National Library of Energy BETA

Sample records for large format li-ion

  1. Addressing the Impact of Temperature Extremes on Large Format Li-Ion Batteries for Vehicle Applications (Presentation)

    SciTech Connect (OSTI)

    Pesaran, A.; Santhanagopalan, S.; Kim, G. H.

    2013-05-01

    This presentation discusses the effects of temperature on large format lithium-ion batteries in electric drive vehicles.

  2. Multifunctional, Inorganic-Filled Separators for Large Format...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries...

  3. Fail-Safe Design for Large Capacity Li-Ion Battery Systems - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Find More Like This Return to Search Fail-Safe Design for Large Capacity Li-Ion Battery Systems National Renewable Energy Laboratory Contact NREL About This Technology Publications: PDF Document Publication Fail Safe Design for Large Capacity Lithium-ion Batteries.pdf (2,324 KB) Technology Marketing Summary Lithium-ion batteries (LIBs) are a promising candidate for energy storage of electric drive vehicles due to their high power and energy density. The total electric

  4. Significant Cost Improvement of Li-Ion Cells Through Non-NMP...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies Significant Cost Improvement of Li-Ion ...

  5. Three-Dimensional Thermal-Electrochemical Coupled Model for Spirally Wound Large-Format Lithium-Ion Batteries (Presentation)

    SciTech Connect (OSTI)

    Lee, K. J.; Smith K.; Kim, G. H.

    2011-04-01

    This presentation discusses the behavior of spirally wound large-format Li-ion batteries with respect to their design. The objectives of the study include developing thermal and electrochemical models resolving 3-dimensional spirally wound structures of cylindrical cells, understanding the mechanisms and interactions between local electrochemical reactions and macroscopic heat and electron transfers, and developing a tool and methodology to support macroscopic designs of cylindrical Li-ion battery cells.

  6. Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion

    Broader source: Energy.gov (indexed) [DOE]

    Energy Futures Study | Department of Energy U.S. Department of Energy Light Duty Vehicle Workshop in Washington, D.C. on July 26, 2010. multi-path_trans_futures.pdf (250.21 KB) More Documents & Publications Alternative Transportation Technologies: Hydrogen, Biofuels, Advanced Efficiency, and Plug-in Hybrid Electric Vehicles Support for Government Performance and Results Act (GPRA) Analysis Environmental Assessment of Plug-In Hybrid Electric Vehicles Volume 1: Nationwide Greenhouse Gas

  7. Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  8. Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  9. Modeling of Nonuniform Degradation in Large-Format Li-ion Batteries (Poster)

    SciTech Connect (OSTI)

    Smith, K.; Kim, G. H.; Pesaran, A.

    2009-06-01

    Shows results of an empirical model capturing effects of both storage and cycling and developed the lithium ion nickel cobalt aluminum advanced battery chemistry.

  10. Material review of Li ion battery separators

    SciTech Connect (OSTI)

    Weber, Christoph J. Geiger, Sigrid; Falusi, Sandra; Roth, Michael

    2014-06-16

    Separators for Li Ion batteries have a strong impact on cell production, cell performance, life, as well as reliability and safety. The separator market volume is about 500 million m{sup 2} mainly based on consumer applications. It is expected to grow strongly over the next decade for mobile and stationary applications using large cells. At present, the market is essentially served by polyolefine membranes. Such membranes have some technological limitations, such as wettability, porosity, penetration resistance, shrinkage and meltdown. The development of a cell failure due to internal short circuit is potentially closely related to separator material properties. Consequently, advanced separators became an intense area of worldwide research and development activity in academia and industry. New separator technologies are being developed especially to address safety and reliability related property improvements.

  11. Enabling Future Li-Ion Battery Recycling | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Future Li-Ion Battery Recycling Title Enabling Future Li-Ion Battery Recycling Publication Type Presentation Year of Publication 2014 Authors Gaines, LL Abstract Presentation made...

  12. Electrode Materials for Rechargeable Li-ion Batteries: a New...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrode Materials for Rechargeable Li-ion Batteries: a New Synthetic Approach ... multiple cycles which enables Li-ion batteries with exceptionally high-power.

    This ...

  13. Vehicle Technologies Office Merit Review 2016: Development of Si-Composite Anode for Large-Format Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Hydro Quebec at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  14. Predictive Models of Li-ion Battery Lifetime (Presentation) (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Predictive Models of Li-ion Battery Lifetime (Presentation) Citation Details In-Document Search Title: Predictive Models of Li-ion Battery Lifetime (Presentation) Predictive models of Li-ion battery reliability must consider a multiplicity of electrochemical, thermal and mechanical degradation modes experienced by batteries in application environments. Complicating matters, Li-ion batteries can experience several path dependent degradation trajectories dependent on storage

  15. Predictive Models of Li-ion Battery Lifetime (Presentation) Smith...

    Office of Scientific and Technical Information (OSTI)

    Predictive Models of Li-ion Battery Lifetime (Presentation) Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G.; Shi, Y.; Pesaran, A. 25 ENERGY STORAGE; 33 ADVANCED PROPULSION...

  16. Degradation Mechanisms in Li-Ion Battery Electrolytes Uncovered...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Degradation Mechanisms in Li-Ion Battery Electrolytes Uncovered by In-Situ Scanning ... to evaluate stability and degradation in battery electrolytes Developed a rapid method ...

  17. Characterization of Materials for Li-ion Batteries: Success Stories...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Success Stories from the High Temperature Materials Laboratory (HTML) User Program Characterization of Materials for Li-ion Batteries: Success Stories from the High...

  18. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Broader source: Energy.gov (indexed) [DOE]

    Process for Low Cost Domestic Production of LIB Cathode Materials Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode ...

  19. Li ion Motors Corp formerly EV Innovations Inc | Open Energy...

    Open Energy Info (EERE)

    Vegas, Nevada Zip: 89110 Sector: Vehicles Product: Las Vegas - based manufacturer of lithium-powered plug-in vehicles. References: Li-ion Motors Corp (formerly EV Innovations...

  20. Characterization of Li-ion Batteries using Neutron Diffraction...

    Broader source: Energy.gov (indexed) [DOE]

    Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML User Program Success Stories Characterization of Materials for Li-ion Batteries: ...

  1. Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA...

    Broader source: Energy.gov (indexed) [DOE]

    MB) More Documents & Publications Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA Li-Ion Battery Cell Manufacturing 2010 DOE, Li-Ion Battery Cell Manufacturing

  2. Enabling the Future of Li-Ion Batteries | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enabling the Future of Li-Ion Batteries Title Enabling the Future of Li-Ion Batteries Publication Type Presentation Year of Publication 2015 Authors Gaines, LL Abstract...

  3. Transport and Failure in Li-ion Batteries | Stanford Synchrotron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Li-ion Batteries Monday, February 13, 2012 - 1:30pm SSRL Conference Room 137-322 Stephen J. Harris, General Motors R&D While battery performance is well predicted by the...

  4. Miniature all-solid-state heterostructure nanowire Li-ion batteries...

    Office of Scientific and Technical Information (OSTI)

    Miniature all-solid-state heterostructure nanowire Li-ion batteries as a tool for ... Title: Miniature all-solid-state heterostructure nanowire Li-ion batteries as a tool for ...

  5. Study of novel nonflammable electrolytes in Sandia-built Li-ion...

    Office of Scientific and Technical Information (OSTI)

    Study of novel nonflammable electrolytes in Sandia-built Li-ion cells. Citation Details In-Document Search Title: Study of novel nonflammable electrolytes in Sandia-built Li-ion ...

  6. Model-Experimental Studies on Next-generation Li-ion Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Experimental Studies on Next-generation Li-ion Materials Model-Experimental Studies on Next-generation Li-ion Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program ...

  7. Influence of Li ions on the oxygen reduction reaction of platinum electrocatalyst

    SciTech Connect (OSTI)

    Liu, H; Xing, YC

    2011-06-01

    A Li-air battery can provide a much higher theoretical energy density than a Li-ion battery. The use of aqueous acidic electrolytes may prevent lithium oxide deposition from aprotic electrolytes and lithium carbonate precipitation from alkaline electrolytes. The present communication reports a study on the effect of Li ions on the oxygen reduction reaction (ORR) in sulfuric acid electrolytes. It was found that the Li ions have negligible interactions with the active surface of Pt catalysts. However, significantly lower ORR activities were found when Li ions are present in the sulfuric acid. The intrinsic kinetic activities were found to decrease with the increase of Li ion concentrations, but level off when the Li ion concentrations are larger than 1.0 M. The low activities of Pt catalysts in Li ion containing electrolytes were attributed to a constraining effect of Li ions on the diffusion of oxygen in the electrolyte solution. (C) 2011 Elsevier B.V. All rights reserved.

  8. The significance of Li-ion batteries in electric vehicle life...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The significance of Li-ion batteries in electric vehicle life-cycle energy and emissions and recycling's role in its reduction Title The significance of Li-ion batteries in...

  9. Predictive Models of Li-ion Battery Lifetime

    SciTech Connect (OSTI)

    Smith, Kandler; Wood, Eric; Santhanagopalan, Shriram; Kim, Gi-heon; Shi, Ying; Pesaran, Ahmad

    2015-06-15

    It remains an open question how best to predict real-world battery lifetime based on accelerated calendar and cycle aging data from the laboratory. Multiple degradation mechanisms due to (electro)chemical, thermal, and mechanical coupled phenomena influence Li-ion battery lifetime, each with different dependence on time, cycling and thermal environment. The standardization of life predictive models would benefit the industry by reducing test time and streamlining development of system controls.

  10. Predictive Models of Li-ion Battery Lifetime (Presentation)

    SciTech Connect (OSTI)

    Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G.; Shi, Y.; Pesaran, A.

    2014-09-01

    Predictive models of Li-ion battery reliability must consider a multiplicity of electrochemical, thermal and mechanical degradation modes experienced by batteries in application environments. Complicating matters, Li-ion batteries can experience several path dependent degradation trajectories dependent on storage and cycling history of the application environment. Rates of degradation are controlled by factors such as temperature history, electrochemical operating window, and charge/discharge rate. Lacking accurate models and tests, lifetime uncertainty must be absorbed by overdesign and warranty costs. Degradation models are needed that predict lifetime more accurately and with less test data. Models should also provide engineering feedback for next generation battery designs. This presentation reviews both multi-dimensional physical models and simpler, lumped surrogate models of battery electrochemical and mechanical degradation. Models are compared with cell- and pack-level aging data from commercial Li-ion chemistries. The analysis elucidates the relative importance of electrochemical and mechanical stress-induced degradation mechanisms in real-world operating environments. Opportunities for extending the lifetime of commercial battery systems are explored.

  11. Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting arravt001_es_koo_2012_p.pdf (2.94 MB) More Documents & Publications Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA Li-Ion Battery Cell Manufacturing 2010 DOE, Li-Ion Battery Cell Manufacturing

  12. Atomistic Modeling of the Electrode-Electrolyte Interface in Li-Ion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Systems: Electrolyte Structuring | Argonne Leadership Computing Facility Atomistic Modeling of the Electrode-Electrolyte Interface in Li-Ion Energy Storage Systems: Electrolyte Structuring Authors: Ryan Jorn, Revati Kumar, Daniel P. Abraham, Gregory A. Voth The solid electrolyte interface (SEI) forms as a result of side reactions between the electrolyte and electrode surfaces in Li-ion batteries and can adversely impact performance by impeding Li-ion transport and diminishing

  13. Platforms and Methods for In Situ Characterization of Li-ion...

    Office of Scientific and Technical Information (OSTI)

    Platforms and Methods for In Situ Characterization of Li-ion Battery Materials. Citation Details In-Document Search Title: Platforms and Methods for In Situ Characterization of...

  14. Miniature All-solid-state Heterostructure Nanowire Li-ion Batteries...

    Office of Scientific and Technical Information (OSTI)

    All-solid-state Heterostructure Nanowire Li-ion Batteries as a Toll for Engineering and Structural Diagnostics of Nanoscale Electrochemical Processes Citation Details In-Document...

  15. Analysis of Heat Dissipation in Li-Ion Cells & Modules for Modeling of Thermal Runaway (Presentation)

    SciTech Connect (OSTI)

    Kim, G.-H.; Pesaran, A.

    2007-05-15

    The objectives of this study are: (1) To develop 3D Li-Ion battery thermal abuse ''reaction'' models for cell and module analysis; (2) To understand the mechanisms and interactions between heat transfer and chemical reactions during thermal runaway for Li-Ion cells and modules; (3) To develop a tool and methodology to support the design of abuse-tolerant Li-Ion battery systems for PHEVs/HEVs; and (4) To help battery developers accelerate delivery of abuse-tolerant Li-Ion battery systems in support of the FreedomCAR's Energy Storage Program.

  16. Development of Cell/Pack Level Models for Automotive Li-Ion Batteries...

    Broader source: Energy.gov (indexed) [DOE]

    Level Models for Automotive Li-Ion Batteries with Experimental Validation Computer-Aided Engineering for Electric Drive Vehicle Batteries (CAEBAT) Vehicle Technologies Office ...

  17. Accurate static and dynamic properties of liquid-electrolytes for Li-ion batteries from ab initio molecular dynamics

    SciTech Connect (OSTI)

    Ganesh, Panchapakesan; Jiang, Deen; Kent, Paul R

    2011-01-01

    Lithium-ion batteries have the potential to revolutionize the transportation industry, as they did for wireless communication. A judicious choice of the liquid electrolytes used in these systems is required to achieve a good balance among high-energy storage, long cycle life and stability, and fast charging. Ethylene-carbonate (EC) and propylene-carbonate (PC) are popular electrolytes. However, to date, almost all molecular-dynamics simulations of these fluids rely on classical force fields, while a complete description of the functionality of Li-ion batteries will eventually require quantum mechanics. We perform accurate ab initio molecular-dynamics simulations of ethylene- and propylene-carbonate with LiPF6 at experimental concentrations to build solvation models which explain available neutron scattering and nuclear magnetic resonance (NMR) results and to compute Li-ion solvation energies and diffusion constants. Our results suggest some similarities between the two liquids as well as some important differences. Simulations also provide useful insights into formation of solid-electrolyte interphases in the presence of electrodes in conventional Li-ion batteries.

  18. Accurate static and dynamic properties of liquid electrolytes for Li-ion batteries from ab initio molecular dynamics

    SciTech Connect (OSTI)

    Ganesh, P.; Jiang, D.; Kent, P.R.C.

    2011-03-31

    Lithium-ion batteries have the potential to revolutionize the transportation industry, as they did for wireless communication. A judicious choice of the liquid electrolytes used in these systems is required to achieve a good balance among high-energy storage, long cycle life and stability, and fast charging. Ethylene-carbonate (EC) and propylene-carbonate (PC) are popular electrolytes. However, to date, almost all molecular-dynamics simulations of these fluids rely on classical force fields, while a complete description of the functionality of Li-ion batteries will eventually require quantum mechanics. We perform accurate ab initio molecular-dynamics simulations of ethylene- and propylene-carbonate with LiPF6 at experimental concentrations to build solvation models which explain available neutron scattering and nuclear magnetic resonance (NMR) results and to compute Li-ion solvation energies and diffusion constants. Our results suggest some similarities between the two liquids as well as some important differences. Simulations also provide useful insights into formation of solid-electrolyte interphases in the presence of electrodes in conventional Li-ion batteries.

  19. Green synthesis of boron doped graphene and its application as high performance anode material in Li ion battery

    SciTech Connect (OSTI)

    Sahoo, Madhumita; Sreena, K.P.; Vinayan, B.P.; Ramaprabhu, S.

    2015-01-15

    Graphical abstract: Boron doped graphene (B-G), synthesized by simple hydrogen induced reduction technique using boric acid as boron precursor, have more uneven surface as a result of smaller bonding distance of boron compared to carbon, showed high capacity and high rate capability compared to pristine graphene as an anode material for Li ion battery application. - Abstract: The present work demonstrates a facile route for the large-scale, catalyst free, and green synthesis approach of boron doped graphene (B-G) and its use as high performance anode material for Li ion battery (LIB) application. Boron atoms were doped into graphene framework with an atomic percentage of 5.93% via hydrogen induced thermal reduction technique using graphite oxide and boric acid as precursors. Various characterization techniques were used to confirm the boron doping in graphene sheets. B-G as anode material shows a discharge capacity of 548 mAh g{sup ?1} at 100 mA g{sup ?1} after 30th cycles. At high current density value of 1 A g{sup ?1}, B-G as anode material enhances the specific capacity by about 1.7 times compared to pristine graphene. The present study shows a simplistic way of boron doping in graphene leading to an enhanced Li ion adsorption due to the change in electronic states.

  20. Fluoro-Carbonate Solvents for Li-Ion Cells

    SciTech Connect (OSTI)

    NAGASUBRAMANIAN,GANESAN

    1999-09-17

    A number of fluoro-carbonate solvents were evaluated as electrolytes for Li-ion cells. These solvents are fluorine analogs of the conventional electrolyte solvents such as dimethyl carbonate, ethylene carbonate, diethyl carbonate in Li-ion cells. Conductivity of single and mixed fluoro carbonate electrolytes containing 1 M LiPF{sub 6} was measured at different temperatures. These electrolytes did not freeze at -40 C. We are evaluating currently, the irreversible 1st cycle capacity loss in carbon anode in these electrolytes and the capacity loss will be compared to that in the conventional electrolytes. Voltage stability windows of the electrolytes were measured at room temperature and compared with that of the conventional electrolytes. The fluoro-carbon electrolytes appear to be more stable than the conventional electrolytes near Li voltage. Few preliminary electrochemical data of the fluoro-carbonate solvents in full cells are reported in the literature. For example, some of the fluorocarbonate solvents appear to have a wider voltage window than the conventional electrolyte solvents. For example, methyl 2,2,2 trifluoro ethyl carbonate containing 1 M LiPF{sub 6} electrolyte has a decomposition voltage exceeding 6 V vs. Li compared to <5 V for conventional electrolytes. The solvent also appears to be stable in contact with lithium at room temperature.

  1. High Voltage Electrolytes for Li-ion Batteries | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting es024_jow_2012_o.pdf (6.21 MB) More Documents & Publications High Voltage Electrolytes for Li-ion Batteries High Voltage Electrolytes for Li-ion Batteries Progress in Electrolyte Component R&D within the ABR Program, 2009 thru 2013

  2. High Voltage Electrolytes for Li-ion Batteries | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es024_jow_2011_p.pdf (1.87 MB) More Documents & Publications High Voltage Electrolytes for Li-ion Batteries High Voltage Electrolytes for Li-ion Batteries Molecular dynamics simulation and ab intio studies of electrolytes and electrolyte/electrode interfaces

  3. Oxidation Potentials of Functionalized Sulfone Solvents for High-Voltage Li-Ion Batteries: A Computational Study

    SciTech Connect (OSTI)

    Shao, Nan; Sun, Xiao-Guang; Dai, Sheng; Jiang, Deen

    2012-01-01

    New electrolytes with large electrochemical windows are needed to meet the challenge for high-voltage Li-ion batteries. Sulfone as an electrolyte solvent boasts of high oxidation potentials. Here we examine the effect of multiple functionalization on sulfone's oxidation potential. We compute oxidation potentials for a series of sulfone-based molecules functionalized with fluorine, cyano, ester, and carbonate groups by using a quantum chemistry method within a continuum solvation model. We find that multifunctionalization is a key to achieving high oxidation potentials. This can be realized through either a fluorether group on a sulfone molecule or sulfonyl fluoride with a cyano or ester group.

  4. Effect of an Ultrathin Coating on Stabilizing Li-ion Battery...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes Sunday, January 31, 2016 Improvements in the high-voltage cycling stability of lithium ion battery cathode ...

  5. Understanding Li-ion battery processes at the atomic- to nano...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Understanding Li-ion battery processes at the atomic- to nano-scale Authors: Sullivan, J P ; Huang, Jianyu ; Shaw, M J ; Subramanian, A ; ...

  6. Insights into capacity loss mechanisms in Li-ion all-solid-state...

    Office of Scientific and Technical Information (OSTI)

    Insights into capacity loss mechanisms in Li-ion all-solid-state batteries with Al anodes Citation Details In-Document Search Title: Insights into capacity loss mechanisms in...

  7. Second-Use Li-Ion Batteries to Aid Automotive and Utility Industries (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01

    Repurposing Li-ion batteries at the end of useful life in electric drive vehicles could eliminate owners' disposal concerns and offer low-cost energy storage for certain applications.

  8. First-principles investigation of the electronic and Li-ion diffusion properties of LiFePO{sub 4} by sulfur surface modification

    SciTech Connect (OSTI)

    Xu, Guigui E-mail: zghuang@fjnu.edu.cn; Zhong, Kehua; Zhang, Jian-Min; Huang, Zhigao E-mail: zghuang@fjnu.edu.cn

    2014-08-14

    We present a first-principles calculation for the electronic and Li-ion diffusion properties of the LiFePO{sub 4} (010) surface modified by sulfur. The calculated formation energy indicates that the sulfur adsorption on the (010) surface of the LiFePO{sub 4} is energetically favored. Sulfur is found to form Fe-S bond with iron. A much narrower band gap (0.67 eV) of the sulfur surface-modified LiFePO{sub 4} [S-LiFePO{sub 4} (010)] is obtained, indicating the better electronic conductive properties. By the nudged elastic band method, our calculations show that the activation energy of Li ions diffusion along the one-dimensional channel on the surface can be effectively reduced by sulfur surface modification. In addition, the surface diffusion coefficient of S-LiFePO{sub 4} (010) is estimated to be about 10{sup −11} (cm{sup 2}/s) at room temperature, which implies that sulfur modification will give rise to a higher Li ion carrier mobility and enhanced electrochemical performance.

  9. Vehicle Technologies Office Merit Review 2016: Advanced High Energy Li-Ion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell for PHEV and EV Applications | Department of Energy Advanced High Energy Li-Ion Cell for PHEV and EV Applications Vehicle Technologies Office Merit Review 2016: Advanced High Energy Li-Ion Cell for PHEV and EV Applications Presentation given by 3M at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries es210_singh_2016_o_web.pdf (1.96 MB) More Documents & Publications Vehicle Technologies Office

  10. Development of Large Format Lithium Ion Cells with Higher Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Large Format Lithium Ion Cells with Higher Energy Density Exceeding 500WhL Development of Large Format Lithium Ion Cells with Higher Energy Density Exceeding 500WhL 2012 DOE ...

  11. NANOSTRUCTURED METAL OXIDES FOR ANODES OF LI-ION RECHARGEABLE BATTERIES

    SciTech Connect (OSTI)

    Au, M.

    2009-12-04

    The aligned nanorods of Co{sub 3}O{sub 4} and nanoporous hollow spheres (NHS) of SnO{sub 2} and Mn{sub 2}O{sub 3} were investigated as the anodes for Li-ion rechargeable batteries. The Co{sub 3}O{sub 4} nanorods demonstrated 1433 mAh/g reversible capacity. The NHS of SnO{sub 2} and Mn{sub 2}O{sub 3} delivered 400 mAh/g and 250 mAh/g capacities respectively in multiple galvonastatic discharge-charge cycles. It was found that high capacity of NHS of metal oxides is sustainable attributed to their unique structure that maintains material integrity during cycling. The nanostructured metal oxides exhibit great potential as the new anode materials for Li-ion rechargeable batteries with high energy density, low cost and inherent safety.

  12. A β-VOPO4/ε-VOPO4 composite Li-ion battery cathode

    SciTech Connect (OSTI)

    Chen, Zehua; Chen, Qiyuan; Wang, Haiyan; Zhang, Ruibo; Zhou, Hui; Chen, Liquan; Whittingham, M. Stanley

    2014-09-01

    VOPO4 is an example of a Li-ion battery cathode that can achieve over 300 Ah/kg when two Li-ions are intercalated. A two phase β-VOPO4/ε-VOPO4 composite was found to improve the cycling capacity of ε-VOPO4 from tetragonal H2VOPO4, particularly as the rate is increased. In the potential range of 2.0–4.5 V, this composite showed an initial electrochemical capacity of 208 mAh/g at 0.08 mA/cm2, 190 mAh/g at 0.16 mA/cm2, and 160 mAh/g at 0.41 mA/cm2.

  13. Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford Synchrotron Radiation Lightsource Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes Sunday, January 31, 2016 Improvements in the high-voltage cycling stability of lithium ion battery cathode materials are needed to enable the wide-spread adoption of renewable energy technologies such as electric vehicles. One cathode material which exhibits significant advantages over the commonly-used commercial material LiCoO2 in terms of higher capacity, increased thermal

  14. Biphasic Electrode Suspensions for Li-Ion Semi-Solid Flow Cells with High

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Density, Fast Charge Transport, and Low-Dissipation Flow - Joint Center for Energy Storage Research June 5, 2015, Research Highlights Biphasic Electrode Suspensions for Li-Ion Semi-Solid Flow Cells with High Energy Density, Fast Charge Transport, and Low-Dissipation Flow Images for Biphasic Electrode Suspensions Scientific Achievement We created biphasic electrode suspensions composed of dispersed active particles and uniformly percolated conductive particles, different from the

  15. Degradation Mechanisms in Li-Ion Battery Electrolytes Uncovered by In-Situ

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scanning Transmission Electron Microscopy - Joint Center for Energy Storage Research 27, 2014, Research Highlights Degradation Mechanisms in Li-Ion Battery Electrolytes Uncovered by In-Situ Scanning Transmission Electron Microscopy (Top) e- beam-induced breakdown of electrolyte mixture. (Bottom Left) Two distinct degradation processes observed in the LiAsF6 in DMC electrolyte. Plots of particle diameter evolution using multitarget particle tracking for two electron doses. Once primary growth

  16. Antiperovskite Li 3 OCl superionic conductor films for solid-state Li-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lü, Xujie; Howard, John W.; Chen, Aiping; Zhu, Jinlong; Li, Shuai; Wu, Gang; Dowden, Paul; Xu, Hongwu; Zhao, Yusheng; Jia, Quanxi

    2016-02-02

    We prepared antiperovskite Li3OCl superionic conductor films via pulsed laser deposition using a composite target. A significantly enhanced ionic conductivity of 2.0 × 10-4 S cm-1 at room temperature is achieved, and this value is more than two orders of magnitude higher than that of its bulk counterpart. Moreover, the applicability of Li3OCl as a solid electrolyte for Li-ion batteries is demonstrated.

  17. Vehicle Technologies Office Merit Review 2014: Advanced High Energy Li-Ion Cell for PHEV and EV Applications

    Broader source: Energy.gov [DOE]

    Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced high energy Li-ion cell for PHEV...

  18. Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated polyethylene microspheres

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Baginska, Marta; Blaiszik, Benjamin J.; Rajh, Tijana; Sottos, Nancy R.; White, Scott R.

    2014-07-17

    Thermally triggered autonomic shutdown of a Lithium-ion (Li-ion) battery is demonstrated using polydopamine (PDA)-coated polyethylene microspheres applied onto a battery anode. The microspheres are dispersed in a buffered 10 mM dopamine salt solution and the pH is raised to initiate the polymerization and coat the microspheres. Coated microspheres are then mixed with an aqueous binder, applied onto a battery anode surface, dried, and incorporated into Li-ion coin cells. FTIR and Raman spectroscopy are used to verify the presence of the polydopamine on the surface of the microspheres. Scanning electron microscopy is used to examine microsphere surface morphology and resulting anodemore » coating quality. Charge and discharge capacity, as well as impedance, are measured for Li-ion coin cells as a function of microsphere content. Autonomous shutdown is achieved by applying 1.7 mg cm–2 of PDA-coated microspheres to the electrode. Furthermore, the PDA coating significantly reduces the mass of microspheres for effective shutdown compared to our prior work with uncoated microspheres.« less

  19. Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated polyethylene microspheres

    SciTech Connect (OSTI)

    Baginska, Marta; Blaiszik, Benjamin J.; Rajh, Tijana; Sottos, Nancy R.; White, Scott R.

    2014-07-17

    Thermally triggered autonomic shutdown of a Lithium-ion (Li-ion) battery is demonstrated using polydopamine (PDA)-coated polyethylene microspheres applied onto a battery anode. The microspheres are dispersed in a buffered 10 mM dopamine salt solution and the pH is raised to initiate the polymerization and coat the microspheres. Coated microspheres are then mixed with an aqueous binder, applied onto a battery anode surface, dried, and incorporated into Li-ion coin cells. FTIR and Raman spectroscopy are used to verify the presence of the polydopamine on the surface of the microspheres. Scanning electron microscopy is used to examine microsphere surface morphology and resulting anode coating quality. Charge and discharge capacity, as well as impedance, are measured for Li-ion coin cells as a function of microsphere content. Autonomous shutdown is achieved by applying 1.7 mg cm–2 of PDA-coated microspheres to the electrode. Furthermore, the PDA coating significantly reduces the mass of microspheres for effective shutdown compared to our prior work with uncoated microspheres.

  20. Probing the Degradation Mechanisms in Electrolyte Solutions for Li-ion Batteries by In-Situ Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Abellan Baeza, Patricia; Mehdi, Beata L.; Parent, Lucas R.; Gu, Meng; Park, Chiwoo; Xu, Wu; Zhang, Yaohui; Arslan, Ilke; Zhang, Jiguang; Wang, Chong M.; Evans, James E.; Browning, Nigel D.

    2014-02-21

    One of the goals in the development of new battery technologies is to find new electrolytes with increased electrochemical stability. In-situ (scanning) transmission electron microscopy ((S)TEM) using an electrochemical fluid cell provides the ability to rapidly and directly characterize electrode/electrolyte interfacial reactions under battery relevant electrochemical conditions. Furthermore, as the electron beam itself causes a localized electrochemical reaction when it interacts with the electrolyte, the breakdown products that occur during the first stages of battery operation can potentially be simulated and characterized using a straightforward in-situ liquid stage (without electrochemical biasing capabilities). In this paper, we have studied the breakdown of a range of inorganic/salt complexes that are used in state-of-the-art Li-ion battery systems. The results of the in-situ (S)TEM experiments matches with previous stability tests performed during battery operation and the breakdown products and mechanisms are also consistent with known mechanisms. This analysis indicates that in-situ liquid stage (S)TEM observations can be used to directly test new electrolyte designs and provide structural insights into the origin of the solid electrolyte interphase (SEI) formation mechanism.

  1. Selected test results from the neosonic polymer Li-ion battery.

    SciTech Connect (OSTI)

    Ingersoll, David T.; Hund, Thomas D.

    2010-07-01

    The performance of the Neosonic polymer Li-ion battery was measured using a number of tests including capacity, capacity as a function of temperature, ohmic resistance, spectral impedance, hybrid pulsed power test, utility partial state of charge (PSOC) pulsed cycle test, and an over-charge/voltage abuse test. The goal of this work was to evaluate the performance of the polymer Li-ion battery technology for utility applications requiring frequent charges and discharges, such as voltage support, frequency regulation, wind farm energy smoothing, and solar photovoltaic energy smoothing. Test results have indicated that the Neosonic polymer Li-ion battery technology can provide power levels up to the 10C{sub 1} discharge rate with minimal energy loss compared to the 1 h (1C) discharge rate. Two of the three cells used in the utility PSOC pulsed cycle test completed about 12,000 cycles with only a gradual loss in capacity of 10 and 13%. The third cell experienced a 40% loss in capacity at about 11,000 cycles. The DC ohmic resistance and AC spectral impedance measurements also indicate that there were increases in impedance after cycling, especially for the third cell. Cell No.3 impedance Rs increased significantly along with extensive ballooning of the foil pouch. Finally, at a 1C (10 A) charge rate, the over charge/voltage abuse test with cell confinement similar to a multi cell string resulted in the cell venting hot gases at about 45 C 45 minutes into the test. At 104 minutes into the test the cell voltage spiked to the 12 volt limit and continued out to the end of the test at 151 minutes. In summary, the Neosonic cells performed as expected with good cycle-life and safety.

  2. Transport and Failure in Li-ion Batteries | Stanford Synchrotron Radiation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lightsource Transport and Failure in Li-ion Batteries Monday, February 13, 2012 - 1:30pm SSRL Conference Room 137-322 Stephen J. Harris, General Motors R&D While battery performance is well predicted by the macrohomogeneous model of Newman and co-workers, predicting degradation and failure remains a challenge. It may be that, like most materials, failure depends on local imperfections and inhomogeneities. We use tomographic data to evaluate the homogeneity of the tortuosity of the

  3. Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries

    SciTech Connect (OSTI)

    Katiyar, Ram S; Gómez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

    2009-01-19

    Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation ‘Li-ion rechargeable battery’ and ‘LiCoO2 cathode’ is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

  4. Predicted Structure, Thermo-Mechanical Properties and Li Ion Transport in LiAlF4 Glass

    SciTech Connect (OSTI)

    Stechert, T. R.; Rushton, M. J. D.; Grimes, R. W.; Dillon, A. C.

    2012-08-15

    Materials with the LiAlF{sub 4} composition are of interest as protective electrode coatings in Li ion battery applications due to their high cationic conductivity. Here classical molecular dynamics calculations are used to produce amorphous model structures by simulating a quench from the molten state. These are analysed in terms of their individual pair correlation functions and atomic coordination environments. This indicates that amorphous LiAlF{sub 4} is formed of a network of corner sharing AlF{sub 6} octahedra. Li ions are distributed within this network, primarily associated with non-bridging fluorine atoms. The nature of the octahedral network is further analysed through intra- and interpolyhedral bond angle distributions and the relative populations of bridging and non-bridging fluorine ions are calculated. Network topology is considered through the use of ring statistics, which indicates that, although topologically well connected, LiAlF{sub 4} contains an appreciable number of corner-linked branch-like AlF{sub 6} chains. Thermal expansion values are determined above and below the predicted glass transition temperature of 1340 K. Finally, movement of Li ions within the network is examined with predictions of the mean squared displacements, diffusion coefficients and Li ion activation energy. Different regimes for lithium ion movement are identified, with both diffusive and sessile Li ions observed. For migrating ions, a typical trajectory is illustrated and discussed in terms of a hopping mechanism for Li transport.

  5. STAR FORMATION AROUND SUPERGIANT SHELLS IN THE LARGE MAGELLANIC CLOUD

    SciTech Connect (OSTI)

    Book, Laura G.; Chu Youhua; Gruendl, Robert A.; Fukui, Yasuo

    2009-03-15

    We examine the recent star formation associated with four supergiant shells in the Large Magellanic Cloud (LMC): LMC 1, 4, 5, and 6, which have been shown to have simple expanding-shell structures. H II regions and OB associations are used to infer star formation in the last few Myr, while massive young stellar objects reveal the current ongoing star formation. Distributions of ionized H I and molecular components of the interstellar gas are compared with the sites of recent and current star formation to determine whether triggering has taken place. We find that a great majority of the current star formation has occurred in gravitationally unstable regions, and that evidence of triggered star formation is prevalent at both large and local scales.

  6. PHEV/EV Li-Ion Battery Second-Use Project (Presentation)

    SciTech Connect (OSTI)

    Neubauer, J.; Pesaran, A.

    2010-04-01

    Accelerated development and market penetration of plug-in hybrid electric vehicles (PHEVs) and electric vehicles (Evs) are restricted at present by the high cost of lithium-ion (Li-ion) batteries. One way to address this problem is to recover a fraction of the battery cost via reuse in other applications after the battery is retired from service in the vehicle, if the battery can still meet the performance requirements of other energy storage applications. In several current and emerging applications, the secondary use of PHEV and EV batteries may be beneficial; these applications range from utility peak load reduction to home energy storage appliances. However, neither the full scope of possible opportunities nor the feasibility or profitability of secondary use battery opportunities have been quantified. Therefore, with support from the Energy Storage activity of the U.S. Department of Energy's Vehicle Technologies Program, the National Renewable Energy Laboratory (NREL) is addressing this issue. NREL will bring to bear its expertise and capabilities in energy storage for transportation and in distributed grids, advanced vehicles, utilities, solar energy, wind energy, and grid interfaces as well as its understanding of stakeholder dynamics. This presentation introduces NREL's PHEV/EV Li-ion Battery Secondary-Use project.

  7. A three-dimensional meso-macroscopic model for Li-Ion intercalation batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Allu, S.; Kalnaus, S.; Simunovic, S.; Nanda, J.; Turner, J. A.; Pannala, S.

    2016-06-09

    Through this study, we present a three-dimensional computational formulation for electrode-electrolyte-electrode system of Li-Ion batteries. The physical consistency between electrical, thermal and chemical equations is enforced at each time increment by driving the residual of the resulting coupled system of nonlinear equations to zero. The formulation utilizes a rigorous volume averaging approach typical of multiphase formulations used in other fields and recently extended to modeling of supercapacitors [1]. Unlike existing battery modeling methods which use segregated solution of conservation equations and idealized geometries, our unified approach can model arbitrary battery and electrode configurations. The consistency of multi-physics solution also allowsmore » for consideration of a wide array of initial conditions and load cases. The formulation accounts for spatio-temporal variations of material and state properties such as electrode/void volume fractions and anisotropic conductivities. The governing differential equations are discretized using the finite element method and solved using a nonlinearly consistent approach that provides robust stability and convergence. The new formulation was validated for standard Li-ion cells and compared against experiments. Finally, its scope and ability to capture spatio-temporal variations of potential and lithium distribution is demonstrated on a prototypical three-dimensional electrode problem.« less

  8. Fail-Safe Designs for Large Capacity Battery Systems - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Return to Search Fail-Safe Designs for Large Capacity Battery Systems United States Patent ... Design for Large Capacity Li-Ion Battery Systems Abstract: Fail-safe systems and ...

  9. Model-Based Design and Integration of Large Li-ion Battery Systems

    SciTech Connect (OSTI)

    Smith, Kandler; Kim, Gi-Heon; Santhanagopalan, Shriram; Shi, Ying; Pesaran, Ahmad; Mukherjee, Partha; Barai, Pallab; Maute, Kurt; Behrou, Reza; Patil, Chinmaya

    2015-11-17

    This presentation introduces physics-based models of batteries and software toolsets, including those developed by the U.S. Department of Energy's (DOE) Computer-Aided Engineering for Electric-Drive Vehicle Batteries Program (CAEBAT). The presentation highlights achievements and gaps in model-based tools for materials-to-systems design, lifetime prediction and control.

  10. Experimental and theoretical investigations of functionalized boron nitride as electrode materials for Li-ion batteries

    SciTech Connect (OSTI)

    Zhang, Fan; Nemeth, Karoly; Bareño, Javier; Dogan, Fulya; Bloom, Ira D.; Shaw, Leon L.

    2016-01-01

    The feasibility of synthesizing functionalized h-BN (FBN) via the reaction between molten LiOH and solid h-BN is studied for the first time and its first ever application as an electrode material in Li-ion batteries is evaluated. Density functional theory (DFT) calculations are performed to provide mechanistic understanding of the possible electrochemical reactions derived from the FBN. Various materials characterizations reveal that the melt-solid reaction can lead to exfoliation and functionalization of h-BN simultaneously, while electrochemical analysis proves that the FBN can reversibly store charges through surface redox reactions with good cycle stability and coulombic efficiency. DFT calculations have provided physical insights into the observed electrochemical properties derived from the FBN.

  11. A Combustion Chemistry Analysis of Carbonate Solvents in Li-Ion Batteries

    SciTech Connect (OSTI)

    Harris, S J; Timmons, A; Pitz, W J

    2008-11-13

    Under abusive conditions Li-ion batteries can rupture, ejecting electrolyte and other flammable gases. In this paper we consider some of the thermochemical properties of these gases that will determine whether they ignite and how energetically they burn. We show that flames of carbonate solvents are fundamentally less energetic than those of conventional hydrocarbons. An example of this difference is given using a recently developed mechanism for dimethyl carbonate (DMC) combustion, where we show that a diffusion flame burning DMC has only half the peak energy release rate of an analogous propane flame. We find a significant variation among the carbonate solvents in the factors that are important to determining flammability, such as combustion enthalpy and vaporization enthalpy. This result suggests that thermochemical and kinetic factors might well be considered when choosing solvent mixtures.

  12. Selected test results from the LiFeBatt iron phosphate Li-ion battery.

    SciTech Connect (OSTI)

    Ingersoll, David T.; Hund, Thomas D.

    2008-09-01

    In this paper the performance of the LiFeBatt Li-ion cell was measured using a number of tests including capacity measurements, capacity as a function of temperature, ohmic resistance, spectral impedance, high power partial state of charge (PSOC) pulsed cycling, pulse power measurements, and an over-charge/voltage abuse test. The goal of this work was to evaluate the performance of the iron phosphate Li-ion battery technology for utility applications requiring frequent charges and discharges, such as voltage support, frequency regulation, and wind farm energy smoothing. Test results have indicated that the LiFeBatt battery technology can function up to a 10C{sub 1} discharge rate with minimal energy loss compared to the 1 h discharge rate (1C). The utility PSOC cycle test at up to the 4C{sub 1} pulse rate completed 8,394 PSOC pulsed cycles with a gradual loss in capacity of 10 to 15% depending on how the capacity loss is calculated. The majority of the capacity loss occurred during the initial 2,000 cycles, so it is projected that the LiFeBatt should PSOC cycle well beyond 8,394 cycles with less than 20% capacity loss. The DC ohmic resistance and AC spectral impedance measurements also indicate that there were only very small changes after cycling. Finally, at a 1C charge rate, the over charge/voltage abuse test resulted in the cell venting electrolyte at 110 C after 30 minutes and then open-circuiting at 120 C with no sparks, fire, or voltage across the cell.

  13. Use of phosphoranimines to reduce organic carbonate content in Li-ion battery electrolytes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dufek, Eric J.; Klaehn, John R.; McNally, Joshua S.; Rollins, Harry W.; Jamison, David K.

    2016-05-09

    In this study, the use of phosphoranimines (PAs), a class of linear, monomeric phosphazenes, as electrolytes for Li-ion battery applications has been investigated as a route to improve safety and stability for Li-ion batteries. Of the potential PAs for use in battery applications, this work focuses on the initial synthetic preparation and analysis of N-trimethylsilyl-P,P-bis((2-methoxyethoxy)ethoxy)-P-ethylphosphoranimine (PA-5). PA-5 has high LiPF6 solubility in excess of 2 M, high thermal stability with a melting point below -80°C and high thermal stability as a neat compound to at least 250°C. As part of electrolyte blends, the inclusion of PA-5 shifts the onset ofmore » thermal degradation by close to 40°C at 35% loading and by 20°C at a 10% loading, improves the low temperature performance of the electrolyte, and when used as a primary solvent leads to increases in the flash point (by 20°C) when compared to more traditional EC:EMC blends. Cycling capabilities of full-coin cells with graphite negative electrodes and Li1+w[Ni0.5Mn0.3Co0.2]1-wO2 positive electrodes using PA-5:EC:EMC electrolyte blends are comparable with the performance seen for traditional EC:EMC blends. Analysis of the impact of the use of additives such as vinylene carbonate in PA-5:EC:EMC blended electrolyte results in enhanced capacity retention and improved coulombic efficiency.« less

  14. Statistical Design of Experiment for Li-ion Cell Formation Parameters...

    Broader source: Energy.gov (indexed) [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer ... Office: 2008 Energy Storage R&D Annual Progress Report ... Review 2015: Cell ...

  15. Statistical Design of Experiment for Li-ion Cell Formation Parameters using

    Broader source: Energy.gov (indexed) [DOE]

    Sates across the nation celebrated Weatherization Day on October 30 with guided tours and Gubernatorial proclamations. In this photo, A team of weatherization technicians perform a site demonstration in Minnesota on Weatherization Day in 2012. | Photo courtesy of WAPTAC. Sates across the nation celebrated Weatherization Day on October 30 with guided tours and Gubernatorial proclamations. In this photo, A team of weatherization technicians perform a site demonstration in Minnesota on

  16. Improved layered mixed transition metal oxides for Li-ion batteries

    SciTech Connect (OSTI)

    Doeff, Marca M.; Conry, Thomas; Wilcox, James

    2010-03-05

    Recent work in our laboratory has been directed towards development of mixed layered transition metal oxides with general composition Li[Ni, Co, M, Mn]O2 (M=Al, Ti) for Li ion battery cathodes. Compounds such as Li[Ni1/3Co1/3Mn1/3]O2 (often called NMCs) are currently being commercialized for use in consumer electronic batteries, but the high cobalt content makes them too expensive for vehicular applications such as electric vehicles (EV), plug-in hybrid electric vehicles (PHEVs), or hybrid electric vehicles (HEVs). To reduce materials costs, we have explored partial or full substitution of Co with Al, Ti, and Fe. Fe substitution generally decreases capacity and results in poorer rate and cycling behavior. Interestingly, low levels of substitution with Al or Ti improve aspects of performance with minimal impact on energy densities, for some formulations. High levels of Al substitution compromise specific capacity, however, so further improvements require that the Ni and Mn content be increased and Co correspondingly decreased. Low levels of Al or Ti substitution can then be used offset negative effects induced by the higher Ni content. The structural and electrochemical characterization of substituted NMCs is presented in this paper.

  17. Vehicle Technologies Office Merit Review 2015: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li-ion cells for...

  18. Composit, Nanoparticle-Based Anode material for Li-ion Batteries Applied in Hybrid Electric (HEV's)

    SciTech Connect (OSTI)

    Dr. Malgorzata Gulbinska

    2009-08-24

    Lithium-ion batteries are promising energy storage devices in hybrid and electric vehicles with high specific energy values ({approx}150 Wh/kg), energy density ({approx}400 Wh/L), and long cycle life (>15 years). However, applications in hybrid and electric vehicles require increased energy density and improved low-temperature (<-10 C) performance. Silicon-based anodes are inexpensive, environmentally benign, and offer excellent theoretical capacity values ({approx}4000 mAh/g), leading to significantly less anode material and thus increasing the overall energy density value for the complete battery (>500 Wh/L). However, tremendous volume changes occur during cycling of pure silicon-based anodes. The expansion and contraction of these silicon particles causes them to fracture and lose electrical contact to the current collector ultimately severely limiting their cycle life. In Phase I of this project Yardney Technical Products, Inc. proposed development of a carbon/nano-silicon composite anode material with improved energy density and silicon's cycleability. In the carbon/nano-Si composite, silicon nanoparticles were embedded in a partially-graphitized carbonaceous matrix. The cycle life of anode material would be extended by decreasing the average particle size of active material (silicon) and by encapsulation of silicon nanoparticles in a ductile carbonaceous matrix. Decreasing the average particle size to a nano-region would also shorten Li-ion diffusion path and thus improve rate capability of the silicon-based anodes. Improved chemical inertness towards PC-based, low-temperature electrolytes was expected as an additional benefit of a thin, partially graphitized coating around the active electrode material.

  19. Connecting the irreversible capacity loss in Li-ion batteries with the electronic insulating properties of solid electrolyte interphase (SEI) components.

    SciTech Connect (OSTI)

    Leung, Kevin; Lin, Yu -Xiao; Liu, Zhe; Chen, Long -Qing; Lu, Peng; Qi, Yue

    2016-01-01

    The formation and continuous growth of a solid electrolyte interphase (SEI) layer are responsible for the irreversible capacity loss of batteries in the initial and subsequent cycles, respectively. In this article, the electron tunneling barriers from Li metal through three insulating SEI components, namely Li2CO3, LiF and Li3PO4, are computed by density function theory (DFT) approaches. Based on electron tunneling theory, it is estimated that sufficient to block electron tunneling. It is also found that the band gap decreases under tension while the work function remains the same, and thus the tunneling barrier decreases under tension and increases under compression. A new parameter, η, characterizing the average distances between anions, is proposed to unify the variation of band gap with strain under different loading conditions into a single linear function of η. An analytical model based on the tunneling results is developed to connect the irreversible capacity loss, due to the Li ions consumed in forming these SEI component layers on the surface of negative electrodes. As a result, the agreement between the model predictions and experimental results suggests that only the initial irreversible capacity loss is due to the self-limiting electron tunneling property of the SEI.

  20. Connecting the irreversible capacity loss in Li-ion batteries with the electronic insulating properties of solid electrolyte interphase (SEI) components.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Leung, Kevin; Lin, Yu -Xiao; Liu, Zhe; Chen, Long -Qing; Lu, Peng; Qi, Yue

    2016-01-01

    The formation and continuous growth of a solid electrolyte interphase (SEI) layer are responsible for the irreversible capacity loss of batteries in the initial and subsequent cycles, respectively. In this article, the electron tunneling barriers from Li metal through three insulating SEI components, namely Li2CO3, LiF and Li3PO4, are computed by density function theory (DFT) approaches. Based on electron tunneling theory, it is estimated that sufficient to block electron tunneling. It is also found that the band gap decreases under tension while the work function remains the same, and thus the tunneling barrier decreases under tension and increases under compression.more » A new parameter, η, characterizing the average distances between anions, is proposed to unify the variation of band gap with strain under different loading conditions into a single linear function of η. An analytical model based on the tunneling results is developed to connect the irreversible capacity loss, due to the Li ions consumed in forming these SEI component layers on the surface of negative electrodes. As a result, the agreement between the model predictions and experimental results suggests that only the initial irreversible capacity loss is due to the self-limiting electron tunneling property of the SEI.« less

  1. ALD of Al2O3 for Highly Improved Performance in Li-Ion Batteries

    SciTech Connect (OSTI)

    Dillon, A.; Jung, Y. S.; Ban, C.; Riley, L.; Cavanagh, A.; Yan, Y.; George, S.; Lee, S. H.

    2012-01-01

    Significant advances in energy density, rate capability and safety will be required for the implementation of Li-ion batteries in next generation electric vehicles. We have demonstrated atomic layer deposition (ALD) as a promising method to enable superior cycling performance for a vast variety of battery electrodes. The electrodes range from already demonstrated commercial technologies (cycled under extreme conditions) to new materials that could eventually lead to batteries with higher energy densities. For example, an Al2O3 ALD coating with a thickness of ~ 8 A was able to stabilize the cycling of unexplored MoO3 nanoparticle anodes with a high volume expansion. The ALD coating enabled stable cycling at C/2 with a capacity of ~ 900 mAh/g. Furthermore, rate capability studies showed the ALD-coated electrode maintained a capacity of 600 mAh/g at 5C. For uncoated electrodes it was only possible to observe stable cycling at C/10. Also, we recently reported that a thin ALD Al2O3 coating with a thickness of ~5 A can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 degrees C. The ALD-coated NG electrodes displayed a 98% capacity retention after 200 charge-discharge cycles. In contrast, bare NG showed a rapid decay. Additionally, Al2O3 ALD films with a thickness of 2 to 4 A have been shown to allow LiCoO2 to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs Li/Li+. Bare LiCoO2 rapidly deteriorated in the first few cycles. The capacity fade is likely caused by oxidative decomposition of the electrolyte at higher potentials or perhaps cobalt dissolution. Interestingly, we have recently fabricated full cells of NG and LiCoO2 where we coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. We have also recently coated a binder free LiNi0.04Mn0

  2. High Rate and High Capacity Li-Ion Electrodes for Vehicular Applications

    SciTech Connect (OSTI)

    Dillon, A. C.

    2012-01-01

    Significant advances in both energy density and rate capability for Li-ion batteries are necessary for implementation in electric vehicles. We have employed two different methods to improve the rate capability of high capacity electrodes. For example, we previously demonstrated that thin film high volume expansion MoO{sub 3} nanoparticle electrodes ({approx}2 {micro}m thick) have a stable capacity of {approx}630 mAh/g, at C/2 (charge/dicharge in 2 hours). By fabricating thicker conventional electrodes, an improved reversible capacity of {approx}1000 mAh/g is achieved, but the rate capability decreases. To achieve high-rate capability, we applied a thin Al{sub 2}O{sub 3} atomic layer deposition coating to enable the high volume expansion and prevent mechanical degradation. Also, we recently reported that a thin ALD Al{sub 2}O{sub 3} coating can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 C. Additionally, Al{sub 2}O{sub 3} ALD films with a thickness of 2 to 4 {angstrom} have been shown to allow LiCoO{sub 2} to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs. Li/Li{sup +}. Capacity fade at this high voltage is generally caused by oxidative decomposition of the electrolyte or cobalt dissolution. We have recently fabricated full cells of NG and LiCoO{sub 2} and coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. In a different approach we have employed carbon single-wall nanotubes (SWNTs) to synthesize binder-free, high-rate capability electrodes, with 95 wt.% active materials. In one case, Fe{sub 3}O{sub 4} nanorods are employed as the active storage anode material. Recently, we have also employed this method to demonstrate improved conductivity and highly improved rate capability for a LiNi{sub 0.4}Mn{sub 0.4}Co{sub 0.2}O{sub 2

  3. Investigation of Path Dependence in Commercial Li-ion Cells Chosen for PHEV Duty Cycle Protocols (paper)

    SciTech Connect (OSTI)

    Kevin L. Gering

    2011-04-01

    Path dependence is emerging as a premier issue of how electrochemical cells age in conditions that are diverse and variable in the time domain. For example, lithium-ion cells in a vehicle configuration will experience a variable combination of usage and rest periods over a range of temperature and state of charge (SOC). This is complicated by the fact that some aging can actually become worse (or better) when a lithium-ion cell is idle for extended periods under calendar-life (calL) aging, as opposed to cycle-life (cycL) conditions where the cell is used within a predictable schedule. The purpose of this study is to bridge the gap between highly idealized and controlled laboratory test conditions and actual field conditions regarding PHEV applications, so that field-type aging mechanisms can be mimicked and quantified in a repeatable laboratory setting. The main parameters are the magnitude and frequency of the thermal cycling, looking at isothermal, mild, and severe scenarios. To date, little is known about Li-ion aging effects caused by thermal cycling superimposed onto electrochemical cycling, and related path dependence. This scenario is representative of what Li-ion batteries will experience in vehicle service, where upon the typical start of a HEV/PHEV, the batteries will be cool or cold, will gradually warm up to normal temperature and operate there for a time, then will cool down after the vehicle is turned off. Such thermal cycling will occur thousands of times during the projected life of a HEV/PHEV battery pack. We propose to quantify the effects of thermal cycling on Li-ion batteries using a representative chemistry that is commercially available. The secondary Li-ion cells used in this study are of the 18650 configuration, have a nominal capacity rating of 1.9 Ah, and consist of a {LiMn2O4 + LiMn(1/3)Ni(1/3)Co(1/3)O2} cathode and a graphite anode. Electrochemical cycling is based on PHEV-relevant cycle-life protocols that are a combination of charge

  4. Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management

    SciTech Connect (OSTI)

    Viswanathan, Vilayanur V; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A; Williford, Ralph E; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

    2010-06-01

    The entropy changes (ΔS) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

  5. Failure analysis of pinch-torsion tests as a thermal runaway risk evaluation method of Li-Ion Cells

    SciTech Connect (OSTI)

    Xia, Yuzhi; Li, Dr. Tianlei; Ren, Prof. Fei; Gao, Yanfei; Wang, Hsin

    2014-01-01

    Recently a pinch-torsion test is developed for safety testing of Li-ion batteries (Ren et al., J. Power Source, 2013). It has been demonstrated that this test can generate small internal short-circuit spots in the separator in a controllable and repeatable manner. In the current research, the failure mechanism is examined by numerical simulations and comparisons to experimental observations. Finite element models are developed to evaluate the deformation of the separators under both pure pinch and pinch-torsion loading conditions. It is discovered that the addition of the torsion component significantly increased the maximum principal strain, which is believed to induce the internal short circuit. In addition, the applied load in the pinch-torsion test is significantly less than in the pure pinch test, thus dramatically improving the applicability of this method to ultra-thick batteries which otherwise require heavy load in excess of machine capability. It is further found that the separator failure is achieved in the early stage of torsion (within a few degree of rotation). Effect of coefficient of friction on the maximum principal strain is also examined.

  6. Recent advances on the understanding of structural and composition evolution of LMR cathodes for Li-ion batteries

    SciTech Connect (OSTI)

    Yan, Pengfei; Zheng, Jianming; Xiao, Jie; Wang, Chong-Min; Zhang, Jiguang

    2015-06-08

    Lithium-rich, magnesium-rich (LMR) cathode materials have been regarded as one of the very promising cathodes for Li-ion battery applications. However, their practical application is still limited by several challenges, especially by their limited electrochemical stability rate capability. In this work, we present recent progresses on the understanding of the structural and composition evolution of LMR cathode materials with emphasis being placed on the correlation between structural/chemical evolution and electrochemical properties. In particular, using Li [Li0.2Ni0.2Mn0.6O2 as a typical example, we clearly illustrate the structural characteristics of the pristine materials and their dependence on the materials processing history, cycling induced structural degradation/chemical partition and their correlation with degradation of electrochemical performance. The fundamental understanding obtained in this work may also guide the design and preparation of new cathode materials based on ternary system of transitional metal oxide.

  7. Recent advances on the understanding of structural and composition evolution of LMR cathodes for Li-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yan, Pengfei; Zheng, Jianming; Xiao, Jie; Wang, Chong-Min; Zhang, Jiguang

    2015-06-08

    Lithium-rich, magnesium-rich (LMR) cathode materials have been regarded as one of the very promising cathodes for Li-ion battery applications. However, their practical application is still limited by several challenges, especially by their limited electrochemical stability rate capability. In this work, we present recent progresses on the understanding of the structural and composition evolution of LMR cathode materials with emphasis being placed on the correlation between structural/chemical evolution and electrochemical properties. In particular, using Li [Li0.2Ni0.2Mn0.6O2 as a typical example, we clearly illustrate the structural characteristics of the pristine materials and their dependence on the materials processing history, cycling induced structuralmore » degradation/chemical partition and their correlation with degradation of electrochemical performance. The fundamental understanding obtained in this work may also guide the design and preparation of new cathode materials based on ternary system of transitional metal oxide.« less

  8. 3D Thermal and Electrochemical Model for Spirally Wound Large Format Lithium-ion Batteries (Presentation)

    SciTech Connect (OSTI)

    Lee, K. J.; Kim, G. H.; Smith, K.

    2010-10-14

    In many commercial cells, long tabs at both cell sides, leading to uniform potentials along the spiral direction of wound jelly rolls, are rarely seen because of their high manufacturing cost. More often, several metal strips are welded at discrete locations along both current collector foils. With this design, the difference of electrical potentials is easily built up along current collectors in the spiral direction. Hence, the design features of the tabs, such as number, location and size, can be crucial factors for spiral-shaped battery cells. This paper presents a Li-ion battery cell model having a 3-dimensional spiral mesh involving a wound jellyroll structure. Further results and analysis will be given regarding impacts of tab location, number, and size.

  9. Screening report on cell materials for high-power Li-Ion HEV batteries.

    SciTech Connect (OSTI)

    Liu, J.; Kahaian, A.; Belharouak, I.; Kang, S.; Oliver, S.; Henriksen, S.; Amine, K.

    2003-04-24

    The Battery Technology Department at Argonne National Laboratory is a major participant in the U.S. Department of Energy's Advanced Technology Development (ATD) program. This multi-national laboratory program is dedicated to improving lithium-ion batteries for high-power HEV and FCEV applications. As part of the FreedomCAR Partnership, this program is addressing the three key barriers for high-power lithium-ion batteries: calendar life, abuse tolerance, and cost. All three of these barriers can be addressed by the choice of materials used in the cell chemistry. To date, the ATD program has developed two high-power cell chemistries, denoted our Gen 1 and Gen 2 cell chemistries. The selection of materials for use in the Gen 2 cell chemistry was based largely on reducing material cost and extending cell calendar life, relative to our Gen 1 cell chemistry. Table 1 provides a list of the materials used in our Gen 2 cell chemistry and their projected costs, when produced in large-scale quantities. In evaluating advanced materials, we have focused our efforts on materials that are lower cost than those listed in Table 1, while simultaneously offering enhanced chemical, structural, and thermal stability. Therefore, we have focused on natural graphite anode materials (having round-edge particle morphologies), cathode materials that contain more Mn and less Co and Ni (which can be produced via low-cost processes), lower cost electrode binders and/or binders that possess superior bonding properties at lower concentrations, and lower cost salts and solvents (with superior thermal and oxidation/reduction stability) for use in the electrolyte. The purpose of this report is to document the results of screening tests that were performed on a large number of advanced low-cost materials. These materials were screened for their potential to impact positively on the calendar life, safety, and/or cost of high-power lithium-ion cell chemistries, relative to our Gen 2 cell chemistry. As

  10. Nanoscale Silicon as Anode for Li-ion Batteries: The Fundamentals, Promise, and Challenges

    SciTech Connect (OSTI)

    Gu, Meng; He, Yang; Zheng, Jianming; Wang, Chong M.

    2015-09-24

    Silicon (Si), associated with its natural abundance, low discharge voltage vs. Li/Li+, and extremely high theoretical discharge capacity (~ 4200 mAh g-1,), has been extensively explored as anode for lithium ion battery. One of the key challenges for using Si as anode is the large volume change upon lithiation and delithiation, which causes a fast capacity fading. Over the last few years, dramatic progress has been made for addressing this issue. In this paper, we summarize the progress towards tailoring of Si as anode for lithium ion battery. The paper is organized such that it covers the fundamentals, the promise offered based on nanoscale designing, and the remaining challenges that need to be attacked to allow using of Si based materials as anode for battery.

  11. Low-cost flexible packaging for high-power Li-Ion HEV batteries.

    SciTech Connect (OSTI)

    Jansen, A. N.; Amine, K.; Henriksen, G. L.

    2004-06-18

    Batteries with various types of chemistries are typically sold in rigid hermetically sealed containers that, at the simplest level, must contain the electrolyte while keeping out the exterior atmosphere. However, such rigid containers can have limitations in packaging situations where the form of the battery is important, such as in hand-held electronics like personal digital assistants (PDAs), laptops, and cell phones. Other limitations exist as well. At least one of the electrode leads must be insulated from the metal can, which necessitates the inclusion of an insulated metal feed-through in the containment hardware. Another limitation may be in hardware and assembly cost, such as exists for the lithium-ion batteries that are being developed for use in electric vehicles (EVs) and hybrid electric vehicles (HEVs). The large size (typically 10-100 Ah) of these batteries usually results in electric beam or laser welding of the metal cap to the metal can. The non-aqueous electrolyte used in these batteries are usually based on flammable solvents and therefore require the incorporation of a safety rupture vent to relieve pressure in the event of overcharging or overheating. Both of these features add cost to the battery. Flexible packaging provides an alternative to the rigid container. A common example of this is the multi-layered laminates used in the food packaging industry, such as for vacuum-sealed coffee bags. However, flexible packaging for batteries does not come without concerns. One of the main concerns is the slow egress of the electrolyte solvent through the face of the inner laminate layer and at the sealant edge. Also, moisture and air could enter from the outside via the same method. These exchanges may be acceptable for brief periods of time, but for the long lifetimes required for batteries in electric/hybrid electric vehicles, batteries in remote locations, and those in satellites, these exchanges are unacceptable. Argonne National Laboratory (ANL

  12. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen Chemistry in Pristine Li1.2Ni0.2Mn0.6O2 for Li-Ion Batteries

    SciTech Connect (OSTI)

    Gu, Meng; Genc, Arda; Belharouak, Ilias; Wang, Dapeng; Amine, Khalil; Thevuthasan, Suntharampillai; Baer, Donald R.; Zhang, Jiguang; Browning, Nigel D.; Liu, Jun; Wang, Chong M.

    2013-05-14

    Li-rich layered material Li1.2Ni0.2Mn0.6O2 possesses high voltage and high specific capacity, which makes it an attractive candidate for the transportation industry and sustainable energy storage systems. The rechargeable capacity of the Li-ion battery is linked largely to the structural stability of the cathode materials during the charge-discharge cycles. However, the structure and cation distribution in pristine (un-cycled) Li1.2Ni0.2Mn0.6O2 have not yet been fully characterized. Using a combination of aberration-corrected scanning/transmission electron microscopy, X-ray dispersive energy spectroscopy (XEDS), electron energy loss spectroscopy (EELS), and complementary multislice image simulation, we have probed the crystal structure, cation/anion distribution, and electronic structure of Li1.2Ni0.2Mn0.6O2 nanoparticle. We discovered that the electronic structure and valence state of transition metal ions show significant variations, which have been identified to be attributed to the oxygen deficiency near the particle surfaces. Characterization of the nanoscale phase separation and cation ordering in the pristine material are critical for understanding the capacity and voltage fading of this material for battery application.

  13. Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries

    SciTech Connect (OSTI)

    Zhang, Linjing; Li, Ning; Wu, Borong; Xu, Hongliang; Wang, Lei; Yang, Xiao-Qing; Wu, Feng

    2015-01-14

    High-energy and high-power Li-ion batteries have been intensively pursued as power sources in electronic vehicles and renewable energy storage systems in smart grids. With this purpose, developing high-performance cathode materials is urgently needed. Here we report an easy and versatile strategy to fabricate high-rate and cycling-stable hierarchical sphered cathode Li1.2Ni0.13Mn0.54Co0.13O2, by using an ionic interfusion method. The sphere-shaped hierarchical cathode is assembled with primary nanoplates with enhanced growth of nanocrystal planes in favor of Li+ intercalation/deintercalation, such as (010), (100), and (110) planes. This material with such unique structural features exhibits outstanding rate capability, cyclability, and high discharge capacities, achieving around 70% (175 mAhg–1) of the capacity at 0.1 C rate within about 2.1 min of ultrafast charging. Such cathode is feasible to construct high-energy and high-power Li-ion batteries.

  14. Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Linjing; Li, Ning; Wu, Borong; Xu, Hongliang; Wang, Lei; Yang, Xiao-Qing; Wu, Feng

    2015-01-14

    High-energy and high-power Li-ion batteries have been intensively pursued as power sources in electronic vehicles and renewable energy storage systems in smart grids. With this purpose, developing high-performance cathode materials is urgently needed. Here we report an easy and versatile strategy to fabricate high-rate and cycling-stable hierarchical sphered cathode Li1.2Ni0.13Mn0.54Co0.13O2, by using an ionic interfusion method. The sphere-shaped hierarchical cathode is assembled with primary nanoplates with enhanced growth of nanocrystal planes in favor of Li+ intercalation/deintercalation, such as (010), (100), and (110) planes. This material with such unique structural features exhibits outstanding rate capability, cyclability, and high discharge capacities, achievingmore » around 70% (175 mAhg–1) of the capacity at 0.1 C rate within about 2.1 min of ultrafast charging. Such cathode is feasible to construct high-energy and high-power Li-ion batteries.« less

  15. The role of electronic and ionic conductivities in the rate performance of tunnel structured manganese oxides in Li-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Byles, B. W.; Palapati, N. K. R.; Subramanian, A.; Pomerantseva, E.

    2016-04-29

    Single nanowires of two manganese oxide polymorphs (α-MnO2 and todorokite manganese oxide), which display a controlled size variation in terms of their square structural tunnels, were isolated onto nanofabricated platforms using dielectrophoresis. This platform allowed for the measurement of the electronic conductivity of these manganese oxides, which was found to be higher in α-MnO2 as compared to that of the todorokite phase by a factor of similar to 46. Despite this observation of substantially higher electronic conductivity in α-MnO2, the todorokite manganese oxide exhibited better electrochemical rate performance as a Li-ion battery cathode. The relationship between this electrochemical performance, themore » electronic conductivities of the manganese oxides, and their reported ionic conductivities is discussed for the first time, clearly revealing that the rate performance of these materials is limited by their Li+ diffusivity, and not by their electronic conductivity. This result reveals important new insights relevant for improving the power density of manganese oxides, which have shown promise as a low-cost, abundant, and safe alternative for next-generation cathode materials. Moreover, the presented experimental approach is suitable for assessing a broader family of one-dimensional electrode active materials (in terms of their electronic and ionic conductivities) for both Li-ion batteries and for electrochemical systems utilizing charge-carrying ions beyond Li+.« less

  16. ESTABLISHING SUSTAINABLE US HEV/PHEV MANUFACTURING BASE: STABILIZED LITHIUM METAL POWDER, ENABLING MATERIAL AND REVOLUTIONARY TECHNOLOGY FOR HIGH ENERGY LI-ION BATTERIES

    SciTech Connect (OSTI)

    Yakovleva, Marina

    2012-12-31

    FMC Lithium Division has successfully completed the project “Establishing Sustainable US PHEV/EV Manufacturing Base: Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries”. The project included design, acquisition and process development for the production scale units to 1) produce stabilized lithium dispersions in oil medium, 2) to produce dry stabilized lithium metal powders, 3) to evaluate, design and acquire pilot-scale unit for alternative production technology to further decrease the cost, and 4) to demonstrate concepts for integrating SLMP technology into the Li- ion batteries to increase energy density. It is very difficult to satisfy safety, cost and performance requirements for the PHEV and EV applications. As the initial step in SLMP Technology introduction, industry can use commercially available LiMn2O4 or LiFePO4, for example, that are the only proven safer and cheaper lithium providing cathodes available on the market. Unfortunately, these cathodes alone are inferior to the energy density of the conventional LiCoO2 cathode and, even when paired with the advanced anode materials, such as silicon composite material, the resulting cell will still not meet the energy density requirements. We have demonstrated, however, if SLMP Technology is used to compensate for the irreversible capacity in the anode, the efficiency of the cathode utilization will be improved and the cost of the cell, based on the materials, will decrease.

  17. Induced core formation time in subcritical magnetic clouds by large-scale trans-Alfvnic flows

    SciTech Connect (OSTI)

    Kudoh, Takahiro; Basu, Shantanu E-mail: basu@uwo.ca

    2014-10-20

    We clarify the mechanism of accelerated core formation by large-scale nonlinear flows in subcritical magnetic clouds by finding a semi-analytical formula for the core formation time and describing the physical processes that lead to them. Recent numerical simulations show that nonlinear flows induce rapid ambipolar diffusion that leads to localized supercritical regions that can collapse. Here, we employ non-ideal magnetohydrodynamic simulations including ambipolar diffusion for gravitationally stratified sheets threaded by vertical magnetic fields. One of the horizontal dimensions is eliminated, resulting in a simpler two-dimensional simulation that can clarify the basic process of accelerated core formation. A parameter study of simulations shows that the core formation time is inversely proportional to the square of the flow speed when the flow speed is greater than the Alfvn speed. We find a semi-analytical formula that explains this numerical result. The formula also predicts that the core formation time is about three times shorter than that with no turbulence, when the turbulent speed is comparable to the Alfvn speed.

  18. SUPERGIANT SHELLS AND MOLECULAR CLOUD FORMATION IN THE LARGE MAGELLANIC CLOUD

    SciTech Connect (OSTI)

    Dawson, J. R.; Dickey, John M.; McClure-Griffiths, N. M.; Wong, T.; Hughes, A.; Fukui, Y.; Kawamura, A.

    2013-01-20

    We investigate the influence of large-scale stellar feedback on the formation of molecular clouds in the Large Magellanic Cloud (LMC). Examining the relationship between H I and {sup 12}CO(J = 1-0) in supergiant shells (SGSs), we find that the molecular fraction in the total volume occupied by SGSs is not enhanced with respect to the rest of the LMC disk. However, the majority of objects ({approx}70% by mass) are more molecular than their local surroundings, implying that the presence of a supergiant shell does on average have a positive effect on the molecular gas fraction. Averaged over the full SGS sample, our results suggest that {approx}12%-25% of the molecular mass in supergiant shell systems was formed as a direct result of the stellar feedback that created the shells. This corresponds to {approx}4%-11% of the total molecular mass of the galaxy. These figures are an approximate lower limit to the total contribution of stellar feedback to molecular cloud formation in the LMC, and constitute one of the first quantitative measurements of feedback-triggered molecular cloud formation in a galactic system.

  19. Optimized Operating Range for Large-Format LiFePO4/Graphite Batteries

    SciTech Connect (OSTI)

    Jiang, Jiuchun; Shi, Wei; Zheng, Jianming; Zuo, Pengjian; Xiao, Jie; Chen, Xilin; Xu, Wu; Zhang, Jiguang

    2014-06-01

    e investigated the long-term cycling performance of large format 20Ah LiFePO4/graphite batteries when they are cycled in various state-of-charge (SOC) ranges. It is found that batteries cycled in the medium SOC range (ca. 20~80% SOC) exhibit superior cycling stability than batteries cycled at both ends (0-20% or 80-100%) of the SOC even though the capcity utilized in the medium SOC range is three times as large as those cycled at both ends of the SOC. Several non-destructive techniques, including a voltage interruption approach, model-based parameter identification, electrode impedance spectra analysis, ΔQ/ΔV analysis, and entropy change test, were used to investigate the performance of LiFePO4/graphite batteries within different SOC ranges. The results reveal that batteries at the ends of SOC exhibit much higher polarization impedance than those at the medium SOC range. These results can be attributed to the significant structural change of cathode and anode materials as revealed by the large entropy change within these ranges. The direct correlation between the polarization impedance and the cycle life of the batteries provides an effective methodology for battery management systems to control and prolong the cycle life of LiFePO4/graphite and other batteries.

  20. Vehicle Technologies Office Merit Review 2014: Development of Large Format Lithium Ion Cells with Higher Energy Density

    Broader source: Energy.gov [DOE]

    Presentation given by XALT Energy LLC at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about development of large format...

  1. Formation of Large Polysulfide Complexes during the Lithium-Sulfur Battery Discharge

    SciTech Connect (OSTI)

    Wang, Bin; Alhassan, Saeed M.; Pantelides, Sokrates T

    2014-01-01

    Sulfur cathodes have much larger capacities than transition-metal-oxide cathodes used in commercial lithium-ion batteries but suffer from unsatisfactory capacity retention and long-term cyclability. Capacity degradation originates from soluble lithium polysulfides gradually diffusing into the electrolyte. Understanding of the formation and dynamics of soluble polysulfides during the discharging process at the atomic level remains elusive, which limits further development of lithium-sulfur (Li-S) batteries. Here we report first-principles molecular dynamics simulations and density functional calculations, through which the discharging products of Li-S batteries are studied. We find that, in addition to simple Li2Sn (1 n 8) clusters generated from single cyclooctasulfur (S8) rings, large Li-S clusters form by collectively coupling several different rings to minimize the total energy. At high lithium concentration, a Li-S network forms at the sulfur surfaces. The results can explain the formation of the soluble Li-S complex, such as Li2S8, Li2S6, and Li2S4, and the insoluble Li2S2 and Li2S structures. In addition, we show that the presence of oxygen impurities in graphene, particularly oxygen atoms bonded to vacancies and edges, may stabilize the lithium polysulfides that may otherwise diffuse into the electrolyte.

  2. CARMA LARGE AREA STAR FORMATION SURVEY: OBSERVATIONAL ANALYSIS OF FILAMENTS IN THE SERPENS SOUTH MOLECULAR CLOUD

    SciTech Connect (OSTI)

    Fernndez-Lpez, M.; Looney, L.; Lee, K.; Segura-Cox, D.; Arce, H. G.; Plunkett, A.; Mundy, L. G.; Storm, S.; Teuben, P. J.; Pound, M.; Isella, A.; Kauffmann, J.; Tobin, J. J.; Rosolowsky, E.; Kwon, W.; Ostriker, E.; Tassis, K.; Shirley, Y. L.

    2014-08-01

    We present the N{sub 2}H{sup +} (J = 1 ? 0) map of the Serpens South molecular cloud obtained as part of the CARMA Large Area Star Formation Survey. The observations cover 250 arcmin{sup 2} and fully sample structures from 3000 AU to 3pc with a velocity resolution of 0.16kms{sup 1}, and they can be used to constrain the origin and evolution of molecular cloud filaments. The spatial distribution of the N{sub 2}H{sup +} emission is characterized by long filaments that resemble those observed in the dust continuum emission by Herschel. However, the gas filaments are typically narrower such that, in some cases, two or three quasi-parallel N{sub 2}H{sup +} filaments comprise a single observed dust continuum filament. The difference between the dust and gas filament widths casts doubt on Herschel ability to resolve the Serpens South filaments. Some molecular filaments show velocity gradients along their major axis, and two are characterized by a steep velocity gradient in the direction perpendicular to the filament axis. The observed velocity gradient along one of these filaments was previously postulated as evidence for mass infall toward the central cluster, but these kind of gradients can be interpreted as projection of large-scale turbulence.

  3. A Novel In-situ Electrochemical Cell for Neutron Diffraction Studies of Phase Transitions in Small Volume Electrodes of Li-ion Batteries

    SciTech Connect (OSTI)

    Vadlamani, Bhaskar S; An, Ke; Jagannathan, M.; Ravi Chandran, K.

    2014-01-01

    The design and performance of a novel in-situ electrochemical cell that greatly facilitates the neutron diffraction study of complex phase transitions in small volume electrodes of Li-ion cells, is presented in this work. Diffraction patterns that are Rietveld-refinable could be obtained simultaneously for all the electrodes, which demonstrates that the cell is best suited to explore electrode phase transitions driven by the lithiation and delithiation processes. This has been facilitated by the use of single crystal (100) Si sheets as casing material and the planar cell configuration, giving improved signal-to-noise ratio relative to other casing materials. The in-situ cell has also been designed for easy assembly and to facilitate rapid experiments. The effectiveness of cell is demonstrated by tracking the neutron diffraction patterns during the charging of graphite/LiCoO2 and graphite/LiMn2O4 cells. It is shown that good quality neutron diffraction data can be obtained and that most of the finer details of the phase transitions, and the associated changes in crystallographic parameters in these electrodes, can be captured.

  4. Crystal chemical modeling of the Li ion distribution in Li{sub x}Mn{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Rohrer, C.L.; Rohrer, G.S.

    1996-12-31

    The Monte Carlo bond valence method was used to model the local atomic structure of Li{sub x}Mn{sub 2}O{sub 4} (x = 0.25 and x = 1.0). The results predict that Mn{sup +3} and Mn{sup +4} are randomly distributed at the octahedral positions and that the Mn{sup +3}-O bond distance is 2.02 {Angstrom} while the Mn{sup +4}-O distance is 1.91 {Angstrom}. As the Li content decreases, the cell contracts due to the higher concentration of shorter bonds. Based on maps that show the distribution of crystal chemically equivalent sites, we conclude that the Li ion diffusion paths go through 48f sites, that Li might be more mobile for the case of x = 1.0 than for x = 0.25 (due to the expanded cell volume), and that for x > 1, the 16c position is the most likely Li site.

  5. First-Principles Study of Novel Conversion Reactions for High-Capacity Li-Ion Battery Anodes in the Li-Mg-B-N-H System

    SciTech Connect (OSTI)

    Mason, T.H.; Graetz, J.; Liu, X.; Hong, J.; Majzoub, E.H.

    2011-07-28

    Anodes for Li-ion batteries are primarily carbon-based due to their low cost and long cycle life. However, improvements to the Li capacity of carbon anodes, LiC{sub 6} in particular, are necessary to obtain a larger energy density. State-of-the-art light-metal hydrides for hydrogen storage applications often contain Li and involve reactions requiring Li transport, and light-metal ionic hydrides are candidates for novel conversion materials. Given a set of known solid-state and gas-phase reactants, we have determined the phase diagram in the Li-Mg-B-N-H system in the grand canonical ensemble, as a function of lithium chemical potential. We present computational results for several new conversion reactions with capacities between 2400 and 4000 mAh g{sup -1} that are thermodynamically favorable and that do not involve gas evolution. We provide experimental evidence for the reaction pathway on delithiation for the compound Li{sub 4}BN{sub 3}H{sub 10}. While the predicted reactions involve multiple steps, the maximum volume increase for these materials on lithium insertion is significantly smaller than that for Si.

  6. Vehicle Technologies Office Merit Review 2014: Significant Cost Improvement of Li-ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Johnson Controls at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about significant cost improvement...

  7. Vehicle Technologies Office Merit Review 2015: Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Johnson Controls at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about significant cost improvement...

  8. Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  9. CARMA LARGE AREA STAR FORMATION SURVEY: STRUCTURE AND KINEMATICS OF DENSE GAS IN SERPENS MAIN

    SciTech Connect (OSTI)

    Lee, Katherine I.; Storm, Shaye; Mundy, Lee G.; Teuben, Peter; Pound, Marc W.; Salter, Demerese M.; Chen, Che-Yu; Fernndez-Lpez, Manuel; Looney, Leslie W.; Segura-Cox, Dominique; Rosolowsky, Erik; Arce, Hctor G.; Plunkett, Adele L.; Ostriker, Eve C.; Shirley, Yancy L.; Kwon, Woojin; Kauffmann, Jens; Tobin, John J.; Volgenau, N. H.; Tassis, Konstantinos; and others

    2014-12-20

    We present observations of N{sub 2}H{sup +} (J = 1 ? 0), HCO{sup +} (J = 1 ? 0), and HCN (J = 1 ? 0) toward the Serpens Main molecular cloud from the CARMA Large Area Star Formation Survey (CLASSy). We mapped 150 arcmin{sup 2} of Serpens Main with an angular resolution of ?7''. The gas emission is concentrated in two subclusters (the NW and SE subclusters). The SE subcluster has more prominent filamentary structures and more complicated kinematics compared to the NW subcluster. The majority of gas in the two subclusters has subsonic to sonic velocity dispersions. We applied a dendrogram technique with N{sub 2}H{sup +}(1-0) to study the gas structures; the SE subcluster has a higher degree of hierarchy than the NW subcluster. Combining the dendrogram and line fitting analyses reveals two distinct relations: a flat relation between nonthermal velocity dispersion and size, and a positive correlation between variation in velocity centroids and size. The two relations imply a characteristic depth of 0.15 pc for the cloud. Furthermore, we have identified six filaments in the SE subcluster. These filaments have lengths of ?0.2 pc and widths of ?0.03 pc, which is smaller than a characteristic width of 0.1 pc suggested by Herschel observations. The filaments can be classified into two types based on their properties. The first type, located in the northeast of the SE subcluster, has larger velocity gradients, smaller masses, and nearly critical mass-per-unit-length ratios. The other type, located in the southwest of the SE subcluster, has the opposite properties. Several YSOs are formed along two filaments which have supercritical mass per unit length ratios, while filaments with nearly critical mass-per-unit-length ratios are not associated with YSOs, suggesting that stars are formed on gravitationally unstable filaments.

  10. An Efficient Format for Nearly Constant-Time Access to Arbitrary Time Intervals in Large Trace Files

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chan, Anthony; Gropp, William; Lusk, Ewing

    2008-01-01

    A powerful method to aid in understanding the performance of parallel applications uses log or trace files containing time-stamped events and states (pairs of events). These trace files can be very large, often hundreds or even thousands of megabytes. Because of the cost of accessing and displaying such files, other methods are often used that reduce the size of the tracefiles at the cost of sacrificing detail or other information. This paper describes a hierarchical trace file format that provides for display of an arbitrary time window in a time independent of the total size of the file andmore » roughly proportional to the number of events within the time window. This format eliminates the need to sacrifice data to achieve a smaller trace file size (since storage is inexpensive, it is necessary only to make efficient use of bandwidth to that storage). The format can be used to organize a trace file or to create a separate file of annotations that may be used with conventional trace files. We present an analysis of the time to access all of the events relevant to an interval of time and we describe experiments demonstrating the performance of this file format.« less

  11. Fail Safe Design for Large Capacity Lithium-ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fail Safe Design for Large Capacity Lithium-ion Batteries NREL Commercialization & Tech Transfer Webinar March 27, 2011 Gi-Heon Kim gi-heon.kim@nrel.gov John Ireland, Kyu-Jin Lee, Ahmad Pesaran Kandler Smith kandler.smith@nrel.gov Source: A123 Source: GM NATIONAL RENEWABLE ENERGY LABORATORY Challenges for Large LIB Systems 2 * Li-ion batteries are flammable, require expensive manufacturing to reduce defects * Small-cell protection devices do not work for large systems * Difficult to detect

  12. Large Area Microcorrals and Cavity Formation on Cantilevers using a Focused Ion Beam

    SciTech Connect (OSTI)

    Saraf, Laxmikant V.; Britt, David W.

    2011-09-14

    We utilize focused ion beam (FIB) to explore various sputtering parameters to form large area microcorrals and cavities on cantilevers. Microcorrals were rapidly created by modifying ion beam blur and overlaps. Modification in FIB sputtering parameters affects the periodicity and shape of corral microstructure. Cantilever deflections show ion beam amorphization effects as a function of sputtered area and cantilever base cavities with or without side walls. The FIB sputtering parameters address a method for rapid creation of a cantilever tensiometer with integrated fluid storage and delivery.

  13. Large-diameter coiled tubing completions decrease risk of formation damage

    SciTech Connect (OSTI)

    Norton, V. ); Edens, F. ); Coker, G. ); King, G. )

    1992-07-20

    Amoco Production Co. has used large-diameter coiled tubing strings to avoid damaging gas wells with kill fluids. The coiled tubing is stripped in the gas well under pressure. In Amoco's case, the gas flows up the tubing/casing annulus. The coiled tubing string provides a way to blow down the well whenever the well loads up with liquids from completion, workover, or naturally produced fluids. This paper reports that to date, Amoco has installed coiled tubing in four wells. The oldest has 18 months of service. Although some turbine longevity questions must be answered, the first four completions have proven fast and trouble free. The basic equipment for handling coil tubing is shown. The transport trailer and tubing injector head are similar to standard servicing equipment and not considered experimental. The production tubing reel is capable of carrying 14,000 ft of 2-in tubing or 18,000 ft of 1 3/4-in. tubing. For shallower wells, multiple tubing strings can be would on the same spool. Because of handling difficulties of large tubing, spools must be wound at the factory. Most of the largest sizes are made to order, making lead time a necessary consideration.

  14. STAR FORMATION AT 4 < z < 6 FROM THE SPITZER LARGE AREA SURVEY WITH HYPER-SUPRIME-CAM (SPLASH)

    SciTech Connect (OSTI)

    Steinhardt, Charles L.; Capak, Peter; Masters, Dan; Petric, Andreea; Speagle, Josh S.; Silverman, John D.; Carollo, Marcella; Dunlop, James; Hashimoto, Yasuhiro; Hsieh, Bau-Ching; Lin, Lihwai; Lin, Yen-Ting; Le Floc'h, Emeric; Lee, Nicholas; Sanders, Dave; McCracken, Henry J.; Nagao, Tohru; Salvato, Mara; and others

    2014-08-20

    Using the first 50% of data collected for the Spitzer Large Area Survey with Hyper-Suprime-Cam observations on the 1.8deg{sup 2} Cosmological Evolution Survey we estimate the masses and star formation rates of 3398 M {sub *} > 10{sup 10} M {sub ?} star-forming galaxies at 4 < z < 6 with a substantial population up to M {sub *} ? 10{sup 11.5} M {sub ?}. We find that the strong correlation between stellar mass and star formation rate seen at lower redshift (the ''main sequence'' of star-forming galaxies) extends to z ? 6. The observed relation and scatter is consistent with a continued increase in star formation rate at fixed mass in line with extrapolations from lower-redshift observations. It is difficult to explain this continued correlation, especially for the most massive systems, unless the most massive galaxies are forming stars near their Eddington-limited rate from their first collapse. Furthermore, we find no evidence for moderate quenching at higher masses, indicating quenching either has not occurred prior to z ? 6 or else occurs rapidly, so that few galaxies are visible in transition between star-forming and quenched.

  15. Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Unocic, Raymond R; Sun, Xiao-Guang; Sacci, Robert L; Adamczyk, Leslie A; Alsem, Daan Hein; Dai, Sheng; Dudney, Nancy J; More, Karren Leslie

    2014-01-01

    Complex, electrochemically driven transport processes form the basis of electrochemical energy storage devices. The direct imaging of electrochemical processes at high spatial resolution and within their native liquid electrolyte would significantly enhance our understanding of device functionality, but has remained elusive. In this work we use a recently developed liquid cell for in situ electrochemical transmission electron microscopy to obtain insight into the electrolyte decomposition mechanisms and kinetics in lithium-ion (Li-ion) batteries by characterizing the dynamics of solid electrolyte interphase (SEI) formation and evolution. Here we are able to visualize the detailed structure of the SEI that forms locally at the electrode/electrolyte interface during lithium intercalation into natural graphite from an organic Li-ion battery electrolyte. We quantify the SEI growth kinetics and observe the dynamic self-healing nature of the SEI with changes in cell potential.

  16. CARMA Large Area Star Formation Survey: project overview with analysis of dense gas structure and kinematics in Barnard 1

    SciTech Connect (OSTI)

    Storm, Shaye; Mundy, Lee G.; Lee, Katherine I.; Teuben, Peter; Pound, Marc W.; Salter, Demerese M.; Chen, Che-Yu; Gong, Hao; Fernndez-Lpez, Manuel; Looney, Leslie W.; Segura-Cox, Dominique M.; Rosolowsky, Erik; Arce, Hctor G.; Plunkett, Adele L.; Ostriker, Eve C.; Volgenau, Nikolaus H.; Shirley, Yancy L.; Tobin, John J.; Kwon, Woojin; Isella, Andrea; and others

    2014-10-20

    We present details of the CARMA Large Area Star Formation Survey (CLASSy), while focusing on observations of Barnard 1. CLASSy is a CARMA Key Project that spectrally imaged N{sub 2}H{sup +}, HCO{sup +}, and HCN (J = 1 ? 0 transitions) across over 800 square arcminutes of the Perseus and Serpens Molecular Clouds. The observations have angular resolution near 7'' and spectral resolution near 0.16 km s{sup 1}. We imaged ?150 square arcminutes of Barnard 1, focusing on the main core, and the B1 Ridge and clumps to its southwest. N{sub 2}H{sup +} shows the strongest emission, with morphology similar to cool dust in the region, while HCO{sup +} and HCN trace several molecular outflows from a collection of protostars in the main core. We identify a range of kinematic complexity, with N{sub 2}H{sup +} velocity dispersions ranging from ?0.05 to 0.50 km s{sup 1} across the field. Simultaneous continuum mapping at 3 mm reveals six compact object detections, three of which are new detections. A new, non-binary dendrogram algorithm is used to analyze dense gas structures in the N{sub 2}H{sup +} position-position-velocity (PPV) cube. The projected sizes of dendrogram-identified structures range from about 0.01 to 0.34 pc. Size-linewidth relations using those structures show that non-thermal line-of-sight velocity dispersion varies weakly with projected size, while rms variation in the centroid velocity rises steeply with projected size. Comparing these relations, we propose that all dense gas structures in Barnard 1 have comparable depths into the sky, around 0.1-0.2 pc; this suggests that overdense, parsec-scale regions within molecular clouds are better described as flattened structures rather than spherical collections of gas. Science-ready PPV cubes for Barnard 1 molecular emission are available for download.

  17. The fabrication of foam-like 3D mesoporous NiO-Ni as anode for high performance Li-ion batteries

    SciTech Connect (OSTI)

    Huang, Peng; Zhang, Xin; Wei, Jumeng; Pan, Jiaqi; Sheng, Yingzhou; Feng, Boxue

    2015-03-15

    Graphical abstract: Foam-like 3 dimensional (3D) mesoporous NiO on 3D micro-porous Ni was fabricated. - Highlights: We prepare NiO-Ni foam composite via hydrothermal etching and subsequent annealing. The NiO exhibits novel foam-like 3D mesoporous architecture. The NiO-Ni anode shows good cycle stability. - Abstract: Foam-like three dimensional mesoporous NiO on Ni foam was fabricated via facile hydrothermal etching and subsequent annealing treatment. The porous NiO consists of a large number of nanosheets with mean thickness about 50 nm, among which a large number of mesoscopic pores with size ranges from 100 nm to 1 ?m distribute. The electrochemical performance of the as-prepared NiO-Ni as anode for lithium ion battery was studied by conventional charge/discharge test, which shows excellent cycle stability and rate capability. It exhibits initial discharge and charge capacities of 979 and 707 mA h g{sup ?1} at a charge/discharge rate of 0.7 C, which maintain of 747 and 738 mA h g{sup ?1} after 100 cycles. Even after 60 cycles at various rates from 0.06 to 14 C, the 10th discharge and charge capacities of the NiO-Ni electrode can revert to 699 and 683 mA h g{sup ?1} when lowering the charge/discharge rate to 0.06 C.

  18. Effect of fuel rate and annealing process of LiFePO{sub 4} cathode material for Li-ion batteries synthesized by flame spray pyrolysis method

    SciTech Connect (OSTI)

    Halim, Abdul; Setyawan, Heru; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng

    2014-02-24

    In this study the effect of fuel rate and annealing on particle formation of LiFePO{sub 4} as battery cathode using flame spray pyrolysis method was investigated numerically and experimentally. Numerical study was done using ANSYS FLUENT program. In experimentally, LiFePO{sub 4} was synthesized from inorganic aqueous solution followed by annealing. LPG was used as fuel and air was used as oxidizer and carrier gas. Annealing process attempted in inert atmosphere at 700C for 240 min. Numerical result showed that the increase of fuel rate caused the increase of flame temperature. Microscopic observation using Scanning Electron Microscopy (SEM) revealed that all particles have sphere and polydisperse. Increasing fuel rate caused decreasing particle size and increasing particles crystallinity. This phenomenon attributed to the flame temperature. However, all produced particles still have more amorphous phase. Therefore, annealing needed to increase particles crystallinity. Fourier Transform Infrared (FTIR) analysis showed that all particles have PO4 function group. Increasing fuel rate led to the increase of infrared spectrum absorption corresponding to the increase of particles crystallinity. This result indicated that phosphate group vibrated easily in crystalline phase. From Electrochemical Impedance Spectroscopy (EIS) analysis, annealing can cause the increase of Li{sup +} diffusivity. The diffusivity coefficient of without and with annealing particles were 6.8439910{sup ?10} and 8.5988810{sup ?10} cm{sup 2} s{sup ?1}, respectively.

  19. One-pot synthesis of a metal–organic framework as an anode for Li-ion batteries with improved capacity and cycling stability

    SciTech Connect (OSTI)

    Gou, Lei Hao, Li-Min; Shi, Yong-Xin; Ma, Shou-Long; Fan, Xiao-Yong; Xu, Lei; Li, Dong-Lin Wang, Kang

    2014-02-15

    Metal–organic framework is a kind of novel electrode materials for lithium ion batteries. Here, a 3D metal–organic framework Co{sub 2}(OH){sub 2}BDC (BDC=1,4-benzenedicarboxylate) was synthesized for the first time by the reaction of Co{sup 2+} with a bio-inspired renewable organic ligand 1,4-benzenedicarboxylic acid through a solvothermal method. As an anode material for lithium ion batteries, this material exhibited an excellent cyclic stability as well as a large reversible capacity of ca. 650 mA h g{sup −1} at a current density of 50 mA g{sup −1} after 100 cycles within the voltage range of 0.02–3.0 V, higher than that of other BDC based anode. - Graphical abstract: The PXRD pattern and the cycleability curves (inset) of Co{sub 2}(OH){sub 2}BDC. Display Omitted - Highlights: • Co{sub 2}(OH){sub 2}BDC was synthesized through a one pot solvothermal process. • The solvent had a great effect on the purity of this material. • This material was used as anode material for lithium ion batteries for the first time. • Co{sub 2}(OH){sub 2}BDC showed improved capacity and cycling stability.

  20. Materials Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid

    SciTech Connect (OSTI)

    Liu, Jun; Zhang, Jiguang; Yang, Zhenguo; Lemmon, John P.; Imhoff, Carl H.; Graff, Gordon L.; Li, Liyu; Hu, Jian Z.; Wang, Chong M.; Xiao, Jie; Xia, Guanguang; Viswanathan, Vilayanur V.; Baskaran, Suresh; Sprenkle, Vincent L.; Li, Xiaolin; Shao, Yuyan; Schwenzer, Birgit

    2013-02-15

    Large-scale electrical energy storage has become more important than ever for reducing fossil energy consumption in transportation and for the widespread deployment of intermittent renewable energy in electric grid. However, significant challenges exist for its applications. Here, the status and challenges are reviewed from the perspective of materials science and materials chemistry in electrochemical energy storage technologies, such as Li-ion batteries, sodium (sulfur and metal halide) batteries, Pb-acid battery, redox flow batteries, and supercapacitors. Perspectives and approaches are introduced for emerging battery designs and new chemistry combinations to reduce the cost of energy storage devices.

  1. GM Li-Ion Battery Pack Manufacturing

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  2. GM Li-Ion Battery Pack Manufacturing

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  3. Analysis and experimental study on formation conditions of large-scale barrier-free diffuse atmospheric pressure air plasmas in repetitive pulse mode

    SciTech Connect (OSTI)

    Li, Lee Liu, Lun; Liu, Yun-Long; Bin, Yu; Ge, Ya-Feng; Lin, Fo-Chang

    2014-01-14

    Atmospheric air diffuse plasmas have enormous application potential in various fields of science and technology. Without dielectric barrier, generating large-scale air diffuse plasmas is always a challenging issue. This paper discusses and analyses the formation mechanism of cold homogenous plasma. It is proposed that generating stable diffuse atmospheric plasmas in open air should meet the three conditions: high transient power with low average power, excitation in low average E-field with locally high E-field region, and multiple overlapping electron avalanches. Accordingly, an experimental configuration of generating large-scale barrier-free diffuse air plasmas is designed. Based on runaway electron theory, a low duty-ratio, high voltage repetitive nanosecond pulse generator is chosen as a discharge excitation source. Using the wire-electrodes with small curvature radius, the gaps with highly non-uniform E-field are structured. Experimental results show that the volume-scaleable, barrier-free, homogeneous air non-thermal plasmas have been obtained between the gap spacing with the copper-wire electrodes. The area of air cold plasmas has been up to hundreds of square centimeters. The proposed formation conditions of large-scale barrier-free diffuse air plasmas are proved to be reasonable and feasible.

  4. Nanoscale imaging of fundamental Li battery chemistry: solid-electrolyte interphase formation and preferential growth of lithium metal nanoclusters

    SciTech Connect (OSTI)

    Sacci, Robert L; Black, Jennifer M; Wisinger, Nina; Dudney, Nancy J.; More, Karren Leslie; Unocic, Raymond R

    2015-01-01

    The performance characteristics of Li-ion batteries are intrinsically linked to evolving nanoscale interfacial electrochemical reactions. To probe the mechanisms of solid electrolyte interphase formation and Li electrodeposition from a standard battery electrolyte, we use in situ electrochemical scanning transmission electron microscopy for controlled potential sweep-hold electrochemical measurements with simultaneous BF and ADF STEM image acquisition. Through a combined quantitative electrochemical measurement and quantitative STEM imaging approach, based upon electron scattering theory, we show that chemically sensitive ADF STEM imaging can be used to estimate the density of evolving SEI constituents and distinguish contrast mechanisms of Li-bearing components in the liquid cell.

  5. Nanoscale imaging of fundamental Li battery chemistry: solid-electrolyte interphase formation and preferential growth of lithium metal nanoclusters

    SciTech Connect (OSTI)

    Sacci, Robert L; Black, Jennifer M.; Wisinger, Nina; Dudney, Nancy J.; More, Karren Leslie; Unocic, Raymond R.

    2015-02-23

    The performance characteristics of Li-ion batteries are intrinsically linked to evolving nanoscale interfacial electrochemical reactions. To probe the mechanisms of solid electrolyte interphase formation and Li electrodeposition from a standard battery electrolyte, we use in situ electrochemical scanning transmission electron microscopy for controlled potential sweep-hold electrochemical measurements with simultaneous BF and ADF STEM image acquisition. Through a combined quantitative electrochemical measurement and quantitative STEM imaging approach, based upon electron scattering theory, we show that chemically sensitive ADF STEM imaging can be used to estimate the density of evolving SEI constituents and distinguish contrast mechanisms of Li-bearing components in the liquid cell.

  6. Coagulation calculations of icy planet formation around 0.1-0.5 M {sub ?} stars: Super-Earths from large planetesimals

    SciTech Connect (OSTI)

    Kenyon, Scott J.; Bromley, Benjamin C. E-mail: bromley@physics.utah.edu

    2014-01-01

    We investigate formation mechanisms for icy super-Earth-mass planets orbiting at 2-20 AU around 0.1-0.5 M {sub ?} stars. A large ensemble of coagulation calculations demonstrates a new formation channel: disks composed of large planetesimals with radii of 30-300 km form super-Earths on timescales of ?1 Gyr. In other gas-poor disks, a collisional cascade grinds planetesimals to dust before the largest planets reach super-Earth masses. Once icy Earth-mass planets form, they migrate through the leftover swarm of planetesimals at rates of 0.01-1 AU Myr{sup 1}. On timescales of 10 Myr to 1 Gyr, many of these planets migrate through the disk of leftover planetesimals from semimajor axes of 5-10 AU to 1-2 AU. A few percent of super-Earths might migrate to semimajor axes of 0.1-0.2 AU. When the disk has an initial mass comparable with the minimum-mass solar nebula, scaled to the mass of the central star, the predicted frequency of super-Earths matches the observed frequency.

  7. Early science with the large millimeter telescope: exploring the effect of AGN activity on the relationships between molecular gas, dust, and star formation

    SciTech Connect (OSTI)

    Kirkpatrick, Allison; Pope, Alexandra; Calzetti, Daniela; Narayanan, Gopal; Schloerb, F. Peter; Yun, Min S.; Aretxaga, Itziar; Montaa, Alfredo; Vega, Olga; Armus, Lee; Helou, George; Shi, Yong

    2014-12-01

    The molecular gas, H{sub 2}, that fuels star formation in galaxies is difficult to observe directly. As such, the ratio of L {sub IR} to L{sub CO}{sup ?} is an observational estimate of the star formation rate compared with the amount of molecular gas available to form stars, which is related to the star formation efficiency and the inverse of the gas consumption timescale. We test what effect an IR luminous active galactic nucleus (AGN) has on the ratio L{sub IR}/L{sub CO}{sup ?} in a sample of 24 intermediate redshift galaxies from the 5 mJy Unbiased Spitzer Extragalactic Survey (5MUSES). We obtain new CO(1-0) observations with the Redshift Search Receiver on the Large Millimeter Telescope. We diagnose the presence and strength of an AGN using Spitzer IRS spectroscopy. We find that removing the AGN contribution to L{sub IR}{sup tot} results in a mean L{sub IR}{sup SF}/L{sub CO}{sup ?} for our entire sample consistent with the mean L{sub IR}/L{sub CO}{sup ?} derived for a large sample of star forming galaxies from z ? 0-3. We also include in our comparison the relative amount of polycyclic aromatic hydrocarbon emission for our sample and a literature sample of local and high-redshift ultra luminous infrared galaxies and find a consistent trend between L{sub 6.2}/L{sub IR}{sup SF} and L{sub IR}{sup SF}/L{sub CO}{sup ?}, such that small dust grain emission decreases with increasing L{sub IR}{sup SF}/L{sub CO}{sup ?} for both local and high-redshift dusty galaxies.

  8. Characterization of Pliocene and Miocene Formations in the Wilmington Graben, Offshore Los Angeles, for Large-Scale Geologic Storage of CO₂

    SciTech Connect (OSTI)

    Bruno, Michael

    2014-12-08

    Geomechanics Technologies has completed a detailed characterization study of the Wilmington Graben offshore Southern California area for large-scale CO₂ storage. This effort has included: an evaluation of existing wells in both State and Federal waters, field acquisition of about 175 km (109 mi) of new seismic data, new well drilling, development of integrated 3D geologic, geomechanics, and fluid flow models for the area. The geologic analysis indicates that more than 796 MMt of storage capacity is available within the Pliocene and Miocene formations in the Graben for midrange geologic estimates (P50). Geomechanical analyses indicate that injection can be conducted without significant risk for surface deformation, induced stresses or fault activation. Numerical analysis of fluid migration indicates that injection into the Pliocene Formation at depths of 1525 m (5000 ft) would lead to undesirable vertical migration of the CO₂ plume. Recent well drilling however, indicates that deeper sand is present at depths exceeding 2135 m (7000 ft), which could be viable for large volume storage. For vertical containment, injection would need to be limited to about 250,000 metric tons per year per well, would need to be placed at depths greater than 7000ft, and would need to be placed in new wells located at least 1 mile from any existing offset wells. As a practical matter, this would likely limit storage operations in the Wilmington Graben to about 1 million tons per year or less. A quantitative risk analysis for the Wilmington Graben indicate that such large scale CO₂ storage in the area would represent higher risk than other similar size projects in the US and overseas.

  9. Predictions of long-term behavior of a large-volume pilot test for CO2 geological storage in a saline formation in the Central Valley, California

    SciTech Connect (OSTI)

    Doughty, Christine; Myer, Larry R.; Oldenburg, Curtis M.

    2008-11-01

    The long-term behavior of a CO{sub 2} plume injected into a deep saline formation is investigated, focusing on mechanisms that lead to plume stabilization. Key measures are plume migration distance and the time evolution of CO{sub 2} phase-partitioning, which are examined by developing a numerical model of the subsurface at a proposed power plant with CO{sub 2} capture in the San Joaquin Valley, California, where a large-volume pilot test of CO{sub 2} injection will be conducted. The numerical model simulates a four-year CO{sub 2} injection period and the subsequent evolution of the CO{sub 2} plume until it stabilizes. Sensitivity studies are carried out to investigate the effect of poorly constrained model parameters permeability, permeability anisotropy, and residual gas saturation.

  10. Star formation quenching in high-redshift large-scale structure: post-starburst galaxies in the Cl 1604 supercluster at z ∼ 0.9

    SciTech Connect (OSTI)

    Wu, Po-Feng; Gal, Roy R.; Lemaux, Brian C.; Kocevski, Dale D.; Lubin, Lori M.; Rumbaugh, Nicholas; Squires, Gordon K.

    2014-09-01

    The Cl 1604 supercluster at z ∼ 0.9 is one of the most extensively studied high-redshift large-scale structures, with more than 500 spectroscopically confirmed members. It consists of eight clusters and groups, with members numbering from a dozen to nearly a hundred, providing a broad range of environments for investigating the large-scale environmental effects on galaxy evolution. Here we examine the properties of 48 post-starburst galaxies in Cl 1604, comparing them to other galaxy populations in the same supercluster. Incorporating photometry from ground-based optical and near-infrared imaging, along with Spitzer mid-infrared observations, we derive stellar masses for all Cl 1604 members. The colors and stellar masses of the K+A galaxies support the idea that they are progenitors of red sequence galaxies. Their morphologies, residual star formation rates, and spatial distributions suggest that galaxy mergers may be the principal mechanism producing post-starburst galaxies. Interaction between galaxies and the dense intracluster medium (ICM) is also effective, but only in the cores of dynamically evolved clusters. The prevalence of post-starburst galaxies in clusters correlates with the dynamical state of the host cluster, as both galaxy mergers and the dense ICM produce post-starburst galaxies. We also investigate the incompleteness and contamination of K+A samples selected by means of Hδ and [O II] equivalent widths. K+A samples may be up to ∼50% incomplete due to the presence of LINERs/Seyferts, and up to ∼30% of K+A galaxies could have substantial star formation activity.

  11. Investigation of CO2 plume behavior for a large-scale pilot test of geologic carbon storage in a saline formation

    SciTech Connect (OSTI)

    Doughty, C.

    2009-04-01

    The hydrodynamic behavior of carbon dioxide (CO{sub 2}) injected into a deep saline formation is investigated, focusing on trapping mechanisms that lead to CO{sub 2} plume stabilization. A numerical model of the subsurface at a proposed power plant with CO{sub 2} capture is developed to simulate a planned pilot test, in which 1,000,000 metric tons of CO{sub 2} is injected over a four-year period, and the subsequent evolution of the CO{sub 2} plume for hundreds of years. Key measures are plume migration distance and the time evolution of the partitioning of CO{sub 2} between dissolved, immobile free-phase, and mobile free-phase forms. Model results indicate that the injected CO{sub 2} plume is effectively immobilized at 25 years. At that time, 38% of the CO{sub 2} is in dissolved form, 59% is immobile free phase, and 3% is mobile free phase. The plume footprint is roughly elliptical, and extends much farther up-dip of the injection well than down-dip. The pressure increase extends far beyond the plume footprint, but the pressure response decreases rapidly with distance from the injection well, and decays rapidly in time once injection ceases. Sensitivity studies that were carried out to investigate the effect of poorly constrained model parameters permeability, permeability anisotropy, and residual CO{sub 2} saturation indicate that small changes in properties can have a large impact on plume evolution, causing significant trade-offs between different trapping mechanisms.

  12. Airbrushed Nickel Nanoparticles for Large-Area

    SciTech Connect (OSTI)

    Sarac, Mehmet; ANDERSON, BRYAN; Pearce, Ryan; Railsback, Justin; Oni, Adedapo; White, Ryan M.; Hensley, Dale K; Lebeau, James M; Melechko, Anatoli; Tracy, Joseph B

    2013-01-01

    Vertically aligned carbon nanofibers (VACNFs) were grown by plasma-enhanced chemical vapor deposition (PECVD) using Ni nanoparticle (NP) catalysts that were deposited by airbrushing onto Si, Al, Cu, and Ti substrates. Airbrushing is a simple method for depositing catalyst NPs over large areas that is compatible with roll-to-roll processing. The distribution and morphology of VACNFs are affected by the airbrushing parameters and the composition of the metal foil. Highly concentrated Ni NPs in heptane give more uniform distributions than pentane and hexanes, resulting in more uniform coverage of VACNFs. For VACNF growth on metal foils, Si micropowder was added as a precursor for Si-enriched coatings formed in situ on the VACNFs that impart mechanical rigidity. Interactions between the catalyst NPs and the metal substrates impart control over the VACNF morphology. Growth of carbon nanostructures on Cu is particularly noteworthy because the miscibility of Ni with Cu poses challenges for VACNF growth, and carbon nanostructures anchored to Cu substrates are desired as anode materials for Li-ion batteries and for thermal interface materials.

  13. Observation of Electron-Beam-Induced Phase Evolution Mimicking the Effect of the ChargeDischarge Cycle in Li-Rich Layered Cathode Materials Used for Li Ion Batteries

    SciTech Connect (OSTI)

    Lu, Ping; Yan, Pengfei; Romero, Eric; Spoerke, Erik David; Zhang, Ji-Guang; Wang, Chong-Min

    2015-01-27

    Capacity loss, and voltage decrease upon electrochemical charge-discharge cycling observed in lithium-rich layered cathode oxides (Li[LixMnyTM1-x-y]O2, TM = Ni, Co or Fe) have recently been attributed to the formation of a surface reconstructed layer (SRL) that evolves from a thin (<2 nm), defect spinel layer upon the first charge, to a relatively thick (~5nm), spinel or rock-salt layer upon continuous charge-discharge cycling. Here we report observations of a SRL and structural evolution of the SRL on the Li[Li0.2Ni0.2Mn0.6]O2 (LNMO) particles, which are identical to those reported due to the charge-discharge cycle but are a result of electron-beam irradiation during scanning transmission electron microscopy (STEM) imaging. Sensitivity of the lithium-rich layered oxides to high-energy electrons leads to the formation of thin, defect spinel layer on surfaces of the particles when exposed to a 200kV electron beam for as little as 30 seconds under normal high-resolution STEM imaging conditions. Further electron irradiation produces a thicker layer of the spinel phase, ultimately producing a rock-salt layer at a higher electron exposure. Atomic-scale chemical mapping by electron dispersive X-ray spectroscopy in STEM indicates the electron-beam-induced SRL formation on LNMO is accomplished by migration of the transition metal ions to the Li sites without breaking down the lattice. The observation through this study provides an insight for understanding the mechanism of forming the SRL and also possibly a mean to study structural evolution in the Li-rich layered oxides without involving the electrochemistry.

  14. Observation of Electron-Beam-Induced Phase Evolution Mimicking the Effect of the Charge–Discharge Cycle in Li-Rich Layered Cathode Materials Used for Li Ion Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Ping; Yan, Pengfei; Romero, Eric; Spoerke, Erik David; Zhang, Ji-Guang; Wang, Chong-Min

    2015-01-27

    Capacity loss, and voltage decrease upon electrochemical charge-discharge cycling observed in lithium-rich layered cathode oxides (Li[LixMnyTM1-x-y]O2, TM = Ni, Co or Fe) have recently been attributed to the formation of a surface reconstructed layer (SRL) that evolves from a thin (<2 nm), defect spinel layer upon the first charge, to a relatively thick (~5nm), spinel or rock-salt layer upon continuous charge-discharge cycling. Here we report observations of a SRL and structural evolution of the SRL on the Li[Li0.2Ni0.2Mn0.6]O2 (LNMO) particles, which are identical to those reported due to the charge-discharge cycle but are a result of electron-beam irradiation during scanningmore » transmission electron microscopy (STEM) imaging. Sensitivity of the lithium-rich layered oxides to high-energy electrons leads to the formation of thin, defect spinel layer on surfaces of the particles when exposed to a 200kV electron beam for as little as 30 seconds under normal high-resolution STEM imaging conditions. Further electron irradiation produces a thicker layer of the spinel phase, ultimately producing a rock-salt layer at a higher electron exposure. Atomic-scale chemical mapping by electron dispersive X-ray spectroscopy in STEM indicates the electron-beam-induced SRL formation on LNMO is accomplished by migration of the transition metal ions to the Li sites without breaking down the lattice. The observation through this study provides an insight for understanding the mechanism of forming the SRL and also possibly a mean to study structural evolution in the Li-rich layered oxides without involving the electrochemistry.« less

  15. Nanoscale imaging of fundamental Li battery chemistry: solid-electrolyte interphase formation and preferential growth of lithium metal nanoclusters

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sacci, Robert L; Black, Jennifer M.; Wisinger, Nina; Dudney, Nancy J.; More, Karren Leslie; Unocic, Raymond R.

    2015-02-23

    The performance characteristics of Li-ion batteries are intrinsically linked to evolving nanoscale interfacial electrochemical reactions. To probe the mechanisms of solid electrolyte interphase formation and Li electrodeposition from a standard battery electrolyte, we use in situ electrochemical scanning transmission electron microscopy for controlled potential sweep-hold electrochemical measurements with simultaneous BF and ADF STEM image acquisition. Through a combined quantitative electrochemical measurement and quantitative STEM imaging approach, based upon electron scattering theory, we show that chemically sensitive ADF STEM imaging can be used to estimate the density of evolving SEI constituents and distinguish contrast mechanisms of Li-bearing components in the liquidmore » cell.« less

  16. 3D Printing of Interdigitated Li-Ion Microbattery Architectures...

    Office of Scientific and Technical Information (OSTI)

    of Publication: United States Language: English Subject: solar (photovoltaic), solid state lighting, phonons, thermal conductivity, electrodes - solar, materials and chemistry...

  17. Development of High Capacity Anode for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  18. Development of High Energy Cathode for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  19. Thermally Stable Electrolyte For Li-ion Cells. (Conference) ...

    Office of Scientific and Technical Information (OSTI)

    Conference held November 9-10, 2011 in Las Vegas, NV.; Related Information: Proposed for presentation at the The Knowledge Foundation's 2nd Annual International Conference held ...

  20. 2010 DOE, Li-Ion Battery Cell Manufacturing

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  1. Batteries - Next-generation Li-ion batteries Breakout session

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to enable Li-metal * Inter-digitated electrodes for improved fast-charge capability * Nano-engineered electrode films to allow for thicker films Research Suggestions * See above ...

  2. Electrolytes in Support of 5 V Li-ion Chemistries

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  3. Li-Ion Battery Cell Manufacturing | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Level 1 Charging at the Workplace (1.89 MB) More Documents & Publications Workplace Charging Presentation Workplace Charging Toolkit: Workshop Outreach Presentation Template Richmond Electric Vehicle Initiative Electric Vehicle Readiness Plan Department of Energy

    Karl Fraiser, a member of the Savannah River Special Emphasis Planning Committee, meets with Dot Harris at the site’s Women’s Equality Day Celebration. | Photo by Rob Davis, Savannah River Site. Karl Fraiser, a

  4. Anode Materials for Rechargeable Li-Ion Batteries

    SciTech Connect (OSTI)

    Fultz, B.

    2001-01-12

    This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. At present, our experimental work involves only materials for Li storage, but we have been writing papers from our previous work on hydrogen-storage materials.

  5. Lithium Source For High Performance Li-ion Cells

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  6. Lithium Source For High Performance Li-ion Cells

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  7. Automotive Li-ion Battery Cooling Requirements | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Presents thermal management of lithium-ion battery packs for electric vehicles cunningham.pdf (691.5 KB) More Documents & Publications Overview and Progress of the Battery Testing, Analysis, and Design Activity Vehicle Technologies Office Merit Review 2014: Overview and Progress of the Battery Testing, Design and Analysis Activity Overview of Battery R&D Activities

  8. GM Li-Ion Battery Pack Manufacturing | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Energy A guide to providing input to GETEM, the Geothermal Electricity Technology Evaluation Model. GETEM is designed to help the Geothermal Technologies Program of the U.S. Department of Energy in estimating some of the technical and economic values of its rese geothermal_electricity_technology_evaluation_model_2012.pdf (665.87 KB) More Documents & Publications U.S. DOE Geothermal Electricity Technology Evaluation Model (GETEM) Webinar Presentation GETEM -Geothermal Electricity

  9. GM Li-Ion Battery Pack Manufacturing | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation arravt005_es_trumm_2011_p.pdf (783.35 KB

  10. Predictive Models of Li-ion Battery Lifetime (Presentation) ...

    Office of Scientific and Technical Information (OSTI)

    Opportunities for extending the lifetime of commercial battery systems are explored. Authors: Smith, K. ; Wood, E. ; Santhanagopalan, S. ; Kim, G. ; Shi, Y. ; Pesaran, A. ...

  11. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Broader source: Energy.gov (indexed) [DOE]

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting arravt007esconner2012p.pdf (11.41 MB) More Documents & ...

  12. Degradation Reactions in SONY-Type Li-Ion Batteries

    SciTech Connect (OSTI)

    Nagasubramanian, G.; Roth, E. Peter

    1999-05-04

    Thermal instabilities were identified in SONY-type lithium-ion cells and correlated with interactions of cell constituents and reaction products. Three temperature regions of interaction were identified and associated with the state of charge (degree of Li intercalation) of the cell. Anodes were shown to undergo exothermic reactions as low as 100°C involving the solid electrolyte interface (SEI) layer and the LiPF6 salt in the electrolyte (EC: PC: DEC/LiPF6). These reactions could account for the thermal runaway observed in these cells beginning at 100°C. Exothermic reactions were also observed in the 200°C-300°C region between the intercalated lithium anodes, the LiPF6 salt and the PVDF. These reactions were followed by a high- temperature reaction region, 300°C-400°C, also involving the PVDF binder and the intercalated lithium anodes. The solvent was not directly involved in these reactions but served as a moderator and transport medhun. Cathode exotherrnic reactions with the PVDF binder were observed above 200oC and increased with the state of charge (decreasing Li content). This offers an explanation for the observed lower thermal runaway temperatures for charged cells.

  13. Polymer electrolytes for a rechargeable li-Ion battery

    SciTech Connect (OSTI)

    Argade, S.D.; Saraswat, A.K.; Rao, B.M.L.; Lee, H.S.; Xiang, C.L.; McBreen, J.

    1996-10-01

    Lithium-ion polymer electrolyte battery technology is attractive for many consumer and military applications. A Li{sub x}C/Li{sub y}Mn{sub 2}O{sub 4} battery system incorporating a polymer electrolyte separator base on novel Li-imide salts is being developed under sponsorship of US Army Research Laboratory (Fort Monmouth NJ). This paper reports on work currently in progress on synthesis of Li-imide salts, polymer electrolyte films incorporating these salts, and development of electrodes and cells. A number of Li salts have been synthesized and characterized. These salts appear to have good voltaic stability. PVDF polymer gel electrolytes based on these salts have exhibited conductivities in the range 10{sup -4} to 10{sub -3} S/cm.

  14. Electrolytes and Separators for High Voltage Li Ion Cells

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  15. Investigation of critical parameters in Li-ion battery electrodes...

    Broader source: Energy.gov (indexed) [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es070cabana2011o.pdf More Documents & Publications ...

  16. Electrolytes and Separators for High Voltage Li Ion Cells

    Office of Energy Efficiency and Renewable Energy (EERE)

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  17. Investigation of critical parameters in Li-ion battery electrodes

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  18. Electrolytes and Separators for High Voltage Li Ion Cells

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  19. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C.

  20. Li-ion Batteries and Beyond George Crabtree

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low-Level Radiation Research Letter on Low-Level Radiation Research The Secretary of Energy Advisory Board (SEAB) transmitted a letter to the Department regarding its perspective on how DOE should pursue research on low-level radiation. SEAB recommends DOE continue to sponsor a small, sustained, high quality research program primarily in DOE laboratories as well as centers of excellence within universities, medical schools, and hospitals. SEAB Letter on Low-Level Radiation Research (73.09 KB)

  1. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  2. Searching for Sustainable and "Greener" Li-ion Batteries

    ScienceCinema (OSTI)

    Tarascon, Jean-Marie [University of Picardie at Aimens, France

    2010-01-08

    Lithium-ion batteries are strong candidates for powering upcoming generations of hybrid electric vehicles and plug-in hybrid electric vehicles. But improvements in safety must be achieved while keeping track of materials resources and abundances, as well as materials synthesis and recycling processes, all of which could inflict a heavy energy cost. Thus, electrode materials that have a minimum footprint in nature and are made via eco-efficient processes are sorely needed. The arrival of electrode materials based on minerals such as LiFePO4 (tryphilite) is a significant, but not sufficient, step toward the long-term demand for materials sustainability. The eco-efficient synthesis of LiFePO4 nanopowders via hydrothermal/ solvo-thermal processes using latent bases, structure directing templates, or other bio-related approaches will be presented in this talk. However, to secure sustainability and greeness, organic electrodes appear to be ideal candidates.... We took a fresh look at organic based electrodes; the results of this research into sequentially metal-organic-framework electrodes and Li-based organic electrodes (LixCyOz) will be reported and discussed.

  3. First-Principles Calculations, Electrochemical and X-ray Absorption Studies of Li-Ni-PO4 Surface-Treated xLi2MnO3 (1 x)LiMO2 (M = Mn, Ni, Co) Electrodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Wolverton, Christopher; Croy, J R; Balasubramanian, M; Kang, Sun-Ho; Lopez-Rivera, C. M.; Thackeray, Michael M.

    2012-01-01

    It has been previously hypothesized that the enhanced rate capability of Li-Ni-PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} positive electrodes (M = Mn, Ni, Co) in Li-ion batteries might be associated with a defect Ni-doped Li{sub 3}PO{sub 4} surface structure [i.e., Li{sub 3-2y}Ni{sub y}PO{sub 4} (0 < y < 1)], thereby promoting fast Li{sup +}-ion conduction at the xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} particle surface. In this paper, the solubility of divalent metals (Fe, Mn, Ni, Mg) in {gamma}-Li{sub 3}PO{sub 4} is predicted with the first-principles GGA+U method in an effort to understand the enhanced rate capability. The predicted solubility (x) is extremely small; this finding is consistent with experimental evidence: 1) X-ray diffraction data obtained from Li-Ni-PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} electrodes that show that, after annealing at 550 C, a Li{sub 3}PO{sub 4}-like structure forms as a second phase at the electrode particle surface, and 2) X-ray absorption spectroscopy, which indicate that the nickel ions are accommodated in the transition metal layers of the Li{sub 2}MnO{sub 3} component during the annealing process. However, electrochemical studies of Li{sub 3-2y}Ni{sub y}PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} electrodes indicate that their rate capability increases as a function of y over the range y = 0 (Li{sub 3}PO{sub 4}) to y = 1 (LiNiPO{sub 4}), strongly suggesting that, at some level, the nickel ions play a role in reducing electrochemical impedance and increasing electrode stability at the electrode particle surface.

  4. CX-009182: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    (0675-1536) Oak Ridge National Laboratory -Temperature Self-Regulation for Large Format Li-ion Cells CX(s) Applied: B3.6 Date: 08/29/2012 Location(s): Tennessee, California Offices(s): Advanced Research Projects Agency-Energy

  5. Celgard and Entek - Battery Separator Development | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. es_08_tataria.pdf (2.24 MB) More Documents & Publications USABC Battery Separator Development Overview and Progress of United States Advanced Battery Consortium (USABC) Activity Multifunctional, Inorganic-Filled Separators for Large Format, Li-ion Batteries

  6. Sparse Image Format

    Energy Science and Technology Software Center (OSTI)

    2007-04-12

    The Sparse Image Format (SIF) is a file format for storing spare raster images. It works by breaking an image down into tiles. Space is savid by only storing non-uniform tiles, i.e. tiles with at least two different pixel values. If a tile is completely uniform, its common pixel value is stored instead of the complete tile raster. The software is a library in the C language used for manipulating files in SIF format. Itmore » supports large files (> 2GB) and is designed to build in Windows and Linux environments.« less

  7. Particulate Formation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  8. Formation testers

    SciTech Connect (OSTI)

    Brieger, E.

    1980-07-01

    A description is given of a method for use in obtaining multiple pressure tests of an earth formation traversed by a well bore by use of a sidewall fluid sampler well tool which has a fluid pressure sampling chamber in the well tool in open fluid communication with a pad sealing means, comprising the steps of: for one selected level in a well bore, moving a pad sealing means on the well tool into engagement with the wall of a well bore and isolating a wall segment of the earth formation; after the pad sealing means engges the wall segment of the earth formation, generating a hydraulic pressure in the well tool and applying said hydraulic pressure to said fluid pressure sampling chamber for increasing the volume of said fluid pressure sampling chamber thereby to dray a fluid sample from the earth formation engaged by the pad sealing means into the fluid pressure sampling chamber, sensing the pressure of said fluid sample as it is drawn into the fluid pressure sampling chamber while the volume of the sampling chamber is being increased, relieving the hydraulic pressure in the well tool with respect to said fluid pressur sampling chamber for decreasing the volume of said fluid pressure sampling chamber thereby to contact the sampling chamber to dischrge the fluid sample through the pad sealing means; retracting the sealing pad means and, after retrction of sealing pad means from engagement from the wall of the well bore, moving the well tool to a second location at another level in the well bore and, at the second location, repeating the steps of the method performed at the one selected level for obtaining another fluid sample and pressure sensing at said second location.

  9. Kent_AIMD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Partial radial-distribution of Li- ion with the carbonyl oxygen of ethylene carbonate (EC) and propylene carbonate (PC) from AIMD simulations. In both cases the first solvation shell of the Li-ion has 4 EC or PC molecules, consistent with experiment. Figure from Ref. 1. FIRST Center Research Perspective: AIMD Simulations of Li-ion Battery Electrolytes and Incipient SEI formation Paul R. C. Kent, P. Ganesh, D. Jiang Oak Ridge National Laboratory Research Summary: Using ab initio molecular

  10. Formation testers

    SciTech Connect (OSTI)

    Brieger, E.F.

    1981-09-08

    A formation tester apparatus is disclosed for use in a well bore for multiple testing of pressures of earth formation fluids and the taking of a fluid sample. Pad and shoe means are selectively operable for sealingly engaging a well bore. Upon sealing engagement of the pad with the wall of a well bore, a fluid sample is ingested into an expanding chamber while its pressure is sensed. Upon completion of the pressure test, the pad is retracted from the wall of a well bore, and the expanding chamber contracts to expel the fluid sample. The pressure test may be repeated any number of times. The expanding chamber includes a piston operated with fluid pressure used to actuate the pad. A choke delays the application of pressure to the piston until after the pad seals on the wall of the well bore. When a fluid sample is desired, the fluid pressure used to actuate the pad is increased to operate a first valve which connects the pad of a water cushion sampling chamber. After a fluid sample is collected, the fluid pressure is further increased to operate a second valve which closes off the sampling chamber. When the formations are unconsolidated a slidable probe in the pad extends outwardly into the wall and forms a mechanical filter. When the probe retracts the filter is self-cleaning.

  11. Formation, characterization and dynamics of onion like carbon structures from nanodiamonds using reactive force-fields for electrical energy storage

    SciTech Connect (OSTI)

    Ganesh, Panchapakesan; Kent, Paul R; Mochalin, Vadym N

    2011-01-01

    We simulate the experimentally observed graphitization of nanodiamonds into multi-shell onion-like carbon nanostructures, also called carbon onions, at different temperatures, using reactive force fields. The simulations include long-range Coulomb and van der Waals interactions. Our results suggest that long-range interactions play a crucial role in the phase-stability and the graphitization process. Graphitization is both enthalpically and entropically driven and can hence be controlled with temperature. The outer layers of the nanodiamond have a lower kinetic barrier toward graphitization irrespective of the size of the nanodiamond and graphitize within a few-hundred picoseconds, with a large volume increase. The inner core of the nanodiamonds displays a large size-dependent kinetic barrier, and graphitizes much more slowly with abrupt jumps in the internal energy. It eventually graphitizes by releasing pressure and expands once the outer shells have graphitized. The degree of transformation at a particular temperature is thereby determined by a delicate balance between the thermal energy, long-range interactions, and the entropic/enthalpic free energy gained by graphitization. Upon full graphitization, a multi-shell carbon nanostructure appears, with a shell-shell spacing of about {approx}3.4 {angstrom} for all sizes. The shells are highly defective with predominantly five- and seven-membered rings to curve space. Larger nanodiamonds with a diameter of 4 nm can graphitize into spiral structures with a large ({approx}29-atom carbon ring) pore opening on the outermost shell. Such a large one-way channel is most attractive for a controlled insertion of molecules/ions such as Li ions, water, or ionic liquids, for increased electrochemical capacitor or battery electrode applications.

  12. Formation, characterization, and dynamics of onion-like carbon structures for electrical energy storage from nanodiamonds using reactive force fields

    SciTech Connect (OSTI)

    Ganesh, P.; Kent, P. R. C.; Mochalin, V.

    2011-10-01

    We simulate the experimentally observed graphitization of nanodiamonds into multi-shell onion-like carbonnanostructures, also called carbon onions, at different temperatures, using reactive force fields. The simulations include long-range Coulomb and van der Waals interactions. Our results suggest that long-range interactions play a crucial role in the phase-stability and the graphitization process. Graphitization is both enthalpically and entropically driven and can hence be controlled with temperature. The outer layers of the nanodiamond have a lower kinetic barrier toward graphitization irrespective of the size of the nanodiamond and graphitize within a few-hundred picoseconds, with a large volume increase. The inner core of the nanodiamonds displays a large size-dependent kinetic barrier, and graphitizes much more slowly with abrupt jumps in the internal energy. It eventually graphitizes by releasing pressure and expands once the outer shells have graphitized. The degree of transformation at a particular temperature is thereby determined by a delicate balance between the thermal energy, long-range interactions, and the entropic/enthalpic free energy gained by graphitization. Upon full graphitization, a multi-shell carbonnanostructure appears, with a shell-shell spacing of about ~3.4 for all sizes. The shells are highly defective with predominantly five- and seven-membered rings to curve space. Larger nanodiamonds with a diameter of 4 nm can graphitize into spiral structures with a large (~29-atom carbon ring) pore opening on the outermost shell. Such a large one-way channel is most attractive for a controlled insertion of molecules/ions such as Li ions, water, or ionic liquids, for increased electrochemical capacitor or battery electrode applications.

  13. Multifunctional, Inorganic-Filled Separators for Large Format...

    Broader source: Energy.gov (indexed) [DOE]

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es008pekala2012

  14. Multifunctional, Inorganic-Filled Separators for Large Format...

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es008pekala2011

  15. The Relationship of the Nail Penetration Test to Safety of Li-Ion Cells

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  16. Vehicle Technologies Office Merit Review 2016: High Energy Anode Material Development for Li-Ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Sinode Systems at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  17. Vehicle Technologies Office Merit Review 2015: High Energy Anode Material Development for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Sinode Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy anode material...

  18. Model-Experimental Studies on Next-generation Li-ion Materials

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  19. Numerical and Experimental Investigation of Internal Short Circuit in a Li-ion Cell

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  20. Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery...

    Office of Scientific and Technical Information (OSTI)

    The half-wave potential (E12) for oxidation of VEC is ca. 3.6 V producing a resistive film on the electrode surface. GPC analysis of the film on a gold electrode produced by ...

  1. Model-Experimental Studies on Next-generation Li-ion Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es086srinivasan2010p.pdf More...

  2. Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  3. Studies on the thermal breakdown of common Li-ion battery electrolyte components

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lamb, Joshua; Orendorff, Christopher J.; Roth, Emanuel Peter; Langendorf, Jill Louise

    2015-08-06

    While much attention is paid to the impact of the active materials on the catastrophic failure of lithium ion batteries, much of the severity of a battery failure is also governed by the electrolytes used, which are typically flammable themselves and can decompose during battery failure. The use of LiPF6 salt can be problematic as well, not only catalyzing electrolyte decomposition, but also providing a mechanism for HF production. This work evaluates the safety performance of the common components ethylene carbonate (EC), diethyl carbonate (DEC), dimethyl carbonate (DMC), and ethyl methyl carbonate (EMC) in the context of the gasses producedmore » during thermal decomposition, looking at both the quantity and composition of the vapor produced. EC and DEC were found to be the largest contributors to gas production, both producing upwards of 1.5 moles of gas/mole of electrolyte. DMC was found to be relatively stable, producing very little gas regardless of the presence of LiPF6. EMC was stable on its own, but the addition of LiPF6 catalyzed decomposition of the solvent. As a result, while gas analysis did not show evidence of significant quantities of any acutely toxic materials, the gasses themselves all contained enough flammable components to potentially ignite in air.« less

  4. Studies on the thermal breakdown of common Li-ion battery electrolyte components

    SciTech Connect (OSTI)

    Lamb, Joshua; Orendorff, Christopher J.; Roth, Emanuel Peter; Langendorf, Jill Louise

    2015-08-06

    While much attention is paid to the impact of the active materials on the catastrophic failure of lithium ion batteries, much of the severity of a battery failure is also governed by the electrolytes used, which are typically flammable themselves and can decompose during battery failure. The use of LiPF6 salt can be problematic as well, not only catalyzing electrolyte decomposition, but also providing a mechanism for HF production. This work evaluates the safety performance of the common components ethylene carbonate (EC), diethyl carbonate (DEC), dimethyl carbonate (DMC), and ethyl methyl carbonate (EMC) in the context of the gasses produced during thermal decomposition, looking at both the quantity and composition of the vapor produced. EC and DEC were found to be the largest contributors to gas production, both producing upwards of 1.5 moles of gas/mole of electrolyte. DMC was found to be relatively stable, producing very little gas regardless of the presence of LiPF6. EMC was stable on its own, but the addition of LiPF6 catalyzed decomposition of the solvent. As a result, while gas analysis did not show evidence of significant quantities of any acutely toxic materials, the gasses themselves all contained enough flammable components to potentially ignite in air.

  5. Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  6. Vehicle Technologies Office Merit Review 2014: Metal-Based High Capacity Li-Ion Anodes

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Binghamton University-SUNY at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about metal-based high...

  7. Biphasic Electrode Suspensions for Li-Ion Semi-solid Flow Cells...

    Office of Scientific and Technical Information (OSTI)

    and Low-Dissipation Flow Authors: Wei, Teng-Sing ; Fan, Frank Y. ; Helal, Ahmed ; Smith, Kyle C. ; McKinley, Gareth H. ; Chiang, Yet-Ming ; Lewis, Jennifer A. 1 ; MIT) 2...

  8. Hard Carbon Materials for High-Capacity Li-ion Battery Anodes | Department

    Office of Environmental Management (EM)

    Harbec: A Fifteen Year Journey to the Beginning Harbec: A Fifteen Year Journey to the Beginning This presentation by HARBEC, Inc. at the 2014 Energy Summit in Niagara Falls, Ontario. discusses the company's progress over 15 years taking advantage of eco-economic opportunities by implementing an ISO 50001 Energy Management System and participating the Superior Energy Performance® (SEP(tm)) program. 15 Year Pursuit of Sustainable Manufacturing, 2014 (2.26 MB) More Documents & Publications

  9. Source fabrication and lifetime for Li+ ion beams extracted from alumino-silicate sources

    SciTech Connect (OSTI)

    Roy, Prabir K.; Greenway, Wayne G.; Kwan, Joe W

    2012-03-05

    A space-charge-limited beam with current densities (J) exceeding 1 mA/cm{sup 2} have been measured from lithium alumino-silicate ion sources at a temperature of #24;~1275#14;{degrees} C. At higher extraction voltages, the source appears to become emission limited with J #21;{>=} 1.5 mA/cm{sup 2}, and J increases weakly with the applied voltage. A 6.35 mm diameter source with an alumino-silicate coating, {<=}#20;0.25 mm thick, has a measured lifetime of ~#24;40 hours at ~#24;1275#14;{degrees} C, when pulsed at 0.05 Hz and with pulse length of #24;~6 μs each. At this rate, the source lifetime was independent of the actual beam charge extracted due to the loss of neutral atoms at high temperature. The source lifetime increases with the amount of alumino-silicate coated on the emitting surface, and may also be further extended if the temperature is reduced between pulses.

  10. Probing the failure mechanism of nanoscale LiFePO₄ for Li-ion batteries

    SciTech Connect (OSTI)

    Gu, Meng; Shi, Wei; Zheng, Jianming; Yan, Pengfei; Zhang, Ji-guang; Wang, Chongmin

    2015-05-18

    LiFePO4 is a high power rate cathode material for lithium ion battery and shows remarkable capacity retention, featuring a 91% capacity retention after 3300 cycles. In this work, we use high-resolution transmission electron microscopy (HRTEM), energy dispersive x-ray spectroscopy (EDS), and electron energy loss spectroscopy (EELS) to study the gradual capacity fading mechanism of LiFePO4 materials. We found that upon prolonged electrochemical cycling of the battery, the LiFePO4 cathode shows surface amorphization and loss of oxygen species, which directly contribute to the gradual capacity fading of the battery. The finding is of great importance for the design and improvement of new LiFePO4 cathode for high-energy and high-power rechargeable battery for electric transportation.

  11. Li-Ion polymer cells thermal property changes as a function of cycle-life

    SciTech Connect (OSTI)

    Maleki, Hossein; Wang, Hsin; Porter, Wallace D; Hallmark, Jerry

    2014-01-01

    The impact of elevated temperature chargeedischarge cycling on thermal conductivity (K-value) of Lithium Ion Polymer (LIP) cells of various chemistries from three different manufacturers was investigated. These included high voltage (Graphite/LiCoO2:3.0e4.35 V), wide voltage (Si:C/LiCoO2:2.7e4.35 V) and conventional (Graphite/LiCoO2:3.0e4.2 V) chemistries. Investigation results show limited variability within the in-plane and through-plane K-values for the fresh cells with graphite-based anodes from all three suppliers. After 500 cycles at 45 C, in-plane and through-plane K-values of the high voltage cells reduced less vs. those for the wide voltage cells. Such results suggest that high temperature cycling could have a greater impact on thermal properties of Si:C cells than on the LIP cells with graphite (Gr) anode cells we tested. This difference is due to the excess swelling of Si:C-anode based cells vs. Gr-anode cells during cycling, especially at elevated temperatures. Thermal modeling is used to evaluate the impact of K-value changes, due to cycles at 45 C, on the cells internal heat propagation under internal short circuit condition that leads to localized meltdown of the separator.

  12. Materials cost evaluation report for high-power Li-ion batteries.

    SciTech Connect (OSTI)

    Henriksen, G. L.; Amine, K.; Liu, J.

    2003-01-10

    The U.S. Department of Energy (DOE) is the lead federal agency in the partnership between the U.S. automobile industry and the federal government to develop fuel cell electric vehicles (FCEVs) and hybrid electric vehicles (HEVs) as part of the FreedomCAR Partnership. DOE's FreedomCAR and Vehicle Technologies Office sponsors the Advanced Technology Development (ATD) Program--involving 5 of its national laboratories--to assist the industrial developers of high-power lithium-ion batteries to overcome the barriers of cost, calendar life, and abuse tolerance so that this technology can be rendered practical for use in HEV and FCEV applications under the FreedomCAR Partnership. In the area of cost reduction, Argonne National Laboratory (ANL) is working to identify and develop advanced anode, cathode, and electrolyte components that can significantly reduce the cost of the cell chemistry, while simultaneously extending the calendar life and enhancing the inherent safety of this electrochemical system. The material cost savings are quantified and tracked via the use of a cell and battery design model that establishes the quantity of each material needed in the production of batteries that are designed to meet the requirements of a minimum-power-assist HEV battery or a maximum-power-assist HEV battery for the FreedomCAR Partnership. Similar models will be developed for FEV batteries when the requirements for those batteries are finalized. In order to quantify the material costs relative to the FreedomCAR battery cost goals, ANL uses (1) laboratory cell performance data, (2) its battery design model and (3) battery manufacturing process yields to create battery-level material cost models. Using these models and industry-supplied material cost information, ANL assigns battery-level material costs for different cell chemistries. These costs can then be compared with the battery cost goals to determine the probability of meeting the goals with these cell chemistries. As can be seen from the results of this materials cost study, a cell chemistry based on the use of a LiMn{sub 2}O{sub 4} cathode material is lowest-cost and meets our battery-level material cost goal of <$250 for a 25-kW minimum-power-assist HEV battery. A major contributing factor is the high-rate capability of this material, which allows one to design a lower-capacity cell to meet the battery-level power and energy requirements. This reduces the quantities of the other materials needed to produce a 25-kW minimum-power-assist HEV battery. The same is true for the 40-kW maximum-power-assist HEV battery. Additionally, the LiMn{sub 2}O{sub 4} cathode is much more thermally and chemically stable than the LiNi{sub 0.8}Co{sub 0.2}O{sub 2} type cathode, which should enhance inherent safety and extend calendar life (if the LiMn{sub 2}O{sub 4} cathode can be stabilized against dissolution via HF attack). Therefore, we recommend that the FreedomCAR Partnership focus its research and development efforts on developing this type of low-cost high-power lithium-ion cell chemistry. Details supporting this recommendation are provided in the body of this report.

  13. Eddy current sensor for in-situ monitoring of swelling of Li-ion prismatic cells

    SciTech Connect (OSTI)

    Plotnikov, Yuri Karp, Jason Knobloch, Aaron Kapusta, Chris Lin, David

    2015-03-31

    In-situ monitoring an on-board rechargeable battery in hybrid cars can be used to ensure a long operating life of the battery and safe operation of the vehicle. Intercalations of ions in the electrode material during charge and discharge of a Lithium Ion battery cause periodic stress and strain of the electrode materials that can ultimately lead to fatigue resulting in capacity loss and potential battery failure. Currently this process is not monitored directly on the cells. This work is focused on development technologies that would quantify battery swelling and provide in-situ monitoring for onboard vehicle applications. Several rounds of tests have been performed to spatially characterize cell expansion of a 5 Ah cell with a nickel/manganese/cobalt-oxide cathode (Sanyo, Japan) used by Ford in their Fusion HEV battery pack. A collaborative team of researchers from GE and the University of Michigan has characterized the free expansion of these cells to be in the range of 100×125 microns (1% of total cell thickness) at the center point of the cell. GE proposed to use a thin eddy current (EC) coil to monitor these expansions on the cells while inside the package. The photolithography manufacturing process previously developed for EC arrays for detecting cracks in aircraft engine components was used to build test coils for gap monitoring. These sensors are thin enough to be placed safely between neighboring cells and capable of monitoring small variations in the gap between the cells. Preliminary investigations showed that these coils can be less than 100 micron thick and have sufficient sensitivity in a range from 0 to 2 mm. Laboratory tests revealed good correlation between EC and optical gap measurements in the desired range. Further technology development could lead to establishing a sensor network for a low cost solution for the in-situ monitoring of cell swelling during battery operation.

  14. Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery...

    Office of Scientific and Technical Information (OSTI)

    Authors: Chen, Guoying ; Zhuang, Guorong V. ; Richardson, Thomas J. ; Gao, Liu ; Ross Jr., Philip N. Publication Date: 2005-02-28 OSTI Identifier: 861305 Report Number(s): ...

  15. Thermal Stability of LiPF6 Salt and Li-ion Battery Electrolytes...

    Office of Scientific and Technical Information (OSTI)

    Authors: Yang, Hui ; Zhuang, Guorong V ; Ross, Jr, Philip N Publication Date: 2006-03-08 OSTI Identifier: 898281 Report Number(s): LBNL--58758 Journal ID: ISSN 0378-7753; JPSODZ; ...

  16. Model-Experimental Studies on Next-generation Li-ion Materials | Department

    Broader source: Energy.gov (indexed) [DOE]

    Performance | Department of Energy Investigates operating conditions under which PGM elements get volatilized and transferred onto the downstream SCR catalyst, resulting in loss of NOx reduction performance deer12_chen.pdf (856.01 KB) More Documents & Publications The Effects of Hydrothermal Agingon a Commercial Cu SCR Catalyst Function Specific Analysis of the Thermal Durability of Cu-Zeolite SCR Catalyst Lean NOx Reduction with Dual Layer LNT/SCR Catalysts Energy

    May 7, 2010 In

  17. Multi-physics Modeling for Improving Li-Ion Battery Safety; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Pesaran, A.; Kim, G.; Santhanagopalan, S.; Yang, C.

    2015-04-21

    Battery performance, cost, and safety must be further improved for larger market share of HEVs/PEVs and penetration into the grid. Significant investment is being made to develop new materials, fine tune existing ones, improve cell and pack designs, and enhance manufacturing processes to increase performance, reduce cost, and make batteries safer. Modeling, simulation, and design tools can play an important role by providing insight on how to address issues, reducing the number of build-test-break prototypes, and accelerating the development cycle of generating products.

  18. A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes

    SciTech Connect (OSTI)

    Liu, Nian; Wu, Hui; Mcdowell, Matthew T.; Yao, Yan; Wang, Chong M.; Cui, Yi

    2012-05-02

    Silicon is regarded as one of the most promising anode materials for next generation lithium-ion batteries. For use in practical applications, a Si electrode must have high capacity, long cycle life, high efficiency, and the fabrication must be industrially scalable. Here, we design and fabricate a yolk-shell structure to meet all these needs. The fabrication is carried out without special equipment and mostly at room temperature. Commercially available Si nanoparticles are completely sealed inside conformal, thin, self-supporting carbon shells, with rationally designed void space in between the particles and the shell. The well-defined void space allows the Si particles to expand freely without breaking the outer carbon shell, therefore stabilizing the solid-electrolyte interphase on the shell surface. High capacity (?2800 mAh/g at C/10), long cycle life (1000 cycles with 74% capacity retention), and high Coulombic efficiency (99.84%) have been realized in this yolk-shell structured Si electrode.

  19. Electrochemical and physical analysis of a Li-ion cell cycled at elevated temperature

    SciTech Connect (OSTI)

    Shim, Joongpyo; Kostecki, Robert; Richardson, Thomas; Song, Xiangyun; Striebel, Kathryn A.

    2002-06-21

    Laboratory-size LiNi0.8Co0.15Al0.05O2/graphite lithium-ion pouch cells were cycled over 100 percent DOD at room temperature and 60 degrees C in order to investigate high-temperature degradation mechanisms of this important technology. Capacity fade for the cell was correlated with that for the individual components, using electrochemical analysis of the electrodes and other diagnostic techniques. The high-temperature cell lost 65 percent of its initial capacity after 140 cycles at 60 degrees C compared to only 4 percent loss for the cell cycled at room temperature. Cell ohmic impedance increased significantly with the elevated temperature cycling, resulting in some of loss of capacity at the C/2 rate. However, as determined with slow rate testing of the individual electrodes, the anode retained most of its original capacity, while the cathode lost 65 percent, even when cycled with a fresh source of lithium. Diagnostic evaluation of cell components including XRD, Raman, CSAFM and suggest capacity loss occurs primarily due to a rise in the impedance of the cathode, especially at the end-of-charge. The impedance rise may be caused in part by a loss of the conductive carbon at the surface of the cathode and/or by an organic film on the surface of the cathode that becomes non-ionically conductive at low lithium content.

  20. Vehicle Technologies Office Merit Review 2014: Fluorinated Electrolyte for 5-V Li-Ion Chemistry

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fluorinated...

  1. Vehicle Technologies Office Merit Review 2015: Fluorinated Electrolyte for 5-V Li-Ion Chemistry

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fluorinated...

  2. Experimental design and analysis for accelerated degradation tests with Li-ion cells.

    SciTech Connect (OSTI)

    Doughty, Daniel Harvey; Thomas, Edward Victor; Jungst, Rudolph George; Roth, Emanuel Peter

    2003-08-01

    This document describes a general protocol (involving both experimental and data analytic aspects) that is designed to be a roadmap for rapidly obtaining a useful assessment of the average lifetime (at some specified use conditions) that might be expected from cells of a particular design. The proposed experimental protocol involves a series of accelerated degradation experiments. Through the acquisition of degradation data over time specified by the experimental protocol, an unambiguous assessment of the effects of accelerating factors (e.g., temperature and state of charge) on various measures of the health of a cell (e.g., power fade and capacity fade) will result. In order to assess cell lifetime, it is necessary to develop a model that accurately predicts degradation over a range of the experimental factors. In general, it is difficult to specify an appropriate model form without some preliminary analysis of the data. Nevertheless, assuming that the aging phenomenon relates to a chemical reaction with simple first-order rate kinetics, a data analysis protocol is also provided to construct a useful model that relates performance degradation to the levels of the accelerating factors. This model can then be used to make an accurate assessment of the average cell lifetime. The proposed experimental and data analysis protocols are illustrated with a case study involving the effects of accelerated aging on the power output from Gen-2 cells. For this case study, inadequacies of the simple first-order kinetics model were observed. However, a more complex model allowing for the effects of two concurrent mechanisms provided an accurate representation of the experimental data.

  3. Biphasic Electrode Suspensions for Li-Ion Semi-Solid Flow Cells...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Details By using a steric stabilizer Polyvinylpyrrolidone (PVP) and proper colloidal suspension processing steps (milling, filtration, consolidation, mixing), biphasic ...

  4. Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  5. Thermal/Electrical Modeling for Abuse-Tolerant Design of Li-Ion Modules (Presentation)

    SciTech Connect (OSTI)

    Smith, K.; Kim, G.-H.; Pesaran, A.; Darcy, E.

    2008-11-01

    To help design safe, high-performing batteries, NREL and NASA created and verified a new multicell math model capturing electrical-thermal interactions of cells with PTC devices during thermal abuse.

  6. Layer cathode methods of manufacturing and materials for Li-ion rechargeable batteries

    DOE Patents [OSTI]

    Kang, Sun-Ho; Amine, Khalil

    2008-01-01

    A positive electrode active material for lithium-ion rechargeable batteries of general formula Li.sub.1+xNi.sub..alpha.Mn.sub..beta.A.sub..gamma.O.sub.2 and further wherein A is Mg, Zn, Al, Co, Ga, B, Zr, or Ti and 0

  7. Development of Cell/Pack Level Models for Automotive Li-Ion Batteries with Experimental Validation

    Office of Energy Efficiency and Renewable Energy (EERE)

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  8. Computer-Aided Engineering of Batteries for Designing Better Li-Ion Batteries (Presentation)

    SciTech Connect (OSTI)

    Pesaran, A.; Kim, G. H.; Smith, K.; Lee, K. J.; Santhanagopalan, S.

    2012-02-01

    This presentation describes the current status of the DOE's Energy Storage R and D program, including modeling and design tools and the Computer-Aided Engineering for Automotive Batteries (CAEBAT) program.

  9. Thermal Stability of LiPF6 Salt and Li-ion Battery Electrolytes...

    Office of Scientific and Technical Information (OSTI)

    OSTI Identifier: 898281 Report Number(s): LBNL--58758 Journal ID: ISSN 0378-7753; JPSODZ; R&D Project: 673502; BnR: VT0301030; TRN: US200703%%412 DOE Contract Number: ...

  10. Diagnostic Studies to Improve Abuse Tolerance and Life of Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  11. Thermal Stability of LiPF 6 Salt and Li-ion Battery Electrolytes...

    Office of Scientific and Technical Information (OSTI)

    In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF 6 and water vapor to form ...

  12. Diagnostic Studies to Improve Abuse Tolerance and Life of Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  13. Diagnostic Studies to Improve Abuse Tolerance and Life of Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  14. Diagnostic Studies to Improve Abuse Tolerance and Life of Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  15. Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode

    Broader source: Energy.gov (indexed) [DOE]

    Sicangu Lakota Oyate (Rosebud Sioux Tribe) Hihan Sapa Wapaha Tate Woilagyapi Project (Owl Feather War Bonnet Wind Project) 30 MW Wind Energy Facility Phil Two Eagle, Director Ken Haukaas, Project Manager Resource Development Office Dale Osborn, President Distributed Generation Systems, Inc. (DISGEN) www.disgenonline.com Sicangu Lakota Oyate (Rosebud Sioux Tribe) Hihan Sapa Wapaha Tate Woilagyapi Project (Owl Feather War Bonnet Wind Project) Project Objectives 1. Complete all the development

  16. Streamlining the Optimization of Li-Ion Battery Electrodes | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Optimized EGR and boost pressure under transient conditions lowers in-cylinder NOx for diesels and reduces pumping losses and improves knock resistance for gasoline engines. p-03_czarnowski.pdf (311.74 KB) More Documents & Publications Can Future Emissions Limits be Met with a Hybrid EGR System Alone? Control Strategy for a Dual Loop EGR System to Meet Euro 6 and Beyond Advanced Diesel Engine Technology Development for HECC

    A new filter system technology

  17. Vehicle Technologies Office Merit Review 2016: Tailoring Spinel Electrodes for High Capacity Li-Ion Cells

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory (ANL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  18. Characterization of Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  19. Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  20. Role of Surface Structure on Li-ion Energy Storage Capacity of...

    Office of Scientific and Technical Information (OSTI)

    (FIRST) Sponsoring Org: USDOE SC Office of Basic Energy Sciences (SC-22) Country of Publication: United States Language: English Subject: catalysis (heterogeneous), solar ...

  1. Platforms and Methods for In Situ Characterization of Li-ion...

    Office of Scientific and Technical Information (OSTI)

    Electron Transmission X-ray Microscopies. Abstract not provided. Authors: Sullivan, John P ; Bartelt, Norman C. ; El Gabaly Marquez, Farid ; Fenton, Kyle R 1 ;...

  2. Large displacement spherical joint

    DOE Patents [OSTI]

    Bieg, Lothar F.; Benavides, Gilbert L.

    2002-01-01

    A new class of spherical joints has a very large accessible full cone angle, a property which is beneficial for a wide range of applications. Despite the large cone angles, these joints move freely without singularities.

  3. Running Large Scale Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Running Large Scale Jobs Running Large Scale Jobs Users face various challenges with running and scaling large scale jobs on peta-scale production systems. For example, certain applications may not have enough memory per core, the default environment variables may need to be adjusted, or I/O dominates run time. This page lists some available programming and run time tuning options and tips users can try on their large scale applications on Hopper for better performance. Try different compilers

  4. Running Large Scale Jobs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    try on their large scale applications on Hopper for better performance. Try different compilers and compiler options The available compilers on Hopper are PGI, Cray, Intel, GNU,...

  5. Microsoft PowerPoint - Sacci_2015_UserProjectHighlight_NanoLett...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium dendrite formation is a major safety concern existing in Li-ion and Li-metal batteries. In situ ec-STEM (a liquid cell electron microscopy based characterization method)...

  6. Large Customers (DR Sellers)

    SciTech Connect (OSTI)

    Kiliccot, Sila

    2011-10-25

    State of the large customers for demand response integration of solar and wind into electric grid; openADR; CAISO; DR as a pseudo generation; commercial and industrial DR strategies; California regulations

  7. I/O Formats

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formats I/O Formats Software I/O continues to be one of the main bottlenecks for scientific applications. Here are two software packages that many application developers use to manage input/output of heterogeneous types of binary application data used on many different platforms. HDF5 and NETCDF are both implemented on top of MPI-IO and have gained popularity as alternatives to basic POSIX API. HDF5 is a machine-independent and self-documenting file format. Each HDF5 file "looks" like

  8. Level Diagram Format Choice

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Which format should I use? There is no clear-cut answer to this question -- different solutions work better in different situations. In an effort to help you decide which will work best for you, we provide a discussion of the advantages and disadvantages of the three available formats. GIF: GIF stands for Graphic Interchange Format. It was developed by CompuServe as a device-independent way to store pictures. The files are well-compressed, so download time is relatively short. Most web browsers

  9. Large Group Visits

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Group Visits Large Group Visits All tours of the Museum are self-guided, but please schedule in advance so we can best accommodate your group. Contact Us thumbnail of 1350 Central Avenue (505) 667-4444 Email Let us know if you plan to bring a group of 10 or more. All tours of the Museum are self-guided, but please schedule in advance so we can best accommodate your group. Parking for buses and RVs is available on Iris Street behind the Museum off of 15th St. See attached map (pdf). Contact

  10. Extra-Large Memory Nodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extra-Large Memory Nodes Extra-Large Memory Nodes Extra-Large Memory Nodes Overview Carver has two "extra-large" memory nodes; each node has four 8-core Intel X7550 ("Nehalem EX")...

  11. Large Eddy Simulations: Where

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Eddy Simulations: Where observations and modeling collides July 18, 2015 Cascade of Models ⌅ General Circulation Models ⌅ Regional Models ⌅ Large-Eddy Simulations ⌅ Direct Numerical Simulations LES GCM vs LES History Theory What if? Using LES together with Observations Testbed LES 2 / 37 Cascade of Models General Circulation Models ⌅ Domain size: Entire Earth ⌅ Horizontal Boundary conditions: None ⌅ Horizontal grid spacing: 50km ⌅ Total number of points: about 400 ⇥ 400 ⇥ 100

  12. Meet with Large Businesses

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meet with Large Businesses and learn about upcoming acquisitions! * Federal Energy Management Program (FEMP) * National Renewable Energy Laboratory (NREL) * Small Business Administration (SBA) * U.S. Department of Energy / Energy, Efficiency, and Renewable Energy (EERE) * U.S. Department of Energy / Golden Field Office (GFO) * Western Area Power Administration (WAPA) * Colorado Procurement Technical Assistance Center (PTAC) SMALL BUSINESS OUTREACH "Federal Contracting with Small

  13. formatting | OpenEI Community

    Open Energy Info (EERE)

    formatting Home Jweers's picture Submitted by Jweers(88) Contributor 7 August, 2013 - 18:23 New Robust References citation citing developer formatting reference Semantic Mediawiki...

  14. Gaussian entanglement of formation

    SciTech Connect (OSTI)

    Wolf, M.M.; Giedke, G.; Krueger, O.; Werner, R. F.; Cirac, J.I.

    2004-05-01

    We introduce a Gaussian version of the entanglement of formation adapted to bipartite Gaussian states by considering decompositions into pure Gaussian states only. We show that this quantity is an entanglement monotone under Gaussian operations and provide a simplified computation for states of arbitrary many modes. For the case of one mode per site the remaining variational problem can be solved analytically. If the considered state is in addition symmetric with respect to interchanging the two modes, we prove additivity of the considered entanglement measure. Moreover, in this case and considering only a single copy, our entanglement measure coincides with the true entanglement of formation.

  15. Gyrokinetic large eddy simulations

    SciTech Connect (OSTI)

    Morel, P.; Navarro, A. Banon; Albrecht-Marc, M.; Carati, D.; Merz, F.; Goerler, T.; Jenko, F.

    2011-07-15

    The large eddy simulation approach is adapted to the study of plasma microturbulence in a fully three-dimensional gyrokinetic system. Ion temperature gradient driven turbulence is studied with the GENE code for both a standard resolution and a reduced resolution with a model for the sub-grid scale turbulence. A simple dissipative model for representing the effect of the sub-grid scales on the resolved scales is proposed and tested. Once calibrated, the model appears to be able to reproduce most of the features of the free energy spectra for various values of the ion temperature gradient.

  16. Large Particle Titanate Sorbents

    SciTech Connect (OSTI)

    Taylor-Pashow, K.

    2015-10-08

    This research project was aimed at developing a synthesis technique for producing large particle size monosodium titanate (MST) to benefit high level waste (HLW) processing at the Savannah River Site (SRS). Two applications were targeted, first increasing the size of the powdered MST used in batch contact processing to improve the filtration performance of the material, and second preparing a form of MST suitable for deployment in a column configuration. Increasing the particle size should lead to improvements in filtration flux, and decreased frequency of filter cleaning leading to improved throughput. Deployment of MST in a column configuration would allow for movement from a batch process to a more continuous process. Modifications to the typical MST synthesis led to an increase in the average particle size. Filtration testing on dead-end filters showed improved filtration rates with the larger particle material; however, no improvement in filtration rate was realized on a crossflow filter. In order to produce materials suitable for column deployment several approaches were examined. First, attempts were made to coat zirconium oxide microspheres (196 µm) with a layer of MST. This proved largely unsuccessful. An alternate approach was then taken synthesizing a porous monolith of MST which could be used as a column. Several parameters were tested, and conditions were found that were able to produce a continuous structure versus an agglomeration of particles. This monolith material showed Sr uptake comparable to that of previously evaluated samples of engineered MST in batch contact testing.

  17. Sean Large | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sean Large Sean Large Sean Large - Intern with the Office of Energy Efficiency and Renewable Energy Most Recent Be Part of the Solution! June 22 What's Up With Fuel Cells? June 8

  18. Formate-assisted pyrolysis

    SciTech Connect (OSTI)

    DeSisto, William Joseph; Wheeler, Marshall Clayton; van Heiningen, Adriaan R. P.

    2015-03-17

    The present invention provides, among other thing, methods for creating significantly deoxygenated bio-oils form biomass including the steps of providing a feedstock, associating the feedstock with an alkali formate to form a treated feedstock, dewatering the treated feedstock, heating the dewatered treated feedstock to form a vapor product, and condensing the vapor product to form a pyrolysis oil, wherein the pyrolysis oil contains less than 30% oxygen by weight.

  19. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  20. TEMPORAL SELF-ORGANIZATION IN GALAXY FORMATION

    SciTech Connect (OSTI)

    Cen, Renyue

    2014-04-20

    We report on the discovery of a relation between the number of star formation (SF) peaks per unit time, ?{sub peak}, and the size of the temporal smoothing window function, ?t, used to define the peaks: ?{sub peak}??t {sup 1} {sup } {sup ?} (? ? 1.618). This relation holds over the range of ?t = 10-1000Myr that can be reliably computed here, using a large sample of galaxies obtained from a state-of-the-art cosmological hydrodynamic simulation. This means that the temporal distribution of SF peaks in galaxies as a population is fractal with a Hausdorff fractal dimension equal to ? 1. This finding reveals, for the first time, that the superficially chaotic process of galaxy formation is underlined by temporal self-organization up to at least one gigayear. It is tempting to suggest that, given the known existence of spatial fractals (such as the power-law two-point function of galaxies), there is a joint spatio-temporal self-organization in galaxy formation. From an observational perspective, it will be urgent to devise diagnostics to probe the SF histories of galaxies with good temporal resolution to facilitate a test of this prediction. If confirmed, it would provide unambiguous evidence for a new picture of galaxy formation that is interaction driven, cooperative, and coherent in and between time and space. Unravelling its origin may hold the key to understanding galaxy formation.

  1. Large forging manufacturing process

    DOE Patents [OSTI]

    Thamboo, Samuel V.; Yang, Ling

    2002-01-01

    A process for forging large components of Alloy 718 material so that the components do not exhibit abnormal grain growth includes the steps of: a) providing a billet with an average grain size between ASTM 0 and ASTM 3; b) heating the billet to a temperature of between 1750.degree. F. and 1800.degree. F.; c) upsetting the billet to obtain a component part with a minimum strain of 0.125 in at least selected areas of the part; d) reheating the component part to a temperature between 1750.degree. F. and 1800.degree. F.; e) upsetting the component part to a final configuration such that said selected areas receive no strains between 0.01 and 0.125; f) solution treating the component part at a temperature of between 1725.degree. F. and 1750.degree. F.; and g) aging the component part over predetermined times at different temperatures. A modified process achieves abnormal grain growth in selected areas of a component where desirable.

  2. Large scale tracking algorithms.

    SciTech Connect (OSTI)

    Hansen, Ross L.; Love, Joshua Alan; Melgaard, David Kennett; Karelitz, David B.; Pitts, Todd Alan; Zollweg, Joshua David; Anderson, Dylan Z.; Nandy, Prabal; Whitlow, Gary L.; Bender, Daniel A.; Byrne, Raymond Harry

    2015-01-01

    Low signal-to-noise data processing algorithms for improved detection, tracking, discrimination and situational threat assessment are a key research challenge. As sensor technologies progress, the number of pixels will increase signi cantly. This will result in increased resolution, which could improve object discrimination, but unfortunately, will also result in a significant increase in the number of potential targets to track. Many tracking techniques, like multi-hypothesis trackers, suffer from a combinatorial explosion as the number of potential targets increase. As the resolution increases, the phenomenology applied towards detection algorithms also changes. For low resolution sensors, "blob" tracking is the norm. For higher resolution data, additional information may be employed in the detection and classfication steps. The most challenging scenarios are those where the targets cannot be fully resolved, yet must be tracked and distinguished for neighboring closely spaced objects. Tracking vehicles in an urban environment is an example of such a challenging scenario. This report evaluates several potential tracking algorithms for large-scale tracking in an urban environment.

  3. EM Active Sites (large) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Active Sites (large) EM Active Sites (large) Center

  4. Tribal Utility Formation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    I L L E P O W E R A D M I N I S T R A T I O N Tribal Utility Formation in the Bonneville Power Administration Service Territory Ken Johnston Acting Tribal Affairs Manager BPA TRIBAL AFFAIRS DEPARTMENT JULY 2015 B O N N E V I L L E P O W E R A D M I N I S T R A T I O N 2 The Basics  BPA markets power from 31 Federal dams, the Columbia Generating Station Nuclear Plant, and several small non- Federal power plants  About 80% of the power BPA sells is hydroelectric  BPA accounts for about

  5. Vehicle Technologies Office Merit Review 2015: Giga Life Cycle: Manufacture of Cells from Recycled EV Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by OnTo Technology at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Giga Life Cycle: manufacture...

  6. Vehicle Technologies Office Merit Review 2015: Low-cost, High Energy Si/Graphene Anodes for Li-ion Batteries

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by XG Sciences at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about low-cost, high energy Si/graphene...

  7. Vehicle Technologies Office Merit Review 2016: Low-cost, High Energy Si/Graphene Anodes for Li-Ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by XG Sciences at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  8. Porous Two-Dimensional Transition Metal Carbide (MXene) Flakes for High-Performance Li-Ion Storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ren, Chang E.; Zhao, M-Q; Makaryan, Taron; Halim, Joseph; Boota, M.; Kota, Sankalp; Anasori, Babak; Barsoum, M W; Gogotsi, Yury

    2016-02-16

    Herein we develop a chemical etching method to produce porous two-dimensional (2D) Ti3C2Tx MXenes at room temperature in aqueous solutions. The as-produced porous Ti3C2Tx (p-Ti3C2Tx) have larger specific surface areas and more open structures than their pristine counterparts, and can be fabricated into flexible films with, or without, the addition of carbon nanotubes (CNTs). The as-fabricated p-Ti3C2Tx/CNT films showed significantly improved lithium ion storage capabilities compared to pristine Ti3C2Tx based films, with a very high capacity of ≈1250 mAh g-1 at 0.1 C, excellent cycling stability, and good rate performance (330 mAh g-1 at 10 C). Using the same chemicalmore » etching method, we also made porous Nb2CTx and V2CTx MXenes. Therefore, this study provides a simple, yet effective, procedure to introduce pores into MXenes and possibly other 2D sheets that in turn, can enhance their electrochemical properties.« less

  9. Probing the failure mechanism of nanoscale LiFePO{sub 4} for Li-ion batteries

    SciTech Connect (OSTI)

    Gu, Meng; Yan, Pengfei; Wang, Chongmin; Shi, Wei; Zheng, Jianming; Zhang, Ji-guang

    2015-05-18

    LiFePO{sub 4} is a high power rate cathode material for lithium ion battery and shows remarkable capacity retention, featuring a 91% capacity retention after 3300 cycles. In this work, we use high-resolution transmission electron microscopy and electron energy loss spectroscopy to study the gradual capacity fading mechanism of LiFePO{sub 4} materials. We found that upon prolonged electrochemical cycling of the battery, the LiFePO{sub 4} cathode shows surface amorphization and loss of oxygen species, which directly contribute to the gradual capacity fading of the battery. The finding can guide the design and improvement of LiFePO{sub 4} cathode for high-energy and high-power rechargeable battery for electric transportation.

  10. Vehicle Technologies Office Merit Review 2014: Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Li-ion Anode Systems

    Broader source: Energy.gov [DOE]

    Presentation given by University of Pittsburgh at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about nanoscale...