National Library of Energy BETA

Sample records for large volume co2

  1. Predictions of long-term behavior of a large-volume pilot test for CO2 geological storage in a saline formation in the Central Valley, California

    SciTech Connect (OSTI)

    Doughty, Christine; Myer, Larry R.; Oldenburg, Curtis M.

    2008-11-01

    The long-term behavior of a CO{sub 2} plume injected into a deep saline formation is investigated, focusing on mechanisms that lead to plume stabilization. Key measures are plume migration distance and the time evolution of CO{sub 2} phase-partitioning, which are examined by developing a numerical model of the subsurface at a proposed power plant with CO{sub 2} capture in the San Joaquin Valley, California, where a large-volume pilot test of CO{sub 2} injection will be conducted. The numerical model simulates a four-year CO{sub 2} injection period and the subsequent evolution of the CO{sub 2} plume until it stabilizes. Sensitivity studies are carried out to investigate the effect of poorly constrained model parameters permeability, permeability anisotropy, and residual gas saturation.

  2. Physical Constraints on Geologic CO2 Sequestration in Low-Volume Basalt Formations

    SciTech Connect (OSTI)

    Ryan M. Pollyea; Jerry P. Fairley; Robert K. Podgorney; Travis L. McLing

    2014-03-01

    Deep basalt formations within large igneous provinces have been proposed as target reservoirs for carbon capture and sequestration on the basis of favorable CO2-water-rock reaction kinetics that suggest carbonate mineralization rates on the order of 102–103 d. Although these results are encouraging, there exists much uncertainty surrounding the influence of fracture-controlled reservoir heterogeneity on commercial-scale CO2 injections in basalt formations. This work investigates the physical response of a low-volume basalt reservoir to commercial-scale CO2 injections using a Monte Carlo numerical modeling experiment such that model variability is solely a function of spatially distributed reservoir heterogeneity. Fifty equally probable reservoirs are simulated using properties inferred from the deep eastern Snake River Plain aquifer in southeast Idaho, and CO2 injections are modeled within each reservoir for 20 yr at a constant mass rate of 21.6 kg s–1. Results from this work suggest that (1) formation injectivity is generally favorable, although injection pressures in excess of the fracture gradient were observed in 4% of the simulations; (2) for an extensional stress regime (as exists within the eastern Snake River Plain), shear failure is theoretically possible for optimally oriented fractures if Sh is less than or equal to 0.70SV; and (3) low-volume basalt reservoirs exhibit sufficient CO2 confinement potential over a 20 yr injection program to accommodate mineral trapping rates suggested in the literature.

  3. Modelling CO2 diffusion and assimilation in a leaf with axisymmetric finite volumes

    E-Print Network [OSTI]

    Herbin, Raphaèle

    Modelling CO2 diffusion and assimilation in a leaf with axisymmetric finite volumes Emily Gallouët. This paper deals with the numerical simulation of the diffusion and assimilation by photosynthesis of CO2 medium, from experimental measurements of the pointwise value of internal CO2 concentration, giving some

  4. GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2)

    E-Print Network [OSTI]

    Green, Donna

    GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2) from the combustion- related CO2 emissions have risen 130-fold since 1850--from 200 million tons to 27 billion tons a year--and are projected to rise another 60 percent by 2030 (see Figure 1).1 Most of the world's emissions come from

  5. EA-1886: Big Sky Regional Carbon Sequestration Partnership- Phase III: Large Volume CO2 Injection-Site Characterization, Well Drilling, and Infrastructure Development, Injection, MVA, and Site Closure, Kevin Dome, Toole County, Montana

    Broader source: Energy.gov [DOE]

    This EA will evaluate the environmental impacts of a proposal for the Big Sky Carbon Sequestration Regional Partnership to demonstrate the viability and safety of CO2 storage in a regionally significant subsurface formation in Toole County, Montana and to promote the commercialization of future anthropogenic carbon storage in this region.

  6. Feasibility of Large-Scale Ocean CO2 Sequestration

    SciTech Connect (OSTI)

    Peter Brewer

    2008-08-31

    Scientific knowledge of natural clathrate hydrates has grown enormously over the past decade, with spectacular new findings of large exposures of complex hydrates on the sea floor, the development of new tools for examining the solid phase in situ, significant progress in modeling natural hydrate systems, and the discovery of exotic hydrates associated with sea floor venting of liquid CO{sub 2}. Major unresolved questions remain about the role of hydrates in response to climate change today, and correlations between the hydrate reservoir of Earth and the stable isotopic evidence of massive hydrate dissociation in the geologic past. The examination of hydrates as a possible energy resource is proceeding apace for the subpermafrost accumulations in the Arctic, but serious questions remain about the viability of marine hydrates as an economic resource. New and energetic explorations by nations such as India and China are quickly uncovering large hydrate findings on their continental shelves. In this report we detail research carried out in the period October 1, 2007 through September 30, 2008. The primary body of work is contained in a formal publication attached as Appendix 1 to this report. In brief we have surveyed the recent literature with respect to the natural occurrence of clathrate hydrates (with a special emphasis on methane hydrates), the tools used to investigate them and their potential as a new source of natural gas for energy production.

  7. Volume 42A, number 1 6 November 1972PHYSICS LETTERS THE ROLE OF CO IN CO2 LASERS

    E-Print Network [OSTI]

    Friedland, Lazar

    Volume 42A, number 1 6 November 1972PHYSICS LETTERS THE ROLE OF CO IN CO2 LASERS P. AVIVI, F. A defined vibrational temperature exists for each of the different vibrational modes of the CO2 molecule. 2 The vibrational energy balance for the CO2 (oov) and CO (v) levels is Q,(r,) = Q,(r,) + &(T,) + Q,,(T,) (1) where

  8. 2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses

    E-Print Network [OSTI]

    Firestone, Jeremy

    2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses 4] We develop methods for assessing offshore wind 9 resources, using a model of the vertical structure. Dhanju, R. W. 26 Garvine, and M. Z. Jacobson (2007), Large CO2 reductions via 27 offshore wind power

  9. Large Releases from CO2 Storage Reservoirs: A Discussion of Natural Analogs, FEPS, and Modeling Needs

    E-Print Network [OSTI]

    Birkholzer, J.; Pruess, K.; Lewicki, J.L.; Rutqvist, J.; Tsang, C-F.; Karimjee, A.

    2008-01-01

    migration away from the primary storage reservoir, towards shallow depthsextend from depth to surface. During upward migration, CO 2

  10. Large releases from CO2 storage reservoirs: Analogs, scenarios, and modeling needs

    E-Print Network [OSTI]

    Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Rutqvist, Jonny; Tsang, Chin-Fu; Karimjee, Anhar

    2006-01-01

    migration away from the primary storage reservoir, towards shallow depthsextend from depth to surface. During upward migration, CO 2

  11. ORIGINAL PAPER Potential volume for CO2 deep ocean sequestration: an assessment

    E-Print Network [OSTI]

    Wu, Yih-Min

    . In the future, CO2 captured from the power plants can be designed and transported by a CO2 tanker shipped/seawater density D. C.-F. Shih (&) Institute of Nuclear Energy Research, AEC, P.O. Box 3-7, Longtan 32546, Taiwan to a single floating discharge platform for inje

  12. Biomass Energy for Transport and Electricity: Large scale utilization under low CO2 concentration scenarios

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.; Kim, Son H.

    2010-01-25

    This paper examines the potential role of large scale, dedicated commercial biomass energy systems under global climate policies designed to stabilize atmospheric concentrations of CO2 at 400ppm and 450ppm. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. The costs of processing and transporting biomass energy at much larger scales than current experience are also incorporated into the modeling. From the scenario results, 120-160 EJ/year of biomass energy is produced by midcentury and 200-250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the dominant source. A key finding of this paper is the role that carbon dioxide capture and storage (CCS) technologies coupled with commercial biomass energy can play in meeting stringent emissions targets. Despite the higher technology costs of CCS, the resulting negative emissions used in combination with biomass are a very important tool in controlling the cost of meeting a target, offsetting the venting of CO2 from sectors of the energy system that may be more expensive to mitigate, such as oil use in transportation. The paper also discusses the role of cellulosic ethanol and Fischer-Tropsch biomass derived transportation fuels and shows that both technologies are important contributors to liquid fuels production, with unique costs and emissions characteristics. Through application of the GCAM integrated assessment model, it becomes clear that, given CCS availability, bioenergy will be used both in electricity and transportation.

  13. Large Hybrid Energy Systems for Making Low CO2 Load-Following Power and Synthetic Fuel

    SciTech Connect (OSTI)

    Robert S. Cherry; Richard D. Boardman; Steven Aumeier

    2012-02-01

    Hybrid energy systems using nuclear heat sources can economically produce load-following electrical power by exploiting the surplus generation capacity available at night or seasonally to make synthetic fuel. Vehicle fuel is the only current energy use large enough to absorb all the energy capacity that might be diverted from the power industry, and its ease of storage obviates problems with discontinuous synfuel production. The potential benefits and challenges of synfuels integration are illustrated by the production of methanol from natural gas (as a source of carbon) using steam from a light water nuclear power reactor which is assumed to be available in accord with a year's worth of power demand data. Methanol's synthesis process is easily adapted to using 300 C heat from a light water reactor and this simple compound can be further processed into gasoline, biodiesel, or dimethyl ether, fuels which can be used with the current vehicle fleet. A supplemental feed to the methanol process of natural gas (for energy) allows operation at constant full rate when the nuclear heat is being used to produce electrical power. The higher capital costs of such a system are offset by a lower cost of heat and power production from a large base load type of plant and by reduced costs associated with much lower CO2 emissions. Other less tangible economic benefits of this and similar hybrid systems include better use of natural resource for fuels and greater energy services security from the domestic production of vehicle fuel.

  14. CASSEMCHAPTER 5 HOW DOWE KNOWWHERETHE CO2

    E-Print Network [OSTI]

    where some minimum threshold volume or saturation of CO2 has been exceeded within a subsurface reservoir reservoir engineering by repeated or continuous assessment that informs on the evolving physical conditions to a large amount of injected CO2 are only viable (1) for onshore reservoirs and (2) where the target

  15. Geomechanical effects on CO2 leakage through fault zones during large-scale underground injection

    E-Print Network [OSTI]

    Rinaldi, A.P.

    2014-01-01

    Rutqvist, J. , 2012. The Geomechanics of CO 2 Storage in2001. Fully coupled geomechanics and fluid-flow analysis ofUS Rock Mechanics, Geomechanics Symposium. San Francisco, 23

  16. Large-scale impact of CO2 storage in deep saline aquifers: A sensitivity study on pressure response in stratified systems

    E-Print Network [OSTI]

    Zhou, Quanlin

    Large-scale impact of CO2 storage in deep saline aquifers: A sensitivity study on pressure response storage potential of all the geological CO2 storage options and are widely distributed throughout the globe in all sedimentary basins.ForCO2 storage tohaveasignificantimpact on atmospheric levels

  17. Large CO2 reductions via offshore wind power matched to inherent storage in energy end-uses

    E-Print Network [OSTI]

    Large CO2 reductions via offshore wind power matched to inherent storage in energy end-uses Willett develop methods for assessing offshore wind resources, using a model of the vertical structure offshore wind power matched to inherent storage in energy end- uses, Geophys. Res. Lett., 34, L02817, doi

  18. 2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses

    E-Print Network [OSTI]

    Firestone, Jeremy

    2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses 4 by matching the winds of the 14 Middle-Atlantic Bight (MAB) to energy demand in the 15 adjacent states] We develop methods for assessing offshore wind 9 resources, using a model of the vertical structure

  19. Research project on CO2 geological storage and groundwaterresources: Large-scale hydrological evaluation and modeling of impact ongroundwater systems

    SciTech Connect (OSTI)

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan,Preston; Zhang,K.; Tsang, Chin-Fu

    2007-10-24

    If carbon dioxide capture and storage (CCS) technologies areimplemented on a large scale, the amounts of CO2 injected and sequesteredunderground could be extremely large. The stored CO2 then replaces largevolumes of native brine, which can cause considerable pressureperturbation and brine migration in the deep saline formations. Ifhydraulically communicating, either directly via updipping formations orthrough interlayer pathways such as faults or imperfect seals, theseperturbations may impact shallow groundwater or even surface waterresources used for domestic or commercial water supply. Possibleenvironmental concerns include changes in pressure and water table,changes in discharge and recharge zones, as well as changes in waterquality. In compartmentalized formations, issues related to large-scalepressure buildup and brine displacement may also cause storage capacityproblems, because significant pressure buildup can be produced. Toaddress these issues, a three-year research project was initiated inOctober 2006, the first part of which is summarized in this annualreport.

  20. The Potential for Increased Atmospheric CO2 Emissions and Accelerated Consumption of Deep Geologic CO2 Storage Resources Resulting from the Large-Scale Deployment of a CCS-Enabled Unconventional Fossil Fuels Industry in the U.S.

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-11-02

    Desires to enhance the energy security of the United States have spurred significant interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000-7000 MtCO2, in addition to storing potentially 900-5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000-5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000-22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result in an accelerated rate of utilization of the nation’s CO2 storage resource, leaving less high-quality storage capacity for other carbon-producing industries including electric power generation.

  1. On scale and magnitude of pressure build-up induced by large-scale geologic storage of CO2

    E-Print Network [OSTI]

    Zhou, Q.

    2012-01-01

    activities, such as oil production. Large-scale pressureannual volume of world oil production and the pore volumem 3 . In 2006, the world oil production was 4.3 km 3 (73.46

  2. Large interannual CO 2 and energy exchange variability in a freshwater marsh under consistent environmental conditions

    E-Print Network [OSTI]

    Rocha, Adrian V.; Goulden, Michael L.

    2008-01-01

    Net Ecosystem Production (NEP) variability was the largestthe annual sums of GEE, TER and NEP were large (Figure 5).NEP ranged from – 251 gC m À2 a À1 in 2000 to 515 gC m À2 a

  3. A quantitative comparison of the cost of employing EOR-coupled CSS supplemented with secondary DSF storage for two large CO2 point sources

    SciTech Connect (OSTI)

    Davidson, Casie L.; Dahowski, Robert T.; Dooley, James J.

    2011-04-18

    This paper explores the impact of the temporally dynamic demand for CO2 for enhanced hydrocarbon recovery with CO2 storage. Previous evaluations of economy-wide CO2 capture and geologic storage (CCS) deployment have typically applied a simplifying assumption that 100% of the potential storage capacity for a given formation is available on the first day of the analysis, and that the injection rate impacts only the number of wells required to inject a given volume of fluid per year, making it a cost driver rather than a technical one. However, as discussed by Dahowski and Bachu [1], storing CO2 in a field undergoing CO2 flooding for enhanced oil recovery (EOR) is subject to a set of constraints to which storage in DSFs is not, and these constraints combined with variable demand for CO2 may strongly influence the ability of an EOR field to serve as a baseload storage formation for commercial scale CCS projects undertaken as a means of addressing climate change mitigation targets. This analysis assumes that CCS is being undertaken in order to reduce CO2 emissions from the industrial sources evaluated and that there is enough of a disincentive associated with venting CO2 to the atmosphere that any CO2 not used within the EOR field will be stored in a suitable nearby deep saline formation (DSF). The authors have applied a CO2 demand profile to two cases chosen to illustrate the differences in cost impacts of employing EOR-based CCS as a part of a given source’s CCS portfolio. The first scenario is a less-than-ideal case in which a single EOR field is used for storage and all CO2 not demanded by the EOR project is stored in a DSF; the second scenario is designed to optimize costs by minimizing storage in the DSF and maximizing lower-cost EOR-based storage. Both scenarios are evaluated for two facilities emitting 3 and 6 MtCO2/y, corresponding to a natural gas processing facility and an IGCC electric power plant, respectively. Annual and lifetime average CO2 transport and storage costs are presented, and the impact of added capture and compression costs on overall project economics is examined.

  4. Comparing large scale CCS deployment potential in the USA and China: a detailed analysis based on country-specific CO2 transport & storage cost curves

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Davidson, Casie L.; Dooley, James J.

    2011-04-18

    The United States and China are the two largest emitters of greenhouse gases in the world and their projected continued growth and reliance on fossil fuels, especially coal, make them strong candidates for CCS. Previous work has revealed that both nations have over 1600 large electric utility and other industrial point CO2 sources as well as very large CO2 storage resources on the order of 2,000 billion metric tons (Gt) of onshore storage capacity. In each case, the vast majority of this capacity is found in deep saline formations. In both the USA and China, candidate storage reservoirs are likely to be accessible by most sources with over 80% of these large industrial CO2 sources having a CO2 storage option within just 80 km. This suggests a strong potential for CCS deployment as a meaningful option to efforts to reduce CO2 emissions from these large, vibrant economies. However, while the USA and China possess many similarities with regards to the potential value that CCS might provide, including the range of costs at which CCS may be available to most large CO2 sources in each nation, there are a number of more subtle differences that may help us to understand the ways in which CCS deployment may differ between these two countries in order for the USA and China to work together - and in step with the rest of the world - to most efficiently reduce greenhouse gas emissions. This paper details the first ever analysis of CCS deployment costs in these two countries based on methodologically comparable CO2 source and sink inventories, economic analysis, geospatial source-sink matching and cost curve modeling. This type of analysis provides a valuable insight into the degree to which early and sustained opportunities for climate change mitigation via commercial-scale CCS are available to the two countries, and could facilitate greater collaboration in areas where those opportunities overlap.

  5. Distribution of CO2 ice on the large moons of Uranus and evidence for compositional stratification of their near-surfaces

    E-Print Network [OSTI]

    Cartwright, Richard J; Rivkin, Andy S; Trilling, David E; Pinilla-Alonso, Noemi

    2015-01-01

    The surfaces of the large Uranian satellites are characterized by a mixture of H2O ice and a dark, potentially carbon-rich, constituent, along with CO2 ice. At the mean heliocentric distance of the Uranian system, native CO2 ice should be removed on timescales shorter than the age of the Solar System. Consequently, the detected CO2 ice might be actively produced. Analogous to irradiation of icy moons in the Jupiter and Saturn systems, we hypothesize that charged particles caught in Uranus' magnetic field bombard the surfaces of the Uranian satellites, driving a radiolytic CO2 production cycle. To test this hypothesis, we investigated the distribution of CO2 ice by analyzing near-infrared (NIR) spectra of these moons, gathered using the SpeX spectrograph at NASA's Infrared Telescope Facility (IRTF) (2000 - 2013). Additionally, we made spectrophotometric measurements using images gathered by the Infrared Array Camera (IRAC) onboard the Spitzer Space Telescope (2003 - 2005). We find that the detected CO2 ice is ...

  6. On scale and magnitude of pressure build-up induced by large-scale geologic storage of CO2

    E-Print Network [OSTI]

    Zhou, Q.

    2012-01-01

    and Veil, 2009) US Oil Consumption Year Figure 1. Comparisonoil production and U.S. oil consumption, as well as producedGt CO 2 ) to crude oil consumption of 1.2 km 3 (7.55 billion

  7. On scale and magnitude of pressure build-up induced by large-scale geologic storage of CO2

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J. T.

    2011-05-01

    The scale and magnitude of pressure perturbation and brine migration induced by geologic carbon sequestration is discussed assuming a full-scale deployment scenario in which enough CO{sub 2} is captured and stored to make relevant contributions to global climate change mitigation. In this scenario, the volumetric rates and cumulative volumes of CO{sub 2} injection would be comparable to or higher than those related to existing deep-subsurface injection and extraction activities, such as oil production. Large-scale pressure build-up in response to the injection may limit the dynamic storage capacity of suitable formations, because over-pressurization may fracture the caprock, may drive CO{sub 2}/brine leakage through localized pathways, and may cause induced seismicity. On the other hand, laterally extensive sedimentary basins may be less affected by such limitations because (i) local pressure effects are moderated by pressure propagation and brine displacement into regions far away from the CO{sub 2} storage domain; and (ii) diffuse and/or localized brine migration into overlying and underlying formations allows for pressure bleed-off in the vertical direction. A quick analytical estimate of the extent of pressure build-up induced by industrial-scale CO{sub 2} storage projects is presented. Also discussed are pressure perturbation and attenuation effects simulated for two representative sedimentary basins in the USA: the laterally extensive Illinois Basin and the partially compartmentalized southern San Joaquin Basin in California. These studies show that the limiting effect of pressure build-up on dynamic storage capacity is not as significant as suggested by Ehlig-Economides and Economides, who considered closed systems without any attenuation effects.

  8. Large volume flow-through scintillating detector

    DOE Patents [OSTI]

    Gritzo, Russ E. (Los Alamos, NM); Fowler, Malcolm M. (Los Alamos, NM)

    1995-01-01

    A large volume flow through radiation detector for use in large air flow situations such as incinerator stacks or building air systems comprises a plurality of flat plates made of a scintillating material arranged parallel to the air flow. Each scintillating plate has a light guide attached which transfers light generated inside the scintillating plate to an associated photomultiplier tube. The output of the photomultiplier tubes are connected to electronics which can record any radiation and provide an alarm if appropriate for the application.

  9. Why Is the Partial Molar Volume of CO2 So Small When Dissolved in a Room Temperature Ionic Liquid? Structure and

    E-Print Network [OSTI]

    Berne, Bruce J.

    , Iowa 52242 Received August 4, 2005; E-mail: berne@chem.columbia.edu Abstract: When supercritical CO2 volumetric behavior experimentally observed when supercritical CO2 is dissolved in 1-butyl-3 phase.8 Supercritical CO2 is particularly ap- pealing as an extraction solvent because it is clean

  10. Effective upliftings in Large volume compactifications

    E-Print Network [OSTI]

    Gallego, Diego

    2015-01-01

    After reviewing several mechanisms proposed to get a dS/Minkowski vacuum in moduli stabilization scenarios of type-IIB superstring orientifold compactifications we propose a criterium for characterizing those that may effectively lead to a positive small cosmological constant. We suggest that the variation in the expectation value of a good uplifting term, due to the shift in the minimum of the potential after uplifting, is much smaller than the original cosmological constant. This is studied with some detail in Large volume scenarios where the dependency on the volume direction is rather generic and easy to spot. Here we find that an uplifting term in the potential, with generic form $V_{up}\\sim 1/{\\cal V}^\\gamma$, should be restricted to the one satisfying $\\gamma\\ll 12$. Such a bound might explain why in models previously studied no uplifting has been achieved, and gives motivations to study a novel proposal of dilaton dependent uplifting mechanism for which no numerical studies has been performed before. ...

  11. Effective upliftings in Large volume compactifications

    E-Print Network [OSTI]

    Diego Gallego

    2015-08-05

    After reviewing several mechanisms proposed to get a dS/Minkowski vacuum in moduli stabilization scenarios of type-IIB superstring orientifold compactifications we propose a criterium for characterizing those that may effectively lead to a positive small cosmological constant. We suggest that the variation in the expectation value of a good uplifting term, due to the shift in the minimum of the potential after uplifting, is much smaller than the original cosmological constant. This is studied with some detail in Large volume scenarios where the dependency on the volume direction is rather generic and easy to spot. Here we find that an uplifting term in the potential, with generic form $V_{up}\\sim 1/{\\cal V}^\\gamma$, should be restricted to the one satisfying $\\gamma^2\\ll 12$. Such a bound might explain why in models previously studied no uplifting has been achieved, and gives motivations to study a novel proposal of dilaton dependent uplifting mechanism for which no numerical studies has been performed before. We find that in this case it is actually possible to get a dS vacuum, but still leave open the question of a more precise discrimination feature the good uplifting mechanisms should satisfy.

  12. Large-Scale Utilization of Biomass Energy and Carbon Dioxide Capture and Storage in the Transport and Electricity Sectors under Stringent CO2 Concentration Limit Scenarios

    SciTech Connect (OSTI)

    Luckow, Patrick; Wise, Marshall A.; Dooley, James J.; Kim, Son H.

    2010-08-05

    This paper examines the potential role of large scale, dedicated commercial biomass energy systems under global climate policies designed to meet atmospheric concentrations of CO2 at 400ppm and 450ppm by the end of the century. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. A key aspect of the research presented here is that the costs of processing and transporting biomass energy at much larger scales than current experience are explicitly incorporated into the modeling. From the scenario results, 120-160 EJ/year of biomass energy is produced globally by midcentury and 200-250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the majority source, along with growing utilization of waste-to-energy. The ability to draw on a diverse set of biomass based feedstocks helps to reduce the pressure for drastic large-scale changes in land use and the attendant environmental, ecological, and economic consequences those changes would unleash. In terms of the conversion of bioenergy feedstocks into value added energy, this paper demonstrates that biomass is and will continue to be used to generate electricity as well as liquid transportation fuels. A particular focus of this paper is to show how climate policies and technology assumptions - especially the availability of carbon dioxide capture and storage (CCS) technologies - affect the decisions made about where the biomass is used in the energy system. The potential for net-negative electric sector emissions through the use of CCS with biomass feedstocks provides an attractive part of the solution for meeting stringent emissions constraints; we find that at carbon prices above 150$/tCO2, over 90% of biomass in the energy system is used in combination with CCS. Despite the higher technology costs of CCS, it is a very important tool in controlling the cost of meeting a target, offsetting the venting of CO2 from sectors of the energy system that may be more expensive to mitigate, such as oil use in transportation. CCS is also used heavily with other fuels such as coal and natural gas, and by 2095 a total of 1530 GtCO2 has been stored in deep geologic reservoirs. The paper also discusses the role of cellulosic ethanol and Fischer-Tropsch biomass derived transportation fuels as two representative conversion processes and shows that both technologies may be important contributors to liquid fuels production, with unique costs and emissions characteristics.

  13. amine methanol, ether . Amine amine CO2

    E-Print Network [OSTI]

    Hong, Deog Ki

    IP [2012] 7 C O 2 (CO2) . CO2 amine methanol, ether . Amine amine CO2 CO2 .Amine CO2 (functional group) amine amine+ +promoter .Amine CO2 CO2 . . , methanol ether methanol, ether promoter CO2 CO2 H2S, COS CO2 . Methanol rectisol process, di-methylene ether polypropylene glycol selexol (-30oC) . CO2

  14. PVTx properties of the CO2H2O and CO2H2ONaCl systems below 647 K: Assessment of experimental data

    E-Print Network [OSTI]

    Polly, David

    PVTx properties of the CO2­H2O and CO2­H2O­NaCl systems below 647 K: Assessment of experimental-composition (PVTx) properties for the CO2­H2O and CO2­H2O­NaCl systems. This paper presents a comprehensive review. Keywords: CO2 sequestration; PVTx properties; Volume; Density; Thermodynamic modeling 1. Introduction CO2­H

  15. Large mode-volume, large beta, photonic crystal laser resonator

    SciTech Connect (OSTI)

    Dezfouli, Mohsen Kamandar; Dignam, Marc M. [Department of Physics, Engineering Physics and Astronomy, Queen’s University, Kingston, ON K7L 3N6 (Canada)

    2014-12-15

    We propose an optical resonator formed from the coupling of 13, L2 defects in a triangular-lattice photonic crystal slab. Using a tight-binding formalism, we optimized the coupled-defect cavity design to obtain a resonator with predicted single-mode operation, a mode volume five times that of an L2-cavity mode and a beta factor of 0.39. The results are confirmed using finite-difference time domain simulations. This resonator is very promising for use as a single mode photonic crystal vertical-cavity surface-emitting laser with high saturation output power compared to a laser consisting of one of the single-defect cavities.

  16. On Leakage from Geologic Storage Reservoirs of CO2

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-02-14

    Large amounts of CO2 would need to be injected underground to achieve a significant reduction of atmospheric emissions. The large areal extent expected for CO2 plumes makes it likely that caprock imperfections will be encountered, such as fault zones or fractures, which may allow some CO2 to escape from the primary storage reservoir. Leakage of CO2 could also occur along wellbores. Concerns with escape of CO2 from a primary geologic storage reservoir include (1) acidification of groundwater resources, (2) asphyxiation hazard when leaking CO2 is discharged at the land surface, (3) increase in atmospheric concentrations of CO2, and (4) damage from a high-energy, eruptive discharge (if such discharge is physically possible). In order to gain public acceptance for geologic storage as a viable technology for reducing atmospheric emissions of CO2, it is necessary to address these issues and demonstrate that CO2 can be injected and stored safely in geologic formations.

  17. Cosmological moduli problem in large volume scenario and thermal inflation

    SciTech Connect (OSTI)

    Choi, Kiwoon [Department of Physics, KAIST, Daejeon 305-701 (Korea, Republic of); Park, Wan-Il [School of Physics, KIAS, Seoul 130-722 (Korea, Republic of); Shin, Chang Sub, E-mail: kchoi@kaist.ac.kr, E-mail: wipark@kias.re.kr, E-mail: csshin@apctp.org [APCTP, Pohang, Gyeongbuk 790-784 (Korea, Republic of)

    2013-03-01

    We show that in a large volume scenario of type IIB string or F-theory compactifications, single thermal inflation provides only a partial solution to the cosmological problem of the light volume modulus. We then clarify the conditions for double thermal inflation, being a simple extension of the usual single thermal inflation scenario, to solve the cosmological moduli problem in the case of relatively light moduli masses. Using a specific example, we demonstrate that double thermal inflation can be realized in large volume scenario in a natural manner, and the problem of the light volume modulus can be solved for the whole relevant mass range. We also find that right amount of baryon asymmetry and dark matter can be obtained via a late-time Affleck-Dine mechanism and the decays of the visible sector NLSP to flatino LSP.

  18. Exploration of Melt Spinning as a Route to Large Volume Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exploration of Melt Spinning as a Route to Large Volume Production of Skutterudite Thermoelectric Materials Exploration of Melt Spinning as a Route to Large Volume Production of...

  19. he leading technology under development for management of CO2

    E-Print Network [OSTI]

    Aydilek, Ahmet

    T he leading technology under development for management of CO2 separated and captured from large assessment in relation to deploy- ment of the technology. Potential mechanisms for leakage from CO2 storage Series*sponsored by John J. Kirlin Lecture funds Geologic Sequestration of CO2 : Evaluating

  20. Leakage of CO2 from geologic storage: Role of secondary accumulation at shallow depth

    E-Print Network [OSTI]

    Pruess, K.

    2008-01-01

    Large Releases from CO2 Storage Reservoirs: Analogs,S.T. Nelson. Natural Leaking CO2-charged Systems as AnalogsY. Sano, and H.U. Schmincke. CO2-rich Gases from Lakes Nyos

  1. Rechargeable Li/CO2O2 (2 : 1) battery and Li/CO2 Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen

    E-Print Network [OSTI]

    Wang, Wei Hua

    under suitable conditions. Therefore, it is plausible that a recharge- able Li/CO2 battery couldRechargeable Li/CO2­O2 (2 : 1) battery and Li/CO2 battery Yali Liu, Rui Wang, Yingchun Lyu, Hong Li* and Liquan Chen A Li/CO2­O2 (2 : 1, volume ratio) battery and a Li/CO2 battery with discharging specific

  2. Visualization of Very Large Oceanography Time-Varying Volume Datasets

    E-Print Network [OSTI]

    Laidlaw, David

    Visualization of Very Large Oceanography Time-Varying Volume Datasets Sanghun Park1 , Chandrajit://grmanet.sogang.ac.kr/~ihm Abstract. This paper presents two visualization techniques suitable for huge oceanography time generated in the field of oceanography. The model has a resolution of 1/6 degree (2160 by 960 points

  3. AdS/CFT and Large-N Volume Independence

    SciTech Connect (OSTI)

    Poppitz, Erich; Unsal, Mithat; /SLAC /Stanford U., Phys. Dept.

    2010-08-26

    We study the Eguchi-Kawai reduction in the strong-coupling domain of gauge theories via the gravity dual of N=4 super-Yang-Mills on R{sup 3} x S{sup 1}. We show that D-branes geometrize volume independence in the center-symmetric vacuum and give supergravity predictions for the range of validity of reduced large-N models at strong coupling.

  4. Hybrid Parallelism for Volume Rendering on Large, Multi-core Systems

    E-Print Network [OSTI]

    Howison, Mark

    2010-01-01

    W. , and Childs, H. (2010) MPI-hybrid parallelism for volumeHybrid Parallelism for Volume Rendering on Large, Multi-corecharacteristics of “hybrid” parallel program- ming and

  5. Acid Gas Capture Using CO2-Binding Organic Liquids

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Rainbolt, James E.; Zheng, Feng

    2010-11-10

    Current chemical CO2 scrubbing technology is primarily aqueous alkanolamine based. These systems rapidly bind CO2 (forming water-soluble carbamate and bicarbonate salts) however, the process has serious disadvantages. The concentration of monoethanolamine rarely exceeds 30 wt % due to the corrosive nature of the solution, and this reduces the maximum CO2 volumetric (?108 g/L) and gravimetric capacity (?7 wt%) of the CO2 scrubber. The ?30 wt % loading of ethanolamine also means that a large excess of water must be pumped and heated during CO2 capture and release, and this greatly increases the energy requirements especially considering the high specific heat of water (4 j/g-1K-1). Our approach is to switch to organic systems that chemically bind CO2 as liquid alkylcarbonate salts. Our CO2-binding organic liquids have higher CO2 solubility, lower specific heats, potential for less corrosion and lower binding energies for CO2 than aqueous systems. CO2BOLs also reversibly bind and release mixed sulfur oxides. Furthermore the CO2BOL system can be direct solvent replacements for any solvent based CO2 capture systems because they are commercially available reagents and because they are fluids they would not require extensive process re-engineering.

  6. Research project on CO2 geological storage and groundwater resources: Large-scale hydrological evaluation and modeling of impact on groundwater systems

    E-Print Network [OSTI]

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan, Preston; Zhang, K.; Tsang, Chin-Fu

    2008-01-01

    storage on shallow groundwater and pressure-controlled72 5.2. Modeling of Regional Groundwater2 Geological Storage and Groundwater Resources Large-Scale

  7. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    SciTech Connect (OSTI)

    Fauth, D.J.; Filburn, T.P.; Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2 concentration resulted in incremental loss in IAS performance and revealed progressive degrees of “staining” upon testing. Adsorption of SO2 by the IAS necessitates upstream removal of SO2 prior to CO2 capture.

  8. CO2 interaction with geomaterials.

    SciTech Connect (OSTI)

    Guthrie, George D. (U.S. Department of Energy, Pittsburgh, PA); Al-Saidi, Wissam A. (University of Pittsburgh, Pittsburgh, PA); Jordan, Kenneth D. (University of Pittsburgh, Pittsburgh, PA); Voora, Vamsee, K. (University of Pittsburgh, Pittsburgh, PA); Romanov, Vyacheslav N. (U.S. Department of Energy, Pittsburgh, PA); Lopano, Christina L (U.S. Department of Energy, Pittsburgh, PA); Myshakin, Eugene M. (URS Corporation, Pittsburgh, PA); Hur, Tae Bong (University of Pittsburgh, Pittsburgh, PA); Warzinski, Robert P. (U.S. Department of Energy, Pittsburgh, PA); Lynn, Ronald J. (URS Corporation, Pittsburgh, PA); Howard, Bret H. (U.S. Department of Energy, Pittsburgh, PA); Cygan, Randall Timothy

    2010-09-01

    This work compares the sorption and swelling processes associated with CO2-coal and CO2-clay interactions. We investigated the mechanisms of interaction related to CO2 adsortion in micropores, intercalation into sub-micropores, dissolution in solid matrix, the role of water, and the associated changes in reservoir permeability, for applications in CO2 sequestration and enhanced coal bed methane recovery. The structural changes caused by CO2 have been investigated. A high-pressure micro-dilatometer was equipped to investigate the effect of CO2 pressure on the thermoplastic properties of coal. Using an identical dilatometer, Rashid Khan (1985) performed experiments with CO2 that revealed a dramatic reduction in the softening temperature of coal when exposed to high-pressure CO2. A set of experiments was designed for -20+45-mesh samples of Argonne Premium Pocahontas No.3 coal, which is similar in proximate and ultimate analysis to the Lower Kittanning seam coal that Khan used in his experiments. No dramatic decrease in coal softening temperature has been observed in high-pressure CO2 that would corroborate the prior work of Khan. Thus, conventional polymer (or 'geopolymer') theories may not be directly applicable to CO2 interaction with coals. Clays are similar to coals in that they represent abundant geomaterials with well-developed microporous structure. We evaluated the CO2 sequestration potential of clays relative to coals and investigated the factors that affect the sorption capacity, rates, and permanence of CO2 trapping. For the geomaterials comparison studies, we used source clay samples from The Clay Minerals Society. Preliminary results showed that expandable clays have CO2 sorption capacities comparable to those of coal. We analyzed sorption isotherms, XRD, DRIFTS (infrared reflectance spectra at non-ambient conditions), and TGA-MS (thermal gravimetric analysis) data to compare the effects of various factors on CO2 trapping. In montmorillonite, CO2 molecules may remain trapped for several months following several hours of exposure to high pressure (supercritical conditions), high temperature (above boiling point of water) or both. Such trapping is well preserved in either inert gas or the ambient environment and appears to eventually result in carbonate formation. We performed computer simulations of CO2 interaction with free cations (normal modes of CO2 and Na+CO2 were calculated using B3LYP / aug-cc-pVDZ and MP2 / aug-cc-pVDZ methods) and with clay structures containing interlayer cations (MD simulations with Clayff potentials for clay and a modified CO2 potential). Additionally, interaction of CO2 with hydrated Na-montmorillonite was studied using density functional theory with dispersion corrections. The sorption energies and the swelling behavior were investigated. Preliminary modeling results and experimental observations indicate that the presence of water molecules in the interlayer region is necessary for intercalation of CO2. Our preliminary conclusion is that CO2 molecules may intercalate into interlayer region of swelling clay and stay there via coordination to the interlayer cations.

  9. Efficient parallel simulation of CO2 geologic sequestration in saline aquifers

    E-Print Network [OSTI]

    Zhang, Keni; Doughty, Christine; Wu, Yu-Shu; Pruess, Karsten

    2007-01-01

    +6s, no salt, 3D CO2 Mass Fraction Z (m) Y(m) Figure 6. CO 2s), salt=12.5%, 3D CO2 mass fraction Z (m) X (m) Figure 7.25% with Large K, 3D CO2 mass fraction Z (m) Y (m) Figure 9.

  10. Investigation of CO2 plume behavior for a large-scale pilot test of geologic carbon storage in a saline formation

    SciTech Connect (OSTI)

    Doughty, C.

    2009-04-01

    The hydrodynamic behavior of carbon dioxide (CO{sub 2}) injected into a deep saline formation is investigated, focusing on trapping mechanisms that lead to CO{sub 2} plume stabilization. A numerical model of the subsurface at a proposed power plant with CO{sub 2} capture is developed to simulate a planned pilot test, in which 1,000,000 metric tons of CO{sub 2} is injected over a four-year period, and the subsequent evolution of the CO{sub 2} plume for hundreds of years. Key measures are plume migration distance and the time evolution of the partitioning of CO{sub 2} between dissolved, immobile free-phase, and mobile free-phase forms. Model results indicate that the injected CO{sub 2} plume is effectively immobilized at 25 years. At that time, 38% of the CO{sub 2} is in dissolved form, 59% is immobile free phase, and 3% is mobile free phase. The plume footprint is roughly elliptical, and extends much farther up-dip of the injection well than down-dip. The pressure increase extends far beyond the plume footprint, but the pressure response decreases rapidly with distance from the injection well, and decays rapidly in time once injection ceases. Sensitivity studies that were carried out to investigate the effect of poorly constrained model parameters permeability, permeability anisotropy, and residual CO{sub 2} saturation indicate that small changes in properties can have a large impact on plume evolution, causing significant trade-offs between different trapping mechanisms.

  11. Monitoring CO 2 sequestration into deep saline aquifer and associated salt intrusion using coupled multiphase flow modeling and time lapse electrical resistivity tomography

    SciTech Connect (OSTI)

    Chuan Lu; CHI Zhang; Hai Hanag; Timothy C. Johnson

    2014-04-01

    Successful geological storage and sequestration of carbon dioxide (CO2) require efficient monitoring of the migration of CO2 plume during and after large-scale injection in order to verify the containment of the injected CO2 within the target formation and to evaluate potential leakage risk. Field studies have shown that surface and cross-borehole electrical resistivity tomography (ERT) can be a useful tool in imaging and characterizing solute transport in heterogeneous subsurface. In this synthetic study, we have coupled a 3-D multiphase flow model with a parallel 3-D time-lapse ERT inversion code to explore the feasibility of using time-lapse ERT for simultaneously monitoring the migration of CO2 plume in deep saline formation and potential brine intrusion into shallow fresh water aquifer. Direct comparisons of the inverted CO2 plumes resulting from ERT with multiphase flow simulation results indicate the ERT could be used to delineate the migration of CO2 plume. Detailed comparisons on the locations, sizes and shapes of CO2 plume and intruded brine plumes suggest that ERT inversion tends to underestimate the area review of the CO2 plume, but overestimate the thickness and total volume of the CO2 plume. The total volume of intruded brine plumes is overestimated as well. However, all discrepancies remain within reasonable ranges. Our study suggests that time-lapse ERT is a useful monitoring tool in characterizing the movement of injected CO2 into deep saline aquifer and detecting potential brine intrusion under large-scale field injection conditions.

  12. Uncertainty quantification for CO2 sequestration and enhanced oil recovery

    E-Print Network [OSTI]

    Dai, Zhenxue; Fessenden-Rahn, Julianna; Middleton, Richard; Pan, Feng; Jia, Wei; Lee, Si-Yong; McPherson, Brian; Ampomah, William; Grigg, Reid

    2014-01-01

    This study develops a statistical method to perform uncertainty quantification for understanding CO2 storage potential within an enhanced oil recovery (EOR) environment at the Farnsworth Unit of the Anadarko Basin in northern Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil-water flow and reactive transport in the Morrow formation are conducted for global sensitivity and statistical analysis of the major uncertainty metrics: net CO2 injection, cumulative oil production, cumulative gas (CH4) production, and net water injection. A global sensitivity and response surface analysis indicates that reservoir permeability, porosity, and thickness are the major intrinsic reservoir parameters that control net CO2 injection/storage and oil/gas recovery rates. The well spacing and the initial water saturation also have large impact on the oil/gas recovery rates. Further, this study has revealed key insights into the potential behavior and the operational parameters of CO2 sequestration at CO2-EOR s...

  13. Vehicular Sensing System for CO2 Monitoring Applications

    E-Print Network [OSTI]

    Tseng, Yu-Chee

    --We are interested in monitoring the concentration of carbon dioxide (CO2) gas in a large field such as an urban area sensor, vehicular sensing system, wireless sensor network. I. INTRODUCTION Carbon dioxide (CO2) gas has concentration in Hsin-Chu city, Taiwan. The collected data is reported to a remote server, which is integrated

  14. An Investigation of CO2 Sequestration

    E-Print Network [OSTI]

    Saldin, Dilano

    An Investigation of CO2 Sequestration through Mineralization Conference on Sustainable Construction area and increased availability of CO2 for rapid carbonation. The hardened and carbonated materials Slag #12;Carbonation Chemistry Dissolution of CO2 in water. CO2(g) CO2(aq) Formation of carbonic acid

  15. Northern California CO2 Reduction Project

    SciTech Connect (OSTI)

    Hymes, Edward

    2010-06-16

    C6 Resources LLC, a wholly owned subsidiary of Shell Oil Company, worked with the US Department of Energy (DOE) under a Cooperative Agreement to develop the Northern California CO2 Reduction Project. The objective of the Project is to demonstrate the viability of using Carbon Capture and Sequestration (CCS) to reduce existing greenhouse gas emissions from industrial sources on a large-scale. The Project will capture more than 700,000 metric tonnes of CO2 per year, which is currently being vented to the atmosphere from the Shell Martinez Refinery in Contra Costa County. The CO2 will be compressed and dehydrated at the refinery and then transported via pipeline to a sequestration site in a rural area in neighboring Solano County. The CO2 will be sequestered into a deep saline formation (more than two miles underground) and will be monitored to assure secure, long-term containment. The pipeline will be designed to carry as much as 1,400,000 metric tonnes of CO2 per year, so additional capacity will be available to accommodate CO2 captured from other industrial sources. The Project is expected to begin operation in 2015. The Project has two distinct phases. The overall objective of Phase 1 was to develop a fully definitive design basis for the Project. The Cooperative Agreement with the DOE provided cost sharing for Phase 1 and the opportunity to apply for additional DOE cost sharing for Phase 2, comprising the design, construction and operation of the Project. Phase 1 has been completed. DOE co-funding is provided by the American Recovery and Reinvestment Act (ARRA) of 2009. As prescribed by ARRA, the Project will stimulate the local economy by creating manufacturing, transportation, construction, operations, and management jobs while addressing the need to reduce greenhouse gas emissions at an accelerated pace. The Project, which will also assist in meeting the CO2 reduction requirements set forth in California?s Climate Change law, presents a major opportunity for both the environment as well as the region. C6 Resources is conducting the Project in collaboration with federally-funded research centers, such as Lawrence Berkeley National Lab and Lawrence Livermore National Lab. C6 Resources and Shell have identified CCS as one of the critical pathways toward a worldwide goal of providing cleaner energy. C6 Resources, in conjunction with the West Coast Regional Carbon Sequestration Partnership (WESTCARB), has conducted an extensive and ongoing public outreach and CCS education program for local, regional and state-wide stakeholders. As part of a long term relationship, C6 Resources will continue to engage directly with community leaders and residents to ensure public input and transparency. This topical report summarizes the technical work from Phase 1 of the Project in the following areas: ? Surface Facility Preliminary Engineering: summarizes the preliminary engineering work performed for CO2 capture, CO2 compression and dehydration at the refinery, and surface facilities at the sequestration site ? Pipeline Preliminary Engineering: summarizes the pipeline routing study and preliminary engineering design ? Geologic Sequestration: summarizes the work to characterize, model and evaluate the sequestration site ? Monitoring, Verification and Accounting (MVA): summarizes the MVA plan to assure long-term containment of the sequestered CO2

  16. Surface CO2 leakage during the first shallow subsurface CO2 release experiment

    E-Print Network [OSTI]

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2008-01-01

    numbered 0-6. Plots of F CO2 measured along the surface wellin Figure 2. Figure 2. Log F CO2 maps for measurements madeof soil CO 2 flux (F CO2 ). The surface leakage onset,

  17. Climatedependent CO2 emissions from lakes Sarian Kosten,1

    E-Print Network [OSTI]

    Cole, Jonathan J.

    in carbon dioxide partial pressure (pCO2) in 83 shallow lakes over a large climatic gradient in South influence lakes' metabolism as well. For instance through its effect on the hydraulic residence time, which

  18. Commitment accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, SJ; Socolow, RH

    2014-01-01

    us My IOPscience Commitment accounting of CO2 emissions This9326/9/8/084018 Commitment accounting of CO 2 emissionsthe potential for ‘commitment accounting’ to inform public

  19. Hybrid Parallelism for Volume Rendering on Large, Multi-core Systems

    E-Print Network [OSTI]

    Howison, Mark

    2010-01-01

    Hybrid Parallelism for Volume Rendering on Large, Multi-corendings indicate that the hybrid-parallel implementation, atpassing against a “hybrid” parallel im- plementation, which

  20. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01

    E EPM2- TIP4P2005 PPL- TIP4P2005 Predicted (f) a P ? CO2 2SE? CO2 2SE? CO2 2SE ? CO2 2SE ? CO2 2SE ? CO2 2SE a Surface excess CO

  1. Crystallography and Physical Properties of BaCo2As2, Ba0.94K0.06Co2As2, and Ba0.78K0.22Co2As2

    SciTech Connect (OSTI)

    Anand, V K; Quirinale, Dante G; Lee, Yongbin; Harmon, Bruce N; Furukawa, Yuji; Ogloblichev, V V; Huq, A; Abernathy, D L; Stephens, P W; McQueeney, Robert J; Kreyssig, Aandreas; Goldman, Alan I; Johnston, David C

    2014-08-01

    The crystallographic and physical properties of polycrystalline and single crystal samples of BaCo2As2 and K-doped Ba{1-x}K{x}Co2As2 (x = 0.06, 0.22) are investigated by x-ray and neutron powder diffraction, magnetic susceptibility chi, magnetization, heat capacity Cp, {75}As NMR and electrical resistivity rho measurements versus temperature T. The crystals were grown using both Sn flux and CoAs self-flux, where the Sn-grown crystals contain 1.6-2.0 mol% Sn. All samples crystallize in the tetragonal ThCr2Si2-type structure (space group I4/mmm). For BaCo2As2, powder neutron diffraction data show that the c-axis lattice parameter exhibits anomalous negative thermal expansion from 10 to 300 K, whereas the a-axis lattice parameter and the unit cell volume show normal positive thermal expansion over this T range. No transitions in BaCo2As2 were found in this T range from any of the measurements. Below 40-50 K, we find rho ~ T^2 indicating a Fermi liquid ground state. A large density of states at the Fermi energy D(EF) ~ 18 states/(eV f.u.) for both spin directions is found from low-T Cp(T) measurements, whereas the band structure calculations give D(EF) = 8.23 states/(eV f.u.). The {75}As NMR shift data versus T have the same T dependence as the chi(T) data, demonstrating that the derived chi(T) data are intrinsic. The observed {75}As nuclear spin dynamics are consistent with the presence of ferromagnetic and/or stripe-type antiferromagnetic spin fluctuations. The crystals of Ba{0.78}K{0.22}Co2As2 were grown in Sn flux and show properties very similar to those of undoped BaCo2As2. On the other hand, the crystals from two batches of Ba{0.94}K{0.06}Co2As2 grown in CoAs self-flux show evidence of weak ferromagnetism at T < 10 K with small ordered moments at 1.8 K of 0.007 and 0.03 muB per formula unit, respectively.

  2. Does elevated CO2 alter silica uptake in trees?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fulweiler, Robinson W.; Maguire, Timothy J.; Carey, Joanna C.; Finzi, Adrien C.

    2015-01-13

    Human activities have greatly altered global carbon (C) and Nitrogen (N) cycling. In fact, atmospheric concentrations of carbon dioxide (CO2) have increased 40% over the last century and the amount of N cycling in the biosphere has more than doubled. In an effort to understand how plants will respond to continued global CO2 fertilization, longterm free-air CO2 enrichment experiments have been conducted at sites around the globe. Here we examine how atmospheric CO2 enrichment and N fertilization affects the uptake of silicon (Si) in the Duke Forest, North Carolina, a stand dominated by Pinus taeda (loblolly pine), and five hardwoodmore »species. Specifically, we measured foliar biogenic silica concentrations in five deciduous and one coniferous species across three treatments: CO2 enrichment, N enrichment, and N and CO2 enrichment. We found no consistent trends in foliar Si concentration under elevated CO2, N fertilization, or combined elevated CO2 and N fertilization. However, two-thirds of the tree species studied here have Si foliar concentrations greater than well-known Si accumulators, such as grasses. Based on net primary production values and aboveground Si concentrations in these trees, we calculated forest Si uptake rates under control and elevated CO2 concentrations. Due largely to increased primary production, elevated CO2 enhanced the magnitude of Si uptake between 20 and 26%, likely intensifying the terrestrial silica pump. This uptake of Si by forests has important implications for Si export from terrestrial systems, with the potential to impact C sequestration and higher trophic levels in downstream ecosystems.« less

  3. Short communication Satellite-derived surface water pCO2 and airsea CO2 fluxes

    E-Print Network [OSTI]

    Short communication Satellite-derived surface water pCO2 and air­sea CO2 fluxes in the northern for the estimation of the partial pressure of carbon dioxide (pCO2) and air­sea CO2 fluxes in the northern South), respectively, the monthly pCO2 fields were computed. The derived pCO2 was compared with the shipboard pCO2

  4. CO2 leakage impacts on shallow groundwater. Field-scale reactive-transport simulations informed by observations at a natural analog site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Keating, Elizabeth H.; Hakala, J. Alexandra; Viswanathan, Hari; Carey, J. William; Pawar, Rajesh; Guthrie, George D.; Fessenden-Rahn, Julianna

    2013-03-01

    It is challenging to predict the degree to which shallow groundwater might be affected by leaks from a CO2 sequestration reservoir, particularly over long time scales and large spatial scales. In this study observations at a CO2 enriched shallow aquifer natural analog were used to develop a predictive model which is then used to simulate leakage scenarios. This natural analog provides the opportunity to make direct field observations of groundwater chemistry in the presence of elevated CO2, to collect aquifer samples and expose them to CO2 under controlled conditions in the laboratory, and to test the ability of multiphase reactivemore »transport models to reproduce measured geochemical trends at the field-scale. The field observations suggest that brackish water entrained with the upwelling CO2 are a more significant source of trace metals than in situ mobilization of metals due to exposure to CO2. The study focuses on a single trace metal of concern at this site: U. Experimental results indicate that cation exchange/adsorption and dissolution/precipitation of calcite containing trace amounts of U are important reactions controlling U in groundwater at this site, and that the amount of U associated with calcite is fairly well constrained. Simulations incorporating these results into a 3-D multi-phase reactive transport model are able to reproduce the measured ranges and trends between pH, pCO2, Ca, total C, U and Cl-at the field site. Although the true fluxes at the natural analog site are unknown, the cumulative CO2 flux inferred from these simulations are approximately equivalent to 37.8E-3 MT, approximately corresponding to a .001% leak rate for injection at a large (750 MW) power plant. The leakage scenario simulations suggest that if the leak only persists for a short time the volume of aquifer contaminated by CO2-induced mobilization of U will be relatively small, yet persistent over 100 a.« less

  5. The effect of CO2 on the plasma remediation of NxOy Ann C. Gentilea)

    E-Print Network [OSTI]

    Kushner, Mark

    The effect of CO2 on the plasma remediation of NxOy Ann C. Gentilea) and Mark J. Kushnerb repetitively pulsed dielectric barrier discharges. As combustion effluents contain large percentages of CO2, in this paper we discuss the consequences of CO2 in the gas mixture on the efficiency of remediation

  6. Modern soil system constraints on reconstructing deep-time atmospheric CO2

    E-Print Network [OSTI]

    Montañez, Isabel Patricia

    Modern soil system constraints on reconstructing deep-time atmospheric CO2 Isabel P. Montan October 2012 Abstract Paleosol carbonate-based estimates of paleo-atmospheric CO2 play a prominent role in constraining radiative-forcing and climate sensitivity in the deep-time. Large uncertainty in paleo-CO2

  7. Dynamic micro-mapping of CO2 sorption in coal

    SciTech Connect (OSTI)

    Radlinski, Andrzej Pawell [ORNL; Melnichenko, Yuri B [ORNL; Cheng, Gang [ORNL; Mastalerz, Maria [Indiana Geological Survey

    2009-01-01

    We have applied X-ray and neutron small-angle scattering techniques (SAXS, SANS and USANS) to study the interaction between fluids and porous media in the particular case of sub- and super-critical CO2 sorption in coal. These techniques are demonstrated to give unique, pore-size-specific insights into the kinetics of CO2 sorption in a wide range of coal pores (nano to meso), and to provide data that may be used to determine the density of the sorbed CO2. We observed densification of the adsorbed CO2 by a factor up to five compared to the free fluid at the same (p,T) conditions. Our results indicate that details of CO2 sorption into coal pores differ greatly between different coals and depend on the amount of mineral matter dispersed in the coal matrix: a purely organic matrix absorbs more CO2 per unit volume than one contaminated with mineral matter, but mineral matter markedly accelerates the sorption kinetics.

  8. MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE

    E-Print Network [OSTI]

    Foss, Bjarne A.

    MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE Lars Imsland Dagfinn Snarheim and control of a semi-closed O2/CO2 gas turbine cycle for CO2 capture. In the first part the process predictive control, Gas turbines, CO2 capture 1. INTRODUCTION Gas turbines are widely used for power

  9. Fluid flow and CO2fluidmineral interactions during CO2-storage in sedimentary basins

    E-Print Network [OSTI]

    Cambridge, University of

    mineral dissolution rates. Observations from CO2-EOR exper- iments and natural analogues suggestFluid flow and CO2­fluid­mineral interactions during CO2-storage in sedimentary basins Niko Kampman Natural CO2 analogues Modelling the progress of geochemical processes in CO2 storage sites is frustrated

  10. Performance of large electron energy filter in large volume plasma device

    SciTech Connect (OSTI)

    Singh, S. K.; Srivastava, P. K.; Awasthi, L. M.; Mattoo, S. K.; Sanyasi, A. K.; Kaw, P. K. [Institute for Plasma Research, Gandhinagar 382 428, Gujarat (India)] [Institute for Plasma Research, Gandhinagar 382 428, Gujarat (India); Singh, R. [Institute for Plasma Research, Gandhinagar 382 428, Gujarat (India) [Institute for Plasma Research, Gandhinagar 382 428, Gujarat (India); WCI Center for Fusion Theory, National Fusion Research Institute Gwahangno 113, Yu-seong-gu, Daejeon, 305-333 (Korea, Republic of)

    2014-03-15

    This paper describes an in-house designed large Electron Energy Filter (EEF) utilized in the Large Volume Plasma Device (LVPD) [S. K. Mattoo, V. P. Anita, L. M. Awasthi, and G. Ravi, Rev. Sci. Instrum. 72, 3864 (2001)] to secure objectives of (a) removing the presence of remnant primary ionizing energetic electrons and the non-thermal electrons, (b) introducing a radial gradient in plasma electron temperature without greatly affecting the radial profile of plasma density, and (c) providing a control on the scale length of gradient in electron temperature. A set of 19 independent coils of EEF make a variable aspect ratio, rectangular solenoid producing a magnetic field (B{sub x}) of 100?G along its axis and transverse to the ambient axial field (B{sub z} ? 6.2?G) of LVPD, when all its coils are used. Outside the EEF, magnetic field reduces rapidly to 1?G at a distance of 20 cm from the center of the solenoid on either side of target and source plasma. The EEF divides LVPD plasma into three distinct regions of source, EEF and target plasma. We report that the target plasma (n{sub e} ? 2 × 10{sup 11}?cm{sup ?3} and T{sub e} ? 2?eV) has no detectable energetic electrons and the radial gradients in its electron temperature can be established with scale length between 50?and?600 cm by controlling EEF magnetic field. Our observations reveal that the role of the EEF magnetic field is manifested by the energy dependence of transverse electron transport and enhanced transport caused by the plasma turbulence in the EEF plasma.

  11. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extractionmore »control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing ‘Area of Review’, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.« less

  12. Improvements of Calcium Oxide Based Sorbents for multiple CO2 Capture Laetitia Vieille*, Alexandre Govin, Philippe Grosseau

    E-Print Network [OSTI]

    Boyer, Edmond

    ;particle. At the same time, CaO sintering may occur during high-temperature calcination. The decline of CO2Improvements of Calcium Oxide Based Sorbents for multiple CO2 Capture cycles Laetitia Vieille for CO2. Compared to others, a higher BET surface area and a larger pore volume were observed

  13. Implications of "peak oil" for atmospheric CO2 and climate

    E-Print Network [OSTI]

    Kharecha, P A

    2007-01-01

    Peaking of global oil production may have a large effect on future atmospheric CO2 amount and climate change, depending upon choices made for subsequent energy sources. We suggest that, if estimates of oil and gas reserves by the Energy Information Administration are realistic, it is feasible to keep atmospheric CO2 from exceeding approximately 450 ppm, provided that future exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration, must be phased out before mid-century to achieve this limit on atmospheric CO2. We also suggest that it is important to "stretch" oil reserves via energy efficiency, thus avoiding the need to extract liquid fuels from coal or unconventional fossil fuels. We argue that a rising price on carbon emissions is probably needed to keep CO2 beneath the 450 ppm ceiling.

  14. co2-transport | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transport Cost Model FENETL CO2 Transport Cost Model About the model: This model was developed to estimate the cost of transporting a user-specified mass rate of CO2 by pipeline...

  15. Engineered yeast for enhanced CO2 mineralization

    E-Print Network [OSTI]

    Barbero, Roberto Juan

    2013-01-01

    In this work, a biologically catalysed CO2 mineralization process for the capture of CO2 from point sources was designed, constructed at a laboratory scale, and, using standard chemical process scale-up protocols, was ...

  16. Large-volume Rhyolite Genesis in Caldera Complexes of the Snake River Plain: Insights

    E-Print Network [OSTI]

    Bindeman, Ilya N.

    Large-volume Rhyolite Genesis in Caldera Complexes of the Snake River Plain: Insights from-volume rhyolites in the shallow crust is an im- portant, yet enigmatic, process in the Snake River Plain and world; rhyolite; Snake River Plain, zircon *Corresponding author. E-mail: kwatts@uoregon.edu y E-mail: address

  17. Testing volume independence of large N gauge theories on the lattice

    E-Print Network [OSTI]

    Antonio Gonzalez-Arroyo; Masanori Okawa

    2014-11-12

    For a pure SU(N) gauge theory on the lattice we test if the expectation values of small Wilson loops become volume independent in the large N limit.

  18. CO2 Cycle du Fiche dtaille

    E-Print Network [OSTI]

    Dintrans, Boris

    CO2 ­ Cycle du Carbone Polluants Fiche détaillée Niveau (A partir de la 2nd) #12;I. Introduction Les origines du CO2 atmosphérique dépendent de l'échelle de temps que l'on considère. A l, ce cycle commence avec la dissolution du CO2 dans l'eau de pluie pour former de l'acide carbonique

  19. Regional Opportunities for Carbon Dioxide Capture and Storage in China: A Comprehensive CO2 Storage Cost Curve and Analysis of the Potential for Large Scale Carbon Dioxide Capture and Storage in the People’s Republic of China

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Li, Xiaochun; Davidson, Casie L.; Wei, Ning; Dooley, James J.

    2009-12-01

    This study presents data and analysis on the potential for carbon dioxide capture and storage (CCS) technologies to deploy within China, including a survey of the CO2 source fleet and potential geologic storage capacity. The results presented here indicate that there is significant potential for CCS technologies to deploy in China at a level sufficient to deliver deep, sustained and cost-effective emissions reductions for China over the course of this century.

  20. Optimal Process Design for Coupled CO2 Sequestration and Enhanced Gas Recovery in Carbonate Reservoirs 

    E-Print Network [OSTI]

    Odi, Uchenna

    2013-12-09

    ........................................................................................................ 26 Figure 11: PVT System for Dew Point Measurement (a) Oven (b) Computer Data Gathering Equipment (c) Top Pump B (d) PVT Visual Cell (e) Bottom Pump A... adequate understanding of condensate blockage and its interaction with CO2. Accomplishing this requires a fundamental understanding of the pressure, volume, and temperature (PVT) interactions between gas condensate and CO2. Discerning these PVT...

  1. Upper ocean control on the solubility pump of CO2 by Takamitsu Ito1

    E-Print Network [OSTI]

    Follows, Mick

    and the degree of saturation of the waters. The depth of thermocline sets the relative volume of warm and cold waters, which sets the mean solubility of CO2 in the ocean. The degree of saturation depends lead to changes in atmospheric pCO2 of as much as 30 ppmv. The deep ocean carbon reservoir

  2. The unstable CO2 feedback cycle on ocean planets

    E-Print Network [OSTI]

    Kitzmann, D; Godolt, M; Grenfell, J L; Heng, K; Patzer, A B C; Rauer, H; Stracke, B; von Paris, P

    2015-01-01

    Ocean planets are volatile rich planets, not present in our Solar System, which are thought to be dominated by deep, global oceans. This results in the formation of high-pressure water ice, separating the planetary crust from the liquid ocean and, thus, also from the atmosphere. Therefore, instead of a carbonate-silicate cycle like on the Earth, the atmospheric carbon dioxide concentration is governed by the capability of the ocean to dissolve carbon dioxide (CO2). In our study, we focus on the CO2 cycle between the atmosphere and the ocean which determines the atmospheric CO2 content. The atmospheric amount of CO2 is a fundamental quantity for assessing the potential habitability of the planet's surface because of its strong greenhouse effect, which determines the planetary surface temperature to a large degree. In contrast to the stabilising carbonate-silicate cycle regulating the long-term CO2 inventory of the Earth atmosphere, we find that the CO2 cycle feedback on ocean planets is negative and has strong...

  3. Summary Trees exposed to elevated CO2 partial pressure ([CO2]) generally show increased rates of photosynthesis and

    E-Print Network [OSTI]

    ), nighttime respiration, number of mitochondria. Introduction Terrestrial plant photosynthesis and respiration the atmosphere and terrestrial biosphere are large, because photosynthesis assimilates about 120 Pg C year­1- nistically explained in large part by the direct effect of ele- vated [CO2] on Rubisco kinetics (Farquhar

  4. Reversible Acid Gas Capture Using CO2-Binding Organic Liquids

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Yonker, Clement R.; Rainbolt, James E.; Zheng, Feng

    2010-08-31

    Acid gas scrubbing technology is predominantly aqueous alkanolamine based. Of the acid gases, CO2, H2S and SO2 have been shown to be reversible, however there are serious disadvantages with corrosion and high regeneration costs. The primary scrubbing system composed of monoethanolamine is limited to 30% by weight because of the highly corrosive solution. This gravimetric limitation limits the CO2 volumetric (?108 g/L) and gravimetric capacity (?7 wt%) of the system. Furthermore the scrubbing system has a large energy penalty from pumping and heating the excess water required to dissolve the MEA bicarbonate salt. Considering the high specific heat of water (4 j/g-1K-1), low capacities and the high corrosion we set out to design a fully organic solvent that can chemically bind all acid gases i.e. CO2 as reversible alkylcarbonate ionic liquids or analogues thereof. Having a liquid acid gas carrier improves process economics because there is no need for excess solvent to pump and to heat. We have demonstrated illustrated in Figure 1, that CO2-binding organic liquids (CO2BOLs) have a high CO2 solubility paired with a much lower specific heat (<1.5 J/g-1K-1) than aqueous systems. CO2BOLs are a subsection of a larger class of materials known as Binding Organic Liquids (BOLs). Our BOLs have been shown to reversibly bind and release COS, CS2, and SO2, which we denote COSBOLS, CS2BOLs and SO2BOLs. Our BOLs are highly tunable and can be designed for post or pre-combustion gas capture. The design and testing of the next generation zwitterionic CO2BOLs and SO2BOLs are presented.

  5. Using CO2 spatial variability to quantify representation errors of satellite CO2 retrievals

    E-Print Network [OSTI]

    Michalak, Anna M.

    global data of column- averaged CO2 dry-air mole fraction (XCO2) at high spatial resolutions. These dataUsing CO2 spatial variability to quantify representation errors of satellite CO2 retrievals A. A 2008; published 29 August 2008. [1] Satellite measurements of column-averaged CO2 dry- air mole

  6. Gibbs and Helmholtz energies of formation of sI clathrate hydrates from CO$_2$, CH$_4$ and water

    E-Print Network [OSTI]

    K. S. Glavatskiy; T. J. H. Vlugt; S. Kjelstrup

    2013-07-26

    We determine thermodynamic stability conditions in terms of Helmholtz and Gibbs energies for sI clathrate hydrates with CH$_4$ and CO$_2$ at 278 K. Helmholtz energies are relevant for processing from porous rocks (constant volume), while Gibbs energies are relevant for processing from layers on the ocean floor (constant pressure). We define three steps leading to hydrate formation, and find Helmholtz energy differences from molecular simulations for two of them using grand-canonical Monte Carlo simulations at constant temperature and volume; while the third step was calculated from literature data. The Gibbs energy change for the same steps are also determined. From the variations in the total Helmholtz and Gibbs energies we suggest thermodynamic paths for exchange of CH$_4$ by CO$_2$ in the isothermal hydrate, for constant volume or pressure, respectively. We show how these paths for the mixed hydrate can be understood from single-component occupancy isotherms, where CO$_2$, but not CH$_4$, can distinguish between large and small cages. The strong preference for CH$_4$ for a range of compositions can be explained by these.

  7. Comparative Assessment of Status and Opportunities for CO2 Capture and Storage and Radioactive Waste Disposal in North America

    E-Print Network [OSTI]

    Oldenburg, C.

    2010-01-01

    power generation. Large coal-fired power plants will requiresequestration of CO 2 from coal- fired power plants. Asideon sequestration of CO 2 from coal-fired power plants (the

  8. Comments on Economides and Ehlig-Economides,"Sequestering carbon dioxide in a closed underground volume," SPE 124430, October 2009

    SciTech Connect (OSTI)

    Oldenburg, Curt; Pruess, Karsten; Birkholzer, Jens; Doughty, Christine

    2009-10-22

    The paper examines the pressure increase resulting from injection of CO2 into a 1D radial system with closed boundaries. The finding is that unacceptably high pressures are obtained when only 1% or less of the pore volume is occupied by injected CO2. These results are used to make the general conclusion that large-scale CCS is not feasible.

  9. CO2 Storage and Enhanced Oil Recovery: Bald Unit Test Site, Mumford Hills Oil Field, Posey County, Indiana

    SciTech Connect (OSTI)

    Frailey, Scott M.; Krapac, Ivan G.; Damico, James R.; Okwen, Roland T.; McKaskle, Ray W.

    2012-03-30

    The Midwest Geological Sequestration Consortium (MGSC) carried out a small-scale carbon dioxide (CO2) injection test in a sandstone within the Clore Formation (Mississippian System, Chesterian Series) in order to gauge the large-scale CO2 storage that might be realized from enhanced oil recovery (EOR) of mature Illinois Basin oil fields via miscible liquid CO2 flooding. As part of the MGSC�������¢����������������s Validation Phase (Phase II) studies, the small injection pilot test was conducted at the Bald Unit site within the Mumford Hills Field in Posey County, southwestern Indiana, which was chosen for the project on the basis of site infrastructure and reservoir conditions. Geologic data on the target formation were extensive. Core analyses, porosity and permeability data, and geophysical logs from 40 wells were used to construct cross sections and structure contour and isopach maps in order to characterize and define the reservoir architecture of the target formation. A geocellular model of the reservoir was constructed to improve understanding of CO2 behavior in the subsurface. At the time of site selection, the Field was under secondary recovery through edge-water injection, but the wells selected for the pilot in the Bald Unit had been temporarily shut-in for several years. The most recently shut-in production well, which was surrounded by four nearby shut-in production wells in a five-spot pattern, was converted to CO2 injection for this pilot. Two additional wells outside the immediate five-spot pattern, one of which was an active producer, were instrumented to measure surface temperature and pressure. The CO2 injection period lasted from September 3, 2009, through December 14, 2010, with one three-month interruption caused by cessation of CO2 deliveries due to winter weather. Water was injected into the CO2 injection well during this period. A total of 6,300 tonnes (6,950 tons) of CO2 were injected into the reservoir at rates that generally ranged from 18 to 32 tonnes (20 to 35 tons) per day. The CO2 injection bottomhole pressure generally remained at 8.3 to 9.0 MPag (1,200 to 1,300 psig). The CO2 injection was followed by continued monitoring for nine months during post-CO2 water injection. A monitoring, verification, and accounting (MVA) program was designed to determine the fate of injected CO2. Extensive periodic sampling and analysis of brine, groundwater, and produced gases began before CO2 injection and continued through the monitored waterflood periods. Samples were gathered from production wells and three newly installed groundwater monitoring wells. Samples underwent geochemical and isotopic analyses to reveal any CO2-related changes. Groundwater and kinetic modeling and mineralogical analysis were also employed to better understand the long-term dynamics of CO2 in the reservoir. No CO2 leakage into groundwater was detected, and analysis of brine and gas chemistry made it possible to track the path of plume migration and infer geochemical reactions and trapping of CO2. Cased-hole logging did not detect any CO2 in the near-wellbore region. An increase in CO2 concentration was first detected in February 2010 from the gas present in the carboy during brine sampling; however, there was no appreciable gas volume associated with the detection of CO2. The first indication of elevated gas rates from the commingled gas of the pilot�������¢����������������s production wells occurred in July 2010 and reached a maximum of 0.36 tonnes/day (0.41 tons/day) in September 2010. An estimated 27 tonnes (30 tons) of CO2 were produced at the surface from the gas separator at the tank battery from September 3, 2009, through September 11, 2011, representing 0.5% of the injected CO2. Consequently, 99.5%

  10. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01

    emissions from traded fossil fuels; Top), production (F Pr )Regional, and National Fossil-Fuel CO 2 Emissions (Carbonfrom the burning of fossil fuels are conventionally

  11. CO2 Heat Pump Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO 2 Heat Pump Water Heater 2014 Building Technologies Office Peer Review Evaporator Kyle Gluesenkamp, gluesenkampk@ornl.gov Oak Ridge National Laboratory Project Summary Timeline:...

  12. CO2 Conference Presentation | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    CO2 Conference Presentation More Documents & Publications POWER-GEN Conference Presentation U.S. Energy Association Presentation EEI Environment Meetings Presentation...

  13. Regional Ecosystem-Atmosphere CO2 Exchange Via Atmospheric Budgets

    SciTech Connect (OSTI)

    Davis, K.J.; Richardson, S.J.; Miles, N.L.

    2007-03-07

    Inversions of atmospheric CO2 mixing ratio measurements to determine CO2 sources and sinks are typically limited to coarse spatial and temporal resolution. This limits our ability to evaluate efforts to upscale chamber- and stand-level CO2 flux measurements to regional scales, where coherent climate and ecosystem mechanisms govern the carbon cycle. As a step towards the goal of implementing atmospheric budget or inversion methodology on a regional scale, a network of five relatively inexpensive CO2 mixing ratio measurement systems was deployed on towers in northern Wisconsin. Four systems were distributed on a circle of roughly 150-km radius, surrounding one centrally located system at the WLEF tower near Park Falls, WI. All measurements were taken at a height of 76 m AGL. The systems used single-cell infrared CO2 analyzers (Licor, model LI-820) rather than the siginificantly more costly two-cell models, and were calibrated every two hours using four samples known to within ± 0.2 ppm CO2. Tests prior to deployment in which the systems sampled the same air indicate the precision of the systems to be better than ± 0.3 ppm and the accuracy, based on the difference between the daily mean of one system and a co-located NOAA-ESRL system, is consistently better than ± 0.3 ppm. We demonstrate the utility of the network in two ways. We interpret regional CO2 differences using a Lagrangian parcel approach. The difference in the CO2 mixing ratios across the network is at least 2?3 ppm, which is large compared to the accuracy and precision of the systems. Fluxes estimated assuming Lagrangian parcel transport are of the same sign and magnitude as eddy-covariance flux measurements at the centrally-located WLEF tower. These results indicate that the network will be useful in a full inversion model. Second, we present a case study involving a frontal passage through the region. The progression of a front across the network is evident; changes as large as four ppm in one minute are captured. Influence functions, derived using a Lagrangian Particle Dispersion model driven by the CSU Regional Atmospheric Modeling System and nudged to NCEP reanalysis meteorological fields, are used to determine source regions for the towers. The influence functions are combined with satellite vegetation observations to interpret the observed trends in CO2 concentration. Full inversions will combine these elements in a more formal analytic framework.

  14. CO2watermineral reactions during CO2 leakage: Geochemical and isotopic monitoring of a CO2 injection field test

    E-Print Network [OSTI]

    to be addressed during the selection and characterization of suitable CO2 storage sites (IEA-GHG, 2011; Lemieux., 2007; IEA-GHG, 2011). Considering a sce- nario where CO2 ­ or brine or both ­ escapes from the storage., 2010; Kharaka et al., 2010; Humez et al., 2011a, 2011b; IEA-GHG, 2011; Lemieux, 2011; Keating et al

  15. Production of large resonant plasma volumes in microwave electron cyclotron resonance ion sources

    DOE Patents [OSTI]

    Alton, G.D.

    1998-11-24

    Microwave injection methods are disclosed for enhancing the performance of existing electron cyclotron resonance (ECR) ion sources. The methods are based on the use of high-power diverse frequency microwaves, including variable-frequency, multiple-discrete-frequency, and broadband microwaves. The methods effect large resonant ``volume`` ECR regions in the ion sources. The creation of these large ECR plasma volumes permits coupling of more microwave power into the plasma, resulting in the heating of a much larger electron population to higher energies, the effect of which is to produce higher charge state distributions and much higher intensities within a particular charge state than possible in present ECR ion sources. 5 figs.

  16. Production of large resonant plasma volumes in microwave electron cyclotron resonance ion sources

    DOE Patents [OSTI]

    Alton, Gerald D. (Kingston, TN)

    1998-01-01

    Microwave injection methods for enhancing the performance of existing electron cyclotron resonance (ECR) ion sources. The methods are based on the use of high-power diverse frequency microwaves, including variable-frequency, multiple-discrete-frequency, and broadband microwaves. The methods effect large resonant "volume" ECR regions in the ion sources. The creation of these large ECR plasma volumes permits coupling of more microwave power into the plasma, resulting in the heating of a much larger electron population to higher energies, the effect of which is to produce higher charge state distributions and much higher intensities within a particular charge state than possible in present ECR ion sources.

  17. An Integrated Framework for CO2 Accounting and Risk Analysis...

    Office of Scientific and Technical Information (OSTI)

    for CO2 Accounting and Risk Analysis in CO2-EOR Sites An integrated framework for CO2 accounting and risk analysis of CO2-EOR Authors: Dai, Zhenxue 1 ; Viswanathan, Hari S....

  18. SecuestrodeCO2enestructurasgeolgicas Modelacin numrica de

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    Inyección CO2 en medio carbonatado #12;SecuestrodeCO2enestructurasgeológicas Gases de efecto invernadero #12

  19. Legal Implications of CO2 Ocean Storage

    E-Print Network [OSTI]

    Legal Implications of CO2 Ocean Storage Jason Heinrich Working Paper Laboratory for Energy the deployment of CO2 storage technologies used in the marine environment. This paper will address some of the legal issues involved in ocean storage of carbon dioxide from a US perspective. The following paragraphs

  20. The Outlook for CO2 Capture Costs

    E-Print Network [OSTI]

    Common Measures of CCS Cost · Capital cost · Increased cost of electricity · Cost of CO2 avoided · Cost of CO2 captured E.S. Rubin, Carnegie Mellon Elements of Capital Cost Note: · Nomenclature and cost items construction Total Capital Requirement (TCR) E.S. Rubin, Carnegie Mellon Cost of Electricity (COE) COE ($/MWh

  1. Capturing CO2 via reactions in nanopores.

    SciTech Connect (OSTI)

    Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z; Dong, J. H.

    2008-10-01

    This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

  2. 2, 711743, 2006 Glacial CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    CO2 change: a simple "hypsometric effect" on deep-ocean carbon sequestration? L. C. Skinner Godwin carbon sequestration, this mechanism may help to significantly reduce the "deficit" of explained glacialCPD 2, 711­743, 2006 Glacial CO2 sequestration L. C. Skinner Title Page Abstract Introduction

  3. CO2 Capture with Enzyme Synthetic Analogue

    SciTech Connect (OSTI)

    Harry Cordatos

    2010-11-08

    Overview of an ongoing, 2 year research project partially funded by APRA-E to create a novel, synthetic analogue of carbonic anhydrase and incorporate it into a membrane for removal of CO2 from flue gas in coal power plants. Mechanism background, preliminary feasibility study results, molecular modeling of analogue-CO2 interaction, and program timeline are provided.

  4. 4, 23852405, 2007 CO2 and climate

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 2385­2405, 2007 CO2 and climate affect European carbon ballance R. Harrison and C. Jones Competing roles of rising CO2 and climate change in the contemporary European carbon balance R. Harrison and C. Jones Met Office, Hadley Centre for Climate Change, Exeter, EX1 3PB, UK Received: 13 April 2007

  5. Study of CO2 Mobility Control in Heterogeneous Media Using CO2 Thickening Agents 

    E-Print Network [OSTI]

    Al Yousef, Zuhair

    2012-10-19

    CO2 injection is an effective method for performing enhanced oil recovery (EOR). There are several factors that make CO2 useful for EOR, including promoting swelling, reducing oil viscosity, decreasing oil density, and vaporizing and extracting...

  6. Dynamics of CO2 fluxes and concentrations during a shallow subsurface CO2 release

    SciTech Connect (OSTI)

    Lewicki, J.L.; Hilley, G.E.; Dobeck, L.; Spangler, L.

    2009-09-01

    A field facility located in Bozeman, Montana provides the opportunity to test methods to detect, locate, and quantify potential CO2 leakage from geologic storage sites. From 9 July to 7 August 2008, 0.3 t CO2 d{sup -1} were injected from a 100-m long, {approx}2.5 m deep horizontal well. Repeated measurements of soil CO2 fluxes on a grid characterized the spatio-temporal evolution of the surface leakage signal and quantified the surface leakage rate. Infrared CO2 concentration sensors installed in the soil at 30 cm depth at 0 to 10 m from the well and at 4 cm above the ground at 0 and 5 m from the well recorded surface breakthrough of CO2 leakage and migration of CO2 leakage through the soil. Temporal variations in CO2 concentrations were correlated with atmospheric and soil temperature, wind speed, atmospheric pressure, rainfall, and CO2 injection rate.

  7. Rapid estimate of solid volume in large tuff cores using a gas pycnometer

    SciTech Connect (OSTI)

    Thies, C.; Geddis, A.M.; Guzman, A.G.

    1996-09-01

    A thermally insulated, rigid-volume gas pycnometer system has been developed. The pycnometer chambers have been machined from solid PVC cylinders. Two chambers confine dry high-purity helium at different pressures. A thick-walled design ensures minimal heat exchange with the surrounding environment and a constant volume system, while expansion takes place between the chambers. The internal energy of the gas is assumed constant over the expansion. The ideal gas law is used to estimate the volume of solid material sealed in one of the chambers. Temperature is monitored continuously and incorporated into the calculation of solid volume. Temperature variation between measurements is less than 0.1{degrees}C. The data are used to compute grain density for oven-dried Apache Leap tuff core samples. The measured volume of solid and the sample bulk volume are used to estimate porosity and bulk density. Intrinsic permeability was estimated from the porosity and measured pore surface area and is compared to in-situ measurements by the air permeability method. The gas pycnometer accommodates large core samples (0.25 m length x 0.11 m diameter) and can measure solid volume greater than 2.20 cm{sup 3} with less than 1% error.

  8. Mechanically Cooled Large-Volume Germanium Detector Systems for Nuclear Explosion Monitoring DOENA27323-1

    SciTech Connect (OSTI)

    Hull, E.L.

    2006-07-28

    Compact maintenance free mechanical cooling systems are being developed to operate large volume germanium detectors for field applications. To accomplish this we are utilizing a newly available generation of Stirling-cycle mechanical coolers to operate the very largest volume germanium detectors with no maintenance. The user will be able to leave these systems unplugged on the shelf until needed. The flip of a switch will bring a system to life in ~ 1 hour for measurements. The maintenance-free operating lifetime of these detector systems will exceed 5 years. These features are necessary for remote long-duration liquid-nitrogen free deployment of large-volume germanium gamma-ray detector systems for Nuclear Explosion Monitoring. The Radionuclide Aerosol Sampler/Analyzer (RASA) will greatly benefit from the availability of such detectors by eliminating the need for liquid nitrogen at RASA sites while still allowing the very largest available germanium detectors to be reliably utilized.

  9. meters in CO2 euthanasia chambers. All CO2 euthanasia chambers in both

    E-Print Network [OSTI]

    George, Edward I.

    meters in CO2 euthanasia chambers. All CO2 euthanasia chambers in both the facilities, and durable flow meter to install in all of the CO2 chambers in all of the vivaria. When a specific model and laboratories will need flow meters. ULAR is currently in the process of identifying a cost-effective, accurate

  10. Sustainable Carbon Sequestration: Increasing CO2-Storage Efficiency through a CO2-Brine Displacement Approach 

    E-Print Network [OSTI]

    Akinnikawe, Oyewande

    2012-10-19

    CO2 sequestration is one of the proposed methods for reducing anthropogenic CO2 emissions to the atmosphere and therefore mitigating global climate change. Few studies on storing CO2 in an aquifer have been conducted on a regional scale. This study...

  11. Probing the Earth's interior with a large-volume liquid scintillator detector

    E-Print Network [OSTI]

    Kathrin A. Hochmuth; Franz v. Feilitzsch; Brian D. Fields; Teresa Marrodan Undagoitia; Lothar Oberauer; Walter Potzel; Georg G. Raffelt; Michael Wurm

    2006-10-04

    A future large-volume liquid scintillator detector would provide a high-statistics measurement of terrestrial antineutrinos originating from $\\beta$-decays of the uranium and thorium chains. In addition, the forward displacement of the neutron in the detection reaction $\\bar\

  12. A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes

    E-Print Network [OSTI]

    Cai, Long

    A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes Nian Liu1 lithium-ion batteries and in more recent Li­O2 and Li­S batteries as a replacement for the dendrite to the level of commercial lithium-ion batteries (3.7 mAh cm22 ). Particle fracture and loss of electrical

  13. Natural and industrial analogues for release of CO2 from storage reservoirs: Identification of features, events, and processes and lessons learned

    E-Print Network [OSTI]

    Lewicki, Jennifer L.; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    COMPOSITION OF FLUE GAS STREAMS AND CO 2 SEPARATION 43 3.3. NATURALcompositions by volume of flue (and fuel) gases from selected coal, fuel oil, natural

  14. How much CO2 is too much? Nobody knows for sure, but sophisticated

    E-Print Network [OSTI]

    Haszeldine, Stuart

    the next 30 to 60 years than by capturing and storing CO2. Carbon capture and storage (CCS) is no panacea. Carbon capture and storage(CCS)offersoneofthemostdirectandrapidwaysofreducing CO2 emissions right now fuels provides most of the world's electrical energy. It also produces large amounts of carbon dioxide

  15. Mesoscale circulations and atmospheric CO2 variations in the Tapajos Region, Para, Brazil

    E-Print Network [OSTI]

    Collett Jr., Jeffrey L.

    Mesoscale circulations and atmospheric CO2 variations in the Tapajo´s Region, Para´, Brazil Lixin; published 2 November 2005. [1] We have investigated mesoscale circulations and atmospheric CO2 variations over a heterogeneous landscape of forests, pastures, and large rivers during the Santare´m Mesoscale

  16. Implications of ``peak oil'' for atmospheric CO2 and climate Pushker A. Kharecha1

    E-Print Network [OSTI]

    Implications of ``peak oil'' for atmospheric CO2 and climate Pushker A. Kharecha1 and James E environments. If conventional oil production peaks within the next few decades, it may have a large effect., and J. E. Hansen (2008), Implications of ``peak oil'' for atmospheric CO2 and climate, Global Biogeochem

  17. Risk Assessment and Monitoring of Stored CO2 in Organic Rocks Under Non-Equilibrium Conditions

    SciTech Connect (OSTI)

    Malhotra, Vivak

    2014-06-30

    The USA is embarking upon tackling the serious environmental challenges posed to the world by greenhouse gases, especially carbon dioxide (CO2). The dimension of the problem is daunting. In fact, according to the Energy Information Agency, nearly 6 billion metric tons of CO2 were produced in the USA in 2007 with coal-burning power plants contributing about 2 billion metric tons. To mitigate the concerns associated with CO2 emission, geological sequestration holds promise. Among the potential geological storage sites, unmineable coal seams and shale formations in particular show promise because of the probability of methane recovery while sequestering the CO2. However. the success of large-scale sequestration of CO2 in coal and shale would hinge on a thorough understanding of CO2's interactions with host reservoirs. An important parameter for successful storage of CO2 reservoirs would be whether the pressurized CO2 would remain invariant in coal and shale formations under reasonable internal and/or external perturbations. Recent research has brought to the fore the potential of induced seismicity, which may result in caprock compromise. Therefore, to evaluate the potential risks involved in sequestering CO2 in Illinois bituminous coal seams and shale, we studied: (i) the mechanical behavior of Murphysboro (Illinois) and Houchin Creek (Illinois) coals, (ii) thermodynamic behavior of Illinois bituminous coal at - 100oC ? T ? 300oC, (iii) how high pressure CO2 (up to 20.7 MPa) modifies the viscosity of the host, (iv) the rate of emission of CO2 from Illinois bituminous coal and shale cores if the cores, which were pressurized with high pressure (? 20.7 MPa) CO2, were exposed to an atmospheric pressure, simulating the development of leakage pathways, (v) whether there are any fractions of CO2 stored in these hosts which are resistance to emission by simply exposing the cores to atmospheric pressure, and (vi) how compressive shockwaves applied to the coal and shale cores, which were pressurized with high pressure CO2, determine the fate of sequestered CO2 in these cores. Our results suggested that Illinois bituminous coal in its unperturbed state, i.e., when not pressurized with CO2, showed large variations in the mechanical properties. Modulus varied from 0.7 GPa to 3.4 GPa even though samples were extracted from a single large chunk of coal. We did not observe any glass transition for Illinois bituminous coal at - 100oC ? T ? 300oC, however, when the coal was pressurized with CO2 at ambient ? P ? 20.7 MPa, the viscosity of the coal decreased and inversely scaled with the CO2 pressure. The decrease in viscosity as a function of pressure could pose CO2 injection problems for coal as lower viscosity would allow the solid coal to flow to plug the fractures, fissures, and cleats. Our experiments also showed a very small fraction of CO2 was absorbed in coal; and when CO2 pressurized coals were exposed to atmospheric conditions, the loss of CO2 from coals was massive. Half of the sequestered gas from the coal cores was lost in less than 20 minutes. Our shockwave experiments on Illinois bituminous coal, New Albany shale (Illinois), Devonian shale (Ohio), and Utica shale (Ohio) presented clear evidence that the significant emission of the sequestered CO2 from these formations cannot be discounted during seismic activity, especially if caprock is compromised. It is argued that additional shockwave studies, both compressive and transverse, would be required for successfully mapping the risks associated with sequestering high pressure CO2 in coal and shale formations.

  18. Heterogenised Molecular Catalysts for CO2 Conversion

    E-Print Network [OSTI]

    Windle, Christopher D.; Reisner, Erwin

    2015-08-01

    perspective, these systems do not utilise solar light directly but could be powered by photovoltaics. 2) No electrode is required in photocatalysis and the energy for the reaction is obtained through light absorption. Electrons are typically supplied by a... cluster.[3a] 2. Photocatalytic CO2 reduction Photocatalytic CO2 reduction cuts out the electrolytic middleman in solar fuels synthesis. Instead of relying on a photovoltaic panel for providing the electricity to drive electrolysis, photocatalysis...

  19. Version 3.0 SOP 4 --p(CO2) October 12, 2007 (p(CO2))

    E-Print Network [OSTI]

    Version 3.0 SOP 4 -- p(CO2) October 12, 2007 91 SOP 4 (p(CO2)) - 1. . microatmospheres . (20°C 250-2000 µatm) (mole fraction) . 2. CO2 (mole fraction) . 2 2(CO ) (CO( ) . . Frit . #12;October 12, 2007 SOP 4 -- p(CO2) Version 3.0 92 CO2 CO2 2 . p(CO2) (1) . 4. 3

  20. Insights into the structure of mixed CO2/CH4 in gas hydrates

    SciTech Connect (OSTI)

    Everett, Susan M; Rawn, Claudia J; Chakoumakos, Bryan C; Keffer, David J.; Huq, Ashfia; Phelps, Tommy Joe

    2015-01-01

    The exchange of CO2 for CH4 in natural gas hydrates is an attractive approach to methane for energy production while simultaneously sequestering CO2. In addition to the energy and environmental implications, the solid solution of clathrate hydrate (CH4)1-x(CO2)x 5.75H2O provides a model system to study how the distinct bonding and shapes of CH4 and CO2 influence the structure and properties of the compound. High-resolution neutron diffraction was used to examine mixed CO2/CH4 gas hydrates. CO2-rich hydrates had smaller lattice parameters, which were attributed to the higher affinity of the CO2 molecule interacting with H2O molecules that form the surrounding cages, and resulted in a reduction in the unit cell volume. Experimental nuclear scattering densities illustrate how the cage occupants and energy landscape change with composition. These results provide important insights on the impact and mechanisms for exchanging CH4 and CO2.

  1. Measurement of atmospheric neutrino oscillations with very large volume neutrino telescopes

    E-Print Network [OSTI]

    J. P. Yañez; A. Kouchner

    2015-09-28

    Neutrino oscillations have been probed during the last few decades using multiple neutrino sources and experimental set-ups. In the recent years, very large volume neutrino telescopes have started contributing to the field. First ANTARES and then IceCube have relied on large and sparsely instrumented volumes to observe atmospheric neutrinos for combinations of baselines and energies inaccessible to other experiments. Using this advantage, the latest result from IceCube starts approaching the precision of other established technologies, and is paving the way for future detectors, such as ORCA and PINGU. These new projects seek to provide better measurements of neutrino oscillation parameters, and eventually determine the neutrino mass ordering. The results from running experiments and the potential from proposed projects are discussed in this review, emphasizing the experimental challenges involved in the measurements.

  2. Measurement of atmospheric neutrino oscillations with very large volume neutrino telescopes

    E-Print Network [OSTI]

    Yañez, J P

    2015-01-01

    Neutrino oscillations have been probed during the last few decades using multiple neutrino sources and experimental set-ups. In the recent years, very large volume neutrino telescopes have started contributing to the field. First ANTARES and then IceCube have relied on large and sparsely instrumented volumes to observe atmospheric neutrinos for combinations of baselines and energies inaccessible to other experiments. Using this advantage, the latest result from IceCube starts approaching the precision of other established technologies, and is paving the way for future detectors, such as ORCA and PINGU. These new projects seek to provide better measurements of neutrino oscillation parameters, and eventually determine the neutrino mass ordering. The results from running experiments and the potential from proposed projects are discussed in this review, emphasizing the experimental challenges involved in the measurements.

  3. CO2 Sorption to Subsingle Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction Measurements

    SciTech Connect (OSTI)

    Rother, Gernot; Ilton, Eugene S.; Wallacher, Dirk; Hauss, Thomas; Schaef, Herbert T.; Qafoku, Odeta; Rosso, Kevin M.; Felmy, Andrew R.; Krukowski, Elizabeth; Stack, Andrew G.; Grimm, Nico; Bodnar, Robert J.

    2013-01-15

    Geologic storage of CO2 requires that the caprock sealing the storage rock is highly impermeable by CO2. Swelling clays, which are important components of caprocks, may interact with CO2 under volume change, potentially impacting the seal quality. The interactions of scCO2 with Na saturated montmorillonite clay containing a sub-single layer of water in the interlayer region have been studied by sorption and neutron diffraction techniques. The excess sorption isotherms show maxima at bulk CO2 densities of ??0.15 g/cm3, followed by an approximately linear decrease of excess sorption to zero and negative values with increasing CO2 bulk density. Neutron diffraction experiments on the same clay sample measured interlayer spacing and composition. The results show that limited amounts of CO2 are sorbed into the interlayer region, leading to depression of the interlayer peak intensity and an increase of the d(001) spacing by ca. 0.5 Å. The density of CO2 in the clay pores is relatively stable over a wide range of CO2 pressures at a given temperature, indicating the formation of a clay-CO2 phase. At the excess sorption maximum, increasing CO2 sorption with decreasing temperature is observed while the high-pressure sorption properties exhibit weak temperature dependence.

  4. CO2 Adsorption to Sub-Single Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction

    SciTech Connect (OSTI)

    Rother, Gernot [ORNL; Ilton, Eugene [Pacific Northwest National Laboratory (PNNL); Wallacher, Dirk [Helmholtz-Zentrum Berlin; Hauss, Thomas [Helmholtz-Zentrum Berlin; Schaef, Herbert [Pacific Northwest National Laboratory (PNNL); Qafoku, Odeta [Pacific Northwest National Laboratory (PNNL); Rosso, Kevin M. [Pacific Northwest National Laboratory (PNNL); Felmy, Andrew [Pacific Northwest National Laboratory (PNNL); Krukowski, Elizabeth G [ORNL; Stack, Andrew G [ORNL; Bodnar, Robert J [ORNL

    2013-01-01

    Geologic storage of CO2 requires that the caprock sealing the storage rock is highly impermeable by CO2. Swelling clays, which are important components of caprocks, may react with CO2 under volume change, potentially impacting the seal quality. The interactions of scCO2 with Na saturated montmorillonite clay containing a sub-single layer of water in the interlayer region have been studied by sorption and neutron diffraction techniques. The excess sorption isotherms show maxima at bulk CO2 densities of 0.15 g/cm3, followed by an approximately linear decrease of excess sorption to zero and negative values with increasing CO2 bulk density. Neutron diffraction experiments on the same clay sample measured interlayer spacing and composition. The results show that limited amounts of CO2 are sorbed into the interlayer region, leading to depression of the interlayer peak intensity and an increase of the d(001) spacing by ca. 0.5 . The density of CO2 in the clay pores is relatively stable over a wide range of CO2 pressures at a given temperature, indicating the formation of a clay-CO2 phase. At low pressure increasing CO2 adsorption with decreasing temperature is observed while the high-pressure sorption properties exhibit weak or no temperature dependence. Supercritical fluids, sorption phenomena, carbon dioxide, carbon sequestration, caprock integrity

  5. Prospects of the search for neutrino bursts from Supernovae with Baksan Large Volume Scintillation Detector

    E-Print Network [OSTI]

    Petkov, V B

    2015-01-01

    Observing a high-statistics neutrino signal from the supernova explosions in the Galaxy is a major goal of low-energy neutrino astronomy. The prospects for detecting all flavors of neutrinos and antineutrinos from the core-collapse supernova (ccSN) in operating and forthcoming large liquid scintillation detectors (LLSD) are widely discussed now. One of proposed LLSD is Baksan Large Volume Scintillation Detector (BLVSD). This detector will be installed at the Baksan Neutrino Observatory (BNO) of the Institute for Nuclear Research, Russian Academy of Sciences, at a depth of 4800 m.w.e. Low-energy neutrino astronomy is one of the main lines of research of the BLVSD.

  6. Growth, CO2 Consumption, and H2 Production of Anabaena variabilis ATCC 29413-U under Different Irradiances and CO2 Concentrations

    E-Print Network [OSTI]

    Berberoglu, Halil; Barra, Natasha; Pilon, Laurent; Jay, Jenny

    2008-01-01

    Phase Medium Irradiance ? H2 ? CO2 Maximum Reported Ratesa) Specific CO 2 uptake rate, ? CO2 (kg CO 2 /kg dry cell/h)

  7. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    WITH SITE SCREENING AND SELECTION FOR CO 2 STORAGE D. A.77 ASSESSING AND EXPANDING CO 2 STORAGE CAPACITY IN DEPLETEDFOR CO 2 GEOLOGICAL STORAGE IN CENTRAL COAL BASIN (NORTHERN

  8. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    20-22, 2006 End of CO2 injection Fraction Variation 5E-05 -point. End of CO2 injection Fraction Variation Figure 3.poin Y (m (m X End of CO2 storage Fraction Variation Y (m (m

  9. Uncertainty analyses of CO2 plume expansion subsequent to wellbore...

    Office of Scientific and Technical Information (OSTI)

    The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we...

  10. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    of the buoyancy of supercritical CO2 in the presence ofindividual pock- ets of supercritical CO2 to form, therebydomain. Injection of supercritical CO2 occurs at a depth of

  11. Feasibility of CO2 Capture from Mobile Sources | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 Capture from Mobile Sources Feasibility of CO2 Capture from Mobile Sources Presents integrated system for post-combustion CO2 capture from mobile sources p-16davis.pdf More...

  12. System-level modeling for geological storage of CO2

    E-Print Network [OSTI]

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01

    of Geologic Storage of CO2, in Carbon Dioxide Capture forFormations - Results from the CO2 Capture Project: GeologicBenson, Process Modeling of CO2 Injection into Natural Gas

  13. The Influence of a CO2 Pricing Scheme on Distributed Energy Resources in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    impact of mid-sized building CHP systems on CO 2 emissions.of medium-sized commercial building CHP-enabled DG in GHGbased CHP systems is wrong and large office buildings,

  14. Interpretation of observed atmospheric variations of CO2 and CH4. 

    E-Print Network [OSTI]

    Barlow, James Mathew

    2015-06-30

    The overarching theme of my thesis is understanding observed variations of northern hemisphere atmospheric carbon dioxide (CO2) and methane (CH4) concentrations. I focus my analysis on high-latitude observations of these gases, as there are large...

  15. Variations in 13 C discrimination during CO2 exchange by

    E-Print Network [OSTI]

    as to differential diffusivities of 13 CO2 and 12 CO2 in air (Farquhar, O'Leary & Berry 1982; O'Leary 1984

  16. Carbon Storage Partner Completes First Year of CO2 Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Storage Partner Completes First Year of CO2 Injection Operations in Illinois Carbon Storage Partner Completes First Year of CO2 Injection Operations in Illinois November 19,...

  17. Electron Transfer Dynamics in Photocatalytic CO2 Conversion ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Transfer Dynamics in Photocatalytic CO2 Conversion Electron Transfer Dynamics in Photocatalytic CO2 Conversion Coal is the workhorse of our power industry, responsible for...

  18. Quantum Alloys Offer Prospects for CO2 Management Technologies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantum Alloys Offer Prospects for CO2 Mgt. Technologies Utilizing and Storing Carbon Dioxide Emissions Quantum Alloys Offer Unique Prospects for CO2 Management Technologies...

  19. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantum Chemistry of CO2 Interaction with Swelling Clays Quantum Chemistry of CO2 Interaction with Swelling Clays Ubiquitous clay minerals can play an important role in assessing...

  20. Meeting the CO2 Challenge DEER 2002 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the CO2 Challenge DEER 2002 Meeting the CO2 Challenge DEER 2002 2002 DEER Conference Presentation: Ricardo 2002deergraham.pdf More Documents & Publications Application of...

  1. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From CO2 to Methanol via Novel Nanocatalysts Print Researchers have found novel nanocatalysts that lower the barrier to converting carbon dioxide (CO2)-an abundant greenhouse...

  2. Theoretical Synthesis of Mixed Materials for CO2 Capture Applications...

    Office of Scientific and Technical Information (OSTI)

    Theoretical Synthesis of Mixed Materials for CO2 Capture Applications Citation Details In-Document Search Title: Theoretical Synthesis of Mixed Materials for CO2 Capture...

  3. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    CONSTRAIN CO2 INJECTION FEASIBILITY: TEAPOT DOME EOR PILOTEOR, and coupled process modeling will investigate the total system including preliminary estimates of CO2

  4. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01

    Texas •? Over 30 years of CO2-EOR •? Sampled outside ofF Monitoring studies above EOR-CO2 fields Weyburn-Midale

  5. 10 MW Supercritical CO2 Turbine Test

    SciTech Connect (OSTI)

    Turchi, Craig

    2014-01-29

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650ºC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late in Phase 1 an opportunity arose to collaborate with another turbine-development team to construct a shared s-CO2 test facility. The synergy of the combined effort would result in greater facility capabilities than either separate project could produce and would allow for testing of both turbine designs within the combined budgets of the two projects. The project team requested a no-cost extension to Phase 1 to modify the subsequent work based on this collaborative approach. DOE authorized a brief extension, but ultimately opted not to pursue the collaborative facility and terminated the project.

  6. Buildings, Commissioning, Efficiency, Comfort, and CO2 

    E-Print Network [OSTI]

    Claridge, D. E.

    2006-01-01

    .6% of world CO2 emissions)? US commercial sector use ~50% of world commercial use? Asia today 10-20% of world commercial use 2055200514 7 Billion of Tons of Carbon Emitted per Year 1955 0 C Flat path Historicalemissions 1.9 ?Æ?Æ 2105 14 GtC/y7 GtC/y Seven..., Commissioning, Efficiency, Comfort, and CO2 Asian Pacific Building Commissioning Conference ICEBONovember 8, 2006Shenzhen, ChinaPresented ByDavid E. ClaridgeEnergy Systems LaboratoryTexas A&M University Commissioning New Buildings Beginnings Building Handover...

  7. Mechanically Cooled Large-Volume Germanium Detector Systems for Neclear Explosion Monitoring DOENA27323-2

    SciTech Connect (OSTI)

    Hull, E.L.

    2006-10-30

    Compact maintenance free mechanical cooling systems are being developed to operate large volume high-resolution gamma-ray detectors for field applications. To accomplish this we are utilizing a newly available generation of Stirling-cycle mechanical coolers to operate the very largest volume germanium detectors with no maintenance. The user will be able to leave these systems unplugged on the shelf until needed. The maintenance-free operating lifetime of these detector systems will exceed 5 years. Three important factors affect the operation of mechanically cooled germanium detectors: temperature, vacuum, and vibration. These factors will be studied in the laboratory at the most fundamental levels to insure a solid understanding of the physical limitations each factor places on a practical mechanically cooled germanium detector system. Using this knowledge, mechanically cooled germanium detector prototype systems will be designed and fabricated.

  8. Silurian "Clinton" Sandstone Reservoir Characterization for Evaluation of CO2-EOR Potential in the East Canton Oil Field, Ohio

    SciTech Connect (OSTI)

    Riley, Ronald; Wicks, John; Perry, Christopher

    2009-12-30

    The purpose of this study was to evaluate the efficacy of using CO2-enhanced oil recovery (EOR) in the East Canton oil field (ECOF). Discovered in 1947, the ECOF in northeastern Ohio has produced approximately 95 million barrels (MMbbl) of oil from the Silurian “Clinton” sandstone. The original oil-in-place (OOIP) for this field was approximately 1.5 billion bbl and this study estimates by modeling known reservoir parameters, that between 76 and 279 MMbbl of additional oil could be produced through secondary recovery in this field, depending on the fluid and formation response to CO2 injection. A CO2 cyclic test (“Huff-n-Puff”) was conducted on a well in Stark County to test the injectivity in a “Clinton”-producing oil well in the ECOF and estimate the dispersion or potential breakthrough of the CO2 to surrounding wells. Eighty-one tons of CO2 (1.39 MMCF) were injected over a 20-hour period, after which the well was shut in for a 32-day “soak” period before production was resumed. Results demonstrated injection rates of 1.67 MMCF of gas per day, which was much higher than anticipated and no CO2 was detected in gas samples taken from eight immediately offsetting observation wells. All data collected during this test was analyzed, interpreted, and incorporated into the reservoir characterization study and used to develop the geologic model. The geologic model was used as input into a reservoir simulation performed by Fekete Associates, Inc., to estimate the behavior of reservoir fluids when large quantities of CO2 are injected into the “Clinton” sandstone. Results strongly suggest that the majority of the injected CO2 entered the matrix porosity of the reservoir pay zones, where it diffused into the oil. Evidence includes: (A) the volume of injected CO2 greatly exceeded the estimated capacity of the hydraulic fracture and natural fractures; (B) there was a gradual injection and pressure rate build-up during the test; (C) there was a subsequent, gradual flashout of the CO2 within the reservoir during the ensuing monitored production period; and (D) a large amount of CO2 continually off-gassed from wellhead oil samples collected as late as 3½ months after injection. After the test well was returned to production, it produced 174 bbl of oil during a 60-day period (September 22 to November 21, 2008), which represents an estimated 58 percent increase in incremental oil production over preinjection estimates of production under normal, conditions. The geologic model was used in a reservoir simulation model for a 700-acre model area and to design a pilot to test the model. The model was designed to achieve a 1-year response time and a five-year simulation period. The reservoir simulation modeling indicated that the injection wells could enhance oil production and lead to an additional 20 percent recovery in the pilot area over a five-year period. The base case estimated that by injecting 500 MCF per day of CO2 into each of the four corner wells, 26,000 STBO would be produced by the central producer over the five-year period. This would compare to 3,000 STBO if a new well were drilled without the benefit of CO2 injection. This study has added significant knowledge to the reservoir characterization of the “Clinton” in the ECOF and succeeded in identifying a range on CO2-EOR potential. However, additional data on fluid properties (PVT and swelling test), fractures (oriented core and microseis), and reservoir characteristics (relative permeability, capillary pressure, and wet ability) are needed to further narrow the uncertainties and refine the reservoir model and simulation. After collection of this data and refinement of the model and simulation, it is recommended that a larger scale cyclic- CO2 injection test be conducted to better determine the efficacy of CO2-EOR in the “Clinton” reservoir in the ECOF.

  9. Silurian "Clinton" Sandstone Reservoir Characterization for Evaluation of CO2-EOR Potential in the East Canton Oil Field, Ohio

    SciTech Connect (OSTI)

    Ronald Riley; John Wicks; Christopher Perry

    2009-12-30

    The purpose of this study was to evaluate the efficacy of using CO2-enhanced oil recovery (EOR) in the East Canton oil field (ECOF). Discovered in 1947, the ECOF in northeastern Ohio has produced approximately 95 million barrels (MMbbl) of oil from the Silurian 'Clinton' sandstone. The original oil-in-place (OOIP) for this field was approximately 1.5 billion bbl and this study estimates by modeling known reservoir parameters, that between 76 and 279 MMbbl of additional oil could be produced through secondary recovery in this field, depending on the fluid and formation response to CO2 injection. A CO2 cyclic test ('Huff-n-Puff') was conducted on a well in Stark County to test the injectivity in a 'Clinton'-producing oil well in the ECOF and estimate the dispersion or potential breakthrough of the CO2 to surrounding wells. Eighty-one tons of CO2 (1.39 MMCF) were injected over a 20-hour period, after which the well was shut in for a 32-day 'soak' period before production was resumed. Results demonstrated injection rates of 1.67 MMCF of gas per day, which was much higher than anticipated and no CO2 was detected in gas samples taken from eight immediately offsetting observation wells. All data collected during this test was analyzed, interpreted, and incorporated into the reservoir characterization study and used to develop the geologic model. The geologic model was used as input into a reservoir simulation performed by Fekete Associates, Inc., to estimate the behavior of reservoir fluids when large quantities of CO2 are injected into the 'Clinton' sandstone. Results strongly suggest that the majority of the injected CO2 entered the matrix porosity of the reservoir pay zones, where it diffused into the oil. Evidence includes: (A) the volume of injected CO2 greatly exceeded the estimated capacity of the hydraulic fracture and natural fractures; (B) there was a gradual injection and pressure rate build-up during the test; (C) there was a subsequent, gradual flashout of the CO2 within the reservoir during the ensuing monitored production period; and (D) a large amount of CO2 continually off-gassed from wellhead oil samples collected as late as 3 1/2 months after injection. After the test well was returned to production, it produced 174 bbl of oil during a 60-day period (September 22 to November 21, 2008), which represents an estimated 58 percent increase in incremental oil production over preinjection estimates of production under normal, conditions. The geologic model was used in a reservoir simulation model for a 700-acre model area and to design a pilot to test the model. The model was designed to achieve a 1-year response time and a five-year simulation period. The reservoir simulation modeling indicated that the injection wells could enhance oil production and lead to an additional 20 percent recovery in the pilot area over a five-year period. The base case estimated that by injecting 500 MCF per day of CO2 into each of the four corner wells, 26,000 STBO would be produced by the central producer over the five-year period. This would compare to 3,000 STBO if a new well were drilled without the benefit of CO2 injection. This study has added significant knowledge to the reservoir characterization of the 'Clinton' in the ECOF and succeeded in identifying a range on CO2-EOR potential. However, additional data on fluid properties (PVT and swelling test), fractures (oriented core and microseis), and reservoir characteristics (relative permeability, capillary pressure, and wet ability) are needed to further narrow the uncertainties and refine the reservoir model and simulation. After collection of this data and refinement of the model and simulation, it is recommended that a larger scale cyclic-CO2 injection test be conducted to better determine the efficacy of CO2-EOR in the 'Clinton' reservoir in the ECOF.

  10. Modelling the deployment of CO2 storage in U.S. gas-bearing shales

    SciTech Connect (OSTI)

    Davidson, Casie L.; Dahowski, Robert T.; Dooley, James J.; McGrail, B. Peter

    2014-10-23

    The proliferation of commercial development in U.S. gas-bearing shales helped to drive a twelve-fold increase in domestic gas production between 2000 and 2010, and the nation’s gas production rates continue to grow. While shales have long been regarded as a desirable caprock for CCS operations because of their low permeability and porosity, there is increasing interest in the feasibility of injecting CO2 into shales to enhance methane recovery and augment CO2 storage. Laboratory work published in recent years observes that shales with adsorbed methane appear to exhibit a stronger affinity for CO2 adsorption, offering the potential to drive additional CH4 recovery beyond primary production and perhaps the potential to store a larger volume of CO2 than the volume of methane displaced. Recent research by the authors on the revenues associated with CO2-enhanced gas recovery (CO2-EGR) in gas-bearing shales estimates that, based on a range of EGR response rates, the average revenue per ton of CO2 for projects managed over both EGR and subsequent storage-only phases could range from $0.50 to $18/tCO2. While perhaps not as profitable as EOR, for regions where lower-cost storage options may be limited, shales could represent another “early opportunity” storage option if proven feasible for reliable EGR and CO2 storage. Significant storage potential exists in gas shales, with theoretical CO2 storage resources estimated at approximately 30-50 GtCO2. However, an analysis of the comprehensive cost competitiveness of these various options is necessary to understand the degree to which they might meaningfully impact U.S. CCS deployment or costs. This preliminary analysis shows that the degree to which EGR-based CO2 storage could play a role in commercial-scale deployment is heavily dependent upon the offsetting revenues associated with incremental recovery; modeling the low revenue case resulted in only five shale-based projects, while under the high revenue case, shales accounted for as much as 20 percent of total U.S. storage in the first 20 years of deployment. Interestingly, even in this highest revenue case, there appear to be no negative-cost projects that would be profitable in a no-policy environment as modeled under the assumptions employed. While this reflects a very first look at the potential for shales, it is clear that more laboratory and experimental work are needed to reduce uncertainty in key variables and begin to differentiate and identify high-potential shales for early pilot study.

  11. The supply chain of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Peters, G. P; Caldeira, K.

    2011-01-01

    impose a price on the carbon in their own fossil fuels forprice A nthropogenic climate change is driven by CO 2 emissions from the burning of fossil fuels (fossil fuel resources are suf?ciently concentrated such that, if the relatively few countries that extract the most fuels imposed a price

  12. Ocean Acidification: The Other CO2 Problem

    E-Print Network [OSTI]

    Childress, Michael J.

    reserved 1941-1405/09/0115-0169$20.00 Key Words biogeochemistry, calcification, carbon dioxide, climate of calcium carbonate saturation states, which impacts shell-forming marine organisms from plankton to benthic for marine organisms to adapt to increasing CO2 and broader implications for ocean ecosystems are not well

  13. BUILDING A CO2 STORAGE HUB IN

    E-Print Network [OSTI]

    Painter, Kevin

    , once at the forefront of this innovative technology that can give us clean energy from abundant fossil technology we have in the battle to reduce CO2 emissions from power and industrial sources. Without it we and global reliance on low-cost energy from coal and gas shows no sign of diminishing, the time has come

  14. Aquifer Management for CO2 Sequestration 

    E-Print Network [OSTI]

    Anchliya, Abhishek

    2010-07-14

    Storage of carbon dioxide is being actively considered for the reduction of green house gases. To make an impact on the environment CO2 should be put away on the scale of gigatonnes per annum. The storage capacity of deep saline aquifers...

  15. Porous Hexacyanometalates for CO2 capture applications

    SciTech Connect (OSTI)

    Motkuri, Radha K.; Thallapally, Praveen K.; McGrail, B. Peter

    2013-07-30

    Prussian blue analogues of M3[Fe(CN)6]2 x H2O (where M=Fe, Mn and Ni) were synthesized, characterized and tested for their gas sorption capabilities. The sorption studies reveal that, these Prussian blue materials preferentially sorb CO2 over N2 and CH4 at low pressure (1bar).

  16. No Leafcaster? No Problem! Using the suction table to fill large lacunae in an entire volume

    E-Print Network [OSTI]

    Baker, Whitney

    2005-07-22

    stream_size 4814 stream_content_type text/plain stream_name iowa poster 2005 small.pdf.txt stream_source_info iowa poster 2005 small.pdf.txt Content-Encoding ISO-8859-1 Content-Type text/plain; charset=ISO-8859...-1 No Leafcaster? No Problem! Using the Suction Table to Fill Large Lacunae in an Entire Volume Whitney Baker, Conservator, University of Kansas Libraries, Lawrence, KS 66045, wbaker@ku.edu C a s e S t u d y W o r k f l o w R e s u l t s CONDITION OF ITEM The 17...

  17. NOVEL CONCEPTS FOR THE COMPRESSION OF LARGE VOLUMES OF CARBON DIOXIDE-PHASE III

    SciTech Connect (OSTI)

    Moore, J. Jeffrey; Allison, Timothy; Evans, Neal; Moreland, Brian; Hernandez, Augusto; Day, Meera; Ridens, Brandon

    2014-06-30

    In the effort to reduce the release of CO2 greenhouse gases to the atmosphere, sequestration of CO2 from Integrated Gasification Combined Cycle (IGCC) and Oxy-Fuel power plants is being pursued. This approach, however, requires significant compression power to boost the pressure to typical pipeline levels. The penalty can be as high as 8-12% on a typical IGCC plant. The goal of this research is to reduce this penalty through novel compression concepts and integration with existing IGCC processes. The primary objective of the study of novel CO2 compression concepts is to reliably boost the pressure of CO2 to pipeline pressures with the minimal amount of energy required. Fundamental thermodynamics were studied to explore pressure rise in both liquid and gaseous states. For gaseous compression, the project investigated novel methods to compress CO2 while removing the heat of compression internal to the compressor. The highpressure ratio, due to the delivery pressure of the CO2 for enhanced oil recovery, results in significant heat of compression. Since less energy is required to boost the pressure of a cooler gas stream, both upstream and inter-stage cooling is desirable. While isothermal compression has been utilized in some services, it has not been optimized for the IGCC environment. Phase I of this project determined the optimum compressor configuration and developed technology concepts for internal heat removal. Other compression options using liquefied CO2 and cryogenic pumping were explored as well. Preliminary analysis indicated up to a 35% reduction in power is possible with the new concepts being considered. In the Phase II program, two experimental test rigs were developed to investigate the two concepts further. A new pump loop facility was constructed to qualify a cryogenic turbopump for use on liquid CO2. Also, an internally cooled compressor diaphragm was developed and tested in a closed loop compressor facility using CO2. Both test programs successfully demonstrated good performance and mechanical behavior. In Phase III, a pilot compression plant consisting of a multi-stage centrifugal compressor with cooled diaphragm technology has been designed, constructed, and tested. Comparative testing of adiabatic and cooled tests at equivalent inlet conditions shows that the cooled diaphragms reduce power consumption by 3-8% when the compressor is operated as a back-to-back unit and by up to 9% when operated as a straight-though compressor with no intercooler. The power savings, heat exchanger effectiveness, and temperature drops for the cooled diaphragm were all slightly higher than predicted values but showed the same trends.

  18. IMPLICATION FOR THE CORE-COLLAPSE SUPERNOVA RATE FROM 21 YEARS OF DATA OF THE LARGE VOLUME DETECTOR

    E-Print Network [OSTI]

    Pless, Irwin A.

    The Large Volume Detector (LVD) has been continuously taking data since 1992 at the INFN Gran Sasso National Laboratory. The LVD is sensitive to neutrino bursts from gravitational stellar collapses with full detection ...

  19. The millennial atmospheric lifetime of anthropogenic CO2

    E-Print Network [OSTI]

    Cambridge, University of

    /ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, rangingThe millennial atmospheric lifetime of anthropogenic CO2 David Archer & Victor Brovkin Received: 19

  20. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2005 Quarterly Progress. #12;3 Abstract The objective of this work is to improve the process for CO2 capture by alkanolamine transfer area as IMTP#40 dumped packing. Independent measurements of CO2 solubility give a CO2 loading

  1. CO2 enrichment increases carbon and nitrogen input from

    E-Print Network [OSTI]

    CO2 enrichment increases carbon and nitrogen input from fine roots in a deciduous forest Colleen2 Ecological Society of America, 2008 #12;#12;#12;#12;#12;+ [CO2] #12;+ Net primary production + [CO2] #12;+ Net primary production + [CO2] + C and N storage in biomass #12;+ Net primary production

  2. Non-isothermal CO2 flow through an injection well

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    production - superheated steam injection The CO2 phase, whether gas, liquid or supercritical, is determined

  3. Rate Determination of the CO2* Chemiluminescence Reaction CO + O + M = CO2* + M 

    E-Print Network [OSTI]

    Kopp, Madeleine Marissa, 1987-

    2012-10-15

    numerous works have monitored CO2* chemiluminescence, a full kinetic scheme for the species has yet to be developed. A series of shock-tube experiments was performed in H2-N2O-CO mixtures highly diluted in argon at conditions where emission from CO2... for eleven common collision partners. The final mechanism developed for CO2* consisted of 14 reactions and 13 species. The rate for R1 was determined based on low-pressure experiments performed in two different H2-N2O-CO-Ar mixtures. Final mechanism...

  4. Hybrid Parallelism for Volume Rendering on Large, Multi-core Systems

    SciTech Connect (OSTI)

    Howison, Mark; Bethel, E. Wes; Childs, Hank

    2010-07-12

    This work studies the performance and scalability characteristics of"hybrid'"parallel programming and execution as applied to raycasting volume rendering -- a staple visualization algorithm -- on a large, multi-core platform. Historically, the Message Passing Interface (MPI) has become the de-facto standard for parallel programming and execution on modern parallel systems. As the computing industry trends towards multi-core processors, with four- and six-core chips common today and 128-core chips coming soon, we wish to better understand how algorithmic and parallel programming choices impact performance and scalability on large, distributed-memory multi-core systems. Our findings indicate that the hybrid-parallel implementation, at levels of concurrency ranging from 1,728 to 216,000, performs better, uses a smaller absolute memory footprint, and consumes less communication bandwidth than the traditional, MPI-only implementation.

  5. MPI-hybrid Parallelism for Volume Rendering on Large, Multi-core Systems

    SciTech Connect (OSTI)

    Howison, Mark; Bethel, E. Wes; Childs, Hank

    2010-03-20

    This work studies the performance and scalability characteristics of"hybrid'" parallel programming and execution as applied to raycasting volume rendering -- a staple visualization algorithm -- on a large, multi-core platform. Historically, the Message Passing Interface (MPI) has become the de-facto standard for parallel programming and execution on modern parallel systems. As the computing industry trends towards multi-core processors, with four- and six-core chips common today and 128-core chips coming soon, we wish to better understand how algorithmic and parallel programming choices impact performance and scalability on large, distributed-memory multi-core systems. Our findings indicate that the hybrid-parallel implementation, at levels of concurrency ranging from 1,728 to 216,000, performs better, uses a smaller absolute memory footprint, and consumes less communication bandwidth than the traditional, MPI-only implementation.

  6. Hybrid Parallelism for Volume Rendering on Large, Multi- and Many-core Systems

    SciTech Connect (OSTI)

    Howison, Mark; Bethel, E. Wes; Childs, Hank

    2011-01-01

    With the computing industry trending towards multi- and many-core processors, we study how a standard visualization algorithm, ray-casting volume rendering, can benefit from a hybrid parallelism approach. Hybrid parallelism provides the best of both worlds: using distributed-memory parallelism across a large numbers of nodes increases available FLOPs and memory, while exploiting shared-memory parallelism among the cores within each node ensures that each node performs its portion of the larger calculation as efficiently as possible. We demonstrate results from weak and strong scaling studies, at levels of concurrency ranging up to 216,000, and with datasets as large as 12.2 trillion cells. The greatest benefit from hybrid parallelism lies in the communication portion of the algorithm, the dominant cost at higher levels of concurrency. We show that reducing the number of participants with a hybrid approach significantly improves performance.

  7. Hybrid Parallelism for Volume Rendering on Large, Multi-core Systems

    SciTech Connect (OSTI)

    Howison, Mark; Bethel, E. Wes; Childs, Hank

    2010-06-14

    This work studies the performance and scalability characteristics of"hybrid" parallel programming and execution as applied to raycasting volume rendering -- a staple visualization algorithm -- on a large, multi-core platform. Historically, the Message Passing Interface (MPI) has become the de-facto standard for parallel programming and execution on modern parallel systems. As the computing industry trends towards multi-core processors, with four- and six-core chips common today and 128-core chips coming soon, we wish to better understand how algorithmic and parallel programming choices impact performance and scalability on large, distributed-memory multi-core systems. Our findings indicate that the hybrid-parallel implementation, at levels of concurrency ranging from 1,728 to 216,000, performs better, uses a smaller absolute memory footprint, and consumes less communication bandwidth than the traditional, MPI-only implementation.

  8. Modeling Hydrogeological and Geomenchanical Processes Related to CO2 Injection in a Faulted Multilayer System

    E-Print Network [OSTI]

    Rutqvist, Jonny; Birkholzer, Jens; Tsang, Chin-Fu

    2006-01-01

    underground injection of supercritical CO2 in a hypotheticalthe CO2-rich phase (supercritical CO2 with small amounts of

  9. Mechanically Cooled Large-Volume Germanium Detector Systems for Nuclear Explosion Monitoring

    SciTech Connect (OSTI)

    Hull, Ethan L.; Pehl, Richard H.; Lathrop, James R.; Martin, Gregory N.; Mashburn, R. B.; Miley, Harry S.; Aalseth, Craig E.; Hossbach, Todd W.; Bowyer, Ted W.

    2006-09-21

    Compact maintenance free mechanical cooling systems are being developed to operate large volume (~570 cm3, ~3 kg, 140% or larger) germanium detectors for field applications. We are using a new generation of Stirling-cycle mechanical coolers for operating the very largest volume germanium detectors with absolutely no maintenance or liquid nitrogen requirements. The user will be able to leave these systems unplugged on the shelf until needed. The flip of a switch will bring a system to life in ~1 hour for measurements. The maintenance-free operating lifetime of these detector systems will exceed five years. These features are necessary for remote long-duration liquid-nitrogen free deployment of large-volume germanium gamma-ray detector systems for Nuclear Explosion Monitoring (NEM). The Radionuclide Aerosol Sampler/Analyzer (RASA) will greatly benefit from the availability of such detectors by eliminating the need for liquid nitrogen at RASA sites while still allowing the very largest available germanium detectors to be utilized. These mechanically cooled germanium detector systems being developed here will provide the largest, most sensitive detectors possible for use with the RASA. To provide such systems, the appropriate technical fundamentals are being researched. Mechanical cooling of germanium detectors has historically been a difficult endeavor. The success or failure of mechanically cooled germanium detectors stems from three main technical issues: temperature, vacuum, and vibration. These factors affect one another. There is a particularly crucial relationship between vacuum and temperature. These factors will be experimentally studied both separately and together to insure a solid understanding of the physical limitations each factor places on a practical mechanically cooled germanium detector system for field use. Using this knowledge, a series of mechanically cooled germanium detector prototype systems are being designed and fabricated. Our collaborators at Pacific Northwest National Laboratory (PNNL) will evaluate these detector systems on the bench top and eventually in RASA systems to insure reliable and practical operation.

  10. Using CO2 & Algae to Treat Wastewater and

    E-Print Network [OSTI]

    Keller, Arturo A.

    Using CO2 & Algae to Treat Wastewater and Produce Biofuel Feedstock Tryg Lundquist Cal Poly State of the Industry and Growth · Algae's Role in WW Treatment · CO2's New Role · Research at Cal Poly · Future Work/MG 0.3 MGD average flow per facility #12;Reclaimed Algae Bacteria O2 CO2 N Organics N P CO2 P CO2 Waste

  11. VolumeExplorer: Roaming Large Volumes to Couple Visualization and Data Processing for Oil and Gas Exploration

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . Geoscientists build this model from the interpretation of seismic data, i.e. 3D images of the subsurface for the interpretation of seismic data. It is based on volume roaming along with efficient volume paging to manipulate Seismic interpretation is an important task in the oil and gas exploration-production (EP) workflow [9, 26

  12. The response of soil CO2 ux to changes in atmospheric CO2, nitrogen supply and plant diversity

    E-Print Network [OSTI]

    Thomas, David D.

    The response of soil CO2 ¯ux to changes in atmospheric CO2, nitrogen supply and plant diversity J O. Paul, MN 55108 USA Abstract We measured soil CO2 ¯ux over 19 sampling periods that spanned two growing three major anthropogenic global changes: atmos- pheric carbon dioxide (CO2) concentration, nitrogen (N

  13. An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of atmospheric CO2

    E-Print Network [OSTI]

    Hoffman, Forrest M.

    An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of atmospheric CO2 D. J. Erickson III,1,2 R. T. Mills,1 J. Gregg,3 T. J. Blasing,4 F. M. Hoffman,1 R. J. Andres,4 of anthropogenic CO2 are presented. Approximating the seasonal CO2 emission cycle using a 2-harmonic Fourier series

  14. CO2-H2O mixtures in the geological sequestration of CO2. II ...

    E-Print Network [OSTI]

    2005-07-01

    experimental and field data. ... In all studies discussed above, the solubility of CO2 in water ...... Li Y., and Nghiem L. X. (1986) Phase equilibria of oil, gas and.

  15. Continuous CO2 extractor and methods

    SciTech Connect (OSTI)

    None listed

    2010-06-15

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  16. 10-MW Supercritical-CO2 Turbine

    Office of Energy Efficiency and Renewable Energy (EERE)

    This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cycle—the supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

  17. Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers

    SciTech Connect (OSTI)

    Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

    2014-08-01

    In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

  18. Carbon dioxide in silica-undersaturated melt Part I: The effect of mixed alkalis (K and Na) on CO2 solubility and speciation.

    E-Print Network [OSTI]

    Boyer, Edmond

    . These low-silica melts can dissolve a large quantity of CO2 and are rich in alkalis. However, the way CO2 experimental results on the CO2 solubility and speciation in synthetic nephelinite in the NKCMAS system, equilibrated at high-pressure (50-300 MPa), high-temperature (1250C) with an excess C-O-H fluid phase

  19. Summary IsotoperatioanalysesofatmosphericCO2 atnatu-ral abundance have significant potential for contributing to our

    E-Print Network [OSTI]

    Ehleringer, Jim

    dioxide in atmospheric air. Routine analysis of carbon dioxide in air volumes of approxi- mately 50 levels. Among the immediate applications are the carbon and oxygen isotope ratio analyses of carbon to sample CO2 extensively in remote forest locations. The air-sampling system was used to measure

  20. Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen Generation | Center forPostcombustion Carbon Dioxide Capture |

  1. Predicting Large CO2 Adsorption in Aluminosilicate Zeolites for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen Generation | Center forPostcombustion Carbon Dioxide Capture

  2. A large volume uniform plasma generator for the experiments of electromagnetic wave propagation in plasma

    SciTech Connect (OSTI)

    Yang Min; Li Xiaoping; Xie Kai; Liu Donglin; Liu Yanming

    2013-01-15

    A large volume uniform plasma generator is proposed for the experiments of electromagnetic (EM) wave propagation in plasma, to reproduce a 'black out' phenomenon with long duration in an environment of the ordinary laboratory. The plasma generator achieves a controllable approximate uniform plasma in volume of 260 mm Multiplication-Sign 260 mm Multiplication-Sign 180 mm without the magnetic confinement. The plasma is produced by the glow discharge, and the special discharge structure is built to bring a steady approximate uniform plasma environment in the electromagnetic wave propagation path without any other barriers. In addition, the electron density and luminosity distributions of plasma under different discharge conditions were diagnosed and experimentally investigated. Both the electron density and the plasma uniformity are directly proportional to the input power and in roughly reverse proportion to the gas pressure in the chamber. Furthermore, the experiments of electromagnetic wave propagation in plasma are conducted in this plasma generator. Blackout phenomena at GPS signal are observed under this system and the measured attenuation curve is of reasonable agreement with the theoretical one, which suggests the effectiveness of the proposed method.

  3. Enhanced Coal Bed Methane Recovery and CO2 Sequestration in the Powder River Basin

    SciTech Connect (OSTI)

    Eric P. Robertson

    2010-06-01

    Unminable coal beds are potentially large storage reservoirs for the sequestration of anthropogenic CO2 and offer the benefit of enhanced methane production, which can offset some of the costs associated with CO2 sequestration. The objective of this report is to provide a final topical report on enhanced coal bed methane recovery and CO2 sequestration to the U.S. Department of Energy in fulfillment of a Big Sky Carbon Sequestration Partnership milestone. This report summarizes work done at Idaho National Laboratory in support of Phase II of the Big Sky Carbon Sequestration Partnership. Research that elucidates the interaction of CO2 and coal is discussed with work centering on the Powder River Basin of Wyoming and Montana. Sorption-induced strain, also referred to as coal swelling/shrinkage, was investigated. A new method of obtaining sorption-induced strain was developed that greatly decreases the time necessary for data collection and increases the reliability of the strain data. As coal permeability is a strong function of sorption-induced strain, common permeability models were used to fit measured permeability data, but were found inadequate. A new permeability model was developed that can be directly applied to coal permeability data obtained under laboratory stress conditions, which are different than field stress conditions. The coal permeability model can be used to obtain critical coal parameters that can be applied in field models. An economic feasibility study of CO2 sequestration in unminable coal seams in the Powder River Basin of Wyoming was done. Economic analyses of CO2 injection options are compared. Results show that injecting flue gas to recover methane from CBM fields is marginally economical; however, this method will not significantly contribute to the need to sequester large quantities of CO2. Separating CO2 from flue gas and injecting it into the unminable coal zones of the Powder River Basin seam is currently uneconomical, but can effectively sequester over 86,000 tons (78,200 Mg) of CO2 per acre while recovering methane to offset costs. The cost to separate CO2 from flue gas was identified as the major cost driver associated with CO2 sequestration in unminable coal seams. Improvements in separations technology alone are unlikely to drive costs low enough for CO2 sequestration in unminable coal seams in the Powder River Basin to become economically viable. Breakthroughs in separations technology could aid the economics, but in the Powder River Basin, they cannot achieve the necessary cost reductions for breakeven economics without incentives.

  4. Early opportunities of CO2 geological storage deployment in coal chemical industry in China

    SciTech Connect (OSTI)

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, Robert T.; Davidson, Casie L.

    2014-11-12

    Abstract: Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO2 emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO2 sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation or in late planning stages. These emission sources together emit 430 million tons CO2 per year, of which about 30% are emit high-purity and pure CO2 (CO2 concentration >80% and >99% respectively).Four typical source-sink pairs are studied by a techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and experienced economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO2 capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO2. When a 15USD/t CO2 tax and 15USD/t for CO2 sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a net economic benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.

  5. Early Opportunities of CO2 Geological Storage Deployment in Coal Chemical Industry in China

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Ning; Li, Xiaochun; Liu, Shengnan; Dahowski, R.T.; Davidson, C.L.

    2014-12-31

    Carbon dioxide capture and geological storage (CCS) is regarded as a promising option for climate change mitigation; however, the high capture cost is the major barrier to large-scale deployment of CCS technologies. High-purity CO2 emission sources can reduce or even avoid the capture requirements and costs. Among these high-purity CO2 sources, certain coal chemical industry processes are very important, especially in China. In this paper, the basic characteristics of coal chemical industries in China is investigated and analyzed. As of 2013 there were more than 100 coal chemical plants in operation. These emission sources together emit 430 million tons CO2more »per year, of which about 30% are emit high-purity and pure CO2 (CO2 concentration >80% and >98.5% respectively). Four typical source-sink pairs are chosen for techno-economic evaluation, including site screening and selection, source-sink matching, concept design, and economic evaluation. The technical-economic evaluation shows that the levelized cost of a CO2 capture and aquifer storage project in the coal chemistry industry ranges from 14 USD/t to 17 USD/t CO2. When a 15USD/t CO2 tax and 20USD/t for CO2 sold to EOR are considered, the levelized cost of CCS project are negative, which suggests a benefit from some of these CCS projects. This might provide China early opportunities to deploy and scale-up CCS projects in the near future.« less

  6. PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP

    SciTech Connect (OSTI)

    Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O'Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

    2006-01-01

    During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

  7. NETL CO2 Storage Frequently Asked Questions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMissionStressMoveMuncriefB NESEA Newsletter ContentCO2

  8. CO2 Compression | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &Bradbury ScienceComplex earning FPEComplex CNS,CO2

  9. CO2 | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick, Maine:IAEATCNAA Jump to:Emissions fromCO2

  10. CO2 Utilization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:I DueBETOof Energy Office ofCERTIFIED2,May 4, 2011CO2

  11. Scope for Future CO2 Emission Reductions from Electricity Generation through the Deployment of Carbon Capture and Storage Technologies

    E-Print Network [OSTI]

    Scope for Future CO2 Emission Reductions from Electricity Generation through the Deployment-emission electricity within one or two decades. Renewable generation is also planned to increase over similar time, it is therefore possible that large (~45%) reductions in CO2 emissions from UK electricity generation could

  12. Integration & Co-development of a Geophysical CO2 Monitoring Suite

    SciTech Connect (OSTI)

    Friedmann, S J

    2007-07-24

    Carbon capture and sequestration (CCS) has emerged as a key technology for dramatic short-term reduction in greenhouse gas emissions in particular from large stationary. A key challenge in this arena is the monitoring and verification (M&V) of CO2 plumes in the deep subsurface. Towards that end, we have developed a tool that can simultaneously invert multiple sub-surface data sets to constrain the location, geometry, and saturation of subsurface CO2 plumes. We have focused on a suite of unconventional geophysical approaches that measure changes in electrical properties (electrical resistance tomography, electromagnetic induction tomography) and bulk crustal deformation (til-meters). We had also used constraints of the geology as rendered in a shared earth model (ShEM) and of the injection (e.g., total injected CO{sub 2}). We describe a stochastic inversion method for mapping subsurface regions where CO{sub 2} saturation is changing. The technique combines prior information with measurements of injected CO{sub 2} volume, reservoir deformation and electrical resistivity. Bayesian inference and a Metropolis simulation algorithm form the basis for this approach. The method can (a) jointly reconstruct disparate data types such as surface or subsurface tilt, electrical resistivity, and injected CO{sub 2} volume measurements, (b) provide quantitative measures of the result uncertainty, (c) identify competing models when the available data are insufficient to definitively identify a single optimal model and (d) rank the alternative models based on how well they fit available data. We present results from general simulations of a hypothetical case derived from a real site. We also apply the technique to a field in Wyoming, where measurements collected during CO{sub 2} injection for enhanced oil recovery serve to illustrate the method's performance. The stochastic inversions provide estimates of the most probable location, shape, volume of the plume and most likely CO{sub 2} saturation. The results suggest that the method can reconstruct data with poor signal to noise ratio and use hard constraints available from many sites and applications. External interest in the approach and method is high, and already commercial and DOE entities have requested technical work using the newly developed methodology for CO{sub 2} monitoring.

  13. Coupled reservoir-geomechanical analysis of CO2 injection and ground deformations at In Salah, Algeria

    E-Print Network [OSTI]

    Rutqvist, J.

    2010-01-01

    CO 2 sequestration; In Salah; geomechanics; ground surfaceCO 2 injection, geomechanics, and ground surface

  14. CO2 capture processes in power plants - Le captage du CO2 dans les centrales thermiques

    E-Print Network [OSTI]

    Chakib Bouallou

    2010-08-12

    This review is devoted to assess and compare various processes aiming at recover CO2 from power plants fed with natural gas (NGCC) and pulverized coal (PC). These processes are post combustion CO2 capture using chemical solvents, natural gas reforming for pre-combustion capture and oxy-fuel combustion with cryogenic recovery of CO2. These processes were evaluated to give some clues for choosing the best option for each type of power plant. The comparison of these various concepts suggests that, in the short and medium term, chemical absorption is the most interesting process for NGCC power plants. For CP power plants, oxy-combustion can be a very interesting option, as well as post-combustion capture by chemical solvents.

  15. CO2 Heat Pump Water Heater | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    CO2 Heat Pump Water Heater Prototype
    Credit: Oak Ridge National Lab CO2 Heat Pump Water Heater Prototype Credit: Oak Ridge National Lab Lead Performer: Oak Ridge National...

  16. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01

    emission and resource accounting. Ecol Econ 69:211–222. 12.Consumption-based accounting of CO 2 emissions Steven J.Consump- tion-based accounting of CO 2 emissions differs

  17. Formation Damage due to CO2 Sequestration in Saline Aquifers 

    E-Print Network [OSTI]

    Mohamed, Ibrahim Mohamed 1984-

    2012-10-25

    Carbon dioxide (CO2) sequestration is defined as the removal of gas that would be emitted into the atmosphere and its subsequent storage in a safe, sound place. CO2 sequestration in underground formations is currently being considered to reduce...

  18. UPDATE ON THE INTERNATIONAL EXPERIMENT ON CO2 OCEAN SEQUESTRATION

    E-Print Network [OSTI]

    discussed strategies for ocean carbon sequestration are direct injection of CO2 into the deep ocean and iron effort is solely focused on the direct injection approach. In this method, liquid CO2 is injected

  19. HYDROMECHANICAL CHARACTERIZATION FOR SITE SELECTION IN CO2 PERMANENT

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    of info and lack of info Arguments against: - It increases electricity cost + extra CO2 (CO2 market Sleipner In Salah Weyburn Snohvit #12;Uplift of 5 mm/yr in In Salah (Rutqvist et al., 2010, IJGGC

  20. North America's net terrestrial CO2 exchange with the atmosphere...

    Office of Scientific and Technical Information (OSTI)

    a synthesis of net land-atmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 1990-2009. Only CO2 is considered, not methane or...

  1. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    phase dispersivity test (BTC) Porosity-thickness product oftest Two-phase tracer BTC Evolution of CO 2 saturation

  2. CO2 stabilization, climate change and the terrestrial carbon sink

    E-Print Network [OSTI]

    White, Andrew

    CO2 stabilization, climate change and the terrestrial carbon sink A N D R E W W H I T E , * M E L V, Hybrid v4.1, with a subdaily timestep, was driven by increasing CO2 and transient climate output from scenarios were used: (i) IS92a, giving 790 ppm CO2 by 2100, (ii) CO2 stabilization at 750 ppm by 2225

  3. Variability of primary production and air-sea CO 2 flux in the Southern Ocean

    E-Print Network [OSTI]

    Wang, Shanlin; Moore, J. Keith

    2012-01-01

    Lima (2007), Enhanced CO 2 outgassing in the Southern OceanCO 2 run, there is a CO 2 outgassing trend of 0.07 PgC/yr/sink and a natural CO 2 outgassing. The anthropogenic CO 2

  4. Analytical Estimation of CO2 Storage Capacity in Depleted Oil and Gas Reservoirs Based on Thermodynamic State Functions 

    E-Print Network [OSTI]

    Valbuena Olivares, Ernesto

    2012-02-14

    from commercial PVT software package. Results present excellent agreement. Limited significant digits in commercial software lead to scattered data. ....................................... 80 Fig. 5.5? Case A?Fluid volume comparison from analytical... model and calculations from commercial PVT software package. Results present excellent agreement. ............................................................... 81 Fig. 5.6? Case B?CO2 molar density distribution at the end of injection. The CO2...

  5. Center for By-Products Utilization CO2 SEQUESTRATION

    E-Print Network [OSTI]

    Saldin, Dilano

    climate change, reduced GHGs, improved air quality, CO2 reduction & sequestration, and carbon offsets. #12 for the development of a technology for the carbon dioxide (CO2) sequestration in non-air entrained concreteCenter for By-Products Utilization CO2 SEQUESTRATION IN NON-AIR ENTRAINED CONCRETE By Tarun R. Naik

  6. Post-Combustion CO2 Capture 11 -13 July 2010

    E-Print Network [OSTI]

    Post-Combustion CO2 Capture Workshop 11 - 13 July 2010 Tufts European Center Talloires, France Institute | | Clean Air Task Force | | Asia Clean Energy Innovation Initiative | #12;Post-Combustion CO2 Capture Workshop 11 - 13 July 2010 Talloires, France PROCEEDINGS: Post-Combustion CO2 Capture Workshop

  7. Aquatic primary production in a high-CO2 world

    E-Print Network [OSTI]

    Fussman, Gregor

    Aquatic primary production in a high-CO2 world Etienne Low-De´carie, Gregor F. Fussmann, and Graham-Penfield, Montreal, QC, H3A 1B1, Canada Here, we provide a review of the direct effect of increas- ing CO2 on aquatic: the assessment of theories about limitation of productivity and the integration of CO2 into the co

  8. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Second Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing% inlet CO2. A rate-based model demonstrates that the stripper is primarily controlled by liquid film mast

  9. Widespread foliage d15 N depletion under elevated CO2

    E-Print Network [OSTI]

    Thomas, David D.

    Widespread foliage d15 N depletion under elevated CO2: inferences for the nitrogen cycle H O R M O an integrated assessment of the nitrogen (N) cycle and whether it is influenced by rising atmospheric CO2 concentration. We tested the hypothesis that elevated CO2 significantly changes foliage d15 N in a wide range

  10. Cimpor inventa nova frmula para reduzir pegada de CO2

    E-Print Network [OSTI]

    Instituto de Sistemas e Robotica

    Cimpor inventa nova fórmula para reduzir pegada de CO2 CIMENTO. A Cimpor descobriu uma nova fórmula para produzir ci- mento que lhe permitirá reduzir a pegada de CO 2 em 25%. Segundo as contas da as fábricas do grupo, seriam emitidos menos quatro milhões de toneladas de CO 2 por ano, o que permitiria uma

  11. CO2 dissolution in water using long serpentine microchannels

    E-Print Network [OSTI]

    Cubaud, Thomas

    CO2 dissolution in water using long serpentine microchannels Thomas Cubaud,a) Martin Sauzade dioxide-water is particularly impor- tant to the environment. When CO2 dissolves in water, it forms a weak shells.2 A method for enriching minute amount of water with CO2 on-chip would facilitate biological

  12. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2007 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing, requires equivalent work of 31.8 kJ/mole CO2 when used with a double matrix stripper and an intercooled

  13. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2006 Quarterly Progress the process for CO2 capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous. Uninhibited 5 m KHCO3/2.5 m PZ corrodes 5 to 6 times faster that 30% MEA with 0.2 mol CO2/mol MEA. #12

  14. Central serotonin neurons are required for arousal to CO2

    E-Print Network [OSTI]

    Central serotonin neurons are required for arousal to CO2 Gordon F. Buchanana,b,1 and George B neurons are stimulated by CO2, and sero- tonin activates thalamocortical networks, we hypothesized any arousal response to inhalation of 10% CO2 (with 21% O2 in balance N2) but had normal arousal

  15. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing use. Extensive measurements of CO2 solubility in 7 m MEA at 40 and 60o C have confirmed the work

  16. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing 20% of the power output from a 500 MW power plant with 90% CO2 removal. The stripper rate model shows

  17. Directed Technical Change and the Adoption of CO2 Abatement Technology: The Case of CO2 Capture and Storage

    E-Print Network [OSTI]

    Otto, Vincent M.

    This paper studies the cost effectiveness of combining traditional environmental policy, such as CO2 trading schemes, and technology policy that has aims of reducing the cost and speeding the adoption of CO2 abatement ...

  18. Study of CO2 Mobility Control Using Cross-linked Gel Conformance Control and CO2 Viscosifiers in Heterogeneous Media 

    E-Print Network [OSTI]

    Cai, Shuzong

    2011-10-21

    CO2 has been widely used as a displacement fluid in both immiscible and miscible displacement processes to obtain tertiary recovery from the field. There are several problems associated with the application of CO2 flooding, especially when...

  19. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Energy Concept Utilizing Supercritical CO2 Instead of Water,Feasibility of Using Supercritical CO2 as Heat Transmissionsupercritical CO 2 and rock minerals. Studies of geochemical interactions in EGS-CO2

  20. Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater

    E-Print Network [OSTI]

    Birkholzer, Jens

    2008-01-01

    Changes in Response to CO2 Leakage from Deep Geologicalstudy mineral trapping for CO2 disposal in deep arenaceousconstituents as function of P(CO2)? function of P(CO2)? – –

  1. The c2d Spitzer spectroscopic survey of ices around low-mass young stellar objects II: CO2

    E-Print Network [OSTI]

    Klaus M. Pontoppidan; A. C. A. Boogert; Helen J. Fraser; Ewine F. van Dishoeck; Geoffrey A. Blake; Fred Lahuis; Karin I. Oberg; Neal J. Evans II; Colette Salyk

    2007-11-28

    This paper presents Spitzer-IRS spectroscopy of the CO2 15.2 micron bending mode toward a sample of 50 embedded low-mass stars in nearby star-forming clouds, taken mostly from the ``Cores to Disks (c2d)'' Legacy program. The average abundance of solid CO2 relative to water in low-mass protostellar envelopes is 0.32 +/- 0.02, significantly higher than that found in quiescent molecular clouds and in massive star forming regions. It is found that a decomposition of all the observed CO2 bending mode profiles requires a minimum of five unique components. Roughly 2/3 of the CO2 ice is found in a water-rich environment, while most of the remaining 1/3 is found in a CO environment. Ground-based observations of solid CO toward a large subset of the c2d sample are used to further constrain the CO2:CO component and suggest a model in which low-density clouds form the CO2:H2O component and higher density clouds form the CO2:CO ice during and after the freeze-out of gas-phase CO. It is suggested that the subsequent evolution of the CO2 and CO profiles toward low-mass protostars, in particular the appearance of the splitting of the CO2 bending mode due to pure, crystalline CO2, is first caused by distillation of the CO2:CO component through evaporation of CO due to thermal processing to ~20-30 K in the inner regions of infalling envelopes. The formation of pure CO2 via segregation from the H2O rich mantle may contribute to the band splitting at higher levels of thermal processing (>50 K), but is harder to reconcile with the physical structure of protostellar envelopes around low-luminosity objects.

  2. Surface controls on the characteristics of natural CO2 seeps: implications for engineered CO2 stores

    E-Print Network [OSTI]

    Haszeldine, Stuart

    be characterized to design the most effective monitoring strategy. Key words: carbon capture and storage, carbon are considering adoption of carbon capture and storage technology to meet carbon emission reduction targets of Edinburgh, Edinburgh, UK ABSTRACT Long-term security of performance of engineered CO2 storage is a principle

  3. INTEGRATING MEA REGENERATION WITH CO2 COMPRESSION AND PEAKING TO REDUCE CO2 CAPTURE COSTS

    E-Print Network [OSTI]

    Rochelle, Gary T.

    by combining use of the heat integration configurations evaluated in this study and for the support and guidance of the DOE/NETL project manager, Jose D. Figueroa. Platte River Power Authority's insight on integrating a CO2 capture system into a full-scale power plant was also of great value

  4. Determination of the efficiency of a detector in gamma spectrometry of large-volume samples

    E-Print Network [OSTI]

    E. G. Tertyshnik; A. T. Korsakov

    2012-07-19

    The experimental - calculated method is proposed to determine the full energy peak efficiency (FEPE) of detectors {\\epsilon}(E) in case a measurement of the large-volume samples. Water is used as standard absorber in which the linear attenuation coefficients for photons {\\mu}0 (E) is well known. The value {\\mu} (E) in sample material (matrix of the sample) is determined experimentally by means of spectrometer. The formulas are given for calculation of the ratio {\\epsilon}(E)/ {\\epsilon}0(E), where {\\epsilon}0(E) is FEPE of the detector for photons those are arising in the container filled with water (it is found by adding in the container of the Reference radioactive solutions). To prove the validity of the method ethanol (density 0,8 g/cm3) and water solutions of salts (density 1,2 and 1,5 g/cm3) were used for simulation of the samples with different attenuation coefficients. Standard deviation between experimental and calculated efficiencies has been about 5 %.

  5. Plasma response to electron energy filter in large volume plasma device

    SciTech Connect (OSTI)

    Sanyasi, A. K.; Awasthi, L. M.; Mattoo, S. K.; Srivastava, P. K.; Singh, S. K.; Singh, R.; Kaw, P. K. [Institute for Plasma Research, Gandhinagar, 382 428 Gujarat (India)] [Institute for Plasma Research, Gandhinagar, 382 428 Gujarat (India)

    2013-12-15

    An electron energy filter (EEF) is embedded in the Large Volume Plasma Device plasma for carrying out studies on excitation of plasma turbulence by a gradient in electron temperature (ETG) described in the paper of Mattoo et al. [S. K. Mattoo et al., Phys. Rev. Lett. 108, 255007 (2012)]. In this paper, we report results on the response of the plasma to the EEF. It is shown that inhomogeneity in the magnetic field of the EEF switches on several physical phenomena resulting in plasma regions with different characteristics, including a plasma region free from energetic electrons, suitable for the study of ETG turbulence. Specifically, we report that localized structures of plasma density, potential, electron temperature, and plasma turbulence are excited in the EEF plasma. It is shown that structures of electron temperature and potential are created due to energy dependence of the electron transport in the filter region. On the other hand, although structure of plasma density has origin in the particle transport but two distinct steps of the density structure emerge from dominance of collisionality in the source-EEF region and of the Bohm diffusion in the EEF-target region. It is argued and experimental evidence is provided for existence of drift like flute Rayleigh-Taylor in the EEF plasma.

  6. Agricultural green revolution as a driver of increasing atmospheric CO2 seasonal amplitude

    SciTech Connect (OSTI)

    Zeng, Ning; Zhao, Fang; Collatz, George; Kalnay, Eugenia; Salawitch, Ross J.; West, Tristram O.; Guanter, Luis

    2014-11-20

    The atmospheric carbon dioxide (CO2) record displays a prominent seasonal cycle that arises mainly from changes in vegetation growth and the corresponding CO2 uptake during the boreal spring and summer growing seasons and CO2 release during the autumn and winter seasons. The CO2 seasonal amplitude has increased over the past five decades, suggesting an increase in Northern Hemisphere biospheric activity. It has been proposed that vegetation growth may have been stimulated by higher concentrations of CO2 as well as by warming in recent decades, but such mechanisms have been unable to explain the full range and magnitude of the observed increase in CO2 seasonal amplitude. Here we suggest that the intensification of agriculture (the Green Revolution, in which much greater crop yield per unit area was achieved by hybridization, irrigation and fertilization) during the past five decades is a driver of changes in the seasonal characteristics of the global carbon cycle. Our analysis of CO2 data and atmospheric inversions shows a robust 15 per cent long-term increase in CO2 seasonal amplitude from 1961 to 2010, punctuated by large decadal and interannual variations. Using a terrestrial carbon cycle model that takes into account high-yield cultivars, fertilizer use and irrigation, we find that the long-term increase in CO2 seasonal amplitude arises from two major regions: the mid-latitude cropland between 256N and 606N and the high-latitude natural vegetation between 506N and 706 N. The long-term trend of seasonal amplitude increase is 0.311 ± 0.027 percent per year, of which sensitivity experiments attribute 45, 29 and 26 per cent to land-use change, climate variability and change, and increased productivity due to CO2 fertilization, respectively. Vegetation growth was earlier by one to two weeks, as measured by the mid-point of vegetation carbon uptake, and took up 0.5 petagrams more carbon in July, the height of the growing season, during 2001–2010 than in 1961–1970, suggesting that human land use and management contribute to seasonal changes in the CO2 exchange between the biosphere and the atmosphere.

  7. A BIOMECHANICAL PERSPECTIVE ON THE ROLE OF LARGE STEM VOLUME AND HIGH WATER CONTENT IN BAOBAB TREES

    E-Print Network [OSTI]

    Holbrook, N. Michele

    A BIOMECHANICAL PERSPECTIVE ON THE ROLE OF LARGE STEM VOLUME AND HIGH WATER CONTENT IN BAOBAB TREES storage capacity in the six Madagascar baobab species. Baobab wood has a high water content (up to 79 to that in temperate deciduous trees. Furthermore, the elastic modulus of the wood decreases with water content

  8. Fusion of Metrology Data for Large-Scale High-Volume Manufacturing of Polymer-based Microfluidic Devices

    E-Print Network [OSTI]

    Fusion of Metrology Data for Large-Scale High-Volume Manufacturing of Polymer-based Microfluidic@mit.edu, youcef@mit.edu 2 Singapore Inst. of Manufacturing Technology; email: sgli@ntu.edu.sg, ivanr@SIMTech.a-star multiple data sets from disparate instru- ments. For example, fusion of data from different metrol- ogy

  9. Proceedings of the Combustion Institute, Volume 29, 2002/pp. 19711978 IMPROVED POLLUTANT PREDICTIONS IN LARGE-EDDY SIMULATIONS

    E-Print Network [OSTI]

    Pitsch, Heinz

    1971 Proceedings of the Combustion Institute, Volume 29, 2002/pp. 1971­1978 IMPROVED POLLUTANT PREDICTIONS IN LARGE-EDDY SIMULATIONS OF TURBULENT NON-PREMIXED COMBUSTION BY CONSIDERING SCALAR DISSIPATION-eddy simulation (LES) of turbulent combustion has become a subject of in- tensive research and modeling efforts

  10. SOLUBILITIES OF CO AND H2 IN NEAT AND CO2-EXPANDED HYDROFORMYLATION REACTION MIXTURES CONTAINING 1-OCTENE AND NONANAL UP TO 80 °C AND 90 BARS

    E-Print Network [OSTI]

    Xie, Zhuanzhuan

    2009-01-01

    Accurate knowledge of the phase equilibria of CO2-expanded hydroformylation reaction mixtures is essential to rational process design and development. Vapor liquid equilibria of the following systems were measured in a variable volume view cell...

  11. Sequestration of Dissolved CO2 in the Oriskany Formation

    SciTech Connect (OSTI)

    Dilmore, R.M.; Allen, D.E. (Salem State College, Salem, MA); McCarthy-Jones, J.R.; Hedges, S.W.; Soong, Yee

    2008-04-15

    Experiments were conducted to determine the solubility of CO2 in a natural brine solution of the Oriskany formation under elevated temperature and pressure conditions. These data were collected at temperatures of 22 and 75 °C and pressures between 100 and 450 bar. Experimentally determined data were compared with CO2 solubility predictions using a model developed by Duan and Sun (Chem. Geol. 2003, 193, 257-271). Model results compare well with Oriskany brine CO2 solubility data collected experimentally, suggesting that the Duan and Sun model is a reliable tool for estimating solution CO2 capacity in high salinity aquifers in the temperature and pressure range evaluated. The capacity for the Oriskany formation to sequester dissolved CO2 was calculated using results of the solubility models, estimation of the density of CO2 saturated brine, and available geographic information system (GIS) information on the formation depth and thickness. Results indicate that the Oriskany formation can hold approximately 0.36 gigatonnes of dissolved CO2 if the full basin is considered. When only the region where supercritical CO2 can exist (temperatures greater than 31° C and pressures greater than 74 bar) is considered, the capacity of the Oriskany formation to sequester dissolved CO2 is 0.31 gigatonnes. The capacity estimate considering the potential to sequester free-phase supercritical CO2 if brine were displaced from formation pore space is 8.8 gigatonnes in the Oriskany formation.

  12. Supersonic Technology for CO2 Capture: A High Efficiency Inertial CO2 Extraction System

    SciTech Connect (OSTI)

    2010-07-01

    IMPACCT Project: Researchers at ATK and ACENT Laboratories are developing a device that relies on aerospace wind-tunnel technologies to turn CO2 into a condensed solid for collection and capture. ATK’s design incorporates a special nozzle that converges and diverges to expand flue gas, thereby cooling it off and turning the CO2 into solid particles which are removed from the system by a cyclonic separator. This technology is mechanically simple, contains no moving parts and generates no chemical waste, making it inexpensive to construct and operate, readily scalable, and easily integrated into existing facilities. The increase in the cost to coal-fired power plants associated with introduction of this system would be 50% less than current technologies.

  13. Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2008-02-29

    There is growing interest regarding the potential size of a future U.S. dedicated CO2 pipeline infrastructure if carbon dioxide capture and storage (CCS) technologies are commercially deployed on a large scale. In trying to understand the potential scale of a future national CO2 pipeline network, comparisons are often made to the existing pipeline networks used to deliver natural gas and liquid hydrocarbons to markets within the U.S. This paper assesses the potential scale of the CO2 pipeline system needed under two hypothetical climate policies and compares this to the extant U.S. pipeline infrastructures used to deliver CO2 for enhanced oil recovery (EOR), and to move natural gas and liquid hydrocarbons from areas of production and importation to markets. The data presented here suggest that the need to increase the size of the existing dedicated CO2 pipeline system should not be seen as a significant obstacle for the commercial deployment of CCS technologies.

  14. Enhanced Geothermal Systems (EGS) comparing water with CO2 as heat transmission fluids

    E-Print Network [OSTI]

    Pruess, Karsten

    2007-01-01

    Interactions at the Supercritical CO2–liquid InterfaceEnergy Concept Utilizing Supercritical CO2 Instead of Water,Feasibility of Using Supercritical CO2 as Heat Transmission

  15. Optical Probing of CO2 Laser-Plasma Interactions at Near Critical Density

    E-Print Network [OSTI]

    Gong, Chao

    2015-01-01

    351. Tsung, F. , et al. , CO2 Laser acceleration of forwardJoshi, Fifteen terawatt picosecond CO2 laser system. Opticspicosecond, multiwavelength CO2 laser pulse. Applied Optics,

  16. SUBTASK 2.19 – OPERATIONAL FLEXIBILITY OF CO2 TRANSPORT AND STORAGE

    SciTech Connect (OSTI)

    Jensen, Melanie; Schlasner, Steven; Sorensen, James; Hamling, John

    2014-12-31

    Carbon dioxide (CO2) is produced in large quantities during electricity generation and by industrial processes. These CO2 streams vary in terms of both composition and mass flow rate, sometimes substantially. The impact of a varying CO2 stream on pipeline and storage operation is not fully understood in terms of either operability or infrastructure robustness. This study was performed to summarize basic background from the literature on the topic of operational flexibility of CO2 transport and storage, but the primary focus was on compiling real-world lessons learned about flexible operation of CO2 pipelines and storage from both large-scale field demonstrations and commercial operating experience. Modeling and pilot-scale results of research in this area were included to illustrate some of the questions that exist relative to operation of carbon capture and storage (CCS) projects with variable CO2 streams. It is hoped that this report’s real-world findings provide readers with useful information on the topic of transport and storage of variable CO2 streams. The real-world results were obtained from two sources. The first source consisted of five full-scale, commercial transport–storage projects: Sleipner, Snøhvit, In Salah, Weyburn, and Illinois Basin–Decatur. These scenarios were reviewed to determine the information that is available about CO2 stream variability/intermittency on these demonstration-scale projects. The five projects all experienced mass flow variability or an interruption in flow. In each case, pipeline and/or injection engineers were able to accommodate any issues that arose. Significant variability in composition has not been an issue at these five sites. The second source of real- world results was telephone interviews conducted with experts in CO2 pipeline transport, injection, and storage during which commercial anecdotal information was acquired to augment that found during the literature search of the five full-scale projects. The experts represented a range of disciplines and hailed from North America and Europe. Major findings of the study are that compression and transport of CO2 for enhanced oil recovery (EOR) purposes in the United States has shown that impurities are not likely to cause transport problems if CO2 stream composition standards are maintained and pressures are kept at 10.3 MPa or higher. Cyclic, or otherwise intermittent, CO2 supplies historically have not impacted in-field distribution pipeline networks, wellbore integrity, or reservoir conditions. The U.S. EOR industry has demonstrated that it is possible to adapt to variability and intermittency in CO2 supply through flexible operation of the pipeline and geologic storage facility. This CO2 transport and injection experience represents knowledge that can be applied in future CCS projects. A number of gaps in knowledge were identified that may benefit from future research and development, further enhancing the possibility for widespread application of CCS. This project was funded through the Energy & Environmental Research Center–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the IEA Greenhouse Gas R&D Programme.

  17. Spatial Disaggregation of CO2 Emissions for the State of California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; de la Rue du Can, Stephane; Wenzel, Tom; Fischer, Marc

    2008-06-11

    This report allocates California's 2004 statewide carbon dioxide (CO2) emissions from fuel combustion to the 58 counties in the state. The total emissions are allocated to counties using several different methods, based on the availability of data for each sector. Data on natural gas use in all sectors are available by county. Fuel consumption by power and combined heat and power generation plants is available for individual plants. Bottom-up models were used to distribute statewide fuel sales-based CO2 emissions by county for on-road vehicles, aircraft, and watercraft. All other sources of CO2 emissions were allocated to counties based on surrogates for activity. CO2 emissions by sector were estimated for each county, as well as for the South Coast Air Basin. It is important to note that emissions from some sources, notably electricity generation, were allocated to counties based on where the emissions were generated, rather than where the electricity was actually consumed. In addition, several sources of CO2 emissions, such as electricity generated in and imported from other states and international marine bunker fuels, were not included in the analysis. California Air Resource Board (CARB) does not include CO2 emissions from interstate and international air travel, in the official California greenhouse gas (GHG) inventory, so those emissions were allocated to counties for informational purposes only. Los Angeles County is responsible for by far the largest CO2 emissions from combustion in the state: 83 Million metric tonnes (Mt), or 24percent of total CO2 emissions in California, more than twice that of the next county (Kern, with 38 Mt, or 11percent of statewide emissions). The South Coast Air Basin accounts for 122 MtCO2, or 35percent of all emissions from fuel combustion in the state. The distribution of emissions by sector varies considerably by county, with on-road motor vehicles dominating most counties, but large stationary sources and rail travel dominating in other counties.The CO2 emissions data by county and source are available upon request.

  18. Capture and Sequestration of CO2 at the Boise White Paper Mill

    SciTech Connect (OSTI)

    B.P. McGrail; C.J. Freeman; G.H. Beeman; E.C. Sullivan; S.K. Wurstner; C.F. Brown; R.D. Garber; D. Tobin E.J. Steffensen; S. Reddy; J.P. Gilmartin

    2010-06-16

    This report documents the efforts taken to develop a preliminary design for the first commercial-scale CO2 capture and sequestration (CCS) project associated with biomass power integrated into a pulp and paper operation. The Boise Wallula paper mill is located near the township of Wallula in Southeastern Washington State. Infrastructure at the paper mill will be upgraded such that current steam needs and a significant portion of the current mill electric power are supplied from a 100% biomass power source. A new biomass power system will be constructed with an integrated amine-based CO2 capture plant to capture approximately 550,000 tons of CO2 per year for geologic sequestration. A customized version of Fluor Corporation’s Econamine Plus™ carbon capture technology will be designed to accommodate the specific chemical composition of exhaust gases from the biomass boiler. Due to the use of biomass for fuel, employing CCS technology represents a unique opportunity to generate a net negative carbon emissions footprint, which on an equivalent emissions reduction basis is 1.8X greater than from equivalent fossil fuel sources (SPATH and MANN, 2004). Furthermore, the proposed project will offset a significant amount of current natural gas use at the mill, equating to an additional 200,000 tons of avoided CO2 emissions. Hence, the total net emissions avoided through this project equates to 1,100,000 tons of CO2 per year. Successful execution of this project will provide a clear path forward for similar kinds of emissions reduction that can be replicated at other energy-intensive industrial facilities where the geology is suitable for sequestration. This project also represents a first opportunity for commercial development of geologic storage of CO2 in deep flood basalt formations. The Boise paper mill site is host to a Phase II pilot study being carried out under DOE’s Regional Carbon Partnership Program. Lessons learned from this pilot study and other separately funded projects studying CO2 sequestration in basalts will be heavily leveraged in developing a suitable site characterization program and system design for permanent sequestration of captured CO2. The areal extent, very large thickness, high permeability in portions of the flows, and presence of multiple very low permeability flow interior seals combine to produce a robust sequestration target. Moreover, basalt formations are quite reactive with water-rich supercritical CO2 and formation water that contains dissolved CO2 to generate carbonate minerals, providing for long-term assurance of permanent sequestration. Sub-basalt sediments also exist at the site providing alternative or supplemental storage capacity.

  19. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2005 Quarterly Progress. #12;3 Abstract The objective of this work is to improve the process for CO2 capture by alkanolamine from 0.06 to 0.01 mol/(m3 .s.kPa) as the rich loading increased from 0.45 to 0.6 mol CO2/ mol MEA

  20. Near Miscible CO2 Application to Improve Oil Recovery

    E-Print Network [OSTI]

    Bui, Ly H.

    2010-07-26

    control due to the reduction of oil viscosity. This suggested that application of carbon dioxide in the field would require injection and recycling of large volumes of carbon dioxide. Further study is needed to determine if such a process is economically...

  1. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01

    Efforts Investigating Water Extraction •! LLNL –! Active CObenefits of various water extraction, treatment, and reuseof CO 2 storage and water extraction scenarios –! Technical

  2. Gravity monitoring of CO2 movement during sequestration: Model studies

    E-Print Network [OSTI]

    Gasperikova, E.

    2008-01-01

    COAL MODEL Significant potential exists for carbon sequestration and enhanced methane recoverycoal zones within the Lower Pennsylvanian Pottsville Formation. Assessment of the CO 2 sequestration and enhanced recovery

  3. The geomechanics of CO2 storage in deep sedimentary formations

    E-Print Network [OSTI]

    Rutqvist, J.

    2013-01-01

    The geomechanics of CO 2 storage in deep sedimentaryThis paper provides a review of the geomechanics andmodeling of geomechanics associated with geologic carbon

  4. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01

    and performance of oil well cement with 30 years of CO 2cement –? Carbonation –? Sulfate attack –? Acid attack State of Alaska Oil and Gas Division Old Wells

  5. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    researchers have discovered that nanoparticles of cerium oxide (ceria) in contact with copper will form metal-oxide interfaces that allow the adsorption and activation of CO2,...

  6. North America's net terrestrial CO2 exchange with the atmosphere...

    Office of Scientific and Technical Information (OSTI)

    of the global carbon cycle is required for developing national and international policy to mitigate fossil fuel CO2 emissions by managing terrestrial carbon uptake. Toward...

  7. Advanced Post-Combustion CO2 Capture Prepared for the

    E-Print Network [OSTI]

    Advanced Post-Combustion CO2 Capture Prepared for the Clean Air Task Force under a grant from...................................................................................... 3 2. Current Status of Post-Combustion Capture

  8. Evaluating a new approach to CO2 capture and storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 capture and storage In a perspective paper published in Greenhouse Gases: Science and Technology, researchers examined a new approach that could potentially overcome many...

  9. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    by well/VSP (Vertical Seismic Profile) data. Fractures andat the Frio site, a vertical seismic profile ficult due towells VSP (vertical seismic profile) CO 2 distribution updip

  10. Enhanced Geothermal Systems (EGS) with CO2 as Heat Transmission...

    Open Energy Info (EERE)

    Enhanced Geothermal Systems (EGS) with CO2 as Heat Transmission Fluid Geothermal Lab Call Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Enhanced...

  11. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods Citation Details In-Document Search Title:...

  12. Direct s-CO2 Reciever Development | Department of Energy

    Office of Environmental Management (EM)

    Solar Receiver for Use in a Supercritical CO2 Recompression Cycle - FY13 Q1 High-Temperature Solar Thermoelectric Generators (STEG) Near-Blackbody Enclosed Particle Receiver...

  13. The geomechanics of CO2 storage in deep sedimentary formations

    E-Print Network [OSTI]

    Rutqvist, J.

    2013-01-01

    implications for CO 2 storage risk. Energy Procedia 4:3699–storage events and putting risk into perspective with other areas of the energy

  14. Volumetric Properties and Fluid Phase Equilibria of CO2 + H2O

    SciTech Connect (OSTI)

    Capobianco, Ryan [Virginia Polytechnic Institute and State University; Gruszkiewicz, Miroslaw {Mirek} S [ORNL; Wesolowski, David J [ORNL; Cole, David R [ORNL; Bodnar, Robert [Virginia Polytechnic Institute and State University

    2013-01-01

    The need for accurate modeling of fluid-mineral processes over wide ranges of temperature, pressure and composition highlighted considerable uncertainties of available property data and equations of state, even for the CO2 + H2O binary system. In particular, the solubility, activity, and ionic dissociation equilibrium data for the CO2-rich phase, which are essential for understanding dissolution/precipitation, fluid-matrix reactions, and solute transport, are uncertain or missing. In this paper we report the results of a new experimental study of volumetric and phase equilibrium properties of CO2 + H2O, to be followed by measurements for bulk and confined multicomponent fluid mixtures. Mixture densities were measured by vibrating tube densimetry (VTD) over the entire composition range at T = 200 and 250 C and P = 20, 40, 60, and 80 MPa. Initial analysis of the mutual solubilities, determined from volumetric data, shows good agreement with earlier results for the aqueous phase, but finds that the data of Takenouchi and Kennedy (1964) significantly overestimated the solubility of water in supercritical CO2 (by a factor of more than two at 200 C). Resolving this well-known discrepancy will have a direct impact on the accuracy of predictive modeling of CO2 injection in geothermal reservoirs and geological carbon sequestration through improved equations of state, needed for calibration of predictive molecular-scale models and large-scale reactive transport simulations.

  15. Metal Organic Framework Research: High Throughput Discovery of Robust Metal Organic Framework for CO2 Capture

    SciTech Connect (OSTI)

    None

    2010-08-01

    IMPACCT Project: LBNL is developing a method for identifying the best metal organic frameworks for use in capturing CO2 from the flue gas of coal-fired power plants. Metal organic frameworks are porous, crystalline compounds that, based on their chemical structure, vary considerably in terms of their capacity to grab hold of passing CO2 molecules and their ability to withstand the harsh conditions found in the gas exhaust of coal-fired power plants. Owing primarily to their high tunability, metal organic frameworks can have an incredibly wide range of different chemical and physical properties, so identifying the best to use for CO2 capture and storage can be a difficult task. LBNL uses high-throughput instrumentation to analyze nearly 100 materials at a time, screening them for the characteristics that optimize their ability to selectively adsorb CO2 from coal exhaust. Their work will identify the most promising frameworks and accelerate their large-scale commercial development to benefit further research into reducing the cost of CO2 capture and storage.

  16. CO2-Binding Organic Liquids, an Integrated Acid Gas Capture System

    SciTech Connect (OSTI)

    Heldebrant, David J.; Koech, Phillip K.; Rainbolt, James E.; Zheng, Feng

    2011-04-01

    Amine systems are effective for CO2 capture, but they are still inefficient because the solvent regeneration energy is largely defined by the amount of water in the process. Most amines form heat-stable salts with SO2 and COS resulting in parasitic solvent loss and degradation. Stripping the CO2-rich solvent is energy intensive it requires temperatures above 100 ?C due to the high specific heat and heat of vaporization of water. CO2-capture processes could be much more energy efficient in a water free amine process. In addition, if the capture-material is chemically compatible with other acid gases, less solvent would be lost to heat-stable salts and the process economics would be further improved. One such system that can address these concerns is Binding Organic Liquids (BOLs), a class of switchable ionic liquids.

  17. Final Progress Report: Direct Experiments on the Ocean Disposal of Fossil Fuel CO2.

    SciTech Connect (OSTI)

    James P. Barry; Peter G. Brewer

    2004-05-25

    OAK-B135 This report summarizes activities and results of investigations of the potential environmental consequences of direct injection of carbon dioxide into the deep-sea as a carbon sequestration method. Results of field experiments using small scale in situ releases of liquid CO2 are described in detail. The major conclusions of these experiments are that mortality rates of deep sea biota will vary depending on the concentrations of CO2 in deep ocean waters that result from a carbon sequestration project. Large changes in seawater acidity and carbon dioxide content near CO2 release sites will likely cause significant harm to deep-sea marine life. Smaller changes in seawater chemistry at greater distances from release sites will be less harmful, but may result in significant ecosystem changes.

  18. Jumpstarting commercial-scale CO2 capture and storage with ethylene production and enhanced oil recovery in the US Gulf

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Middleton, Richard S.; Levine, Jonathan S.; Bielicki, Jeffrey M.; Viswanathan, Hari S.; Carey, J. William; Stauffer, Philip H.

    2015-04-27

    CO2 capture, utilization, and storage (CCUS) technology has yet to be widely deployed at a commercial scale despite multiple high-profile demonstration projects. We suggest that developing a large-scale, visible, and financially viable CCUS network could potentially overcome many barriers to deployment and jumpstart commercial-scale CCUS. To date, substantial effort has focused on technology development to reduce the costs of CO2 capture from coal-fired power plants. Here, we propose that near-term investment could focus on implementing CO2 capture on facilities that produce high-value chemicals/products. These facilities can absorb the expected impact of the marginal increase in the cost of production onmore »the price of their product, due to the addition of CO2 capture, more than coal-fired power plants. A financially viable demonstration of a large-scale CCUS network requires offsetting the costs of CO2 capture by using the CO2 as an input to the production of market-viable products. As a result, we demonstrate this alternative development path with the example of an integrated CCUS system where CO2 is captured from ethylene producers and used for enhanced oil recovery in the U.S. Gulf Coast region.« less

  19. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    is the largest source of NEU-CO2 emissions (233 Mt CO 2 ),black (another key source of NEU-CO2 emissions reported bysource and geographical distributions of NEU-CO2 emissions.

  20. Solid molecular basket sorbent for CO2 capture from gas streams with low CO2 concentration at ambient conditions

    SciTech Connect (OSTI)

    Wang, Xiaoxing [Pennsylvania State University; Ma, Xiaoliang [Pennsylvania State University; Schwartz, Viviane [ORNL; Clark, Jason C [ORNL; Overbury, Steven {Steve} H [ORNL; Zhao, Shuqi [Pennsylvania State University, University Park, PA; Xu, Xiaochun [Pennsylvania State University; Song, Chunshan [Pennsylvania State University

    2012-01-01

    In this paper, a solid molecular basket sorbent, 50 wt% PEI/SBA-15 was studied for CO2 capture from gas streams with low CO2 concentration at ambient conditions. The sorbent was able to effectively and selectively capture CO2 from a gas stream containing 1% CO2 at 75 C, with a breakthrough and saturation capacity of 63.1 and 66.7 mg/g, respectively, and a selectivity of 14 for CO2/CO and 185 for CO2/Ar. The sorption performance of the sorbent was influenced greatly by the operating temperature. The CO2-TPD study showed that the sorbent could be regenerated at mild conditions (50-110 C) and was stable in the cyclical operations for at least 20 cycles. Furthermore, the possibility for CO2 capture from air using the PEI/SBA-15 sorbent was studied by FTIR and proved by TPD. A capacity of 22.5 mg/g was attained at 75 C via TPD method using a simulated air with 400 ppmv CO2 in N2.

  1. Leakage and Sepage of CO2 from Geologic Carbon Sequestration Sites: CO2 Migration into Surface Water

    E-Print Network [OSTI]

    Oldenburg, Curt M.; Lewicki, Jennifer L.

    2005-01-01

    from geologic carbon sequestration sites: unsaturated zoneCO 2 from Geologic Carbon Sequestration Sites, Vadose Zoneseepage from geologic carbon sequestration sites may occur.

  2. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLED Street Lighting Host Site: City ofNovel CO 2

  3. Version 3.0 SOP 5 --Underway p(CO2) October 12, 2007 Determination of p(CO2) in air that is in

    E-Print Network [OSTI]

    as the product of the mole fraction of CO2, x(CO2), in the equilibrated gas phase and the total pressure (p . The analyzer is calibrated using gases of known CO2 concentration (mole fraction). The partial pressure, p(CO2 in sea water, it is necessary to convert the mole fraction to fugacity, (CO2), to account for the fact

  4. Greener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from the flue gases of coal-fired power plants would alleviate concerns

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    to remove CO2 from dilute gas streams because they have very high affinity for CO2. Unfortunately high solvents that balance high affinity for CO2 with ease of solvent recovery and reuse. Because the numberGreener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from

  5. Single photon ionization of van der Waals clusters with a soft x-ray laser: ,,CO2...n and ,,CO2...n,,H2O...m

    E-Print Network [OSTI]

    Rocca, Jorge J.

    Single photon ionization of van der Waals clusters with a soft x-ray laser: ,,CO2...n and ,,CO2...n 2006; published online 20 October 2006 Pure neutral CO2 n clusters and mixed CO2 n H2O m clustersV. The distribution of pure CO2 n clusters decreases roughly exponentially with increasing cluster size. During

  6. Quantifying Regional Economic Impacts of CO2 Intensity Targets in China

    E-Print Network [OSTI]

    Zhang, Da

    2012-09-01

    To address rising energy use and CO2 emissions, China’s leadership has enacted energy and CO2 intensity

  7. Mathematical models as tools for probing long-term safety of CO2 storage

    E-Print Network [OSTI]

    Pruess, Karsten

    2010-01-01

    Interactions at the Supercritical CO2–liquid InterfaceProperties of the Supercritical CO2–Water Pure Interface, J.

  8. Numerical investigation for the impact of CO2 geologic sequestration on regional groundwater flow

    E-Print Network [OSTI]

    Yamamoto, H.

    2010-01-01

    displaces. In situ, the supercritical CO2 partitions betweenprocess, CO2 is injected in a supercritical state that has a

  9. Intercomparison of simulation models for CO2 disposal in underground storage reservoirs

    E-Print Network [OSTI]

    Pruess, Karsten; Tsang, Chin-Fu; Law, David; Oldenburg, Curt

    2001-01-01

    experience with using CO2 for EOR projects (SPE, 1999), andoil recovery (EOR) using CO2 requires an understanding of

  10. CO2 Sequestration Modeling Using Pattern Recognition and Data Mining;

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    . In order to perform a safe and efficient carbon dioxide capture and storage (CCS) project, a comprehensive. Carbon dioxide capture and storage (CCS) is a process including the capture of CO2 from high production, USA Abstract Capturing carbon dioxide (CO2) from industrial and energy-related sources and depositing

  11. Influence of C4 vegetation on 13 CO2 discrimination

    E-Print Network [OSTI]

    Minnesota, University of

    Influence of C4 vegetation on 13 CO2 discrimination and isoforcing in the upper Midwest, United vegetation on the 13 CO2 photosynthetic discrimination and atmospheric isotopic forcing in the upper Midwest discrimination within this heterogeneous landscape? (3) To what extent does land use change (i.e., a change in C4

  12. CO2 Injection in the Subsurface Kjetil Haugen

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    (1015 BTU) Year Oil Coal Gas Hydro Nuclear Other Figure 1: World energy consumption by energy type. Thus, replacing oil and coal with less carbon-intensive natural gas, is probably the fastest way of achieving a significant reduction in CO2 emissions. CO2 Capture Natural gas is the most clean burning fossil

  13. Variations in 13 C discrimination during CO2 exchange1

    E-Print Network [OSTI]

    exchange. Observed 13 were described well by the classical model of5 Farquhar, O'Leary & Berry (1982 enzymes, as well as to differential diffusivities of 13 CO2 and 12 CO2 in air9 (O'Leary, 1984; Farquhar, O'Leary

  14. Consumption-based accounting of CO2 emissions

    E-Print Network [OSTI]

    Davis, S. J; Caldeira, K.

    2010-01-01

    gross world product, E is global energy consumption, Authorglobal consumption-based CO 2 emissions inventory and calcula- tions of associated consumption-based energyenergy consumption, and combustion-based CO 2 emissions of each region sector were all taken from Version 7 of the Global

  15. Comprehensive Monitoring of CO2 Sequestration in Subalpine Forest Ecosystems

    E-Print Network [OSTI]

    Han, Richard Y.

    , carbon sequestration, ecosystem, multi-tier, multi-modal, multi-scale, self organized, sensor array to comprehensively monitor ecosystem carbon sequestration. The network consists of CO2, Weather (pressureComprehensive Monitoring of CO2 Sequestration in Subalpine Forest Ecosystems and Its Relation

  16. The Energy and CO2 Emissions Impact of

    E-Print Network [OSTI]

    The Energy and CO2 Emissions Impact of Renewable Energy Development in China Xiliang Zhang, Tianyu://globalchange.mit.edu/ Printed on recycled paper #12;1 The Energy and CO2 Emissions Impact of Renewable Energy Development Qi, and Valerie J. Karplus Report No. 242 April 2013 China Energy & Climate Project TSINGHUA - MIT

  17. Distribution of anthropogenic CO2 in the Pacific Ocean

    E-Print Network [OSTI]

    Distribution of anthropogenic CO2 in the Pacific Ocean C. L. Sabine,1 R. A. Feely,2 R. M. Key,3 J] This work presents an estimate of anthropogenic CO2 in the Pacific Ocean based on measurements from the WOCE tracers; 9355 Information Related to Geographic Region: Pacific Ocean; KEYWORDS: Pacific Ocean

  18. CO2 Emissions Mitigation and Technological Advance: An

    E-Print Network [OSTI]

    PNNL-18075 CO2 Emissions Mitigation and Technological Advance: An Updated Analysis of Advanced/2003) #12;PNNL-18075 CO2 Emissions Mitigation and Technological Advance: An Analysis of Advanced Technology, by itself, the scope or quantity of greenhouse gas emissions reductions needed to achiev

  19. Estimating the supply and demand for deep geologic CO2 storage capacity over the course of the 21st Century: A meta-analysis of the literature

    SciTech Connect (OSTI)

    Dooley, James J.

    2013-08-05

    Whether there is sufficient geologic CO2 storage capacity to allow CCS to play a significant role in mitigating climate change has been the subject of debate since the 1990s. This paper presents a meta- analysis of a large body of recently published literature to derive updated estimates of the global deep geologic storage resource as well as the potential demand for this geologic CO2 storage resource over the course of this century. This analysis reveals that, for greenhouse gas emissions mitigation scenarios that have end-of-century atmospheric CO2 concentrations of between 350 ppmv and 725 ppmv, the average demand for deep geologic CO2 storage over the course of this century is between 410 GtCO2 and 1,670 GtCO2. The literature summarized here suggests that -- depending on the stringency of criteria applied to calculate storage capacity – global geologic CO2 storage capacity could be: 35,300 GtCO2 of “theoretical” capacity; 13,500 GtCO2 of “effective” capacity; 3,900 GtCO2, of “practical” capacity; and 290 GtCO2 of “matched” capacity for the few regions where this narrow definition of capacity has been calculated. The cumulative demand for geologic CO2 storage is likely quite small compared to global estimates of the deep geologic CO2 storage capacity, and therefore, a “lack” of deep geologic CO2 storage capacity is unlikely to be an impediment for the commercial adoption of CCS technologies in this century.

  20. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration

    SciTech Connect (OSTI)

    Zuo, Lin; Benson, Sally M.

    2013-01-01

    A novel EOR method using carbonated water injection followed by depressurization is introduced. Results from micromodel experiments are presented to demonstrate the fundamental principles of this oil recovery method. A depressurization process (1 MPa/hr) was applied to a micromodel following carbonated water injection (Ca ? 10-5). The exsolved CO2 in water-filled pores blocked water flow in swiped portions and displaced water into oil-filled pores. Trapped oil after the carbonated water injection was mobilized by sequentially invading water. This method's self-distributed mobility control and local clogging was tested in a sandstone sample under reservoir conditions. A 10% incremental oil recovery was achieved by lowering the pressure 2 MPa below the CO2 liberation pressure. Additionally, exsolved CO2 resides in the pores of a reservoir as an immobile phase with a high residual saturation after oil production, exhibiting a potential synergy opportunity between CO2 EOR and CO2 sequestration

  1. Transfer Function Based Adaptive Decompression for Volume Rendering of Large Medical Data Sets

    E-Print Network [OSTI]

    performance limitations in direct volume rendering pipelines. The methods presented in this paper exploit the medical knowledge embedded in the transfer function to reduce the required bandwidth in the pipeline be developed, replacing invasive methods with non-invasive methods to minimize patient risk and discomfort

  2. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Supercritical CO 2 as Heat Transmission Fluid in the EGSof Using Supercritical CO2 as Heat Transmission Fluid in anEGS) with CO 2 as Heat Transmission Fluid - A Scheme for

  3. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Could Sequestration of CO2 be Combined with the DevelopmentTOUGH2 Code for Studies of CO2 Storage in Saline Aquifers,and J. Ennis- King. CO2-H2O Mixtures in the Geological

  4. Odors that Modify CO2 Receptor Activity in Insects and Their Effect on Innate CO2-Mediated Behavior and Neuronal Plasticity

    E-Print Network [OSTI]

    Turner, Stephanie

    2010-01-01

    Intermediates in Insect CO2 Sensory Systems. Science Certel,2007). The molecular basis of CO2 reception in Drosophila.J. (2004). Floral CO2 Reveals Flower Profitability to Moths.

  5. "Target CO2" publication, "Obstruction" clarification, Paterson letter 1. "Target Atmospheric CO2: Where Should Humanity Aim?" will appear in 3-4 days in The

    E-Print Network [OSTI]

    Hansen, James E.

    "Target CO2" publication, "Obstruction" clarification, Paterson letter 1. "Target Atmospheric CO2 the Australian position, but their subsequently stated goals of 450-550 ppm CO2 does. That plan appears to have

  6. CO2 diffusion in polar ice: observations from naturally formed CO2 spikes in the Siple Dome (Antarctica) ice core

    E-Print Network [OSTI]

    Raggio Parkway, Reno, Nevada 89512-1095, USA ABSTRACT. One common assumption in interpreting ice-core CO2 records is that diffusion in the ice does not affect the concentration profile. However, this assumption/Ar and Kr/Ar), electrical conductivity and Ca2+ ion concentrations to show that substantial CO2 diffusion

  7. CO2 Capture with Liquid-to-Solid Absorbents: CO2 Capture Process Using Phase-Changing Absorbents

    SciTech Connect (OSTI)

    2010-10-01

    IMPACCT Project: GE and the University of Pittsburgh are developing a unique CO2 capture process in which a liquid absorbent, upon contact with CO2, changes into a solid phase. Once in solid form, the material can be separated and the CO2 can be released for storage by heating. Upon heating, the absorbent returns to its liquid form, where it can be reused to capture more CO2. The approach is more efficient than other solventbased processes because it avoids the heating of extraneous solvents such as water. This ultimately leads to a lower cost of CO2 capture and will lower the additional cost to produce electricity for coal-fired power plants that retrofit their facilities to include this technology.

  8. Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. Based on a range of well schemes, techno-economic analyses of the levelized cost of electricity (LCOE) are conducted to determine the economic benefits of integrating GCS with geothermal energy production. In addition to considering CO2 injection, reservoir analyses are conducted for nitrogen (N2) injection to investigate the potential benefits of incorporating N2 injection with integrated geothermal-GCS, as well as the use of N2 injection as a potential pressure-support and working-fluid option. Phase 1 includes preliminary environmental risk assessments of integrated geothermal-GCS, with the focus on managing reservoir overpressure. Phase 1 also includes an economic survey of pipeline costs, which will be applied in Phase 2 to the analysis of CO2 conveyance costs for techno-economics analyses of integrated geothermal-GCS reservoir sites. Phase 1 also includes a geospatial GIS survey of potential integrated geothermal-GCS reservoir sites, which will be used in Phase 2 to conduct sweet-spot analyses that determine where promising geothermal resources are co-located in sedimentary settings conducive to safe CO2 storage, as well as being in adequate proximity to large stationary CO2 sources.

  9. Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Buscheck, Thomas A.

    2012-01-01

    The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. Based on a range of well schemes, techno-economic analyses of the levelized cost of electricity (LCOE) are conducted to determine the economic benefits of integrating GCS with geothermal energy production. In addition to considering CO2 injection, reservoir analyses are conducted for nitrogen (N2) injection to investigate the potential benefits of incorporating N2 injection with integrated geothermal-GCS, as well as the use of N2 injection as a potential pressure-support and working-fluid option. Phase 1 includes preliminary environmental risk assessments of integrated geothermal-GCS, with the focus on managing reservoir overpressure. Phase 1 also includes an economic survey of pipeline costs, which will be applied in Phase 2 to the analysis of CO2 conveyance costs for techno-economics analyses of integrated geothermal-GCS reservoir sites. Phase 1 also includes a geospatial GIS survey of potential integrated geothermal-GCS reservoir sites, which will be used in Phase 2 to conduct sweet-spot analyses that determine where promising geothermal resources are co-located in sedimentary settings conducive to safe CO2 storage, as well as being in adequate proximity to large stationary CO2 sources.

  10. New Magnetic confirguration in paramagnetic phase of HoCo2

    SciTech Connect (OSTI)

    Bonilla, C.M.; Calvo, I.; Herrero-Albillos, J.; Figueroa, A.I.; Castan-Guerrero, C.; Bertolome, J.; Rodriguez-Velamazan, J.A.; Schmitz, D.; Weschke, E.; Paudyal, Durga; Pecharsky, Vitalij; Gschneidner Jr, Karl; Bartolome, F.; Garcia, D.

    2012-02-23

    X-ray magnetic circular dichroism (XMCD) measurements on HoCo2 reveal the inversion of Co moment at temperatures higher than the critical temperature, Tc, showing that the net magnetization under a field of the Ho and Co sublattices remain antiparallel even above Tc. The Ho moment also changes its orientation to align antiparallel to the applied field at high temperature giving rise to a new magnetic configuration in the paramagnetic regime. Transverse susceptibility (TS) and small angle neutron scattering (SANS) measurements performed above Tc indicate the existence of sizable magnetic short-range correlated regions in HoCo2. First principles calculations based on spin polarized local-density approximation, LSDA+U havebeen performed to obtain insights on the origin of the short-range correlated volume.

  11. Methanogenic Conversion of CO2 Into CH4

    SciTech Connect (OSTI)

    Stevens, S.H., Ferry, J.G., Schoell, M.

    2012-05-06

    This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

  12. Evaluating the Suitability for CO2 Storage at the FutureGen 2.0 Site, Morgan County, Illinois, USA

    SciTech Connect (OSTI)

    Bonneville, Alain; Gilmore, Tyler J.; Sullivan, E. C.; Vermeul, Vincent R.; Kelley, Mark E.; White, Signe K.; Appriou, Delphine; Bjornstad, Bruce N.; Gerst, Jacqueline L.; Gupta, Neeraj; Horner, Jacob A.; McNeil, Caitlin; Moody, Mark A.; Rike, William M.; Spane, Frank A.; Thorne, Paul D.; Zeller, Evan R.; Zhang, Z. F.; Hoffman, Jeffrey; Humphreys, Kenneth K.

    2013-08-05

    FutureGen 2.0 site will be the first near-zero emission power plant with fully integrated long-term storage in a deep, non-potable saline aquifer in the United States. The proposed FutureGen 2.0 CO2 storage site is located in northeast Morgan County, Illinois, U.S.A., forty-eight kilometres from the Meredosia Energy Center where a large-scale oxy-combustion demonstration will be conducted. The demonstration will involve > 90% carbon capture, which will produce more than one million metric tons (MMT) of CO2 per year. The CO2 will be compressed at the power plant and transported via pipeline to the storage site. To examine CO2 storage potential of the site, a 1,467m characterization well (FGA#1) was completed in December 2011. The target reservoir for CO2 storage is the Mt. Simon Sandstone and Elmhurst Sandstone Member of the lower Eau Claire Formation for a combined thickness of 176 m. Confining beds of the overlying Lombard and Proviso Members (upper Eau Claire Formation) reach a thickness of 126 m. Characterization of the target injection zone and the overlying confining zone was based on wellbore data, cores, and geophysical logs, along with surface geophysical (2-D seismic profiles, magnetic and gravity), and structural data collected during the initial stage of the project . Based on this geological model, 3D simulations of CO2 injection and redistribution were conducted using STOMP-CO2, a multiphase flow and transport simulator. After this characterization stage, it appears that the injection site is a suitable geologic system for CO2 sequestration and that the injection zone is sufficient to receive up to 33 MMT of CO2 at a rate of 1.1 MMT/yr. GHGT-11 conference

  13. Comparing Existing Pipeline Networks with the Potential Scale of Future U.S. CO2 Pipeline Networks

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-04-20

    There is growing interest regarding the potential size of a future U.S. dedicated carbon dioxide (CO2) pipeline infrastructure if carbon dioxide capture and storage (CCS) technologies are commercially deployed on a large scale within the United States. This paper assesses the potential scale of the CO2 pipeline system needed under two hypothetical climate policies (so called WRE450 and WRE550 stabilization scenarios) and compares this to the extant U.S. pipeline infrastructures used to deliver CO2 for enhanced oil recovery (EOR), and to move natural gas and liquid hydrocarbons from areas of production and importation to markets. The analysis reveals that between 11,000 and 23,000 additional miles of dedicated CO2 pipeline might be needed in the U.S. before 2050 across these two cases. While that is a significant increase over the 3,900 miles that comprise the existing national CO2 pipeline infrastructure, it is critically important to realize that the demand for additional CO2 pipeline capacity will unfold relatively slowly and in a geographically dispersed manner as new dedicated CCS-enabled power plants and industrial facilities are brought online. During the period 2010-2030, the growth in the CO2 pipeline system is on the order of a few hundred to less than a thousand miles per year. In comparison during the period 1950-2000, the U.S. natural gas pipeline distribution system grew at rates that far exceed these projections in growth in a future dedicated CO2 pipeline system. This analysis indicates that the need to increase the size of the existing dedicated CO2 pipeline system should not be seen as a major obstacle for the commercial deployment of CCS technologies in the U.S. Nevertheless, there will undoubtedly be some associated regulatory and siting issues to work through but these issues should not be unmanageable based on the size of infrastructure requirements alone.

  14. Predicting long-term carbon sequestration in response to CO2 enrichment: How and why do current ecosystem models differ?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Walker, Anthony P.; Zaehle, Sönke; Medlyn, Belinda E.; De Kauwe, Martin G.; Asao, Shinichi; Hickler, Thomas; Parton, William; Ricciuto, Daniel M.; Wang, Ying -Ping; Wårlind, David; et al

    2015-04-27

    Large uncertainty exists in model projections of the land carbon (C) sink response to increasing atmospheric CO2. Free-Air CO2 Enrichment (FACE) experiments lasting a decade or more have investigated ecosystem responses to a step change in atmospheric CO2 concentration. To interpret FACE results in the context of gradual increases in atmospheric CO2 over decades to centuries, we used a suite of seven models to simulate the Duke and Oak Ridge FACE experiments extended for 300 years of CO2 enrichment. We also determine key modeling assumptions that drive divergent projections of terrestrial C uptake and evaluate whether these assumptions can bemore »constrained by experimental evidence. All models simulated increased terrestrial C pools resulting from CO2 enrichment, though there was substantial variability in quasi-equilibrium C sequestration and rates of change. In two of two models that assume that plant nitrogen (N) uptake is solely a function of soil N supply, the net primary production response to elevated CO2 became progressively N limited. In four of five models that assume that N uptake is a function of both soil N supply and plant N demand, elevated CO2 led to reduced ecosystem N losses and thus progressively relaxed nitrogen limitation. Many allocation assumptions resulted in increased wood allocation relative to leaves and roots which reduced the vegetation turnover rate and increased C sequestration. Additionally, self-thinning assumptions had a substantial impact on C sequestration in two models. As a result, accurate representation of N process dynamics (in particular N uptake), allocation, and forest self-thinning is key to minimizing uncertainty in projections of future C sequestration in response to elevated atmospheric CO2.« less

  15. Analysis of the kinetic slowing down during carbonation of CaO by CO2 Lydie Rouchon, Loc Favergeon, Michle Pijolat

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ,5], chemical heat pump [6-9], energy's storage [10-11], reaction integrated gasification process for H2 cause of climate change [1]. So, decrease of CO2 emitted by large industrial combustion sources or power at an industrial scale [3]. CaO (s) + CO2 (g) CaCO3 (s) (R1) This carbonation reaction has been studied from

  16. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    clean sources of energy. Asturias, in northern Spain, is theThe CO 2 emissions in Asturias represent the 8% of total COsequestration in Asturias are deep saline aquifers and

  17. Gravity monitoring of CO2 movement during sequestration: Model studies

    E-Print Network [OSTI]

    Gasperikova, E.

    2008-01-01

    right. Figure 14: Surface gravity response (?Gal) for theAbsolute and relative gravity integration for high precision2003, Seafloor Micro-gravity Survey of the Sleipner CO 2

  18. Modeling the release of CO2 in the deep ocean

    E-Print Network [OSTI]

    Liro, Christopher R.

    1991-01-01

    The idea of capturing and disposing of carbon dioxide (CO2) from the flue gas of fossil fuel-fired power plants has recently received attention as a possible mitigation strategy to counteract potential global warming due ...

  19. DOE Manual Studies 11 Major CO2 Geologic Storage Formations

    Broader source: Energy.gov [DOE]

    A comprehensive study of 11 geologic formations suitable for permanent underground carbon dioxide (CO2) storage is contained in a new manual issued by the U.S. Department of Energy.

  20. Novel CO2-Thickeners for Improved Mobility Control

    SciTech Connect (OSTI)

    Enick, Dr. Robert M.; Beckman, Dr. Eric J.; Hamilton, Dr. Andrew

    2002-01-15

    The objective of this contract was to design, synthesize, and characterize thickening agents for dense carbon dioxide and to evaluate their solubility and viscosity-enhancing potential in CO2.

  1. Bees, Balloons, Pollen Used as Novel CO2 Monitoring Approach

    Broader source: Energy.gov [DOE]

    Researchers at the Office of Fossil Energy's National Energy Technology Laboratory have discovered an innovative way to use bees, pollen, and helium-filled balloons to verify that no carbon dioxide (CO2) leaks from carbon sequestration sites.

  2. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    90 times faster than catalysts commonly used for this reaction today. What to Do with CO2? Recently, the United States and China announced a joint agreement setting targets for...

  3. Secretary Moniz Announces New CO2 Storage Network at Multinational...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    collaboration builds on the success of the CO2 Capture Test Center Network, chaired by Norway since 2013. The U.S. will take the lead on the capture center initiative next year. At...

  4. System-level modeling for geological storage of CO2

    E-Print Network [OSTI]

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01

    reservoir, a natural gas power plant that burns CH 4 , CO 2from the natural gas power plant, there are two otherflue gas of the natural gas power plant in the system. When

  5. EGS rock reactions with Supercritical CO2 saturated with water...

    Office of Scientific and Technical Information (OSTI)

    CO2 as a working fluid. less Authors: Earl D. Mattson ; Travis L. McLing ; William Smith ; Carl Palmer Publication Date: 2013-02-01 OSTI Identifier: 1076541 Report Number(s):...

  6. Alabama Project Testing Potential for Combining CO2 Storage with...

    Broader source: Energy.gov (indexed) [DOE]

    to sequester 1.1 gigatons to 2.3 gigatons of CO2--approximately the amount that Alabama's coal-fired power plants emit in two decades. Enhanced coalbed methane recovery combined...

  7. CO2ReMoVe - Progress Report

    E-Print Network [OSTI]

    Danilo R. Velis

    of CO2 and brine or oil at liquid, supercritical and gaseous conditions, using a Biot-Gassmann ...... micro-heterogeneous water saturation field S. (j) w . We obtain ...

  8. Seismic modeling to monitor CO2 geological storage: The Atzbach ...

    E-Print Network [OSTI]

    2012-05-30

    Jun 8, 2012 ... When CO2 is stored into depleted oil and gas fields or unmineable .... where rb is the water (brine) density and g is the acceleration of gravity.

  9. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    the arrival of CO 2 . The drilling fluids were tagged withSeismic survey Drilling phase Fluid loss record, PWD Leak-as fluid path should be investigated during drilling phase.

  10. Canada’s Bitumen Industry Under CO2 Constraints

    E-Print Network [OSTI]

    Chen, Y.-H. Henry

    We investigate the effects of implementing CO2 emissions reduction policies on Canada’s oil sands industry, the largest of its kind in the world. The production of petroleum products from oils sands involves extraction of ...

  11. Thermodynamic and kinetic analyses of the CO2 chemisorption mechanism...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Thermodynamic and kinetic analyses of the CO2 chemisorption mechanism on Na2TiO3: Experimental and theoretical evidences Citation Details In-Document Search Title:...

  12. Electronic Structure, Phonon Dynamical Properties, and CO2 Capture...

    Office of Scientific and Technical Information (OSTI)

    Electronic Structure, Phonon Dynamical Properties, and CO2 Capture Capability of Na2-xMxZrO3 ( MLi ,K): Density-Functional Calculations and Experimental Validations Citation...

  13. Electronic Structure, Phonon Dynamical Properties, and CO2 Capture...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Electronic Structure, Phonon Dynamical Properties, and CO2 Capture Capability of Na2-xMxZrO3 ( MLi ,K): Density-Functional Calculations and Experimental...

  14. Improving CO2 Efficiency for Recovering Oil in Heterogeneous Reservoirs

    SciTech Connect (OSTI)

    Grigg, Reid B.; Svec, Robert K.

    2003-03-10

    The work strived to improve industry understanding of CO2 flooding mechanisms with the ultimate goal of economically recovering more of the U.S. oil reserves. The principle interests are in the related fields of mobility control and injectivity.

  15. Conference on Physics with Large Gamma-Ray Detector Arrays, Volume II Proceedings

    E-Print Network [OSTI]

    Lawler editor, G.

    2010-01-01

    CONFERENCE ON PHYSICS FROM LARGE Y-RRV DETECTOR HRRRVS ClarkHa.gema.nn, lecture at this conference [4] G . Baldsiefen etHiïbel, lecture at this conference [7] R. M . Clark, lecture

  16. CO2 Removal using a Synthetic Analogue of Carbonic Anhydrase

    SciTech Connect (OSTI)

    Harry Cordatos

    2010-09-14

    Project attempts to develop a synthetic analogue for carbonic anhydrase and incorporate it in a membrane for separation of CO2 from coal power plant flue gas. Conference poster presents result of first 9 months of project progress including concept, basic system architecture and membrane properties target, results of molecular modeling for analogue - CO2 interaction, and next steps of testing analogue resistance to flue gas contaminants.

  17. Modeling long-term CO2 storage, sequestration and cycling

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-11-11

    The application of numerical and analytical models to the problem of storage, sequestration and migration of carbon dioxide in geologic formations is discussed. A review of numerical and analytical models that have been applied to CO2 sequestration are presented, as well as a description of frameworks for risk analysis. Application of models to various issues related to carbon sequestration are discussed, including trapping mechanisms, density convection mixing, impurities in the CO2 stream, changes in formation porosity and permeability, the risk of vertical leakage, and the impacts on groundwater resources if leakage does occur. A discussion of the development and application of site-specific models first addresses the estimation of model parameters and the use of natural analogues to inform the development of CO2 sequestration models, and then surveys modeling that has been done at two commercial-scale CO2 sequestration sites, Sleipner and In Salah, along with a pilot-scale injection sites used to study CO2 sequestration in saline aquifers (Frio) and an experimental site designed to test monitoring of CO2 leakage in the vadose zone (ZERT Release Facility).

  18. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

  19. An Enhanced Engineering Perspective of Global Climate Systems and Statistical Formulation of Terrestrial CO2 Exchanges

    SciTech Connect (OSTI)

    Dai, Yuanshun [University of Tennessee, Knoxville (UTK); Baek, Seung H. [Samsung Electronics Co., Ltd. Korea; Garcia-Diza, Alberto [University of Tennessee, Knoxville (UTK); Tsui, Kwok [Georgia Institute of Technology; Zhuang, Jie [University of Tennessee, Knoxville (UTK); Yang, Bai [ORNL

    2012-01-01

    This paper designs a comprehensive approach based on the engineering machine/system concept, to model, analyze, and assess the level of CO2 exchange between the atmosphere and terrestrial ecosystems, which is an important factor in understanding changes in global climate. The focus of this article is on spatial patterns and on the correlation between levels of CO2 fluxes and a variety of influencing factors in eco-environments. The engineering/machine concept used is a system protocol that includes the sequential activities of design, test, observe, and model. This concept is applied to explicitly include various influencing factors and interactions associated with CO2 fluxes. To formulate effective models of a large and complex climate system, this article introduces a modeling technique that will be referred to as Stochastic Filtering Analysis of Variance (SFANOVA). The CO2 flux data observed from some sites of AmeriFlux are used to illustrate and validate the analysis, prediction and globalization capabilities of the proposed engineering approach and the SF-ANOVA technology. The SF-ANOVA modeling approach was compared to stepwise regression, ridge regression, and neural networks. The comparison indicated that the proposed approach is a valid and effective tool with similar accuracy and less complexity than the other procedures.

  20. Photosynthesis, carboxylation and leaf nitrogen responses of 16 species to elevated pCO2 across four free-air CO2

    E-Print Network [OSTI]

    Thomas, David D.

    Photosynthesis, carboxylation and leaf nitrogen responses of 16 species to elevated pCO2 across four free-air CO2 enrichment experiments in forest, grassland and desert D AV I D S . E L L S W O R T H species under long-term elevated CO2 exposure (elevated pCa) directly impacts ecosystem CO2 assimilation

  1. Ris Energy Report 6 CO2 capture and storage 2 6.1 What is CO2 capture and storage?

    E-Print Network [OSTI]

    Gas Biomass Power & heat Power & heat Power & heat Gasification Air separation Process+CO2 sep-combustion Pre-combustion Oxyfuel Industrial processes Coal Gas Biomass Coal Gas Biomass Coal Gas Biomass Coal

  2. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    E-Print Network [OSTI]

    Zheng, L.

    2011-01-01

    1980). Mole fraction of organics in CO2 60 C o benzene+CO2,1980). Mole fraction of organics in CO2 100 C phenol+CO2,o VP CO2 Vapor pressure (bar) VP C6H6 0 Mole fraction of CO

  3. Low-temperature reactive coupling at polymerpolymer interfaces facilitated by supercritical CO2

    E-Print Network [OSTI]

    Low-temperature reactive coupling at polymer­polymer interfaces facilitated by supercritical CO2 S online 22 August 2005 Abstract Supercritical CO2 (scCO2) has been used to facilitate reactions in thin,6,7], the formation of such BCPs via reactive compatibilization [8­10], and the use of supercritical CO2 (scCO2) [11

  4. Abstract Atmospheric CO2 partial pressure (pCO2) was as low as 18 Pa during the Pleistocene and is projected to

    E-Print Network [OSTI]

    Antonovics, Janis

    Abstract Atmospheric CO2 partial pressure (pCO2) was as low as 18 Pa during the Pleistocene and is projected to increase from 36 to 70 Pa CO2 before the end of the 21st century. High pCO2 often increases the growth and repro- duction of C3 annuals, whereas low pCO2 decreases growth and may reduce or prevent

  5. Positron Annihilation Spectroscopy of High Performance Polymer Films under CO2 Pressure

    SciTech Connect (OSTI)

    C.A. Quarles; John R. Klaehn; Eric S. Peterson; Jagoda M. Urban-Klaehn

    2010-08-01

    Positron annihilation Lifetime and Doppler broadening measurements are reported for six polymer films as a function of carbon dioxide absolute pressure ranging from 0 to 45 psi. Since the polymer films were thin and did not absorb all positrons, corrections were made in the lifetime analysis for the absorption of positrons in the positron source and sample holder using the Monte Carlo transport code MCNP. Different polymers are found to behave differently. Some polymers studied form positronium and some, such as the polyimide structures, do not. For those samples that form positronium an interpretation in terms of free volume is possible; for those that don’t form positronium, further work is needed to determine how best to describe the behavior in terms of the bulk positron annihilation parameters. Some polymers exhibit changes in positron lifetime and intensity under CO2 pressure which may be described by the Henry or Langmuir sorption models, while the positron response of other polymers is rather insensitive to the CO2 pressure. The results demonstrate the usefulness of positron annihilation spectroscopy in investigating the sorption of CO2 into various polymers at pressures up to about 3 atm.

  6. Formation of Submicron Magnesite during Reaction of Natural Forsterite in H2O-Saturated Supercritical CO2

    SciTech Connect (OSTI)

    Qafoku, Odeta; Hu, Jian Z.; Hess, Nancy J.; Hu, Mary Y.; Ilton, Eugene S.; Feng, Ju; Arey, Bruce W.; Felmy, Andrew R.

    2014-06-01

    Natural forsterite was reacted in a) liquid water saturated with supercritical CO2 (scCO2) and in b) H2O-saturated scCO2 at 35-80 °C and 90 atm. The solid reaction products were analyzed with nuclear magnetic resonance (NMR), scanning electron microscopy (SEM), and confocal Raman spectroscopy. Two carbonate phases, nesquehonite (MgCO3.3H2O) and magnesite (MgCO3), were identified with the proportions of the two phases depending on experimental conditions. In water saturated with scCO2, nesquehonite was the dominant carbonate phase at 35-80 °C with only a limited number of large, micron size magnesite particles forming at the highest temperature, 80 °C. In contrast, in H2O-saturated scCO2 magnesite formation was identified at all three temperatures: 35 °, 50 °, and 80 °C. Magnesite was the dominant carbonation reaction product at 50 ° and 80 °C; but nesquehonite was dominant at 35 °C. The magnesite particles formed under H2O-saturated scCO2 conditions exhibited an extremely uniform submicron grain-size and nearly identical rhombohedral morphologies at all temperatures. The distribution and form of the particles were not consistent with epitaxial nucleation and growth on the forsterite surface.

  7. Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo2As2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pandey, Abhishek [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Quirinale, D. G. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Jayasekara, W. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Sapkota, A. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Kim, M. G. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Dhaka, R. S. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Lee, Y. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Heitmann, T. W. [Univ. of Missouri, Columbia, MO (United States). Missouri Research Reactor; Stephens, P. W. [State Univ. of New York (SUNY), Plattsburgh, NY (United States); Ogloblichev, V. [Russian Academy of Sciences, Urals Div., Ekaterinburg (Russian Federation). Inst. of Metal Physics; Kreyssig, A. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; McQueeney, R. J. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Goldman, A. I. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Kaminski, Adam [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Harmon, B. N. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Furukawa, Y. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Johnston, D. C. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy

    2013-07-01

    In tetragonal SrCo2As2 single crystals, inelastic neutron scattering measurements demonstrated that strong stripe-type antiferromagnetic (AFM) correlations occur at a temperature T = 5 K [W. Jayasekara et al., arXiv:1306.5174] that are the same as in the isostructural AFe2As2 (A = Ca, Sr, Ba) parent compounds of high-Tc superconductors. This surprising discovery suggests that SrCo2As2 may also be a good parent compound for high-Tc superconductivity. Here, structural and thermal expansion, electrical resistivity ?, angle-resolved photoemission spectroscopy (ARPES), heat capacity Cp, magnetic susceptibility ?, 75As NMR and neutron diffraction measurements of SrCo2As2 crystals are reported together with LDA band structure calculations that shed further light on this fascinating material. The c-axis thermal expansion coefficient ?c is negative from 7 to 300 K, whereas ?a is positive over this T range. The ?(T) shows metallic character. The ARPES measurements and band theory confirm the metallic character and in addition show the presence of a flat band near the Fermi energy EF. The band calculations exhibit an extremely sharp peak in the density of states D(EF) arising from a flat dx2-y2 band. A comparison of the Sommerfeld coefficient of the electronic specific heat with ?(T ? 0) suggests the presence of strong ferromagnetic itinerant spin correlations which on the basis of the Stoner criterion predicts that SrCo2As2 should be an itinerant ferromagnet, in conflict with the magnetization data. The ?(T) does have a large magnitude, but also exhibits a broad maximum at 115 K suggestive of dynamic short-range AFM spin correlations, in agreement with the neutron scattering data. The measurements show no evidence for any type of phase transition between 1.3 and 300 K and we propose that metallic SrCo2As2 has a gapless quantum spin-liquid ground state.

  8. North America's net terrestrial CO2 exchange with the atmosphere 1990–2009

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    King, Anthony W.; Andres, Robert; Davis, Kenneth J.; Hafer, M.; Hayes, Daniel J.; Huntzinger, Deborah N.; de Jong, Bernardus; Kurz, Werner; McGuire, A. David; Vargas, Rodrigo; et al

    2015-01-21

    Scientific understanding of the global carbon cycle is required for developing national and international policy to mitigate fossil fuel CO2 emissions by managing terrestrial carbon uptake. Toward that understanding and as a contribution to the REgional Carbon Cycle Assessment and Processes (RECCAP) project, this paper provides a synthesis of net land–atmosphere CO2 exchange for North America (Canada, United States, and Mexico) over the period 1990–2009. Only CO2 is considered, not methane or other greenhouse gases. This synthesis is based on results from three different methods: atmospheric inversion, inventory-based methods and terrestrial biosphere modeling. All methods indicate that the North Americanmore »land surface was a sink for atmospheric CO2, with a net transfer from atmosphere to land. Estimates ranged from -890 to -280 Tg C yr-1, where the mean of atmospheric inversion estimates forms the lower bound of that range (a larger land sink) and the inventory-based estimate using the production approach the upper (a smaller land sink). This relatively large range is due in part to differences in how the approaches represent trade, fire and other disturbances and which ecosystems they include. Integrating across estimates, \\"best\\" estimates (i.e., measures of central tendency) are -472 ± 281 Tg C yr-1 based on the mean and standard deviation of the distribution and -360 Tg C yr-1 (with an interquartile range of -496 to -337) based on the median. Considering both the fossil fuel emissions source and the land sink, our analysis shows that North America was, however, a net contributor to the growth of CO2 in the atmosphere in the late 20th and early 21st century. With North America's mean annual fossil fuel CO2 emissions for the period 1990–2009 equal to 1720 Tg C yr-1 and assuming the estimate of -472 Tg C yr-1 as an approximation of the true terrestrial CO2 sink, the continent's source : sink ratio for this time period was 1720:472, or nearly 4:1.« less

  9. CO2 Sequestration in Unmineable Coal Seams: Potential Environmental Impacts

    SciTech Connect (OSTI)

    Hedges, S.W.; Soong, Yee; McCarthy Jones, J.R.; Harrison, D.K.; Irdi, G.A.; Frommell, E.A.; Dilmore, R.M.; Pique, P.J.; Brown, T.D

    2005-09-01

    An initial investigation into the potential environmental impacts of CO2 sequestration in unmineable coal seams has been conducted, focusing on changes in the produced water during enhanced coalbed methane (ECBM) production using a CO2 injection process (CO2-ECBM). Two coals have been used in this study, the medium volatile bituminous Upper Freeport coal (APCS 1) of the Argonne Premium Coal Samples series, and an as-mined Pittsburgh #8 coal, which is a high volatile bituminous coal. Coal samples were reacted with either synthetic produced water or field collected produced water and gaseous carbon dioxide at 40 ?C and 50 bar to evaluate the potential for mobilizing toxic metals during CO2-ECBM/sequestration. Microscopic and x-ray diffraction analysis of the post-reaction coal samples clearly show evidence of chemical reaction, and chemical analysis of the produced water shows substantial changes in composition. These results suggest that changes to the produced water chemistry and the potential for mobilizing toxic trace elements from coalbeds are important factors to be considered when evaluating deep, unmineable coal seams for CO2 sequestration.

  10. CO2-selective, Hybrid Membranes by Silation of Alumina

    SciTech Connect (OSTI)

    Luebke, D.R.; Pennline, H.W.

    2007-09-01

    Hybrid membranes are feasible candidates for the separation of CO2 from gas produced in coal-based power generation since they have the potential to combine the high selectivity of polymer membranes and the high permeability of inorganic membranes. An interesting method for producing hybrid membranes is the silation of an inorganic membrane. In this method, trichloro- or alkoxy-silanes interact with hydroxyl groups on the surface of ?-AlO3 or TiO2, binding organic groups to that surface. By varying the length of these organic groups on the organosilane, it should be possible to tailor the effective pore size of the membrane. Similarly, the addition of “CO2-phillic” groups to the silating agent allows for the careful control of surface affinity and the enhancement of surface diffusion mechanisms. This method of producing hybrid membranes selective to CO2 was first attempted by Hyun [1] who silated TiO2 with phenyltriethoxysilane. Later, Way [2] silated ?-AlO3 with octadecyltrichlorosilane. Both researchers were successful in producing membranes with improved selectivity toward CO2, but permeability was not maintained at a commercially applicable level. XPS data indicated that the silating agent did not penetrate into the membrane pores and separation actually occurred in a thin “polymer-like” surface layer. The present study attempts to overcome the mass transfer problems associated with this technique by producing the desired monolayer coverage of silane, and thus develop a highly-permeable CO2-selective hybrid membrane.

  11. Surface Ocean CO2 Atlas (SOCAT) gridded data products

    SciTech Connect (OSTI)

    Sabine, Christopher; Hankin, S.; Koyuk, H; Bakker, D C E; Pfeil, B; Olsen, A; Metzl, N; Fassbender, A; Manke, A; Malczyk, J; Akl, J; Alin, S R; Bellerby, R G J; Borges, A; Boutin, J; Cai, W-J; Chavez, F P; Chen, A; Cosa, C; Feely, R A; Gonzalez-Davila, M; Goyet, C; Hardman-Mountford, N; Heinze, C; Hoppema, M; Hunt, C W; Hydes, D; Ishii, M; Johannessen, T; Key, R M; Kortzinger, A; Landschutzer, P; Lauvset, S K; Lefevre, N; Lourantou, A; Mintrop, L; Miyazaki, C; Murata, A; Nakadate, A; Nakano, Y; Nakaoka, S; Nojiri, Y; et al.

    2013-01-01

    A well documented, publicly available, global data set for surface ocean carbon dioxide (CO2) parameters has been called for by international groups for nearly two decades. The Surface Ocean CO2 Atlas (SOCAT) project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO2, which had been subject to quality control (QC). SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO2 data from the global oceans and coastal seas, spanning four decades (1968 2007). The SOCAT gridded data is the second data product to come from the SOCAT project. Recognizing that some groups may have trouble working with millions of measurements, the SOCAT gridded product was generated to provide a robust regularly spaced fCO2 product with minimal spatial and temporal interpolation which should be easier to work with for many applications. Gridded SOCAT is rich with information that has not been fully explored yet, but also contains biases and limitations that the user needs to recognize and address.

  12. International Symposium on Site Characterization for CO2Geological Storage

    SciTech Connect (OSTI)

    Tsang, Chin-Fu

    2006-02-23

    Several technological options have been proposed to stabilize atmospheric concentrations of CO{sub 2}. One proposed remedy is to separate and capture CO{sub 2} from fossil-fuel power plants and other stationary industrial sources and to inject the CO{sub 2} into deep subsurface formations for long-term storage and sequestration. Characterization of geologic formations for sequestration of large quantities of CO{sub 2} needs to be carefully considered to ensure that sites are suitable for long-term storage and that there will be no adverse impacts to human health or the environment. The Intergovernmental Panel on Climate Change (IPCC) Special Report on Carbon Dioxide Capture and Storage (Final Draft, October 2005) states that ''Site characterization, selection and performance prediction are crucial for successful geological storage. Before selecting a site, the geological setting must be characterized to determine if the overlying cap rock will provide an effective seal, if there is a sufficiently voluminous and permeable storage formation, and whether any abandoned or active wells will compromise the integrity of the seal. Moreover, the availability of good site characterization data is critical for the reliability of models''. This International Symposium on Site Characterization for CO{sub 2} Geological Storage (CO2SC) addresses the particular issue of site characterization and site selection related to the geologic storage of carbon dioxide. Presentations and discussions cover the various aspects associated with characterization and selection of potential CO{sub 2} storage sites, with emphasis on advances in process understanding, development of measurement methods, identification of key site features and parameters, site characterization strategies, and case studies.

  13. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01

    China's 2008 Total CO 2 Emissions from Energy Consumption:10. China's 2008 Total CO 2 Emissions from Energy: Sectoral16 Table 11. China's 2008 CO 2 Emissions from Energy:

  14. Propane-Diesel Dual Fuel for CO2 and Nox Reduction | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Propane-Diesel Dual Fuel for CO2 and Nox Reduction Propane-Diesel Dual Fuel for CO2 and Nox Reduction Test results show significant CO2 and NOx emission reductions, fuel economy...

  15. CO2 balance of boreal, temperate, and tropical forests derived from a global database

    E-Print Network [OSTI]

    2007-01-01

    2486.2007.01439.x CO 2 balance of boreal, temperate, andR T et al. Fig. 10 Observed CO 2 balance for boreal biomes.These CO 2 balances were not closed and therefore the

  16. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    and opportunities in accounting for non-energy use CO 2emissions (233 Mt CO 2 ), accounting for around one-third ofCO2 emissions? 3 Accounting challenges and opportunities

  17. Experiment-based modeling of geochemical interactions in CO2-based geothermal systems

    E-Print Network [OSTI]

    Jung, Y.

    2014-01-01

    associated with CO 2 -EGS,” Proceedings, 37th Workshop onEnhanced geothermal systems (EGS) using CO 2 as workingenhanced geothermal system (EGS) using CO 2 instead of water

  18. Experiment-based modeling of geochemical interactions in CO2-based geothermal systems

    E-Print Network [OSTI]

    Jung, Y.

    2014-01-01

    K. (2006), “Enhanced geothermal systems (EGS) using CO 2 asBehavior of Enhanced Geothermal Systems with CO 2 as Workingof operating enhanced geothermal system (EGS) using CO 2

  19. Single-well Low Temperature CO2- based Engineered Geothemal System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Single-well Low Temperature CO2- based Engineered Geothemal System Single-well Low Temperature CO2- based Engineered Geothemal System Single-well Low Temperature CO2- based...

  20. On CO2 Behavior in the Subsurface, Following Leakage from a Geologic Storage Reservoir

    E-Print Network [OSTI]

    Pruess, Karsten

    2006-01-01

    1 - 16, 1987. Skinner, L. CO2 Blowouts: An Emerging Problem,Assessment for Underground CO2 Storage, paper 234, presentedReservoir Performance Risk in CO2 Storage Projects, paper

  1. Regulation, Allocation, and Leakage in Cap-and-Trade Markets for CO2

    E-Print Network [OSTI]

    Bushnell, Jim B; Chen, Yihsu

    2009-01-01

    and Philippe Quirion. Co2 abatement, competitiveness andDaniel Kahn. Allocation of co2 emissions al- lowances in theA short-run case analysis of co2 leakage and nox and so2

  2. CATALYST CATALYSTADSORBENT ADSORBENT HCS + H2O H2 + CO2

    E-Print Network [OSTI]

    Southern California, University of

    - CO2 Adsorbent Effect of Membrane Properties On HAMR performance 3.190.3883--H2O --54.30.0248Ar --67 CATALYST CATALYSTADSORBENT ADSORBENT C O 2CO2 CO2 CO2 HCS + H2O H2 + CO2 Mork Family Department of Chemical using hydrotalcite-type CO2 adsorbents and nanoporous H2-selective carbon molecular sieve membranes (CMS

  3. Thermal desorption of CH4 retained in CO2 ice

    E-Print Network [OSTI]

    Luna, R; Domingo, M; Satorre, M A

    2008-01-01

    CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO2 traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH4 in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO2 ice.

  4. Thermal desorption of CH4 retained in CO2 ice

    E-Print Network [OSTI]

    R. Luna; C. Millan; M. Domingo; M. A. Satorre

    2008-01-21

    CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO2 traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH4 in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO2 ice.

  5. Use of experience curves to estimate the future cost of power plants with CO2 capture

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Antes, Matt; Berkenpas, Michael; Davison, John

    2007-01-01

    2004. Experience curves for power plant emission controlassessments of fossil fuel power plants with CO 2 capturethe future cost of power plants with CO 2 capture Edward S.

  6. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    as NEU-CO2 emissions (i.e. , a carbon storage fraction ofand stored fractions. It follows that, in practice, NEU-CO2

  7. Joule-Thomson Cooling Due to CO2 Injection into Natural Gas Reservoirs

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2006-01-01

    of “recovery factor”. IEA Oil Reserves Conference, Paris,used today for CO 2 -enhanced oil recovery. Pipeline CO 2 is

  8. Experiment-based modeling of geochemical interactions in CO2-based geothermal systems

    E-Print Network [OSTI]

    Jung, Y.

    2014-01-01

    in a granite-hosted geothermal system: Experimental insightsof CO 2 -based geothermal systems,” Proceedings, 38thK. (2006), “Enhanced geothermal systems (EGS) using CO 2 as

  9. Does low stomatal conductance or photosynthetic capacity enhance growth at elevated CO2 in Arabidopsis thaliana?

    E-Print Network [OSTI]

    Easlon, Hsien M; Carlisle, Eli; McKay, John K; Bloom, Arnold J

    2015-01-01

    Does low g enhance growth at elevated CO 2 ? To whomEcophysiology and Sustainability Does low g enhance growthat elevated CO 2 ? Does low stomatal conductance or

  10. Highlights of the 2009 SEG summer research workshop on "CO2 Sequestration Geophysics"

    E-Print Network [OSTI]

    Lumley, D.

    2010-01-01

    L. and McPherson, B. , 2008, Microseismic monitoring of CO 2profiling) and passive microseismic, are being used toactivity in passive microseismic techniques to monitor CO 2

  11. Fundamental study of CO2-H2O-mineral interactions for carbon...

    Office of Scientific and Technical Information (OSTI)

    E.; Wang, Yifeng; Matteo, Edward N.; Meserole, Stephen P.; Tallant, David Robert In the supercritical CO2-water-mineral systems relevant to subsurface CO2 sequestration,...

  12. Enhanced Geothermal Systems (EGS) comparing water with CO2 as heat transmission fluids

    E-Print Network [OSTI]

    Pruess, Karsten

    2007-01-01

    with the Development of Enhanced Geothermal Systems? , paper2004. Pruess, K. Enhanced Geothermal Systems (EGS) Using CO2Behavior of Enhanced Geothermal Systems with CO 2 as Working

  13. The Influence of a CO2 Pricing Scheme on Distributed Energy Resources in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    The Influence of a CO2 Pricing Scheme on Distributed Energy5. Regional Results for the CO2 Pricing Scheme no-invest

  14. CO2 hydrogenation to formate and methanol as an alternative to photo- and electrochemical CO2 reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Wan -Hui; Himeda, Yuichiro; Muckerman, James T.; Manbeck, Gerald F.; Fujita, Etsuko

    2015-09-03

    In this study, carbon dioxide is one of the end products of combustion, and is not a benign component of the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented levels and continues to increase owing to an escalating rate of fossil fuel combustion, causing concern about climate change and rising sea levels. In view of the inevitable depletion of fossil fuels, a possible solution to this problem is the recycling of carbon dioxide, possibly captured at its point of generation, to fuels. Researchers in this field are using solar energy for CO2 activation and utilization in severalmore »ways: (i) so-called artificial photosynthesis using photo-induced electrons; (ii) bulk electrolysis of a CO2 saturated solution using electricity produced by photovoltaics; (iii) CO2 hydrogenation using solar-produced H2; and (iv) the thermochemical reaction of metal oxides at extremely high temperature reached by solar collectors. Since the thermodynamics of CO2 at high temperature (> 1000 ºC) are quite different from those near room temperature, only chemistry below 200 ºC is discussed in this review.« less

  15. VUV-absorption cross section of CO2 at high temperatures and impact on exoplanet atmospheres

    E-Print Network [OSTI]

    Venot, Olivia; Bénilan, Yves; Gazeau, Marie-Claire; Hébrard, Eric; Larcher, Gwenaelle; Schwell, Martin; Dobrijevic, Michel; Selsis, Franck

    2015-01-01

    Ultraviolet (UV) absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar system. Transiting exoplanets whose atmospheres can now be studied by transit spectroscopy receive extremely strong UV fluxes and have typical temperatures ranging from 400 to 2500 K. At these temperatures, UV photolysis cross section data are severely lacking. Our goal is to provide high-temperature absorption cross sections and their temperature dependency for important atmospheric compounds. This study is dedicated to CO2, which is observed and photodissociated in exoplanet atmospheres. We performed these measurements for the 115 - 200 nm range at 300, 410, 480, and 550 K. In the 195 - 230 nm range, we worked at seven temperatures between 465 and 800 K. We found that the absorption cross section of CO2 is very sensitive to temperature, especially above 160 nm....

  16. Evaporative CO2 cooling using microchannels etched in silicon for the future LHCb vertex detector

    E-Print Network [OSTI]

    A. Nomerotski; J. Buytart; P. Collins; R. Dumps; E. Greening; M. John; A. Mapelli; A. Leflat; Y. Li; G. Romagnoli; B. Verlaat

    2013-02-16

    The extreme radiation dose received by vertex detectors at the Large Hadron Collider dictates stringent requirements on their cooling systems. To be robust against radiation damage, sensors should be maintained below -20 degree C and at the same time, the considerable heat load generated in the readout chips and the sensors must be removed. Evaporative CO2 cooling using microchannels etched in a silicon plane in thermal contact with the readout chips is an attractive option. In this paper, we present the first results of microchannel prototypes with circulating, two-phase CO2 and compare them to simulations. We also discuss a practical design of upgraded VELO detector for the LHCb experiment employing this approach.

  17. On modeling the potential impacts of CO2 sequestration on shallow groundwater: Transport of organics and co-injected H2S by supercritical CO2 to shallow aquifers

    E-Print Network [OSTI]

    Zheng, L.

    2014-01-01

    F.C. Knopf, 1991. Supercritical CO2 extraction of organicaqueous sulfide and supercritical CO2. Chemical Geology 271(reactivity with supercritical CO2 and aqueous sulfide.

  18. Mass hierarchy discrimination with atmospheric neutrinos in large volume ice/water Cherenkov detectors

    E-Print Network [OSTI]

    D. Franco; C. Jollet; A. Kouchner; V. Kulikovskiy; A. Meregaglia; S. Perasso; T. Pradier; A. Tonazzo; V. Van Elewyck

    2013-03-14

    Large mass ice/water Cherenkov experiments, optimized to detect low energy (1-20 GeV) atmospheric neutrinos, have the potential to discriminate between normal and inverted neutrino mass hierarchies. The sensitivity depends on several model and detector parameters, such as the neutrino flux profile and normalization, the Earth density profile, the oscillation parameter uncertainties, and the detector effective mass and resolution. A proper evaluation of the mass hierarchy discrimination power requires a robust statistical approach. In this work, the Toy Monte Carlo, based on an extended unbinned likelihood ratio test statistic, was used. The effect of each model and detector parameter, as well as the required detector exposure, was then studied. While uncertainties on the Earth density and atmospheric neutrino flux profiles were found to have a minor impact on the mass hierarchy discrimination, the flux normalization, as well as some of the oscillation parameter (\\Delta m^2_{31}, \\theta_{13}, \\theta_{23}, and \\delta_{CP}) uncertainties and correlations resulted critical. Finally, the minimum required detector exposure, the optimization of the low energy threshold, and the detector resolutions were also investigated.

  19. Regional Analysis of Building Distributed Energy Costs and CO2 Abatement: A U.S. - China Comparison

    E-Print Network [OSTI]

    Mendes, Goncalo

    2014-01-01

    Analysis of Building Energy Costs and CO 2 Emissions, ACEEEDistributed   Energy  Costs  and  CO 2  Abatement:     A  of Building Distributed Energy Costs and CO 2 Abatement: A

  20. Experimental study of rock-fluid interaction using automated multichannel system operated under conditions of CO2-based geothermal systems

    E-Print Network [OSTI]

    Petro, M.

    2014-01-01

    Interactions in CO 2 -based EGS,” 38 th Workshop onimportant aspects of the CO 2 -EGS reservoir development andof a potential CO 2 -EGS project. Originally, both illite

  1. The solubility and kinetics of minerals under CO2-EGS geothermal conditions: Comparison of experimental and modeling results

    E-Print Network [OSTI]

    Xu, T.

    2014-01-01

    K. , 2006. Enhanced Geothermal Systems (EGS) Using CO 2 asinteractions in enhanced geothermal systems (EGS) with CO 2behavior of enhanced geothermal systems with CO 2 as Working

  2. Large

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand CubicResourcelogo and mastheadLakeLanguage of a fly provesLarge

  3. COS: A new tracer to constrain photosynthetic CO2 fluxes

    E-Print Network [OSTI]

    Einat, Aharonov

    COS: A new tracer to constrain photosynthetic CO2 fluxes Dan Yakir1, Max Berkelhammer2, Hulin Chen2 COS (110-190) Indirect CS2, DMS (149-330) Unknown (~600) Stratosphere COSàSO2 OH uptake (82-110) Global COS Budget (Gg S a-1; Kettle et al., 2002; Montzka et al., 2007; Berry et al., 2013 ) Mean

  4. Chemical Looping Combustion for inherent CO2 capture in a

    E-Print Network [OSTI]

    HRSG Stack Steam TurbineFuel Compr. Air Flue gas H2O CO2 to compression Depleted air HP Steam not possible with Ni/NiO 6 CLC in a combined cycle power plant Fuel Reactor Air Reactor Gas Turbine Gas Turbine) ­ adiabatic, 20 bar Stoichiometric MeO Air-fuel ratio Stoichiometric ­ 3*Stoicihometric Gas turbine

  5. CO2 Storage and Sink Enhancements: Developing Comparable Economics

    E-Print Network [OSTI]

    capital, engineering and home office overhead, project and process contingencies, and miscellaneousCO2 Storage and Sink Enhancements: Developing Comparable Economics B.R. Bock1 , R.G. Rhudy2 , and H Research Institute, Palo Alto, CA, USA 3 Laboratory for Energy and the Environment, Massachusetts Institute

  6. Carbonation: An Efficient and Economical Process for CO2 Sequestration

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Carbonation: An Efficient and Economical Process for CO2 Sequestration Tarun R Naik1 and Rakesh sequestration. Most of the studies related to the carbonation are limited to its effects on corrosion. The possibility of using carbonation process as a direct means for carbon dioxide sequestration is yet

  7. Challenges in elevated CO2 experiments on forests

    E-Print Network [OSTI]

    Oren, Ram

    of Illinois, Urbana-Champaign, IL, USA 4 Technical University of Denmark, Roskilde, Denmark 5 University concentrations in future experiments to better predict the effects of climate change? Plantations and natural. Forest ecosystems under climate change Carbon dioxide (CO2) is the most important greenhouse gas emitted

  8. REVIEW ARTICLE Nitrogen cycle responses to elevated CO2 depend

    E-Print Network [OSTI]

    Thomas, David D.

    carbon dioxide (CO2) concentra- tion leads to an increase in the net flux of carbon (C) from sequestration of C (Drigo et al. 2008). Potentially, the additional sequestration of C in SOM will also cause-Liebig-University Giessen, Gießen, Germany 123 Nutr Cycl Agroecosyst DOI 10.1007/s10705-015-9683-8 #12;(N) sequestration

  9. INFLUENCE OF CAPILLARY PRESSURE ON CO2 STORAGE AND MONITORING

    E-Print Network [OSTI]

    Santos, Juan

    - 0.3 sin 1 - 0.5 sin : pore pressure : critical porosity 0: initial porosity : bulk INFLUENCE OF CAPILLARY PRESSURE ON CO2 STORAGE AND MONITORING Juan E. Santos Work in collaboration and capillary pressure relations) are determined from on-site resistivity measurements. In particular we

  10. Adsorption and Strain: The CO2-Induced Swelling of Coal

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Adsorption and Strain: The CO2-Induced Swelling of Coal M. Vandamme1 , L. Brochard2 , B. Lecampion3.07.014 #12;Abstract Enhanced coal bed methane recovery (ECBM) consists in injecting carbon dioxide in coal gets adsorbed at the surface of the coal pores, which causes the coal to swell. This swelling

  11. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01

    capture of CO 2 from gasifier process producing electricalPlaquemine, Louisiana. The gasifier is a proprietary designGasifier .

  12. Deep Pacific CaCO3 compensation and glacialinterglacial atmospheric CO2

    E-Print Network [OSTI]

    Lynch-Stieglitz, Jean

    Analysis of air trapped in Antarctic ice cores indicates that atmospheric CO2 concentrations have varied

  13. Industrial CO2 emissions as a proxy for anthropogenic influence on lower tropospheric temperature trends

    E-Print Network [OSTI]

    Laat, Jos de

    Industrial CO2 emissions as a proxy for anthropogenic influence on lower tropospheric temperature­2001 are spatially correlated to anthropogenic surface CO2 emissions, which we use as a measure of industrialization change, CO2 emissions. Citation: de Laat, A. T. J., and A. N. Maurellis (2004), Industrial CO2 emissions

  14. Economically Efficient Operation of CO2 Capturing Process Part II: Control Layer

    E-Print Network [OSTI]

    Skogestad, Sigurd

    be considered as the CO2 recovery in the absorber and the CO2 mole fraction at the bottom of the stripper Efficient Operation of CO2 Capturing Process Part II: Control Layer Mehdi Panahi, Sigurd Skogestad regions of a post-combustion CO2 capturing process using the top-down steady-state economic part

  15. Forest Sensitivity to Elevated Atmospheric CO2 and its Relevance to Carbon Management Richard J. Norby

    E-Print Network [OSTI]

    the airborne fraction of CO2 from fossil fuel combustion, and, therefore, the rate of increase of CO2Forest Sensitivity to Elevated Atmospheric CO2 and its Relevance to Carbon Management Richard J the responses of forest trees to rising concentrations of atmospheric CO2 has for the past two decades been

  16. Recent advances in well-based monitoring of CO2 sequestration

    E-Print Network [OSTI]

    Freifeld, B.

    2009-01-01

    seismic tomography for monitoring the pilot CO2 injection into an onshore aquifer, Nagaoka, Japan, Exploration

  17. Stoichiometry of CH4 and CO2 flux in a California Rice Paddy

    E-Print Network [OSTI]

    McMillan, Andrew M. S.; Goulden, Michael L.; Tyler, Stanley C.

    2007-01-01

    harvest. Respiratory losses (positive fluxes of CO 2 ) were highest following the drainage of standing water

  18. Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification

    E-Print Network [OSTI]

    are a strong motivation to reduce CO2 emissions from industrial processes. Burning of fossil fuel to generate electricity is a major source of CO2 in the atmosphere, but the capture and sequestration of CO2 from flue gasEnhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification Youn-Sang Bae

  19. Wavelet-based reconstruction of fossil-fuel CO2 emissions from sparse measurements

    E-Print Network [OSTI]

    Ray, Jaideep

    for source locations #12;Background on ffCO2 inversion · Unlike biogenic CO2 emissions, anthropogenicWavelet-based reconstruction of fossil-fuel CO2 emissions from sparse measurements J. Ray1, V: Develop a technique to estimate anthropogenic (fossil- fuel) CO2 emissions from sparse observations

  20. CARBON DIOXIDE -CO2 MSDS (DOCUMENT #001013) PAGE 1 OF 12 MATERIAL SAFETY DATA SHEET

    E-Print Network [OSTI]

    Choi, Kyu Yong

    CARBON DIOXIDE - CO2 MSDS (DOCUMENT #001013) PAGE 1 OF 12 MATERIAL SAFETY DATA SHEET Prepared to U in an emergency? 1. PRODUCT IDENTIFICATION CHEMICAL NAME; CLASS: CARBON DIOXIDE - CO2, GASEOUS CARBON DIOXIDE - CO2, CRYOGENIC CARBON DIOXIDE - CO2, SOLID Document Number: 001013 PRODUCT USE: For general analytical

  1. DOI: 10.1002/cssc.201000032 The Immobility of CO2 in Marine Sediments Beneath 1500

    E-Print Network [OSTI]

    Schrag, Daniel

    -than-sea- water CO2 in deep-sea sediments is inherently more secure then storing buoyant supercritical CO2 with the mobility of supercritical CO2 that has been injected into geologically equivalent (i.e., identical porosityDOI: 10.1002/cssc.201000032 The Immobility of CO2 in Marine Sediments Beneath 1500 Meters of Water

  2. Observations and simulations of synoptic, regional, and local variations in atmospheric CO2

    E-Print Network [OSTI]

    Collett Jr., Jeffrey L.

    Observations and simulations of synoptic, regional, and local variations in atmospheric CO2 Jih] Synoptic events may play an important role in determining the CO2 spatial distribution and temporal 2001, which had the most significant CO2 concentration variation in our case pool. The CO2

  3. Using CO2:CO correlations to improve inverse analyses of carbon fluxes

    E-Print Network [OSTI]

    Palmer, Paul

    Using CO2:CO correlations to improve inverse analyses of carbon fluxes Paul I. Palmer,1,2 Parvadha 30 June 2006. [1] Observed correlations between atmospheric concentrations of CO2 and CO represent potentially powerful information for improving CO2 surface flux estimates through coupled CO2-CO inverse

  4. CO2 enrichment accelerates successional development of an understory plant community

    E-Print Network [OSTI]

    Post, Wilfred M.

    CO2 enrichment accelerates successional development of an understory plant community Contact Research · Over 11 years of CO2 enrichment in the ORNL FACE experiment, the understory community changed dramatically. · Aboveground biomass was on average 25% greater in elevated [CO2] than in ambient [CO2] plots

  5. Pilot plant for CO2 capture with aqueous piperazine/potassium carbonate , Gary T. Rochelle1

    E-Print Network [OSTI]

    Rochelle, Gary T.

    GHGT-8 1 Pilot plant for CO2 capture with aqueous piperazine/potassium carbonate Eric Chen1 , Gary pilot for CO2 capture was successfully operated using potassium carbonate promoted with piperazine heat duty for a given CO2 removal efficiency than 6.4m K+ /1.6m PZ. Keywords: CO2, pilot plant

  6. CO2 efflux from Amazonian headwater streams represents a significant fate for deep soil respiration

    E-Print Network [OSTI]

    CO2 efflux from Amazonian headwater streams represents a significant fate for deep soil respiration amounts of CO2 to the atmosphere, while the magnitude of CO2 degassing from small streams remains a major was as terrestrially-respired CO2 dissolved within soils, over 90% of which evaded to the atmosphere within headwater

  7. Constraint of the CO2 rise by new atmospheric carbon isotopic measurements during the last deglaciation

    E-Print Network [OSTI]

    Chappellaz, Jérôme

    Click Here for Full Article Constraint of the CO2 rise by new atmospheric carbon isotopic increase of atmospheric carbon dioxide (CO2) during the last glacialinterglacial climatic transition remain debated. We analyzed the parallel evolution of CO2 and its stable carbon isotopic ratio (d13 CO2

  8. Physical controls on the isotopic composition of soil-respired CO2

    E-Print Network [OSTI]

    Physical controls on the isotopic composition of soil-respired CO2 Nick Nickerson1 and Dave Risk1] Measurement of the isotopic composition of soil and soil-respired CO2 (d13 CO2) has become an invaluable tool in understanding the effects of diffusive transport on soil CO2 isotopic composition, it is crucial

  9. Experimental Assessment of CO2Mineral-Toxic Ion Interactions in a Simplified Freshwater Aquifer: Implications for CO2 Leakage from

    E-Print Network [OSTI]

    that remobilization of trace elements by CO2 intrusion is not a universal physicochemical effect. In fact goethite, a decrease in pH resulting from CO2 intrusion could reactivate the adsorption of Se(IV) and As(V) if goethite, arsenite As(III) is significantly adsorbed on goethite, but is partially remobilized by CO2 intrusion

  10. Modeling Density Effects in CO2 Injection in Oil Reservoirs and A Case Study of CO2 Sequestration in a Qatari Saline Aquifer 

    E-Print Network [OSTI]

    Ahmed, Tausif

    2012-10-19

    CO2 injection has been used to improve oil recovery for several decades. In recent years, CO2 injection has become even more attractive because of a dual effect; injection in the subsurface 1) allows reduction of CO2 concentration in the atmosphere...

  11. 1M. Panahi, S. Skogestad ' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances' Optimal Operation of a CO2 Capturing

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1M. Panahi, S. Skogestad ' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances Mehdi Panahi Sigurd Skogestad 18.10.2011 AIChE Annual Meeting #12;2M. Panahi, S. Skogestad ' Optimal Operation of a CO2

  12. Experimental study of crossover from capillary to viscous fingering for supercritical CO2 - water displacement in a homogeneous pore network

    SciTech Connect (OSTI)

    Wang, Ying; Zhang, Changyong; Wei, Ning; Oostrom, Martinus; Wietsma, Thomas W.; Li, Xiaochun; Bonneville, Alain

    2013-01-01

    Carbon sequestration in saline aquifers involves displacing resident brine from the pore space by supercritical CO2 (scCO2). The displacement process is considered unstable due to the unfavorable viscosity ratio (logM < 0). The unstable mechanisms that affect scCO2 - water displacement under reservoir conditions (i.e., 41 °C, 9 MPa) were investigated in a homogeneous micromodel. A wide range of injection rates (logCa = -7.61~-4.73) was studied in two sets of experiments: discontinuous-rate injection, where the micromodel was first cleaned and saturated with water before each injection rate was imposed, and continuous-rate injection, where the rate was increased after quasi-steady conditions were reached for a certain rate. For the discontinuous-rate experiments, capillary fingering and viscous fingering are the dominant mechanisms for low (logCa <= -6.61) and high injection rates (logCa >= -5.21), respectively. Crossover from capillary to viscous fingering was observed for logCa = -5.91~-5.21, resulting in a large decrease in scCO2 saturation. The discontinuous-rate experimental results confirmed the decrease in nonwetting fluid saturation during crossover from capillary to viscous fingering predicted by numerical simulations by Lenormand et al. (1988).1 Capillary fingering was the only mechanism that dominates all injection rates in the continuous-rate experiment, and resulted in monotonic increase in scCO2 saturation.

  13. Constraining the reservoir model of an injected CO2 plume with crosswell CASSM at the Frio-II brine plot

    E-Print Network [OSTI]

    Daley, T.M.

    2011-01-01

    and the reservoir properties (CO 2 saturation distribution).residual CO 2 saturation and the associated reservoir CO 2reservoir model (top) with zoom of central portion showing predicted CO 2 saturation

  14. Numerical Modeling Studies of The Dissolution-Diffusion-Convection Process During CO2 Storage in Saline Aquifers

    E-Print Network [OSTI]

    Pruess, Karsten

    2008-01-01

    Properties of the Supercritical CO2–Water Pure Interface, J.and pressure conditions, supercritical CO2 (scCO2) has lowerthe overlying free supercritical CO2 phase. This is modeled

  15. The role of CO2 in CH4 exsolution from deep brine: Implications for geologic carbon sequestration

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2014-01-01

    to CO 2 -enhanced geothermal systems. Trans. Porous Med.to CO 2 -enhanced geothermal systems. Trans. Porous Med.

  16. Thermal properties of high-volume fly ash

    E-Print Network [OSTI]

    Bentz, Dale P.

    , the utilization of high-volume fly ash concrete mixtures to reduce CO2 emissions and cement consumption per unit, reducing cement consumption and the CO2 emissions accompanying its production, on a per volume unit a transient plane source method. Because the specimens being examined are well hydrated, estimates

  17. Photodesorption of ices I: CO, N2 and CO2

    E-Print Network [OSTI]

    Karin I. Oberg; Ewine F. van Dishoeck; Harold Linnartz

    2009-01-23

    A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed cold gas in cloud cores and disk mid-planes. This paper aims to determine the UV photodesorption yields and to constrain the photodesorption mechanisms of three astrochemically relevant ices: CO, N2 and CO2. In addition, the possibility of co-desorption in mixed and layered CO:N2 ices is explored. The ice photodesorption is studied experimentally under ultra high vacuum conditions and at 15-60 K using a hydrogen discharge lamp (7-10.5 eV). The ice desorption during irradiation is monitored by reflection absorption infrared spectroscopy of the ice and simultaneous mass spectrometry of the desorbed molecules. Both the UV photodesorption yields per incident photon and the photodesorption mechanisms are molecule specific. CO photodesorbs without dissociation from the surface layer of the ice. N2, which lacks an electronic transition in this wavelength range, has a photodesorption yield that is more than an order of magnitude lower. This yield increases significantly due to co-desorption when N2 is mixed in with or layered on top of CO ice. CO2 photodesorbs through dissociation and subsequent recombination from the top 10 layers of the ice. At low temperatures (15-18 K) the derived photodesorption yields are 2.7x10^-3 and CO2 photodesorption yield is 1.2x10^-3x(1-e^(-X/2.9)) + 1.1x10^-3x(1-e^(-X/4.6)) molecules photon-1, where X is the ice thickness in monolayers and the two parts of the expression represent a CO2 and CO photodesorption pathway.

  18. Large volume high-pressure cell for inelastic neutron scattering W. Wang, D. A. Sokolov, A. D. Huxley, and K. V. Kamenev

    E-Print Network [OSTI]

    Hall, Christopher

    Large volume high-pressure cell for inelastic neutron scattering W. Wang, D. A. Sokolov, A. D for inelastic neutron scattering measurements of quantum fluids and solids Rev. Sci. Instrum. 84, 015101 (2013) TOF-SEMSANS--Time-of-flight spin-echo modulated small-angle neutron scattering J. Appl. Phys. 112

  19. Testing the Early Mars H2-CO2 Greenhouse Hypothesis with a 1-D Photochemical Model

    E-Print Network [OSTI]

    Batalha, Natasha; Ramirez, Ramses; Kasting, James

    2015-01-01

    A recent study by Ramirez et al. (2014) demonstrated that an atmosphere with 1.3-4 bar of CO2 and H2O, in addition to 5-20% H2, could have raised the mean annual and global surface temperature of early Mars above the freezing point of water. Such warm temperatures appear necessary to generate the rainfall (or snowfall) amounts required to carve the ancient martian valleys. Here, we use our best estimates for early martian outgassing rates, along with a 1-D photochemical model, to assess the conversion efficiency of CO, CH4, and H2S to CO2, SO2, and H2. Our outgassing estimates assume that Mars was actively recycling volatiles between its crust and interior, as Earth does today. H2 production from serpentinization and deposition of banded iron-formations is also considered. Under these assumptions, maintaining an H2 concentration of ~1-2% by volume is achievable, but reaching 5% H2 requires additional H2 sources or a slowing of the hydrogen escape rate below the diffusion limit. If the early martian atmosphere...

  20. HIGH-TEMPERATURE CO-ELECTROLYSIS OF H2O AND CO2 FOR SYNGAS PRODUCTION

    SciTech Connect (OSTI)

    Stoots, C.M.

    2006-11-01

    Worldwide, the demand for light hydrocarbon fuels like gasoline and diesel oil is increasing. To satisfy this demand, oil companies have begun to utilize oil deposits of lower hydrogen content (an example is the Athabasca Oil Sands). Additionally, the higher contents of sulfur and nitrogen of these resources requires processes such as hydrotreating to meet environmental requirements. In the mean time, with the price of oil currently over $50 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. South Africa has used synfuels to power a significant number of their buses, trucks, and taxicabs. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to investigate the feasibility of producing syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. The syngas can then be used for synthetic fuel production. This program is a combination of experimental and computational activities. Since the solid oxide electrolyte material is a conductor of oxygen ions, CO can be produced by electrolyzing CO2 sequestered from some greenhouse gas-emitting process. Under certain conditions, however, CO can further electrolyze to produce carbon, which can then deposit on cell surfaces and reduce cell performance. The understanding of the co-electrolysis of steam and CO2 is also complicated by the competing water-gas shift reaction. Results of experiments and calculations to date of CO2 and CO2/H2O electrolysis will be presented and discussed. These will include electrolysis performance at various temperatures, gas mixtures, and electrical settings. Product gas compositions, as measured via a gas analyser, and their relationship to conversion efficiencies will be presented. These measurements will be compared to predictions obtained from chemical equilibrium computer codes. Better understanding of the feasibility of producing syngas using high-temperature electrolysis will initiate the systematic investigation of nuclear-powered synfuel production as a bridge to the future hydrogen economy and ultimate independence from foreign energy resources.

  1. The Influence of a CO2 Pricing Scheme on Distributed Energy Resources in California's Commercial Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Marnay, Chris; Lai, Judy; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal

    2010-06-01

    The Ernest Orlando Lawrence Berkeley National Laboratory (LBNL) is working with the California Energy Commission (CEC) to determine the potential role of commercial-sector distributed energy resources (DER) with combined heat and power (CHP) in greenhouse gas emissions (GHG) reductions. Historically, relatively little attention has been paid to the potential of medium-sized commercial buildings with peak electric loads ranging from 100 kW to 5 MW. In our research, we examine how these medium-sized commercial buildings might implement DER and CHP. The buildings are able to adopt and operate various technologies, e.g., photovoltaics (PV), on-site thermal generation, heat exchangers, solar thermal collectors, absorption chillers, batteries and thermal storage systems. We apply the Distributed Energy Resources Customer Adoption Model (DER-CAM), which is a mixed-integer linear program (MILP) that minimizes a site?s annual energy costs and/or CO2 emissions. Using 138 representative mid-sized commercial sites in California, existing tariffs of major utilities, and expected performance data of available technologies in 2020, we find the GHG reduction potential for these buildings. We compare different policy instruments, e.g., a CO2 pricing scheme or a feed-in tariff (FiT), and show their contributions to the California Air Resources Board (CARB) goals of additional 4 GW CHP capacities and 6.7 Mt/a GHG reduction in California by 2020. By applying different price levels for CO2, we find that there is competition between fuel cells and PV/solar thermal. It is found that the PV/solar thermal adoption increases rapidly, but shows a saturation at high CO2 prices, partly due to limited space for PV and solar thermal. Additionally, we find that large office buildings are good hosts for CHP in general. However, most interesting is the fact that fossil-based CHP adoption also increases with increasing CO2 prices. We will show service territory specific results since the attractiveness of DER varies widely by climate zone and service territory.

  2. Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo2As2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pandey, Abhishek; Quirinale, D. G.; Jayasekara, W.; Sapkota, A.; Kim, M. G.; Dhaka, R. S.; Lee, Y.; Heitmann, T. W.; Stephens, P. W.; Ogloblichev, V.; et al

    2013-07-01

    In tetragonal SrCo2As2 single crystals, inelastic neutron scattering measurements demonstrated that strong stripe-type antiferromagnetic (AFM) correlations occur at a temperature T = 5 K [W. Jayasekara et al., arXiv:1306.5174] that are the same as in the isostructural AFe2As2 (A = Ca, Sr, Ba) parent compounds of high-Tc superconductors. This surprising discovery suggests that SrCo2As2 may also be a good parent compound for high-Tc superconductivity. Here, structural and thermal expansion, electrical resistivity ?, angle-resolved photoemission spectroscopy (ARPES), heat capacity Cp, magnetic susceptibility ?, 75As NMR and neutron diffraction measurements of SrCo2As2 crystals are reported together with LDA band structure calculations thatmore »shed further light on this fascinating material. The c-axis thermal expansion coefficient ?c is negative from 7 to 300 K, whereas ?a is positive over this T range. The ?(T) shows metallic character. The ARPES measurements and band theory confirm the metallic character and in addition show the presence of a flat band near the Fermi energy EF. The band calculations exhibit an extremely sharp peak in the density of states D(EF) arising from a flat dx2-y2 band. A comparison of the Sommerfeld coefficient of the electronic specific heat with ?(T ? 0) suggests the presence of strong ferromagnetic itinerant spin correlations which on the basis of the Stoner criterion predicts that SrCo2As2 should be an itinerant ferromagnet, in conflict with the magnetization data. The ?(T) does have a large magnitude, but also exhibits a broad maximum at 115 K suggestive of dynamic short-range AFM spin correlations, in agreement with the neutron scattering data. The measurements show no evidence for any type of phase transition between 1.3 and 300 K and we propose that metallic SrCo2As2 has a gapless quantum spin-liquid ground state.« less

  3. STOMP Subsurface Transport Over Multiple Phases: STOMP-CO2 and STOMP-CO2e Guide: Version 1.0

    SciTech Connect (OSTI)

    White, Mark D.; Bacon, Diana H.; McGrail, B. Peter; Watson, David J.; White, Signe K.; Zhang, Z. F.

    2012-04-03

    This STOMP (Subsurface Transport Over Multiple Phases) guide document describes the theory, use, and application of the STOMP-CO2 and STOMP-CO2e operational modes. These operational modes of the STOMP simulator are configured to solve problems involving the sequestration of CO2 in geologic saline reservoirs. STOMP-CO2 is the isothermal version and STOMP-CO2e is the nonisothermal version. These core operational modes solve the governing conservation equations for component flow and transport through geologic media; where, the STOMP-CO2 components are water, CO2 and salt and the STOMP-CO2e operational mode also includes an energy conservation equation. Geochemistry can be included in the problem solution via the ECKEChem (Equilibrium-Conservation-Kinetic-Equation Chemistry) module, and geomechanics via the EPRMech (Elastic-Plastic-Rock Mechanics) module. This addendum is designed to provide the new user with a full guide for the core capabilities of the STOMP-CO2 and -CO2e simulators, and to provide the experienced user with a quick reference on implementing features. Several benchmark problems are provided in this addendum, which serve as starting points for developing inputs for more complex problems and as demonstrations of the simulator’s capabilities.

  4. Effects of CO2 on H2O band profiles and band strengths in mixed H2O:CO2 ices

    E-Print Network [OSTI]

    Karin I. Oberg; Helen J. Fraser; A. C. Adwin Boogert; Suzanne E. Bisschop; Guido W. Fuchs; Ewine F. van Dishoeck; Harold Linnartz

    2006-10-25

    H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent Spitzer observations have revealed CO2 ice in high abundances and it has been suggested that CO2 mixed into H2O ice can affect relative strengths of the 3 um and 6 um bands. We used laboratory infrared transmission spectroscopy of H2O:CO2 ice mixtures to investigate the effects of CO2 on H2O ice spectral features at 15-135 K. We find that the H2O peak profiles and band strengths are significantly different in H2O:CO2 ice mixtures compared to pure H2O ice. In all H2O:CO2 mixtures, a strong free-OH stretching band appears around 2.73 um, which can be used to put an upper limit on the CO2 concentration in the H2O ice. The H2O bending mode profile also changes drastically with CO2 concentration; the broad pure H2O band gives way to two narrow bands as the CO2 concentration is increased. This makes it crucial to constrain the environment of H2O ice to enable correct assignments of other species contributing to the interstellar 6 um absorption band. The amount of CO2 present in the H2O ice of B5:IRS1 is estimated by simultaneously comparing the H2O stretching and bending regions and the CO2 bending mode to laboratory spectra of H2O, CO2, H2O:CO2 and HCOOH.

  5. NREL's Cyanobacteria Engineering Shortens Biofuel Production Process, Captures CO2

    SciTech Connect (OSTI)

    2015-09-01

    This highlight describes NREL's work to systematically analyze the flow of energy in a photosynthetic microbe and show how the organism adjusts its metabolism to meet the increased energy demand for making ethylene. This work successfully demonstrates that the organism could cooperate by stimulating photosynthesis. The results encourage further genetic engineering for the conversion of CO2 to biofuels and chemicals. This highlight is being developed for the September 2015 Alliance S&T Board meeting. biofuels and chemicals. This highlight is being developed for the September 2015 Alliance S&T Board meeting.

  6. 2015 CO2 Capture Technology Meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-InspiredAtmosphericdevicesPPONeApril 30, 2013Program95 CalendarCO2 Capture

  7. CantorCO2e | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick,CalendarFork Electric Coop,CantorCO2e Jump

  8. CO2 Capture Poject CCP | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank, Maine:Kansas: Energy Resources JumpCIA-The World FactbookCN Solar CoCO2

  9. CO2 Heat Pump Water Heater | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l DeInsulation at04-86)ContractorsCNG Exports by Truck out ofCO2

  10. co2 capture meeting | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLos AlamosSimulation Initiative ccsi.jpglibfabric:Nauru:2012 NETL CO2

  11. From CO2 to Methanol via Novel Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article)Forthcoming Upgrades toFreezingHSA BankFriendshipsFrom CO2

  12. Sorption Phase of Supercritical CO2 in Silica Aerogel: Experiments and Mesoscale Computer Simulations

    SciTech Connect (OSTI)

    Rother, Gernot [ORNL; Vlcek, Lukas [ORNL; Gruszkiewicz, Miroslaw {Mirek} S [ORNL; Chialvo, Ariel A [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Banuelos, Jose Leo [ORNL; Wallacher, Dirk [Helmholtz-Zentrum Berlin; Grimm, Nico [Helmholtz-Zentrum Berlin; Cole, David [Ohio State University

    2014-01-01

    Adsorption of supercritical CO2 in nanoporous silica aerogel was investigated by a combination of experiments and molecular-level computer modeling. High-pressure gravimetric and vibrating tube densimetry techniques were used to measure the mean pore fluid density and excess sorption at 35 C and 50 C and pressures of 0-200 bar. Densification of the pore fluid was observed at bulk fluid densities below 0.7 g/cm3. Far above the bulk fluid density, near-zero sorption or weak depletion effects were measured, while broad excess sorption maxima form in the vicinity of the bulk critical density region. The CO2 sorption properties are very similar for two aerogels with different bulk densities of 0.1 g/cm3 and 0.2 g/cm3, respectively. The spatial distribution of the confined supercritical fluid was analyzed in terms of sorption- and bulk-phase densities by means of the Adsorbed Phase Model (APM), which used data from gravimetric sorption and small-angle neutron scattering experiments. To gain more detailed insight into supercritical fluid sorption, large-scale lattice gas GCMC simulations were utilized and tuned to resemble the experimental excess sorption data. The computed three-dimensional pore fluid density distributions show that the observed maximum of the excess sorption near the critical density originates from large density fluctuations pinned to the pore walls. At this maximum, the size of these fluctuations is comparable to the prevailing pore sizes.

  13. An experimental study iof the diffusion of C and O in calcite in mixed Co2-H2O fluids.

    SciTech Connect (OSTI)

    Labotka, Theodore C. [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL); Cole, David [Ohio State University; Fayek, Mostafa [University of Manitoba, Canada; Chacko, Thomas {nmn} [ORNL

    2011-01-01

    The diffusivity of C and O in calcite in mixed CO2-H2O fluid was determined over the range in xCO2 from 1.0 to about 0.2 at 700 C, 100 MPa, with selected experiments conducted at pressures to 250 MPa and temperatures of 600 and 800 C. The diffusivity of C, DC, varies little with xCO2, although there is some evidence for a slight increase in DC from 5 10 18 to 5 10 17 cm2/s with decreasing xCO2. Our data and those of others are consistent with a model for DC 1/fCO2. Despite the large uncertainty, we observed that the diffusivity of O, DO, increases from 2 10 16 to 5 10 14 cm2/s with xCO2 decreasing from 1.0 to 0. There is a good correlation at 700 C between log DO and log fH2O regardless of the total pressure, matching the observations of previous workers. The data are consistent with a simple two-component model for the diffusion of O in calcite, one component for diffusion in the presence of CO2 and one in the presence of H2O: DO = DOCO2 + DOH2O aH2O. The activity of H2O is relative to the fugacity at 100 MPa, 700 C. DOCO2 is 3.45 10 16, and DOH2O is 3.8 10 14 cm2/s. The data indicate that the rate of diffusion of C and O in calcite is controlled by reactions at the surface of calcite. Adsorption of H2O and the creation of vacancies at the surface account for the dependence of the diffusivity on the fugacity of the fluid components. There is little evidence that H itself diffuses into calcite. With this model and the values of DO in pure CO2 (Labotka et al. 2000) and in pure H2O (Farver 1994), the value of DO is predicted over the temperature range 600 800 C and pH2O up to 300 MPa, the range of the data. Calculated closure temperatures for diffusive exchange of O between calcite and fluid are reduced by about 150 C in the presence of an aqueous fluid.

  14. Efficient Theoretical Screening of Solid Sorbents for CO2 Capture...

    Office of Scientific and Technical Information (OSTI)

    Type: Journal Article Resource Relation: Journal Name: International Journal of Clean Coal and Energy; Journal Volume: 1; Journal Issue: 1 Research Org: National Energy...

  15. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    of the rock volume. Oil-production data indicate that theal. , 2006). Historical oil production at depths around 2400logs in regionally dis- oil production tributed wells Well

  16. Highlights of the 2009 SEG summer research workshop on "CO2 Sequestration Geophysics"

    E-Print Network [OSTI]

    Lumley, D.

    2010-01-01

    on “CO 2 Sequestration Geophysics” David Lumley (U. W.on “CO 2 Sequestration Geophysics” was held August 23-27,sequestration: Model Studies: Geophysics, 73, WA105-WA112.

  17. Advanced Development Of The Coal Fired Oxyfuel Process With CO2...

    Open Energy Info (EERE)

    Advanced Development Of The Coal Fired Oxyfuel Process With CO2 Separation ADECOS Jump to: navigation, search Name: Advanced Development Of The Coal-Fired Oxyfuel Process With CO2...

  18. Biases of CO2 Storage in Eddy Flux Measurements pertinent to...

    Office of Scientific and Technical Information (OSTI)

    Biases of CO2 Storage in Eddy Flux Measurements pertinent to Vertical Configurations of a Profile System and CO2 Density Averaging Citation Details In-Document Search Title: Biases...

  19. Mathematical models as tools for probing long-term safety of CO2 storage

    E-Print Network [OSTI]

    Pruess, Karsten

    2010-01-01

    for CO2 geological storage, Int. J. Greenhouse Gas Control,1008, DOI Bachu, S. CO2 Storage in Geological Media: Role,R.H. Worden. Geological Storage of Carbon Dioxide, in: S.J.

  20. DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage...

    Energy Savers [EERE]

    DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage Site DOE-Funded Project Testing Laser CO2 Monitoring at Carbon Storage Site June 3, 2015 - 8:44am Addthis Photo...

  1. Enhanced Geothermal Systems (EGS) comparing water with CO2 as heat transmission fluids

    E-Print Network [OSTI]

    Pruess, Karsten

    2007-01-01

    of Enhanced Geothermal Systems? , paper presented at ThirdPruess, K. Enhanced Geothermal Systems (EGS) Using CO2 asBehavior of Enhanced Geothermal Systems with CO 2 as Working

  2. The Influence of a CO2 Pricing Scheme on Distributed Energy Resources in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    to all DER technologies, PV adoption increases, but only in2 Pricing Scheme on CHP/PV adoption and CO 2 emissions SinceCO 2 price, PV and solar thermal adoption increases in all

  3. Automobile Fuel; Economy and CO2 Emissions in Industrialized Countries: Troubling Trends through 2005/6

    E-Print Network [OSTI]

    Schipper, Lee

    2008-01-01

    related to fuel use or emissions than car ownership alone.Limiting CO2 Emissions from new cars promulgated by the EU (of 120 gm/km CO2 emissions from new cars, which corresponds

  4. Interaction between CO2-rich solutions and reservoir-seal rocks. Experimentation

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    coal systems 5.Use of CO2 in enhanced coal bed methane recovery 6.Other suggested options (basalts, oil shales, cavities) #12;Motivation CO2 subsurface behavior and trapping mechanisms Four basic trapping

  5. Nonclassical hydrodynamic behavior of Sn plasma irradiated with a long duration CO2 laser pulse

    E-Print Network [OSTI]

    Tao, Y.; Tillack, M. S.; Yuseph, S.; Burdt, R.; Najmabadi, F.

    2010-01-01

    a long duration CO 2 laser pulse Y. Tao · M.S. Tillack · S.a long duration CO 2 laser pulse is much shorter than thatsource. When an intense laser pulse arrives at the surface

  6. Enhanced Geothermal Systems (EGS) comparing water with CO2 as heat transmission fluids

    E-Print Network [OSTI]

    Pruess, Karsten

    2007-01-01

    Supercritical CO 2 as Heat Transmission Fluid in the EGSof Using Supercritical CO2 as Heat Transmission Fluid in an2 instead of water as heat transmission fluid (D.W. Brown,

  7. On the production behavior of enhanced geothermal systems with CO2 as working fluid

    E-Print Network [OSTI]

    Pruess, K.

    2008-01-01

    either CO 2 or water as heat transmission fluid. For a modelsystems (EGS), heat transmission, thermal breakthrough, CO 2instead of water as heat transmission fluid was proposed by

  8. Future CO2 Emissions and Climate Change from Existing Energy Infrastructure

    E-Print Network [OSTI]

    Davis, SJ; Caldeira, K; Matthews, HD

    2010-01-01

    Future CO 2 Emissions and Climate Change from Existing Energynon-energy emissions could diminish in the future. In viewfuture CO 2 emissions is much greater in China, because China’s energy

  9. CO2 migration in saline aquifers. Part 1. Capillary trapping under slope and groundwater flow

    E-Print Network [OSTI]

    MacMinn, Christopher W.

    Injection of carbon dioxide (CO2) into geological formations is widely regarded as a promising tool for reducing global atmospheric CO2 emissions. To evaluate injection scenarios, estimate reservoir capacity and assess ...

  10. U.S. Manufacturers Save $1 Billion, 11 Million Tons of CO2 through...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy Efficiency Investments U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy Efficiency...

  11. Porous compaction in transient creep regime and implications for melt, petroleum, and CO2 circulation

    E-Print Network [OSTI]

    Kaminski, Edouard

    Porous compaction in transient creep regime and implications for melt, petroleum, and CO2 in transient creep regime and implications for melt, petroleum, and CO2 circulation, J. Geophys. Res., 113, B

  12. Assessing velocity and impedance changes due to CO2 saturation using interferometry on repeated seismic sources.

    E-Print Network [OSTI]

    Boyer, Edmond

    , Barcelona : Spain (2010)" #12;Introduction The role played by the industrial emission of carbon dioxide (CO2) in climate change has been well documented. Geological sequestration is a process to store CO2

  13. Non-CO2, Non-Greenhouse, Non-Gas Forcing Stephen E. Schwartz

    E-Print Network [OSTI]

    Schwartz, Stephen E.

    AEROSOLS: Non-CO2, Non-Greenhouse, Non-Gas Forcing Stephen E. Schwartz Symposium on Controlling Emissions of Non-CO2 Greenhouse Gases and Aerosols: Scientific and Policy Challenges http

  14. CO2 - Based Demand-Controlled Ventilation Control Strategies for Multi-Zone HVAC Systems 

    E-Print Network [OSTI]

    Nassif, N.

    2011-01-01

    CO2-based demand-controlled ventilation DCV strategy offers a great opportunity to reduce energy consumption in HVAC systems while providing the required ventilation. However, implementing CO2-based DCV under ASHRAE 62.1.2004 through 2010...

  15. CO2 on the Integrity of Well Cement | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2 on the Integrity of Well Cement Effect of CO2 on the Integrity of Well Cement under Geologic Storage Conditions Geologic carbon storage is the separation and capture of carbon...

  16. Carbon Dioxide (CO2) Capture Project Phase 2 (CCP2) - Storage...

    Open Energy Info (EERE)

    Carbon Dioxide (CO2) Capture Project Phase 2 (CCP2) - Storage Program: Closing Long-Term CO2 Geological Storage Gaps Relevant to Regulatory and Policy Development Jump to:...

  17. Impacts of CO2 Mandates for New Cars in the European Union

    E-Print Network [OSTI]

    Paltsev, S.

    CO2 emissions mandates for new light-duty passenger vehicles have recently been adopted in the European Union (EU), which require steady reductions to 95 g CO2/km in 2021. Using a computable general equilibrium (CGE) model, ...

  18. Evaluation of KDOT's Vehicle Fleet's CO2 Emissions and Possible Energy Reductions

    E-Print Network [OSTI]

    Nielsen, Eric

    2012-12-31

    Increasing energy demands require more energy extraction from fossil fuels. The energy is extracted through combustion and results in mainly CO2 emissions as well as other trace emissions. Reducing energy usage can save money and CO2 emissions...

  19. What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions

    E-Print Network [OSTI]

    G. Fridley, David

    2010-01-01

    He, et. al. 2005. “Oil consumption and CO2 emissions inHe, et. al. 2005. “Oil consumption and CO2 emissions inin all types of oil consumption are needed to reduce crude

  20. Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution in EGS Rocks

    Broader source: Energy.gov [DOE]

    Project objective: Quantify key parameters critically needed for developing and validating numerical modeling of chemical interactions between EGS reservoir rocks and supercritical CO2and CO2-rich aqueous fluids.

  1. U.S. Manufacturers Save $1 Billion, 11 Million Tons of CO2 through...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy Efficiency Investments U.S. Manufacturers Save 1 Billion, 11 Million Tons of CO2 through Energy...

  2. Effect of dissolved CO2 on a shallow groundwater system: A controlled...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Effect of dissolved CO2 on a shallow groundwater system: A controlled release experiment Citation Details In-Document Search Title: Effect of dissolved CO2 on a...

  3. Diesel Engine CO2 and SOx Emission Compliance Strategy for the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CO2 and SOx Emission Compliance Strategy for the Royal Navy (RN) and Royal Fleet Auxiliary (RFA) Flotillas Diesel Engine CO2 and SOx Emission Compliance Strategy for the Royal Navy...

  4. Reduction of Heavy-Duty Fuel Consumption and CO2 Generation ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Fuel Consumption and CO2 Generation -- What the Industry Does and What the Government Can Do Reduction of Heavy-Duty Fuel Consumption and CO2 Generation -- What the...

  5. CO2 interaction with aquifer and seal on geological timescales: the Miller oilfield, UK North Sea 

    E-Print Network [OSTI]

    Lu, Jiemin

    2008-01-01

    Carbon Capture and Storage (CCS) has been identified as a feasible technology to reduce CO2 emissions whilst permitting the continued use of fossil fuels. Injected CO2 must remain efficiently isolated from the atmosphere ...

  6. Misrepresentation of the IPCC CO2 emission scenarios

    SciTech Connect (OSTI)

    Manning, Martin; Edmonds, James A.; Emori, S.; Grubler, Arnulf; Hibbard, Kathleen A.; Joos, Fortunat; Kainuma, M.; Keeling, Ralph; Kram, Tom; Manning, Andrew; Meinhausen, Malte; Moss, Richard H.; Nakicenovic, Nebojsa; Riahi, Keywan; Rose, Steven K.; Smith, Steven J.; Swart, Robert; Van Vuuren, Detlef

    2010-06-01

    Estimates of recent fossil fuel CO2 emissions have been compared with the IPCC SRES (Special Report on Emission Scenarios) emission scenarios that had been developed for analysis of future climate change, impacts and mitigation. In some cases this comparison uses averages across subgroups of SRES scenarios and for one category of greenhouse gases (industrial sources of CO2). That approach can be misleading and cause confusion as it is inconsistent with many of the papers on future climate change projections that are based on a specific subset of closely scrutinized SRES scenarios, known as illustrative marker scenarios. Here, we show that comparison between recent estimates of fossil fuel emissions trends and the SRES illustrative marker scenarios leads to the conclusion that recent trends are not outside the SRES range. Furthermore, the recent economic downturn appears to have brought actual emission back toward the middle of the SRES illustrative marker scenarios. We also note that SRES emission scenarios are designed to reflect potential alternative long-term trends in a world without climate policy intervention and the trend in the resulting climate change is not sensitive to short-term fluctuations.

  7. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Interactions in Enhanced Geothermal Systems (EGS) with CO 2Fluid, Proceedings, World Geothermal Congress 2010, Bali,Remain? Transactions, Geothermal Resources Council, Vol. 17,

  8. A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage

    E-Print Network [OSTI]

    Apps, J.A.

    2006-01-01

    A Review of Hazardous Chemical Species Associated with CO 2the inventory of most hazardous trace elements are capturedequilibrium concentrations of hazardous trace elements in

  9. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Interactions in Enhanced Geothermal Systems (EGS) with CO 2of Enhanced Geothermal Systems? , paper presented at Thirdfrom Enhanced Geothermal Systems, Proceedings, Paper

  10. A Phase-Partitioning Model for CO2–Brine Mixtures at Elevated Temperatures and Pressures: Application to CO2-Enhanced Geothermal Systems

    E-Print Network [OSTI]

    Spycher, Nicolas; Pruess, Karsten

    2010-01-01

    of water as the heat transmission ?uid in EGS has beena sys- tem with CO 2 as heat transmission ?uid requires an

  11. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    in Enhanced Geothermal Systems (EGS) with CO 2 as WorkingTransmission Fluid in the EGS Integrating the Carbon Storageand F. Rummel. The Deep EGS (Enhanced Geothermal System)

  12. Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2

    E-Print Network [OSTI]

    Pruess, K.

    2010-01-01

    Interactions in Enhanced Geothermal Systems (EGS) with CO 2with the Development of Enhanced Geothermal Systems? , paperProspects from Enhanced Geothermal Systems, Proceedings,

  13. A Phase-Partitioning Model for CO2–Brine Mixtures at Elevated Temperatures and Pressures: Application to CO2-Enhanced Geothermal Systems

    E-Print Network [OSTI]

    Spycher, Nicolas; Pruess, Karsten

    2010-01-01

    the development of enhanced geothermal systems? In: PaperThe deep EGS (Enhanced Geothermal System) project at Soultz-Application to CO 2 -Enhanced Geothermal Systems Moore, J.

  14. Continuous active-source seismic monitoring of CO2 injection in a brine aquifer

    E-Print Network [OSTI]

    Daley, Thomas M.; Solbau, Ray D.; Ajo-Franklin, Jonathan B.; Benson, Sally M.

    2008-01-01

    INTERPRETATION The injection of CO 2 causes a decrease in seismicseismic monitoring during injection. Although quantitative interpretation

  15. Assessing the health risks of natural CO2 seeps in Italy

    E-Print Network [OSTI]

    Haszeldine, Stuart

    risk from surface CO2 seeps. Data were elicited from Googas (17), a web-based catalogue of degassing

  16. Future CO2 Emissions and Climate Change from Existing Energy Infrastructure

    E-Print Network [OSTI]

    Davis, SJ; Caldeira, K; Matthews, HD

    2010-01-01

    14. International Energy Agency (IEA), CO 2 Emissionsfrom Fuel Combustion (IEA, Paris, 2009). 15. G. A. Meehl et

  17. Patterns and Controls of Temporal Variation in CO2 Sequestration and Loss in Arctic Ecosystems

    SciTech Connect (OSTI)

    Oechel, Walter C.

    2002-03-21

    Determine seasonal and interannual patterns of net ecosystem CO2 flux from wet coastal and moist tussock tundra.

  18. A Framework for Environmental Assessment of CO2 Capture and Storage Systems

    E-Print Network [OSTI]

    Sathre, Roger

    2013-01-01

    OF  CO2  CAPTURE  AND  STORAGE   SYSTEMS   Roger  Sathre,  2  Capture  and  Storage  Systems   Roger Sathre 1 , Mikhail

  19. Leakage Risk Assessment for a Potential CO2 Storage Project in Saskatchewan, Canada

    E-Print Network [OSTI]

    Houseworth, J.E.

    2012-01-01

    Framework Leakage Risk Assessment for a Potential CO 2Risk Assessment..confidence in the risk assessment. . Potential Sequestration

  20. Highlights of the 2009 SEG summer research workshop on "CO2 Sequestration Geophysics"

    E-Print Network [OSTI]

    Lumley, D.

    2010-01-01

    groundwater, natural gas storage, waste disposal…). Rock andfrom CO 2 EOR and natural gas storage projects, the risk of

  1. 6.11 Atmospheric CO2 and O2 During the Phanerozoic: Tools, Patterns, and Impacts

    E-Print Network [OSTI]

    Royer, Dana

    6.11 Atmospheric CO2 and O2 During the Phanerozoic: Tools, Patterns, and Impacts DL Royer, Wesleyan.11.2 Models for Atmospheric CO2 and O2 Estimation 251 6.11.2.1 Key Principles 251 6.11.2.2 GEOCARB Models 252.11.2.2.5 Estimates of CO2 and O2 from the GEOCARB model 254 6.11.2.3 Other Models for CO2 and O2 Reconstruction 254 6

  2. ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2

    E-Print Network [OSTI]

    Pruess, K.

    2011-01-01

    third primary variable (CO2 mass fraction) from X = 0 to X =1# X X " b " CO2 where X is the mass fraction of CO 2 in theCO2 X = Assuming a single co-existing CO 2 -rich phase, water mass fraction

  3. Experimental Investigation on the Use of Water Soluble Polyacrylamides as Thickeners During CO_(2) WAG EOR 

    E-Print Network [OSTI]

    Tovar, Francisco

    2014-07-24

    of polymers as water thickeners during CO_(2). The work has been divided into three stages: An investigation on the stability of acrylamide based polymers exposed to CO_(2) for 328 days at 122 °F. The determination of the MMP for the system crude oil – CO_(2...

  4. ORIGINAL PAPER Effects of elevated CO2 and soil water content on phytohormone

    E-Print Network [OSTI]

    DeLucia, Evan H.

    ORIGINAL PAPER Effects of elevated CO2 and soil water content on phytohormone transcript induction the abundance of SA compared with plants grown in ambient CO2. A mild reduction in soil water content had herbivory. When applied in combination, elevated CO2 and reduced soil water content suppressed

  5. Hollow-waveguide delivery systems for high-power, industrial CO2 lasers

    E-Print Network [OSTI]

    Hollow-waveguide delivery systems for high-power, industrial CO2 lasers Ricky K. Nubling and James to deliver CO2 laser power for industrial laser applications. The transmission, bending loss, and output, beam delivery, industrial lasers, power delivery, CO2 lasers. r 1996 Optical Society of America 1

  6. The Role of Non-CO2 GHGs in Climate Policy

    E-Print Network [OSTI]

    . Furthermore, we estimate the costs of the non-CO2 policies to be a small fraction of the Kyoto policy. Whether503 The Role of Non-CO2 GHGs in Climate Policy: Analysis Using the MIT IGSM John Reilly, Marcus comprehensive in term of greenhouse gases (GHGs), including only the non-CO2 GHGs, but is geographically

  7. Free-Air CO2 Enrichment (FACE) Experiment PRINCIPAL INVESTIGATOR: Richard J. Norby

    E-Print Network [OSTI]

    is projected to reduce the airborne fraction of anthropogenic CO2 emissions. Coupled climate-carbon cycleFree-Air CO2 Enrichment (FACE) Experiment PRINCIPAL INVESTIGATOR: Richard J. Norby PARTICIPATING Free-Air CO2 Enrichment (FACE) project is to understand how the eastern deciduous forest

  8. Solubility trapping in formation water as dominant CO2 sink in natural gas fields

    E-Print Network [OSTI]

    Haszeldine, Stuart

    LETTERS Solubility trapping in formation water as dominant CO2 sink in natural gas fields Stuart M, dissolu- tion in formation water at a pH of 5­5.8 is the sole major sink for CO2. In two fields dissolved in water. Noble gas and CO2 carbon isotopes are powerful tracers of crustal fluid processes

  9. Available online at www.sciencedirect.com Electrochemical conversion of CO2 to useful chemicals: current

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    ://dx.doi.org/10.1016/j.coche.2013.03.005 Introduction Carbon dioxide (CO2) emissions into the atmosphere will needAvailable online at www.sciencedirect.com Electrochemical conversion of CO2 to useful chemicals further undesirable climate change. Electrochemical reduction of CO2 into value-added chemicals using

  10. Carbon Sequestration GeoloGical SequeStration of co2

    E-Print Network [OSTI]

    Pennycook, Steve

    Growing concern over the potential adverse effects of carbon dioxide (CO2 ) buildup in the atmosphere in three world-class CO2 storage projects that are endorsed by the Carbon Sequestration Leadership Forum04/2008 Carbon Sequestration GeoloGical SequeStration of co2 : the Geo-Seq Project Background

  11. Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Report TKK-ENY-9 Mineral carbonation for long-term storage of CO2 from flue gases Jens Kohlmann 1 University of Technology was "Mineral carbonation for long-term storage of CO2 from flue gases"; the progress storage by mineral carbonation in Finland (CO2 lagring genom mineral karbonering i Finland)" Ron

  12. An improved strategy to detect CO2 leakage for verification of geologic carbon sequestration

    E-Print Network [OSTI]

    Hilley, George

    An improved strategy to detect CO2 leakage for verification of geologic carbon sequestration J. L the success of geologic carbon sequestration projects. To detect subtle CO2 leakage signals, we present), An improved strategy to detect CO2 leakage for verification of geologic carbon sequestration, Geophys. Res

  13. Carborane-based metalorganic frameworks as highly selective sorbents for CO2 over methane

    E-Print Network [OSTI]

    (PSA) are attractive due to their low cost and high energy efficiency.1 High CO2 selectivityCarborane-based metal­organic frameworks as highly selective sorbents for CO2 over methane Youn Article on the web 15th July 2008 DOI: 10.1039/b805785k Separation of CO2/CH4 mixtures was studied

  14. Plumbing the Depths: Testing Natural Tracers of Subsurface CO2 Origin and

    E-Print Network [OSTI]

    Gilfillan, Stuart

    to be added to the CO2 at the time of injec- tion. This will marginally increase the cost of storagePlumbing the Depths: Testing Natural Tracers of Subsurface CO2 Origin and Migration, Utah Mark storage of fluid CO2 in porous subsurface rock will re- quire the ability to track, and identify

  15. Interactions among mycorrhizae, atmospheric CO2 and soil N impact plant community composition

    E-Print Network [OSTI]

    Thomas, David D.

    of several C3 forbs and may suggest that CO2 enrichment ameliorates the carbon cost of some AM symbiosesREPORT Interactions among mycorrhizae, atmospheric CO2 and soil N impact plant community of atmospheric CO2 and soil N. Communities of 14 plant species were grown in mesocosms containing living

  16. Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment

    E-Print Network [OSTI]

    Masanet, Eric; Sathaye, Jayant

    2009-01-01

    for preliminary cost–bene?t analyses of discrete NEU-CO2of the costs and bene?ts of various NEU-CO2 emissionscosts and GHG emissions reduction bene?ts as compared to competing options—will require greater NEU-CO2

  17. UV absorption of CO2 for temperature diagnostics of hydrocarbon combustion applications

    E-Print Network [OSTI]

    Lee, Tonghun

    CO2 LIF [8], which for hydrocarbon combustion effluent can interfere with NO-LIF measurements [9UV absorption of CO2 for temperature diagnostics of hydrocarbon combustion applications J and 320 nm. Because CO2 is a major product of hydrocarbon combustion and because both the magnitude

  18. Using the National Fire Research Laboratory as a Test Bed for Traceable CO2

    E-Print Network [OSTI]

    at the source ­ Predicted Emissions vs Direct Emissions #12;Hydrocarbon Fuels GHG: CO2 Hydrocarbon Fuels GHG: CO Research Laboratory · Goal: Measure CO2 emissions with ±1% uncertainty · Reconcile the carbon mass balanceUsing the National Fire Research Laboratory as a Test Bed for Traceable CO2 Measurements Rodney

  19. The urgency of the development of CO2 capture from ambient air

    E-Print Network [OSTI]

    Bergman, Keren

    their CO2 emissions. Point-source CCS could be implemented without significant changes for consumers, which, 11). Point-source CCS and air capture are not the only options for reducing CO2 emissions. Stationary as insurance against CO2 leaking from storage and furthermore may provide an option for dealing with emissions

  20. Quick Notes on CO2 Diagram and Energy Diagram For the ESRP 285 Website (Spring 2008)

    E-Print Network [OSTI]

    Ford, Andrew

    (CO2) emissions are the largest source of greenhouse gas emissions, accounting for over 80% of the emissions in the USA (EIA 2003, p. 35). CO2 emissions arise from the combustion of carbon fuels arrows are sized to represent emissions in million metric tons of CO2 equivalent, hereafter abbreviated

  1. SPECIAL ISSUE Multi-spectral imaging of vegetation for detecting CO2 leaking

    E-Print Network [OSTI]

    Shaw, Joseph A.

    vegetation near shallow subsurface CO2 releases during summers 2007 and 2008 at the Zero Emissions Research to the CO2 sink­source relationship and vegetation density. The data also show short-term effects of rain sequestration for reducing greenhouse gas emissions is accompanied by a need for methods to detect CO2

  2. emissions: mineral carbonation and Finnish pulp and paper industry (CO2

    E-Print Network [OSTI]

    Zevenhoven, Ron

    CO2 emissions: mineral carbonation and Finnish pulp and paper industry (CO2 Nordic Plus) and Use, utilisation and long-term storage of carbon dioxide (CO2) in the pulp and paper industry. The Geological of serpentinites in energy and metal industry (ECOSERP) Carl-Johan Fogelholm, Project leader, professor Sanni

  3. ORNL/CDIAC-152 GLOBAL OCEAN SURFACE WATER PARTIAL PRESSURE OF CO2 DATABASE

    E-Print Network [OSTI]

    ORNL/CDIAC-152 NDP-088r GLOBAL OCEAN SURFACE WATER PARTIAL PRESSURE OF CO2 DATABASE: MEASUREMENTS .....................................................................................................................................9 #12;#12;v LIST OF FIGURES 1 Location of LDEO master database of sea surface pCO2 observations. .............................................2 LIST OF TABLES 1 List of data contributors to the global surface water pCO2 LDEO database

  4. Soil CO2 production and surface flux at four climate observatories in eastern Canada

    E-Print Network [OSTI]

    Beltrami, Hugo

    Soil CO2 production and surface flux at four climate observatories in eastern Canada David Risk December 2002. [1] Soils constitute the largest terrestrial source of carbon dioxide to the atmosphere the climatic controls on soil respiration. We use subsurface CO2 concentrations, surface CO2 flux and detailed

  5. Effect of CO2 Sorption and Desorption on the Creep Response of Polycarbonate

    E-Print Network [OSTI]

    Hochberg, Michael

    foams can be found in Kumar [3]. The motivation for studying the effect of CO2 sorption and desorptionEffect of CO2 Sorption and Desorption on the Creep Response of Polycarbonate Arun Pasricha, Gregory, Easton, Pennsylvania 18042 In this article, experimental results on the effect of CO2 sorption

  6. CO2 Enhanced Oil Recovery Feasibility Evaluation for East Texas Oil Field

    E-Print Network [OSTI]

    Lu, Ping

    2012-08-31

    Carbon dioxide enhanced oil recovery (CO2-EOR) has been undergoing for four decades and is now a proven technology. CO2-EOR increases oil recovery, and in the meantime reduces the greenhouse gas emissions by capture CO2 underground. The objectives...

  7. Solar dimming and CO2 effects on soil moisture trends Alan Robock1

    E-Print Network [OSTI]

    Robock, Alan

    Solar dimming and CO2 effects on soil moisture trends Alan Robock1 and Haibin Li1 Received 15 July solar dimming and upward CO2 trends, we conducted experiments with a sophisticated land surface model. Li (2006), Solar dimming and CO2 effects on soil moisture trends, Geophys. Res. Lett., 33, L20708

  8. Uncertainty Analysis of Otway CO2 Sequestration Project Shohreh Amini 1,2

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    this Surrogate Reservoir Model enables us to predict the pressure, phase saturation, and CO2 distribution presents the application of a grid-based Surrogate Reservoir Model (SRM) to a real case CO2 sequestration project in which CO2 were injected into a depleted gas reservoir. This project is a part of the National

  9. Complex Flow and Composition Path in CO2 Injection Schemes from Density Effects

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    is that the downward flow of the CO2 and oil mixture may not be gravity-stable, despite the widespread assumption States ABSTRACT: CO2 injection has been used to improve oil recovery for the last 4 decades. In recent) improves the oil recovery. One of the screening criteria for CO2 injection as an enhanced oil recovery

  10. ASSESSMENT OF THE MODELS FOR THE ESTIMATION OF THE CO2 RELEASES TOXIC EFFECTS

    E-Print Network [OSTI]

    Boyer, Edmond

    the global warming due to high concentration of CO2 in the atmosphere. However, in case of massive accidental to specific properties regarding its triple point. Then, this CO2 flakes creation may be followed1 ASSESSMENT OF THE MODELS FOR THE ESTIMATION OF THE CO2 RELEASES TOXIC EFFECTS Frédéric Antoine

  11. Effect of CO2 on wood properties of Liquidambar styraciflua after

    E-Print Network [OSTI]

    Gray, Matthew

    1/18/2010 1 Effect of CO2 on wood properties of Liquidambar styraciflua after 10 years-Knoxville face.ornl.gov IntroductionIntroductionIntroductionIntroduction FACEFACEFACEFACE The free air CO2 enrichment experiment on the Oak Ridge National Environmental Research Park The effect of CO2 enrichment

  12. Generation of CO2-rich melts during basalt magma ascent and degassing

    E-Print Network [OSTI]

    Boyer, Edmond

    to solubilities. In contrast, the rate of vesiculation controls the final melt CO2 concentration. HighGeneration of CO2-rich melts during basalt magma ascent and degassing Michel Pichavant . Ida Di magma degassing, continuous decompressions of volatile-bearing (2.7-3.8 wt% H2O, 600-1300 ppm CO2

  13. Environmental control of CO2 assimilation rates and stomatal conductance in five oak species

    E-Print Network [OSTI]

    Boyer, Edmond

    Short note Environmental control of CO2 assimilation rates and stomatal conductance in five oak compared CO2 assimilation rate and stomatal conductance of five oak species from the beginning of May'assimilation nette de CO2 et la conductance sto- matique de cinq espèces de chênes en plantation en Grèce. Cette

  14. Infrared emission spectroscopy of CO2 at high temperature. Part I: Experimental setup and source

    E-Print Network [OSTI]

    Boyer, Edmond

    Infrared emission spectroscopy of CO2 at high temperature. Part I: Experimental setup and source measurement, tube effects, CO2 infrared radiation 1. Introduction The knowledge of very high temperature for instance that the IR emission of the CO2 molecule remains predominant at temperatures as high as 4000 K [1

  15. CO2-SO2 clathrate hydrate formation on early Mars1 Eric Chassefirea,b

    E-Print Network [OSTI]

    Boyer, Edmond

    and maintained a global average surface temperature ~230 K. Because35 clathrates trap SO2 more favorably than CO2 as a possible greenhouse gas which worked together55 with CO2 to raise the surface temperature of early Mars1 CO2-SO2 clathrate hydrate formation on early Mars1 2 Eric Chassefièrea,b , Emmanuel Dartoisc

  16. Cooling of the mesosphere and lower thermosphere due to doubling of CO2

    E-Print Network [OSTI]

    Boyer, Edmond

    Cooling of the mesosphere and lower thermosphere due to doubling of CO2 R. A. Akmaev1 , V. I 1998 Abstract. A new parameterization of infrared radiative transfer in the 15-lm CO2 band has been to calcu- lations of heating rates above approximately 15 km for arbitrary vertical pro®les of the CO2

  17. Constraining the density of CO2 within the Utsira formation using time-lapse gravity measurements

    E-Print Network [OSTI]

    Nooner, Scott

    best fit a high temperature forward model based on the seismically determined CO2 geometry, suggesting to study the behavior and physical properties of the injected CO2. The gravity measurements show1 Constraining the density of CO2 within the Utsira formation using time-lapse gravity measurements

  18. Metal Oxide Thin Films Deposited from Metal Organic Precursors in Supercritical CO2 Solutions

    E-Print Network [OSTI]

    Gougousi, Theodosia

    Metal Oxide Thin Films Deposited from Metal Organic Precursors in Supercritical CO2 Solutions and oxidizing agents are delivered in liquid and supercritical CO2. A cyclic deposition process is presented properties of supercritical CO2 can aid in the delivery of precursors and in the removal of byproducts

  19. Enhanced Miscibility of Low-Molecular-Weight Polystyrene/Polyisoprene Blends in Supercritical CO2

    E-Print Network [OSTI]

    Raghavan, Srinivasa

    Enhanced Miscibility of Low-Molecular-Weight Polystyrene/Polyisoprene Blends in Supercritical CO2 solution temperature (UCST) polymer blend in the presence of supercritical carbon dioxide (scCO2 been examined as a function of temperature in scCO2 by visual inspection, small-angle neutron

  20. Solubility measurements and modeling of molecules of biological and pharmaceutical interest with supercritical CO2

    E-Print Network [OSTI]

    Stadtherr, Mark A.

    with supercritical CO2 G. I. Burgos-Solórzano, J. F. Brennecke* and M. A. Stadtherr Department of Chemical behavior. Here we explore the use of supercritical CO2 to dissolve molecules of potential interest and erythromycin in supercritical CO2 at temperatures between 40 and 60 °C and pressures up to 300 bar