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Sample records for li earth system

  1. Climate & Earth Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable ... Climate & Earth Systems Climate Measurement & Modeling Arctic Climate Measurements Global ...

  2. Earth System Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Earth System Observations Research comprises Earth, ocean, and atmospheric sciences to better understand and predict climate change's impact on ecosystems and to study subsurface geological materials and their interactions. Deploying research facilities globally Forecasting forests' responses to climate change Monitoring terrestrial ecosystems Contact Us Group Leader Claudia Mora Email Deputy Group Leader Bob Roback Email Profile pages header Search our Profile pages Investigating carbon

  3. Modeling the earth system

    SciTech Connect (OSTI)

    Ojima, D.

    1992-12-31

    The 1990 Global Change Institute (GCI) on Earth System Modeling is the third of a series organized by the Office for Interdisciplinary Earth Studies to look in depth at particular issues critical to developing a better understanding of the earth system. The 1990 GCI on Earth System Modeling was organized around three themes: defining critical gaps in the knowledge of the earth system, developing simplified working models, and validating comprehensive system models. This book is divided into three sections that reflect these themes. Each section begins with a set of background papers offering a brief tutorial on the subject, followed by working group reports developed during the institute. These reports summarize the joint ideas and recommendations of the participants and bring to bear the interdisciplinary perspective that imbued the institute. Since the conclusion of the 1990 Global Change Institute, research programs, nationally and internationally, have moved forward to implement a number of the recommendations made at the institute, and many of the participants have maintained collegial interactions to develop research projects addressing the needs identified during the two weeks in Snowmass.

  4. SciTech Connect: "earth system models"

    Office of Scientific and Technical Information (OSTI)

    earth system models" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "earth system models" Semantic Semantic Term Title: Full Text: Bibliographic...

  5. Electrochemistry of LiCl-Li2O-H2O Molten Salt Systems

    SciTech Connect (OSTI)

    Natalie J. Gese; Batric Pesic

    2013-03-01

    Uranium can be recovered from uranium oxide (UO2) spent fuel through the combination of the oxide reduction and electrorefining processes. During oxide reduction, the spent fuel is introduced to molten LiCl-Li2O salt at 650 degrees C and the UO2 is reduced to uranium metal via two routes: (1) electrochemically, and (2) chemically by lithium metal (Li0) that is produced electrochemically. However, the hygroscopic nature of both LiCl and Li2O leads to the formation of LiOH, contributing hydroxyl anions (OH-), the reduction of which interferes with the Li0 generation required for the chemical reduction of UO2. In order for the oxide reduction process to be an effective method for the treatment of uranium oxide fuel, the role of moisture in the LiCl-Li2O system must be understood. The behavior of moisture in the LiCl-Li2O molten salt system was studied using cyclic voltammetry, chronopotentiometry and chronoamperometry, while reduction to hydrogen was confirmed with gas chromatography.

  6. Modeling the Earth System, volume 3

    SciTech Connect (OSTI)

    Ojima, D.

    1992-01-01

    The topics covered fall under the following headings: critical gaps in the Earth system conceptual framework; development needs for simplified models; and validating Earth system models and their subcomponents.

  7. A toolkit for building earth system models

    SciTech Connect (OSTI)

    Foster, I.

    1993-03-01

    An earth system model is a computer code designed to simulate the interrelated processes that determine the earth`s weather and climate, such as atmospheric circulation, atmospheric physics, atmospheric chemistry, oceanic circulation, and biosphere. I propose a toolkit that would support a modular, or object-oriented, approach to the implementation of such models.

  8. A toolkit for building earth system models

    SciTech Connect (OSTI)

    Foster, I.

    1993-03-01

    An earth system model is a computer code designed to simulate the interrelated processes that determine the earth's weather and climate, such as atmospheric circulation, atmospheric physics, atmospheric chemistry, oceanic circulation, and biosphere. I propose a toolkit that would support a modular, or object-oriented, approach to the implementation of such models.

  9. Climate, Earth system project draws on science powerhouses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate, Earth system project draws on science powerhouses Alumni Link: Opportunities, ... Latest Issue:September 2015 all issues All Issues submit Climate, Earth system project ...

  10. Climate, Earth system project draws on science powerhouses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate, Earth system project draws on science powerhouses Climate, Earth system project draws on science powerhouses The project will focus initially on three climate-change ...

  11. LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery

    DOE Patents [OSTI]

    Ko, Suk M.

    1980-01-01

    This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

  12. A Reactive Force Field study of Li/C Systems for Electrical Energy...

    Office of Scientific and Technical Information (OSTI)

    A Reactive Force Field study of LiC Systems for Electrical Energy Storage Citation Details In-Document Search Title: A Reactive Force Field study of LiC Systems for Electrical ...

  13. Atmosphere Component in Community Earth System Model

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atiq Warraich About Us Atiq Warraich - Technical Lead/Project Manager Atiq Warraich

    Atmosphere Component in Community Earth System Model - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power

  14. The Community Earth System Model: A Framework for Collaborative Research

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Earth System Model: A Framework for Collaborative Research Citation Details In-Document Search Title: The Community Earth System Model: A Framework for Collaborative Research The Community Earth System Model (CESM) is a flexible and extensible community tool used to investigate a diverse set of earth system interactions across multiple time and space scales. This global coupled model is a natural evolution from its predecessor, the Community Climate System

  15. 2012 Community Earth System Model (CESM) Tutorial - Proposal to DOE

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: 2012 Community Earth System Model (CESM) Tutorial - Proposal to DOE Citation Details In-Document Search Title: 2012 Community Earth System Model (CESM) Tutorial - Proposal to DOE The Community Earth System Model (CESM) is a fully-coupled, global climate model that provides state-of-the-art computer simulations of the Earth's past, present, and future climate states. This document provides the agenda and list of participants for the conference. Web

  16. 2012 Community Earth System Model (CESM) Tutorial - Proposal to DOE

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: 2012 Community Earth System Model (CESM) Tutorial - Proposal to DOE Citation Details In-Document Search Title: 2012 Community Earth System Model (CESM) Tutorial - Proposal to DOE The Community Earth System Model (CESM) is a fully-coupled, global climate model that provides state-of-the-art computer simulations of the Earth's past, present, and future climate states. This document provides the agenda and list of participants for the conference. Web

  17. The Community Earth System Model: A Framework for Collaborative...

    Office of Scientific and Technical Information (OSTI)

    This global coupled model is a natural evolution from its predecessor, the Community Climate System Model, following the incorporation of new earth system capabilities. These ...

  18. Microsoft Word - li_z.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Cloud Liquid Water Path and Its Potential for Rain Detection Z. Li, R. Chen, and F-L Chang Earth System Science Interdisciplinary Center, University of Maryland College Park,...

  19. Combined effect of chemical pressure and valence electron concentration through the electron-deficient Li substitution on the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system

    SciTech Connect (OSTI)

    Nam, Gnu; Jeon, Jieun; Kim, Youngjo; Kwon Kang, Sung; Ahn, Kyunghan; You, Tae-Soo

    2013-09-15

    Four members of the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system have been prepared by high-temperature reaction method and characterized by X-ray diffractions. All compounds crystallize in the orthorhombic Gd{sub 5}Si{sub 4}-type structure (space group Pnma, Pearson code oP16) with bonding interactions for interslab Ge{sub 2} dimers. The Li substitution for rare-earth elements in the RE{sub 4}LiGe{sub 4} system leads to a combined effect of the increased chemical pressure and the decreased valance electron concentration (VEC), which eventually results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type with all broken interslab Ge–Ge bond for the parental RE{sub 5}Ge{sub 4} to the Gd{sub 5}Si{sub 4}-type structure for the ternary RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. Site-preference between rare-earth metals and Li is proven to generate energetically the most favorable atomic arrangements according to coloring-problem, and the rationale is provided using both the size-factor and the electronic-factor related, respectively, to site-volume and electronegativity as well as QVAL values. Tight-binding, linear-muffin-tin-orbital (TB-LMTO) calculations are performed to investigate electronic densities of states (DOS) and crystal orbital Hamilton population (COHP) curves. The influence of reduced VEC for chemical bonding including the formation of interslab Ge{sub 2} dimers is also discussed. The magnetic property measurements prove that the non-magnetic Li substitution leads to the ferromagnetic (FM)-like ground state for Ce{sub 4}LiGe{sub 4} and the co-existence of antiferromagntic (AFM) and FM ground states for Sm{sub 4}LiGe{sub 4}. - Graphical abstract: Reported is a combined effect of the chemical pressure and the reduced VEC caused by the smaller monovalent non-magnetic Li substitution for the larger trivalent magnetic rare-earth metals in the RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr, and Sm) system. This results in the structure transformation from the Sm{sub 5}Ge{sub 4}-type to the Gd{sub 5}Si{sub 4}-type structure and the changes in magnetic properties. Display Omitted - Highlights: • Four Li-containing intermetallic compounds RE{sub 4}LiGe{sub 4} (RE=La, Ce, Pr and Sm) were synthesized. • The combined effect of the chemical pressure and the reduced VEC caused by Li substitution for a rare-earth metal results in the structure transformation. • Electronic structures and magnetic properties of title compounds were thoroughly investigated.

  20. The integrated Earth System Model Version 1: formulation and functionality

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect The integrated Earth System Model Version 1: formulation and functionality Citation Details In-Document Search Title: The integrated Earth System Model Version 1: formulation and functionality The integrated Earth System Model (iESM) has been developed as a new tool for pro- jecting the joint human/climate system. The iESM is based upon coupling an Integrated Assessment Model (IAM) and an Earth System Model (ESM) into a common modeling in- frastructure.

  1. Final Report for proposal "The Interface between Earth System...

    Office of Scientific and Technical Information (OSTI)

    The creation of a new Community Earth System Model (CESM) working group, combining ... goals and objectives of the new working group, to discuss how it will interact with ...

  2. A Scalable and Extensible Earth System Model for Climate Change...

    Office of Scientific and Technical Information (OSTI)

    Scalable and Extensible Earth System Model for Climate Change Science Gent, Peter; Lamarque, Jean-Francois; Conley, Andrew; Vertenstein, Mariana; Craig, Anthony 54 ENVIRONMENTAL...

  3. DOE SciDAC's Earth System Grid Center for Enabling Technologies...

    Office of Scientific and Technical Information (OSTI)

    of Southern California 96 KNOWLEDGE MANAGEMENT AND PRESERVATION Earth System Grid, data replication, system monitoring Earth System Grid, data replication, system monitoring...

  4. The integrated Earth System Model Version 1: formulation and...

    Office of Scientific and Technical Information (OSTI)

    The iESM is based upon coupling an Integrated Assessment Model (IAM) and an Earth System ... The iESM project integrates the economic and human dimension modeling of an IAM and a ...

  5. Collaborative Project. Mode and Intermediate Waters in Earth System Models

    SciTech Connect (OSTI)

    Sarmiento, Jorge L.; Dufour, Carolina; Rodgers, Keith B.

    2015-12-16

    The focus of this grant was on diagnosing the physical mechanisms controlling upper ocean water mass formation and carbon distribution in Earth System Models (ESMs), with the goal of improving the physics that controls their formation.

  6. Climate, Earth system project draws on science powerhouses

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate, Earth system project draws on science powerhouses Climate, Earth system project draws on science powerhouses The project will focus initially on three climate-change science drivers and corresponding questions to be answered during the project's initial phase. September 25, 2014 Computer modeling provides policymakers with essential information on such data as global sea surface temperatures related to specific currents. Computer modeling provides policymakers with essential information

  7. Calibration of LI-7500 sensor for 60m CO2/H20 flux system

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of LI-7500 Sensor for the CO2flx and ECOR Systems Marc L. Fischer David R. Cook Revision Date 05042007 (D. R. Cook) Introduction This...

  8. A reactive force field study of Li/C systems for electrical energy storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Raju, Muralikrishna; Ganesh, P.; Kent, Paul R. C.; van Duin, Adri C.T.

    2015-04-02

    Graphitic carbon is still the most ubiquitously used anode material in Li-ion batteries. In spite of its ubiquity, there are few theoretical studies that fully capture the energetics and kinetics of Li in graphite and related nanostructures at experimentally relevant length, time-scales, and Li-ion concentrations. In this paper, we describe the development and application of a ReaxFF reactive force field to describe Li interactions in perfect and defective carbon-based materials using atomistic simulations. We develop force field parameters for Li–C systems using van der Waals-corrected density functional theory (DFT). Grand canonical Monte Carlo simulations of Li intercalation in perfect graphitemore » with this new force field not only give a voltage profile in good agreement with known experimental and DFT results but also capture the in-plane Li ordering and interlayer separations for stage I and II compounds. In defective graphite, the ratio of Li/C (i.e., the capacitance increases and voltage shifts) both in proportion to the concentration of vacancy defects and metallic lithium is observed to explain the lithium plating seen in recent experiments. We also demonstrate the robustness of the force field by simulating model carbon nanostructures (i.e., both 0D and 1D structures) that can be potentially used as battery electrode materials. Whereas a 0D defective onion-like carbon facilitates fast charging/discharging rates by surface Li adsorption, a 1D defect-free carbon nanorod requires a critical density of Li for intercalation to occur at the edges. Our force field approach opens the opportunity for studying energetics and kinetics of perfect and defective Li/C structures containing thousands of atoms as a function of intercalation. As a result, this is a key step toward modeling of realistic carbon materials for energy applications.« less

  9. Reactive force field study of Li/C systems for electrical energy storage

    SciTech Connect (OSTI)

    Raju, Muralikrishna; Ganesh, P.; Kent, Paul R. C.; van Duin, Adri C.T.

    2015-04-02

    Graphitic carbon is still the most ubiquitously used anode material in Li-ion batteries. In spite of its ubiquity, there are few theoretical studies that fully capture the energetics and kinetics of Li in graphite and related nanostructures at experimentally relevant length, time-scales, and Li-ion concentrations. In this paper, we describe the development and application of a ReaxFF reactive force field to describe Li interactions in perfect and defective carbon-based materials using atomistic simulations. We develop force field parameters for Li–C systems using van der Waals-corrected density functional theory (DFT). Grand canonical Monte Carlo simulations of Li intercalation in perfect graphite with this new force field not only give a voltage profile in good agreement with known experimental and DFT results but also capture the in-plane Li ordering and interlayer separations for stage I and II compounds. In defective graphite, the ratio of Li/C (i.e., the capacitance increases and voltage shifts) both in proportion to the concentration of vacancy defects and metallic lithium is observed to explain the lithium plating seen in recent experiments. We also demonstrate the robustness of the force field by simulating model carbon nanostructures (i.e., both 0D and 1D structures) that can be potentially used as battery electrode materials. Whereas a 0D defective onion-like carbon facilitates fast charging/discharging rates by surface Li adsorption, a 1D defect-free carbon nanorod requires a critical density of Li for intercalation to occur at the edges. Our force field approach opens the opportunity for studying energetics and kinetics of perfect and defective Li/C structures containing thousands of atoms as a function of intercalation. As a result, this is a key step toward modeling of realistic carbon materials for energy applications.

  10. Investigation of Mechanical Activation on Li-N-H Systems Using 6Li Magic Angle Spinning Nuclear Magnetic Resonance at Ultra-High Field

    SciTech Connect (OSTI)

    Hu, Jian Zhi; Kwak, Ja Hun; Yang, Zhenguo; Osborn, William; Markmaitree, Tippawan; Shaw, Leonard D.

    2008-07-15

    Abstract The significantly enhanced spectral resolution in the 6Li MAS NMR spectra of Li-N-H systems at ultra-high field of 21.1 tesla is exploited, for the first time, to study the detailed electronic and chemical environmental changes associated with mechanical activation of Li-N-H system using high energy balling milling. Complementary to ultra-high field studies, the hydrogen discharge dynamics are investigated using variable temperature in situ 1H MAS NMR at 7.05 tesla field. The significantly enhanced spectral resolution using ultra-high filed of 21.1 tesla was demonstrated along with several major findings related to mechanical activation, including the upfield shift of the resonances in 6Li MAS spectra induced by ball milling, more efficient mechanical activation with ball milling at liquid nitrogen temperature than with ball milling at room temperature, and greatly enhanced hydrogen discharge exhibited by the liquid nitrogen ball milled samples.

  11. First-Principles Study of Novel Conversion Reactions for High-Capacity Li-Ion Battery Anodes in the Li-Mg-B-N-H System

    SciTech Connect (OSTI)

    Mason, T.H.; Graetz, J.; Liu, X.; Hong, J.; Majzoub, E.H.

    2011-07-28

    Anodes for Li-ion batteries are primarily carbon-based due to their low cost and long cycle life. However, improvements to the Li capacity of carbon anodes, LiC{sub 6} in particular, are necessary to obtain a larger energy density. State-of-the-art light-metal hydrides for hydrogen storage applications often contain Li and involve reactions requiring Li transport, and light-metal ionic hydrides are candidates for novel conversion materials. Given a set of known solid-state and gas-phase reactants, we have determined the phase diagram in the Li-Mg-B-N-H system in the grand canonical ensemble, as a function of lithium chemical potential. We present computational results for several new conversion reactions with capacities between 2400 and 4000 mAh g{sup -1} that are thermodynamically favorable and that do not involve gas evolution. We provide experimental evidence for the reaction pathway on delithiation for the compound Li{sub 4}BN{sub 3}H{sub 10}. While the predicted reactions involve multiple steps, the maximum volume increase for these materials on lithium insertion is significantly smaller than that for Si.

  12. The integrated Earth System Model Version 1: formulation and functionality

    SciTech Connect (OSTI)

    Collins, William D.; Craig, Anthony P.; Truesdale, John E.; Di Vittorio, Alan; Jones, Andrew D.; Bond-Lamberty, Benjamin; Calvin, Katherine V.; Edmonds, James A.; Kim, Son H.; Thomson, Allison M.; Patel, Pralit L.; Zhou, Yuyu; Mao, Jiafu; Shi, Xiaoying; Thornton, Peter E.; Chini, Louise M.; Hurtt, George C.

    2015-07-23

    The integrated Earth System Model (iESM) has been developed as a new tool for pro- jecting the joint human/climate system. The iESM is based upon coupling an Integrated Assessment Model (IAM) and an Earth System Model (ESM) into a common modeling in- frastructure. IAMs are the primary tool for describing the human–Earth system, including the sources of global greenhouse gases (GHGs) and short-lived species, land use and land cover change, and other resource-related drivers of anthropogenic climate change. ESMs are the primary scientific tools for examining the physical, chemical, and biogeochemical impacts of human-induced changes to the climate system. The iESM project integrates the economic and human dimension modeling of an IAM and a fully coupled ESM within a sin- gle simulation system while maintaining the separability of each model if needed. Both IAM and ESM codes are developed and used by large communities and have been extensively applied in recent national and international climate assessments. By introducing heretofore- omitted feedbacks between natural and societal drivers, we can improve scientific under- standing of the human–Earth system dynamics. Potential applications include studies of the interactions and feedbacks leading to the timing, scale, and geographic distribution of emissions trajectories and other human influences, corresponding climate effects, and the subsequent impacts of a changing climate on human and natural systems. This paper de- scribes the formulation, requirements, implementation, testing, and resulting functionality of the first version of the iESM released to the global climate community.

  13. The integrated Earth system model version 1: formulation and functionality

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collins, W. D.; Craig, A. P.; Truesdale, J. E.; Di Vittorio, A. V.; Jones, A. D.; Bond-Lamberty, B.; Calvin, K. V.; Edmonds, J. A.; Kim, S. H.; Thomson, A. M.; et al

    2015-07-23

    The integrated Earth system model (iESM) has been developed as a new tool for projecting the joint human/climate system. The iESM is based upon coupling an integrated assessment model (IAM) and an Earth system model (ESM) into a common modeling infrastructure. IAMs are the primary tool for describing the human–Earth system, including the sources of global greenhouse gases (GHGs) and short-lived species (SLS), land use and land cover change (LULCC), and other resource-related drivers of anthropogenic climate change. ESMs are the primary scientific tools for examining the physical, chemical, and biogeochemical impacts of human-induced changes to the climate system. Themore » iESM project integrates the economic and human-dimension modeling of an IAM and a fully coupled ESM within a single simulation system while maintaining the separability of each model if needed. Both IAM and ESM codes are developed and used by large communities and have been extensively applied in recent national and international climate assessments. By introducing heretofore-omitted feedbacks between natural and societal drivers, we can improve scientific understanding of the human–Earth system dynamics. Potential applications include studies of the interactions and feedbacks leading to the timing, scale, and geographic distribution of emissions trajectories and other human influences, corresponding climate effects, and the subsequent impacts of a changing climate on human and natural systems. This paper describes the formulation, requirements, implementation, testing, and resulting functionality of the first version of the iESM released to the global climate community.« less

  14. Big Data Visual Analytics for Exploratory Earth System Simulation Analysis

    SciTech Connect (OSTI)

    Steed, Chad A.; Ricciuto, Daniel M.; Shipman, Galen M.; Smith, Brian E.; Thornton, Peter E.; Wang, Dali; Shi, Xiaoying; Williams, Dean N.

    2013-12-01

    Rapid increases in high performance computing are feeding the development of larger and more complex data sets in climate research, which sets the stage for so-called big data analysis challenges. However, conventional climate analysis techniques are inadequate in dealing with the complexities of today s data. In this paper, we describe and demonstrate a visual analytics system, called the Exploratory Data analysis ENvironment (EDEN), with specific application to the analysis of complex earth system simulation data sets. EDEN represents the type of interactive visual analysis tools that are necessary to transform data into insight, thereby improving critical comprehension of earth system processes. In addition to providing an overview of EDEN, we describe real-world studies using both point ensembles and global Community Land Model Version 4 (CLM4) simulations.

  15. The Brief History and Future Development of Earth System Models:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brief History and Future Development of Earth System Models: Resolution and Complexity Warren M. Washington National Center for Atmospheric Research NERSC Lecture Series at Berkeley Lab May, 2014 Overview * Brief history of climate modeling * Brief discussion of computational methods * Environmental Justice connected to climate change * Behind the scenes White House origin of the U. S. Global Change Research Program (USGCRP) * The future of the USGCRP and National Climate Assessment The next two

  16. FORTRAN M as a language for building earth system models

    SciTech Connect (OSTI)

    Foster, I.

    1992-01-01

    FORTRAN M is a small set of extensions to FORTRAN 77 that supports a modular or object-oriented approach to the development of parallel programs. In this paper, I discuss the use of FORTRAN M as a tool for building earth system models on massively parallel computers. I hypothesize that the use of FORTRAN M has software engineering advantages and outline experiments that we are conducting to investigate this hypothesis.

  17. FORTRAN M as a language for building earth system models

    SciTech Connect (OSTI)

    Foster, I.

    1992-12-31

    FORTRAN M is a small set of extensions to FORTRAN 77 that supports a modular or object-oriented approach to the development of parallel programs. In this paper, I discuss the use of FORTRAN M as a tool for building earth system models on massively parallel computers. I hypothesize that the use of FORTRAN M has software engineering advantages and outline experiments that we are conducting to investigate this hypothesis.

  18. Mode and Intermediate Waters in Earth System Models

    SciTech Connect (OSTI)

    Gnanadesikan, Anand; Sarmiento, Jorge L.

    2015-12-22

    This report describes work done as part of a joint Princeton-Johns Hopkins project to look at the impact of mode and intermediate waters in Earth System Models. The Johns Hopkins portion of this work focussed on the role of lateral mixing in ventilating such waters, with important implications for hypoxia, the uptake of anthropogenic carbon, the dynamics of El Nino and carbon pumps. The Johns Hopkins group also collaborated with the Princeton Group to help develop a watermass diagnostics framework.

  19. Earth Videos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth Videos Earth

  20. Solid Solution Phases in the Olivine-Type LiMnPO4/MnPO4 System

    SciTech Connect (OSTI)

    Chen, Guoying; Richardson, Thomas J.

    2009-04-07

    Nonstoichiometry is reported in the LiMnPO{sub 4}/MnPO{sub 4} system for the first time. As lithium is removed from crystalline LiMnPO{sub 4} by chemical or electrochemical methods, the resulting two phase mixture consists of stoichiometric LiMnPO{sub 4} and a delithiated phase, Li{sub y}MnPO{sub 4}, whose lattice parameters depend upon the global extent of delithiation and on the crystalline domain size of the delithiated phase. This behavior is reproduced during electrochemical insertion of lithium. Again, no evidence for nonstoichiometry was found in the vicinity of LiMnPO{sub 4}. Attempts to create single phase solid solutions by heating mixtures of the two phases failed due to the thermal instability of Li{sub y}MnPO{sub 4}.

  1. A Scalable and Extensible Earth System Model for Climate Change Science

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect A Scalable and Extensible Earth System Model for Climate Change Science Citation Details In-Document Search Title: A Scalable and Extensible Earth System Model for Climate Change Science The objective of this award was to build a scalable and extensible Earth System Model that can be used to study climate change science. That objective has been achieved with the public release of the Community Earth System Model, version 1 (CESM1). In particular, the

  2. A Scalable and Extensible Earth System Model for Climate Change Science

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Technical Report: A Scalable and Extensible Earth System Model for Climate Change Science Citation Details In-Document Search Title: A Scalable and Extensible Earth System Model for Climate Change Science The objective of this award was to build a scalable and extensible Earth System Model that can be used to study climate change science. That objective has been achieved with the public release of the Community Earth System Model, version 1 (CESM1). In

  3. Climate Model Datasets on Earth System Grid II (ESG II)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Earth System Grid (ESG) is a project that combines the power and capacity of supercomputers, sophisticated analysis servers, and datasets on the scale of petabytes. The goal is to provide a seamless distributed environment that allows scientists in many locations to work with large-scale data, perform climate change modeling and simulation,and share results in innovative ways. Though ESG is more about the computing environment than the data, still there are several catalogs of data available at the web site that can be browsed or search. Most of the datasets are restricted to registered users, but several are open to any access.

  4. Elastic scattering for the system {sup 6}Li+p at near barrier energies with MAGNEX

    SciTech Connect (OSTI)

    Soukeras, V.; Pakou, A.; Sgouros, O.; Cappuzzello, F.; Bondi, M.; Nicolosi, D.; Acosta, L.; Marquinez-Duran, G.; Martel, I.; Agodi, C.; Carbone, D.; Cavallaro, M.; Cunsolo, A.; Di Pietro, A.; Fernández-García, J. P.; Figuera, P.; Fisichella, M.; Alamanos, N.; De Napoli, M.; Foti, A.; and others

    2015-02-24

    Elastic scattering measurements have been performed for the {sup 6}Li+p system in inverse kinematics at the energies of 16, 20, 25 and 29 MeV. The heavy ejectile was detected by the large acceptance MAGNEX spectrometer at the Laboratori Nazionali del Sud (LNS) in Catania, in the angular range between ∼2{sup 0} and 12{sup 0} in the laboratory system, giving us the possibility to span almost a full angular range in the center of mass system. Results will be presented and discussed for one of the energies.

  5. Performance of the Community Earth System Model (Conference) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Conference: Performance of the Community Earth System Model Citation Details In-Document Search Title: Performance of the Community Earth System Model The Community Earth System Model (CESM), released in June 2010, incorporates new physical process and new numerical algorithm options, significantly enhancing simulation capabilities over its predecessor, the June 2004 release of the Community Climate System Model. CESM also includes enhanced performance tuning options and performance

  6. Earth System Modeling (ESM) Program | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Earth System Modeling (ESM) Program Biological and Environmental Research (BER) BER Home About Research Biological Systems Science Division (BSSD) Climate and Environmental Sciences Division (CESD) ARM Climate Research Facility Atmospheric System Research (ASR) Program Data Management Earth System Modeling (ESM) Program William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) Integrated Assessment of Global Climate Change Regional & Global Climate Modeling (RGCM) Program

  7. DOE Science Showcase - Earth System Models | OSTI, US Dept of Energy,

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information Earth System Models U.S. DOE Office of Science: Getting Forest Carbon Right in Climate Models. "Boreal Forest" Image Credit: Wikimedia Commons, peupleloup. Optimizing emerging high-performance computing and information technologies, the Department of Energy's (DOE) Earth System Modeling (ESM) Program concentrates on advancing coupled climate and earth system models for climate change projections at global-to-regional spatial scales and

  8. Final Report for proposal "The Interface between Earth System Models and

    Office of Scientific and Technical Information (OSTI)

    Impacts on Society Workshop, Spring 2011 (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Final Report for proposal "The Interface between Earth System Models and Impacts on Society Workshop, Spring 2011 Citation Details In-Document Search Title: Final Report for proposal "The Interface between Earth System Models and Impacts on Society Workshop, Spring 2011 The creation of a new Community Earth System Model (CESM) working group, combining

  9. DOE SciDAC's Earth System Grid Center for Enabling Technologies Final

    Office of Scientific and Technical Information (OSTI)

    Report (Technical Report) | SciTech Connect DOE SciDAC's Earth System Grid Center for Enabling Technologies Final Report Citation Details In-Document Search Title: DOE SciDAC's Earth System Grid Center for Enabling Technologies Final Report The mission of the Earth System Grid Federation (ESGF) is to provide the worldwide climate-research community with access to the data, information, model codes, analysis tools, and intercomparison capabilities required to make sense of enormous climate

  10. BioEarth: Envisioning and developing a new regional earth system model to inform natural and agricultural resource management

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adam, Jennifer C.; Stephens, Jennie C.; Chung, Serena H.; Brady, Michael P.; Evans, R. David; Kruger, Chad E.; Lamb, Brian K.; Liu, Mingliang; Stöckle, Claudio O.; Vaughan, Joseph K.; et al

    2014-04-24

    Uncertainties in global change impacts, the complexities associated with the interconnected cycling of nitrogen, carbon, and water present daunting management challenges. Existing models provide detailed information on specific sub-systems (e.g., land, air, water, and economics). An increasing awareness of the unintended consequences of management decisions resulting from interconnectedness of these sub-systems, however, necessitates coupled regional earth system models (EaSMs). Decision makers’ needs and priorities can be integrated into the model design and development processes to enhance decision-making relevance and “usability” of EaSMs. BioEarth is a research initiative currently under development with a focus on the U.S. Pacific Northwest region thatmore » explores the coupling of multiple stand-alone EaSMs to generate usable information for resource decision-making. Direct engagement between model developers and non-academic stakeholders involved in resource and environmental management decisions throughout the model development process is a critical component of this effort. BioEarth utilizes a bottom-up approach for its land surface model that preserves fine spatial-scale sensitivities and lateral hydrologic connectivity, which makes it unique among many regional EaSMs. Here, we describe the BioEarth initiative and highlights opportunities and challenges associated with coupling multiple stand-alone models to generate usable information for agricultural and natural resource decision-making.« less

  11. BioEarth: Envisioning and developing a new regional earth system model to inform natural and agricultural resource management

    SciTech Connect (OSTI)

    Adam, J. C.; Stephens, J. C.; Chung, Serena; Brady, M. P.; Evans, R. D.; Kruger, C. E.; Lamb, Brian K.; Liu, M. L.; Stockle, Claudio O.; Vaughan, Joseph K.; Rajagopalan, K.; Harrison, John; Tague, C. L.; Kalyanaraman, Anantharaman; Chen, Yong; Guenther, Alex B.; Leung, F. Y.; Leung, Lai-Yung R.; Perleberg, A. B.; Yoder, J.; Allen, Elizabeth; Anderson, S.; Chandrasekharan, B.; Malek, K.; Mullis, T.; Miller, C.; Nergui, T.; Poinsatte, J.; Reyes, J.; Zhu, J.; Choate, J. S.; Jiang, X.; Nelson, R.; Yoon, Jin-Ho; Yorgey, G. G.; Johnson, Kristen; Chinnayakanhalli, K. J.; Hamlet, A. F.; Nijssen, B.; Walden, Von

    2015-04-01

    As managers of agricultural and natural resources are confronted with uncertainties in global change impacts, the complexities associated with the interconnected cycling of nitrogen, carbon, and water present daunting management challenges. Existing models provide detailed information on specific sub-systems (land, air, water, economics, etc). An increasing awareness of the unintended consequences of management decisions resulting from interconnectedness of these sub-systems, however, necessitates coupled regional earth system models (EaSMs). Decision makers needs and priorities can be integrated into the model design and development processes to enhance decision-making relevance and "usability" of EaSMs. BioEarth is a current research initiative with a focus on the U.S. Pacific Northwest region that explores the coupling of multiple stand-alone EaSMs to generate usable information for resource decision-making. Direct engagement between model developers and non-academic stakeholders involved in resource and environmental management decisions throughout the model development process is a critical component of this effort. BioEarth utilizes a "bottom-up" approach, upscaling a catchment-scale model to basin and regional scales, as opposed to the "top-down" approach of downscaling global models utilized by most other EaSM efforts. This paper describes the BioEarth initiative and highlights opportunities and challenges associated with coupling multiple stand-alone models to generate usable information for agricultural and natural resource decision-making.

  12. Scaling the Earth System Grid to 100Gbps Networks

    SciTech Connect (OSTI)

    Balman, Mehmet; Sim, Alex

    2012-03-02

    The SC11 demonstration, titled Scaling the Earth System Grid to 100Gbps Networks, showed the ability to use underlying infrastructure for the movement of climate data over 100Gbps network. Climate change research is one of the critical data intensive sciences, and the amount of data is continuously growing. Climate simulation data is geographically distributed over the world, and it needs to be accessed from many sources for fast and efficient analysis and inter-comparison of simulations. We used a 100Gbps link connecting National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory (LBNL), Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL). In the demo, the Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report (AR4) phase 3 of the Coupled Model Intercomparison Project (CMIP-3) dataset was staged into the memory of computing nodes at ANL and ORNL from NERSC over the 100Gbps network for analysis and visualization. In general, climate simulation data consists of relatively small and large files with irregular file size distribution in each dataset. In this demo, we addressed challenges on data management in terms of high bandwidth networks, usability of existing protocols and middleware tools, and how applications can adapt and benefit from next generation networks.

  13. Improving the representation of hydrologic processes in Earth System Models

    SciTech Connect (OSTI)

    Clark, Martyn P.; Fan, Ying; Lawrence, David M.; Adam, J. C.; Bolster, Diogo; Gochis, David; Hooper, Richard P.; Kumar, Mukesh; Leung, Lai-Yung R.; Mackay, D. Scott; Maxwell, Reed M.; Shen, Chaopeng; Swenson, Sean C.; Zeng, Xubin

    2015-08-21

    Many of the scientific and societal challenges in understanding and preparing for global environmental change rest upon our ability to understand and predict the water cycle change at large river basin, continent, and global scales. However, current large-scale models, such as the land components of Earth System Models (ESMs), do not yet represent the terrestrial water cycle in a fully integrated manner or resolve the finer-scale processes that can dominate large-scale water budgets. This paper reviews the current representation of hydrologic processes in ESMs and identifies the key opportunities for improvement. This review suggests that (1) the development of ESMs has not kept pace with modeling advances in hydrology, both through neglecting key processes (e.g., groundwater) and neglecting key aspects of spatial variability and hydrologic connectivity; and (2) many modeling advances in hydrology can readily be incorporated into ESMs and substantially improve predictions of the water cycle. Accelerating modeling advances in ESMs requires comprehensive hydrologic benchmarking activities, in order to systematically evaluate competing modeling alternatives, understand model weaknesses, and prioritize model development needs. This demands stronger collaboration, both through greater engagement of hydrologists in ESM development and through more detailed evaluation of ESM processes in research watersheds. Advances in the representation of hydrologic process in ESMs can substantially improve energy, carbon and nutrient cycle prediction capabilities through the fundamental role the water cycle plays in regulating these cycles.

  14. 9Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    deduced log ft, Gamow-Teller transition strength, level width, di-neutron, neutron halo roles. 1991LUZZ: 9Li(-); measured T12. 1992LI24: 9Li(-); measured NMR...

  15. 07Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li Thermal Neutron Capture Evaluated Data Measurements 1967RA24: 6Li(n, ), E thermal; measured E; deduced Q. 1968SP01: 6Li(n, ), E thermal; measured E, I; deduced Q....

  16. 08Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Neutron Capture Evaluated Data Measurements 1967RA24: 7Li(n, ), E thermal; measured E; deduced Q. 1973JUZT, 1973JUZU: 7Li(n, ), E thermal; measured (E). 7Li...

  17. 11Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li β--Decay Evaluated Data Measurements 1969KL08: 11Li; measured T1/2. 1974RO31: 11Li; measured Eγ, Iγ, T1/2, delayed neutrons, βγ-coin, Eβ. 1975TH08: 11Li; measured neutron binding energy, delayed neutron branching ratio, T1/2; deduced log ft. 1979ANZZ: 11Li; 11Li deduced evidence for β-delayed 2n emission. 1979AZ03: 11Li; measured β-delayed En, nn-coin. 11Be levels deduced 1n, 2n decay probabilities. 1979DEYX, 1980DE39, 1980DEZF: 11Li; measured Eγ, Iγ, Iβ, β-delayed En, In; deduced

  18. 5Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li Ground-State Decay Evaluated Data Measured Ground-State Γcm for 5Li Adopted value: 1.23 MeV (2002TI10) Measured Mass Excess for 5Li Adopted value: 11680 ± 50 keV (2003AU02) Measurements 1960BA45: 5Li; measured not abstracted; deduced nuclear properties. 1960BR10: 5Li; measured not abstracted; deduced nuclear properties. 1960BR19: 5Li; measured not abstracted; deduced nuclear properties. 1960HA14: 5Li; measured not abstracted; deduced nuclear properties. 1960PE14: 5Li; measured not

  19. Runtime Tracing of The Community Earth System Model: Feasibility and Benefits

    SciTech Connect (OSTI)

    Wang, Dali [ORNL] [ORNL; Domke, Jens [ORNL] [ORNL

    2011-01-01

    Community Earth System Models (CESM) is one of US's leading earth system modeling systems, which has over decades of development history and embraced by large, active user communities. In this paper, we first review the history of CESM software development and layout the general objectives of performance analysis. Then we present an offline global community land model simulation within the CESM framework to demonstrate the procedure of runtime tracing of CESM using the Vampir toolset. Finally, we explain the benefits of runtime tracing to the general earth system modeling community. We hope those considerations can also be beneficial to many other modeling research programs involving legacy high-performance computing applications.

  20. Earth System Modeling -- Director`s initiative. LDRD Program final report

    SciTech Connect (OSTI)

    MacCracken, M.; Penner, J. [Lawrence Livermore National Lab., CA (United States). Atmospheric Science Div.

    1996-06-01

    The objective of the Earth System Modeling Director`s Initiative is to develop and test a framework for interactively coupling subsystem models that represent the physical, chemical, and biological processes which determine the state of the atmosphere, ocean, land surface and vegetation. Most studies of the potential for human perturbations of the climate system made previously have treated only limited components of the Earth system. The purpose of this project was to demonstrate the capability of coupling all relevant components in a flexible framework that will permit a wide variety of tests to be conducted to assure realistic interactions. A representation of the Earth system is shown and its important interactions.

  1. 2011 Community Earth System Model (CESM) Tutorial, August 1-5, 2011

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: 2011 Community Earth System Model (CESM) Tutorial, August 1-5, 2011 Citation Details In-Document Search Title: 2011 Community Earth System Model (CESM) Tutorial, August 1-5, 2011 In fiscal year 2011, the Community Earth System Model (CESM) tutorial was taught at NCAR from 1-5 August 2011. This project hosted 79 full participants (1 accepted participant from China couldn't get a visa) selected from 180 applications. The tutorial was advertised

  2. DOE SciDAC's Earth System Grid Center for Enabling Technologies...

    Office of Scientific and Technical Information (OSTI)

    For the ESGF, the U.S. Department of Energy's (DOE's) Earth System Grid Center for ... Publication Date: 2013-12-19 OSTI Identifier: 1111156 Report Number(s): DOE-USC-25773 DOE ...

  3. In the OSTI Collections: Earth System Models | OSTI, US Dept of Energy,

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information Earth System Models Dr. Watson computer sleuthing scientist. Article Acknowledgement: Dr. William N. Watson, Physicist DOE Office of Scientific and Technical Information Experiment, theoretical analysis, and something like both Perfecting and using earth system models Enabling technologies, user training Towards decisions References Reports available from SciTech Connect Research organizations Additional References "The abstract of the

  4. DOE SciDAC's Earth System Grid Center for Enabling Technologies Final

    Office of Scientific and Technical Information (OSTI)

    Report for University of Southern California Information Sciences Institute (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: DOE SciDAC's Earth System Grid Center for Enabling Technologies Final Report for University of Southern California Information Sciences Institute Citation Details In-Document Search Title: DOE SciDAC's Earth System Grid Center for Enabling Technologies Final Report for University of Southern California Information Sciences Institute

  5. THE EFFECTS OF HALIDE MODIFIERS ON THE SORPTION KINETICS OF THE LI-MG-N-H SYSTEM

    SciTech Connect (OSTI)

    Anton, D.; Gray, J.; Price, C.; Lascola, R.

    2011-07-20

    The effects of different transition metal halides (TiCl{sub 3}, VCl{sub 3}, ScCl{sub 3} and NiCl{sub 2}) on the sorption properties of the 1:1 molar ratio of LiNH{sub 2} to MgH{sub 2} are investigated. The modified mixtures were found to contain LiNH{sub 2}, MgH{sub 2} and LiCl. TGA results showed that the hydrogen desorption temperature was reduced with the modifier addition in this order: TiCl{sub 3} > ScCl{sub 3} > VCl{sub 3} > NiCL{sub 2}. Ammonia release was not significantly reduced resulting in a weight loss greater than the theoretical hydrogen storage capacity of the material. The isothermal sorption kinetics of the modified systems showed little improvement after the first dehydrogenation cycle over the unmodified system but showed drastic improvement in rehydrogenation cycles. X-ray diffraction and Raman spectroscopy identified the cycled material to be composed of LiH, MgH{sub 2}, Mg(NH{sub 2}){sub 2} and Mg{sub 3}N{sub 2}.

  6. 4Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vs relative E(3He, n), E(3He, p); deduced . 4Li deduced levels, . 1996ED02: 4He(p, nX), E 100, 200 MeV; measured inclusive (, En). 4Li deduced evidence for narrow...

  7. 10Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li Ground-State Decay Evaluated Data Measured Ground-State Γcm(T1/2) for 10Li Adopted value: 2.0 ± 0.5 zs (2003AU02) Measured Mass Excess for 10Li Adopted value: 33051 ± 15 keV (2003AU02) Measurements 1975WI26: 9Be(9Be, 8B), E = 121 MeV; measured σ(E(8B), θ); deduced Q. 10Li deduced mass excess. 1990AM05: 11B(π-, X), E at rest; measured inclusive p-, d-, t-spectra, X = 10Li production. 10Li deduced level, Γ. 1992AMZY: 11B(π-, X), E at rest; measured pion, deuteron, triton spectra. 10Li

  8. Toward an Earth System Modeling Approach to Simulate Irrigation Effects |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Technical Report) | SciTech Connect Toward a new metric for ranking high performance computing systems. Citation Details In-Document Search Title: Toward a new metric for ranking high performance computing systems. The High Performance Linpack (HPL), or Top 500, benchmark [1] is the most widely recognized and discussed metric for ranking high performance computing systems. However, HPL is increasingly unreliable as a true measure of system performance for a growing collection of important

  9. The Ho-Ni-Ge system: Isothermal section and new rare-earth nickel

    Office of Scientific and Technical Information (OSTI)

    germanides (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: The Ho-Ni-Ge system: Isothermal section and new rare-earth nickel germanides Citation Details In-Document Search Title: The Ho-Ni-Ge system: Isothermal section and new rare-earth nickel germanides The Ho-Ni-Ge system has been investigated at 1070 K and up to ~60 at% Ho by X-ray diffraction and microprobe analyses. Besides the eight known compounds, HoNi{sub 5}Ge{sub 3} (YNi{sub 5}Si{sub 3}-type),

  10. Characterization of the LiSi/CsBr-LiBr-KBr/FeS(2) System for Potential Use as a Geothermal Borehole Power Source

    SciTech Connect (OSTI)

    GUIDOTTI, RONALD A.; REINHARDT, FREDERICK W.

    1999-10-18

    We are continuing to study the suitability of modified thermal-battery technology as a potential power source for geothermal borehole applications. Previous work focused on the LiSi/FeS{sub 2} couple over a temperature range of 350 C to 400 C with the LiBr-KBr-LiF eutectic, which melts at 324.5 C. In this work, the discharge processes that take place in LiSi/CsBr-LiBr-KBr eutectic/FeS{sub 2} thermal cells were studied at temperatures between 250 C and 400 C using pelletized cells with immobilized electrolyte. The CsBr-LiBr-KBr eutectic was selected because of its lower melting point (228.5 C). Incorporation of a quasi-reference electrode allowed the determination of the relative contribution of each electrode to the overall cell polarization. The results of single-cell tests and limited battery tests are presented, along with preliminary data for battery stacks tested in a simulated geothermal borehole environment.

  11. Materials for Better Li-based Storage Systems for a "Green Energy Society"

    ScienceCinema (OSTI)

    Jean-Marie Tarascon

    2010-01-08

    Li-ion batteries are strongly considered for powering the upcoming generations of HEVs and PHEVs, but there are still the issues of safety and costs in terms of materials resources and abundances, synthesis, and recycling processes. Notions of materials having minimum footprint in nature, made via eco-efficient processes, must be integrated in our new research towards the next generation of sustainable and "greener" Li-ion batteries. In this July 13, 2009 talk sponsored by Berkeley Lab's Environental Energy Technologies Division, Jean-Marie Tarascon, a professor at the University of Picardie (Amiens), discuss Eco-efficient synthesis via hydrothermal/solvothermal processes using latent bases as well as structure directing templates or other bio-related approaches of LiFePO4 nanopowders.

  12. 8Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -asymmetry, NMR; deduced polarization. 1986WA01: 8Li(-); analyzed -delayed breakup -spectra; deduced intruder states role. 8Be deduced level, , Gamow-Teller matrix...

  13. 2013 Community Earth System Model (CESM) Tutorial-Proposal to DOE

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect 3 Community Earth System Model (CESM) Tutorial-Proposal to DOE Citation Details In-Document Search Title: 2013 Community Earth System Model (CESM) Tutorial-Proposal to DOE × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and

  14. Optimal Initial Conditions for Coupling Ice Sheet Models to Earth System

    Office of Scientific and Technical Information (OSTI)

    Models. (Journal Article) | SciTech Connect Optimal Initial Conditions for Coupling Ice Sheet Models to Earth System Models. Citation Details In-Document Search Title: Optimal Initial Conditions for Coupling Ice Sheet Models to Earth System Models. Abstract not provided. Authors: Perego, Mauro ; Price, Stephen ; Stadler, Georg Publication Date: 2014-04-01 OSTI Identifier: 1142266 Report Number(s): SAND2014-2781J 507169 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Journal Article

  15. Improved structural systems for earth sheltered housing. Structural supplement to the design program

    SciTech Connect (OSTI)

    Behr, R.

    1981-10-01

    Additional engineering information is provided with regard to the structural analysis and design of thin shell concrete structures. The design program has tentatively demonstrated the overall architectural and marketing feasibility of curved, thin shell structural systems for earth sheltered housing. This supplement will address the structural feasibility question by presenting a complete manual analysis and structural design of an earth sheltered dome/tension ring/wall structural system, and also by presenting the results of a parametric sensitivity study of the dome/ring/wall configuration with respect to variations in span and rise for a three foot soil loading condition. Double curvature dome configurations are emphasized in this structural supplement because their analysis is not extensively addressed in earth sheltered housing literature.

  16. Earth System Grid (ESG) Data Node Software Stack

    Energy Science and Technology Software Center (OSTI)

    2009-12-01

    The ESG-CET system consist of two major components: 1) Gateways that support portal services, which serve as interfaces to end-users who can search, discover, and request data and data products, and 2) Data Nodes where the data actually resides. The Data is "published" to the Data Node, which makes the data visible to a Gateway and enables its delivery to end-users. It is expected that Gateways will only be installed by a small number ofmore » centers devoted to serving data (e.g., LLNL/PCMDI, NCAR, GFDL, DADC, DKRZ, ANU, JAMSTEC), whereas it is hoped that most climate modeling centers will install the Data Node software through which they can serve their model output.« less

  17. PMEL contributions to the collaboration: SCALING THE EARTH SYSTEM GRID TO PETASCALE DATA for the DOE SciDACs Earth System Grid Center for Enabling Technologies

    SciTech Connect (OSTI)

    Hankin, Steve

    2012-06-01

    Drawing to a close after five years of funding from DOE's ASCR and BER program offices, the SciDAC-2 project called the Earth System Grid (ESG) Center for Enabling Technologies has successfully established a new capability for serving data from distributed centers. The system enables users to access, analyze, and visualize data using a globally federated collection of networks, computers and software. The ESG software??now known as the Earth System Grid Federation (ESGF)??has attracted a broad developer base and has been widely adopted so that it is now being utilized in serving the most comprehensive multi-model climate data sets in the world. The system is used to support international climate model intercomparison activities as well as high profile U.S. DOE, NOAA, NASA, and NSF projects. It currently provides more than 25,000 users access to more than half a petabyte of climate data (from models and from observations) and has enabled over a 1,000 scientific publications.

  18. Interaction of CuS and sulfur in Li-S battery system

    SciTech Connect (OSTI)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, under a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.

  19. Interaction of CuS and sulfur in Li-S battery system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, undermore » a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.« less

  20. The integrated Earth System Model (iESM): formulation and functionality

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collins, W. D.; Craig, A. P.; Truesdale, J. E.; Di Vittorio, A. V.; Jones, A. D.; Bond-Lamberty, B.; Calvin, K. V.; Edmonds, J. A.; Kim, S. H.; Thomson, A. M.; et al

    2015-01-21

    The integrated Earth System Model (iESM) has been developed as a new tool for projecting the joint human/climate system. The iESM is based upon coupling an Integrated Assessment Model (IAM) and an Earth System Model (ESM) into a common modeling infrastructure. IAMs are the primary tool for describing the human–Earth system, including the sources of global greenhouse gases (GHGs) and short-lived species, land use and land cover change, and other resource-related drivers of anthropogenic climate change. ESMs are the primary scientific tools for examining the physical, chemical, and biogeochemical impacts of human-induced changes to the climate system. The iESM projectmore » integrates the economic and human dimension modeling of an IAM and a fully coupled ESM within a single simulation system while maintaining the separability of each model if needed. Both IAM and ESM codes are developed and used by large communities and have been extensively applied in recent national and international climate assessments. By introducing heretofore-omitted feedbacks between natural and societal drivers, we can improve scientific understanding of the human–Earth system dynamics. Potential applications include studies of the interactions and feedbacks leading to the timing, scale, and geographic distribution of emissions trajectories and other human influences, corresponding climate effects, and the subsequent impacts of a changing climate on human and natural systems. This paper describes the formulation, requirements, implementation, testing, and resulting functionality of the first version of the iESM released to the global climate community.« less

  1. Development of hybrid 3-D hydrological modeling for the NCAR Community Earth System Model (CESM)

    SciTech Connect (OSTI)

    Zeng, Xubin; Troch, Peter; Pelletier, Jon; Niu, Guo-Yue; Gochis, David

    2015-11-15

    This is the Final Report of our four-year (3-year plus one-year no cost extension) collaborative project between the University of Arizona (UA) and the National Center for Atmospheric Research (NCAR). The overall objective of our project is to develop and evaluate the first hybrid 3-D hydrological model with a horizontal grid spacing of 1 km for the NCAR Community Earth System Model (CESM).

  2. Multicomponent analysis of mixed rare-earth metal ion solutions by the electronic tongue sensor system

    SciTech Connect (OSTI)

    Legin, A.; Kirsanov, D.; Rudnitskaya, A.; Rovny, S.; Logunov, M.

    2007-07-01

    Novel electrochemical sensors based on well-known extracting agents are developed. Sensors have shown high sensitivity towards a variety of rear earth metal ions in acidic media at pH=2. Multi-sensor system (electronic tongue) comprising newly developed sensors was successfully applied for the analysis of binary and ternary mixtures of Ce{sup 3+}, Nd{sup 3+}, Sm{sup 3+} and Gd{sup 3+} cations in different combinations. (authors)

  3. A Subbasin-based framework to represent land surface processes in an Earth System Model

    SciTech Connect (OSTI)

    Tesfa, Teklu K.; Li, Hongyi; Leung, Lai-Yung R.; Huang, Maoyi; Ke, Yinghai; Sun, Yu; Liu, Ying

    2014-05-20

    Realistically representing spatial heterogeneity and lateral land surface processes within and between modeling units in earth system models is important because of their implications to surface energy and water exchange. The traditional approach of using regular grids as computational units in land surface models and earth system models may lead to inadequate representation of lateral movements of water, energy and carbon fluxes, especially when the grid resolution increases. Here a new subbasin-based framework is introduced in the Community Land Model (CLM), which is the land component of the Community Earth System Model (CESM). Local processes are represented assuming each subbasin as a grid cell on a pseudo grid matrix with no significant modifications to the existing CLM modeling structure. Lateral routing of water within and between subbasins is simulated with the subbasin version of a recently-developed physically based routing model, Model for Scale Adaptive River Routing (MOSART). As an illustration, this new framework is implemented in the topographically diverse region of the U.S. Pacific Northwest. The modeling units (subbasins) are delineated from high-resolution Digital Elevation Model while atmospheric forcing and surface parameters are remapped from the corresponding high resolution datasets. The impacts of this representation on simulating hydrologic processes are explored by comparing it with the default (grid-based) CLM representation. In addition, the effects of DEM resolution on parameterizing topography and the subsequent effects on runoff processes are investigated. Limited model evaluation and comparison showed that small difference between the averaged forcing can lead to more significant difference in the simulated runoff and streamflow because of nonlinear horizontal processes. Topographic indices derived from high resolution DEM may not improve the overall water balance, but affect the partitioning between surface and subsurface runoff. More systematic analyses are needed to determine the relative merits of the subbasin representation compared to the commonly used grid-based representation, especially when land surface models are approaching higher resolutions.

  4. On an improved sub-regional water resources management representation for integration into earth system models

    SciTech Connect (OSTI)

    Voisin, Nathalie; Li, Hongyi; Ward, Duane L.; Huang, Maoyi; Wigmosta, Mark S.; Leung, Lai-Yung R.

    2013-09-30

    Human influence on the hydrologic cycle includes regulation and storage, consumptive use and overall redistribution of water resources in space and time. Representing these processes is essential for applications of earth system models in hydrologic and climate predictions, as well as impact studies at regional to global scales. Emerging large-scale research reservoir models use generic operating rules that are flexible for coupling with earth system models. Those generic operating rules have been successful in reproducing the overall regulated flow at large basin scales. This study investigates the uncertainties of the reservoir models from different implementations of the generic operating rules using the complex multi-objective Columbia River Regulation System in northwestern United States as an example to understand their effects on not only regulated flow but also reservoir storage and fraction of the demand that is met. Numerical experiments are designed to test new generic operating rules that combine storage and releases targets for multi-purpose reservoirs and to compare the use of reservoir usage priorities, withdrawals vs. consumptive demand, as well as natural vs. regulated mean flow for calibrating operating rules. Overall the best performing implementation is the use of the combined priorities (flood control storage targets and irrigation release targets) operating rules calibrated with mean annual natural flow and mean monthly withdrawals. The challenge of not accounting for groundwater withdrawals, or on the contrary, assuming that all remaining demand is met through groundwater extractions, is discussed.

  5. Progress Report 2008: A Scalable and Extensible Earth System Model for Climate Change Science

    SciTech Connect (OSTI)

    Drake, John B; Worley, Patrick H; Hoffman, Forrest M; Jones, Phil

    2009-01-01

    This project employs multi-disciplinary teams to accelerate development of the Community Climate System Model (CCSM), based at the National Center for Atmospheric Research (NCAR). A consortium of eight Department of Energy (DOE) National Laboratories collaborate with NCAR and the NASA Global Modeling and Assimilation Office (GMAO). The laboratories are Argonne (ANL), Brookhaven (BNL) Los Alamos (LANL), Lawrence Berkeley (LBNL), Lawrence Livermore (LLNL), Oak Ridge (ORNL), Pacific Northwest (PNNL) and Sandia (SNL). The work plan focuses on scalablity for petascale computation and extensibility to a more comprehensive earth system model. Our stated goal is to support the DOE mission in climate change research by helping ... To determine the range of possible climate changes over the 21st century and beyond through simulations using a more accurate climate system model that includes the full range of human and natural climate feedbacks with increased realism and spatial resolution.

  6. Earth materials and earth dynamics

    SciTech Connect (OSTI)

    Bennett, K; Shankland, T.

    2000-11-01

    In the project ''Earth Materials and Earth Dynamics'' we linked fundamental and exploratory, experimental, theoretical, and computational research programs to shed light on the current and past states of the dynamic Earth. Our objective was to combine different geological, geochemical, geophysical, and materials science analyses with numerical techniques to illuminate active processes in the Earth. These processes include fluid-rock interactions that form and modify the lithosphere, non-linear wave attenuations in rocks that drive plate tectonics and perturb the earth's surface, dynamic recrystallization of olivine that deforms the upper mantle, development of texture in high-pressure olivine polymorphs that create anisotropic velocity regions in the convecting upper mantle and transition zone, and the intense chemical reactions between the mantle and core. We measured physical properties such as texture and nonlinear elasticity, equation of states at simultaneous pressures and temperatures, magnetic spins and bonding, chemical permeability, and thermal-chemical feedback to better characterize earth materials. We artificially generated seismic waves, numerically modeled fluid flow and transport in rock systems and modified polycrystal plasticity theory to interpret measured physical properties and integrate them into our understanding of the Earth. This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL).

  7. 2014 Earth System Grid Federation and Ultrascale Visualization Climate Data Analysis Tools Conference Report

    SciTech Connect (OSTI)

    Williams, Dean N.

    2015-01-27

    The climate and weather data science community met December 9–11, 2014, in Livermore, California, for the fourth annual Earth System Grid Federation (ESGF) and Ultrascale Visualization Climate Data Analysis Tools (UV-CDAT) Face-to-Face (F2F) Conference, hosted by the Department of Energy, National Aeronautics and Space Administration, National Oceanic and Atmospheric Administration, the European Infrastructure for the European Network of Earth System Modelling, and the Australian Department of Education. Both ESGF and UVCDATremain global collaborations committed to developing a new generation of open-source software infrastructure that provides distributed access and analysis to simulated and observed data from the climate and weather communities. The tools and infrastructure created under these international multi-agency collaborations are critical to understanding extreme weather conditions and long-term climate change. In addition, the F2F conference fosters a stronger climate and weather data science community and facilitates a stronger federated software infrastructure. The 2014 F2F conference detailed the progress of ESGF, UV-CDAT, and other community efforts over the year and sets new priorities and requirements for existing and impending national and international community projects, such as the Coupled Model Intercomparison Project Phase Six. Specifically discussed at the conference were project capabilities and enhancements needs for data distribution, analysis, visualization, hardware and network infrastructure, standards, and resources.

  8. A modern solver framework to manage solution algorithms in the Community Earth System Model

    SciTech Connect (OSTI)

    Evans, Katherine J [ORNL; Worley, Patrick H [ORNL; Nichols, Dr Jeff A [ORNL; WhiteIII, James B [National Center for Atmospheric Research (NCAR); Salinger, Andy [Sandia National Laboratories (SNL); Price, Stephen [Los Alamos National Laboratory (LANL); Lemieux, Jean-Francois [New York University; Lipscomb, William [Los Alamos National Laboratory (LANL); Perego, Mauro [Florida State University; Vertenstein, Mariana [National Center for Atmospheric Research (NCAR); Edwards, Jim [IBM and National Center for Atmospheric Research

    2012-01-01

    Global Earth-system models (ESM) can now produce simulations that resolve ~50 km features and include finer-scale, interacting physical processes. In order to achieve these scale-length solutions, ESMs require smaller time steps, which limits parallel performance. Solution methods that overcome these bottlenecks can be quite intricate, and there is no single set of algorithms that perform well across the range of problems of interest. This creates significant implementation challenges, which is further compounded by complexity of ESMs. Therefore, prototyping and evaluating new algorithms in these models requires a software framework that is flexible, extensible, and easily introduced into the existing software. We describe our efforts to create a parallel solver framework that links the Trilinos library of solvers to Glimmer-CISM, a continental ice sheet model used in the Community Earth System Model (CESM). We demonstrate this framework within both current and developmental versions of Glimmer-CISM and provide strategies for its integration into the rest of the CESM.

  9. The Earth System Grid Federation: An Open Infrastructure for Access to Distributed Geo-Spatial Data

    SciTech Connect (OSTI)

    Cinquini, Luca; Crichton, Daniel; Miller, Neill; Mattmann, Chris; Harney, John F; Shipman, Galen M; Wang, Feiyi; Bell, Gavin; Drach, Bob; Ananthakrishnan, Rachana; Pascoe, Stephen; Fiore, Sandro; Schweitzer, Roland; Danvil, Sebastian; Morgan, Mark

    2012-01-01

    The Earth System Grid Federation (ESGF) is a multi-agency, international collaboration that aims at developing the software infrastructure needed to facilitate and empower the study of climate change on a global scale. The ESGF s architecture employs a system of geographically distributed peer nodes, which are independently administered yet united by the adoption of common federation protocols and application programming interfaces (APIs). The cornerstones of its interoperability are the peer-to-peer messaging that is continuously exchanged among all nodes in the federation; a shared architecture and API for search and discovery; and a security infrastructure based on industry standards (OpenID, SSL, GSI and SAML). The ESGF software is developed collaboratively across institutional boundaries and made available to the community as open source. It has now been adopted by multiple Earth science projects and allows access to petabytes of geophysical data, including the entire model output used for the next international assessment report on climate change (IPCC-AR5) and a suite of satellite observations (obs4MIPs) and reanalysis data sets (ANA4MIPs).

  10. Final Report Collaborative Project. Improving the Representation of Coastal and Estuarine Processes in Earth System Models

    SciTech Connect (OSTI)

    Bryan, Frank; Dennis, John; MacCready, Parker; Whitney, Michael

    2015-11-20

    This project aimed to improve long term global climate simulations by resolving and enhancing the representation of the processes involved in the cycling of freshwater through estuaries and coastal regions. This was a collaborative multi-institution project consisting of physical oceanographers, climate model developers, and computational scientists. It specifically targeted the DOE objectives of advancing simulation and predictive capability of climate models through improvements in resolution and physical process representation. The main computational objectives were: 1. To develop computationally efficient, but physically based, parameterizations of estuary and continental shelf mixing processes for use in an Earth System Model (CESM). 2. To develop a two-way nested regional modeling framework in order to dynamically downscale the climate response of particular coastal ocean regions and to upscale the impact of the regional coastal processes to the global climate in an Earth System Model (CESM). 3. To develop computational infrastructure to enhance the efficiency of data transfer between specific sources and destinations, i.e., a point-to-point communication capability, (used in objective 1) within POP, the ocean component of CESM.

  11. The Earth System Grid Federation: An Open Infrastructure for Access to Distributed Geospatial Data

    SciTech Connect (OSTI)

    Ananthakrishnan, Rachana; Bell, Gavin; Cinquini, Luca; Crichton, Daniel; Danvil, Sebastian; Drach, Bob; Fiore, Sandro; Gonzalez, Estanislao; Harney, John F; Mattmann, Chris; Kershaw, Philip; Morgan, Mark; Pascoe, Stephen; Shipman, Galen M; Wang, Feiyi

    2013-01-01

    The Earth System Grid Federation (ESGF) is a multi-agency, international collaboration that aims at developing the software infrastructure needed to facilitate and empower the study of climate change on a global scale. The ESGF s architecture employs a system of geographically distributed peer nodes, which are independently administered yet united by the adoption of common federation protocols and application programming interfaces (APIs). The cornerstones of its interoperability are the peer-to-peer messaging that is continuously exchanged among all nodes in the federation; a shared architecture and API for search and discovery; and a security infrastructure based on industry standards (OpenID, SSL, GSI and SAML). The ESGF software is developed collaboratively across institutional boundaries and made available to the community as open source. It has now been adopted by multiple Earth science projects and allows access to petabytes of geophysical data, including the entire model output used for the next international assessment report on climate change (IPCC-AR5) and a suite of satellite observations (obs4MIPs) and reanalysis data sets (ANA4MIPs).

  12. Exploring the isopycnal mixing and helium-heat paradoxes in a suite of Earth System Models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gnanadesikan, A.; Abernathey, R.; Pradal, M.-A.

    2014-11-20

    This paper uses a suite of Earth System models which simulate the distribution of He isotopes and radiocarbon to examine two paradoxes in Earth science. The helium-heat paradox refers to the fact that helium emissions to the deep ocean are far lower than would be expected given the rate of geothermal heating, since both are thought to be the result of radioactive decay in the earth's interior. The isopycnal mixing paradox comes from the fact that many theoretical parameterizations of the isopycnal mixing coefficient ARedi that link it to baroclinic instability project it to be small (of order a fewmore » hundred m2 s−1) in the ocean interior away from boundary currents. However, direct observations using tracers and floats (largely in the upper ocean) suggest that values of this coefficient are an order of magnitude higher. Because helium isotopes equilibrate rapidly with the atmosphere, but radiocarbon equilibrates slowly, it might be thought that resolving the isopycnal mixing paradox in favor of the higher observational estimates of ARedi might also solve the helium paradox. In this paper we show that this is not the case. In a suite of models with different spatially constant and spatially varying values of ARedi the distribution of radiocarbon and helium isotopes is sensitive to the value of ARedi. However, away from strong helium sources in the Southeast Pacific, the relationship between the two is not sensitive, indicating that large-scale advection is the limiting process for removing helium and radiocarbon from the deep ocean. The helium isotopes, in turn, suggest a higher value of ARedi in the deep ocean than is seen in theoretical parameterizations based on baroclinic growth rates. We argue that a key part of resolving the isopycnal mixing paradox is to abandon the idea that ARedi has a direct relationship to local baroclinic instability and to the so called "thickness" mixing coefficient AGM.« less

  13. Effects of Ti-Based Additives on the Hydrogen Storage Properties of aLiBH4/CaH2Destabilized System

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Hongwei; Ibikunle, Adeola; Goudy, Andrew J.

    2010-01-01

    The hydrogen storage properties of a destabilizedLiBH4/CaH2system ball-milled withTiCl3,TiF3, andTiO2additives have been investigated. It is found that the system withTiCl3additive has a lower dehydrogenation temperature than the ones with other additives. Further study shows that a higher amount ofTiCl3is more effective in reducing the desorption temperature of theLiBH4/CaH2system, since it leads to a lower activation energy of dehydrogenation. The activations energies for mixtures containing 4, 10, and 25?mol% ofTiCl3are 141, 126, and 110?kJ/mol, respectively. However, the benefits of higher amounts ofTiCl3are offset by a larger reduction in hydrogen capacity of the mixtures.

  14. MAS NMR Study of the Metastable Solid Solutions Found in the LiFePO4/FePO4 System

    SciTech Connect (OSTI)

    Cabana, Jordi; Shirakawa, Junichi; Chen, Guoying; Richardson, Thomas; Grey, Clare P.

    2009-10-09

    Li and 3IP NMR experiments were conducted on a series of single- or two-phase samples in the LiFePCvFePCM system with different overall lithium contents, and containing the two end-members and/or two metastable solid solution hases, Lio.6FeP04 or Lio.34FeP04. These experiments were carried out at different temperatures in order to search for vacancy/charge ordering and ion/electron mobility in the metastable phases. Evidence for Li+-Fe2+ interactions was bserved for both Lio.6FeP04 and Lio.34FePC>4. The strength of this interaction leads to the formation of LiFePCvlike clusters in the latter, as shown by the room temperature data. Different motional processes are proposed to exist as the temperature is increased and various scenarios are discussed. While concerted lithium-electron hopping and/or correlations explains the data below 125C, evidence for some uncorrelated motion is found at higher temperatures, together with the onset of phase mixing.

  15. 7Li Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7Li(, '): emission yield 1.0 - 3.4 1 01182012 2011YA02 7Li(, ): elastic scattering differential 1.0 - 4.5 cm 170 07192011 7Li(, p): differential...

  16. Model-Based Design and Integration of Large Li-ion Battery Systems

    SciTech Connect (OSTI)

    Smith, Kandler; Kim, Gi-Heon; Santhanagopalan, Shriram; Shi, Ying; Pesaran, Ahmad; Mukherjee, Partha; Barai, Pallab; Maute, Kurt; Behrou, Reza; Patil, Chinmaya

    2015-11-17

    This presentation introduces physics-based models of batteries and software toolsets, including those developed by the U.S. Department of Energy's (DOE) Computer-Aided Engineering for Electric-Drive Vehicle Batteries Program (CAEBAT). The presentation highlights achievements and gaps in model-based tools for materials-to-systems design, lifetime prediction and control.

  17. Exploring the isopycnal mixing and helium–heat paradoxes in a suite of Earth system models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gnanadesikan, A.; Pradal, M.-A.; Abernathey, R.

    2015-07-27

    This paper uses a suite of Earth system models which simulate the distribution of He isotopes and radiocarbon to examine two paradoxes in Earth science, each of which results from an inconsistency between theoretically motivated global energy balances and direct observations. The helium–heat paradox refers to the fact that helium emissions to the deep ocean are far lower than would be expected given the rate of geothermal heating, since both are thought to be the result of radioactive decay in Earth's interior. The isopycnal mixing paradox comes from the fact that many theoretical parameterizations of the isopycnal mixing coefficient ARedimore » that link it to baroclinic instability project it to be small (of order a few hundred m2 s−1) in the ocean interior away from boundary currents. However, direct observations using tracers and floats (largely in the upper ocean) suggest that values of this coefficient are an order of magnitude higher. Helium isotopes equilibrate rapidly with the atmosphere and thus exhibit large gradients along isopycnals while radiocarbon equilibrates slowly and thus exhibits smaller gradients along isopycnals. Thus it might be thought that resolving the isopycnal mixing paradox in favor of the higher observational estimates of ARedi might also solve the helium paradox, by increasing the transport of mantle helium to the surface more than it would radiocarbon. In this paper we show that this is not the case. In a suite of models with different spatially constant and spatially varying values of ARedi the distribution of radiocarbon and helium isotopes is sensitive to the value of ARedi. However, away from strong helium sources in the southeastern Pacific, the relationship between the two is not sensitive, indicating that large-scale advection is the limiting process for removing helium and radiocarbon from the deep ocean. The helium isotopes, in turn, suggest a higher value of ARedi below the thermocline than is seen in theoretical parameterizations based on baroclinic growth rates. We argue that a key part of resolving the isopycnal mixing paradox is to abandon the idea that ARedi has a direct relationship to local baroclinic instability and to the so-called "thickness" mixing coefficient AGM.« less

  18. 6Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 6Li is subdivided into the following categories: Ground State Properties of 6Li Special States Theoretical Shell Model Cluster Models Complex Reactions Involving 6Li Model Calculations Electromagnetic Transitions Muon and Neutrino Capture and Reactions Reactions Involving Pions, Other Mesons and Baryon States Light-ion and Neutron Induced Reactions Pions Hypernuclei Reactions Involving Antiprotons Astrophysics

  19. Design and experimental testing of the performance of an outdoor LiBr/H{sub 2}O solar thermal absorption cooling system with a cold store

    SciTech Connect (OSTI)

    Agyenim, Francis; Knight, Ian; Rhodes, Michael

    2010-05-15

    A domestic-scale prototype experimental solar cooling system has been developed based on a LiBr/H{sub 2}O absorption system and tested during the 2007 summer and autumn months in Cardiff University, UK. The system consisted of a 12 m{sup 2} vacuum tube solar collector, a 4.5 kW LiBr/H{sub 2}O absorption chiller, a 1000 l cold storage tank and a 6 kW fan coil. The system performance, as well as the performances of the individual components in the system, were evaluated based on the physical measurements of the daily solar radiation, ambient temperature, inlet and outlet fluid temperatures, mass flow rates and electrical consumption by component. The average coefficient of thermal performance (COP) of the system was 0.58, based on the thermal cooling power output per unit of available thermal solar energy from the 12 m{sup 2} Thermomax DF100 vacuum tube collector on a hot sunny day with average peak insolation of 800 W/m{sup 2} (between 11 and 13.30 h) and ambient temperature of 24 C. The system produced an electrical COP of 3.6. Experimental results prove the feasibility of the new concept of cold store at this scale, with chilled water temperatures as low as 7.4 C, demonstrating its potential use in cooling domestic scale buildings. (author)

  20. Development of hybrid 3-D hydrological modeling for the NCAR Community Earth System Model (CESM)

    SciTech Connect (OSTI)

    Zeng, Xubin; Troch, Peter; Pelletier, Jon; Niu, Guo-Yue; Gochis, David

    2015-11-15

    This is the Final Report of our four-year (3-year plus one-year no cost extension) collaborative project between the University of Arizona (UA) and the National Center for Atmospheric Research (NCAR). The overall objective of our project is to develop and evaluate the first hybrid 3-D hydrological model with a horizontal grid spacing of 1 km for the NCAR Community Earth System Model (CESM). We have made substantial progress in model development and evaluation, computational efficiencies and software engineering, and data development and evaluation, as discussed in Sections 2-4. Section 5 presents our success in data dissemination, while Section 6 discusses the scientific impacts of our work. Section 7 discusses education and mentoring success of our project, while Section 8 lists our relevant DOE services. All peer-reviewed papers that acknowledged this project are listed in Section 9. Highlights of our achievements include: • We have finished 20 papers (most published already) on model development and evaluation, computational efficiencies and software engineering, and data development and evaluation • The global datasets developed under this project have been permanently archived and publicly available • Some of our research results have already been implemented in WRF and CLM • Patrick Broxton and Michael Brunke have received their Ph.D. • PI Zeng has served on DOE proposal review panels and DOE lab scientific focus area (SFA) review panels

  1. Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases. Final report

    SciTech Connect (OSTI)

    Prather, Michael J.; Hsu, Juno; Nicolau, Alex; Veidenbaum, Alex; Smith, Philip Cameron; Bergmann, Dan

    2014-11-07

    Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

  2. Department of Energy's Biological and Environmental Research Strategic Data Roadmap for Earth System Science

    SciTech Connect (OSTI)

    Williams, Dean N.; Palanisamy, Giri; Shipman, Galen; Boden, Thomas A.; Voyles, Jimmy W.

    2014-04-25

    Rapid advances in experimental, sensor, and computational technologies and techniques are driving exponential growth in the volume, acquisition rate, variety, and complexity of scientific data. This wealth of scientifically meaningful data has tremendous potential to lead to scientific discovery. However, to achieve scientific breakthroughs, these data must be exploitable—they must be analyzed effectively and efficiently and the results shared and communicated easily within the wider Department of Energy’s (DOE’s) Biological and Environmental Research (BER) Climate and Environmental Sciences Division (CESD) community. The explosion in data complexity and scale makes these tasks exceedingly difficult to achieve, particularly given that an increasing number of disciplines are working across techniques, integrating simulation and experimental or observational results (see Table 5 in Appendix 2). Consequently, we need new approaches to data management, analysis, and visualization that provide research teams with easy-to-use and scalable end-to-end solutions. These solutions must facilitate (and where feasible, automate and capture) every stage in the data lifecycle (shown in Figure 1), from collection to management, annotation, sharing, discovery, analysis, and visualization. In addition, the core functionalities are the same across climate science communities, but they require customization to adapt to specific needs and fit into research and analysis workflows. To this end, the mission of CESD’s Data and Informatics Program is to integrate all existing and future distributed CESD data holdings into a seamless and unified environment for the acceleration of Earth system science.

  3. Incorporating Stakeholder Decision Support Needs into an Integrated Regional Earth System Model

    SciTech Connect (OSTI)

    Rice, Jennie S.; Moss, Richard H.; Runci, Paul J.; Anderson, K. L.; Malone, Elizabeth L.

    2012-03-21

    A new modeling effort exploring the opportunities, constraints, and interactions between mitigation and adaptation at regional scale is utilizing stakeholder engagement in an innovative approach to guide model development and demonstration, including uncertainty characterization, to effectively inform regional decision making. This project, the integrated Regional Earth System Model (iRESM), employs structured stakeholder interactions and literature reviews to identify the most relevant adaptation and mitigation alternatives and decision criteria for each regional application of the framework. The information is used to identify important model capabilities and to provide a focus for numerical experiments. This paper presents the stakeholder research results from the first iRESM pilot region. The pilot region includes the Great Lakes Basin in the Midwest portion of the United States as well as other contiguous states. This geographic area (14 states in total) permits cohesive modeling of hydrologic systems while also providing gradients in climate, demography, land cover/land use, and energy supply and demand. The results from the stakeholder research indicate that iRESM should prioritize addressing adaptation alternatives in the water resources, urban infrastructure, and agriculture sectors, such as water conservation, expanded water quality monitoring, altered reservoir releases, lowered water intakes, urban infrastructure upgrades, increased electric power reserves in urban areas, and land use management/crop selection changes. Regarding mitigation alternatives, the stakeholder research shows a need for iRESM to focus on policies affecting the penetration of renewable energy technologies, and the costs and effectiveness of energy efficiency, bioenergy production, wind energy, and carbon capture and sequestration.

  4. A Generalized Stability Analysis of the AMOC in Earth System Models: Implication for Decadal Variability and Abrupt Climate Change

    SciTech Connect (OSTI)

    Fedorov, Alexey V.; Fedorov, Alexey

    2015-01-14

    The central goal of this research project was to understand the mechanisms of decadal and multi-decadal variability of the Atlantic Meridional Overturning Circulation (AMOC) as related to climate variability and abrupt climate change within a hierarchy of climate models ranging from realistic ocean models to comprehensive Earth system models. Generalized Stability Analysis, a method that quantifies the transient and asymptotic growth of perturbations in the system, is one of the main approaches used throughout this project. The topics we have explored range from physical mechanisms that control AMOC variability to the factors that determine AMOC predictability in the Earth system models, to the stability and variability of the AMOC in past climates.

  5. DOE SciDAC's Earth System Grid Center for Enabling Technologies Final Report

    SciTech Connect (OSTI)

    Williams, Dean N.

    2011-09-27

    The mission of the Earth System Grid Federation (ESGF) is to provide the worldwide climate-research community with access to the data, information, model codes, analysis tools, and intercomparison capabilities required to make sense of enormous climate data sets. Its specific goals are to (1) provide an easy-to-use and secure web-based data access environment for data sets; (2) add value to individual data sets by presenting them in the context of other data sets and tools for comparative analysis; (3) address the specific requirements of participating organizations with respect to bandwidth, access restrictions, and replication; (4) ensure that the data are readily accessible through the analysis and visualization tools used by the climate research community; and (5) transfer infrastructure advances to other domain areas. For the ESGF, the U.S. Department of Energy's (DOE's) Earth System Grid Center for Enabling Technologies (ESG-CET) team has led international development and delivered a production environment for managing and accessing ultra-scale climate data. This production environment includes multiple national and international climate projects (such as the Community Earth System Model and the Coupled Model Intercomparison Project), ocean model data (such as the Parallel Ocean Program), observation data (Atmospheric Radiation Measurement Best Estimate, Carbon Dioxide Information and Analysis Center, Atmospheric Infrared Sounder, etc.), and analysis and visualization tools, all serving a diverse user community. These data holdings and services are distributed across multiple ESG-CET sites (such as ANL, LANL, LBNL/NERSC, LLNL/PCMDI, NCAR, and ORNL) and at unfunded partner sites, such as the Australian National University National Computational Infrastructure, the British Atmospheric Data Centre, the National Oceanic and Atmospheric Administration Geophysical Fluid Dynamics Laboratory, the Max Planck Institute for Meteorology, the German Climate Computing Centre, the National Aeronautics and Space Administration Jet Propulsion Laboratory, and the National Oceanic and Atmospheric Administration. The ESGF software is distinguished from other collaborative knowledge systems in the climate community by its widespread adoption, federation capabilities, and broad developer base. It is the leading source for present climate data holdings, including the most important and largest data sets in the global-climate community, and - assuming its development continues - we expect it to be the leading source for future climate data holdings as well. Recently, ESG-CET extended its services beyond data-file access and delivery to include more detailed information products (scientific graphics, animations, etc.), secure binary data-access services (based upon the OPeNDAP protocol), and server-side analysis. The latter capabilities allow users to request data subsets transformed through commonly used analysis and intercomparison procedures. As we transition from development activities to production and operations, the ESG-CET team is tasked with making data available to all users seeking to understand, process, extract value from, visualize, and/or communicate it to others. This ongoing effort, though daunting in scope and complexity, will greatly magnify the value of numerical climate model outputs and climate observations for future national and international climate-assessment reports. The ESG-CET team also faces substantial technical challenges due to the rapidly increasing scale of climate simulation and observational data, which will grow, for example, from less than 50 terabytes for the last Intergovernmental Panel on Climate Change (IPCC) assessment to multiple Petabytes for the next IPCC assessment. In a world of exponential technological change and rapidly growing sophistication in climate data analysis, an infrastructure such as ESGF must constantly evolve if it is to remain relevant and useful. Regretfully, we submit our final report at the end of project funding. To continue to serve the climate-science community, we are currently seeking additional funding. Such funding would allow us to maintain and enhance ESGF production and operation of this vital endeavor of cataloging, serving, and analyzing ultra-scale climate science data. At this time, the entire ESG-CET team would like to take this opportunity to sincerely thank our funding agencies in the DOE Scientific Discovery through Advanced Computing (SciDAC) program and the Office of Biological and Environmental Research (OBER) - as well as our national and international collaborators, stakeholders, and partners - for allowing us to work with you and serve the community these past several years.

  6. DETECTABILITY OF EARTH-LIKE PLANETS IN CIRCUMSTELLAR HABITABLE ZONES OF BINARY STAR SYSTEMS WITH SUN-LIKE COMPONENTS

    SciTech Connect (OSTI)

    Eggl, Siegfried; Pilat-Lohinger, Elke; Haghighipour, Nader

    2013-02-20

    Given the considerable percentage of stars that are members of binaries or stellar multiples in the solar neighborhood, it is expected that many of these binaries host planets, possibly even habitable ones. The discovery of a terrestrial planet in the {alpha} Centauri system supports this notion. Due to the potentially strong gravitational interaction that an Earth-like planet may experience in such systems, classical approaches to determining habitable zones (HZ), especially in close S-type binary systems, can be rather inaccurate. Recent progress in this field, however, allows us to identify regions around the star permitting permanent habitability. While the discovery of {alpha} Cen Bb has shown that terrestrial planets can be detected in solar-type binary stars using current observational facilities, it remains to be shown whether this is also the case for Earth analogs in HZs. We provide analytical expressions for the maximum and rms values of radial velocity and astrometric signals, as well as transit probabilities of terrestrial planets in such systems, showing that the dynamical interaction of the second star with the planet may indeed facilitate the planets' detection. As an example, we discuss the detectability of additional Earth-like planets in the averaged, extended, and permanent HZs around both stars of the {alpha} Centauri system.

  7. Variable C : N : P stoichiometry of dissolved organic matter cycling in the Community Earth System Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Letscher, R. T.; Moore, J. K.; Teng, Y. -C.; Primeau, F.

    2014-06-16

    Dissolved organic matter (DOM) plays an important role in the ocean's biological carbon pump by providing an advective/mixing pathway for ~ 20% of export production. DOM is known to have a stoichiometry depleted in nitrogen (N) and phosphorus (P) compared to the particulate organic matter pool, a~fact that is often omitted from biogeochemical-ocean general circulation models. However the variable C : N : P stoichiometry of DOM becomes important when quantifying carbon export from the upper ocean and linking the nutrient cycles of N and P with that of carbon. Here we utilize recent advances in DOM observational data coveragemore » and offline tracer-modeling techniques to objectively constrain the variable production and remineralization rates of the DOM C / N / P pools in a simple biogeochemical-ocean model of DOM cycling. The optimized DOM cycling parameters are then incorporated within the Biogeochemical Elemental Cycling (BEC) component of the Community Earth System Model and validated against the compilation of marine DOM observations. The optimized BEC simulation including variable DOM C : N : P cycling was found to better reproduce the observed DOM spatial gradients than simulations that used the canonical Redfield ratio. Global annual average export of dissolved organic C, N, and P below 100 m was found to be 2.28 Pg C yr-1 (143 Tmol C yr-1), 16.4 Tmol N yr-1, and 1 Tmol P yr-1, respectively with an average export C : N : P stoichiometry of 225 : 19 : 1 for the semilabile (degradable) DOM pool. DOC export contributed ~ 25% of the combined organic C export to depths greater than 100 m.« less

  8. Variable C : N : P stoichiometry of dissolved organic matter cycling in the Community Earth System Model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Letscher, R. T.; Moore, J. K.; Teng, Y. -C.; Primeau, F.

    2015-01-12

    Dissolved organic matter (DOM) plays an important role in the ocean's biological carbon pump by providing an advective/mixing pathway for ~ 20% of export production. DOM is known to have a stoichiometry depleted in nitrogen (N) and phosphorus (P) compared to the particulate organic matter pool, a fact that is often omitted from biogeochemical ocean general circulation models. However the variable C : N : P stoichiometry of DOM becomes important when quantifying carbon export from the upper ocean and linking the nutrient cycles of N and P with that of carbon. Here we utilize recent advances in DOM observationalmore » data coverage and offline tracer-modeling techniques to objectively constrain the variable production and remineralization rates of the DOM C : N : P pools in a simple biogeochemical-ocean model of DOM cycling. The optimized DOM cycling parameters are then incorporated within the Biogeochemical Elemental Cycling (BEC) component of the Community Earth System Model (CESM) and validated against the compilation of marine DOM observations. The optimized BEC simulation including variable DOM C : N : P cycling was found to better reproduce the observed DOM spatial gradients than simulations that used the canonical Redfield ratio. Global annual average export of dissolved organic C, N, and P below 100 m was found to be 2.28 Pg C yr-1 (143 Tmol C yr-1, 16.4 Tmol N yr-1, and 1 Tmol P yr-1, respectively, with an average export C : N : P stoichiometry of 225 : 19 : 1 for the semilabile (degradable) DOM pool. Dissolved organic carbon (DOC) export contributed ~ 25% of the combined organic C export to depths greater than 100 m.« less

  9. On linking an Earth system model to the equilibrium carbon representation of an economically optimizing land use model

    SciTech Connect (OSTI)

    Bond-Lamberty, Benjamin; Calvin, Katherine V.; Jones, Andrew D.; Mao, Jiafu; Patel, Pralit L.; Shi, Xiaoying; Thomson, Allison M.; Thornton, Peter E.; Zhou, Yuyu

    2014-01-01

    Human activities are significantly altering biogeochemical cycles at the global scale, posing a significant problem for earth system models (ESMs), which may incorporate static land-use change inputs but do not actively simulate policy or economic forces. One option to address this problem is a to couple an ESM with an economically oriented integrated assessment model. Here we have implemented and tested a coupling mechanism between the carbon cycles of an ESM (CLM) and an integrated assessment (GCAM) model, examining the best proxy variables to share between the models, and quantifying our ability to distinguish climate- and land-use-driven flux changes. CLMs net primary production and heterotrophic respiration outputs were found to be the most robust proxy variables by which to manipulate GCAMs assumptions of long-term ecosystem steady state carbon, with short-term forest production strongly correlated with long-term biomass changes in climate-change model runs. By leveraging the fact that carbon-cycle effects of anthropogenic land-use change are short-term and spatially limited relative to widely distributed climate effects, we were able to distinguish these effects successfully in the model coupling, passing only the latter to GCAM. By allowing climate effects from a full earth system model to dynamically modulate the economic and policy decisions of an integrated assessment model, this work provides a foundation for linking these models in a robust and flexible framework capable of examining two-way interactions between human and earth system processes.

  10. Causes and Implications of Persistent Atmospheric Carbon Dioxide Biases in Earth System Models

    SciTech Connect (OSTI)

    Hoffman, Forrest M [ORNL] [ORNL; Randerson, James T. [University of California, Irvine] [University of California, Irvine; Arora, Vivek K. [Canadian Centre for Climate Modelling and Analysis, Meteorological Service of Canada] [Canadian Centre for Climate Modelling and Analysis, Meteorological Service of Canada; Bao, Qing [State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics] [State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics; Cadule, Patricia [Institut Pierre Simon Laplace, Laboratoire des Sciences du Climat et de l'Environment] [Institut Pierre Simon Laplace, Laboratoire des Sciences du Climat et de l'Environment; Ji, Duoying [State Key Laboratory of Earth Surface Processes and Resource Ecology, Beijing] [State Key Laboratory of Earth Surface Processes and Resource Ecology, Beijing; Jones, Chris D. [Hadley Centre, U.K. Met Office] [Hadley Centre, U.K. Met Office; Kawamiya, Michio [Japan Agency for Marine-Earth Science and Technology (JAMSTEC)] [Japan Agency for Marine-Earth Science and Technology (JAMSTEC); Khatiwala, Samar [Lamont-Doherty Earth Observatory, Columbia University, Palisades, NY] [Lamont-Doherty Earth Observatory, Columbia University, Palisades, NY; Lindsay, Keith [National Center for Atmospheric Research (NCAR)] [National Center for Atmospheric Research (NCAR); Obata, Atsushi [Meteorological Research Institute, Japan] [Meteorological Research Institute, Japan; Shevliakova, Elena [Princeton University] [Princeton University; Six, Katharina D. [Max Planck Institute for Meteorology, Hamburg, Germany] [Max Planck Institute for Meteorology, Hamburg, Germany; Tjiputra, Jerry F. [Uni Climate, Uni Research] [Uni Climate, Uni Research; Volodin, Evgeny M. [Institute of Numerical Mathematics, Russian Academy of Science, Moscow] [Institute of Numerical Mathematics, Russian Academy of Science, Moscow; Wu, Tongwen [China Meteorological Administration (CMA), Beijing] [China Meteorological Administration (CMA), Beijing

    2014-01-01

    The strength of feedbacks between a changing climate and future CO2 concentrations are uncertain and difficult to predict using Earth System Models (ESMs). We analyzed emission-driven simulations--in which atmospheric CO2 levels were computed prognostically--for historical (1850-2005) and future periods (RCP 8.5 for 2006-2100) produced by 15 ESMs for the Fifth Phase of the Coupled Model Intercomparison Project (CMIP5). Comparison of ESM prognostic atmospheric CO2 over the historical period with observations indicated that ESMs, on average, had a small positive bias in predictions of contemporary atmospheric CO2. Weak ocean carbon uptake in many ESMs contributed to this bias, based on comparisons with observations of ocean and atmospheric anthropogenic carbon inventories. We found a significant linear relationship between contemporary atmospheric CO2 biases and future CO2 levels for the multi-model ensemble. We used this relationship to create a contemporary CO2 tuned model (CCTM) estimate of the atmospheric CO2 trajectory for the 21st century. The CCTM yielded CO2 estimates of 600 {plus minus} 14 ppm at 2060 and 947 {plus minus} 35 ppm at 2100, which were 21 ppm and 32 ppm below the multi-model mean during these two time periods. Using this emergent constraint approach, the likely ranges of future atmospheric CO2, CO2-induced radiative forcing, and CO2-induced temperature increases for the RCP 8.5 scenario were considerably narrowed compared to estimates from the full ESM ensemble. Our analysis provided evidence that much of the model-to-model variation in projected CO2 during the 21st century was tied to biases that existed during the observational era, and that model differences in the representation of concentration-carbon feedbacks and other slowly changing carbon cycle processes appear to be the primary driver of this variability. By improving models to more closely match the long-term time series of CO2 from Mauna Loa, our analysis suggests uncertainties in future climate projections can be reduced.

  11. 7Li Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p, X) (Current as of 12/16/2015) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 1997GO13 7Li(pol. p, γ): total σ, S-factor for capture to third-excited state 0 - 80 keV X4 06/12/2014 1994CH23 7Li(pol. p, γ): deduced S-factor ≤ 80 keV X4 06/12/2014 1999SP09 7Li(p, α): deduced S-factor < 0.4 X4 06/12/2014 1974BU16 7Li(p, n): σ < 3.8 X4 03/14/2012 2011PI04 7Li(p, α): analyzed excitation functions Ecm = 0 - 7 X4 06/12/2014 2001LA35 7Li(p, α): deduced S(E)-factor 10 -

  12. Livermore Lab's giant laser system will bring star power to Earth

    SciTech Connect (OSTI)

    Moses, E

    2010-04-08

    In the 50 years since the laser was first demonstrated in Malibu, California, on May 16, 1960, Lawrence Livermore National Laboratory (LLNL) has been a world leader in laser technology and the home for many of the world's most advanced laser systems. That tradition continues today at LLNL's National Ignition Facility (NIF), the world's most energetic laser system. NIF's completion in March 2009 not only marked the dawn of a new era of scientific research - it could also prove to be the next big step in the quest for a sustainable, carbon-free energy source for the world. NIF consists of 192 laser beams that will focus up to 1.8 million joules of energy on a bb-sized target filled with isotopes of hydrogen - forcing the hydrogen nuclei to collide and fuse in a controlled thermonuclear reaction similar to what happens in the sun and the stars. More energy will be produced by this 'ignition' reaction than the amount of laser energy required to start it. This is the long-sought goal of 'energy gain' that has eluded fusion researchers for more than half a century. Success will be a scientific breakthrough - the first demonstration of fusion ignition in a laboratory setting, duplicating on Earth the processes that power the stars. This impending success could not be achieved without the valuable partnerships forged with other national and international laboratories, private industry and universities. One of the most crucial has been between LLNL and the community in which it resides. Over 155 businesses in the local Tri-Valley area have contributed to the NIF, from industrial technology and engineering firms to tool manufacturing, electrical, storage and supply companies. More than $2.3B has been spent locally between contracts with nearby merchants and employee salaries. The Tri-Valley community has enabled the Laboratory to complete a complex and far-reaching project that will have national and global impact in the future. The first experiments were conducted on NIF last summer and fall, successfully delivering a world-record level of ultraviolet laser energy - more than 1.2 million joules - to a target. The experiments also demonstrated the target drive and target capsule conditions required to achieve fusion ignition. When ignition experiments begin later this year, NIF's lasers will create temperatures and pressures in the hydrogen target that exist only in the cores of stars and giant planets and inside thermonuclear weapons. As a key component of the National Nuclear Security Administration's Stockpile Stewardship Program, NIF will offer the means for sustaining a safe, secure and reliable U.S. nuclear deterrent without nuclear testing. NIF is uniquely capable of providing the experimental data needed to develop and validate computer models that will enable scientists to assess the continuing viability of the nation's nuclear stockpile. Along with this vital national security mission, success at NIF also offers the possibility of groundbreaking scientific discoveries in a wide variety of disciplines ranging from hydrodynamics to astrophysics. As a unique facility in the world that can create the conditions that exist in supernovas and in the cores of giant planets, NIF will help unlock the secrets of the cosmos and inspire the next generation of scientists. It is NIF's third mission, energy security that has been generating the most excitement in the news media and the international scientific community. The reasons are obvious: global energy demand, driven by population growth and the aspirations of the developing world, already is straining the planet's existing energy resources. Global need for electricity is expected to double from its current level of about two trillion watts (TW) to four TW by 2030 and could reach eight to ten TW by the end of the century. As many as 10,000 new billion-watt power plants will have to be built to keep up with this demand. Meeting this pressing need will require a sustainable carbon-free energy technology that can supply base load electricity to the world. Successful ignition experim

  13. 3rd Annual Earth System Grid Federation and 3rd Annual Earth System Grid Federation and Ultrascale Visualization Climate Data Analysis Tools Face-to-Face Meeting Report December 2013

    SciTech Connect (OSTI)

    Williams, Dean N.

    2014-02-21

    The climate and weather data science community gathered December 3–5, 2013, at Lawrence Livermore National Laboratory, in Livermore, California, for the third annual Earth System Grid Federation (ESGF) and Ultra-scale Visualization Climate Data Analysis Tools (UV-CDAT) Face-to-Face (F2F) Meeting, which was hosted by the Department of Energy, National Aeronautics and Space Administration, National Oceanic and Atmospheric Administration, the European Infrastructure for the European Network of Earth System Modelling, and the Australian Department of Education. Both ESGF and UV-CDAT are global collaborations designed to develop a new generation of open-source software infrastructure that provides distributed access and analysis to observed and simulated data from the climate and weather communities. The tools and infrastructure developed under these international multi-agency collaborations are critical to understanding extreme weather conditions and long-term climate change, while the F2F meetings help to build a stronger climate and weather data science community and stronger federated software infrastructure. The 2013 F2F meeting determined requirements for existing and impending national and international community projects; enhancements needed for data distribution, analysis, and visualization infrastructure; and standards and resources needed for better collaborations.

  14. 5Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Table for 5Li is subdivided into the folowing categories: Ground State Properties Cluster Model Shell Model Special States Model Calculations Model Discussions Complex...

  15. Precise rare earth analysis of geological materials

    SciTech Connect (OSTI)

    Laul, J.C.; Wogman, N.A.

    1982-01-01

    Rare earth element (REE) concentrations are very informative in revealing chemical fractionation processs in geological systems. The REE's (La-Lu) behavior is characteristic of various primary and secondary minerals which comprise a rock. The REE's contents and their patterns provide a strong fingerprint in distinguishing among various rock types and in understanding the partial melting and/or fractional crystallization of the source region. The REE contents in geological materials are usually at trace levels. To measure all the REE at such levels, radiochemical neutron activation analysis (RNAA) has been used with a REE group separation scheme. To maximize detection sensitivites for individual REE, selective ..gamma..-ray/x-ray measurements have been made using normal Ge(Li) and low-energy photon detectors (LEPD), and Ge(Li)-NaI(Tl) coincidence-noncoincidence spectrometer systems. Using these detection methods an individual REE can be measured at or below the ppB levels; chemical yields of the REE are determined by reactivation.

  16. Making Li-air batteries rechargeable: material challenges

    SciTech Connect (OSTI)

    Shao, Yuyan; Ding, Fei; Xiao, Jie; Zhang, Jian; Xu, Wu; Park, Seh Kyu; Zhang, Jiguang; Wang, Yong; Liu, Jun

    2013-02-25

    A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.

  17. Feasibility of a super high-energy-density battery of the Li/Br/F sub 3 electrochemical system. Final report, 15 August 1989-14 May 1990

    SciTech Connect (OSTI)

    Frysz, C.A.; Pyszczek, M.F.; Ebel, S.J.

    1990-08-16

    Feasibility studies on the practical aspects of developing a lithium/bromine trifluoride battery have been studied. Efforts directed toward identifying materials for porous electrode separators, glasses for insulated electrical feed-throughs, and metals for lid, case and current collector fabrication via electrochemical testing techniques have resulted in a list of materials suitable for these applications. Prototype cells utilizing a spirally wound electrode configuration have been constructed and discharged. The use of lithium salts as an electrolyte additive has been explored, and has shown a positive effect on discharge performance. Through the use of currently available technology, however, the lithium/bromine trifluoride couple has not delivered energy density comparable to other high energy density lithium systems. This investigation has revealed that practical Li/BrF3 cell development will require further extensive fundamental electrochemical research.

  18. Thermal Properties of LiCl-KCl Molten Salt for Nuclear Waste Separation

    SciTech Connect (OSTI)

    Sridharan, Kumar; Allen, Todd; Anderson, Mark; Simpson, Mike

    2012-11-30

    This project addresses both practical and fundamental scientific issues of direct relevance to operational challenges of the molten LiCl-KCl salt pyrochemical process, while providing avenues for improvements in the process. In order to understand the effects of the continually changing composition of the molten salt bath during the process, the project team will systematically vary the concentrations of rare earth surrogate elements, lanthanum, cerium, praseodymium, and neodymium, which will be added to the molten LiCl-KCl salt. They will also perform a limited number of focused experiments by the dissolution of depleted uranium. All experiments will be performed at 500 deg C. The project consists of the following tasks. Researchers will measure density of the molten salts using an instrument specifically designed for this purpose, and will determine the melting points with a differential scanning calorimeter. Knowledge of these properties is essential for salt mass accounting and taking the necessary steps to prevent melt freezing. The team will use cyclic voltammetry studies to determine redox potentials of the rare earth cations, as well as their diffusion coefficients and activities in the molten LiCl-KCl salt. In addition, the team will perform anodic stripping voltammetry to determine the concentration of the rare earth elements and their solubilities, and to develop the scientific basis for an on-line diagnostic system for in situ monitoring of the cation species concentration (rare earths in this case). Solubility and activity of the cation species are critically important for the prediction of the salt's useful lifetime and disposal.

  19. Behavior of Rare Earth Element In Geothermal Systems; A New Exploration/Exploitation Tool

    SciTech Connect (OSTI)

    Scott A. Wood

    2002-01-28

    The goal of this four-year project was to provide a database by which to judge the utility of the rare earth elements (REE) in the exploration for and exploitation of geothermal fields in the United States. Geothermal fluids from hot springs and wells have been sampled from a number of locations, including: (1) the North Island of New Zealand (1 set of samples); (2) the Cascades of Oregon; (3) the Harney, Alvord Desert and Owyhee geothermal areas of Oregon; (4) the Dixie Valley and Beowawe fields in Nevada; (5) Palinpion, the Philippines: (6) the Salton Sea and Heber geothermal fields of southern California; and (7) the Dieng field in Central Java, Indonesia. We have analyzed the samples from all fields for REE except the last two.

  20. LiDAR (Lewicki & Oldenburg, 2005) | Open Energy Information

    Open Energy Info (EERE)

    Technique LiDAR Activity Date Usefulness useful DOE-funding Unknown References Jennifer L. Lewicki, Curtis M. Oldenburg (2005) Strategies To Detect Hidden Geothermal Systems...

  1. LiDAR (Lewicki & Oldenburg, 2004) | Open Energy Information

    Open Energy Info (EERE)

    Technique LiDAR Activity Date Usefulness useful DOE-funding Unknown References Jennifer L. Lewicki, Curtis M. Oldenburg (2004) Strategies For Detecting Hidden Geothermal Systems...

  2. 7Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 7Li is subdivided into the following categories: Reviews Ground State Properties Shell Model Cluster Model Other Theoretical Work Model Calculations Photodisintegration Polarization Fission and Fusion Elastic and Inelastic Scattering Projectile Fragmentation and Multifragmentation Astrophysical Hyperfine Structure b-decay Muons Hypernuclei and Mesons Hypernuclei and Baryons Pion, Kaon and Eta-Mesons Other Work Applications

  3. 8Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Tables The General Table for 8Li is subdivided into the following categories: Reviews Ground State Properties Shell Model Cluster Model Other Models Photodissociation Fusion and Fission Elastic and Inelastic Scattering Fragmentation Reactions Astrophysical b Decay Hypernuclei Pions, Kaons and h-mesons

  4. 9Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 9Li is subdivided into the following categories: Shell Model Cluster Model Theoretical Ground State Properties Special States Other Model Calculations Complex Reactions Beta-Decay Pions Muons Photodisintegration Elastic and Inelastic Scattering Electromagnetic Transitions Astrophysical

  5. Earth System Grid Center for Enabling Technologies (ESG-CET): A Data Infrastructure for Data-Intensive Climate Research

    SciTech Connect (OSTI)

    Williams, Dean N.

    2011-06-03

    For the Earth System Grid Federation (ESGF), the ESG-CET team has led international development and delivered a production environment for managing and accessing ultrascale climate data. This production environment includes multiple national and international climate projects (e.g., Couple Model Intercomparison Project, Community Earth System Model), ocean model data (such as the Parallel Ocean Program), observation data (Carbon Dioxide Information and Analysis Center, Atmospheric Infrared Sounder, and so forth), and analysis and visualization tools, all of which serve a diverse community of users. These data holdings and services are distributed across multiple ESG-CET sites (such as LANL, LBNL, LLNL, NCAR, and ORNL) as well as at unfunded partners sites such as the Australian National University National Computational Infrastructure, the British Atmospheric Data Centre, the National Oceanic and Atmospheric Administration Geophysical Fluid Dynamics Laboratory, the Max Planck Institute for Meteorology, the German Climate Computing Centre, and the National Aeronautics and Space Administration Jet Propulsion Laboratory. More recently, ESG-CET has been extending services beyond data-file access and delivery to develop more detailed information products (scientific graphics, animations, etc.), secure binary data-access services (based upon the OPeNDAP protocol), and server-side analysis capabilities. These will allow users to request data subsets transformed through commonly used analysis and intercomparison procedures. As we transition from development activities to production and operations, the ESG-CET team is tasked with making data available to all users seeking to understand, process, extract value from, visualize, and/or communicate it to others. This ongoing effort, though daunting in scope and complexity, will greatly magnify the value of numerical climate model outputs and climate observations for future national and international climate-assessment reports. Continued ESGF progress will result in a production ultrascale data system for empowering scientists who attempt new and exciting data exchanges that could ultimately lead to breakthrough climate-science discoveries.

  6. Luminescent nanocrystals in the rare-earth niobatezirconia system formed via hydrothermal method

    SciTech Connect (OSTI)

    Hirano, Masanori Dozono, Hayato

    2013-08-15

    Luminescent nanocrystals based on the rare-earth niobates (Ln{sub 3}NbO{sub 7}, Ln=Y, Eu) and zirconia (ZrO{sub 2}) that were composed of 50 mol% Ln{sub 3}NbO{sub 7} and 50 mol% ZrO{sub 2}, were hydrothermally formed as cubic phase under weakly basic conditions at 240 C. The lattice parameter of the as-prepared nanoparticles corresponding to the composition of Y{sub 3?x}Eu{sub x}NbO{sub 7}4ZrO{sub 2} that was estimated as a single phase of cubic gradually increased as the content of europium x increased. The existence of small absorbance peaks at 395 and 466 nm corresponding to the Eu{sup 3+7}F{sub 0}?{sup 5}L{sub 6}, and {sup 7}F{sub 0}?{sup 5}D{sub 2} excitation transition, respectively, was clearly observed in the diffuse reflectance spectra of the as-prepared samples containing europium. The optical band gap of the as-prepared samples was in the range from 3.5 to 3.7 eV. The photoluminescence spectra of the as-prepared nanocrystals containing europium showed orange and red luminescences with main peaks at 590 and 610 nm, corresponding to {sup 5}D{sub 0}?{sup 7}F{sub 1} and {sup 5}D{sub 0}?{sup 7}F{sub 2} transitions of Eu{sup 3+}, respectively, under excitation at 395 nm Xe lamp. The emission intensity corresponding to {sup 5}D{sub 0}?{sup 7}F{sub 2} transition increased as heat-treatment temperature rose from 800 to 1200 C. - Graphical abstract: This graphical abstract shows the excitation and emission spectra and a transmission electron microscopy image of nanocrystals (with composition based on the rare-earth niobates (Ln{sub 3}NbO{sub 7}, Ln=Y, Eu) and zirconia (ZrO{sub 2}) that were composed of 50 mol% Ln{sub 3}NbO{sub 7} and 50 mol% ZrO{sub 2}) formed via hydrothermal route. Display Omitted - Highlights: Nanocrystals composed of 50 mol% Y{sub 3?x}Eu{sub x}NbO{sub 7} and 50 mol% ZrO{sub 2} was directly formed. The nanocrystals were hydrothermally formed under weakly basic conditions at 240 C. The Y{sub 3}NbO{sub 7} showed an UV-blue and broad-band emission under excitation at 240 nm. The emission is originated from the niobate octahedral group [NbO{sub 6}]{sup 7?}. The nanocrystals showed orange and red luminescences ({sup 5}D{sub 0}?{sup 7}F{sub 1} and {sup 5}D{sub 0}?{sup 7}F{sub 2} , Eu{sup 3+})

  7. System for beaming power from earth to a high altitude platform

    DOE Patents [OSTI]

    Friedman, Herbert W.; Porter, Terry J.

    2002-01-01

    Power is transmitted to a high altitude platform by an array of diode pumped solid state lasers each operated at a single range of laser wavelengths outside of infrared and without using adaptive optics. Each laser produces a beam with a desired arrival spot size. An aircraft avoidance system uses a radar system for automatic control of the shutters of the lasers.

  8. Substrate and environmental controls on microbial assimilation of soil organic carbon: a framework for Earth System Models

    SciTech Connect (OSTI)

    Xu, Xiaofeng; Schimel, Joshua; Thornton, Peter E; Song, Xia; Yuan, Fengming; Goswami, Santonu

    2014-01-01

    Microbial assimilation of soil organic carbon is one of the fundamental processes of global carbon cycling and it determines the magnitude of microbial biomass in soils. Mechanistic understanding of microbial assimilation of soil organic carbon and its controls is important for to improve Earth system models ability to simulate carbon-climate feedbacks. Although microbial assimilation of soil organic carbon is broadly considered to be an important parameter, it really comprises two separate physiological processes: one-time assimilation efficiency and time-dependent microbial maintenance energy. Representing of these two mechanisms is crucial to more accurately simulate carbon cycling in soils. In this study, a simple modeling framework was developed to evaluate the substrate and environmental controls on microbial assimilation of soil organic carbon using a new term: microbial annual active period (the length of microbes remaining active in one year). Substrate quality has a positive effect on microbial assimilation of soil organic carbon: higher substrate quality (lower C:N ratio) leads to higher ratio of microbial carbon to soil organic carbon and vice versa. Increases in microbial annual active period from zero stimulate microbial assimilation of soil organic carbon; however, when microbial annual active period is longer than an optimal threshold, increasing this period decreases microbial biomass. The simulated ratios of soil microbial biomass to soil organic carbon are reasonably consistent with a recently compiled global dataset at the biome-level. The modeling framework of microbial assimilation of soil organic carbon and its controls developed in this study offers an applicable ways to incorporate microbial contributions to the carbon cycling into Earth system models for simulating carbon-climate feedbacks and to explain global patterns of microbial biomass.

  9. 6Li Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p, X) (Current as of 03/01/2016) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 2004TU02 6Li(p, α): coincidence yields, deduced S-factors low 1, S-factors from direct data, S-factors from indirect data 03/20/2012 2004TU06 6Li(p, α): σ, coincidence yields, deduced S-factors low σ, coincidence yields, S-factors from direct data, S-factors from indirect data 03/20/2012 1966GE11 6Li(p, α): S-factor Ec.m. = 0.01 - 1.00 X4 12/15/2015 2005CR05 6Li(p, α): S-factor 20 - 100 keV X4

  10. 6Li Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    α, X) (Current as of 02/01/2016) NSR Reaction Eα (MeV) Cross Section File X4 Dataset Date Added 1985NE05 6Li(α, γ): γ thick target yield resonance X4 02/15/2012 1966FO05 6Li(α, γ): σ 0.9 - 3.0 2 < Eγ < 4 MeV, 4 < Eγ < 7 MeV, thick target capture γ-ray yield, capture γ-ray yield of 2.43 MeV resonance 02/29/2012 1989BA24 6Li(α, γ): σ 1.085, 1.175 X4 02/15/2012 1979SP01 6Li(α, γ): thick target yield curve for 718 keV γ-rays 1140 - 1250 keV 1175 keV resonance 07/19/2011

  11. Vehicle Technologies Office Merit Review 2014: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis Energy, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li...

  12. Vehicle Technologies Office Merit Review 2015: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li-ion cells for...

  13. 10Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 10Li is subdivided into the following categories: Reviews Theoretical Ground State Properties Shell Model Cluster Model Other Models Special States Astrophysical Electromagnetic Transitions Hypernuclei Photodisintegration Light-Ion and Neutron Induced Reactions These General Tables correspond to the 2003 preliminary evaluation of ``Energy Levels of Light Nuclei, A = 10''. The prepublication version of A = 10 is available on this website in PDF format: A =

  14. Mars, the Moon, and the Ends of the Earth: Autonomy for Small Reactor Power Systems

    SciTech Connect (OSTI)

    Wood, Richard Thomas [ORNL

    2008-01-01

    In recent years, the National Aeronautics and Space Administration (NASA) has been considering deep space missions that utilize a small-reactor power system (SRPS) to provide energy for propulsion and spacecraft power. Additionally, application of SRPS modules as a planetary power source is being investigated to enable a continuous human presence for nonpolar lunar sites and on Mars. A SRPS can supply high-sustained power for space and surface applications that is both reliable and mass efficient. The use of small nuclear reactors for deep space or planetary missions presents some unique challenges regarding the operations and control of the power system. Current-generation terrestrial nuclear reactors employ varying degrees of human control and decision-making for operations and benefit from periodic human interaction for maintenance. In contrast, the control system of a SRPS employed for deep space missions must be able to accommodate unattended operations due to communications delays and periods of planetary occlusion while adapting to evolving or degraded conditions with no opportunity for repair or refurbishment. While surface power systems for planetary outposts face less extreme delays and periods of isolation and may benefit from limited maintenance capabilities, considerations such as human safety, resource limitations and usage priorities, and economics favor minimizing direct, continuous human interaction with the SRPS for online, dedicated power system management. Thus, a SRPS control system for space or planetary missions must provide capabilities for operational autonomy. For terrestrial reactors, large-scale power plants remain the preferred near-term option for nuclear power generation. However, the desire to reduce reliance on carbon-emitting power sources in developing countries may lead to increased consideration of SRPS modules for local power generation in remote regions that are characterized by emerging, less established infrastructures. Additionally, many Generation IV (Gen IV) reactor concepts have goals for optimizing investment recovery and economic efficiency that promote significant reductions in plant operations and maintenance staff over current-generation nuclear power plants. To accomplish these Gen IV goals and also address the SRPS remote-siting challenges, higher levels of automation, fault tolerance, and advanced diagnostic capabilities are needed to provide nearly autonomous operations with anticipatory maintenance. Essentially, the SRPS control system for several anticipated terrestrial applications can benefit from the kind of operational autonomy that is necessary for deep space and planetary SRPS-enabled missions. Investigation of the state of the technology for autonomous control confirmed that control systems with varying levels of autonomy have been employed in robotic, transportation, spacecraft, and manufacturing applications. As an example, NASA has pursued autonomy for spacecraft and surface exploration vehicles (e.g., rovers) to reduce mission costs, increase efficiency for communications between ground control and the vehicle, and enable independent operation of the vehicle during times of communications blackout. However, autonomous control has not been implemented for an operating terrestrial nuclear power plant nor has there been any experience beyond automating simple control loops for space reactors. Current automated control technologies for nuclear power plants are reasonably mature, and fully automated control of normal SRPS operations is clearly feasible. However, the space-based and remote terrestrial applications of SRPS modules require autonomous capabilities that can accommodate nonoptimum operations when degradation, failure, and other off-normal events challenge the performance of the reactor while immediate human intervention is not possible. The independent action provided by autonomous control, which is distinct from the more limited self action of automated control, can satisfy these conditions. Key characteristics that distinguish autonomous control i

  15. Earth's Magnetosphere

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mysterious electron stash found hidden among Van Allen belts March 1, 2013 Instruments detect never-before-seen phenomenon in Earth's Magnetosphere LOS ALAMOS, N.M., March 1, 2013-U.S. researchers, including a trio from Los Alamos National Laboratory, have witnessed the mysterious appearance of a relatively long-lived zone of high-energy electrons stored between Earth's Van Allen radiation belts. The surprising findings, discovered by NASA's Van Allen Probes (formerly known as the Radiation Belt

  16. A metallurgical approach toward alloying in rare earth permanen magnet systems

    SciTech Connect (OSTI)

    Branagan, D. J.

    1995-02-23

    The approach was developed to allow microstructural enhancement and control during solidification and processing. Compound additions of Group IVA, VA, or VIA transition metals (TM) and carbon were added to Nd{sub 2}Fe{sub 14}B (2-14-1). Transition metal carbides formed in IVA (TiC, ZrC, HfC) and Group VA (VC, NbC, TaC) systems, but not in the VIA system. The alloying ability of each TM carbide was graded using phase stability, liquid and equilibrium solid solubility, and high temperature carbide stability. Ti with C additions was chosen as the best system. The practically zero equilibrium solid solubility means that the Ti and C additions will ultimately form TiC after heat treatment which allows the development of a composite microstructure consisting of the 2-14-1 phase and TiC. Thus, the excellent intrinsic magnetic properties of the 2-14-1 phase remain unaltered and the extrinsic properties relating to the microstructure are enhanced due to the TiC stabilized microstructure which is much more resistant to grain growth. When Ti + C are dissolved in the liquid melt or solid phases, such as the glass or 2-14-1 phase, the intrinsic properties are changed; favorable changes include increased glass forming ability, reduced optimum cooling rate, increased optimum energy product, and enhanced nucleation kinetics of crystallization.

  17. SciDAC's Earth System Grid Center for Enabling Technologies Semiannual Progress Report October 1, 2010 through March 31, 2011

    SciTech Connect (OSTI)

    Williams, Dean N.

    2011-04-02

    This report summarizes work carried out by the Earth System Grid Center for Enabling Technologies (ESG-CET) from October 1, 2010 through March 31, 2011. It discusses ESG-CET highlights for the reporting period, overall progress, period goals, and collaborations, and lists papers and presentations. To learn more about our project and to find previous reports, please visit the ESG-CET Web sites: http://esg-pcmdi.llnl.gov/ and/or https://wiki.ucar.edu/display/esgcet/Home. This report will be forwarded to managers in the Department of Energy (DOE) Scientific Discovery through Advanced Computing (SciDAC) program and the Office of Biological and Environmental Research (OBER), as well as national and international collaborators and stakeholders (e.g., those involved in the Coupled Model Intercomparison Project, phase 5 (CMIP5) for the Intergovernmental Panel on Climate Change (IPCC) 5th Assessment Report (AR5); the Community Earth System Model (CESM); the Climate Science Computational End Station (CCES); SciDAC II: A Scalable and Extensible Earth System Model for Climate Change Science; the North American Regional Climate Change Assessment Program (NARCCAP); the Atmospheric Radiation Measurement (ARM) program; the National Aeronautics and Space Administration (NASA), the National Oceanic and Atmospheric Administration (NOAA)), and also to researchers working on a variety of other climate model and observation evaluation activities. The ESG-CET executive committee consists of Dean N. Williams, Lawrence Livermore National Laboratory (LLNL); Ian Foster, Argonne National Laboratory (ANL); and Don Middleton, National Center for Atmospheric Research (NCAR). The ESG-CET team is a group of researchers and scientists with diverse domain knowledge, whose home institutions include eight laboratories and two universities: ANL, Los Alamos National Laboratory (LANL), Lawrence Berkeley National Laboratory (LBNL), LLNL, NASA/Jet Propulsion Laboratory (JPL), NCAR, Oak Ridge National Laboratory (ORNL), Pacific Marine Environmental Laboratory (PMEL)/NOAA, Rensselaer Polytechnic Institute (RPI), and University of Southern California, Information Sciences Institute (USC/ISI). All ESG-CET work is accomplished under DOE open-source guidelines and in close collaboration with the project's stakeholders, domain researchers, and scientists. Through the ESG project, the ESG-CET team has developed and delivered a production environment for climate data from multiple climate model sources (e.g., CMIP (IPCC), CESM, ocean model data (e.g., Parallel Ocean Program), observation data (e.g., Atmospheric Infrared Sounder, Microwave Limb Sounder), and analysis and visualization tools) that serves a worldwide climate research community. Data holdings are distributed across multiple sites including LANL, LBNL, LLNL, NCAR, and ORNL as well as unfunded partners sites such as the Australian National University (ANU) National Computational Infrastructure (NCI), the British Atmospheric Data Center (BADC), the Geophysical Fluid Dynamics Laboratory/NOAA, the Max Planck Institute for Meteorology (MPI-M), the German Climate Computing Centre (DKRZ), and NASA/JPL. As we transition from development activities to production and operations, the ESG-CET team is tasked with making data available to all users who want to understand it, process it, extract value from it, visualize it, and/or communicate it to others. This ongoing effort is extremely large and complex, but it will be incredibly valuable for building 'science gateways' to critical climate resources (such as CESM, CMIP5, ARM, NARCCAP, Atmospheric Infrared Sounder (AIRS), etc.) for processing the next IPCC assessment report. Continued ESG progress will result in a production-scale system that will empower scientists to attempt new and exciting data exchanges, which could ultimately lead to breakthrough climate science discoveries.

  18. Feasibility of a superhigh energy-density battery of the Li/BrF sub 3 electrochemical system. Technical report

    SciTech Connect (OSTI)

    Pyszczek, M.F.; Ebel, S.J.; Frysz, C.A.

    1989-01-01

    To date, design and construction of a material-handling and measurement system along with the apparatus required for waste material disposal has been completed. Preliminary corrosion screening of potential case materials is currently underway. A review of the literature, has led us to the use of Monel (trademark) 400 as the material of construction for the handling and measurement system. The inherent stability of this material with bromine trifluoride in its liquid state is crucial to ensure that contamination does not occur during storage and handling. For applications which require a flexible or transparent material, items fabricated from perfluoroalkyoxy polymers (Teflon) (trademark PFA) were utilized. One such application encountered was in the design of the graduated tank which allows visual inspection of the material prior to dispensing. Containers used for compatibility/corrosion testing were also constructed of PFA.

  19. Optimal Initial Conditions for Coupling Ice Sheet Models to Earth...

    Office of Scientific and Technical Information (OSTI)

    for Coupling Ice Sheet Models to Earth System Models. Citation Details In-Document Search Title: Optimal Initial Conditions for Coupling Ice Sheet Models to Earth System Models. ...

  20. EarthEnergy Limited | Open Energy Information

    Open Energy Info (EERE)

    Cornwall, United Kingdom Product: EarthEnergy Systems specialises in ground source heat pump systems. References: EarthEnergy Limited1 This article is a stub. You can help OpenEI...

  1. C LI CI

    Office of Legacy Management (LM)

    LI CI - - 11 C LI I I Mb II II OAK RIDGE NATIONAL LABORATORY UPERml BY M A R T IN M A R IETTA ENERGY S Y S T E M S , INC. FOR THE UNfTEG STATES OEPARTMENT OF ENERGY ORNLITM-10007 RADIOLOGICAL SURVEY OF THE PERIMETER FENCE LINE OF THE FORMER COTTER SITE, HAZELWOOD, M ISSOURI (LM002) R. F. Carrier W . D. Cottrell FILE COPY This report was prepared as an account of work sponsored by an agency of the UnitedStatesGovernment. NeithertheUnitedStatesGovernment noranyagency thereof, nor any of their

  2. Li Tec | Open Energy Information

    Open Energy Info (EERE)

    Drezden, Germany Product: Based in Kamez, near Dresden, Li-Tec produces components for lithium-ion batteries. References: Li-Tec1 This article is a stub. You can help OpenEI by...

  3. Earth System Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cleaner, greener, and more efficient biofuels and hydrocarbon resources, extraction ... field exercises Contamination fate and transport and environmental remediation ...

  4. Earth System Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rates. The ability to measure the concentrations of cosmogenic nuclides in rock and sediment has revolutionized geomorphology. Erosional surfaces and depositional features formed...

  5. SciDAC's Earth System Grid Center for Enabling Technologies Semi-Annual Progress Report for the Period October 1, 2009 through March 31, 2010

    SciTech Connect (OSTI)

    Williams, Dean N.; Foster, I. T.; Middleton, D. E.; Ananthakrishnan, R.; Siebenlist, F.; Shoshani, A.; Sim, A.; Bell, G.; Drach, R.; Ahrens, J.; Jones, P.; Brown, D.; Chastang, J.; Cinquini, L.; Fox, P.; Harper, D.; Hook, N.; Nienhouse, E.; Strand, G.; West, P.; Wilcox, H.; Wilhelmi, N.; Zednik, S.; Hankin, S.; Schweitzer, R.; Bernholdt, D.; Chen, M.; Miller, R.; Shipman, G.; Wang, F.; Bharathi, S.; Chervenak, A.; Schuler, R.; Su, M.

    2010-04-21

    This report summarizes work carried out by the ESG-CET during the period October 1, 2009 through March 31, 2009. It includes discussion of highlights, overall progress, period goals, collaborations, papers, and presentations. To learn more about our project, and to find previous reports, please visit the Earth System Grid Center for Enabling Technologies (ESG-CET) website. This report will be forwarded to the DOE SciDAC program management, the Office of Biological and Environmental Research (OBER) program management, national and international collaborators and stakeholders (e.g., the Community Climate System Model (CCSM), the Intergovernmental Panel on Climate Change (IPCC) 5th Assessment Report (AR5), the Climate Science Computational End Station (CCES), the SciDAC II: A Scalable and Extensible Earth System Model for Climate Change Science, the North American Regional Climate Change Assessment Program (NARCCAP), and other wide-ranging climate model evaluation activities).

  6. A Generic Biogeochemical Module for Earth System Models: Next Generation BioGeoChemical Module (NGBGC), Version 1.0

    SciTech Connect (OSTI)

    Fang, Yilin; Huang, Maoyi; Liu, Chongxuan; Li, Hongyi; Leung, Lai-Yung R.

    2013-11-13

    Physical and biogeochemical processes regulate soil carbon dynamics and CO2 flux to and from atmosphere, influencing global climate changes. Integration of these processes into earth system models (e.g., community land models (CLM)), however, currently faces three major challenges: 1) extensive efforts are required to modify modeling structures and to rewrite computer programs to incorporate new or updated processes as new knowledge is being generated, 2) computational cost is prohibitively expensive to simulate biogeochemical processes in land models due to large variations in the rates of biogeochemical processes, and 3) various mathematical representations of biogeochemical processes exist to incorporate different aspects of fundamental mechanisms, but systematic evaluation of the different mathematical representations is difficult, if not possible. To address these challenges, we propose a new computational framework to easily incorporate physical and biogeochemical processes into land models. The new framework consists of a new biogeochemical module with a generic algorithm and reaction database so that new and updated processes can be incorporated into land models without the need to manually set up the ordinary differential equations to be solved numerically. The reaction database consists of processes of nutrient flow through the terrestrial ecosystems in plants, litter and soil. This framework facilitates effective comparison studies of biogeochemical cycles in an ecosystem using different conceptual models under the same land modeling framework. The approach was first implemented in CLM and benchmarked against simulations from the original CLM-CN code. A case study was then provided to demonstrate the advantages of using the new approach to incorporate a phosphorus cycle into the CLM model. To our knowledge, the phosphorus-incorporated CLM is a new model that can be used to simulate phosphorus limitation on the productivity of terrestrial ecosystems.

  7. Description and Evaluation of Tropospheric Chemistry and Aerosols in the Community Earth System Model (CESM1.2)

    SciTech Connect (OSTI)

    Tilmes, S.; Lamarque, J.-F.; Emmons, L.; Kinnison, Douglas E.; Ma, Po-Lun; Liu, Xiaohong; Ghan, Steven J.; Bardeen, C.; Arnold, S.; Deeter, M.; Vitt, Francis; Ryerson, T. B.; Elkins, J. W.; Moore, F.; Spackman, R.; Martin, M. V.

    2015-01-01

    The Community Atmosphere Model (CAM), version 5, is now coupled to extensive tropospheric and stratospheric chemistry, called CAM5-chem, and is available in addition to CAM4-chem in the Community Earth System Model (CESM) version 1.2. Both configurations are well suited as tools for atmospheric-chemistry modeling studies in the troposphere and lower stratosphere, whether with internally derived free running (FR) meteorology, or specified dynamics (SD). The main focus of this paper is to compare the performance of these configurations against observations from surface, aircraft, and satellite, as well as understand the origin of the identified differences. We particularly focus on comparing present-day methane lifetime estimates within the different model configurations, which range between 7.8 years in the SD configuration of CAM5-chem and 8.8 years in the FR configuration of CAM4-chem. We find that tropospheric surface area density is an important factor in controlling the burden of the hydroxyl radical (OH), which causes differences in tropical methane lifetime of about half a year between CAM4-chem and CAM5-chem. In addition, different distributions of nitrogen oxides (NOx) produced from lightning production explain about half of the difference between SD and FR model versions in both CAM4-chem and CAM5-chem. Remaining differences in the tropical OH burden are due to enhanced tropical ozone burden in SD configurations compared to the FR versions, which are not only caused by differences in chemical production or loss, but also by transport and mixing. For future studies, we recommend the use of CAM5-chem, due to improved aerosol description and inclusion of aerosol-cloud interactions. However, smaller tropospheric surface area density in the current version of CAM5-chem compared to CAM4-chem results in larger oxidizing capacity in the troposphere and therefore a shorter methane lifetime.

  8. Description and Evaluation of Tropospheric Chemistry and Aerosols in the Community Earth System Model (CESM1.2)

    SciTech Connect (OSTI)

    Tilmes, S.; Lamarque, J. -F.; Emmons, L.; Kinnison, Douglas E.; Ma, Po-Lun; Liu, Xiaohong; Ghan, Steven J.; Bardeen, C.; Arnold, S.; Deeter, M.; Vitt, Francis; Ryerson, T. B.; Elkins, J. W.; Moore, F.; Spackman, R.; Martin, M. V.

    2015-05-13

    The Community Atmosphere Model (CAM), version 5, is now coupled to extensive tropospheric and stratospheric chemistry, called CAM5-chem, and is available in addition to CAM4-chem in the Community Earth System Model (CESM) version 1.2. Both configurations are well suited as tools for atmospheric-chemistry modeling studies in the troposphere and lower stratosphere, whether with internally derived free running (FR) meteorology, or specified dynamics (SD). The main focus of this paper is to compare the performance of these configurations against observations from surface, aircraft, and satellite, as well as understand the origin of the identified differences. We particularly focus on comparing present-day methane lifetime estimates within the different model configurations, which range between 7.8 years in the SD configuration of CAM5-chem and 8.8 years in the FR configuration of CAM4-chem. We find that tropospheric surface area density is an important factor in controlling the burden of the hydroxyl radical (OH), which causes differences in tropical methane lifetime of about half a year between CAM4-chem and CAM5-chem. In addition, different distributions of nitrogen oxides (NOx) produced from lightning production explain about half of the difference between SD and FR model versions in both CAM4-chem and CAM5-chem. Remaining differences in the tropical OH burden are due to enhanced tropical ozone burden in SD configurations compared to the FR versions, which are not only caused by differences in chemical production or loss, but also by transport and mixing. For future studies, we recommend the use of CAM5-chem, due to improved aerosol description and inclusion of aerosol-cloud interactions. However, smaller tropospheric surface area density in the current version of CAM5-chem compared to CAM4-chem results in larger oxidizing capacity in the troposphere and therefore a shorter methane lifetime.

  9. Differences in carbon cycle and temperature projections from emission- and concentration-driven earth system model simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, P.; Zeng, X.; Zeng, X.

    2014-08-29

    The influence of prognostic and prescribed atmospheric CO2 concentrations ([CO2]) on the carbon uptake and temperature is investigated using all eight Earth System Models (ESMs) with relevant output variables from the Coupled Model Intercomparison Project Phase 5 (CMIP5). Under the RCP8.5 scenario, the projected [CO2] differences in 2100 vary from -19.7 to +207.3 ppm in emission-driven ESMs. Incorporation of the interactive concentrations also increases the range of global warming, computed as the 20 year average difference between 20812100 and 18501869/18611880, by 49% from 2.36 K (i.e. ranging from 3.11 to 5.47 K) in the concentration-driven simulations to 3.51 K inmorethe emission-driven simulations. The observed seasonal amplitude of global [CO2] from 19802011 is about 1.25.3 times as large as those from the eight emission-driven ESMs, while the [CO2] seasonality is simply neglected in concentration-driven ESMs, suggesting the urgent need of ESM improvements in this area. The temperature-concentration feedback parameter ? is more sensitive to [CO2] (e.g. during 19802005 versus 20752100) than how [CO2] is handled (i.e. prognostic versus prescribed). This sensitivity can be substantially reduced by using a more appropriate parameter ?' computed from the linear regression of temperature change versus that of the logarithm of [CO2]. However, the inter-model relative variations of both ? and ?' remain large, suggesting the need of more detailed studies to understand and hopefully reduce these discrepancies.less

  10. Description and Evaluation of Tropospheric Chemistry and Aerosols in the Community Earth System Model (CESM1.2)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tilmes, S.; Lamarque, J. -F.; Emmons, L.; Kinnison, Douglas E.; Ma, Po-Lun; Liu, Xiaohong; Ghan, Steven J.; Bardeen, C.; Arnold, S.; Deeter, M.; et al

    2015-05-13

    The Community Atmosphere Model (CAM), version 5, is now coupled to extensive tropospheric and stratospheric chemistry, called CAM5-chem, and is available in addition to CAM4-chem in the Community Earth System Model (CESM) version 1.2. Both configurations are well suited as tools for atmospheric-chemistry modeling studies in the troposphere and lower stratosphere, whether with internally derived “free running” (FR) meteorology, or “specified dynamics” (SD). The main focus of this paper is to compare the performance of these configurations against observations from surface, aircraft, and satellite, as well as understand the origin of the identified differences. We particularly focus on comparing present-daymore » methane lifetime estimates within the different model configurations, which range between 7.8 years in the SD configuration of CAM5-chem and 8.8 years in the FR configuration of CAM4-chem. We find that tropospheric surface area density is an important factor in controlling the burden of the hydroxyl radical (OH), which causes differences in tropical methane lifetime of about half a year between CAM4-chem and CAM5-chem. In addition, different distributions of nitrogen oxides (NOx) produced from lightning production explain about half of the difference between SD and FR model versions in both CAM4-chem and CAM5-chem. Remaining differences in the tropical OH burden are due to enhanced tropical ozone burden in SD configurations compared to the FR versions, which are not only caused by differences in chemical production or loss, but also by transport and mixing. For future studies, we recommend the use of CAM5-chem, due to improved aerosol description and inclusion of aerosol-cloud interactions. However, smaller tropospheric surface area density in the current version of CAM5-chem compared to CAM4-chem results in larger oxidizing capacity in the troposphere and therefore a shorter methane lifetime.« less

  11. Origin of high Li? conduction in doped Li?La?Zr?O?? garnets

    SciTech Connect (OSTI)

    Chen, Yan; Rangasamy, Ezhiylmurugan; Liang, Chengdu; An, Ke

    2015-08-06

    Substitution of a native ion in the crystals with a foreign ion that differs in valence (aliovalent doping) has been widely attempted to upgrade solid-state ionic conductors for various charge carriers including O?, H?, Li?, Na?, etc. The doping helps promote the high-conductive framework and dredge the tunnel for fast ion transport. The garnet-type Li?La?Zr?O?? (LLZO) is a fast Li? solid conductor, which received much attention as an electrolyte candidate for all-solid-state lithium ion batteries, showing great potential to offer high energy density and minimize battery safety concerns to meet extensive applications in large energy storage systems such as those for electric vehicles and aerospace. In the Li-stuffed garnet framework of LLZO, the 3D pathway formed by the incompletely occupied tetrahedral sites bridged by a single octahedron enables the superior Li? conductivity. For optimal performance, many aliovalent-doping efforts have been made throughout metal elements (Al?, Ta??) and metalloid elements (Ga?, Te??) in the periodic table with various valences to stabilize the high-conductive phase and increase the Li vacancy concentration.

  12. Correlation of anisotropy and directional conduction in β-Li3PS4 fast Li+ conductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Yan; Cai, Lu; Liu, Zengcai; dela Cruz, Clarina R.; Liang, Chengdu; An, Ke

    2015-07-06

    Our letter reports the correlation of anisotropy and directional conduction in the fast Li+ conductor β-Li3PS4, one of the low-symmetry crystalline electrolyte candidates. The material has both high conductivity and good stability that serves well for the large-scale energy storage applications of all-solid-state lithium ion batteries. The anisotropic physical properties, demonstrated here by the thermal expansion coefficients, are crucial for compatibility in the solid-state system and battery performance. Neutron and X-ray powder diffraction measurements were done to determine the crystal structure and thermal stability. Moreover, the crystallographic b-axis was revealed as a fast expansion direction, while negligible thermal expansion wasmore » observed along the a-axis around the battery operating temperatures. The anisotropic behavior has its structural origin from the Li+ conduction channels with incomplete Li occupancy and a flexible connection of LiS4 and PS4 tetrahedra within the framework. This indicates a strong correlation in the direction of the ionic transport in the low-symmetry Li+ conductor.« less

  13. Final Report. Evaluating the Climate Sensitivity of Dissipative Subgrid-Scale Mixing Processes and Variable Resolution in NCAR's Community Earth System Model

    SciTech Connect (OSTI)

    Jablonowski, Christiane

    2015-12-14

    The goals of this project were to (1) assess and quantify the sensitivity and scale-dependency of unresolved subgrid-scale mixing processes in NCAR’s Community Earth System Model (CESM), and (2) to improve the accuracy and skill of forthcoming CESM configurations on modern cubed-sphere and variable-resolution computational grids. The research thereby contributed to the description and quantification of uncertainties in CESM’s dynamical cores and their physics-dynamics interactions.

  14. Polymer electrolytes for a rechargeable li-Ion battery

    SciTech Connect (OSTI)

    Argade, S.D.; Saraswat, A.K.; Rao, B.M.L.; Lee, H.S.; Xiang, C.L.; McBreen, J.

    1996-10-01

    Lithium-ion polymer electrolyte battery technology is attractive for many consumer and military applications. A Li{sub x}C/Li{sub y}Mn{sub 2}O{sub 4} battery system incorporating a polymer electrolyte separator base on novel Li-imide salts is being developed under sponsorship of US Army Research Laboratory (Fort Monmouth NJ). This paper reports on work currently in progress on synthesis of Li-imide salts, polymer electrolyte films incorporating these salts, and development of electrodes and cells. A number of Li salts have been synthesized and characterized. These salts appear to have good voltaic stability. PVDF polymer gel electrolytes based on these salts have exhibited conductivities in the range 10{sup -4} to 10{sub -3} S/cm.

  15. Electrochemical Study on the Electrodeposition of U, Nd, Ce, La and Y on a Liquid Cadmium Cathode in a LiCl-KCl Eutectic Salt

    SciTech Connect (OSTI)

    Sung Bin Park; Jong Hyeon Lee; Sung Chan Hwang; Young Ho Kang; Joon Bo Shim; Han Soo Lee; Eung Ho Kim; Seong Won Park

    2007-07-01

    Electro-depositions of U, Nd, Ce, La and Y on a liquid cadmium cathode in a LiCl-KCl eutectic salt were studied by using an electrolytic cell. For the LiCl-KCl-UCl{sub 3}- NdCl{sub 3}-CeCl{sub 3}-LaCl{sub 3}-YCl{sub 3}/Cd system, cyclic voltammograms and polarization curves were measured and the electrochemical properties of the system were discussed. From the results of the electro-depositions of U and rare earth metals on the LCC, separation factors and recovery ratios of U and REs were obtained and co-electro-depositions of U and REs were investigated. (authors)

  16. Center for Space and Earth Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Institute of Geophysics, Planetary Physics, and Signatures Center for Space and Earth Science Promoting and supporting high-quality, cutting-edge science in the areas of astrophysics, space physics, solid planetary geoscience, and climate science. Contact Director Reiner Friedel (505) 665-1936 Email Professional Staff Assistant Georgia Sanchez (505) 665-0855 Email Astophysics and Cosmology Hui Li (505) 665-3131 Email Climate Keeley Costigan (505) 665-4788 Email Geophysics David Coblentz (505)

  17. Optically pumped cerium-doped LiSrAlF{sub 6} and LiCaAlF{sub 6}

    DOE Patents [OSTI]

    Marshall, C.D.; Payne, S.A.; Krupke, W.F.

    1996-05-14

    Ce{sup 3+}-doped LiSrAlF{sub 6} crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF{sub 6} with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF{sub 6} type of chemical formula, e.g. Ce-doped LiCaAlF{sub 6} and LiSrGaF{sub 6}, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator. 10 figs.

  18. Optically pumped cerium-doped LiSrAlF.sub.6 and LiCaAlF.sub.6

    DOE Patents [OSTI]

    Marshall, Christopher D.; Payne, Stephen A.; Krupke, William F.

    1996-01-01

    Ce.sup.3+ -doped LiSrAlF.sub.6 crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF.sub.6 with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF.sub.6 type of chemical formula, e.g. Ce-doped LiCaAlF.sub.6 and LiSrGaF.sub.6, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator.

  19. Isothermal evaporation process simulation using the Pitzer model for the Quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Lingzong; Gruszkiewicz, Miroslaw S.; Deng, Tianlong; Guo, Yafei; Li, Dan

    2015-08-05

    In this study, the Pitzer thermodynamic model for solid-liquid equilibria in the quinary system LiCl–NaCl–KCl–SrCl2–H2O at 298.15 K was constructed by selecting the proper parameters for the subsystems in the literature. The solubility data of the systems NaCl–SrCl2–H2O, KCl–SrCl2–H2O, LiCl–SrCl2–H2O, and NaCl–KCl–SrCl2–H2O were used to evaluate the model. Good agreement between the experimental and calculated solubilities shows that the model is reliable. The Pitzer model for the quinary system at 298.15 K was then used to calculate the component solubilities and conduct computer simulation of isothermal evaporation of the mother liquor for the oilfield brine from Nanyishan district in themore » Qaidam Basin. The evaporation-crystallization path and sequence of salt precipitation, change in concentration and precipitation of lithium, sodium, potassium, and strontium, and water activities during the evaporation process were demonstrated. The salts precipitated from the brine in the order : KCl, NaCl, SrCl2∙6H2O, SrCl2∙2H2O, and LiCl∙H2O. The entire evaporation process may be divided into six stages. In each stage the variation trends for the relationships between ion concentrations or water activities and the evaporation ratio are different. This result of the simulation of brines can be used as a theoretical reference for comprehensive exploitation and utilization of this type of brine resources.« less

  20. Google Earth Tour: Contaminants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Google Earth Tour: Contaminants Google Earth Tour: Contaminants Historical operations used the best available waste handling methods for that time.

  1. Alternating magnetic anisotropy of Li 2 ( Li 1 - x T x ) N ( T = Mn , Fe , Co , and Ni )

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-01

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li?(Li1-xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.moreThe calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.less

  2. Alternating magnetic anisotropy of Li2(Li1xTx)N(T=Mn,Fe,Co,andNi)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.moreAs a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.less

  3. Alternating magnetic anisotropy of Li2(Li1–xTx)N (T = Mn, Fe, Co, and Ni)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1–xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane→easy axis→easy plane→easy axis when progressing from T = Mn → Fe → Co → Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model.more » As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.« less

  4. Direct observation of the redistribution of sulfur and polysufides in Li-S batteries during first cycle by in situ X-Ray fluorescence microscopy

    SciTech Connect (OSTI)

    Yu, Xiquian; Pan, Huilin; Zhou, Yongning; Northrup, Paul; Xiao, Jie; Bak, Seongmin; Liu, Mingzhao; Nam, Kyung-Wan; Qu, Deyang; Liu, Jun; Wu, Tianpin; Yang, Xiao-Qing

    2015-03-25

    The demands on low cost and high energy density rechargeable batteries for both transportation and large-scale stationary energy storage are stimulating more and more research toward new battery systems. Since sulfur is an earth-abundant material with low cost, research on the high energy density LiS batteries (2600 W h kg?) are getting more and more attention. The reactions between sulfur and lithium during chargedischarge cycling are quite complicated, going through multiple electron transfer process associated with chemical and electrochemical equilibrium between long- and short-chain polysulfide Li?Sx intermediates (1 < x ? 8). It is reported that the long-chain polysulfides can be dissolved into electrolyte with aprotic organic solvents and migrated to the Li anode side. This so-called shuttle effect is believed to be the main reason for capacity loss and low columbic efficiency of the LiS batteries. In the past few years, a great deal of efforts have been made on how to overcome the problem of polysulfide dissolution through new sulfur electrode construction and cell designs, as well as the modification of the electrolyte. Although it has been reported by several publications that some LiS cells can sustain more than a thousand cycles based on the thin film electrode configurations, the long-term cycling stability is still one of the major barriers for the real application of LiS batteries. More in-depth studies on the fundamental understanding of the sulfur reaction mechanism and interactions among the different polysulfide species, the electrolyte and the electrodes are still greatly needed. Various in situ techniques have been developed and applied to study the mechanism of the sulfur chemistry in LiS batteries during electrochemical cycling, such as transmission X-ray microscopy (TXM), X-ray absorption spectroscopy (XAS), X-ray diffraction (XRD), UVvisible spectroscopy, and electron paramagnetic resonance (EPR). The applications of these characterization techniques have demonstrated their power in probing the structure changes, morphology evolutions, and coordination of sulfur and polysulfides with the electrolyte in LiS cells, providing complementary information to each other thus enhancing the understanding in LiS battery systems. In this communication, in situ X-ray fluorescence (XRF) microscopy was combined with XAS to directly probe the morphology changes of LiS batteries during first cycle. The morphology changes of the sulfur electrode and the redistribution of sulfur and polysulfides were monitored in real time through the XRF images, while the changes of the sulfur containing compounds were characterized through the XAS spectra simultaneously. In contrast to other studies using ex situ or single characterization technique as reported in the literatures, the in situ technique used in this work has the unique feature of probing the LiS cell under operating conditions, as well as the combination of XRF imaging with spectroscopy data. By doing this, the morphology evolution and redistribution of specific sulfur particles during cycling can be tracked and identified at certain locations in a real time. In addition, this technique allows us to select the field-of-view (FOV) area from micrometer to centimeter size, providing the capability to study the LiS reactions not just at the material level, but also at the electrode level. This is very important for both understanding LiS chemistry and designing effective strategies for LiS batteries.

  5. Performance of LiAlloy/Ag(2)CrO(4) Couples in Molten CsBr-LiBr-KBr Eutectic

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    1999-10-18

    The performance of Li-alloy/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} systems was studied over a temperature range of 250 C to 300 C, for possible use as a power source for geothermal borehole applications. Single cells were discharged at current densities of 15.8 and 32.6 mA/cm{sup 2} using Li-Si and Li-Al anodes. When tested in 5-cell batteries, the Li-Si/CsBr-LiBr-KBr/Ag{sub 2}CrO{sub 4} system exhibited thermal runaway. Thermal analytical tests showed that the Ag{sub 2}CrO{sub 4} cathode reacted exothermically with the electrolyte on activation. Consequently, this system would not be practical for the envisioned geothermal borehole applications.

  6. Li2ikk+

    Office of Legacy Management (LM)

    Li2ikk+ 0/-/.3~+ ' Department of Energy Washington, DC 20585 m 19 1999 Mr. William R. Augustine Deputy Chief Programs Management Division U.S. Army Corps of Engineers Depanment of the Army Washington. D.C. 203 14-1000 Dear Mr. Augustine: I am writing to you as a follow-up to discussions our staffs have had regarding two former Department of the Army facilities in the Formerly Used Defense Sites (FUDS) program where the former Atomic Energy Commission (AEC) also conducted activities. These sites

  7. UJ LiJ

    Office of Legacy Management (LM)

    o >- tD o UJ :> LiJ o W ~ Central Nevada-23 UNITED STATES DEPARTMENT OF THE INTERIOR GEOLOGICAL SURVEY Federal Center, Denver, Colorado 80225 ANALYSIS OF HYDRAULIC TESTS IN HOT CREEK VALLEY, NEVADA June 1970 Open-file report Prepared Under Contract AT(29-2)-474 for the Nevada Operations Office U.S. Atomic Energy Commission USGS-474-82 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor

  8. A=11Li (2012KE01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E(11Li) 246 MeVA, analysis of a complete three-body kinematical measurement of 11Li breakup on a 12C target indicates the reaction mechanism is 11Li inelastic scattering to...

  9. Liang Li | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liang Li Postdoctoral Appointee (Supervisor, Maria Chan) Current research focuses on ab-initio theoretical studies on hybrid lithium-ion/lithium-oxygen battery materials and photocatalytic reduction of CO2. Telephone 630.252.2788 Fax 630.252.4646 E-mail liangli@anl.gov CV/Resume PDF icon Liang_Li

  10. Lithium Salts for Advanced Lithium Batteries: Li-metal, Li-O2, and Li-S

    SciTech Connect (OSTI)

    Younesi, Reza; Veith, Gabriel M; Johansson, Patrik; Edstrom, Kristina; Vegge, Tejs

    2015-01-01

    Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions and conditions within such cells. This review explores the critical role Li-salts play in ensuring in these batteries viability.

  11. Lithium salts for advanced lithium batteries: Li-metal, Li-O2, and Li-S

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Younesi, Reza; Veith, Gabriel M.; Johansson, Patrik; Edstrom, Kristina; Vegge, Tejs

    2015-06-01

    Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions andmore » conditions within such cells. Furthermore, this review explores the critical role Li-salts play in ensuring in these batteries viability.« less

  12. Lithium salts for advanced lithium batteries: Li-metal, Li-O2, and Li-S

    SciTech Connect (OSTI)

    Younesi, Reza; Veith, Gabriel M.; Johansson, Patrik; Edstrom, Kristina; Vegge, Tejs

    2015-06-01

    Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions and conditions within such cells. Furthermore, this review explores the critical role Li-salts play in ensuring in these batteries viability.

  13. Recovery of Li from alloys of Al- Li and Li- Al using engineered scavenger compounds

    DOE Patents [OSTI]

    Riley, W. D.; Jong, B. W.; Collins, W. K.; Gerdemann, S. J.

    1994-01-01

    A method of producing lithium of high purity from lithium aluminum alloys using an engineered scavenger compound, comprising: I) preparing an engineered scavenger compound by: a) mixing and heating compounds of TiO2 and Li2CO3 at a temperature sufficient to dry the compounds and convert Li.sub.2 CO.sub.3 to Li.sub.2 O; and b) mixing and heating the compounds at a temperature sufficient to produce a scavenger Li.sub.2 O.3TiO.sub.2 compound; II) loading the scavenger into one of two electrode baskets in a three electrode cell reactor and placing an Al-Li alloy in a second electrode basket of the three electrode cell reactor; III) heating the cell to a temperature sufficient to enable a mixture of KCl-LiCl contained in a crucible in the cell to reach its melting point and become a molten bath; IV) immersing the baskets in the bath until an electrical connection is made between the baskets to charge the scavenger compound with Li until there is an initial current and voltage followed by a fall off ending current and voltage; and V) making a connection between the basket electrode containing engineered scavenger compound and a steel rod electrode disposed between the basket electrodes and applying a current to cause Li to leave the scavenger compound and become electrodeposited on the steel rod electrode.

  14. Rare-Earth-Free Nanostructure Magnets: Rare-Earth-Free Permanent Magnets for Electric Vehicle Motors and Wind Turbine Generators: Hexagonal Symmetry Based Materials Systems Mn-Bi and M-type Hexaferrite

    SciTech Connect (OSTI)

    2012-01-01

    REACT Project: The University of Alabama is developing new iron- and manganese-based composite materials for use in the electric motors of EVs and renewable power generators that will demonstrate magnetic properties superior to todays best rare-earth-based magnets. Rare earths are difficult and expensive to refine. EVs and renewable power generators typically use rare earths to make their electric motors smaller and more powerful. The University of Alabama has the potential to improve upon the performance of current state-of-the-art rare-earth-based magnets using low-cost and more abundant materials such as manganese and iron. The ultimate goal of this project is to demonstrate improved performance in a full-size prototype magnet at reduced cost.

  15. Earth and Environmental Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EES Earth and Environmental Sciences (EES) Sustainable energy, climate impacts, nuclear threat detection, and environmental management are primary focus areas of earth and...

  16. Computational Earth Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 Computational Earth Science We develop and apply a range of high-performance computational methods and software tools to Earth science projects in support of environmental ...

  17. Earth, Space Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth, Space Sciences science-innovationassetsimagesicon-science.jpg Earth, Space Sciences National security depends on science and technology. The United States relies on Los ...

  18. Google Earth Tour: Contaminants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Google Earth Tour: Contaminants Google Earth Tour: Contaminants Historical operations used the best available waste handling methods for that time. Open full screen to view more...

  19. Through-the-earth radio

    DOE Patents [OSTI]

    Reagor, David; Vasquez-Dominguez, Jose

    2006-12-12

    A through-the-earth communication system that includes a digital signal input device; a transmitter operating at a predetermined frequency sufficiently low to effectively penetrate useful distances through-the earth; a data compression circuit that is connected to an encoding processor; an amplifier that receives encoded output from the encoding processor for amplifying the output and transmitting the data to an antenna; and a receiver with an antenna, a band pass filter, a decoding processor, and a data decompressor.

  20. A=14Li (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    86AJ01) (Not illustrated) 14Li has not been observed. The calculated mass excess is 72.29 MeV: see (1981AJ01). 14Li is then particle unstable with respect to decay into 13Li + n and 12Li + 2n by 3.88 and 3.22 MeV, respectively

  1. A=15Li (1981AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1AJ01) (Not illustrated) 15Li has not been observed: its atomic mass excess is calculated to be 81.60 MeV. It is then unstable with respect to decay into 14Li + n and 13Li + 2n by 1.24 and 3.90 MeV, respectively (1974TH01). See also 13Li

  2. A=9Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    66LA04) (See Energy Level Diagrams for 9Li) GENERAL: See (GR64C). See also Table 9.1 Table of Energy Levels (in PDF or PS). Mass of 9Li: From the Q-value for 7Li(t, p)9Li: Q ...

  3. Analysis of Heat Dissipation in Li-Ion Cells & Modules for Modeling of Thermal Runaway (Presentation)

    SciTech Connect (OSTI)

    Kim, G.-H.; Pesaran, A.

    2007-05-15

    The objectives of this study are: (1) To develop 3D Li-Ion battery thermal abuse ''reaction'' models for cell and module analysis; (2) To understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-Ion cells and modules; (3) To develop a tool and methodology to support the design of abuse-tolerant Li-Ion battery systems for PHEVs/HEVs; and (4) To help battery developers accelerate delivery of abuse-tolerant Li-Ion battery systems in support of the FreedomCAR's Energy Storage Program.

  4. li(2)-98.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1994 through March 1995. The calibration accuracy is estimated to be 1% to 2% (Kandel et al. 1998; Trishchenko and Li 1998). While GOES provides data at much higher...

  5. Microsoft Word - li_abstract

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    will be served at 3:30 pm A few new issues regarding the density dependence of nuclear symmetry energy Professor Bao-An Li Department of Physics and Astronomy, Texas A&M ...

  6. Earth coupled cooling techniques

    SciTech Connect (OSTI)

    Grondzik, W.T.; Boyer, L.L.; Johnston, T.L.

    1981-01-01

    Earth coupled cooling is an important consideration for residential and commercial designers, owners, and builders in many regions of the country. The potential benefits which can be expected from passive earth contact cooling are reviewed. Recommendations for the design of earth sheltered structures incorporating earth coupled cooling strategies are also presented.

  7. Precise trace rare earth analysis by radiochemical neutron activation

    SciTech Connect (OSTI)

    Laul, J.C.; Lepel, E.A.; Weimer, W.C.; Wogman, N.A.

    1981-06-01

    A rare earth group separation scheme followed by normal Ge(Li), low energy photon detector (LEPD), and Ge(Li)-NaI(Tl) coincidence-noncoincidence spectrometry significantly enhances the detection sensitivity of individual rare earth elements (REE) at or below the ppB level. Based on the selected ..gamma..-ray energies, normal Ge(Li) counting is favored for /sup 140/La, /sup 170/Tb, and /sup 169/Yb; LEPD is favored for low ..gamma..-ray energies of /sup 147/Nd, /sup 153/Sm, /sup 166/Ho, and /sup 169/Yb; and noncoincidence counting is favored for /sup 141/Ce, /sup 143/Ce, /sup 142/Pr, /sup 153/Sm, /sup 171/Er, and /sup 175/Yb. The detection of radionuclides /sup 152m/Eu, /sup 159/Gd, and /sup 177/Lu is equally sensitive by normal Ge(Li) and noncoincidence counting; /sup 152/Eu is equally sensitive by LEPD and normal Ge(Li); and /sup 153/Gd and /sup 170/Tm is equally favored by all the counting modes. Overall, noncoincidence counting is favored for most of the REE. Precise measurements of the REE were made in geological and biological standards.

  8. CoolEarth formerly Cool Earth Solar | Open Energy Information

    Open Energy Info (EERE)

    CoolEarth formerly Cool Earth Solar Jump to: navigation, search Name: CoolEarth (formerly Cool Earth Solar) Place: Livermore, California Zip: 94550 Product: CoolEarth is a...

  9. Anion Coordination Interactions in Solvates with the Lithium Salts LiDCTA and LiTDI

    SciTech Connect (OSTI)

    McOwen, Dennis W.; Delp, Samuel A.; Paillard, Elie; Herriot, Cristelle; Han, Sang D.; Boyle, Paul D.; Sommer, Roger D.; Henderson, Wesley A.

    2014-04-17

    Lithium 4,5-dicyano-1,2,3-triazolate (LiDCTA) and lithium 2-trifluoromethyl-4,5-dicyanoimidazole (LiTDI) are two salts proposed for lithium battery electrolyte applications, but little is known about the manner in which the DCTA- and TDI- anions coordinate Li+ cations. To explore this in-depth, crystal structures are reported here for two solvates with LiDCTA: (G2)1:LiDCTA and (G1)1:LiDCTA with diglyme and monoglyme, respectively, and seven solvates with LiTDI: (G1)2:LiTDI, (G2)2:LiTDI, (G3)1:LiTDI, (THF)1:LiTDI, (EC)1:LiTDI, (PC)1:LiTDI and (DMC)1/2:LiTDI with monoglyme, diglyme, triglyme, tetrahydrofuran, ethylene carbonate, propylene carbonate and dimethyl carbonate, respectively. These latter solvate structures are compared with the previously reported acetonitrile (AN)2:LiTDI structure. The solvates indicate that the LiTDI salt is much less associated than the LiDCTA salt and that the ions in LiTDI, when aggregated in solvates, have a very similar TDI-...Li+ cation mode of coordination through both the anion ring and cyano nitrogen atoms. Such coordination facilitates the formation of polymeric ion aggregates, instead of dimers. Insight into such ion speciation is instrumental for understanding the electrolyte properties of aprotic solvent mixtures with these salts.

  10. MOA-2011-BLG-262Lb: A sub-Earth-mass moon orbiting a gas giant primary or a high velocity planetary system in the galactic Bulge

    SciTech Connect (OSTI)

    Bennett, D. P.; Batista, V.; Bond, I. A.; Ling, C. H.; Bennett, C. S.; Suzuki, D.; Koshimoto, N.; Beaulieu, J.-P.; Udalski, A.; Donatowicz, J.; Bozza, V.; Abe, F.; Fukunaga, D.; Itow, Y.; Masuda, K.; Matsubara, Y.; Muraki, Y.; Botzler, C. S.; Freeman, M.; Fukui, A.; Collaboration: MOA Collaboration; PLANET Collaboration; μFUN Collaboration; OGLE Collaboration; RoboNet Collaboration; and others

    2014-04-20

    We present the first microlensing candidate for a free-floating exoplanet-exomoon system, MOA-2011-BLG-262, with a primary lens mass of M {sub host} ∼ 4 Jupiter masses hosting a sub-Earth mass moon. The argument for an exomoon hinges on the system being relatively close to the Sun. The data constrain the product M{sub L} π{sub rel} where M{sub L} is the lens system mass and π{sub rel} is the lens-source relative parallax. If the lens system is nearby (large π{sub rel}), then M{sub L} is small (a few Jupiter masses) and the companion is a sub-Earth-mass exomoon. The best-fit solution has a large lens-source relative proper motion, μ{sub rel} = 19.6 ± 1.6 mas yr{sup –1}, which would rule out a distant lens system unless the source star has an unusually high proper motion. However, data from the OGLE collaboration nearly rule out a high source proper motion, so the exoplanet+exomoon model is the favored interpretation for the best fit model. However, there is an alternate solution that has a lower proper motion and fits the data almost as well. This solution is compatible with a distant (so stellar) host. A Bayesian analysis does not favor the exoplanet+exomoon interpretation, so Occam's razor favors a lens system in the bulge with host and companion masses of M{sub host}=0.12{sub −0.06}{sup +0.19} M{sub ⊙} and m{sub comp}=18{sub −10}{sup +28} M{sub ⊕}, at a projected separation of a{sub ⊥}=0.84{sub −0.14}{sup +0.25} AU. The existence of this degeneracy is an unlucky accident, so current microlensing experiments are in principle sensitive to exomoons. In some circumstances, it will be possible to definitively establish the mass of such lens systems through the microlensing parallax effect. Future experiments will be sensitive to less extreme exomoons.

  11. SciDAC's Earth System Grid Center for Enabling Technologies Semi-Annual Progress Report for the Period April 1, 2009 through September 30, 2009

    SciTech Connect (OSTI)

    Williams, Dean N.; Foster, I. T.; Middleton, D. E.

    2009-10-15

    This report summarizes work carried out by the ESG-CET during the period April 1, 2009 through September 30, 2009. It includes discussion of highlights, overall progress, period goals, collaborations, papers, and presentations. To learn more about our project, and to find previous reports, please visit the Earth System Grid Center for Enabling Technologies (ESG-CET) website. This report will be forwarded to the DOE SciDAC program management, the Office of Biological and Environmental Research (OBER) program management, national and international collaborators and stakeholders (e.g., the Community Climate System Model (CCSM), the Intergovernmental Panel on Climate Change (IPCC) 5th Assessment Report (AR5), the Climate Science Computational End Station (CCES), the SciDAC II: A Scalable and Extensible Earth System Model for Climate Change Science, the North American Regional Climate Change Assessment Program (NARCCAP), and other wide-ranging climate model evaluation activities). During this semi-annual reporting period, the ESG-CET team continued its efforts to complete software components needed for the ESG Gateway and Data Node. These components include: Data Versioning, Data Replication, DataMover-Lite (DML) and Bulk Data Mover (BDM), Metrics, Product Services, and Security, all joining together to form ESG-CET's first beta release. The launch of the beta release is scheduled for late October with the installation of ESG Gateways at NCAR and LLNL/PCMDI. Using the developed ESG Data Publisher, the ESG II CMIP3 (IPCC AR4) data holdings - approximately 35 TB - will be among the first datasets to be published into the new ESG enterprise system. In addition, the NCAR's ESG II data holdings will also be published into the new system - approximately 200 TB. This period also saw the testing of the ESG Data Node at various collaboration sites, including: the British Atmospheric Data Center (BADC), the Max-Planck-Institute for Meteorology, the University of Tokyo Center for Climate System Research, and the Australian National University. This period, a total of 14 national and international sites installed an ESG Data Node for testing. During this period, we also continued to provide production-level services to the community, providing researchers worldwide with access to CMIP3 (IPCC AR4), CCES, and CCSM, Parallel Climate Model (PCM), Parallel Ocean Program (POP), and Cloud Feedback Model Intercomparison Project (CFMIP), and NARCCAP data.

  12. THE HIGH TEMPERATURE CHEMICAL REACTIVITY OF LI2O

    SciTech Connect (OSTI)

    Kessinger, G.; Missimer, D.

    2009-11-13

    The ultimate purpose of this study was to investigate the use of a Li-Ca mixture for direct reduction of actinide oxides to actinide metals at temperatures below 1500 C. For such a process to be successful, the products of the reduction reaction, actinide metals, Li{sub 2}O, and CaO, must all be liquid at the reaction temperature so the resulting actinide metal can coalesce and be recovered as a monolith. Since the established melting temperature of Li{sub 2}O is in the range 1427-1700 C and the melting temperature of CaO is 2654 C, the Li{sub 2}O-CaO (lithium oxidecalcium oxide) pseudo-binary system was investigated in an attempt to identify the presence of low-melting eutectic compositions. The results of our investigation indicate that there is no evidence of ternary Li-Ca-O phases or solutions melting below 1200 C. In the 1200-1500 C range utilizing MgO crucibles, there is some evidence for the formation of a ternary phase; however, it was not possible to determine the phase composition. The results of experiments performed with ZrO{sub 2} crucibles in the same temperature range did not show the formation of the possible ternary phase seen in the earlier experiment involving MgO crucibles, so it was not possible to confirm the possibility that a ternary Li-Ca-O or Li-Mg-O phase was formed. It appears that the Li{sub 2}O-CaO materials reacted, to some extent, with all of the container materials, alumina (Al{sub 2}O{sub 3}), magnesia (MgO), zirconia (ZrO{sub 2}), and 95% Pt-5% Au; however, to clarify the situation additional experiments are required. In addition to the primary purpose of this study, the results of this investigation led to the conclusions that: (1) The melting temperature of Li{sub 2}O may be as low as 1250 C, which is considerably lower than the previously published values in the range 1427-1700 C; (2) Lithium oxide (Li{sub 2}O) vaporizes congruently; (3) Lithium carbonate and Li2O react with 95% Pt-5% Au, and also reacts with pure Pt; and (4) It is likely that some or all of the past high temperature phase behavior and vaporization experiments involving Li{sub 2}O(s) at temperatures above 1250 C have actually involved Li{sub 2}O(l). If these past measurements were actually measurements performed on Li{sub 2}O(l) instead of the solid, the thermochemical data for phases and species in the Li-O system will require reevaluation.

  13. 7Li MRI of Li batteries reveals location of microstructural lithium...

    Office of Scientific and Technical Information (OSTI)

    Title: 7Li MRI of Li batteries reveals location of microstructural lithium Authors: Chandrashekar, S. ; Trease, Nicole M. ; Chang, Hee Jung ; Du, Lin-Shu ; Grey, Clare P. ; ...

  14. A=12Li (1975AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    75AJ02) (Not illustrated) 12Li is not observed in the 4.8 GeV proton bombardment of a uranium target: it is particle unstable (1974BO05). Its atomic mass excess is therefore > 49.0 MeV. (1974TH01) calculate the mass excess of 12Li to be 52.92 MeV. 12Li would then be unstable with respect to 11Li + n, 10Li + 2n and 9Li + 3n by 3.9, 3.68 and 3.74 MeV, respectively. See also (1972TH13, 1973BO30, 1974IR04

  15. A=12Li (1990AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    90AJ01) (Not illustrated) 12Li is not observed in the 4.8 GeV proton bombardment of a uranium target: it is particle unstable. The calculated value of its mass excess is 52.93 MeV [see (1980AJ01)]: 12Li would then be unstable with respect to 11Li + n ,10Li + 2n and 9Li + 3n by 4.01, 2.96 and 3.76 MeV, respectively. The ground state of 12Li is predicted to have Jπ = 2- (1988POZS, 1985PO10; theor.). See also (1980AJ01

  16. IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (GdLu)

    SciTech Connect (OSTI)

    Mioduski, Tomasz; Gumi?ski, Cezary; Zeng, Dewen

    2015-06-15

    This is the third part of the volume devoted to solubility data for the rare earth metal (REM) fluorides in water and in aqueous ternary and multicomponent systems. It covers experimental results of trivalent fluorides of Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu (so-called heavy lanthanides), since no quantitative data on solubilities of TbF{sub 4} and YbF{sub 2} (the most stable compounds at these valencies) are available. The related literature has been covered through the end of 2014. Compilations of all available papers with the solubility data are introduced for each REM fluoride with a corresponding critical evaluation. Every such assessment contains a collection of all solubility results in aqueous solution, a selection of suggested solubility data, a solubility equation, and a brief discussion of the multicomponent systems. Only simple fluorides (no complexes or double salts) are treated as the input substances in this report. General features of the systems, such as nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, solution pH, mixed solvent medium on the solubility, quality of the solubility results, and the solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.

  17. A PLANETARY SYSTEM AROUND THE NEARBY M DWARF GJ 667C WITH AT LEAST ONE SUPER-EARTH IN ITS HABITABLE ZONE

    SciTech Connect (OSTI)

    Anglada-Escude, Guillem; Butler, R. Paul; Arriagada, Pamela; Minniti, Dante; Vogt, Steven S.; Rivera, Eugenio J.; Haghighipour, Nader; Carter, Brad D.; Tinney, C. G.; Wittenmyer, Robert A.; Bailey, Jeremy A.; O'Toole, Simon J.; Jones, Hugh R. A.; Jenkins, James S.

    2012-05-20

    We re-analyze 4 years of HARPS spectra of the nearby M1.5 dwarf GJ 667C available through the European Southern Observatory public archive. The new radial velocity (RV) measurements were obtained using a new data analysis technique that derives the Doppler measurement and other instrumental effects using a least-squares approach. Combining these new 143 measurements with 41 additional RVs from the Magellan/Planet Finder Spectrograph and Keck/High Resolution Echelle Spectrometer spectrometers reveals three additional signals beyond the previously reported 7.2 day candidate, with periods of 28 days, 75 days, and a secular trend consistent with the presence of a gas giant (period {approx}10 years). The 28 day signal implies a planet candidate with a minimum mass of 4.5 M{sub Circled-Plus} orbiting well within the canonical definition of the star's liquid water habitable zone (HZ), that is, the region around the star at which an Earth-like planet could sustain liquid water on its surface. Still, the ultimate water supporting capability of this candidate depends on properties that are unknown such as its albedo, atmospheric composition, and interior dynamics. The 75 day signal is less certain, being significantly affected by aliasing interactions among a potential 91 day signal, and the likely rotation period of the star at 105 days detected in two activity indices. GJ 667C is the common proper motion companion to the GJ 667AB binary, which is metal-poor compared to the Sun. The presence of a super-Earth in the HZ of a metal-poor M dwarf in a triple star system supports the evidence that such worlds should be ubiquitous in the Galaxy.

  18. CI L C C I LI C

    Office of Legacy Management (LM)

    CI L C C - I LI C c C I I I I I I I L rr ORNL/RASA-94/l 0t-t. 27-6 \O [I ,-' :..L, &ml OAK RIDGE NATIONAL LABORATORY RESULTS OF THE RADIOLOGICAL SURVEY at the former HERRING-HALL-MARVIN SAFE COMPANY (3rd Floor) 1550 Grand Boulevard, Hamilton, Ohio (HOOOl) M. E. Murray C. A. Johnson MANA6ED BY MARTIN MARIETTA ENERGY SYSTEMS, INC. FOR THE UNITE0 STATES DEPARTMENT OF ENEMY This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office

  19. Argonne's Earth Day 2011

    ScienceCinema (OSTI)

    None

    2013-04-19

    Argonne celebrated Earth Day on April 21, 2011 with an event that featured green activities and information booths.

  20. A=18Li (1995TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1995TI07) (Not illustrated) 18Li has not been observed. Shell model calculations described in (1988POZS) predict the ground-state magentic dipole moment and charge and matter...

  1. A=11Li (1980AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    80AJ01) (See the Isobar Diagram for 11Li) 11Li has been observed in the bombardment of iridium by 24 GeV protons. Its mass excess is 40.94 ± 0.08 MeV (1975TH08). The cross section for its formation is ~ 50 μb (1976TH1A). 11Li is bound: Eb for break up into 9Li + 2n and 10Li + n are 158 ± 80 and 960 ± 250 keV, respectively [see (1979AJ01) for discussions of the masses of 9Li and 10Li]. The half-life of 11Li is 8.5 ± 0.2 msec (1974RO31): it decays to neutron unstable states of 11Be [Pn =

  2. A=10Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 10Li) GENERAL: References to articles on general properties of 10Li published since the previous review (1988AJ01) are grouped into...

  3. A=5Li (2002TI10)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2002TI10) (See Energy Level Diagrams for 5Li) GENERAL: References to articles on general properties of 5Li published since the previous review (1988AJ01) are grouped into...

  4. A=9Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004TI06) (See Energy Level Diagrams for 9Li) GENERAL: References to articles on general properties of 9Li published since the previous review (1988AJ01) are grouped into...

  5. Construction Consultants, L.I., Inc.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Eric Baumack Senior Project Manager Construction Consultants L.I., Inc. 36 East 2 nd ... to Construction Consultants L.I., Inc. (CCLI) at the Brookhaven National Laboratory (BNL). ...

  6. Ying Li | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ying Li Margaret Butler Postdoctoral Fellow Ying Li Argonne National Laboratory 9700 S. Cass Avenue Building 240 Wkstn. 1D21 Argonne, IL 60439 630-252-3394 yingli...

  7. Alternating magnetic anisotropy of Li2(Li1xTx)N (T = Mn, Fe, Co, and Ni)

    SciTech Connect (OSTI)

    Jesche, A.; Ke, L.; Jacobs, J. L.; Harmon, B.; Houk, R. S.; Canfield, P. C.

    2015-05-11

    Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li2(Li1xTx)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with magnitudes significantly exceeding the spin-only value. The additional contributions stem from unquenched orbital moments that lead to rare-earth-like behavior of the magnetic properties. Accordingly, extremely large magnetic anisotropies have been found. Most notably, the magnetic anisotropy alternates as easy plane?easy axis?easy plane?easy axis when progressing from T = Mn ? Fe ? Co ? Ni. This behavior can be understood based on a perturbation approach in an analytical, single-ion model. As a result, the calculated magnetic anisotropies show surprisingly good agreement with the experiment and capture the basic features observed for the different transition metals.

  8. Earth sheltered structures

    SciTech Connect (OSTI)

    Boyer, L.L.

    1982-01-01

    The earth shelter concept has been utilized successfully around the world for thousands of years, but its use with contemporary mechanically conditioned buildings dates only from the oil embargo of the mid-1970s. This is an architectural innovation and a growing and viable response to the energy imperative. Most of the technical problems of earth shelters have been effectively addressed, but a systems design approach could further enhance overall energy savings. Although occupant lifestyle seems to be at a high level, areas that require further attention include site design, daylighting, and refined thermal design. The proper integration of passive solar heating and disaster protection represent opportunities for improved multifunctional aspects. With proper design, annual heating and cooling energy use reductions on the order of 80% can be anticipated. Research on energy design refinements and occupancy aspects necessary to achieve such levels of savings is presently under way at Oklahoma State University, the University of Minnesota, and other study centers throughout the nation and the world.

  9. Jennifer Li | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jennifer Garson About Us Jennifer Garson - Tech to Market Analyst, Commercialization Program (EERE) Most Recent Hyliion Wins 2015 National Clean Energy Business Plan Competition, Cleantech University Prize Awardees Announced June 25 REEcyle Takes the Gold in the 2014 National Clean Energy Business Plan Competition June 12 Vote for People's Choice Award! June 6

    Jennifer Li Jennifer Li Jennifer Li E-mail: jennifer.li

  10. A=20Li (1998TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1998TI06) (Not observed) See (1977CE05, 1983ANZQ, 1986AN07, 1987SIZX).

  11. Geoengineering the Earth's Climate

    ScienceCinema (OSTI)

    Google Tech Talks

    2009-09-01

    Emergency preparedness is generally considered to be a good thing, yet there is no plan regarding what we might do should we be faced with a climate emergency. Such an emergency could take the form of a rapid shift in precipitation patterns, a collapse of the great ice sheets, the imminent triggering of strong climate system feedbacks, or perhaps the loss of valuable ecosystems. Over the past decade, we have used climate models to investigate the potential to reverse some of the effects of greenhouse gases in the atmosphere by deflecting some incoming sunlight back to space. This would probably be most cost-effectively achieved with the placement of small particles in or above the stratosphere. Our model simulations indicate that such geoengineering approaches could potentially bring our climate closer to the state is was in prior to the introduction of greenhouse gases. This talk will present much of what is known about such geoengineering approaches, and raise a range of issues likely to stimulate lively discussion. Speaker: Ken Caldeira Ken Caldeira is a scientist at the Carnegie Institution Department of Global Ecology and a Professor (by courtesy) at the Stanford University Department of Environmental and Earth System Sciences. Previously, he worked for 12 years in the Energy and Environment Directorate at the Lawrence Livermore National Laboratory (Department of Energy). His research interests include the numerical simulation of Earth's climate, carbon, and biogeochemistry; ocean acidification; climate emergency response systems; evaluating approaches to supplying environmentally-friendly energy services; ocean carbon sequestration; long-term evolution of climate and geochemical cycles; and marine biogeochemical cycles. Caldeira has a B.A. in Philosophy from Rutgers College and an M.S. and Ph.D. in Atmospheric Sciences from New York University.

  12. A=11Li (1975AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by GeV protons. Its mass excess is 40.9 0.1 MeV (1973KL1C). 11Li is bound: Eb for breakup into 9Li + 2n and 10Li + n are 0.2 and 0.3 MeV, respectively see (1974AJ01) for a...

  13. A=13Li (1976AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13Li is predicted to have an atomic mass excess of 61.56 MeV: it is then unstable for breakup into 12Li + n and 11Li + 2n by 0.6 and 4.5 MeV, respectively (1974TH01). The modified...

  14. A=13Li (1981AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13Li is predicted to have an atomic mass excess of 61.56 MeV: it is then unstable for breakup into 12Li + n and 11Li + 2n by 0.6 and 4.5 MeV, respectively (1974TH01). The modified...

  15. A=14Li (1976AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    76AJ04) (Not illustrated) 14Li has not been observed: it is calculated to be particle unstable with a binding energy of -2.66 MeV for decay into 13Li + n and of -3.23 MeV for decay into 12Li + 2n. The calculated mass excess is 72.29 MeV (1974TH01)

  16. A=15Li (1976AJ04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    76AJ04) (Not illustrated) 15Li has not been observed: its atomic mass excess is calculated to be 81.60 MeV. It is then unstable with respect to decay into 14Li + n and 13Li + 2n by 1.24 and 3.90 MeV, respectively (1974TH01)

  17. A=15Li (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6AJ01) (Not illustrated) 15Li has not been observed. Its atomic mass excess is calculated to be 81.60 MeV: see (1981AJ01). It is then unstable with respect to decay into 14Li + n and 13Li + 2n by 1.24 and 3.90 MeV, repsectively

  18. A=8Li (2004TI06)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p)8Li Qm 0.80079 Angular distributions have been obtained at Et 23 MeV for the proton groups to 8Li*(0, 0.98, 2.26, 6.54 0.03); cm for 8Li*(2.26, 6.54) are 35 10 and 35...

  19. A=8Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the geometric value, supports the hypothesis that 7Li may be described as an ( + t) cluster (RO62C). See also (AL63N, BA63O, BR63M, VA64G). 9. 7Li(d, p)8Li Qm -0.192...

  20. Recovery of Li from alloys of Al-Li and Li-Al using engineered scavenger compounds

    SciTech Connect (OSTI)

    Riley, W.D.; Jong, B.W.; Collins, W.K.; Gerdemann, S.J.

    1992-01-01

    The invention relates to a process for obtaining Li metal selectively recovered from Li-Al or Al-Li alloy scrap by: (1) removing Li from aluminum-lithium alloys at temperatures between about 400 C-750 C in a molten salt bath of KC1-LiCl using lithium titanate (Li2O.3TiO2) as an engineered scavenger compound (ESC); and (2) electrodepositing of Li from the loaded ESC to a stainless steel electrode. By use of the second step, the ESC is prepared for reuse. A molten salt bath is required in the invention because of the inability of molten aluminum alloys to wet the ESC.

  1. HOW THERMAL EVOLUTION AND MASS-LOSS SCULPT POPULATIONS OF SUPER-EARTHS AND SUB-NEPTUNES: APPLICATION TO THE KEPLER-11 SYSTEM AND BEYOND

    SciTech Connect (OSTI)

    Lopez, Eric D.; Miller, Neil; Fortney, Jonathan J. [Department of Astronomy and Astrophysics, University of California, Santa Cruz, CA 95064 (United States)

    2012-12-10

    We use models of thermal evolution and extreme ultraviolet (XUV) driven mass loss to explore the composition and history of low-mass, low-density transiting planets. We investigate the Kepler-11 system in detail and provide estimates of both the current and past planetary compositions. We find that an H/He envelope on Kepler-11b is highly vulnerable to mass loss. By comparing to formation models, we show that in situ formation of the system is extremely difficult. Instead we propose that it is a water-rich system of sub-Neptunes that migrated from beyond the snow line. For the broader population of observed planets, we show that there is a threshold in bulk planet density and incident flux above which no low-mass transiting planets have been observed. We suggest that this threshold is due to the instability of H/He envelopes to XUV-driven mass loss. Importantly, we find that this mass-loss threshold is well reproduced by our thermal evolution/contraction models that incorporate a standard mass-loss prescription. Treating the planets' contraction history is essential because the planets have significantly larger radii during the early era of high XUV fluxes. Over time low-mass planets with H/He envelopes can be transformed into water-dominated worlds with steam envelopes or rocky super-Earths. Finally, we use this threshold to provide likely minimum masses and radial-velocity amplitudes for the general population of Kepler candidates. Likewise, we use this threshold to provide constraints on the maximum radii of low-mass planets found by radial-velocity surveys.

  2. A=12Li (1985AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5AJ01) (Not illustrated) 12Li is not observed in the 4.8 GeV proton bombardment of a uranium target: it is particle-unstable. The calculated value of its mass excess is 52.93 MeV [see (1980AJ01)]: 12Li would then be unstable with respect to 11Li + n, 10Li + 2n and 9Li + 3n by 3.92, 2.96 and 3.76 MeV, respectively. See also (1980AJ01) and (1982KA1D, 1983ANZQ, 1984VA06

  3. A=13Li (1986AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    86AJ01) (Not illustrated) 13Li has not been observed. The calculated value of its mass excess is 60.34 MeV [see (1981AJ01)]: 13Li would then be unstable with respect to 11Li + 2n by 3.26 MeV. (1980BO31) have not observed 13Li in the bombardment of 124Sn by 6.7 GeV protons but state that the statistics were poor in the region of interest and that it is not excluded that 13Li may be stable. See also (1983ANZQ

  4. A=11Li (1985AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5AJ01) (See the Isobar Diagram for 11Li) GENERAL: The mass excess of 11Li is 40.94 ± 0.08 MeV (1975TH08). [(A.H. Wapstra, private communication) suggests 40.91 ± 0.11 MeV.] Using the value reported by (1975TH08) 11Li is bound with respect to 9Li + 2n by 156 ± 80 keV and with respect to 10Li + n by 966 ± 260 keV [see (1984AJ01) for the masses of 9Li and 10Li]. Systematics suggest Jπ = 1/2- for 11Lig.s.. See also (1979AZ03, 1980AZ01, 1980BO31, 1981BO1X, 1982BO1Y, 1982OG02), (1981HA2C),

  5. A=9Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    59AJ76) (Not illustrated) Mass of 9Li: From the threshold for 9Be(d, 2p)9Li, Ed = 19 ± 1 MeV (GA51C), the mass excess of 9Li is determined as M - A = 28.1 ± 1 MeV. 1. 9Li(β-)9Be* --> 8Be + n Qm = 12.4 9Li decays to excited states of 9Be which decay by neutron emission. The mean of the reported half-lives is 0.169 ± 0.003 sec (GA51C, HO52B). See also (SH52, FR53A, BE55D, FL56, TA58B). 2. 9Be(d, 2p)9Li Qm = -15.5 The threshold is 19 ± 1 MeV (GA51C). 3. 11B(γ, 2p)9Li Qm = -31.4 See (SH52,

  6. Holding Mother Earth Sacred

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Holding Mother Earth Sacred Photo Journal Project Resource List 2010 Mountain and Plains Education and Research ... (NIOSH): www.cdc.govniosh American Industrial Hygiene ...

  7. li(1)-98.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23 Radiative Forcing by Smoke Aerosols Determined from Satellite and Surface Measurements Z. Li Canada Centre for Remote Sensing Ottawa, Ontario, Canada L. Kou Intermap Technologies Ottawa, Ontario, Canada Introduction As a potential offsetting agent to the greenhouse effect, aerosols are receiving increasing attention in the atmospheric science community. Notwithstanding, our knowledge of the impact of aerosols on radiation and climate is rather poor and falls well behind that of the greenhouse

  8. li(1)-99.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Consistency Check of Cloud Optical Properties Derived from Satellite and Surface Observations Z. Li, A. P. Trishchenko, and F.-L. Chang Canada Center for Remote Sensing Ottawa, Canada H. W. Barker Atmospheric Environmental Service Downsview, Canada W. B. Sun Dalhousie University Halifax, Nova Scotia, Canada Introduction Much work has been done to retrieve both cloud and radiative variables using space-borne observations. Several recent studies also attempted to retrieve cloud optical depth using

  9. Crystal structure and chemical bonding of novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16}

    SciTech Connect (OSTI)

    Jung, Yaho; Nam, Gnu; Jeon, Jieun; Kim, Youngjo; You, Tae-Soo

    2012-12-15

    A novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16} has been synthesized using the high-temperature reaction method and characterized by both powder and single-crystal X-ray diffractions. The title compound crystallized in the orthorhombic crystal system (space group Immm, Z=2, Pearson symbol oI78) with fifteen crystallographically unique atomic positions in the asymmetric unit, and the lattice parameters are refined as a=4.5244(4) A, b=6.9932(6) A, and c=53.043(5) A. The complex crystal structure of the title compound can be described as a 2:1 intergrowth of two closely related compounds: La{sub 2}Li{sub 2}Ge{sub 3} (Ce{sub 2}Li{sub 2}Ge{sub 3}-type) and La{sub 3}Li{sub 4}Ge{sub 4} (Zr{sub 3}Cu{sub 4}Si{sub 4}-type) acting like 'building-blocks' along the c-axis. Six La sites are categorized into three distinct types based on the local coordination environment showing the coordination numbers of 12-14. Three unique Li sites are placed in the centers of local tetrahedra formed by four Ge atoms which eventually construct Ge{sub 2} dimers or 1-dimensional cis-/trans-Ge chains. Theoretical investigations using the tight-binding linear muffin-tin orbital (LMTO) method provide rationales for an improved structural stability and for unique local coordination geometries established by anionic elements including [LiGe{sub 4}] tetrahedra, cis-/trans-Ge chain and Ge{sub 2} dimers. - Graphical abstract: Reported is a novel ternary Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16}. The complex crystal structure can be viewed as a simple combination of two closely related known compounds acting as 'building-blocks', La{sub 2}Li{sub 2}G{sub 3} and La{sub 3}Li{sub 4}Ge{sub 4}, in a 2:1 stoichiometric ratio. Highlights: Black-Right-Pointing-Pointer A novel Li-containing polar intermetallic compound La{sub 11}Li{sub 12}Ge{sub 16} was synthesized. Black-Right-Pointing-Pointer The complex crystal structure was easily explained as a combination of two known compounds. Black-Right-Pointing-Pointer Theoretical calculations indicated that the Fermi level was located near the pseudogap.

  10. Phase transitions of LiAlO{sub 2} at high pressure and high temperature

    SciTech Connect (OSTI)

    Lei Li; He Duanwei Zou Yongtao; Zhang Wei; Wang Zhao; Jiang Ming; Du Maolu

    2008-08-15

    This work presents a comprehensive study on phase transitions in LiAlO{sub 2} system at high pressures and temperatures (0.5-5.0 GPa and 300-1873 K, respectively), as well as the phase stability for polymeric phases of LiAlO{sub 2} in the studied P-T space by X-ray diffraction (XRD). Besides the previously described polymorphic hexagonal {alpha}-phase, orthorhombic {beta}-phase and tetragonal {delta}-phase, a possible new phase of LiAlO{sub 2} was observed after the tetragonal {gamma}-LiAlO{sub 2} sample was treated at 5.0 GPa and 389 K. The stable regimes of these high-pressure phases were defined through the observation of coexistence points of the polymeric phases. Our results revealed that LiAlO{sub 2} could experience structural phase transitions from {gamma}-LiAlO{sub 2} to its polymorphs at lower pressures and temperatures compared to the reported results. Hexagonal {alpha}-LiAlO{sub 2} with highly (003) preferential orientation was prepared at 5.0 GPa and 1873 K. - Graphical abstract: Constructing the pressure-temperature phase diagram for LiAlO{sub 2}.

  11. Fusion reactions in collisions induced by Li isotopes on Sn targets

    SciTech Connect (OSTI)

    Fisichella, M.; Shotter, A. C.; Di Pietro, A.; Figuera, P.; Lattuada, M.; Marchetta, C.; Musumarra, A.; Pellegriti, M. G.; Ruiz, C.; Scuderi, V.; Strano, E.; Torresi, D.; Zadro, M.

    2012-10-20

    Fusion cross sections for the {sup 6}Li+{sup 120}Sn and {sup 7}Li+{sup 119}Sn systems have been measured. We aim to search for possible effects due to the different neutron transfer Q-values, by comparing the fusion cross sections for the two systems below the barrier. This experiment is the first step of a wider systematic aiming to study the above problems in collisions induced by stable and unstable Li isotopes on tin all forming the same compound nucleus.

  12. Improvement in Clouds and the Earth's Radiant Energy System/Surface and Atmosphere Radiation Budget Dust Aerosol Properties, Effects on Surface Validation of Clouds and Radiative Swath

    SciTech Connect (OSTI)

    Rutan, D.; Rose, F.; Charlock, T.P.

    2005-03-18

    Within the Clouds and the Earth's Radiant Energy System (CERES) science team (Wielicki et al. 1996), the Surface and Atmospheric Radiation Budget (SARB) group is tasked with calculating vertical profiles of heating rates, globally, and continuously, beneath CERES footprint observations of Top of Atmosphere (TOA) fluxes. This is accomplished using a fast radiative transfer code originally developed by Qiang Fu and Kuo-Nan Liou (Fu and Liou 1993) and subsequently highly modified by the SARB team. Details on the code and its inputs can be found in Kato et al. (2005) and Rose and Charlock (2002). Among the many required inputs is characterization of the vertical column profile of aerosols beneath each footprint. To do this SARB combines aerosol optical depth information from the moderate-resolution imaging spectroradiometer (MODIS) instrument along with aerosol constituents specified by the Model for Atmosphere and Chemical Transport (MATCH) of Collins et al. (2001), and aerosol properties (e.g. single scatter albedo and asymmetry parameter) from Tegen and Lacis (1996) and OPAC (Hess et al. 1998). The publicly available files that include these flux profiles, called the Clouds and Radiative Swath (CRS) data product, available from the Langley Atmospheric Sciences Data Center (http://eosweb.larc.nasa.gov/). As various versions of the code are completed, publishable results are named ''Editions.'' After CRS Edition 2A was finalized it was found that dust aerosols were too absorptive. Dust aerosols have subsequently been modified using a new set of properties developed by Andy Lacis and results have been released in CRS Edition 2B. This paper discusses the effects of changing desert dust aerosol properties, which can be significant for the radiation budget in mid ocean, a few thousand kilometers from the source regions. Resulting changes are validated via comparison of surface observed fluxes from the Saudi Solar Village surface site (Myers et al. 1999), and the E13 site at the Atmospheric Radiation Measurement (ARM), Southern Great Plains (SGP) central facility.

  13. From land use to land cover: Restoring the afforestation signal in a coupled integrated assessment - earth system model and the implications for CMIP5 RCP simulations

    SciTech Connect (OSTI)

    Di Vittorio, Alan; Chini, Louise M.; Bond-Lamberty, Benjamin; Mao, Jiafu; Shi, Xiaoying; Truesdale, John E.; Craig, Anthony P.; Calvin, Katherine V.; Jones, Andrew D.; Collins, William D.; Edmonds, James A.; Hurtt, George; Thornton, Peter E.; Thomson, Allison M.

    2014-11-27

    Climate projections depend on scenarios of fossil fuel emissions and land use change, and the IPCC AR5 parallel process assumes consistent climate scenarios across Integrated Assessment and Earth System Models (IAMs and ESMs). To facilitate consistency, CMIP5 used a novel land use harmonization to provide ESMs with seamless, 1500-2100 land use trajectories generated by historical data and four IAMs. However, we have identified and partially addressed a major gap in the CMIP5 land coupling design. The CMIP5 Community ESM (CESM) global afforestation is only 22% of RCP4.5 afforestation from 2005 to 2100. Likewise, only 17% of the Global Change Assessment Models (GCAMs) 2040 RCP4.5 afforestation signal, and none of the pasture loss, were transmitted to CESM within a newly integrated model. This is a critical problem because afforestation is necessary for achieving the RCP4.5 climate stabilization. We attempted to rectify this problem by modifying only the ESM component of the integrated model, enabling CESM to simulate 66% of GCAMs afforestation in 2040, and 94% of GCAMs pasture loss as grassland and shrubland losses. This additional afforestation increases vegetation carbon gain by 19 PgC and decreases atmospheric CO2 gain by 8 ppmv from 2005 to 2040, implying different climate scenarios between CMIP5 GCAM and CESM. Similar inconsistencies likely exist in other CMIP5 model results, primarily because land cover information is not shared between models, with possible contributions from afforestation exceeding model-specific, potentially viable forest area. Further work to harmonize land cover among models will be required to adequately rectify this problem.

  14. Earth and Environmental Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EES Division Earth and Environmental Sciences We provide solutions to complex problems in climate and environmental change, sustainable energy, and national security. Climate Science Monitoring and studying dynamics between Earth, ecosystems, the atmosphere and climate Sustainable Energy Capturing carbon and researching cleaner, more efficient energy sources Global Security Detecting and predicting threats such as wildfires, earthquakes, and nuclear detonations Repository Science Geoscience,

  15. Cool Earth Solar

    ScienceCinema (OSTI)

    Lamkin, Rob; McIlroy, Andy; Swalwell, Eric; Rajan, Kish

    2014-02-26

    In a public-private partnership that takes full advantage of the Livermore Valley Open Campus (LVOC) for the first time, Sandia National Laboratories and Cool Earth Solar have signed an agreement that could make solar energy more affordable and accessible. In this piece, representatives from Sandia, Cool Earth Solar, and leaders in California government all discuss the unique partnership and its expected impact.

  16. A=12Li (1980AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0AJ01) (Not illustrated) 12Li is not observed in the 4.8 GeV proton bombardment of a uranium target: it is particle unstable. Its atomic mass excess would then be > 49.0 MeV. (1974TH01) calculate the mass excess of 12Li to be 52.92 MeV, while (1975JE02) calculate 52.94 MeV. Taking the average of these two values, 12Li would then be unstable with respect to 11Li + n, 10Li + 2n and 9Li + 3n by 3.92, 2.96 and 3.76 MeV, respectively. See also (1975AJ02) and (1975BE31, 1976IR1B

  17. A=14Li (1991AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    91AJ01) (Not illustrated) 14Li has not been observed. The calculated mass excess is 72.29 MeV: see (1981AJ01). 14Li is then particle unstable with respect to decay into 13Li + n and 12Li + 2n by 3.9 and 3.2 MeV, respectively [see, however, 13Li]. (1985PO10) calculate [in a (0 + 1)ℏω model space] that the first four states of 14Li at 0, 0.75, 1.22 and 1.48 MeV have, respectively, Jπ = 2-, 4-, 3- and 1-. See also (1986AL09, 1989OG1B) and (1988POZS; theor.)

  18. Method of gas purification and system therefor

    DOE Patents [OSTI]

    Szwarc, R.

    1983-12-29

    A method and device are disclosed for conducting gettering. The gettering is conducted with one of an LiB, LiSi or LiAl system. Preferably the LiB system is of the formula Li/sub x/B/sub 1-x/ wherein 0 < x < 1 with gettering conducted at room or slightly elevated temperature of about 100 to 200/sup 0/C.

  19. Local field effects at Li K edges in electron energy-loss spectra of Li, Li{sub 2}O and LiF

    SciTech Connect (OSTI)

    Mauchamp, V.; Moreau, P.; Ouvrard, G.; Boucher, F.

    2008-01-15

    Local field effects (LFEs) in low-losses of electron energy-loss spectra of Li, Li{sub 2}O, and LiF were calculated using the density functional theory under the generalized gradient approximation. By including the lithium 1s semicore state in the pseudopotentials, the amplitude of LFE was assessed all the way up to the Li K edge (from 0 to 80 eV). They are found to be much larger for semicore levels (2s of oxygen, 2s of fluorine, and 1s of lithium) than for the valence electron energy-loss region. LFEs at the Li K edge are studied in detail. In particular, for q=0 they are shown to increase with the inhomogeneities of the compounds (from Li to LiF). The influence of the magnitude and the direction of q is also presented. Both parameters have negligible effect in the case of Li metal but changes are quite substantial for Li{sub 2}O and LiF. This is in agreement with the isotropy and the delocalization of the metallic bonding as compared to the ionic one. LFEs at the Li K edge are, however, whatever the compound, much smaller than those observed at transition metal M{sub 2,3} edges situated at similar energy positions. This result can be accounted for by considering the wave functions associated with the initial and final states involved in both edges. For lithium battery materials, most often presenting a transition metal edge close to the Li K edge, these findings imply significant consequences with respect to the interpretation of their electron energy-loss spectroscopy spectra. In particular, LFE can be expected to be stronger in positive electrodes than in negative ones.

  20. Li-rich anti-perovskite Li3OCl films with enhanced ionic conductivity

    SciTech Connect (OSTI)

    Lu, XJ; Wu, G; Howard, JW; Chen, AP; Zhao, YS; Daemen, LL; Jia, QX

    2014-08-13

    Anti-perovskite solid electrolyte films were prepared by pulsed laser deposition, and their room-temperature ionic conductivity can be improved by more than an order of magnitude in comparison with its bulk counterpart. The cyclability of Li3OCl films in contact with lithium was evaluated using a Li/Li3OCl/Li symmetric cell, showing self-stabilization during cycling test.

  1. A=16Li (1993TI07)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li (1993TI07) (Not illustrated) This nucleus has not been observed. Shell model studies (1988POZS) are used to predict J and the magnetic dipole moment....

  2. Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries

    SciTech Connect (OSTI)

    Jaiswal, A.; Horne, C.R.; Chang, O.; Zhang, W.; Kong, W.; Wang, E.; Chern, T.; Doeff, M. M.

    2009-08-04

    The electrochemical performances of nanoscale LiFePO4 and Li4Ti5O12 materials are described in this communication. The nanomaterials were synthesized by pyrolysis of an aerosol precursor. Both compositions required moderate heat-treatment to become electrochemically active. LiFePO4 nanoparticles were coated with a uniform, 2-4 nm thick carbon-coating using an organic precursor in the heat treatment step and showed high tap density of 1.24 g/cm3, in spite of 50-100 nm particle size and 2.9 wtpercent carbon content. Li4Ti5O12 nanoparticles were between 50-200 nm in size and showed tap density of 0.8 g/cm3. The nanomaterials were tested both in half cell configurations against Li-metal and also in LiFePO4/Li4Ti5O12 full cells. Nano-LiFePO4 showed high discharge rate capability with values of 150 and 138 mAh/g at C/25 and 5C, respectively, after constant C/25 charges. Nano-Li4Ti5O12 also showed high charge capability with values of 148 and 138 mAh/g at C/25 and 5C, respectively, after constant C/25 discharges; the discharge (lithiation) capability was comparatively slower. LiFePO4/Li4Ti5O12 full cells deliver charge/discharge capacity values of 150 and 122 mAh/g at C/5 and 5C, respectively.

  3. Method for treating rare earth-transition metal scrap

    DOE Patents [OSTI]

    Schmidt, F.A.; Peterson, D.T.; Wheelock, J.T.; Jones, L.L.

    1992-12-29

    Rare earth-transition metal (e.g., iron) scrap (e.g., Nd-Fe-B scrap) is flux (slag) remelted to reduce tramp non-metallic impurities, such as oxygen and nitrogen, and metallic impurities, such as Li, Na, Al, etc., picked up by the scrap from previous fabrication operations. The tramp impurities are reduced to concentrations acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. The scrap is electroslag or inductoslag melted using a rare earth fluoride-bearing flux of CaF[sub 2], CaCl[sub 2] or mixtures thereof or the slag resulting from practice of the thermite reduction process to make a rare earth-iron alloy. 3 figs.

  4. Method for treating rare earth-transition metal scrap

    DOE Patents [OSTI]

    Schmidt, Frederick A.; Peterson, David T.; Wheelock, John T.; Jones, Lawrence L.

    1992-12-29

    Rare earth-transition metal (e.g., iron) scrap (e.g., Nd-Fe-B scrap) is flux (slag) remelted to reduce tramp non-metallic impurities, such as oxygen and nitrogen, and metallic impurities, such as Li, Na, Al, etc., picked up by the scrap from previous fabrication operations. The tramp impurities are reduced to concentrations acceptable for reuse of the treated alloy in the manufacture of end-use articles, such as permanent magnets. The scrap is electroslag or inductoslag melted using a prefused, rare earth fluoride-bearing flux of CaF.sub.2, CaCl.sub.2 or mixtures thereof or the slag resulting from practice of the thermite reduction process to make a rare earth-iron alloy.

  5. Rare earth gas laser

    DOE Patents [OSTI]

    Krupke, W.F.

    1975-10-31

    A high energy gas laser with light output in the infrared or visible region of the spectrum is described. Laser action is obtained by generating vapors of rare earth halides, particularly neodymium iodide or, to a lesser extent, neodymium bromide, and disposing the rare earth vapor medium in a resonant cavity at elevated temperatures; e.g., approximately 1200/sup 0/ to 1400/sup 0/K. A particularly preferred gaseous medium is one involving a complex of aluminum chloride and neodymium chloride, which exhibits tremendously enhanced vapor pressure compared to the rare earth halides per se, and provides comparable increases in stored energy densities.

  6. Antiperovskite Li 3 OCl superionic conductor films for solid...

    Office of Scientific and Technical Information (OSTI)

    Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries Citation Details In-Document Search Title: Antiperovskite Li 3 OCl superionic conductor films ...

  7. LI

    Office of Legacy Management (LM)

    Submlt invoices to8 United State8 Atomic Energy Commission, P. 0. Box 30, Anaonia Station, New York 23, New Yorir j . . CONTRACT NO. AT(30-1).1335, Mod. No. 4 THIS SUPPLEXENTAL ...

  8. LANL Studies Earth's Magnetosphere

    ScienceCinema (OSTI)

    Daughton, Bill

    2014-08-12

    A new 3-D supercomputer model presents a new theory of how magnetic reconnection works in high-temperature plasmas. This Los Alamos National Laboratory research supports an upcoming NASA mission to study Earth's magnetosphere in greater detail than ever.

  9. Lab celebrates Earth Day

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lab celebrates Earth Day Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue:May 2016 all issues All Issues » submit Lab celebrates Earth Day Multiple activities focus on environmental protection. May 1, 2013 A team from Industrial Hygiene and Safety during the Great Garbage Grab A team from Industrial Hygiene and Safety during the Great Garbage Grab. Contact Editor Linda Anderman Email Community Programs Office Kurt Steinhaus Email Great

  10. optimal initial conditions for coupling ice sheet models to earth...

    Office of Scientific and Technical Information (OSTI)

    optimal initial conditions for coupling ice sheet models to earth system models Perego, Mauro Sandia National Laboratories Sandia National Laboratories; Price, Stephen F. Dr...

  11. A=10Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10B: see (HA68V), the mass excess of 10Li, (M - A) 33.10 0.06 MeV (AB73D). The breakup energy into 9Li + n is then -0.06 0.06 MeV. Using the calculated values suggested...

  12. A=6Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p)6Li Qm -4.004 See (CH58D). 3. 4He(d, )6Li Qm 1.471 An upper limit for capture radiation at Ed 1.055 MeV (2.18-MeV state) is 0.1 mb (SI54). A search for resonant...

  13. A=11Li (68AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    68AJ02) (See the Isobar Diagram for 11Li) 11Li has been identified in the 5.3 GeV proton bombardment of uranium. It is particle stable (PO66H). See also (GA66C, CO67A

  14. A=9Li (1979AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.3 2.9 keV for the second T 32 state in A 9 (1975KA18). 1. 9Li(-)9Be Qm 13.607 The half-life of 9Li is 178.3 0.4 msec (1976AL02). Other recent values are 175 1...

  15. A=8Li (1988AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nuclear radius of 8Li is 2.36 0.02 fm (1985TA18) see also for derived nuclear matter, charge and neutron matter r.m.s. radii. 1. 8Li(-)8Be Qm 16.0039 The - decay is...

  16. A=8Li (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    one event corresponding to the transition to an excited state at 0.7 0.2 MeV. 3. 7Li(n, )8Li Qm 2.035 The thermal capture cross section is 33 5 mb (HU47A), 42 10 mb...

  17. Cluster-continuum quantum mechanical models to guide the choice of anions for Li{sup +}-conducting ionomers

    SciTech Connect (OSTI)

    Shiau, Huai-Suen; Janik, Michael J.; Liu, Wenjuan; Colby, Ralph H.

    2013-11-28

    A quantum-mechanical investigation on Li poly(ethylene oxide)-based ionomers was performed in the cluster-continuum solvation model (CCM) that includes specific solvation in the first shell surrounding the cation, all surrounded by a polarizable continuum. A four-state model, including a free Li cation, Li{sup +}-anion pair, triple ion, and quadrupole was used to represent the states of Li{sup +} within the ionomer in the CCM. The relative energy of each state was calculated for Li{sup +} with various anions, with dimethyl ether representing the ether oxygen solvation. The population distribution of Li{sup +} ions among states was estimated by applying Boltzmann statistics to the CCM energies. Entropy difference estimates are needed for populations to better match the true ionomer system. The total entropy change is considered to consist of four contributions: translational, rotational, electrostatic, and solvent immobilization entropies. The population of ion states is reported as a function of Bjerrum length divided by ion-pair separation with/without entropy considered to investigate the transition between states. Predicted concentrations of Li{sup +}-conducting states (free Li{sup +} and positive triple ions) are compared among a series of anions to indicate favorable features for design of an optimal Li{sup +}-conducting ionomer; the perfluorotetraphenylborate anion maximizes the conducting positive triple ion population among the series of anions considered.

  18. Atsun Solar Electric Technology Co Ang Li Tiansheng | Open Energy...

    Open Energy Info (EERE)

    Co (Ang Li Tiansheng) Place: Zaozhuang, Shandong Province, China Product: Chinese PV cell and module maker. References: Atsun Solar Electric Technology Co (Ang Li...

  19. Enabling Future Li-Ion Battery Recycling | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Future Li-Ion Battery Recycling Title Enabling Future Li-Ion Battery Recycling Publication Type Presentation Year of Publication 2014 Authors Gaines, LL Abstract Presentation made...

  20. Predictive Models of Li-ion Battery Lifetime (Presentation) ...

    Office of Scientific and Technical Information (OSTI)

    Predictive Models of Li-ion Battery Lifetime (Presentation) Citation Details In-Document Search Title: Predictive Models of Li-ion Battery Lifetime (Presentation) You are ...

  1. Investigation of critical parameters in Li-ion battery electrodes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    critical parameters in Li-ion battery electrodes Investigation of critical parameters in Li-ion battery electrodes 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle ...

  2. Key Parameters Governing the Energy Density of Rechargeable Li...

    Office of Scientific and Technical Information (OSTI)

    of Rechargeable LiS Batteries Citation Details In-Document Search Title: Key Parameters Governing the Energy Density of Rechargeable LiS Batteries Authors: Gao, Jie ; ...

  3. Electrode Materials for Rechargeable Li-ion Batteries: a New...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrode Materials for Rechargeable Li-ion Batteries: a New Synthetic Approach ... multiple cycles which enables Li-ion batteries with exceptionally high-power.

    This ...

  4. Correlation of anisotropy and directional conduction in β-Li3PS4 fast Li+ conductor

    SciTech Connect (OSTI)

    Chen, Yan; Cai, Lu; Liu, Zengcai; dela Cruz, Clarina R.; Liang, Chengdu; An, Ke

    2015-07-06

    Our letter reports the correlation of anisotropy and directional conduction in the fast Li+ conductor β-Li3PS4, one of the low-symmetry crystalline electrolyte candidates. The material has both high conductivity and good stability that serves well for the large-scale energy storage applications of all-solid-state lithium ion batteries. The anisotropic physical properties, demonstrated here by the thermal expansion coefficients, are crucial for compatibility in the solid-state system and battery performance. Neutron and X-ray powder diffraction measurements were done to determine the crystal structure and thermal stability. Moreover, the crystallographic b-axis was revealed as a fast expansion direction, while negligible thermal expansion was observed along the a-axis around the battery operating temperatures. The anisotropic behavior has its structural origin from the Li+ conduction channels with incomplete Li occupancy and a flexible connection of LiS4 and PS4 tetrahedra within the framework. This indicates a strong correlation in the direction of the ionic transport in the low-symmetry Li+ conductor.

  5. Predictive Models of Li-ion Battery Lifetime

    SciTech Connect (OSTI)

    Smith, Kandler; Wood, Eric; Santhanagopalan, Shriram; Kim, Gi-heon; Shi, Ying; Pesaran, Ahmad

    2015-06-15

    It remains an open question how best to predict real-world battery lifetime based on accelerated calendar and cycle aging data from the laboratory. Multiple degradation mechanisms due to (electro)chemical, thermal, and mechanical coupled phenomena influence Li-ion battery lifetime, each with different dependence on time, cycling and thermal environment. The standardization of life predictive models would benefit the industry by reducing test time and streamlining development of system controls.

  6. Good Earths and Rare Earths | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Good Earths and Rare Earths Good Earths and Rare Earths April 20, 2011 - 6:17pm Addthis Charles Rousseaux Charles Rousseaux Senior Communications Specialist (detailee) What does this mean for me? Rare earth elements -- dysprosium, neodymium, terbium, europium and yttrium -- are essential to a wide range of green energy technologies ranging from windmills to electric vehicles One of their primary uses is in permanent magnets, which amount to over a $4 billion global industry Ames Laboratory

  7. Google Earth Tour: Water reuse at LANL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Google Earth Tour: Water reuse at LANL Google Earth Tour: Water reuse at LANL

  8. Earth shelter goes international

    SciTech Connect (OSTI)

    Boyer, L.L.

    1983-06-01

    Since the mid-1970's earth sheltered buildings in the US have become more numerous and important as a contemporary passive building concept. Further, an intense international interest has now developed, as evidenced by a number of important activities. One of these events is the 1983 International Conference on Energy Efficient Buildings with Earth Shelter Protection to be conducted during 1-6 August in Sydney, Australia. A review of past activities leading up to this event, as well as a brief review of the conference program, is the subject of this discussion.

  9. Earth sheltered housing phenomenon

    SciTech Connect (OSTI)

    Boyer, L.L.

    1981-06-21

    Both national and international attention has recently been focused on earth sheltered construction as an emerging energy alternative. This is especially true for the High Plains region of the central United States. Traditionally, inhabitants of this region have been sensitized to the need for windstorm protection. However, the dramatic potentials for energy savings have served as a strong secondary inducement to the burgeoning construction activity in what is now viewed as a contemporary dwelling concept. The typical characteristics of such dwellings are reviewed as well as the educational challenge awaiting professional input to this developing boom in earth sheltered construction. 12 refs.

  10. Li2Se as a Neutron Scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Du, Mao-Hua; Shi, Hongliang; Singh, David J.

    2015-06-23

    We show that Li2Se:Te is a potential neutron scintillator material based on density functional calculations. Li2Se exhibits a number of properties favorable for efficient neutron detection, such as a high Li concentration for neutron absorption, a small effective atomic mass and a low density for reduced sensitivity to background gamma rays, and a small band gap for a high light yield. Our calculations show that Te doping should lead to the formation of deep acceptor complex VLi-TeSe, which can facilitate efficient light emission, similar to the emission activation in Te doped ZnSe.

  11. Efimov physics in {sup 6}Li atoms

    SciTech Connect (OSTI)

    Braaten, Eric; Hammer, H.-W.; Kang, Daekyoung; Platter, Lucas

    2010-01-15

    A new narrow three-atom loss resonance associated with an Efimov trimer crossing the three-atom threshold has recently been discovered in a many-body system of ultracold {sup 6}Li atoms in the three lowest hyperfine spin states at a magnetic field near 895 G. O'Hara and coworkers have used measurements of the three-body recombination rate in this region to determine the complex three-body parameter associated with Efimov physics. Using this parameter as the input, we calculate the universal predictions for the spectrum of Efimov states and for the three-body recombination rate in the universal region above 600 G where all three scattering lengths are large. We predict an atom-dimer loss resonance at 672+-2 G associated with an Efimov trimer disappearing through an atom-dimer threshold. We also predict an interference minimum in the three-body recombination rate at 759+-1 G where the three-spin mixture may be sufficiently stable to allow experimental study of the many-body system.

  12. Diagnosis of the Marine Low Cloud Simulation in the NCAR Community Earth System Model (CESM) and the NCEP Global Forecast System (GFS)-Modular Ocean Model v4 (MOM4) coupled model

    SciTech Connect (OSTI)

    Xiao, Heng; Mechoso, C. R.; Sun, Rui; Han, J.; Pan, H. L.; Park, S.; Hannay, Cecile; Bretherton, Christopher S.; Teixeira, J.

    2014-07-25

    We present a diagnostic analysis of the marine low cloud climatology simulated by two state-of-the-art coupled atmosphere-ocean models: the NCAR Community Earth System Model (CESM) and the NCEP Global Forecasting System (GFS). In both models, the shallow convection and boundary layer turbulence parameterizations have been recently updated: both models now use a mass-flux scheme for the parameterization of shallow convection, and a turbulence parameterization capable of handling Stratocumulus (Sc)-topped Planetary Boundary Layers (PBLs). For shallow convection, both models employ a convective trigger function based on the concept of convective inhibition and both include explicit convective overshooting/penetrative entrainment formulation. For Sc-topped PBL, both models treat explicitly turbulence mixing and cloud-top entrainment driven by cloud-top radiative cooling. Our focus is on the climatological transition from Sc to shallow Cumulus (Cu)-topped PBL in the subtropical eastern oceans. We show that in the CESM the coastal Sc-topped PBLs in the subtropical Eastern Pacific are well-simulated but the climatological transition from Sc to shallow Cu is too abrupt and happens too close to the coast. By contrast, in the GFS coupled simulation the coastal Sc amount and PBL depth are severely underestimated while the transition from Sc to shallow Cu is delayed and offshore Sc cover is too extensive in the subtropical Eastern Pacific. We discuss the possible connections between such differences in the simulations and differences in the parameterizations of shallow convection and boundary layer turbulence in the two models.

  13. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lü, Xujie; Howard, John W.; Chen, Aiping; Zhu, Jinlong; Li, Shuai; Wu, Gang; Dowden, Paul; Xu, Hongwu; Zhao, Yusheng; Jia, Quanxi

    2016-02-02

    We prepared antiperovskite Li3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10-4 S cm-1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li3OCl as a solid electrolyte for Li-ion batteries is demonstrated.

  14. A=4Li (1992TI02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    experiments (1990BR14, 1990BR17) that detect 4Li states in the particle spectra of breakup reactions. It may even be possible that these experiments are not detecting the 2-and...

  15. A=11Li (1990AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    increase in matter radii with increasing A and do not support the idea of a neutron halo in 11Li (1988POZS; prelim.). See, however, (1988TA1A). Fragmentation cross sections of...

  16. A=13Li (1991AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    91AJ01) (Not illustrated) 13Li has not been observed: see (1986AJ01). The calculated value of its mass excess is 60.34 MeV [see (1981AJ01)]: 13Li would then be unstable with respect to 11Li + 2n by 3.34 MeV. (1985PO10) calculate [in a (0 + 1)ℏω model space] that the first four states of 13Li at 0, 1.42, 2.09 and 2.77 MeV have, respectively, Jπ = 3/2-, 7/2-, 1/2-, 5/2-. See also (1987PE1C, 1989OG1B) and (1988POZS, 1988ZV1A

  17. A=15Li (1991AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    91AJ01) (Not illustrated) 15Li has not been observed. Its atomic mass excess is calculated to be 81.60 MeV: see (1981AJ01). It is then unstable with respect to decay into 14Li + n and 13Li + 2n by 1.2 and 5.1 MeV, respectively. (1985PO10) calculate [in a (0 + 1)ℏω model space] that the first four states of 15Li at 0, 0.73, 2.39 and 2.77 MeV have, respectively, Jπ = 3/2-, 1/2-, 7/2- and 5/2-. See also (1988POZS; theor.)

  18. A=9Li (1984AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4AJ01) (See Energy Level Diagrams for 9Li) GENERAL: See also (1979AJ01) and Table 9.1 Table of Energy Levels (in PDF or PS). Model calculations: (1979LA06). Complex reactions...

  19. A=5Li (1984AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    84AJ01) (See Energy Level Diagrams for 5Li) GENERAL: See also (1979AJ01) and Table 5.3 Table of Energy Levels (in PDF or PS) here. Model calculations:(1978RE1A, 1979MA1J,...

  20. A=8Li (1984AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4AJ01) (See Energy Level Diagrams for 8Li) GENERAL: See also (1979AJ01) and Table 8.2 Table of Energy Levels (in PDF or PS). Special states: (1980OK01). Complex reactions...

  1. A=5Li (1974AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4AJ01) (See Energy Level Diagrams for 5Li) GENERAL: See also (1966LA04) and Table 5.5 Table of Energy Levels (in PDF or PS) here. Shell model calculations: (1966FR1B, 1968GO01,...

  2. A=5Li (1979AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9AJ01) (See Energy Level Diagrams for 5Li) GENERAL: See also (1974AJ01) and Table 5.3 Table of Energy Levels (in PDF or PS) here. Model calculations: (1975KR1A). Special states:...

  3. A=9Li (1988AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8AJ01) (See Energy Level Diagrams for 9Li) GENERAL: See also (1984AJ01) and Table 9.1 Table of Energy Levels (in PDF or PS). Model calculations: (1983KU17, 1984CH24, 1984VA06)....

  4. A=8Li (1979AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    79AJ01) (See Energy Level Diagrams for 8Li) GENERAL: See also (1974AJ01) and Table 8.1 Table of Energy Levels (in PDF or PS). Nuclear models: (1975KH1A, 1977ST24). Special...

  5. A=8Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cross section, comparable to the geometric value, is understood in terms of the ( + t) cluster nature of 7Li (RO62C). Cross sections for this reaction have recently been...

  6. Construction Consultants, L.I., Inc.

    Energy Savers [EERE]

    Mr. Eric Baumack Senior Project Manager Construction Consultants L.I., Inc. 36 East 2 nd Street Riverhead, New York 11901 WEL-2015-05 Dear Mr. Baumack: The Office of Enterprise Assessments' Office of Enforcement has completed an investigation into an electrical shock incident involving a worker employed by a subcontractor to Construction Consultants L.I., Inc. (CCLI) at the Brookhaven National Laboratory (BNL). CCLI is a first-tier subcontractor to Brookhaven Science Associates, LLC (BSA),

  7. Rare Earth Elements Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Elements Rare Earth Elements from Coal and Coal By-Products logo. Download the 2016 Rare Earth Elements from Coal and Coal By-Products Project Portfolio Rare Earth Elements from Coal and Coal By-Products program overview slide. The REE Program is focused on developing technologies for the recovery of REEs from Coal and Coal By-Products. Rare Earth Elements from Coal and Coal By-Products background slide The 17-element group known as rare earth elements (REEs) provides significant

  8. First Principles Prediction of Nitrogen-doped Carbon Nanotubes as a High-Performance Cathode for Li-S Batteries

    SciTech Connect (OSTI)

    Wang, Zhiguo; Niu, Xinyue; Xiao, Jie; Wang, Chong M.; Liu, Jun; Gao, Fei

    2013-07-16

    The insulating nature of sulfur and the solubility of the polysulfide in organic electrolyte are two main factors that limit the application of lithium sulfur (Li-S) battery systems. Enhancement of Li conductivity, identification of a strong adsorption agent of polysulfides and the improvement of the whole sulfur-based electrode are of great technological importance. The diffusion of Li atoms on the outer-wall, inner-wall and inter-wall spaces in nitrogen-doped double-walled carbon nanotubes (CNTs) and penetrations of Li and S atoms through the walls are studied using density functional theory. We find that N-doping does not alternate the diffusion behaviors of Li atoms throughout the CNTs, but the energy barrier for Li atoms to penetrate the wall is greatly decreased by N-doping (from ~9.0 eV to ~ 1.0 eV). On the other hand, the energy barrier for S atoms to penetrate the wall remains very high, which is caused by the formation of the chemical bonds between the S and nearby N atoms. The results indicate that Li atoms are able to diffuse freely, whereas S atoms can be encapsulated inside the N-doped CNTs, suggesting that the N-doped CNTs can be potentially used in high performance Li-S batteries.

  9. Li K-Edge XANES Spectra of Lithium Niobate and Lithium Tantalite

    SciTech Connect (OSTI)

    Mizota, H.; Ito, Y.; Tochio, T.; Handa, K.; Takekawa, S.; Kitamura, K.

    2007-02-02

    The x-ray emission with the single crystal of lithium niobate (LiNbO3) or lithium tantalite (LiTaO3) by thermal changes in a vacuum system is closely concerned with the electronic state of each crystal. Therefore, lithium K-edge x-ray absorption near edge structures (XANES) spectra of these materials were measured in the region from 50 eV to 90 eV by means of total electron yield method (T.E.Y.), using the extremely soft x-ray. Samples were powder of lithium carbonate (Li2CO3) and single crystal of lithium fluoride (LiF), LiNbO3 and LiTaO3 in order to compare the shapes of these XANES spectra. Various peak structures appear in these spectra in the range from 55 eV to 80 eV and each spectrum has different shapes as a result of the difference of bond length and bond angles for the atoms which are in less than 60 nm from the absorbing atom. The relationship between these spectra and the electronic states was discussed by FEFF 8.

  10. Rare-Earth-Free Permanent Magnets for Electrical Vehicle Motors and Wind Turbine Generators: Hexagonal Symmetry Based Materials Systems Mn-Bi and M-type Hexaferrite

    SciTech Connect (OSTI)

    Hong, Yang-Ki; Haskew, Timothy; Myryasov, Oleg; Jin, Sungho; Berkowitz, Ami

    2014-06-05

    The research we conducted focuses on the rare-earth (RE)-free permanent magnet by modeling, simulating, and synthesizing exchange coupled two-phase (hard/soft) RE-free core-shell nano-structured magnet. The RE-free magnets are made of magnetically hard core materials (high anisotropy materials including Mn-Bi-X and M-type hexaferrite) coated by soft shell materials (high magnetization materials including Fe-Co or Co). Therefore, our research helps understand the exchange coupling conditions of the core/shell magnets, interface exchange behavior between core and shell materials, formation mechanism of core/shell structures, stability conditions of core and shell materials, etc.

  11. Solar Power Beaming: From Space to Earth

    SciTech Connect (OSTI)

    Rubenchik, A M; Parker, J M; Beach, R J; Yamamoto, R M

    2009-04-14

    Harvesting solar energy in space and power beaming the collected energy to a receiver station on Earth is a very attractive way to help solve mankind's current energy and environmental problems. However, the colossal and expensive 'first step' required in achieving this goal has to-date stifled its initiation. In this paper, we will demonstrate that recent advance advances in laser and optical technology now make it possible to deploy a space-based system capable of delivering 1 MW of energy to a terrestrial receiver station, via a single unmanned commercial launch into Low Earth Orbit (LEO). Figure 1 depicts the overall concept of our solar power beaming system, showing a large solar collector in space, beaming a coherent laser beam to a receiving station on Earth. We will describe all major subsystems and provide technical and economic discussion to support our conclusions.

  12. Interfacial reaction dependent performance of hollow carbon nanosphere - sulfur composite as a cathode for Li-S battery

    SciTech Connect (OSTI)

    Zheng, Jianming; Yan, Pengfei; Gu, Meng; Wagner, Michael J.; Hays, Kevin A.; Chen, Junzheng; Li, Xiaohong S.; Wang, Chong M.; Zhang, Ji -Guang; Liu, Jun; Xiao, Jie

    2015-05-26

    Lithium-sulfur (Li-S) battery is a promising energy storage system due to its high energy density, cost effectiveness and environmental friendliness of sulfur. However, there are still a number of challenges, such as low Coulombic efficiency and poor long-term cycling stability, impeding the commercialization of Li-S battery. The electrochemical performance of Li-S battery is closely related with the interfacial reactions occurring between hosting substrate and active sulfur species which are poorly conducting at fully oxidized and reduced states. Here, we correlate the relationship between the performance and interfacial reactions in the Li-S battery system, using a hollow carbon nanosphere (HCNS) with highly graphitic character as hosting substrate for sulfur. With an appropriate amount of sulfur loading, HCNS/S composite exhibits excellent electrochemical performance because of the fast interfacial reactions between HCNS and the polysulfides. However, further increase of sulfur loading leads to increased formation of highly resistive insoluble reaction products (Li2S2/Li2S) which limits the reversibility of the interfacial reactions and results in poor electrochemical performance. In conclusion, these findings demonstrate the importance of the interfacial reaction reversibility in the whole electrode system on achieving high capacity and long cycle life of sulfur cathode for Li-S batteries.

  13. Interfacial reaction dependent performance of hollow carbon nanosphere - sulfur composite as a cathode for Li-S battery

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Jianming; Yan, Pengfei; Gu, Meng; Wagner, Michael J.; Hays, Kevin A.; Chen, Junzheng; Li, Xiaohong S.; Wang, Chong M.; Zhang, Ji -Guang; Liu, Jun; et al

    2015-05-26

    Lithium-sulfur (Li-S) battery is a promising energy storage system due to its high energy density, cost effectiveness and environmental friendliness of sulfur. However, there are still a number of challenges, such as low Coulombic efficiency and poor long-term cycling stability, impeding the commercialization of Li-S battery. The electrochemical performance of Li-S battery is closely related with the interfacial reactions occurring between hosting substrate and active sulfur species which are poorly conducting at fully oxidized and reduced states. Here, we correlate the relationship between the performance and interfacial reactions in the Li-S battery system, using a hollow carbon nanosphere (HCNS) withmore » highly graphitic character as hosting substrate for sulfur. With an appropriate amount of sulfur loading, HCNS/S composite exhibits excellent electrochemical performance because of the fast interfacial reactions between HCNS and the polysulfides. However, further increase of sulfur loading leads to increased formation of highly resistive insoluble reaction products (Li2S2/Li2S) which limits the reversibility of the interfacial reactions and results in poor electrochemical performance. In conclusion, these findings demonstrate the importance of the interfacial reaction reversibility in the whole electrode system on achieving high capacity and long cycle life of sulfur cathode for Li-S batteries.« less

  14. NASA Earth at Night Video

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Twitter Google + Vimeo GovDelivery SlideShare NASA Earth at Night Video HomeEC, Energy, Energy Efficiency, Global, Modeling, News & Events, Solid-State Lighting, VideosNASA Earth ...

  15. Superhydrophobic diatomaceous earth

    DOE Patents [OSTI]

    Simpson, John T.; D'Urso, Brian R.

    2012-07-10

    A superhydrophobic powder is prepared by coating diatomaceous earth (DE) with a hydrophobic coating on the particle surface such that the coating conforms to the topography of the DE particles. The hydrophobic coating can be a self assembly monolayer of a perfluorinated silane coupling agent. The DE is preferably natural-grade DE where organic impurities have been removed. The superhydrophobic powder can be applied as a suspension in a binder solution to a substrate to produce a superhydrophobic surface on the substrate.

  16. Excitation functions of {sup 6,7}Li+{sup 7}Li reactions at low energies

    SciTech Connect (OSTI)

    Prepolec, L.; Soic, N.; Blagus, S.; Miljanic, D.; Siketic, Z.; Skukan, N.; Uroic, M.; Milin, M.

    2009-08-26

    Differential cross sections of {sup 6,7}Li+{sup 7}Li nuclear reactions have been measured at forward angles (10 deg. and 20 deg.), using particle identification detector telescopes, over the energy range 2.75-10.00 MeV. Excitation functions have been obtained for low-lying residual-nucleus states. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) at beam energy about 8 MeV, first observed by Wyborny and Carlson in 1971 at 0 deg., has been observed at 10 deg., but is less evident at 20 deg. The cross section obtained for the {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(g.s,0{sup +}) reaction is about ten times smaller. The well pronounced peak in the excitation function of {sup 7}Li({sup 7}Li,{sup 4}He){sup 10}Be(3.37 MeV,2{sup +}) reaction could correspond to excited states in {sup 14}C, at excitation energies around 30 MeV.

  17. LLNL-Earth3D

    Energy Science and Technology Software Center (OSTI)

    2013-10-01

    Earth3D is a computer code designed to allow fast calculation of seismic rays and travel times through a 3D model of the Earth. LLNL is using this for earthquake location and global tomography efforts and such codes are of great interest to the Earth Science community.

  18. Ames Lab 101: Rare Earths

    SciTech Connect (OSTI)

    Gschneidner, Karl

    2010-01-01

    "Mr. Rare Earth," Ames Laboratory scientist Karl Gschneidner Jr., explains the importance of rare-earth materials in many of the technologies we use today -- ranging from computers to hybrid cars to wind turbines. Gschneidner is a world renowned rare-earths expert at the U.S. Department of Energy's Ames Laboratory.

  19. Ames Lab 101: Rare Earths

    ScienceCinema (OSTI)

    Gschneidner, Karl

    2012-08-29

    "Mr. Rare Earth," Ames Laboratory scientist Karl Gschneidner Jr., explains the importance of rare-earth materials in many of the technologies we use today -- ranging from computers to hybrid cars to wind turbines. Gschneidner is a world renowned rare-earths expert at the U.S. Department of Energy's Ames Laboratory.

  20. Structural investigation of MO⋅P{sub 2}O{sub 5}⋅Li{sub 2}O (MO = Fe{sub 2}O{sub 3} or V{sub 2}O{sub 5}) glass systems by FTIR spectroscopy

    SciTech Connect (OSTI)

    Andronache, Constantin I. Racolta, Dania

    2014-11-24

    Glasses from the systems xMO⋅(100−x)[P{sub 2}O{sub 5}⋅Li{sub 2}O] (MO = Fe{sub 2}O{sub 3} or V{sub 2}O{sub 5}) with 0 ≤ x ≤ mol % were prepared in the same conditions and characterized by IR spectroscopy. It was established the mode in which both Fe{sub 2}O{sub 3} and V{sub 2}O{sub 5} influences the local structure of these glasses. The iron ions generally modify in a different way the local structure of these glasses then vanadium ions. The results shown that phosphate units are the main structural units of glass system and the iron and vanadium ions are located in the network.

  1. Earth Sciences Division annual report 1990

    SciTech Connect (OSTI)

    1991-06-01

    This Annual Report presents summaries of selected representative research activities grouped according to the principal disciplines of the Earth Sciences Division: Reservoir Engineering and Hydrogeology, Geology and Geochemistry, and Geophysics and Geomechanics. Much of the Division`s research deals with the physical and chemical properties and processes in the earth`s crust, from the partially saturated, low-temperature near-surface environment to the high-temperature environments characteristic of regions where magmatic-hydrothermal processes are active. Strengths in laboratory and field instrumentation, numerical modeling, and in situ measurement allow study of the transport of mass and heat through geologic media -- studies that now include the appropriate chemical reactions and the hydraulic-mechanical complexities of fractured rock systems. Of particular note are three major Division efforts addressing problems in the discovery and recovery of petroleum, the application of isotope geochemistry to the study of geodynamic processes and earth history, and the development of borehole methods for high-resolution imaging of the subsurface using seismic and electromagnetic waves. In 1989 a major DOE-wide effort was launched in the areas of Environmental Restoration and Waste Management. Many of the methods previously developed for and applied to deeper regions of the earth will in the coming years be turned toward process definition and characterization of the very shallow subsurface, where man-induced contaminants now intrude and where remedial action is required.

  2. A Star on Earth

    SciTech Connect (OSTI)

    Prager, Stewart; Zwicker, Andrew; Hammet, Greg; Tresemer, Kelsey; Diallo, Ahmed

    2014-03-05

    At the Energy Department's Princeton Plasma Physics Lab, scientists are trying to accomplish what was once considered the realm of science fiction: create a star on Earth. The National Spherical Torus Experiment (NSTX) is a magnetic fusion device that is used to study the physics principles of spherically shaped plasmas -- hot ionized gases in which, under the right conditions, nuclear fusion will occur. Fusion is the energy source of the sun and all of the stars. Not just limited to theoretical work, the NSTX is enabling cutting-edge research to develop fusion as a future energy source.

  3. Earth-sheltered apartments

    SciTech Connect (OSTI)

    Germer, J.

    1984-12-01

    Earth-sheltered apartments for students at St. Johns University, Collegeville, MN are described. The intent was to provide energy-efficient, low maintenance housing in a neighborhood environment for the students. Students would learn about energy-conscious architecture from living in the buildings. The buildings have had few problems, but energy performance has not been up to expectations. The consumption of electricity exceeded predictions by 49%. The most likely answer to the problem is deviation from design. Several items of energy-efficient design were specified but deleted in order to cut costs.

  4. A Star on Earth

    ScienceCinema (OSTI)

    Prager, Stewart; Zwicker, Andrew; Hammet, Greg; Tresemer, Kelsey; Diallo, Ahmed

    2014-06-06

    At the Energy Department's Princeton Plasma Physics Lab, scientists are trying to accomplish what was once considered the realm of science fiction: create a star on Earth. The National Spherical Torus Experiment (NSTX) is a magnetic fusion device that is used to study the physics principles of spherically shaped plasmas -- hot ionized gases in which, under the right conditions, nuclear fusion will occur. Fusion is the energy source of the sun and all of the stars. Not just limited to theoretical work, the NSTX is enabling cutting-edge research to develop fusion as a future energy source.

  5. Earth Day 2016 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Earth Day 2016 Earth Day 2016 April 18, 2016 - 7:39am Addthis Earth Day 2016 April 22, 2016 is the forty-sixth anniversary of the founding of Earth Day which marked the beginning ...

  6. White Earth Nation Biomass Fasibility Study

    Energy Savers [EERE]

    November 16, 2012 Jerome Lhotka, Director, Economic Development Mike Triplett, Planner White Earth Nation Presentation Overview * Study Objectives * Accomplishments to Date * Initial Findings * Observations * Plans Forward 2 Study Objectives * Primary Objectives: * Conduct a due diligence grade feasibility study to assess the opportunity to convert existing thermal and power systems at the Shooting Star Casino to a sustainable bioenergy system. * Background * The Casino is utilizing fuel oil and

  7. White Earth Nation Biomass Feasibility Study

    Energy Savers [EERE]

    May 5, 2015 - DOE Tribal Energy Program Mike Triplett, Planner White Earth Nation Presentation Overview * Study Objectives * Accomplishments to Date * Initial Findings * Observations * Plans Forward 2 Study Objectives * Primary Objectives: * Conduct a due diligence grade feasibility study to assess the opportunity to convert existing thermal and power systems at the Shooting Star Casino to a sustainable bioenergy system. * Background * The Casino is utilizing fuel oil and propane fired boilers

  8. White Earth Nation Biomass Feasibility Study

    Energy Savers [EERE]

    March 27, 2014 Mike Triplett, Planner White Earth Nation Presentation Overview * Study Objectives * Accomplishments to Date * Initial Findings * Observations * Plans Forward 2 Study Objectives * Primary Objectives: * Conduct a due diligence grade feasibility study to assess the opportunity to convert existing thermal and power systems at the Shooting Star Casino to a sustainable bioenergy system. * Background * The Casino is utilizing fuel oil and propane fired boilers as primary source of

  9. Hydrogen storage in LiH: A first principle study

    SciTech Connect (OSTI)

    Banger, Suman Nayak, Vikas Verma, U. P.

    2014-04-24

    First principles calculations have been performed on the Lithium hydride (LiH) using the full potential linearized augmented plane wave (FP-LAPW) method within the framework of density functional theory. We have extended our calculations for LiH+2H and LiH+6H in NaCl structure. The structural stability of three compounds have been studied. It is found that LiH with 6 added Hydrogen atoms is most stable. The obtained results for LiH are in good agreement with reported experimental data. Electronic structures of three compounds are also studied. Out of three the energy band gap in LiH is ∼3.0 eV and LiH+2H and LiH+6H are metallic.

  10. Shanghai Shen Li High Tech Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Shen Li High Tech Co Ltd Jump to: navigation, search Name: Shanghai Shen-Li High Tech Co Ltd Place: Shanghai, Shanghai Municipality, China Zip: 201400 Product: Focused on the...

  11. Low energy detectors: 6Li-glass scintillators (Conference) |...

    Office of Scientific and Technical Information (OSTI)

    Low energy detectors: 6Li-glass scintillators Citation Details In-Document Search Title: Low energy detectors: 6Li-glass scintillators You are accessing a document from the ...

  12. Predicting Reaction Sequences for Li-S Batteries - Joint Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    May 2, 2014, Research Highlights Predicting Reaction Sequences for Li-S Batteries Computed ... polysulfide species will be used to identify more stable electrolytes for Li-S batteries. ...

  13. Batteries - Next-generation Li-ion batteries Breakout session

    Broader source: Energy.gov (indexed) [DOE]

    the Other Technical Areas Being Discussed * Main point: we should consider next-gen Li-ion and beyond Li-ion together as a single portfolio of work, in which risk and...

  14. Enforcement Letter, Construction Consultants L.I., Inc. | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Construction Consultants L.I., Inc. Enforcement Letter, Construction Consultants L.I., Inc. December 4, 2015 Worker Safety and Health Enforcement Letter issued to Construction Consultants L.I., Inc. On December 4, 2015, the U.S. Department of Energy (DOE) Office of Enterprise Assessments' Office of Enforcement issued an Enforcement Letter (WEL-2015-05) to Construction Consultants L.I., Inc., relating to an electrical shock suffered by a subcontractor while working on a meteorological

  15. Observing and modeling Earths energy flows

    SciTech Connect (OSTI)

    Stevens B.; Schwartz S.

    2012-05-11

    This article reviews, from the authors perspective, progress in observing and modeling energy flows in Earth's climate system. Emphasis is placed on the state of understanding of Earth's energy flows and their susceptibility to perturbations, with particular emphasis on the roles of clouds and aerosols. More accurate measurements of the total solar irradiance and the rate of change of ocean enthalpy help constrain individual components of the energy budget at the top of the atmosphere to within {+-}2 W m{sup -2}. The measurements demonstrate that Earth reflects substantially less solar radiation and emits more terrestrial radiation than was believed even a decade ago. Active remote sensing is helping to constrain the surface energy budget, but new estimates of downwelling surface irradiance that benefit from such methods are proving difficult to reconcile with existing precipitation climatologies. Overall, the energy budget at the surface is much more uncertain than at the top of the atmosphere. A decade of high-precision measurements of the energy budget at the top of the atmosphere is providing new opportunities to track Earth's energy flows on timescales ranging from days to years, and at very high spatial resolution. The measurements show that the principal limitation in the estimate of secular trends now lies in the natural variability of the Earth system itself. The forcing-feedback-response framework, which has developed to understand how changes in Earth's energy flows affect surface temperature, is reviewed in light of recent work that shows fast responses (adjustments) of the system are central to the definition of the effective forcing that results from a change in atmospheric composition. In many cases, the adjustment, rather than the characterization of the compositional perturbation (associated, for instance, with changing greenhouse gas concentrations, or aerosol burdens), limits accurate determination of the radiative forcing. Changes in clouds contribute importantly to this adjustment and thus contribute both to uncertainty in estimates of radiative forcing and to uncertainty in the response. Models are indispensable to calculation of the adjustment of the system to a compositional change but are known to be flawed in their representation of clouds. Advances in tracking Earth's energy flows and compositional changes on daily through decadal timescales are shown to provide both a critical and constructive framework for advancing model development and evaluation.

  16. Energy Department Earth Week 2015

    Broader source: Energy.gov [DOE]

    To celebrate Earth Week and Earth Day, the Bioenergy Technologies Office (BETO) is participating in several Energy Department activities! Look for us inside the lobby of the U.S. Department of Energy Forrestal Building in Washington, D.C., from April 13–17. Then, on Earth Day, April 22, everyone is welcome to join us outside on the Forrestal West Plaza for Community Day!

  17. Thermal Stability of LiPF 6 Salt and Li-ion Battery Electrolytes...

    Office of Scientific and Technical Information (OSTI)

    In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF 6 and water vapor to form ...

  18. Probing the failure mechanism of nanoscale LiFePO₄ for Li-ion batteries

    SciTech Connect (OSTI)

    Gu, Meng; Shi, Wei; Zheng, Jianming; Yan, Pengfei; Zhang, Ji-guang; Wang, Chongmin

    2015-05-18

    LiFePO4 is a high power rate cathode material for lithium ion battery and shows remarkable capacity retention, featuring a 91% capacity retention after 3300 cycles. In this work, we use high-resolution transmission electron microscopy (HRTEM), energy dispersive x-ray spectroscopy (EDS), and electron energy loss spectroscopy (EELS) to study the gradual capacity fading mechanism of LiFePO4 materials. We found that upon prolonged electrochemical cycling of the battery, the LiFePO4 cathode shows surface amorphization and loss of oxygen species, which directly contribute to the gradual capacity fading of the battery. The finding is of great importance for the design and improvement of new LiFePO4 cathode for high-energy and high-power rechargeable battery for electric transportation.

  19. A=10Li (1988AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MeV) corresponds to the ground state. 10Lig.s. would then be unbound with respect to breakup into 9Li + n by 0.80 0.25 MeV: see (1979AJ01). See also (1986GI10, 1987AB15),...

  20. A=10Li (1979AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    width of the ground state is 1.2 0.3 MeV. 10Lig.s. is unbound with respect to breakup into 9Li + n by 0.80 0.25 MeV (1975WI26). See also (1974BA15, 1974CE1A, 1974TH01,...

  1. A=10Li (1984AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MeV) corresponds to the ground state. 10Lig.s. would the be unbound with respect to breakup into 9Li + n by 0.80 0.25 MeV (1975WI26). However (1979AB11, 1980AB16), on the...

  2. A=7Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7Li) GENERAL: See also (66LA04) and Table 7.1 Table of Energy Levels (in PDF or PS). Shell model:(KO61L, CO65I, KU65D, VO65A, BA66T, HA66F, WI66E, BO67R, BO67V, CO67M, FA67A,...

  3. A=6Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    66LA04) (See Energy Level Diagrams for 6Li) GENERAL: See Table 6.4 Table of Energy Levels (in PDF or PS). See also (AU55, LA55, ME56, FR57, HU57D, LE57F, PI58, BA59K, BR59M,...

  4. A=9Li (74AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    74AJ01) (See Energy Level Diagrams for 9Li) GENERAL: See also Table 9.1 Table of Energy Levels (in PDF or PS). Model calculations:(BA66T). Special reactions:(DO56D, GA66K, KL66C,...

  5. Desorption induced by atomic and molecular ion collisions on LiF

    SciTech Connect (OSTI)

    Pereira, J. A. M.; Silveira, E. F. da

    1999-06-10

    Atomic and molecular nitrogen ion beams, produced by the PUC-Rio Van de Graaff accelerator, were used to bombard lithium fluoride thin films. Desorption of secondary ions was measured by means of a time-of-flight mass spectrometer equipped with a double grid acceleration system. The outputs of the experiment are the axial kinetic energy distribution and the desorption yield of the emitted ions. This information allowed determination of the relative contribution to desorption due to collision cascades (nuclear sputtering) and to electronic excitation (electronic sputtering). It was observed that F{sup -} ions are desorbed as a result of collision cascades and that the F{sup -} ion yields depends linearly on the number of constuents in the projectile, i.e., Y(N{sub 2}{sup +})=2Y(N{sup +}). The emission of clusters such as (LiF)Li{sup +} was found to be caused by electronic excitation and the (LiF)Li{sup +} yield revealed a nonlinear dependence: Y(N{sub 2}{sup +})>2Y(N{sup +}). Both processes were found to contribute to Li{sup +} desorption. These effects are discussed in terms of the density of deposited energy which depends on the projectile velocity and on the electronic stopping power.

  6. Evolution of stable and metastable phases and coercivity in rare-earth-rich alloys of the Fe-Nd and Fe-Pr systems

    SciTech Connect (OSTI)

    Cabral, F.A.O. ); Gama, S. )

    1990-09-01

    The authors have studied eutectic alloys of the Fe-Nd and Fe-Pr systems regarding their magnetic behavior in the as-cast state and heat-treated at 600 C for different periods. In both systems the initial precipitation of a metastable phase is observed. This phase transforms into Fe{sub 17}Nd{sub 2} and this finally into a second phase with Fe{sub 17}Nd{sub 5} stoichiometry that is stable. For the Fe-Pr system the precipitation of two metastable phases that transform into the stable Fe{sub 17}Pr{sub 2} is observed. The authors have also measured the influence of these transformations on the coercivity of these alloys.

  7. Epitaxial thin film growth of LiH using a liquid-Li atomic template

    SciTech Connect (OSTI)

    Oguchi, Hiroyuki; Ikeshoji, Tamio; Orimo, Shin-ichi; Ohsawa, Takeo; Shiraki, Susumu; Hitosugi, Taro; Kuwano, Hiroki

    2014-11-24

    We report on the synthesis of lithium hydride (LiH) epitaxial thin films through the hydrogenation of a Li melt, forming abrupt LiH/MgO interface. Experimental and first-principles molecular dynamics studies reveal a comprehensive microscopic picture of the crystallization processes, which sheds light on the fundamental atomistic growth processes that have remained unknown in the vapor-liquid-solid method. We found that the periodic structure that formed, because of the liquid-Li atoms at the film/MgO-substrate interface, serves as an atomic template for the epitaxial growth of LiH crystals. In contrast, films grown on the Al{sub 2}O{sub 3} substrates indicated polycrystalline films with a LiAlO{sub 2} secondary phase. These results and the proposed growth process provide insights into the preparation of other alkaline metal hydride thin films on oxides. Further, our investigations open the way to explore fundamental physics and chemistry of metal hydrides including possible phenomena that emerge at the heterointerfaces of metal hydrides.

  8. The ARIES-RS power core -- Recent development in Li/V designs

    SciTech Connect (OSTI)

    Sze, D.K.; Billone, M.C.; Hua, T.Q.

    1997-04-01

    The ARIES-RS fusion power plant design study is based on reversed-shear (RS) physics with a Li/V (lithium breeder and vanadium structure) blanket. The reversed-shear discharge has been documented in many large tokamak experiments. The plasma in the RS mode has a high beta, low current, and low current drive requirements. Therefore, it is an attractive physics regime for a fusion power plant. The blanket system based on a Li/V has high temperature operating capability, good tritium breeding, excellent high heat flux removal capability, long structural life time, low activation, low after heat and good safety characteristics. For these reasons, the ARIES-RS reactor study selected Li/V as the reference blanket. The combination of attractive physics and attractive blanket engineering is expected to result in a superior power plant design. This paper summarizes the power core design of the ARIES-RS power plant study.

  9. Two earth sheltered passive solar residences with photovoltaic electricity

    SciTech Connect (OSTI)

    Strong, S.J.; Osten, R.J. Jr.

    1980-01-01

    The design and construction of two earth sheltered passive solar residence with photovoltaic electricity are described. The sizing and design of the P.V. system as well as the module fabrication and array integration are also discussed.

  10. Method for improving voltage regulation of batteries, particularly Li/FeS.sub.2 thermal batteries

    DOE Patents [OSTI]

    Godshall, Ned A.

    1988-01-01

    Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS.sub.2 system.

  11. Method for improving voltage regulation of batteries, particularly Li/FeS/sub 2/ thermal batteries

    DOE Patents [OSTI]

    Godshall, N.A.

    1986-06-10

    Batteries are improved, especially with respect to voltage regulation properties, by employing as anode and cathode compositions, those which fall in a thermodynamically invariant region of the metallurgical phase diagram of the combination of the constituent components. The invention is especially useful in the Li/FeS/sub 2/ system.

  12. Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management

    SciTech Connect (OSTI)

    Viswanathan, Vilayanur V; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A; Williford, Ralph E; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

    2010-06-01

    The entropy changes (ΔS) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

  13. Scientists compose complex math equations to replicate behaviors of Earth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    systems | Argonne National Laboratory Rob Jacob talks about climate models Climate Models: Rob Jacob Scientists compose complex math equations to replicate behaviors of Earth systems By Angela Hardin * December 16, 2015 Tweet EmailPrint Whenever news breaks about what Earth's climate is expected to be like decades into the future or how much rainfall various regions around the country or the world are likely to receive, those educated estimates are generated by a global climate model. But

  14. Phase stable rare earth garnets

    DOE Patents [OSTI]

    Kuntz, Joshua D.; Cherepy, Nerine J.; Roberts, Jeffery J.; Payne, Stephen A.

    2013-06-11

    A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.

  15. Solution-processable glass LiI-Li4SnS4 superionic conductors for all-solid-state Li-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kern Ho Park; Oh, Dae Yang; Choi, Young Eun; Nam, Young Jin; Han, Lili; Kim, Ju -Young; Xin, Huolin; Lin, Feng; Oh, Seung M.; Jung, Yoon Seok

    2015-12-22

    The new, highly conductive (4.1 × 10–4 S cm–1 at 30 °C), highly deformable, and dry-air-stable glass 0.4LiI-0.6Li4SnS4 is prepared using a homogeneous methanol solution. Furthermore, the solution process enables the wetting of any exposed surface of the active materials with highly conductive solidified electrolytes (0.4LiI-0.6Li4SnS4), resulting in considerable improvements in electrochemical performances of these electrodes over conventional mixture electrodes.

  16. White Earth Biomass/Biogas Feasibility Study

    SciTech Connect (OSTI)

    Triplett, Michael

    2015-03-12

    The White Earth Nation examined the feasibility of cost savings and fossil energy reduction through the installation of biogas/biomass boiler at the tribal casino. The study rejected biogas options due to availability and site constraints, but found a favorable environment for technical and financial feasibility of installing a 5 MMBtu hot water boiler system to offset 60-70 percent of current fuel oil and propane usage.

  17. Rare-Earth-Free Traction Motor: Rare Earth-Free Traction Motor for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2012-01-01

    REACT Project: Baldor will develop a new type of traction motor with the potential to efficiently power future generations of EVs. Unlike todays large, bulky EV motors which use expensive, imported rare-earth-based magnets, Baldors motor could be light, compact, contain no rare earth materials, and have the potential to deliver more torque at a substantially lower cost. Key innovations in this project include the use of a unique motor design, incorporation of an improved cooling system, and the development of advanced materials manufacturing techniques. These innovations could significantly reduce the cost of an electric motor.

  18. Modeling and analysis of a molten salt electrowinning system with liquid cadmium cathode

    SciTech Connect (OSTI)

    Kim, K.R.; Ahn, D.H.; Paek, S.; Kwon, S.W.; Kim, S.H.; Shim, J.B.; Chung, H.; Kim, E.H.

    2007-07-01

    In the present work, an electrowinning process in the LiCl-KCl/Cd system is considered to model and analyze the equilibrium behavior and electro-transport of the actinide and rare-earth elements. Equilibrium distributions of the actinide and rare-earth elements in a molten salt and liquid cadmium system have been estimated for an infinite potentiostatic electrolysis from the thermodynamic data and material balance. A simple dynamic modeling of this process was performed by taking into account the material balances and diffusion-controlled electrochemical reactions in a diffusion layer at an electrode interface between the molten salt and liquid cadmium cathode. This model demonstrated a prediction of the concentration behaviors, a faradic current of each element and an electrochemical potential as function of the time up to the corresponding electro-transport satisfying a given applied current based on a galvano-static electrolysis. (authors)

  19. FIRST_Research Perspective_Li

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1. Structure factor obtained from MD (a) and SAXS (b) at different temperatures: comparison of spatial heterogeneity from snapshots (c) of DILs (top) and MILs (bottom) FIRST Center Research Perspective: Nanoscale Heterogeneity and Dynamics of Room Temperature Ionic Liquids Song Li Vanderbilt University Jianchang Guo, Kee Sung Han, Jose L. Bañuelos, Edward W. Hagaman, Robert W. Shaw Oak Ridge National Laboratory Research Summary: An increase of the alkyl chain length of the cation of room

  20. High Poisson;s ratio of Earth;s inner core explained by carbon...

    Office of Scientific and Technical Information (OSTI)

    High Poisson;s ratio of Earth;s inner core explained by carbon alloying Citation Details In-Document Search Title: High Poisson;s ratio of Earth;s inner core explained by carbon ...

  1. Spin transition zone in Earth;s lower mantle (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Spin transition zone in Earth;s lower mantle Citation Details In-Document Search Title: Spin transition zone in Earth;s lower mantle Authors: Lin, J.-F. ; Vanko, G. ; Jacobsen, ...

  2. Earth Day | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Earth Day Earth Day If you do not see the event begin at 3pm ET, please refresh your browser. Are you looking for ways to go green while saving yourself some green? Or are you interested in learning how to incorporate renewable energy options -- like solar, wind and geothermal -- into your home? This Earth Day, hang out with Energy Department experts to learn how you can reduce your energy use, improve your home's comfort and cut your energy bills. We hope you'll join us on April 22 at 3 pm ET

  3. VenEarth Group | Open Energy Information

    Open Energy Info (EERE)

    VenEarth Group Jump to: navigation, search Name: VenEarth Group Place: San Francisco, California Product: San Francisco-based venture capital company. References: VenEarth Group1...

  4. Celebrate Earth Day! | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Savers Facebook pages, our Earth Day poll provides another opportunity for you to interact with us. Log on to our Earth Day Web site and tell us how you'll recognize Earth Day,...

  5. Earth Day 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This year, we're celebrating Earth Day all week long. It's Earth Week on Energy.gov We're focusing on climate change, highlighting Earth Day events and sharing ways Americans ...

  6. Happy Earth Day 2011! | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Earth Day Website This page from the Office of Energy Efficiency and Renewable Energy highlights other great resources to help you be energy efficient and Earth-friendly Earth Day ...

  7. Method of increasing the sulfation capacity of alkaline earth sorbents

    DOE Patents [OSTI]

    Shearer, J.A.; Turner, C.B.; Johnson, I.

    1980-03-13

    A system and method for increasing the sulfation capacity of alkaline earth carbonates to scrub sulfur dioxide produced during the fluidized bed combustion of coal in which partially sulfated alkaline earth carbonates are hydrated in a fluidized bed to crack the sulfate coating and convert the alkaline earth oxide to the hydroxide. Subsequent dehydration of the sulfate-hydroxide to a sulfate-oxide particle produces particles having larger pore size, increased porosity, decreased grain size and additional sulfation capacity. A continuous process is disclosed.

  8. Method of increasing the sulfation capacity of alkaline earth sorbents

    DOE Patents [OSTI]

    Shearer, John A.; Turner, Clarence B.; Johnson, Irving

    1982-01-01

    A system and method for increasing the sulfation capacity of alkaline earth carbonates to scrub sulfur dioxide produced during the fluidized bed combustion of coal in which partially sulfated alkaline earth carbonates are hydrated in a fluidized bed to crack the sulfate coating and convert the alkaline earth oxide to the hydroxide. Subsequent dehydration of the sulfate-hydroxide to a sulfate-oxide particle produces particles having larger pore size, increased porosity, decreased grain size and additional sulfation capacity. A continuous process is disclosed.

  9. Earth analysis methods, subsurface feature detection methods, earth analysis devices, and articles of manufacture

    DOE Patents [OSTI]

    West, Phillip B.; Novascone, Stephen R.; Wright, Jerry P.

    2011-09-27

    Earth analysis methods, subsurface feature detection methods, earth analysis devices, and articles of manufacture are described. According to one embodiment, an earth analysis method includes engaging a device with the earth, analyzing the earth in a single substantially lineal direction using the device during the engaging, and providing information regarding a subsurface feature of the earth using the analysis.

  10. Earth analysis methods, subsurface feature detection methods, earth analysis devices, and articles of manufacture

    DOE Patents [OSTI]

    West, Phillip B.; Novascone, Stephen R.; Wright, Jerry P.

    2012-05-29

    Earth analysis methods, subsurface feature detection methods, earth analysis devices, and articles of manufacture are described. According to one embodiment, an earth analysis method includes engaging a device with the earth, analyzing the earth in a single substantially lineal direction using the device during the engaging, and providing information regarding a subsurface feature of the earth using the analysis.

  11. rare earth recycling | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rare earth recycling Meet CMI Researcher David Reed CMI researcher David Reed is the principal investigator for the CMI project bioleaching for recovery of recycled rare earth...

  12. Earth Tidal Analysis | Open Energy Information

    Open Energy Info (EERE)

    of earth tide response of three deep, confined aquifers Earth Tidal Analysis At Raft River Geothermal Area (1980) Raft River Geothermal Area 1980 1980 Reservoir response to...

  13. Green Earth Fuels | Open Energy Information

    Open Energy Info (EERE)

    Earth Fuels Jump to: navigation, search Name: Green Earth Fuels Place: Houston, Texas Zip: 77057 Product: A producer and distributor of soy and palm based biodiesel Coordinates:...

  14. Smiling Earth Energy LLC | Open Energy Information

    Open Energy Info (EERE)

    Earth Energy LLC Place: Bakersfield, California Zip: 93314 Product: California based biodiesel producer and project developer. References: Smiling Earth Energy LLC1 This...

  15. Chemistry, Life, and Earth Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ADCLES Chemistry, Life, and Earth Sciences The CLES Directorate is home to world class capabilities in chemistry, bioscience, and earth and environmental sciences. Structural protein research Structural protein research A wide range of protein folding research Field Instrument Deployments and Operations (FIDO) Field Instrument Deployments and Operations (FIDO) Atmospheric science research Quantum Dots Quantum Dots Quantum dot research for energy and light Contact Us Associate Director Nan Sauer

  16. Google Earth Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Google Drive for Work Google Drive for Work Computer.png Welcome to the U.S. Department of Energy Pilot Program, Google Drive for Work. Please read and sign the Terms of Use and Privacy Statement below. DISCLAIMER All data is owned by DOE and may be monitored, intercepted, recorded, read, copied, or captured in any manner and disclosed in any manner, by authorized personnel. THERE IS NO RIGHT OF PRIVACY IN THIS SYSTEM, and system personnel may give to law enforcement officials any potential

  17. Properties of (Ga,Mn)As codoped with Li

    SciTech Connect (OSTI)

    Miyakozawa, Shohei; Chen, Lin; Matsukura, Fumihiro; Ohno, Hideo

    2014-06-02

    We grow Li codoped (Ga,Mn)As layers with nominal Mn composition up to 0.15 by molecular beam epitaxy. The layers before and after annealing are characterized by x-ray diffraction, transport, magnetization, and ferromagnetic resonance measurements. The codoping with Li reduces the lattice constant and electrical resistivity of (Ga,Mn)As after annealing. We find that (Ga,Mn)As:Li takes similar Curie temperature to that of (Ga,Mn)As, but with pronounced magnetic moments and in-plane magnetic anisotropy, indicating that the Li codoping has nontrivial effects on the magnetic properties of (Ga,Mn)As.

  18. Automotive Li-ion Battery Cooling Requirements | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Li-ion Battery Cooling Requirements Presents thermal management of lithium-ion ... Overview and Progress of the Battery Testing, Analysis, and Design Activity Vehicle ...

  19. Prediction of superconductivity in Li-intercalated bilayer phosphorene

    SciTech Connect (OSTI)

    Huang, G. Q.; Xing, Z. W.; Xing, D. Y.

    2015-03-16

    It is shown that bilayer phosphorene can be transformed from a direct-gap semiconductor to a BCS superconductor by intercalating Li atoms. For the Li-intercalated bilayer phosphorene, we find that the electron occupation of Li-derived band is small and superconductivity is intrinsic. With increasing the intercalation of Li atoms, both increased metallicity and strong electron-phonon coupling are favorable for the enhancement of superconductivity. The obtained electron-phonon coupling λ can be larger than 1 and the superconducting temperature T{sub c} can be increased up to 16.5 K, suggesting that phosphorene may be a good candidate for a nanoscale superconductor.

  20. Li ion Motors Corp formerly EV Innovations Inc | Open Energy...

    Open Energy Info (EERE)

    Vegas, Nevada Zip: 89110 Sector: Vehicles Product: Las Vegas - based manufacturer of lithium-powered plug-in vehicles. References: Li-ion Motors Corp (formerly EV Innovations...

  1. Combined Quantum Chemical/Raman Spectroscopic Analyses of Li...

    Office of Scientific and Technical Information (OSTI)

    Combined Quantum ChemicalRaman Spectroscopic Analyses of Li+ Cation Solvation: Cyclic ... Citation Details In-Document Search Title: Combined Quantum ChemicalRaman Spectroscopic ...

  2. Characterization of Materials for Li-ion Batteries: Success Stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Success Stories from the High Temperature Materials Laboratory (HTML) User Program Characterization of Materials for Li-ion Batteries: Success Stories from the High...

  3. Electrical conduction of LiF interlayers in organic diodes

    SciTech Connect (OSTI)

    Bory, Benjamin F.; Janssen, Ren A. J.; Meskers, Stefan C. J.; Gomes, Henrique L.; Leeuw, Dago M. de

    2015-04-21

    An interlayer of LiF in between a metal and an organic semiconductor is commonly used to improve the electron injection. Here, we investigate the effect of moderate bias voltages on the electrical properties of Al/LiF/poly(spirofluorene)/Ba/Al diodes by systematically varying the thickness of the LiF layer (2-50?nm). Application of forward bias V below the bandgap of LiF (V?LiF/poly(spirofluorene) hetero-junction. Electrons are trapped on the poly(spirofluorene) side of the junction, while positively charged defects accumulate in the LiF with number densities as high as 10{sup 25}/m{sup 3}. Optoelectronic measurements confirm the built-up of aggregated, ionized F centres in the LiF as the positive trapped charges. The charged defects result in efficient transport of electrons from the polymer across the LiF, with current densities that are practically independent of the thickness of the LiF layer.

  4. Predictive Models of Li-ion Battery Lifetime (Presentation) Smith...

    Office of Scientific and Technical Information (OSTI)

    Predictive Models of Li-ion Battery Lifetime (Presentation) Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G.; Shi, Y.; Pesaran, A. 25 ENERGY STORAGE; 33 ADVANCED PROPULSION...

  5. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process for Low Cost Domestic Production of LIB Cathode Materials Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode ...

  6. Magnetism reflectometer study shows LiF layers improve efficiency...

    Office of Scientific and Technical Information (OSTI)

    Magnetism reflectometer study shows LiF layers improve efficiency in spin valve devices ... when an organic polymer semiconductor layer is placed between the magnetic materials. ...

  7. Characterization of Li-ion Batteries using Neutron Diffraction...

    Broader source: Energy.gov (indexed) [DOE]

    Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML User Program Success Stories Characterization of Materials for Li-ion Batteries: ...

  8. Digital Through-The-Earth Communication System

    Broader source: Energy.gov [DOE]

    Traditional radio uses frequencies above 500 kHz and does not penetrate any significant distance into typical underground rock masses. Hard-wired links such as phone lines, coaxial cables, mining...

  9. REVERSIBLE HYDROGEN STORAGE IN A LiBH{sub 4}-C{sub 60} NANOCOMPOSITE

    SciTech Connect (OSTI)

    Teprovich, J.; Zidan, R.; Peters, B.; Wheeler, J.

    2013-08-06

    Reversible hydrogen storage in a LiBH{sub 4}:C{sub 60} nanocomposite (70:30 wt. %) synthesized by solvent-assisted mixing has been demonstrated. During the solvent-assisted mixing and nanocomposite formation, a chemical reaction occurs in which the C{sub 60} cages are significantly modified by polymerization as well as by hydrogenation (fullerane formation) in the presence of LiBH{sub 4}. We have determined that two distinct hydrogen desorption events are observed upon rehydrogenation of the material, which are attributed to the reversible formation of a fullerane (C{sub 60}H{sub x}) as well as a LiBH4 species. This system is unique in that the carbon species (C{sub 60}) actively participates in the hydrogen storage process which differs from the common practice of melt infiltration of high surface area carbon materials with LiBH{sub 4} (nanoconfinment effect). This nanocomposite demonstrated good reversible hydrogen storage properties as well as the ability to absorb hydrogen under mild conditions (pressures as low as 10 bar H{sub 2} or temperatures as low as 150?C). The nanocomposite was characterized by TGA-RGA, DSC, XRD, LDI-TOF-MS, FTIR, 1H NMR, and APPI MS.

  10. Measuring Li+ inventory losses in LiCoO2/graphite cells using Raman microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Snyder, Chelsea Marie; Apblett, Christopher A.; Grillet, Anne; Thomas Edwin Beechem; Duquette, David

    2016-03-25

    Here, the contribution from loss of Li+ inventory to capacity fade is described for slow rates (C/10) and long-term cycling (up to 80 cycles). It was found through electrochemical testing and ex-situ Raman analysis that at these slow rates, the entirety of capacity loss up to 80 cycles can be explained by loss of Li+ inventory in the cell. The Raman spectrum of LiCoO2 is sensitive to the state of lithiation and can therefore be leveraged to quantify the state of lithiation for individual particles. With these Raman derived estimates, the lithiation state of the cathode in the discharged statemore » is compared to electrochemical data as a function of cycle number. High correlation is found between Raman quantifications of cycleable lithium and the capacity fade. Additionally, the linear relationship between discharge capacity and cell overpotential suggests that the loss of capacity stems from an impedance rise of the electrodes, which based on Li inventory losses, is caused by SEI formation and repair.« less

  11. The earth is in your hands

    SciTech Connect (OSTI)

    Browner, C.M.

    1995-08-01

    Earth Day 25 is a time to reflect on how mankind is doing in protecting their environment. Twenty-five years ago, in the wake of the first Earth Day, the US has created, virtually from scratch, the most advanced system of environmental protection in the world. In the course of a very short history--a mere quarter-century--man has made tremendous progress. Their skies and rivers are cleaner. And US environmental expertise and technology are in demand throughout the world. In the years since the first Earth Day, EPA banned lead in gasoline, lowering lead levels in the air by more than 90 percent and protecting millions of children from harm. Dangerous and widely used pesticides were banned. Unsafe local garbage dumps all over the nation were closed and recycling has become a household habit. American towns have been provided with substantial funding for wastewater treatment--the second biggest public works effort in US history, resulting in cleaner rivers all over the US. All cars and trucks now have standards for fuel economy, set by EPA, that allow consumers to choose a car for its energy efficiency. And EPA has played an important role in ensuring that companies and others comply with their environmental laws or face stiff penalties. Perhaps most important, the nation has gained a new understanding. More Americans than ever understand that to ensure a good quality of life they must act as responsible stewards of their air, their water, and their land.

  12. Primordial Li abundance and massive particles

    SciTech Connect (OSTI)

    Latin-Capital-Letter-Eth apo, H.

    2012-10-20

    The problem of the observed lithium abundance coming from the Big Bang Nucleosynthesis is as of yet unsolved. One of the proposed solutions is including relic massive particles into the Big Bang Nucleosynthesis. We investigated the effects of such particles on {sup 4}HeX{sup -}+{sup 2}H{yields}{sup 6}Li+X{sup -}, where the X{sup -} is the negatively charged massive particle. We demonstrate the dominance of long-range part of the potential on the cross-section.

  13. Characterization of low-melting electrolytes for potential geothermal borehole power supplies: The LiBr-KBr-LiF eutectic

    SciTech Connect (OSTI)

    Guidotti, R.A.; Reinhardt, F.W.

    1998-05-01

    The suitability of modified thermal-battery technology for use as a potential power source for geothermal borehole applications is under investigation. As a first step, the discharge processes that take place in LiSi/LiBr-KBr-LiF/FeS{sub 2} thermal cells were studied at temperatures of 350 C and 400 C using pelletized cells with immobilized electrolyte. Incorporation of a reference electrode allowed the relative contribution of each electrode to the overall cell polarization to be determined. The results of single-cell tests are presented, along with preliminary data for cells based on a lower-melting CsBr-LiBr-KBr eutectic salt.

  14. Predicted Structure, Thermo-Mechanical Properties and Li Ion Transport in LiAlF4 Glass

    SciTech Connect (OSTI)

    Stechert, T. R.; Rushton, M. J. D.; Grimes, R. W.; Dillon, A. C.

    2012-08-15

    Materials with the LiAlF{sub 4} composition are of interest as protective electrode coatings in Li ion battery applications due to their high cationic conductivity. Here classical molecular dynamics calculations are used to produce amorphous model structures by simulating a quench from the molten state. These are analysed in terms of their individual pair correlation functions and atomic coordination environments. This indicates that amorphous LiAlF{sub 4} is formed of a network of corner sharing AlF{sub 6} octahedra. Li ions are distributed within this network, primarily associated with non-bridging fluorine atoms. The nature of the octahedral network is further analysed through intra- and interpolyhedral bond angle distributions and the relative populations of bridging and non-bridging fluorine ions are calculated. Network topology is considered through the use of ring statistics, which indicates that, although topologically well connected, LiAlF{sub 4} contains an appreciable number of corner-linked branch-like AlF{sub 6} chains. Thermal expansion values are determined above and below the predicted glass transition temperature of 1340 K. Finally, movement of Li ions within the network is examined with predictions of the mean squared displacements, diffusion coefficients and Li ion activation energy. Different regimes for lithium ion movement are identified, with both diffusive and sessile Li ions observed. For migrating ions, a typical trajectory is illustrated and discussed in terms of a hopping mechanism for Li transport.

  15. Study on a regeneration process of LiCl-KCl eutectic based waste salt generated from the pyrochemical process

    SciTech Connect (OSTI)

    Eun, H.C.; Cho, Y.Z.; Choi, J.H.; Kim, J.H.; Lee, T.K.; Park, H.S.; Kim, I.T.; Park, G.I.

    2013-07-01

    A regeneration process of LiCl-KCl eutectic waste salt generated from the pyrochemical process of spent nuclear fuel has been studied. This regeneration process is composed of a chemical conversion process and a vacuum distillation process. Through the regeneration process, a high efficiency of renewable salt recovery can be obtained from the waste salt and rare earth nuclides in the waste salt can be separated as oxide or phosphate forms. Thus, the regeneration process can contribute greatly to a reduction of the waste volume and a creation of durable final waste forms. (authors)

  16. Predicting Chemical Pathways for Li-O2 Batteries - Joint Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 6, 2014, Research Highlights Predicting Chemical Pathways for Li-O2 Batteries ... figure) and (LiO2)6 (red curve, upper figure) to Li2O2 using quantum chemical theory. ...

  17. Update on Performance Improvement of Sandia-Built Li/(CFx)n and...

    Office of Scientific and Technical Information (OSTI)

    Update on Performance Improvement of Sandia-Built Li(CFx)n and LiFePO4 Cells. Citation Details In-Document Search Title: Update on Performance Improvement of Sandia-Built Li(CFx)n ...

  18. Update on Performance Improvement of Sandia-Built Li/(CFx)n and...

    Office of Scientific and Technical Information (OSTI)

    Update on Performance Improvement of Sandia-Built Li(CFx)n and LiFePO4 Cells. Citation Details In-Document Search Title: Update on Performance Improvement of Sandia-Built Li...

  19. A=07Li (66LA04)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    66LA04) (See Energy Level Diagrams for 7Li) GENERAL: See (HU57D, BA59K, BA59N, BR59M, FE59E, MA59E, MA59H, KU60A, PE60E, PH60A, SH60C, TA60L, BA61H, BA61N, BL61C, CL61D, KH61, TA61G, TO61B, CL62E, CR62A, IN62, CH63, CL63C, KL63, SC63I, BE64H, GR64C, MA64HH, NE64C, OL64A, SA64G, BE65F, FA65A, JA65H, NE65, PR65). See also Table 7.1 [Table of Energy Levels] (in PDF or PS). Ground state: Q = -45 ± 5 mb (KA61F, VA63F, WH64); μ = +3.2564 nm (FU65E). 1. 4He(t, γ)7Li Qm = 2.467 Excitation functions

  20. Enabling the Future of Li-Ion Batteries | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enabling the Future of Li-Ion Batteries Title Enabling the Future of Li-Ion Batteries Publication Type Presentation Year of Publication 2015 Authors Gaines, LL Abstract...

  1. Significant Cost Improvement of Li-Ion Cells Through Non-NMP...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies Significant Cost Improvement of Li-Ion ...

  2. Statistical Design of Experiment for Li-ion Cell Formation Parameters...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design of Experiment for Li-ion Cell Formation Parameters using Gen3 Electrode Materials: Final Summary Statistical Design of Experiment for Li-ion Cell Formation Parameters ...

  3. Localization of vacancies and mobility of lithium ions in Li{sub 2}ZrO{sub 3} as obtained by {sup 6,7}Li NMR

    SciTech Connect (OSTI)

    Baklanova, Ya. V., E-mail: baklanovay@ihim.uran.ru [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation); Arapova, I. Yu.; Buzlukov, A.L.; Gerashenko, A.P.; Verkhovskii, S.V.; Mikhalev, K.N. [Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, 18 Kovalevskaya str., 620990 Ekaterinburg (Russian Federation); Denisova, T.A.; Shein, I.R.; Maksimova, L.G. [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91 Pervomaiskaya str., 620990 Ekaterinburg (Russian Federation)

    2013-12-15

    The {sup 6,7}Li NMR spectra and the {sup 7}Li spinlattice relaxation rate were measured on polycrystalline samples of Li{sub 2}ZrO{sub 3}, synthesized at 1050 K and 1300 K. The {sup 7}Li NMR lines were attributed to corresponding structural positions of lithium Li1 and Li2 by comparing the EFG components with those obtained in the first-principles calculations of the charge density in Li{sub 2}ZrO{sub 3}. For both samples the line width of the central {sup 7}Li transition and the spinlattice relaxation time decrease abruptly at the temperature increasing above ?500 K, whereas the EFG parameters are averaged (??{sub Q}?=42 (5) kHz) owing to thermally activated diffusion of lithium ions. - Graphical abstract: Path of lithium ion hopping in lithium zirconate Li{sub 2}ZrO{sub 3}. - Highlights: Polycrystalline samples Li{sub 2}ZrO{sub 3} with monoclinic crystal structure synthesized at different temperatures were investigated by {sup 6,7}Li NMR spectroscopy. Two {sup 6,7}Li NMR lines were attributed to the specific structural positions Li1 and Li2. The distribution of vacancies was clarified for both lithium sites. The activation energy and pathways of lithium diffusion in Li{sub 2}ZrO{sub 3} were defined.

  4. Solution-processable glass LiI-Li4SnS4 superionic conductors for all-solid-state Li-ion batteries

    SciTech Connect (OSTI)

    Kern Ho Park; Oh, Dae Yang; Choi, Young Eun; Nam, Young Jin; Han, Lili; Kim, Ju -Young; Xin, Huolin; Lin, Feng; Oh, Seung M.; Jung, Yoon Seok

    2015-12-22

    The new, highly conductive (4.1 × 10–4 S cm–1 at 30 °C), highly deformable, and dry-air-stable glass 0.4LiI-0.6Li4SnS4 is prepared using a homogeneous methanol solution. Furthermore, the solution process enables the wetting of any exposed surface of the active materials with highly conductive solidified electrolytes (0.4LiI-0.6Li4SnS4), resulting in considerable improvements in electrochemical performances of these electrodes over conventional mixture electrodes.

  5. Wide-band-gap, alkaline-earth-oxide semiconductor and devices utilizing same

    DOE Patents [OSTI]

    Abraham, Marvin M.; Chen, Yok; Kernohan, Robert H.

    1981-01-01

    This invention relates to novel and comparatively inexpensive semiconductor devices utilizing semiconducting alkaline-earth-oxide crystals doped with alkali metal. The semiconducting crystals are produced by a simple and relatively inexpensive process. As a specific example, a high-purity lithium-doped MgO crystal is grown by conventional techniques. The crystal then is heated in an oxygen-containing atmosphere to form many [Li].degree. defects therein, and the resulting defect-rich hot crystal is promptly quenched to render the defects stable at room temperature and temperatures well above the same. Quenching can be effected conveniently by contacting the hot crystal with room-temperature air.

  6. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries

    SciTech Connect (OSTI)

    Gu, Meng; Genc, Arda; Belharouak, Ilias; Wang, Dapeng; Amine, Khalil; Thevuthasan, Suntharampillai; Baer, Donald R.; Zhang, Jiguang; Browning, Nigel D.; Liu, Jun; Wang, Chong M.

    2013-05-14

    Li-rich layered material Li1.2Ni0.2Mn0.6O2 possesses high voltage and high specific capacity, which makes it an attractive candidate for the transportation industry and sustainable energy storage systems. The rechargeable capacity of the Li-ion battery is linked largely to the structural stability of the cathode materials during the charge-discharge cycles. However, the structure and cation distribution in pristine (un-cycled) Li1.2Ni0.2Mn0.6O2 have not yet been fully characterized. Using a combination of aberration-corrected scanning/transmission electron microscopy, X-ray dispersive energy spectroscopy (XEDS), electron energy loss spectroscopy (EELS), and complementary multislice image simulation, we have probed the crystal structure, cation/anion distribution, and electronic structure of Li1.2Ni0.2Mn0.6O2 nanoparticle. We discovered that the electronic structure and valence state of transition metal ions show significant variations, which have been identified to be attributed to the oxygen deficiency near the particle surfaces. Characterization of the nanoscale phase separation and cation ordering in the pristine material are critical for understanding the capacity and voltage fading of this material for battery application.

  7. Barometric and Earth Tide Correction

    Energy Science and Technology Software Center (OSTI)

    2005-11-10

    BETCO corrects for barometric and earth tide effects in long-term water level records. A regression deconvolution method is used ot solve a series of linear equations to determine an impulse response function for the well pressure head. Using the response function, a pressure head correction is calculated and applied.

  8. Structure of neutron-rich Isotopes {sup 8}Li and {sup 9}Li and allowance for it in elastic scattering

    SciTech Connect (OSTI)

    Ibraeva, E. T.; Zhusupov, M. A.; Imambekov, O.; Sagindykov, Sh. Sh.

    2008-07-15

    The differential cross sections for elastic proton scattering on the unstable neutron-rich nuclei {sup 8}Li and {sup 9}Li at E = 700 and 60 MeV per nucleon were considered. The {sup 8}Li nucleus was treated on the basis of the three-body {alpha}-t-n model, while the {sup 9}Li nucleus was considered within the {alpha}-t-n and {sup 7}Li-n-n models. The cross sections in question were calculated within Glauber diffraction theory. A comparison of the results with available experimental data made it possible to draw conclusions on the quality of the wave functions and potential used in the calculations.

  9. Habitability and energy performance of earth sheltered dwellings

    SciTech Connect (OSTI)

    Boyer, L.L.; Grondzik, W.T.

    1980-12-01

    The High Plains region of the central United States has become host to an emerging dwelling concept which incorporates the use of earth shelter technologies. Traditionally, inhabitants of this region have been sensitized to the need for windstorm protection. More recently, dramatic potentials for energy savings have served as a strong secondary inducement to the exploration of earth sheltered housing as an energy alternative. Habitability and passive energy design of earth sheltered structures are key focal elements being investigated at Oklahoma State University. Habitability aspects have received little treatment elsewhere, and existing passive energy design strategies have generally not considered the passive cooling benefits of earth sheltered construction. Extended questionnaires were used to obtain earth sheltered occupant responses to both habitability and energy design aspects including measured energy usage. Preliminary analysis has been completed on about 80 (eighty) projects in the State of Oklahoma, and the study is being extended to 8 (eight) additional surrounding states. Initial results indicate that occupants are generally satisfied with such attributes as structural safety, thermal comfort, and acoustical environment; but have some reservations concerning daylighting, site design, and energy design and performance. Energy usage patterns tend to indicate that, in fact, sizeable savings are being realized by owners of current generation earth shelters. However, it is anticipated that with optimized passive systems design, the presently realized savings could be further increased by perhaps a factor of two. An appropriate design balance must be realized between passive heating and passive cooling needs.

  10. Suitable thin shell structural configurations for earth sheltered housing

    SciTech Connect (OSTI)

    Behr, R.A.

    1982-01-01

    An earth sheltered house is one whose building envelope is substantially in contact with soil, without necessarily being totally underground. Hence, it can provide the commonly sought attributes of a residence, including natural light, exterior views, and curb appeal. It also exhibits strong energy performance, lower maintenance, and good storm protection. Despite the longer-term life cycle cost advantages of earth sheltered buildings, a current hindrance to the mass market acceptance of earth sheltered housing is higher initial cost which is caused, in part, by the inability of conventional rectilinear structural systems to support economically the massive soil loads imposed on earth covered buildings. In deference to the premise that technical suitability is no guarantee of innovation acceptance in the housing industry, a survey of the nontechnical impediments to housing innovation was first undertaken. These impediment areas include: market inhibition; builder trepidations; industry constraints; and financing problems. As a result of an architectural design program written under contract for the Department of Energy, it was possible to include a rather extensive (but necessarily subjective) evaluation of the architectural potential for earth sheltered shell structures. Engineering suitability dimensions included structural effectiveness, constructability, and economy of construction for single- and double-curvature thin shell structures. Overall engineering suitability and architectural potential are deemed to be adequate, although non-engineering impediments to housing innovation appear to raise significant questions regarding the potential for mass market implementation of thin shell stuctures in earth sheltered housing.

  11. I I LI I L I

    Office of Legacy Management (LM)

    LI - I L I 1 II C c - ORNL/RASA-9618 OAK RlDGE NATlONAl. LA8ORATORY Results of the Independent Radiological Verification Survey at B&T Metals, 425 West Town Street, Columbus, Ohio (cooolv) M . E. Murray V. P. Patania C. A. Johnson M N M E D *wD OPEbM~ B V WUCNEEDllW?ME IWiARCH CoRpoRAng FoRTHEwITf@%tATeB ltEpAAMwTmBMeR(Ly ORNL-27 (34el ~~- L._~ This report has been reproduced directly from the best available copy. Avaiiable to DOE and DOE contractors from the Office of Scientific and

  12. Material review of Li ion battery separators

    SciTech Connect (OSTI)

    Weber, Christoph J. Geiger, Sigrid; Falusi, Sandra; Roth, Michael

    2014-06-16

    Separators for Li Ion batteries have a strong impact on cell production, cell performance, life, as well as reliability and safety. The separator market volume is about 500 million m{sup 2} mainly based on consumer applications. It is expected to grow strongly over the next decade for mobile and stationary applications using large cells. At present, the market is essentially served by polyolefine membranes. Such membranes have some technological limitations, such as wettability, porosity, penetration resistance, shrinkage and meltdown. The development of a cell failure due to internal short circuit is potentially closely related to separator material properties. Consequently, advanced separators became an intense area of worldwide research and development activity in academia and industry. New separator technologies are being developed especially to address safety and reliability related property improvements.

  13. Earth Week event all about energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth Week 2016 Earth Week 2016 Earth Week 2016 THIS YEAR, WE'RE CELEBRATING EARTH DAY ALL WEEK LONG. It's #EarthWeek on Energy.gov! We're focusing on climate change, highlighting how we're helping the nation #ActOnClimate. Follow along all week on Twitter, Facebook and Instagram. VIDEO Building a Better Future Through Clean Energy As we celebrate #EarthWeek, meet some of the inspirational individuals who are making America's clean energy future a reality and addressing climate change every day.

  14. Earth Week 2016 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Earth Week 2016 Earth Week 2016 Earth Week 2016 THIS YEAR, WE'RE CELEBRATING EARTH DAY ALL WEEK LONG. It's #EarthWeek on Energy.gov! We're focusing on climate change, highlighting how we're helping the nation #ActOnClimate. Follow along all week on Twitter, Facebook and Instagram. VIDEO Building a Better Future Through Clean Energy As we celebrate #EarthWeek, meet some of the inspirational individuals who are making America's clean energy future a reality and addressing climate change every day.

  15. Investigation of the Decomposition Mechanism of Lithium Bis(oxalate)borate (LiBOB) Salt in the Electrolyte of an Aprotic LiO2 Battery

    SciTech Connect (OSTI)

    Lau, Kah Chun; Lu, Jun; Low, John; Peng, Du; Wu, Huiming; Albishri, Hassan M.; Al-Hady, D. Abd; Curtiss, Larry A.; Amine, Khalil

    2014-04-01

    The stability of the lithium bis(oxalate) borate (LiBOB) salt against lithium peroxide (Li2O2) formation in an aprotic LiO2 (Liair) battery is investigated. From theoretical and experimental findings, we find that the chemical decomposition of LiBOB in electrolytes leads to the formation lithium oxalate during the discharge of a LiO2 cell. According to density functional theory (DFT) calculations, the formation of lithium oxalate as the reaction product is exothermic and therefore is thermodynamically feasible. This reaction seems to be independent of solvents used in the LiO2 cell, and therefore LiBOB is probably not suitable to be used as the salt in LiO2 cell electrolytes.

  16. New solid-state synthesis routine and mechanism for LiFePO{sub 4} using LiF as lithium precursor

    SciTech Connect (OSTI)

    Wang Deyu; Li Hong; Wang Zhaoxiang; Wu Xiaodong; Sun Yucheng; Huang Xuejie; Chen Liquan . E-mail: lqchen@aphy.iphy.ac.cn

    2004-12-01

    Li{sub 2}CO{sub 3} and LiOH.H{sub 2}O are widely used as Li-precursors to prepare LiFePO{sub 4} in solid-phase reactions. However, impurities are often found in the final product unless the sintering temperature is increased to 800 deg. C. Here, we report that lithium fluoride (LiF) can also be used as Li-precursor for solid-phase synthesis of LiFePO{sub 4} and very pure olivine phase was obtained even with sintering at a relatively low temperature (600 deg. C). Consequently, the product has smaller particle size (about 500nm), which is beneficial for Li-extraction/insertion in view of kinetics. As for cathode material for Li-ion batteries, LiFePO{sub 4} obtained from LiF shows high Li-storage capacity of 151mAhg{sup -1} at small current density of 10mAg{sup -1} (1/15C) and maintains capacity of 54.8mAhg{sup -1} at 1500mAg{sup -1} (10C). The solid-state reaction mechanisms using LiF and Li{sub 2}CO{sub 3} precursors are compared based on XRD and TG-DSC.

  17. DOE Co-Spnsors Earth Day Activities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DOE Co-Sponsors Earth Day Activities Free trees and native plants are available to the first participants at the Idaho Falls Earth Day festivities in Tautphaus Park. There are a...

  18. EarthCraft Virginia | Open Energy Information

    Open Energy Info (EERE)

    EarthCraft Virginia Jump to: navigation, search Name: EarthCraft Virginia Place: Richmond, VA Zip: 23220 Website: www.ecvirginia.org Coordinates: 37.5464259, -77.4644607 Show...

  19. EarthRise Capital | Open Energy Information

    Open Energy Info (EERE)

    EarthRise Capital Jump to: navigation, search Name: EarthRise Capital Place: New York, New York Zip: NY 10111 Sector: Efficiency Product: Venture capital fund focused on new...

  20. Google Earth Tour: Water reuse at LANL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Google Earth Tour: Water reuse at LANL Google Earth Tour: Water reuse at LANL Open full screen to view more You are running an unsupported browser, some features may not work....

  1. Alternative Earth Resources Inc | Open Energy Information

    Open Energy Info (EERE)

    840 - 1140 West Pender St. Place: Vancouver, B.C. Zip: V6E 4G1 Sector: Geothermal energy Website: www.alternative-earth.comsHo References: Alternative Earth Website1...

  2. Production method for making rare earth compounds

    DOE Patents [OSTI]

    McCallum, R.W.; Ellis, T.W.; Dennis, K.W.; Hofer, R.J.; Branagan, D.J.

    1997-11-25

    A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g., a transition metal and optional boron), and a carbide-forming element (e.g., a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g., Nd{sub 2}Fe{sub 14}B or LaNi{sub 5}) and a carbide of the carbide-forming element are formed.

  3. Production method for making rare earth compounds

    DOE Patents [OSTI]

    McCallum, R. William; Ellis, Timothy W.; Dennis, Kevin W.; Hofer, Robert J.; Branagan, Daniel J.

    1997-11-25

    A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g. a transition metal and optional boron), and a carbide-forming element (e.g. a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g. Nd.sub.2 Fe.sub.14 B or LaNi.sub.5) and a carbide of the carbide-forming element are formed.

  4. Earth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Services » Earned Value Management Earned Value Management Earned Value Management The mission of the DOE Earned Value Management website is to educate and train on theory and practice of Earned Value Management, and use it as an integrated Project Management process. Earned Value Management (EVM) is a systematic approach to the integration and measurement of cost, schedule, and technical (scope) accomplishments on a project or task. It provides both the government and contractors the ability

  5. Earth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Take Monica Witt, for example. The Lab's sustainability program manager and a key advocate ... A volunteer on the county's sustainability board for eight years, Witt is committed to ...

  6. Earth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... last month. - 71315 Claudia Mora Geological Society of America selects Los Alamos ... Photo courtesy U.S. Department of Energy. Global samples from nuclear contamination sites ...

  7. Argonne's 2012 Earth Day Event

    ScienceCinema (OSTI)

    None

    2013-04-19

    Argonne's 2012 Earth Day event drew crowds from across the laboratory. Argonne and U.S. Department of Energy employees toured booths and interactive displays set up by Argonne programs and clubs. Several of Argonne's partners participated, including U.S. Department of Energy, University of Chicago, Abri Credit Union, DuPage County Forest Preserve, DuPage Water Commission, PACE and Morton Arboretum. Argonne scientists and engineers also participated in a poster session, discussing their clean energy research.

  8. Effects of electrolyte salts on the performance of Li-O2 batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Burton, Sarah D.; Cosimbescu, Lelia; Gross, Mark E.; Zhang, Jiguang

    2013-02-05

    It is well known that the stability of nonaqueous electrolyte is critical for the rechargeable Li-O2 batteries. Although stability of many solvents used in the electrolytes has been investigated, considerably less attention has been paid to the stability of electrolyte salt which is the second major component. Herein, we report the systematic investigation of the stability of seven common lithium salts in tetraglyme used as electrolytes for Li-O2 batteries. The discharge products of Li-O2 reaction were analyzed by X-ray diffraction, X-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy. The performance of Li-O2 batteries was strongly affected by the salt used in the electrolyte. Lithium tetrafluoroborate (LiBF4) and lithium bis(oxalato)borate (LiBOB) decompose and form LiF and lithium borates, respectively during the discharge of Li-O2 batteries. Several other salts, including lithium bis(trifluoromethane)sulfonamide (LiTFSI), lithium trifluoromethanesulfonate (LiTf), lithium hexafluorophosphate (LiPF6), lithium perchlorate (LiClO4) , and lithium bromide (LiBr) led to the discharge products which mainly consisted of Li2O2 and only minor signs of decomposition of LiTFSI, LiTf, LPF6 and LiClO4 were detected. LiBr showed the best stability during the discharge process. As for the cycling performance, LiTf and LiTFSI were the best among the studied salts. In addition to the instability of lithium salts, decomposition of tetraglyme solvent was a more significant factor contributing to the limited cycling stability. Thus a more stable nonaqueous electrolyte including organic solvent and lithium salt still need to be further developed to reach a fully reversible Li-O2 battery.

  9. LiF/ZnS Neutron Multiplicity Counter

    SciTech Connect (OSTI)

    Stave, Sean C.; Bliss, Mary; Kouzes, Richard T.; Lintereur, Azaree T.; Robinson, Sean M.; Siciliano, Edward R.; Wood, Lynn S.

    2015-06-01

    Abstract: Alternatives to the use of 3He for the detection of thermal neutrons are being investigated. One of the most challenging applications for 3He alternatives is in neutron multiplicity counters. Neutron multiplicity counters are used to provide rapid assay of samples which contain an unknown amount of plutonium in a potentially unknown configuration. With appropriate detector design, the neutron single, double, and triple coincidence events can be used to extract information of three unknown parameters such as the 240Pu-effective mass, the sample self-multiplication, and the (α,n) rate. A project at PNNL has investigated replacing 3He-based tubes with LiF/ZnS neutron-scintillator sheets and wavelength shifting plastic for light pipes. A four-panel demonstrator module has been constructed, tested, and compared with detailed modeling results. The findings indicate that a full-scale system can be constructed with the same overall size as the most efficient 3He-based system and with improved performance. Remaining design challenges include electronics and robust neutron/gamma-ray discrimination based on pulse shape analysis at high rates. A review of the current effort and the most recent findings will be presented.

  10. Wood panel earth shelter construction

    SciTech Connect (OSTI)

    Berg, J.R.; Loveless, J.G.; Senkow, W.

    1986-05-27

    An earth sheltered building is described including an arch structure, the structure including footings, a floor extending between the footings and arch means extending between the footings and having a base having lower ends on the footings for defining an enclosure which is covered with earth and open at opposite ends. The arch structure consists of: joined, curved wooden panel sections arranged in tandem in adjacent rows with more than two panel sections in a row, each of the sections including circumferentially extending wooden side members; wooden sheathing sections overlying the top skins of panel sections, the sheathing including a plurality of plywood sheets lapped over the joints between the panel sections and treated with a preservative; an adhesive joining the panel sections together within each row and to adjacent rows; waterproofing means on the sheathing for waterproofing the exterior surface of the arch means; connecting means engaging the base of the arch means at the footings and within the floor for tying the base together at its lower ends; and end walls and fastener means for joining the end walls to lateral edges of the arch means, the end walls dimensioned to extend above the arch means to retain earth placed on the arch means.

  11. Electrochemical Investigation of Al–Li/LixFePO4 Cells in Oligo(ethylene glycol) Dimethyl Ether/LiPF6

    SciTech Connect (OSTI)

    Wang, X.J.; Zhou, Y.N.; Lee, H.S.; Nam, K.W.; Yang, X.Q.; Haas, O.

    2011-02-01

    1 M LiPF{sub 6} dissolved in oligo(ethylene glycol) dimethyl ether with a molecular weight, 500 g mol{sup -1} (OEGDME500, 1 M LiPF{sub 6}), was investigated as an electrolyte in experimental Al-Li/LiFePO{sub 4} cells. More than 60 cycles were achieved using this electrolyte in a Li-ion cell with an Al-Li alloy as an anode sandwiched between two Li x FePO{sub 4} electrodes (cathodes). Charging efficiencies of 96-100% and energy efficiencies of 86-89% were maintained during 60 cycles at low current densities. A theoretical investigation revealed that the specific energy can be increased up to 15% if conventional LiC{sub 6} anodes are replaced by Al-Li alloy electrodes. The specific energy and the energy density were calculated as a function of the active mass per electrode surface (charge density). The results reveal that for a charge density of 4 mAh cm{sup -2} about 160 mWh g{sup -1} can be reached with Al-Li/LiFePO{sub 4} batteries. Power limiting diffusion processes are discussed, and the power capability of Al-Li/LiFePO{sub 4} cells was experimentally evaluated using conventional electrolytes.

  12. Category:Earth Tidal Analysis | Open Energy Information

    Open Energy Info (EERE)

    Earth Tidal Analysis Jump to: navigation, search Geothermalpower.jpg Looking for the Earth Tidal Analysis page? For detailed information on Earth Tidal Analysis, click here....

  13. Beijing ChangLi Union Energy Company | Open Energy Information

    Open Energy Info (EERE)

    Municipality, China Product: China-based technology company that research in zinc-air batteries (fuel cells). References: Beijing ChangLi Union Energy Company1 This article is a...

  14. Transport and Failure in Li-ion Batteries | Stanford Synchrotron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Li-ion Batteries Monday, February 13, 2012 - 1:30pm SSRL Conference Room 137-322 Stephen J. Harris, General Motors R&D While battery performance is well predicted by the...

  15. LiDAR (Lewicki & Oldenburg) | Open Energy Information

    Open Energy Info (EERE)

    Technique LiDAR Activity Date Usefulness useful DOE-funding Unknown References Jennifer L. Lewicki, Curtis M. Oldenburg (Unknown) Near-Surface Co2 Monitoring And Analysis To...

  16. Qiaojia River Power Co Ltd Li County | Open Energy Information

    Open Energy Info (EERE)

    Changde City, Hainan Province, China Zip: 415500 Sector: Hydro Product: Hunan-based small hydro developer. References: Qiaojia River Power Co., Ltd, Li County1 This article is a...

  17. Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Wang, Chong M.; Zuo, Pengjian; Koech, Phillip K.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-09-20

    Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially three to five times higher energy density than that of traditional lithium ion batteries. However, the dissolution and precipitation of soluble polysulfides during cycling initiate a series of key-chain reactions that significantly shorten battery life. Herein, we demonstrate that through a simple but effective strategy, significantly improved cycling performance is achieved for high sulfur loading electrodes through controlling the nucleation and precipitation of polysulfieds on the electrode surface. More than 400 or 760 stable cycling are successfully displayed in the cells with locked discharge capacity of 625 mAh g-1 or 500 mAh g-1, respectively. The nucleation and growth process of dissolved polysulfides has been electrochemically altered to confine the thickness of discharge products passivated on the cathode surface, increasing the utilization rate of sulfur while avoiding severe morphology changes on the electrode. More importantly, the exposure of new lithium metal surface to the S-containing electrolyte is also greatly reduced through this strategy, largely minimizing the anode corrosion caused by polysulfides. This work interlocks the electrode morphologies and its evolution with electrochemical interference to modulate cell performances by using Li-S system as a platform, providing different but critical directions for this community.

  18. Unraveling the voltage fade mechanism in layer Li-Mn-rich electrode: formation of the tetrahedral cations for spinel conversion

    SciTech Connect (OSTI)

    Mohanty, Debasish; Li, Jianlin; Abraham, Daniel P; Huq, Ashfia; Payzant, E Andrew; Wood III, David L; Daniel, Claus

    2014-01-01

    Discovery of high-voltage layered lithium-and manganese-rich (LMR) composite oxide electrode has dramatically enhanced the energy density of current Li-ion energy storage systems. However, practical usage of these materials is currently not viable because of their inability to maintain a consistent voltage profile (voltage fading) during subsequent charge-discharge cycles. This report rationalizes the cause of this voltage fade by providing the evidence of layer to spinel-like (LSL) structural evolution pathways in the host Li1.2Mn0.55Ni0.15Co0.1O2 LMR composite oxide. By employing neutron powder diffraction, and temperature dependent magnetic susceptibility, we show that LSL structural rearrangement in LMR oxide occurs through a tetrahedral cation intermediate via: i) diffusion of lithium atoms from octahedral to tetrahedral sites of the lithium layer [(LiLioct LiLitet] which is followed by the dispersal of the lithium ions from the adjacent octahedral site of the metal layer to the tetrahedral sites of lithium layer [LiTM oct LiLitet]; and ii) migration of Mn from the octahedral sites of the transition metal layer to the permanent octahedral site of lithium layer via tetrahedral site of lithium layer [MnTMoct MnLitet MnLioct)]. The findings opens the door to the potential routes to mitigate this atomic restructuring in the high-voltage LMR composite oxide cathodes by manipulating the composition/structure for practical use in high-energy-density lithium-ion batteries.

  19. ARM - Campaign Instrument - twin-otter-li-prof

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentstwin-otter-li-prof Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign Instrument : Twin Otter Lidar Profiles (TWIN-OTTER-LI-PROF) Instrument Categories Aerosols, Atmospheric Profiling, Cloud Properties Campaigns Tropical Warm Pool - International Cloud Experiment (TWP-ICE) [ Download Data ] Tropical Western Pacific, 2006.01.21 - 2006.02.13 Primary Measurements Taken The following measurements are those considered

  20. Combined Quantum Chemical/Raman Spectroscopic Analyses of Li+ Cation

    Office of Scientific and Technical Information (OSTI)

    Solvation: Cyclic Carbonate Solvents - Ethylene Carbonate and Propylene Earbonate (Journal Article) | SciTech Connect Combined Quantum Chemical/Raman Spectroscopic Analyses of Li+ Cation Solvation: Cyclic Carbonate Solvents - Ethylene Carbonate and Propylene Earbonate Citation Details In-Document Search Title: Combined Quantum Chemical/Raman Spectroscopic Analyses of Li+ Cation Solvation: Cyclic Carbonate Solvents - Ethylene Carbonate and Propylene Earbonate Combined computational/Raman

  1. Dendrite-Free Li Deposition Using Trace-Amounts of Water as an Electrolyte

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Additive - Joint Center for Energy Storage Research April 25, 2015, Research Highlights Dendrite-Free Li Deposition Using Trace-Amounts of Water as an Electrolyte Additive Dendrite growth leads to low CE and safety issues of Li anode. Trace amount of water enables dendrite-free Li deposition. Scientific Achievement Residual water (H2O) present in nonaqueous electrolytes has been widely regarded as a detrimental factor for lithium (Li) batteries. However, dendrite-free Li film can be obtained

  2. Heteroclite electrochemical stability of an I based Li7P2S8I superionic conductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rangasamy, Ezhiylmurugan; Liu, Zengcai; Gobet, Mallory; Pilar, Kartik; Sahu, Gayatri; Greenbaum, Steve; Liang, Chengdu

    2015-01-01

    Stability from Instability: A Li7P2S8I solid state Li-ion conductor derived from -Li3PS4 and LiI demonstrates exceptional electrochemical stability. The oxidation instability of I is subverted nullified via its incorporation into the coordinated structure. The inclusion of I also creates stability with metallic Li anode while simultaneously improving the interfacial kinetics. Low temperature membrane processability enables facile fabrication of dense membranes, making it suitable for industrial adoption.

  3. Fluoro-Carbonate Solvents for Li-Ion Cells

    SciTech Connect (OSTI)

    NAGASUBRAMANIAN,GANESAN

    1999-09-17

    A number of fluoro-carbonate solvents were evaluated as electrolytes for Li-ion cells. These solvents are fluorine analogs of the conventional electrolyte solvents such as dimethyl carbonate, ethylene carbonate, diethyl carbonate in Li-ion cells. Conductivity of single and mixed fluoro carbonate electrolytes containing 1 M LiPF{sub 6} was measured at different temperatures. These electrolytes did not freeze at -40 C. We are evaluating currently, the irreversible 1st cycle capacity loss in carbon anode in these electrolytes and the capacity loss will be compared to that in the conventional electrolytes. Voltage stability windows of the electrolytes were measured at room temperature and compared with that of the conventional electrolytes. The fluoro-carbon electrolytes appear to be more stable than the conventional electrolytes near Li voltage. Few preliminary electrochemical data of the fluoro-carbonate solvents in full cells are reported in the literature. For example, some of the fluorocarbonate solvents appear to have a wider voltage window than the conventional electrolyte solvents. For example, methyl 2,2,2 trifluoro ethyl carbonate containing 1 M LiPF{sub 6} electrolyte has a decomposition voltage exceeding 6 V vs. Li compared to <5 V for conventional electrolytes. The solvent also appears to be stable in contact with lithium at room temperature.

  4. Optimized Operating Range for Large-Format LiFePO4/Graphite Batteries

    SciTech Connect (OSTI)

    Jiang, Jiuchun; Shi, Wei; Zheng, Jianming; Zuo, Pengjian; Xiao, Jie; Chen, Xilin; Xu, Wu; Zhang, Jiguang

    2014-06-01

    e investigated the long-term cycling performance of large format 20Ah LiFePO4/graphite batteries when they are cycled in various state-of-charge (SOC) ranges. It is found that batteries cycled in the medium SOC range (ca. 20~80% SOC) exhibit superior cycling stability than batteries cycled at both ends (0-20% or 80-100%) of the SOC even though the capcity utilized in the medium SOC range is three times as large as those cycled at both ends of the SOC. Several non-destructive techniques, including a voltage interruption approach, model-based parameter identification, electrode impedance spectra analysis, ΔQ/ΔV analysis, and entropy change test, were used to investigate the performance of LiFePO4/graphite batteries within different SOC ranges. The results reveal that batteries at the ends of SOC exhibit much higher polarization impedance than those at the medium SOC range. These results can be attributed to the significant structural change of cathode and anode materials as revealed by the large entropy change within these ranges. The direct correlation between the polarization impedance and the cycle life of the batteries provides an effective methodology for battery management systems to control and prolong the cycle life of LiFePO4/graphite and other batteries.

  5. On the spin-axis dynamics of a Moonless Earth

    SciTech Connect (OSTI)

    Li, Gongjie; Batygin, Konstantin

    2014-07-20

    The variation of a planet's obliquity is influenced by the existence of satellites with a high mass ratio. For instance, Earth's obliquity is stabilized by the Moon and would undergo chaotic variations in the Moon's absence. In turn, such variations can lead to large-scale changes in the atmospheric circulation, rendering spin-axis dynamics a central issue for understanding climate. The relevant quantity for dynamically forced climate change is the rate of chaotic diffusion. Accordingly, here we re-examine the spin-axis evolution of a Moonless Earth within the context of a simplified perturbative framework. We present analytical estimates of the characteristic Lyapunov coefficient as well as the chaotic diffusion rate and demonstrate that even in absence of the Moon, the stochastic change in Earth's obliquity is sufficiently slow to not preclude long-term habitability. Our calculations are consistent with published numerical experiments and illustrate the putative system's underlying dynamical structure in a simple and intuitive manner.

  6. Mitigation of ASR by the use of LiNO{sub 3}Characterization of the reaction products

    SciTech Connect (OSTI)

    Leemann, Andreas, E-mail: andreas.leemann@empa.ch [Empa, Swiss Federal Laboratories for Materials Science and Technology, berlandstr. 129, 8600 Dbendorf (Switzerland); Lrtscher, Luzia [Institute for Surface Science and Technology (D-MATL), ETH Zurich, Schafmattstr. 6, 8093 Zurich (Switzerland); Bernard, Laetitia; Le Saout, Gwenn; Lothenbach, Barbara [Empa, Swiss Federal Laboratories for Materials Science and Technology, berlandstr. 129, 8600 Dbendorf (Switzerland); Espinosa-Marzal, Rosa M. [Institute for Surface Science and Technology (D-MATL), ETH Zurich, Schafmattstr. 6, 8093 Zurich (Switzerland)

    2014-05-01

    The influence of the LiNO{sub 3} on the ASR product was studied both in a model system and in mortars. In the model system, the addition of LiNO{sub 3} decreases the dissolution rate and the solubility of silica. Lithium changes the 2-dimensional cross-linked (Q{sub 3} dominated) network of the ASR product into a less structured, Q{sub 2} dominated product, likely by adopting the role of calcium. In the mortar samples the addition of LiNO{sub 3} decreases expansion and significantly influences the chemical composition and the morphology of the reaction product. Lithium decreases the calcium, sodium and potassium content and changes the relatively porous plate-like reaction product into a dense one without texture. The findings in the mortars indicate that the ASR-suppressing effect of lithium is caused by the lower potential of the reaction product to swell. Furthermore, it forms a protective barrier after an initial reaction slowing down ASR. - Highlights: Detection of lithium in ASR product by ToF-SIMS Relation between composition of pore solution and ASR product Identification of ASR suppressing mechanisms of LiNO{sub 3}.

  7. Earth boring machine and method

    SciTech Connect (OSTI)

    Sullinger, R.

    1983-09-13

    An earth boring machine and method are disclosed. An above-ground reference line, such as a laser beam, is established for a hole to be bored. The direction of the reference line is detected. The direction of a cutting head of the boring machine in a bore hole is detected and signals of the detected direction are transmitted to a control unit for comparison with the reference line direction. The boring machine is controlled with, for example, cam actuated adjustable peripheral cutters on the cutting head so that the direction of the boring machine can be adjusted to that of the reference line.

  8. Structural and Electrochemical Characterization of Pure LiFePO 4 and Nanocomposite C- LiFePO 4 Cathodes for Lithium Ion Rechargeable Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumar, Arun; Thomas, R.; Karan, N. K.; Saavedra-Arias, J. J.; Singh, M. K.; Majumder, S. B.; Tomar, M. S.; Katiyar, R. S.

    2009-01-01

    Pure limore » thium iron phosphate ( LiFePO 4 ) and carbon-coated LiFePO 4 (C- LiFePO 4 ) cathode materials were synthesized for Li-ion batteries. Structural and electrochemical properties of these materials were compared. X-ray diffraction revealed orthorhombic olivine structure. Micro-Raman scattering analysis indicates amorphous carbon, and TEM micrographs show carbon coating on LiFePO 4 particles. Ex situ Raman spectrum of C- LiFePO 4 at various stages of charging and discharging showed reversibility upon electrochemical cycling. The cyclic voltammograms of LiFePO 4 and C- LiFePO 4 showed only a pair of peaks corresponding to the anodic and cathodic reactions. The first discharge capacities were 63, 43, and 13 mAh/g for C/5, C/3, and C/2, respectively for LiFePO 4 where as in case of C- LiFePO 4 that were 163, 144, 118, and 70 mAh/g for C/5, C/3, C/2, and 1C, respectively. The capacity retention of pure LiFePO 4 was 69% after 25 cycles where as that of C- LiFePO 4 was around 97% after 50 cycles. These results indicate that the capacity and the rate capability improved significantly upon carbon coating.« less

  9. Structural and Electrochemical Characterization of PureLiFePO4and Nanocomposite C-LiFePO4Cathodes for Lithium Ion Rechargeable Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumar, Arun; Thomas, R.; Karan, N. K.; Saavedra-Arias, J. J.; Singh, M. K.; Majumder, S. B.; Tomar, M. S.; Katiyar, R. S.

    2009-01-01

    Pure lithium iron phosphate (LiFePO4) and carbon-coatedLiFePO4(C-LiFePO4) cathode materials were synthesized for Li-ion batteries. Structural and electrochemical properties of these materials were compared. X-ray diffraction revealed orthorhombic olivine structure. Micro-Raman scattering analysis indicates amorphous carbon, and TEM micrographs show carbon coating onLiFePO4particles. Ex situ Raman spectrum of C-LiFePO4at various stages of charging and discharging showed reversibility upon electrochemical cycling. The cyclic voltammograms ofLiFePO4and C-LiFePO4showed only a pair of peaks corresponding to the anodic and cathodic reactions. The first discharge capacities were 63, 43, and 13?mAh/g for C/5, C/3, and C/2, respectively forLiFePO4where as in case of C-LiFePO4that were 163, 144,more118, and 70?mAh/g for C/5, C/3, C/2, and 1C, respectively. The capacity retention of pureLiFePO4was 69% after 25 cycles where as that of C-LiFePO4was around 97% after 50 cycles. These results indicate that the capacity and the rate capability improved significantly upon carbon coating.less

  10. Through-the-earth radio

    DOE Patents [OSTI]

    Reagor, David; Vasquez-Dominguez, Jose

    2006-05-09

    A method and apparatus for effective through-the-earth communication involves a signal input device connected to a transmitter operating at a predetermined frequency sufficiently low to effectively penetrate useful distances through-the earth, and having an analog to digital converter receiving the signal input and passing the signal input to a data compression circuit that is connected to an encoding processor, the encoding processor output being provided to a digital to analog converter. An amplifier receives the analog output from the digital to analog converter for amplifying said analog output and outputting said analog output to an antenna. A receiver having an antenna receives the analog output passes the analog signal to a band pass filter whose output is connected to an analog to digital converter that provides a digital signal to a decoding processor whose output is connected to an data decompressor, the data decompressor providing a decompressed digital signal to a digital to analog converter. An audio output device receives the analog output form the digital to analog converter for producing audible output.

  11. 2016 CROSSCUTTING RESEARCH & RARE EARTH ELEMENTS PORTFOLIOS REVIEW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2016 CROSSCUTTING RESEARCH & RARE EARTH ELEMENTS PORTFOLIOS REVIEW GRAND STATION 3-5 POSTER PRESENTATIONS TUESDAY, APRIL 19 - 5:00-6:45 P.M. ADVANCED SENSORS 1 2 3 4 5 * Passive Wireless Sensors Fabricated by Direct-Writing for Temperature and Health Monitoring of Energy Systems in Harsh-Environments - Ioannis Kortidis and Michael Comparetto, West Virginia University * High Temperature Integrated Gas and Temperature Wireless Microwave Acoustic Sensor System for Fossil Energy Applications -

  12. High performance anode for advanced Li batteries

    SciTech Connect (OSTI)

    Lake, Carla

    2015-11-02

    The overall objective of this Phase I SBIR effort was to advance the manufacturing technology for ASI’s Si-CNF high-performance anode by creating a framework for large volume production and utilization of low-cost Si-coated carbon nanofibers (Si-CNF) for the battery industry. This project explores the use of nano-structured silicon which is deposited on a nano-scale carbon filament to achieve the benefits of high cycle life and high charge capacity without the consequent fading of, or failure in the capacity resulting from stress-induced fracturing of the Si particles and de-coupling from the electrode. ASI’s patented coating process distinguishes itself from others, in that it is highly reproducible, readily scalable and results in a Si-CNF composite structure containing 25-30% silicon, with a compositionally graded interface at the Si-CNF interface that significantly improve cycling stability and enhances adhesion of silicon to the carbon fiber support. In Phase I, the team demonstrated the production of the Si-CNF anode material can successfully be transitioned from a static bench-scale reactor into a fluidized bed reactor. In addition, ASI made significant progress in the development of low cost, quick testing methods which can be performed on silicon coated CNFs as a means of quality control. To date, weight change, density, and cycling performance were the key metrics used to validate the high performance anode material. Under this effort, ASI made strides to establish a quality control protocol for the large volume production of Si-CNFs and has identified several key technical thrusts for future work. Using the results of this Phase I effort as a foundation, ASI has defined a path forward to commercialize and deliver high volume and low-cost production of SI-CNF material for anodes in Li-ion batteries.

  13. Influence of Li ions on the oxygen reduction reaction of platinum electrocatalyst

    SciTech Connect (OSTI)

    Liu, H; Xing, YC

    2011-06-01

    A Li-air battery can provide a much higher theoretical energy density than a Li-ion battery. The use of aqueous acidic electrolytes may prevent lithium oxide deposition from aprotic electrolytes and lithium carbonate precipitation from alkaline electrolytes. The present communication reports a study on the effect of Li ions on the oxygen reduction reaction (ORR) in sulfuric acid electrolytes. It was found that the Li ions have negligible interactions with the active surface of Pt catalysts. However, significantly lower ORR activities were found when Li ions are present in the sulfuric acid. The intrinsic kinetic activities were found to decrease with the increase of Li ion concentrations, but level off when the Li ion concentrations are larger than 1.0 M. The low activities of Pt catalysts in Li ion containing electrolytes were attributed to a constraining effect of Li ions on the diffusion of oxygen in the electrolyte solution. (C) 2011 Elsevier B.V. All rights reserved.

  14. DISCOVERY OF SUPER-Li-RICH RED GIANTS IN DWARF SPHEROIDAL GALAXIES

    SciTech Connect (OSTI)

    Kirby, Evan N.; Fu, Xiaoting; Deng, Licai; Guhathakurta, Puragra

    2012-06-10

    Stars destroy lithium (Li) in their normal evolution. The convective envelopes of evolved red giants reach temperatures of millions of kelvin, hot enough for the {sup 7}Li(p, {alpha}){sup 4}He reaction to burn Li efficiently. Only about 1% of first-ascent red giants more luminous than the luminosity function bump in the red giant branch exhibit A(Li) > 1.5. Nonetheless, Li-rich red giants do exist. We present 15 Li-rich red giants-14 of which are new discoveries-among a sample of 2054 red giants in Milky Way dwarf satellite galaxies. Our sample more than doubles the number of low-mass, metal-poor ([Fe/H] {approx}< -0.7) Li-rich red giants, and it includes the most-metal-poor Li-enhanced star known ([Fe/H] = -2.82, A(Li){sub NLTE} = 3.15). Because most of the stars have Li abundances larger than the universe's primordial value, the Li in these stars must have been created rather than saved from destruction. These Li-rich stars appear like other stars in the same galaxies in every measurable regard other than Li abundance. We consider the possibility that Li enrichment is a universal phase of evolution that affects all stars, and it seems rare only because it is brief.

  15. Towards a Fine-Resolution Global Coupled Climate System for Prediction...

    Office of Scientific and Technical Information (OSTI)

    58 GEOSCIENCES climate, numerical modeling, earth system model, ocean, sea-ice, mesoscale eddies climate, numerical modeling, earth system model, ocean, sea-ice, mesoscale...

  16. Accurate static and dynamic properties of liquid electrolytes for Li-ion batteries from ab initio molecular dynamics

    SciTech Connect (OSTI)

    Ganesh, P.; Jiang, D.; Kent, P.R.C.

    2011-03-31

    Lithium-ion batteries have the potential to revolutionize the transportation industry, as they did for wireless communication. A judicious choice of the liquid electrolytes used in these systems is required to achieve a good balance among high-energy storage, long cycle life and stability, and fast charging. Ethylene-carbonate (EC) and propylene-carbonate (PC) are popular electrolytes. However, to date, almost all molecular-dynamics simulations of these fluids rely on classical force fields, while a complete description of the functionality of Li-ion batteries will eventually require quantum mechanics. We perform accurate ab initio molecular-dynamics simulations of ethylene- and propylene-carbonate with LiPF6 at experimental concentrations to build solvation models which explain available neutron scattering and nuclear magnetic resonance (NMR) results and to compute Li-ion solvation energies and diffusion constants. Our results suggest some similarities between the two liquids as well as some important differences. Simulations also provide useful insights into formation of solid-electrolyte interphases in the presence of electrodes in conventional Li-ion batteries.

  17. Accurate static and dynamic properties of liquid-electrolytes for Li-ion batteries from ab initio molecular dynamics

    SciTech Connect (OSTI)

    Ganesh, Panchapakesan; Jiang, Deen; Kent, Paul R

    2011-01-01

    Lithium-ion batteries have the potential to revolutionize the transportation industry, as they did for wireless communication. A judicious choice of the liquid electrolytes used in these systems is required to achieve a good balance among high-energy storage, long cycle life and stability, and fast charging. Ethylene-carbonate (EC) and propylene-carbonate (PC) are popular electrolytes. However, to date, almost all molecular-dynamics simulations of these fluids rely on classical force fields, while a complete description of the functionality of Li-ion batteries will eventually require quantum mechanics. We perform accurate ab initio molecular-dynamics simulations of ethylene- and propylene-carbonate with LiPF6 at experimental concentrations to build solvation models which explain available neutron scattering and nuclear magnetic resonance (NMR) results and to compute Li-ion solvation energies and diffusion constants. Our results suggest some similarities between the two liquids as well as some important differences. Simulations also provide useful insights into formation of solid-electrolyte interphases in the presence of electrodes in conventional Li-ion batteries.

  18. Educate yourself about stewardship this Earth Day

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Educate yourself about stewardship this Earth Day Educate yourself about stewardship this Earth Day WHEN: Apr 20, 2016 12:00 PM - 2:00 PM WHERE: Bradbury Science Museum 1350 Central Ave, Los Alamos, NM 87544, USA CONTACT: Linda Anderman (505) 665-9196 CATEGORY: Bradbury INTERNAL: Calendar Login Event Description Earth Day open house Open House at the Bradbury Science Museum hosted by the Lab's Environmental Protection & Compliance-Environmental Stewardship resources team. Laboratory

  19. Local Students Celebrate Earth Day at NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Students Celebrate Earth Day at NREL For more information contact: e:mail: Public Affairs Golden, Colo., April 17, 1998 — Media are invited to cover Earth Day celebration designed to inspire a new generation of scientists to discover better ways of using our natural resources. What: The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) will host an Earth Day celebration for 60 elementary students. Hands-on activities will include building model solar cars and

  20. High Performance Cathodes for Li-Air Batteries

    SciTech Connect (OSTI)

    Xing, Yangchuan

    2013-08-22

    The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

  1. Degradation Reactions in SONY-Type Li-Ion Batteries

    SciTech Connect (OSTI)

    Nagasubramanian, G.; Roth, E. Peter

    1999-05-04

    Thermal instabilities were identified in SONY-type lithium-ion cells and correlated with interactions of cell constituents and reaction products. Three temperature regions of interaction were identified and associated with the state of charge (degree of Li intercalation) of the cell. Anodes were shown to undergo exothermic reactions as low as 100°C involving the solid electrolyte interface (SEI) layer and the LiPF6 salt in the electrolyte (EC: PC: DEC/LiPF6). These reactions could account for the thermal runaway observed in these cells beginning at 100°C. Exothermic reactions were also observed in the 200°C-300°C region between the intercalated lithium anodes, the LiPF6 salt and the PVDF. These reactions were followed by a high- temperature reaction region, 300°C-400°C, also involving the PVDF binder and the intercalated lithium anodes. The solvent was not directly involved in these reactions but served as a moderator and transport medhun. Cathode exotherrnic reactions with the PVDF binder were observed above 200oC and increased with the state of charge (decreasing Li content). This offers an explanation for the observed lower thermal runaway temperatures for charged cells.

  2. A Highly Active Nanostructured Metallic Oxide Cathode for Li-O2 Batteries -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Joint Center for Energy Storage Research 27, 2015, Research Highlights A Highly Active Nanostructured Metallic Oxide Cathode for Li-O2 Batteries (Top Right) Electrochemistry of a metallic Magnéli-phase Ti4O7 cathode in a Li-O2 cell depicting the galvanostatic discharge/charge profile with an onset of OER at 3.0V vs Li/Li, and formation of a TiO2-x interface on cycling. (Top Left) SEM image shows Li2O2 as ~10 nm thin platelets and film formed on Ti4O7 cathode. (Bottom) On-line mass spec

  3. Elastic Scattering of {sup 7}Li+{sup 27}Al at Backward Angles in the 7-11 MeV Energy Range for Application in RBS

    SciTech Connect (OSTI)

    Carnelli, P. F. F.; Arazi, A.; Cardona, M. A.; Figueira, J. M.; Hojman, D.; Martinez Heimann, D.; Negri, A. E.; Pacheco, A. J.; Abriola, D.; Capurro, O. A.; Fimiani, L.; Grinberg, P.; Marti, G. V.; Fernandez Niello, J. O.

    2010-08-04

    We have measured elastic excitation functions for the {sup 7}Li+{sup 27}Al system, in an energy range close to its Coulomb barrier (E{sub lab} = 8.4 MeV) in steps of 0.25 MeV. For this purpose, an array of eight surface-barrier detectors was used. To get an insight on the background composition (mainly {alpha} particles), a telescope-detector was used for atomic-number identification. Identical measurements for the {sup 6}Li+{sup 27}Al system are planned for the near future.

  4. LANL | Solid Earth Geophysics | EES-17

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to monitor underground explosions, maintain our ability to conduct tests, and develop the Yucca Mountain Project. In addition, we study the nonlinear properties of earth materials,...

  5. Earth-abundant semiconductors for photovoltaic applications ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth-abundant semiconductors for photovoltaic applications Thin film photovoltaics (solar cells) has the potential to revolutionize our energy landscape by producing clean,...

  6. Earth Turbines Inc | Open Energy Information

    Open Energy Info (EERE)

    Earth Turbines Inc Place: Hinesburg, Vermont Zip: 5461 Sector: Wind energy Product: Start-up company developing small-scale wind technology for the residential and commercial...

  7. EarthTronics Inc | Open Energy Information

    Open Energy Info (EERE)

    Name: EarthTronics Inc. Place: Muskegon, Michigan Zip: 49440 Product: Michigan-based firm that has licensed the Honeywell International brand for its gearless micro-scale...

  8. Earth Power Resources Inc | Open Energy Information

    Open Energy Info (EERE)

    Resources Inc is a company based in Tulsa, Oklahoma. Earth Power Resources Inc in Tulsa, OK is a private company categorized under: Electric Companies. Records show it was...

  9. Improved method for preparing rare earth sesquichalcogenides

    DOE Patents [OSTI]

    Takeshita, T.; Beaudry, B.J.; Gschneidner, K.A. Jr.

    1982-04-14

    An improved method for the preparation of high purity rare earth sesquichalcogenides is described. The rare earth, as one or more pieces of the metal, is sealed under a vacuum with a stoichiometric amount of sulfur or selenium and a small amount of iodine into a quartz reaction vessel. The sealed vessel is then heated to above the vaporization temperature of the chalcogen and below the melting temperature of the rare earth metal and maintained until the product has been formed. The iodine is then vaporized off leaving a pure product. The rare earth sulfides and selenides thus formed are useful as semiconductors and as thermoelectric generators. 3 tables.

  10. Clean Earth Capital LLP | Open Energy Information

    Open Energy Info (EERE)

    Capital LLP Jump to: navigation, search Name: Clean Earth Capital LLP Place: EDINBURGH, United Kingdom Zip: EH6 4NW Sector: Renewable Energy Product: Edinburgh-based corporate...

  11. Center for Space and Earth Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deadlines, Events Partnerships NSEC CSES Center for Space and Earth Science Formerly ... Geophysics David Coblentz (505) 667-2781 Email Space Physics Geoffrey Reeves (505) ...

  12. MIT- Earth Resources Laboratory | Open Energy Information

    Open Energy Info (EERE)

    Name: MIT- Earth Resources Laboratory Address: 77 Massachusetts Avenue Place: Cambridge, Massachusetts Zip: 02139 Region: Greater Boston Area Website: eaps.mit.eduerl...

  13. Earth Day Coalition | Open Energy Information

    Open Energy Info (EERE)

    Day Coalition Jump to: navigation, search Name: Earth Day Coalition Address: 3606 Bridge Avenue, Suite 4 Place: Cleveland, Ohio Zip: 44113 Coordinates: 41.4829135, -81.7117416...

  14. Earth Share Oregon | Open Energy Information

    Open Energy Info (EERE)

    Share Oregon Jump to: navigation, search Name: Earth Share Oregon Address: 319 SW Washington Street Place: Portland, Oregon Zip: 97204 Region: Pacific Northwest Area Website:...

  15. Ferrocement: a technique for passive solar earth sheltered structures

    SciTech Connect (OSTI)

    Impson, L.C.

    1982-01-01

    A system of construction is discussed which allows for the least cost with the most return yet noted in any of the current publications. This system utilizes commonly available and relatively inexpensive materials. The use of unskilled labor is possible, thereby expanding one's labor pool. This system also allows more design freedom than do any of the other construction techniques now widely practiced. This system of construction is ferrocement, a technique which has been in use intermittently since 1847. A method of insulating Earth Shelters is also discussed, as well as air flow characteristics of domes.

  16. Construction details of an earth-sheltered passive solar thermosiphon air house

    SciTech Connect (OSTI)

    Ashelman, R.B.; Hagen, G.C.

    1980-01-01

    Construction details are presented for Sunrise, a passive solar, earth-sheltered house in eastern West Virginia. Particular attention is paid to the thermosiphon air system, as well as structural, waterproofing and insulation details.

  17. Google Earth locations of USA and seafloor hydrothermal vents with associated rare earth element data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Andrew Fowler

    2016-02-10

    Google Earth .kmz files that contain the locations of geothermal wells and thermal springs in the USA, and seafloor hydrothermal vents that have associated rare earth element data. The file does not contain the actual data, the actual data is available through the GDR website in two tier 3 data sets entitled "Compilation of Rare Earth Element Analyses from US Geothermal Fields and Mid Ocean Ridge (MOR) Hydrothermal Vents" and "Rare earth element content of thermal fluids from Surprise Valley, California"

  18. Enhanced Geothermal in Nevada: Extracting Heat From the Earth to Generate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sustainable Power | Department of Energy Enhanced Geothermal in Nevada: Extracting Heat From the Earth to Generate Sustainable Power Enhanced Geothermal in Nevada: Extracting Heat From the Earth to Generate Sustainable Power April 12, 2013 - 11:17am Addthis Learn the basics of enhanced geothermal systems technology. I Infographic by <a href="http://energy.gov/contributors/sarah-gerrity">Sarah Gerrity</a>. Learn the basics of enhanced geothermal systems technology. I

  19. Ames Lab 101: Rare-Earth Recycling

    ScienceCinema (OSTI)

    Ryan Ott

    2013-06-05

    Recycling keeps paper, plastics, and even jeans out of landfills. Could recycling rare-earth magnets do the same? Perhaps, if the recycling process can be improved. Scientists at the U.S. Department of Energy's Ames Laboratory are working to more effectively remove the neodymium, a rare earth, from the mix of other materials in a magnet.

  20. The significance of Li-ion batteries in electric vehicle life...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The significance of Li-ion batteries in electric vehicle life-cycle energy and emissions and recycling's role in its reduction Title The significance of Li-ion batteries in...

  1. X-ray line polarization spectroscopy of Li-like satellite line...

    Office of Scientific and Technical Information (OSTI)

    spectroscopy of Li-like satellite line spectra Citation Details In-Document Search Title: X-ray line polarization spectroscopy of Li-like satellite line spectra We apply the ...

  2. X-ray line polarization spectroscopy of Li-like satellite line...

    Office of Scientific and Technical Information (OSTI)

    X-ray line polarization spectroscopy of Li-like satellite line spectra Citation Details In-Document Search Title: X-ray line polarization spectroscopy of Li-like satellite line ...

  3. Digital Sofcell Shanghai ShenLi Goeta solid oxide fuel cell joint...

    Open Energy Info (EERE)

    ShenLi Goeta solid oxide fuel cell joint venture Jump to: navigation, search Name: Digital Sofcell - Shanghai ShenLi - Goeta solid oxide fuel cell joint venture Place: China...

  4. Dendrite-free Li deposition using trace-amounts of water as an...

    Office of Scientific and Technical Information (OSTI)

    Dendrite-free Li deposition using trace-amounts of water as an electrolyte additive ... Title: Dendrite-free Li deposition using trace-amounts of water as an electrolyte additive ...

  5. Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Li-Ion Polymer Battery Cell Manufacturing Plant in USA Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA 2012 DOE Hydrogen and Fuel Cells Program and Vehicle ...

  6. LiDAR At Chocolate Mountains Area (Alm, Et Al., 2010) | Open...

    Open Energy Info (EERE)

    aerial Li-DAR survey flown over the project areas, securing over 177,000 square kilometers of <30cm accuracy digital elevation data. LiDAR data were analyzed to characterize...

  7. Xiang Ge Li La Xian Mai Di He Hydro Power Development Co Ltd...

    Open Energy Info (EERE)

    Xiang Ge Li La Xian Mai Di He Hydro Power Development Co Ltd Jump to: navigation, search Name: Xiang Ge Li La Xian Mai Di He Hydro Power Development Co., Ltd. Place: Yunnan...

  8. Study of novel nonflammable electrolytes in Sandia-built Li-ion...

    Office of Scientific and Technical Information (OSTI)

    Study of novel nonflammable electrolytes in Sandia-built Li-ion cells. Citation Details In-Document Search Title: Study of novel nonflammable electrolytes in Sandia-built Li-ion ...

  9. Model-Experimental Studies on Next-generation Li-ion Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Experimental Studies on Next-generation Li-ion Materials Model-Experimental Studies on Next-generation Li-ion Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program ...

  10. Miniature all-solid-state heterostructure nanowire Li-ion batteries...

    Office of Scientific and Technical Information (OSTI)

    Miniature all-solid-state heterostructure nanowire Li-ion batteries as a tool for ... Title: Miniature all-solid-state heterostructure nanowire Li-ion batteries as a tool for ...

  11. Effect of the Anion Activity on the Stability of Li Metal Anodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Li Metal Anodes in Lithium-Sulfur Batteries The lithium metal anode (bottom) ... Significance and Impact Identified one reason behind Li-S batteries failing to hold a ...

  12. Electrochemical Performances of LiMnPO4 Synthesized from Non...

    Office of Scientific and Technical Information (OSTI)

    Li1.1MnPO4 exhibits the most stable cycling ability probably because of the existence of a trace amount of Li3PO4 impurity that functions as a solid-state electrolyte on...

  13. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP...

  14. Method for laser drilling subterranean earth formations

    DOE Patents [OSTI]

    Shuck, Lowell Z.

    1976-08-31

    Laser drilling of subterranean earth formations is efficiently accomplished by directing a collimated laser beam into a bore hole in registry with the earth formation and transversely directing the laser beam into the earth formation with a suitable reflector. In accordance with the present invention, the bore hole is highly pressurized with a gas so that as the laser beam penetrates the earth formation the high pressure gas forces the fluids resulting from the drilling operation into fissures and pores surrounding the laser-drilled bore so as to inhibit deleterious occlusion of the laser beam. Also, the laser beam may be dynamically programmed with some time dependent wave form, e.g., pulsed, to thermally shock the earth formation for forming or enlarging fluid-receiving fissures in the bore.

  15. Redox Mediators that Promote Three-Dimensional Growth of Li2S on Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current Collectors in Lithium-Sulfur Batteries - Joint Center for Energy Storage Research 21, 2015, Research Highlights Redox Mediators that Promote Three-Dimensional Growth of Li2S on Carbon Current Collectors in Lithium-Sulfur Batteries Controlling the electrodeposition of Li2S onto C using a redox mediator, BPI. With BPI, sulfur utilization improves in Li-S cells due to remote reduction of polysulfides to Li2S. Scientific Achievement Developed, from computation and experiment, redox

  16. 2016 CROSSCUTTING RESEARCH AND RARE EARTH ELEMENTS PORTFOLIOS REVIEW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CROSSCUTTING RESEARCH AND RARE EARTH ELEMENTS PORTFOLIOS REVIEW MONDAY APRIL 18 7:00 AM REGISTRATION - Grand Station Foyer CONTINENTAL BREAKFAST - Grand Station 3-5 8:30 AM GENERAL SESSION Grand Station 1 & 2 Welcome and NETL Overview Grace M. Bochenek, Ph.D. Director National Energy Technology Laboratory Program Overviews * Fossil Energy Advanced Energy Systems (FE AES) - Regis Conrad, Division Director, FE AES * NETL Crosscutting Research and Analysis (CCRA) - Robert Romanosky, Acting

  17. Viscosity and density of aqueous solutions of LiBr, LiCl, ZnBr[sub 2], CaCl[sub 2], and LiNO[sub 3]; 1: Single salt solutions

    SciTech Connect (OSTI)

    Wimby, J.M.; Berntsson, T.S. . Dept. of Heat and Power Technology)

    1994-01-01

    New experimental data for the viscosity and density of the binary systems lithium chloride + water, lithium bromide + water, calcium chloride + water, lithium nitrate + water, and zinc bromide + water are presented. Densities are presented in tabular form and as 10-parameter correlations, while kinematic and dynamic viscosities are presented in tabular form. Data are presented in the concentration range from intermediate dilution to close to room temperature crystallization concentration. The temperature ranges are 20--70 C for density and 25--90 C for viscosity. When available, literature data are compared with the new data, and some disagreement is found. New thermogravimetric curves are presented for the dehydration of CaCl[sub 2], ZnBr[sub 2], and LiBr in order to enable evaluation of drying as a composition determination technique.

  18. Anode Materials for Rechargeable Li-Ion Batteries

    SciTech Connect (OSTI)

    Fultz, B.

    2001-01-12

    This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. At present, our experimental work involves only materials for Li storage, but we have been writing papers from our previous work on hydrogen-storage materials.

  19. Solvent extraction of Li+, H3O+ and NH4+ into nitrobenzene by using sodium dicarbollylcobaltate and calix[4]arene-bis(t-octylbenzo-18-crown-6)

    SciTech Connect (OSTI)

    Makrlik, Emanuel; Selucky, P.; Vanura, Petr; Moyer, Bruce A

    2013-01-01

    From extraction experiments and c-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + NaL+ (nb) , ML+ (nb) + Na+ (aq) taking place in the two-phase water nitrobenzene system (M+ = Li+, H3O+, NH+4; L = calix[4]arene-bis(t-octylbenzo-18-crown-6); aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complexes in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: zH3O+ < Li+ < NH+4.

  20. The Effects of Lithium Triflate (LiCF{sub 3}SO{sub 3}) on the PMMA-based Solid Polymer Electrolytes

    SciTech Connect (OSTI)

    Chew, K. W.; Chen, S. S.; Pang, W. L.; Tan, C. G.; Osman, Z.

    2010-03-11

    The effects of Lithium triflate salt (LiCF{sub 3}SO{sub 3}), on the poly (methyl methacrylate)(PMMA)-based solid polymer electrolytes plasticized with propylene carbonate (PC) solvated in Tetrahydrofuran (THF) have been studied through a.c impedance spectroscopy and infrared spectroscopy. Lithium triflate was incorporated into the predetermined PMMA/PC system that has the highest value of ionic conductivity. In current investigations, four combination systems: Pure PMMA, (PMMA+PC) systems, (PMMA+LiCF{sub 3}SO{sub 3}) and (PMMA+PC+LiCF{sub 3}SO{sub 3}) systems were prepared using the solution cast method. Solutions were stirred for numerous hours to obtain a homogenous solution before it is poured into the petri dishes under ambient temperature to form the solid electrolyte thin film. The films were then removed from petri discs and transferred into the dessicator for further drying prior to the different tests. From the characterization done through the a.c impedance spectroscopy, the highest room temperature ionic conductivity in the pure PMMA sample, (PMMA+PC) system and (PMMA+LiCF{sub 3}SO{sub 3}) system is 2.83x10{sup -12} Scm{sup -1}, 4.39x10{sup -11} Scm{sup -1} and 3.93x10{sup -6} Scm{sup -1} respectively. The conductivity for (PMMA+PC+LiCF{sub 3}SO{sub 3}) system was obtained with the 30 wt% of lithium triflate, which is 2.48x10{sup -5} Scm{sup -1}. Infrared spectroscopy shows that complexation occurred between the polymer and the plasticizer, and the polymer and plasticizer and salt. The interactions have been studied in the C=O band, C-O-C band and the O-CH{sub 3} band.

  1. Electrochemical Investigation of Li-Al Anodes in Oligo (ethylene glycol) Dimethyl ether/LiPF6

    SciTech Connect (OSTI)

    Y Zhou; X Wang; H Lee; K Nam; X Yang; O Haas

    2011-12-31

    LiPF{sub 6} dissolved in oligo(ethylene glycol) dimethyl ether with a molecular weight 5 g mol{sup -1} was investigated as a new electrolyte (OEGDME5, 1 M LiPF{sub 6}) for metal deposition and battery applications. At 25 C a conductivity of .48 x 1{sup -3} S cm{sup -1} was obtained and at 85 C, 3.78 x 1{sup -3} S cm{sup -1}. The apparent activation barrier for ionic transport was evaluated to be 3.7 kJ mol{sup -1}. OEGDME5, 1 M LiPF{sub 6} allows operating temperature above 1 C with very attractive conductivity. The electrolyte shows excellent performance at negative and positive potentials. With this investigation, we report experimental results obtained with aluminum electrodes using this electrolyte. At low current densities lithium ion reduction and re-oxidation can be achieved on aluminum electrodes at potentials about 28 mV more positive than on lithium electrodes. In situ X-ray diffraction measurements collected during electrochemical lithium deposition on aluminum electrodes show that the shift to positive potentials is due to the negative Gibbs free energy change of the Li-Al alloy formation reaction.

  2. Method for treating electrolyte to remove Li.sub.2 O

    DOE Patents [OSTI]

    Tomczuk, Zygmunt; Miller, William E.; Johnson, Gerald K.; Willit, James L.

    1998-01-01

    A method of removing Li.sub.2 O present in an electrolyte predominantly of LiCl and KCl. The electrolyte is heated to a temperature not less than about 500.degree. C. and then Al is introduced into the electrolyte in an amount in excess of the stoichiometric amount needed to convert the Li.sub.2 O to a Li-Al alloy and lithium aluminate salt. The salt and aluminum are maintained in contact with agitation for a time sufficient to convert the Li.sub.2 O.

  3. Method for treating electrolyte to remove Li{sub 2}O

    DOE Patents [OSTI]

    Tomczuk, Z.; Miller, W.E.; Johnson, G.K.; Willit, J.L.

    1998-01-20

    A method is described for removing Li{sub 2}O present in an electrolyte predominantly of LiCl and KCl. The electrolyte is heated to a temperature not less than about 500 C and then Al is introduced into the electrolyte in an amount in excess of the stoichiometric amount needed to convert the Li{sub 2}O to a Li-Al alloy and lithium aluminate salt. The salt and aluminum are maintained in contact with agitation for a time sufficient to convert the Li{sub 2}O.

  4. First-Principles Calculations, Electrochemical and X-ray Absorption Studies of Li-Ni-PO4 Surface-Treated xLi2MnO3 (1 x)LiMO2 (M = Mn, Ni, Co) Electrodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Wolverton, Christopher; Croy, J R; Balasubramanian, M; Kang, Sun-Ho; Lopez-Rivera, C. M.; Thackeray, Michael M.

    2012-01-01

    It has been previously hypothesized that the enhanced rate capability of Li-Ni-PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} positive electrodes (M = Mn, Ni, Co) in Li-ion batteries might be associated with a defect Ni-doped Li{sub 3}PO{sub 4} surface structure [i.e., Li{sub 3-2y}Ni{sub y}PO{sub 4} (0 < y < 1)], thereby promoting fast Li{sup +}-ion conduction at the xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} particle surface. In this paper, the solubility of divalent metals (Fe, Mn, Ni, Mg) in {gamma}-Li{sub 3}PO{sub 4} is predicted with the first-principles GGA+U method in an effort to understand the enhanced rate capability. The predicted solubility (x) is extremely small; this finding is consistent with experimental evidence: 1) X-ray diffraction data obtained from Li-Ni-PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} electrodes that show that, after annealing at 550 C, a Li{sub 3}PO{sub 4}-like structure forms as a second phase at the electrode particle surface, and 2) X-ray absorption spectroscopy, which indicate that the nickel ions are accommodated in the transition metal layers of the Li{sub 2}MnO{sub 3} component during the annealing process. However, electrochemical studies of Li{sub 3-2y}Ni{sub y}PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} electrodes indicate that their rate capability increases as a function of y over the range y = 0 (Li{sub 3}PO{sub 4}) to y = 1 (LiNiPO{sub 4}), strongly suggesting that, at some level, the nickel ions play a role in reducing electrochemical impedance and increasing electrode stability at the electrode particle surface.

  5. Effect of the Anion Activity on the Stability of Li Metal Anodes in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium-Sulfur Batteries - Joint Center for Energy Storage Research March 29, 2016, Research Highlights Effect of the Anion Activity on the Stability of Li Metal Anodes in Lithium-Sulfur Batteries The lithium metal anode (bottom) corrodes after just 35 cycles in the LiFSI electrolyte, while the lithium anode (top) stays relatively stable in the LiTFSI electrolyte after more than 200 cycles. Scientific Achievement Discovered why the salt LiTFSI - when added to the electrolyte of a Li-S

  6. How Are You Celebrating Earth Day This Year? | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Day This Year? How Are You Celebrating Earth Day This Year? April 21, 2011 - 7:30am Addthis Tomorrow is Earth Day We've already written about how you can resolve to make Earth Day ...

  7. Earth Day Events Flyer 2016 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Events Flyer 2016 Earth Day Events Flyer 2016 The schedule of events for the 2016 Department of Energy Earth Day activities. PDF icon Earth Day Events Flyer 2016 More Documents & ...

  8. Earth sheltering: the form of energy and the energy of form

    SciTech Connect (OSTI)

    Frenette, E.R.

    1981-01-01

    Winners in a national competition illustrate the state of the art in earth-sheltered construction. The winners were chosen from student and professional entries in four categories: single-family residential, multi-family residential, non-residential, and research. The book presents architectural details, including construction plans, floor plans, landscaping ideas, and photographs of the 50 examples. The three research examples include a regional analysis of ground and above-ground climate, biotechnical earth-support systems, and evaluation of free-span earth-sheltered structure and its method of production. 199 figures. (DCK)

  9. mRNA Transcript Abundance during Plant Growth and the Influence of Li+ Exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duff, M. C.; Kuhne, W. W.; Halverson, N. V.; Chang, C. -S.; Kitamura, E.; Hawthorn, L.; Martinez, N. E.; Stafford, C.; Milliken, C. E.; Caldwell, E. F.; et al

    2014-10-23

    Lithium (Li) toxicity in plants is, at a minimum, a function of Li+ concentration, exposure time, species and growth conditions. Most plant studies with Li+ focus on short-term acute exposures. This study examines short- and long-term effects of Li+ exposure in Arabidopsis with Li+ uptake studies and measured shoot mRNA transcript abundance levels in treated and control plants. Stress, pathogen-response and arabinogalactan protein genes were typically more up-regulated in older (chronic, low level) Li+-treatment plants and in the much younger plants from acute high-level exposures. The gene regulation behavior of high-level Li+ resembled prior studies due to its influence on:more »inositol synthesis, 1-aminocyclopropane-1-carboxylate synthases and membrane ion transport. In contrast, chronically-exposed plants had gene regulation responses that were indicative of pathogen, cold, and heavy-metal stress, cell wall degradation, ethylene production, signal transduction, and calcium-release modulation. Acute Li+ exposure phenocopies magnesium-deficiency symptoms and is associated with elevated expression of stress response genes that could lead to consumption of metabolic and transcriptional energy reserves and the dedication of more resources to cell development. In contrast, chronic Li+ exposure increases expression signal transduction genes. The identification of new Li+-sensitive genes and a gene-based “response plan” for acute and chronic Li+ exposure are delineated.« less

  10. mRNA Transcript Abundance during Plant Growth and the Influence of Li+ Exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Duff, M. C.; Kuhne, W. W.; Halverson, N. V.; Chang, C. -S.; Kitamura, E.; Hawthorn, L.; Martinez, N. E.; Stafford, C.; Milliken, C. E.; Caldwell, E. F.; et al

    2014-10-23

    Lithium (Li) toxicity in plants is, at a minimum, a function of Li+ concentration, exposure time, species and growth conditions. Most plant studies with Li+ focus on short-term acute exposures. This study examines short- and long-term effects of Li+ exposure in Arabidopsis with Li+ uptake studies and measured shoot mRNA transcript abundance levels in treated and control plants. Stress, pathogen-response and arabinogalactan protein genes were typically more up-regulated in older (chronic, low level) Li+-treatment plants and in the much younger plants from acute high-level exposures. The gene regulation behavior of high-level Li+ resembled prior studies due to its influence on:more » inositol synthesis, 1-aminocyclopropane-1-carboxylate synthases and membrane ion transport. In contrast, chronically-exposed plants had gene regulation responses that were indicative of pathogen, cold, and heavy-metal stress, cell wall degradation, ethylene production, signal transduction, and calcium-release modulation. Acute Li+ exposure phenocopies magnesium-deficiency symptoms and is associated with elevated expression of stress response genes that could lead to consumption of metabolic and transcriptional energy reserves and the dedication of more resources to cell development. In contrast, chronic Li+ exposure increases expression signal transduction genes. The identification of new Li+-sensitive genes and a gene-based “response plan” for acute and chronic Li+ exposure are delineated.« less

  11. Ames Lab 101: Rare-Earth Magnets

    ScienceCinema (OSTI)

    McCallum, Bill

    2012-08-29

    Senior Scientist, Bill McCallum, briefly discusses rare-earth magnets and their uses and how Ames Lab is research new ways to save money and energy using magnets.

  12. Planning for Earth Day | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    not do something for the good ol' Earth and save a little energy at the same time? We talk a lot about insulation and home energy audits and other fancy stuff, but energy saving...

  13. New Earth Energy Limited | Open Energy Information

    Open Energy Info (EERE)

    Zip: BH31 6AT Sector: Renewable Energy Product: UK-based subsidiary of British waste treatment and renewable energy company New Earth Group, formed to deploy thermal conversion...

  14. Google Earth Tour: Waters LANL Protects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home > Clean the Past > What waters does LANL protect? PreviousNext Google Earth Tour: Waters LANL Protects Click here to load the tour...then click the play button below

  15. Earth Sciences Division Research Summaries 2006-2007

    SciTech Connect (OSTI)

    DePaolo, Donald; DePaolo, Donald

    2008-07-21

    Research in earth and atmospheric sciences has become increasingly important in light of the energy, climate change, and other environmental issues facing the United States and the world. The development of new energy resources other than fossil hydrocarbons, the safe disposal of nuclear waste and greenhouse gases, and a detailed understanding of the climatic consequences of our energy choices are all critical to meeting energy needs while ensuring environmental safety. The cleanup of underground contamination and the preservation and management of water supplies continue to provide challenges, as they will for generations into the future. To address the critical energy and environmental issues requires continuing advances in our knowledge of Earth systems and our ability to translate that knowledge into new technologies. The fundamental Earth science research common to energy and environmental issues largely involves the physics, chemistry, and biology of fluids in and on the Earth. To manage Earth fluids requires the ability to understand their properties and behavior at the most fundamental molecular level, as well as prediction, characterization, imaging, and manipulation of those fluids and their behavior in real Earth reservoirs. The broad range of disciplinary expertise, the huge range of spatial and time scales, and the need to integrate theoretical, computational, laboratory and field research, represent both the challenge and the excitement of Earth science research. The Earth Sciences Division (ESD) of the Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) is committed to addressing the key scientific and technical challenges that are needed to secure our energy future in an environmentally responsibly way. Our staff of over 200 scientists, UC Berkeley faculty, support staff and guests perform world-acclaimed fundamental research in hydrogeology and reservoir engineering, geophysics and geomechanics, geochemistry, microbial ecology, climate systems, and environmental engineering. Building on this scientific foundation, we also perform applied earth science research and technology development to support DOE in a number of its program areas. We currently organize our efforts in the following Division Programs: Fundamental and Exploratory Research--fundamental research in geochemistry, geophysics, and hydrology to provide a basis for new and improved energy and environmental technologies; Climate and Carbon Sciences--carbon cycling in the terrestrial biosphere and oceans, and global and regional climate modeling, are the cornerstones of a major developing divisional research thrust related to understanding and mitigating the effects of increased greenhouse gas concentrations in the atmosphere; Energy Resources--collaborative projects with industry to develop or improve technologies for the exploration and production of oil, gas, and geothermal reservoirs, and for the development of bioenergy; Environmental Remediation and Water Resources--innovative technologies for locating, containing, and remediating metals, radionuclides, chlorinated solvents, and energy-related contaminants in soils and groundwaters; Geologic Carbon Sequestration--development and testing of methods for introducing carbon dioxide to subsurface geologic reservoirs, and predicting and monitoring its subsequent migration; and Nuclear Waste and Energy--theoretical, experimental, and simulation studies of the unsaturated zone at Yucca Mountain, Nevada. These programs draw from each of ESD's disciplinary departments: Climate Science, Ecology, Geochemistry, Geophysics, and Hydrogeology. Short descriptions of these departments are provided as introductory material. In this document, we present summaries of selected current research projects. While it is not a complete accounting, the projects described here are representative of the nature and breadth of the ESD research effort. We are proud of our scientific accomplishments and we hope that you will find this material useful and exciting. A list of publications for the period from January 2006 to June 2007, along with a listing of our personnel, are also appended. Any comments on our research are appreciated and can be sent to me personally.

  16. Earth Week 2008 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jefferson Lab has given new meaning to dirt cheap. The lab uses a geothermal well system to control heating and cooling on two floors of one wing of its main administrative...

  17. Engineering Density of States of Earth Abundant Semiconductors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Density of States of Earth Abundant Semiconductors for Enhanced Thermoelectric Power Factor Engineering Density of States of Earth Abundant Semiconductors for Enhanced ...

  18. USGS-Earth Resources Observation and Science (EROS) Center |...

    Open Energy Info (EERE)

    USGS-Earth Resources Observation and Science (EROS) Center Jump to: navigation, search Tool Summary LAUNCH TOOL Name: USGS-Earth Resources Observation and Science (EROS) Center...

  19. Characterization and Recovery of Rare Earths from Coal and By...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Characterization and Recovery of Rare Earths from Coal and By-Products Citation Details In-Document Search Title: Characterization and Recovery of Rare Earths ...

  20. Seismic Imaging of the Earth's Interior (LBNL Summer Lecture Series)

    ScienceCinema (OSTI)

    Romanowicz, Barbara

    2011-04-28

    Summer Lecture Series 2006: Earth scientist Barbara Romanowicz discusses how she explores the deep structure and dynamics of the Earth using seismic tomography.