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Sample records for li zhanqing university

  1. Linkping University Electronic Press Electronic Publication of a Thesis with LiU Electronic Press

    E-Print Network [OSTI]

    Zhao, Yuxiao

    Linköping University Electronic Press Electronic Publication of a Thesis with LiU Electronic Press with LiU E-Press. In individual cases where there are complications because of e.g. copyright on the world wide web by Linköping University Electronic Press (www.ep.liu.se). In so doing, I certify

  2. LI

    Office of Legacy Management (LM)

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  3. LiU E-Press Linkoping University Electronic Press 2006-01

    E-Print Network [OSTI]

    Zhao, Yuxiao

    LiU E-Press Link¨oping University Electronic Press 2006-01 Erik Sandewall and Peter Berkesand Link¨oping University Electronic Press Activities during 2005 Date of Manuscript: 2006-02-13 Related information can be obtained via the following WWW pages: E-Press Website: The author: http://www.ep.liu.se/ http

  4. Lithium Diffusion in the Post-Recombination Universe and Spatial Variation of [Li/H

    E-Print Network [OSTI]

    Maxim Pospelov; Niayesh Afshordi

    2012-08-03

    The observed amount of lithium for low metallicity population II stars (known as the Spite plateau) is a factor of $\\sim 3-5$ lower than the predictions of the standard cosmology. Since the observations are limited to the local Universe (halo stars, globular clusters and satellites of the Milky Way) it is possible that certain physical processes may have led to the spatial separation of lithium and local reduction of [Li/H]. We study the question of lithium diffusion after the cosmological recombination in sub-Jeans dark matter haloes, taking into account that more than 95% of lithium remains in the singly-ionized state at all times. Large scattering cross sections on the rest of the ionized gas leads to strong coupling of lithium to protons and its initial direction of diffusion coincides with that of H$^+$. In the rest frame of the neutral gas this leads to the diffusion of H$^+$ and Li$^+$ out of overdensities with the trend of reducing [Li/H] in the minima of gravitational wells relative to the primordial value. We quantify this process and argue that, with certain qualifications, it may have played a significant role in creating local lithium deficiency within the primordial dark matter haloes, comparable to those observed along the Spite plateau.

  5. Virus Electrodes for Universal Biodetection Li-Mei C. Yang, Phillip Y. Tam, Benjamin J. Murray, Theresa M. McIntire, Cathie M. Overstreet,

    E-Print Network [OSTI]

    Weiss, Gregory A.

    Virus Electrodes for Universal Biodetection Li-Mei C. Yang, Phillip Y. Tam, Benjamin J. Murray of Chemistry, University of California, Irvine, California 92697-2025 A dense virus layer, readily tailored-assembled mono- layer. The resistance of this "virus electrode", ZRe, mea- sured in the frequency range from 2

  6. O:\\Seminar (SEM)\\2015\\IE Seminars\\sem1615_Husheng Li_JWH_180615.docx THE CHINESE UNIVERSITY OF HONG KONG

    E-Print Network [OSTI]

    Huang, Jianwei

    focused on statistical signal processing, wireless communications, networking, smart grid and game theory and Communications in Cyber Physical Systems: An Entropy Framework by Professor Husheng Li University of Tennessee uncertainty) via communications in CPSs. We consider the controller as the Maxwell's demon that decimates

  7. Bin Li, John O'Loughlin and Lee Gillam (PI) Department of Computing, FEPS, University of Surrey

    E-Print Network [OSTI]

    Gillam, Lee

    Application-Specific Service Level Agreements: Experiments in Clouds and Grids, In Antonopoulos and Gillam Journal of Grid and Utility Computing (IJGUC) ISSN (Online): 1741-8488 - ISSN (Print): 1741-847X. (In, Oxford, UK. [1] Li, B. and Gillam, L. (2009), Grid Service Level Agreements using Financial Risk Analysis

  8. 11Li

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  9. Nanoscale In Situ Characterization of Li-ion Battery Electrochemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hersam, Northwestern University and CEES EFRC To enhance the performance and lifetime of lithium-ion (Li-ion) batteries, researchers require an improved understanding of the...

  10. Saroj Saimek Perry Y. Li

    E-Print Network [OSTI]

    Li, Perry Y.

    Saroj Saimek Perry Y. Li Department of Mechanical Engineering, University of Minnesota, 111 Church) that uses an oscillating foil as a propulsor. The challenge of this problem lies in the need to consider of this paper was presented at the 2001 American Control Conference. Current address: Department of Mechanical

  11. Computations Modulo Regular Chains Xin Li, Marc Moreno Maza and Wei Pan

    E-Print Network [OSTI]

    Moreno Maza, Marc

    Computations Modulo Regular Chains Xin Li, Marc Moreno Maza and Wei Pan (University of Western Ontario) ISSAC 2009, Seoul July 30, 2009 Xin Li, Marc Moreno Maza and Wei Pan (University of Western) = (2 x - 1) y - 7 - x. Xin Li, Marc Moreno Maza and Wei Pan (University of Western Ontario

  12. C: LI

    Office of Legacy Management (LM)

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  13. LI I

    Office of Legacy Management (LM)

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  14. 4Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  15. 5Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  16. 9Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  17. 10Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  18. IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 45, NO. 4, APRIL 2007 1039 The Effects of Scattering Angle and Cumulus Cloud

    E-Print Network [OSTI]

    Zeng, Ning

    Vant-Hull, Alexander Marshak, Lorraine A. Remer, and Zhanqing Li Abstract--The effect of scattering-42-57, and in part by the National Science Foundation under Grant ATM0425069. B. Vant-Hull is with the Department

  19. Magnetic propulsion of liquid Li in tokamaks 1

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    Magnetic propulsion of liquid Li in tokamaks 1 Leonid E. Zakharov, Princeton University, Princeton of liquid lithium, with the tokamak magnetic field is discussed as a mechanism a) for creating fast moving (plasma facing) Li streams along the inner wall of tokamak and b) for mixing the liquid in a closed volume

  20. Lithium Lorentz Force Accelerator Thruster (LiLFA)

    E-Print Network [OSTI]

    Petta, Jason

    Lithium Lorentz Force Accelerator Thruster (LiLFA) Adam Coulon Princeton University Electric #12;LiLFA Thruster · Lithium vapor ionizes in the electric field · A current evolves in the plasma and Control System Position Sensing Detector #12;Lithium Reservoir Argon Flow Copper Water Flow Piston/Lithium

  1. Linkping University Electronic Press

    E-Print Network [OSTI]

    Zhao, Yuxiao

    Linköping University Electronic Press Strategic Plan 2009-2011 December, 2008 1 #12;1. Background As of January 1st , 2008, Linköping University Electronic Press (LiU E-Press) became a unit withinU E-Press. For these reasons, the Strategic Plan for LiU E-Press (2007- 2009) is being updated

  2. ELECTROCHEMICAL ENERGY STORAGE DEVICES Arlin Alvarado Hernandez, Guanglian Li, Sylvia Nguyen, Fouche Smith,

    E-Print Network [OSTI]

    ELECTROCHEMICAL ENERGY STORAGE DEVICES By Arlin Alvarado Hernandez, Guanglian Li, Sylvia Nguyen 55455-0436 Phone: 612-624-6066 Fax: 612-626-7370 URL: http://www.ima.umn.edu #12;Electrochemical Energy Storage Devices Arlin Alvarado Hernandez University of Puerto Rico Guanglian Li Texas A & M University

  3. *The contact author is Prof. Yibo Xue (yiboxue@tsinghua.edu.cn). Mr. Chenglong Li is a Ph.Dstudent at Tsinghua University.

    E-Print Network [OSTI]

    Dong, Yingfei

    , Tor 1. INTRODUCTION Tor is the realization of the second generation onion routing for low.Dstudent at Tsinghua University. "Super Nodes" in Tor: Existence and Security Implication ABSTRACT Tor (the second generation onion routing) is arguably the most popular low-latency anonymous communication system now

  4. PHASE I ENERGY RECOVERY LINAC AT CORNELL UNIVERSITY* I. Bazarov, S. Belomestnykh, D. Bilderback, S. Gray, S. Gruner, Y. Li, M. Liepe, H. Padamsee, V.

    E-Print Network [OSTI]

    Gruner, Sol M.

    components, heat losses in the cryogenic system, and energy recovery efficiency. Study of halo formationPHASE I ENERGY RECOVERY LINAC AT CORNELL UNIVERSITY* I. Bazarov, S. Belomestnykh, D. Bilderback, S on the energy recovery linac (ERL) concept [1, 2]. Such a source will exceed the brightness of third generation

  5. Li4SiO4-Li3PO4 solid solutions as ceramic electrolytes in Li metal cells

    E-Print Network [OSTI]

    Zhang, Liying

    2012-01-01

    3 PO 4 solid solutions as ceramic electrolytes in Li metalpotential application as a ceramic protective layer in Li

  6. Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries

    E-Print Network [OSTI]

    Jaiswal, A.

    2010-01-01

    a LiFePO 4 /Li 4 Ti 5 O 12 full-cell at several different4 /Li 4 Ti 5 O 12 coin full-cell. Figure 1. 0.2 µ m (a) (b)in LiFePO 4 /Li 4 Ti 5 O 12 full cells. Nano-LiFePO 4 showed

  7. 10Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  8. 11Li.eps

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  9. Linkping University Electronic Press

    E-Print Network [OSTI]

    Zhao, Yuxiao

    Linköping University Electronic Press Strategic Plan 2007-2009 January, 2007 #12;Executive SummaryU E-Press for 2007 to 2009. LiU E-Press currently has a collection of about 350 Ph.D. theses, 120 activities for LiU E-Press between 2007 and 2009: 2007 · Re-design of E-Press' website; · Application

  10. Aircraft measurements of SO2 and aerosols over northeastern China: Vertical pro les and the in uence of weather on air quality

    E-Print Network [OSTI]

    Dickerson, Russell R.

    (e.g., Li et al., 2010a), and should be accounted for in remote sensing of air pollution from space and the in uence of weather on air quality Can Li a , Jeffrey W. Stehr a , Lackson T. Marufu a , Zhanqing Li a t s air quality caused by shift in weather pattern.

  11. An Algorithm for Locating Microseismic Events Brian L.F. Daku, J. Eric Salt, Li Sha

    E-Print Network [OSTI]

    Saskatchewan, University of

    An Algorithm for Locating Microseismic Events Brian L.F. Daku, J. Eric Salt, Li Sha University is potash mines. Potash mines produce potash salts, and potas- sium, extracted from potash salts, is a major

  12. Li4SiO4-Li3PO4 system as protective layer in Li-metal batteries

    E-Print Network [OSTI]

    Zhang, Liying

    2012-01-01

    protective layer in Li-metal batteries Liying Zhang 1 , LeiThe application of Li-metal batteries is plagued with issues

  13. Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries

    E-Print Network [OSTI]

    Jaiswal, A.

    2010-01-01

    12 for High Rate Li-ion Batteries A. Jaiswal 1 , C. R. Hornenext generation of Li-ion batteries for consumer electronics

  14. Music Data Mining: An Introduction Tao Li and Lei Li

    E-Print Network [OSTI]

    Li, Tao

    Music Data Mining: An Introduction Tao Li and Lei Li October 17, 2010 #12;2 #12;Contents 1 Introduction 5 1.1 Music Data Sources . . . . . . . . . . . . . . . . . . . . . . . . . 5 1.2 An Introduction and Algorithms . . . . . . . . . . . . . 11 1.3 Music Data Mining

  15. MATH 576: Quantitative Risk Management (3 credits) Instructor: Haijun Li

    E-Print Network [OSTI]

    Li, Haijun

    MATH 576: Quantitative Risk Management (3 credits) Instructor: Haijun Li Office Locations: Neill: Quantitative Risk Management, Ch 1~7, Princeton University Press, New Jersey Course Purpose This course/computational methods in quantitative risk management. Concepts and methods covered in this course can be applied

  16. Basic Notation and Background Chi-Kwong Li

    E-Print Network [OSTI]

    Li, Chi-Kwong

    and Mary, Williamsburg, Virginia, USA; Department of Mathematics, Taiyuan University of Technology, Taiyuan Let Mn be the set (vector space/algebra) of n � n matrices. (a) One can perform A + B, AB and µA for A, B Mn and µ C. (b) One can compute the eigenvalues and eigenvectors of A Mn. Chi-Kwong Li Basic

  17. C LI CI

    Office of Legacy Management (LM)

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  18. 5Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  19. 5Li.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  20. 7Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  1. 7Li.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-InspiredAtmosphericdevicesPPONeApril351APPLICATION OFsafer The mp4 23Heα, X)Li

  2. Peijun Li's Home Page

    E-Print Network [OSTI]

    Transportation · Accomodation · Campus Map · Visitor Parking ... Mathematics of Finite Elements and Applications, Brunel University, London, UK, June 2016.

  3. Courses: Hutchins School of Liberal Studies (LIBS) Page 331Sonoma State University 2015-2016 Catalog LiBS 204 MinoritieS in AMeriCAn CineMA (4)

    E-Print Network [OSTI]

    Ravikumar, B.

    -2016 Catalog LiBS 204 MinoritieS in AMeriCAn CineMA (4) This course is designed to examine the fundamental will be the representations of racial minorities in American cinema from the beginning of the 20th century up to the present cinemas. We will supplement our inquiry through related works of literature and drama, in addition

  4. Lithium Salts for Advanced Lithium Batteries: Li-metal, Li-O2, and Li-S

    SciTech Connect (OSTI)

    Younesi, Reza; Veith, Gabriel M; Johansson, Patrik; Edstrom, Kristina; Vegge, Tejs

    2015-01-01

    Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions and conditions within such cells. This review explores the critical role Li-salts play in ensuring in these batteries viability.

  5. Optical-Model Parameters for the C-12(li-7,li-7)c-12 Reaction at 63 and 78.7 Mev 

    E-Print Network [OSTI]

    Zeller, A. F.; Lui, YW; Tribble, Robert E.; Tanner, D. M.

    1980-01-01

    VOLUME 22, NUMBER 4 OCTOBER 1980 Optical model parameters for the "C('Li,'Li)"C reaction at 63 and 78.7 MeV A. F. Zeller, *Y. -W. Lui, R. E. Tribble, and D. M. Tanner Cyclot'ron Institute, Texas Ac%M University, College Station, Texas 77843 (Received... extracted from I i inelastic scattering. 1538 ZELLER, LUI, TRIBBLE, AND TANNER 22 IV. CONCLUSION The present analysis of the 'Li scattering on "C shows that a single potential set does not ap- pear to describe the data in the energy range from 48 to 78...

  6. Li ion migration in Li3PO4 electrolytes: Effects of O vacancies and N substitutions

    E-Print Network [OSTI]

    Holzwarth, Natalie

    Li ion migration in Li3PO4 electrolytes: Effects of O vacancies and N substitutions Y. A. Dua and N an understanding of detailed mechanisms of Li ion migration in these materials. In previous work, (7) we used first-principles calculations to model Li ion migration in crystalline Li3PO4, finding very good agreement with the experimental

  7. University of Alberta REAL-TIME PROCESSING FOR

    E-Print Network [OSTI]

    Joseph, Dileepan

    University of Alberta REAL-TIME PROCESSING FOR LOGARITHMIC CMOS IMAGE SENSORS by Jing Li A thesis Engineering c Jing Li Spring 2012 Edmonton, Alberta Permission is hereby granted to the University of Alberta form, the University of Alberta will advise potential users of the thesis of these terms. The author

  8. Anion Coordination Interactions in Solvates with the Lithium Salts LiDCTA and LiTDI

    SciTech Connect (OSTI)

    McOwen, Dennis W.; Delp, Samuel A.; Paillard, Elie; Herriot, Cristelle; Han, Sang D.; Boyle, Paul D.; Sommer, Roger D.; Henderson, Wesley A.

    2014-04-17

    Lithium 4,5-dicyano-1,2,3-triazolate (LiDCTA) and lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI) are two salts proposed for lithium battery electrolyte applications, but little is known about the manner in which the DCTA- and TDI- anions coordinate Li+ cations. To explore this in-depth, crystal structures are reported here for two solvates with LiDCTA: (G2)1:LiDCTA and (G1)1:LiDCTA with diglyme and monoglyme, respectively, and seven solvates with LiTDI: (G1)2:LiTDI, (G2)2:LiTDI, (G3)1:LiTDI, (THF)1:LiTDI, (EC)1:LiTDI, (PC)1:LiTDI and (DMC)1/2:LiTDI with monoglyme, diglyme, triglyme, tetrahydrofuran, ethylene carbonate, propylene carbonate and dimethyl carbonate, respectively. These latter solvate structures are compared with the previously reported acetonitrile (AN)2:LiTDI structure. The solvates indicate that the LiTDI salt is much less associated than the LiDCTA salt and that the ions in LiTDI, when aggregated in solvates, have a very similar TDI-...Li+ cation mode of coordination through both the anion ring and cyano nitrogen atoms. Such coordination facilitates the formation of polymeric ion aggregates, instead of dimers. Insight into such ion speciation is instrumental for understanding the electrolyte properties of aprotic solvent mixtures with these salts.

  9. Li Ion Diffusion Mechanisms in the Crystalline Electrolyte Yaojun A. Du and N. A. W. Holzwarth*,z

    E-Print Network [OSTI]

    Holzwarth, Natalie

    electronically September 6, 2007. Recently, there has been a lot of interest in solid electrolyte ma- terialsLi Ion Diffusion Mechanisms in the Crystalline Electrolyte -Li3PO4 Yaojun A. Du and N. A. W. Holzwarth*,z Department of Physics, Wake-Forest University, Winston-Salem, North Carolina 27109, USA Solid

  10. New Impossible Di#erential Cryptanalysis of Ruilin Li, Bing Sun, Peng Zhang and Chao Li

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    New Impossible Di#erential Cryptanalysis of ARIA Ruilin Li, Bing Sun, Peng Zhang and Chao Li until only one key left using some impossible di#erential path. Since its #12; 2 Ruilin Li, Bing Sun

  11. New Impossible Differential Cryptanalysis of Ruilin Li, Bing Sun, Peng Zhang and Chao Li

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    New Impossible Differential Cryptanalysis of ARIA Ruilin Li, Bing Sun, Peng Zhang and Chao Li, Bing Sun, Peng Zhang and Chao Li emergence, impossible differential cryptanalysis has been applied

  12. P-232L / X. Li P-232L: Late-News Poster: New Results on Bistable Photoaligned

    E-Print Network [OSTI]

    Water Bay, Kowloon, Hong Kong Abstract The principles for intrinsic greyscale generation: Grey Scale Generation, Stabilization and Passive Driving Scheme Xihua Li, Anatoli Muravsky, Alexander, Department of Electrical and Electronic Engineering Hong Kong University of Science and Technology Clear

  13. Li4SiO4-Li3PO4 solid solutions as ceramic electrolytes in Li metal cells

    E-Print Network [OSTI]

    Zhang, Liying

    2012-01-01

    between lithium and solid electrolyte. After heating, theP-O and Li-Si-P-B-O solid electrolytes were found to have a3 PO 4 solid solutions as ceramic electrolytes in Li metal

  14. PHILADELPHIA UNIVERSITY PHILADELPHIA UNIVERSITY

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY . . . #12;PHILADELPHIA UNIVERSITY . . : : (132) . : . . . : . #12;PHILADELPHIA UNIVERSITY

  15. SmartTunnel: Achieving Reliability in the Internet Yi Li, Yin Zhang, LiLi Qiu, Simon Lam

    E-Print Network [OSTI]

    Qiu, Lili

    1 SmartTunnel: Achieving Reliability in the Internet Yi Li, Yin Zhang, LiLi Qiu, Simon Lam's Internet. In this paper, we propose SmartTunnel, an end-to-end approach to achieving reliability. A SmartTunnel is a logical point-to-point tunnel between two end points that spans multiple physical network paths

  16. Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries Hyunjung Lee an increase in the cut-off voltage of the cell from 4.2 V to 4.4 V (vs. graphite). As an alterna- tive, we can

  17. First principles simulations of Li ion migration in materials related to LiPON electrolytes

    E-Print Network [OSTI]

    Holzwarth, Natalie

    energies for Li ion migration. In the course of this work, we discovered new stable crystalline forms of Li. For crystalline materials the activa- tion energy EA is related to the migration energy Em and the "formationFirst principles simulations of Li ion migration in materials related to LiPON electrolytes Y. A

  18. Al+LiF Coated Focal Plane

    E-Print Network [OSTI]

    Al+LiF Coated Mirror #2 Focal Plane Assemblies (4) Detectors (2) Al+LiF Coated Mirror #1 SiC Coated Mirror #2 SiC Coated Mirror #1 Rowland Circles Al+LiF Coated Grating #2 Al+LiF Coated Grating #1 SiC Coated Grating #2 z y x Figure 1 A schematic view of the FUSE optical system. 1. INTRODUCTION The Far

  19. Li-Z

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and-E C H N13, 2009 In

  20. biogas to indian buses come home, dad biosensor lab in singapore sexy statistics world university No reason to rush homeLiU alumna Klara Tiitso enjoys her life in London | page 30

    E-Print Network [OSTI]

    Zhao, Yuxiao

    biogas to indian buses come home, dad biosensor lab in singapore sexy statistics world university an Indian Master's student whose studies at Linköping inspired him to use biogas as fuel for busses. He

  1. IMPACT OF AEROSOLS ON CONVECTIVE CLOUDS AND PRECIPITATION

    E-Print Network [OSTI]

    Zeng, Ning

    IMPACT OF AEROSOLS ON CONVECTIVE CLOUDS AND PRECIPITATION Wei-Kuo Tao,1 Jen-Ping Chen,2 Zhanqing Li effects on clouds could further extend to precipitation, both through the formation of cloud particles mechan- isms behind these effects, in particular, the ones connected to precipitation, are not yet well

  2. Simulated electrolyte-metal interfaces ---Li3PO4 and Li Xiao Xu , Yaojun Du and N.A.W. Holzwarth

    E-Print Network [OSTI]

    Holzwarth, Natalie

    or LiClO4 Solid : LiPON , -Li3PO4 Electrolyte materials Store Li+ ions and electrons in discharge modeSimulated electrolyte-metal interfaces -- -Li3PO4 and Li Xiao Xu , Yaojun Du and N.A.W. Holzwarth + 0427055 #12;Discharge operation of Li ion battery Cathode Electrolyte Anode Li+ e- #12;provide source

  3. Efimov physics in {sup 6}Li atoms

    SciTech Connect (OSTI)

    Braaten, Eric; Hammer, H.-W.; Kang, Daekyoung; Platter, Lucas

    2010-01-15

    A new narrow three-atom loss resonance associated with an Efimov trimer crossing the three-atom threshold has recently been discovered in a many-body system of ultracold {sup 6}Li atoms in the three lowest hyperfine spin states at a magnetic field near 895 G. O'Hara and coworkers have used measurements of the three-body recombination rate in this region to determine the complex three-body parameter associated with Efimov physics. Using this parameter as the input, we calculate the universal predictions for the spectrum of Efimov states and for the three-body recombination rate in the universal region above 600 G where all three scattering lengths are large. We predict an atom-dimer loss resonance at 672+-2 G associated with an Efimov trimer disappearing through an atom-dimer threshold. We also predict an interference minimum in the three-body recombination rate at 759+-1 G where the three-spin mixture may be sufficiently stable to allow experimental study of the many-body system.

  4. Efimov Physics in 6Li Atoms

    E-Print Network [OSTI]

    Eric Braaten; H. -W. Hammer; Daekyoung Kang; Lucas Platter

    2010-07-26

    A new narrow 3-atom loss resonance associated with an Efimov trimer crossing the 3-atom threshold has recently been discovered in a many-body system of ultracold 6Li atoms in the three lowest hyperfine spin states at a magnetic field near 895 G. O'Hara and coworkers have used measurements of the 3-body recombination rate in this region to determine the complex 3-body parameter associated with Efimov physics. Using this parameter as the input, we calculate the universal predictions for the spectrum of Efimov states and for the 3-body recombination rate in the universal region above 600 G where all three scattering lengths are large. We predict an atom-dimer loss resonance at (672 +/- 2) G associated with an Efimov trimer disappearing through an atom-dimer threshold. We also predict an interference minimum in the 3-body recombination rate at (759 +/- 1) G where the 3-spin mixture may be sufficiently stable to allow experimental study of the many-body system.

  5. Vacancy-Driven Anisotropic Defect Distribution in the Battery-Cathode Material LiFePO4 Jaekwang Lee,1,2

    E-Print Network [OSTI]

    Pennycook, Steve

    , and environmental friendliness [1­3]. The Li-ion mobility is the key param- eter for battery applications with highVacancy-Driven Anisotropic Defect Distribution in the Battery-Cathode Material LiFePO4 Jaekwang Lee of Physics Astronomy, Vanderbilt University, Nashville, Tennessee 37235, USA 2 Materials Science Technology

  6. Linkping University Electronic Press

    E-Print Network [OSTI]

    Zhao, Yuxiao

    Linköping University Electronic Press Activity Summary, 2007 January, 2008 1 #12;1. Organization In March of 2007, Erik Sandewall, E-Press' director, resigned in order to take up a position at the Royal solution was found as part of a larger restructuring of LiU E-Press. As of September 1st , the Board

  7. Rechargeable Li/CO2O2 (2 : 1) battery and Li/CO2 Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen

    E-Print Network [OSTI]

    Wang, Wei Hua

    under suitable conditions. Therefore, it is plausible that a recharge- able Li/CO2 battery couldRechargeable Li/CO2­O2 (2 : 1) battery and Li/CO2 battery Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen A Li/CO2­O2 (2 : 1, volume ratio) battery and a Li/CO2 battery with discharging specific

  8. THE {sup 7}Li/{sup 6}Li ISOTOPE RATIO NEAR THE SUPERNOVA REMNANT IC 443

    SciTech Connect (OSTI)

    Taylor, C. J.; Ritchey, A. M.; Federman, S. R. [Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606 (United States); Lambert, D. L., E-mail: corbin.taylor@rockets.utoledo.edu, E-mail: steven.federman@utoledo.edu, E-mail: aritchey@astro.washington.edu, E-mail: dll@astro.as.utexas.edu [W. J. McDonald Observatory, University of Texas at Austin, Austin, TX 78712 (United States)

    2012-05-01

    We present an analysis of {sup 7}Li/{sup 6}Li isotope ratios along four sight lines that probe diffuse molecular gas near the supernova remnant IC 443. Recent gamma-ray observations have revealed the presence of shock-accelerated cosmic rays interacting with the molecular cloud surrounding the remnant. Our results indicate that the {sup 7}Li/{sup 6}Li ratio is lower in regions more strongly affected by these interactions, a sign of recent Li production by cosmic rays. We find that {sup 7}Li/{sup 6}Li Almost-Equal-To 7 toward HD 254755, which is located just outside the visible edge of IC 443, while {sup 7}Li/{sup 6}Li Almost-Equal-To 3 along the line of sight to HD 43582, which probes the interior region of the supernova remnant. No evidence of {sup 7}Li synthesis by neutrino-induced spallation is found in material presumably contaminated by the ejecta of a core-collapse supernova. The lack of a neutrino signature in the {sup 7}Li/{sup 6}Li ratios near IC 443 is consistent with recent models of Galactic chemical evolution, which suggest that the {nu}-process plays only a minor role in Li production.

  9. Li-rich anti-perovskite Li3OCl films with enhanced ionic conductivity

    SciTech Connect (OSTI)

    Lu, XJ; Wu, G; Howard, JW; Chen, AP; Zhao, YS; Daemen, LL; Jia, QX

    2014-08-13

    Anti-perovskite solid electrolyte films were prepared by pulsed laser deposition, and their room-temperature ionic conductivity can be improved by more than an order of magnitude in comparison with its bulk counterpart. The cyclability of Li3OCl films in contact with lithium was evaluated using a Li/Li3OCl/Li symmetric cell, showing self-stabilization during cycling test.

  10. A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries

    E-Print Network [OSTI]

    1 A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries: Power of a commercial LiFePO4-graphite Li-ion battery. Compared to the isothermal reference, the mechanism of porosity;2 Due to their high power and energy densities, Li-ion technologies are the leading battery systems

  11. Modeling the interface of Li metal and Li solid electrolytes from first principles Nicholas Lepley, N. A. W. Holzwarth

    E-Print Network [OSTI]

    Holzwarth, Natalie

    Modeling the interface of Li metal and Li solid electrolytes from first principles Nicholas Lepley an electrochemical cell of Li/Li3PS4/Li with excellent cycle life . Overview Solid electrolyte materials reactive electrode/electrolyte interfaces, and with the discovery of several new high conductivity solids

  12. Li3PX4: Bulk and Surface

    E-Print Network [OSTI]

    Holzwarth, Natalie

    show considerable promise for advancing battery technology · Improved safety characteristics · Allow properties are: · Stability · Inteface stability · Ionic Conductivity Tesla Model S #12;Li3PX4: Bulk

  13. Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries

    SciTech Connect (OSTI)

    Jaiswal, A.; Horne, C.R.; Chang, O.; Zhang, W.; Kong, W.; Wang, E.; Chern, T.; Doeff, M. M.

    2009-08-04

    The electrochemical performances of nanoscale LiFePO4 and Li4Ti5O12 materials are described in this communication. The nanomaterials were synthesized by pyrolysis of an aerosol precursor. Both compositions required moderate heat-treatment to become electrochemically active. LiFePO4 nanoparticles were coated with a uniform, 2-4 nm thick carbon-coating using an organic precursor in the heat treatment step and showed high tap density of 1.24 g/cm3, in spite of 50-100 nm particle size and 2.9 wtpercent carbon content. Li4Ti5O12 nanoparticles were between 50-200 nm in size and showed tap density of 0.8 g/cm3. The nanomaterials were tested both in half cell configurations against Li-metal and also in LiFePO4/Li4Ti5O12 full cells. Nano-LiFePO4 showed high discharge rate capability with values of 150 and 138 mAh/g at C/25 and 5C, respectively, after constant C/25 charges. Nano-Li4Ti5O12 also showed high charge capability with values of 148 and 138 mAh/g at C/25 and 5C, respectively, after constant C/25 discharges; the discharge (lithiation) capability was comparatively slower. LiFePO4/Li4Ti5O12 full cells deliver charge/discharge capacity values of 150 and 122 mAh/g at C/5 and 5C, respectively.

  14. Verification of Automotive Control Applications using S-TaLiRo Georgios E. Fainekos, Sriram Sankaranarayanan, Koichi Ueda and Hakan Yazarel

    E-Print Network [OSTI]

    Fainekos, Georgios E.

    Verification of Automotive Control Applications using S-TaLiRo Georgios E. Fainekos, Sriram is with the Department of Computer Science, University of Colorado, Boulder. E-mail: srirams@colorado.edu K. Ueda and H

  15. An Analysis of Facebook Photo Caching Qi Huang, Ken Birman, Robbert van Renesse, Wyatt Lloyd, Sanjeev Kumar, Harry C. Li

    E-Print Network [OSTI]

    Keinan, Alon

    An Analysis of Facebook Photo Caching Qi Huang, Ken Birman, Robbert van Renesse, Wyatt Lloyd, Sanjeev Kumar, Harry C. Li Cornell University, Princeton University, Facebook Inc. Abstract This paper examines the workload of Facebook's photo- serving stack and the effectiveness of the many layers

  16. Earth Observations for rapid response to large earthquakes Supervisors: Dr Zhenhong Li and Prof Trevor Hoey

    E-Print Network [OSTI]

    Guo, Zaoyang

    Earth Observations for rapid response to large earthquakes Supervisors: Dr Zhenhong Li and Prof Trevor Hoey School of Geographical and Earth Sciences, University of Glasgow, UK Earthquakes, together of the earth system; they are messengers of the fundamental processes that shape the surface of the Earth

  17. LiNbO3 thin film growth on (0001)-GaN Peter J. Hansen

    E-Print Network [OSTI]

    York, Robert A.

    generation (SHG) or surface acoustic wave (SAW) filters. The utilization of the polar nature of LiNbO3 has, 1-11-2 Osaki, Shinagawa-ku, Tokyo 141-0032, Japan Yuan Wu Materials Department, University for application in future generation microwave power devices4­6 The extremely high charge density at the Al

  18. Computer Vision Technology for Applications to Assist Blind Dr. Ying-Li Tian, Associate Professor

    E-Print Network [OSTI]

    Zhu, Zhigang

    Professor Dept of Electrical Engineering The City College, City University of New York Time: 2:00 pm, March-Li Tian is an associate professor in the Department of Electrical Engineering at the City College of New of the inventors of the IBM Smart Surveillance Solutions (SSS) product and was leading the video analytics team

  19. Securing Wireless Systems via Lower Layer Enforcements Zang Li, Wenyuan Xu, Rob Miller, Wade Trappe

    E-Print Network [OSTI]

    Xu, Wenyuan

    Securing Wireless Systems via Lower Layer Enforcements Zang Li, Wenyuan Xu, Rob Miller, Wade Trappe Wireless Information Network Laboratory (WINLAB) Rutgers, The State University of New Jersey 73 Brett Rd security mechanisms are essential to the overall problem of securing wireless net- works, these techniques

  20. Optimal Provisioning of Elastic Service Availability Dahai Xu Ying Li Mung Chiang A. Robert Calderbank

    E-Print Network [OSTI]

    Papadopouli, Maria

    Optimal Provisioning of Elastic Service Availability Dahai Xu Ying Li Mung Chiang A. Robert University, NJ 08544, USA Abstract-- Service availability is one of the most closely scruti- nized metrics higher service availability at the cost of higher operational expense. It is important to cost

  1. LiT Electrolysis Research at Savannah River National Laboratory...

    Office of Environmental Management (EM)

    LiT Electrolysis Research at Savannah River National Laboratory (SRNL) LiT Electrolysis Research at Savannah River National Laboratory (SRNL) Presentation from the 35th Tritium...

  2. Enabling Future Li-Ion Battery Recycling | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Future Li-Ion Battery Recycling Title Enabling Future Li-Ion Battery Recycling Publication Type Presentation Year of Publication 2014 Authors Gaines, LL Abstract Presentation made...

  3. Characterization of Li-ion Batteries using Neutron Diffraction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques Characterization of Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques 2011 DOE...

  4. Electrochemistry of LiCl-Li2O-H2O Molten Salt Systems

    SciTech Connect (OSTI)

    Natalie J. Gese; Batric Pesic

    2013-03-01

    Uranium can be recovered from uranium oxide (UO2) spent fuel through the combination of the oxide reduction and electrorefining processes. During oxide reduction, the spent fuel is introduced to molten LiCl-Li2O salt at 650 degrees C and the UO2 is reduced to uranium metal via two routes: (1) electrochemically, and (2) chemically by lithium metal (Li0) that is produced electrochemically. However, the hygroscopic nature of both LiCl and Li2O leads to the formation of LiOH, contributing hydroxyl anions (OH-), the reduction of which interferes with the Li0 generation required for the chemical reduction of UO2. In order for the oxide reduction process to be an effective method for the treatment of uranium oxide fuel, the role of moisture in the LiCl-Li2O system must be understood. The behavior of moisture in the LiCl-Li2O molten salt system was studied using cyclic voltammetry, chronopotentiometry and chronoamperometry, while reduction to hydrogen was confirmed with gas chromatography.

  5. Math/Stat 370: Engineering Statistics, Washington State University

    E-Print Network [OSTI]

    Li, Haijun

    8 10 x u = 5, v = 15 f(x) u = 5, v = 5 f1 ­ , ,u v f (x) Haijun Li Math/Stat 370: Engineering f1 ­ , , f, ,u v u v f (x) Haijun Li Math/Stat 370: Engineering Statistics, Washington State f1-,n1-1,n2-1. Haijun Li Math/Stat 370: Engineering Statistics, Washington State University Week 11

  6. Patterning of graphene Wenbin Li,b

    E-Print Network [OSTI]

    Chen, Sow-Hsin

    Patterning of graphene Ji Feng,a Wenbin Li,b Xiaofeng Qian,b Jingshan Qi,c Liang Qib and Ju Li of carbon (graphene, graphane, etc.) are amenable to unique patterning schemes such as cutting, bending theoretical understanding and processing routes for patterning graphene and highlight potential applications

  7. DFT+U Study of Polaronic Conduction in Li2O2 and Li2CO3: Implications for Li-Air Batteries

    E-Print Network [OSTI]

    Thygesen, Kristian

    DFT+U Study of Polaronic Conduction in Li2O2 and Li2CO3: Implications for Li-Air Batteries J. M-air batteries are known to be Li2O2 and residual Li2CO3. Recent experiments indicate that the charge transport through these materials is the main limiting factor for the battery performance. It has been also shown

  8. 4/6/2012 Seminar: University of Louisville 1 Solid electrolytes for battery applications

    E-Print Network [OSTI]

    Holzwarth, Natalie

    4/6/2012 Seminar: University of Louisville 1 Solid electrolytes for battery applications of a Li ion battery #12;4/6/2012 Seminar: University of Louisville 3 Example: Thin-film battery developed liquid electrolytes in Li ion batteries Advantages 1. Excellent chemical and physical stability. 2

  9. Materials for Better Li-based Storage Systems for a "Green Energy Society"

    ScienceCinema (OSTI)

    Jean-Marie Tarascon

    2010-01-08

    Li-ion batteries are strongly considered for powering the upcoming generations of HEVs and PHEVs, but there are still the issues of safety and costs in terms of materials resources and abundances, synthesis, and recycling processes. Notions of materials having minimum footprint in nature, made via eco-efficient processes, must be integrated in our new research towards the next generation of sustainable and "greener" Li-ion batteries. In this July 13, 2009 talk sponsored by Berkeley Lab's Environental Energy Technologies Division, Jean-Marie Tarascon, a professor at the University of Picardie (Amiens), discuss Eco-efficient synthesis via hydrothermal/solvothermal processes using latent bases as well as structure directing templates or other bio-related approaches of LiFePO4 nanopowders.

  10. Asymptotic normalization coefficients for B-8 -> Be-7+p from a study of Li-8 -> Li-7+n 

    E-Print Network [OSTI]

    Trache, L.; Azhari, A.; Carstoiu, F.; Clark, HL; Gagliardi, Carl A.; Lui, YW; Mukhamedzhanov, AM; Tang, X.; Timofeyuk, N.; Tribble, Robert E.

    2003-01-01

    Asymptotic normalization coefficients (ANCs) for Li-8-->Li-7+n have been extracted from the neutron transfer reaction C-13(Li-7,Li-8)C-12 at 63 MeV. These are related to the ANCs in B-8-->Be-7 + p using charge symmetry. ...

  11. Simplified Electrochemical and Thermal Model of LiFePO4-Graphite Li-Ion Batteries for Fast Charge Applications

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Simplified Electrochemical and Thermal Model of LiFePO4- Graphite Li-Ion Batteries for Fast Charge, a simplified electrochemical and thermal model of LiFePO4-graphite based Li-ion batteries is developed for battery management system (BMS) applications and comprehensive aging investigations. Based on a modified

  12. Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries Hyun diameters less than 10 nm and lengths of several micrometers. Galvanostatic battery testing showed that Li, lithium ion battery, LiMn2O4 nanowires, high power density, Jahn-Teller distortion T he high energy

  13. Population III Generated Cosmic Rays and the Production of Li6

    E-Print Network [OSTI]

    Emmanuel Rollinde; Elisabeth Vangioni; Keith A. Olive

    2006-05-24

    We calculate the evolution of Li6 generated from cosmic rays produced by an early population of massive stars. The computation is performed in the framework of hierarchical structure formation and is based on cosmic star formation histories constrained to reproduce the observed star formation rate at redshift z \\la 6, the observed chemical abundances in damped Lyman alpha absorbers and in the intergalactic medium, and to allow for an early reionization of the Universe at z\\sim 11 by Pop III stars as indicated by the third year results released by WMAP. We show that the pregalactic production of the Li6 isotope in the IGM via these Pop III stars can account for the Li6 plateau observed in metal poor halo stars without additional over-production of Li7. Our results depend on the efficiency of cosmic rays to propagate out of minihalos and the fraction of supernovae energy deposited in cosmic rays. We also compute the cosmic ray heating of the IGM gas. In general, we find somewhat high temperatures (of order 10^5 K) implying that the cosmic rays production of Li6 may be required to be confined to the so-called warm-hot IGM.

  14. Chair: Victor Li Professor, Civil & Environmental Engineering

    E-Print Network [OSTI]

    Kamat, Vineet R.

    environmental impact, which limit the resilience and sustainability of the concrete infrastructure (buildings CEMENTITIOUS COMPOSITE DEVELOPMENT FOR RESILIENT AND SUSTAINABLE INFRASTRUCTURE" Ravi Ranade Date: January 17Chair: Victor Li Professor, Civil & Environmental Engineering Doctoral Defense "ADVANCED

  15. BBN Concordance: What's the Matter with Li?

    E-Print Network [OSTI]

    Yamamoto, Hirosuke

    ,7 Li - BeB #12;WMAP best fit Bh2 = 0.0227 ± 0.0006 10 = 6.22 ± 0.16 #12;#12;additional factors are used

  16. Page 1 of 2 UNIVERSAL WASTE

    E-Print Network [OSTI]

    Jia, Songtao

    -Cadmium (Ni-Cd) Nickel Metal Hydride (Ni-MH) Lithium Ion (Li-ion) Large or Small sealed lead acid (Pb) MercuryPage 1 of 2 UNIVERSAL WASTE and OTHER ENVIRONMENTALLY DELETERIOUS PRODUCTS Batteries All Universal Waste Batteries generated in laboratories must be collected through the hazardous waste program

  17. A Survey of Fog Computing: Concepts, Applications and Shanhe Yi, Cheng Li, Qun Li

    E-Print Network [OSTI]

    Li, Qun

    A Survey of Fog Computing: Concepts, Applications and Issues Shanhe Yi, Cheng Li, Qun Li Department-awareness. Fog computing, also termed edge computing, can address those problems by providing elastic resources distributed in the core network. This survey dis- cusses the definition of fog computing and similar concepts

  18. First principles simulations of Li ion migration in materials related to LiPON electrolytes a

    E-Print Network [OSTI]

    Holzwarth, Natalie

    of known materials reported in the literature together with new stable and meta-stable predictedFirst principles simulations of Li ion migration in materials related to LiPON electrolytes materials in the LixPOyNz family (x = 2y + 3z - 5). In order to systematize the current state

  19. Cost-Sensitive Classification with Genetic Programming Jin Li, Xiaoli Li and Xin Yao

    E-Print Network [OSTI]

    Yao, Xin

    Cost-Sensitive Classification with Genetic Programming Jin Li, Xiaoli Li and Xin Yao The Centre.Yao}@cs.bham.ac.uk Abstract- Cost-sensitive classification is an attractive topic in data mining. Although genetic programming exploited to ad- dress cost-sensitive classification in the literature, where the costs of misclassification

  20. Proportional Fairness in Multi-rate Wireless LANs Li (Erran) Li

    E-Print Network [OSTI]

    Li, Li Erran

    Proportional Fairness in Multi-rate Wireless LANs Li (Erran) Li Martin Pal ¡ Yang Richard Yang throughput while serving users in a fair manner, proportional fair or time-based fair scheduling has been consist of a network of APs, this paper considers proportional fairness in this much wider setting. Our

  1. Excitation functions of {sup 6,7}Li+{sup 7}Li reactions at low energies

    SciTech Connect (OSTI)

    Prepolec, L.; Soic, N.; Blagus, S.; Miljanic, D.; Siketic, Z.; Skukan, N.; Uroic, M.; Milin, M.

    2009-08-26

    Differential cross sections of {sup 6,7}Li+{sup 7}Li nuclear reactions have been measured at forward angles (10 deg. and 20 deg.), using particle identification detector telescopes, over the energy range 2.75-10.00 MeV. Excitation functions have been obtained for low-lying residual-nucleus states. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) at beam energy about 8 MeV, first observed by Wyborny and Carlson in 1971 at 0 deg., has been observed at 10 deg., but is less evident at 20 deg. The cross section obtained for the {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(g.s,0{sup +}) reaction is about ten times smaller. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) reaction could correspond to excited states in {sup 14}C, at excitation energies around 30 MeV.

  2. Rate-dependent morphology of Li2O2 growth in Li-O2 batteries

    E-Print Network [OSTI]

    Horstmann, B; Mitchell, R; Bessler, W G; Shao-Horn, Y; Bazant, M Z

    2013-01-01

    Compact solid discharge products enable energy storage devices with high gravimetric and volumetric energy densities, but solid deposits on active surfaces can disturb charge transport and induce mechanical stress. In this Letter we develop a nanoscale continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes, based on a theory of electrochemical non-equilibrium thermodynamics originally applied to Li-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory predicts a transition from complex to uniform morphologies of Li2O2 with increasing current. Discrete particle growth at low discharge rates becomes suppressed at high rates, resulting in a film of electronically insulating Li2O2 that limits cell performance. We predict that the transition between these surface growth modes occurs at current densities close to the exchange current density of the cathode reaction, consistent with experimental observations.

  3. The X^- Solution to the ^6Li and ^7Li Big Bang Nucleosynthesis Problems

    E-Print Network [OSTI]

    Motohiko Kusakabe; Toshitaka Kajino; Richard N. Boyd; Takashi Yoshida; Grant J. Mathews

    2008-03-24

    The $^6$Li abundance observed in metal poor halo stars appears to exhibit a plateau as a function of metallicity similar to that for $^7$Li, suggesting a big bang origin. However, the inferred primordial abundance of $^6$Li is $\\sim$1000 times larger than that predicted by standard big bang nucleosynthesis for the baryon-to-photon ratio inferred from the WMAP data. Also, the inferred $^7$Li primordial abundance is 3 times smaller than the big bang prediction. We here describe in detail a possible simultaneous solution to both the problems of underproduction of $^6$Li and overproduction of $^7$Li in big bang nucleosynthesis. This solution involves a hypothetical massive, negatively-charged leptonic particle that would bind to the light nuclei produced in big bang nucleosynthesis, but would decay long before it could be detected. We consider only the $X$-nuclear reactions and assume that the effect of decay products is negligible, as would be the case if lifetime were large or the mass difference between the charged particle and its daughter were small. An interesting feature of this paradigm is that, because the particle remains bound to the existing nuclei after the cessation of the usual big bang nuclear reactions, a second longer epoch of nucleosynthesis can occur among $X$-nuclei. We confirm that reactions in which the hypothetical particle is transferred can occur that greatly enhance the production of $^6$Li while depleting $^7$Li. We also identify a new reaction that destroys large amounts of $^7$Be, and hence reduces the ultimate $^7$Li abundance. Thus, big-bang nucleosynthesis in the presence of these hypothetical particles, together with or without an event of stellar processing, can simultaneously solve the two Li abundance problems.

  4. LI,HOSPEDALES,SONG,GONG: FINE-GRAINED SKETCH-BASED IMAGE RETRIEVAL 1 Fine-Grained Sketch-Based Image Retrieval

    E-Print Network [OSTI]

    Gong, Shaogang

    LI,HOSPEDALES,SONG,GONG: FINE-GRAINED SKETCH-BASED IMAGE RETRIEVAL 1 Fine-Grained Sketch.hospedales@qmul.ac.uk Yi-Zhe Song yizhe.song@qmul.ac.uk Shaogang Gong s.gong@qmul.ac.uk Queen Mary University of London. It may be distributed unchanged freely in print or electronic forms. #12;2 LI,HOSPEDALES,SONG,GONG: FINE

  5. Fast Response No-Bias-Bend LCD F. S. Y. Yeung, Y. W. Li and H. S. Kwok

    E-Print Network [OSTI]

    Fast Response No-Bias-Bend LCD F. S. Y. Yeung, Y. W. Li and H. S. Kwok Center for Display Research, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong ABSTRACT Fast for fast switching applications [6-10]. Its response time can be very fast since there is no backflow

  6. Using Normal Flow for Detection and Tracking of Limbs in Color Images Zoran Duric, Fayin Li, Yan Sun, Harry Wechsler

    E-Print Network [OSTI]

    Duric, Zoran

    Using Normal Flow for Detection and Tracking of Limbs in Color Images Zoran Duric, Fayin Li, Yan Sun, Harry Wechsler Department of Computer Science George Mason University Fairfax, VA 22030 {zduric and tracking human motions over various periods of time. In this paper we de- scribe a method of detecting

  7. A Light Weight Rotary Double Pendulum: Maximizing the Domain of Attraction R. W. Brockett* and Hongyi Li*

    E-Print Network [OSTI]

    A Light Weight Rotary Double Pendulum: Maximizing the Domain of Attraction R. W. Brockett* and Hongyi Li* Engineering and Applied Sciences Harvard University Cambridge, MA 02138, USA {brockett, hongyi an experimental effort concerned with the stabilization of a rotary double link pendulum. This problem

  8. Event based Kalman filter observer for rotary high speed on/off valve Meng Wang, Perry Y. Li

    E-Print Network [OSTI]

    Li, Perry Y.

    Event based Kalman filter observer for rotary high speed on/off valve Meng Wang, Perry Y. Li ERC for Compact and Efficient Fluid Power Department of Mechanical Engineering University of Minnesota {wang134, pli}@me.umn.edu Abstract-- A novel hydraulic rotary self-spinning high speed on/off valve is being

  9. First-principles investigation of Li intercalation kinetics in phospho-olivines

    E-Print Network [OSTI]

    Malik, Rahul

    2013-01-01

    This thesis focuses broadly on characterizing and understanding the Li intercalation mechanism in phospho-olivines, namely LiFePO? and Li(Fe,Mn)PO?, using first-principles calculations. Currently Li-ion battery technology ...

  10. Linkping University Electronic Press Publication Conditions at Linkping University Electronic Press

    E-Print Network [OSTI]

    Zhao, Yuxiao

    Linköping University Electronic Press 1 Publication Conditions at Linköping University Electronic Press This document is used as Appendix 1 to publication agreements at the Electronic Press Press (LiU E-Press) has been created to provide an electronic publishing service for Linköping

  11. Modeling - Scale-Bridging Simulations Active Materials in Li...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Scale-Bridging Simulations Active Materials in Li-ion Batteries, and Validation in BATT Electrodes Modeling - Scale-Bridging Simulations Active Materials in Li-ion Batteries, and...

  12. UNIVERSITY AVE UNIVERSITY AVE

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    P UNIVERSITY AVE UNIVERSITY AVE UNIVERSITY AVE UNIVERSITY AVE PATTESON DR VANVOORHISRDVANVOORHISR STKREPPS AVE BROAD ST ELM ST DOGWOOD ST UNIVERSITY AVE MONONGAHELABLVD US HWY 19 41 48 Patient 48 53 78 58 Complex Pierpont Apartments UNIVERSITY PARK Erickson Alumni Center Fieldcrest Hall University Services

  13. A=11Li (1980AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries80AJ01) (See the Isobar Diagram for 11Li) 11Li

  14. A=8Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams8Be (59AJ76) (See8AJ01)8AJ01)8Li 8Li

  15. LiDAR | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History ViewInformationWinds Jump to:LaredoLeelanauLeonicsLewisville,LiLiDAR

  16. Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, Thomas M.

    2008-01-01

    1:1 EC+ DMC with 1M mixture of 98:2 LiTFSI+LiBOB. Figure 10.1:1 EC+DMC with 1M mixture of 98:2 LiTFSI+LiBOB. Figure 1a.+DMC with 1M mixture of 98:2 LiTFSI+LiBOB. Figure10. Optical

  17. Improved Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas Edward

    2012-01-01

    commercial Li-ion batteries today use graphite or a mixturein certain primary batteries). Graphite has a potential of

  18. LiBeB and Big Bang Nucleosynthesis

    E-Print Network [OSTI]

    Keith A. Olive; Brian D. Fields

    1999-02-20

    The dual origin of population II Li7, in both big bang nucleosynthesis and galactic cosmic-ray nucleosynthesis is discussed. It is argued that with additional Li6 data, stringent limits on the degree of Li7 depletion can be obtained. Li7 depletion is also constrained by the concordance of big bang predictions with observational determinations of light element abundances. Stringent limits can also be obtained for a fixed primordial D/H abundance.

  19. Identity of Passive Film Formed on Aluminum in Li-ion Battery Electrolytes with LiPF6

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, T.M.

    2008-01-01

    Influence Formation of AlF 3 Passive Film on Aluminum in Li-Identity of Passive Film Formed on Aluminum in Li-ionEngineering Abstract The passive film that forms on aluminum

  20. Current collectors for rechargeable Li-Air batteries

    SciTech Connect (OSTI)

    Veith, Gabriel M [ORNL; Dudney, Nancy J [ORNL

    2011-01-01

    Here we report the negative influence of porous nickel foam for use as current collectors in rechargeable Li-air batteries. Uncoated nickel foam promotes the decomposition of LiPF6-organic carbonate electrolytes under normal charging conditions reported for rechargeable Li-air cells. We have identified Ni free porous carbon supports as more appropriate cathode current collectors.

  1. The prospects for highbeta tokamaks with Li walls 1

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    . Why Li walls ? 2. Magnetic propulsion of liquid Li. 3. Plasma profiles in the non­recycling regime. 4 can be magnetically propulsed along the plasma facing surfaces in the tokamak chamber. This allows the stabilizing wall right at the plasma boundary. 2. Intense (V ' 20 m=sec) magnetic propulsion allows to keep Li

  2. A periodic orbit analysis of the vibrationally highly excited LiNC/LiCN: A comparison with quantum mechanics

    E-Print Network [OSTI]

    Guantes, Raúl

    mechanical calculations, avail- able mainly for the low energy vibrational levels. Now, the LiA periodic orbit analysis of the vibrationally highly excited LiNC/LiCN: A comparison with quantum mechanics R. Prosmiti and S. C. Farantos Institute of Electronic Structure and Laser, Foundation

  3. Epitaxial thin film growth of LiH using a liquid-Li atomic template

    SciTech Connect (OSTI)

    Oguchi, Hiroyuki; Ikeshoji, Tamio; Orimo, Shin-ichi; Ohsawa, Takeo; Shiraki, Susumu; Hitosugi, Taro; Kuwano, Hiroki

    2014-11-24

    We report on the synthesis of lithium hydride (LiH) epitaxial thin films through the hydrogenation of a Li melt, forming abrupt LiH/MgO interface. Experimental and first-principles molecular dynamics studies reveal a comprehensive microscopic picture of the crystallization processes, which sheds light on the fundamental atomistic growth processes that have remained unknown in the vapor-liquid-solid method. We found that the periodic structure that formed, because of the liquid-Li atoms at the film/MgO-substrate interface, serves as an atomic template for the epitaxial growth of LiH crystals. In contrast, films grown on the Al{sub 2}O{sub 3} substrates indicated polycrystalline films with a LiAlO{sub 2} secondary phase. These results and the proposed growth process provide insights into the preparation of other alkaline metal hydride thin films on oxides. Further, our investigations open the way to explore fundamental physics and chemistry of metal hydrides including possible phenomena that emerge at the heterointerfaces of metal hydrides.

  4. Origin of high Li? conduction in doped Li?La?Zr?O?? garnets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Yan; Rangasamy, Ezhiylmurugan; Liang, Chengdu; An, Ke

    2015-08-06

    Substitution of a native ion in the crystals with a foreign ion that differs in valence (aliovalent doping) has been widely attempted to upgrade solid-state ionic conductors for various charge carriers including O²?, H?, Li?, Na?, etc. The doping helps promote the high-conductive framework and dredge the tunnel for fast ion transport. The garnet-type Li?La?Zr?O?? (LLZO) is a fast Li? solid conductor, which received much attention as an electrolyte candidate for all-solid-state lithium ion batteries, showing great potential to offer high energy density and minimize battery safety concerns to meet extensive applications in large energy storage systems such as thosemore »for electric vehicles and aerospace. In the Li-stuffed garnet framework of LLZO, the 3D pathway formed by the incompletely occupied tetrahedral sites bridged by a single octahedron enables the superior Li? conductivity. For optimal performance, many aliovalent-doping efforts have been made throughout metal elements (Al³?, Ta??) and metalloid elements (Ga³?, Te??) in the periodic table with various valences to stabilize the high-conductive phase and increase the Li vacancy concentration.« less

  5. Origin of high Li? conduction in doped Li?La?Zr?O?? garnets

    SciTech Connect (OSTI)

    Chen, Yan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Rangasamy, Ezhiylmurugan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Liang, Chengdu [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); An, Ke [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-01-01

    Substituting a native ion in the crystals with a foreign ion that has a difference in valence, termed as aliovalent doping, has been widely attempted to upgrade solid-state ionic conductors for various charge carriers including O²?, H?, Li?, Na?, and so forth.(1-4) The doping aids to promote the high-conductive framework and dredge the tunnel for fast ion transport. The garnet-type Li?La?Zr?O?? (LLZO) is a fast Li? solid conductor, which received vast attention as an electrolyte candidate for all-solid-state lithium ion batteries, showing great potential to offer high energy density and minimize battery safety concerns to meet extensive applications in large energy storage systems such as electric vehicles and aerospace.(5-8) In the Li-stuffed garnet framework of LLZO, the 3D pathway formed through the incompletely occupied tetrahedral sites bridged by a single octahedron enables the superior Li? conductivity.(9, 10) For the purpose of optimal performance, many efforts of aliovalent doping have been made throughout metal elements (Al³?, Ta??) and metalloid elements (Ga³?, Te??) in the periodic table with various valences(11-14) to stabilize the high-conductive phase and increase the Li vacancy concentration.(7, 10, 15)

  6. Women @ Energy: Yan Li | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State University), and Babes-Bolyai University in Romania, studying chemistryelectrochemistry and physics with an education minor. She holds a Ph.D in chemistry...

  7. tokamakreactors University ,

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    France PRINCETON PLASMA PHYSICS LABORATORY PPPL 3 #12; 1 Introduction Li is an excellent getter PRINCETON PLASMA PHYSICS LABORATORY PPPL 4 #12; 1 Introduction (cont.) The concept of LiWalls relies PLASMA PHYSICS LABORATORY PPPL 5 #12; 1 Introduction (cont.) #15; Physics goal n #1; T #1; #28;E > 50 [10

  8. Spectroscopy of Lambda-9Li by electroproduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urciuoli, G. M.; Cusanno, F.; Marrone, S.; Acha, A.; Ambrozewicz, P.; Aniol, K. A.; Baturin, P.; Bertin, P. Y.; Benaoum, H.; Blomqvist, K. I.; et al

    2015-03-01

    Background: In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Purpose: To obtain a high-resolution spectrum for the 9Be(e,e?K+)Li?9 reaction. Method: Electroproduction of the hypernucleus Li?9 has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a Be9 target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. Results: The crossmore »section to low-lying states of Li?9 is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A ? separation energy, B?, of 8.36±0.08 (stat.) ±0.08 (syst.) MeV was measured, in agreement with an earlier experiment.« less

  9. Spectroscopy of Li?9 by electroproduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urciuoli, G. M.; Cusanno, F.; Marrone, S.; Acha, A.; Ambrozewicz, P.; Aniol, K. A.; Baturin, P.; Bertin, P. Y.; Benaoum, H.; Blomqvist, K. I.; et al

    2015-03-01

    Background: In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Purpose: To obtain a high-resolution spectrum for the 9Be(e,e'K+)9?Li reaction. Method: Electroproduction of the hypernucleus 9?Li has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a 9Be target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. Results: The crossmore »section to low-lying states of 9?Li is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A ? separation energy, B?, of 8.36±0.08 (stat.) ±0.08 (syst.) MeV was measured, in agreement with an earlier experiment.« less

  10. Spectroscopy of Lambda-9Li by electroproduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urciuoli, G. M.; Cusanno, F.; Marrone, S.; Acha, A.; Ambrozewicz, P.; Aniol, K. A.; Baturin, P.; Bertin, P. Y.; Benaoum, H.; Blomqvist, K. I.; Boeglin, W. U.; Breuer, H.; Brindza, P.; Bydzovsky, P.; Camsonne, A.; Chang, C. C.; Chen, J. -P.; Choi, Seonho; Chudakov, E. A.; Cisbani, E.; Colilli, S.; Coman, L.; Craver, B. J.; De Cataldo, G.; de Jager, C. W.; De Leo, R.; Deur, A. P.; Ferdi, C.; Feuerbach, R. J.; Folts, E.; Fratoni, R.; Frullani, S.; Garibaldi, F.; Gayou, O.; Giuliani, F.; Gomez, J.; Gricia, M.; Hansen, J. O.; Hayes, D.; Higinbotham, D. W.; Holmstrom, T. K.; Hyde, C. E.; Ibrahim, H. F.; Iodice, M.; Jiang, X.; Kaufman, L. J.; Kino, K.; Kross, B.; Lagamba, L.; LeRose, J. J.; Lindgren, R. A.; Lucentini, M.; Margaziotis, D. J.; Markowitz, P.; Meziani, Z. E.; McCormick, K.; Michaels, R. W.; Millener, D. J.; Miyoshi, T.; Moffit, B.; Monaghan, P. A.; Moteabbed, M.; Camacho, C. Munoz; Nanda, S.; Nappi, E.; Nelyubin, V. V.; Norum, B. E.; Okasyasu, Y.; Paschke, K. D.; Perdrisat, C. F.; Piasetzky, E.; Punjabi, V. A.; Qiang, Y.; Reimer, P. E.; Reinhold, J.; Reitz, B.; Roche, R. E.; Rodriguez, V. M.; Saha, A.; Santavenere, F.; Sarty, A. J.; Segal, J.; Shahinyan, A.; Singh, J.; Sirca, S.; Snyder, R.; Solvignon, P. H.; Sotona, M.; Subedi, R.; Sulkosky, V. A.; Suzuki, T.; Ueno, H.; Ulmer, P. E.; Veneroni, P.; Voutier, E.; Wojtsekhowski, B. B.; Zheng, X.; Zorn, C.

    2015-03-01

    Background: In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Purpose: To obtain a high-resolution spectrum for the 9Be(e,e?K+)Li?9 reaction. Method: Electroproduction of the hypernucleus Li?9 has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a Be9 target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. Results: The cross section to low-lying states of Li?9 is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A ? separation energy, B?, of 8.36±0.08 (stat.) ±0.08 (syst.) MeV was measured, in agreement with an earlier experiment.

  11. Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1

    E-Print Network [OSTI]

    Zhou, Yaoqi

    Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1 , Wen Chao Lee1 This study demonstrates the feasibility of using water and the contents of waste Li-ion batteries for the electrodes in a Li-liquid battery system. Li metal was collected electrochemically from a waste Li

  12. Predictive Models of Li-ion Battery Lifetime (Presentation) Smith...

    Office of Scientific and Technical Information (OSTI)

    Predictive Models of Li-ion Battery Lifetime (Presentation) Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G.; Shi, Y.; Pesaran, A. 25 ENERGY STORAGE; 33 ADVANCED PROPULSION...

  13. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of LIB Cathode Materials Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio...

  14. Properties of (Ga,Mn)As codoped with Li

    SciTech Connect (OSTI)

    Miyakozawa, Shohei; Chen, Lin; Matsukura, Fumihiro; Ohno, Hideo

    2014-06-02

    We grow Li codoped (Ga,Mn)As layers with nominal Mn composition up to 0.15 by molecular beam epitaxy. The layers before and after annealing are characterized by x-ray diffraction, transport, magnetization, and ferromagnetic resonance measurements. The codoping with Li reduces the lattice constant and electrical resistivity of (Ga,Mn)As after annealing. We find that (Ga,Mn)As:Li takes similar Curie temperature to that of (Ga,Mn)As, but with pronounced magnetic moments and in-plane magnetic anisotropy, indicating that the Li codoping has nontrivial effects on the magnetic properties of (Ga,Mn)As.

  15. Electrical conduction of LiF interlayers in organic diodes

    SciTech Connect (OSTI)

    Bory, Benjamin F.; Janssen, René A. J.; Meskers, Stefan C. J.; Gomes, Henrique L.; Leeuw, Dago M. de

    2015-04-21

    An interlayer of LiF in between a metal and an organic semiconductor is commonly used to improve the electron injection. Here, we investigate the effect of moderate bias voltages on the electrical properties of Al/LiF/poly(spirofluorene)/Ba/Al diodes by systematically varying the thickness of the LiF layer (2-50?nm). Application of forward bias V below the bandgap of LiF (V?LiF/poly(spirofluorene) hetero-junction. Electrons are trapped on the poly(spirofluorene) side of the junction, while positively charged defects accumulate in the LiF with number densities as high as 10{sup 25}/m{sup 3}. Optoelectronic measurements confirm the built-up of aggregated, ionized F centres in the LiF as the positive trapped charges. The charged defects result in efficient transport of electrons from the polymer across the LiF, with current densities that are practically independent of the thickness of the LiF layer.

  16. YAO-CHENG LI lli@salk.edu

    E-Print Network [OSTI]

    Wahl, Geoffrey M.

    abilities. PLoS One 8, e58395. Wade M*, YC Li*, and GM Wahl. (2013). MDM2, MDMX and p53 in oncogenesis

  17. Combined Quantum Chemical/Raman Spectroscopic Analyses of Li...

    Office of Scientific and Technical Information (OSTI)

    ChemicalRaman Spectroscopic Analyses of Li+ Cation Solvation: Cyclic Carbonate Solvents - Ethylene Carbonate and Propylene Earbonate Citation Details In-Document Search...

  18. LiU E-Press Newsletter Autumn, 2008

    E-Print Network [OSTI]

    Zhao, Yuxiao

    to Increase Biogas Yields by Anders Ek was one of the winners. For more information about LiU E-Press and how

  19. Characterization of Materials for Li-ion Batteries: Success Stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials Laboratory (HTML) User Program Characterization of Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User...

  20. Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4

    E-Print Network [OSTI]

    Bazant, Martin Z.

    Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4 Betar continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory

  1. Improved layered mixed transition metal oxides for Li-ion batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2010-01-01

    State Chemistry and Electrochemistry of LiCoi Ni, Mni/ 0 forState Chemistry and Electrochemistry of LiCo Nii/ Mn 0 forM. , "Structure and electrochemistry of LiNii/ Coi/ . M Mn

  2. Thermodynamic and kinetic properties of the Li-graphite system from first-principles calculations

    E-Print Network [OSTI]

    Ceder, Gerbrand

    We present an ab initio study of the thermodynamics and kinetics of Li [subscript x]C[subscript 6], relevant for anode Li intercalation in rechargeable Li batteries. In graphite, the interlayer interactions are dominated ...

  3. Suppression of Phase Separation in LiFePO 4 Nanoparticles During Battery Discharge

    E-Print Network [OSTI]

    Bai, Peng

    Using a novel electrochemical phase-field model, we question the common belief that LiXFePO? nanoparticles always separate into Li-rich and Li-poor phases during battery discharge. For small currents, spinodal decomposition ...

  4. Novel Laser-Based Manufacturing of nano-LiFePO4-Based Materials for High Power Li Ion Batteries

    E-Print Network [OSTI]

    Horne, Craig R.; Jaiswal, Abhishek; Chang, On; Crane, S.; Doeff, Marca M.; Wang, Emile

    2006-01-01

    II “Olivines in Lithium Batteries” The Beckman Institute,for High Power Li Ion Batteries C.R. Horne 1 , A. Jaiswal

  5. A New Perspective on Material Classification and Ink Identification Rakesh Shiradkar* Li Shen George Landon Sim Heng Ong* and Ping Tan*

    E-Print Network [OSTI]

    Tan, Ping

    A New Perspective on Material Classification and Ink Identification Rakesh Shiradkar* Li Shen Research Eastern Kentucky University Motivation Most previous methods on material classification use a head Since, Isotropic BRDFs can be approximated by a 2D BRDF (d, h) Rusinkiewicz [3] Our New Perspective

  6. Nuclear Pleomorphism Scoring by Selective Cell Nuclei Detection Jean-Romain Dalle Hao Li Chao-Hui Huang Wee Kheng Leow

    E-Print Network [OSTI]

    Leow, Wee Kheng

    Nuclear Pleomorphism Scoring by Selective Cell Nuclei Detection Jean-Romain Dalle Hao Li Chao, National University Hospital pattcp@nus.edu.sg Abstract Scoring the nuclear pleomorphism for nuclear pleo- morphism scoring according to the Nottingham grading system. In contrast, most

  7. Riboproteomics of the Hepatitis C Virus Internal Ribosomal Entry Henry Lu, Weiqun Li, William Stafford Noble, Donald Payan, and D. C. Anderson*,

    E-Print Network [OSTI]

    Noble, William Stafford

    Riboproteomics of the Hepatitis C Virus Internal Ribosomal Entry Site Henry Lu, Weiqun Li, William of Molecular Biology, University of Oregon, Eugene, Oregon 97403 Received February 8, 2004 Hepatitis C virus. Keywords: hepatitis C · IRES · RNA · binding proteins · shotgun peptide sequencing · machine learning

  8. Positive correlation between Li and Mg isotope ratios in the river waters of the Mackenzie Basin challenges the interpretation of apparent isotopic

    E-Print Network [OSTI]

    Paytan, Adina

    Positive correlation between Li and Mg isotope ratios in the river waters of the Mackenzie Basin a Institut de Physique du Globe de Paris, Sorbonne Paris Cite´, Univ Paris Diderot, UMR 7154 CNRS, F-75005 Paris, France b Department of Earth Sciences, University of Cambridge, Downing Street, Cambridge CB23EQ

  9. Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li

    E-Print Network [OSTI]

    Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li Lithium-halogen exchange reactions are essentially inert. 2 t-BuLi t-BuI + RLi t-BuLi isobutene + isobutane + LiI Lithium-halogen exchange reactions, and lithium iodide. H OEtBr H H OEtLi H1.1 eq n-BuLi Et2O, !80 °C Lau, K. S.; Schlosser, M. J. Org. Chem. 1978

  10. Primordial Li abundance and massive particles

    SciTech Connect (OSTI)

    Latin-Capital-Letter-Eth apo, H.

    2012-10-20

    The problem of the observed lithium abundance coming from the Big Bang Nucleosynthesis is as of yet unsolved. One of the proposed solutions is including relic massive particles into the Big Bang Nucleosynthesis. We investigated the effects of such particles on {sup 4}HeX{sup -}+{sup 2}H{yields}{sup 6}Li+X{sup -}, where the X{sup -} is the negatively charged massive particle. We demonstrate the dominance of long-range part of the potential on the cross-section.

  11. A=11Li (1985AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries80AJ01) (See the Isobar Diagram for 11Li)

  12. A=12Li (1980AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries80AJ01) (See0AJ01) (Not illustrated) 12Li is

  13. A=12Li (1985AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries80AJ01) (See0AJ01) (Not illustrated) 12Li

  14. A=13Li (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries80AJ01)86AJ01) (Not illustrated) 13Li has not

  15. A=13Li (1991AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries80AJ01)86AJ01) (Not illustrated) 13Li has

  16. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02) (See Energy Level Diagrams forLi (1995TI07)

  17. A=20Li (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03) (Not98TI06) (See EnergyLi (1998TI06)

  18. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion1AJ01)72AJ02)78AJ03)98TI06) (See2010PU04)1987TI07)4AHeLi

  19. A=8Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams8Be (59AJ76) (See8AJ01)8AJ01)8Li

  20. A=8Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See Energy Level Diagrams8Be (59AJ76) (See8AJ01)8AJ01)8Li

  1. Surround modulation of global form perception Department of Psychology, National Taiwan University,

    E-Print Network [OSTI]

    Chen, Chein Chung

    Surround modulation of global form perception Department of Psychology, National Taiwan University, Taipei, TaiwanHsin-Hung Li Department of Psychology, National Taiwan University, Taipei, Taiwan, & Center for Neurobiology and Cognitive Science, National Taiwan University, Taipei, TaiwanChien-Chung Chen We demonstrate

  2. 10/19/2012 Seminar: Duquesne University 1 Solid electrolytes for battery applications

    E-Print Network [OSTI]

    Holzwarth, Natalie

    10/19/2012 Seminar: Duquesne University 1 Solid electrolytes for battery applications;10/19/2012 Seminar: Duquesne University 2 Materials components of a Li ion battery #12;10/19/2012 Seminar: Duquesne University 3 Example: Thin-film battery developed by Nancy Dudney and collaborators at Oak Ridge National

  3. The rotational spectrum and dynamical structure of LiOH and LiOD: A combined laboratory and ab initio study

    E-Print Network [OSTI]

    Ziurys, Lucy M.

    crystals and Li­O­Li molecules in the gas phase.2 The system just between bent H2O and linear Li2O is Li. Mol. Spectrosc. 135, 89 1989 , a change from a linear to a bent minimum energy configuration at elongated Li­O distances, but also a similar change from linear to bent at elongated O­H distances. © 2004

  4. Air stable Al2O3-coated Li2NiO2 cathode additive as a surplus current consumer in a Li-ion cell

    E-Print Network [OSTI]

    Cho, Jaephil

    increases to 2.75V (2.85V vs. graphite), its discharge capacity decreases to 120 mAh/g, which corresponds for the irreversible capacity of the Li-ion cell using LiCoO2 and natural graphite as cathode and anode materials the complete decomposition of the Li2NiO2. 1. Introduction Most Li secondary batteries use LiCoO2 as a cathode

  5. Significant Cost Improvement of Li-Ion Cells Through Non-NMP...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies Significant Cost Improvement of Li-Ion...

  6. Localization of vacancies and mobility of lithium ions in Li{sub 2}ZrO{sub 3} as obtained by {sup 6,7}Li NMR

    SciTech Connect (OSTI)

    Baklanova, Ya. V., E-mail: baklanovay@ihim.uran.ru [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation); Arapova, I. Yu.; Buzlukov, A.L.; Gerashenko, A.P.; Verkhovskii, S.V.; Mikhalev, K.N. [Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, 18 Kovalevskaya str., 620990 Ekaterinburg (Russian Federation); Denisova, T.A.; Shein, I.R.; Maksimova, L.G. [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation)

    2013-12-15

    The {sup 6,7}Li NMR spectra and the {sup 7}Li spin–lattice relaxation rate were measured on polycrystalline samples of Li{sub 2}ZrO{sub 3}, synthesized at 1050 K and 1300 K. The {sup 7}Li NMR lines were attributed to corresponding structural positions of lithium Li1 and Li2 by comparing the EFG components with those obtained in the first-principles calculations of the charge density in Li{sub 2}ZrO{sub 3}. For both samples the line width of the central {sup 7}Li transition and the spin–lattice relaxation time decrease abruptly at the temperature increasing above ?500 K, whereas the EFG parameters are averaged (??{sub Q}?=42 (5) kHz) owing to thermally activated diffusion of lithium ions. - Graphical abstract: Path of lithium ion hopping in lithium zirconate Li{sub 2}ZrO{sub 3}. - Highlights: • Polycrystalline samples Li{sub 2}ZrO{sub 3} with monoclinic crystal structure synthesized at different temperatures were investigated by {sup 6,7}Li NMR spectroscopy. • Two {sup 6,7}Li NMR lines were attributed to the specific structural positions Li1 and Li2. • The distribution of vacancies was clarified for both lithium sites. • The activation energy and pathways of lithium diffusion in Li{sub 2}ZrO{sub 3} were defined.

  7. Spectroscopy of Lambda-9Li by electroproduction

    E-Print Network [OSTI]

    G. M. Urciuoli; F. Cusanno; S. Marrone; A. Acha; P. Ambrozewicz; K. A. Aniol; P. Baturin; P. Y. Bertin; H. Benaoum; K. I. Blomqvist; W. U. Boeglin; H. Breuer; P. Brindza; P. Bydzovsky; A. Camsonne; C. C. Chang; J. -P. Chen; Seonho Choi; E. A. Chudakov; E. Cisbani; S. Colilli; L. Coman; B. J. Craver; G. De Cataldo; C. W. de Jager; R. De Leo; A. P. Deur; C. Ferdi; R. J. Feuerbach; E. Folts; R. Fratoni; S. Frullani; F. Garibaldi; O. Gayou; F. Giuliani; J. Gomez; M. Gricia; J. O. Hansen; D. Hayes; D. W. Higinbotham; T. K. Holmstrom; C. E. Hyde; H. F. Ibrahim; M. Iodice; X. Jiang; L. J. Kaufman; K. Kino; B. Kross; L. Lagamba; J. J. LeRose; R. A. Lindgren; M. Lucentini; D. J. Margaziotis; P. Markowitz; Z. E. Meziani; K. McCormick; R. W. Michaels; D. J. Millener; T. Miyoshi; B. Moffit; P. A. Monaghan; M. Moteabbed; C. Munoz Camacho; S. Nanda; E. Nappi; V. V. Nelyubin; B. E. Norum; Y. Okasyasu; K. D. Paschke; C. F. Perdrisat; E. Piasetzky; V. A. Punjabi; Y. Qiang; P. E. Reimer; J. Reinhold; B. Reitz; R. E. Roche; V. M. Rodriguez; A. Saha; F. Santavenere; A. J. Sarty; J. Segal; A. Shahinyan; J. Singh; S. Sirca; R. Snyder; P. H. Solvignon; M. Sotona; R. Subedi; V. A. Sulkosky; T. Suzuki; H. Ueno; P. E. Ulmer; P. Veneroni; E. Voutier; B. B. Wojtsekhowski; X. Zheng; C. Zorn

    2014-10-01

    In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Electroproduction of the hypernucleus Lambda-9Li has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a 9Be target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. The cross section to low-lying states of Lambda-9Li is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A Lambda separation energy of 8.36 +- 0.08 (stat.) +- 0.08 (syst.) MeV was measured, in agreement with an earlier experiment.

  8. Approved Module Information for LI2008, 2014/5 Module Title/Name: Communication across Cultures Module Code: LI2008

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for LI2008, 2014/5 Module Title/Name: Communication across Cultures Module Code: LI2008 School: Languages and Social Sciences Module Type: Standard Module New Module? No Module Credits: 10 Module Management Information Module Leader Name Olga Castro Email Address o

  9. PHILADELPHIA UNIVERSITY PHILADELPHIA UNIVERSITY

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY : 626 25/9/1991 137 28/10/2007 195164 626 25/9/1991 10/1/2010 --- 1062 : : #12;PHILADELPHIA UNIVERSITY : 2009/2010 11221245 16171952 1211730 2002 2003 2004 2005 2006 2007 2008 2009 2010 #12;PHILADELPHIA UNIVERSITY : : : #12

  10. LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery

    DOE Patents [OSTI]

    Ko, Suk M. (Huntsville, AL)

    1980-01-01

    This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

  11. Material review of Li ion battery separators

    SciTech Connect (OSTI)

    Weber, Christoph J., E-mail: Christoph.Weber@freudenberg-nw.com; Geiger, Sigrid, E-mail: Christoph.Weber@freudenberg-nw.com [Freudenberg Vliesstoffe SE and Co KG, 69465 Weinheim (Germany); Falusi, Sandra; Roth, Michael [Freudenberg Forschungsdienste SE and Co KG, 69465 Weinheim (Germany)

    2014-06-16

    Separators for Li Ion batteries have a strong impact on cell production, cell performance, life, as well as reliability and safety. The separator market volume is about 500 million m{sup 2} mainly based on consumer applications. It is expected to grow strongly over the next decade for mobile and stationary applications using large cells. At present, the market is essentially served by polyolefine membranes. Such membranes have some technological limitations, such as wettability, porosity, penetration resistance, shrinkage and meltdown. The development of a cell failure due to internal short circuit is potentially closely related to separator material properties. Consequently, advanced separators became an intense area of worldwide research and development activity in academia and industry. New separator technologies are being developed especially to address safety and reliability related property improvements.

  12. University Library University of Saskatchewan

    E-Print Network [OSTI]

    Saskatchewan, University of

    University Library University of Saskatchewan Core Competencies for University of Saskatchewan Librarians This document defines the basic knowledge and skills librarians at the University of Saskatchewan in the Canadian academic research environment. The University Library Competencies Framework (Figure 1) maps

  13. Effects of electrolyte salts on the performance of Li-O2 batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Burton, Sarah D.; Cosimbescu, Lelia; Gross, Mark E.; Zhang, Jiguang

    2013-02-05

    It is well known that the stability of nonaqueous electrolyte is critical for the rechargeable Li-O2 batteries. Although stability of many solvents used in the electrolytes has been investigated, considerably less attention has been paid to the stability of electrolyte salt which is the second major component. Herein, we report the systematic investigation of the stability of seven common lithium salts in tetraglyme used as electrolytes for Li-O2 batteries. The discharge products of Li-O2 reaction were analyzed by X-ray diffraction, X-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy. The performance of Li-O2 batteries was strongly affected by the salt used in the electrolyte. Lithium tetrafluoroborate (LiBF4) and lithium bis(oxalato)borate (LiBOB) decompose and form LiF and lithium borates, respectively during the discharge of Li-O2 batteries. Several other salts, including lithium bis(trifluoromethane)sulfonamide (LiTFSI), lithium trifluoromethanesulfonate (LiTf), lithium hexafluorophosphate (LiPF6), lithium perchlorate (LiClO4) , and lithium bromide (LiBr) led to the discharge products which mainly consisted of Li2O2 and only minor signs of decomposition of LiTFSI, LiTf, LPF6 and LiClO4 were detected. LiBr showed the best stability during the discharge process. As for the cycling performance, LiTf and LiTFSI were the best among the studied salts. In addition to the instability of lithium salts, decomposition of tetraglyme solvent was a more significant factor contributing to the limited cycling stability. Thus a more stable nonaqueous electrolyte including organic solvent and lithium salt still need to be further developed to reach a fully reversible Li-O2 battery.

  14. High Energy Density Cathode for Lithium Batteries: From LiCoO_(2) to Sulfur 

    E-Print Network [OSTI]

    Pu, Xiong

    2014-05-29

    be viable. This dissertation, motivated with these aims, investigated both Li-ion batteries and Li-S batteries. LiCoO_(2), though it has been commercialized in Li-ion batteries, still has the potential to achieve higher energy density, since its practical...

  15. Dynamic dipole polarizability of Li{sup +} embedded in plasmas

    SciTech Connect (OSTI)

    Kar, S., E-mail: skar@hit.edu.cn [Center for Theoretical Atomic and Molecular Physics, The Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, People's Republic of China and Institute of Mathematical Sciences, University of Malaya, Ku (Malaysia); Kamali, M. Z. M., E-mail: Mzmk200@yahoo.com [Centre for Foundation Studies in Science, University of Malaya, Kuala Lumpur (Malaysia); Ratnavelu, K., E-mail: Kururatan2012@gmail.com [Institute of Mathematical Sciences, University of Malaya, Kuala Lumpur (Malaysia)

    2014-03-05

    Dynamic dipole polarizabilities of the system Li{sup +} embedded in weakly coupled plasmas are investigated using highly correlated exponential wave functions in the framework of the pseudostate summation technique. The Debye-Hückel shielding approach of plasma modeling is used to represent weakly coupled plasma environment. In free-atomic cases, results obtained from the present study are in agreement with the available calculations. Frequency-dependent polarizability of Li{sup +} as function of screening parameter is presented for the first time. Resonance frequencies for Li{sup +} are also presented in terms of screening parameter.

  16. Optically pumped cerium-doped LiSrAlF{sub 6} and LiCaAlF{sub 6}

    DOE Patents [OSTI]

    Marshall, C.D.; Payne, S.A.; Krupke, W.F.

    1996-05-14

    Ce{sup 3+}-doped LiSrAlF{sub 6} crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF{sub 6} with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF{sub 6} type of chemical formula, e.g. Ce-doped LiCaAlF{sub 6} and LiSrGaF{sub 6}, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator. 10 figs.

  17. Optically pumped cerium-doped LiSrAlF.sub.6 and LiCaAlF.sub.6

    DOE Patents [OSTI]

    Marshall, Christopher D. (Livermore, CA); Payne, Stephen A. (Castro Valley, CA); Krupke, William F. (Pleasanton, CA)

    1996-01-01

    Ce.sup.3+ -doped LiSrAlF.sub.6 crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF.sub.6 with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF.sub.6 type of chemical formula, e.g. Ce-doped LiCaAlF.sub.6 and LiSrGaF.sub.6, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator.

  18. On the Origin and Implications of Li$_2$O$_2$ Toroid Formation in Nonaqueous Li-O$_2$ Batteries

    E-Print Network [OSTI]

    Aetukuri, Nagaphani B; García, Jeannette M; Krupp, Leslie E; Viswanathan, Venkatasubramanian; Luntz, Alan C

    2014-01-01

    The lithium-air (Li-O$_2$) battery has received enormous attention as a possible alternative to current state-of-the-art rechargeable Li-ion batteries given their high theoretical specific energy. However, the maximum discharge capacity in nonaqueous Li-O$_2$ batteries is limited to a small fraction of its theoretical value due to the insulating nature of lithium peroxide, Li$_2$O$_2$, the battery$'$s primary discharge product. In this work, we show that the inclusion of trace amounts of electrolyte additives, such as H$_2$O, significantly improve the capacity of the Li-O$_2$ battery. These additives trigger a solution-based growth mechanism due to their solvating properties, thereby circumventing the Li$_2$O$_2$ conductivity limitation. Experimental observations and a growth model imply that this solution mechanism is responsible for Li$_2$ toroid formation. We present a general formalism describing an additive$'$s tendency to trigger the solution process, providing a rational design route for electrolytes t...

  19. PHILADELPHIA UNIVERSITY -1 1191

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY :: -1 1191) . : : : . #12;PHILADELPHIA UNIVERSITY . . : . . . . #12;PHILADELPHIA UNIVERSITY

  20. Heteroclite electrochemical stability of an I based Li7P2S8I superionic conductor

    SciTech Connect (OSTI)

    Rangasamy, Ezhiylmurugan; Liu, Zengcai; Gobet, Mallory; Pilar, Kartik; Sahu, Gayatri; Greenbaum, Steve; Liang, Chengdu

    2015-01-01

    Stability from Instability: A Li7P2S8I solid state Li-ion conductor derived from -Li3PS4 and LiI demonstrates exceptional electrochemical stability. The oxidation instability of I is subverted nullified via its incorporation into the coordinated structure. The inclusion of I also creates stability with metallic Li anode while simultaneously improving the interfacial kinetics. Low temperature membrane processability enables facile fabrication of dense membranes, making it suitable for industrial adoption.

  1. Transport and Failure in Li-ion Batteries | Stanford Synchrotron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transport and Failure in Li-ion Batteries Monday, February 13, 2012 - 1:30pm SSRL Conference Room 137-322 Stephen J. Harris, General Motors R&D While battery performance is well...

  2. Modeling - Scale-Bridging Simulations Active Materials in Li...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Society, v. 154 (10), pp. A978-A986. 3. Wang, C.-W. and Sastry, A.M., 2007, "Mesoscale Modeling of a Li-Ion Poly Cell," Journal of the Electrochemical Society, v. 154...

  3. Multiscale Simulations of Li Ion Conductivity in Solid Electrolyte

    SciTech Connect (OSTI)

    Sushko, Maria L.; Rosso, Kevin M.; Zhang, Jiguang; Liu, Jun

    2011-09-15

    Optimizing solid electrolyte design for its application in Li-ion and Li-metal batteries requires a fundamental understanding of the mechanism of ion and electron transport in the material at the nano- to micron-scales. We have performed simulations of Li+ and electron conductivity in lithium phosphorus oxynitride, one of the most widely used solid electrolytes, using novel hierarchical multiscale models. By comparing the results of one- and three-dimensional models we show that for this material with complex non-linear Li+ diffusion pathways three-dimensional description is essential for reproducing experimentally measured conductivity. We also suggest some basic principles to design optimum electrolyte tailored for low and high temperature regimes.

  4. Boston University Columbia University

    E-Print Network [OSTI]

    Bucci, David J.

    University CUNY Hunter College University of Massachusetts Amherst & Yestermorrow Design/Build School to consider the safety and security of the programs you are considering attending. Also Dartmouth's Dickey searching for program options by criteria: http://www.iiepassport.org/ http

  5. Friendship 3-Hypergraphs P. C. (Ben) Li

    E-Print Network [OSTI]

    van Rees, John

    , all joined at one vertex, called the universal friend. The graphs are called windmill graphs or 2 of a triangle. (one-vane windmill graph). The proofs can be found in [4] and [1]. This eectively ends

  6. Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material

    E-Print Network [OSTI]

    Kim, Jae Chul

    We investigated the structural stability and electrochemical properties of LiMnBO3 in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on monoclinic ...

  7. Synthesis and Electrochemical Properties of Monoclinic LiMnBO[subscript 3] as a Li Intercalation Material

    E-Print Network [OSTI]

    Kim, Jae Chul

    We investigated the structural stability and electrochemical properties of LiMnBO[subscript 3] in the hexagonal and monoclinic form with ab initio computations and, for the first time, report electrochemical data on ...

  8. Structural Evolution and Li Dynamics in Nanophase Li3PS4 by Solid-State and Pulsed Field Gradient NMR

    SciTech Connect (OSTI)

    Gobet, Mallory [Hunter College of the City University of New York] [Hunter College of the City University of New York; Greenbaum, Steve [Hunter College of the City University of New York] [Hunter College of the City University of New York; Sahu, Gayatri [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2014-01-01

    The ceramic lithium ion conductor -Li3PS4 has a disordered and nanoporous structure that leads to an enhancement in ionic conductivity by some three orders of magnitude compared to the crystalline phase. The phase is prepared by thermal treatment of an inorganic-organic complex based on Li3PS4 and THF. Multinuclear (1H, 6,7Li, 31P) solid state NMR spectroscopy is used to characterize the structural phase evolution of the starting material at various steps in the thermal treatment. The phase formed after high temperature treatment is recognized as spectroscopically distinct from the bulk -Li3PS4 compound. Also formed is an amorphous lithium thiophosphate phase that is metastable as verified by annealing over an extended period. Lithium ion self-diffusion coefficients are measurable by standard pulsed gradient NMR methods at 100oC and with values consistent with the high ionic conductivity previously reported for this material.

  9. THE HIGH TEMPERATURE CHEMICAL REACTIVITY OF LI2O

    SciTech Connect (OSTI)

    Kessinger, G.; Missimer, D.

    2009-11-13

    The ultimate purpose of this study was to investigate the use of a Li-Ca mixture for direct reduction of actinide oxides to actinide metals at temperatures below 1500 C. For such a process to be successful, the products of the reduction reaction, actinide metals, Li{sub 2}O, and CaO, must all be liquid at the reaction temperature so the resulting actinide metal can coalesce and be recovered as a monolith. Since the established melting temperature of Li{sub 2}O is in the range 1427-1700 C and the melting temperature of CaO is 2654 C, the Li{sub 2}O-CaO (lithium oxidecalcium oxide) pseudo-binary system was investigated in an attempt to identify the presence of low-melting eutectic compositions. The results of our investigation indicate that there is no evidence of ternary Li-Ca-O phases or solutions melting below 1200 C. In the 1200-1500 C range utilizing MgO crucibles, there is some evidence for the formation of a ternary phase; however, it was not possible to determine the phase composition. The results of experiments performed with ZrO{sub 2} crucibles in the same temperature range did not show the formation of the possible ternary phase seen in the earlier experiment involving MgO crucibles, so it was not possible to confirm the possibility that a ternary Li-Ca-O or Li-Mg-O phase was formed. It appears that the Li{sub 2}O-CaO materials reacted, to some extent, with all of the container materials, alumina (Al{sub 2}O{sub 3}), magnesia (MgO), zirconia (ZrO{sub 2}), and 95% Pt-5% Au; however, to clarify the situation additional experiments are required. In addition to the primary purpose of this study, the results of this investigation led to the conclusions that: (1) The melting temperature of Li{sub 2}O may be as low as 1250 C, which is considerably lower than the previously published values in the range 1427-1700 C; (2) Lithium oxide (Li{sub 2}O) vaporizes congruently; (3) Lithium carbonate and Li2O react with 95% Pt-5% Au, and also reacts with pure Pt; and (4) It is likely that some or all of the past high temperature phase behavior and vaporization experiments involving Li{sub 2}O(s) at temperatures above 1250 C have actually involved Li{sub 2}O(l). If these past measurements were actually measurements performed on Li{sub 2}O(l) instead of the solid, the thermochemical data for phases and species in the Li-O system will require reevaluation.

  10. http://lez1.pppl.gov/pub/LiMagPropulsion.ps http://lez1.pppl.gov/pub/LiMagPropulsion.pdf

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    http://lez1.pppl.gov/pub/LiMagPropulsion.ps http://lez1.pppl.gov/pub/LiMagPropulsion.pdf Magnetic propulsion for driving liquid Li walls L. E. Zakharov, PPPL Background: The mechanism of magnetic propulsion the technical aspects of magnetic propulsion, the issues and the necessary R & D. Electro-magnetic propulsion

  11. Structural and Electrochemical Characterization of PureLiFePO4and Nanocomposite C-LiFePO4Cathodes for Lithium Ion Rechargeable Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumar, Arun; Thomas, R.; Karan, N. K.; Saavedra-Arias, J. J.; Singh, M. K.; Majumder, S. B.; Tomar, M. S.; Katiyar, R. S.

    2009-01-01

    Pure lithium iron phosphate (LiFePO4) and carbon-coatedLiFePO4(C-LiFePO4) cathode materials were synthesized for Li-ion batteries. Structural and electrochemical properties of these materials were compared. X-ray diffraction revealed orthorhombic olivine structure. Micro-Raman scattering analysis indicates amorphous carbon, and TEM micrographs show carbon coating onLiFePO4particles. Ex situ Raman spectrum of C-LiFePO4at various stages of charging and discharging showed reversibility upon electrochemical cycling. The cyclic voltammograms ofLiFePO4and C-LiFePO4showed only a pair of peaks corresponding to the anodic and cathodic reactions. The first discharge capacities were 63, 43, and 13?mAh/g for C/5, C/3, and C/2, respectively forLiFePO4where as in case of C-LiFePO4that were 163, 144,more »118, and 70?mAh/g for C/5, C/3, C/2, and 1C, respectively. The capacity retention of pureLiFePO4was 69% after 25 cycles where as that of C-LiFePO4was around 97% after 50 cycles. These results indicate that the capacity and the rate capability improved significantly upon carbon coating.« less

  12. Structural and Electrochemical Characterization of Pure LiFePO 4 and Nanocomposite C- LiFePO 4 Cathodes for Lithium Ion Rechargeable Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumar, Arun; Thomas, R.; Karan, N. K.; Saavedra-Arias, J. J.; Singh, M. K.; Majumder, S. B.; Tomar, M. S.; Katiyar, R. S.

    2009-01-01

    Pure lithium iron phosphate ( LiFePO 4 ) and carbon-coated LiFePO 4 (C- LiFePO 4 ) cathode materials were synthesized for Li-ion batteries. Structural and electrochemical properties of these materials were compared. X-ray diffraction revealed orthorhombic olivine structure. Micro-Raman scattering analysis indicates amorphous carbon, and TEM micrographs show carbon coating on LiFePO 4 particles. Ex situ Raman spectrum of C- LiFePO 4 at various stages of charging and discharging showed reversibility upon electrochemical cycling. The cyclic voltammograms of more » LiFePO 4 and C- LiFePO 4 showed only a pair of peaks corresponding to the anodic and cathodic reactions. The first discharge capacities were 63, 43, and 13?mAh/g for C/5, C/3, and C/2, respectively for LiFePO 4 where as in case of C- LiFePO 4 that were 163, 144, 118, and 70?mAh/g for C/5, C/3, C/2, and 1C, respectively. The capacity retention of pure LiFePO 4 was 69% after 25 cycles where as that of C- LiFePO 4 was around 97% after 50 cycles. These results indicate that the capacity and the rate capability improved significantly upon carbon coating. « less

  13. Math/Stat 370: Engineering Statistics, Washington State University

    E-Print Network [OSTI]

    Li, Haijun

    Li Math/Stat 370: Engineering Statistics, Washington State University Week 12 7 / 29 #12;Six-Sigma point plots outside three-sigma control limits Two out of three consecutive points plot beyond a two-sigma limit. Four out of five consecutive points plot at a distance of one sigma or beyond from the center

  14. Influence of Li ions on the oxygen reduction reaction of platinum electrocatalyst

    SciTech Connect (OSTI)

    Liu, H; Xing, YC

    2011-06-01

    A Li-air battery can provide a much higher theoretical energy density than a Li-ion battery. The use of aqueous acidic electrolytes may prevent lithium oxide deposition from aprotic electrolytes and lithium carbonate precipitation from alkaline electrolytes. The present communication reports a study on the effect of Li ions on the oxygen reduction reaction (ORR) in sulfuric acid electrolytes. It was found that the Li ions have negligible interactions with the active surface of Pt catalysts. However, significantly lower ORR activities were found when Li ions are present in the sulfuric acid. The intrinsic kinetic activities were found to decrease with the increase of Li ion concentrations, but level off when the Li ion concentrations are larger than 1.0 M. The low activities of Pt catalysts in Li ion containing electrolytes were attributed to a constraining effect of Li ions on the diffusion of oxygen in the electrolyte solution. (C) 2011 Elsevier B.V. All rights reserved.

  15. High Performance Anode for Advanced Li Batteries

    SciTech Connect (OSTI)

    Lake, Carla

    2015-11-02

    The overall objective of this Phase I SBIR effort was to advance the manufacturing technology for ASI’s Si-CNF high-performance anode by creating a framework for large volume production and utilization of low-cost Si-coated carbon nanofibers (Si-CNF) for the battery industry. This project explores the use of nano-structured silicon which is deposited on a nano-scale carbon filament to achieve the benefits of high cycle life and high charge capacity without the consequent fading of, or failure in the capacity resulting from stress-induced fracturing of the Si particles and de-coupling from the electrode. ASI’s patented coating process distinguishes itself from others, in that it is highly reproducible, readily scalable and results in a Si-CNF composite structure containing 25-30% silicon, with a compositionally graded interface at the Si-CNF interface that significantly improve cycling stability and enhances adhesion of silicon to the carbon fiber support. In Phase I, the team demonstrated the production of the Si-CNF anode material can successfully be transitioned from a static bench-scale reactor into a fluidized bed reactor. In addition, ASI made significant progress in the development of low cost, quick testing methods which can be performed on silicon coated CNFs as a means of quality control. To date, weight change, density, and cycling performance were the key metrics used to validate the high performance anode material. Under this effort, ASI made strides to establish a quality control protocol for the large volume production of Si-CNFs and has identified several key technical thrusts for future work. Using the results of this Phase I effort as a foundation, ASI has defined a path forward to commercialize and deliver high volume and low-cost production of SI-CNF material for anodes in Li-ion batteries.

  16. High Performance Cathodes for Li-Air Batteries

    SciTech Connect (OSTI)

    Xing, Yangchuan

    2013-08-22

    The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

  17. Inner-Shell Capture and Ionization in Collisions of H+, He2+, and Li3+ Projectiles with Neon and Carbon 

    E-Print Network [OSTI]

    Ford, A. Lewis; Reading, John F.; Becker, R. L.

    1981-01-01

    , T. Bratton, and T. K. Saylor, Phys. Rev. A 16, 2248 (1977). E. Clementi and C. Roetti, At. Data Nucl. Data Tables 14, 177 (1974). J. A. Bearden and A. F. Burr, Rev. Mod. Phys. 39, 125 (1967). R. Manne and T. Aberg, Chem. Phys. Lett. 7, 282...PHYSICAL REVIEW A VOLUME 23, NUMBF R FEBRUARY 1981 Inner-shell capture and ionization in collisions of H+, He'+, and Li'+ projectiles with neon and carbon A. L. Ford~ and J. F. Reading* Physics Department, Texas A &M University, College Station...

  18. Lithium cobalt(II) pyrophosphate, Li[subscript 1.86]CoP[subscript...

    Office of Scientific and Technical Information (OSTI)

    of intersecting tunnels containing Li cations and could be of great interest in Li ion battery chemistry. The structure also exhibits cation disorder with 13.5% Co residing at the...

  19. Dendrite-Free Li Deposition Using Trace-Amounts of Water as an...

    Office of Scientific and Technical Information (OSTI)

    (Li) batteries. This is because water is highly reactive with the commonly used LiPF6 salt and leads to the formation of HF that corrodes battery materials. In this work, we...

  20. Synthesis and Electrochemistry of Li3MnO4: Mn in the +5 Oxidation State

    E-Print Network [OSTI]

    Saint, Juliette.A.; Doeff, Marca M.; Reed, John

    2008-01-01

    Synthesis and Electrochemistry of Li 3 MnO 4 : Mn in the +5A study describing the electrochemistry of Li 2 MnO 3 in ainvestigation into the electrochemistry of this system

  1. Structural Analysis of Southern Dixie Valley using LiDAR and...

    Open Energy Info (EERE)

    and tonal lineaments were used to define possible faults in both the LiDAR and LSA photo data sets.The LiDAR and LSA photo analysis has identified a large number of previously...

  2. Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Graphite and Olivine-Based Materials for Li-Ion Batteries Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries Presentation from the U.S. DOE Office of Vehicle...

  3. A Reactive Force Field study of Li/C Systems for Electrical Energy...

    Office of Scientific and Technical Information (OSTI)

    A Reactive Force Field study of LiC Systems for Electrical Energy Storage Citation Details In-Document Search Title: A Reactive Force Field study of LiC Systems for Electrical...

  4. Lithium fluoride (LiF) crystal for parametric X-ray (PXR) production

    E-Print Network [OSTI]

    Danon, Yaron

    Lithium fluoride (LiF) crystal for parametric X-ray (PXR) production B. Sones *, Y. Danon, R 2004 Abstract Parametric X-ray (PXR) production is reported using lithium fluoride (LiF) as a target

  5. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP...

  6. The significance of Li-ion batteries in electric vehicle life...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The significance of Li-ion batteries in electric vehicle life-cycle energy and emissions and recycling's role in its reduction Title The significance of Li-ion batteries in...

  7. Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Li-Ion Polymer Battery Cell Manufacturing Plant in USA Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  8. Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, Thomas M.

    2008-01-01

    of Aluminum in Lithium-ion Battery Electrolytes with LiBOBin commercially available lithium-ion battery electrolytes,

  9. Aalborg Universitet Datasheet-based modeling of Li-Ion batteries

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    SLPB 120216216 53Ah Li-Ion cell. Keywords: battery model, Lithium Ion battery, equivalent circuit model

  10. Alternating magnetic anisotropy of Li2(Li1–xTx)N(T=Mn,Fe,Co,andNi)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1–xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.more »As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.« less

  11. Alternating magnetic anisotropy of Li 2 ( Li 1 - x T x ) N ( T = Mn , Fe , Co , and Ni )

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-01

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li?(Li1-xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.more »The calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.« less

  12. Alternating magnetic anisotropy of Li 2 ( Li 1 - x T x ) N ( T = Mn , Fe , Co , and Ni )

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-01

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li?(Li1-xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model. The calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.

  13. New York University UNIVERSITY POLICIES

    E-Print Network [OSTI]

    Van Den Eijnden, Eric

    1 New York University UNIVERSITY POLICIES Title: Developing University Policies Effective Date President, Office of the President Responsible Officer: General Counsel Policy It is the policy of New York

  14. Electrochemical Performance of LiMnPO[subscript 4] Synthesized with Off-Stoichiometry

    E-Print Network [OSTI]

    Kang, Byoungwoo

    LiMnPO[subscript 4] was synthesized from an off-stoichiometric mix of starting materials with nominal composition LiMn[subscript 0.9]P[subscript 0.95]O[subscript 4??]. Stoichiometric LiMnPO[subscript 4] with particle size ...

  15. Li2O Particulate Flow Concept, APPLE APEX Interim Report November, 1999

    E-Print Network [OSTI]

    California at Los Angeles, University of

    Li2O Particulate Flow Concept, APPLE APEX Interim Report November, 1999 9-1 CHAPTER 9: Li2O PARTICULATE FLOW CONCEPT ­ APPLE DESIGN Contributors Lead Author: Dai Kai Sze Dai Kai Sze, Zhanhe Wang (ANL Particulate Flow Concept, APPLE APEX Interim Report November, 1999 9-2 9. LI2O PARTICULATE FLOW CONCEPT

  16. Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries

    E-Print Network [OSTI]

    Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries g h l i g h t s We demonstrated that thermal management of Li-ion batteries improves dramatically incorporation leads to significant decrease in the temperature rise in Li-ion batteries. Graphene leads

  17. Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries

    E-Print Network [OSTI]

    Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries to a transformative change in thermal management of Li-ion batteries. a r t i c l e i n f o Article history: Received September 2013 Keywords: Battery Thermal management Graphene Phase change material a b s t r a c t Li

  18. Comment on Li pellet conditioning in tokamak fusion test reactor R. V. Budny

    E-Print Network [OSTI]

    Budny, Robert

    Comment on Li pellet conditioning in tokamak fusion test reactor R. V. Budny Princeton Plasma; published online 9 September 2011) Li pellet conditioning in TFTR results in a reduction of the edge technique for introducing Li is via pellet injection. This was pioneered in ALCATOR- CMOD where it was first

  19. Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide (LiHMDS)

    E-Print Network [OSTI]

    Collum, David B.

    Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide, and 13C NMR spectroscopic studies of 6Li-15N labeled lithium hexamethyldisilazide ([6Li,15N]- Li ligand structure and lithium amide aggregation state is a complex and sensitive function of amine alkyl

  20. University Bookstore University Art Store

    E-Print Network [OSTI]

    Sorin, Eric J.

    & Pub* Nugget Express* Squeeze Me Starbucks* The Outpost Grill* University Student Union Carl's Jr El Ground Floor Coffee House Central Park Coffee House University Library Starbucks* DINING www

  1. Polarization and Pressure-Dependence of 2p-1s Transitions in He-Like and Li-Like Neon Recoil Ions 

    E-Print Network [OSTI]

    Watson, R. L.; Palinkas, J.; Pedrazzini, G. J.; Bandong, B.; Can, C.; Church, David A.; Kenefick, R. A.

    1987-01-01

    VOLUME 35, NUMBER 4 FEBRUARY 15, 1987 Polarization and pressure dependence of 2p-1s transitions in He-like and Li-like neon recoil ions R. L. Watson, J. Palinkas, * G. J. Pedrazzini, B. Bandong, and C. Can Cyclotron Institute and Department... of Chemistry, Texas A&M University, College Station, Texas 77843 D. A. Church and R. A. Kenefick Department of Physics, Texas A&M University, College Station, Texas 77843 (Received 1 August 1986) The pressure dependences of 2p-1s transitions in H~- like...

  2. Performance of LiAlloy/Ag(2)CrO(4) Couples in Molten CsBr-LiBr-KBr Eutectic

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    1999-10-18

    The performance of Li-alloy/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} systems was studied over a temperature range of 250 C to 300 C, for possible use as a power source for geothermal borehole applications. Single cells were discharged at current densities of 15.8 and 32.6 mA/cm{sup 2} using Li-Si and Li-Al anodes. When tested in 5-cell batteries, the Li-Si/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} system exhibited thermal runaway. Thermal analytical tests showed that the Ag{sub 2}CrO{sub 4} cathode reacted exothermically with the electrolyte on activation. Consequently, this system would not be practical for the envisioned geothermal borehole applications.

  3. LiU E-Press Newsletter Spring, 2008

    E-Print Network [OSTI]

    Zhao, Yuxiao

    LiU E-Press Newsletter Spring, 2008 http://www.ep.liu.se/ Publication Database Joins E-Press to spread the results is via electronic publishing at E- Press. Ideally, full articles are published, but power-point presentations are also possible. Beyond basic publish- ing, E-Press also offers our article

  4. Solar Photovoltaic Capacity F t P f d P li

    E-Print Network [OSTI]

    6/19/2013 1 Solar Photovoltaic ­ Capacity F t P f d P li Generating Resources Advisory Committee Advisor Model (SAM), version 2013.1.15 Technology: Solar PV (PVWatts system model)Technology: Solar PV (MWh) (First year output, each year thereafter degrades 0.5%) 6 #12;6/19/2013 4 Shape of PNW Solar PV

  5. LICOR LI-6400 STANDARD OPERATING PROCEDURE -FIELD SOIL RESPIRATION MEAUSUREMENTS

    E-Print Network [OSTI]

    Barger, Nichole

    ) Field LiCor kit with spares and tools 8) Trash bags to cover the licor in case of rain 9) soil Measurements Set the Licor near the spot to be measured Set or check that the stop collar on the soil chamber head is in the right location so that the insertion depth is correct (likely use 2cm unless

  6. Water at biomolecular binding interfaces Zheng Li and Themis Lazaridis*

    E-Print Network [OSTI]

    Lazaridis, Themis

    Water at biomolecular binding interfaces Zheng Li and Themis Lazaridis* Received 29th August 2006.1039/b612449f Water molecules are often found at the binding interface of biomolecular complexes Waals interactions. Recent studies have demonstrated the importance of taking such water molecules

  7. New Modeling Tools for Energy Markets Chung-Li Tseng

    E-Print Network [OSTI]

    Tseng, Chung-Li

    EDITORIAL New Modeling Tools for Energy Markets Chung-Li Tseng Special Editor The electricity crisis, the Great Blackout in the East Coast, and the FERC's Standard Market Design clearly indicate the challenges and complexity embedded by this industrial restructuring, demanding new mod- eling tools

  8. High Capacity Graphite Anodes for Li-Ion battery applications

    E-Print Network [OSTI]

    Popov, Branko N.

    High Capacity Graphite Anodes for Li-Ion battery applications using Tin microencapsulation Basker range 1.6V to 0.01V at 0.05 mV/s Physical characterization SEM, EDAX and XRD #12;SEM images of Bare

  9. Anode Materials for Rechargeable Li-Ion Batteries

    SciTech Connect (OSTI)

    Fultz, B.

    2001-01-12

    This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. At present, our experimental work involves only materials for Li storage, but we have been writing papers from our previous work on hydrogen-storage materials.

  10. Honorary Doctor of Social Science Mr LI Ka-shing

    E-Print Network [OSTI]

    Po, Lai-Man

    . However, we appreciate more his outlook on life. He once said, "We are all climbing the same mountain in this world." Mr Li's philosophy is his greatest capital for successful business ventures. Seventy years ago Island, thus beginning his illustrious career in the business world. In 1957, accurately foreseeing

  11. Polymer geometry and Li+ conduction in poly(ethylene oxide)

    E-Print Network [OSTI]

    Averbuch, Amir

    Polymer geometry and Li+ conduction in poly(ethylene oxide) L. Gitelman a , M. Israeli b, , A: Lithium battery Polymer molecule Brownian motion Simulation Conductivity PEO a b s t r a c t We study of the amorphous PE structure is increased by mechanical stretching due to the unraveling of loops in the polymer

  12. Synthesis, characterization and electrochemical performance of Al-substituted Li?MnO?

    SciTech Connect (OSTI)

    Dhital, Chetan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Huq, Ashfia [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Paranthaman, Mariappan Parans [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Manivannan, Ayyakkannu [National Energy Technology Lab. (NETL), Morgantown, WV (United States); West Virginia Univ., Morgantown, WV (United States); Torres-Castro, Loraine [Univ. of Puerto Rico, San Juan (Puerto Rico); Shojan, Jifi [Univ. of Puerto Rico, San Juan (Puerto Rico); Julien, Christian M. [Univ. Pierre et Marie Curie, Paris (France); Katiyar, Ram S. [Univ. of Puerto Rico, San Juan (Puerto Rico)

    2015-01-01

    Li?MnO? is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li?MnO?, Li1.5Al0.17MnO?, Li1.0Al0.33MnO? and Li0.5Al0.5MnO? were synthesized by a sol-gel Pechini method. All the samples were characterized with XRD, Raman, XPS, SEM, Tap density and BET analyzer. XRD patterns indicated the presence of monoclinic phase for pristine Li?MnO? and mixed monoclinic/spinel phases (Li2-xMn1-yAlx+yO3+z) for Al-substituted Li?MnO? compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. XPS analysis for Mn 2p orbital reveal a significant decrease in binding energy for Li1.0Al0.33MnO? and Li0.5Al0.5MnO? compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g?¹ for Li?MnO?, 68mAh g?¹ for Li1.5Al0.17MnO?, 58 mAh g?¹ for Li1.0Al0.33MnO? and 74 mAh g?¹ for Li0.5Al0.5MnO? were obtained. Aluminum substitutions increased the discharge capacity and the spinel phase.

  13. Synthesis, characterization and electrochemical performance of Al-substituted Li?MnO?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dhital, Chetan; Huq, Ashfia; Paranthaman, Mariappan Parans; Manivannan, Ayyakkannu; Torres-Castro, Loraine; Shojan, Jifi; Julien, Christian M.; Katiyar, Ram S.

    2015-08-08

    Li2MnO3 is known to be electrochemically inactive due to Mn in tetravalent oxidation state. Several compositions such as Li2MnO3 , Li1.5Al0.17MnO3, Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 were synthesized by a sol–gel Pechini method. All the samples were characterized with x-ray diffraction, Raman, x-ray photoelectron spectroscopy, scanning electron microscopy, Tap density and BET analyzer. X-ray diffraction patterns indicated the presence of monoclinic phase for pristine Li2MnO3and mixed monoclinic/spinel phases (Li2 - xMn1 - yAlx + yO3 + z) for Al-substituted Li2MnO3compounds. The Al substitution seems to occur both at Li and Mn sites, which could explain the presence of spinel phase. X-ray photoelectronmore »spectroscopy for Mn 2p orbital reveals a significant decrease in binding energy for Li1.0Al0.33MnO3 and Li0.5Al0.5MnO3 compounds. Cyclic voltammetry, charge/discharge cycles and electrochemical impedance spectroscopy were also performed. A discharge capacity of 24 mAh g-1 for Li2MnO3, 68 mAh g-1 for Li1.5Al0.17MnO3, 58 mAh g-1 for Li1.0Al0.33MnO3 and 74 mAh g-1 for Li0.5Al0.5MnO3 were obtained. Aluminum substitutions increased the formation of spinel phase which is responsible for cycling.« less

  14. This article was downloaded by: [KU Leuven University Library] On: 30 July 2014, At: 04:25

    E-Print Network [OSTI]

    be independently verified with primary sources of information. Taylor and #12;Francis shall not be liable for anyThis article was downloaded by: [KU Leuven University Library] On: 30 July 2014, At: 04://www.tandfonline.com/page/terms-and- conditions Downloadedby[KULeuvenUniversityLibrary]at04:2530July2014 #12;Baibing Li 2nd Bart De Moor Kcy !~t

  15. Electromagnetic Dipole Response as a Test of the $^{\\bf 11}$Li g.s. Structure and the n-$^{\\bf 9}$Li Interaction

    E-Print Network [OSTI]

    B. V. Danilin; M. V. Zhukov; J. S. Vaagen; I. J. Thompson; J. M. Bang

    1993-04-23

    The electric dipole response of the halo nucleus $^{11}$Li is calculated in a hyperspherical three-body formulation, and is studied as a function of the interaction employed for $n-^9$Li to reflect the Pauli principle. Strength concentrations at lower energies are found but no narrow resonances. Only one possible scenario of $^{11}$Li structure is in close correspondence with MSU and RIKEN experimental data.

  16. Method for treating electrolyte to remove Li{sub 2}O

    DOE Patents [OSTI]

    Tomczuk, Z.; Miller, W.E.; Johnson, G.K.; Willit, J.L.

    1998-01-20

    A method is described for removing Li{sub 2}O present in an electrolyte predominantly of LiCl and KCl. The electrolyte is heated to a temperature not less than about 500 C and then Al is introduced into the electrolyte in an amount in excess of the stoichiometric amount needed to convert the Li{sub 2}O to a Li-Al alloy and lithium aluminate salt. The salt and aluminum are maintained in contact with agitation for a time sufficient to convert the Li{sub 2}O.

  17. Structural Underpinnings of the Enhanced Cycling Stability upon Al-Substitution in LiNi0.45Mn0.45Co0.1-yAlyO2 Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas E.

    2013-01-01

    materials for Li-ion batteries Thomas E. Conry, a,b Apurvamaterials in Li-ion batteries. Synchrotron-based high-materials for Li-ion batteries. LiNi z Mn z Co 1-2z O 2 (NMC

  18. UNIVERSITY OF ABERDEEN UNIVERSITY COURT

    E-Print Network [OSTI]

    Neri, Peter

    application for the refurbishment had been submitted to Aberdeen City Council. The University had also signed

  19. Magnetism reflectometer study shows LiF layers improve efficiency in spin valve devices

    SciTech Connect (OSTI)

    Bardoel, Agatha A [ORNL; Lauter, Valeria [ORNL; Szulczewski, Greg J [ORNL

    2012-01-01

    New, more efficient materials for spin valves - a device used in magnetic sensors, random access memories, and hard disk drives - may be on the way based on research using the magnetism reflectometer at Oak Ridge National Laboratory (ORNL). Spin valve devices work by means of two or more conducting magnetic material layers that alternate their electrical resistance depending on the layers alignment. Giant magnetoresistance is a quantum mechanical effect first observed in thin film structures about 20 years ago. The effect is observed as a significant change in electrical resistance, depending on whether the magnetization of adjacent ferromagnetic layers is in a parallel or an antiparallel magnetic alignment. 'What we are doing here is developing new materials. The search for new materials suitable for injecting and transferring carriers with a preferential spin orientation is most important for the development of spintronics,' said Valeria Lauter, lead instrument scientist on the magnetism reflectometer at the Spallation Neutron Source (SNS), who collaborated on the experiment. The researchers discovered that the conductivity of such materials is improved when an organic polymer semiconductor layer is placed between the magnetic materials. Organic semiconductors are now the material of choice for future spin valve devices because they preserve spin coherence over longer times and distances than conventional semiconductors. While research into spin valves has been ongoing, research into organic semiconductors is recent. Previous research has shown that a 'conductivity mismatch' exists in spin valve systems in which ferromagnetic metal electrodes interface with such organic semiconductors as Alq3 ({pi}-conjugated molecule tris(8-hydroxy-quinoline) aluminium). This mismatch limits the efficient injection of the electrons from the electrodes at the interface with the semiconductor material. However, lithium fluoride (LiF), commonly used in light-emitting diodes, has been found to enhance the injection of electrons through the semiconductor. Researchers from the University of Alabama and ORNL used polarized neutrons at the magnetism reflectometer at SNS to investigate the electronic, magnetic, and structural properties of the electrodes in a novel system. In this system, the magnetic layers cobalt and Ni{sub 80}Fe{sub 20} are interfaced with spacer layers composed of the organic semiconductor Alq3. A coupling layer of LiF is inserted to separate the magnetized layers from the semiconductor. 'ALQ3 is an organic semiconductor material,' said Lauter. 'Normally in these systems a first magnetic layer is grown on a hard substrate so that one can get the controlled magnetic parameters. Then you grow the organic semiconductor layer, followed by another magnetic material layer, such as cobalt.' In addition to determining the effect of the LiF layers on the efficiency of the electron injection, the researchers wanted to determine the magnetic properties of the cobalt and Ni{sub 80}Fe{sub 20} as well as the interfacial properties: whether there is interdiffusion of cobalt through the LiF layer to the semiconductor, for example. The researchers used polarized neutrons at beam line 4A to probe the entire, layer-by-layer assembly of the system. 'Reflectometry with polarized neutrons is a perfect method to study thin magnetic films,' Lauter said. 'These thin films - if you put one on a substrate, you see it just like a mirror. However, this mirror has a very complicated internal multilayer structure. The neutrons look inside this complicated structure and characterize each and every interface. Due to the depth sensitivity of the method, we measure the structural and magnetic properties of each layer with the resolution of 0.5 nm. The neutron scattering results found that inserting LiF as a barrier significantly improves the quality of the interface, increasing the injection of electrons from the magnetic layer through the organic semiconductor in the spin valve and enhancing the overall properties of the system. In related work the magneti

  20. Maximum Li storage in Si nanowires for the high capacity three-dimensional Li-ion battery

    E-Print Network [OSTI]

    Jo, Moon-Ho

    , such as fuel cells and secondary batteries. Here we report a coin-type Si nanowire NW half-cell Li-ion battery is the central research subject in various energy conversion systems, such as solar cells, fuel cells must be optimally coordinated.7 In this respect, Si nanowire NW arrays can serve as the high capacity

  1. mRNA Transcript Abundance during Plant Growth and the Influence of Li+ Exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duff, M. C.; Kuhne, W. W.; Halverson, N. V.; Chang, C. -S.; Kitamura, E.; Hawthorn, L.; Martinez, N. E.; Stafford, C.; Milliken, C. E.; Caldwell, E. F.; et al

    2014-10-23

    Lithium (Li) toxicity in plants is, at a minimum, a function of Li+ concentration, exposure time, species and growth conditions. Most plant studies with Li+ focus on short-term acute exposures. This study examines short- and long-term effects of Li+ exposure in Arabidopsis with Li+ uptake studies and measured shoot mRNA transcript abundance levels in treated and control plants. Stress, pathogen-response and arabinogalactan protein genes were typically more up-regulated in older (chronic, low level) Li+-treatment plants and in the much younger plants from acute high-level exposures. The gene regulation behavior of high-level Li+ resembled prior studies due to its influence on:more »inositol synthesis, 1-aminocyclopropane-1-carboxylate synthases and membrane ion transport. In contrast, chronically-exposed plants had gene regulation responses that were indicative of pathogen, cold, and heavy-metal stress, cell wall degradation, ethylene production, signal transduction, and calcium-release modulation. Acute Li+ exposure phenocopies magnesium-deficiency symptoms and is associated with elevated expression of stress response genes that could lead to consumption of metabolic and transcriptional energy reserves and the dedication of more resources to cell development. In contrast, chronic Li+ exposure increases expression signal transduction genes. The identification of new Li+-sensitive genes and a gene-based “response plan” for acute and chronic Li+ exposure are delineated.« less

  2. mRNA Transcript Abundance during Plant Growth and the Influence of Li+ Exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duff, M. C. [Savannah River National Laboratory, Aiken, SC (United States); Kuhne, W. W. [Savannah River National Laboratory, Aiken, SC (United States); Halverson, N. [Savannah River National Laboratory, Aiken, SC (United States); Chang, C. -S. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Kitamura, E. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Hawthorn, L. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Milliken, C. E. [Savannah River National Laboratory, Aiken, SC (United States); Caldwell, E. F. [Savannah River National Laboratory, Aiken, SC (United States); Stieve-Caldwell, E. [Savannah River National Laboratory, Aiken, SC (United States); Martinez, N. E. [Savannah River National Laboratory, Aiken, SC (United States); Colorado State University, Ft. Collins, CO (United States). Dept. of Environmental and Radiological Health Sciences; Stafford, C. [Savannah River National Laboratory, Aiken, SC (United States); Univ. of South Carolina Medical School, Columbia, SC (United States)

    2014-12-01

    Lithium (Li) toxicity in plants is, at a minimum, a function of Li+ concentration, exposure time, species and growth conditions. Most plant studies with Li+ focus on short-term acute exposures. This study examines short- and long-term effects of Li+ exposure in Arabidopsis with Li+ uptake studies and measured shoot mRNA transcript abundance levels in treated and control plants. Stress, pathogen-response and arabinogalactan protein genes were typically more up-regulated in older (chronic, low level) Li+-treatment plants and in the much younger plants from acute high-level exposures. The gene regulation behavior of high-level Li+ resembled prior studies due to its influence on: inositol synthesis, 1-aminocyclopropane-1-carboxylate synthases and membrane ion transport. In contrast, chronically-exposed plants had gene regulation responses that were indicative of pathogen, cold, and heavy-metal stress, cell wall degradation, ethylene production, signal transduction, and calcium-release modulation. Acute Li+ exposure phenocopies magnesium-deficiency symptoms and is associated with elevated expression of stress response genes that could lead to consumption of metabolic and transcriptional energy reserves and the dedication of more resources to cell development. In contrast, chronic Li+ exposure increases expression signal transduction genes. The identification of new Li+-sensitive genes and a gene-based “response plan” for acute and chronic Li+ exposure are delineated.

  3. Effect of LiAlO{sub 2} nanoparticle filler concentration on the electrical properties of PEO–LiClO{sub 4} composite

    SciTech Connect (OSTI)

    Masoud, E.M.; El-Bellihi, A.-A.; Bayoumy, W.A.; Mousa, M.A.

    2013-03-15

    Highlights: ? Structural modification of nano LiAlO{sub 2} filler increased conductivity. ? Good ionic conductivity for (LiAlO{sub 2}){sub 1.5}(PEO){sub 11}(LiClO{sub 4}) at room temperature. ? Nano LiAlO{sub 2} filler enhanced both ion migration and orientation. ? High dielectric properties for (LiAlO{sub 2}){sub 1.5}(PEO){sub 11}(LiClO{sub 4}) at room temperature. - Abstract: Nano-composite polymer electrolytes are receiving attention as potential candidates to be used as electrolyte membranes in lithium polymer batteries and other devices. In this work, polyethylene oxide–LiClO{sub 4} based composite polymer electrolyte was prepared by solution casting method. The effect of LiAlO{sub 2} nanoparticle ceramic filler concentration on the structure and electrical conduction of the composite was studied. Nano-LiAlO{sub 2} was synthesized by sol–gel method. The samples were characterized using X-ray diffraction, Fourier Transmission-Infra Red, Differential Scanning Calorimetry, and tested by dielectric properties, Direct and Alternating current measurements as well as by impedance spectroscopy. All samples showed a behavior referring to an ionic conduction. Generally, the melting temperature of the polymer electrolyte decreased with filler concentration. Both thermal property and filler concentration influenced conductivity value. At room temperature, the highest ionic conductivity was 9.76 × 10{sup ?5} ohm{sup ?1} cm{sup ?1} for sample with a composition of (LiAlO{sub 2}){sub 1.5}(polyethylene oxide){sub 11}(LiClO{sub 4}). All results were correlated and discussed.

  4. Fractal universe

    E-Print Network [OSTI]

    D. L. Khokhlov

    1999-01-15

    The model of the universe is considered in which background of the universe is not defined by the matter but is a priori specified as a homogenous and isotropic flat space. The scale factor of the universe follows the linear law. The scale of mass changes proportional to the scale factor. This leads to that the universe has the fractal structure with a power index of 2.

  5. PHILADELPHIA UNIVERSITY -1 1989

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY :: -1 1989 . . . -2 . . 3- : #12;PHILADELPHIA UNIVERSITY . (132) . #12;PHILADELPHIA UNIVERSITY

  6. Big Bang nucleosynthesis in scalar tensor gravity: the key problem of the $^7$Li abundance

    E-Print Network [OSTI]

    Julien Larena; Jean-Michel Alimi; Arturo Serna

    2006-11-20

    Combined with other CMB experiments, the WMAP survey provides an accurate estimate of the baryon density of the Universe. In the framework of the standard Big Bang Nucleosynthesis (BBN), such a baryon density leads to predictions for the primordial abundances of $^{4}$He and D in good agreement with observations. However, it also leads to a significant discrepancy between the predicted and observed primordial abundance of $^{7}$Li. Such a discrepancy is often termed as 'the lithium problem'. In this paper, we analyze this problem in the framework of scalar-tensor theories of gravity. It is shown that an expansion of the Universe slightly slower than in General Relativity before BBN, but faster during BBN, solves the lithium problem and leads to $^4$He and D primordial abundances consistent with the observational constraints. This kind of behavior is obtained in numerous scalar-tensor models, both with and without a self-interaction potential for the scalar field. In models with a self-interacting scalar field, the convergence towards General Relativity is ensured without any condition, thanks to an attraction mechanism which starts to work during the radiation-dominated epoch.

  7. New Mexico State University University Accounts Receivable

    E-Print Network [OSTI]

    Johnson, Eric E.

    New Mexico State University University Accounts Receivable Petty Cash Reconciliation - Instructions, should be kept on file within the department. #12;New Mexico State University University Accounts

  8. Theoretical exploration of various lithium peroxide crystal structures in a Li-air battery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lau, Kah; Qiu, Dantong; Luo, Xiangyi; Greeley, Jeffrey; Curtiss, Larry; Lu, Jun; Amine, Khalil

    2015-01-14

    We describe a series of metastable Li?O? crystal structures involving different orientations and displacements of the O?²? peroxy ions based on the known Li?O? crystal structure. Within the vicinity of the chemical potential ?G ~ 0.20 eV/Li from the thermodynamic ground state of the Li?O? crystal structure (i.e., Föppl structure), all of these newly found metastable Li?O? crystal structures are found to be insulating and high-k materials, and they have a common unique signature of an O?²? O-O vibration mode (? ~ 799–865 cm?¹), which is in the range of that commonly observed in Li-air battery experiments, regardless of themore »random O?²? orientations and the symmetry in the crystal lattice. From XRD patterns analysis, the commercially available Li?O? powder is confirmed to be the thermodynamic ground state Föppl-like structure. However, for Li?O? compounds that are grown electrochemically under the environment of Li-O? cells, we found that the XRD patterns alone are not sufficient for structural identification of these metastable Li?O? crystalline phases due to the poor crystallinity of the sample. In addition, the commonly known Raman signal of O?²? vibration mode is also found to be insufficient to validate the possible existence of these newly predicted Li?O? crystal structures, as all of them similarly share the similar O?²? vibration mode. However considering that the discharge voltage in most Li-O? cells are typically several tenths of an eV below the thermodynamic equilibrium for the formation of ground state Föppl structure, the formation of these metastable Li?O? crystal structures appears to be thermodynamically feasible.« less

  9. UNIVERSITY OF ABERDEEN UNIVERSITY COURT

    E-Print Network [OSTI]

    Neri, Peter

    Subsea Research Institute was to be based on the University campus. This was highly significant for the future development of the University's energy-related research and links with the oil and gas subsea

  10. Polymer graphite composite anodes for Li-ion batteries

    E-Print Network [OSTI]

    Popov, Branko N.

    Polymer graphite composite anodes for Li-ion batteries Basker Veeraraghavan, Bala Haran, Ralph analysis #12;TGA analysis of polymer composite SFG10 samples -0.0 150.0 300.0 450.0 600.0 750.0 900-discharge curves of polymer composite SFG10 samples 0 200 400 600 800 Specific Capacity (mAh/g) 0.0 1.0 2.0 3.0 4

  11. Microsoft PowerPoint - ARM2008_Poster_KHLee [Compatibility Mode]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on darkMicroorganisms to SpeedJacksonville, IllinoisbZhanqing Li

  12. Microsoft PowerPoint - ARM2008_norfolk.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on darkMicroorganisms to SpeedJacksonville, IllinoisbZhanqing Li

  13. Searching for Sustainable and "Greener" Li-ion Batteries

    ScienceCinema (OSTI)

    Tarascon, Jean-Marie [University of Picardie at Aimens, France

    2010-01-08

    Lithium-ion batteries are strong candidates for powering upcoming generations of hybrid electric vehicles and plug-in hybrid electric vehicles. But improvements in safety must be achieved while keeping track of materials resources and abundances, as well as materials synthesis and recycling processes, all of which could inflict a heavy energy cost. Thus, electrode materials that have a minimum footprint in nature and are made via eco-efficient processes are sorely needed. The arrival of electrode materials based on minerals such as LiFePO4 (tryphilite) is a significant, but not sufficient, step toward the long-term demand for materials sustainability. The eco-efficient synthesis of LiFePO4 nanopowders via hydrothermal/ solvo-thermal processes using latent bases, structure directing templates, or other bio-related approaches will be presented in this talk. However, to secure sustainability and greeness, organic electrodes appear to be ideal candidates.... We took a fresh look at organic based electrodes; the results of this research into sequentially metal-organic-framework electrodes and Li-based organic electrodes (LixCyOz) will be reported and discussed.

  14. UCC UNIVERSITIES CLIMATE UNIVERSITY CLIMATE

    E-Print Network [OSTI]

    Kidston, Joseph

    CONSORTIUM UCC UNIVERSITIES CLIMATE UNIVERSITY CLIMATE World-class excellence Internationally recognised Australia based www.monash.edu.au/climate-consortium CONSORTIUM An International Collaborative of the institutional leads within the UCC: The University Climate Consortium (UCC) comprises four research intensive

  15. Analytic potentials and vibrational energies for Li$_{2}$ states dissociating to $\\mbox{Li}\\left(2S\\right)+\\mbox{Li}\\left(3P\\right)$. Part 1: The $^{2S+1}\\Pi_{u/g}$ states

    E-Print Network [OSTI]

    Dattani, Nikesh S

    2015-01-01

    Analytic potentials are built for all four $^{2S+1}\\Pi_{u/g}$ states of Li$_{2}$ dissociating to Li$(2S)$ + Li$(3P)$: $3b(3^{3}\\Pi_{u})$, $3B(3^{1}\\Pi_{u})$, $3C(3^{1}\\Pi_{g}),$ and $3d(3^{3}\\Pi_{g})$. These potentials include the effect of spin-orbit coupling for large internuclear distances, and include state of the art long-range constants. This is the first successful demonstration of fully analytic diatomic potentials that capture features that are usually considered too difficult to capture without a point-wise potential, such as multiple minima, and shelves. Vibrational energies for each potential are presented for the isotopologues $^{6,6}$Li$_{2}$, $^{6,7}$Li$_{2}$, $^{7,7}$Li$_{2}$, and the elusive `halo nucleonic molecule' $^{11,11}$Li$_{2}$. These energies are claimed to be accurate enough for new high-precision experimental setups such as the one presented in {[}Sebastian \\emph{et al.} Phys. Rev. A, \\textbf{90}, 033417 (2014){]} to measure and assign energy levels of these electronic states, all ...

  16. Graphene Modified LiFePO4 Cathode Materials for High Power Lithium ion Batteries

    SciTech Connect (OSTI)

    Zhou, X.; Wang, F.; Zhu, Y.; Liu, Z.

    2011-01-24

    Graphene-modified LiFePO{sub 4} composite has been developed as a Li-ion battery cathode material with excellent high-rate capability and cycling stability. The composite was prepared with LiFePO{sub 4} nanoparticles and graphene oxide nanosheets by spray-drying and annealing processes. The LiFePO{sub 4} primary nanoparticles embedded in micro-sized spherical secondary particles were wrapped homogeneously and loosely with a graphene 3D network. Such a special nanostructure facilitated electron migration throughout the secondary particles, while the presence of abundant voids between the LiFePO{sub 4} nanoparticles and graphene sheets was beneficial for Li{sup +} diffusion. The composite cathode material could deliver a capacity of 70 mAh g{sup -1} at 60C discharge rate and showed a capacity decay rate of <15% when cycled under 10C charging and 20C discharging for 1000 times.

  17. Traka yon kretyen pandan vwayaj li : adaptasyon liv “Pilgrim’s Progress" / John Bunyan

    E-Print Network [OSTI]

    Paultre, Carrie?; Bunyan, John; Ross, Jim D.; Freeman, Bryant C.

    2000-01-01

    konmanse pfcdi tbt li. K6m li te fin aswe, yo fe 1 ale kouche nan kabann li, paske yo konprann yon bon ti domi ta mete lespri 1 anplas. Men nwit la te move tankou jounen an. Li te si eksite, li pa t kapab jwenn som£y. Li pase tout nwit la ap plede... kite zanmi nou 8 yo, kalite bon jan van ki gen isit la?» Kretyen menm reponn yo: «Se sa menm mwen di nou pou nou fe. Zanmi ak plezi pa kapab vin we devan sa m ap chache a. Paske kote m prale a, se la ki gen tout bon bagay. Vin non n a we si sa m...

  18. Crystal structure and chemical bonding of novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16}

    SciTech Connect (OSTI)

    Jung, Yaho; Nam, Gnu; Jeon, Jieun; Kim, Youngjo; You, Tae-Soo

    2012-12-15

    A novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16} has been synthesized using the high-temperature reaction method and characterized by both powder and single-crystal X-ray diffractions. The title compound crystallized in the orthorhombic crystal system (space group Immm, Z=2, Pearson symbol oI78) with fifteen crystallographically unique atomic positions in the asymmetric unit, and the lattice parameters are refined as a=4.5244(4) A, b=6.9932(6) A, and c=53.043(5) A. The complex crystal structure of the title compound can be described as a 2:1 intergrowth of two closely related compounds: La{sub 2}Li{sub 2}Ge{sub 3} (Ce{sub 2}Li{sub 2}Ge{sub 3}-type) and La{sub 3}Li{sub 4}Ge{sub 4} (Zr{sub 3}Cu{sub 4}Si{sub 4}-type) acting like 'building-blocks' along the c-axis. Six La sites are categorized into three distinct types based on the local coordination environment showing the coordination numbers of 12-14. Three unique Li sites are placed in the centers of local tetrahedra formed by four Ge atoms which eventually construct Ge{sub 2} dimers or 1-dimensional cis-/trans-Ge chains. Theoretical investigations using the tight-binding linear muffin-tin orbital (LMTO) method provide rationales for an improved structural stability and for unique local coordination geometries established by anionic elements including [LiGe{sub 4}] tetrahedra, cis-/trans-Ge chain and Ge{sub 2} dimers. - Graphical abstract: Reported is a novel ternary Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16}. The complex crystal structure can be viewed as a simple combination of two closely related known compounds acting as 'building-blocks', La{sub 2}Li{sub 2}G{sub 3} and La{sub 3}Li{sub 4}Ge{sub 4}, in a 2:1 stoichiometric ratio. Highlights: Black-Right-Pointing-Pointer A novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16} was synthesized. Black-Right-Pointing-Pointer The complex crystal structure was easily explained as a combination of two known compounds. Black-Right-Pointing-Pointer Theoretical calculations indicated that the Fermi level was located near the pseudogap.

  19. Paul Edward Smith Department of Biochemistry, 36 Willard Hall, Kansas State University

    E-Print Network [OSTI]

    Smith, Paul E.

    . Protein Modeling and Engineering BIOCH 890 - Fall 98. Biochemistry I BIOCH 755 - Fall 98. Sophomore - M.Sc., Chemical Engineering Li Zheng - Ph.D., Biochemistry Maria Zavodszky - Ph.D., BiochemistryPaul Edward Smith Department of Biochemistry, 36 Willard Hall, Kansas State University Manhattan

  20. University of California, San Diego UCSD-ENG-107 Fusion Division

    E-Print Network [OSTI]

    Raffray, A. René

    geometry to flow the liquid metal coolant parallel to the magnetic field in the high heat flux region of vaporization of Li and requiring lower flow rates could operate without insulator in the high heat flux region University of California, San Diego La Jolla, CA 92093-0417 Advanced Heat Sink Material for Fusion Energy

  1. Facile synthesis of nanostructured vanadium oxide as cathode materials for efficient Li-ion batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    -ion batteries Yanyi Liu,a Evan Uchaker,a Nan Zhou,ab Jiangang Li,ac Qifeng Zhanga and Guozhong Cao*a Received 23 and VO2 (B) nanorods were tested as active cathode materials for Li-ion batteries. The V2O5 sheet for efficient Li-ion batteries. Introduction The expansion and demands for energy use in the past several

  2. Electrochemical performance of Sol-Gel synthesized LiFePO4 in lithium batteries

    E-Print Network [OSTI]

    Hu, Yaoqin; Doeff, Marca M.; Kostecki, Robert; Finones, Rita

    2003-01-01

    LiFePO 4 in Lithium Batteries Yaoqin Hu,* Marca M. Doeff,*material in lithium ion batteries based on environmental and

  3. Chemical and Electrochemical Lithiation of LiVOPO4 Cathodes for Lithium-ion Batteries

    SciTech Connect (OSTI)

    Harrison, Katharine L; Bridges, Craig A; Segre, C; VernadoJr, C Daniel; Applestone, Danielle; Bielawski, Christopher W; Paranthaman, Mariappan Parans; Manthiram, Arumugam

    2014-01-01

    The theoretical capacity of LiVOPO4 could be increased from 159 to 318 mAh/g with the insertion of a second Li+ ion into the lattice to form Li2VOPO4, significantly enhancing the energy density of lithium-ion batteries. The changes accompanying the second Li+ insertion into -LiVOPO4 and -LiVOPO4 are presented here at various degrees of lithiation, employing both electrochemical and chemical lithiation. Inductively coupled plasma, X-ray absorption spectroscopy, and Fourier transform spectroscopy measurements indicate that a composition of Li2VOPO4 could be realized with an oxidation state of V3+ by the chemical lithiation process. The accompanying structural changes are evidenced by X-ray and neutron powder diffraction. Spectroscopic and diffraction data collected with the chemically lithiated samples as well as diffraction data on the electrochemically lithiated samples reveal that significant amount of lithium can be inserted into -LiVOPO4 before a more dramatic structural change occurs. In contrast, lithiation of -LiVOPO4 is more consistent with the formation of a two-phase mixture throughout most of the lithiation range. The phases observed with the ambient-temperature lithiation processes presented here are significantly different from those reported in the literature.

  4. Miniature all-solid-state heterostructure nanowire Li-ion batteries...

    Office of Scientific and Technical Information (OSTI)

    all-solid-state heterostructure nanowire Li-ion batteries as a tool for engineering and structural diagnostics of nanoscale electrochemical processes Citation Details In-Document...

  5. Miniature All-solid-state Heterostructure Nanowire Li-ion Batteries...

    Office of Scientific and Technical Information (OSTI)

    All-solid-state Heterostructure Nanowire Li-ion Batteries as a Toll for Engineering and Structural Diagnostics of Nanoscale Electrochemical Processes Citation Details In-Document...

  6. Microsoft Word - RM1_Tidal Turbine_NREL Lawson, Li Y, Sale_2011...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Address all correspondence to this author. Michael J. Lawson National Renewable Energy Laboratory National Wind Technology Center Ye Li National Renewable Energy...

  7. Enhanced Electrochemical Lithium Storage Activity of LiCrO2 by Size Effect

    SciTech Connect (OSTI)

    Feng, G.; Li, L; Liu, J; Liu, N; Li, H; Yang, X; Huang, X; Chen, L; Nam, K; Yoon, W

    2009-01-01

    Cr8O21 was chemically lithiated using a lithium-biphenyl-dimethoxyethane solution. Lithiated Cr8O21 shows a structure in which as-formed LiCrO2 units are sandwiched between Cr2O3 superlattice layers. Chemically lithiated Cr8O21 shows a delithiation capacity of 200 mAh g-1. It means that LiCrO2 units in lithiated Cr8O21 are electrochemically active. This finding is opposite to previous reports that LiCrO2 materials have very poor Li-storage capacities. Our new result implies that LiCrO2 with extremely small domain size could show enhanced reactivity. This proposal is proved unambiguously by the fact that LiCrO2 powder materials with smaller grain size (<20 nm) show much higher capacities than LiCrO2 materials with larger grain size (>50 nm). In addition, it is found that the cation mixing is more significantly in LiCrO2 materials with smaller grain size, which seems a key factor for the storage and transport of lithium in layered Cr-based materials. The cation mixing may also explain the result that the lattice parameters of LiCrO2 do not change significantly upon lithium extraction and insertion, investigated by in situ and ex situ XRD techniques.

  8. Factors Influencing the Quality of Carbon Coatings on LiFePO4

    E-Print Network [OSTI]

    Wilcox, James D.; Doeff, Marca M.; Marcinek, Marek; Kostecki, Robert

    2006-01-01

    2 H 3 O 2 Li•2H 2 O (lithium acetate, Sigma Aldrich), and HThe iron nitrate and lithium acetate were combined with the

  9. Analysis of Heat Dissipation in Li-Ion Cells & Modules for Modeling of Thermal Runaway (Presentation)

    SciTech Connect (OSTI)

    Kim, G.-H.; Pesaran, A.

    2007-05-15

    The objectives of this study are: (1) To develop 3D Li-Ion battery thermal abuse ''reaction'' models for cell and module analysis; (2) To understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-Ion cells and modules; (3) To develop a tool and methodology to support the design of abuse-tolerant Li-Ion battery systems for PHEVs/HEVs; and (4) To help battery developers accelerate delivery of abuse-tolerant Li-Ion battery systems in support of the FreedomCAR's Energy Storage Program.

  10. Development of Cell/Pack Level Models for Automotive Li-Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with Experimental Validation Development of CellPack Level Models for Automotive Li-Ion Batteries with Experimental Validation 2012 DOE Hydrogen and Fuel Cells Program and...

  11. Platforms and Methods for In Situ Characterization of Li-ion...

    Office of Scientific and Technical Information (OSTI)

    Platforms and Methods for In Situ Characterization of Li-ion Battery Materials. Citation Details In-Document Search Title: Platforms and Methods for In Situ Characterization of...

  12. Machian Universe

    E-Print Network [OSTI]

    Burra G. Sidharth

    2006-10-26

    We give arguments from the point of view of Gravitation as well as Electromagnetism which indicate a Machian view for the universe.

  13. First-Principles Study of Novel Conversion Reactions for High-Capacity Li-Ion Battery Anodes in the Li-Mg-B-N-H System

    SciTech Connect (OSTI)

    Mason, T.H.; Graetz, J.; Liu, X.; Hong, J.; Majzoub, E.H.

    2011-07-28

    Anodes for Li-ion batteries are primarily carbon-based due to their low cost and long cycle life. However, improvements to the Li capacity of carbon anodes, LiC{sub 6} in particular, are necessary to obtain a larger energy density. State-of-the-art light-metal hydrides for hydrogen storage applications often contain Li and involve reactions requiring Li transport, and light-metal ionic hydrides are candidates for novel conversion materials. Given a set of known solid-state and gas-phase reactants, we have determined the phase diagram in the Li-Mg-B-N-H system in the grand canonical ensemble, as a function of lithium chemical potential. We present computational results for several new conversion reactions with capacities between 2400 and 4000 mAh g{sup -1} that are thermodynamically favorable and that do not involve gas evolution. We provide experimental evidence for the reaction pathway on delithiation for the compound Li{sub 4}BN{sub 3}H{sub 10}. While the predicted reactions involve multiple steps, the maximum volume increase for these materials on lithium insertion is significantly smaller than that for Si.

  14. High-energy break-up of 6Li as a tool to study the Big-Bang nucleosynthesis reaction 2H(alpha,gamma)6Li

    E-Print Network [OSTI]

    F. Hammache; M. Heil; S. Typel; D. Galaviz; K. Sümmerer; A. Coc; F. Uhlig; F. Attallah; M. Caamano; D. Cortina; H. Geissel; M. Hellström; N. Iwasa; J. Kiener; P. Koczon; B. Kohlmeyer; P. Mohr; E. Schwab; K. Schwarz; F. Schümann; P. Senger; O. Sorlin; V. Tatischeff; J. P. Thibaud; E. Vangioni; A. Wagner; W. Walus

    2010-11-29

    The recently claimed observations of non-negligible amounts of 6Li in old halo stars have renewed interest in the Big-Bang Nucleosynthesis (BBN) of 6Li. One important ingredient in the predicted BBN abundance of 6Li is the low-energy 2H(alpha,gamma)6Li cross section. Up to now, the only available experimental result for this cross section showed an almost constant astrophysical S-factor below 400 keV, contrary to theoretical expectations. We report on a new measurement of the 2H(alpha,gamma)6Li reaction using the break-up of 6Li at 150 A MeV. Even though we cannot separate experimentally the Coulomb contribution from the nuclear one, we find clear evidence for Coulomb-nuclear interference by analyzing the scattering-angular distributions. This is in-line with our theoretical description which indicates a drop of the S_24-factor at low energies as predicted also by most other models. Consequently, we find even lower upper limits for the calculated primordial 6Li abundance than before.

  15. A new glass-free LTCC microwave ceramic – (1 ? x) Li{sub 2.08}TiO{sub 3} + xLiF

    SciTech Connect (OSTI)

    Bian, Jianjiang, E-mail: jjbian@Shu.Edu.Cn; Ding, Yaomin

    2014-01-01

    Graphical abstract: - Highlights: • Sintering temperature of Li{sub 2}TiO{sub 3} was reduced to 900 °C by doping with LiF and excessive lithium. • A new glass-free LTCC microwave ceramic – (1 ? x) Li{sub 2.08}TiO{sub 3} + xLiF was obtained. • The obtained LTCC material exhibited excellent microwave dielectric properties. - Abstract: The structure and microstructure of the (1 ? x) Li{sub 2.08}TiO{sub 3} + xLiF (0.11 ? x ? 0.14) ceramics were studied by X-ray powder diffraction (XRD), thermal dilatometry and scanning electron microscopy (SEM). The microwave dielectric properties of the ceramics were studied with a network analyzer. All samples exhibited single monoclinic phase. The sintering temperature was successfully reduced to about 900 °C/2 h for the LiF-doped Li{sub 2.08}TiO{sub 3} specimens. The dielectric permittivity slightly decreased, whereas the Q × f value changed little, with the increase in LiF dopant. The temperature coefficient of resonant of frequency (?{sub f}) value changed from positive to negative with increasing x, and a near zero value was obtained at x = 0.13 composition. Optimized microwave dielectric properties with ?{sub r} = ?22.8, Q × f = ?63,000 GHz and ?{sub f} = ?1.0 ppm/°C for x = 0.13 composition sintered at 900 °C/2 h. The XRD and back scattering SEM analysis showed that the ceramic was compatible with Ag powders after sintering at 900 °C/2 h.

  16. Li (Lily) Wang Address: 223 Statistics Building, University of Georgia, Athens, GA 30602-7952

    E-Print Network [OSTI]

    Wang, Lily

    ). A nonparametric analysis on the environmental Kuznets curve. Environmetrics, 22(3), 420­430. [9] Liu, X., Wang, L

  17. Silicon Based Anodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Wang, Wei; Xiao, Jie; Xu, Wu; Graff, Gordon L.; Yang, Zhenguo; Choi, Daiwon; Li, Xiaolin; Wang, Deyu; Liu, Jun

    2012-06-15

    Silicon is environmentally benign and ubiquitous. Because of its high specific capacity, it is considered one of the most promising candidates to replace the conventional graphite negative electrode used in today's Li ion batteries. Silicon has a theoretical specific capacity of nearly 4200 mAh/g (Li21Si5), which is 10 times larger than the specific capacity of graphite (LiC6, 372 mAh/g). However, the high capacity of silicon is associated with huge volume changes (more than 300 percent) when alloyed with lithium, which can cause severe cracking and pulverization of the electrode and lead to significant capacity loss. Significant scientific research has been conducted to circumvent the deterioration of silicon based anode materials during cycling. Various strategies, such as reduction of particle size, generation of active/inactive composites, fabrication of silicon based thin films, use of alternative binders, and the synthesis of 1-D silicon nanostructures have been implemented by a number of research groups. Fundamental mechanistic research has also been performed to better understand the electrochemical lithiation and delithiation process during cycling in terms of crystal structure, phase transitions, morphological changes, and reaction kinetics. Although efforts to date have not attained a commercially viable Si anode, further development is expected to produce anodes with three to five times the capacity of graphite. In this chapter, an overview of research on silicon based anodes used for lithium-ion battery applications will be presented. The overview covers electrochemical alloying of the silicon with lithium, mechanisms responsible for capacity fade, and methodologies adapted to overcome capacity degradation observed during cycling. The recent development of silicon nanowires and nanoparticles with significantly improved electrochemical performance will also be discussed relative to the mechanistic understanding. Finally, future directions on the development of silicon based anodes will be considered.

  18. LiWall Fusion - The New Concept of Magnetic Fusion

    SciTech Connect (OSTI)

    L.E. Zakharov

    2011-01-12

    Utilization of the outstanding abilities of a liquid lithium layer in pumping hydrogen isotopes leads to a new approach to magnetic fusion, called the LiWall Fusion. It relies on innovative plasma regimes with low edge density and high temperature. The approach combines fueling the plasma by neutral injection beams with the best possible elimination of outside neutral gas sources, which cools down the plasma edge. Prevention of cooling the plasma edge suppresses the dominant, temperature gradient related turbulence in the core. Such an approach is much more suitable for controlled fusion than the present practice, relying on high heating power for compensating essentially unlimited turbulent energy losses.

  19. Fatigue crack growth behavior of Al-Li alloy 1441

    SciTech Connect (OSTI)

    Prakash, R.V.; Parida, B.K.

    1995-12-31

    Fatigue crack growth behavior of Al-Li alloy 1441 having a marginally lower lithium content, compared to 80xx and 20xx series Al-Li alloys is presented in this paper. This investigation was conducted on single edge tension--SE(T)--specimens, under constant amplitude as well as under MiniLCA flight spectrum loading with the specific objective of determining the effects of stress ratio, orientation, thickness and cladding. Three thicknesses were considered: 1.2 mm(clad and unclad), 2.0 mm(clad and unclad) and 8.0 mm unclad. Constant amplitude fatigue tests were conducted at stress ratios of {minus}0.3, 0.1 and 0.7. Testing was performed under ambient conditions and along three orientations, namely L-T, T-L and L+45 degrees. Crack growth characteristics of this alloy are compared with that of BS:L73 (2014-T4 equivalent) for assessing the possibility of replacing BS:L73. Significant effect of stress ratio on crack growth rate was observed in all thicknesses. However, in case of 1.2 and 2.0 mm thick sheets, the effect was minimal at intermediate-crack growth regime. The orientation of the specimen does not adversely affect the fatigue crack growth behavior of 8.0 mm and 2.0 mm thick specimens. However, for 1.2 mm unclad sheet crack growth resistance in L-T direction was found to be superior to that along T-L direction. In majority of test cases considered, no significant effect was observed on crack growth rate due to thickness or cladding. Crack growth characteristics of Al-Li alloy 1441 and Al-Cu alloy BS:L73 under constant amplitude as well as MiniLCA spectrum loading are similar in the low and intermediate-crack growth rate regime. Based on these observations, it is felt that this Al-Li alloy has the potential for future aerospace applications.

  20. Beijing ChangLi Union Energy Company | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC Jump to:Greece:Bajo en Carbono,BeWind PowerBeemerBeiyiChangLi

  1. Qiaojia River Power Co Ltd Li County | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg,Energy LLCALLETE Inc dEAPrysmianPvT CapitalCo Ltd Li County

  2. Automotive Li-ion Battery Cooling Requirements | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels Research atDepartmentAuditsDepartment of EnergyConversionLi-ion

  3. Phase Transition and Electrical Properties of Ba0.7Ca0.3TiO3BiFeO3 Ceramics Cai-Xia Li,,

    E-Print Network [OSTI]

    Cao, Wenwu

    Phase Transition and Electrical Properties of Ba0.7Ca0.3TiO3­BiFeO3 Ceramics Cai-Xia Li,,§ Bin Yang, University Park, Pennsylvania 16802 Lead-free piezoelectric ceramics of (1 À x)Ba0.70 Ca0.30TiO3­x BiFeO3 [(1 À x)BCT­xBF, x = 0­0.065] have been prepared and investigated. The ceramics with x 0.06 have

  4. Adaptation of an Electrochemistry-based Li-Ion Battery Model to Account for Deterioration Observed Under Randomized Use

    E-Print Network [OSTI]

    Daigle, Matthew

    Adaptation of an Electrochemistry-based Li-Ion Battery Model to Account for Deterioration Observed). In this paper, we use an electrochemistry-based lithium ion (Li-ion) battery model developed in (Daigle

  5. Operando NMR and XRD study of chemically synthesized LiCx oxidation in a dry room environment

    SciTech Connect (OSTI)

    Sacci, Robert L [ORNL; Gill, Lance W [ORNL; Hagaman, Edward {Ed} W [ORNL; Dudney, Nancy J [ORNL

    2015-01-01

    We test the stability of pre-lithiated graphite anodes for Li-ion batteries in a dry room battery processing room. The reaction between LiCx and laboratory air was followed using operando NMR and x-ray diffraction as these methods are sensitive to change in Li stoichiometry in graphite. There is minimal reactivity between LiC6 and N2, CO2 or O2; however, LiC6 reacts with moisture to form lithium (hydr)oxide. The reaction rate follows zero-order kinetics with respects to intercalated lithium suggesting that lithium transport through the graphite is fast. The reaction mechanism occurs by sequential formation of higher stages LiC12, then LiC18, and then LiC24 as the hydrolysis proceeds to the formation of LixOHy and graphite end products. Slowing down the formation rate of the LixOHy passivation layer stabilizes of the higher stages.

  6. Electrochemical Properties of Li3Fe0.2Mn0.8CO3PO4 as a Li-Ion Battery Cathode

    E-Print Network [OSTI]

    Matts, Ian L.

    Previously conducted high-throughput ab initio calculations have identified carbonophosphates as a new class of polyanion cathode materials. Li3MnCO3PO4 is the most promising candidate due to its high theoretical capacity ...

  7. Investigation of Mechanical Activation on Li-N-H Systems Using 6Li Magic Angle Spinning Nuclear Magnetic Resonance at Ultra-High Field

    SciTech Connect (OSTI)

    Hu, Jian Zhi; Kwak, Ja Hun; Yang, Zhenguo; Osborn, William; Markmaitree, Tippawan; Shaw, Leonard D.

    2008-07-15

    Abstract The significantly enhanced spectral resolution in the 6Li MAS NMR spectra of Li-N-H systems at ultra-high field of 21.1 tesla is exploited, for the first time, to study the detailed electronic and chemical environmental changes associated with mechanical activation of Li-N-H system using high energy balling milling. Complementary to ultra-high field studies, the hydrogen discharge dynamics are investigated using variable temperature in situ 1H MAS NMR at 7.05 tesla field. The significantly enhanced spectral resolution using ultra-high filed of 21.1 tesla was demonstrated along with several major findings related to mechanical activation, including the upfield shift of the resonances in 6Li MAS spectra induced by ball milling, more efficient mechanical activation with ball milling at liquid nitrogen temperature than with ball milling at room temperature, and greatly enhanced hydrogen discharge exhibited by the liquid nitrogen ball milled samples.

  8. PHILADELPHIA UNIVERSITY 1995

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY 1.: 1995 . (95/2002. . 2. : 1. #12;PHILADELPHIA UNIVERSITY . 2) 2005/2006 . #12;PHILADELPHIA UNIVERSITY 2007

  9. Aalborg Universitet Multi-Objective Control of Balancing Systems for Li-Ion Battery Packs

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    in a e-mobility application. Simulation results demonstrate the technical feasibility of this newlyAalborg Universitet Multi-Objective Control of Balancing Systems for Li-Ion Battery Packs Barreras, R. E. (2014). Multi-Objective Control of Balancing Systems for Li-Ion Battery Packs: A paradigm

  10. Simulating a double casting technique using level set method Qiang Du a,*, Dianzhong Li a

    E-Print Network [OSTI]

    Zhang, Pingwen

    Simulating a double casting technique using level set method Qiang Du a,*, Dianzhong Li a , Yiyi Li. It is used here for the ®rst time to track the interface evolution during the process of casting a second in real double casting processes. Ó 2001 Elsevier Science B.V. All rights reserved. Keywords: Level set

  11. Doped LiFePO? cathodes for high power density lithium ion batteries

    E-Print Network [OSTI]

    Bloking, Jason T. (Jason Thompson), 1979-

    2003-01-01

    Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

  12. Prediction of a New Material Lithium Phosphorus Oxynitride Li2PO2N a

    E-Print Network [OSTI]

    Holzwarth, Natalie

    vibration modes and frequencies () · Heats of formation (H) · Energies for ion migration (Em for solid electrolytes and LiPON · Computational methods · Crystal structures and formation energies of Li. Thin film geometry provides poor contact area for high capacity electrodes. 2. Subject to interface

  13. SkypeMorph: Protocol Obfuscation for Tor Bridges Hooman Mohajeri Moghaddam Baiyu Li

    E-Print Network [OSTI]

    Goldberg, Ian

    SkypeMorph: Protocol Obfuscation for Tor Bridges Hooman Mohajeri Moghaddam Baiyu Li Mohammad {hmohajer,b5li,mderakhs,iang}@cs.uwaterloo.ca ABSTRACT The Tor network is designed to provide users with low- latency anonymous communications. Tor clients build cir- cuits with publicly listed relays to anonymously

  14. Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries

    E-Print Network [OSTI]

    Schmidt, Volker

    Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries Ralf August 30, 2010 Abstract Battery technology plays an important role in energy storage. In particular, lithium­ ion (Li-ion) batteries are of great interest, because of their high capacity, long cycle life

  15. Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries

    E-Print Network [OSTI]

    Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries Dmitry Ruzmetov, all-solid-state Li ion batteries (LIBs) with high specific capacity and small footprint are highly, into the nanometer regime, can lead to rapid self-discharge of the battery even when the electrolyte layer

  16. Adsorption and Diffusion of Lithium on Layered Silicon for Li-Ion Georgios A. Tritsaris,,

    E-Print Network [OSTI]

    -dimensional silicon in the form of silicene layers for Li-ion storage. KEYWORDS: Lithium-ion battery, energy storage batteries constitute a promising energy storage technology suitable for portable and grid applicationsAdsorption and Diffusion of Lithium on Layered Silicon for Li-Ion Storage Georgios A. Tritsaris

  17. Li Conductivity in LixMPO4 ,,M Mn, Fe, Co, Ni... Olivine Materials

    E-Print Network [OSTI]

    Ceder, Gerbrand

    , USA Materials with the olivine LixMPO4 structure form an important class of rechargeable battery-ion batteries. In particular, early work on the LixFePO4 material demonstrated its potential to reversibly cycle in supercells containing eight formula units to reduce interactions between images of the Li being moved. The Li

  18. PoLiDBMS: Design and Prototype Implementation of a DBMS for Portable

    E-Print Network [OSTI]

    Schreiber, Fabio A.

    PoLiDBMS: Design and Prototype Implementation of a DBMS for Portable Devices C. Bolchini, C. Curino e Informazione Proc. SEBD'04 S. Margherita di Pula, June 2004 pp. 166-177 #12;PoLiDBMS: Design and Prototype Implementation of a DBMS for Portable Devices C. Bolchini, C. Curino, M. Giorgetta, A. Giusti, A

  19. LI, SONG, GONG: SKETCH RECOGNITION BY ENSEMBLE MATCHING 1 Sketch Recognition by Ensemble Matching

    E-Print Network [OSTI]

    Gong, Shaogang

    LI, SONG, GONG: SKETCH RECOGNITION BY ENSEMBLE MATCHING 1 Sketch Recognition by Ensemble Matching://www.eecs.qmul.ac.uk/~yzs Shaogang Gong http://www.eecs.qmul.ac.uk/~sgg School of Electronic Engineering and Computer Science, Queen with its authors. It may be distributed unchanged freely in print or electronic forms. #12;2 LI, SONG, GONG

  20. Study on generating of thermal neutron scattering cross sections for LiH

    SciTech Connect (OSTI)

    Wang, L.; Jiang, X.; Zhao, Z.; Chen, L. [Northwest Institute of Nuclear Technology, Xi'an 710024 (China)

    2013-07-01

    LiH is designated as a promising moderator and shielding material because of its low density, high melting point and large fraction of H atoms. However, lack of the thermal neutron cross sections of LiH makes numerical calculation deviate from experimental data to some extent. As a result, it is necessary to study LiH thermal kernel effect. The phonon property of LiH has been investigated by first-principles calculations using the plane-wave pseudo potential method with CASTEP code. The scattering law and the thermal neutron scattering cross sections for Li and H have been generated using this distribution. The results have been compared with zirconium hydride data. The GASKET and NJOY/LEAPR codes have been used in the calculation of scattering law, whose results have been compared with the reference; the discrepancy mainly comes from phonon spectrums and its expansion. LEAPR had the capability to compute scattering through larger energy and momentum transfers than GASKET did. By studying LiH phonon spectrum and constructing the model of LiH thermal kernel and scattering matrix, the ACE format LiH thermal neutron cross sections for MCNP software could be made and used for reactor Neutronics calculation. (authors)

  1. Design and optimization of 6li neutron-capture pulse mode ion chamber 

    E-Print Network [OSTI]

    Chung, Kiwhan

    2009-05-15

    The purpose of this research is to design and optimize the performance of a unique, inexpensive 6Li neutron-capture pulse-mode ion chamber (LiPMIC) for neutron detection that overcomes the fill-gas contamination stemming from outgas of detector...

  2. The Influence of Catalysts on Discharge and Charge Voltages of Rechargeable Li–Oxygen Batteries

    E-Print Network [OSTI]

    Gasteiger, Hubert A.

    This study revealed the strong influence of carbon, Au/C, and Pt/C catalysts on the charge and discharge voltages of rechargeable Li–O[subscript 2] batteries. Li–O[subscript 2] single-cell measurements showed that Au/C had ...

  3. Studies of Line Emission from Collisions of Multiply Charged Ions on He and Li Targets for Tokamak Diagnostics

    E-Print Network [OSTI]

    Studies of Line Emission from Collisions of Multiply Charged Ions on He and Li Targets for Tokamak Diagnostics

  4. Scanning tunneling microscopy reveals LiMnAs is a room temperature anti-ferromagnetic semiconductor

    SciTech Connect (OSTI)

    Wijnheijmer, A. P.; Koenraad, P. M.; Marti, X.; Holy, V.; Cukr, M.; Novak, V.; Jungwirth, T.

    2012-03-12

    We performed scanning tunneling microscopy and spectroscopy on a LiMnAs(001) thin film epitaxially grown on an InAs(001) substrate by molecular beam epitaxy. While the in situ cleavage exposed only the InAs(110) non-polar planes, the cleavage continued into the LiMnAs thin layer across several facets. We combined both topography and current mappings to confirm that the facets correspond to LiMnAs. By spectroscopy we show that LiMnAs has a band gap. The band gap evidenced in this study, combined with the known Neel temperature well above room temperature, confirms that LiMnAs is a promising candidate for exploring the concepts of high temperature semiconductor spintronics based on antiferromagnets.

  5. Analytic potentials and vibrational energies for Li$_{2}$ states dissociating to $\\mbox{Li}\\left(2S\\right)+\\mbox{Li}\\left(3P\\right)$. Part 1: The $^{2S+1}?_{u/g}$ states

    E-Print Network [OSTI]

    Nikesh S. Dattani

    2015-09-23

    Analytic potentials are built for all four $^{2S+1}\\Pi_{u/g}$ states of Li$_{2}$ dissociating to Li$(2S)$ + Li$(3P)$: $3b(3^{3}\\Pi_{u})$, $3B(3^{1}\\Pi_{u})$, $3C(3^{1}\\Pi_{g}),$ and $3d(3^{3}\\Pi_{g})$. These potentials include the effect of spin-orbit coupling for large internuclear distances, and include state of the art long-range constants. This is the first successful demonstration of fully analytic diatomic potentials that capture features that are usually considered too difficult to capture without a point-wise potential, such as multiple minima, and shelves. Vibrational energies for each potential are presented for the isotopologues $^{6,6}$Li$_{2}$, $^{6,7}$Li$_{2}$, $^{7,7}$Li$_{2}$, and the elusive `halo nucleonic molecule' $^{11,11}$Li$_{2}$. These energies are claimed to be accurate enough for new high-precision experimental setups such as the one presented in {[}Sebastian \\emph{et al.} Phys. Rev. A, \\textbf{90}, 033417 (2014){]} to measure and assign energy levels of these electronic states, all of which have not yet been explored in the long-range region. Measuring energies in the long-range region of these electronic states may be significant for studying the \\emph{ab initio} vs experiment discrepancy discussed in {[}Tang \\emph{et al.} Phys. Rev. A, \\textbf{84}, 052502 (2014){]} for the $C_{3}$ long-range constant of Lithium, which has significance for improving the SI definition of the second.

  6. Enhanced hydrogen storage properties of LiAlH4 catalyzed by CoFe2O4 nanoparticles

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Enhanced hydrogen storage properties of LiAlH4 catalyzed by CoFe2O4 nanoparticles Ziliang Li The catalytic effects of CoFe2O4 nanoparticles on the hydrogen storage properties of LiAlH4 prepared by ball of advanced hydrogen storage materials for safely storing it at high gravimetric and volumetric densities.4

  7. GUIDE TO WASHINGTON UNIVERSITY LIBRARIES UNIVERSITY ARCHIVES

    E-Print Network [OSTI]

    GUIDE TO WASHINGTON UNIVERSITY LIBRARIES UNIVERSITY ARCHIVES DEPARMENT OF SPECIAL COLLECTIONS of both Washington University and the St. Louis communities from 1853 to present day. Our collections. CONTACT INFORMATION: Our street address: Our mailing address: Washington University Archives Washington

  8. UNIVERSITY OF ABERDEEN UNIVERSITY COURT

    E-Print Network [OSTI]

    Levi, Ran

    from Talisman towards student scholarships and from a number of oil companies towards a centre to be a post-doctoral researcher. The University had been ranked as one of the top twenty institutions outside

  9. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect (OSTI)

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-05-15

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles [1-2], among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials [3] and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique [4], including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

  10. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    SciTech Connect (OSTI)

    Chen, Jiajun; Doeff, Marca M.; Wang, Ruigang

    2008-10-12

    Among the olivine-structured metal phosphate family, LiMnPO{sub 4} exhibits a high discharge potential (4V), which is still compatible with common electrolytes, making it interesting for use in the next generation of Li ion batteries. The extremely low electronic conductivity of this material severely limits its electrochemical performance, however. One strategy to overcome this limitation is to make LiMnPO{sub 4} nanoparticulate to decrease the diffusion distance. Another is to add a carbon or other conductive coating in intimate contact with the nanoparticles of the main phase, as is commonly done with LiFePO{sub 4}. The electrochemical performance of LiFePO{sub 4} is highly dependent on the quality of the carbon coatings on the particles, among other variables. Combustion synthesis allows the co-synthesis of nanoparticles coated with carbon in one step. Hydrothermal synthesis is used industrially to make LiFePO{sub 4} cathode materials and affords a good deal of control over purity, crystallinity, and particle size. A wide range of olivine-structured materials has been successfully prepared by this technique, including LiMnPO{sub 4} in this study. In this paper, we report on the new synthesis of nano-LiMnPO{sub 4} by a combustion method. The purity is dependent upon the conditions used for synthesis, including the type of fuel and precursors that are chosen. The fuel to nitrate ratio influences the combustion temperature, which determines the type and amount of carbon found in the LiMnPO{sub 4} composites. This can further be modified by use of carbon structural modifiers added during a subsequent (optional) calcination step. Figure 1 shows a transmission electron microscopy (TEM) image of the spherical nano-sized LiMnPO{sub 4} particles typically formed by combustion synthesis. The average particle size is around 30 nm, in agreement with values obtained by the Rietveld refinement of XRD patterns. The small size of the particles cause the peak broadening evident in the pattern of combustion formed LiMnPO{sub 4}, shown in Figure 2. Figure 2 also shows a pattern of hydrothermally prepared LiMnPO{sub 4}, which is sub-micron in size. In this presentation, we will show how the crystallographic parameters, particle size, particle morphology, and carbon content and structure impact the electrochemical properties of the LiMnPO{sub 4}/C composites produced by these methods.

  11. University Ave SE University Ave W

    E-Print Network [OSTI]

    Thomas, David D.

    University Ave SE University Ave W Service Layer Credits: Sources: Esri, DeLorme, NAVTEQ, USGS, Intermap, i UV55 ")280 University Ave. Ramp Major Access Routes University Ave. Ramp §¨¦35W §¨¦94 ")280 Date: 5/30/2014 #12;, , , , , , , ""A TCF Bank Stadium Access Routes University Ave. Ramp University Ave SE Service

  12. Formation of Interfacial Layer and Long-Term Cylability of Li-O-2 Batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Mehdi, Beata L.; Thomsen, Edwin C.; Engelhard, Mark H.; Masse, Robert C.; Bhattacharya, Priyanka; Gu, Meng; Bennett, Wendy D.; Nie, Zimin; Wang, Chong M.; Browning, Nigel D.; Zhang, Jiguang

    2014-08-27

    Extended cycling of the Li-O2 battery under full discharge/charge conditions is achievable upon selection of appropriate electrode materials and cycling protocol. However, the decomposition of the side products also contribute to the observed good cycling behavior of high capacity Li-O2 batteries. Quantitative analyses of the discharge and charge products reveals a quick switch from the predominant formation of Li2O2 to the predominant formation of side products during the first a few cycles of the Li-O2 batteries. After the switch, cycling stabilizes with a repeatable formation of Li2O2/side products at ~1:2 ratio. CNTs/Ru composite electrodes exhibits lower charge voltage and deliver 50 full discharge-charge cycles without sharp capacity drop. Ru coated glass carbon electrode can lead to more than 500 cycles without change in its cycling profiles. The better understanding on Li-O2 reaction processes developed in this work may lead to the further improvement on the long term cycling behavior of high capacity Li-O2 batteries.

  13. Stability of the solid electrolyte Li{sub 3}OBr to common battery solvents

    SciTech Connect (OSTI)

    Schroeder, D.J.; Hubaud, A.A.; Vaughey, J.T.

    2014-01-01

    Graphical abstract: The stability of the anti-perovskite phase Li{sub 3}OBr has been assessed in a variety of battery solvents. - Highlights: • Lithium stable solid electrolyte Li{sub 3}OBr unstable to polar organic solvents. • Solvation with no dissolution destroys long-range structure. • Ion exchange with protons observed. - Abstract: Recently a new class of solid lithium ion conductors was reported based on the anti-perovskite structure, notably Li{sub 3}OCl and Li{sub 3}OBr. For many beyond lithium-ion battery uses, the solid electrolyte is envisioned to be in direct contact with liquid electrolytes and lithium metal. In this study we evaluated the stability of the Li{sub 3}OBr phase against common battery solvents electrolytes, including diethylcarbonate (DEC) and dimethylcarbonate (DMC), as well as a LiPF{sub 6} containing commercial electrolyte. In contact with battery-grade organic solvents, Li{sub 3}OBr was typically found to be insoluble but lost its crystallinity and reacted with available protons and in some cases with the solvent. A low temperature heat treatment was able to restore crystallinity of the samples; however evidence of proton ion exchange was conserved.

  14. Comparison of LiFePO4 from different sources

    SciTech Connect (OSTI)

    Striebel, Kathryn; Shim, Joongpyo; Srinivasan, Venkat; Newman, John

    2003-11-25

    The lithium iron phosphate chemistry is plagued by the poor conductivity and slow lithium diffusion in the solid phase. In order to alleviate these problems, various research groups have adopted different strategies including decreasing the particle sizes, increasing the carbon content, and adding dopants. In this study we obtained LiFePO4 electrodes from six different sources and used a combined model-experimental approach to compare the performance. Samples ranged from one with no carbon coating to one with 15 percent coating. In addition, particle sizes varied by as much as a order of magnitude between samples. The study detailed in this manuscript allows us to provide insight into the relative importance of the conductivity of the samples compared to the particle size, the impact of dopant on performance and ideas for making materials in order to maximize the power capability of this chemistry.

  15. Comparison of LiFePO4 from different sources

    SciTech Connect (OSTI)

    Striebel, Kathryn; Shim, Joongpyo; Srinivasan, Venkat; Newman, John

    2004-06-21

    The lithium iron phosphate chemistry is plagued by the poor conductivity and slow diffusion in the solid phase. In order to alleviate these problems, various research groups have adopted different strategies including decreasing the particle sizes, increasing the carbon content, and adding dopants. In this study, we obtained LiFePO{sub 4} powders and/or electrodes from six different sources and used a combined model-experimental approach to compare the performance. Samples ranged from 0.4% to 15% ''in-situ'' carbon. In addition, particle sizes varied by as much as an order of magnitude between samples. The study detailed in this manuscript allows us to provide insight into the relative importance of the conductivity of the samples compared to the particle size, the impact of having a distribution in particle sizes, and ideas for making materials in order to maximize the power capability of this chemistry.

  16. DIMACS Center Rutgers University

    E-Print Network [OSTI]

    Graduate Program, Rutgers University Jeff Kahn, Professor of Mathematics, Rutgers University Eric Allender Jozsef Beck, Professor of Mathematics, Rutgers University US Faculty Mentors: 1 #12;Eric Allender, RUTCOR, Rutgers University Peter Hammer, RUTCOR, Rutgers University Leonid Khachiyan, Department

  17. Summary of mechanical properties data and correlations for Li/sub 2/O, Li/sub 4/SiO/sub 4/, LiAlO/sub 2/, and Be

    SciTech Connect (OSTI)

    Billone, M.C.; Grayhack, W.T.

    1988-04-01

    The data base for thermal expansion, elastic constants, compressive and tensile failure strengths and secondary thermal creep of leading solid-breeder (Li/sub 2/O, Li/sub 4/SiO/sub 4/, and LiAlO/sub 2/) and multiplier (Be) materials is reviewed, porosity, grain size, and stress (for thermal creep). Because the data base is rather sparse in some areas, general properties of ceramics and metals are used to help guide the formulation of the correlations. The primary purpose of the data base summary and correlation development is to pave the way for stress analysis sensitivity studies. These studies will help determine which properties are important enough to structural lifetime and deformation assessments to require more data. 18 refs., 5 figs., 20 tabs.

  18. Geophysical inversion using petrophysical constraints with application to lithology differentiation Jiajia Sun and Yaoguo Li, Center for Gravity, Electrical and Magnetic Studies, Colorado School of Mines

    E-Print Network [OSTI]

    Jiajia Sun and Yaoguo Li, Center for Gravity, Electrical and Magnetic Studies, Colorado School of Mines

  19. Inversion of surface and borehole gravity with thresholding and density constraints Jiajia Sun and Yaoguo Li, Center for Gravity, Electrical and Magnetic Studies, Department of Geophysics, Colorado

    E-Print Network [OSTI]

    and Yaoguo Li, Center for Gravity, Electrical and Magnetic Studies, Department of Geophysics, Colorado School

  20. Hydrogen storage in LiAlH4 : Predictions of the crystal structures and reaction mechanisms of intermediate phases from quantum mechanics

    E-Print Network [OSTI]

    Goddard III, William A.

    Hydrogen storage in LiAlH4 : Predictions of the crystal structures and reaction mechanisms in decomposition of the potential hydrogen storage material LiAlH4 . First, we explore the decomposition mechanism of monoclinic LiAlH4 into monoclinic Li3AlH6 plus face-centered cubic fcc Al and hydrogen. We find

  1. E17 to P1 Cortical Cultures (Ghosh Lab Protocol) 1. Prepare solutions: Enzyme (E), heavy inhibitor (HI), light inhibitor (LI), culture

    E-Print Network [OSTI]

    Ghosh, Anirvan

    (HI), light inhibitor (LI), culture media. Place at 37 C. 2. Prepare for dissection: Spray dissection' with tissue, HI, LI, media to TC hood. [during the enzymatic step clean up dissection area, and wash) Rinse cells 1X with LI. (iv) Remove LI, add HI, leave tissue in HI for 2 mins at 37 C. (v) Remove HI

  2. Fusion reactions in collisions induced by Li isotopes on Sn targets

    SciTech Connect (OSTI)

    Fisichella, M.; Shotter, A. C.; Di Pietro, A.; Figuera, P.; Lattuada, M.; Marchetta, C.; Musumarra, A.; Pellegriti, M. G.; Ruiz, C.; Scuderi, V.; Strano, E.; Torresi, D.; Zadro, M.

    2012-10-20

    Fusion cross sections for the {sup 6}Li+{sup 120}Sn and {sup 7}Li+{sup 119}Sn systems have been measured. We aim to search for possible effects due to the different neutron transfer Q-values, by comparing the fusion cross sections for the two systems below the barrier. This experiment is the first step of a wider systematic aiming to study the above problems in collisions induced by stable and unstable Li isotopes on tin all forming the same compound nucleus.

  3. Compact Li-doped Gd{sub 2}Ti{sub 2}O{sub 7} prepared with LiO{sub 0.5} self-flux

    SciTech Connect (OSTI)

    Wen, L.C.; Hsieh, H.Y.; Chang, S.C.; Lin, M.Y.; Lee, Y.H.; Su, W.P. [Department of Chemistry, Tamkang University, New Taipei City 25137, Taiwan (China); Kao, H.-C.I., E-mail: kaohci@mail.tku.edu.tw [Department of Chemistry, Tamkang University, New Taipei City 25137, Taiwan (China); Sheu, H.S.; Jang, L.Y. [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Lee, M.C.; Lee, Y.S. [Institute of Nuclear Energy Research, Atomic Energy Council, Longtan 32546, Taiwan (China)

    2014-02-01

    Graphical abstract: Left figure is the unit cell a-axis of the GLT-2L (?), GLT (?) and GT (?) as a function of x. Both of the GLT-2L and GLT have the same results so that they have the same chemical formula, (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x}, in which GT has a formula of Gd{sub 2?x}Ti{sub 2}O{sub 7?x}. Relative densities are shown in the right figure. GLT-2L (?) has higher values than GLT (?). 2x moles of LiO{sub 0.5} were added as a self-flux to prepare GLT-2L at 1250 °C, which was about 300 °C lowered than required without the co-existence of the flux and Li ion substitution. - Highlights: • A new series of compounds with a formula as (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x} was synthesized. • Each GLT-2L sample contains (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x} and 2x moles of LiO{sub 0.5} self-flux. • 1250 °C was used to prepare the GLT-2L samples; 300 °C lower than required. • Electrical conductivity of the GLT-2L is not affected by the presence of the flux. • Average valence of the Ti ions is slightly less than 4. - Abstract: A series of (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x} with x = 0.040–0.110 was first reported. Parent compound with 2x moles of LiO{sub 0.5} self-flux was prepared at 1250 °C and abbreviated as GLT-2L. Relative density of all the samples is higher than 92%. By the addition of flux and Li ions substitution, preparation temperature is lowered for more than 300 °C. Comparing the unit cell a-axis, GLT with a formula as (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x} without flux addition has exactly the same as the GLT-2L with the same x. By the addition of flux, materials become more compact and grains grow bigger for the GLT-2L than the corresponding GLT samples. Electrical conductivity of a GLT-2L with x = 0.110 at 700 °C is 3 times larger than the measurements done by other research groups in the Gd{sub 2}Ti{sub 2}O{sub 7}. In order to demonstrate the successful substitution of the Li ion into the Gd site, a series of GT samples was prepared with a formula of Gd{sub 2?x}Ti{sub 2}O{sub 7?1.5x}. With the same amount of x, every GLT samples have a longer unit cell a-axis than that of the GT. The difference is caused by the substitution of the Li ion into the Gd site. Valence of the Ti atoms of the GLT-2L samples is slightly less than 4 studied by the XANES spectroscopy.

  4. Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries

    E-Print Network [OSTI]

    Shim, J.; Guerfi, A.; Zaghib, K.; Striebel, K.A.

    2003-01-01

    Cathode for Lithium-Ion Batteries J. Shim a , A. Guerfi b ,material for Li rechargeable batteries because of low-cost,is a part of BATT (Batteries for Advanced Transportation

  5. Nanocrystallization of LiCoO2 Cathodes for Thin Film Batteries Utilizing Pulse Thermal Processing

    SciTech Connect (OSTI)

    2009-04-01

    This factsheet describes a study whose focus is on the nanocrystallization of the LiCoO2 cathode thin films on polyimide substrates and evaluate the microstructural evolution and resistance as a function of PTP processing conditions.

  6. Microsoft PowerPoint - Garcia-Diaz - LiT Electrolysis Projects...

    Office of Environmental Management (EM)

    * Maroni is the Baseline for LiT Electrolysis * LLNL LDRD tries to improve molten salt liquid-liquid extraction and SRNL is contributing by investigating RbCl containing salts *...

  7. Synthesis, electrochemistry and First Principles Calculation studies of layered Li-Ni-Ti-O compounds

    E-Print Network [OSTI]

    Kang, Kisuk

    New layered cathode materials, Li?.?Ni?.??Ti?.??O?, were synthesized by means of ion-exchange from Na?.?Ni?.??Ti?.??O?. The degree of cation disordering in the material depends critically on the synthesis conditions. Longer ...

  8. Factors Influencing the Quality of Carbon Coatings on LiFePO4

    E-Print Network [OSTI]

    Wilcox, James D.; Doeff, Marca M.; Marcinek, Marek; Kostecki, Robert

    2006-01-01

    the Quality of Carbon Coatings on LiFePO 4 James D. Wilcoxamounts of a less-conductive coating. It has also been shownin markedly improved coatings, as will be shown below.

  9. Mesoscale Modeling of a Li-Ion Polymer Cell Chia-Wei Wanga,

    E-Print Network [OSTI]

    Sastry, Ann Marie

    Mesoscale Modeling of a Li-Ion Polymer Cell Chia-Wei Wanga, * and Ann Marie Sastrya,b,c, *,z, the study reported critical data required for mesoscale numerical simulation, including ionic con- ductivity

  10. Proposal for an Electron Antineutrino Disappearance Search Using High-Rate 8Li Production and Decay

    E-Print Network [OSTI]

    Bungau, Adriana

    This paper introduces an experimental probe of the sterile neutrino with a novel, high-intensity source of electron antineutrinos from the production and subsequent decay of [superscript 8]Li. When paired with an existing ...

  11. Vehicle Technologies Office Merit Review 2015: A 12V Start-Stop Li Polymer Battery Pack

    Broader source: Energy.gov [DOE]

    Presentation given by LG Chem Power at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about A 12V start-stop Li polymer...

  12. Search for Solar Axion Emission from 7Li and D(p,gamma)3He Nuclear...

    Office of Scientific and Technical Information (OSTI)

    Solar Axion Emission from 7Li and D(p,gamma)3He Nuclear Decays with the CAST gamma-ray Calorimeter Andriamonje, S.; Aune, S.; DAPNIA, Saclay; Autiero, D.; CERN Lyon, IPN; Barth,...

  13. Proceedings of the AD HOC Workshop on Ceramics for Li/FeS{sub 2} batteries

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    Representatives from industry, the U.S. Advanced Battery Consortium (USABC), DOE, national laboratories, and other govt agencies met to develop recommendations and actions for accelerating the development of ceramic components critical to the successful introduction of the Li/FeS{sub 2} bipolar battery for electric vehicles. Most of the workshop is devoted to electrode materials, bipolar designs, separators, and bipolar plates. The bulk of this document is viewographs and is divided into: ceramics, USABC overview, SAFT`s Li/FeS{sub 2} USABC program, bipolar Li/FeS{sub 2} component development, design requirements for bipolar plates, separator design requirements, compatibility of ceramic insulators with lithium, characterization of MgO for use in separators, resistivity measurements of separators, sintered AlN separators for LiMS batteries, etc.

  14. The mechanism of HF formation in LiPF6-based organic carbonate electrolytes

    E-Print Network [OSTI]

    Lux, Simon

    2014-01-01

    The mechanism of HF formation in LiPF6-based organicliterature data, a simplified mechanism for the formation of3 . In this proposed mechanism, the blue lines represent the

  15. Second-Use Li-Ion Batteries to Aid Automotive and Utility Industries (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01

    Repurposing Li-ion batteries at the end of useful life in electric drive vehicles could eliminate owners' disposal concerns and offer low-cost energy storage for certain applications.

  16. An ultra-compact and efficient Li-ion battery charger circuit for biomedical applications

    E-Print Network [OSTI]

    Do Valle, Bruno Guimaraes

    This paper describes an ultra-compact analog lithium-ion (Li-ion) battery charger for wirelessly powered implantable medical devices. The charger presented here takes advantage of the tanh output current profile of an ...

  17. Search for Solar Axion Emission from 7Li and D(p,gamma)3He Nuclear...

    Office of Scientific and Technical Information (OSTI)

    Search for Solar Axion Emission from 7Li and D(p,gamma)3He Nuclear Decays with the CAST gamma-ray Calorimeter Citation Details In-Document Search Title: Search for Solar Axion...

  18. STUDY OF THE REACTION DYNAMICS OF Li + HF, HC1 BY THE CROSSED MOLECULAR BEAMS METHOD

    E-Print Network [OSTI]

    Becker, Christopher H.

    2013-01-01

    the angular and velocity distributions of reaction products~of~flight velocity measurements of the reaction product atLi + HF reaction at EC 2.2 kcal/mole. Velocity distributions

  19. LiNaK : multi-species apparatus for the study of ultracold quantum degenerate mixtures

    E-Print Network [OSTI]

    Santiago González, Ibon

    2012-01-01

    This thesis describes the construction of a versatile apparatus to study ultracold quantum mixtures capable of simultaneously cooling fermionic ?Li and ??K, as well as the bosonic ?¹K. The main features of the experimental ...

  20. Construction, Pattern Recognition and Performance of the CLEO III LiF-TEA RICH Detector

    E-Print Network [OSTI]

    M. Artuso; R. Ayad; K. Bukin; A. Efimov; C. Boulahouache; E. Dambasuren; S. Kopp; R. Mountain; G. Majumder; S. Schuh; T. Skwarnicki; S. Stone; G. Viehhauser; J. C. Wang; T. E. Coan; V. Fadeyev; Y. Maravin; I. Volobouev; J. Ye; S. Anderson; Y. Kubota; A. Smith

    2002-09-13

    We briefly describe the design, construction and performance of the LiF-Tea RICH detector built to identify charged particles in the CLEO III experiment. Excellent pion/kaon separation is demonstrated.

  1. Construction, Pattern Recognition and Performance of the CLEO III LiF-TEA RICH Detector

    E-Print Network [OSTI]

    Artuso, M; Bukin, K; Efimov, A; Boulahouache, C; Dambasuren, E; Kopp, S E; Mountain, R; Majumder, G; Schuh, S; Skwarnicki, T; Stone, S; Viehhauser, G; Wang, J C; Coan, T E; Fadeev, V; Maravin, Y; Volobuev, I P; Ye, J; Anderson, S; Kubota, Y; Smith, A

    2003-01-01

    We briefly describe the design, construction and performance of the LiF-Tea RICH detector built to identify charged particles in the CLEO III experiment. Excellent pion/kaon separation is demonstrated.

  2. UNIVERSITY OF ABERDEEN UNIVERSITY COURT

    E-Print Network [OSTI]

    Neri, Peter

    that there remained a considerable number of areas within the University that depended on the future success as the location of one of three Scottish Enterprise Intermediary Technology Institutes, namely the Energy for the financial year 2001-02 and noted the annual Report on Endowments. SUBSIDIARY COMPANIES ANNUAL ACCOUNTS 2001

  3. UNIVERSITY OF ABERDEEN UNIVERSITY COURT

    E-Print Network [OSTI]

    Neri, Peter

    in "Europe's Energy Capital". It was vital, however, that the Institute developed a comprehensive marketing strategy to make best use of the University's location and its academic strengths in Energy. Page 1 of 11. PRESENTATION ON THE ABERDEEN INSTITUTE OF ENERGY 178 Mr J Scrimgeour, Executive Director of the Aberdeen

  4. Modeling Crystalline Electrolytes: Li7P3S11 and Analogous Phosphates

    E-Print Network [OSTI]

    Holzwarth, Natalie

    and interstitial defect migration mechanisms Energy cost for migration (Em) Energy cost for defect pair formation.42 eV a 0.29 eV b 0.15 eV Calculated value agrees with experiment: 0.15eV 0.12eV Lowest energy melt Metastable with respect to Li4P2S6 and Li3PS4 Conductivity of 3 x 10-3S/cm Activation energy of 0

  5. Structural and Chemical Evolution of Li- and Mn-rich Layered Cathode Material

    SciTech Connect (OSTI)

    Zheng, Jianming; Xu, Pinghong; Gu, Meng; Xiao, Jie; Browning, Nigel D.; Yan, Pengfei; Wang, Chong M.; Zhang, Jiguang

    2015-02-24

    Lithium (Li)- and manganese-rich (LMR) layered-structure materials are very promising cathodes for high energy density lithium-ion batteries. However, their voltage fading mechanism and its relationships with fundamental structural changes are far from being sufficiently understood. Here we report the detailed phase transformation pathway in the LMR cathode (Li[Li0.2Ni0.2Mn0.6]O2) during cycling for the samples prepared by hydro-thermal assistant method. It is found the transformation pathway of LMR cathode is closely correlated to its initial structure and preparation conditions. The results reveal that LMR cathode prepared by HA approach experiences a phase transformation from the layered structure to a LT-LiCoO2 type defect spinel-like structure (Fd-3m space group) and then to a disordered rock-salt structure (Fm-3m space group). The voltage fade can be well correlated with the Li ion insertion into octahedral sites, rather than tetrahedral sites, in both defect spinel-like structure and disordered rock-salt structure. The reversible Li insertion/removal into/from the disordered rock-salt structure is ascribed to the Li excess environment that can satisfy the Li percolating in the disordered rock-salt structure despite the increased kinetic barrier. Meanwhile, because of the presence of a great amount of oxygen vacancies, a significant decrease of Mn valence is detected in the cycled particle, which is below that anticipated for a potentially damaging Jahn-Teller distortion (+3.5). Clarification of the phase transformation pathway, cation redistribution, oxygen vacancy and Mn valence change undoubtedly provides insights into a profound understanding on the voltage fade, and capacity degradation of LMR cathode. The results also inspire us to further enhance the reversibility of LMR cathode via improving its surface structural stability.

  6. NREL's PHEV/EV Li-Ion Battery Secondary-Use Project

    SciTech Connect (OSTI)

    Newbauer, J.; Pesaran, A.

    2010-06-01

    Accelerated development and market penetration of plug-in hybrid electric vehicles (PHEVs) and electric vehicles (EVs) is restricted at present by the high cost of lithium-ion (Li-ion) batteries. One way to address this problem is to recover a fraction of the Li-ion battery's cost via reuse in other applications after it is retired from service in the vehicle, when the battery may still have sufficient performance to meet the requirements of other energy storage applications.

  7. Electrochemical Properties of Disordered-Carbon-Coated SnO2 Nanoparticles for Li Rechargeable Batteries

    E-Print Network [OSTI]

    Park, Byungwoo

    Batteries Taeho Moon, Chunjoong Kim, Sun-Tae Hwang, and Byungwoo Park*,z School of Materials Science batteries.1-5 It is rationalized that the reactions of SnO2 with lithium are SnO2 + 4Li Sn + 2Li2O and Sn is to distribute nanoparticles uniformly on a large matrix such as graphite, mesoporous carbon, etc.12,13 However

  8. Department of Li/sup /minus// and H/sup /minus// ion sources

    SciTech Connect (OSTI)

    Walther, S.R.

    1988-12-01

    Sources of Li/sup /minus// and H/sup /minus// ions are needed for diagnostic neutral beam and for current drive in fusion plasmas. Previous efforts to generate Li/sup /minus// beams have focused on electron capture in a gas or production on a low work function surface in a plasma. Volume production of Li/sup /minus// by dissociative attachment of optically pumped lithium molecules has also been studied. This thesis presents the first experimental results for volume production of a Li/sup /minus// ion beam from a plasma discharge. A theoretical model for volume production of Li/sup /minus// ions and separate model for Li/sub 2/ production in the lithium discharge are developed to explain the experimental results. The model is in good agreement with the experiment and shows favorable parameter scalings for further improvement of the Li/sup /minus// ion source. A /sup 6/Li/degree/ diagnostic neutral beam based on this ion source is proposed for measurement of magnetic pitch angle in the International Thermonuclear Experimental Reactor (ITER). Previous efforts in developing H/sup /minus// ion sources have concentrated on volume production in a plasma discharge. Experiments to improve the H/sup /minus// current density from a magnetically filtered multicusp ion source by seeding the discharge with cesium or barium have been conducted. A substantial (> factor of five) increase in H/sup /minus// output is achieved for both cesium and barium addition. Further experiments with barium have shown that the increase is due to H/sup /minus// production on the anode walls. The experiments with cesium are consistent with this formation mechanism. These results show that this new type of 'converterless' surface production H/sup /minus// source provides greatly improved performance when compared to a volume H/sup /minus// source. 92 refs., 47 figs.

  9. CONFIDENTIAL UNIVERSITY OF ABERDEEN

    E-Print Network [OSTI]

    Neri, Peter

    University, the Robert Gordon University and Napier University to submit a bid covering oil and gas, environmental diagnostics and engineering, medical imaging, food, agriculture and aquaculture. Participating

  10. DIMACS Center Rutgers University

    E-Print Network [OSTI]

    , Chair, Bell Labs Bernard Chazelle, Princeton Bill Steiger, Rutgers University Computational Geometry University Nina Amenta, University of California ­ Davis Fausto Bernardini, IBM - T. J. Watson Research

  11. PHILADELPHIA UNIVERSITY 1995

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY 1.: 1995 (95/96/1997) (750000. . 7. . #12;PHILADELPHIA UNIVERSITY 8. . 9. . 10. . 11. . 3. . 2005/2006. #12;PHILADELPHIA UNIVERSITY 5. : 1. . 2. . 3

  12. PHILADELPHIA UNIVERSITY 1995

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY : 1995 (95/96/1997) (750000. . 5. . #12;PHILADELPHIA UNIVERSITY 6. . 7. . 8%) : . . ( ) . . . . . . . (15) (20). . #12;PHILADELPHIA UNIVERSITY 4. : : 1. . 2. . (23) (15

  13. PHILADELPHIA UNIVERSITY (374)

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY : - - . . : (374;PHILADELPHIA UNIVERSITY : ( :) 1). http://dx.doi.org/10.1016/j.infrared.2006.01.032 #12;PHILADELPHIA UNIVERSITY . Gary Rayson, Baolong Bai

  14. Open University

    ScienceCinema (OSTI)

    None

    2011-04-25

    Michel Pentz est née en Afrique du Sud et venu au Cern en 1957 comme physicien et président de l'associaion du personnel. Il est également fondateur du mouvement Antiapartheid de Genève et a participé à la fondation de l'Open University en Grande-Bretagne. Il nous parle des contextes pédagogiques, culturels et nationaux dans lesquels la méthode peut s'appliquer.

  15. University of Memphis University Libraries -Position Description

    E-Print Network [OSTI]

    Dasgupta, Dipankar

    the needs of library users and library personnel. The Emerging Technologies Librarian is a memberUniversity of Memphis University Libraries - Position Description Description Updated: November 2012 1 I. DEPARTMENT: University Libraries ­ Library Information Systems II. POSITION: Emerging

  16. Optimization of LiFePO4 Nanoparticle Suspensions with Polyethyleneimine for Aqueous Processing

    SciTech Connect (OSTI)

    Li, Jianlin; Armstrong, Beth L; Kiggans, Jim; Daniel, Claus; Wood III, David L

    2012-01-01

    Addition of dispersants to aqueous based lithium-ion battery electrode formulations containing LiFePO{sub 4} is critical to obtaining a stable suspension. The resulting colloidal suspensions enable dramatically improved coating deposition when processing electrodes. This research examines the colloidal chemistry modifications based on polyethyleneimine (PEI) addition and dispersion characterization required to produce high quality electrode formulations and coatings for LiFePO{sub 4} active cathode material. The isoelectric point, a key parameter in characterizing colloidal dispersion stability, of LiFePO{sub 4} and super P C45 were determined to be pH = 4.3 and 3.4, respectively. PEI, a cationic surfactant, was found to be an effective dispersant. It is demonstrated that 1.0 wt % and 0.5 wt % PEI were required to stabilize the LiFePO{sub 4} and super P C45 suspension, respectively. LiFePO{sub 4} cathode suspensions with 1.5 wt % PEI demonstrated the best dispersibility of all components, as evidenced by viscosity and agglomerate size of the suspensions and elemental distribution within dry cathodes. The addition of PEI significantly improved the LiFePO{sub 4} performance.

  17. Redox probing study of the potential dependence of charge transport through Li2O2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knudsen, Kristian B.; Luntz, Alan C.; Jensen, Søren H.; Vegge, Tejs; Hjelm, Johan

    2015-11-20

    In the field of energy storage devices the pursuit for cheap, high energy density, reliable secondary batteries is at the top of the agenda. The Li–O2 battery is one of the possible technologies that, in theory, should be able to close the gap, which exists between the present state-of-the-art Li-ion technologies and the demand placed on batteries by technologies such as electrical vehicles. Here we present a redox probing study of the charge transfer across the main deposition product lithium peroxide, Li2O2, in the Li–O2 battery using outer-sphere redox shuttles. The change in heterogeneous electron transfer exchange rate as amore »function of the potential and the Li2O2 layer thickness (~depth-of-discharge) was determined using electrochemical impedance spectroscopy. In addition, the attenuation of the electron transfer exchange rate with film thickness is dependent on the probing potential, providing evidence that hole transport is the dominant process for charge transfer through Li2O2 and showing that the origin of the sudden death observed upon discharge is due to charge transport limitations.« less

  18. Cylindrical target Li-beam-driven hohlraum experiments

    SciTech Connect (OSTI)

    Derzon, M.S.; Aubert, J.; Chandler, G.A.

    1998-06-01

    The authors performed a series of experiments on the Particle Beam Fusion Accelerator II (PBFA II) in May, 1994, and obtained a brightness temperature of 61 {+-} 2 eV for an ion-beam heated hohlraum. The hohlraum was a 4-mm-diameter, right-circular cylinder with a 1.5-mm-thick gold wall, a low-density CH foam fill, and a 1.5- or 3-mm-diameter diagnostic aperture in the top. The nominal parameters of the radially-incident PBFA II Li ion beam were 9 MeV peak energy ({approximately}10 MeV at the gas cell) at the target at a peak power of 2.5 {+-} 0.3 TW/cm{sup 2} and a 15 ns pulse width. Azimuthal variations in intensity of a factor of 3, with respect to the mean, were observed. Nonuniformities in thermal x-ray emission across the area of the diagnostic hole were also observed. Time-dependent hole-closure velocities were measured: the time-averaged velocity of {approximately}2 cm/{micro}s is in good agreement with sound speed estimates. Unfolded x-ray spectra and brightness temperatures as a function of time are reported and compared to simulations. Hole closure corrections are discussed with comparisons between XRD and bolometer measurements. Temperature scaling with power on target is also presented.

  19. Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F) as cathode materials for lithium ion battery from atomistic simulation

    SciTech Connect (OSTI)

    Lee, Sanghun Park, Sung Soo

    2013-08-15

    Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) have been investigated from atomistic simulation. In order to predict the characteristics of these materials as cathode materials for lithium ion batteries, structural property, defect chemistry, and Li{sup +} ion transportation property are characterized. The core–shell model with empirical force fields is employed to reproduce the unit-cell parameters of crystal structure, which are in good agreement with the experimental data. In addition, the formation energies of intrinsic defects (Frenkel and antisite) are determined by energetics calculation. From migration energy calculations, it is found that these flurophosphates have a 3D Li{sup +} ion diffusion network forecasting good Li{sup +} ion conducting performances. Accordingly, we expect that this study provides an atomic scale insight as cathode materials for lithium ion batteries. - Graphical abstract: Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F). Display Omitted - Highlights: • Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) are investigated from classical atomistic simulation. • The unit-cell parameters from experimental studies are reproduced by the core–shell model. • Li{sup +} ion conducting Li{sub 2}MPO{sub 4}F has a 3D Li{sup +} ion diffusion network. • It is predicted that Li/Co or Li/Ni antisite defects are well-formed at a substantial concentration level.

  20. Participating University of Connecticut

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Participating Schools University of Connecticut Trinity College Yale University University of Bridgeport Southern Connecticut State University Participating Corporations United Technologies Research Coherent-DEOS JDS-Uniphase C-Cor ASML Jetek, LLC Connecticut Symposium on Microelectronics

  1. University of Iceland Description

    E-Print Network [OSTI]

    Bristol, University of

    University of Iceland __________________________________________________________________________________________ Description The University of Iceland (Háskóli Íslands) is a state university founded in 1911. Today, the University of Iceland serves a nation of approximately 320,000 people and provides instruction for some 15

  2. Active control of the resistive wall mode with power saturation Li Li, Yue Liu, and Yueqiang Liu

    E-Print Network [OSTI]

    Liu2 1 School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian. The RWM is also often present in the reversed field pinch (RFP) devices, where the mode onset often

  3. Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li-O$_2$ battery capacity

    E-Print Network [OSTI]

    Burke, Colin M; Khetan, Abhishek; Viswanathan, Venkatasubramanian; McCloskey, Bryan D

    2015-01-01

    Among the 'beyond Li-ion' battery chemistries, nonaqueous Li-O$_2$ batteries have the highest theoretical specific energy and as a result have attracted significant research attention over the past decade. A critical scientific challenge facing nonaqueous Li-O$_2$ batteries is the electronically insulating nature of the primary discharge product, lithium peroxide, which passivates the battery cathode as it is formed, leading to low ultimate cell capacities. Recently, strategies to enhance solubility to circumvent this issue have been reported, but rely upon electrolyte formulations that further decrease the overall electrochemical stability of the system, thereby deleteriously affecting battery rechargeability. In this study, we report that a significant enhancement (greater than four-fold) in Li-O$_2$ cell capacity is possible by appropriately selecting the salt anion in the electrolyte solution. Using $^7$Li nuclear magnetic resonance and modeling, we confirm that this improvement is a result of enhanced Li...

  4. Li{sub 4}FeH{sub 6}: Iron-containing complex hydride with high gravimetric hydrogen density

    SciTech Connect (OSTI)

    Saitoh, Hiroyuki, E-mail: cyto@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Iijima, Yuki [WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Endo, Naruki [Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology, Fukushima 963-0215 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2014-07-01

    Li{sub 4}FeH{sub 6}, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900?°C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li{sub 4}FeH{sub 6} is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li{sub 4}FeH{sub 6} at moderate pressures. Li{sub 4}FeH{sub 6} can be recovered at ambient conditions where Li{sub 4}FeH{sub 6} is metastable.

  5. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte

    SciTech Connect (OSTI)

    Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2014-08-25

    Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

  6. PHILADELPHIA UNIVERSITY 2003.

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY Learning Campus)). - 2003 : . . (10) 2005 http://avicenna.philadelphia.edu.jo: #12;PHILADELPHIA UNIVERSITY * . * . * . * . "-" . - (Online Training Course

  7. PHILADELPHIA UNIVERSITY (252) (197)

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY;PHILADELPHIA UNIVERSITY / 12 28/11/2005 . Human cytogenesis18/2006. - / 2005. - Lund- Lund- . - . #12;PHILADELPHIA

  8. PHILADELPHIA UNIVERSITY 2003.

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY Learning Campus)). - 2003 : . . (10) 2005 #12;PHILADELPHIA UNIVERSITY http://avicenna.philadelphia.edu.jo: * . * . * . * . "-" . - (Online Training

  9. Electrical conductivity in Li2O2 and its role in determining capacity limitations in non-aqueous Li-O2 batteries

    E-Print Network [OSTI]

    Thygesen, Kristian

    -O2 batteries V. Viswanathan, K. S. Thygesen, J. S. Hummelshøj, J. K. Nørskov, G. Girishkumar et al limitations in non-aqueous Li-O2 batteries V. Viswanathan,1 K. S. Thygesen,2 J. S. Hummelshøj,3 J. K. Nørskov energy density battery couple. Such cells, however, show sudden death at capacities far below

  10. http://lez1.pppl.gov/pub/LiWTokamak.ps http://lez1.pppl.gov/pub/LiWTokamak.pdf

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    with Lithium Walls L. E. Zakharov, PPPL Background: A recently discovered mechanism of magnetic propulsion of withstanding the possible electromagnetic forces during potential disruptions. Electro-magnetic propulsion is smallest. The velocity of the Li streams due to magnetic propulsion is of order 10-20 m/sec and should

  11. Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Wang, Chong M.; Zuo, Pengjian; Koech, Phillip K.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-09-20

    Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially three to five times higher energy density than that of traditional lithium ion batteries. However, the dissolution and precipitation of soluble polysulfides during cycling initiate a series of key-chain reactions that significantly shorten battery life. Herein, we demonstrate that through a simple but effective strategy, significantly improved cycling performance is achieved for high sulfur loading electrodes through controlling the nucleation and precipitation of polysulfieds on the electrode surface. More than 400 or 760 stable cycling are successfully displayed in the cells with locked discharge capacity of 625 mAh g-1 or 500 mAh g-1, respectively. The nucleation and growth process of dissolved polysulfides has been electrochemically altered to confine the thickness of discharge products passivated on the cathode surface, increasing the utilization rate of sulfur while avoiding severe morphology changes on the electrode. More importantly, the exposure of new lithium metal surface to the S-containing electrolyte is also greatly reduced through this strategy, largely minimizing the anode corrosion caused by polysulfides. This work interlocks the electrode morphologies and its evolution with electrochemical interference to modulate cell performances by using Li-S system as a platform, providing different but critical directions for this community.

  12. New Mexico State University University Accounts Receivable

    E-Print Network [OSTI]

    Johnson, Eric E.

    New Mexico State University University Accounts Receivable Petty Cash Voucher - Instructions Page 1 are appropriate for the Indexes and Accounts being charged. #12;New Mexico State University University Accounts purchased in New Mexico; therefore, any tax paid will not be refunded unless assessed for labor or services

  13. University of Washington University of Washington -Bothell

    E-Print Network [OSTI]

    Brown, Sally

    University of Washington University of Washington - Bothell University of Washington - Tacoma Diver- sity Outreach & Recruitment 425.352.3254 AKelley@uwb.edu UW Tacoma Equity & Diversity http://www.tacoma.washington.edu/diversity University of Washington Tacoma, 1900 Commerce St, Box 358430 Tacoma, WA 98402-3100 Dr. Sharon Parkter

  14. University Library AMSTERDAM UNIVERSITY LIBRARY USER REGULATIONS

    E-Print Network [OSTI]

    van Rooij, Robert

    University Library AMSTERDAM UNIVERSITY LIBRARY USER REGULATIONS Regulations for the users of the libraries of the University of Amsterdam General 1. The Amsterdam University Library (from hereon: the library) is understood to mean the whole body of faculty libraries and facilities of the Library

  15. Structure and electrochemical potential simulation for the cathode material Li(1+x)V(3)O(8).

    SciTech Connect (OSTI)

    Benedek, R.; Thackeray, M. M.; Yang, L. H.

    1997-12-05

    The structure and electrochemical potential of monoclinic Li{sub 1+x}V{sub 3}O{sub 8} were calculated within the local-density-functional-theory framework by use of plane-wave-pseudopotential methods. Special attention was given to the compositions 1+x=1.2 and 1+x=4, for which x-ray diffraction structure refinements are available. The calculated low-energy configuration for 1+x=4 is consistent with the three Li sites identified in x-ray diffraction measurements and predicts the position of the unobserved Li. The location of the tetrahedrally coordinated Li in the calculated low-energy configuration for 1+x=1.5 is consistent with the structure measured by x-ray diffraction for Li{sub 1.2}V{sub 3}O{sub 8}. Calculations were also performed for the two monoclinic phases at intermediate Li compositions, for which no structural information is available. Calculations at these compositions are based on hypothetical Li configurations suggested by the ordering of vacancy energies for Li{sub 4}V{sub 3}O{sub 8} and tetrahedral site energies in Li{sub 1.5}V{sub 3}O{sub 8}. The internal energy curves for the two phases cross near 1+x=3. Predicted electrochemical potential curves agree well with experiment.

  16. Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries

    SciTech Connect (OSTI)

    Katiyar, Ram S; Gómez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

    2009-01-19

    Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation ‘Li-ion rechargeable battery’ and ‘LiCoO2 cathode’ is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

  17. Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management

    SciTech Connect (OSTI)

    Viswanathan, Vilayanur V.; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A.; Williford, Ralph E.; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

    2010-06-01

    The entropy changes (?S) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

  18. Three Li-rich K giants: IRAS 12327-6523, IRAS 13539-4153, and IRAS 17596-3952

    E-Print Network [OSTI]

    Bacham E. Reddy; David L. Lambert

    2005-03-11

    We report on spectroscopic analyses of three K giants previously suggested to be Li-rich: IRAS 12327-6523, IRAS 13539-4153, and IRAS 17596-3952. High-resolution optical spectra and the LTE model atmospheres are used to derive the stellar parameters: ($T_{\\rm eff}$, log $g$, [Fe/H]), elemental abundances, and the isotopic ratio $^{12}$C/$^{13}$C. IRAS 13539-4153 shows an extremely high Li abundance of $\\log\\epsilon$(Li) $\\approx$ 4.2, a value ten times more than the present Li abundance in the local interstellar medium. This is the third highest Li abundance yet reported for a K giant. IRAS 12327-6523 shows a Li abundances of $\\log\\epsilon$(Li)$\\approx$ 1.4. IRAS 17596-3952 is a rapidly rotating ($V{\\sin i}$ $\\approx$ 35 km s$^{-1}$) K giant with $\\log\\epsilon$(Li) $\\approx$ 2.2. Infrared photometry which shows the presence of an IR excess suggesting mass-loss. A comparison is made between these three stars and previously recognized Li-rich giants.

  19. Design and experimental testing of the performance of an outdoor LiBr/H{sub 2}O solar thermal absorption cooling system with a cold store

    SciTech Connect (OSTI)

    Agyenim, Francis; Knight, Ian; Rhodes, Michael

    2010-05-15

    A domestic-scale prototype experimental solar cooling system has been developed based on a LiBr/H{sub 2}O absorption system and tested during the 2007 summer and autumn months in Cardiff University, UK. The system consisted of a 12 m{sup 2} vacuum tube solar collector, a 4.5 kW LiBr/H{sub 2}O absorption chiller, a 1000 l cold storage tank and a 6 kW fan coil. The system performance, as well as the performances of the individual components in the system, were evaluated based on the physical measurements of the daily solar radiation, ambient temperature, inlet and outlet fluid temperatures, mass flow rates and electrical consumption by component. The average coefficient of thermal performance (COP) of the system was 0.58, based on the thermal cooling power output per unit of available thermal solar energy from the 12 m{sup 2} Thermomax DF100 vacuum tube collector on a hot sunny day with average peak insolation of 800 W/m{sup 2} (between 11 and 13.30 h) and ambient temperature of 24 C. The system produced an electrical COP of 3.6. Experimental results prove the feasibility of the new concept of cold store at this scale, with chilled water temperatures as low as 7.4 C, demonstrating its potential use in cooling domestic scale buildings. (author)

  20. IOWA STATE UNIVERSITY Department of Economics

    E-Print Network [OSTI]

    Tesfatsion, Leigh

    electric power market, capacity withholding, market power, AMES wholesale power market testbed, heat maps-7612. Co-Learning Patterns As Emergent Market Phenomena: An Electricity Market Illustration Hongyan Li as emergent market phenomena: An electricity market illustration Hongyan Li and Leigh Tesfatsion Hongyan Li

  1. ALD of Al2O3 for Highly Improved Performance in Li-Ion Batteries

    SciTech Connect (OSTI)

    Dillon, A.; Jung, Y. S.; Ban, C.; Riley, L.; Cavanagh, A.; Yan, Y.; George, S.; Lee, S. H.

    2012-01-01

    Significant advances in energy density, rate capability and safety will be required for the implementation of Li-ion batteries in next generation electric vehicles. We have demonstrated atomic layer deposition (ALD) as a promising method to enable superior cycling performance for a vast variety of battery electrodes. The electrodes range from already demonstrated commercial technologies (cycled under extreme conditions) to new materials that could eventually lead to batteries with higher energy densities. For example, an Al2O3 ALD coating with a thickness of ~ 8 A was able to stabilize the cycling of unexplored MoO3 nanoparticle anodes with a high volume expansion. The ALD coating enabled stable cycling at C/2 with a capacity of ~ 900 mAh/g. Furthermore, rate capability studies showed the ALD-coated electrode maintained a capacity of 600 mAh/g at 5C. For uncoated electrodes it was only possible to observe stable cycling at C/10. Also, we recently reported that a thin ALD Al2O3 coating with a thickness of ~5 A can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 degrees C. The ALD-coated NG electrodes displayed a 98% capacity retention after 200 charge-discharge cycles. In contrast, bare NG showed a rapid decay. Additionally, Al2O3 ALD films with a thickness of 2 to 4 A have been shown to allow LiCoO2 to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs Li/Li+. Bare LiCoO2 rapidly deteriorated in the first few cycles. The capacity fade is likely caused by oxidative decomposition of the electrolyte at higher potentials or perhaps cobalt dissolution. Interestingly, we have recently fabricated full cells of NG and LiCoO2 where we coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. We have also recently coated a binder free LiNi0.04Mn0.04Co02O2 electrode containing 5 wt% single-walled carbon nanotubes as the conductive additive and demonstrated both high rate capability as well as the ability to cycle the cathode to 5 V vrs. Li/Li+. Finally, we coated a Celgard (TM) separator and enabled stable cycling in a high dielectric electrolyte. These results will be presented in detail.

  2. Pushing the Theoretical Limit of Li-CFx Batteries: A Tale of Bi-functional Electrolyte

    SciTech Connect (OSTI)

    Rangasamy, Ezhiylmurugan; Li, Juchuan; Sahu, Gayatri; Dudney, Nancy J; Liang, Chengdu

    2014-01-01

    In a typical battery, electrodes deliver capacities less or equal the theoretical maxima of the electrode materials.1 The inert electrolyte functions solely as the ionic conductor without contribution to the cell capacity because of its distinct mono-function in the concept of conventional batteries. Here we demonstrate that the most energy-dense Li-CFx battery2 delivers a capacity exceeding the theoretical maximum of CFx with a solid electrolyte of Li3PS4 (LPS) that has dual functions: as the inert electrolyte at the anode and the active component at the cathode. Such a bi-functional electrolyte reconciles both inert and active characteristics through a synergistic discharge mechanism of CFx and LPS. Li3PS4 is known as an inactive solid electrolyte with a broad electrochemical window over 5 V.3 The synergy at the cathode is through LiF, the discharge product of CFx, which activates the electrochemical discharge of LPS at a close electrochemical potential of CFx. Therefore, the solid-state Li-CFx batteries output 126.6% energy beyond their theoretic limits without compromising the stability of the cell voltage. The extra energy comes from the electrochemical discharge of LPS, the inert electrolyte. This bi-functional electrolyte revolutionizes the concept of conventional batteries and opens a new avenue for the design of batteries with an unprecedentedly high energy density.

  3. mRNA Transcript Abundance during Plant Growth and the Influence of Li+ Exposure

    SciTech Connect (OSTI)

    Duff, M. C. [Savannah River National Laboratory, Aiken, SC (United States); Kuhne, W. W. [Savannah River National Laboratory, Aiken, SC (United States); Halverson, N. [Savannah River National Laboratory, Aiken, SC (United States); Chang, C. -S. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Kitamura, E. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Hawthorn, L. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Milliken, C. E. [Savannah River National Laboratory, Aiken, SC (United States); Caldwell, E. F. [Savannah River National Laboratory, Aiken, SC (United States); Stieve-Caldwell, E. [Savannah River National Laboratory, Aiken, SC (United States); Martinez, N. E. [Savannah River National Laboratory, Aiken, SC (United States); Colorado State University, Ft. Collins, CO (United States). Dept. of Environmental and Radiological Health Sciences; Stafford, C. [Savannah River National Laboratory, Aiken, SC (United States); Univ. of South Carolina Medical School, Columbia, SC (United States)

    2014-12-01

    Lithium (Li) toxicity in plants is, at a minimum, a function of Li+ concentration, exposure time, species and growth conditions. Most plant studies with Li+ focus on short-term acute exposures. This study examines short- and long-term effects of Li+ exposure in Arabidopsis with Li+ uptake studies and measured shoot mRNA transcript abundance levels in treated and control plants. Stress, pathogen-response and arabinogalactan protein genes were typically more up-regulated in older (chronic, low level) Li+-treatment plants and in the much younger plants from acute high-level exposures. The gene regulation behavior of high-level Li+ resembled prior studies due to its influence on: inositol synthesis, 1-aminocyclopropane-1-carboxylate synthases and membrane ion transport. In contrast, chronically-exposed plants had gene regulation responses that were indicative of pathogen, cold, and heavy-metal stress, cell wall degradation, ethylene production, signal transduction, and calcium-release modulation. Acute Li+ exposure phenocopies magnesium-deficiency symptoms and is associated with elevated expression of stress response genes that could lead to consumption of metabolic and transcriptional energy reserves and the dedication of more resources to cell development. In contrast, chronic Li+ exposure increases expression signal transduction genes. The identification of new Li+-sensitive genes and a gene-based “response plan” for acute and chronic Li+ exposure are delineated.

  4. Fusion of $^{6}$Li with $^{159}$Tb} at near barrier energies

    E-Print Network [OSTI]

    M. K. Pradhan; A. Mukherjee; P. Basu; A. Goswami; R. Kshetri; R. Palit; V. V. Parkar; M. Ray; Subinit Roy; P. Roy Chowdhury; M. Saha Sarkar; S. Santra

    2011-06-10

    Complete and incomplete fusion cross sections for $^{6}$Li+$^{159}$Tb have been measured at energies around the Coulomb barrier by the $\\gamma$-ray method. The measurements show that the complete fusion cross sections at above-barrier energies are suppressed by $\\sim$34% compared to the coupled channels calculations. A comparison of the complete fusion cross sections at above-barrier energies with the existing data of $^{11,10}$B+$^{159}$Tb and $^{7}$Li+$^{159}$Tb shows that the extent of suppression is correlated with the $\\alpha$-separation energies of the projectiles. It has been argued that the Dy isotopes produced in the reaction $^{6}$Li+$^{159}$Tb, at below-barrier energies are primarily due to the $d$-transfer to unbound states of $^{159}$Tb, while both transfer and incomplete fusion processes contribute at above-barrier energies.

  5. Washington University Financial Statements

    E-Print Network [OSTI]

    Grant, Gregory

    Washington University Financial Statements June 30, 2011 and 2010 #12;Washington University Index: (314) 206-8514, www.pwc.com/us To the Board of Trustees of Washington University In our opinion fairly, in all material respects, the financial position of Washington University (the "University

  6. ATMOSPHERIC COMPOSITION OF WEAK G BAND STARS: CNO AND Li ABUNDANCES

    SciTech Connect (OSTI)

    Adamczak, Jens; Lambert, David L., E-mail: adamczak@astro.as.utexas.edu [McDonald Observatory, University of Texas, Austin, TX 78712 (United States)

    2013-03-10

    We determined the chemical composition of a large sample of weak G band stars-a rare class of G and K giants of intermediate mass with unusual abundances of C, N, and Li. We have observed 24 weak G band stars with the 2.7 m Harlan J. Smith Telescope at the McDonald Observatory and derived spectroscopic abundances for C, N, O, and Li, as well as for selected elements from Na-Eu. The results show that the atmospheres of weak G band stars are highly contaminated with CN-cycle products. The C underabundance is about a factor of 20 larger than for normal giants and the {sup 12}C/{sup 13}C ratio approaches the CN-cycle equilibrium value. In addition to the striking CN-cycle signature the strong N overabundance may indicate the presence of partially ON-cycled material in the atmospheres of the weak G band stars. The exact mechanism responsible for the transport of the elements to the surface has yet to be identified but could be induced by rapid rotation of the main sequence progenitors of the stars. The unusually high Li abundances in some of the stars are an indicator for Li production by the Cameron-Fowler mechanism. A quantitative prediction of a weak G band star's Li abundance is complicated by the strong temperature sensitivity of the mechanism and its participants. In addition to the unusual abundances of CN-cycle elements and Li, we find an overabundance of Na that is in accordance with the NeNa chain running in parallel with the CN cycle. Apart from these peculiarities, the element abundances in a weak G band star's atmosphere are consistent with those of normal giants.

  7. Detailed Hydrographic Feature Extraction from High-Resolution LiDAR Data

    SciTech Connect (OSTI)

    Danny L. Anderson

    2012-05-01

    Detailed hydrographic feature extraction from high-resolution light detection and ranging (LiDAR) data is investigated. Methods for quantitatively evaluating and comparing such extractions are presented, including the use of sinuosity and longitudinal root-mean-square-error (LRMSE). These metrics are then used to quantitatively compare stream networks in two studies. The first study examines the effect of raster cell size on watershed boundaries and stream networks delineated from LiDAR-derived digital elevation models (DEMs). The study confirmed that, with the greatly increased resolution of LiDAR data, smaller cell sizes generally yielded better stream network delineations, based on sinuosity and LRMSE. The second study demonstrates a new method of delineating a stream directly from LiDAR point clouds, without the intermediate step of deriving a DEM. Direct use of LiDAR point clouds could improve efficiency and accuracy of hydrographic feature extractions. The direct delineation method developed herein and termed “mDn”, is an extension of the D8 method that has been used for several decades with gridded raster data. The method divides the region around a starting point into sectors, using the LiDAR data points within each sector to determine an average slope, and selecting the sector with the greatest downward slope to determine the direction of flow. An mDn delineation was compared with a traditional grid-based delineation, using TauDEM, and other readily available, common stream data sets. Although, the TauDEM delineation yielded a sinuosity that more closely matches the reference, the mDn delineation yielded a sinuosity that was higher than either the TauDEM method or the existing published stream delineations. Furthermore, stream delineation using the mDn method yielded the smallest LRMSE.

  8. Operando NMR and XRD study of chemically synthesized LiCx oxidation in a dry room environment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sacci, Robert L.; Gill, Lance W.; Hagaman, Edward W.; Dudney, Nancy J.

    2015-08-01

    We test the stability of pre-lithiated graphite anodes for Li-ion batteries in a dry room battery processing room. The reaction between LiCx and laboratory air was followed using operando NMR and x-ray diffraction as these methods are sensitive to change in Li stoichiometry in graphite. There is minimal reactivity between LiC6 and N2, CO2 or O2; however, LiC6 reacts with moisture to form lithium (hydr)oxide. The reaction rate follows zero-order kinetics with respects to intercalated lithium suggesting that lithium transport through the graphite is fast. The reaction mechanism occurs by sequential formation of higher stages LiC12, then LiC18, and thenmore »LiC24 as the hydrolysis proceeds to the formation of LixOHy and graphite end products. Slowing down the formation rate of the LixOHy passivation layer stabilizes of the higher stages.« less

  9. MODELING LIQUID METAL CORROSION IN A FERRITIC STEEL PbLi SYSTEM WITH AND WITHOUT A MAGNETIC FIELD

    E-Print Network [OSTI]

    Abdou, Mohamed

    conditions have been reproduced in the computations: (1) corrosion of ferritic-martensitic steels in purelyMODELING LIQUID METAL CORROSION IN A FERRITIC STEEL ­ PbLi SYSTEM WITH AND WITHOUT A MAGNETIC FIELD associated with corrosion of ferritic steel in the flowing eutectic alloy lead-lithium (PbLi). New computer

  10. Progress in the material development of LiCaAlF sub 6 :Cr sup 3+ laser crystals

    SciTech Connect (OSTI)

    Michelle D. Shinn.; Chase, L.L.; Caird, J.A.; Payne, S.A.; Atherton, L.J.; Kway, W.L.

    1990-03-01

    High Cr{sup 3+} doping levels, up to 8 mole percent, and low losses have been obtained with the tunable solid-state laser material LiCaAlF{sub 6}:Cr{sup 3+} (Cr:LiCAF). Measurements and calculations show that high pumping and extraction efficiencies are possible with the improved material. 13 refs., 4 figs., 1 tab.

  11. Influence of Electric Vehicles Connected to the Grid Guangbin Li (gl2423) Influence of Electric Vehicles Connected to the Grid

    E-Print Network [OSTI]

    Lavaei, Javad

    Influence of Electric Vehicles Connected to the Grid Guangbin Li (gl2423) 1/13 Influence of Electric Vehicles Connected to the Grid Guangbin Li (gl2423) 1. Introduction 1.1 Background of electric vehicles and its meaning of research An electric vehicle refers to the vehicle powered from batteries

  12. Applied Surface Science 266 (2013) 516 Interphase chemistry of Si electrodes used as anodes in Li-ion batteries

    E-Print Network [OSTI]

    Boyer, Edmond

    2013-01-01

    to the lithiation of graphite, which also contributes to the increase of the energy density of the battery. Among in Li-ion batteries Catarina Pereira-Nabaisa,b , Jolanta S´wiatowskaa, , Alexandre Chagnesb, , Franc made to increase the energy density of lithium-ion batteries (LiB), namely for electric vehicle

  13. Tunable blue light source by intracavity frequency doubling of a Cr-LiSrAIF6 laser

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Tunable blue light source by intracavity frequency doubling of a Cr- LiSrAIF6 laser Franqois-switched operation at 10 kHz was intracavity frequency doubled by using a LiIOl crystal. The 230 ns tunable blue lasers emitting in the blue-green wavelength range are expected to be the key components for optical

  14. Aalborg Universitet Influence of Li-ion Battery Models in the Sizing of Hybrid Storage Systems with

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    Aalborg Universitet Influence of Li-ion Battery Models in the Sizing of Hybrid Storage Systems, R. E. (2014). Influence of Li-ion Battery Models in the Sizing of Hybrid Storage Systems Storage Systems with Supercapacitors Cl´audio Pinto, Jorge V. Barreras, Ricardo de Castro, Erik Schaltz

  15. Ferromagnetism in Topochemically Prepared Layered Perovskite Li0.3Ni0.85La2Ti3O10

    E-Print Network [OSTI]

    Spinu, Leonard

    Ferromagnetism in Topochemically Prepared Layered Perovskite Li0.3Ni0.85La2Ti3O10 Doinita Neiner between the perovskite blocks of triple-layer Ruddlesden-Popper titanate Li2La2Ti3O10 by ion exchange

  16. CONVEX AND SEMI-NONNEGATIVE MATRIX FACTORIZATIONS: DING, LI AND JORDAN 1 Convex and Semi-Nonnegative Matrix

    E-Print Network [OSTI]

    Jordan, Michael I.

    CONVEX AND SEMI-NONNEGATIVE MATRIX FACTORIZATIONS: DING, LI AND JORDAN 1 Convex and Semi-Nonnegative Matrix Factorizations Chris Ding, Tao Li, and Michael I. Jordan Chris Ding is with the Department of California at Berkeley, CA 94720, USA. October 24, 2008 DRAFT #12;CONVEX AND SEMI-NONNEGATIVE MATRIX

  17. CONVEX AND SEMI-NONNEGATIVE MATRIX FACTORIZATIONS: DING, LI AND JORDAN 1 Convex and Semi-Nonnegative Matrix

    E-Print Network [OSTI]

    Ding, Chris

    CONVEX AND SEMI-NONNEGATIVE MATRIX FACTORIZATIONS: DING, LI AND JORDAN 1 Convex and Semi-Nonnegative Matrix Factorizations Chris Ding, Tao Li, and Michael I. Jordan Chris Ding is with the Department of California at Berkeley, CA 94720, USA. November 5, 2008 DRAFT #12;CONVEX AND SEMI-NONNEGATIVE MATRIX

  18. First Principles Prediction of Nitrogen-doped Carbon Nanotubes as a High-Performance Cathode for Li-S Batteries

    SciTech Connect (OSTI)

    Wang, Zhiguo; Niu, Xinyue; Xiao, Jie; Wang, Chong M.; Liu, Jun; Gao, Fei

    2013-07-16

    The insulating nature of sulfur and the solubility of the polysulfide in organic electrolyte are two main factors that limit the application of lithium sulfur (Li-S) battery systems. Enhancement of Li conductivity, identification of a strong adsorption agent of polysulfides and the improvement of the whole sulfur-based electrode are of great technological importance. The diffusion of Li atoms on the outer-wall, inner-wall and inter-wall spaces in nitrogen-doped double-walled carbon nanotubes (CNTs) and penetrations of Li and S atoms through the walls are studied using density functional theory. We find that N-doping does not alternate the diffusion behaviors of Li atoms throughout the CNTs, but the energy barrier for Li atoms to penetrate the wall is greatly decreased by N-doping (from ~9.0 eV to ~ 1.0 eV). On the other hand, the energy barrier for S atoms to penetrate the wall remains very high, which is caused by the formation of the chemical bonds between the S and nearby N atoms. The results indicate that Li atoms are able to diffuse freely, whereas S atoms can be encapsulated inside the N-doped CNTs, suggesting that the N-doped CNTs can be potentially used in high performance Li-S batteries.

  19. Compatibility of Lithium Salts with Solvent of the Non-Aqueous Electrolyte in Li–O2 Batteries

    SciTech Connect (OSTI)

    Du, Peng; Lu, Jun; Lau, Kah Chun; Luo, Xiangyi; Bareno, Javier; Zhang, Xiaoyi; Ren, Yang; Zhang, Zhengcheng; Curtiss, Larry A.; Sun, Yang-Kook; Amine, Khalil

    2013-02-20

    The stability of lithium salts, especially in the presence of reduced oxygen species, O2 and H2O (even in a small amount), plays an important role in the cyclability and capacity of Li–O2 cells. This combined experimental and computational study provides evidence that the stability of the electrolyte used in Li–O2 cells strongly depends on the compatibility of lithium salts with solvent. In the case of the LiPF6–1NM3 electrolyte, the decomposition of LiPF6 occurs in the cell as evidenced by in situ XRD, FT-IR and XPS analysis, which triggers the decomposition of 1NM3 solvent due to formation of HF from the decomposition of LiPF6. These reactions lead to degradation of the electrolyte and cause poor cyclability of the cell. The same reactions are not observed when LiTFSI and LiCF3SO3 are used as the lithium salts in 1NM3 solvent, or LiPF6 is used in TEGDME solvent.

  20. A synthesis of LiFePO{sub 4} starting from FePO{sub 4} under reducing atmosphere

    SciTech Connect (OSTI)

    Prosini, Pier Paolo [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome, Italy and DInESto, Drive the Innovation in Energy Storage, Via Provin (Italy); Cento, Cinzia; Masci, Amedeo; Carewska, Maria; Gislon, Paola [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome (Italy)

    2014-06-19

    A fast and easy way to produce LiFePO{sub 4} starting from FePO{sub 4}, used as iron and phosphorus source, is proposed. 5% hydrogen is employed as a reducing agent and various compounds containing lithium as lithiation agents. The selected lithiation agents included: LiCl, CH{sub 3}COOLi, LiOH, Li{sub 2}S, LiH, and Li{sub 2}CO{sub 3}. Solid state synthesis is used for the LiFePO{sub 4} preparation and the so obtained materials are structurally characterized by XRD. The materials are used to fabricate composite electrode and their specific capacity is evaluated by low rate galvanostatic charge/discharge cycles (C/10 rate). Among the various lithium salts, the acetate give rise to the LiFePO{sub 4} with the best electrochemical performance. The morphology of this material is further investigated by SEM microscopy and the specific capacity is evaluated as a function of the discharge rate and the cycle number.

  1. Fast Lithium Ion Conduction in Li2SnS3: Synthesis, Physicochemical Characterization, and Electronic Structure

    E-Print Network [OSTI]

    Holzwarth, Natalie

    Fast Lithium Ion Conduction in Li2SnS3: Synthesis, Physicochemical Characterization, and Electronic conduction. The high thermal stability, significant lithium ion conductivity, and environmental stability make Li2SnS3 a promising new solid-state electrolyte for lithium ion batteries. 1. INTRODUCTION

  2. First-principles study of LiPON and related solid electrolytes Yaojun A. Du* and N. A. W. Holzwarth

    E-Print Network [OSTI]

    Holzwarth, Natalie

    First-principles study of LiPON and related solid electrolytes Yaojun A. Du* and N. A. W. Holzwarth x=2y+3z-5, and is the most widely used solid electrolyte for thin-film batteries and a number years, especially in relation to the thin-film electrolyte LiPON, developed at Oak Ridge National

  3. Report for in-situ 7Li NMR experiment in PNNL Phase -1

    SciTech Connect (OSTI)

    Hu, Jian Zhi

    2014-08-19

    To understand the detailed local structural evolution, an in-situ 7Li NMR study was performed. An operando identification of the lithium germanide phases under various cycling regimens permitted understanding of the kinetics of phase transition between different structural phases, including the amorphous phases, and how these correlated with capacity retention. Combining data from TEM and in-situ 7Li NMR, we discovered that the phase inter-conversion during cycling was mediated by co-existing amorphous and crystalline phases, and that the high capacity observed was correlated with an over-lithiated lithium germanide phase.

  4. Surface treated natural graphite as anode material for high-power Li-ion battery applications.

    SciTech Connect (OSTI)

    Liu, J.; Vissers, D. R.; Amine, K.; Barsukov, I. V.; Henry, F.; Doniger, J.; Chemical Engineering; Superior Graphite Co.

    2006-01-01

    High power application of Li-ion battery in hybrid electrical vehicles requires low cost and safe cell materials. Among the various carbon anode materials used in lithium ion batteries, natural graphite shows the most promise with advantages in performance and cost. However, natural graphite is not compatible with propylene carbonate (PC)-based electrolytes, which have a lower melting point and improved safety characteristics. The problem with it is that the molecules of propylene carbonate intercalate with Li+ into graphite, and that frequently leads to the exfoliation of the graphite matrix.

  5. Self-limiting lithiation of electrode nanoparticles in Li-ion batteries

    SciTech Connect (OSTI)

    Drozdov, A. D., E-mail: add@teknologisk.dk [Center for Plastics Technology, Danish Technological Institute, Gregersensvej 7, Taastrup 2630 (Denmark); Department of Mechanical and Manufacturing Engineering, Aalborg University, Fibigerstraede 16, Aalborg 9220 (Denmark); Sommer-Larsen, P. [Center for Plastics Technology, Danish Technological Institute, Gregersensvej 7, Taastrup 2630 (Denmark); Claville Christiansen, J. de [Department of Mechanical and Manufacturing Engineering, Aalborg University, Fibigerstraede 16, Aalborg 9220 (Denmark)

    2013-12-14

    A model is derived for the viscoplastic behavior of a host medium driven by stress-induced diffusion of guest atoms. The constitutive equations are applied to study development of stresses in a spherical electrode particle subjected to insertion of lithium. Numerical simulation demonstrates the ability of the model to capture basic phenomena observed in anode nanoparticles under lithiation: formation of a sharp interphase between a Li-poor core and a Li-rich shell, slowing down of the interphase motion revealed as self-limiting lithiation, and growth of tensile hoop stresses near the outer surface of a particle leading to its fracture.

  6. University of Memphis University Libraries Position Description

    E-Print Network [OSTI]

    Dasgupta, Dipankar

    III. CLASSIFICATION: LIBRARY ASSISTANT III IV. NAME OF INCUMBENT: Vacant V. POSITION NO.: 1259 VI. JOBUniversity of Memphis University Libraries Position Description 1 I. DEPARTMENT: University Libraries: Collection Management, ILL & Document Delivery II. POSITION: Interlibrary Loan Library Assistant

  7. Essays on University Technology Management

    E-Print Network [OSTI]

    Drivas, Kyriakos

    2011-01-01

    of university technology management and their implicationson University Technology Management by Kyriakos Drivas Aon University Technology Management by Kyriakos Drivas

  8. San Francisco State University

    E-Print Network [OSTI]

    Ovchinnikov, Sergei

    San Francisco State University Multi-Hazard Emergency Operations Plan August 2014 Preparedness Response Recovery Mitigation #12;BLANK PAGE #12;Preface #12;BLANK PAGE #12;San Francisco State University.........................................................................................................vi Profile of San Francisco State University

  9. Michigan State University Press

    E-Print Network [OSTI]

    Liu, Taosheng

    Michigan State University Press FALL/ WINTER 2013 #12;MICHIGANSTATEUNIVERSITYPRESS This symbol MSU PRESS TITLES American Literature ........................................................... 2 .............................................................................. 7 UNIVERSITY OF CALGARY PRESS .............................. 22­24 UNIVERSITY OF MANITOBA PRESS

  10. PHILADELPHIA UNIVERSITY (301) (191)

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY : . . : (301 in Mathematics 2004 #12;PHILADELPHIA UNIVERSITY 2-. 1 Z. El-bayyari Embryonic forms of Nickel of Materials Chemistry and Physics (In review) (2005) 2005 x #12;PHILADELPHIA UNIVERSITY 5 Carol J. Hirschmugl

  11. PHILADELPHIA UNIVERSITY 160

    E-Print Network [OSTI]

    PHILADELPHIA UNIVERSITY 1.: : - - - - - 160 . 2.: (205) (283) 2005/2006 : - :(35) - :(70) - :(56) - :(22) - :(55) #12;PHILADELPHIA UNIVERSITY 3 MESM International Conference 2000 #12;PHILADELPHIA UNIVERSITY - The 4th CATAEE Conference 2002

  12. Three-phase model for the reversible lithiation/delithiation of SnO anodes in Li-ion batteries

    E-Print Network [OSTI]

    Pedersen, Andreas; Luisier, Mathieu

    2015-01-01

    Using first-principles calculations, we propose a microscopic model to explain the reversible lithiation/delithiation of tin-oxide anodes in lithium-ion batteries. When the irreversible regime ends, the anode grains consist of layers of Li-oxide separated by Sn bilayers. During the following reversible lithiation, the Li-oxide undergoes two phase transformations that give rise to a Li-enrichment of the oxide and the formation of a SnLi composite. The anode grain structure stays layered and ordered with an effective theoretical reversible capacity of 4.5 Li per Sn atom. The predicted anode volume expansion and voltage profile agree well with experiments, contrary to existing models.

  13. University of SaskatchewanUniversity of Saskatchewan Dept. of Physics andDept. of Physics and

    E-Print Network [OSTI]

    Saskatchewan, University of

    )Ph.D. Graduate Student (2009, expected graduation) 6,76,7 Li(Li( ,n), Blowfish Efficiency,n), Blowfish Efficiency spectrum with GEANT4 simulationGEANT4 simulation #12;Cell EfficienciesCell Efficiencies - Experiment

  14. University of Memphis University Libraries -Position Description

    E-Print Network [OSTI]

    Dasgupta, Dipankar

    Libraries ­ Library Information Systems II. POSITION: ILS Librarian III. CLASSIFICATION: Faculty IV. NAME of the various components of the ILMS to meet the needs of library users and library personnel. The ILS LibrarianUniversity of Memphis University Libraries - Position Description I. DEPARTMENT: University

  15. University of Memphis University Libraries -Position Description

    E-Print Network [OSTI]

    Dasgupta, Dipankar

    1 I. DEPARTMENT: University Libraries II. POSITION: ILS Librarian III. CLASSIFICATION: Faculty IV strategies to maximize the effective use of the various components of the ILMS to meet the needs of libraryUniversity of Memphis University Libraries - Position Description Description Updated: August 2010

  16. New Mexico State University University Accounts Receivable

    E-Print Network [OSTI]

    Johnson, Eric E.

    New Mexico State University University Accounts Receivable Department External Invoice UAR checks payable to: New Mexico State University. Please contact the department listed for services or items provided. NMSU Fed Tax ID #: 85-60000401. Remit Payment To: Department: MSC: New Mexico State

  17. University of Washington University of Washington

    E-Print Network [OSTI]

    Van Volkenburgh, Elizabeth

    University of Washington University of Washington President's Advisory Committee on Women PACW 2007 REPORT ON WOMEN AT UW Contact Us: pacw@u.washington.edu http://depts.washington.edu/pacw/reports/women2007 #12;University of Washington Introduction From President Emmert: One of the charges given

  18. University Library University Library Opening Hours

    E-Print Network [OSTI]

    Banaji,. Murad

    University Library University Library Opening Hours 5 June to 31 December 2015 www.le.ac.uk/library Access during non staffed service hours is with a valid Library card and access after midnight is for University of Leicester students and staff only. Friday 5 June to Sunday 27 September 2015 except Public

  19. Philadelphia University Faculty of Law

    E-Print Network [OSTI]

    1 Philadelphia University Faculty of Law PROGRAM HANDBOOK 2004-2005 Philadelphia University Mission Map #12;2 Philadelphia University Mission: Philadelphia University has been established to actively

  20. Effect of fuel rate and annealing process of LiFePO{sub 4} cathode material for Li-ion batteries synthesized by flame spray pyrolysis method

    SciTech Connect (OSTI)

    Halim, Abdul; Setyawan, Heru; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng

    2014-02-24

    In this study the effect of fuel rate and annealing on particle formation of LiFePO{sub 4} as battery cathode using flame spray pyrolysis method was investigated numerically and experimentally. Numerical study was done using ANSYS FLUENT program. In experimentally, LiFePO{sub 4} was synthesized from inorganic aqueous solution followed by annealing. LPG was used as fuel and air was used as oxidizer and carrier gas. Annealing process attempted in inert atmosphere at 700°C for 240 min. Numerical result showed that the increase of fuel rate caused the increase of flame temperature. Microscopic observation using Scanning Electron Microscopy (SEM) revealed that all particles have sphere and polydisperse. Increasing fuel rate caused decreasing particle size and increasing particles crystallinity. This phenomenon attributed to the flame temperature. However, all produced particles still have more amorphous phase. Therefore, annealing needed to increase particles crystallinity. Fourier Transform Infrared (FTIR) analysis showed that all particles have PO4 function group. Increasing fuel rate led to the increase of infrared spectrum absorption corresponding to the increase of particles crystallinity. This result indicated that phosphate group vibrated easily in crystalline phase. From Electrochemical Impedance Spectroscopy (EIS) analysis, annealing can cause the increase of Li{sup +} diffusivity. The diffusivity coefficient of without and with annealing particles were 6.84399×10{sup ?10} and 8.59888×10{sup ?10} cm{sup 2} s{sup ?1}, respectively.

  1. Multiphoton photoluminescence contrast in switched Mg:LiNbO{sub 3} and Mg:LiTaO{sub 3} single crystals

    SciTech Connect (OSTI)

    Reichenbach, P., E-mail: philipp.reichenbach@iapp.de; Kämpfe, T.; Thiessen, A.; Haußmann, A.; Eng, L. M. [Institut für Angewandte Photophysik, Technische Universität Dresden, George-Bähr-Str. 1, 01069 Dresden (Germany); Woike, T. [Institut für Strukturphysik, Technische Universität Dresden, Zellescher Weg 16, 01069 Dresden (Germany)

    2014-09-22

    We observed a multiphoton luminescence contrast between virgin and single-switched domains in Mg-doped LiNbO{sub 3} (LNO) and LiTaO{sub 3} (LTO) single crystals with different doping levels of 0–7?mol. % and 0–8?mol. %, respectively. A luminescence contrast in the range of 3% was measured between as-grown and electrically inverted domain areas in Mg:LNO samples, while the contrast reaches values of up to 30% for the Mg:LTO case. Under annealing, an exponential decay of the domain contrast was observed. The activation energy of about 1?eV being determined for the decay allowed a comparison with reported activation energies of associated defects, clearly illustrating a strong connection between thermal contrast decay and the H{sup +} and Li{sup +}-ion mobility. Finally, performing similar experiments on oxidized samples undoubtedly demonstrated that the origin of the reported luminescence contrast is strongly connected with lithium ions.

  2. New Faculty - - Purdue University

    E-Print Network [OSTI]

    $author.value

    Ph.D. University of Minnesota, 2012.Postdoc, Technische Universität München, 2012-14. Daniel Kelleher – analysis on fractals. Ph.D. University of Connecticut, ...

  3. Purdue University Probability Seminar

    E-Print Network [OSTI]

    Purdue University, Stochastic differential equations driven by loops ... University of Connecticut, Hypoelliptic heat kernel on $n$-step nilpotent Lie groups

  4. University Partners Panel

    Office of Energy Efficiency and Renewable Energy (EERE)

    Matt Tirrell, Pritzker Director and Professor, Institute for Molecular Engineering, University of Chicago Thomas Glasmacher, Facility for Rare Isotope Beams (FRIB) Project Manager, Michigan State University

  5. Electronic structure and thermoelectric properties of orthorhombic SrLiAs

    SciTech Connect (OSTI)

    Guo, Li Bin; Wang, Yuan Xu, E-mail: wangyx@henu.edu.cn; Yan, Yu Li; Yang, Gui; Yang, Jue Ming; Feng, Zhen Zhen [Institute for Computational Materials Science, School of Physics and Electronics, Henan University, Kaifeng 475004 (China)

    2014-07-21

    The electronic structure and the transport properties of orthorhombic SrLiAs were investigated using first-principles calculations and the semiclassical Boltzmann theory. It is found that the electrical conductivity along the y-direction is higher than those along other two directions, which is most likely originated from the covalent ladder-like structure formed by the Li and As atoms. Moreover, the transport properties of n-type SrLiAs are better than those of p-type one, due to the large band dispersion along the y-direction near the Fermi level. Further, the value of power factor with respect to relaxation time achieves 9.2?×?10{sup 11} W K{sup ?2}?m{sup ?1}?s{sup ?1} for n-type SrLiAs along the y-direction at 1000?K with an optimal carrier concentration of 6.5?×?10{sup 20?}cm{sup ?3}. The obtained minimum lattice thermal conductivity is comparable to those of other Zintl phase compounds.

  6. Gravity inversion using a binary formulation Richard A. Krahenbuhl* and Yaoguo Li

    E-Print Network [OSTI]

    Gravity inversion using a binary formulation Richard A. Krahenbuhl* and Yaoguo Li Gravity contrast that gives rise to zero gravity response on the surface. As a result, part of the salt structure structure using gravity data can be divided into two general categories. The first are interface inversions

  7. Fourier Law in the Alternate-Mass Hard-Core Potential Chain Baowen Li,1

    E-Print Network [OSTI]

    Li, Baowen

    Fourier Law in the Alternate-Mass Hard-Core Potential Chain Baowen Li,1 Giulio Casati,2,3,1 Jiao size. We provide convincing numerical evidence for the validity of Fourier law of heat conduction in order to obey the Fourier law of heat conduction are still not known. For noninteracting particles

  8. Effects of LiDAR-Quickbird fusion on object-oriented

    E-Print Network [OSTI]

    Lawrence, Rick L.

    Effects of LiDAR-Quickbird fusion on object-oriented classification of mountain resort development Natalie Campos Rick Lawrence Brian McGlynn Kristin Gardner Downloaded from SPIE Digital Library on 03 Nov on object-oriented classification of mountain resort development Natalie Campos, Rick Lawrence, Brian Mc

  9. Electrostatic Energy Harvester and Li-Ion Charger Circuit for Micro-Scale Applications

    E-Print Network [OSTI]

    Rincon-Mora, Gabriel A.

    of the available technologies [7]. Mobile and outdoors applications, for instance, are more likely to vibrateElectrostatic Energy Harvester and Li-Ion Charger Circuit for Micro-Scale Applications Erick O-cycle operation, smart power-aware net- work architectures, and batteries with improved energy density, the stored

  10. Architecture Evaluation for Power-Efficient FPGAs Fei Li, Deming Chen*, Lei He, Jason Cong*

    E-Print Network [OSTI]

    Chen, Deming

    Architecture Evaluation for Power-Efficient FPGAs Fei Li, Deming Chen*, Lei He, Jason Cong architecture evaluation framework, named fpgaEVA-LP, for power efficiency analysis of LUT-based FPGA architectures. Our work has several contributions: (i) We develop a mixed-level FPGA power model that combines

  11. Leaping shampoo glides on a lubricating air layer , E. Q. Li2

    E-Print Network [OSTI]

    Bonito, Andrea

    Leaping shampoo glides on a lubricating air layer S. Lee1 , E. Q. Li2 , J. O. Marston2 , A. Bonito1 unambiguously that the jet slides on a lubricating air layer. We identify this layer by looking through the pool lubricating between the jet and pool surfaces. Figure 1 shows a typical leaping shampoo jet along

  12. Large-Scale Software Unit Testing on the Grid Yaohang Li, 2

    E-Print Network [OSTI]

    Li, Yaohang

    Large-Scale Software Unit Testing on the Grid 1 Yaohang Li, 2 Tao Dong, 3 Xinyu Zhang, 4 Yongduan-scale and cost-efficient computational grid resources as a software testing test bed to support automated software unit test in a complicated system. Within this test framework, a dynamic bag-of-tasks model

  13. SEVERE PARTICULATE POLLUTION IN LANZHOU Peter C. Chu, Yuchun Chen*, Shihua Lu*, Zhenchao Li*, Yaqiong Lu**

    E-Print Network [OSTI]

    Chu, Peter C.

    SEVERE PARTICULATE POLLUTION IN LANZHOU CHINA Peter C. Chu, Yuchun Chen*, Shihua Lu*, Zhenchao Li and fall, but much worse in winter, reaching low to mid alert level of air pollution. Since 1999 increasing, and become major pollutants. The mean concentration of PM10 is 2.56 mg m-3 . Even in summer

  14. A Model Reduction Framework for Efficient Simulation of Li-Ion Batteries

    E-Print Network [OSTI]

    A Model Reduction Framework for Efficient Simulation of Li-Ion Batteries Mario Ohlberger Stephan of degradation processes in lithium-ion batteries, the modelling of cell dynamics at the mircometer scale algorithms. In this contribution we discuss the reduction of microscale battery models with the reduced basis

  15. Near-Field Electrospinning Daoheng Sun,, Chieh Chang, Sha Li, and Liwei Lin*,

    E-Print Network [OSTI]

    Lin, Liwei

    Near-Field Electrospinning Daoheng Sun,, Chieh Chang, Sha Li, and Liwei Lin*, Department on silicon-based collectors while the liquid polymer solution is supplied in a manner analogous to that of a dip pen. The minimum applied bias voltage is 600 V, and minimum electrode-to-collector distance is 500

  16. Temperature Dependence of Aliovalent-vanadium Doping in LiFePO4 Cathodes

    SciTech Connect (OSTI)

    Harrison, Katharine L; Bridges, Craig A; Paranthaman, Mariappan Parans; Idrobo Tapia, Juan C; Manthiram, Arumugam; Goodenough, J. B.; Segre, C; Katsoudas, John; Maroni, V. A.

    2013-01-01

    Vanadium-doped olivine LiFePO4 cathode materials have been synthesized by a novel low-temperature microwave-assisted solvothermal (MW-ST) method at 300 oC. Based on chemical and powder neutron/X-ray diffraction analysis, the compositions of the synthesized materials were found to be LiFe1-3x/2Vx x/2PO4 (0 x 0.2) with the presence of a small number of lithium vacancies charge-compensated by V4+, not Fe3+, leading to an average oxidation state of ~ 3.2+ for vanadium. Heating the pristine 15 % V-doped sample in inert or reducing atmospheres led to a loss of vanadium from the olivine lattice with the concomitant formation of a Li3V2(PO4)3 impurity phase; after phase segregation, a partially V-doped olivine phase remained. For comparison, V-doped samples were also synthesized by conventional ball milling and heating, but only ~ 10 % V could be accommodated in the olivine lattice in agreement with previous studies. The higher degree of doping realized with the MW-ST samples demonstrates the temperature dependence of the aliovalent-vanadium doping in LiFePO4.

  17. On Virtualizing Ethernet Switches Mark McGinley, Tao Li, and Malathi Veeraraghavan

    E-Print Network [OSTI]

    Huang, Wei

    On Virtualizing Ethernet Switches Mark McGinley, Tao Li, and Malathi Veeraraghavan 151 Engineer network switches in order to create multiple logical switches from one physical switch. The motivation of them a logical switch that could coexist with other R&E projects' logical switches, so that each would

  18. Frame-based Matching Algorithms for Optical Switches Yihan Li, Shivendra Panwar and H. Jonathan Chao

    E-Print Network [OSTI]

    Panwar, Shivendra S.

    Frame-based Matching Algorithms for Optical Switches Yihan Li, Shivendra Panwar and H. Jonathan used by fixed- length high-speed electronic switches to overcome head-of-line blocking. This is done, in every time slot, a new matching set is calculated and the switch fabric is updated to connect matched

  19. Method for improving voltage regulation of batteries, particularly Li/FeS.sub.2 thermal batteries

    DOE Patents [OSTI]

    Godshall, Ned A. (Albuquerque, NM)

    1988-01-01

    Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS.sub.2 system.

  20. DESIGN OF POWER-SPLIT HYBRID VEHICLES WITH A SINGLE PLANETARY GEAR Chiao-Ting Li

    E-Print Network [OSTI]

    Peng, Huei

    DESIGN OF POWER-SPLIT HYBRID VEHICLES WITH A SINGLE PLANETARY GEAR Chiao-Ting Li Department between gears on the planetary gearset K Final drive gear ratio on output shaft R Gear radius of the ring gear S Gear radius of the sun gear e (subscript) Engine MG (subscript) Electric machine out (subscript

  1. Packet Transmission Policies for Battery Operated Communication Systems Ye Li & Chaitali Chakrabarti

    E-Print Network [OSTI]

    Kambhampati, Subbarao

    Packet Transmission Policies for Battery Operated Communication Systems Ye Li & Chaitali In this paper, we address the problem of designing battery- friendly packet transmission policies for wireless data transmission. Our objective is to maximize the lifetime of battery for wireless devices subject

  2. Modeling of 12 September 1859 super magnetic storm Xinlin Li a,*,1

    E-Print Network [OSTI]

    Li, Xinlin

    ; received in revised form 10 June 2005; accepted 11 June 2005 Abstract Based on an estimated solar wind an updated Dst prediction model from Temerin and Li (2002), which provides a prediction efficiency of 0 in the magnetometer record could be explained by assumptions as to the condition of the solar wind that, though far

  3. Prediction of the AL index using solar wind Xinlin Li,1,2,5

    E-Print Network [OSTI]

    Li, Xinlin

    Prediction of the AL index using solar wind parameters Xinlin Li,1,2,5 Kap Soo Oh,1,3 and M are based on solar wind and magnetometer data from the year 1995. The simple model predicts the 10-min averaged AL index for 1995 using only solar wind measurements with a prediction efficiency of 0

  4. The Impact of Manufacturer Rebates on Supply Chain Profits Chung-Lun Li,2

    E-Print Network [OSTI]

    Chen, Xin

    The Impact of Manufacturer Rebates on Supply Chain Profits Xin Chen,1 Chung-Lun Li,2 Byong-Duk RheeScience (www.interscience.wiley.com). Abstract: Manufacturer rebates are commonly used as price discount tools the impact of a manufacturer rebate on the expected profits of both the manufacturer and the retailer. We

  5. High-capacity Li2Sgraphene oxide composite cathodes with stable cycling performance

    E-Print Network [OSTI]

    Cui, Yi

    such as vehicle electrification and grid energy storage. Herein, we demonstrate facile synthesis of Li2S and grid energy storage applica- tions.1­6 Although rechargeable lithium-ion batteries are widely used2S is in a fully-lithi- ated state and can be paired with lithium metal-free anodes (such as silicon

  6. Atomistic insights into Li-ion diffusion in amorphous silicon , Afif Gouissem a

    E-Print Network [OSTI]

    Sharma, Pradeep

    are a critical part of the future energy storage needs in a broad range of applica- tions: portable electronics is currently focused on understanding the basic materials science underscoring these energy storage devicesAtomistic insights into Li-ion diffusion in amorphous silicon Xin Yan a , Afif Gouissem a , Pradeep

  7. New Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy

    E-Print Network [OSTI]

    Cui, Yi

    of the active electrode materials. KEYWORDS Energy storage, lithium-sulfur battery, mesoporous carbon, silicon, California 94305 ABSTRACT Rechargeable lithium ion batteries are important energy storage devices; howeverNew Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy Yuan Yang,,§ Matthew

  8. A NEW PASSIVE CONTROLLER FOR A HYDRAULIC HUMAN POWER AMPLIFIER Perry Y. Li

    E-Print Network [OSTI]

    Li, Perry Y.

    A NEW PASSIVE CONTROLLER FOR A HYDRAULIC HUMAN POWER AMPLIFIER Perry Y. Li Department of Mechanical A new, intrinsically passive controller for hydraulic human power amplifier is presented. The hydraulic human power am- plifier is a tool that amplifies (or attenuates) the force that the hu- man exerts on it

  9. A Transmission-Constrained Unit Commitment Method Chung-Li Tseng, Shmuel S. Oren,

    E-Print Network [OSTI]

    A Transmission-Constrained Unit Commitment Method Chung-Li Tseng, Shmuel S. Oren, Department 94177, USA Abstract This paper presents a transmission-constrained unit commitmentmethod using-phase al- gorithm is devised including dual optimization, a fea- sibility phase and unit decommitment

  10. Aalborg Universitet Performance-degradation model for Li4Ti5O12-

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    of the virtual power plant will become more controllable, predictable and less variable [1]. Lithium-ion (Li. INTRODUCTION Future wind power plants (WPPs) are intended to function like todays conventional power plants improvement). This will become possible by energy storage (ES) integration in the so-called virtual power

  11. Method for improving voltage regulation of batteries, particularly Li/FeS/sub 2/ thermal batteries

    DOE Patents [OSTI]

    Godshall, N.A.

    1986-06-10

    Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS/sub 2/ system.

  12. APEX-TASK IV (A W-alloy structure, vaporized Li blanket concept)

    E-Print Network [OSTI]

    California at Los Angeles, University of

    /blanket configuration · Blanket lithium boiling analysis · First Wall/Blanket Li transpiration cooling analysis;Schematic of EVOLVE First Wall Tubes and Blanket Trays #12;A A B QF [W/m2 ] B Btoroidal Transpiration Cooled and Recommendatons · The transpiration cooled first wall seems to be a credible concept. This is a critical concept

  13. On the nuclear $(n;t)-$reaction in the three-electron ${}^{6}$Li atom

    E-Print Network [OSTI]

    Alexei M. Frolov; David M. Wardlaw

    2013-01-04

    The nuclear $(n;t)-$reaction of the three-electron ${}^{6}$Li atom with thermal/slow neutrons is considered. An effective method has been developed for determining the probabilities of formation of various atoms and ions in different bound states. We discuss a number of fundamental questions directly related to numerical computations of the final state atomic probabilities. A few appropriate variational expansions for atomic wave functions of the incident lithium atom and final helium atom and/or tritium negatively charged ion are discussed. It appears that the final ${}^4$He atom arising during the nuclear $(n,{}^{6}$Li; ${}^4$He$,t)$-reaction in the three-electron Li atom can also be created in its triplet states. The formation of the quasi-stable three-electron $e^{-}_3$ during the nuclear $(n; t)-$reaction at the Li atom is briefly discussed. Bremsstrahlung emitted by atomic electrons accelerated by the rapidly moving nuclear fragments from this reaction is analyzed. The frequency spectrum of the emitted radiation is investigated.

  14. Flexible Facility Interior Layout: A Real Options and Chung-Li Tseng

    E-Print Network [OSTI]

    Tseng, Chung-Li

    Flexible Facility Interior Layout: A Real Options Approach Tong Zhao and Chung-Li Tseng Abstract needs to constantly exercise managerial real options, such as partitioning a big unit to small units. In this situation, the interior layout can be changed easily within a short time. In this paper, we take a real-options

  15. Energy Impact of Secure Computation on a Handheld Device Zhiyuan Li

    E-Print Network [OSTI]

    Li, Zhiyuan

    Energy Impact of Secure Computation on a Handheld Device Zhiyuan Li Rong Xu Department of Computer is an important approach to save the energy consumption while improving perfor- mance for wireless networked security to the wireless network changes the relative cost of computation and commu- nication

  16. Private Mining of Association Rules Justin Zhan, Stan Matwin and LiWu Chang

    E-Print Network [OSTI]

    Matwin, Stan

    Private Mining of Association Rules Justin Zhan, Stan Matwin and LiWu Chang 1 School of Information the parties. Our focus is data sharing among two parties involved in a data mining task. We study how to share to collaboratively conduct association rule mining without disclosing their private data to each other or any other

  17. Version 11/5/99 Summary of Chapter 9: Li2O Particulate Flow Concept

    E-Print Network [OSTI]

    California at Los Angeles, University of

    are, 1. Low vapor pressure at high temperature 2. Low activation 3. Good tritium breeding capability 4 pressure requirement becomes most important. Based on ITER assessment (3), the total vapor pressure over Li2O is very low. At 1000C, the combined vapor pressure of all the possible components is about 10

  18. Stochastic reconstruction and electrical transport studies of porous cathode of Li-ion batteries

    E-Print Network [OSTI]

    Liu, Fuqiang

    are among the most viable candidates for next generation, clean, and potentially fossil fuels independent. Siddique, Amir Salehi, Fuqiang Liu* Electrochemical Energy Laboratory, Department of Materials Science of detailed understanding has stagnated the development of the next generation Li-ion batteries. The state

  19. Optical Flow Estimation using Laplacian Mesh Energy Wenbin Li Darren Cosker Matthew Brown Rui Tang

    E-Print Network [OSTI]

    Martin, Ralph R.

    Optical Flow Estimation using Laplacian Mesh Energy Wenbin Li Darren Cosker Matthew Brown Rui Tang.p.cosker,m.brown,r.tang}@bath.ac.uk Abstract In this paper we present a novel non-rigid optical flow algorithm for dense image correspondence and non-rigid registration. The algorithm uses a unique Laplacian Mesh Energy term to encourage local

  20. Nanoparticle iron-phosphate anode material for Li-ion battery Dongyeon Son

    E-Print Network [OSTI]

    Park, Byungwoo

    density.1 The graphite generally used in lithium rechargeable batteries has a capacity of 372 mNanoparticle iron-phosphate anode material for Li-ion battery Dongyeon Son School of Materials rechargeable batteries. The electrochemical properties of the nanoparticle iron phosphates were characterized

  1. Calendar aging of a Graphite/LiFePO4 cell M. Kassem,a

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Calendar aging of a Graphite/LiFePO4 cell M. Kassem,a J. Bernard,b R. Revel,b S. Pélissier,c F Rochelle, France Abstract Graphite/LFP commercial cells are stored under 3 different conditions increase is 70% or less. 1. Introduction Lithium-ion batteries are now the dominant rechargeable systems

  2. Beyond Single-Page Web Search Results Ramakrishna Varadarajan, Vagelis Hristidis, and Tao Li

    E-Print Network [OSTI]

    Li, Tao

    Beyond Single-Page Web Search Results Ramakrishna Varadarajan, Vagelis Hristidis, and Tao Li Abstract--Given a user keyword query, current Web search engines return a list of individual Web pages and stitching together relevant pieces from hyperlinked Web pages and retaining links to the original Web pages

  3. Searching the Web Using Composed Pages Ramakrishna Varadarajan Vagelis Hristidis Tao Li

    E-Print Network [OSTI]

    Hristidis, Vagelis

    Searching the Web Using Composed Pages Ramakrishna Varadarajan Vagelis Hristidis Tao Li Florida. INTRODUCTION Given a user keyword query, current Web search engines return a list of pages ranked pages containing all query keywords on-the-fly. We view a web page as a set of interconnected text

  4. Negotiation of Multilateral Security Decisions for Grid Computing Li Zhou Clifford Neuman

    E-Print Network [OSTI]

    Hwang, Kai

    Negotiation of Multilateral Security Decisions for Grid Computing Li Zhou Clifford Neuman Architecture that facilitates the collaboration in making security decisions for grid services. In particular security decisions according to the level of trust among grid service providers. 1. Introduction The grid

  5. Evolution of Landau Levels into Edge States in Graphene Guohong Li1

    E-Print Network [OSTI]

    Andrei, Eva Y.

    field), as is the case in typical graphene devices then, similar to the case in semiconductor-based 2DES,1 Evolution of Landau Levels into Edge States in Graphene Guohong Li1 , Adina Luican-Mayer1 semiconductor based two-dimensional electron systems these elegant concepts were difficult to realize because

  6. ,fv\\/Li."YL-14UD TANK OPENING FEBRUARY 2nd, 1976 -No.I.

    E-Print Network [OSTI]

    Chen, Ying

    ,fv\\/Li."YL- 14UD TANK OPENING FEBRUARY 2nd, 1976 - No.I. The main reason for going in the t terminal pulley, and No. 3 motor pulley were taken out early in December (to attend to the bearing wear of chains 1 and 3; none were taken out of chain 2. During the procedure the mounting bolts for the bearing

  7. Neural Network Training Using Stochastic PSO Xin Chen and Yangmin Li

    E-Print Network [OSTI]

    Li, Yangmin

    Neural Network Training Using Stochastic PSO Xin Chen and Yangmin Li Department is huge, when PSO algorithms are applied for NN training, the dimension of search space is so large that PSOs always converge prematurely. In this paper an improved stochastic PSO (SPSO) is presented

  8. On the Importance of Evaluating Storage Systems' $Costs Zhichao Li, Amanpreet Mukker, and Erez Zadok

    E-Print Network [OSTI]

    Zadok, Erez

    On the Importance of Evaluating Storage Systems' $Costs Zhichao Li, Amanpreet Mukker, and Erez in Storage and File Systems (HotStorage '14) Abstract Modern storage systems are becoming more complex- terize storage systems: energy efficiency, durability, and more are becoming equally important. We posit

  9. Aliovalent titanium substitution in layered mixed Li Ni-Mn-Co oxides for lithium battery applications

    SciTech Connect (OSTI)

    Kam, Kinson; Doeff, Marca M.

    2010-12-01

    Improved electrochemical characteristics are observed for Li[Ni1/3Co1/3-yMyMn1/3]O2 cathode materials when M=Ti and y<0.07, compared to the baseline material, with up to 15percent increased discharge capacity.

  10. Emergence and control of heat current from strict zero thermal bias Jie Ren* and Baowen Li

    E-Print Network [OSTI]

    Li, Baowen

    Emergence and control of heat current from strict zero thermal bias Jie Ren* and Baowen Li NUS energy transport. An open question is whether we can create and control heat current at strict zero. The emergence and control of heat current over a broad range of parameters are studied. Our results reveal

  11. Examination of the high-frequency capability of carbon nanotube FETs David L. Pulfrey *, Li Chen

    E-Print Network [OSTI]

    Pulfrey, David L.

    Examination of the high-frequency capability of carbon nanotube FETs David L. Pulfrey *, Li Chen was arranged by Jurriaan Schmitz Keywords: Carbon nanotubes Field-effect transistors High-frequency a b s t r a c t New results are added to a recent critique of the high-frequency performance of carbon nanotube

  12. LI ET AL. VOL. XXX ' NO. XX ' 000000 ' XXXX www.acsnano.org

    E-Print Network [OSTI]

    Wang, Zhong L.

    Fiber-Based Hybrid Nanogenerator for Energy Harvesting and as a Self-Powered Pressure Sensor Xiuhan Li electronic devices and sensors is a kind of green energy and have attracted worldwide atten- tion.1À4 Mechanical energy is a huge re- source in our daily life with various energy scales and types such as wind

  13. A central discontinuous Galerkin method for Hamilton-Jacobi Fengyan Li 1

    E-Print Network [OSTI]

    Li, Fengyan

    A central discontinuous Galerkin method for Hamilton-Jacobi equations Fengyan Li 1 and Sergey- cosity solutions of Hamilton-Jacobi equations. Central discontinuous Galerkin methods were originally method and therefore carry many features of both methods. Since Hamilton-Jacobi equations in general

  14. Evolving Neural Networks for Hexapod Leg Controllers Gary B. Parker and Zhiyi Li

    E-Print Network [OSTI]

    Parker, Gary B.

    Evolving Neural Networks for Hexapod Leg Controllers Gary B. Parker and Zhiyi Li Computer Science -- The incremental evolution of neural networks to control hexapod robot locomotion can be separated into two main that produces leg cycles for a hexapod robot. The robot has 12 servo effectors; two per leg to produce

  15. A Bragg grating on LiNbO? waveguide for velocity-matching of electrooptic modulators 

    E-Print Network [OSTI]

    Wang, Ruiyu

    2001-01-01

    An experimental study of the fabrication of a surface grating in a TiO? film on a LiNbO? substrate is described. Such a grating can be used to achieve velocity-matching between an optical wave and a RF signal in a slow-wave modulator structure. A 1...

  16. On Trade-Wind Cumulus Cold Pools Paquita Zuidema & Zhujun Li

    E-Print Network [OSTI]

    Zuidema, Paquita

    On Trade-Wind Cumulus Cold Pools Paquita Zuidema & Zhujun Li Reg Hill, Ludovic Bariteau, Bob - but precipitation ~ mm/day not mm/hr and no wind shear stratocumulus `squall-line' Jensen et al. 2008 tropical deep rainrate `undisturbed' `disturbed' sensible/latent Tuesday, December 6, 2011 #12;`gust' winds faster than

  17. Aalborg Universitet A novel BEV concept based on fixed and swappable li-ion battery packs

    E-Print Network [OSTI]

    Berning, Torsten

    and Control, Robotics and Mechatronics Center German Aerospace Center (DLR), Wessling, D-82234, Germany Email@fe.up.pt Abstract--In this paper a novel battery electric vehicle (BEV) concept based on a small fixed and a big swappable li-ion battery pack is proposed in order to achieve: longer range, lower initial purchase price

  18. Relative grain boundary area and energy distributions in nickel Jia Li, Shen J. Dillon 1

    E-Print Network [OSTI]

    Rohrer, Gregory S.

    Relative grain boundary area and energy distributions in nickel Jia Li, Shen J. Dillon 1 , Gregory crystallographic parameters, a quantity that will be referred to as the grain boundary energy distribution (GBED­20]. The first comprehensive measurement of the grain boundary energy distribution was carried out for Mg

  19. REVERSIBLE HYDROGEN STORAGE IN A LiBH{sub 4}-C{sub 60} NANOCOMPOSITE

    SciTech Connect (OSTI)

    Teprovich, J.; Zidan, R.; Peters, B.; Wheeler, J.

    2013-08-06

    Reversible hydrogen storage in a LiBH{sub 4}:C{sub 60} nanocomposite (70:30 wt. %) synthesized by solvent-assisted mixing has been demonstrated. During the solvent-assisted mixing and nanocomposite formation, a chemical reaction occurs in which the C{sub 60} cages are significantly modified by polymerization as well as by hydrogenation (fullerane formation) in the presence of LiBH{sub 4}. We have determined that two distinct hydrogen desorption events are observed upon rehydrogenation of the material, which are attributed to the reversible formation of a fullerane (C{sub 60}H{sub x}) as well as a LiBH4 species. This system is unique in that the carbon species (C{sub 60}) actively participates in the hydrogen storage process which differs from the common practice of melt infiltration of high surface area carbon materials with LiBH{sub 4} (nanoconfinment effect). This nanocomposite demonstrated good reversible hydrogen storage properties as well as the ability to absorb hydrogen under mild conditions (pressures as low as 10 bar H{sub 2} or temperatures as low as 150?C). The nanocomposite was characterized by TGA-RGA, DSC, XRD, LDI-TOF-MS, FTIR, 1H NMR, and APPI MS.

  20. Strong and ductile nanostructured Cu-carbon nanotube composite Hongqi Li,1,a

    E-Print Network [OSTI]

    Zhu, Yuntian T.

    . Past research effort mainly focused on the polymer/ceramic-based CNT composites5­8 and studies on metal in the CNT-metallic matrix composites has been growing rapidly for the past five years.9­21 GenerallyStrong and ductile nanostructured Cu-carbon nanotube composite Hongqi Li,1,a Amit Misra,1 Zenji

  1. A Hardware Assisted High Performance PHK Memory Manager Wentong Li Saraju P. Mohanty Krishna Kavi

    E-Print Network [OSTI]

    Kavi, Krishna

    A Hardware Assisted High Performance PHK Memory Manager Wentong Li Saraju P. Mohanty Krishna Kavi that uses hardware assistance to improve the performance of a existing software allocator (PHK allocator, and the search is in the criti- cal path of allocator performance. Hardware allocators can perform parallel

  2. Hydride transfer reaction dynamics of OD+ Li Liu, Elizabeth S. Richards, and James M. Farrara

    E-Print Network [OSTI]

    Farrar, James M.

    Hydride transfer reaction dynamics of OD+ +C3H6 Li Liu, Elizabeth S. Richards, and James M. Farrara 30 April 2007; published online 29 June 2007 The hydride transfer reaction between OD+ and C3H6 has, with maxima close to the velocity and direction of the precursor propylene beam, characteristic of direct

  3. Understanding Pedestrian Behaviors from Stationary Crowd Groups Hongsheng Li1,2

    E-Print Network [OSTI]

    Wang, Xiaogang

    Understanding Pedestrian Behaviors from Stationary Crowd Groups Shuai Yi1 Hongsheng Li1,2 Xiaogang@ee.cuhk.edu.hk lihongsheng@gmail.com xgwang@ee.cuhk.edu.hk Abstract Pedestrian behavior modeling and analysis is important are a key factor influencing pedestrian walking patterns but was largely ignored in literature

  4. Astrophysical factor for the radiative capture reaction alpha+d->Li-6+gamma 

    E-Print Network [OSTI]

    Mukhamedzhanov, AM; Schmitt, R. P.; Tribble, Robert E.; Sattarov, A.

    1995-01-01

    We consider the radiative capture process alpha+d-->Li-6+gamma at energies, E(c.m.)less than or equal to 300 keV, that are relevant for astrophysical processes. Due to the peripheral character of the reaction, the overall normalization...

  5. BGP Behavior Analysis During the August 2003 Z. Wu, E. Purpus, J. Li

    E-Print Network [OSTI]

    Lowd, Daniel

    BGP Behavior Analysis During the August 2003 Blackout Z. Wu, E. Purpus, J. Li Computer under the often hostile environments of the Internet. The East coast blackout in 2003 is an event which and Canada. The blackout affected the connectivity of 3,175 networks according to the Renesys report by Cowie

  6. On the Design of Trivium Yun Tian, Gongliang Chen, Jianhua Li

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    On the Design of Trivium Yun Tian, Gongliang Chen, Jianhua Li School of Information Security.edu.cn Abstract. eSTREAM called for new stream ciphers designed for niche areas such as exceptional performance successfully applied to it. This paper illustrates new design principles of stream ciphers based

  7. Shadow Prices vs. Vickrey Prices in Multipath Routing Parthasarathy Ramanujam, Zongpeng Li, Lisa Higham

    E-Print Network [OSTI]

    Li, Zongpeng

    Shadow Prices vs. Vickrey Prices in Multipath Routing Parthasarathy Ramanujam, Zongpeng Li, Lisa}@ucalgary.ca Abstract--Shadow price and Vickrey price are two classic metrics that can be applied to measure routing. We show that Vickrey prices provide upper-bounds for shadow prices in general, and the fine

  8. Structure and Dynamics of Colliding Plasma Jets C. K. Li,1,* D. D. Ryutov,2

    E-Print Network [OSTI]

    Structure and Dynamics of Colliding Plasma Jets C. K. Li,1,* D. D. Ryutov,2 S. X. Hu,3 M. J December 2013) Monoenergetic-proton radiographs of laser-generated, high-Mach-number plasma jets colliding favorably with results from 2D hydrodynamic simulations of multistream plasma jets, and also with results

  9. Block Copolymer Solid Battery Electrolyte with High Li-Ion Transference Number

    E-Print Network [OSTI]

    Rubloff, Gary W.

    Block Copolymer Solid Battery Electrolyte with High Li-Ion Transference Number Ayan Ghosh The electrochemical properties of a solid polymer electrolyte consisting of a diblock copolymer and lithium bis of withstanding such high voltage conditions. Unlike traditional liquid electrolytes, solid-state polymer electro

  10. Image distortion in thermoacoustic tomography caused by microwave diffraction Changhui Li,* Manojit Pramanik,

    E-Print Network [OSTI]

    Wang, Lihong

    Image distortion in thermoacoustic tomography caused by microwave diffraction Changhui Li,* Manojit-induced thermoacoustic tomography. The distortion, due to microwave diffraction in the object to be imaged, leads Thermoacoustic TA tomography TAT in biological tis- sue reconstructs the TA source distribution from the acoustic

  11. A deeper respired carbon pool in the glacial equatorial Pacific Ocean L.I. Bradtmiller a,

    E-Print Network [OSTI]

    Sachs, Julian P.

    A deeper respired carbon pool in the glacial equatorial Pacific Ocean L.I. Bradtmiller a, , R in paleoceanography. We present evidence from ten equatorial Pacific Ocean sediment cores to show that the deep Pacific Ocean likely stored more carbon during the last glacial period than the Holocene

  12. Modeling atomic force microscopy at LiNbO3 surfaces from first-principles

    E-Print Network [OSTI]

    Schmidt, Wolf Gero

    on different atomic tip models interacting with x-cut and z-cut LiNbO3 surfaces are calculated within density 30 years AFM has become a major tool for imaging and manipulating matter at the atomic scale [5]. Due of the converse piezoelectric effect to excite deformations of the sample with a metal-coated tip under alternat

  13. What is the future of Amazon f sts d li t h ?forests under climate change?

    E-Print Network [OSTI]

    Saleska, Scott

    10/11/2010 1 What is the future of Amazon f sts d li t h ?forests under climate change? -Increase kinds of philosophy in predicting Amazon future Climate Model coupled with Vegetation Dynamics Similar scenarios in history used to predict future NowPast (~21,000 years BP) Future (2100) Savana grasslands

  14. A penny-shaped cohesive crack model for material damage G. Wang, S.F. Li *

    E-Print Network [OSTI]

    Li, Shaofan

    A penny-shaped cohesive crack model for material damage G. Wang, S.F. Li * Department of Civil solids with ran- domly distributed penny-shaped cohesive micro-cracks (Barenblatt­Dugdale type). Energy are derived based on homogenization of randomly distributed penny-shaped cohesive cracks (Barenblatt

  15. Image Mining in IRIS: Integrated Retinal Information System Wynne Hsu, Mong Li Lee, Kheng Guan Goh

    E-Print Network [OSTI]

    Lee, Mong Li "Janice"

    , applies state-of- the-art data mining and image processing techniques on the retinal images to aid in the screening process. 2. Image Classification An abnormal retinal image has one or more of the following signs1 Image Mining in IRIS: Integrated Retinal Information System Wynne Hsu, Mong Li Lee, Kheng Guan

  16. Aging memory and glassiness of a driven vortex , Guohong Li1

    E-Print Network [OSTI]

    Andrei, Eva Y.

    1 Aging memory and glassiness of a driven vortex system. Xu Du1 , Guohong Li1 , Eva Y. Andrei1 , M memory, aging and nonlinear-dynamics. Glasses[1-11], interfaces[12] and fractures are some examples[13 the deviation from equilibrium. After removing the force, the system ages with time and its subsequent response

  17. Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4

    E-Print Network [OSTI]

    Cui, Yi

    nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials energy storage devices for portable electronic devices, power tools, and electrical vehicles.1-4 Anodes applied to battery researches. This work represents the first example of single nanostructure device

  18. Measurements of the Fracture Energy of Lithiated Silicon Electrodes of Li-Ion Batteries

    E-Print Network [OSTI]

    Suo, Zhigang

    Measurements of the Fracture Energy of Lithiated Silicon Electrodes of Li-Ion Batteries Matt Pharr, Cambridge, Massachusetts 02138, United States ABSTRACT: We have measured the fracture energy of lithiated of the observed cracks appear brittle in nature. By determining the condition for crack initiation, the fracture

  19. Self-adaptive Cloud Capacity Planning Yexi Jiang, Chang-shing Perng, Tao Li, Rong Chang

    E-Print Network [OSTI]

    Li, Tao

    Self-adaptive Cloud Capacity Planning Yexi Jiang, Chang-shing Perng, Tao Li, Rong Chang School}@us.ibm.com Abstract--The popularity of cloud service spurs the increas- ing demands of cloud resources to the cloud a new method for cloud capacity planning with the goal of fully utilizing the physical resources, as we

  20. Modular Dual Coolant Pb-17Li Blanket Design For ARIES-CS Compact Stellarator Power Plant

    E-Print Network [OSTI]

    Raffray, A. René

    of the study. The preferred blanket concept is a dual coolant blanket with a He- cooled ferritic steel firstModular Dual Coolant Pb-17Li Blanket Design For ARIES-CS Compact Stellarator Power Plant X.R. Wanga from the engineering effort during the second phase of ARIES-CS study on the conceptual design