National Library of Energy BETA

Sample records for large-scale co2 storage

  1. Large-scale impact of CO2 storage in deep saline aquifers: A sensitivity study on pressure response in stratified systems

    E-Print Network [OSTI]

    Zhou, Quanlin

    Large-scale impact of CO2 storage in deep saline aquifers: A sensitivity study on pressure response storage potential of all the geological CO2 storage options and are widely distributed throughout the globe in all sedimentary basins.ForCO2 storage tohaveasignificantimpact on atmospheric levels

  2. Research project on CO2 geological storage and groundwaterresources: Large-scale hydrological evaluation and modeling of impact ongroundwater systems

    SciTech Connect (OSTI)

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan,Preston; Zhang,K.; Tsang, Chin-Fu

    2007-10-24

    If carbon dioxide capture and storage (CCS) technologies areimplemented on a large scale, the amounts of CO2 injected and sequesteredunderground could be extremely large. The stored CO2 then replaces largevolumes of native brine, which can cause considerable pressureperturbation and brine migration in the deep saline formations. Ifhydraulically communicating, either directly via updipping formations orthrough interlayer pathways such as faults or imperfect seals, theseperturbations may impact shallow groundwater or even surface waterresources used for domestic or commercial water supply. Possibleenvironmental concerns include changes in pressure and water table,changes in discharge and recharge zones, as well as changes in waterquality. In compartmentalized formations, issues related to large-scalepressure buildup and brine displacement may also cause storage capacityproblems, because significant pressure buildup can be produced. Toaddress these issues, a three-year research project was initiated inOctober 2006, the first part of which is summarized in this annualreport.

  3. On scale and magnitude of pressure build-up induced by large-scale geologic storage of CO2

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J. T.

    2011-05-01

    The scale and magnitude of pressure perturbation and brine migration induced by geologic carbon sequestration is discussed assuming a full-scale deployment scenario in which enough CO{sub 2} is captured and stored to make relevant contributions to global climate change mitigation. In this scenario, the volumetric rates and cumulative volumes of CO{sub 2} injection would be comparable to or higher than those related to existing deep-subsurface injection and extraction activities, such as oil production. Large-scale pressure build-up in response to the injection may limit the dynamic storage capacity of suitable formations, because over-pressurization may fracture the caprock, may drive CO{sub 2}/brine leakage through localized pathways, and may cause induced seismicity. On the other hand, laterally extensive sedimentary basins may be less affected by such limitations because (i) local pressure effects are moderated by pressure propagation and brine displacement into regions far away from the CO{sub 2} storage domain; and (ii) diffuse and/or localized brine migration into overlying and underlying formations allows for pressure bleed-off in the vertical direction. A quick analytical estimate of the extent of pressure build-up induced by industrial-scale CO{sub 2} storage projects is presented. Also discussed are pressure perturbation and attenuation effects simulated for two representative sedimentary basins in the USA: the laterally extensive Illinois Basin and the partially compartmentalized southern San Joaquin Basin in California. These studies show that the limiting effect of pressure build-up on dynamic storage capacity is not as significant as suggested by Ehlig-Economides and Economides, who considered closed systems without any attenuation effects.

  4. Research project on CO2 geological storage and groundwater resources: Large-scale hydrological evaluation and modeling of impact on groundwater systems

    E-Print Network [OSTI]

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan, Preston; Zhang, K.; Tsang, Chin-Fu

    2008-01-01

    storage on shallow groundwater and pressure-controlled72 5.2. Modeling of Regional Groundwater2 Geological Storage and Groundwater Resources Large-Scale

  5. On scale and magnitude of pressure build-up induced by large-scale geologic storage of CO2

    E-Print Network [OSTI]

    Zhou, Q.

    2012-01-01

    activities, such as oil production. Large-scale pressureannual volume of world oil production and the pore volumem 3 . In 2006, the world oil production was 4.3 km 3 (73.46

  6. On scale and magnitude of pressure build-up induced by large-scale geologic storage of CO2

    E-Print Network [OSTI]

    Zhou, Q.

    2012-01-01

    and Veil, 2009) US Oil Consumption Year Figure 1. Comparisonoil production and U.S. oil consumption, as well as producedGt CO 2 ) to crude oil consumption of 1.2 km 3 (7.55 billion

  7. The Potential for Increased Atmospheric CO2 Emissions and Accelerated Consumption of Deep Geologic CO2 Storage Resources Resulting from the Large-Scale Deployment of a CCS-Enabled Unconventional Fossil Fuels Industry in the U.S.

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-11-02

    Desires to enhance the energy security of the United States have spurred significant interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000-7000 MtCO2, in addition to storing potentially 900-5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000-5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000-22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result in an accelerated rate of utilization of the nation’s CO2 storage resource, leaving less high-quality storage capacity for other carbon-producing industries including electric power generation.

  8. Large-Scale Utilization of Biomass Energy and Carbon Dioxide Capture and Storage in the Transport and Electricity Sectors under Stringent CO2 Concentration Limit Scenarios

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.; Kim, Son H.

    2010-08-05

    This paper examines the potential role of large scale, dedicated commercial biomass energy systems under global climate policies designed to meet atmospheric concentrations of CO2 at 400ppm and 450ppm by the end of the century. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. A key aspect of the research presented here is that the costs of processing and transporting biomass energy at much larger scales than current experience are explicitly incorporated into the modeling. From the scenario results, 120-160 EJ/year of biomass energy is produced globally by midcentury and 200-250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the majority source, along with growing utilization of waste-to-energy. The ability to draw on a diverse set of biomass based feedstocks helps to reduce the pressure for drastic large-scale changes in land use and the attendant environmental, ecological, and economic consequences those changes would unleash. In terms of the conversion of bioenergy feedstocks into value added energy, this paper demonstrates that biomass is and will continue to be used to generate electricity as well as liquid transportation fuels. A particular focus of this paper is to show how climate policies and technology assumptions - especially the availability of carbon dioxide capture and storage (CCS) technologies - affect the decisions made about where the biomass is used in the energy system. The potential for net-negative electric sector emissions through the use of CCS with biomass feedstocks provides an attractive part of the solution for meeting stringent emissions constraints; we find that at carbon prices above 150$/tCO2, over 90% of biomass in the energy system is used in combination with CCS. Despite the higher technology costs of CCS, it is a very important tool in controlling the cost of meeting a target, offsetting the venting of CO2 from sectors of the energy system that may be more expensive to mitigate, such as oil use in transportation. CCS is also used heavily with other fuels such as coal and natural gas, and by 2095 a total of 1530 GtCO2 has been stored in deep geologic reservoirs. The paper also discusses the role of cellulosic ethanol and Fischer-Tropsch biomass derived transportation fuels as two representative conversion processes and shows that both technologies may be important contributors to liquid fuels production, with unique costs and emissions characteristics.

  9. Comparing large scale CCS deployment potential in the USA and China: a detailed analysis based on country-specific CO2 transport & storage cost curves

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Davidson, Casie L.; Dooley, James J.

    2011-04-18

    The United States and China are the two largest emitters of greenhouse gases in the world and their projected continued growth and reliance on fossil fuels, especially coal, make them strong candidates for CCS. Previous work has revealed that both nations have over 1600 large electric utility and other industrial point CO2 sources as well as very large CO2 storage resources on the order of 2,000 billion metric tons (Gt) of onshore storage capacity. In each case, the vast majority of this capacity is found in deep saline formations. In both the USA and China, candidate storage reservoirs are likely to be accessible by most sources with over 80% of these large industrial CO2 sources having a CO2 storage option within just 80 km. This suggests a strong potential for CCS deployment as a meaningful option to efforts to reduce CO2 emissions from these large, vibrant economies. However, while the USA and China possess many similarities with regards to the potential value that CCS might provide, including the range of costs at which CCS may be available to most large CO2 sources in each nation, there are a number of more subtle differences that may help us to understand the ways in which CCS deployment may differ between these two countries in order for the USA and China to work together - and in step with the rest of the world - to most efficiently reduce greenhouse gas emissions. This paper details the first ever analysis of CCS deployment costs in these two countries based on methodologically comparable CO2 source and sink inventories, economic analysis, geospatial source-sink matching and cost curve modeling. This type of analysis provides a valuable insight into the degree to which early and sustained opportunities for climate change mitigation via commercial-scale CCS are available to the two countries, and could facilitate greater collaboration in areas where those opportunities overlap.

  10. Regional Opportunities for Carbon Dioxide Capture and Storage in China: A Comprehensive CO2 Storage Cost Curve and Analysis of the Potential for Large Scale Carbon Dioxide Capture and Storage in the People’s Republic of China

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Li, Xiaochun; Davidson, Casie L.; Wei, Ning; Dooley, James J.

    2009-12-01

    This study presents data and analysis on the potential for carbon dioxide capture and storage (CCS) technologies to deploy within China, including a survey of the CO2 source fleet and potential geologic storage capacity. The results presented here indicate that there is significant potential for CCS technologies to deploy in China at a level sufficient to deliver deep, sustained and cost-effective emissions reductions for China over the course of this century.

  11. Large Scale Computing and Storage Requirements for Advanced Scientific...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Scale Computing and Storage Requirements for Advanced Scientific Computing Research: Target 2014 ASCRFrontcover.png Large Scale Computing and Storage Requirements for...

  12. Batteries for Large Scale Energy Storage

    SciTech Connect (OSTI)

    Soloveichik, Grigorii L.

    2011-07-15

    In recent years, with the deployment of renewable energy sources, advances in electrified transportation, and development in smart grids, the markets for large-scale stationary energy storage have grown rapidly. Electrochemical energy storage methods are strong candidate solutions due to their high energy density, flexibility, and scalability. This review provides an overview of mature and emerging technologies for secondary and redox flow batteries. New developments in the chemistry of secondary and flow batteries as well as regenerative fuel cells are also considered. Advantages and disadvantages of current and prospective electrochemical energy storage options are discussed. The most promising technologies in the short term are high-temperature sodium batteries with ?”-alumina electrolyte, lithium-ion batteries, and flow batteries. Regenerative fuel cells and lithium metal batteries with high energy density require further research to become practical.

  13. The Promise Of Data Grouping In Large Scale Storage Systems

    E-Print Network [OSTI]

    Wildani, Avani

    2013-01-01

    Martin. Why traditional storage systems donâ??t help us saveB. Dufrasne et al. IBM XIV Storage System Gen3 Architecture,in large scale storage systems. In Proceedings of the 11th

  14. Biomass Energy for Transport and Electricity: Large scale utilization under low CO2 concentration scenarios

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.; Kim, Son H.

    2010-01-25

    This paper examines the potential role of large scale, dedicated commercial biomass energy systems under global climate policies designed to stabilize atmospheric concentrations of CO2 at 400ppm and 450ppm. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. The costs of processing and transporting biomass energy at much larger scales than current experience are also incorporated into the modeling. From the scenario results, 120-160 EJ/year of biomass energy is produced by midcentury and 200-250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the dominant source. A key finding of this paper is the role that carbon dioxide capture and storage (CCS) technologies coupled with commercial biomass energy can play in meeting stringent emissions targets. Despite the higher technology costs of CCS, the resulting negative emissions used in combination with biomass are a very important tool in controlling the cost of meeting a target, offsetting the venting of CO2 from sectors of the energy system that may be more expensive to mitigate, such as oil use in transportation. The paper also discusses the role of cellulosic ethanol and Fischer-Tropsch biomass derived transportation fuels and shows that both technologies are important contributors to liquid fuels production, with unique costs and emissions characteristics. Through application of the GCAM integrated assessment model, it becomes clear that, given CCS availability, bioenergy will be used both in electricity and transportation.

  15. Geomechanical effects on CO2 leakage through fault zones during large-scale underground injection

    E-Print Network [OSTI]

    Rinaldi, A.P.

    2014-01-01

    Rutqvist, J. , 2012. The Geomechanics of CO 2 Storage in2001. Fully coupled geomechanics and fluid-flow analysis ofUS Rock Mechanics, Geomechanics Symposium. San Francisco, 23

  16. Large Scale Energy Storage: From Nanomaterials to Large Systems

    E-Print Network [OSTI]

    Fisher, Frank

    Large Scale Energy Storage: From Nanomaterials to Large Systems Wednesday October 26, 2011, Babbio energy storage devices. Specifically, this talk discusses 1) the challenges for grid scale of emergent technologies with ultralow costs on new energy storage materials and mechanisms. Dr. Jun Liu

  17. Legal Implications of CO2 Ocean Storage

    E-Print Network [OSTI]

    Legal Implications of CO2 Ocean Storage Jason Heinrich Working Paper Laboratory for Energy the deployment of CO2 storage technologies used in the marine environment. This paper will address some of the legal issues involved in ocean storage of carbon dioxide from a US perspective. The following paragraphs

  18. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    WITH SITE SCREENING AND SELECTION FOR CO 2 STORAGE D. A.77 ASSESSING AND EXPANDING CO 2 STORAGE CAPACITY IN DEPLETEDFOR CO 2 GEOLOGICAL STORAGE IN CENTRAL COAL BASIN (NORTHERN

  19. Carbon Storage Partner Completes First Year of CO2 Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Storage Partner Completes First Year of CO2 Injection Operations in Illinois Carbon Storage Partner Completes First Year of CO2 Injection Operations in Illinois November 19,...

  20. Fluid flow and CO2fluidmineral interactions during CO2-storage in sedimentary basins

    E-Print Network [OSTI]

    Cambridge, University of

    mineral dissolution rates. Observations from CO2-EOR exper- iments and natural analogues suggestFluid flow and CO2­fluid­mineral interactions during CO2-storage in sedimentary basins Niko Kampman Natural CO2 analogues Modelling the progress of geochemical processes in CO2 storage sites is frustrated

  1. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage

    E-Print Network [OSTI]

    Wang, Wei Hua

    Room-temperature stationary sodium-ion batteries for large-scale electric energy storage Huilin Pan attention particularly in large- scale electric energy storage applications for renewable energy and smart, such as the wind and the sun, large-scale electric energy storage systems are becoming extremely important

  2. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    20-22, 2006 End of CO2 injection Fraction Variation 5E-05 -point. End of CO2 injection Fraction Variation Figure 3.poin Y (m (m X End of CO2 storage Fraction Variation Y (m (m

  3. System-level modeling for geological storage of CO2

    E-Print Network [OSTI]

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01

    of Geologic Storage of CO2, in Carbon Dioxide Capture forFormations - Results from the CO2 Capture Project: GeologicBenson, Process Modeling of CO2 Injection into Natural Gas

  4. Membraneless hydrogen bromine laminar flow battery for large-scale energy storage

    E-Print Network [OSTI]

    Braff, William Allan

    2014-01-01

    Electrochemical energy storage systems have been considered for a range of potential large-scale energy storage applications. These applications vary widely, both in the order of magnitude of energy storage that is required ...

  5. AMP: An Affinity-based Metadata Prefetching Scheme in Large-Scale Distributed Storage Systems

    E-Print Network [OSTI]

    Zhu, Yifeng

    1 AMP: An Affinity-based Metadata Prefetching Scheme in Large-Scale Distributed Storage Systems Lin significantly reduce access latency for I/O systems. In distributed storage systems, prefetching for metadata Prefetching (AMP) scheme is proposed for metadata servers in large-scale distributed storage systems

  6. An Energy-Efficient Framework for Large-Scale Parallel Storage Systems

    E-Print Network [OSTI]

    Qin, Xiao

    An Energy-Efficient Framework for Large-Scale Parallel Storage Systems Ziliang Zong, Matt Briggs-scale and energy-efficient parallel storage systems. To validate the efficiency of the proposed framework, a buffer that this new framework can significantly improves the energy efficiency of large-scale parallel storage systems

  7. Large Scale Computing and Storage Requirements for High Energy Physics

    E-Print Network [OSTI]

    Gerber, Richard A.

    2011-01-01

    Journal of Computational Physics, Large Scale Computing andRequirements for High Energy Physics [3] A. S. Almgren, J.Journal of Computational Physics, 87:171–200, 1990. [7] G.

  8. The geomechanics of CO2 storage in deep sedimentary formations

    E-Print Network [OSTI]

    Rutqvist, J.

    2013-01-01

    implications for CO 2 storage risk. Energy Procedia 4:3699–storage events and putting risk into perspective with other areas of the energy

  9. On Leakage from Geologic Storage Reservoirs of CO2

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-02-14

    Large amounts of CO2 would need to be injected underground to achieve a significant reduction of atmospheric emissions. The large areal extent expected for CO2 plumes makes it likely that caprock imperfections will be encountered, such as fault zones or fractures, which may allow some CO2 to escape from the primary storage reservoir. Leakage of CO2 could also occur along wellbores. Concerns with escape of CO2 from a primary geologic storage reservoir include (1) acidification of groundwater resources, (2) asphyxiation hazard when leaking CO2 is discharged at the land surface, (3) increase in atmospheric concentrations of CO2, and (4) damage from a high-energy, eruptive discharge (if such discharge is physically possible). In order to gain public acceptance for geologic storage as a viable technology for reducing atmospheric emissions of CO2, it is necessary to address these issues and demonstrate that CO2 can be injected and stored safely in geologic formations.

  10. Large Scale Computing and Storage Requirements for Nuclear Physics Research

    E-Print Network [OSTI]

    Gerber, Richard A.

    2012-01-01

    Requirements for Nuclear Physics [10] Hammer, N. J. , Janka,and Storage Requirements for Nuclear Physics ResearchIntegration of ab initio nuclear physics calculations with

  11. Large Scale Computing and Storage Requirements for Nuclear Physics Research

    E-Print Network [OSTI]

    Gerber, Richard A.

    2012-01-01

    Requirements for Nuclear Physics [10] Hammer, N. J. , Janka,and Storage Requirements for Nuclear Physics Researchof ab initio nuclear physics calculations with optimization

  12. The geomechanics of CO2 storage in deep sedimentary formations

    E-Print Network [OSTI]

    Rutqvist, J.

    2013-01-01

    The geomechanics of CO 2 storage in deep sedimentaryThis paper provides a review of the geomechanics andmodeling of geomechanics associated with geologic carbon

  13. Evaluating a new approach to CO2 capture and storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 capture and storage In a perspective paper published in Greenhouse Gases: Science and Technology, researchers examined a new approach that could potentially overcome many...

  14. Electrochemical cells for medium- and large-scale energy storage

    SciTech Connect (OSTI)

    Wang, Wei; Wei, Xiaoliang; Choi, Daiwon; Lu, Xiaochuan; Yang, G.; Sun, C.

    2014-12-12

    This is one of the chapters in the book titled “Advances in batteries for large- and medium-scale energy storage: Applications in power systems and electric vehicles” that will be published by the Woodhead Publishing Limited. The chapter discusses the basic electrochemical fundamentals of electrochemical energy storage devices with a focus on the rechargeable batteries. Several practical secondary battery systems are also discussed as examples

  15. Large Scale Distribution of Stochastic Control Algorithms for Gas Storage Constantinos Makassikis, Stephane Vialle

    E-Print Network [OSTI]

    Vialle, Stéphane

    Large Scale Distribution of Stochastic Control Algorithms for Gas Storage Valuation Constantinos algorithm which is applied to gas storage valuation, and presents its experimental performances on two PC distribution allows to run gas storage val- uation models which require considerable amounts of com- putational

  16. Large Scale Computing and Storage Requirements for Nuclear Physics Research

    SciTech Connect (OSTI)

    Gerber, Richard A.; Wasserman, Harvey J.

    2012-03-02

    IThe National Energy Research Scientific Computing Center (NERSC) is the primary computing center for the DOE Office of Science, serving approximately 4,000 users and hosting some 550 projects that involve nearly 700 codes for a wide variety of scientific disciplines. In addition to large-scale computing resources NERSC provides critical staff support and expertise to help scientists make the most efficient use of these resources to advance the scientific mission of the Office of Science. In May 2011, NERSC, DOE’s Office of Advanced Scientific Computing Research (ASCR) and DOE’s Office of Nuclear Physics (NP) held a workshop to characterize HPC requirements for NP research over the next three to five years. The effort is part of NERSC’s continuing involvement in anticipating future user needs and deploying necessary resources to meet these demands. The workshop revealed several key requirements, in addition to achieving its goal of characterizing NP computing. The key requirements include: 1. Larger allocations of computational resources at NERSC; 2. Visualization and analytics support; and 3. Support at NERSC for the unique needs of experimental nuclear physicists. This report expands upon these key points and adds others. The results are based upon representative samples, called “case studies,” of the needs of science teams within NP. The case studies were prepared by NP workshop participants and contain a summary of science goals, methods of solution, current and future computing requirements, and special software and support needs. Participants were also asked to describe their strategy for computing in the highly parallel, “multi-core” environment that is expected to dominate HPC architectures over the next few years. The report also includes a section with NERSC responses to the workshop findings. NERSC has many initiatives already underway that address key workshop findings and all of the action items are aligned with NERSC strategic plans.

  17. A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage

    E-Print Network [OSTI]

    Cui, Yi

    A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage Yuan Yang,a Guangyuan Zhengb and Yi Cui*ac Large-scale energy storage represents a key challenge for renewable energy develop a new lithium/ polysulfide (Li/PS) semi-liquid battery for large-scale energy storage

  18. Large Scale Computing and Storage Requirements for High Energy Physics

    SciTech Connect (OSTI)

    Gerber, Richard A.; Wasserman, Harvey

    2010-11-24

    The National Energy Research Scientific Computing Center (NERSC) is the leading scientific computing facility for the Department of Energy's Office of Science, providing high-performance computing (HPC) resources to more than 3,000 researchers working on about 400 projects. NERSC provides large-scale computing resources and, crucially, the support and expertise needed for scientists to make effective use of them. In November 2009, NERSC, DOE's Office of Advanced Scientific Computing Research (ASCR), and DOE's Office of High Energy Physics (HEP) held a workshop to characterize the HPC resources needed at NERSC to support HEP research through the next three to five years. The effort is part of NERSC's legacy of anticipating users needs and deploying resources to meet those demands. The workshop revealed several key points, in addition to achieving its goal of collecting and characterizing computing requirements. The chief findings: (1) Science teams need access to a significant increase in computational resources to meet their research goals; (2) Research teams need to be able to read, write, transfer, store online, archive, analyze, and share huge volumes of data; (3) Science teams need guidance and support to implement their codes on future architectures; and (4) Projects need predictable, rapid turnaround of their computational jobs to meet mission-critical time constraints. This report expands upon these key points and includes others. It also presents a number of case studies as representative of the research conducted within HEP. Workshop participants were asked to codify their requirements in this case study format, summarizing their science goals, methods of solution, current and three-to-five year computing requirements, and software and support needs. Participants were also asked to describe their strategy for computing in the highly parallel, multi-core environment that is expected to dominate HPC architectures over the next few years. The report includes a section that describes efforts already underway or planned at NERSC that address requirements collected at the workshop. NERSC has many initiatives in progress that address key workshop findings and are aligned with NERSC's strategic plans.

  19. Membraneless Hydrogen Bromine Laminar Flow Battery for Large-Scale Energy Storage

    E-Print Network [OSTI]

    Poonen, Bjorn

    Membraneless Hydrogen Bromine Laminar Flow Battery for Large-Scale Energy Storage by William Allan and examined for its potential to provide low cost energy storage using the rapid reaction kinetics of hydrogen by . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . David E. Hardt Chairman, Department Committee on Graduate Theses #12;2 #12;Membraneless Hydrogen Bromine

  20. INORGANIC NANOPARTICLES AS PHASE-CHANGE MATERIALS FOR LARGE-SCALE THERMAL ENERGY STORAGE

    E-Print Network [OSTI]

    Pennycook, Steve

    INORGANIC NANOPARTICLES AS PHASE-CHANGE MATERIALS FOR LARGE- SCALE THERMAL ENERGY STORAGE Miroslaw storage performance. The expected immediate outcome of this effort is the demonstration of high-energy generation at high efficiency could revolutionize the development of solar energy. Nanoparticle-based phase

  1. BUILDING A CO2 STORAGE HUB IN

    E-Print Network [OSTI]

    Painter, Kevin

    , once at the forefront of this innovative technology that can give us clean energy from abundant fossil technology we have in the battle to reduce CO2 emissions from power and industrial sources. Without it we and global reliance on low-cost energy from coal and gas shows no sign of diminishing, the time has come

  2. DOE Manual Studies 11 Major CO2 Geologic Storage Formations

    Broader source: Energy.gov [DOE]

    A comprehensive study of 11 geologic formations suitable for permanent underground carbon dioxide (CO2) storage is contained in a new manual issued by the U.S. Department of Energy.

  3. Day-Ahead and Real-Time Models for Large-Scale Energy Storage

    E-Print Network [OSTI]

    Engineering Research Center Empowering Minds to Engineer the Future Electric Energy System #12;DayDay-Ahead and Real-Time Models for Large-Scale Energy Storage Final Project Report Power Systems of Electrical, Computer, and Energy Engineering P.O. BOX 875706 Tempe, AZ 85287-5706 Phone: 480 965-1276 Fax

  4. NETL CO2 Storage Frequently Asked Questions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStressMoveMuncriefB NESEA Newsletter ContentCO2

  5. Early opportunities of CO2 geological storage deployment in coal chemical industry in China

    SciTech Connect (OSTI)

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, Robert T.; Davidson, Casie L.

    2014-11-12

    Abstract: Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO2 emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO2 sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation or in late planning stages. These emission sources together emit 430 million tons CO2 per year, of which about 30% are emit high-purity and pure CO2 (CO2 concentration >80% and >99% respectively).Four typical source-sink pairs are studied by a techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and experienced economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO2 capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO2. When a 15USD/t CO2 tax and 15USD/t for CO2 sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a net economic benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.

  6. Early Opportunities of CO2 Geological Storage Deployment in Coal Chemical Industry in China

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, R.T.; Davidson, C.L.

    2014-12-31

    Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO2 emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO2 sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation. These emission sources together emit 430 million tons CO2more »per year, of which about 30% are emit high-purity and pure CO2 (CO2 concentration >80% and >98.5% respectively). Four typical source-sink pairs are chosen for techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO2 capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO2. When a 15USD/t CO2 tax and 20USD/t for CO2 sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.« less

  7. Materials Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid

    SciTech Connect (OSTI)

    Liu, Jun; Zhang, Jiguang; Yang, Zhenguo; Lemmon, John P.; Imhoff, Carl H.; Graff, Gordon L.; Li, Liyu; Hu, Jian Z.; Wang, Chong M.; Xiao, Jie; Xia, Guanguang; Viswanathan, Vilayanur V.; Baskaran, Suresh; Sprenkle, Vincent L.; Li, Xiaolin; Shao, Yuyan; Schwenzer, Birgit

    2013-02-15

    Large-scale electrical energy storage has become more important than ever for reducing fossil energy consumption in transportation and for the widespread deployment of intermittent renewable energy in electric grid. However, significant challenges exist for its applications. Here, the status and challenges are reviewed from the perspective of materials science and materials chemistry in electrochemical energy storage technologies, such as Li-ion batteries, sodium (sulfur and metal halide) batteries, Pb-acid battery, redox flow batteries, and supercapacitors. Perspectives and approaches are introduced for emerging battery designs and new chemistry combinations to reduce the cost of energy storage devices.

  8. On CO2 Behavior in the Subsurface, Following Leakage from a Geologic Storage Reservoir

    E-Print Network [OSTI]

    Pruess, Karsten

    2006-01-01

    1 - 16, 1987. Skinner, L. CO2 Blowouts: An Emerging Problem,Assessment for Underground CO2 Storage, paper 234, presentedReservoir Performance Risk in CO2 Storage Projects, paper

  9. A Framework for Environmental Assessment of CO2 Capture and Storage Systems

    E-Print Network [OSTI]

    Sathre, Roger

    2013-01-01

    OF  CO2  CAPTURE  AND  STORAGE   SYSTEMS   Roger  Sathre,  2  Capture  and  Storage  Systems   Roger Sathre 1 , Mikhail

  10. SUBTASK 2.19 – OPERATIONAL FLEXIBILITY OF CO2 TRANSPORT AND STORAGE

    SciTech Connect (OSTI)

    Jensen, Melanie; Schlasner, Steven; Sorensen, James; Hamling, John

    2014-12-31

    Carbon dioxide (CO2) is produced in large quantities during electricity generation and by industrial processes. These CO2 streams vary in terms of both composition and mass flow rate, sometimes substantially. The impact of a varying CO2 stream on pipeline and storage operation is not fully understood in terms of either operability or infrastructure robustness. This study was performed to summarize basic background from the literature on the topic of operational flexibility of CO2 transport and storage, but the primary focus was on compiling real-world lessons learned about flexible operation of CO2 pipelines and storage from both large-scale field demonstrations and commercial operating experience. Modeling and pilot-scale results of research in this area were included to illustrate some of the questions that exist relative to operation of carbon capture and storage (CCS) projects with variable CO2 streams. It is hoped that this report’s real-world findings provide readers with useful information on the topic of transport and storage of variable CO2 streams. The real-world results were obtained from two sources. The first source consisted of five full-scale, commercial transport–storage projects: Sleipner, Snøhvit, In Salah, Weyburn, and Illinois Basin–Decatur. These scenarios were reviewed to determine the information that is available about CO2 stream variability/intermittency on these demonstration-scale projects. The five projects all experienced mass flow variability or an interruption in flow. In each case, pipeline and/or injection engineers were able to accommodate any issues that arose. Significant variability in composition has not been an issue at these five sites. The second source of real- world results was telephone interviews conducted with experts in CO2 pipeline transport, injection, and storage during which commercial anecdotal information was acquired to augment that found during the literature search of the five full-scale projects. The experts represented a range of disciplines and hailed from North America and Europe. Major findings of the study are that compression and transport of CO2 for enhanced oil recovery (EOR) purposes in the United States has shown that impurities are not likely to cause transport problems if CO2 stream composition standards are maintained and pressures are kept at 10.3 MPa or higher. Cyclic, or otherwise intermittent, CO2 supplies historically have not impacted in-field distribution pipeline networks, wellbore integrity, or reservoir conditions. The U.S. EOR industry has demonstrated that it is possible to adapt to variability and intermittency in CO2 supply through flexible operation of the pipeline and geologic storage facility. This CO2 transport and injection experience represents knowledge that can be applied in future CCS projects. A number of gaps in knowledge were identified that may benefit from future research and development, further enhancing the possibility for widespread application of CCS. This project was funded through the Energy & Environmental Research Center–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the IEA Greenhouse Gas R&D Programme.

  11. CO2 Storage and Sink Enhancements: Developing Comparable Economics

    E-Print Network [OSTI]

    capital, engineering and home office overhead, project and process contingencies, and miscellaneousCO2 Storage and Sink Enhancements: Developing Comparable Economics B.R. Bock1 , R.G. Rhudy2 , and H Research Institute, Palo Alto, CA, USA 3 Laboratory for Energy and the Environment, Massachusetts Institute

  12. INFLUENCE OF CAPILLARY PRESSURE ON CO2 STORAGE AND MONITORING

    E-Print Network [OSTI]

    Santos, Juan

    - 0.3 sin 1 - 0.5 sin : pore pressure : critical porosity 0: initial porosity : bulk INFLUENCE OF CAPILLARY PRESSURE ON CO2 STORAGE AND MONITORING Juan E. Santos Work in collaboration and capillary pressure relations) are determined from on-site resistivity measurements. In particular we

  13. Modeling long-term CO2 storage, sequestration and cycling

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-11-11

    The application of numerical and analytical models to the problem of storage, sequestration and migration of carbon dioxide in geologic formations is discussed. A review of numerical and analytical models that have been applied to CO2 sequestration are presented, as well as a description of frameworks for risk analysis. Application of models to various issues related to carbon sequestration are discussed, including trapping mechanisms, density convection mixing, impurities in the CO2 stream, changes in formation porosity and permeability, the risk of vertical leakage, and the impacts on groundwater resources if leakage does occur. A discussion of the development and application of site-specific models first addresses the estimation of model parameters and the use of natural analogues to inform the development of CO2 sequestration models, and then surveys modeling that has been done at two commercial-scale CO2 sequestration sites, Sleipner and In Salah, along with a pilot-scale injection sites used to study CO2 sequestration in saline aquifers (Frio) and an experimental site designed to test monitoring of CO2 leakage in the vadose zone (ZERT Release Facility).

  14. Mathematical models as tools for probing long-term safety of CO2 storage

    E-Print Network [OSTI]

    Pruess, Karsten

    2010-01-01

    for CO2 geological storage, Int. J. Greenhouse Gas Control,1008, DOI Bachu, S. CO2 Storage in Geological Media: Role,R.H. Worden. Geological Storage of Carbon Dioxide, in: S.J.

  15. Survey and analysis of selected jointly owned large-scale electric utility storage projects

    SciTech Connect (OSTI)

    Not Available

    1982-05-01

    The objective of this study was to examine and document the issues surrounding the curtailment in commercialization of large-scale electric storage projects. It was sensed that if these issues could be uncovered, then efforts might be directed toward clearing away these barriers and allowing these technologies to penetrate the market to their maximum potential. Joint-ownership of these projects was seen as a possible solution to overcoming the major barriers, particularly economic barriers, of commercializaton. Therefore, discussions with partners involved in four pumped storage projects took place to identify the difficulties and advantages of joint-ownership agreements. The four plants surveyed included Yards Creek (Public Service Electric and Gas and Jersey Central Power and Light); Seneca (Pennsylvania Electric and Cleveland Electric Illuminating Company); Ludington (Consumers Power and Detroit Edison, and Bath County (Virginia Electric Power Company and Allegheny Power System, Inc.). Also investigated were several pumped storage projects which were never completed. These included Blue Ridge (American Electric Power); Cornwall (Consolidated Edison); Davis (Allegheny Power System, Inc.) and Kttatiny Mountain (General Public Utilities). Institutional, regulatory, technical, environmental, economic, and special issues at each project were investgated, and the conclusions relative to each issue are presented. The major barriers preventing the growth of energy storage are the high cost of these systems in times of extremely high cost of capital, diminishing load growth and regulatory influences which will not allow the building of large-scale storage systems due to environmental objections or other reasons. However, the future for energy storage looks viable despite difficult economic times for the utility industry. Joint-ownership can ease some of the economic hardships for utilites which demonstrate a need for energy storage.

  16. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01

    E EPM2- TIP4P2005 PPL- TIP4P2005 Predicted (f) a P ? CO2 2SE? CO2 2SE? CO2 2SE ? CO2 2SE ? CO2 2SE ? CO2 2SE a Surface excess CO

  17. Jumpstarting commercial-scale CO2 capture and storage with ethylene production and enhanced oil recovery in the US Gulf

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Middleton, Richard S.; Levine, Jonathan S.; Bielicki, Jeffrey M.; Viswanathan, Hari S.; Carey, J. William; Stauffer, Philip H.

    2015-04-27

    CO2 capture, utilization, and storage (CCUS) technology has yet to be widely deployed at a commercial scale despite multiple high-profile demonstration projects. We suggest that developing a large-scale, visible, and financially viable CCUS network could potentially overcome many barriers to deployment and jumpstart commercial-scale CCUS. To date, substantial effort has focused on technology development to reduce the costs of CO2 capture from coal-fired power plants. Here, we propose that near-term investment could focus on implementing CO2 capture on facilities that produce high-value chemicals/products. These facilities can absorb the expected impact of the marginal increase in the cost of production onmore »the price of their product, due to the addition of CO2 capture, more than coal-fired power plants. A financially viable demonstration of a large-scale CCUS network requires offsetting the costs of CO2 capture by using the CO2 as an input to the production of market-viable products. As a result, we demonstrate this alternative development path with the example of an integrated CCUS system where CO2 is captured from ethylene producers and used for enhanced oil recovery in the U.S. Gulf Coast region.« less

  18. Leakage of CO2 from geologic storage: Role of secondary accumulation at shallow depth

    E-Print Network [OSTI]

    Pruess, K.

    2008-01-01

    Large Releases from CO2 Storage Reservoirs: Analogs,S.T. Nelson. Natural Leaking CO2-charged Systems as AnalogsY. Sano, and H.U. Schmincke. CO2-rich Gases from Lakes Nyos

  19. The value of electricity storage under large-scale penetration of renewable energy : a hybrid modeling approach

    E-Print Network [OSTI]

    Octaviano Villasana, Claudia Alejandra

    2015-01-01

    Due to the physics of electricity, and the current high costs of storage technologies, electricity generation and demand need to be instantaneously balanced at all times. The large-scale deployment of intermittent renewables ...

  20. Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.

    2008-11-18

    This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However, additional analyses plus detailed regional and site characterization is needed, along with a closer examination of competing storage demands.

  1. First U.S. Large-Scale CO2 Storage Project Advances | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive Order14,EnergyFinancingWIPP |Department of EnergyFirst

  2. Evaluating the Suitability for CO2 Storage at the FutureGen 2.0 Site, Morgan County, Illinois, USA

    SciTech Connect (OSTI)

    Bonneville, Alain; Gilmore, Tyler J.; Sullivan, E. C.; Vermeul, Vincent R.; Kelley, Mark E.; White, Signe K.; Appriou, Delphine; Bjornstad, Bruce N.; Gerst, Jacqueline L.; Gupta, Neeraj; Horner, Jacob A.; McNeil, Caitlin; Moody, Mark A.; Rike, William M.; Spane, Frank A.; Thorne, Paul D.; Zeller, Evan R.; Zhang, Z. F.; Hoffman, Jeffrey; Humphreys, Kenneth K.

    2013-08-05

    FutureGen 2.0 site will be the first near-zero emission power plant with fully integrated long-term storage in a deep, non-potable saline aquifer in the United States. The proposed FutureGen 2.0 CO2 storage site is located in northeast Morgan County, Illinois, U.S.A., forty-eight kilometres from the Meredosia Energy Center where a large-scale oxy-combustion demonstration will be conducted. The demonstration will involve > 90% carbon capture, which will produce more than one million metric tons (MMT) of CO2 per year. The CO2 will be compressed at the power plant and transported via pipeline to the storage site. To examine CO2 storage potential of the site, a 1,467m characterization well (FGA#1) was completed in December 2011. The target reservoir for CO2 storage is the Mt. Simon Sandstone and Elmhurst Sandstone Member of the lower Eau Claire Formation for a combined thickness of 176 m. Confining beds of the overlying Lombard and Proviso Members (upper Eau Claire Formation) reach a thickness of 126 m. Characterization of the target injection zone and the overlying confining zone was based on wellbore data, cores, and geophysical logs, along with surface geophysical (2-D seismic profiles, magnetic and gravity), and structural data collected during the initial stage of the project . Based on this geological model, 3D simulations of CO2 injection and redistribution were conducted using STOMP-CO2, a multiphase flow and transport simulator. After this characterization stage, it appears that the injection site is a suitable geologic system for CO2 sequestration and that the injection zone is sufficient to receive up to 33 MMT of CO2 at a rate of 1.1 MMT/yr. GHGT-11 conference

  3. A Report on Simulation-Driven Reliability and Failure Analysis of Large-Scale Storage Systems

    SciTech Connect (OSTI)

    Wan, Lipeng; Wang, Feiyi; Oral, H. Sarp; Vazhkudai, Sudharshan S.; Cao, Qing

    2014-11-01

    High-performance computing (HPC) storage systems provide data availability and reliability using various hardware and software fault tolerance techniques. Usually, reliability and availability are calculated at the subsystem or component level using limited metrics such as, mean time to failure (MTTF) or mean time to data loss (MTTDL). This often means settling on simple and disconnected failure models (such as exponential failure rate) to achieve tractable and close-formed solutions. However, such models have been shown to be insufficient in assessing end-to-end storage system reliability and availability. We propose a generic simulation framework aimed at analyzing the reliability and availability of storage systems at scale, and investigating what-if scenarios. The framework is designed for an end-to-end storage system, accommodating the various components and subsystems, their interconnections, failure patterns and propagation, and performs dependency analysis to capture a wide-range of failure cases. We evaluate the framework against a large-scale storage system that is in production and analyze its failure projections toward and beyond the end of lifecycle. We also examine the potential operational impact by studying how different types of components affect the overall system reliability and availability, and present the preliminary results

  4. DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage...

    Energy Savers [EERE]

    DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage Site DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage Site June 3, 2015 - 8:44am Addthis Photo...

  5. Carbon Dioxide (CO2) Capture Project Phase 2 (CCP2) - Storage...

    Open Energy Info (EERE)

    Carbon Dioxide (CO2) Capture Project Phase 2 (CCP2) - Storage Program: Closing Long-Term CO2 Geological Storage Gaps Relevant to Regulatory and Policy Development Jump to:...

  6. Large Releases from CO2 Storage Reservoirs: A Discussion of Natural Analogs, FEPS, and Modeling Needs

    E-Print Network [OSTI]

    Birkholzer, J.; Pruess, K.; Lewicki, J.L.; Rutqvist, J.; Tsang, C-F.; Karimjee, A.

    2008-01-01

    migration away from the primary storage reservoir, towards shallow depthsextend from depth to surface. During upward migration, CO 2

  7. Large releases from CO2 storage reservoirs: Analogs, scenarios, and modeling needs

    E-Print Network [OSTI]

    Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Rutqvist, Jonny; Tsang, Chin-Fu; Karimjee, Anhar

    2006-01-01

    migration away from the primary storage reservoir, towards shallow depthsextend from depth to surface. During upward migration, CO 2

  8. Technical and economical aspects of large-scale CO{sub 2} storage in deep oceans

    SciTech Connect (OSTI)

    Sarv, H.; John, J.

    2000-07-01

    The authors examined the technical and economical feasibility of two options for large-scale transportation and ocean sequestration of captured CO{sub 2} at depths of 3000 meters or greater. In one case, CO{sub 2} was pumped from a land-based collection center through six parallel-laid subsea pipelines. Another case considered oceanic tanker transport of liquid carbon dioxide to an offshore floating platform or a barge for vertical injection through a large-diameter pipe to the ocean floor. Based on the preliminary technical and economic analyses, tanker transportation and offshore injection through a large-diameter, 3,000-meter vertical pipeline from a floating structure appears to be the best method for delivering liquid CO{sub 2} to deep ocean floor depressions for distances greater than 400 km. Other benefits of offshore injection are high payload capability and ease of relocation. For shorter distances (less than 400 km), CO{sub 2} delivery by subsea pipelines is more cost-effective. Estimated costs for 500-km transport and storage at a depth of 3000 meters by subsea pipelines or tankers were under 2 dollars per ton of stored CO{sub 2}. Their analyses also indicates that large-scale sequestration of captured CO{sub 2} in oceans is technologically feasible and has many commonalities with other strategies for deepsea natural gas and oil exploration installations.

  9. Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2 from flue gases Jens Kohlmann 1 University of Technology was "Mineral carbonation for long-term storage of CO2 from flue gases"; the progress storage by mineral carbonation in Finland (CO2 lagring genom mineral karbonering i Finland)" Ron

  10. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Could Sequestration of CO2 be Combined with the DevelopmentTOUGH2 Code for Studies of CO2 Storage in Saline Aquifers,and J. Ennis- King. CO2-H2O Mixtures in the Geological

  11. International Symposium on Site Characterization for CO2Geological Storage

    SciTech Connect (OSTI)

    Tsang, Chin-Fu

    2006-02-23

    Several technological options have been proposed to stabilize atmospheric concentrations of CO{sub 2}. One proposed remedy is to separate and capture CO{sub 2} from fossil-fuel power plants and other stationary industrial sources and to inject the CO{sub 2} into deep subsurface formations for long-term storage and sequestration. Characterization of geologic formations for sequestration of large quantities of CO{sub 2} needs to be carefully considered to ensure that sites are suitable for long-term storage and that there will be no adverse impacts to human health or the environment. The Intergovernmental Panel on Climate Change (IPCC) Special Report on Carbon Dioxide Capture and Storage (Final Draft, October 2005) states that ''Site characterization, selection and performance prediction are crucial for successful geological storage. Before selecting a site, the geological setting must be characterized to determine if the overlying cap rock will provide an effective seal, if there is a sufficiently voluminous and permeable storage formation, and whether any abandoned or active wells will compromise the integrity of the seal. Moreover, the availability of good site characterization data is critical for the reliability of models''. This International Symposium on Site Characterization for CO{sub 2} Geological Storage (CO2SC) addresses the particular issue of site characterization and site selection related to the geologic storage of carbon dioxide. Presentations and discussions cover the various aspects associated with characterization and selection of potential CO{sub 2} storage sites, with emphasis on advances in process understanding, development of measurement methods, identification of key site features and parameters, site characterization strategies, and case studies.

  12. Sustainable Carbon Sequestration: Increasing CO2-Storage Efficiency through a CO2-Brine Displacement Approach 

    E-Print Network [OSTI]

    Akinnikawe, Oyewande

    2012-10-19

    CO2 sequestration is one of the proposed methods for reducing anthropogenic CO2 emissions to the atmosphere and therefore mitigating global climate change. Few studies on storing CO2 in an aquifer have been conducted on a regional scale. This study...

  13. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    of the buoyancy of supercritical CO2 in the presence ofindividual pock- ets of supercritical CO2 to form, therebydomain. Injection of supercritical CO2 occurs at a depth of

  14. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    CONSTRAIN CO2 INJECTION FEASIBILITY: TEAPOT DOME EOR PILOTEOR, and coupled process modeling will investigate the total system including preliminary estimates of CO2

  15. Biases of CO2 Storage in Eddy Flux Measurements pertinent to...

    Office of Scientific and Technical Information (OSTI)

    Biases of CO2 Storage in Eddy Flux Measurements pertinent to Vertical Configurations of a Profile System and CO2 Density Averaging Citation Details In-Document Search Title: Biases...

  16. Power-Saving in Large-Scale Storage Systems with Data Migration Koji Hasebe, Tatsuya Niwa, Akiyoshi Sugiki, and Kazuhiko Kato

    E-Print Network [OSTI]

    Banbara, Mutsunori

    Power-Saving in Large-Scale Storage Systems with Data Migration Koji Hasebe, Tatsuya Niwa, Akiyoshi,kato}@cs.tsukuba.ac.jp Abstract--We present a power-saving method for large- scale distributed storage systems. The key idea. In particular, as a high percentage of the total computing system's energy is used by the data storage systems

  17. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    phase dispersivity test (BTC) Porosity-thickness product oftest Two-phase tracer BTC Evolution of CO 2 saturation

  18. Microsoft Word - NETL-TRS-4-2014_CO2 Storage and Enhanced Gas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigation of CO 2 Storage and Enhanced Gas Recovery in Depleted Shale Gas Formations Using a Dual- PorosityDual-Permeability, Multiphase Reservoir Simulator 25 September 2014...

  19. ARRA-Multi-Level Energy Storage and Controls for Large-Scale Wind Energy Integration

    SciTech Connect (OSTI)

    David Wenzhong Gao

    2012-09-30

    The Project Objective is to design innovative energy storage architecture and associated controls for high wind penetration to increase reliability and market acceptance of wind power. The project goals are to facilitate wind energy integration at different levels by design and control of suitable energy storage systems. The three levels of wind power system are: Balancing Control Center level, Wind Power Plant level, and Wind Power Generator level. Our scopes are to smooth the wind power fluctuation and also ensure adequate battery life. In the new hybrid energy storage system (HESS) design for wind power generation application, the boundary levels of the state of charge of the battery and that of the supercapacitor are used in the control strategy. In the controller, some logic gates are also used to control the operating time durations of the battery. The sizing method is based on the average fluctuation of wind profiles of a specific wind station. The calculated battery size is dependent on the size of the supercapacitor, state of charge of the supercapacitor and battery wear. To accommodate the wind power fluctuation, a hybrid energy storage system (HESS) consisting of battery energy system (BESS) and super-capacitor is adopted in this project. A probability-based power capacity specification approach for the BESS and super-capacitors is proposed. Through this method the capacities of BESS and super-capacitor are properly designed to combine the characteristics of high energy density of BESS and the characteristics of high power density of super-capacitor. It turns out that the super-capacitor within HESS deals with the high power fluctuations, which contributes to the extension of BESS lifetime, and the super-capacitor can handle the peaks in wind power fluctuations without the severe penalty of round trip losses associated with a BESS. The proposed approach has been verified based on the real wind data from an existing wind power plant in Iowa. An intelligent controller that increases battery life within hybrid energy storage systems for wind application was developed. Comprehensive studies have been conducted and simulation results are analyzed. A permanent magnet synchronous generator, coupled with a variable speed wind turbine, is connected to a power grid (14-bus system). A rectifier, a DC-DC converter and an inverter are used to provide a complete model of the wind system. An Energy Storage System (ESS) is connected to a DC-link through a DC-DC converter. An intelligent controller is applied to the DC-DC converter to help the Voltage Source Inverter (VSI) to regulate output power and also to control the operation of the battery and supercapacitor. This ensures a longer life time for the batteries. The detailed model is simulated in PSCAD/EMTP. Additionally, economic analysis has been done for different methods that can reduce the wind power output fluctuation. These methods are, wind power curtailment, dumping loads, battery energy storage system and hybrid energy storage system. From the results, application of single advanced HESS can save more money for wind turbines owners. Generally the income would be the same for most of methods because the wind does not change and maximum power point tracking can be applied to most systems. On the other hand, the cost is the key point. For short term and small wind turbine, the BESS is the cheapest and applicable method while for large scale wind turbines and wind farms the application of advanced HESS would be the best method to reduce the power fluctuation. The key outcomes of this project include a new intelligent controller that can reduce energy exchanged between the battery and DC-link, reduce charging/discharging cycles, reduce depth of discharge and increase time interval between charge/discharge, and lower battery temperature. This improves the overall lifetime of battery energy storages. Additionally, a new design method based on probability help optimize the power capacity specification for BESS and super-capacitors. Recommendations include experimental imp

  20. CO2 storage researchers at the Australian School of Petroleum focusing on the following areas

    E-Print Network [OSTI]

    Balasuriya, Sanjeeva

    CO2 storage researchers at the Australian School of Petroleum focusing on the following areas and Learn Student Sally Edwards ASP Associate Researcher Sally Holl CO2CRC/ASP Act ivit y Purp ose To assess t he im p act on geological st orage of CO2. Key p roject s o Gip psland Basin (onshore): Com p let ed

  1. Physical and chemical effects of CO2 storage in saline aquifers of the southern North Sea 

    E-Print Network [OSTI]

    Heinemann, Niklas

    2013-07-01

    One of the most promising mitigation strategies for greenhouse gas accumulation in the atmosphere is carbon capture and storage (CCS). Deep saline aquifers are seen as the most efficient carbon dioxide (CO2) storage sites, ...

  2. Why we need the and in CO2 utilization and storage.

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2013-01-01

    as cushion gas for natural gas storage. Energ Fuels 17:240–CO 2 as a cushion gas for energy storage. 5 Granted, if ourstorage (seques- tration) by which mankind can decrease greenhouse gas (

  3. The effects of gas-fluid-rock interactions on CO2 injection and storage: Insights from reactive transport modeling

    E-Print Network [OSTI]

    Xu, T.

    2009-01-01

    CO2 injection and storage, gas-fluid-rock interactions,this study covered gas injection and storage in bothof CO 2 and acid gas injection and storage is controlled by

  4. Using Pressure and Volumetric Approaches to Estimate CO2 Storage Capacity in Deep Saline Aquifers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thibeau, Sylvain; Bachu, Stefan; Birkholzer, Jens; Holloway, Sam; Neele, Filip; Zhou, Quanlin

    2014-12-31

    Various approaches are used to evaluate the capacity of saline aquifers to store CO2, resulting in a wide range of capacity estimates for a given aquifer. The two approaches most used are the volumetric “open aquifer” and “closed aquifer” approaches. We present four full-scale aquifer cases, where CO2 storage capacity is evaluated both volumetrically (with “open” and/or “closed” approaches) and through flow modeling. These examples show that the “open aquifer” CO2 storage capacity estimation can strongly exceed the cumulative CO2 injection from the flow model, whereas the “closed aquifer” estimates are a closer approximation to the flow-model derived capacity. Anmore »analogy to oil recovery mechanisms is presented, where the primary oil recovery mechanism is compared to CO2 aquifer storage without producing formation water; and the secondary oil recovery mechanism (water flooding) is compared to CO2 aquifer storage performed simultaneously with extraction of water for pressure maintenance. This analogy supports the finding that the “closed aquifer” approach produces a better estimate of CO2 storage without water extraction, and highlights the need for any CO2 storage estimate to specify whether it is intended to represent CO2 storage capacity with or without water extraction.« less

  5. Probabilistic cost estimation methods for treatment of water extracted during CO2 storage and EOR

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graham, Enid J. Sullivan; Chu, Shaoping; Pawar, Rajesh J.

    2015-08-08

    Extraction and treatment of in situ water can minimize risk for large-scale CO2 injection in saline aquifers during carbon capture, utilization, and storage (CCUS), and for enhanced oil recovery (EOR). Additionally, treatment and reuse of oil and gas produced waters for hydraulic fracturing will conserve scarce fresh-water resources. Each treatment step, including transportation and waste disposal, generates economic and engineering challenges and risks; these steps should be factored into a comprehensive assessment. We expand the water treatment model (WTM) coupled within the sequestration system model CO2-PENS and use chemistry data from seawater and proposed injection sites in Wyoming, to demonstratemore »the relative importance of different water types on costs, including little-studied effects of organic pretreatment and transportation. We compare the WTM with an engineering water treatment model, utilizing energy costs and transportation costs. Specific energy costs for treatment of Madison Formation brackish and saline base cases and for seawater compared closely between the two models, with moderate differences for scenarios incorporating energy recovery. Transportation costs corresponded for all but low flow scenarios (3/d). Some processes that have high costs (e.g., truck transportation) do not contribute the most variance to overall costs. Other factors, including feed-water temperature and water storage costs, are more significant contributors to variance. These results imply that the WTM can provide good estimates of treatment and related process costs (AACEI equivalent level 5, concept screening, or level 4, study or feasibility), and the complex relationships between processes when extracted waters are evaluated for use during CCUS and EOR site development.« less

  6. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    by well/VSP (Vertical Seismic Profile) data. Fractures andat the Frio site, a vertical seismic profile ficult due towells VSP (vertical seismic profile) CO 2 distribution updip

  7. ENVIRONMENTAL ASSESSMENT OF GEOLOGIC STORAGE OF CO2 Jason J. Heinrich, Howard J. Herzog, David M. Reiner

    E-Print Network [OSTI]

    analogs: acid gas injection (AGI), enhanced oil recovery (EOR), natural gas storage, and CO2 transportENVIRONMENTAL ASSESSMENT OF GEOLOGIC STORAGE OF CO2 * Jason J. Heinrich, Howard J. Herzog, David M of reducing CO2 emissions. The storage of CO2 in underground geologic reservoirs is one such idea that employs

  8. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    Interpretation of Aquifer Gas Storage Conditions from Waterthe re- lated problem of gas storage in aquifers and devel-1967) for aquifer gas storage. The other issue discussed in

  9. First-Generation Risk Profiles Help Predict CO2 Storage Site...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 18, 2012 - 1:00pm Addthis Washington, DC - In support of large-scale carbon capture, utilization and storage (CCUS) projects, a collaboration of five U.S. Department...

  10. Using Big Data and Smart Field Technology for Detecting Leakage in a CO2 Storage Projects

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    of the underground carbon dioxide storage to confine and sustain the injected CO2 for very long time. If a leakageSPE 166137 Using Big Data and Smart Field Technology for Detecting Leakage in a CO2 Storage sequestration of carbon dioxide is one of the most fascinating developing technologies in order to reduce

  11. Rigorous Screening Technology for Identifying Suitable CO2 Storage Sites II

    SciTech Connect (OSTI)

    George J. Koperna Jr.; Vello A. Kuuskraa; David E. Riestenberg; Aiysha Sultana; Tyler Van Leeuwen

    2009-06-01

    This report serves as the final technical report and users manual for the 'Rigorous Screening Technology for Identifying Suitable CO2 Storage Sites II SBIR project. Advanced Resources International has developed a screening tool by which users can technically screen, assess the storage capacity and quantify the costs of CO2 storage in four types of CO2 storage reservoirs. These include CO2-enhanced oil recovery reservoirs, depleted oil and gas fields (non-enhanced oil recovery candidates), deep coal seems that are amenable to CO2-enhanced methane recovery, and saline reservoirs. The screening function assessed whether the reservoir could likely serve as a safe, long-term CO2 storage reservoir. The storage capacity assessment uses rigorous reservoir simulation models to determine the timing, ultimate storage capacity, and potential for enhanced hydrocarbon recovery. Finally, the economic assessment function determines both the field-level and pipeline (transportation) costs for CO2 sequestration in a given reservoir. The screening tool has been peer reviewed at an Electrical Power Research Institute (EPRI) technical meeting in March 2009. A number of useful observations and recommendations emerged from the Workshop on the costs of CO2 transport and storage that could be readily incorporated into a commercial version of the Screening Tool in a Phase III SBIR.

  12. Coal laboratory characterisation for CO2 geological storage E.C. Gaucher1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Coal laboratory characterisation for CO2 geological storage E.C. Gaucher1 *, P.D.C. Défossez1 storage of CO2 in unmineable coal seams could be a very interesting option in the sustainable management of coal basins. However, the various chemical and physical parameters that determine the success

  13. Techno-economic Modeling of the Integration of 20% Wind and Large-scale Energy Storage in ERCOT by 2030

    SciTech Connect (OSTI)

    Ross Baldick; Michael Webber; Carey King; Jared Garrison; Stuart Cohen; Duehee Lee

    2012-12-21

    This study�¢����s objective is to examine interrelated technical and economic avenues for the Electric Reliability Council of Texas (ERCOT) grid to incorporate up to and over 20% wind generation by 2030. Our specific interests are to look at the factors that will affect the implementation of both high level of wind power penetration (> 20% generation) and installation of large scale storage.

  14. A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage

    SciTech Connect (OSTI)

    Yang, Yuan; Zheng, Guangyuan; Cui, Yi

    2013-01-01

    Large-scale energy storage represents a key challenge for renewable energy and new systems with low cost, high energy density and long cycle life are desired. In this article, we develop a new lithium/polysulfide (Li/PS) semi-liquid battery for large-scale energy storage, with lithium polysulfide (Li{sub 2}S{sub 8}) in ether solvent as a catholyte and metallic lithium as an anode. Unlike previous work on Li/S batteries with discharge products such as solid state Li{sub 2}S{sub 2} and Li{sub 2}S, the catholyte is designed to cycle only in the range between sulfur and Li{sub 2}S{sub 4}. Consequently all detrimental effects due to the formation and volume expansion of solid Li{sub 2}S{sub 2}/Li{sub 2}S are avoided. This novel strategy results in excellent cycle life and compatibility with flow battery design. The proof-of-concept Li/PS battery could reach a high energy density of 170 W h kg{sup -1} and 190 W h L{sup -1} for large scale storage at the solubility limit, while keeping the advantages of hybrid flow batteries. We demonstrated that, with a 5 M Li{sub 2}S{sub 8} catholyte, energy densities of 97 W h kg{sup -1} and 108 W h L{sup -1} can be achieved. As the lithium surface is well passivated by LiNO{sub 3} additive in ether solvent, internal shuttle effect is largely eliminated and thus excellent performance over 2000 cycles is achieved with a constant capacity of 200 mA h g{sup -1}. This new system can operate without the expensive ion-selective membrane, and it is attractive for large-scale energy storage.

  15. Large Scale Computing and Storage Requirements for Fusion Energy Sciences Research

    E-Print Network [OSTI]

    Gerber, Richard

    2012-01-01

    and  Storage  Requirements  for  Fusion  Energy  Sciences  Requirements  for  Fusion  Energy  Sciences   14 General  Storage  Requirements  for  Fusion  Energy  Sciences   i  

  16. CO2-Brine Surface Dissolution and Injection: CO2 Storage Enhancement Paul Emeka Eke, SPE, Mark Naylor, Stuart Haszeldine and Andrew Curtis, Scottish Centre for Carbon Storage,

    E-Print Network [OSTI]

    . The abstract must contain conspicuous acknowledgment of SPE copyright. Abstract Carbon capture and storage (CCS, Mark Naylor, Stuart Haszeldine and Andrew Curtis, Scottish Centre for Carbon Storage, School of Geo. The upward buoyancy of dense phase carbon dioxide (CO2) in deep reservoirs means that sites need to be chosen

  17. How secure is CO2 storage? Leakage mechanisms of natural CO2 reservoirs

    E-Print Network [OSTI]

    and Petroleum Geology, v. 16, no. 6, p. 489-494. 1. Introduction Carbon Capture and Storage (CCS) is the only.miocic@ed.ac.uk blog jojomio.wordpress.com Scan me! References 1 IPCC, 2005, IPCC Special report on Carbon Dioxide Capture and Storage: Cambridge University Press. 2 Wycherley, H., Fleet, A., and Shaw, H., 1999, Some

  18. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    clean sources of energy. Asturias, in northern Spain, is theThe CO 2 emissions in Asturias represent the 8% of total COsequestration in Asturias are deep saline aquifers and

  19. Secretary Moniz Announces New CO2 Storage Network at Multinational...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    collaboration builds on the success of the CO2 Capture Test Center Network, chaired by Norway since 2013. The U.S. will take the lead on the capture center initiative next year. At...

  20. System-level modeling for geological storage of CO2

    E-Print Network [OSTI]

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01

    reservoir, a natural gas power plant that burns CH 4 , CO 2from the natural gas power plant, there are two otherflue gas of the natural gas power plant in the system. When

  1. Alabama Project Testing Potential for Combining CO2 Storage with...

    Broader source: Energy.gov (indexed) [DOE]

    to sequester 1.1 gigatons to 2.3 gigatons of CO2--approximately the amount that Alabama's coal-fired power plants emit in two decades. Enhanced coalbed methane recovery combined...

  2. Seismic modeling to monitor CO2 geological storage: The Atzbach ...

    E-Print Network [OSTI]

    2012-05-30

    Jun 8, 2012 ... When CO2 is stored into depleted oil and gas fields or unmineable .... where rb is the water (brine) density and g is the acceleration of gravity.

  3. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    the arrival of CO 2 . The drilling fluids were tagged withSeismic survey Drilling phase Fluid loss record, PWD Leak-as fluid path should be investigated during drilling phase.

  4. The geomechanics of CO2 storage in deep sedimentary formations

    E-Print Network [OSTI]

    Rutqvist, J.

    2013-01-01

    EOR operations, natural gas storage, and acid gas disposal.seal. For example, underground gas storage in aquifers is anFor example, at the Leroy gas storage facility in Wyoming,

  5. Leakage of CO2 from geologic storage: Role of secondaryaccumulation at shallow depth

    SciTech Connect (OSTI)

    Pruess, K.

    2007-05-31

    Geologic storage of CO2 can be a viable technology forreducing atmospheric emissions of greenhouse gases only if it can bedemonstrated that leakage from proposed storage reservoirs and associatedhazards are small or can be mitigated. Risk assessment must evaluatepotential leakage scenarios and develop a rational, mechanisticunderstanding of CO2 behavior during leakage. Flow of CO2 may be subjectto positive feedbacks that could amplify leakage risks and hazards,placing a premium on identifying and avoiding adverse conditions andmechanisms. A scenario that is unfavorable in terms of leakage behavioris formation of a secondary CO2 accumulation at shallow depth. This paperdevelops a detailed numerical simulation model to investigate CO2discharge from a secondary accumulation, and evaluates the role ofdifferent thermodynamic and hydrogeologic conditions. Our simulationsdemonstrate self-enhancing as well as self-limiting feedbacks.Condensation of gaseous CO2, 3-phase flow of aqueous phase -- liquid CO2-- gaseous CO2, and cooling from Joule-Thomson expansion and boiling ofliquid CO2 are found to play important roles in the behavior of a CO2leakage system. We find no evidence that a subsurface accumulation of CO2at ambient temperatures could give rise to a high-energy discharge, aso-called "pneumatic eruption."

  6. Ris Energy Report 6 CO2 capture and storage 2 6.1 What is CO2 capture and storage?

    E-Print Network [OSTI]

    Gas Biomass Power & heat Power & heat Power & heat Gasification Air separation Process+CO2 sep-combustion Pre-combustion Oxyfuel Industrial processes Coal Gas Biomass Coal Gas Biomass Coal Gas Biomass Coal

  7. Hydro-mechanical modelling of geological CO2 storage and the study of possible caprock fracture mechanisms

    E-Print Network [OSTI]

    Hydro-mechanical modelling of geological CO2 storage and the study of possible caprock fracture element modelling of a hypothetical underground carbon dioxide (CO2) storage operation. The hydro

  8. Large Scale Computing and Storage Requirements for Fusion Energy Sciences Research

    E-Print Network [OSTI]

    Gerber, Richard

    2012-01-01

    simulations of fusion and energy systems with unprecedentedRequirements  for  Fusion  Energy  Sciences   14 General  and  Storage  Requirements  for  Fusion  Energy  Sciences  

  9. Scenario Development and Analysis of Hydrogen as a Large-Scale Energy Storage Medium (Presentation)

    SciTech Connect (OSTI)

    Steward, D. M.

    2009-06-10

    The conclusions from this report are: (1) hydrogen has several important advantages over competing technologies, including - very high storage energy density (170 kWh/m{sup 3} vs. 2.4 for CAES and 0.7 for pumped hydro) which allows for potential economic viability of above-ground storage and relatively low environmental impact in comparison with other technologies; and (2) the major disadvantage of hydrogen energy storage is cost but research and deployment of electrolyzers and fuel cells may reduce cost significantly.

  10. Role of large scale storage in a UK low carbon energy future Philipp Grunewalda

    E-Print Network [OSTI]

    ) and enable demand side management (DSM) of electric appliances, including ground source heat pumps, air conditioning units and industrial refrigerators, thereby acting as virtual storage. The combined UK potential

  11. Modelling the deployment of CO2 storage in U.S. gas-bearing shales

    SciTech Connect (OSTI)

    Davidson, Casie L.; Dahowski, Robert T.; Dooley, James J.; McGrail, B. Peter

    2014-10-23

    The proliferation of commercial development in U.S. gas-bearing shales helped to drive a twelve-fold increase in domestic gas production between 2000 and 2010, and the nation’s gas production rates continue to grow. While shales have long been regarded as a desirable caprock for CCS operations because of their low permeability and porosity, there is increasing interest in the feasibility of injecting CO2 into shales to enhance methane recovery and augment CO2 storage. Laboratory work published in recent years observes that shales with adsorbed methane appear to exhibit a stronger affinity for CO2 adsorption, offering the potential to drive additional CH4 recovery beyond primary production and perhaps the potential to store a larger volume of CO2 than the volume of methane displaced. Recent research by the authors on the revenues associated with CO2-enhanced gas recovery (CO2-EGR) in gas-bearing shales estimates that, based on a range of EGR response rates, the average revenue per ton of CO2 for projects managed over both EGR and subsequent storage-only phases could range from $0.50 to $18/tCO2. While perhaps not as profitable as EOR, for regions where lower-cost storage options may be limited, shales could represent another “early opportunity” storage option if proven feasible for reliable EGR and CO2 storage. Significant storage potential exists in gas shales, with theoretical CO2 storage resources estimated at approximately 30-50 GtCO2. However, an analysis of the comprehensive cost competitiveness of these various options is necessary to understand the degree to which they might meaningfully impact U.S. CCS deployment or costs. This preliminary analysis shows that the degree to which EGR-based CO2 storage could play a role in commercial-scale deployment is heavily dependent upon the offsetting revenues associated with incremental recovery; modeling the low revenue case resulted in only five shale-based projects, while under the high revenue case, shales accounted for as much as 20 percent of total U.S. storage in the first 20 years of deployment. Interestingly, even in this highest revenue case, there appear to be no negative-cost projects that would be profitable in a no-policy environment as modeled under the assumptions employed. While this reflects a very first look at the potential for shales, it is clear that more laboratory and experimental work are needed to reduce uncertainty in key variables and begin to differentiate and identify high-potential shales for early pilot study.

  12. co2-saline-storage | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for 2-D seismic, 3-D seismic, vertical seismic profiling, crosswell seismic and microseismic technologies. Which Reservoir for Low Cost Capture, Transportation, and Storage? -...

  13. The Rosetta Resources CO2 Storage Project - A WESTCARB GeologicPilot Test

    SciTech Connect (OSTI)

    Trautz, Robert; Benson, Sally; Myer, Larry; Oldenburg, Curtis; Seeman, Ed; Hadsell, Eric; Funderburk, Ben

    2006-01-30

    WESTCARB, one of seven U.S. Department of Energypartnerships, identified (during its Phase I study) over 600 gigatonnesof CO2 storage capacity in geologic formations located in the Westernregion. The Western region includes the WESTCARB partnership states ofAlaska, Arizona, California, Nevada, Oregon and Washington and theCanadian province of British Columbia. The WESTCARB Phase II study iscurrently under way, featuring three geologic and two terrestrial CO2pilot projects designed to test promising sequestration technologies atsites broadly representative of the region's largest potential carbonsinks. This paper focuses on two of the geologic pilot studies plannedfor Phase II -referred to-collectively as the Rosetta-Calpine CO2 StorageProject. The first pilot test will demonstrate injection of CO2 into asaline formation beneath a depleted gas reservoir. The second test willgather data for assessing CO2 enhanced gas recovery (EGR) as well asstorage in a depleted gas reservoir. The benefit of enhanced oil recovery(EOR) using injected CO2 to drive or sweep oil from the reservoir towarda production well is well known. EaR involves a similar CO2 injectionprocess, but has received far less attention. Depleted natural gasreservoirs still contain methane; therefore, CO2 injection may enhancemethane production by reservoir repressurization or pressure maintenance.CO2 injection into a saline formation, followed by injection into adepleted natural gas reservoir, is currently scheduled to start inOctober 2006.

  14. European and Global Perspectives for CO2 Capture and Storage

    E-Print Network [OSTI]

    a large point source, compression, transport and subsequent storage in a geological reservoir, the ocean the penetration of renewable energy sources and nuclear. Policies that provide flexibility, for instance through storage in a geological reservoir, the ocean, or in mineral carbonates. This paper analyses the role of CO

  15. UKERC Landscapes CO2 Capture and Storage Last Updated: 14 May 2009 UKERC ENERGY RESEARCH LANDSCAPE: CARBON CAPTURE AND STORAGE

    E-Print Network [OSTI]

    Wilkinson, Mark

    of CCS worldwide could halve new CO2 emissions (IPCC, 2005). In the 2006 IEA World Energy Outlook (BeyondUKERC ­ Landscapes ­ CO2 Capture and Storage Last Updated: 14 May 2009 UKERC ENERGY RESEARCH) Programmes. Section 8: UK participation in energy-related EU Framework Research and Technology Development

  16. Fuels generated from renewable energy: a possible solution for large scale energy storage

    E-Print Network [OSTI]

    Franssen, Michael

    To perform leading fundamental research in the fields of fusion energy and solar fuels, New Mission DIFFER, energy infrastructure essential #12;4/22/2012 3 Theoretical potential energy sources Solar energy....... solar generation ...energy demand Storage and transport is part of the challenge! #12;4/22/2012 6 PV

  17. ECONOMIC EVALUATION OF CO2 STORAGE AND SINK ENHANCEMENT OPTIONS

    SciTech Connect (OSTI)

    Bert Bock; Richard Rhudy; Howard Herzog; Michael Klett; John Davison; Danial G. De La Torre Ugarte; Dale Simbeck

    2003-02-01

    This project developed life-cycle costs for the major technologies and practices under development for CO{sub 2} storage and sink enhancement. The technologies evaluated included options for storing captured CO{sub 2} in active oil reservoirs, depleted oil and gas reservoirs, deep aquifers, coal beds, and oceans, as well as the enhancement of carbon sequestration in forests and croplands. The capture costs for a nominal 500 MW{sub e} integrated gasification combined cycle plant from an earlier study were combined with the storage costs from this study to allow comparison among capture and storage approaches as well as sink enhancements.

  18. Large Scale Computing and Storage Requirements for Basic Energy Sciences Research

    SciTech Connect (OSTI)

    Gerber, Richard; Wasserman, Harvey

    2011-03-31

    The National Energy Research Scientific Computing Center (NERSC) is the leading scientific computing facility supporting research within the Department of Energy's Office of Science. NERSC provides high-performance computing (HPC) resources to approximately 4,000 researchers working on about 400 projects. In addition to hosting large-scale computing facilities, NERSC provides the support and expertise scientists need to effectively and efficiently use HPC systems. In February 2010, NERSC, DOE's Office of Advanced Scientific Computing Research (ASCR) and DOE's Office of Basic Energy Sciences (BES) held a workshop to characterize HPC requirements for BES research through 2013. The workshop was part of NERSC's legacy of anticipating users future needs and deploying the necessary resources to meet these demands. Workshop participants reached a consensus on several key findings, in addition to achieving the workshop's goal of collecting and characterizing computing requirements. The key requirements for scientists conducting research in BES are: (1) Larger allocations of computational resources; (2) Continued support for standard application software packages; (3) Adequate job turnaround time and throughput; and (4) Guidance and support for using future computer architectures. This report expands upon these key points and presents others. Several 'case studies' are included as significant representative samples of the needs of science teams within BES. Research teams scientific goals, computational methods of solution, current and 2013 computing requirements, and special software and support needs are summarized in these case studies. Also included are researchers strategies for computing in the highly parallel, 'multi-core' environment that is expected to dominate HPC architectures over the next few years. NERSC has strategic plans and initiatives already underway that address key workshop findings. This report includes a brief summary of those relevant to issues raised by researchers at the workshop.

  19. Economic analysis of large-scale hydrogen storage for renewable utility applications.

    SciTech Connect (OSTI)

    Schoenung, Susan M.

    2011-08-01

    The work reported here supports the efforts of the Market Transformation element of the DOE Fuel Cell Technology Program. The portfolio includes hydrogen technologies, as well as fuel cell technologies. The objective of this work is to model the use of bulk hydrogen storage, integrated with intermittent renewable energy production of hydrogen via electrolysis, used to generate grid-quality electricity. In addition the work determines cost-effective scale and design characteristics and explores potential attractive business models.

  20. Large Scale Computing and Storage Requirements for Fusion Energy Sciences: Target 2017

    SciTech Connect (OSTI)

    Gerber, Richard

    2014-05-02

    The National Energy Research Scientific Computing Center (NERSC) is the primary computing center for the DOE Office of Science, serving approximately 4,500 users working on some 650 projects that involve nearly 600 codes in a wide variety of scientific disciplines. In March 2013, NERSC, DOE?s Office of Advanced Scientific Computing Research (ASCR) and DOE?s Office of Fusion Energy Sciences (FES) held a review to characterize High Performance Computing (HPC) and storage requirements for FES research through 2017. This report is the result.

  1. A method for quick assessment of CO2 storage capacity in closed and semi-closed saline formations

    E-Print Network [OSTI]

    Zhou, Quanlin

    the fraction of total pore space available for CO2 storage, limited by heterogeneity, buoyancy effectsA method for quick assessment of CO2 storage capacity in closed and semi-closed saline formations, USA 1. Introduction Geological carbon dioxide (CO2) sequestration in deep forma- tions (e.g., saline

  2. CO2-Driven Enhanced Gas Recovery and Storage in Depleted Shale Reservoir-A Numerical Simulation Study

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    1 CO2-Driven Enhanced Gas Recovery and Storage in Depleted Shale Reservoir- A Numerical Simulation for storage and enhanced gas recovery may be organic-rich shales, which CO2 is preferentially adsorbed comprehensive simulation studies to better understand CO2 injection process in shale gas reservoir. This paper

  3. CO2 utilization and storage in shale gas reservoirs: Experimental results and economic impacts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schaef, Herbert T.; Davidson, Casie L.; Owen, Antionette Toni; Miller, Quin R. S.; Loring, John S.; Thompson, Christopher J.; Bacon, Diana H.; Glezakou, Vassiliki Alexandra; McGrail, B. Peter

    2014-12-31

    Natural gas is considered a cleaner and lower-emission fuel than coal, and its high abundance from advanced drilling techniques has positioned natural gas as a major alternative energy source for the U.S. However, each ton of CO2 emitted from any type of fossil fuel combustion will continue to increase global atmospheric concentrations. One unique approach to reducing anthropogenic CO2 emissions involves coupling CO2 based enhanced gas recovery (EGR) operations in depleted shale gas reservoirs with long-term CO2 storage operations. In this paper, we report unique findings about the interactions between important shale minerals and sorbing gases (CH4 and CO2) andmore »associated economic consequences. Where enhanced condensation of CO2 followed by desorption on clay surface is observed under supercritical conditions, a linear sorption profile emerges for CH4. Volumetric changes to montmorillonites occur during exposure to CO2. Theory-based simulations identify interactions with interlayer cations as energetically favorable for CO2 intercalation. Thus, experimental evidence suggests CH4 does not occupy the interlayer and has only the propensity for surface adsorption. Mixed CH4:CO2 gas systems, where CH4 concentrations prevail, indicate preferential CO2 sorption as determined by in situ infrared spectroscopy and X-ray diffraction techniques. Collectively, these laboratory studies combined with a cost-based economic analysis provide a basis for identifying favorable CO2-EOR opportunities in previously fractured shale gas reservoirs approaching final stages of primary gas production. Moreover, utilization of site-specific laboratory measurements in reservoir simulators provides insight into optimum injection strategies for maximizing CH4/CO2 exchange rates to obtain peak natural gas production.« less

  4. On scale and magnitude of pressure build-up induced by large-scale geologic storage of CO2

    E-Print Network [OSTI]

    Zhou, Q.

    2012-01-01

    produced water from production of crude oil, natural gas,combined U.S. production rate of crude oil (0.3 km 3 ) and

  5. Microsoft Word - NRAP-TRS-III-002-2012_Modeling the Performance of Large Scale CO2 Storage_20121024.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetection of Hydrates on Gas BubblesUse of Modeling the

  6. Large Scale Computing and Storage Requirements for Biological and Environmental Research

    SciTech Connect (OSTI)

    DOE Office of Science, Biological and Environmental Research Program Office ,

    2009-09-30

    In May 2009, NERSC, DOE's Office of Advanced Scientific Computing Research (ASCR), and DOE's Office of Biological and Environmental Research (BER) held a workshop to characterize HPC requirements for BER-funded research over the subsequent three to five years. The workshop revealed several key points, in addition to achieving its goal of collecting and characterizing computing requirements. Chief among them: scientific progress in BER-funded research is limited by current allocations of computational resources. Additionally, growth in mission-critical computing -- combined with new requirements for collaborative data manipulation and analysis -- will demand ever increasing computing, storage, network, visualization, reliability and service richness from NERSC. This report expands upon these key points and adds others. It also presents a number of"case studies" as significant representative samples of the needs of science teams within BER. Workshop participants were asked to codify their requirements in this"case study" format, summarizing their science goals, methods of solution, current and 3-5 year computing requirements, and special software and support needs. Participants were also asked to describe their strategy for computing in the highly parallel,"multi-core" environment that is expected to dominate HPC architectures over the next few years.

  7. Leakage risk assessment of the In Salah CO2 storage project: Applying the Certification Framework in a dynamic context.

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2011-01-01

    Leakage risk assessment of the In Salah CO 2 storageCF) is a simple risk assessment approach for evaluating CO 2system including two risk assessment efforts, one before

  8. CO2 Storage and Enhanced Oil Recovery: Bald Unit Test Site, Mumford Hills Oil Field, Posey County, Indiana

    SciTech Connect (OSTI)

    Frailey, Scott M.; Krapac, Ivan G.; Damico, James R.; Okwen, Roland T.; McKaskle, Ray W.

    2012-03-30

    The Midwest Geological Sequestration Consortium (MGSC) carried out a small-scale carbon dioxide (CO2) injection test in a sandstone within the Clore Formation (Mississippian System, Chesterian Series) in order to gauge the large-scale CO2 storage that might be realized from enhanced oil recovery (EOR) of mature Illinois Basin oil fields via miscible liquid CO2 flooding. As part of the MGSC�������¢����������������s Validation Phase (Phase II) studies, the small injection pilot test was conducted at the Bald Unit site within the Mumford Hills Field in Posey County, southwestern Indiana, which was chosen for the project on the basis of site infrastructure and reservoir conditions. Geologic data on the target formation were extensive. Core analyses, porosity and permeability data, and geophysical logs from 40 wells were used to construct cross sections and structure contour and isopach maps in order to characterize and define the reservoir architecture of the target formation. A geocellular model of the reservoir was constructed to improve understanding of CO2 behavior in the subsurface. At the time of site selection, the Field was under secondary recovery through edge-water injection, but the wells selected for the pilot in the Bald Unit had been temporarily shut-in for several years. The most recently shut-in production well, which was surrounded by four nearby shut-in production wells in a five-spot pattern, was converted to CO2 injection for this pilot. Two additional wells outside the immediate five-spot pattern, one of which was an active producer, were instrumented to measure surface temperature and pressure. The CO2 injection period lasted from September 3, 2009, through December 14, 2010, with one three-month interruption caused by cessation of CO2 deliveries due to winter weather. Water was injected into the CO2 injection well during this period. A total of 6,300 tonnes (6,950 tons) of CO2 were injected into the reservoir at rates that generally ranged from 18 to 32 tonnes (20 to 35 tons) per day. The CO2 injection bottomhole pressure generally remained at 8.3 to 9.0 MPag (1,200 to 1,300 psig). The CO2 injection was followed by continued monitoring for nine months during post-CO2 water injection. A monitoring, verification, and accounting (MVA) program was designed to determine the fate of injected CO2. Extensive periodic sampling and analysis of brine, groundwater, and produced gases began before CO2 injection and continued through the monitored waterflood periods. Samples were gathered from production wells and three newly installed groundwater monitoring wells. Samples underwent geochemical and isotopic analyses to reveal any CO2-related changes. Groundwater and kinetic modeling and mineralogical analysis were also employed to better understand the long-term dynamics of CO2 in the reservoir. No CO2 leakage into groundwater was detected, and analysis of brine and gas chemistry made it possible to track the path of plume migration and infer geochemical reactions and trapping of CO2. Cased-hole logging did not detect any CO2 in the near-wellbore region. An increase in CO2 concentration was first detected in February 2010 from the gas present in the carboy during brine sampling; however, there was no appreciable gas volume associated with the detection of CO2. The first indication of elevated gas rates from the commingled gas of the pilot�������¢����������������s production wells occurred in July 2010 and reached a maximum of 0.36 tonnes/day (0.41 tons/day) in September 2010. An estimated 27 tonnes (30 tons) of CO2 were produced at the surface from the gas separator at the tank battery from September 3, 2009, through September 11, 2011, representing 0.5% of the injected CO2. Consequently, 99.5%

  9. Directed Technical Change and the Adoption of CO2 Abatement Technology: The Case of CO2 Capture and Storage

    E-Print Network [OSTI]

    Otto, Vincent M.

    This paper studies the cost effectiveness of combining traditional environmental policy, such as CO2 trading schemes, and technology policy that has aims of reducing the cost and speeding the adoption of CO2 abatement ...

  10. Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review

    SciTech Connect (OSTI)

    Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

    2012-07-09

    Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

  11. Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers

    SciTech Connect (OSTI)

    Wu, Yu-Shu; Chen, Zizhong; Kazemi, Hossein; Yin, Xiaolong; Pruess, Karsten; Oldenburg, Curt; Winterfeld, Philip; Zhang, Ronglei

    2014-09-30

    This report is the final scientific one for the award DE- FE0000988 entitled “Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers.” The work has been divided into six tasks. In task, “Development of a Three-Phase Non-Isothermal CO2 Flow Module,” we developed a fluid property module for brine-CO2 mixtures designed to handle all possible phase combinations of aqueous phase, sub-critical liquid and gaseous CO2, supercritical CO2, and solid salt. The thermodynamic and thermophysical properties of brine-CO2 mixtures (density, viscosity, and specific enthalpy of fluid phases; partitioning of mass components among the different phases) use the same correlations as an earlier fluid property module that does not distinguish between gaseous and liquid CO2-rich phases. We verified the fluid property module using two leakage scenarios, one that involves CO2 migration up a blind fault and subsequent accumulation in a secondary “parasitic” reservoir at shallower depth, and another investigating leakage of CO2 from a deep storage reservoir along a vertical fault zone. In task, “Development of a Rock Mechanical Module,” we developed a massively parallel reservoir simulator for modeling THM processes in porous media brine aquifers. We derived, from the fundamental equations describing deformation of porous elastic media, a momentum conservation equation relating mean stress, pressure, and temperature, and incorporated it alongside the mass and energy conservation equations from the TOUGH2 formulation, the starting point for the simulator. In addition, rock properties, namely permeability and porosity, are functions of effective stress and other variables that are obtained from the literature. We verified the simulator formulation and numerical implementation using analytical solutions and example problems from the literature. For the former, we matched a one-dimensional consolidation problem and a two-dimensional simulation of the Mandel-Cryer effect. For the latter, we obtained a good match of temperature and gas saturation profiles, and surface uplift, after injection of hot fluid into a model of a caldera structure. In task, “Incorporation of Geochemical Reactions of Selected Important Species,” we developed a novel mathematical model of THMC processes in porous and fractured saline aquifers, simulating geo-chemical reactions associated with CO2 sequestration in saline aquifers. Two computational frameworks, sequentially coupled and fully coupled, were used to simulate the reactions and transport. We verified capabilities of the THMC model to treat complex THMC processes during CO2 sequestration by analytical solutions and we constructed reactive transport models to analyze the THMC process quantitatively. Three of these are 1D reactive transport under chemical equilibrium, a batch reaction model with equilibrium chemical reactions, and a THMC model with CO2 dissolution. In task “Study of Instability in CO2 Dissolution-Diffusion-Convection Processes,” We reviewed literature related to the study of density driven convective flows and on the instability of CO2 dissolution-diffusion-convection processes. We ran simulations that model the density-driven flow instability that would occur during CO2 sequestration. CO2 diffused through the top of the system and dissolved in the aqueous phase there, increasing its density. Density fingers formed along the top boundary, and coalesced into a few prominent ones, causing convective flow that forced the fluid to the system bottom. These simulations were in two and three dimensions. We ran additional simulations of convective mixing with density contrast caused by variable dissolved CO2 concentration in saline water, modeled after laboratory experiments in which supercritical CO2 was circulated in the headspace above a brine saturated packed sand in a pressure vessel. As CO2 dissolved into the upper part of the saturated sand, liquid phase density increases causing instability and setting off convective mixing. We obtained good agreement

  12. Drilling and Abandonment Preparation of CO2 storage wells – Experience from the Ketzin pilot site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Prevedel, Bernhard; Martens, Sonja; Norden, Ben; Henninges, Jan; Freifeld, Barry M.

    2014-01-01

    At Ketzin, located west of Berlin, the GFZ German Centre for Geosciences is operating Europe's largest CO2 research storage site. This pilot site has been developed since 2004 and is comprised of one combined injection/observation well and four monitoring wells. From June 2008 to August 2013, a total of 67 kilotons of CO2 were safely injected into the sandstone units of the Upper Triassic Stuttgart Formation in a depth between 630 to 650 m. The paper discusses the well designs and lessons learned in drilling engineering and operations. The abandonment phase started in Ketzin with the first plug cementation ofmore »the observation well Ktzi 202 shortly after shut-in of CO2 injection. The experience with the first CO2 well killing operation will be reviewed.« less

  13. Managing Environmental and Human Safety Risks Associated with Geologic Storage of CO2

    E-Print Network [OSTI]

    London School of Economics, 2001 Submitted to the Engineering Systems Division in partial fulfillment transportation, injection and storage has been operational and scaling up in size and geographical distribution, transportation and injection, which have been successfully deployed in existing applications. Once CO2

  14. Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong David W. Keith April 11, 2003 Abstract Fossil fuels can be used with minimal atmospheric emissions of carbon diox, the cost of sequestration and the energy penalty (the energy necessary to capture, transport and inject

  15. NOVEL CONCEPTS RESEARCH IN GEOLOGIC STORAGE OF CO2 PHASE III THE OHIO RIVER VALLEY CO2 STORAGE PROJECT

    SciTech Connect (OSTI)

    Neeraj Gupta

    2005-05-26

    As part of the Department of Energy's (DOE) initiation on developing new technologies for storage of carbon dioxide in geologic reservoir, Battelle has been awarded a project to investigate the feasibility of CO{sub 2} sequestration in the deep saline reservoirs in the Ohio River Valley region. This project is the Phase III of Battelle's work under the Novel Concepts in Greenhouse Gas Management grant. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant in particular, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations and potentially in nearby deep coal seams. The current technical progress report summarizes activities completed for the January through March 2005 period of the project. As discussed in the report, the technical activities focused on development of injection well design, preparing a Class V Underground Injection Control permit, assessment of monitoring technologies, analysis of coal samples for testing the capture system by Mitsubishi Heavy Industry, and presentation of project progress at several venues. In addition, related work has progressed on a collaborative risk assessment project with Japan research institute CREIPI and technical application for the Midwest Regional Carbon Sequestration Partnership.

  16. Developing a Comprehensive Risk Assessment Framework for Geological Storage CO2

    SciTech Connect (OSTI)

    Duncan, Ian

    2014-08-31

    The operational risks for CCS projects include: risks of capturing, compressing, transporting and injecting CO?; risks of well blowouts; risk that CO? will leak into shallow aquifers and contaminate potable water; and risk that sequestered CO? will leak into the atmosphere. This report examines these risks by using information on the risks associated with analogue activities such as CO2 based enhanced oil recovery (CO2-EOR), natural gas storage and acid gas disposal. We have developed a new analysis of pipeline risk based on Bayesian statistical analysis. Bayesian theory probabilities may describe states of partial knowledge, even perhaps those related to non-repeatable events. The Bayesian approach enables both utilizing existing data and at the same time having the capability to adsorb new information thus to lower uncertainty in our understanding of complex systems. Incident rates for both natural gas and CO2 pipelines have been widely used in papers and reports on risk of CO2 pipelines as proxies for the individual risk created by such pipelines. Published risk studies of CO2 pipelines suggest that the individual risk associated with CO2 pipelines is between 10-3 and 10-4, which reflects risk levels approaching those of mountain climbing, which many would find unacceptably high. This report concludes, based on a careful analysis of natural gas pipeline failures, suggests that the individual risk of CO2 pipelines is likely in the range of 10-6 to 10-7, a risk range considered in the acceptable to negligible range in most countries. If, as is commonly thought, pipelines represent the highest risk component of CCS outside of the capture plant, then this conclusion suggests that most (if not all) previous quantitative- risk assessments of components of CCS may be orders of magnitude to high. The potential lethality of unexpected CO2 releases from pipelines or wells are arguably the highest risk aspects of CO2 enhanced oil recovery (CO2-EOR), carbon capture, and storage (CCS). Assertions in the CCS literature, that CO2 levels of 10% for ten minutes, or 20 to 30% for a few minutes are lethal to humans, are not supported by the available evidence. The results of published experiments with animals exposed to CO2, from mice to monkeys, at both normal and depleted oxygen levels, suggest that lethal levels of CO2 toxicity are in the range 50 to 60%. These experiments demonstrate that CO2 does not kill by asphyxia, but rather is toxic at high concentrations. It is concluded that quantitative risk assessments of CCS have overestimated the risk of fatalities by using values of lethality a factor two to six lower than the values estimated in this paper. In many dispersion models of CO2 releases from pipelines, no fatalities would be predicted if appropriate levels of lethality for CO2 had been used in the analysis.

  17. Initial results from seismic monitoring at the Aquistore CO2 storage site, Saskatchewan, Canada

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    White, D. J.; Roach, L. A.N.; Roberts, B.; Daley, T. M.

    2014-12-31

    The Aquistore Project, located near Estevan, Saskatchewan, is one of the first integrated commercial-scale CO2 storage projects in the world that is designed to demonstrate CO2 storage in a deep saline aquifer. Starting in 2014, CO2 captured from the nearby Boundary Dam coal-fired power plant will be transported via pipeline to the storage site and to nearby oil fields for enhanced oil recovery. At the Aquistore site, the CO2 will be injected into a brine-filled sandstone formation at ~3200 m depth using the deepest well in Saskatchewan. The suitability of the geological formations that will host the injected CO2 hasmore »been predetermined through 3D characterization using high-resolution 3D seismic images and deep well information. These data show that 1) there are no significant faults in the immediate area of the storage site, 2) the regional sealing formation is continuous in the area, and 3) the reservoir is not adversely affected by knolls on the surface of the underlying Precambrian basement. Furthermore, the Aquistore site is located within an intracratonic region characterized by extremely low levels of seismicity. This is in spite of oil-field related water injection in the nearby Weyburn-Midale field where a total of 656 million m3 of water have been injected since the 1960`s with no demonstrable related induced seismicity. A key element of the Aquistore research program is the further development of methods to monitor the security and subsurface distribution of the injected CO2. Toward this end, a permanent areal seismic monitoring array was deployed in 2012, comprising 630 vertical-component geophones installed at 20 m depth on a 2.5x2.5 km regular grid. This permanent array is designed to provide improved 3D time-lapse seismic imaging for monitoring subsurface CO2. Prior to the onset of CO2 injection, calibration 3D surveys were acquired in May and November of 2013. Comparison of the data from these surveys relative to the baseline 3D survey data from 2012 shows excellent repeatability (NRMS less than 10%) which will provide enhanced monitoring sensitivity to smaller amounts of CO2. The permanent array also provides continuous passive monitoring for injection-related microseismicity. Passive monitoring has been ongoing since the summer of 2012 in order to establish levels of background seismicity before CO2 injection starts in 2014. Microseismic monitoring was augmented in 2013 by the installation of 3 broadband seismograph stations surrounding the Aquistore site. These surface installations should provide a detection capability of seismic events with magnitudes as low as ~0. Downhole seismic methods are also being utilized for CO2 monitoring at the Aquistore site. Baseline crosswell tomographic images depict details (meters-scale) of the reservoir in the 150-m interval between the observation and injection wells. This level of resolution is designed to track the CO2 migration between the wells during the initial injection period. A baseline 3D vertical seismic profile (VSP) was acquired in the fall of 2013 to provide seismic images with resolution on a scale between that provided by the surface seismic array and the downhole tomography. The 3D VSP was recorded simultaneously using both a conventional array of downhole geophones (60-levels) and an optical fibre system. The latter utilized an optical fiber cable deployed on the outside of the monitor well casing and cemented in place. A direct comparison of these two methodologies will determine the suitability of using the fiber cable for ongoing time-lapse VSP monitoring.« less

  18. Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. Based on a range of well schemes, techno-economic analyses of the levelized cost of electricity (LCOE) are conducted to determine the economic benefits of integrating GCS with geothermal energy production. In addition to considering CO2 injection, reservoir analyses are conducted for nitrogen (N2) injection to investigate the potential benefits of incorporating N2 injection with integrated geothermal-GCS, as well as the use of N2 injection as a potential pressure-support and working-fluid option. Phase 1 includes preliminary environmental risk assessments of integrated geothermal-GCS, with the focus on managing reservoir overpressure. Phase 1 also includes an economic survey of pipeline costs, which will be applied in Phase 2 to the analysis of CO2 conveyance costs for techno-economics analyses of integrated geothermal-GCS reservoir sites. Phase 1 also includes a geospatial GIS survey of potential integrated geothermal-GCS reservoir sites, which will be used in Phase 2 to conduct sweet-spot analyses that determine where promising geothermal resources are co-located in sedimentary settings conducive to safe CO2 storage, as well as being in adequate proximity to large stationary CO2 sources.

  19. Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    2012-01-01

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. Based on a range of well schemes, techno-economic analyses of the levelized cost of electricity (LCOE) are conducted to determine the economic benefits of integrating GCS with geothermal energy production. In addition to considering CO2 injection, reservoir analyses are conducted for nitrogen (N2) injection to investigate the potential benefits of incorporating N2 injection with integrated geothermal-GCS, as well as the use of N2 injection as a potential pressure-support and working-fluid option. Phase 1 includes preliminary environmental risk assessments of integrated geothermal-GCS, with the focus on managing reservoir overpressure. Phase 1 also includes an economic survey of pipeline costs, which will be applied in Phase 2 to the analysis of CO2 conveyance costs for techno-economics analyses of integrated geothermal-GCS reservoir sites. Phase 1 also includes a geospatial GIS survey of potential integrated geothermal-GCS reservoir sites, which will be used in Phase 2 to conduct sweet-spot analyses that determine where promising geothermal resources are co-located in sedimentary settings conducive to safe CO2 storage, as well as being in adequate proximity to large stationary CO2 sources.

  20. Physical and Economic Potential of Geological CO2 Storage in Saline

    E-Print Network [OSTI]

    Jackson, Robert B.

    received November 10, 2008. Accepted January 5, 2009. Carbon sequestration in sandstone saline reservoirsPhysical and Economic Potential of Geological CO2 Storage in Saline Aquifers J O R D A N K . E C C L E S , * , L I N C O L N P R A T S O N , R I C H A R D G . N E W E L L , A N D R O B E R T B . J

  1. Basin-Scale Hydrologic Impacts of CO2 Storage: Regulatory and Capacity Implications

    SciTech Connect (OSTI)

    Birkholzer, J.T.; Zhou, Q.

    2009-04-02

    Industrial-scale injection of CO{sub 2} into saline sedimentary basins will cause large-scale fluid pressurization and migration of native brines, which may affect valuable groundwater resources overlying the deep sequestration reservoirs. In this paper, we discuss how such basin-scale hydrologic impacts can (1) affect regulation of CO{sub 2} storage projects and (2) may reduce current storage capacity estimates. Our assessment arises from a hypothetical future carbon sequestration scenario in the Illinois Basin, which involves twenty individual CO{sub 2} storage projects in a core injection area suitable for long-term storage. Each project is assumed to inject five million tonnes of CO{sub 2} per year for 50 years. A regional-scale three-dimensional simulation model was developed for the Illinois Basin that captures both the local-scale CO{sub 2}-brine flow processes and the large-scale groundwater flow patterns in response to CO{sub 2} storage. The far-field pressure buildup predicted for this selected sequestration scenario suggests that (1) the area that needs to be characterized in a permitting process may comprise a very large region within the basin if reservoir pressurization is considered, and (2) permits cannot be granted on a single-site basis alone because the near- and far-field hydrologic response may be affected by interference between individual sites. Our results also support recent studies in that environmental concerns related to near-field and far-field pressure buildup may be a limiting factor on CO{sub 2} storage capacity. In other words, estimates of storage capacity, if solely based on the effective pore volume available for safe trapping of CO{sub 2}, may have to be revised based on assessments of pressure perturbations and their potential impact on caprock integrity and groundwater resources, respectively. We finally discuss some of the challenges in making reliable predictions of large-scale hydrologic impacts related to CO{sub 2} sequestration projects.

  2. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and competency. The results from these investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological, deep subsurface CO2 storage and sequestration.

  3. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    A series of batch and column experiments combined with solid phase characterization studies (i.e., quantitative x-ray diffraction and wet chemical extractions) were conducted to address a variety of scientific issues and evaluate the impacts of the potential leakage of carbon dioxide (CO2) from deep subsurface storage reservoirs. The main objective was to gain an understanding of how CO2 gas influences: 1) the aqueous phase pH; and 2) mobilization of major, minor, and trace elements from minerals present in an aquifer overlying potential CO2 sequestration subsurface repositories. Rocks and slightly weathered rocks representative of an unconfined, oxidizing carbonate aquifer within the continental US, i.e., the Edwards aquifer in Texas, were used in these studies. These materials were exposed to a CO2 gas stream or were leached with a CO2-saturated influent solution to simulate different CO2 gas leakage scenarios, and changes in aqueous phase pH and chemical composition were measured in the liquid samples collected at pre-determined experimental times (batch experiments) or continuously (column experiments). The results from the strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the Edward aquifer samples contain As, Cd, Pb, Cu, and occasionally Zn, which may potentially be mobilized from the solid to the aqueous phase during or after exposure to CO2. The results from the batch and column experiments confirmed the release of major chemical elements into the contacting aqueous phase (such as Ca, Mg, Ba, Sr, Si, Na, and K); the mobilization and possible rapid immobilization of minor elements (such as Fe, Al, and Mn), which are able to form highly reactive secondary phases; and sporadic mobilization of only low concentrations of trace elements (such as As, Cd, Pb, Cu, Zn, Mo, etc.). The results from this experimental research effort will help in developing a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption) in the aquifer sediments and will support site selection, risk assessment, policy-making, and public education efforts associated with geologic carbon sequestration.

  4. Sensitivity study of CO2 storage capacity in brine aquifers withclosed boundaries: Dependence on hydrogeologic properties

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Rutqvist, J.; Tsang, C-F.

    2007-02-07

    In large-scale geologic storage projects, the injected volumes of CO{sub 2} will displace huge volumes of native brine. If the designated storage formation is a closed system, e.g., a geologic unit that is compartmentalized by (almost) impermeable sealing units and/or sealing faults, the native brine cannot (easily) escape from the target reservoir. Thus the amount of supercritical CO{sub 2} that can be stored in such a system depends ultimately on how much pore space can be made available for the added fluid owing to the compressibility of the pore structure and the fluids. To evaluate storage capacity in such closed systems, we have conducted a modeling study simulating CO{sub 2} injection into idealized deep saline aquifers that have no (or limited) interaction with overlying, underlying, and/or adjacent units. Our focus is to evaluate the storage capacity of closed systems as a function of various reservoir parameters, hydraulic properties, compressibilities, depth, boundaries, etc. Accounting for multi-phase flow effects including dissolution of CO{sub 2} in numerical simulations, the goal is to develop simple analytical expressions that provide estimates for storage capacity and pressure buildup in such closed systems.

  5. Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    2000-01-01

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

  6. Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    2012-01-01

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

  7. Integrated Geothermal-CO2 Storage Reservoirs: FY1 Final Report

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    2012-01-01

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

  8. Integrated Geothermal-CO2 Storage Reservoirs: FY1 Final Report

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

  9. Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

  10. Mathematical models as tools for probing long-term safety of CO2 storage

    E-Print Network [OSTI]

    Pruess, Karsten

    2010-01-01

    Interactions at the Supercritical CO2–liquid InterfaceProperties of the Supercritical CO2–Water Pure Interface, J.

  11. Intercomparison of simulation models for CO2 disposal in underground storage reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten; Tsang, Chin-Fu; Law, David; Oldenburg, Curt

    2001-01-01

    experience with using CO2 for EOR projects (SPE, 1999), andoil recovery (EOR) using CO2 requires an understanding of

  12. 2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses

    E-Print Network [OSTI]

    Firestone, Jeremy

    2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses 4] We develop methods for assessing offshore wind 9 resources, using a model of the vertical structure. Dhanju, R. W. 26 Garvine, and M. Z. Jacobson (2007), Large CO2 reductions via 27 offshore wind power

  13. Alabama Project Testing Potential for Combining CO2 Storage with Enhanced

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment| DepartmentAL/FALGeologic CO2 Storage | Department of Energy

  14. Numerical Modeling Studies of The Dissolution-Diffusion-Convection ProcessDuring CO2 Storage in Saline Aquifers

    SciTech Connect (OSTI)

    Pruess, Karsten; Zhang, Keni

    2008-11-17

    For purposes of geologic storage, CO2 would be injected into saline formations at supercritical temperature and pressure conditions, and would form a separate phase that is immiscible with the aqueous phase (brine). At typical subsurface temperature and pressure conditions, supercritical CO2 (scCO2) has lower density than the aqueous phase and would experience an upward buoyancy force. Accordingly, the CO2 is expected to accumulate beneath the caprock at the top of the permeable interval, and could escape from the storage formation wherever (sub-)vertical pathways are available, such as fractures or faults through the caprock, or improperly abandoned wells. Over time, an increasing fraction of CO2 may dissolve in the aqueous phase, and eventually some of the aqueous CO2 may react with rock minerals to form poorly soluble carbonates. Dissolution into the aqueous phase and eventual sequestration as carbonates are highly desirable processes as they would increase permanence and security of storage. Dissolution of CO2 will establish phase equilibrium locally between the overlying CO2 plume and the aqueous phase beneath. If the aqueous phase were immobile, CO2 dissolution would be limited by the rate at which molecular diffusion can remove dissolved CO2 from the interface between CO2-rich and aqueous phases. This is a slow process. However, dissolution of CO2 is accompanied by a small increase in the density of the aqueous phase, creating a negative buoyancy force that can give rise to downward convection of CO2-rich brine, which in turn can greatly accelerate CO2 dissolution. This study explores the process of dissolution-diffusion-convection (DDC), using high-resolution numerical simulation. We find that geometric features of convection patterns are very sensitive to small changes in problem specifications, reflecting self-enhancing feedbacks and the chaotic nature of the process. Total CO2 dissolution rates on the other hand are found to be quite robust against modest changes in problem parameters, and are essentially constant as long as no dissolved CO2 reaches the lower boundary of the system.

  15. Energy Policy 34 (2006) 395410 The economics of large-scale wind power in a carbon

    E-Print Network [OSTI]

    Barlaz, Morton A.

    2006-01-01

    Energy Policy 34 (2006) 395­410 The economics of large-scale wind power in a carbon constrained to supplement variable wind power output to meet a time-varying load. We find that, with somewhat optimistic cost of delivered wind power. Due to residual CO2 emissions, compressed air storage is surprisingly

  16. NETL's 2015 Carbon Storage Atlas Shows Increase in U.S. CO2 Storage...

    Energy Savers [EERE]

    September 28, 2015 - 9:49am Addthis The U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) today released the fifth edition of the Carbon Storage...

  17. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Energy Concept Utilizing Supercritical CO2 Instead of Water,Feasibility of Using Supercritical CO2 as Heat Transmissionsupercritical CO 2 and rock minerals. Studies of geochemical interactions in EGS-CO2

  18. Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater

    E-Print Network [OSTI]

    Birkholzer, Jens

    2008-01-01

    Changes in Response to CO2 Leakage from Deep Geologicalstudy mineral trapping for CO2 disposal in deep arenaceousconstituents as function of P(CO2)? function of P(CO2)? – –

  19. Large CO2 reductions via offshore wind power matched to inherent storage in energy end-uses

    E-Print Network [OSTI]

    Large CO2 reductions via offshore wind power matched to inherent storage in energy end-uses Willett develop methods for assessing offshore wind resources, using a model of the vertical structure offshore wind power matched to inherent storage in energy end- uses, Geophys. Res. Lett., 34, L02817, doi

  20. Characterization of Pliocene and Miocene Formations in the Wilmington Graben, Offshore Los Angeles, for Large-Scale Geologic Storage of CO?

    SciTech Connect (OSTI)

    Bruno, Michael

    2014-12-08

    Geomechanics Technologies has completed a detailed characterization study of the Wilmington Graben offshore Southern California area for large-scale CO? storage. This effort has included: an evaluation of existing wells in both State and Federal waters, field acquisition of about 175 km (109 mi) of new seismic data, new well drilling, development of integrated 3D geologic, geomechanics, and fluid flow models for the area. The geologic analysis indicates that more than 796 MMt of storage capacity is available within the Pliocene and Miocene formations in the Graben for midrange geologic estimates (P50). Geomechanical analyses indicate that injection can be conducted without significant risk for surface deformation, induced stresses or fault activation. Numerical analysis of fluid migration indicates that injection into the Pliocene Formation at depths of 1525 m (5000 ft) would lead to undesirable vertical migration of the CO? plume. Recent well drilling however, indicates that deeper sand is present at depths exceeding 2135 m (7000 ft), which could be viable for large volume storage. For vertical containment, injection would need to be limited to about 250,000 metric tons per year per well, would need to be placed at depths greater than 7000ft, and would need to be placed in new wells located at least 1 mile from any existing offset wells. As a practical matter, this would likely limit storage operations in the Wilmington Graben to about 1 million tons per year or less. A quantitative risk analysis for the Wilmington Graben indicate that such large scale CO? storage in the area would represent higher risk than other similar size projects in the US and overseas.

  1. No geologic evidence that seismicity causes fault leakage that would render large-scale carbon capture and storage unsuccessful

    E-Print Network [OSTI]

    Juanes, Ruben

    In a recent Perspective (1), Zoback and Gorelick argued that carbon capture and storage (CCS) is likely not a viable strategy for reducing CO[subscript 2] emissions to the atmosphere. They argued that maps of earthquake ...

  2. A Stable Vanadium Redox-Flow Battery with High Energy Density for Large-scale Energy Storage

    SciTech Connect (OSTI)

    Li, Liyu; Kim, Soowhan; Wang, Wei; Vijayakumar, M.; Nie, Zimin; Chen, Baowei; Zhang, Jianlu; Xia, Guanguang; Hu, Jian Z.; Graff, Gordon L.; Liu, Jun; Yang, Zhenguo

    2011-05-01

    Low cost, high performance redox flow batteries are highly demanded for up to multi-megawatt levels of renewable and grid energy storage. Here, we report a new vanadium redox flow battery with a significant improvement over the current technologies. This new battery utilizes a sulfate-chloride mixed solution, which is capable of dissolving more than 2.5 M vanadium or about a 70% increase in the energy storage capacity over the current vanadium sulfate system. More importantly, the new electrolyte remains stable over a wide temperature range of -5 to 60oC, potentially eliminating the need of active heat management. Its high energy density, broad operational temperature window, and excellent electrochemical performance would lead to a significant reduction in the cost of energy storage, thus accelerating its market penetration.

  3. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Supercritical CO 2 as Heat Transmission Fluid in the EGSof Using Supercritical CO2 as Heat Transmission Fluid in anEGS) with CO 2 as Heat Transmission Fluid - A Scheme for

  4. Estimating the supply and demand for deep geologic CO2 storage capacity over the course of the 21st Century: A meta-analysis of the literature

    SciTech Connect (OSTI)

    Dooley, James J.

    2013-08-05

    Whether there is sufficient geologic CO2 storage capacity to allow CCS to play a significant role in mitigating climate change has been the subject of debate since the 1990s. This paper presents a meta- analysis of a large body of recently published literature to derive updated estimates of the global deep geologic storage resource as well as the potential demand for this geologic CO2 storage resource over the course of this century. This analysis reveals that, for greenhouse gas emissions mitigation scenarios that have end-of-century atmospheric CO2 concentrations of between 350 ppmv and 725 ppmv, the average demand for deep geologic CO2 storage over the course of this century is between 410 GtCO2 and 1,670 GtCO2. The literature summarized here suggests that -- depending on the stringency of criteria applied to calculate storage capacity – global geologic CO2 storage capacity could be: 35,300 GtCO2 of “theoretical” capacity; 13,500 GtCO2 of “effective” capacity; 3,900 GtCO2, of “practical” capacity; and 290 GtCO2 of “matched” capacity for the few regions where this narrow definition of capacity has been calculated. The cumulative demand for geologic CO2 storage is likely quite small compared to global estimates of the deep geologic CO2 storage capacity, and therefore, a “lack” of deep geologic CO2 storage capacity is unlikely to be an impediment for the commercial adoption of CCS technologies in this century.

  5. Leakage Risk Assessment for a Potential CO2 Storage Project in Saskatchewan, Canada

    E-Print Network [OSTI]

    Houseworth, J.E.

    2012-01-01

    Framework Leakage Risk Assessment for a Potential CO 2Risk Assessment..confidence in the risk assessment. . Potential Sequestration

  6. Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong, David W. Keith

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs Minh Ha-Duong, David W. Keith Abstract Fossil fuels can be used with minimal atmo- spheric emissions of carbon dioxide, the cost of sequestration and the energy penalty (the energy necessary to capture, transport and inject

  7. 2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses

    E-Print Network [OSTI]

    Firestone, Jeremy

    2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses 4 by matching the winds of the 14 Middle-Atlantic Bight (MAB) to energy demand in the 15 adjacent states] We develop methods for assessing offshore wind 9 resources, using a model of the vertical structure

  8. Hydro-mechanical modelling of geological CO2 storage and the study of possible caprock fracture mechanisms

    E-Print Network [OSTI]

    element modelling of a hypothetical underground carbon dioxide (CO2) storage operation. The hydro-mechanical properties of the materials modelled are chosen to be representative of a potential injection site. For high on the injection process, and on site and rock properties. Rutqvist et al. (2008) showed through a coupled

  9. Impact of Sorption Isotherms on the Simulation of CO2-Enhanced Gas Recovery and Storage Process in Marcellus Shale

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Continuous, low-permeability, fractured, organic-rich gas shale units are widespread and are possible, organic-rich rocks that are both the source and trap for natural gas (primarily methane). In shale gas1 Impact of Sorption Isotherms on the Simulation of CO2-Enhanced Gas Recovery and Storage Process

  10. Organo-sulfur molecules enable iron-based battery electrodes to meet the challenges of large-scale electrical energy storage

    SciTech Connect (OSTI)

    Yang, B; Malkhandi, S; Manohar, AK; Prakash, GKS; Narayanan, SR

    2014-07-03

    Rechargeable iron-air and nickel-iron batteries are attractive as sustainable and inexpensive solutions for large-scale electrical energy storage because of the global abundance and eco-friendliness of iron, and the robustness of iron-based batteries to extended cycling. Despite these advantages, the commercial use of iron-based batteries has been limited by their low charging efficiency. This limitation arises from the iron electrodes evolving hydrogen extensively during charging. The total suppression of hydrogen evolution has been a significant challenge. We have found that organo-sulfur compounds with various structural motifs (linear and cyclic thiols, dithiols, thioethers and aromatic thiols) when added in milli-molar concentration to the aqueous alkaline electrolyte, reduce the hydrogen evolution rate by 90%. These organo-sulfur compounds form strongly adsorbed layers on the iron electrode and block the electrochemical process of hydrogen evolution. The charge-transfer resistance and double-layer capacitance of the iron/electrolyte interface confirm that the extent of suppression of hydrogen evolution depends on the degree of surface coverage and the molecular structure of the organo-sulfur compound. An unanticipated electrochemical effect of the adsorption of organo-sulfur molecules is "de-passivation" that allows the iron electrode to be discharged at high current values. The strongly adsorbed organo-sulfur compounds were also found to resist electro-oxidation even at the positive electrode potentials at which oxygen evolution can occur. Through testing on practical rechargeable battery electrodes we have verified the substantial improvements to the efficiency during charging and the increased capability to discharge at high rates. We expect these performance advances to enable the design of efficient, inexpensive and eco-friendly iron-based batteries for large-scale electrical energy storage.

  11. Locations of Smart Grid Demonstration and Large-Scale Energy...

    Office of Environmental Management (EM)

    Locations of Smart Grid Demonstration and Large-Scale Energy Storage Projects Locations of Smart Grid Demonstration and Large-Scale Energy Storage Projects Map of the United States...

  12. Using the Choquet integral for screening geological CO2 storage sites

    E-Print Network [OSTI]

    Zhang, Y.

    2012-01-01

    interpretation of the Choquet integral. IEEE Transactions onUsing the Choquet integral for screening geological CO 2the use of the Choquet integral for aggregating the scores.

  13. Why we need the and in CO2 utilization and storage.

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2013-01-01

    the output of a 750 MW coal- fired power plant. CO 2 -EOR3 or the output of six 1-GW coal-fired power plants. Urea

  14. Why we need the and in CO2 utilization and storage.

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2013-01-01

    output of a 750 MW coal- fired power plant. CO 2 -EOR withinoutput of six 1-GW coal-fired power plants. Urea production

  15. Effects of Increased Upward Flux of Saline Water Caused by CO2 Storage or Other Factors

    SciTech Connect (OSTI)

    Murdoch, Lawrence; Xie, Shuang; Falta, Ronald W.; Yonkofski, Catherine MR

    2015-08-01

    Injection of CO2 in deep saline aquifers is being considered to reduce greenhouse gases in the atmosphere, and this process is expected to increase the pressure in these deep aquifers. One potential consequence of pressurization is an increase in the upward flux of saline water. Saline groundwater occurs naturally at shallow depths in many sedimentary basins, so an upward flux of solutes could degrade the quality of freshwater aquifers and threaten aquatic ecosystems. One problem could occur where saline water flowed upward along preferential paths, like faults or improperly abandoned wells. Diffuse upward flow through the natural stratigraphy could also occur in response to basin pressurization. This process would be slower, but diffuse upward flow could affect larger areas than flow through preferential paths, and this motivated us to evaluate this process. We analyzed idealized 2D and 3D geometries representing the essential details of a shallow, freshwater aquifer underlain by saline ground water in a sedimentary basin. The analysis was conducted in two stages, one that simulated the development of a freshwater aquifer by flushing out saline water, and another that simulated the effect of a pulse-like increase in the upward flux from the basin. The results showed that increasing the upward flux from a basin increased the salt concentration and mass loading of salt to streams, and decrease the depth to the fresh/salt transition. The magnitude of these effects varied widely, however, from a small, slow process that would be challenging to detect, to a large, rapid response that could be an environmental catastrophe. The magnitude of the increased flux, and the initial depth to the fresh/salt transition in groundwater controlled the severity of the response. We identified risk categories for salt concentration, mass loading, and freshwater aquifer thickness, and we used these categories to characterize the severity of the response. This showed that risks would likely be minor if the upward flux was smaller than a few tenths of the magnitude of recharge, according to the 2D analyses. The 3D analyses also show that upward flux could occur without a significant increase in the risk categories. The major contribution of this work is that it shows how a large increase in diffuse upward flux from a basin could cause significant problems, but a small increase in upward flux may occur without significantly affecting risks to the shallow freshwater flow system. This heightens the importance of understanding interactions between shallow and deep hydrologic systems when characterizing CO2 storage projects.

  16. Utilization of CO2 as cushion gas for porous media compressed air energy storage

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2014-01-01

    of compressed air energy storage electric power systems.RH, Compressed Air Energy Storage: Theory, Resources, andmedia compressed air energy storage (PM-CAES): theory and

  17. Mathematical models as tools for probing long-term safety of CO2 storage

    E-Print Network [OSTI]

    Pruess, Karsten

    2010-01-01

    and depth, and proximity to gas storage fields as well as toof oil and gas production and storage, geothermal energyfor the Storage of Greenhouse Gases in Sedimentary Basins,

  18. Modeling basin- and plume-scale processes of CO2 storage for full-scale deployment

    E-Print Network [OSTI]

    Zhou, Q.

    2010-01-01

    models of Mt. Simon gas storage fields in the Illinoiscaprock in aquifer gas storage, 1: Caprock of infiniteEvaluation of underground gas storage conditions in aquifers

  19. Basin-Scale Hydrologic Impacts of CO2 Storage: Regulatory and Capacity Implications

    E-Print Network [OSTI]

    Birkholzer, J.T.

    2009-01-01

    depth, minimum distance to gas storage fields, and proximityof which from natural gas storage and groundwater resourcesin the Hudson natural gas storage field in 1969 (ISWS and

  20. Running Large Scale Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    try on their large scale applications on Hopper for better performance. Try different compilers and compiler options The available compilers on Hopper are PGI, Cray, Intel, GNU,...

  1. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01

    capture of CO 2 from gasifier process producing electricalPlaquemine, Louisiana. The gasifier is a proprietary designGasifier .

  2. Estimating nocturnal ecosystem respiration from the vertical turbulent flux and change in storage of CO2

    SciTech Connect (OSTI)

    Gu, Lianhong; Van Gorsel, Eva; Leuning, Ray; Delpierre, Nicolas; Black, Andy; Chen, Baozhang; Munger, J. William; Wofsy, Steve; Aubinet, M.

    2009-11-01

    Micrometeorological measurements of nighttime ecosystem respiration can be systematically biased when stable atmospheric conditions lead to drainage flows associated with decoupling of air flow above and within plant canopies. The associated horizontal and vertical advective fluxes cannot be measured using instrumentation on the single towers typically used at micrometeorological sites. A common approach to minimize bias is to use a threshold in friction velocity, u*, to exclude periods when advection is assumed to be important, but this is problematic in situations when in-canopy flows are decoupled from the flow above. Using data from 25 flux stations in a wide variety of forest ecosystems globally, we examine the generality of a novel approach to estimating nocturnal respiration developed by van Gorsel et al. (van Gorsel, E., Leuning, R., Cleugh, H.A., Keith, H., Suni, T., 2007. Nocturnal carbon efflux: reconciliation of eddy covariance and chamber measurements using an alternative to the u*-threshold filtering technique. Tellus 59B, 397 403, Tellus, 59B, 307-403). The approach is based on the assumption that advection is small relative to the vertical turbulent flux (FC) and change in storage (FS) of CO2 in the few hours after sundown. The sum of FC and FS reach a maximum during this period which is used to derive a temperature response function for ecosystem respiration. Measured hourly soil temperatures are then used with this function to estimate respiration RRmax. The new approach yielded excellent agreement with (1) independent measurements using respiration chambers, (2) with estimates using ecosystem light-response curves of Fc + Fs extrapolated to zero light, RLRC, and (3) with a detailed process-based forest ecosystem model, Rcast. At most sites respiration rates estimated using the u*-filter, Rust, were smaller than RRmax and RLRC. Agreement of our approach with independent measurements indicates that RRmax provides an excellent estimate of nighttime ecosystem respiration

  3. Investigation of CO2 plume behavior for a large-scale pilot test of geologic carbon storage in a saline formation

    SciTech Connect (OSTI)

    Doughty, C.

    2009-04-01

    The hydrodynamic behavior of carbon dioxide (CO{sub 2}) injected into a deep saline formation is investigated, focusing on trapping mechanisms that lead to CO{sub 2} plume stabilization. A numerical model of the subsurface at a proposed power plant with CO{sub 2} capture is developed to simulate a planned pilot test, in which 1,000,000 metric tons of CO{sub 2} is injected over a four-year period, and the subsequent evolution of the CO{sub 2} plume for hundreds of years. Key measures are plume migration distance and the time evolution of the partitioning of CO{sub 2} between dissolved, immobile free-phase, and mobile free-phase forms. Model results indicate that the injected CO{sub 2} plume is effectively immobilized at 25 years. At that time, 38% of the CO{sub 2} is in dissolved form, 59% is immobile free phase, and 3% is mobile free phase. The plume footprint is roughly elliptical, and extends much farther up-dip of the injection well than down-dip. The pressure increase extends far beyond the plume footprint, but the pressure response decreases rapidly with distance from the injection well, and decays rapidly in time once injection ceases. Sensitivity studies that were carried out to investigate the effect of poorly constrained model parameters permeability, permeability anisotropy, and residual CO{sub 2} saturation indicate that small changes in properties can have a large impact on plume evolution, causing significant trade-offs between different trapping mechanisms.

  4. Research project on CO2 geological storage and groundwater resources: Large-scale hydrological evaluation and modeling of impact on groundwater systems

    E-Print Network [OSTI]

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan, Preston; Zhang, K.; Tsang, Chin-Fu

    2008-01-01

    1995. 1995 National Oil and Gas Assessment: Sacramento BasinNational assessment of United States oil and gas resources -

  5. Research project on CO2 geological storage and groundwater resources: Large-scale hydrological evaluation and modeling of impact on groundwater systems

    E-Print Network [OSTI]

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan, Preston; Zhang, K.; Tsang, Chin-Fu

    2008-01-01

    Report, Midwest Regional Carbon Sequestration Partnership.West Coast Regional Carbon Sequestration Partnership, Final

  6. Investigation of CO2 plume behavior for a large-scale pilot test of geologic carbon storage in a saline formation

    E-Print Network [OSTI]

    Doughty, C.

    2010-01-01

    as sand permeability, shale permeability, and residual gasb) shale vertical permeability; and (c) residual gasNo shale k x = k y = k z = 200 md Residual Gas Saturation

  7. Investigation of CO2 plume behavior for a large-scale pilot test of geologic carbon storage in a saline formation

    E-Print Network [OSTI]

    Doughty, C.

    2010-01-01

    of 15 o C and a geothermal gradient of 30 o C per km, bothgradients and geothermal temperature gradients, free-phase1 + 0.1 z and a geothermal temperature gradient T(z) = 15 +

  8. Investigation of CO2 Plume Behavior for a Large-Scale Pilot Test of Geologic Carbon Storage in a Saline Formation

    E-Print Network [OSTI]

    Doughty, Christine

    2010-01-01

    of 15 ? C and a geothermal gradient of 30 ? C per km, bothgradients and geothermal temperature gradients, free- phase1 + 0.1 z and a geothermal temperature gradient T (z) = 15 +

  9. DOE Research Projects to Examine Promising Geologic Formations for CO2 Storage

    Broader source: Energy.gov [DOE]

    The Department of Energy today announced 11 projects valued at $75.5 million aimed at increasing scientific understanding about the potential of promising geologic formations to safely and permanently store carbon dioxide (CO2).

  10. Leakage of CO2 from geologic storage: Role of secondary accumulation at shallow depth

    E-Print Network [OSTI]

    Pruess, K.

    2008-01-01

    of CO 2 discharge behavior to the geothermal gradient.in a typical crustal geothermal gradient of 0.03 ?C/m, for ain an ambient geothermal gradient. Geothermal gradients in

  11. Synthetic Catalysts for CO2 Storage: Catalytic Improvement of Solvent Capture Systems

    SciTech Connect (OSTI)

    None

    2010-08-15

    IMPACCT Project: LLNL is designing a process to pull CO2 out of the exhaust gas of coal-fired power plants so it can be transported, stored, or utilized elsewhere. Human lungs rely on an enzyme known as carbonic anhydrase to help separate CO2 from our blood and tissue as part of the normal breathing process. LLNL is designing a synthetic catalyst with the same function as this enzyme. The catalyst can be used to quickly capture CO2 from coal exhaust, just as the natural enzyme does in our lungs. LLNL is also developing a method of encapsulating chemical solvents in permeable microspheres that will greatly increase the speed of binding of CO2. The goal of the project is an industry-ready chemical vehicle that can withstand the harsh environments found in exhaust gas and enable new, simple process designs requiring less capital investment.

  12. New Strategies for Finding Abandoned Wells at Proposed Geologic Storage Sites for CO2

    SciTech Connect (OSTI)

    Hammack, R.W.; Veloski, G.A.

    2007-09-01

    Prior to the injection of CO2 into geological formations, either for enhanced oil recovery or for CO2 sequestration, it is necessary to locate wells that perforate the target formation and are within the radius of influence for planned injection wells. Locating and plugging wells is necessary because improperly plugged well bores provide the most rapid route for CO2 escape to the surface. This paper describes the implementation and evaluation of helicopter and ground-based well detection strategies at a 100+ year old oilfield in Wyoming where a CO2 flood is planned. This project was jointly funded by the U.S. Department of Energy’s National Energy Technology Laboratory and Fugro Airborne Surveys.

  13. Utilization of CO2 as cushion gas for porous media compressed air energy storage

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2014-01-01

    cushion gas for natural gas storage. Energy&Fuels 17:240-246gas in underground natural gas storage. Soc Petrol Eng SPE-from aquifers used for gas storage. J Inst Petrol 48:457 (

  14. Mathematical models as tools for probing long-term safety of CO2 storage

    E-Print Network [OSTI]

    Pruess, Karsten

    2010-01-01

    Issue on Site Characterization for Geological Storage ofgeological model needs to be acknowledged. Further site characterization

  15. Using the Choquet integral for screening geological CO2 storage sites

    E-Print Network [OSTI]

    Zhang, Y.

    2012-01-01

    reservoirs, deep saline aquifers, and in salt caverns. 1 Before a detailed storage site characterization

  16. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Interactions in Enhanced Geothermal Systems (EGS) with CO 2Fluid, Proceedings, World Geothermal Congress 2010, Bali,Remain? Transactions, Geothermal Resources Council, Vol. 17,

  17. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01

    A Review of Hazardous Chemical Species Associated with CO 2the inventory of most hazardous trace elements are capturedequilibrium concentrations of hazardous trace elements in

  18. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Interactions in Enhanced Geothermal Systems (EGS) with CO 2of Enhanced Geothermal Systems? , paper presented at Thirdfrom Enhanced Geothermal Systems, Proceedings, Paper

  19. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    in Enhanced Geothermal Systems (EGS) with CO 2 as WorkingTransmission Fluid in the EGS Integrating the Carbon Storageand F. Rummel. The Deep EGS (Enhanced Geothermal System)

  20. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Interactions in Enhanced Geothermal Systems (EGS) with CO 2with the Development of Enhanced Geothermal Systems? , paperProspects from Enhanced Geothermal Systems, Proceedings,

  1. Numerical Modeling Studies of The Dissolution-Diffusion-Convection Process During CO2 Storage in Saline Aquifers

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01

    Properties of the Supercritical CO2–Water Pure Interface, J.and pressure conditions, supercritical CO2 (scCO2) has lowerthe overlying free supercritical CO2 phase. This is modeled

  2. Physics and Seismic Modeling for Monitoring CO2 Storage JOSE M. CARCIONE,1

    E-Print Network [OSTI]

    Santos, Juan

    -elastical equations model the seismic properties of reservoir rocks saturated with CO2, methane, oil and brine. The gas properties are obtained from the van der Waals equation and we take into account the absorption, methane-bearing coal beds and saline aquifers. An example of the latter is the Sleipner field in the North

  3. Abstract Rising atmospheric CO2 may stimulate future forest productivity, possibly increasing carbon storage

    E-Print Network [OSTI]

    solution (DOC) were monitored biweekly. Soil respiration was measured with a portable infrared gas analyzer. Soil pCO2 and DOC samples were collected from soil gas wells and tension lysimeters, respectively; Ceulemans et al. 1999). Productivity may be further stimulated by nitrogen (N) deposition (Galloway et al

  4. A quantitative comparison of the cost of employing EOR-coupled CSS supplemented with secondary DSF storage for two large CO2 point sources

    SciTech Connect (OSTI)

    Davidson, Casie L.; Dahowski, Robert T.; Dooley, James J.

    2011-04-18

    This paper explores the impact of the temporally dynamic demand for CO2 for enhanced hydrocarbon recovery with CO2 storage. Previous evaluations of economy-wide CO2 capture and geologic storage (CCS) deployment have typically applied a simplifying assumption that 100% of the potential storage capacity for a given formation is available on the first day of the analysis, and that the injection rate impacts only the number of wells required to inject a given volume of fluid per year, making it a cost driver rather than a technical one. However, as discussed by Dahowski and Bachu [1], storing CO2 in a field undergoing CO2 flooding for enhanced oil recovery (EOR) is subject to a set of constraints to which storage in DSFs is not, and these constraints combined with variable demand for CO2 may strongly influence the ability of an EOR field to serve as a baseload storage formation for commercial scale CCS projects undertaken as a means of addressing climate change mitigation targets. This analysis assumes that CCS is being undertaken in order to reduce CO2 emissions from the industrial sources evaluated and that there is enough of a disincentive associated with venting CO2 to the atmosphere that any CO2 not used within the EOR field will be stored in a suitable nearby deep saline formation (DSF). The authors have applied a CO2 demand profile to two cases chosen to illustrate the differences in cost impacts of employing EOR-based CCS as a part of a given source’s CCS portfolio. The first scenario is a less-than-ideal case in which a single EOR field is used for storage and all CO2 not demanded by the EOR project is stored in a DSF; the second scenario is designed to optimize costs by minimizing storage in the DSF and maximizing lower-cost EOR-based storage. Both scenarios are evaluated for two facilities emitting 3 and 6 MtCO2/y, corresponding to a natural gas processing facility and an IGCC electric power plant, respectively. Annual and lifetime average CO2 transport and storage costs are presented, and the impact of added capture and compression costs on overall project economics is examined.

  5. Tagging CO2 to Enable Quantitative Inventories of Geological Carbon Storage

    SciTech Connect (OSTI)

    Lackner, Klaus; Matter, Juerg; Park, Ah-Hyung; Stute, Martin; Carson, Cantwell; Ji, Yinghuang

    2014-06-30

    In the wake of concerns about the long term integrity and containment of sub-surface CO2 sequestration reservoirs, many efforts have been made to improve the monitoring, verification, and accounting methods for geo-sequestered CO2. Our project aimed to demonstrate the feasibility of a system designed to tag CO2 with carbon isotope 14C immediately prior to sequestration to a level that is normal on the surface (one part per trillion). Because carbon found at depth is naturally free of 14C, this tag would easily differentiate pre-existing carbon from anthropogenic injected carbon and provide an excellent handle for monitoring its whereabouts in the subsurface. It also creates an excellent handle for adding up anthropogenic carbon inventories. Future inventories in effect count 14C atoms. Accordingly, we have developed a 14C tagging system suitable for use at the part-per-trillion level. This system consists of a gas-exchange apparatus to make disposable cartridges ready for controlled injection into a fast flowing stream of pressurized CO2. We built a high-pressure injection and tagging system, and a 14C detection system. The disposable cartridge and injection system have been successfully demonstrated in the lab with a high-pressure flow reactor, as well as in the field at the CarbFix CO2 sequestration site in Iceland. The laser-based 14C detection system originally conceived has been shown to possess inadequate sensitivity for ambient levels. Alternative methods for detecting 14C, such as saturated cavity absorption ringdown spectroscopy and scintillation counting, may still be suitable. KEYWORDS

  6. Evaluation of the Nordland Group overburden as an effective seal for the Sleipner CO2 storage site (offshore Norway) using analytical and stochastic modelling techniques 

    E-Print Network [OSTI]

    Nicoll, Grant Douglas

    2012-11-29

    Saline aquifers and depleted hydrocarbon fields situated beneath the North Sea are currently being proposed as storage repositories for anthropogenic CO2 captured from point source emitters in the UK and mainland Europe. ...

  7. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    effects on heat extraction rates and the water content ofof heat extraction for CO 2 and water- based systems, we hadover water-based systems, including larger heat extraction

  8. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01

    such alternative recovery technologies: Coal combustion inCOAL FIRED POWER PLANTS .. 5 2.2.1 MEA CO 2 Recovery..Recovery .7 2.2.4 Discussion ..8 2.3 STATE-OF-ART IGCC COAL-

  9. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    An Analysis of Power Generation Prospects from Enhancedfor Competitive Geothermal Power Generation, Energy & Fuels,1,000 MWe of EGS-CO 2 power generation would amount to the

  10. A Framework for Environmental Assessment of CO2 Capture and Storage Systems

    E-Print Network [OSTI]

    Sathre, Roger

    2013-01-01

    of a pulverized coal power plant with post-combustionand storage of coal power plants. Energy Policy 2010; 38(Existing Pulverized Coal (EXPC) Power Plant. Report Number

  11. 24/02/2012 12:49SPE Projects, Facilities & Construction -CO2/Brine Surface Dissolution and Injection: CO2 Storage Enhancement Page 1 of 1http://www.spe.org/ejournals/jsp/journalapp.jsp?pageType=Preview&jid=EFC&pdfChronicleId=090147628022501b&mid=SPE-12471

    E-Print Network [OSTI]

    Haszeldine, Stuart

    Strategies, Climate Change, Leakage Risk Mitigation Summary Carbon capture and storage (CCS) is capable.1.5 Processing Equipment Keywords CO2 Capture and Storage, Process Design and Simulation, CO2 Injection of dense-phase carbon dioxide (CO2) in deep reservoirs means that sites need to be chosen

  12. SPE -124703 Process for tracking the evolving perception of risk during CO2 storage

    E-Print Network [OSTI]

    the pressure on all nations to reduce emissions of greenhouse gases. Carbon capture and storage (CCS, primarily power plants, is captured and transported to a storage site where it is injective into the Earth. Carbon dioxide injected into deep geological formations will initially be more buoyant than the existing

  13. Using Pressure and Volumetric Approaches to Estimate CO2 Storage Capacity in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Thibeau, Sylvain; Bachu, Stefan; Birkholzer, Jens; Holloway, Sam; Neele, Filip; Zhou, Quanlin

    2014-12-31

    Various approaches are used to evaluate the capacity of saline aquifers to store CO2, resulting in a wide range of capacity estimates for a given aquifer. The two approaches most used are the volumetric “open aquifer” and “closed aquifer” approaches. We present four full-scale aquifer cases, where CO2 storage capacity is evaluated both volumetrically (with “open” and/or “closed” approaches) and through flow modeling. These examples show that the “open aquifer” CO2 storage capacity estimation can strongly exceed the cumulative CO2 injection from the flow model, whereas the “closed aquifer” estimates are a closer approximation to the flow-model derived capacity. An analogy to oil recovery mechanisms is presented, where the primary oil recovery mechanism is compared to CO2 aquifer storage without producing formation water; and the secondary oil recovery mechanism (water flooding) is compared to CO2 aquifer storage performed simultaneously with extraction of water for pressure maintenance. This analogy supports the finding that the “closed aquifer” approach produces a better estimate of CO2 storage without water extraction, and highlights the need for any CO2 storage estimate to specify whether it is intended to represent CO2 storage capacity with or without water extraction.

  14. Numerical Modeling Studies of The Dissolution-Diffusion-Convection Process During CO2 Storage in Saline Aquifers

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01

    boundary concentration (CO2 mass fraction) X 0 , applied atcorresponds a dissolved CO2 mass fraction of X = 0.0236 atFigure 7. Dissolved CO2 mass fractions near the top of the

  15. High Resolution Simulation and Characterization of Density-Driven Flow in CO2 Storage in Saline Aquifers

    E-Print Network [OSTI]

    are routinely used to study the process of carbon dioxide (CO2) sequestration in saline aquifers. In this paper TOUGH2-MP. 1. Introduction Geologic carbon dioxide (CO2) sequestration involves injecting CO2

  16. Energy Department Applauds Nation's First Large-Scale Industrial...

    Office of Environmental Management (EM)

    Large-Scale Industrial Carbon Capture, Storage Plant Begins Construction The 15,000 square-foot sustainably designed National Sequestration Education Center, located at Richland...

  17. Energy Department Applauds Nation's First Large-Scale Industrial...

    Broader source: Energy.gov (indexed) [DOE]

    today's groundbreaking for construction of the nation's first large-scale industrial carbon capture and storage (ICCS) facility in Decatur, Illinois. Supported by the 2009...

  18. Pressure Buildup and Brine Migration During CO2 Storage in Multilayered Aquifers

    E-Print Network [OSTI]

    Zhou, Quanlin

    of resident brine caused by CCS operations require modeling/analysis tools of considerable complexity (Celia and may allow for effective pressure bleed-off in the storage reservoirs. This study presents, for uncertainty quantification, for parameter estimation, or for the optimization of pressure-management schemes

  19. New DOE-Sponsored Study Helps Advance Scientific Understanding of Potential CO2 Storage Impacts

    Broader source: Energy.gov [DOE]

    In another step forward toward improved scientific understanding of potential geologic carbon dioxide storage impacts, a new U.S. Department of Energy sponsored study has confirmed earlier research showing that proper site selection and monitoring is essential for helping anticipate and mitigate possible risks.

  20. Feasibility of Large-Scale Ocean CO2 Sequestration

    SciTech Connect (OSTI)

    Peter Brewer

    2008-08-31

    Scientific knowledge of natural clathrate hydrates has grown enormously over the past decade, with spectacular new findings of large exposures of complex hydrates on the sea floor, the development of new tools for examining the solid phase in situ, significant progress in modeling natural hydrate systems, and the discovery of exotic hydrates associated with sea floor venting of liquid CO{sub 2}. Major unresolved questions remain about the role of hydrates in response to climate change today, and correlations between the hydrate reservoir of Earth and the stable isotopic evidence of massive hydrate dissociation in the geologic past. The examination of hydrates as a possible energy resource is proceeding apace for the subpermafrost accumulations in the Arctic, but serious questions remain about the viability of marine hydrates as an economic resource. New and energetic explorations by nations such as India and China are quickly uncovering large hydrate findings on their continental shelves. In this report we detail research carried out in the period October 1, 2007 through September 30, 2008. The primary body of work is contained in a formal publication attached as Appendix 1 to this report. In brief we have surveyed the recent literature with respect to the natural occurrence of clathrate hydrates (with a special emphasis on methane hydrates), the tools used to investigate them and their potential as a new source of natural gas for energy production.

  1. The Ohio River Valley CO2 Storage Project AEP Mountaineer Plan, West Virginia

    SciTech Connect (OSTI)

    Neeraj Gupta

    2009-01-07

    This report includes an evaluation of deep rock formations with the objective of providing practical maps, data, and some of the issues considered for carbon dioxide (CO{sub 2}) storage projects in the Ohio River Valley. Injection and storage of CO{sub 2} into deep rock formations represents a feasible option for reducing greenhouse gas emissions from coal-burning power plants concentrated along the Ohio River Valley area. This study is sponsored by the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL), American Electric Power (AEP), BP, Ohio Coal Development Office, Schlumberger, and Battelle along with its Pacific Northwest Division. An extensive program of drilling, sampling, and testing of a deep well combined with a seismic survey was used to characterize the local and regional geologic features at AEP's 1300-megawatt (MW) Mountaineer Power Plant. Site characterization information has been used as part of a systematic design feasibility assessment for a first-of-a-kind integrated capture and storage facility at an existing coal-fired power plant in the Ohio River Valley region--an area with a large concentration of power plants and other emission sources. Subsurface characterization data have been used for reservoir simulations and to support the review of the issues relating to injection, monitoring, strategy, risk assessment, and regulatory permitting. The high-sulfur coal samples from the region have been tested in a capture test facility to evaluate and optimize basic design for a small-scale capture system and eventually to prepare a detailed design for a capture, local transport, and injection facility. The Ohio River Valley CO{sub 2} Storage Project was conducted in phases with the ultimate objectives of demonstrating both the technical aspects of CO{sub 2} storage and the testing, logistical, regulatory, and outreach issues related to conducting such a project at a large point source under realistic constraints. The site characterization phase was completed, laying the groundwork for moving the project towards a potential injection phase. Feasibility and design assessment activities included an assessment of the CO{sub 2} source options (a slip-stream capture system or transported CO{sub 2}); development of the injection and monitoring system design; preparation of regulatory permits; and continued stakeholder outreach.

  2. Monitoring CO2 Storage at Cranfield, Mississippi with Time-Lapse Offset VSP – Using Integration and Modeling to Reduce Uncertainty

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Daley, Thomas M.; Hendrickson, Joel; Queen, John H.

    2014-12-31

    A time-lapse Offset Vertical Seismic Profile (OVSP) data set was acquired as part of a subsurface monitoring program for geologic sequestration of CO2. The storage site at Cranfield, near Natchez, Mississippi, is part of a detailed area study (DAS) site for geologic carbon sequestration operated by the U.S. Dept. of Energy’s Southeast Regional Carbon Sequestration Partnership (SECARB). The DAS site includes three boreholes, an injection well and two monitoring wells. The project team selected the DAS site to examine CO2 sequestration multiphase fluid flow and pressure at the interwell scale in a brine reservoir. The time-lapse (TL) OVSP was partmore »of an integrated monitoring program that included well logs, crosswell seismic, electrical resistance tomography and 4D surface seismic. The goals of the OVSP were to detect the CO2 induced change in seismic response, give information about the spatial distribution of CO2 near the injection well and to help tie the high-resolution borehole monitoring to the 4D surface data. The VSP data were acquired in well CFU 31-F1, which is the ~3200 m deep CO2 injection well at the DAS site. A preinjection survey was recorded in late 2009 with injection beginning in December 2009, and a post injection survey was conducted in Nov 2010 following injection of about 250 kT of CO2. The sensor array for both surveys was a 50-level, 3-component, Sercel MaxiWave system with 15 m (49 ft) spacing between levels. The source for both surveys was an accelerated weight drop, with different source trucks used for the two surveys. Consistent time-lapse processing was applied to both data sets. Time-lapse processing generated difference corridor stacks to investigate CO2 induced reflection amplitude changes from each source point. Corridor stacks were used for amplitude analysis to maximize the signal-to-noise ratio (S/N) for each shot point. Spatial variation in reflectivity (used to ‘map’ the plume) was similar in magnitude to the corridor stacks but, due to relatively lower S/N, the results were less consistent and more sensitive to processing and therefore are not presented. We examined the overall time-lapse repeatability of the OVSP data using three methods, the NRMS and Predictability (Pred) measures of Kragh and Christie (2002) and the signal-to-distortion ratio (SDR) method of Cantillo (2011). Because time-lapse noise was comparable to the observed change, multiple methods were used to analyze data reliability. The reflections from the top and base reservoir were identified on the corridor stacks by correlation with a synthetic response generated from the well logs. A consistent change in the corridor stack amplitudes from pre- to post-CO2 injection was found for both the top and base reservoir reflections on all ten shot locations analyzed. In addition to the well-log synthetic response, a finite-difference elastic wave propagation model was built based on rock/fluid properties obtained from well logs, with CO2 induced changes guided by time-lapse crosswell seismic tomography (Ajo-Franklin, et al., 2013) acquired at the DAS site. Time-lapse seismic tomography indicated that two reservoir zones were affected by the flood. The modeling established that interpretation of the VSP trough and peak event amplitudes as reflectivity from the top and bottom of reservoir is appropriate even with possible tuning effects. Importantly, this top/base change gives confidence in an interpretation that these changes arise from within the reservoir, not from bounding lithology. The modeled time-lapse change and the observed field data change from 10 shotpoints are in agreement for both magnitude and polarity of amplitude change for top and base of reservoir. Therefore, we conclude the stored CO2 has been successfully detected and, furthermore, the observed seismic reflection change can be applied to Cranfield’s 4D surface seismic for spatially delineating the CO2/brine interface.« less

  3. Modeling basin- and plume-scale processes of CO2 storage for full-scale deployment

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.T.; Mehnert, E.; Lin, Y.-F.; Zhang, K.

    2009-08-15

    Integrated modeling of basin- and plume-scale processes induced by full-scale deployment of CO{sub 2} storage was applied to the Mt. Simon Aquifer in the Illinois Basin. A three-dimensional mesh was generated with local refinement around 20 injection sites, with approximately 30 km spacing. A total annual injection rate of 100 Mt CO{sub 2} over 50 years was used. The CO{sub 2}-brine flow at the plume scale and the single-phase flow at the basin scale were simulated. Simulation results show the overall shape of a CO{sub 2} plume consisting of a typical gravity-override subplume in the bottom injection zone of high injectivity and a pyramid-shaped subplume in the overlying multilayered Mt. Simon, indicating the important role of a secondary seal with relatively low-permeability and high-entry capillary pressure. The secondary-seal effect is manifested by retarded upward CO{sub 2} migration as a result of multiple secondary seals, coupled with lateral preferential CO{sub 2} viscous fingering through high-permeability layers. The plume width varies from 9.0 to 13.5 km at 200 years, indicating the slow CO{sub 2} migration and no plume interference between storage sites. On the basin scale, pressure perturbations propagate quickly away from injection centers, interfere after less than 1 year, and eventually reach basin margins. The simulated pressure buildup of 35 bar in the injection area is not expected to affect caprock geomechanical integrity. Moderate pressure buildup is observed in Mt. Simon in northern Illinois. However, its impact on groundwater resources is less than the hydraulic drawdown induced by long-term extensive pumping from overlying freshwater aquifers.

  4. Leakage Risk Assessment for a Potential CO2 Storage Project in Saskatchewan, Canada

    SciTech Connect (OSTI)

    Houseworth, J.E.; Oldenburg, C.M.; Mazzoldi, A.; Gupta, A.K.; Nicot, J.-P.; Bryant, S.L.

    2011-05-01

    A CO{sub 2} sequestration project is being considered to (1) capture CO{sub 2} emissions from the Consumers Cooperative Refineries Limited at Regina, Saskatchewan and (2) geologically sequester the captured CO{sub 2} locally in a deep saline aquifer. This project is a collaboration of several industrial and governmental organizations, including the Petroleum Technology Research Centre (PTRC), Sustainable Development Technology Canada (SDTC), SaskEnvironment Go Green Fund, SaskPower, CCRL, Schlumberger Carbon Services, and Enbridge. The project objective is to sequester 600 tonnes CO{sub 2}/day. Injection is planned to start in 2012 or 2013 for a period of 25 years for a total storage of approximately 5.5 million tonnes CO{sub 2}. This report presents an assessment of the leakage risk of the proposed project using a methodology known as the Certification Framework (CF). The CF is used for evaluating CO{sub 2} leakage risk associated with geologic carbon sequestration (GCS), as well as brine leakage risk owing to displacement and pressurization of brine by the injected CO{sub 2}. We follow the CF methodology by defining the entities (so-called Compartments) that could be impacted by CO{sub 2} leakage, the CO{sub 2} storage region, the potential for leakage along well and fault pathways, and the consequences of such leakage. An understanding of the likelihood and consequences of leakage forms the basis for understanding CO{sub 2} leakage risk, and forms the basis for recommendations of additional data collection and analysis to increase confidence in the risk assessment.

  5. Comparative Assessment of Status and Opportunities for CO2 Capture and Storage and Radioactive Waste Disposal in North America

    E-Print Network [OSTI]

    Oldenburg, C.

    2010-01-01

    America for 100 years or more of sequestration of CO 2 from coal-coal-fired power plants (the largest stationary point sources of CO 2 in North America)

  6. Comparative Assessment of Status and Opportunities for CO2 Capture and Storage and Radioactive Waste Disposal in North America

    E-Print Network [OSTI]

    Oldenburg, C.

    2010-01-01

    power generation. Large coal-fired power plants will requiresequestration of CO 2 from coal- fired power plants. Asideon sequestration of CO 2 from coal-fired power plants (the

  7. Site Characterization for CO2 Geologic Storage and Vice Versa - The Frio Brine Pilot as a Case Study

    E-Print Network [OSTI]

    Doughty, Christine

    2006-01-01

    The wireline reservoir saturation tool (RST) uses pulsedCO 2 saturation between wells RST (reservoir simulation

  8. Site Characterization for CO2 Geologic Storage and Vice Versa - The Frio Brine Pilot as a Case Study

    E-Print Network [OSTI]

    Doughty, Christine

    2006-01-01

    seismic VSP (vertical seismic profile) CO 2 distributionFigure 3 compares vertical seismic profile (VSP) results for

  9. Large scale tracking algorithms.

    SciTech Connect (OSTI)

    Hansen, Ross L.; Love, Joshua Alan; Melgaard, David Kennett; Karelitz, David B.; Pitts, Todd Alan; Zollweg, Joshua David; Anderson, Dylan Z.; Nandy, Prabal; Whitlow, Gary L.; Bender, Daniel A.; Byrne, Raymond Harry

    2015-01-01

    Low signal-to-noise data processing algorithms for improved detection, tracking, discrimination and situational threat assessment are a key research challenge. As sensor technologies progress, the number of pixels will increase signi cantly. This will result in increased resolution, which could improve object discrimination, but unfortunately, will also result in a significant increase in the number of potential targets to track. Many tracking techniques, like multi-hypothesis trackers, suffer from a combinatorial explosion as the number of potential targets increase. As the resolution increases, the phenomenology applied towards detection algorithms also changes. For low resolution sensors, "blob" tracking is the norm. For higher resolution data, additional information may be employed in the detection and classfication steps. The most challenging scenarios are those where the targets cannot be fully resolved, yet must be tracked and distinguished for neighboring closely spaced objects. Tracking vehicles in an urban environment is an example of such a challenging scenario. This report evaluates several potential tracking algorithms for large-scale tracking in an urban environment.

  10. ECO2N - A New TOUGH2 Fluid Property Module for Studies of CO2 Storage in Saline Aquifers

    E-Print Network [OSTI]

    Pruess, Karsten; Spycher, Nicholas

    2006-01-01

    to a dissolved CO2 mass fraction in the aqueous phase,so that gas phase CO2 mass fraction Y2,eq = 1 -Y1,eq islarger than 0.99. The CO2 mass fraction X3 in single-phase

  11. Well injectivity during CO2 storage operations in deep saline aquifers6 1: Experimental investigation of drying effects, salt precipitation and7

    E-Print Network [OSTI]

    Boyer, Edmond

    Carbon Capture and Storage (CCS) is a technique than can potentially limit the accumulation29-17Jan2014 #12;3 1. Introduction51 52 Geological sequestration of CO2 into deep saline aquifers studied54 much less than mature oil & gas reservoirs. Injection of carbon dioxide into saline aquifers55

  12. sRecovery Act: Geologic Characterization of the South Georgia Rift Basin for Source Proximal CO2 Storage

    SciTech Connect (OSTI)

    Waddell, Michael

    2014-09-30

    This study focuses on evaluating the feasibility and suitability of using the Jurassic/Triassic (J/TR) sediments of the South Georgia Rift basin (SGR) for CO2 storage in southern South Carolina and southern Georgia The SGR basin in South Carolina (SC), prior to this project, was one of the least understood rift basin along the east coast of the U.S. In the SC part of the basin there was only one well (Norris Lightsey #1) the penetrated into J/TR. Because of the scarcity of data, a scaled approach used to evaluate the feasibility of storing CO2 in the SGR basin. In the SGR basin, 240 km (~149 mi) of 2-D seismic and 2.6 km2 3-D (1 mi2) seismic data was collected, process, and interpreted in SC. In southern Georgia 81.3 km (~50.5 mi) consisting of two 2-D seismic lines were acquired, process, and interpreted. Seismic analysis revealed that the SGR basin in SC has had a very complex structural history resulting the J/TR section being highly faulted. The seismic data is southern Georgia suggest SGR basin has not gone through a complex structural history as the study area in SC. The project drilled one characterization borehole (Rizer # 1) in SC. The Rizer #1 was drilled but due to geologic problems, the project team was only able to drill to 1890 meters (6200 feet) instead of the proposed final depth 2744 meters (9002 feet). The drilling goals outlined in the original scope of work were not met. The project was only able to obtain 18 meters (59 feet) of conventional core and 106 rotary sidewall cores. All the conventional core and sidewall cores were in sandstone. We were unable to core any potential igneous caprock. Petrographic analysis of the conventional core and sidewall cores determined that the average porosity of the sedimentary material was 3.4% and the average permeability was 0.065 millidarcy. Compaction and diagenetic studies of the samples determined there would not be any porosity or permeability at depth in SC. In Georgia there appears to be porosity in the J/TR section based on neutron log porosity values. The only zones in Rizer #1 that appear to be porous were fractured diabase units where saline formation water was flowing into the borehole. Two geocellular models were created for the SC and GA study area. Flow simulation modeling was performed on the SC data set. The injection simulation used the newly acquired basin data as well as the Petrel 3-D geologic model that included geologic structure. Due to the new basin findings as a result of the newly acquired data, during phase two of the modeling the diabase unit was used as reservoir and the sandstone units were used as caprock. Conclusion are: 1) the SGR basin is composed of numerous sub-basins, 2) this study only looked at portions of two sub-basins, 3) in SC, 30 million tonnes of CO2 can be injected into the diabase units if the fracture network is continuous through the units, 4) due to the severity of the faulting there is no way of assuring the injected CO2 will not migrate upward into the overlying Coastal Plain aquifers, 5) in Georgia there appears to porous zones in the J/TR sandstones, 6) as in SC there is faulting in the sub-basin and the seismic suggest the faulting extends upward into the Coastal Plain making that area not suitable for CO2 sequestration, 7) the complex faulting observed at both study areas appear to be associated with transfer fault zones (Heffner 2013), if sub-basins in the Georgia portion of the SGR basin can be located that are far away from the transfer fault zones there is a strong possibility of sequestering CO2 in these areas, and 9) the SGR basin covers area in three states and this project only studied two small areas so there is enormous potential for CO2 sequestration in other portions the basin and further research needs to be done to find these areas.

  13. High Areal Capacity Hybrid Magnesium-Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large-Scale Energy Storage

    E-Print Network [OSTI]

    High Areal Capacity Hybrid Magnesium-Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large, United States *S Supporting Information ABSTRACT: Hybrid magnesium-lithium-ion batteries (MLIBs magnesium-lithium-ion batteries (MLIBs), energy storage, Coulombic efficiency, dendrite-free magnesium

  14. Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-05-15

    Storage of CO{sub 2} in saline aquifers is intended to be at supercritical pressure and temperature conditions, but CO{sub 2} leaking from a geologic storage reservoir and migrating toward the land surface (through faults, fractures, or improperly abandoned wells) would reach subcritical conditions at depths shallower than 500-750 m. At these and shallower depths, subcritical CO{sub 2} can form two-phase mixtures of liquid and gaseous CO{sub 2}, with significant latent heat effects during boiling and condensation. Additional strongly non-isothermal effects can arise from decompression of gas-like subcritical CO{sub 2}, the so-called Joule-Thomson effect. Integrated modeling of CO{sub 2} storage and leakage requires the ability to model non-isothermal flows of brine and CO{sub 2} at conditions that range from supercritical to subcritical, including three-phase flow of aqueous phase, and both liquid and gaseous CO{sub 2}. In this paper, we describe and demonstrate comprehensive simulation capabilities that can cope with all possible phase conditions in brine-CO{sub 2} systems. Our model formulation includes: (1) an accurate description of thermophysical properties of aqueous and CO{sub 2}-rich phases as functions of temperature, pressure, salinity and CO{sub 2} content, including the mutual dissolution of CO{sub 2} and H{sub 2}O; (2) transitions between super- and subcritical conditions, including phase change between liquid and gaseous CO{sub 2}; (3) one-, two-, and three-phase flow of brine-CO{sub 2} mixtures, including heat flow; (4) non-isothermal effects associated with phase change, mutual dissolution of CO{sub 2} and water, and (de-) compression effects; and (5) the effects of dissolved NaCl, and the possibility of precipitating solid halite, with associated porosity and permeability change. Applications to specific leakage scenarios demonstrate that the peculiar thermophysical properties of CO{sub 2} provide a potential for positive as well as negative feedbacks on leakage rates, with a combination of self-enhancing and self-limiting effects. Lower viscosity and density of CO{sub 2} as compared to aqueous fluids provides a potential for self-enhancing effects during leakage, while strong cooling effects from liquid CO{sub 2} boiling into gas, and from expansion of gas rising towards the land surface, act to self-limit discharges. Strong interference between fluid phases under three-phase conditions (aqueous - liquid CO{sub 2} - gaseous CO{sub 2}) also tends to reduce CO{sub 2} fluxes. Feedback on different space and time scales can induce non-monotonic behavior of CO{sub 2} flow rates.

  15. Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater

    SciTech Connect (OSTI)

    Birkholzer, Jens; Apps, John; Zheng, Liange; Zhang, Yingqi; Xu, Tianfu; Tsang, Chin-Fu

    2008-10-01

    One promising approach to reduce greenhouse gas emissions is injecting CO{sub 2} into suitable geologic formations, typically depleted oil/gas reservoirs or saline formations at depth larger than 800 m. Proper site selection and management of CO{sub 2} storage projects will ensure that the risks to human health and the environment are low. However, a risk remains that CO{sub 2} could migrate from a deep storage formation, e.g. via local high-permeability pathways such as permeable faults or degraded wells, and arrive in shallow groundwater resources. The ingress of CO{sub 2} is by itself not typically a concern to the water quality of an underground source of drinking water (USDW), but it will change the geochemical conditions in the aquifer and will cause secondary effects mainly induced by changes in pH, in particular the mobilization of hazardous inorganic constituents present in the aquifer minerals. Identification and assessment of these potential effects is necessary to analyze risks associated with geologic sequestration of CO{sub 2}. This report describes a systematic evaluation of the possible water quality changes in response to CO{sub 2} intrusion into aquifers currently used as sources of potable water in the United States. Our goal was to develop a general understanding of the potential vulnerability of United States potable groundwater resources in the event of CO{sub 2} leakage. This goal was achieved in two main tasks, the first to develop a comprehensive geochemical model representing typical conditions in many freshwater aquifers (Section 3), the second to conduct a systematic reactive-transport modeling study to quantify the effect of CO{sub 2} intrusion into shallow aquifers (Section 4). Via reactive-transport modeling, the amount of hazardous constituents potentially mobilized by the ingress of CO{sub 2} was determined, the fate and migration of these constituents in the groundwater was predicted, and the likelihood that drinking water standards might be exceeded was evaluated. A variety of scenarios and aquifer conditions was considered in a sensitivity evaluation. The scenarios and conditions simulated in Section 4, in particular those describing the geochemistry and mineralogy of potable aquifers, were selected based on the comprehensive geochemical model developed in Section 3.

  16. Scope for Future CO2 Emission Reductions from Electricity Generation through the Deployment of Carbon Capture and Storage Technologies

    E-Print Network [OSTI]

    Scope for Future CO2 Emission Reductions from Electricity Generation through the Deployment-emission electricity within one or two decades. Renewable generation is also planned to increase over similar time, it is therefore possible that large (~45%) reductions in CO2 emissions from UK electricity generation could

  17. Two-Stage, Integrated, Geothermal-CO2 Storage Reservoirs: An Approach for Sustainable Energy Production, CO2-Sequestration Security, and Reduced Environmental Risk

    SciTech Connect (OSTI)

    Buscheck, T A; Chen, M; Sun, Y; Hao, Y; Elliot, T R

    2012-02-02

    We introduce a hybrid two-stage energy-recovery approach to sequester CO{sub 2} and produce geothermal energy at low environmental risk and low cost by integrating geothermal production with CO{sub 2} capture and sequestration (CCS) in saline, sedimentary formations. Our approach combines the benefits of the approach proposed by Buscheck et al. (2011b), which uses brine as the working fluid, with those of the approach first suggested by Brown (2000) and analyzed by Pruess (2006), using CO{sub 2} as the working fluid, and then extended to saline-formation CCS by Randolph and Saar (2011a). During stage one of our hybrid approach, formation brine, which is extracted to provide pressure relief for CO{sub 2} injection, is the working fluid for energy recovery. Produced brine is applied to a consumptive beneficial use: feedstock for fresh water production through desalination, saline cooling water, or make-up water to be injected into a neighboring reservoir operation, such as in Enhanced Geothermal Systems (EGS), where there is often a shortage of a working fluid. For stage one, it is important to find economically feasible disposition options to reduce the volume of brine requiring reinjection in the integrated geothermal-CCS reservoir (Buscheck et al. 2012a). During stage two, which begins as CO{sub 2} reaches the production wells; coproduced brine and CO{sub 2} are the working fluids. We present preliminary reservoir engineering analyses of this approach, using a simple conceptual model of a homogeneous, permeable CO{sub 2} storage formation/geothermal reservoir, bounded by relatively impermeable sealing units. We assess both the CO{sub 2} sequestration capacity and geothermal energy production potential as a function of well spacing between CO{sub 2} injectors and brine/CO{sub 2} producers for various well patterns and for a range of subsurface conditions.

  18. Analytical Estimation of CO2 Storage Capacity in Depleted Oil and Gas Reservoirs Based on Thermodynamic State Functions 

    E-Print Network [OSTI]

    Valbuena Olivares, Ernesto

    2012-02-14

    from commercial PVT software package. Results present excellent agreement. Limited significant digits in commercial software lead to scattered data. ....................................... 80 Fig. 5.5? Case A?Fluid volume comparison from analytical... model and calculations from commercial PVT software package. Results present excellent agreement. ............................................................... 81 Fig. 5.6? Case B?CO2 molar density distribution at the end of injection. The CO2...

  19. Final Report on "Rising CO2 and Long-term Carbon Storage in Terrestrial Ecosystems: An Empirical Carbon Budget Validation"

    SciTech Connect (OSTI)

    J. Patrick Megonigal; Bert G. Drake

    2010-08-27

    The primary goal of this report is to report the results of Grant DE-FG02-97ER62458, which began in 1997 as Grant DOE-98-59-MP-4 funded through the TECO program. However, this project has a longer history because DOE also funded this study from its inception in 1985 through 1997. The original grant was focused on plant responses to elevated CO2 in an intact ecosystem, while the latter grant was focused on belowground responses. Here we summarize the major findings across the 25 years this study has operated, and note that the experiment will continue to run through 2020 with NSF support. The major conclusions of the study to date are: (1 Elevated CO2 stimulated plant productivity in the C3 plant community by ~30% during the 25 year study. The magnitude of the increase in productivity varied interannually and was sometime absent altogether. There is some evidence of down-regulation at the ecosystem level across the 25 year record that may be due to interactions with other factors such as sea-level rise or long-term changes in N supply; (2) Elevated CO2 stimulated C4 productivity by <10%, perhaps due to more efficient water use, but C3 plants at elevated CO2 did not displace C4 plants as predicted; (3) Increased primary production caused a general stimulation of microbial processes, but there were both increases and decreases in activity depending on the specific organisms considered. An increase in methanogenesis and methane emissions implies elevated CO2 may amplify radiative forcing in the case of wetland ecosystems; (4) Elevated CO2 stimulated soil carbon sequestration in the form of an increase in elevation. The increase in elevation is 50-100% of the increase in net ecosystem production caused by elevated CO2 (still under analysis). The increase in soil elevation suggests the elevated CO2 may have a positive outcome for the ability of coastal wetlands to persist despite accelerated sea level rise; (5) Crossing elevated CO2 with elevated N causes the elevated CO2 effect to diminish, with consequences for change in soil elevation.

  20. Impact-driven pressure management via targeted brine extraction Conceptual studies of CO2 storage in saline formations

    E-Print Network [OSTI]

    Birkholzer, J.T.

    2013-01-01

    Risk, Presentation at the SPE International Workshop on Carbon Capture, Utilization, and Storage (CCUS): Environment, Energy

  1. Modeling Basin-and Plume-Scale Processes of CO2 Storage for Full-Scale Deployment

    E-Print Network [OSTI]

    Zhou, Quanlin

    on groundwater resources is less than the hydraulic drawdown induced by long-term extensive pumping from for two decades as an effective measure for mitigating climate change--by storing CO2 in oil and gas the United States (U.S. Department of Energy [USDOE] 2008) and other countries. The main objective

  2. Scope for Future CO2 Emission Reductions from Electricity Generation through the Deployment of Carbon Capture and Storage Technologies

    E-Print Network [OSTI]

    Haszeldine, Stuart

    Projections (UEP) [1] show a decrease over the next two decades, but at a reduced rate compared to the 1990's represent electricity supplies with no (historically) or low (UEP projections) UK CO2 reduction targets of alternative options to deliver at a lower price. Additional costs for the 'decarbonised electricity' options

  3. Carbon capture and storage update Matthew E. Boot-Handford,a

    E-Print Network [OSTI]

    Haszeldine, Stuart

    intermittent sources such as wind) and thus CCS reduces the need for large-scale energy storage to be developed, hence the importance of retaining them as an option in the energy mix. Here, we review the leading CO2 in terms of e.g. energy efficiency is already used). The captured CO2 is then pressurised to $100 bar (or

  4. Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2008-02-29

    There is growing interest regarding the potential size of a future U.S. dedicated CO2 pipeline infrastructure if carbon dioxide capture and storage (CCS) technologies are commercially deployed on a large scale. In trying to understand the potential scale of a future national CO2 pipeline network, comparisons are often made to the existing pipeline networks used to deliver natural gas and liquid hydrocarbons to markets within the U.S. This paper assesses the potential scale of the CO2 pipeline system needed under two hypothetical climate policies and compares this to the extant U.S. pipeline infrastructures used to deliver CO2 for enhanced oil recovery (EOR), and to move natural gas and liquid hydrocarbons from areas of production and importation to markets. The data presented here suggest that the need to increase the size of the existing dedicated CO2 pipeline system should not be seen as a significant obstacle for the commercial deployment of CCS technologies.

  5. DOE Regional Partnership Successfully Demonstrates Terrestrial CO2 Storage Practices in Great Plains Region of U.S. and Canada

    Broader source: Energy.gov [DOE]

    A field test demonstrating the best approaches for terrestrial carbon dioxide storage in the heartland of North America has been successfully completed by one of the U.S. Department of Energy's seven Regional Carbon Sequestration Partnerships.

  6. A method for quick assessment of CO2 storage capacity in closedand semi-closed saline formations

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Tsang, C.F.; Rutqvist, J.

    2008-02-10

    Saline aquifers of high permeability bounded by overlying/underlying seals may be surrounded laterally by low-permeability zones, possibly caused by natural heterogeneity and/or faulting. Carbon dioxide (CO{sub 2}) injection into and storage in such 'closed' systems with impervious seals, or 'semi-closed' systems with nonideal (low-permeability) seals, is different from that in 'open' systems, from which the displaced brine can easily escape laterally. In closed or semi-closed systems, the pressure buildup caused by continuous industrial-scale CO{sub 2} injection may have a limiting effect on CO{sub 2} storage capacity, because geomechanical damage caused by overpressure needs to be avoided. In this research, a simple analytical method was developed for the quick assessment of the CO{sub 2} storage capacity in such closed and semi-closed systems. This quick-assessment method is based on the fact that native brine (of an equivalent volume) displaced by the cumulative injected CO{sub 2} occupies additional pore volume within the storage formation and the seals, provided by pore and brine compressibility in response to pressure buildup. With nonideal seals, brine may also leak through the seals into overlying/underlying formations. The quick-assessment method calculates these brine displacement contributions in response to an estimated average pressure buildup in the storage reservoir. The CO{sub 2} storage capacity and the transient domain-averaged pressure buildup estimated through the quick-assessment method were compared with the 'true' values obtained using detailed numerical simulations of CO{sub 2} and brine transport in a two-dimensional radial system. The good agreement indicates that the proposed method can produce reasonable approximations for storage-formation-seal systems of various geometric and hydrogeological properties.

  7. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    are the primary pathways for CO 2 migration to the surface.are the primary pathways for CO 2 migration to the surface (

  8. Energy-Efficient Antenna Selection and Power Allocation for Large-Scale Multiple Antenna

    E-Print Network [OSTI]

    ) sector has been estimated to represent about 2 percent of the global CO2 emissions [1], and 1.8 percent reduce CO2 emissions [5]. On the other hand, large-scale multiple antenna systems which employ hundreds of the total world electricity consumption [2]. The mobile network operational expenditure (OPEX

  9. The Ohio River Valley CO2 Storage Project AEP Mountaineer Plant, West Virginia Numerical Simulation and Risk Assessment Report

    SciTech Connect (OSTI)

    Neeraj Gupta

    2008-03-31

    A series of numerical simulations of carbon dioxide (CO{sub 2}) injection were conducted as part of a program to assess the potential for geologic sequestration in deep geologic reservoirs (the Rose Run and Copper Ridge formations), at the American Electric Power (AEP) Mountaineer Power Plant outside of New Haven, West Virginia. The simulations were executed using the H{sub 2}O-CO{sub 2}-NaCl operational mode of the Subsurface Transport Over Multiple Phases (STOMP) simulator (White and Oostrom, 2006). The objective of the Rose Run formation modeling was to predict CO{sub 2} injection rates using data from the core analysis conducted on the samples. A systematic screening procedure was applied to the Ohio River Valley CO{sub 2} storage site utilizing the Features, Elements, and Processes (FEP) database for geological storage of CO{sub 2} (Savage et al., 2004). The objective of the screening was to identify potential risk categories for the long-term geological storage of CO{sub 2} at the Mountaineer Power Plant in New Haven, West Virginia. Over 130 FEPs in seven main classes were assessed for the project based on site characterization information gathered in a geological background study, testing in a deep well drilled on the site, and general site conditions. In evaluating the database, it was apparent that many of the items were not applicable to the Mountaineer site based its geologic framework and environmental setting. Nine FEPs were identified for further consideration for the site. These FEPs generally fell into categories related to variations in subsurface geology, well completion materials, and the behavior of CO{sub 2} in the subsurface. Results from the screening were used to provide guidance on injection system design, developing a monitoring program, performing reservoir simulations, and other risk assessment efforts. Initial work indicates that the significant FEPs may be accounted for by focusing the storage program on these potential issues. The screening method was also useful in identifying unnecessary items that were not significant given the site-specific geology and proposed scale of the Ohio River Valley CO{sub 2} Storage Project. Overall, the FEP database approach provides a comprehensive methodology for assessing potential risk for a practical CO{sub 2} storage application. An integrated numerical fate and transport model was developed to enable risk and consequence assessment at field scale. Results show that such an integrated modeling effort would be helpful in meeting the project objectives (such as site characterization, engineering, permitting, monitoring and closure) during different stages. A reservoir-scale numerical model was extended further to develop an integrated assessment framework which can address the risk and consequence assessment, monitoring network design and permitting guidance needs. The method was used to simulate sequestration of CO{sub 2} in moderate quantities at the Mountaineer Power Plant. Results indicate that at the relatively low injection volumes planned for pilot scale demonstration at this site, the risks involved are minor to negligible, owing to a thick, low permeability caprock and overburden zones. Such integrated modeling approaches coupled with risk and consequence assessment modeling are valuable to project implementation, permitting, monitoring as well as site closure.

  10. CO2watermineral reactions during CO2 leakage: Geochemical and isotopic monitoring of a CO2 injection field test

    E-Print Network [OSTI]

    to be addressed during the selection and characterization of suitable CO2 storage sites (IEA-GHG, 2011; Lemieux., 2007; IEA-GHG, 2011). Considering a sce- nario where CO2 ­ or brine or both ­ escapes from the storage., 2010; Kharaka et al., 2010; Humez et al., 2011a, 2011b; IEA-GHG, 2011; Lemieux, 2011; Keating et al

  11. Conundrum of the Large Scale Streaming

    E-Print Network [OSTI]

    T. M. Malm

    1999-09-12

    The etiology of the large scale peculiar velocity (large scale streaming motion) of clusters would increasingly seem more tenuous, within the context of the gravitational instability hypothesis. Are there any alternative testable models possibly accounting for such large scale streaming of clusters?

  12. THE OHIO RIVER VALLEY CO2 STORAGE PROJECT - PRELIMINARY ASSESSMENT OF DEEP SALINE RESERVOIRS AND COAL SEAMS

    SciTech Connect (OSTI)

    Michael J. Mudd; Howard Johnson; Charles Christopher; T.S. Ramakrishnan, Ph.D.

    2003-08-01

    This report describes the geologic setting for the Deep Saline Reservoirs and Coal Seams in the Ohio River Valley CO{sub 2} Storage Project area. The object of the current project is to site and design a CO{sub 2} injection facility. A location near New Haven, WV, has been selected for the project. To assess geologic storage reservoirs at the site, regional and site-specific geology were reviewed. Geologic reports, deep well logs, hydraulic tests, and geologic maps were reviewed for the area. Only one well within 25 miles of the site penetrates the deeper sedimentary rocks, so there is a large amount of uncertainty regarding the deep geology at the site. New Haven is located along the Ohio River on the border of West Virginia and Ohio. Topography in the area is flat in the river valley but rugged away from the Ohio River floodplain. The Ohio River Valley incises 50-100 ft into bedrock in the area. The area of interest lies within the Appalachian Plateau, on the western edge of the Appalachian Mountain chain. Within the Appalachian Basin, sedimentary rocks are 3,000 to 20,000 ft deep and slope toward the southeast. The rock formations consist of alternating layers of shale, limestone, dolomite, and sandstone overlying dense metamorphic continental shield rocks. The Rome Trough is the major structural feature in the area, and there may be some faults associated with the trough in the Ohio-West Virginia Hinge Zone. The area has a low earthquake hazard with few historical earthquakes. Target injection reservoirs include the basal sandstone/Lower Maryville and the Rose Run Sandstone. The basal sandstone is an informal name for sandstones that overlie metamorphic shield rock. Regional geology indicates that the unit is at a depth of approximately 9,100 ft below the surface at the project site and associated with the Maryville Formation. Overall thickness appears to be 50-100 ft. The Rose Run Sandstone is another potential reservoir. The unit is located approximately 1,100 ft above the basal sandstone and is 100-200 ft thick. The storage capacity estimates for a 20-mile radius from the injection well ranged from 39-78 million tons (Mt) for each formation. Several other oil and gas plays have hydraulic properties conducive for injection, but the formations are generally only 5-50 ft thick in the study area. Overlying the injection reservoirs are thick sequences of dense, impermeable dolomite, limestone, and shale. These layers provide containment above the potential injection reservoirs. In general, it appears that the containment layers are much thicker and extensive than the injection intervals. Other physical parameters for the study area appear to be typical for the region. Anticipated pressures at maximum depths are approximately 4,100 psi based on a 0.45 psi/ft pressure gradient. Temperatures are likely to be 150 F. Groundwater flow is slow and complex in deep formations. Regional flow directions appear to be toward the west-northwest at less than 1 ft per year within the basal sandstone. Vertical gradients are downward in the study area. A review of brine geochemistry indicates that formation fluids have high salinity and dissolved solids. Total dissolved solids ranges from 200,000-325,000 mg/L in the deep reservoirs. Brine chemistry is similar throughout the different formations, suggesting extensive mixing in a mature basin. Unconsolidated sediments in the Ohio River Valley are the primary source of drinking water in the study area.

  13. Leakage risk assessment of the In Salah CO2 storage project: Applying the Certification Framework in a dynamic context.

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Jordan, P.D.; Nicot, J.-P.; Mazzoldi, A.; Gupta, A.K.; Bryant, S.L.

    2010-08-01

    The Certification Framework (CF) is a simple risk assessment approach for evaluating CO{sub 2} and brine leakage risk at geologic carbon sequestration (GCS) sites. In the In Salah CO{sub 2} storage project assessed here, five wells at Krechba produce natural gas from the Carboniferous C10.2 reservoir with 1.7-2% CO{sub 2} that is delivered to the Krechba gas processing plant, which also receives high-CO{sub 2} natural gas ({approx}10% by mole fraction) from additional deeper gas reservoirs and fields to the south. The gas processing plant strips CO{sub 2} from the natural gas that is then injected through three long horizontal wells into the water leg of the Carboniferous gas reservoir at a depth of approximately 1,800 m. This injection process has been going on successfully since 2004. The stored CO{sub 2} has been monitored over the last five years by a Joint Industry Project (JIP) - a collaboration of BP, Sonatrach, and Statoil with co-funding from US DOE and EU DG Research. Over the years the JIP has carried out extensive analyses of the Krechba system including two risk assessment efforts, one before injection started, and one carried out by URS Corporation in September 2008. The long history of injection at Krechba, and the accompanying characterization, modeling, and performance data provide a unique opportunity to test and evaluate risk assessment approaches. We apply the CF to the In Salah CO{sub 2} storage project at two different stages in the state of knowledge of the project: (1) at the pre-injection stage, using data available just prior to injection around mid-2004; and (2) after four years of injection (September 2008) to be comparable to the other risk assessments. The main risk drivers for the project are CO{sub 2} leakage into potable groundwater and into the natural gas cap. Both well leakage and fault/fracture leakage are likely under some conditions, but overall the risk is low due to ongoing mitigation and monitoring activities. Results of the application of the CF during these different state-of-knowledge periods show that the assessment of likelihood of various leakage scenarios increased as more information became available, while assessment of impact stayed the same. Ongoing mitigation, modeling, and monitoring of the injection process is recommended.

  14. Japan's Long-term Energy Demand and Supply Scenario to 2050 - Estimation for the Potential of Massive CO2 Mitigation

    E-Print Network [OSTI]

    Komiyama, Ryoichi

    2010-01-01

    and large-scale electricity storage technologies. In thisand introducing electricity storage (storage batteries,and storage technologies Developing higlily efficient electricity

  15. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    gas streams that have variable CO 2 concentrations and pressures. Other separation and capture methods include membrane-

  16. Leveraging Regional Exploration to Develop Geologic Framework for CO2 Storage in Deep Formations in Midwestern United States

    SciTech Connect (OSTI)

    Neeraj Gupta

    2009-09-30

    Obtaining subsurface data for developing a regional framework for geologic storage of CO{sub 2} can require drilling and characterization in a large number of deep wells, especially in areas with limited pre-existing data. One approach for achieving this objective, without the prohibitive costs of drilling costly standalone test wells, is to collaborate with the oil and gas drilling efforts in a piggyback approach that can provide substantial cost savings and help fill data gaps in areas that may not otherwise get characterized. This leveraging with oil/gas drilling also mitigates some of the risk involved in standalone wells. This collaborative approach has been used for characterizing in a number of locations in the midwestern USA between 2005 and 2009 with funding from U.S. Department of Energy's National Energy Technology Laboratory (DOE award: DE-FC26-05NT42434) and in-kind contributions from a number of oil and gas operators. The results are presented in this final technical report. In addition to data collected under current award, selected data from related projects such as the Midwestern Regional Carbon Sequestration Partnership (MRCSP), the Ohio River Valley CO{sub 2} storage project at and near the Mountaineer Plant, and the drilling of the Ohio Stratigraphic well in Eastern Ohio are discussed and used in the report. Data from this effort are also being incorporated into the MRCSP geologic mapping. The project activities were organized into tracking and evaluation of characterization opportunities; participation in the incremental drilling, basic and advanced logging in selected wells; and data analysis and reporting. Although a large number of opportunities were identified and evaluated, only a small subset was carried into the field stage. Typical selection factors included reaching an acceptable agreement with the operator, drilling and logging risks, and extent of pre-existing data near the candidate wells. The region of study is primarily along the Ohio River Valley corridor in the Appalachian Basin, which underlies large concentrations of CO{sub 2} emission sources. In addition, some wells in the Michigan basin are included. Assessment of the geologic and petrophysical properties of zones of interest has been conducted. Although a large number of formations have been evaluated across the geologic column, the primary focus has been on evaluating the Cambrian sandstones (Mt. Simon, Rose Run, Kerbel) and carbonates layers (Knox Dolomite) as well as on the Silurian-Devonian carbonates (Bass Island, Salina) and sandstones (Clinton, Oriskany, Berea). Factors controlling the development of porosity and permeability, such as the depositional setting have been explored. In northern Michigan the Bass Islands Dolomite appears to have favorable reservoir development. In west central Michigan the St. Peter sandstone exhibits excellent porosity in the Hart and Feuring well and looks promising. In Southeastern Kentucky in the Appalachian Basin, the Batten and Baird well provided valuable data on sequestration potential in organic shales through adsorption. In central and eastern Ohio and western West Virginia, the majority of the wells provided an insight to the complex geologic framework of the relatively little known Precambrian through Silurian potential injection targets. Although valuable data was acquired and a number of critical data gaps were filled through this effort, there are still many challenges ahead and questions that need answered. The lateral extent to which favorable potential injection conditions exist in most reservoirs is still generally uncertain. The prolongation of the characterization of regional geologic framework through partnership would continue to build confidence and greatly benefit the overall CO{sub 2} sequestration effort.

  17. The Next-Generation Massively Parallel Reactive Flow and Transport Code PFLOTRAN: Application to CO2 Storage in Saline Aquifers P. Lichtner

    E-Print Network [OSTI]

    Mills, Richard

    aquifers as a possible solution to reduce green house gas emissions. Dissolution of supercritical CO2-term fate of a supercritical CO2 plume will be resolved with high-resolution numerical simulations into a relatively deep saline aquifer above the critical point where CO2 exists as a supercritical fluid (Tcrit =31

  18. Risk Assessment and Monitoring of Stored CO2 in Organic Rocks Under Non-Equilibrium Conditions

    SciTech Connect (OSTI)

    Malhotra, Vivak

    2014-06-30

    The USA is embarking upon tackling the serious environmental challenges posed to the world by greenhouse gases, especially carbon dioxide (CO2). The dimension of the problem is daunting. In fact, according to the Energy Information Agency, nearly 6 billion metric tons of CO2 were produced in the USA in 2007 with coal-burning power plants contributing about 2 billion metric tons. To mitigate the concerns associated with CO2 emission, geological sequestration holds promise. Among the potential geological storage sites, unmineable coal seams and shale formations in particular show promise because of the probability of methane recovery while sequestering the CO2. However. the success of large-scale sequestration of CO2 in coal and shale would hinge on a thorough understanding of CO2's interactions with host reservoirs. An important parameter for successful storage of CO2 reservoirs would be whether the pressurized CO2 would remain invariant in coal and shale formations under reasonable internal and/or external perturbations. Recent research has brought to the fore the potential of induced seismicity, which may result in caprock compromise. Therefore, to evaluate the potential risks involved in sequestering CO2 in Illinois bituminous coal seams and shale, we studied: (i) the mechanical behavior of Murphysboro (Illinois) and Houchin Creek (Illinois) coals, (ii) thermodynamic behavior of Illinois bituminous coal at - 100oC ? T ? 300oC, (iii) how high pressure CO2 (up to 20.7 MPa) modifies the viscosity of the host, (iv) the rate of emission of CO2 from Illinois bituminous coal and shale cores if the cores, which were pressurized with high pressure (? 20.7 MPa) CO2, were exposed to an atmospheric pressure, simulating the development of leakage pathways, (v) whether there are any fractions of CO2 stored in these hosts which are resistance to emission by simply exposing the cores to atmospheric pressure, and (vi) how compressive shockwaves applied to the coal and shale cores, which were pressurized with high pressure CO2, determine the fate of sequestered CO2 in these cores. Our results suggested that Illinois bituminous coal in its unperturbed state, i.e., when not pressurized with CO2, showed large variations in the mechanical properties. Modulus varied from 0.7 GPa to 3.4 GPa even though samples were extracted from a single large chunk of coal. We did not observe any glass transition for Illinois bituminous coal at - 100oC ? T ? 300oC, however, when the coal was pressurized with CO2 at ambient ? P ? 20.7 MPa, the viscosity of the coal decreased and inversely scaled with the CO2 pressure. The decrease in viscosity as a function of pressure could pose CO2 injection problems for coal as lower viscosity would allow the solid coal to flow to plug the fractures, fissures, and cleats. Our experiments also showed a very small fraction of CO2 was absorbed in coal; and when CO2 pressurized coals were exposed to atmospheric conditions, the loss of CO2 from coals was massive. Half of the sequestered gas from the coal cores was lost in less than 20 minutes. Our shockwave experiments on Illinois bituminous coal, New Albany shale (Illinois), Devonian shale (Ohio), and Utica shale (Ohio) presented clear evidence that the significant emission of the sequestered CO2 from these formations cannot be discounted during seismic activity, especially if caprock is compromised. It is argued that additional shockwave studies, both compressive and transverse, would be required for successfully mapping the risks associated with sequestering high pressure CO2 in coal and shale formations.

  19. Large-Scale Information Systems

    SciTech Connect (OSTI)

    D. M. Nicol; H. R. Ammerlahn; M. E. Goldsby; M. M. Johnson; D. E. Rhodes; A. S. Yoshimura

    2000-12-01

    Large enterprises are ever more dependent on their Large-Scale Information Systems (LSLS), computer systems that are distinguished architecturally by distributed components--data sources, networks, computing engines, simulations, human-in-the-loop control and remote access stations. These systems provide such capabilities as workflow, data fusion and distributed database access. The Nuclear Weapons Complex (NWC) contains many examples of LSIS components, a fact that motivates this research. However, most LSIS in use grew up from collections of separate subsystems that were not designed to be components of an integrated system. For this reason, they are often difficult to analyze and control. The problem is made more difficult by the size of a typical system, its diversity of information sources, and the institutional complexities associated with its geographic distribution across the enterprise. Moreover, there is no integrated approach for analyzing or managing such systems. Indeed, integrated development of LSIS is an active area of academic research. This work developed such an approach by simulating the various components of the LSIS and allowing the simulated components to interact with real LSIS subsystems. This research demonstrated two benefits. First, applying it to a particular LSIS provided a thorough understanding of the interfaces between the system's components. Second, it demonstrated how more rapid and detailed answers could be obtained to questions significant to the enterprise by interacting with the relevant LSIS subsystems through simulated components designed with those questions in mind. In a final, added phase of the project, investigations were made on extending this research to wireless communication networks in support of telemetry applications.

  20. Metal Organic Framework Research: High Throughput Discovery of Robust Metal Organic Framework for CO2 Capture

    SciTech Connect (OSTI)

    None

    2010-08-01

    IMPACCT Project: LBNL is developing a method for identifying the best metal organic frameworks for use in capturing CO2 from the flue gas of coal-fired power plants. Metal organic frameworks are porous, crystalline compounds that, based on their chemical structure, vary considerably in terms of their capacity to grab hold of passing CO2 molecules and their ability to withstand the harsh conditions found in the gas exhaust of coal-fired power plants. Owing primarily to their high tunability, metal organic frameworks can have an incredibly wide range of different chemical and physical properties, so identifying the best to use for CO2 capture and storage can be a difficult task. LBNL uses high-throughput instrumentation to analyze nearly 100 materials at a time, screening them for the characteristics that optimize their ability to selectively adsorb CO2 from coal exhaust. Their work will identify the most promising frameworks and accelerate their large-scale commercial development to benefit further research into reducing the cost of CO2 capture and storage.

  1. Highlights of the 2009 SEG summer research workshop on "CO2 Sequestration Geophysics"

    E-Print Network [OSTI]

    Lumley, D.

    2010-01-01

    groundwater, natural gas storage, waste disposal…). Rock andfrom CO 2 EOR and natural gas storage projects, the risk of

  2. High Performance Electronic Structure Engineering: Large Scale...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Performance Electronic Structure Engineering: Large Scale GW Calculations Event Sponsor: Argonne Leadership Computing Facility Seminar Start Date: Aug 7 2015 - 10:00am...

  3. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    COMPOSITION OF FLUE GAS STREAMS AND CO 2 SEPARATION 43 3.3. NATURALcompositions by volume of flue (and fuel) gases from selected coal, fuel oil, natural

  4. Microfluidic Large-Scale Integration: The Evolution

    E-Print Network [OSTI]

    Quake, Stephen R.

    Microfluidic Large-Scale Integration: The Evolution of Design Rules for Biological Automation, polydimethylsiloxane Abstract Microfluidic large-scale integration (mLSI) refers to the develop- ment of microfluidic, are discussed. Several microfluidic components used as building blocks to create effective, complex, and highly

  5. Management of Large-Scale International

    E-Print Network [OSTI]

    Management of Large- Scale International Science Projects Dr. Benjamin J. Cross, P.E. Savannah of Government Commerce) #12;Extending Project Management to New, Complex Challenges · Emergence of large-scale-of-the-art R&D and technologies ­ Exceedingly high energies, temperatures, radiological conditions, special

  6. DLFM library tools for large scale dynamic applications.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DLFM library tools for large scale dynamic applications DLFM library tools for large scale dynamic applications Large scale Python and other dynamic applications may spend huge...

  7. CO2 enrichment increases carbon and nitrogen input from

    E-Print Network [OSTI]

    CO2 enrichment increases carbon and nitrogen input from fine roots in a deciduous forest Colleen2 Ecological Society of America, 2008 #12;#12;#12;#12;#12;+ [CO2] #12;+ Net primary production + [CO2] #12;+ Net primary production + [CO2] + C and N storage in biomass #12;+ Net primary production

  8. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    be associated with migration of CO 2 from depth along majordepth. The 1996 and 2000 VLP earthquakes were probably caused by migrationdepth to the surface, risk assessment should be focused on determining the potential for and nature of CO 2 migration

  9. Monitoring CO 2 sequestration into deep saline aquifer and associated salt intrusion using coupled multiphase flow modeling and time lapse electrical resistivity tomography

    SciTech Connect (OSTI)

    Chuan Lu; CHI Zhang; Hai Hanag; Timothy C. Johnson

    2014-04-01

    Successful geological storage and sequestration of carbon dioxide (CO2) require efficient monitoring of the migration of CO2 plume during and after large-scale injection in order to verify the containment of the injected CO2 within the target formation and to evaluate potential leakage risk. Field studies have shown that surface and cross-borehole electrical resistivity tomography (ERT) can be a useful tool in imaging and characterizing solute transport in heterogeneous subsurface. In this synthetic study, we have coupled a 3-D multiphase flow model with a parallel 3-D time-lapse ERT inversion code to explore the feasibility of using time-lapse ERT for simultaneously monitoring the migration of CO2 plume in deep saline formation and potential brine intrusion into shallow fresh water aquifer. Direct comparisons of the inverted CO2 plumes resulting from ERT with multiphase flow simulation results indicate the ERT could be used to delineate the migration of CO2 plume. Detailed comparisons on the locations, sizes and shapes of CO2 plume and intruded brine plumes suggest that ERT inversion tends to underestimate the area review of the CO2 plume, but overestimate the thickness and total volume of the CO2 plume. The total volume of intruded brine plumes is overestimated as well. However, all discrepancies remain within reasonable ranges. Our study suggests that time-lapse ERT is a useful monitoring tool in characterizing the movement of injected CO2 into deep saline aquifer and detecting potential brine intrusion under large-scale field injection conditions.

  10. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extractionmore »control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing ‘Area of Review’, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.« less

  11. Formation Damage due to CO2 Sequestration in Saline Aquifers 

    E-Print Network [OSTI]

    Mohamed, Ibrahim Mohamed 1984-

    2012-10-25

    Carbon dioxide (CO2) sequestration is defined as the removal of gas that would be emitted into the atmosphere and its subsequent storage in a safe, sound place. CO2 sequestration in underground formations is currently being considered to reduce...

  12. Program Management for Large Scale Engineering Programs

    E-Print Network [OSTI]

    Oehmen, Josef

    The goal of this whitepaper is to summarize the LAI research that applies to program management. The context of most of the research discussed in this whitepaper are large-scale engineering programs, particularly in the ...

  13. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    41 2.3.7. Leroy Gas Storage Facility, Wyoming,and M.R. Tek, Leroy gas storage facility, Unita County,reservoirs and natural gas storage facilities, respectively,

  14. Dynamics of CO2 fluxes and concentrations during a shallow subsurface CO2 release

    SciTech Connect (OSTI)

    Lewicki, J.L.; Hilley, G.E.; Dobeck, L.; Spangler, L.

    2009-09-01

    A field facility located in Bozeman, Montana provides the opportunity to test methods to detect, locate, and quantify potential CO2 leakage from geologic storage sites. From 9 July to 7 August 2008, 0.3 t CO2 d{sup -1} were injected from a 100-m long, {approx}2.5 m deep horizontal well. Repeated measurements of soil CO2 fluxes on a grid characterized the spatio-temporal evolution of the surface leakage signal and quantified the surface leakage rate. Infrared CO2 concentration sensors installed in the soil at 30 cm depth at 0 to 10 m from the well and at 4 cm above the ground at 0 and 5 m from the well recorded surface breakthrough of CO2 leakage and migration of CO2 leakage through the soil. Temporal variations in CO2 concentrations were correlated with atmospheric and soil temperature, wind speed, atmospheric pressure, rainfall, and CO2 injection rate.

  15. An investigation of reaction parameters on geochemical storage of non-pure CO2 streams in iron oxides-bearing formations

    SciTech Connect (OSTI)

    Garcia, Susana; Liu, Q.; Bacon, Diana H.; Maroto-Valer, M. M.

    2014-08-26

    Hematite deposit that is the main FeIII-bearing mineral in sedimentary red beds was proposed as a potential host repository for converting CO2 into carbonate minerals such as siderite (FeCO3), when CO2–SO2 gas mixtures are co-injected. This work investigated CO2 mineral trapping using hematite and sensitivity of the reactive systems to different parameters, including particle size, gas composition, temperature, pressure, and solid-to-liquid ratio. Experimental and modelling studies of hydrothermal experiments were conducted, which emulated a CO2 sequestration scenario by injecting CO2-SO2 gas streams into a NaCl-NaOH brine hosted in iron oxide-containing aquifer. This study provides novel information on the mineralogical changes and fluid chemistry derived from the co-injection of CO2-SO2 gas mixtures in hematite deposit. It can be concluded that the amount of siderite precipitate depends primarily on the SO2 content of the gas stream. Increasing SO2 content in the system could promote the reduction of Fe3+ from the hematite sample to Fe2+, which will be further available for its precipitation as siderite. Moreover, siderite precipitation is enhanced at low temperatures and high pressures. The influence of the solid to liquid ratio on the overall carbonation reaction suggests that the conversion increases if the system becomes more diluted.

  16. A combined saline formation and gas reservoir CO2 injection pilot in Northern California

    E-Print Network [OSTI]

    Trautz, Robert; Myer, Larry; Benson, Sally; Oldenburg, Curt; Daley, Thomas; Seeman, Ed

    2006-01-01

    cushion gas for natural gas storage. Energy & Fuels, 2003; [demonstrate CO 2 Storage with Enhanced Gas Recovery (CSEGR).formations and storage/enhanced recovery projects in gas

  17. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    as NEU-CO2 emissions (i.e. , a carbon storage fraction ofand stored fractions. It follows that, in practice, NEU-CO2

  18. Geomechanical effects on CO2 leakage through fault zones during large-scale underground injection

    E-Print Network [OSTI]

    Rinaldi, A.P.

    2014-01-01

    approach for Enhanced Geothermal Systems. Geophys. J. Int.earthquakes in the enhanced geothermal system in Basel,including enhanced geothermal systems (Rutqvist et al. ,

  19. Large-scale Screening of Zeolite Structures for CO2 Membrane Separations |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeat PumpsTechnologies | Blandine Jerome LanfangCenter for

  20. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01

    Efforts Investigating Water Extraction •! LLNL –! Active CObenefits of various water extraction, treatment, and reuseof CO 2 storage and water extraction scenarios –! Technical

  1. "Applications and future trends in polymer materials for green energy systems: from energy generation and storage, to CO2 capture and transportaion"

    SciTech Connect (OSTI)

    George Zafiris

    2010-08-24

    Presentation describes United Technologies Research Center's recent work in green energy systems, including APRA-E project content to create a synthetic analogue of the carbonic anhydrase enzyme and incorporate it into a membrane for CO2 separation from the flue gas of a coal power plant.

  2. Relative Roles of Changes in CO2 and Climate to Equilibrium Responses of Net Primary Production and Carbon Storage of the Terrestrial Biosphere

    E-Print Network [OSTI]

    -GFDL) and a 2-dimensional climate model (Land-Ocean climate model at Massachusetts Institute of TechnologyRelative Roles of Changes in CO2 and Climate to Equilibrium Responses of Net Primary Production Institute of Technology, Cambridge, MA 02139, USA 3 National Biological Service, Alaska Cooperative Fish

  3. The lifetime of carbon capture and storage as a climate-change mitigation technology

    SciTech Connect (OSTI)

    Juanes, Ruben

    2013-12-30

    In carbon capture and storage (CCS), CO2 is captured at power plants and then injected underground into reservoirs like deep saline aquifers for long-term storage. While CCS may be critical for the continued use of fossil fuels in a carbon-constrained world, the deployment of CCS has been hindered by uncertainty in geologic storage capacities and sustainable injection rates, which has contributed to the absence of concerted government policy. Here, we clarify the potential of CCS to mitigate emissions in the United States by developing a storage-capacity supply curve that, unlike current large-scale capacity estimates, is derived from the fluid mechanics of CO2 injection and trapping and incorporates injection-rate constraints. We show that storage supply is a dynamic quantity that grows with the duration of CCS, and we interpret the lifetime of CCS as the time for which the storage supply curve exceeds the storage demand curve from CO2 production. We show that in the United States, if CO2 production from power generation continues to rise at recent rates, then CCS can store enough CO2 to stabilize emissions at current levels for at least 100 years. This result suggests that the large-scale implementation of CCS is a geologically viable climate-change mitigation option in the United States over the next century.

  4. Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-04-20

    There is growing interest regarding the potential size of a future U.S. dedicated carbon dioxide (CO2) pipeline infrastructure if carbon dioxide capture and storage (CCS) technologies are commercially deployed on a large scale within the United States. This paper assesses the potential scale of the CO2 pipeline system needed under two hypothetical climate policies (so called WRE450 and WRE550 stabilization scenarios) and compares this to the extant U.S. pipeline infrastructures used to deliver CO2 for enhanced oil recovery (EOR), and to move natural gas and liquid hydrocarbons from areas of production and importation to markets. The analysis reveals that between 11,000 and 23,000 additional miles of dedicated CO2 pipeline might be needed in the U.S. before 2050 across these two cases. While that is a significant increase over the 3,900 miles that comprise the existing national CO2 pipeline infrastructure, it is critically important to realize that the demand for additional CO2 pipeline capacity will unfold relatively slowly and in a geographically dispersed manner as new dedicated CCS-enabled power plants and industrial facilities are brought online. During the period 2010-2030, the growth in the CO2 pipeline system is on the order of a few hundred to less than a thousand miles per year. In comparison during the period 1950-2000, the U.S. natural gas pipeline distribution system grew at rates that far exceed these projections in growth in a future dedicated CO2 pipeline system. This analysis indicates that the need to increase the size of the existing dedicated CO2 pipeline system should not be seen as a major obstacle for the commercial deployment of CCS technologies in the U.S. Nevertheless, there will undoubtedly be some associated regulatory and siting issues to work through but these issues should not be unmanageable based on the size of infrastructure requirements alone.

  5. Surface controls on the characteristics of natural CO2 seeps: implications for engineered CO2 stores

    E-Print Network [OSTI]

    Haszeldine, Stuart

    be characterized to design the most effective monitoring strategy. Key words: carbon capture and storage, carbon are considering adoption of carbon capture and storage technology to meet carbon emission reduction targets of Edinburgh, Edinburgh, UK ABSTRACT Long-term security of performance of engineered CO2 storage is a principle

  6. Aquifer Management for CO2 Sequestration 

    E-Print Network [OSTI]

    Anchliya, Abhishek

    2010-07-14

    Storage of carbon dioxide is being actively considered for the reduction of green house gases. To make an impact on the environment CO2 should be put away on the scale of gigatonnes per annum. The storage capacity of deep saline aquifers...

  7. Large-scale gyrokinetic particle simulation of

    E-Print Network [OSTI]

    Oliker, Leonid

    areas of research including plasma astrophysics and fusion energy science. Fusion is the power source that are still needed to make fusion energy a practical realization. Research in plasma science requiresLarge-scale gyrokinetic particle simulation of microturbulence in magnetically confined fusion

  8. learn invent impact Design of Large Scale

    E-Print Network [OSTI]

    McCalley, James D.

    learn invent impact Design of Large Scale Permanent Magnet Synchronous Generators for Wind Turbines.iastate.edu Permanent Magnet Synchronous Generators (PMSGs) Source: http://www.digikey.com/en-US/articles/techzone/2012of% 20PM_Generator_RPI_Qu_v8.pdf Permanent Magnet Synchronous Generators Rotor PMDD Generator Full

  9. he leading technology under development for management of CO2

    E-Print Network [OSTI]

    Aydilek, Ahmet

    T he leading technology under development for management of CO2 separated and captured from large assessment in relation to deploy- ment of the technology. Potential mechanisms for leakage from CO2 storage Series*sponsored by John J. Kirlin Lecture funds Geologic Sequestration of CO2 : Evaluating

  10. The Effective Field Theory of Cosmological Large Scale Structures...

    Office of Scientific and Technical Information (OSTI)

    The Effective Field Theory of Cosmological Large Scale Structures Citation Details In-Document Search Title: The Effective Field Theory of Cosmological Large Scale Structures...

  11. The Effective Field Theory of Cosmological Large Scale Structures...

    Office of Scientific and Technical Information (OSTI)

    The Effective Field Theory of Cosmological Large Scale Structures Citation Details In-Document Search Title: The Effective Field Theory of Cosmological Large Scale Structures ...

  12. ACCOLADES: A Scalable Workflow Framework for Large-Scale Simulation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ACCOLADES: A Scalable Workflow Framework for Large-Scale Simulation and Analyses of Automotive Engines Title ACCOLADES: A Scalable Workflow Framework for Large-Scale Simulation and...

  13. Overcoming the Barrier to Achieving Large-Scale Production -...

    Office of Environmental Management (EM)

    Overcoming the Barrier to Achieving Large-Scale Production - A Case Study Overcoming the Barrier to Achieving Large-Scale Production - A Case Study This presentation summarizes the...

  14. CO2 on the Integrity of Well Cement | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 on the Integrity of Well Cement Effect of CO2 on the Integrity of Well Cement under Geologic Storage Conditions Geologic carbon storage is the separation and capture of carbon...

  15. CO2 Sequestration Modeling Using Pattern Recognition and Data Mining;

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    . In order to perform a safe and efficient carbon dioxide capture and storage (CCS) project, a comprehensive. Carbon dioxide capture and storage (CCS) is a process including the capture of CO2 from high production, USA Abstract Capturing carbon dioxide (CO2) from industrial and energy-related sources and depositing

  16. Geochemical and Microbiological Characterization of the Arbuckle Saline Aquifer, a Potential CO2 Storage Reservoir; Implications for Hydraulic Separation and Caprock Integrity

    E-Print Network [OSTI]

    Scheffer, Aimee

    2012-12-31

    goals, implementation of GCS is almost certainly necessary. As a result, the Department of Energy has funded the examination of the Arbuckle saline aquifer, as well as other aquifers around the United States, to assess their potential as carbon storage...

  17. amine methanol, ether . Amine amine CO2

    E-Print Network [OSTI]

    Hong, Deog Ki

    IP [2012] 7 C O 2 (CO2) . CO2 amine methanol, ether . Amine amine CO2 CO2 .Amine CO2 (functional group) amine amine+ +promoter .Amine CO2 CO2 . . , methanol ether methanol, ether promoter CO2 CO2 H2S, COS CO2 . Methanol rectisol process, di-methylene ether polypropylene glycol selexol (-30oC) . CO2

  18. Large-Scale PV Integration Study

    SciTech Connect (OSTI)

    Lu, Shuai; Etingov, Pavel V.; Diao, Ruisheng; Ma, Jian; Samaan, Nader A.; Makarov, Yuri V.; Guo, Xinxin; Hafen, Ryan P.; Jin, Chunlian; Kirkham, Harold; Shlatz, Eugene; Frantzis, Lisa; McClive, Timothy; Karlson, Gregory; Acharya, Dhruv; Ellis, Abraham; Stein, Joshua; Hansen, Clifford; Chadliev, Vladimir; Smart, Michael; Salgo, Richard; Sorensen, Rahn; Allen, Barbara; Idelchik, Boris

    2011-07-29

    This research effort evaluates the impact of large-scale photovoltaic (PV) and distributed generation (DG) output on NV Energy’s electric grid system in southern Nevada. It analyzes the ability of NV Energy’s generation to accommodate increasing amounts of utility-scale PV and DG, and the resulting cost of integrating variable renewable resources. The study was jointly funded by the United States Department of Energy and NV Energy, and conducted by a project team comprised of industry experts and research scientists from Navigant Consulting Inc., Sandia National Laboratories, Pacific Northwest National Laboratory and NV Energy.

  19. 1 National Roadmap Committee for Large-Scale Research Facilities the netherlands' roadmap for large-scale research facilities

    E-Print Network [OSTI]

    Horn, David

    #12;1 National Roadmap Committee for Large-Scale Research Facilities the netherlands' roadmap for large-scale research facilities #12;2 National Roadmap Committee for Large-Scale Research Facilities1 by Roselinde Supheert) #12;3 National Roadmap Committee for Large-Scale Research Facilities The Netherlands

  20. Large Scale Computing and Storage Requirements for Nuclear Physics Research

    E-Print Network [OSTI]

    Gerber, Richard A.

    2012-01-01

    electron-ion collider (MEIC, a JLAB concept). The presentbeam-beam simulations for MEIC, RHIC and LHC • Argonneat BNL and also to support MEIC design studies at JLAB. The

  1. Large Scale Computing and Storage Requirements for Nuclear Physics Research

    E-Print Network [OSTI]

    Gerber, Richard A.

    2012-01-01

    neutrino matrix. Neutrinoless double beta decay experiments,process called neutrinoless double beta decay in nuclei,

  2. Large-Scale Industrial Carbon Capture, Storage Plant Begins Constructi...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from biologic fermentation, a significant feature of the project is its "negative carbon footprint," meaning that the sequestration results in a net reduction of...

  3. Large Scale Computing and Storage Requirements for High Energy Physics

    E-Print Network [OSTI]

    Gerber, Richard A.

    2011-01-01

    Type Ia supernovae, gamma-ray bursts, X-ray bursts and corerelativistic jet, making a gamma-ray burst, the luminositythose that lead to gamma-ray bursts. The current frontier is

  4. Large Scale Computing and Storage Requirements for Nuclear Physics Research

    E-Print Network [OSTI]

    Gerber, Richard A.

    2012-01-01

    in the process of thermonuclear incineration of theircore-collapse and thermonuclear events to test predictionsprocesses. In contrast to thermonuclear supernova modeling,

  5. Large Scale Computing and Storage Requirements for High Energy Physics

    E-Print Network [OSTI]

    Gerber, Richard A.

    2011-01-01

    number modeling of type ia supernovae. I. Hydrodynamics.number modeling of type ia supernovae. II. Energy evolution.Mach number modeling of type ia supernovae. III. Reactions.

  6. Large Scale Computing and Storage Requirements for Nuclear Physics Research

    E-Print Network [OSTI]

    Gerber, Richard A.

    2012-01-01

    proceedings of High Performance Computing – 2011 (HPC-2011)In recent years, high performance computing has becomeNERSC is the primary high-performance computing facility for

  7. Large Scale Computing and Storage Requirements for High Energy Physics

    E-Print Network [OSTI]

    Gerber, Richard A.

    2011-01-01

    second resulting from a thermonuclear explosion of materialresult from the thermonuclear burning of a carbon-oxygensensitive to how the thermonuclear runaway is ignited (

  8. Automatic Reconfiguration for Large-Scale Reliable Storage Systems

    E-Print Network [OSTI]

    Rodrigues, Rodrigo

    Byzantine-fault-tolerant replication enhances the availability and reliability of Internet services that store critical state and preserve it despite attacks or software errors. However, existing Byzantine-fault-tolerant ...

  9. Large Scale Computing and Storage Requirements for High Energy Physics

    E-Print Network [OSTI]

    Gerber, Richard A.

    2011-01-01

    the proposed International Linear Collider; • Assessment ofX and the International Linear Collider (ILC). Normalsoftware International Linear Collider Innovative and Novel

  10. Large Scale Computing and Storage Requirements for High Energy Physics

    E-Print Network [OSTI]

    Gerber, Richard A.

    2011-01-01

    LHC upgrade, Project X, Compact Linear Collider (CLIC), highNuclear Research Compact Linear Collider Community Petascale

  11. The Promise Of Data Grouping In Large Scale Storage Systems

    E-Print Network [OSTI]

    Wildani, Avani

    2013-01-01

    the possibility of cache churn, and because it runs in O(n),making them less likely to churn the cache and more likelyin turn limits the amount of churn in our cache. To avoid an

  12. Large Scale Computing and Storage Requirements for Basic Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SciencesAn BES ASCR NERSC WorkshopFebruary 9-10, 2010... Read More Workshop Logistics Workshop location, directions, and registration information are included here......

  13. Large Scale Computing and Storage Requirements for Advanced Scientific

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratory program

  14. Large Scale Computing and Storage Requirements for Basic Energy Sciences:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratory programTarget 2014 Large

  15. Large Scale Computing and Storage Requirements for Biological and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratory programTarget 2014

  16. Large Scale Computing and Storage Requirements for Fusion Energy Sciences:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratory programTarget 2014Target

  17. Large Scale Computing and Storage Requirements for High Energy Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratory programTarget 2014Target

  18. Large Scale Computing and Storage Requirements for Nuclear Physics: Target

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratory programTarget

  19. Large Scale Production Computing and Storage Requirements for Advanced

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratory programTargetScientific

  20. Large Scale Production Computing and Storage Requirements for Basic Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratory

  1. Large Scale Production Computing and Storage Requirements for Biological

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratoryand Environmental Research:

  2. Large Scale Production Computing and Storage Requirements for Fusion Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratoryand Environmental

  3. Large Scale Production Computing and Storage Requirements for High Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratoryand EnvironmentalPhysics: Target

  4. Large Scale Production Computing and Storage Requirements for Nuclear

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse Bergkamp Graduate studentScienceLaboratoryand EnvironmentalPhysics:

  5. Large Scale Computing and Storage Requirements for High Energy Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and mastheadLakeLanguage ofRequirements

  6. Large-Scale Industrial Carbon Capture, Storage Plant Begins Construction |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and mastheadLakeLanguage

  7. Role of Fluid Pressure in the Production Behavior of Enhanced Geothermal Systems with CO2 as Working Fluid

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01

    systems (EGS), heat transmission, CO 2 storage, numericaleither CO 2 or water as heat transmission fluid. For a modelCO 2 instead of water as heat transmission fluid. Originally

  8. FEMP Helps Federal Facilities Develop Large-Scale Renewable Energy...

    Office of Environmental Management (EM)

    FEMP Helps Federal Facilities Develop Large-Scale Renewable Energy Projects FEMP Helps Federal Facilities Develop Large-Scale Renewable Energy Projects August 21, 2013 - 12:00am...

  9. Energy Department Loan Guarantee Would Support Large-Scale Rooftop...

    Energy Savers [EERE]

    Loan Guarantee Would Support Large-Scale Rooftop Solar Power for U.S. Military Housing Energy Department Loan Guarantee Would Support Large-Scale Rooftop Solar Power for U.S....

  10. Copyright 2014 IEEE. Reprinted, with permission from: CERTS Microgrid Demonstration With Large-Scale Energy

    E-Print Network [OSTI]

    Copyright © 2014 IEEE. Reprinted, with permission from: CERTS Microgrid Demonstration With Large GRID, VOL. 5, NO. 2, MARCH 2014 937 CERTS Microgrid Demonstration With Large-Scale Energy Storage (CERTS) Microgrid concept captures the emerging po- tential of Distributed Energy Resource (DER) using

  11. Exploring Adaptive Reconfiguration to Optimize Energy Efficiency in Large-Scale Battery Systems

    E-Print Network [OSTI]

    with hundreds or thousands of batteries are now widely used in electric vehicles [33], [36], energy storageExploring Adaptive Reconfiguration to Optimize Energy Efficiency in Large-Scale Battery Systems systems such as electric vehicles and smart micro-grids. For many applications, the load requirements

  12. Kronos: A Java-Based Software System for the Processing and Retrieval of Large Scale

    E-Print Network [OSTI]

    Bader, David A.

    Kronos: A Java-Based Software System for the Processing and Retrieval of Large Scale AVHRR Data and preprocessing, indexing and storage, search and processing engine, and a Java interface. We illustrate the power of Maryland, College Park, MD 20742 March 4, 1999 1UMIACS and Department of Electrical Engineering 2Department

  13. Uncertainty quantification for CO2 sequestration and enhanced oil recovery

    E-Print Network [OSTI]

    Dai, Zhenxue; Fessenden-Rahn, Julianna; Middleton, Richard; Pan, Feng; Jia, Wei; Lee, Si-Yong; McPherson, Brian; Ampomah, William; Grigg, Reid

    2014-01-01

    This study develops a statistical method to perform uncertainty quantification for understanding CO2 storage potential within an enhanced oil recovery (EOR) environment at the Farnsworth Unit of the Anadarko Basin in northern Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil-water flow and reactive transport in the Morrow formation are conducted for global sensitivity and statistical analysis of the major uncertainty metrics: net CO2 injection, cumulative oil production, cumulative gas (CH4) production, and net water injection. A global sensitivity and response surface analysis indicates that reservoir permeability, porosity, and thickness are the major intrinsic reservoir parameters that control net CO2 injection/storage and oil/gas recovery rates. The well spacing and the initial water saturation also have large impact on the oil/gas recovery rates. Further, this study has revealed key insights into the potential behavior and the operational parameters of CO2 sequestration at CO2-EOR s...

  14. Theoretical Tools for Large Scale Structure

    E-Print Network [OSTI]

    J. R. Bond; L. Kofman; D. Pogosyan; J. Wadsley

    1998-10-06

    We review the main theoretical aspects of the structure formation paradigm which impinge upon wide angle surveys: the early universe generation of gravitational metric fluctuations from quantum noise in scalar inflaton fields; the well understood and computed linear regime of CMB anisotropy and large scale structure (LSS) generation; the weakly nonlinear regime, where higher order perturbation theory works well, and where the cosmic web picture operates, describing an interconnected LSS of clusters bridged by filaments, with membranes as the intrafilament webbing. Current CMB+LSS data favour the simplest inflation-based $\\Lambda$CDM models, with a primordial spectral index within about 5% of scale invariant and $\\Omega_\\Lambda \\approx 2/3$, similar to that inferred from SNIa observations, and with open CDM models strongly disfavoured. The attack on the nonlinear regime with a variety of N-body and gas codes is described, as are the excursion set and peak-patch semianalytic approaches to object collapse. The ingredients are mixed together in an illustrative gasdynamical simulation of dense supercluster formation.

  15. Plumbing the Depths: Testing Natural Tracers of Subsurface CO2 Origin and

    E-Print Network [OSTI]

    Gilfillan, Stuart

    to be added to the CO2 at the time of injec- tion. This will marginally increase the cost of storagePlumbing the Depths: Testing Natural Tracers of Subsurface CO2 Origin and Migration, Utah Mark storage of fluid CO2 in porous subsurface rock will re- quire the ability to track, and identify

  16. Large-Scale Optimization of Complex Separator and Reactor Networks

    E-Print Network [OSTI]

    Ghougassian, Paul Gougas

    2013-01-01

    CO2 capture ready fossil plants with post- combustion capture. Part 1: requirements for supercritical

  17. Sensitivity technologies for large scale simulation.

    SciTech Connect (OSTI)

    Collis, Samuel Scott; Bartlett, Roscoe Ainsworth; Smith, Thomas Michael; Heinkenschloss, Matthias; Wilcox, Lucas C.; Hill, Judith C.; Ghattas, Omar; Berggren, Martin Olof; Akcelik, Volkan; Ober, Curtis Curry; van Bloemen Waanders, Bart Gustaaf; Keiter, Eric Richard

    2005-01-01

    Sensitivity analysis is critically important to numerous analysis algorithms, including large scale optimization, uncertainty quantification,reduced order modeling, and error estimation. Our research focused on developing tools, algorithms and standard interfaces to facilitate the implementation of sensitivity type analysis into existing code and equally important, the work was focused on ways to increase the visibility of sensitivity analysis. We attempt to accomplish the first objective through the development of hybrid automatic differentiation tools, standard linear algebra interfaces for numerical algorithms, time domain decomposition algorithms and two level Newton methods. We attempt to accomplish the second goal by presenting the results of several case studies in which direct sensitivities and adjoint methods have been effectively applied, in addition to an investigation of h-p adaptivity using adjoint based a posteriori error estimation. A mathematical overview is provided of direct sensitivities and adjoint methods for both steady state and transient simulations. Two case studies are presented to demonstrate the utility of these methods. A direct sensitivity method is implemented to solve a source inversion problem for steady state internal flows subject to convection diffusion. Real time performance is achieved using novel decomposition into offline and online calculations. Adjoint methods are used to reconstruct initial conditions of a contamination event in an external flow. We demonstrate an adjoint based transient solution. In addition, we investigated time domain decomposition algorithms in an attempt to improve the efficiency of transient simulations. Because derivative calculations are at the root of sensitivity calculations, we have developed hybrid automatic differentiation methods and implemented this approach for shape optimization for gas dynamics using the Euler equations. The hybrid automatic differentiation method was applied to a first order approximation of the Euler equations and used as a preconditioner. In comparison to other methods, the AD preconditioner showed better convergence behavior. Our ultimate target is to perform shape optimization and hp adaptivity using adjoint formulations in the Premo compressible fluid flow simulator. A mathematical formulation for mixed-level simulation algorithms has been developed where different physics interact at potentially different spatial resolutions in a single domain. To minimize the implementation effort, explicit solution methods can be considered, however, implicit methods are preferred if computational efficiency is of high priority. We present the use of a partial elimination nonlinear solver technique to solve these mixed level problems and show how these formulation are closely coupled to intrusive optimization approaches and sensitivity analyses. Production codes are typically not designed for sensitivity analysis or large scale optimization. The implementation of our optimization libraries into multiple production simulation codes in which each code has their own linear algebra interface becomes an intractable problem. In an attempt to streamline this task, we have developed a standard interface between the numerical algorithm (such as optimization) and the underlying linear algebra. These interfaces (TSFCore and TSFCoreNonlin) have been adopted by the Trilinos framework and the goal is to promote the use of these interfaces especially with new developments. Finally, an adjoint based a posteriori error estimator has been developed for discontinuous Galerkin discretization of Poisson's equation. The goal is to investigate other ways to leverage the adjoint calculations and we show how the convergence of the forward problem can be improved by adapting the grid using adjoint-based error estimates. Error estimation is usually conducted with continuous adjoints but if discrete adjoints are available it may be possible to reuse the discrete version for error estimation. We investigate the advantages and disadvantages of continuous and discre

  18. Use of experience curves to estimate the future cost of power plants with CO2 capture

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Antes, Matt; Berkenpas, Michael; Davison, John

    2007-01-01

    Cost of electricity (excluding transport/ storage) Nominal (of electricity (excluding CO 2 transport and storage costs).electricity after 100 GW of capture plant capacity (excluding transport and storage

  19. CO2 interaction with aquifer and seal on geological timescales: the Miller oilfield, UK North Sea 

    E-Print Network [OSTI]

    Lu, Jiemin

    2008-01-01

    Carbon Capture and Storage (CCS) has been identified as a feasible technology to reduce CO2 emissions whilst permitting the continued use of fossil fuels. Injected CO2 must remain efficiently isolated from the atmosphere ...

  20. Optimizing Cluster Heads for Energy Efficiency in Large-Scale...

    Office of Scientific and Technical Information (OSTI)

    Optimizing Cluster Heads for Energy Efficiency in Large-Scale Heterogeneous Wireless Sensor Networks Gu, Yi; Wu, Qishi; Rao, Nageswara S. V. Hindawi Publishing Corporation None...

  1. Optimizing Cluster Heads for Energy Efficiency in Large-Scale...

    Office of Scientific and Technical Information (OSTI)

    clustering is generally considered as an efficient and scalable way to facilitate the management and operation of such large-scale networks and minimize the total energy...

  2. ORNL demonstrates first large-scale graphene fabrication | ornl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ORNL demonstrates first large-scale graphene composite fabrication ORNL's ultrastrong graphene features layers of graphene and polymers and is an effective conductor of...

  3. A Model for Turbulent Combustion Simulation of Large Scale Hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Model for Turbulent Combustion Simulation of Large Scale Hydrogen Explosions Event Sponsor: Argonne Leadership Computing Facility Seminar Start Date: Oct 6 2015 - 10:00am...

  4. Effects of Volcanism, Crustal Thickness, and Large Scale Faulting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effects of Volcanism, Crustal Thickness, and Large Scale Faulting on the Development and Evolution of Geothermal Systems: Collaborative Project in Chile Effects of Volcanism,...

  5. Large Scale GSHP as Alternative Energy for American Farmers Geothermal...

    Open Energy Info (EERE)

    technologies, and remove the farming business risk associated with fluctuating fuel prices. PI Xu has many years experience in large scale GSHP for commercial and industrial...

  6. Optimization Online - A fictitious play approach to large-scale ...

    E-Print Network [OSTI]

    Theodore Lambert

    2004-08-01

    Aug 1, 2004 ... A fictitious play approach to large-scale optimization. Theodore Lambert (tlambert ***at*** tmcc.edu) Marina A. Epelman (mepelman ***at*** ...

  7. Advancing Cellulosic Ethanol for Large Scale Sustainable Transportation

    E-Print Network [OSTI]

    Wyman, C

    2007-01-01

    Advancing Cellulosic Ethanol for Large Scale SustainableHydrogen Batteries Nuclear By Lee Lynd, Dartmouth Ethanol •Ethanol, ethyl alcohol, fermentation ethanol, or just “

  8. Towards a Large-Scale Recording System: Demonstration of Polymer...

    Office of Scientific and Technical Information (OSTI)

    Towards a Large-Scale Recording System: Demonstration of Polymer-Based Penetrating Array for Chronic Neural Recording Citation Details In-Document Search Title: Towards a...

  9. Northern California CO2 Reduction Project

    SciTech Connect (OSTI)

    Hymes, Edward

    2010-06-16

    C6 Resources LLC, a wholly owned subsidiary of Shell Oil Company, worked with the US Department of Energy (DOE) under a Cooperative Agreement to develop the Northern California CO2 Reduction Project. The objective of the Project is to demonstrate the viability of using Carbon Capture and Sequestration (CCS) to reduce existing greenhouse gas emissions from industrial sources on a large-scale. The Project will capture more than 700,000 metric tonnes of CO2 per year, which is currently being vented to the atmosphere from the Shell Martinez Refinery in Contra Costa County. The CO2 will be compressed and dehydrated at the refinery and then transported via pipeline to a sequestration site in a rural area in neighboring Solano County. The CO2 will be sequestered into a deep saline formation (more than two miles underground) and will be monitored to assure secure, long-term containment. The pipeline will be designed to carry as much as 1,400,000 metric tonnes of CO2 per year, so additional capacity will be available to accommodate CO2 captured from other industrial sources. The Project is expected to begin operation in 2015. The Project has two distinct phases. The overall objective of Phase 1 was to develop a fully definitive design basis for the Project. The Cooperative Agreement with the DOE provided cost sharing for Phase 1 and the opportunity to apply for additional DOE cost sharing for Phase 2, comprising the design, construction and operation of the Project. Phase 1 has been completed. DOE co-funding is provided by the American Recovery and Reinvestment Act (ARRA) of 2009. As prescribed by ARRA, the Project will stimulate the local economy by creating manufacturing, transportation, construction, operations, and management jobs while addressing the need to reduce greenhouse gas emissions at an accelerated pace. The Project, which will also assist in meeting the CO2 reduction requirements set forth in California?s Climate Change law, presents a major opportunity for both the environment as well as the region. C6 Resources is conducting the Project in collaboration with federally-funded research centers, such as Lawrence Berkeley National Lab and Lawrence Livermore National Lab. C6 Resources and Shell have identified CCS as one of the critical pathways toward a worldwide goal of providing cleaner energy. C6 Resources, in conjunction with the West Coast Regional Carbon Sequestration Partnership (WESTCARB), has conducted an extensive and ongoing public outreach and CCS education program for local, regional and state-wide stakeholders. As part of a long term relationship, C6 Resources will continue to engage directly with community leaders and residents to ensure public input and transparency. This topical report summarizes the technical work from Phase 1 of the Project in the following areas: ? Surface Facility Preliminary Engineering: summarizes the preliminary engineering work performed for CO2 capture, CO2 compression and dehydration at the refinery, and surface facilities at the sequestration site ? Pipeline Preliminary Engineering: summarizes the pipeline routing study and preliminary engineering design ? Geologic Sequestration: summarizes the work to characterize, model and evaluate the sequestration site ? Monitoring, Verification and Accounting (MVA): summarizes the MVA plan to assure long-term containment of the sequestered CO2

  10. Modeling of CO2 storage in aquifers

    E-Print Network [OSTI]

    santos,,,

    Feb 6, 2011 ... the PVT data as a simplified thermodynamic model. ..... M S 2005 Simulation of the oil and gas flow toward a well - A stability analysis Journal.

  11. Underground CO2 Storage | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPPfinal designUltrafastUncovering theand Astrophysics -Enhanced

  12. POWER SYSTEMS STABILITY WITH LARGE-SCALE WIND POWER PENETRATION

    E-Print Network [OSTI]

    Bak-Jensen, Birgitte

    of offshore wind farms, wind power fluctuations may introduce several challenges to reliable power system behaviour due to natural wind fluctuations. The rapid power fluctuations from the large scale wind farms Generation Control (AGC) system which includes large- scale wind farms for long-term stability simulation

  13. Language Requirements for Large-Scale Generic Libraries

    E-Print Network [OSTI]

    Lumsdaine, Andrew

    Language Requirements for Large-Scale Generic Libraries Jeremy Siek and Andrew Lumsdaine {jsiek-scale software libraries. The fundamental principle of generic pro- gramming is the realization of interfaces programming and large-scale libraries. In this paper, we present an overview of G and analyze

  14. Climate impacts of a large-scale biofuels expansion*

    E-Print Network [OSTI]

    Climate impacts of a large-scale biofuels expansion* Willow Hallgren, C. Adam Schlosser, Erwan impacts of a large-scale biofuels expansion Willow Hallgren,1 C. Adam Schlosser,1 Erwan Monier,1 David March 2013. [1] A global biofuels program will potentially lead to intense pressures on land supply

  15. Large-Scale Eucalyptus Energy Farms and Power Cogeneration1

    E-Print Network [OSTI]

    Large-Scale Eucalyptus Energy Farms and Power Cogeneration1 Robert C. Noronla2 The initiation of a large-scale cogeneration project, especially one that combines construction of the power generation supplemental fuel source must be sought if the cogeneration facility will consume more fuel than

  16. Detection and Classification of Ash Dieback on Large-Scale

    E-Print Network [OSTI]

    Detection and Classification of Ash Dieback on Large-Scale Color Aerial Photographs Ralph J of Agriculture 1966 #12;Croxton, Ralph J. 1966. Detection and classification of ash dieback on large- scale. Forest Serv. Res. Paper PSW-35) Aerial color photographs were taken at two scales over ash stands in New

  17. Markov Chain Analysis for Large-Scale Grid Systems

    E-Print Network [OSTI]

    Markov Chain Analysis for Large-Scale Grid Systems Christopher Dabrowski Fern Hunt NISTIR 7566 #12;2 #12;3 NISTIR 7566 Markov Chain Analysis for Large-Scale Grid Systems Christopher Dabrowski Software and Systems Division Information Technology Laboratory National Institute of Standards and Technology

  18. 2015 carbon storage rd | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Verification, and Accounting (MVA); and CO2 UseRe-Use), Infrastructure (Regional Carbon Sequestration Partnership's (RCSPs) Large-Scale Field Projects; other Small-Scale...

  19. CO2 interaction with geomaterials.

    SciTech Connect (OSTI)

    Guthrie, George D. (U.S. Department of Energy, Pittsburgh, PA); Al-Saidi, Wissam A. (University of Pittsburgh, Pittsburgh, PA); Jordan, Kenneth D. (University of Pittsburgh, Pittsburgh, PA); Voora, Vamsee, K. (University of Pittsburgh, Pittsburgh, PA); Romanov, Vyacheslav N. (U.S. Department of Energy, Pittsburgh, PA); Lopano, Christina L (U.S. Department of Energy, Pittsburgh, PA); Myshakin, Eugene M. (URS Corporation, Pittsburgh, PA); Hur, Tae Bong (University of Pittsburgh, Pittsburgh, PA); Warzinski, Robert P. (U.S. Department of Energy, Pittsburgh, PA); Lynn, Ronald J. (URS Corporation, Pittsburgh, PA); Howard, Bret H. (U.S. Department of Energy, Pittsburgh, PA); Cygan, Randall Timothy

    2010-09-01

    This work compares the sorption and swelling processes associated with CO2-coal and CO2-clay interactions. We investigated the mechanisms of interaction related to CO2 adsortion in micropores, intercalation into sub-micropores, dissolution in solid matrix, the role of water, and the associated changes in reservoir permeability, for applications in CO2 sequestration and enhanced coal bed methane recovery. The structural changes caused by CO2 have been investigated. A high-pressure micro-dilatometer was equipped to investigate the effect of CO2 pressure on the thermoplastic properties of coal. Using an identical dilatometer, Rashid Khan (1985) performed experiments with CO2 that revealed a dramatic reduction in the softening temperature of coal when exposed to high-pressure CO2. A set of experiments was designed for -20+45-mesh samples of Argonne Premium Pocahontas No.3 coal, which is similar in proximate and ultimate analysis to the Lower Kittanning seam coal that Khan used in his experiments. No dramatic decrease in coal softening temperature has been observed in high-pressure CO2 that would corroborate the prior work of Khan. Thus, conventional polymer (or 'geopolymer') theories may not be directly applicable to CO2 interaction with coals. Clays are similar to coals in that they represent abundant geomaterials with well-developed microporous structure. We evaluated the CO2 sequestration potential of clays relative to coals and investigated the factors that affect the sorption capacity, rates, and permanence of CO2 trapping. For the geomaterials comparison studies, we used source clay samples from The Clay Minerals Society. Preliminary results showed that expandable clays have CO2 sorption capacities comparable to those of coal. We analyzed sorption isotherms, XRD, DRIFTS (infrared reflectance spectra at non-ambient conditions), and TGA-MS (thermal gravimetric analysis) data to compare the effects of various factors on CO2 trapping. In montmorillonite, CO2 molecules may remain trapped for several months following several hours of exposure to high pressure (supercritical conditions), high temperature (above boiling point of water) or both. Such trapping is well preserved in either inert gas or the ambient environment and appears to eventually result in carbonate formation. We performed computer simulations of CO2 interaction with free cations (normal modes of CO2 and Na+CO2 were calculated using B3LYP / aug-cc-pVDZ and MP2 / aug-cc-pVDZ methods) and with clay structures containing interlayer cations (MD simulations with Clayff potentials for clay and a modified CO2 potential). Additionally, interaction of CO2 with hydrated Na-montmorillonite was studied using density functional theory with dispersion corrections. The sorption energies and the swelling behavior were investigated. Preliminary modeling results and experimental observations indicate that the presence of water molecules in the interlayer region is necessary for intercalation of CO2. Our preliminary conclusion is that CO2 molecules may intercalate into interlayer region of swelling clay and stay there via coordination to the interlayer cations.

  20. Stabilization of Large Scale Structure by Adhesive Gravitational Clustering

    E-Print Network [OSTI]

    Thomas Buchert

    1999-08-13

    The interplay between gravitational and dispersive forces in a multi-streamed medium leads to an effect which is exposed in the present note as the genuine driving force of stabilization of large-scale structure. The conception of `adhesive gravitational clustering' is advanced to interlock the fairly well-understood epoch of formation of large-scale structure and the onset of virialization into objects that are dynamically in equilibrium with their large-scale structure environment. The classical `adhesion model' is opposed to a class of more general models traced from the physical origin of adhesion in kinetic theory.

  1. Carbon Sequestration GeoloGical SequeStration of co2

    E-Print Network [OSTI]

    Pennycook, Steve

    Growing concern over the potential adverse effects of carbon dioxide (CO2 ) buildup in the atmosphere in three world-class CO2 storage projects that are endorsed by the Carbon Sequestration Leadership Forum04/2008 Carbon Sequestration GeoloGical SequeStration of co2 : the Geo-Seq Project Background

  2. The urgency of the development of CO2 capture from ambient air

    E-Print Network [OSTI]

    Bergman, Keren

    their CO2 emissions. Point-source CCS could be implemented without significant changes for consumers, which, 11). Point-source CCS and air capture are not the only options for reducing CO2 emissions. Stationary as insurance against CO2 leaking from storage and furthermore may provide an option for dealing with emissions

  3. emissions: mineral carbonation and Finnish pulp and paper industry (CO2

    E-Print Network [OSTI]

    Zevenhoven, Ron

    CO2 emissions: mineral carbonation and Finnish pulp and paper industry (CO2 Nordic Plus) and Use, utilisation and long-term storage of carbon dioxide (CO2) in the pulp and paper industry. The Geological of serpentinites in energy and metal industry (ECOSERP) Carl-Johan Fogelholm, Project leader, professor Sanni

  4. CO2 leakage through existing wells: current technology and regulations S. Taku Ide1

    E-Print Network [OSTI]

    CO2 leakage through existing wells: current technology and regulations S. Taku Ide1 , S. Julio the crust, and as such present zones of elevated risk to CO2 storage projects. Although current well closure and abandonment technology appears sufficient to contain CO2 at most sites, individual wells may suffer from

  5. Numerical modeling of fluid flow and time-lapse seismics to monitor CO2

    E-Print Network [OSTI]

    Santos, Juan

    Numerical modeling of fluid flow and time-lapse seismics to monitor CO2 Sequestration in aquifers J, ITALY). IMAL, 30/5/2014 Numerical modeling of fluid flow and time-lapse seismics to monitor CO2 Sequestration in aquifers ­ p. #12;Introduction. I Storage of CO2 in geological formations is a procedure

  6. Large-Scale Data Challenges in Future Power Grids

    SciTech Connect (OSTI)

    Yin, Jian; Sharma, Poorva; Gorton, Ian; Akyol, Bora A.

    2013-03-25

    This paper describes technical challenges in supporting large-scale real-time data analysis for future power grid systems and discusses various design options to address these challenges. Even though the existing U.S. power grid has served the nation remarkably well over the last 120 years, big changes are in the horizon. The widespread deployment of renewable generation, smart grid controls, energy storage, plug-in hybrids, and new conducting materials will require fundamental changes in the operational concepts and principal components. The whole system becomes highly dynamic and needs constant adjustments based on real time data. Even though millions of sensors such as phase measurement units (PMUs) and smart meters are being widely deployed, a data layer that can support this amount of data in real time is needed. Unlike the data fabric in cloud services, the data layer for smart grids must address some unique challenges. This layer must be scalable to support millions of sensors and a large number of diverse applications and still provide real time guarantees. Moreover, the system needs to be highly reliable and highly secure because the power grid is a critical piece of infrastructure. No existing systems can satisfy all the requirements at the same time. We examine various design options. In particular, we explore the special characteristics of power grid data to meet both scalability and quality of service requirements. Our initial prototype can improve performance by orders of magnitude over existing general-purpose systems. The prototype was demonstrated with several use cases from PNNL’s FPGI and was shown to be able to integrate huge amount of data from a large number of sensors and a diverse set of applications.

  7. How Three Retail Buyers Source Large-Scale Solar Electricity

    Broader source: Energy.gov [DOE]

    Large-scale, non-utility solar power purchase agreements (PPAs) are still a rarity despite the growing popularity of PPAs across the country. In this webinar, participants will learn more about how...

  8. LARGE-SCALE CORONAL PROPAGATING FRONTS IN SOLAR ERUPTIONS AS...

    Office of Scientific and Technical Information (OSTI)

    LARGE-SCALE CORONAL PROPAGATING FRONTS IN SOLAR ERUPTIONS AS OBSERVED BY THE ATMOSPHERIC IMAGING ASSEMBLY ON BOARD THE SOLAR DYNAMICS OBSERVATORY-AN ENSEMBLE STUDY Re-direct...

  9. Surrogate modeling for large-scale black-box systems

    E-Print Network [OSTI]

    Liem, Rhea Patricia

    2007-01-01

    This research introduces a systematic method to reduce the complexity of large-scale blackbox systems for which the governing equations are unavailable. For such systems, surrogate models are critical for many applications, ...

  10. Exploration of large scale manufacturing of polydimethylsiloxane (PDMS) microfluidic devices

    E-Print Network [OSTI]

    Hum, Philip W. (Philip Wing-Jung)

    2006-01-01

    Discussion of the current manufacturing process of polydimethylsiloxane (PDMS) parts and the emergence of PDMS use in biomedical microfluidic devices addresses the need to develop large scale manufacturing processes for ...

  11. Infrastructure for large-scale tests in marine autonomy

    E-Print Network [OSTI]

    Hummel, Robert A. (Robert Andrew)

    2012-01-01

    This thesis focuses on the development of infrastructure for research with large-scale autonomous marine vehicle fleets and the design of sampling trajectories for compressive sensing (CS). The newly developed infrastructure ...

  12. Platforms and real options in large-scale engineering systems

    E-Print Network [OSTI]

    Kalligeros, Konstantinos C., 1976-

    2006-01-01

    This thesis introduces a framework and two methodologies that enable engineering management teams to assess the value of real options in programs of large-scale, partially standardized systems implemented a few times over ...

  13. Interference management techniques in large-scale wireless networks 

    E-Print Network [OSTI]

    Luo, Yi

    2015-06-29

    In this thesis, advanced interference management techniques are designed and evaluated for large-scale wireless networks with realistic assumptions, such as signal propagation loss, random node distribution and ...

  14. Channel Meander Migration in Large-Scale Physical Model Study 

    E-Print Network [OSTI]

    Yeh, Po Hung

    2010-10-12

    A set of large-scale laboratory experiments were conducted to study channel meander migration. Factors affecting the migration of banklines, including the ratio of curvature to channel width, bend angle, and the Froude number were tested...

  15. Data mining techniques for large-scale gene expression analysis

    E-Print Network [OSTI]

    Palmer, Nathan Patrick

    2011-01-01

    Modern computational biology is awash in large-scale data mining problems. Several high-throughput technologies have been developed that enable us, with relative ease and little expense, to evaluate the coordinated expression ...

  16. CO2 Capture with Liquid-to-Solid Absorbents: CO2 Capture Process Using Phase-Changing Absorbents

    SciTech Connect (OSTI)

    2010-10-01

    IMPACCT Project: GE and the University of Pittsburgh are developing a unique CO2 capture process in which a liquid absorbent, upon contact with CO2, changes into a solid phase. Once in solid form, the material can be separated and the CO2 can be released for storage by heating. Upon heating, the absorbent returns to its liquid form, where it can be reused to capture more CO2. The approach is more efficient than other solventbased processes because it avoids the heating of extraneous solvents such as water. This ultimately leads to a lower cost of CO2 capture and will lower the additional cost to produce electricity for coal-fired power plants that retrofit their facilities to include this technology.

  17. Methanogenic Conversion of CO2 Into CH4

    SciTech Connect (OSTI)

    Stevens, S.H., Ferry, J.G., Schoell, M.

    2012-05-06

    This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

  18. Large-Scale Optimization of Complex Separator and Reactor Networks

    E-Print Network [OSTI]

    Ghougassian, Paul Gougas

    2013-01-01

    Fig. 5.2: UniSim PFD of steam turbine train; No CO 2 captureFig. 5.5 UniSim PFD of steam turbine train; 90% CO 2 captureCold reheat steam exits the HP turbine at the said

  19. How much CO2 is too much? Nobody knows for sure, but sophisticated

    E-Print Network [OSTI]

    Haszeldine, Stuart

    the next 30 to 60 years than by capturing and storing CO2. Carbon capture and storage (CCS) is no panacea. Carbon capture and storage(CCS)offersoneofthemostdirectandrapidwaysofreducing CO2 emissions right now fuels provides most of the world's electrical energy. It also produces large amounts of carbon dioxide

  20. EINSTEIN'S SIGNATURE IN COSMOLOGICAL LARGE-SCALE STRUCTURE

    SciTech Connect (OSTI)

    Bruni, Marco; Hidalgo, Juan Carlos; Wands, David

    2014-10-10

    We show how the nonlinearity of general relativity generates a characteristic nonGaussian signal in cosmological large-scale structure that we calculate at all perturbative orders in a large-scale limit. Newtonian gravity and general relativity provide complementary theoretical frameworks for modeling large-scale structure in ?CDM cosmology; a relativistic approach is essential to determine initial conditions, which can then be used in Newtonian simulations studying the nonlinear evolution of the matter density. Most inflationary models in the very early universe predict an almost Gaussian distribution for the primordial metric perturbation, ?. However, we argue that it is the Ricci curvature of comoving-orthogonal spatial hypersurfaces, R, that drives structure formation at large scales. We show how the nonlinear relation between the spatial curvature, R, and the metric perturbation, ?, translates into a specific nonGaussian contribution to the initial comoving matter density that we calculate for the simple case of an initially Gaussian ?. Our analysis shows the nonlinear signature of Einstein's gravity in large-scale structure.

  1. Large Scale Cosmic Microwave Background Anisotropies and Dark Energy

    E-Print Network [OSTI]

    J. Weller; A. M. Lewis

    2003-08-29

    In this note we investigate the effects of perturbations in a dark energy component with a constant equation of state on large scale cosmic microwave background anisotropies. The inclusion of perturbations increases the large scale power. We investigate more speculative dark energy models with w<-1 and find the opposite behaviour. Overall the inclusion of perturbations in the dark energy component increases the degeneracies. We generalise the parameterization of the dark energy fluctuations to allow for an arbitrary const ant sound speeds and show how constraints from cosmic microwave background experiments change if this is included. Combining cosmic microwave background with large scale structure, Hubble parameter and Supernovae observations we obtain w=-1.02+-0.16 (1 sigma) as a constraint on the equation of state, which is almost independent of the sound speed chosen. With the presented analysis we find no significant constraint on the constant speed of sound of the dark energy component.

  2. An Investigation of CO2 Sequestration

    E-Print Network [OSTI]

    Saldin, Dilano

    An Investigation of CO2 Sequestration through Mineralization Conference on Sustainable Construction area and increased availability of CO2 for rapid carbonation. The hardened and carbonated materials Slag #12;Carbonation Chemistry Dissolution of CO2 in water. CO2(g) CO2(aq) Formation of carbonic acid

  3. Breakthrough Large-Scale Industrial Project Begins Carbon Capture...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    one of the company's steam methane reformers using a gas-separation technology called "vacuum swing adsorption." After compression and drying, the CO2 purity is greater than 97...

  4. Harmonic influence in large-scale networks Daron Acemoglu

    E-Print Network [OSTI]

    Como, Giacomo

    Harmonic influence in large-scale networks Daron Acemoglu , Giacomo Como , Fabio Fagnani , and Asuman Ozdaglar§ 1. INTRODUCTION Harmonic influence has been recently introduced as a measure = 0 and xs1 = 1, respectively, the harmonic influence vector x measures the relative influence of s1

  5. A Reconfigurable Fabric for Accelerating Large-Scale Datacenter Services

    E-Print Network [OSTI]

    Hauck, Scott

    A Reconfigurable Fabric for Accelerating Large-Scale Datacenter Services Andrew Putnam, Adrian M, Doug Burger Abstract To advance datacenter capabilities beyond what commodity server designs can,632 servers and FPGAs in a production datacenter and successfully used to accelerate the ranking portion

  6. Materials Availability Expands the Opportunity for Large-Scale

    E-Print Network [OSTI]

    Kammen, Daniel M.

    , 2009. Accepted January 22, 2009. Solar photovoltaics have great promise for a low-carbon future­3). Solar photovoltaics (PV) are frequently cited as a promising but an economically unre- alistic largeMaterials Availability Expands the Opportunity for Large-Scale Photovoltaics Deployment C Y R U S W

  7. Evolving Large Scale UAV Communication System Adrian Agogino

    E-Print Network [OSTI]

    Tumer, Kagan

    Evolving Large Scale UAV Communication System Adrian Agogino UCSC at NASA Ames Mail Stop 269 Corvallis, OR 97331 Kagan.Tumer@ oregonstate.edu ABSTRACT Unmanned Aerial Vehicles (UAVs) have traditionally powered unmanned aerial vehicles (UAVs) to fly long term missions at high altitudes. This will revo

  8. Characterizing Google Hacking: A First Large-Scale Quantitative Study

    E-Print Network [OSTI]

    Gu, Guofei

    Characterizing Google Hacking: A First Large-Scale Quantitative Study Jialong Zhang, Jayant Notani.com Abstract. Google Hacking continues to be abused by attackers to find vulnerable websites on current the characteristics of vulnerabilities targeted by Google Hacking (e.g., what kind of vulnerabilities are typically

  9. A Robust Data Delivery Protocol for Large Scale Sensor Networks

    E-Print Network [OSTI]

    California at Los Angeles, University of

    by the sender. GRAB design harnesses the advantage of large scale and relies on the col- lective e#11;orts simulation exper- iments, GRAB can successfully deliver above 90% of data with relatively low energy cost the small, power-limited sensor nodes are prone to errors. Severe operational conditions (e.g. strong wind

  10. Optimal Transmission Radius for Flooding in Large Scale Sensor Networks

    E-Print Network [OSTI]

    Krishnamachari, Bhaskar

    1 Optimal Transmission Radius for Flooding in Large Scale Sensor Networks Marco Z´u~niga Z and bandwidth resources, the flooded packet may keep the transmission medium within the network busy for too long, reducing overall network throughput. We analyze the impact of the transmission radius

  11. Optimal Transmission Radius for Flooding in Large Scale Sensor Networks

    E-Print Network [OSTI]

    Krishnamachari, Bhaskar

    1 Optimal Transmission Radius for Flooding in Large Scale Sensor Networks Marco Z´u~niga Z. If the transmission radius is not set optimally, the flooded packet may be holding the transmission medium for longer periods than are necessary, reducing overall network throughput. We analyze the impact of the transmission

  12. IFIP/IEEE International Conference on Very Large Scale Integration

    E-Print Network [OSTI]

    Pierre, Laurence

    -Signal IC Design · 3-D Integration · Physical Design · SoC Design for Variability, Reliability, Fault22nd IFIP/IEEE International Conference on Very Large Scale Integration VLSI-SoC 2014 October 6-8, 2014 Playa del Carmen, Mexico Iberostar Tucán and Quetzal Hotel General Chairs: Arturo Sarmiento Reyes

  13. PERSPECTIVE SPECIAL SERIES IN LARGE-SCALE BIOLOGY

    E-Print Network [OSTI]

    Gent, Universiteit

    PERSPECTIVE SPECIAL SERIES IN LARGE-SCALE BIOLOGY PLAZA: a comparative genomics resource to study gene and genome evolution in plants Sebastian Proost1,2+ , Michiel Van Bel1,2+ , Lieven Sterck1: comparative genomics, evolution, colinearity, gene family, plants Running title: Comparative genomics

  14. Feasibility Study of Large Scale Photosynthetic Biohydrogen Greg Burgess1

    E-Print Network [OSTI]

    Feasibility Study of Large Scale Photosynthetic Biohydrogen Production Greg Burgess1 , Joel Freeman.Burgess@anu.edu.au, Javier.Fernandez@rsbs.anu.edu.au, Keith.Lovegrove@anu.edu.au A method of industrial production, the same as in some non-biological systems of H2 production. In normal conditions in algae and all plants

  15. Modeling emergent large-scale structures of barchan dune fields

    E-Print Network [OSTI]

    Claudin, Philippe

    Modeling emergent large-scale structures of barchan dune fields S. Worman , A.B. Murray , R, barchan dunes typically exist as members of larger fields that display strik- ing, enigmatic structures that cannot be readily explained by examining the dynamics at the scale of single dunes, or by appealing

  16. Hi-LION: Hierarchical Large-Scale Interconnection Optical Network

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Hi-LION: Hierarchical Large-Scale Interconnection Optical Network With AWGRs [Invited] Zheng Cao, Roberto Proietti, and S. J. B. Yoo Abstract--This paper proposes Hi-LION, a hierarchical large wavelength routing property of AWGRs together with electrical switching inside the processors, Hi-LION can

  17. Large-scale Scene Understanding Challenge: Eye Tracking Saliency Estimation

    E-Print Network [OSTI]

    Xiao, Jianxiong

    Large-scale Scene Understanding Challenge: Eye Tracking Saliency Estimation Yinda Zhang, Fisher Yu of eye tracking saliency challenge is to generate a saliency map (Fig. 1(c)), which can predict map and unzip them in to a same folder, e.g. Root. The raw images are collected from SUN database [2

  18. Supplementary Material: Large Scale Read Classification for Next Generation Sequencing

    E-Print Network [OSTI]

    Liang, Huizhi "Elly"

    genomics. 1 Introduction This document provides a list of sequences used in the study Large Scale Read.3 Bordetella bronchiseptica RB50 chromosome, complete genome 2 Negative NC_009495.1 Clostridium botulinum A str. ATCC 3502 chromosome, complete genome 2 Negative NC_022121.1 Chlamydia trachomatis strain J/31

  19. Lessons from Large-Scale Renewable Energy Integration Studies: Preprint

    SciTech Connect (OSTI)

    Bird, L.; Milligan, M.

    2012-06-01

    In general, large-scale integration studies in Europe and the United States find that high penetrations of renewable generation are technically feasible with operational changes and increased access to transmission. This paper describes other key findings such as the need for fast markets, large balancing areas, system flexibility, and the use of advanced forecasting.

  20. Large-Scale Streamwise Turbulent Structures in Hypersonic Boundary Layers 

    E-Print Network [OSTI]

    English, Benjamin L.

    2013-04-22

    Prior research in the field of boundary layer turbulence has identified streamwise-elongated large-scale turbulence structures in both low speed compressible and high speed (M=2.0) flow. No experimental work has been done in any flow of M> or =3...

  1. Surface CO2 leakage during the first shallow subsurface CO2 release experiment

    E-Print Network [OSTI]

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2008-01-01

    numbered 0-6. Plots of F CO2 measured along the surface wellin Figure 2. Figure 2. Log F CO2 maps for measurements madeof soil CO 2 flux (F CO2 ). The surface leakage onset,

  2. Commitment accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, SJ; Socolow, RH

    2014-01-01

    us My IOPscience Commitment accounting of CO2 emissions This9326/9/8/084018 Commitment accounting of CO 2 emissionsthe potential for ‘commitment accounting’ to inform public

  3. Stochastic Ordering of Interferences in Large-scale Wireless Networks

    E-Print Network [OSTI]

    Lee, Junghoon

    2012-01-01

    Stochastic orders are binary relations defined on probability distributions which capture intuitive notions like being larger or being more variable. This paper introduces stochastic ordering of interference distributions in large-scale networks modeled as point process. Interference is the main performance-limiting factor in most wireless networks, thus it is important to understand its statistics. Since closed-form results for the distribution of interference for such networks are only available in limited cases, interference of networks are compared using stochastic orders, even when closed form expressions for interferences are not tractable. We show that the interference from a large-scale network depends on the fading distributions with respect to the stochastic Laplace transform order. The condition for path-loss models is also established to have stochastic ordering between interferences. The stochastic ordering of interferences between different networks are also shown. Monte-Carlo simulations are us...

  4. Large-scale flow generation by inhomogeneous helicity

    E-Print Network [OSTI]

    Yokoi, Nobumitsu

    2015-01-01

    The effect of kinetic helicity (velocity--vorticity correlation) on turbulent momentum transport is investigated. The turbulent kinetic helicity (pseudoscalar) enters into the Reynolds stress (mirrorsymmetric tensor) expression in the form of a helicity gradient as the coupling coefficient for the mean vorticity and/or the angular velocity (axial vector), which suggests the possibility of mean-flow generation in the presence of inhomogeneous helicity. This inhomogeneous helicity effect, which was previously confirmed at the level of a turbulence- or closure-model simulation, is examined with the aid of direct numerical simulations of rotating turbulence with non-uniform helicity sustained by an external forcing. The numerical simulations show that the spatial distribution of the Reynolds stress is in agreement with the helicity-related term coupled with the angular velocity, and that a large-scale flow is generated in the direction of angular velocity. Such a large-scale flow is not induced in the case of hom...

  5. LARGE-SCALE MOTIONS IN THE PERSEUS GALAXY CLUSTER

    SciTech Connect (OSTI)

    Simionescu, A.; Werner, N.; Urban, O.; Allen, S. W.; Fabian, A. C.; Sanders, J. S.; Mantz, A.; Nulsen, P. E. J.; Takei, Y.

    2012-10-01

    By combining large-scale mosaics of ROSAT PSPC, XMM-Newton, and Suzaku X-ray observations, we present evidence for large-scale motions in the intracluster medium of the nearby, X-ray bright Perseus Cluster. These motions are suggested by several alternating and interleaved X-ray bright, low-temperature, low-entropy arcs located along the east-west axis, at radii ranging from {approx}10 kpc to over a Mpc. Thermodynamic features qualitatively similar to these have previously been observed in the centers of cool-core clusters, and were successfully modeled as a consequence of the gas sloshing/swirling motions induced by minor mergers. Our observations indicate that such sloshing/swirling can extend out to larger radii than previously thought, on scales approaching the virial radius.

  6. Simulating the Large-Scale Structure of HI Intensity Maps

    E-Print Network [OSTI]

    Seehars, Sebastian; Witzemann, Amadeus; Refregier, Alexandre; Amara, Adam; Akeret, Joel

    2015-01-01

    Intensity mapping of neutral hydrogen (HI) is a promising observational probe of cosmology and large-scale structure. We present wide field simulations of HI intensity maps based on N-body simulations, the halo model, and a phenomenological prescription for assigning HI mass to halos. The simulations span a redshift range of 0.35 HI. We apply and compare several estimators for the angular power spectrum and its covariance. We verify that they agree with analytic predictions on large scales and study the validity of approximations based on Gaussian random fields, particularly in the context of the covariance. We discuss how our results and the simulated maps can be useful for planning and interpreting future HI intensity mapping surveys.

  7. Clusters and Large-Scale Structure: the Synchrotron Keys

    E-Print Network [OSTI]

    Rudnick, L; Andernach, H; Battaglia, N; Brown, S; Brunetti, Gf; Burns, J; Clarke, T; Dolag, K; Farnsworth, D; Giovannini, G; Hallman, E; Johnston-Hollit, M; Jones, T W; Kang, H; Kassim, N; Kravtsov, A; Lazio, J; Lonsdale, C; McNamara, B; Myers, S; Owen, F; Pfrommer, C; Ryu, D; Sarazin, C; Subrahmanyan, R; Taylor, G; Taylor, R

    2009-01-01

    For over four decades, synchrotron-radiating sources have played a series of pathfinding roles in the study of galaxy clusters and large scale structure. Such sources are uniquely sensitive to the turbulence and shock structures of large-scale environments, and their cosmic rays and magnetic fields often play important dynamic and thermodynamic roles. They provide essential complements to studies at other wavebands. Over the next decade, they will fill essential gaps in both cluster astrophysics and the cosmological growth of structure in the universe, especially where the signatures of shocks and turbulence, or even the underlying thermal plasma itself, are otherwise undetectable. Simultaneously, synchrotron studies offer a unique tool for exploring the fundamental question of the origins of cosmic magnetic fields. This work will be based on the new generation of m/cm-wave radio telescopes now in construction, as well as major advances in the sophistication of 3-D MHD simulations.

  8. Performance Health Monitoring of Large-Scale Systems

    SciTech Connect (OSTI)

    Rajamony, Ram

    2014-11-20

    This report details the progress made on the ASCR funded project Performance Health Monitoring for Large Scale Systems. A large-­?scale application may not achieve its full performance potential due to degraded performance of even a single subsystem. Detecting performance faults, isolating them, and taking remedial action is critical for the scale of systems on the horizon. PHM aims to develop techniques and tools that can be used to identify and mitigate such performance problems. We accomplish this through two main aspects. The PHM framework encompasses diagnostics, system monitoring, fault isolation, and performance evaluation capabilities that indicates when a performance fault has been detected, either due to an anomaly present in the system itself or due to contention for shared resources between concurrently executing jobs. Software components called the PHM Control system then build upon the capabilities provided by the PHM framework to mitigate degradation caused by performance problems.

  9. The Phoenix series large scale LNG pool fire experiments.

    SciTech Connect (OSTI)

    Simpson, Richard B.; Jensen, Richard Pearson; Demosthenous, Byron; Luketa, Anay Josephine; Ricks, Allen Joseph; Hightower, Marion Michael; Blanchat, Thomas K.; Helmick, Paul H.; Tieszen, Sheldon Robert; Deola, Regina Anne; Mercier, Jeffrey Alan; Suo-Anttila, Jill Marie; Miller, Timothy J.

    2010-12-01

    The increasing demand for natural gas could increase the number and frequency of Liquefied Natural Gas (LNG) tanker deliveries to ports across the United States. Because of the increasing number of shipments and the number of possible new facilities, concerns about the potential safety of the public and property from an accidental, and even more importantly intentional spills, have increased. While improvements have been made over the past decade in assessing hazards from LNG spills, the existing experimental data is much smaller in size and scale than many postulated large accidental and intentional spills. Since the physics and hazards from a fire change with fire size, there are concerns about the adequacy of current hazard prediction techniques for large LNG spills and fires. To address these concerns, Congress funded the Department of Energy (DOE) in 2008 to conduct a series of laboratory and large-scale LNG pool fire experiments at Sandia National Laboratories (Sandia) in Albuquerque, New Mexico. This report presents the test data and results of both sets of fire experiments. A series of five reduced-scale (gas burner) tests (yielding 27 sets of data) were conducted in 2007 and 2008 at Sandia's Thermal Test Complex (TTC) to assess flame height to fire diameter ratios as a function of nondimensional heat release rates for extrapolation to large-scale LNG fires. The large-scale LNG pool fire experiments were conducted in a 120 m diameter pond specially designed and constructed in Sandia's Area III large-scale test complex. Two fire tests of LNG spills of 21 and 81 m in diameter were conducted in 2009 to improve the understanding of flame height, smoke production, and burn rate and therefore the physics and hazards of large LNG spills and fires.

  10. PERSPECTIVES This large-scale variation in base compo-

    E-Print Network [OSTI]

    Eyre-Walker, Adam

    ,000 kb kb 2,500 3,000 3,500 4,000 b Class II Class III Class I Figure 1 | Large-scale variation in G+C, according to its G+C content, by ultracentrifugation, and found that there was substantial variation in its mammals and birds, and that the G+C content of large (>300-kb) blocks of DNA varied from ~35 to 55

  11. Greening the Networks of Large-Scale Distributed Systems

    E-Print Network [OSTI]

    Lefèvre, Laurent

    -tier fat-tree architecture Energy savings of Green compared to No off : - 73% for a 20% workload - 68Greening the Networks of Large-Scale Distributed Systems ENS de Lyon ­ INRIA RESO ­ UCBL ­ LIP://perso.ens-lyon.fr/annececile.orgerie/networks.html HERMES : High-level Energy-awaRe Model for bandwidth reservation in End-to-end NetworkS · Unused network

  12. Primordial quantum nonequilibrium and large-scale cosmic anomalies

    E-Print Network [OSTI]

    Samuel Colin; Antony Valentini

    2015-06-12

    We study incomplete relaxation to quantum equilibrium at long wavelengths, during a pre-inflationary phase, as a possible explanation for the reported large-scale anomalies in the cosmic microwave background (CMB). Our scenario makes use of the de Broglie-Bohm pilot-wave formulation of quantum theory, in which the Born probability rule has a dynamical origin. The large-scale power deficit could arise from incomplete relaxation for the amplitudes of the primordial perturbations. We show, by numerical simulations for a spectator scalar field, that if the pre-inflationary era is radiation dominated then the deficit in the emerging power spectrum will have a characteristic shape (an inverse-tangent dependence on wavenumber k, with oscillations). It is found that our scenario is able to produce a power deficit in the observed region and of the observed (approximate) magnitude for an appropriate choice of cosmological parameters. We also discuss the large-scale anisotropy, which might arise from incomplete relaxation for the phases of the primordial perturbations. We present numerical simulations for phase relaxation, and we show how to define characteristic scales for amplitude and phase nonequilibrium. The extent to which the data might support our scenario is left as a question for future work. Our results suggest that we have a potentially viable model that might explain two apparently independent cosmic anomalies by means of a single mechanism.

  13. A Model of Plasma Heating by Large-Scale Flow

    E-Print Network [OSTI]

    Pongkitiwanichakul, P; Boldyrev, S; Mason, J; Perez, J C

    2015-01-01

    In this work we study the process of energy dissipation triggered by a slow large scale motion of a magnetized conducting fluid. Our consideration is motivated by the problem of heating the solar corona, which is believed to be governed by fast reconnection events set off by the slow motion of magnetic field lines anchored in the photospheric plasma. To elucidate the physics governing the disruption of the imposed laminar motion and the energy transfer to small scales, we propose a simplified model where the large-scale motion of magnetic field lines is prescribed not at the footpoints but rather imposed volumetrically. As a result, the problem can be treated numerically with an efficient, highly-accurate spectral method, allowing us to use a resolution and statistical ensemble exceeding those of the previous work. We find that, even though the large-scale deformations are slow, they eventually lead to reconnection events that drive a turbulent state at smaller scales. The small-scale turbulence displays many...

  14. Geospatial Optimization of Siting Large-Scale Solar Projects

    SciTech Connect (OSTI)

    Macknick, J.; Quinby, T.; Caulfield, E.; Gerritsen, M.; Diffendorfer, J.; Haines, S.

    2014-03-01

    Recent policy and economic conditions have encouraged a renewed interest in developing large-scale solar projects in the U.S. Southwest. However, siting large-scale solar projects is complex. In addition to the quality of the solar resource, solar developers must take into consideration many environmental, social, and economic factors when evaluating a potential site. This report describes a proof-of-concept, Web-based Geographical Information Systems (GIS) tool that evaluates multiple user-defined criteria in an optimization algorithm to inform discussions and decisions regarding the locations of utility-scale solar projects. Existing siting recommendations for large-scale solar projects from governmental and non-governmental organizations are not consistent with each other, are often not transparent in methods, and do not take into consideration the differing priorities of stakeholders. The siting assistance GIS tool we have developed improves upon the existing siting guidelines by being user-driven, transparent, interactive, capable of incorporating multiple criteria, and flexible. This work provides the foundation for a dynamic siting assistance tool that can greatly facilitate siting decisions among multiple stakeholders.

  15. A Fundamental Study of Convective Mixing of CO2 in Heterogeneous Geologic Media using Surrogate Fluids and Numerical Modeling

    E-Print Network [OSTI]

    , H. A., and Huppert H. E., 2010, Convective dissolution of carbon dioxide in saline aquifers, GeophysA Fundamental Study of Convective Mixing of CO2 in Heterogeneous Geologic Media using Surrogate mechanisms contributing to storage of supercritical CO2 (scCO2) in deep saline geologic formations. When

  16. The impact of geologic variability on capacity and cost estimates for storing CO2 in deep-saline aquifers

    E-Print Network [OSTI]

    Jackson, Robert B.

    The impact of geologic variability on capacity and cost estimates for storing CO2 in deep States could store many de- cades worth of the nation's current annual CO2 emissions, the likely cost estimates for storage span three orders of magnitude and average>$100/tonne CO2. However, when the cost

  17. Using batch experiments to quantify the potential of North Sea saline aquifers to leach contaminants upon injection of CO2

    E-Print Network [OSTI]

    contaminants upon injection of CO2 Kit Carruthers MSc, Dr. Mark Wilkinson, Dr. Katriona Edlmann · Saline aquifer CO2 storage limited by water and pore compressibilities · Pressure relief via water production · CO2 acidifies water upon dissolution, promoting leaching of heavy metals into solution

  18. Calculation of CO2 column heights in depleted gas fields from known pre-production gas column heights

    E-Print Network [OSTI]

    Wilkinson, Mark

    Calculation of CO2 column heights in depleted gas fields from known pre-production gas column that the CO2 is in a dense phase (either liquid or supercritical). Accurate assessment of the storage capacity also requires an estimation of the amount of CO2 that can be safely stored beneath the reservoir seal

  19. Short communication Satellite-derived surface water pCO2 and airsea CO2 fluxes

    E-Print Network [OSTI]

    Short communication Satellite-derived surface water pCO2 and air­sea CO2 fluxes in the northern for the estimation of the partial pressure of carbon dioxide (pCO2) and air­sea CO2 fluxes in the northern South), respectively, the monthly pCO2 fields were computed. The derived pCO2 was compared with the shipboard pCO2

  20. Process Integration Techniques for Planning Large-Scale Deployment of

    E-Print Network [OSTI]

    Ahrendt, Wolfgang

    Trends Strong demand growth for reliable, low-cost energy in the developing world will continue requirement to supply bioenergy 0.74-1.94 ha/capita Nonhebel (2005) #12;CO2 Abatement Technology "Wedges of existing power generation facilities Disadvantages Loss of power (15 ­ 20%) Increased cost of electricity

  1. MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE

    E-Print Network [OSTI]

    Foss, Bjarne A.

    MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE Lars Imsland Dagfinn Snarheim and control of a semi-closed O2/CO2 gas turbine cycle for CO2 capture. In the first part the process predictive control, Gas turbines, CO2 capture 1. INTRODUCTION Gas turbines are widely used for power

  2. Monitoring CO2 Intrusion and Associated Geochemical Transformations in a Shallow Groundwater System Using Complex

    E-Print Network [OSTI]

    Hubbard, Susan

    Geologic carbon sequestration, which aims to capture and inject carbon dioxide (CO2) into deep subsurface Using Complex Electrical Methods Baptiste Dafflon,, * Yuxin Wu, Susan S. Hubbard, Jens T. Birkholzer: The risk of CO2 leakage from a properly permitted deep geologic storage facility is expected to be very low

  3. Robust Morphological Measures for Large-Scale Structure

    E-Print Network [OSTI]

    T. Buchert

    1994-12-17

    A complete family of statistical descriptors for the morphology of large--scale structure based on Minkowski--Functionals is presented. These robust and significant measures can be used to characterize the local and global morphology of spatial patterns formed by a coverage of point sets which represent galaxy samples. Basic properties of these measures are highlighted and their relation to the `genus statistics' is discussed. Test models like a Poissonian point process and samples generated from a Voronoi--model are put into perspective.

  4. Large scale obscuration and related climate effects open literature bibliography

    SciTech Connect (OSTI)

    Russell, N.A.; Geitgey, J.; Behl, Y.K.; Zak, B.D.

    1994-05-01

    Large scale obscuration and related climate effects of nuclear detonations first became a matter of concern in connection with the so-called ``Nuclear Winter Controversy`` in the early 1980`s. Since then, the world has changed. Nevertheless, concern remains about the atmospheric effects of nuclear detonations, but the source of concern has shifted. Now it focuses less on global, and more on regional effects and their resulting impacts on the performance of electro-optical and other defense-related systems. This bibliography reflects the modified interest.

  5. Large-Scale Anisotropy of EGRET Gamma Ray Sources

    E-Print Network [OSTI]

    Luis Anchordoqui; Thomas McCauley; Thomas Paul; Olaf Reimer; Diego F. Torres

    2005-06-24

    In the course of its operation, the EGRET experiment detected high-energy gamma ray sources at energies above 100 MeV over the whole sky. In this communication, we search for large-scale anisotropy patterns among the catalogued EGRET sources using an expansion in spherical harmonics, accounting for EGRET's highly non-uniform exposure. We find significant excess in the quadrupole and octopole moments. This is consistent with the hypothesis that, in addition to the galactic plane, a second mid-latitude (5^{\\circ} < |b| < 30^{\\circ}) population, perhaps associated with the Gould belt, contributes to the gamma ray flux above 100 MeV.

  6. Future large-scale water-Cherenkov detector

    E-Print Network [OSTI]

    L. Agostino; M. Buizza-Avanzini; M. Marafini; T. Patzak; A. Tonazzo; M. Dracos; N. Vassilopoulos; D. Duchesneau; M. Mezzetto; L. Mosca

    2013-06-28

    MEMPHYS (MEgaton Mass PHYSics) is a proposed large-scale water-Cherenkov experiment to be performed deep underground. It is dedicated to nucleon decay searches and the detection of neutrinos from supernovae, solar, and atmospheric neutrinos, as well as neutrinos from a future beam to measure the CP violating phase in the leptonic sector and the mass hierarchy. This paper provides an overview of the latest studies on the expected performance of MEMPHYS in view of detailed estimates of its physics reach, mainly concerning neutrino beams.

  7. Large-scale cosmic flows and moving dark energy

    E-Print Network [OSTI]

    Jose Beltran Jimenez; Antonio L. Maroto

    2009-02-24

    Large-scale matter bulk flows with respect to the cosmic microwave background have very recently been detected on scales 100 Mpc/h and 300 Mpc/h by using two different techniques showing an excellent agreement in the motion direction. However, the unexpectedly large measured amplitudes are difficult to understand within the context of standard LCDM cosmology. In this work we show that the existence of such a flow could be signaling the presence of moving dark energy at the time when photons decoupled from matter. We also comment on the relation between the direction of the CMB dipole and the preferred axis observed in the quadrupole in this scenario.

  8. Streamflow forecasting for large-scale hydrologic systems 

    E-Print Network [OSTI]

    Awwad, Haitham Munir

    1991-01-01

    Farland (Member) J esTR ao (Head of Department) May 1991 ABSTRACT Streamflow Forecasting for Large-Scale Hydrologic Systems. (May 1991) Haitham Munir Awwad, B. S. , University of Jordan Chair of Advisory Committee: Dr. Juan B. Valdes An on-line streamflow... thankful to Dr. Ralph A. Wurbs and Dr. Marshall J. McFarland for their assistance on my advisory committee. Support for this thesis by the Department of Civil Engineering through the Engineering Excellence Fund, and by the U, S. Army Corps of Engineers...

  9. Large Scale GSHP as Alternative Energy for American Farmers Geothermal

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas:Montezuma, Arizona: Energy ResourcesProject | Open Energy Information Large Scale

  10. Enhanced Geothermal Systems (EGS) comparing water with CO2 as heat transmission fluids

    E-Print Network [OSTI]

    Pruess, Karsten

    2007-01-01

    Transmission Fluid in the EGS Integrating the Carbon StorageK. Enhanced Geothermal Systems (EGS) Using CO2 as WorkingNHANCED G EOTHERMAL S YSTEMS (EGS): C OMPARING W ATER AND CO

  11. The role of optimality in characterizing CO2 seepage from geological carbon sequestration sites

    E-Print Network [OSTI]

    Cortis, Andrea

    2009-01-01

    2 emission from a 1 GWatt coal-fired power plant (sufficientprogram designed for a 1 GW coal-fired power plant, whichCO 2 storage for a 1 GW coal-fired power plant. R=10 -2 R=

  12. Experimental studies on pore wetting and displacement of fluid by CO2 in porous media 

    E-Print Network [OSTI]

    Li, Xingxun

    2015-06-29

    The study of multiphase flow in porous media is highly relevant to many problems of great scientific importance, such as CO2 storage and enhanced oil recovery. Even though significant progress has been made in these ...

  13. Modeling Leakage through Faults of CO2 Stored in an Aquifer Kyung Won Chang,* Susan E. Minkoff,** and Steven L. Bryant,* SPE

    E-Print Network [OSTI]

    Minkoff, Susan E.

    for drinking water. Thus, CO2 leakage along faults will have three behaviors: upward migration from the storage. The difference arises because of preferential flow within the layer (CO2 in the upper part, water below

  14. Large scale structure simulations of inhomogeneous LTB void models

    E-Print Network [OSTI]

    David Alonso; Juan Garcia-Bellido; Troels Haugboelle; Julian Vicente

    2011-01-11

    We perform numerical simulations of large scale structure evolution in an inhomogeneous Lemaitre-Tolman-Bondi (LTB) model of the Universe. We follow the gravitational collapse of a large underdense region (a void) in an otherwise flat matter-dominated Einstein-deSitter model. We observe how the (background) density contrast at the centre of the void grows to be of order one, and show that the density and velocity profiles follow the exact non-linear LTB solution to the full Einstein equations for all but the most extreme voids. This result seems to contradict previous claims that fully relativistic codes are needed to properly handle the non-linear evolution of large scale structures, and that local Newtonian dynamics with an explicit expansion term is not adequate. We also find that the (local) matter density contrast grows with the scale factor in a way analogous to that of an open universe with a value of the matter density OmegaM(r) corresponding to the appropriate location within the void.

  15. Large scale CMB anomalies from thawing cosmic strings

    E-Print Network [OSTI]

    Christophe Ringeval; Daisuke Yamauchi; Jun'ichi Yokoyama; Francois R. Bouchet

    2015-10-07

    Cosmic strings formed during inflation are expected to be either diluted over super-Hubble distances, i.e., invisible today, or to have crossed our past light cone very recently. We discuss the latter situation in which a few strings imprint their signature in the Cosmic Microwave Background (CMB) Anisotropies after recombination. Being almost frozen in the Hubble flow, these strings are quasi static and evade almost all of the previously derived constraints on their tension while being able to source large scale anisotropies in the CMB sky. Using a local variance estimator on thousand of numerically simulated Nambu-Goto all sky maps, we compute the expected signal and show that it can mimic a dipole modulation at large angular scales while being negligible at small angles. Interestingly, such a scenario generically produces one cold spot from the thawing of a cosmic string loop. Mixed with anisotropies of inflationary origin, we find that a few strings of tension GU = O(1) x 10^(-6) match the amplitude of the dipole modulation reported in the Planck satellite measurements and could be at the origin of other large scale anomalies.

  16. Large-scale screening of hypothetical metalorganic frameworks

    E-Print Network [OSTI]

    of small molecules for gas storage1­6 , separ- ating mixtures7­12, catalysis13,14, analysis and detection15

  17. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground

    SciTech Connect (OSTI)

    Oldenburg

    2009-07-30

    July 21, 2009 Berkeley Lab summer lecture: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  18. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    ScienceCinema (OSTI)

    Oldenburg, Curtis M [LBNL Earth Sciences Division

    2011-04-28

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  19. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.

    2009-07-21

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  20. co2-transport | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transport Cost Model FENETL CO2 Transport Cost Model About the model: This model was developed to estimate the cost of transporting a user-specified mass rate of CO2 by pipeline...

  1. Engineered yeast for enhanced CO2 mineralization

    E-Print Network [OSTI]

    Barbero, Roberto Juan

    2013-01-01

    In this work, a biologically catalysed CO2 mineralization process for the capture of CO2 from point sources was designed, constructed at a laboratory scale, and, using standard chemical process scale-up protocols, was ...

  2. CO2 Cycle du Fiche dtaille

    E-Print Network [OSTI]

    Dintrans, Boris

    CO2 ­ Cycle du Carbone Polluants Fiche détaillée Niveau (A partir de la 2nd) #12;I. Introduction Les origines du CO2 atmosphérique dépendent de l'échelle de temps que l'on considère. A l, ce cycle commence avec la dissolution du CO2 dans l'eau de pluie pour former de l'acide carbonique

  3. A review of large-scale LNG spills : experiment and modeling.

    SciTech Connect (OSTI)

    Luketa-Hanlin, Anay Josephine

    2005-04-01

    The prediction of the possible hazards associated with the storage and transportation of liquefied natural gas (LNG) by ship has motivated a substantial number of experimental and analytical studies. This paper reviews the experimental and analytical work performed to date on large-scale spills of LNG. Specifically, experiments on the dispersion of LNG, as well as experiments of LNG fires from spills on water and land are reviewed. Explosion, pool boiling, and rapid phase transition (RPT) explosion studies are described and discussed, as well as models used to predict dispersion and thermal hazard distances. Although there have been significant advances in understanding the behavior of LNG spills, technical knowledge gaps to improve hazard prediction are identified. Some of these gaps can be addressed with current modeling and testing capabilities. A discussion of the state of knowledge and recommendations to further improve the understanding of the behavior of LNG spills on water is provided.

  4. Multiscale spatial density smoothing: an application to large-scale radiological survey and anomaly detection

    E-Print Network [OSTI]

    Tansey, Wesley; Reinhart, Alex; Scott, James G

    2015-01-01

    We consider the problem of estimating a spatially varying density function, motivated by problems that arise in large-scale radiological survey and anomaly detection. In this context, the density functions to be estimated are the background gamma-ray energy spectra at sites spread across a large geographical area, such as nuclear production and waste-storage sites, military bases, medical facilities, university campuses, or the downtown of a city. Several challenges combine to make this a difficult problem. First, the spectral density at any given spatial location may have both smooth and non-smooth features. Second, the spatial correlation in these density functions is neither stationary nor locally isotropic. Third, the spatial correlation decays at different length scales at different locations in the support of the underlying density. Finally, at some spatial locations, there is very little data. We present a method called multiscale spatial density smoothing that successfully addresses these challenges. ...

  5. Nuclear-pumped lasers for large-scale applications

    SciTech Connect (OSTI)

    Anderson, R.E.; Leonard, E.M.; Shea, R.F.; Berggren, R.R.

    1989-05-01

    Efficient initiation of large-volume chemical lasers may be achieved by neutron induced reactions which produce charged particles in the final state. When a burst mode nuclear reactor is used as the neutron source, both a sufficiently intense neutron flux and a sufficiently short initiation pulse may be possible. Proof-of-principle experiments are planned to demonstrate lasing in a direct nuclear-pumped large-volume system; to study the effects of various neutron absorbing materials on laser performance; to study the effects of long initiation pulse lengths; to demonstrate the performance of large-scale optics and the beam quality that may be obtained; and to assess the performance of alternative designs of burst systems that increase the neutron output and burst repetition rate. 21 refs., 8 figs., 5 tabs.

  6. Nuclear-pumped lasers for large-scale applications

    SciTech Connect (OSTI)

    Anderson, R.E.; Leonard, E.M.; Shea, R.E.; Berggren, R.R.

    1988-01-01

    Efficient initiation of large-volume chemical lasers may be achieved by neutron induced reactions which produce charged particles in the final state. When a burst mode nuclear reactor is used as the neutron source, both a sufficiently intense neutron flux and a sufficient short initiation pulse may be possible. Proof-of-principle experiments are planned to demonstrate lasing in a direct nuclear-pumped large-volume system: to study the effects of various neutron absorbing materials on laser performance; to study the effects of long initiation pulse lengths; to determine the performance of large-scale optics and the beam quality that may bo obtained; and to assess the performance of alternative designs of burst systems that increase the neutron output and burst repetition rate. 21 refs., 7 figs., 5 tabs.

  7. The XMM/Megacam-VST/VIRMOS Large Scale Structure Survey

    E-Print Network [OSTI]

    M. Pierre

    2000-11-08

    The objective of the XMM-LSS Survey is to map the large scale structure of the universe, as highlighted by clusters and groups of galaxies, out to a redshift of about 1, over a single 8x8 sq.deg. area. For the first time, this will reveal the topology of the distribution of the deep potential wells and provide statistical measurements at truly cosmological distances. In addition, clusters identified via their X-ray properties will form the basis for the first uniformly-selected, multi-wavelength survey of the evolution of clusters and individual cluster galaxies as a function of redshift. The survey will also address the very important question of the QSO distribution within the cosmic web.

  8. Unfolding large-scale online collaborative human dynamics

    E-Print Network [OSTI]

    Zha, Yilong; Zhou, Changsong

    2015-01-01

    Large-scale interacting human activities underlie all social and economic phenomena, but quantitative understanding of regular patterns and mechanism is very challenging and still rare. Self-organized online collaborative activities with precise record of event timing provide unprecedented opportunity. Our empirical analysis of the history of millions of updates in Wikipedia shows a universal double power-law distribution of time intervals between consecutive updates of an article. We then propose a generic model to unfold collaborative human activities into three modules: (i) individual behavior characterized by Poissonian initiation of an action, (ii) human interaction captured by a cascading response to others with a power-law waiting time, and (iii) population growth due to increasing number of interacting individuals. This unfolding allows us to obtain analytical formula that is fully supported by the universal patterns in empirical data. Our modeling approaches reveal "simplicity" beyond complex interac...

  9. Planning under uncertainty solving large-scale stochastic linear programs

    SciTech Connect (OSTI)

    Infanger, G. . Dept. of Operations Research Technische Univ., Vienna . Inst. fuer Energiewirtschaft)

    1992-12-01

    For many practical problems, solutions obtained from deterministic models are unsatisfactory because they fail to hedge against certain contingencies that may occur in the future. Stochastic models address this shortcoming, but up to recently seemed to be intractable due to their size. Recent advances both in solution algorithms and in computer technology now allow us to solve important and general classes of practical stochastic problems. We show how large-scale stochastic linear programs can be efficiently solved by combining classical decomposition and Monte Carlo (importance) sampling techniques. We discuss the methodology for solving two-stage stochastic linear programs with recourse, present numerical results of large problems with numerous stochastic parameters, show how to efficiently implement the methodology on a parallel multi-computer and derive the theory for solving a general class of multi-stage problems with dependency of the stochastic parameters within a stage and between different stages.

  10. Recovery Act - Large Scale SWNT Purification and Solubilization

    SciTech Connect (OSTI)

    Michael Gemano; Dr. Linda B. McGown

    2010-10-07

    The goal of this Phase I project was to establish a quantitative foundation for development of binary G-gels for large-scale, commercial processing of SWNTs and to develop scientific insight into the underlying mechanisms of solubilization, selectivity and alignment. In order to accomplish this, we performed systematic studies to determine the effects of G-gel composition and experimental conditions that will enable us to achieve our goals that include (1) preparation of ultra-high purity SWNTs from low-quality, commercial SWNT starting materials, (2) separation of MWNTs from SWNTs, (3) bulk, non-destructive solubilization of individual SWNTs in aqueous solution at high concentrations (10-100 mg/mL) without sonication or centrifugation, (4) tunable enrichment of subpopulations of the SWNTs based on metallic vs. semiconductor properties, diameter, or chirality and (5) alignment of individual SWNTs.

  11. 2015 Carbon Storage final.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from prominent storage efforts both domestic and international including the Regional Carbon Sequestration Partnership's large-scale field projects. Additional plenary sessions...

  12. Energy Storage for the Power Grid

    ScienceCinema (OSTI)

    Wang, Wei; Imhoff, Carl; Vaishnav, Dave

    2014-06-12

    The iron vanadium redox flow battery was developed by researchers at Pacific Northwest National Laboratory as a solution to large-scale energy storage for the power grid.

  13. Energy Storage for the Power Grid

    SciTech Connect (OSTI)

    Wang, Wei; Imhoff, Carl; Vaishnav, Dave

    2014-04-23

    The iron vanadium redox flow battery was developed by researchers at Pacific Northwest National Laboratory as a solution to large-scale energy storage for the power grid.

  14. Training a Large Scale Classifier with the Quantum Adiabatic Algorithm

    E-Print Network [OSTI]

    Hartmut Neven; Vasil S. Denchev; Geordie Rose; William G. Macready

    2009-12-04

    In a previous publication we proposed discrete global optimization as a method to train a strong binary classifier constructed as a thresholded sum over weak classifiers. Our motivation was to cast the training of a classifier into a format amenable to solution by the quantum adiabatic algorithm. Applying adiabatic quantum computing (AQC) promises to yield solutions that are superior to those which can be achieved with classical heuristic solvers. Interestingly we found that by using heuristic solvers to obtain approximate solutions we could already gain an advantage over the standard method AdaBoost. In this communication we generalize the baseline method to large scale classifier training. By large scale we mean that either the cardinality of the dictionary of candidate weak classifiers or the number of weak learners used in the strong classifier exceed the number of variables that can be handled effectively in a single global optimization. For such situations we propose an iterative and piecewise approach in which a subset of weak classifiers is selected in each iteration via global optimization. The strong classifier is then constructed by concatenating the subsets of weak classifiers. We show in numerical studies that the generalized method again successfully competes with AdaBoost. We also provide theoretical arguments as to why the proposed optimization method, which does not only minimize the empirical loss but also adds L0-norm regularization, is superior to versions of boosting that only minimize the empirical loss. By conducting a Quantum Monte Carlo simulation we gather evidence that the quantum adiabatic algorithm is able to handle a generic training problem efficiently.

  15. Phase-Changing Ionic Liquids: CO2 Capture with Ionic Liquids Involving Phase Change

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: Notre Dame is developing a new CO2 capture process that uses special ionic liquids (ILs) to remove CO2 from the gas exhaust of coal-fired power plants. ILs are salts that are normally liquid at room temperature, but Notre Dame has discovered a new class of ILs that are solid at room temperature and change to liquid when they bind to CO2. Upon heating, the CO2 is released for storage, and the ILs re-solidify and donate some of the heat generated in the process to facilitate further CO2 release. These new ILs can reduce the energy required to capture CO2 from the exhaust stream of a coal-fired power plant when compared to state-ofthe- art technology.

  16. Energy Department Awards $66.7 Million for Large-Scale Carbon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to permanently store CO2. ADM's ethanol plant in Decatur, IL, will serve as the source of CO2 for the project. ADM will cost share the expense of the CO2, which will come...

  17. Spatial Energy Balancing in Large-scale Wireless Multihop Networks

    E-Print Network [OSTI]

    de Veciana, Gustavo

    communications systems and/or distributed sensing ap- plications, where energy storage and availability may be quite limited. There are many levels at which one can address this problem. Advances in silicon

  18. Using CO2 spatial variability to quantify representation errors of satellite CO2 retrievals

    E-Print Network [OSTI]

    Michalak, Anna M.

    global data of column- averaged CO2 dry-air mole fraction (XCO2) at high spatial resolutions. These dataUsing CO2 spatial variability to quantify representation errors of satellite CO2 retrievals A. A 2008; published 29 August 2008. [1] Satellite measurements of column-averaged CO2 dry- air mole

  19. TIME-LAPSE SEISMIC MODELING & INVERSION OF CO2 SATURATION FOR SEQUESTRATION AND ENHANCED OIL RECOVERY

    SciTech Connect (OSTI)

    Mark A. Meadows

    2006-03-31

    Injection of carbon dioxide (CO2) into subsurface aquifers for geologic storage/sequestration, and into subsurface hydrocarbon reservoirs for enhanced oil recovery, has become an important topic to the nation because of growing concerns related to global warming and energy security. In this project we developed new ways to predict and quantify the effects of CO2 on seismic data recorded over porous reservoir/aquifer rock systems. This effort involved the research and development of new technology to: (1) Quantitatively model the rock physics effects of CO2 injection in porous saline and oil/brine reservoirs (both miscible and immiscible). (2) Quantitatively model the seismic response to CO2 injection (both miscible and immiscible) from well logs (1D). (3) Perform quantitative inversions of time-lapse 4D seismic data to estimate injected CO2 distributions within subsurface reservoirs and aquifers. This work has resulted in an improved ability to remotely monitor the injected CO2 for safe storage and enhanced hydrocarbon recovery, predict the effects of CO2 on time-lapse seismic data, and estimate injected CO2 saturation distributions in subsurface aquifers/reservoirs. We applied our inversion methodology to a 3D time-lapse seismic dataset from the Sleipner CO2 sequestration project, Norwegian North Sea. We measured changes in the seismic amplitude and traveltime at the top of the Sleipner sandstone reservoir and used these time-lapse seismic attributes in the inversion. Maps of CO2 thickness and its standard deviation were generated for the topmost layer. From this information, we estimated that 7.4% of the total CO2 injected over a five-year period had reached the top of the reservoir. This inversion approach could also be applied to the remaining levels within the anomalous zone to obtain an estimate of the total CO2 injected.

  20. Reducing Data Center Loads for a Large-Scale, Net Zero Office...

    Energy Savers [EERE]

    Reducing Data Center Loads for a Large-Scale, Net Zero Office Building Reducing Data Center Loads for a Large-Scale, Net Zero Office Building Document describes the design,...

  1. The IR-resummed Effective Field Theory of Large Scale Structures...

    Office of Scientific and Technical Information (OSTI)

    The IR-resummed Effective Field Theory of Large Scale Structures Citation Details In-Document Search Title: The IR-resummed Effective Field Theory of Large Scale Structures We...

  2. HyLights -- Tools to Prepare the Large-Scale European Demonstration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HyLights -- Tools to Prepare the Large-Scale European Demonstration Projects on Hydrogen for Transport HyLights -- Tools to Prepare the Large-Scale European Demonstration Projects...

  3. Aalborg Universitet Optimal Selection of AC Cables for Large Scale Offshore Wind Farms

    E-Print Network [OSTI]

    Hu, Weihao

    Aalborg Universitet Optimal Selection of AC Cables for Large Scale Offshore Wind Farms Hou, Peng Cables for Large Scale Offshore Wind Farms. In Proceedings of the 40th Annual Conference of IEEE of AC Cables for Large Scale Offshore Wind Farms Peng Hou, Weihao Hu, Zhe Chen Department of Energy

  4. SMALL AND LARGE-SCALE MAGNETIC FIELDS INVOLVED WITH SOLAR FLARES

    E-Print Network [OSTI]

    ABSTRACT SMALL AND LARGE-SCALE MAGNETIC FIELDS INVOLVED WITH SOLAR FLARES by Chang Liu Solar flares of an EUV sigmoid. #12;SMALL AND LARGE-SCALE MAGNETIC FIELDS INVOLVED WITH SOLAR FLARES by Chang Liu RESERVED #12;APPROVAL PAGE SMALL AND LARGE-SCALE MAGNETIC FIELDS INVOLVED WITH SOLAR FLARES Chang Liu Dr

  5. Microwave Mapping As a Possible New Diagnostic Tool for LargeScale Solar Magnetic Fields

    E-Print Network [OSTI]

    Petrovay, Kristóf

    Microwave Mapping As a Possible New Diagnostic Tool for Large­Scale Solar Magnetic Fields M of microwave maps in the study of weak large­scale solar magnetic fields is discussed. Our knowledge of the large­scale solar background magnetic fields is limited by the circumstance that magnetograph

  6. UNIVERSITY OF SOUTHERN CALIFORNIA Large-Scale Active Middleware (LSAM) September 3, 1997 1 of 27

    E-Print Network [OSTI]

    Touch, Joe

    transport UNIVERSITY OF SOUTHERN CALIFORNIA Large-Scale Active Middleware (LSAM) September 3, 1997 8 of 27UNIVERSITY OF SOUTHERN CALIFORNIA Large-Scale Active Middleware (LSAM) September 3, 1997 1 of 27 Middleware Project USC/ISI Computer Networks Division UNIVERSITY OF SOUTHERN CALIFORNIA Large-Scale Active

  7. Large-Scale Spray Releases: Additional Aerosol Test Results

    SciTech Connect (OSTI)

    Daniel, Richard C.; Gauglitz, Phillip A.; Burns, Carolyn A.; Fountain, Matthew S.; Shimskey, Rick W.; Billing, Justin M.; Bontha, Jagannadha R.; Kurath, Dean E.; Jenks, Jeromy WJ; MacFarlan, Paul J.; Mahoney, Lenna A.

    2013-08-01

    One of the events postulated in the hazard analysis for the Waste Treatment and Immobilization Plant (WTP) and other U.S. Department of Energy (DOE) nuclear facilities is a breach in process piping that produces aerosols with droplet sizes in the respirable range. The current approach for predicting the size and concentration of aerosols produced in a spray leak event involves extrapolating from correlations reported in the literature. These correlations are based on results obtained from small engineered spray nozzles using pure liquids that behave as a Newtonian fluid. The narrow ranges of physical properties on which the correlations are based do not cover the wide range of slurries and viscous materials that will be processed in the WTP and in processing facilities across the DOE complex. To expand the data set upon which the WTP accident and safety analyses were based, an aerosol spray leak testing program was conducted by Pacific Northwest National Laboratory (PNNL). PNNL’s test program addressed two key technical areas to improve the WTP methodology (Larson and Allen 2010). The first technical area was to quantify the role of slurry particles in small breaches where slurry particles may plug the hole and prevent high-pressure sprays. The results from an effort to address this first technical area can be found in Mahoney et al. (2012a). The second technical area was to determine aerosol droplet size distribution and total droplet volume from prototypic breaches and fluids, including sprays from larger breaches and sprays of slurries for which literature data are mostly absent. To address the second technical area, the testing program collected aerosol generation data at two scales, commonly referred to as small-scale and large-scale testing. The small-scale testing and resultant data are described in Mahoney et al. (2012b), and the large-scale testing and resultant data are presented in Schonewill et al. (2012). In tests at both scales, simulants were used to mimic the relevant physical properties projected for actual WTP process streams.

  8. The Large Scale Roll-Out of Electric Vehicles

    E-Print Network [OSTI]

    Talaei, Alireza; Begg, Katherine; Jamasb, Tooraj

    2012-10-26

    , biomass power plant, nuclear, imported electricity, coal steam turbine, heavy fuel oil steam turbine and natural gas combined cycle (Vuorinen, 2007). In 2007, nuclear and renewable were the main sources which were used to generate up to 17 GW and 20 GW... factor from such a plant is between 350 and 450 g/kWh. Our calculations (for 2010) are in line with the CO2 emission factor of a typical gas turbine power plant operating in the UK in 2010. 0.15 0.2 0.25 0.3 0.35 0.4 0.45 0 1 2 3 4 5 6 7 8 9 10 11 12...

  9. Development of a Large-Scale Ubiquitous Computing Interface We propose the development of a unique experimental facility for the exploration of large-scale ubiquitous computing

    E-Print Network [OSTI]

    Haro, Antonio

    Development of a Large-Scale Ubiquitous Computing Interface 1 Summary We propose the development of a unique experimental facility for the exploration of large-scale ubiquitous computing interfaces reveal how it will be used and the scientific issues raised. Current ubiquitous computing experiments

  10. Large Scale Obscuration and Related Climate Effects Workshop: Proceedings

    SciTech Connect (OSTI)

    Zak, B.D.; Russell, N.A.; Church, H.W.; Einfeld, W.; Yoon, D.; Behl, Y.K.

    1994-05-01

    A Workshop on Large Scale Obsurcation and Related Climate Effects was held 29--31 January, 1992, in Albuquerque, New Mexico. The objectives of the workshop were: to determine through the use of expert judgement the current state of understanding of regional and global obscuration and related climate effects associated with nuclear weapons detonations; to estimate how large the uncertainties are in the parameters associated with these phenomena (given specific scenarios); to evaluate the impact of these uncertainties on obscuration predictions; and to develop an approach for the prioritization of further work on newly-available data sets to reduce the uncertainties. The workshop consisted of formal presentations by the 35 participants, and subsequent topical working sessions on: the source term; aerosol optical properties; atmospheric processes; and electro-optical systems performance and climatic impacts. Summaries of the conclusions reached in the working sessions are presented in the body of the report. Copies of the transparencies shown as part of each formal presentation are contained in the appendices (microfiche).

  11. Large scale electromechanical transistor with application in mass sensing

    SciTech Connect (OSTI)

    Jin, Leisheng; Li, Lijie

    2014-12-07

    Nanomechanical transistor (NMT) has evolved from the single electron transistor, a device that operates by shuttling electrons with a self-excited central conductor. The unfavoured aspects of the NMT are the complexity of the fabrication process and its signal processing unit, which could potentially be overcome by designing much larger devices. This paper reports a new design of large scale electromechanical transistor (LSEMT), still taking advantage of the principle of shuttling electrons. However, because of the large size, nonlinear electrostatic forces induced by the transistor itself are not sufficient to drive the mechanical member into vibration—an external force has to be used. In this paper, a LSEMT device is modelled, and its new application in mass sensing is postulated using two coupled mechanical cantilevers, with one of them being embedded in the transistor. The sensor is capable of detecting added mass using the eigenstate shifts method by reading the change of electrical current from the transistor, which has much higher sensitivity than conventional eigenfrequency shift approach used in classical cantilever based mass sensors. Numerical simulations are conducted to investigate the performance of the mass sensor.

  12. Bias in the Effective Field Theory of Large Scale Structures

    E-Print Network [OSTI]

    Leonardo Senatore

    2014-11-05

    We study how to describe collapsed objects, such as galaxies, in the context of the Effective Field Theory of Large Scale Structures. The overdensity of galaxies at a given location and time is determined by the initial tidal tensor, velocity gradients and spatial derivatives of the regions of dark matter that, during the evolution of the universe, ended up at that given location. Similarly to what recently done for dark matter, we show how this Lagrangian space description can be recovered by upgrading simpler Eulerian calculations. We describe the Eulerian theory. We show that it is perturbatively local in space, but non-local in time, and we explain the observational consequences of this fact. We give an argument for why to a certain degree of accuracy the theory can be considered as quasi time-local and explain what the operator structure is in this case. We describe renormalization of the bias coefficients so that, after this and after upgrading the Eulerian calculation to a Lagrangian one, the perturbative series for galaxies correlation functions results in a manifestly convergent expansion in powers of $k/k_{\\rm NL}$ and $k/k_{\\rm M}$, where $k$ is the wavenumber of interest, $k_{\\rm NL}$ is the wavenumber associated to the non-linear scale, and $k_{\\rm M}$ is the comoving wavenumber enclosing the mass of a galaxy.

  13. ANALYSIS OF TURBULENT MIXING JETS IN LARGE SCALE TANK

    SciTech Connect (OSTI)

    Lee, S; Richard Dimenna, R; Robert Leishear, R; David Stefanko, D

    2007-03-28

    Flow evolution models were developed to evaluate the performance of the new advanced design mixer pump for sludge mixing and removal operations with high-velocity liquid jets in one of the large-scale Savannah River Site waste tanks, Tank 18. This paper describes the computational model, the flow measurements used to provide validation data in the region far from the jet nozzle, the extension of the computational results to real tank conditions through the use of existing sludge suspension data, and finally, the sludge removal results from actual Tank 18 operations. A computational fluid dynamics approach was used to simulate the sludge removal operations. The models employed a three-dimensional representation of the tank with a two-equation turbulence model. Both the computational approach and the models were validated with onsite test data reported here and literature data. The model was then extended to actual conditions in Tank 18 through a velocity criterion to predict the ability of the new pump design to suspend settled sludge. A qualitative comparison with sludge removal operations in Tank 18 showed a reasonably good comparison with final results subject to significant uncertainties in actual sludge properties.

  14. Large-Scale Magnetic Fields, Dark Energy and QCD

    E-Print Network [OSTI]

    Federico R. Urban; Ariel R. Zhitnitsky

    2010-08-20

    Cosmological magnetic fields are being observed with ever increasing correlation lengths, possibly reaching the size of superclusters, therefore disfavouring the conventional picture of generation through primordial seeds later amplified by galaxy-bound dynamo mechanisms. In this paper we put forward a fundamentally different approach that links such large-scale magnetic fields to the cosmological vacuum energy. In our scenario the dark energy is due to the Veneziano ghost (which solves the $U(1)_A$ problem in QCD). The Veneziano ghost couples through the triangle anomaly to the electromagnetic field with a constant which is unambiguously fixed in the standard model. While this interaction does not produce any physical effects in Minkowski space, it triggers the generation of a magnetic field in an expanding universe at every epoch. The induced energy of the magnetic field is thus proportional to cosmological vacuum energy: $\\rho_{EM}\\simeq B^2 \\simeq (\\frac{\\alpha}{4\\pi})^2 \\rho_{DE}$, $\\rho_{DE}$ hence acting as a source for the magnetic energy $\\rho_{EM}$. The corresponding numerical estimate leads to a magnitude in the nG range. There are two unique and distinctive predictions of our proposal: an uninterrupted active generation of Hubble size correlated magnetic fields throughout the evolution of the universe; the presence of parity violation on the enormous scales $1/H$, which apparently has been already observed in CMB. These predictions are entirely rooted into the standard model of particle physics.

  15. Importance-Truncated Large-Scale Shell Model

    E-Print Network [OSTI]

    Stumpf, Christina; Roth, Robert

    2015-01-01

    We propose an importance-truncation scheme for the large-scale nuclear shell model that extends its range of applicability to larger valence spaces and mid-shell nuclei. It is based on a perturbative measure for the importance of individual basis states that acts as an additional truncation for the many-body model space in which the eigenvalue problem of the Hamiltonian is solved numerically. Through a posteriori extrapolations of all observables to vanishing importance threshold, the full shell-model results can be recovered. In addition to simple threshold extrapolations, we explore extrapolations based on the energy variance. We apply the importance-truncated shell model for the study of 56-Ni in the pf valence space and of 60-Zn and 64-Ge in the pfg9/2 space. We demonstrate the efficiency and accuracy of the approach, which pave the way for future shell-model calculations in larger valence spaces with valence-space interactions derived in ab initio approaches.

  16. Large scale structures in gas-liquid mixture flows

    SciTech Connect (OSTI)

    Davis, M.R.; Fungtamasan, B.

    1984-12-01

    Relatively slow variations in mixture void fraction in gas-liquid mixture flows are indicated by low pass filter averaging. The slow void fluctuations are found to have a regular characteristic frequency or scale in the churn flow regime or near the boundary with the dispersed bubble flow regime. These regular disturbances develop inherently in a vertical pipe flow in strength and in size and are not due to the method of flow mixing. There was no evidence of distinctive gas slugs in the flow, and the structures were identified as large clouds of bubbles which moved faster than the average velocity, growing in size and strength as they moved with the flow. The magnitude of the voidage fluctuations in the churn flow regime was on average 57% of the value for a slug flow. The large scale bubble clouds convect coherently over relatively long distances a up to 1.45 times the mean mixture flow velocity at a gas volume flow fraction of 0.4. In the bubbl flow regime, the slow voidage variations were more random in scale and were only approx. 10% of the slug flow (maximum possible) value. However, even in the bubble flow regime, the disturbances convected coherently over relatively long distances at a velocity of approx. 1.1 time the mean mixture velocity.

  17. Large scale CMB anomalies from thawing cosmic strings

    E-Print Network [OSTI]

    Ringeval, Christophe; Yokoyama, Jun'ichi; Bouchet, Francois R

    2015-01-01

    Cosmic strings formed during inflation are expected to be either diluted over super-Hubble distances, i.e., invisible today, or to have crossed our past light cone very recently. We discuss the latter situation in which a few strings imprint their signature in the Cosmic Microwave Background (CMB) Anisotropies after recombination. Being almost frozen in the Hubble flow, these strings are quasi static and evade almost all of the previously derived constraints on their tension while being able to source large scale anisotropies in the CMB sky. Using a local variance estimator on thousand of numerically simulated Nambu-Goto all sky maps, we compute the expected signal and show that it can mimic a dipole modulation at large angular scales while being negligible at small angles. Interestingly, such a scenario generically produces one cold spot from the thawing of a cosmic string loop. Mixed with anisotropies of inflationary origin, we find that a few strings of tension GU = O(1) x 10^(-6) match the amplitude of th...

  18. Modeling of CO2 Reduction Impacts on Energy Prices with Modelica Philip Machanick1

    E-Print Network [OSTI]

    Machanick, Philip

    at an increasing rate as technologies such as wind, solar and carbon capture and storage mature ­ hence the need.machanick@gmail.com, petfr@ida.liu.se Abstract There is growing evidence that anthropogenic carbon dioxide (CO2) emissions will then grow at an increas- ing rate as technologies such as wind, solar and car- bon capture and storage

  19. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01

    emissions from traded fossil fuels; Top), production (F Pr )Regional, and National Fossil-Fuel CO 2 Emissions (Carbonfrom the burning of fossil fuels are conventionally

  20. CO2 Heat Pump Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO 2 Heat Pump Water Heater 2014 Building Technologies Office Peer Review Evaporator Kyle Gluesenkamp, gluesenkampk@ornl.gov Oak Ridge National Laboratory Project Summary Timeline:...

  1. CO2 Conference Presentation | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    CO2 Conference Presentation More Documents & Publications POWER-GEN Conference Presentation U.S. Energy Association Presentation EEI Environment Meetings Presentation...

  2. CO2 Sorption to Subsingle Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction Measurements

    SciTech Connect (OSTI)

    Rother, Gernot; Ilton, Eugene S.; Wallacher, Dirk; Hauss, Thomas; Schaef, Herbert T.; Qafoku, Odeta; Rosso, Kevin M.; Felmy, Andrew R.; Krukowski, Elizabeth; Stack, Andrew G.; Grimm, Nico; Bodnar, Robert J.

    2013-01-15

    Geologic storage of CO2 requires that the caprock sealing the storage rock is highly impermeable by CO2. Swelling clays, which are important components of caprocks, may interact with CO2 under volume change, potentially impacting the seal quality. The interactions of scCO2 with Na saturated montmorillonite clay containing a sub-single layer of water in the interlayer region have been studied by sorption and neutron diffraction techniques. The excess sorption isotherms show maxima at bulk CO2 densities of ??0.15 g/cm3, followed by an approximately linear decrease of excess sorption to zero and negative values with increasing CO2 bulk density. Neutron diffraction experiments on the same clay sample measured interlayer spacing and composition. The results show that limited amounts of CO2 are sorbed into the interlayer region, leading to depression of the interlayer peak intensity and an increase of the d(001) spacing by ca. 0.5 Å. The density of CO2 in the clay pores is relatively stable over a wide range of CO2 pressures at a given temperature, indicating the formation of a clay-CO2 phase. At the excess sorption maximum, increasing CO2 sorption with decreasing temperature is observed while the high-pressure sorption properties exhibit weak temperature dependence.

  3. CO2 Adsorption to Sub-Single Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction

    SciTech Connect (OSTI)

    Rother, Gernot [ORNL; Ilton, Eugene [Pacific Northwest National Laboratory (PNNL); Wallacher, Dirk [Helmholtz-Zentrum Berlin; Hauss, Thomas [Helmholtz-Zentrum Berlin; Schaef, Herbert [Pacific Northwest National Laboratory (PNNL); Qafoku, Odeta [Pacific Northwest National Laboratory (PNNL); Rosso, Kevin M. [Pacific Northwest National Laboratory (PNNL); Felmy, Andrew [Pacific Northwest National Laboratory (PNNL); Krukowski, Elizabeth G [ORNL; Stack, Andrew G [ORNL; Bodnar, Robert J [ORNL

    2013-01-01

    Geologic storage of CO2 requires that the caprock sealing the storage rock is highly impermeable by CO2. Swelling clays, which are important components of caprocks, may react with CO2 under volume change, potentially impacting the seal quality. The interactions of scCO2 with Na saturated montmorillonite clay containing a sub-single layer of water in the interlayer region have been studied by sorption and neutron diffraction techniques. The excess sorption isotherms show maxima at bulk CO2 densities of 0.15 g/cm3, followed by an approximately linear decrease of excess sorption to zero and negative values with increasing CO2 bulk density. Neutron diffraction experiments on the same clay sample measured interlayer spacing and composition. The results show that limited amounts of CO2 are sorbed into the interlayer region, leading to depression of the interlayer peak intensity and an increase of the d(001) spacing by ca. 0.5 . The density of CO2 in the clay pores is relatively stable over a wide range of CO2 pressures at a given temperature, indicating the formation of a clay-CO2 phase. At low pressure increasing CO2 adsorption with decreasing temperature is observed while the high-pressure sorption properties exhibit weak or no temperature dependence. Supercritical fluids, sorption phenomena, carbon dioxide, carbon sequestration, caprock integrity

  4. Large-Scale Spray Releases: Initial Aerosol Test Results

    SciTech Connect (OSTI)

    Schonewill, Philip P.; Gauglitz, Phillip A.; Bontha, Jagannadha R.; Daniel, Richard C.; Kurath, Dean E.; Adkins, Harold E.; Billing, Justin M.; Burns, Carolyn A.; Davis, James M.; Enderlin, Carl W.; Fischer, Christopher M.; Jenks, Jeromy WJ; Lukins, Craig D.; MacFarlan, Paul J.; Shutthanandan, Janani I.; Smith, Dennese M.

    2012-12-01

    One of the events postulated in the hazard analysis at the Waste Treatment and Immobilization Plant (WTP) and other U.S. Department of Energy (DOE) nuclear facilities is a breach in process piping that produces aerosols with droplet sizes in the respirable range. The current approach for predicting the size and concentration of aerosols produced in a spray leak involves extrapolating from correlations reported in the literature. These correlations are based on results obtained from small engineered spray nozzles using pure liquids with Newtonian fluid behavior. The narrow ranges of physical properties on which the correlations are based do not cover the wide range of slurries and viscous materials that will be processed in the WTP and across processing facilities in the DOE complex. Two key technical areas were identified where testing results were needed to improve the technical basis by reducing the uncertainty due to extrapolating existing literature results. The first technical need was to quantify the role of slurry particles in small breaches where the slurry particles may plug and result in substantially reduced, or even negligible, respirable fraction formed by high-pressure sprays. The second technical need was to determine the aerosol droplet size distribution and volume from prototypic breaches and fluids, specifically including sprays from larger breaches with slurries where data from the literature are scarce. To address these technical areas, small- and large-scale test stands were constructed and operated with simulants to determine aerosol release fractions and generation rates from a range of breach sizes and geometries. The properties of the simulants represented the range of properties expected in the WTP process streams and included water, sodium salt solutions, slurries containing boehmite or gibbsite, and a hazardous chemical simulant. The effect of anti-foam agents was assessed with most of the simulants. Orifices included round holes and rectangular slots. The round holes ranged in size from 0.2 to 4.46 mm. The slots ranged from (width × length) 0.3 × 5 to 2.74 × 76.2 mm. Most slots were oriented longitudinally along the pipe, but some were oriented circumferentially. In addition, a limited number of multi-hole test pieces were tested in an attempt to assess the impact of a more complex breach. Much of the testing was conducted at pressures of 200 and 380 psi, but some tests were conducted at 100 psi. Testing the largest postulated breaches was deemed impractical because of the large size of some of the WTP equipment. The purpose of this report is to present the experimental results and analyses for the aerosol measurements obtained in the large-scale test stand. The report includes a description of the simulants used and their properties, equipment and operations, data analysis methodology, and test results. The results of tests investigating the role of slurry particles in plugging of small breaches are reported in Mahoney et al. 2012a. The results of the aerosol measurements in the small-scale test stand are reported in Mahoney et al. (2012b).

  5. Large-Scale Sequencing: The Future of Genomic Sciences Colloquium

    SciTech Connect (OSTI)

    Margaret Riley; Merry Buckley

    2009-01-01

    Genetic sequencing and the various molecular techniques it has enabled have revolutionized the field of microbiology. Examining and comparing the genetic sequences borne by microbes - including bacteria, archaea, viruses, and microbial eukaryotes - provides researchers insights into the processes microbes carry out, their pathogenic traits, and new ways to use microorganisms in medicine and manufacturing. Until recently, sequencing entire microbial genomes has been laborious and expensive, and the decision to sequence the genome of an organism was made on a case-by-case basis by individual researchers and funding agencies. Now, thanks to new technologies, the cost and effort of sequencing is within reach for even the smallest facilities, and the ability to sequence the genomes of a significant fraction of microbial life may be possible. The availability of numerous microbial genomes will enable unprecedented insights into microbial evolution, function, and physiology. However, the current ad hoc approach to gathering sequence data has resulted in an unbalanced and highly biased sampling of microbial diversity. A well-coordinated, large-scale effort to target the breadth and depth of microbial diversity would result in the greatest impact. The American Academy of Microbiology convened a colloquium to discuss the scientific benefits of engaging in a large-scale, taxonomically-based sequencing project. A group of individuals with expertise in microbiology, genomics, informatics, ecology, and evolution deliberated on the issues inherent in such an effort and generated a set of specific recommendations for how best to proceed. The vast majority of microbes are presently uncultured and, thus, pose significant challenges to such a taxonomically-based approach to sampling genome diversity. However, we have yet to even scratch the surface of the genomic diversity among cultured microbes. A coordinated sequencing effort of cultured organisms is an appropriate place to begin, since not only are their genomes available, but they are also accompanied by data on environment and physiology that can be used to understand the resulting data. As single cell isolation methods improve, there should be a shift toward incorporating uncultured organisms and communities into this effort. Efforts to sequence cultivated isolates should target characterized isolates from culture collections for which biochemical data are available, as well as other cultures of lasting value from personal collections. The genomes of type strains should be among the first targets for sequencing, but creative culture methods, novel cell isolation, and sorting methods would all be helpful in obtaining organisms we have not yet been able to cultivate for sequencing. The data that should be provided for strains targeted for sequencing will depend on the phylogenetic context of the organism and the amount of information available about its nearest relatives. Annotation is an important part of transforming genome sequences into useful resources, but it represents the most significant bottleneck to the field of comparative genomics right now and must be addressed. Furthermore, there is a need for more consistency in both annotation and achieving annotation data. As new annotation tools become available over time, re-annotation of genomes should be implemented, taking advantage of advancements in annotation techniques in order to capitalize on the genome sequences and increase both the societal and scientific benefit of genomics work. Given the proper resources, the knowledge and ability exist to be able to select model systems, some simple, some less so, and dissect them so that we may understand the processes and interactions at work in them. Colloquium participants suggest a five-pronged, coordinated initiative to exhaustively describe six different microbial ecosystems, designed to describe all the gene diversity, across genomes. In this effort, sequencing should be complemented by other experimental data, particularly transcriptomics and metabolomics data, all of which

  6. Solar energy storage through the homogeneous electrocatalytic reduction of carbon dioxide : photoelectrochemical and photovoltaic approaches

    E-Print Network [OSTI]

    Sathrum, Aaron John

    2011-01-01

    8 Electricity Storage in CO 2 and H 2 OS OLAR F UELS 1.5.1 Electricity Storage in CO 2 and H 2 Oand rapid storage system for solar electricity. Figure 1-6

  7. PUBLISHED ONLINE: 30 SEPTEMBER 2012 | DOI: 10.1038/NCLIMATE1694 Decade-long soil nitrogen constraint on the CO2

    E-Print Network [OSTI]

    Thomas, David D.

    constraint on the CO2 fertilization of plant biomass Peter B. Reich1,2 * and Sarah E. Hobbie3 The stimulation of plant growth by elevated CO2 concentration has been widely observed. Such fertilization, and associated carbon storage, could dampen future increases in atmospheric CO2 levels and associated climate warming1

  8. An Integrated Framework for CO2 Accounting and Risk Analysis...

    Office of Scientific and Technical Information (OSTI)

    for CO2 Accounting and Risk Analysis in CO2-EOR Sites An integrated framework for CO2 accounting and risk analysis of CO2-EOR Authors: Dai, Zhenxue 1 ; Viswanathan, Hari S....

  9. FT-IR Study of CO2 Interaction with Na-rich Montmorillonite

    SciTech Connect (OSTI)

    Krukowski, Elizabeth G [ORNL; Goodman, Angela [National Energy Technology Laboratory (NETL); Rother, Gernot [ORNL; Ilton, Eugene [Pacific Northwest National Laboratory (PNNL); Guthrie, George [National Energy Technology Laboratory (NETL); Bodnar, Robert [Virginia Polytechnic Institute and State University

    2015-01-01

    Carbon capture, utilization and storage (CCUS) in saline reservoirs in sedimentary formations has the potential to reduce the impact of fossil fuel combustion on climate change by reducing CO2 emissions to the atmosphere and storing the CO2 in geologic formations in perpetuity. At pressure and temperature (PT) conditions relevant to CCUS, CO2 is less dense than the pre-existing brine in the formation, and the more buoyant CO2 will migrate to the top of the formation where it will be in contact with cap rock. Interactions between clay-rich shale cap rocks and CO2 are poorly understood at PT conditions appropriate for CCUS in saline formations. In this study, the interaction of CO2 with clay minerals in the cap rock overlying a saline formation has been examined using Na+ exchanged montmorillonite (Mt) (Na+-STx-1) (Na+ Mt) as an analog for clay-rich shale. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) was used to discern mechanistic information for CO2 interaction with hydrated (both one- and two-water layers) and relatively dehydrated (both dehydrated layers and one-water layers) Na+-STx-1 at 35 C and 50 C and CO2 pressure from 0 5.9 MPa. CO2-induced perturbations associated with the water layer and Na+-STx-1 vibrational modes such as AlAlOH and AlMgOH were examined. Data indicate that CO2 is preferentially incorporated into the interlayer space, with relatively dehydrated Na+-STx-1 capable of incorporating more CO2 compared to hydrated Na+-STx-1. Spectroscopic data provide no evidence of formation of carbonate minerals or the interaction of CO2 with sodium cations in the Na+-STx-1 structure.

  10. SecuestrodeCO2enestructurasgeolgicas Modelacin numrica de

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    Inyección CO2 en medio carbonatado #12;SecuestrodeCO2enestructurasgeológicas Gases de efecto invernadero #12

  11. The Outlook for CO2 Capture Costs

    E-Print Network [OSTI]

    Common Measures of CCS Cost · Capital cost · Increased cost of electricity · Cost of CO2 avoided · Cost of CO2 captured E.S. Rubin, Carnegie Mellon Elements of Capital Cost Note: · Nomenclature and cost items construction Total Capital Requirement (TCR) E.S. Rubin, Carnegie Mellon Cost of Electricity (COE) COE ($/MWh

  12. Capturing CO2 via reactions in nanopores.

    SciTech Connect (OSTI)

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z; Dong, J. H.

    2008-10-01

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  13. 2, 711743, 2006 Glacial CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    CO2 change: a simple "hypsometric effect" on deep-ocean carbon sequestration? L. C. Skinner Godwin carbon sequestration, this mechanism may help to significantly reduce the "deficit" of explained glacialCPD 2, 711­743, 2006 Glacial CO2 sequestration L. C. Skinner Title Page Abstract Introduction

  14. CASSEMCHAPTER 5 HOW DOWE KNOWWHERETHE CO2

    E-Print Network [OSTI]

    where some minimum threshold volume or saturation of CO2 has been exceeded within a subsurface reservoir reservoir engineering by repeated or continuous assessment that informs on the evolving physical conditions to a large amount of injected CO2 are only viable (1) for onshore reservoirs and (2) where the target

  15. CO2 Capture with Enzyme Synthetic Analogue

    SciTech Connect (OSTI)

    Harry Cordatos

    2010-11-08

    Overview of an ongoing, 2 year research project partially funded by APRA-E to create a novel, synthetic analogue of carbonic anhydrase and incorporate it into a membrane for removal of CO2 from flue gas in coal power plants. Mechanism background, preliminary feasibility study results, molecular modeling of analogue-CO2 interaction, and program timeline are provided.

  16. 4, 23852405, 2007 CO2 and climate

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 2385­2405, 2007 CO2 and climate affect European carbon ballance R. Harrison and C. Jones Competing roles of rising CO2 and climate change in the contemporary European carbon balance R. Harrison and C. Jones Met Office, Hadley Centre for Climate Change, Exeter, EX1 3PB, UK Received: 13 April 2007

  17. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01

    and transport properties of carbon dioxide for molecularinterfacial properties of binary carbon dioxide – waterCarbon dioxide’s liquid—vapor coexistence curve and critical properties

  18. High-Surface-Area CO2 Sponge: High Performance CO2 Scrubbing Based on Hollow Fiber-Supported Designer Ionic Liquid Sponges

    SciTech Connect (OSTI)

    None

    2010-09-01

    IMPACCT Project: The team from ORNL and Georgia Tech is developing a new technology that will act like a sponge, integrating a new, alcohol-based ionic liquid into hollow fibers (magnified image, right) to capture CO2 from the exhaust produced by coal-fired power plants. Ionic liquids, or salts that exist in liquid form, are promising materials for carbon capture and storage, but their tendency to thicken when combined with CO2 limits their efficiency and poses a challenge for their development as a cost-effective alternative to current-generation solutions. Adding alcohol to the mix limits this tendency to thicken in the presence of CO2 but can also make the liquid more likely to evaporate, which would add significantly to the cost of CO2 capture. To solve this problem, ORNL is developing new classes of ionic liquids with high capacity for absorbing CO2. ORNL’s sponge would reduce the cost associated with the energy that would need to be diverted from power plants to capture CO2 and release it for storage.

  19. Study of CO2 Mobility Control in Heterogeneous Media Using CO2 Thickening Agents 

    E-Print Network [OSTI]

    Al Yousef, Zuhair

    2012-10-19

    CO2 injection is an effective method for performing enhanced oil recovery (EOR). There are several factors that make CO2 useful for EOR, including promoting swelling, reducing oil viscosity, decreasing oil density, and vaporizing and extracting...

  20. Cosmological implications of the CMB large-scale structure

    SciTech Connect (OSTI)

    Melia, Fulvio

    2015-01-01

    The Wilkinson Microwave Anisotropy Probe (WMAP) and Planck may have uncovered several anomalies in the full cosmic microwave background (CMB) sky that could indicate possible new physics driving the growth of density fluctuations in the early universe. These include an unusually low power at the largest scales and an apparent alignment of the quadrupole and octopole moments. In a ?CDM model where the CMB is described by a Gaussian Random Field, the quadrupole and octopole moments should be statistically independent. The emergence of these low probability features may simply be due to posterior selections from many such possible effects, whose occurrence would therefore not be as unlikely as one might naively infer. If this is not the case, however, and if these features are not due to effects such as foreground contamination, their combined statistical significance would be equal to the product of their individual significances. In the absence of such extraneous factors, and ignoring the biasing due to posterior selection, the missing large-angle correlations would have a probability as low as ?0.1% and the low-l multipole alignment would be unlikely at the ?4.9% level; under the least favorable conditions, their simultaneous observation in the context of the standard model could then be likely at only the ?0.005% level. In this paper, we explore the possibility that these features are indeed anomalous, and show that the corresponding probability of CMB multipole alignment in the R{sub h}=ct universe would then be ?7–10%, depending on the number of large-scale Sachs–Wolfe induced fluctuations. Since the low power at the largest spatial scales is reproduced in this cosmology without the need to invoke cosmic variance, the overall likelihood of observing both of these features in the CMB is ?7%, much more likely than in ?CDM, if the anomalies are real. The key physical ingredient responsible for this difference is the existence in the former of a maximum fluctuation size at the time of recombination, which is absent in the latter because of inflation.