Sample records for larson garnet alkali

  1. Possible origin of Larson's lows

    E-Print Network [OSTI]

    A. W. Zaharow

    2007-04-10T23:59:59.000Z

    It was found that approximately constant column densities of giant molecular clouds (Larson's low) can be explained as cloud existence condition in external (galactic) gravitational field. This condition can be also applied to objects (clumps and cores) embedded into the cloud and its gravitational field. Derived existence condition do not rely on any internal dynamic of a cloud and embedded objects.

  2. QER- Comment of Pat Larson

    Broader source: Energy.gov [DOE]

    First in Massachusetts and other New England states, we need to mount a major campaign to conserve energy. That means getting people and businesses to USE LESS. There are many ways for people to do this. For example, people could use less electricity by shutting off air conditioners and helping cut back electricity use in public buildings such as schools. If we are serious about doing something about the crisis related to climate change, the electric rate system could be re-structured. People who use less pay less, and people who use more (over a certain amount) pay more. Second energy efficiency should be a top priority. We do not need new gas pipelines, such as the proposed Northeast Expansion project in the planning stages by Tennessee Gas Pipeline Co. (owned by Kinder Morgan). This proposed pipeline would cut across protected forests, farmland, and small towns in northern and western parts of Massachusetts. Massachusetts does not need this new proposed gas pipeline. We should fix the leaks in established gas pipelines (Sen. Markey's proposal) to boost efficiency and also use less energy. Continuing to extract fossil fuels such as oil and gas and build new transmission systems is not a good idea at this point in our history as we face a very serious climate change crisis. Patricia Larson

  3. B. C. (Ben) Larson | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ... B&WBen Larson (2003) February

  4. Phase stable rare earth garnets

    DOE Patents [OSTI]

    Kuntz, Joshua D.; Cherepy, Nerine J.; Roberts, Jeffery J.; Payne, Stephen A.

    2013-06-11T23:59:59.000Z

    A transparent ceramic according to one embodiment includes a rare earth garnet comprising A.sub.hB.sub.iC.sub.jO.sub.12, where h is 3.+-.10%, i is 2.+-.10%, and j is 3.+-.10%. A includes a rare earth element or a mixture of rare earth elements, B includes at least one of aluminum, gallium and scandium, and C includes at least one of aluminum, gallium and scandium, where A is at a dodecahedral site of the garnet, B is at an octahedral site of the garnet, and C is at a tetrahedral site of the garnet. In one embodiment, the rare earth garment has scintillation properties. A radiation detector in one embodiment includes a transparent ceramic as described above and a photo detector optically coupled to the rare earth garnet.

  5. Garnet Wind | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualPropertyd8c-a9ae-f8521cbb8489InformationFrenchtown, NewG22 Jump to:Garnet Wind Jump to:

  6. Penn State Hybrid and Hydrogen Vehicle Research Laboratory The Larson Transportation Institute (LTI)

    E-Print Network [OSTI]

    Lee, Dongwon

    Penn State Hybrid and Hydrogen Vehicle Research Laboratory The Larson Transportation Institute (LTI) The Hybrid and Hydrogen Vehicle Research Laboratory (HHVRL) at the Larson Transportation Institute (LTI on the internal combustion engine and fossil fuels to "greener" fuel cell and hybrid electric technology

  7. Combinatorial pulsed laser deposition of doped yttrium iron garnet films on yttrium aluminium garnet

    SciTech Connect (OSTI)

    Sposito, A., E-mail: as11g10@orc.soton.ac.uk; Eason, R. W. [Optoelectronics Research Centre, University of Southampton, Southampton SO17 1BJ (United Kingdom); Gregory, S. A.; Groot, P. A. J. de [Physics and Astronomy, University of Southampton, Southampton SO17 1BJ (United Kingdom)

    2014-02-07T23:59:59.000Z

    We investigate the crystalline growth of yttrium iron garnet (YIG) films doped with bismuth (Bi) and cerium (Ce) by combinatorial pulsed laser deposition, co-ablating a YIG target and either a Bi{sub 2}O{sub 3} or a CeO{sub 2} target, for applications in microwave and optical communications. Substrate temperature is critical for crystalline growth of YIG with simultaneous inclusion of Bi in the garnet lattice, whereas Ce is not incorporated in the garnet structure, but forms a separate CeO{sub 2} phase.

  8. U.S. Energy Secretary Steven Chu, U.S. Representatives Larson...

    Broader source: Energy.gov (indexed) [DOE]

    in innovation and clean energy to put people back to work, grow the economy, and win the future. He will be joined by U.S. Representatives John Larson and Joe Courtney for...

  9. Methods of recovering alkali metals

    DOE Patents [OSTI]

    Krumhansl, James L; Rigali, Mark J

    2014-03-04T23:59:59.000Z

    Approaches for alkali metal extraction, sequestration and recovery are described. For example, a method of recovering alkali metals includes providing a CST or CST-like (e.g., small pore zeolite) material. The alkali metal species is scavenged from the liquid mixture by the CST or CST-like material. The alkali metal species is extracted from the CST or CST-like material.

  10. Hydrothermal alkali metal recovery process

    DOE Patents [OSTI]

    Wolfs, Denise Y. (Houston, TX); Clavenna, Le Roy R. (Baytown, TX); Eakman, James M. (Houston, TX); Kalina, Theodore (Morris Plains, NJ)

    1980-01-01T23:59:59.000Z

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

  11. Ion irradiation effects in natural garnets: Comparison with zircon

    E-Print Network [OSTI]

    Utsunomiya, Satoshi

    .C. Ewing * Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Cooley Bldg.25 and for zircon $À1.5. Based on topology the critical amorphization dose for garnet should be higher than that of zircon; however, the average amorphization dose of garnet (0.20 dpa) is lower than that of zircon (0

  12. EIGENVALUES OF SATURATED HYDROCARBONS D. J. KLEIN AND C. E. LARSON

    E-Print Network [OSTI]

    Larson, Craig E.

    EIGENVALUES OF SATURATED HYDROCARBONS D. J. KLEIN AND C. E. LARSON Abstract. A simplified H¨uckel-type molecular-orbital (MO) model for the valence electrons of saturated hydrocarbons is proposed and half negative. Keywords: saturated hydrocarbons, alkanes, stellation, para-line graph. 1. Saturated

  13. A new formula for the total longshore sediment transport rate Atilla Bayram a,, Magnus Larson b

    E-Print Network [OSTI]

    US Army Corps of Engineers

    A new formula for the total longshore sediment transport rate Atilla Bayram a,, Magnus Larson b April 2007 Available online 7 June 2007 Abstract A new predictive formula for the total longshore employed to evaluate the predictive capability of the new formula. The main parameter of the formula (a

  14. The 2006 aseismic slow slip event in Guerrero, Mexico: New results Kristine M. Larson,1

    E-Print Network [OSTI]

    Larson, Kristine

    The 2006 aseismic slow slip event in Guerrero, Mexico: New results from GPS Kristine M. Larson,1. Miyazaki, and J. A. S. Santiago (2007), The 2006 aseismic slow slip event in Guerrero, Mexico: New results from Guerrero, Mexico were made with continuous GPS instrumentation. This network spans 75 km along

  15. Glaciohydraulic supercooling in former ice sheets? Grahame J. Larson a,*, Daniel E. Lawson b

    E-Print Network [OSTI]

    Lachniet, Matthew S.

    a Department of Geological Sciences, Michigan State University, East Lansing MI 48824, USA b Geophysical Vegas, NV 89154-4010, USA g Department of Geology, Central Michigan University, Mount Pleasant, MI 48859Glaciohydraulic supercooling in former ice sheets? Grahame J. Larson a,*, Daniel E. Lawson b

  16. Upgrading platform using alkali metals

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09T23:59:59.000Z

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  17. Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator

    SciTech Connect (OSTI)

    Joshi, Ashok V. (Salt Lake City, UT); Balagopal, Shekar (Sandy, UT); Pendelton, Justin (Salt Lake City, UT)

    2011-12-13T23:59:59.000Z

    Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. An alkali ion conducting solid electrolyte configured to selectively transport alkali ions is positioned between the anolyte compartment and the buffer compartment. An alkali ion permeable separator is positioned between the buffer compartment and the catholyte compartment. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.

  18. Regenerable activated bauxite adsorbent alkali monitor probe

    DOE Patents [OSTI]

    Lee, S.H.D.

    1992-12-22T23:59:59.000Z

    A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases. 6 figs.

  19. Diamond films treated with alkali-halides

    DOE Patents [OSTI]

    Anderson, D.F.; Kwan, S.W.

    1997-04-08T23:59:59.000Z

    A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide. 5 figs.

  20. Equivalent roughness height for plane bed under oscillatory flow Benoi^t Camenen a,*, Magnus Larson b

    E-Print Network [OSTI]

    US Army Corps of Engineers

    of a flat and fixed bed is given in terms of the Nikuradse roughness height (ks). For flat beds larger than for a fixed bed. This is probably caused by the increased energy dissipation in the sheetEquivalent roughness height for plane bed under oscillatory flow Benoi^t Camenen a,*, Magnus Larson

  1. A general formula for non-cohesive bed load sediment transport Benoi^t Camenen), Magnus Larson

    E-Print Network [OSTI]

    US Army Corps of Engineers

    A general formula for non-cohesive bed load sediment transport Benoi^t Camenen), Magnus Larson 2004; accepted 29 October 2004 Abstract A bed load transport formula for non-cohesive sediment, based, oscillatory flows, and combined steady and oscillatory flows. The bed load formula introduced in this study

  2. Doug Larson

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisitingContract ManagementDiscovering HowAna Moore Anne Jones

  3. Sublattice Magnetic Relaxation in Rare Earth Iron Garnets

    SciTech Connect (OSTI)

    McCloy, John S.; Walsh, Brian

    2013-07-08T23:59:59.000Z

    The magnetic properties of rare earth garnets make them attractive materials for applications ranging from optical communications to magnetic refrigeration. The purpose of this research was to determine the AC magnetic properties of several rare earth garnets, in order to ascertain the contributions of various sublattices. Gd3Fe5O¬12, Gd3Ga5O12, Tb3Fe5O12, Tb3Ga5O12, and Y3Fe5O12 were synthesized by a solid state reaction of their oxides and verified by x-ray diffraction. Frequency-dependent AC susceptibility and DC magnetization were measured versus temperature (10 – 340 K). Field cooling had little effect on AC susceptibility, but large effect on DC magnetization, increasing magnetization at the lowest temperature and shifting the compensation point to lower temperatures. Data suggest that interaction of the two iron lattices results in the two frequency dependent magnetic relaxations in the iron garnets, which were fit using the Vogel-Fulcher and Arrhenius laws.

  4. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

    2007-10-23T23:59:59.000Z

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  5. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

    2006-07-26T23:59:59.000Z

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  6. Super stable garnet ceramics may be ideal for high-energy lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Relations (865) 574-7308 Super stable garnet ceramics may be ideal for high-energy lithium batteries ORNL researchers used scanning transmission electron microscopy to take an...

  7. alkali-metal difluorodioxoperoxouranatevi monohydrates: Topics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  8. alkalies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 3 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  9. alkali: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 3 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  10. Stephan Klemme Hugh StC. O'Neill The near-solidus transition from garnet lherzolite to spinel lherzolite

    E-Print Network [OSTI]

    is somewhat premature, in that the position of the spinel lherzolite to garnet Contrib Mineral Petrol (2000

  11. Author's personal copy Corundum-bearing garnet peridotite from northern Dominican Republic

    E-Print Network [OSTI]

    Author's personal copy Corundum-bearing garnet peridotite from northern Dominican Republic in the late Cretaceous to early Tertiary subduction complex in northern Dominican Republic. The garnet., 2009) and in the Rio San Juan Complex of northern Dominican Republic (Abbott et al., 2005, 2006, 2007

  12. Hydrogen Release Studies of Alkali Metal Amidoboranes. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release Studies of Alkali Metal Amidoboranes. Hydrogen Release Studies of Alkali Metal Amidoboranes. Abstract: A series of metal amido boranes LiNH2BH3 (LAB), NaNH2BH3 (SAB),...

  13. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Wednesday, 29 March 2006 00:00 Turning a...

  14. Alkali-aggregate reaction in concrete containing high-alkali cement and granite aggregate

    SciTech Connect (OSTI)

    Owsiak, Z

    2004-01-01T23:59:59.000Z

    The paper discusses results of the research into the influence of high-alkali Portland cement on granite aggregate. The deformation of the concrete structure occurred after 18 months. The research was carried out by means of a scanning electron microscope equipped with a high-energy dispersive X-ray analyzer that allowed observation of unpolished sections of concrete bars exhibiting the cracking pattern typical of the alkali-silica reaction. Both the microscopic observation and the X-ray elemental analysis confirm the presence of alkali-silica gel and secondary ettringite in the cracks.

  15. Ferromagnetic resonance of sputtered yttrium iron garnet nanometer films

    SciTech Connect (OSTI)

    Liu, Tao [Department of Physics, Colorado State University, Fort Collins, Colorado 80523 (United States); State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China); Chang, Houchen; Sun, Yiyan; Kabatek, Michael; Wu, Mingzhong, E-mail: mwu@lamar.colostate.edu [Department of Physics, Colorado State University, Fort Collins, Colorado 80523 (United States); Vlaminck, Vincent; Hoffmann, Axel [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Deng, Longjiang [State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China)

    2014-05-07T23:59:59.000Z

    Growth of nm-thick yttrium iron garnet (YIG) films by sputtering and ferromagnetic resonance (FMR) properties in the films were studied. The FMR linewidth of the YIG film decreased as the film thickness was increased from several nanometers to about 100?nm. For films with very smooth surfaces, the linewidth increased linearly with frequency. In contrast, for films with big grains on the surface, the linewidth-frequency response was strongly nonlinear. Films in the 7–26?nm thickness range showed a surface roughness between 0.1?nm and 0.4?nm, a 9.48-GHz FMR linewidth in the 6–10?Oe range, and a damping constant of about 0.001.

  16. Alkali resistant optical coatings for alkali lasers and methods of production thereof

    DOE Patents [OSTI]

    Soules, Thomas F; Beach, Raymond J; Mitchell, Scott C

    2014-11-18T23:59:59.000Z

    In one embodiment, a multilayer dielectric coating for use in an alkali laser includes two or more alternating layers of high and low refractive index materials, wherein an innermost layer includes a thicker, >500 nm, and dense, >97% of theoretical, layer of at least one of: alumina, zirconia, and hafnia for protecting subsequent layers of the two or more alternating layers of high and low index dielectric materials from alkali attack. In another embodiment, a method for forming an alkali resistant coating includes forming a first oxide material above a substrate and forming a second oxide material above the first oxide material to form a multilayer dielectric coating, wherein the second oxide material is on a side of the multilayer dielectric coating for contacting an alkali.

  17. Alkali metal recovery from carbonaceous material conversion process

    DOE Patents [OSTI]

    Sharp, David W. (Seabrook, TX); Clavenna, LeRoy R. (Baytown, TX); Gorbaty, Martin L. (Fanwood, NJ); Tsou, Joe M. (Galveston, TX)

    1980-01-01T23:59:59.000Z

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced in the gasifier or similar reaction zone, alkali metal constitutents are recovered from the particles by withdrawing and passing the particles from the reaction zone to an alkali metal recovery zone in the substantial absence of molecular oxygen and treating the particles in the recovery zone with water or an aqueous solution in the substantial absence of molecular oxygen. The solution formed by treating the particles in the recovery zone will contain water-soluble alkali metal constituents and is recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preventing contact of the particles with oxygen as they are withdrawn from the reaction zone and during treatment in the recovery zone avoids the formation of undesirable alkali metal constituents in the aqueous solution produced in the recovery zone and insures maximum recovery of water-soluble alkali metal constituents from the alkali metal residues.

  18. Temperature-dependent Urbach tail measurements of lutetium aluminum garnet single crystals

    E-Print Network [OSTI]

    Liberman, Vladimir

    Lutetium aluminum garnet (LuAG) is the most promising candidate for a high-index lens material for use in microlithographic imaging lenses. In the deep ultraviolet spectral range the transmission of high-purity LuAG was ...

  19. Alkali Metal Heat Pipe Life Issues

    SciTech Connect (OSTI)

    Reid, Robert S. [Marshall Space Flight Center, National Aeronautics and Space Administration, Huntsville, Alabama, 35812 (United States)

    2004-07-01T23:59:59.000Z

    One approach to fission power system design uses alkali metal heat pipes for the core primary heat-transfer system. Heat pipes may also be used as radiator elements or auxiliary thermal control elements. This synopsis characterizes long-life core heat pipes. References are included where information that is more detailed can be found. Specifics shown here are for demonstration purposes and do not necessarily reflect current Nasa Project Prometheus point designs. (author)

  20. alkali metal alkaline: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for hydrogen, the alkali-metal atoms, the alkaline earth atoms, and the inert gases are tabulated along with the resulting values of the atomic static polarizabilities,...

  1. alkali vapor species: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of hexagonal patterns in a nonlinear optical system: Alkali metal vapor in a single-mirror arrangement Physics Websites Summary: Secondary bifurcations of hexagonal patterns in...

  2. alkali metals analiz: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    daniausiai (more) Andrijauskait?, Virginija 2009-01-01 3 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  3. alkali atom vapor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    low power requirements, these "chip-scale" atomic Popovic, Zoya 3 Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis Physics...

  4. alkali metal li: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Elisabetta Caffau 2008-12-11 77 Ab initio prediction of thermodynamics in alkali metal-air batteries . Open Access Theses and Dissertations Summary: ??Electric vehicles ("EVs")...

  5. A Primitive Alkali Basaltic Stratovolcano And Associated Eruptive...

    Open Energy Info (EERE)

    Significance Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Primitive Alkali Basaltic Stratovolcano And Associated Eruptive Centres,...

  6. Semiconductor sensor for optically measuring polarization rotation of optical wavefronts using rare earth iron garnets

    DOE Patents [OSTI]

    Duncan, Paul G. (8544 Electric Ave., Vienna, VA 22182)

    2002-01-01T23:59:59.000Z

    Described are the design of a rare earth iron garnet sensor element, optical methods of interrogating the sensor element, methods of coupling the optical sensor element to a waveguide, and an optical and electrical processing system for monitoring the polarization rotation of a linearly polarized wavefront undergoing external modulation due to magnetic field or electrical current fluctuation. The sensor element uses the Faraday effect, an intrinsic property of certain rare-earth iron garnet materials, to rotate the polarization state of light in the presence of a magnetic field. The sensor element may be coated with a thin-film mirror to effectively double the optical path length, providing twice the sensitivity for a given field strength or temperature change. A semiconductor sensor system using a rare earth iron garnet sensor element is described.

  7. alkali-metal vapor density: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    system: Alkali metal vapor in a single-mirror arrangement Physics Websites Summary: Secondary bifurcations of hexagonal patterns in a nonlinear optical system: Alkali metal vapor...

  8. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, Wen Y. (Houston, TX)

    1984-01-01T23:59:59.000Z

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them (46, 53, 61, 69) with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide (63) to precipitate silicon constituents, the pH of the resultant solution is increased (81), preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated (84) to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process (86, 18, 17) where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  9. Reply to Comment on "Garnet-bearing ultramafic rocks from the Dominican Republic: Fossil mantle plume fragments in an ultra high pressure oceanic complex?"

    E-Print Network [OSTI]

    Abbott Jr., Richard N.

    Discussion Reply to Comment on "Garnet-bearing ultramafic rocks from the Dominican Republic: Fossil-pressure metamorphism REE partitioning Garnet-spinel thermometry Dominican Republic Two competing hypotheses have been proposed for garnet-bearing ultramafic rocks in the Dominican Republic: (1) The ultrahigh pressure (UHP

  10. Atomistic Modeling of Native Point Defects in Yttrium Aluminum Garnet Crystals

    E-Print Network [OSTI]

    Pandey, Ravi

    and Ravindra Pandey Department of Physics, Michigan Technological University, Houghton, Michigan 49931 Native, and dielectric constants of YAG very well. The calculated formulation energies for native defects sug- gestAtomistic Modeling of Native Point Defects in Yttrium Aluminum Garnet Crystals Maija M. Kuklja

  11. Ion irradiation-induced amorphization and nano-crystal formation in garnets

    E-Print Network [OSTI]

    Utsunomiya, Satoshi

    .M. Wang a , S. Yudintsev b , R.C. Ewing a,c,* a Department of Nuclear Engineering and Radiological and in digital display systems [7]. The radiation susceptibility of nuclear waste form garnet requires systematic Engineering and Radiological Sciences, University of Michigan, 1906 Cooley Building 2355 Bonisteel Boulevard

  12. Ion Irradiation Effects in Synthetic Garnets Incorporating Actinides Satoshi Utsunomiya1

    E-Print Network [OSTI]

    Utsunomiya, Satoshi

    -Min Wang1 , Sergey Yudintsev2 and Rodney C. Ewing1,3 1 Department of Nuclear Engineering and Radiological] then examined the relationship between physical-chemical properties and the critical amorphization dose of 25 in the Eby et al. study [10]. But the temperature dependence of the critical amorphization dose of the garnet

  13. Controlled in-situ dissolution of an alkali metal

    DOE Patents [OSTI]

    Jones, Jeffrey Donald; Dooley, Kirk John; Tolman, David Donald

    2012-09-11T23:59:59.000Z

    A method for the controllable dissolution of one or more alkali metals from a vessel containing a one or more alkali metals and/or one or more partially passivated alkali metals. The vessel preferably comprising a sodium, NaK or other alkali metal-cooled nuclear reactor that has been used. The alkali metal, preferably sodium, potassium or a combination thereof, in the vessel is exposed to a treatment liquid, preferably an acidic liquid, more preferably citric acid. Preferably, the treatment liquid is maintained in continuous motion relative to any surface of unreacted alkali metal with which the treatment liquid is in contact. The treatment liquid is preferably pumped into the vessel containing the one or more alkali metals and the resulting fluid is extracted and optionally further processed. Preferably, the resulting off-gases are processed by an off-gas treatment system and the resulting liquids are processed by a liquid disposal system. In one preferred embodiment, an inert gas is pumped into the vessel along with the treatment liquid.

  14. Electrochemical cell utilizing molten alkali metal electrode-reactant

    DOE Patents [OSTI]

    Virkar, Anil V. (Sandy, UT); Miller, Gerald R. (Salt Lake City, UT)

    1983-11-04T23:59:59.000Z

    An improved electrochemical cell comprising an additive-modified molten alkali metal electrode-reactant and/or electrolyte is disclosed. Various electrochemical cells employing a molten alkali metal, e.g., sodium, electrode in contact with a cationically conductive ceramic membrane experience a lower resistance and a lower temperature coefficient of resistance whenever small amounts of selenium are present at the interface of the electrolyte and the molten alkali metal. Further, cells having small amounts of selenium present at the electrolyte-molten metal interface exhibit less degradation of the electrolyte under long term cycling conditions.

  15. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or...

  16. Method for intercalating alkali metal ions into carbon electrodes

    DOE Patents [OSTI]

    Doeff, M.M.; Ma, Y.; Visco, S.J.; DeJonghe, L.

    1995-08-22T23:59:59.000Z

    A low cost, relatively flexible, carbon electrode for use in a secondary battery is described. A method is provided for producing same, including intercalating alkali metal salts such as sodium and lithium into carbon.

  17. Method for intercalating alkali metal ions into carbon electrodes

    DOE Patents [OSTI]

    Doeff, Marca M. (Hayward, CA); Ma, Yanping (Berkeley, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard (Lafayette, CA)

    1995-01-01T23:59:59.000Z

    A low cost, relatively flexible, carbon electrode for use in a secondary battery is described. A method is provided for producing same, including intercalating alkali metal salts such as sodium and lithium into carbon.

  18. alkali treated wheat: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is predicted in alkali metal clusters where it is represented by Ipi2- low-energy excitations of valence electrons with strong M2 transitions to the ground state. We...

  19. alkali metal extraction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  20. alkali metal isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 3 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  1. alkali metal concentrations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  2. alkalis tuhkan muuntuminen: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 3 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  3. alkali metals phase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  4. alkali borohydrides mbh4: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of unidentate phosphines can be made Girolami, Gregory S. 8 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  5. alkali ion exchange: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    many biological processes. In ion channels3 Guidoni, Leonardo 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  6. alkali metal compounds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  7. alkali metal chlorides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  8. alkali metal chloride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  9. alkali metals final: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  10. alkali metal nitrate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  11. aqueous alkali metal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  12. alkali sacaton sporobolus: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 4 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  13. alkali metal complexes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  14. alkali metal thermoelectric: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  15. alkali metal intercalates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 3 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  16. alkali vaporisation titandioxidadditiv: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 3 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  17. alkali metal hydrides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    metal complexes to cleave strong carbon Jones, William D. 4 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  18. alkali metal thermal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  19. alkali metal ion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (more) Pramitha,V 2010-01-01 88 Ab initio prediction of thermodynamics in alkali metal-air batteries . Open Access Theses and Dissertations Summary: ??Electric vehicles ("EVs")...

  20. alkali metal ions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (more) Pramitha,V 2010-01-01 88 Ab initio prediction of thermodynamics in alkali metal-air batteries . Open Access Theses and Dissertations Summary: ??Electric vehicles ("EVs")...

  1. alkali silicate glasses: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with two laser beams. In this regime, the two-photon detuning from the Raman resonance controls Yavuz, Deniz 412 1262 J. Phys. Chem. 1984, 88, 1262-1268 Alkali Oxides. Analysis...

  2. alkali phosphate glasses: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with two laser beams. In this regime, the two-photon detuning from the Raman resonance controls Yavuz, Deniz 242 1262 J. Phys. Chem. 1984, 88, 1262-1268 Alkali Oxides. Analysis...

  3. alkali tellurite glasses: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with two laser beams. In this regime, the two-photon detuning from the Raman resonance controls Yavuz, Deniz 196 1262 J. Phys. Chem. 1984, 88, 1262-1268 Alkali Oxides. Analysis...

  4. alkali halides irradiated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are considered. We predict the major alkali and halogen species in a Pele-like volcanic gas and the major alklai and halogen condensates. We also model disequilibrium chemistry...

  5. alkali modified sbn: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are considered. We predict the major alkali and halogen species in a Pele-like volcanic gas and the major alklai and halogen condensates. We also model disequilibrium chemistry...

  6. alkali halides calorimetro: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are considered. We predict the major alkali and halogen species in a Pele-like volcanic gas and the major alklai and halogen condensates. We also model disequilibrium chemistry...

  7. alkali gabbros: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are considered. We predict the major alkali and halogen species in a Pele-like volcanic gas and the major alklai and halogen condensates. We also model disequilibrium chemistry...

  8. alkali ion beams: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DT capsule a heavy-ion beam. and is presented in Fig.1. unknown authors 4 METHOD FOR EFFICIENCY AND TIME RESPONSE MEASUREMENT ON DIVERSE TARGET ION SOURCES WITH STABLE ALKALI...

  9. Origin of color centers in the flux-grown europium gallium garnet

    SciTech Connect (OSTI)

    Aleksandrovsky, A. S.; Arkhipkin, V. G.; Bezmaternykh, L. N.; Gudim, I. A.; Krylov, A. S. [L. V. Kirensky Institute of Physics, Akademgorodok, Krasnoyarsk 660036, Russia and Siberian Federal University, Krasnoyarsk 660079 (Russian Federation); Vagizov, F. [Department of Physics, Texas A and M University, College Station, Texas 77840 (United States)

    2008-04-15T23:59:59.000Z

    Europium gallium garnet (EuGG) single crystals were grown from fluxes with various contents. Optical absorption spectra of EuGG grown from a flux containing calcium show an additional band in the ultraviolet and blue regions of the spectra as compared to the case of a calcium-free flux. Moessbauer spectra of the samples grown from the fluxes with different additives show no signs of other valence states of the europium ions except for 3+. However, they indicate changes in the crystal field due to the entrance of additive ions. The nature of the additional absorption must be the same as that for calcium-doped gadolinium gallium garnet, i.e., anion vacancies. Moessbauer isotope shifts and quadrupole splitting for EuGG are determined.

  10. Spin wave localization in one-dimensional magnonic microcavity comprising yttrium iron garnet

    SciTech Connect (OSTI)

    Kanazawa, Naoki; Goto, Taichi, E-mail: goto@ee.tut.ac.jp; Inoue, Mitsuteru [Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibari-Ga-Oka, Tempaku, Toyohashi, Aichi 441-8580 (Japan)

    2014-08-28T23:59:59.000Z

    We demonstrate the localization of magnetostatic surface waves, i.e., spin waves, in a one-dimensional magnonic microcavity substantialized with periodical conductivity modulation. The narrow localized state is observed inside band gaps and is responsible for a sharp transmission peak. The experimental results strongly agree with the theoretical prediction made with the shape magnetic anisotropy of the propagating medium composed of yttrium iron garnet taken into account.

  11. Bulk optical damage thresholds for doped and undoped, crystalline and ceramic yttrium aluminum garnet

    SciTech Connect (OSTI)

    Do, Binh T.; Smith, Arlee V.

    2009-06-20T23:59:59.000Z

    We measured the bulk optical damage thresholds of pure and Nd-doped ceramic yttrium aluminum garnet (YAG), and of pure, Nd-doped, Cr-doped, and Yb-doped crystalline YAG. We used 9.9 ns, 1064 nm, single-longitudinal mode, TEM00 pulses, to determine that the breakdown thresholds are deterministic, with multiple-pulse thresholds ranging from 1.1 to 2.2 kJ/cm{sup 2}.

  12. The reaction dynamics of alkali dimer molecules and electronically excited alkali atoms with simple molecules

    SciTech Connect (OSTI)

    Hou, H. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley National Lab., CA (United States). Chemical Sciences Div.

    1995-12-01T23:59:59.000Z

    This dissertation presents the results from the crossed molecular beam studies on the dynamics of bimolecular collisions in the gas phase. The primary subjects include the interactions of alkali dimer molecules with simple molecules, and the inelastic scattering of electronically excited alkali atoms with O{sub 2}. The reaction of the sodium dimers with oxygen molecules is described in Chapter 2. Two reaction pathways were observed for this four-center molecule-molecule reaction, i.e. the formations of NaO{sub 2} + Na and NaO + NaO. NaO{sub 2} products exhibit a very anisotropic angular distribution, indicating a direct spectator stripping mechanism for this reaction channel. The NaO formation follows the bond breaking of O{sub 2}, which is likely a result of a charge transfer from Na{sub 2} to the excited state orbital of O{sub 2}{sup {minus}}. The scattering of sodium dimers from ammonium and methanol produced novel molecules, NaNH{sub 3} and Na(CH{sub 3}OH), respectively. These experimental observations, as well as the discussions on the reaction dynamics and the chemical bonding within these molecules, will be presented in Chapter 3. The lower limits for the bond dissociation energies of these molecules are also obtained. Finally, Chapter 4 describes the energy transfer between oxygen molecules and electronically excited sodium atoms.

  13. Effect of recording condition on the diffraction efficiency of magnetic hologram with magnetic garnet films

    SciTech Connect (OSTI)

    Nakamura, Yuichi, E-mail: nakamura@ee.tut.ac.jp; Takagi, Hiroyuki; Lim, Pang Boey; Inoue, Mitsuteru [Department of Electrical and Electronic Engineering, Toyohashi University of Technology, 1-1 Tempaku-cho, Toyohashi, Aichi 441-8580 (Japan)

    2014-09-14T23:59:59.000Z

    A holographic memory has been attracting attention as recording media with high recording density and high data transfer rate. We have studied the magnetic garnets as a rewritable and long life media for magnetic holography. However, since the signal intensity of reconstructed image was relatively low, the effects of recording conditions on the diffraction efficiency of magnetic hologram were investigated with experiments and the numerical simulation using COMSOL multi-physics. The diffraction efficiency tends to decrease as increasing the spatial frequency, and the use of short pulse laser with the pulse width of 50 ps was found to be effective to achieve high diffraction efficiency. This suggests that the formation of clear magnetic fringe similar to interference pattern can be obtained by the use of short pulse laser since undesirable heat diffusion during radiation does not occur. On the other hand, the diffraction efficiency increased as increasing the film thickness up to 3.1??m but was saturated in the garnet film thicker than 3.1??m in the case of spatial frequency of 1500 line pair/mm. The numerical simulation showed that the effective depth of magnetic fringe was limited about 1.8??m irrespective of the garnet film thickness because the fringes were connected by thermal diffusion near the surface of the film, and the effective depth is limited due to this connection of the magnetic fringe. Avoiding this fringe connection, much higher diffraction efficiency will be achieved.

  14. Cerium Substitution in Yttrium Iron Garnet: Valence State, Structure, and Energetics

    SciTech Connect (OSTI)

    Guo, Xiaofeng; Tavakoli, Amir H.; Sutton, Steve; Kukkadapu, Ravi K.; Qi, Liang; Lanzirotti, Anthony; Newville, Mathew; Asta, Mark D.; Navrotsky, Alexandra

    2014-01-28T23:59:59.000Z

    The garnet structure is a promising nuclear waste form because it can accommodate various actinide elements. Y3Fe5O12 (YIG) is a model composition for such substitutions. Since cerium (Ce) can be considered an analogue of actinide elements such as thorium (Th), plutonium (Pu), and uranium (U), studying the local structure and thermodynamic stability of Ce-substituted YIG (Ce:YIG) can provide insights into the structural and energetic aspects of large ion substitution in garnets. Single phases of yttrium iron garnet with Ce substitution up to 20 mol % (Y3-xCexFe5O12 with 0 ? x ? 0.2) were synthesized through a citrate-nitrate combustion method. The oxidation state of cerium was examined by X-ray absorption near edge structure spectroscopy (XANES); the oxidation state and site occupancy of Fe as a function of Ce loading also was monitored by 57Fe-Mössbauer spectroscopy. These measurements establish that Ce is predominantly in the trivalent state at low substitution levels, while a mixture of trivalent and tetravalent states are observed at higher concentrations. Fe was predominately trivalent and exists in multiple environments. High temperature oxide melt solution calorimetry was used to determine the enthalpy of formation of these Ce-substituted YIG garnets. The thermodynamic analysis demonstrated that, although there is an entropic driving force for the substitution of Ce for Y, the substitution reaction is enthalpically unfavorable. The experimental results are complemented by electronic structure calculations performed within the framework of density functional theory (DFT) with Hubbard-U corrections, which reproduce the observed increase in the tendency for tetravalent Ce to be present with higher loading of Ce. The DFT+U results suggest that the energetics underlying the formation of tetravalent Ce involves a competition between an unfavorable energy to oxidize Ce and reduce Fe, and a favorable contribution due to strain-energy reduction. The structural and thermodynamic findings suggest a strategy to design thermodynamically-favorable substitutions of actinides in the garnet system.

  15. Release and sorption of alkali metals in coal conversion

    SciTech Connect (OSTI)

    Witthohn, A.; Oeltjen, L.; Hilpert, K.

    1998-07-01T23:59:59.000Z

    Released as gaseous species during coal combustion and gasification, alkali metal compounds cause high temperature corrosion especially at the gas turbine blading of coal-fired combined cycle power plants. Experimental and theoretical basic investigations are presented, which contribute to the understanding of the release and sorption of these contaminants. Knudsen effusion mass spectrometry was used to study the vaporization of coal ashes and slags at temperatures between 200 and 1,800 C and to determine the released alkali species and their partial pressures. The data base system FACT and the modified quasi-chemical model for non-ideal solutions were applied to model the thermodynamic behavior of coal slags and to determine material compositions of maximum alkali sorption capacity.

  16. Adsorption of alkali metals on Ge(001)(2×1) surface. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali metals on Ge(001)(2×1) surface. Adsorption of alkali metals on Ge(001)(2×1) surface. Abstract: Ab initio total energy calculations have been performed for Na, K...

  17. Spin polarizations of photoelectrons emitted by alkali atoms

    E-Print Network [OSTI]

    Stuart, Kenneth Charles

    1976-01-01T23:59:59.000Z

    ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ o 55 LXS f OF %BURRS 1 Tso-photon ionization of an ~ atom. ~ . ~ ~ . . ~ ~, ~ 2 ihe photoelectron and the incident radiation. . . . . . ~ 3. ')he transitions fram the ground state substates of an alkali sterne...O and Qe2e ~ ~ ~ Ground state substate populations oi' the alkali atoms f' or &"/& -5o. I"p'- 0'4 ~ Ip? - 'fo ~ X" -0. 0~ 0. 2. . e. ee ~ e ~ e ~ ~ ~ . ~ e ~ e. eee ~ e ~ ~ ~ ~ ~ t Spin polaris. zations of the photoelectrons forX. /X. 50e (p? ~10 Vo t 7...

  18. Magnetic polarizations of electrons at dislocations in alkali halides

    E-Print Network [OSTI]

    McClurg, Gene Roark

    1969-01-01T23:59:59.000Z

    interval. 25 NAGNETIC POLARIZATIONS OF ELECTRONS AT DISLOCATIONS IN ALKALI HALIDES 1. INTRODUCTION. The new magnetic effects observed in our laboratory on a number of single crystals of alkali halides are thought to be caused by electrons trapped... on d1slocations. The magnet1c properties are perhaps more interesting as a bas1c contribution to the sc1ence of magnetism than to a knowledge of d. islocations 1n these very pure, optically clear, s1ngle crystals of alkal1 halides. The gross magnet...

  19. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09T23:59:59.000Z

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  20. Influence of Nucleation Seeding on the Compressive Strength of Ordinary Portland Cement and Alkali

    E-Print Network [OSTI]

    Portland Cement and Alkali Activated Blast-Furnace Slag M. Hubler, H. Jennings OF NUCLEATION SEEDING ON THE COMPRESSIVE STRENGTH OF ORDINARY PORTLAND CEMENT AND ALKALI ACTIVATED BLAST on the early hydration kinetics and compressive strength by seeding of Portland cement and alkali

  1. High capacity nickel battery material doped with alkali metal cations

    DOE Patents [OSTI]

    Jackovitz, John F. (Monroeville, PA); Pantier, Earl A. (Penn Hills, PA)

    1982-05-18T23:59:59.000Z

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  2. Method of assembling and sealing an alkali metal battery

    DOE Patents [OSTI]

    Elkins, P.E.; Bell, J.E.; Harlow, R.A.; Chase, G.G.

    1983-03-01T23:59:59.000Z

    A method of initially assembling and then subsequently hermetically sealing a container portion of an alkali metal battery to a ceramic portion of such a battery is disclosed. Sealing surfaces are formed respectively on a container portion and a ceramic portion of an alkali metal battery. These sealing surfaces are brought into juxtaposition and a material is interposed there between. This interposed material is one which will diffuse into sealing relationship with both the container portion and the ceramic portion of the alkali metal battery at operational temperatures of such a battery. A pressure is applied between these sealing surfaces to cause the interposed material to be brought into intimate physical contact with such juxtaposed surfaces. A temporary sealing material which will provide a seal against a flow of alkali metal battery reactants there through at room temperatures and is applied over the juxtaposed sealing surfaces and material interposed there between. The entire assembly is heated to an operational temperature so that the interposed material diffuses into the container portion and the ceramic portion to form a hermetic seal there between. The pressure applied to the juxtaposed sealing surfaces is maintained in order to ensure the continuation of the hermetic seal. 4 figs.

  3. alkali earth aluminium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali earth aluminium First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Long range interactions between...

  4. alkali earth metal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali earth metal First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Efficient qubit detection using...

  5. alkali earth elements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali earth elements First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Long range interactions between...

  6. alkali earth metals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali earth metals First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Efficient qubit detection using...

  7. alkali alkaline earth: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali alkaline earth First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Long range interactions between...

  8. Spin-wave excitation and propagation in microstructured waveguides of yttrium iron garnet/Pt bilayers

    SciTech Connect (OSTI)

    Pirro, P.; Chumak, A. V.; Lägel, B.; Leven, B.; Hillebrands, B. [Fachbereich Physik and Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, D-67663 Kaiserslautern (Germany)] [Fachbereich Physik and Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, D-67663 Kaiserslautern (Germany); Brächer, T. [Fachbereich Physik and Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, D-67663 Kaiserslautern (Germany) [Fachbereich Physik and Landesforschungszentrum OPTIMAS, Technische Universität Kaiserslautern, D-67663 Kaiserslautern (Germany); Graduate School Materials Science in Mainz, Gottlieb-Daimler-Strasse 47, D-67663 Kaiserslautern (Germany); Dubs, C.; Surzhenko, O.; Görnert, P. [Innovent e.V., Prüssingstraße 27B, 07745 Jena (Germany)] [Innovent e.V., Prüssingstraße 27B, 07745 Jena (Germany)

    2014-01-06T23:59:59.000Z

    We present an experimental study of spin-wave excitation and propagation in microstructured waveguides consisting of a 100?nm thick yttrium iron garnet/platinum (Pt) bilayer. The life time of the spin waves is found to be more than an order of magnitude higher than in comparably sized metallic structures, despite the fact that the Pt capping enhances the Gilbert damping. Utilizing microfocus Brillouin light scattering spectroscopy, we reveal the spin-wave mode structure for different excitation frequencies. An exponential spin-wave amplitude decay length of 31??m is observed which is a significant step towards low damping, insulator based micro-magnonics.

  9. Effect of reversible adsorption on the magnetic properties of iron garnet films

    SciTech Connect (OSTI)

    Zubov, V. E., E-mail: zubov@magn.ru; Kudakov, A. D.; Levshin, N. L.; Vlasov, M. A. [Moscow State University (Russian Federation)

    2013-05-15T23:59:59.000Z

    The reversible change in the domain structure and the magnetic domain width in bismuth-containing iron garnet films with an easy magnetization axis oriented normal to their surface during adsorption caused by hydrogen bonds is studied by a magnetooptical method. The dependence of the domain width on the vapor pressure of methyl alcohol or water in a cell with a sample is determined, and the time dependence of the domain width induced by the adsorption-desorption processes occurring between methyl alcohol molecules or water molecules on the film surface is studied. A model is proposed to explain the detected effects.

  10. Unidirectional anisotropy in the spin pumping voltage in yttrium iron garnet/platinum bilayers

    SciTech Connect (OSTI)

    Vilela-Leao, L. H.; Salvador, C.; Azevedo, A.; Rezende, S. M.

    2011-09-05T23:59:59.000Z

    Detailed measurements of the dc voltage generated in a thin Pt layer deposited on films of yttrium iron garnet (YIG) have been carried out to study the spin pumping effect produced by magnetostatic (MS) modes excited by a microwave field. In relatively thick YIG films the modes are far apart so that one can identify clearly the spin pumping voltage in V{sub SP} produced by each MS mode. We have discovered that when the sputter deposition of the thin Pt layer is made on the YIG film magnetized by a static magnetic field, V{sub SP} exhibits a strong unidirectional anisotropy.

  11. Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue

    DOE Patents [OSTI]

    Sharp, David W. (Seabrook, TX)

    1980-01-01T23:59:59.000Z

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  12. Identification of spin wave modes in yttrium iron garnet strongly coupled to a co-axial cavity.

    E-Print Network [OSTI]

    Lambert, N. J.; Haigh, J. A.; Ferguson, A. J.

    2015-02-05T23:59:59.000Z

    AIP/123-QED Identification of spin wave modes in yttrium iron garnet strongly coupled to a co-axial cavity. N. J. Lambert,1 J. A. Haigh,2 and A. J. Ferguson1 1)Microelectronics Group, Cavendish Laboratory, University of Cambridge, Cambridge, CB3 0HE...

  13. The unexpected properties of alkali metal iron selenide superconductors

    SciTech Connect (OSTI)

    Dagotto, Elbio R [ORNL

    2013-01-01T23:59:59.000Z

    The iron-based superconductors that contain FeAs layers as the fundamental building block in the crystal structures have been rationalized in the past using ideas based on the Fermi surface nesting of hole and electron pockets when in the presence of weak Hubbard U interactions. This approach seemed appropriate considering the small values of the magnetic moments in the parent compounds and the clear evidence based on photoemission experiments of the required electron and hole pockets. However, recent results in the context of alkali metal iron selenides, with generic chemical composition AxFe2ySe2 (A alkali metal element), have challenged those previous ideas since at particular compositions y the low-temperature ground states are insulating and display antiferromagnetic order with large iron magnetic moments. Moreover, angle-resolved photoemission studies have revealed the absence of hole pockets at the Fermi level in these materials. The present status of this exciting area of research, with the potential to alter conceptually our understanding of the ironbased superconductors, is here reviewed, covering both experimental and theoretical investigations. Other recent related developments are also briefly reviewed, such as the study of selenide two-leg ladders and the discovery of superconductivity in a single layer of FeSe. The conceptual issues considered established for the alkali metal iron selenides, as well as several issues that still require further work, are discussed.

  14. Phase-controllable spin wave generation in iron garnet by linearly polarized light pulses

    SciTech Connect (OSTI)

    Yoshimine, Isao; Iida, Ryugo; Shimura, Tsutomu [Institute of Industrial Science, The University of Tokyo, Tokyo 153-8505 (Japan); Satoh, Takuya, E-mail: satoh@phys.kyushu-u.ac.jp [Institute of Industrial Science, The University of Tokyo, Tokyo 153-8505 (Japan); PRESTO, Japan Science and Technology Agency, Tokyo 102-0076 (Japan); Department of Physics, Kyushu University, Fukuoka 812-8581 (Japan); Stupakiewicz, Andrzej; Maziewski, Andrzej [Laboratory of Magnetism, Faculty of Physics, University of Bialystok, Bialystok 15-424 (Poland)

    2014-07-28T23:59:59.000Z

    A phase-controlled spin wave was non-thermally generated in bismuth-doped rare-earth iron garnet by linearly polarized light pulses. We controlled the initial phase of the spin wave continuously within a range of 180° by changing the polarization azimuth of the excitation light. The azimuth dependences of the initial phase and amplitude of the spin wave were attributed to a combination of the inverse Cotton-Mouton effect and photoinduced magnetic anisotropy. Temporally and spatially resolved spin wave propagation was observed with a CCD camera, and the waveform was in good agreement with calculations. A nonlinear effect of the spin excitation was observed for excitation fluences higher than 100 mJ/cm{sup 2}.

  15. Ratchet effects for paramagnetic beads above striped ferrite-garnet films

    E-Print Network [OSTI]

    Jorn Inge Vestgarden; Tom Henning Johansen

    2011-09-29T23:59:59.000Z

    We calculate the motion of a small paramagnetic bead which is manipulated by the stripe domain pattern of a ferrite-garnet film. A model for the bead's motion in a liquid above the film is developed and used to look for ratchet solutions, where the bead acquires net coherent motion in one direction when the external field is modulated periodically. We consider three cases. First, the ratchet, where the beads all go in the same direction. Second, the height dependent ratchet, where beads at different heights go in opposite direction. This case can be used to separate beads of different sizes, as considered in J. Phys. Chem. B 112, 3833 (2008). Third, we describe how the separation threshold can be tuned by changing the amplitude of the applied field. Finally, we describe a pseudo ratchet, where the external modulation is not periodic and the ratchet changes direction periodically.

  16. Determination of oxygen in molten alkali halide salts by proton activation analysis

    SciTech Connect (OSTI)

    Wai, C.M.; Dysart, M.E.

    1986-12-01T23:59:59.000Z

    The authors have recently used a lanthanum fluoride precipitation method to separate /sup 18/F produced from proton activation of /sup 18/O in alkali chloride and fluoride salts. The procedure was developed for studying dissolved oxide species in alkali halide melts. Determination of oxygen in these systems is important for research in batteries and in extractive metallurgy utilizing molten salts as solvents. The details are given oxygen determination in alkali chloride and fluoride systems.

  17. E-Print Network 3.0 - alkali ion scattering Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Floppy modes and the Boson peak in crystalline and amorphous silicates: an inelastic neutron scattering study Summary: ion from Li+ to K+ in the alkali disilicate glasses,...

  18. alkali-metal atoms li: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    under certain Schnadt, Joachim 90 Ab initio prediction of thermodynamics in alkali metal-air batteries . Open Access Theses and Dissertations Summary: ??Electric vehicles ("EVs")...

  19. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.; Franco, S.C.S.

    1994-03-29T23:59:59.000Z

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications. 6 figures.

  20. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, Lynn A. (Oak Ridge, TN); Sales, Brian C. (Knoxville, TN); Franco, Sofia C. S. (Santafe de Bogota, CO)

    1994-01-01T23:59:59.000Z

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications.

  1. Novel rubidium atomic beam with an alkali dispenser source

    SciTech Connect (OSTI)

    Roach, Timothy M.; Henclewood, Dwayne [College of the Holy Cross, Worcester, Massachusetts 01610 (United States)

    2004-11-01T23:59:59.000Z

    We describe a novel atomic beam apparatus with a resistively heated alkali dispenser source and a cold-pumped intermediate chamber. Using laser fluorescence spectroscopy we have measured the atomic density to be 3x10{sup 11} atoms/m{sup 3} and the total flux to be 5x10{sup 8} atoms/s in a 0.3 cm diameter beam. We have also characterized the velocity distribution of the source based on the Doppler-shifted fluorescence spectrum. The compact geometry, flexibility, and simplicity of the beam may make it useful as an optical frequency reference or for experiments on atom-cooling.

  2. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamosCharacterization of Selective Binding of Alkali Cations

  3. Pulsed laser deposition of epitaxial yttrium iron garnet films with low Gilbert damping and bulk-like magnetization

    SciTech Connect (OSTI)

    Onbasli, M. C., E-mail: onbasli@mit.edu; Kim, D. H.; Ross, C. A. [Department of Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139 (United States); Kehlberger, A. [Institute of Physics, Johannes Gutenberg-University of Mainz, 55099 Mainz (Germany); Graduate School Materials Science in Mainz, Staudinger Weg 9, 55128 Mainz (Germany); Jakob, G.; Kläui, M. [Institute of Physics, Johannes Gutenberg-University of Mainz, 55099 Mainz (Germany); Chumak, A. V.; Hillebrands, B. [Fachbereich Physik and Landesforschungszentrum, OPTIMAS, Technische Universität Kaiserslautern, 67663 Kaiserslautern (Germany)

    2014-10-01T23:59:59.000Z

    Yttrium iron garnet (YIG, Y {sub 3}Fe{sub 5}O{sub 12}) films have been epitaxially grown on Gadolinium Gallium Garnet (GGG, Gd{sub 3}Ga{sub 5}O{sub 12}) substrates with (100) orientation using pulsed laser deposition. The films were single-phase, epitaxial with the GGG substrate, and the root-mean-square surface roughness varied between 0.14 nm and 0.2 nm. Films with thicknesses ranging from 17 to 200 nm exhibited low coercivity (<2 Oe), near-bulk room temperature saturation moments (?135 emu cm{sup ?3}), in-plane easy axis, and damping parameters as low as 2.2 × 10{sup ?4}. These high quality YIG thin films are useful in the investigation of the origins of novel magnetic phenomena and magnetization dynamics.

  4. Performance-based approach to evaluate alkali-silica reaction potential of aggregate and concrete using dilatometer method 

    E-Print Network [OSTI]

    Shon, Chang Seon

    2009-05-15T23:59:59.000Z

    The undesirable expansion of concrete because of a reaction between alkalis and certain type of reactive siliceous aggregates, known as alkali-silica reactivity (ASR), continues to be a major problem across the entire ...

  5. A new polarizable force field for alkali and halide ions

    SciTech Connect (OSTI)

    Kiss, Péter T.; Baranyai, András [Institute of Chemistry, Eötvös University, 1518 Budapest 112, PO BOX 32 (Hungary)

    2014-09-21T23:59:59.000Z

    We developed transferable potentials for alkali and halide ions which are consistent with our recent model of water [P. T. Kiss and A. Baranyai, J. Chem. Phys. 138, 204507 (2013)]. Following the approach used for the water potential, we applied Gaussian charge distributions, exponential repulsion, and r{sup ?6} attraction. One of the two charges of the ions is fixed to the center of the particle, while the other is connected to this charge by a harmonic spring to express polarization. Polarizability is taken from quantum chemical calculations. The repulsion between different species is expressed by the combining rule of Kong [J. Chem. Phys. 59, 2464 (1972)]. Our primary target was the hydration free energy of ions which is correct within the error of calculations. We calculated water-ion clusters up to 6 water molecules, and, as a crosscheck, we determined the density and internal energy of alkali-halide crystals at ambient conditions with acceptable accuracy. The structure of hydrated ions was also discussed.

  6. Crystal structure and electron microprobe analyses of a lanthanum lutetium gallium garnet

    SciTech Connect (OSTI)

    Parise, J.B.; Harlow, R.L.; Shannon, R.D. (Central Research and Development Department, E. I. DuPont De Nemours and Co., Experimental Station, Wilmington, Delaware 19880-0228 (United States)); Kwei, G.H. (LANSCE, MS-H805, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)); Allik, T.H. (Science Applications International Corporation, 1710 Goodridge Dr., P.O. Box 1303, McLean, Virginia 22102 (United States)); Armstrong, J.T. (Department of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125 (United States))

    1992-09-15T23:59:59.000Z

    Single-crystal electron microprobe analysis of a lanthanum lutetium gallium garnet has resulted in a composition of La{sub 2.37}Nd{sub 0.07}Pb{sub 0.01}Lu{sub 2.54}Cr{sub 0.01} Ga{sub 3.00}O{sub 12}. This composition gives better agreement between observed and calculated total dielectric polarizabilities than previously reported compositions (La{sub 2.26--2.32}Nd{sub 0.04}Lu{sub 2.57--2.63}Ga{sub 3.07}O{sub 12} by x-ray fluorescence and La{sub 2.655}Nd{sub 0.027}Lu{sub 2.656}Ga{sub 2.655}O{sub 12} by inductively coupled plasma analyses), and does not imply the crystal-chemically improbable presence of Lu{sup 3+} in the tetrahedral site. X-ray and neutron crystal-structure analyses have confirmed that little or no Lu resides in this site.

  7. 3718-F Alkali Metal Treatment and Storage Facility Closure Plan

    SciTech Connect (OSTI)

    none,

    1991-12-01T23:59:59.000Z

    Since 1987, Westinghouse Hanford Company has been a major contractor to the U.S. Department of Energy-Richland Operations Office and has served as co-operator of the 3718-F Alkali Metal Treatment and Storage Facility, the waste management unit addressed in this closure plan. The closure plan consists of a Part A Dangerous waste Permit Application and a RCRA Closure Plan. An explanation of the Part A Revision (Revision 1) submitted with this document is provided at the beginning of the Part A section. The closure plan consists of 9 chapters and 5 appendices. The chapters cover: introduction; facility description; process information; waste characteristics; groundwater; closure strategy and performance standards; closure activities; postclosure; and references.

  8. An antidot array as an edge for total non-reflection of spin waves in yttrium iron garnet films

    SciTech Connect (OSTI)

    Gieniusz, R., E-mail: gieniusz@uwb.edu.pl; Guzowska, U.; Maziewski, A. [Faculty of Physics, University of Bia?ystok, Lipowa 41, 15-424 Bia?ystok (Poland); Bessonov, V. D. [Faculty of Physics, University of Bia?ystok, Lipowa 41, 15-424 Bia?ystok (Poland); Institute of Metal Physics, Ural Division of RAS, Yekaterinburg 620041 (Russian Federation); Stognii, A. I. [Scientific-Practical Materials Research Center at National Academy of Sciences of Belarus, ul. P. Brovki 19, Minsk 220072 (Belarus)

    2014-02-24T23:59:59.000Z

    An array of antidots has been used as an edge to create the phenomenon of total non-reflection of spin waves in yttrium iron garnet films. At the critical angle between the line of antidots and the magnetic field, we observe a high-intensity beam of spin waves moving along the line of antidots. The properties of these waves are investigated experimentally by Brillouin light scattering spectroscopy. The conditions required for the occurrence of this phenomenon based on an analysis of the properties of the isofrequency dependencies are presented. The numerical simulations are in good agreement with those of the experimental measurements.

  9. Mixed ionic and electronic conducting electrode studies for an alkali metal thermal to electric converter

    E-Print Network [OSTI]

    Guo, Yuyan

    2009-05-15T23:59:59.000Z

    This research focuses on preparation, kinetics, and performance studies of mixed ionic and electronic conducting electrodes (MIEE) applied in an alkali metal thermal to electric converter (AMTEC). Two types of MIEE, metal/sodium titanate and metal...

  10. Alkali corrosion resistant coatings and ceramic foams having superfine open cell structure and method of processing

    DOE Patents [OSTI]

    Brown, Jr., Jesse J. (Christiansburg, VA); Hirschfeld, Deidre A. (Elliston, VA); Li, Tingkai (Blacksburg, VA)

    1993-12-07T23:59:59.000Z

    Alkali corrosion resistant coatings and ceramic foams having superfine open cell structure are created using sol-gel processes. The processes have particular application in creating calcium magnesium zirconium phosphate, CMZP, coatings and foams.

  11. alkali pre-treatments producao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are considered. We predict the major alkali and halogen species in a Pele-like volcanic gas and the major alklai and halogen condensates. We also model disequilibrium chemistry...

  12. alkali promoted cobalt-molybdenum: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are considered. We predict the major alkali and halogen species in a Pele-like volcanic gas and the major alklai and halogen condensates. We also model disequilibrium chemistry...

  13. Detection of alkali-silica reaction swelling in concrete by staining

    DOE Patents [OSTI]

    Guthrie, G.D. Jr.; Carey, J.W.

    1998-04-14T23:59:59.000Z

    A method using concentrated aqueous solutions of sodium cobalt nitrite and rhodamine B is described which can be used to identify concrete that contains gels formed by the alkali-silica reaction (ASR). These solutions present little health or environmental risk, are readily applied, and rapidly discriminate between two chemically distinct gels; K-rich, Na-K-Ca-Si gels are identified by yellow staining, and alkali-poor, Ca-Si gels are identified by pink staining.

  14. Detection of alkali-silica reaction swelling in concrete by staining

    DOE Patents [OSTI]

    Guthrie, Jr., George D. (Santa Fe, NM); Carey, J. William (Santa Fe, NM)

    1998-01-01T23:59:59.000Z

    A method using concentrated aqueous solutions of sodium cobaltinitrite and rhodamine B is described which can be used to identify concrete that contains gels formed by the alkali-silica reaction (ASR). These solutions present little health or environmental risk, are readily applied, and rapidly discriminate between two chemically distinct gels; K-rich, Na--K--Ca--Si gels are identified by yellow staining, and alkali-poor, Ca--Si gels are identified by pink staining.

  15. In situ formation of coal gasification catalysts from low cost alkali metal salts

    DOE Patents [OSTI]

    Wood, Bernard J. (Santa Clara, CA); Brittain, Robert D. (Cupertino, CA); Sancier, Kenneth M. (Menlo Park, CA)

    1985-01-01T23:59:59.000Z

    A carbonaceous material, such as crushed coal, is admixed or impregnated with an inexpensive alkali metal compound, such as sodium chloride, and then pretreated with a stream containing steam at a temperature of 350.degree. to 650.degree. C. to enhance the catalytic activity of the mixture in a subsequent gasification of the mixture. The treatment may result in the transformation of the alkali metal compound into another, more catalytically active, form.

  16. Determination of the concentration of conduction electrons in Y{sub 3}Fe{sub 5}O{sub 12} garnet crystals

    SciTech Connect (OSTI)

    Lomako, I. D., E-mail: lomako@ifttp.bas-net.by [National Academy of Sciences of Belarus, Scientific and Practical Materials Research Center (Belarus)

    2013-07-15T23:59:59.000Z

    Ferrites (garnets) are a model object of study and a promising material to be used in magneto-optical devices for data recording and processing and IR modulators. Due to the narrow ferromagnetic resonance line, optical transparency, and high elastic Q factor of ferrite single crystals, they are promising for solid-state microwave, optoelectronic, and computation devices. To ensure the optimal application of ferromagnetic materials, it is necessary to complete the following important task: develop a certification for samples with allowance for the degree of their imperfection caused by the deviation of crystals with garnet structure from stoichiometry, the competitive incorporation of process and dominant impurities, oxygen vacancies, etc.

  17. Measurement of alkali-vapor emission from pressurized fluidized-bed combustion of Illinois coals

    SciTech Connect (OSTI)

    Lee, S.H.D.; Teats, F.G.; Swift, W.M. (Argonne National Lab., IL (United States)); Banerjee, D.D. (Illinois Clean Coal Inst., Carterville, IL (United States))

    1993-01-01T23:59:59.000Z

    Two Illinois Herrin No. 6 coals and one Illinois Springfield No. 5 coal were separately combusted in a laboratory-scale (15-cm dia) pressurized fluidized-bed combustor (PFBC) combined with an alkali sorber. These coals were combusted in a fluidized bed of Tymochtee dolomite at temperatures ranging from 910 to 950[degree]C and a system pressure of 9.2 atm absolute. Alkali-vapor emission (Na and K) in the PFBC flue gas was determined by the analytical activated-bauxite sorber bed technique developed at Argonne National Laboratory. The test results showed that sodium is the major alkali-vapor species present in the PFBC flue gas, and that the level of sodium-vapor emission increases linearly with both Na and Cl contents in the coals. This suggests that the sodium-vapor emission results from direct vaporization of NaCl present in the coals. The measured alkali-vapor concentration (Na + K), 67 to 190 ppbW, is more than 2.5 times greater than the allowable alkali limit of 24 ppb for an industrial gas turbine. Combusting these coals in a PFBC for power generation may require developing a method to control alkali vapors.

  18. Measurement of alkali-vapor emission from pressurized fluidized-bed combustion of Illinois coals

    SciTech Connect (OSTI)

    Lee, S.H.D.; Teats, F.G.; Swift, W.M. [Argonne National Lab., IL (United States); Banerjee, D.D. [Illinois Clean Coal Inst., Carterville, IL (United States)

    1993-04-01T23:59:59.000Z

    Two Illinois Herrin No. 6 coals and one Illinois Springfield No. 5 coal were separately combusted in a laboratory-scale (15-cm dia) pressurized fluidized-bed combustor (PFBC) combined with an alkali sorber. These coals were combusted in a fluidized bed of Tymochtee dolomite at temperatures ranging from 910 to 950{degree}C and a system pressure of 9.2 atm absolute. Alkali-vapor emission (Na and K) in the PFBC flue gas was determined by the analytical activated-bauxite sorber bed technique developed at Argonne National Laboratory. The test results showed that sodium is the major alkali-vapor species present in the PFBC flue gas, and that the level of sodium-vapor emission increases linearly with both Na and Cl contents in the coals. This suggests that the sodium-vapor emission results from direct vaporization of NaCl present in the coals. The measured alkali-vapor concentration (Na + K), 67 to 190 ppbW, is more than 2.5 times greater than the allowable alkali limit of 24 ppb for an industrial gas turbine. Combusting these coals in a PFBC for power generation may require developing a method to control alkali vapors.

  19. Rapid Microwave Preparation of Highly Efficient Ce[superscript 3+]-Substituted Garnet Phosphors for Solid State White Lighting

    SciTech Connect (OSTI)

    Birkel, Alexander; Denault, Kristin A.; George, Nathan C.; Doll, Courtney E.; Héry, Bathylle; Mikhailovsky, Alexander A.; Birkel, Christina S.; Hong, Byung-Chul; Seshadri, Ram (UCSB); (Mitsubishi)

    2012-04-30T23:59:59.000Z

    Ce{sup 3+}-substituted aluminum garnet compounds of yttrium (Y{sub 3}Al{sub 5}O{sub 12}) and lutetium (Lu{sub 3}Al{sub 5}O{sub 12}) - both important compounds in the generation of (In,Ga)N-based solid state white lighting - have been prepared using a simple microwave heating technique involving the use of a microwave susceptor to provide the initial heat source. Carbon used as the susceptor additionally creates a reducing atmosphere around the sample that helps stabilize the desired luminescent compound. High quality, phase-pure materials are prepared within a fraction of the time and using a fraction of the energy required in a conventional ceramic preparation; the microwave technique allows for a reduction of about 95% in preparation time, making it possible to obtain phase pure, Ce{sup 3+}-substituted garnet compounds in under 20 min of reaction time. It is estimated that the overall reduction in energy compared with ceramic routes as practiced in the lab is close to 99%. Conventionally prepared material is compared with material prepared using microwave heating in terms of structure, morphology, and optical properties, including quantum yield and thermal quenching of luminescence. Finally, the microwave-prepared compounds have been incorporated into light-emitting diode 'caps' to test their performance characteristics in a real device, in terms of their photon efficiency and color coordinates.

  20. Microfabricated alkali vapor cell with anti-relaxation wall coating

    SciTech Connect (OSTI)

    Straessle, R.; Pétremand, Y.; Briand, D.; Rooij, N. F. de, E-mail: nico.derooij@epfl.ch [Institute of Microengineering (IMT), Sensors, Actuators and Microsystems Laboratory (SAMLAB), Ecole Polytechnique Fédérale de Lausanne EPFL, 2000 Neuchâtel (Switzerland); Pellaton, M.; Affolderbach, C.; Mileti, G., E-mail: gaetano.mileti@unine.ch [Laboratoire Temps-Fréquence (LTF), Institut de Physique, Université de Neuchâtel, 2000 Neuchâtel (Switzerland)

    2014-07-28T23:59:59.000Z

    We present a microfabricated alkali vapor cell equipped with an anti-relaxation wall coating. The anti-relaxation coating used is octadecyltrichlorosilane and the cell was sealed by thin-film indium-bonding at a low temperature of 140?°C. The cell body is made of silicon and Pyrex and features a double-chamber design. Depolarizing properties due to liquid Rb droplets are avoided by confining the Rb droplets to one chamber only. Optical and microwave spectroscopy performed on this wall-coated cell are used to evaluate the cell's relaxation properties and a potential gas contamination. Double-resonance signals obtained from the cell show an intrinsic linewidth that is significantly lower than the linewidth that would be expected in case the cell had no wall coating but only contained a buffer-gas contamination on the level measured by optical spectroscopy. Combined with further experimental evidence this proves the presence of a working anti-relaxation wall coating in the cell. Such cells are of interest for applications in miniature atomic clocks, magnetometers, and other quantum sensors.

  1. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24T23:59:59.000Z

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  2. An alternative model for ultra-high pressure in the Svartberget Fe-Ti garnet-peridotite, Western Gneiss Region, Norway

    E-Print Network [OSTI]

    Andersen, Torgeir Bjørge

    Gneiss Region, Norway JOHANNES C. VRIJMOED1,*, YURI Y. PODLADCHIKOV1 , TORGEIR B. ANDERSEN1 and EBBE H, Norway *Corresponding author, e-mail: j.c.vrijmoed@fys.uio.no 2 Aker Exploration AS, PO Box 580, Sentrum, 4003 Stavanger, Norway Abstract: The previously reported ``Fe-Ti type'' garnet-peridotite is located

  3. Communication: Angular momentum alignment and fluorescence polarization of alkali atoms photodetached from helium nanodroplets

    SciTech Connect (OSTI)

    Hernando, Alberto; Beswick, J. Alberto; Halberstadt, Nadine [LCAR-IRSAMC, Université Toulouse 3 - Paul Sabatier and CNRS, 31062 Toulouse (France)] [LCAR-IRSAMC, Université Toulouse 3 - Paul Sabatier and CNRS, 31062 Toulouse (France)

    2013-12-14T23:59:59.000Z

    The theory of photofragments angular momentum polarization is applied to the photodetachment of an electronically excited alkali atom from a helium nanocluster (N = 200). The alignment of the electronic angular momentum of the bare excited alkali atoms produced is calculated quantum mechanically by solving the excited states coupled equations with potentials determined by density functional theory (DFT). Pronounced oscillations as a function of excitation energy are predicted for the case of Na@(He){sub 200}, in marked contrast with the absorption cross-section and angular distribution of the ejected atoms which are smooth functions of the energy. These oscillations are due to quantum interference between different coherently excited photodetachment pathways. Experimentally, these oscillations should be reflected in the fluorescence polarization and polarization-resolved photoelectron yield of the ejected atoms, which are proportional to the electronic angular momentum alignment. In addition, this result is much more general than the test case of NaHe{sub 200} studied here. It should be observable for larger droplets, for higher excited electronic states, and for other alkali as well as for alkali-earth atoms. Detection of these oscillations would show that the widely used pseudo-diatomic model can be valid beyond the prediction of absorption spectra and could help in interpreting parts of the dynamics, as already hinted by some experimental results on angular anisotropy of bare alkali fragments.

  4. High pressure elastic properties of minerals from ab initio simulations: The case of pyrope, grossular and andradite silicate garnets

    SciTech Connect (OSTI)

    Erba, A., E-mail: alessandro.erba@unito.it; Mahmoud, A.; Dovesi, R. [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Università di Torino, via Giuria 5, IT-10125 Torino (Italy)] [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Università di Torino, via Giuria 5, IT-10125 Torino (Italy); Belmonte, D. [DISTAV, Università di Genova, Corso Europa 26, 16132 Genoa (Italy)] [DISTAV, Università di Genova, Corso Europa 26, 16132 Genoa (Italy)

    2014-03-28T23:59:59.000Z

    A computational strategy is devised for the accurate ab initio simulation of elastic properties of crystalline materials under pressure. The proposed scheme, based on the evaluation of the analytical stress tensor and on the automated computation of pressure-dependent elastic stiffness constants, is implemented in the CRYSTAL solid state quantum-chemical program. Elastic constants and related properties (bulk, shear and Young moduli, directional seismic wave velocities, elastic anisotropy index, Poisson's ratio, etc.) can be computed for crystals of any space group of symmetry. We apply such a technique to the study of high-pressure elastic properties of three silicate garnet end-members (namely, pyrope, grossular, and andradite) which are of great geophysical interest, being among the most important rock-forming minerals. The reliability of this theoretical approach is proved by comparing with available experimental measurements. The description of high-pressure properties provided by several equations of state is also critically discussed.

  5. Tuning of the spin pumping in yttrium iron garnet/Au bilayer system by fast thermal treatment

    SciTech Connect (OSTI)

    Jin, Lichuan, E-mail: lichuanj@udel.edu, E-mail: hwzhang@uestc.edu.cn; Zhang, Huaiwu, E-mail: lichuanj@udel.edu, E-mail: hwzhang@uestc.edu.cn; Yang, Qinghui; Tang, Xiaoli; Zhong, Zhiyong [State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology, Chengdu 610054 (China); Zhang, Dainan [Department of Electrical and Computer Engineering, University of Delaware, Newark, Delaware 19716 (United States); Xiao, John Q. [Department of Physics and Astronomy, University of Delaware, Newark, Delaware 19716 (United States)

    2014-05-07T23:59:59.000Z

    In this Letter, we investigated the influence of the fast thermal treatment on the spin pumping in ferromagnetic insulator yttrium iron garnet (YIG)/normal metal Au bilayer system. The YIG/Au bilayer thin films were treated by fast annealing process with different temperatures from 0 to 800?°C. The spin pumping was studied using ferromagnetic resonance. The surface evolution was investigated using a high resolution scanning microscopy and an atomic force microscopy. A strong thermal related spin pumping in YIG/Au bilayer system has been revealed. It was found that the spin pumping process can be enhanced by using fast thermal treatment due to the thermal modifications of the Au surface. The effective spin-mixing conductance of the fast thermal treated YIG/Au bilayer has been obtained.

  6. Effect of alkali addition on DC conductivity and thermal properties of vanadium-bismo-borate glasses

    SciTech Connect (OSTI)

    Khasa, S., E-mail: skhasa@rediff.com; Dahiya, M. S., E-mail: skhasa@rediff.com [Physics Department, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131039 (India); Agarwal, A. [Physics Department, Guru Jambheshwara University of Science and Technology, Hisar-125001 (India)

    2014-04-24T23:59:59.000Z

    The DC Conductivity and Differential Thermal Analysis of glasses with composition (30?x)Li{sub 2}O?xV{sub 2}O{sub 5}?20Bi{sub 2}O{sub 3}?50B{sub 2}O{sub 3}(x=15, 10, 5) has been carried out in order to study the effect of replacing the Transition Metal Oxide (TMO) with alkali oxide. A significant increase in the DC conductivity has been observed with increase in alkali content. Again the thermal measurements have shown the decrease in both glass transition temperature (T{sub g}) and crystallization temperature (T{sub x}). The Glass Stability (GS) and Glass Forming Ability (GFA) have also been calculated and these also were found to decrease with increase in alkali oxide content at the cost of TMO.

  7. Potentials for fuel cells in refineries and chlor-alkali plants

    SciTech Connect (OSTI)

    Altseimer, J.H.; Roach, F.

    1986-01-01T23:59:59.000Z

    The market potentials for fuel cell cogeneration systems in petroleum refineries and chlor-alkali plants were evaluated. the most promising application appears to be in chlor-alkali plants where the production process is electricity intensive. Future anticipated changes in the production process are favorable to the use of fuel cells. The energy use in refineries is steam intensive with the required steam pressures ranging from approximately 15 to 650 psig. The near-term use of fuel cell cogeneration in refineries is not as attractive as in chlor-alkali plants. The phosphoric acid fuel cell is the most developed and the most competitive, but its use is limited by its being able to produce only low-pressure steam. Over the longer term, the molten carbonate and the solid oxide fuel cell both of which operate at significantly higher temperatures, are technically very attractive. However, they do not appear to be cost competitive with conventional systems.

  8. Synergistic capture mechanisms for alkali and sulfur species from combustion. Final report

    SciTech Connect (OSTI)

    Peterson, T.W.; Shadman, F.; Wendt, J.O.L.; Mwabe, P.O.

    1994-02-01T23:59:59.000Z

    Experimental work was carried out on a 17 kW, 600 cm long, gas laboratory combustor, to investigate the post flame reactive capture of alkali species by kaolinite. Emphasis was on alkali/sorbent interactions occurring in flue gas at temperatures above the alkali dewpoint and on the formation of water insoluble reaction products. Time-temperature studies were carried out by injecting kaolinite at different axial points along the combustor. The effect of chlorine and sulfur on alkali capture was investigated by doping the flame with SO{sub 2} and Cl{sub 2} gases to simulate coal flame environments. Particle time and temperature history was kept as close as possible to that which would ordinarily be found in a practical boiler. Experiments designed to extract apparent initial reaction rates were carried using a narrow range, 1-2 {mu}m modal size sorbent, while, a coarse, multi size sorbent was used to investigate the governing transport mechanisms. The capture reaction has been proposed to be between alkali hydroxide and activated kaolinite, and remains so in the presence of sulfur and chlorine. The presence of sulfur reduces sodium capture by under 10% at 1300{degree}C. Larger reductions at lower temperatures are attributed to the elevated dewpoint of sodium ({approximately}850{degree}C) with subsequent reduction in sorbent residence time in the alkali gas phase domain. Chlorine reduces sodium capture by 30% across the temperature range covered by the present experiments. This result has been linked to thermodynamic equilibria between sodium hydroxide, sodium chloride and water.

  9. DOI: 10.1002/chem.200702012 Properties of Alkali Metal Atoms Deposited on a MgO Surface: A

    E-Print Network [OSTI]

    Gao, Hongjun

    properties. A classical case is that of lithium-doped MgO in which the presence of monovalent lithium ionsDOI: 10.1002/chem.200702012 Properties of Alkali Metal Atoms Deposited on a MgO Surface,[d] and Hans-Joachim Freund[d] Introduction The interaction of alkali metal atoms with oxide materials

  10. Potential Modulated Intercalation of Alkali Cations into Metal Hexacyanoferrate Coated Electrodes

    SciTech Connect (OSTI)

    Daniel T. Schwartz; Bekki Liu; Marlina Lukman; Kavita M. Jeerage; William A. Steen; Haixia Dai; Qiuming Yu; J. Antonio Medina

    2002-02-18T23:59:59.000Z

    Nickel hexacyanoferrate is a polynuclear inorganic ion intercalation material that loads (intercalates) and elutes (deintercalates) alkali cations from its structure when electrochemically reduced and oxidized, respectively. Nickel hexacyanoferrrate (NiHCF) is known to preferentially intercalate cesium over all other alkali cations, thus providing a basis for a separation scheme that can tackle DOE's radiocesium contamination problem. This program studied fundamental issues in alkalization intercalation and deintercalation in nickel hexacyanoferrate compounds, with the goal of (1) quantifying the ion exchange selectivity properties from cation mixtures, (2) enhancing ion exchange capacities, and (3) and understanding the electrochemically-switched ion exchange process (ESIX).

  11. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, Anthony A. (Allentown, PA)

    1985-01-01T23:59:59.000Z

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  12. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, A.A.

    1985-07-02T23:59:59.000Z

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  13. Ultralow-power local laser control of the dimer density in alkali-metal vapors

    E-Print Network [OSTI]

    Jha, Pankaj K; Yi, Zhenhuan; Yuan, Luqi; Sautenkov, Vladimir A; Rostovtsev, Yuri V; Welch, George R; Zheltikov, Aleksei M; Scully, Marlan O

    2011-01-01T23:59:59.000Z

    Ultralow-power diode-laser radiation is employed to induce photodesorption of cesium from a partially transparent thin-film cesium adsorbate on a solid surface. Using resonant Raman spectroscopy, we demonstrate that this photodesorption process enables an accurate local optical control of the density of dimer molecules in alkali-metal vapors.

  14. Alkali slurry ozonation to produce a high capacity nickel battery material

    DOE Patents [OSTI]

    Jackovitz, John F. (Monroeville, PA); Pantier, Earl A. (Penn Hills, PA)

    1984-11-06T23:59:59.000Z

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  15. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

    1996-09-24T23:59:59.000Z

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

  16. Method for inhibiting alkali metal corrosion of nickel-containing alloys

    DOE Patents [OSTI]

    DeVan, Jackson H. (Oak Ridge, TN); Selle, James E. (Westminster, CO)

    1983-01-01T23:59:59.000Z

    Structural components of nickel-containing alloys within molten alkali metal systems are protected against corrosion during the course of service by dissolving therein sufficient aluminum, silicon, or manganese to cause the formation and maintenance of a corrosion-resistant intermetallic reaction layer created by the interaction of the molten metal, selected metal, and alloy.

  17. COLOUR CENTRES IN DOPED ALKALI HALIDES. THE ROLE OF OXYGEN AND TITANIUM

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    COLOUR CENTRES IN DOPED ALKALI HALIDES. THE ROLE OF OXYGEN AND TITANIUM IN THE LUMINESCENCE OF Li that the luminescence occurs by hole capture at a titanium defect site. However electron spin resonance has shown that the titanium is incorporated in the crystal as Ti3+ and Ti4+ ions with the possibility of charge compensa- tion

  18. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, Marca M. (Hayward, CA); Peng, Marcus Y. (Cupertino, CA); Ma, Yanping (Albany, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    1996-01-01T23:59:59.000Z

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell.

  19. Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis

    E-Print Network [OSTI]

    Romalis, Mike

    Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas M. V. Romalis; published 7 December 2010) Optical pumping of an optically thick atomic vapor typically requires a quenching the atoms. We show that optical pumping of a trace contamination of Rb present in K metal results in a 4

  20. The carbon dioxide solubility in alkali basalts: an experimental PRISCILLE LESNE 1,*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 The carbon dioxide solubility in alkali basalts: an experimental study PRISCILLE LESNE 1 in both fluid and melt is required since, because of its low solubility, carbon dioxide is usually a major in silicate melts dramatically influence the physical properties of magmas, such as density, viscosity

  1. A computational linear elastic fracture mechanics-based model for alkali-silica reaction

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    with the case of a concrete made up of dense aggregates submitted to chemical attack. The chemistry condi- tions are required: high water content, high alkali concentration and reactive ag- gregates first fill the available porous space, and then tend to create microcracks which are thought to play

  2. alkali halide-alkaline earth: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali halide-alkaline earth First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Long range interactions...

  3. Photon self-induced spin-to-orbital conversion in a terbium-gallium-garnet crystal at high laser power

    SciTech Connect (OSTI)

    Mosca, S.; De Rosa, R.; Milano, L. [Dipartimento di Scienze Fisiche, Universita di Napoli 'Federico II', Complesso Universitario di Monte S. Angelo, 80126 Napoli (Italy); INFN Sezione di Napoli, Complesso Universitario di Monte S. Angelo, 80126 Napoli (Italy); Canuel, B.; Genin, E. [EGO, European Gravitational Observatory, Via E. Amaldi, 56021 S. Stefano a Macerata, Cascina (Italy); Karimi, E. [Dipartimento di Scienze Fisiche, Universita di Napoli 'Federico II', Complesso Universitario di Monte S. Angelo, 80126 Napoli (Italy); Piccirillo, B.; Santamato, E. [Dipartimento di Scienze Fisiche, Universita di Napoli 'Federico II', Complesso Universitario di Monte S. Angelo, 80126 Napoli (Italy); CNISM-Consorzio Nazionale Interuniversitario per le Scienze Fisiche della Materia, Napoli (Italy); Marrucci, L. [Dipartimento di Scienze Fisiche, Universita di Napoli 'Federico II', Complesso Universitario di Monte S. Angelo, 80126 Napoli (Italy); CNR-INFM Coherentia, Complesso Universitario di Monte S. Angelo, 80126 Napoli (Italy)

    2010-10-15T23:59:59.000Z

    In this paper, we present experimental evidence of a third-order nonlinear optical process, self-induced spin-to-orbital conversion (SISTOC) of the photon angular momentum. This effect is the physical mechanism at the origin of the depolarization of very intense laser beams propagating in isotropic materials. The SISTOC process, like self-focusing, is triggered by laser heating leading to a radial temperature gradient in the medium. In this work we tested the occurrence of SISTOC in a terbium-gallium-garnet rod for an impinging laser power of about 100 W. To study the SISTOC process we used different techniques: polarization analysis, interferometry, and tomography of the photon orbital angular momentum. Our results confirm, in particular, that the apparent depolarization of the beam is due to the occurrence of maximal entanglement between the spin and orbital angular momentum of the photons undergoing the SISTOC process. This explanation of the true nature of the depolarization mechanism could be of some help in finding novel methods to reduce or to compensate for this usually unwanted depolarization effect in all cases where very high laser power and good beam quality are required.

  4. The influence of high quantity of fly ash on reducing the expansion due to ASR in the presence of alkalis

    E-Print Network [OSTI]

    Mohidekar, Saleel D.

    2000-01-01T23:59:59.000Z

    in Portland cement to prevent the deleterious reaction from occurring. Preliminary work by numerous researchers had indicated that expansive reaction was unlikely to occur when the alkali content of the cement was below 0. 6% NEO, ?by weight of the cemenn... or to be buried underground because it is a potential ground water pollutant. ' So, the research efforts were then directed to demonstrate that portland cement containing higher than the permissible alkali content (according to ASTM C ISO) could be safely used...

  5. Evaluation of the physi- and chemisorption of hydrogen in alkali (Na, Li) doped fullerenes

    SciTech Connect (OSTI)

    Ward, Patrick [University of Tennessee, Knoxville (UTK); Teprovich, Jospeph A. [Savannah River National Laboratory (SRNL); Compton, Robert [ORNL; Affholter, Kathleen A [ORNL; Schwartz, Viviane [ORNL; Veith, Gabriel M [ORNL; Zidan, Ragiay [Savannah River National Laboratory (SRNL)

    2015-01-01T23:59:59.000Z

    Alkali doped fullerenes synthesized by two different solvent assisted mixing techniques are compared for their hydrogen uptake activity. In this study we investigated the interaction of hydrogen with alkali doped fullerenes via physisorption. In addition, we present the first mass spectrometric evidence for the formation of C60H60 via chemisorption. Hydrogen physisorption isotherms up to 1 atm at temperatures ranging from 77-303 K were measured demonstrating an increase in hydrogen uptake versus pure C60 and increased isosteric heats of adsorption for the lithium doped fullerene Li12C60. However, despite these improvements the low amount of physisorbed hydrogen at 1 atm and 77 K in these materials suggests that fullerenes do not possess enough accessible surface area to effectively store hydrogen due to their close packed crystalline nature.

  6. Effects from Alkali-Silica Reacton and Delayed Ettringite Formation on Reinforced Concrete Column Lap Splices

    E-Print Network [OSTI]

    Eck, Mary

    2012-07-16T23:59:59.000Z

    EFFECTS FROM ALKALI-SILICA REACTION AND DELAYED ETTRINGITE FORMATION ON REINFORCED CONCRETE COLUMN LAP SPLICES A Thesis by MARY KATHLEEN ECK Submitted to the Office of Graduate Studies of Texas A&M University in partial... by MARY KATHLEEN ECK Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved by: Chair of Committee, Joseph M. Bracci Committee Members...

  7. Structural Assessment of D-Regions Affected by Alkali-Silica Reaction/Delayed Ettringite Formation

    E-Print Network [OSTI]

    Liu, Shih-Hsiang 1979-

    2012-11-12T23:59:59.000Z

    STRUCTURAL ASSESSMENT OF D-REGIONS AFFECTED BY ALKALI- SILICA REACTION/DELAYED ETTRINGITE FORMATION A Dissertation by SHIH-HSIANG LIU Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved by: Chair of Committee, Joseph M. Bracci Committee Members, John B. Mander Stefan Hurlebaus Harry A. Hogan Head of Department, John M. Niedzwecki December 2012 Major Subject: Civil...

  8. Potentials for Fuel Cells in Refineries and Chlor-Alkali Plants

    E-Print Network [OSTI]

    Altseimer, J. H.; Roach, F.

    POTENTIALS FOR FUEL CELLS IN REFINERIES AND CHLOR-ALKALI PLANTS John H. Altseimer and Fred Roach Los Alamos National Laboratory Los Alamos, New Mexico ABSTRACT The market potentials for fuel cell cogenera tion systems in petroleum refineries... in the production process are favorable to the use of fuel cells. The energy use in refineries is steam intensive with the required steam pressures ranging from approximately 15 to 650 psig. The near-term use of fuel cell cogeneration in refineries...

  9. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1995-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  10. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-31T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  11. Accurate Measurement of Ferrite Garnets to be used for Fast-Tuned loaded cavities in the range of 20-40 MHZ

    E-Print Network [OSTI]

    Vollinger, C

    2012-01-01T23:59:59.000Z

    For the implementation of ferrite-tuned cavities with orthogonally biased ferrites in the frequency range of 20- 40 MHz, different types of ferrite garnets were evaluated in terms of their electromagnetic properties. This paper describes a precision measurement method applicable to small-sized ferrite samples of 1-square-inch surface and 1.8 mm thickness in the given frequency range by means of a one-port reflection method. The material samples are exposed to a magnetic bias field range with different orientations. We present a detailed description of this technique as well as material results obtained.

  12. High-temperature measurements of alkali levels in an experimental 6-inch AFBC

    SciTech Connect (OSTI)

    Anderson, R.J.; Grimm, U.; Romanosky, R.R.

    1981-02-01T23:59:59.000Z

    Alkali metals (K and Na) were measured with an on-line atomic emission (AE) spectrometer in the effluent stream of a 6-inch diameter atmospheric fluidized-bed combustor (AFBC). In an effort to simulate the performance of a pressurized fluidized-bed combustor (PFBC), the AFBC was operated at 1650/sup 0/F and dolomite was used for the bed material. Pittswick coal was burned during the tests. The on-line AE unit monitored a representative fraction of the effluent stream. The sample stream was provided by a specially designed sample system with the inlet port located in the freeboard of the FBC. The sample system was fabricated of Hastalloy X and could be heated up to 1200/sup 0/F. In order to control the size of particles in the sample stream, the sample system contained a cyclone designed to have a cut-off diameter of 10 ..mu..m. Flow through the sample system was regulated by controlling the pressure of the freeboard from 0 to 20 inches of water. In all tests (even when coal was not being burned in the FBC) a ratio of K to Na of about 3 to 1 was observed. This ratio was verified by analysis of aerosol samples for Test 6 (coal and dolomite feed). However, concentrations of alkali as determined by analysis of aerosol samples for Test 6 were about an order of magnitude higher than those measured by the AE unit. Alkali levels (K and Na) on the order of 10 ppM were measured on the sample stream.

  13. Effect of silicate modulus and metakaolin incorporation on the carbonation of alkali silicate-activated slags

    SciTech Connect (OSTI)

    Bernal, Susan A., E-mail: susana.bernal@gmail.co [Materials Engineering Department, Composite Materials Group, CENM, Universidad del Valle, Cali (Colombia); Mejia de Gutierrez, Ruby [Materials Engineering Department, Composite Materials Group, CENM, Universidad del Valle, Cali (Colombia); Provis, John L., E-mail: jprovis@unimelb.edu.a [Department of Chemical and Biomolecular Engineering, University of Melbourne, Victoria 3010 (Australia); Rose, Volker [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

    2010-06-15T23:59:59.000Z

    Accelerated carbonation is induced in pastes and mortars produced from alkali silicate-activated granulated blast furnace slag (GBFS)-metakaolin (MK) blends, by exposure to CO{sub 2}-rich gas atmospheres. Uncarbonated specimens show compressive strengths of up to 63 MPa after 28 days of curing when GBFS is used as the sole binder, and this decreases by 40-50% upon complete carbonation. The final strength of carbonated samples is largely independent of the extent of metakaolin incorporation up to 20%. Increasing the metakaolin content of the binder leads to a reduction in mechanical strength, more rapid carbonation, and an increase in capillary sorptivity. A higher susceptibility to carbonation is identified when activation is carried out with a lower solution modulus (SiO{sub 2}/Na{sub 2}O ratio) in metakaolin-free samples, but this trend is reversed when metakaolin is added due to the formation of secondary aluminosilicate phases. High-energy synchrotron X-ray diffractometry of uncarbonated paste samples shows that the main reaction products in alkali-activated GBFS/MK blends are C-S-H gels, and aluminosilicates with a zeolitic (gismondine) structure. The main crystalline carbonation products are calcite in all samples and trona only in samples containing no metakaolin, with carbonation taking place in the C-S-H gels of all samples, and involving the free Na{sup +} present in the pore solution of the metakaolin-free samples. Samples containing metakaolin do not appear to have the same availability of Na{sup +} for carbonation, indicating that this is more effectively bound in the presence of a secondary aluminosilicate gel phase. It is clear that claims of exceptional carbonation resistance in alkali-activated binders are not universally true, but by developing a fuller mechanistic understanding of this process, it will certainly be possible to improve performance in this area.

  14. Oxygen-consuming chlor alkali cell configured to minimize peroxide formation

    DOE Patents [OSTI]

    Chlistunoff, Jerzy B. (Los Alamos, NM); Lipp, Ludwig (Brookfield, CT); Gottesfeld, Shimshon (Niskayuna, NY)

    2006-08-01T23:59:59.000Z

    Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. The cell included an ion-exchange membrane that divided the cell into an anode chamber including an anode and a cathode chamber including an oxygen gas diffusion cathode. The cathode included a single-piece of electrically conducting graphitized carbon cloth. Catalyst and polytetrafluoroethylene were attached to only one side of the cloth. When the cathode was positioned against the cation exchange membrane with the catalyst side away from the membrane, electrolysis of sodium chloride to chlorine and caustic (sodium hydroxide) proceeded with minimal peroxide formation.

  15. DuraLith Alkali-Aluminosilicate Geopolymer Waste Form Testing for Hanford Secondary Waste

    SciTech Connect (OSTI)

    Gong, W. L.; Lutz, Werner; Pegg, Ian L.

    2011-07-21T23:59:59.000Z

    The primary objective of the work reported here was to develop additional information regarding the DuraLith alkali aluminosilicate geopolymer as a waste form for liquid secondary waste to support selection of a final waste form for the Hanford Tank Waste Treatment and Immobilization Plant secondary liquid wastes to be disposed in the Integrated Disposal Facility on the Hanford Site. Testing focused on optimizing waste loading, improving waste form performance, and evaluating the robustness of the waste form with respect to waste variability.

  16. Alkali vapor pressure modulation on the 100 ms scale in a single-cell vacuum system for cold atom experiments

    SciTech Connect (OSTI)

    Dugrain, Vincent; Reichel, Jakob [Laboratoire Kastler Brossel, ENS, UPMC, CNRS, 24 rue Lhomond, 75005 Paris (France); Rosenbusch, Peter [LNE-SYRTE, Observatoire de Paris, CNRS, UPMC, 61 av de l’Observatoire, 75014 Paris (France)

    2014-08-15T23:59:59.000Z

    We describe and characterize a device for alkali vapor pressure modulation on the 100 ms timescale in a single-cell cold atom experiment. Its mechanism is based on optimized heat conduction between a current-modulated alkali dispenser and a heat sink at room temperature. We have studied both the short-term behavior during individual pulses and the long-term pressure evolution in the cell. The device combines fast trap loading and relatively long trap lifetime, enabling high repetition rates in a very simple setup. These features make it particularly suitable for portable atomic sensors.

  17. Kimzeyite garnet phosphors

    DOE Patents [OSTI]

    Lyons, Robert Joseph

    2013-05-14T23:59:59.000Z

    A phosphor of formula I is included in a phosphor composition in a lighting apparatus capable of emitting white light, Ca.sub.3-x-zSr.sub.xCe.sub.zM.sup.1.sub.2M.sup.2AlSiO.sub.12 (I) wherein M.sup.1 is Hf, Zr, or a combination thereof; M.sup.2 is Al, or a combination of Al and Ga; z<3-x; and 0.2>x.gtoreq.0. The lighting apparatus includes a semiconductor light source in addition to the phosphor composition.

  18. Alkali gabbronorite, ultra-KREEPy melt rock and the diverse suite of clasts in North Ray crater feldspathic fragmental breccia 67975

    SciTech Connect (OSTI)

    Lindstrom, M.M.

    1984-11-15T23:59:59.000Z

    Lunar breccia 67975 is a feldspathic fragmental breccia from North Ray crater, Apollo 16. It contains clasts of alkali gabbronorite and ultra-KREEPy mafic fragment-laden melt breccias, which are unique among Apollo 16 samples. Both are alkali- and iron-rich rocks with moderate to high REE concentrations. They more strongly resemble Apollo 14 gabbronorites and alkali anorthosites and KREEP-rich rocks than they do other Apollo 16 samples. The other clasts in 67975 are the ferroan anorthosites, feldspathic melt rocks, and magnesian granulites, which are typical of other feldspathic fragmental breccias. Examination of bulk and mineral compositions of other breccias and melt rocks suggests that alkali gabbronorite may be a minor component in other North Ray crater breccias and feldspathic melt rocks. This implies that alkali gabbronorite was a fairly early (4.0 b.y.) crustal component in the North Ray crater region.

  19. Hydration of a low-alkali CEM III/B-SiO{sub 2} cement (LAC)

    SciTech Connect (OSTI)

    Lothenbach, Barbara, E-mail: barbara.lothenbach@empa.ch [Empa, Laboratory for Concrete and Construction Chemistry, CH-8600 Duebendorf (Switzerland); Le Saout, Gwenn; Ben Haha, Mohsen; Figi, Renato [Empa, Laboratory for Concrete and Construction Chemistry, CH-8600 Duebendorf (Switzerland); Wieland, Erich [PSI, Laboratory for Waste Management, CH-5232 Villigen PSI (Switzerland)

    2012-02-15T23:59:59.000Z

    The hydration of a low-alkali cement based on CEM III/B blended with 10 wt.% of nanosilica has been studied. The nanosilica reacted within the first days and 90% of the slag reacted within 3.5 years. C-S-H (Ca/Si {approx} 1.2, Al/Si {approx} 0.12), calcite, hydrotalcite, ettringite and possibly straetlingite were the main hydrates. The pore water composition revealed ten times lower alkali concentrations than in Portland cements. Reducing conditions (HS{sup -}) and a pH value of 12.2 were observed. Between 1 month and 3.5 years of hydration more hydrates were formed due to the ongoing slag reaction but no significant differences in the composition of the pore solution or solid phase assemblage were observed. On the basis of thermodynamic calculations it is predicted that siliceous hydrogarnet could form in the long-term and, in the presence of siliceous hydrogarnet, also thaumasite. Nevertheless, even after 3.5 year hydration, neither siliceous hydrogarnet nor thaumasite have been observed.

  20. Sharply tunable group velocity in alkali vapors using a single low-power control field

    E-Print Network [OSTI]

    Pardeep Kumar; Shubhrangshu Dasgupta

    2014-06-20T23:59:59.000Z

    We show how a single linearly polarized control field can produce a sharply tunable group velocity of a weak probe field at resonance in a four-level atomic configuration of alkali vapors. The dispersion can be switched from normal to anomalous along with vanishing absorption, just by changing intensity of the resonant control field. In addition, by allowing different intensities of the different polarization components of the control field, the anomalous dispersion can be switched back to the normal. This thereby creates a "valley of anomaly" in group index variation and offers two sets of control field intensities, for which the system behaves like a vacuum. The explicit analytical expressions for the probe coherence are provided along with all physical explanations. We demonstrate our results in $J = 1/2 \\leftrightarrow J = 1/2$ transition for D_1 lines in alkali atoms, in which one can obtain a group index as large as $3.2\\times10^{8}$ and as negative as $-1.5\\times10^{5}$ using a control field with power as low as 0.017 mW/cm$^2$ and 9.56 mW/cm$^2$ .

  1. Dual alkali approaches for the capture and separation of CO{sub 2}

    SciTech Connect (OSTI)

    Huang, H.P.; Shi, Y.; Li, W.; Chang, S.G.

    2000-04-04T23:59:59.000Z

    The Solvay process utilizes two alkalis in sequential order to convert CO{sub 2} to sodium carbonate for commercial use. The ability to transform CO{sub 2} into sodium carbonate cost-effectively would be a breakthrough in CO{sub 2} sequestration by providing benign long-term storage of CO{sub 2}. However, the Solvay process was not designed for CO{sub 2} sequestration and is not practical for use in the sequestration of CO{sub 2} from fossil fuel power plants. This paper investigates methods to modify the process in order to make it effective for the control of power plant CO{sub 2} emissions. The new modified process, called the Dual Alkali Approach, attempts to replace either or both bases, ammonia and lime, in the Solvay process with other compounds to make CO{sub 2} capture and separation efficient. Ammonia was replaced with different amines in aqueous solutions of salts and it was found that bicarbonate precipitation did occur. A method to regenerate the amine in the second step has not been implemented. However, the second step in Solvay Process has been implemented without using lime, namely, ammonia has been regenerated from an ammonium chloride solution using activated carbon. The HCl adsorbed in the activated carbon was removed by water to regenerate the activated carbon.

  2. Investigation of anti-Relaxation coatings for alkali-metal vapor cells using surface science techniques

    SciTech Connect (OSTI)

    Seltzer, S. J.; Michalak, D. J.; Donaldson, M. H.; Balabas, M. V.; Barber, S. K.; Bernasek, S. L.; Bouchiat, M.-A.; Hexemer, A.; Hibberd, A. M.; Jackson Kimball, D. F.; Jaye, C.; Karaulanov, T.; Narducci, F. A.; Rangwala, S. A.; Robinson, H. G.; Shmakov, A. K.; Voronov, D. L.; Yashchuk, V. V.; Pines, A.; Budker, D.

    2010-10-11T23:59:59.000Z

    Many technologies based on cells containing alkali-metal atomic vapor benefit from the use of antirelaxation surface coatings in order to preserve atomic spin polarization. In particular, paraffin has been used for this purpose for several decades and has been demonstrated to allow an atom to experience up to 10?000 collisions with the walls of its container without depolarizing, but the details of its operation remain poorly understood. We apply modern surface and bulk techniques to the study of paraffin coatings in order to characterize the properties that enable the effective preservation of alkali spin polarization. These methods include Fourier transform infrared spectroscopy, differential scanning calorimetry, atomic force microscopy, near-edge x-ray absorption fine structure spectroscopy, and x-ray photoelectron spectroscopy. We also compare the light-induced atomic desorption yields of several different paraffin materials. Experimental results include the determination that crystallinity of the coating material is unnecessary, and the detection of C=C double bonds present within a particular class of effective paraffin coatings. Further study should lead to the development of more robust paraffin antirelaxation coatings, as well as the design and synthesis of new classes of coating materials.

  3. Origin of alkali-feldspar granites: An example from the Poimena Granite, northeastern Tasmania, Australia

    SciTech Connect (OSTI)

    Mackenzie, D.E.; Black, L.P.; Sun, Shensu (Bureau of Mineral Resources, Canberra (Australia))

    1988-10-01T23:59:59.000Z

    The Lottah Granite is a composite pluton of tin mineralized strongly peraluminous alkali-feldspar granite which intrudes the Poimena Granite, a major component of the mid-Devonian Blue Tier Batholith of northeastern Tasmania. Earlier workers interpreted the Lottah Granite as a metasomatised differentiate of the Poimena Granite. The Poimena Granite is a slightly peraluminous, felsic, I-type biotite granite which contains restite minerals and shows linear trends on Harker plots, both consistent with restite separation. The mineralogy, chemical variation, and isotopic characteristics of the Lottah Granite are consistent with origin as a magma genetically unrelated to the host granite. The Lottah Granite contains sanidine, albite, topaz, zinnwaldite and other minerals consistent with crystallization from a melt. Furthermore, Rb-Sr isotopic dating indicates that the Lottah Granite was emplaced about 10 Ma after the Poimena Granite, and initial Sr and Nd isotope ratios indicate that the Lottah Granite was derived from a higher-{sup 87}Sr/{sup 86}Sr, higher-{epsilon}Nd source composition. Chemical and mineralogical evolution of the Lottah Granite conform to the experimental behavior of Li-F-rich melts, and indicate a possible crystallization temperature range as extreme as 750-430{degree}C. Many other examples of alkali-feldspar granite, and much of the associated mineralization, are probably also of essentially primary magmatic origin rather than of metasomatic or hydrothermal origin as commonly interpreted. They may also be genetically unrelated to granites with which they are associated.

  4. Raman Analysis of Perrhenate and Pertechnetate in Alkali Salts and Borosilicate Glasses

    SciTech Connect (OSTI)

    Gassman, Paul L.; McCloy, John S.; Soderquist, Chuck Z.; Schweiger, Michael J.

    2014-01-03T23:59:59.000Z

    Sodium borosilicate glasses containing various concentrations of rhenium or technetium were fabricated, and their vibrational spectra studied using a Raman microscope. Spectra were interpreted with reference to new high resolution measurements of alkali pertechnetates and perrhenates NaReO4, KReO4, NaTcO4, and KTcO4. At low concentrations of ReO4- or TcO4-, glass spectra show weak peaks superimposed on a dominant spectrum of glass characteristic of silicate and borate network vibrations. At high concentrations, sharp peaks characteristic of crystal field splitting and C4h symmetry dominate the spectra of glasses, indicating alkali nearby tetrahedral Re or Tc. Often peaks indicative of both the K and Na pertechnetates/ perrhenates are evident in the Raman spectrum, with the latter being favored at high additions of the source chemical, since Na is more prevalent in the glass and ion exchange takes place. These results have significance to immobilization of nuclear waste containing radioactive 99Tc in glass for ultimate disposal.

  5. The development of high-performance alkali-hybrid polarized He3 targets for electron scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, Jaideep T. [University of Virginia, Charlottesville, VA (United States); Argonne National Lab., Argonne, IL (United States); Technische Universitat Munchen, Exzellenzcluster Universe, Garching, Germany (Europe); Dolph, Peter A.M. [University of Virginia, Charlottesville, VA (United States); Tobias, William Al [University of Virginia, Charlottesville, VA (United States); Averett, Todd D. [College of William and Mary, Williamsburg, VA (United States); Kelleher, Aiden [College of William and Mary, Williamsburg, VA (United States); Mooney, K. E. [University of Virginia, Charlottesville, VA (United States); Nelyubin, Vladimir V. [University of Virginia, Charlottesville, VA (United States); Wang, Yunxiao [University of Virginia, Charlottesville, VA (United States); Zheng, Yuan [University of Virginia, Charlottesville, VA (United States); Cates, Gordon D. [University of Virginia, Charlottesville, VA (United States)

    2015-05-01T23:59:59.000Z

    We present the development of high-performance polarized ³He targets for use in electron scattering experiments that utilize the technique of alkali-hybrid spin-exchange optical pumping. We include data obtained during the characterization of 24 separate target cells, each of which was constructed while preparing for one of four experiments at Jefferson Laboratory in Newport News, Virginia. The results presented here document dramatic improvement in the performance of polarized ³He targets, as well as the target properties and operating parameters that made those improvements possible. Included in our measurements were determinations of the so-called X-factors that quantify a temperature-dependent and as-yet poorly understood spin-relaxation mechanism that limits the maximum achievable ³He polarization to well under 100%. The presence of this spin-relaxation mechanism was clearly evident in our data. We also present results from a simulation of the alkali-hydrid spin-exchange optical pumping process that was developed to provide guidance in the design of these targets. Good agreement with actual performance was obtained by including details such as off-resonant optical pumping. Now benchmarked against experimental data, the simulation is useful for the design of future targets. Included in our results is a measurement of the K- ³He spin-exchange rate coefficient $k^\\mathrm{K}_\\mathrm{se} = \\left ( 7.46 \\pm 0.62 \\right )\\!\\times\\!10^{-20}\\ \\mathrm{cm^3/s}$ over the temperature range 503 K to 563 K.

  6. Optically pumped alkali laser and amplifier using helium-3 buffer gas

    DOE Patents [OSTI]

    Beach, Raymond J. (Livermore, CA); Page, Ralph (Castro Valley, CA); Soules, Thomas (Livermore, CA); Stappaerts, Eddy (San Ramon, CA); Wu, Sheldon Shao Quan (Livermore, CA)

    2010-09-28T23:59:59.000Z

    In one embodiment, a laser oscillator is provided comprising an optical cavity, the optical cavity including a gain medium including an alkali vapor and a buffer gas, the buffer gas including .sup.3He gas, wherein if .sup.4He gas is also present in the buffer gas, the ratio of the concentration of the .sup.3He gas to the .sup.4He gas is greater than 1.37.times.10.sup.-6. Additionally, an optical excitation source is provided. Furthermore, the laser oscillator is capable of outputting radiation at a first frequency. In another embodiment, an apparatus is provided comprising a gain medium including an alkali vapor and a buffer gas including .sup.3He gas, wherein if .sup.4He gas is also present in the buffer gas, the ratio of the concentration of the .sup.3He gas to the .sup.4He gas is greater than 1.37.times.10.sup.-6. Other embodiments are also disclosed.

  7. 3718-F Alkali Metal Treatment and Storage Facility Closure Plan. Revision 1

    SciTech Connect (OSTI)

    none,

    1992-11-01T23:59:59.000Z

    The Hanford Site, located northwest of the city of Richland, Washington, houses reactors, chemical-separation systems, and related facilities used for the production of special nuclear materials, as well as for activities associated with nuclear energy development. The 300 Area of the Hanford Site contains reactor fuel manufacturing facilities and several research and development laboratories. The 3718-F Alkali Metal Treatment and Storage Facility (3718-F Facility), located in the 300 Area, was used to store and treat alkali metal wastes. Therefore, it is subject to the regulatory requirements for the storage and treatment of dangerous wastes. Closure will be conducted pursuant to the requirements of the Washington Administrative Code (WAC) 173-303-610 (Ecology 1989) and 40 CFR 270.1. Closure also will satisfy the thermal treatment facility closure requirements of 40 CFR 265.381. This closure plan presents a description of the 3718-F Facility, the history of wastes managed, and the approach that will be followed to close the facility. Only hazardous constituents derived from 3718-F Facility operations will be addressed.

  8. A comparative transport study of Bi{sub 2}Se{sub 3} and Bi{sub 2}Se{sub 3}/yttrium iron garnet

    SciTech Connect (OSTI)

    Jiang, Zilong; Tang, Chi; Shi, Jing [Department of Physics and Astronomy, University of California, Riverside, California 92521 (United States); Katmis, Ferhat; Wei, Peng; Moodera, Jagadeesh S. [Francis Bitter Magnet Laboratory, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2014-06-02T23:59:59.000Z

    Bilayers of 20 quintuple layer Bi{sub 2}Se{sub 3} on 30?nm thick yttrium iron garnet (YIG) have been grown with molecular beam epitaxy in conjunction with pulsed laser deposition. The presence of the ferri-magnetic insulator YIG causes additional scattering to the surface states of the Bi{sub 2}Se{sub 3} topological insulator layer, as indicated by the temperature dependence of the resistivity. From the two-channel analysis of the Hall data, we find that the surface contribution in the bilayer samples is greatly reduced. Furthermore, the weak antilocalization effect from the surface states is clearly suppressed due to the presence of the YIG layer.

  9. THE HEIDELBERG POLARIZED ALKALI SOURCE E. STEFFENS, W. DREVES, P. EGELHOF, D. KASSEN, W. WEISS, P. ZUPRANSKI (*) and D. FICK

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and 23Na (see Fig. 2). Alkali metal vapour leaves a heated oven through a Laval nozzle and the atomic are oriented parallel which allows for the induction of o-transitions only (AF = 1, 0394mF = 0). The static

  10. Ultralow-power local laser control of the dimer density in alkali-metal vapors through photodesorption

    E-Print Network [OSTI]

    Pankaj K. Jha; Konstantin E. Dorfman; Zhenhuan Yi; Luqi Yuan; Vladimir A. Sautenkov; Yuri V. Rostovtsev; George R. Welch; Aleksei M. Zheltikov; Marlan O. Scully

    2012-10-08T23:59:59.000Z

    Ultralow-power diode-laser radiation is employed to induce photodesorption of cesium from a partially transparent thin-film cesium adsorbate on a solid surface. Using resonant Raman spectroscopy, we demonstrate that this photodesorption process enables an accurate local optical control of the density of dimer molecules in alkali-metal vapors.

  11. Interactions of hydrogen with alkali promoted Ru/SiO{sub 2} catalysts: A proton NMR study

    SciTech Connect (OSTI)

    Ozbay, U.D.

    1994-05-10T23:59:59.000Z

    Role of H spillover to the silica support was studied using chemisorption; a strongly bound component of spilled over H was found in the silica support which interfered with accurate measurements of active metal sites via volumetric strong H chemisorption. The volumetric chemisorption technique was modified so that measurement times were reduced from 12--36 h to 1 h. The active Ru surface was characterized means of changes in proton spin counts and NMR Knight shifts vs alkali loading. Na, K blocked the active surface of Ru metal, but Cs was pushed off by H chemisorption. The alkali promoters restricted H mobility on both metal surface and at the metal support interfaces; this is consistent with effects on Fischer-Tropsch synthesis. {sup 1}H NMR was used to study the effect of the active metal and promoter on support hydroxyl groups. The OH group density in the silica support decreased with metal and/or promoter loading, but not on a one-to-one basis; the exchange efficiency of the hydroxyls decreased with atomic size of the alkali metal. An additional downfield proton resonance was detected which was assigned to the alkali hydroxide species in the support.

  12. The influence of high quantity of fly ash on reducing the expansion due to ASR in the presence of alkalis 

    E-Print Network [OSTI]

    Mohidekar, Saleel D.

    2000-01-01T23:59:59.000Z

    was 58% by mass of cement. A reactive siliceous aggregate was used. The influence of inherent alkalis in cement to the reaction was also studied. The test results confirm that HVFA significantly helps in controlling expansion caused by ASR. The test...

  13. Rheological properties of water-coal slurries based on brown coal in the presence of sodium lignosulfonates and alkali

    SciTech Connect (OSTI)

    D.P. Savitskii; A.S. Makarov; V.A. Zavgorodnii [National Academy of Sciences of Ukraine, Kiev (Ukraine). Dumanskii Institute of Colloid and Water Chemistry

    2009-07-01T23:59:59.000Z

    The effect of the oxidized surface of brown coal on the structural and rheological properties of water-coal slurries was found. The kinetics of structure formation processes in water-coal slurries based on as-received and oxidized brown coal was studied. The effect of lignosulfonate and alkali additives on the samples of brown coal was considered.

  14. Structural features of alkali and barium aluminofluorophosphate glasses studied by IR spectroscopy

    SciTech Connect (OSTI)

    Urusovskaya, L.N.; Smirnova, E.V. [Research and Technological Institute of Optical Materials Science, State Scientific Center, St. Petersburg (Russian Federation)

    1995-03-01T23:59:59.000Z

    IR reflection spectra of the Al(PO{sub 3}){sub 3}-MeF{sub x} glasses (Me=Li, Na, K, Ba) with the maximum content of fluoride varied for each specific glass within certain concentration limits are considered. Analysis of the spectra for glasses obtained upon variation in the content of alkali metal fluoride introduced into these glasses has demonstrated that the increase in the MeF{sub x} content leads to breaking the chain groupings and forming the [PO{sub 3}F]{sup 2-} groups, whereas the rise in concentration of barium fluoride in the Al(PO{sub 3}){sub 3}-BaF{sub 2} glasses brings about the stabilization of the chain structures.

  15. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1995-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  16. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-24T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  17. The development of high-performance alkali-hybrid polarized He3 targets for electron scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, Jaideep T.; Dolph, Peter A.M.; Tobias, William Al; Averett, Todd D.; Kelleher, Aiden; Mooney, K. E.; Nelyubin, Vladimir V.; Wang, Yunxiao; Zheng, Yuan; Cates, Gordon D.

    2015-05-01T23:59:59.000Z

    We present the development of high-performance polarized ³He targets for use in electron scattering experiments that utilize the technique of alkali-hybrid spin-exchange optical pumping. We include data obtained during the characterization of 24 separate target cells, each of which was constructed while preparing for one of four experiments at Jefferson Laboratory in Newport News, Virginia. The results presented here document dramatic improvement in the performance of polarized ³He targets, as well as the target properties and operating parameters that made those improvements possible. Included in our measurements were determinations of the so-called X-factors that quantify a temperature-dependent and as-yet poorlymore »understood spin-relaxation mechanism that limits the maximum achievable ³He polarization to well under 100%. The presence of this spin-relaxation mechanism was clearly evident in our data. We also present results from a simulation of the alkali-hydrid spin-exchange optical pumping process that was developed to provide guidance in the design of these targets. Good agreement with actual performance was obtained by including details such as off-resonant optical pumping. Now benchmarked against experimental data, the simulation is useful for the design of future targets. Included in our results is a measurement of the K- ³He spin-exchange rate coefficient $k^\\mathrm{K}_\\mathrm{se} = \\left ( 7.46 \\pm 0.62 \\right )\\!\\times\\!10^{-20}\\ \\mathrm{cm^3/s}$ over the temperature range 503 K to 563 K.« less

  18. Water adsorption, solvation and deliquescence of alkali halide thin films on SiO2 studied by ambient pressure X-ray photoelectron spectroscopy

    E-Print Network [OSTI]

    Arima, Kenta

    2011-01-01T23:59:59.000Z

    Water adsorption, solvation and deliquescence of alkali94720, USA Abstract The adsorption of water on KBr thinBr and Cl, but not for F upon adsorption of water and after

  19. Methods of use of calcium hexa aluminate refractory linings and/or chemical barriers in high alkali or alkaline environments

    DOE Patents [OSTI]

    McGowan, Kenneth A; Cullen, Robert M; Keiser, James R; Hemrick, James G; Meisner, Roberta A

    2013-10-22T23:59:59.000Z

    A method for improving the insulating character/and or penetration resistance of a liner in contact with at least one of an alkali and/or alkaline environments is provided. The method comprises lining a surface that is subject to wear by an alkali environment and/or an alkaline environment with a refractory composition comprising a refractory aggregate consisting essentially of a calcium hexa aluminate clinker having the formula CA.sub.6, wherein C is equal to calcium oxide, wherein A is equal to aluminum oxide, and wherein the hexa aluminate clinker has from zero to less than about fifty weight percent C.sub.12A.sub.7, and wherein greater than 98 weight percent of the calcium hexa aluminate clinker having a particle size ranging from -20 microns to +3 millimeters, for forming a liner of the surface. This method improves the insulating character/and or penetration resistance of the liner.

  20. Dhanya Mary Abraham Reece Larson Adamson

    E-Print Network [OSTI]

    Lozano-Robledo, Alvaro

    James R Boivie John William Bojorquez Lindsey Elizabeth Bonitz Olivia Ann Bonner Dean's List Spring 2014 Curran Tapan Paresh Dalal Tara Lin D'Ambruoso Zachary James D'Amico David Clark Daniels Corey Danko Ian

  1. Larson,Cheryl A * PS-6

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 - -/e),,sand CERNLandLargefor HighDOE

  2. A computational analysis of the evaporator/artery of an alkali metal thermal to electric conversion (AMTEC) PX series cell

    E-Print Network [OSTI]

    Pyrtle, Frank

    1999-01-01T23:59:59.000Z

    , while minimizing mass. Current technology, such as Radioisotope Thermoelectric Generators (RTG's) are reliable, but do not supply the power conversion efficiencies desired for future space missions. That leads to Alkali Metal Thermal to Electric...-series cells to generate electricity for the deep space vehicle. The higher efficiency of AMTEC compared to other conversion technologies, such as Radioisotope Thermoelectric Generators (RTG's), results in less energy source material being launched...

  3. The etching process of boron nitride by alkali and alkaline earth fluorides under high pressure and high temperature

    SciTech Connect (OSTI)

    Guo, W., E-mail: guowei1982cry@163.com [College of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024 (China); National Key Lab of Superhard Materials, Jilin University, Changchun 130012 (China); Ma, H.A.; Jia, X. [National Key Lab of Superhard Materials, Jilin University, Changchun 130012 (China)

    2014-03-01T23:59:59.000Z

    Graphical abstract: - Highlights: • Appropriate etch processes of hBN and cBN under HPHT are proposed. • The degree of the crystallization of hBN was decreased. • A special cBN growth mechanism with a triangular unit is proposed. • Plate-shape cBN crystals with large ratio of length to thickness were obtained. • A strategy provides useful guidance for controlling the cBN morphology. - Abstract: Some new etching processes of hexagonal boron nitride (hBN) and cubic boron nitride (cBN) under high pressure and high temperature in the presence of alkali and alkaline earth fluorides have been discussed. It is found that hBN is etched distinctly by alkali and alkaline earth fluorides and the morphology of hBN is significantly changed from plate-shape to spherical-shape. Based on the “graphitization index” values of hBN, the degree of the crystallization of hBN under high pressure and high temperature decreases in the sequence of LiF > CaF{sub 2} > MgF{sub 2}. This facilitates the formation of high-quality cBN single crystals. Different etch steps, pits, and islands are observed on cBN surface, showing the strong etching by alkali and alkaline earth fluorides and the tendency of layer-by-layer growth. A special layer growth mechanism of cBN with a triangular unit has been found. Furthermore, the morphologies of cBN crystals are apparently affected by a preferential surface etching of LiF, CaF{sub 2} and MgF{sub 2}. Respectively, the plate-shape and tetrahedral cBN crystals can be obtained in the presence of different alkali and alkaline earth fluorides.

  4. Internal Spin Control, Squeezing and Decoherence in Ensembles of Alkali Atomic Spins

    E-Print Network [OSTI]

    Leigh M. Norris

    2014-10-01T23:59:59.000Z

    This dissertation studies spin squeezing, entanglement and decoherence in large ensembles of cold, trapped alkali atoms with hyperfine spin f interacting with optical fields. Restricting the state of each atom to a qutrit embedded in the 2f+1 dimensional hyperfine spin enables us to efficiently model the coherent and dissipative dynamics of the ensemble. This formalism also allows us to explore the effects of local control on the internal hyperfine spins of the atoms. State preparation using such control increases the entangling power of the atom-light interface for f>1/2. Subsequent control of the internal spins converts entanglement into metrologically relevant spin squeezing. In the case of squeezing by quantum nondemolition measurement, we employ a numerical search to find state preparations that maximize spin squeezing in the presence of decoherence. Dissipative dynamics on our system include optical pumping due to spontaneous emission. While most works ignore optical pumping or treat it phenomenologically, we employ a master equation derived from first principles. This work is extended to the case of an atomic ensemble interacting with a non-homogeneous paraxial probe. The geometries of the ensemble and the probe are optimized to maximize both spatial mode matching and spin squeezing.

  5. Cellular morphology of organic-inorganic hybrid foams based on alkali alumino-silicate matrix

    SciTech Connect (OSTI)

    Verdolotti, Letizia; Capasso, Ilaria; Lavorgna, Marino [Institute of Composite and Biomedical Materials, National Research Council, Naples (Italy); Liguori, Barbara; Caputo, Domenico [Department of Chemical, Materials and Industrial Engineering, University of Naples Federico II, Naples (Italy); Iannace, Salvatore [Institute of Composite and Biomedical Materials, National Research Council, Naples, Italy and IMAST SCRAL, Piazza Bovio 22 Napoli 80133 (Italy)

    2014-05-15T23:59:59.000Z

    Organic-inorganic hybrid foams based on an alkali alumino-silicate matrix were prepared by using different foaming methods. Initially, the synthesis of an inorganic matrix by using aluminosilicate particles, activated through a sodium silicate solution, was performed at room temperature. Subsequently the viscous paste was foamed by using three different methods. In the first method, gaseous hydrogen produced by the oxidization of Si powder in an alkaline media, was used as blowing agent to generate gas bubbles in the paste. In the second method, the porous structure was generated by mixing the paste with a “meringue” type of foam previously prepared by whipping, under vigorous stirring, a water solution containing vegetal proteins as surfactants. In the third method, a combination of these two methods was employed. The foamed systems were consolidated for 24 hours at 40°C and then characterized by FTIR, X-Ray diffraction, scanning electron microscopy (SEM) and compression tests. Low density foams (?500 Kg/m{sup 3}) with good cellular structure and mechanical properties were obtained by combining the “meringue” approach with the use of the chemical blowing agent based on Si.

  6. Influence of steel fibers on the development of alkali-aggregate reaction

    SciTech Connect (OSTI)

    Pires de Carvalho, Maria Rita [COPPE/Universidade Federal do Rio de Janeiro, Civil Engineering Department, P.B. 68506, CEP 21941-972, Rio de Janeiro-RJ (Brazil); Moraes Rego Fairbairn, Eduardo de, E-mail: eduardo@coc.ufrj.b [COPPE/Universidade Federal do Rio de Janeiro, Civil Engineering Department, P.B. 68506, CEP 21941-972, Rio de Janeiro-RJ (Brazil); Dias Toledo Filho, Romildo [COPPE/Universidade Federal do Rio de Janeiro, Civil Engineering Department, P.B. 68506, CEP 21941-972, Rio de Janeiro-RJ (Brazil); Chagas Cordeiro, Guilherme [Universidade Estadual Norte Fluminense Darcy Ribeiro, Laboratory of Civil Engineering, Campos dos Goytacazes-RJ (Brazil); Pagan Hasparyk, Nicole [FURNAS Centrais Eletricas S.A., DCT.C., Aparecida de Goiania-GO (Brazil)

    2010-04-15T23:59:59.000Z

    This work presents the results of an experimental research concerning the use of fibers in mortar specimens subjected to alkali-aggregate reaction (AAR). Two types of steel fibers (0.16 mm diameter and 6.0 mm length, and 0.20 mm diameter and 13.0 mm length) were used with fiber volume contents of 1% and 2%. Besides the expansion accelerated tests, compressive tests and flexural tests have also been carried out to display the main mechanical characteristics of the fiber-reinforced mortars after being subjected to AAR. Moreover, the microstructure of the specimens was analyzed by scanning electron microscopy and energy dispersive X-ray. The results shown that the addition of steel fibers reduced the expansion due to AAR for the experimental conditions studied in this paper. The most expressive benefit corresponded to the addition of 13.0 mm fibers in the mixture containing 2% fiber content. This fiber volume content also corresponded to the maximum increment in the mechanical properties compared to the reference mortar, mainly for the post-cracking strength and for the toughness in bending. It was observed that the fibers have a beneficial effect on the material, without compromising its main mechanical properties.

  7. An Alkali-Vapor Cell with Metal Coated Windows for Efficient Application of an Electric Field

    E-Print Network [OSTI]

    Sarkisyan, D; Guena, J; Lintz, M; Bouchiat, M A; Sarkisyan, David; Gu\\'{e}na, Jocelyne; Lintz, Michel; Bouchiat, Marie-Anne

    2005-01-01T23:59:59.000Z

    We describe the implementation of a cylindrical T-shaped alkali-vapor cell for laser spectroscopy in the presence of a longitudinal electric field. The two windows are used as two electrodes of the high-voltage assembly, which is made possible by a metallic coating which entirely covers the inner and outer sides of the windows except for a central area to let the laser beams in and out of the cell. This allows very efficient application of the electric field, up to 2 kV/cm in a rather dense superheated vapor, even when significant photoemission takes place at the windows during pulsed laser irradiation. The body of the cell is made of sapphire or alumina ceramic to prevent large currents resulting from surface conduction observed in cesiated glass cells. The technique used to attach the monocrystalline sapphire windows to the cell body causes minimal stress birefringence in the windows. In addition, reflection losses at the windows can be made very small. The vapor cell operates with no buffer gas and has no ...

  8. Transformation of alkali metals during pyrolysis and gasification of a lignite

    SciTech Connect (OSTI)

    Xiaofang Wei; Jiejie Huang; Tiefeng Liu; Yitian Fang; Yang Wang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-05-15T23:59:59.000Z

    Transformation of Na and K in a lignite was investigated during pyrolysis and gasification in a fixed-bed by using a serial dissolution method with H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solutions. The evolution of the fractions of four forms in solid and alkali volatilization during pyrolysis and gasification was determined. The results show that a different mode of occurrence between Na and of K in coal existed. Na in coal can be nearly completely dissolved by H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solution. However, K in coal exists almost in the stable forms. Both H{sub 2}O soluble and CH{sub 3}COONH{sub 4} soluble Na and K fractions decline during pyrolysis and early gasification stage and increase a little with the process of char gasification. The stable form Na in the char produced during pyrolysis is transferred to other forms during char gasification via the pore opening and a series of chemical reactions. Na{sub 2}SO{sub 4} (K{sub 2}SO{sub 4}) may play an important role in producing stable forms such as Na{sub 2}O.Al{sub 2}O{sub 3}2SiO{sub 2} and K{sub 2}O.Al{sub 2}O{sub 3}.2SiO{sub 2} during pyrolysis. The fraction of HCl soluble K increases during pyrolysis but decreases markedly during the early gasification stage. 20 refs., 7 figs., 1 tabs.

  9. Theoretical simulations of protective thin film Fabry-Pérot filters for integrated optical elements of diode pumped alkali lasers (DPAL)

    SciTech Connect (OSTI)

    Quarrie, L., E-mail: Lindsay.Quarrie@l-3com.com, E-mail: lindsay.o.quarrie@gmail.com [New Mexico Institute of Mining and Technology, Department of Materials Engineering, 801 LeRoy Place, Socorro, NM 87801 (United States); Air Force Research Laboratory, AFRL/RDLC Laser CoE, 3550 Aberdeen Avenue SE, Kirtland AFB, NM 87117-5776 (United States)

    2014-09-15T23:59:59.000Z

    The lifetime of Diode-Pumped Alkali Lasers (DPALs) is limited by damage initiated by reaction of the glass envelope of its gain medium with rubidium vapor. Rubidium is absorbed into the glass and the rubidium cations diffuse through the glass structure, breaking bridging Si-O bonds. A damage-resistant thin film was developed enhancing high-optical transmission at natural rubidium resonance input and output laser beam wavelengths of 780 nm and 795 nm, while protecting the optical windows of the gain cell in a DPAL. The methodology developed here can be readily modified for simulation of expected transmission performance at input pump and output laser wavelengths using different combination of thin film materials in a DPAL. High coupling efficiency of the light through the gas cell was accomplished by matching the air-glass and glass-gas interfaces at the appropriate wavelengths using a dielectric stack of high and low index of refraction materials selected to work at the laser energies and protected from the alkali metal vapor in the gain cell. Thin films as oxides of aluminum, zirconium, tantalum, and silicon were selected allowing the creation of Fabry-Perot optical filters on the optical windows achieving close to 100% laser transmission in a solid optic combination of window and highly reflective mirror. This approach allows for the development of a new whole solid optic laser.

  10. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: thermal cycle stability and chemical compatibility

    SciTech Connect (OSTI)

    Chou, Y. S.; Thomsen, Edwin C.; Williams, Riley T.; Choi, Jung-Pyung; Canfield, Nathan L.; Bonnett, Jeff F.; Stevenson, Jeffry W.; Shyam, Amit; Lara-Curzio, E.

    2011-03-01T23:59:59.000Z

    An alkali silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel (SOFC) applications. The glass containing ~17 mole% alkalis (K2O and Na2O) remains vitreous and compliant during SOFC operation, unlike conventional SOFC sealing glasses, which experience substantial devitrification after the sealing process. The non-crystallizing compliant sealing glass has lower glass transition and softening temperatures since the microstructure remains glassy without significant crystallite formation, and hence can relieve or reduce residual stresses and also has the potential for crack healing. Sealing approaches based on compliant glass will also need to satisfy all the mechanical, thermal, chemical, physical, and electrical requirements for SOFC applications, not only in bulk properties but also at sealing interfaces. In this first of a series of papers we will report the thermal cycle stability of the glass when sealed between two SOFC components, i.e., a NiO/YSZ anode supported YSZ bilayer and a coated ferritic stainless steel interconnect material. High temperature leak rates were monitored versus thermal cycles between 700-850oC using back pressures ranging from 0.2 psi to 1.0 psi. Isothermal stability was also evaluated in a dual environment consisting of flowing dilute H2 fuel versus ambient air. In addition, chemical compatibility at the alumina and YSZ interfaces was examined with scanning electron microscopy and energy dispersive spectroscopy. The results shed new light on the topic of SOFC glass seal development.

  11. Cathodoluminescence microscopy and petrographic image analysis of aggregates in concrete pavements affected by alkali-silica reaction

    SciTech Connect (OSTI)

    Stastna, A., E-mail: astastna@gmail.com [Institute of Geochemistry, Mineralogy and Mineral Resources, Faculty of Science, Charles University in Prague, Albertov 6, 128 43 Praha 2 (Czech Republic); Sachlova, S.; Pertold, Z.; Prikryl, R. [Institute of Geochemistry, Mineralogy and Mineral Resources, Faculty of Science, Charles University in Prague, Albertov 6, 128 43 Praha 2 (Czech Republic); Leichmann, J. [Department of Geological Sciences, Faculty of Science, Masaryk University in Brno, Kotlarska 267/2, 611 37 Brno (Czech Republic)

    2012-03-15T23:59:59.000Z

    Various microscopic techniques (cathodoluminescence, polarizing and electron microscopy) were combined with image analysis with the aim to determine a) the modal composition and degradation features within concrete, and b) the petrographic characteristics and the geological types (rocks, and their provenance) of the aggregates. Concrete samples were taken from five different portions of Highway Nos. D1, D11, and D5 (the Czech Republic). Coarse and fine aggregates were found to be primarily composed of volcanic, plutonic, metamorphic and sedimentary rocks, as well as of quartz and feldspar aggregates of variable origins. The alkali-silica reaction was observed to be the main degradation mechanism, based upon the presence of microcracks and alkali-silica gels in the concrete. Use of cathodoluminescence enabled the identification of the source materials of the quartz aggregates, based upon their CL characteristics (i.e., color, intensity, microfractures, deformation, and zoning), which is difficult to distinguish only employing polarizing and electron microscopy. - Highlights: Black-Right-Pointing-Pointer ASR in concrete pavements on the Highways Nos. D1, D5 and D11 (Czech Republic). Black-Right-Pointing-Pointer Cathodoluminescence was combined with various microscopic techniques and image analysis. Black-Right-Pointing-Pointer ASR was attributed to aggregates. Black-Right-Pointing-Pointer Source materials of aggregates were identified based on cathodoluminescence characteristics. Black-Right-Pointing-Pointer Quartz comes from different volcanic, plutonic and metamorphic parent rocks.

  12. Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry

    SciTech Connect (OSTI)

    Baxter, Larry L.

    2008-06-09T23:59:59.000Z

    This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt mixtures and compared with sodium-based binary and higher order systems. Predictions and measurements were demonstrated for both salt systems and for some more complex silicate-bearing systems, substantially exceeding the original scope of this work. 4. A multi-dimensional model of char bed reactivity developed under this project demonstrated that essentially all reactions in char beds occur on or near the surface, with the internal portions of the bed being essentially inert. The model predicted composition, temperature, and velocity profiles in the bed and showed that air jet penetration is limited to the immediate vicinity of the char bed, with minimal impact on most of the bed. The modeling efforts substantially exceeded the original scope of this project. 5. Near the completion of this project, DOE withdrew the BYU portion of a multiparty agreement to complete this and additional work with no advanced warning, which compromised the integration of all of this material into a commercial computer code. However, substantial computer simulations of much of this work were initiated, but not completed. 6. The gasification modeling is nearly completed but was aborted near its completion according to a DOE redirection of funds. This affected both this and the previous tasks.

  13. MOSSBAUER STUDY OF Fe(ll) DOPED ALKALI CHLORIDE CRYSTALS AND DEFECT STRUCTURE Y. Takashima, N. Kai, T. Nishida and L. Chandler*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    MOSSBAUER STUDY OF Fe(ll) DOPED ALKALI CHLORIDE CRYSTALS AND DEFECT STRUCTURE Y. Takashima, N. Kai-ray diffraction measurements and absorption Mossbauer spectroscopy, the behavior of the system especially related as being due to the substitution of Fe2+ for Li+ was observed in the Mossbauer spectrum. In the Na

  14. Interactions of simulated high level waste (HLW) calcine with alkali borosilicate glass. S. Morgan, R. J. Hand, N. C. Hyatt and W. E. Lee

    E-Print Network [OSTI]

    Sheffield, University of

    a full scale inactive trial (Magnox: oxide "blend" 25:75) was pre-mixed with alkali borosilicate glass such as molybdates, refractory oxides within the glass and anything which is immiscible in the melt may adversely affect the long term durability of the glass wasteform and also lead to enhanced melter corrosion [1

  15. Evaluation of laboratory test method for determining the potential alkali contribution from aggregate and the ASR safety of the Three-Gorges dam concrete

    SciTech Connect (OSTI)

    Lu Duyou [College of Materials Science and Engineering, Nanjing University of Technology, No. 5 Xin Mafan Road, Nanjing, Jiangsu, 210009 (China)]. E-mail: duyoulu@njut.edu.cn; Zhou, Xiaoling [College of Materials Science and Engineering, Nanjing University of Technology, No. 5 Xin Mafan Road, Nanjing, Jiangsu, 210009 (China); Xu Zhongzi [College of Materials Science and Engineering, Nanjing University of Technology, No. 5 Xin Mafan Road, Nanjing, Jiangsu, 210009 (China); Lan Xianghui [College of Materials Science and Engineering, Nanjing University of Technology, No. 5 Xin Mafan Road, Nanjing, Jiangsu, 210009 (China); Tang Mingshu [College of Materials Science and Engineering, Nanjing University of Technology, No. 5 Xin Mafan Road, Nanjing, Jiangsu, 210009 (China); Fournier, Benoit [ICON/CANMET, Natural Resources Canada, 405 Rocherster Street, Ottawa, ON, K1A 0G1 (Canada)

    2006-06-15T23:59:59.000Z

    The releasable alkali from granite, which was used in the Three-Gorges concrete dam project in China, and from gneiss and feldspar was estimated by extraction in distilled water and super-saturated Ca(OH){sub 2} solution. Results show that: i) the finer the particles and the higher the temperature, the greater and faster the release of alkali; ii) compared with extraction by distilled water, super-saturated Ca(OH){sub 2} solution had a stronger activation on feldspar than on granite and gneiss; iii) for the three rocks tested, thermal activation had the largest effect on gneiss and a lower and similar effect on granite and feldspar. For very fine particles, temperature had a similar effect on the release of alkali by all three rocks. Because the aggregate used in the Three-Gorges dam concrete is non-reactive and a low calcium fly ash was used in the concrete, ASR would not be an issue for the dam, despite the release of alkali from the aggregate into the concrete.

  16. Carbon dioxide in silica-undersaturated melt Part I: The effect of mixed alkalis (K and Na) on CO2 solubility and speciation.

    E-Print Network [OSTI]

    Boyer, Edmond

    . These low-silica melts can dissolve a large quantity of CO2 and are rich in alkalis. However, the way CO2 experimental results on the CO2 solubility and speciation in synthetic nephelinite in the NKCMAS system, equilibrated at high-pressure (50-300 MPa), high-temperature (1250C) with an excess C-O-H fluid phase

  17. Enhancement of specific heat capacity of high-temperature silica-nanofluids synthesized in alkali chloride salt eutectics for solar thermal-energy

    E-Print Network [OSTI]

    Banerjee, Debjyoti

    Enhancement of specific heat capacity of high-temperature silica-nanofluids synthesized in alkali nanoparticles at 1% mass concentration. The specific heat capacity of the nanofluid was enhanced by 14 of nanoparticles at min- ute concentrations are termed as ``nanofluids'' [1­3]. Nanoparticles are defined

  18. Alkali injection system with controlled CO.sub.2 /O.sub.2 ratios for combustion of coal

    DOE Patents [OSTI]

    Berry, Gregory F. (Naperville, IL)

    1988-01-01T23:59:59.000Z

    A high temperature combustion process for an organic fuel containing sulfur n which the nitrogen of air is replaced by carbon dioxide for combination with oxygen with the ratio of CO.sub.2 /O.sub.2 being controlled to generate combustion temperatures above 2000 K. for a gas-gas reaction with SO.sub.2 and an alkali metal compound to produce a sulfate and in which a portion of the carbon-dioxide rich gas is recycled for mixing with oxygen and/or for injection as a cooling gas upstream from heating exchangers to limit fouling of the exchangers, with the remaining carbon-dioxide rich gas being available as a source of CO.sub.2 for oil recovery and other purposes.

  19. Formation of multi-solitons and vortex bright solitons in Bose-condensed alkali-metal atoms

    E-Print Network [OSTI]

    Luca Salasnich

    2003-09-02T23:59:59.000Z

    Formation of multi-solitons and vortex bright solitons in Bose-condensed alkali-metal atoms is analyzed by using the nonpolynomial Schordinger equation. A train of bright solitons is obtained from an axially homogeneous Bose-Einstein condensate by a sudden change of the scattering length from repulsive to attractive. We derive an analytical expression for the number of bright solitons generated by using this mechanism. The formula generalizes a previous formula obtained with the 1D Gross-Pitaevskii equation. In the second part we consider vortex bright solitons, namely cigar-shaped bright solitons with a nonzero angular quantum number $k$ along the axial direction. By using a variational approach we determine the shape of vortex bright solitons, showing that the critical number of atoms for the collapse of the vortex soliton increases with a larger $k$. Finally we calculate monopole and quadrupole collective oscillations of these vortex bright solitons.

  20. Sensitivity of alkali halide scintillating calorimeters with particle identification to investigate the DAMA dark matter detection claim

    E-Print Network [OSTI]

    Patrick Nadeau; Michael Clark; P. C. F. Di Stefano; J. -C. Lanfranchi; S. Roth; M. von Sivers; Itay Yavin

    2015-04-07T23:59:59.000Z

    Scintillating calorimeters are cryogenic detectors combining a measurement of scintillation with one of phonons to provide particle identification. In view of developing alkali halide devices of this type able to check the DAMA/LIBRA claim for the observation of dark matter, we have simulated detector performances to determine their sensitivity by two methods with little model-dependence. We conclude that if performance of the phonon channel can be brought in line with those of other materials, an exposure of 10 kg-days would suffice to check the DAMA/LIBRA claim in standard astrophysical scenarios. Additionally, a fairly modest array of 5 kg with background rejection would be able to directly check the DAMA/LIBRA modulation result in 2 years.

  1. Effect of Acid, Alkali, and Steam Explosion Pretreatments on Characteristics of Bio-Oil Produced from Pinewood

    SciTech Connect (OSTI)

    Wang, Hui; Srinivasan, Radhakrishnan; Yu, Fei; Steele, Philip; Li, Qi; Mitchell, Brian

    2011-06-21T23:59:59.000Z

    Bio-oil produced from pinewood by fast pyrolysis has the potential to be a valuable substitute for fossil fuels. Pretreatment prior to the fast pyrolysis process has been shown to alter the structure and chemical composition of biomass. To determine the influence of biomass pretreatments on bio-oil produced during fast pyrolysis, we tested three pretreatment methods: dilute acid, dilute alkali, and steam explosion. Bio-oils were produced from untreated and pretreated pinewood feedstocks in an auger reactor at 450 C. The bio-oils�¢���� physical properties including pH, water content, acid value, density, viscosity, and heating value were measured. Chemical characteristics of the bio-oils were determined by gas chromatographymass spectrometry. Results showed that bio-oil yield and composition were influenced by biomass pretreatment. Of the three pretreatment methods, 1%H2SO4 pretreatment resulted in the highest bio-oil yield and best bio-oil quality.

  2. Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis

    DOE Patents [OSTI]

    Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

    1993-01-01T23:59:59.000Z

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  3. Studies on the production of ultra-clean coal by alkali-acid leaching of low-grade coals

    SciTech Connect (OSTI)

    Nabeel, A.; Khan, T.A.; Sharma, D.K. [Jamia Millia Islamia, New Delhi (India). Dept. of Chemistry

    2009-07-01T23:59:59.000Z

    The use of low-grade coal in thermal power stations is leading to environmental pollution due to the generation of large amounts of fly ash, bottom ash, and CO{sub 2} besides other pollutants. It is therefore important to clean the coal before using it in thermal power stations, steel plants, or cement industries etc. Physical beneficiation of coal results in only limited cleaning of coal. The increasing environmental pollution problems from the use of coal have led to the development of clean coal technologies. In fact, the clean use of coal requires the cleaning of coal to ultra low ash contents, keeping environmental norms and problems in view and the ever-growing need to increase the efficiency of coal-based power generation. Therefore this requires the adaptation of chemical cleaning techniques for cleaning the coal to obtain ultra clean coal having ultra low ash contents. Presently the reaction conditions for chemical demineralization of low-grade coal using 20% aq NaOH treatment followed by 10% H{sub 2}SO{sub 4} leaching under reflux conditions have been optimized. In order to reduce the concentration of alkali and acid used in this process of chemical demineralization of low-grade coals, stepwise, i.e., three step process of chemical demineralization of coal using 1% or 5% aq NaOH treatment followed by 1% or 5% H{sub 2}SO{sub 4} leaching has been developed, which has shown good results in demineralization of low-grade coals. In order to conserve energy, the alkali-acid leaching of coal was also carried out at room temperature, which gave good results.

  4. Reply to N. C. Higgins' comment on origin of alkali-feldspar granites: An example from the Poimena Granite, northeastern Tasmania, Australia

    SciTech Connect (OSTI)

    MacKenzie, D.E.; Sun, S.S.; Black, L.P. (Bureau of Mineral Resources, Canberra (Australia))

    1990-08-01T23:59:59.000Z

    This paper acts as a rebuttal to comments made by other scientists regarding the origin of the Poimena Granite as discussed in an earlier paper by these authors. The Lottah Granite and the enclosing Poimena Granite of northeastern Tasmania represent one of the best documented and most intensely Li-F-rich alkali-feldspar granite and its much more voluminous biotite granite host. The issue under debate is which of the two most generally supported models for the origin of Li-F-Sn granites-magmatic or metasomatic-hydrothermal-best explains the data obtained from the Lottah and Poimena Granites It is not the authors intent to imply that alkali-feldspar granites cannot be generated from granites similar to the Poimena Granite by fractional crystallization: the St. Austell Granite is an excellent example of such a relationship. Nor do the authors intend to imply that metasomatic and hydrothermal processes have not operated at all in the Lottah Granite. They seek rather to demonstrate that magmatic processes alone are capable of generating alkali-feldspar granites enriched in Sn, Li, Rb, F etc. and that such granites need not be genetically linked to spatially associated normal granites. Some of the arguments and data are subsequently presented in this paper.

  5. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: the effect of protective alumina coating on electrical stability in dual environment

    SciTech Connect (OSTI)

    Chou, Y. S.; Choi, Jung-Pyung; Stevenson, Jeffry W.

    2012-12-01T23:59:59.000Z

    An alkali-containing silicate glass was recently proposed as a potential sealant for solid oxide fuel cells (SOFC). The glass contains appreciable amount of alkalis and retains its glassy microstructure at elevated temperatures over time. It is more compliant as compared to conventional glass-ceramics sealants and could potentially heal cracks during thermal cycling. In previous papers the thermal cycle stability, thermal stability and chemical compatibility were reported with yttria-stabilized zirconia (YSZ) electrolyte and YSZ-coated ferritic stainless steel interconnect. In this paper, we report the electrical stability of the compliant glass with aluminized AISI441 interconnect material under DC load in dual environment at 700-800oC. Apparent electrical resistivity was measured with a 4-point method for the glass sealed between two aluminized AISI441 metal coupons as well as plain AISI441 substrates. The results showed good electrical stability with the aluminized AISI441 substrate, while unstable behavior was observed for un-coated substrates. In addition, interfacial microstructure was examined with scanning electron microscopy and correlated with the measured resistivity results. Overall, the alumina coating demonstrated good chemical stability with the alkali-containing silicate sealing glass under DC loading.

  6. EPR study of polarons in a conducting polymer with nondegenerate ground states: Alkali metal complexes of poly (p-phenylene) and phenylene oligomers

    SciTech Connect (OSTI)

    Kispert, L.D.; Joseph, J.; Miller, G.G.; Baughman, R.H.

    1984-08-15T23:59:59.000Z

    EPR measurements are used to characterize electronic states relevant for carrier transport in alkali metal doped poly(p-phenylene), PPP, fully deuterated poly(p-phenylene), DPPP, and phenylene oligomers. Observed spin concentrations per carbon are at least one decade higher than the Curie spin concentration for Na-doped polyacetylene. The number of these spins, which likely corresponds to polarons (mobile radical anions), is much less than the amount of alkali metal dopant, suggesting that much of the charge on the polymer chains is in bipolarons (spinless dianions). Relevant to the interaction between spins on the polymer chain and the metal cations, the observed g values are close to the free electron value and do not substantially vary with the donor dopant, temperature, or the molecular weight of the phenylene chain. Although the spin-orbit effect on g values is small, room temperature linewidth tends to increase with increasing atomic number of dopant: suggesting some interaction, albeit a smaller magnitude effect than for alkali-metal graphite complexes. The EPR linewidths are exchange narrowed and proton hyperfine broadening is significant. The latter explains the generally broader linewidths for doped PPP than for doped DPPP. The measured susceptibilities have a temperature dependence which suggests equilibrium between separated polaron defects and singlet and triplet spin states formed intermolecularly via polaron pairing. The interaction is antiferromagnetic and the binding energy between polarons is about 2.2 to 3.3 meV. An upper limit estimate of the Fermi-surface density of states for K-doped PPP (0.7 states/eV phenyl) is derived from an upper limit estimate of Pauli susceptibility.

  7. Dynamics of alkali ions-neutral molecules reactions: Radio frequency-guided beam experimental cross-sections and direct quasiclassical trajectory studies

    SciTech Connect (OSTI)

    Aguilar, J.; Andres, J. de; Lucas, J. M.; Alberti, M.; Huarte-Larranaga, F.; Bassi, D.; Aguilar, A. [Departament de Quimica Fisica, Institut de Quimica Teorica i Computacional (IQTCUB), Universitat de Barcelona, Marti i Franques, 1, 08028 Barcelona (Spain); Dipartimento di Fisica, Universita degli Studi di Trento, 38123 Povo-Trento (Italy); Departament de Quimica Fisica, Institut de Quimica Teorica i Computacional (IQTCUB), Universitat de Barcelona, Marti i Franques, 1, 08028 Barcelona (Spain)

    2012-11-27T23:59:59.000Z

    Different reactive processes taking place in collisions between alkali ions and neutral i-C{sub 3}H{sub 7}Cl molecules in the low (center of mass frame) energy range have been studied using an octopole radiofrequency guided-ion-beam apparatus developed in our laboratory. Cross-section energy dependences for all these reactions have been obtained in absolute units. Ab initio electronic structure calculations for those colliding systems evolving on the ground single potential surface have given relevant information on the main topological features of the surfaces. For some of the reactions a dynamic study by 'on the fly' trajectories has complemented the available experimental and electronic structure information.

  8. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 3, Appendix B: NO{sub x} and alkali vapor control strategies: Final report

    SciTech Connect (OSTI)

    Not Available

    1990-07-01T23:59:59.000Z

    CRS Sirrine (CRSS) is evaluating a novel IGCC process in which gases exiting the gasifier are burned in a gas turbine combustion system. The turbine exhaust gas is used to generate additional power in a conventional steam generator. This results in a significant increase in efficiency. However, the IGCC process requires development of novel approaches to control SO{sub 2} and NO{sub x} emissions and alkali vapors which can damage downstream turbine components. Ammonia is produced from the reaction of coal-bound nitrogen with steam in the reducing zone of any fixed bed coal gasifier. This ammonia can be partially oxidized to NO{sub x} when the product gas is oxidized in a gas turbine combustor. Alkali metals vaporize in the high-temperature combustion zone of the gasifier and laser condense on the surface of small char or ash particles or on cooled metal surfaces. It these alkali-coated materials reach the gas turbine combustor, the alkali will revaporize condense on turbine blades and cause rapid high temperature corrosion. Efficiency reduction will result. PSI Technology Company (PSIT) was contracted by CRSS to evaluate and recommend solutions for NO{sub x} emissions and for alkali metals deposition. Various methods for NO{sub x} emission control and the potential process and economic impacts were evaluated. This included estimates of process performance, heat and mass balances around the combustion and heat transfer units and a preliminary economic evaluation. The potential for alkali metal vaporization and condensation at various points in the system was also estimated. Several control processes and evaluated, including an order of magnitude cost for the control process.

  9. Generation of alkali-free and high-proton concentration layer in a soda lime glass using non-contact corona discharge

    SciTech Connect (OSTI)

    Ikeda, Hiroshi; Sakai, Daisuke; Nishii, Junji [Research Institute for Electronic Science, Hokkaido University, N20 W10, Kita-ku, Sapporo, Hokkaido 001-0020 (Japan)] [Research Institute for Electronic Science, Hokkaido University, N20 W10, Kita-ku, Sapporo, Hokkaido 001-0020 (Japan); Funatsu, Shiro [Production Technology Center, Asahi Glass Co., Ltd., 1-1 Suehiro-cyo, Tsurumiku, Yokohama, Kanagawa 230-0045 (Japan)] [Production Technology Center, Asahi Glass Co., Ltd., 1-1 Suehiro-cyo, Tsurumiku, Yokohama, Kanagawa 230-0045 (Japan); Yamamoto, Kiyoshi; Suzuki, Toshio [Research Center, Asahi Glass Co., Ltd., 1150 Hazawa-cho, Kanagawa-ku, Yokohama, Kanagawa 221-8755 (Japan)] [Research Center, Asahi Glass Co., Ltd., 1150 Hazawa-cho, Kanagawa-ku, Yokohama, Kanagawa 221-8755 (Japan); Harada, Kenji [Department of Computer Science, Kitami Institute of Technology, 165 Koen-cho, Kitami, Hokkaido 090-8507 (Japan)] [Department of Computer Science, Kitami Institute of Technology, 165 Koen-cho, Kitami, Hokkaido 090-8507 (Japan)

    2013-08-14T23:59:59.000Z

    Formation mechanisms of alkali-free and high-proton concentration surfaces were investigated for a soda lime glass using a corona discharge treatment under an atmospheric pressure. Protons produced by high DC voltage around an anode needle electrode were incorporated into a sodium ion site in the anode side glass. The sodium ion was swept away to the cathode side as a charge carrier. Then it was discharged. The precipitated sodium was transformed to a Na{sub 2}CO{sub 3} powder when the surface contacted with air. The sodium ion in the glass surface layer of the anode side was replaced completely by protons. The concentration of OH groups in the layer was balanced with the amount of excluded sodium ions. The substitution reaction of sodium ions with protons tends to be saturated according to a square root function of time. The alkali depletion layer formation rate was affected by the large difference in mobility between sodium ions and protons in the glass.

  10. Atomic Beam Merging and Suppression of Alkali Contaminants in Multi Body High Power Targets: Design and Test of Target and Ion Source Prototypes at ISOLDE

    E-Print Network [OSTI]

    Bouquerel, Elian J A; Lettry, J; Stora, T

    2009-01-01T23:59:59.000Z

    The next generation of high power ISOL-facilities will deliver intense and pure radioactive ion beams. Two key issues of developments mandatory for the forthcoming generation of ISOL target-ion source units are assessed and demonstrated in this thesis. The design and production of target and ion-source prototypes is described and dedicated measurements at ISOLDE-CERN of their radioisotope yields are analyzed. The purity of short lived or rare radioisotopes suffer from isobaric contaminants, notably alkalis which are highly volatile and easily ionized elements. Therefore, relying on their chemical nature, temperature controlled transfer lines were equipped with a tube of quartz that aimed at trapping these unwanted elements before they reached the ion source. The successful application yields high alkali-suppression factors for several elements (ie: 80, 82mRb, 126, 142Cs, 8Li, 46K, 25Na, 114In, 77Ga, 95, 96Sr) for quartz temperatures between 300ºC and 1100ºC. The enthalpies of adsorption on quartz were measu...

  11. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: the effect of protective YSZ coating on electrical stability in dual environment

    SciTech Connect (OSTI)

    Chou, Y. S.; Thomsen, Edwin C.; Choi, Jung-Pyung; Stevenson, Jeffry W.

    2012-03-15T23:59:59.000Z

    Recently, compliant sealing glass has been proposed as a potential candidate sealant for solid oxide fuel cell (SOFC) applications. In a previous paper, the thermal stability and chemical compatibility were reported for a compliant alkali-containing silicate glass sealed between anode supported YSZ bi-layer and YSZ-coated stainless steel interconnect. In this paper, we will report the electrical stability of the compliant glass under a DC load and dual environment at 700-800 degrees C. Apparent electrical resistivity was measured with a 4-point method for the glass sealed between two plain SS441 metal coupons or YSZ-coated aluminized substrates. The results showed instability with plain SS441 at 800 degrees C, but stable behavior of increasing resistivity with time was observed with the YSZ coated SS441. In addition, results of interfacial microstructure analysis with scanning electron microscopy will be correlated with the measured resistivity results. Overall, the YSZ coating demonstrated chemically stability with the alkali-containing compliant silicate sealing glass under electrical field and dual environments.

  12. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: Combined stability in isothermal ageing and thermal cycling with YSZ coated ferritic stainless steels

    SciTech Connect (OSTI)

    Chou, Y. S.; Thomsen, Edwin C.; Choi, Jung-Pyung; Stevenson, Jeffry W.

    2012-01-01T23:59:59.000Z

    An alkali-containing silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel cell (SOFC) applications. The glass contains about 17 mole% alkalis (K+Na) and has low glass transition and softening temperatures. It remains vitreous and compliant around 750-800oC after sealing without substantial crystallization, as contrary to conventional glass-ceramic sealants, which experience rapid crystallization after the sealing process. The glassy nature and low characteristic temperatures can reduce residual stresses and result in the potential for crack healing. In a previous study, the glass was found to have good thermal cycle stability and was chemically compatible with YSZ coating during short term testing. In the current study, the compliant glass was further evaluated in a more realistic way in that the sealed glass couples were first isothermally aged for 1000h followed by thermal cycling. High temperature leakage was measured. The chemical compatibility was also investigated with powder mixtures at 700 and 800oC to enhance potential interfacial reaction. In addition, interfacial microstructure was examined with scanning electron microscopy and evaluated with regard to the leakage and chemical compatibility results.

  13. Simultaneous high-temperature removal of alkali and particulates in a pressurized gasification system. Final technical progress report, April 1981-July 1983

    SciTech Connect (OSTI)

    Mulik, P.R.; Alvin, M.A.; Bachovchin, D.M.

    1983-09-01T23:59:59.000Z

    This program is directed at performing experimental and analytical investigations, deriving system designs, and estimating costs to ascertain the feasibility of using aluminosilicate-based getters for controlling alkali in pressurized gasification systems. Its overall objective is to develop a plan for evaluating a scaled-up version of the gettering process as a unit operation or as an integral part of a particulate removal device. This report describes work completed on the four technical program tasks: Thermodynamic projections; Getter Selection and Qualification; System Performance Projections; and Program Definition for Concept Scale-up during the 27-month contract performance period. Work completed on the thermodynamic projections includes a data base update, development of alkali phase diagrams, and system performance projections. Getter selection and qualification efforts involved over 70 kinetic studies in which a leading candidate getter - emathlite - was selected and characterized. System performance projections identified a packed-bed configuration containing relatively large getter pellets as the preferred contacting device for a full-scale unit. For emathlite, we concluded that full-scale unit bed heights of 2 m or less would be required if we assume annual replacement on the basis of bed saturation capacity. Concept scale-up work involved defining the hardware and test program requirements for further development of the emathlite packed-bed system. 56 references, 80 figures, 74 tables.

  14. Alkali ionization detector

    DOE Patents [OSTI]

    Hrizo, John (Monroeville, PA); Bauerle, James E. (Plum Borough, PA); Witkowski, Robert E. (West Mifflin, PA)

    1982-01-01T23:59:59.000Z

    A calibration filament containing a sodium-bearing compound is included in combination with the sensing filament and ion collector plate of a sodium ionization detector to permit periodic generation of sodium atoms for the in-situ calibration of the detector.

  15. Solar Wind Electrons and Langmuir Turbulence , D.E. Larson

    E-Print Network [OSTI]

    California at Berkeley, University of

    electron VDFs contain high-energy tail [9] which is typically described as thermal core plus superthermal are in dynamical equilibrium with quasi-thermal noise turbulence. Customary theories of superthermal electrons

  16. Compound and Elemental Analysis At Seven Mile Hole Area (Larson...

    Open Energy Info (EERE)

    Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Standard X-ray diffractometer (XRD) analyses were used in the...

  17. Sharing of Fire Fighting Resources Kate Larson and Alan Tsang

    E-Print Network [OSTI]

    Waterloo, University of

    -pronged problem; greater resource demand and (at best) current levels of resources to meet the demand (which have. The last (and current) state is an era of agencies lending resources as a standard practice, often to the limit of their capacity, and resource demand occasionally outstripping national availability

  18. Miscomputing Ratio: Social Cost of Selfish Computing Kate Larson

    E-Print Network [OSTI]

    Gordon, Geoffrey J.

    systems. The bulk of auction theory assumes that the bidders' valuations for items are given a priori their valuations. We intro- duce a way of measuring the negative impact of agents choosing computing strategies.) in multiagent systems. The bulk of auction theory assumes that the bidders' valuations for items are given

  19. LARSON--MATH 255CLASSROOM WORKSHEET 24 Sage Interacts

    E-Print Network [OSTI]

    Larson, Craig E.

    Cloud account. (a) Start Firefox or Chrome browser. (b) Go to http://cloud.sagemath.com (c) Click "Sign and infinity being white) while the ar- gument is represented by the hue (with red being positive real

  20. October 1991 Effect of Alkali Hydroxides on the Strength and Fatigue of Fused Silica Optical Fiber 2593 face features that are similar in shape but not size. The fiber

    E-Print Network [OSTI]

    Matthewson, M. John

    the strength. 11. Experimental Procedure The strength of optical fiber has been measured using the two#12;October 1991 Effect of Alkali Hydroxides on the Strength and Fatigue of Fused Silica Optical Fiber 2593 face features that are similar in shape but not size. The fiber fatigue is then controlled

  1. Dispersion coefficients for the interactions of the alkali and alkaline-earth ions and inert gas atoms with a graphene layer

    E-Print Network [OSTI]

    Kaur, Kiranpreet; Sahoo, B K

    2015-01-01T23:59:59.000Z

    Largely motivated by a number of applications, the van der Waals dispersion coefficients ($C_3$s) of the alkali ions (Li$^+$, Na$^+$, K$^+$ and Rb$^+$), the alkaline-earth ions (Ca$^+$, Sr$^+$, Ba$^+$ and Ra$^+$) and the inert gas atoms (He, Ne, Ar and Kr) with a graphene layer are determined precisely within the framework of Dirac model. For these calculations, we have evaluated the dynamic polarizabilities of the above atomic systems very accurately by evaluating the transition matrix elements employing relativistic many-body methods and using the experimental values of the excitation energies. The dispersion coefficients are, finally, given as functions of the separation distance of an atomic system from the graphene layer and the ambiance temperature during the interactions. For easy extraction of these coefficients, we give a logistic fit to the functional forms of the dispersion coefficients in terms of the separation distances at the room temperature.

  2. Garnet VRX sro | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating A PotentialJumpGermanFifeGEXAGarnet VRX sro Jump to: navigation, search Name:

  3. Influence of slag chemistry on the hydration of alkali-activated blast-furnace slag - Part I: Effect of MgO

    SciTech Connect (OSTI)

    Ben Haha, M.; Lothenbach, B., E-mail: barbara.lothenbach@empa.ch; Le Saout, G.; Winnefeld, F.

    2011-09-15T23:59:59.000Z

    The hydration and the microstructure of three alkali activated slags (AAS) with MgO contents between 8 and 13 wt.% are investigated. The slags were hydrated in the presence of two different alkaline activators, NaOH and Na{sub 2}SiO{sub 3}.5H{sub 2}O (WG). Higher MgO content of the slag resulted in a faster reaction and higher compressive strengths during the first days. The formation of C(- A)-S-H and of a hydrotalcite-like phase was observed in all samples by X-ray diffraction (XRD), thermal analysis (TGA) and scanning electron microscopy (SEM) techniques. Increasing the MgO content of the slag from 8 to 13% increased the amount of hydrotalcite and lowered the Al uptake by C-S-H resulting in 9% higher volume of the hydrates and a 50 to 80% increase of the compressive strength after 28 days and longer for WG activated slag pastes. For NaOH activated slags only a slight increase of the compressive strength was measured.

  4. Influence of slag chemistry on the hydration of alkali-activated blast-furnace slag - Part II: Effect of Al{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Ben Haha, M.; Lothenbach, B., E-mail: barbara.lothenbach@empa.ch; Le Saout, G.; Winnefeld, F.

    2012-01-15T23:59:59.000Z

    The hydration and microstructural evolution of three alkali activated slags (AAS) with Al{sub 2}O{sub 3} contents between 7 and 17% wt.% have been investigated. The slags were hydrated in the presence of two different alkaline activators, NaOH and Na{sub 2}SiO{sub 3}{center_dot}5H{sub 2}O. The formation of C(-A)-S-H and hydrotalcite was observed in all samples by X-ray diffraction, thermal analysis and scanning electron microscopy. Higher Al{sub 2}O{sub 3} content of the slag decreased the Mg/Al ratio of hydrotalcite, increased the Al incorporation in the C(-A)-S-H and led to the formation of straetlingite. Increasing Al{sub 2}O{sub 3} content of the slag slowed down the early hydration and a lower compressive strength during the first days was observed. At 28 days and longer, no significant effects of slag Al{sub 2}O{sub 3} content on the degree of hydration, the volume of the hydrates, the coarse porosity or on the compressive strengths were observed.

  5. Ab initio properties of the ground-state polar and paramagnetic europium-alkali-metal-atom and europium-alkaline-earth-metal-atom molecules

    E-Print Network [OSTI]

    Tomza, Micha?

    2014-01-01T23:59:59.000Z

    The properties of the electronic ground state of the polar and paramagnetic europium-$S$-state-atom molecules have been investigated. Ab initio techniques have been applied to compute the potential energy curves for the europium-alkali-metal-atom, Eu$X$ ($X$=Li, Na, K, Rb, Cs), europium-alkaline-earth-metal-atom, Eu$Y$ ($Y$=Be, Mg, Ca, Sr, Ba), and europium-ytterbium, EuYb, molecules in the Born-Oppenheimer approximation for the high-spin electronic ground state. The spin restricted open-shell coupled cluster method restricted to single, double, and noniterative triple excitations, RCCSD(T), was employed and the scalar relativistic effects within the small-core energy-consistent pseudopotentials were included. The permanent electric dipole moments and static electric dipole polarizabilities were computed. The leading long-range coefficients describing the dispersion interaction between atoms at large internuclear distances $C_6$ are also reported. The EuK, EuRb, and EuCs molecules are examples of species poss...

  6. Multi-phase glass-ceramics as a waste form for combined fission products: alkalis, alkaline earths, lanthanides, and transition metals

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Turo, Laura A.; Riley, Brian J.; Tang, Ming; Kossoy, Anna

    2012-04-01T23:59:59.000Z

    In this study, multi-phase silicate-based glass-ceramics were investigated as an alternate waste form for immobilizing non-fissionable products from used nuclear fuel. Currently, borosilicate glass is the waste form selected for immobilization of this waste stream, however, the low thermal stability and solubility of MoO{sub 3} in borosilicate glass translates into a maximum waste loading in the range of 15-20 mass%. Glass-ceramics provide the opportunity to target durable crystalline phases, e.g., powellite, oxyapatite, celsian, and pollucite, that will incorporate MoO{sub 3} as well as other waste components such as lanthanides, alkalis, and alkaline earths at levels 2X the solubility limits of a single-phase glass. In addition a glass-ceramic could provide higher thermal stability, depending upon the properties of the crystalline and amorphous phases. Glass-ceramics were successfully synthesized at waste loadings of 42, 45, and 50 mass% with the following glass additives: B{sub 2}O{sub 3}, Al{sub 2}O{sub 3}, CaO and SiO{sub 2} by slow cooling form from a glass melt. Glass-ceramics were characterized in terms of phase assemblage, morphology, and thermal stability. The targeted phases: powellite and oxyapatite were observed in all of the compositions along with a lanthanide borosilicate, and cerianite. Results of this initial investigation of glass-ceramics show promise as a potential waste form to replace single-phase borosilicate glass.

  7. Alkali deposits found in biomass boilers: The behavior of inorganic material in biomass-fired power boilers -- Field and laboratory experiences. Volume 2

    SciTech Connect (OSTI)

    Baxter, L.L. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Miles, T.R.; Miles, T.R. Jr. [Miles (Thomas R.), Portland, OR (United States); Jenkins, B.M. [California Univ., Davis, CA (United States); Dayton, D.C.; Milne, T.A. [National Renewable Energy Lab., Golden, CO (United States); Bryers, R.W. [Foster Wheeler Development Corp., Livingston, NJ (United States); Oden, L.L. [Bureau of Mines, Albany, OR (United States). Albany Research Center

    1996-03-01T23:59:59.000Z

    This report documents the major findings of the Alkali Deposits Investigation, a collaborative effort to understand the causes of unmanageable ash deposits in biomass-fired electric power boilers. Volume 1 of this report provide an overview of the project, with selected highlights. This volume provides more detail and discussion of the data and implications. This document includes six sections. The first, the introduction, provides the motivation, context, and focus for the investigation. The remaining sections discuss fuel properties, bench-scale combustion tests, a framework for considering ash deposition processes, pilot-scale tests of biomass fuels, and field tests in commercially operating biomass power generation stations. Detailed chemical analyses of eleven biomass fuels representing a broad cross-section of commercially available fuels reveal their properties that relate to ash deposition tendencies. The fuels fall into three broad categories: (1) straws and grasses (herbaceous materials); (2) pits, shells, hulls and other agricultural byproducts of a generally ligneous nature; and (3) woods and waste fuels of commercial interest. This report presents a systematic and reasonably detailed analysis of fuel property, operating condition, and boiler design issues that dictate ash deposit formation and property development. The span of investigations from bench-top experiments to commercial operation and observations including both practical illustrations and theoretical background provide a self-consistent and reasonably robust basis to understand the qualitative nature of ash deposit formation in biomass boilers. While there remain many quantitative details to be pursued, this project encapsulates essentially all of the conceptual aspects of the issue. It provides a basis for understanding and potentially resolving the technical and environmental issues associated with ash deposition during biomass combustion. 81 refs., 124 figs., 76 tabs.

  8. Electronic structure and bonding in garnet crystals Gd{sub 3}Sc{sub 2}Ga{sub 3}O{sub 12}, Gd{sub 3}Sc{sub 2}Al{sub 3}O{sub 12}, and Gd{sub 3}Ga{sub 3}O{sub 12} compared to Y{sub 3}Al{sub 3}O{sub 12}

    SciTech Connect (OSTI)

    Xu, Yong-Nian [Department of Physics, University of Missouri-Kansas City, Kansas City, Missouri 64110 (United States)] [Department of Physics, University of Missouri-Kansas City, Kansas City, Missouri 64110 (United States); Ching, W. Y. [Department of Physics, University of Missouri-Kansas City, Kansas City, Missouri 64110 (United States)] [Department of Physics, University of Missouri-Kansas City, Kansas City, Missouri 64110 (United States); Brickeen, B. K. [Allied Signal FM and T, Kansas City, Missouri 64141 (United States)] [Allied Signal FM and T, Kansas City, Missouri 64141 (United States)

    2000-01-15T23:59:59.000Z

    The electronic structure and bonding of Gd{sub 3}Sc{sub 2}Ga{sub 3}O{sub 12} (GSGG), Gd{sub 3}Sc{sub 2}Al{sub 3}O{sub 12} (GSAG), and Gd{sub 3}Ga{sub 5}O{sub 12} (GGG) crystals with a garnet structure are studied by means of first-principles local-density calculations. The results are compared with a similar calculation on yttrium aluminum garnet [Y{sub 3}Al{sub 5}O{sub 12} (YAG)]. The calculated equilibrium volumes of the three crystals are close to the measured volumes with a slight overestimation for GGG. GGG also has a smaller bulk modulus than the other three crystals. The calculated density of states and their atomic and orbital decompositions are presented and contrasted. All four crystals show very similar band structures and interatomic bonding. However, it is found that in GSGG and GSAG crystals, the Sc atom at the octahedral site shows a higher covalent character and an increased bond order in comparison to Ga or Al at the same site. This result may provide some insight into the significant difference in the radiation hardness of Cr{sup 3+}:Nd{sup 3+}:GSGG as compared to Nd{sup 3+}:YAG. (c) 2000 The American Physical Society.

  9. DIVALENT ION EXCHANGE WITH ALKALI

    E-Print Network [OSTI]

    Bunge, A.L.

    2011-01-01T23:59:59.000Z

    and Imporved Drilling Methods, Tulsa, OK, Aug. 22-24, 1979.on Enhanced Oil Recovery, Tulsa, OK, Apri120-23, 1980.on Improved Oil Recovery, Tulsa, OK, March 22-24, Radke, C.

  10. DIVALENT ION EXCHANGE WITH ALKALI

    E-Print Network [OSTI]

    Bunge, A.L.

    2011-01-01T23:59:59.000Z

    Injection for Enhanced Oil Recovery - A Status Report," SPEDOE Symposium on Enhanced Oil Recovery, Tulsa, OK, Apri120-ions is important enhanced oil recovery with chemical addi-

  11. Linda A. Cohen, At Large, Chair David M. Larson, Congressional District 3,

    E-Print Network [OSTI]

    Amin, S. Massoud

    Department; Professor, Animal Science and Equine Science DeMuth, David, Ph.D., Associate Professor, Physics and Software Engineering Dingmann, Brian, Ph.D., Associate Professor, Biology, Environmental Sciences, and Health Sciences Dingmann, Melissa, M.Ed., Director of Student Financial Aid Elf, Pamela, Ph.D., Associate

  12. Last name First name LARSON--MATH 255CLASSROOM WORKSHEET 24

    E-Print Network [OSTI]

    Larson, Craig E.

    Cloud account. (a) Start Firefox or Chrome browser. (b) Go to http://cloud.sagemath.com (c) Click "Sign and infinity being white) while the ar- gument is represented by the hue (with red being positive real

  13. Field Mapping At Seven Mile Hole Area (Larson, Et Al., 2009) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualPropertyd8c-a9ae-f8521cbb8489 NoEurope BVEnergy Information

  14. Eric D. Larson July 8, 1994 Summary Report on Visit to Cuba

    E-Print Network [OSTI]

    look at the Museumof the Revolution, a viewing of the 300-yeartradition of the daily 9 p.m. canonf utility branch), Lic. Julio Torres (MEPLAN), and Dr. Antonio Valdes (MCTE). This "task force" appeared

  15. Larson,Cheryl A * PS·6 From: Roberts,Timothy C - PGL-5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 - -/e),,sand CERNLandLargefor

  16. Isotopic Analysis At Seven Mile Hole Area (Larson, Et Al., 2009) | Open

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetecGtelInterias Solar Energy JumpIremNot2007) | Open EnergyOpenEnergyEnergy

  17. Isotopic Analysis At San Juan Volcanic Field Area (Larson & Jr, 1986) |

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOf Kilauea Volcano, Hawaii | OpenSuperiorEnergy Information GolesOpen

  18. U.S. Energy Secretary Steven Chu, U.S. Representatives Larson and Courtney

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO Overview OCHCOSystems Analysis Success| DepartmentEnergyFeed Reporting Period:Energyto

  19. Rock Sampling At San Juan Volcanic Field Area (Larson & Jr, 1986) | Open

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ |Rippey Jump to: navigation, searchRobbinsDensityOpenEnergy

  20. U.S. Energy Secretary Steven Chu, U.S. Representatives Larson and Courtney

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic|IndustrialCenterMarchC.DepartmentTexas to Call for Extensionto

  1. Compound and Elemental Analysis At Seven Mile Hole Area (Larson, Et Al.,

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia:PowerCER.png ElColumbia,2005) | Open(Thompson,2006) | Open2009) | Open

  2. Rock Sampling At Seven Mile Hole Area (Larson, Et Al., 2009) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt Ltd Jump to: navigation,MazeOhio:Ohio: Energy ResourcesRock Lab|

  3. aluminum garnet phosphor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 161 UV Curable Coatings in Aluminum Can Production Texas A&M University - TxSpace Summary: based...

  4. aluminum garnet powders: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nuclear applications. Two specific uses for which this powder is intended are Al2O3 pellets and Al2O 3 ? B4C composite pellets for use as thermal insulator or burnable neutron...

  5. GARNET : a Graphical Attack graph and Reachability Network Evaluation Tool

    E-Print Network [OSTI]

    Williams, Leevar (Leevar Christoff)

    2008-01-01T23:59:59.000Z

    Attack graphs are valuable tools in the assessment of network security, revealing potential attack paths an adversary could use to gain control of network assets. Creating an effective visualization for attack graphs is ...

  6. Real-time alkali monitoring system

    DOE Patents [OSTI]

    Goff, David R. (Christiansburg, VA); Romanosky, Robert R. (Prosperity, PA); Hensel, Peter (Morgantown, WV)

    1990-01-01T23:59:59.000Z

    A fiber optics based optical emission line monitoring system is provided in which selected spectral emission lines, such as the sodium emission line, may be detected in the presence of interfering background radiation. A combustion flame is fed by a diverted portion of a process stream and the common end of a bifurcated or quadfurcated fiber optic light guide is adapted to collect light from the flame. The light is guided through the branches of the fiber optic cable to bandpass filters, one of which is adapted to each of the branches of the fiber optic light guide. The bandpass filters are centered at wavelengths corresponding to the emission lines to be detected and two separate filters are required for each species being detected. The first filter has a bandwidth of about 3 nms and the second filter has a bandwidth of about 10 nms. Light detectors are located to view the light passing through the bandpass filters and amplifiers are connected to receive signals from the light detectors. The amplifier corresponding to the bandpass filter having the narrower bandwidth is preset to scale the signal by a factor equal to the ratio of the wide and narrow bandwidths of the bandpass filters. This scaling produces a scaled signal from which the difference between the scaled signal on the other signal can be calculated to produce a signal having an amplitude directly proportional to the concentration of the species of interest and independent of background radiation.

  7. Membrane Cells in Chlor Alkali Application

    E-Print Network [OSTI]

    Lesker, K.

    there is a stfluorinated Inembrallt~ dates 30 years age. Since then a lot of research has been performed to reach an economical. commercial chloralkali industry: 1962 Invention... of the per fluorinated ion exchange membrane 1968-72 Development of the membrane process 1 30% of NaOH IY81 first conversion of a diaphragm plant In a membrane chloralkali...

  8. New hypodiphosphates of the alkali metals: Synthesis, crystal structure and vibrational spectra of the hypodiphosphates(IV) M{sub 2}[(H{sub 2}P{sub 2}O{sub 6})(H{sub 4}P{sub 2}O{sub 6})] (M=Rb and Cs)

    SciTech Connect (OSTI)

    Wu, Peng [Institut fuer Anorganische und Analytische Chemie der TU Clausthal, Paul-Ernst-Strasse 4, D-38678 Clausthal-Zellerfeld (Germany)] [Institut fuer Anorganische und Analytische Chemie der TU Clausthal, Paul-Ernst-Strasse 4, D-38678 Clausthal-Zellerfeld (Germany); Wiegand, Thomas; Eckert, Hellmut [Institut fuer Physikalische Chemie and Graduate School of Chemistry, Westfaelische Wilhelms-Universitaet Muenster, Corrensstr. 28/30, D-48149 Muenster (Germany)] [Institut fuer Physikalische Chemie and Graduate School of Chemistry, Westfaelische Wilhelms-Universitaet Muenster, Corrensstr. 28/30, D-48149 Muenster (Germany); Gjikaj, Mimoza, E-mail: mimoza.gjikaj@tu-clausthal.de [Institut fuer Anorganische und Analytische Chemie der TU Clausthal, Paul-Ernst-Strasse 4, D-38678 Clausthal-Zellerfeld (Germany)] [Institut fuer Anorganische und Analytische Chemie der TU Clausthal, Paul-Ernst-Strasse 4, D-38678 Clausthal-Zellerfeld (Germany)

    2012-10-15T23:59:59.000Z

    The new hypodiphosphates(IV) Rb{sub 2}[(H{sub 2}P{sub 2}O{sub 6})(H{sub 4}P{sub 2}O{sub 6})] (1) and Cs{sub 2}[(H{sub 2}P{sub 2}O{sub 6})(H{sub 4}P{sub 2}O{sub 6})] (2) were synthesized by soft chemistry reactions from aqueous solutions of hypophosphoric acid and the corresponding heavy alkali-metal carbonates. Their crystal structures were determined by single crystal X-ray diffraction. Both compounds crystallize isotypic in the triclinic space group P-1 with one formula unit in the unit cell. The structures are built up by discrete (H{sub 2}P{sub 2}O{sub 6}){sup 2-} and (H{sub 4}P{sub 2}O{sub 6}) units in staggered conformation for the P{sub 2}O{sub 6} skeleton and the corresponding alkali-metal cations. In the (H{sub 2}P{sub 2}O{sub 6}){sup 2-} ion the hydrogen atoms are in a 'trans-trans' conformation. O{center_dot}H-O hydrogen bonds between the (H{sub 2}P{sub 2}O{sub 6}){sup 2-} and (H{sub 4}P{sub 2}O{sub 6}) groups consolidate the structures into a three-dimensional network. The FT-Raman and {sup 31}P and {sup 1}H and MAS NMR spectra of the title compounds have been recorded and interpreted, especially with respect to their assignment to the (H{sub 2}P{sub 2}O{sub 6}){sup 2-} and (H{sub 4}P{sub 2}O{sub 6}) groups. Thermogravimetric data of 2 have been interpreted in terms of a thermal decomposition model. - Graphical Abstract: The layered compounds Rb{sub 2}[(H{sub 2}P{sub 2}O{sub 6})(H{sub 4}P{sub 2}O{sub 6})] and Cs{sub 2}[(H{sub 2}P{sub 2}O{sub 6})(H{sub 4}P{sub 2}O{sub 6})] have been synthesized and investigated. Both crystallize isotypic. The structures are built up by discrete (H{sub 2}P{sub 2}O{sub 6}){sup 2-} and (H{sub 4}P{sub 2}O{sub 6}) units and the corresponding alkali-metal cations. Highlights: Black-Right-Pointing-Pointer Synthesis and single-crystal structure of new alkali hypodiphosphates. Black-Right-Pointing-Pointer Structures are characterized by [(H{sub 2}P{sub 2}O{sub 6})(H{sub 4}P{sub 2}O{sub 6})]{sup 2-} units and M{sup +} cations. Black-Right-Pointing-Pointer (H{sub 2}P{sub 2}O{sub 6}){sup 2-} and (H{sub 4}P{sub 2}O{sub 6}) units are linked by short hydrogen bonds. Black-Right-Pointing-Pointer Both compounds are characterized by {sup 31}P MAS-NMR spectra.

  9. Just-In-Time Context-Sensitive Questioning for Preventative Health Care Stephen S. Intille Kent Larson Chuck Kukla

    E-Print Network [OSTI]

    : a preventative monitoring system for congestive heart failure that uses "just-in-time," context applications. The problem The U.S. medical system and those in other countries face an impending crisis: how that "financing problems in the near term will be dwarfed by the crisis that could occur as the baby- boom

  10. U. S. FUSION ENERGY FUTURE John A. Schmidt, Dan Jassby, Scott Larson, Maria Pueyo, and Paul H. Rutherford

    E-Print Network [OSTI]

    into terms that are meaningful to the public. This report focuses on electrical production in the United draw the general conclusion that a large fraction of the electrical production must come from non fraction of the North American (and world) electricity production will need to be from non­carbon dioxide

  11. Fischer-Tropsch Fuels from Coal and Biomass Thomas G. Kreutz, Eric D. Larson, Guangjian Liu, Robert H. Williams

    E-Print Network [OSTI]

    ...................................................................................................................................8 2.2.2 Biomass as feedstock

  12. Thermodynamic modelling of Cr-bearing garnets with implications for diamond inclusions and peridotite xenoliths

    E-Print Network [OSTI]

    , Zürich, Switzerland e Geological Survey of Western Australia, Mineral House, 100 Plain Street, East Perth, WA 6004, Australia a b s t r a c ta r t i c l e i n f o Article history: Received 8 September 2008 using free energy minimization techniques. Here we present calculated phase relations in Cr-rich mantle

  13. Subducted oceanic crust as diamond hosts revealed by garnets of mantle xenoliths from Nyurbinskaya, Siberia

    E-Print Network [OSTI]

    Perfect, Ed

    , Siberia Amy J.V. Riches a, , Yang Liu a , James M.D. Day b , Zdislav V. Spetsius c , Lawrence A. Taylor of the lithospheric mantle (e.g., Griffin et al., 1999a; Griffin and O'Reilly, 2007). Several early studies suggested

  14. Trace element abundances in rutiles from eclogites and associated garnet mica schists

    E-Print Network [OSTI]

    Zack, Thomas

    23 July 2001 Abstract We present electron microprobe and laser ablation microprobe (LAM) data by both electron and laser ablation microprobe techniques yield similar results and confirm

  15. Garnet: A Middleware Archtecture for Distributing Data Streams in Wireless Sensor Networks

    E-Print Network [OSTI]

    St.; Ville, L.

    St. Ville,L. Dickman,P. Proceedings of the First International Workshop on Data Distribution for Real-Time Systems (DDRTS'03), held in conjunction with ICDCS'03 (23rd IEEE International Conference on Distributed Computer Systems) pp 235--240 IEEE

  16. Sm^Nd dating of spatially controlled domains of garnet single crystals: a new method of

    E-Print Network [OSTI]

    Ganguly, Jibamitra

    a peak metamorphic P^T condition of 8 þ 1 kbar, 820 þ 30C [Spear and Parrish, J. Petrol. 37 (1996) 733 of multiple geochronological systems [Spear and Parrish, J. Petrol. 37 (1996) 733^ 765], a cooling rate of V15

  17. Super stable garnet ceramics may be ideal for high-energy lithium batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our InstagramStructure of All-Polymer. .Energy8 Career DaySunShotSuper HeavySuper|

  18. Evaluation of Alkali Bromide Salts for Potential Pyrochemical Applications

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Steven D. Herrmann; Guy L. Fredrickson; Tedd E. Lister; Toni Y. Gutknecht

    2013-10-01T23:59:59.000Z

    Transient techniques were employed to study the electrochemical behavior, reduction mechanism and transport properties of REBr3 (RE - La, Nd and Gd) in pure LiBr, LiBr-KBr (eutectic) and LiBr-KBr-CsBr (eutectic) melts. Gd(III) showed a reversible single step soluble-insoluble exchange phenomenon in LiBr melt at 973K. Although La (III), Nd(III) and Gd(III) ions showed reversible behavior in eutectic LiBr-KBr melts, these ions showed a combination of temperature dependent reversible and pseudo-reversible behavior. While both La(III) and Gd(III) showed one step reduction, the reduction of Nd(III) was observed to be a two step process. La metal could be electrodeposited from the ternary electrolyte at a temperature of 673K. Various electrochemical measurements suggest that both binary and ternary bromide melts can potentially be used to electrodeposit high purity RE metals at comparatively lower operating temperatures.

  19. Surfactant-enhanced alkaline flooding with weak alkalis

    SciTech Connect (OSTI)

    French, T.R.; Josephson, C.B.

    1991-02-01T23:59:59.000Z

    The objective of Project BE4B in FY90 was to develop cost-effective and efficient chemical flooding formulations using surfactant-enhanced, lower pH (weak) alkaline chemical systems. Chemical systems were studied that mitigate the deleterious effects of divalent ions. The experiments were conducted with carbonate mixtures and carbonate/phosphate mixtures of pH 10.5, where most of the phosphate ions exist as the monohydrogen phosphate species. Orthophosphate did not further reduce the deleterious effect of divalent ions on interfacial tension behavior in carbonate solutions, where the deleterious effect of the divalent ions is already very low. When added to a carbonate mixture, orthophosphate did substantially reduce the adsorption of an atomic surfactant, which was an expected result; however, there was no correlation between the amount of reduction and the divalent ion levels. For acidic oils, a variety of surfactants are available commercially that have potential for use between pH 8.3 and pH 9.5. Several of these surfactants were tested with oil from Wilmington (CA) field and found to be suitable for use in that field. Two low-acid crude oils, with acid numbers of 0.01 and 0.27 mg KOH/g of oil, were studied. It was shown that surfactant-enhanced alkaline flooding does have merit for use with these low-acid crude oils. However, each low-acid oil tested was found to behave differently, and it was concluded that the applicability of the method must be experimentally determined for any given low-acid crude oil. 19 refs., 10 figs. 4 tabs.

  20. alkali feldspars ii: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16 at 4:00 p.m. (Climate Change and comprehensive) Exams I and II are planned as two Dibble, Theodore 300 by popular demand: Addiction II Computer Technologies and Information...

  1. alkali substitutes technical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Madhavapeddy, Thomas Pasquier, W Madhavapeddy, Thomas Pasquier, W. Kuan Hon, Christopher Millard Technical reports published by the University Haddadi, Hamed 117 MATHEMATICAL...

  2. Near-threshold photodetachment of heavy alkali-metal anions

    SciTech Connect (OSTI)

    Bahrim, C.; Thumm, U.; Khuskivadze, A.A.; Fabrikant, I.I. [Department of Physics, Kansas State University, Manhattan, Kansas 66506-2604 (United States); Department of Chemistry and Physics, Lamar University, Beaumont, Texas 77710-10046 (United States); Department of Physics, Kansas State University, Manhattan, Kansas 66506-2604 (United States); Department of Physics and Astronomy, University of Nebraska, Lincoln, Nebraska 68588-0111 (United States)

    2002-11-01T23:59:59.000Z

    We calculate near-threshold photodetachment cross sections for Rb{sup -}, Cs{sup -}, and Fr{sup -} using the Pauli equation method with a model potential describing the effective electron-atom interaction. Parameters of the model potential are fitted to reproduce ab initio scattering phase shifts obtained from Dirac R-matrix calculations. Special care is taken to formulate the boundary conditions near the atomic nucleus for solving the Pauli equation, based on the analytic solution of the Dirac equation for a Coulomb potential. We find a {sup 3}P{sub 1}{sup o} resonance contribution to the photodetachment cross section of Rb{sup -}, Cs{sup -}, and Fr{sup -} ions. Our calculated total photodetachment cross sections for Cs agree with experiments after tuning the resonance position by 2.4 meV. For Rb{sup -} and Fr{sup -} the resonance contribution is much smaller than for Cs. We therefore also provide angle-differential cross sections and asymmetry parameters which are much more sensitive to the resonant contribution than total cross sections.

  3. alkali metal cations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas-solid chromatographic model studied in Ja. In JSV appears a more general model of isotherm ( uid Seplveda, Mauricio 279 Visual Exploration of Uncertainty in...

  4. alkali metal cation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas-solid chromatographic model studied in Ja. In JSV appears a more general model of isotherm ( uid Seplveda, Mauricio 279 Visual Exploration of Uncertainty in...

  5. alkali carbonate reactions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    was constructed. (more) Petcoff, Darrell George 1970-01-01 17 Experimental Study of Carbon Sequestration Reactions Controlled Materials Science Websites Summary: -rich...

  6. The fate of alkali species in advanced coal conversion systems

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01T23:59:59.000Z

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950[degree]C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800[degree] to 950[degree]C, the concentrations of vapor phase sodium species (Na, Na[sub 2]O, NaCl, and Na[sub 2]SO[sub 4]) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820[degree]. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na[sub 2]SO[sub 4] increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 [mu]m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  7. alkali carbonate melts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 Glass Transition and Melting Behavior of Carbon Fiber Reinforced Thermoplastic Composite, Studied by Materials Science Websites Summary: Glass Transition and Melting...

  8. Mechanical Properties of Alkali Resistant Glass Fabric Composites

    E-Print Network [OSTI]

    Mobasher, Barzin

    of research experience in civil engineering materials. He is a member of American Concrete Institute University. She is an independent consultant for Stealth Management Group, LLC focusing on construction, planning and development of hotels and other commercial projects. Corina-Maria Aldea is senior materials

  9. Conversion of alkali metal sulfate to the carbonate

    DOE Patents [OSTI]

    Sheth, Atul C. (Woodridge, IL)

    1982-01-01T23:59:59.000Z

    A process for converting potassium sulfate to potassium carbonate in which a mixture of potassium sulfate and calcium oxide are reacted at a temperature in the range of between about 700.degree. C. and about 800.degree. C. with a gaseous mixture having a minor amount of hydrogen and/or carbon monoxide in a diluent with the calcium oxide being present in an amount not greater than about 20 percent by weight of the potassium sulfate to produce an aqueous mixture of potassium sulfide, potassium bisulfide, potassium hydroxide and calcium sulfide and a gaseous mixture of steam and hydrogen sulfide. The potassium and calcium salts are quenched to produce an aqueous slurry of soluble potassium salts and insoluble calcium salts and a gaseous mixture of steam and hydrogen sulfide. The insoluble calcium salts are then separated from the aqueous solution of soluble potassium salts. The calcium salts are dried to produce calcium sulfide, calcium bisulfide and steam, and then, the calcium sulfide and calcium bisulfide are converted to the oxide and recycled. The soluble potassium salts are carbonated to produce potassium carbonate which is concentrated and the precipitated crystals separated. The sulfur-containing compounds are further treated.

  10. Ultracold chemistry with alkali-metal-rare-earth molecules

    E-Print Network [OSTI]

    C. Makrides; J. Hazra; G. B. Pradhan; A. Petrov; B. K. Kendrick; T. González-Lezana; N. Balakrishnan; S. Kotochigova

    2014-10-28T23:59:59.000Z

    A first principles study of the dynamics of $^6$Li($^{2}$S) + $^6$Li$^{174}$Yb($^2\\Sigma^+$)$ \\to ^6$Li$_2(^1\\Sigma^+$) + $^{174}$Yb($^1$S) reaction is presented at cold and ultracold temperatures. The computations involve determination and analytic fitting of a three-dimensional potential energy surface for the Li$_2$Yb system and quantum dynamics calculations of varying complexities, ranging from exact quantum dynamics within the close-coupling scheme, to statistical quantum treatment, and universal models. It is demonstrated that the two simplified methods yield zero-temperature limiting reaction rate coefficients in reasonable agreement with the full close-coupling calculations. The effect of the three-body term in the interaction potential is explored by comparing quantum dynamics results from a pairwise potential that neglects the three-body term to that derived from the full interaction potential. Inclusion of the three-body term in the close-coupling calculations was found to reduce the limiting rate coefficients by a factor of two. The reaction exoergicity populates vibrational levels as high as $v=19$ of the $^6$Li$_2$ molecule in the limit of zero collision energy. Product vibrational distributions from the close-coupling calculations reveal sensitivity to inclusion of three-body forces in the interaction potential. Overall, the results indicate that a simplified model based on the long-range potential is able to yield reliable values of the total reaction rate coefficient in the ultracold limit but a more rigorous approach based on statistical quantum or quantum close-coupling methods is desirable when product rovibrational distribution is required.

  11. ORIGINAL ARTICLE Mitigation of autogenous shrinkage in alkali activated slag

    E-Print Network [OSTI]

    Bentz, Dale P.

    % of the global primary industrial energy supply [21, 36, 47]. A great deal of research has therefore gone and total shrinkage mea- surements used to determine the effects of internal curing on the overall shrinkage between 0.5 and 1 ton of CO2 into the atmosphere and consumes 4­5 GJ of energy [28, 50]. Due to the large

  12. Geneticprogrammingapproachforelectron-alkali-metalatomcollisions SalahYaseenEl-Bakry1

    E-Print Network [OSTI]

    Fernandez, Thomas

    , Egypt Email: elbakry_salah@Yahoo.com & Email: Amr_Radi@hotmail.com Abstract: New technique is presented and intermediate energy regions. The calculations have been performed in the framework of genetic programming ( GP to produce the total cross sections for each target atom. The incident energy and atomic number as well

  13. Ultracold chemistry with alkali-metal-rare-earth molecules

    E-Print Network [OSTI]

    Makrides, C; Pradhan, G B; Petrov, A; Kendrick, B K; González-Lezana, T; Balakrishnan, N; Kotochigova, S

    2014-01-01T23:59:59.000Z

    A first principles study of the dynamics of $^6$Li($^{2}$S) + $^6$Li$^{174}$Yb($^2\\Sigma^+$)$ \\to ^6$Li$_2(^1\\Sigma^+$) + $^{174}$Yb($^1$S) reaction is presented at cold and ultracold temperatures. The computations involve determination and analytic fitting of a three-dimensional potential energy surface for the Li$_2$Yb system and quantum dynamics calculations of varying complexities, ranging from exact quantum dynamics within the close-coupling scheme, to statistical quantum treatment, and universal models. It is demonstrated that the two simplified methods yield zero-temperature limiting reaction rate coefficients in reasonable agreement with the full close-coupling calculations. The effect of the three-body term in the interaction potential is explored by comparing quantum dynamics results from a pairwise potential that neglects the three-body term to that derived from the full interaction potential. Inclusion of the three-body term in the close-coupling calculations was found to reduce the limiting rate ...

  14. alkali burn traumatic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (TBI). The goal of the current study was to assess: Performance monitoring, traumatic brain injury, children, head injury, neuropsychology, pediatrics. Traumatic Logan, Gordon...

  15. alkali silica reactions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    method, the recently developed pin-drying method for producing high-refractive-index aerogels with high transparency was studied in detail. Optical qualities and large tile...

  16. alkali silica reaction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    method, the recently developed pin-drying method for producing high-refractive-index aerogels with high transparency was studied in detail. Optical qualities and large tile...

  17. alkali metal carbonates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of carbon nanofibers for use in polymer electrolyte membrane (PEM) fuel cells and metal-air batteries. The process involved electrospinning ... Kurpiewski, John Paul 2005-01-01...

  18. alkali hydroxide flux: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a range of renewable energy solutions including water splitting and rechargeable metal-air batteries. Here, we report the synthesis of ultrathin nickel iron layered double...

  19. PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS

    SciTech Connect (OSTI)

    Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

    2011-01-04T23:59:59.000Z

    The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions. The incorporation of 1 wt % Pu in the glass did not adversely impact glass viscosity (as assessed using Hf surrogate) or glass durability. Finally, evaluation of DWPF glass pour samples that had Pu concentrations below the 897 g/m{sup 3} limit showed that Pu concentrations in the glass pour stream were close to targeted compositions in the melter feed indicating that Pu neither volatilized from the melt nor stratified in the melter when processed in the DWPF melter.

  20. alkali metal salt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of each system, these reports can facilitate the evaluation of effective means of pollution control by those involved in metal finishing wastewater pollution control....

  1. alkali salt deposition: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

  2. alkali metal salts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of each system, these reports can facilitate the evaluation of effective means of pollution control by those involved in metal finishing wastewater pollution control....

  3. Characterization of Selective Binding of Alkali Cations with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    comprises a main chamber, detector, liquid microjet, skimmer, liquid nitrogen traps, turbo pumps, and a differential pump section (not shown here). A density functional theory...

  4. alkali metal vapors: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    deposition onto micro- and nanopowders14 and coating of nanoparticle films15 as well as aerogel coating of porous materials that exhibit ultrahigh-aspect ratios.12,13 To date,...

  5. alkali metal vapor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    deposition onto micro- and nanopowders14 and coating of nanoparticle films15 as well as aerogel coating of porous materials that exhibit ultrahigh-aspect ratios.12,13 To date,...

  6. alkali borate glasses: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with two laser beams. In this regime, the two-photon detuning from the Raman resonance controls Yavuz, Deniz First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17...

  7. alkali sodic soil: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MATERIALS Renewable Energy Websites Summary: -forming materials on brownfield, landfill or otherwise disturbed sites. Forest Research is able to give advice No...

  8. NOvel Refractory Materials for High Alkali, High Temperature Environments

    SciTech Connect (OSTI)

    Hemrick, J.G.; Griffin, R. (MINTEQ International, Inc.)

    2011-08-30T23:59:59.000Z

    Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, highalkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. A research team was formed to carry out the proposed work led by Oak Ridge National Laboratory (ORNL) and was comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The two goals of this project were to produce novel refractory compositions which will allow for improved energy efficiency and to develop new refractory application techniques which would improve the speed of installation. Also methods of hot installation were sought which would allow for hot repairs and on-line maintenance leading to reduced process downtimes and eliminating the need to cool and reheat process vessels.

  9. alkali vapor cells: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    THE POROUS SILICON PROCESS APPLYING CONVECTION for the first time to monocrystalline Si thin-film solar cells from the porous silicon (PSI) layer transfer for manufacturing high...

  10. Cold electron beams from cryo-cooled, alkali antimonide photocathodes

    E-Print Network [OSTI]

    Cultrera, Luca; Lee, Hyeri; Liu, Xianghong; Bazarov, Ivan

    2015-01-01T23:59:59.000Z

    In this letter we report on the generation of cold electron beams using a Cs3Sb photocathode grown by co-deposition of Sb and Cs. By cooling the photocathode to 90 K we demonstrate a significant reduction in the mean transverse energy validating the long standing speculation that the lattice temperature contribution limits the mean transverse energy or thermal emittance near the photoemission threshold, opening new frontiers in generating ultra-bright beams. At 90 K, we achieve a record low thermal emittance of 0.2 $\\mu$m (rms) per mm of laser spot diameter from an ultrafast (sub-picosecond) photocathode with quantum efficiency greater than $7\\times 10^{-5}$ using a visible laser wavelength of 690 nm.

  11. alkali sulfate aerosol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemical transport model and comparison with observations integrals over the aerosol size distribution when only the lower-order moments of the distribution are known...

  12. alkali chloride ternary: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    behavior and absorption spectra of the ternary system cobaltous chloride-water-acetonitrile Texas A&M University - TxSpace Summary: . HE PHASZ BEHAVIOR ARD ABSORPTION SPECTRA....

  13. Gabbs Alkali Flat Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualPropertyd8c-a9ae-f8521cbb8489InformationFrenchtown, NewG2 EnergyGISGSA JumpGTP

  14. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSS A-Zand Analysis Utilities (TAU) References

  15. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSS A-Zand Analysis Utilities (TAU)

  16. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSS A-Zand Analysis Utilities (TAU)Tuning of the

  17. alkali electrolysis process: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in "IRES and CO2 methanation 1. Power-to-SNG : architecture studied 2. High temperature steam electrolysis Paris-Sud XI, Universit de 2 Manufacturing of A micro probe using...

  18. alkalis hydroxides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    D . P E A K * A N D D . L . S P A R to animals and its mobility in the soil environment. It is known that iron(III) oxides and hydroxides are important sorbents for SeO4...

  19. alkali metal iodogallates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  20. alkali metal rhenium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  1. alkali metal picrates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  2. alkali metals sintez: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  3. alkali metal astatides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  4. anionic alkali mineral: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foreign investment: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum 444 Mineral-filled polypropylene: Improvement of scratch...

  5. alkali mineral complex: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Foreign investment: Coal 45 1 Oil 4.7 6 Industrial minerals: Cement 42 1 Fluorspar 55 1 Rare earths 85 1 Metals: Aluminum 303 Mineral-filled polypropylene: Improvement of scratch...

  6. alkali metals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  7. alkali metal hydroxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  8. alkali metal hydroxides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  9. alkali metal 2-aminonicotinates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  10. alkali metal iodides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  11. alkali metal perrhenate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  12. alkali metal diphenylamide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  13. alkali metal mole: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  14. alkali metal ln: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    complexes, Ln(DMF)6(-CN)2Fe(CN)48 (DMF N,N-dimethylformamide; Ln rare earths excluding Pm), were synthesized in dry DMF through the metathesis reactions...

  15. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWPSuccessAlamos

  16. Polyanionic Polymers with High Alkali-Ion Conductivity and Wide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeedingBiomassPPPOPetroleum38Polaron Behavior in1PollutionElectrochemical

  17. A Primitive Alkali Basaltic Stratovolcano And Associated Eruptive Centres,

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcat 1 WindtheEnergy InformationOf TheLtd APWR

  18. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C oCNMSStaffCeriumfor theChapter

  19. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C oCNMSStaffCeriumfor theChapterCharacterization of

  20. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C oCNMSStaffCeriumfor theChapterCharacterization

  1. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C oCNMSStaffCeriumfor

  2. Cubic Ionic Conductor Ceramics for Alkali Ion Batteries - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration would likeConstitution4 Department of WeeklyCrystalnamedCuban Missile

  3. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesisAppliancesTrending:ScheduleTsung-Dao

  4. Jiangxi Ganzhong Chlorine Caustic Company aka China Jiangxi Chlor Alkali

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunanInformationJamesManufacturing | Open Energy

  5. Jidong Chlorine and Alkali Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluatingGroup | OpenHunanInformationJamesManufacturingJiaxingJidong Chlorine and

  6. Gabbs Alkali Flat Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdf Jump1946865°, -86.0529604°Wisconsin:FyreStormGLOBAL

  7. Diode-Pumped Alkali Laser: A New Combination

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField Campaign: Potential ApplicationYu,EnergyDimitri Kusnezov

  8. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Trace elements and alkaliTrace elements and alkali

    E-Print Network [OSTI]

    Zevenhoven, Ron

    elements in fossil - and waste-derived fuelsTrace elements in fossil - and waste-derived fuels Coal Peat Heavy fuel oil Pet coke MSW RDF Wood Waste wood Waste paper Scrap tyres Sew. sludge Hg 0.02-3 ~0.07 .153 Behaviour of trace elements in coalBehaviour of trace elements in coal combustion flue gasescombustion flue

  9. Ogden, Williams and Larson, Toward a Hydrogen-Based Transportation System, final draft, 8 May 2001 Toward a Hydrogen-Based Transportation System

    E-Print Network [OSTI]

    ..................................................................................6 Hydrogen from Fossil Fuels with Geological Sequestration of Carbon Dioxide

  10. Molecular Cell, Volume 23 Pulling on the Nascent RNA during

    E-Print Network [OSTI]

    Block, Steven

    of Elongation or Ubiquitous Pausing Ravindra V. Dalal, Matthew H. Larson, Keir C. Neuman, Jeff Gelles, Robert

  11. Quarterly Biomass Program/Clean Cities State Web Conference:...

    Broader source: Energy.gov (indexed) [DOE]

    larson.pdf More Documents & Publications Renewable Fuel Standards Program Update EISA 2007: Focus on Renewable Fuels Standard Program...

  12. Electrically and magnetically tunable phase shifters based on a barium strontium titanate-yttrium iron garnet layered structure

    E-Print Network [OSTI]

    to rapidly change the dielectric constant of a ferroelectric material under the application of a dc electric, by incorporating a ferrite material into a device, one gains the ability to change both the dielectric constant, a phase shifter will have changing characteris- tic impedance as it changes its phase. In this work, we em

  13. Modal mineralogy and geochemistry of Kaapvaal peridotites; the origin of garnet and diopside and implications for craton stability

    E-Print Network [OSTI]

    Simon, Nina

    and produces modal mineral variations that are a function of both the amount of melt extracted from the rock with observations from mineral chemistry #12;that bear on these hypotheses. Many other models have been produced extraction of large degrees of melt extraction. This model involves single or multiple-stage melt depletion

  14. Comment on 'A planar refractive x-ray lens made of nanocrystalline diamond'[J. Appl. Phys. 108, 123107 (2010)

    SciTech Connect (OSTI)

    Kroon, R. E. [Department of Physics (IB51), University of the Free State, Box 339, Bloemfontein (South Africa)] [Department of Physics (IB51), University of the Free State, Box 339, Bloemfontein (South Africa)

    2013-05-28T23:59:59.000Z

    The material LuAG (lutetium aluminium garnet) has been confused with LAG (lanthanum aluminium garnet). In general, aluminium garnet phases only occur for the smaller trivalent metal cations and LAG is not known to have been synthesized.

  15. alkali-silica reaction observed: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observations for Comparison of Uranium Fission with Low Energy Nuclear Reactions LENR CiteSeer Summary: The discovery of nuclear fission by Hahn and Stramann was based on...

  16. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOE Patents [OSTI]

    Erickson, Donald C. (Annapolis)

    1985-06-04T23:59:59.000Z

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power.

  17. Synthesis of higher alcohols on copper catalysts supported on alkali-promoted basic oxides

    E-Print Network [OSTI]

    Iglesia, Enrique

    -butyl-ether (MTBE) after isobutanol dehydration to form isobutene. An equimolar ratio of methanol to isobutanol would be preferred for MTBE synthesis. Methanol and higher alcohols can also be used for direct blending

  18. Corrosion resistance of stainless steels during thermal cycling in alkali nitrate molten salts.

    SciTech Connect (OSTI)

    Bradshaw, Robert W.; Goods, Steven Howard

    2001-09-01T23:59:59.000Z

    The corrosion behavior of three austenitic stainless steels was evaluated during thermal cycling in molten salt mixtures consisting of NaNO{sub 3} and KNO{sub 3}. Corrosion tests were conducted with Types 316, 316L and 304 stainless steels for more than 4000 hours and 500 thermal cycles at a maximum temperature of 565 C. Corrosion rates were determined by chemically descaling coupons. Metal losses ranged from 5 to 16 microns and thermal cycling resulted in moderately higher corrosion rates compared to isothermal conditions. Type 316 SS was somewhat more corrosion resistant than Type 304 SS in these tests. The effect of carbon content on corrosion resistance was small, as 316L SS corroded only slightly slower than 316 SS. The corrosion rates increased as the dissolved chloride content of the molten salt mixtures increased. Chloride concentrations approximating 1 wt.%, coupled with thermal cycling, resulted in linear weight loss kinetics, rather than parabolic kinetics, which described corrosion rates for all other conditions. Optical microscopy and electron microprobe analysis revealed that the corrosion products consisted of iron-chromium spinel, magnetite, and sodium ferrite, organized as separate layers. Microanalysis of the elemental composition of the corrosion products further demonstrated that the chromium content of the iron-chromium spinel layer was relatively high for conditions in which parabolic kinetics were observed. However, linear kinetics were observed when the spinel layer contained relatively little chromium.

  19. NEGATIVE-HYDROGEN-ION PRODUCTION BY BACKSCATTERING FROM ALKALI-METAL TARGETS

    E-Print Network [OSTI]

    Schneider, P.J.

    2010-01-01T23:59:59.000Z

    tion of Negative Hydrogen ions and Beams, Brookhaven 1977,of the Workshop on Hydrogen Recycling, Dublin, CA, October"18, 1979 NEGATIVE-HYDROGEN-ION PRODUCTION BY BACKSCATTERING

  20. Ion Segregation and Deliquescence of Alkali Halide Nanocrystals on SiO2

    E-Print Network [OSTI]

    Arima, Kenta

    2010-01-01T23:59:59.000Z

    it can provide surface topography and surface potentialz displacement represents a surface topography modulated byheight represents surface topography modulated by the local

  1. E-Print Network 3.0 - alkali metal oxides Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    , sodium carbide, turpentine, finely divided metals Calcium water, carbon dioxide, carbon tetrachloride... , and chlorinated hydrocarbons Carbon, activated calcium...

  2. alkali-doped helium nanodroplets: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cold Compressor Units (CCU). This unit is based on a cryogenic axial-centrifugal compressor, running on ceramic ball bearings and driven by a variable-frequency electrical...

  3. alkali-silica reaction gel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  4. Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy

    E-Print Network [OSTI]

    Cohen, Ronald C.

    spectra measured for aqueous formate and acetate solutions containing lithium, sodium, and potassium 290 eV clearly indicate a preferential interaction of sodium versus potassium, which was less apparent interactions aqueous systems The discovery of the selective interactions between simple ions and proteins dates

  5. An investigation of the transfer of alkali metal chlorides from dimethyl sulfoxide to water

    E-Print Network [OSTI]

    Williams, Roger

    1966-01-01T23:59:59.000Z

    works well with sodium metal also. In some preliminary investigations lithium amalgam was prepared electrolytically by depositing lithium at a stirred mercury cathode from a concentrated solution of lithium hydroxide. Lithium amalgams could... -7 -1 18. 3-18. 4o C Redistilled Dimethyl sulfoxide Wate r -7 -1 -1 9. 4x 10 ohm cm -8 -1 -1 2 5x 10 ohm cm 17, 8-17. 9 C 13 Salutes. Salts used in the preparation of solutions were lithium, sodium, potassium, and cesium chlorrdes. Each...

  6. Influence of bath composition on aluminum corrosion in alkali carbonate melt

    SciTech Connect (OSTI)

    Sannikov, V.I.; Kudyakov, V.Y.; Nikitina, E.V.; Pankratov, A.A. (Russian Academy of Sciences, Ekaterinburg (Russian Federation). Inst. of High-Temperature Electrochemistry of Ural)

    1994-08-01T23:59:59.000Z

    The influence of sodium (Na) additions with different chemical natures (sodium peroxide [Na[sub 2]O[sub 2

  7. alkali-resistant denox catalysts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    non-food biomass (lignocellulose Chemistry (C-IIAC), Ruilian Wu and Louis "Pete" Silks of Bioenergy and Environmental Science (B-8) have 23 Multifunctional Catalysts for Singlewall...

  8. The H2O solubility of alkali basaltic melts: an experimental study Priscille Lesne1, 2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    implications for the functioning of the pelagic ecosystem. For example, due to their direct uptake of dissolved

  9. Influence of zirconium and niobium on cathodic deposition of uranium dioxide from alkali chloride melts

    SciTech Connect (OSTI)

    Komarov, V.E.; Borodina, N.P.; Martem`yanova, Z.S. [Institute of High-Temperature Electrochemistry, Ekaterinburg (Russian Federation)

    1995-07-01T23:59:59.000Z

    Electrocrystallization of uranium dioxide from molten chloride electrolytes in the presence of zirconium(IV) and niobium(V) was studied by voltammetry. Zirconium(IV) was found to react with uranium dioxide according to exchange mechanism to form (1 - x)UO{sub 2}{center_dot}xZrO{sub 2} solid solutions. Niobium(IV), a product of cathodic reduction of niobium(V), enters into the exchange reaction with uranium dioxide to yield (1 - y)UO{sub 2{center_dot}y}NbO{sub 2} solid solutions. In the case of simultaneous presence of Nb(V) and Zr(IV) in electrolyte, ternary (1 - x - y)UO{sub 2 {center_dot}x}ZrO{sub 2{center_dot}y}NbO{sub 2} solid solutions are obtained at the cathode surface. Nucleation of the solid solutions phase was shown to occurs at the most active sites of the crystalline precipitate of uranium dioxide.

  10. Method and system for producing lower alcohols. [Heteropolyatomic lead salt coated with alkali metal formate

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.; Heiberger, J.J.

    1983-09-26T23:59:59.000Z

    It is an object of the present invention to provide an improved catalyst for the reaction of carbon monoxide with water to produce methanol and other lower alcohols. It is a further object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol in which ethanol is also directly produced. It is another object to provide a process for the production of mixtures of methanol with ethanol and propanol from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. It is likewise an object to provide a system for the catalytic production of lower alcohols from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. In accordance with the present invention, a catalyst is provided for the reaction of carbon monoxide and water to produce lower alcohols. The catalyst includes a lead heteropolyatomic salt in mixture with a metal formate or a precursor to a metal formate.

  11. The fate of alkali species in advanced coal conversion systems. Final report

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01T23:59:59.000Z

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950{degree}C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800{degree} to 950{degree}C, the concentrations of vapor phase sodium species (Na, Na{sub 2}O, NaCl, and Na{sub 2}SO{sub 4}) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820{degree}. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na{sub 2}SO{sub 4} increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 {mu}m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  12. E-Print Network 3.0 - alkali-activated fly ash Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering ; Materials Science 12 By-Products Utilization Summary: CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique... of...

  13. Inorganic Corrosion-Inhibitive Pigments for High-Temperature Alkali-activated Well Casing Foam Cement

    SciTech Connect (OSTI)

    Sugama, T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Pyatina, T. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-11-14T23:59:59.000Z

    This study evaluates inorganic pigments for improving carbon steel (CS) brine-corrosion protection by the sodium metasilicate-activated calcium aluminate cement/Fly Ash blend at 300°C. Calcium borosilicate (CBS) and zinc phosphate, significantly improved CS corrosion-protection by decreasing cement’s permeability for corrosive ions and inhibiting anodic corrosion. An amorphous Na2O-Al2O3-SiO2-H2O phase tightly attached to CS surface formed at 300oC in CBS-modified cement pore solution. The corrosion rate of the CS covered with this phase was nearly 4-fold lower than in the case of nonmodified cement pore solution where the major phase formed on the surface of CS was crystalline analcime.

  14. Inorganic Corrosion-Inhibitive Pigments for High-Temperature Alkali-activated Well Casing Foam Cement

    SciTech Connect (OSTI)

    Sugama, T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Pyatina, T. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-11-01T23:59:59.000Z

    This study evaluates inorganic pigments for improving carbon steel (CS) brine-corrosion protection by the sodium metasilicate-activated calcium aluminate cement/Fly Ash blend at 300°C. Calcium borosilicate (CBS) and zinc phosphate, significantly improved CS corrosion-protection by decreasing cement’s permeability for corrosive ions and inhibiting anodic corrosion. An amorphous Na2O-Al2O3-SiO2-H2O phase tightly attached to CS surface formed at 300oC in CBS-modified cement pore solution. The corrosion rate of the CS covered with this phase was nearly 4-fold lower than in the case of nonmodified cement pore solution where the major phase formed on the surface of CS was crystalline analcime.

  15. alkali-activated complex binders: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Logspace using only poly-logarithmically many be solved by a probabilistic log-space Turing Machines. There are many ways to view a probabilistic log-space to have a space...

  16. A grid-level alkali liquid metal battery recycling process : design, implementation, and characterization

    E-Print Network [OSTI]

    Thomas, Dale Arlington, III

    2014-01-01T23:59:59.000Z

    The application of liquid metal batteries for large scale grid-level energy storage is being enabled through the development of research conducted at the Massachusetts Institute of Technology (MIT) in 2006. A recycling ...

  17. alkali-transition metal borohydrides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or...

  18. Alkali metal ions through glass: a possible radioactive waste management application

    E-Print Network [OSTI]

    Jones, Robert Allan

    1996-01-01T23:59:59.000Z

    Early studies show that some types of glass can become conductors of electricity at higher temperatures. The nature of the conductance was shown to be ionic. The studies also showed that, due to structural properties within the glass, the ionic...

  19. Alkali-metal plasmons, pseudopotentials, and optical sum rules Paola Alippi

    E-Print Network [OSTI]

    calculations of the optical properties of very small lithium clusters, also based on nonlocal pseudopotentials for a closer look at some nontrivial properties ofnon- local electron-ion interactions which are not peculiar and theoretical results on the optical absorption of lithium clusters, we reexamine some effects of the angular

  20. Hydrogenation of Carbon Dioxide by Water: Alkali-Promoted Synthesis of Formate

    SciTech Connect (OSTI)

    Hrbek, J.; Hoffmann, F.M.; Yang, Y.; Paul, J.; White, M.G.

    2010-07-15T23:59:59.000Z

    Conversion of carbon dioxide utilizing protons from water decomposition is likely to provide a sustainable source of fuels and chemicals in the future. We present here a time-evolved infrared reflection absorption spectroscopy (IRAS) and temperature-programmed desorption (TPD) study of the reaction of CO{sub 2} + H{sub 2}O in thin potassium layers. Reaction at temperatures below 200 K results in the hydrogenation of carbon dioxide to potassium formate. Thermal stability of the formate, together with its sequential transformation to oxalate and to carbonate, is monitored and discussed. The data of this model study suggest a dual promoter mechanism of the potassium: the activation of CO{sub 2} and the dissociation of water. Reaction at temperatures above 200 K, in contrast, is characterized by the absence of formate and the direct reaction of CO{sub 2} to oxalate, due to a drastic reduction of the sticking coefficient of water at higher temperatures.

  1. A comparison of the products of the hydrolysis of cottonseed meats with acid and alkali

    E-Print Network [OSTI]

    Schoch, Henry Bernard

    1939-01-01T23:59:59.000Z

    ??eisa yorsawgesato eollltieao ill tho aitregoa lib?rat?4 ie thea aeesero4 eager ?taosyherie yreseure ea4 to?Der?tare. The yolia-Desi? at?re K)olgehl eu ueeg in detoraiaiag tho total aitregoa of the bess?i Oelouletioa ef the hisii4iae aitrogea eas yes?ibis b7...

  2. Alkali salt ash formation during black liquor combustion at kraft recovery boilers

    SciTech Connect (OSTI)

    Mikkanen, P. Kauppinen, E.I.; Pyykoenen, J.; Jokiniemi, J.K. [VTT (Finland); Maekinen, M. [Finnish Meterological Inst., Helsinki (Finland)

    1996-12-31T23:59:59.000Z

    Recovery boiler is an essential part of paper pulping process, where waste sludge called black liquor is burned for chemical recovery and energy production. This study was carried out at an operating industrial recovery boiler in Finland. Measurement of aerosol particles was carried out at bullnose level of furnace, at boiler exit, and at outlet of electrostatic precipitator (ESP). Aerosol mass size distributions in size range 0.02--50 {micro}m were measured with Berner type low pressure impactor (BLPI) operated with precyclone. BLPI samples were further analyzed with ion chromatography for water soluble Na, K, SO{sub 4}, and Cl. Particle morphology was studied with scanning electron microscopy (SEM). Phase composition of crystalline salts was measured with X-ray diffraction (XRD). Particles larger than 1 {micro}m were analyzed with computer controlled scanning electron microscopy (CCSEM) to derive particle composition classes. At ESP inlet mass size distribution was bimodal with a major mode at about 1.2 {micro}m and a minor mode at about 5 {micro}m (aerodynamic diameter). At ESP outlet the mass size distribution showed only one peak at about 1.2 {micro}m. Both submicron and supermicron particles were agglomerates formed from 0.3 to 0.5 {micro}m spherical primary particles. XRD analyses indicated that particles were crystalline with two phases of Na{sub 2}SO{sub 4} (thenardite and sodium sulphate) and K{sub 3}Na(SO{sub 4}){sub 2}. CCSEM results of individual particles larger than 1 {micro}m showed that 79 to 88 volume percent of particles contained mainly Na and S, 7 to 10 volume percent Na, K, and S with minor amount of particles containing Na, S, and Ca.

  3. Low temperature pyrolysis of black liquor and polymerization of products in alkali aqueous medium

    SciTech Connect (OSTI)

    Demirbas, A. (Dept. of Chemical Education, Karadeniz Teknik Univ., Trabzon (TR)); Ucan, H. (Dept. of Chemistry, Selcuk Univ., Konya (TR))

    1991-01-01T23:59:59.000Z

    Atmospheric pressure pyrolysis for the production of liquids and gases from black liquor and its calcium salts and acidic precipitate have been carried out in a little stainless steel tube. Yields, sum of liquid and gas products, from black liquor and its calcium salts and acidic precipitate were 44.7%, 52.0% and 59.1% of dry basis respectively. The precipitates obtained from black liquor by acidifying with hydrochloric acid and passing carbon dioxide have been polymerized in aqueous acetone containing formaldehyde and ammonia, and converted a polymeric resin.

  4. The Effects of Using Alkali-Silica Reaction Affected Recycled Concrete Aggregate in Hot Mix Asphalt

    E-Print Network [OSTI]

    Geiger, Brian James

    2011-10-21T23:59:59.000Z

    mix asphalt (HMA) were investigated in this study. Dilatometer and modified beam tests were performed to determine the possibility of new ASR occurring in reactive aggregates within the HMA or re-expansion of existing gel. The Lottman test... (XRD) was used to check for the potential presence of gel in the filler fraction of the ASR-RCAs. Micro-deval and freeze-thaw tests were evaluated for their potential to indicate the presence of excess micro-cracks or ASR gel. Expansion testing...

  5. alkali heavy-ion reaction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dynamics predicts substantial modifications of the kaon properties in a dense nuclear environment. The status of the theoretical predictions as well as experimental evidences...

  6. Hybrid Optical Pumping of Optically Dense Alkali-Metal Vapor without Quenching Gas

    SciTech Connect (OSTI)

    Romalis, M. V. [Department of Physics, Princeton University, Princeton, New Jersey 08544 (United States)

    2010-12-10T23:59:59.000Z

    Optical pumping of an optically thick atomic vapor typically requires a quenching buffer gas, such as N{sub 2}, to prevent radiation trapping of unpolarized photons which would depolarize the atoms. We show that optical pumping of a trace contamination of Rb present in K metal results in a 4.5 times higher polarization of K than direct optical pumping of K in the absence of N{sub 2}. Such spin-exchange polarization transfer from optically thin species is useful in a variety of areas, including spin-polarized nuclear scattering targets and electron beams, quantum-nondemolition spin measurements, and ultrasensitive magnetometry.

  7. Ab initio prediction of thermodynamics in alkali metal-air batteries

    E-Print Network [OSTI]

    Kang, ShinYoung

    2014-01-01T23:59:59.000Z

    Electric vehicles ("EVs") require high-energy-density batteries with reliable cyclability and rate capability. However, the current state-of-the-art Li-ion batteries only exhibit energy densities near ~150 Wh/kg, limiting ...

  8. alkali-activated slag concrete: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on the compressive, flexural strength, and split tensile test of polymer modified steel fibre reinforced concrete (PSFC) concrete was examined. Including SBR latex at a certain %...

  9. Green's Function Approach to B.E. Condensation in the Alkali Atoms

    E-Print Network [OSTI]

    Mahendra Sinha Roy

    2002-10-08T23:59:59.000Z

    A new scheme has been proposed to solve the B.E. condenstates in terms of Green's function approach. It has been shown that the radial wave function of two interacting atoms, moving in a common harmonic oscillator potential modified by an effective interaction,satifies an integral equation whose kernel is separable.The solution of the integral equation can be written in terms of the harmonic oscillator wave functions. The ground state wave function of the system can be written in terms of these solutions. PACS numbers:03.75Fi,02.60Cb,32.80Pj

  10. alkali-promoted cobalt oxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Properties 827 2 Kovacs, Julie 106 Ferromagnetism in cobalt-implanted ZnO D. P. Norton,a) Materials Science Websites Summary: November 2003 The magnetic and structural...

  11. alkali-metal vapor-filled ceramic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    j and the magnetic field H in Bi2Sr2CaCu2O8 x ceramics. We provided in high-Tc superconduct- ing granular ceramics remain an intriguing subject of inten- sive investigations...

  12. alkali oxide-tantalum niobium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AT SLAC* CiteSeer Summary: summarq The program of measurements at SLAC on superconduct-. I ing niobium cavities is described. Results for TE and TM;r. mode X-band...

  13. ALKALI – CATALYSED PRODUCTION OF BIODIESEL FUEL FROM NIGERIAN CITRUS SEEDS OIL

    E-Print Network [OSTI]

    unknown authors

    The potential of oil extracted from the seeds of three different Nigerian citrus fruits for biodiesel production was investigated. Fatty acid alkyl esters were produced from orange seed oil, grape seed oil and tangerine seed oil by transesterification of the oils with ethanol using potassium hydroxide as a catalyst. In the conversion of the citrus seed oils to alkyl esters (biodiesel), the grape seed oil gave the highest yield of 90.6%, while the tangerine seed oil and orange seed oil gave a yield of 83.1 % and 78.5%, respectively. Fuel properties of the seed oil and its biodiesel were determined. The results showed that orange seed oil had a density of 730 Kg/m 3, a viscosity of 36.5 mm 2 /s, and a pour point of- 14 o C; while its biodiesel fuel had a density of 892 Kg/m 3, a viscosity of 5.60 mm 2 /s, and a pour point of- 25 o C. Grape seed oil had a density of 675 Kg/m 3, a viscosity of 39.5 mm 2 /s, and a pour point of- 12 o C, while its biodiesel fuel had a density of 890 Kg/m 3, a viscosity of 4.80 mm 2 /s, and a pour point of- 22 o C. Tangerine seed oil had an acid value of 1.40 mg/g, a density of 568 Kg/m 3, a viscosity of 37.3 mm 2 /s, and a pour point of- 15 o C, while its biodiesel fuel had an acid value of 0.22 mg/g, a density of 895 Kg/m 3, a viscosity of 5.30 mm 2 /s, and a pour point of- 24 o C.

  14. alkali-metal vapor cells: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    THE POROUS SILICON PROCESS APPLYING CONVECTION for the first time to monocrystalline Si thin-film solar cells from the porous silicon (PSI) layer transfer for manufacturing high...

  15. alkali-resistant silicon nitride: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Amorphous Silicon B. L. Zink,1,2,* R. Pietri,1. Above 50 K the thermal conductivity of thin-film amorphous silicon agrees with values previously Hellman, Frances 131 Profiles:...

  16. Potentials for Fuel Cells in Refineries and Chlor-Alkali Plants 

    E-Print Network [OSTI]

    Altseimer, J. H.; Roach, F.

    1986-01-01T23:59:59.000Z

    -pressure steam. Over the longer term, the molten carbonate and the solid oxide fuel cell, both of which operate at significantly higher temperatures, are technically very attractive. However, they do not appear to be cost competitive with conventional systems....

  17. The Effects of Using Alkali-Silica Reaction Affected Recycled Concrete Aggregate in Hot Mix Asphalt 

    E-Print Network [OSTI]

    Geiger, Brian James

    2011-10-21T23:59:59.000Z

    occurring in reactive aggregates within the HMA or re-expansion of existing gel. The Lottman test and micro-calorimeter were used to determine the moisture susceptibility of HMA made with ASR-RCA. A differential scanning calorimeter (DSC...

  18. alkali-silicate glass exposed: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    applications. - Int. J. Solids & Struct. 49 and Motivation Components of Thin Film Solar Modules back sheet or glass encapsulant electrical conductor thin 40 Glass Forming...

  19. acid based alkali-free: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    unknown authors 340 Separation of Vitamin B2 and B12 by Impregnate HPTLC Plates with Boric Acid CiteSeer Summary: AbstractA high performance thin layer chromatography system...

  20. TECHNOLOGY DATA FOR HIGH TEMPERATURE SOLID OXIDE ELECTROLYSER CELLS, ALKALI AND PEM ELECTROLYSERS

    E-Print Network [OSTI]

    Nielsen, Mads Pagh

    Mathiesen Iva Ridjan David Connolly Department of Energy Technology Mads Pagh Nielsen Technical University% losses included, as an approximation for including balance of plant consumption and losses. The second set of data which includes losses is recommended where analysis is carried out for assessing

  1. alkali metal thermal-to-electric: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to sustainable development. Particular issues considered include: current metal reserves and how these may change in the future, some of the environmental impacts (Total...

  2. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOE Patents [OSTI]

    Erickson, D.C.

    1985-06-04T23:59:59.000Z

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power. 1 fig.

  3. Studies of non-proportionality in alkali halide and strontium iodide scintillators using SLYNCI

    E-Print Network [OSTI]

    Ahle, Larry

    2011-01-01T23:59:59.000Z

    and the impact of europium doping level in strontium iodide.looking at effects due to europium dopant concentration.

  4. 2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDITCaliforniaWeifangwiki Home Jweers's picture

  5. Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) | Open

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdf Jump1946865°,Park,2005)EnergyAmatitlanGmbH und Co KGEnergyFish LakeEnergy

  6. Characterization of Ballistocardiogram Recorded at 1.5 and 3.0 Tesla in Simultaneous EEG-fMRI Zempel, J. M., Vincent, J. L., Larson-Prior, L. J., and Snyder, A. Z.

    E-Print Network [OSTI]

    Larson-Prior, Linda

    Characterization of Ballistocardiogram Recorded at 1.5 and 3.0 Tesla in Simultaneous EEG of BKG at 1.5 and 3.0 Tesla: ·3 subjects Experimental protocol: ·Functional images were simultaneously in the scanner (1.5 and 3 Tesla) with the same EEG equipment (amplifier, cap, cables) in consecutive sessions. ·3

  7. Energy Design Guidelines for High Performance Schools: Hot and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assoc.: Lynn Simon; Southern California Edison: Gregg Ander; Sustainable Buildings Industry Council: Deane Evans and Ellen Larson; US DOE: Mark Bailey; US Department of...

  8. Dynamic Interactions and Molecular Rearrangements Occurring when RNA Polymerase II Meets the Nucleosome

    E-Print Network [OSTI]

    Bintu, Lacramioara

    2010-01-01T23:59:59.000Z

    Larson, K.C. Neuman, J. Gelles, R. Landick, and S.M. Block.E.A. Abbondanzieri, R. Landick, J. Gelles, and S.M. Block.

  9. Periodic Comet Recoverers James V. Scotti

    E-Print Network [OSTI]

    Scotti, Jim

    . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.10 Tom Gehrels . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.11 James B. Gibson . . . . . . . . . . . . . . . . . . . . . . . 18 3.19 Stephen M. Larson . . . . . . . . . . . . . . . . . . . . . . . . 18 3.20 Robert H. Mc

  10. A STUDY OF ROCK-WATER-NUCLEAR WASTE INTERACTIONS IN THE PASCO BASIN, WASHINGTON -- Part: Distribution and Composition of Secondary and Primary Mineral Phases in Basalts of the Pasco Basin, Washington

    E-Print Network [OSTI]

    Benson, L.V.

    2010-01-01T23:59:59.000Z

    J. , and R. R. Larson, 1975. Diagenesis of Miocene siliceousA. W. , 1975. Zeolitic diagenesis in Oligocene volcanic1963. Stratigraphy and zeolite diagenesis of the John Day

  11. arendt paul pvet: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    processes Paul B. Larson Mathematics Websites Summary: of Leo Harrington from the 1970's, showing that a counterexample to Vaught's Conjecture has modelsScott processes Paul...

  12. avo toomsoo paul: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    processes Paul B. Larson Mathematics Websites Summary: of Leo Harrington from the 1970's, showing that a counterexample to Vaught's Conjecture has modelsScott processes Paul...

  13. 2011

    E-Print Network [OSTI]

    Optimization Software and Modeling Systems Submissions - 2011. June 2011. Non-intrusive Termination of Noisy Optimization Jeffrey Larson, Stefan M. Wild.

  14. Stasis: Flexible Transactional Storage

    E-Print Network [OSTI]

    Sears, Russell C.

    2009-01-01T23:59:59.000Z

    Stasis: Flexible Transactional Storage by Russell C. Sears AR. Larson Fall 2009 Stasis: Flexible Transactional StorageC. Sears Abstract Stasis: Flexible Transactional Storage by

  15. Franciscan subduction off to a slow start: evidence from high-precision LuHf garnet ages on high grade-blocks

    E-Print Network [OSTI]

    Wang, Zhi "Luke"

    from progressive underthrusting and underplating in a cooling subduction system. Combining geothermometry with geochronological data allow us to estimate cooling rate along the subduction zone interface

  16. PHYSICAL REVIEW A 82, 043806 (2010) Photon self-induced spin-to-orbital conversion in a terbium-gallium-garnet crystal

    E-Print Network [OSTI]

    Marrucci, Lorenzo

    `a di Napoli "Federico II", Complesso Universitario di Monte S. Angelo, 80126 Napoli, Italy 2 INFN Sezione di Napoli, Complesso Universitario di Monte S. Angelo, 80126 Napoli, Italy 3 EGO, European Gravitational Observatory, Via E. Amaldi, 56021 S. Stefano a Macerata, Cascina (PI), Italy 4 CNISM

  17. J. PHYS. IV FRANCE 7 (1997) Colloque C1, SupplCmentau Journal de Physique 111de mars 1997

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Defects in Yttrium Iron Garnet P. Novkk, J. Englich*, H. Stepankova*, J. Kohout*, H. Liitgemeier**, K

  18. EMERGENCY RESPONSE FOR HOMELAND SECURITY: LESSONS LEARNED AND THE

    E-Print Network [OSTI]

    Wang, Hai

    EMERGENCY RESPONSE FOR HOMELAND SECURITY: LESSONS LEARNED AND THE NEED FOR ANALYSIS Larson, R;Emergency Response for Homeland Security: Lessons Learned and the Need for Analysis By Richard C. Larson. In this section, we are particularly concerned with `lessons learned' and with recurring decisions that must

  19. Humanitarian Operations Pinar Keskinocak

    E-Print Network [OSTI]

    Li, Mo

    1 Humanitarian Operations Pinar Keskinocak H. Milton Stewart School of Industrial & Systems for Allocating Urban Emergency Units: A Survey Larson (1972), Urban Police Patrol Analysis Larson and Odoni (1981), Urban Operations Research Jones and Eden (1981), O.R. in the Community Pollock, Rothkopf, Barnett (1994

  20. Zevenhoven & Kilpinen TRACE ELEMENTS, ALKALI METALS 19.6.2001 8-1 Chapter 8 Trace elements,

    E-Print Network [OSTI]

    Zevenhoven, Ron

    air pollutants), "known or suspected of causing cancer or other serious health effects" (see also, in part stemming from anthropogenic sources, i.e. pollution. In wastes and waste-derived fuels the "trace to fouling of turbine blades (mainly Ca)or pollute or poison catalysts (mainly As) or sorbents downstream

  1. NEGATIVE ION PRODUCTION BY BACK-SCATTERING FROM ALKALI-METAL SURFACES BOMBARDED BY IONS OF HYDROGEN AND DEUTERIUM.

    E-Print Network [OSTI]

    Schneider, Peter Juergen

    2010-01-01T23:59:59.000Z

    and Neutralization of Negative Hydrogen Ions and Beams (and Neutralization of Negative Hydrogen Ions and Beams (and Neutralization of Negative Hydrogen Ions and Beams,

  2. Shaking the Veil: Islam, Gender and Feminist Configurations in the Nigeraian Novels of Hauwa Ali and Zaynab Alkali

    E-Print Network [OSTI]

    Ezenwa-Ohaeto, n/a

    1996-01-01T23:59:59.000Z

    ~unt Vol. 2 (1.11£05: Ouwlian Boob, 1988), p. 327. • Ibid. 'Enuau: New GencRtioa Boob, 1994). p. 171. - AIbli.17N

  3. Characterization of selective binding of alkali cations with carboxylate by x-ray absorption spectroscopy of liquid microjets

    E-Print Network [OSTI]

    Uejio, Janel S.

    2008-01-01T23:59:59.000Z

    of the interaction of the carboxylate with lithium; this isinteraction strengths of the monovalent cations of sodium, potassium, and lithiumlithium acetate revealing distinct shifts between the cations, indicative of preferential interactions.

  4. Metal and Ceramic Thin Film Growth by Reaction of Alkali Metals with Metal Halides: A New Route for

    E-Print Network [OSTI]

    Zachariah, Michael R.

    or metal oxide ceramic films are easily formed by the introduction of nitrogen or oxygen gases the precursors of sodium metal vapor, titanium tetrachloride (the limiting reagent), and either Ar or N2 gas, salt-free titanium (Ti), titanium nitride (TiN), and titanium silicide (TixSiy) thin films have been

  5. Selective Recognition of an Alkali Halide Contact Joseph M. Mahoney, Alicia M. Beatty, and Bradley D. Smith*

    E-Print Network [OSTI]

    Smith, Bradley D.

    in organic solvents.1 We2 and others3 have shown that if both of the counterions in a target salt have

  6. Structural studies of alkali methylidyne radicals: High resolution spectroscopy of NaCH and KCH ,,X~ 3

    E-Print Network [OSTI]

    Ziurys, Lucy M.

    Institute of Physics. S0021-9606 99 02605-7 I. INTRODUCTION The interaction of metals with organic molecules, especially those involving lithium, sodium, and potassium.6 The usefulness of organolithium compounds and therefore concern oligomeric structures. Evaluating the properties of even the simplest organoalkali

  7. Electronic and phonon instabilities in face-centered-cubic alkali metals under pressure studied using ab initio calculations

    E-Print Network [OSTI]

    Oganov, Artem R.

    electron model is known to be a good approxi- mation to describe their electronic properties due to the weak interaction between valence electrons and ionic core under ambient conditions.1 However, under be the origin of the complex phase transitions for fcc lithium. In this work, we investigate systemically

  8. Performance-based approach to evaluate alkali-silica reaction potential of aggregate and concrete using dilatometer method

    E-Print Network [OSTI]

    Shon, Chang Seon

    2009-05-15T23:59:59.000Z

    and encouragement. Finally, this research was supported in part by grants from the Innovative Pavement Research Foundation (IPRF) and 2004 Education Foundation Fellowship from Portland Cement Association (PCA). The author is grateful for their support... CHAPTER I INTRODUCTION .................................................................................. 1 Background....................................................................................... 1 Research...

  9. Room-temperature photomagnetism in the spinel ferrite (Mn,Zn,Fe)3O4 as seen via soft x-ray magnetic circular dichroism

    E-Print Network [OSTI]

    Bettinger, J.S.

    2010-01-01T23:59:59.000Z

    photomagnetism in the spinel ferrite (Mn,Zn,Fe)3O4 as seendoped garnets 1 , doped spinel ferrites 2 , doped perovskiteIn the doped garnets and ferrites, the microscopic origin of

  10. Thursday 30.8.2012 Characterization and Bioanalytic Applications of Luminescent

    E-Print Network [OSTI]

    Schubart, Christoph

    Aluminum Garnet (YAG:Ce) Nanoparticles 13:50 ­ 14:10 I. Hyppänen (UTU): Frequency-domain measurements

  11. Records of the evolution of the Himalayan orogen from in situ ThPb ion microprobe dating of monazite: Eastern Nepal and western Garhwal

    E-Print Network [OSTI]

    Harrison, Mark

    Ma inclusions are preserved within garnets of the Greater Himalayan Crystallines. The presence of 45:2

  12. In The Name Of The Father, The Governor, And "A-1 Good Men": Performing Gender and Statehood In Territorial New Mexico, 1880 - 1912

    E-Print Network [OSTI]

    Sanchez, Sabrina

    2013-01-01T23:59:59.000Z

    Review 84 (1990): 293-310. Lamar, Howard. The Far Southwest,1985); and Howard Roberts Lamar, The Far Southwest, 1846-s Quest for Statehood; and Lamar, The Far Southwest. Larson,

  13. APPENDIX 13-C Abnormally Hazardous Task Report DER-DCLR-33.

    E-Print Network [OSTI]

    Sheridan, Jennifer

    APPENDIX 13-C Abnormally Hazardous Task Report DER-DCLR-33. EMPLOYING UNIT CONTACT PERSON Academic Technology--Printing Areas Geoff Larson, 212 Env Protection-Safefty Bldg 263-9002 All Others Areas Tom Rutlin

  14. Probabilistic phonotactics in production 1 Running Head: PROBABILISTIC PHONOTACTICS IN PRODUCTION

    E-Print Network [OSTI]

    Reber, Paul J.

    Probabilistic phonotactics in production 1 Running Head: PROBABILISTIC PHONOTACTICS IN PRODUCTION Phonotactic probability influences speech production Matthew Goldrick and Meredith Larson Department in production 2 Abstract Speakers are faster and more accurate at processing certain sound sequences within

  15. Frontiers in Chemical Imaging Seminar Series

    E-Print Network [OSTI]

    Frontiers in Chemical Imaging Seminar Series On the trail of the Chimera The Atom the Chimera is still elusive. 1. Thomas F. Kelly and David J. Larson. Ann Rev. Materials Res 42 (2012) 1. 2

  16. Changing Places: How Communities Will Improve the Health of Boys of Color

    E-Print Network [OSTI]

    Edley, Christopher; Ruiz de Velasco, Jorge

    2010-01-01T23:59:59.000Z

    and Larson 2002. References Aspen Institute Roundtable onKubisch. Washington, D.C. : Aspen Institute. Brown, Brett.in young people’s lives (Aspen Report 2005; Davis, Kolburn,

  17. EVALUATION OF VARIOUS FOLIAR SPRAYS FOR USE AS A CANADA GOOSE GRAZING DETERRENT

    E-Print Network [OSTI]

    and constant support. I would especially like to thank members of the Webster, SD office, especially Blake and advice in regards to the project. I also thank my committee members, Dr. Gary Larson and Dr. KC Jensen

  18. arXiv:astroph/0007038 A&A manuscript no.

    E-Print Network [OSTI]

    Saglia, Roberto P.

    , and fit logarithmic gradients in the range \\Gamma0:2 to 0.1 mag per decade. These values are similar of the monolithic collapse `a la Larson (1974) Send offprint requests to: R.P. Saglia (email: saglia

  19. Silicon based millimeterwave integrated circuits for multi giga-bits-per-second wireless data

    E-Print Network [OSTI]

    Kodkani, Rahul M.

    2009-01-01T23:59:59.000Z

    Figure 1.8: Direct-conversion receiverL. Larson, “ A 24-GHz CMOS Direct-Conversion Sub- Harmonic2000. [17] A. Abidi, “Direct-conversion radio transceivers

  20. Portable Wireless Sensors for Object Usage Sensing in the Home: Challenges and Practicalities

    E-Print Network [OSTI]

    Emmanuel Munguia Tapia, Stephen S. Intille, Kent Larson House_n, Massachusetts Institute of Technology 1 battery performance. Results of testing 168 of the sensors in an instrumented home for one month of normal

  1. Multi-Grain Clustering Topic Model (MGCTM)Motivation Evaluation of Document Clustering Integrating Document Clustering and Topic Modeling

    E-Print Network [OSTI]

    Xing, Eric P.

    proportion ·Sample Bernoulli parameter ·For each word (l) (l) ( )Dir (g) (g) ( )Dir ( )Beta w Sample kuwait larson shuttle energy usr motif xterm henrik armenians jews mission dc apr Local topics of 3

  2. 1st Rangeland Research Symposium 1/19/2012 http://rangelandwatersheds.ucdavis.edu 1

    E-Print Network [OSTI]

    Tate, Kenneth

    Latimer David Lewis, Toby O'Geen, Mel George, Kevin Rice, Ken Tate, Truman Young Project collaborators Gustafson, John Harper, Roger Ingram, Doug Johnson, Carissa Koopman, Royce Larsen, Stephanie Larson, David

  3. University Graduate School Academic Bulletin

    E-Print Network [OSTI]

    Indiana University

    's Professors Judith H. Anderson*, Anthony Ardizzone*, Robert Fulk*, James Naremore* (Emeritus) Rudy Professor*, Charles Forker* (Emeritus), Robert Dennis Fulk*, Mary Gaither* (Emerita), Donald Gray* (Emeritus), Kenneth* (Emeritus) Associate Professors Michael P. Adams*, Dana Larson Anderson*, Purnima Bose*, William Burgan

  4. Development of Eu{sup 3+} activated monoclinic, perovskite, and garnet compounds in the Gd{sub 2}O{sub 3}–Al{sub 2}O{sub 3} phase diagram as efficient red-emitting phosphors

    SciTech Connect (OSTI)

    Li, Jinkai [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Li, Ji-Guang, E-mail: LI.Jiguang@nims.go.jp [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Advanced Materials Processing Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047 (Japan); Li, Jing [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Advanced Materials Processing Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047 (Japan); Liu, Shaohong; Li, Xiaodong; Sun, Xudong [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang, Liaoning 110004 (China); Sakka, Yoshio [Advanced Materials Processing Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba, Ibaraki 305-0047 (Japan)

    2013-10-15T23:59:59.000Z

    Eu{sup 3+} doped Gd{sub 4}Al{sub 2}O{sub 9} (GdAM), GdAlO{sub 3} (GdAP), and Gd{sub 3}Al{sub 5}O{sub 12} (GdAG, containing 10 at% of Lu{sup 3+} for lattice stabilization) have been developed in this work as efficient red-emitting phosphors. With coprecipitated carbonate precursors, phase evolution studies found minimum processing temperatures of ?1000, 1100, and 1300 °C for the three phosphors to crystallize as pure phases, respectively. Compared with their yttrium aluminate counterparts, the gadolinium-based phosphors exhibit red-shifted O{sup 2?}–Eu{sup 3+} charge transfer excitation band (CTB) centers due to the lower electronegativity of Gd{sup 3+} and appreciably higher quantum yields of photoluminescence owing to the occurrence of efficient Gd{sup 3+}?Eu{sup 3+}energy transfer. The optimal Eu{sup 3+} contents were determined to be ?7.5 at% for GdAM and 5.0 at% for both GdAP and GdAG, and concentration quenching of luminescence was suggested to be due to exchange interactions. Fluorescence decay analysis found a shorter lifetime for the phosphor powder processed at a higher temperature or with a higher Eu{sup 3+} content, and the underlying mechanism was discussed. Fluorescence lifetimes were also compared between the yttrium and gadolinium phosphor systems for the dominant emissions. - Graphical abstract: Eu{sup 3+} doped Gd{sub 4}Al{sub 2}O{sub 9} (GdAM), GdAlO{sub 3} (GdAP), and Gd{sub 3}Al{sub 5}O{sub 12} (GdAG, containing 10 at% of Lu{sup 3+} for lattice stabilization) have been developed as efficient red-emitting phosphors. Owing to the Gd{sup 3+} to Eu{sup 3+} energy transfer, improved luminescence is observed for the compounds than their yttrium-based counterparts. Display Omitted - Highlights: • Eu{sup 3+} doped Gd{sub 4}Al{sub 2}O{sub 9}, GdAlO{sub 3} and (Gd{sub 0.9}Lu{sub 0.1}){sub 3}Al{sub 5}O{sub 12} developed as red phosphors. • Improved red-emissions than their yttrium-based counterparts confirmed. • Efficient Gd{sup 3+}?Eu{sup 3+}energy transfer observed. • Applications in various lighting, display, and scintillation areas expected.

  5. alcumg alloy corrosion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkali sulfates, and alkali chlorides. Candidate alloys are also exposed in a small-scale coal-fired combustor at the National Energy Technology Laboratory in Pittsburgh....

  6. Comparison of CsBr and KBr coated Cu photocathodes: Effects of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    processes, that introduce defect states into the alkali halide bandgap, induced by UV laser irradiation. It is possible that alkali metal formation occurs during UV irradiation...

  7. INTERACTION OF A SUB-BITUMINOUS COAL WITH A STRONG ACID AND A STRONG BASE

    E-Print Network [OSTI]

    Seth, M.

    2010-01-01T23:59:59.000Z

    alkali con- alkali-soluble Seam coal over the temperaturefor the Pittsburgh Seam coal. Another important conclusionVI, Composition of Roland seam coal--ultimate analysis~ wt%,

  8. A BRIEF HISTORY OF INDUSTRIAL CATALYSIS

    E-Print Network [OSTI]

    Heinemann, Heinz

    2013-01-01T23:59:59.000Z

    this by ion exchanging rare earth metals for alkali meta lChlorides of rare earths and alkali metals often serve as

  9. THE PHOTOCATALYZED PRODUCTION OF HYDROGEN FROM WATER ON Pt-FREE SrTi03 SINGLE CRYSTALS IN THE PRESENCE OF ALKALI HYDROXIDES

    E-Print Network [OSTI]

    Wagner, F.T.

    2012-01-01T23:59:59.000Z

    Capt ion_§_ Figure 1. Hydrogen photogeneration on a metal-NaOH at 44°C. Figure 2. Hydrogen photoproduction on a metal-PHOTOCATALYZED PRODUCTION OF HYDROGEN FROM WATER ON Pt-FREE

  10. Ion Partitioning at the liquid/vapor interface of a multi-component alkali halide solution: A model for aqueous sea salt aerosols

    E-Print Network [OSTI]

    Ghosal, Sutapa

    2009-01-01T23:59:59.000Z

    1988, 334, 138-141,. Hausmann, M. ; Platt, U. J. Geophys.Res. 1994, 99, 25399-25413. Platt, U. ; Hausmann, M. Res.Trost, B. ; Unold, W. ; Platt, U. Tellus, 1997, 49B, 533-

  11. Figure 1. Total alkali vs. silica plot of composition of existing ChemCam standards (open grey circles), new samples (open colored symbols), and APXS values for

    E-Print Network [OSTI]

    Rossman. George R.

    a pulsed laser beam at a point on a rock or soil target. Material is ablated from a 350-550 µm diameter the first 100 sols of the mis- sion, the laser-induced breakdown spectroscopy (LIBS) experiment on the Chem

  12. Effect of Sodium Carboxymethyl Celluloses on Water-catalyzed Self-degradation of 200-degree C-heated Alkali-Activated Cement

    SciTech Connect (OSTI)

    Sugama T.; Pyatina, T.

    2012-05-01T23:59:59.000Z

    We investigated the usefulness of sodium carboxymethyl celluloses (CMC) in promoting self-degradation of 200°C-heated sodium silicate-activated slag/Class C fly ash cementitious material after contact with water. CMC emitted two major volatile compounds, CO2 and acetic acid, creating a porous structure in cement. CMC also reacted with NaOH from sodium silicate to form three water-insensitive solid reaction products, disodium glycolate salt, sodium glucosidic salt, and sodium bicarbonate. Other water-sensitive solid reaction products, such as sodium polysilicate and sodium carbonate, were derived from hydrolysates of sodium silicate. Dissolution of these products upon contact with water generated heat that promoted cement’s self-degradation. Thus, CMC of high molecular weight rendered two important features to the water-catalyzed self-degradation of heated cement: One was the high heat energy generated in exothermic reactions in cement; the other was the introduction of extensive porosity into cement.

  13. CONNORMAN: "CHAP08" --2009/3/31 --18:08 --PAGE 195 --#1 Conceptual model for small-volume alkali basalt

    E-Print Network [OSTI]

    Bigelow, Stephen

    waste repository F. J. Spera and S. J. Fowler Today, 31 countries operate 450 nuclear power reactors supplying electric power to 1 billion people, 15% of the world population. Nuclear reactors generate 17% of global electric power needs and a number of industrialized countries depend on nuclear power for at least

  14. Ion Partitioning at the liquid/vapor interface of a multi-component alkali halide solution: A model for aqueous sea salt aerosols

    E-Print Network [OSTI]

    Ghosal, Sutapa

    2009-01-01T23:59:59.000Z

    A model for aqueous sea salt aerosols Sutapa Ghosal, 1species associated with sea salt ice and aerosols has beena minor component in sea salt, which has a Br – /Cl – molar

  15. Fluid origins, paths, and fluid-rock reactions at convergent margins, using halogens, Cl stable isotopes, and alkali metals as geochemical tracers

    E-Print Network [OSTI]

    Wei, Wei

    2007-01-01T23:59:59.000Z

    range kg/yr Cl sources and sinks Water or rock mass mol/kgtemperature at the source of fluid-rock reactions, asto identify the fluid-rock reactions at source. In addition,

  16. Fluid origins, paths, and fluid-rock reactions at convergent margins, using halogens, Cl stable isotopes, and alkali metals as geochemical tracers

    E-Print Network [OSTI]

    Wei, Wei

    2007-01-01T23:59:59.000Z

    to Mineralogy and Petrology 23(2): 117-127. Moore, G. F. ,to Mineralogy and Petrology 76(1): 17-23. Miyashiro, A. ,to Mineralogy and Petrology 138(3): 265-283. Peacock, S.

  17. Mercury Effects, Sources and Control Measures

    E-Print Network [OSTI]

    ...........................................................................................................................................................................................................5 Coal-Fired Power Plants.......................................................................................................................................................................................................7 Chlor-Alkali Plants

  18. The official student voice of the Florida State University Panama City Summer 2011 Issue

    E-Print Network [OSTI]

    Sura, Philip

    @my.fsu.edu or Mrs. Cristina Rios at crios@pc.fsu.edu. Jenn Davis staff writer Garnet Key Honor Society Induc- tion

  19. The Origin and Evolution of the Kaapvaal Cratonic Lithospheric Mantle

    E-Print Network [OSTI]

    Simon, Nina

    -depleted samples. Garnet Nd^Hf isotope characteristics indicate metasomatic trace element enrichment during to the magmaphile element depletion of the Kaapvaal cratonic lithospheric mantle and its subsequent re-enrichment^Os isotope compositions, and major and trace element concentrations, and garnet and clinopyroxene for Lu

  20. This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research

    E-Print Network [OSTI]

    Abbott Jr., Richard N.

    Rare earth elements Ultra high pressure Mantle plume Ultra high pressure (UHP) garnet of coexisting garnet+spinel+corundum, indicative of very high pressure. Chondrite-normalized REEs (rare earth Elsevier B.V. All rights reserved. 1. Introduction Globally scarce ultra high pressure (UHP) rocks

  1. Regenerable sorbents for CO.sub.2 capture from moderate and high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    2008-01-01T23:59:59.000Z

    A process for making a granular sorbent to capture carbon dioxide from gas streams comprising homogeneously mixing an alkali metal oxide, alkali metal hydroxide, alkaline earth metal oxide, alkaline earth metal hydroxide, alkali titanate, alkali zirconate, alkali silicate and combinations thereof with a binder selected from the group consisting of sodium ortho silicate, calcium sulfate dihydrate (CaSO.sub.4.2H.sub.2O), alkali silicates, calcium aluminate, bentonite, inorganic clays and organic clays and combinations thereof and water; drying the mixture and placing the sorbent in a container permeable to a gas stream.

  2. Internal-integral sodium return line for sodium heat engine

    DOE Patents [OSTI]

    Hunt, Thomas K. (Ann Arbor, MI)

    1985-01-01T23:59:59.000Z

    A thermoelectric generator device which converts heat energy to electrical energy. An alkali metal is used with a solid electrolyte and a portion of the return line for the alkali metal is located within the generator vacuum space.

  3. THE SCIENCE OF INFORMATION PROTECTION Daniel F. Warren

    E-Print Network [OSTI]

    between different classes of elements (Alkali metals, Alkali earth metals, Transition metals, Rare earth metals, Noble gases and Halogens) and there is a significance to the order of elements in the table

  4. Equivalent roughness height for plane bed under oscillatory flow

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , the bed roughness height of a flat and fixed bed is given in terms of the Nikuradse roughness height (ks may be several orders of magnitude larger than for a fixed bed. This is probably causedEquivalent roughness height for plane bed under oscillatory flow Beno^it Camenen , Magnus Larson

  5. Asymmetric growth in micelles containing oil Peter H. Nelson,a)

    E-Print Network [OSTI]

    Nelson, Peter Hugo

    applications range from drug delivery to providing understanding of basic bio- logical processes. Recently was not in- vestigated. Extensive equilibrium studies of oil­water­surfactant systems have been conducted by Larson in recent years8­12 using a lattice model. The rich phase behavior of mainly ordered condensed

  6. 1 | Building America eere.energy.gov DOE's Building America

    E-Print Network [OSTI]

    1 | Building America eere.energy.gov DOE's Building America Low-E Storm Window Adoption Program Working Group #12;2 | Building America eere.energy.gov Pacific Northwest National Laboratory · Katie Cort, Larson Manufacturing Company Key Staff #12;3 | Building America eere.energy.gov Problem · Windows account

  7. VOL. 9 NO. 5 MAY/JUNE 2006 Also in this issue.........

    E-Print Network [OSTI]

    Sadoulet, Elisabeth

    ? Explaining the Price Premium for Organic Fresh Produce by Yuko Onozaka, David Bunch, and Douglas Larson How Vulnerable is California Agriculture to Higher Energy Prices? by David Roland-Holst and David Zilberman Energy price risk is important to California agriculture. The degree of vulnerability varies

  8. Dimethyl ether (DME) from coal as a household cooking fuel in China

    E-Print Network [OSTI]

    be made from any carbonaceous feedstock, including natural gas, coal, or biomass, using establishedDimethyl ether (DME) from coal as a household cooking fuel in China Eric D. Larson Princeton gas (LPG) as a household cooking fuel. As such, DME is an attractive fuel for clean cooking. DME can

  9. Running head: GUIDING ATTENTION ON PHYSICS PROBLEMS 1 Guiding Attention on Physics Problems Using Visual Cues Modeled After Experts' Eye

    E-Print Network [OSTI]

    Zollman, Dean

    Visual Cues Modeled After Experts' Eye Movements Adrian Madsen, Adam Larson, Amy Rouinfar, Allison Coy by recording their eye movements. In Study 1, we record eye movements of introductory and graduate physics in visual attention. We use the eye movements of those who answer these questions correctly to design visual

  10. 3944 VOLUME 14J O U R N A L O F C L I M A T E 2001 American Meteorological Society

    E-Print Network [OSTI]

    Randall, David A.

    on the amount and vertical distribution of water vapor above the cold-pool boundary layer (CPBL). In response; Sun and Liu 1996; Miller 1997; Larson et al. 1999, hereinafter LHK; Sherwood 1999; Clement and Seager cloud-radiative effects and specified the potential temperature difference between the upper * Current

  11. Brazil Week "Vanderbilt"and the Vanderbilt logo are registered trademarks and service marks of

    E-Print Network [OSTI]

    Bordenstein, Seth

    Brazil Week "Vanderbilt"and the Vanderbilt logo are registered trademarks and service marks of Citizenship in Late-Nineteenth-Century Brazil" 4:00 p.m. Buttrick Hall 123 Futebol Tournament All are invited.d.larson@vanderbilt.edu. 5:30 p.m. Alumni Lawn Wednesday SEPT World on Wednesday "Vanderbilt and Brazil: Past Present

  12. BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS

    E-Print Network [OSTI]

    BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS ERIC D. LARSON modeling of gasifier/gas turbine pulp-mill cogeneration systemsusing gasifier designs under commercial gasification. The use of biomass fuels with gas turbines could transform a typical pulp mill from a net

  13. IEEE TRANSACTIONS ON MICROWAVE THEORY AND TECHNIQUES, VOL. 49, NO. 11, NOVEMBER 2001 2163 Synergistic Design of DSP and Power Amplifiers for

    E-Print Network [OSTI]

    Galton, Ian

    Synergistic Design of DSP and Power Amplifiers for Wireless Communications Peter M. Asbeck, Fellow, IEEE Initiative on Low Power, Low Noise Electronics for Mobile Communications. The authors are with the Electrical, Lawrence E. Larson, and Ian G. Galton, Member, IEEE Abstract--Co-design of digital signal-processing (DSP

  14. TATE OF CALIFORNI NERGY COMMISSION

    E-Print Network [OSTI]

    information disclosed to consumers and calculating net system power. Using the detailed information from. Rosenfeld Steve Larson, Executive Director Drake Johnson, Principal Author, Chuck Mizutani, Manager Code, Section 398.5(e), this report compares the source of power that retailers have disclosed

  15. ANNUAL VARIABILITY OF REEF-FISH ASSEMBLAGES IN KELP FORESTS OFF SANTABARBARA, CALIFORNIA

    E-Print Network [OSTI]

    ANNUAL VARIABILITY OF REEF-FISH ASSEMBLAGES IN KELP FORESTS OFF SANTABARBARA, CALIFORNIA ALFRED W. EBELING/ RALPH J. LARSON,2 WILLIAM S. ALEVIZON,3 AND RICHARD N. BRAy 4 ABSTRACT Assemblages of kelp-bed fishes that live in and about the kelp canopy or over the reef bottom were censused by movie strips

  16. The technology menu for efficient energy use in India

    E-Print Network [OSTI]

    of energy audit and other studies from the files of the National Productivity Council were reviewed. SinceThe technology menu for efficient energy use in India Eric D. Larson and Anand Subbiah Center for Energy and Environmental Studies Princeton, New Jersey, 08544, USA TOTAL ELECTRICITY GENERATION in India

  17. domain of the leading head is angled forward and has a kink shortly after emerging from the

    E-Print Network [OSTI]

    Ronquist, Fredrik

    . U.S.A. 96, 13726 (1999). 8. W. Hua, J. Chung, J. Gelles, Science 295, 844 (2002). 9. M. Y. Ali et al (2000). 18. R. E. Thompson, D. R. Larson, W. W. Webb, Biophys. J. 82, 2775 (2002). 19. J. Gelles, B. J

  18. DRAFT VERSION SEPTEMBER 3, 2002 Preprint typeset using L A T E X style emulateapj

    E-Print Network [OSTI]

    Saglia, Roberto P.

    from optical Lick (Fe, Mg and H#12;) indices. Uncertainties in the calibration, the fitting functions are within the range allowed by the models and the large uncertainties in the fitting functions. b­ els for galaxy formation and evolution. The classical picture of monolithic collapse (Larson 1974

  19. VO L U M E 1 4 N U M B E R 4 FA L L 2 0 1 2 CLASS OF 2016 p. 8

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    treatments to maximize effectiveness in patient care FALL 2012 Diagnostic Imaging and Radiology Research UW Student Life 34 WIMR II 36 Healer's Journey 40 Larson's Perspective Addiction Medicine Fellowship Training future primary care providers to confront this serious issue Connecting Disciplines for Digestive Health

  20. Bioenergy and land-use competition in Northeast Brazil

    E-Print Network [OSTI]

    . Larson Center for Energy and Environmental Studies, Princeton University, Princeton, NJ 08544, USA] for a review.) (For reference, total annual commercial energy consumption is roughly 400 EJ/yr, and total area It is often claimed that dedicated energy plantations may be established on degraded lands so as to prevent

  1. BIOGRAPHIES Randolph Hall: Networks, Emergency Response,

    E-Print Network [OSTI]

    Southern California, University of

    BIOGRAPHIES Randolph Hall: Networks, Emergency Response, Mathematical Modeling Hall, the center: Emergency Response Larson, former co-director of the MIT Operations Research Center, was one of the youngest and more than 75 scientific articles, primarily in emergency response, queuing, logistics and workforce

  2. Preparedfor SeptemberI, 1994 BloResources'94 BiomassResources:ameansto sustainabledevelopment

    E-Print Network [OSTI]

    -7,1994, Bangalore,India. DRAFT FARM FORESTRY IN BRAZIL Eric D. Larson Center for Energy and Environmental Studies of Forest Science University of Sao Paulo Piracicaba, SP 13418-900, Brazil ABSTRACT-scaleplantationsto consumersin Brazil. Most private-sectorforestry companieshavestartedsuchprograms

  3. Hallucal grasping in Nycticebus coucang: further implications for the functional significance of a large peroneal process

    E-Print Network [OSTI]

    Boyer, Doug M.

    of a large peroneal process Amanda K. Kingston a,*, Doug M. Boyer b , Biren A. Patel b , Susan G. Larson b Medical Center, Stony Brook, New York 11794, USA a r t i c l e i n f o Article history: Received 28 May grasping in lemurids (Boyer et al., 2007). However, non-lemurid prosimians have a I-V opposable grasp

  4. ERDC/ELTR-12-25 Army Range Technology Program

    E-Print Network [OSTI]

    US Army Corps of Engineers

    ERDC/ELTR-12-25 Army Range Technology Program Large-Scale Physical Separation of Depleted Uranium-Scale Physical Separation of Depleted Uranium from Soil Steven Larson, Victor Medina, John Ballard, Chris Griggs) at Yuma Proving Ground (YPG) to evaluate this technique for removal of depleted uranium (DU) metal from

  5. The undersigned, appointed by the Dean of the Graduate School, have examined the thesis entitled

    E-Print Network [OSTI]

    Missouri at Columbia, University of

    and assistance: Drs. Bill Kurtz, Dave Larsen, Rose-Marie Muzika, Gene Garrett, Hong He, Bernie Lewis, and Hank of acceptance. _____________________________________ Dr. David R. Larsen _______________________________________________ by CHAD LARSON Dr. David R. Larsen, Thesis Supervisor DECEMBER 2004 #12;ii ACKNOWLEDGEMENTS I would like

  6. NOAA Competitive Level -Codes List of changes All This document converted without change to MSWord from WordPerfect, 8/5/04.

    E-Print Network [OSTI]

    , per John Hanson. 6/10/02 5201 Diving Equipment Worker added per Brooke Larson, WASC. 11/19/01 #12;NOAA, qualification requirements, pay schedules, and working conditions so that an agency may reassign the incumbent are familiar with qualification requirements and recruiting practices. Care and thought is needed in assigning

  7. Annual Graduate Student Symposium Schedule Time Presenter Title

    E-Print Network [OSTI]

    Meyers, Steven D.

    of the Mississippi River Diversions During the Deepwater Horizon Oil Spill 10:1510:30 am Rebekka Larson Shifts Petroleum Dispersal and Partitioning After the Deepwater Horizon Blowout 99:15 am Robert Ulrich Grouper in Depositional Patterns in the NE Gulf of Mexico Following the 2010 BP Blowout Event: Stratigraphy

  8. Introduction to CMI-13: The thirteen annual meeting of

    E-Print Network [OSTI]

    in ocean and terrestrial carbon science Stone and Phillips New independent report on geothermal energy: tomorrow Agenda item Why included? Meggers New faculty: energy-efficient buildings revisited Steingart New the mechanisms and effects of global change" Low-Carbon Energy Group: Eric Larson: "Energy systems analysis

  9. Eur. Phys. J. D (2010) DOI: 10.1140/epjd/e2010-10118-y

    E-Print Network [OSTI]

    Ebeling, Werner

    for the appli- cations in geocosmical alkali plasma research [10]. Near the critical point and at higher

  10. ) L'w LLOAJO>' , Ris-R-516 One-Electron Theory of Metals

    E-Print Network [OSTI]

    , the structural phase transitions in the alkali, alkaline earth, and rare earth metals, and the local- ization transitions in the alkali, alkaline earth, and rare earth metals, and the localization of 3d, 4f, and 5f metals 46 5.2 The alkali metals at moderate compression 48 5.3 The alkaline earth metals 54 5

  11. [The Journal of Geology, 1999, volume 107, p. 353374] 1999 by The University of Chicago. All rights reserved. 0022-1376/99/10703-0007$01.00 Early Carboniferous Unroofing in Western Norway: A Tale of Alkali

    E-Print Network [OSTI]

    Andersen, Torgeir Bjørge

    rights reserved. 0022-1376/99/10703-0007$01.00 353 Early Carboniferous Unroofing in Western Norway Geological Survey of Norway, N-7491 Trondheim, Norway (e-mail: Elizabeth.Eide@ngu.no) A B S T R A C T 40 Ar/39 Ar thermochronologic data from an extensional detachment zone in western Norway document

  12. Soranakom, C., Bakhshi M. , and Mobasher, B. " Role of Alkali Resistant Glass Fibers in Suppression of Restrained Shrinkage Cracking of Concrete Materials," 15th International Glass Fibre Reinforced Concrete Association

    E-Print Network [OSTI]

    Mobasher, Barzin

    environments, concrete shrinks due to loss of moisture from capillary and gel pore microstructure. It is also, relative humidity, temperature and geometry of the structure [1]. One possible method to reduce the adverse effect of cracking is the addition of short glass fibers; however, the quantitative methods for assessing

  13. Treating I anion as a zero-electron system : the Li I and CsI alkali halides anions Vincent ROBERT , 1, 2 Fernand SPIEGELMAN, 1 and Marie-Bernadette LEPETIT 1

    E-Print Network [OSTI]

    ) on lithium (respectively cesium). An original scheme is proposed to build a pseudo-potential describing the short-range electron-I interaction beyond the point charge approximation. The importance of the ZEP mechanical determination of electronic properties of large molecules and sophisticated materials has become

  14. A Simple Thermodynamic Model for Melting of Peridotite in the System NCFMASOCr

    E-Print Network [OSTI]

    Jennings, Eleanor S.; Holland, Tim J. B.

    2015-05-25T23:59:59.000Z

    not included and melting was not considered. The consequences of adding Fe3þ and Cr to peridotites and their constituent phases is exam- ined here, particularly with respect to the effects on the spinel–garnet transition and on melting at depth. Addition of Fe3... þ and Cr in garnet is done via the end- members andradite (andr, Ca3Fe2Si3O12) and knorrin- gite (knor, Mg3Cr2Si3O12), both of which exist already in the dataset of Holland & Powell (2011). The mixing model for garnets is an extension of that used...

  15. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, Lamar T. (Knoxville, TN)

    1988-01-01T23:59:59.000Z

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  16. Carbonation of metal silicates for long-term CO2 sequestration

    SciTech Connect (OSTI)

    Blencoe, James G; Palmer, Donald A; Anovitz, Lawrence M; Beard, James S

    2014-03-18T23:59:59.000Z

    In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).

  17. Carbonation of metal silicates for long-term CO.sub.2 sequestration

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Palmer, Donald A. (Oliver Springs, TN); Anovitz, Lawrence M. (Knoxville, TN); Beard, James S. (Martinsville, VA)

    2012-02-14T23:59:59.000Z

    In a preferred embodiment, the invention relates to a process of sequestering carbon dioxide. The process comprises the steps of: (a) reacting a metal silicate with a caustic alkali-metal hydroxide to produce a hydroxide of the metal formerly contained in the silicate; (b) reacting carbon dioxide with at least one of a caustic alkali-metal hydroxide and an alkali-metal silicate to produce at least one of an alkali-metal carbonate and an alkali-metal bicarbonate; and (c) reacting the metal hydroxide product of step (a) with at least one of the alkali-metal carbonate and the alkali-metal bicarbonate produced in step (b) to produce a carbonate of the metal formerly contained in the metal silicate of step (a).

  18. March/April 1998 WAS 1998 Motor Carrier Permit Honey Board Busy

    E-Print Network [OSTI]

    Ferrara, Katherine W.

    you drop at the Palouse shopping mall (you can walk to it). A little further away you can jet boat Creek garnet area; or hike to the top of Kamiak Butte for a spectacular view of the Palouse Hills

  19. Basalt petrogenesis beneath slow- and ultraslow-spreading Arctic mid-ocean ridges

    E-Print Network [OSTI]

    Elkins, Lynne J

    2009-01-01T23:59:59.000Z

    To explore the ability of melting mafic lithologies to produce alkaline ocean-island basalts (OIB), an experimental study was carried out measuring clinopyroxene (Cpx)melt and garnet (Gt)-melt partition coefficients during ...

  20. Sandia National Laboratories: SAND 2011-5054W

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    array of these phosphors has been developed for use with fluorescent lamps. The first SSL white LEDs have used an yttrium aluminum garnet doped with trivalent cerium (YAG:Ce+3)...