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  1. Earth System Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    earth system processes Earth System Processes Cosmogenic isotopes are rare isotopes created when a high-energy cosmic ray interacts with the nucleus of an atom, causing cosmic ray spallation. These isotopes are produced within earth materials such as rocks or soil, in Earth's atmosphere, and in extraterrestrial items such as meteorites. By measuring cosmogenic isotopes, scientists are able to gain insight into a range of geological and astronomical processes. Cosmogenic nuclides can provide a

  2. Earth System Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Earth System Observations Research comprises Earth, ocean, and atmospheric sciences to better understand and predict climate change's impact on ecosystems and to study subsurface geological materials and their interactions. Deploying research facilities globally Forecasting forests' responses to climate change Monitoring terrestrial ecosystems Contact Us Group Leader Claudia Mora Email Deputy Group Leader Bob Roback Email Profile pages header Search our Profile pages Investigating carbon

  3. Modeling the earth system

    SciTech Connect (OSTI)

    Ojima, D.

    1992-12-31

    The 1990 Global Change Institute (GCI) on Earth System Modeling is the third of a series organized by the Office for Interdisciplinary Earth Studies to look in depth at particular issues critical to developing a better understanding of the earth system. The 1990 GCI on Earth System Modeling was organized around three themes: defining critical gaps in the knowledge of the earth system, developing simplified working models, and validating comprehensive system models. This book is divided into three sections that reflect these themes. Each section begins with a set of background papers offering a brief tutorial on the subject, followed by working group reports developed during the institute. These reports summarize the joint ideas and recommendations of the participants and bring to bear the interdisciplinary perspective that imbued the institute. Since the conclusion of the 1990 Global Change Institute, research programs, nationally and internationally, have moved forward to implement a number of the recommendations made at the institute, and many of the participants have maintained collegial interactions to develop research projects addressing the needs identified during the two weeks in Snowmass.

  4. SciTech Connect: "earth system models"

    Office of Scientific and Technical Information (OSTI)

    earth system models" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "earth system models" Semantic Semantic Term Title: Full Text: Bibliographic...

  5. Electrochemistry of LiCl-Li2O-H2O Molten Salt Systems

    SciTech Connect (OSTI)

    Natalie J. Gese; Batric Pesic

    2013-03-01

    Uranium can be recovered from uranium oxide (UO2) spent fuel through the combination of the oxide reduction and electrorefining processes. During oxide reduction, the spent fuel is introduced to molten LiCl-Li2O salt at 650 degrees C and the UO2 is reduced to uranium metal via two routes: (1) electrochemically, and (2) chemically by lithium metal (Li0) that is produced electrochemically. However, the hygroscopic nature of both LiCl and Li2O leads to the formation of LiOH, contributing hydroxyl anions (OH-), the reduction of which interferes with the Li0 generation required for the chemical reduction of UO2. In order for the oxide reduction process to be an effective method for the treatment of uranium oxide fuel, the role of moisture in the LiCl-Li2O system must be understood. The behavior of moisture in the LiCl-Li2O molten salt system was studied using cyclic voltammetry, chronopotentiometry and chronoamperometry, while reduction to hydrogen was confirmed with gas chromatography.

  6. Modeling the Earth System, volume 3

    SciTech Connect (OSTI)

    Ojima, D.

    1992-01-01

    The topics covered fall under the following headings: critical gaps in the Earth system conceptual framework; development needs for simplified models; and validating Earth system models and their subcomponents.

  7. Earth Systems Science and Engineering

    SciTech Connect (OSTI)

    Rotman, D A

    2006-02-21

    Providing the essential energy and water systems to support human needs while understanding and addressing their environmental consequences is a watershed problem for the 21st century. The LLNL Earth System Science and Engineering Program seeks to provide the scientific understanding and technological expertise to help provide solutions at both global and regional scales. Our work is highly collaborative with universities, laboratories and industrial partners across the world and involves observational data, laboratory experiments, and numerical simulations. The energy systems we have enjoyed for the last 100 years have resulted in the advanced standard of living in the developed world and a major emerging problem with climate change. Now we face a simultaneous realization that our reliance on fossil fuels is a source of conflict and economic disruption as well as causing potentially abrupt, even catastrophic global climate change. The climate and energy problem is perhaps the greatest challenge ever faced by mankind. Fossil fuel remains the least expensive and most available source of energy and the basis of our economy. The use of fossil fuels, especially over the last 100 years has led to a 30% increase in CO{sub 2} in the atmosphere. The problem is growing. The population of the Earth will increase by several billion people in the next 50 years. If economic growth is to continue, the demand for energy is estimated to approximately double in the next 50 years so that we will need approximately 10 TW more energy than the 15 TW we use now. Much of this demand will come from the developing world where most of the population growth will occur and where advanced energy technology is not generally used. The problem affects and is affected by a complex system of systems. The climate and energy problem will affect resources, social structure and the probability of increased conflict. No one person, no one nation, no one technology can solve the problem. There is no

  8. A toolkit for building earth system models

    SciTech Connect (OSTI)

    Foster, I.

    1993-03-01

    An earth system model is a computer code designed to simulate the interrelated processes that determine the earth`s weather and climate, such as atmospheric circulation, atmospheric physics, atmospheric chemistry, oceanic circulation, and biosphere. I propose a toolkit that would support a modular, or object-oriented, approach to the implementation of such models.

  9. Predictive Materials Modeling for Li-Air Battery Systems | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Leadership Computing Facility Predictive Materials Modeling for Li-Air Battery Systems PI Name: Larry Curtiss PI Email: curtiss@anl.gov Institution: Argonne National Laboratory Allocation Program: INCITE Allocation Hours at ALCF: 50 Million Year: 2015 Research Domain: Materials Science A rechargeable lithium-air (Li-air) battery can potentially store five to ten times the energy of a lithium-ion (Li-ion) battery of the same weight. Realizing this enormous potential presents a challenging

  10. Re-evaluation of the eutectic region of the LiBr-KBr-LiF system

    SciTech Connect (OSTI)

    Redey, L.; Guidotti, R.A.

    1996-05-01

    The separator pellet in a thermal battery consists of electrolyte immobilized by a binder (typically, MgO powder). The melting point of the electrolyte determines the effective operating window for its use in a thermal battery. The development of a two-hour thermal battery required the use of a molten salt that had a lower melting point and larger liquidus range than the LiCl-KCl eutectic which melts at 352 C. Several candidate eutectic electrolyte systems were evaluated for their suitability for this application. One was the LiCl-LiBr-KBr eutectic used at Argonne National Laboratories for high-temperature rechargeable batteries for electric-vehicle applications. Using a custom-designed high-temperature conductivity cell, the authors were able to readily determine the liquidus region for the various compositions studied around the original eutectic for the LiBr-KBr-LiF system. The actual eutectic composition was found to be 60.0 m/o LiBr-37.5 m/o KBr-2.5 m/o LiF with a melting point of 324 {+-} 0.5 C.

  11. A toolkit for building earth system models

    SciTech Connect (OSTI)

    Foster, I.

    1993-03-01

    An earth system model is a computer code designed to simulate the interrelated processes that determine the earth's weather and climate, such as atmospheric circulation, atmospheric physics, atmospheric chemistry, oceanic circulation, and biosphere. I propose a toolkit that would support a modular, or object-oriented, approach to the implementation of such models.

  12. OSTIblog Articles in the earth systems modeling Topic | OSTI...

    Office of Scientific and Technical Information (OSTI)

    earth systems modeling Topic ACME - Perfecting Earth System Models by Kathy Chambers 29 Oct, 2014 in Earth system modeling as we know it and how it benefits climate change research ...

  13. A Scalable and Extensible Earth System Model for Climate Change...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: A Scalable and Extensible Earth System Model for Climate Change Science Citation Details In-Document Search Title: A Scalable and Extensible Earth System Model ...

  14. Climate, Earth system project draws on science powerhouses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate, Earth system project draws on science powerhouses Climate, Earth system project draws on science powerhouses The project will focus initially on three climate-change ...

  15. LI

    Office of Legacy Management (LM)

    \ LI g. / This document con&s of lf pages. No. 1 &of #copies, Series fl . .! ' \ ' > .b P .--r ' i ' ./' MJDIFICATION NO. k sUPPLEMENTALAMw24ENrto CONTRACT NO. A T (30-l)-1335 M O D IFICATION NO. 4 CONTRACTOR AND A D D m S : KIDIFICATION TO: -EINESTIEUTED CCSTOFWORKr TOTAT,ESTIIUTEDC~T OFWRKI INCREASEIN C O M K rSSI~ OBLlDATIONt NEMTOTALCOMMISSION OBLIOaTIONt PAYl%NTTDBEMADEBY: HORIZONS, INCORPOlZATED R-inceton, New Jersey AIBNDSCOPEOFK#tK,EXTENDTR?M AND OTflER CHANOES $&31,lbOO

  16. LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery

    DOE Patents [OSTI]

    Ko, Suk M.

    1980-01-01

    This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

  17. Atmosphere Component in Community Earth System Model

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atiq Warraich About Us Atiq Warraich - Technical Lead/Project Manager Atiq Warraich Most Recent Digital Strategy May

    Atmosphere Component in Community Earth System Model - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy

  18. A Reactive Force Field study of Li/C Systems for Electrical Energy...

    Office of Scientific and Technical Information (OSTI)

    A Reactive Force Field study of LiC Systems for Electrical Energy Storage Citation Details In-Document Search Title: A Reactive Force Field study of LiC Systems for Electrical ...

  19. The integrated Earth System Model Version 1: formulation and...

    Office of Scientific and Technical Information (OSTI)

    Title: The integrated Earth System Model Version 1: formulation and functionality The integrated Earth System Model (iESM) has been developed as a new tool for pro- jecting the ...

  20. 2013 Community Earth System Model (CESM) Tutorial-Proposal to...

    Office of Scientific and Technical Information (OSTI)

    3 Community Earth System Model (CESM) Tutorial-Proposal to DOE Citation Details In-Document Search Title: 2013 Community Earth System Model (CESM) Tutorial-Proposal to DOE THE SAME ...

  1. Microsoft Word - li_z.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Cloud Liquid Water Path and Its Potential for Rain Detection Z. Li, R. Chen, and F-L Chang Earth System Science Interdisciplinary Center, University of Maryland College Park,...

  2. Combined effect of chemical pressure and valence electron concentration through the electron-deficient Li substitution on the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system

    SciTech Connect (OSTI)

    Nam, Gnu; Jeon, Jieun; Kim, Youngjo; Kwon Kang, Sung; Ahn, Kyunghan; You, Tae-Soo

    2013-09-15

    Four members of the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system have been prepared by high-temperature reaction method and characterized by X-ray diffractions. All compounds crystallize in the orthorhombic Gd{sub 5}Si{sub 4}-type structure (space group Pnma, Pearson code oP16) with bonding interactions for interslab Ge{sub 2} dimers. The Li substitution for rare-earth elements in the RE{sub 4}LiGe{sub 4} system leads to a combined effect of the increased chemical pressure and the decreased valance electron concentration (VEC), which eventually results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type with all broken interslab Ge–Ge bond for the parental RE{sub 5}Ge{sub 4} to the Gd{sub 5}Si{sub 4}-type structure for the ternary RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. Site-preference between rare-earth metals and Li is proven to generate energetically the most favorable atomic arrangements according to coloring-problem, and the rationale is provided using both the size-factor and the electronic-factor related, respectively, to site-volume and electronegativity as well as QVAL values. Tight-binding, linear-muffin-tin-orbital (TB-LMTO) calculations are performed to investigate electronic densities of states (DOS) and crystal orbital Hamilton population (COHP) curves. The influence of reduced VEC for chemical bonding including the formation of interslab Ge{sub 2} dimers is also discussed. The magnetic property measurements prove that the non-magnetic Li substitution leads to the ferromagnetic (FM)-like ground state for Ce{sub 4}LiGe{sub 4} and the co-existence of antiferromagntic (AFM) and FM ground states for Sm{sub 4}LiGe{sub 4}. - Graphical abstract: Reported is a combined effect of the chemical pressure and the reduced VEC caused by the smaller monovalent non-magnetic Li substitution for the larger trivalent magnetic rare-earth metals in the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. This results in the structure

  3. DOE Science Showcase - Earth System Models | OSTI, US Dept of...

    Office of Scientific and Technical Information (OSTI)

    Earth System Models U.S. DOE Office of Science: Getting Forest Carbon Right in Climate ... agencies, particularly the National Science Foundation, the National Oceanic and ...

  4. 2012 Community Earth System Model (CESM) Tutorial - Proposal...

    Office of Scientific and Technical Information (OSTI)

    The Community Earth System Model (CESM) is a fully-coupled, global climate model that ... Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 54 ...

  5. The Community Earth System Model: A Framework for Collaborative...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: Community Earth System Model; global coupled model; atmosperic chemistry Word Cloud More Like ...

  6. A Scalable and Extensible Earth System Model for Climate Change...

    Office of Scientific and Technical Information (OSTI)

    Scalable and Extensible Earth System Model for Climate Change Science Gent, Peter; Lamarque, Jean-Francois; Conley, Andrew; Vertenstein, Mariana; Craig, Anthony 54 ENVIRONMENTAL...

  7. Modeling the Changing Earth System: Prospects and Challenges

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bill Collins Modeling the Changing Earth System: Prospects and Challenges February 4, 2014 Bill Collins, Berkeley Lab Downloads CollinSNERSCUG020514.pdf | Adobe Acrobat PDF file Modeling the Changing Earth System: Prospects and Challenges - William Collins, Berkeley Lab Last edited: 2016-04-29 11:35:09

  8. DOE SciDAC's Earth System Grid Center for Enabling Technologies...

    Office of Scientific and Technical Information (OSTI)

    of Southern California 96 KNOWLEDGE MANAGEMENT AND PRESERVATION Earth System Grid, data replication, system monitoring Earth System Grid, data replication, system monitoring...

  9. Possibility of creating weldable alloys on the basis of the system Al-Cu-Li

    SciTech Connect (OSTI)

    Fridlyander, I.N.; Drits, A.M.; Krymova, T.V.

    1992-03-01

    The weldability of alloys of the system Al-Cu-Li is studied and promising alloying ranges are established for weldable alloys: 5.5-6.5% Cu, 0.8-1.4% Li and 2.5-3.5% Cu, 1.9-2.5% Li. The positive effect of adding small amounts of scandium on the weldability and mechanical properties of alloys of the system Al-Cu-Li is demonstrated. Properties at normal and cryogenic temperatures are given for a new weldable alloy 1460. 7 refs., 6 figs., 2 tabs.

  10. Earth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enthusiastic employees: sustaining the Earth January 30, 2014 Green Teams work hard to make sustainable choices at home, at work The Lab has made many energy sustainable ...

  11. Performance of the Community Earth System Model | Argonne Leadership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility Performance of the Community Earth System Model Authors: Worley, P.H., Craig, A., Dennis, J., Mirin, A.A., Taylor, M.A., Vertenstein, M. The Community Earth System Model (CESM), released in June 2010, incorporates new physical process and new numerical algorithm options, significantly enhancing simulation capabilities over its predecessor, the June 2004 release of the Community Climate System Model. CESM also includes enhanced performance tuning options and performance

  12. Collaborative Project. Mode and Intermediate Waters in Earth System Models

    SciTech Connect (OSTI)

    Sarmiento, Jorge L.; Dufour, Carolina; Rodgers, Keith B.

    2015-12-16

    The focus of this grant was on diagnosing the physical mechanisms controlling upper ocean water mass formation and carbon distribution in Earth System Models (ESMs), with the goal of improving the physics that controls their formation.

  13. Climate, Earth system project draws on science powerhouses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate, Earth system project draws on science powerhouses Climate, Earth system project draws on science powerhouses The project will focus initially on three climate-change science drivers and corresponding questions to be answered during the project's initial phase. September 25, 2014 Computer modeling provides policymakers with essential information on such data as global sea surface temperatures related to specific currents. Computer modeling provides policymakers with essential information

  14. Climate, Earth system project draws on science powerhouses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate, Earth system project draws on science powerhouses Alumni Link: Opportunities, News and Resources for Former Employees Latest Issue:September 2015 all issues All Issues » submit Climate, Earth system project draws on science powerhouses The project will focus initially on three climate-change science drivers and corresponding questions to be answered during the project's initial phase. November 1, 2014 Computer modeling provides policymakers with essential information on such data as

  15. Predictive Materials Modeling for Li-Air Battery Systems | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Leadership Computing Facility electron density obtained from a density functional theory Shown here is the electron density obtained from a density functional theory (DFT) calculation of lithium oxide (Li2O) performed with the GPAW code. This visualization was the result of a simulation run on Intrepid, a supercomputer at the Argonne Leadership Computing Facility. Kah Chun Lau, Aaron Knoll and Larry A. Curtiss, Argonne National Laboratory Predictive Materials Modeling for Li-Air Battery

  16. A reactive force field study of Li/C systems for electrical energy storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Raju, Muralikrishna; Ganesh, P.; Kent, Paul R. C.; van Duin, Adri C.T.

    2015-04-02

    Graphitic carbon is still the most ubiquitously used anode material in Li-ion batteries. In spite of its ubiquity, there are few theoretical studies that fully capture the energetics and kinetics of Li in graphite and related nanostructures at experimentally relevant length, time-scales, and Li-ion concentrations. In this paper, we describe the development and application of a ReaxFF reactive force field to describe Li interactions in perfect and defective carbon-based materials using atomistic simulations. We develop force field parameters for Li–C systems using van der Waals-corrected density functional theory (DFT). Grand canonical Monte Carlo simulations of Li intercalation in perfect graphitemore » with this new force field not only give a voltage profile in good agreement with known experimental and DFT results but also capture the in-plane Li ordering and interlayer separations for stage I and II compounds. In defective graphite, the ratio of Li/C (i.e., the capacitance increases and voltage shifts) both in proportion to the concentration of vacancy defects and metallic lithium is observed to explain the lithium plating seen in recent experiments. We also demonstrate the robustness of the force field by simulating model carbon nanostructures (i.e., both 0D and 1D structures) that can be potentially used as battery electrode materials. Whereas a 0D defective onion-like carbon facilitates fast charging/discharging rates by surface Li adsorption, a 1D defect-free carbon nanorod requires a critical density of Li for intercalation to occur at the edges. Our force field approach opens the opportunity for studying energetics and kinetics of perfect and defective Li/C structures containing thousands of atoms as a function of intercalation. As a result, this is a key step toward modeling of realistic carbon materials for energy applications.« less

  17. A reactive force field study of Li/C systems for electrical energy storage

    SciTech Connect (OSTI)

    Raju, Muralikrishna; Ganesh, P.; Kent, Paul R. C.; van Duin, Adri C.T.

    2015-04-02

    Graphitic carbon is still the most ubiquitously used anode material in Li-ion batteries. In spite of its ubiquity, there are few theoretical studies that fully capture the energetics and kinetics of Li in graphite and related nanostructures at experimentally relevant length, time-scales, and Li-ion concentrations. In this paper, we describe the development and application of a ReaxFF reactive force field to describe Li interactions in perfect and defective carbon-based materials using atomistic simulations. We develop force field parameters for Li–C systems using van der Waals-corrected density functional theory (DFT). Grand canonical Monte Carlo simulations of Li intercalation in perfect graphite with this new force field not only give a voltage profile in good agreement with known experimental and DFT results but also capture the in-plane Li ordering and interlayer separations for stage I and II compounds. In defective graphite, the ratio of Li/C (i.e., the capacitance increases and voltage shifts) both in proportion to the concentration of vacancy defects and metallic lithium is observed to explain the lithium plating seen in recent experiments. We also demonstrate the robustness of the force field by simulating model carbon nanostructures (i.e., both 0D and 1D structures) that can be potentially used as battery electrode materials. Whereas a 0D defective onion-like carbon facilitates fast charging/discharging rates by surface Li adsorption, a 1D defect-free carbon nanorod requires a critical density of Li for intercalation to occur at the edges. Our force field approach opens the opportunity for studying energetics and kinetics of perfect and defective Li/C structures containing thousands of atoms as a function of intercalation. As a result, this is a key step toward modeling of realistic carbon materials for energy applications.

  18. Predictive Materials Modeling for Li-Air Battery Systems | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Leadership Computing Facility The electron density obtained from a density functional theory (DFT) calculation of lithium oxide performed with the GPAW code Shown here is the electron density obtained from a density functional theory (DFT) calculation of lithium oxide (Li2O) performed with the GPAW code. This visualization was the result of a simulation run on Intrepid, a supercomputer at the Argonne Leadership Computing Facility. Kah Chun Lau, Aaron Knoll and Larry A. Curtiss, Argonne

  19. Investigation of Mechanical Activation on Li-N-H Systems Using 6Li Magic Angle Spinning Nuclear Magnetic Resonance at Ultra-High Field

    SciTech Connect (OSTI)

    Hu, Jian Zhi; Kwak, Ja Hun; Yang, Zhenguo; Osborn, William; Markmaitree, Tippawan; Shaw, Leonard D.

    2008-07-15

    Abstract The significantly enhanced spectral resolution in the 6Li MAS NMR spectra of Li-N-H systems at ultra-high field of 21.1 tesla is exploited, for the first time, to study the detailed electronic and chemical environmental changes associated with mechanical activation of Li-N-H system using high energy balling milling. Complementary to ultra-high field studies, the hydrogen discharge dynamics are investigated using variable temperature in situ 1H MAS NMR at 7.05 tesla field. The significantly enhanced spectral resolution using ultra-high filed of 21.1 tesla was demonstrated along with several major findings related to mechanical activation, including the upfield shift of the resonances in 6Li MAS spectra induced by ball milling, more efficient mechanical activation with ball milling at liquid nitrogen temperature than with ball milling at room temperature, and greatly enhanced hydrogen discharge exhibited by the liquid nitrogen ball milled samples.

  20. First-Principles Study of Novel Conversion Reactions for High-Capacity Li-Ion Battery Anodes in the Li-Mg-B-N-H System

    SciTech Connect (OSTI)

    Mason, T.H.; Graetz, J.; Liu, X.; Hong, J.; Majzoub, E.H.

    2011-07-28

    Anodes for Li-ion batteries are primarily carbon-based due to their low cost and long cycle life. However, improvements to the Li capacity of carbon anodes, LiC{sub 6} in particular, are necessary to obtain a larger energy density. State-of-the-art light-metal hydrides for hydrogen storage applications often contain Li and involve reactions requiring Li transport, and light-metal ionic hydrides are candidates for novel conversion materials. Given a set of known solid-state and gas-phase reactants, we have determined the phase diagram in the Li-Mg-B-N-H system in the grand canonical ensemble, as a function of lithium chemical potential. We present computational results for several new conversion reactions with capacities between 2400 and 4000 mAh g{sup -1} that are thermodynamically favorable and that do not involve gas evolution. We provide experimental evidence for the reaction pathway on delithiation for the compound Li{sub 4}BN{sub 3}H{sub 10}. While the predicted reactions involve multiple steps, the maximum volume increase for these materials on lithium insertion is significantly smaller than that for Si.

  1. The integrated Earth System Model Version 1: formulation and functionality

    SciTech Connect (OSTI)

    Collins, William D.; Craig, Anthony P.; Truesdale, John E.; Di Vittorio, Alan; Jones, Andrew D.; Bond-Lamberty, Benjamin; Calvin, Katherine V.; Edmonds, James A.; Kim, Son H.; Thomson, Allison M.; Patel, Pralit L.; Zhou, Yuyu; Mao, Jiafu; Shi, Xiaoying; Thornton, Peter E.; Chini, Louise M.; Hurtt, George C.

    2015-07-23

    The integrated Earth System Model (iESM) has been developed as a new tool for pro- jecting the joint human/climate system. The iESM is based upon coupling an Integrated Assessment Model (IAM) and an Earth System Model (ESM) into a common modeling in- frastructure. IAMs are the primary tool for describing the human–Earth system, including the sources of global greenhouse gases (GHGs) and short-lived species, land use and land cover change, and other resource-related drivers of anthropogenic climate change. ESMs are the primary scientific tools for examining the physical, chemical, and biogeochemical impacts of human-induced changes to the climate system. The iESM project integrates the economic and human dimension modeling of an IAM and a fully coupled ESM within a sin- gle simulation system while maintaining the separability of each model if needed. Both IAM and ESM codes are developed and used by large communities and have been extensively applied in recent national and international climate assessments. By introducing heretofore- omitted feedbacks between natural and societal drivers, we can improve scientific under- standing of the human–Earth system dynamics. Potential applications include studies of the interactions and feedbacks leading to the timing, scale, and geographic distribution of emissions trajectories and other human influences, corresponding climate effects, and the subsequent impacts of a changing climate on human and natural systems. This paper de- scribes the formulation, requirements, implementation, testing, and resulting functionality of the first version of the iESM released to the global climate community.

  2. The integrated Earth system model version 1: formulation and functionality

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collins, W. D.; Craig, A. P.; Truesdale, J. E.; Di Vittorio, A. V.; Jones, A. D.; Bond-Lamberty, B.; Calvin, K. V.; Edmonds, J. A.; Kim, S. H.; Thomson, A. M.; et al

    2015-07-23

    The integrated Earth system model (iESM) has been developed as a new tool for projecting the joint human/climate system. The iESM is based upon coupling an integrated assessment model (IAM) and an Earth system model (ESM) into a common modeling infrastructure. IAMs are the primary tool for describing the human–Earth system, including the sources of global greenhouse gases (GHGs) and short-lived species (SLS), land use and land cover change (LULCC), and other resource-related drivers of anthropogenic climate change. ESMs are the primary scientific tools for examining the physical, chemical, and biogeochemical impacts of human-induced changes to the climate system. Themore » iESM project integrates the economic and human-dimension modeling of an IAM and a fully coupled ESM within a single simulation system while maintaining the separability of each model if needed. Both IAM and ESM codes are developed and used by large communities and have been extensively applied in recent national and international climate assessments. By introducing heretofore-omitted feedbacks between natural and societal drivers, we can improve scientific understanding of the human–Earth system dynamics. Potential applications include studies of the interactions and feedbacks leading to the timing, scale, and geographic distribution of emissions trajectories and other human influences, corresponding climate effects, and the subsequent impacts of a changing climate on human and natural systems. This paper describes the formulation, requirements, implementation, testing, and resulting functionality of the first version of the iESM released to the global climate community.« less

  3. Big Data Visual Analytics for Exploratory Earth System Simulation Analysis

    SciTech Connect (OSTI)

    Steed, Chad A.; Ricciuto, Daniel M.; Shipman, Galen M.; Smith, Brian E.; Thornton, Peter E.; Wang, Dali; Shi, Xiaoying; Williams, Dean N.

    2013-12-01

    Rapid increases in high performance computing are feeding the development of larger and more complex data sets in climate research, which sets the stage for so-called big data analysis challenges. However, conventional climate analysis techniques are inadequate in dealing with the complexities of today s data. In this paper, we describe and demonstrate a visual analytics system, called the Exploratory Data analysis ENvironment (EDEN), with specific application to the analysis of complex earth system simulation data sets. EDEN represents the type of interactive visual analysis tools that are necessary to transform data into insight, thereby improving critical comprehension of earth system processes. In addition to providing an overview of EDEN, we describe real-world studies using both point ensembles and global Community Land Model Version 4 (CLM4) simulations.

  4. The Brief History and Future Development of Earth System Models:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brief History and Future Development of Earth System Models: Resolution and Complexity Warren M. Washington National Center for Atmospheric Research NERSC Lecture Series at Berkeley Lab May, 2014 Overview * Brief history of climate modeling * Brief discussion of computational methods * Environmental Justice connected to climate change * Behind the scenes White House origin of the U. S. Global Change Research Program (USGCRP) * The future of the USGCRP and National Climate Assessment The next two

  5. FORTRAN M as a language for building earth system models

    SciTech Connect (OSTI)

    Foster, I.

    1992-01-01

    FORTRAN M is a small set of extensions to FORTRAN 77 that supports a modular or object-oriented approach to the development of parallel programs. In this paper, I discuss the use of FORTRAN M as a tool for building earth system models on massively parallel computers. I hypothesize that the use of FORTRAN M has software engineering advantages and outline experiments that we are conducting to investigate this hypothesis.

  6. FORTRAN M as a language for building earth system models

    SciTech Connect (OSTI)

    Foster, I.

    1992-12-31

    FORTRAN M is a small set of extensions to FORTRAN 77 that supports a modular or object-oriented approach to the development of parallel programs. In this paper, I discuss the use of FORTRAN M as a tool for building earth system models on massively parallel computers. I hypothesize that the use of FORTRAN M has software engineering advantages and outline experiments that we are conducting to investigate this hypothesis.

  7. Mode and Intermediate Waters in Earth System Models

    SciTech Connect (OSTI)

    Gnanadesikan, Anand; Sarmiento, Jorge L.

    2015-12-22

    This report describes work done as part of a joint Princeton-Johns Hopkins project to look at the impact of mode and intermediate waters in Earth System Models. The Johns Hopkins portion of this work focussed on the role of lateral mixing in ventilating such waters, with important implications for hypoxia, the uptake of anthropogenic carbon, the dynamics of El Nino and carbon pumps. The Johns Hopkins group also collaborated with the Princeton Group to help develop a watermass diagnostics framework.

  8. A Scalable and Extensible Earth System Model for Climate Change Science

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect A Scalable and Extensible Earth System Model for Climate Change Science Citation Details In-Document Search Title: A Scalable and Extensible Earth System Model for Climate Change Science The objective of this award was to build a scalable and extensible Earth System Model that can be used to study climate change science. That objective has been achieved with the public release of the Community Earth System Model, version 1 (CESM1). In particular, the

  9. OSTIblog Articles in the earth systems modeling Topic | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy Office of Scientific and Technical Information earth systems modeling Topic ACME - Perfecting Earth System Models by Kathy Chambers 29 Oct, 2014 in Earth system modeling as we know it and how it benefits climate change research is about to transform with the newly launched Accelerated Climate Modeling for Energy (ACME) project sponsored by the Earth System Modeling program within the Department of Energy's (DOE) Office of Biological and Environmental Research. ACME is an unprecedented

  10. Solid Solution Phases in the Olivine-Type LiMnPO4/MnPO4 System

    SciTech Connect (OSTI)

    Chen, Guoying; Richardson, Thomas J.

    2009-04-07

    Nonstoichiometry is reported in the LiMnPO{sub 4}/MnPO{sub 4} system for the first time. As lithium is removed from crystalline LiMnPO{sub 4} by chemical or electrochemical methods, the resulting two phase mixture consists of stoichiometric LiMnPO{sub 4} and a delithiated phase, Li{sub y}MnPO{sub 4}, whose lattice parameters depend upon the global extent of delithiation and on the crystalline domain size of the delithiated phase. This behavior is reproduced during electrochemical insertion of lithium. Again, no evidence for nonstoichiometry was found in the vicinity of LiMnPO{sub 4}. Attempts to create single phase solid solutions by heating mixtures of the two phases failed due to the thermal instability of Li{sub y}MnPO{sub 4}.

  11. Climate Model Datasets on Earth System Grid II (ESG II)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Earth System Grid (ESG) is a project that combines the power and capacity of supercomputers, sophisticated analysis servers, and datasets on the scale of petabytes. The goal is to provide a seamless distributed environment that allows scientists in many locations to work with large-scale data, perform climate change modeling and simulation,and share results in innovative ways. Though ESG is more about the computing environment than the data, still there are several catalogs of data available at the web site that can be browsed or search. Most of the datasets are restricted to registered users, but several are open to any access.

  12. Solar energy system case study: Telex Communications, Blue Earth, Minnesota

    SciTech Connect (OSTI)

    Raymond, M.G.

    1984-09-01

    A study is made of a solar energy system for space heating a 97,000-square-foot office, factory, and warehouse building owned by Telex Communications, Inc. in Blue Earth, Minnesota. The solar system has 11,520 square feet of ground-oriented flat-plate collectors and a 20,000-gallon storage tank inside the building. Freeze protection is by drainback. Solar heated water from the storage tank circulates around the clock throughout the heating season to heating coils in the ducts. The system achieves its design solar fraction, is efficient, and generally reliable, but not cost-effective. Performance data for the solar system was collected by the National Solar Data Network for three heating seasons from 1978 to 1981. Because of a freeze-up of the collector array in December 1978, the solar system was only partially operational in the 1978 to 1979 heating season. The data in this report were collected in the 1979 to 1980 and 1980 to 1981 heating seasons.

  13. Fail-Safe Design for Large Capacity Li-Ion Battery Systems - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Find More Like This Return to Search Fail-Safe Design for Large Capacity Li-Ion Battery Systems National Renewable Energy Laboratory Contact NREL About This Technology Publications: PDF Document Publication Fail Safe Design for Large Capacity Lithium-ion Batteries.pdf (2,324 KB) Technology Marketing Summary Lithium-ion batteries (LIBs) are a promising candidate for energy storage of electric drive vehicles due to their high power and energy density. The total electric

  14. Earth System Modeling (ESM) Program | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Earth System Modeling (ESM) Program Biological and Environmental Research (BER) BER Home About Research Biological Systems Science Division (BSSD) Climate and Environmental Sciences Division (CESD) ARM Climate Research Facility Atmospheric System Research (ASR) Program Data Management Earth System Modeling (ESM) Program William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) Integrated Assessment of Global Climate Change Regional & Global Climate Modeling (RGCM) Program

  15. Elastic scattering for the system {sup 6}Li+p at near barrier energies with MAGNEX

    SciTech Connect (OSTI)

    Soukeras, V.; Pakou, A.; Sgouros, O.; Cappuzzello, F.; Bondi, M.; Nicolosi, D.; Acosta, L.; Marquinez-Duran, G.; Martel, I.; Agodi, C.; Carbone, D.; Cavallaro, M.; Cunsolo, A.; Di Pietro, A.; Fernández-García, J. P.; Figuera, P.; Fisichella, M.; Alamanos, N.; De Napoli, M.; Foti, A.; and others

    2015-02-24

    Elastic scattering measurements have been performed for the {sup 6}Li+p system in inverse kinematics at the energies of 16, 20, 25 and 29 MeV. The heavy ejectile was detected by the large acceptance MAGNEX spectrometer at the Laboratori Nazionali del Sud (LNS) in Catania, in the angular range between ∼2{sup 0} and 12{sup 0} in the laboratory system, giving us the possibility to span almost a full angular range in the center of mass system. Results will be presented and discussed for one of the energies.

  16. DOE SciDAC's Earth System Grid Center for Enabling Technologies Final

    Office of Scientific and Technical Information (OSTI)

    Report for University of Southern California Information Sciences Institute (Technical Report) | SciTech Connect DOE SciDAC's Earth System Grid Center for Enabling Technologies Final Report for University of Southern California Information Sciences Institute Citation Details In-Document Search Title: DOE SciDAC's Earth System Grid Center for Enabling Technologies Final Report for University of Southern California Information Sciences Institute The mission of the Earth System Grid Federation

  17. Final Report for proposal "The Interface between Earth System Models and

    Office of Scientific and Technical Information (OSTI)

    Impacts on Society Workshop, Spring 2011 (Technical Report) | SciTech Connect Technical Report: Final Report for proposal "The Interface between Earth System Models and Impacts on Society Workshop, Spring 2011 Citation Details In-Document Search Title: Final Report for proposal "The Interface between Earth System Models and Impacts on Society Workshop, Spring 2011 The creation of a new Community Earth System Model (CESM) working group, combining science-driven research with

  18. DOE Science Showcase - Earth System Models | OSTI, US Dept of Energy Office

    Office of Scientific and Technical Information (OSTI)

    of Scientific and Technical Information Earth System Models U.S. DOE Office of Science: Getting Forest Carbon Right in Climate Models. "Boreal Forest" Image Credit: Wikimedia Commons, peupleloup. Optimizing emerging high-performance computing and information technologies, the Department of Energy's (DOE) Earth System Modeling (ESM) Program concentrates on advancing coupled climate and earth system models for climate change projections at global-to-regional spatial scales and

  19. BioEarth: Envisioning and developing a new regional earth system model to inform natural and agricultural resource management

    SciTech Connect (OSTI)

    Adam, J. C.; Stephens, J. C.; Chung, Serena; Brady, M. P.; Evans, R. D.; Kruger, C. E.; Lamb, Brian K.; Liu, M. L.; Stockle, Claudio O.; Vaughan, Joseph K.; Rajagopalan, K.; Harrison, John; Tague, C. L.; Kalyanaraman, Anantharaman; Chen, Yong; Guenther, Alex B.; Leung, F. Y.; Leung, Lai-Yung R.; Perleberg, A. B.; Yoder, J.; Allen, Elizabeth; Anderson, S.; Chandrasekharan, B.; Malek, K.; Mullis, T.; Miller, C.; Nergui, T.; Poinsatte, J.; Reyes, J.; Zhu, J.; Choate, J. S.; Jiang, X.; Nelson, R.; Yoon, Jin-Ho; Yorgey, G. G.; Johnson, Kristen; Chinnayakanhalli, K. J.; Hamlet, A. F.; Nijssen, B.; Walden, Von

    2015-04-01

    As managers of agricultural and natural resources are confronted with uncertainties in global change impacts, the complexities associated with the interconnected cycling of nitrogen, carbon, and water present daunting management challenges. Existing models provide detailed information on specific sub-systems (land, air, water, economics, etc). An increasing awareness of the unintended consequences of management decisions resulting from interconnectedness of these sub-systems, however, necessitates coupled regional earth system models (EaSMs). Decision makers needs and priorities can be integrated into the model design and development processes to enhance decision-making relevance and "usability" of EaSMs. BioEarth is a current research initiative with a focus on the U.S. Pacific Northwest region that explores the coupling of multiple stand-alone EaSMs to generate usable information for resource decision-making. Direct engagement between model developers and non-academic stakeholders involved in resource and environmental management decisions throughout the model development process is a critical component of this effort. BioEarth utilizes a "bottom-up" approach, upscaling a catchment-scale model to basin and regional scales, as opposed to the "top-down" approach of downscaling global models utilized by most other EaSM efforts. This paper describes the BioEarth initiative and highlights opportunities and challenges associated with coupling multiple stand-alone models to generate usable information for agricultural and natural resource decision-making.

  20. BioEarth: Envisioning and developing a new regional earth system model to inform natural and agricultural resource management

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adam, Jennifer C.; Stephens, Jennie C.; Chung, Serena H.; Brady, Michael P.; Evans, R. David; Kruger, Chad E.; Lamb, Brian K.; Liu, Mingliang; Stöckle, Claudio O.; Vaughan, Joseph K.; et al

    2014-04-24

    Uncertainties in global change impacts, the complexities associated with the interconnected cycling of nitrogen, carbon, and water present daunting management challenges. Existing models provide detailed information on specific sub-systems (e.g., land, air, water, and economics). An increasing awareness of the unintended consequences of management decisions resulting from interconnectedness of these sub-systems, however, necessitates coupled regional earth system models (EaSMs). Decision makers’ needs and priorities can be integrated into the model design and development processes to enhance decision-making relevance and “usability” of EaSMs. BioEarth is a research initiative currently under development with a focus on the U.S. Pacific Northwest region thatmore » explores the coupling of multiple stand-alone EaSMs to generate usable information for resource decision-making. Direct engagement between model developers and non-academic stakeholders involved in resource and environmental management decisions throughout the model development process is a critical component of this effort. BioEarth utilizes a bottom-up approach for its land surface model that preserves fine spatial-scale sensitivities and lateral hydrologic connectivity, which makes it unique among many regional EaSMs. Here, we describe the BioEarth initiative and highlights opportunities and challenges associated with coupling multiple stand-alone models to generate usable information for agricultural and natural resource decision-making.« less

  1. BioEarth: Envisioning and developing a new regional earth system model to inform natural and agricultural resource management

    SciTech Connect (OSTI)

    Adam, Jennifer C.; Stephens, Jennie C.; Chung, Serena H.; Brady, Michael P.; Evans, R. David; Kruger, Chad E.; Lamb, Brian K.; Liu, Mingliang; Stöckle, Claudio O.; Vaughan, Joseph K.; Rajagopalan, Kirti; Harrison, John A.; Tague, Christina L.; Kalyanaraman, Ananth; Chen, Yong; Guenther, Alex; Leung, Fok-Yan; Leung, L. Ruby; Perleberg, Andrew B.; Yoder, Jonathan; Allen, Elizabeth; Anderson, Sarah; Chandrasekharan, Bhagyam; Malek, Keyvan; Mullis, Tristan; Miller, Cody; Nergui, Tsengel; Poinsatte, Justin; Reyes, Julian; Zhu, Jun; Choate, Janet S.; Jiang, Xiaoyan; Nelson, Roger; Yoon, Jin-Ho; Yorgey, Georgine G.; Johnson, Kristen; Chinnayakanahalli, Kiran J.; Hamlet, Alan F.; Nijssen, Bart; Walden, Von

    2014-04-24

    Uncertainties in global change impacts, the complexities associated with the interconnected cycling of nitrogen, carbon, and water present daunting management challenges. Existing models provide detailed information on specific sub-systems (e.g., land, air, water, and economics). An increasing awareness of the unintended consequences of management decisions resulting from interconnectedness of these sub-systems, however, necessitates coupled regional earth system models (EaSMs). Decision makers’ needs and priorities can be integrated into the model design and development processes to enhance decision-making relevance and “usability” of EaSMs. BioEarth is a research initiative currently under development with a focus on the U.S. Pacific Northwest region that explores the coupling of multiple stand-alone EaSMs to generate usable information for resource decision-making. Direct engagement between model developers and non-academic stakeholders involved in resource and environmental management decisions throughout the model development process is a critical component of this effort. BioEarth utilizes a bottom-up approach for its land surface model that preserves fine spatial-scale sensitivities and lateral hydrologic connectivity, which makes it unique among many regional EaSMs. Here, we describe the BioEarth initiative and highlights opportunities and challenges associated with coupling multiple stand-alone models to generate usable information for agricultural and natural resource decision-making.

  2. Improving the representation of hydrologic processes in Earth System Models

    SciTech Connect (OSTI)

    Clark, Martyn P.; Fan, Ying; Lawrence, David M.; Adam, J. C.; Bolster, Diogo; Gochis, David; Hooper, Richard P.; Kumar, Mukesh; Leung, Lai-Yung R.; Mackay, D. Scott; Maxwell, Reed M.; Shen, Chaopeng; Swenson, Sean C.; Zeng, Xubin

    2015-08-21

    Many of the scientific and societal challenges in understanding and preparing for global environmental change rest upon our ability to understand and predict the water cycle change at large river basin, continent, and global scales. However, current large-scale models, such as the land components of Earth System Models (ESMs), do not yet represent the terrestrial water cycle in a fully integrated manner or resolve the finer-scale processes that can dominate large-scale water budgets. This paper reviews the current representation of hydrologic processes in ESMs and identifies the key opportunities for improvement. This review suggests that (1) the development of ESMs has not kept pace with modeling advances in hydrology, both through neglecting key processes (e.g., groundwater) and neglecting key aspects of spatial variability and hydrologic connectivity; and (2) many modeling advances in hydrology can readily be incorporated into ESMs and substantially improve predictions of the water cycle. Accelerating modeling advances in ESMs requires comprehensive hydrologic benchmarking activities, in order to systematically evaluate competing modeling alternatives, understand model weaknesses, and prioritize model development needs. This demands stronger collaboration, both through greater engagement of hydrologists in ESM development and through more detailed evaluation of ESM processes in research watersheds. Advances in the representation of hydrologic process in ESMs can substantially improve energy, carbon and nutrient cycle prediction capabilities through the fundamental role the water cycle plays in regulating these cycles.

  3. Scaling the Earth System Grid to 100Gbps Networks

    SciTech Connect (OSTI)

    Balman, Mehmet; Sim, Alex

    2012-03-02

    The SC11 demonstration, titled Scaling the Earth System Grid to 100Gbps Networks, showed the ability to use underlying infrastructure for the movement of climate data over 100Gbps network. Climate change research is one of the critical data intensive sciences, and the amount of data is continuously growing. Climate simulation data is geographically distributed over the world, and it needs to be accessed from many sources for fast and efficient analysis and inter-comparison of simulations. We used a 100Gbps link connecting National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory (LBNL), Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL). In the demo, the Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4) phase 3 of the Coupled Model Intercomparison Project (CMIP-3) dataset was staged into the memory of computing nodes at ANL and ORNL from NERSC over the 100Gbps network for analysis and visualization. In general, climate simulation data consists of relatively small and large files with irregular file size distribution in each dataset. In this demo, we addressed challenges on data management in terms of high bandwidth networks, usability of existing protocols and middleware tools, and how applications can adapt and benefit from next generation networks.

  4. 07Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li Thermal Neutron Capture Evaluated Data Measurements 1967RA24: 6Li(n, γ), E = thermal; measured Eγ; deduced Q. 1968SP01: 6Li(n, γ), E = thermal; measured Eγ, Iγ; deduced Q. 7Li deduced levels, branchings. 1970MEZS: 6Li(n, γ), E = thermal; measured σ. 1970SP02: 6Li(n, γ), E = thermal; measured Eγ, Iγ; deduced Q. 1972OP01: 6Li(n, γ), E = thermal; measured Eγ, Iγ. 1973JUZT, 1973JUZU: 6Li(n, γ), E = thermal; measured σ(Eγ). 7Li deduced γ-branching. 1985KO47: 6Li(n, γ), E =

  5. Projections of leaf area index in earth system models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mahowald, Natalie; Lo, Fiona; Zheng, Yun; Harrison, Laura; Funk, Chris; Lombardozzi, Danica; Goodale, Christine

    2016-03-09

    The area of leaves in the plant canopy, measured as leaf area index (LAI), modulates key land–atmosphere interactions, including the exchange of energy, moisture, carbon dioxide (CO2), and other trace gases and aerosols, and is therefore an essential variable in predicting terrestrial carbon, water, and energy fluxes. Here our goal is to characterize the LAI projections from the latest generation of earth system models (ESMs) for the Representative Concentration Pathway (RCP) 8.5 and RCP4.5 scenarios. On average, the models project increases in LAI in both RCP8.5 and RCP4.5 over most of the globe, but also show decreases in some partsmore » of the tropics. Because of projected increases in variability, there are also more frequent periods of low LAI across broad regions of the tropics. Projections of LAI changes varied greatly among models: some models project very modest changes, while others project large changes, usually increases. Modeled LAI typically increases with modeled warming in the high latitudes, but often decreases with increasing local warming in the tropics. The models with the most skill in simulating current LAI in the tropics relative to satellite observations tend to project smaller increases in LAI in the tropics in the future compared to the average of all the models. Using LAI projections to identify regions that may be vulnerable to climate change presents a slightly different picture than using precipitation projections, suggesting LAI may be an additional useful tool for understanding climate change impacts. Going forward, users of LAI projections from the CMIP5 ESMs evaluated here should be aware that model outputs do not exhibit clear-cut relationships to vegetation carbon and precipitation. Lastly, our findings underscore the need for more attention to LAI projections, in terms of understanding the drivers of projected changes and improvements to model skill.« less

  6. Runtime Tracing of The Community Earth System Model: Feasibility and Benefits

    SciTech Connect (OSTI)

    Wang, Dali [ORNL] [ORNL; Domke, Jens [ORNL] [ORNL

    2011-01-01

    Community Earth System Models (CESM) is one of US's leading earth system modeling systems, which has over decades of development history and embraced by large, active user communities. In this paper, we first review the history of CESM software development and layout the general objectives of performance analysis. Then we present an offline global community land model simulation within the CESM framework to demonstrate the procedure of runtime tracing of CESM using the Vampir toolset. Finally, we explain the benefits of runtime tracing to the general earth system modeling community. We hope those considerations can also be beneficial to many other modeling research programs involving legacy high-performance computing applications.

  7. Earth System Modeling -- Director`s initiative. LDRD Program final report

    SciTech Connect (OSTI)

    MacCracken, M.; Penner, J. [Lawrence Livermore National Lab., CA (United States). Atmospheric Science Div.

    1996-06-01

    The objective of the Earth System Modeling Director`s Initiative is to develop and test a framework for interactively coupling subsystem models that represent the physical, chemical, and biological processes which determine the state of the atmosphere, ocean, land surface and vegetation. Most studies of the potential for human perturbations of the climate system made previously have treated only limited components of the Earth system. The purpose of this project was to demonstrate the capability of coupling all relevant components in a flexible framework that will permit a wide variety of tests to be conducted to assure realistic interactions. A representation of the Earth system is shown and its important interactions.

  8. 5Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    abstracted; deduced nuclear properties. 1968TA11: 2H(, p), E 29.2 MeV; measured (Ep, E, ). 5Li deduced resonances. 1968VI03: 6Li(3He, p), E 2 MeV; 5Li; measured...

  9. 9Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    deduced log ft, Gamow-Teller transition strength, level width, di-neutron, neutron halo roles. 1991LUZZ: 9Li(-); measured T12. 1992LI24: 9Li(-); measured NMR...

  10. Lithium oxide in the Li(Si)/FeS/sub 2/ thermal battery system

    SciTech Connect (OSTI)

    Searcy, J.Q.; Neiswander, P.A.; Armijo, J.R.; Bild, R.W.

    1981-11-01

    The formation of lithium oxide (Li/sub 2/O) in Li(Si)/FeS/sub 2/ thermal batteries during the required shelf life of twenty-five years has been identified in previous work as a reaction deleterious to thermal battery performance. This paper gives the results of a study designed to determine performance degradation caused by Li/sub 2/O and to determine an acceptable level of Li/sub 2/O that can be used to define required dryness of battery parts and allowable leak rates. Pellets preconditioned with Li/sub 2/O were used in single cells or in batteries. Their performance was compared with discharges made using pellets with no Li/sub 2/O added. The actual Li/sub 2/O present in anode pellets at various stages during fabrication was determined by using 14 MeV neutron activation analysis. Results are reported. This work shows that thermal battery production controls should be designed in such a manner that not more than 15 wt.% of the Li(Si) is oxidized at the end of the desired self life. Furthermore, the formation of a Li/sub 2/O layer equivalent to the oxidation of 6.0 wt.% of the anode on the surface facing the current collector must be prevented. Battery designers must allow for a drop in coulombic efficiency as the Li(Si) reacts, and the effect on performance of Li/sub 2/O in the separator must be considered.

  11. 4Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li Ground-State Decay Evaluated Data Measured Ground-State Γcm(T1/2) for 4Li Adopted value: 91 ± 9 ys (2003AU02) Measured Mass Excess for 4Li Adopted value: 25320 ± 210 keV (2003AU02) Measurements 1960BR05: 4Li; measured not abstracted; deduced nuclear properties. 1960BR10: 4Li; measured not abstracted; deduced nuclear properties. 1960BR19: 4Li; measured not abstracted; deduced nuclear properties. 1960RO11: 4Li; measured not abstracted; deduced nuclear properties. 1963WE10: 4Li; measured not

  12. 11Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li β--Decay Evaluated Data Measurements 1969KL08: 11Li; measured T1/2. 1974RO31: 11Li; measured Eγ, Iγ, T1/2, delayed neutrons, βγ-coin, Eβ. 1975TH08: 11Li; measured neutron binding energy, delayed neutron branching ratio, T1/2; deduced log ft. 1979ANZZ: 11Li; 11Li deduced evidence for β-delayed 2n emission. 1979AZ03: 11Li; measured β-delayed En, nn-coin. 11Be levels deduced 1n, 2n decay probabilities. 1979DEYX, 1980DE39, 1980DEZF: 11Li; measured Eγ, Iγ, Iβ, β-delayed En, In; deduced

  13. 2011 Community Earth System Model (CESM) Tutorial, August 1-5, 2011

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: 2011 Community Earth System Model (CESM) Tutorial, August 1-5, 2011 Citation Details In-Document Search Title: 2011 Community Earth System Model (CESM) Tutorial, August 1-5, 2011 In fiscal year 2011, the Community Earth System Model (CESM) tutorial was taught at NCAR from 1-5 August 2011. This project hosted 79 full participants (1 accepted participant from China couldn't get a visa) selected from 180 applications. The tutorial was advertised

  14. 2011 Community Earth System Model (CESM) Tutorial, August 1-5...

    Office of Scientific and Technical Information (OSTI)

    Model (CESM) Tutorial, August 1-5, 2011 Citation Details In-Document Search Title: 2011 Community Earth System Model (CESM) Tutorial, August 1-5, 2011 In fiscal year 2011, the ...

  15. In the OSTI Collections: Earth System Models | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information Earth System Models Dr. Watson computer sleuthing scientist. Article Acknowledgement: Dr. William N. Watson, Physicist DOE Office of Scientific and Technical Information Experiment, theoretical analysis, and something like both Perfecting and using earth system models Enabling technologies, user training Towards decisions References Reports available from SciTech Connect Research organizations Additional References "The abstract of the

  16. THE EFFECTS OF HALIDE MODIFIERS ON THE SORPTION KINETICS OF THE LI-MG-N-H SYSTEM

    SciTech Connect (OSTI)

    Anton, D.; Gray, J.; Price, C.; Lascola, R.

    2011-07-20

    The effects of different transition metal halides (TiCl{sub 3}, VCl{sub 3}, ScCl{sub 3} and NiCl{sub 2}) on the sorption properties of the 1:1 molar ratio of LiNH{sub 2} to MgH{sub 2} are investigated. The modified mixtures were found to contain LiNH{sub 2}, MgH{sub 2} and LiCl. TGA results showed that the hydrogen desorption temperature was reduced with the modifier addition in this order: TiCl{sub 3} > ScCl{sub 3} > VCl{sub 3} > NiCL{sub 2}. Ammonia release was not significantly reduced resulting in a weight loss greater than the theoretical hydrogen storage capacity of the material. The isothermal sorption kinetics of the modified systems showed little improvement after the first dehydrogenation cycle over the unmodified system but showed drastic improvement in rehydrogenation cycles. X-ray diffraction and Raman spectroscopy identified the cycled material to be composed of LiH, MgH{sub 2}, Mg(NH{sub 2}){sub 2} and Mg{sub 3}N{sub 2}.

  17. BioMon: A Google Earth Based Continuous Biomass Monitoring System (Demo Paper)

    SciTech Connect (OSTI)

    Vatsavai, Raju

    2009-01-01

    We demonstrate a Google Earth based novel visualization system for continuous monitoring of biomass at regional and global scales. This system is integrated with a back-end spatiotemporal data mining system that continuously detects changes using high temporal resolution MODIS images. In addition to the visualization, we demonstrate novel query features of the system that provides insights into the current conditions of the landscape.

  18. 08Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Neutron Capture Evaluated Data Measurements 1967RA24: 7Li(n, γ), E = thermal; measured Eγ; deduced Q. 1973JUZT, 1973JUZU: 7Li(n, γ), E = thermal; measured σ(Eγ). 7Li deduced γ-branching. 1991LY01: 7Li(n, γ), E = thermal; measured Eγ, Iγ, capture σ. 1996BL10: 7Li(n, γ), E = 1.5-1340 eV; measured Eγ, Iγ, γ yield, absolute σ(E). 1997HEZW, 1998HE35: 7Li(n, γ), E ≈ 5 meV, 54 keV; measured σ. 1999ZHZM, 2000ZHZP: 7Li(n, γ), E = thermal; compiled, evaluated prompt γ-ray

  19. 10Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li Ground-State Decay Evaluated Data Measured Ground-State Γcm(T1/2) for 10Li Adopted value: 2.0 ± 0.5 zs (2003AU02) Measured Mass Excess for 10Li Adopted value: 33051 ± 15 keV (2003AU02) Measurements 1975WI26: 9Be(9Be, 8B), E = 121 MeV; measured σ(E(8B), θ); deduced Q. 10Li deduced mass excess. 1990AM05: 11B(π-, X), E at rest; measured inclusive p-, d-, t-spectra, X = 10Li production. 10Li deduced level, Γ. 1992AMZY: 11B(π-, X), E at rest; measured pion, deuteron, triton spectra. 10Li

  20. Improved structural systems for earth sheltered housing. Structural supplement to the design program

    SciTech Connect (OSTI)

    Behr, R.

    1981-10-01

    Additional engineering information is provided with regard to the structural analysis and design of thin shell concrete structures. The design program has tentatively demonstrated the overall architectural and marketing feasibility of curved, thin shell structural systems for earth sheltered housing. This supplement will address the structural feasibility question by presenting a complete manual analysis and structural design of an earth sheltered dome/tension ring/wall structural system, and also by presenting the results of a parametric sensitivity study of the dome/ring/wall configuration with respect to variations in span and rise for a three foot soil loading condition. Double curvature dome configurations are emphasized in this structural supplement because their analysis is not extensively addressed in earth sheltered housing literature.

  1. Earth System Grid (ESG) Data Node Software Stack

    Energy Science and Technology Software Center (OSTI)

    2009-12-01

    The ESG-CET system consist of two major components: 1) Gateways that support portal services, which serve as interfaces to end-users who can search, discover, and request data and data products, and 2) Data Nodes where the data actually resides. The Data is "published" to the Data Node, which makes the data visible to a Gateway and enables its delivery to end-users. It is expected that Gateways will only be installed by a small number ofmore » centers devoted to serving data (e.g., LLNL/PCMDI, NCAR, GFDL, DADC, DKRZ, ANU, JAMSTEC), whereas it is hoped that most climate modeling centers will install the Data Node software through which they can serve their model output.« less

  2. Characterization of the LiSi/CsBr-LiBr-KBr/FeS(2) System for Potential Use as a Geothermal Borehole Power Source

    SciTech Connect (OSTI)

    GUIDOTTI, RONALD A.; REINHARDT, FREDERICK W.

    1999-10-18

    We are continuing to study the suitability of modified thermal-battery technology as a potential power source for geothermal borehole applications. Previous work focused on the LiSi/FeS{sub 2} couple over a temperature range of 350 C to 400 C with the LiBr-KBr-LiF eutectic, which melts at 324.5 C. In this work, the discharge processes that take place in LiSi/CsBr-LiBr-KBr eutectic/FeS{sub 2} thermal cells were studied at temperatures between 250 C and 400 C using pelletized cells with immobilized electrolyte. The CsBr-LiBr-KBr eutectic was selected because of its lower melting point (228.5 C). Incorporation of a quasi-reference electrode allowed the determination of the relative contribution of each electrode to the overall cell polarization. The results of single-cell tests and limited battery tests are presented, along with preliminary data for battery stacks tested in a simulated geothermal borehole environment.

  3. Materials for Better Li-based Storage Systems for a "Green Energy Society"

    ScienceCinema (OSTI)

    Jean-Marie Tarascon

    2010-01-08

    Li-ion batteries are strongly considered for powering the upcoming generations of HEVs and PHEVs, but there are still the issues of safety and costs in terms of materials resources and abundances, synthesis, and recycling processes. Notions of materials having minimum footprint in nature, made via eco-efficient processes, must be integrated in our new research towards the next generation of sustainable and "greener" Li-ion batteries. In this July 13, 2009 talk sponsored by Berkeley Lab's Environental Energy Technologies Division, Jean-Marie Tarascon, a professor at the University of Picardie (Amiens), discuss Eco-efficient synthesis via hydrothermal/solvothermal processes using latent bases as well as structure directing templates or other bio-related approaches of LiFePO4 nanopowders.

  4. PMEL contributions to the collaboration: SCALING THE EARTH SYSTEM GRID TO PETASCALE DATA for the DOE SciDACs Earth System Grid Center for Enabling Technologies

    SciTech Connect (OSTI)

    Hankin, Steve

    2012-06-01

    Drawing to a close after five years of funding from DOE's ASCR and BER program offices, the SciDAC-2 project called the Earth System Grid (ESG) Center for Enabling Technologies has successfully established a new capability for serving data from distributed centers. The system enables users to access, analyze, and visualize data using a globally federated collection of networks, computers and software. The ESG software now known as the Earth System Grid Federation (ESGF) has attracted a broad developer base and has been widely adopted so that it is now being utilized in serving the most comprehensive multi-model climate data sets in the world. The system is used to support international climate model intercomparison activities as well as high profile U.S. DOE, NOAA, NASA, and NSF projects. It currently provides more than 25,000 users access to more than half a petabyte of climate data (from models and from observations) and has enabled over a 1,000 scientific publications.

  5. 8Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -asymmetry, NMR; deduced polarization. 1986WA01: 8Li(-); analyzed -delayed breakup -spectra; deduced intruder states role. 8Be deduced level, , Gamow-Teller matrix...

  6. The integrated Earth System Model (iESM): formulation and functionality

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collins, W. D.; Craig, A. P.; Truesdale, J. E.; Di Vittorio, A. V.; Jones, A. D.; Bond-Lamberty, B.; Calvin, K. V.; Edmonds, J. A.; Kim, S. H.; Thomson, A. M.; et al

    2015-01-21

    The integrated Earth System Model (iESM) has been developed as a new tool for projecting the joint human/climate system. The iESM is based upon coupling an Integrated Assessment Model (IAM) and an Earth System Model (ESM) into a common modeling infrastructure. IAMs are the primary tool for describing the human–Earth system, including the sources of global greenhouse gases (GHGs) and short-lived species, land use and land cover change, and other resource-related drivers of anthropogenic climate change. ESMs are the primary scientific tools for examining the physical, chemical, and biogeochemical impacts of human-induced changes to the climate system. The iESM projectmore » integrates the economic and human dimension modeling of an IAM and a fully coupled ESM within a single simulation system while maintaining the separability of each model if needed. Both IAM and ESM codes are developed and used by large communities and have been extensively applied in recent national and international climate assessments. By introducing heretofore-omitted feedbacks between natural and societal drivers, we can improve scientific understanding of the human–Earth system dynamics. Potential applications include studies of the interactions and feedbacks leading to the timing, scale, and geographic distribution of emissions trajectories and other human influences, corresponding climate effects, and the subsequent impacts of a changing climate on human and natural systems. This paper describes the formulation, requirements, implementation, testing, and resulting functionality of the first version of the iESM released to the global climate community.« less

  7. Interaction of CuS and sulfur in Li-S battery system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, undermore » a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.« less

  8. Interaction of CuS and sulfur in Li-S battery system

    SciTech Connect (OSTI)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, under a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.

  9. Development of hybrid 3-D hydrological modeling for the NCAR Community Earth System Model (CESM)

    SciTech Connect (OSTI)

    Zeng, Xubin; Troch, Peter; Pelletier, Jon; Niu, Guo-Yue; Gochis, David

    2015-11-15

    This is the Final Report of our four-year (3-year plus one-year no cost extension) collaborative project between the University of Arizona (UA) and the National Center for Atmospheric Research (NCAR). The overall objective of our project is to develop and evaluate the first hybrid 3-D hydrological model with a horizontal grid spacing of 1 km for the NCAR Community Earth System Model (CESM).

  10. Multicomponent analysis of mixed rare-earth metal ion solutions by the electronic tongue sensor system

    SciTech Connect (OSTI)

    Legin, A.; Kirsanov, D.; Rudnitskaya, A.; Rovny, S.; Logunov, M.

    2007-07-01

    Novel electrochemical sensors based on well-known extracting agents are developed. Sensors have shown high sensitivity towards a variety of rear earth metal ions in acidic media at pH=2. Multi-sensor system (electronic tongue) comprising newly developed sensors was successfully applied for the analysis of binary and ternary mixtures of Ce{sup 3+}, Nd{sup 3+}, Sm{sup 3+} and Gd{sup 3+} cations in different combinations. (authors)

  11. Earth Systems Questions in Experimental Climate Change Science: Pressing Questions and Necessary Facilities

    SciTech Connect (OSTI)

    Osmond, B.

    2002-05-20

    Sixty-four scientists from universities, national laboratories, and other research institutions worldwide met to evaluate the feasibility and potential of the Biosphere2 Laboratory (B2L) as an inclusive multi-user scientific facility (i.e., a facility open to researchers from all institutions, according to agreed principles of access) for earth system studies and engineering research, education, and training relevant to the mission of the United States Department of Energy (DOE).

  12. Jennifer Li | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jennifer Li Jennifer Li Jennifer Li E-mail: jennifer.li

  13. THROUGH-THE-EARTH (TTE) COMMUNICATIONS SYSTEM AND THE IN-MINE POWER LINE (IMPL) COMMUNICATIONS SYSTEM

    SciTech Connect (OSTI)

    Zvi H. Meiksin

    2002-01-01

    Work has progressed on both subsystems: the Through-the-Earth (TTE) Communications system and the In-Mine Power Line (IMPL) Communications system. The TTE system: The system was fabricated and repackaged as an industrial product enclosed in a commercial rugged, waterproof housing suitable for installation in mines. Features were added to the system to appeal to the preferences of different mine managers. Arrangements were made with NIOSH to install the system in the Lake Lynn underground mine for evaluation and demonstration to potential users. The IMPL system: Voice compression was successfully implemented and incorporated into the laboratory model. Compressed voice was transmitted through a power line, expanded at the receiving end, and received with high clarity.

  14. A Subbasin-based framework to represent land surface processes in an Earth System Model

    SciTech Connect (OSTI)

    Tesfa, Teklu K.; Li, Hongyi; Leung, Lai-Yung R.; Huang, Maoyi; Ke, Yinghai; Sun, Yu; Liu, Ying

    2014-05-20

    Realistically representing spatial heterogeneity and lateral land surface processes within and between modeling units in earth system models is important because of their implications to surface energy and water exchange. The traditional approach of using regular grids as computational units in land surface models and earth system models may lead to inadequate representation of lateral movements of water, energy and carbon fluxes, especially when the grid resolution increases. Here a new subbasin-based framework is introduced in the Community Land Model (CLM), which is the land component of the Community Earth System Model (CESM). Local processes are represented assuming each subbasin as a grid cell on a pseudo grid matrix with no significant modifications to the existing CLM modeling structure. Lateral routing of water within and between subbasins is simulated with the subbasin version of a recently-developed physically based routing model, Model for Scale Adaptive River Routing (MOSART). As an illustration, this new framework is implemented in the topographically diverse region of the U.S. Pacific Northwest. The modeling units (subbasins) are delineated from high-resolution Digital Elevation Model while atmospheric forcing and surface parameters are remapped from the corresponding high resolution datasets. The impacts of this representation on simulating hydrologic processes are explored by comparing it with the default (grid-based) CLM representation. In addition, the effects of DEM resolution on parameterizing topography and the subsequent effects on runoff processes are investigated. Limited model evaluation and comparison showed that small difference between the averaged forcing can lead to more significant difference in the simulated runoff and streamflow because of nonlinear horizontal processes. Topographic indices derived from high resolution DEM may not improve the overall water balance, but affect the partitioning between surface and subsurface runoff

  15. On an improved sub-regional water resources management representation for integration into earth system models

    SciTech Connect (OSTI)

    Voisin, Nathalie; Li, Hongyi; Ward, Duane L.; Huang, Maoyi; Wigmosta, Mark S.; Leung, Lai-Yung R.

    2013-09-30

    Human influence on the hydrologic cycle includes regulation and storage, consumptive use and overall redistribution of water resources in space and time. Representing these processes is essential for applications of earth system models in hydrologic and climate predictions, as well as impact studies at regional to global scales. Emerging large-scale research reservoir models use generic operating rules that are flexible for coupling with earth system models. Those generic operating rules have been successful in reproducing the overall regulated flow at large basin scales. This study investigates the uncertainties of the reservoir models from different implementations of the generic operating rules using the complex multi-objective Columbia River Regulation System in northwestern United States as an example to understand their effects on not only regulated flow but also reservoir storage and fraction of the demand that is met. Numerical experiments are designed to test new generic operating rules that combine storage and releases targets for multi-purpose reservoirs and to compare the use of reservoir usage priorities, withdrawals vs. consumptive demand, as well as natural vs. regulated mean flow for calibrating operating rules. Overall the best performing implementation is the use of the combined priorities (flood control storage targets and irrigation release targets) operating rules calibrated with mean annual natural flow and mean monthly withdrawals. The challenge of not accounting for groundwater withdrawals, or on the contrary, assuming that all remaining demand is met through groundwater extractions, is discussed.

  16. Progress Report 2008: A Scalable and Extensible Earth System Model for Climate Change Science

    SciTech Connect (OSTI)

    Drake, John B; Worley, Patrick H; Hoffman, Forrest M; Jones, Phil

    2009-01-01

    This project employs multi-disciplinary teams to accelerate development of the Community Climate System Model (CCSM), based at the National Center for Atmospheric Research (NCAR). A consortium of eight Department of Energy (DOE) National Laboratories collaborate with NCAR and the NASA Global Modeling and Assimilation Office (GMAO). The laboratories are Argonne (ANL), Brookhaven (BNL) Los Alamos (LANL), Lawrence Berkeley (LBNL), Lawrence Livermore (LLNL), Oak Ridge (ORNL), Pacific Northwest (PNNL) and Sandia (SNL). The work plan focuses on scalablity for petascale computation and extensibility to a more comprehensive earth system model. Our stated goal is to support the DOE mission in climate change research by helping ... To determine the range of possible climate changes over the 21st century and beyond through simulations using a more accurate climate system model that includes the full range of human and natural climate feedbacks with increased realism and spatial resolution.

  17. Earth materials and earth dynamics

    SciTech Connect (OSTI)

    Bennett, K; Shankland, T.

    2000-11-01

    In the project ''Earth Materials and Earth Dynamics'' we linked fundamental and exploratory, experimental, theoretical, and computational research programs to shed light on the current and past states of the dynamic Earth. Our objective was to combine different geological, geochemical, geophysical, and materials science analyses with numerical techniques to illuminate active processes in the Earth. These processes include fluid-rock interactions that form and modify the lithosphere, non-linear wave attenuations in rocks that drive plate tectonics and perturb the earth's surface, dynamic recrystallization of olivine that deforms the upper mantle, development of texture in high-pressure olivine polymorphs that create anisotropic velocity regions in the convecting upper mantle and transition zone, and the intense chemical reactions between the mantle and core. We measured physical properties such as texture and nonlinear elasticity, equation of states at simultaneous pressures and temperatures, magnetic spins and bonding, chemical permeability, and thermal-chemical feedback to better characterize earth materials. We artificially generated seismic waves, numerically modeled fluid flow and transport in rock systems and modified polycrystal plasticity theory to interpret measured physical properties and integrate them into our understanding of the Earth. This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL).

  18. The Earth System Grid Federation: An Open Infrastructure for Access to Distributed Geospatial Data

    SciTech Connect (OSTI)

    Ananthakrishnan, Rachana; Bell, Gavin; Cinquini, Luca; Crichton, Daniel; Danvil, Sebastian; Drach, Bob; Fiore, Sandro; Gonzalez, Estanislao; Harney, John F; Mattmann, Chris; Kershaw, Philip; Morgan, Mark; Pascoe, Stephen; Shipman, Galen M; Wang, Feiyi

    2013-01-01

    The Earth System Grid Federation (ESGF) is a multi-agency, international collaboration that aims at developing the software infrastructure needed to facilitate and empower the study of climate change on a global scale. The ESGF s architecture employs a system of geographically distributed peer nodes, which are independently administered yet united by the adoption of common federation protocols and application programming interfaces (APIs). The cornerstones of its interoperability are the peer-to-peer messaging that is continuously exchanged among all nodes in the federation; a shared architecture and API for search and discovery; and a security infrastructure based on industry standards (OpenID, SSL, GSI and SAML). The ESGF software is developed collaboratively across institutional boundaries and made available to the community as open source. It has now been adopted by multiple Earth science projects and allows access to petabytes of geophysical data, including the entire model output used for the next international assessment report on climate change (IPCC-AR5) and a suite of satellite observations (obs4MIPs) and reanalysis data sets (ANA4MIPs).

  19. The Earth System Grid Federation: An Open Infrastructure for Access to Distributed Geo-Spatial Data

    SciTech Connect (OSTI)

    Cinquini, Luca; Crichton, Daniel; Miller, Neill; Mattmann, Chris; Harney, John F; Shipman, Galen M; Wang, Feiyi; Bell, Gavin; Drach, Bob; Ananthakrishnan, Rachana; Pascoe, Stephen; Fiore, Sandro; Schweitzer, Roland; Danvil, Sebastian; Morgan, Mark

    2012-01-01

    The Earth System Grid Federation (ESGF) is a multi-agency, international collaboration that aims at developing the software infrastructure needed to facilitate and empower the study of climate change on a global scale. The ESGF s architecture employs a system of geographically distributed peer nodes, which are independently administered yet united by the adoption of common federation protocols and application programming interfaces (APIs). The cornerstones of its interoperability are the peer-to-peer messaging that is continuously exchanged among all nodes in the federation; a shared architecture and API for search and discovery; and a security infrastructure based on industry standards (OpenID, SSL, GSI and SAML). The ESGF software is developed collaboratively across institutional boundaries and made available to the community as open source. It has now been adopted by multiple Earth science projects and allows access to petabytes of geophysical data, including the entire model output used for the next international assessment report on climate change (IPCC-AR5) and a suite of satellite observations (obs4MIPs) and reanalysis data sets (ANA4MIPs).

  20. A modern solver framework to manage solution algorithms in the Community Earth System Model

    SciTech Connect (OSTI)

    Evans, Katherine J [ORNL; Worley, Patrick H [ORNL; Nichols, Dr Jeff A [ORNL; WhiteIII, James B [National Center for Atmospheric Research (NCAR); Salinger, Andy [Sandia National Laboratories (SNL); Price, Stephen [Los Alamos National Laboratory (LANL); Lemieux, Jean-Francois [New York University; Lipscomb, William [Los Alamos National Laboratory (LANL); Perego, Mauro [Florida State University; Vertenstein, Mariana [National Center for Atmospheric Research (NCAR); Edwards, Jim [IBM and National Center for Atmospheric Research

    2012-01-01

    Global Earth-system models (ESM) can now produce simulations that resolve ~50 km features and include finer-scale, interacting physical processes. In order to achieve these scale-length solutions, ESMs require smaller time steps, which limits parallel performance. Solution methods that overcome these bottlenecks can be quite intricate, and there is no single set of algorithms that perform well across the range of problems of interest. This creates significant implementation challenges, which is further compounded by complexity of ESMs. Therefore, prototyping and evaluating new algorithms in these models requires a software framework that is flexible, extensible, and easily introduced into the existing software. We describe our efforts to create a parallel solver framework that links the Trilinos library of solvers to Glimmer-CISM, a continental ice sheet model used in the Community Earth System Model (CESM). We demonstrate this framework within both current and developmental versions of Glimmer-CISM and provide strategies for its integration into the rest of the CESM.

  1. 2014 Earth System Grid Federation and Ultrascale Visualization Climate Data Analysis Tools Conference Report

    SciTech Connect (OSTI)

    Williams, Dean N.

    2015-01-27

    The climate and weather data science community met December 9–11, 2014, in Livermore, California, for the fourth annual Earth System Grid Federation (ESGF) and Ultrascale Visualization Climate Data Analysis Tools (UV-CDAT) Face-to-Face (F2F) Conference, hosted by the Department of Energy, National Aeronautics and Space Administration, National Oceanic and Atmospheric Administration, the European Infrastructure for the European Network of Earth System Modelling, and the Australian Department of Education. Both ESGF and UVCDATremain global collaborations committed to developing a new generation of open-source software infrastructure that provides distributed access and analysis to simulated and observed data from the climate and weather communities. The tools and infrastructure created under these international multi-agency collaborations are critical to understanding extreme weather conditions and long-term climate change. In addition, the F2F conference fosters a stronger climate and weather data science community and facilitates a stronger federated software infrastructure. The 2014 F2F conference detailed the progress of ESGF, UV-CDAT, and other community efforts over the year and sets new priorities and requirements for existing and impending national and international community projects, such as the Coupled Model Intercomparison Project Phase Six. Specifically discussed at the conference were project capabilities and enhancements needs for data distribution, analysis, visualization, hardware and network infrastructure, standards, and resources.

  2. Final Report Collaborative Project. Improving the Representation of Coastal and Estuarine Processes in Earth System Models

    SciTech Connect (OSTI)

    Bryan, Frank; Dennis, John; MacCready, Parker; Whitney, Michael

    2015-11-20

    This project aimed to improve long term global climate simulations by resolving and enhancing the representation of the processes involved in the cycling of freshwater through estuaries and coastal regions. This was a collaborative multi-institution project consisting of physical oceanographers, climate model developers, and computational scientists. It specifically targeted the DOE objectives of advancing simulation and predictive capability of climate models through improvements in resolution and physical process representation. The main computational objectives were: 1. To develop computationally efficient, but physically based, parameterizations of estuary and continental shelf mixing processes for use in an Earth System Model (CESM). 2. To develop a two-way nested regional modeling framework in order to dynamically downscale the climate response of particular coastal ocean regions and to upscale the impact of the regional coastal processes to the global climate in an Earth System Model (CESM). 3. To develop computational infrastructure to enhance the efficiency of data transfer between specific sources and destinations, i.e., a point-to-point communication capability, (used in objective 1) within POP, the ocean component of CESM.

  3. Exploring the isopycnal mixing and helium-heat paradoxes in a suite of Earth System Models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gnanadesikan, A.; Abernathey, R.; Pradal, M.-A.

    2014-11-20

    This paper uses a suite of Earth System models which simulate the distribution of He isotopes and radiocarbon to examine two paradoxes in Earth science. The helium-heat paradox refers to the fact that helium emissions to the deep ocean are far lower than would be expected given the rate of geothermal heating, since both are thought to be the result of radioactive decay in the earth's interior. The isopycnal mixing paradox comes from the fact that many theoretical parameterizations of the isopycnal mixing coefficient ARedi that link it to baroclinic instability project it to be small (of order a fewmore » hundred m2 s−1) in the ocean interior away from boundary currents. However, direct observations using tracers and floats (largely in the upper ocean) suggest that values of this coefficient are an order of magnitude higher. Because helium isotopes equilibrate rapidly with the atmosphere, but radiocarbon equilibrates slowly, it might be thought that resolving the isopycnal mixing paradox in favor of the higher observational estimates of ARedi might also solve the helium paradox. In this paper we show that this is not the case. In a suite of models with different spatially constant and spatially varying values of ARedi the distribution of radiocarbon and helium isotopes is sensitive to the value of ARedi. However, away from strong helium sources in the Southeast Pacific, the relationship between the two is not sensitive, indicating that large-scale advection is the limiting process for removing helium and radiocarbon from the deep ocean. The helium isotopes, in turn, suggest a higher value of ARedi in the deep ocean than is seen in theoretical parameterizations based on baroclinic growth rates. We argue that a key part of resolving the isopycnal mixing paradox is to abandon the idea that ARedi has a direct relationship to local baroclinic instability and to the so called "thickness" mixing coefficient AGM.« less

  4. F LI

    Office of Legacy Management (LM)

    >"- -- F LI c ------- RADIATION SURVEY REPORT OF THE M IDDLESEX LANDFILL SITE RADIATION SURVEY REPORT OF THE ~IDDLESEX LfiMDFI.LL S I:TE it%RCH 25 - AFRiL 4, 1374 ;)UNE 27, 1974 T.!BLE OF CONTENTS Introduction and Summary . . . . . . . . . . . . . . . 1 Conclusions. . . . . . w . . . . . . , . . . , . . . . 2 Histohcal Background0 . . . . . . . . . . . . b (I . . 2 Description of Area Surveyed . . . . . . . . I . . . * 3 Survey Findings. * *,. a . . . , . . . . . . . . . . . 4 Surface

  5. Exploring the isopycnal mixing and helium–heat paradoxes in a suite of Earth system models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gnanadesikan, A.; Pradal, M.-A.; Abernathey, R.

    2015-07-27

    This paper uses a suite of Earth system models which simulate the distribution of He isotopes and radiocarbon to examine two paradoxes in Earth science, each of which results from an inconsistency between theoretically motivated global energy balances and direct observations. The helium–heat paradox refers to the fact that helium emissions to the deep ocean are far lower than would be expected given the rate of geothermal heating, since both are thought to be the result of radioactive decay in Earth's interior. The isopycnal mixing paradox comes from the fact that many theoretical parameterizations of the isopycnal mixing coefficient ARedimore » that link it to baroclinic instability project it to be small (of order a few hundred m2 s−1) in the ocean interior away from boundary currents. However, direct observations using tracers and floats (largely in the upper ocean) suggest that values of this coefficient are an order of magnitude higher. Helium isotopes equilibrate rapidly with the atmosphere and thus exhibit large gradients along isopycnals while radiocarbon equilibrates slowly and thus exhibits smaller gradients along isopycnals. Thus it might be thought that resolving the isopycnal mixing paradox in favor of the higher observational estimates of ARedi might also solve the helium paradox, by increasing the transport of mantle helium to the surface more than it would radiocarbon. In this paper we show that this is not the case. In a suite of models with different spatially constant and spatially varying values of ARedi the distribution of radiocarbon and helium isotopes is sensitive to the value of ARedi. However, away from strong helium sources in the southeastern Pacific, the relationship between the two is not sensitive, indicating that large-scale advection is the limiting process for removing helium and radiocarbon from the deep ocean. The helium isotopes, in turn, suggest a higher value of ARedi below the thermocline than is seen in theoretical

  6. Effects of Ti-Based Additives on the Hydrogen Storage Properties of aLiBH4/CaH2Destabilized System

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Hongwei; Ibikunle, Adeola; Goudy, Andrew J.

    2010-01-01

    The hydrogen storage properties of a destabilizedLiBH4/CaH2system ball-milled withTiCl3,TiF3, andTiO2additives have been investigated. It is found that the system withTiCl3additive has a lower dehydrogenation temperature than the ones with other additives. Further study shows that a higher amount ofTiCl3is more effective in reducing the desorption temperature of theLiBH4/CaH2system, since it leads to a lower activation energy of dehydrogenation. The activations energies for mixtures containing 4, 10, and 25?mol% ofTiCl3are 141, 126, and 110?kJ/mol, respectively. However, the benefits of higher amounts ofTiCl3are offset by a larger reduction in hydrogen capacity of the mixtures.

  7. MAS NMR Study of the Metastable Solid Solutions Found in the LiFePO4/FePO4 System

    SciTech Connect (OSTI)

    Cabana, Jordi; Shirakawa, Junichi; Chen, Guoying; Richardson, Thomas; Grey, Clare P.

    2009-10-09

    Li and 3IP NMR experiments were conducted on a series of single- or two-phase samples in the LiFePCvFePCM system with different overall lithium contents, and containing the two end-members and/or two metastable solid solution hases, Lio.6FeP04 or Lio.34FeP04. These experiments were carried out at different temperatures in order to search for vacancy/charge ordering and ion/electron mobility in the metastable phases. Evidence for Li+-Fe2+ interactions was bserved for both Lio.6FeP04 and Lio.34FePC>4. The strength of this interaction leads to the formation of LiFePCvlike clusters in the latter, as shown by the room temperature data. Different motional processes are proposed to exist as the temperature is increased and various scenarios are discussed. While concerted lithium-electron hopping and/or correlations explains the data below 125C, evidence for some uncorrelated motion is found at higher temperatures, together with the onset of phase mixing.

  8. The Cost of Jointness: Insights from Environmental Monitoring Systems in Low-Earth Orbit

    SciTech Connect (OSTI)

    Dwyer, Morgan Maeve

    2014-09-01

    This report summarizes the results of doctoral research that explored the cost impact of acquiring complex government systems jointly. The report begins by reviewing recent evidence that suggests that joint programs experience greater cost growth than non-joint programs. It continues by proposing an alternative approach for studying cost growth on government acquisition programs and demonstrates the utility of this approach by applying it to study the cost of jointness on three past programs that developed environmental monitoring systems for low-Earth orbit. Ultimately, the report concludes that joint programs' costs grow when the collaborating government agencies take action to retain or regain their autonomy. The report provides detailed qualitative and quantitative data in support of this conclusion and generalizes its findings to other joint programs that were not explicitly studied here. Finally, it concludes by presenting a quantitative model that assesses the cost impacts of jointness and by demonstrating how government agencies can more effectively architect joint programs in the future.

  9. 2011 Community Earth System Model (CESM) Tutorial, August 1-5, 2011

    SciTech Connect (OSTI)

    Hurrell, James W.

    2013-10-11

    In fiscal year 2011, the Community Earth System Model (CESM) tutorial was taught at NCAR from 1-5 August 2011. This project hosted 79 full participants (1 accepted participant from China couldn't get a visa) selected from 180 applications. The tutorial was advertised through emails to CESM mailing lists. NCAR staff and long-term visitors (who were not eligible to attend) were also invited to 'audit' the climate and practical lectures and to work on the practical sessions on their own. 15 NCAR staff and long-term visitors took advantage of this opportunity. The majority of the students were graduate students, but several post-docs, faculty, and other research scientists also attended. Additionally, many people are using the on-line lessons and practical sessions. As of August 18, 2011, 407 people had registered to access and use the tutorial from 33 countries all over the world, but a majority from US universities. In fiscal year 2011, the Climate and Global Dynamics Division Information Systems Group (CGD/ISG) built and operated a temporary computer laboratory in a meeting room. This project was made possible through funding from the National Science Foundation Directorate of Geosciences, and the Department of Energy Office of Science.

  10. 6Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 6Li is subdivided into the following categories: Ground State Properties of 6Li Special States Theoretical Shell Model Cluster Models Complex...

  11. 7Li Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7Li(, '): emission yield 1.0 - 3.4 1 01182012 2011YA02 7Li(, ): elastic scattering differential 1.0 - 4.5 cm 170 07192011 7Li(, p): differential...

  12. Model-Based Design and Integration of Large Li-ion Battery Systems

    SciTech Connect (OSTI)

    Smith, Kandler; Kim, Gi-Heon; Santhanagopalan, Shriram; Shi, Ying; Pesaran, Ahmad; Mukherjee, Partha; Barai, Pallab; Maute, Kurt; Behrou, Reza; Patil, Chinmaya

    2015-11-17

    This presentation introduces physics-based models of batteries and software toolsets, including those developed by the U.S. Department of Energy's (DOE) Computer-Aided Engineering for Electric-Drive Vehicle Batteries Program (CAEBAT). The presentation highlights achievements and gaps in model-based tools for materials-to-systems design, lifetime prediction and control.

  13. Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases. Final report

    SciTech Connect (OSTI)

    Prather, Michael J.; Hsu, Juno; Nicolau, Alex; Veidenbaum, Alex; Smith, Philip Cameron; Bergmann, Dan

    2014-11-07

    Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

  14. Department of Energy's Biological and Environmental Research Strategic Data Roadmap for Earth System Science

    SciTech Connect (OSTI)

    Williams, Dean N.; Palanisamy, Giri; Shipman, Galen; Boden, Thomas A.; Voyles, Jimmy W.

    2014-04-25

    Rapid advances in experimental, sensor, and computational technologies and techniques are driving exponential growth in the volume, acquisition rate, variety, and complexity of scientific data. This wealth of scientifically meaningful data has tremendous potential to lead to scientific discovery. However, to achieve scientific breakthroughs, these data must be exploitable—they must be analyzed effectively and efficiently and the results shared and communicated easily within the wider Department of Energy’s (DOE’s) Biological and Environmental Research (BER) Climate and Environmental Sciences Division (CESD) community. The explosion in data complexity and scale makes these tasks exceedingly difficult to achieve, particularly given that an increasing number of disciplines are working across techniques, integrating simulation and experimental or observational results (see Table 5 in Appendix 2). Consequently, we need new approaches to data management, analysis, and visualization that provide research teams with easy-to-use and scalable end-to-end solutions. These solutions must facilitate (and where feasible, automate and capture) every stage in the data lifecycle (shown in Figure 1), from collection to management, annotation, sharing, discovery, analysis, and visualization. In addition, the core functionalities are the same across climate science communities, but they require customization to adapt to specific needs and fit into research and analysis workflows. To this end, the mission of CESD’s Data and Informatics Program is to integrate all existing and future distributed CESD data holdings into a seamless and unified environment for the acceleration of Earth system science.

  15. Leaf respiration (GlobResp) - global trait database supports Earth System Models

    SciTech Connect (OSTI)

    Wullschleger, Stan D.; Warren, Jeffrey; Thornton, Peter E.

    2015-03-20

    Here we detail how Atkin and his colleagues compiled a global database (GlobResp) that details rates of leaf dark respiration and associated traits from sites that span Arctic tundra to tropical forests. This compilation builds upon earlier research (Reich et al., 1998; Wright et al., 2006) and was supplemented by recent field campaigns and unpublished data.In keeping with other trait databases, GlobResp provides insights on how physiological traits, especially rates of dark respiration, vary as a function of environment and how that variation can be used to inform terrestrial biosphere models and land surface components of Earth System Models. Although an important component of plant and ecosystem carbon (C) budgets (Wythers et al., 2013), respiration has only limited representation in models. Seen through the eyes of a plant scientist, Atkin et al. (2015) give readers a unique perspective on the climatic controls on respiration, thermal acclimation and evolutionary adaptation of dark respiration, and insights into the covariation of respiration with other leaf traits. We find there is ample evidence that once large databases are compiled, like GlobResp, they can reveal new knowledge of plant function and provide a valuable resource for hypothesis testing and model development.

  16. Development of hybrid 3-D hydrological modeling for the NCAR Community Earth System Model (CESM)

    SciTech Connect (OSTI)

    Zeng, Xubin; Troch, Peter; Pelletier, Jon; Niu, Guo-Yue; Gochis, David

    2015-11-15

    This is the Final Report of our four-year (3-year plus one-year no cost extension) collaborative project between the University of Arizona (UA) and the National Center for Atmospheric Research (NCAR). The overall objective of our project is to develop and evaluate the first hybrid 3-D hydrological model with a horizontal grid spacing of 1 km for the NCAR Community Earth System Model (CESM). We have made substantial progress in model development and evaluation, computational efficiencies and software engineering, and data development and evaluation, as discussed in Sections 2-4. Section 5 presents our success in data dissemination, while Section 6 discusses the scientific impacts of our work. Section 7 discusses education and mentoring success of our project, while Section 8 lists our relevant DOE services. All peer-reviewed papers that acknowledged this project are listed in Section 9. Highlights of our achievements include: • We have finished 20 papers (most published already) on model development and evaluation, computational efficiencies and software engineering, and data development and evaluation • The global datasets developed under this project have been permanently archived and publicly available • Some of our research results have already been implemented in WRF and CLM • Patrick Broxton and Michael Brunke have received their Ph.D. • PI Zeng has served on DOE proposal review panels and DOE lab scientific focus area (SFA) review panels

  17. Electrolyte effects in Li(Si)/FeS{sub 2} thermal batteries

    SciTech Connect (OSTI)

    Guidotti, R.A.; Reinhardt, F.W.

    1994-10-01

    The most common electrochemical couple for thermally activated (``thermal``) batteries is the Li-alloy/FeS{sub 2} system. The most common Li-alloys used for anodes are 20% Li-80% Al and 44% Li-56% Si (by weight); liquid Li immobilized with iron powder has also been used. The standard electrolyte that has been used in thermal batteries over the years is the LiCl-KCl eutectic that melts at 352{degrees}C. The LiCl-LiBr-LiF eutectic had the best rate and power characteristics. This electrolyte melts at 436{degrees}C and shows very low polarization because of the absence of Li+ gradients common with the LiCl-KCl eutectic. The low-melting electrolytes examined included a KBr-LiBr-LiCl eutectic (melting at 321{degrees}C), a LiBr-KBr-LiF eutectic (melting at 313{degrees}C), and a CsBr-LiBr-KBr eutectic (melting at 238{degrees}C). The CsBr-based salt had poor conductivity and was not studied further. The LiBr-KBr-LiF eutectic outperformed the KBr-LiBr-LiCl eutectic and was selected for more extensive testing. Because of their lower melting points and larger liquidi relative to the LiCl-KCl eutectic, the low-melting electrolytes are prime candidates for long-life applications (i.e., for activated lives of one hour or more). This paper will detail the relative performance of the Li(Si)/FeS{sub 2} couple using primarily the LiCl-KCl (standard) eutectic, the LiCl-LiBr-LiF (all-Li) eutectic, and the LiBr-KBr-LiF (low-melting) eutectic electrolytes. Most of the tests were conducted with 5-cell batteries; validation tests were also carried out with appropriate full-sized batteries.

  18. Incorporating Stakeholder Decision Support Needs into an Integrated Regional Earth System Model

    SciTech Connect (OSTI)

    Rice, Jennie S.; Moss, Richard H.; Runci, Paul J.; Anderson, K. L.; Malone, Elizabeth L.

    2012-03-21

    A new modeling effort exploring the opportunities, constraints, and interactions between mitigation and adaptation at regional scale is utilizing stakeholder engagement in an innovative approach to guide model development and demonstration, including uncertainty characterization, to effectively inform regional decision making. This project, the integrated Regional Earth System Model (iRESM), employs structured stakeholder interactions and literature reviews to identify the most relevant adaptation and mitigation alternatives and decision criteria for each regional application of the framework. The information is used to identify important model capabilities and to provide a focus for numerical experiments. This paper presents the stakeholder research results from the first iRESM pilot region. The pilot region includes the Great Lakes Basin in the Midwest portion of the United States as well as other contiguous states. This geographic area (14 states in total) permits cohesive modeling of hydrologic systems while also providing gradients in climate, demography, land cover/land use, and energy supply and demand. The results from the stakeholder research indicate that iRESM should prioritize addressing adaptation alternatives in the water resources, urban infrastructure, and agriculture sectors, such as water conservation, expanded water quality monitoring, altered reservoir releases, lowered water intakes, urban infrastructure upgrades, increased electric power reserves in urban areas, and land use management/crop selection changes. Regarding mitigation alternatives, the stakeholder research shows a need for iRESM to focus on policies affecting the penetration of renewable energy technologies, and the costs and effectiveness of energy efficiency, bioenergy production, wind energy, and carbon capture and sequestration.

  19. A Generalized Stability Analysis of the AMOC in Earth System Models: Implication for Decadal Variability and Abrupt Climate Change

    SciTech Connect (OSTI)

    Fedorov, Alexey V.; Fedorov, Alexey

    2015-01-14

    The central goal of this research project was to understand the mechanisms of decadal and multi-decadal variability of the Atlantic Meridional Overturning Circulation (AMOC) as related to climate variability and abrupt climate change within a hierarchy of climate models ranging from realistic ocean models to comprehensive Earth system models. Generalized Stability Analysis, a method that quantifies the transient and asymptotic growth of perturbations in the system, is one of the main approaches used throughout this project. The topics we have explored range from physical mechanisms that control AMOC variability to the factors that determine AMOC predictability in the Earth system models, to the stability and variability of the AMOC in past climates.

  20. DOE SciDAC's Earth System Grid Center for Enabling Technologies Final Report

    SciTech Connect (OSTI)

    Williams, Dean N.

    2011-09-27

    The mission of the Earth System Grid Federation (ESGF) is to provide the worldwide climate-research community with access to the data, information, model codes, analysis tools, and intercomparison capabilities required to make sense of enormous climate data sets. Its specific goals are to (1) provide an easy-to-use and secure web-based data access environment for data sets; (2) add value to individual data sets by presenting them in the context of other data sets and tools for comparative analysis; (3) address the specific requirements of participating organizations with respect to bandwidth, access restrictions, and replication; (4) ensure that the data are readily accessible through the analysis and visualization tools used by the climate research community; and (5) transfer infrastructure advances to other domain areas. For the ESGF, the U.S. Department of Energy's (DOE's) Earth System Grid Center for Enabling Technologies (ESG-CET) team has led international development and delivered a production environment for managing and accessing ultra-scale climate data. This production environment includes multiple national and international climate projects (such as the Community Earth System Model and the Coupled Model Intercomparison Project), ocean model data (such as the Parallel Ocean Program), observation data (Atmospheric Radiation Measurement Best Estimate, Carbon Dioxide Information and Analysis Center, Atmospheric Infrared Sounder, etc.), and analysis and visualization tools, all serving a diverse user community. These data holdings and services are distributed across multiple ESG-CET sites (such as ANL, LANL, LBNL/NERSC, LLNL/PCMDI, NCAR, and ORNL) and at unfunded partner sites, such as the Australian National University National Computational Infrastructure, the British Atmospheric Data Centre, the National Oceanic and Atmospheric Administration Geophysical Fluid Dynamics Laboratory, the Max Planck Institute for Meteorology, the German Climate Computing

  1. DETECTABILITY OF EARTH-LIKE PLANETS IN CIRCUMSTELLAR HABITABLE ZONES OF BINARY STAR SYSTEMS WITH SUN-LIKE COMPONENTS

    SciTech Connect (OSTI)

    Eggl, Siegfried; Pilat-Lohinger, Elke; Haghighipour, Nader

    2013-02-20

    Given the considerable percentage of stars that are members of binaries or stellar multiples in the solar neighborhood, it is expected that many of these binaries host planets, possibly even habitable ones. The discovery of a terrestrial planet in the {alpha} Centauri system supports this notion. Due to the potentially strong gravitational interaction that an Earth-like planet may experience in such systems, classical approaches to determining habitable zones (HZ), especially in close S-type binary systems, can be rather inaccurate. Recent progress in this field, however, allows us to identify regions around the star permitting permanent habitability. While the discovery of {alpha} Cen Bb has shown that terrestrial planets can be detected in solar-type binary stars using current observational facilities, it remains to be shown whether this is also the case for Earth analogs in HZs. We provide analytical expressions for the maximum and rms values of radial velocity and astrometric signals, as well as transit probabilities of terrestrial planets in such systems, showing that the dynamical interaction of the second star with the planet may indeed facilitate the planets' detection. As an example, we discuss the detectability of additional Earth-like planets in the averaged, extended, and permanent HZs around both stars of the {alpha} Centauri system.

  2. Variable C : N : P stoichiometry of dissolved organic matter cycling in the Community Earth System Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Letscher, R. T.; Moore, J. K.; Teng, Y. -C.; Primeau, F.

    2015-01-12

    Dissolved organic matter (DOM) plays an important role in the ocean's biological carbon pump by providing an advective/mixing pathway for ~ 20% of export production. DOM is known to have a stoichiometry depleted in nitrogen (N) and phosphorus (P) compared to the particulate organic matter pool, a fact that is often omitted from biogeochemical ocean general circulation models. However the variable C : N : P stoichiometry of DOM becomes important when quantifying carbon export from the upper ocean and linking the nutrient cycles of N and P with that of carbon. Here we utilize recent advances in DOM observationalmore » data coverage and offline tracer-modeling techniques to objectively constrain the variable production and remineralization rates of the DOM C : N : P pools in a simple biogeochemical-ocean model of DOM cycling. The optimized DOM cycling parameters are then incorporated within the Biogeochemical Elemental Cycling (BEC) component of the Community Earth System Model (CESM) and validated against the compilation of marine DOM observations. The optimized BEC simulation including variable DOM C : N : P cycling was found to better reproduce the observed DOM spatial gradients than simulations that used the canonical Redfield ratio. Global annual average export of dissolved organic C, N, and P below 100 m was found to be 2.28 Pg C yr-1 (143 Tmol C yr-1, 16.4 Tmol N yr-1, and 1 Tmol P yr-1, respectively, with an average export C : N : P stoichiometry of 225 : 19 : 1 for the semilabile (degradable) DOM pool. Dissolved organic carbon (DOC) export contributed ~ 25% of the combined organic C export to depths greater than 100 m.« less

  3. Variable C : N : P stoichiometry of dissolved organic matter cycling in the Community Earth System Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Letscher, R. T.; Moore, J. K.; Teng, Y. -C.; Primeau, F.

    2014-06-16

    Dissolved organic matter (DOM) plays an important role in the ocean's biological carbon pump by providing an advective/mixing pathway for ~ 20% of export production. DOM is known to have a stoichiometry depleted in nitrogen (N) and phosphorus (P) compared to the particulate organic matter pool, a~fact that is often omitted from biogeochemical-ocean general circulation models. However the variable C : N : P stoichiometry of DOM becomes important when quantifying carbon export from the upper ocean and linking the nutrient cycles of N and P with that of carbon. Here we utilize recent advances in DOM observational data coveragemore » and offline tracer-modeling techniques to objectively constrain the variable production and remineralization rates of the DOM C / N / P pools in a simple biogeochemical-ocean model of DOM cycling. The optimized DOM cycling parameters are then incorporated within the Biogeochemical Elemental Cycling (BEC) component of the Community Earth System Model and validated against the compilation of marine DOM observations. The optimized BEC simulation including variable DOM C : N : P cycling was found to better reproduce the observed DOM spatial gradients than simulations that used the canonical Redfield ratio. Global annual average export of dissolved organic C, N, and P below 100 m was found to be 2.28 Pg C yr-1 (143 Tmol C yr-1), 16.4 Tmol N yr-1, and 1 Tmol P yr-1, respectively with an average export C : N : P stoichiometry of 225 : 19 : 1 for the semilabile (degradable) DOM pool. DOC export contributed ~ 25% of the combined organic C export to depths greater than 100 m.« less

  4. Design and experimental testing of the performance of an outdoor LiBr/H{sub 2}O solar thermal absorption cooling system with a cold store

    SciTech Connect (OSTI)

    Agyenim, Francis; Knight, Ian; Rhodes, Michael

    2010-05-15

    A domestic-scale prototype experimental solar cooling system has been developed based on a LiBr/H{sub 2}O absorption system and tested during the 2007 summer and autumn months in Cardiff University, UK. The system consisted of a 12 m{sup 2} vacuum tube solar collector, a 4.5 kW LiBr/H{sub 2}O absorption chiller, a 1000 l cold storage tank and a 6 kW fan coil. The system performance, as well as the performances of the individual components in the system, were evaluated based on the physical measurements of the daily solar radiation, ambient temperature, inlet and outlet fluid temperatures, mass flow rates and electrical consumption by component. The average coefficient of thermal performance (COP) of the system was 0.58, based on the thermal cooling power output per unit of available thermal solar energy from the 12 m{sup 2} Thermomax DF100 vacuum tube collector on a hot sunny day with average peak insolation of 800 W/m{sup 2} (between 11 and 13.30 h) and ambient temperature of 24 C. The system produced an electrical COP of 3.6. Experimental results prove the feasibility of the new concept of cold store at this scale, with chilled water temperatures as low as 7.4 C, demonstrating its potential use in cooling domestic scale buildings. (author)

  5. On linking an Earth system model to the equilibrium carbon representation of an economically optimizing land use model

    SciTech Connect (OSTI)

    Bond-Lamberty, Benjamin; Calvin, Katherine V.; Jones, Andrew D.; Mao, Jiafu; Patel, Pralit L.; Shi, Xiaoying; Thomson, Allison M.; Thornton, Peter E.; Zhou, Yuyu

    2014-01-01

    Human activities are significantly altering biogeochemical cycles at the global scale, posing a significant problem for earth system models (ESMs), which may incorporate static land-use change inputs but do not actively simulate policy or economic forces. One option to address this problem is a to couple an ESM with an economically oriented integrated assessment model. Here we have implemented and tested a coupling mechanism between the carbon cycles of an ESM (CLM) and an integrated assessment (GCAM) model, examining the best proxy variables to share between the models, and quantifying our ability to distinguish climate- and land-use-driven flux changes. CLMs net primary production and heterotrophic respiration outputs were found to be the most robust proxy variables by which to manipulate GCAMs assumptions of long-term ecosystem steady state carbon, with short-term forest production strongly correlated with long-term biomass changes in climate-change model runs. By leveraging the fact that carbon-cycle effects of anthropogenic land-use change are short-term and spatially limited relative to widely distributed climate effects, we were able to distinguish these effects successfully in the model coupling, passing only the latter to GCAM. By allowing climate effects from a full earth system model to dynamically modulate the economic and policy decisions of an integrated assessment model, this work provides a foundation for linking these models in a robust and flexible framework capable of examining two-way interactions between human and earth system processes.

  6. Causes and Implications of Persistent Atmospheric Carbon Dioxide Biases in Earth System Models

    SciTech Connect (OSTI)

    Hoffman, Forrest M [ORNL] [ORNL; Randerson, James T. [University of California, Irvine] [University of California, Irvine; Arora, Vivek K. [Canadian Centre for Climate Modelling and Analysis, Meteorological Service of Canada] [Canadian Centre for Climate Modelling and Analysis, Meteorological Service of Canada; Bao, Qing [State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics] [State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics; Cadule, Patricia [Institut Pierre Simon Laplace, Laboratoire des Sciences du Climat et de l'Environment] [Institut Pierre Simon Laplace, Laboratoire des Sciences du Climat et de l'Environment; Ji, Duoying [State Key Laboratory of Earth Surface Processes and Resource Ecology, Beijing] [State Key Laboratory of Earth Surface Processes and Resource Ecology, Beijing; Jones, Chris D. [Hadley Centre, U.K. Met Office] [Hadley Centre, U.K. Met Office; Kawamiya, Michio [Japan Agency for Marine-Earth Science and Technology (JAMSTEC)] [Japan Agency for Marine-Earth Science and Technology (JAMSTEC); Khatiwala, Samar [Lamont-Doherty Earth Observatory, Columbia University, Palisades, NY] [Lamont-Doherty Earth Observatory, Columbia University, Palisades, NY; Lindsay, Keith [National Center for Atmospheric Research (NCAR)] [National Center for Atmospheric Research (NCAR); Obata, Atsushi [Meteorological Research Institute, Japan] [Meteorological Research Institute, Japan; Shevliakova, Elena [Princeton University] [Princeton University; Six, Katharina D. [Max Planck Institute for Meteorology, Hamburg, Germany] [Max Planck Institute for Meteorology, Hamburg, Germany; Tjiputra, Jerry F. [Uni Climate, Uni Research] [Uni Climate, Uni Research; Volodin, Evgeny M. [Institute of Numerical Mathematics, Russian Academy of Science, Moscow] [Institute of Numerical Mathematics, Russian Academy of Science, Moscow; Wu, Tongwen [China Meteorological Administration (CMA), Beijing] [China Meteorological Administration (CMA), Beijing

    2014-01-01

    The strength of feedbacks between a changing climate and future CO2 concentrations are uncertain and difficult to predict using Earth System Models (ESMs). We analyzed emission-driven simulations--in which atmospheric CO2 levels were computed prognostically--for historical (1850-2005) and future periods (RCP 8.5 for 2006-2100) produced by 15 ESMs for the Fifth Phase of the Coupled Model Intercomparison Project (CMIP5). Comparison of ESM prognostic atmospheric CO2 over the historical period with observations indicated that ESMs, on average, had a small positive bias in predictions of contemporary atmospheric CO2. Weak ocean carbon uptake in many ESMs contributed to this bias, based on comparisons with observations of ocean and atmospheric anthropogenic carbon inventories. We found a significant linear relationship between contemporary atmospheric CO2 biases and future CO2 levels for the multi-model ensemble. We used this relationship to create a contemporary CO2 tuned model (CCTM) estimate of the atmospheric CO2 trajectory for the 21st century. The CCTM yielded CO2 estimates of 600 {plus minus} 14 ppm at 2060 and 947 {plus minus} 35 ppm at 2100, which were 21 ppm and 32 ppm below the multi-model mean during these two time periods. Using this emergent constraint approach, the likely ranges of future atmospheric CO2, CO2-induced radiative forcing, and CO2-induced temperature increases for the RCP 8.5 scenario were considerably narrowed compared to estimates from the full ESM ensemble. Our analysis provided evidence that much of the model-to-model variation in projected CO2 during the 21st century was tied to biases that existed during the observational era, and that model differences in the representation of concentration-carbon feedbacks and other slowly changing carbon cycle processes appear to be the primary driver of this variability. By improving models to more closely match the long-term time series of CO2 from Mauna Loa, our analysis suggests uncertainties in

  7. Livermore Lab's giant laser system will bring star power to Earth

    SciTech Connect (OSTI)

    Moses, E

    2010-04-08

    In the 50 years since the laser was first demonstrated in Malibu, California, on May 16, 1960, Lawrence Livermore National Laboratory (LLNL) has been a world leader in laser technology and the home for many of the world's most advanced laser systems. That tradition continues today at LLNL's National Ignition Facility (NIF), the world's most energetic laser system. NIF's completion in March 2009 not only marked the dawn of a new era of scientific research - it could also prove to be the next big step in the quest for a sustainable, carbon-free energy source for the world. NIF consists of 192 laser beams that will focus up to 1.8 million joules of energy on a bb-sized target filled with isotopes of hydrogen - forcing the hydrogen nuclei to collide and fuse in a controlled thermonuclear reaction similar to what happens in the sun and the stars. More energy will be produced by this 'ignition' reaction than the amount of laser energy required to start it. This is the long-sought goal of 'energy gain' that has eluded fusion researchers for more than half a century. Success will be a scientific breakthrough - the first demonstration of fusion ignition in a laboratory setting, duplicating on Earth the processes that power the stars. This impending success could not be achieved without the valuable partnerships forged with other national and international laboratories, private industry and universities. One of the most crucial has been between LLNL and the community in which it resides. Over 155 businesses in the local Tri-Valley area have contributed to the NIF, from industrial technology and engineering firms to tool manufacturing, electrical, storage and supply companies. More than $2.3B has been spent locally between contracts with nearby merchants and employee salaries. The Tri-Valley community has enabled the Laboratory to complete a complex and far-reaching project that will have national and global impact in the future. The first experiments were conducted on NIF

  8. 3rd Annual Earth System Grid Federation and 3rd Annual Earth System Grid Federation and Ultrascale Visualization Climate Data Analysis Tools Face-to-Face Meeting Report December 2013

    SciTech Connect (OSTI)

    Williams, Dean N.

    2014-02-21

    The climate and weather data science community gathered December 3–5, 2013, at Lawrence Livermore National Laboratory, in Livermore, California, for the third annual Earth System Grid Federation (ESGF) and Ultra-scale Visualization Climate Data Analysis Tools (UV-CDAT) Face-to-Face (F2F) Meeting, which was hosted by the Department of Energy, National Aeronautics and Space Administration, National Oceanic and Atmospheric Administration, the European Infrastructure for the European Network of Earth System Modelling, and the Australian Department of Education. Both ESGF and UV-CDAT are global collaborations designed to develop a new generation of open-source software infrastructure that provides distributed access and analysis to observed and simulated data from the climate and weather communities. The tools and infrastructure developed under these international multi-agency collaborations are critical to understanding extreme weather conditions and long-term climate change, while the F2F meetings help to build a stronger climate and weather data science community and stronger federated software infrastructure. The 2013 F2F meeting determined requirements for existing and impending national and international community projects; enhancements needed for data distribution, analysis, and visualization infrastructure; and standards and resources needed for better collaborations.

  9. Precise rare earth analysis of geological materials

    SciTech Connect (OSTI)

    Laul, J.C.; Wogman, N.A.

    1982-01-01

    Rare earth element (REE) concentrations are very informative in revealing chemical fractionation processs in geological systems. The REE's (La-Lu) behavior is characteristic of various primary and secondary minerals which comprise a rock. The REE's contents and their patterns provide a strong fingerprint in distinguishing among various rock types and in understanding the partial melting and/or fractional crystallization of the source region. The REE contents in geological materials are usually at trace levels. To measure all the REE at such levels, radiochemical neutron activation analysis (RNAA) has been used with a REE group separation scheme. To maximize detection sensitivites for individual REE, selective ..gamma..-ray/x-ray measurements have been made using normal Ge(Li) and low-energy photon detectors (LEPD), and Ge(Li)-NaI(Tl) coincidence-noncoincidence spectrometer systems. Using these detection methods an individual REE can be measured at or below the ppB levels; chemical yields of the REE are determined by reactivation.

  10. Behavior of Rare Earth Element In Geothermal Systems; A New Exploration/Exploitation Tool

    SciTech Connect (OSTI)

    Scott A. Wood

    2002-01-28

    The goal of this four-year project was to provide a database by which to judge the utility of the rare earth elements (REE) in the exploration for and exploitation of geothermal fields in the United States. Geothermal fluids from hot springs and wells have been sampled from a number of locations, including: (1) the North Island of New Zealand (1 set of samples); (2) the Cascades of Oregon; (3) the Harney, Alvord Desert and Owyhee geothermal areas of Oregon; (4) the Dixie Valley and Beowawe fields in Nevada; (5) Palinpion, the Philippines: (6) the Salton Sea and Heber geothermal fields of southern California; and (7) the Dieng field in Central Java, Indonesia. We have analyzed the samples from all fields for REE except the last two.

  11. DOE SciDAC's Earth System Grid Center for Enabling Technologies...

    Office of Scientific and Technical Information (OSTI)

    Jet Propulsion Laboratory, and the National Oceanic and Atmospheric Administration. ... System Grid, data replication, system monitoring Word Cloud More Like This Full Text ...

  12. LiDAR Technology | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LiDAR Technology LiDAR Technology Enables the Location of Historic Energy Production Sites Understanding the impact that newly developed novel methods for extracting resources from the Earth has on our environment is important, but this requires baseline data against which potential changes can be measured. In Pennsylvania, as in other parts of the United States, commercial activity has already left environmental impacts that are not readily discernible. Charcoal from a completed burn (image

  13. Making Li-air batteries rechargeable: material challenges

    SciTech Connect (OSTI)

    Shao, Yuyan; Ding, Fei; Xiao, Jie; Zhang, Jian; Xu, Wu; Park, Seh Kyu; Zhang, Jiguang; Wang, Yong; Liu, Jun

    2013-02-25

    A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.

  14. Thermal Properties of LiCl-KCl Molten Salt for Nuclear Waste Separation

    SciTech Connect (OSTI)

    Sridharan, Kumar; Allen, Todd; Anderson, Mark; Simpson, Mike

    2012-11-30

    This project addresses both practical and fundamental scientific issues of direct relevance to operational challenges of the molten LiCl-KCl salt pyrochemical process, while providing avenues for improvements in the process. In order to understand the effects of the continually changing composition of the molten salt bath during the process, the project team will systematically vary the concentrations of rare earth surrogate elements, lanthanum, cerium, praseodymium, and neodymium, which will be added to the molten LiCl-KCl salt. They will also perform a limited number of focused experiments by the dissolution of depleted uranium. All experiments will be performed at 500 deg C. The project consists of the following tasks. Researchers will measure density of the molten salts using an instrument specifically designed for this purpose, and will determine the melting points with a differential scanning calorimeter. Knowledge of these properties is essential for salt mass accounting and taking the necessary steps to prevent melt freezing. The team will use cyclic voltammetry studies to determine redox potentials of the rare earth cations, as well as their diffusion coefficients and activities in the molten LiCl-KCl salt. In addition, the team will perform anodic stripping voltammetry to determine the concentration of the rare earth elements and their solubilities, and to develop the scientific basis for an on-line diagnostic system for in situ monitoring of the cation species concentration (rare earths in this case). Solubility and activity of the cation species are critically important for the prediction of the salt's useful lifetime and disposal.

  15. Feasibility of a super high-energy-density battery of the Li/Br/F sub 3 electrochemical system. Final report, 15 August 1989-14 May 1990

    SciTech Connect (OSTI)

    Frysz, C.A.; Pyszczek, M.F.; Ebel, S.J.

    1990-08-16

    Feasibility studies on the practical aspects of developing a lithium/bromine trifluoride battery have been studied. Efforts directed toward identifying materials for porous electrode separators, glasses for insulated electrical feed-throughs, and metals for lid, case and current collector fabrication via electrochemical testing techniques have resulted in a list of materials suitable for these applications. Prototype cells utilizing a spirally wound electrode configuration have been constructed and discharged. The use of lithium salts as an electrolyte additive has been explored, and has shown a positive effect on discharge performance. Through the use of currently available technology, however, the lithium/bromine trifluoride couple has not delivered energy density comparable to other high energy density lithium systems. This investigation has revealed that practical Li/BrF3 cell development will require further extensive fundamental electrochemical research.

  16. 5Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Table for 5Li is subdivided into the folowing categories: Ground State Properties Cluster Model Shell Model Special States Model Calculations Model Discussions Complex...

  17. Earth System Grid Center for Enabling Technologies (ESG-CET): A Data Infrastructure for Data-Intensive Climate Research

    SciTech Connect (OSTI)

    Williams, Dean N.

    2011-06-03

    For the Earth System Grid Federation (ESGF), the ESG-CET team has led international development and delivered a production environment for managing and accessing ultrascale climate data. This production environment includes multiple national and international climate projects (e.g., Couple Model Intercomparison Project, Community Earth System Model), ocean model data (such as the Parallel Ocean Program), observation data (Carbon Dioxide Information and Analysis Center, Atmospheric Infrared Sounder, and so forth), and analysis and visualization tools, all of which serve a diverse community of users. These data holdings and services are distributed across multiple ESG-CET sites (such as LANL, LBNL, LLNL, NCAR, and ORNL) as well as at unfunded partners sites such as the Australian National University National Computational Infrastructure, the British Atmospheric Data Centre, the National Oceanic and Atmospheric Administration Geophysical Fluid Dynamics Laboratory, the Max Planck Institute for Meteorology, the German Climate Computing Centre, and the National Aeronautics and Space Administration Jet Propulsion Laboratory. More recently, ESG-CET has been extending services beyond data-file access and delivery to develop more detailed information products (scientific graphics, animations, etc.), secure binary data-access services (based upon the OPeNDAP protocol), and server-side analysis capabilities. These will allow users to request data subsets transformed through commonly used analysis and intercomparison procedures. As we transition from development activities to production and operations, the ESG-CET team is tasked with making data available to all users seeking to understand, process, extract value from, visualize, and/or communicate it to others. This ongoing effort, though daunting in scope and complexity, will greatly magnify the value of numerical climate model outputs and climate observations for future national and international climate-assessment reports

  18. Luminescent nanocrystals in the rare-earth niobatezirconia system formed via hydrothermal method

    SciTech Connect (OSTI)

    Hirano, Masanori Dozono, Hayato

    2013-08-15

    Luminescent nanocrystals based on the rare-earth niobates (Ln{sub 3}NbO{sub 7}, Ln=Y, Eu) and zirconia (ZrO{sub 2}) that were composed of 50 mol% Ln{sub 3}NbO{sub 7} and 50 mol% ZrO{sub 2}, were hydrothermally formed as cubic phase under weakly basic conditions at 240 C. The lattice parameter of the as-prepared nanoparticles corresponding to the composition of Y{sub 3?x}Eu{sub x}NbO{sub 7}4ZrO{sub 2} that was estimated as a single phase of cubic gradually increased as the content of europium x increased. The existence of small absorbance peaks at 395 and 466 nm corresponding to the Eu{sup 3+7}F{sub 0}?{sup 5}L{sub 6}, and {sup 7}F{sub 0}?{sup 5}D{sub 2} excitation transition, respectively, was clearly observed in the diffuse reflectance spectra of the as-prepared samples containing europium. The optical band gap of the as-prepared samples was in the range from 3.5 to 3.7 eV. The photoluminescence spectra of the as-prepared nanocrystals containing europium showed orange and red luminescences with main peaks at 590 and 610 nm, corresponding to {sup 5}D{sub 0}?{sup 7}F{sub 1} and {sup 5}D{sub 0}?{sup 7}F{sub 2} transitions of Eu{sup 3+}, respectively, under excitation at 395 nm Xe lamp. The emission intensity corresponding to {sup 5}D{sub 0}?{sup 7}F{sub 2} transition increased as heat-treatment temperature rose from 800 to 1200 C. - Graphical abstract: This graphical abstract shows the excitation and emission spectra and a transmission electron microscopy image of nanocrystals (with composition based on the rare-earth niobates (Ln{sub 3}NbO{sub 7}, Ln=Y, Eu) and zirconia (ZrO{sub 2}) that were composed of 50 mol% Ln{sub 3}NbO{sub 7} and 50 mol% ZrO{sub 2}) formed via hydrothermal route. Display Omitted - Highlights: Nanocrystals composed of 50 mol% Y{sub 3?x}Eu{sub x}NbO{sub 7} and 50 mol% ZrO{sub 2} was directly formed. The nanocrystals were hydrothermally formed under weakly basic conditions at 240 C. The Y{sub 3}NbO{sub 7} showed an UV-blue and broad

  19. LiDAR (Lewicki & Oldenburg, 2005) | Open Energy Information

    Open Energy Info (EERE)

    Technique LiDAR Activity Date Usefulness useful DOE-funding Unknown References Jennifer L. Lewicki, Curtis M. Oldenburg (2005) Strategies To Detect Hidden Geothermal Systems...

  20. LiDAR (Lewicki & Oldenburg, 2004) | Open Energy Information

    Open Energy Info (EERE)

    Technique LiDAR Activity Date Usefulness useful DOE-funding Unknown References Jennifer L. Lewicki, Curtis M. Oldenburg (2004) Strategies For Detecting Hidden Geothermal Systems...

  1. System for beaming power from earth to a high altitude platform

    DOE Patents [OSTI]

    Friedman, Herbert W.; Porter, Terry J.

    2002-01-01

    Power is transmitted to a high altitude platform by an array of diode pumped solid state lasers each operated at a single range of laser wavelengths outside of infrared and without using adaptive optics. Each laser produces a beam with a desired arrival spot size. An aircraft avoidance system uses a radar system for automatic control of the shutters of the lasers.

  2. Tuning complexity by lithiation: A family of intergrowth structures using condensed hypho-icosahedra in the Li-doped Ca–Zn system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Qisheng; Zhu, Ran; Miller, Gordon J.

    2016-04-26

    Cluster chemistry of intermetallics with valence electron counts (VECs) in the range of 2.0–3.0 is intriguing. Lithiation of polar intermetallics in this VEC region is found to be an effective chemical route to produce new complex structures with different stability mechanisms. In this work, two new complex intermetallic structures have been discovered in the Ca–Li–Zn system: Ca12LixZn59–x and Ca15LixZn75–x. Ca12LixZn59–x, x ≈ 5.65(3)–14.95(3), forms in the trigonal space group R3m, with a = 9.074(1)–9.1699(2) Å, c = 53.353(1)–53.602(1) Å, and Z = 3. In comparison, Ca15LixZn75–x, x ≈ 19.07(2), crystallizes in the space group P63/mmc, with a ≈ 9.183(1) Å,more » c ≈ 45.191(5) Å), and Z = 2. Both structures are members of a large intergrowth family featuring slabs of dimers (D) and trimers (T) stacking along [001], with the sequences DTDDTDDTD for Ca12LixZn59–x and TDDDTDDD for Ca15LixZn75–x. Each dimer consists of two face-sharing Zn-centered hypho-icosahedra, and each trimer comprises a Li-centered icosahedron sandwiched by two hypho-icosahedra. Furthermore, this intergrowth family includes several known intermetallic structure types involving very electropositive metals, e.g., SrMg5.2, Ba2Li4.21Al4.79, and Sr9Li17.5Al25.5. Because of cluster defects and condensation, both Ca12LixZn59–x and Ca15LixZn75–x are electronically akin to close-packed metals, and their structural stabilities can be interpreted by a Hume-Rothery mechanism rather than the Zintl–Klemm concept.« less

  3. Ammonium Additives to Dissolve Li2S through Hydrogen Binding for High

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Li-S Batteries - Joint Center for Energy Storage Research July 1, 2016, Research Highlights Ammonium Additives to Dissolve Li2S through Hydrogen Binding for High Energy Li-S Batteries (a) Solubility of Li2S in DMSO solvent with different amounts of NH4NO3 as additive. (b) 1H chemical shifts as a function of Li2S concentration in DMSO-d6 with NH4NO3 additive. (c) DFT-derived structure of Li2S-NH4-NO3-8DMSO system shows the dissolution process of Li2S is enhanced through hydrogen

  4. Substrate and environmental controls on microbial assimilation of soil organic carbon: a framework for Earth System Models

    SciTech Connect (OSTI)

    Xu, Xiaofeng; Schimel, Joshua; Thornton, Peter E; Song, Xia; Yuan, Fengming; Goswami, Santonu

    2014-01-01

    Microbial assimilation of soil organic carbon is one of the fundamental processes of global carbon cycling and it determines the magnitude of microbial biomass in soils. Mechanistic understanding of microbial assimilation of soil organic carbon and its controls is important for to improve Earth system models ability to simulate carbon-climate feedbacks. Although microbial assimilation of soil organic carbon is broadly considered to be an important parameter, it really comprises two separate physiological processes: one-time assimilation efficiency and time-dependent microbial maintenance energy. Representing of these two mechanisms is crucial to more accurately simulate carbon cycling in soils. In this study, a simple modeling framework was developed to evaluate the substrate and environmental controls on microbial assimilation of soil organic carbon using a new term: microbial annual active period (the length of microbes remaining active in one year). Substrate quality has a positive effect on microbial assimilation of soil organic carbon: higher substrate quality (lower C:N ratio) leads to higher ratio of microbial carbon to soil organic carbon and vice versa. Increases in microbial annual active period from zero stimulate microbial assimilation of soil organic carbon; however, when microbial annual active period is longer than an optimal threshold, increasing this period decreases microbial biomass. The simulated ratios of soil microbial biomass to soil organic carbon are reasonably consistent with a recently compiled global dataset at the biome-level. The modeling framework of microbial assimilation of soil organic carbon and its controls developed in this study offers an applicable ways to incorporate microbial contributions to the carbon cycling into Earth system models for simulating carbon-climate feedbacks and to explain global patterns of microbial biomass.

  5. 7Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 7Li is subdivided into the following categories: Reviews Ground State Properties Shell Model Cluster Model Other Theoretical Work Model Calculations Photodisintegration Polarization Fission and Fusion Elastic and Inelastic Scattering Projectile Fragmentation and Multifragmentation Astrophysical Hyperfine Structure b-decay Muons Hypernuclei and Mesons Hypernuclei and Baryons Pion, Kaon and Eta-Mesons Other Work Applications

  6. 8Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Tables The General Table for 8Li is subdivided into the following categories: Reviews Ground State Properties Shell Model Cluster Model Other Models Photodissociation Fusion and Fission Elastic and Inelastic Scattering Fragmentation Reactions Astrophysical b Decay Hypernuclei Pions, Kaons and h-mesons

  7. 9Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 9Li is subdivided into the following categories: Shell Model Cluster Model Theoretical Ground State Properties Special States Other Model Calculations Complex Reactions Beta-Decay Pions Muons Photodisintegration Elastic and Inelastic Scattering Electromagnetic Transitions Astrophysical

  8. Earth's Magnetosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mysterious electron stash found hidden among Van Allen belts March 1, 2013 Instruments detect never-before-seen phenomenon in Earth's Magnetosphere LOS ALAMOS, N.M., March 1, 2013-U.S. researchers, including a trio from Los Alamos National Laboratory, have witnessed the mysterious appearance of a relatively long-lived zone of high-energy electrons stored between Earth's Van Allen radiation belts. The surprising findings, discovered by NASA's Van Allen Probes (formerly known as the Radiation Belt

  9. Mars, the Moon, and the Ends of the Earth: Autonomy for Small Reactor Power Systems

    SciTech Connect (OSTI)

    Wood, Richard Thomas [ORNL

    2008-01-01

    In recent years, the National Aeronautics and Space Administration (NASA) has been considering deep space missions that utilize a small-reactor power system (SRPS) to provide energy for propulsion and spacecraft power. Additionally, application of SRPS modules as a planetary power source is being investigated to enable a continuous human presence for nonpolar lunar sites and on Mars. A SRPS can supply high-sustained power for space and surface applications that is both reliable and mass efficient. The use of small nuclear reactors for deep space or planetary missions presents some unique challenges regarding the operations and control of the power system. Current-generation terrestrial nuclear reactors employ varying degrees of human control and decision-making for operations and benefit from periodic human interaction for maintenance. In contrast, the control system of a SRPS employed for deep space missions must be able to accommodate unattended operations due to communications delays and periods of planetary occlusion while adapting to evolving or degraded conditions with no opportunity for repair or refurbishment. While surface power systems for planetary outposts face less extreme delays and periods of isolation and may benefit from limited maintenance capabilities, considerations such as human safety, resource limitations and usage priorities, and economics favor minimizing direct, continuous human interaction with the SRPS for online, dedicated power system management. Thus, a SRPS control system for space or planetary missions must provide capabilities for operational autonomy. For terrestrial reactors, large-scale power plants remain the preferred near-term option for nuclear power generation. However, the desire to reduce reliance on carbon-emitting power sources in developing countries may lead to increased consideration of SRPS modules for local power generation in remote regions that are characterized by emerging, less established infrastructures

  10. Earth Day 2016

    Broader source: Energy.gov [DOE]

    Earth Day 2016 event details and links. Earth Day video montage and Earth Day Nationals video link. Earth Day photo contest.

  11. A metallurgical approach toward alloying in rare earth permanen magnet systems

    SciTech Connect (OSTI)

    Branagan, D. J.

    1995-02-23

    The approach was developed to allow microstructural enhancement and control during solidification and processing. Compound additions of Group IVA, VA, or VIA transition metals (TM) and carbon were added to Nd{sub 2}Fe{sub 14}B (2-14-1). Transition metal carbides formed in IVA (TiC, ZrC, HfC) and Group VA (VC, NbC, TaC) systems, but not in the VIA system. The alloying ability of each TM carbide was graded using phase stability, liquid and equilibrium solid solubility, and high temperature carbide stability. Ti with C additions was chosen as the best system. The practically zero equilibrium solid solubility means that the Ti and C additions will ultimately form TiC after heat treatment which allows the development of a composite microstructure consisting of the 2-14-1 phase and TiC. Thus, the excellent intrinsic magnetic properties of the 2-14-1 phase remain unaltered and the extrinsic properties relating to the microstructure are enhanced due to the TiC stabilized microstructure which is much more resistant to grain growth. When Ti + C are dissolved in the liquid melt or solid phases, such as the glass or 2-14-1 phase, the intrinsic properties are changed; favorable changes include increased glass forming ability, reduced optimum cooling rate, increased optimum energy product, and enhanced nucleation kinetics of crystallization.

  12. Presence of Li clusters in molten LiCl-Li

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Merwin, Augustus; Phillips, William C.; Williamson, Mark A.; Willit, James L.; Motsegood, Perry N.; Chidambaram, Dev

    2016-05-05

    Molten mixtures of lithium chloride and metallic lithium are of significant interest in various metal oxide reduction processes. These solutions have been reported to exhibit seemingly anomalous physical characteristics that lack a comprehensive explanation. ln the current work, the physical chemistry of molten solutions of lithium chloride and metallic lithium, with and without lithium oxide, was investigated using in situ Raman spectroscopy. The Raman spectra obtained from these solutions were in agreement with the previously reported spectrum of the lithium cluster, Li8. Furthermore, this observation is indicative of a nanofluid type colloidal suspension of Li8, in a molten salt matrix.more » It is suggested that the formation and suspension of lithium clusters in lithium chloride is the cause of various phenomena exhibited by these solutions that were previously unexplainable.« less

  13. SciDAC's Earth System Grid Center for Enabling Technologies Semiannual Progress Report October 1, 2010 through March 31, 2011

    SciTech Connect (OSTI)

    Williams, Dean N.

    2011-04-02

    This report summarizes work carried out by the Earth System Grid Center for Enabling Technologies (ESG-CET) from October 1, 2010 through March 31, 2011. It discusses ESG-CET highlights for the reporting period, overall progress, period goals, and collaborations, and lists papers and presentations. To learn more about our project and to find previous reports, please visit the ESG-CET Web sites: http://esg-pcmdi.llnl.gov/ and/or https://wiki.ucar.edu/display/esgcet/Home. This report will be forwarded to managers in the Department of Energy (DOE) Scientific Discovery through Advanced Computing (SciDAC) program and the Office of Biological and Environmental Research (OBER), as well as national and international collaborators and stakeholders (e.g., those involved in the Coupled Model Intercomparison Project, phase 5 (CMIP5) for the Intergovernmental Panel on Climate Change (IPCC) 5th Assessment Report (AR5); the Community Earth System Model (CESM); the Climate Science Computational End Station (CCES); SciDAC II: A Scalable and Extensible Earth System Model for Climate Change Science; the North American Regional Climate Change Assessment Program (NARCCAP); the Atmospheric Radiation Measurement (ARM) program; the National Aeronautics and Space Administration (NASA), the National Oceanic and Atmospheric Administration (NOAA)), and also to researchers working on a variety of other climate model and observation evaluation activities. The ESG-CET executive committee consists of Dean N. Williams, Lawrence Livermore National Laboratory (LLNL); Ian Foster, Argonne National Laboratory (ANL); and Don Middleton, National Center for Atmospheric Research (NCAR). The ESG-CET team is a group of researchers and scientists with diverse domain knowledge, whose home institutions include eight laboratories and two universities: ANL, Los Alamos National Laboratory (LANL), Lawrence Berkeley National Laboratory (LBNL), LLNL, NASA/Jet Propulsion Laboratory (JPL), NCAR, Oak Ridge National

  14. Vehicle Technologies Office Merit Review 2015: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li-ion cells for...

  15. Vehicle Technologies Office Merit Review 2014: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis Energy, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li...

  16. 6Li Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    α, X) (Current as of 02/01/2016) NSR Reaction Eα (MeV) Cross Section File X4 Dataset Date Added 1985NE05 6Li(α, γ): γ thick target yield resonance X4 02/15/2012 1966FO05 6Li(α, γ): σ 0.9 - 3.0 2 < Eγ < 4 MeV, 4 < Eγ < 7 MeV, thick target capture γ-ray yield, capture γ-ray yield of 2.43 MeV resonance 02/29/2012 1989BA24 6Li(α, γ): σ 1.085, 1.175 X4 02/15/2012 1979SP01 6Li(α, γ): thick target yield curve for 718 keV γ-rays 1140 - 1250 keV 1175 keV resonance 07/19/2011

  17. 6Li Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p, X) (Current as of 03012016) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 2004TU02 6Li(p, ): coincidence yields, deduced S-factors low 1, S-factors from ...

  18. 7Li Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p, X) (Current as of 12162015) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 1997GO13 7Li(pol. p, ): total , S-factor for capture to third-excited state 0 - ...

  19. Li2OHCl crystalline electrolyte for stable metallic lithium anodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hood, Zachary D.; Wang, Hui; Samuthira Pandian, Amaresh; Keum, Jong Kahk; Liang, Chengdu

    2016-01-22

    In a classic example of stability from instability, we show that Li2OHCl solid electrolyte forms a stable solid electrolyte interface (SEI) with metallic lithium anode. The Li2OHCl solid electrolyte can be readily achieved through simple mixing of air-stable LiOH and LiCl precursors with a mild processing temperature under 400 °C. Additionally, we show that continuous, dense Li2OHCl membranes can be fabricated at temperatures less than 400 °C, standing in great contrast to current processing temperatures of over 1600 °C for most oxide-based solid electrolytes. The ionic conductivity and Arrhenius activation energy were explored for the LiOH-LiCl system of crystalline solidmore » electrolytes where Li2OHCl with increased crystal defects was found to have the highest ionic conductivity and reasonable Arrhenius activation energy. The Li2OHCl solid electrolyte displays stability against metallic lithium, even in extreme conditions past the melting point of lithium metal. Furthermore, to understand this excellent stability, we show that SEI formation is critical in stabilizing the interface between metallic lithium and the Li2OHCl solid electrolyte.« less

  20. Li-Z

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Cloud Spectral Radiance/Irradiance at the Surface and Top-of-the-Atmosphere from Modeling and Observations Z. Li and A. Trishchenko Canada Centre for Remote Sensing Ottawa, Ontario, Canada M. Cribb Intermap Technologies Ltd. Ottawa, Ontario, Canada Introduction In view of some reported discrepancies concerning cloud parameter retrievals and cloud absorption (Stephens and Tsay 1990; Li et al. 1999; Rossow and Schiffer 1999) it is useful to compare cloud spectral signatures derived

  1. 10Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 10Li is subdivided into the following categories: Reviews Theoretical Ground State Properties Shell Model Cluster Model Other Models Special States Astrophysical Electromagnetic Transitions Hypernuclei Photodisintegration Light-Ion and Neutron Induced Reactions These General Tables correspond to the 2003 preliminary evaluation of ``Energy Levels of Light Nuclei, A = 10''. The prepublication version of A = 10 is available on this website in PDF format: A =

  2. EarthEnergy Limited | Open Energy Information

    Open Energy Info (EERE)

    Cornwall, United Kingdom Product: EarthEnergy Systems specialises in ground source heat pump systems. References: EarthEnergy Limited1 This article is a stub. You can help OpenEI...

  3. Earth System Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Primary Expertise Atmospheric, climate, and ecosystem science Geology, geochemistry, and ... utilization and storage Next Generation Ecosystem Experiment: examines Arctic permafrost ...

  4. Climate & Earth Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicle Buyer's Guide Clean Cities Biodiesel Ethanol Flex-Fuel Hybrid Electric Plug-In Hybrid All-Electric Hydrogen Fuel Cell Propane Natural Gas Disclaimers This report was prepared as an account of work sponsored by an agency of the United States govern- ment. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any

  5. SciDAC's Earth System Grid Center for Enabling Technologies Semi-Annual Progress Report for the Period October 1, 2009 through March 31, 2010

    SciTech Connect (OSTI)

    Williams, Dean N.; Foster, I. T.; Middleton, D. E.; Ananthakrishnan, R.; Siebenlist, F.; Shoshani, A.; Sim, A.; Bell, G.; Drach, R.; Ahrens, J.; Jones, P.; Brown, D.; Chastang, J.; Cinquini, L.; Fox, P.; Harper, D.; Hook, N.; Nienhouse, E.; Strand, G.; West, P.; Wilcox, H.; Wilhelmi, N.; Zednik, S.; Hankin, S.; Schweitzer, R.; Bernholdt, D.; Chen, M.; Miller, R.; Shipman, G.; Wang, F.; Bharathi, S.; Chervenak, A.; Schuler, R.; Su, M.

    2010-04-21

    This report summarizes work carried out by the ESG-CET during the period October 1, 2009 through March 31, 2009. It includes discussion of highlights, overall progress, period goals, collaborations, papers, and presentations. To learn more about our project, and to find previous reports, please visit the Earth System Grid Center for Enabling Technologies (ESG-CET) website. This report will be forwarded to the DOE SciDAC program management, the Office of Biological and Environmental Research (OBER) program management, national and international collaborators and stakeholders (e.g., the Community Climate System Model (CCSM), the Intergovernmental Panel on Climate Change (IPCC) 5th Assessment Report (AR5), the Climate Science Computational End Station (CCES), the SciDAC II: A Scalable and Extensible Earth System Model for Climate Change Science, the North American Regional Climate Change Assessment Program (NARCCAP), and other wide-ranging climate model evaluation activities).

  6. Feasibility of a superhigh energy-density battery of the Li/BrF sub 3 electrochemical system. Technical report

    SciTech Connect (OSTI)

    Pyszczek, M.F.; Ebel, S.J.; Frysz, C.A.

    1989-01-01

    To date, design and construction of a material-handling and measurement system along with the apparatus required for waste material disposal has been completed. Preliminary corrosion screening of potential case materials is currently underway. A review of the literature, has led us to the use of Monel (trademark) 400 as the material of construction for the handling and measurement system. The inherent stability of this material with bromine trifluoride in its liquid state is crucial to ensure that contamination does not occur during storage and handling. For applications which require a flexible or transparent material, items fabricated from perfluoroalkyoxy polymers (Teflon) (trademark PFA) were utilized. One such application encountered was in the design of the graduated tank which allows visual inspection of the material prior to dispensing. Containers used for compatibility/corrosion testing were also constructed of PFA.

  7. Description and Evaluation of Tropospheric Chemistry and Aerosols in the Community Earth System Model (CESM1.2)

    SciTech Connect (OSTI)

    Tilmes, S.; Lamarque, J. -F.; Emmons, L.; Kinnison, Douglas E.; Ma, Po-Lun; Liu, Xiaohong; Ghan, Steven J.; Bardeen, C.; Arnold, S.; Deeter, M.; Vitt, Francis; Ryerson, T. B.; Elkins, J. W.; Moore, F.; Spackman, R.; Martin, M. V.

    2015-05-13

    The Community Atmosphere Model (CAM), version 5, is now coupled to extensive tropospheric and stratospheric chemistry, called CAM5-chem, and is available in addition to CAM4-chem in the Community Earth System Model (CESM) version 1.2. Both configurations are well suited as tools for atmospheric-chemistry modeling studies in the troposphere and lower stratosphere, whether with internally derived “free running” (FR) meteorology, or “specified dynamics” (SD). The main focus of this paper is to compare the performance of these configurations against observations from surface, aircraft, and satellite, as well as understand the origin of the identified differences. We particularly focus on comparing present-day methane lifetime estimates within the different model configurations, which range between 7.8 years in the SD configuration of CAM5-chem and 8.8 years in the FR configuration of CAM4-chem. We find that tropospheric surface area density is an important factor in controlling the burden of the hydroxyl radical (OH), which causes differences in tropical methane lifetime of about half a year between CAM4-chem and CAM5-chem. In addition, different distributions of nitrogen oxides (NOx) produced from lightning production explain about half of the difference between SD and FR model versions in both CAM4-chem and CAM5-chem. Remaining differences in the tropical OH burden are due to enhanced tropical ozone burden in SD configurations compared to the FR versions, which are not only caused by differences in chemical production or loss, but also by transport and mixing. For future studies, we recommend the use of CAM5-chem, due to improved aerosol description and inclusion of aerosol-cloud interactions. However, smaller tropospheric surface area density in the current version of CAM5-chem compared to CAM4-chem results in larger oxidizing capacity in the troposphere and therefore a shorter methane lifetime.

  8. Description and Evaluation of Tropospheric Chemistry and Aerosols in the Community Earth System Model (CESM1.2)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tilmes, S.; Lamarque, J. -F.; Emmons, L.; Kinnison, Douglas E.; Ma, Po-Lun; Liu, Xiaohong; Ghan, Steven J.; Bardeen, C.; Arnold, S.; Deeter, M.; et al

    2015-05-13

    The Community Atmosphere Model (CAM), version 5, is now coupled to extensive tropospheric and stratospheric chemistry, called CAM5-chem, and is available in addition to CAM4-chem in the Community Earth System Model (CESM) version 1.2. Both configurations are well suited as tools for atmospheric-chemistry modeling studies in the troposphere and lower stratosphere, whether with internally derived “free running” (FR) meteorology, or “specified dynamics” (SD). The main focus of this paper is to compare the performance of these configurations against observations from surface, aircraft, and satellite, as well as understand the origin of the identified differences. We particularly focus on comparing present-daymore » methane lifetime estimates within the different model configurations, which range between 7.8 years in the SD configuration of CAM5-chem and 8.8 years in the FR configuration of CAM4-chem. We find that tropospheric surface area density is an important factor in controlling the burden of the hydroxyl radical (OH), which causes differences in tropical methane lifetime of about half a year between CAM4-chem and CAM5-chem. In addition, different distributions of nitrogen oxides (NOx) produced from lightning production explain about half of the difference between SD and FR model versions in both CAM4-chem and CAM5-chem. Remaining differences in the tropical OH burden are due to enhanced tropical ozone burden in SD configurations compared to the FR versions, which are not only caused by differences in chemical production or loss, but also by transport and mixing. For future studies, we recommend the use of CAM5-chem, due to improved aerosol description and inclusion of aerosol-cloud interactions. However, smaller tropospheric surface area density in the current version of CAM5-chem compared to CAM4-chem results in larger oxidizing capacity in the troposphere and therefore a shorter methane lifetime.« less

  9. Differences in carbon cycle and temperature projections from emission- and concentration-driven earth system model simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, P.; Zeng, X.; Zeng, X.

    2014-08-29

    The influence of prognostic and prescribed atmospheric CO2 concentrations ([CO2]) on the carbon uptake and temperature is investigated using all eight Earth System Models (ESMs) with relevant output variables from the Coupled Model Intercomparison Project Phase 5 (CMIP5). Under the RCP8.5 scenario, the projected [CO2] differences in 2100 vary from -19.7 to +207.3 ppm in emission-driven ESMs. Incorporation of the interactive concentrations also increases the range of global warming, computed as the 20 year average difference between 20812100 and 18501869/18611880, by 49% from 2.36 K (i.e. ranging from 3.11 to 5.47 K) in the concentration-driven simulations to 3.51 K inmorethe emission-driven simulations. The observed seasonal amplitude of global [CO2] from 19802011 is about 1.25.3 times as large as those from the eight emission-driven ESMs, while the [CO2] seasonality is simply neglected in concentration-driven ESMs, suggesting the urgent need of ESM improvements in this area. The temperature-concentration feedback parameter ? is more sensitive to [CO2] (e.g. during 19802005 versus 20752100) than how [CO2] is handled (i.e. prognostic versus prescribed). This sensitivity can be substantially reduced by using a more appropriate parameter ?' computed from the linear regression of temperature change versus that of the logarithm of [CO2]. However, the inter-model relative variations of both ? and ?' remain large, suggesting the need of more detailed studies to understand and hopefully reduce these discrepancies.less

  10. Representation of the Community Earth System Model (CESM1) CAM4-chem within the Chemistry-Climate Model Initiative (CCMI)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tilmes, Simone; Lamarque, Jean -Francois; Emmons, Louisa K.; Kinnison, Doug E.; Marsh, Dan; Garcia, Rolando R.; Smith, Anne K.; Neely, Ryan R.; Conley, Andrew; Vitt, Francis; et al

    2016-05-20

    The Community Earth System Model (CESM1) CAM4-chem has been used to perform the Chemistry Climate Model Initiative (CCMI) reference and sensitivity simulations. In this model, the Community Atmospheric Model version 4 (CAM4) is fully coupled to tropospheric and stratospheric chemistry. Details and specifics of each configuration, including new developments and improvements are described. CESM1 CAM4-chem is a low-top model that reaches up to approximately 40 km and uses a horizontal resolution of 1.9° latitude and 2.5° longitude. For the specified dynamics experiments, the model is nudged to Modern-Era Retrospective Analysis for Research and Applications (MERRA) reanalysis. We summarize the performance ofmore » the three reference simulations suggested by CCMI, with a focus on the last 15 years of the simulation when most observations are available. Comparisons with selected data sets are employed to demonstrate the general performance of the model. We highlight new data sets that are suited for multi-model evaluation studies. Most important improvements of the model are the treatment of stratospheric aerosols and the corresponding adjustments for radiation and optics, the updated chemistry scheme including improved polar chemistry and stratospheric dynamics and improved dry deposition rates. These updates lead to a very good representation of tropospheric ozone within 20 % of values from available observations for most regions. In particular, the trend and magnitude of surface ozone is much improved compared to earlier versions of the model. Furthermore, stratospheric column ozone of the Southern Hemisphere in winter and spring is reasonably well represented. In conclusion, all experiments still underestimate CO most significantly in Northern Hemisphere spring and show a significant underestimation of hydrocarbons based on surface observations.« less

  11. A Generic Biogeochemical Module for Earth System Models: Next Generation BioGeoChemical Module (NGBGC), Version 1.0

    SciTech Connect (OSTI)

    Fang, Yilin; Huang, Maoyi; Liu, Chongxuan; Li, Hongyi; Leung, Lai-Yung R.

    2013-11-13

    Physical and biogeochemical processes regulate soil carbon dynamics and CO2 flux to and from atmosphere, influencing global climate changes. Integration of these processes into earth system models (e.g., community land models (CLM)), however, currently faces three major challenges: 1) extensive efforts are required to modify modeling structures and to rewrite computer programs to incorporate new or updated processes as new knowledge is being generated, 2) computational cost is prohibitively expensive to simulate biogeochemical processes in land models due to large variations in the rates of biogeochemical processes, and 3) various mathematical representations of biogeochemical processes exist to incorporate different aspects of fundamental mechanisms, but systematic evaluation of the different mathematical representations is difficult, if not possible. To address these challenges, we propose a new computational framework to easily incorporate physical and biogeochemical processes into land models. The new framework consists of a new biogeochemical module with a generic algorithm and reaction database so that new and updated processes can be incorporated into land models without the need to manually set up the ordinary differential equations to be solved numerically. The reaction database consists of processes of nutrient flow through the terrestrial ecosystems in plants, litter and soil. This framework facilitates effective comparison studies of biogeochemical cycles in an ecosystem using different conceptual models under the same land modeling framework. The approach was first implemented in CLM and benchmarked against simulations from the original CLM-CN code. A case study was then provided to demonstrate the advantages of using the new approach to incorporate a phosphorus cycle into the CLM model. To our knowledge, the phosphorus-incorporated CLM is a new model that can be used to simulate phosphorus limitation on the productivity of terrestrial ecosystems.

  12. Description and Evaluation of Tropospheric Chemistry and Aerosols in the Community Earth System Model (CESM1.2)

    SciTech Connect (OSTI)

    Tilmes, S.; Lamarque, J.-F.; Emmons, L.; Kinnison, Douglas E.; Ma, Po-Lun; Liu, Xiaohong; Ghan, Steven J.; Bardeen, C.; Arnold, S.; Deeter, M.; Vitt, Francis; Ryerson, T. B.; Elkins, J. W.; Moore, F.; Spackman, R.; Martin, M. V.

    2015-01-01

    The Community Atmosphere Model (CAM), version 5, is now coupled to extensive tropospheric and stratospheric chemistry, called CAM5-chem, and is available in addition to CAM4-chem in the Community Earth System Model (CESM) version 1.2. Both configurations are well suited as tools for atmospheric-chemistry modeling studies in the troposphere and lower stratosphere, whether with internally derived free running (FR) meteorology, or specified dynamics (SD). The main focus of this paper is to compare the performance of these configurations against observations from surface, aircraft, and satellite, as well as understand the origin of the identified differences. We particularly focus on comparing present-day methane lifetime estimates within the different model configurations, which range between 7.8 years in the SD configuration of CAM5-chem and 8.8 years in the FR configuration of CAM4-chem. We find that tropospheric surface area density is an important factor in controlling the burden of the hydroxyl radical (OH), which causes differences in tropical methane lifetime of about half a year between CAM4-chem and CAM5-chem. In addition, different distributions of nitrogen oxides (NOx) produced from lightning production explain about half of the difference between SD and FR model versions in both CAM4-chem and CAM5-chem. Remaining differences in the tropical OH burden are due to enhanced tropical ozone burden in SD configurations compared to the FR versions, which are not only caused by differences in chemical production or loss, but also by transport and mixing. For future studies, we recommend the use of CAM5-chem, due to improved aerosol description and inclusion of aerosol-cloud interactions. However, smaller tropospheric surface area density in the current version of CAM5-chem compared to CAM4-chem results in larger oxidizing capacity in the troposphere and therefore a shorter methane lifetime.

  13. Li Tec | Open Energy Information

    Open Energy Info (EERE)

    Drezden, Germany Product: Based in Kamez, near Dresden, Li-Tec produces components for lithium-ion batteries. References: Li-Tec1 This article is a stub. You can help OpenEI by...

  14. Final Report. Evaluating the Climate Sensitivity of Dissipative Subgrid-Scale Mixing Processes and Variable Resolution in NCAR's Community Earth System Model

    SciTech Connect (OSTI)

    Jablonowski, Christiane

    2015-12-14

    The goals of this project were to (1) assess and quantify the sensitivity and scale-dependency of unresolved subgrid-scale mixing processes in NCAR’s Community Earth System Model (CESM), and (2) to improve the accuracy and skill of forthcoming CESM configurations on modern cubed-sphere and variable-resolution computational grids. The research thereby contributed to the description and quantification of uncertainties in CESM’s dynamical cores and their physics-dynamics interactions.

  15. Center for Space and Earth Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Institute of Geophysics, Planetary Physics, and Signatures Center for Space and Earth Science Promoting and supporting high-quality, cutting-edge science in the areas of astrophysics, space physics, solid planetary geoscience, and climate science. Contact Director Reiner Friedel (505) 665-1936 Email Professional Staff Assistant Georgia Sanchez (505) 665-0855 Email Astophysics and Cosmology Hui Li (505) 665-3131 Email Climate Keeley Costigan (505) 665-4788 Email Geophysics David Coblentz (505)

  16. Google Earth Tour: Contaminants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Google Earth Tour: Contaminants Google Earth Tour: Contaminants Historical operations used the best available waste handling methods for that time.

  17. Correlation of anisotropy and directional conduction in β-Li3PS4 fast Li+ conductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Yan; Cai, Lu; Liu, Zengcai; dela Cruz, Clarina R.; Liang, Chengdu; An, Ke

    2015-07-06

    Our letter reports the correlation of anisotropy and directional conduction in the fast Li+ conductor β-Li3PS4, one of the low-symmetry crystalline electrolyte candidates. The material has both high conductivity and good stability that serves well for the large-scale energy storage applications of all-solid-state lithium ion batteries. The anisotropic physical properties, demonstrated here by the thermal expansion coefficients, are crucial for compatibility in the solid-state system and battery performance. Neutron and X-ray powder diffraction measurements were done to determine the crystal structure and thermal stability. Moreover, the crystallographic b-axis was revealed as a fast expansion direction, while negligible thermal expansion wasmore » observed along the a-axis around the battery operating temperatures. The anisotropic behavior has its structural origin from the Li+ conduction channels with incomplete Li occupancy and a flexible connection of LiS4 and PS4 tetrahedra within the framework. This indicates a strong correlation in the direction of the ionic transport in the low-symmetry Li+ conductor.« less

  18. Electrochemical Study on the Electrodeposition of U, Nd, Ce, La and Y on a Liquid Cadmium Cathode in a LiCl-KCl Eutectic Salt

    SciTech Connect (OSTI)

    Sung Bin Park; Jong Hyeon Lee; Sung Chan Hwang; Young Ho Kang; Joon Bo Shim; Han Soo Lee; Eung Ho Kim; Seong Won Park

    2007-07-01

    Electro-depositions of U, Nd, Ce, La and Y on a liquid cadmium cathode in a LiCl-KCl eutectic salt were studied by using an electrolytic cell. For the LiCl-KCl-UCl{sub 3}- NdCl{sub 3}-CeCl{sub 3}-LaCl{sub 3}-YCl{sub 3}/Cd system, cyclic voltammograms and polarization curves were measured and the electrochemical properties of the system were discussed. From the results of the electro-depositions of U and rare earth metals on the LCC, separation factors and recovery ratios of U and REs were obtained and co-electro-depositions of U and REs were investigated. (authors)

  19. Polymer electrolytes for a rechargeable li-Ion battery

    SciTech Connect (OSTI)

    Argade, S.D.; Saraswat, A.K.; Rao, B.M.L.; Lee, H.S.; Xiang, C.L.; McBreen, J.

    1996-10-01

    Lithium-ion polymer electrolyte battery technology is attractive for many consumer and military applications. A Li{sub x}C/Li{sub y}Mn{sub 2}O{sub 4} battery system incorporating a polymer electrolyte separator base on novel Li-imide salts is being developed under sponsorship of US Army Research Laboratory (Fort Monmouth NJ). This paper reports on work currently in progress on synthesis of Li-imide salts, polymer electrolyte films incorporating these salts, and development of electrodes and cells. A number of Li salts have been synthesized and characterized. These salts appear to have good voltaic stability. PVDF polymer gel electrolytes based on these salts have exhibited conductivities in the range 10{sup -4} to 10{sub -3} S/cm.

  20. Optically pumped cerium-doped LiSrAlF.sub.6 and LiCaAlF.sub.6

    DOE Patents [OSTI]

    Marshall, Christopher D.; Payne, Stephen A.; Krupke, William F.

    1996-01-01

    Ce.sup.3+ -doped LiSrAlF.sub.6 crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF.sub.6 with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF.sub.6 type of chemical formula, e.g. Ce-doped LiCaAlF.sub.6 and LiSrGaF.sub.6, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator.

  1. Optically pumped cerium-doped LiSrAlF{sub 6} and LiCaAlF{sub 6}

    DOE Patents [OSTI]

    Marshall, C.D.; Payne, S.A.; Krupke, W.F.

    1996-05-14

    Ce{sup 3+}-doped LiSrAlF{sub 6} crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF{sub 6} with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF{sub 6} type of chemical formula, e.g. Ce-doped LiCaAlF{sub 6} and LiSrGaF{sub 6}, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator. 10 figs.

  2. Isothermal evaporation process simulation using the Pitzer model for the Quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Lingzong; Gruszkiewicz, Miroslaw S.; Deng, Tianlong; Guo, Yafei; Li, Dan

    2015-08-05

    In this study, the Pitzer thermodynamic model for solid-liquid equilibria in the quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K was constructed by selecting the proper parameters for the subsystems in the literature. The solubility data of the systems NaCl–SrCl2–H2O, KCl–SrCl2–H2O, LiCl–SrCl2–H2O, and NaCl–KCl–SrCl2–H2O were used to evaluate the model. Good agreement between the experimental and calculated solubilities shows that the model is reliable. The Pitzer model for the quinary system at 298.15 K was then used to calculate the component solubilities and conduct computer simulation of isothermal evaporation of the mother liquor for the oilfield brine from Nanyishan district in themore » Qaidam Basin. The evaporation-crystallization path and sequence of salt precipitation, change in concentration and precipitation of lithium, sodium, potassium, and strontium, and water activities during the evaporation process were demonstrated. The salts precipitated from the brine in the order : KCl, NaCl, SrCl2∙6H2O, SrCl2∙2H2O, and LiCl∙H2O. The entire evaporation process may be divided into six stages. In each stage the variation trends for the relationships between ion concentrations or water activities and the evaporation ratio are different. This result of the simulation of brines can be used as a theoretical reference for comprehensive exploitation and utilization of this type of brine resources.« less

  3. Direct observation of the redistribution of sulfur and polysufides in Li-S batteries during first cycle by in situ X-Ray fluorescence microscopy

    SciTech Connect (OSTI)

    Yu, Xiquian; Pan, Huilin; Zhou, Yongning; Northrup, Paul; Xiao, Jie; Bak, Seongmin; Liu, Mingzhao; Nam, Kyung-Wan; Qu, Deyang; Liu, Jun; Wu, Tianpin; Yang, Xiao-Qing

    2015-03-25

    The demands on low cost and high energy density rechargeable batteries for both transportation and large-scale stationary energy storage are stimulating more and more research toward new battery systems. Since sulfur is an earth-abundant material with low cost, research on the high energy density LiS batteries (2600 W h kg?) are getting more and more attention. The reactions between sulfur and lithium during chargedischarge cycling are quite complicated, going through multiple electron transfer process associated with chemical and electrochemical equilibrium between long- and short-chain polysulfide Li?Sx intermediates (1 < x ? 8). It is reported that the long-chain polysulfides can be dissolved into electrolyte with aprotic organic solvents and migrated to the Li anode side. This so-called shuttle effect is believed to be the main reason for capacity loss and low columbic efficiency of the LiS batteries. In the past few years, a great deal of efforts have been made on how to overcome the problem of polysulfide dissolution through new sulfur electrode construction and cell designs, as well as the modification of the electrolyte. Although it has been reported by several publications that some LiS cells can sustain more than a thousand cycles based on the thin film electrode configurations, the long-term cycling stability is still one of the major barriers for the real application of LiS batteries. More in-depth studies on the fundamental understanding of the sulfur reaction mechanism and interactions among the different polysulfide species, the electrolyte and the electrodes are still greatly needed. Various in situ techniques have been developed and applied to study the mechanism of the sulfur chemistry in LiS batteries during electrochemical cycling, such as transmission X-ray microscopy (TXM), X-ray absorption spectroscopy (XAS), X-ray diffraction (XRD), UVvisible spectroscopy, and electron paramagnetic resonance (EPR). The applications of

  4. I!' L;I)

    Office of Legacy Management (LM)

    ".>;jy i.~jp.~[~~ i,Zz>-c C,+;) ir,i:%J :' 0 p 'd-i I /) f) ic.c iq -.I ,'c i - * w. 3'2 , phi ': r-t;, ; *.i .; I!' L;I) --, -II s;.,yE;J-~,~;~* I' ;, f: >,p.yg ,p ' .L (3 i!>;' !i.3 y/y!-; x>:-y rJgbf;..qp: \' :sF*:l,' 5-".13, -9 _ ..-;~c~-' ~;Li;-~~~~;, 3h' ;[;i-y ; c; ' 1' 1.b y&k' 2 1 , . ..l =i. 1; G.1 ;Tr.; .j. i-:. I qr:i.gky, M,C. Jp, 2.1 F... ii, Ross CENTRAL F ILES ~"CTIVE OF TXIP m --w- The 0' 0 jet% ive Of this trip xas to evaluate tkie !- .zalth

  5. Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1–xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane→easy axis→easy plane→easy axis when progressing from T = Mn → Fe → Co → Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.more » As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.« less

  6. Alternating magnetic anisotropy of Li 2 ( Li 1 - x T x ) N ( T = Mn , Fe , Co , and Ni )

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-01

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li?(Li1-xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.moreThe calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.less

  7. Alternating magnetic anisotropy of Li2(Li1xTx)N(T=Mn,Fe,Co,andNi)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.moreAs a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.less

  8. Performance of LiAlloy/Ag(2)CrO(4) Couples in Molten CsBr-LiBr-KBr Eutectic

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    1999-10-18

    The performance of Li-alloy/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} systems was studied over a temperature range of 250 C to 300 C, for possible use as a power source for geothermal borehole applications. Single cells were discharged at current densities of 15.8 and 32.6 mA/cm{sup 2} using Li-Si and Li-Al anodes. When tested in 5-cell batteries, the Li-Si/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} system exhibited thermal runaway. Thermal analytical tests showed that the Ag{sub 2}CrO{sub 4} cathode reacted exothermically with the electrolyte on activation. Consequently, this system would not be practical for the envisioned geothermal borehole applications.

  9. 7Li MRI of Li batteries reveals location of microstructural lithium...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: 7Li MRI of Li batteries reveals location of microstructural lithium Citation Details In-Document Search Title: 7Li MRI of Li ...

  10. Rare-Earth-Free Nanostructure Magnets: Rare-Earth-Free Permanent Magnets for Electric Vehicle Motors and Wind Turbine Generators: Hexagonal Symmetry Based Materials Systems Mn-Bi and M-type Hexaferrite

    SciTech Connect (OSTI)

    2012-01-01

    REACT Project: The University of Alabama is developing new iron- and manganese-based composite materials for use in the electric motors of EVs and renewable power generators that will demonstrate magnetic properties superior to todays best rare-earth-based magnets. Rare earths are difficult and expensive to refine. EVs and renewable power generators typically use rare earths to make their electric motors smaller and more powerful. The University of Alabama has the potential to improve upon the performance of current state-of-the-art rare-earth-based magnets using low-cost and more abundant materials such as manganese and iron. The ultimate goal of this project is to demonstrate improved performance in a full-size prototype magnet at reduced cost.

  11. Computational Earth Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 Computational Earth Science We develop and apply a range of high-performance computational methods and software tools to Earth science projects in support of environmental ...

  12. Google Earth Tour: Contaminants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Google Earth Tour: Contaminants Google Earth Tour: Contaminants Historical operations used the best available waste handling methods for that time. Open full screen to view more...

  13. Earth and Environmental Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EES Earth and Environmental Sciences (EES) Sustainable energy, climate impacts, nuclear threat detection, and environmental management are primary focus areas of earth and...

  14. UJ LiJ

    Office of Legacy Management (LM)

    o >- tD o UJ :> LiJ o W ~ Central Nevada-23 UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY Federal Center, Denver, Colorado 80225 ANALYSIS OF HYDRAULIC TESTS IN HOT CREEK VALLEY, NEVADA June 1970 Open-file report Prepared Under Contract AT(29-2)-474 for the Nevada Operations Office U.S. Atomic Energy Commission USGS-474-82 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor

  15. A=11Li (2012KE01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E(11Li) 246 MeVA, analysis of a complete three-body kinematical measurement of 11Li breakup on a 12C target indicates the reaction mechanism is 11Li inelastic scattering to...

  16. Through-the-earth radio

    DOE Patents [OSTI]

    Reagor, David; Vasquez-Dominguez, Jose

    2006-12-12

    A through-the-earth communication system that includes a digital signal input device; a transmitter operating at a predetermined frequency sufficiently low to effectively penetrate useful distances through-the earth; a data compression circuit that is connected to an encoding processor; an amplifier that receives encoded output from the encoding processor for amplifying the output and transmitting the data to an antenna; and a receiver with an antenna, a band pass filter, a decoding processor, and a data decompressor.

  17. Atomistic Modeling of the Electrode-Electrolyte Interface in Li-Ion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Systems: Electrolyte Structuring | Argonne Leadership Computing Facility Atomistic Modeling of the Electrode-Electrolyte Interface in Li-Ion Energy Storage Systems: Electrolyte Structuring Authors: Ryan Jorn, Revati Kumar, Daniel P. Abraham, Gregory A. Voth The solid electrolyte interface (SEI) forms as a result of side reactions between the electrolyte and electrode surfaces in Li-ion batteries and can adversely impact performance by impeding Li-ion transport and diminishing

  18. Lithium salts for advanced lithium batteries: Li-metal, Li-O2, and Li-S

    SciTech Connect (OSTI)

    Younesi, Reza; Veith, Gabriel M.; Johansson, Patrik; Edstrom, Kristina; Vegge, Tejs

    2015-06-01

    Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions and conditions within such cells. Furthermore, this review explores the critical role Li-salts play in ensuring in these batteries viability.

  19. Lithium salts for advanced lithium batteries: Li-metal, Li-O2, and Li-S

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Younesi, Reza; Veith, Gabriel M.; Johansson, Patrik; Edstrom, Kristina; Vegge, Tejs

    2015-06-01

    Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions andmore » conditions within such cells. Furthermore, this review explores the critical role Li-salts play in ensuring in these batteries viability.« less

  20. Lithium Salts for Advanced Lithium Batteries: Li-metal, Li-O2, and Li-S

    SciTech Connect (OSTI)

    Younesi, Reza; Veith, Gabriel M; Johansson, Patrik; Edstrom, Kristina; Vegge, Tejs

    2015-01-01

    Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions and conditions within such cells. This review explores the critical role Li-salts play in ensuring in these batteries viability.

  1. Partitioning and Leaching Behavior of Actinides and Rare Earth Elements in a Zirconolite- Bearing Hydrothermal Vein System

    SciTech Connect (OSTI)

    Payne, Timothy E.; Hart, Kaye P.; Lumpkin, Gregory R.; McGlinn, Peter J.; Giere, Reto

    2007-07-01

    Chemical extraction techniques and scanning electron microscopy were used to study the distribution and behavior of actinides and rare earth elements (REE) in hydrothermal veins at Adamello (Italy). The six samples discussed in this paper were from the phlogopite zone, which is one of the major vein zones. The samples were similar in their bulk chemical composition, mineralogy, and leaching behavior of major elements (determined by extraction with 9 M HCl). However, there were major differences in the extractability of REE and actinides. The most significant influence on the leaching characteristics appears to be the amounts of U, Th and REE incorporated in resistant host phases (zirconolite and titanite) rather than readily leached phases (such as apatite). Uranium and Th are very highly enriched in zirconolite grains. Actinides were more readily leached from samples with a higher content of U and Th, relative to the amount of zirconium. The results show that REE and actinides present in chemically resistant host minerals can be retained under aggressive leaching conditions. (authors)

  2. Earth coupled cooling techniques

    SciTech Connect (OSTI)

    Grondzik, W.T.; Boyer, L.L.; Johnston, T.L.

    1981-01-01

    Earth coupled cooling is an important consideration for residential and commercial designers, owners, and builders in many regions of the country. The potential benefits which can be expected from passive earth contact cooling are reviewed. Recommendations for the design of earth sheltered structures incorporating earth coupled cooling strategies are also presented.

  3. Recovery of Li from alloys of Al- Li and Li- Al using engineered scavenger compounds

    DOE Patents [OSTI]

    Riley, W. D.; Jong, B. W.; Collins, W. K.; Gerdemann, S. J.

    1994-01-01

    A method of producing lithium of high purity from lithium aluminum alloys using an engineered scavenger compound, comprising: I) preparing an engineered scavenger compound by: a) mixing and heating compounds of TiO2 and Li2CO3 at a temperature sufficient to dry the compounds and convert Li.sub.2 CO.sub.3 to Li.sub.2 O; and b) mixing and heating the compounds at a temperature sufficient to produce a scavenger Li.sub.2 O.3TiO.sub.2 compound; II) loading the scavenger into one of two electrode baskets in a three electrode cell reactor and placing an Al-Li alloy in a second electrode basket of the three electrode cell reactor; III) heating the cell to a temperature sufficient to enable a mixture of KCl-LiCl contained in a crucible in the cell to reach its melting point and become a molten bath; IV) immersing the baskets in the bath until an electrical connection is made between the baskets to charge the scavenger compound with Li until there is an initial current and voltage followed by a fall off ending current and voltage; and V) making a connection between the basket electrode containing engineered scavenger compound and a steel rod electrode disposed between the basket electrodes and applying a current to cause Li to leave the scavenger compound and become electrodeposited on the steel rod electrode.

  4. CoolEarth formerly Cool Earth Solar | Open Energy Information

    Open Energy Info (EERE)

    CoolEarth formerly Cool Earth Solar Jump to: navigation, search Name: CoolEarth (formerly Cool Earth Solar) Place: Livermore, California Zip: 94550 Product: CoolEarth is a...

  5. Precise trace rare earth analysis by radiochemical neutron activation

    SciTech Connect (OSTI)

    Laul, J.C.; Lepel, E.A.; Weimer, W.C.; Wogman, N.A.

    1981-06-01

    A rare earth group separation scheme followed by normal Ge(Li), low energy photon detector (LEPD), and Ge(Li)-NaI(Tl) coincidence-noncoincidence spectrometry significantly enhances the detection sensitivity of individual rare earth elements (REE) at or below the ppB level. Based on the selected ..gamma..-ray energies, normal Ge(Li) counting is favored for /sup 140/La, /sup 170/Tb, and /sup 169/Yb; LEPD is favored for low ..gamma..-ray energies of /sup 147/Nd, /sup 153/Sm, /sup 166/Ho, and /sup 169/Yb; and noncoincidence counting is favored for /sup 141/Ce, /sup 143/Ce, /sup 142/Pr, /sup 153/Sm, /sup 171/Er, and /sup 175/Yb. The detection of radionuclides /sup 152m/Eu, /sup 159/Gd, and /sup 177/Lu is equally sensitive by normal Ge(Li) and noncoincidence counting; /sup 152/Eu is equally sensitive by LEPD and normal Ge(Li); and /sup 153/Gd and /sup 170/Tm is equally favored by all the counting modes. Overall, noncoincidence counting is favored for most of the REE. Precise measurements of the REE were made in geological and biological standards.

  6. Earth, Space Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth, Space Sciences Earth, Space Sciences National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place on Earth pursues a broader array of world-class scientific endeavors. Climate, Ocean and Sea Ice Modeling (COSIM)» Earth and Environmental Sciences Division» Intelligence and Space Research» Earth Read caption + A team of scientists is working to understand how local changes in hydrology might bring about

  7. Analysis the configuration of earthing system based on high-low and low-high soil structure

    SciTech Connect (OSTI)

    Ramani, A. N.; Ahmad, Abdul Rahman; Sulaima, M. F.; Nasir, M. N. M.; Ahmad, Arfah

    2015-05-15

    Each TNB transmission tower requires a tower footing resistance (TFR) with a lower grounding resistance value that depends on the transmission line voltage. For 132kV and 275kV tower, the TFR must less than 10Ω and 500kV tower must less than 5Ω. The TFR is changeable with variable factors such as soil resistivity. Low TFR provides essential protection to the fault such as lightning strike that may occur at any time. The fault current flow to the lowest resistance path and easily disperses to earth. Back flashover voltage across the insulator of transmission lines may occur when the TFR is high. The TFR is influenced by soil resistivity. There are three parameters affecting the soil resistivity; moisture content, salt content and temperature of the soil. High moisture content in soil will reduce the soil resistivity and resultant low TFR. Small scale moisture control by using Micro Reservoir (MR) irrigation with semi-permeable membranes have the power to offer the stable moisture in soil. By using osmosis concept, it is the process of net movement of water molecules from high potential water to lower potential water though a semi permeable membrane. The MR can withstand for 3 to 5 days without continuous water supply. The MR installed in the centre of the tower that contains a multiple parallel of electrode rods. The concentrated of electrode rods grounding configuration with a combination of MR will improve the TFR even at multilayer soil. As a result, MR gives a little improvement to TFR. The MR in area of concentrated electrode rod configuration to ensure the soil always wet and moist at all times. The changes in soil affect the tower-footing-resistance. The tower-footing-resistance measurement at afternoon is higher than at evening because of the temperature and moisture content in soil is change due to sun radiation.

  8. MOA-2011-BLG-262Lb: A sub-Earth-mass moon orbiting a gas giant primary or a high velocity planetary system in the galactic Bulge

    SciTech Connect (OSTI)

    Bennett, D. P.; Batista, V.; Bond, I. A.; Ling, C. H.; Bennett, C. S.; Suzuki, D.; Koshimoto, N.; Beaulieu, J.-P.; Udalski, A.; Donatowicz, J.; Bozza, V.; Abe, F.; Fukunaga, D.; Itow, Y.; Masuda, K.; Matsubara, Y.; Muraki, Y.; Botzler, C. S.; Freeman, M.; Fukui, A.; Collaboration: MOA Collaboration; PLANET Collaboration; μFUN Collaboration; OGLE Collaboration; RoboNet Collaboration; and others

    2014-04-20

    We present the first microlensing candidate for a free-floating exoplanet-exomoon system, MOA-2011-BLG-262, with a primary lens mass of M {sub host} ∼ 4 Jupiter masses hosting a sub-Earth mass moon. The argument for an exomoon hinges on the system being relatively close to the Sun. The data constrain the product M{sub L} π{sub rel} where M{sub L} is the lens system mass and π{sub rel} is the lens-source relative parallax. If the lens system is nearby (large π{sub rel}), then M{sub L} is small (a few Jupiter masses) and the companion is a sub-Earth-mass exomoon. The best-fit solution has a large lens-source relative proper motion, μ{sub rel} = 19.6 ± 1.6 mas yr{sup –1}, which would rule out a distant lens system unless the source star has an unusually high proper motion. However, data from the OGLE collaboration nearly rule out a high source proper motion, so the exoplanet+exomoon model is the favored interpretation for the best fit model. However, there is an alternate solution that has a lower proper motion and fits the data almost as well. This solution is compatible with a distant (so stellar) host. A Bayesian analysis does not favor the exoplanet+exomoon interpretation, so Occam's razor favors a lens system in the bulge with host and companion masses of M{sub host}=0.12{sub −0.06}{sup +0.19} M{sub ⊙} and m{sub comp}=18{sub −10}{sup +28} M{sub ⊕}, at a projected separation of a{sub ⊥}=0.84{sub −0.14}{sup +0.25} AU. The existence of this degeneracy is an unlucky accident, so current microlensing experiments are in principle sensitive to exomoons. In some circumstances, it will be possible to definitively establish the mass of such lens systems through the microlensing parallax effect. Future experiments will be sensitive to less extreme exomoons.

  9. Analysis of Heat Dissipation in Li-Ion Cells & Modules for Modeling of Thermal Runaway (Presentation)

    SciTech Connect (OSTI)

    Kim, G.-H.; Pesaran, A.

    2007-05-15

    The objectives of this study are: (1) To develop 3D Li-Ion battery thermal abuse ''reaction'' models for cell and module analysis; (2) To understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-Ion cells and modules; (3) To develop a tool and methodology to support the design of abuse-tolerant Li-Ion battery systems for PHEVs/HEVs; and (4) To help battery developers accelerate delivery of abuse-tolerant Li-Ion battery systems in support of the FreedomCAR's Energy Storage Program.

  10. A=14Li (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    86AJ01) (Not illustrated) 14Li has not been observed. The calculated mass excess is 72.29 MeV: see (1981AJ01). 14Li is then particle unstable with respect to decay into 13Li + n and 12Li + 2n by 3.88 and 3.22 MeV, respectively

  11. A=15Li (1981AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1AJ01) (Not illustrated) 15Li has not been observed: its atomic mass excess is calculated to be 81.60 MeV. It is then unstable with respect to decay into 14Li + n and 13Li + 2n by 1.24 and 3.90 MeV, respectively (1974TH01). See also 13Li

  12. SciDAC's Earth System Grid Center for Enabling Technologies Semi-Annual Progress Report for the Period April 1, 2009 through September 30, 2009

    SciTech Connect (OSTI)

    Williams, Dean N.; Foster, I. T.; Middleton, D. E.

    2009-10-15

    This report summarizes work carried out by the ESG-CET during the period April 1, 2009 through September 30, 2009. It includes discussion of highlights, overall progress, period goals, collaborations, papers, and presentations. To learn more about our project, and to find previous reports, please visit the Earth System Grid Center for Enabling Technologies (ESG-CET) website. This report will be forwarded to the DOE SciDAC program management, the Office of Biological and Environmental Research (OBER) program management, national and international collaborators and stakeholders (e.g., the Community Climate System Model (CCSM), the Intergovernmental Panel on Climate Change (IPCC) 5th Assessment Report (AR5), the Climate Science Computational End Station (CCES), the SciDAC II: A Scalable and Extensible Earth System Model for Climate Change Science, the North American Regional Climate Change Assessment Program (NARCCAP), and other wide-ranging climate model evaluation activities). During this semi-annual reporting period, the ESG-CET team continued its efforts to complete software components needed for the ESG Gateway and Data Node. These components include: Data Versioning, Data Replication, DataMover-Lite (DML) and Bulk Data Mover (BDM), Metrics, Product Services, and Security, all joining together to form ESG-CET's first beta release. The launch of the beta release is scheduled for late October with the installation of ESG Gateways at NCAR and LLNL/PCMDI. Using the developed ESG Data Publisher, the ESG II CMIP3 (IPCC AR4) data holdings - approximately 35 TB - will be among the first datasets to be published into the new ESG enterprise system. In addition, the NCAR's ESG II data holdings will also be published into the new system - approximately 200 TB. This period also saw the testing of the ESG Data Node at various collaboration sites, including: the British Atmospheric Data Center (BADC), the Max-Planck-Institute for Meteorology, the University of Tokyo Center for

  13. Microsoft Word - li_abstract

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    will be served at 3:30 pm A few new issues regarding the density dependence of nuclear symmetry energy Professor Bao-An Li Department of Physics and Astronomy, Texas A&M ...

  14. Women @ Energy: Yan Li | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Yan Li Women @ Energy: Yan Li March 12, 2013 - 9:23am Addthis Yan Li is a Computational Physicist at the Computational Science Center at Brookhaven National Laboratory. Yan Li is a Computational Physicist at the Computational Science Center at Brookhaven National Laboratory. Yan Li is a Computational Physicist at the Computational Science Center at Brookhaven National Laboratory. Her work is mainly focused on developing and applying advanced computational tools to investigate material properties

  15. Liang Li | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liang Li Postdoctoral Appointee (Supervisor, Maria Chan) Current research focuses on ab-initio theoretical studies on hybrid lithium-ion/lithium-oxygen battery materials and photocatalytic reduction of CO2. News Visualizing Redox Dynamics of a Single Ag/AgCl Heterogeneous Nanocatalyst at Atomic Resolution Telephone 630.252.2788 Fax 630.252.4646 E-mail liangli@anl.gov CV/Resume PDF icon Liang_Li

  16. Anion Coordination Interactions in Solvates with the Lithium Salts LiDCTA and LiTDI

    SciTech Connect (OSTI)

    McOwen, Dennis W.; Delp, Samuel A.; Paillard, Elie; Herriot, Cristelle; Han, Sang D.; Boyle, Paul D.; Sommer, Roger D.; Henderson, Wesley A.

    2014-04-17

    Lithium 4,5-dicyano-1,2,3-triazolate (LiDCTA) and lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI) are two salts proposed for lithium battery electrolyte applications, but little is known about the manner in which the DCTA- and TDI- anions coordinate Li+ cations. To explore this in-depth, crystal structures are reported here for two solvates with LiDCTA: (G2)1:LiDCTA and (G1)1:LiDCTA with diglyme and monoglyme, respectively, and seven solvates with LiTDI: (G1)2:LiTDI, (G2)2:LiTDI, (G3)1:LiTDI, (THF)1:LiTDI, (EC)1:LiTDI, (PC)1:LiTDI and (DMC)1/2:LiTDI with monoglyme, diglyme, triglyme, tetrahydrofuran, ethylene carbonate, propylene carbonate and dimethyl carbonate, respectively. These latter solvate structures are compared with the previously reported acetonitrile (AN)2:LiTDI structure. The solvates indicate that the LiTDI salt is much less associated than the LiDCTA salt and that the ions in LiTDI, when aggregated in solvates, have a very similar TDI-...Li+ cation mode of coordination through both the anion ring and cyano nitrogen atoms. Such coordination facilitates the formation of polymeric ion aggregates, instead of dimers. Insight into such ion speciation is instrumental for understanding the electrolyte properties of aprotic solvent mixtures with these salts.

  17. IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (GdLu)

    SciTech Connect (OSTI)

    Mioduski, Tomasz; Gumi?ski, Cezary; Zeng, Dewen

    2015-06-15

    This is the third part of the volume devoted to solubility data for the rare earth metal (REM) fluorides in water and in aqueous ternary and multicomponent systems. It covers experimental results of trivalent fluorides of Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu (so-called heavy lanthanides), since no quantitative data on solubilities of TbF{sub 4} and YbF{sub 2} (the most stable compounds at these valencies) are available. The related literature has been covered through the end of 2014. Compilations of all available papers with the solubility data are introduced for each REM fluoride with a corresponding critical evaluation. Every such assessment contains a collection of all solubility results in aqueous solution, a selection of suggested solubility data, a solubility equation, and a brief discussion of the multicomponent systems. Only simple fluorides (no complexes or double salts) are treated as the input substances in this report. General features of the systems, such as nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, solution pH, mixed solvent medium on the solubility, quality of the solubility results, and the solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.

  18. A PLANETARY SYSTEM AROUND THE NEARBY M DWARF GJ 667C WITH AT LEAST ONE SUPER-EARTH IN ITS HABITABLE ZONE

    SciTech Connect (OSTI)

    Anglada-Escude, Guillem; Butler, R. Paul; Arriagada, Pamela; Minniti, Dante; Vogt, Steven S.; Rivera, Eugenio J.; Haghighipour, Nader; Carter, Brad D.; Tinney, C. G.; Wittenmyer, Robert A.; Bailey, Jeremy A.; O'Toole, Simon J.; Jones, Hugh R. A.; Jenkins, James S.

    2012-05-20

    We re-analyze 4 years of HARPS spectra of the nearby M1.5 dwarf GJ 667C available through the European Southern Observatory public archive. The new radial velocity (RV) measurements were obtained using a new data analysis technique that derives the Doppler measurement and other instrumental effects using a least-squares approach. Combining these new 143 measurements with 41 additional RVs from the Magellan/Planet Finder Spectrograph and Keck/High Resolution Echelle Spectrometer spectrometers reveals three additional signals beyond the previously reported 7.2 day candidate, with periods of 28 days, 75 days, and a secular trend consistent with the presence of a gas giant (period {approx}10 years). The 28 day signal implies a planet candidate with a minimum mass of 4.5 M{sub Circled-Plus} orbiting well within the canonical definition of the star's liquid water habitable zone (HZ), that is, the region around the star at which an Earth-like planet could sustain liquid water on its surface. Still, the ultimate water supporting capability of this candidate depends on properties that are unknown such as its albedo, atmospheric composition, and interior dynamics. The 75 day signal is less certain, being significantly affected by aliasing interactions among a potential 91 day signal, and the likely rotation period of the star at 105 days detected in two activity indices. GJ 667C is the common proper motion companion to the GJ 667AB binary, which is metal-poor compared to the Sun. The presence of a super-Earth in the HZ of a metal-poor M dwarf in a triple star system supports the evidence that such worlds should be ubiquitous in the Galaxy.

  19. Argonne's Earth Day 2011

    ScienceCinema (OSTI)

    None

    2013-04-19

    Argonne celebrated Earth Day on April 21, 2011 with an event that featured green activities and information booths.

  20. DOE SciDAC’s Earth System Grid Center for Enabling Technologies Final Report for University of Southern California Information Sciences Institute

    SciTech Connect (OSTI)

    Chervenak, Ann Louise

    2013-12-19

    The mission of the Earth System Grid Federation (ESGF) is to provide the worldwide climate-research community with access to the data, information, model codes, analysis tools, and intercomparison capabilities required to make sense of enormous climate data sets. Its specific goals are to (1) provide an easy-to-use and secure web-based data access environment for data sets; (2) add value to individual data sets by presenting them in the context of other data sets and tools for comparative analysis; (3) address the specific requirements of participating organizations with respect to bandwidth, access restrictions, and replication; (4) ensure that the data are readily accessible through the analysis and visualization tools used by the climate research community; and (5) transfer infrastructure advances to other domain areas. For the ESGF, the U.S. Department of Energy’s (DOE’s) Earth System Grid Center for Enabling Technologies (ESG-CET) team has led international development and delivered a production environment for managing and accessing ultra-scale climate data. This production environment includes multiple national and international climate projects (such as the Community Earth System Model and the Coupled Model Intercomparison Project), ocean model data (such as the Parallel Ocean Program), observation data (Atmospheric Radiation Measurement Best Estimate, Carbon Dioxide Information and Analysis Center, Atmospheric Infrared Sounder, etc.), and analysis and visualization tools, all serving a diverse user community. These data holdings and services are distributed across multiple ESG-CET sites (such as ANL, LANL, LBNL/NERSC, LLNL/PCMDI, NCAR, and ORNL) and at unfunded partner sites, such as the Australian National University National Computational Infrastructure, the British Atmospheric Data Centre, the National Oceanic and Atmospheric Administration Geophysical Fluid Dynamics Laboratory, the Max Planck Institute for Meteorology, the German Climate Computing

  1. THE HIGH TEMPERATURE CHEMICAL REACTIVITY OF LI2O

    SciTech Connect (OSTI)

    Kessinger, G.; Missimer, D.

    2009-11-13

    The ultimate purpose of this study was to investigate the use of a Li-Ca mixture for direct reduction of actinide oxides to actinide metals at temperatures below 1500 C. For such a process to be successful, the products of the reduction reaction, actinide metals, Li{sub 2}O, and CaO, must all be liquid at the reaction temperature so the resulting actinide metal can coalesce and be recovered as a monolith. Since the established melting temperature of Li{sub 2}O is in the range 1427-1700 C and the melting temperature of CaO is 2654 C, the Li{sub 2}O-CaO (lithium oxidecalcium oxide) pseudo-binary system was investigated in an attempt to identify the presence of low-melting eutectic compositions. The results of our investigation indicate that there is no evidence of ternary Li-Ca-O phases or solutions melting below 1200 C. In the 1200-1500 C range utilizing MgO crucibles, there is some evidence for the formation of a ternary phase; however, it was not possible to determine the phase composition. The results of experiments performed with ZrO{sub 2} crucibles in the same temperature range did not show the formation of the possible ternary phase seen in the earlier experiment involving MgO crucibles, so it was not possible to confirm the possibility that a ternary Li-Ca-O or Li-Mg-O phase was formed. It appears that the Li{sub 2}O-CaO materials reacted, to some extent, with all of the container materials, alumina (Al{sub 2}O{sub 3}), magnesia (MgO), zirconia (ZrO{sub 2}), and 95% Pt-5% Au; however, to clarify the situation additional experiments are required. In addition to the primary purpose of this study, the results of this investigation led to the conclusions that: (1) The melting temperature of Li{sub 2}O may be as low as 1250 C, which is considerably lower than the previously published values in the range 1427-1700 C; (2) Lithium oxide (Li{sub 2}O) vaporizes congruently; (3) Lithium carbonate and Li2O react with 95% Pt-5% Au, and also reacts with pure Pt; and (4

  2. Earth sheltered structures

    SciTech Connect (OSTI)

    Boyer, L.L.

    1982-01-01

    The earth shelter concept has been utilized successfully around the world for thousands of years, but its use with contemporary mechanically conditioned buildings dates only from the oil embargo of the mid-1970s. This is an architectural innovation and a growing and viable response to the energy imperative. Most of the technical problems of earth shelters have been effectively addressed, but a systems design approach could further enhance overall energy savings. Although occupant lifestyle seems to be at a high level, areas that require further attention include site design, daylighting, and refined thermal design. The proper integration of passive solar heating and disaster protection represent opportunities for improved multifunctional aspects. With proper design, annual heating and cooling energy use reductions on the order of 80% can be anticipated. Research on energy design refinements and occupancy aspects necessary to achieve such levels of savings is presently under way at Oklahoma State University, the University of Minnesota, and other study centers throughout the nation and the world.

  3. Geoengineering the Earth's Climate

    ScienceCinema (OSTI)

    Google Tech Talks

    2009-09-01

    Emergency preparedness is generally considered to be a good thing, yet there is no plan regarding what we might do should we be faced with a climate emergency. Such an emergency could take the form of a rapid shift in precipitation patterns, a collapse of the great ice sheets, the imminent triggering of strong climate system feedbacks, or perhaps the loss of valuable ecosystems. Over the past decade, we have used climate models to investigate the potential to reverse some of the effects of greenhouse gases in the atmosphere by deflecting some incoming sunlight back to space. This would probably be most cost-effectively achieved with the placement of small particles in or above the stratosphere. Our model simulations indicate that such geoengineering approaches could potentially bring our climate closer to the state is was in prior to the introduction of greenhouse gases. This talk will present much of what is known about such geoengineering approaches, and raise a range of issues likely to stimulate lively discussion. Speaker: Ken Caldeira Ken Caldeira is a scientist at the Carnegie Institution Department of Global Ecology and a Professor (by courtesy) at the Stanford University Department of Environmental and Earth System Sciences. Previously, he worked for 12 years in the Energy and Environment Directorate at the Lawrence Livermore National Laboratory (Department of Energy). His research interests include the numerical simulation of Earth's climate, carbon, and biogeochemistry; ocean acidification; climate emergency response systems; evaluating approaches to supplying environmentally-friendly energy services; ocean carbon sequestration; long-term evolution of climate and geochemical cycles; and marine biogeochemical cycles. Caldeira has a B.A. in Philosophy from Rutgers College and an M.S. and Ph.D. in Atmospheric Sciences from New York University.

  4. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005

    Office of Energy Efficiency and Renewable Energy (EERE)

    Development status of air-cooled lithium bromide (LiBr)-water absorption chillers for cooling, heating, and power (CHP) system applications in light-commercial buildings.

  5. A=12Li (1975AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    75AJ02) (Not illustrated) 12Li is not observed in the 4.8 GeV proton bombardment of a uranium target: it is particle unstable (1974BO05). Its atomic mass excess is therefore > 49.0 MeV. (1974TH01) calculate the mass excess of 12Li to be 52.92 MeV. 12Li would then be unstable with respect to 11Li + n, 10Li + 2n and 9Li + 3n by 3.9, 3.68 and 3.74 MeV, respectively. See also (1972TH13, 1973BO30, 1974IR04

  6. A=12Li (1990AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    90AJ01) (Not illustrated) 12Li is not observed in the 4.8 GeV proton bombardment of a uranium target: it is particle unstable. The calculated value of its mass excess is 52.93 MeV [see (1980AJ01)]: 12Li would then be unstable with respect to 11Li + n ,10Li + 2n and 9Li + 3n by 4.01, 2.96 and 3.76 MeV, respectively. The ground state of 12Li is predicted to have Jπ = 2- (1988POZS, 1985PO10; theor.). See also (1980AJ01

  7. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1992TI02) (See Energy Level Diagrams for 4Li) GENERAL: The stability of 8B against particle decay (1988AJ01), in particular against decay into 4He + 4Li, sets an upper limit of 1.7 MeV on the separation energy of 4Li into p + 3He (1952SH44). The instability of 4H against particle decay (see 4H, GENERAL section) makes the particle stability of 4Li very unlikely, since the Coulomb energy of 4Li is approximately 1.7 MeV larger than that of 4H (1963WE10), and the nuclear energies should be

  8. Rare Earth Elements Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Elements Rare Earth Elements from Coal and Coal By-Products logo. Download the 2016 Rare Earth Elements from Coal and Coal By-Products Project Portfolio Rare Earth ...

  9. HOW THERMAL EVOLUTION AND MASS-LOSS SCULPT POPULATIONS OF SUPER-EARTHS AND SUB-NEPTUNES: APPLICATION TO THE KEPLER-11 SYSTEM AND BEYOND

    SciTech Connect (OSTI)

    Lopez, Eric D.; Miller, Neil; Fortney, Jonathan J. [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States)

    2012-12-10

    We use models of thermal evolution and extreme ultraviolet (XUV) driven mass loss to explore the composition and history of low-mass, low-density transiting planets. We investigate the Kepler-11 system in detail and provide estimates of both the current and past planetary compositions. We find that an H/He envelope on Kepler-11b is highly vulnerable to mass loss. By comparing to formation models, we show that in situ formation of the system is extremely difficult. Instead we propose that it is a water-rich system of sub-Neptunes that migrated from beyond the snow line. For the broader population of observed planets, we show that there is a threshold in bulk planet density and incident flux above which no low-mass transiting planets have been observed. We suggest that this threshold is due to the instability of H/He envelopes to XUV-driven mass loss. Importantly, we find that this mass-loss threshold is well reproduced by our thermal evolution/contraction models that incorporate a standard mass-loss prescription. Treating the planets' contraction history is essential because the planets have significantly larger radii during the early era of high XUV fluxes. Over time low-mass planets with H/He envelopes can be transformed into water-dominated worlds with steam envelopes or rocky super-Earths. Finally, we use this threshold to provide likely minimum masses and radial-velocity amplitudes for the general population of Kepler candidates. Likewise, we use this threshold to provide constraints on the maximum radii of low-mass planets found by radial-velocity surveys.

  10. Alternating magnetic anisotropy of Li2(Li1xTx)N (T = Mn, Fe, Co, and Ni)

    SciTech Connect (OSTI)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model. As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.

  11. Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni)

    SciTech Connect (OSTI)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1–xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane→easy axis→easy plane→easy axis when progressing from T = Mn → Fe → Co → Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model. As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.

  12. A=11Li (1980AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    80AJ01) (See the Isobar Diagram for 11Li) 11Li has been observed in the bombardment of iridium by 24 GeV protons. Its mass excess is 40.94 ± 0.08 MeV (1975TH08). The cross section for its formation is ~ 50 μb (1976TH1A). 11Li is bound: Eb for break up into 9Li + 2n and 10Li + n are 158 ± 80 and 960 ± 250 keV, respectively [see (1979AJ01) for discussions of the masses of 9Li and 10Li]. The half-life of 11Li is 8.5 ± 0.2 msec (1974RO31): it decays to neutron unstable states of 11Be [Pn =

  13. A=10Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 10Li) GENERAL: References to articles on general properties of 10Li published since the previous review (1988AJ01) are grouped into...

  14. Construction Consultants, L.I., Inc.

    Office of Environmental Management (EM)

    Mr. Eric Baumack Senior Project Manager Construction Consultants L.I., Inc. 36 East 2 nd ... worker employed by a subcontractor to Construction Consultants L.I., Inc. (CCLI) at the ...

  15. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1995TI07) (Not illustrated) 18Li has not been observed. Shell model calculations described in (1988POZS) predict the ground-state magentic dipole moment and charge and matter radii.

  16. A=20Li (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1998TI06) (Not observed) See (1977CE05, 1983ANZQ, 1986AN07, 1987SIZX).

  17. Earth and Environmental Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reveal climate change drivers and ecosystem impacts Perfect geological greenhouse gas ... Advanced computational Earth sciences Atmospheric, climate and ecosystem science Geology ...

  18. Happy Earth Day 2011!

    Broader source: Energy.gov [DOE]

    Check out these resources from the Department of Energy to help you celebrate, get in the Earth Day spirit, and take action.

  19. A=14Li (1976AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    76AJ04) (Not illustrated) 14Li has not been observed: it is calculated to be particle unstable with a binding energy of -2.66 MeV for decay into 13Li + n and of -3.23 MeV for decay into 12Li + 2n. The calculated mass excess is 72.29 MeV (1974TH01)

  20. A=15Li (1976AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    76AJ04) (Not illustrated) 15Li has not been observed: its atomic mass excess is calculated to be 81.60 MeV. It is then unstable with respect to decay into 14Li + n and 13Li + 2n by 1.24 and 3.90 MeV, respectively (1974TH01)

  1. A=15Li (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6AJ01) (Not illustrated) 15Li has not been observed. Its atomic mass excess is calculated to be 81.60 MeV: see (1981AJ01). It is then unstable with respect to decay into 14Li + n and 13Li + 2n by 1.24 and 3.90 MeV, repsectively

  2. A=11Li (1975AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by GeV protons. Its mass excess is 40.9 0.1 MeV (1973KL1C). 11Li is bound: Eb for breakup into 9Li + 2n and 10Li + n are 0.2 and 0.3 MeV, respectively see (1974AJ01) for a...

  3. A=13Li (1976AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13Li is predicted to have an atomic mass excess of 61.56 MeV: it is then unstable for breakup into 12Li + n and 11Li + 2n by 0.6 and 4.5 MeV, respectively (1974TH01). The modified...

  4. A=13Li (1981AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13Li is predicted to have an atomic mass excess of 61.56 MeV: it is then unstable for breakup into 12Li + n and 11Li + 2n by 0.6 and 4.5 MeV, respectively (1974TH01). The modified...

  5. A=8Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p)8Li Qm 0.80079 Angular distributions have been obtained at Et 23 MeV for the proton groups to 8Li*(0, 0.98, 2.26, 6.54 0.03); cm for 8Li*(2.26, 6.54) are 35 10 and 35...

  6. A=8Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the geometric value, supports the hypothesis that 7Li may be described as an ( + t) cluster (RO62C). See also (AL63N, BA63O, BR63M, VA64G). 9. 7Li(d, p)8Li Qm -0.192...

  7. Recovery of Li from alloys of Al-Li and Li-Al using engineered scavenger compounds

    SciTech Connect (OSTI)

    Riley, W.D.; Jong, B.W.; Collins, W.K.; Gerdemann, S.J.

    1992-01-01

    The invention relates to a process for obtaining Li metal selectively recovered from Li-Al or Al-Li alloy scrap by: (1) removing Li from aluminum-lithium alloys at temperatures between about 400 C-750 C in a molten salt bath of KC1-LiCl using lithium titanate (Li2O.3TiO2) as an engineered scavenger compound (ESC); and (2) electrodepositing of Li from the loaded ESC to a stainless steel electrode. By use of the second step, the ESC is prepared for reuse. A molten salt bath is required in the invention because of the inability of molten aluminum alloys to wet the ESC.

  8. A=12Li (1985AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5AJ01) (Not illustrated) 12Li is not observed in the 4.8 GeV proton bombardment of a uranium target: it is particle-unstable. The calculated value of its mass excess is 52.93 MeV [see (1980AJ01)]: 12Li would then be unstable with respect to 11Li + n, 10Li + 2n and 9Li + 3n by 3.92, 2.96 and 3.76 MeV, respectively. See also (1980AJ01) and (1982KA1D, 1983ANZQ, 1984VA06

  9. A=13Li (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    86AJ01) (Not illustrated) 13Li has not been observed. The calculated value of its mass excess is 60.34 MeV [see (1981AJ01)]: 13Li would then be unstable with respect to 11Li + 2n by 3.26 MeV. (1980BO31) have not observed 13Li in the bombardment of 124Sn by 6.7 GeV protons but state that the statistics were poor in the region of interest and that it is not excluded that 13Li may be stable. See also (1983ANZQ

  10. Cool Earth Solar

    SciTech Connect (OSTI)

    Lamkin, Rob; McIlroy, Andy; Swalwell, Eric; Rajan, Kish

    2013-04-22

    In a public-private partnership that takes full advantage of the Livermore Valley Open Campus (LVOC) for the first time, Sandia National Laboratories and Cool Earth Solar have signed an agreement that could make solar energy more affordable and accessible. In this piece, representatives from Sandia, Cool Earth Solar, and leaders in California government all discuss the unique partnership and its expected impact.