fractal-type agglomeration. It is believed that the structure of the particle flocs in these suspensions changes with the addition of saccharides which leads to the resultant viscosity decrease. The viscosity of the BECy suspensions increased with solids content, and the viscosity increase was greater than predicted by the classical Einstein equation for dilute suspensions. Instead, the Mooney equation fits the viscosity behavior well from 0-20 vol% solids. The viscosity reduction achieved at high particle loadings by the addition of benzoic acid was also investigated by NMR. It appears that the benzoic acid interacts with the surface of the alumina particle which may be the cause of the viscosity reduction. The flow behavior of alumina particles in water and BECy is markedly different. Aqueous alumina suspensions are shear thinning at all alumina loadings and capable of 50 vol% loading before losing fluidity whereas BECy/alumina suspensions show Newtonian behavior up to 5 vol%, and above 5 vol% show shear thinning at all shear rates. Highly loaded suspensions (i.e. 20vol% alumina) exhibit shear thinning at low and moderate shear rates and shear thickening at higher shear rates. The maximum particle loading for a fluid suspension, in this case, appears to be about 20 vol%. The difference in the viscosity of these suspensions must be related to the solvent-particle interactions for each system. The reason is not exactly known, but there are some notable differences between BECy and water. Water molecules are {approx}0.28 nm in length and highly hydrogen bonded with a low viscosity (1 mPa's) whereas in the cyanate ester (BECy) system, the solvent molecule is about 1.2 nm, in the largest dimension, with surfaces of varied charge distribution throughout the molecule. The viscosity of the monomer is also reasonably low for organic polymer precursor, about 7 mPa's. Nanoparticles in water tend to agglomerate and form flocs which are broken with the shear force applied during viscosity measurement. The particle-particle interaction is very important in this system. In BECy, the particles appear to be well dispersed and not as interactive. The solvent-particle interaction appears to be most important. It is not known exactly how the alumina particles interact with the monomer, but NMR suggests hydrogen bonding. These hydrogen bonds between the particle and monomer could very well affect the viscosity. A conclusion that can be reached in this work is that the presence of hydroxyl groups on the surface of the alumina particles is significant and seems to affect the interactions between other particles and the solvent. Thus, the hydrogen bonding between particles, particle/additive and/or particle/solvent dictates the behavior of nanos

Lawler, Katherine

2009-08-05T23:59:59.000Z

138

Reduction of NO{sub x} emissions from cement kiln/calciner through the use of the NO{sub x}OUT process  

SciTech Connect (OSTI)

The post combustion reduction of NO{sub x} using urea has proven to be an effective method in controlling NO{sub x} from various combustion sources. This process, a selective non-catalytic reduction process known as NO{sub x}OUT, has been successfully demonstrated in a cement kiln/calciner operated by Ash Grove Cement. Testing was done under ten different kiln/calciner operating conditions. Using three to four injectors, NO{sub x} was efficiently reduced from 350--600 pounds per hour (3.5--6.0 lb/ton of clinker) to less than 100 pounds per hour (1.0 lb/ton of clinker). This calculates to a NO{sub x} reduction of > 80% for most cases. Chemical utilization was greater than 50%. A high degree of mixing and a long residence time at an appropriate temperature present in the preheater tower contributed to these excellent results. An average ammonia slip was four ppm above a baseline level at normalized stoichiometric ratio of 1. Based on this demonstration, cement kiln/calciners have been identified as an ideal application for the NO{sub x}OUT Process. NO{sub x} was efficiently and effectively reduced with minimal byproduct emissions and virtually no effect on plant operations.

Sun, W.H. [Nalco Fuel Tech., Naperville, IL (United States); Bisnett, M.J.; Kirk, D.W. [Nalco Fuel Tech, Santa Fe Springs, CA (United States); Steuch, H.E. [Ash Grove Cement Co., Portland, OR (United States); Hille, J. [Ash Grove Cement Co., Seattle, WA (United States)

1994-12-31T23:59:59.000Z

139

Stresses in thermally grown alumina scales near edges and corners.  

SciTech Connect (OSTI)

We have investigated the residual stress near edges and corners of thermally grown alumina scales. Micro-fluorescence measurements, performed on alloys with composition Fe-5Cr-28Al (at.%, bal. Fe) oxidized at 900 C, showed a large (>50%) reduction in hydrostatic stress in the vicinity of edges and corners. Surprisingly, stress relaxation persists out to distances ten times the scale thickness from the edge. Finite element analysis calculations confirm the experimental results and provide a considerably more detailed picture of the stress distribution and its components.

Grimsditch, M.

1998-06-03T23:59:59.000Z

140

Silicon carbide whisker-zirconia reinforced mullite and alumina ceramics  

DOE Patents [OSTI]

The flexural strength and/or fracture toughness of SiC whisker-reinforced composites utilizing mullite or alumina as the matrix material for the composite are increased by the addition of zirconia in a monoclinic or tetragonal phase to the matrix. The zirconia addition also provides for a lower hot-pressing temperature and increases the flexural strength and/or fracture toughness of the SiC whisker-reinforced composites over SiC whisker-reinforced composites of the similar matrix materials reinforced with similar concentrations of SiC whiskers.

Becher, Paul F. (Oak Ridge, TN); Tiegs, Terry N. (Lenoir City, TN)

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Method for thermal processing alumina-enriched spinel single crystals  

DOE Patents [OSTI]

A process for age-hardening alumina-rich magnesium aluminum spinel to obtain the desired combination of characteristics of hardness, clarity, flexural strength and toughness comprises selection of the time-temperature pair for isothermal heating followed by quenching. The time-temperature pair is selected from the region wherein the precipitate groups have the characteristics sought. The single crystal spinel is isothermally heated and will, if heated long enough pass from its single phase through two pre-precipitates and two metastable precipitates to a stable secondary phase precipitate within the spinel matrix. Quenching is done slowly at first to avoid thermal shock, then rapidly.

Jantzen, Carol M. (Aiken, SC)

1995-01-01T23:59:59.000Z

142

Method for thermal processing alumina-enriched spinel single crystals  

DOE Patents [OSTI]

A process for age-hardening alumina-rich magnesium aluminum spinel to obtain the desired combination of characteristics of hardness, clarity, flexural strength and toughness comprises selection of the time-temperature pair for isothermal heating followed by quenching. The time-temperature pair is selected from the region wherein the precipitate groups have the characteristics sought. The single crystal spinel is isothermally heated and will, if heated long enough pass from its single phase through two pre-precipitates and two metastable precipitates to a stable secondary phase precipitate within the spinel matrix. Quenching is done slowly at first to avoid thermal shock, then rapidly. 12 figs.

Jantzen, C.M.

1995-05-09T23:59:59.000Z

143

The ultra-high lime with aluminum process for removing chloride from recirculating cooling water  

E-Print Network [OSTI]

THE ULTRA-HIGH LIME WITH ALUMINUM PROCESS FOR REMOVING CHLORIDE FROM RECIRCULATING COOLING WATER A Dissertation by AHMED IBRAHEEM ALI ABDEL-WAHAB Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...-WAHAB Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved as to style and content by: Bill Batchelor (Chair of Committee) Robin L. Autenrieth (Member...

Abdel-wahab, Ahmed Ibraheem Ali

2004-09-30T23:59:59.000Z

144

Liming effects on slash pine (Pinus elliottii Englm.) seedlings growing on acid soils  

E-Print Network [OSTI]

Growth Liming CHAPTER III. NETHODS Experimental Design Soil Treatments Greenhouse Care Laboratory Analysis Statistical Analysis . CHAPTER IV. RESULTS . Soils Exchangeable Aluminum Extractable Aluminum Exchangeable Acidity pH Calcium Page 1... growth; and under very acid conditions, phosphorus may be tied up with soluble aluminum (Shoulders and McKee, 1973). Solubility of aluminum is strongly influenced by pH and may interfere with the uptake of phosphorus and subsequent growth of southern...

Elzner, John Thomas

1978-01-01T23:59:59.000Z

145

Final report on DSA methods for monitoring alumina in aluminum reduction cells with cermet anodes  

SciTech Connect (OSTI)

The Sensors Development Program was conducted at the Pacific Northwest Laboratory (PNL) for the US Department of Energy, Office of Industrial Processes. The work was performed in conjunction with the Inert Electrodes Program at PNL. The objective of the Sensors Development Program in FY 1990 through FY 1992 was to determine whether methods based on digital signal analysis (DSA) could be used to measure alumina concentration in aluminum reduction cells. Specifically, this work was performed to determine whether useful correlations exist between alumina concentration and various DSA-derived quantification parameters, calculated for current and voltage signals from laboratory and field aluminum reduction cells. If appropriate correlations could be found, then the quantification parameters might be used to monitor and, consequently, help control the alumina concentration in commercial reduction cells. The control of alumina concentration is especially important for cermet anodes, which have exhibited instability and excessive wear at alumina concentrations removed from saturation.

Windisch, C.F. Jr.

1992-04-01T23:59:59.000Z

146

Microwave sintering of pure and doped nanocrystalline alumina compacts  

SciTech Connect (OSTI)

A single-mode cavity microwave furnace, operating in the TE{sub 103} mode at 2.45 GHz is being used to investigate sintering of pure and doped nanocrystalline alumina. The purpose of these experiments is to determine the effect of additives on the sintering process in the nanocrystalline regime. Using the sol-gel method, high purity Al{sub 2}O{sub 3} nanocrystalline powders were synthesized. These powders were calcined at 700 C and then CIP`ed to 414 MPa, producing 0.4 in. diameter, 0.25 in. high cylindrical compacts. The compacts were heated in the microwave furnace to temperatures between 1,100 C to approximately 1,800 C and were then brought back to room temperature using a triangular heating profile of about 30 minutes duration. A two-color IR pyrometer was used to monitor the surface temperature of the workpiece. The additives tested in this work lowered the temperature needed for densification but this effect was offset by increased grain growth. Initial grain growth from <5 nm to {approximately}50 nm was closely correlated with the {gamma} to {alpha}-alumina phase transition.

Bruce, R.W. [SFA, Inc., Largo, MD (United States); Fliflet, A.W.; Lewis, D. III; Rayne, R.J.; Bender, B.A.; Chow, G.M.; Schoen, P.E. [Naval Research Lab., Washington, DC (United States); Kurihara, L.K. [Georgetown Univ., Washington, DC (United States). Dept. of Biochemistry

1996-12-31T23:59:59.000Z

147

Bath for electrolytic reduction of alumina and method therefor  

DOE Patents [OSTI]

An electrolytic bath for use during the electrolytic reduction of alumina to aluminum. The bath comprises a molten electrolyte having the following ingredients: (a) AlF.sub.3 and at least one salt selected from the group consisting of NaF, KF, and LiF; and (b) about 0.004 wt. % to about 0.2 wt. %, based on total weight of the molten electrolyte, of at least one transition metal or at least one compound of the metal or both. The compound may be, for example, a fluoride, oxide, or carbonate. The metal can be nickel, iron, copper, cobalt, or molybdenum. The bath can be employed in a combination that includes a vessel for containing the bath and at least one non-consumable anode and at least one dimensionally stable cathode in the bath. Employing the bath of the present invention during electrolytic reduction of alumina to aluminum can improve the wetting of aluminum on a cathode by reducing or eliminating the formation of non-metallic deposits on the cathode. Removing sulfur from the bath can also minimize cathode deposits. Aluminum formed on the cathode can be removed directly from the cathode.

Brown, Craig W. (Seattle, WA); Brooks, Richard J. (Seattle, WA); Frizzle, Patrick B. (Lynnwood, WA); Juric, Drago D. (Bulleen, AU)

2002-11-26T23:59:59.000Z

148

Removal of hazardous anions from aqueous solutions by La(III)- and Y(III)-impregnated alumina  

SciTech Connect (OSTI)

New adsorbents, La(III)- and Y(III)-impregnated alumina, were prepared for the removal of hazardous anions from aqueous solutions. A commercially available alumina was impregnated with La(III) or Y(III) ions by the adsorption process. The change in the surface charge due to the impregnation was measured by acid/base titration. The adsorption rate and the capacity of the alumina for La(III) and Y(III) ions were determined. The adsorption characteristics of the La(III)- and Y(III)-impregnated alumina and the original alumina for fluoride, phosphate, arsenate and selenite ions were analyzed under various conditions. The pH effect, dose effect, and kinetics were studied. The removal selectivity by the impregnated alumina was in the order fluoride > phosphate > arsenate > selenite. The impregnated alumina has been successfully applied for the removal of hazardous anions from synthetic and high-tech industrial wastewaters.

Wasay, Syed Abdul; Tokunaga, Shuzo [National Inst. of Materials and Chemical Research, Ibaraka (Japan); Park, S.W. [Keimyung Univ., Daegu City (Korea, Democratic People`s Republic of)

1996-06-01T23:59:59.000Z

149

Effect of the isoelectric point on the adsorption of molybdates on fluoride-modified aluminas  

SciTech Connect (OSTI)

The isoelectric point (IEP) of ..gamma..-alumina was modified by the addition of various amounts of fluoride. The modified aluminas were used as supports for molybdenum catalysts prepared by equilibrium adsorption at pH = 6.5. Also, the adsorption of molybdate on supports containing various amounts of fluoride was studied as a function of pH. The amount of molybdenum adsorbed on the fluoride-modified aluminas was found to decrease the IEP of the carrier decreased. An electrostatic model is used to interpret the results. 9 references.

Mulcahy, F.M.; Houalla, M.; Hercules, D.M.

1987-07-01T23:59:59.000Z

150

The wetting behavior of NiAl and NiPtAl on polycrystalline alumina  

SciTech Connect (OSTI)

In order to understand the beneficial effect of Pt on the adherence of thermally grown alumina scales, sessile drop experiments were performed to study the wetting of poly-crystalline alumina by nickel-aluminum alloys with or without platinum addition where the amount of Pt ranged from 2.4 to 10 at.%. Subsequent interfacial structure was evaluated using atomic force microscopy. Platinum addition enhances the wettability of NiAl alloys on alumina, reduces the oxide/alloy interface energy and increases the interfacial mass transport rates.

Saiz, Eduardo; Gauffier, Antoine; Saiz, Eduardo; Tomsia, Antoni P.; Hou, Peggy Y.

2007-07-01T23:59:59.000Z

151

Reactive Spreading of a Lead-Free Solder on Alumina  

SciTech Connect (OSTI)

The wetting of Sn3Ag-based alloys on Al{sub 2}O{sub 3} has been studied using the sessile-drop configuration. Small additions of Ti decrease the contact angle of Sn3Ag alloys on alumina from 115 to 23 degrees. Adsorption of Ti-species at the solid-liquid interface prior to reaction is the driving force for the observed decrease in contact angle, and the spreading kinetics is controlled by the kinetics of Ti dissolution into the molten alloy. The addition of Ti increases the transport rates at the solid-liquid interface, resulting in the formation of triple-line ridges that pin the liquid front and promote a wide variability in the final contact angles.

Gremillard, L.; Saiz, E.; Radmilovic, V.R.; Tomsia, A.P.

2005-12-01T23:59:59.000Z

152

Separating hydrogen from coal gasification gases with alumina membranes  

SciTech Connect (OSTI)

Synthesis gas produced in coal gasification processes contains hydrogen, along with carbon monoxide, carbon dioxide, hydrogen sulfide, water, nitrogen, and other gases, depending on the particular gasification process. Development of membrane technology to separate the hydrogen from the raw gas at the high operating temperatures and pressures near exit gas conditions would improve the efficiency of the process. Tubular porous alumina membranes with mean pore radii ranging from about 9 to 22 {Angstrom} have been fabricated and characterized. Based on hydrostatic tests, the burst strength of the membranes ranged from 800 to 1600 psig, with a mean value of about 1300 psig. These membranes were evaluated for separating hydrogen and other gases. Tests of membrane permeabilities were made with helium, nitrogen, and carbon dioxide. Measurements were made at room temperature in the pressure range of 15 to 589 psi. Selected membranes were tested further with mixed gases simulating a coal gasification product gas. 5 refs., 7 figs.

Egan, B.Z. (Oak Ridge National Lab., TN (USA)); Fain, D.E.; Roettger, G.E.; White, D.E. (Oak Ridge K-25 Site, TN (USA))

1991-01-01T23:59:59.000Z

153

Optical Basicity and Nepheline Crystallization in High Alumina Glasses  

SciTech Connect (OSTI)

The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

2011-02-25T23:59:59.000Z

154

DOE - Office of Legacy Management -- New England Lime Co - CT 10  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou are herePA 3003A AECMexicoEngland Lime Co -

155

Ammoniated silica-alumina gel and catalyst containing the same and processes for producing same  

SciTech Connect (OSTI)

This invention relates to hydrothermally treated silica-alumina cogels resulting in a reduction in the NH/sub 4/ content of the gel and the employment of such gels as cracking catalysts.

Alafandi, H.; Stamires, D.

1980-12-09T23:59:59.000Z

156

Phenomenological study of Au and Pt nanowires grown in porous alumina scaffolds  

E-Print Network [OSTI]

Porous anodic aluminum oxide, commonly known as AAO, has been widely used as a scaffold to synthesize nanowires and nanotubes. The porous alumina structure can be obtained from a simple electrochemical oxidation process, ...

Shin, Yong Cheol, S.M. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

157

Templated self-assembly of nanoporous alumina : pore formation and ordering mechanisms, methodologies, and applications  

E-Print Network [OSTI]

Porous anodic aluminum oxide (AAO), also known as porous alumina, is a self-ordered nanostructured material well-suited for use in electronic, magnetic, optical and biological applications due to its small pore size (4-200nm) ...

Krishnan, Ramkumar, 1975-

2005-01-01T23:59:59.000Z

158

The Effect of Nanoparticle Concentration on Thermo-physical Properties of Alumina-nitrate Nanofluid  

E-Print Network [OSTI]

The objective of this study was to determine how Al2O3 nanoparticle concentration affected the specific heat, heat of fusion, melting point, thermal diffusivity and thermal conductivity of Alumina-Nitrate nanofluids. Al2O3 nanoparticles were...

Shao, Qian

2013-02-15T23:59:59.000Z

159

E-Print Network 3.0 - alumina-on-polyethylene bearing surfaces...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on-polyethylene bearing surfaces Search Powered by Explorit Topic List Advanced Search Sample search results for: alumina-on-polyethylene bearing surfaces Page: << < 1 2 3 4 5 > >>...

160

Effective parameters in axial injection suspension plasma spray process of alumina-zirconia ceramics  

E-Print Network [OSTI]

Effective parameters in axial injection suspension plasma spray process of alumina- zirconia phases using extra small particles as compared to conventional thermal spraying. Suspension spraying% yittria stabilized zirconia was deposited by axial injection SPS process. The effects of principal

Medraj, Mamoun

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

E-Print Network 3.0 - alumina films formed Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

constant in RF devices. Some unique features of thin-film silica and alumina aerogels have been... for aerogel films in various etchants. 1.0 m thick 1.0 m thick 0.75...

162

E-Print Network 3.0 - alumina sol addition Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

constant in RF devices. Some unique features of thin-film silica and alumina aerogels have been... . In this paper, we report on the mechanical properties of silica and...

163

E-Print Network 3.0 - alumina fibrous insulation Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

constant in RF devices. Some unique features of thin-film silica and alumina aerogels have been... . In this paper, we report on the mechanical properties of silica and...

164

Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia  

E-Print Network [OSTI]

catalysts: (a) ethane ODH, (b) propane ODH (663 K, 14 kPa CDehydrogenation of Ethane and Propane on Alumina-Supporteddehydrogenation of ethane and propane. UV-visible and Raman

Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

2001-01-01T23:59:59.000Z

165

Energy Efficiency Improvement Opportunities for the Cement Industry  

E-Print Network [OSTI]

Lime Institute. 2001. Energy Efficiency Opportunity Guide inIndustry, Office of Energy Efficiency, Natural Resourcesof a Cement Kiln, Energy Efficiency Demonstration Scheme,

Worrell, Ernst

2008-01-01T23:59:59.000Z

166

Effect of heat treatment on the catalytic activity of activated alumina  

E-Print Network [OSTI]

'0, The authors report a definite crystal growth, so that surface area diminishes and pore widths becoae greater, The first samples in the sequence had very fine pores& and these becanm continuously widened on further heating, Alumina gel prepared from... being indicated after firing at i/20'F. for five hours. Jellinek and Fankuchen (22) later reported that alpha alumina is first detectable after heating the gel at 1880'F. for two hours. The end product may be amorphous or comparatively crystalline, de...

Farrar, Gerald Leland

1950-01-01T23:59:59.000Z

167

ICSE6 Paris -August 27-31, 2012 Herrier, Berger, Bonelli The Friant-Kern canal : a forgotten example of lime-treated structure  

E-Print Network [OSTI]

: a forgotten example of lime-treated structure in hydraulic conditions Gontran HERRIER1 , Eric BERGER2 in the paper. The treated clay was replaced and compacted by a sheep- foot roller, to achieve a typical in the 70's . Despite the fact that the lime-treated soil has been in constant direct contact

Paris-Sud XI, Université de

168

Physico-chemical modifications of the interactions between hemp fibres and a lime mineral matrix: impacts on mechanical properties of mortars  

E-Print Network [OSTI]

Physico-chemical modifications of the interactions between hemp fibres and a lime mineral matrix interactions between hemp fibres and a lime-based mineral matrix, the consequences of various chemical treatments onto hemp fibres characteristics were measured using scanning electron microscopy, thermal

Paris-Sud XI, Université de

169

Effects of composition on the mechanical response of alumina-filled epoxy.  

SciTech Connect (OSTI)

The effect of composition on the elastic responses of alumina particle-filled epoxy composites is examined using isotropic elastic response models relating the average stresses and strains in a discretely reinforced composite material consisting of perfectly bonded and uniformly distributed particles in a solid isotropic elastic matrix. Responses for small elastic deformations and large hydrostatic and plane-strain compressions are considered. The response model for small elastic deformations depends on known elastic properties of the matrix and particles, the volume fraction of the particles, and two additional material properties that reflect the composition and microstructure of the composite material. These two material properties, called strain concentration coefficients, are characterized for eleven alumina-filled epoxy composites. It is found that while the strain concentration coefficients depend strongly on the volume fraction of alumina particles, no significant dependence on particle morphology and size is observed for the compositions examined. Additionally, an analysis of the strain concentration coefficients reveals a remarkably simple dependency on the alumina volume fraction. Responses for large hydrostatic and plane-strain compressions are obtained by generalizing the equations developed for small deformation, and letting the alumina volume fraction in the composite increase with compression. The large compression plane-strain response model is shown to predict equilibrium Hugoniot states in alumina-filled epoxy compositions remarkably well.

Montgomery, Stephen Tedford

2009-10-01T23:59:59.000Z

170

Densification of nanosized alumina powders by hot isostatic pressing (HIP)  

SciTech Connect (OSTI)

The densification of nanosized alumina powders to compacts of nearly theoretical density by Hot Isostatic Pressing was the aim of this work. Three types of powders produced by the so called exploding wire technique in the mesh size between 20 to 80 nm were used. Because of the big internal friction during dry pressing the densities achieved were only in the range of about 30% TD. Therefore it was necessary to use a second post densification step by cold isostatic pressing (CIP). With pressures as high as 750 MPa the authors received a density of 58% TD. The pellets were sealed in capsules of stainless steel which were densified at different temperatures between 900 C and 1,350 C with pressures between 120 and 300 MPa. The resulting compacts were examined by scanning electron microscopy. The resulting phases were determined by X-ray diffraction. Grain size measurement at the as fabricated compacts was a decisive criterion for the success of the experiments.

Weimar, P.; Knitter, R.; Szabo, D.V. [Forschungszentrum, Karlsruhe (Germany); Krauss, W.

1996-12-31T23:59:59.000Z

171

Final report on the PNL program to develop an alumina sensor  

SciTech Connect (OSTI)

An alumina concentration sensor was required to ensure safe operating conditions for cermet inert anodes that were under development at the Pacific Northwest Laboratory (PNL)(a) for the electrolytic production of aluminum metal. The Sensors Development Program at PNL was conducted in response to this need for an alumina sensor. In all, eight different approaches to developing an alumina sensor were evaluated as part of this program. Each approach sought to correlate alumina concentration either to some spectral, physical, or electrical property of the molten electrolytic, or alternatively, to some operational characteristic of the reduction cell such as the integrity of the cermet anodes or the electrical noise generated by them during cell operation. The studies on electrical noise were performed using a large number of digital signal analysis (DSA) methods. There were two primary requirements for success for an alumina sensor to be used in conjunction with cermet anodes: (1) adequate sensitivity to alumina concentration at concentrations close to saturation, and (2) ease of use in an industrial setting. After numerous laboratory experiments as well as field studies in some cases, it was concluded that none of the approaches sufficiently satisfied the two criteria to serve as the basis for an alumina sensor. If further work is to continue in this area, it is recommended that the research focus on altemative DSA approaches, primarily because DSA methods would be so easy to use in an industrial environment. Due to the lack of correlation using DSA in the present work, however, it is recommended that altemative strategies for data collection and analysis be used in any further development activities.

Windisch, C.F. Jr.; Brenden, B.B.; Koski, O.H.; Williford, R.E.

1992-10-01T23:59:59.000Z

172

Final report on the PNL program to develop an alumina sensor. Sensors Development Program  

SciTech Connect (OSTI)

An alumina concentration sensor was required to ensure safe operating conditions for cermet inert anodes that were under development at the Pacific Northwest Laboratory (PNL)(a) for the electrolytic production of aluminum metal. The Sensors Development Program at PNL was conducted in response to this need for an alumina sensor. In all, eight different approaches to developing an alumina sensor were evaluated as part of this program. Each approach sought to correlate alumina concentration either to some spectral, physical, or electrical property of the molten electrolytic, or alternatively, to some operational characteristic of the reduction cell such as the integrity of the cermet anodes or the electrical noise generated by them during cell operation. The studies on electrical noise were performed using a large number of digital signal analysis (DSA) methods. There were two primary requirements for success for an alumina sensor to be used in conjunction with cermet anodes: (1) adequate sensitivity to alumina concentration at concentrations close to saturation, and (2) ease of use in an industrial setting. After numerous laboratory experiments as well as field studies in some cases, it was concluded that none of the approaches sufficiently satisfied the two criteria to serve as the basis for an alumina sensor. If further work is to continue in this area, it is recommended that the research focus on altemative DSA approaches, primarily because DSA methods would be so easy to use in an industrial environment. Due to the lack of correlation using DSA in the present work, however, it is recommended that altemative strategies for data collection and analysis be used in any further development activities.

Windisch, C.F. Jr.; Brenden, B.B.; Koski, O.H.; Williford, R.E.

1992-10-01T23:59:59.000Z

173

Soil Acidity and Liming L. A. Redmon, M. L. McFarland, V. A. Haby, and D. H. Bade  

E-Print Network [OSTI]

Soil Acidity and Liming L. A. Redmon, M. L. McFarland, V. A. Haby, and D. H. Bade Department of Soil and Crop Sciences The Agriculture Program The Texas A&M University System SCS-2001-06 What Causes SoilAcidity? Various environmental, climatic, and cultural factors can af- fect formation of acid soils

174

An investigation of the use of lime as a soil additive to modify the detrimental effects of frost action  

E-Print Network [OSTI]

chosen from those availabls in the Soil Mechanics Laboratory of A and M College of Texas. A local silty brown CL clay and a sandy gray' CH olay from Corpus Christi were chosen because past experience indicated them to bs bsnefitted by lime...

Earnest, Clyde Talley

1959-01-01T23:59:59.000Z

175

ATOMIC LAYER DEPOSITION OF TITANIUM OXIDE THIN FILMS ONNANOPOROUS ALUMINA TEMPLATES FOR MEDICAL APPLICATIONS  

SciTech Connect (OSTI)

Nanostructured materials may play a significant role in controlled release of pharmacologic agents for treatment of cancer. Many nanoporous polymer materials are inadequate for use in drug delivery. Nanoporous alumina provides several advantages over other materials for use in controlled drug delivery and other medical applications. Atomic layer deposition was used to coat all the surfaces of the nanoporous alumina membrane in order to reduce the pore size in a controlled manner. Both the 20 nm and 100 nm titanium oxide-coated nanoporous alumina membranes did not exhibit statistically lower viability compared to the uncoated nanoporous alumina membrane control materials. In addition, 20 nm pore size titanium oxide-coated nanoporous alumina membranes exposed to ultraviolet light demonstrated activity against Escherichia coli and Staphylococcus aureus bacteria. Nanostructured materials prepared using atomic layer deposition may be useful for delivering a pharmacologic agent at a precise rate to a specific location in the body. These materials may serve as the basis for 'smart' drug delivery devices, orthopedic implants, or self-sterilizing medical devices.

Brigmon, R.

2009-05-05T23:59:59.000Z

176

JOURNAL OF SOLID STATE CHEMISTRY 65, 231-240 (1986) Synthesis of Di-and Trivalent /3"-Aluminas by Ion Exchange  

E-Print Network [OSTI]

diffusion is rapid within these quasi- two-dimensional regions, but many orders of magnitude slower between-, and trivalent cations in the periodic chart diffuse rapidly in the p"-alumina structure. /3"-Aluminas containing

Rohrer, Gregory S.

177

Kilns and Firing Structures  

E-Print Network [OSTI]

actually employed for metallurgy (or less correctly glasssince slag is specific to metallurgy). In fact the substance

Nicholson, Paul

2010-01-01T23:59:59.000Z

178

Study by IR-spectroscopy and adsorption of platinum-alumina catalysts modified by manganese  

SciTech Connect (OSTI)

Additions of Re are widely employed for modifying platinum-alumina catalysts (PAC). The effect of Mn on the catalysis of and the physicochemical properties of PAC has been less studied. It is only known that adding <0.2 wt. % Mn has no effect on the dispersity of the Pt crystallites. In this work the authors have studied the state of Pt in unmodified PAC by IR spectroscopy of adsorbed CO and by the adsorption of H/sub 2/ at elevated temperatures. The state of the metallic platinum in platinum-alumina catalysts modified by Mn is more heterogeneous than in the unmodified sample. When manganese is added, platinum crystallites with stronger electron-donor properties form on the surface of the catalyst. In platinum-alumina catalysts modified by manganese, there is an increase in the number of sites for the high-temperature dissociative adsorption of hydrogen located on the surface of the Mn-modified carrier.

Zaitsev, A.V.; Barkova, A.P.; Borovkov, B.Yu.; Sterligov, O.D.; Isagulyants, G.V.; Kazanskii, V.B.

1987-03-10T23:59:59.000Z

179

The effect of competition by chloride and sulfate anions on the adsorption of arsenate ion onto activated alumina  

E-Print Network [OSTI]

for adsorption sites on the activated alumina. The results of this study showed that the presence of 15 meq/L chloride anion depresses the ability of the arsenate to be adsorbed by F-1 activated alumina initial liquid phase arsenate ion concentration of 5 mg...

Janis, Patrick John

2000-01-01T23:59:59.000Z

180

Formation of Crystalline Zn-Al Layered Double Hydroxide Precipitates on Alumina: The Role of Mineral Dissolution  

E-Print Network [OSTI]

Formation of Crystalline Zn-Al Layered Double Hydroxide Precipitates on Alumina: The Role) phases in soils, we systematically examined the presence of Al and the role of mineral dissolution during Zn sorption/precipitation on -Al2O3 (-alumina) at pH 7.5 using extended X-ray absorption fine

Sparks, Donald L.

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Final report on DSA methods for monitoring alumina in aluminum reduction cells with cermet anodes. Inert Electrodes Program  

SciTech Connect (OSTI)

The Sensors Development Program was conducted at the Pacific Northwest Laboratory (PNL) for the US Department of Energy, Office of Industrial Processes. The work was performed in conjunction with the Inert Electrodes Program at PNL. The objective of the Sensors Development Program in FY 1990 through FY 1992 was to determine whether methods based on digital signal analysis (DSA) could be used to measure alumina concentration in aluminum reduction cells. Specifically, this work was performed to determine whether useful correlations exist between alumina concentration and various DSA-derived quantification parameters, calculated for current and voltage signals from laboratory and field aluminum reduction cells. If appropriate correlations could be found, then the quantification parameters might be used to monitor and, consequently, help control the alumina concentration in commercial reduction cells. The control of alumina concentration is especially important for cermet anodes, which have exhibited instability and excessive wear at alumina concentrations removed from saturation.

Windisch, C.F. Jr.

1992-04-01T23:59:59.000Z

182

Solid-state NMR studies of the adsorption of acetylene on platinum/alumina catalysts  

E-Print Network [OSTI]

SOLID-STATE NMR STUDIES OF THE ADSORPTION OF ACETYLENE ON PLATINUM/ALUMINA CATALYSTS A Thesis by MARSHA JO LUPHER LAMBREGTS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1991 Major Subject: Chemistry SOLID-STATE NMR STUDIES OF THE ADSORPTION OF ACETYLENE ON PLATINUM/ALUMINA CATALYSTS A Thesis by MARSHA JO LUPHER LAMBREGTS Approved as to style and content by: ames F. Haw...

Lambregts, Marsha Jo Lupher

1991-01-01T23:59:59.000Z

183

Alumina reinforced tetragonal zirconia (TZP) composites. Final technical report, July 1, 1993--December 31, 1996  

SciTech Connect (OSTI)

This final technical report summarizes the significant research results obtained during the period July 1, 1993 through December 31, 1996 in the DOE-supported research project entitled, {open_quotes}Alumina Reinforced Tetragonal Zirconia (TZP) Composites{close_quotes}. The objective of the research was to develop high-strength and high-toughness ceramic composites by combining mechanisms of platelet, whisker or fiber reinforcement with transformation toughening. The approach used included reinforcement of Celia- or yttria-partially-stabilized zirconia (Ce-TZP or Y-TZP) with particulates, platelets, or continuous filaments of alumina.

Shetty, D.K.

1997-06-01T23:59:59.000Z

184

Biogeochemical redox cycling in hyper alkaline sediment-water systems. Ian Burke, Rob Mortimer and Doug Stewart (Civil Engineering)  

E-Print Network [OSTI]

kiln contrusted at Harper Hill in Derbyshire by the Buxton Lime Company was biggest of its type and was in operation continuously, 24/7, from 1872 until it was closed in 1944. (The kiln was demolished in 1980 of the kiln, and groundwater in contact with this waste has become saturated in Ca-, Na-, and K- hydroxides

Burke, Ian

185

Biogeochemical redox cycling in hyper alkaline sediment-water systems. Ian Burke, Rob Mortimer and Doug Stewart (Civil Engineering)  

E-Print Network [OSTI]

kiln constructed at Harper Hill in Derbyshire by the Buxton Lime Company was biggest of its type and was in operation continuously, 24/7, from 1872 until it was closed in 1944. (The kiln was demolished in 1980 of the kiln, and groundwater in contact with this waste has become saturated in Ca-, Na-, and K- hydroxides

Burke, Ian

186

Massive hydraulic fracture test Cotton Valley Lime East Texas. Final report, 8 August 1978-31 July 1980  

SciTech Connect (OSTI)

This report summarizes the results of an active stimulation program on the Cotton Valley Lime as evaluated using reservoir production and pressure transient data. Using standard economic parameters and reservoir permeabilities determined by history matching, a detailed study was made to determine the well spacing and fracture length radius necessary for optimum development of the Fallon and North Personville Fields. In addition, the major details of designing and executing a super massive hydraulic fracture job are discussed in the appendix.

Kozik, H.G.; Holditch, S.A.; Kumar, A.

1980-08-01T23:59:59.000Z

187

Processing and Mechanical Properties of Ti2AlC Reinforced with Alumina Fibers  

E-Print Network [OSTI]

, even at temperature as high as 1400 oC at which reaction between Ti2AlC and NextelTM 720 was observed. The double torsion (DT) tests were carried out at room temperature to measure the fracture toughness of the HIPed pure and 5vol% alumina fiber...

Jeon, Kwonguk

2012-10-19T23:59:59.000Z

188

STRESS-DENSITY VARIATIONS IN ALUMINA SEDIMENTS: EFFECTS OF POLYMER CHEMISTRY  

E-Print Network [OSTI]

151 STRESS-DENSITY VARIATIONS IN ALUMINA SEDIMENTS: EFFECTS OF POLYMER CHEMISTRY C. H. SCHILLING present a novel approach for analyzing sediments by gamma-ray densitometry 1 and a fluid mechanics model.g., rheometry, sedimentation kinetics modeling, soil mechanics tests), especially for the low stresses (

Aksay, Ilhan A.

189

Discrete Barium Strontium Titanate (BST) Thin-Film Interdigital Varactors on Alumina: Design, Fabrication, Characterization, and  

E-Print Network [OSTI]

Discrete Barium Strontium Titanate (BST) Thin-Film Interdigital Varactors on Alumina: Design, Raleigh, NC-27695-7914, USA. Email:jayeshnath@ieee.org Abstract -- Discrete Barium Strontium Titanate (BST, capacitors, BST, ferroelectric, thin-film, barium strontium titanate, bandpass filter, IP3, ACPR, temperature

190

Advanced Materials for Sodium-Beta Alumina Batteries: Status, Challenges and Perspectives  

SciTech Connect (OSTI)

The increasing penetration of renewable energy and the trend toward clean, efficient transportation have spurred growing interests in sodium-beta alumina batteries that store electrical energy via sodium ion transport across a ?"-Al2O3 solid electrolyte at elevated temperatures (typically 300~350C). Currently, the negative electrode or anode is metallic sodium in molten state during battery operation; the positive electrode or cathode can be molten sulfur (Na-S battery) or solid transition metal halides plus a liquid phase secondary electrolyte (e.g., ZEBRA battery). Since the groundbreaking works in the sodium-beta alumina batteries a few decades ago, encouraging progress has been achieved in improving battery performance, along with cost reduction. However there remain issues that hinder broad applications and market penetration of the technologies. To better the Na-beta alumina technologies require further advancement in materials along with component and system design and engineering. This paper offers a comprehensive review on materials of electrodes and electrolytes for the Na-beta alumina batteries and discusses the challenges ahead for further technology improvement.

Lu, Xiaochuan; Xia, Guanguang; Lemmon, John P.; Yang, Zhenguo

2010-05-01T23:59:59.000Z

191

Differential Pair Distribution Function Study of the Structure of Arsenate Adsorbed on Nanocrystalline [gamma]-Alumina  

SciTech Connect (OSTI)

Structural information is important for understanding surface adsorption mechanisms of contaminants on metal (hydr)oxides. In this work, a novel technique was employed to study the interfacial structure of arsenate oxyanions adsorbed on {gamma}-alumina nanoparticles, namely, differential pair distribution function (d-PDF) analysis of synchrotron X-ray total scattering. The d-PDF is the difference of properly normalized PDFs obtained for samples with and without arsenate adsorbed, otherwise identically prepared. The real space pattern contains information on atomic pair correlations between adsorbed arsenate and the atoms on {gamma}-alumina surface (Al, O, etc.). PDF results on the arsenate adsorption sample on {gamma}-alumina prepared at 1 mM As concentration and pH 5 revealed two peaks at 1.66 {angstrom} and 3.09 {angstrom}, corresponding to As-O and As-Al atomic pair correlations. This observation is consistent with those measured by extended X-ray absorption fine structure (EXAFS) spectroscopy, which suggests a first shell of As-O at 1.69 {+-} 0.01 {angstrom} with a coordination number of 4 and a second shell of As-Al at 3.13 {+-} 0.04 {angstrom} with a coordination number of 2. These results are in agreement with a bidentate binuclear coordination environment to the octahedral Al of {gamma}-alumina as predicted by density functional theory (DFT) calculation.

Li, Wei; Harrington, Richard; Tang, Yuanzhi; Kubicki, James D.; Aryanpour, Masoud; Reeder, Richard J.; Parise, John B.; Phillips, Brian L. (SBU); (Penn)

2012-03-15T23:59:59.000Z

192

Alumina atomic layer deposition nanocoatings on primary diamond particles using a fluidized bed reactor  

E-Print Network [OSTI]

/high-temperature (HP/HT) synthesis methods [47] led to the discovery of polycrystalline diamond grit and the manufacture of polycrystalline diamond compact (PDC) materials [8]. PDC cutters are well known and widely usedAlumina atomic layer deposition nanocoatings on primary diamond particles using a fluidized bed

George, Steven M.

193

Evaluation of Composite Alumina Nanoparticle and Nitrate Eutectic Materials for use in Concentrating Solar Power Plants  

E-Print Network [OSTI]

of the Solar Two power tower and is currently employed as the TES material at Andasol 1 in Spain. Concentrations of alumina nanoparticles between 0.1% and 10% by weight were introduced into the base material in an effort to create nanofluids which would exhibit...

Malik, Darren R.

2010-07-14T23:59:59.000Z

194

Texture and porosity effects on the thermal radiative behavior of alumina ceramics.  

E-Print Network [OSTI]

1 Texture and porosity effects on the thermal radiative behavior of alumina ceramics. O. Rozenbaum1 for the comprehension of the ceramics thermal properties. Keywords: ceramics, texture, emissivity spectra, infrared (2009) 580-590" DOI : 10.1007/s10765-008-0510-1 #12;2 Abstract Thermal and optical properties

Paris-Sud XI, Université de

195

Mullite/Alumina Mixtures for Use as Porous Matrices in Oxide Fiber Composites  

E-Print Network [OSTI]

ceramic composites. Conditions for the deflection of a matrix crack at a fiber-matrix interface are used particle mixtures of mullite and alumina are assessed as candidate matrixes for use in porous matrix to identify the combinations of modulus and toughness of the fibers and the matrix for which damage

Zok, Frank

196

Surface preparation for high purity alumina ceramics enabling direct brazing in hydrogen atmospheres  

DOE Patents [OSTI]

The present invention relates to a method for preparing the surface of a high purity alumina ceramic or sapphire specimen that enables direct brazing in a hydrogen atmosphere using an active braze alloy. The present invention also relates to a method for directly brazing a high purity alumina ceramic or sapphire specimen to a ceramic or metal member using this method of surface preparation, and to articles produced by this brazing method. The presence of silicon, in the form of a SiO.sub.2 -containing surface layer, can more than double the tensile bond strength in alumina ceramic joints brazed in a hydrogen atmosphere using an active Au-16Ni-0.75 Mo-1.75V filler metal. A thin silicon coating applied by PVD processing can, after air firing, produce a semi-continuous coverage of the alumina surface with a SiO.sub.2 film. Room temperature tensile strength was found to be proportional to the fraction of air fired surface covered by silicon-containing films. Similarly, the ratio of substrate fracture versus interface separation was also related to the amount of surface silicon present prior to brazing. This process can replace the need to perform a "moly-manganese" metallization step.

Cadden, Charles H. (Danville, CA); Yang, Nancy Yuan Chi (Lafayette, CA); Hosking, Floyd M. (Albuquerque, NM)

2001-01-01T23:59:59.000Z

197

Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application  

E-Print Network [OSTI]

Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application Takashi: A micro-scale catalytic combustor using high-precision ceramic tape-casting technology has been developed surface reaction of butane. In combustion experiments with a prototype combustor, the wall temperature

Kasagi, Nobuhide

198

Creep behavior in SiC whisker-reinforced alumina composite  

SciTech Connect (OSTI)

Grain boundary sliding (often accompanied by cavitation) is a major contributor to compressive and tensile creep deformation in fine-grained aluminas, both with and without whisker-reinforcement. Studies indicate that the creep response of alumina composites reinforced with SiC whiskers can be tailored by controlling the composite microstructure and composition. The addition of SiC whiskers (< 30 vol%) significantly increases the creep resistance of fine-grained (1--2 {mu}m) alumina in air at temperatures of 1,200 and 1,300 C. However, at higher whisker contents (30 and 50 vol%), the creep resistance is degraded due to enhanced surface oxidation reactions accompanied by extensive creep cavitation. Densification aids (i.e., Y{sub 2}O{sub 3}), which facilitate silica glass formation and thus liquid phase densification of the composites, can also result in degradation of creep resistance. On the other hand, increasing the matrix grain size or decreasing the whisker aspect ratio (increased whisker number density) results in raising the creep resistance of the composites. These observations not only explain the variability in the creep response of various SiC whisker-reinforced alumina composites but also indicate factors that can be used to enhance the elevated temperature performance.

Lin, H.T.; Becher, P.F. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

1994-10-01T23:59:59.000Z

199

Photothermal investigation of the thermal shock behavior of alumina ceramics for engine components  

E-Print Network [OSTI]

. to transform highly dense bulk ceramic materials to a state with high thermal shock resistance with- out treatment improved the thermal shock resistance of alumina ceramic materials from the critical temperature have shown much higher thermal shock resistance than corresponding untreated ceramics. A theoretical

Mandelis, Andreas

200

Atomistic structure of sodium and calcium silicate intergranular films in alumina  

E-Print Network [OSTI]

Atomistic structure of sodium and calcium silicate intergranular films in alumina David A. Litton March 1998; accepted 21 October 1998) Sodium silicate intergranular films (IGF) in contact. The results were compared to previous simulations of calcium silicate and sol-gel silica IGF's in contact

Garofalini, Stephen H.

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

FUNCTIONALLY GRADED ALUMINA/MULLITE COATINGS FOR PROTECTION OF SILICON CARBIDE CERAMIC COMPONENTS FROM CORROSION  

SciTech Connect (OSTI)

The main objective of this research project is the formulation of processes that can be used to prepare compositionally graded alumina/mullite coatings for protection from corrosion of silicon carbide components (monolithic or composite) used or proposed to be used in coal utilization systems (e.g., combustion chamber liners, heat exchanger tubes, particulate removal filters, and turbine components) and other energy-related applications. Mullite will be employed as the inner (base) layer and the composition of the film will be continuously changed to a layer of pure alumina, which will function as the actual protective coating of the component. Chemical vapor deposition reactions of silica, alumina, and aluminosilicates (mullite) through hydrolysis of aluminum and silicon chlorides in the presence of CO{sub 2} and H{sub 2} will be employed to deposit compositionally graded films of mullite and alumina. Our studies will include the kinetic investigation of the silica, alumina, and aluminosilicate deposition processes, characterization of the composition, microstructure, surface morphology, and mechanical behavior of the prepared films, and modeling of the various deposition processes. During this six-month reporting period, we continued the work on the development and construction of the thermogravimetric chemical vapor deposition system that we intend to employ for studying the deposition of alumina, silica, and aluminosilicates (such as mullite) from mixtures of metal chlorides in H{sub 2} and CO{sub 2}. Specifically, we worked on the development of the tubular flow reactor that will be used for producing aluminum chloride for delivery to the chemical vapor deposition system and of the vapor and gas supply system. Various problems arising from condensation of aluminum chlorides in some sections of the supply line were resolved, and we expect to perform experiments using mixtures containing AlCl{sub 3} in the next reporting period. Preliminary experiments on the deposition of SiO{sub 2} from mixtures of methyltrichlorosilane (MTS) or tetrachlorosilane in H{sub 2} and CO{sub 2} were carried out, and the results showed that the deposition rates from MTS were much higher than those from SiCl{sub 4} and comparable to those reported in the literature for alumina deposition from AlC{sub 3}-H{sub 2}-CO{sub 2} mixtures of similar composition. It was thus decided to employ MTS as silicon source in our codeposition experiments, and a comprehensive investigation of thermodynamic equilibrium in the Al/Si/Cl/C/O/H system for compositions corresponding to MTS-AlCl{sub 3}-H{sub 2}-CO{sub 2} mixtures was conducted so as to identify the boundaries of the region of the space of operating parameters and conditions where preparation of functionally graded mullite/alumina coatings through CVD from metal chloride, CO{sub 2}, and H{sub 2} is feasible. The results showed that deposition of silica, alumina, mullite, and other aluminosilicates is feasible in a broad range of operating conditions from the equilibrated gas phase, but temperatures above 1148 K have to employed to obtain deposits of alumina and mullite if the solid phases are also at equilibrium with each other.

NONE

1997-10-01T23:59:59.000Z

202

Synthesis of High Surface Area Alumina Aerogels without the Use of Alkoxide Precursors  

SciTech Connect (OSTI)

Alumina aerogels were prepared through the addition of propylene oxide to aqueous or ethanolic solutions of hydrated aluminum salts, AlCl{sub 3} {center_dot} 6H{sub 2}O or Al(NO{sub 3}){sub 3} {center_dot} 9H{sub 2}O, followed by drying with supercritical CO{sub 2}. This technique affords low-density (60-130 kg/m{sup 3}), high surface area (600-700 m{sup 2}/g) alumina aerogel monoliths without the use of alkoxide precursors. The dried alumina aerogels were characterized using elemental analysis, high-resolution transmission electron microscopy, powder X-ray diffraction, solid state NMR, acoustic measurements and nitrogen adsorption/desorption analysis. Powder X-ray diffraction and TEM analysis indicated that the aerogel prepared from hydrated AlCl{sub 3} in water or ethanol possessed microstructures containing highly reticulated networks of pseudoboehmite fibers, 2-5 nm in diameter and of varying lengths, while the aerogels prepared from hydrated Al(NO{sub 3}){sub 3} in ethanol were amorphous with microstructures comprised of interconnected spherical particles with diameters in the 5-15 nm range. The difference in microstructure resulted in each type of aerogel displaying distinct physical and mechanical properties. In particular, the alumina aerogels with the weblike microstructure were far more mechanically robust than those with the colloidal network, based on acoustic measurements. Both types of alumina aerogels can be transformed to {gamma}-Al{sub 2}O{sub 3} through calcination at 800 C without a significant loss in surface area or monolithicity.

Baumann, T F; Gash, A E; Chinn, S C; Sawvel, A M; Maxwell, R S; Satcher Jr., J H

2004-06-25T23:59:59.000Z

203

Chemically sensitive polymer-mediated nanoporous alumina SAW sensors for the detection of vapor-phase analytes  

E-Print Network [OSTI]

We have investigated the chemical sensitivity of nanoporous (NP) alumina-coated surface acoustic wave (SAW) devices that have been surface-modified with polymeric mediating films. The research in this dissertation covers the refinement of the NP...

Perez, Gregory Paul

2005-08-29T23:59:59.000Z

204

Structures and charging of alpha-alumina (0001)/water interfaces studies by sum-frequency vibrational spectroscopy  

SciTech Connect (OSTI)

Sum-frequency vibrational spectroscopy in the OH stretch region was employed to study structures of water/{alpha}-Al{sub 2}O{sub 3} (0001) interfaces at different pH values. Observed spectra indicate that protonation and deprotonation of the alumina surface dominate at low and high pH, respectively, with the interface positively and negatively charged accordingly. The point of zero charge (p.z.c.) appears at pH {approx}6.3, which is close to the values obtained from streaming potential and second harmonic generation studies. It is significantly lower than the p.z.c. of alumina powder. The result can be understood from the pK values of protonation and deprotonation at the water/{alpha}-Al{sub 2}O{sub 3} (0001) interface. The p.z.c. of amorphous alumina was found to be similar to that of powder alumina.

Zhang, L.; Tian, C.; Waychunas, G.A.; Shen, Y.R.

2008-11-10T23:59:59.000Z

205

Synthesis and characterization of aluminiumalumina micro- and nano-composites by spark plasma sintering  

SciTech Connect (OSTI)

Graphical abstract: The evolution of microstructure by varying the particle size of reinforcement in the matrix employing spark plasma sintering has been demonstrated here in AlAl{sub 2}O{sub 3} system. An emphasis has been laid on varying the reinforcement particle size and evaluating the microstructural morphologies and their implications on mechanical performance of the composites. Nanocomposites of 0.5, 1, 3, 5, 7 volume % alumina (average size < 50 nm) reinforced in aluminium matrix were fabricated by powder metallurgy route using spark plasma sintering technique technique at a temperature of 773 K and pressure of 50 MPa. Another set of specimens having composition 1, 5, 20 vol.% of alumina (average size ? 10 ?m) had been fabricated to compare the physical as well as mechanical attributes of the microcomposite as well as the nanocomposites. These micro- and nano-composites have been characterized using X-ray diffraction, scanning electron microscopy and transmission electron microscopy followed by density, microhardness and nanoindentation measurements. The alumina nanoparticles revealed an interface showing appreciable physical intimacy with the aluminium matrix compared to that of the alumina microparticles. The interfacial integrity in case of nanocomposites is better than in the microcomposite which has been studied using microscopic techniques. Spark plasma sintering imparts enhanced densification as well as matrix-reinforcement proximity which has been corroborated with the experimental results. - Highlights: The AlAl{sub 2}O{sub 3} micro- and nano-composites fabricated by spark plasma sintering. Better matrix-reinforcement integrity in nanocomposites than microcomposites. Spark plasma sintering method results in higher density and hardness values. High density and hardness values of nanocomposites than microcomposites. High dislocation density in spark plasma sintered AlAl{sub 2}O{sub 3} composites. - Abstract: In the present study, an emphasis has been laid on evaluation of the microstructural morphologies and their implications on mechanical performance of the composites by varying the reinforcement particle size. Nanocomposites of 0.5, 1, 3, 5, 7 volume % alumina (average size < 50 nm) and microcomposites of 1, 5, 20 volume % of alumina (average size ? 10 ?m) reinforced in aluminium matrix were fabricated by spark plasma sintering technique at a temperature of 773 K and pressure of 50 MPa. These micro- and nano-composites have been characterized using X-ray diffraction, scanning electron microscopy and transmission electron microscopy followed by density, microhardness and nanoindentation hardness measurements. The alumina nanoparticles revealed appreciable physical intimacy with the aluminium matrix than that of alumina microparticles. The highest nanohardness recorded 0.85 GPa and 99% densification for 7 and 1 vol.% AlAl{sub 2}O{sub 3} nancomposites respectively. Spark plasma sintering imparts enhanced densification and matrix-reinforcement proximity which have been corroborated with the experimental results.

Dash, K., E-mail: khushbudash@gmail.com; Chaira, D.; Ray, B.C.

2013-07-15T23:59:59.000Z

206

Magnetic properties of mesoporous cobalt-silica-alumina ternary mixed oxides  

SciTech Connect (OSTI)

Mesoporous cobalt-silica-alumina mixed oxides with variable cobalt content have been synthesized through slow evaporation method by using Pluronic F127 non-ionic surfactant as template. N{sub 2} sorption analysis of the template-free mixed oxide samples revealed that these mesoporous materials have high BET surface areas together with large mesopores. Powder XRD, TEM, EDS, FT IR and EPR spectroscopic analysis have been employed to understand the nature of the mesophases, bonding and composition of the materials. Low temperature magnetic measurements of these mixed oxide materials show the presence of ferromagnetic correlation at elevated temperature though at low temperature paramagnetic to ferrimagnetic transition is observed. Highlights: Black-Right-Pointing-Pointer Mesoporous cobalt-silica-alumina ternary mixed oxides. Black-Right-Pointing-Pointer High surface area and mesoporosity in magnetic materials. Black-Right-Pointing-Pointer Ferromagnetic correlation at elevated temperature. Black-Right-Pointing-Pointer Low temperature paramagnetic to ferrimagnetic transition.

Pal, Nabanita [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032 (India)] [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032 (India); Seikh, Md. Motin [Department of Chemistry, Visva-Bharati University, Santiniketan, West Bengal (India)] [Department of Chemistry, Visva-Bharati University, Santiniketan, West Bengal (India); Bhaumik, Asim, E-mail: msab@iacs.res.in [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032 (India)] [Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032 (India)

2013-02-15T23:59:59.000Z

207

A Fracture Mechanics Approach to Thermal Shock Investigation in Alumina-Based Refractory  

SciTech Connect (OSTI)

The thermal shock behavior of large grain size, alumina-based refractories was investigated experimentally using a standard water quench test. A mathematical model was employed to simulate the thermal stability behavior. Behavior of the samples under repeated thermal shock was monitored using ultrasonic measurements of dynamic Young's modulus. Image analysis was used to observe the extent of surface degradation. Analysis of the obtained results for the behavior of large grain size samples under conditions of rapid temperature changes is given.

Volkov-Husovic, T.; Heinemann, R. Jancic; Mitrakovic, D. [Faculty of Technology and Metallurgy, Karnegijeva 4, Belgrade (Serbia and Montenegro)

2008-02-15T23:59:59.000Z

208

Structural studies of alumina pillared hectorite using polyvinyl alcohol as a pillaring agent  

E-Print Network [OSTI]

of the clay's hydrated cations to be replaced with almost any desired cation by using simple ion exchange methods, allows for the preparation of pillared interlayered clays (PILC's). Homoionic exchange derivatives are readily achievable with simple... the pillaring precursor into A1203 pillars. The resulting alumina pillared clay (Al-PILC) is a stable microporous material with high specific surface area, although this porosity is mainly influenced by the method of preparation. 90 Occelli and Pinnavaia...

Kroenig, Andrea N

1997-01-01T23:59:59.000Z

209

Hydrogen Selective Thin Palladium-Copper Composite Membranes on Alumina Supports  

SciTech Connect (OSTI)

Thin and defect-free PdCu composite membranes with high hydrogen permeances and selectivities were prepared by electroless plating of palladium and copper on porous alumina supports with pore sizes of 5 and 100 nm coated with intermediate layers. The intermediate layers on the 100 nm supports were prepared by the deposition of boehmite sols of different particle sizes, and provided a graded, uniform substrate for the formation of defect-free, ultra-thin palladium composite layers. The dependence of hydrogen flux on pressure difference was studied to understand the dominant mechanism of hydrogen transport through a PdCu composite membrane plated on an alumina support with a pore size of 5 nm. The order in hydrogen pressure was 0.98, and indicated that bulk diffusion through the PdCu layer was fast and the overall process was limited by external mass-transfer or a surface process. Scanning electron microscopy (SEM) images of the PdCu composite membrane showed a uniform substrate created after depositing one intermediate layer on top of the alumina support and a dense PdCu composite layer with no visible defects. Cross-sectional views of the membrane showed that the PdCu composite layer had a top layer thickness of 160 nm (0.16 ?m), which is much thinner than previously reported.

Lim, Hankwon; Oyama, S. Ted

2011-08-15T23:59:59.000Z

210

Time-resolved measurement of photon emission during fast crack propagation in three-point bending fracture of silica glass and soda lime glass  

SciTech Connect (OSTI)

Simultaneous time-resolved measurements of photon emission (PE) and fast crack propagation upon bending fracture were conducted in silica glass and soda lime glass. Observation of fracture surfaces revealed that macroscopic crack propagation behavior was similar between the silica glass and soda lime glass when fracture loads for these specimens were comparable and cracks propagated without branching. However, a large difference in the PE characteristics was found between the two glasses. In silica glass, PE (645655?nm) was observed during the entire crack propagation process, whereas intense PE (430490?nm and 500600?nm) was observed during the initial stages of propagation. In contrast, only weak PE was detected in soda lime glass. These results show that there is a large difference in the atomic processes involved in fast crack propagation between these glasses, and that PE can be used to study brittle fracture on the atomic scale.

Shiota, Tadashi, E-mail: tshiota@ceram.titech.ac.jp; Sato, Yoshitaka; Yasuda, Kouichi [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1-S7-13 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan)] [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1-S7-13 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan)

2014-03-10T23:59:59.000Z

211

FUNCTIONALLY GRADED ALUMINA/MULLITE COATINGS FOR PROTECTION OF SILICON CARBIDE CERAMIC COMPONENTS FROM CORROSION  

SciTech Connect (OSTI)

The main objective of this research project is the formulation of processes that can be used to prepare compositionally graded alumina/mullite coatings for protection from corrosion of silicon carbide components (monolithic or composite) used or proposed to be used in coal utilization systems (e.g., combustion chamber liners, heat exchanger tubes, particulate removal filters, and turbine components) and other energy-related applications. Mullite will be employed as the inner (base) layer and the composition of the film will be continuously changed to a layer of pure alumina, which will function as the actual protective coating of the component. Chemical vapor deposition reactions of silica, alumina, and aluminosilicates (mullite) through hydrolysis of aluminum and silicon chlorides in the presence of CO{sub 2} and H{sub 2} will be employed to deposit compositionally graded films of mullite and alumina. Our studies will include the kinetic investigation of the silica, alumina, and aluminosilicate deposition processes, characterization of the composition, microstructure, surface morphology, and mechanical behavior of the prepared films, and modeling of the various deposition processes. During this reporting period, the construction and development of the chemical vapor deposition system was completed, and experiments were conducted on the deposition of alumina, silica, and aluminosilicates (such as mullite) from mixtures of AlCl{sub 3} and CH{sub 3}SiCl{sub 3} in CO{sub 2} and H{sub 2}. Work was mainly done on the investigation of the effects of the reaction temperature on the deposition kinetics. It was found that the temperature had a positive effect on the single oxides deposition rates and the codeposition rate. The apparent activation energy values extracted from the deposition rate vs. temperature curves in the high temperature region were similar for the three deposition processes, having a value around 20 kcal/mol. The codeposition rates were higher, by a more than a factor of 2 in some cases, than the sum of the deposition rates of the two oxides in the independent experiments at the same operating conditions, and this result led to the conclusion that there should exist additional surface reaction steps in the codeposition process, that lead to solid formation and involve both silicon-containing and aluminum-containing species. The elemental analysis (EDXA) of films deposited from MTS-AlCl{sub 3}-CO{sub 2}- H2 mixtures showed that silicon oxide was the main component, and comparison of the deposition rates of SiO{sub 2} and Al{sub 2}O{sub 3} during codeposition with those seen in single species deposition experiments at the same conditions revealed that the codeposition process was characterized by a dramatic enhancement of the deposition of SiO{sub 2} and an equally dramatic reduction in the rate of Al{sub 2}O{sub 3} deposition. Since the enhanced codeposition rate was caused by increased silicon oxide deposition, it was concluded that the main deposition product of the additional surface reaction steps in codeposition must be silicon oxide. A comprehensive investigation of the effects of the other operating parameters on the kinetics of the codeposition process will be carried out in the next reporting period.

NONE

1998-03-01T23:59:59.000Z

212

Kinetic studies of the water gas shift reaction on a sulfided cobalt/molybdena/alumina catalyst  

SciTech Connect (OSTI)

In this study, the applicability of low temperature oxygen chemisorption (LTOC) to measure the specific surface area of several rare-earth oxides (La, Ce, Pr, Nd, Tb) and the kinetics of the water-gas shift reaction over a sulfided cobalt-molybdena-alumina (AMOCAT 1A) catalyst are investigated. The LTOC results indicate that oxygen is possibly adsorbed in the molecular form, O/sub 2//sup -/, as observed by others after heat treatment of these oxides in vacuum. Lanthana and ceria were found to have ratios of total surface area to LTOC similar to those of chromia and molybdena respectively, after a comparable pretreatment. Furthermore, ceria is deduced to exist as a monolayer on the alumina support at loadings below 12%. An additional hour of reduction after the 6 hours of reduction shows a significant increase in LTOC on lanthana, neodymia and terbia which may be due to phase changes exhibited by these polymorphic oxides. The kinetics of the water-gas shift reaction has been extensively studied on iron oxide (high temperature shift) and copper oxide (low temperature shift) based catalysts. This investigation establishes the kinetics over a sulfided cobalt-molybdena-alumina (AMOCAT 1A) catalyst in the medium temperature shift range, 250-300/sup 0/C. The catalyst was sulfided in-situ in a high pressure integrated Berty reactor system. Reaction rates were measured for different CO/H/sub 2/O feed ratios in the range 0.3-3.0, with and without CO/sub 2/ in the feed. The reaction was carried out at several pressures in the range 5-27 atm. and GHSV's in the range 4800-2400 hr/sup 1/.

Srivatsa, N.R.

1987-01-01T23:59:59.000Z

213

Final report on the application of chaos theory to an alumina sensor for aluminum reduction cells  

SciTech Connect (OSTI)

Four chaos-related digital signal analysis (DSA) methods were applied to the analysis of voltage and current signals collected from aluminum electrolysis cells. Two separate data bases were analyzed: bench-scale laboratory experiments and a pilot-scale test. The objective was to assess the feasibility of using these types of data and analysis methods as the basis for a non-intrusive sensor to measure the alumina content in the electrolysis bath. This was the first time chaos theory approaches have been employed to analyze aluminum electrolysis cells.

Williford, R.E.; Windisch, C.F. Jr.

1992-03-01T23:59:59.000Z

214

Vapor-phase synthesis of a solid precursor for {alpha}-alumina through a catalytic decomposition of aluminum triisopropoxide  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer A new solid precursor for {alpha}-alumina was prepared at about 200 Degree-Sign C from aluminum tri-isopropoxide vapor. Black-Right-Pointing-Pointer The obtained precursor was calcined at 1200 Degree-Sign C to form {alpha}-alumina particles, 75 nm in surface area equivalent diameter. Black-Right-Pointing-Pointer The weight loss of the precursor upon calcination was 24%, lower than that of Al(OH){sub 3}, a conventional alumina precursor. -- Abstract: A new solid precursor, hydrous aluminum oxide, for {alpha}-alumina nanoparticles was prepared by thermal decomposition of aluminum triisopropoxide (ATI) vapor in a 500 mL batch reactor at 170-250 Degree-Sign C with HCl as catalyst. The conversion of ATI increased with increasing temperature and catalyst content; it was nearly complete at 250 Degree-Sign C with the catalyst at 10 mol% of the ATI. The obtained precursor particles were amorphous, spherical and loosely agglomerated. The primary particle size is in the range 50-150 nm. The ignition loss of the precursor was 24%, considerably lower than 35% of Al(OH){sub 3}, the popular precursor for alumina particles. Upon calcination of the precursor at 1200 Degree-Sign C in the air with a heating rate of 10 Degree-Sign C/min and a holding time of 2 h, the phase was completely transformed into {alpha}. The spherical particles composing the precursor turned worm-like by the calcination probably due to sintering between neighboring particles. The surface area equivalent diameter of the resulting {alpha}-alumina was 75 nm.

Nguyen, Tu Quang [Department of Chemical Engineering, Kongju National University, 275 Budae-dong, Cheonan, Chungnam 330-717 (Korea, Republic of)] [Department of Chemical Engineering, Kongju National University, 275 Budae-dong, Cheonan, Chungnam 330-717 (Korea, Republic of); Park, Kyun Young, E-mail: kypark@kongju.ac.kr [Department of Chemical Engineering, Kongju National University, 275 Budae-dong, Cheonan, Chungnam 330-717 (Korea, Republic of); Jung, Kyeong Youl [Department of Chemical Engineering, Kongju National University, 275 Budae-dong, Cheonan, Chungnam 330-717 (Korea, Republic of)] [Department of Chemical Engineering, Kongju National University, 275 Budae-dong, Cheonan, Chungnam 330-717 (Korea, Republic of); Cho, Sung Baek [Korea Institute of Geoscience and Mineral Resources (KIGAM), 92 Gwahang-no, Yuseong-gu 305-350 (Korea, Republic of)] [Korea Institute of Geoscience and Mineral Resources (KIGAM), 92 Gwahang-no, Yuseong-gu 305-350 (Korea, Republic of)

2011-12-15T23:59:59.000Z

215

Sol-gel processed silica-alumina materials for diesel engine emission reduction catalysts  

SciTech Connect (OSTI)

The incorporation of >30% silica in alumina prior to platinum impregnation improves the NOx conversion efficiency in the 200--300 C range from 45 to 57% and reduces light-off temperature. Further increase in the amount of silica to 50% is detrimental to NOx conversion efficiency. The {sup 1}H and {sup 29}Si NMR of the materials suggest that this trend is probably related to the surface acidity. The analyses of these materials by X-ray powder diffraction and electron microscopy do not reveal significant differences. Additional NOx conversion in the 350--450 C range with a maximum of 30% at 400 C can be achieved if a rhodium-impregnated 30% silica-alumina, Rh-30% SiO{sub 2}-Al{sub 2}O{sub 3}, is placed upstream of Pt-30% SiO{sub 2}-Al{sub 2}O{sub 3}. It is important to note that mixing Pt-30% SiO{sub 2}-Al{sub 2}O{sub 3} with Rh-30% SiO{sub 2}-Al{sub 2}O{sub 3} does not enhance conversion efficiency or effective temperature range.

Narula, C.K.; Rokosz, M.; Allard, L.F.; Kudla, R.J.; Chattha, M.S.

2000-04-18T23:59:59.000Z

216

A High Temperature Electrochemical Energy Storage System Based on Sodium Beta-Alumina Solid Electrolyte (Base)  

SciTech Connect (OSTI)

This report summarizes the work done during the period September 1, 2005 and March 31, 2008. Work was conducted in the following areas: (1) Fabrication of sodium beta{double_prime} alumina solid electrolyte (BASE) using a vapor phase process. (2) Mechanistic studies on the conversion of {alpha}-alumina + zirconia into beta{double_prime}-alumina + zirconia by the vapor phase process. (3) Characterization of BASE by X-ray diffraction, SEM, and conductivity measurements. (4) Design, construction and electrochemical testing of a symmetric cell containing BASE as the electrolyte and NaCl + ZnCl{sub 2} as the electrodes. (5) Design, construction, and electrochemical evaluation of Na/BASE/ZnCl{sub 2} electrochemical cells. (6) Stability studies in ZnCl{sub 2}, SnCl{sub 2}, and SnI{sub 4} (7) Design, assembly and testing of planar stacks. (8) Investigation of the effect of porous surface layers on BASE on cell resistance. The conventional process for the fabrication of sodium ion conducting beta{double_prime}-alumina involves calcination of {alpha}-alumina + Na{sub 2}CO{sub 3} + LiNO{sub 3} at 1250 C, followed by sintering powder compacts in sealed containers (platinum or MgO) at {approx}1600 C. The novel vapor phase process involves first sintering a mixture of {alpha}-alumina + yttria-stabilized zirconia (YSZ) into a dense ceramic followed by exposure to soda vapor at {approx}1450 C to convert {alpha}-alumina into beta{double_prime}-alumina. The vapor phase process leads to a high strength BASE, which is also resistant to moisture attack, unlike BASE made by the conventional process. The PI is the lead inventor of the process. Discs and tubes of BASE were fabricated in the present work. In the conventional process, sintering of BASE is accomplished by a transient liquid phase mechanism wherein the liquid phase contains NaAlO{sub 2}. Some NaAlO{sub 2} continues to remain at grain boundaries; and is the root cause of its water sensitivity. In the vapor phase process, NaAlO{sub 2} is never formed. Conversion occurs by a coupled transport of Na{sup +} through BASE formed and of O{sup 2-} through YSZ to the reaction front. Transport to the reaction front is described in terms of a chemical diffusion coefficient of Na{sub 2}O. The conversion kinetics as a function of microstructure is under investigation. The mechanism of conversion is described in this report. A number of discs and tubes of BASE have been fabricated by the vapor phase process. The material was investigated by X-ray diffraction (XRD), optical microscopy and scanning electron microscopy (SEM), before and after conversion. Conductivity (which is almost exclusively due to sodium ion transport at the temperatures of interest) was measured. Conductivity was measured using sodium-sodium tests as well as by impedance spectroscopy. Various types of both planar and tubular electrochemical cells were assembled and tested. In some cases the objective was to determine if there was any interaction between the salt and BASE. The interaction of interest was mainly ion exchange (possible replacement of sodium ion by the salt cation). It was noted that Zn{sup 2+} did not replace Na+ over the conditions of interest. For this reason much of the work was conducted with ZnCl{sub 2} as the cathode salt. In the case of Sn-based, Sn{sup 2+} did ion exchange, but Sn{sup 4+} did not. This suggests that Sn{sup 4+} salts are viable candidates. These results and implications are discussed in the report. Cells made with Na as the anode and ZnCl{sub 2} as the cathode were successfully charged/discharged numerous times. The key advantages of the batteries under investigation here over the Na-S batteries are: (1) Steel wool can be used in the cathode compartment unlike Na-S batteries which require expensive graphite. (2) Planar cells can be constructed in addition to tubular, allowing for greater design flexibility and integration with other devices such as planar SOFC. (3) Comparable or higher open circuit voltage (OCV) than the Na-S battery. (4) Wider operating temperature range and higher temper

Anil Virkar

2008-03-31T23:59:59.000Z

217

Method for preparing configured silicon carbide whisker-reinforced alumina ceramic articles  

DOE Patents [OSTI]

A ceramic article of alumina reinforced with silicon carbide whiskers suitable for the fabrication into articles of complex geometry are provided by pressureless sintering and hot isostatic pressing steps. In accordance with the method of the invention a mixture of 5 to 10 vol. % silicon carbide whiskers 0.5 to 5 wt. % of a sintering aid such as yttria and the balance alumina powders is ball-milled and pressureless sintered in the desired configuration in the desired configuration an inert atmosphere at a temperature of about 1800.degree. C. to provide a self-supporting configured composite of a density of at least about 94% theoretical density. The composite is then hot isostatically pressed at a temperature and pressure adequate to provide configured articles of at least about 98% of theoretical density which is sufficient to provide the article with sufficient strength and fracture toughness for use in most structural applications such as gas turbine blades, cylinders, and other components of advanced heat engines.

Tiegs, Terry N. (Lenoir City, TN)

1987-01-01T23:59:59.000Z

218

[Aluminum coordination and active sites on aluminas, Y-zeolites and pillared layered silicates]. Progress report  

SciTech Connect (OSTI)

This report is organized in four sections. In the first the authors will outline structural features which are common to all fine grained alumina, as well as to non-framework alumina in zeolites. This section will be followed by a study of the surface vs. bulk coordination of aluminum. The third section will deal with measurement of the number of acid sites and the scaling of their strength. The fourth and last section will describe three model reactions: the isomerization of 1-butene and of 2 cis-butene; the isomerization and disproportionation of oxtho-xylene; and the transformation of trichloroethane into vinyl chloride followed by the polymerization of the vinyl chloride. The relationship between chemical activity and selectivity and what is known of the local structure of the active catalytic sites will be underlined. Other kinds of zeolites besides Y zeolite have been studied. Instead of the aluminum pillared silicates they found it more interesting to study the substitution of silicon by aluminum in a layered structure containing a permanent porosity (aluminated sepiolite).

Fripiat, J.J.

1994-02-01T23:59:59.000Z

219

Alumina reinforced tetragonal zirconia (TZP) composites. [Annual report, February 16, 1994--February 15, 1995  

SciTech Connect (OSTI)

Objective is to develop high-strength and high-toughness ceramic composites by combining mechanisms of platelet, whisker or fiber reinforcement with transformation toughening. The approach being used includes reinforcement of ceria or yttria-partially-stabilized zirconia (CE-TZP or Y-T-ZP) with platelets, whiskers or continuous filaments of alumina. Critical stresses for extension of filament-bridged matrix cracks were measured as a function of crack length in a model composite system, SiC (filament)-reinforced epoxy-alumina (matrix). The crack-length dependence of the crack extension stress at short crack lengths followed the prediction of a fracture-mechanics analysis that employed a new force-displacement law for the crack-bridging filaments developed in this study. At large crack lengths, the measured matrix-cracking stress was close to the prediction of the steady-state theory of Budiansky, Hutchinson and Evans. Optical fluorescence was employed to measure stresses in crack-bridging sapphire filaments and assess interfacial properties in a model sapphire-epoxy composite. Composites of yttria-partially-stabilized zirconia (Y-TZP) matrix dispersed with either single crystal A1{sub 2}0{sub 3} platelets or particulars were fabricated by a hybrid suspension/powder processing route to densities greater than 99.0% of theoretical. Both transformation toughening and platelet reinforcement contribute to the high fracture toughness of the A1{sub 2}0{sub 3} (platelet)-Y-TZP composites.

Shetty, D.K.

1995-04-01T23:59:59.000Z

220

Thermal cycling effect on the nanoparticle distribution and specific heat of a carbonate eutectic with alumina nanoparticles  

E-Print Network [OSTI]

. The concentration of alumina nanoparticles in this material was measured using neutron activation analysis. The average specific heat of the uncycled material was found to be 1.37 J/gC.The average specific heat of the thermally cycled material was between 1.7-2.1 J...

Shankar, Sandhya

2011-08-08T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Effects of Adsorbed Pyridine Derivatives and Ultrathin Atomic-Layer-Deposited Alumina Coatings on the Conduction Band-Edge Energy  

E-Print Network [OSTI]

to the identity of shuttle molecules. INTRODUCTION Dye-sensitized solar cells (DSCs) constitute a promising (such as alumina) are known to boost open-circuit photovoltages substantially for dye-sensitized solar. The archetypal cell utilizes a Ru-based dye,7 typically N719 (i.e., ditetrabutyl-ammonium cis

222

A New Optically Reflective Thin Layer Electrode (ORTLE) Window: Gold on a Thin Porous Alumina Film Used to Observe the  

E-Print Network [OSTI]

the electrode face and a window behind it. The electrode is created by thin-film deposition of gold ontoFull Paper A New Optically Reflective Thin Layer Electrode (ORTLE) Window: Gold on a Thin Porous Alumina Film Used to Observe the Onset of Water Reduction Paul G. Miney, Maria V. Schiza, Michael L

Myrick, Michael Lenn

223

Materials Science and Engineering A252 (1998) 117132 Optimization of 316 stainless steel/alumina functionally graded  

E-Print Network [OSTI]

. Introduction Due to differences of thermal and mechanical prop- erties in ceramics and metals, residual stresses develop in regions near the ceramic/metal interfaces during fabrication and under thermal/alumina functionally graded material for reduction of damage induced by thermal residual stresses M. Grujicic *, H

Grujicic, Mica

224

Materials Science and Engineering A 493 (2008) 256260 In situ bend testing of niobium-reinforced alumina nanocomposites  

E-Print Network [OSTI]

pathways [5]. If the frac- ture toughness can be improved, ceramic matrix composites (CMCs) hold great the stress field around the crack tip. The addition of fibers to a brittle ceramic matrix can improve of carbon nanotubes to nanocrystalline alumina (Al2O3) bene- fits the brittle ceramic's mechanical

Ritchie, Robert

2008-01-01T23:59:59.000Z

225

Fracture and Fatigue Behavior at Ambient and Elevated Temperatures of Alumina Bonded with Copper/Niobium/Copper Interlayers  

E-Print Network [OSTI]

Fracture and Fatigue Behavior at Ambient and Elevated Temperatures of Alumina Bonded with Copper and Engineering, University of California, Berkeley, California 94720 Interfacial fracture toughness and cyclic temperatures, and assessed in terms of interfacial chemistry and microstructure. The mean interfacial fracture

Ritchie, Robert

226

Table 2 -Lime use and practices on Corn, major producing states, 2001 CO GA IL IN IA KS KY MI MN MO NE NY NC ND OH PA SD TX WI Area  

E-Print Network [OSTI]

Table 2 - Lime use and practices on Corn, major producing states, 2001 CO GA IL IN IA KS KY MI MN.7 Table 2 - Lime use and practices on Corn, major producing states, 2000 CO IL IN IA KS KY MI MN MO NE NY use and practices on Corn, major producing states, 1999 CO IL IN IA KS KY MI MN MO NE NC OH SD TX WI

Kammen, Daniel M.

227

Effects of dispersion and support on adsorption, catalytic and electronic properties of cobalt/alumina CO hydrogenation catalysts: (Technical progress report)  

SciTech Connect (OSTI)

The continued investigation of dispersion and metal-support interactions and their effects upon the adsorption, activity/selectivity, and electronic properties of the metal in cobalt/alumina (and to a lesser extent on iron/alumina) catalysts is proposed. The objectives of this research are to determine the effects of surface structure and metal dispersion on the adsorption and catalytic properties of cobalt, and determine the effects of metal-support interactions, i.e., effects of decorating support species on metal crystallites and of direct electronic interactions between metal clusters and the support, on the adsoprtion, catalytic and electronic properties of cobalt supported on alumina.

Bartholomew, C.H. Jr.

1986-12-22T23:59:59.000Z

228

Effect of Long-term Lime and Potassium Applications on Quantity-Intensity (Q/I) Relationships in Sandy Soil1  

E-Print Network [OSTI]

IN SANDY SOIL 787 may be presented as a measure of the free energy of exchange of K in the soil by Ca in Sandy Soil1 D. L. SPARKS AND W. C. LiEBHARDT2 ABSTRACT The effects of long-term lime and K applications on quan- tity-intensity (Q/I) relationships were investigated on the Ap and B21t horizons of a Kalmia soil

Sparks, Donald L.

229

Response of rice to ammonium and nitrate nitrogen applied at various stages of plant growth on limed and unlimed Beaumont and Lake Charles clays  

E-Print Network [OSTI]

RESPONSE OF RICE TO AMMONIUM AND NITRATE NITROGEN APPLIED AT VARIOUS STAGES OF PLANT GROWTH ON LIMED AND UNLINED BEAUNONT AND LAKE CHARLES CLAYS A Thesis By William B. Gay, III Submitted to the Graduate Sohool of the Agricultural... BEAUMONT AND LAKE CHARLES CLAYS A Thesis By Nilliam B. Gay, III Chairman of Committee Head of the Department of Soil Sc Crop Sciences ACKNOWLEDGEMENTS I would like to express my appreciation to Dr. A. G. Caldwell for his 1nterest and guidance...

Gay, William Blalock, III

1962-01-01T23:59:59.000Z

230

Characterization of microstructure and crack propagation in alumina using orientation imaging microscopy (OIM). December 1996  

SciTech Connect (OSTI)

A more complete description requires the lattice orientations of a statistically significant number of grains, coupled with morphology such as grain size and shape; this can be obtained using orientation imaging microscopy (OIM), which uses crystallographic orientation data from Backscattered Electron Kikuchi patterns (BEKP) collected using a SEM. This report describes the OIM results for alumina; these include image quality maps, grain boundary maps, pole figures, and lattice misorientations depicted on MacKenzie plot and in Rodrigues space. High quality BEKP were obtained and the images and data readily reveal the grain morphology, texture, and grain boundary misorientations, including those for cracked boundaries. A larger number of grains should be measured to make statistical comparisons between materials with different processing histories.

Glass, S.J.; Michael, J.R. [Sandia National Labs., Albuquerque, NM (United States); Readey, M.J. [Caterpillar, Inc., Peoria, IL (United States); Wright, S.I.; Field, D.P. [TSL, Inc., Provo, UT (United States)

1996-12-01T23:59:59.000Z

231

Activated alumina adsorption of trace amounts of chromium and lead from wastewater  

E-Print Network [OSTI]

the concentration in the initial solution. Data for 100 90 80 70 60 %R 50 20 g/& 10 lr B rr / h. / 0. 5 u, 0. 25 g/1 , + j Pa , I f, ' / '~f/ 30 20 10 pH 10 Figure 3 ? Percent removal of lead by activated alumina for various pH values 28 100...2 for lead model Pb-2 48 15 Q vs X3 for lead model Pb-3 40 16 17 Q vs X4 for lead model Pb-4 Q vs X5 for lead model Pb-5 50 51 18 Investigation of relationship of pH for model Pb-1 54 19 Investigation of relationship of pH for model Pb-4 20...

Dennis, Reid L

1984-01-01T23:59:59.000Z

232

A New Concept in Dryer Control  

E-Print Network [OSTI]

, lumber, fiberboard, gypsum board, crumb rubber, etc. In addition, such dryer types as Rotary Drum, Suspension, Flash, Through, Spray, Oven, Tray, Lime Kilns, etc., should be amenable to control utilizing this model. Moreover, it should apply to most thin...

Robinson, J. W.

233

Experimental study of alumina-water and zirconia-water nanofluids convective heat transfer and viscous pressure loss in Laminar regime  

E-Print Network [OSTI]

The objective of this study is to evaluate experimentally the convective heat transfer and viscous pressure loss characteristics of alumina-water and zirconia-water nanofluids. Nanofluids are colloidal dispersions of ...

Rea, Ulzie L

2008-01-01T23:59:59.000Z

234

EXPERIMENTAL STUDY OF CRITICAL HEAT FLUX WITH ALUMINA-WATER NANOFLUIDS IN DOWNWARD-FACING CHANNELS FOR IN-VESSEL RETENTION APPLICATIONS  

E-Print Network [OSTI]

The Critical Heat Flux (CHF) of water with dispersed alumina nanoparticles was measured for the geometry and flow conditions relevant to the In-Vessel Retention (IVR) situation which can occur during core melting sequences ...

Park, R.J.

235

The transported entropies of ions in solid state fluorides and beta-alumina  

SciTech Connect (OSTI)

The technical relevance of reversible heat effects is discussed with reference to high temperature batteries and electrolysis systems. The transported entropies of Na{sup +} in solid state mixtures of NaF and Na{sub 3}AlF{sub 6} are presented. The transported entropies are S{sup *cry}{sub Na{sup +}} = 140 {+-} 7 J K{sup {minus}1} mol{sup {minus}1} for cryolite, S{sup *NaF}{sub Na{sup +}} = 81 {+-} 8 J K{sup {minus}1} mol{sup {minus}1} for sodium fluoride and S{sup *{beta}}{sub Na{sup +}} = 60 {+-} 5 J K{sup {minus}1} mol{sup {minus}1} for sodium {beta}{double_prime}-alumina at the temperature range 380--500 C. The value obtained for sodium in the solid cryolite is higher than transported entropy of Na{sup +} in other solid sodium conductors and makes the authors predict that the transported entropy for Na{sup +} in the molten electrolyte mixture for aluminum production is substantial, and that so are the reversible heat effects in the aluminum electrolysis cell.

Sharivker, V.S.; Ratkje, S.K. [Univ. of Trondheim (Norway)

1996-10-01T23:59:59.000Z

236

Adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts  

SciTech Connect (OSTI)

The adsorption and desorption of hydrogen and carbon monoxide were studied on alumina-supported iridium catalysts which were examined by a scanning transmission electron microscope (STEM). The metal particle size and number of particles per area of catalyst increased with increasing metal loading. The particles were approx. 10 A. in diameter, cubo-octahedral shaped, and approx. 80-90% disperse. The STEM electron beam caused negligible damage to the samples. Hydrogen adsorption measurements showed that the hydrogen-iridium atom ratio was 1.2:1-1.3:1 and increased with decreasing metal loading. Temperature-programed desorption showed four types of adsorbed hydrogen desorbing at -90/sup 0/C (I), 15/sup 0/C (IV), 115/sup 0/C (II), and 245/sup 0/C (III). Types II and IV desorb from single atom sites and Types I and III from multiple atom sites. Type I is in rapid equilibrium with the gas phase. All desorption processes appear to be first order. Carbon monoxide adsorbed nondissociatively at 25/sup 0/C with approx. 0.7:1 CO/Ir atom ratio. It adsorbed primarily in linear forms at low coverage, but a bridged form appeared at high coverage.

Etherton, B.P.

1980-01-01T23:59:59.000Z

237

Study of discharge after electron irradiation in sapphires and polycrystalline alumina  

SciTech Connect (OSTI)

The fraction R of charges undergoing discharge during the time separating two electron pulses is derived from the induced current method developed in a scanning electron microscope. Irradiation is performed via a 10 keV defocused electron beam and low current density. The evolution of R with temperature (in the range 300-663 K) obeys to an Arrhenius type relation. Activation energies connected with the processes involved are deduced. In sapphire, no discernible discharge is observed due to the dominance of deep traps. In silver doped sapphire, R increases sharply from 10% to 70% as the temperature rises from 360 to 420 K, with a corresponding activation energy of 0.51 eV. In contrast, in polycrystalline alumina processed by solid state sintering (grain diameters of 1.7, 2.7, and 4.5 {mu}m) the degree of discharge increases continuously with temperature and grain size. The enhancement with grain size indicates that the sintering conditions influence strongly the efficiency of a gettering effect. The activation energy below 573 K is about 0.12 eV independently of grain size. Above 573 K, a second activation energy of 0.26 eV appears for the smallest grain size sample. The results suggest that discharge may stem from a density of trapping states, associated to grain boundaries in sintered samples, rather than from a single trapping level linked to the doping element as Ag in sapphire.

Zarbout, K. [IM2NP, UMR CNRS 6242, Aix-Marseille Universite, 13397 Marseille Cedex 20 (France); Laboratoire des Materiaux Ceramiques, Composites et Polymeres, Faculte des Sciences de Sfax, Universite de Sfax, BP 1171, 3000 Sfax (Tunisia); Moya, G.; Ahmed, A. Si [IM2NP, UMR CNRS 6242, Aix-Marseille Universite, 13397 Marseille Cedex 20 (France); Damamme, G. [CEA Ile-de-France, BP. 12, 91680 Bruyeres-le-Chatel (France); Kallel, A. [Laboratoire des Materiaux Ceramiques, Composites et Polymeres, Faculte des Sciences de Sfax, Universite de Sfax, BP 1171, 3000 Sfax (Tunisia)

2010-11-15T23:59:59.000Z

238

Method for fabricating cermets of alumina-chromium systems. [Patent application  

DOE Patents [OSTI]

Cermet insulators resistant to thermal and mechanical shock are prepared from alumina-chromium systems in the following way: by providing an Al/sub 2/O/sub 3/ material of about 0.5 to 7.0 micron size with a solid-hydrocarbon overcoating by slurrying an effective amount of said solid hydrocarbon in a solvent mixture containing said Al/sub 2/O/sub 3/ and thereafter evaporating said solvent, contacting said coated Al/sub 2/O/sub 3/ with a solution of chromium precursor compound, heating the resulting mixture in a reducing environment to a temperature above the decomposition temperature of said chromium precursor compound but less than the melting temperature of the Al/sub 2/O/sub 3/ or chromium for sufficient duration to yield a particulate compound having chromium essentially dispersed throughout the Al/sub 2/O/sub 3/, and then densifying said particulate to provide said cermet characterized by a theoretical density in excess of 96% and having 0.1 to 10.0 vol. % elemental chromium metal present therein as a dispersed phase at the boundaries of the Al/sub 2/O/sub 3/ material. Cermet components prepared thereby are useful in high temperature equipment, advanced heat engines, and nuclear-related equipment applications where electrical or thermal insulators are required.

Morgan, C.S.

1981-10-05T23:59:59.000Z

239

Manufacture of Alumina-Forming Austenitic Steel Alloys by Conventional Casting and Hot-Working Methods  

SciTech Connect (OSTI)

Oak Ridge National Laboratory (ORNL) and Carpenter Technology Corporation (CarTech) participated in an in-kind cost share cooperative research and development agreement (CRADA) effort under the auspices of the Energy Efficiency and Renewable Energy (EERE) Technology Maturation Program to explore the feasibility for scale up of developmental ORNL alumina-forming austenitic (AFA) stainless steels by conventional casting and rolling techniques. CarTech successfully vacuum melted 301b heats of four AFA alloy compositions in the range of Fe-(20-25)Ni-(12-14)Cr-(3-4)Al-(l-2.5)Nb wt.% base. Conventional hot/cold rolling was used to produce 0.5-inch thick plate and 0.1-inch thick sheet product. ORNL subsequently successfully rolled the 0.1-inch sheet to 4 mil thick foil. Long-term oxidation studies of the plate form material were initiated at 650, 700, and 800 C in air with 10 volume percent water vapor. Preliminary results indicated that the alloys exhibit comparable (good) oxidation resistance to ORNL laboratory scale AFA alloy arc casting previously evaluated. The sheet and foil material will be used in ongoing evaluation efforts for oxidation and creep resistance under related CRADAs with two gas turbine engine manufacturers. This work will be directed to evaluation of AFA alloys for use in gas turbine recuperators to permit higher-temperature operating conditions for improved efficiencies and reduced environmental emissions. AFA alloy properties to date have been obtained from small laboratory scale arc-castings made at ORNL. The goal of the ORNL-CarTech CRADA was to establish the viability for producing plate, sheet and foil of the AFA alloys by conventional casting and hot working approaches as a first step towards scale up and commercialization of the AFA alloys. The AFA alloy produced under this effort will then be evaluated in related CRADAs with two gas turbine engine manufacturers for gas turbine recuperator applications.

Brady, M.P.; Yamamoto, Y.; Magee, J.H.

2009-03-10T23:59:59.000Z

240

Preliminary study of niobium alloy contamination by transport through helium. [Nb-1Zr; Sm-Co; Hiperco 50 steel; alumina  

SciTech Connect (OSTI)

Preliminary tests were conducted to determine if interstitial element transport through a circulating helium working fluid was a potential problem in Brayton and Stirling space power systems. Test specimens exposed to a thermal gradient for up to 3000 h included Nb-1%Zr, a Sm-Co alloy, Hiperco 50 steel, and alumina to simulate various engine components of the Brayton and Stirling systems. Results indicate that helium transport of interstitial contaminants can be minimized over a 7-y life with monometallic Nb-1%Zr design. Exposure with other materials indicated a potential for interstitial contaminant transport.

Scheuermann, C.M.; Moore, T.J.; Wheeler, D.R.

1987-01-12T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Final report on the application of chaos theory to an alumina sensor for aluminum reduction cells. Inert Electrodes Program  

SciTech Connect (OSTI)

Four chaos-related digital signal analysis (DSA) methods were applied to the analysis of voltage and current signals collected from aluminum electrolysis cells. Two separate data bases were analyzed: bench-scale laboratory experiments and a pilot-scale test. The objective was to assess the feasibility of using these types of data and analysis methods as the basis for a non-intrusive sensor to measure the alumina content in the electrolysis bath. This was the first time chaos theory approaches have been employed to analyze aluminum electrolysis cells.

Williford, R.E.; Windisch, C.F. Jr.

1992-03-01T23:59:59.000Z

242

Surface acidity and cumene conversion. II. A study of. gamma. -alumina containing fluoride, cobalt, and molybdenum additives: the effect of reduction  

SciTech Connect (OSTI)

The effect of reduction of the cumene conversion activity of a series of fluoride-impregnated, alumina-supported cobalt-molybdenum catalysts has been investigated. Such catalysts exhibit two different types of Broensted acid sites, one associated with the molybdenum and the other with the fluorided alumina surface. Reduction with H/sub 2/ eliminates the former type of site, but does not affect the latter. Reduction does not affect the activity of the alumina catalyst which is impregnated only with fluoride, but conversions for the other catalysts are reduced by 2-10%. In hydrocracking experiments, the dramatic influence of fluoride impregnation on cumene conversion and the synergistic nature of the fluoride and cobalt/molybdenum are demonstrated.

Boorman, P.M.; Kydd, R.A.; Sarbak, Z.; Somogyvari, A.

1986-08-01T23:59:59.000Z

243

Solid-phase synthesis of high-alumina cements by high-temperature treatment on the surface of molten cast iron  

SciTech Connect (OSTI)

The use of block and monolithic concreting technology in the construction of thermal power plants together with the technical and economic advantages arising from the use of high-alumina cements in the production of refractory concretes have made the development of new methods for the production of high-alumina cement clinkers mandatory. To this end the authors of this paper study the kinetics of synthesis of such clinkers obtained by their firing on the surface of molten cast iron as the heat transfer agent. Among the results presented are a structural and quantitative analysis of the clinker along with phase and activation energy studies.

Fedorov, N.F.; Gavrilov, A.P.; Ivanov, N.I.; Khalina, O.M.

1986-09-10T23:59:59.000Z

244

Density dependence of the room temperature thermal conductivity of atomic layer deposition-grown amorphous alumina (Al{sub 2}O{sub 3})  

SciTech Connect (OSTI)

We report on the thermal conductivity of atomic layer deposition-grown amorphous alumina thin films as a function of atomic density. Using time domain thermoreflectance, we measure the thermal conductivity of the thin alumina films at room temperature. The thermal conductivities vary ?35% for a nearly 15% change in atomic density and are substrate independent. No density dependence of the longitudinal sound speeds is observed with picosecond acoustics. The density dependence of the thermal conductivity agrees well with a minimum limit to thermal conductivity model that is modified with a differential effective-medium approximation.

Gorham, Caroline S.; Gaskins, John T.; Hopkins, Patrick E., E-mail: phopkins@virginia.edu [Department of Mechanical and Aerospace Engineering, University of Virginia, Charlottesville, Virginia 22904 (United States); Parsons, Gregory N.; Losego, Mark D. [Department of Chemical and Biomolecular Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States)

2014-06-23T23:59:59.000Z

245

Deformation Behavior of Sub-micron and Micron Sized Alumina Particles in Compression.  

SciTech Connect (OSTI)

The ability to integrate ceramics with other materials has been limited due to high temperature (>800degC) ceramic processing. Recently, researchers demonstrated a novel process , aerosol deposition (AD), to fabricate ceramic films at room temperature (RT). In this process, sub - micro n sized ceramic particles are accelerated by pressurized gas, impacted on the substrate, plastically deformed, and form a dense film under vacuum. This AD process eliminates high temperature processing thereby enabling new coatings and device integration, in which ceramics can be deposited on metals, plastics, and glass. However, k nowledge in fundamental mechanisms for ceramic particle s to deform and form a dense ceramic film is still needed and is essential in advancing this novel RT technology. In this wo rk, a combination of experimentation and atomistic simulation was used to determine the deformation behavior of sub - micron sized ceramic particle s ; this is the first fundamental step needed to explain coating formation in the AD process . High purity, singl e crystal, alpha alumina particles with nominal size s of 0.3 um and 3.0 um were examined. Particle characterization, using transmission electron microscopy (TEM ), showed that the 0.3 u m particles were relatively defect - free single crystals whereas 3.0 u m p articles were highly defective single crystals or particles contained low angle grain boundaries. Sub - micron sized Al 2 O 3 particles exhibited ductile failure in compression. In situ compression experiments showed 0.3um particles deformed plastically, fractured, and became polycrystalline. Moreover, dislocation activit y was observed within the se particles during compression . These sub - micron sized Al 2 O 3 particles exhibited large accum ulated strain (2 - 3 times those of micron - sized particles) before first fracture. I n agreement with the findings from experimentation , a tomistic simulation s of nano - Al 2 O 3 particles showed dislocation slip and significant plastic deformation during compressi on . On the other hand, the micron sized Al 2 O 3 particles exhibited brittle f racture in compression. In situ compression experiments showed 3um Al 2 O 3 particles fractured into pieces without observable plastic deformation in compression. Particle deformation behaviors will be used to inform Al 2 O 3 coating deposition parameters and particle - particle bonding in the consolidated Al 2 O 3 coatings.

Sarobol, Pylin; Chandross, Michael E.; Carroll, Jay; Mook, William; Boyce, Brad; Kotula, Paul G.; McKenzie, Bonnie B.; Bufford, Daniel Charles; Hall, Aaron Christopher.

2014-09-01T23:59:59.000Z

246

The adhesion of electroless Ni(P) on alumina ceramic using a vacuum-deposited Ti-Pd activator layer  

SciTech Connect (OSTI)

The adhesion of electrolessly deposited nickel on Al[sub 2]O[sub 3] ceramic substrates using sputtered and evaporated Ti-Pd activator films was studied. The adhesion was measured using the direct pull-off test and the 90[degree] peel test. The morphology and the chemical composition of the fracture surfaces of the samples with evaporated Ti-Pd activator film were studied with scanning electron microscopy/energy, dispersive x-ray, and static secondary ion mass spectroscopy. Failure did not occur along the metal-ceramic interface, but mainly in the alumina, and therefore the strength of the system is determined primarily by the substrate material. Cross-sectional transmission electron microscopy and high-resolution transmission electron microscopy were used to study the interface structure before failure. The oxidation state of Ti at the interface was measured with X-ray photoelectron spectroscopy. This was carried out in the (sub)monolayer range by using a Ti wedge deposited on alumina with a maximum thickness of 0.35 nm. It is concluded that the strong adhesion at the metal-ceramic interface is caused by chemical bonding of the first Ti monolayer with substrate oxygen atoms.

Severin, J.W.; Hokke, R.; Wel, H. van der; Johnson, M.T.; With, G. de (Philips Research Labs., Eindhoven (Netherlands))

1993-06-01T23:59:59.000Z

247

Selective catalytic reduction of nitric oxide with ethanol/gasoline blends over a silver/alumina catalyst  

SciTech Connect (OSTI)

Lean gasoline engines running on ethanol/gasoline blends and equipped with a silver/alumina catalyst for selective catalytic reduction (SCR) of NO by ethanol provide a pathway to reduced petroleum consumption through both increased biofuel utilization and improved engine efficiency relative to the current stoichiometric gasoline engines that dominate the U.S. light duty vehicle fleet. A pre-commercial silver/alumina catalyst demonstrated high NOx conversions over a moderate temperature window with both neat ethanol and ethanol/gasoline blends containing at least 50% ethanol. Selectivity to NH3 increases with HC dosing and ethanol content in gasoline blends, but appears to saturate at around 45%. NO2 and acetaldehyde behave like intermediates in the ethanol SCR of NO. NH3 SCR of NOx does not appear to play a major role in the ethanol SCR reaction mechanism. Ethanol is responsible for the low temperature SCR activity observed with the ethanol/gasoline blends. The gasoline HCs do not deactivate the catalyst ethanol SCR activity, but they also do not appear to be significantly activated by the presence of ethanol.

Pihl, Josh A [ORNL] [ORNL; Toops, Todd J [ORNL] [ORNL; Fisher, Galen [University of Michigan] [University of Michigan; West, Brian H [ORNL] [ORNL

2014-01-01T23:59:59.000Z

248

Formation of silver nanoparticles inside a soda-lime glass matrix in the presence of a high intensity Ar{sup +} laser beam  

SciTech Connect (OSTI)

Formation and motion of the silver nanoparticles inside an ion-exchanged soda-lime glass in the presence of a focused high intensity continuous wave Ar{sup +} laser beam (intensity: 9.2 x 10{sup 4} W/cm{sup 2}) have been studied in here. One-dimensional diffusion equation has been used to model the diffusion of the silver ions into the glass matrix, and a two-dimensional reverse diffusion model has been introduced to explain the motion of the silver clusters and their migration toward the glass surface in the presence of the laser beam. The results of the mentioned models were in agreement with our measurements on thickness of the ion-exchange layer by means of optical microscopy and recorded morphology of the glass surface around the laser beam axis by using a Mirau interferometer. SEM micrographs were used to extract the size distribution of the migrated silver particles over the glass surface.

Niry, M. D.; Khalesifard, H. R. [Department of Physics, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731 (Iran, Islamic Republic of); Optics Research Center, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731 (Iran, Islamic Republic of); Mostafavi-Amjad, J.; Ahangary, A. [Department of Physics, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731 (Iran, Islamic Republic of); Azizian-Kalandaragh, Y. [Department of Physics, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731 (Iran, Islamic Republic of); Department of Physics, University of Mohaghegh Ardabili (UMA), P.O. Box 179, Ardabil (Iran, Islamic Republic of)

2012-02-01T23:59:59.000Z

249

Template Synthesis of Ordered Pt Nanorods in Porous Anodic Alumina Yar-Ming Wang, Hong-Hsiang Kuo, and Mark W. Verbrugge  

E-Print Network [OSTI]

, Singapore 639798 High-purity aluminum was anodized to form an alumina coating layer (typically 10 to 30 µm composite layer could be used as an oxidizing catalyst for automotive applications. The morphologies (Fig. 1B) obtained after removing the front surface of the aluminum oxide have been observed using

Zhou, Wei

250

The Growth of Silver on an Ordered Alumina Surface K. Luo, X. Lai, C.-W. Yi, K. A. Davis, K. K. Gath, and D. W. Goodman*  

E-Print Network [OSTI]

. Gath, and D. W. Goodman* Department of Chemistry, Texas A&M UniVersity, P.O. Box 30012, College Station with the Ag sublimation energy decreasing with decreasing cluster size. Introduction Alumina-supported silver near zero at 700 K and relatively small sublimation energies have been reported for Ag on R-Al2O3(112h0

Goodman, Wayne

251

Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents  

SciTech Connect (OSTI)

The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur. and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide. but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur. resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium.

Baltrus, J.P.; Granite, E.J.; Rupp, E.C.; Stanko, D.C.; Howard, B.; Pennline, H.W.

2011-01-01T23:59:59.000Z

252

[sup 27]Al NMR, GT-IR and ethanol-[sup 18]O TPD characterization of fluorided alumina  

SciTech Connect (OSTI)

New environmental legislation in the United States requiring reformulation of gasoline and diesel fuels is making its necessary to develop better, alternative acid catalysts for alkylation and isomerization reactions, and for hydrotreating catalysts for sulfur and nitrogen removal from refinery streams. A series of F/Al[sub 2]O[sub 3] samples (wt % F = 0 to 20) has been studied using a combination of solid-state [sup 27]Al NMR, FT-IR, and ethanol-[sup 18]O TPD techniques. Solid-state [sup 27]Al NMR is particularly sensitive to amorphous phases or small crystallites present on the catalyst surface, many of which cannot be detected by XRD. [sup 27]Al NMR shows the presence of three types of AlF[sub 3](H[sub 2]O)[sub n] species (with n varying between 0 and 3) on fluorided alumina. FT-IR studies of ethanol adsorption show that fluoride blocks the sites required for dissociative chemisorption of ethanol. A similar analysis of adsorbed pyridine shows an increase in the number of Broensted acid sites with the addition of up to 10 wt % fluoride. However, increasing the fluoride loading to 20 wt % decreases the number of Broensted acid sites. The TPD of ethanol-[sup 18]O from F/Al[sub 2]O[sub 3] samples shows that at low levels fluoride serves to block Lewis acid sites, but at higher levels its predominant role is to increase the Broensted acidity of the alumina surface. The pyridine adsorption and TPD experiments show that fluoride strengthens the remaining Lewis acid sites. 14 figs., 3 tabs.

DeCanio, E.C. (Texaco R D Dept., Beacon, NY (United States) Wesleyan Univ., Middletown, CT (United States)); Bruno, J.W. (Wesleyan Univ., Middletown, CT (United States)); Nero, V.P.; Edwards, J.C. (Texaco R D Dept., Beacon, NY (United States))

1993-03-01T23:59:59.000Z

253

Effect of Alumina and Titania on the Oxidation of CO over Au Nanoparticles Evaluted by 13C Isotopic Transient Analysis  

SciTech Connect (OSTI)

Titania- and alumina-supported Au nanoparticles were synthesized by a deposition-precipitation method and subsequent thermal treatment in He. X-ray absorption spectroscopy at the Au-L{sub III} edge revealed that the as-prepared Au/TiO{sub 2} sample contained cationic Au that was reduced to a predominately metallic state after treatment in He at 623 K. Scanning transmission electron microscopy showed the Au to be highly dispersed over both the metal oxides, with an average particle size of 3.3 nm for Au/TiO{sub 2} and 2.5 nm for Au/Al{sub 2}O{sub 3}. The global rate, apparent activation energy, and orders of reaction with respect to CO and O{sub 2} of CO oxidation were different for the two metal oxide-supported samples. Steady-state isotopic transient kinetic analysis was used to explore the intrinsic turnover frequency (TOF{sub intr}) and coverage of active carbon-containing intermediates ({theta}{sub COx}) that led to carbon dioxide during CO oxidation. After correcting for CO{sub 2} readsorption, the TOF{sub intr} was found to be independent of temperature, approximately 3.4 s{sup -1} for Au/TiO{sub 2} (261-303 K) and 2.1 s{sup -1} for Au/Al{sub 2}O{sub 3} (272-343 K). At 293 K, the coverage of active carbon-containing intermediates was greater over Au/TiO{sub 2} than over Au/Al{sub 2}O{sub 3}. The higher coverage of species-forming product on Au/TiO{sub 2} is attributed to the greater availability of active surface oxygen on a titania catalyst compared with an alumina catalyst.

Calla,J.; Bore, M.; Datye, A.; Davis, R.

2006-01-01T23:59:59.000Z

254

Effects of dispersion and support on adsorption, catalytic and electronic properties of cobalt/alumina CO hydrogenation catalysts: Annual progress report, August 1, 1987-July 31, 1988  

SciTech Connect (OSTI)

An investigation of the effects of surface structure, dispersion, and support on the adsorption, catalytic, and electronic properties of cobalt/alumina is described, the objectives of which are to determine (1) the effects of surface structure and metal dispersion on the adsorption and catalytic properties of cobalt and (2) the effects of decorating support species on metal crystallites and of direct electronic interactions between metal clusters and support, on the adsorption, catalytic and electronic properties of cobalt supported on alumina. During the first year effects of surface structure and dispersion on the adsorption, activity/selectivity, and electronic properties of Co/W single crystal surfaces and alumina-supported cobalt were investigated in a surface science investigation, lab reactor studies, TPD/TPSR studies, and a Moessbauer spectroscopy study. The structure, stability, surface electronic properties, and chemisorptive properties of vapor-deposited cobalt overlayers (0-4 ML) on W(110) and W(100) were studied by Auger electron spectroscopy, low energy electron diffraction, work function changes, and temperature programmed desorption (TPD) of cobalt, hydrogen, and carbon monoxide. The CO chemisorptive properties of the two cobalt overlayers are quite different, CO adsorption being dissociative on the W(100) surface and nondissociative on the W(110) surface; comparison of the results with those for Ni/W(100) indicate that Co/W(100) as a result of electronic interaction with the tungsten substrate. Activities and selectivities of cobalt/alumina catalysts for CO hydrogenation prepared by decomposition of Co/sub 4/(CO)/sub 12/ were determined as functions of metal loading, dispersion, and extent of reduction. Steady-state activity and product molecular weight were found to increase with increasing metal loading (decreasing dispersion and increasing extent of reduction). 10 refs.

Bartholomew, C.H.

1988-08-22T23:59:59.000Z

255

X-ray Absorption Measurements on Nickel Cathode of Sodium-beta Alumina batteries: Fe-Ni-CI Chemical Associations  

SciTech Connect (OSTI)

Sections of Na-Al-NiCl2 cathodes from sodium-beta alumina ZEBRA batteries have been characterized with X-ray fluorescence mapping, and XANES measurements to probe the microstructure, elemental correlation, and chemical speciation after voltage cycling. Cycling was performed under identical load conditions at either 240 or 280 C operating temperature and subsequently quenched in either the charged or discharged state. X-ray fluorescence mapping and XANES measurements were made adjacent to the current collector and ?"-Al2O3 solid electrolyte interfaces to detect possible gradients in chemical properties across the cathode. An FeS additive, introduced during battery synthesis, was found to be present as either Fe metal or an Fe(II) chloride in all cathode samples. X-ray fluorescence mapping reveals an operating temperature and charge-state dependent spatial correlation between Fe, Ni, and Cl concentration. XANES measurements indicate that both Ni and Fe are chemically reactive and shift between metallic and chloride phases in the charged and discharged states, respectively. However the percentage of chemically active Ni and Fe is significantly less in the cell operated at lower temperature. Additionally, the cathode appeared chemically homogeneous at the scale of our X-ray measurements.

Bowden, Mark E.; Alvine, Kyle J.; Fulton, John L.; Lemmon, John P.; Lu, Xiaochuan; Webb-Robertson, Bobbie-Jo M.; Heald, Steve M.; Balasubramanian, Mahalingam; Mortensen, Devon R.; Seidler, Gerald T.; Hess, Nancy J.

2014-02-01T23:59:59.000Z

256

Manufacture of Alumina-Forming Austenitic Stainless Steel Alloys by Conventional Casting and Hot-Working Methods  

SciTech Connect (OSTI)

Oak Ridge National Laboratory (ORNL) and Carpenter Technology Corporation (CarTech) participated in an in-kind cost share cooperative research and development agreement (CRADA) effort under the auspices of the Energy Efficiency and Renewable Energy (EERE) Technology Maturation program to explore the feasibility for scale up of developmental ORNL alumina-forming austenitic (AFA) stainless steels by conventional casting and rolling techniques. CarTech successfully vacuum melted 30lb heats of four AFA alloy compositions in the range of Fe-(20-25)Ni-(12-14)Cr-(3-4)Al-(1-2.5)Nb wt.% base. Conventional hot/cold rolling was used to produce 0.5-inch thick plate and 0.1-inch thick sheet product. ORNL subsequently successfully rolled the 0.1-inch sheet to 4 mil thick foil. Long-term oxidation studies of the plate form material were initiated at 650, 700, and 800 C in air with 10 volume percent water vapor. Preliminary results indicated that the alloys exhibit comparable (good) oxidation resistance to ORNL laboratory scale AFA alloy arc casting previously evaluated. The sheet and foil material will be used in ongoing evaluation efforts for oxidation and creep resistance under related CRADAs with two gas turbine engine manufacturers. This work will be directed to evaluation of AFA alloys for use in gas turbine recuperators to permit higher-temperature operating conditions for improved efficiencies and reduced environmental emissions.

Brady, M.P.; Yamamoto, Y.; Magee, J.H. (Carpenter Technol. Corp.)

2009-03-23T23:59:59.000Z

257

Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage  

SciTech Connect (OSTI)

Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350C) due to poor wettability of sodium on the surface of ?"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150C. The cells can even operate at 95C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

2014-08-01T23:59:59.000Z

258

Optical absorption and fluorescence properties of Er{sup 3+}/Yb{sup 3+} codoped lead bismuth alumina borate glasses  

SciTech Connect (OSTI)

Lead bismuth alumina borate glasses codoped with Er{sup 3+}/Yb{sup 3+} were prepared by melt quenching technique. Optical absorption, FTIR and photoluminescence spectra of these glasses have been studied. Judd-Ofelt theory has been applied to to the f ? f transitions for evaluating ?{sub 2}, ?{sub 4} and ?{sub 6} parameters. Radiative properties like branching ratio ?{sub r} and the radiative life time ?{sub R} have been determined on the basis of Judd-Ofelt theory. Upconversion emissions have been observed under 980nm laser excitation at room temperature. Green and red up-conversion emissions are centered at 530, 550 and 656 nm corresponding to {sup 2}H{sub 11/2}?{sup 4}I{sub 15/2}, {sup 4}S{sub 3/2}?{sup 4}I{sub 15/2} and {sup 4}F{sub 9/2}?{sup 4}I{sub 15/2} transitions of Er{sup 3+} respectively. The results obtained are discussed quantitatively based on the energy transfer between Yb{sup 3+} and Er{sup 3+}.

Goud, K. Krishna Murthy, E-mail: krishnamurthy.phy@gmail.com; Reddy, M. Chandra Shekhar, E-mail: krishnamurthy.phy@gmail.com; Rao, B. Appa, E-mail: krishnamurthy.phy@gmail.com [Dept. of Physics, Osmania University, Hyderabad-500007, Andhra Pradesh (India)

2014-04-24T23:59:59.000Z

259

"Rest" Creates Momentum  

E-Print Network [OSTI]

to competition among operators. Another display recently generated for the operators is used to support an energy conservation project on the lime kiln. In this display, shown in Figure 5, the energy consumption in millions of BTUs per ton of product... is displayed and graphed. Also, included for the operators benefit is a dust loss calculation that is intended to help the operator optimize his operation by giving continual feedback on the amount of dust lost from the kiln. The operator can take...

Cox, D.

260

Processing and microstructural evolution of alumina/aluminum alloy and aluminum nitride/aluminum alloy composites by directed melt oxidation. Ph.D. Thesis  

SciTech Connect (OSTI)

An experimental investigation on the directed oxidation of aluminum-zinc alloys to produce alumina/aluminum alloy composites with and without alumina preforms has been conducted. It has been suggested in the literature that Al-Mg alloys grow composites by the dissolution of a magnesia surface layer and reprecipitation of alumina in the composite. The intent of this investigation is to reveal relevant distinctions in the proposed dissolution-reprecipitation process as they apply to a more commercially interesting Zn containing alloy with a reinforcing preform. The TGA behavior and microstructural observations on the oxidation of Al-10Zn-8Si alloys were coupled with a thermodynamic and kinetic analysis to develop a composite growth model. Experiments were carried out in air at 1000-1200 C. At the higher temperatures (greater than 1100 C), Al2O3/Al composites grow by dissolving a ZnAl2O4 (spinel) surface layer. The dissolution process releases oxygen that reprecipitates in the form of Al2O3 on the existing composite, and also releases Zn and Al which migrate upward through the spinel to regenerate the surface oxide. Composite growth may only occur when the surface regenerates at a rate comparable with that of the dissolution process. At the lower temperatures, 1000 C, the composite growth is limited by the spinel regeneration process, and becomes intermittent. The addition of Mg to this alloy allows normal composite growth by the dissolution of a surface (Zn,Mg)Al2O4 layer at the lower temperatures, 980-1060 C, but leads to heterogeneous microstructures with voids as the temperature increases above approximately 1060 C. The directed oxidation of an Al-Zn alloy into porous alumina preforms yields an Al2O3/Al composite matrix which fills the preform interstices. Al-10Zn-8Si-0.25Mg alloys that are oxidized from 960-1100 C, and Al-10Zn-8Si alloys that are oxidized at 800-1000 C climb up the preform particle.

Crudele, S.D.

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Ceramic Technology Project database: September 1990 summary report. [SiC, SiN, whisker-reinforced SiN, ZrO-toughened aluminas, zirconias, joints  

SciTech Connect (OSTI)

Data generated within the Ceramic Technology Project (CTP) represent a valuable resource for both research and industry. The CTP database was created to provide easy access to this information in electronic and hardcopy forms by using a computerized database and by issuing periodic hardcopy reports on the database contents. This report is the sixth in a series of semiannual database summaries and covers recent additions to the database, including joined brazed specimen test data. It covers 1 SiC, 34 SiN, 10 whisker-reinforced SiN, 2 zirconia-toughened aluminas, 8 zirconias, and 34 joints.

Keyes, B.L.P.

1992-06-01T23:59:59.000Z

262

Effects of Lime and Carbonate of Lime on Acid Phosphate.  

E-Print Network [OSTI]

.50 .58 .05 -05 .36 .34 .56 .41 .45 day. 12.96 12 86 12:40 7.55 1.14 14 .14 .I5 .21 .32 1.17 4.08 2.80 1.40 .58 .05 .05 .30 .46 .56 1.34 .98 .81 days. 12.98 13 00 12:23 7.58 1.06 .OO days. --- 1.3.10 13 08 12... .03 .03 .41 .GO.. 1.84 1.13 1.06 16 14 .15 .17 .23 .28 .4P, 2.26 3.90 2.65 1.28 .53 .03 .03 .23 .34 .41 1.39 1.03 .76 .20 .25 .32 323 3.95 2.55 1.10 .53 .05 .05 .25 .34 -40 1.61 .93 .76 As was to be expected...

Fraps, G. S. (George Stronach)

1917-01-01T23:59:59.000Z

263

Method and system for the combination of non-thermal plasma and metal/metal oxide doped .gamma.-alumina catalysts for diesel engine exhaust aftertreatment system  

DOE Patents [OSTI]

The present disclosure pertains to a system and method for treatment of oxygen rich exhaust and more specifically to a method and system that combines non-thermal plasma with a metal doped .gamma.-alumina catalyst. Current catalyst systems for the treatment of oxygen rich exhaust are capable of achieving only approximately 7 to 12% NO.sub.x reduction as a passive system and only 25 40% reduction when a supplemental hydrocarbon reductant is injected into the exhaust stream. It has been found that treatment of an oxygen rich exhaust initially with a non-thermal plasma and followed by subsequent treatment with a metal doped .gamma.-alumina prepared by the sol gel method is capable of increasing the NO.sub.x reduction to a level of approximately 90% in the absence of SO.sub.2 and 80% in the presence of 20 ppm of SO.sub.2. Especially useful metals have been found to be indium, gallium, and tin.

Aardahl, Christopher L. (Richland, WA); Balmer-Miller, Mari Lou (West Richland, WA); Chanda, Ashok (Peoria, IL); Habeger, Craig F. (West Richland, WA); Koshkarian, Kent A. (Peoria, IL); Park, Paul W. (Peoria, IL)

2006-07-25T23:59:59.000Z

264

Matrix-grain-bridging contributions to the toughness of SiC composites with alumina-coated SiC platelets  

SciTech Connect (OSTI)

Silicon carbide composites were fabricated through the incorporation of alumina-coated SiC platelets into a SiC matrix. Mechanical properties were evaluated in direct comparison with a commercial Hexoloy SiC. The fracture toughness of the composite, with a fine grained {beta}-SiC matrix, was twice that of the commercial material. The alumina-coating on the platelets provided a weak interface to promote crack deflection and platelet bridging, as well as easing densification of the composites. On the other hand, a three-fold increase in fracture toughness (9.1 MPa {radical}m) of an in situ toughened monolithic SiC was achieved by processing at higher temperatures, promoting the {beta}-to-{alpha} phase transformation and forming a microstructure containing high-aspect-ration plate-shaped grains. Efforts were made to combine the effects of coated-platelets reinforcement and in situ toughening in the matrix. Moderate high toughness (8 MPa {radical}m) was achieved by coupled toughening. The contribution of matrix-grain-bridging, however, was limited by the processing temperature at which the oxide coating was stable.

Cao, J.J.; He, Y.; MoberlyChan, W.J.; De Jonghe, L.C. [Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Mineral Engineering]|[Lawrence Berkeley Lab., CA (United States). Materials Science Div.

1996-05-01T23:59:59.000Z

265

Lime Wind | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's Heat JumpInc Place:KeystoneSolar (Texas) Jump to:LignoKem Jump to:

266

Temperature dependent dielectric function in the near-infrared to vacuum-ultraviolet ultraviolet spectral range of alumina and yttria stabilized zirconia thin films  

SciTech Connect (OSTI)

The dielectric function of nano-/polycrystalline alumina and yttria stabilised zirconia thin films has been investigated in a wide spectral range from 1.0?eV to 7.5?eV and temperatures between 10?K and room temperature. In the near band-edge spectral range, we found a broad distribution of optical transitions within the band gap, the so-called Urbach absorption tail which is typical for amorphous or polycrystalline materials due to the lack of long range order in the crystal structure. The coupling properties of the electronic system to the optical phonon bath and thermal lattice vibrations strongly depend on the ratio of the spectral extent of these disorder states to the main phonon energy, which we correlate with the different crystalline structure of our samples. The films have been grown at room temperature and 650?C by pulsed laser deposition.

Schmidt-Grund, R., E-mail: Schmidt-Grund@physik.uni-leipzig.de; Lhmann, T.; Bntgen, T.; Franke, H.; Lorenz, M.; Grundmann, M. [Fakultt fr Physik und Geowissenschaften, Institut fr Experimentelle Physik II, Universitt Leipzig, Linnstr. 5, D-04103 Leipzig (Germany); Opper, D. [PANalytical GmbH, Nrnberger Strae 113, D-34123 Kassel (Germany)

2013-12-14T23:59:59.000Z

267

Review of composting and anaerobic digestion of municipal solid waste and a methodological proposal for a mid-size city  

E-Print Network [OSTI]

with wastewater sludge, wood ash, coal ash, lime-kiln dust, and/or limestone quarry dust to improve the profile systems [Block & Goldstein 2000]. Anaerobic composting is not well used in the U.S until now [Goldstein of the process, the methane gas ("cleaner energy") and harvesting materials from MSW to #12;either recycle

Wisconsin-Milwaukee, University of

268

Thermochimie solaire hautes tempratures, rsultats exprimentaux. Quelques perspectives d'application  

E-Print Network [OSTI]

of energy and the industrial production of lime or portland cement, using fluidized bed reactor or rotary kiln. This type of chemical reactor has been studied with small solar furnaces (power : ~ 2 k vertical (puissance utile Pu = 1,4 kW), le lit fluidis (Fig. 1) est constitu, pour l'essentiel. d'un tube

Paris-Sud XI, Universit de

269

Development of Surface Complexation Models of Cr(VI) Adsorption on Soils, Sediments and Model Mixtures of Kaolinite, Montmorillonite, ?-Alumina, Hydrous Manganese and Ferric Oxides and Goethite  

SciTech Connect (OSTI)

Hexavalent chromium is a highly toxic contaminant that has been introduced into aquifers and shallow sediments and soils via many anthropogenic activities. Hexavalent chromium contamination is a problem or potential problem in the shallow subsurface at several DOE sites, including Hanford, Idaho National Laboratory, Los Alamos National Laboratory and the Oak Ridge Reservation (DOE, 2008). To accurately quantify the fate and transport of hexavalent chromium at DOE and other contaminated sites, robust geochemical models, capable of correctly predicting changes in chromium chemical form resulting from chemical reactions occurring in subsurface environments are needed. One important chemical reaction that may greatly impact the bioavailability and mobility of hexavalent chromium in the subsurface is chemical binding to the surfaces of particulates, termed adsorption or surface complexation. Quantitative thermodynamic surface complexation models have been derived that can correctly calculate hexavalent chromium adsorption on well-characterized materials over ranges in subsurface conditions, such pH and salinity. However, models have not yet been developed for hexavalent chromium adsorption on many important constituents of natural soils and sediments, such as clay minerals. Furthermore, most of the existing thermodynamic models have been developed for relatively simple, single solid systems and have rarely been tested for the complex mixtures of solids present in real sediments and soils. In this study, the adsorption of hexavalent chromium was measured as a function of pH (3-10), salinity (0.001 to 0.1 M NaNO3), and partial pressure of carbon dioxide(0-5%) on a suite of naturally-occurring solids including goethite (FeOOH), hydrous manganese oxide (MnOOH), hydrous ferric oxide (Fe(OH)3), ?-alumina (Al2O3), kaolinite (Al2Si2O5(OH)4), and montmorillonite (Na3(Al, Mg)2Si4O10(OH)2?nH2O). The results show that all of these materials can bind substantial quantities of hexavalent chromium, especially at low pH. Unexpectedly, experiments with the clay minerals kaolinite and montmorillonite suggest that hexavalent chromium may interact with these solids over much longer periods of time than expected. Furthermore, hexavalent chromium may irreversibly bind to these solids, perhaps because of oxidation-reduction reactions occurring on the surfaces of the clay minerals. More work should be done to investigate and quantify these chemical reactions. Experiments conducted with mixtures of goethite, hydrous manganese oxide, hydrous ferric oxide, ?-alumina, montmorillonite and kaolinite demonstrate that it is possible to correctly predict hexavalent chromium binding in the presence of multiple minerals using thermodynamic models derived for the simpler systems. Further, these models suggest that of the six solid considered in this study, goethite is typically the solid to which most of the hexavalent chromium will bind. Experiments completed with organic-rich and organic-poor natural sediments demonstrate that in organic-rich substrates, organic matter is likely to control uptake of the hexavalent chromium. The models derived and tested in this study for hexavalent chromium binding to ?-alumina, hydrous manganese oxide, goethite, hydrous ferric oxide and clay minerals can be used to better predict changes in hexavalent chromium bioavailability and mobility in contaminated sediments and soils.

Koretsky, Carla [Western Michigan University] [Western Michigan University

2013-11-29T23:59:59.000Z

270

Research and Development of a New Silica-Alumina Based Cementitious Material Largely Using Coal Refuse for Mine Backfill, Mine Sealing and Waste Disposal Stabilization  

SciTech Connect (OSTI)

Coal refuse and coal combustion byproducts as industrial solid waste stockpiles have become great threats to the environment. To activate coal refuse is one practical solution to recycle this huge amount of solid waste as substitute for Ordinary Portland Cement (OPC). The central goal of this project is to investigate and develop a new silica-alumina based cementitious material largely using coal refuse as a constituent that will be ideal for durable construction, mine backfill, mine sealing and waste disposal stabilization applications. This new material is an environment-friendly alternative to Ordinary Portland Cement. The main constituents of the new material are coal refuse and other coal wastes including coal sludge and coal combustion products (CCPs). Compared with conventional cement production, successful development of this new technology could potentially save energy and reduce greenhouse gas emissions, recycle vast amount of coal wastes, and significantly reduce production cost. A systematic research has been conducted to seek for an optimal solution for enhancing pozzolanic reactivity of the relatively inert solid waste-coal refuse in order to improve the utilization efficiency and economic benefit as a construction and building material.

Henghu Sun; Yuan Yao

2012-06-29T23:59:59.000Z

271

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: the effect of protective alumina coating on electrical stability in dual environment  

SciTech Connect (OSTI)

An alkali-containing silicate glass was recently proposed as a potential sealant for solid oxide fuel cells (SOFC). The glass contains appreciable amount of alkalis and retains its glassy microstructure at elevated temperatures over time. It is more compliant as compared to conventional glass-ceramics sealants and could potentially heal cracks during thermal cycling. In previous papers the thermal cycle stability, thermal stability and chemical compatibility were reported with yttria-stabilized zirconia (YSZ) electrolyte and YSZ-coated ferritic stainless steel interconnect. In this paper, we report the electrical stability of the compliant glass with aluminized AISI441 interconnect material under DC load in dual environment at 700-800oC. Apparent electrical resistivity was measured with a 4-point method for the glass sealed between two aluminized AISI441 metal coupons as well as plain AISI441 substrates. The results showed good electrical stability with the aluminized AISI441 substrate, while unstable behavior was observed for un-coated substrates. In addition, interfacial microstructure was examined with scanning electron microscopy and correlated with the measured resistivity results. Overall, the alumina coating demonstrated good chemical stability with the alkali-containing silicate sealing glass under DC loading.

Chou, Y. S.; Choi, Jung-Pyung; Stevenson, Jeffry W.

2012-12-01T23:59:59.000Z

272

Kinetics of the reaction of iron blast furnace slag/hydrated lime sorbents with SO{sub 2} at low temperatures: effects of the presence of CO{sub 2}, O{sub 2}, and NOx  

SciTech Connect (OSTI)

The effects of the presence of CO{sub 2}, O{sub 2}, and NOx in the flue gas on the kinetics of the sulfation of blast furnace slag/hydrated lime sorbents at low temperatures were studied using a differential fixed-bed reactor. When O{sub 2} and NOx were not present simultaneously, the reaction kinetics was about the same as that under the gas mixtures containing SO{sub 2}, H{sub 2}O, and N{sub 2} only, being affected mainly by the relative humidity. The sulfation of sorbents can be described by the surface coverage model and the model equations derived for the latter case. When both O{sub 2} and NOx, were present, the sulfation of sorbents was greatly enhanced, forming a great amount of sulfate in addition to sulfite. The surface coverage model is still valid in this case, but the model equations obtained show a more marked effect of relative humidity and negligible effects of SO{sub 2} concentration and temperature on the reaction. The effect of sorbent composition on the reaction kinetics was entirely represented by the effects of the initial specific surface area (S{sub g0}) and the Ca molar content (M{sup -1}) of sorbent. The initial conversion rate of sorbent increased linearly with increasing S{sub g0}, and the ultimate conversion increased linearly with increasing S{sub g0}M{sup -1}. The model equations obtained in this work are applicable to describe the kinetics of the sulfation of the sorbents in the low-temperature dry and semidry fine gas desulfurization processes either with an upstream NOx, removal unit or without.111

Liu, C.F.; Shih, S.M. [Industrial Technological Research Institute, Hsinchu (Taiwan)

2009-09-15T23:59:59.000Z

273

ancient ceramic kilns: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

j and the magnetic field H in Bi2Sr2CaCu2O8 x ceramics. We provided in high-Tc superconduct- ing granular ceramics remain an intriguing subject of inten- sive investigations...

274

Alumina-based ceramic composite  

DOE Patents [OSTI]

An improved ceramic composite comprising oxide ceramic particulates, nonoxide ceramic particulates selected from the group consisting of carbides, borides, nitrides of silicon and transition metals and mixtures thereof, and a ductile binder selected from the group consisting of metallic, intermetallic alloys and mixtures thereof is described. The ceramic composite is made by blending powders of the ceramic particulates and the ductile to form a mixture and consolidating the mixture of under conditions of temperature and pressure sufficient to produce a densified ceramic composite. 5 figs.

Alexander, K.B.; Tiegs, T.N.; Becher, P.F.; Waters, S.B.

1996-07-23T23:59:59.000Z

275

Alumina-based ceramic composite  

DOE Patents [OSTI]

An improved ceramic composite comprising oxide ceramic particulates, nonoxide ceramic particulates selected from the group consisting of carbides, borides, nitrides of silicon and transition metals and mixtures thereof, and a ductile binder selected from the group consisting of metallic, intermetallic alloys and mixtures thereof is described. The ceramic composite is made by blending powders of the ceramic particulates and the ductile to form a mixture and consolidating the mixture of under conditions of temperature and pressure sufficient to produce a densified ceramic composite.

Alexander, Kathleen B. (Oak Ridge, TN); Tiegs, Terry N. (Lenoir City, TN); Becher, Paul F. (Oak Ridge, TN); Waters, Shirley B. (Knoxville, TN)

1996-01-01T23:59:59.000Z

276

Climate VISION: Private Sector Initiatives: Lime  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite-- Energy, science, and technologyLettersLetters of

277

Climate VISION: Private Sector Initiatives: Lime: Results  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing,-- Energy, science,Links - TechnicalGHGGHGResults The National

278

Exhaust-catalyst development for methanol-fueled vehicles. II. Synergism between palladium and silver in methanol and carbon monoxide oxidation over an alumina-supported palladium-silver catalyst  

SciTech Connect (OSTI)

Methanol and carbon monoxide oxidation were examined over 0.01 Pd, 5% Ag, and 0.01% Pd/5% Ag catalysts - all supported on ..gamma..-alumina. The bimetallic catalyst showed greater CO and CH/sub 3/OH oxidation activity than either of the single-component catalysts; moreover, the Pd and Ag interacted synergistically in the bimetallic catalyst to produce greater CO and CH/sub 3/OH oxidation rates and lower yields of methanol partial oxidation products than expected from a mixture of the single-component catalysts. Temperature-programmed oxidation experiments and reactivity experiments involving changes in O/sub 2/ partial pressure both provided evidence that the Pd-Ag synergism results from Pd promoting the rate of O/sub 2/ adsorption and reaction with CO and CH/sub 3/OH on Ag. The data also indicate that virtually all of the Pd in the bimetallic catalyst is present in Pd-Ag crystallites.

McCabe, R.W.; Mitchell, P.J.

1987-02-01T23:59:59.000Z

279

Paper submitted to 12th SolarPACES International Symposium, October 6-8, 2004, Oaxaca, Mexico  

E-Print Network [OSTI]

is split between electricity and transport use. Estimates of the global anthropogenic CO2 emissions from calcination reaction CaCO3 CaO + CO2 at 1200-1400 K. The indirect heating 10 kW multi-tube rotary kiln% the CO2 emissions in a state-of-the-art lime plant and by 40% in a conventional cement plant. The cost

280

Performance evaluation of ALCAN-AASF50-ferric coated activated alumina and granular ferric hydroxide (GFH) for arsenic removal in the presence of competitive ions in an active well :Kirtland field trial - initial studies.  

SciTech Connect (OSTI)

This report documents a field trial program carried out at Well No.15 located at Kirtland Air Force Base, Albuquerque, New Mexico, to evaluate the performance of two relatively new arsenic removal media, ALCAN-AASF50 (ferric coated activated alumina) and granular ferric hydroxide (US Filter-GFH). The field trial program showed that both media were able to remove arsenate and meet the new total arsenic maximum contaminant level (MCL) in drinking water of 10 {micro}g/L. The arsenate removal capacity was defined at a breakthrough effluent concentration of 5 {micro}g/L arsenic (50% of the arsenic MCL of 10 {micro}g/L). At an influent pH of 8.1 {+-} 0.4, the arsenate removal capacity of AASF50 was 33.5 mg As(V)/L of dry media (29.9 {micro}g As(V)/g of media on a dry basis). At an influent pH of 7.2 {+-} 0.3, the arsenate removal capacity of GFH was 155 mg As(V)/L of wet media (286 {micro}g As(V)/g of media on a dry basis). Silicate, fluoride, and bicarbonate ions are removed by ALCAN AASF50. Chloride, nitrate, and sulfate ions were not removed by AASF50. The GFH media also removed silicate and bicarbonate ions; however, it did not remove fluoride, chloride, nitrate, and sulfate ions. Differences in the media performance partly reflect the variations in the feed-water pH between the 2 tests. Both the exhausted AASF50 and GFH media passed the Toxicity Characteristic Leaching Procedure (TCLP) test with respect to arsenic and therefore could be disposed as nonhazardous waste.

Neidel, Linnah L.; Krumhansl, James Lee; Siegel, Malcolm Dean; Khandaker, Nadim Reza

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

NUCLEAR POWERED CO2 CAPTURE FROM THE ATMOSPHERE  

SciTech Connect (OSTI)

A process for capturing CO{sub 2} from the atmosphere was recently proposed. This process uses a closed cycle of sodium and calcium hydroxide, carbonate, and oxide transformations to capture dilute CO{sub 2} from the atmosphere and to generate a concentrated stream of CO{sub 2} that is amenable to sequestration or subsequent chemical transformations. In one of the process steps, a fossil-fueled lime kiln is needed, which reduces the net CO{sub 2} capture of the process. It is proposed to replace the fossil-fueled lime kiln with a modified kiln heated by a high-temperature nuclear reactor. This will have the effect of eliminating the use of fossil fuels for the process and increasing the net CO{sub 2} capture. Although the process is suitable to support sequestration, the use of a nuclear power source for the process provides additional capabilities, and the captured CO{sub 2} may be combined with nuclear-produced hydrogen to produce liquid fuels via Fischer-Tropsch synthesis or other technologies. Conceivably, such plants would be carbon-neutral, and could be placed virtually anywhere without being tied to fossil fuel sources or geological sequestration sites.

Sherman, S

2008-09-22T23:59:59.000Z

282

Quantifying the Co-benefits of Energy-Efficiency Programs: A Case Study of the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

ingredient in cement: vertical shaft kilns and rotary kilns.cement was produced by plants using outdated vertical shaft kilns (Vertical shaft kilns (Mt) Rotary (NSP + other) kilns (Mt) Clinker production (Mt) Clinker-cement

Hasanbeigi, Ali

2014-01-01T23:59:59.000Z

283

IMPROVED CORROSION RESISTANCE OF ALUMINA REFRACTORIES  

SciTech Connect (OSTI)

The initial objective of this project was to do a literature search to define the problems of refractory selection in the metals and glass industries. The problems fall into three categories: Economic--What do the major problems cost the industries financially? Operational--How do the major problems affect production efficiency and impact the environment? and Scientific--What are the chemical and physical mechanisms that cause the problems to occur? This report presents a summary of these problems. It was used to determine the areas in which the EERC can provide the most assistance through bench-scale and laboratory testing. The final objective of this project was to design and build a bench-scale high-temperature controlled atmosphere dynamic corrosion application furnace (CADCAF). The furnace will be used to evaluate refractory test samples in the presence of flowing corrodents for extended periods, to temperatures of 1600 C under controlled atmospheres. Corrodents will include molten slag, steel, and glass. This test should prove useful for the glass and steel industries when faced with the decision of choosing the best refractory for flowing corrodent conditions.

John P. Hurley; Patty L. Kleven

2001-09-30T23:59:59.000Z

284

Alumina-forming Austenitic Alloys Licensed | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technology Corporation March 13, 2013 Carpenter Technology Corporation has licensed a new alloy developed at the Oak Ridge National Laboratory. Carpenter Technology Corporation...

285

Alumina-forming Austenitic Alloys Licensed | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout theOFFICE OFFuelsPropane TankWashingtonAlternative Measures

286

Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers  

SciTech Connect (OSTI)

This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

Keiser, J.R.

2001-10-22T23:59:59.000Z

287

Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers  

SciTech Connect (OSTI)

This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

Keiser, J.R.

2000-04-18T23:59:59.000Z

288

Proceedings of the DOE/Industry Sensor Working Group meeting, Austin, Texas  

SciTech Connect (OSTI)

This paper report contains topics presented at a sensor workshop group meeting. The topics describe measuring instruments of use in the pulp and paper industry. Topics include: measurement of solids fraction; process instrumentation research for the pulp paper industry; real-time non-contact optical surface motion monitor; on-machine sensors to measure paper mechanical properties; hierarchical intelligent control of industrial processes -- an in-parallel lime kiln application; proposal for research on lignin concentration measurement in pulping liquors; and advanced polymeric sensor materials for industrial drying.

Not Available

1988-11-01T23:59:59.000Z

289

Lime pretreatment and enzymatic hydrolysis of corn stover  

E-Print Network [OSTI]

and then distributed to each column by the air-manifold having one input and 10 output fittings. Compressed nitrogen gas (Praxair Co., College Station, TX) was used to make the non-oxidative condition and supplied to each column by the N2-manifold after preheating...

Kim, Se Hoon

2005-08-29T23:59:59.000Z

290

Kinetic Modeling and Assessment of Lime Pretreatment of Poplar Wood  

E-Print Network [OSTI]

reaction Alcohol Standard Alcohol Co. Power Energy Fuels Lignocellulose Gasification CO/H2 Fermentation Alcohol Alico Inc., Bioenergy, Coskata Lignocellulose Acid Hydrolysis Sugar Fermentation Alcohol Arkenol, BlueFire Ethanol, Masada...

Sierra Ramirez, Rocio

2012-02-14T23:59:59.000Z

291

Lime Energy formerly Electric City Corporation | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey,(Monaster And Coolbaugh, 2007) JumpDesign JumpLily Lake,Corporation Jump

292

Climate VISION: Private Sector Initiatives: Lime - Energy Management  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing,-- Energy, science,Links - TechnicalGHG

293

Climate VISION: Private Sector Initiatives: Lime: GHG Inventory Protocols  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing,-- Energy, science,Links - TechnicalGHGGHG Inventory Protocols

294

Climate VISION: Private Sector Initiatives: Lime: Resource and Links  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing,-- Energy, science,Links - TechnicalGHGGHG Inventory

295

Climate VISION: Private Sector Initiatives: Lime: Resources and Links -  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing,-- Energy, science,Links - TechnicalGHGGHG InventoryIndustry

296

Climate VISION: Private Sector Initiatives: Lime: Resources and Links -  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing,-- Energy, science,Links - TechnicalGHGGHG

297

Climate VISION: Private Sector Initiatives: Lime: Work Plans  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing,-- Energy, science,Links - TechnicalGHGGHGResults The

298

Long-term lime pretreatment of poplar wood  

E-Print Network [OSTI]

Lignocellulosic biomass (e.g., poplar wood) provides a unique and sustainable resource for environmentally safe organic fuels and chemicals. The core of this study is the pretreatment step involved in bioconversion processes. Pretreatment...

Sierra Ramirez, Rocio

2006-04-12T23:59:59.000Z

299

Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry  

E-Print Network [OSTI]

the small cement plants, earthen vertical kiln (and hollowcement plant in North China utilizing vertical shaft kilnsCement Industry Technical Conference: 75- Replacing Vertical Shaft Kilns

Galitsky, Christina

2009-01-01T23:59:59.000Z

300

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

obsolete vertical shaft kiln (VSK) cement plants, with theobsolete vertical shaft kiln (VSK) cement plants, with theobsolete vertical shaft kiln (VSK) cement plants, with the

Price, Lynn

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Industrial Sector Energy Conservation Programs in the People's Republic of China during the Seventh Five-Year Plan (1986-1990)  

E-Print Network [OSTI]

of 165 conventional vertical cement kilns were mechanized,Small cement plants use vertical kilns and generally haveof cement kilns The mechanization of conventional vertical

Zhiping, L.

2010-01-01T23:59:59.000Z

302

Design of fuel efficient brick kiln for ceramic water filter firing in Ghana  

E-Print Network [OSTI]

Ceramic water filters are currently produced in Ghana in order to provide a household solution to contaminated water. These filters, locally branded with the name Kosim filter by originating from Potters for Peace-Nicaragua, ...

Adjorlolo, Eric (Eric James Kofi)

2007-01-01T23:59:59.000Z

303

Indirect-Fired Kiln Conserves Scrap Aluminum and Cuts Costs | Department of  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietipDepartment ofTheDepartment of2012Pathways toDayThe

304

Method for scavenging mercury  

DOE Patents [OSTI]

Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

2009-01-20T23:59:59.000Z

305

Method for scavenging mercury  

DOE Patents [OSTI]

Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

Chang, Shih-Ger (El Cerrito, CA); Liu, Shou-Heng (Kaohsiung, TW); Liu, Zhao-Rong (Beijing, CN); Yan, Naiqiang (Berkeley, CA)

2011-08-30T23:59:59.000Z

306

Method for scavenging mercury  

DOE Patents [OSTI]

Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

Chang, Shih-ger (El Cerrito, CA); Liu, Shou-heng (Kaohsiung, TW); Liu, Zhao-rong (Bejing, CN); Yan, Naiqiang (Burkeley, CA)

2010-07-13T23:59:59.000Z

307

National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China  

E-Print Network [OSTI]

87 kWh/t cement for vertical shaft kiln (VSK) production (cement is produced by either a rotary kiln or a verticalChinese Cement Kilns. Rotary Kiln Production Vertical Shaft

Zhou, Nan

2013-01-01T23:59:59.000Z

308

Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers  

E-Print Network [OSTI]

Modern Vertical Shaft Kiln Technology World Cement 1 26cement has ordered a vertical roller mill for the new kiln

Worrell, Ernst

2008-01-01T23:59:59.000Z

309

Life-Cycle Evaluation of Concrete Building Construction as a Strategy for Sustainable Cities  

E-Print Network [OSTI]

BTu/tonne cement) Baseline Portland Cement produced at wet kiln long dry kiln Coal Electricity Distillate (diesel)

Stadel, Alexander

2013-01-01T23:59:59.000Z

310

Potentials and policy implications of energy and material efficiency improvement  

E-Print Network [OSTI]

clinker cooler, use of waste fuels, dry-suspension preheater kilns Dry precalciner kilns, blended cements, cogeneration, high-temperature

Worrell, Ernst; Levine, Mark; Price, Lynn; Martin, Nathan; van den Broek, Richard; Block, Kornelis

1997-01-01T23:59:59.000Z

311

Effect of thermal residual stresses on the strength for both alumina/Ni/alumina and alumina/Ni/nickel alloy bimaterials  

E-Print Network [OSTI]

and improved over the past 60 years, among which solid-state diffusion bonding [27] and reactive metal brazing to ceramic materials. For a solid-state diffusion bonding, for which the wettability does not intervene or evaporation condensation mass transport pro- cesses. Therefore, the diffusion bonding process is made easier

Paris-Sud XI, Universit de

312

CO2-selective, Hybrid Membranes by Silation of Alumina  

SciTech Connect (OSTI)

Hybrid membranes are feasible candidates for the separation of CO2 from gas produced in coal-based power generation since they have the potential to combine the high selectivity of polymer membranes and the high permeability of inorganic membranes. An interesting method for producing hybrid membranes is the silation of an inorganic membrane. In this method, trichloro- or alkoxy-silanes interact with hydroxyl groups on the surface of ?-AlO3 or TiO2, binding organic groups to that surface. By varying the length of these organic groups on the organosilane, it should be possible to tailor the effective pore size of the membrane. Similarly, the addition of CO2-phillic groups to the silating agent allows for the careful control of surface affinity and the enhancement of surface diffusion mechanisms. This method of producing hybrid membranes selective to CO2 was first attempted by Hyun [1] who silated TiO2 with phenyltriethoxysilane. Later, Way [2] silated ?-AlO3 with octadecyltrichlorosilane. Both researchers were successful in producing membranes with improved selectivity toward CO2, but permeability was not maintained at a commercially applicable level. XPS data indicated that the silating agent did not penetrate into the membrane pores and separation actually occurred in a thin polymer-like surface layer. The present study attempts to overcome the mass transfer problems associated with this technique by producing the desired monolayer coverage of silane, and thus develop a highly-permeable CO2-selective hybrid membrane.

Luebke, D.R.; Pennline, H.W.

2007-09-01T23:59:59.000Z

313

alumina matrix composites: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences Websites Summary: -matrix composites Xiangcheng Luo, D.D.L. Chung* Composite Materials Research Laboratory, State University of New Abstract A carbon-matrix...

314

Torque magnetometry of an amorphous-alumina/strontium-titanate interface  

E-Print Network [OSTI]

We report torque magnetometry measurements of an oxide heterostructure consisting of an amorphous Al[subscript 2]O[subscript 3] thin film grown on a crystalline SrTiO[subscript 3] substrate (a-AO/STO) by atomic layer ...

Lee, S. W.

315

SLOW DEGRADATION AND ELECTRON INJECTION IN SODIUM-B ALUMINAS  

E-Print Network [OSTI]

S. Mitoff of the General Electric Research and Developmentobtained from the General Electric Research and Development

De Jonghe, Lutgard C.

2013-01-01T23:59:59.000Z

316

Nanotube fracture during the failure of carbon nanotube/ alumina composites  

E-Print Network [OSTI]

-based ceramic composites, leading to improved fracture toughness. ? 2011 Elsevier Ltd. All rights reserved. 1 problem, incorporation of particulates, flakes and short/long fibers into ceramics matrix, as a second, chemical and electrical properties [3­7], motivating their use in ceramic composite materials as a fibrous

317

ORNL's Alumina-forming Austenitic Alloys Licensed to Carpenter...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technology Corporation November 30, 2010 Carpenter Technology Corporation has licensed a new alloy developed at the Oak Ridge National Laboratory. Carpenter Technology Corporation...

318

Low Temperature Reduction of Alumina Using Fluorine Containing Ionic Liquids  

SciTech Connect (OSTI)

The major objective of the project is to establish the feasibility of using specific ionic liquids capable of sustaining aluminum electrolysis near room temperature at laboratory and batch recirculation scales. It will explore new technologies for aluminum and other valuable metal extraction and process methods. The new technology will overcome many of the limitations associated with high temperatures processes such as high energy consumption and corrosion attack. Furthermore, ionic liquids are non-toxic and could be recycled after purification, thus minimizing extraction reagent losses and environmental pollutant emissions. Ionic liquids are mixture of inorganic and organic salts which are liquid at room temperature and have wide operational temperature range. During the last several years, they were emerging as novel electrolytes for extracting and refining of aluminum metals and/or alloys, which are otherwise impossible using aqueous media. The superior high temperature characteristics and high solvating capabilities of ionic liquids provide a unique solution to high temperature organic solvent problems associated with device internal pressure build-up, corrosion, and thermal stability. However their applications have not yet been fully implemented due to the insufficient understanding of the electrochemical mechanisms involved in processing of aluminum with ionic liquids. Laboratory aluminum electrodeposition in ionic liquids has been investigated in chloride and bis (trifluoromethylsulfonyl) imide based ionic liquids. The electrowinning process yielded current density in the range of 200-500 A/m2, and current efficiency of about 90%. The results indicated that high purity aluminum (>99.99%) can be obtained as cathodic deposits. Cyclic voltammetry and chronoamperometry studies have shown that initial stages of aluminum electrodeposition in ionic liquid electrolyte at 30C was found to be quasi-reversible, with the charge transfer coefficient (0.40). Nucleation phenomena involved in aluminum deposition on copper in AlCl3-BMIMCl electrolyte was found to be instantaneous followed by diffusion controlled three-dimensional growth of nuclei. Diffusion coefficient (Do) of the electroactive species Al2Cl7 ion was in the range from 6.5 to 3.9107 cm2?s1 at a temperature of 30C. Relatively little research efforts have been made toward the fundamental understanding and modeling of the species transport and transformation information involved in ionic liquid mixtures, which eventually could lead to quantification of electrochemical properties. Except that experimental work in this aspect usually is time consuming and expensive, certain characteristics of ionic liquids also made barriers for such analyses. Low vapor pressure and high viscosity make them not suitable for atomic absorption spectroscopic measurement. In addition, aluminum electrodeposition in ionic liquid electrolytes are considered to be governed by multi-component mass, heat and charge transport in laminar and turbulent flows that are often multi-phase due to the gas evolution at the electrodes. The kinetics of the electrochemical reactions is in general complex. Furthermore, the mass transfer boundary layer is about one order of magnitude smaller than the thermal and hydrodynamic boundary layer (Re=10,000). Other phenomena that frequently occur are side reactions and temperature or concentration driven natural convection. As a result of this complexity, quantitative knowledge of the local parameters (current densities, ion concentrations, electrical potential, temperature, etc.) is very difficult to obtain. This situation is a serious obstacle for improving the quality of products, efficiency of manufacturing and energy consumption. The gap between laboratory/batch scale processing with global process control and nanoscale deposit surface and materials specifications needs to be bridged. A breakthrough can only be realized if on each scale the occurring phenomena are understood and quantified. Multiscale numerical modeling nevertheless can help t

Dr. R. G. Reddy

2007-09-01T23:59:59.000Z

319

Sources of sintering inhibition in tape-cost aluminas  

SciTech Connect (OSTI)

High-purity, lightly MgO-doped Al2O3 tapes were tape cast from slurries. Dilatometric data obtained in directions both parallel and perpendicular to the cast plane under constant-rate-of-heating conditions were utilized to evaluate all aspects of densification behavior during sintering. 38 refs.

Geho, M.; Palmour, H. III [Kanebo Ltd, Osaka (Japan)

1993-11-01T23:59:59.000Z

320

Alumina and Aluminum (2010 MECS) | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists' ResearchThe OfficeUtility Fed.9-0s) All OtherDepartment ofThis tip sheetManufacturing

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

MECS 2006 - Alumina and Aluminum | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of Energy Low-Temperature Combustion DemonstratorEastLynnF 742MEA

322

ORNL's Alumina-forming Austenitic Alloys Licensed to Carpenter Technology  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the ContributionsArms Control R&DNuclearNuclearCamilaOakmaterialFred Strohl Oak

323

Optimized Alumina Coagulants for Water Purification - Energy Innovation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 The 2002Optics Group (X-ray Science Division)ParallelHighPortal

324

Effects of atmospheres on bonding characteristics of silver and alumina. |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed NewcatalystNeutronEnvironmentZIRKLE FRUITYearEffect0/2002catalysts:|EffectsEMSL

325

ITP Aluminum: Alumina Technology Roadmap | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensionalthe U.S. Department ofIOWA

326

Microfluidic Investigation of Tracer Dye Diffusion in Alumina Nanofluids  

E-Print Network [OSTI]

to prepare new refrigerant formulations containing dispersed nanomaterials, including graphene nanosheets, carbon nanotubes and metal oxide and nitride. The influence of key parameters such as particle type, size and volume fraction on the suspension...

Ozturk, Serdar 1979-

2012-10-05T23:59:59.000Z

327

Pitting corrosion protection of stainless steel by sputter deposited hafnia, alumina, and hafnia-alumina nanolaminate films  

SciTech Connect (OSTI)

316L stainless steel coated with sputter deposited HfO{sub 2}, Al{sub 2}O{sub 3}, and HfO{sub 2}-Al{sub 2}O{sub 3} nanolaminate films were subjected to direct current cyclic potentiodynamic polarization (DCP) in Hanks' balanced salt solution electrolyte. Postexposure morphology was characterized by scanning electron microscopy (SEM) with in situ energy dispersive spectroscopy (EDS). SEM/EDS data show that bare steel and steel coated with single-layer HfO{sub 2} develop pits with perforated covers. These pits become autocatalytic, consistent with an observed positive DCP hysteresis. On the other hand, SEM/EDS data show that steel coated with Al{sub 2}O{sub 3} and HfO{sub 2}-Al{sub 2}O{sub 3} nanolaminate films does not develop autocatalytic pits, consistent with an observed negative DCP hysteresis. However, Al{sub 2}O{sub 3} splinters upon polarization whereas the HfO{sub 2}-Al{sub 2}O{sub 3} nanolaminate remains intact. The areas of worst damage in the nanolaminate correspond to pit cover rupture before autocatalysis, allowing pit and bulk electrolyte to mix and the newly exposed steel surface to repassivate. The films' diverse behavior is discussed in terms of a model for perforated pit growth that requires occlusion until an autocatalytic geometry is established. The authors conclude that the key property a film must have to arrest autocatalytic geometry development is the ability to rupture locally at an early stage of pit growth.

Almomani, M. A.; Aita, C. R. [Materials Department and the Advanced Coatings Experimental Laboratory, College of Engineering and Applied Science, University of Wisconsin-Milwaukee, P.O. Box 784, Milwaukee, Wisconsin 53201 (United States)

2009-05-15T23:59:59.000Z

328

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

of O2 in combustion products Excess air used Recommended airtemperature of the air or combustion products and nodules tocombustion products of coal, additional air from various

Price, Lynn

2013-01-01T23:59:59.000Z

329

Improvement of kiln design and combustion/carbonization timing to produce charcoal from agricultural waste in Developing countries  

E-Print Network [OSTI]

Current economic conditions in third world countries like Haiti are so poor that the majority of the population has no access to energy sources that people in the first world take for granted. In Haiti the last two percent ...

Martinez, Jason A. (Jason Alexander)

2006-01-01T23:59:59.000Z

330

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

air used for coal combustion and generation of heat withineven the 0.19% CO generation in coal combustion in a highfor power generation) Possible reduction in coal use Coal

Price, Lynn

2013-01-01T23:59:59.000Z

331

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

and Quantification of Dioxin and Furan Releases. Geneva:unintentional releases of dioxins and furans (Dx/Fu) fromPlan (NIP) to address dioxins and furans, and implement

Price, Lynn

2013-01-01T23:59:59.000Z

332

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

nodules by using hot water and/or using waste heat. 2.Pre dry nodules using waste heat from exhaust gases or airSteam Turbine Generator Waste Heat Boilers Preheaters and

Price, Lynn

2013-01-01T23:59:59.000Z

333

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

transfer in boiler Boiler efficiency Heat used in boiler *hr. Assuming boiler heat recovery efficiency of 90%, totalEfficiency Improvement An analysis of the performance of the heat recovery components (boilers,

Price, Lynn

2013-01-01T23:59:59.000Z

334

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

system that uses steam and turbine generators to produce upwater to cooling towers Steam Turbine Generator Waste Heatcombustion (CO gas) ? Steam turbine condenser cooling water

Price, Lynn

2013-01-01T23:59:59.000Z

335

Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China  

E-Print Network [OSTI]

conversion: 1 kwh = 10,500 Btu for power production Averageelectricity and at 10,500 Btu/kwh or 2,646 kcal/kHz energyHCs Unit Nm3/hr Nm3/hr cfh Btu/scf MM Btu/hr GJ/hr Btu/scf

Price, Lynn

2013-01-01T23:59:59.000Z

336

A study of a lime-free calcium arsenate and lime-free calcium arsenate mixed with organic insecticides for cotton insect control  

E-Print Network [OSTI]

of the cotton aphid. 30 o ?s e* mi SS3 t=>o O fi w ow o Ix) s SM faO MOH Xoli W CtJofa ow w ? !=> o ei M 3...

Roussel, John Severin

1950-01-01T23:59:59.000Z

337

Ten case history studies of energy efficiency improvements in pulp and paper mills. Final report  

SciTech Connect (OSTI)

The ten technologies chosen for case history development are: sonic sootblowing in boilers, boiler operation on oil-water emulsified fuel, energy efficient motors, computerized control of excess air for boilers, boiler control and load allocation, driving of waste-activated sludge by multiple effect evaporation, pre-drying of hog fuel, lime kiln computerization, heat wheel for process heat recovery, and organic Rankine bottoming cycle for thermomechanical pulping heat recovery. For each case study, there is given: the company name, employee contact, plant summary, a description of the energy consuming process and of the energy-saving action, an assessment of energy savings, and the decision process leading to the adoption of the measure. A data summary for discounted cash flow analysis is tabulated for each case. (LEW)

Not Available

1981-01-01T23:59:59.000Z

338

How Can China Lighten Up? Urbanization, Industrialization and Energy Demand Scenarios  

E-Print Network [OSTI]

eliminated all vertical shaft kilns in cement production.cement industry is steadily transitioning from using less-efficient vertical-shaft- kilnvertical shaft kilns to rotary kilns and endogenous process improvements, the final intensity of cement

Aden, Nathaniel T.

2010-01-01T23:59:59.000Z

339

Method for the recovery of fluorides from spent aluminum potlining and the production of an environmentally safe waste residue  

SciTech Connect (OSTI)

A method for recovery of fluoride values from spent potlining and fluoride containing insulating materials associated with the potlining is disclosed. Spent potlining and the insulating matericals are reduced to a fine particle size and incinerated. The ash residue is leached with a dilute caustic and the leachate is treated with a calcium compound to precipitate calcium fluoride. The calcium fluoride is dried to a moisture content of less than 0.1 percent and is treated with about 93 to 99 percent concentration of sulfuric acid to produce hydrogen fluoride gas and a metal sulfate. The hydrogen fluoride gas is fed into an alumina dry scrubber to produce alumina with absorbed fluorides to be used as feed material to reduction cells used in the manufacture of aluminum by electrolytic reduction. The metal sulfate residue is treated with lime and constitutes an environmentally safe product which can be disposed of as landfill material.

Snodgrass, J.B.; Cambridge, E.L.

1984-04-24T23:59:59.000Z

340

Energy Efficiency Improvement Opportunities for the Cement Industry  

E-Print Network [OSTI]

the small cement plants, earthen vertical kiln (and hollowcement plant in North China utilizing vertical shaft kilnscement has ordered a vertical roller mill for the new kiln

Worrell, Ernst

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Sugarcane juice extraction and preservation, and long-term lime pretreatment of bagasse  

E-Print Network [OSTI]

C)................................................................................146 Figure 4.6 Total mass, holocellulose, lignin and ash for treatment without air purging at 23oC. .........................................................................147 Figure 4.7 Total mass, holocellulose, lignin and ash for treatment... without air purging at 30oC. .........................................................................148 Figure 4.8 Total mass, holocellulose, lignin and ash for treatment without air purging at 40o...

Granda Cotlear, Cesar Benigno

2005-02-17T23:59:59.000Z

342

First New World Documentation of an Old World Citrus Pest, the Lime Swallowtail  

E-Print Network [OSTI]

(Lepidoptera:Papilionidae), in the Dominican Republic (Hispaniola) Kelvin A. Guerrero, Denia Veloz, Sarah Lyn, is documented from eastern Dominican Republic on the Ca- ribbean island of Hispaniola. Resumen. Se registra la especiePapilio derrzoleus, una reconocido plaga de 10s citricos en el Mundo Viejo, 1 para la Hispaniola

Farrell, Brian D.

343

Spring 2010 Anders Plejdrup Houmller, CEO, BlueLime Consulting, Karetmagervej 21 A, DK-7000 Fredericia  

E-Print Network [OSTI]

.bluelime.dk 2 2. The Point Tariff System In fig. 2, the water illustrates the electrical energy and the walls of the tanks illustrate the grid. The idea of the system of point tariff is that the producers pay a fee

344

Volatile fatty acid fermentation of lime-treated bagasse by rumen microorganisms  

E-Print Network [OSTI]

and the randomizing pathway through succinate. Carbohydrate Oxatoacetate 2H Malate QH 0 Fumarate Succmate Succinyl CoA C A Methylmalonyl CoA Propionyl CoA HrO Ct ATP? FF F ~~hl A ATP Acetoacetyl CoA 2HQ Acetate B ? hydroxybutyryt CoA Acrylate HtO... to those used to obtain the best yield or production of VFA. 25 13CHtCOOH ~ 4CHsCHtCHgCHtCOOH+ 7COg+ 6HtO (3) 4CHsCOOH ~ CHsCHgCHtCHtCHgCOOH + 2COa + 2HtO (4) However, all of the VFA concentrations can be measured directly, hence it is more convenient...

Lee, Chang-Ming

1993-01-01T23:59:59.000Z

345

Lessons Learned Following the Successful Decommissioning of a Reaction Vessel Containing Lime Sludge and Technetium-99  

SciTech Connect (OSTI)

This paper documents how WESKEM, LLC utilized available source term information, integrated safety management, and associated project controls to safely decommission a reaction vessel and repackage sludge containing various Resource Conservation and Recovery Act constituents and technetium-99 (Tc-99). The decommissioning activities were segmented into five separate stages, allowing the project team to control work related decisions based on their knowledge, experience, expertise, and field observations. The information and experience gained from each previous stage and rehearsals contributed to modifying subsequent entries, further emphasizing the importance of developing hold points and incorporating lessons learned. The hold points and lessons learned, such as performing detailed personal protective equipment (PPE) inspections during sizing and repackaging operations, and using foam-type piping insulation to prevent workers from cutting or puncturing their PPE on sharp edge s or small shards generated during sizing operations, minimized direct contact with the Tc-99. To prevent the spread of contamination, the decommissioning activities were performed inside a containment enclosure connected to negative air machines. After performing over 235 individual entries totaling over 285 project hours, only one first aid was recorded during this five-stage project.

Dawson, P. M.; Watson, D. D.; Hylko, J. M.

2002-02-25T23:59:59.000Z

346

Volatile fatty acid fermentation of lime-treated biomass by rumen microorganisms  

E-Print Network [OSTI]

concentration was studied. A counter-current fermentation system was also simulated to determine if it provided advantages over a conventional batch fermentor. All of the substrates studied produced similar amounts of VFA's. Approximately 7- I 0 g/L of acetic... sugars. This is accomplished by hydrolytic enzymes. However, cellulose possesses a recalcitrant crystalline structure and is insoluble in aqueous solutions, making it highly resistant to enzymatic degradation. Compounding this problem is lignin, which...

Rapier, Charles Robert

1995-01-01T23:59:59.000Z

347

Equations for predicting the layer stiffness moduli in pavement systems containing lime-flyash stabilized materials  

E-Print Network [OSTI]

in site 2. Site 2 resurfaced with 2 in. NIAC jn Dctober 1980. originally constructed of one-course bituminous surface treatment. All ten sections of the test site were re-surfaced in October, 1980, with a 2-inch hot mix concrete overlay. Varying...

Alam, Shah Manzoor

1984-01-01T23:59:59.000Z

348

Evaluation of methods of mixing lime in bituminous paving mixtures in batch and drum plants  

E-Print Network [OSTI]

prepared mixtures, field mixtures obtained at the plant and pavement cores. Laboratory tests included Hveem and Marshall stability, resilient modulus and indirect tension. Mixture conditioning to evaluate resistance to moisture damage included vacuum... Mixed and Compacted Specimens Tensile Strength Ratio for Laboratory Mixed and Compacted Specimens 14 Marshall Stability Before and After 7-days Soaking in Water for Lab Mixed and Compacted Specimens 36 FIGURE Page 15 16 Hveem Stability Before...

Button, Joseph Wade

1984-01-01T23:59:59.000Z

349

CONTROLLED LOW-STRENGTH MATERIAL (CLSM) PRODUCED WITH HIGH-LIME FLY ASH  

E-Print Network [OSTI]

by the Detroit Edison Company, Detroit, Michigan, and Kuhlman Corp., Toledo, Ohio in the 1970s. The investigation

Wisconsin-Milwaukee, University of

350

LiME : A Linux based MPLS Emulator Abhijit Gadgil and Abhay Karandikar  

E-Print Network [OSTI]

(API) for plugging in actual implementation thereby enabling a network device (called Device Under TestME to inject MPLS tra?c into the external world. Rest of the paper is organized as follows. Section 2 discusses

Karandikar, Abhay

351

Failure mode analysis for lime/limestone FGD systems. Volume 3. Plant profiles. Part 2  

SciTech Connect (OSTI)

Plant profiles are given for the following plants: Tombigbee 2, 3; Apache 2, 3; Cholla 1, 2; Four Corners 1, 2, 3; Laramie River 1; Green 1, 2; Duck Creek 1; Craig 1, 2; Conesville 5, 6; Coal Creek 1, 2; Elrama 1, 2, 3, 4; and Phillips 1, 2, 3, 4, 5, 6. (DLC)

Kenney, S.M.; Rosenberg, H.S.; Nilsson, L.I.O.; Oxley, J.H.

1984-08-01T23:59:59.000Z

352

inp_30cm_60x60_1_200Hz_lime_shale  

E-Print Network [OSTI]

... ros(2)= solid grains density (shale)(kg/m^3) used 1.81465889E+10 km(2)= Bulk modulus dry matrix (Pa) used 1.33564722E+10 mum(2)= shear modulus dry

353

RETENTION OF Cd, Cu, Pb AND Zn BY WOOD ASH, LIME AND FUME DUST  

E-Print Network [OSTI]

to immobilize metals from wastewater and soils (Viraraghavan and Rao, 1991). Various methods to remediate heavy metal contaminated soils and wastes exist, including thermal, biological, and physical/chemical treatments. However, most current treatment technologies are either too costly or only partially effective

Ma, Lena

354

Sulfate Fining Chemistry in Oxidized and Reduced Soda-Lime-Silica Glasses  

SciTech Connect (OSTI)

Various reducing agents were used and their additions were varied to (1) increase glass quality through eliminating defects from silica scum, (2) decrease SOx emissions through changing the kind and quantity of reducing agents, and (3) improve production efficiency through increased flexibility of glass redox control during continuous processing. The work included measuring silica sand dissolution and sulfate decomposition in melts from glass batches. Glass batches were heated at a temperature-increase rate deemed similar to that experienced in the melting furnace. The sulfate decomposition kinetics was investigated with thermogravimetric analysis-differential thermal analysis and evolved gas analysis. Sulfur concentrations in glasses quenched at different temperatures were determined using X-ray fluorescence spectroscopy. The distribution of residual sand (that which was not dissolved during the initial batch reactions) in the glass was obtained as a function of temperature with optical microscopy in thin-sections of melts. The fraction of undissolved sand was measured with X-ray diffraction. The results of the present study helped Visteon Inc. reduce the energy consumption and establish the batch containing 0.118 mass% of graphite as the best candidate for Visteon glass production. The improved glass batch has a lower potential for silica scum formation and for brown fault occurrence in the final glass product. It was established that bubbles trapped in the melt even at 1450 C have a high probability to be refined when reaching the hot zone in the glass furnace. Furthermore, silica sand does not accumulate at the glass surface and dissolves faster in the batch with graphite than in the batch with carbocite.

Matyas, Josef; Hrma, Pavel R.

2005-05-13T23:59:59.000Z

355

What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions  

E-Print Network [OSTI]

vertical kiln technology are considered. In particular, these trends towards greater efficiency in cement

G. Fridley, David

2010-01-01T23:59:59.000Z

356

EA-0405: Finding of No Significant Impact  

Broader source: Energy.gov [DOE]

Innovative Sulfur Dioxide Scrubbing System for Coal Burning Cement Kilns, Passamaquoddy Tribe Thomaston, Maine

357

Modeling the Atmospheric Transport and Deposition of PCDD/F to the  

E-Print Network [OSTI]

to be municipal waste incineration, iron sintering, medical waste incineration, and cement kilns burning hazardous

358

Industrial Sector Energy Conservation Programs in the People's Republic of China during the Seventh Five-Year Plan (1986-1990)  

E-Print Network [OSTI]

plants imported advanced technologies such as high-efficiency kilns in addition to renovating existing

Zhiping, L.

2010-01-01T23:59:59.000Z

359

WWWWWoods ofoods ofoods ofoods ofoods of LouisianaLouisianaLouisianaLouisianaLouisiana  

E-Print Network [OSTI]

Jimmy Marionneaux, Jimmy Marionneaux Lumber Co, Livonia, LA David Williams, Kustom Kilns, Maringouin, LA

360

Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed  

SciTech Connect (OSTI)

Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. syngas) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950C), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.

Scott Sinquefield; Xiaoyan Zeng, Alan Ball

2010-03-02T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING  

SciTech Connect (OSTI)

Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

Lucia, Lucian A

2013-04-19T23:59:59.000Z

362

Oil shale retort apparatus  

DOE Patents [OSTI]

A retorting apparatus including a vertical kiln and a plurality of tubes for delivering rock to the top of the kiln and removal of processed rock from the bottom of the kiln so that the rock descends through the kiln as a moving bed. Distributors are provided for delivering gas to the kiln to effect heating of the rock and to disturb the rock particles during their descent. The distributors are constructed and disposed to deliver gas uniformly to the kiln and to withstand and overcome adverse conditions resulting from heat and from the descending rock. The rock delivery tubes are geometrically sized, spaced and positioned so as to deliver the shale uniformly into the kiln and form symmetrically disposed generally vertical paths, or "rock chimneys", through the descending shale which offer least resistance to upward flow of gas. When retorting oil shale, a delineated collection chamber near the top of the kiln collects gas and entrained oil mist rising through the kiln.

Reeves, Adam A. (Grand Junction, CO); Mast, Earl L. (Norman, OK); Greaves, Melvin J. (Littleton, CO)

1990-01-01T23:59:59.000Z

363

Failure mode analysis for lime/limestone FGD system. Volume III. Plant profiles. Part 1 of 3  

SciTech Connect (OSTI)

This volume contains plant profiles for: Petersburg 3; Hawthorn 3, 4; La Cygne 1; Jeffry 1, 2; Lawrence 4, 5; Green River 1-3; Cane Run 4, 5; Mill Creek 1, 3; Paddy's Run 6; Clay Boswell 4; Milton R. Young 2; Pleasants 1, 2; and Colstrip 1, 2. (DLC)

Kenney, S.M.; Rosenberg, H.S.; Nilsson, L.I.O.; Oxley, J.H.

1984-08-01T23:59:59.000Z

364

Development of Oxidative Lime Pretreatment and Shock Treatment to Produce Highly Digestible Lignocellulose for Biofuel and Ruminant Feed Applications  

E-Print Network [OSTI]

enhanced the 72-h glucan digestibility of several promising biomass feedstocks: bagasse (74.0), corn stover (92.0), poplar wood (94.0), sorghum (71.8), and switchgrass (89.0). Highly digestible lignocellulose can also be used as ruminant animal feed. Shock...

Falls, Matthew David

2011-10-21T23:59:59.000Z

365

Zinc Fertilization Plus Liming to Reduce Cadmium Uptake by Romaine Lettuce on Cd-Mineralized Lockwood Soil  

E-Print Network [OSTI]

by emissions from zinc smelters. Trace Subst. Environ.1999) who studied Zn-smelter or mine waste contaminated orgrowing Romaine lettuce on Zn-smelter contaminated soils in

Chaney, Rufus L; Green, Carrie E.; Ajwa, Husein A; Smith, Richard F

2009-01-01T23:59:59.000Z

366

The Use of Lime in Fish Ponds1 Andy M. Lazur, Charles E. Cichra and Craig Watson2  

E-Print Network [OSTI]

small fish are being reared. Calcite and dolomite increase the total hardness, total alkalinity, and p desirable for most freshwater fish. Water in ponds reflects the quality of the soils in which they are located. In acid soils, ponds typically have low total alkalinity, total hardness, and pH. Total hardness

Watson, Craig A.

367

Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants  

E-Print Network [OSTI]

sulfur content is highly dependent upon coal type. In gen~ral, conventional coal cleaning does not effect sufficient sulfur reduction to permit combustion without! i additional flue gas desulfurization. Several novel technologies now under development..., or equilibrium limita tions requires that super stoichiometric quantities of CaO be charged to the boiler. Operationally the introduction of large amounts of calcium additive can pose increased problems due to slagging and fouling in the combustion chamber...

Schwartz, M. H.

1979-01-01T23:59:59.000Z

368

E-Print Network 3.0 - alumina-forming austenitic stainless Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

licensed to Carpenter Technology Corp. Carpenter... for Research and Development Tim Armstrong sign a licensing agreement for an ... Source: Oak Ridge National Laboratory Fossil...

369

Refractory Materials based on Magnesia-Alumina Spinel for Improved Performance in Coal Gasification Environments  

SciTech Connect (OSTI)

As part of a larger project to develop novel refractory systems and techniques to reduce energy consumption of refractory lined vessels, a team composed of Oak Ridge National Laboratory, refractory manufacturer Minteq International, Inc., and academic partner Missouri University of Science and Technology have developed new refractory materials and coating systems specifically for application in coal gasification environments. Materials were developed under this U.S. DOE funded project to address the need for innovative refractory compositions by developing MgO-Al2O3 spinel gunnable refractory compositions utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. Work was conducted to develop and deploy these new materials and to develop and apply low cost coatings using a colloidal approach for protection against attack of the refractory brick by the serviced environment. Additionally, a light-weight back-up refractory system was developed to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the efforts involved in the development of these materials, along with the laboratory testing and evaluation of these materials leading to relevant results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment though compositional and processing modifications.

Hemrick, James Gordon [ORNL; Armstrong, Beth L [ORNL; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla

2013-01-01T23:59:59.000Z

370

Applied Catalysis B: Environmental 37 (2002) 1725 Selective CO oxidation over Pt/alumina catalysts  

E-Print Network [OSTI]

). methanol or partial oxidation of gasoline followed by water gas shift reaction will produce a gas stream al. [11] studied the kinetics of the selective CO oxidation in H2-rich gas on Pt/Al2O3 in detail rich feed gas to proton exchange membrane (PEM) fuel cells can poison the platinum anode electrode

Gulari, Erdogan

371

Analysis of the Temporal Evolution of Thermal Conductivity in Alumina-Water Nanofluid  

E-Print Network [OSTI]

both the United States Department of Energy and Texas Advanced Research Program. vi NOMENCLATURE D Thermal diffusivity Ei Exponential integral k Thermal conductivity k n Nanofluid thermal conductivity k b Base fluid thermal...?s thermal conductivity (k) and thermal diffusivity (D), are related to the temperature difference null?nullnull between the heat source and surrounding medium at a distance (r) from the source of a quantity of heat (Q) a certain time (t) after the heat...

Fortenberry, Stephen

2009-09-30T23:59:59.000Z

372

Development and Characterization of Novel Alumina Based Ceramic Matrix Composites for Energy Efficient Sliding Applications  

E-Print Network [OSTI]

for bearings. Bearings with low friction surface coatings have been used which improved the performance and increased the life cycle of turbines. Similar rolling element bearings are used in rocket engines, micro gas turbine engines, aircraft engines, turbo...

Paluri, Rajeshwari S. Lakshmi

2012-10-19T23:59:59.000Z

373

Tailoring Silica-alumina Supported Pt-Pd As Poison Tolerant Catalyst...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the efficiency of the catalyst in the presence of sulfur. Citation: Yu Y, OY Gutierrez, GL Haller, RJ Colby, BC Kabius, JA Rob van Veen, A Jentys, and JA Lercher.2013."Tailoring...

374

Effects of Slurry Chemistry on the Rate of Agglomeration of Alumina Nanoparticles for Chemical Mechanical Planarization /  

E-Print Network [OSTI]

8.2, respectively. Solid lines are power law fit and dottedcopper at pH 8.0. Solid lines are power law fit and dotted8.2 respectively. Solid lines are power law fit and dotted

Brahma, Neil Anjan

2013-01-01T23:59:59.000Z

375

Chemical bath method to grow precipitated nanorods of iridium oxide on alumina membranes  

E-Print Network [OSTI]

of IrO2 nanostructures exhibiting a high capacitive property can be utilised in supercapacitors for electrochemical supercapacitors [6, 7]. In addition, IrO2 has been preferred for enzyme-based biosensors or neuro supercapacitors, implantable biosensors and electrochemical catalysts. However, the current methods to grow well

Chiao, Jung-Chih

376

E-Print Network 3.0 - alumina-rich magnesium aluminate Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(3 pm... , but no evidence of evaporative loss is seen. The inclusion has a Group II REE pattern and a normal magnesium... ) and SYLVESTER etal. ( 1993). Magnesium, Al, Ti, Mn....

377

alumina-titania high emittance: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and analysis of lateral SiC N-emitter SiGe P-base Schottky metal-collector (NPM) HBT on SOI Engineering Websites Summary: on SOI M. Jagadesh Kumar *, C. Linga Reddy...

378

Chemical Modification of Porous Alumina for Nanowire Templating and NEXAFS Spectroscopy of Aqueous ATP  

E-Print Network [OSTI]

Two: NEXAFS Spectroscopy of Aqueous ATP Chapter 3: AdenosineAdenosine triphsophate (ATP) is an important biomoleculeThe ubiquitous presence of ATP in organisms implies that

Kelly, Daniel Nicholas

2010-01-01T23:59:59.000Z

379

Method And Reactor For Production Of Aluminum By Carbothermic Reduction Of Alumina  

DOE Patents [OSTI]

A hollow partition wall is employed to feed carbon material to an underflow of a carbothermic reduction furnace used to make aluminum. The partition wall divides a low temperature reaction zone where aluminum oxide is reacted with carbon to form aluminum carbide and a high temperature reaction zone where the aluminum carbide and remaining aluminum oxide are reacted to form aluminum and carbon monoxide.

Aune, Jan Arthur (Ytre Enebakk, NO); Johansen, Kai (Kristiansand, NO)

2004-10-19T23:59:59.000Z

380

E-Print Network 3.0 - alumina-iron functionally graded Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

...23 Enter Grades View Grades ... Source: Utah, University of - Energy and Geoscience Institute,...

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

E-Print Network 3.0 - alumina-supported ceria ii Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

13... to the preparation of a ceria-coated silica aerogel. A second opportunity for aerogels relates to the ... Source: Consortium for Fossil Fuel Science, C1 Chemistry Program...

382

E-Print Network 3.0 - alumina ceramic foam Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics 42 Direct Digital Manufacturing Frank Liou, Ming Leu, Joe Newkirk, Fatih Dogan, Summary: Sintering (SLS) of...

383

Acidity and catalytic activity of zeolite catalysts bound with silica and alumina  

E-Print Network [OSTI]

. Micropore surface area and micropore volume are reduced by about 19% and 18%, respectively, indicating some micropores of ZSM-5 are blocked on binding with silica. SiO2-bound ZSM-5 catalysts have less catalytic activity for butane transformation (cracking...

Wu, Xianchun

2004-09-30T23:59:59.000Z

384

Chemical Modification of Porous Alumina for Nanowire Templating and NEXAFS Spectroscopy of Aqueous ATP  

E-Print Network [OSTI]

electrodes through a salt bridge [the salt bridge is made by heating a slurry of 2.5275 g KNO 3 , 0.75 g Agar,

Kelly, Daniel Nicholas

2010-01-01T23:59:59.000Z

385

Strengthening and toughening of carbon nanotube reinforced alumina nanocomposite fabricated by  

E-Print Network [OSTI]

rights reserved. Keywords: Carbon nanotube; Ceramic matrix composite; Molecular level mixing; Spark: one is the weak bonding between CNTs and ceramic matrix and the other is the inhomogeneous distribution of CNTs within the ceramic matrix. Recently, CNTs have been homoge- neously dispersed within

Hong, Soon Hyung

386

A thermionic energy converter with a molybdenum-alumina cermet emitter  

SciTech Connect (OSTI)

A study is made of the properties of cermets as electrode materials for thermionic energy converters. For thermodynamic reasons it is expected that all cermets composed of pure Mo and refractory oxides have the same bare work function. From data on the work function of Mo in an oxygen atmosphere this bare work function is estimated to be {Phi}=4.9 eV (at {ital T}=1400 {degree}C). Experimentally, the bare work function of Al{sub 2}O{sub 3}-Mo cermets was found to be {Phi}=4.5 eV, independent of the relative amounts of Al{sub 2}O{sub 3} and Mo. The cesiated work function of the Al{sub 2}O{sub 3}-Mo cermets was found to be 0.15 eV lower than the cesiated work function of pure Mo. The bare work function of Mo{sub 3}Al was found to be {Phi}=4.0 eV. The cesiated work function of Mo{sub 3}Al at collector temperature conditions was 0.3 eV lower than the cesiated work function of pure Mo. The electrical power density of a diode with an Al{sub 2}O{sub 3}-Mo cermet emitter was 0.4 W/cm{sup 2} at 1300 {degree}C. The barrier index at this temperature was 2.36 V. The high barrier index is attributed to a high plasma voltage drop {ital V}{sub {ital d}}=0.91 V.

Gubbels, G.H.M.; Wolff, L.R.; Metselaar, R. (Centre for Technical Ceramics, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands (NL))

1990-12-01T23:59:59.000Z

387

Alumina Nanoparticle Pre-coated Tubing Ehancing Subcooled Flow Boiling Cricital Heat Flux  

E-Print Network [OSTI]

Nanofluids are engineered colloidal dispersions of nano-sized particle in common base fluids. Previous pool boiling studies have shown that nanofluids can improve critical heat flux (CHF) up to 200% for pool boiling and ...

Truong, Bao H.

388

E-Print Network 3.0 - alumina-zirconium ceramics induced Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cracking in Ceramic Crystals", Materials Letters, 7 5,6, 224 (1988... -Induced Fracture in Ceramic Crystals", Int. Conf. on the Fundamentals of Fracture Conf. Proceedings......

389

Ferromagnetic nanocylinders electrodeposited into nanoporous alumina template: A magnetometry and Brillouin light scattering study  

SciTech Connect (OSTI)

The static magnetization experimental behavior of cobalt (Co), Permalloy (Py), and nickel (Ni) nanocylinders is obtained from vibrating sample magnetometry while the dynamic behavior for the Co and Py ones is analyzed by means of Brillouin light scattering spectroscopy. Assuming the presence at remanence of two populations of cylinders with up and down magnetizations and including the dipolar coupling between the cylinders, a single analytical model based on a mean-field approach allowed us to satisfactorily analyze both series of experimental results. The model requires three physical parameters, allowing us to derive the in-plane saturation field, the eigenfrequency in the absence of applied field, and the eigenfrequency at the in-plane saturation field; these parameters enable us to adjust the whole variation of the eigenfrequency versus the applied field. Moreover, the effect of the magnetocrystalline anisotropy on the softening of the frequency in the nonsaturated state is clearly evidenced: it is more pronounced when the magnetocrystalline anisotropy is not vanishing and adds to the shape anisotropy (Co c-axis parallel to the cylinder axis); the softening being weak in the other cases (Co c-axis perpendicular to the cylinder axis or Permalloy).

Cherif, S. M.; Roussigne, Y.; Stashkevich, A. A. [LSPM-CNRS, Universite Paris13, 93430 Villetaneuse (France); Darques, M. [Institut Neel-CNRS, (CNRS/UJF), 25 Rue des Martyrs BP 166, 38042 Grenoble (France); Institute of Condensed Matter and Nanosciences, Universite Catholique de Louvain, Croix du Sud 1, B-1348 Louvain-la-Neuve (Belgium); Bouziane, K. [Department of Physics, College of Science, Sultan Qaboos University, P.O. Box 36 Al-Khodh 123, Sultanate of Oman (Oman); Piraux, L. [Institute of Condensed Matter and Nanosciences, Universite Catholique de Louvain, Croix du Sud 1, B-1348 Louvain-la-Neuve (Belgium)

2011-05-15T23:59:59.000Z

390

E-Print Network 3.0 - aluminas sinterizadas visando Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering 45 Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings Summary: to estimate upper and lower bounds of the transverse thermal resistance...

391

E-Print Network 3.0 - anodic alumina mask Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Centre de mathmatiques Collection: Mathematics 88 Nanoporous inorganic membranes or coatings for sustained drug delivery in implantable devices Summary: properties can also...

392

E-Print Network 3.0 - alumina based capacitive Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Clarkson University Collection: Materials Science 71 Atomic layer deposited protective coatings for micro-electromechanical systems Summary: of conformal layer deposition, ALD...

393

E-Print Network 3.0 - alumina untuk bahan Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization 50 Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings Summary: to estimate upper and lower bounds of the transverse thermal resistance...

394

E-Print Network 3.0 - alumina determinacion espectrografica Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Utilization 40 Vacuum 65 (2002) 415425 Plasma spraying of micro-composite thermal barrier coatings Summary: to estimate upper and lower bounds of the transverse thermal resistance...

395

E-Print Network 3.0 - alumina-based fluorous liquid Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University of California, Merced Collection: Fission and Nuclear Technologies 13 Microfluidics DOI: 10.1002anie.200805225 Summary: of fluorocarbon, and the surface chemistry of...

396

Theoretical Predictions and Experimental Assessments of the Performance of Alumina RF Windows  

SciTech Connect (OSTI)

Radio frequency (RF) windows are the most likely place for catastrophic failure to occur in input power couplers for particle accelerators. Reliable RF windows are essential for the success of the Accelerator Production of Tritium (APT) program because there are over 1000 windows on the accelerator, and it takes more than one day to recover from a window failure. The goals of this research are to analytically predict the lifetime of the windows, to develop a conditioning procedure, and to evaluate the performance of the RF windows. The analytical goal is to predict the lifetime of the windows. The probability of failure is predicted by the combination of a finite element model of the window, Weibull probabilistic analysis, and fracture mechanics. The window assembly is modeled in a finite element electromagnetic code in order to calculate the electric fields in the window. The geometry (i.e. mesh) and electric fields are input into a translator program to generate the mesh and boundary conditions for a finite element thermal structural code. The temperatures and stresses are determined in the thermal/structural code. The geometry and thermal structural results are input into another translator program to generate an input file for the reliability code. Material, geometry and service data are also input into the reliability code. To obtain accurate Weibull and fatigue data for the analytical model, four point bend tests were done. The analytical model is validated by comparing the measurements to the calculations. The lifetime of the windows is then determined using the reliability code. The analytical model shows the window has a good thermal mechanical design and that fast fracture is unlikely to occur below a power level of 9 Mw. The experimental goal is to develop a conditioning procedure and evaluate the performance of RF windows. During the experimental evaluation, much was learned about processing of the windows to improve the RF performance. Methods of processing included grit blasting and using various coatings.

Karen Ann Cummings

1998-07-01T23:59:59.000Z

397

E-Print Network 3.0 - alumina batteries status Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and gyroscopes continued to deteriorate... a robot capable of replacing the Hubble's aging batteries and gyroscopes. Additionally, ... Source: Johnson, Eric E. - Klipsch School...

398

Particle-size effect on the compressibility of nanocrystalline alumina D. Penwell,1  

E-Print Network [OSTI]

. Benedetti,2 R. Jeanloz,3 and M. B. Kruger1 1 Department of Physics, University of Missouri, Kansas City INTRODUCTION The study of nanocrystalline materials with dimensions less than 100 nm is an active area- crystal transition pressures is explained in terms of surface- energy differences between the phases

Kruger, Michael - Department of Physics, University of Missouri

399

Preparation of ceramic matrix and alumina fiber composites for use as solid electrolytes  

DOE Patents [OSTI]

A process for making solid electrolytes using a fibrous stabilizing dispersed second phase for enhanced conductivity of the electrolyte after deformation and annealing. 1 tab.

Dudney, N.J.

1987-04-30T23:59:59.000Z

400

E-Print Network 3.0 - alumina-supported fe-c nanoparticles Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and biofilms will likely affect ... Source: Ozdoganlar, O. Burak - Department of Mechanical Engineering, Carnegie Mellon University Collection: Engineering 16 Delivery...

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

alumina-zirconia ceramic eutectic: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

j and the magnetic field H in Bi2Sr2CaCu2O8 x ceramics. We provided in high-Tc superconduct- ing granular ceramics remain an intriguing subject of inten- sive investigations...

402

alumina-matrix ceramics research: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

j and the magnetic field H in Bi2Sr2CaCu2O8 x ceramics. We provided in high-Tc superconduct- ing granular ceramics remain an intriguing subject of inten- sive investigations...

403

alumina-coated magnetite nanoparticles: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science Websites Summary: He, Xi Zhang, Hongbo Gu, Haoran Chen, Qiang Wang, Luyi Sun, Suying Wei,* Zhanhu Guo Polystyrene (PS. Scanning electron microscopy reveals that the...

404

Strains in Thermally Growing Alumina Films Measured in-situ usingSynchrotron X-rays  

SciTech Connect (OSTI)

Strains in thermally grown oxides have been measured in-situ, as the oxides develop and evolve. Extensive data have been acquired from oxides grown in air at elevated temperatures on different model alloys that form Al{sub 2}O{sub 3}. Using synchrotron x-rays at the Advanced Photon Source (Beamline 12BM, Argonne National Laboratory), Debye-Scherrer diffraction patterns from the oxidizing specimen were recorded every 5 minutes during oxidation and subsequent cooling. The diffraction patterns were analyzed to determine strains in the oxides, as well as phase changes and the degree of texture. To study a specimen's response to stress perturbation, the oxidizing temperature was quickly cooled from 1100 to 950 C to impose a compressive thermal stress in the scale. This paper describes this new experimental approach and gives examples from oxidized {beta}-NiAl, Fe-20Cr-10Al, Fe-28Al-5Cr and H{sub 2}-annealed Fe-28Al-5Cr (all at. %) alloys to illustrate some current understanding of the development and relaxation of growth stresses in Al{sub 2}O{sub 3}.

Hou, P.Y.; Paulikas, A.P.; Veal, B.W.

2006-01-02T23:59:59.000Z

405

Growth strains and creep in thermally grown alumina : oxide growth mechanisms.  

SciTech Connect (OSTI)

In situ measurements of growth strains and creep relaxation in {alpha}-Al{sub 2}O{sub 3} films, isothermally grown on {beta}-NiAl alloys at 1100 C, are reported and analyzed. Samples containing the reactive element Zr, and Zr-free samples, are examined. For Zr-free samples, steady state growth strains are compressive, whereas the growth strains are tensile when the reactive element (RE) is added to the alloy. This behavior is attributed to the counterflow of oxygen and aluminum interstitials, and to simultaneous counterflow of oxygen and aluminum vacancies, all moving through the grain boundaries. Cross diffusing oxygen and aluminum interstitials may merge and combine within the film, forming new oxide along grain boundary walls, a mechanism that leads to an in-plane compressive stress. Cross diffusing oxygen and aluminum vacancies will also merge and combine within the film; in this case material is removed from grain boundary walls, a mechanism that leads to an in-plane tensile stress. When no RE is present, the interstitial mechanism dominates and the resultant stress is compressive. Consistent with the 'dynamic segregation model', the RE slows the outdiffusion of Al interstitials permitting the tensile mechanism to dominate. This interpretation invokes the unconventional view that oxygen and aluminum interstitials and vacancies, created in and driven by the strong chemical gradient, all participate meaningfully in the scale growth process. Grain boundary diffusion measurements were obtained from low stress creep data, interpreted using the Coble model of grain boundary diffusion. Reported diffusion measurements of oxygen through grain boundaries of {alpha}-Al{sub 2}O{sub 3}, which are known to be inconsistent with oxide scale growth, are critically examined. A simple picture, a 'balanced defect model', emerges that is consistent with the dynamic segregation model, observed growth stresses and their dependence on the presence of a reactive element, sequential oxidation experiments, and our best knowledge about grain boundary diffusion coefficients.

Veal, B. W.; Paulikas, A. P.; Materials Science Division

2008-01-01T23:59:59.000Z

406

Stability and biocompatability of porous silicon and porous alumina for cell and biomolecular sensing  

E-Print Network [OSTI]

and Nanotechnology III, Canberra, ACT, Australia, 2007;SPIE: Canberra, ACT, Australia, 2007; pp 679909-12. Suh, K.

Alvarez, Sara D.

2008-01-01T23:59:59.000Z

407

Tailoring Silica-alumina Supported Pt-Pd As Poison Tolerant Catalyst For  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystallineForeign ObjectOUR TableE9.security Tag: securityTailoredAromatics

408

SO2-induced stability of Ag-alumina catalysts in the SCR of NO with  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 ResourceAwards SAGE Awards ,#2446Smalln n u a l r e p o rmethane.

409

TEST PROGRAM FOR ALUMINA REMOVAL AND SODIUM HYDROXIDE REGENERATION FROM HANFORD WASTE BY LITHIUM HYDROTALCITE PRECIPITATION  

SciTech Connect (OSTI)

This test program sets a multi-phased development path to support the development of the Lithium Hydrotalcite process, in order to raise its Technology Readiness Level from 3 to 6, based on tasks ranging from laboratory scale scientific research to integrated pilot facilities.

SAMS TL; GEINESSE D

2011-01-28T23:59:59.000Z

410

Wagerup Refinery Unit Three September 2005 Alcoa World Alumina Australia Page i TABLE OF CONTENTS  

E-Print Network [OSTI]

1. EXECUTIVE SUMMARY...................................................................................................... 1

unknown authors

411

Manufacturing Energy and Carbon Footprint - Sector: Alumina and Aluminum (NAICS 3313), January 2014 (MECS 2010)  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of Energy Low-TemperatureEnergyAll Manufacturing (NAICS 31-33)

412

Thermally Annealed Iron (Oxide) Thin Film on an Alumina Barrier Layer, by  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1 MembersStability ofXPS. | EMSL Annealed

413

Thermally Evaporated Iron (Oxide) on an Alumina Barrier Layer, by XPS. |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1 MembersStability ofXPS. | EMSL

414

Highly Dispersed and Active ReOx on Alumina-Modified SBA-15 Silica for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in theinPlastics -␤,of Energy2-Butanol

415

D2O Adsorption on an Ultrathin Alumina Film on NiAl(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phases onOrganization FY 2012 FYCustomer-Commentsloadvances fromD2O

416

Structure of δ-Alumina: Toward The Atomic Level Understanding Of  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSiteNeutronStrategicOurStructureSurvivorBacterial Nanowires

417

Plused EPR study of orthophosphoric and boric acid modified {gamma}-alumina  

SciTech Connect (OSTI)

CW EPR, pulsed ENDOR, and one- and two-dimensional ESEEM techniques have been applied to study the influence of H{sub 3}PO{sub 4} and H{sub 3}BO{sub 3} acid modification of {gamma}-Al{sub 2}O{sub 3} on the strong electron acceptor sites of {gamma}-Al{sub 2}O{sub 3} using adsorbed anthraquinone and {omicron}-chloranil as probe molecules. After the adsorption, electron transfer produces free radicals at active sites on the activated {gamma}-Al{sub 2}O{sub 3}. The observed spectra are the superposition of spectra from radicals simply adsorbed on the surface and from three different paramagnetic complexes of anthraquinone with coordinatively unsaturated aluminum. The isotropic hyperfine coupling of aluminum nuclei in these complexes is 2.5, 21, and 28 MHz. Treatment of {gamma}-Al{sub 2}O{sub 3} with H{sub 3}PO{sub 4} decreases the relative amounts of adsorbed radical and the complex with 2.5 MHz hyperfine coupling. The H{sub 3}BO{sub 3} treatment, in contrast, gives only the complex with the 21 MHz hyperfine coupling, and its resolved EPR spectrum indicates two equivalent aluminums in this active site. The ESEEM spectra show only weak dipole-dipole interaction with {sup 31}P and {sup 11}B nuclei located around the paramagnetic complex. These results suggest that acid modification alters the catalytic properties by changing the number and type of catalytic sites on the surface without introducing new species. 31 refs., 8 figs., 2 tabs.

Samoilova, R.I.; Dikanov, S.A. [Pacific Northwest National Lab., Richland, WA (United States)] [Pacific Northwest National Lab., Richland, WA (United States); [Inst. of Chemical Kinetics and Combustion, Novosibirsk (Russian Federation); Fionov, A.V.; Lunina, E.V. [Moscow State Univ (Russian Federation)] [Moscow State Univ (Russian Federation); Tyryshkin, A.M. [Inst. of Chemical Kinetics and Combustion, Novosibirsk (Russian Federation)] [Inst. of Chemical Kinetics and Combustion, Novosibirsk (Russian Federation); Bowman, M.K. [Pacific Northwest National Lab., Richland, WA (United States)] [Pacific Northwest National Lab., Richland, WA (United States)

1996-10-31T23:59:59.000Z

418

adhesive bonding high-alumina: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various conditions, including the type of surface preparation, pH of the environmental media, (more) Xu, Dingying 2004-01-01 2 Bond Characteristics and Qualifications of...

419

Supercritical carbon dioxide aided preparation of nickel oxide/alumina aerogel catalyst.  

E-Print Network [OSTI]

??The strength, thermal stability, pore structure and morphology are keys to success for wider deployment of aerogels. Furthermore, co or subsequent functionalization of the surfaces (more)

Li, Haitao

2005-01-01T23:59:59.000Z

420

China Energy and Emissions Paths to 2030  

E-Print Network [OSTI]

obsolete vertical shaft kiln (VSK) cement plants, with thecement industry is steadily transitioning from using less-efficient vertical-shaft-kilnvertical kiln technology are considered. In particular, these trends towards greater efficiency in cement

Fridley, David

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Review of Aegean Prehistory VII: Neopalatial, Final Palatial, and Postpalatial Crete  

E-Print Network [OSTI]

. The thermoluminescence dates for the MM IB kiln 3 at Phaistos (late 19th century) and for the LM I kiln at Ayia Triada (ca. 1600) seem appropriate; Y. Liritzis and R. Thomas, "Palaeointensity and Thermoluminescence Measurements on Cretan Kilns from 1300-2000 BC," Na... in the number of potter's kilns discovered" increases the possibil- ity of constructing archaeomagnetic and palaeoin- tensity sequences, helping to refine thermolumines- cence dates and to establish the contemporaneity of separated archaeological...

Rehak, Paul; Younger, John G.

2001-01-01T23:59:59.000Z

422

Development of a Calicum-Based Sorbent for Hot Gas Cleanup.  

SciTech Connect (OSTI)

Further review of the technical literature has provided additional information which will support the development of a superior calcium-based sorbent for hot gas cleanup in IGCC systems. Two general methods of sorbent preparation are being investigated. One method involves impregnating a porous refractory substrate with calcium while another method involves pelletizing lime or other calcium containing materials with a suitable binder. Several potential substrates, which are made of alumina and are commercially available, have been characterized by various methods. The surface area and apparent density of the materials have been measured, and it has been shown that some of the high surface area materials (i.e., 200-400 m{sub 2}/g) undergo a large decrease in surface area when heated to higher temperatures. Some of the lower surface area materials (i.e., 1-30 m{sub 2}/g) have been successfully impregnated with calcium by soaking them in a calcium nitrate solution and then heat treating them to decompose the nitrate. Potentially useful sorbents have also been prepared by pelletizing type I Portland cement and mixtures of cement and lime.

Wheelock, T.W.; Constant, K.; Doraiswamy, L.K.; Akiti, T.; Zhu, J.; Amanda, A.; Roe, R.

1997-09-01T23:59:59.000Z

423

The civic forum in ancient Israel : the form, function, and symbolism of city gates  

E-Print Network [OSTI]

of a small strip of lime plaster flooring found inside the 4the other half had a lime plaster finish (Ussishkin, Areaa few patches of lime plaster were found on top of the

Frese, Daniel Allan

2012-01-01T23:59:59.000Z

424

The effects of chemistry on the colloidal behavior of alumina slurries and copper nanohardness for copper chemical mechanical planarization  

E-Print Network [OSTI]

Arizona (2007). DuPont Air Products NanoMaterials L.L.C.February 2008). DuPont Air Products NanoMaterials L.L.C.Arizona (2007). DuPont Air Products NanoMaterials L.L.C.

Ihnfeldt, Robin Veronica

2008-01-01T23:59:59.000Z

425

Hydrogen and the Structure of the Transition Aluminas Karl Sohlberg,*, Stephen J. Pennycook,, and Sokrates T. Pantelides,  

E-Print Network [OSTI]

, with different greek- letter phases corresponding to different distributions of the Aluminum (Al) ions on the two,2 (petroleum refining), and as a support for automotive3,4 and industrial catalysts.5,6 In particular, catalytic reduction of automotive pollutants such as nitric oxide (NOx), as well as oxidation of carbon

Pennycook, Steve

426

MULTI-LAYER COATING OF ULTRATHIN POLYMER FILMS ON NANO-PARTICLES OF ALUMINA BY A PLASMA TREATMENT  

E-Print Network [OSTI]

(HRTEM) experiments showed that an extremely thin film of the pyrrole layer (10-20 ) was uni- formly as a second layer onto the surface of pyrrole. Subsequently, a third layer of pyrrole was coated on the top coating of nanoparticles is an important area in nanomaterials synthesis. Because of their special

Dalal, Vikram

427

Applied Catalysis A: General 232 (2002) 203217 Single step solgel made gold on alumina catalyst for selective  

E-Print Network [OSTI]

Seker, Erdogan Gulari Chemical Engineering Department, University of Michigan, Ann Arbor, MI 48109; Hydrogen tetranitratoaurate; Hydrogen tetrachloroaurate 1. Introduction Since Held et al. [1] and Iwamato operated gasoline engine vehicles. For example, Misono et al. [3] reported that the activity of cerium

Gulari, Erdogan

428

Surface characterizatin of palladium-alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas  

SciTech Connect (OSTI)

Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production, The interactions of mercury and arsenic with PdlAl2D3 model thin film sorbents and PdlAh03 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

Baltrus, J.P.; Granite, E.J.; Pennline, H.W.; Stanko, D.; Hamilton, H.; Rowsell, L.; Poulston, S.; Smith, A.; Chu, W.

2010-01-01T23:59:59.000Z

429

TEMPERATURE-PROGRAMMED DESORPTION AND REACTION OF CO AND H2 ON ALUMINA-SUPPORTED RUTHENIUM CATALYST  

E-Print Network [OSTI]

high temperature The hydrogenation is required carbon to hydrogenate i t to form CH^ of this graphitic Table Results on the TPS

Low, Gordon Gongngai

2011-01-01T23:59:59.000Z

430

INTERNATIONAL STUDIES OF ENHANCED WASTE LOADING AND IMPROVED MELT RATE FOR HIGH ALUMINA CONCENTRATION NUCLEAR WASTE GLASSES  

SciTech Connect (OSTI)

The goal of this study was to determine the impacts of glass compositions with high aluminum concentrations on melter performance, crystallization and chemical durability for Savannah River Site (SRS) and Hanford waste streams. Glass compositions for Hanford targeted both high aluminum concentrations in waste sludge and a high waste loading in the glass. Compositions for SRS targeted Sludge Batch 5, the next sludge batch to be processed in the Defense Waste Processing Facility (DWPF), which also has a relatively high aluminum concentration. Three frits were selected for combination with the SRS waste to evaluate their impact on melt rate. The glasses were melted in two small-scale test melters at the V. G. Khlopin Radium Institute. The results showed varying degrees of spinel formation in each of the glasses. Some improvements in melt rate were made by tailoring the frit composition for the SRS feeds. All of the Hanford and SRS compositions had acceptable chemical durability.

Fox, K; David Peeler, D; James Marra, J

2008-09-11T23:59:59.000Z

431

Alumina-Forming Austenitics: A New Approach to Thermal and Degradation Resistant Stainless Steels for Industrial Use  

SciTech Connect (OSTI)

A series of developmental AFA alloys was selected for study based on: 25 Ni wt.% (alloys A-F), 20 wt% Ni (alloys G-H), and 12 Ni wt.% (alloys I-L). An emphasis in this work was placed on the lower alloy content direction for AFA alloys to reduce alloy raw material cost, rather than more highly alloyed and costly AFA alloys for higher temperature performance. Alloys A-D explored the effects of Al (3-4 wt.%) and C (0.05-0.2 wt.%) in the Fe-25Ni-14Cr-2Mn-2Mo-1W-1Nb wt.% base range; alloys E and F explored the effects of removing costly Mo and W additions in a Fe-25Ni-14Cr-4Al-2.5Nb-2Mn-0.2C base, alloys G and H examined Nb (1-2.5wt.%) and removal of Mo, W in a Fe-20Ni-14Cr-3Al-2Mn-0.2 C wt.% base; and alloys I-L examined effects of C (0.1-0.2 wt.%) and Mn (5-10 wt.%) on a low cost Fe-14Cr-12Ni-3Cu-2.5Al wt.% base (no Mo, W additions). Creep testing resulted in elemental trends that included the beneficial effect of higher carbon and lower niobium in 20-25%Ni AFA alloys and, the beneficial of lower Mn in 12%Ni AFA alloys. Corrosion tests in steam and sulfidation-oxidation environments showed, in general, these alloys were capable of a ten-fold improvement in performance when compared to conventional austenitic stainless steels. Also, corrosion test results in metal-dusting environments were promising and, warrant further investigation.

David A Helmick; John H Magee; Michael P Brady

2012-05-31T23:59:59.000Z

432

Novel High Strength Ceria-Zirconia Toughened Alumina Ceramic with Superior High Temperature Corrosion and Erosion Resistance. Final Report  

SciTech Connect (OSTI)

Composite CeTZP/A1{sub 2}O{sub 3} (CeZTA) foams were developed and tested to determine their suitability as particulate filters in hot gaseous conditions generated by coal combustion in electric power plants. Exposure to these extreme corrosive conditions did not cause significant degradation in strength. Superior properties of these foams suggests they could be used for a variety of applications in environment, energy and chemical fields.

Giulio, R.; Butcher, K.

2004-01-13T23:59:59.000Z

433

Infrared optical properties of ?-alumina with the approach to melting: ?-like tetrahedral structure and small polaron conduction  

SciTech Connect (OSTI)

The normal spectral emittance of ?-Al{sub 2}O{sub 3} single crystal has been measured from room temperature up to the liquid state and from 20?cm{sup ?1} up to 10 000?cm{sup ?1}, in two polarization configurations. The spectra were fitted with a semi-quantum dielectric function model. AlO{sub 4} structure units are revealed within the phonon spectral range more than a hundred degrees below the melting point when heating from the solid state. In parallel, the anomalous increase of emittance observed within the transparency spectral range with the approach to melting appears strongly correlated. Implications on the electronic structure are discussed: the existence of small polaron conduction is suggested which has never been mentioned before.

Brun, J. F., E-mail: brun@cnrs-orleans.fr [CNRS, UPR 3079 CEMHTI, Orlans 45071 (France); UFR Collgium Sciences et Techniques, Universit d'Orlans, Orlans 45067 (France); Campo, L. del; De Sousa Meneses, D. [CNRS, UPR 3079 CEMHTI, Orlans 45071 (France); Polytech'Orlans, Universit d'Orlans, 45072 Orlans (France); Echegut, P. [CNRS, UPR 3079 CEMHTI, Orlans 45071 (France)

2013-12-14T23:59:59.000Z

434

Integration of Self-Assembled Porous Alumina and Distributed Bragg Reflector for Light Trapping in Si Photovoltaic Devices  

E-Print Network [OSTI]

Light trapping is an important issue for thin film silicon photovoltaic cells due to the limited absorption coefficient for near infrared light. In this letter, we present a photonic structure that combines porous anodic ...

Sheng, Xing

435

Effects of the maximum soil aggregates size and cyclic wetting-drying on the stiffness of a lime-treated clayey soil  

E-Print Network [OSTI]

and hydro-mechanical properties of compacted soils. Nevertheless, studies on the scale effect under climatic of treated soils, giving rise to changes in hydro-mechanical properties. This modification could be dependent system via evaporation) can give rise to significant change in soil hydro-mechanical properties

Paris-Sud XI, Université de

436

Production of cements from Illinois coal ash. Final technical report, September 1, 1995--August 31, 1996  

SciTech Connect (OSTI)

The objective of this program is to convert Illinois coal combustion residues, such as fly ash, bottom ash, and boiler slag, into novel cementitious materials for use in the construction industry. These residues are composed largely of SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, MgO, and CaO, which are also the major components of cement. Since the residues are used as an integral component of the cement and not just as additives to concrete, larger amounts of the residues can be utilized. The process uses submerged combustion to melt blends of coal combustion residues with lime, clay, and/or sand. The submerged combustion melter utilizes natural gas-oxidant firing directly into a molten bath to provide efficient melting of mineral-like materials. Use of this melter for cement production has many advantages over rotary kilns including very little, if any, grinding of the feed material, very low emissions, and compact size. During the first year of the program, samples of coal combustion residues were blended and mixed, as needed; with lime, clay, and/or sand to adjust the composition. Six mixtures, three with fly ash and three with bottom ash, were melted in a laboratory-scale furnace. The resultant products were used in mortar cubes and bars which were subjected to ASTM standard tests of cementitious properties. In the hydraulic activity test, mortar cubes were found to have a strength comparable to standard mortar cements. In the compressive strength test, mortar cubes were found to have strengths that exceeded ASTM blended cement performance specifications. In the ASR expansion test, mortar bars were subjected to alkali-silica reaction-induced expansion, which is a problem for siliceous aggregate-based concretes that are exposed to moisture. The mortar bars made with the products inhibited 85 to 97% of this expansion. These results show that residue-based products have an excellent potential as ASR-preventing additions in concretes.

Wagner, J.C.; Bhatty, J.L.; Mishulovich, A.

1997-05-01T23:59:59.000Z

437

Production of cements from Illinois coal ash. Technical report, September 1, 1995--November 30, 1995  

SciTech Connect (OSTI)

The objective of this program is to convert Illinois coal combustion residues, such as fly ash, bottom ash, and boiler slag, into novel cementitious materials for use in the construction industry. Currently only about 30% of the 5 million tons of these coal combustion residues generated in Illinois each year are utilized, mainly as aggregate. These residues are composed largely Of SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, MgO, and CaO, which are also the major components of cement. The process being developed in this program will use the residues directly in the manufacture of cement products. Therefore, a much larger amount of residues can be utilized. To achieve the above objective, in the first phase (current year) samples of coal combustion residues will be blended and mixed, as needed, with a lime or cement kiln dust (CKD) to adjust the CaO composition. Six mixtures will be melted in a laboratory-scale furnace at CTL. The resulting products will then be tested for cementitious properties. Two preliminary blends have been tested. One blend used fly ash with limestone, while the other used fly ash with CKD. Each blend was melted and then quenched, and the resulting product samples were ground to a specific surface area similar to portland cement. Cementitious properties of these product samples were evaluated by compression testing of 1-inch cube specimens. The specimens were formed out of cement paste where a certain percentage of the cement paste is displaced by one of the sample products. The specimens were cured for 24 hours at 55{degrees}C and 100% relative humidity. The specimens made with the product samples obtained 84 and 89% of the strength of a pure portland cement control cube. For comparison, similar (pozzolanic) materials in standard concrete practice are required to have a compressive strength of at least 75% of that of the control.

Wagner, J.C. [Institute of Gas Technology, Chicago, IL (United States); Bhatty, J.I.; Mishulovich, A. [Construction Technology Labs., Inc., Washington, DC (United States)

1995-12-31T23:59:59.000Z

438

Material and energy flows in the materials production, assembly, and end-of-life stages of the automotive lithium-ion battery life cycle  

SciTech Connect (OSTI)

This document contains material and energy flows for lithium-ion batteries with an active cathode material of lithium manganese oxide (LiMn{sub 2}O{sub 4}). These data are incorporated into Argonne National Laboratory's Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, replacing previous data for lithium-ion batteries that are based on a nickel/cobalt/manganese (Ni/Co/Mn) cathode chemistry. To identify and determine the mass of lithium-ion battery components, we modeled batteries with LiMn{sub 2}O{sub 4} as the cathode material using Argonne's Battery Performance and Cost (BatPaC) model for hybrid electric vehicles, plug-in hybrid electric vehicles, and electric vehicles. As input for GREET, we developed new or updated data for the cathode material and the following materials that are included in its supply chain: soda ash, lime, petroleum-derived ethanol, lithium brine, and lithium carbonate. Also as input to GREET, we calculated new emission factors for equipment (kilns, dryers, and calciners) that were not previously included in the model and developed new material and energy flows for the battery electrolyte, binder, and binder solvent. Finally, we revised the data included in GREET for graphite (the anode active material), battery electronics, and battery assembly. For the first time, we incorporated energy and material flows for battery recycling into GREET, considering four battery recycling processes: pyrometallurgical, hydrometallurgical, intermediate physical, and direct physical. Opportunities for future research include considering alternative battery chemistries and battery packaging. As battery assembly and recycling technologies develop, staying up to date with them will be critical to understanding the energy, materials, and emissions burdens associated with batteries.

Dunn, J.B.; Gaines, L.; Barnes, M.; Wang, M.; Sullivan, J. (Energy Systems)

2012-06-21T23:59:59.000Z

439

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Cement Industry in China  

E-Print Network [OSTI]

in Shandong Province. Sinton, J.E. , 1996. Energy Efficiencyenvironmental impacts (Sinton, 1996; ITIBMIC, 2004). Rotarycurrently-used rotary kilns (Sinton, 1996). However, future

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

440

Sources and transport of delta 14C in CO2within the Mexico City Basin and vicinity  

E-Print Network [OSTI]

kilns; medical waste incineration; and emissions from theand haz- ardous waste incineration. Mexico has two hazardousrecycling strategy. This incineration has been led by the

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

24th Benelux Meeting Systems and Control  

E-Print Network [OSTI]

applied on a half-car test rig.30­14.55 Contribution to the control of a rotary cement kiln - A simu- lation . . . . . . . . . . . . . . . . . . . . . . . . . . .

Serdijn, Wouter A.

442

anhui province china: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Guizhu 7 Increasing Energy Efficiency and Reducing Emissions from China's Cement Kilns: Audit Report of Two Cement Plants in Shandong Province, China University of California...

443

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

Wang, L. , 2008. Alternative fuel using and waste materialPolicy Research on Alternative Fuels for Cement Industry incement and using alternative fuels in the cement kiln. There

Price, Lynn

2010-01-01T23:59:59.000Z

444

Energy Efficiency Improvement Opportunities for the Cement Industry  

E-Print Network [OSTI]

on Power Generation by Waste Heat of the Kiln in NingguoPure Low Temperature & Waste Heat in Beijing Cement Ltd. ;flash distillation waste heat power generation demonstration

Worrell, Ernst

2008-01-01T23:59:59.000Z

445

China Energy and Emissions Paths to 2030  

E-Print Network [OSTI]

cooler Low temperature Waste Heat Recovery power generationquantities of low grade waste heat from the kilns or clinkerLow temperature Waste Heat Recovery power generation: A

Fridley, David

2012-01-01T23:59:59.000Z

446

Advanced Organic Vapor Cycles for Improving Thermal Conversion Efficiency in Renewable Energy Systems  

E-Print Network [OSTI]

Systems for Industrial Waste Heat Recovery. c DanielCycle for Cement Kiln Waste Heat Recovery Power Plants. and high temperature waste heat reclamation and solar

Ho, Tony

2012-01-01T23:59:59.000Z

447

Guidebook for Using the Tool BEST Cement: Benchmarking and Energy Savings Tool for the Cement Industry  

E-Print Network [OSTI]

Advanced Concepts of Waste Heat Recovery in Cement Plantsquantities of low grade waste heat from the kilns or clinkerthere is significant effect of waste heat recovery on dioxin

Galitsky, Christina

2009-01-01T23:59:59.000Z

448

Bottom-up Representation of Industrial Energy Efficiency Technologies in Integrated Assessment Models for the Cement Sector  

E-Print Network [OSTI]

Advanced Concepts of Waste Heat Recovery in Cement Plantsbuilding controls, waste heat recovery or adjustable speedquantities of low grade waste heat from the kilns or clinker

Sathaye, J.

2011-01-01T23:59:59.000Z

449

Analysis of Energy-Efficiency Opportunities for the Cement Industry in Shandong Province, China  

E-Print Network [OSTI]

Banerjee, R. , 2005. Energy Efficiency and Demand SideKiln Systems, Energy Efficiency in the Cement Industry (Ed.for Improving Energy Efficiency, Reducing Pollution and

Price, Lynn

2010-01-01T23:59:59.000Z

450

bia-cemkiln | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 Industrial Carbon Capture and Storage Clean Coal Power Initiative Power Plant Improvement Initiative Clean Coal Technology Demonstration Program FutureGen Cement Kiln Flue Gas...

451

Industry  

E-Print Network [OSTI]

A.T, 2001: Prospects for biogas harvesting at Sungunn WongseRenewables Biomass, Biogas, PV, Wind turbines, Hydropowermill, fluidized bed kiln Biogas, Biomass Cullet preheating

Bernstein, Lenny

2008-01-01T23:59:59.000Z

452

Multi-barrier borehole canister designs for a tuff repository  

SciTech Connect (OSTI)

Initial dimensions are presented for proposed multi-barrier spent fuel borehole canisters using coated shells combined with sacrificial anodes and alkaline, oxide barriers to adjust potential and pH of the exterior shell into thermodynamically passive or immune regions of the Pourbaix diagram. Configuration of the 3 PWR canister is similar to the 1983 Site Characterization Project (SCP) borehole design. Canister dimensions were determined by using material performance data to calculate wall thickness, criticality, and sacrificial anode life. For the 3-PWR canister. Incoloy 825 is the preferred exterior canister shell material; copper-nickel alloy CDA 715 is the preferred interior canister shell material. High-lime concrete or alumina is preferred for the alkaline filler. Magnesium alloy is the preferred sacrificial anode material. Coating the canister exterior would be necessary to reduce corrosion current density to the point where a 10,000 year design life is possible. A 1 PWR canister has lower mass, thinner walls and lower criticality than the 3 PWR design. Equilibrium calculations for the historical average composition of J-13 water using the aquatic chemical speciation program WQ4F show positive saturation indices for several minerals, indicating potential for deposition on the canister exterior over long time periods. Uniform deposition could reduce corrosion rate by hindering transport of corrosion products from the canister surface. If deposition is non-uniform, local corrosion could increase through development of differential oxygen concentration cells.

James, D.E.; Skaggs, R.L.; Mohansingh, S.

1994-05-01T23:59:59.000Z

453

Petascale Simulations of Self-Healing Nanomaterials | Argonne...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

simulation of the oxidation of a fractured alumina matrix embedded with silicon carbide nanoparticles Reactive molecular dynamics simulation of the oxidation of a fractured alumina...

454

The Science of Sentiment  

E-Print Network [OSTI]

the models were completed I then took plaster molds of the heads and prepared the molds to be filled with glaze. I filled the molds with a glaze and silica sand... the kiln with the plaster mold included. When the pieces were removed from the kiln the chemical water was no longer present in the plaster and the mold crumbled...

Bates, Jamie M.

2012-05-31T23:59:59.000Z

455

Carbon Offsetting: An Efficient Way to Reduce Emissions or to Avoid Reducing Emissions? An Investigation and Analysis of Offsetting Design and Practice in India and China  

E-Print Network [OSTI]

cement factories are small inefficient vertical shaft kilnvertical shaft kilns (VSKs). Only the USs 73 and Indias cementcement plants creates incentives to carry out the phase out of the factories that use small inefficient vertical shaft kilns.

Haya, Barbara

2010-01-01T23:59:59.000Z

456

Science Arts & Mtiers (SAM) is an open access repository that collects the work of Arts et Mtiers ParisTech  

E-Print Network [OSTI]

the problems associated with the intermittent nature of solar energy. The aim is to collect and store solar this version : David LUNA, Jean-Pierre NADEAU, Yves JANNOT - Model and simulation of a solar kiln with energy.03.024 #12;Model and simulation of a solar kiln with energy storage D. Luna a , J.-P. Nadeau a,*, Y. Jannot b

Boyer, Edmond

457

Cost-effective Surface Modifications of Silica and Alumina Achieved by Way of a Simple In-house Set-up  

E-Print Network [OSTI]

using lead acetate (20wt%), affording a yellow color with samples prepared by the gas-phase approach and enabling diverse application. The classic modification is based upon a hydrolysis- condensation mechanism, and in dry toluene solution or in the gas phase at various pressures if displacement is preferred

Taralp, Alpay

458

New insight into artifactual phenomena during in vitro toxicity assessment of engineered nanoparticles: study of TNF-adsorption on alumina oxide nanoparticle  

E-Print Network [OSTI]

engineered NP [aluminum oxide hydroxide, AlO(OH)]. The rate of TNF- degradation and its adsorption (on dollars (National Science Foundation, 2003). NP have applications in various fields such as automotive by inducing inflammation or oxidative stress. In particular, boehmite NP [aluminum oxide hydroxide, Al

Boyer, Edmond

459

Investigation of porous alumina as a self-assembled diffractive element to facilitate light trapping in thin film silicon solar cells  

E-Print Network [OSTI]

Thin film solar cells are currently being investigated as an affordable alternative energy source because of the reduced material cost. However, these devices suffer from low efficiencies, compared to silicon wafer solar ...

Coronel, Naomi (Naomi Cristina)

2009-01-01T23:59:59.000Z

460

The catalytic oxidation of propylene: investigation of the effects of composition on activities of Fe?O?, K?O promoted chromia-alumina catalysts  

E-Print Network [OSTI]

-five por cent for acrolein, A similar British patent (16) states that the oxidation of propy lens with oxygen in the presence of Ag Se and an o&ds of Cu resulted in formati&m of acrolein. The catalyst consisted of a homogeneous ooat- ing of Ag2Se and Cu...O on asbestos. At 350 degrees Centigrade, fifteen per cent of the propylene was converted to acrolein and four per cent to c=rbon diced. ds. A PbSe-Cu0 on asbestos catalyst under "imilar con- di. tions gave nine per cent, acra ein and two per cent carbon...

Perkins, Thomas Keeble

1953-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Co-Optimization of Wrought Alumina-Forming Austenitic Stainless Steel Composition Ranges for High-Temperature Creep and Oxidation/Corrosion Resistance  

SciTech Connect (OSTI)

A seriesofcandidatealumina-formingaustenitic(AFA)stainlesssteelsdesignedtoevaluatetheeffectsof variationinAl,C,Cr,Mn,Nb,andNicontentonhigh-temperaturetensileproperties,creep,and oxidation/corrosionresistancewerestudied.ThecompositionsassessedwerebasedonmediumNi (20 25 wt%)andlowNi(12wt%)AFAvariationsstrengthenedprimarilybyMCand/orM23C6 carbide precipitates,andahighNi(32wt%)AFAsuperalloyvariationstrengthenedprimarilyby -Ni3Al intermetallic precipitates.Tensileandcreeppropertiesweremeasuredat650and750/760 1C, oxidation resistance from650to900 1C inairwithwatervaporandsteamenvironments,andsulfidation oxidation resistance inAr 20%H2 20%H2O 5% H2S at550and650 1C. Optimizedcompositionrangesfordifferent use temperaturesrangesbasedontheseevaluationsarepresented.

Brady, Michael P [ORNL] [ORNL; Magee, John H [Carpenter Technology Corporation] [Carpenter Technology Corporation; Yamamoto, Yukinori [ORNL] [ORNL; Helmick, David [Carpenter Technology Corporation] [Carpenter Technology Corporation; Wang, Lu [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK)

2014-01-01T23:59:59.000Z

462

On the Loss of Protective Scale Formation in Creep-Resistant, Alumina-Forming Austenitic Stainless Steels at 900?aC in Air  

SciTech Connect (OSTI)

A family of creep-resistant, Al2O3-forming austenitic (AFA) stainless steels was recently developed. The alloys exhibit excellent oxidation resistance up to 800 aC, but are susceptible to internal attack of Al at higher temperatures. In the present work, higher levels of Ni, Cr, Al, and Nb additions were found to correlate with improved oxidation behavior at 900 aC in air. The alloys generally appeared to be initially capable of external Al2O3 scale formation, with a subsequent transition to internal attack of Al (internal oxidation and internal nitridation) that is dependent on alloy composition. Compositional profiles at the alloy/scale interface suggest that the transition to internal oxidation is preceded by subsurface depletion of Al. Alloy design directions to increase the upper-temperature limit of protective Al2O3 scale formation in these alloys are discussed

Brady, Michael P [ORNL; Yamamoto, Yukinori [ORNL; Pint, Bruce A [ORNL; Santella, Michael L [ORNL; Maziasz, Philip J [ORNL; Walker, Larry R [ORNL

2008-01-01T23:59:59.000Z

463

Li{sup +} ion emission from a hot-plate alumina-silicate source stimulated by flash heating with an infrared laser  

SciTech Connect (OSTI)

The Neutralized Drift Compression Experiment-II accelerator under construction at Lawrence Berkeley National Laboratory has been designed to employ a lithium-doped alumino-silicate (Al-Si) hot-plate surface-ionization ion source. In order to achieve the design 1 mA/cm{sup 2} current density, the emitter must be constantly kept at a high temperature, leading to the accelerated loss of Li material as ions or neutrals. As a result, the estimated lifetime of the source is 50 h. This lifetime can be extended if the source is kept at low temperature during standby, and pulse heated to the high temperature during the ion extraction phase only. A pulsed heating technique based on an infrared laser (CO{sub 2} gas discharge, {lambda}= 10.6 {mu}m) is described in this paper. The feasibility of ion current emission stimulated by flash heating with an infrared (IR) laser was demonstrated. High repeatability of the laser-stimulated ion current was observed, creating an opportunity for modulation and gating of the ion current with a laser pulse. It was found that with the available low power ({approx_equal}115 W/cm{sup 2}) IR laser, current densities as high as 0.8 mA/cm{sup 2} could be achieved with a 2.8 mm diameter source. Various approaches for scaling to a larger (10 cm diameter) source and the application of short pulse, high power lasers are discussed. The results and conclusions of this paper may apply to various species of hot-plate ion sources.

Ni, P. A.; Kwan, J. W.; Roy, P. K.; Waldron, W. L. [Lawrence Berkeley National Laboraotry, University of California, Berkeley, California (United States)

2011-02-15T23:59:59.000Z

464

In situ high-energy synchrotron radiation study of boehmite formation, growth, and phase transformation to alumina in sub- and supercritical water.  

SciTech Connect (OSTI)

Boehmite (AlOOH) nanoparticles have been synthesized in subcritical (300 bar, 350 C) and supercritical (300 bar, 400 C) water. The formation and growth of AlOOH nanoparticles were studied in situ by small- and wide-angle X-ray scattering (SAXS and WAXS) using 80 keV synchrotron radiation. The SAXS/WAXS data were measured simultaneously with a time resolution greater than 10 s and revealed the initial nucleation of amorphous particles takes place within 10 s with subsequent crystallization after 30 s. No diffraction signals were observed from Al(OH){sub 3} within the time resolution of the experiment, which shows that the dehydration step of the reaction is fast and the hydrolysis step rate-determining. The sizes of the crystalline particles were determined as a function of time. The overall size evolution patterns are similar in sub- and supercritical water, but the growth is faster and the final particle size larger under supercritical conditions. After approximately 5 min, the rate of particle growth decreases in both sub- and supercritical water. Heating of the boehmite nanoparticle suspension allowed an in situ X-ray investigation of the phase transformation of boehmite to aluminium oxide. Under the wet conditions used in this work, the transition starts at 530 C and gives a two-phase product of hydrated and non-hydrated aluminium oxide.

Lock, N.; Bremholm, M.; Christensen, M.; Almer, J .D.; Chen, Y.-S.; Iverson, B. B.; Univ. of Aarhus; Univ. of Chicago; Princeton Univ.

2009-01-01T23:59:59.000Z

465

Delivered by Ingenta to: Stevens Institute of Technology  

E-Print Network [OSTI]

for hydrophobicity. Nickel nanowires were synthesized by electrodeposition through a porous alumina membrane

Yang, Eui-Hyeok

466

Journal of Catalysis 221 (2004) 354364 www.elsevier.com/locate/jcat  

E-Print Network [OSTI]

for hydrotreating processes. However, most studies on these catalysts have focused on alumina-supported systems

Resasco, Daniel

467

Production of ritual material culture in the Pre-Pottery Neolithic period in Jordan : some methods for analytical investigation  

E-Print Network [OSTI]

Near East: Experimental lime-plaster production at the Pre-just like bone, charcoal, plaster, and anything else thatsuch as studies of lime plaster (Goren and Goring-Morris

Bennallack, Kathleen Celia

2012-01-01T23:59:59.000Z

468

MSU Extension Publication Archive Archive copy of publication, do not use for current recommendations. Up-to-date  

E-Print Network [OSTI]

Diluting and using emulsions Dormant spraying Dry lime-sulphur Dusting D N Oils Dormant oils European red Insects on plums Introduction ..- [ron-sulphate-lime mixture I .ead arsenate Leaf-curl I ,eaf hoppers Leaf

469

Anaerobic fermentation of rice straw and chicken manure to carboxylic acids  

E-Print Network [OSTI]

In this work, 80% lime-treated rice straw and 20% lime-treated chicken manure were used as substrates in rotary fermentors. Countercurrent fermentation was performed at various volatile solid loading rates (VSLR) and liquid residence times (LRT...

Agbogbo, Frank Kwesi

2007-04-25T23:59:59.000Z

470

Conversion of Waste Biomass into Useful Products  

E-Print Network [OSTI]

Waste biomass includes municipal solid waste (MSW), municipal sewage sludge (SS), industrial biosludge, manure, and agricultural residues. When treated with lime, biomass is highly digestible by a mixed culture of acid-forming microorganisms. Lime...

Holtzapple, M.

471

ForPeerReview Biogeochemical reduction processes in a hyper-alkaline  

E-Print Network [OSTI]

of industrial7 processes, e.g., lime production waste, steelworks slags, coal combustion residues, Solvay8

Burke, Ian

472

E-Print Network 3.0 - aurantifolia swingle para Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

avo- cado (Persea americana Mill.) acid lime (Citrus aurantifolia Swingle), and potato (Solanum... aurantifolia, Solanum tuberosum, PLU, postharvest, produce labeling...

473

Environmentally Safe, Large Volume Utilization Applications for Gasification Byproducts  

SciTech Connect (OSTI)

Samples of gasification by-products produced at Polk Station and Eastman Chemical were obtained and characterized. Bulk samples were prepared for utilization studies by screening at the appropriate size fractions where char and vitreous frit distinctly partitioned. Vitreous frit was concentrated in the +20 mesh fraction while char predominated in the -20+100 mesh fraction. The vitreous frit component derived from each gasifier slag source was evaluated for use as a pozzolan and as aggregate. Pozzolan testing required grinding the frit to very fine sizes which required a minimum of 60 kwhr/ton. Grinding studies showed that the energy requirement for grinding the Polk slag were slightly higher than for the Eastman slag. Fine-ground slag from both gasifiers showed pozzoalnic activity in mortar cube testing and met the ASTM C618 strength requirements after only 3 days. Pozzolanic activity was further examined using British Standard 196-5, and results suggest that the Polk slag was more reactive than the Eastman slag. Neither aggregate showed significant potential for undergoing alkali-silica reactions when used as concrete aggregate with ASTM test method 1260. Testing was conducted to evaluate the use of the frit product as a component of cement kiln feed. The clinker produced was comprised primarily of the desirable components Ca{sub 3}SiO{sub 5} and Ca{sub 2}SiO{sub 4} after raw ingredient proportions were adjusted to reduce the amount of free lime present in the clinker. A mobile processing plant was designed to produce 100 tons of carbon from the Eastman slag to conduct evaluations for use as recycle fuel. The processing plant was mounted on a trailer and hauled to the site for use. Two product stockpiles were generated; the frit stockpile contained 5% LOI while the carbon stockpile contained 62% LOI. The products were used to conduct recycle fuel tests. A processing plant was designed to separate the slag produced at Eastman into 3 usable products. The coarse frit has been shown to be suitable for use as clinker feed for producing Portland cement. The intermediate-size product is enriched in carbon (58-62% C) and may be used as recycle fuel either in the gasifier or in a PC boiler. The fines product contains 30-40% C and may also be used as a recycle gasifier fuel, as is presently done at TECO's Polk Station, however, due to gasifier operating requirements for the production of syngas, this is not feasible at Eastman.

J.G. Groppo; R. Rathbone

2008-06-30T23:59:59.000Z

474

EXPOS 20: HUMAN DEATH AND DISEASE--ACHTERBERG SPRING 2012: 2-4 IIDDEEAASS && SSTTRRUUCCTTUURREE  

E-Print Network [OSTI]

of possible "ideas", aka fruits: Apple; Banana; Cranberry; Fig; Kiwi; Lime; Nectarine; Pear; Pitaya; Raspberry don't like Banana Apple Cranberry Fig Kiwi Lime Nectarine Raspberry Pear Pitaya Student 3 Fruits I Cranberry Fig Kiwi Nectarine Banana Pear Pitaya Raspberry Lime Possible type of thesis: Fruits can grow

Wolfe, Patrick J.

475

Ann. For. Sci. 63 (2006) 861869 861 c INRA, EDP Sciences, 2006  

E-Print Network [OSTI]

due to acid rain and soil acidification [39, 40]. The ex- pected positive effects of forest liming, experimental acid irrigation, acid irrigation + liming, normal irrigation, and normal irrigation + liming. The elemental concentrations of the acid irrigated treatment did not differ significantly from the normal

Paris-Sud XI, Université de

476

Beyond Back of the Envelope Savings Calculations  

E-Print Network [OSTI]

of a clay tunnel kiln An old 1950's-vintage tunnel kiln with an independent gas meter is repaired and modernized with new burners. One might think that energy savings can be confmned by simply comparing the before and after gas meter readings..., but this would not tell the whole story. In fact, the gas use had increased! The plant's production levels had increased so that the gross amount being dried had increased and the new kiln improved the net product to gross input ratio by decreasing...

Griffiths, D. M.; Reid, L.

477

Atmos. Chem. Phys., 9, 49734985, 2009 www.atmos-chem-phys.net/9/4973/2009/  

E-Print Network [OSTI]

the burning of hazardous waste in cement kilns; medical waste incineration; and emissions from the Laguna for validating national emission claims of CO2 within the framework of the Kyoto Protocol. 1 Introduction

Meskhidze, Nicholas

478

Multidisciplinary Capstone Design Projects College of Engineering School of Mechanical Engineering  

E-Print Network [OSTI]

charcoal kiln), Climate Healers (Rajasthan, India ­ Solar energy storage cooks stove), Seedr L3C (Cold net energy solar health care clinics and regional vaccine stores), S2O (South Africa ­ Community

Colton, Jonathan S.

479

SOLID WOOD PRODUCTS I TECHNICAL NOTE CALIBRATION OF MOISTURE METERS FOR  

E-Print Network [OSTI]

tanks, and boats, the kiln and allowed to cool. They were content (MC) of wood. However, the cor and electrical resis- cypress have been supplied by moisture handled or conditioned. One moisture tance

480

International Best Practices for Pre-Processing and Co-Processing Municipal Solid Waste and Sewage Sludge in the Cement Industry  

E-Print Network [OSTI]

December. Busato, L.C. n.d. Dioxins and Furans in Brazil:release and control of dioxins in cement kilns - A review.and Quantification of Dioxin and Furan Releases. Geneva,

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lime kiln alumina" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

E-Print Network 3.0 - apc cutting equipment Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Refurbishment Of An Existing Hazardous Waste Incinerator In Eastern Germany On a Tum-Key Contract Basis Summary: of erection of the new rotary kiln and remaining BOP-equipment...

482

Energy Efficiency Improvement and Cost Saving Opportunities for Cement Making. An ENERGY STAR Guide for Energy and Plant Managers  

E-Print Network [OSTI]

B. , 1990. Utilisation of Waste Heat from the Cement RotaryAdvanced Concepts of Waste Heat Recovery in Cement Plantsa roller mill. Utilizing waste heat from the kiln exhaust,

Worrell, Ernst

2008-01-01T23:59:59.000Z

483

Fuel Saving Ideas for Metal and Ceramic Processing  

E-Print Network [OSTI]

An easy method is presented for analyzing sources of heat loss from industrial processing furnaces, kilns, and ovens; and thus for recognizing opportunities for fuel saving. This will relate to melting, heat treating and hot forming of metals...

Reed, R. J.

1982-01-01T23:59:59.000Z

484

In Situ CO, Oxygen, and Opacity Measurement for Optimizing Combustion Control System Performance  

E-Print Network [OSTI]

Applications Alumino Kilns Bog Houses Carbon Black (Furnace Process) Cement KiIns Cool Fired Steam Generators Copper Smelters Electrostatic Precipitators Electr ic Arc Furnaces Fluid Catalytic Cracking Units Glass Furnaces Incinerators Industrial...

Molloy, R. C.

1982-01-01T23:59:59.000Z

485

Development of a CO?b2?s laser-based system for characterization of high-temperature structural ceramics  

E-Print Network [OSTI]

-based testing systems for high-temperature ceramic materials have limited capabilities. To test in these severe testing environments requires special grips that will withstand the elevated temperatures and the environment. Furthermore, kilns severely restrict... because the time response of the system is not constrained by the thermal inertia of the kiln. ~ Thermal shock to the ceramics can be avoided by using the laser at low power to slowly heat the sainple to the desired temperature. Heating would be done...

Bowman, David Winslow

1991-01-01T23:59:59.000Z

486

Using waste wood as fuel saves $2000 per day  

SciTech Connect (OSTI)

Sawdust and wood residue replaced natural gas or number 2 fuel oil to fire 2 kilns at the Cherokee Brick Co. in Raleigh, NC, resulting in savings of $2000/day. Exhaust air from the kilns was sent directly back to a rotating dryer to dry the waste wood. The dried wood containing 8 to 12% moisture was supplied, around the clock, at a rate of 140 ton/day of dry material. (BLM)

Ragland, W. (Cherokee Brick Co., Raleigh, NC); Byrnes, D.

1981-11-01T23:59:59.000Z

487

Passamaquoddy Innovative Clean Coal Technology Program: Public design report  

SciTech Connect (OSTI)

The Passamaquoddy Technology Recovery Scrubber{trademark} was conceived and developed specifically to address two problems experienced by the Dragon cement plant; meeting increasingly stringent gas emission limits for sulfur dioxide, and disposing of kiln dust, containing alkali oxides, which had to be wasted in order to avoid kiln operating and product quality problems. The idea involved making the kiln dust into a slurry in order to leach out the species (primarily potassium and sulfur) which rendered it unacceptable for return to kiln feed. This slurry, the liquid part of which is an alkaline solution, acts as a scrubbing reagent for SO{sub 2} in the flue gas while CO{sub 2} in the gas serves to precipitate soluble calcium and release sulfate for combination with the potassium. The effect of the process is to scrub SO{sub 2} from kiln flue gas, extract the volatile species from the dust allowing it to be returned to the kiln, and yield a leachate comprising potassium sulfate which can be crystallized (using heat recovered from the flue gas) and sold as fertilizer. Apart from widespread application in the cement industry, it was evident that, if the process could be demonstrated, its potential would extend to any plant burning fossil fuel where an alkaline waste either occurs intrinsically or can be juxtaposed. Obvious candidates appeared to include the pulp and paper industry and waste incineration. The chemistry was proved in a 1/100th scale pilot plant using actual kiln dust and a slip stream of kiln gas. A full scale demonstration installation was commissioned in 1989 by CDN (USA), the owners of the Dragon plant with the financial support of the US Department of Energy under its innovative Clean Coal Technology Program.

Not Available

1993-08-01T23:59:59.000Z

488

Energy Savings by Veneering  

E-Print Network [OSTI]

were 10%. Face Brick Manufacturer - The burning zone of a tunnel kiln was veneered with the wallpaper method using 1" of 8/1 density Ceramic Fiber blanket. The customer experienced 5% fuel cost reduction versus a calculated 4%. Due to better... Shock 4. High Reflectivity From 1964, the use of Ceramic Fiber as a total furnace lining material has gained widespread Industry acceptance in heat treating, heating, re heating furnaces, and ceramic kilns. In the 1974-1976 period, it became...

Cook, T. H.

1980-01-01T23:59:59.000Z

489

Muffle furnace evaluation of FGD sludge-coal-clay mixtures as potential synthetic aggregates  

E-Print Network [OSTI]

and fusion, which may make them difficult to handle in commercial production. An actual test using a pilot-sized rotary kiln would be required to evaluate this problem. Small amounts of powdered coal were found not to significantly affect these mixtures... proposed rotary kiln experimental program. ACKNOWLEDBEMENTS The author wishes to thank Twin City Testing and Engineering Laboratories, Inc. of St. Paul, Minnesota and Northe& n States Power Co. for their assistance during this program. A special note...

Pettit, Jesse William

2012-06-07T23:59:59.000Z

490

ONE-DIMENSIONAL PSEUDO-HOMOGENEOUS PACKED BED REACTOR MODELING INCLUDING NO-CO KINETICS  

E-Print Network [OSTI]

the chemical species and energy equations for dynamically incompressible flow in one-dimension. Furthermore, the chemical kinetics on the reduction reaction of nitric oxide by carbon monoxide over rhodium-alumina and platinum-alumina catalysts is investigated...

Srinivasan, Anand

2011-08-31T23:59:59.000Z

491

Method for removing fluoride contamination from nitric acid  

SciTech Connect (OSTI)

Fluoride ions are removed from nitric acid solution by contacting the vaporized solution with alumina or zirconium.

Howerton, W.B.; Pruett, D.J.

1982-07-13T23:59:59.000Z

492

Partial-Transient-Liquid-Phase Bonding of Advanced Ceramics Using Surface-Modified Interlayers  

E-Print Network [OSTI]

Alumina Diffusion Bonding and Titanium Active Brazing."O 3 -Titanium Adhesion in the View of the Diffusion Bonding

Reynolds, Thomas Bither

2012-01-01T23:59:59.000Z

493

Thermal conductivity of highly-ordered mesoporous titania thin films from 30 to 320 K  

E-Print Network [OSTI]

Thermal resistance of grain boundaries in alumina ceramicsThermal conductivity of highly porous zirconia. Journal of the European Ceramic

2011-01-01T23:59:59.000Z

494

Catalytic dehydrogenation of ethane  

E-Print Network [OSTI]

phase of a more thorough investigation of the kinetics of the dehydrogenation of ethane over a chromia-alumina catalyst. This catalyst was prepared by impregnation of activated alumina with a decomposable chromium salt. Experiments were carried out... and butanes using a chromia-alumina catalyst. They reported good results with alumina alone, but showed that impregnation of the aluzd. na with decomposable chromium salts increased the activity of the catalyst considerably. Feed to their reaction chamber...

Place, Harold Glenn

1955-01-01T23:59:59.000Z

495

E-Print Network 3.0 - aluminide green sheet Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Protective Alumina Scales Evaluation of Iron Aluminide Hot... -density, thin, green coatings, therefore, minimizing shrinkage and cracking during sintering....

496

Vegetative regeneration in selected south Texas shrubs  

E-Print Network [OSTI]

. Study Site. Regenerative Structure Description. Sprouting Potential of Roots. Motte Regeneration. Regrowth Comparison. Shrub Stem Classification. . 13 . . . 14 16 17 17 18 RESULTS AND DISCUSSION. Regenerative Morphology Desert Yaupon Lime... varying regenerative responses of south Texas shrubs following burning. Lime pricklyash (~n~xlum tacaara (L. ) Sarg. ) suffered the least mortality (4%) while the highest mortality (40%) occurred with lotebush. Lime pricklyash sprouted vigorous- ly...

Flinn, Robert C.

1986-01-01T23:59:59.000Z

497

Ammonia volatilization from surface application of ammonium sulfate to carbonate systems  

E-Print Network [OSTI]

from surface application of' ammonium fertilizers to calcareous soils 7 Ammonia Volatilization from Limed, Acid Soil Comparison of ammonia vole, tilization from different ammonium fertilizers Other factors affecting ammonia volatilization 10...-Newman-Keul's multiple range analysis of ammonia volatilization from a limed, acid soil supporting Coastal bermudagrass as affected by calcium carbonate . 58 Student-Newman-Keul's multiple range analysis of ammonia volatilization i'rom a limed. , acid soil supporting...

Feagley, Sam Edward

1976-01-01T23:59:59.000Z

498

Geomicrobiology Journal, 24:655669, 2007 Copyright c Taylor & Francis LLC  

E-Print Network [OSTI]

Poorly controlled landfilling of chromite ore processing residue (COPR), particularly highly alkaline lime process is still generating chromium contaminated wastes in countries such as China, Russia, India

Burke, Ian

499

University of Arizona Technology and Research Initiative Fund 2010/2011  

E-Print Network [OSTI]

: cartridge membrane filtration; EDR: electrodialysis reversal; PLS: partial lime softening; GMF: granular: membrane microfiltration; CA: chemical addition; RO: reverse osmosis; PS: permeate stabilization; CF

Fay, Noah

500

Industrial Demand Module  

Gasoline and Diesel Fuel Update (EIA)

products (NAICS 3272) Wood products (NAICS 321) Cement and Lime (NAICS 32731, 32741) Plastic and rubber products (NAICS 326) Construction (NAICS 23) Iron and steel (NAICS 3311-...