Sample records for li zhanqing university

  1. Dingzeyu Li LE Schapiro (CEPSR), Columbia University

    E-Print Network [OSTI]

    Grinspun, Eitan

    Dingzeyu Li LE Schapiro (CEPSR), Columbia University West th St New York, NY , USA ( ) - dli@cs.columbia.edu http://www.cs.columbia.edu/~dli/ Education Columbia University, New York, USA Sept. - present - PhD Research, Advisor: Changxi Zheng, Columbia Computer Graphics Group, Columbia University, New York, Aug

  2. Universal Accumulators with Efficient Nonmembership Jiangtao Li1

    E-Print Network [OSTI]

    Li, Ninghui

    Universal Accumulators with Efficient Nonmembership Proofs Jiangtao Li1 , Ninghui Li2 , and Rui Xue of Illinois at Urbana-Champaign rxue@uiuc.edu Abstract. Based on the notion of accumulators, we propose a new cryptographic scheme called universal accumulators. This scheme enables one to commit to a set of values using

  3. The Senior University Ref. no. LiU-2010-00209

    E-Print Network [OSTI]

    Zhao, Yuxiao

    permeate all operations. LiU's long-term goals for the work environment are that LiU shall environment efforts is the joint cooperation agreement that the University signed with both the workers' and the student unions. ! ! The work environment efforts shall be a natural part of all daily operations. In order

  4. LI

    Office of Legacy Management (LM)

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  5. LINKPING UNIVERSITY DECISION Rector's Office 2005-09-12 Dnr LiU 1088/05-10

    E-Print Network [OSTI]

    Zhao, Yuxiao

    .D., Licentiate, Master's and undergraduate theses at LiU E-Press As a result of the decision of the University such as scientific journals). In the short term, focus will be on publishing Ph.D., Licentiate, Master

  6. Lithium Diffusion in the Post-Recombination Universe and Spatial Variation of [Li/H

    E-Print Network [OSTI]

    Maxim Pospelov; Niayesh Afshordi

    2012-08-03T23:59:59.000Z

    The observed amount of lithium for low metallicity population II stars (known as the Spite plateau) is a factor of $\\sim 3-5$ lower than the predictions of the standard cosmology. Since the observations are limited to the local Universe (halo stars, globular clusters and satellites of the Milky Way) it is possible that certain physical processes may have led to the spatial separation of lithium and local reduction of [Li/H]. We study the question of lithium diffusion after the cosmological recombination in sub-Jeans dark matter haloes, taking into account that more than 95% of lithium remains in the singly-ionized state at all times. Large scattering cross sections on the rest of the ionized gas leads to strong coupling of lithium to protons and its initial direction of diffusion coincides with that of H$^+$. In the rest frame of the neutral gas this leads to the diffusion of H$^+$ and Li$^+$ out of overdensities with the trend of reducing [Li/H] in the minima of gravitational wells relative to the primordial value. We quantify this process and argue that, with certain qualifications, it may have played a significant role in creating local lithium deficiency within the primordial dark matter haloes, comparable to those observed along the Spite plateau.

  7. A Near-Global Climatology of Single-Layer and Overlapped Clouds and Their Optical Properties Retrieved from Terra/MODIS Data Using a New Algorithm

    E-Print Network [OSTI]

    Li, Zhanqing

    Retrieved from Terra/MODIS Data Using a New Algorithm FU-LUNG CHANG Earth System Science Interdisciplinary Center, University of Maryland, College Park, College Park, Maryland ZHANQING LI Earth System Science) trapping longwave radiation in the earth­atmosphere system. Unlike many low clouds that have a cooling

  8. Bin Li, John O'Loughlin and Lee Gillam (PI) Department of Computing, FEPS, University of Surrey

    E-Print Network [OSTI]

    Gillam, Lee

    Application-Specific Service Level Agreements: Experiments in Clouds and Grids, In Antonopoulos and Gillam Journal of Grid and Utility Computing (IJGUC) ISSN (Online): 1741-8488 - ISSN (Print): 1741-847X. (In, Oxford, UK. [1] Li, B. and Gillam, L. (2009), Grid Service Level Agreements using Financial Risk Analysis

  9. Effective bending stiffness for plates with microcracks D. C. Simkins Jr, S. Li

    E-Print Network [OSTI]

    Li, Shaofan

    Effective bending stiffness for plates with microcracks D. C. Simkins Jr, S. Li Summary. C. Simkins Jr, S. Li (&) Department of Civil and Environmental Engineering, University of California

  10. LI I

    Office of Legacy Management (LM)

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  11. 07Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  12. 08Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  13. 5Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . S . D E P ABeHHeHeLi

  14. 10Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less is more:culturingProtonAPRIL/MAY9Hydrate ModelingBBe(p,HeLi

  15. Nanoscale In Situ Characterization of Li-ion Battery Electrochemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale In Situ Characterization of Li-ion Battery Electrochemistry via Scanning Ion Conductance Microscopy A. L. Lipson, R. S. Ginder, and M. C. Hersam, Northwestern University...

  16. LI Co-Facilitator Position Information & Application Leadership Institute (LI)

    E-Print Network [OSTI]

    Sheridan, Jennifer

    1 LI Co-Facilitator Position Information & Application Leadership Institute (LI) Office for Equity for the Co-Facilitator Position in the Leadership Institute. What follows is an overview of LI, a description of LI Co-Facilitator role, and the application. What is the Leadership Institute (LI)? The LI

  17. Community-Based Cloud for Emergency Management , Qingrui Li1

    E-Print Network [OSTI]

    Li, Juan "Jen"

    number of recent disasters, such as the Indonesian volcanic eruption, Gulf of Mexico oil spill, Haitian, University of New Mexico j.li@ndsu.edu, qingrui.li@ndsu.edu, samee.khan@ndsu.edu, nghani@ece.unm.edu Abstract

  18. Neutron spectroscopic factors of 7Li and astrophysical 6Li(n,g)7Li reaction rates

    E-Print Network [OSTI]

    Jun Su; Zhihong Li; Bing Guo; Xixiang Bai; Zhichang Li; Jiancheng Liu; Youbao Wang; Gang Lian; Sheng Zeng; Baoxiang Wang; Shengquan Yan; Yunju Li; Ertao Li; Qiwen Fan; Weiping Liu

    2010-01-25T23:59:59.000Z

    Angular distributions of the 7Li(6Li,6Li)7Li elastic scattering and the 7Li(6Li,7Li_{g.s.})6Li, 7Li(6Li,7Li*_{0.48})6Li transfer reactions at Ec.m. = 23.7 MeV were measured with the Q3D magnetic spectrograph. The optical potential of 6Li+7Li was obtained by fitting the elastic scattering differential cross sections. Based on the distorted wave Born approximation (DWBA) analysis, spectroscopic factors of 7Li=6Li+n were determined to be 0.73 +- 0.05 and 0.90 +- 0.09 for the ground and first exited states in 7Li, respectively. Using the spectroscopic factors, the cross sections of the 6Li(n,g)7Li direct neutron capture reactions and the astrophysical 6Li(n,g)7Li reaction rates were derived.

  19. The Leadership Institute (LI) 2011 2012: Description & Application (The Office for Equity & Diversity Learning Communities)

    E-Print Network [OSTI]

    Sheridan, Jennifer

    1 The Leadership Institute (LI) 2011 ­ 2012: Description & Application (The Office for Equity & Diversity Learning Communities) What is the Leadership Institute (LI)? The LI is a unique opportunity for honing your personal leadership capacities to support the University's strategic priorities and diversity

  20. 10Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less is more:culturingProtonAPRIL/MAY9Hydrate ModelingBBe(p,HeLiLi

  1. ON THE SOLAR RADIATION BUDGET AND THE CLOUD ABSORPTION ANOMALY DEBATE

    E-Print Network [OSTI]

    Li, Zhanqing

    ON THE SOLAR RADIATION BUDGET AND THE CLOUD ABSORPTION ANOMALY DEBATE ZHANQING LI Department-of-the-art radiative transfer models. 1. Introduction Solar radiation is the ultimate source of energy for the planet of solar radiation, which is unfortunately still fraught with large uncertainties (Wild et al. 1995; Li et

  2. Comparison of Overcharge Behavior of AlPO4-Coated LiCoO2 and LiNi0.8Co0.1Mn0.1O2 Cathode Materials in Li-Ion Cells

    E-Print Network [OSTI]

    Cho, Jaephil

    , and Research Center for Energy Conversion and Storage, Seoul National University, Seoul, Korea The overcharge in Li-Ion Cells Jaephil Cho,a, *,z Hyemin Kim,b and Byungwoo Parkb, * a Department of Applied Chemistry

  3. Department Colloquium Speaker: Jack Kalbfleisch, University of Michigan

    E-Print Network [OSTI]

    Offin, Dan

    Department Colloquium Speaker: Jack Kalbfleisch, University of Michigan Date: October 15, 2010 Time Li, and Yan Zhou from the University of Michigan. #12;

  4. A New Vision for High-Capacity Hybrid Li-ion/Li-O2 Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Introduces A New Vision for High-Capacity Hybrid Li-ionLi-O2 Batteries Diagram illustrating the CEES all-in-one vision for a high-capacity Li-ionLi-O2 cell. Illustration of CEES'...

  5. Static magnetic and microwave properties of Li-ferrite films prepared by pulsed laser deposition

    E-Print Network [OSTI]

    Patton, Carl

    Static magnetic and microwave properties of Li-ferrite films prepared by pulsed laser deposition F University, Fort Collins, Colorado 80523 Highly textured Li-ferrite films have been synthesized by pulsed approaching 1000 °C the growth mode was predominantly 333 . A similar growth mode was recently reported for Ni-ferrite

  6. Li4SiO4-Li3PO4 system as protective layer in Li-metal batteries

    E-Print Network [OSTI]

    Zhang, Liying

    2012-01-01T23:59:59.000Z

    protective layer in Li-metal batteries Liying Zhang 1 , LeiThe application of Li-metal batteries is plagued with issues

  7. Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries

    E-Print Network [OSTI]

    Jaiswal, A.

    2010-01-01T23:59:59.000Z

    12 for High Rate Li-ion Batteries A. Jaiswal 1 , C. R. Hornenext generation of Li-ion batteries for consumer electronics

  8. 6Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . S . D E 25Heα, X)Li

  9. 6Li.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . S . D E 25Heα, X)Li

  10. 8Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . SHe GeneralLi

  11. 8Li.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . SHe GeneralLi

  12. 9Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . SHeBBeLi General

  13. 9Li.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 U . SHeBBeLi General

  14. C LI CI

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling Corp -KWatertown Arsenal'.I Y.itBurrisIllLI CI -

  15. Basic Notation and Background Chi-Kwong Li

    E-Print Network [OSTI]

    Li, Chi-Kwong

    and Mary, Williamsburg, Virginia, USA; Department of Mathematics, Taiyuan University of Technology, Taiyuan Let Mn be the set (vector space/algebra) of n � n matrices. (a) One can perform A + B, AB and µA for A, B Mn and µ C. (b) One can compute the eigenvalues and eigenvectors of A Mn. Chi-Kwong Li Basic

  16. MATH 576: Quantitative Risk Management (3 credits) Instructor: Haijun Li

    E-Print Network [OSTI]

    Li, Haijun

    MATH 576: Quantitative Risk Management (3 credits) Instructor: Haijun Li Office Locations: Neill: Quantitative Risk Management, Ch 1~7, Princeton University Press, New Jersey Course Purpose This course/computational methods in quantitative risk management. Concepts and methods covered in this course can be applied

  17. Magnetic propulsion of liquid Li in tokamaks 1

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    Magnetic propulsion of liquid Li in tokamaks 1 Leonid E. Zakharov, Princeton University, Princeton of the torus. This effect of magnetic propulsion can be used for developing new approaches for protecting circumference. On the other hand, when the liquid lithium is held in a closed volume, magnetic propulsion

  18. Recovery of Li from alloys of Al- Li and Li- Al using engineered scavenger compounds

    DOE Patents [OSTI]

    Riley, W. D. (Albany, OR); Jong, B. W. (Corvallis, OR); Collins, W. K. (Albany, OR); Gerdemann, S. J. (Albany, OR)

    1994-01-01T23:59:59.000Z

    A method of producing lithium of high purity from lithium aluminum alloys using an engineered scavenger compound, comprising: I) preparing an engineered scavenger compound by: a) mixing and heating compounds of TiO2 and Li2CO3 at a temperature sufficient to dry the compounds and convert Li.sub.2 CO.sub.3 to Li.sub.2 O; and b) mixing and heating the compounds at a temperature sufficient to produce a scavenger Li.sub.2 O.3TiO.sub.2 compound; II) loading the scavenger into one of two electrode baskets in a three electrode cell reactor and placing an Al-Li alloy in a second electrode basket of the three electrode cell reactor; III) heating the cell to a temperature sufficient to enable a mixture of KCl-LiCl contained in a crucible in the cell to reach its melting point and become a molten bath; IV) immersing the baskets in the bath until an electrical connection is made between the baskets to charge the scavenger compound with Li until there is an initial current and voltage followed by a fall off ending current and voltage; and V) making a connection between the basket electrode containing engineered scavenger compound and a steel rod electrode disposed between the basket electrodes and applying a current to cause Li to leave the scavenger compound and become electrodeposited on the steel rod electrode.

  19. A Cartesian treecode for screened coulomb interactions Peijun Li a,*,1

    E-Print Network [OSTI]

    Krasny, Robert

    Krasny c,2,3 a Department of Mathematics, Purdue University, 150 N. University Street, West Lafayette author. E-mail addresses: lipeijun@math.purdue.edu (P. Li), johnston@math.umass.edu (H. Johnston), krasny@umich.edu (R. Krasny). 1 The research was supported in part by a University of Michigan Research Fellowship

  20. Impact of surface inhomogeneity on solar radiative transfer under overcast conditions

    E-Print Network [OSTI]

    Li, Zhanqing

    Impact of surface inhomogeneity on solar radiative transfer under overcast conditions Zhanqing Li1. Introduction [2] Solar radiative heating is the primary driving force of atmospheric and oceanic movements underlines the impact of surface inhomogeneity on the closure of SW radiative transfer. It also leads

  1. Significant reduction of surface solar irradiance induced by aerosols in a suburban region in northeastern China

    E-Print Network [OSTI]

    Li, Zhanqing

    Significant reduction of surface solar irradiance induced by aerosols in a suburban region in northeastern China Xiangao Xia,1 Hongbin Chen,1 Zhanqing Li,1,2 Pucai Wang,1 and Jiankai Wang1 Received 25 May region in northeastern China. Aerosol properties derived from Sun photometer measurements and aerosol

  2. Optical-Model Parameters for the C-12(li-7,li-7)c-12 Reaction at 63 and 78.7 Mev

    E-Print Network [OSTI]

    Zeller, A. F.; Lui, YW; Tribble, Robert E.; Tanner, D. M.

    1980-01-01T23:59:59.000Z

    PHYSICAL REVIE% C VOLUME 22, NUMBER 4 OCTOBER 1980 Optical model parameters for the "C('Li,'Li)"C reaction at 63 and 78.7 MeV A. F. Zeller, *Y. -W. Lui, R. E. Tribble, and D. M. Tanner Cyclot'ron Institute, Texas Ac%M University, College Station... extracted from I i inelastic scattering. 1538 ZELLER, LUI, TRIBBLE, AND TANNER 22 IV. CONCLUSION The present analysis of the 'Li scattering on "C shows that a single potential set does not ap- pear to describe the data in the energy range from 48 to 78...

  3. Anion Coordination Interactions in Solvates with the Lithium Salts LiDCTA and LiTDI

    SciTech Connect (OSTI)

    McOwen, Dennis W.; Delp, Samuel A.; Paillard, Elie; Herriot, Cristelle; Han, Sang D.; Boyle, Paul D.; Sommer, Roger D.; Henderson, Wesley A.

    2014-04-17T23:59:59.000Z

    Lithium 4,5-dicyano-1,2,3-triazolate (LiDCTA) and lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI) are two salts proposed for lithium battery electrolyte applications, but little is known about the manner in which the DCTA- and TDI- anions coordinate Li+ cations. To explore this in-depth, crystal structures are reported here for two solvates with LiDCTA: (G2)1:LiDCTA and (G1)1:LiDCTA with diglyme and monoglyme, respectively, and seven solvates with LiTDI: (G1)2:LiTDI, (G2)2:LiTDI, (G3)1:LiTDI, (THF)1:LiTDI, (EC)1:LiTDI, (PC)1:LiTDI and (DMC)1/2:LiTDI with monoglyme, diglyme, triglyme, tetrahydrofuran, ethylene carbonate, propylene carbonate and dimethyl carbonate, respectively. These latter solvate structures are compared with the previously reported acetonitrile (AN)2:LiTDI structure. The solvates indicate that the LiTDI salt is much less associated than the LiDCTA salt and that the ions in LiTDI, when aggregated in solvates, have a very similar TDI-...Li+ cation mode of coordination through both the anion ring and cyano nitrogen atoms. Such coordination facilitates the formation of polymeric ion aggregates, instead of dimers. Insight into such ion speciation is instrumental for understanding the electrolyte properties of aprotic solvent mixtures with these salts.

  4. Making Li-air batteries rechargeable: material challenges. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li-air batteries rechargeable: material challenges. Making Li-air batteries rechargeable: material challenges. Abstract: A Li-air battery could potentially provide three to five...

  5. Mixed Salts of LiTFSI and LiBOB for Stable LiFePO4-Based Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in LiTFSI-based electrolytes effectively prevents the severe corrosion to Al current collectors that often is observed in LiTFSI-based electrolytes, which have high thermal...

  6. Algorithms and Software Tools for Extracting Coastal Morphological Information from Airborne LiDAR Data

    E-Print Network [OSTI]

    Gao, Yige

    2010-07-14T23:59:59.000Z

    ALGORITHMS AND SOFTWARE TOOLS FOR EXTRACTING COASTAL MORPHOLOGICAL INFORMATION FROM AIRBORNE LiDAR DATA A Thesis by YIGE GAO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 2009 Major Subject: Geography ALGORITHMS AND SOFTWARE TOOLS FOR EXTRACTING COASTAL MORPHOLOGICAL INFORMATION FROM AIRBORNE LiDAR DATA A Thesis by YIGE GAO...

  7. Energy-Saving Control of an Unstable Valve with a MR Brake QingHui Yuan and Perry Y. Li

    E-Print Network [OSTI]

    Li, Perry Y.

    to the effect of flow induced forces, QingHui Yuan is with Eaton Corporation Innovation Center, Eden Prairie, MN. QinghuiYuan@eaton.com P. Y. Li is with the Department of Mechanical Engineering, University of Minnesota

  8. Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries Hyunjung Lee an increase in the cut-off voltage of the cell from 4.2 V to 4.4 V (vs. graphite). As an alterna- tive, we can

  9. Li Tec | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |Jilin Zhongdiantou NewKoreaLaorLeopold Kostal GmbHLi County JiaxingLiLi

  10. Capacity Fade Studies of LiCoO2 Based Li-ion Cells Cycled at

    E-Print Network [OSTI]

    Popov, Branko N.

    in capacity of commercially available Sony 18650 Cells cycled at different temperatures. Perform rate of a Sony 18650 Li-ion cell Cathode (positive electrode) - LiCoO2. Anode (negative electrode) - MCMB. Cell capacity ­ 1.8 Ah #12;Characteristics of a Sony 18650 Li-ion cell Characteristics Positive LiCoO2 Negative

  11. Interactions and dynamics in Li+Li2 ultracold collisions Marko T. Cvitas,a

    E-Print Network [OSTI]

    Honvault, Pascal

    Interactions and dynamics in Li+Li2 ultracold collisions Marko T. Cvitas,a Pavel Soldán electronic state 4 A of lithium trimer is developed and used to study spin-polarized Li+Li2 collisions There is great interest in the properties of molecules formed in laser-cooled atomic gases by processes

  12. Facile synthesis of Li2Spolypyrrole composite structures for high-performance Li2S cathodes

    E-Print Network [OSTI]

    Cui, Yi

    Facile synthesis of Li2S­polypyrrole composite structures for high-performance Li2S cathodes Zhi demon- strate facile, in situ synthesis of Li2S­polypyrrole composites for use as high-performance Li2S polysulfides during cycling. Poly- pyrrole, being a conducting polymer, also helps to facilitate elec- tronic

  13. Jean Louis BRIAUD1 TEXAS A&M UNIVERSITY

    E-Print Network [OSTI]

    Briaud, Jean Louis

    &M UNIVERSITY i Li= 1.25DL + EQLL+1.0EQ Para Sismos 2 #12;3 VALORES IMPORTANTES DE FACTORES RESISTENCIA PARA

  14. Rechargeable Li/CO2O2 (2 : 1) battery and Li/CO2 Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen

    E-Print Network [OSTI]

    Wang, Wei Hua

    Rechargeable Li/CO2­O2 (2 : 1) battery and Li/CO2 battery Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen A Li/CO2­O2 (2 : 1, volume ratio) battery and a Li/CO2 battery with discharging specific capacities of 1808 mA h gÀ1 and 1032 mA h gÀ1 , respectively, are reported. Li2CO3 is the main discharge

  15. THE {sup 7}Li/{sup 6}Li ISOTOPE RATIO NEAR THE SUPERNOVA REMNANT IC 443

    SciTech Connect (OSTI)

    Taylor, C. J.; Ritchey, A. M.; Federman, S. R. [Department of Physics and Astronomy, University of Toledo, Toledo, OH 43606 (United States); Lambert, D. L., E-mail: corbin.taylor@rockets.utoledo.edu, E-mail: steven.federman@utoledo.edu, E-mail: aritchey@astro.washington.edu, E-mail: dll@astro.as.utexas.edu [W. J. McDonald Observatory, University of Texas at Austin, Austin, TX 78712 (United States)

    2012-05-01T23:59:59.000Z

    We present an analysis of {sup 7}Li/{sup 6}Li isotope ratios along four sight lines that probe diffuse molecular gas near the supernova remnant IC 443. Recent gamma-ray observations have revealed the presence of shock-accelerated cosmic rays interacting with the molecular cloud surrounding the remnant. Our results indicate that the {sup 7}Li/{sup 6}Li ratio is lower in regions more strongly affected by these interactions, a sign of recent Li production by cosmic rays. We find that {sup 7}Li/{sup 6}Li Almost-Equal-To 7 toward HD 254755, which is located just outside the visible edge of IC 443, while {sup 7}Li/{sup 6}Li Almost-Equal-To 3 along the line of sight to HD 43582, which probes the interior region of the supernova remnant. No evidence of {sup 7}Li synthesis by neutrino-induced spallation is found in material presumably contaminated by the ejecta of a core-collapse supernova. The lack of a neutrino signature in the {sup 7}Li/{sup 6}Li ratios near IC 443 is consistent with recent models of Galactic chemical evolution, which suggest that the {nu}-process plays only a minor role in Li production.

  16. Asymptotic normalization coefficients for B-8 -> Be-7+p from a study of Li-8 -> Li-7+n

    E-Print Network [OSTI]

    Trache, L.; Azhari, A.; Carstoiu, F.; Clark, HL; Gagliardi, Carl A.; Lui, YW; Mukhamedzhanov, AM; Tang, X.; Timofeyuk, N.; Tribble, Robert E.

    2003-01-01T23:59:59.000Z

    nuclei, and charge symmetry implies that the spectroscopic amplitudes for the proton single particle orbitals entering the 8B wave 0556-2813/2003/67~6!/062801~5!/$20.00 67 062801- B\\7Be?p from a study of 8Li\\7Li?n ,1 Y.-W. Lui,1 A. M. Mukhamedzhanov.../Oxford University Press, New York, 1983!. @29# L. Trache, A. Azhari, H.L. Clark, C.A. Gagliardi, Y.-W. Lui, A.M. Mukhamedzhanov, R.E. Tribble, and F. Carstoiu, Phys. Rev. C 61, 024612 ~2000!. @30# M. Rhoades-Brown, M.H. Macfarlane, and S.C. Pieper, Phys. Rev. C...

  17. Thermal Stability of LiPF6 Salt and Li-ion Battery ElectrolytesContaining LiPF6

    SciTech Connect (OSTI)

    Yang, Hui; Zhuang, Guorong V.; Ross Jr., Philip N.

    2006-03-08T23:59:59.000Z

    The thermal stability of the neat LiPF6 salt and of 1 molal solutions of LiPF6 in prototypical Li-ion battery solvents was studied with thermogravimetric analysis (TGA) and on-line FTIR. Pure LiPF6 salt is thermally stable up to 380 K in a dry inert atmosphere, and its decomposition path is a simple dissociation producing LiF as solid and PF5 as gaseous products. In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF6 and water vapor to form POF3 and HF. No new products were observed in 1 molal solutions of LiPF6 in EC, DMC and EMC by on-line TGA-FTIR analysis. The storage of the same solutions in sealed containers at 358 K for 300 420 hrs. did not produce any significant quantity of new products as well. In particular, noalkylflurophosphates were found in the solutions after storage at elevated temperature. In the absence of either an impurity like alcohol or cathode active material that may (or may not) act as a catalyst, there is no evidence of thermally induced reaction between LiPF6 and the prototypical Li-ion battery solvents EC, PC, DMC or EMC.

  18. BEST IN THE WEST Portland State University is one of the best colleges and universi-

    E-Print Network [OSTI]

    Bertini, Robert L.

    Syracuse University University of California­Santa Cruz University of Maryland University of Michigan University of Michigan University of Notre Dame University of Pennsylvania Partial liBEST IN THE WEST Portland State University is one of the best colleges and universi- ties

  19. Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Growth Process of Li2S2Li2S in Lithium-Sulfur Batteries. Abstract: Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially...

  20. Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hu, JH Kwak, and Z Yang.2009."Low Temperature Milling of the LiNH2 + LiH Hydrogen Storage System."International Journal of Hydrogen Energy 34(10):4331-4339. doi:10.1016...

  1. Coulomb dissociation of [sup 11]Li

    SciTech Connect (OSTI)

    Ieki, K.; Sackett, D.; Galonsky, A.; Bertulani, C.A.; Kruse, J.J.; Lynch, W.G.; Morrissey, D.J.; Orr, N.A.; Schulz, H.; Sherrill, B.M.; Sustich, A.; Winger, J.A. (National Superconducting Cyclotron Laboratory and Department of Physics, Michigan State Unversity, East Lansing, Michigan 48824 (United States)); Deak, F.; Horvath, A.; Kiss, A. (Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7 H-1088 Budapest 8 (Hungary)); Seres, Z. (KFKI Research Institute for Particle and Nuclear Physics of the Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary)); Kolata, J.J. (Department of Physics, University of Notre Dame, Notre Dame, Indiana 46556 (United States)); Warner, R.E. (Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States)); Humphrey, D.L. (Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States))

    1993-02-08T23:59:59.000Z

    Kinematically complete measurements for Coulomb dissociation of [sup 11]Li into [sup 9]Li+2[ital n] were made at 28 MeV/nucleon. The [ital n]-[ital n] correlation function suggests a large source size for the two-neutron emission. The electromagnetic excitation spectrum of [sup 11]Li has a peak, as anticipated in low-energy dipole resonance models, but a large post-breakup Coulomb acceleration of the [sup 9]Li fragment is observed, indicating a very short lifetime of the excited state and favoring direct breakup as the dissociation mechanism.

  2. A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries

    E-Print Network [OSTI]

    1 A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries: Power of a commercial LiFePO4-graphite Li-ion battery. Compared to the isothermal reference, the mechanism of porosity;2 Due to their high power and energy densities, Li-ion technologies are the leading battery systems

  3. 08LI_1~1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) - Energy Innovation Portal AdvancedUsingLi Thermal1

  4. 09LI_1~1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) - Energy Innovation Portal AdvancedUsingLi6,6,0 Dear093, 2009

  5. biogas to indian buses come home, dad biosensor lab in singapore sexy statistics world university No reason to rush homeLiU alumna Klara Tiitso enjoys her life in London | page 30

    E-Print Network [OSTI]

    Zhao, Yuxiao

    biogas to indian buses come home, dad biosensor lab in singapore sexy statistics world university | page 30 Hearing is about communication Excellence centre focus on cognitive aspects | page 19 Biofuel, but the experience in Malaysia taught us a few lessons: It showed how vulnerable global communication is, but

  6. A Memory Soft Error Measurement on Production Systems Xin Li Kai Shen Michael C. Huang

    E-Print Network [OSTI]

    Shen, Kai

    A Memory Soft Error Measurement on Production Systems Xin Li Kai Shen Michael C. Huang University and dealing with these soft (or transient) errors is impor- tant for system reliability. Several earlier for memory soft error measurement on production systems where performance impact on existing running ap

  7. A Memory Soft Error Measurement on Production Systems # Xin Li Kai Shen Michael C. Huang

    E-Print Network [OSTI]

    Shen, Kai

    A Memory Soft Error Measurement on Production Systems # Xin Li Kai Shen Michael C. Huang University and dealing with these soft (or transient) errors is impor­ tant for system reliability. Several earlier for memory soft error measurement on production systems where performance impact on existing running ap

  8. Earth Observations for rapid response to large earthquakes Supervisors: Dr Zhenhong Li and Prof Trevor Hoey

    E-Print Network [OSTI]

    Guo, Zaoyang

    Earth Observations for rapid response to large earthquakes Supervisors: Dr Zhenhong Li and Prof Trevor Hoey School of Geographical and Earth Sciences, University of Glasgow, UK Earthquakes, together of the earth system; they are messengers of the fundamental processes that shape the surface of the Earth

  9. MOTION CONTROL OF AN OMNIDIRECTIONAL MOBILE ROBOT Xiang Li, Andreas Zell

    E-Print Network [OSTI]

    Zell, Andreas

    MOTION CONTROL OF AN OMNIDIRECTIONAL MOBILE ROBOT Xiang Li, Andreas Zell Wilhelm-Schickard-Institute, Departmant of Computer Architecture, University of T¨ubingen, Sand 1, 72076 T¨ubingen, Germany xiang, actuator saturation, path following control. Abstract: This paper focuses on the motion control problem

  10. Optimal Provisioning of Elastic Service Availability Dahai Xu Ying Li Mung Chiang A. Robert Calderbank

    E-Print Network [OSTI]

    Papadopouli, Maria

    Optimal Provisioning of Elastic Service Availability Dahai Xu Ying Li Mung Chiang A. Robert University, NJ 08544, USA Abstract-- Service availability is one of the most closely scruti- nized metrics higher service availability at the cost of higher operational expense. It is important to cost

  11. Computer Vision Technology for Applications to Assist Blind Dr. Ying-Li Tian, Associate Professor

    E-Print Network [OSTI]

    Zhu, Zhigang

    Professor Dept of Electrical Engineering The City College, City University of New York Time: 2:00 pm, March-Li Tian is an associate professor in the Department of Electrical Engineering at the City College of New of the inventors of the IBM Smart Surveillance Solutions (SSS) product and was leading the video analytics team

  12. Profile-Driven Energy Reduction in Network-on-Chips Feihui Li, Guangyu Chen, Mahmut Kandemir

    E-Print Network [OSTI]

    Budiu, Mihai

    connect and manage communications among a variety of design elements and Intellectual Property (IP) blocksProfile-Driven Energy Reduction in Network-on-Chips Feihui Li, Guangyu Chen, Mahmut Kandemir Department of computer Science and Engineering The Pennsylvania State University, USA {feli

  13. An Analysis of Facebook Photo Caching Qi Huang, Ken Birman, Robbert van Renesse, Wyatt Lloyd, Sanjeev Kumar, Harry C. Li

    E-Print Network [OSTI]

    Keinan, Alon

    An Analysis of Facebook Photo Caching Qi Huang, Ken Birman, Robbert van Renesse, Wyatt Lloyd, Sanjeev Kumar, Harry C. Li Cornell University, Princeton University, Facebook Inc. Abstract This paper examines the workload of Facebook's photo- serving stack and the effectiveness of the many layers

  14. Electrochemistry of LiCl-Li2O-H2O Molten Salt Systems

    SciTech Connect (OSTI)

    Natalie J. Gese; Batric Pesic

    2013-03-01T23:59:59.000Z

    Uranium can be recovered from uranium oxide (UO2) spent fuel through the combination of the oxide reduction and electrorefining processes. During oxide reduction, the spent fuel is introduced to molten LiCl-Li2O salt at 650 degrees C and the UO2 is reduced to uranium metal via two routes: (1) electrochemically, and (2) chemically by lithium metal (Li0) that is produced electrochemically. However, the hygroscopic nature of both LiCl and Li2O leads to the formation of LiOH, contributing hydroxyl anions (OH-), the reduction of which interferes with the Li0 generation required for the chemical reduction of UO2. In order for the oxide reduction process to be an effective method for the treatment of uranium oxide fuel, the role of moisture in the LiCl-Li2O system must be understood. The behavior of moisture in the LiCl-Li2O molten salt system was studied using cyclic voltammetry, chronopotentiometry and chronoamperometry, while reduction to hydrogen was confirmed with gas chromatography.

  15. Characterization of Li-ion Batteries using Neutron Diffraction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques Characterization of Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques 2011 DOE...

  16. Characterization of Materials for Li-ion Batteries: Success Stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program Characterization of Materials for Li-ion Batteries: Success...

  17. DFT+U Study of Polaronic Conduction in Li2O2 and Li2CO3: Implications for Li-Air Batteries

    E-Print Network [OSTI]

    Thygesen, Kristian

    DFT+U Study of Polaronic Conduction in Li2O2 and Li2CO3: Implications for Li-Air Batteries J. M-air batteries are known to be Li2O2 and residual Li2CO3. Recent experiments indicate that the charge transport through these materials is the main limiting factor for the battery performance. It has been also shown

  18. Brandeis University Brown University

    E-Print Network [OSTI]

    Jiang, Huiqiang

    Institute of Technology McGill University Michigan State University New York University Northwestern University of Kansas University of Maryland, College Park University of Michigan University of MinnesotaBrandeis University Brown University California Institute of Technology Carnegie Mellon University

  19. Superplastic forming characteristics of 2090 (OE-16) and 8090 (SP) Al-Li alloys

    E-Print Network [OSTI]

    Khazi-Syed, Razaq H.

    1992-01-01T23:59:59.000Z

    SUPERPLASTIC FORMING CHARACTERISTICS OF 2090 (OE-16) AND 8090 (SP) AL-LI ALLOYS A Thesis by RAZAQ H. KHAZI-SYED Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 1992 Major Subject: Mechanical Engineering SUPERPLASTIC FORMING CHARACTERISTICS OF 2090(OE-16) AND 8090 (SP) AL-LI ALLOYS A Thesis by RAZAQ H. KHAZI-SYED Approved as to style and content by: R. E. Goforth (Chair...

  20. Materials for Better Li-based Storage Systems for a "Green Energy Society"

    SciTech Connect (OSTI)

    Jean-Marie Tarascon

    2009-09-18T23:59:59.000Z

    Li-ion batteries are strongly considered for powering the upcoming generations of HEVs and PHEVs, but there are still the issues of safety and costs in terms of materials resources and abundances, synthesis, and recycling processes. Notions of materials having minimum footprint in nature, made via eco-efficient processes, must be integrated in our new research towards the next generation of sustainable and "greener" Li-ion batteries. In this July 13, 2009 talk sponsored by Berkeley Lab's Environental Energy Technologies Division, Jean-Marie Tarascon, a professor at the University of Picardie (Amiens), discuss Eco-efficient synthesis via hydrothermal/solvothermal processes using latent bases as well as structure directing templates or other bio-related approaches of LiFePO4 nanopowders.

  1. Materials for Better Li-based Storage Systems for a "Green Energy Society"

    ScienceCinema (OSTI)

    Jean-Marie Tarascon

    2010-01-08T23:59:59.000Z

    Li-ion batteries are strongly considered for powering the upcoming generations of HEVs and PHEVs, but there are still the issues of safety and costs in terms of materials resources and abundances, synthesis, and recycling processes. Notions of materials having minimum footprint in nature, made via eco-efficient processes, must be integrated in our new research towards the next generation of sustainable and "greener" Li-ion batteries. In this July 13, 2009 talk sponsored by Berkeley Lab's Environental Energy Technologies Division, Jean-Marie Tarascon, a professor at the University of Picardie (Amiens), discuss Eco-efficient synthesis via hydrothermal/solvothermal processes using latent bases as well as structure directing templates or other bio-related approaches of LiFePO4 nanopowders.

  2. Active control of the resistive wall mode with power saturation Li Li, Yue Liu, and Yueqiang Liu

    E-Print Network [OSTI]

    Active control of the resistive wall mode with power saturation Li Li, Yue Liu, and Yueqiang Liu://pop.aip.org/about/rights_and_permissions #12;Active control of the resistive wall mode with power saturation Li Li,1,a) Yue Liu,1 and Yueqiang, 116024, People's Republic of China 2 Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX

  3. Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li+ ion transport in LiNi0.5Mn1.5O4 through Control of Site Disorder. Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through Control of Site Disorder. Abstract: High voltage spinel...

  4. Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries

    E-Print Network [OSTI]

    Cui, Yi

    Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries Hyun diameters less than 10 nm and lengths of several micrometers. Galvanostatic battery testing showed that Li, lithium ion battery, LiMn2O4 nanowires, high power density, Jahn-Teller distortion T he high energy

  5. Asymptotic normalization coefficients for B-8 -> Be-7+p from a study of Li-8 -> Li-7+n 

    E-Print Network [OSTI]

    Trache, L.; Azhari, A.; Carstoiu, F.; Clark, HL; Gagliardi, Carl A.; Lui, YW; Mukhamedzhanov, AM; Tang, X.; Timofeyuk, N.; Tribble, Robert E.

    2003-01-01T23:59:59.000Z

    Asymptotic normalization coefficients (ANCs) for Li-8-->Li-7+n have been extracted from the neutron transfer reaction C-13(Li-7,Li-8)C-12 at 63 MeV. These are related to the ANCs in B-8-->Be-7 + p using charge symmetry. ...

  6. Simplified Electrochemical and Thermal Model of LiFePO4-Graphite Li-Ion Batteries for Fast Charge Applications

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Simplified Electrochemical and Thermal Model of LiFePO4- Graphite Li-Ion Batteries for Fast Charge, a simplified electrochemical and thermal model of LiFePO4-graphite based Li-ion batteries is developed for battery management system (BMS) applications and comprehensive aging investigations. Based on a modified

  7. Comment on Li pellet Conditioning in TFTR

    SciTech Connect (OSTI)

    R.V. Budny

    2011-05-23T23:59:59.000Z

    Li pellet conditioning in TFTR results in a reduction of the edge electron density which allows increased neutral beam penetration, central heating, and fueling. Consequently the temperature profiles became more peaked with higher central Ti, Te, and neutron emission rates.

  8. Negative Electrodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Kinoshita, Kim; Zaghib, Karim

    2001-10-01T23:59:59.000Z

    Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

  9. Ambient Operation of Li/Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Wang, Deyu; Xu, Wu; Xiao, Jie; Williford, Ralph E.

    2010-07-01T23:59:59.000Z

    In this work, Li/air batteries based on nonaqueous electrolytes were investigated in ambient conditions (with an oxygen partial pressure of 0.21 atm and relative humidity of ~20%). A heat-sealable polymer membrane was used as both an oxygen-diffusion membrane and as a moisture barrier for Li/air batteries. The membrane also can minimize the evaporation of the electrolyte from the batteries. Li/air batteries with this membrane can operate in ambient conditions for more than one month with a specific energy of 362 Wh kg-1, based on the total weight of the battery including its packaging. Among various carbon sources used in this work, Li/air batteries using Ketjenblack (KB) carbon-based air electrodes exhibited the highest specific energy. However, KB-based air electrodes expanded significantly and absorbed much more electrolyte than electrodes made from other carbon sources. The weight distribution of a typical Li/air battery using the KB-based air electrode was dominated by the electrolyte (~70%). Lithium-metal anodes and KB-carbon anodes account for only 5.12% and 5.78% of the battery weight, respectively. We also found that only ~ 20% of the mesopore volume of the air electrode was occupied by reaction products after discharge. To further improve the specific energy of the Li/air batteries, the microstructure of the carbon electrode needs to be further improved to absorb much less electrolyte while still holding significant amounts of reaction products

  10. Li-Ion Battery with LiFePO4 Cathode and Li4Ti5O12 Anode for Stationary Energy Storage

    SciTech Connect (OSTI)

    Wang, Wei; Choi, Daiwon; Yang, Zhenguo

    2013-01-01T23:59:59.000Z

    i-ion batteries based on commercially available LiFePO4 cathode and Li4Ti5O12 anode were investigated for potential stationary energy storage applications. The full cell that operated at flat 1.85V demonstrated stable cycling for 200 cycles followed by a rapid fade. A significant improvement in cycling stability was achieved via Ketjen black coating of the cathode. A Li-ion full cell with Ketjen black modified LiFePO4 cathode and an unmodified Li4Ti5O12 anode exhibited negligible fade after more than 1200 cycles with a capacity of ~130mAh/g. The improved stability, along with its cost-effectiveness, environmentally benignity and safety, make the LiFePO4/ Li4Ti5O12 Li-ion battery a promising option of storing renewable energy.

  11. Email Archive Analysis Through Graphical Visualization Columbia University

    E-Print Network [OSTI]

    Yang, Junfeng

    Email Archive Analysis Through Graphical Visualization Wei-Jen Li Columbia University weijen@cs.columbia.edu Shlomo Hershkop Columbia University shlomo@cs.columbia.edu Salvatore J. Stolfo Columbia University sal@cs.columbia (EMT) developed at Columbia University [3] is a data mining system that computes behavior profiles

  12. Excitation functions of {sup 6,7}Li+{sup 7}Li reactions at low energies

    SciTech Connect (OSTI)

    Prepolec, L.; Soic, N.; Blagus, S.; Miljanic, D.; Siketic, Z.; Skukan, N.; Uroic, M. [Ruder Boskovic Institute, Bijenicka c. 54, HR-10000 Zagreb (Croatia); Milin, M. [Faculty of Science, University of Zagreb, Bijenicka c. 32, HR-10000 Zagreb (Croatia)

    2009-08-26T23:59:59.000Z

    Differential cross sections of {sup 6,7}Li+{sup 7}Li nuclear reactions have been measured at forward angles (10 deg. and 20 deg.), using particle identification detector telescopes, over the energy range 2.75-10.00 MeV. Excitation functions have been obtained for low-lying residual-nucleus states. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) at beam energy about 8 MeV, first observed by Wyborny and Carlson in 1971 at 0 deg., has been observed at 10 deg., but is less evident at 20 deg. The cross section obtained for the {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(g.s,0{sup +}) reaction is about ten times smaller. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) reaction could correspond to excited states in {sup 14}C, at excitation energies around 30 MeV.

  13. Tracking Cardinality Distributions in Network Aiyou Chen, Li Li and Jin Cao

    E-Print Network [OSTI]

    Li, Li Erran

    Tracking Cardinality Distributions in Network Traffic Aiyou Chen, Li Li and Jin Cao Bell Labs distributions of distinct communicating peers or flows. For example, during the worm outbreak, the port scanning in the host distributions of distinct communicating peers or flows. In this paper, we develop an efficient

  14. REGULAR ARTICLE Variational grand-canonical electronic structure of Li+Li

    E-Print Network [OSTI]

    Baer, Roi

    , is applied to the di-lithium (Li?Li) system at temperatures around T & 104 K and electronic chemical the other is ``spin polarized''. This crossing causes near-dis- continuous jumps in calculated properties in strong laser interaction with matter, nuclear and shock- wave physics, astrophysics, and liquid metals [1

  15. Minimum-Energy Topology Control Algorithms in Ad Hoc Joseph Y. Halpern Li (Erran) Li

    E-Print Network [OSTI]

    Halpern, Joseph Y.

    for an extended period of time. In order to accomplish this without a renewable energy source, energy conservationMinimum-Energy Topology Control Algorithms in Ad Hoc Networks1 Joseph Y. Halpern Li (Erran) Li Dept Holmdel, NJ 07733 halpern@cs.cornell.edu erranlli@dnrc.bell-labs.com August 7, 2004 1 Based on "Minimum-Energy

  16. CMOSET 2006Digitally Controlled SMPS 1University of Toronto

    E-Print Network [OSTI]

    Ng, Wai Tung

    ) Power Source · Li-ion · Li-Polymer · Fuel Cell ? #12;CMOSET 2006Digitally Controlled SMPS 5University Protection · UVLO, OVP · OCP, soft-start, etc. · Diagnostics, synchronization "SMART" Features · Multi-mode operation (PWM, PFM, DCM) · Diagnostics · Fully configurable Cost · Size of passives (L,C) · Parts count

  17. Rate-dependent morphology of Li2O2 growth in Li-O2 batteries

    E-Print Network [OSTI]

    Horstmann, B; Mitchell, R; Bessler, W G; Shao-Horn, Y; Bazant, M Z

    2013-01-01T23:59:59.000Z

    Compact solid discharge products enable energy storage devices with high gravimetric and volumetric energy densities, but solid deposits on active surfaces can disturb charge transport and induce mechanical stress. In this Letter we develop a nanoscale continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes, based on a theory of electrochemical non-equilibrium thermodynamics originally applied to Li-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory predicts a transition from complex to uniform morphologies of Li2O2 with increasing current. Discrete particle growth at low discharge rates becomes suppressed at high rates, resulting in a film of electronically insulating Li2O2 that limits cell performance. We predict that the transition between these surface growth modes occurs at current densities close to the exchange current density of the cathode reaction, consistent with experimental observations.

  18. LI,HOSPEDALES,SONG,GONG: FINE-GRAINED SKETCH-BASED IMAGE RETRIEVAL 1 Fine-Grained Sketch-Based Image Retrieval

    E-Print Network [OSTI]

    Gong, Shaogang

    LI,HOSPEDALES,SONG,GONG: FINE-GRAINED SKETCH-BASED IMAGE RETRIEVAL 1 Fine-Grained Sketch.hospedales@qmul.ac.uk Yi-Zhe Song yizhe.song@qmul.ac.uk Shaogang Gong s.gong@qmul.ac.uk Queen Mary University of London. It may be distributed unchanged freely in print or electronic forms. #12;2 LI,HOSPEDALES,SONG,GONG: FINE

  19. First-principles investigation of Li intercalation kinetics in phospho-olivines

    E-Print Network [OSTI]

    Malik, Rahul

    2013-01-01T23:59:59.000Z

    This thesis focuses broadly on characterizing and understanding the Li intercalation mechanism in phospho-olivines, namely LiFePO? and Li(Fe,Mn)PO?, using first-principles calculations. Currently Li-ion battery technology ...

  20. Application of picosecond lasers for surface modification and polishing Krste Pangovski, Kun Li, Dr. Bill O'Neill

    E-Print Network [OSTI]

    Haddadi, Hamed

    with laser cutting, drilling, micro processing and marking comprising the majority of the share withinApplication of picosecond lasers for surface modification and polishing Krste Pangovski, Kun Li, Dr, University of Cambridge, Cambridge, CB3 0FS Abstract: This paper examines the interaction of 100 ps laser

  1. Suppression of Cobalt Dissolution from the LiCoO2 Cathodes with Various Metal-Oxide Coatings

    E-Print Network [OSTI]

    Park, Byungwoo

    and Engineering and Research Center for Energy Conversion and Storage, Seoul National University, Seoul, Korea b Department of Applied Chemistry, Kumoh National Institute of Technology, Gumi, Korea ZrO2-coated LiCoO2 due to its high energy density and good cycling-life performance. However, even though the theoretical

  2. A=8Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram for 8Li) GENERAL: See also

  3. A=8Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram for 8Li) GENERAL: See also

  4. A=8Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level Diagram for 8Li) GENERAL: See

  5. Protection of Li Anodes Using Dual Phase Electrolytes

    Broader source: Energy.gov (indexed) [DOE]

    the laboratory scale Li-S cells. Partners BASF SE, Germany * Development of Li-S battery materials 3 Project Objectives * Develop a unique electrolyte providing two liquid phases...

  6. Hydrogen storage in LiH: A first principle study

    SciTech Connect (OSTI)

    Banger, Suman, E-mail: sumanphy28@gmail.com; Nayak, Vikas, E-mail: sumanphy28@gmail.com; Verma, U. P., E-mail: sumanphy28@gmail.com [School of Studies in Physics, Jiwaji University, Gwalior-474011 (India)

    2014-04-24T23:59:59.000Z

    First principles calculations have been performed on the Lithium hydride (LiH) using the full potential linearized augmented plane wave (FP-LAPW) method within the framework of density functional theory. We have extended our calculations for LiH+2H and LiH+6H in NaCl structure. The structural stability of three compounds have been studied. It is found that LiH with 6 added Hydrogen atoms is most stable. The obtained results for LiH are in good agreement with reported experimental data. Electronic structures of three compounds are also studied. Out of three the energy band gap in LiH is ?3.0 eV and LiH+2H and LiH+6H are metallic.

  7. Development of Li+ alumino-silicate ion source

    E-Print Network [OSTI]

    Roy, P.K.

    2009-01-01T23:59:59.000Z

    Development of a Li + alumino-silicate ion source ? P. K.kinetic energy. Alumino-silicates sources of K + and Cs +and sintering the Li alumino- silicate to the substrate to

  8. Lithium Source For High Performance Li-ion Cells

    Broader source: Energy.gov (indexed) [DOE]

    Designs: For Cell (Li5FeO4+LiV3O8) vs. Carbon Anode (with 5% Irreversible Loss) Composite Cathode Materials Potential to achieve higher energy density (Whkg and WhL) at...

  9. Improved Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas Edward

    2012-01-01T23:59:59.000Z

    commercial Li-ion batteries today use graphite or a mixturein certain primary batteries). Graphite has a potential of

  10. Speaker: Dr. Shuwang Li, University of California, Irvine Title ...

    E-Print Network [OSTI]

    1910-80-10T23:59:59.000Z

    Jan 8, 2008 ... Many multiphysics problems in fluids, materials and biosystems involve ... I will demonstrate that there exist critical conditions such that these.

  11. The prospects for highbeta tokamaks with Li walls 1

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    . Why Li walls ? 2. Magnetic propulsion of liquid Li. 3. Plasma profiles in the non­recycling regime. 4 can be magnetically propulsed along the plasma facing surfaces in the tokamak chamber. This allows the stabilizing wall right at the plasma boundary. 2. Intense (V ' 20 m=sec) magnetic propulsion allows to keep Li

  12. Current collectors for rechargeable Li-Air batteries

    SciTech Connect (OSTI)

    Veith, Gabriel M [ORNL; Dudney, Nancy J [ORNL

    2011-01-01T23:59:59.000Z

    Here we report the negative influence of porous nickel foam for use as current collectors in rechargeable Li-air batteries. Uncoated nickel foam promotes the decomposition of LiPF6-organic carbonate electrolytes under normal charging conditions reported for rechargeable Li-air cells. We have identified Ni free porous carbon supports as more appropriate cathode current collectors.

  13. Aachen RWTH Aarhus University Aberdeen University Adelaide University Alabama University Alberta University Amsterdam University Arizona University Auckland University Australian National University Bath University Beijing

    E-Print Network [OSTI]

    Tisdell, Chris

    Massachusetts University Massey University McGill University McMaster University Melbourne University Michigan State University Michigan University Minnesota University Monash University Montpellier UniversityAachen RWTH Aarhus University Aberdeen University Adelaide University Alabama University Alberta

  14. Corrosion of lithium in LiCl-LiOH-H/sub 2/O-system solutions

    SciTech Connect (OSTI)

    Demidov, A.I.; Kungurtsev, O.A.; Morachevskii, A.G.

    1988-07-10T23:59:59.000Z

    This communication presents the results of an investigation of the corrosion of lithium in solutions of the system LiCl-LiOH-H/sub 2/O at 298 K. The reaction rate of lithium with the electrolyte was calculated on the basis of volumetric measurements. The investigation was carried out in a standard electrochemical cell furnished with a branch pipe for the collection of hydrogen. The results demonstrated that in the absence of polarization the lithium corrosion rate decreased as the concentration of lithium chloride in the electrolyte increased, and also that at lower concentrations of LiOH, additions of LiCl exerted a stronger influence on the corrosion rate of the metal.

  15. A Critical Review of the Li Insertion Mechanisms in LiFePO[subscript 4] Electrodes

    E-Print Network [OSTI]

    Malik, Rahul

    With the ever-growing public and now commercial sentiment supporting the widespread adoption of low and zero-emission vehicles, it is unsurprising that Li-ion batteries which currently assume the bulk of the cost of ...

  16. DlcSsoo |LI Metallurgy Department

    E-Print Network [OSTI]

    DlcSsoo |£LI s TT^rrrc^ G en 2 L-V I 7 Risø-R-523 Metallurgy Department Progress Report;Risø-R-523 METALLURGY DEPARTMENT PROGRESS REPORT FOR THE PERIOD 1 JANUARY TO 31 DECEMBER 1984 Abstract. The activities of the Metallurgy Department at Risø during 1984 are described. The work is presented in three

  17. Performance study of commercial LiCoO2 and spinel-based Li-ion cells

    E-Print Network [OSTI]

    Popov, Branko N.

    -ion cells and Sony 18650 cells using non-stoichiometric spinel and LiCoO2, respectively, as positive at the cathode and loss of active material at both electrodes due to electrolyte oxidation. For the Sony cells Science B.V. All rights reserved. Keywords: Li-ion cells; LiCoO2; Cell-Batt1 ; Capacity fade; Sony 18650

  18. Inner-Shell Capture and Ionization in Collisions of H+, He2+, and Li3+ Projectiles with Neon and Carbon

    E-Print Network [OSTI]

    Ford, A. Lewis; Reading, John F.; Becker, R. L.

    1981-01-01T23:59:59.000Z

    PHYSICAL REVIEW A VOLUME 23, NUMBF R FEBRUARY 1981 Inner-shell capture and ionization in collisions of H+, He'+, and Li'+ projectiles with neon and carbon A. L. Ford~ and J. F. Reading* Physics Department, Texas A &M University, College Station...) Li++ Ne, and (d) H'+ C. The open triangles in (d) are results calculated with the carbon X-shell orbital energy adjusted to give the experimental K-shell binding energy. Note that the scale on the vertical axis is lin- ear. INNER-SHELL CAPTURE...

  19. Thermal Stability of Li-Ion Cells

    SciTech Connect (OSTI)

    ROTH,EMANUEL P.

    1999-09-17T23:59:59.000Z

    The thermal stability of Li-ion cells with intercalating carbon anodes and metal oxide cathodes was measured as a function of state of charge and temperature for two advanced cell chemistries. Cells of the 18650 design with Li{sub x}CoO{sub 2} cathodes (commercial SONY cells) and Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathodes were measured for thermal reactivity in the open circuit cell condition. Accelerating rate calorimetry (ARC) was used to measure cell thermal runaway as a function of state of charge (SOC). Microcalorimetry was used to measure the time dependence of heat generating side reactions also as a function of SOC. Components of cells were measured using differential scanning calorimetry (DSC) to study the thermal reactivity of the individual electrodes to determine the temperature regimes and conditions of the major thermal reactions. Thermal decomposition of the SEI layer at the anodes was identified as the initiating source for thermal runaway. The cells with Li{sub x}CoO{sub 2} cathodes showed greater sensitivity to SOC and higher accelerating heating rates than seen for the cells with Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2}cathodes. Lower temperature reactions starting as low as 40 C were also observed that were SOC dependent but not accelerating. These reactions were also measured in the microcalorimeter and observed to decay over time with a power-law dependence and are believed to result in irreversible capacity loss in the cells.

  20. Is there a bound dineutron in {sup 11}Li?

    SciTech Connect (OSTI)

    Ieki, K.; Galonsky, A.; Sackett, D.; Kruse, J.J.; Lynch, W.G.; Morrissey, D.J.; Orr, N.A.; Sherrill, B.M.; Winger, J.A. [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States)] [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States); Deak, F.; Horvath, A.; Kiss, A. [Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7, H-1088 Budapest 8 (Hungary)] [Department of Atomic Physics, Eoetvoes University, Puskin utca 5-7, H-1088 Budapest 8 (Hungary); Seres, Z. [Central Research Institute for Physics, Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary)] [Central Research Institute for Physics, Hungarian Academy of Sciences, H-1525 Budapest 114 (Hungary); Kolata, J.J. [Physics Department, University of Notre Dame, Notre Dame, Indiana 46556 (United States)] [Physics Department, University of Notre Dame, Notre Dame, Indiana 46556 (United States); Warner, R.E. [Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States)] [Department of Physics, Oberlin College, Oberlin, Ohio 44074 (United States); Humphrey, D.L. [Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States)] [Department of Physics, Western Kentucky University, Bowling Green, Kentucky 42101 (United States)

    1996-10-01T23:59:59.000Z

    Photodisintegration of {sup 11}Li was accomplished by sending a beam of {sup 11}Li at 28 MeV/nucleon through the equivalent photon field of a lead target. By measuring the complete kinematics of the disintegration products, {sup 9}Li+{ital n}+{ital n}, we constructed the correlation of the angle between the two neutrons in the rest frame of the {sup 11}Li. The correlation is independent of angle. This result argues against the existence of a bound dineutron in the ground state of {sup 11}Li. {copyright} {ital 1996 The American Physical Society.}

  1. Making Li-air batteries rechargeable: material challenges

    SciTech Connect (OSTI)

    Shao, Yuyan; Ding, Fei; Xiao, Jie; Zhang, Jian; Xu, Wu; Park, Seh Kyu; Zhang, Jiguang; Wang, Yong; Liu, Jun

    2013-02-25T23:59:59.000Z

    A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.

  2. Electrolyte effects in Li(Si)/FeS{sub 2} thermal batteries

    SciTech Connect (OSTI)

    Guidotti, R.A.; Reinhardt, F.W.

    1994-10-01T23:59:59.000Z

    The most common electrochemical couple for thermally activated (``thermal``) batteries is the Li-alloy/FeS{sub 2} system. The most common Li-alloys used for anodes are 20% Li-80% Al and 44% Li-56% Si (by weight); liquid Li immobilized with iron powder has also been used. The standard electrolyte that has been used in thermal batteries over the years is the LiCl-KCl eutectic that melts at 352{degrees}C. The LiCl-LiBr-LiF eutectic had the best rate and power characteristics. This electrolyte melts at 436{degrees}C and shows very low polarization because of the absence of Li+ gradients common with the LiCl-KCl eutectic. The low-melting electrolytes examined included a KBr-LiBr-LiCl eutectic (melting at 321{degrees}C), a LiBr-KBr-LiF eutectic (melting at 313{degrees}C), and a CsBr-LiBr-KBr eutectic (melting at 238{degrees}C). The CsBr-based salt had poor conductivity and was not studied further. The LiBr-KBr-LiF eutectic outperformed the KBr-LiBr-LiCl eutectic and was selected for more extensive testing. Because of their lower melting points and larger liquidi relative to the LiCl-KCl eutectic, the low-melting electrolytes are prime candidates for long-life applications (i.e., for activated lives of one hour or more). This paper will detail the relative performance of the Li(Si)/FeS{sub 2} couple using primarily the LiCl-KCl (standard) eutectic, the LiCl-LiBr-LiF (all-Li) eutectic, and the LiBr-KBr-LiF (low-melting) eutectic electrolytes. Most of the tests were conducted with 5-cell batteries; validation tests were also carried out with appropriate full-sized batteries.

  3. Spectroscopy of Lambda-9Li by electroproduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urciuoli, G. M.; Cusanno, F.; Marrone, S.; Acha, A.; Ambrozewicz, P.; Aniol, K. A.; Baturin, P.; Bertin, P. Y.; Benaoum, H.; Blomqvist, K. I.; et al

    2015-03-01T23:59:59.000Z

    Background: In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Purpose: To obtain a high-resolution spectrum for the 9Be(e,e?K+)Li?9 reaction. Method: Electroproduction of the hypernucleus Li?9 has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a Be9 target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. Results: The crossmore »section to low-lying states of Li?9 is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A ? separation energy, B?, of 8.36±0.08 (stat.) ±0.08 (syst.) MeV was measured, in agreement with an earlier experiment.« less

  4. Spectroscopy of Lambda-9Li by electroproduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Urciuoli, G. M.; Cusanno, F.; Marrone, S.; Acha, A.; Ambrozewicz, P.; Aniol, K. A.; Baturin, P.; Bertin, P. Y.; Benaoum, H.; Blomqvist, K. I.; Boeglin, W. U.; Breuer, H.; Brindza, P.; Bydzovsky, P.; Camsonne, A.; Chang, C. C.; Chen, J. -P.; Choi, Seonho; Chudakov, E. A.; Cisbani, E.; Colilli, S.; Coman, L.; Craver, B. J.; De Cataldo, G.; de Jager, C. W.; De Leo, R.; Deur, A. P.; Ferdi, C.; Feuerbach, R. J.; Folts, E.; Fratoni, R.; Frullani, S.; Garibaldi, F.; Gayou, O.; Giuliani, F.; Gomez, J.; Gricia, M.; Hansen, J. O.; Hayes, D.; Higinbotham, D. W.; Holmstrom, T. K.; Hyde, C. E.; Ibrahim, H. F.; Iodice, M.; Jiang, X.; Kaufman, L. J.; Kino, K.; Kross, B.; Lagamba, L.; LeRose, J. J.; Lindgren, R. A.; Lucentini, M.; Margaziotis, D. J.; Markowitz, P.; Meziani, Z. E.; McCormick, K.; Michaels, R. W.; Millener, D. J.; Miyoshi, T.; Moffit, B.; Monaghan, P. A.; Moteabbed, M.; Camacho, C. Munoz; Nanda, S.; Nappi, E.; Nelyubin, V. V.; Norum, B. E.; Okasyasu, Y.; Paschke, K. D.; Perdrisat, C. F.; Piasetzky, E.; Punjabi, V. A.; Qiang, Y.; Reimer, P. E.; Reinhold, J.; Reitz, B.; Roche, R. E.; Rodriguez, V. M.; Saha, A.; Santavenere, F.; Sarty, A. J.; Segal, J.; Shahinyan, A.; Singh, J.; Sirca, S.; Snyder, R.; Solvignon, P. H.; Sotona, M.; Subedi, R.; Sulkosky, V. A.; Suzuki, T.; Ueno, H.; Ulmer, P. E.; Veneroni, P.; Voutier, E.; Wojtsekhowski, B. B.; Zheng, X.; Zorn, C.

    2015-03-01T23:59:59.000Z

    Background: In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Purpose: To obtain a high-resolution spectrum for the 9Be(e,e?K+)Li?9 reaction. Method: Electroproduction of the hypernucleus Li?9 has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a Be9 target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. Results: The cross section to low-lying states of Li?9 is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A ? separation energy, B?, of 8.36±0.08 (stat.) ±0.08 (syst.) MeV was measured, in agreement with an earlier experiment.

  5. Experimental simulation of internal short circuit in Li-ion and Li-ion-Polymer cells

    SciTech Connect (OSTI)

    Cai, Wei [ORNL; Wang, Hsin [ORNL; Maleki, Hossein [Motorola Mobility; Howard, Jason [Motorola Mobility; Lara-Curzio, Edgar [ORNL

    2011-01-01T23:59:59.000Z

    A multi-parameter controlled pinch test was developed to study the occurrence of internal short circuits in Li-ion and Li-ion-polymer cells. By tuning the control parameters (i.e., cell voltage as well as pinching area, load, and speed), the pinch test can reproducibly create ~1 to 2 mm wide internal short between a cell jelly-roll s inner layer electrodes. This recreates conditions similar to those that may occur during service. Furthermore, the pinch test is used to determine thermal stability of two Li-ion-polymer cells of different designs built by the same manufacturer. The pinch test method can be used to help distinguish cells with design features or characteristics that lower risk of potential thermal events created by internal short circuits.

  6. Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1

    E-Print Network [OSTI]

    Zhou, Yaoqi

    Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1 , Wen Chao Lee1 This study demonstrates the feasibility of using water and the contents of waste Li-ion batteries for the electrodes in a Li-liquid battery system. Li metal was collected electrochemically from a waste Li

  7. Li overlayer formation, oxidation and sputtering characteristics of Al-Li alloys and W/Al-Li composites for fusion applications

    SciTech Connect (OSTI)

    Krauss, A.R. (Argonne National Lab., IL (USA)); DeWald, A.B.; Scott, P.; Savage, H. (Corium Industries, Inc., Atlanta, GA (USA))

    1990-01-01T23:59:59.000Z

    The next generation of long pulse fusion devices will impose severe requirements on the properties of plasma-facing materials. In devices such as ITER, a divertor design is being considered, using a divertor plate which would be either tungsten or a low-Z material such as graphite or beryllium. Strongly segregating lithium alloys have been proposed as a means of producing a self-sustaining low-Z overlayer which lowers plasma Z{sub eff} and resists self-sputtering. Aluminum-lithium alloys are among the better-characterized lithium-bearing alloys, and it has been demonstrated that lithium segregates strongly in aluminum. However, aluminum has a relatively low melting point, and for low lithium concentrations, the lithium diffusion rate is too slow to replenish lithium at the rate at which it is eroded by the incoming plasma. It has been suggested previously that the superionic {beta} phase Al-Li alloy (48--54 at. % Li) should have high enough diffusivity to be able to replenish surface lithium, and that incorporation of the {beta}-phase AlLi in a composite with tungsten would provide high temperature strength and melt layer stability, along with significantly better thermal conductivity than pure tungsten. Such a composite has been fabricated, as well as a variation containing titanium as a means of controlling oxidation at grain boundaries. The Li overlayer formation, erosion, and replenishment are characterized for the {beta}-phase LiAl alloy, and W-AlLi and W-Ti-AlLi composites. It is found that if there is no oxide layer to inhibit the Li segregation, Li diffusion is extremely rapid, and an oxygen-free Li overlayer is formed which is stable under continuous ion beam sputtering. 21 refs., 7 figs.

  8. Characterization of Li-ion Batteries using Neutron Diffraction...

    Broader source: Energy.gov (indexed) [DOE]

    Li-ion batteries Using Neutron Diffraction and Infrared Imaging Techniques: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2011 Vehicle...

  9. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of LIB Cathode Materials Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio...

  10. Characterization of Materials for Li-ion Batteries: Success Stories...

    Broader source: Energy.gov (indexed) [DOE]

    Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2010 Vehicle Technologies Annual Merit Review and Peer...

  11. LiU E-Press Newsletter Autumn, 2008

    E-Print Network [OSTI]

    Zhao, Yuxiao

    to Increase Biogas Yields by Anders Ek was one of the winners. For more information about LiU E-Press and how

  12. Novel Laser-Based Manufacturing of nano-LiFePO4-Based Materials for High Power Li Ion Batteries

    E-Print Network [OSTI]

    Horne, Craig R.; Jaiswal, Abhishek; Chang, On; Crane, S.; Doeff, Marca M.; Wang, Emile

    2006-01-01T23:59:59.000Z

    17-18, 2007 Novel Laser-Based Manufacturing of nano-LiFePO 4laser-based process for synthesizing nanomaterials, NanoParticle Manufacturing (

  13. Novel Laser-Based Manufacturing of nano-LiFePO4-Based Materials for High Power Li Ion Batteries

    E-Print Network [OSTI]

    Horne, Craig R.; Jaiswal, Abhishek; Chang, On; Crane, S.; Doeff, Marca M.; Wang, Emile

    2006-01-01T23:59:59.000Z

    II “Olivines in Lithium Batteries” The Beckman Institute,for High Power Li Ion Batteries C.R. Horne 1 , A. Jaiswal

  14. Momentum distributions for ([sup 11]Li, [sup 9]Li+[ital n]+[ital n]) breakup reactions

    SciTech Connect (OSTI)

    Esbensen, H.; Bertsch, G.F.; Ieki, K. (Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States) Physics Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States) Institute of Nuclear Theory and Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-07-01T23:59:59.000Z

    We have calculated the momentum distributions of the three fragments emitted in the breakup reaction ([sup 11]Li,[sup 9]Li+[ital n]+[ital n]), induced by the Coulomb field from a heavy target, and made comparisons to recent three-body coincidence measurements. Our three-body model for [sup 11]Li provides a good description of the measured relative momentum distribution for the two emitted neutrons, and also for the single-neutron momentum distribution. The predicted distribution for the [sup 9]Li recoil is much narrower than observed; a plausible explanation is presented.

  15. Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4

    E-Print Network [OSTI]

    Bazant, Martin Z.

    Rate-Dependent Morphology of Li2O2 Growth in Li-O2 Batteries Birger Horstmann,1, 2, 3, 4 Betar continuum model for the growth of Li2O2 crystals in lithium-oxygen batteries with organic electrolytes-ion batteries. As in the case of lithium insertion in phase-separating LiFePO4 nanoparticles, the theory

  16. Suppression of Phase Separation in LiFePO 4 Nanoparticles During Battery Discharge

    E-Print Network [OSTI]

    Bai, Peng

    Using a novel electrochemical phase-field model, we question the common belief that LiXFePO? nanoparticles always separate into Li-rich and Li-poor phases during battery discharge. For small currents, spinodal decomposition ...

  17. High Capacity MoO3 Nanoparticle Li-Ion Battery Anode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    energy functional were employed.) 10 AccomplishmentStatus Theoretical changes in Li-ion intercalated -MoO 3 Mo Li O * Four Li inserted in a theoretical nanoparticle. * 9 ps...

  18. Thermodynamic and kinetic properties of the Li-graphite system from first-principles calculations

    E-Print Network [OSTI]

    Ceder, Gerbrand

    We present an ab initio study of the thermodynamics and kinetics of Li [subscript x]C[subscript 6], relevant for anode Li intercalation in rechargeable Li batteries. In graphite, the interlayer interactions are dominated ...

  19. A HIGH CURRENT DENSITY LI+ ALUMINO-SILICATE ION SOURCE FOR TARGET HEATING EXPERIMENTS

    E-Print Network [OSTI]

    Roy, Prabir K.

    2011-01-01T23:59:59.000Z

    CURRENT DENSITY LI+ ALUMINO-SILICATE ION SOURCE FOR TARGETCURRENT DENSITY LI + ALUMINO-SILICATE ION SOURCE FOR TARGETcm) Li + doped alumino-silicate source with a pulse duration

  20. Homogeneous Factorisations of Graphs and Michael Giudici a, Cai Heng Li a

    E-Print Network [OSTI]

    Giudici, Michael

    Homogeneous Factorisations of Graphs and Digraphs Michael Giudici a, Cai Heng Li a Primoz Potocnik@maths.uwa.edu.au (Michael Giudici), li@maths.uwa.edu.au (Cai Heng Li), primoz.potocnik@fmf.uni-lj.si (Primoz Preprint

  1. Lithium Diffusion in Li4Ti5O12 at High Temperatures. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Diffusion in Li4Ti5O12 at High Temperatures. Lithium Diffusion in Li4Ti5O12 at High Temperatures. Abstract: Synthesis of the spinel lithium titanate Li4Ti5O12 by an...

  2. Primordial Li abundance and massive particles

    SciTech Connect (OSTI)

    Latin-Capital-Letter-Eth apo, H. [Department of Physics, Akdeniz University, TR-07058, Antalya (Turkey)

    2012-10-20T23:59:59.000Z

    The problem of the observed lithium abundance coming from the Big Bang Nucleosynthesis is as of yet unsolved. One of the proposed solutions is including relic massive particles into the Big Bang Nucleosynthesis. We investigated the effects of such particles on {sup 4}HeX{sup -}+{sup 2}H{yields}{sup 6}Li+X{sup -}, where the X{sup -} is the negatively charged massive particle. We demonstrate the dominance of long-range part of the potential on the cross-section.

  3. I I LI I L I

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7111AWell:F E ,"^ I 1' . _ .t.fiom I -'LI -

  4. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07) (Not observed) See72AJ02)72AJ02) (See95TI07)Li

  5. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01)93TI07)7AJ02) (See the98TI06)2010PU04)4He (1992TI02)Li

  6. A=9Li (1979AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not

  7. A=9Li (1984AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01) (See Energy

  8. A=9Li (1988AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01) (See

  9. A=9Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01) (See2004TI06)

  10. A=9Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01)

  11. A=9Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01)66LA04) (See

  12. A=9Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See the Energy Level79AJ01) (Not4AJ01)66LA04)

  13. Ying Li | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contributeSecuritysupports neighbors's/UTAnaYeYing Li

  14. LiDAR | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOf Kilauea Volcano,Lakefront Tow(Redirected from Lewisburg,LiDAR Jump to:

  15. A=15Li (1981AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01) (See0AJ04)1AJ01) (Not illustrated) 15Li

  16. A=16Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less2012KE01) (Not6AJ01)93TI07) (See Energy Level6AJ04)6AJ04)Li

  17. Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li

    E-Print Network [OSTI]

    Chem 115Lithium-Halogen ExchangeMyers RLi + R'X RX + R'Li Lithium-halogen exchange reactions are essentially inert. 2 t-BuLi t-BuI + RLi t-BuLi isobutene + isobutane + LiI Lithium-halogen exchange reactions, and lithium iodide. H OEtBr H H OEtLi H1.1 eq n-BuLi Et2O, !80 °C Lau, K. S.; Schlosser, M. J. Org. Chem. 1978

  18. Nuclear Pleomorphism Scoring by Selective Cell Nuclei Detection Jean-Romain Dalle Hao Li Chao-Hui Huang Wee Kheng Leow

    E-Print Network [OSTI]

    Leow, Wee Kheng

    Nuclear Pleomorphism Scoring by Selective Cell Nuclei Detection Jean-Romain Dalle Hao Li Chao, National University Hospital pattcp@nus.edu.sg Abstract Scoring the nuclear pleomorphism for nuclear pleo- morphism scoring according to the Nottingham grading system. In contrast, most

  19. The Effect of AlPO4-Coating Layer on the Electrochemical Properties in LiCoO2 Thin Films

    E-Print Network [OSTI]

    Park, Byungwoo

    cycling, as measured by electrochemical impedance spectroscopy. This dependence on the deposition and Engineering, and Research Center for Energy Conversion and Storage, Seoul National University, Seoul 151 is widely used as a cathode material in commercial Li-ion batteries because of its good electrochemical

  20. Giant resonances in (116)Sn from 240 MeV (6)Li scattering

    E-Print Network [OSTI]

    Chen, X.; Lui, Y. -W; Clark, H. L.; Tokimoto, Y.; Youngblood, David H.

    2009-01-01T23:59:59.000Z

    PHYSICAL REVIEW C 79, 024320 (2009) Giant resonances in 116Sn from 240 MeV 6Li scattering X. Chen, Y.-W. Lui, H. L. Clark, Y. Tokimoto, and D. H. Youngblood Cyclotron Institute, Texas A&M University, College Station, Texas 77843, USA (Received... multipole excitation operator Q = ? i f (ri)YML (#2;i), (2) 0556-2813/2009/79(2)/024320(8) 024320-1 2009 The American Physical Society CHEN, LUI, CLARK, TOKIMOTO, AND YOUNGBLOOD PHYSICAL REVIEW C 79, 024320 (2009) the EWSR can be evaluated by means...

  1. Giant resonances in (24)Mg and (28)Si from 240 MeV (6)Li scattering

    E-Print Network [OSTI]

    Chen, X.; Lui, Y. -W; Clark, H. L.; Tokimoto, Y.; Youngblood, David H.

    2009-01-01T23:59:59.000Z

    PHYSICAL REVIEW C 80, 014312 (2009) Giant resonances in 24Mg and 28Si from 240 MeV 6Li scattering X. Chen,1 Y.-W. Lui,2 H. L. Clark,2 Y. Tokimoto,2 and D. H. Youngblood2 1Chemistry Department, Washington University, St. Louis, Missouri 63130, USA...-1 ?2009 The American Physical Society CHEN, LUI, CLARK, TOKIMOTO, AND YOUNGBLOOD PHYSICAL REVIEW C 80, 014312 (2009) TABLE I. Spectrometer angles used for measuring elastic scat- tering and giant resonances. The numbers in parenthesis are the slit...

  2. Air stable Al2O3-coated Li2NiO2 cathode additive as a surplus current consumer in a Li-ion cell

    E-Print Network [OSTI]

    Cho, Jaephil

    increases to 2.75V (2.85V vs. graphite), its discharge capacity decreases to 120 mAh/g, which corresponds for the irreversible capacity of the Li-ion cell using LiCoO2 and natural graphite as cathode and anode materials the complete decomposition of the Li2NiO2. 1. Introduction Most Li secondary batteries use LiCoO2 as a cathode

  3. Spectroscopy of Lambda-9Li by electroproduction

    E-Print Network [OSTI]

    G. M. Urciuoli; F. Cusanno; S. Marrone; A. Acha; P. Ambrozewicz; K. A. Aniol; P. Baturin; P. Y. Bertin; H. Benaoum; K. I. Blomqvist; W. U. Boeglin; H. Breuer; P. Brindza; P. Bydzovsky; A. Camsonne; C. C. Chang; J. -P. Chen; Seonho Choi; E. A. Chudakov; E. Cisbani; S. Colilli; L. Coman; B. J. Craver; G. De Cataldo; C. W. de Jager; R. De Leo; A. P. Deur; C. Ferdi; R. J. Feuerbach; E. Folts; R. Fratoni; S. Frullani; F. Garibaldi; O. Gayou; F. Giuliani; J. Gomez; M. Gricia; J. O. Hansen; D. Hayes; D. W. Higinbotham; T. K. Holmstrom; C. E. Hyde; H. F. Ibrahim; M. Iodice; X. Jiang; L. J. Kaufman; K. Kino; B. Kross; L. Lagamba; J. J. LeRose; R. A. Lindgren; M. Lucentini; D. J. Margaziotis; P. Markowitz; Z. E. Meziani; K. McCormick; R. W. Michaels; D. J. Millener; T. Miyoshi; B. Moffit; P. A. Monaghan; M. Moteabbed; C. Munoz Camacho; S. Nanda; E. Nappi; V. V. Nelyubin; B. E. Norum; Y. Okasyasu; K. D. Paschke; C. F. Perdrisat; E. Piasetzky; V. A. Punjabi; Y. Qiang; P. E. Reimer; J. Reinhold; B. Reitz; R. E. Roche; V. M. Rodriguez; A. Saha; F. Santavenere; A. J. Sarty; J. Segal; A. Shahinyan; J. Singh; S. Sirca; R. Snyder; P. H. Solvignon; M. Sotona; R. Subedi; V. A. Sulkosky; T. Suzuki; H. Ueno; P. E. Ulmer; P. Veneroni; E. Voutier; B. B. Wojtsekhowski; X. Zheng; C. Zorn

    2014-10-01T23:59:59.000Z

    In the absence of accurate data on the free two-body hyperon-nucleon interaction, the spectra of hypernuclei can provide information on the details of the effective hyperon-nucleon interaction. Electroproduction of the hypernucleus Lambda-9Li has been studied for the first time with sub-MeV energy resolution in Hall A at Jefferson Lab on a 9Be target. In order to increase the counting rate and to provide unambiguous kaon identification, two superconducting septum magnets and a Ring Imaging CHerenkov detector (RICH) were added to the Hall A standard equipment. The cross section to low-lying states of Lambda-9Li is concentrated within 3 MeV of the ground state and can be fitted with four peaks. The positions of the doublets agree with theory while a disagreement could exist with respect to the relative strengths of the peaks in the doublets. A Lambda separation energy of 8.36 +- 0.08 (stat.) +- 0.08 (syst.) MeV was measured, in agreement with an earlier experiment.

  4. Molecular dynamics simulation of Li surface erosion and bubble formation

    E-Print Network [OSTI]

    Harilal, S. S.

    .49.Sf Keywords: Liquid metal; Lithium; Ion-surface interactions 1. Introduction Bombardment Structure and dynamical properties of liquid Li containing He atoms were studied by the Molecular Dynamics characteristics of light low-energy ions on a liquid Li surface and their diffusion properties have attracted much

  5. Implications of Li divertor and other liquid-metal technologies

    E-Print Network [OSTI]

    plasma-facing systems can rapidly remove heat. h Continuous recovery of damaged surfaces exposed to large. Nuclear Mater. 290-293 (2001) 19. #12;Secondary ion fraction and deuterium- saturation studies of liquid (sputteringions/sputteredatoms) Incident particle energy (eV) Secondary Li ion fraction (non D-sat.) Secondary Li

  6. Ethylmethylcarbonate, a promising solvent for Li-ion rechargeable batteries

    SciTech Connect (OSTI)

    Ein-Eli, Y.; Thomas, S.R.; Koch, V. [Covalent Associates Inc., Woburn, MA (United States); Aurbach, D.; Markovsky, B.; Schechter, A. [Bar-Ilan Univ., Ramat Gan (Israel). Dept. of Chemistry

    1996-12-01T23:59:59.000Z

    Ethylmethylcarbonate (EMC) has been found to be a promising solvent for rechargeable Li-ion batteries. Graphite electrodes, which are usually sensitive to the composition of the electrolyte solution, can be successfully cycled at high reversible capacities in several Li salt solutions in this solvent (LiAsF{sub 6}, LiPF{sub 6}, etc.). These results are interesting because lithium ions cannot intercalate into graphite in diethyl carbonate solutions and cycle poorly in dimethyl carbonate solutions. To understand the high compatibility of EMC for Li-ion battery systems as compared with the other two open-chain alkyl carbonates mentioned above, the surface chemistry developed in both Li and carbon electrodes in EMC solution was studied and compared with that developed on these electrodes in other alkyl carbonate solutions. Basically, the major surface species formed on both electrodes in EMC include ROLi, ROCO{sub 2}Li, and Li{sub 2}CO{sub 3} species. The uniqueness of EMC as a battery solvent is discussed in light of these studies.

  7. Fluorinated Electrolyte for 5-V Li-Ion Chemistry

    Broader source: Energy.gov (indexed) [DOE]

    battery for PHEV and EV applications. Approach 5 LiNi 0.5 Mn 1.5 O 4 1.2M LiPF 6 ECEMC (37 wt%) Graphite, cycled at RT and 55 o C Technical Accomplishments and Progress...

  8. Characterization of LI+ Alumino-Silicate Ion Source for Target Heating Experiments

    E-Print Network [OSTI]

    Roy, P.K.

    2013-01-01T23:59:59.000Z

    OF LI + ALUMINO-SILICATE ION SOURCE FOR TARGET HEATINGcm) Li + doped alumino-silicate source to pro- duce shortdiameter lithium alumino-silicate ion source is presented.

  9. Scalable SMT-Based Verification of GPU Kernel Functions School of Computing, University of Utah

    E-Print Network [OSTI]

    Capecchi, Mario R.

    Scalable SMT-Based Verification of GPU Kernel Functions Guodong Li School of Computing, University Satisfiability Modulo Theo- ries (SMT) tools, detecting bugs such as data races, in- correctly synchronized Satisfiabil- ity Modulo Theories (SMT [2

  10. Localization of vacancies and mobility of lithium ions in Li{sub 2}ZrO{sub 3} as obtained by {sup 6,7}Li NMR

    SciTech Connect (OSTI)

    Baklanova, Ya. V., E-mail: baklanovay@ihim.uran.ru [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation); Arapova, I. Yu.; Buzlukov, A.L.; Gerashenko, A.P.; Verkhovskii, S.V.; Mikhalev, K.N. [Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, 18 Kovalevskaya str., 620990 Ekaterinburg (Russian Federation); Denisova, T.A.; Shein, I.R.; Maksimova, L.G. [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation)

    2013-12-15T23:59:59.000Z

    The {sup 6,7}Li NMR spectra and the {sup 7}Li spin–lattice relaxation rate were measured on polycrystalline samples of Li{sub 2}ZrO{sub 3}, synthesized at 1050 K and 1300 K. The {sup 7}Li NMR lines were attributed to corresponding structural positions of lithium Li1 and Li2 by comparing the EFG components with those obtained in the first-principles calculations of the charge density in Li{sub 2}ZrO{sub 3}. For both samples the line width of the central {sup 7}Li transition and the spin–lattice relaxation time decrease abruptly at the temperature increasing above ?500 K, whereas the EFG parameters are averaged (??{sub Q}?=42 (5) kHz) owing to thermally activated diffusion of lithium ions. - Graphical abstract: Path of lithium ion hopping in lithium zirconate Li{sub 2}ZrO{sub 3}. - Highlights: • Polycrystalline samples Li{sub 2}ZrO{sub 3} with monoclinic crystal structure synthesized at different temperatures were investigated by {sup 6,7}Li NMR spectroscopy. • Two {sup 6,7}Li NMR lines were attributed to the specific structural positions Li1 and Li2. • The distribution of vacancies was clarified for both lithium sites. • The activation energy and pathways of lithium diffusion in Li{sub 2}ZrO{sub 3} were defined.

  11. Structure of neutron-rich Isotopes {sup 8}Li and {sup 9}Li and allowance for it in elastic scattering

    SciTech Connect (OSTI)

    Ibraeva, E. T., E-mail: ibr@inp.k [National Nuclear Center of the Republic of Kazakhstan, Institute for Nuclear Physics (Kazakhstan); Zhusupov, M. A.; Imambekov, O.; Sagindykov, Sh. Sh. [Al Farabi Kazakh National University (Kazakhstan)

    2008-07-15T23:59:59.000Z

    The differential cross sections for elastic proton scattering on the unstable neutron-rich nuclei {sup 8}Li and {sup 9}Li at E = 700 and 60 MeV per nucleon were considered. The {sup 8}Li nucleus was treated on the basis of the three-body {alpha}-t-n model, while the {sup 9}Li nucleus was considered within the {alpha}-t-n and {sup 7}Li-n-n models. The cross sections in question were calculated within Glauber diffraction theory. A comparison of the results with available experimental data made it possible to draw conclusions on the quality of the wave functions and potential used in the calculations.

  12. LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery

    DOE Patents [OSTI]

    Ko, Suk M. (Huntsville, AL)

    1980-01-01T23:59:59.000Z

    This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

  13. Material review of Li ion battery separators

    SciTech Connect (OSTI)

    Weber, Christoph J., E-mail: Christoph.Weber@freudenberg-nw.com; Geiger, Sigrid, E-mail: Christoph.Weber@freudenberg-nw.com [Freudenberg Vliesstoffe SE and Co KG, 69465 Weinheim (Germany); Falusi, Sandra; Roth, Michael [Freudenberg Forschungsdienste SE and Co KG, 69465 Weinheim (Germany)

    2014-06-16T23:59:59.000Z

    Separators for Li Ion batteries have a strong impact on cell production, cell performance, life, as well as reliability and safety. The separator market volume is about 500 million m{sup 2} mainly based on consumer applications. It is expected to grow strongly over the next decade for mobile and stationary applications using large cells. At present, the market is essentially served by polyolefine membranes. Such membranes have some technological limitations, such as wettability, porosity, penetration resistance, shrinkage and meltdown. The development of a cell failure due to internal short circuit is potentially closely related to separator material properties. Consequently, advanced separators became an intense area of worldwide research and development activity in academia and industry. New separator technologies are being developed especially to address safety and reliability related property improvements.

  14. Effects of Nonaqueous Electrolytes on Primary Li-Air Batteries

    SciTech Connect (OSTI)

    Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

    2010-06-14T23:59:59.000Z

    The effects of nonaqueous electrolytes on the performance of primary Li-air batteries operated in dry air environment have been investigated. Organic solvents with low volatility and low moisture absorption are necessary to minimize the change of electrolyte compositions and the reaction between Li anode and water during the discharge process. The polarity of aprotic solvents outweighs the viscosity, ion conductivity and oxygen solubility on the performance of Li-air batteries once these latter properties attain certain reasonable level, because the solvent polarity significantly affects the number of tri-phase regions formed by oxygen, electrolyte, and active carbons (with catalyst) in the air electrode. The most feasible electrolyte formulation is the system of LiTFSI in PC/EC mixtures, whose performance is relatively insensitive to PC/EC ratio and salt concentration. The quantity of such electrolyte added to a Li-air cell has notably effects on the discharge performance of the Li-air battery as well, and a maximum in capacity is observed as a function of electrolyte amount. The coordination effect from the additives or co-solvents [tris(pentafluorophenyl)borane and crown ethers in this study] also greatly affects the discharge performance of a Li-air battery.

  15. Effects of electrolyte salts on the performance of Li-O2 batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Burton, Sarah D.; Cosimbescu, Lelia; Gross, Mark E.; Zhang, Jiguang

    2013-02-05T23:59:59.000Z

    It is well known that the stability of nonaqueous electrolyte is critical for the rechargeable Li-O2 batteries. Although stability of many solvents used in the electrolytes has been investigated, considerably less attention has been paid to the stability of electrolyte salt which is the second major component. Herein, we report the systematic investigation of the stability of seven common lithium salts in tetraglyme used as electrolytes for Li-O2 batteries. The discharge products of Li-O2 reaction were analyzed by X-ray diffraction, X-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy. The performance of Li-O2 batteries was strongly affected by the salt used in the electrolyte. Lithium tetrafluoroborate (LiBF4) and lithium bis(oxalato)borate (LiBOB) decompose and form LiF and lithium borates, respectively during the discharge of Li-O2 batteries. Several other salts, including lithium bis(trifluoromethane)sulfonamide (LiTFSI), lithium trifluoromethanesulfonate (LiTf), lithium hexafluorophosphate (LiPF6), lithium perchlorate (LiClO4) , and lithium bromide (LiBr) led to the discharge products which mainly consisted of Li2O2 and only minor signs of decomposition of LiTFSI, LiTf, LPF6 and LiClO4 were detected. LiBr showed the best stability during the discharge process. As for the cycling performance, LiTf and LiTFSI were the best among the studied salts. In addition to the instability of lithium salts, decomposition of tetraglyme solvent was a more significant factor contributing to the limited cycling stability. Thus a more stable nonaqueous electrolyte including organic solvent and lithium salt still need to be further developed to reach a fully reversible Li-O2 battery.

  16. THE NEW DETECTIONS OF {sup 7}Li/{sup 6}Li ISOTOPIC RATIO IN THE INTERSTELLAR MEDIA

    SciTech Connect (OSTI)

    Kawanomoto, S.; Kajino, T.; Aoki, W.; Ando, H.; Noguchi, K.; Tanaka, W. [National Astronomical Observatory, Mitaka, Tokyo 181-8588 (Japan); Bessell, M. [Research School of Astronomy and Astrophysics, Mount Stromlo Observatory, 2611 ACT (Australia); Suzuki, T. K. [Graduate School of Arts and Sciences, University of Tokyo, Komaba, Meguro, Tokyo 153-8902 (Japan); Honda, S. [Gunma Astronomical Observatory, 6860-86 Nakayama Takayama-mura, Agatsuma-gun, Gunma 377-0702 (Japan); Izumiura, H.; Kambe, E.; Okita, K.; Watanabe, E.; Yoshida, M. [Okayama Astrophysical Observatory, National Astronomical Observatory of Japan, 3037-5 Honjo, Kamogata, Asakuchi, Okayama 719-0232 (Japan); Sadakane, K. [Astronomical Institute, Osaka-Kyoiku University, Kashiwara-shi, Osaka 582-8582 (Japan); Sato, B. [Global Edge Institute Global Edge Institute, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550 (Japan); Tajitsu, A. [Subaru Telescope, National Astronomical Observatory of Japan, 650 North A'ohoku Place, Hilo, HI 96720 (United States); Takada-Hidai, M. [Liberal Arts Education Center, Tokai University 1117 Kitakaname, Hisatsuka-shi, Kanagawa 259-1292 (Japan)

    2009-08-20T23:59:59.000Z

    We have determined the isotopic abundance ratio of {sup 7}Li/{sup 6}Li in the interstellar media (ISMs) along lines of sight to HD169454 and HD250290 using the High-Dispersion Spectrograph on the Subaru Telescope. We also observed {zeta} Oph for comparison with previous data. The observed abundance ratios were {sup 7}Li/{sup 6}Li = 8.1{sup +3.6} {sub -1.8} and 6.3{sup +3.0} {sub -1.7} for HD169454 and HD250290, respectively. These values are in reasonable agreement with those observed previously in the solar neighborhood ISMs within {+-}2{sigma} error bars and are also consistent with our measurement of {sup 7}Li/{sup 6}Li = 7.1{sup +2.9} {sub -1.6} for a cloud along the line of sight to {zeta} Oph. This is good evidence for homogeneous mixing and instantaneous recycling of the gas component in the Galactic disk. We also discuss several source compositions of {sup 7}Li, Galactic cosmic-ray interactions, stellar nucleosynthesis, and big bang nucleosynthesis.

  17. On the Origin and Implications of Li$_2$O$_2$ Toroid Formation in Nonaqueous Li-O$_2$ Batteries

    E-Print Network [OSTI]

    Aetukuri, Nagaphani B; García, Jeannette M; Krupp, Leslie E; Viswanathan, Venkatasubramanian; Luntz, Alan C

    2014-01-01T23:59:59.000Z

    The lithium-air (Li-O$_2$) battery has received enormous attention as a possible alternative to current state-of-the-art rechargeable Li-ion batteries given their high theoretical specific energy. However, the maximum discharge capacity in nonaqueous Li-O$_2$ batteries is limited to a small fraction of its theoretical value due to the insulating nature of lithium peroxide, Li$_2$O$_2$, the battery$'$s primary discharge product. In this work, we show that the inclusion of trace amounts of electrolyte additives, such as H$_2$O, significantly improve the capacity of the Li-O$_2$ battery. These additives trigger a solution-based growth mechanism due to their solvating properties, thereby circumventing the Li$_2$O$_2$ conductivity limitation. Experimental observations and a growth model imply that this solution mechanism is responsible for Li$_2$ toroid formation. We present a general formalism describing an additive$'$s tendency to trigger the solution process, providing a rational design route for electrolytes t...

  18. Optically pumped cerium-doped LiSrAlF{sub 6} and LiCaAlF{sub 6}

    DOE Patents [OSTI]

    Marshall, C.D.; Payne, S.A.; Krupke, W.F.

    1996-05-14T23:59:59.000Z

    Ce{sup 3+}-doped LiSrAlF{sub 6} crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF{sub 6} with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF{sub 6} type of chemical formula, e.g. Ce-doped LiCaAlF{sub 6} and LiSrGaF{sub 6}, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator. 10 figs.

  19. Optically pumped cerium-doped LiSrAlF.sub.6 and LiCaAlF.sub.6

    DOE Patents [OSTI]

    Marshall, Christopher D. (Livermore, CA); Payne, Stephen A. (Castro Valley, CA); Krupke, William F. (Pleasanton, CA)

    1996-01-01T23:59:59.000Z

    Ce.sup.3+ -doped LiSrAlF.sub.6 crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF.sub.6 with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF.sub.6 type of chemical formula, e.g. Ce-doped LiCaAlF.sub.6 and LiSrGaF.sub.6, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator.

  20. Development of High Capacity Anode for Li-ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    stability of Si-based anode. 4 Milestones * Synthesize and characterize TiO 2 Graphene and SnO 2 Graphene nano-composite as anode for Li-ion batteries. - on going *...

  1. BPA's LiDAR program maps corridor to success

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    analyzed by BPA's LiDAR program. The animation was produced by Ryan Beck and Drew Thompson in BPA's Geospatial Services group. Sometimes the pace of change is imperceptible,...

  2. Structure of Liquid PEO-LiTFSI Electrolyte

    SciTech Connect (OSTI)

    Mao, Guomin; Saboungi, Marie-Louise; Price, David L.; Armand, Michel B.; Howells, W. S.

    2000-06-12T23:59:59.000Z

    The structure of a polymer electrolyte, P(EO){sub 7.5}LiN (SO{sub 2} CF{sub 3}){sub 2} , has been determined by neutron diffraction with isotropic substitution. The Li ions are bonded on average to five ether oxygens belonging to pairs of PEO coils. These are arranged with a considerable degree of extended-range order providing pathways for the Li ion conduction. The lack of ion pairing in this system below 4.8 Angstrom is reminiscent of that observed in the remarkable structure of P(EO){sub 6}LiAsF {sub 6} and implies that anions and cations are free to migrate independently. (c) 2000 The American Physical Society.

  3. Construction Sonsultants L.I., Notification of Intent to Investigate

    Broader source: Energy.gov (indexed) [DOE]

    1, 2015 Mr. Joel Itzkowitz OwnerPresident Construction Consultants L.I., Inc. 36 East 2nd Street Riverhead, New York 11901 Dear Mr. Itzkowitz: This letter serves as notification...

  4. Modeling - Scale-Bridging Simulations Active Materials in Li...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Society, v. 154 (10), pp. A978-A986. 3. Wang, C.-W. and Sastry, A.M., 2007, "Mesoscale Modeling of a Li-Ion Poly Cell," Journal of the Electrochemical Society, v. 154...

  5. atoms li na: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ground (doublet) atomic 2S(L 0)-state. It is straightforward to generalize our analysis to other bound states of the three-electron Li atom. Alexei M. Frolov; David M....

  6. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Broader source: Energy.gov (indexed) [DOE]

    Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio Project ID ARRAVT008 Joe DiCarlo BASF Corporation May 11, 2011 "This presentation does not contain...

  7. Heteroclite electrochemical stability of an I based Li7P2S8I superionic conductor

    SciTech Connect (OSTI)

    Rangasamy, Ezhiylmurugan [ORNL; Liu, Zengcai [ORNL; Gobet, Mallory [Hunter College of the City University of New York; Pilar, Kartik [Hunter College, City University of New York (CUNY); Sahu, Gayatri [ORNL; Greenbaum, Steve [Hunter College of the City University of New York; Liang, Chengdu [ORNL

    2015-01-01T23:59:59.000Z

    Stability from Instability: A Li7P2S8I solid state Li-ion conductor derived from -Li3PS4 and LiI demonstrates exceptional electrochemical stability. The oxidation instability of I is subverted nullified via its incorporation into the coordinated structure. The inclusion of I also creates stability with metallic Li anode while simultaneously improving the interfacial kinetics. Low temperature membrane processability enables facile fabrication of dense membranes, making it suitable for industrial adoption.

  8. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    Program 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh 80th 1st 50th 1.0 m LiPF 6 in ECEMC (30:70) with 1% ARL-3 on LiNi 0.5 Mn 1.5 O 4 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh...

  9. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    long cycling 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh 80th 1st 50th 1.0 m LiPF 6 in ECEMC (30:70) with 1% ARL-3 on LiNi 0.5 Mn 1.5 O 4 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh...

  10. Interactions of Relativistic $^6$Li Nuclei with Photoemulsion Nuclei

    E-Print Network [OSTI]

    Adamovich, M I; Larionova, V G; Peresadko, N G; Kharlamov, S P; Bogdanov, V G; Plyushchev, V A; Solovyeva, Z I; 10.1063/S6208-1378(99)007788

    2011-01-01T23:59:59.000Z

    Inelastic interactions of nuclei accelerated to a momentum of 4.5 GeV/$c$ per projectile nucleon with photoemulsion nuclei have been investigated. The main features of these interactions - mean ranges of $^6$Li nuclei, mean multiplicities of secondaries, the isotopic composition of fragments, fragmentation channels, and the mean transverse momenta of projectile fragments - have been measured. The probability of the charge-exchange reaction featuring lithium nuclei has been determined. The results obtained for the $^6$Li nucleus have been compared with data for other nuclei. The observed features of $^6$Li interactions with other nuclei indicate that the $^6$Li structure in the form of the loosely bound system consisting of an $\\alpha$-particle and a deuteron cluster clearly manifests itself in these interactions. Events resulting in the coherent dissociation of $^6$Li nuclei into $^4$He+$d$, $^3$He+$t$, and $t+d+p$ and involving low-lying excitations of $^6$Li have been observed.

  11. Interactions of Relativistic $^6$Li Nuclei with Photoemulsion Nuclei

    E-Print Network [OSTI]

    M. I. Adamovich; I. A. Konorov; V. G. Larionova; N. G. Peresadko; S. P. Kharlamov; V. G. Bogdanov; V. A. Plyushchev; Z. I. Solovyeva

    2011-09-29T23:59:59.000Z

    Inelastic interactions of nuclei accelerated to a momentum of 4.5 GeV/$c$ per projectile nucleon with photoemulsion nuclei have been investigated. The main features of these interactions - mean ranges of $^6$Li nuclei, mean multiplicities of secondaries, the isotopic composition of fragments, fragmentation channels, and the mean transverse momenta of projectile fragments - have been measured. The probability of the charge-exchange reaction featuring lithium nuclei has been determined. The results obtained for the $^6$Li nucleus have been compared with data for other nuclei. The observed features of $^6$Li interactions with other nuclei indicate that the $^6$Li structure in the form of the loosely bound system consisting of an $\\alpha$-particle and a deuteron cluster clearly manifests itself in these interactions. Events resulting in the coherent dissociation of $^6$Li nuclei into $^4$He+$d$, $^3$He+$t$, and $t+d+p$ and involving low-lying excitations of $^6$Li have been observed.

  12. Lithium hydroxide, LiOH, at elevated densities

    SciTech Connect (OSTI)

    Hermann, Andreas [School of Physics and Astronomy and Centre for Science at Extreme Conditions, The University of Edinburgh, Edinburgh EH9 3JZ (United Kingdom); Ashcroft, N. W. [Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, New York 14853 (United States); Hoffmann, Roald [Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853 (United States)

    2014-07-14T23:59:59.000Z

    We discuss the high-pressure phases of crystalline lithium hydroxide, LiOH. Using first-principles calculations, and assisted by evolutionary structure searches, we reproduce the experimentally known phase transition under pressure, but we suggest that the high-pressure phase LiOH-III be assigned to a new hydrogen-bonded tetragonal structure type that is unique amongst alkali hydroxides. LiOH is at the intersection of both ionic and hydrogen bonding, and we examine the various ensuing structural features and their energetic driving mechanisms. At P = 17 GPa, we predict another phase transition to a new phase, Pbcm-LiOH-IV, which we find to be stable over a wide pressure range. Eventually, at extremely high pressures of 1100 GPa, the ground state of LiOH is predicted to become a polymeric structure with an unusual graphitic oxygen-hydrogen net. However, because of its ionic character, the anticipated metallization of LiOH is much delayed; in fact, its electronic band gap increases monotonically into the TPa pressure range.

  13. Identity of Passive Film Formed on Aluminum in Li-ion BatteryElectrolytes with LiPF6

    SciTech Connect (OSTI)

    Zhang, Xueyuan; Devine, T.M.

    2006-09-01T23:59:59.000Z

    The passive film that forms on aluminum in 1:1 ethylene carbonate + ethylmethyl carbonate with 1.2M LiPF{sub 6} and 1:1 ethylene carbonate + dimethyl carbonate with 1.0M LiPF{sub 6} was investigated by a combination of electrochemical quartz crystal microbalance measurements (EQCM), electrochemical impedance spectroscopy (EIS), and x-ray photoelectron spectroscopy. During anodic polarization of aluminum a film of AlF{sub 3} forms on top of the air-formed oxide, creating a duplex, or two-layered film. The thickness of the AlF{sub 3} increases with the applied potential. Independent measurements of film thickness by EQCM and EIS indicate that at a potential of 5.5V vs. Li/Li{sup +}, the thickness of the AlF{sub 3} is approximately 1 nm.

  14. Structural Evolution and Li Dynamics in Nanophase Li3PS4 by Solid-State and Pulsed Field Gradient NMR

    SciTech Connect (OSTI)

    Gobet, Mallory [Hunter College of the City University of New York] [Hunter College of the City University of New York; Greenbaum, Steve [Hunter College of the City University of New York] [Hunter College of the City University of New York; Sahu, Gayatri [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    The ceramic lithium ion conductor -Li3PS4 has a disordered and nanoporous structure that leads to an enhancement in ionic conductivity by some three orders of magnitude compared to the crystalline phase. The phase is prepared by thermal treatment of an inorganic-organic complex based on Li3PS4 and THF. Multinuclear (1H, 6,7Li, 31P) solid state NMR spectroscopy is used to characterize the structural phase evolution of the starting material at various steps in the thermal treatment. The phase formed after high temperature treatment is recognized as spectroscopically distinct from the bulk -Li3PS4 compound. Also formed is an amorphous lithium thiophosphate phase that is metastable as verified by annealing over an extended period. Lithium ion self-diffusion coefficients are measurable by standard pulsed gradient NMR methods at 100oC and with values consistent with the high ionic conductivity previously reported for this material.

  15. The partially reversible formation of Li-metal particles on a solid Li electrolyte: applications toward nanobatteries

    SciTech Connect (OSTI)

    Arruda, Thomas M [ORNL; Kumar, Amit [ORNL; Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL

    2012-01-01T23:59:59.000Z

    The feasibility of large-scale implementation of Li-air batteries (LABs) hinges on understanding the thermodynamic and kinetic factors that control charge-discharge rates, efficiency and life times. Here, the kinetics of bias-induced reactions is explored locally on the surface of Li-ion conductive glass ceramics, a preferred electrolyte for LABs, using direct current-voltage and strain spectroscopies. Above a critical bias, particle growth kinetics were found to be linear in both the bias and time domains. Partial reversibility was observed for Li particles as evidenced by the presence of anodic peaks following the Li{sup +} reduction, as well an associated reduction in particle height. The degree of reversibility was highest for the smallest particles formed. These observations thus suggest the possibility of producing nanobatteries with an active anode volume of the order of 0.1 al.

  16. http://lez1.pppl.gov/pub/LiMagPropulsion.ps http://lez1.pppl.gov/pub/LiMagPropulsion.pdf

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    http://lez1.pppl.gov/pub/LiMagPropulsion.ps http://lez1.pppl.gov/pub/LiMagPropulsion.pdf Magnetic propulsion for driving liquid Li walls L. E. Zakharov, PPPL Background: The mechanism of magnetic propulsion the technical aspects of magnetic propulsion, the issues and the necessary R & D. Electro-magnetic propulsion

  17. Structural and Electrochemical Characterization of PureLiFePO4and Nanocomposite C-LiFePO4Cathodes for Lithium Ion Rechargeable Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumar, Arun; Thomas, R.; Karan, N. K.; Saavedra-Arias, J. J.; Singh, M. K.; Majumder, S. B.; Tomar, M. S.; Katiyar, R. S.

    2009-01-01T23:59:59.000Z

    Pure lithium iron phosphate (LiFePO4) and carbon-coatedLiFePO4(C-LiFePO4) cathode materials were synthesized for Li-ion batteries. Structural and electrochemical properties of these materials were compared. X-ray diffraction revealed orthorhombic olivine structure. Micro-Raman scattering analysis indicates amorphous carbon, and TEM micrographs show carbon coating onLiFePO4particles. Ex situ Raman spectrum of C-LiFePO4at various stages of charging and discharging showed reversibility upon electrochemical cycling. The cyclic voltammograms ofLiFePO4and C-LiFePO4showed only a pair of peaks corresponding to the anodic and cathodic reactions. The first discharge capacities were 63, 43, and 13?mAh/g for C/5, C/3, and C/2, respectively forLiFePO4where as in case of C-LiFePO4that were 163, 144,more »118, and 70?mAh/g for C/5, C/3, C/2, and 1C, respectively. The capacity retention of pureLiFePO4was 69% after 25 cycles where as that of C-LiFePO4was around 97% after 50 cycles. These results indicate that the capacity and the rate capability improved significantly upon carbon coating.« less

  18. Symposium on Advanced Energy Systems Symposium Chair: Xianguo Li, University of Waterloo (x6li@uwaterloo.ca)

    E-Print Network [OSTI]

    and hydrogen · Advanced energy storage and energy distribution technologies · Energy conservation and analysis · Green and renewable energy resources and technologies · Advanced energy conversion technologies and management · Micro/Nanotechnology for energy applications · Advanced environmental protection technologies

  19. The interference effect of laser-assisted bremsstrahlung emission in Coulomb fields of Ankang Li, Jiaxiang Wang, Na Ren, Pingxiao Wang, Wenjun Zhu, Xiaoya Li, Ross Hoehn, and Sabre Kais

    E-Print Network [OSTI]

    Kais, Sabre

    Ankang Li, Jiaxiang Wang, Na Ren, Pingxiao Wang, Wenjun Zhu, Xiaoya Li, Ross Hoehn, and Sabre Kais Li,3 Ross Hoehn,4 and Sabre Kais4,5 1 State Key Laboratory of Precision Spectroscopy and Department

  20. Patterning of graphene Wenbin Li,b

    E-Print Network [OSTI]

    Chen, Sow-Hsin

    is a graduate student in the Department of Materials Science and Engineering at MIT, under the supervision of Physics, Peking University, Beijing 100871, China b Department of Nuclear Science and Engineering. But the ensuing impact on physics, materials science and chemistry has been broad, entailing many fundamental

  1. High Performance Cathodes for Li-Air Batteries

    SciTech Connect (OSTI)

    Xing, Yangchuan

    2013-08-22T23:59:59.000Z

    The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

  2. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    E-Print Network [OSTI]

    Chen, Jiajun

    2010-01-01T23:59:59.000Z

    of nanosized LiMnPO 4 by combustion synthesis Figure 2. X-a) nanometric LiMnPO 4 made by combustion synthesis and b)typically formed by combustion synthesis. The average

  3. Comparison of LiMnPO4 made by Combustion and Hydrothermal Syntheses

    E-Print Network [OSTI]

    Chen, Jiajun

    2008-01-01T23:59:59.000Z

    of nanosized LiMnPO 4 by combustion synthesis Figure 2. X-a) nanometric LiMnPO 4 made by combustion synthesis and b)typically formed by combustion synthesis. The average

  4. Investigation of Mechanical Activation on Li-N-H Systems Using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    resolution in the 6Li MAS NMR spectra of Li-N-H systems at ultra-high field of 21.1 tesla is exploited, for the first time, to study the detailed electronic and chemical...

  5. Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li-Ion Battery Anodes. Hollow Core-Shell Structured Porous Si-C Nanocomposites for Li-Ion Battery Anodes. Abstract:...

  6. Effects of Laser Energy and Wavelength on the Analysis of LiFePO4...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser Energy and Wavelength on the Analysis of LiFePO4 Using Laser Assisted Atom Probe Tomography. Effects of Laser Energy and Wavelength on the Analysis of LiFePO4 Using Laser...

  7. Stability of polymer binders in Li-O2 batteries. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stability of polymer binders in Li-O2 batteries. Stability of polymer binders in Li-O2 batteries. Abstract: A number of polymers with various chemical structures were studied as...

  8. Effects of electrolyte salts on the performance of Li-O2 batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrolyte salts on the performance of Li-O2 batteries. Effects of electrolyte salts on the performance of Li-O2 batteries. Abstract: It is well known that the stability of...

  9. Preparation and electrochemical investigation of Li2CoPO4F cathode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrochemical investigation of Li2CoPO4F cathode material forlithium-ion batteries. Preparation and electrochemical investigation of Li2CoPO4F cathode material forlithium-ion...

  10. Investigation of the Rechargeability of Li-O2 Batteries in Non...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte. Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte. Abstract: In order to...

  11. A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes. A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes. Abstract: Silicon is...

  12. BornOppenheimer breakdown in a combined-isotopomer analysis system of Li2

    E-Print Network [OSTI]

    Le Roy, Robert J.

    of 6,7 Li2 , and new Fourier transform data for the homonuclear lithium dimers. They are combined nonhydride systems for studying such interactions. Moreover, in view of the prominence of Li2 in studies

  13. Li+ alumino-silicate ion source development for the Neutralized Drift Compression Experiment (NDCX-II)

    E-Print Network [OSTI]

    Roy, P.K.

    2011-01-01T23:59:59.000Z

    LBNL-3748E Li+ alumino-silicate ion source development for05CH11231. Li + alumino-silicate ion source development forlithium from the alumino-silicate material either as ions or

  14. Revisit Carbon/Sulfur Composite for Li-S Batteries. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Revisit CarbonSulfur Composite for Li-S Batteries. Revisit CarbonSulfur Composite for Li-S Batteries. Abstract: To correlate the carbon properties e.g. surface area and porous...

  15. Template Free Synthesis of LiV3O8 Nanorods as a Cathode Material...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Free Synthesis of LiV3O8 Nanorods as a Cathode Material for High-Rate Secondary Lithium Batteries . Template Free Synthesis of LiV3O8 Nanorods as a Cathode Material for...

  16. Lithium fluoride (LiF) crystal for parametric X-ray (PXR) production

    E-Print Network [OSTI]

    Danon, Yaron

    Lithium fluoride (LiF) crystal for parametric X-ray (PXR) production B. Sones *, Y. Danon, R 2004 Abstract Parametric X-ray (PXR) production is reported using lithium fluoride (LiF) as a target

  17. Nanosheet-structured LiV3O8 with high capacity and excellent...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanosheet-structured LiV3O8 with high capacity and excellent stability for high energy lithium batteries . Nanosheet-structured LiV3O8 with high capacity and excellent stability...

  18. Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Li-Ion Polymer Battery Cell Manufacturing Plant in USA Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  19. Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Graphite and Olivine-Based Materials for Li-Ion Batteries Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries Presentation from the U.S. DOE Office of Vehicle...

  20. Development of Cell/Pack Level Models for Automotive Li-Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CellPack Level Models for Automotive Li-Ion Batteries with Experimental Validation Development of CellPack Level Models for Automotive Li-Ion Batteries with Experimental...

  1. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption...

    Broader source: Energy.gov (indexed) [DOE]

    Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP...

  2. Alternating magnetic anisotropy of Li 2 ( Li 1 - x T x ) N ( T = Mn , Fe , Co , and Ni )

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-01T23:59:59.000Z

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li?(Li1-xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model. The calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.

  3. Alternating magnetic anisotropy of Li 2 ( Li 1 - x T x ) N ( T = Mn , Fe , Co , and Ni )

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-01T23:59:59.000Z

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li?(Li1-xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.more »The calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.« less

  4. Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, Thomas M.

    2008-01-01T23:59:59.000Z

    of Aluminum in Lithium-ion Battery Electrolytes with LiBOBin commercially available lithium-ion battery electrolytes,

  5. Rate coefficient for the chemi-ionization in slow Li*(n)+Li and Na*(n)+Na collisions

    SciTech Connect (OSTI)

    Ignjatovic, Lj.M.; Mihajlov, A.A. [Institute of Physics, P. O. Box 68, 11080 Zemun, Belgrade (Serbia and Montenegro)

    2005-08-15T23:59:59.000Z

    The chemi-ionization processes in slow-atom-Rydberg-atom collisions are considered in this paper. A version of the semiclassical method of rate coefficient calculation that is free of the presumptions which significantly limited its applicability previously is presented. The method is applied to the cases of Li*(n)+Li and Na*(n)+Na collisions for the principal quantum numbers 5{<=}n{<=}25 and temperatures 600{<=}T{<=}1200 K. The results of calculation of the rate coefficients of the corresponding chemi-ionization processes are compared to the existing experimental data from the literature.

  6. Comment on Li pellet conditioning in tokamak fusion test reactor R. V. Budny

    E-Print Network [OSTI]

    Budny, Robert

    Comment on Li pellet conditioning in tokamak fusion test reactor R. V. Budny Princeton Plasma; published online 9 September 2011) Li pellet conditioning in TFTR results in a reduction of the edge technique for introducing Li is via pellet injection. This was pioneered in ALCATOR- CMOD where it was first

  7. Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide (LiHMDS)

    E-Print Network [OSTI]

    Collum, David B.

    Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide, and 13C NMR spectroscopic studies of 6Li-15N labeled lithium hexamethyldisilazide ([6Li,15N]- Li ligand structure and lithium amide aggregation state is a complex and sensitive function of amine alkyl

  8. Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, Thomas M.

    2008-01-01T23:59:59.000Z

    pitting corrosion of aluminum in 1M LiTFSI. The protectiveAnodic Polarization of Aluminum in 1:1 EC+DMC with 1M LiBOBdeposited thin film of aluminum in 1:1 EC+DMC with 1M LiBOB.

  9. Impact of Li-6 Enrichment ... -1-MZ. Youssef MZY_APEX_98_2

    E-Print Network [OSTI]

    California at Los Angeles, University of

    Impact of Li-6 Enrichment ... -1- MZ. Youssef MZY_APEX_98_2 APEX Study Memorandum MZY_APEX_98_2 March 24.1998 Title: Impact of Li-6 Enrichment of the Convective Layer on Damage and Heat Deposition_1), the impact of Li-6 enrichment inside the Convective layer (Lithium, Flibe) on the total neutron flux

  10. High Capacity Li Ion Battery Anodes Using Ge Nanowires

    E-Print Network [OSTI]

    Cui, Yi

    High Capacity Li Ion Battery Anodes Using Ge Nanowires Candace K. Chan, Xiao Feng Zhang, and Yi Cui efficiency > 99%. Structural characterization revealed that the Ge nanowires remain intact and connected nanowire anodes are promising candidates for the development of high-energy-density lithium batteries

  11. LiU E-Press Newsletter Autumn, 2006

    E-Print Network [OSTI]

    Zhao, Yuxiao

    that virtually all Ph.D., licentiate and undergraduate theses are published on the internet through E at least 90% of the Ph.D. the- ses, licentiate theses and undergraduate theses that are produced at Li publishing of articles. Licentiate theses follow a similar trend (and percentages) to those shown for Ph

  12. Neutronic assessment of He-cooled molten Li fusion blanket

    SciTech Connect (OSTI)

    Han, B. [Nuclear Engineering Dept., Seoul National Univ., San 56-1, Shinlim-dong, Kwanak-gu, Seoul (Korea, Republic of); Kim, Y. [Korea Atomic Energy Research Inst., 150, Deokjin-dong, Yuseong-gu, Daejeon (Korea, Republic of); Kim, C. H. [Nuclear Engineering Dept., Seoul National Univ., San 56-1, Shinlim-dong, Kwanak-gu, Seoul (Korea, Republic of)

    2006-07-01T23:59:59.000Z

    This study is intended to assess overall neutronic performances of He-cooled molten Li (HCML) blanket with a reflector and investigate the impact of {sup 6}Li enrichment on tritium breeding ratio (TBR). To precisely evaluate the neutronic performances of the reflected HCML blanket, three-dimensional D-shape torus model is utilized and Monte-Carlo calculations are performed. In this study, the neutronic characteristics of five potential reflector candidates are compared and the reflected blanket is also optimized from the neutronic point of view. Taking into account the material availability and potential safety features, a high-density graphite reflector can be a practical choice for a high-performance HCML blanket. The graphite-reflected HCML blanket shows the best performances when the reflector is placed such that the blanket is divided into a thick front region and a thin back region. The HCML blanket with a slightly-enriched Li (8-10 wt% {sup 6}Li) breeder shows the highest TBR. (authors)

  13. Overview of design activities for Li/V blankets

    SciTech Connect (OSTI)

    Sze, D.K.; Mattas, R.F.

    1997-12-31T23:59:59.000Z

    Recent fusion power plant design studies in the US have been conducted within the ARIES project. The most recent design of Li/V blankets was conducted as part of the ARIES-RS design. The ARIES-RS fusion power plant design study is based on reversed-shear (RS) physics with a Li/V (lithium breeder and vanadium structure) blanket. The reversed-shear discharge has been documented in many large tokamak experiments. The plasma in the RS mode has a high beta, low current, and low current drive requirement. Therefore, it is an attractive physics regime for a fusion power plant. The blanket system based on a Li/V has high temperature operating capability, good tritium breeding, excellent high heat flux removal capability, long structural life time, low activation, low after heat and good safety characteristics. For these reasons, the ARIES-RS reactor study selected Li/V as the reference blanket. The combination of attractive physics and attractive blanket engineering is expected to result in a superior power plant design.

  14. How Many Species Can Two Essential Resources Support? Bingtuan Li #

    E-Print Network [OSTI]

    and for two species to coexist, driving the others to extinction. In case n = 3, it is shown that every extinct. Every solution approaches a single­species or two­species steady state. However, as already notedHow Many Species Can Two Essential Resources Support? Bingtuan Li # Department of Mathematics

  15. Passive Control of Bilateral Teleoperated Manipulators Perry Y. Li

    E-Print Network [OSTI]

    Li, Perry Y.

    Passive Control of Bilateral Teleoperated Manipulators Perry Y. Li Department of Mechanical of a bilateral teleoperated manipulator system is considered. The goal of the control are to i) coordinate needs to take place and a master manipulator at a possibly remote site under the direct control

  16. Optimal decision making in ventilation control Andrew Kusiak*, Mingyang Li

    E-Print Network [OSTI]

    Kusiak, Andrew

    by heating, ventilating and air- conditioning (HVAC) systems. According to published statistics, HVAC systemsOptimal decision making in ventilation control Andrew Kusiak*, Mingyang Li Department of Mechanical Accepted 24 July 2009 Available online 15 August 2009 Keywords: Ventilation Air quality Multi

  17. Solar Photovoltaic Capacity F t P f d P li

    E-Print Network [OSTI]

    6/19/2013 1 Solar Photovoltaic ­ Capacity F t P f d P li Generating Resources Advisory Committee Advisor Model (SAM), version 2013.1.15 Technology: Solar PV (PVWatts system model)Technology: Solar PV (MWh) (First year output, each year thereafter degrades 0.5%) 6 #12;6/19/2013 4 Shape of PNW Solar PV

  18. ARMA systems in wind engineering Yousun Li and A. Kareem

    E-Print Network [OSTI]

    Kareem, Ahsan

    ARMA systems in wind engineering Yousun Li and A. Kareem Structural Aerodynamics and Ocean System The time domain solution of the equations of motion of structures subjected to a stochastic wind field histories of the aerodynamic force. Recently, autoregressive and moving average (ARMA) recursive models have

  19. Polymer geometry and Li+ conduction in poly(ethylene oxide)

    E-Print Network [OSTI]

    Averbuch, Amir

    Polymer geometry and Li+ conduction in poly(ethylene oxide) L. Gitelman a , M. Israeli b, , A: Lithium battery Polymer molecule Brownian motion Simulation Conductivity PEO a b s t r a c t We study of the amorphous PE structure is increased by mechanical stretching due to the unraveling of loops in the polymer

  20. -OK 8>00jigLi Metallurgy Department

    E-Print Network [OSTI]

    -OK 8°>00jigLi 00 tf) Risø-M-28B Metallurgy Department Publications 1988 Risø National Laboratory, DK-4000 Roskilde, Denmark August 1989 #12;Metallurgy Department Publications 1988 Edited by A by the staffof the Metallurgy Department during 1988 is given. The list comprises journal papers, conference

  1. Spring 2014 CISC1600 Yanjun Li 1 Introduction to

    E-Print Network [OSTI]

    Li, Yanjun "Lisa"

    units on secondary storage devices (like hard disk and flash dri are the electronic and mechanical parts. hardware devices Keyboard, mouse, etc. Screen (monitor) Disks Memory 2014 CISC1600 Yanjun Li 14 Secondary storage Stores programs or data not currently being used by other

  2. Comment on Li pellet conditioning in tokamak fusion test reactor

    SciTech Connect (OSTI)

    Budny, R. V. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)

    2011-09-15T23:59:59.000Z

    Li pellet conditioning in TFTR results in a reduction of the edge electron density which allows increased neutral beam penetration, central heating, and fueling. Consequently, the temperature profiles became more peaked with higher central T{sub i}, T{sub e}, toroidal rotation, and neutron emission rates.

  3. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    0.992 0.994 0.996 0.998 1 0 100 200 300 400 500 600 700 Baseline: 1.2 M LiPF 6 in ECEMC (30:70) Baseline + 5 mM PFBP Baseline + 10 mM AFAC Cycle Number ANL LMNOGR Full Cells...

  4. Polymer graphite composite anodes for Li-ion batteries

    E-Print Network [OSTI]

    Popov, Branko N.

    Polymer graphite composite anodes for Li-ion batteries Basker Veeraraghavan, Bala Haran, Ralph for the graphite particles by in-situ polymerization #12;Experimental Preparation of PPy/Graphite composites Dropwise addition of pyrrole into aqueous slurry of graphite at 0 °C with nitric acid acting as an oxidizer

  5. The Grid Workloads Archive Alexandru Iosup a,, Hui Li b

    E-Print Network [OSTI]

    Iosup, Alexandru

    The Grid Workloads Archive Alexandru Iosup a,, Hui Li b , Mathieu Jan a , Shanny Anoep a , Catalin, The Netherlands Abstract While large grids are currently supporting the work of thousands of scientists, very or no traces of grid workloads available to the grid researcher and practitioner. To address this problem

  6. Lithium Lorentz Force Accelerator Thruster (LiLFA)

    E-Print Network [OSTI]

    Petta, Jason

    Argon Flow Copper Water Flow Piston/Lithium Feeding System Lithium Flow Pipes Heaters Heaters MAI Li procedure · Fire the thruster! #12;Previous Firing #12;Conclusions · Heaters and Thermocouples · Water Vacuum Pumps Thrust Stand Main Tank Water Line In Water Line Out Power Lines Computer Data Acquisition

  7. Method for treating electrolyte to remove Li{sub 2}O

    DOE Patents [OSTI]

    Tomczuk, Z.; Miller, W.E.; Johnson, G.K.; Willit, J.L.

    1998-01-20T23:59:59.000Z

    A method is described for removing Li{sub 2}O present in an electrolyte predominantly of LiCl and KCl. The electrolyte is heated to a temperature not less than about 500 C and then Al is introduced into the electrolyte in an amount in excess of the stoichiometric amount needed to convert the Li{sub 2}O to a Li-Al alloy and lithium aluminate salt. The salt and aluminum are maintained in contact with agitation for a time sufficient to convert the Li{sub 2}O.

  8. Modeling the interface of Li metal and Li solid electrolytes from first principles Nicholas Lepley, N. A. W. Holzwarth

    E-Print Network [OSTI]

    Holzwarth, Natalie

    battery electrolytes. Simplified theoretical models often fail to agree with experimental observations are of considerable interest for Li-ion battery applications, both for their use as thin films capable of passivating." Physical Review B 88.10 (2013): 104103. 2. Kuwata, Naoaki, et al. "Characterization of thin-film lithium

  9. Effect of mineralogy, salinity, and temperature on Li/Ca and Li isotope composition of calcium carbonate

    E-Print Network [OSTI]

    Henderson, Gideon

    during growth of calcium carbonate. This study improves such understanding with two sets of new). This suggests little biological control during Li incorporation into biogenic calcium carbonates. The difference­15 www.elsevier.com/locate/chemgeo #12;1. Introduction Natural calcium carbonate may provide an archive

  10. Maximum Li storage in Si nanowires for the high capacity three-dimensional Li-ion battery

    E-Print Network [OSTI]

    Jo, Moon-Ho

    , such as fuel cells and secondary batteries. Here we report a coin-type Si nanowire NW half-cell Li-ion battery is the central research subject in various energy conversion systems, such as solar cells, fuel cells must be optimally coordinated.7 In this respect, Si nanowire NW arrays can serve as the high capacity

  11. Corrosion and anodic behavior of lithium in solutions of the system LiC1-LiOH-H/sub 2/O

    SciTech Connect (OSTI)

    Konstantinova, M.V.; Demidov, A.I.; Morachevskii, A.G.

    1986-03-10T23:59:59.000Z

    The study of the electrochemical behavior of lithium in aqueous electrolyte solutions is of interest to the development of water-activated electrochemical cells. This paper reports the results of a study of the electrochemical behavior of lithium in solutions of the system LiC1-LiOH-H/sub 2/O ( /SUP m/ LiC1 = 0.4-1.2, /SUP m/ LiOH = 3.1-4.2, where m is the molality) at 298 K. Solutions of the specificed compositions have the highest conductivity in this system. The LiC1 and LiOH concentrations in solutions of the specified compositions were found by analytical determination of their chloride and hydroxide ion contents. The investigations show that addition of lithium chloride to the LiOH-H/sub 2/O electrolyte lowers the rate of lithium corrosion in solution by a factor of 1.5-4. The influence of added LiC1 on the corrosion rate of the metal is stronger in electrolytes of lower LiOH concentrations.

  12. Identifying the structure of the intermediate, Li_2/3CoPO_4, formed during electrochemical cycling of LiCoPO_4

    E-Print Network [OSTI]

    Strobridge, Fiona C.; Clément, Raphaële J.; Leskes, Michal; Middlemiss, Derek S.; Borkiewicz, Olaf J.; Wiaderek, Kamila M.; Chapman, Karena W.; Chupas, Peter J.; Grey, Clare P.

    2014-10-09T23:59:59.000Z

    Ah/g (compared to the practical capacity of 140 mAh/g for LiCoO2, 3 the commonly used cathode in the portable communications industry). However, the low operating voltage of LiFePO4 leads to an energy density that is considered low for use in electric... in situ cell in an argon-filled glove box, using Li metal as the counter electrode, a Whatman GF/B borosilicate microfiber filter as the separator, and 1 M LiPF6 solution in a 1:1 mixture of ethylene car- bonate/dimethyl carbonate as the electrolyte...

  13. Structural Underpinnings of the Enhanced Cycling Stability upon Al-Substitution in LiNi0.45Mn0.45Co0.1-yAlyO2 Positive Electrode Materials for Li-ion Batteries

    E-Print Network [OSTI]

    Conry, Thomas E.

    2013-01-01T23:59:59.000Z

    materials for Li-ion batteries Thomas E. Conry, a,b Apurvamaterials in Li-ion batteries. Synchrotron-based high-materials for Li-ion batteries. LiNi z Mn z Co 1-2z O 2 (NMC

  14. Magnetism reflectometer study shows LiF layers improve efficiency in spin valve devices

    SciTech Connect (OSTI)

    Bardoel, Agatha A [ORNL; Lauter, Valeria [ORNL; Szulczewski, Greg J [ORNL

    2012-01-01T23:59:59.000Z

    New, more efficient materials for spin valves - a device used in magnetic sensors, random access memories, and hard disk drives - may be on the way based on research using the magnetism reflectometer at Oak Ridge National Laboratory (ORNL). Spin valve devices work by means of two or more conducting magnetic material layers that alternate their electrical resistance depending on the layers alignment. Giant magnetoresistance is a quantum mechanical effect first observed in thin film structures about 20 years ago. The effect is observed as a significant change in electrical resistance, depending on whether the magnetization of adjacent ferromagnetic layers is in a parallel or an antiparallel magnetic alignment. 'What we are doing here is developing new materials. The search for new materials suitable for injecting and transferring carriers with a preferential spin orientation is most important for the development of spintronics,' said Valeria Lauter, lead instrument scientist on the magnetism reflectometer at the Spallation Neutron Source (SNS), who collaborated on the experiment. The researchers discovered that the conductivity of such materials is improved when an organic polymer semiconductor layer is placed between the magnetic materials. Organic semiconductors are now the material of choice for future spin valve devices because they preserve spin coherence over longer times and distances than conventional semiconductors. While research into spin valves has been ongoing, research into organic semiconductors is recent. Previous research has shown that a 'conductivity mismatch' exists in spin valve systems in which ferromagnetic metal electrodes interface with such organic semiconductors as Alq3 ({pi}-conjugated molecule tris(8-hydroxy-quinoline) aluminium). This mismatch limits the efficient injection of the electrons from the electrodes at the interface with the semiconductor material. However, lithium fluoride (LiF), commonly used in light-emitting diodes, has been found to enhance the injection of electrons through the semiconductor. Researchers from the University of Alabama and ORNL used polarized neutrons at the magnetism reflectometer at SNS to investigate the electronic, magnetic, and structural properties of the electrodes in a novel system. In this system, the magnetic layers cobalt and Ni{sub 80}Fe{sub 20} are interfaced with spacer layers composed of the organic semiconductor Alq3. A coupling layer of LiF is inserted to separate the magnetized layers from the semiconductor. 'ALQ3 is an organic semiconductor material,' said Lauter. 'Normally in these systems a first magnetic layer is grown on a hard substrate so that one can get the controlled magnetic parameters. Then you grow the organic semiconductor layer, followed by another magnetic material layer, such as cobalt.' In addition to determining the effect of the LiF layers on the efficiency of the electron injection, the researchers wanted to determine the magnetic properties of the cobalt and Ni{sub 80}Fe{sub 20} as well as the interfacial properties: whether there is interdiffusion of cobalt through the LiF layer to the semiconductor, for example. The researchers used polarized neutrons at beam line 4A to probe the entire, layer-by-layer assembly of the system. 'Reflectometry with polarized neutrons is a perfect method to study thin magnetic films,' Lauter said. 'These thin films - if you put one on a substrate, you see it just like a mirror. However, this mirror has a very complicated internal multilayer structure. The neutrons look inside this complicated structure and characterize each and every interface. Due to the depth sensitivity of the method, we measure the structural and magnetic properties of each layer with the resolution of 0.5 nm. The neutron scattering results found that inserting LiF as a barrier significantly improves the quality of the interface, increasing the injection of electrons from the magnetic layer through the organic semiconductor in the spin valve and enhancing the overall properties of the system. In related work the magneti

  15. mRNA Transcript Abundance during Plant Growth and the Influence of Li+ Exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duff, M. C.; Kuhne, W. W.; Halverson, N.; Chang, C. -S.; Kitamura, E.; Hawthorn, L.; Milliken, C. E.; Caldwell, E. F.; Stieve-Caldwell, E.; Martinez, N. E.; et al

    2014-12-01T23:59:59.000Z

    Lithium (Li) toxicity in plants is, at a minimum, a function of Li+ concentration, exposure time, species and growth conditions. Most plant studies with Li+ focus on short-term acute exposures. This study examines short- and long-term effects of Li+ exposure in Arabidopsis with Li+ uptake studies and measured shoot mRNA transcript abundance levels in treated and control plants. Stress, pathogen-response and arabinogalactan protein genes were typically more up-regulated in older (chronic, low level) Li+-treatment plants and in the much younger plants from acute high-level exposures. The gene regulation behavior of high-level Li+ resembled prior studies due to its influence on:more »inositol synthesis, 1-aminocyclopropane-1-carboxylate synthases and membrane ion transport. In contrast, chronically-exposed plants had gene regulation responses that were indicative of pathogen, cold, and heavy-metal stress, cell wall degradation, ethylene production, signal transduction, and calcium-release modulation. Acute Li+ exposure phenocopies magnesium-deficiency symptoms and is associated with elevated expression of stress response genes that could lead to consumption of metabolic and transcriptional energy reserves and the dedication of more resources to cell development. In contrast, chronic Li+ exposure increases expression signal transduction genes. The identification of new Li+-sensitive genes and a gene-based “response plan” for acute and chronic Li+ exposure are delineated.« less

  16. mRNA Transcript Abundance during Plant Growth and the Influence of Li+ Exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duff, M. C. [Savannah River National Laboratory, Aiken, SC (United States); Kuhne, W. W. [Savannah River National Laboratory, Aiken, SC (United States); Halverson, N. [Savannah River National Laboratory, Aiken, SC (United States); Chang, C. -S. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Kitamura, E. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Hawthorn, L. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Milliken, C. E. [Savannah River National Laboratory, Aiken, SC (United States); Caldwell, E. F. [Savannah River National Laboratory, Aiken, SC (United States); Stieve-Caldwell, E. [Savannah River National Laboratory, Aiken, SC (United States); Martinez, N. E. [Savannah River National Laboratory, Aiken, SC (United States); Colorado State University, Ft. Collins, CO (United States). Dept. of Environmental and Radiological Health Sciences; Stafford, C. [Savannah River National Laboratory, Aiken, SC (United States); Univ. of South Carolina Medical School, Columbia, SC (United States)

    2014-12-01T23:59:59.000Z

    Lithium (Li) toxicity in plants is, at a minimum, a function of Li+ concentration, exposure time, species and growth conditions. Most plant studies with Li+ focus on short-term acute exposures. This study examines short- and long-term effects of Li+ exposure in Arabidopsis with Li+ uptake studies and measured shoot mRNA transcript abundance levels in treated and control plants. Stress, pathogen-response and arabinogalactan protein genes were typically more up-regulated in older (chronic, low level) Li+-treatment plants and in the much younger plants from acute high-level exposures. The gene regulation behavior of high-level Li+ resembled prior studies due to its influence on: inositol synthesis, 1-aminocyclopropane-1-carboxylate synthases and membrane ion transport. In contrast, chronically-exposed plants had gene regulation responses that were indicative of pathogen, cold, and heavy-metal stress, cell wall degradation, ethylene production, signal transduction, and calcium-release modulation. Acute Li+ exposure phenocopies magnesium-deficiency symptoms and is associated with elevated expression of stress response genes that could lead to consumption of metabolic and transcriptional energy reserves and the dedication of more resources to cell development. In contrast, chronic Li+ exposure increases expression signal transduction genes. The identification of new Li+-sensitive genes and a gene-based “response plan” for acute and chronic Li+ exposure are delineated.

  17. Effect of LiAlO{sub 2} nanoparticle filler concentration on the electrical properties of PEO–LiClO{sub 4} composite

    SciTech Connect (OSTI)

    Masoud, E.M., E-mail: emad_masoud1981@yahoo.com [Chemistry Department, Faculty of Science, Benha University, Benha (Egypt); El-Bellihi, A.-A.; Bayoumy, W.A.; Mousa, M.A. [Chemistry Department, Faculty of Science, Benha University, Benha (Egypt)

    2013-03-15T23:59:59.000Z

    Highlights: ? Structural modification of nano LiAlO{sub 2} filler increased conductivity. ? Good ionic conductivity for (LiAlO{sub 2}){sub 1.5}(PEO){sub 11}(LiClO{sub 4}) at room temperature. ? Nano LiAlO{sub 2} filler enhanced both ion migration and orientation. ? High dielectric properties for (LiAlO{sub 2}){sub 1.5}(PEO){sub 11}(LiClO{sub 4}) at room temperature. - Abstract: Nano-composite polymer electrolytes are receiving attention as potential candidates to be used as electrolyte membranes in lithium polymer batteries and other devices. In this work, polyethylene oxide–LiClO{sub 4} based composite polymer electrolyte was prepared by solution casting method. The effect of LiAlO{sub 2} nanoparticle ceramic filler concentration on the structure and electrical conduction of the composite was studied. Nano-LiAlO{sub 2} was synthesized by sol–gel method. The samples were characterized using X-ray diffraction, Fourier Transmission-Infra Red, Differential Scanning Calorimetry, and tested by dielectric properties, Direct and Alternating current measurements as well as by impedance spectroscopy. All samples showed a behavior referring to an ionic conduction. Generally, the melting temperature of the polymer electrolyte decreased with filler concentration. Both thermal property and filler concentration influenced conductivity value. At room temperature, the highest ionic conductivity was 9.76 × 10{sup ?5} ohm{sup ?1} cm{sup ?1} for sample with a composition of (LiAlO{sub 2}){sub 1.5}(polyethylene oxide){sub 11}(LiClO{sub 4}). All results were correlated and discussed.

  18. Corrosion behavior of 8090 Al-Li alloy

    SciTech Connect (OSTI)

    Hu, Z.Q.; Zhang, Y.; Liu, Y.L. (Academia Sinica, Shenyang (China). Inst. of Metal Research); Zhu, Z.Y. (Academia Sinica, Shenyang (China). Inst. of Corrosion and Protection of Metals)

    1993-06-01T23:59:59.000Z

    An evaluation was conducted of the corrosion behavior of 8090 aluminum-lithium (Al-Li) alloy (UNS A98090), when aged under various conditions and subjected to corrosion in a solution of 3.5% NaCl + 1% H[sub 2]O[sub 2]. Susceptibility to pitting, intergranular corrosion, and exfoliation corrosion was shown to be influenced by heat treatment, which reduced from natural aging, through overaging to peak aging, Materials with peak aging showed low corrosion resistance. The decreased corrosion resistance corresponded to decreased corrosion potential of the alloy. Insoluble constituents were susceptible to corrosion. The corrosion extended along grain boundaries. Al-Li alloys showed mismatched tensile strength and stress corrosion resistance. The growth rate of stress corrosion cracks was large in the peak-aged state. The growth rate was strengthened by overaging, but tensile strength was reduced. That problem was solved by retrogression and reaging processing.

  19. Subbarrier fusion of {sup 9}Li with {sup 70}Zn

    SciTech Connect (OSTI)

    Loveland, W.; Vinodkumar, A. M.; Naik, R. S.; Sprunger, P. H.; Matteson, B.; Neeway, J. [Department of Chemistry, Oregon State University, Corvallis, Oregon 97331 (United States); Trinczek, M.; Dombsky, M.; Machule, P.; Ottewell, D. [TRIUMF, Vancouver, British Columbia, V6T 2A3 (Canada); Cross, D. [TRIUMF, Vancouver, British Columbia, V6T 2A3 (Canada); Department of Chemistry, Simon Fraser University, Burnaby, British Columbia, V5A 1S6 (Canada); Gagnon, K.; Mills, W. J. [TRIUMF, Vancouver, British Columbia, V6T 2A3 (Canada); Department of Physics, Simon Fraser University, Burnaby, British Columbia, V5A 1S6 (Canada)

    2006-12-15T23:59:59.000Z

    The cross section for the fusion of {sup 9}Li with {sup 70}Zn was measured for seven projectile energies spanning the subbarrier and near-barrier region (E{sub c.m.} ranging from 9.7 to 13.4 MeV) using the ISAC facility at TRIUMF. {gamma}-ray spectroscopy of the irradiated target foils along with {beta} counting of the chemically separated Ge and As evaporation residues were used to measure the fusion cross sections. Statistical model calculations were used to correct for the yields of any unobserved nuclei. The observed fusion excitation function shows significant subbarrier fusion enhancement with a large deduced value of the fusion radius, R{sub B}=12.1{+-}1.0 fm. Coupled-channels calculations do not account for the observed subbarrier enhancement. The implications of this finding for understanding the fusion of {sup 11}Li are discussed.

  20. Google:[Leonid Zakharov] http://w3.pppl.gov/~zakharov The LiWall Fusion (LiWF) Concept

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    Google:[Leonid Zakharov] http://w3.pppl.gov/~zakharov The LiWall Fusion (LiWF) Concept (part I Seminar, ASIPP July 07, 2008, Hefei, Ahnui, China 1 This work is supported by US DoE contract No. DE­AC020. Zakharov, ASIPP Seminar, July 07, 2008, ASIPP Hefei, Anhui Province, ChinaPRINCETON PLASMA PHYSICS

  1. Solvate Structures and Computational/Spectroscopic Characterization of LiBF4 Electrolytes

    SciTech Connect (OSTI)

    Seo, D. M.; Boyle, Paul D.; Allen, Joshua L.; Han, Sang D.; Jonsson , Erlendur; Johansson, Patrik; Henderson, Wesley A.

    2014-07-21T23:59:59.000Z

    Crystal structures have been determined for both LiBF4 and HBF4 solvates?(acetonitrile)2:LiBF4, (ethylene glycol diethyl ether)1:LiBF4, (diethylene glycol diethyl ether)1:LiBF4, (tetrahydrofuran)1:LiBF4, (methyl methoxyacetate)1:LiBF4, (suc-cinonitrile)1:LiBF4, (N,N,N',N",N"-pentamethyldiethylenetriamine)1:HBF4, (N,N,N',N'-tetramethylethylenediamine)3/2:HBF4 and (phenanthroline)2:HBF4. These, as well as other known LiBF4 solvate structures, have been characterized by Raman vibrational spectroscopy to unambiguously assign the anion Raman band positions to specific forms of BF4-...Li+ cation coordination. In addition, complementary DFT calculations of BF4-...Li+ cation complexes have provided additional insight into the challenges associated with accurately interpreting the anion interactions from experimental Raman spectra. This information provides a crucial tool for the characterization of the ionic association interactions within electrolytes.

  2. UConn Extension offers Bedding Plant Program for Greenhouse The University of Connecticut Cooperative Extension is offering Bedding Plants

    E-Print Network [OSTI]

    Alpay, S. Pamir

    UConn Extension offers Bedding Plant Program for Greenhouse Growers The University of Connecticut Cooperative Extension is offering Bedding Plants - Spring 2015! This educational program will feature, University of Connecticut, Storrs, CT · Diseases of Spring Crops and Their Management, Yonghao Li, Plant

  3. Thermal characterization of Li-ion cells using calorimetric techniques

    SciTech Connect (OSTI)

    ROTH,EMANUEL P.

    2000-05-31T23:59:59.000Z

    The thermal stability of Li-ion cells with intercalating carbon anodes and metal oxide cathodes was measured as a function of state of charge and temperature for two advanced cell chemistries. Cells of the 18650 design with Li{sub x}CoO{sub 2} cathodes (commercial Sony cells) and Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathodes were measured for thermal reactivity. Accelerating rate calorimetry (ARC) was used to measure cell thermal runaway as a function of state of charge (SOC), microcalorimetry was used to measure the time dependence of thermal output, and differential scanning calorimetry (DSC) was used to study the thermal reactivity of the individual components. Thermal decomposition of the anode solid electrolyte interphase (SEI) layer occurred at low temperatures and contributes to the initiation of thermal runaway. Low temperature reactions from 40 C--70 C were observed during the ARC runs that were SOC dependent. These reactions measured in the microcalorimeter decayed over time with power-law dependence and were highly sensitive to SOC and temperature. ARC runs of aged and cycled cells showed complete absence of these low-temperature reactions but showed abrupt exothermic spikes between 105--135 C. These results suggest that during aging the anode SEI layer is decomposing from a metastable state to a stable composition that is breaking down at elevated temperatures.

  4. Anomalous high ionic conductivity of nanoporous -Li3PS4

    SciTech Connect (OSTI)

    Liu, Zengcai [ORNL] [ORNL; Fu, Wujun [ORNL] [ORNL; Payzant, E Andrew [ORNL] [ORNL; Yu, Xiang [ORNL] [ORNL; Wu, Zili [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Kiggans, Jim [ORNL] [ORNL; Hong, Kunlun [ORNL] [ORNL; Rondinone, Adam Justin [ORNL; Liang, Chengdu [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    Lithium-ion conducting solid electrolytes hold the promise for enabling high-energy battery chemistries and circumventing safety issues of conventional lithium batteries1-3. Achieving the combination of high ionic conductivity and broad electrochemical window in solid electrolytes is a grand challenge for the synthesis of battery materials. Herein we show an enhancement of room-temperature lithium-ion conductivity of 3 orders of magnitude by creating nanostructured Li3PS4. This material has a wide (5V) electrochemical window and superior chemical stability against lithium metal. The nanoporous structure of Li3PS4 reconciles two vital effects that enhance ionic conductivity: (1) The reduced dimension to nanometer-sized framework stabilizes the high conduction beta phase that occurs at elevated temperatures1,4; and (2) The high surface-to-bulk ratio of nanoporous -Li3PS4 promotes surface conduction5,6. Manipulating the ionic conductivity of solid electrolytes has far-reaching implications for materials design and synthesis in a broad range of applications such as batteries, fuel-cells, sensors, photovoltaic systems, and so forth3,7.

  5. Revisit Carbon/Sulfur Composite for Li-S Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Wagner, Michael J.; Hays, Kevin; Li, Xiaohong S.; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-07-23T23:59:59.000Z

    To correlate the carbon properties e.g. surface area and porous structure, with the electrochemical behaviors of carbon/sulfur (C/S) composite cathodes for lithium-sulfur (Li-S) batteries, four different carbon frameworks including Ketjen Black (KB, high surface area and porous), Graphene (high surface area and nonporous), Acetylene Black (AB, low surface area and nonporous) and Hollow Carbon Nano Sphere (HCNS, low surface area and porous) are employed to immobilize sulfur (80 wt.%). It has been revealed that high surface area of carbon improves the utilization rate of active sulfur and decreases the real current density during the electrochemical reactions. Accordingly, increased reversible capacities and reduced polarization are observed for high surface area carbon hosts such as KB/S and graphene/S composites. The porous structure of KB or HCNS matrix promotes the long-term cycling stability of C/S composites but only at relatively low rate (0.2 C). Once the current density increases, the pore effect completely disappears and all Li-S batteries show similar trend of capacity degradation regardless of the different carbon hosts used in the cathodes. The reason has been assigned to the formation of reduced amount of irreversible Li2S on the cathode as well as shortened time for polysulfides to transport towards lithium anode at elevated current densities. This work provides valuable information for predictive selection on carbon materials to construct C/S composite for practical applications from the electrochemical point of view.

  6. High Capacity Pouch-Type Li-air Batteries

    SciTech Connect (OSTI)

    Wang, Deyu; Xiao, Jie; Xu, Wu; Zhang, Jiguang

    2010-05-05T23:59:59.000Z

    The pouch-type Li-air batteries operated in ambient condition are reported in this work. The battery used a heat sealable plastic membrane as package material, O2¬ diffusion membrane and moisture barrier. The large variation in internal resistance of the batteries is minimized by a modified separator which can bind the cell stack together. The cells using the modified separators show improved and repeatable discharge performances. It is also found that addition of about 20% of 1,2-dimethoxyethane (DME) in PC:EC (1:1) based electrolyte solvent improves can improve the wetability of carbon electrode and the discharge capacities of Li-air batteries, but further increase in DME amount lead to a decreased capacity due to increase electrolyte loss during discharge process. The pouch-type Li-air batteries with the modified separator and optimized electrolyte has demonstrated a specific capacity of 2711 mAh g-1 based on carbon and a specific energy of 344 Wh kg-1 based on the complete batteries including package.

  7. Vincennes University

    E-Print Network [OSTI]

    Julie Napier

    2015-04-22T23:59:59.000Z

    150 N. University Street. West Lafayette IN, 47907-2067 ... Highest degree from an accredited college/university ... ______ Library professional staff. ______ ...

  8. Crystal structure and chemical bonding of novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16}

    SciTech Connect (OSTI)

    Jung, Yaho; Nam, Gnu; Jeon, Jieun; Kim, Youngjo [Department of Chemistry, Chungbuk National University, Cheongju, 410 Seungbong-ro Heungduk-gu Chungbuk 361-763 (Korea, Republic of)] [Department of Chemistry, Chungbuk National University, Cheongju, 410 Seungbong-ro Heungduk-gu Chungbuk 361-763 (Korea, Republic of); You, Tae-Soo, E-mail: tsyou@chungbuk.ac.kr [Department of Chemistry, Chungbuk National University, Cheongju, 410 Seungbong-ro Heungduk-gu Chungbuk 361-763 (Korea, Republic of)] [Department of Chemistry, Chungbuk National University, Cheongju, 410 Seungbong-ro Heungduk-gu Chungbuk 361-763 (Korea, Republic of)

    2012-12-15T23:59:59.000Z

    A novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16} has been synthesized using the high-temperature reaction method and characterized by both powder and single-crystal X-ray diffractions. The title compound crystallized in the orthorhombic crystal system (space group Immm, Z=2, Pearson symbol oI78) with fifteen crystallographically unique atomic positions in the asymmetric unit, and the lattice parameters are refined as a=4.5244(4) A, b=6.9932(6) A, and c=53.043(5) A. The complex crystal structure of the title compound can be described as a 2:1 intergrowth of two closely related compounds: La{sub 2}Li{sub 2}Ge{sub 3} (Ce{sub 2}Li{sub 2}Ge{sub 3}-type) and La{sub 3}Li{sub 4}Ge{sub 4} (Zr{sub 3}Cu{sub 4}Si{sub 4}-type) acting like 'building-blocks' along the c-axis. Six La sites are categorized into three distinct types based on the local coordination environment showing the coordination numbers of 12-14. Three unique Li sites are placed in the centers of local tetrahedra formed by four Ge atoms which eventually construct Ge{sub 2} dimers or 1-dimensional cis-/trans-Ge chains. Theoretical investigations using the tight-binding linear muffin-tin orbital (LMTO) method provide rationales for an improved structural stability and for unique local coordination geometries established by anionic elements including [LiGe{sub 4}] tetrahedra, cis-/trans-Ge chain and Ge{sub 2} dimers. - Graphical abstract: Reported is a novel ternary Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16}. The complex crystal structure can be viewed as a simple combination of two closely related known compounds acting as 'building-blocks', La{sub 2}Li{sub 2}G{sub 3} and La{sub 3}Li{sub 4}Ge{sub 4}, in a 2:1 stoichiometric ratio. Highlights: Black-Right-Pointing-Pointer A novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16} was synthesized. Black-Right-Pointing-Pointer The complex crystal structure was easily explained as a combination of two known compounds. Black-Right-Pointing-Pointer Theoretical calculations indicated that the Fermi level was located near the pseudogap.

  9. Facile synthesis of nanostructured vanadium oxide as cathode materials for efficient Li-ion batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    -ion batteries Yanyi Liu,a Evan Uchaker,a Nan Zhou,ab Jiangang Li,ac Qifeng Zhanga and Guozhong Cao*a Received 23 and VO2 (B) nanorods were tested as active cathode materials for Li-ion batteries. The V2O5 sheet for efficient Li-ion batteries. Introduction The expansion and demands for energy use in the past several

  10. IV. -PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    IV. - PHOTOMAGNETISM AND CONDUCT I W r PHOTOMAGNETIC EFFECT IN A Li-Mn FERRITE P. BERNSTEIN and T'effet photomagnCtique dans le ferrite Fez,I oLi0.45Mn0.4504 au moyen de la variation de la perm investigated in a Fez.loLi0.45Mn0.4504ferrite by looking at the variations of the permeability under light

  11. Thermal Instability of Olivine-Type LiMnP04 Cathodes

    E-Print Network [OSTI]

    Chen, Guoying

    2010-01-01T23:59:59.000Z

    lithium-ion battery electrolyte is also evaluated, and its impact on the safety of high energy phosphate Li-ion batteries

  12. Chemical and Electrochemical Lithiation of LiVOPO4 Cathodes for Lithium-ion Batteries

    SciTech Connect (OSTI)

    Harrison, Katharine L [University of Texas at Austin; Bridges, Craig A [ORNL; Segre, C [Illinois Institute of Technology; VernadoJr, C Daniel [University of Texas at Austin; Applestone, Danielle [University of Texas at Austin; Bielawski, Christopher W [University of Texas at Austin; Paranthaman, Mariappan Parans [ORNL; Manthiram, Arumugam [University of Texas at Austin

    2014-01-01T23:59:59.000Z

    The theoretical capacity of LiVOPO4 could be increased from 159 to 318 mAh/g with the insertion of a second Li+ ion into the lattice to form Li2VOPO4, significantly enhancing the energy density of lithium-ion batteries. The changes accompanying the second Li+ insertion into -LiVOPO4 and -LiVOPO4 are presented here at various degrees of lithiation, employing both electrochemical and chemical lithiation. Inductively coupled plasma, X-ray absorption spectroscopy, and Fourier transform spectroscopy measurements indicate that a composition of Li2VOPO4 could be realized with an oxidation state of V3+ by the chemical lithiation process. The accompanying structural changes are evidenced by X-ray and neutron powder diffraction. Spectroscopic and diffraction data collected with the chemically lithiated samples as well as diffraction data on the electrochemically lithiated samples reveal that significant amount of lithium can be inserted into -LiVOPO4 before a more dramatic structural change occurs. In contrast, lithiation of -LiVOPO4 is more consistent with the formation of a two-phase mixture throughout most of the lithiation range. The phases observed with the ambient-temperature lithiation processes presented here are significantly different from those reported in the literature.

  13. Electrochemical performance of Sol-Gel synthesized LiFePO4 in lithium batteries

    E-Print Network [OSTI]

    Hu, Yaoqin; Doeff, Marca M.; Kostecki, Robert; Finones, Rita

    2003-01-01T23:59:59.000Z

    LiFePO 4 in Lithium Batteries Yaoqin Hu,* Marca M. Doeff,*material in lithium ion batteries based on environmental and

  14. Structural Analysis of Southern Dixie Valley using LiDAR and...

    Open Energy Info (EERE)

    Structural Analysis of Southern Dixie Valley using LiDAR and Low-Sun-Angle Aerial Photography, NAS Fallon Geothermal Exploration Project, Dixie Valley, Nevada Jump to: navigation,...

  15. Li+ alumino-silicate ion source development for the Neutralized Drift Compression Experiment (NDCX)

    E-Print Network [OSTI]

    Roy, Prabir K.

    2010-01-01T23:59:59.000Z

    Li + alumino-silicate ion source development for theresults on lithium alumino-silicate ion source developmentfor a lithium alumino-silicate source is determined by the

  16. Thermal Abuse Modeling of Li-Ion Cells and Propagation in Modules (Presentation)

    SciTech Connect (OSTI)

    Kim, G.-H.; Pesaran, A.; Smith, K.

    2008-05-01T23:59:59.000Z

    The objectives of this paper are: (1) continue to explore thermal abuse behaviors of Li-ion cells and modules that are affected by local conditions of heat and materials; (2) use the 3D Li-ion battery thermal abuse 'reaction' model developed for cells to explore the impact of the location of internal short, its heating rate, and thermal properties of the cell; (3) continue to understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-ion cells and modules; and (4) explore the use of the developed methodology to support the design of abuse-tolerant Li-ion battery systems.

  17. Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries

    E-Print Network [OSTI]

    Shim, J.; Guerfi, A.; Zaghib, K.; Striebel, K.A.

    2003-01-01T23:59:59.000Z

    Effect of Conductive Additives in LiFePO 4 Cathode forcapacity on conductive additive content and specificthe amount of conductive additive increases. The addition of

  18. Investigation of the Rechargeability of Li-O2 Batteries in Non-aqueous Electrolyte

    SciTech Connect (OSTI)

    Xiao, Jie; Hu, Jian Z.; Wang, Deyu; Hu, Dehong; Xu, Wu; Graff, Gordon L.; Nie, Zimin; Liu, Jun; Zhang, Jiguang

    2011-07-01T23:59:59.000Z

    In order to understand the nature of the limited cycle life and poor energy efficiency associated with the secondary Li-O¬2 batteries the discharge products of primary Li-O2 cells at different depth of discharge (DOD) are systematically analyzed in this work. It is revealed that if discharged to 2.0 V a small amount of Li2O2 coexist with Li2CO3 and RO-(C=O)-OLi) in alkyl carbonate-based electrolyte. Further discharging the air electrodes to below 2.0 V the amount of Li2CO3 and LiRCO3 increases significantly due to the severe electrolyte decomposition. There is no Li2O detected in this alkyl carbonate electrolyte regardless of DOD. It is also found that the alkyl carbonate based electrolyte begins to decompose at 4.0 V during charging under the combined influences from the high surface area carbon, the nickel metal current collector and the oxygen atmosphere. Accordingly the impedance of the Li-O2 cell continues to increase after each discharge and recharge process indicating a repeated plating of insoluble lithium salts on the carbon surface. Therefore the whole carbon electrode becomes completely insulated only after a few cycles and loses the function of providing active tri-phase regions for the Li-oxygen batteries.

  19. Analysis of Heat Dissipation in Li-Ion Cells & Modules for Modeling of Thermal Runaway (Presentation)

    SciTech Connect (OSTI)

    Kim, G.-H.; Pesaran, A.

    2007-05-15T23:59:59.000Z

    The objectives of this study are: (1) To develop 3D Li-Ion battery thermal abuse ''reaction'' models for cell and module analysis; (2) To understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-Ion cells and modules; (3) To develop a tool and methodology to support the design of abuse-tolerant Li-Ion battery systems for PHEVs/HEVs; and (4) To help battery developers accelerate delivery of abuse-tolerant Li-Ion battery systems in support of the FreedomCAR's Energy Storage Program.

  20. On 7Li Enrichment by Low Mass Metal Poor Red Giant Branch Stars

    E-Print Network [OSTI]

    Ramiro de la Reza; Licio da Silva; Natalia A. Drake; Marco A. Terra

    2000-04-25T23:59:59.000Z

    First-ascent red giants with strong and very strong Li lines have just been discovered in globular clusters. Using the stellar internal prompt 7Li enrichment - mass loss scenario, we explore the possibility of 7Li enrichment in the interstellar matter of the globular cluster M3 produced by these Li-rich giants. We found that enrichment as large as 70% or more compared to the initial 7Li content of M3 can be obtained during the entire life of this cluster. However, due to the several crossings of M3 into the Galactic plane, the new 7Li will be very probably removed by ram pressure into the disk. Globular clusters appear then as possible new sources of 7Li in the galactic disk. It is also suggested that the known Na/Al variations in stars of globular clusters could be somehow related to the 7Li variations and that the cool bottom mixing mechanism acting in the case of 7Li could also play a role in the case of Na and Al surface enrichments.

  1. High-energy break-up of 6Li as a tool to study the Big-Bang nucleosynthesis reaction 2H(alpha,gamma)6Li

    E-Print Network [OSTI]

    F. Hammache; M. Heil; S. Typel; D. Galaviz; K. Sümmerer; A. Coc; F. Uhlig; F. Attallah; M. Caamano; D. Cortina; H. Geissel; M. Hellström; N. Iwasa; J. Kiener; P. Koczon; B. Kohlmeyer; P. Mohr; E. Schwab; K. Schwarz; F. Schümann; P. Senger; O. Sorlin; V. Tatischeff; J. P. Thibaud; E. Vangioni; A. Wagner; W. Walus

    2010-11-29T23:59:59.000Z

    The recently claimed observations of non-negligible amounts of 6Li in old halo stars have renewed interest in the Big-Bang Nucleosynthesis (BBN) of 6Li. One important ingredient in the predicted BBN abundance of 6Li is the low-energy 2H(alpha,gamma)6Li cross section. Up to now, the only available experimental result for this cross section showed an almost constant astrophysical S-factor below 400 keV, contrary to theoretical expectations. We report on a new measurement of the 2H(alpha,gamma)6Li reaction using the break-up of 6Li at 150 A MeV. Even though we cannot separate experimentally the Coulomb contribution from the nuclear one, we find clear evidence for Coulomb-nuclear interference by analyzing the scattering-angular distributions. This is in-line with our theoretical description which indicates a drop of the S_24-factor at low energies as predicted also by most other models. Consequently, we find even lower upper limits for the calculated primordial 6Li abundance than before.

  2. Investigation on the Charging Process of Li2O2-Based Air Electrodes in Li-O2 Batteries with Organic Carbonate Electrolytes

    SciTech Connect (OSTI)

    Xu, Wu; Viswanathan, Vilayanur V.; Wang, Deyu; Towne, Silas A.; Xiao, Jie; Nie, Zimin; Hu, Dehong; Zhang, Jiguang

    2011-04-15T23:59:59.000Z

    The charge processes of Li-O2 batteries were investigated by analyzing the gas evolution by in situ gas chromatography-mass spectroscopy (GC/MS) technique. The mixture of Li2O2/Fe3O4/Super P carbon/polyvinylidene fluoride (PVDF) was used as the starting air electrode material and 1M LiTFSI in carbonate-based solvents was used as electrolyte. It was found that Li2O2 is reactive to 1-methyl-2-pyrrolidinone and PVDF binder used in the electrode preparation. During the 1st charge (up to 4.6 V), O2 was the main component in the gases released. The amount of O2 measured by GC/MS was consistent with the amount of Li2O2 decomposed in the electrochemical process as measured by the charge capacity, indicative of the good chargeability of Li2O2. However, after the cell was discharged to 2.0 V in O2 atmosphere and re-charged to ~ 4.6 V in the second cycle, CO2 was dominant in the released gases. Further analysis of the discharged air electrode by X-ray diffraction and Fourier transform infrared spectroscopy indicated that lithium-containing carbonate species (lithium alkyl carbonate and/or Li2CO3) were the main reaction products. Therefore, compatible electrolyte and electrodes as well as the electrode preparation procedures need to be developed for long term operation of rechargeable Li-O2 or Li-air batteries.

  3. Determination of the spherically symmetric potential components for Li sup + --N sub 2 and Li sup + --CO from total cross section measurements (USA)

    SciTech Connect (OSTI)

    Gislason, E.A.; Polak-Dingels, P.; Rajan, M.S. (Department of Chemistry, University of Illinois at Chicago, Box 4348, Chicago, IL (USA))

    1990-08-15T23:59:59.000Z

    Total cross sections have been measured for Li{sup +} ions scattered by N{sub 2} and CO in the range {ital E}{Theta}{sub {ital R}}=5--1000 eV deg. Here {ital E} is the lab energy of the Li{sup +} beam, and {Theta}{sub {ital R}} is the resolution angle of the apparatus. From the data the spherically symmetric parts of the intermolecular potentials have been determined over a wide range of Li{sup +}-molecule distances including the attractive well region. The results are compared with other theoretical and experimental work on these systems.

  4. Silicon Based Anodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Wang, Wei; Xiao, Jie; Xu, Wu; Graff, Gordon L.; Yang, Zhenguo; Choi, Daiwon; Li, Xiaolin; Wang, Deyu; Liu, Jun

    2012-06-15T23:59:59.000Z

    Silicon is environmentally benign and ubiquitous. Because of its high specific capacity, it is considered one of the most promising candidates to replace the conventional graphite negative electrode used in today's Li ion batteries. Silicon has a theoretical specific capacity of nearly 4200 mAh/g (Li21Si5), which is 10 times larger than the specific capacity of graphite (LiC6, 372 mAh/g). However, the high capacity of silicon is associated with huge volume changes (more than 300 percent) when alloyed with lithium, which can cause severe cracking and pulverization of the electrode and lead to significant capacity loss. Significant scientific research has been conducted to circumvent the deterioration of silicon based anode materials during cycling. Various strategies, such as reduction of particle size, generation of active/inactive composites, fabrication of silicon based thin films, use of alternative binders, and the synthesis of 1-D silicon nanostructures have been implemented by a number of research groups. Fundamental mechanistic research has also been performed to better understand the electrochemical lithiation and delithiation process during cycling in terms of crystal structure, phase transitions, morphological changes, and reaction kinetics. Although efforts to date have not attained a commercially viable Si anode, further development is expected to produce anodes with three to five times the capacity of graphite. In this chapter, an overview of research on silicon based anodes used for lithium-ion battery applications will be presented. The overview covers electrochemical alloying of the silicon with lithium, mechanisms responsible for capacity fade, and methodologies adapted to overcome capacity degradation observed during cycling. The recent development of silicon nanowires and nanoparticles with significantly improved electrochemical performance will also be discussed relative to the mechanistic understanding. Finally, future directions on the development of silicon based anodes will be considered.

  5. Phase transitions in the adsorption system Li/Mo(112)

    E-Print Network [OSTI]

    Fedorus, A.; Kolthoff, D.; Koval, V.; Lyuksyutov, Igor F.; Naumovets, AG; Pfnur, H.

    2000-01-01T23:59:59.000Z

    limit can be quasi-one-dimensional. Such model systems are formed upon submonolayer adsorption on surfaces with strongly an- PRB 620163-1829/2000/62~4!/2852~10!/$15.00 n system Li?Mo?112? ,1,3 A. G. Naumovets,1 and H. Pfnu?r2,* , Prospect Nauki 46... W/Re thermocouple and was con- trolled by a computerized feedback circuit with a resolution of 0.01 K. The source of lithium was constructed and outgassed as PRB 62 PHASE TRANSITIONS IN TH described in Ref. 6. The LEED patterns have been taken...

  6. LiWall Fusion - The New Concept of Magnetic Fusion

    SciTech Connect (OSTI)

    L.E. Zakharov

    2011-01-12T23:59:59.000Z

    Utilization of the outstanding abilities of a liquid lithium layer in pumping hydrogen isotopes leads to a new approach to magnetic fusion, called the LiWall Fusion. It relies on innovative plasma regimes with low edge density and high temperature. The approach combines fueling the plasma by neutral injection beams with the best possible elimination of outside neutral gas sources, which cools down the plasma edge. Prevention of cooling the plasma edge suppresses the dominant, temperature gradient related turbulence in the core. Such an approach is much more suitable for controlled fusion than the present practice, relying on high heating power for compensating essentially unlimited turbulent energy losses.

  7. LiDAR (Laney, 2005) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer Plant Jump to:Landowners and Wind EnergyIndiana:NewJump to: navigation,Oklahoma:LeyteLiDAR

  8. LiDAR (Lewicki & Oldenburg, 2005) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer Plant Jump to:Landowners and Wind EnergyIndiana:NewJump to:Oldenburg, 2004) Jump to:LiDAR

  9. Li County Jiujiayi Hydropower Development Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup |Jilin Zhongdiantou NewKoreaLaorLeopold Kostal GmbHLi County JiaxingLi

  10. Wei-li W Lee | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsing Maps1DOETHEWeekly Reports 2014 Weekly ReportWei-li W

  11. Yuncong Li 1 Professor and Sate Extension Specialist

    E-Print Network [OSTI]

    Jawitz, James W.

    Award (University of Florida); Junior Faculty Research Award (Sigma Xi, the international honor society Distinguished Extension Award (Extension Association of Florida); International Educator of the Year (University editor for two journals, Critical Reviews in Environmental Science and Technology and Communications

  12. Investigation of Mechanical Activation on Li-N-H Systems Using 6Li Magic Angle Spinning Nuclear Magnetic Resonance at Ultra-High Field

    SciTech Connect (OSTI)

    Hu, Jian Zhi; Kwak, Ja Hun; Yang, Zhenguo; Osborn, William; Markmaitree, Tippawan; Shaw, Leonard D.

    2008-07-15T23:59:59.000Z

    Abstract The significantly enhanced spectral resolution in the 6Li MAS NMR spectra of Li-N-H systems at ultra-high field of 21.1 tesla is exploited, for the first time, to study the detailed electronic and chemical environmental changes associated with mechanical activation of Li-N-H system using high energy balling milling. Complementary to ultra-high field studies, the hydrogen discharge dynamics are investigated using variable temperature in situ 1H MAS NMR at 7.05 tesla field. The significantly enhanced spectral resolution using ultra-high filed of 21.1 tesla was demonstrated along with several major findings related to mechanical activation, including the upfield shift of the resonances in 6Li MAS spectra induced by ball milling, more efficient mechanical activation with ball milling at liquid nitrogen temperature than with ball milling at room temperature, and greatly enhanced hydrogen discharge exhibited by the liquid nitrogen ball milled samples.

  13. Lattice Mn3+ Behaviors in Li4Ti5O12/LiNi0.5Mn1.5O4 Full Cells

    SciTech Connect (OSTI)

    Zheng, Jianming; Xiao, Jie; Nie, Zimin; Zhang, Jiguang

    2013-05-28T23:59:59.000Z

    High voltage spinels LiNi0.5Mn1.5O4 (LNMO) with different contents of residual Mn3+ ions have been evaluated in full cells using Li4Ti5O12 (LTO) as standard anode. Greatly improved cycling stability has been observed for all spinels in LTO-limited full cell, compared with those in LNMO-limited ones, while the underlying mechanisms are quite different. It has been discovered that the participation of active Mn3+ in the extended cycling and thus its observable contribution to Li+ diffusion kinetics depend on the limiting electrode and the sufficiency of Li+ ions. Potential Mn dissolution has also been discussed to identify the key factors that need to be considered to construct full cells employing high voltage spinel as the cathode.

  14. Modeling the evolution of anisotropy in AlLi alloys: application to AlLi 2090-T8E41

    E-Print Network [OSTI]

    Garmestani, Hamid

    University, Philadelphia, PA 19104, USA c Code 4342, M55, Bldg 2188, Naval Air Systems Command, Patuxent River, MD 20670, USA d Department of Mechanical Engineering, Loyola Marymount University, Los Angeles

  15. Development of First Principles Capacity Fade Model for Li-Ion Cells

    E-Print Network [OSTI]

    Popov, Branko N.

    into a lithium-ion battery model. The model explains the self-discharge process occurring in Li-ion cells processes in lithium-ion batteries may cause a number of undesirable effects leading to capacity loss.3 with the existing Li- ion intercalation model. Model Development The side reaction of general interest in lithium-ion

  16. LiFTinG: Lightweight Freerider-Tracking in Gossip Rachid Guerraoui

    E-Print Network [OSTI]

    Guerraoui, Rachid

    by simulations and PlanetLab experiments. In a 300-node system, where a stream of 674 kbps is broadcast, LiFTinGLiFTinG: Lightweight Freerider-Tracking in Gossip Rachid Guerraoui EPFL rachid.guerraoui@epfl.ch K IIT Guwahati swagatika@iitg.ernet.in Abstract This paper presents LiFTinG, the first protocol

  17. Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses

    E-Print Network [OSTI]

    Osterloh, Frank

    -iodopropionic acid treated LiMo3Se3 nanowire bundles with oleic acid-stabilized Fe3O4 nanoparticles of 2.8, 5Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses Frank E. Osterloh,*, Hiroki A scaleable chemical approach to functional nanoscale analogues of the magnetic compasses in magnetotactic

  18. LI ET AL. VOL. XXX ' NO. XX ' 000000 ' XXXX www.acsnano.org

    E-Print Network [OSTI]

    Zare, Richard N.

    LI ET AL. VOL. XXX ' NO. XX ' 000­000 ' XXXX www.acsnano.org A C XXXX American Chemical Society. PERSPECTIVE #12;LI ET AL. VOL. XXX ' NO. XX ' 000­000 ' XXXX www.acsnano.org B transmembrane potential

  19. Study on generating of thermal neutron scattering cross sections for LiH

    SciTech Connect (OSTI)

    Wang, L.; Jiang, X.; Zhao, Z.; Chen, L. [Northwest Institute of Nuclear Technology, Xi'an 710024 (China)

    2013-07-01T23:59:59.000Z

    LiH is designated as a promising moderator and shielding material because of its low density, high melting point and large fraction of H atoms. However, lack of the thermal neutron cross sections of LiH makes numerical calculation deviate from experimental data to some extent. As a result, it is necessary to study LiH thermal kernel effect. The phonon property of LiH has been investigated by first-principles calculations using the plane-wave pseudo potential method with CASTEP code. The scattering law and the thermal neutron scattering cross sections for Li and H have been generated using this distribution. The results have been compared with zirconium hydride data. The GASKET and NJOY/LEAPR codes have been used in the calculation of scattering law, whose results have been compared with the reference; the discrepancy mainly comes from phonon spectrums and its expansion. LEAPR had the capability to compute scattering through larger energy and momentum transfers than GASKET did. By studying LiH phonon spectrum and constructing the model of LiH thermal kernel and scattering matrix, the ACE format LiH thermal neutron cross sections for MCNP software could be made and used for reactor Neutronics calculation. (authors)

  20. Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries

    E-Print Network [OSTI]

    Schmidt, Volker

    Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries Ralf August 30, 2010 Abstract Battery technology plays an important role in energy storage. In particular, lithium­ ion (Li-ion) batteries are of great interest, because of their high capacity, long cycle life

  1. Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries

    E-Print Network [OSTI]

    Rubloff, Gary W.

    Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries Dmitry Ruzmetov, all-solid-state Li ion batteries (LIBs) with high specific capacity and small footprint are highly, into the nanometer regime, can lead to rapid self-discharge of the battery even when the electrolyte layer

  2. LI, SONG, GONG: SKETCH RECOGNITION BY ENSEMBLE MATCHING 1 Sketch Recognition by Ensemble Matching

    E-Print Network [OSTI]

    Gong, Shaogang

    LI, SONG, GONG: SKETCH RECOGNITION BY ENSEMBLE MATCHING 1 Sketch Recognition by Ensemble Matching://www.eecs.qmul.ac.uk/~yzs Shaogang Gong http://www.eecs.qmul.ac.uk/~sgg School of Electronic Engineering and Computer Science, Queen with its authors. It may be distributed unchanged freely in print or electronic forms. #12;2 LI, SONG, GONG

  3. Geospatial revolution and remote sensing LiDAR in Mesoamerican archaeology

    E-Print Network [OSTI]

    Weishampel, John F.

    #12;Geospatial revolution and remote sensing LiDAR in Mesoamerican archaeology Arlen F. Chasea,1. The impor- tance of this geospatial innovation is demonstrated with newly acquired LiDAR data from in the remote geospatial imaging of cultural landscapes, including ancient communities and their anthropogenic

  4. MHD Analysis of Dual Coolant Pb-17Li Blanket for ARIES-CS C. Mistrangelo1

    E-Print Network [OSTI]

    Raffray, A. René

    MHD Analysis of Dual Coolant Pb-17Li Blanket for ARIES-CS C. Mistrangelo1 , A. R. Raffray2 of California, San Diego, La Jolla, CA 92093-0438, USA, rraffray@ucsd.edu A dual coolant Pb-17Li (DCLL) blanket of magnetohydrodynamic (MHD) flows in the poloidal channels that distribute the liquid metal in the breeder units has

  5. Improved Capacity Retention for LiVO[subscript 2] by Cr Substitution

    E-Print Network [OSTI]

    Ma, Xiaohua

    We present a layered Li-intercalation oxide that operates on the V[superscript 3+]/V[superscript 4+] redox couple. The stabilization effect of adding a +3 element into the layered LiVO[subscript 2] has been studied by first ...

  6. Doped LiFePO? cathodes for high power density lithium ion batteries

    E-Print Network [OSTI]

    Bloking, Jason T. (Jason Thompson), 1979-

    2003-01-01T23:59:59.000Z

    Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

  7. SPECIAL ISSUE: Quantitative Models for Energy Systems SPECIAL EDITORS: Chung-Li Tseng

    E-Print Network [OSTI]

    Tseng, Chung-Li

    to mitigate transmission congestion, which can subsequently change locational marginal prices of the network la Torre and Antonio J. Conejo 52 Impact of Phase Shifters on Locational Prices Bo Lu, Zuyi Li Shifters on Locational Prices" by Bo Lu, Zuyi Li, and Mohammand Shahidehpour, proposes using phase shifters

  8. Observation of laser-induced associative ionization in crossed-beam Na+Li collisions

    SciTech Connect (OSTI)

    Polak-Dingels, P.; Keller, J.; Weiner, J.; Gauthier, J.h.; Bras, N.

    1981-08-01T23:59:59.000Z

    We report the observation of NaLi/sup +/ produced by crossed-beam collisions of Na and Li in the presence of a single laser field. The magnitude of the cross section and its dependence on laser intensity are in accord with a simple second-order perturbation theory.

  9. A new family of locally 5arc transitive Michael Giudici a, Cai Heng Li a

    E-Print Network [OSTI]

    Giudici, Michael

    A new family of locally 5­arc transitive graphs Michael Giudici a, Cai Heng Li a Cheryl E. Praeger@maths.uwa.edu.au (Cai Heng Li), praeger@maths.uwa.edu.au (Cheryl E. Praeger). Preprint submitted to Elsevier Science 17

  10. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries. Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For...

  11. Temperature dependence of d7 Ca and Li/Ca during growth

    E-Print Network [OSTI]

    Temperature dependence of d7 Li, d44 Ca and Li/Ca during growth of calcium carbonate Caedmon S; calcium isotopes; calcium carbonate 1. Introduction The trace element and isotope chemistry of calci- um variable, in controlling the fraction- ation of three such potential proxies in calcium carbonates

  12. A Model Reduction Framework for Efficient Simulation of Li-Ion Batteries

    E-Print Network [OSTI]

    of degradation processes in lithium-ion batteries, the modelling of cell dynamics at the mircometer scale lithium-ion batteries is the deposition of metallic lithium at the negative battery electrode (LiA Model Reduction Framework for Efficient Simulation of Li-Ion Batteries Mario Ohlberger Stephan

  13. Complete Residential Urban Area Reconstruction from Dense Aerial LiDAR Point Clouds

    E-Print Network [OSTI]

    Shahabi, Cyrus

    Complete Residential Urban Area Reconstruction from Dense Aerial LiDAR Point Clouds Qian-Yi Zhou area modeling and residential area modeling is that the latter usually con- tains rich vegetation. Thus representing the 3D urban reality of residential areas. Keywords: urban modeling, LiDAR, residential area

  14. Modeling Residential Urban Areas from Dense Aerial LiDAR Point Clouds

    E-Print Network [OSTI]

    Shahabi, Cyrus

    Modeling Residential Urban Areas from Dense Aerial LiDAR Point Clouds Qian-Yi Zhou and Ulrich models for residential areas from aerial LiDAR scans. The key differ- ence between downtown area modeling and residential area modeling is that the latter usually contains rich vegetation. Thus, we propose a robust

  15. Dynamic Query Forms for Database Queries Liang Tang, Tao Li, Yexi Jiang, and Zhiyuan Chen

    E-Print Network [OSTI]

    Li, Tao

    queries on databases. However, the creation of customized queries totally depends on users' manual editing. Different from traditional document retrieval, users in database · Liang Tang, Tao Li, and Yexi Jiang1 Dynamic Query Forms for Database Queries Liang Tang, Tao Li, Yexi Jiang, and Zhiyuan Chen

  16. Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries

    E-Print Network [OSTI]

    , Li-ion batteries suffer from strong self-heating, which limits their life-time and creates* Nano-Device Laboratory, Department of Electrical Engineering and Materials Science and Engineering, automotive and aerospace industries. Li-ion batteries are an essential part of the hybrid electric vehicles

  17. New Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy

    E-Print Network [OSTI]

    Cui, Yi

    -ion batteries based on LiCoO2 cathodes and graphite anodes (410 Wh kg-1 ). The nanostructured design of bothNew Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy Yuan Yang,,§ Matthew, California 94305 ABSTRACT Rechargeable lithium ion batteries are important energy storage devices; however

  18. Thermal Model for a Li-Ion Cell Karthikeyan Kumaresan,* Godfrey Sikha,** and Ralph E. White***,z

    E-Print Network [OSTI]

    cathode in 1 M LiPF6 salt, in a mixture of ethylene carbonate, propylene carbonate, ethyl-methyl carbonate. Recent experimental characterization8 of transport properties of LiPF6 in a solvent mixture of propylene

  19. Nano-Structured Li3V2(PO4)3 /Carbon Composite for High Rate Lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nano-Structured Li3V2(PO4)3 Carbon Composite for High Rate Lithium Ion Batteries. Nano-Structured Li3V2(PO4)3 Carbon Composite for High Rate Lithium Ion Batteries. Abstract:...

  20. Interpolating Vancouver's Daily Ambient PM10 Field Li Sun James V. Zidek Nhu D. Le Haluk Ozkaynak

    E-Print Network [OSTI]

    Washington at Seattle, University of

    Interpolating Vancouver's Daily Ambient PM10 Field Li Sun James V. Zidek Nhu D. Le Haluk Ozkaynak the Center's primary funding. #12;Interpolating Vancouver's Daily Ambient PM10 Field Li Sun1 , James V Zidek1

  1. Journal of Power Sources 159 (2006) 14221427 Li diffusion in LiCoO2 thin films prepared by pulsed laser deposition

    E-Print Network [OSTI]

    Ceder, Gerbrand

    2006-01-01T23:59:59.000Z

    to be in the range of 10-11 to 10-13 cm2 s-1 depending on Li concentration and on the characterization method used. © 2006 Elsevier B.V. All rights reserved. Keywords: Thin-film battery; LiCoO2; Lithium diffusion; Pulsed-ion batteries. Without the presence of a polymer binder and carbonaceous powders, the dense and flat thin films

  2. Sub- and above barrier fusion of loosely bound $^6$Li with $^{28}$Si

    E-Print Network [OSTI]

    Mandira Sinha; H. Majumdar; P. Basu; Subinit Roy; R. Bhattacharya; M. Biswas; M. K. Pradhan; R. Palit; I. Mazumdar; S. Kailas

    2010-05-07T23:59:59.000Z

    Fusion excitation functions are measured for the system $^6$Li+$^{28}$Si using the characteristic $\\gamma$-ray method, encompassing both the sub-barrier and above barrier regions, viz., $E_{lab}$= 7-24 MeV. Two separate experiments were performed, one for the above barrier region ($E_{lab}$= 11-24 MeV) and another for the below barrier region ($E_{lab}$= 7-10 MeV). The results were compared with our previously measured fusion cross section for the $^7$Li+$^{28}$Si system. We observed enhancement of fusion cross section at sub-barrier regions for both $^6$Li and $^7$Li, but yield was substantially larger for $^6$Li. However, for well above barrier regions, similar type of suppression was identified for both the systems.

  3. LiU E-Press Linkoping University Electronic Press 2006-01

    E-Print Network [OSTI]

    Zhao, Yuxiao

    for the E-Press. Increasing the publication of PhD and licentiate theses has been our first priority on the committee report, specifies two major priorities: to increase the publication of doctorate and licentiate(1 reasons 1 The licentiate degree is a Swedish research degree that is in-between the mas- ter

  4. Li (Lily) Wang Address: 223 Statistics Building, University of Georgia, Athens, GA 30602-7952

    E-Print Network [OSTI]

    Wang, Lily

    ). A nonparametric analysis on the environmental Kuznets curve. Environmetrics, 22(3), 420­430. [9] Liu, X., Wang, L

  5. Electrochemical behavior of LiCoO2 as aqueous lithium-ion battery electrodes Riccardo Ruffo a

    E-Print Network [OSTI]

    Cui, Yi

    Electrochemical behavior of LiCoO2 as aqueous lithium-ion battery electrodes Riccardo Ruffo 2008 Available online xxxx Keywords: LiCoO2 Aqueous electrolyte LiNO3 Lithium-ion battery Cathode substrate using the procedures typical for the study of electrodes for lithium-ion batteries in organic

  6. Fusion Engineering and Design 81 (2006) 461467 An overview of dual coolant Pb17Li breeder first wall and blanket

    E-Print Network [OSTI]

    Abdou, Mohamed

    2006-01-01T23:59:59.000Z

    . Helium is used to cool the first wall and blanket structure, and the self-cooled breeder Pb­17Li.V. All rights reserved. Keywords: Blanket; Pb­17Li breeder; Dual-coolant; Helium-cooled; ITER coolant Pb­17Li liquid breeder (DCLL) blanket design, a con- cept that has been explored extensively

  7. Thermal stability of LiPF6EC:EMC electrolyte for lithium ion batteries Gerardine G. Bottea

    E-Print Network [OSTI]

    Thermal stability of LiPF6±EC:EMC electrolyte for lithium ion batteries Gerardine G. Bottea , Ralph study of the LiPF6±EC:EMC electrolyte. The effect of different variables on its thermal stability was evaluated: salt (LiPF6) concentration effect, solvents, EC:EMC ratios, and heating rates. Hermetically

  8. Linkping University Electronic Press

    E-Print Network [OSTI]

    Zhao, Yuxiao

    .D. (and Licentiate) examination process. The details vary a little from faculty to faculty, but in general in the electronic publication of at least 95% of LiU Ph.D. and Licentiate theses. Furthermore, 40 Licentiate theses undergraduate reports, 293 Ph.D. theses and 122 Licentiate theses. Beyond theses, LiU E-Press also publishes

  9. Charles Darwin University Flinders University Griffith University James Cook University La Trobe University Murdoch University The University of Newcastle Biography for GLOVER, Professor Barney

    E-Print Network [OSTI]

    University Murdoch University The University of Newcastle Biography for GLOVER, Professor Barney Vice Chancellor, Charles Darwin University Professor Barney Glover is Vice-Chancellor of Charles Darwin University

  10. University Profile University of Canterbury

    E-Print Network [OSTI]

    Hickman, Mark

    University Profile 2007­2009 #12;University of Canterbury PROFILE 2007 - 2009 Submitted to the Tertiary Education Commission, 31 October, 2006 #12;University of Canterbury Profile 2007-2009 Page 2 of 64 #12;Contents Page Profile Purpose and Structure 4 Part A: Strategic Direction 5 Part B: Key Strategic

  11. Elastic Hadron Scattering on Li Isotopes at Intermediate Energies

    SciTech Connect (OSTI)

    Zhusupov, M.A.; Imambekov, O. [Institute of Experimental and Theoretical Physics, Kazakh State University, ul. Timiryazeva 46, Almaty, 480121 (Kazakhstan); Ibraeva, E.T. [Institute of Nuclear Physics, National Nuclear Center of the Republic of Kazakhstan, Almaty, 480082 (Kazakhstan)

    2005-01-01T23:59:59.000Z

    The elastic scattering of hadrons (protons, charged pions, and positively charged kaons) on {sup 6,7,8}Li nuclei is analyzed on the basis of Glauber-Sitenko diffraction theory. A few nuclear-wave-function versions found within two- and three-particle potential cluster models are used in the calculations. It is shown that the application of these wave functions in diffraction theory makes it possible to describe adequately the experimental differential cross sections and analyzing powers in hadron scattering at intermediate energies. In this study, particular attention is given to a comparison of the scattering of different particles on the same target nucleus, as well as to a comparison of scattering of particles of the same sort on different target nuclei.

  12. Multicell Li/SOCl/sub 2/ reserve battery

    SciTech Connect (OSTI)

    Baldwin, A.R.; Garoutte, K.F.

    1984-01-01T23:59:59.000Z

    Recent development work on reserve lithium thionyl chloride (RLTC) batteries at SNLA and Honeywell has included safety and performance evaluations. The RLTC battery is being considered for applications that have traditionally been fulfilled by state-of-the-art thermal batteries and reserve silver oxide zinc electrochemical systems. These applications typically demand a reserve battery having a rapid voltage rise, high reliability, operational safety and useful active lifetime ranging from minutes to hours. The RLTC work reported here was directed toward a power battery capable of meeting or exceeding the design requirements. Performance and safety test data indicate that the RLTC battery may be better suited than thermal batteries for some long-life applications. Table II presents a comparison between a Li(Si)/FeS/sub 2/ thermal battery and an RLTC battery, both of which were designed to fulfill the requirements.

  13. Stability of the solid electrolyte Li{sub 3}OBr to common battery solvents

    SciTech Connect (OSTI)

    Schroeder, D.J. [Department of Engineering Technology, College of Engineering and Engineering Technology, Northern Illinois University, 301B Still Gym, DeKalb, IL 60115 (United States); Hubaud, A.A. [Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439-4837 (United States); Vaughey, J.T., E-mail: vaughey@anl.gov [Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439-4837 (United States)

    2014-01-01T23:59:59.000Z

    Graphical abstract: The stability of the anti-perovskite phase Li{sub 3}OBr has been assessed in a variety of battery solvents. - Highlights: • Lithium stable solid electrolyte Li{sub 3}OBr unstable to polar organic solvents. • Solvation with no dissolution destroys long-range structure. • Ion exchange with protons observed. - Abstract: Recently a new class of solid lithium ion conductors was reported based on the anti-perovskite structure, notably Li{sub 3}OCl and Li{sub 3}OBr. For many beyond lithium-ion battery uses, the solid electrolyte is envisioned to be in direct contact with liquid electrolytes and lithium metal. In this study we evaluated the stability of the Li{sub 3}OBr phase against common battery solvents electrolytes, including diethylcarbonate (DEC) and dimethylcarbonate (DMC), as well as a LiPF{sub 6} containing commercial electrolyte. In contact with battery-grade organic solvents, Li{sub 3}OBr was typically found to be insoluble but lost its crystallinity and reacted with available protons and in some cases with the solvent. A low temperature heat treatment was able to restore crystallinity of the samples; however evidence of proton ion exchange was conserved.

  14. Formation of Interfacial Layer and Long-Term Cylability of Li-O-2 Batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Mehdi, Beata L.; Thomsen, Edwin C.; Engelhard, Mark H.; Masse, Robert C.; Bhattacharya, Priyanka; Gu, Meng; Bennett, Wendy D.; Nie, Zimin; Wang, Chong M.; Browning, Nigel D.; Zhang, Jiguang

    2014-07-28T23:59:59.000Z

    Extended cycling of the Li-O2 battery under full discharge/charge conditions is achievable upon selection of appropriate electrode materials and cycling protocol. However, the decomposition of the side products also contribute to the observed good cycling behavior of high capacity Li-O2 batteries. Quantitative analyses of the discharge and charge products reveals a quick switch from the predominant formation of Li2O2 to the predominant formation of side products during the first a few cycles of the Li-O2 batteries. After the switch, cycling stabilizes with a repeatable formation of Li2O2/side products at ~1:2 ratio. CNTs/Ru composite electrodes exhibits lower charge voltage and deliver 50 full discharge-charge cycles without sharp capacity drop. Ru coated glass carbon electrode can lead to more than 500 cycles without change in its cycling profiles. The better understanding on Li-O2 reaction processes developed in this work may lead to the further improvement on the long term cycling behavior of high capacity Li-O2 batteries.

  15. Lithium ion diffusion in Li ?-alumina single crystals measured by pulsed field gradient NMR spectroscopy

    SciTech Connect (OSTI)

    Chowdhury, Mohammed Tareque, E-mail: mtareque@mail.tagen.tohoku.ac.jp; Takekawa, Reiji; Iwai, Yoshiki; Kuwata, Naoaki; Kawamura, Junichi [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku Sendai 980-8577 (Japan)] [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1, Katahira, Aoba-ku Sendai 980-8577 (Japan)

    2014-03-28T23:59:59.000Z

    The lithium ion diffusion coefficient of a 93% Li ?-alumina single crystal was measured for the first time using pulsed field gradient (PFG) NMR spectroscopy with two different crystal orientations. The diffusion coefficient was found to be 1.2 × 10{sup ?11} m{sup 2}/s in the direction perpendicular to the c axis at room temperature. The Li ion diffusion coefficient along the c axis direction was found to be very small (6.4 × 10{sup ?13} m{sup 2}/s at 333 K), which suggests that the macroscopic diffusion of the Li ion in the ?-alumina crystal is mainly two-dimensional. The diffusion coefficient for the same sample was also estimated using NMR line narrowing data and impedance measurements. The impedance data show reasonable agreement with PFG-NMR data, while the line narrowing measurements provided a lower value for the diffusion coefficient. Line narrowing measurements also provided a relatively low value for the activation energy and pre-exponential factor. The temperature dependent diffusion coefficient was obtained in the temperature range 297–333 K by PFG-NMR, from which the activation energy for diffusion of the Li ion was estimated. The activation energy obtained by PFG-NMR was smaller than that obtained by impedance measurements, which suggests that thermally activated defect formation energy exists for 93% Li ?-alumina single crystals. The diffusion time dependence of the diffusion coefficient was observed for the Li ion in the 93% Li ?-alumina single crystal by means of PFG-NMR experiments. Motion of Li ion in fractal dimension might be a possible explanation for the observed diffusion time dependence of the diffusion coefficient in the 93% Li ?–alumina system.

  16. Density functional theory study of the mechanism of Li diffusion in rutile RuO{sub 2}

    SciTech Connect (OSTI)

    Jung, Jongboo; Cho, Maenghyo [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of)] [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of); Zhou, Min, E-mail: min.zhou@gatech.edu [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of) [WCU Program on Multiscale Mechanical Design, School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea, Republic of); George W. Woodruff School of Mechanical Engineering, School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0405 (United States)

    2014-01-15T23:59:59.000Z

    First-principle calculations are carried out to study the diffusion of Li ions in rutile structure RuO{sub 2}, a material for positive electrodes in rechargeable Li ion batteries. The calculations focus on migration pathways and energy barriers for diffusion in Li-poor and Li-rich phases using the Nudged Elastic Band Method. Diffusion coefficients estimated based on calculated energy barriers are in good agreement with experimental values reported in the literature. The results confirm the anisotropic nature of diffusion of Li ions in one-dimensional c channels along the [001] crystalline direction of rutile RuO{sub 2} and show that Li diffusion in the Li-poor phase is faster than in the Li-rich phase. The findings of fast Li diffusion and feasible Li insertion at low temperatures in the host rutile RuO{sub 2} suggest this material is a good ionic conductor for Li transport. The finding also suggests possible means for enhancing the performance of RuO{sub 2}-based electrode materials.

  17. Fusion reactions in collisions induced by Li isotopes on Sn targets

    SciTech Connect (OSTI)

    Fisichella, M.; Shotter, A. C.; Di Pietro, A.; Figuera, P.; Lattuada, M.; Marchetta, C.; Musumarra, A.; Pellegriti, M. G.; Ruiz, C.; Scuderi, V.; Strano, E.; Torresi, D.; Zadro, M. [Dipartimento di Fisica, Universita di Messina, Messina (Italy) and INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy); School of Physics and Astronomy, University of Edinburgh, Edinburgh (United Kingdom) and TRIUMF, Vancouver (Canada); INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy); INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania, Italy and Dipartimento di Fisica ed Astronomia, Universita di Catania, Catania (Italy); INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy); INFN- Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy) and Dipartimento di Fisica ed Astronomia, Universita di Catania, Catania (Italy); TRIUMF, Vancouver (Canada); INFN-Laboratori Nazionali del Sud and sezione di Catania, Catania (Italy) and Dipartimento di Fisica ed Astronomia, Universita di Catania, Catania (Italy); Ruder Boskovic Institute, Zagreb (Croatia)

    2012-10-20T23:59:59.000Z

    Fusion cross sections for the {sup 6}Li+{sup 120}Sn and {sup 7}Li+{sup 119}Sn systems have been measured. We aim to search for possible effects due to the different neutron transfer Q-values, by comparing the fusion cross sections for the two systems below the barrier. This experiment is the first step of a wider systematic aiming to study the above problems in collisions induced by stable and unstable Li isotopes on tin all forming the same compound nucleus.

  18. The growth and characterization of LiGd?(Mo0?)? single crystals

    E-Print Network [OSTI]

    Reimund, James Allyn

    1981-01-01T23:59:59.000Z

    ' C/second 37 Pyroelectric Current vs. Temperature dT/dt = 30' C/second 180' Domains (Gd (MoO ) ) 37 39 INTRODUCTION This thesis discusses the growth and some single crystalline properties of lithium-gadolinium-molybdate of the type LiGd (Mo...O ) 3 45' This compound is one of the three thus far discovered compounds of the lithium ? gadolinium-molybdate (LGMO) system. In general, this system can be expressed as Li2Mo04. XGd2(Mo04)3, where LiGd3(MoO, )5 4 5 single crystals synthesize when X...

  19. OLD DOMINION UNIVERSITY University Policies and Procedures

    E-Print Network [OSTI]

    AND ADMINISTRATOR RECRUITMENT FUNDING PROCEDURE Statement: University Recruitment Budget (1) The university6010 - 1 OLD DOMINION UNIVERSITY University Policies and Procedures 6010 - FACULTY maintains a central budget, called the University Recruitment Budget, for the support of essential

  20. 1 Columbia University--The University Seminars COLUMBIA UNIVERSITY

    E-Print Network [OSTI]

    Champagne, Frances A.

    1 Columbia University--The University Seminars COLUMBIA UNIVERSITY T H E U N I V E R S I T Y S E M. Belknap Professor Emeritus of Russian, Columbia University, Director Emeritus of The University Seminars, Columbia University Susan Boynton Associate Professor of Music, Columbia University Ester Fuchs Professor

  1. Hydrogen storage in LiAlH4 : Predictions of the crystal structures and reaction mechanisms of intermediate phases from quantum mechanics

    E-Print Network [OSTI]

    Goddard III, William A.

    Hydrogen storage in LiAlH4 : Predictions of the crystal structures and reaction mechanisms in decomposition of the potential hydrogen storage material LiAlH4 . First, we explore the decomposition mechanism of monoclinic LiAlH4 into monoclinic Li3AlH6 plus face-centered cubic fcc Al and hydrogen. We find

  2. Geophysical inversion using petrophysical constraints with application to lithology differentiation Jiajia Sun and Yaoguo Li, Center for Gravity, Electrical and Magnetic Studies, Colorado School of Mines

    E-Print Network [OSTI]

    Jiajia Sun and Yaoguo Li, Center for Gravity, Electrical and Magnetic Studies, Colorado School of Mines

  3. Compact Li-doped Gd{sub 2}Ti{sub 2}O{sub 7} prepared with LiO{sub 0.5} self-flux

    SciTech Connect (OSTI)

    Wen, L.C.; Hsieh, H.Y.; Chang, S.C.; Lin, M.Y.; Lee, Y.H.; Su, W.P. [Department of Chemistry, Tamkang University, New Taipei City 25137, Taiwan (China); Kao, H.-C.I., E-mail: kaohci@mail.tku.edu.tw [Department of Chemistry, Tamkang University, New Taipei City 25137, Taiwan (China); Sheu, H.S.; Jang, L.Y. [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China); Lee, M.C.; Lee, Y.S. [Institute of Nuclear Energy Research, Atomic Energy Council, Longtan 32546, Taiwan (China)

    2014-02-01T23:59:59.000Z

    Graphical abstract: Left figure is the unit cell a-axis of the GLT-2L (?), GLT (?) and GT (?) as a function of x. Both of the GLT-2L and GLT have the same results so that they have the same chemical formula, (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x}, in which GT has a formula of Gd{sub 2?x}Ti{sub 2}O{sub 7?x}. Relative densities are shown in the right figure. GLT-2L (?) has higher values than GLT (?). 2x moles of LiO{sub 0.5} were added as a self-flux to prepare GLT-2L at 1250 °C, which was about 300 °C lowered than required without the co-existence of the flux and Li ion substitution. - Highlights: • A new series of compounds with a formula as (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x} was synthesized. • Each GLT-2L sample contains (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x} and 2x moles of LiO{sub 0.5} self-flux. • 1250 °C was used to prepare the GLT-2L samples; 300 °C lower than required. • Electrical conductivity of the GLT-2L is not affected by the presence of the flux. • Average valence of the Ti ions is slightly less than 4. - Abstract: A series of (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x} with x = 0.040–0.110 was first reported. Parent compound with 2x moles of LiO{sub 0.5} self-flux was prepared at 1250 °C and abbreviated as GLT-2L. Relative density of all the samples is higher than 92%. By the addition of flux and Li ions substitution, preparation temperature is lowered for more than 300 °C. Comparing the unit cell a-axis, GLT with a formula as (Gd{sub 2?x}Li{sub x})Ti{sub 2}O{sub 7?x} without flux addition has exactly the same as the GLT-2L with the same x. By the addition of flux, materials become more compact and grains grow bigger for the GLT-2L than the corresponding GLT samples. Electrical conductivity of a GLT-2L with x = 0.110 at 700 °C is 3 times larger than the measurements done by other research groups in the Gd{sub 2}Ti{sub 2}O{sub 7}. In order to demonstrate the successful substitution of the Li ion into the Gd site, a series of GT samples was prepared with a formula of Gd{sub 2?x}Ti{sub 2}O{sub 7?1.5x}. With the same amount of x, every GLT samples have a longer unit cell a-axis than that of the GT. The difference is caused by the substitution of the Li ion into the Gd site. Valence of the Ti atoms of the GLT-2L samples is slightly less than 4 studied by the XANES spectroscopy.

  4. Second-Use Li-Ion Batteries to Aid Automotive and Utility Industries (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01T23:59:59.000Z

    Repurposing Li-ion batteries at the end of useful life in electric drive vehicles could eliminate owners' disposal concerns and offer low-cost energy storage for certain applications.

  5. High Energy Density Li-ion Cells for EVs Based on Novel, High...

    Broader source: Energy.gov (indexed) [DOE]

    Storage Systems Vehicle Technologies Annual Merit Review 6182014 1 High Energy Density Li-ion Cells for EV's Based on Novel, High Voltage Cathode Material Systems Keith D. Kepler...

  6. LiNaK : multi-species apparatus for the study of ultracold quantum degenerate mixtures

    E-Print Network [OSTI]

    Santiago González, Ibon

    2012-01-01T23:59:59.000Z

    This thesis describes the construction of a versatile apparatus to study ultracold quantum mixtures capable of simultaneously cooling fermionic ?Li and ??K, as well as the bosonic ?¹K. The main features of the experimental ...

  7. Spatial Sound Rendering Using Measured Room Impulse Responses Yan Li, Peter F. Driessen

    E-Print Network [OSTI]

    Driessen, Peter F.

    Spatial Sound Rendering Using Measured Room Impulse Responses Yan Li, Peter F. Driessen Dept, Banff Centre Banff, Alberta, Canada Abstract-- Spatial sound rendering has many applications different quality and complexity requirements. This paper presents a new spatial sound rendering framework

  8. An ultra-compact and efficient Li-ion battery charger circuit for biomedical applications

    E-Print Network [OSTI]

    Do Valle, Bruno Guimaraes

    This paper describes an ultra-compact analog lithium-ion (Li-ion) battery charger for wirelessly powered implantable medical devices. The charger presented here takes advantage of the tanh output current profile of an ...

  9. Proceedings of the AD HOC Workshop on Ceramics for Li/FeS{sub 2} batteries

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    Representatives from industry, the U.S. Advanced Battery Consortium (USABC), DOE, national laboratories, and other govt agencies met to develop recommendations and actions for accelerating the development of ceramic components critical to the successful introduction of the Li/FeS{sub 2} bipolar battery for electric vehicles. Most of the workshop is devoted to electrode materials, bipolar designs, separators, and bipolar plates. The bulk of this document is viewographs and is divided into: ceramics, USABC overview, SAFT`s Li/FeS{sub 2} USABC program, bipolar Li/FeS{sub 2} component development, design requirements for bipolar plates, separator design requirements, compatibility of ceramic insulators with lithium, characterization of MgO for use in separators, resistivity measurements of separators, sintered AlN separators for LiMS batteries, etc.

  10. Improved layered mixed transition metal oxides for Li-ion batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2010-01-01T23:59:59.000Z

    M n , ^ for Advanced Lithium-Ion Batteries," J. Electrochem.of LiCoi/3Nii/ Mn 02 for lithium-ion batteries," Chem.Mni/ 0 for advanced lithium-ion batteries," J. Power

  11. Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries

    E-Print Network [OSTI]

    Shim, J.; Guerfi, A.; Zaghib, K.; Striebel, K.A.

    2003-01-01T23:59:59.000Z

    Cathode for Lithium-Ion Batteries J. Shim a , A. Guerfi b ,material for Li rechargeable batteries because of low-cost,is a part of BATT (Batteries for Advanced Transportation

  12. Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    Graphite and Olivine-Based Materials for Li-Ion Batteries K. Zaghib Hydro-Qubec (IREQ), 1800 Lionel-Boulet Varennes, QC, Canada, J3X 1S1 BATT Review Meeting February 25 - 28,...

  13. Sen's Theorem: Geometric Proof and New Interpretations Lingfang (Ivy) Li and Donald G. Saari

    E-Print Network [OSTI]

    Saari, Don

    Sen's Theorem: Geometric Proof and New Interpretations Lingfang (Ivy) Li and Donald G. Saari Dept liberal, paradox, decision theory 2 Saari's research was supported by NSF grant DMI 0233798. 1 #12;A

  14. Characterization of LiNi?.?Mn?.?O? Thin Film Cathode Prepared by Pulsed Laser Deposition

    E-Print Network [OSTI]

    Xia, Hui

    LiNi?.?Mn?.?O? thin films have been grown by pulsed laser deposition (PLD) on stainless steel (SS) substrates. The crystallinity and structure of thin films were investigated by X-ray diffraction (XRD). Microstructure and ...

  15. Study on LiCl waste salt treatment process by layer melt crystallization

    SciTech Connect (OSTI)

    Cho, Yung-Zun; Lee, Tae-Kyo; Choi, Jung-Hoon; Eun, Hee-Chul; Park, Hwan-Seo; Kim, In-Tae; Park, Geun-Il [Korea Atomic Energy Research Institute, 1045 Daedeok-daero, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

    2013-07-01T23:59:59.000Z

    Layer melt crystallization operated in a static mode has been applied to separate Group I and II chlorides from surrogate LiCl waste salt. The effects of operating conditions such as crystal growing rate(or flux) and initial impurity concentration on separation (or concentration) of cesium, strontium and barium involved in a LiCl melts were analyzed. In a layer crystallization process, separation was impaired by occlusion of impurities and by residual melt adhering to LiCl crystal after at the end of the process. The crystal growth rate strongly affects the crystal structure, therefore the separation efficiency, while the effect of the initial Cs and Sr concentration in LiCl molten salt was nearly negligible. (authors)

  16. Vehicle Technologies Office Merit Review 2015: A 12V Start-Stop Li Polymer Battery Pack

    Broader source: Energy.gov [DOE]

    Presentation given by LG Chem Power at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about A 12V start-stop Li polymer...

  17. Towards Quantifying the (In)Security of Networked Systems Xiaohu Li T. Paul Parker Shouhuai Xu

    E-Print Network [OSTI]

    Xu, Shouhuai

    Towards Quantifying the (In)Security of Networked Systems Xiaohu Li T. Paul Parker Shouhuai Xu Traditional security analyses are often geared towards cryptographic primitives or protocols. Although approach. 1 Introduction Traditional security analyses are typically geared to- wards cryptographic

  18. The Li'an ("Docketing") Process: Barriers to Initiating Lawsuits in China and Possible Reforms

    E-Print Network [OSTI]

    Cheuk, Andrea

    2008-01-01T23:59:59.000Z

    Supreme People's Court ("SPC") found it necessary to pro-note 10, at 88-9. The 1999 SPC Five Year Reform Program ("On May 29, 1997, the SPC issued the Li'an ("Docketing") Work

  19. Solid-State Hydriding Mechanism in the LiBH4 + MgH2 System. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The LiBH4+MgH2 system has great potential in reversible hydrogen storage for fuel cell vehicles. However, it has always been dehydrogenated and re-hydrogenated in the liquid...

  20. Mesoscale Modeling of a Li-Ion Polymer Cell Chia-Wei Wanga,

    E-Print Network [OSTI]

    Sastry, Ann Marie

    Mesoscale Modeling of a Li-Ion Polymer Cell Chia-Wei Wanga, * and Ann Marie Sastrya,b,c, *,z, the study reported critical data required for mesoscale numerical simulation, including ionic con- ductivity

  1. Traka yon kretyen pandan vwayaj li : adaptasyon liv “Pilgrim’s Progress" / John Bunyan

    E-Print Network [OSTI]

    Paultre, Carrie?; Bunyan, John; Ross, Jim D.; Freeman, Bryant C.

    2000-01-01T23:59:59.000Z

    nan syM la. »4 Li fe lekti yon I6t pasaj nan Bib la: «Moun mwen fe gras la ap viv, paske li gen konfyans nan mwen. Men, si 1 vire do 1 tounen fe bak, li p ap fe ke m kontan. »5 Levanjil esplike Kretyen paw6l la konsa: «Men sa ki rive, ou te kite... rekonpans li nan lemonn ki ap vini an.» 27 Entepret: «Ougenrezon. Bagay nou wb ak je p ap dire non. Se sa je pa we ki eten£l.»4 Le sa a nan rev la, mwen wb Ent£pr£t pran men Kretyen epi 1 mennen 1 devan yon mi, kote ki te gen yon gwo dife k ap boule...

  2. Technical Note LiDAR-derived measures of hurricane-and restoration-generated beach

    E-Print Network [OSTI]

    Weishampel, John F.

    are particularly vulnerable, as they rely on specific beaches for reproduction and exhibit high-nest-site fidelityTechnical Note LiDAR-derived measures of hurricane- and restoration-generated beach morphodynamics

  3. DIMACS Center Rutgers University

    E-Print Network [OSTI]

    Hopkins University Andrew Patrick, NRC Canada Norman Sadeh, Carnegie Mellon University Working Group University Mark Ackerman, University of Michigan Fabian Monrose, Johns Hopkins University Andrew Patrick, NRC Canada Norman Sadeh, Carnegie Mellon University Workshop: Cryptography: Theory Meets Practice Dates

  4. ADMINISTRATIVE UNIVERSITY POLICY

    E-Print Network [OSTI]

    ADMINISTRATIVE UNIVERSITY POLICY FACULTY UNIVERSITY POLICY STUDENT UNIVERSITY POLICY Issue stakeholder list "Log-In" of Proposed University Policy with the University Compliance Committee (UCC) UCC identifies which track (i.e., Administrative, Faculty, or Student) the proposed University Policy

  5. Nanostructured ion beam-modified Ge films for high capacity Li ion battery anodes

    SciTech Connect (OSTI)

    Rudawski, N. G.; Darby, B. L.; Yates, B. R.; Jones, K. S. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611-6400 (United States); Elliman, R. G. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, Australian Capital Territory 0200 (Australia); Volinsky, A. A. [Department of Mechanical Engineering, University of South Florida, Tampa Florida 33620 (United States)

    2012-02-20T23:59:59.000Z

    Nanostructured ion beam-modified Ge electrodes fabricated directly on Ni current collector substrates were found to exhibit excellent specific capacities during electrochemical cycling in half-cell configuration with Li metal for a wide range of cycling rates. Structural characterization revealed that the nanostructured electrodes lose porosity during cycling but maintain excellent electrical contact with the metallic current collector substrate. These results suggest that nanostructured Ge electrodes have great promise for use as high performance Li ion battery anodes.

  6. Electrochemical Performance of LiMnPO4 Synthesized with Off-Stoichiometry

    E-Print Network [OSTI]

    Ceder, Gerbrand

    of LiMPO4 compounds is of interest as cathode ma- terials for rechargeable lithium batteries. LiFePO4 has been in- tensely studied and several techniques such as carbon coating, coat- ing with a metallic2PO4 using heat-treatments at 350°C for 10 h and at 700°C for 10 h under Ar or air atmosphere

  7. Electrochemical Properties of Disordered-Carbon-Coated SnO2 Nanoparticles for Li Rechargeable Batteries

    E-Print Network [OSTI]

    Park, Byungwoo

    Batteries Taeho Moon, Chunjoong Kim, Sun-Tae Hwang, and Byungwoo Park*,z School of Materials Science batteries.1-5 It is rationalized that the reactions of SnO2 with lithium are SnO2 + 4Li Sn + 2Li2O and Sn is to distribute nanoparticles uniformly on a large matrix such as graphite, mesoporous carbon, etc.12,13 However

  8. NREL's PHEV/EV Li-Ion Battery Secondary-Use Project

    SciTech Connect (OSTI)

    Newbauer, J.; Pesaran, A.

    2010-06-01T23:59:59.000Z

    Accelerated development and market penetration of plug-in hybrid electric vehicles (PHEVs) and electric vehicles (EVs) is restricted at present by the high cost of lithium-ion (Li-ion) batteries. One way to address this problem is to recover a fraction of the Li-ion battery's cost via reuse in other applications after it is retired from service in the vehicle, when the battery may still have sufficient performance to meet the requirements of other energy storage applications.

  9. Synthesis and Characterization of Lithium Bis(fluoromalonato)borate (LiBFMB) for Lithium Ion Battery Applications

    SciTech Connect (OSTI)

    Liao, Chen [ORNL] [ORNL; Han, Kee Sung [ORNL] [ORNL; Baggetto, Loic [ORNL] [ORNL; Hillesheim, Daniel A [ORNL] [ORNL; Custelcean, Radu [ORNL] [ORNL; Lee, Dr. Eun-Sung [University of Texas at Austin] [University of Texas at Austin; Guo, Bingkun [ORNL] [ORNL; Bi, Zhonghe [ORNL] [ORNL; Jiang, Deen [ORNL] [ORNL; Veith, Gabriel M [ORNL] [ORNL; Hagaman, Edward {Ed} W [ORNL; Brown, Gilbert M [ORNL] [ORNL; Bridges, Craig A [ORNL] [ORNL; Paranthaman, Mariappan Parans [ORNL] [ORNL; Manthiram, Arumugam [University of Texas at Austin] [University of Texas at Austin; Dai, Sheng [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    A new orthochelated salt, lithium bis(monofluoromalonato)borate (LiBFMB), has been synthesized and purified for the first time for application in lithium ion batteries. The presence of fluorine in the borate anion of LiBFMB increases its oxidation potential and also facilitates ion dissociation, as reflected by the ratio of ionic conductivity measured by electrochemical impedance spectroscopy ( exp) and that by ion diffusivity coefficients obtained using pulsed field gradient nuclear magnetic resonance (PFG-NMR) technique ( NMR). Half-cell tests using 5.0 V lithium nickel manganese oxide (LiNi0.5Mn1.5O4) as a cathode and EC/DMC/DEC as a solvent reveals that the impedance of the LiBFMB cell is much larger than those of LiPF6 and LiBOB based cells, which results in lower capacity and poor cycling performance of the former. XPS spectra of the cycled cathode electrode suggest that because of the stability of the LiBFMB salt, the solid electrolyte interphase (SEI) formed on the cathode surface is significantly different from those of LiPF6 and LiBOB based electrolytes, resulting in more solvent decomposition and thicker SEI layer. Initial results also indicate that using high dielectric constant solvent PC alters the surface chemistry, reduces the interfacial impedance, and enhances the performance of LiBFMB based 5.0V cell.

  10. CONSORTIUM MEMBERS EU Universities

    E-Print Network [OSTI]

    Heermann, Dieter W.

    coordinator > University of Tirana, Albania > University of Sarajevo, Bosnia & Herzegovina > South East Foundation, Belgium > University of Tuzla, Bosnia & Herzegovina > Roma Virtual Network, Israel > University

  11. Delayed neutron emission probabilities of Li-F nuclides

    SciTech Connect (OSTI)

    Reeder, P.L.; Warner, R.A.; Hensley, W.K. (Pacific Northwest Lab., Richland, WA (USA)); Vieira, D.J.; Wouters, J.M. (Los Alamos National Lab., NM (USA))

    1989-09-01T23:59:59.000Z

    Delayed neutron emission probabilities (P{sub n}) have been measured for 18 nuclides ranging from {sup 9}Li to {sup 25}F. Neutron-rich nuclides were produced by reaction of 800 MeV p on a {sup 232}Th target at the LAMPF accelerator at Los Alamos National Laboratory. Recoil nuclides were individually identified as to their mass, nuclear charged, and ionic charge by use of the Time-of-Flight Isochronous (TOFI) spectrometer. The distribution of time intervals between the arrival of a specific ion and the subsequent detection of a neutron was determined. The P{sub n} was calculated from the total number of ions observed, the initial neutron count rate, the neutron counting efficiency, and the half-life. The technique is shown to be valid for half-lives ranging from 10 ms ({sup 15}B) to 4 s ({sup 17}N) and for P{sub n} values as low as 0.3% ({sup 13}B). Delayed neutron emission has been measured for {sup 12}Be, {sup 14}B, {sup 17}C, {sup 18}N, {sup 21}N, and {sup 25}F for the first time. A small branch for beta-delayed two-neutron emission was observed in {sup 15}B (P{sub 2n} = 0.4 {plus minus} 0.2%). 14 refs., 6 figs., 1 tab.

  12. Cylindrical target Li-beam-driven hohlraum experiments

    SciTech Connect (OSTI)

    Derzon, M.S.; Aubert, J.; Chandler, G.A. [and others

    1998-06-01T23:59:59.000Z

    The authors performed a series of experiments on the Particle Beam Fusion Accelerator II (PBFA II) in May, 1994, and obtained a brightness temperature of 61 {+-} 2 eV for an ion-beam heated hohlraum. The hohlraum was a 4-mm-diameter, right-circular cylinder with a 1.5-mm-thick gold wall, a low-density CH foam fill, and a 1.5- or 3-mm-diameter diagnostic aperture in the top. The nominal parameters of the radially-incident PBFA II Li ion beam were 9 MeV peak energy ({approximately}10 MeV at the gas cell) at the target at a peak power of 2.5 {+-} 0.3 TW/cm{sup 2} and a 15 ns pulse width. Azimuthal variations in intensity of a factor of 3, with respect to the mean, were observed. Nonuniformities in thermal x-ray emission across the area of the diagnostic hole were also observed. Time-dependent hole-closure velocities were measured: the time-averaged velocity of {approximately}2 cm/{micro}s is in good agreement with sound speed estimates. Unfolded x-ray spectra and brightness temperatures as a function of time are reported and compared to simulations. Hole closure corrections are discussed with comparisons between XRD and bolometer measurements. Temperature scaling with power on target is also presented.

  13. University of Michigan, Ann Arbor Indiana University, Bloomington

    E-Print Network [OSTI]

    Wu, Yih-Min

    / 1 #12; 2005 4 University of Michigan, Ann Arbor Indiana University, Bloomington University of Illinois, Urbana-Champagne University of Michigan, Ann Arbor 19 Center University of Michigan, Georgetown University, University of Nebraska, University of Kansas University

  14. Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F) as cathode materials for lithium ion battery from atomistic simulation

    SciTech Connect (OSTI)

    Lee, Sanghun, E-mail: sh0129.lee@samsung.com; Park, Sung Soo, E-mail: sung.s.park@samsung.com

    2013-08-15T23:59:59.000Z

    Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) have been investigated from atomistic simulation. In order to predict the characteristics of these materials as cathode materials for lithium ion batteries, structural property, defect chemistry, and Li{sup +} ion transportation property are characterized. The core–shell model with empirical force fields is employed to reproduce the unit-cell parameters of crystal structure, which are in good agreement with the experimental data. In addition, the formation energies of intrinsic defects (Frenkel and antisite) are determined by energetics calculation. From migration energy calculations, it is found that these flurophosphates have a 3D Li{sup +} ion diffusion network forecasting good Li{sup +} ion conducting performances. Accordingly, we expect that this study provides an atomic scale insight as cathode materials for lithium ion batteries. - Graphical abstract: Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F). Display Omitted - Highlights: • Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) are investigated from classical atomistic simulation. • The unit-cell parameters from experimental studies are reproduced by the core–shell model. • Li{sup +} ion conducting Li{sub 2}MPO{sub 4}F has a 3D Li{sup +} ion diffusion network. • It is predicted that Li/Co or Li/Ni antisite defects are well-formed at a substantial concentration level.

  15. Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li-O$_2$ battery capacity

    E-Print Network [OSTI]

    Burke, Colin M; Khetan, Abhishek; Viswanathan, Venkatasubramanian; McCloskey, Bryan D

    2015-01-01T23:59:59.000Z

    Among the 'beyond Li-ion' battery chemistries, nonaqueous Li-O$_2$ batteries have the highest theoretical specific energy and as a result have attracted significant research attention over the past decade. A critical scientific challenge facing nonaqueous Li-O$_2$ batteries is the electronically insulating nature of the primary discharge product, lithium peroxide, which passivates the battery cathode as it is formed, leading to low ultimate cell capacities. Recently, strategies to enhance solubility to circumvent this issue have been reported, but rely upon electrolyte formulations that further decrease the overall electrochemical stability of the system, thereby deleteriously affecting battery rechargeability. In this study, we report that a significant enhancement (greater than four-fold) in Li-O$_2$ cell capacity is possible by appropriately selecting the salt anion in the electrolyte solution. Using $^7$Li nuclear magnetic resonance and modeling, we confirm that this improvement is a result of enhanced Li...

  16. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte

    SciTech Connect (OSTI)

    Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2014-08-25T23:59:59.000Z

    Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

  17. Li{sub 4}FeH{sub 6}: Iron-containing complex hydride with high gravimetric hydrogen density

    SciTech Connect (OSTI)

    Saitoh, Hiroyuki, E-mail: cyto@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Iijima, Yuki [WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Endo, Naruki [Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology, Fukushima 963-0215 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2014-07-01T23:59:59.000Z

    Li{sub 4}FeH{sub 6}, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900?°C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li{sub 4}FeH{sub 6} is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li{sub 4}FeH{sub 6} at moderate pressures. Li{sub 4}FeH{sub 6} can be recovered at ambient conditions where Li{sub 4}FeH{sub 6} is metastable.

  18. Montgomery, *University

    E-Print Network [OSTI]

    Zink+, Doug Montgomery, Jin Ho Hahm# National Institute of Standards and Technology (NIST) *University Label table Label table APIs Label routing APIs RSVP label APIs user level kernel level NIST Switch 6

  19. Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Wang, Chong M.; Zuo, Pengjian; Koech, Phillip K.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-09-20T23:59:59.000Z

    Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially three to five times higher energy density than that of traditional lithium ion batteries. However, the dissolution and precipitation of soluble polysulfides during cycling initiate a series of key-chain reactions that significantly shorten battery life. Herein, we demonstrate that through a simple but effective strategy, significantly improved cycling performance is achieved for high sulfur loading electrodes through controlling the nucleation and precipitation of polysulfieds on the electrode surface. More than 400 or 760 stable cycling are successfully displayed in the cells with locked discharge capacity of 625 mAh g-1 or 500 mAh g-1, respectively. The nucleation and growth process of dissolved polysulfides has been electrochemically altered to confine the thickness of discharge products passivated on the cathode surface, increasing the utilization rate of sulfur while avoiding severe morphology changes on the electrode. More importantly, the exposure of new lithium metal surface to the S-containing electrolyte is also greatly reduced through this strategy, largely minimizing the anode corrosion caused by polysulfides. This work interlocks the electrode morphologies and its evolution with electrochemical interference to modulate cell performances by using Li-S system as a platform, providing different but critical directions for this community.

  20. Electrical conductivity in Li2O2 and its role in determining capacity limitations in non-aqueous Li-O2 batteries

    E-Print Network [OSTI]

    Thygesen, Kristian

    -O2 batteries V. Viswanathan, K. S. Thygesen, J. S. Hummelshøj, J. K. Nørskov, G. Girishkumar et al limitations in non-aqueous Li-O2 batteries V. Viswanathan,1 K. S. Thygesen,2 J. S. Hummelshøj,3 J. K. Nørskov energy density battery couple. Such cells, however, show sudden death at capacities far below

  1. http://lez1.pppl.gov/pub/LiWTokamak.ps http://lez1.pppl.gov/pub/LiWTokamak.pdf

    E-Print Network [OSTI]

    Zakharov, Leonid E.

    with Lithium Walls L. E. Zakharov, PPPL Background: A recently discovered mechanism of magnetic propulsion of withstanding the possible electromagnetic forces during potential disruptions. Electro-magnetic propulsion is smallest. The velocity of the Li streams due to magnetic propulsion is of order 10-20 m/sec and should

  2. Mechanical property, biocorrosion and in vitro biocompatibility evaluations of MgLi(Al)(RE) alloys for future cardiovascular stent

    E-Print Network [OSTI]

    Zheng, Yufeng

    ­Li alloys have become candi- date materials for many applications in the fields of aerospace and military­Li­(Al)­(RE) alloys for future cardiovascular stent application q W.R. Zhou a , Y.F. Zheng a,b, , M.A. Leeflang c , J February 2013 Keywords: Mg­Li-based alloys Biodegradable Corrosion Biocompatibility In vitro a b s t r a c

  3. Synthesis of spherical LiMnPO{sub 4}/C composite microparticles

    SciTech Connect (OSTI)

    Bakenov, Zhumabay [Department of Chemical Engineering, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552 (Japan)] [Department of Chemical Engineering, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552 (Japan); Taniguchi, Izumi, E-mail: taniguchi.i.aa@m.titech.ac.jp [Department of Chemical Engineering, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552 (Japan)] [Department of Chemical Engineering, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8552 (Japan)

    2011-08-15T23:59:59.000Z

    Highlights: {yields} We could prepare LiMnPO{sub 4}/C composites by a novel preparation method. {yields} The LiMnPO{sub 4}/C composites were spherical particles with a mean diameter of 3.65 {mu}m. {yields} The LiMnPO{sub 4}/C composite cathode exhibited 112 mAh g{sup -1} at 0.05 C. {yields} It also showed a good rate capability up to 5 C at room temperature and 55 {sup o}C. -- Abstract: Spherical LiMnPO{sub 4}/C composite microparticles were prepared by a combination of spray pyrolysis and spray drying followed by heat treatment and examined as a cathode material for lithium batteries. The structure, morphology and electrochemical performance of the resulting spherical LiMnPO{sub 4}/C microparticles were characterized by X-ray diffraction, field-emission scanning electron microscopy, transmission electronic microscopy and standard electrochemical techniques. The final sample was identified as a single phase orthorhombic structure of LiMnPO{sub 4} and spherical powders with a geometric mean diameter of 3.65 {mu}m and a geometric standard deviation of 1.34. The electrochemical cells contained the spherical LiMnPO{sub 4}/C microparticles exhibited first discharge capacities of 112 and 130 mAh g{sup -1} at 0.05 C at room temperature and 55 {sup o}C, respectively. These also showed a good rate capability up to 5 C at room temperature and 55 {sup o}C.

  4. University Archives University of Missouri at Columbia

    E-Print Network [OSTI]

    Taylor, Jerry

    University Archives University of Missouri at Columbia 703 Lewis Hall University of Missouri-Columbia Archives of the University of Missouri at Columbia reserves the right to refuse permission to individuals agree to credit the University Archives of the University of Missouri at Columbia in accordance

  5. The Environmental Impacts of Logistics Systems and Options for Mitigation Nakul Sathaye, Yuwei Li, Arpad Horvath and Samer Madanat

    E-Print Network [OSTI]

    California at Berkeley, University of

    The Environmental Impacts of Logistics Systems and Options for Mitigation Nakul Sathaye, Yuwei Li.2. Indirect Environmental Externalities....................................................................12 3. The Problem of Environmental Externalities

  6. Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries

    SciTech Connect (OSTI)

    Katiyar, Ram S; Gómez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

    2009-01-19T23:59:59.000Z

    Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation ‘Li-ion rechargeable battery’ and ‘LiCoO2 cathode’ is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

  7. Three Li-rich K giants: IRAS 12327-6523, IRAS 13539-4153, and IRAS 17596-3952

    E-Print Network [OSTI]

    Bacham E. Reddy; David L. Lambert

    2005-03-11T23:59:59.000Z

    We report on spectroscopic analyses of three K giants previously suggested to be Li-rich: IRAS 12327-6523, IRAS 13539-4153, and IRAS 17596-3952. High-resolution optical spectra and the LTE model atmospheres are used to derive the stellar parameters: ($T_{\\rm eff}$, log $g$, [Fe/H]), elemental abundances, and the isotopic ratio $^{12}$C/$^{13}$C. IRAS 13539-4153 shows an extremely high Li abundance of $\\log\\epsilon$(Li) $\\approx$ 4.2, a value ten times more than the present Li abundance in the local interstellar medium. This is the third highest Li abundance yet reported for a K giant. IRAS 12327-6523 shows a Li abundances of $\\log\\epsilon$(Li)$\\approx$ 1.4. IRAS 17596-3952 is a rapidly rotating ($V{\\sin i}$ $\\approx$ 35 km s$^{-1}$) K giant with $\\log\\epsilon$(Li) $\\approx$ 2.2. Infrared photometry which shows the presence of an IR excess suggesting mass-loss. A comparison is made between these three stars and previously recognized Li-rich giants.

  8. Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management

    SciTech Connect (OSTI)

    Viswanathan, Vilayanur V.; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A.; Williford, Ralph E.; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

    2010-06-01T23:59:59.000Z

    The entropy changes (?S) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

  9. UNIVERSITY STANDARDS AND REGULATIONS

    E-Print Network [OSTI]

    Royer, Dana

    2014­2015 UNIVERSITY STANDARDS AND REGULATIONS #12;Wesleyan University does not discriminate STANDARDS OF CONDUCT

  10. UNIVERSITY STANDARDS AND REGULATIONS

    E-Print Network [OSTI]

    Royer, Dana

    2013­2014 UNIVERSITY STANDARDS AND REGULATIONS #12;Wesleyan University does not discriminate STANDARDS OF CONDUCT

  11. UNIVERSITY OF ABERDEEN UNIVERSITY COURT

    E-Print Network [OSTI]

    Levi, Ran

    from Talisman towards student scholarships and from a number of oil companies towards a centre to be a post-doctoral researcher. The University had been ranked as one of the top twenty institutions outside

  12. 1st Observation of the (Li-6, He-8) Reaction

    E-Print Network [OSTI]

    Gagliardi, Carl A.; Semon, D. R.; Takada, E.; Tanner, D. M.; Tribble, Robert E.

    1988-01-01T23:59:59.000Z

    was supported in. part by the U.S. Depart- ment of Energy and the Robert A. Welch Foundation. 'Present address: Department of Physics, University of Tokyo, Bunkyo-ku, Tokyo 113,Japan. ~Present address: Sandia National Laboratory, Albuquerque, NM 87185. R...

  13. Design and experimental testing of the performance of an outdoor LiBr/H{sub 2}O solar thermal absorption cooling system with a cold store

    SciTech Connect (OSTI)

    Agyenim, Francis; Knight, Ian; Rhodes, Michael [The Welsh School of Architecture, Bute Building, King Edward VII Avenue, Cardiff University, Cardiff, CF10 3NB Wales (United Kingdom)

    2010-05-15T23:59:59.000Z

    A domestic-scale prototype experimental solar cooling system has been developed based on a LiBr/H{sub 2}O absorption system and tested during the 2007 summer and autumn months in Cardiff University, UK. The system consisted of a 12 m{sup 2} vacuum tube solar collector, a 4.5 kW LiBr/H{sub 2}O absorption chiller, a 1000 l cold storage tank and a 6 kW fan coil. The system performance, as well as the performances of the individual components in the system, were evaluated based on the physical measurements of the daily solar radiation, ambient temperature, inlet and outlet fluid temperatures, mass flow rates and electrical consumption by component. The average coefficient of thermal performance (COP) of the system was 0.58, based on the thermal cooling power output per unit of available thermal solar energy from the 12 m{sup 2} Thermomax DF100 vacuum tube collector on a hot sunny day with average peak insolation of 800 W/m{sup 2} (between 11 and 13.30 h) and ambient temperature of 24 C. The system produced an electrical COP of 3.6. Experimental results prove the feasibility of the new concept of cold store at this scale, with chilled water temperatures as low as 7.4 C, demonstrating its potential use in cooling domestic scale buildings. (author)

  14. ALD of Al2O3 for Highly Improved Performance in Li-Ion Batteries

    SciTech Connect (OSTI)

    Dillon, A.; Jung, Y. S.; Ban, C.; Riley, L.; Cavanagh, A.; Yan, Y.; George, S.; Lee, S. H.

    2012-01-01T23:59:59.000Z

    Significant advances in energy density, rate capability and safety will be required for the implementation of Li-ion batteries in next generation electric vehicles. We have demonstrated atomic layer deposition (ALD) as a promising method to enable superior cycling performance for a vast variety of battery electrodes. The electrodes range from already demonstrated commercial technologies (cycled under extreme conditions) to new materials that could eventually lead to batteries with higher energy densities. For example, an Al2O3 ALD coating with a thickness of ~ 8 A was able to stabilize the cycling of unexplored MoO3 nanoparticle anodes with a high volume expansion. The ALD coating enabled stable cycling at C/2 with a capacity of ~ 900 mAh/g. Furthermore, rate capability studies showed the ALD-coated electrode maintained a capacity of 600 mAh/g at 5C. For uncoated electrodes it was only possible to observe stable cycling at C/10. Also, we recently reported that a thin ALD Al2O3 coating with a thickness of ~5 A can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 degrees C. The ALD-coated NG electrodes displayed a 98% capacity retention after 200 charge-discharge cycles. In contrast, bare NG showed a rapid decay. Additionally, Al2O3 ALD films with a thickness of 2 to 4 A have been shown to allow LiCoO2 to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs Li/Li+. Bare LiCoO2 rapidly deteriorated in the first few cycles. The capacity fade is likely caused by oxidative decomposition of the electrolyte at higher potentials or perhaps cobalt dissolution. Interestingly, we have recently fabricated full cells of NG and LiCoO2 where we coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. We have also recently coated a binder free LiNi0.04Mn0.04Co02O2 electrode containing 5 wt% single-walled carbon nanotubes as the conductive additive and demonstrated both high rate capability as well as the ability to cycle the cathode to 5 V vrs. Li/Li+. Finally, we coated a Celgard (TM) separator and enabled stable cycling in a high dielectric electrolyte. These results will be presented in detail.

  15. Primary and secondary lithium passivation characteristics and effects in the Li/SO sub 2 couple

    SciTech Connect (OSTI)

    Bittner, H.F. (Aerospace Corp., Los Angeles, CA (USA). Chemistry and Physics Lab.)

    1989-11-01T23:59:59.000Z

    This paper presents a study of the characteristics and effects of the lithium passivation layer in the lithium sulfur dioxide (Li/SO{sub 2}) cell. Four aspects have been investigated: passivation layer-induced polarization; effects of long-term, low discharge rates; chemistry of the lithium passivation layer; and kinetics of the passivation layer growth. Polarization studies showed that an initial polarization (voltage delay) was in some cases followed by a secondary polarization. Studies of the effects of long-term, low discharge rates indicated that low discharge rates modified the lithium passivation layer, which resulted in increased lithium corrosion and decreased cell capacity. The degradation was greater at higher temperature. Results of the studies of the chemistry and formation kinetics of the lithium passivation layer were interpreted in terms of a primary layer, which was responsible for the passivation, and a thicker, porous secondary layer. Formation of the secondary layer is exacerbated by partial discharge. The secondary layer results from precipitation of the Li corrosion products, and was found to contain Li{sub 2}S{sub 2}O{sub 4}, Li{sub 2}S{sub 2}O{sub 5}, and Li{sub 2}S{sub n}O{sub 6}, where n > 2. The primary layer is responsible for the initial polarization (voltage delay) under load, whereas the secondary layer induces a second polarization that inhibits high-rate discharge.

  16. Pushing the Theoretical Limit of Li-CFx Batteries: A Tale of Bi-functional Electrolyte

    SciTech Connect (OSTI)

    Rangasamy, Ezhiylmurugan [ORNL] [ORNL; Li, Juchuan [ORNL] [ORNL; Sahu, Gayatri [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    In a typical battery, electrodes deliver capacities less or equal the theoretical maxima of the electrode materials.1 The inert electrolyte functions solely as the ionic conductor without contribution to the cell capacity because of its distinct mono-function in the concept of conventional batteries. Here we demonstrate that the most energy-dense Li-CFx battery2 delivers a capacity exceeding the theoretical maximum of CFx with a solid electrolyte of Li3PS4 (LPS) that has dual functions: as the inert electrolyte at the anode and the active component at the cathode. Such a bi-functional electrolyte reconciles both inert and active characteristics through a synergistic discharge mechanism of CFx and LPS. Li3PS4 is known as an inactive solid electrolyte with a broad electrochemical window over 5 V.3 The synergy at the cathode is through LiF, the discharge product of CFx, which activates the electrochemical discharge of LPS at a close electrochemical potential of CFx. Therefore, the solid-state Li-CFx batteries output 126.6% energy beyond their theoretic limits without compromising the stability of the cell voltage. The extra energy comes from the electrochemical discharge of LPS, the inert electrolyte. This bi-functional electrolyte revolutionizes the concept of conventional batteries and opens a new avenue for the design of batteries with an unprecedentedly high energy density.

  17. Recycling universe

    E-Print Network [OSTI]

    Jaume Garriga; Alexander Vilenkin

    1997-07-26T23:59:59.000Z

    If the effective cosmological constant is non-zero, our observable universe may enter a stage of exponential expansion. In such case, regions of it may tunnel back to the false vacuum of an inflaton scalar field, and inflation with a high expansion rate may resume in those regions. An ``ideal'' eternal observer would then witness an infinite succession of cycles from false vacuum to true, and back. Within each cycle, the entire history of a hot universe would be replayed. If there were several minima of the inflaton potential, our ideal observer would visit each one of these minima with a frequency which depends on the shape of the potential. We generalize the formalism of stochastic inflation to analyze the global structure of the universe when this `recycling' process is taken into account.

  18. mRNA Transcript Abundance during Plant Growth and the Influence of Li+ Exposure

    SciTech Connect (OSTI)

    Duff, M. C. [Savannah River National Laboratory, Aiken, SC (United States); Kuhne, W. W. [Savannah River National Laboratory, Aiken, SC (United States); Halverson, N. [Savannah River National Laboratory, Aiken, SC (United States); Chang, C. -S. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Kitamura, E. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Hawthorn, L. [Georgia Regents University Cancer Center, Augusta, GA (United States). Integrated Genomics Core; Milliken, C. E. [Savannah River National Laboratory, Aiken, SC (United States); Caldwell, E. F. [Savannah River National Laboratory, Aiken, SC (United States); Stieve-Caldwell, E. [Savannah River National Laboratory, Aiken, SC (United States); Martinez, N. E. [Savannah River National Laboratory, Aiken, SC (United States); Colorado State University, Ft. Collins, CO (United States). Dept. of Environmental and Radiological Health Sciences; Stafford, C. [Savannah River National Laboratory, Aiken, SC (United States); Univ. of South Carolina Medical School, Columbia, SC (United States)

    2014-12-01T23:59:59.000Z

    Lithium (Li) toxicity in plants is, at a minimum, a function of Li+ concentration, exposure time, species and growth conditions. Most plant studies with Li+ focus on short-term acute exposures. This study examines short- and long-term effects of Li+ exposure in Arabidopsis with Li+ uptake studies and measured shoot mRNA transcript abundance levels in treated and control plants. Stress, pathogen-response and arabinogalactan protein genes were typically more up-regulated in older (chronic, low level) Li+-treatment plants and in the much younger plants from acute high-level exposures. The gene regulation behavior of high-level Li+ resembled prior studies due to its influence on: inositol synthesis, 1-aminocyclopropane-1-carboxylate synthases and membrane ion transport. In contrast, chronically-exposed plants had gene regulation responses that were indicative of pathogen, cold, and heavy-metal stress, cell wall degradation, ethylene production, signal transduction, and calcium-release modulation. Acute Li+ exposure phenocopies magnesium-deficiency symptoms and is associated with elevated expression of stress response genes that could lead to consumption of metabolic and transcriptional energy reserves and the dedication of more resources to cell development. In contrast, chronic Li+ exposure increases expression signal transduction genes. The identification of new Li+-sensitive genes and a gene-based “response plan” for acute and chronic Li+ exposure are delineated.

  19. University Partnerships

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrinceton Plasma Physics Lab UniqueFeet)UniversityUniversity

  20. Fusion of $^{6}$Li with $^{159}$Tb} at near barrier energies

    E-Print Network [OSTI]

    M. K. Pradhan; A. Mukherjee; P. Basu; A. Goswami; R. Kshetri; R. Palit; V. V. Parkar; M. Ray; Subinit Roy; P. Roy Chowdhury; M. Saha Sarkar; S. Santra

    2011-06-10T23:59:59.000Z

    Complete and incomplete fusion cross sections for $^{6}$Li+$^{159}$Tb have been measured at energies around the Coulomb barrier by the $\\gamma$-ray method. The measurements show that the complete fusion cross sections at above-barrier energies are suppressed by $\\sim$34% compared to the coupled channels calculations. A comparison of the complete fusion cross sections at above-barrier energies with the existing data of $^{11,10}$B+$^{159}$Tb and $^{7}$Li+$^{159}$Tb shows that the extent of suppression is correlated with the $\\alpha$-separation energies of the projectiles. It has been argued that the Dy isotopes produced in the reaction $^{6}$Li+$^{159}$Tb, at below-barrier energies are primarily due to the $d$-transfer to unbound states of $^{159}$Tb, while both transfer and incomplete fusion processes contribute at above-barrier energies.

  1. Electrochemical Behavior of Lithium in LiOH-H/sub 2/O-System Solutions

    SciTech Connect (OSTI)

    Demidov, A.I.; Gerasimenko, L.N.; Konstantinova, M.V.; Morachevskii, A.G.

    1985-04-10T23:59:59.000Z

    A study of the anodic behavior and corrosion of lithium in LiOH-H/sub 2/O-system solutions at 298 /SUP o/ K is made. Anodic potentiodynamic and galvanostatic polarization plots were taken with a P-5827M potentiostat and displayed on a PDP-4 flatbed X-Y recorder. The potentiodynamic polarization curves were taken at a scanning rate of 80 mV/sec where the data were almost reproducible. Ptentiodynamic polarization plots taken for solutions of various LiOH concentrations are shown. Corrosion of the lithium in the aqueous electrolyte was studied volumetrically. Data obtained on lithium corrosion in solutions of the LiOH-H/sub 2/O system confirm the postualte that a lithium hydroxide concentration of more than 4 m densifies passive film on the lithium electrode.

  2. The ARIES-RS power core -- Recent development in Li/V designs

    SciTech Connect (OSTI)

    Sze, D.K.; Billone, M.C.; Hua, T.Q. [and others

    1997-04-01T23:59:59.000Z

    The ARIES-RS fusion power plant design study is based on reversed-shear (RS) physics with a Li/V (lithium breeder and vanadium structure) blanket. The reversed-shear discharge has been documented in many large tokamak experiments. The plasma in the RS mode has a high beta, low current, and low current drive requirements. Therefore, it is an attractive physics regime for a fusion power plant. The blanket system based on a Li/V has high temperature operating capability, good tritium breeding, excellent high heat flux removal capability, long structural life time, low activation, low after heat and good safety characteristics. For these reasons, the ARIES-RS reactor study selected Li/V as the reference blanket. The combination of attractive physics and attractive blanket engineering is expected to result in a superior power plant design. This paper summarizes the power core design of the ARIES-RS power plant study.

  3. Fusion of {sup 6}Li with {sup 159}Tb at near-barrier energies

    SciTech Connect (OSTI)

    Pradhan, M. K.; Mukherjee, A.; Basu, P.; Goswami, A.; Kshetri, R.; Roy, Subinit; Chowdhury, P. Roy; Sarkar, M. Saha; Palit, R.; Parkar, V. V.; Santra, S.; Ray, M. [Nuclear Physics Division, Saha Institute of Nuclear Physics, 1/AF, Bidhan Nagar, Kolkata-700064 (India); Department of Nuclear and Atomic Physics, Tata Institute of Fundamental Research, Mumbai-400005 (India); Nuclear Physics Division, Bhabha Atomic Research Centre, Mumbai-400085 (India); Department of Physics, Behala College, Parnasree, Kolkata-700060 (India)

    2011-06-15T23:59:59.000Z

    Complete and incomplete fusion cross sections for {sup 6}Li + {sup 159}Tb have been measured at energies around the Coulomb barrier by the {gamma}-ray method. The measurements show that the complete fusion cross sections at above-barrier energies are suppressed by {approx}34% compared to coupled-channel calculations. A comparison of the complete fusion cross sections at above-barrier energies with the existing data for {sup 11,10}B + {sup 159}Tb and {sup 7}Li + {sup 159}Tb shows that the extent of suppression is correlated with the {alpha} separation energies of the projectiles. It has been argued that the Dy isotopes produced in the reaction {sup 6}Li + {sup 159}Tb at below-barrier energies are primarily due to the d transfer to unbound states of {sup 159}Tb, while both transfer and incomplete fusion processes contribute at above-barrier energies.

  4. Target structure independent $^7\\vec{Li}$ elastic scattering at low momentum transfers

    E-Print Network [OSTI]

    O. A. Momotyuk; N. Keeley; K. W. Kemper; B. T. Roeder; A. M. Crisp; W. Cluff; B. G. Schmidt; M. Wiedeking; F. Marechal; K. Rusek; S. Yu. Mezhevych; J. Liendo

    2006-08-08T23:59:59.000Z

    Analyzing powers and cross sections for the elastic scattering of polarized 7Li by targets of 6Li, 7Li and 12C are shown to depend only on the properties of the projectile for momentum transfers of less than 1.0 fm-1. The result of a detailed analysis of the experimental data within the framework of the coupled channels model with ground state reorientation and transitions to the excited states of the projectile and targets included in the coupling schemes are presented. This work suggests that nuclear properties of weakly-bound nuclei can be tested by elastic scattering experiments, independent of the target used, if data are acquired for momentum transfers less than ~1.0 fm-1.

  5. ATMOSPHERIC COMPOSITION OF WEAK G BAND STARS: CNO AND Li ABUNDANCES

    SciTech Connect (OSTI)

    Adamczak, Jens; Lambert, David L., E-mail: adamczak@astro.as.utexas.edu [McDonald Observatory, University of Texas, Austin, TX 78712 (United States)

    2013-03-10T23:59:59.000Z

    We determined the chemical composition of a large sample of weak G band stars-a rare class of G and K giants of intermediate mass with unusual abundances of C, N, and Li. We have observed 24 weak G band stars with the 2.7 m Harlan J. Smith Telescope at the McDonald Observatory and derived spectroscopic abundances for C, N, O, and Li, as well as for selected elements from Na-Eu. The results show that the atmospheres of weak G band stars are highly contaminated with CN-cycle products. The C underabundance is about a factor of 20 larger than for normal giants and the {sup 12}C/{sup 13}C ratio approaches the CN-cycle equilibrium value. In addition to the striking CN-cycle signature the strong N overabundance may indicate the presence of partially ON-cycled material in the atmospheres of the weak G band stars. The exact mechanism responsible for the transport of the elements to the surface has yet to be identified but could be induced by rapid rotation of the main sequence progenitors of the stars. The unusually high Li abundances in some of the stars are an indicator for Li production by the Cameron-Fowler mechanism. A quantitative prediction of a weak G band star's Li abundance is complicated by the strong temperature sensitivity of the mechanism and its participants. In addition to the unusual abundances of CN-cycle elements and Li, we find an overabundance of Na that is in accordance with the NeNa chain running in parallel with the CN cycle. Apart from these peculiarities, the element abundances in a weak G band star's atmosphere are consistent with those of normal giants.

  6. Detailed Hydrographic Feature Extraction from High-Resolution LiDAR Data

    SciTech Connect (OSTI)

    Danny L. Anderson

    2012-05-01T23:59:59.000Z

    Detailed hydrographic feature extraction from high-resolution light detection and ranging (LiDAR) data is investigated. Methods for quantitatively evaluating and comparing such extractions are presented, including the use of sinuosity and longitudinal root-mean-square-error (LRMSE). These metrics are then used to quantitatively compare stream networks in two studies. The first study examines the effect of raster cell size on watershed boundaries and stream networks delineated from LiDAR-derived digital elevation models (DEMs). The study confirmed that, with the greatly increased resolution of LiDAR data, smaller cell sizes generally yielded better stream network delineations, based on sinuosity and LRMSE. The second study demonstrates a new method of delineating a stream directly from LiDAR point clouds, without the intermediate step of deriving a DEM. Direct use of LiDAR point clouds could improve efficiency and accuracy of hydrographic feature extractions. The direct delineation method developed herein and termed “mDn”, is an extension of the D8 method that has been used for several decades with gridded raster data. The method divides the region around a starting point into sectors, using the LiDAR data points within each sector to determine an average slope, and selecting the sector with the greatest downward slope to determine the direction of flow. An mDn delineation was compared with a traditional grid-based delineation, using TauDEM, and other readily available, common stream data sets. Although, the TauDEM delineation yielded a sinuosity that more closely matches the reference, the mDn delineation yielded a sinuosity that was higher than either the TauDEM method or the existing published stream delineations. Furthermore, stream delineation using the mDn method yielded the smallest LRMSE.

  7. University Archives University of Missouri at Columbia

    E-Print Network [OSTI]

    Taylor, Jerry

    University Archives University of Missouri at Columbia 703 Lewis Hall Columbia, Missouri 65211 of Missouri at Columbia, may be loaned out to University personnel. All items on loan will be listed below on loan from the University Archives, University of Missouri at Columbia. He/She further acknowledges full

  8. University of Maryland University Health Center

    E-Print Network [OSTI]

    Milchberg, Howard

    special care is taken, should the extracts be lost or damaged, the University Health Center cannot assumeUniversity of Maryland University Health Center ALLERGY INJECTION POLICY The University Health to effectively use our service, we require your cooperation. INSTRUCTIONS Because the University Health Center

  9. UNIVERSITY SPACE POLICY ALLOCATION OF UNIVERSITY SPACE

    E-Print Network [OSTI]

    UNIVERSITY COLLEGE DUBLIN UNIVERSITY SPACE POLICY #12;ALLOCATION OF UNIVERSITY SPACE I Purpose To provide a methodology for the allocation of space across the University II Background Due to the university's success in attracting research funding, the need for space and facilities has grown

  10. Self-limiting lithiation of electrode nanoparticles in Li-ion batteries

    SciTech Connect (OSTI)

    Drozdov, A. D., E-mail: add@teknologisk.dk [Center for Plastics Technology, Danish Technological Institute, Gregersensvej 7, Taastrup 2630 (Denmark); Department of Mechanical and Manufacturing Engineering, Aalborg University, Fibigerstraede 16, Aalborg 9220 (Denmark); Sommer-Larsen, P. [Center for Plastics Technology, Danish Technological Institute, Gregersensvej 7, Taastrup 2630 (Denmark); Claville Christiansen, J. de [Department of Mechanical and Manufacturing Engineering, Aalborg University, Fibigerstraede 16, Aalborg 9220 (Denmark)

    2013-12-14T23:59:59.000Z

    A model is derived for the viscoplastic behavior of a host medium driven by stress-induced diffusion of guest atoms. The constitutive equations are applied to study development of stresses in a spherical electrode particle subjected to insertion of lithium. Numerical simulation demonstrates the ability of the model to capture basic phenomena observed in anode nanoparticles under lithiation: formation of a sharp interphase between a Li-poor core and a Li-rich shell, slowing down of the interphase motion revealed as self-limiting lithiation, and growth of tensile hoop stresses near the outer surface of a particle leading to its fracture.

  11. {sup 7}Li NMR study of poly(p-phenylene) electrochemically doped with lithium

    SciTech Connect (OSTI)

    Shteinberg, V.G.; Shumm, B.A.; Zueva, A.F. [Institute of Chemical Physics, Moscow (Russian Federation)] [and others

    1994-09-01T23:59:59.000Z

    Lithium ions in electrochemically doped poly(p-phenylene) (PPP) were studied by {sup 7}Li NMR. Two types of lithium cations exhibiting different mobility are found to exist. The fraction of more mobile cations increases with temperature but does not exceed 0.5. In the PPP{sup -}-Li{sup +} system, ion mobility is considerably lower than that found in the previously studied PPP{sup +}-AsF{sub 6}{sup -} (BF{sub 4}{sup -}) system, and up to 400 K no chemical reactions of polymer destruction occur.

  12. Ab initio calculations of the electronic structure of silicon nanocrystals doped with shallow donors (Li, P)

    SciTech Connect (OSTI)

    Kurova, N. V., E-mail: kurova_natasha@mail.ru; Burdov, V. A. [Lobachevskii Nizhni Novgorod State University (Russian Federation)

    2013-12-15T23:59:59.000Z

    The results of ab initio calculations of the electronic structure of Si nanocrystals doped with shallow donors (Li, P) are reported. It is shown that phosphorus introduces much more significant distortions into the electronic structure of the nanocrystal than lithium, which is due to the stronger central cell potential of the phosphorus ion. It is found that the Li-induced splitting of the ground state in the conduction band of the nanocrystal into the singlet, doublet, and triplet retains its inverse structure typical for bulk silicon.

  13. Report for in-situ 7Li NMR experiment in PNNL Phase -1

    SciTech Connect (OSTI)

    Hu, Jian Zhi [Pacific Northwest National Laboratory

    2014-08-19T23:59:59.000Z

    To understand the detailed local structural evolution, an in-situ 7Li NMR study was performed. An operando identification of the lithium germanide phases under various cycling regimens permitted understanding of the kinetics of phase transition between different structural phases, including the amorphous phases, and how these correlated with capacity retention. Combining data from TEM and in-situ 7Li NMR, we discovered that the phase inter-conversion during cycling was mediated by co-existing amorphous and crystalline phases, and that the high capacity observed was correlated with an over-lithiated lithium germanide phase.

  14. Passivation of Aluminum in Lithium-ion Battery Electrolytes withLiBOB

    SciTech Connect (OSTI)

    Zhang, Xueyuan; Devine, Thomas M.

    2006-09-09T23:59:59.000Z

    A combination of cyclic polarization tests, electrochemical impedance spectroscopy, and electrochemical quartz crystal microbalance (EQCM) measurements indicate a film is formed when aluminum is polarized above 4.5V in 1:1 EC+DMC with 1M LiBOB. The quantity of film that is formed increases with increasing applied potential. Results of EQCM tests suggest the film is AlBO{sub 3}. The film is very protective against corrosion and inhibits pitting corrosion of aluminum in normally corrosive 1M LiTFSI.

  15. Surface treated natural graphite as anode material for high-power Li-ion battery applications.

    SciTech Connect (OSTI)

    Liu, J.; Vissers, D. R.; Amine, K.; Barsukov, I. V.; Henry, F.; Doniger, J.; Chemical Engineering; Superior Graphite Co.

    2006-01-01T23:59:59.000Z

    High power application of Li-ion battery in hybrid electrical vehicles requires low cost and safe cell materials. Among the various carbon anode materials used in lithium ion batteries, natural graphite shows the most promise with advantages in performance and cost. However, natural graphite is not compatible with propylene carbonate (PC)-based electrolytes, which have a lower melting point and improved safety characteristics. The problem with it is that the molecules of propylene carbonate intercalate with Li+ into graphite, and that frequently leads to the exfoliation of the graphite matrix.

  16. Effect of flame-retarding additives on surface chemistry in Li-ion batteries

    SciTech Connect (OSTI)

    Nam, N.D.; Park, I.J. [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of)] [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kim, J.G., E-mail: kimjg@skku.ac.kr [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kim, H.S. [Battery Research Group, Korea Electrotechnology Research Institute, Changwon 641-120 (Korea, Republic of)] [Battery Research Group, Korea Electrotechnology Research Institute, Changwon 641-120 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    This study examined the properties of 1 wt.% vinylene carbonate (VC), vinyl ethylene carbonate (VEC), and diphenyl octyl phosphate (DPOF) additive electrolytes as a promising way of beneficially improving the surface and cell resistance of Li-ion batteries. Surface film formation on the negative and positive electrodes was analyzed by electrochemical impedance spectroscopy (EIS), Fourier transform infrared (FT-IR) spectroscopy, and scanning electron microscopy (SEM). In conclusion, EIS, FT-IR spectroscopy and SEM results confirmed that DPOF is an excellent additive to the electrolyte in the Li-ion batteries due to the improved co-intercalation of the solvent molecules.

  17. Particle-size and morphology dependence of the preferred interface orientation in LiFePO4 nano-

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Particle-size and morphology dependence of the preferred interface orientation in LiFePO4 nano insights into the equilibrium properties and potential two-phase lithiation mechanisms in LiFePO4 nano, if experimentally-relevant nano-particles were to (de)lithiate under a thermodynamic two-phase mechanism

  18. Controlled Nanoparticle Metal Phosphates (Metal = Al, Fe, Ce, and Sr) Coatings on LiCoO2 Cathode Materials

    E-Print Network [OSTI]

    Cho, Jaephil

    Controlled Nanoparticle Metal Phosphates (Metal = Al, Fe, Ce, and Sr) Coatings on LiCoO2 Cathode and annealing temperature are used for MPO4 nanoparticle coatings M = Al, Fe, Ce, and SrH on a LiCoO2 cathode, the extent of the coating coverage is influenced by the nanoparticle size or morphology. Nanoparticles AlPO4

  19. Tunable blue light source by intracavity frequency doubling of a Cr-LiSrAIF6 laser

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Tunable blue light source by intracavity frequency doubling of a Cr- LiSrAIF6 laser Franqois-switched operation at 10 kHz was intracavity frequency doubled by using a LiIOl crystal. The 230 ns tunable blue lasers emitting in the blue-green wavelength range are expected to be the key components for optical

  20. Highly Reversible Li-Ion Intercalating MoP2 Nanoparticle Cluster Anode for Lithium Rechargeable Batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Highly Reversible Li-Ion Intercalating MoP2 Nanoparticle Cluster Anode for Lithium Rechargeable nanoparticle clusters have quite reversible lithium-ion insertion and extraction, showing the first discharge lithium reactions, i MPn LixMPn simple Li-ion interca- lation and ii MPn M LixM + LixP alloying followed

  1. A synthesis of LiFePO{sub 4} starting from FePO{sub 4} under reducing atmosphere

    SciTech Connect (OSTI)

    Prosini, Pier Paolo [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome, Italy and DInESto, Drive the Innovation in Energy Storage, Via Provin (Italy); Cento, Cinzia; Masci, Amedeo; Carewska, Maria; Gislon, Paola [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome (Italy)

    2014-06-19T23:59:59.000Z

    A fast and easy way to produce LiFePO{sub 4} starting from FePO{sub 4}, used as iron and phosphorus source, is proposed. 5% hydrogen is employed as a reducing agent and various compounds containing lithium as lithiation agents. The selected lithiation agents included: LiCl, CH{sub 3}COOLi, LiOH, Li{sub 2}S, LiH, and Li{sub 2}CO{sub 3}. Solid state synthesis is used for the LiFePO{sub 4} preparation and the so obtained materials are structurally characterized by XRD. The materials are used to fabricate composite electrode and their specific capacity is evaluated by low rate galvanostatic charge/discharge cycles (C/10 rate). Among the various lithium salts, the acetate give rise to the LiFePO{sub 4} with the best electrochemical performance. The morphology of this material is further investigated by SEM microscopy and the specific capacity is evaluated as a function of the discharge rate and the cycle number.

  2. Functional Analysis of Cardiac MR Images using SPHARM Heng Huanga, Li Shenb, James Forda, Fillia Makedona, Rong Zhangc

    E-Print Network [OSTI]

    Huang, Heng

    Functional Analysis of Cardiac MR Images using SPHARM Modeling Heng Huanga, Li Shenb, James Forda relationship with stages of disease. At the same time, Further author information: (Send correspondence to Heng Huang) Heng Huang: E-mail: hh@cs.dartmouth.edu, Telephone: 1 603 646 1694 Li Shen: lshen

  3. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and ultrahigh power lithium-ion batteries. Simply AlF3-treated Li4Ti5O12 composite anode materials for stable and...

  4. Figure 1. Schematic drawing showing the components of a Li-ion battery cell and the information that can be

    E-Print Network [OSTI]

    Figure 1. Schematic drawing showing the components of a Li-ion battery cell and the information Proposals In Situ Electron Microscopy and Spectroscopy Studies of Interfaces in Advanced Li-ion Batteries Under Dynamic Operation Conditions Project start date: Spring 2008 EMSL Lead Investigator: Chongmin Wang

  5. MODELING LIQUID METAL CORROSION IN A FERRITIC STEEL PbLi SYSTEM WITH AND WITHOUT A MAGNETIC FIELD

    E-Print Network [OSTI]

    Abdou, Mohamed

    MODELING LIQUID METAL CORROSION IN A FERRITIC STEEL ­ PbLi SYSTEM WITH AND WITHOUT A MAGNETIC FIELD associated with corrosion of ferritic steel in the flowing eutectic alloy lead-lithium (PbLi). New computer to perform more analysis and comparisons against available experimental data on corrosion in various flow

  6. Applied Surface Science 266 (2013) 516 Interphase chemistry of Si electrodes used as anodes in Li-ion batteries

    E-Print Network [OSTI]

    Boyer, Edmond

    2013-01-01T23:59:59.000Z

    to the lithiation of graphite, which also contributes to the increase of the energy density of the battery. Among in Li-ion batteries Catarina Pereira-Nabaisa,b , Jolanta S´wiatowskaa, , Alexandre Chagnesb, , Franc made to increase the energy density of lithium-ion batteries (LiB), namely for electric vehicle

  7. MAS NMR Study of the Metastable Solid Solutions Found in the LiFePO4/FePO4 System

    E-Print Network [OSTI]

    Cabana, Jordi

    2010-01-01T23:59:59.000Z

    compared to the lithium-electron interaction in x Li FeP04 (by Fermi contact interactions between the lithium ions andlithium ions in LiFePC^ suggests a modification of the Fe -O-P interaction.

  8. Study of MHD Corrosion and Transport of Corrosion Products of Ferritic/Martensitic Steels in the Flowing PbLi and its Application to Fusion Blanket

    E-Print Network [OSTI]

    Saeidi, Sheida

    2014-01-01T23:59:59.000Z

    components of a liquid breeder blanket of a fusion powerPb-17Li breeder first wall and blanket concept developmentPb-17Li breeder first wall and blanket concept development

  9. In-situ X-ray absorption spectroscopy analysis of capacity fade in nanoscale-LiCoO{sub 2}

    SciTech Connect (OSTI)

    Patridge, Christopher J. [NRC/NRL Cooperative Research Associate, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Love, Corey T., E-mail: corey.love@nrl.navy.mil [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Swider-Lyons, Karen E. [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Twigg, Mark E. [Electronics Science and Technology Division, Code 6812, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Ramaker, David E. [Chemistry Division, Code 6189, U.S. Naval Research laboratory, Washington, DC 20375 (United States)

    2013-07-15T23:59:59.000Z

    The local structure of nanoscale (?10–40 nm) LiCoO{sub 2} is monitored during electrochemical cycling utilizing in-situ X-ray absorption spectroscopy (XAS). The high surface area of the LiCoO{sub 2} nanoparticles not only enhances capacity fade, but also provides a large signal from the particle surface relative to the bulk. Changes in the nanoscale LiCoO{sub 2} metal-oxide bond lengths, structural disorder, and chemical state are tracked during cycling by adapting the delta mu (??) technique in complement with comprehensive extended X-ray absorption fine structure (EXAFS) modeling. For the first time, we use a ?? EXAFS method, and by comparison of the difference EXAFS spectra, extrapolate significant coordination changes and reduction of cobalt species with cycling. This combined approach suggests Li–Co site exchange at the surface of the nanoscale LiCoO{sub 2} as a likely factor in the capacity fade and irreversible losses in practical, microscale LiCoO{sub 2}. - Graphical abstract: Electrochemical cycling of Li-ion batteries has strong impact on the structure and integrity of the cathode active material particularly near the surface/electrolyte interface. In developing a new method, we have used in-situ X-ray absorption spectroscopy during electrochemical cycling of nanoscale LiCoO{sub 2} to track changes during charge and discharge and between subsequent cycles. Using difference spectra, several small changes in Co-O bond length, Co-O and Co-Co coordination, and site exchange between Co and Li sites can be tracked. These methods show promise as a new technique to better understand processes which lead to capacity fade and loss in Li-ion batteries. - Highlights: • A new method is developed to understand capacity fade in Li-ion battery cathodes. • Structural changes are tracked during Li intercalation/deintercalation of LiCoO{sub 2}. • Surface structural changes are emphasized using nanoscale-LiCoO{sub 2} and difference spectra. • Full multiple scattering calculations are used to support ?? analysis.

  10. University Faculty Awareness and Attitudes towards Open Access Publishing and the Institutional Repository: A Case Study

    E-Print Network [OSTI]

    Yang, Zheng Ye; Li, Yu

    2015-05-06T23:59:59.000Z

    mentioned by faculty, such as OA publishing and repository services, copyright, data management, a seminar on how to most effectively make their research available to others, and a workshop on tools for data deposit for OA. Some faculty expressed...Journal of Librarianship and Scholarly Communication Volume 3 | Issue 1 eP1210 University Faculty Awareness and Attitudes towards Open Access Publishing and the Institutional Repository: A Case Study Zheng Y. Yang, Yu Li © 2015 by the author...

  11. Spin-waves in antiferromagnetic single-crystal LiFePO4 Jiying Li,* Vasile O. Garlea, Jerel L. Zarestky, and David Vaknin

    E-Print Network [OSTI]

    Vakni, David

    -wave theory by including in the spin Hamiltonian in-plane nearest- and next-nearest-neighbor interactions J1 and J2 , inter-plane nearest-neighbor interactions J and a single-ion anisotropy D . A weak 0 number s : 75.25. z, 75.30.Ds, 75.50.Ee I. INTRODUCTION Lithium-orthophosphates LiMPO4 M=Mn,Fe,Co,Ni have

  12. Ab initio structure search and in situ 7Li NMR studies of discharge products in the Li-S battery system

    E-Print Network [OSTI]

    See, Kimberly A.; Leskes, Michal; Griffin, John M.; Britto, Sylvia; Matthews, Peter D.; Emly, Alexandra; Van der Ven, Anton; Wright, Dominic S.; Morris, Andrew J.; Grey, Clare P.; Seshadri, Ram

    2014-11-10T23:59:59.000Z

    of discharge and most of the intermediate polysulfides are retained inside the cathode matrix.8 Lowe et al. also used in situ XRD and coupled it with absorption spectroscopy to show that a limited number of polysulfide intermediates are involved... to correctly describe the system, which includes the activity of the solvent. However, the suggested discharge profile for a pure solid-state cathode (Figure 1c) could explain the mechanisms observed for Li?S batteries that utilize ceramic and even polymer...

  13. Biased interface between solid ion conductor LiBH{sub 4} and lithium metal: A first principles molecular dynamics study

    SciTech Connect (OSTI)

    Ikeshoji, Tamio [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan) [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan); Ando, Yasunobu; Otani, Minoru; Tsuchida, Eiji [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan)] [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 2, 1-1-1 Umezono, Tsukuba 305-8568 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan)] [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan) [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Sendai 980-8577 (Japan)

    2013-09-23T23:59:59.000Z

    We use first-principles molecular dynamics to study the electrochemical solid-solid interface between lithium metal and lithium electrolyte LiBH{sub 4}. An external bias is applied by using an effective screening medium. We observe large polarization in the LiBH{sub 4}, because the lithium cations in LiBH{sub 4} are shifted more on one side of the double-well potential of Li{sup +}. This results in a large potential drop in the interface region and a large double-layer capacity corresponding to ca. 70 ?F/cm{sup 2}. H-coordination to the Li atoms plays an important role in the charge-transfer reaction and ion transfer.

  14. Three-phase model for the reversible lithiation/delithiation of SnO anodes in Li-ion batteries

    E-Print Network [OSTI]

    Pedersen, Andreas; Luisier, Mathieu

    2015-01-01T23:59:59.000Z

    Using first-principles calculations, we propose a microscopic model to explain the reversible lithiation/delithiation of tin-oxide anodes in lithium-ion batteries. When the irreversible regime ends, the anode grains consist of layers of Li-oxide separated by Sn bilayers. During the following reversible lithiation, the Li-oxide undergoes two phase transformations that give rise to a Li-enrichment of the oxide and the formation of a SnLi composite. The anode grain structure stays layered and ordered with an effective theoretical reversible capacity of 4.5 Li per Sn atom. The predicted anode volume expansion and voltage profile agree well with experiments, contrary to existing models.

  15. Correlation between biaxial stress and free exciton transition in AlN B. N. Pantha, N. Nepal, T. M. Al Tahtamouni, M. L. Nakarmi, J. Li,

    E-Print Network [OSTI]

    Jiang, Hongxing

    . Nepal, T. M. Al Tahtamouni, M. L. Nakarmi, J. Li, J. Y. Lin, and H. X. Jianga Department of Physics

  16. Effect of fuel rate and annealing process of LiFePO{sub 4} cathode material for Li-ion batteries synthesized by flame spray pyrolysis method

    SciTech Connect (OSTI)

    Halim, Abdul; Setyawan, Heru; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng [Chemical Engineering, Sepuluh Nopember Institute of Technology, Kampus Sukolilo Surabaya Indonesia 60111 (Indonesia)

    2014-02-24T23:59:59.000Z

    In this study the effect of fuel rate and annealing on particle formation of LiFePO{sub 4} as battery cathode using flame spray pyrolysis method was investigated numerically and experimentally. Numerical study was done using ANSYS FLUENT program. In experimentally, LiFePO{sub 4} was synthesized from inorganic aqueous solution followed by annealing. LPG was used as fuel and air was used as oxidizer and carrier gas. Annealing process attempted in inert atmosphere at 700°C for 240 min. Numerical result showed that the increase of fuel rate caused the increase of flame temperature. Microscopic observation using Scanning Electron Microscopy (SEM) revealed that all particles have sphere and polydisperse. Increasing fuel rate caused decreasing particle size and increasing particles crystallinity. This phenomenon attributed to the flame temperature. However, all produced particles still have more amorphous phase. Therefore, annealing needed to increase particles crystallinity. Fourier Transform Infrared (FTIR) analysis showed that all particles have PO4 function group. Increasing fuel rate led to the increase of infrared spectrum absorption corresponding to the increase of particles crystallinity. This result indicated that phosphate group vibrated easily in crystalline phase. From Electrochemical Impedance Spectroscopy (EIS) analysis, annealing can cause the increase of Li{sup +} diffusivity. The diffusivity coefficient of without and with annealing particles were 6.84399×10{sup ?10} and 8.59888×10{sup ?10} cm{sup 2} s{sup ?1}, respectively.

  17. UNIVERSITY OF ABERDEEN UNIVERSITY COURT

    E-Print Network [OSTI]

    Levi, Ran

    of catering and residential services. Any proposals on the future direction of the company would be received that there remained a considerable number of areas within the University that depended on the future success had been scrutinised by the Audit Committee, and forwarded by the Joint Planning Finance & Estates

  18. Electrochimica Acta 50 (2005) 41824187 Control of AlPO4-nanoparticle coating on LiCoO2 by using

    E-Print Network [OSTI]

    Cho, Jaephil

    2005-01-01T23:59:59.000Z

    Electrochimica Acta 50 (2005) 4182­4187 Control of AlPO4-nanoparticle coating on LiCoO2 by using of the AlPO4 nanoparticle-coated LiCoO2 with ethanol showed an enhanced thermal stability. © 2005 Elsevier Ltd. All rights reserved. Keywords: AlPO4 nanoparticle; Coating; Crystallinity; Co dissolution; Li

  19. Challenges in synthesizing carbon-coated LiFePO4 nanoparticles from hydrous FePO4 and their electrochemical properties

    E-Print Network [OSTI]

    Park, Byungwoo

    Challenges in synthesizing carbon-coated LiFePO4 nanoparticles from hydrous FePO4 properties A B S T R A C T Carbon-coated LiFePO4 nanoparticles are obtained from a polymer-coated hydrous Fe polymer additives which are subsequently carbonized by calcination [14­19]. Carbon-coated LiFePO4

  20. Li/Ca, B/Ca, and Mg/Ca Composition of Cultured Sea Urchin Spines and Paleo-Echinoderms Measured Using a Secondary Ion Mass Spectrometer

    E-Print Network [OSTI]

    Nguyen, Trung Timothy Do

    2013-01-01T23:59:59.000Z

    Li/Ca was normalized to HTP-CC standard, B/Ca was normalizednormalized to calcites (CAL-HTP and UCI) for Li and Mg and aintensity ratios of Li/Ca (CAL-HTP), B/Ca (M93), and Mg/Ca (

  1. Open University

    ScienceCinema (OSTI)

    None

    2011-04-25T23:59:59.000Z

    Michel Pentz est née en Afrique du Sud et venu au Cern en 1957 comme physicien et président de l'associaion du personnel. Il est également fondateur du mouvement Antiapartheid de Genève et a participé à la fondation de l'Open University en Grande-Bretagne. Il nous parle des contextes pédagogiques, culturels et nationaux dans lesquels la méthode peut s'appliquer.

  2. Engineering Recently, we created the first Li-ion electrochemical cell

    E-Print Network [OSTI]

    characterization of Li-ion battery materials. In this presentation, I'll first review our latest progress of using-ion battery anodes. In the future, we will need further advancements in in-situ characterization nanotubes, and graphene. Several electrochemical mechanisms were observed and characterized in real

  3. Maps preserving the joint numerical radius distance of operators Chi-Kwong Li

    E-Print Network [OSTI]

    Li, Chi-Kwong

    Maps preserving the joint numerical radius distance of operators Chi-Kwong Li and Edward Poon Dedicated to Professor David Lutzer on the occasion of his retirement. Abstract Denote the joint numerical radius of an m-tuple of bounded operators A = (A1, . . . , Am) by w(A). We give a complete description

  4. Degradation of Li/S Battery Electrodes Studied Using X-ray Phase Contrast Tomography

    E-Print Network [OSTI]

    Schmidt, Volker

    in lithium-ion battery systems. This technology is thus drawing attention from academic and industrial researchers intensively studied rechargeable lithium-ion batteries, since the energy demand of electric1 Degradation of Li/S Battery Electrodes Studied Using X-ray Phase Contrast Tomography L. Zielkea

  5. Millikelvin cooling of an optically trapped microsphere Tongcang Li, Simon Kheifets, and Mark G. Raizen

    E-Print Network [OSTI]

    Raizen, Mark G.

    of macroscopic observables. In recent years, great progress has been made in cooling micromechanical resonators detection system24 was not sufficient to enable feedback cooling. According to the equipartition theorem1 Millikelvin cooling of an optically trapped microsphere in vacuum Tongcang Li, Simon Kheifets

  6. Improved estimates of forest vegetation structure and biomass with a LiDAR-optimized sampling design

    E-Print Network [OSTI]

    Radeloff, Volker C.

    and Spies, 1992; Jakubauskas and Price, 1997], and forest biomass [Fassnacht et al., 1997; Gower et alImproved estimates of forest vegetation structure and biomass with a LiDAR-optimized sampling, to estimate forest structure and biomass across a 53,600 ha study area in northeastern Wisconsin. Additionally

  7. Results from Infrared Spectral Observation of 1991 Total Solar Eclipse Hui Li and Jianqi You

    E-Print Network [OSTI]

    Li, Hui

    et al. 1992; Deming et al. 1992; Sime and Streete 1993). The solar eclipse observation team of ChinaResults from Infrared Spectral Observation of 1991 Total Solar Eclipse Hui Li and Jianqi You Purple Mountain Observatory, CAS, Nanjing 210008, P. R. China Abstract. We describe in this paper the data

  8. REVERSIBLE HYDROGEN STORAGE IN A LiBH{sub 4}-C{sub 60} NANOCOMPOSITE

    SciTech Connect (OSTI)

    Teprovich, J.; Zidan, R.; Peters, B.; Wheeler, J.

    2013-08-06T23:59:59.000Z

    Reversible hydrogen storage in a LiBH{sub 4}:C{sub 60} nanocomposite (70:30 wt. %) synthesized by solvent-assisted mixing has been demonstrated. During the solvent-assisted mixing and nanocomposite formation, a chemical reaction occurs in which the C{sub 60} cages are significantly modified by polymerization as well as by hydrogenation (fullerane formation) in the presence of LiBH{sub 4}. We have determined that two distinct hydrogen desorption events are observed upon rehydrogenation of the material, which are attributed to the reversible formation of a fullerane (C{sub 60}H{sub x}) as well as a LiBH4 species. This system is unique in that the carbon species (C{sub 60}) actively participates in the hydrogen storage process which differs from the common practice of melt infiltration of high surface area carbon materials with LiBH{sub 4} (nanoconfinment effect). This nanocomposite demonstrated good reversible hydrogen storage properties as well as the ability to absorb hydrogen under mild conditions (pressures as low as 10 bar H{sub 2} or temperatures as low as 150?C). The nanocomposite was characterized by TGA-RGA, DSC, XRD, LDI-TOF-MS, FTIR, 1H NMR, and APPI MS.

  9. Feedforward Control of a Piezoelectric Flexure Stage for AFM Yang Li and John Bechhoefer

    E-Print Network [OSTI]

    Bechhoefer, John

    to physics [1], [2]; by the publication, by control engineers, of the first textbook on modern control theory of an interesting "cross-over" work that analyzes physical systems from a control perspective [4]. While influencesFeedforward Control of a Piezoelectric Flexure Stage for AFM Yang Li and John Bechhoefer Abstract

  10. Relative grain boundary area and energy distributions in nickel Jia Li, Shen J. Dillon 1

    E-Print Network [OSTI]

    Rohrer, Gregory S.

    Relative grain boundary area and energy distributions in nickel Jia Li, Shen J. Dillon 1 , Gregory boundary energies and areas are inversely correlated. Ó 2009 Acta Materialia Inc. Published by Elsevier Ltd and focused ion beam serial sectioning. These data have been used to determine the relative areas of different

  11. Mining Unexpected Sequential Patterns and Dong (Haoyuan) Li, Anne Laurent, Pascal Poncelet

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Mining Unexpected Sequential Patterns and Rules Dong (Haoyuan) Li, Anne Laurent, Pascal Poncelet November 14, 2007 Abstract Sequential pattern mining is the one most concentrated and applied in sequence mining research, it gives a frequency based view of the cor- relations between elements contained

  12. Molecular Adsorption to LiMo3Se3 Nanowire Film Chemiresistors

    E-Print Network [OSTI]

    Chiang, Shirley

    Molecular Adsorption to LiMo3Se3 Nanowire Film Chemiresistors Xiubin Qi, Frank E. Osterloh,*, S. A that the temporal and steady-state resistance changes of the films depend on the time following the adsorption and on the number of molecules that adsorb to the nanowire films at a given pressure. The adsorption ability

  13. A Control Theoretical Model for Quality of Service Adaptations Baochun Li, Klara Nahrstedt

    E-Print Network [OSTI]

    Li, Baochun

    A Control Theoretical Model for Quality of Service Adaptations Baochun Li, Klara Nahrstedt to adapt their behavior to the resource variations of the system. We propose a Task Control Model to rigorously model the dynamics of an adaptive system, using the digital control theory. With our Task Control

  14. A Control Theoretical Model for Quality of Service Adaptations Baochun Li, Klara Nahrstedt \\Lambda

    E-Print Network [OSTI]

    Nahrstedt, Klara

    A Control Theoretical Model for Quality of Service Adaptations Baochun Li, Klara Nahrstedt \\Lambda to adapt their behavior to the resource variations of the system. We propose a Task Control Model to rigorously model the dynamics of an adaptive system, using the digital control theory. With our Task Control

  15. Measuring design complexity of semantic web ontologies Hongyu Zhang a,*, Yuan-Fang Li b

    E-Print Network [OSTI]

    Li, Yuan-Fang

    of the ontology, therefore allowing them to better evaluate its design and control its development processMeasuring design complexity of semantic web ontologies Hongyu Zhang a,*, Yuan-Fang Li b , Hee Beng form 19 November 2009 Accepted 19 November 2009 Available online 1 December 2009 Index Terms: Design

  16. Method for improving voltage regulation of batteries, particularly Li/FeS.sub.2 thermal batteries

    DOE Patents [OSTI]

    Godshall, Ned A. (Albuquerque, NM)

    1988-01-01T23:59:59.000Z

    Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS.sub.2 system.

  17. A deeper respired carbon pool in the glacial equatorial Pacific Ocean L.I. Bradtmiller a,

    E-Print Network [OSTI]

    Sachs, Julian P.

    A deeper respired carbon pool in the glacial equatorial Pacific Ocean L.I. Bradtmiller a, , R in paleoceanography. We present evidence from ten equatorial Pacific Ocean sediment cores to show that the deep Pacific Ocean likely stored more carbon during the last glacial period than the Holocene

  18. A new communication paradigm for mobile TV over cellular network Dr. Hongxiang Li

    E-Print Network [OSTI]

    A new communication paradigm for mobile TV over cellular network Dr. Hongxiang Li Electrical terrestrial TV network and propose a new mobile TV communication paradigm that is radically different from and communication theory (i.e., Network Coding and Dirty Paper Coding) in the new mobile TV system design. Despite

  19. Method for improving voltage regulation of batteries, particularly Li/FeS/sub 2/ thermal batteries

    DOE Patents [OSTI]

    Godshall, N.A.

    1986-06-10T23:59:59.000Z

    Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS/sub 2/ system.

  20. A Measurement-Based Admission-Controlled Web Server Kelvin Li Sugih Jamin

    E-Print Network [OSTI]

    Jamin, Sugih

    A Measurement-Based Admission-Controlled Web Server Kelvin Li Sugih Jamin Electrical Engineering-2122 {nivlek, jamin}@eecs.umich.edu Abstract- Current HTTP servers process requests using a first come first serve queuing policy. What this implies is that the web server must process each request as it arrives

  1. Energy Impact of Secure Computation on a Handheld Device Zhiyuan Li

    E-Print Network [OSTI]

    Li, Zhiyuan

    Energy Impact of Secure Computation on a Handheld Device Zhiyuan Li Rong Xu Department of Computer is an important approach to save the energy consumption while improving perfor- mance for wireless networked security to the wireless network changes the relative cost of computation and commu- nication

  2. High-capacity Li2Sgraphene oxide composite cathodes with stable cycling performance

    E-Print Network [OSTI]

    Cui, Yi

    oxide onto the surface of Li2S through favorable lithium­oxygen interactions helps to minimize and grid energy storage applica- tions.1­6 Although rechargeable lithium-ion batteries are widely used-mentioned applications.1­6 The major limiting factor in lithium-ion batteries today is the low theoretical capacity

  3. FEATURE ARTICLE T.S. Zhao, Y.S. Li, S.Y. Shen

    E-Print Network [OSTI]

    Zhao, Tianshou

    FEATURE ARTICLE T.S. Zhao, Y.S. Li, S.Y. Shen Anion-exchange membrane direct ethanol fuel cells Direct ethanol fuel cells (DEFCs) are a promising carbon-neutral and sustainable power source strategies to overcome them. Keywords fuel cell, direct ethanol fuel cells, anion- exchange membrane, ethanol

  4. Control of a Mobile Modular Manipulator Moving on a Slope Yangmin Li, Yugang Liu

    E-Print Network [OSTI]

    Li, Yangmin

    Control of a Mobile Modular Manipulator Moving on a Slope Yangmin Li, Yugang Liu Department. An effective control method is applied to the ntobile mudular manipulator control in case of moving on a slope mobile basis and manipulator were studied in [I]. A hybrid control idea was presented for robot control

  5. Cooling output optimization of an air handling unit Andrew Kusiak *, Mingyang Li

    E-Print Network [OSTI]

    Kusiak, Andrew

    supply temperature and supply air temperature in response to the dynamic cooling load and changingCooling output optimization of an air handling unit Andrew Kusiak *, Mingyang Li Department mining Neural network Multi-objective optimization Evolutionary computation Dynamic modeling Cooling

  6. Energy Impact of Secure Computation on a Handheld Device # Zhiyuan Li + Rong Xu

    E-Print Network [OSTI]

    Li, Zhiyuan

    and mobile computing. Many architectural and software e#orts have been initiated to improve the energy eEnergy Impact of Secure Computation on a Handheld Device # Zhiyuan Li + Rong Xu Department#oading is an important approach to save the energy consumption while improving perfor­ mance for wireless networked

  7. ON THE APPLICATION OF LOAD RELAXATION IN CHARACTERIZING SUPERPLASTIC Al-Li 8090

    E-Print Network [OSTI]

    Garmestani, Hamid

    ON THE APPLICATION OF LOAD RELAXATION IN CHARACTERIZING SUPERPLASTIC Al-Li 8090 F. Booeshaghi and H is typically calculated as the slope of the log versus log curve where is the steady state flow stress test, and load relaxation tests. In this paper, the use of the load relaxation experiment to obtain

  8. Coupled displacive and orderdisorder dynamics in LiNbO3 by molecular-dynamics simulation

    E-Print Network [OSTI]

    Gopalan, Venkatraman

    .1063/1.1669063 Ferroelectric lithium niobate (LiNbO3) has emerged as an important material in surface acoustic wave devices1 the structure and properties of materials. Indeed, atomic-level simulations have been used previously-dynamics MD simulations described here we treat the Coulomb interactions using a direct summation method

  9. SEVERE PARTICULATE POLLUTION IN LANZHOU Peter C. Chu, Yuchun Chen*, Shihua Lu*, Zhenchao Li*, Yaqiong Lu**

    E-Print Network [OSTI]

    Chu, Peter C.

    SEVERE PARTICULATE POLLUTION IN LANZHOU CHINA Peter C. Chu, Yuchun Chen*, Shihua Lu*, Zhenchao Li and fall, but much worse in winter, reaching low to mid alert level of air pollution. Since 1999 increasing, and become major pollutants. The mean concentration of PM10 is 2.56 mg m-3 . Even in summer

  10. THIN FILM EPITAXY WITH OR WITHOUT SLOPE SELECTION BO LI AND JIAN-GUO LIU

    E-Print Network [OSTI]

    Soatto, Stefano

    THIN FILM EPITAXY WITH OR WITHOUT SLOPE SELECTION BO LI AND JIAN-GUO LIU Abstract. Two nonlinear diffusion equations for thin film epitaxy, with or without slope se- lection, are studied in this work = - · h 1 + | h|2 + h (1.1) and th = - · 1 - | h|2 h + h (1.2) that model epitaxial growth of thin films

  11. Modular Dual Coolant Pb-17Li Blanket Design For ARIES-CS Compact Stellarator Power Plant

    E-Print Network [OSTI]

    Raffray, A. René

    of the study. The preferred blanket concept is a dual coolant blanket with a He- cooled ferritic steel firstModular Dual Coolant Pb-17Li Blanket Design For ARIES-CS Compact Stellarator Power Plant X.R. Wanga from the engineering effort during the second phase of ARIES-CS study on the conceptual design

  12. A novel solid-state self powered neutron detector Nicholas LiCausi*a

    E-Print Network [OSTI]

    Danon, Yaron

    A novel solid-state self powered neutron detector Nicholas LiCausi*a , Justin Dingleyb , Yaron procedures. Keywords: Neutron detector, thermal neutrons, solid-state detector, DRIE, computer simulations 1 source and could be entirely self-powered. With no moving parts it would be robust and work in a variety

  13. A NEWTON METHOD FOR AMERICAN OPTION PRICING THOMAS F. COLEMAN, YUYING LI, AND ARUN VERMA

    E-Print Network [OSTI]

    Li, Yuying

    in the American option valuation. We illustrate that the proposed method on aver- age solves a discretized problem curve. American option valuation has been an active research area; many methods have been proposedA NEWTON METHOD FOR AMERICAN OPTION PRICING THOMAS F. COLEMAN, YUYING LI, AND ARUN VERMA December

  14. Short-Term Generation Asset Valuation Chung-Li Tseng, Graydon Barz

    E-Print Network [OSTI]

    Short-Term Generation Asset Valuation Chung-Li Tseng, Graydon Barz Department of Civil Engineering 94305, USA chungli@eng.umd.edu, gbarz@leland.stanford.edu Abstract In this paper we present a method for valuing a power plant over a short-term period using Monte Carlo sim- ulation. The power plant valuation

  15. PID Admittance Control for an Upper Limb Exoskeleton Wen Yu, Jacob Rosen, Xiaoou Li

    E-Print Network [OSTI]

    Rosen, Jacob

    PID Admittance Control for an Upper Limb Exoskeleton Wen Yu, Jacob Rosen, Xiaoou Li Abstract PID control. Three force sensors in the upper-level send desired trajectories to the lower, a model-free PID type admittance control is applied, whose parameters can be designed by human impedance

  16. Image distortion in thermoacoustic tomography caused by microwave diffraction Changhui Li,* Manojit Pramanik,

    E-Print Network [OSTI]

    Wang, Lihong

    Image distortion in thermoacoustic tomography caused by microwave diffraction Changhui Li,* Manojit-induced thermoacoustic tomography. The distortion, due to microwave diffraction in the object to be imaged, leads Thermoacoustic TA tomography TAT in biological tis- sue reconstructs the TA source distribution from the acoustic

  17. Fourier Law in the Alternate-Mass Hard-Core Potential Chain Baowen Li,1

    E-Print Network [OSTI]

    Li, Baowen

    Fourier Law in the Alternate-Mass Hard-Core Potential Chain Baowen Li,1 Giulio Casati,2,3,1 Jiao size. We provide convincing numerical evidence for the validity of Fourier law of heat conduction in order to obey the Fourier law of heat conduction are still not known. For noninteracting particles

  18. Blood-flow magnetic resonance imaging of the retina Yingxia Li,a,1

    E-Print Network [OSTI]

    Duong, Timothy Q.

    Blood-flow magnetic resonance imaging of the retina Yingxia Li,a,1 Haiying Cheng,a,1 and Timothy Q 1 November 2007 This study describes a novel MRI application to image basal blood flow, physiologically induced blood-flow changes, and the effects of isoflurane concentration on blood flow

  19. Infrared Imaging Solar Spectrograph at Purple Mountain Observatory Hui Li , Zhongyu Fan and Jianqi You

    E-Print Network [OSTI]

    Li, Hui

    Infrared Imaging Solar Spectrograph at Purple Mountain Observatory Hui Li , Zhongyu Fan and Jianqi, Chinese Academy of Sciences Abstract. Since 1986, we have made some improvements to the multichannel solar to it a multichannel infrared imaging solar spectrograph. The original spectrograph can be used to observe

  20. Chemical weathering of granitic rock: experiments and Pb-Li isotopes tracing Romain Millot

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    is to better constrain the processes of water/rock interactions both in terms of source (dissolutionChemical weathering of granitic rock: experiments and Pb-Li isotopes tracing Romain Millot Philippe of weathering. In order to go further and to better characterize water/rock interactions, we performed

  1. Solid State NMR Studies of Li-Rich NMC Cathodes: Investigating...

    Broader source: Energy.gov (indexed) [DOE]

    in dQdV plots center of mass of Li shifts in NMR spectra shift to lower frequencies. 2.0 2.5 3.0 3.5 4.0 4.5 dQdV Voltage NMR11 Cycle 2 NMR14 Cycle 11 NMR 14 NMR 11 NMR 15...

  2. Phonon-like excitation in secondary and tertiary structure of hydrated protein Mingda Li,a

    E-Print Network [OSTI]

    Chen, Sow-Hsin

    Phonon-like excitation in secondary and tertiary structure of hydrated protein powders Mingda Li dispersion relations and their damping in two hydrated proteins, a-chymotrypsinogen A and casein, differing transition temperature TD: hydrated proteins are conformationally flexible and enzymatically active above TD

  3. Prediction of the AL index using solar wind Xinlin Li,1,2,5

    E-Print Network [OSTI]

    Li, Xinlin

    Prediction of the AL index using solar wind parameters Xinlin Li,1,2,5 Kap Soo Oh,1,3 and M. [1] Two empirical models, one simple, one more complex, are introduced to predict the AL index are based on solar wind and magnetometer data from the year 1995. The simple model predicts the 10-min

  4. The study of threshold behaviour of effective potential for $^{6}$Li+$^{58,64}$Ni systems

    E-Print Network [OSTI]

    M. Biswas; Subinit Roy; M. Sinha; M. K. Pradhan; A. Mukherjee; P. Basu; H. Majumdar; K. Ramachandran; A. Shrivastava

    2008-01-30T23:59:59.000Z

    The elastic scattering for $^6$Li+$^{64}$Ni system was measured in the bombarding energy range of 13 MeV $\\leq$ $E_{lab}$ $\\leq$ 26 MeV. A phenomenological optical model analysis was performed and the behaviour of the surface strengths of the potential components with decreasing energy was extracted. A further analysis of the measured angular distributions, along with the existing data for $^6$Li+$^{58}$Ni, was performed with two different model potentials - one with the folded potential normalized with a complex factor (OMP1) and the other with a {\\it hybrid} potential composed of a renormalized folded real and a phenomenological imaginary (OMP2) potential components - were used in the calculation. All the model potentials predict similar energy dependent behaviour for the interaction potential around the barrier. The observed energy dependence of the strengths of the real and imaginary potentials corroborate with the dispersion relation prediction for both the $^6$Li+$^{64}$Ni and $^6$Li+$^{58}$Ni systems. Though the evidence of breakup is distinct in the energy variation of the potential strengths, close to the barrier the variation is more in the line of conventional threshold anomaly. Also the threshold behaviour of the interaction potential does not indicate any distinct isotopic dependence.

  5. ENERGY EFFICIENT TURBO BASED SPACE-TIMECODER YumingZhu, Laura Li and ChaitaliChakrabarti

    E-Print Network [OSTI]

    Kambhampati, Subbarao

    ENERGY EFFICIENT TURBO BASED SPACE-TIMECODER YumingZhu, Laura Li and ChaitaliChakrabarti Department that Space-Time code is an effective approach to increasing the data rate over wireless channels. Turbo of the Turbo codes. In this paper, we compare two Turbo-based Space-Time Codes and their approximate versions

  6. Dynamic control of wind turbines Andrew Kusiak*, Wenyan Li, Zhe Song

    E-Print Network [OSTI]

    Kusiak, Andrew

    Dynamic control of wind turbines Andrew Kusiak*, Wenyan Li, Zhe Song Department of Mechanical Keywords: Wind turbine Wind energy Data mining Model predictive control Evolutionary computation algorithm Control strategy optimization a b s t r a c t The paper presents an intelligent wind turbine control

  7. Virtual Shelves: Interactions with Orientation Aware Devices Frank Chun Yat Li, David Dearman & Khai N. Truong

    E-Print Network [OSTI]

    Toronto, University of

    Virtual Shelves: Interactions with Orientation Aware Devices Frank Chun Yat Li, David Dearman mobile situations when eyes-free interactions may be preferable. We present Virtual Shelves, a technique. With Virtual Shelves, the user triggers shortcuts by orienting a spatially-aware mobile device within

  8. Structure and Dynamics of Colliding Plasma Jets C. K. Li,1,* D. D. Ryutov,2

    E-Print Network [OSTI]

    Structure and Dynamics of Colliding Plasma Jets C. K. Li,1,* D. D. Ryutov,2 S. X. Hu,3 M. J at various angles shed light on the structures and dynamics of these collisions. The observations compare noncollinear jets, the observed flow structure is similar to the analytic model's prediction of a character

  9. Nanoparticle iron-phosphate anode material for Li-ion battery Dongyeon Son

    E-Print Network [OSTI]

    Park, Byungwoo

    density.1 The graphite generally used in lithium rechargeable batteries has a capacity of 372 mNanoparticle iron-phosphate anode material for Li-ion battery Dongyeon Son School of Materials rechargeable batteries. The electrochemical properties of the nanoparticle iron phosphates were characterized

  10. Partial Encryption of Compressed Images and Videos \\Lambda Howard Cheng y and Xiaobo Li z

    E-Print Network [OSTI]

    Cheng, Howard

    Partial Encryption of Compressed Images and Videos \\Lambda Howard Cheng y and Xiaobo Li z, if not impossible, to carry out real­time secure image and video communication and processing. Methods have been of the compressed data. Partial encryption is applied to several image and video compression algorithms

  11. Nonlinear Control Via PDC: The TORA System Example Hua Wang and Jing Li

    E-Print Network [OSTI]

    Nonlinear Control Via PDC: The TORA System Example Hua Wang and Jing Li Dept. of Electrical the stabilty of the system. The PDC controller design is to derive each control rule for each linear model­S model, we can analyze or design the PDC controller. In this paper, our main focus is on a nonlinear

  12. Frequent Pattern Mining for Kernel Trace Data Christopher LaRosa, Li Xiong, Ken Mandelberg

    E-Print Network [OSTI]

    Xiong, Li

    , application programmers, operating systems engineers, and security analysts. In the systems area, data miningFrequent Pattern Mining for Kernel Trace Data Christopher LaRosa, Li Xiong, Ken Mandelberg patterns and other recurring runtime execution patterns in operating system trace logs, we employ data

  13. Mining Logs Files for Computing System Management Wei Peng, Tao Li

    E-Print Network [OSTI]

    Li, Tao

    reporting, asynchronous data collection, and temporal characteristics in data representation. FirstMining Logs Files for Computing System Management Wei Peng, Tao Li School of Computer Science experts through a knowledge acquisition process to translate domain knowl- edge into operating rules

  14. On Trade-Wind Cumulus Cold Pools Paquita Zuidema & Zhujun Li

    E-Print Network [OSTI]

    Zuidema, Paquita

    On Trade-Wind Cumulus Cold Pools Paquita Zuidema & Zhujun Li Reg Hill, Ludovic Bariteau, Bob - but precipitation ~ mm/day not mm/hr and no wind shear stratocumulus `squall-line' Jensen et al. 2008 tropical deep rainrate `undisturbed' `disturbed' sensible/latent Tuesday, December 6, 2011 #12;`gust' winds faster than

  15. R i l P tf li M d lRegional Portfolio Model Software Redevelopment

    E-Print Network [OSTI]

    R i l P tf li M d lRegional Portfolio Model Software Redevelopment Request for Proposals #12;II. Services Desired by the CouncilII. Services Desired by the Council Software redevelopment of the Council's Regional Software redevelopment of the Council s Regional Portfolio Model (RPM) Redeveloped

  16. Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4

    E-Print Network [OSTI]

    Cui, Yi

    nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials energy storage devices for portable electronic devices, power tools, and electrical vehicles.1-4 Anodes applied to battery researches. This work represents the first example of single nanostructure device

  17. Electrochemical properties of magnesium doped LiFePO{sub 4} cathode material prepared by sol–gel method

    SciTech Connect (OSTI)

    Zhao, Xiaohui; Baek, Dong-Ho; Manuel, James; Heo, Min-Yeong; Yang, Rong [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)] [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of); Ha, Jong Keun; Ryu, Ho-Suk; Ahn, Hyo-Jun; Kim, Ki-Won [Department of Metallurgical Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)] [Department of Metallurgical Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of); Cho, Kwon-Koo, E-mail: kkcho66@gnu.ac.kr [Department of Metallurgical Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)] [Department of Metallurgical Science and Engineering, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of); Ahn, Jou-Hyeon, E-mail: jhahn@gnu.ac.kr [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)] [Department of Chemical and Biological Engineering and Research Institute for Green Energy Convergence Technology, Gyeongsang National University, 900, Gajwa-dong, Jinju 600-701 (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    Magnesium doped Li{sub 1?2x}Mg{sub x}FePO{sub 4}/C (x = 0.00, 0.01, 0.03, 0.05) cathode materials were synthesized by sol–gel method, and the effect of magnesium doping as well as its content on the electrochemical properties for lithium batteries was also investigated{sub .} Their morphology was studied with field emission scanning electron microscope and Li{sub 1?2x}Mg{sub x}FePO{sub 4} materials showed the olivine phase without impurities. The thin carbon layer of Li{sub 1?2x}Mg{sub x}FePO{sub 4}/C was confirmed by high resolution transmission electron microscopy. The magnesium doped Li{sub 1?2x}Mg{sub x}FePO{sub 4}/C particles were smaller than those undoped. The Li{sub 1?2x}Mg{sub x}FePO{sub 4}/C materials showed better cycling behavior than undoped LiFePO{sub 4}, especially at high C-rate in which Li{sub 0.94}Mg{sub 0.03}FePO{sub 4}/C composition exhibited the best electrochemical properties.

  18. University Profile The University of Canterbury

    E-Print Network [OSTI]

    Hickman, Mark

    05 University Profile 2005-2007 #12;The University of Canterbury Te Whare Wnanga o Waitaha PROFILE Profile 2005-2007 Page 1 of 66 #12;University of Canterbury Profile 2005-2007 Page 2 of 66 #12;University of Canterbury PROFILE 2005-2007 Part A Overview of Strategic Direction and relationship to the Tertiary

  19. University Library AMSTERDAM UNIVERSITY LIBRARY USER REGULATIONS

    E-Print Network [OSTI]

    van Rooij, Robert

    University Library AMSTERDAM UNIVERSITY LIBRARY USER REGULATIONS Regulations for the users of the libraries of the University of Amsterdam General 1. The Amsterdam University Library (from hereon: the library) is understood to mean the whole body of faculty libraries and facilities of the Library

  20. Nanoscale imaging of fundamental Li battery chemistry: solid-electrolyte interphase formation and preferential growth of lithium metal nanoclusters

    SciTech Connect (OSTI)

    Sacci, Robert L [ORNL; Black, Jennifer M [ORNL; Wisinger, Nina [ORNL; Dudney, Nancy J. [Oak Ridge National Laboratory (ORNL); More, Karren Leslie [ORNL; Unocic, Raymond R [ORNL

    2015-01-01T23:59:59.000Z

    The performance characteristics of Li-ion batteries are intrinsically linked to evolving nanoscale interfacial electrochemical reactions. To probe the mechanisms of solid electrolyte interphase formation and Li electrodeposition from a standard battery electrolyte, we use in situ electrochemical scanning transmission electron microscopy for controlled potential sweep-hold electrochemical measurements with simultaneous BF and ADF STEM image acquisition. Through a combined quantitative electrochemical measurement and quantitative STEM imaging approach, based upon electron scattering theory, we show that chemically sensitive ADF STEM imaging can be used to estimate the density of evolving SEI constituents and distinguish contrast mechanisms of Li-bearing components in the liquid cell.