National Library of Energy BETA

Sample records for landfill gas methane

  1. Methane Gas Utilization Project from Landfill at Ellery (NY)

    SciTech Connect (OSTI)

    Pantelis K. Panteli

    2012-01-10

    Landfill Gas to Electric Energy Generation and Transmission at Chautauqua County Landfill, Town of Ellery, New York. The goal of this project was to create a practical method with which the energy, of the landfill gas produced by the decomposing waste at the Chautauqua County Landfill, could be utilized. This goal was accomplished with the construction of a landfill gas to electric energy plant (originally 6.4MW and now 9.6MW) and the construction of an inter-connection power-line, from the power-plant to the nearest (5.5 miles) power-grid point.

  2. Methane emissions from MBT landfills

    SciTech Connect (OSTI)

    Heyer, K.-U. Hupe, K.; Stegmann, R.

    2013-09-15

    Highlights: • Compilation of methane generation potential of mechanical biological treated (MBT) municipal solid waste. • Impacts and kinetics of landfill gas production of MBT landfills, approach with differentiated half-lives. • Methane oxidation in the waste itself and in soil covers. • Estimation of methane emissions from MBT landfills in Germany. - Abstract: Within the scope of an investigation for the German Federal Environment Agency (“Umweltbundesamt”), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 18–24 m{sup 3} CH{sub 4}/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH{sub 4}/(m{sup 2} h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD

  3. 7.4 Landfill Methane Utilization

    Office of Energy Efficiency and Renewable Energy (EERE)

    A chapter on Landfill Methane Utilization from the Clean Energy Strategies for Local Governments publication.

  4. LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL

    SciTech Connect (OSTI)

    Don Augenstein; Ramin Yazdani; Rick Moore; Michelle Byars; Jeff Kieffer; Professor Morton Barlaz; Rinav Mehta

    2000-02-26

    Controlled landfilling is an approach to manage solid waste landfills, so as to rapidly complete methane generation, while maximizing gas capture and minimizing the usual emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated to more rapid and earlier completion to full potential by improving conditions (principally moisture, but also temperature) to optimize biological processes occurring within the landfill. Gas is contained through use of surface membrane cover. Gas is captured via porous layers, under the cover, operated at slight vacuum. A field demonstration project has been ongoing under NETL sponsorship for the past several years near Davis, CA. Results have been extremely encouraging. Two major benefits of the technology are reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times, more predictably, than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role both in reduction of US greenhouse gas emissions and in US renewable energy. The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with conventional

  5. US EPA Landfill Methane Outreach Program | Open Energy Information

    Open Energy Info (EERE)

    EPA Landfill Methane Outreach Program Jump to: navigation, search Name US EPA Landfill Methane Outreach Program AgencyCompany Organization United States Environmental Protection...

  6. Landfill Gas | Open Energy Information

    Open Energy Info (EERE)

    Gas Jump to: navigation, search TODO: Add description List of Landfill Gas Incentives Retrieved from "http:en.openei.orgwindex.php?titleLandfillGas&oldid267173...

  7. Analysis of factors affecting methane-gas recovery from six landfills...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 09 BIOMASS FUELS; 54 ENVIRONMENTAL SCIENCES; METHANE; MATERIALS RECOVERY; AIR POLLUTION; CLIMATES; DATA PROCESSING; FIELD TESTS; GLOBAL ASPECTS; ...

  8. Landfill Methane Project Development Handbook | Open Energy Informatio...

    Open Energy Info (EERE)

    Methane Project Development Handbook Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Landfill Methane Project Development Handbook AgencyCompany Organization: United...

  9. Feasibility study: utilization of landfill gas for a vehicle fuel system, Rossman's landfill, Clackamas County, Oregon

    SciTech Connect (OSTI)

    1981-01-01

    In 1978, a landfill operator in Oregon became interested in the technical and economic feasibility of recovering the methane generated in the landfill for the refueling of vehicles. DOE awarded a grant for a site-specific feasibility study of this concept. This study investigated the expected methane yield and the development of a conceptual gas-gathering system; gas processing, compressing, and storage systems; and methane-fueled vehicle systems. Cost estimates were made for each area of study. The results of the study are presented. Reasoning that gasoline prices will continue to rise and that approximately 18,000 vehicles in the US have been converted to operate on methane, a project is proposed to use this landfill as a demonstration site to produce and process methane and to fuel a fleet (50 to 400) vehicles with the gas produced in order to obtain performance and economic data on the systems used from gas collection through vehicle operation. (LCL)

  10. LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL

    SciTech Connect (OSTI)

    Don Augenstein

    2001-02-01

    The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with conventional landfills. This is the highest methane recovery rate per unit waste, and thus progress toward stabilization, documented anywhere for such a large waste mass. This high recovery rate is attributed to moisture, and elevated temperature attained inexpensively during startup. Economic analyses performed under Phase I of this NETL contract indicate ''greenhouse cost effectiveness'' to be excellent. Other benefits include substantial waste volume loss (over 30%) which translates to extended landfill life. Other environmental benefits include rapidly improved quality and stabilization (lowered pollutant levels) in liquid leachate which drains from the waste.

  11. Methane recovery from landfill in China

    SciTech Connect (OSTI)

    Gaolai, L.

    1996-12-31

    GEF has approved a special project for a demonstration project for Methane Recovery from the Urban Refuse Land Fill. This paper will introduce the possibility of GHG reduction from the landfill in China, describe the activities of the GEF project, and the priorities for international cooperation in this field. The Global Environment Facility (GEF) approved the project, China Promoting Methane Recovery and Unlization from Mixed Municipal Refuse, at its Council meeting in last April. This project is the first one supported by international organization in this field.

  12. Powering Microturbines With Landfill Gas, October 2002 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants 7.4 Landfill Methane Utilization CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market ...

  13. Fluxes of methane between landfills and the atmosphere: Natural and engineered controls

    SciTech Connect (OSTI)

    Bogner, J.; Meadows, M.; Czepiel, P.

    1997-08-01

    Field measurement of landfill methane emissions indicates natural variability spanning more than 2 seven orders of magnitude, from approximately 0.0004 to more than 4000 g m{sub -2} day{sup -1}. This wide range reflects net emissions resulting from production (methanogenesis), consumption (methanotrophic oxidation), and gaseous transport processes. The determination of an {open_quotes}average{close_quotes} emission rate for a given field site requires sampling designs and statistical techniques which consider spatial and temporal variability. Moreover, particularly at sites with pumped gas recovery systems, it is possible for methanotrophic microorganisms in aerated cover soils to oxidize all of the methane from landfill sources below and, additionally, to oxidize methane diffusing into cover soils from atmospheric sources above. In such cases, a reversed soil gas concentration gradient is observed in shallow cover soils, indicating bidirectional diffusional transport to the depth of optimum methane oxidation. Rates of landfill methane oxidation from field and laboratory incubation studies range up to 166 g m{sup -2} day{sup -1} among the highest for any natural setting, providing an effective natural control on net emissions. Estimates of worldwide landfill methane emissions to the atmosphere have ranged from 9 to 70 Tg yr{sup -1}, differing mainly in assumed methane yields from estimated quantities of landfilled refuse. At highly controlled landfill sites in developed countries, landfill methane is often collected via vertical wells or horizontal collectors. Recovery of landfill methane through engineered systems can provide both environmental and energy benefits by mitigating subsurface migration, reducing surface emissions, and providing an alternative energy resource for industrial boiler use, on-site electrical generation, or upgrading to a substitute natural gas.

  14. LIQUID NATURAL GAS (LNG): AN ALTERNATIVE FUEL FROM LANDFILL GAS (LFG) AND WASTEWATER DIGESTER GAS

    SciTech Connect (OSTI)

    VANDOR,D.

    1999-03-01

    This Research and Development Subcontract sought to find economic, technical and policy links between methane recovery at landfill and wastewater treatment sites in New York and Maryland, and ways to use that methane as an alternative fuel--compressed natural gas (CNG) or liquid natural gas (LNG) -- in centrally fueled Alternative Fueled Vehicles (AFVs).

  15. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 1. Project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  16. ARM - Methane Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Gas Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Methane Gas Methane gas is another naturally occurring greenhouse gas. It is produced as a result of microbial activity in the absence of oxygen. Pre-industrial concentrations of methane were about 700 ppb and in 1994 they were up

  17. Sour landfill gas problem solved

    SciTech Connect (OSTI)

    Nagl, G.; Cantrall, R.

    1996-05-01

    In Broward County, Fla., near Pompano Beach, Waste Management of North America (WMNA, a subsidiary of WMX Technologies, Oak Brook, IL) operates the Central Sanitary Landfill and Recycling Center, which includes the country`s largest landfill gas-to-energy plant. The landfill consists of three collection sites: one site is closed, one is currently receiving garbage, and one will open in the future. Approximately 9 million standard cubic feet (scf) per day of landfill gas is collected from approximately 300 wells spread over the 250-acre landfill. With a dramatic increase of sulfur-containing waste coming to a South Florida landfill following Hurricane Andrew, odors related to hydrogen sulfide became a serious problem. However, in a matter of weeks, an innovative desulfurization unit helped calm the landfill operator`s fears. These very high H{sub 2}S concentrations caused severe odor problems in the surrounding residential area, corrosion problems in the compressors, and sulfur dioxide (SO{sub 2}) emission problems in the exhaust gas from the turbine generators.

  18. Hartford Landfill Gas Utilization Proj Biomass Facility | Open...

    Open Energy Info (EERE)

    Landfill Gas Utilization Proj Biomass Facility Jump to: navigation, search Name Hartford Landfill Gas Utilization Proj Biomass Facility Facility Hartford Landfill Gas Utilization...

  19. Albany Landfill Gas Utilization Project Biomass Facility | Open...

    Open Energy Info (EERE)

    Landfill Gas Utilization Project Biomass Facility Jump to: navigation, search Name Albany Landfill Gas Utilization Project Biomass Facility Facility Albany Landfill Gas Utilization...

  20. Balefill Landfill Gas Utilization Proj Biomass Facility | Open...

    Open Energy Info (EERE)

    Balefill Landfill Gas Utilization Proj Biomass Facility Jump to: navigation, search Name Balefill Landfill Gas Utilization Proj Biomass Facility Facility Balefill Landfill Gas...

  1. Woodland Landfill Gas Recovery Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Landfill Gas Recovery Biomass Facility Jump to: navigation, search Name Woodland Landfill Gas Recovery Biomass Facility Facility Woodland Landfill Gas Recovery Sector Biomass...

  2. Lopez Landfill Gas Utilization Project Biomass Facility | Open...

    Open Energy Info (EERE)

    Lopez Landfill Gas Utilization Project Biomass Facility Jump to: navigation, search Name Lopez Landfill Gas Utilization Project Biomass Facility Facility Lopez Landfill Gas...

  3. Olinda Landfill Gas Recovery Plant Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Olinda Landfill Gas Recovery Plant Biomass Facility Jump to: navigation, search Name Olinda Landfill Gas Recovery Plant Biomass Facility Facility Olinda Landfill Gas Recovery Plant...

  4. Spadra Landfill Gas to Energy Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Spadra Landfill Gas to Energy Biomass Facility Jump to: navigation, search Name Spadra Landfill Gas to Energy Biomass Facility Facility Spadra Landfill Gas to Energy Sector Biomass...

  5. Assessment of the methane oxidation capacity of compacted soils intended for use as landfill cover materials

    SciTech Connect (OSTI)

    Rachor, Ingke; Gebert, Julia; Groengroeft, Alexander; Pfeiffer, Eva-Maria

    2011-05-15

    The microbial oxidation of methane in engineered cover soils is considered a potent option for the mitigation of emissions from old landfills or sites containing wastes of low methane generation rates. A laboratory column study was conducted in order to derive design criteria that enable construction of an effective methane oxidising cover from the range of soils that are available to the landfill operator. Therefore, the methane oxidation capacity of different soils was assessed under simulated landfill conditions. Five sandy potential landfill top cover materials with varying contents of silt and clay were investigated with respect to methane oxidation and corresponding soil gas composition over a period of four months. The soils were compacted to 95% of their specific proctor density, resulting in bulk densities of 1.4-1.7 g cm{sup -3}, reflecting considerably unfavourable conditions for methane oxidation due to reduced air-filled porosity. The soil water content was adjusted to field capacity, resulting in water contents ranging from 16.2 to 48.5 vol.%. The investigated inlet fluxes ranged from 25 to about 100 g CH{sub 4} m{sup -2} d{sup -1}, covering the methane load proposed to allow for complete oxidation in landfill covers under Western European climate conditions and hence being suggested as a criterion for release from aftercare. The vertical distribution of gas concentrations, methane flux balances as well as stable carbon isotope studies allowed for clear process identifications. Higher inlet fluxes led to a reduction of the aerated zone, an increase in the absolute methane oxidation rate and a decline of the relative proportion of oxidized methane. For each material, a specific maximum oxidation rate was determined, which varied between 20 and 95 g CH{sub 4} m{sup -2} d{sup -1} and which was positively correlated to the air-filled porosity of the soil. Methane oxidation efficiencies and gas profile data imply a strong link between oxidation capacity

  6. Reducing Open Cell Landfill Methane Emissions with a Bioactive Alternative Daily

    SciTech Connect (OSTI)

    Helene Hilger; James Oliver; Jean Bogner; David Jones

    2009-03-31

    Methane and carbon dioxide are formed in landfills as wastes degrade. Molecule-for-molecule, methane is about 20 times more potent than carbon dioxide at trapping heat in the earth's atmosphere, and thus, it is the methane emissions from landfills that are scrutinized. For example, if emissions composed of 60% methane and 40% carbon dioxide were changed to a mix that was 40% methane and 60% carbon dioxide, a 30% reduction in the landfill's global warming potential would result. A 10% methane, 90% carbon dioxide ratio will result in a 75% reduction in global warming potential compared to the baseline. Gas collection from a closed landfill can reduce emissions, and it is sometimes combined with a biocover, an engineered system where methane oxidizing bacteria living in a medium such as compost, convert landfill methane to carbon dioxide and water. Although methane oxidizing bacteria merely convert one greenhouse gas (methane) to another (carbon dioxide), this conversion can offer significant reductions in the overall greenhouse gas contribution, or global warming potential, associated with the landfill. What has not been addressed to date is the fact that methane can also escape from a landfill when the active cell is being filled with waste. Federal regulations require that newly deposited solid waste to be covered daily with a 6 in layer of soil or an alternative daily cover (ADC), such as a canvas tarp. The aim of this study was to assess the feasibility of immobilizing methane oxidizing bacteria into a tarp-like matrix that could be used for alternative daily cover at open landfill cells to prevent methane emissions. A unique method of isolating methanotrophs from landfill cover soil was used to create a liquid culture of mixed methanotrophs. A variety of prospective immobilization techniques were used to affix the bacteria in a tarp-like matrix. Both gel encapsulation of methanotrophs and gels with liquid cores containing methanotrophs were readily made but

  7. Improved methodology to assess modification and completion of landfill gas management in the aftercare period

    SciTech Connect (OSTI)

    Morris, Jeremy W.F.; Crest, Marion; Barlaz, Morton A.; Spokas, Kurt A.; Akerman, Anna; Yuan, Lei

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer Performance-based evaluation of landfill gas control system. Black-Right-Pointing-Pointer Analytical framework to evaluate transition from active to passive gas control. Black-Right-Pointing-Pointer Focus on cover oxidation as an alternative means of passive gas control. Black-Right-Pointing-Pointer Integrates research on long-term landfill behavior with practical guidance. - Abstract: Municipal solid waste landfills represent the dominant option for waste disposal in many parts of the world. While some countries have greatly reduced their reliance on landfills, there remain thousands of landfills that require aftercare. The development of cost-effective strategies for landfill aftercare is in society's interest to protect human health and the environment and to prevent the emergence of landfills with exhausted aftercare funding. The Evaluation of Post-Closure Care (EPCC) methodology is a performance-based approach in which landfill performance is assessed in four modules including leachate, gas, groundwater, and final cover. In the methodology, the objective is to evaluate landfill performance to determine when aftercare monitoring and maintenance can be reduced or possibly eliminated. This study presents an improved gas module for the methodology. While the original version of the module focused narrowly on regulatory requirements for control of methane migration, the improved gas module also considers best available control technology for landfill gas in terms of greenhouse gas emissions, air quality, and emissions of odoriferous compounds. The improved module emphasizes the reduction or elimination of fugitive methane by considering the methane oxidation capacity of the cover system. The module also allows for the installation of biologically active covers or other features designed to enhance methane oxidation. A methane emissions model, CALMIM, was used to assist with an assessment of the methane oxidation capacity of

  8. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 2. Appendices to project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  9. Impact of different plants on the gas profile of a landfill cover

    SciTech Connect (OSTI)

    Reichenauer, Thomas G.; Watzinger, Andrea; Riesing, Johann; Gerzabek, Martin H.

    2011-05-15

    Research highlights: > Plants influence gas profile and methane oxidation in landfill covers. > Plants regulate water content and increase the availability of oxygen for methane oxidation. > Plant species with deep roots like alfalfa showed more stimulation of methane oxidation than plants with shallow root systems like grasses. - Abstract: Methane is an important greenhouse gas emitted from landfill sites and old waste dumps. Biological methane oxidation in landfill covers can help to reduce methane emissions. To determine the influence of different plant covers on this oxidation in a compost layer, we conducted a lysimeter study. We compared the effect of four different plant covers (grass, alfalfa + grass, miscanthus and black poplar) and of bare soil on the concentration of methane, carbon dioxide and oxygen in lysimeters filled with compost. Plants were essential for a sustainable reduction in methane concentrations, whereas in bare soil, methane oxidation declined already after 6 weeks. Enhanced microbial activity - expected in lysimeters with plants that were exposed to landfill gas - was supported by the increased temperature of the gas in the substrate and the higher methane oxidation potential. At the end of the first experimental year and from mid-April of the second experimental year, the methane concentration was most strongly reduced in the lysimeters containing alfalfa + grass, followed by poplar, miscanthus and grass. The observed differences probably reflect the different root morphology of the investigated plants, which influences oxygen transport to deeper compost layers and regulates the water content.

  10. Evaluation of methane emissions from Palermo municipal landfill: Comparison between field measurements and models

    SciTech Connect (OSTI)

    Di Bella, Gaetano; Di Trapani, Daniele; Viviani, Gaspare

    2011-08-15

    Methane (CH{sub 4}) diffuse emissions from Municipal Solid Waste (MSW) landfills represent one of the most important anthropogenic sources of greenhouse gas. CH{sub 4} is produced by anaerobic biodegradation of organic matter in landfilled MSW and constitutes a major component of landfill gas (LFG). Gas recovery is a suitable method to effectively control CH{sub 4} emissions from landfill sites and the quantification of CH{sub 4} emissions represents a good tool to evaluate the effectiveness of a gas recovery system in reducing LFG emissions. In particular, LFG emissions can indirectly be evaluated from mass balance equations between LFG production, recovery and oxidation in the landfill, as well as by a direct approach based on LFG emission measurements from the landfill surface. However, up to now few direct measurements of landfill CH{sub 4} diffuse emissions have been reported in the technical literature. In the present study, both modeling and direct emission measuring methodologies have been applied to the case study of Bellolampo landfill located in Palermo, Italy. The main aim of the present study was to evaluate CH{sub 4} diffuse emissions, based on direct measurements carried out with the flux accumulation chamber (static, non-stationary) method, as well as to obtain the CH{sub 4} contoured flux map of the landfill. Such emissions were compared with the estimate achieved by means of CH{sub 4} mass balance equations. The results showed that the emissions obtained by applying the flux chamber method are in good agreement with the ones derived by the application of the mass balance equation, and that the evaluated contoured flux maps represent a reliable tool to locate areas with abnormal emissions in order to optimize the gas recovery system efficiency.

  11. Modified biochemical methane potential (BMP) assays to assess biodegradation potential of landfilled refuse

    SciTech Connect (OSTI)

    Bogner, J.E.; Rose, C.; Piorkowski, R.

    1989-01-01

    Modified Biochemical Methane Potential (BMP) assays were used to assess biogas production potential of solid landfill samples. In landfill samples with visible soil content, moisture addition alone was generally as effective at stimulating biogas production as the addition of a comprehensive nutrient media. In a variety of samples from humid and semiarid landfills, addition of an aqueous nutrient media was the most effective stimulant for biogas production; however, moisture addition was almost as effective for most samples, suggesting that water addition would be the most cost-effective field approach. Onset of methanogenesis was slower in fresh refuse samples (even when inoculated with anaerobic digester sludge) than in landfill samples, indicating that the soil into which materials are landfilled is a major source of microorganisms. High volatile solids loading in fresh refuse and landfill assays retarded methanogenesis. A comparison of anaerobic and aerobic sample handling techniques showed no significant differences with regard to onset of methanogenesis and total gas production. The technique shows initial promise with regard to replication and reproducibility of results and could be a meaningful addition to landfill site evaluations where commercial gas recovery is anticipated. The BMP technique could also be adapted to assess anaerobic biodegradability of other solid waste materials for conventional anaerobic digestion applications. 9 refs., 6 figs., 2 tabs.

  12. Penrose Landfill Gas Conversion LLC | Open Energy Information

    Open Energy Info (EERE)

    Page Edit with form History Penrose Landfill Gas Conversion LLC Jump to: navigation, search Name: Penrose Landfill Gas Conversion LLC Place: Los Angeles, California Product: Owner...

  13. Landfill Gas Conversion to LNG and LCO{sub 2}. Final Report

    SciTech Connect (OSTI)

    Brown, W.R.; Cook, W. J.; Siwajek, L.A.

    2000-10-20

    This report summarizes work on the development of a process to produce LNG (liquefied methane) for heavy vehicle use from landfill gas (LFG) using Acrion's CO{sub 2} wash process for contaminant removal and CO{sub 2} recovery. Work was done in the following areas: (1) production of natural gas pipeline methane for liquefaction at an existing LNG facility, (2) production of LNG from sewage digester gas, (3) the use of mixed refrigerants for process cooling in the production of LNG, liquid CO{sub 2} and pipeline methane, (4) cost estimates for an LNG production facility at the Arden Landfill in Washington PA.

  14. Tapping Landfill Gas to Provide Significant Energy Savings and...

    Energy Savers [EERE]

    Central Landfill in Johnston, Rhode Island, and Olinda Alpha Landfill in Brea, California. ... The California plant is the third-largest landfill-gas-to-electricity facility in the ...

  15. Operating a fuel cell using landfill gas

    SciTech Connect (OSTI)

    Trippel, C.E.; Preston, J.L. Jr.; Trocciola, J.; Spiegel, R.

    1996-12-31

    An ONSI PC25{trademark}, 200 kW (nominal capacity) phosphoric acid fuel cell operating on landfill gas is installed at the Town of Groton Flanders Road landfill in Groton, Connecticut. This joint project by the Connecticut Light & Power Company (CL&P) which is an operating company of Northeast Utilities, the Town of Groton, International Fuel Cells (IFC), and the US EPA is intended to demonstrate the viability of installing, operating and maintaining a fuel cell operating on landfill gas at a landfill site. The goals of the project are to evaluate the fuel cell and gas pretreatment unit operation, test modifications to simplify the GPU design and demonstrate reliability of the entire system.

  16. Franklin County Sanitary Landfill - Landfill Gas (LFG) to Liquefied Natural Gas (LNG) - Project

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    FRANKLIN COUNTY SANITARY LANDFILL - LANDFILL GAS (LFG) TO LIQUEFIED NATURAL GAS (LNG) - PROJECT January/February 2005 Prepared for: National Renewable Energy Laboratory 1617 Cole Boulevard Golden, Colorado 80401 Table of Contents Page BACKGROUND AND INTRODUCTION .......................................................................................1 SUMMARY OF EFFORT PERFORMED ......................................................................................2 Task 2B.1 - Literature Search

  17. Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications

    Broader source: Energy.gov [DOE]

    Landfill gas (LFG), composed largely of methane and carbon dioxide, is used in over 450 operational projects in 43 states. These projects convert a large source of greenhouse gases into a fuel that...

  18. Livingston Parish Landfill Methane Recovery Project (Feasibility Study)

    SciTech Connect (OSTI)

    White, Steven

    2012-11-15

    The Woodside Landfill is owned by Livingston Parish, Louisiana and is operated under contract by Waste Management of Louisiana LLC. This public owner/private operator partnership is commonplace in the solid waste industry today. The landfill has been in operation since approximately 1988 and has a permitted capacity of approximately 41 million cubic yards. Based on an assumed in-place waste density of 0.94 ton per cubic yard, the landfill could have an expected design capacity of 39.3 million tons. The landfill does have an active landfill gas collection and control system (LFGCCS) in place because it meets the minimum thresholds for the New Source Performance Standards (NSPS). The initial LFGCS was installed prior to 2006 and subsequent phases were installed in 2007 and 2010. The Parish received a grant from the United States Department of Energy in 2009 to evaluate the potential for landfill gas recovery and utilization at the Woodside Landfill. This includes a technical and economic feasibility study of a project to install a landfill gas to energy (LFGTE) plant and to compare alternative technologies. The LFGTE plant can take the form of on-site electrical generation, a direct use/medium Btu option, or a high-Btu upgrade technology. The technical evaluation in Section 2 of this report concludes that landfill gas from the Woodside landfill is suitable for recovery and utilization. The financial evaluations in sections 3, 4, and 5 of this report provide financial estimates of the returns for various utilization technologies. The report concludes that the most economically viable project is the Electricity Generation option, subject to the Parish’s ability and willingness to allocate adequate cash for initial capital and/or to obtain debt financing. However, even this option does not present a solid return: by our estimates, there is a 19 year simple payback on the electricity generation option. All of the energy recovery options discussed in this report

  19. Alternative Fuels Data Center: Renewable Natural Gas From Landfill Powers

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Refuse Vehicles Renewable Natural Gas From Landfill Powers Refuse Vehicles to someone by E-mail Share Alternative Fuels Data Center: Renewable Natural Gas From Landfill Powers Refuse Vehicles on Facebook Tweet about Alternative Fuels Data Center: Renewable Natural Gas From Landfill Powers Refuse Vehicles on Twitter Bookmark Alternative Fuels Data Center: Renewable Natural Gas From Landfill Powers Refuse Vehicles on Google Bookmark Alternative Fuels Data Center: Renewable Natural Gas From

  20. Using landfill gas for energy: Projects that pay

    SciTech Connect (OSTI)

    1995-02-01

    Pending Environmental Protection Agency regulations will require 500 to 700 landfills to control gas emissions resulting from decomposing garbage. Conversion of landfill gas to energy not only meets regulations, but also creates energy and revenue for local governments.

  1. Investigation of Integrated Subsurface Processing of Landfill Gas and Carbon Sequestration, Johnson County, Kansas

    SciTech Connect (OSTI)

    K. David Newell; Timothy R. Carr

    2007-03-31

    The Johnson County Landfill in Shawnee, KS is operated by Deffenbaugh Industries and serves much of metropolitan Kansas City. Refuse, which is dumped in large plastic-underlined trash cells covering several acres, is covered over with shale shortly after burial. The landfill waste, once it fills the cell, is then drilled by Kansas City LFG, so that the gas generated by anaerobic decomposition of the refuse can be harvested. Production of raw landfill gas from the Johnson County landfill comes from 150 wells. Daily production is approximately 2.2 to 2.5 mmcf, of which approximately 50% is methane and 50% is carbon dioxide and NMVOCs (non-methane volatile organic compounds). Heating value is approximately 550 BTU/scf. A upgrading plant, utilizing an amine process, rejects the carbon dioxide and NMVOCs, and upgrades the gas to pipeline quality (i.e., nominally a heating value >950 BTU/scf). The gas is sold to a pipeline adjacent to the landfill. With coal-bearing strata underlying the landfill, and carbon dioxide a major effluent gas derived from the upgrading process, the Johnson County Landfill is potentially an ideal setting to study the feasibility of injecting the effluent gas in the coals for both enhanced coalbed methane recovery and carbon sequestration. To these ends, coals below the landfill were cored and then were analyzed for their thickness and sorbed gas content, which ranged up to 79 scf/ton. Assuming 1 1/2 square miles of land (960 acres) at the Johnson County Landfill can be utilized for coalbed and shale gas recovery, the total amount of in-place gas calculates to 946,200 mcf, or 946.2 mmcf, or 0.95 bcf (i.e., 985.6 mcf/acre X 960 acres). Assuming that carbon dioxide can be imbibed by the coals and shales on a 2:1 ratio compared to the gas that was originally present, then 1682 to 1720 days (4.6 to 4.7 years) of landfill carbon dioxide production can be sequestered by the coals and shales immediately under the landfill. Three coal--the Bevier

  2. Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils

    SciTech Connect (OSTI)

    Jeremy Semrau; Sung-Woo Lee; Jeongdae Im; Sukhwan Yoon; Michael Barcelona

    2010-09-30

    The overall objective of this project, 'Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils' was to develop effective, efficient, and economic methodologies by which microbial production of nitrous oxide can be minimized while also maximizing microbial consumption of methane in landfill cover soils. A combination of laboratory and field site experiments found that the addition of nitrogen and phenylacetylene stimulated in situ methane oxidation while minimizing nitrous oxide production. Molecular analyses also indicated that methane-oxidizing bacteria may play a significant role in not only removing methane, but in nitrous oxide production as well, although the contribution of ammonia-oxidizing archaea to nitrous oxide production can not be excluded at this time. Future efforts to control both methane and nitrous oxide emissions from landfills as well as from other environments (e.g., agricultural soils) should consider these issues. Finally, a methanotrophic biofiltration system was designed and modeled for the promotion of methanotrophic activity in local methane 'hotspots' such as landfills. Model results as well as economic analyses of these biofilters indicate that the use of methanotrophic biofilters for controlling methane emissions is technically feasible, and provided either the costs of biofilter construction and operation are reduced or the value of CO{sub 2} credits is increased, can also be economically attractive.

  3. Energy potential of modern landfills

    SciTech Connect (OSTI)

    Bogner, J.E.

    1990-01-01

    Methane produced by refuse decomposition in a sanitary landfill can be recovered for commercial use. Landfill methane is currently under-utilized, with commercial recovery at only a small percentage of US landfills. New federal regulations mandating control of landfill gas migration and atmospheric emissions are providing impetus to methane recovery schemes as a means of recovering costs for increased environmental control. The benefits of landfill methane recovery include utilization of an inexpensive renewable energy resource, removal of explosive gas mixtures from the subsurface, and mitigation of observed historic increases in atmospheric methane. Increased commercial interest in landfill methane recovery is dependent on the final form of Clean Air Act amendments pertaining to gaseous emissions from landfills; market shifts in natural gas prices; financial incentives for development of renewable energy resources; and support for applied research and development to develop techniques for increased control of the gas generation process in situ. This paper will discuss the controls on methane generation in landfills. In addition, it will address how landfill regulations affect landfill design and site management practices which, in turn, influence decomposition rates. Finally, future trends in landfilling, and their relationship to gas production, will be examined. 19 refs., 2 figs., 3 tabs.

  4. Methane Gas Conversion Property Tax Exemption

    Broader source: Energy.gov [DOE]

    Under Iowa's methane gas conversion property tax exemption, real and personal property used to decompose waste and convert the waste to gas, collect the methane or other gases, convert the gas to...

  5. Landfill Gas Conversion to LNG and LCO{sub 2}. Phase II Final Report for January 25, 1999 - April 30, 2000

    SciTech Connect (OSTI)

    Brown, W. R.; Cook, W. J.; Siwajek, L. A.

    2000-10-20

    This report summarizes work on the development of a process to produce LNG (liquefied methane) for heavy vehicle use from landfill gas (LFG) using Acrion's CO{sub 2} wash process for contaminant removal and CO{sub 2} recovery.

  6. EIA - Greenhouse Gas Emissions - Methane Emissions

    Gasoline and Diesel Fuel Update (EIA)

    3. Methane Emissions 3.1. Total emissions The major sources of U.S. methane emissions are energy production, distribution, and use; agriculture; and waste management (Figure 17). U.S. methane emissions in 2009 totaled 731 MMTCO2e, 0.9 percent higher than the 2008 total of 724 MMTCO2e (Table 17). Methane emissions declined steadily from 1990 to 2001, as emissions from coal mining and landfills fell, then rose from 2002 to 2009 as a result of moderate increases in emissions related to energy,

  7. Renewable Energy Holdings Landfill Gas Wales Ltd REH Wales |...

    Open Energy Info (EERE)

    Gas Wales Ltd REH Wales Jump to: navigation, search Name: Renewable Energy Holdings Landfill Gas (Wales) Ltd (REH Wales) Place: United Kingdom Product: A joint venture to own and...

  8. Recovery Act: Brea California Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2012-12-31

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Olinda Landfill near Brea, California. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting Project reflected a cost effective balance of the following specific sub-objectives: • Meeting the environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas • Utilizing proven and reliable technology and equipment • Maximizing electrical efficiency • Maximizing electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Olinda Landfill • Maximizing equipment uptime • Minimizing water consumption • Minimizing post-combustion emissions • The Project produced and will produce a myriad of beneficial impacts. o The Project created 360 FTE construction and manufacturing jobs and 15 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. o By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). o The Project will annually produce 280,320 MWh’s of clean energy o By destroying the methane in the landfill gas, the Project will generate CO2 equivalent reductions of 164,938 tons annually. The completed facility produces 27.4 MWnet and operates 24 hours a day, seven days a week.

  9. Albany Interim Landfill gas extraction and mobile power system: Using landfill gas to produce electricity. Final report

    SciTech Connect (OSTI)

    1997-06-01

    The Albany Interim Landfill Gas Extraction and Mobile Power System project served three research objectives: (1) determination of the general efficiency and radius of influence of horizontally placed landfill gas extraction conduits; (2) determination of cost and effectiveness of a hydrogen sulfide gas scrubber utilizing Enviro-Scrub{trademark} liquid reagent; and (3) construction and evaluation of a dual-fuel (landfill gas/diesel) 100 kW mobile power station. The horizontal gas extraction system was very successful; overall, gas recovery was high and the practical radius of influence of individual extractors was about 50 feet. The hydrogen sulfide scrubber was effective and its use appears feasible at typical hydrogen sulfide concentrations and gas flows. The dual-fuel mobile power station performed dependably and was able to deliver smooth power output under varying load and landfill gas fuel conditions.

  10. Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2013-06-30

    systems, the Project established new national standards for best available control technology (BACT). 3) The Project will annually produce 365,292 MWh's of clean energy. 4) By destroying the methane in the landfill gas, the Project will generate CO{sub 2} equivalent reductions of 164,938 tons annually. The completed facility produces 28.3 MWnet and operates 24 hours a day, seven days a week.

  11. Emission assessment at the Burj Hammoud inactive municipal landfill: Viability of landfill gas recovery under the clean development mechanism

    SciTech Connect (OSTI)

    El-Fadel, Mutasem; Abi-Esber, Layale; Salhab, Samer

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer LFG emissions are measured at an abandoned landfill with highly organic waste. Black-Right-Pointing-Pointer Mean headspace and vent emissions are 0.240 and 0.074 l CH{sub 4}/m{sup 2} hr, respectively. Black-Right-Pointing-Pointer At sites with high food waste content, LFG generation drops rapidly after site closure. Black-Right-Pointing-Pointer The viability of LFG recovery for CDMs in developing countries is doubtful. - Abstract: This paper examines landfill gas (LFG) emissions at a large inactive waste disposal site to evaluate the viability of investment in LFG recovery through the clean development mechanism (CDM) initiative. For this purpose, field measurements of LFG emissions were conducted and the data were processed by geospatial interpolation to estimate an equivalent site emission rate which was used to calibrate and apply two LFG prediction models to forecast LFG emissions at the site. The mean CH{sub 4} flux values calculated through tessellation, inverse distance weighing and kriging were 0.188 {+-} 0.014, 0.224 {+-} 0.012 and 0.237 {+-} 0.008 l CH{sub 4}/m{sup 2} hr, respectively, compared to an arithmetic mean of 0.24 l/m{sup 2} hr. The flux values are within the reported range for closed landfills (0.06-0.89 l/m{sup 2} hr), and lower than the reported range for active landfills (0.42-2.46 l/m{sup 2} hr). Simulation results matched field measurements for low methane generation potential (L{sub 0}) values in the range of 19.8-102.6 m{sup 3}/ton of waste. LFG generation dropped rapidly to half its peak level only 4 yrs after landfill closure limiting the sustainability of LFG recovery systems in similar contexts and raising into doubt promoted CDM initiatives for similar waste.

  12. Fuel Flexibility: Landfill Gas Contaminant Mitigation for Power Generation

    SciTech Connect (OSTI)

    Storey, John Morse; Theiss, Timothy J; Kass, Michael D; FINNEY, Charles E A; Lewis, Samuel; Kaul, Brian C; Besmann, Theodore M; Thomas, John F; Rogers, Hiram; Sepaniak, Michael

    2014-04-01

    This research project focused on the mitigation of silica damage to engine-based renewable landfill gas energy systems. Characterization of the landfill gas siloxane contamination, combined with characterization of the silica deposits in engines, led to development of two new mitigation strategies. The first involved a novel method for removing the siloxanes and other heavy contaminants from the landfill gas prior to use by the engines. The second strategy sought to interrupt the formation of hard silica deposits in the engine itself, based on inspection of failed landfill gas engine parts. In addition to mitigation, the project had a third task to develop a robust sensor for siloxanes that could be used to control existing and/or future removal processes.

  13. Renewable LNG: Update on the World's Largest Landfill Gas to...

    Broader source: Energy.gov (indexed) [DOE]

    Success story about LNG from landfill gas. Presented by Mike McGowan, Linde NA, Inc., at the NRELDOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado. ...

  14. Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications

    SciTech Connect (OSTI)

    2009-02-01

    Gas Technology Institute will collaborate with Integrated CHP Systems Corporation, West Virginia University, Vronay Engineering Services, KAR Engineering Associates, Pioneer Air Systems, and Energy Concepts Company to recover waste heat from reciprocating engines. The project will integrate waste heat recovery along with gas clean-up technology system improvements. This will address fuel quality issues that have hampered expanded use of opportunity fuels such as landfill gas, digester biogas, and coal mine methane. This will enable increased application of CHP using renewable and domestically derived opportunity fuels.

  15. Landfill Gas and Biogas - Energy Explained, Your Guide To Understanding

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy - Energy Information Administration Landfill Gas and Biogas Energy Explained - Home What Is Energy? Forms of Energy Sources of Energy Laws of Energy Units and Calculators Energy Conversion Calculators British Thermal Units (Btu) Degree-Days U.S. Energy Facts State and U.S. Territory Data Use of Energy In Industry For Transportation In Homes In Commercial Buildings Efficiency and Conservation Energy and the Environment Greenhouse Gases Effect on the Climate Where Greenhouse Gases Come

  16. Methanation process utilizing split cold gas recycle

    DOE Patents [OSTI]

    Tajbl, Daniel G.; Lee, Bernard S.; Schora, Jr., Frank C.; Lam, Henry W.

    1976-07-06

    In the methanation of feed gas comprising carbon monoxide and hydrogen in multiple stages, the feed gas, cold recycle gas and hot product gas is mixed in such proportions that the mixture is at a temperature sufficiently high to avoid carbonyl formation and to initiate the reaction and, so that upon complete reaction of the carbon monoxide and hydrogen, an excessive adiabatic temperature will not be reached. Catalyst damage by high or low temperatures is thereby avoided with a process that utilizes extraordinarily low recycle ratios and a minimum of investment in operating costs.

  17. Spatial variability of nitrous oxide and methane emissions from an MBT landfill in operation: Strong N{sub 2}O hotspots at the working face

    SciTech Connect (OSTI)

    Harborth, Peter; Fu, Roland; Mnnich, Kai; Flessa, Heinz; Fricke, Klaus

    2013-10-15

    Highlights: ? First measurements of N{sub 2}O and CH{sub 4} emissions from an MBT landfill. ? High N{sub 2}O emissions from recently deposited material. ? N{sub 2}O emissions associated with aeration and the occurrence of nitrite and nitrate. ? Strong negative correlation between CH{sub 4} and N{sub 2}O production activity. - Abstract: Mechanical biological treatment (MBT) is an effective technique, which removes organic carbon from municipal solid waste (MSW) prior to deposition. Thereby, methane (CH{sub 4}) production in the landfill is strongly mitigated. However, direct measurements of greenhouse gas emissions from full-scale MBT landfills have not been conducted so far. Thus, CH{sub 4} and nitrous oxide (N{sub 2}O) emissions from a German MBT landfill in operation as well as their concentrations in the landfill gas (LFG) were measured. High N{sub 2}O emissions of 20200 g CO{sub 2} eq. m{sup ?2} h{sup ?1} magnitude (up to 428 mg N m{sup ?2} h{sup ?1}) were observed within 20 m of the working face. CH{sub 4} emissions were highest at the landfill zone located at a distance of 3040 m from the working face, where they reached about 10 g CO{sub 2} eq. m{sup ?2} h{sup ?1}. The MBT material in this area has been deposited several weeks earlier. Maximum LFG concentration for N{sub 2}O was 24.000 ppmv in material below the emission hotspot. At a depth of 50 cm from the landfill surface a strong negative correlation between N{sub 2}O and CH{sub 4} concentrations was observed. From this and from the distribution pattern of extractable ammonium, nitrite, and nitrate it has been concluded that strong N{sub 2}O production is associated with nitrification activity and the occurrence of nitrite and nitrate, which is initiated by oxygen input during waste deposition. Therefore, CH{sub 4} mitigation measures, which often employ aeration, could result in a net increase of GHG emissions due to increased N{sub 2}O emissions, especially at MBT landfills.

  18. Case Studies from the Climate Technology Partnership: Landfill Gas Projects in South Korea and Lessons Learned

    SciTech Connect (OSTI)

    Larney, C.; Heil, M.; Ha, G. A.

    2006-12-01

    This paper examines landfill gas projects in South Korea. Two case studies provide concrete examples of lessons learned and offer practical guidance for future projects.

  19. Community Renewable Energy Success Stories: Landfill Gas-to-Energy Projects Webinar (text version)

    Broader source: Energy.gov [DOE]

    Below is the text version of the Webinar titled "Community Renewable Energy Success Stories: Landfill Gas-to-Energy Projects," originally presented on July 17, 2012.

  20. Industrial landfill leachate characterization and treatment utilizing anaerobic digestion with methane production

    SciTech Connect (OSTI)

    Corbo, P.

    1985-01-01

    Anaerobic digestion of organic compounds found in an industrial landfill leachate originating from a Superfund site was assessed using mixed methanogenic cultures. Leachate was found to contain a dissolved organic content (DOC) of about 16,000 mg/liter, of which 40% was in the form of acetic, propionic and butyric acids. The overall reduction of DOC and the fates of individual volatile fatty acids were studied during batch experiments of 5, 10, and 20% leachate dilutions. Other leachate components were characterized. Two methanogenic cultures were selected. A leachate digesting culture was selected directly with the leachate. A volatile fatty acid digesting culture was selected using acetic, propionic and butyric acids in the ratio found in the leachate. An overall DOC reduction of 64.3% was observed for the leachate digesting culture. A reduction of 69.1% was observed for the volatile fatty acid digesting culture. Specific DOC utilization rates were 0.154 and 0.211 day/sup -1/, for the leachate digesting and volatile fatty acid digesting cultures, respectively. Methane was produced at levels of 0.95-0.99 liters per gram DOC removed. Cell growth could not be observed during batch experiments. Acetate appeared to be the rate-limiting step in the DOC removal. Batch experiments with 20% leachate dilutions did not produce much methane, possibly due to overloading systems with volatile fatty acids. Other leachate components did not appear to effect anaerobic digestion.

  1. Landfill gas cleanup for carbonate fuel cell power generation. Final report

    SciTech Connect (OSTI)

    Steinfield, G.; Sanderson, R.

    1998-02-01

    Landfill gas represents a significant fuel resource both in the US and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. A pilot plant cleaned approximately 970,000 scf of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations: less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorinated hydrocarbon; and 1.5 ppm sulfur dioxide.

  2. Controlling Methane Emissions in the Natural Gas Sector: A Review...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State ... often are constrained in the investments that they are willing or able to make ...

  3. Project identification for methane reduction options

    SciTech Connect (OSTI)

    Kerr, T.

    1996-12-31

    This paper discusses efforts directed at reduction in emission of methane to the atmosphere. Methane is a potent greenhouse gas, which on a 20 year timeframe may present a similar problem to carbon dioxide. In addition, methane causes additional problems in the form of smog and its longer atmospheric lifetime. The author discusses strategies for reducing methane emission from several major sources. This includes landfill methane recovery, coalbed methane recovery, livestock methane reduction - in the form of ruminant methane reduction and manure methane recovery. The author presents examples of projects which have implemented these ideas, the economics of the projects, and additional gains which come from the projects.

  4. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study

    SciTech Connect (OSTI)

    2013-04-30

    BroadRock Renewables, LLC built two high efficiency electricity generating facilities that utilize landfill gas in California and Rhode Island. The two projects received a total of $25 million in U.S. Department of Energy funding from the American Recovery and Reinvestment Act (ARRA) of 2009. Private-sector cost share for the projects totaled approximately $186 million.

  5. Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill

    SciTech Connect (OSTI)

    Wang, Xiaojun; Jia, Mingsheng; Chen, Xiaohai; Xu, Ying; Lin, Xiangyu; Kao, Chih Ming; Chen, Shaohua

    2014-07-15

    Highlights: • Young and aged leachate works accounted for 89.1% and 10.9% of 33.35 Gg CO{sub 2} yr{sup −1}. • Fresh leachate owned extremely low ORP and high organic matter content. • Strong CH{sub 4} emissions occurred in the fresh leachate ponds, but small in the aged. • N{sub 2}O emissions became dominant in the treatment units of both systems. • 8.45–11.9% of nitrogen was removed as the form of N{sub 2}O under steady-state. - Abstract: With limited assessment, leachate treatment of a specified landfill is considered to be a significant source of greenhouse gas (GHG) emissions. In our study, the cumulative GHG emitted from the storage ponds and process configurations that manage fresh or aged landfill leachate were investigated. Our results showed that strong CH{sub 4} emissions were observed from the fresh leachate storage pond, with the fluxes values (2219–26,489 mg C m{sup −2} h{sup −1}) extremely higher than those of N{sub 2}O (0.028–0.41 mg N m{sup −2} h{sup −1}). In contrast, the emission values for both CH{sub 4} and N{sub 2}O were low for the aged leachate tank. N{sub 2}O emissions became dominant once the leachate entered the treatment plants of both systems, accounting for 8–12% of the removal of N-species gases. Per capita, the N{sub 2}O emission based on both leachate treatment systems was estimated to be 7.99 g N{sub 2}O–N capita{sup −1} yr{sup −1}. An increase of 80% in N{sub 2}O emissions was observed when the bioreactor pH decreased by approximately 1 pH unit. The vast majority of carbon was removed in the form of CO{sub 2}, with a small portion as CH{sub 4} (<0.3%) during both treatment processes. The cumulative GHG emissions for fresh leachate storage ponds, fresh leachate treatment system and aged leachate treatment system were 19.10, 10.62 and 3.63 Gg CO{sub 2} eq yr{sup −1}, respectively, for a total that could be transformed to 9.09 kg CO{sub 2} eq capita{sup −1} yr{sup −1}.

  6. Westchester Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Landfill Biomass Facility Jump to: navigation, search Name Westchester Landfill Biomass Facility Facility Westchester Landfill Sector Biomass Facility Type Landfill Gas Location...

  7. Kiefer Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Kiefer Landfill Biomass Facility Jump to: navigation, search Name Kiefer Landfill Biomass Facility Facility Kiefer Landfill Sector Biomass Facility Type Landfill Gas Location...

  8. Venice Park landfill: Working with the community

    SciTech Connect (OSTI)

    McAdams, C.L.

    1993-09-01

    Venice Park landfill was one of the first sites to be permitted under Michigan's proposed Public Act 641. PA 641 essentially changed the rules and regulations for landfills from the simple design of digging a hole and filling it. It also upgraded standards to those that are more sophisticated, including liners, leachate collection systems, and gas extraction systems. In 1992, methane gas from the landfill was collected into wells drilled into the trash varying in depth from 30-50 feet in depth. A vacuum pulls the gas from the trash into the wells, then through a piping system. The landfill uses about 80-100 kilowatts in-house. The remainder of the gas is sold to Consumers Power Co. which uses landfill gas to supply power to homes.

  9. Renewable LNG: Update on the World's Largest Landfill Gas to LNG Plant

    Office of Energy Efficiency and Renewable Energy (EERE)

    Success story about LNG from landfill gas. Presented by Mike McGowan, Linde NA, Inc., at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

  10. Property:Building/SPPurchasedEngyForPeriodMwhYrDigesterLandfillGas...

    Open Energy Info (EERE)

    YrDigesterLandfillGas" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  11. Property:Building/SPPurchasedEngyNrmlYrMwhYrDigesterLandfillGas...

    Open Energy Info (EERE)

    YrDigesterLandfillGas" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  12. GTZ-Greenhouse Gas Calculator for Waste Management | Open Energy...

    Open Energy Info (EERE)

    a great part of the national greenhouse gas production, because landfills produce methane which has a particularly strong effect on climate change. Therefore, it is essential...

  13. A Path to Reduce Methane Emissions from Gas Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Path to Reduce Methane Emissions from Gas Systems A Path to Reduce Methane Emissions from Gas Systems July 29, 2014 - 3:33pm Addthis A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy Department. A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy

  14. BUNCOMBE COUNTY WASTEWATER PRE-TREATMENT AND LANDFILL GAS TO ENERGY PROJECT

    SciTech Connect (OSTI)

    Jon Creighton

    2012-03-13

    The objective of this project was to construct a landfill gas-to-energy (LFGTE) facility that generates a renewable energy source utilizing landfill gas to power a 1.4MW generator, while at the same time reducing the amount of leachate hauled offsite for treatment. The project included an enhanced gas collection and control system, gas conditioning equipment, and a 1.4 MW generator set. The production of cleaner renewable energy will help offset the carbon footprint of other energy sources that are currently utilized.

  15. Experimental and life cycle assessment analysis of gas emission from mechanicallybiologically pretreated waste in a landfill with energy recovery

    SciTech Connect (OSTI)

    Di Maria, Francesco Sordi, Alessio; Micale, Caterina

    2013-11-15

    Highlights: Bio-methane landfill emissions from different period (0, 4, 8, 16 weeks) MTB waste have been evaluated. Electrical energy recoverable from landfill gas ranges from 11 to about 90 kW h/tonne. Correlation between oxygen uptake, energy recovery and anaerobic gas production shows R{sup 2} ranging from 0.78 to 0.98. LCA demonstrate that global impact related to gaseous emissions achieve minimum for 4 week of MBT. - Abstract: The global gaseous emissions produced by landfilling the Mechanically Sorted Organic Fraction (MSOF) with different weeks of Mechanical Biological Treatment (MBT) was evaluated for an existing waste management system. One MBT facility and a landfill with internal combustion engines fuelled by the landfill gas for electrical energy production operate in the waste management system considered. An experimental apparatus was used to simulate 0, 4, 8 and 16 weeks of aerobic stabilization and the consequent biogas potential (Nl/kg) of a large sample of MSOF withdrawn from the full-scale MBT. Stabilization achieved by the waste was evaluated by dynamic oxygen uptake and fermentation tests. Good correlation coefficients (R{sup 2}), ranging from 0.7668 to 0.9772, were found between oxygen uptake, fermentation and anaerobic test values. On the basis of the results of several anaerobic tests, the methane production rate k (year{sup ?1}) was evaluated. k ranged from 0.436 to 0.308 year{sup ?1} and the bio-methane potential from 37 to 12 N m{sup 3}/tonne, respectively, for the MSOF with 0 and 16 weeks of treatment. Energy recovery from landfill gas ranged from about 11 to 90 kW h per tonne of disposed MSOF depending on the different scenario investigated. Life cycle analysis showed that the scenario with 0 weeks of pre-treatment has the highest weighted global impact even if opposite results were obtained with respect to the single impact criteria. MSOF pre-treatment periods longer than 4 weeks showed rather negligible variation in the global

  16. Dewatering of coalbed methane wells with hydraulic gas pump

    SciTech Connect (OSTI)

    Amani, M.; Juvkam-Wold, H.C.

    1995-12-31

    The coalbed methane industry has become an important source of natural gas production. Proper dewatering of coalbed methane (CBM) wells is the key to efficient gas production from these reservoirs. This paper presents the Hydraulic Gas Pump as a new alternative dewatering system for CBM wells. The Hydraulic Gas Pump (HGP) concept offers several operational advantages for CBM wells. Gas interference does not affect its operation. It resists solids damage by eliminating the lift mechanism and reducing the number of moving parts. The HGP has a flexible production rate and is suitable for all production phases of CBM wells. It can also be designed as a wireline retrievable system. We conclude that the Hydraulic Gas Pump is a suitable dewatering system for coalbed methane wells.

  17. Commodity chemicals from natural gas by methane chlorination

    SciTech Connect (OSTI)

    Che, S.C.; Minet, R.G.; Giacobbe, F.; Mullick, S.L.

    1987-01-01

    Ethylene and vinyl chloride monomer (VCM) can be produced from natural gas through methane chlorination by reacting methane and chlorine at 900/sup 0/C or higher. Experimental results indicate total ethylene equivalent yield from methane of 45%(wt) and marginal process economics. Fundamental kinetic modeling predicts improved C/sub 2/ yields of up to 70%(wt) at optimum reaction conditions. This optimum condition established the basis for the process design study to evaluate the potential for producing ethylene and VCM from natural gas. HCl by-product is recycled for economic viability. Using the Kel-Chlor process for recycling HCl, the proposed plant produces 27,200 TPA of C/sub 2/H/sub 4/ and 383,800 TPA of VCM. The Midwest is an ethylene consumption area requiring imports of ethylene derivatives from other regions. A methane chlorination plant located on a Midwestern natural gas pipeline network has a good commercial potential.

  18. Methane Credit | Open Energy Information

    Open Energy Info (EERE)

    Methane Credit Jump to: navigation, search Name: Methane Credit Place: Charlotte, North Carolina Zip: 28273 Product: Specialises in utilising methane produced on municipal landfill...

  19. Methanation of gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C.

    1983-01-01

    Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

  20. Discovery of New Materials to Capture Methane | U.S. DOE Office...

    Office of Science (SC) Website

    Summary Methane, a common gas emitted from natural gas systems, landfills, coal mining, waste water treatment and hydrates in the ocean, is both a great energy source and a ...

  1. Garbage In, Power Out: South Carolina BMW Plant Demonstrates Landfill Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Hydrogen Fuel | Department of Energy Garbage In, Power Out: South Carolina BMW Plant Demonstrates Landfill Gas to Hydrogen Fuel Garbage In, Power Out: South Carolina BMW Plant Demonstrates Landfill Gas to Hydrogen Fuel August 25, 2015 - 2:15pm Addthis The plant BMW plant in Greer, South Carolina is home to the world's largest fleet of fuel cell forklifts. | Photo courtesy of BMW Manufacturing. The plant BMW plant in Greer, South Carolina is home to the world's largest fleet of fuel cell

  2. Ocean County Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    County Landfill Biomass Facility Jump to: navigation, search Name Ocean County Landfill Biomass Facility Facility Ocean County Landfill Sector Biomass Facility Type Landfill Gas...

  3. Pearl Hollow Landfil Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Hollow Landfil Biomass Facility Jump to: navigation, search Name Pearl Hollow Landfil Biomass Facility Facility Pearl Hollow Landfil Sector Biomass Facility Type Landfill Gas...

  4. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions- Case Study, 2013

    Broader source: Energy.gov [DOE]

    Case study overviewing two large landfill projects in California and Rhode Island funded by the Recovery Act

  5. Property:Building/SPPurchasedEngyPerAreaKwhM2DigesterLandfillGas...

    Open Energy Info (EERE)

    M2DigesterLandfillGas" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  6. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Xu, Liukang; McDermitt, Dayle; Anderson, Tyler; Riensche, Brad; Komissarov, Anatoly; Howe, Julie

    2012-02-01

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been

  7. Nation's first fuel cell power plant powered by processed landfill gas

    SciTech Connect (OSTI)

    Leeper, J.D.; Engels, W.W.

    1986-04-01

    Southern California Edison Company (Edison) and the Los Angeles Department of Water and Power (LADWP) installed, and are operating, a 40 kw phosphoric acid fuel cell utilizing processed landfill gas at a hotel and convention complex in the City of Industry, California. This field test aims to establish important electric utility operating criteria of two separate, promising technologies linked together for the first time. Among the key objectives to be established during this project are: (1) operating a fuel cell to establish electric generation equipment criteria, such as fuel efficiency, reliability, siteability, and emission and electric output characteristics; (2) determining whether under-utilized landfill gas can be used in a fuel cell designed to operate on natural gas; and (3) identifying methods to improve the economic viability of such a system.

  8. Sources of biogenic methane to form marine gas hydrates: In situ production or upward migration?

    SciTech Connect (OSTI)

    Paull, C.K.; Ussler, W. III; Borowski, W.S.

    1993-09-01

    Potential sources of biogenic methane in the Carolina Continental Rise -- Blake Ridge sediments have been examined. Two models were used to estimate the potential for biogenic methane production: (1) construction of sedimentary organic carbon budgets, and (2) depth extrapolation of modern microbial production rates. While closed-system estimates predict some gas hydrate formation, it is unlikely that >3% of the sediment volume could be filled by hydrate from methane produced in situ. Formation of greater amounts requires migration of methane from the underlying continental rise sediment prism. Methane may be recycled from below the base of the gas hydrate stability zone by gas hydrate decomposition, upward migration of the methane gas, and recrystallization of gas hydrate within the overlying stability zone. Methane bubbles may also form in the sediment column below the depth of gas hydrate stability because the methane saturation concentration of the pore fluids decreases with increasing depth. Upward migration of methane bubbles from these deeper sediments can add methane to the hydrate stability zone. From these models it appears that recycling and upward migration of methane is essential in forming significant gas hydrate concentrations. In addition, the depth distribution profiles of methane hydrate will differ if the majority of the methane has migrated upward rather than having been produced in situ.

  9. Gettering of Hydrogen and Methane from a Helium Gas Mixture

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cardenas, Rosa E.; Stewart, Kenneth D.; Cowgill, Donald F.

    2014-10-21

    In our study, the authors developed an approach for accurately quantifying the helium content in a gas mixture also containing hydrogen and methane using commercially available getters. The authors performed a systematic study to examine how both H2 and CH4 can be removed simultaneously from the mixture using two SAES St 172® getters operating at different temperatures. The remaining He within the gas mixture can then be measured directly using a capacitance manometer. Moreover, the optimum combination involved operating one getter at 650°C to decompose the methane, and the second at 110°C to remove the hydrogen. Finally, this approach eliminatedmore » the need to reactivate the getters between measurements, thereby enabling multiple measurements to be made within a short time interval, with accuracy better than 1%. The authors anticipate that such an approach will be particularly useful for quantifying the He-3 in mixtures that include tritium, tritiated methane, and helium-3. The presence of tritiated methane, generated by tritium activity, often complicates such measurements.« less

  10. Gettering of Hydrogen and Methane from a Helium Gas Mixture

    SciTech Connect (OSTI)

    Cardenas, Rosa E.; Stewart, Kenneth D.; Cowgill, Donald F.

    2014-10-21

    In our study, the authors developed an approach for accurately quantifying the helium content in a gas mixture also containing hydrogen and methane using commercially available getters. The authors performed a systematic study to examine how both H2 and CH4 can be removed simultaneously from the mixture using two SAES St 172® getters operating at different temperatures. The remaining He within the gas mixture can then be measured directly using a capacitance manometer. Moreover, the optimum combination involved operating one getter at 650°C to decompose the methane, and the second at 110°C to remove the hydrogen. Finally, this approach eliminated the need to reactivate the getters between measurements, thereby enabling multiple measurements to be made within a short time interval, with accuracy better than 1%. The authors anticipate that such an approach will be particularly useful for quantifying the He-3 in mixtures that include tritium, tritiated methane, and helium-3. The presence of tritiated methane, generated by tritium activity, often complicates such measurements.

  11. Gettering of hydrogen and methane from a helium gas mixture

    SciTech Connect (OSTI)

    Crdenas, Rosa Elia; Stewart, Kenneth D.; Cowgill, Donald F.

    2014-11-01

    In this study, the authors developed an approach for accurately quantifying the helium content in a gas mixture also containing hydrogen and methane using commercially available getters. The authors performed a systematic study to examine how both H{sub 2} and CH{sub 4} can be removed simultaneously from the mixture using two SAES St 172{sup } getters operating at different temperatures. The remaining He within the gas mixture can then be measured directly using a capacitance manometer. The optimum combination involved operating one getter at 650?C to decompose the methane, and the second at 110?C to remove the hydrogen. This approach eliminated the need to reactivate the getters between measurements, thereby enabling multiple measurements to be made within a short time interval, with accuracy better than 1%. The authors anticipate that such an approach will be particularly useful for quantifying the He-3 in mixtures that include tritium, tritiated methane, and helium-3. The presence of tritiated methane, generated by tritium activity, often complicates such measurements.

  12. List of Landfill Gas Incentives | Open Energy Information

    Open Energy Info (EERE)

    Waste Photovoltaics Solar Thermal Electric Coal with CCS Energy Storage Nuclear Wind Natural Gas Yes Alternative Energy Portfolio Standard (Pennsylvania) Renewables Portfolio...

  13. Methane sources and emissions in Italy

    SciTech Connect (OSTI)

    Guidotti, G.R.; Castagnola, A.M.

    1994-12-31

    Methane emissions in Italy were assessed in the framework of the measures taken to follow out the commitments undertaken at the 1992 U.N. Conference for Environment and Development. Methane emissions of anthropic origin were estimated to be in the range of 1.6 to 2.3 million ton of methane per year. Some of these methane sources (natural gas production, transmission and distribution; rice paddies; managed livestock enteric fermentation and waste; solid waste landfills) are given here particular care as they mainly contribute to the total methane emission budget.

  14. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Infrastructure R&D and Methane Emissions Mitigation Workshop November 12-13, 2014 Advanced Materials Manufacturing and Innovative Technologies for Natural Gas Pipeline Systems and Components Panel > November 12, 2014 > Pittsburgh, PA > By Daniel Ersoy, GTI Nat. Gas Infrastructure R&D /Methane Emissions Mitigation Workshop, Nov. 2014, Pittsburgh, PA 2 Nat. Gas Infrastructure R&D /Methane Emissions Mitigation Workshop, Nov. 2014, Pittsburgh, PA 2 GTI Company Overview

  15. Saga of coal bed methane, Ignacio Blanco gas field, Colorado

    SciTech Connect (OSTI)

    Boyce, B.C.; Harr, C.L.; Burch, L.C. )

    1989-09-01

    Prior to the 1977 discovery of the Cedar Hill Basal Fruitland pool (the first officially designated coal-bed methane field in the western US) 28.5 bcf of gas had been produced from Fruitland Formation coal seams in the Ignacio Blanco Fruitland-Pictured Cliffs field, Northern San Juan basin, Colorado. The discovery well for the field, Southern Ute D-1, was drilled and completed in 1951 on the Ignacio anticline, La Plata County, Colorado. Initial completion was attempted in the Pictured Cliffs Sandstone. The well was plugged back after making water from the Pictured Cliffs and was completed in the lower coal-bearing section of the Fruitland Formation. The well produced 487,333 mcf of gas in nine years and was abandoned in 1959 due to water encroachment. Additionally, 52 similarly completed Ignacio anticline Fruitland wells were abandoned by the early 1970s due to the nemesis of If it's starting to kick water, you're through. Under today's coal-bed methane technology and economics, Amoco has twinned 12 of the abandoned wells, drilled five additional wells, and is successfully dewatering and producing adsorbed methane from previously depleted coal sections of the Ignacio structure. Field-wide drilling activity in 1988 exceeded all previous annual levels, with coal-seam degasification projects leading the resurgence. Drilling and completion forecasts for 1989 surpass 1988 levels by 50%.

  16. Catalyst for the methanation of carbon monoxide in sour gas

    DOE Patents [OSTI]

    Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

    1985-01-01

    The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

  17. JISEA News: Study on Methane Emissions from Natural Gas Systems Indicates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Priorities - News Releases | NREL JISEA News: Study on Methane Emissions from Natural Gas Systems Indicates New Priorities Study findings published in Policy Forum of Journal Science February 18, 2014 A new study published in the journal Science says that the total impact of switching to natural gas depends heavily on leakage of methane (CH4) during the natural gas life cycle, and suggests that more can be done to reduce methane emissions and to improve measurement tools which help

  18. Landfill Energy Systems LES | Open Energy Information

    Open Energy Info (EERE)

    Energy Systems LES Jump to: navigation, search Name: Landfill Energy Systems (LES) Place: Michigan Zip: 48393 Product: Landfill gas to energy systems project developer, gas...

  19. Renewable LNG: Update on the World's Largest Landfill Gas to LNG Plant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LNG Update on the world's largest landfill gas to LNG plant Mike McGowan Head of Government Affairs Linde NA, Inc. June 12, 2012 $18.3 billion global sales A leading gases and engineering company Linde North America Profile $2.3 billion in gases sales revenue in North America in 2011 5,000 employees throughout the U.S., Canada and the Caribbean Supplier of compressed and cryogenic gases and technology Atmospheric gases - oxygen, nitrogen, argon Helium LNG and LPG Hydrogen Rare gases Plant

  20. The future of methane

    SciTech Connect (OSTI)

    Howell, D.G.

    1995-12-31

    Natural gas, mainly methane, produces lower CO{sub 2}, CO, NO{sub x}, SO{sub 2} and particulate emissions than either oil or coal; thus further substitutions of methane for these fuels could help mitigate air pollution. Methane is, however, a potent greenhouse gas and the domestication of ruminants, cultivation of rice, mining of coal, drilling for oil, and transportation of natural gas have all contributed to a doubling of the amount of atmospheric methane since 1800. Today nearly 300,000 wells yearly produce ca. 21 trillion cubic feet of methane. Known reserves suggest about a 10 year supply at the above rates of recovery; and the potential for undiscovered resources is obscured by uncertainty involving price, new technologies, and environmental restrictions steming from the need to drill an enormous number of wells, many in ecologically sensitive areas. Until all these aspects of methane are better understood, its future role in the world`s energy mix will remain uncertain. The atomic simplicity of methane, composed of one carbon and four hydrogen atoms, may mask the complexity and importance of this, the most basic of organic molecules. Within the Earth, methane is produced through thermochemical alteration of organic materials, and by biochemical reactions mediated by metabolic processes of archaebacteria; some methane may even be primordial, a residue of planetary accretion. Methane also occurs in smaller volumes in landfills, rice paddies, termite complexes, ruminants, and even many humans. As an energy source, its full energy potential is controversial. Methane is touted by some as a viable bridge to future energy systems, fueled by the sun and uranium and carried by electricity and hydrogen.

  1. Controlling Methane Emissions in the Natural Gas Sector: A Review of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Federal & State Regulatory Frameworks Governing Production, Processing, Transmission, and Distribution | Department of Energy Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Processing, Transmission, and Distribution Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Processing, Transmission, and Distribution This paper

  2. METHANE GAS STABILIZES SUPERCOOLED ETHANE DROPLETS IN TITAN'S CLOUDS

    SciTech Connect (OSTI)

    Wang, Chia C.; Lang, E. Kathrin; Signorell, Ruth

    2010-03-20

    Strong evidence for ethane clouds in various regions of Titan's atmosphere has recently been found. Ethane is usually assumed to exist as ice particles in these clouds, although the possible role of liquid and supercooled liquid ethane droplets has been recognized. Here, we report on infrared spectroscopic measurements of ethane aerosols performed in the laboratory under conditions mimicking Titan's lower atmosphere. The results clearly show that liquid ethane droplets are significantly stabilized by methane gas which is ubiquitous in Titan's nitrogen atmosphere-a phenomenon that does not have a counterpart for water droplets in Earth's atmosphere. Our data imply that supercooled ethane droplets are much more abundant in Titan's clouds than previously anticipated. Possibly, these liquid droplets are even more important for cloud processes and the formation of lakes than ethane ice particles.

  3. Landfill gas cleanup for carbonate fuel cell power generation. CRADA final report

    SciTech Connect (OSTI)

    Steinfeld, G.; Sanderson, R.

    1998-02-01

    The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. The technical effort was conducted by EPRI, consultant David Thimsen, Kaltec of Minnesota, Energy Research Corporation (ERC) and Interpoll Laboratories. The Electric Power Research Institute (EPRI) made available two test skids originally used to test an ERC 30 kW carbonate fuel cell at the Destec Coal Gasification Plan in Plaquemine, LA. EPRI`s carbonate fuel cell pilot plant was installed at the Anoka County Regional Landfill in Ramsey, Minnesota. Additional gas cleaning equipment was installed to evaluate a potentially inexpensive, multi-stage gas cleaning process to remove sulfur and chlorine in the gas to levels acceptable for long-term, economical carbonate fuel cell operation. The pilot plant cleaned approximately 970,000 scf (27,500 Nm{sup 3}) of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations. Less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorined hydrocarbon; and 1.5 ppm sulfur dioxide. These were the detection limits of the analytical procedures employed. It is probable that the actual concentrations are below these analytical limits.

  4. Development of Real-Time, Gas Quality Sensor Technology

    Broader source: Energy.gov [DOE]

    Landfill gas (LFG), composed largely of methane and carbon dioxide, is used in over 645 operational projects in 48 states. These projects convert a large source of greenhouse gases into a fuel that...

  5. LANDFILL GAS CONVERSION TO LNG AND LCO{sub 2}. PHASE 1, FINAL REPORT FOR THE PERIOD MARCH 1998-FEBRUARY 1999

    SciTech Connect (OSTI)

    COOK,W.J.; NEYMAN,M.; SIWAJEK,L.A.; BROWN,W.R.; VAN HAUWAERT,P.M.; CURREN,E.D.

    1998-02-25

    Process designs and economics were developed to produce LNG and liquid carbon dioxide (CO{sub 2}) from landfill gas (LFG) using the Acrion CO{sub 2} wash process. The patented Acrion CO{sub 2} wash process uses liquid CO{sub 2} to absorb contaminants from the LFG. The process steps are compression, drying, CO{sub 2} wash contaminant removal and CO{sub 2} recovery, residual CO{sub 2} removal and methane liquefaction. Three flowsheets were developed using different residual CO{sub 2} removal schemes. These included physical solvent absorption (methanol), membranes and molecular sieves. The capital and operating costs of the flowsheets were very similar. The LNG production cost was around ten cents per gallon. In parallel with process flowsheet development, the business aspects of an eventual commercial project have been explored. The process was found to have significant potential commercial application. The business plan effort investigated the economics of LNG transportation, fueling, vehicle conversion, and markets. The commercial value of liquid CO{sub 2} was also investigated. This Phase 1 work, March 1998 through February 1999, was funded under Brookhaven National laboratory contract 725089 under the research program entitled ``Liquefied Natural Gas as a Heavy Vehicle Fuel.'' The Phase 2 effort will develop flowsheets for the following: (1) CO{sub 2} and pipeline gas production, with the pipeline methane being liquefied at a peak shaving site, (2) sewage digester gas as an alternate feedstock to LFG and (3) the use of mixed refrigerants for process cooling. Phase 2 will also study the modification of Acrion's process demonstration unit for the production of LNG and a market site for LNG production.

  6. Measuring seasonal variations of moisture in a landfill with the partitioning gas tracer test

    SciTech Connect (OSTI)

    Han, Byunghyun; Jafarpour, Behnam; Gallagher, Victoria N.; Imhoff, Paul T. . E-mail: imhoff@udel.edu; Chiu, Pei C.; Fluman, Daniel A.

    2006-07-01

    Seven pilot-scale partitioning gas tracer tests (PGTTs) were conducted to assess the accuracy and reproducibility of this method for measuring water in municipal solid waste landfills. Tests were conducted in the same location over a 12-month period, and measured moisture conditions ranged from possible dry waste to refuse with a moisture content of 24.7%. The final moisture content of 24.7% was in reasonable agreement with gravimetric measurements of excavated refuse, where the moisture content was 26.5 {+-} 6.0CI%. Laboratory tests were used to assess the utility of the PGTT for measuring water in small pores, water sorbed to solid surfaces, and the influence of dry waste on PGTTs. These experiments indicated that when refuse surfaces are not completely solvated with water, PGTTs may produce misleading results (negative estimates) of water saturation and moisture content.

  7. Illinois Turning Landfill Trash into Future Cash

    Office of Energy Efficiency and Renewable Energy (EERE)

    Will County, Illinois officials yesterday formally broke ground on a new $7 million project (that includes $1 million of Energy Efficiency Conservation Block Grant funds) to turn methane gas from the Prairie View Landfill into electricity in a partnership with Waste Management. Will County will receive revenue from the sale of the gas created from decomposing garbage which will be harnessed and converted to generate 4.8 megawatts of green electrical power and used to power up to 8,000 homes. The future revenue generated from the sale of the gas and the sale of the electricity could reach $1 million annually.

  8. Efficient gas-separation process to upgrade dilute methane stream for use as fuel

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Merkel, Timothy C.; Lin, Haiqing; Thompson, Scott; Daniels, Ramin

    2012-03-06

    A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

  9. WC Landfill Energy | Open Energy Information

    Open Energy Info (EERE)

    WC Landfill Energy Place: New Jersey Product: Joint venture between DCO Energy and Marina Energy to develop landfill gas-to-energy plants in New Jersey. References: WC Landfill...

  10. Differences in volatile methyl siloxane (VMS) profiles in biogas from landfills and anaerobic digesters and energetics of VMS transformations

    SciTech Connect (OSTI)

    Tansel, Berrin Surita, Sharon C.

    2014-11-15

    Highlights: • In the digester gas, D4 and D5 comprised the 62% and 27% if siloxanes, respectively. • In landfill gas, the bulk of siloxanes were TMSOH (58%) followed by D4 (17%). • Methane utilization may be a possible mechanism for TMSOH formation in the landfills. • The geometric configurations of D4 and D5 molecules make them very stable. - Abstract: The objectives of this study were to compare the types and levels of volatile methyl siloxanes (VMS) present in biogas generated in the anaerobic digesters and landfills, evaluate the energetics of siloxane transformations under anaerobic conditions, compare the conditions in anaerobic digesters and municipal solid waste (MSW) landfills which result in differences in siloxane compositions. Biogas samples were collected at the South District Wastewater Treatment Plant and South Dade Landfill in Miami, Florida. In the digester gas, D4 and D5 comprised the bulk of total siloxanes (62% and 27%, respectively) whereas in the landfill gas, the bulk of siloxanes were trimethylsilanol (TMSOH) (58%) followed by D4 (17%). Presence of high levels of TMSOH in the landfill gas indicates that methane utilization may be a possible reaction mechanism for TMSOH formation. The free energy change for transformation of D5 and D4 to TMSOH either by hydrogen or methane utilization are thermodynamically favorable. Either hydrogen or methane should be present at relatively high concentrations for TMSOH formation which explains the high levels present in the landfill gas. The high bond energy and bond distance of the Si–O bond, in view of the atomic sizes of Si and O atoms, indicate that Si atoms can provide a barrier, making it difficult to break the Si–O bonds especially for molecules with specific geometric configurations such as D4 and D5 where oxygen atoms are positioned inside the frame formed by the large Si atoms which are surrounded by the methyl groups.

  11. FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE SUMMARY

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE SUMMARY Beaudoin, Y. C., Boswell, R., Dallimore, S. R., and Waite, W. (eds), 2014. Frozen Heat: A UNEP Global Outlook on Methane Gas Hydrates. United Nations Environment Programme, GRID-Arendal. © United Nations Environment Programme, 2014 This publication may be reproduced in whole or in part and in any form for educational or non-profit purposes without special permission from the copyright holder, provided acknowledgement of the

  12. Diffusion of methane and other alkanes in metal-organic frameworks for natural gas storage

    SciTech Connect (OSTI)

    Borah, B; Zhang, HD; Snurr, RQ

    2015-03-03

    Diffusion of methane, ethane, propane and n-butane was studied within the micropores of several metal organic frameworks (MOFs) of varying topologies, including the MOFs PCN-14, NU-125, NU-1100 and DUT-49. Diffusion coefficients of the pure components, as well as methane/ethane, methane/ propane and methane/butane binary mixtures, were calculated using molecular dynamics simulations to understand the effect of the longer alkanes on uptake of natural gas in MOB. The calculated self diffusion coefficients of all four components are on the order of 10(-8) m(2)/s. The diffusion coefficients of the pure components decrease as a function of chain length in all of the MOFs studied and show different behaviour as a function of loading in different MOB. The self-diffusivities follow the trend DPCN-14 < DNU-125 approximate to DNU-1100 < DDUT-49, which is exactly the reverse order of the densities of the MOFs: PCN-14 > NU-125 approximate to NU-1100 > DUT-49. By comparing the diffusion of pure methane and methane mixtures vvith the higher alkancs, it is observed that the diffusivity of methane is unaffected by the presence of the higher alkanes in the MOFs considered, indicating that the diffusion path of methane is not blocked by the higher alkanes present in natural gas. (C) 2014 Elsevier Ltd. All rights reserved.

  13. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes

    SciTech Connect (OSTI)

    Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

    2011-06-01

    Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

  14. Methane storage in advanced porous materials | Center for Gas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane storage in advanced porous materials Previous Next List Trevor A. Makal, Jian-Rong Li, Weigang Lu and Hong-Cai Zhou, Chem. Soc. Rev., 2012,41, 7761-7779 DOI: 10.1039...

  15. Controlling Methane Emissions in the Natural Gas Sector: A Review...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Rather, methane emission reductions from this sector have typically occurred as a co-benefit of policies that target air pollution (such as smog) and improve safety. In general, ...

  16. Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report

    SciTech Connect (OSTI)

    McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

    2007-09-01

    Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

  17. Reduction of Non-CO2 Gas Emissions Through The In Situ Bioconversion of Methane

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, B; Balin, D F

    2012-09-06

    The primary objectives of this research were to seek previously unidentified anaerobic methanotrophs and other microorganisms to be collected from methane seeps associated with coal outcrops. Subsurface application of these microbes into anaerobic environments has the potential to reduce methane seepage along coal outcrop belts and in coal mines, thereby preventing hazardous explosions. Depending upon the types and characteristics of the methanotrophs identified, it may be possible to apply the microbes to other sources of methane emissions, which include landfills, rice cultivation, and industrial sources where methane can accumulate under buildings. Finally, the microbes collected and identified during this research also had the potential for useful applications in the chemical industry, as well as in a variety of microbial processes. Sample collection focused on the South Fork of Texas Creek located approximately 15 miles east of Durango, Colorado. The creek is located near the subsurface contact between the coal-bearing Fruitland Formation and the underlying Pictured Cliffs Sandstone. The methane seeps occur within the creek and in areas adjacent to the creek where faulting may allow fluids and gases to migrate to the surface. These seeps appear to have been there prior to coalbed methane development as extensive microbial soils have developed. Our investigations screened more than 500 enrichments but were unable to convince us that anaerobic methane oxidation (AMO) was occurring and that anaerobic methanotrophs may not have been present in the samples collected. In all cases, visual and microscopic observations noted that the early stage enrichments contained viable microbial cells. However, as the levels of the readily substrates that were present in the environmental samples were progressively lowered through serial transfers, the numbers of cells in the enrichments sharply dropped and were eliminated. While the results were disappointing we acknowledge that

  18. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop November 12-13, 2014, Sheraton Pittsburgh Airport Hotel, Coraopolis, PA 15108 FINAL AGENDA Day 1 (Wednesday, November 12) 12:00-1:00 pm REGISTRATION 1:00-1:30 pm Welcome and Overviews Mark Johnson, Director, Advanced Manufacturing Office (AMO), DOE Office of Energy Efficiency and Renewable Energy Christopher J. Freitas, Senior Program Manager, Natural Gas Infrastructure, Office of Oil and Natural Gas, DOE Office of

  19. Natural Gas Infrastructure R&D and Methane Emissions Mitigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    November 12-13, 2014 DOE's Natural Gas Modernization Initiative Christopher Freitas, Program Manager, Natural Gas Midstream Infrastructure R&D, Office of Oil and Natural Gas, U.S. ...

  20. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Advanced Manufacturing Office (AMO) at the U.S. Department of Energy (DOE)’s Office of Energy Efficiency and Renewable Energy and the Office of Fossil Energy (FE) hosted a workshop, November 12-13, 2014, in Coraopolis, Pennsylvania, as a follow-up to the President’s Climate Action Plan and the DOE meeting series on reducing methane emissions from natural gas pipeline systems. The workshop is part of the larger Administration Strategy to Reduce Methane Emissions associated with natural gas transmission and distribution infrastructure.

  1. Functionally gradient material for membrane reactors to convert methane gas into value-added products

    DOE Patents [OSTI]

    Balachandran, U.; Dusek, J.T.; Kleefisch, M.S.; Kobylinski, T.P.

    1996-11-12

    A functionally gradient material for a membrane reactor for converting methane gas into value-added-products includes an outer tube of perovskite, which contacts air; an inner tube which contacts methane gas, of zirconium oxide, and a bonding layer between the perovskite and zirconium oxide layers. The bonding layer has one or more layers of a mixture of perovskite and zirconium oxide, with the layers transitioning from an excess of perovskite to an excess of zirconium oxide. The transition layers match thermal expansion coefficients and other physical properties between the two different materials. 7 figs.

  2. Functionally gradient material for membrane reactors to convert methane gas into value-added products

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Dusek, Joseph T.; Kleefisch, Mark S.; Kobylinski, Thadeus P.

    1996-01-01

    A functionally gradient material for a membrane reactor for converting methane gas into value-added-products includes an outer tube of perovskite, which contacts air; an inner tube which contacts methane gas, of zirconium oxide, and a bonding layer between the perovskite and zirconium oxide layers. The bonding layer has one or more layers of a mixture of perovskite and zirconium oxide, with the layers transitioning from an excess of perovskite to an excess of zirconium oxide. The transition layers match thermal expansion coefficients and other physical properties between the two different materials.

  3. FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Many countries have begun to explore alternative energy sources, including so- called ... What Role Do Gas Hydrates Play in Nature? Theme 2 Gas Hydrates as a Potential Energy ...

  4. Well-to-Wheels analysis of landfill gas-based pathways and their addition to the GREET model.

    SciTech Connect (OSTI)

    Mintz, M.; Han, J.; Wang, M.; Saricks, C.; Energy Systems

    2010-06-30

    Today, approximately 300 million standard cubic ft/day (mmscfd) of natural gas and 1600 MW of electricity are produced from the decomposition of organic waste at 519 U.S. landfills (EPA 2010a). Since landfill gas (LFG) is a renewable resource, this energy is considered renewable. When used as a vehicle fuel, compressed natural gas (CNG) produced from LFG consumes up to 185,000 Btu of fossil fuel and generates from 1.5 to 18.4 kg of carbon dioxide-equivalent (CO{sub 2}e) emissions per million Btu of fuel on a 'well-to-wheel' (WTW) basis. This compares with approximately 1.1 million Btu and 78.2 kg of CO{sub 2}e per million Btu for CNG from fossil natural gas and 1.2 million Btu and 97.5 kg of CO{sub 2}e per million Btu for petroleum gasoline. Because of the additional energy required for liquefaction, LFG-based liquefied natural gas (LNG) requires more fossil fuel (222,000-227,000 Btu/million Btu WTW) and generates more GHG emissions (approximately 22 kg CO{sub 2}e /MM Btu WTW) if grid electricity is used for the liquefaction process. However, if some of the LFG is used to generate electricity for gas cleanup and liquefaction (or compression, in the case of CNG), vehicle fuel produced from LFG can have no fossil fuel input and only minimal GHG emissions (1.5-7.7 kg CO{sub 2}e /MM Btu) on a WTW basis. Thus, LFG-based natural gas can be one of the lowest GHG-emitting fuels for light- or heavy-duty vehicles. This report discusses the size and scope of biomethane resources from landfills and the pathways by which those resources can be turned into and utilized as vehicle fuel. It includes characterizations of the LFG stream and the processes used to convert low-Btu LFG into high-Btu renewable natural gas (RNG); documents the conversion efficiencies and losses of those processes, the choice of processes modeled in GREET, and other assumptions used to construct GREET pathways; and presents GREET results by pathway stage. GREET estimates of well-to-pump (WTP), pump

  5. Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Natural Gas Landfills Convert Biogas Into Renewable Natural Gas to someone by E-mail Share Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable Natural Gas on Facebook Tweet about Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable Natural Gas on Twitter Bookmark Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable Natural Gas on Google Bookmark Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable Natural Gas on

  6. Analysis and Methane Gas Separations Studies for City of Marsing, Idaho An Idaho National Laboratory Technical Assistance Program Study

    SciTech Connect (OSTI)

    Christopher Orme

    2012-08-01

    Introduction and Background Large amounts of methane in well water is a wide spread problem in North America. Methane gas from decaying biomass and oil and gas deposits escape into water wells typically through cracks or faults in otherwise non-porous rock strata producing saturated water systems. This methane saturated water can pose several problems in the delivery of drinking water. The problems range from pumps vapor locking (cavitating), to pump houses exploding. The City of Marsing requested Idaho National Laboratory (INL) to assist with some water analyses as well as to provide some engineering approaches to methane capture through the INL Technical Assistance Program (TAP). There are several engineering approaches to the removal of methane and natural gas from water sources that include gas stripping followed by compression and/or dehydration; membrane gas separators coupled with dehydration processes, membrane water contactors with dehydration processes.

  7. AIRBORNE, OPTICAL REMOTE SENSNG OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2005-04-15

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The scope of the work involved designing and developing an airborne, optical remote sensor capable of sensing methane and, if possible, ethane for the detection of natural gas pipeline leaks. Flight testing using a custom dual wavelength, high power fiber amplifier was initiated in February 2005. Ophir successfully demonstrated the airborne system, showing that it was capable of discerning small amounts of methane from a simulated pipeline leak. Leak rates as low as 150 standard cubic feet per hour (scf/h) were detected by the airborne sensor.

  8. GAS METHANE HYDRATES-RESEARCH STATUS, ANNOTATED BIBLIOGRAPHY, AND ENERGY IMPLICATIONS

    SciTech Connect (OSTI)

    James Sorensen; Jaroslav Solc; Bethany Bolles

    2000-07-01

    The objective of this task as originally conceived was to compile an assessment of methane hydrate deposits in Alaska from available sources and to make a very preliminary evaluation of the technical and economic feasibility of producing methane from these deposits for remote power generation. Gas hydrates have recently become a target of increased scientific investigation both from the standpoint of their resource potential to the natural gas and oil industries and of their positive and negative implications for the global environment After we performed an extensive literature review and consulted with representatives of the U.S. Geological Survey (USGS), Canadian Geological Survey, and several oil companies, it became evident that, at the current stage of gas hydrate research, the available information on methane hydrates in Alaska does not provide sufficient grounds for reaching conclusions concerning their use for energy production. Hence, the original goals of this task could not be met, and the focus was changed to the compilation and review of published documents to serve as a baseline for possible future research at the Energy & Environmental Research Center (EERC). An extensive annotated bibliography of gas hydrate publications has been completed. The EERC will reassess its future research opportunities on methane hydrates to determine where significant initial contributions could be made within the scope of limited available resources.

  9. Natural Gas Methane Emissions in the United States Greenhouse Gas Inventory: Sources, Uncertainties and Opportunities for Improvement

    SciTech Connect (OSTI)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-11-19

    Presentation summarizing key findings of a Joint Institute for Strategic Energy Analysis Report at an Environmental Protection Agency workshop: 'Stakeholder Workshop on EPA GHG Data on Petroleum and Natural Gas Systems' on November 19, 2015. For additional information see the JISEA report, 'Estimating U.S. Methane Emissions from the Natural Gas Supply Chain: Approaches, Uncertainties, Current Estimates, and Future Studies' NREL/TP-6A50-62820.

  10. Incentives for Methane Mitigation and Energy-Efficiency Improvements in Case of Ukraine’s Natural Gas Transmission System

    SciTech Connect (OSTI)

    Roshchanka, Volha; Evans, Meredydd

    2014-06-01

    Reducing methane losses is a concern for climate change policy and energy policy. The energy sector is the major source of methane emissions into the atmosphere. Reducing methane emissions and avoiding combustion can be very cost-effective, but various barriers prevent such energy-efficiency measures from taking place. To date, few examples of industry-wide improvements exist. One example of substantial investments into upgrading natural gas transmission system comes from Ukraine. The Ukrainian transmission company, Ukrtransgaz, reduced its own system’s natural gas consumption by 68 percent in 2011 compared to the level in 2005. Evaluating reductions in methane emissions is challenging because of lack of accurate data and gaps in accounting methodologies. At the same time, Ukraine’s transmission system has undergone improvements that, at the very least, have contained methane emissions, if not substantially reduced them. In this paper, we describe recent developments in Ukraine’s natural gas transmission system and analyze the incentives that forced the sector to pay close attention to its methane losses. Ukraine is one of most energy-intensive countries, among the largest natural gas consumers in the world, and a significant emitter of methane. The country is also dependent on imports of natural gas. A combination of steep increases in the price of imported natural gas, and comprehensive domestic environmental and energy policies, regional integration policy, and international environmental agreements has created conditions for successful methane emission and combustion reductions. Learning about such case studies can help us design better policies elsewhere.

  11. UNDERSTANDING METHANE EMISSIONS SOURCES AND VIABLE MITIGATION MEASURES IN THE NATURAL GAS TRANSMISSION SYSTEMS: RUSSIAN AND U.S. EXPERIENCE

    SciTech Connect (OSTI)

    Ishkov, A.; Akopova, Gretta; Evans, Meredydd; Yulkin, Grigory; Roshchanka, Volha; Waltzer, Suzie; Romanov, K.; Picard, David; Stepanenko, O.; Neretin, D.

    2011-10-01

    This article will compare the natural gas transmission systems in the U.S. and Russia and review experience with methane mitigation technologies in the two countries. Russia and the United States (U.S.) are the world's largest consumers and producers of natural gas, and consequently, have some of the largest natural gas infrastructure. This paper compares the natural gas transmission systems in Russia and the U.S., their methane emissions and experiences in implementing methane mitigation technologies. Given the scale of the two systems, many international oil and natural gas companies have expressed interest in better understanding the methane emission volumes and trends as well as the methane mitigation options. This paper compares the two transmission systems and documents experiences in Russia and the U.S. in implementing technologies and programs for methane mitigation. The systems are inherently different. For instance, while the U.S. natural gas transmission system is represented by many companies, which operate pipelines with various characteristics, in Russia predominately one company, Gazprom, operates the gas transmission system. However, companies in both countries found that reducing methane emissions can be feasible and profitable. Examples of technologies in use include replacing wet seals with dry seals, implementing Directed Inspection and Maintenance (DI&M) programs, performing pipeline pump-down, applying composite wrap for non-leaking pipeline defects and installing low-bleed pneumatics. The research methodology for this paper involved a review of information on methane emissions trends and mitigation measures, analytical and statistical data collection; accumulation and analysis of operational data on compressor seals and other emission sources; and analysis of technologies used in both countries to mitigate methane emissions in the transmission sector. Operators of natural gas transmission systems have many options to reduce natural gas losses

  12. Natural Gas Infrastructure R&D and Methane Emissions Mitigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and transportation efficiency. Due to economic efficiency Interstate Natural Gas Pipelines typically do not operate at their optimum design condition. So, most ...

  13. Improved Recovery from Gulf of Mexico Reservoirs, Volume 4, Comparison of Methane, Nitrogen and Flue Gas for Attic Oil. February 14, 1995 - October 13, 1996. Final Report

    SciTech Connect (OSTI)

    Wolcott, Joanne; Shayegi, Sara

    1997-01-13

    Gas injection for attic oil recovery was modeled in vertical sandpacks to compare the process performance characteristics of three gases, namely methane, nitrogen and flue gas. All of the gases tested recovered the same amount of oil over two cycles of gas injection. Nitrogen and flue gas recovered oil more rapidly than methane because a large portion of the methane slug dissolved in the oil phase and less free gas was available for oil displacement. The total gas utilization for two cycles of gas injection was somewhat better for nitrogen as compared to methane and flue gas. The lower nitrogen utilization was ascribed to the lower compressibility of nitrogen.

  14. Decomposition of forest products buried in landfills

    SciTech Connect (OSTI)

    Wang, Xiaoming; Padgett, Jennifer M.; Powell, John S.; Barlaz, Morton A.

    2013-11-15

    Highlights: • This study tracked chemical changes of wood and paper in landfills. • A decomposition index was developed to quantify carbohydrate biodegradation. • Newsprint biodegradation as measured here is greater than previous reports. • The field results correlate well with previous laboratory measurements. - Abstract: The objective of this study was to investigate the decomposition of selected wood and paper products in landfills. The decomposition of these products under anaerobic landfill conditions results in the generation of biogenic carbon dioxide and methane, while the un-decomposed portion represents a biogenic carbon sink. Information on the decomposition of these municipal waste components is used to estimate national methane emissions inventories, for attribution of carbon storage credits, and to assess the life-cycle greenhouse gas impacts of wood and paper products. Hardwood (HW), softwood (SW), plywood (PW), oriented strand board (OSB), particleboard (PB), medium-density fiberboard (MDF), newsprint (NP), corrugated container (CC) and copy paper (CP) were buried in landfills operated with leachate recirculation, and were excavated after approximately 1.5 and 2.5 yr. Samples were analyzed for cellulose (C), hemicellulose (H), lignin (L), volatile solids (VS), and organic carbon (OC). A holocellulose decomposition index (HOD) and carbon storage factor (CSF) were calculated to evaluate the extent of solids decomposition and carbon storage. Samples of OSB made from HW exhibited cellulose plus hemicellulose (C + H) loss of up to 38%, while loss for the other wood types was 0–10% in most samples. The C + H loss was up to 81%, 95% and 96% for NP, CP and CC, respectively. The CSFs for wood and paper samples ranged from 0.34 to 0.47 and 0.02 to 0.27 g OC g{sup −1} dry material, respectively. These results, in general, correlated well with an earlier laboratory-scale study, though NP and CC decomposition measured in this study were higher than

  15. New Natural Gas Storage and Transportation Capabilities Utilizing Rapid Methane Hydrate Formation Techniques

    SciTech Connect (OSTI)

    Brown, T.D.; Taylor, C.E.; Bernardo, M.

    2010-01-01

    Natural gas (methane as the major component) is a vital fossil fuel for the United States and around the world. One of the problems with some of this natural gas is that it is in remote areas where there is little or no local use for the gas. Nearly 50 percent worldwide natural gas reserves of ~6,254.4 trillion ft3 (tcf) is considered as stranded gas, with 36 percent or ~86 tcf of the U.S natural gas reserves totaling ~239 tcf, as stranded gas [1] [2]. The worldwide total does not include the new estimates by U.S. Geological Survey of 1,669 tcf of natural gas north of the Arctic Circle, [3] and the U.S. ~200,000 tcf of natural gas or methane hydrates, most of which are stranded gas reserves. Domestically and globally there is a need for newer and more economic storage, transportation and processing capabilities to deliver the natural gas to markets. In order to bring this resource to market, one of several expensive methods must be used: 1. Construction and operation of a natural gas pipeline 2. Construction of a storage and compression facility to compress the natural gas (CNG) at 3,000 to 3,600 psi, increasing its energy density to a point where it is more economical to ship, or 3. Construction of a cryogenic liquefaction facility to produce LNG, (requiring cryogenic temperatures at <-161 °C) and construction of a cryogenic receiving port. Each of these options for the transport requires large capital investment along with elaborate safety systems. The Department of Energy's Office of Research and Development Laboratories at the National Energy Technology Laboratory (NETL) is investigating new and novel approaches for rapid and continuous formation and production of synthetic NGHs. These synthetic hydrates can store up to 164 times their volume in gas while being maintained at 1 atmosphere and between -10 to -20°C for several weeks. Owing to these properties, new process for the economic storage and transportation of these synthetic hydrates could be envisioned

  16. Plasma-produced phase-pure cuprous oxide nanowires for methane gas sensing

    SciTech Connect (OSTI)

    Cheng, Qijin Zhang, Fengyan; Yan, Wei; Randeniya, Lakshman; Ostrikov, Kostya

    2014-03-28

    Phase-selective synthesis of copper oxide nanowires is warranted by several applications, yet it remains challenging because of the narrow windows of the suitable temperature and precursor gas composition in thermal processes. Here, we report on the room-temperature synthesis of small-diameter, large-area, uniform, and phase-pure Cu{sub 2}O nanowires by exposing copper films to a custom-designed low-pressure, thermally non-equilibrium, high-density (typically, the electron number density is in the range of 10{sup 11}10{sup 13}?cm{sup ?3}) inductively coupled plasmas. The mechanism of the plasma-enabled phase selectivity is proposed. The gas sensors based on the synthesized Cu{sub 2}O nanowires feature fast response and recovery for the low-temperature (?140?C) detection of methane gas in comparison with polycrystalline Cu{sub 2}O thin film-based gas sensors. Specifically, at a methane concentration of 4%, the response and the recovery times of the Cu{sub 2}O nanowire-based gas sensors are 125 and 147?s, respectively. The Cu{sub 2}O nanowire-based gas sensors have a potential for applications in the environmental monitoring, chemical industry, mining industry, and several other emerging areas.

  17. Methane Hydrate | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane Hydrate Methane Hydrate Types of Methane Hydrate Deposits Types of Methane Hydrate Deposits Methane hydrate is a cage-like lattice of ice inside of which are trapped molecules of methane, the chief constituent of natural gas. If methane hydrate is either warmed or depressurized, it will revert back to water and natural gas. When brought to the earth's surface, one cubic meter of gas hydrate releases 164 cubic meters of natural gas. Hydrate deposits may be several hundred meters thick and

  18. Other States Natural Gas Coalbed Methane, Reserves Based Production

    Gasoline and Diesel Fuel Update (EIA)

    August 2009 Revised: October 2009 Next MECS will be conducted in 2010 Table 3.5 Selected Byproducts in Fuel Consumption, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Waste Blast Pulping Liquor Oils/Tars NAICS Furnace/Coke Petroleum or Wood Chips, and Waste Code(a) Subsector and Industry Total Oven Gases Waste Gas Coke Black Liquor Bark Materials Total United States 311 Food 10 0 3 0 0 7 Q 3112 Grain and Oilseed Milling 7 0 1 0 0 6 *

  19. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C.

    1980-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  20. Assessing methane oxidation under landfill covers and its contribution to the above atmospheric CO{sub 2} levels: The added value of the isotope ({delta}{sup 13}C and {delta}{sup 18}O CO{sub 2}; {delta}{sup 13}C and {delta}D CH{sub 4}) approach

    SciTech Connect (OSTI)

    Widory, D.; Proust, E.; Bellenfant, G.; Bour, O.

    2012-09-15

    Highlights: Black-Right-Pointing-Pointer Comparison of the isotope and mass balance approaches to evaluate the level of methane oxidation within a landfill. Black-Right-Pointing-Pointer The level of methane oxidation is not homogenous under the landfill cover and is strongly correlated to the methane flux. Black-Right-Pointing-Pointer Isotope tracking of the contribution of the methane oxidation to the CO{sub 2} concentrations in the ambient air. - Abstract: We are presenting here a multi-isotope approach ({delta}{sup 13}C and {delta}{sup 18}O of CO{sub 2}; {delta}{sup 13}C and {delta}D of CH{sub 4}) to assess (i) the level(s) of methane oxidation during waste biodegradation and its migration through a landfill cover in Sonzay (France), and (ii) its contribution to the atmospheric CO{sub 2} levels above the surface. The isotope approach is compared to the more conventional mass balance approach. Results from the two techniques are comparable and show that the CH{sub 4} oxidation under the landfill cover is heterogenous, with low oxidation percentages in samples showing high biogas fluxes, which was expected in clay covers presenting fissures, through which CH{sub 4} is rapidly transported. At shallow depth, more immobile biogas pockets show a higher level of CH{sub 4} oxidation by the methanotrophic bacteria. {delta}{sup 13}C of CO{sub 2} samples taken at different heights (from below the cover up to 8 m above the ground level) were also used to identify and assess the relative contributions of its main sources both under the landfill cover and in the surrounding atmosphere.

  1. DOE THREE-DIMENSIONAL STRUCTURE AND PHYSICAL PROPERTIES OF A METHANE HYDRATE DEPOSIT AND GAS RESERVOIR, BLAKE RIDGE

    SciTech Connect (OSTI)

    W. Steven Holbrook

    2004-11-11

    This report contains a summary of work conducted and results produced under the auspices of award DE-FC26-00NT40921, ''DOE Three-Dimensional Structure and Physical Properties of a Methane Hydrate Deposit and Gas Reservoir, Blake Ridge.'' This award supported acquisition, processing, and interpretation of two- and three-dimensional seismic reflection data over a large methane hydrate reservoir on the Blake Ridge, offshore South Carolina. The work supported by this project has led to important new conclusions regarding (1) the use of seismic reflection data to directly detect methane hydrate, (2) the migration and possible escape of free gas through the hydrate stability zone, and (3) the mechanical controls on the maximum thickness of the free gas zone and gas escape.

  2. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-05-13

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This six-month technical report summarizes the progress for each of the proposed tasks, discusses project concerns, and outlines near-term goals. Ophir has completed a data survey of two major natural gas pipeline companies on the design requirements for an airborne, optical remote sensor. The results of this survey are disclosed in this report. A substantial amount of time was spent on modeling the expected optical signal at the receiver at different absorption wavelengths, and determining the impact of noise sources such as solar background, signal shot noise, and electronic noise on methane and ethane gas detection. Based upon the signal to noise modeling and industry input, Ophir finalized the design requirements for the airborne sensor, and released the critical sensor light source design requirements to qualified vendors. Responses from the vendors indicated that the light source was not commercially available, and will require a research and development effort to produce. Three vendors have responded positively with proposed design solutions. Ophir has decided to conduct short path optical laboratory experiments to verify the existence of methane and absorption at the specified wavelength, prior to proceeding with the light source selection. Techniques to eliminate common mode noise were also evaluated during the laboratory tests. Finally, Ophir has included a summary of the potential concerns for project success and has established future goals.

  3. Methanation assembly using multiple reactors

    DOE Patents [OSTI]

    Jahnke, Fred C.; Parab, Sanjay C.

    2007-07-24

    A methanation assembly for use with a water supply and a gas supply containing gas to be methanated in which a reactor assembly has a plurality of methanation reactors each for methanating gas input to the assembly and a gas delivery and cooling assembly adapted to deliver gas from the gas supply to each of said methanation reactors and to combine water from the water supply with the output of each methanation reactor being conveyed to a next methanation reactor and carry the mixture to such next methanation reactor.

  4. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPLINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2004-05-12

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The third six-month technical report contains a summary of the progress made towards finalizing the design and assembling the airborne, remote methane and ethane sensor. The vendor has been chosen and is on contract to develop the light source with the appropriate linewidth and spectral shape to best utilize the Ophir gas correlation software. Ophir has expanded upon the target reflectance testing begun in the previous performance period by replacing the experimental receiving optics with the proposed airborne large aperture telescope, which is theoretically capable of capturing many times more signal return. The data gathered from these tests has shown the importance of optimizing the fiber optic receiving fiber to the receiving optic and has helped Ophir to optimize the design of the gas cells and narrowband optical filters. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  5. One Man's Trash, Another Man's Fuel: BMW Plant Converts Landfill...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    One Man's Trash, Another Man's Fuel: BMW Plant Converts Landfill Gas to Hydrogen Fuel One Man's Trash, Another Man's Fuel: BMW Plant Converts Landfill Gas to Hydrogen Fuel August ...

  6. Influence of mechanical-biological waste pre-treatment methods on the gas formation in landfills

    SciTech Connect (OSTI)

    Bockreis, A. . E-mail: a.bockreis@iwar.tu-darmstadt.de; Steinberg, I.

    2005-07-01

    In order to minimise emissions and environmental impacts, only pre-treated waste should be disposed of. For the last six years, a series of continuous experiments has been conducted at the Institute WAR, TU Darmstadt, in order to determine the emissions from pre-treated waste. Different kinds of pre-treated waste were incubated in several reactors and various data, including production and composition of the gas and the leachate, were collected. In this paper, the interim results of gas production and the gas composition from different types of waste after a running time of six years are presented and discussed.

  7. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-11-12

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This second six-month technical report summarizes the progress made towards defining, designing, and developing the hardware and software segments of the airborne, optical remote methane and ethane sensor. The most challenging task to date has been to identify a vendor capable of designing and developing a light source with the appropriate output wavelength and power. This report will document the work that has been done to identify design requirements, and potential vendors for the light source. Significant progress has also been made in characterizing the amount of light return available from a remote target at various distances from the light source. A great deal of time has been spent conducting laboratory and long-optical path target reflectance measurements. This is important since it helps to establish the overall optical output requirements for the sensor. It also reduces the relative uncertainty and risk associated with developing a custom light source. The data gathered from the optical path testing has been translated to the airborne transceiver design in such areas as: fiber coupling, optical detector selection, gas filters, and software analysis. Ophir will next, summarize the design progress of the transceiver hardware and software development. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  8. Estimating U.S. Methane Emissions from the Natural Gas Supply Chain. Approaches, Uncertainties, Current Estimates, and Future Studies

    SciTech Connect (OSTI)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-08-01

    A growing number of studies have raised questions regarding uncertainties in our understanding of methane (CH4) emissions from fugitives and venting along the natural gas (NG) supply chain. In particular, a number of measurement studies have suggested that actual levels of CH4 emissions may be higher than estimated by EPA" tm s U.S. GHG Emission Inventory. We reviewed the literature to identify the growing number of studies that have raised questions regarding uncertainties in our understanding of methane (CH4) emissions from fugitives and venting along the natural gas (NG) supply chain.

  9. Methane Hydrates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Hydrates 2016 Methane Hydrates Funding Opportunity Announcement The objective of this Funding Opportunity Announcement is to select projects in FY16 that will further ongoing programmatic efforts to characterize naturally occurring gas hydrate deposits as well as their role in the natural environment and that will: Support fundamental laboratory and numerical simulation studies of gas hydrate reservoir response to potential production activities Support fundamental field, laboratory and

  10. Coalbed Methane (CBM) is natural

    Broader source: Energy.gov (indexed) [DOE]

    and continued ural gas liquids and crude oil, which have a higher value in energy ... Submersible pump Coal Methane released from coal Methane to pipeline Water (discharged) ...

  11. Methane Hydrates R&D Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Hydrate Methane Hydrate Types of Methane Hydrate Deposits Types of Methane Hydrate Deposits Methane hydrate is a cage-like lattice of ice inside of which are trapped molecules of methane, the chief constituent of natural gas. If methane hydrate is either warmed or depressurized, it will revert back to water and natural gas. When brought to the earth's surface, one cubic meter of gas hydrate releases 164 cubic meters of natural gas. Hydrate deposits may be several hundred meters thick and

  12. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  13. Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas. A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture

    SciTech Connect (OSTI)

    Lebarbier, Vanessa M.C.; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2013-07-08

    Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325°C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600°C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700ºC) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600°C. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent

  14. Heat pipe methanator

    DOE Patents [OSTI]

    Ranken, William A.; Kemme, Joseph E.

    1976-07-27

    A heat pipe methanator for converting coal gas to methane. Gravity return heat pipes are employed to remove the heat of reaction from the methanation promoting catalyst, transmitting a portion of this heat to an incoming gas pre-heat section and delivering the remainder to a steam generating heat exchanger.

  15. U.S. Natural Gas System Methane Emissions: State of Knowledge from LCAs, Inventories, and Atmospheric Measurements (Presentation)

    SciTech Connect (OSTI)

    Heath, G.

    2014-04-01

    Natural gas (NG) is a potential "bridge fuel" during transition to a decarbonized energy system: It emits less carbon dioxide during combustion than other fossil fuels and can be used in many industries. However, because of the high global warming potential of methane (CH4, the major component of NG), climate benefits from NG use depend on system leakage rates. Some recent estimates of leakage have challenged the benefits of switching from coal to NG, a large near-term greenhouse gas (GHG) reduction opportunity. During this presentation, Garvin will review evidence from multiple perspectives - life cycle assessments (LCAs), inventories and measurements - about NG leakage in the US. Particular attention will be paid to a recent article in Science magazine which reviewed over 20 years of published measurements to better understand what we know about total methane emissions and those from the oil and gas sectors. Scientific and policy implications of the state of knowledge will be discussed.

  16. Greenhouse Gas Management Institute (GHGMI) | Open Energy Information

    Open Energy Info (EERE)

    Inventories * 302 GHG Accounting for Forest Projects * 311 GHG Accounting for Landfill Methane Projects (forthcoming) * 312 GHG Accounting for Coalmine Methane Projects * 321 GHG...

  17. Microstructure-Dependent Gas Adsorption: Accurate Predictions of Methane Uptake in Nanoporous Carbons

    SciTech Connect (OSTI)

    Ihm, Yungok; Cooper, Valentino R; Gallego, Nidia C; Contescu, Cristian I; Morris, James R

    2014-01-01

    We demonstrate a successful, efficient framework for predicting gas adsorption properties in real materials based on first-principles calculations, with a specific comparison of experiment and theory for methane adsorption in activated carbons. These carbon materials have different pore size distributions, leading to a variety of uptake characteristics. Utilizing these distributions, we accurately predict experimental uptakes and heats of adsorption without empirical potentials or lengthy simulations. We demonstrate that materials with smaller pores have higher heats of adsorption, leading to a higher gas density in these pores. This pore-size dependence must be accounted for, in order to predict and understand the adsorption behavior. The theoretical approach combines: (1) ab initio calculations with a van der Waals density functional to determine adsorbent-adsorbate interactions, and (2) a thermodynamic method that predicts equilibrium adsorption densities by directly incorporating the calculated potential energy surface in a slit pore model. The predicted uptake at P=20 bar and T=298 K is in excellent agreement for all five activated carbon materials used. This approach uses only the pore-size distribution as an input, with no fitting parameters or empirical adsorbent-adsorbate interactions, and thus can be easily applied to other adsorbent-adsorbate combinations.

  18. A Perspective of petroleum, natural gas, and coal bed methane on the energy security of India

    SciTech Connect (OSTI)

    Ghose, M.K.; Paul, B.

    2008-07-01

    The global energy requirement has grown at a phenomenal rate and the consumption of primary energy sources has been a very high positive growth. This article focuses on the consumption of different primary energy sources and it identifies that coal will continue to remain as the prime energy in the foreseeable future. It examines energy requirement perspectives for India and demands of petroleum, natural gas, and coal bed methane in the foreseeable future. It discusses the state of present day petroleum and petrochemical industries in the country and the latest advances in them to take over in the next few years. The regional pattern of consumption of primary energy sources shows that oil remains as the largest single source of primary energy in most parts of the world. However, gas dominates as the prime source in some parts of the world. Economic development and poverty alleviation depend on securing affordable energy sources and for the country's energy security; it is necessary to adopt the latest technological advances in petroleum and petrochemical industries by supportive government policies. But such energy is very much concerned with environmental degradation and must be driven by contemporary managerial acumen addressing environmental and social challenges effectively. Environmental laws for the abatement of environmental degradation are discussed in this paper. The paper concludes that energy security leading to energy independence is certainly possible and can be achieved through a planned manner.

  19. Process for the utilization of household rubbish or garbage and other organic waste products for the production of methane gas

    SciTech Connect (OSTI)

    Hunziker, M.; Schildknecht, A.

    1985-04-16

    Non-organic substances are separated from household garbage and the organic substances are fed in proportioned manner into a mixing tank and converted into slurry by adding liquid. The slurry is crushed for homogenization purposes in a crushing means and passed into a closed holding container. It is then fed over a heat exchanger and heated to 55/sup 0/ to 60/sup 0/ C. The slurry passes into a plurality of reaction vessels in which the methane gas and carbon dioxide are produced. In a separating plant, the mixture of gaseous products is broken down into its components and some of the methane gas is recycled by bubbling it through both the holding tank and the reaction tank, the remainder being stored in gasholders. The organic substances are degraded much more rapidly through increasing the degradation temperature and as a result constructional expenditure can be reduced.

  20. Stable isotope signatures for characterising the biological stability of landfilled municipal solid waste

    SciTech Connect (OSTI)

    Wimmer, Bernhard; Hrad, Marlies; Huber-Humer, Marion; Watzinger, Andrea; Wyhlidal, Stefan; Reichenauer, Thomas G.

    2013-10-15

    Highlights: ► The isotopic signature of δ{sup 13}C-DIC of leachates is linked to the reactivity of MSW. ► Isotopic signatures of leachates depend on aerobic/anaerobic conditions in landfills. ► In situ aeration of landfills can be monitored by isotope analysis in leachate. ► The isotopic analysis of leachates can be used for assessing the stability of MSW. ► δ{sup 13}C-DIC of leachates helps to define the duration of landfill aftercare. - Abstract: Stable isotopic signatures of landfill leachates are influenced by processes within municipal solid waste (MSW) landfills mainly depending on the aerobic/anaerobic phase of the landfill. We investigated the isotopic signatures of δ{sup 13}C, δ{sup 2}H and δ{sup 18}O of different leachates from lab-scale experiments, lysimeter experiments and a landfill under in situ aeration. In the laboratory, columns filled with MSW of different age and reactivity were percolated under aerobic and anaerobic conditions. In landfill simulation reactors, waste of a 25 year old landfill was kept under aerobic and anaerobic conditions. The lysimeter facility was filled with mechanically shredded fresh waste. After starting of the methane production the waste in the lysimeter containments was aerated in situ. Leachate and gas composition were monitored continuously. In addition the seepage water of an old landfill was collected and analysed periodically before and during an in situ aeration. We found significant differences in the δ{sup 13}C-value of the dissolved inorganic carbon (δ{sup 13}C-DIC) of the leachate between aerobic and anaerobic waste material. During aerobic degradation, the signature of δ{sup 13}C-DIC was mainly dependent on the isotopic composition of the organic matter in the waste, resulting in a δ{sup 13}C-DIC of −20‰ to −25‰. The production of methane under anaerobic conditions caused an increase in δ{sup 13}C-DIC up to values of +10‰ and higher depending on the actual reactivity of the MSW

  1. Commercialization of waste gob gas and methane produced in conjunction with coal mining operations. Final report, August 1992--December 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The primary objectives of the project were to identify and evaluate existing processes for (1) using gas as a feedstock for production of marketable, value-added commodities, and (2) enriching contaminated gas to pipeline quality. The following gas conversion technologies were evaluated: (1) transformation to liquid fuels, (2) manufacture of methanol, (3) synthesis of mixed alcohols, and (4) conversion to ammonia and urea. All of these involved synthesis gas production prior to conversion to the desired end products. Most of the conversion technologies evaluated were found to be mature processes operating at a large scale. A drawback in all of the processes was the need to have a relatively pure feedstock, thereby requiring gas clean-up prior to conversion. Despite this requirement, the conversion technologies were preliminarily found to be marginally economic. However, the prohibitively high investment for a combined gas clean-up/conversion facility required that REI refocus the project to investigation of gas enrichment alternatives. Enrichment of a gas stream with only one contaminant is a relatively straightforward process (depending on the contaminant) using available technology. However, gob gas has a unique nature, being typically composed of from constituents. These components are: methane, nitrogen, oxygen, carbon dioxide and water vapor. Each of the four contaminants may be separated from the methane using existing technologies that have varying degrees of complexity and compatibility. However, the operating and cost effectiveness of the combined system is dependent on careful integration of the clean-up processes. REI is pursuing Phase 2 of this project for demonstration of a waste gas enrichment facility using the approach described above. This is expected to result in the validation of the commercial and technical viability of the facility, and the refinement of design parameters.

  2. Table 11.3 Methane Emissions, 1980-2009 (Million Metric Tons of Methane)

    U.S. Energy Information Administration (EIA) Indexed Site

    Methane Emissions, 1980-2009 (Million Metric Tons of Methane) Year Energy Sources Waste Management Agricultural Sources Industrial Processes 9 Total 5 Coal Mining Natural Gas Systems 1 Petroleum Systems 2 Mobile Com- bustion 3 Stationary Com- bustion 4 Total 5 Landfills Waste- water Treatment 6 Total 5 Enteric Fermen- tation 7 Animal Waste 8 Rice Cultivation Crop Residue Burning Total 5 1980 3.06 4.42 NA 0.28 0.45 8.20 10.52 0.52 11.04 5.47 2.87 0.48 0.04 8.86 0.17 28.27 1981 2.81 5.02 NA .27

  3. Drilling and Production Testing the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields

    SciTech Connect (OSTI)

    Steve McRae; Thomas Walsh; Michael Dunn; Michael Cook

    2010-02-22

    In November of 2008, the Department of Energy (DOE) and the North Slope Borough (NSB) committed funding to develop a drilling plan to test the presence of hydrates in the producing formation of at least one of the Barrow Gas Fields, and to develop a production surveillance plan to monitor the behavior of hydrates as dissociation occurs. This drilling and surveillance plan was supported by earlier studies in Phase 1 of the project, including hydrate stability zone modeling, material balance modeling, and full-field history-matched reservoir simulation, all of which support the presence of methane hydrate in association with the Barrow Gas Fields. This Phase 2 of the project, conducted over the past twelve months focused on selecting an optimal location for a hydrate test well; design of a logistics, drilling, completion and testing plan; and estimating costs for the activities. As originally proposed, the project was anticipated to benefit from industry activity in northwest Alaska, with opportunities to share equipment, personnel, services and mobilization and demobilization costs with one of the then-active exploration operators. The activity level dropped off, and this benefit evaporated, although plans for drilling of development wells in the BGF's matured, offering significant synergies and cost savings over a remote stand-alone drilling project. An optimal well location was chosen at the East Barrow No.18 well pad, and a vertical pilot/monitoring well and horizontal production test/surveillance well were engineered for drilling from this location. Both wells were designed with Distributed Temperature Survey (DTS) apparatus for monitoring of the hydrate-free gas interface. Once project scope was developed, a procurement process was implemented to engage the necessary service and equipment providers, and finalize project cost estimates. Based on cost proposals from vendors, total project estimated cost is $17.88 million dollars, inclusive of design work

  4. Direct use of natural gas (methane) for conversion of carbonaceous raw materials to fuels and chemical feedstocks

    SciTech Connect (OSTI)

    Steinberg, M.

    1985-04-01

    It appears that natural gas is almost as abundant as petroleum, if not more so, as a natural resource in many parts of the world. Because of its rich hydrogen content, it is probably the lowest cost source of hydrogen wherever it is available. The most abundant fossil energy resource in the world appears to be coal, and the most abundant renewable resource appears to be biomass (trees and plants), both of which contain a deficiency of hydrogen. It is proposed to use natural gas in conjunction with coal and biomass to produce the preferred liquid fuel simulating petroleum products. Processes are described which include methanolysis that is the direct use of methane for gasification and liquefaction of coal and biomass, and for desulfurization of coal derived liquid and gases. The thermal decomposition of methane is described for hydrogen and carbon particulate production. A cyclical process is described for producing a clean particulate carbon from coal for use in a carbon-water-fuel-mix as a substitute diesel fuel or premium-grade boiler fuel. The hydrogen from methane can be used for flash hydropyrolysis or can be used to produce ammonia fertilizer. 7 refs., 3 figs., 5 tabs.

  5. Enhanced Renewable Methane Production System Benefits Wastewater Treatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plants, Farms, and Landfills - Energy Innovation Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Enhanced Renewable Methane Production System Benefits Wastewater Treatment Plants, Farms, and Landfills Argonne National Laboratory Contact ANL About This Technology <p> Argonne&rsquo;s Enhanced Renewable Methane Production System &mdash; Process Schematic.</p> Argonne's Enhanced Renewable Methane Production System - Process Schematic.

  6. UNFCCC-Consolidated baseline and monitoring methodology for landfill...

    Open Energy Info (EERE)

    Consolidated baseline and monitoring methodology for landfill gas project activities Jump to: navigation, search Tool Summary LAUNCH TOOL Name: UNFCCC-Consolidated baseline and...

  7. Geophysical exploration and hydrologic impact of the closed Gracelawn landfill in Auburn, ME

    SciTech Connect (OSTI)

    Wisniewski, D. . Geology Dept.)

    1993-03-01

    Several geophysical methods were used over portions of the Gracelawn landfill, in Auburn, Maine to determine the surface boundaries and subsurface structure of this closed landfill, and to determine the landfill's effects on groundwater quality. The landfill was originally a sand and gravel pit excavated in the 1950's and early 1960's, and was used as a landfill from 1964--1977. The site is unlined, has a clay cap, and has been graded and developed as a baseball park. Two seismic refraction lines were performed to obtain a minimum depth to bedrock of 80 m. Seismic velocities of methane gas-saturated trash ranged from 250 to 340 m/s, and sand velocities are approximately 800 m/s. Two electrical resistivity Wenner surveys over the trash yielded the depth to saturated material and thickness of the trash layers. Resistivity values for dry refuse ranged from 1,000-2,000 [Omega]*m. A third electrical resistivity survey yielded the thickness of unsaturated and saturated sands bordering the landfill. Dry sands were found to have a resistivity of 1,000 [Omega]*m, and saturated sands a resistivity of 500 [Omega]*m. Gravity and magnetic survey grids across the site revealed anomalies which were mapped to illustrate the irregular morphology of the buried trash as well as its surface boundaries. Residual magnetic anomalies are on the order of 2,000 nT. Residual gravity anomalies are up to 5 mGal. Groundwater elevations determined by the geophysical survey, combined with a survey of existing water monitoring well logs, indicate that the groundwater flow in the sand and gravel aquifer is to the southeast, away from the public water supply, Lake Auburn, which lies to the north of the site. However, correlations between the bedrock fracture analysis and the geophysical survey illustrate that there is potential for contamination of Lake Auburn via the bedrock aquifer.

  8. Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead

    SciTech Connect (OSTI)

    BC Technologies

    2009-12-30

    Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL

  9. Direct production of hydrogen and aromatics from methane or natural gas: Review of recent U.S. patents

    SciTech Connect (OSTI)

    Lucia M. Petkovic; Daniel M. Ginosar

    2012-03-01

    Since the year 2000, the United States Patent and Trademark Office (USPTO) has granted a dozen patents for inventions related to methane dehydroaromatization processes. One of them was granted to UOP LLC (Des Plaines). It relates to a catalyst composition and preparation method. Two patents were granted to Conoco Phillips Company (Houston, TX). One was aimed at securing a process and operating conditions for methane aromatization. The other was aimed at securing a process that may be integrated with separation of wellhead fluids and blending of the aromatics produced from the gas with the crude. Nine patents were granted to ExxonMobil Chemical Patents Inc. (Houston, TX). Most of these were aimed at securing a dehydroaromatization process where methane-containing feedstock moves counter currently to a particulate catalyst. The coked catalyst is heated or regenerated either in the reactor, by cyclic operation, or in annex equipment, and returned to the reactor. The reactor effluent stream may be separated in its main components and used or recycled as needed. A brief summary of those inventions is presented in this review.

  10. Integrated exploration strategy for locating areas capable of high gas rate cavity completion in coalbed methane reservoirs

    SciTech Connect (OSTI)

    Klawitter, A.L.; Hoak, T.E.; Decker, A.D.

    1995-10-01

    In 1993, the San Juan Basin accounted for approximately 605 Bcf of the 740 Bcf of all coalbed gas produced in the United States. The San Juan {open_quotes}cavitation fairway{close_quotes} in which production occurs in open-hole cavity completions, is responsible for over 60% of all U.S. coalbed methane production. Perhaps most striking is the fact that over 17,000 wells had penetrated the Fruitland formation in the San Juan Basin prior to recognition of the coalbed methan potential. To understand the dynamic cavity fairway reservoir in the San Juan Basin, an exploration rationale for coalbed methan was developed that permits a sequential reduction in total basin exploration area based on four primary exploration criteria. One of the most significant criterion is the existence of thick, thermally mature, friable coals. A second criterion is the existence of fully gas-charged coals. Evaluation of this criterion requires reservoir geochemical data to delineate zones of meteoric influx where breaching has occurred. A third criterion is the presence of adequate reservoir permeability. Natural fracturing in coals is due to cleating and tectonic processes. Because of the general relationship between coal cleating and coal rank, coal cleating intensity can be estimated by analysis of regional coal rank maps. The final criterion is determining whether natural fractures are open or closed. To make this determination, remote sensing imagery interpretation is supported by ancillary data compiled from regional tectonic studies. Application of these four criteria to the San Juan Basin in a heuristic, stepwise process resulted in an overall 94% reduction in total basin exploration area. Application of the first criterion reduced the total basin exploration area by 80%. Application of the second criterion further winnows this area by an addition 9%. Application of the third criterion reduces the exploration area to 6% of the total original exploration area.

  11. Science on the Hill: Methane cloud hunting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane cloud hunting Methane cloud hunting Los Alamos researchers go hunting for methane gas over the Four Corners area of northwest New Mexico and find a strange daily pattern. July 12, 2015 methane map Methane, the primary component of natural gas, is also a potent greenhouse gas, trapping energy in the atmosphere. Last year NASA released satellite images showing a hot spot in the area where New Mexico, Colorado, Utah and Arizona meet, prompting scientists to go in search of the sources.

  12. Methane modeling: predicting the inflow of methane gas into coal mines. Quarterly technical progress report, April 1, 1982-June 30, 1982

    SciTech Connect (OSTI)

    Boyer, C.M. II; Hoysan, P.M.; Pavone, A.M.; Richmond, O.; Schwerer, F.C.; Smelser, R.E.

    1982-01-01

    Work on Phase I of the Contract program is essentially complete and was reported in the Phase I Technical Report which has been reviewed and accepted by the Contract Technical Project Officer. Phase I work included a survey of relevant technical literature and development, demonstration and documentation of a computer model, MINE1D, for flow of methane and water in coal strata for geometries corresponding to an advancing mine face and to a mine pillar. The Phase I models are one-dimensional in the space variable but describe time-dependent (nonsteady) phenomena and include gas sorption phenomena. Some revisions have been made to input/output sections of MINE1D and the documentation has been expanded. These modifications will be reported in the next Quarterly Technical Report. Preliminary test scenarios have been formulated and reviewed with the Contract Technical Project Officer for measurement of emissions during room-and-pillar and longwall mining operations. These preliminary scenarios are described in this report. A mathematical model has been developed to describe the increased stresses on the coal seam near mine openings. The model is based on an approximate elastic/plastic treatment of the coal seam and an elastic treatment of surrounding strata. In this model, elastic compaction of the coal seam decreases porosity and permeability, whereas plastic deformation increases the porosity of the natural fracture network and thereby increases the permeability. The model takes into account the effect of changes in pore fluid pressure (in the natural fracture network of the coal seam) on the deformation of the coal seam. This model is described in this report, and will be programmed for inclusion in revised versions of MINE1D and for use in the two-dimensional computer models now under development. 8 figures.

  13. Improved energy recovery from municipal solid wastes in sanitary landfills by two-phase digestion of biomass

    SciTech Connect (OSTI)

    Onu, Chukwu.

    1990-01-01

    The concept under investigaton was the separation of the acidogenic and the methanogenic phases of anaerobic fermentation, converting the sanitary landfill into an acid reactor and using a separate upflow fixed-film anaerobic reactor for methanogenesis. Acidic leachate from the landfill simulator was used as the influent substrate to the anaerobic reactor. The goal of the study was to improve both methane yield and concentration through nutrient addition and two-phase digestion of MSW. Sewage sludge was utilized to provide moisture, buffering capacity, nutrients, and an adequate microbial population. Single-phase systems with other enhancement techniques were also compared to the two-phase with sludge addition. Data from this study indicated that gas produced in the anaerobic reactor had methane concentration as high as 80 Mole % at the fixed-bed reactor (FBR) hydraulic retention time (HRT) of 7 days. The system reached a cumulative methane production rate of 78.6 {ell}/kg dry waste at an estimated cumulative production rate of approximately 270 {ell}/kg/yr. This performance was better than that reported in the literature for a similar type of feed. This study has also indicated that sewage sludge addition appears to be a successful enhancement technique for methane gas production from municipal solid waste. The addition of mineral nutrients and buffer solutions appears to have influenced the development of a dominant population of methanogenic bacteria in the FBR as indicated by the COD removal efficiency of 90% and 100% conversion of all influent organic acids. In terms of the overall system performance, the two-phase system was superior to the one-phase technique currently in use for methane generation.

  14. The presence of natural gas-primarily methane-in the shale layers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Late 1940s - Hydraulic fracturing first used to stimulate oil and gas wells. The first hydraulic fracturing treatment (not shown here ) was pumped in 1947 on a gas well operated by ...

  15. Methane Hydrates and Climate Change | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrates and Climate Change Methane Hydrates and Climate Change Methane hydrates store huge volumes of methane formed by the bacterial decay of organic matter or leaked from underlying oil and natural gas deposits. The active formation of methane hydrates in the shallow crust prevents methane, a greenhouse gas, from entering the atmosphere. On the other hand, warming of arctic sediments or ocean waters has the potential to cause methane hydrate to dissociate, releasing methane into the deepwater

  16. methane hydrates | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methane hydrates methane-hydrates.jpg Maintaining a focused vision on what's next is one trait that makes NETL a lab of the future, and methane hydrates are one "cool" part of that vision. Found in Arctic and deep-water marine environments, methane hydrates are an untapped abundant source of natural gas. A hydrate comprises a crystal structure in which frozen water creates a cage that traps molecules of primarily methane (natural gas). NETL researchers are exploring and developing

  17. Controlling Methane Emissions in the Natural Gas Sector. A Review of Federal and State Regulatory Frameworks Governing Production, Gathering, Processing, Transmission, and Distribution

    SciTech Connect (OSTI)

    Paranhos, Elizabeth; Kozak, Tracy G.; Boyd, William; Bradbury, James; Steinberg, D. C.; Arent, D. J.

    2015-04-23

    This report provides an overview of the regulatory frameworks governing natural gas supply chain infrastructure siting, construction, operation, and maintenance. Information was drawn from a number of sources, including published analyses, government reports, in addition to relevant statutes, court decisions and regulatory language, as needed. The scope includes all onshore facilities that contribute to methane emissions from the natural gas sector, focusing on three areas of state and federal regulations: (1) natural gas pipeline infrastructure siting and transportation service (including gathering, transmission, and distribution pipelines), (2) natural gas pipeline safety, and (3) air emissions associated with the natural gas supply chain. In addition, the report identifies the incentives under current regulatory frameworks to invest in measures to reduce leakage, as well as the barriers facing investment in infrastructure improvement to reduce leakage. Policy recommendations regarding how federal or state authorities could regulate methane emissions are not provided; rather, existing frameworks are identified and some of the options for modifying existing regulations or adopting new regulations to reduce methane leakage are discussed.

  18. Coalbed Methane | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coalbed Methane Coalbed Methane Coalbed methane is natural gas found in coal deposits. It was once considered a nuisance and mine safety hazard, but today has become a valuable part of the U.S. energy portfolio. A major reason for this is resource characterization and the establishment of efficient recovery methods pioneered by Office of Fossil Energy R&D. Fossil Energy Research Benefits - Coalbed Methane (920.32 KB) More Documents & Publications Before the Senate Energy and Natural

  19. Vertical borehole design and completion practices used to remove methane gas from mineable coalbeds

    SciTech Connect (OSTI)

    Lambert, S.W.; Trevits, M.A.; Steidl, P.F.

    1980-08-01

    Coalbed gas drainage from the surface in advance of mining has long been the goal of researchers in mine safety. Bureau of Mines efforts to achieve this goal started about 1965 with the initiation of an applied research program designed to test drilling, completion, and production techniques for vertical boreholes. Under this program, over 100 boreholes were completed in 16 different coalbeds. The field methods derived from these tests, together with a basic understanding of the coalbed reservoir, represent an available technology applicable to any gas drainage program whether designed primarily for mine safety or for gas recovery, or both.

  20. Aerobic landfill bioreactor

    DOE Patents [OSTI]

    Hudgins, Mark P; Bessette, Bernard J; March, John; McComb, Scott T.

    2000-01-01

    The present invention includes a method of decomposing municipal solid waste (MSW) within a landfill by converting the landfill to aerobic degradation in the following manner: (1) injecting air via the landfill leachate collection system (2) injecting air via vertical air injection wells installed within the waste mass; (3) applying leachate to the waste mass using a pressurized drip irrigation system; (4) allowing landfill gases to vent; and (5) adjusting air injection and recirculated leachate to achieve a 40% to 60% moisture level and a temperature between 120.degree. F. and 140.degree. F. in steady state.

  1. Aerobic landfill bioreactor

    DOE Patents [OSTI]

    Hudgins, Mark P; Bessette, Bernard J; March, John C; McComb, Scott T.

    2002-01-01

    The present invention includes a system of decomposing municipal solid waste (MSW) within a landfill by converting the landfill to aerobic degradation in the following manner: (1) injecting air via the landfill leachate collection system (2) injecting air via vertical air injection wells installed within the waste mass; (3) applying leachate to the waste mass using a pressurized drip irrigation system; (4) allowing landfill gases to vent; and (5) adjusting air injection and recirculated leachate to achieve a 40% to 60% moisture level and a temperature between 120.degree. F. and 140.degree. F. in steady state.

  2. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; Pinnau, Ingo; Segelke, Scott

    1997-01-01

    A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

  3. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

    1997-09-23

    A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

  4. Russian Policy on Methane Emissions in the Oil and Gas Sector: A Case Study in Opportunities and Challenges in Reducing Short-Lived Forcers

    SciTech Connect (OSTI)

    Evans, Meredydd; Roshchanka, Volha

    2014-08-04

    This paper uses Russian policy in the oil and gas sector as a case study in assessing options and challenges for scaling-up emission reductions. We examine the challenges to achieving large-scale emission reductions, successes that companies have achieved to date, how Russia has sought to influence methane emissions through its environmental fine system, and options for helping companies achieve large-scale emission reductions in the future through simpler and clearer incentives.

  5. GHG emission factors developed for the collection, transport and landfilling of municipal waste in South African municipalities

    SciTech Connect (OSTI)

    Friedrich, Elena; Trois, Cristina

    2013-04-15

    Highlights: ► An average GHG emission factor for the collection and transport of municipal solid waste in South Africa is calculated. ► A range of GHG emission factors for different types of landfills (including dumps) in South Africa are calculated. ► These factors are compared internationally and their implications for South Africa and developing countries are discussed . ► Areas for new research are highlighted. - Abstract: Greenhouse gas (GHG) emission factors are used with increased frequency for the accounting and reporting of GHG from waste management. However, these factors have been calculated for developed countries of the Northern Hemisphere and are lacking for developing countries. This paper shows how such factors have been developed for the collection, transport and landfilling of municipal waste in South Africa. As such it presents a model on how international results and methodology can be adapted and used to calculate country-specific GHG emission factors from waste. For the collection and transport of municipal waste in South Africa, the average diesel consumption is around 5 dm{sup 3} (litres) per tonne of wet waste and the associated GHG emissions are about 15 kg CO{sub 2} equivalents (CO{sub 2} e). Depending on the type of landfill, the GHG emissions from the landfilling of waste have been calculated to range from −145 to 1016 kg CO{sub 2} e per tonne of wet waste, when taking into account carbon storage, and from 441 to 2532 kg CO{sub 2} e per tonne of wet waste, when carbon storage is left out. The highest emission factor per unit of wet waste is for landfill sites without landfill gas collection and these are the dominant waste disposal facilities in South Africa. However, cash strapped municipalities in Africa and the developing world will not be able to significantly upgrade these sites and reduce their GHG burdens if there is no equivalent replacement of the Clean Development Mechanism (CDM) resulting from the Kyoto agreement

  6. Conversion of forest residues to a methane-rich gas: Interim Report

    SciTech Connect (OSTI)

    Feldmann, H.G.; Paisley, M.A.; Appelbaum, H.R.

    1986-03-01

    A process is being developed that produces a fuel gas with a heating value of 500 Btu/SCF from diverse forms of biomass, including shredded bark, wood chips, and sawdust. The system uses a high throughput, non-oxygen gasifier that employs sand circulation to supply process heat. Results obtained with a 10-inch I.D. gasifier are presented and compared with those in a 6-inch I.D. reactor. Feed rates up to 12 tons/day (dry) have been achieved corresponding to a specific wood throughput of 2000 lbs/ft/sup 2/-hr. Gas compositions in the two reactors are in excellent agreement and performance in the larger reactor, as measured by carbon conversion, is significantly improved. Cost projections comparing this process with direct combustion are presented that indicate gasification technology should have very significant cost advantages for both generation of plant steam and cogeneration of electricity. 5 refs., 14 figs., 5 tabs.

  7. Performance evaluation of an anaerobic/aerobic landfill-based digester using yard waste for energy and compost production

    SciTech Connect (OSTI)

    Yazdani, Ramin; Barlaz, Morton A.; Augenstein, Don; Kayhanian, Masoud; Tchobanoglous, George

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Biochemical methane potential decreased by 83% during the two-stage operation. Black-Right-Pointing-Pointer Net energy produced was 84.3 MWh or 46 kWh per million metric tons (Mg). Black-Right-Pointing-Pointer The average removal efficiency of volatile organic compounds (VOCs) was 96-99%. Black-Right-Pointing-Pointer The average removal efficiency of non-methane organic compounds (NMOCs) was 68-99%. Black-Right-Pointing-Pointer The two-stage batch digester proved to be simple to operate and cost-effective. - Abstract: The objective of this study was to evaluate a new alternative for yard waste management by constructing, operating and monitoring a landfill-based two-stage batch digester (anaerobic/aerobic) with the recovery of energy and compost. The system was initially operated under anaerobic conditions for 366 days, after which the yard waste was aerated for an additional 191 days. Off gas generated from the aerobic stage was treated by biofilters. Net energy recovery was 84.3 MWh, or 46 kWh per million metric tons of wet waste (as received), and the biochemical methane potential of the treated waste decreased by 83% during the two-stage operation. The average removal efficiencies of volatile organic compounds and non-methane organic compounds in the biofilters were 96-99% and 68-99%, respectively.

  8. Electrochemical methane sensor

    DOE Patents [OSTI]

    Zaromb, S.; Otagawa, T.; Stetter, J.R.

    1984-08-27

    A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

  9. ARM - Measurement - Methane concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Methane concentration The amount of methane, a greenhouse gas, per unit of volume. Categories Atmospheric Carbon Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those

  10. Methyl chloride via oxyhydrochlorination of methane: A building block for chemicals and fuels from natural gas

    SciTech Connect (OSTI)

    Benson, R.L.; Brown, S.S.D.; Ferguson, S.P.; Jarvis, R.F. Jr.

    1995-12-31

    The objectives of this program are to (a) develop a process for converting natural gas to methyl chloride via an oxyhydrochlorination route using highly selective, stable catalysts in a fixed-bed, (b) design a reactor capable of removing the large amount of heat generated in the process so as to control the reaction, (c) develop a recovery system capable of removing the methyl chloride from the product stream and (d) determine the economics and commercial viability of the process. The general approach has been as follows: (a) design and build a laboratory scale reactor, (b) define and synthesize suitable OHC catalysts for evaluation, (c) select first generation OHC catalyst for Process Development Unit (PDU) trials, (d) design, construct and startup PDU, (e) evaluate packed bed reactor design, (f) optimize process, in particular, product recovery operations, (g) determine economics of process, (h) complete preliminary engineering design for Phase II and (i) make scale-up decision and formulate business plan for Phase II. Conclusions regarding process development and catalyst development are presented.

  11. Natural gas cleanup: Evaluation of a molecular sieve carbon as a pressure swing adsorbent for the separation of methane/nitrogen mixtures

    SciTech Connect (OSTI)

    Grimes, R.W.

    1994-06-01

    This report describes the results of a preliminary evaluation to determine the technical feasibility of using a molecular sieve carbon manufactured by the Takeda Chemical Company of Japan in a pressure owing adsorption cycle for upgrading natural gas (methane) contaminated with nitrogen. Adsorption tests were conducted using this adsorbent in two, four, and five-step adsorption cycles. Separation performance was evaluated in terms of product purity, product recovery, and sorbent productivity for all tests. The tests were conducted in a small, single-column adsorption apparatus that held 120 grams of the adsorbent. Test variables included adsorption pressure, pressurization rate, purge rate and volume, feed rate, and flow direction in the steps from which the product was collected. Sorbent regeneration was accomplished by purging the column with the feed gas mixture for all but one test series where a pure methane purge was used. The ratio between the volumes of the pressurization gas and the purge gas streams was found to be an important factor in determining separation performance. Flow rates in the various cycle steps had no significant effect. Countercurrent flow in the blow-down and purge steps improved separation performance. Separation performance appears to improve with increasing adsorption pressure, but because there are a number of interrelated variables that are also effected by pressure, further testing will be needed to verify this. The work demonstrates that a molecular sieve carbon can be used to separate a mixture of methane and nitrogen when used in a pressure swing cycle with regeneration by purge. Further work is needed to increase product purity and product recovery.

  12. Landfill mining: A critical review of two decades of research

    SciTech Connect (OSTI)

    Krook, Joakim; Svensson, Niclas; Eklund, Mats

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer We analyze two decades of landfill mining research regarding trends and topics. Black-Right-Pointing-Pointer So far landfill mining has mainly been used to solve waste management issues. Black-Right-Pointing-Pointer A new perspective on landfills as resource reservoirs is emerging. Black-Right-Pointing-Pointer The potential of resource extraction from landfills is significant. Black-Right-Pointing-Pointer We outline several key challenges for realization of resource extraction from landfills. - Abstract: Landfills have historically been seen as the ultimate solution for storing waste at minimum cost. It is now a well-known fact that such deposits have related implications such as long-term methane emissions, local pollution concerns, settling issues and limitations on urban development. Landfill mining has been suggested as a strategy to address such problems, and in principle means the excavation, processing, treatment and/or recycling of deposited materials. This study involves a literature review on landfill mining covering a meta-analysis of the main trends, objectives, topics and findings in 39 research papers published during the period 1988-2008. The results show that, so far, landfill mining has primarily been seen as a way to solve traditional management issues related to landfills such as lack of landfill space and local pollution concerns. Although most initiatives have involved some recovery of deposited resources, mainly cover soil and in some cases waste fuel, recycling efforts have often been largely secondary. Typically, simple soil excavation and screening equipment have therefore been applied, often demonstrating moderate performance in obtaining marketable recyclables. Several worldwide changes and recent research findings indicate the emergence of a new perspective on landfills as reservoirs for resource extraction. Although the potential of this approach appears significant, it is argued that

  13. Gas Recovery Systems | Open Energy Information

    Open Energy Info (EERE)

    Systems Jump to: navigation, search Name: Gas Recovery Systems Place: California Zip: 94550 Product: Turnkey landfill gas (LFG) energy extraction systems. References: Gas Recovery...

  14. DFW Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    DFW Gas Recovery Biomass Facility Jump to: navigation, search Name DFW Gas Recovery Biomass Facility Facility DFW Gas Recovery Sector Biomass Facility Type Landfill Gas Location...

  15. Lake Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Gas Recovery Biomass Facility Jump to: navigation, search Name Lake Gas Recovery Biomass Facility Facility Lake Gas Recovery Sector Biomass Facility Type Landfill Gas Location Cook...

  16. CID Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    CID Gas Recovery Biomass Facility Jump to: navigation, search Name CID Gas Recovery Biomass Facility Facility CID Gas Recovery Sector Biomass Facility Type Landfill Gas Location...

  17. CSL Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    CSL Gas Recovery Biomass Facility Jump to: navigation, search Name CSL Gas Recovery Biomass Facility Facility CSL Gas Recovery Sector Biomass Facility Type Landfill Gas Location...

  18. BJ Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    BJ Gas Recovery Biomass Facility Jump to: navigation, search Name BJ Gas Recovery Biomass Facility Facility BJ Gas Recovery Sector Biomass Facility Type Landfill Gas Location...

  19. Enzymatic Oxidation of Methane

    SciTech Connect (OSTI)

    Sirajuddin, S; Rosenzweig, AC

    2015-04-14

    Methane monooxygenases (MMOs) are enzymes that catalyze the oxidation of methane to methanol in methanotrophic bacteria. As potential targets for new gas-to-liquid methane bioconversion processes, MMOs have attracted intense attention in recent years. There are two distinct types of MMO, a soluble, cytoplasmic MMO (sMMO) and a membrane-bound, particulate MMO (pMMO). Both oxidize methane at metal centers within a complex, multisubunit scaffold, but the structures, active sites, and chemical mechanisms are completely different. This Current Topic review article focuses on the overall architectures, active site structures, substrate reactivities, proteinprotein interactions, and chemical mechanisms of both MMOs, with an emphasis on fundamental aspects. In addition, recent advances, including new details of interactions between the sMMO components, characterization of sMMO intermediates, and progress toward understanding the pMMO metal centers are highlighted. The work summarized here provides a guide for those interested in exploiting MMOs for biotechnological applications.

  20. Unconventional gas outlook: resources, economics, and technologies

    SciTech Connect (OSTI)

    Drazga, B.

    2006-08-15

    The report explains the current and potential of the unconventional gas market including country profiles, major project case studies, and new technology research. It identifies the major players in the market and reports their current and forecasted projects, as well as current volume and anticipated output for specific projects. Contents are: Overview of unconventional gas; Global natural gas market; Drivers of unconventional gas sources; Forecast; Types of unconventional gas; Major producing regions Overall market trends; Production technology research; Economics of unconventional gas production; Barriers and challenges; Key regions: Australia, Canada, China, Russia, Ukraine, United Kingdom, United States; Major Projects; Industry Initiatives; Major players. Uneconomic or marginally economic resources such as tight (low permeability) sandstones, shale gas, and coalbed methane are considered unconventional. However, due to continued research and favorable gas prices, many previously uneconomic or marginally economic gas resources are now economically viable, and may not be considered unconventional by some companies. Unconventional gas resources are geologically distinct in that conventional gas resources are buoyancy-driven deposits, occurring as discrete accumulations in structural or stratigraphic traps, whereas unconventional gas resources are generally not buoyancy-driven deposits. The unconventional natural gas category (CAM, gas shales, tight sands, and landfill) is expected to continue at double-digit growth levels in the near term. Until 2008, demand for unconventional natural gas is likely to increase at an AAR corresponding to 10.7% from 2003, aided by prioritized research and development efforts. 1 app.

  1. Presentations from the March 27th - 28th Methane Hydrates Advisory...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting PDF icon International Gas ...

  2. Enhanced Renewable Methane Production System | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced Renewable Methane Production System Technology available for licensing: Enhanced renewable methane production system provides a low-cost process that accelerates biological methane production rates at least fivefold. Low cost Delivers near-pipeline-quality gas and eliminates carbon dioxide emissions PDF icon methane_production_system

  3. Capping methane leaks a win-win

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capping methane leaks a win-win Capping methane leaks a win-win As special correspondent Kathleen McCleery explains, that's why both environmentalists and the energy industry are trying to find ways to capture leaks from oil and gas facilities. November 13, 2015 Capping methane leaks a win-win Methane, the primary component of natural gas, is also a potent greenhouse gas, trapping energy in the atmosphere. Last year NASA released satellite images showing a hot spot in the area where New Mexico,

  4. New Methane Hydrate Research: Investing in Our Energy Future | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Methane Hydrate Research: Investing in Our Energy Future New Methane Hydrate Research: Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped natural gas. Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed or depressurized, it will release the trapped

  5. Altamont Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    search Name Altamont Gas Recovery Biomass Facility Facility Altamont Gas Recovery Sector Biomass Facility Type Landfill Gas Location Alameda County, California Coordinates...

  6. Effect of bubble size and density on methane conversion to hydrate

    SciTech Connect (OSTI)

    Leske, J.; Taylor, C.E.; Ladner, E.P.

    2007-03-01

    Research is underway at NETL to understand the physical properties of methane hydrates. One area of investigation is the storage of methane as methane hydrates. An economical and efficient means of storing methane in hydrates opens many commercial opportunities such as transport of stranded gas, off-peak storage of line gas, etc.We have observed during our investigations that the ability to convert methane to methane hydrate is enhanced by foaming of the methanewater solution using a surfactant. The density of the foam, along with the bubble size, is important in the conversion of methane to methane hydrate.

  7. Phytoremediation of landfill leachate

    SciTech Connect (OSTI)

    Jones, D.L. . E-mail: d.jones@bangor.ac.uk; Williamson, K.L.; Owen, A.G.

    2006-07-01

    Leachate emissions from landfill sites are of concern, primarily due to their toxic impact when released unchecked into the environment, and the potential for landfill sites to generate leachate for many hundreds of years following closure. Consequently, economically and environmentally sustainable disposal options are a priority in waste management. One potential option is the use of soil-plant based remediation schemes. In many cases, using either trees (including short rotation coppice) or grassland, phytoremediation of leachate has been successful. However, there are a significant number of examples where phytoremediation has failed. Typically, this failure can be ascribed to excessive leachate application and poor management due to a fundamental lack of understanding of the plant-soil system. On balance, with careful management, phytoremediation can be viewed as a sustainable, cost effective and environmentally sound option which is capable of treating 250 m{sup 3} ha{sup -1} yr{sup -1}. However, these schemes have a requirement for large land areas and must be capable of responding to changes in leachate quality and quantity, problems of scheme establishment and maintenance, continual environmental monitoring and seasonal patterns of plant growth. Although the fundamental underpinning science is well understood, further work is required to create long-term predictive remediation models, full environmental impact assessments, a complete life-cycle analysis and economic analyses for a wide range of landfill scenarios.

  8. Process for separating nitrogen from methane using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee; Qiu, Dongming; Dritz, Terence Andrew; Neagle, Paul; Litt, Robert Dwayne; Arora, Ravi; Lamont, Michael Jay; Pagnotto, Kristina M.

    2007-07-31

    The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

  9. International Cooperation in Methane Hydrates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oil & Gas » Methane Hydrate » International Cooperation in Methane Hydrates International Cooperation in Methane Hydrates In 1982 the multi-national Deep Sea Drilling Program (DSDP) recovered the first subsea substantial methane hydrate deposits, which spurred methane hydrate research in the US and other countries. The successor programs, the Ocean Drilling Program (ODP) and the Integrated Ocean Drilling Program (IODP) sampled hydrate deposits off Oregon (ODP 204, 2002) and in the Cascadia

  10. METHOD FOR PRODUCING ISOTOPIC METHANES AND PARTIALLY HALOGENATED DERIVATIVES THEROF

    DOE Patents [OSTI]

    Frazer, J.W.

    1959-08-18

    A method is given for producing isotopic methanes and/ or partially halogenated derivatives. Lithium hydride, deuteride, or tritide is reacted with a halogenated methane or with a halogenated methane in combination with free halogen. The process is conveniently carried out by passing a halogenated methane preferably at low pressures or in an admixture with an inert gas through a fixed bed of finely divided lithium hydride heated initially to temperatures of 100 to 200 deg C depending upon the halogenated methane used.

  11. ARM - Methane Background Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WarmingMethane Background Information Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Methane Background Information What is Methane? Why Do We Use Methane? How is Methane Made? Where Do We Find Methane? Can Methane Be Dangerous? Does Methane Contribute to Climate Change? What is Methane?

  12. Conversion of forest residues to a methane-rich gas in a high-throughput gasifier. Summary report

    SciTech Connect (OSTI)

    Feldmann, H.F.; Paisley, M.A.; Folsom, D.W.; Kim, B.C.

    1981-10-31

    Results of the experimental work conducted thus far have shown that wood can be readily gasified in a steam environment into a hydrocarbon rich fuel gas that can be used as a replacement for petroleum-based fuels or natural gas with minimal boiler retrofit. Further, this conversion can be achieved in a compact gasification reactor with heat supplied by a circulating entrained phase, thereby eliminating the need for an oxygen plant. Tars have not been found except at the lowest gasifier temperatures employed, and therefore heat recovery from the product gas should be much simpler than that from commercially available fixed-bed gasification systems where product gas contains significant quantities of tar. The data generated have been used in a preliminary conceptual design. Evaluation of this design has shown that a medium-Btu gas can be produced from wood at a cost competitive with natural gas or petroleum-based fuels.

  13. Solubility of methane in water under natural conditions: a laboratory...

    Office of Scientific and Technical Information (OSTI)

    302sup 0F. Also the solubility of crude oil and water in methane has been determined ... Increasing pressure increases the solubility of crude oil in methane gas. At an elevated ...

  14. Estimating global and North American methane emissions with high spatial resolution using GOSAT satellite data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Turner, A. J.; Jacob, D. J.; Wecht, K. J.; Maasakkers, J. D.; Biraud, S. C.; Boesch, H.; Bowman, K. W.; Deutscher, N. M.; Dubey, M. K.; Griffith, D. W. T.; et al

    2015-02-18

    We use 2009–2011 space-borne methane observations from the Greenhouse Gases Observing SATellite (GOSAT) to constrain global and North American inversions of methane emissions with 4° × 5° and up to 50 km × 50 km spatial resolution, respectively. The GOSAT data are first evaluated with atmospheric methane observations from surface networks (NOAA, TCCON) and aircraft (NOAA/DOE, HIPPO), using the GEOS-Chem chemical transport model as a platform to facilitate comparison of GOSAT with in situ data. This identifies a high-latitude bias between the GOSAT data and GEOS-Chem that we correct via quadratic regression. The surface and aircraft data are subsequently usedmore » for independent evaluation of the methane source inversions. Our global adjoint-based inversion yields a total methane source of 539 Tg a−1 and points to a large East Asian overestimate in the EDGARv4.2 inventory used as a prior. Results serve as dynamic boundary conditions for an analytical inversion of North American methane emissions using radial basis functions to achieve high resolution of large sources and provide full error characterization. We infer a US anthropogenic methane source of 40.2–42.7 Tg a−1, as compared to 24.9–27.0 Tg a−1 in the EDGAR and EPA bottom-up inventories, and 30.0–44.5 Tg a−1 in recent inverse studies. Our estimate is supported by independent surface and aircraft data and by previous inverse studies for California. We find that the emissions are highest in the South-Central US, the Central Valley of California, and Florida wetlands, large isolated point sources such as the US Four Corners also contribute. We attribute 29–44% of US anthropogenic methane emissions to livestock, 22–31% to oil/gas, 20% to landfills/waste water, and 11–15% to coal with an additional 9.0–10.1 Tg a−1 source from wetlands.« less

  15. LASO Airport Landfill | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LASO Airport Landfill LASO Airport Landfill The Los Alamos Airport Landfill consists of two inactive solid waste disposal sites [the airport landfill, SWMU 73-001(a) and the debris disposal area (DDA), SWMU 73-001(d)] are located at the Los Alamos County Airport. In late 2006 and early 2007, the Final Remedy landfill cover system was installed at the airport landfill. The Final Remedy design and completion activities for the airport landfill and the DDA are provided in the Remedy Completion

  16. ITP Industrial Distributed Energy: CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market Opportunities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Landfills and Wastewater Treatment Plants: Market Opportunities November 7, 2007 Denver, Colorado Paul Lemar Jr., President pll@rdcnet.com www.rdcnet.com www.distributed-generation.com CHP and Bioenergy for Landfills and Wastewater Treatment Plants November 7, 2007 The Opportunity for Alternative CHP Fuels z High natural gas prices have decreased spark spreads and reduced CHP market potential z Increasing natural gas supply or reducing demand substantially is unlikely z Renewable portfolio

  17. Landfilling ash/sludge mixtures

    SciTech Connect (OSTI)

    Benoit, J.; Eighmy, T.T.; Crannell, B.S.

    1999-10-01

    The geotechnical properties of a mixture of municipal solid waste incinerator bottom ash and municipal wastewater treatment plant sludge was investigated for a proposed ash/sludge secure landfill. The components as well as mixtures ranging from 10:1 to 5:1 (ash:sludge, by volume) were evaluated, where appropriate, for a number of geotechnical index and mechanical properties including particle size, water content, specific gravity, density-moisture relationships, shear strength, and compressibility. The results from a compactibility study and stability analysis of the proposed landfill were used to help approve a landfill codisposal concept; a full-scale facility was constructed and is currently operating successfully.

  18. Blackburn Landfill Co-Generation Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Blackburn Landfill Co-Generation Biomass Facility Jump to: navigation, search Name Blackburn Landfill Co-Generation Biomass Facility Facility Blackburn Landfill Co-Generation...

  19. EA-1997: Construction Landfill Expansion, Pantex Plant, Amarillo...

    Office of Environmental Management (EM)

    7: Construction Landfill Expansion, Pantex Plant, Amarillo, Texas EA-1997: Construction Landfill Expansion, Pantex Plant, Amarillo, Texas SUMMARY Construction Landfill Expansion,...

  20. Miramar Landfill Metro Biosolids Center Biomass Facility | Open...

    Open Energy Info (EERE)

    Miramar Landfill Metro Biosolids Center Biomass Facility Jump to: navigation, search Name Miramar Landfill Metro Biosolids Center Biomass Facility Facility Miramar Landfill Metro...

  1. Prima Desheha Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Prima Desheha Landfill Biomass Facility Jump to: navigation, search Name Prima Desheha Landfill Biomass Facility Facility Prima Desheha Landfill Sector Biomass Facility Type...

  2. EA-1707: Closure of Nonradioactive Dangerous Waste Landfill and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    07: Closure of Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill, Hanford Site, Richland, Washington EA-1707: Closure of Nonradioactive Dangerous Waste Landfill and...

  3. Byxbee Park Sanitary Landfill Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Byxbee Park Sanitary Landfill Biomass Facility Jump to: navigation, search Name Byxbee Park Sanitary Landfill Biomass Facility Facility Byxbee Park Sanitary Landfill Sector Biomass...

  4. Risk assessment of landfill disposal sites - State of the art

    SciTech Connect (OSTI)

    Butt, Talib E. Lockley, Elaine; Oduyemi, Kehinde O.K.

    2008-07-01

    A risk assessment process can assist in drawing a cost-effective compromise between economic and environmental costs, thereby assuring that the philosophy of 'sustainable development' is adhered to. Nowadays risk analysis is in wide use to effectively manage environmental issues. Risk assessment is also applied to other subjects including health and safety, food, finance, ecology and epidemiology. The literature review of environmental risk assessments in general and risk assessment approaches particularly regarding landfill disposal sites undertaken by the authors, reveals that an integrated risk assessment methodology for landfill gas, leachate or degraded waste does not exist. A range of knowledge gaps is discovered in the literature reviewed to date. From the perspective of landfill leachate, this paper identifies the extent to which various risk analysis aspects are absent in the existing approaches.

  5. Estimation of landfill emission lifespan using process oriented modeling

    SciTech Connect (OSTI)

    Ustohalova, Veronika . E-mail: veronika.ustohalova@uni-essen.de; Ricken, Tim; Widmann, Renatus

    2006-07-01

    Depending on the particular pollutants emitted, landfills may require service activities lasting from hundreds to thousands of years. Flexible tools allowing long-term predictions of emissions are of key importance to determine the nature and expected duration of maintenance and post-closure activities. A highly capable option represents predictions based on models and verified by experiments that are fast, flexible and allow for the comparison of various possible operation scenarios in order to find the most appropriate one. The intention of the presented work was to develop a experimentally verified multi-dimensional predictive model capable of quantifying and estimating processes taking place in landfill sites where coupled process description allows precise time and space resolution. This constitutive 2-dimensional model is based on the macromechanical theory of porous media (TPM) for a saturated thermo-elastic porous body. The model was used to simulate simultaneously occurring processes: organic phase transition, gas emissions, heat transport, and settlement behavior on a long time scale for municipal solid waste deposited in a landfill. The relationships between the properties (composition, pore structure) of a landfill and the conversion and multi-phase transport phenomena inside it were experimentally determined. In this paper, we present both the theoretical background of the model and the results of the simulations at one single point as well as in a vertical landfill cross section.

  6. Chestnut Ridge Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Chestnut Ridge Gas Recovery Sector Biomass Facility Type Landfill Gas Location Anderson County, Tennessee Coordinates 36.0809574, -84.2278796 Show Map Loading map......

  7. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of

  8. Estimating global and North American methane emissions with high spatial resolution using GOSAT satellite data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Turner, A. J.; Jacob, D. J.; Wecht, K. J.; Maasakkers, J. D.; Lundgren, E.; Andrews, A. E.; Biraud, S. C.; Boesch, H.; Bowman, K. W.; Deutscher, N. M.; et al

    2015-06-30

    We use 2009–2011 space-borne methane observations from the Greenhouse Gases Observing SATellite (GOSAT) to estimate global and North American methane emissions with 4° × 5° and up to 50 km × 50 km spatial resolution, respectively. GEOS-Chem and GOSAT data are first evaluated with atmospheric methane observations from surface and tower networks (NOAA/ESRL, TCCON) and aircraft (NOAA/ESRL, HIPPO), using the GEOS-Chem chemical transport model as a platform to facilitate comparison of GOSAT with in situ data. This identifies a high-latitude bias between the GOSAT data and GEOS-Chem that we correct via quadratic regression. Our global adjoint-based inversion yields a totalmore » methane source of 539 Tg a−1 with some important regional corrections to the EDGARv4.2 inventory used as a prior. Results serve as dynamic boundary conditions for an analytical inversion of North American methane emissions using radial basis functions to achieve high resolution of large sources and provide error characterization. We infer a US anthropogenic methane source of 40.2–42.7 Tg a−1, as compared to 24.9–27.0 Tg a−1 in the EDGAR and EPA bottom-up inventories, and 30.0–44.5 Tg a−1 in recent inverse studies. Our estimate is supported by independent surface and aircraft data and by previous inverse studies for California. We find that the emissions are highest in the southern–central US, the Central Valley of California, and Florida wetlands; large isolated point sources such as the US Four Corners also contribute. Using prior information on source locations, we attribute 29–44 % of US anthropogenic methane emissions to livestock, 22–31 % to oil/gas, 20 % to landfills/wastewater, and 11–15 % to coal. Wetlands contribute an additional 9.0–10.1 Tg a−1.« less

  9. Semi-annual report for the unconventional gas recovery program, period ending March 31, 1980

    SciTech Connect (OSTI)

    Manilla, R.D.

    1980-06-01

    Four subprograms are reported on: methane recovery from coalbeds, Eastern gas shales, Western gas sands, and methane from geopressured aquifers. (DLC)

  10. Application of gas-liquid two-phase cross-flow filtration to pilot-scale methane fermentation

    SciTech Connect (OSTI)

    Imasaka, Takuo; So, Hiroyuki; Matsushita, Kohnosuke; Furukawa, Tomoya; Kanekuni, Nobuhiko )

    1993-01-01

    As part of a national project, Aqua-Renaissance '90,' by the MITI, a pilot-scale evaluation of membrane-enhanced anaerobic fermentation, has progressed for the wastewater from a pulp and paper mill. A novel membrane filtration system was newly proposed with the aim of saving energy. That is, a gas-liquid two-phase cross-flow filtration which was generated with liquid circulation by an air-lift pump effect, was combined in the anaerobic bioreactor. It was confirmed that the membrane filtration not only offered very stable and large permeate flux, but enhanced the processing efficiency by retaining the microorganisms in the bioreactor. Furthermore, the power consumption per unit permeate volume in the membrane system of 1.78 kWh/m[sup 3] was achieved, which was a very high-performance result from the viewpoint of saving energy, as compared with 3-5 kWh/m[sup 3] of conventional liquid single-phase cross-flow filtration.

  11. Methane Hydrate Production Technologies to be Tested on Alaska's North

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Slope | Department of Energy Methane Hydrate Production Technologies to be Tested on Alaska's North Slope Methane Hydrate Production Technologies to be Tested on Alaska's North Slope October 24, 2011 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy, the Japan Oil, Gas and Metals National Corporation, and ConocoPhillips will work together to test innovative technologies for producing methane gas from hydrate deposits on the Alaska North Slope. The collaborative testing will

  12. Rapid Production of Methane Hydrates | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rapid Production of Methane Hydrates NETL Develops a Method for Rapidly Producing Methane Hydrates Natural gas, which is predominantly methane, is recognized as clean burning and an important bridge fuel to a future where renewable energy sources are more common. Natural gas currently accounts for nearly a quarter of the U.S. energy supply, and that share is expected to remain roughly constant over the next several decades. Energy demand during this time period is expected to continue growing,

  13. Short Mountain Landfill gas recovery project

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The Bonneville Power Administration (BPA), a Federal power marketing agency, has statutory responsibilities to supply electrical power to its utility, industrial, and other customers in the Pacific Northwest. BPA's latest load/resource balance forecast, projects the capability of existing resources to satisfy projected Federal system loads. The forecast indicates a potential resource deficit. The underlying need for action is to satisfy BPA customers' demand for electrical power.

  14. Comparison of slope stability in two Brazilian municipal landfills

    SciTech Connect (OSTI)

    Gharabaghi, B. Singh, M.K.; Inkratas, C. Fleming, I.R. McBean, E.

    2008-07-01

    The implementation of landfill gas to energy (LFGTE) projects has greatly assisted in reducing the greenhouse gases and air pollutants, leading to an improved local air quality and reduced health risks. The majority of cities in developing countries still dispose of their municipal waste in uncontrolled 'open dumps.' Municipal solid waste landfill construction practices and operating procedures in these countries pose a challenge to implementation of LFGTE projects because of concern about damage to the gas collection infrastructure (horizontal headers and vertical wells) caused by minor, relatively shallow slumps and slides within the waste mass. While major slope failures can and have occurred, such failures in most cases have been shown to involve contributory factors or triggers such as high pore pressures, weak foundation soil or failure along weak geosynthetic interfaces. Many researchers who have studied waste mechanics propose that the shear strength of municipal waste is sufficient such that major deep-seated catastrophic failures under most circumstances require such contributory factors. Obviously, evaluation of such potential major failures requires expert analysis by geotechnical specialists with detailed site-specific information regarding foundation soils, interface shearing resistances and pore pressures both within the waste and in clayey barrier layers or foundation soils. The objective of this paper is to evaluate the potential use of very simple stability analyses which can be used to study the potential for slumps and slides within the waste mass and which may represent a significant constraint on construction and development of the landfill, on reclamation and closure and on the feasibility of a LFGTE project. The stability analyses rely on site-specific but simple estimates of the unit weight of waste and the pore pressure conditions and use 'generic' published shear strength envelopes for municipal waste. Application of the slope stability

  15. Sanitary landfill groundwater monitoring data

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-05-01

    This report for first quarter 1992 contains sanitary landfill groundwater monitoring data for the Savannah River Plant. The data tables presented in this report are copies of draft analytical results and therefore do contain errors. These errors will be corrected when the finalized data is received from the laboratory.

  16. Study of the VOC emissions from a municipal solid waste storage pilot-scale cell: Comparison with biogases from municipal waste landfill site

    SciTech Connect (OSTI)

    Chiriac, R.; De Araujos Morais, J.; Carre, J.; Bayard, R.; Chovelon, J.M.; Gourdon, R.

    2011-11-15

    Highlights: > Follow-up of the emission of VOCs in a municipal waste pilot-scale cell during the acidogenesis and acetogenesis phases. > Study from the very start of waste storage leading to a better understanding of the decomposition/degradation of waste. > Comparison of the results obtained on the pilot-scale cell with those from 3 biogases coming from the same landfill site. > A methodology of characterization for the progression of the stabilization/maturation of waste is finally proposed. - Abstract: The emission of volatile organic compounds (VOCs) from municipal solid waste stored in a pilot-scale cell containing 6.4 tonnes of waste (storage facility which is left open during the first period (40 days) and then closed with recirculation of leachates during a second period (100 days)) was followed by dynamic sampling on activated carbon and analysed by GC-MS after solvent extraction. This was done in order to know the VOC emissions before the installation of a methanogenesis process for the entire waste mass. The results, expressed in reference to toluene, were exploited during the whole study on all the analyzable VOCs: alcohols, ketones and esters, alkanes, benzenic and cyclic compounds, chlorinated compounds, terpene, and organic sulphides. The results of this study on the pilot-scale cell are then compared with those concerning three biogases from a municipal waste landfill: biogas (1) coming from waste cells being filled or recently closed, biogas (2) from all the waste storage cells on site, and biogas (3) which is a residual gas from old storage cells without aspiration of the gas. The analysis of the results obtained revealed: (i) a high emission of VOCs, principally alcohols, ketones and esters during the acidogenesis; (ii) a decrease in the alkane content and an increase in the terpene content were observed in the VOCs emitted during the production of methane; (iii) the production of heavier alkanes and an increase in the average number of carbon

  17. Case studies in alternative landfill design

    SciTech Connect (OSTI)

    Barbagallo, J.C.; Druback, G.W.

    1995-12-31

    In the past, landfills or {open_quotes}dumps{close_quotes} were not highly regulated and typically did not require a detailed engineering design. However, landfills are no longer just holes in the ground, and landfill closures entail more than just spreading some dirt on top of piles of garbage. Today landfill design is a highly regulated, complex design effort that integrates soils and geosynthetics into systems aimed at providing long-term protection for the environment and surrounding communities. Integrating these complex design systems into the available landscape and exising landfill configuration often requires the designer go beyond the {open_quotes}typical{close_quotes} landfill and landfill closure design to satisfy regulations and provide cost-effective solutions.

  18. Estimating water content in an active landfill with the aid of GPR

    SciTech Connect (OSTI)

    Yochim, April, E-mail: ayochim@regionofwaterloo.ca [Region of Waterloo Waste Management Division, 925 Erb Street West, Waterloo, ON N2J 3Z4 (Canada); Zytner, Richard G., E-mail: rzytner@uoguelph.ca [School of Engineering, University of Guelph, Guelph, ON N1G 2W1 (Canada); McBean, Edward A., E-mail: emcbean@uoguelph.ca [School of Engineering, University of Guelph, Guelph, ON N1G 2W1 (Canada); Endres, Anthony L., E-mail: alendres@sciborg.uwaterloo.ca [Dept. of Earth and Environmental Sciences, University of Waterloo, Waterloo, ON N2L 3G1 (Canada)

    2013-10-15

    Highlights: Limited information in the literature on the use of GPR to measure in situ water content in a landfill. Developed GPR method allows measurement of in situ water content in a landfill. Developed GPR method is appealing to waste management professionals operating landfills. - Abstract: Landfill gas (LFG) receives a great deal of attention due to both negative and positive environmental impacts, global warming and a green energy source, respectively. However, predicting the quantity of LFG generated at a given landfill, whether active or closed is difficult due to the heterogeneities present in waste, and the lack of accurate in situ waste parameters like water content. Accordingly, ground penetrating radar (GPR) was evaluated as a tool for estimating in situ water content. Due to the large degree of subsurface heterogeneity and the electrically conductive clay cap covering landfills, both of which affect the transmission of the electromagnetic pulses, there is much scepticism concerning the use of GPR to quantify in situ water content within a municipal landfill. Two landfills were studied. The first landfill was used to develop the measurement protocols, while the second landfill provided a means of confirming these protocols. GPR measurements were initially completed using the surface GPR approach, but the lack of success led to the use of borehole (BH) GPR. Both zero offset profiling (ZOP) and multiple offset gathers (MOG) modes were tried, with the results indicating that BH GPR using the ZOP mode is the most simple and efficient method to measure in situ water content. The best results were obtained at a separation distance of 2 m, where higher the water content, smaller the effective separation distance. However, an increase in water content did appear to increase the accuracy of the GPR measurements. For the effective separation distance of 2 m at both landfills, the difference between GPR and lab measured water contents were reasonable at 33

  19. Alternative Fuels Data Center: DeKalb County Turns Trash to Gas

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    from landfill gas helps displace imported oil, makes good economic sense, and is good for ... "Processing natural gas from LFG helps displace imported oil, makes good economic sense, ...

  20. X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well

    SciTech Connect (OSTI)

    Kneafsey, T.J.; Rees, E.V.L.

    2010-03-01

    When maintained under hydrate-stable conditions, methane hydrate in laboratory samples is often considered a stable and immobile solid material. Currently, there do not appear to be any studies in which the long-term redistribution of hydrates in sediments has been investigated in the laboratory. These observations are important because if the location of hydrate in a sample were to change over time (e.g. by dissociating at one location and reforming at another), the properties of the sample that depend on hydrate saturation and pore space occupancy would also change. Observations of hydrate redistribution under stable conditions are also important in understanding natural hydrate deposits, as these may also change over time. The processes by which solid hydrate can move include dissociation, hydrate-former and water migration in the gas and liquid phases, and hydrate formation. Chemical potential gradients induced by temperature, pressure, and pore water or host sediment chemistry can drive these processes. A series of tests were performed on a formerly natural methane-hydrate-bearing core sample from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well, in order to observe hydrate formation and morphology within this natural sediment, and changes over time using X-ray computed tomography (CT). Long-term observations (over several weeks) of methane hydrate in natural sediments were made to investigate spatial changes in hydrate saturation in the core. During the test sequence, mild buffered thermal and pressure oscillations occurred within the sample in response to laboratory temperature changes. These oscillations were small in magnitude, and conditions were maintained well within the hydrate stability zone.

  1. Natural Gas Infrastructure Modernization | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Infrastructure Modernization Natural Gas Infrastructure Modernization A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy Department. A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy Department. In order to help modernize the nation's natural gas

  2. Landfill reduction experience in The Netherlands

    SciTech Connect (OSTI)

    Scharff, Heijo

    2014-11-15

    Highlights: • ‘Zero waste’ initiatives never consider risks, side effects or experience of achieved low levels of landfill. • This paper provides insight into what works and what not. • Where strong gradients in regulations and tax occur between countries, waste will find its way to landfills across borders. • Strong landfill reduction can create a fierce competition over the remaining waste to be landfilled resulting in losses. • At some point a public organisation should take responsibility for the operation of a ‘safety net’ in waste management. - Abstract: Modern waste legislation aims at resource efficiency and landfill reduction. This paper analyses more than 20 years of landfill reduction in the Netherlands. The combination of landfill regulations, landfill tax and landfill bans resulted in the desired landfill reduction, but also had negative effects. A fierce competition developed over the remaining waste to be landfilled. In 2013 the Dutch landfill industry generated €40 million of annual revenue, had €58 million annual costs and therefore incurred an annual loss of €18 million. It is not an attractive option to prematurely end business. There is a risk that Dutch landfill operators will not be able to fulfil the financial obligations for closure and aftercare. Contrary to the polluter pays principle the burden may end up with society. EU regulations prohibiting export of waste for disposal are in place. Strong differentials in landfill tax rate between nations have nevertheless resulted in transboundary shipment of waste and in non-compliance with the self-sufficiency and proximity principles. During the transformation from a disposal society to a recycling society, it is important to carefully plan required capacity and to guide the reorganisation of the landfill sector. At some point, it is no longer profitable to provide landfill services. It may be necessary for public organisations or the state to take responsibility for the

  3. EA-1707: Closure of Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill, Hanford Site, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the potential environmental impacts of closing the Nonradioactive Dangerous Waste Landfill and the Solid Waste Landfill. The Washington State Department of Ecology is a cooperating agency in preparing this EA.

  4. I 95 Landfill Phase II Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    I 95 Landfill Phase II Biomass Facility Jump to: navigation, search Name I 95 Landfill Phase II Biomass Facility Facility I 95 Landfill Phase II Sector Biomass Facility Type...

  5. Milliken Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    2006 Database Retrieved from "http:en.openei.orgwindex.php?titleMillikenLandfillBiomassFacility&oldid397777" Feedback Contact needs updating Image needs updating...

  6. Acme Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    NEEDS 2006 Database Retrieved from "http:en.openei.orgwindex.php?titleAcmeLandfillBiomassFacility&oldid397115" Feedback Contact needs updating Image needs updating...

  7. Colton Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    2006 Database Retrieved from "http:en.openei.orgwindex.php?titleColtonLandfillBiomassFacility&oldid397336" Feedback Contact needs updating Image needs updating...

  8. Girvin Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    2006 Database Retrieved from "http:en.openei.orgwindex.php?titleGirvinLandfillBiomassFacility&oldid397500" Feedback Contact needs updating Image needs updating...

  9. Methane Hydrate Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FY 2011 Methane Hydrate Program Report to Congress July 2012 United States Department of Energy Washington, DC 20585 Department of Energy | July 2012 FY 2011 Methane Hydrate Program Report to Congress | Page ii Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report entitled U.S. Department of Energy FY 2011 Methane

  10. CHP and Bioenergy Systems for Landfills and Wastewater Treatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems for Landfills and Wastewater Treatment Plants CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants There are important issues to consider when selecting ...

  11. CHP and Bioenergy for Landfills and Wastewater Treatment Plants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Landfills and Wastewater Treatment Plants: Market Opportunities CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market Opportunities This document explores ...

  12. DOE - Office of Legacy Management -- West Lake Landfill - MO...

    Office of Legacy Management (LM)

    Lake Landfill - MO 05 FUSRAP Considered Sites Site: West Lake Landfill (MO.05) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition:...

  13. Briefing: DOE EM ITR Landfill Assessment Project Lessons Learned...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ITR Landfill Assessment Project Lessons Learned Briefing: DOE EM ITR Landfill Assessment Project Lessons Learned By: Craig H. Benson, PhD, PE Where: EM SSAB Teleconference: 1 ...

  14. Modeling Analysis of Biosparging at the Sanitary Landfill (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Modeling Analysis of Biosparging at the Sanitary Landfill Citation Details In-Document Search Title: Modeling Analysis of Biosparging at the Sanitary Landfill ...

  15. Microsoft Word - Final TTR Landfill Extension EA--December 2006...

    National Nuclear Security Administration (NNSA)

    ... Once the landfill reaches capacity, sources of air pollution associated with the landfill would no longer be present. Waste transport vehicles would cause minor increases in car- ...

  16. Physical Properties of Gas Hydrates: A Review (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Physical Properties of Gas Hydrates: A Review Citation Details In-Document Search Title: Physical Properties of Gas Hydrates: A Review Methane gas hydrates in ...

  17. Physical Properties of Gas Hydrates: A Review (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Physical Properties of Gas Hydrates: A Review Citation Details In-Document Search Title: Physical Properties of Gas Hydrates: A Review Methane gas hydrates in sediments have been ...

  18. Data summary of municipal solid waste management alternatives. Volume 8, Appendix F, Landfills

    SciTech Connect (OSTI)

    1992-10-01

    While the preceding appendices have focused on the thermochemical approaches to managing municipal solid waste (MSW), this appendix and those that follow on composting and anaerobic digestion address more of the bioconversion process technologies. Landfilling is the historical baseline MSW management option central to every community`s solid waste management plan. It generally encompasses shredfills, balefills, landfill gas recovery, and landfill mining. While landfilling is virtually universal in use, it continues to undergo intense scrutiny by the public and regulators alike. Most recently, the US Environmental Protection Agency (EPA) issued its final rule on criteria for designing, operating, monitoring, and closing municipal solid waste landfills. While the Federal government has established nationwide standards and will assist the States in planning and developing their own practices, the States and local governments will carry out the actual planning and direct implementation. The States will also be authorized to devise programs to deal with their specific conditions and needs. While the main body of this appendix and corresponding research was originally prepared in July of 1991, references to the new RCRA Subtitle D, Part 258 EPA regulations have been included in this resubmission (908). By virtue of timing, this appendix is, necessarily, a ``transition`` document, combining basic landfill design and operation information as well as reference to new regulatory requirements. Given the speed with which landfill practices are and will be changing, the reader is encouraged to refer to Part 258 for additional details. As States set additional requirements and schedules and owners and operators of MSW landfills seek to comply, additional guidance and technical information, including case studies, will likely become available in the literature.

  19. Data Summary of Municipal Solid Waste Management Alternatives. Volume VIII: Appendix F - Landfills

    SciTech Connect (OSTI)

    1992-10-01

    While the preceding appendices have focused on the thermochemical approaches to managing municipal solid waste (MSW), this appendix and those that follow on composting and anaerobic digestion address more of the bioconversion process technologies. Landfilling is the historical baseline MSW management option central to every community's solid waste management plan. It generally encompasses shredfills, balefills, landfill gas recovery, and landfill mining. While landfilling is virtually universal in use, it continues to undergo intense scrutiny by the public and regulators alike. Most recently, the US Environmental Protection Agency (EPA) issued its final rule on criteria for designing, operating, monitoring, and closing municipal solid waste landfills. While the Federal government has established nationwide standards and will assist the States in planning and developing their own practices, the States and local governments will carry out the actual planning and direct implementation. The States will also be authorized to devise programs to deal with their specific conditions and needs. While the main body of this appendix and corresponding research was originally prepared in July of 1991, references to the new RCRA Subtitle D, Part 258 EPA regulations have been included in this resubmission (908). By virtue of timing, this appendix is, necessarily, a transition'' document, combining basic landfill design and operation information as well as reference to new regulatory requirements. Given the speed with which landfill practices are and will be changing, the reader is encouraged to refer to Part 258 for additional details. As States set additional requirements and schedules and owners and operators of MSW landfills seek to comply, additional guidance and technical information, including case studies, will likely become available in the literature.

  20. Knowledge based ranking algorithm for comparative assessment of post-closure care needs of closed landfills

    SciTech Connect (OSTI)

    Sizirici, Banu; Tansel, Berrin; Kumar, Vivek

    2011-06-15

    Post-closure care (PCC) activities at landfills include cap maintenance; water quality monitoring; maintenance and monitoring of the gas collection/control system, leachate collection system, groundwater monitoring wells, and surface water management system; and general site maintenance. The objective of this study was to develop an integrated data and knowledge based decision making tool for preliminary estimation of PCC needs at closed landfills. To develop the decision making tool, 11 categories of parameters were identified as critical areas which could affect future PCC needs. Each category was further analyzed by detailed questions which could be answered with limited data and knowledge about the site, its history, location, and site specific characteristics. Depending on the existing knowledge base, a score was assigned to each question (on a scale 1-10, as 1 being the best and 10 being the worst). Each category was also assigned a weight based on its relative importance on the site conditions and PCC needs. The overall landfill score was obtained from the total weighted sum attained. Based on the overall score, landfill conditions could be categorized as critical, acceptable, or good. Critical condition indicates that the landfill may be a threat to the human health and the environment and necessary steps should be taken. Acceptable condition indicates that the landfill is currently stable and the monitoring should be continued. Good condition indicates that the landfill is stable and the monitoring activities can be reduced in the future. The knowledge base algorithm was applied to two case study landfills for preliminary assessment of PCC performance.

  1. The environmental comparison of landfilling vs. incineration of MSW accounting for waste diversion

    SciTech Connect (OSTI)

    Assamoi, Bernadette; Lawryshyn, Yuri

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Residential waste diversion initiatives are more successful with organic waste. Black-Right-Pointing-Pointer Using a incineration to manage part of the waste is better environmentally. Black-Right-Pointing-Pointer Incineration leads to more power plant emission offsets. Black-Right-Pointing-Pointer Landfilling all of the waste would be preferred financially. - Abstract: This study evaluates the environmental performance and discounted costs of the incineration and landfilling of municipal solid waste that is ready for the final disposal while accounting for existing waste diversion initiatives, using the life cycle assessment (LCA) methodology. Parameters such as changing waste generation quantities, diversion rates and waste composition were also considered. Two scenarios were assessed in this study on how to treat the waste that remains after diversion. The first scenario is the status quo, where the entire residual waste was landfilled whereas in the second scenario approximately 50% of the residual waste was incinerated while the remainder is landfilled. Electricity was produced in each scenario. Data from the City of Toronto was used to undertake this study. Results showed that the waste diversion initiatives were more effective in reducing the organic portion of the waste, in turn, reducing the net electricity production of the landfill while increasing the net electricity production of the incinerator. Therefore, the scenario that incorporated incineration performed better environmentally and contributed overall to a significant reduction in greenhouse gas emissions because of the displacement of power plant emissions; however, at a noticeably higher cost. Although landfilling proves to be the better financial option, it is for the shorter term. The landfill option would require the need of a replacement landfill much sooner. The financial and environmental effects of this expenditure have yet to be considered.

  2. Bioconversion of methane to lactate by an obligate methanotrophic bacterium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Henard, Calvin A.; Smith, Holly; Dowe, Nancy; Kalyuzhnaya, Marina G.; Pienkos, Philip T.; Guarnieri, Michael T.

    2016-02-23

    Methane is the second most abundant greenhouse gas (GHG), with nearly 60% of emissions derived from anthropogenic sources. Microbial conversion of methane to fuels and value-added chemicals offers a means to reduce GHG emissions, while also valorizing this otherwise squandered high-volume, high-energy gas. However, to date, advances in methane biocatalysis have been constrained by the low-productivity and limited genetic tractability of natural methane-consuming microbes. Here, leveraging recent identification of a novel, tractable methanotrophic bacterium, Methylomicrobium buryatense, we demonstrate microbial biocatalysis of methane to lactate, an industrial platform chemical. Heterologous overexpression of a Lactobacillus helveticus L-lactate dehydrogenase in M. buryatense resultedmore » in an initial titer of 0.06 g lactate/L from methane. Cultivation in a 5 L continuously stirred tank bioreactor enabled production of 0.8 g lactate/L, representing a 13-fold improvement compared to the initial titer. The yields (0.05 g lactate/g methane) and productivity (0.008 g lactate/L/h) indicate the need and opportunity for future strain improvement. Additionally, real-time analysis of methane utilization implicated gas-to-liquid transfer and/or microbial methane consumption as process limitations. This work opens the door to develop an array of methanotrophic bacterial strain-engineering strategies currently employed for biocatalytic sugar upgrading to “green” chemicals and fuels.« less

  3. Top-down estimate of methane emissions in California using a mesoscale inverse modeling technique: The South Coast Air Basin

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cui, Yu Yan; Brioude, Jerome; McKeen, Stuart A.; Angevine, Wayne M.; Kim, Si -Wan; Frost, Gregory J.; Ahmadov, Ravan; Peischl, Jeff; Bousserez, Nicolas; Liu, Zhen; et al

    2015-07-28

    Methane (CH4) is the primary component of natural gas and has a larger global warming potential than CO2. Some recent top-down studies based on observations showed CH4 emissions in California's South Coast Air Basin (SoCAB) were greater than those expected from population-apportioned bottom-up state inventories. In this study, we quantify CH4 emissions with an advanced mesoscale inverse modeling system at a resolution of 8 km × 8 km, using aircraft measurements in the SoCAB during the 2010 Nexus of Air Quality and Climate Change campaign to constrain the inversion. To simulate atmospheric transport, we use the FLEXible PARTicle-Weather Research andmore » Forecasting (FLEXPART-WRF) Lagrangian particle dispersion model driven by three configurations of the Weather Research and Forecasting (WRF) mesoscale model. We determine surface fluxes of CH4 using a Bayesian least squares method in a four-dimensional inversion. Simulated CH4 concentrations with the posterior emission inventory achieve much better correlations with the measurements (R2 = 0.7) than using the prior inventory (U.S. Environmental Protection Agency's National Emission Inventory 2005, R2 = 0.5). The emission estimates for CH4 in the posterior, 46.3 ± 9.2 Mg CH4/h, are consistent with published observation-based estimates. Changes in the spatial distribution of CH4 emissions in the SoCAB between the prior and posterior inventories are discussed. Missing or underestimated emissions from dairies, the oil/gas system, and landfills in the SoCAB seem to explain the differences between the prior and posterior inventories. Furthermore, we estimate that dairies contributed 5.9 ± 1.7 Mg CH4/h and the two sectors of oil and gas industries (production and downstream) and landfills together contributed 39.6 ± 8.1 Mg CH4/h in the SoCAB.« less

  4. Method for removal of methane from coalbeds

    DOE Patents [OSTI]

    Pasini, III, Joseph; Overbey, Jr., William K.

    1976-01-01

    A method for removing methane gas from underground coalbeds prior to mining the coal which comprises drilling at least one borehole from the surface into the coalbed. The borehole is started at a slant rather than directly vertically, and as it descends, a gradual curve is followed until a horizontal position is reached where the desired portion of the coalbed is intersected. Approaching the coalbed in this manner and fracturing the coalbed in the major natural fraction direction cause release of large amounts of the trapped methane gas.

  5. Lantana landfill: A history of environmental management 1965--96

    SciTech Connect (OSTI)

    Statom, R.A.

    1997-08-01

    The Lantana Sanitary Landfill (LSL) is located in central Palm Beach County, Florida. The history of this landfill is a case study of the changes in environmental law, demography, solid waste management, hydrogeology, and public opinion in south Florida in the last 30 years. In 1983 Palm Beach County transferred ownership of the LSL to the Palm Beach County Solid Waste Authority (SWA). Environmental regulation enacted by Florida in the mid 1980`s resulted in negotiations to close the LSL. Closure was completed in 1988 utilizing a synthetic top liner, a landfill gas extraction/flare system, and a stormwater management system. In 1990 a groundwater mitigation system was installed to remediate the eastern plume. Closure of the LSL, extension of municipal water to local residents, and extensive public education by the SWA all served to answer most of the complaints of the local residents. In 1996 the LSL fell under a new series of air regulations and was required to apply for a Title V permit.

  6. Upgraded biogas from municipal solid waste for natural gas substitution and CO{sub 2} reduction – A case study of Austria, Italy, and Spain

    SciTech Connect (OSTI)

    Starr, Katherine; Villalba, Gara; Gabarrell, Xavier

    2015-04-15

    Highlights: • Biogas can be upgraded to create biomethane, a substitute to natural gas. • Biogas upgrading was applied to landfills and anaerobic digestors in 3 countries. • Up to 0.6% of a country’s consumption of natural gas could be replaced by biomethane. • Italy could save 46% of the national CO{sub 2} emissions attributed to the waste sector. • Scenarios were created to increase biomethane production. - Abstract: Biogas is rich in methane and can be further purified through biogas upgrading technologies, presenting a viable alternative to natural gas. Landfills and anaerobic digestors treating municipal solid waste are a large source of such biogas. They therefore offer an attractive opportunity to tap into this potential source of natural gas while at the same time minimizing the global warming impact resulting from methane emissions in waste management schemes (WMS) and fossil fuel consumption reduction. This study looks at the current municipal solid waste flows of Spain, Italy, and Austria over one year (2009), in order to determine how much biogas is generated. Then it examines how much natural gas could be substituted by using four different biogas upgrading technologies. Based on current waste generation rates, exploratory but realistic WMS were created for each country in order to maximize biogas production and potential for natural gas substitution. It was found that the potential substitution of natural gas by biogas resulting from the current WMS seems rather insignificant: 0.2% for Austria, 0.6% for Italy and 0.3% for Spain. However, if the WMS is redesigned to maximize biogas production, these figures can increase to 0.7% for Austria, 1% for Italy and 2% for Spain. Furthermore, the potential CO{sub 2} reduction as a consequence of capturing the biogas and replacing fossil fuel can result in up to a 93% reduction of the annual national waste greenhouse gas emissions of Spain and Italy.

  7. Presentations from June 6-7 2013 Methane Hydrates Advisory Meeting |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy June 6-7 2013 Methane Hydrates Advisory Meeting Presentations from June 6-7 2013 Methane Hydrates Advisory Meeting ConocoPhillips test results and data analysis (8.24 MB) Methane Hydrate Workshop as part of the FY 2013 Methane Hydrate Field Program (904.56 KB) Methane Hydrates Advisory Committee Meeting: Program Funding (292.15 KB) Update on BOEM Lower 48 Assessment: A presentation to the Methane Hydrate Advisory Committee (9.13 MB) Gas Hydrate Program Activities in

  8. U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies

    Broader source: Energy.gov [DOE]

    Methane Hydrates May Exceed the Energy Content of All Other Fossil Fuels Combined; Could Ensure Decades of Affordable Natural Gas and Cut America’s Foreign Oil Dependence

  9. UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION

    SciTech Connect (OSTI)

    Anna Lee Tonkovich

    2004-01-01

    The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the feasibility of upgrading low-Btu methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys' modular microchannel process technology. The project is on schedule and under budget. For Task 1.1, the open literature, patent information, and vendor contacts were surveyed to identify adsorbent candidates for experimental validation and subsequent demonstration in an MPT-based ultra-fast TSA separation for methane upgrading. The leading candidates for preferential adsorption of methane over nitrogen are highly microporous carbons. A Molecular Gate{trademark} zeolite from Engelhard Corporation has emerged as a candidate. For Task 1.2, experimental evaluation of adsorbents was initiated, and data were collected on carbon (MGN-101) from PICA, Inc. This carbon demonstrated a preferential capacity for methane over nitrogen, as well as a reasonable thermal swing differential capacity for a 90% methane and 10% nitrogen mixture. A similar methane swing capacity at 2 psig was measured. The mixture composition is relevant because gob gas contains nearly 85% methane and must be purified to 97% methane for pipeline quality.

  10. Sorption-enhanced synthetic natural gas (SNG) production from...

    Office of Scientific and Technical Information (OSTI)

    A novel process combining CO methanation, water-gas shift, and CO2 capture Citation ... A novel process combining CO methanation, water-gas shift, and CO2 capture Authors: ...

  11. Methane Hydrate Field Program

    SciTech Connect (OSTI)

    2013-12-31

    This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. • Historical Methane Hydrate Project Review Report • Methane Hydrate Workshop Report • Topical Report: Marine Methane Hydrate Field Research Plan • Final Scientific/Technical Report

  12. Methane Hydrate R&D | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    R&D Methane Hydrate R&D Natural gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of Fossil Energy has played a major role in developing technologies to help tap new, unconventional sources of natural gas. Fossil Energy Research Benefits - Methane Hydrate (1.01 MB) More Documents & Publications Idaho Operations AMWTP Fact Sheet Greenpower Trap Mufflerl System CERTIFIED REALTY SPECIALIST

  13. Generating power with drained coal mine methane

    SciTech Connect (OSTI)

    2005-09-01

    The article describes the three technologies most commonly used for generating electricity from coal mine methane: internal combustion engines, gas turbines, and microturbines. The most critical characteristics and features of these technologies, such as efficiency, output and size are highlighted. 5 refs.

  14. Prometheus Energy Inc | Open Energy Information

    Open Energy Info (EERE)

    to convert waste gas - eg landfill gas, coal mine methane - into usable compressed liquid natural gas. Coordinates: 47.67856, -122.130994 Show Map Loading map......

  15. Recent federal initiatives to promote unconventional gas: High octane delivery of just hot air?

    SciTech Connect (OSTI)

    Griff, M.T.

    1995-10-01

    This paper provides an overview of recent initiatives of the United States which promote greater use of natural gas and unconventional gas as one part of this nations`s larger response to the global warming threat. Measurable increases in greenhouse gas concentrations since the beginning of the industrial revolution have led to the belief in the existence of a global warming problem. The international community has responded to the global warming threat with the United Nations Framework Convention on Climate Change which is directed toward the stabilization of greenhouse gases in the atmosphere. The Climate Change Action Plan is the Clinton Administration`s detailed response to the global warming threat. It is designed to return United States emissions of greenhouse gases to their 1990 levels by the year 2000. The Action Plan targets all greenhouse gases and emphasizes energy efficiency. Significant regulatory reformation designed to increase the efficiency of the natural gas industry has already occurred and will be continued. Recovery of methane emissions from landfills will be encouraged through indentification of suitable sites and use of existing technology and development of new technology. Recovery of methane from coal mining operations will be promoted by targeting 50 of the gassiest mines in the United States. Even if the Action Plan is fully implemented. legitimate questions arise as to whether its goals will be achieved as a result of funding shortfalls.

  16. Methane Hydrate Field Studies

    Broader source: Energy.gov [DOE]

    Since 2001, DOE has conducted field trials of exploration and production technology in the Alaska North Slope. Although Alaska methane hydrate resources are smaller than marine deposits and...

  17. Enhanced carbon monoxide utilization in methanation process

    DOE Patents [OSTI]

    Elek, Louis F.; Frost, Albert C.

    1984-01-01

    Carbon monoxide - containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is subsequently reacted with steam or hydrogen to form methane. Surprisingly, hydrogen and water vapor present in the feed gas do not adversely affect CO utilization significantly, and such hydrogen actually results in a significant increase in CO utilization.

  18. Waste management health risk assessment: A case study of a solid waste landfill in South Italy

    SciTech Connect (OSTI)

    Davoli, E.; Fattore, E.; Paiano, V.; Colombo, A.; Palmiotto, M.; Rossi, A.N.; Il Grande, M.; Fanelli, R.

    2010-08-15

    An integrated risk assessment study has been performed in an area within 5 km from a landfill that accepts non hazardous waste. The risk assessment was based on measured emissions and maximum chronic population exposure, for both children and adults, to contaminated air, some foods and soil. The toxic effects assessed were limited to the main known carcinogenic compounds emitted from landfills coming both from landfill gas torch combustion (e.g., dioxins, furans and polycyclic aromatic hydrocarbons, PAHs) and from diffusive emissions (vinyl chloride monomer, VCM). Risk assessment has been performed both for carcinogenic and non-carcinogenic effects. Results indicate that cancer and non-cancer effects risk (hazard index, HI) are largely below the values accepted from the main international agencies (e.g., WHO, US EPA) and national legislation ( and ).

  19. Instrumentation of dredge spoil for landfill construction

    SciTech Connect (OSTI)

    Byle, M.J.; McCullough, M.L.; Alexander, R.; Vasuki, N.C.; Langer, J.A.

    1999-07-01

    The Delaware Solid Waste Authority's Northern Solid Waste Management Center is located outside of Wilmington Delaware at Cherry Island, a former dredge disposal site. Dredge spoils, of very low permeability, range in depths up to 30 m (100 feet) which form a natural liner and the foundation for the 140 ha (350-acre) municipal solid waste landfill. The soils beneath the landfill have been extensively instrumented to measure pore pressure, settlement and deflections, using inclinometer casings, standpipe piezometers, vibrating wire piezometers, pneumatic piezometers, settlement plates, liquid settlement gages, total pressure cells and thermistors. The nature of the existing waste and anticipated settlements (up to 6 m (19 feet)) have required some unique installation details. The instrumentation data has been integral in planning the landfilling sequence to maintain perimeter slope stability and has provided key geotechnical parameters needed for operation and construction of the landfill. The performance of the instrumentation and monitoring results are discussed.

  20. Methane activation using noble gases in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon

    2013-08-15

    The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gasesHe, Ne, and Aras additives. The empirical results obtained clearly indicate that methane activation is considerably affected by thy type of noble gas used. Through 0-D calculations, the discharge parameters inside the reactor, i.e., electron temperature and electron density, are estimated using experiment results. A comparison of the discharge characteristics and experimental results shows that the electron temperature is an important factor in achieving high methane activation and the mixture with Ar gas shows the highest methane conversion. These results are constructed using the mechanisms of energy and charge transfer from excited and ionized noble gas atoms to methane molecules, considering the number density of active atoms of noble gases. Finally, electron temperatures obtained for gas mixtures having different reactant compositions and concentrations are analyzed to estimate methane activation.

  1. Production of methane by anaerobic fermentation of waste materials

    SciTech Connect (OSTI)

    Hitzman, D.O.

    1989-01-17

    This patent describes an apparatus for producing methane by anaerobic fermentation of waste material, comprising: cavity means in the earth for holding a quantity of the waste material; means for covering a quantity of the waste material in the cavity means and thereby separating the quantity of the waste material from the atmosphere; first conduit means communicating between the waste material in the cavity means and a location remote from the cavity means for conveying gas comprising carbon dioxide and methane from the cavity means to the location; gas separation means communicating with the first conduit means at the location for separating carbon dioxide from methane, the first conduit means including at least one pipe having a plurality of apertures therein and disposed in the cavity means extending into and in fluid flow communication with the waste material for receiving gas liberated by the anaerobic fermentation of the waste material and comprising carbon dioxide and methane, through the apertures therein for conveyance via the first conduit means to the gas separation means; second conduit means communicating between the gas separation means and the waste material in the cavity means for conveying carbon dioxide from the gas separation means to the waste material; and third conduit means communicating with the gas separation means for conveying methane from the gas separation means.

  2. Landfill aeration worldwide: Concepts, indications and findings

    SciTech Connect (OSTI)

    Ritzkowski, M.; Stegmann, R.

    2012-07-15

    Highlights: Black-Right-Pointing-Pointer Different landfill aeration concepts and accordant application areas are described. Black-Right-Pointing-Pointer Examples of full scale projects are provided for Europe, North-America and Asia. Black-Right-Pointing-Pointer Major project findings are summarised, including prospects and limitations. Black-Right-Pointing-Pointer Inconsistencies between laboratory and full scale results have been elaborated. Black-Right-Pointing-Pointer An explanatory approach in connection with the inconsistencies is provided. - Abstract: The creation of sustainable landfills is a fundamental goal in waste management worldwide. In this connection landfill aeration contributes towards an accelerated, controlled and sustainable conversion of conventional anaerobic landfills into a biological stabilized state associated with a minimised emission potential. The technology has been successfully applied to landfills in Europe, North America and Asia, following different strategies depending on the geographical region, the specific legislation and the available financial resources. Furthermore, methodologies for the incorporation of landfill aeration into the carbon trade mechanisms have been developed in recent years. This manuscript gives an overview on existing concepts for landfill aeration; their application ranges and specifications. For all of the described concepts examples from different countries worldwide are provided, including details regarding their potentials and limitations. Some of the most important findings from these aeration projects are summarised and future research needs have been identified. It becomes apparent that there is a great demand for a systematisation of the available results and implications in order to further develop and optimise this very promising technology. The IWWG (International Waste Working Group) Task Group 'Landfill Aeration' contributes towards the achievement of this goal.

  3. Photovoltaics on Landfills in Puerto Rico

    SciTech Connect (OSTI)

    Salasovich, J.; Mosey, G.

    2011-01-01

    The U.S. Environmental Protection Agency (EPA), in accordance with the RE-Powering America's Land initiative, selected the Commonwealth of Puerto Rico for a feasibility study of m0treAlables on several brownfield sites. The EPA defines a brownfield as 'a property, the expansion, redevelopment, or reuse of which may be complicated by the presence or potential presence of a hazardous substance, pollutant, or contaminant.' All of the brownfields in this study are landfill sites. Citizens of Puerto Rico, city planners, and site managers are interested in redevelopment uses for landfills in Puerto Rico, which are particularly well suited for solar photovoltaic (PV) installation. The purpose of this report is to assess the landfills with the highest potential for possible solar PV installation and estimate cost, performance, and site impacts of three different PV options: crystalline silicon (fixed-tilt), crystalline silicon (single-axis tracking), and thin film (fixed-tilt). Each option represents a standalone system that can be sized to use an entire available site area. In addition, the report outlines financing options that could assist in the implementation of a system. The feasibility of PV systems installed on landfills is highly impacted by the available area for an array, solar resource, operating status, landfill cap status, distance to transmission lines, and distance to major roads. All of the landfills in Puerto Rico were screened according to these criteria in order to determine the sites with the greatest potential. Eight landfills were chosen for site visits based on the screening criteria and location. Because of time constraints and the fact that Puerto Rico is a relatively large island, the eight landfills for this visit were all located in the eastern half of the island. The findings from this report can be applied to landfills in the western half of the island. The economics of a potential PV system on landfills in Puerto Rico depend greatly on the

  4. Methane activation using Kr and Xe in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Lee, Dae Hoon Kim, Kwan-Tae; Kang, Woo Seok; Song, Young-Hoon

    2014-10-15

    Methane has interested many researchers as a possible new energy source, but the high stability of methane causes a bottleneck in methane activation, limiting its practical utilization. To determine how to effectively activate methane using non-thermal plasma, the conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gases—Ar, Kr, and Xe—as additives. In addition to the methane conversion results at various applied voltages, the discharge characteristics such as electron temperature and electron density were calculated through zero-dimensional calculations. Moreover, the threshold energies of excitation and ionization were used to distinguish the dominant particle for activating methane between electrons, excited atoms, and ionized atoms. From the experiments and calculations, the selection of the additive noble gas is found to affect not only the conversion of methane but also the selectivity of product gases even under similar electron temperature and electron density conditions.

  5. Microbial diversity and dynamics during methane production from municipal solid waste

    SciTech Connect (OSTI)

    Bareither, Christopher A.; Wolfe, Georgia L.; McMahon, Katherine D.; Benson, Craig H.

    2013-10-15

    Highlights: ► Similar bacterial communities developed following different start-up operation. ► Total methanogens in leachate during the decelerated methane phase reflected overall methane yield. ► Created correlations between methanogens, methane yield, and available substrate. ► Predominant bacteria identified with syntrophic polysaccharide degraders. ► Hydrogenotrophic methanogens were dominant in the methane generation process. - Abstract: The objectives of this study were to characterize development of bacterial and archaeal populations during biodegradation of municipal solid waste (MSW) and to link specific methanogens to methane generation. Experiments were conducted in three 0.61-m-diameter by 0.90-m-tall laboratory reactors to simulate MSW bioreactor landfills. Pyrosequencing of 16S rRNA genes was used to characterize microbial communities in both leachate and solid waste. Microbial assemblages in effluent leachate were similar between reactors during peak methane generation. Specific groups within the Bacteroidetes and Thermatogae phyla were present in all samples and were particularly abundant during peak methane generation. Microbial communities were not similar in leachate and solid fractions assayed at the end of reactor operation; solid waste contained a more abundant bacterial community of cellulose-degrading organisms (e.g., Firmicutes). Specific methanogen populations were assessed using quantitative polymerase chain reaction. Methanomicrobiales, Methanosarcinaceae, and Methanobacteriales were the predominant methanogens in all reactors, with Methanomicrobiales consistently the most abundant. Methanogen growth phases coincided with accelerated methane production, and cumulative methane yield increased with increasing total methanogen abundance. The difference in methanogen populations and corresponding methane yield is attributed to different initial cellulose and hemicellulose contents of the MSW. Higher initial cellulose and

  6. Preliminary assessment of numerical data requirements TA-73 landfill Los Alamos, New Mexico

    SciTech Connect (OSTI)

    Not Available

    1993-11-19

    A numerical model, TOUGH2, was selected for describing liquid- and gas-phase flow in the unsaturated tuff underlying the TA-73 landfill. The model was selected primarily for its ability to simulate the significant mechanisms that may affect transport of contaminants through the vadose zone at the TA-73 landfill, including non-isothermal flow through fractured media. TOUGH2 is the best documented, verified, and validated model capable of performing the required simulations. The sensitivity analyses that were performed and describes in this report identified the input parameters that the selected numerical model is most sensitive to. The input parameters analyzed were saturated hydraulic conductivity, van Genuchten {alpha} and n, residual and saturated moisture contents, infiltration rate, fracture spacing and permeability, atmospheric pressure, and temperature. The sensitivity analyses were performed using a model grid that was designed to incorporate the regions in the landfill vicinity where contaminant transport is likely to occur and where the physical processes affecting flow and transport are the most dynamic. The sensitivity analyses performed suggest that the model is quite sensitive to a number of input parameters, including saturated hydraulic conductivity, the van Genuchten parameters {alpha} and n (for both the tuff matrix and fractures), fracture density and aperture, and atmospheric pressure. The results indicate that additional site-specific hydraulic properties and fracture data should be obtained before attempting to perform predictive, numerical simulations of gas- and liquid-phase flow beneath the landfill.

  7. Oil and Gas Announcements Archive | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil and Gas Announcements Archive The December, 2015 Issue of the Methane Hydrate ... that Utica Shale could hold far more natural gas and oil than previously estimated. ...

  8. Shale Gas Application in Hydraulic Fracturing Market is likely...

    Open Energy Info (EERE)

    on unconventional reservoirs such as coal bed methane, tight gas, tight oil, shale gas, and shale oil. Over the period of time, hydraulic fracturing technique has found...

  9. Methane production from grape skins. Final technical report

    SciTech Connect (OSTI)

    Yunghans, W.N.

    1981-10-09

    Methane production from grape pomace was measured for a 50-day digestion period. Gas production was calculated to be 2400 ft/sup 3//10 d/ton at 53% methane content. Microorganisms particularly a fungus which grows on grape pomace and lignin was isolated. Lignin content of pomace was measured at approximately 60%. Lignin is slowly digested and may represent a residue which requires long term digestion. Research is continuing on isolation of anaerobic methane bacteria and codigestion of pomace with enzymes as cellulase and pectinase. The sewage sludge functioned adequately as a mixed source of organisms capable of digesting grape pomace. A sediment from stored grape juice produced significant amounts of methane and represents a nutrient substrate for additional studies on continuous flow methane production. 3 figs.

  10. Treatment of municipal landfill leachate using a combined anaerobic digester and activated sludge system

    SciTech Connect (OSTI)

    Kheradmand, S.; Karimi-Jashni, A.; Sartaj, M.

    2010-06-15

    The main objective of this study was to assess the feasibility of treating sanitary landfill leachate using a combined anaerobic and activated sludge system. A high-strength leachate from Shiraz municipal landfill site was treated using this system. A two-stage laboratory-scale anaerobic digester under mesophilic conditions and an activated sludge unit were used. Landfill leachate composition and characteristics varied considerably during 8 months experiment (COD concentrations of 48,552-62,150 mg/L). It was found that the system could reduce the COD of the leachate by 94% at a loading rate of 2.25 g COD/L/d and 93% at loading rate of 3.37 g COD/L/d. The anaerobic digester treatment was quite effective in removing Fe, Cu, Mn, and Ni. However, in the case of Zn, removal efficiency was about 50%. For the rest of the HMs the removal efficiencies were in the range 88.8-99.9%. Ammonia reduction did not occur in anaerobic digesters. Anaerobic reactors increased alkalinity about 3.2-4.8% in the 1st digester and 1.8-7.9% in the 2nd digester. In activated sludge unit, alkalinity and ammonia removal efficiency were 49-60% and 48.6-64.7%, respectively. Methane production rate was in the range of 0.02-0.04, 0.04-0.07, and 0.02-0.04 L/g COD{sub rem} for the 1st digester, the 2nd digester, and combination of both digesters, respectively; the methane content of the biogas varied between 60% and 63%.

  11. Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water

    SciTech Connect (OSTI)

    Song Jin

    2007-05-31

    Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

  12. Support EM LA Airport Landfill Cover Project by providing 40000...

    Office of Environmental Management (EM)

    Support EM LA Airport Landfill Cover Project by providing 40000 tons of soil Support EM LA Airport Landfill Cover Project by providing 40000 tons of soil DE-DT0010454-Task-Order-4 ...

  13. Exploiting coalbed methane and protecting the global environment

    SciTech Connect (OSTI)

    Yuheng, Gao

    1996-12-31

    The global climate change caused by greenhouse gases (GHGs) emission has received wide attention from all countries in the world. Global environmental protection as a common problem has confronted the human being. As a main component of coalbed methane, methane is an important factor influencing the production safety of coal mine and threatens the lives of miners. The recent research on environment science shows that methane is a very harmful GHG. Although methane gas has very little proportion in the GHGs emission and its stayed period is also very short, it has very obvious impact on the climate change. From the estimation, methane emission in the coal-mining process is only 10% of the total emission from human`s activities. As a clean energy, Methane has mature recovery technique before, during and after the process of mining. Thus, coalbed methane is the sole GHG generated in the human`s activities and being possible to be reclaimed and utilized. Compared with the global greenhouse effect of other GHGs emission abatement, coalbed methane emission abatement can be done in very low cost with many other benefits: (1) to protect global environment; (2) to improve obviously the safety of coal mine; and (3) to obtain a new kind of clean energy. Coal is the main energy in China, and coalbed contains very rich methane. According to the exploration result in recent years, about 30000{approximately}35000 billion m{sup 2} methane is contained in the coalbed below 2000 m in depth. China has formed a good development base in the field of reclamation and utilization of coalbed methane. The author hopes that wider international technical exchange and cooperation in the field will be carried out.

  14. Landfill Cover Revegetation at the Rocky Flats Environmental Technology

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Site | Department of Energy Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site (507.34 KB) More Documents & Publications Revegetation of the Rocky Flats Site Smooth Brome Monitoring at Rocky Flats-2005 Results EIS-0285-SA-134:

  15. CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities | Department of Energy for Landfills and Wastewater Treatment Plants: Market Opportunities CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market Opportunities This document explores opportunities for alternative CHP fuels. CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market Opportunities (November 2007) (342.09 KB) More Documents & Publications CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants Barriers to CHP with

  16. Science on the Hill: Methane cloud hunting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane cloud hunting Science on the Hill: Methane cloud hunting Los Alamos researchers go ... Science on the Hill: Methane cloud hunting When our team from Los Alamos National ...

  17. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting Minutes May 15, 2014 Washington, DC...

  18. Methane Hydrate Program Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Reports Methane Hydrate Program Reports PDF icon Secretary of Energy Advisory Board Task Force Report on Methane Hydrate PDF icon FY14 Methane Hydrate Report to Congress ...

  19. ARM - Measurement - Methane flux

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    flux ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Methane flux Vertical flux of methane near the surface due to turbulent transport. Categories Surface Properties, Atmospheric Carbon Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including

  20. Enhanced Microbial Pathways for Methane Production from Oil Shale

    SciTech Connect (OSTI)

    Paul Fallgren

    2009-02-15

    Methane from oil shale can potentially provide a significant contribution to natural gas industry, and it may be possible to increase and continue methane production by artificially enhancing methanogenic activity through the addition of various substrate and nutrient treatments. Western Research Institute in conjunction with Pick & Shovel Inc. and the U.S. Department of Energy conducted microcosm and scaled-up reactor studies to investigate the feasibility and optimization of biogenic methane production from oil shale. The microcosm study involving crushed oil shale showed the highest yield of methane was produced from oil shale pretreated with a basic solution and treated with nutrients. Incubation at 30 C, which is the estimated temperature in the subsurface where the oil shale originated, caused and increase in methane production. The methane production eventually decreased when pH of the system was above 9.00. In the scaled-up reactor study, pretreatment of the oil shale with a basic solution, nutrient enhancements, incubation at 30 C, and maintaining pH at circumneutral levels yielded the highest rate of biogenic methane production. From this study, the annual biogenic methane production rate was determined to be as high as 6042 cu. ft/ton oil shale.

  1. US EPA record of decision review for landfills: Sanitary landfill (740-G), Savannah River Site

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    This report presents the results of a review of the US Environmental Protection Agency (EPA) Record of Decision System (RODS) database search conducted to identify Superfund landfill sites where a Record of Decision (ROD) has been prepared by EPA, the States or the US Army Corps of Engineers describing the selected remedy at the site. ROD abstracts from the database were reviewed to identify site information including site type, contaminants of concern, components of the selected remedy, and cleanup goals. Only RODs from landfill sites were evaluated so that the results of the analysis can be used to support the remedy selection process for the Sanitary Landfill at the Savannah River Site (SRS).

  2. DOE/BNL Liquid Natural Gas Heavy Vehicle Program

    SciTech Connect (OSTI)

    James E. Wegrzyn; Wai-Lin Litzke; Michael Gurevich

    1998-08-11

    As a means of lowering greenhouse gas emissions, increasing economic growth, and reducing the dependency on imported oil, the Department of Energy and Brookhaven National Laboratory (DOE/ BNL) is promoting the substitution of liquefied natural gas (LNG) in heavy-vehicles that are currently being fueled by diesel. Heavy vehicles are defined as Class 7 and 8 trucks (> 118,000 pounds GVVV), and transit buses that have a fuel usage greater than 10,000 gallons per year and driving range of more than 300 miles. The key in making LNG market-competitive with all types of diesel fuels is in improving energy efficiency and reducing costs of LNG technologies through systems integration. This paper integrates together the three LNG technologies of: (1) production from landfills and remote well sites; (2) cryogenic fuel delivery systems; and (3) state-of-the-art storage tank and refueling facilities, with market end-use strategies. The program's goal is to develop these technologies and strategies under a ''green'' and ''clean'' strategy. This ''green'' approach reduces the net contribution of global warming gases by reducing levels of methane and carbon dioxide released by heavy vehicles usage to below recoverable amounts of natural gas from landfills and other natural resources. Clean technology refers to efficient use of energy with low environmental emissions. The objective of the program is to promote fuel competition by having LNG priced between $0.40 - $0.50 per gallon with a combined production, fuel delivery and engine systems efficiency approaching 45%. This can make LNG a viable alternative to diesel.

  3. Methane recovery from animal manures: A current opportunities casebook

    SciTech Connect (OSTI)

    1995-08-01

    This Casebook examines some of the current opportunities for the recovery of methane from the anaerobic digestion of animal manures US livestock operations currently employ four types of anaerobic digester technology: Slurry, plug flow, complete mix, and covered lagoon. An introduction to the engineering economies of these technologies is provided, and possible end-use applications for the methane gas generated by the digestion process are discussed. The economic evaluations are based on engineering studies of digesters that generate electricity from the recovered methane. Regression models, which can be used to estimate digester cost and internal rate of return, are developed from the evaluations.

  4. Landfill stabilization focus area: Technology summary

    SciTech Connect (OSTI)

    1995-06-01

    Landfills within the DOE Complex as of 1990 are estimated to contain 3 million cubic meters of buried waste. The DOE facilities where the waste is predominantly located are at Hanford, the Savannah River Site (SRS), the Idaho National Engineering Laboratory (INEL), the Los Alamos National Laboratory (LANL), the Oak Ridge Reservation (ORR), the Nevada Test Site (NTS), and the Rocky Flats Plant (RFP). Landfills include buried waste, whether on pads or in trenches, sumps, ponds, pits, cribs, heaps and piles, auger holes, caissons, and sanitary landfills. Approximately half of all DOE buried waste was disposed of before 1970. Disposal regulations at that time permitted the commingling of various types of waste (i.e., transuranic, low-level radioactive, hazardous). As a result, much of the buried waste throughout the DOE Complex is presently believed to be contaminated with both hazardous and radioactive materials. DOE buried waste typically includes transuranic-contaminated radioactive waste (TRU), low-level radioactive waste (LLW), hazardous waste per 40 CFR 26 1, greater-than-class-C waste per CFR 61 55 (GTCC), mixed TRU waste, and mixed LLW. The mission of the Landfill Stabilization Focus Area is to develop, demonstrate, and deliver safer,more cost-effective and efficient technologies which satisfy DOE site needs for the remediation and management of landfills. The LSFA is structured into five technology areas to meet the landfill remediation and management needs across the DOE complex. These technology areas are: assessment, retrieval, treatment, containment, and stabilization. Technical tasks in each of these areas are reviewed.

  5. NREL Research Helps Convert Overabundant Methane into Useful Products |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioenergy | NREL Research Helps Convert Overabundant Methane into Useful Products March 18, 2016 Photo of a fermentation vessel cultivating our bacteria to produce lactic acid. Using fermentation vessels such as the one pictured here, NREL researchers have discovered how to cultivate genetically engineered methanotrophic bacteria to produce lactic acid, a high-value precursor to bioplastics. Photo by Holly Smith, NREL Methane is Earth's second most abundant greenhouse gas (GHG) after carbon

  6. NREL Research Helps Convert Overabundant Methane into Useful Products -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News Releases | NREL Research Helps Convert Overabundant Methane into Useful Products March 18, 2016 Photo of a fermentation vessel cultivating our bacteria to produce lactic acid. Using fermentation vessels such as the one pictured here, NREL researchers have discovered how to cultivate genetically engineered methanotrophic bacteria to produce lactic acid, a high-value precursor to bioplastics. Photo by Holly Smith, NREL Methane is Earth's second most abundant greenhouse gas (GHG) after

  7. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, K.

    1997-07-15

    A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

  8. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid

    1997-01-01

    A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

  9. Ownership questions can stymie development of coalbed methane

    SciTech Connect (OSTI)

    Counts, R.A. )

    1990-01-01

    Although the technology exists for commercial recovery of coalbed methane, production has been hindered because of the legal quandary as to ownership. The author discusses how claims to ownership of coalbed methane can and have been made by the coal owner or lessee, the oil and gas owner or lessee, the surface owner, or any combination thereof. The federal perspective on this question of ownership is described and several state rulings are assessed.

  10. Method of determining methane and electrochemical sensor therefor

    DOE Patents [OSTI]

    Zaromb, Solomon; Otagawa, Takaaki; Stetter, Joseph R.

    1986-01-01

    A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about about 1.4 volts versus R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

  11. Ridgewood Renewable Power LLC | Open Energy Information

    Open Energy Info (EERE)

    and Egypt. Projects developed include hydro, biomass, natural gas and landfill methane gas power plants. Coordinates: 40.700725, -73.895329 Show Map Loading map......

  12. Energy Recovery Associates | Open Energy Information

    Open Energy Info (EERE)

    - NY NJ CT PA Area Sector: Biofuels Product: Landfill Gas, Digester Gas, mixed methane and Greenhouse gases recovery and utilization equipment and projects. Number of...

  13. Understanding the nature of methane emission from rice ecosystems as basis of mitigation strategies

    SciTech Connect (OSTI)

    Buendia, L.V.; Neue, H.U.; Wassmann, R.

    1996-12-31

    Methane is considered as an important Greenhouse gas and rice fields are one of the major atmospheric methane sources. The paper aims to develop sampling strategies and formulate mitigation options based on diel (day and night) and seasonal pattern of methane emission. The study was conducted in 4 countries to measure methane flux using an automatic closed chamber system. A 24-hour bihourly methane emissions were continuously obtained during the whole growing season. Daily and seasonal pattern of methane fluxes from different rice ecosystems were evaluated. Diel pattern of methane emission from irrigated rice fields, in all sites, displayed similar pattern from planting to flowering. Fluxes at 0600, 1200, and 1800 h were important components of the total diel flux. A proposed sampling frequency to accurately estimate methane emission within the growing season was designed based on the magnitude of daily flux variation. Total methane emission from different ecosystems follow the order: deepwater rice > irrigated rice > rainfed rice. Application of pig manure increased total emission by 10 times of that without manure. Green manure application increased emission by 49% of that applied only with inorganic fertilizer. Removal of floodwater at 10 DAP and 35 DAP, within a period of 4 days, inhibited production and emission of methane. The level of variation in daily methane emission and seasonal emission pattern provides useful information for accurate determination of methane fluxes. Characterization of seasonal emission pattern as to ecologies, fertilizer amendments, and water management gives an idea of where to focus mitigation strategies for sustainable rice production.

  14. Methane Recovery from Hydrate-bearing Sediments

    SciTech Connect (OSTI)

    J. Carlos Santamarina; Costas Tsouris

    2011-04-30

    Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with

  15. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-08-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Liquid addition has commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell is nearly complete with only the biofilter remaining and is scheduled to be complete by the end of August 2003. The current project status and preliminary monitoring results are summarized in this report.

  16. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-05-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Construction is complete on the 3.5-acre anaerobic cell and liquid addition has commenced. Construction of the 2.5-acre aerobic cell is nearly complete with only the biofilter remaining and construction of the west-side 6-acre anaerobic cell is nearly complete with only the liquid addition system remaining. The current project status and preliminary monitoring results are summarized in this report.

  17. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-12-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Liquid addition has commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell and biofilter has been completed. The remaining task to be completed is to test the biofilter prior to operation, which is currently anticipated to begin in January 2004. The current project status and preliminary monitoring results are summarized in this report.

  18. Full Scale Bioreactor Landfill for Carbon Sequestration and Greenhouse Emission Control

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Kathy Sananikone; Don Augenstein

    2005-03-30

    The Yolo County Department of Planning and Public Works constructed a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective was to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entailed the construction of a 12-acre module that contained a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells were highly instrumented to monitor bioreactor performance. Liquid addition commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell and biofilter has been completed. The current project status and preliminary monitoring results are summarized in this report.

  19. Definition:Digester Gas | Open Energy Information

    Open Energy Info (EERE)

    digestion is a biological process that produces a gas principally composed of methane (CH4) and carbon dioxide (CO2) otherwise known as biogas. These gases are produced...

  20. Shale Gas 101 | Department of Energy

    Energy Savers [EERE]

    ... Protection Agency U.S. Government Accountability Office Clean Coal Carbon Capture and Storage Oil & Gas Methane Hydrate LNG Offshore Drilling Enhanced Oil Recovery Shale

  1. Presentations from the March 27th - 28th Methane Hydrates Advisory

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Committee Meeting | Department of Energy March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting International Gas Hydrate Research (5.5 MB) DOE's Natural Gas Hydrates Program (8.75 MB) Gas Hydrates as a Geohazard: What Really Are the Issues? (2.58 MB) Quantifying Climate-Hydrate Interactions: A Progress Report (616.36 KB) More Documents & Publications May 21, 2014 Committee Recommendations to

  2. U.S. and Japan Complete Successful Field Trial of Methane Hydrate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Technologies | Department of Energy and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies U.S. and Japan Complete Successful Field Trial of Methane Hydrate Production Technologies May 2, 2012 - 1:00pm Addthis Washington, DC - U.S. Energy Secretary Steven Chu announced today the completion of a successful, unprecedented test of technology in the North Slope of Alaska that was able to safely extract a steady flow of natural gas from methane hydrates -

  3. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  4. MethaneHydrateRD_FC.indd

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of Fossil Energy (FE) has played a major role in developing technologies to help tap new, unconventional sources of natural gas. FOSSIL ENERGY RESEARCH BENEFITS Methane Hydrate R&D "The (DOE) Program has supported and managed a high-quality research portf olio that has enabled signifi cant progress toward the (DOE) Program's long-term

  5. Top-down estimate of methane emissions in California using a mesoscale inverse modeling technique: The South Coast Air Basin

    SciTech Connect (OSTI)

    Cui, Yu Yan; Brioude, Jerome; McKeen, Stuart A.; Angevine, Wayne M.; Kim, Si -Wan; Frost, Gregory J.; Ahmadov, Ravan; Peischl, Jeff; Bousserez, Nicolas; Liu, Zhen; Ryerson, Thomas B.; Wofsy, Steve C.; Santoni, Gregory W.; Kort, Eric A.; Fischer, Marc L.; Trainer, Michael

    2015-07-28

    Methane (CH4) is the primary component of natural gas and has a larger global warming potential than CO2. Some recent top-down studies based on observations showed CH4 emissions in California's South Coast Air Basin (SoCAB) were greater than those expected from population-apportioned bottom-up state inventories. In this study, we quantify CH4 emissions with an advanced mesoscale inverse modeling system at a resolution of 8 km × 8 km, using aircraft measurements in the SoCAB during the 2010 Nexus of Air Quality and Climate Change campaign to constrain the inversion. To simulate atmospheric transport, we use the FLEXible PARTicle-Weather Research and Forecasting (FLEXPART-WRF) Lagrangian particle dispersion model driven by three configurations of the Weather Research and Forecasting (WRF) mesoscale model. We determine surface fluxes of CH4 using a Bayesian least squares method in a four-dimensional inversion. Simulated CH4 concentrations with the posterior emission inventory achieve much better correlations with the measurements (R2 = 0.7) than using the prior inventory (U.S. Environmental Protection Agency's National Emission Inventory 2005, R2 = 0.5). The emission estimates for CH4 in the posterior, 46.3 ± 9.2 Mg CH4/h, are consistent with published observation-based estimates. Changes in the spatial distribution of CH4 emissions in the SoCAB between the prior and posterior inventories are discussed. Missing or underestimated emissions from dairies, the oil/gas system, and landfills in the SoCAB seem to explain the differences between the prior and posterior inventories. Furthermore, we estimate that dairies contributed 5.9 ± 1.7 Mg CH4/h and the two sectors of oil and gas industries (production and downstream) and landfills together contributed 39.6 ± 8.1 Mg CH4/h in the SoCAB.

  6. Top-down estimate of methane emissions in California using a mesoscale inverse modeling technique: The South Coast Air Basin

    SciTech Connect (OSTI)

    Cui, Yu Yan; Brioude, Jerome; McKeen, Stuart A.; Angevine, Wayne M.; Kim, Si -Wan; Frost, Gregory J.; Ahmadov, Ravan; Peischl, Jeff; Bousserez, Nicolas; Liu, Zhen; Ryerson, Thomas B.; Wofsy, Steve C.; Santoni, Gregory W.; Kort, Eric A.; Fischer, Marc L.; Trainer, Michael

    2015-07-28

    Methane (CH4) is the primary component of natural gas and has a larger global warming potential than CO2. Some recent top-down studies based on observations showed CH4 emissions in California's South Coast Air Basin (SoCAB) were greater than those expected from population-apportioned bottom-up state inventories. In this study, we quantify CH4 emissions with an advanced mesoscale inverse modeling system at a resolution of 8 km 8 km, using aircraft measurements in the SoCAB during the 2010 Nexus of Air Quality and Climate Change campaign to constrain the inversion. To simulate atmospheric transport, we use the FLEXible PARTicle-Weather Research and Forecasting (FLEXPART-WRF) Lagrangian particle dispersion model driven by three configurations of the Weather Research and Forecasting (WRF) mesoscale model. We determine surface fluxes of CH4 using a Bayesian least squares method in a four-dimensional inversion. Simulated CH4 concentrations with the posterior emission inventory achieve much better correlations with the measurements (R2 = 0.7) than using the prior inventory (U.S. Environmental Protection Agency's National Emission Inventory 2005, R2 = 0.5). The emission estimates for CH4 in the posterior, 46.3 9.2 Mg CH4/h, are consistent with published observation-based estimates. Changes in the spatial distribution of CH4 emissions in the SoCAB between the prior and posterior inventories are discussed. Missing or underestimated emissions from dairies, the oil/gas system, and landfills in the SoCAB seem to explain the differences between the prior and posterior inventories. Furthermore, we estimate that dairies contributed 5.9 1.7 Mg CH4/h and the two sectors of oil and gas industries (production and downstream) and landfills together contributed 39.6 8.1 Mg CH4/h in the SoCAB.

  7. Direct Aromaization of Methane

    SciTech Connect (OSTI)

    George Marcelin

    1997-01-15

    The thermal decomposition of methane offers significant potential as a means of producing higher unsaturated and aromatic hydrocarbons when the extent of reaction is limited. Work in the literature previous to this project had shown that cooling the product and reacting gases as the reaction proceeds would significantly reduce or eliminate the formation of solid carbon or heavier (Clo+) materials. This project studied the effect and optimization of the quenching process as a means of increasing the amount of value added products during the pyrolysis of methane. A reactor was designed to rapidly quench the free-radical combustion reaction so as to maximize the yield of aromatics. The use of free-radical generators and catalysts were studied as a means of lowering the reaction temperature. A lower reaction temperature would have the benefits of more rapid quenching as well as a more feasible commercial process due to savings realized in energy and material of construction costs. It was the goal of the project to identify promising routes from methane to higher hydrocarbons based on the pyrolysis of methane.

  8. Louisiana--North Coalbed Methane Proved Reserves (Billion Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Coalbed Methane Proved Reserves (Billion Cubic Feet) Louisiana--North Coalbed Methane ... Coalbed Methane Proved Reserves as of Dec. 31 North Louisiana Coalbed Methane Proved ...

  9. Request for Qualifications for Sacramento Landfill

    Broader source: Energy.gov [DOE]

    This Request for Qualifications (RFQ) solicits experienced companies to design, permit, finance, build, and operate a solar photovoltaic farm (SPV Farm) on the City of Sacramento’s 28th Street Landfill. Respondents to this RFQ must demonstrate experience and capacity to design, permit, finance, build, and operate a SPV Farm that generates electricity that can be sold for electrical use through a power-purchase agreement. Submittals must be prepared and delivered in accordance with the requirements set forth in this document.

  10. DOE - Office of Legacy Management -- Pfohl Brothers Landfill - NY 66

    Office of Legacy Management (LM)

    Pfohl Brothers Landfill - NY 66 FUSRAP Considered Sites Site: Pfohl Brothers Landfill (NY.66 ) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Five-Year Review Report Pfohl Brothers Landfill Superfund Site Erie County Town of Cheektowaga, New York EPA REGION 2 Congressional District(s): 30 Erie Cheektowaga NPL LISTING HISTORY Documents

  11. CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Systems for Landfills and Wastewater Treatment Plants CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants There are important issues to consider when selecting a CHP technology, such as size, emissions, location of maintenance personnel, and efficiency. This document summarizes the following CHP technologies: Reciprocating Engine, Microturbine, Combustion Turbines, Stirling Engine, and Fuel Cell. CHP and Bioenergy Systems for Landfills and Wastewater

  12. http://ndep.nv.gov/bwm/landfill.htm

    National Nuclear Security Administration (NNSA)

    ... Republic Services, Inc Operating - Class I Permitted Laughlin Nevada Clark County Apex Regional Landfill Republic Services, Inc Operating - Class I Permitted Las Vegas Valley ...

  13. Savannah River Site - Sanitary Landfill | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Name: Sanitary Landfill Remediation Contractor: Savannah River Nuclear Solutions, LLC PBS Number: 30 Report Last Updated: 2013 Contaminants Halogenated VOCsSVOCs Present?: Yes ...

  14. A Multi-tower Measurement Network Estimate of California's Methane Emissions

    SciTech Connect (OSTI)

    Jeong, Seongeun; Hsu, Ying-Kuang; Andrews, Arlyn E.; Bianco, Laura; Vaca, Patrick; Wilczak, James M.; Fischer, Marc L.

    2013-12-02

    We present an analysis of methane (CH{sub 4}) emissions using atmospheric observations from five sites in California’s Central Valley across different seasons (September 2010 to June 2011). CH{sub 4} emissions for spatial regions and source sectors are estimated by comparing measured CH{sub 4} mixing ratios with transport model (WRF-STILT) predictions based on two 0.1 degree CH{sub 4} (seasonally varying “California-specific” (CALGEM) and a static global (EDGAR42)) prior emission models. Region-specific Bayesian analyses indicate that for California’s Central Valley the CALGEM- and EDGAR42-based inversions provide consistent annual total CH{sub 4} emissions (32.87±2.09 vs. 31.60±2.17 Tg CO{sub 2}eq yr{sup -1}; 68% C.I., assuming uncorrelated errors between regions). Summing across all regions of California, optimized CH{sub 4} emissions are only marginally consistent between CALGEM- and EDGAR42-based inversions (48.35±6.47 vs. 64.97±11.85 Tg CO{sub 2}eq), because emissions from coastal urban regions (where landfill and natural gas emissions are much higher in EDGAR than CALGEM) are not strongly constrained by the measurements. Combining our results with those from a recent study of the South Coast air basin narrows the range of estimates to 43 – 57 Tg CO{sub 2}eq yr{sup -1} (1.3 - 1.8 times higher than the current state inventory). These results suggest that the combination of rural and urban measurements will be necessary to verify future changes in California’s total CH{sub 4} emissions.

  15. Briefing: DOE EM Landfill Workshop & Path Forward | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Landfill Workshop & Path Forward Briefing: DOE EM Landfill Workshop & Path Forward By: Office of Groundwater and Soil Remediation Where: SSAB Teleconference 2 Subject: DOE EM Landfill Workshop & Path Forward DOE EM Landfill Workshop and Path Forward - July 2009 (316.86 KB) More Documents & Publications Briefing: Summary and Recommendations of EM Landfill Workshop Briefing: DOE EM ITR Landfill Assessment Project Lessons Learned Environmental Management Waste Management Facility

  16. Field Exploration of Methane Seep Near Atqasuk

    SciTech Connect (OSTI)

    Katey Walter, Dennis Witmer, Gwen Holdmann

    2008-12-31

    Methane (CH{sub 4}) in natural gas is a major energy source in the U.S., and is used extensively on Alaska's North Slope, including the oilfields in Prudhoe Bay, the community of Barrow, and the National Petroleum Reserve, Alaska (NPRA). Smaller villages, however, are dependent on imported diesel fuel for both power and heating, resulting in some of the highest energy costs in the U.S. and crippling local economies. Numerous CH{sub 4} gas seeps have been observed on wetlands near Atqasuk, Alaska (in the NPRA), and initial measurements have indicated flow rates of 3,000-5,000 ft{sup 3} day{sup -1} (60-100 kg CH{sub 4} day{sup -1}). Gas samples collected in 1996 indicated biogenic origin, although more recent sampling indicated a mixture of biogenic and thermogenic gas. In this study, we (1) quantified the amount of CH{sub 4} generated by several seeps and evaluated their potential use as an unconventional gas source for the village of Atqasuk; (2) collected gas and analyzed its composition from multiple seeps several miles apart to see if the source is the same, or if gas is being generated locally from isolated biogenic sources; and (3) assessed the potential magnitude of natural CH{sub 4} gas seeps for future use in climate change modeling.

  17. Quantification of the Potential Gross Economic Impacts of Five Methane Reduction Scenarios

    Office of Energy Efficiency and Renewable Energy (EERE)

    This study assessed five potential methane reduction scenarios from natural gas transmission, storage, and distribution (TS&D) infrastructure using published literature on the costs and the estimated quantity of methane reduced. The results show that implementation of these five measures could support approximately 85,000 jobs annually from 2015 to 2019 and reduce CH4 emissions from natural gas TS&D by over 40%. Based on standard input/output analysis methodology, measures are estimated to support over $8 billion in GDP annually over the same time period and allow producers to recover approximately $912 million annually in captured gas. Mitigation of methane emission reductions through repair, replacement and new technologies are found to support economic development and jobs. The study also found that a portfolio approach to infrastructure modernization may be appropriate to meaningfully improve safety, maintain or create high levels of employment, and significant losses of methane from across TS&D segments of natural gas systems.

  18. Methane conversion to methanol

    SciTech Connect (OSTI)

    Noble, R.D.; Falconer, J.L.

    1992-06-01

    The objective of this research study is to demonstrate the effectiveness of a catalytic membrane reactor for the partial oxidation of methane. The specific goals are to demonstrate that we can improve product yield, demonstrate the optimal conditions for membrane reactor operation, determine the transport properties of the membrane, and provide demonstration of the process at the pilot plant scale. The last goal will be performed by Unocal, Inc., our industrial partner, upon successful completion of this study.

  19. Methane conversion to methanol

    SciTech Connect (OSTI)

    Noble, R.D.; Falconer, J.L.

    1992-01-01

    The objective of this research study is to demonstrate the effectiveness of a catalytic membrane reactor for the partial oxidation of methane. The specific goals are to demonstrate that we can improve product yield, demonstrate the optimal conditions for membrane reactor operation, determine the transport properties of the membrane, and provide demonstration of the process at the pilot plant scale. The last goal will be performed by Unocal, Inc., our industrial partner, upon successful completion of this study.

  20. CONTENTS Gas Hydrate-Bearing Sand

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONTENTS Gas Hydrate-Bearing Sand Reservoir Systems in the Offshore of India: Results of the India National Gas Hydrate Program Expedition 02 ..............1 The Potential for Abiotic Methane in Arctic Gas Hydrates .................9 Coupled Thermo-Hydro-Chemo- Mechanical (THCM) Models for Hydrate-Bearing Sediments ....13 Emerging Issues in the Development of Geologic Models for Gas Hydrate Numerical Simulation ................19 Announcements ...................... 23 * DOE/NETL FY2016 Methane

  1. Gas evolution from geopressured brines

    SciTech Connect (OSTI)

    Matthews, C.S.

    1980-06-01

    The process of gas evolution from geopressured brine is examined using as a basis the many past studies of gas evolution from liquids in porous media. A discussion of a number of speculations that have been made concerning gas evolution from geopressured brines is provided. According to one, rapid pressure reduction will cause methane gas to evolve as when one opens a champagne bottle. It has been further speculated that evolved methane gas would migrate up to form an easily producible cap. As a result of detailed analyses, it can be concluded that methane gas evolution from geopressured brines is far too small to ever form a connected gas saturation except very near to the producing well. Thus, no significant gas cap could ever form. Because of the very low solubility of methaned in brine, the process of methane gas evolution is not at all analogous to evolution of carbon dioxide from champagne. A number of other speculations and questions on gas evolution are analyzed, and procedures for completing wells and testing geopressured brine reservoirs are discussed, with the conclusion that presently used procedures will provide adequate data to enable a good evaluation of this resource.

  2. H. R. 2998: A bill to amend the Natural Gas Act to permit the development of coalbed methane gas in areas where its development has been impeded or made impossible by uncertainty and litigation over ownership rights, and for other purposes, introduced in the US House of Representatives, One Hundred Second Congress, First Session, July 23, 1991

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This bill would direct the Secretary of Energy to compile a list of affected states which are determined to be states in which disputes, uncertainty, or litigation exist or potentially exists regarding the ownership of coalbed methane; in which the development of significant deposits of coalbed methane may be impeded by such disputes; in which statutory or regulatory procedures permitting and encouraging development of coalbed methane prior to final resolution of disputes are not in place; and in which extensive development of coalbed methane does not exist. Colorado, Montana, New Mexico, Wyoming, Utah, Virginia, and Alabama are excluded from such a list since they currently have development of coalbed methane. Until the Secretary of Energy publishes a different list, the affected states are West Virginia, Pennsylvania, Kentucky, Ohio, Tennessee, Indiana, and Illinois, effective on the date of enactment of this bill.

  3. Methane Hydrate Research and Modeling | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research and Modeling Methane Hydrate Research and Modeling Research is focused on understanding the physical and chemical nature of gas hydrate-bearing sediments. These studies advance the understanding of the in situ nature of GHBS and their potential response in terms of fluid flow and geomechanical response to destabilizing forces. The latest research results from DOE projects, both current and completed, can be found on the NETL website. These include: Gas Hydrate Characterization in the

  4. Methane Hydrate Advisory Committee (MHAC) Meeting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrate Advisory Committee (MHAC) Meeting May 7, 2015 1:00 - 3:00PM (EDT) Via Teleconference MEETING SUMMARY Attached are the meeting agenda and the list of attendees; a quorum of Committee members was present. DFO Welcome and Introductions - Paula A. Gant, DFO The meeting was called to order at 1:00PM EDT by Paula A. Gant, Deputy Assistant Secretary (DAS) for Oil and Gas within the U.S. Department of Energy (DOE) and Designated Federal Officer (DFO) for the Methane Hydrate Advisory Committee

  5. Greenhouse gas emissions from landfill leachate treatment plants...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 54 ENVIRONMENTAL SCIENCES; 12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; AGING; CARBON DIOXIDE; GREENHOUSE GASES; LEACHATES; ...

  6. Winnebago County Landfill Gas Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    2.72.7 MW 2,700 kW 2,700,000 W 2,700,000,000 mW 0.0027 GW Commercial Online Date 2000 Heat Rate (BTUkWh) 9350.0 References EPA Web Site1 Loading map... "minzoom":false,"map...

  7. RCWMD Badlands Landfill Gas Project Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    mW 1.0e-3 GW Commercial Online Date 2001 Heat Rate (BTUkWh) 12916.67 References EPA Web Site1 Loading map... "minzoom":false,"mappingservice":"googlemaps3","type":"TERRAIN...

  8. Short Mountain Landfill Gas Recovery Project : Stage 1 Environmental Assessment.

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration.

    1992-05-01

    The Bonneville Power Administration (BPA), a Federal power marketing agency, has statutory responsibilities to supply electrical power to its utility, industrial, and other customers in the Pacific Northwest. BPA`s latest load/resource balance forecast, projects the capability of existing resources to satisfy projected Federal system loads. The forecast indicates a potential resource deficit. The underlying need for action is to satisfy BPA customers` demand for electrical power.

  9. Comparison between lab- and full-scale applications of in situ aeration of an old landfill and assessment of long-term emission development after completion

    SciTech Connect (OSTI)

    Hrad, Marlies; Gamperling, Oliver; Huber-Humer, Marion

    2013-10-15

    Highlights: ? Current data on in situ aeration effects from the first Austrian full-scale case study. ? Data on lasting waste stabilisation after aeration completion. ? Information on the transferability of results from lab- to full-scale aeration. - Abstract: Sustainable landfilling has become a fundamental objective in many modern waste management concepts. In this context, the in situ aeration of landfills has been recognised for its potential to convert conventional anaerobic landfills into biological stabilised state, whereby both current and potential (long-term) emissions of the landfilled waste are mitigated. In recent years, different in situ aeration concepts have been successfully applied in Europe, North America and Asia, all pursuing different objectives and strategies. In Austria, the first full-scale application of in situ landfill aeration by means of low pressure air injection and simultaneous off-gas collection and treatment was implemented on an old, small municipal solid waste (MSW) landfill (2.6 ha) in autumn 2007. Complementary laboratory investigations were conducted with waste samples taken from the landfill site in order to provide more information on the transferability of the results from lab- to full-scale aeration measures. In addition, long-term emission development of the stabilised waste after aeration completion was assessed in an ongoing laboratory experiment. Although the initial waste material was described as mostly stable in terms of the biological parameters gas generation potential over 21 days (GP{sub 21}) and respiration activity over 4 days (RA{sub 4}), the lab-scale experiments indicated that aeration, which led to a significant improvement of leachate quality, was accompanied by further measurable changes in the solid waste material under optimised conditions. Even 75 weeks after aeration completion the leachate, as well as gaseous emissions from the stabilised waste material, remained low and stayed below the authorised

  10. EA-1762: Finding of No Significant Impact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of No Significant Impact EA-1762: Finding of No Significant Impact Wellford Landfill Methane and Greenhouse Gas to Energy Project, Spartanburg County, South Carolina The...

  11. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    decay prior to landfill capping resulting in the atmospheric release of methane a green house gas GHG This research project was therefore conceptualized and implemented by...

  12. One Man's Trash is Another Man's Fuel | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Dennis A. Smith Director, National Clean Cities The average American throws away more than 900 pounds of trash every year. Organic waste degrading in landfills produces methane gas ...

  13. Island Gas | Open Energy Information

    Open Energy Info (EERE)

    United Kingdom Zip: W1J 7BU Sector: Renewable Energy Product: UK-based coal bed methane company, Island Gas was the subject of a reverse takeover by KP Renewables in...

  14. Organic and nitrogen removal from landfill leachate in aerobic granular sludge sequencing batch reactors

    SciTech Connect (OSTI)

    Wei Yanjie; Ji Min; Li Ruying; Qin Feifei

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Aerobic granular sludge SBR was used to treat real landfill leachate. Black-Right-Pointing-Pointer COD removal was analyzed kinetically using a modified model. Black-Right-Pointing-Pointer Characteristics of nitrogen removal at different ammonium inputs were explored. Black-Right-Pointing-Pointer DO variations were consistent with the GSBR performances at low ammonium inputs. - Abstract: Granule sequencing batch reactors (GSBR) were established for landfill leachate treatment, and the COD removal was analyzed kinetically using a modified model. Results showed that COD removal rate decreased as influent ammonium concentration increasing. Characteristics of nitrogen removal at different influent ammonium levels were also studied. When the ammonium concentration in the landfill leachate was 366 mg L{sup -1}, the dominant nitrogen removal process in the GSBR was simultaneous nitrification and denitrification (SND). Under the ammonium concentration of 788 mg L{sup -1}, nitrite accumulation occurred and the accumulated nitrite was reduced to nitrogen gas by the shortcut denitrification process. When the influent ammonium increased to a higher level of 1105 mg L{sup -1}, accumulation of nitrite and nitrate lasted in the whole cycle, and the removal efficiencies of total nitrogen and ammonium decreased to only 35.0% and 39.3%, respectively. Results also showed that DO was a useful process controlling parameter for the organics and nitrogen removal at low ammonium input.

  15. The Greenhouse Gas Protocol Initiative: GHG Emissions from Purchased...

    Open Energy Info (EERE)

    Outputs include: The tool outputs greenhouse gas emissions (carbon dioxide, methane, nitrous oxide, and carbon dioxide equivalent) for each facility as well as total...

  16. An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs...

    Open Energy Info (EERE)

    based on the analysis of geochemical anomalies to the main components, such as methane and hydrocarbon series, an integrated assessment of prospective gas hydrate...

  17. The Greenhouse Gas Protocol Initiative: GHG Emissions from Transport...

    Open Energy Info (EERE)

    Outputs include: The tool outputs greenhouse gas emissions (including carbon dioxide, methane, nitrous oxide, carbon dioxide equivalent, and biogenic carbon dioxide) for each...

  18. oil-gas-announcements | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil and Gas Announcements The Spring, 2016 Issue of the Methane Hydrate Newsletter Fire in ... research and emergency situations, such as oil spills and search and rescue missions. ...

  19. Technologies to characterize natural gas emissions tested in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies to characterize natural gas emissions tested in ... development of ultra-sensitive methane-sensing technology. ... have been focused on upstream applications in the oil ...

  20. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2012 Houston, TX PDF icon July 26, 2012 Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting...

  1. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Office of Environmental Management (EM)

    Washington, DC PDF icon July 16, 2013 Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes Methane Hydrate Advisory Committee Meeting...

  2. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Energy Savers [EERE]

    DC PDF icon March 27-28, 2014, Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane Hydrate Advisory...

  3. Methane Power Inc | Open Energy Information

    Open Energy Info (EERE)

    Power Inc Jump to: navigation, search Logo: Methane Power Inc. Name: Methane Power Inc. Address: 121 Edinburgh South Drive Place: Cary, NC Zip: 27511 Sector: Renewable Energy...

  4. Methane Hydrate Advisory Committee Meeting Minutes | Department...

    Broader source: Energy.gov (indexed) [DOE]

    June 6th - 7th, 2013 Meeting Minutes More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee Meeting...

  5. Industrial Waste Landfill IV upgrade package

    SciTech Connect (OSTI)

    Not Available

    1994-03-29

    The Y-12 Plant, K-25 Site, and ORNL are managed by DOE`s Operating Contractor (OC), Martin Marietta Energy Systems, Inc. (Energy Systems) for DOE. Operation associated with the facilities by the Operating Contractor and subcontractors, DOE contractors and the DOE Federal Building result in the generation of industrial solid wastes as well as construction/demolition wastes. Due to the waste streams mentioned, the Y-12 Industrial Waste Landfill IV (IWLF-IV) was developed for the disposal of solid industrial waste in accordance to Rule 1200-1-7, Regulations Governing Solid Waste Processing and Disposal in Tennessee. This revised operating document is a part of a request for modification to the existing Y-12 IWLF-IV to comply with revised regulation (Rule Chapters 1200-1-7-.01 through 1200-1-7-.08) in order to provide future disposal space for the ORR, Subcontractors, and the DOE Federal Building. This revised operating manual also reflects approved modifications that have been made over the years since the original landfill permit approval. The drawings referred to in this manual are included in Drawings section of the package. IWLF-IV is a Tennessee Department of Environmental and Conservation/Division of Solid Waste Management (TDEC/DSWM) Class 11 disposal unit.

  6. Expression of barley SUSIBA2 transcription factor yields high-starch low-methane rice

    SciTech Connect (OSTI)

    Su, J.; Hu, C.; Yan, X.; Jin, Y.; Chen, Z.; Guan, Q.; Wang, Y.; Zhong, D.; Jansson, Georg C.; Wang, F.; Schnrer, Anna; Sun, Chuanxin

    2015-07-22

    Atmospheric methane is the second most important greenhouse gas after carbon dioxide, and is responsible for about 20% of the global warming effect since pre-industrial times. Rice paddies are the largest anthropogenic methane source and produce 7–17% of atmospheric methane. Warm waterlogged soil and exuded nutrients from rice roots provide ideal conditions for methanogenesis in paddies with annual methane emissions of 25–100-million tonnes. This scenario will be exacerbated by an expansion in rice cultivation needed to meet the escalating demand for food in the coming decades4. There is an urgent need to establish sustainable technologies for increasing rice production while reducing methane fluxes from rice paddies. However, ongoing efforts for methane mitigation in rice paddies are mainly based on farming practices and measures that are difficult to implement5. Despite proposed strategies to increase rice productivity and reduce methane emissions4,6, no high-starch low-methane-emission rice has been developed. Here we show that the addition of a single transcription factor gene, barley SUSIBA2, conferred a shift of carbon flux to SUSIBA2 rice, favouring the allocation of photosynthates to aboveground biomass over allocation to roots. The altered allocation resulted in an increased biomass and starch content in the seeds and stems, and suppressed methanogenesis, possibly through a reduction in root exudates. Three-year field trials in China demonstrated that the cultivation of SUSIBA2 rice was associated with a significant reduction in methane emissions and a decrease in rhizospheric methanogen levels. SUSIBA2 rice offers a sustainable means of providing increased starch content for food production while reducing greenhouse gas emissions from rice cultivation. Approaches to increase rice productivity and reduce methane emissions as seen in SUSIBA2 rice may be particularly beneficial in a future climate with rising temperatures resulting in increased methane

  7. Coal mine methane global review

    SciTech Connect (OSTI)

    2008-07-01

    This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

  8. ITP Industrial Distributed Energy: CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems for Landfills and Wastewater Treatment Plants November 7, 2007 Denver, Colorado Paul Lemar Jr., President pll@rdcnet.com www.rdcnet.com www.distributed-generation.com Reciprocating Engines for ADG and LFG z Reciprocating engines are either Otto (spark ignition) or Diesel (compression ignition) cycle systems z Natural gas engines, as well as those powered by ADG or LFG, are typically spark ignition systems z Some dual fuel engines have been developed using ADG/LFG with a portion of diesel

  9. Gas content of Gladys McCall reservoir brine (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    ... However, observed small transients in EthaneMethane and PropaneMethane ratios indicate that some free gas was produced from the near wellbore region. These results suggest that ...

  10. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the revolutionary and new

  11. A case study: Environmental benefit plan for Blydenburgh Landfill

    SciTech Connect (OSTI)

    Hansen, J.M.; Druback, G.W.

    1995-12-31

    The Town of Islip, New York, encompasses 285 square kilometers (110 square miles) along the southern shore of Suffolk County, Long Island. The Town relied upon Blydenburgh Landfill for the disposal of its estimated 290 kilotonnes per year (320,000 tons per year) of municipal solid waste (MSW) without having to contract for off-Long Island hauling and disposal. In 1983, the Long Island Landfill Law was enacted and effectively banned landfilling of raw garbage on most of Long Island after December 18, 1990. The act precluded the economic development of new landfill capacity for the Town. Blydenburgh Landfill was projected to reach capacity in early 1987 and close. To conserve landfill capacity for residential use, the Town prohibited commercial haulers from the landfill in the fall of 1986. In response, the Mobro barge departed Long Island City on March 22, 1987 loaded with commercial MSW that was no longer accepted at the Blydenburgh site. Negative publicity surrounded the Mobro barge and the continuing need to provide for waste disposal. In response, the New York State Department of Environmental Conservation (NYSDEC) and the Town`s Resource Recovery Agency entered into an Order on Consent on May 12, 1987. This allowed for continued operations and a vertical MSW {open_quotes}piggyback{close_quotes} expansion on top of a closed and capped portion of the existing 181,000 square meter (44.8 acre) landfill mound. In addition, the Order on Consent permitted construction of a separate 12,000 square meter (3.0 acre) ash residue vertical piggyback expansion adjacent to the MSW piggyback expansion. Both expansions were designed for and constructed on top of existing landfilled MSW.

  12. Capture and Use of Coal Mine Ventilation Air Methane

    SciTech Connect (OSTI)

    Deborah Kosmack

    2008-10-31

    CONSOL Energy Inc., in conjunction with MEGTEC Systems, Inc., and the U.S. Department of Energy with the U.S. Environmental Protection Agency, designed, built, and operated a commercial-size thermal flow reversal reactor (TFRR) to evaluate its suitability to oxidize coal mine ventilation air methane (VAM). Coal mining, and particularly coal mine ventilation air, is a major source of anthropogenic methane emissions, a greenhouse gas. Ventilation air volumes are large and the concentration of methane in the ventilation air is low; thus making it difficult to use or abate these emissions. This test program was conducted with simulated coal mine VAM in advance of deploying the technology on active coal mine ventilation fans. The demonstration project team installed and operated a 30,000 cfm MEGTEC VOCSIDIZER oxidation system on an inactive coal mine in West Liberty, WV. The performance of the unit was monitored and evaluated during months of unmanned operation at mostly constant conditions. The operating and maintenance history and how it impacts the implementation of the technology on mine fans were investigated. Emission tests showed very low levels of all criteria pollutants at the stack. Parametric studies showed that the equipment can successfully operate at the design specification limits. The results verified the ability of the TFRR to oxidize {ge}95% of the low and variable concentration of methane in the ventilation air. This technology provides new opportunities to reduce greenhouse gas emissions by the reduction of methane emissions from coal mine ventilation air. A large commercial-size installation (180,000 cfm) on a single typical mine ventilation bleeder fan would reduce methane emissions by 11,000 to 22,100 short tons per year (the equivalent of 183,000 to 366,000 metric tonnes carbon dioxide).

  13. Manhattan Project truck unearthed at landfill cleanup site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manhattan project truck Manhattan Project truck unearthed at landfill cleanup site A LANL excavation crew working on a Recovery Act cleanup project has uncovered the remnants of a 1940s military truck buried in a Manhattan Project-era landfill. April 8, 2011 image description Excavator operator Kevin Miller looks at the remnants of a 1940s military truck buried in a Manhattan Project-era landfill. Contact Fred deSousa Communications Office (505) 665-3430 Email Remnants of a 1940s military truck

  14. DOE - Office of Legacy Management -- Shpack Landfill - MA 06

    Office of Legacy Management (LM)

    Shpack Landfill - MA 06 FUSRAP Considered Sites Shpack Landfill, NY Alternate Name(s): Attleboro, MA Metals and Controls Site Norton Landfill area MA.06-2 MA.06-3 Location: 68 Union Road, Norton, Massachusetts MA.06-2 Historical Operations: No AEC activities were conducted on site. Contamination was suspected from disposal of materials containing uranium and zirconium ash. MA.06-2 MA.06-3 Eligibility Determination: Eligible MA.06-1 Radiological Survey(s): Assessment Surveys MA.06-4 MA.06-5

  15. Coalbed Methane Production

    Gasoline and Diesel Fuel Update (EIA)

    Methane Production (Billion Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2009 2010 2011 2012 2013 2014 View History U.S. 1,914 1,886 1,763 1,655 1,466 1,404 1989-2014 Alabama 105 102 98 91 62 78 1989-2014 Alaska 0 0 0 0 0 0 2005-2014 Arkansas 3 3 4 2 2 2 2005-2014 California 0 0 0 0 0 0 2005-2014 Colorado 498 533 516 486 444 412 1989-2014 Florida 0 0 0 0 0 0 2005-2014 Kansas 43 41 37 34 30 27

  16. Nanostructural control of methane release in kerogen and its implications to wellbore production decline

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ho, Tuan Anh; Criscenti, Louise J.; Wang, Yifeng

    2016-06-16

    In spite of the massive success of shale gas production in the US in the last few decades there are still major concerns with the steep decline in wellbore production and the large uncertainty in a long-term projection of decline curves. A reliable projection must rely on a mechanistic understanding of methane release in shale matrix–a limiting step in shale gas extraction. Here we show that methane release in nanoporous kerogen matrix is characterized by fast release of pressurized free gas (accounting for ~30–47% recovery) followed by slow release of adsorbed gas as the gas pressure decreases, and we usemore » molecular simulations to demonstrate it. The first stage is driven by the gas pressure gradient while the second stage is controlled by gas desorption and diffusion. We further show that diffusion of all methane in nanoporous kerogen behaves differently from the bulk phase, with much smaller diffusion coefficients. The MD simulations also indicate that a significant fraction (3–35%) of methane deposited in kerogen can potentially become trapped in isolated nanopores and thus not recoverable. Finally, our results shed a new light on mechanistic understanding gas release and production decline in unconventional reservoirs. The long-term production decline appears controlled by the second stage of gas release.« less

  17. Methane Stakeholder Roundtables | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane Stakeholder Roundtables Methane Stakeholder Roundtables April 24, 2014 - 3:00pm Addthis Methane Stakeholder Roundtables Advancing the Interagency Methane Strategy As directed by President Obama in his Climate Action Plan, the Department of Energy (DOE) collaborated with other Federal agencies to develop a Strategy to Reduce Methane Emissions, which was formally announced by the White House last month. To advance this strategy, DOE is now working with other Federal agencies and the White

  18. State-of-the-art in coalbed methane drilling fluids

    SciTech Connect (OSTI)

    Baltoiu, L.V.; Warren, B.K.; Natras, T.A.

    2008-09-15

    The production of methane from wet coalbeds is often associated with the production of significant amounts of water. While producing water is necessary to desorb the methane from the coal, the damage from the drilling fluids used is difficult to assess, because the gas production follows weeks to months after the well is drilled. Commonly asked questions include the following: What are the important parameters for drilling an organic reservoir rock that is both the source and the trap for the methane? Has the drilling fluid affected the gas production? Are the cleats plugged? Does the 'filtercake' have an impact on the flow of water and gas? Are stimulation techniques compatible with the drilling fluids used? This paper describes the development of a unique drilling fluid to drill coalbed methane wells with a special emphasis on horizontal applications. The fluid design incorporates products to match the delicate surface chemistry on the coal, a matting system to provide both borehole stability and minimize fluid losses to the cleats, and a breaker method of removing the matting system once drilling is completed. This paper also discusses how coal geology impacts drilling planning, drilling practices, the choice of drilling fluid, and completion/stimulation techniques for Upper Cretaceous Mannville-type coals drilled within the Western Canadian Sedimentary Basin. A focus on horizontal coalbed methane (CBM) wells is presented. Field results from three horizontal wells are discussed, two of which were drilled with the new drilling fluid system. The wells demonstrated exceptional stability in coal for lengths to 1000 m, controlled drilling rates and ease of running slotted liners. Methods for, and results of, placing the breaker in the horizontal wells are covered in depth.

  19. INVESTIGATION OF HOLOCENE FAULTING PROPOSED C-746-U LANDFILL EXPANSION

    SciTech Connect (OSTI)

    Lettis, William

    2006-07-01

    This report presents the findings of a fault hazard investigation for the C-746-U landfill's proposed expansion located at the Department of Energy's (DOE) Paducah Gaseous Diffusion Plant (PGDP), in Paducah, Kentucky. The planned expansion is located directly north of the present-day C-746-U landfill. Previous geophysical studies within the PGDP site vicinity interpret possible northeast-striking faults beneath the proposed landfill expansion, although prior to this investigation the existence, locations, and ages of these inferred faults have not been confirmed through independent subsurface exploration. The purpose of this investigation is to assess whether or not Holocene-active fault displacement is present beneath the footprint of the proposed landfill expansion.

  20. Sandia National Laboratories: No More Green Waste in the Landfill

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    No More Green Waste in the Landfill June 09, 2011 Dump Truck Image On the heels of Sandia National Laboratories' successful food waste composting program, Pollution Prevention (P2)...

  1. Briefing: Summary and Recommendations of EM Landfill Workshop...

    Broader source: Energy.gov (indexed) [DOE]

    The briefing is an independent technical review report from the summary and recommendations of the EM Landfill Workshop help in October 2008. By: Craig H. Bendson, PhD, PE; William ...

  2. Development and utilization strategies for recovery and utilization of coal mine methane

    SciTech Connect (OSTI)

    Byrer, C.W.; Layne, A.W.; Guthrie, H.D.

    1995-10-01

    The U.S. Department of Energy (DOE), at its Morgantown Energy Technology Center, has been involved in natural gas research since the 1970`s. DOE has assessed the potential of gas in coals throughout the U.S. and promoted research and development for recovery and use of methane found in minable and unminable coalbeds. DOE efforts have focused on the use of coal mine methane for regional economic gas self-sufficiency, energy parks, self-help initiatives, and small-power generation. This paper focuses on DOE`s past and present efforts to more effectively and efficiently recover and use this valuable domestic energy source. The Climate Change Action Plan (CCAP) (1) lists a series of 50 voluntary initiatives designed to reduce greenhouse gas emissions, such as methane from mining operations, to their 1990 levels. Action No. 36 of the CCAP expands the DOE research, development, and demonstration (RD&D) efforts to broaden the range of cost-effective technologies and practices for recovering methane associated with coal mining operations. The major thrust of Action No. 36 is to reduce methane emissions associated with coal mining operations from target year 2000 levels by 1.5 MMT of carbon equivalent. Crosscutting activities in the DOE Natural Gas Program supply the utilization sectors will address RD&D to reduce methane emissions released from various mining operations, focusing on recovery and end use technology systems to effectively drain, capture, and utilize the emitted gas. Pilot projects with industry partners will develop and test the most effective methods and technology systems for economic recovery and utilization of coal mine gas emissions in regions where industry considers efforts to be presently non-economic. These existing RD&D programs focus on near-term gas recovery and gathering systems, gas upgrading, and power generation.

  3. Natural Gas Modernization Clearinghouse | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modernization Clearinghouse Natural Gas Modernization Clearinghouse Overview This Natural Gas Modernization Clearinghouse provides information about the implications of natural gas infrastructure modernization, including strategies and technologies that increase public safety, improve efficiency and environmental performance and enhance natural gas deliverability. Specific topic areas include information on measuring and reducing methane emissions, technology research and development, job

  4. Sandia National Laboratories: No More Green Waste in the Landfill

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    No More Green Waste in the Landfill June 09, 2011 Dump Truck Image On the heels of Sandia National Laboratories' successful food waste composting program, Pollution Prevention (P2) has teamed with the Facilities' Grounds and Roads team and the Solid Waste Transfer Facility to implement green waste composting. Previously, branches and logs were being diverted and mulched by Kirtland Air Force Base at their Construction & Demolition Landfill that is on base and utilized under contract by

  5. Climate Change Adaptation Technical Fact Sheet: Landfills and Containment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    as an Element of Site Remediation | Department of Energy Landfills and Containment as an Element of Site Remediation Climate Change Adaptation Technical Fact Sheet: Landfills and Containment as an Element of Site Remediation This fact sheet addresses contaminated site remedies involving source containment systems. It is intended to serve as an adaptation planning tool by (1) providing an overview of potential climate change vulnerabilities and (2) presenting possible adaptation measures that

  6. Computer Modeling of Saltstone Landfills by Intera Environmental Consultants

    SciTech Connect (OSTI)

    Albenesius, E.L.

    2001-08-09

    This report summaries the computer modeling studies and how the results of these studies were used to estimate contaminant releases to the groundwater. These modeling studies were used to improve saltstone landfill designs and are the basis for the current reference design. With the reference landfill design, EPA Drinking Water Standards can be met for all chemicals and radionuclides contained in Savannah River Plant waste salts.

  7. DOE - Office of Legacy Management -- Woburn Landfill - MA 07

    Office of Legacy Management (LM)

    Woburn Landfill - MA 07 FUSRAP Considered Sites Site: Woburn Landfill (MA.07) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Woburn , Massachusetts MA.07-2 Evaluation Year: 1987 MA.07-6 Site Operations: The National Lead Company, Inc. disposed of approximately fifty 55-gallon drums of low grade uranium ore in at this site in 1960. MA.07-2 MA.07-4 Site Disposition: Eliminated - Conditions determined meet applicable requirements

  8. Methane Hydrate Advisory Committee Charter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charter Methane Hydrate Advisory Committee Charter Methane Hydrate Advisory Committee Charter PDF icon Methane Hydrate Advisory Committee Charter More Documents & Publications ...

  9. May 15, 2014 Methane Hydrates Committee Meeting Agenda | Department...

    Office of Environmental Management (EM)

    May 15, 2014 Methane Hydrates Committee Meeting Agenda May 15, 2014 Methane Hydrates Committee Meeting Agenda May 15, 2014 Methane Hydrates Committee Meeting Agenda PDF icon...

  10. Methane Hydrate Advisory Committee Meeting Minutes, March 2010...

    Energy Savers [EERE]

    March 2010 Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane Hydrate Advisory Committee Meeting Minutes March 2010 Washington, DC PDF icon Methane Hydrate...

  11. Methane Hydrate Advisory Committee Meeting Minutes, January 2010...

    Broader source: Energy.gov (indexed) [DOE]

    0 Atlanta, GA Methane Hydrate Advisory Committee Meeting Minutes, January 2010 More Documents & Publications Methane Hydrate Advisory Committee Meeting Minutes, March 2010 Methane...

  12. Methane Hydrate Advisory Committee Meeting Minutes, June 6th...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee Meeting Minutes, June 6th-7th, 2013 Methane Hydrate Advisory Committee...

  13. China United Coalbed Methane Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Coalbed Methane Co Ltd Jump to: navigation, search Name: China United Coalbed Methane Co Ltd Place: Beijing Municipality, China Zip: 100011 Product: Coal bed methane developer in...

  14. Metro Methane Recovery Facility Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Methane Recovery Facility Biomass Facility Jump to: navigation, search Name Metro Methane Recovery Facility Biomass Facility Facility Metro Methane Recovery Facility Sector Biomass...

  15. New Mexico Coalbed Methane Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Production (Billion Cubic Feet) New Mexico Coalbed Methane Production (Billion Cubic Feet) ... Referring Pages: Coalbed Methane Estimated Production New Mexico Coalbed Methane Proved ...

  16. New Mexico Coalbed Methane Proved Reserves (Billion Cubic Feet...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Proved Reserves (Billion Cubic Feet) New Mexico Coalbed Methane Proved Reserves (Billion ... Coalbed Methane Proved Reserves as of Dec. 31 New Mexico Coalbed Methane Proved Reserves, ...

  17. North Dakota Coalbed Methane Proved Reserves (Billion Cubic Feet...

    U.S. Energy Information Administration (EIA) Indexed Site

    North Dakota Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 ... Coalbed Methane Proved Reserves as of Dec. 31 North Dakota Coalbed Methane Proved ...

  18. Methane Hydrate Research and Development Act of 2000 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 Methane Hydrate Research and Development Act of 2000 PDF icon Methane Hydrate Research and ...

  19. Methane generation from animal wastes

    SciTech Connect (OSTI)

    Fulton, E.L.

    1980-06-01

    The conversion of manure to biogas via anaerobic digestion is described. The effluent resulting from the conversion retains fertilizer value and is environmentally acceptable. Discussion is presented under the headings: methane formation in the digester; the Tarleton State Poultry Waste to Methane production system; operating experience at Tarleton State; economics of biogas production from poultry waste; construction cost and biogas value; energy uses; feed and waste processing; and advantages of anaerobic digestion. (DMC)

  20. Valuing the ozone-related health benefits of methane emission controls

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sarofim, Marcus C.; Waldhoff, Stephanie T.; Anenberg, Susan C.

    2015-06-29

    Methane is a greenhouse gas that oxidizes to form ground-level ozone, itself a greenhouse gas and a health-harmful air pollutant. Reducing methane emissions will both slow anthropogenic climate change and reduce ozone-related mortality. We estimate the benefits of reducing methane emissions anywhere in the world for ozone-related premature mortality globally and for eight geographic regions. Our methods are consistent with those used by the US Government to estimate the social cost of carbon (SCC). We find that the global short- and long-term premature mortality benefits due to reduced ozone production from methane mitigation are (2011) $790 and $1775 per tonnemore » methane, respectively. These correspond to approximately 70 and 150 % of the valuation of methane’s global climate impacts using the SCC after extrapolating from carbon dioxide to methane using global warming potential estimates. Results for monetized benefits are sensitive to a number of factors, particularly the choice of elasticity to income growth used when calculating the value of a statistical life. The benefits increase for emission years further in the future. Regionally, most of the global mortality benefits accrue in Asia, but 10 % accrue in the United States. As a result, this methodology can be used to assess the benefits of methane emission reductions anywhere in the world, including those achieved by national and multinational policies.« less

  1. Valuing the ozone-related health benefits of methane emission controls

    SciTech Connect (OSTI)

    Sarofim, Marcus C.; Waldhoff, Stephanie T.; Anenberg, Susan C.

    2015-06-29

    Methane is a greenhouse gas that oxidizes to form ground-level ozone, itself a greenhouse gas and a health-harmful air pollutant. Reducing methane emissions will both slow anthropogenic climate change and reduce ozone-related mortality. We estimate the benefits of reducing methane emissions anywhere in the world for ozone-related premature mortality globally and for eight geographic regions. Our methods are consistent with those used by the US Government to estimate the social cost of carbon (SCC). We find that the global short- and long-term premature mortality benefits due to reduced ozone production from methane mitigation are (2011) $790 and $1775 per tonne methane, respectively. These correspond to approximately 70 and 150 % of the valuation of methane’s global climate impacts using the SCC after extrapolating from carbon dioxide to methane using global warming potential estimates. Results for monetized benefits are sensitive to a number of factors, particularly the choice of elasticity to income growth used when calculating the value of a statistical life. The benefits increase for emission years further in the future. Regionally, most of the global mortality benefits accrue in Asia, but 10 % accrue in the United States. As a result, this methodology can be used to assess the benefits of methane emission reductions anywhere in the world, including those achieved by national and multinational policies.

  2. Method and apparatus for recovering hydrogen from a feed comprising methane, ethylene, hydrogen and acetylene

    SciTech Connect (OSTI)

    O'Reilly, R.

    1985-01-08

    Hydrogen is recovered from a feed comprising methane, ethylene, hydrogen and acetylene by first cooling the feed and then scrubbing the cooled feed with a scrubbing liquid selected from the group consisting of liquid ethylene, liquid propane, liquid ethane and mixtures thereof to remove substantially all the acetylene. The scrubbed gas is then further cooled to condense the methane and ethylene leaving gaseous hydrogen as product.

  3. System dynamics of the competition of municipal solid waste to landfill, electricity, and liquid fuel in California

    SciTech Connect (OSTI)

    Westbrook, Jessica; Malczynski, Leonard A.; Manley, Dawn Kataoka

    2014-03-01

    A quantitative system dynamics model was created to evaluate the economic and environmental tradeoffs between biomass to electricity and to liquid fuel using MSW biomass in the state of California as a case study. From an environmental perspective, landfilling represents the worst use of MSW over time, generating more greenhouse gas (GHG) emissions compared to converting MSW to liquid fuel or to electricity. MSW to ethanol results in the greatest displacement of GHG emissions per dollar spent compared to MSW to electricity. MSW to ethanol could save the state of California approximately $60 billion in energy costs by 2050 compared to landfilling, while also reducing GHG emissions state-wide by approximately 140 million metric tons during that timeframe. MSW conversion to electricity creates a significant cost within the state's electricity sector, although some conversion technologies are cost competitive with existing renewable generation.

  4. Unconventional oil and gas (UOG) development and operations release...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office of Oil and Natural Gas Goals The Administration has set a goal to reduce methane emissions from the oil and gas sector by 40-45 percent from 2012 levels by 2025. Achieving ...

  5. Large-scale simulation of methane dissociation along the West Spitzbergen Margin

    SciTech Connect (OSTI)

    Reagan, M.T.; Moridis, G.J.

    2009-07-15

    Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of methane into the atmosphere. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope west of Spitsbergen could be an indication of this process, if the source of the methane can be confidently attributed to dissociating hydrates. In the first large-scale simulation study of its kind, we simulate shallow hydrate dissociation in conditions representative of the West Spitsbergen margin to test the hypothesis that the observed gas release originated from hydrates. The simulation results are consistent with this hypothesis, and are in remarkable agreement with the recently published observations. They show that shallow, low-saturation hydrate deposits, when subjected to temperature increases at the seafloor, can release significant quantities of methane, and that the releases will be localized near the landward limit of the top of the GHSZ. These results indicate the possibility that hydrate dissociation and methane release may be both a consequence and a cause of climate change.

  6. Performance of catalysts for CO removal by methanation

    SciTech Connect (OSTI)

    Oshiro, Hitoshi; Nagaya, Kiichi; Mitani, Koichi

    1996-12-31

    This report forms part of a joint study on a PEFC propulsion system for surface ships, summarized in a presentation to this Seminar, entitled {open_quotes}Study on a Polymer Electrolyte Fuel Cell (PEFC) Propulsion System for Surface Ships{close_quotes}, and which envisages application to a 1,500 DWT cargo vessel. The aspect treated here concerns an experiment in reducing by methanation to a level below 10 ppm the CO that is contained to around 1% in reformate gas.

  7. Thermal Conversion of Methane to Acetylene Final Report

    SciTech Connect (OSTI)

    Fincke, J.R.; Anderson, R.P.; Hyde, T.; Wright, R.; Bewley, R.; Haggard, D.C.; Swank, W.D.

    2000-01-31

    This report describes the experimental demonstration of a process for the direct thermal conversion of methane to acetylene. The process utilizes a thermal plasma heat source to dissociation products react to form a mixture of acetylene and hydrogen. The use of a supersonic expansion of the hot gas is investigated as a method of rapidly cooling (quenching) the product stream to prevent further reaction or thermal decomposition of the acetylene which can lower the overall efficiency of the process.

  8. Enhanced catalyst stability for cyclic co methanation operations

    DOE Patents [OSTI]

    Risch, Alan P.; Rabo, Jule A.

    1983-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is thereafter reacted with steam or hydrogen to form methane. Enhanced catalyst stability for long term, cyclic operation is obtained by the incorporation of an alkali or alkaline earth dopant in a silica binding agent added to the catalyst-support additive composition.

  9. Methane Hydrate Annual Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Reports Methane Hydrate Annual Reports Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of Methane Hydrate research. Listed are the Annual Reports per Fiscal Year. FY 14 Methane Hydrate Program Report to Congress (10.92 MB) FY 13 Methane Hydrates Annual Report to Congress (960.13 KB) FY 12 Methane Hydrates Annual Report to Congress (1.09 MB) FY 11 Methane Hydrates Annual Report to Congress (953.09 KB) FY

  10. Methane Hydrate Reservoir Simulator Code Comparison Study

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Annual Reports Methane Hydrate Annual Reports Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of Methane Hydrate research. Listed are the Annual Reports per Fiscal Year. FY 14 Methane Hydrate Program Report to Congress (10.92 MB) FY 13 Methane Hydrates Annual Report to Congress (960.13 KB) FY 12 Methane Hydrates Annual Report to Congress (1.09 MB) FY 11 Methane Hydrates Annual Report to Congress (953.09 KB) FY

  11. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Thomas E. Williams; Keith Millheim; Buddy King

    2004-06-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope drilled and cored a well The HOT ICE No.1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report.

  12. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Thomas E. Williams; Keith Millheim; Bill Liddell

    2005-03-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated and is

  13. Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water

    SciTech Connect (OSTI)

    David Kirchman

    2011-12-31

    The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (??Methane in the Arctic Shelf? or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (??metagenomes?). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially

  14. gas-hydrate-global-assessment | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas-hydrate-global-assessment Frozen Heat: A Global Outlook on Methane Hydrate cover of executive summary The United Nations Environmental Programme released this new, two-volume report in March 2015. Frozen Heat: A Global Outlook on Methane Hydrate details the science and history of gas hydrates, evaluates the current state of gas hydrate research, and explores the potential impact of this untapped natural gas source on the future global energy mix. An executive summary of report is also

  15. METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy Advisory Committee Charter - - - - ---- ---- ------ 1. Committee's Official Designation. Methane Hydrate Advisory...

  16. Oil & Gas Tech Center Breaks Ground in Oklahoma | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Oil & Gas Research Methane Hydrate R&amp;D Methane Hydrate R&D DOE is conducting groundbreaking research to unlock the energy potential of gas hydrates. Read more Unconventional Oil and Natural Gas Unconventional Oil and Natural Gas DOE highlights research results from the unconventional oil and natural gas program. Read more FE's Office of Oil & Natural Gas supports research and policy options to ensure environmentally sustainable domestic and global supplies of oil and

  17. EIA - Natural Gas Pipeline System - Southeast Region

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Island and a new 875 MW natural gas fired power plant located in southeastern South Carolina. ... also from the developing coal-bed methane production sources in the State as well. ...

  18. Risk mitigation methodology for solid waste landfills. Doctoral thesis

    SciTech Connect (OSTI)

    Nixon, W.B.

    1995-05-01

    Several recent models have attempted to simulate or assess the probability and consequences of the leakage of aqueous contaminant leakage from solid waste landfills. These models incorporate common factors, including climatological and geological characteristics. Each model, however, employs a unique approach to the problem, assigns different relative weights to factors, and relies upon extrapolated small-scale experimental data and/or subjective judgment in predicting the full-scale landfill failure mechanisms leading to contaminant migration. As a result, no two models are likely to equally assess a given landfill, and no one model has been validated as a predictor of long-term performance. The United States Air Force maintains a database for characterization of potential hazardous waste sites. Records include more than 500 landfills, providing such information as waste, soil, aquifer, monitoring location data, and the results of sample testing. Through analysis of this information, nearly 300 landfills were assessed to have sufficiently, partially, or inadequately contained hazardous constituents of the wastes placed within them.

  19. File:Methane.pdf | Open Energy Information

    Open Energy Info (EERE)

    Methane.pdf Jump to: navigation, search File File history File usage File:Methane.pdf Size of this preview: 448 600 pixels. Go to page 1 2 3 4 5 Go next page next page ...

  20. Miscellaneous States Coalbed Methane Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Coalbed Methane Proved Reserves (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 ...

  1. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  2. Coalbed methane could cut India`s energy deficit

    SciTech Connect (OSTI)

    Kelafant, J.; Stern, M.

    1998-05-25

    Foreign interest in upcoming Indian coalbed methane (CBM) concession rounds will depend on prospect quality, fiscal regime attractiveness, and perceptions interested parties will have concerning the government`s willingness to promote development. The more liberal tax and royalty provisions for foreign producers announced by the ministry of Petroleum and Natural Gas indicate that India is interested in attracting international CBM investments. This article examines the potential for developing the country`s large CBM resource base, estimated between 30 tcf (250 billion cu m) and 144 tcf (4 trillion cu m) of gas. It also provides an overview of the current contractual and regulatory framework governing CBM development.

  3. Method for the photocatalytic conversion of methane

    DOE Patents [OSTI]

    Noceti, R.P.; Taylor, C.E.; D`Este, J.R.

    1998-02-24

    A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time. 3 figs.

  4. Methane Hydrate Production Feasibility | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Feasibility Methane Hydrate Production Feasibility The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the area of methane hydrate stability. The red curves are temperature profiles for various water depths; the blue line shows methane hydrate stability relative to temperature and pressure. The area enclosed by the two curves represents the

  5. Method for the photocatalytic conversion of methane

    DOE Patents [OSTI]

    Noceti, Richard P.; Taylor, Charles E.; D'Este, Joseph R.

    1998-01-01

    A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.

  6. Semi-annual report for the unconventional gas recovery program, period ending September 30, 1980

    SciTech Connect (OSTI)

    Manilla, R.D.

    1980-11-01

    Progress is reported in research on methane recovery from coalbeds, eastern gas shales, western gas sands, and geopressured aquifers. In the methane from coalbeds project, data on information evaluation and management, resource and site assessment and characterization, model development, instrumentation, basic research, and production technology development are reported. In the methane from eastern gas shales project, data on resource characterization and inventory, extraction technology, and technology testing and verification are presented. In the western gas sands project, data on resource assessments, field tests and demonstrations and project management are reported. In the methane from geopressured aquifers project, data on resource assessment, supporting research, field tests and demonstrations, and technology transfer are reported.

  7. Methane enrichment digestion experiments at the anaerobic experimental test unit at Walt Disney World. Final report, March 1989-August 1990

    SciTech Connect (OSTI)

    Srivastava, V.J.; Hill, A.H.

    1993-06-01

    The goal of the project was to determine the technical feasibility of utilizing a novel concept in anaerobic digestion, in-situ methane enrichment digestion or MED for producing utility-grade gas from a pilot-scale anaerobic digester. MED tests conducted during this program consistently achieved digester product gas with a methane (CH4) content of greater than 90% (on a dry-, nitrogen-free basis). The MED concept, because it requires relatively simple equipment and modest energy input, has the potential to simplify gas cleanup requirements and substantially reduce the cost of converting wastes and biomass to pipeline quality gas.

  8. OXIDATIVE COUPLING OF METHANE USING INORGANIC MEMBRANE REACTORS

    SciTech Connect (OSTI)

    Dr. Y.H. Ma; Dr. W.R. Moser; Dr. A.G. Dixon; Dr. A.M. Ramachandra; Dr. Y. Lu; C. Binkerd

    1998-04-01

    The objective of this research is to study the oxidative coupling of methane in catalytic inorganic membrane reactors. A specific target is to achieve conversion of methane to C{sub 2} hydrocarbons at very high selectivity and higher yields than in conventional non-porous, co-feed, fixed bed reactors by controlling the oxygen supply through the membrane. A membrane reactor has the advantage of precisely controlling the rate of delivery of oxygen to the catalyst. This facility permits balancing the rate of oxidation and reduction of the catalyst. In addition, membrane reactors minimize the concentration of gas phase oxygen thus reducing non selective gas phase reactions, which are believed to be a main route for the formation of CO{sub x} products. Such gas phase reactions are a cause of decreased selectivity in the oxidative coupling of methane in conventional flow reactors. Membrane reactors could also produce higher product yields by providing better distribution of the reactant gases over the catalyst than the conventional plug flow reactors. Membrane reactor technology also offers the potential for modifying the membranes both to improve catalytic properties as well as to regulate the rate of the permeation/diffusion of reactants through the membrane to minimize by-product generation. Other benefits also exist with membrane reactors, such as the mitigation of thermal hot-spots for highly exothermic reactions such as the oxidative coupling of methane. The application of catalytically active inorganic membranes has potential for drastically increasing the yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity.

  9. A Long Term Field Emissions Study of Natural Gas Fueled Refuse Haulers in New York City

    SciTech Connect (OSTI)

    Nigel N. Clark; Byron l. Rapp; Mridul Gautam; Wenguang Wang; Donald W. Lyons

    1998-10-19

    New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these was for street collection and transporting the refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines. Five trucks were equipped with electronically controlled Detroit Diesel Series 50 lean burn engines, while another five were powered by Caterpillar stoichiometric burn 3306 natural gas engines, The Ca terpillar engines employed an exhaust oxygen sensor feedback and three way catalysts. Since the refuse haulers had automatic Allison transmissions, and since they were employed in stop-and-go city service, initial emissions measurements were made using the Central Business Cycle (SAE Jl376) for buses at 42,000 pound test weight. Some additional measurements were made using an ad hoc cycle that has been designed to be more representative of the real refuse hauler use that included several compaction cycles. The Cummins powered natural gas vehicles showed oxides of nitrogen and carbon monoxide emission variations typically associated with variable fuel mixer performance. In the first Year of testing, the stoichiometric Caterpillar engines yielded low emission levels, but in later years two of these refuse haulers had high carbon monoxide attributed to failure of the feedback system. For example, carbon monoxide on these two vehicles rose from 1.4 g/mile and 10 g/mile in 1995 to 144.9 g

  10. Pathway analysis for a contaminated landfill in Middlesex, New Jersey

    SciTech Connect (OSTI)

    Yu, C.; Merry-Libby, P.; Yang, J.Y.

    1985-01-01

    Under the Formerly Utilized Sites Remedial Action Program, the US Department of Energy began excavating contaminated materials from the Middlesex Municipal landfill in 1984. A total of 16,000 mT of landfill materials covering a 0.2-ha area was excavated, of which 11,000 mT was contaminated and has been transported to the nearby sampling plant site for interim storage. Based on the pathway analysis for the onsite and near-site resident scenarios, the radiation dose rates and radionuclide concentrations in groundwater would be below the regulatory requirements for both the short-term and long-term scenarios. Hence, the potential health risks to maximally exposed individuals due to radioactive releases from the Middlesex landfill would be insignificant.

  11. Corrective Action Plan for Corrective Action Unit 424: Area 3 Landfill Complex, Tonopah Test Range, Nevada

    SciTech Connect (OSTI)

    Bechtel Nevada

    1998-08-31

    This corrective action plan provides the closure implementation methods for the Area 3 Landfill Complex, Corrective Action Unit (CAU) 424, located at the Tonopah Test Range. The Area 3 Landfill Complex consists of 8 landfill sites, each designated as a separate corrective action site.

  12. Patterns in wetland microbial community composition and functional gene repertoire associated with methane emissions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, Shaomei; Malfatti, Stephanie A.; McFarland, Jack W.; Anderson, Frank E.; Pati, Amrita; Huntemann, Marcel; Tremblay, Julien; Glavina del Rio, Tijana; Waldrop, Mark P.; Windham-Myers, Lisamarie; et al

    2015-05-19

    Wetland restoration on peat islands previously drained for agriculture has potential to reverse land subsidence and sequester atmospheric carbon dioxide as peat accretes. However, the emission of methane could potentially offset the greenhouse gas benefits of captured carbon. As microbial communities play a key role in governing wetland greenhouse gas fluxes, we are interested in how microbial community composition and functions are associated with wetland hydrology, biogeochemistry, and methane emission, which is critical to modeling the microbial component in wetland methane fluxes and to managing restoration projects for maximal carbon sequestration. Here, we couple sequence-based methods with biogeochemical and greenhousemore » gas measurements to interrogate microbial communities from a pilot-scale restored wetland in the Sacramento-San Joaquin Delta of California, revealing considerable spatial heterogeneity even within this relatively small site. A number of microbial populations and functions showed strong correlations with electron acceptor availability and methane production; some also showed a preference for association with plant roots. Marker gene phylogenies revealed a diversity of major methane-producing and -consuming populations and suggested novel diversity within methanotrophs. Methanogenic archaea were observed in all samples, as were nitrate-, sulfate-, and metal-reducing bacteria, indicating that no single terminal electron acceptor was preferred despite differences in energetic favorability and suggesting spatial microheterogeneity and microniches. Notably, methanogens were negatively correlated with nitrate-, sulfate-, and metal-reducing bacteria and were most abundant at sampling sites with high peat accretion and low electron acceptor availability, where methane production was highest. Wetlands are the largest nonanthropogenic source of atmospheric methane but also a key global carbon reservoir. Characterizing belowground microbial

  13. Patterns in wetland microbial community composition and functional gene repertoire associated with methane emissions

    SciTech Connect (OSTI)

    He, Shaomei; Malfatti, Stephanie A.; McFarland, Jack W.; Anderson, Frank E.; Pati, Amrita; Huntemann, Marcel; Tremblay, Julien; Glavina del Rio, Tijana; Waldrop, Mark P.; Windham-Myers, Lisamarie; Tringe, Susannah G.

    2015-05-19

    Wetland restoration on peat islands previously drained for agriculture has potential to reverse land subsidence and sequester atmospheric carbon dioxide as peat accretes. However, the emission of methane could potentially offset the greenhouse gas benefits of captured carbon. As microbial communities play a key role in governing wetland greenhouse gas fluxes, we are interested in how microbial community composition and functions are associated with wetland hydrology, biogeochemistry, and methane emission, which is critical to modeling the microbial component in wetland methane fluxes and to managing restoration projects for maximal carbon sequestration. Here, we couple sequence-based methods with biogeochemical and greenhouse gas measurements to interrogate microbial communities from a pilot-scale restored wetland in the Sacramento-San Joaquin Delta of California, revealing considerable spatial heterogeneity even within this relatively small site. A number of microbial populations and functions showed strong correlations with electron acceptor availability and methane production; some also showed a preference for association with plant roots. Marker gene phylogenies revealed a diversity of major methane-producing and -consuming populations and suggested novel diversity within methanotrophs. Methanogenic archaea were observed in all samples, as were nitrate-, sulfate-, and metal-reducing bacteria, indicating that no single terminal electron acceptor was preferred despite differences in energetic favorability and suggesting spatial microheterogeneity and microniches. Notably, methanogens were negatively correlated with nitrate-, sulfate-, and metal-reducing bacteria and were most abundant at sampling sites with high peat accretion and low electron acceptor availability, where methane production was highest. Wetlands are the largest nonanthropogenic source of atmospheric methane but also a key global carbon reservoir. Characterizing belowground microbial communities

  14. Utilization of coal mine methane for methanol and SCP production. Topical report, May 5, 1995--March 4, 1996

    SciTech Connect (OSTI)

    1998-12-31

    The feasibility of utilizing a biological process to reduce methane emissions from coal mines and to produce valuable single cell protein (SCP) and/or methanol as a product has been demonstrated. The quantities of coal mine methane from vent gas, gob wells, premining wells and abandoned mines have been determined in order to define the potential for utilizing mine gases as a resource. It is estimated that 300 MMCFD of methane is produced in the United States at a typical concentration of 0.2-0.6 percent in ventilation air. Of this total, almost 20 percent is produced from the four Jim Walter Resources (JWR) mines, which are located in very gassy coal seams. Worldwide vent gas production is estimated at 1 BCFD. Gob gas methane production in the U.S. is estimated to be 38 MMCFD. Very little gob gas is produced outside the U.S. In addition, it is estimated that abandoned mines may generate as much as 90 MMCFD of methane. In order to make a significant impact on coal mine methane emissions, technology which is able to utilize dilute vent gases as a resource must be developed. Purification of the methane from the vent gases would be very expensive and impractical. Therefore, the process application must be able to use a dilute methane stream. Biological conversion of this dilute methane (as well as the more concentrated gob gases) to produce single cell protein (SCP) and/or methanol has been demonstrated in the Bioengineering Resources, Inc. (BRI) laboratories. SCP is used as an animal feed supplement, which commands a high price, about $0.11 per pound.

  15. Techno-Economic Analysis of Bioconversion of Methane into Biofuel and Biochemical (Poster)

    SciTech Connect (OSTI)

    Fei, Q.; Tao, L.; Pienkos, P .T.; Guarnieri, M.; Palou-Rivera, I.

    2014-10-01

    In light of the relatively low price of natural gas and increasing demands of liquid transportation fuels and high-value chemicals, attention has begun to turn to novel biocatalyst for conversion of methane (CH4) into biofuels and biochemicals [1]. A techno-economic analysis (TEA) was performed for an integrated biorefinery process using biological conversion of methane, such as carbon yield, process efficiency, productivity (both lipid and acid), natural gas and other raw material prices, etc. This analysis is aimed to identify research challenges as well provide guidance for technology development.

  16. Potential Cost-Effective Opportunities for Methane Emission Abatement

    SciTech Connect (OSTI)

    Warner, Ethan; Steinberg, Daniel; Hodson, Elke; Heath, Garvin

    2015-08-01

    The energy sector was responsible for approximately 84% of carbon dioxide equivalent (CO2e) greenhouse gas (GHG) emissions in the U.S. in 2012 (EPA 2014a). Methane is the second most important GHG, contributing 9% of total U.S. CO2e emissions. A large portion of those methane emissions result from energy production and use; the natural gas, coal, and oil industries produce approximately 39% of anthropogenic methane emissions in the U.S. As a result, fossil-fuel systems have been consistently identified as high priority sectors to contribute to U.S. GHG reduction goals (White House 2015). Only two studies have recently attempted to quantify the abatement potential and cost associated with the breadth of opportunities to reduce GHG emissions within natural gas, oil, and coal supply chains in the United States, namely the U.S. Environmental Protection Agency (EPA) (2013a) and ICF (2014). EPA, in its 2013 analysis, estimated the marginal cost of abatement for non-CO2 GHG emissions from the natural gas, oil, and coal supply chains for multiple regions globally, including the United States. Building on this work, ICF International (ICF) (2014) provided an update and re-analysis of the potential opportunities in U.S. natural gas and oil systems. In this report we synthesize these previously published estimates as well as incorporate additional data provided by ICF to provide a comprehensive national analysis of methane abatement opportunities and their associated costs across the natural gas, oil, and coal supply chains. Results are presented as a suite of marginal abatement cost curves (MACCs), which depict the total potential and cost of reducing emissions through different abatement measures. We report results by sector (natural gas, oil, and coal) and by supply chain segment - production, gathering and boosting, processing, transmission and storage, or distribution - to facilitate identification of which sectors and supply chain

  17. Delineation of landfill migration boundaries using chemical surrogates

    SciTech Connect (OSTI)

    Thielen, D.R.; Foreman, P.S.; Davis, A.; Wyeth, R.

    1987-02-01

    A purge/trap procedures for the determination of monochlorobenzene and monochlorotoluene at the 10 ng/g level in soil is described. The advantages of a heated and stirred vessel for sample preparation are demonstrated. This method was applied to samples from the Hyde Park landfill site in Niagara Falls, NY, and the results were used to define chemical migration is illustrated with both two- and three-dimensional plotting techniques. This study is a first phase in the development of a remedial plan for the Hyde Park landfill.

  18. Sanitary Landfill Groundwater Monitoring Report. Second Quarter 1995

    SciTech Connect (OSTI)

    Chase, J.A.

    1995-08-01

    This report contains analytical data for samples taken during second quarter 1995 from wells of the LFW series located at the Sanitary Landfill at the Savannah River Site (SRS). The data are submitted in reference to the Sanitary landfill Operating Permit (DWP-087A). The report presents monitoring results that equaled or exceeded the Safe Drinking Water Act final Primary Water Standards (PDWS) or screening levels, established by the US Environmental Protection Agency (Appendix A), the South Carolina final Primary Drinking Water Standard for lead (Appendix A), or the SRS flagging criteria (Appendix B).

  19. Sanitary landfill groundwater monitoring report. Third quarter 1995

    SciTech Connect (OSTI)

    1995-11-01

    This report contains analytical data for samples taken during third quarter 1995 from wells of the LFW series located at the Sanitary Landfill at the Savannah River Site (SRS). The data are submitted in reference to the Sanitary Landfill Operating Permit (DWP-087A). The report presents monitoring results that equaled or exceeded the Safe Drinking Water Act final Primary Drinking Water Standards (PDWS) or screening levels, established by the U.S. Environmental Protection Agency, the South Carolina final Primary Drinking Water Standard for lead, or the SRS flagging criteria.

  20. A study of tritium in municipal solid waste leachate and gas

    SciTech Connect (OSTI)

    Mutch Jr, R. D.; Mahony, J. D.

    2008-07-15

    It has become increasingly clear in the last few years that the vast majority of municipal solid waste landfills produce leachate that contains elevated levels of tritium. The authors recently conducted a study of landfills in New York and New Jersey and found that the mean concentration of tritium in the leachate from ten municipal solid waste (MSW) landfills was 33,800 pCi/L with a peak value of 192,000 pCi/L. A 2003 study in California reported a mean tritium concentration of 99,000 pCi/L with a peak value of 304,000 pCi/L. Studies in Pennsylvania and the UK produced similar results. The USEPA MCL for tritium is 20,000 pCi/L. Tritium is also manifesting itself as landfill gas and landfill gas condensate. Landfill gas condensate samples from landfills in the UK and California were found to have tritium concentrations as high as 54,400 and 513,000 pCi/L, respectively. The tritium found in MSW leachate is believed to derive principally from gaseous tritium lighting devices used in some emergency exit signs, compasses, watches, and even novelty items, such as 'glow stick' key chains. This study reports the findings of recent surveys of leachate from a number of municipal solid waste landfills, both open and closed, from throughout the United States and Europe. The study evaluates the human health and ecological risks posed by elevated tritium levels in municipal solid waste leachate and landfill gas and the implications to their safe management. We also assess the potential risks posed to solid waste management facility workers exposed to tritium-containing waste materials in transfer stations and other solid waste management facilities. (authors)

  1. Assessing the Efficacy of the Aerobic Methanotrophic Biofilter in Methane Hydrate Environments

    SciTech Connect (OSTI)

    Valentine, David

    2012-09-30

    process as a biofilter by studying the distribution of methane oxidation and disposition of methanotrophic populations in the Pacific Ocean. We investigated several environments including the basins offshore California, the continental margin off Central America, and the shallow waters around gas seeps. We succeeded in identifying the distributions of activity in these environments, identified potential physical and chemical controls on methanotrophic activity, we further revealed details about the methanotrophic communities active in these settings, and we developed new approaches to study methanotrophic communities. These findings should improve our capacity to predict the methanotrophic response in ocean waters, and further our ability to generate specific hypotheses as to the ecology and efficacy of pelagic methanotrophic communites. The discharge of methane and other hydrocarbons to Gulf of Mexico that followed the sinking of the Deepwater Horizon provided a unique opportunity to study the methanotorphic biofilter in the deep ocean environment. We set out to understand the consumption of methane and the bloom of methanotrophs resulting from this event, as a window into the regional scale release of gas hydrate under rapid warming scenarios. We found that other hydrocarbon gases, notably propane and ethane, were preferred for consumption over methane, but that methane consumption accelerated rapidly and drove the depletion of methane within a matter of months after initial release. These results revealed the identity of the responsible community, and point to the importance of the seed population in determining the rate at which a methanotrophic community is able to respond to an input of methane. Collectively, these results provide a significant advance in our understanding of the marine methanotrohic biofilter, and further provide direction and context for future investigations of this important phenomenon. This project has resulted in fourteen publications to date

  2. Methane generation from waste materials

    SciTech Connect (OSTI)

    Samani, Zohrab A.; Hanson, Adrian T.; Macias-Corral, Maritza

    2010-03-23

    An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

  3. Methane production by attached film

    DOE Patents [OSTI]

    Jewell, William J.

    1981-01-01

    A method for purifying wastewater of biodegradable organics by converting the organics to methane and carbon dioxide gases is disclosed, characterized by the use of an anaerobic attached film expanded bed reactor for the reaction process. Dilute organic waste material is initially seeded with a heterogeneous anaerobic bacteria population including a methane-producing bacteria. The seeded organic waste material is introduced into the bottom of the expanded bed reactor which includes a particulate support media coated with a polysaccharide film. A low-velocity upward flow of the organic waste material is established through the bed during which the attached bacterial film reacts with the organic material to produce methane and carbon dioxide gases, purified water, and a small amount of residual effluent material. The residual effluent material is filtered by the film as it flows upwardly through the reactor bed. In a preferred embodiment, partially treated effluent material is recycled from the top of the bed to the bottom of the bed for further treatment. The methane and carbon dioxide gases are then separated from the residual effluent material and purified water.

  4. Methane ignition catalyzed by in situ generated palladium nanoparticles

    SciTech Connect (OSTI)

    Shimizu, T.; Abid, A.D.; Poskrebyshev, G.; Wang, H. [Department of Aerospace and Mechanical Engineering, University of Southern California, Los Angeles, CA 90089 (United States); Nabity, J.; Engel, J.; Yu, J. [TDA Research, Inc., 12345 W. 52nd Ave, Wheat Ridge, CO 80033 (United States); Wickham, D. [Reaction Systems, LLC, 19039 E. Plaza Drive, Suite 290, Parker, CO 80134 (United States); Van Devener, B.; Anderson, S.L. [Department of Chemistry, University of Utah, Salt Lake City, UT 84112 (United States); Williams, S. [Air Force Research Laboratory, Mail Stop RZA, 1950 Fifth Street, WPAFB, OH 45433 (United States)

    2010-03-15

    Catalytic ignition of methane over the surfaces of freely-suspended and in situ generated palladium nanoparticles was investigated experimentally and numerically. The experiments were conducted in a laminar flow reactor. The palladium precursor was a compound (Pd(THD){sub 2}, THD: 2,2,6,6-tetramethyl-3,5-heptanedione) dissolved in toluene and injected into the flow reactor as a fine aerosol, along with a methane-oxygen-nitrogen mixture. For experimental conditions chosen in this study, non-catalytic, homogeneous ignition was observed at a furnace temperature of {proportional_to}1123 K, whereas ignition of the same mixture with the precursor was found to be {proportional_to}973 K. In situ production of Pd/PdO nanoparticles was confirmed by scanning mobility, transmission electron microscopy and X-ray photoelectron spectroscopy analyses of particles collected at the reactor exit. The catalyst particle size distribution was log-normal. Depending on the precursor loading, the median diameter ranged from 10 to 30 nm. The mechanism behind catalytic ignition was examined using a combined gas-phase and gas-surface reaction model. Simulation results match the experiments closely and suggest that palladium nanocatalyst significantly shortens the ignition delay times of methane-air mixtures over a wide range of conditions. (author)

  5. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida; Del Paggio, Alan Anthony; Nair, Vijay; Roes, Augustinus Wilhelmus Maria

    2011-12-06

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  6. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Richard Sigal; Kent Newsham; Thomas Williams; Barry Freifeld; Timothy Kneafsey; Carl Sondergeld; Shandra Rai; Jonathan Kwan; Stephen Kirby; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. The work scope drilled and cored a well The Hot Ice No. 1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report. The Hot Ice No. 1 well was drilled from the surface to a measured depth of 2300 ft. There was almost 100% core recovery from the bottom of surface casing at 107 ft to total depth. Based on the best estimate of the bottom of the methane hydrate stability zone (which used new data obtained from Hot Ice No. 1 and new analysis of data from adjacent wells), core was recovered over its complete range. Approximately 580 ft of porous, mostly frozen, sandstone and 155 of conglomerate were recovered in the Ugnu Formation and approximately 215 ft of porous sandstone were recovered in the West Sak Formation. There were gas shows in the bottom

  7. Quantification of the Potential Gross Economic Impacts of Five Methane Reduction Scenarios

    SciTech Connect (OSTI)

    Keyser, David; Warner, Ethan; Curley, Christina

    2015-04-23

    Methane (CH4) is a potent greenhouse gas that is released from the natural gas supply chain into the atmosphere as a result of fugitive emissions1 and venting2 . We assess five potential CH4 reduction scenarios from transmission, storage, and distribution (TS&D) using published literature on the costs and the estimated quantity of CH4 reduced. We utilize cost and methane inventory data from ICF (2014) and Warner et al. (forthcoming) as well as data from Barrett and McCulloch (2014) and the American Gas Association (AGA) (2013) to estimate that the implementation of these measures could support approximately 85,000 jobs annually from 2015 to 2019 and reduce CH4 emissions from natural gas TS&D by over 40%. Based on standard input/output analysis methodology, measures are estimated to support over $8 billion in GDP annually over the same time period and allow producers to recover approximately $912 million annually in captured gas.

  8. INTEGRATED POWER GENERATION SYSTEMS FOR COAL MINE WASTE METHANE UTILIZATION

    SciTech Connect (OSTI)

    Peet M. Soot; Dale R. Jesse; Michael E. Smith

    2005-08-01

    An integrated system to utilize the waste coal mine methane (CMM) at the Federal No. 2 Coal Mine in West Virginia was designed and built. The system includes power generation, using internal combustion engines, along with gas processing equipment to upgrade sub-quality waste methane to pipeline quality standards. The power generation has a nominal capacity of 1,200 kw and the gas processing system can treat about 1 million cubic feet per day (1 MMCFD) of gas. The gas processing is based on the Northwest Fuel Development, Inc. (NW Fuel) proprietary continuous pressure swing adsorption (CPSA) process that can remove nitrogen from CMM streams. The two major components of the integrated system are synergistic. The byproduct gas stream from the gas processing equipment can be used as fuel for the power generating equipment. In return, the power generating equipment provides the nominal power requirements of the gas processing equipment. This Phase III effort followed Phase I, which was comprised of a feasibility study for the project, and Phase II, where the final design for the commercial-scale demonstration was completed. The fact that NW Fuel is desirous of continuing to operate the equipment on a commercial basis provides the validation for having advanced the project through all of these phases. The limitation experienced by the project during Phase III was that the CMM available to operate the CPSA system on a commercial basis was not of sufficiently high quality. NW Fuel's CPSA process is limited in its applicability, requiring a relatively high quality of gas as the feed to the process. The CPSA process was demonstrated during Phase III for a limited time, during which the processing capabilities met the expected results, but the process was never capable of providing pipeline quality gas from the available low quality CMM. The NW Fuel CPSA process is a low-cost ''polishing unit'' capable of removing a few percent nitrogen. It was never intended to process CMM

  9. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Ali Kadaster; Bill Liddell; Tommy Thompson; Thomas Williams; Michael Niedermayr

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and implemented for determining physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. Final efforts of the project are to correlate geology, geophysics, logs, and drilling and

  10. Mitigating the effect of siloxanes on internal combustion engines using landfill gasses

    DOE Patents [OSTI]

    Besmann, Theodore M

    2015-01-06

    A waste gas combustion method that includes providing a combustible fuel source, in which the combustible fuel source is composed of at least methane and siloxane gas. A sodium source or magnesium source is mixed with the combustible fuel source. Combustion of the siloxane gas of the combustible fuel source produces a silicon containing product. The sodium source or magnesium source reacts with the silicon containing product to provide a sodium containing glass or sodium containing silicate, or a magnesium containing silicate. By producing the sodium containing glass or sodium containing silicate, or the magnesium containing silicate, or magnesium source for precipitating particulate silica instead of hard coating, the method may reduce or eliminate the formation of silica deposits within the combustion chamber and the exhaust components of the internal combustion engine.

  11. Mitigating the effect of siloxanes on internal combustion engines using landfill gasses

    DOE Patents [OSTI]

    Besmann, Theodore M

    2014-01-21

    A waste gas combustion method that includes providing a combustible fuel source, in which the combustible fuel source is composed of at least methane and siloxane gas. A sodium source or magnesium source is mixed with the combustible fuel source. Combustion of the siloxane gas of the combustible fuel source produces a silicon containing product. The sodium source or magnesium source reacts with the silicon containing product to provide a sodium containing glass or sodium containing silicate, or a magnesium containing silicate. By producing the sodium containing glass or sodium containing silicate, or the magnesium containing silicate, or magnesium source for precipitating particulate silica instead of hard coating, the method may reduce or eliminate the formation of silica deposits within the combustion chamber and the exhaust components of the internal combustion engine.

  12. Nitrogen removal from natural gas using two types of membranes

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; Wijmans, Johannes G.; Da Costa, Andre R.

    2003-10-07

    A process for treating natural gas or other methane-rich gas to remove excess nitrogen. The invention relies on two-stage membrane separation, using methane-selective membranes for the first stage and nitrogen-selective membranes for the second stage. The process enables the nitrogen content of the gas to be substantially reduced, without requiring the membranes to be operated at very low temperatures.

  13. Story Road Landfill Solar Site Evaluation: San Jose

    Office of Energy Efficiency and Renewable Energy (EERE)

    This report describes the findings of a solar site evaluation conducted at the Story Road Landfill (Site) in the City of San Jose, California (City). This evaluation was conducted as part of a larger study to assess solar potential at multiple public facilities within the City.

  14. Sanitary landfill groundwater monitoring data. First quarter 1992

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-05-01

    This report for first quarter 1992 contains sanitary landfill groundwater monitoring data for the Savannah River Plant. The data tables presented in this report are copies of draft analytical results and therefore do contain errors. These errors will be corrected when the finalized data is received from the laboratory.

  15. Performance of paper mill sludges as landfill capping material

    SciTech Connect (OSTI)

    Moo-Young, H.K. Jr.; Zimmie, T.F.

    1997-12-31

    The high cost of waste containment has sparked interest in low cost and effective strategies of containing wastes. Paper mill sludges have been effectively used as the impermeable barrier in landfill covers. Since paper mill sludges are viewed as a waste material, the sludge is given to the landfill owner at little or no cost. Thus, when a clay soil is not locally available to use as the impermeable barrier in a cover system, paper sludge barriers can save $20,000 to $50,000 per acre in construction costs. This study looks at the utilization and performance of blended and primary paper sludge as landfill capping material. To determine the effectiveness of paper sludge as an impermeable barrier layer, test pads were constructed to simulate a typical landfill cover with paper sludge and clay as the impermeable barrier and were monitored for infiltration rates for five years. Long-term hydraulic conductivity values estimated from the leachate generation rates of the test pads indicate that paper sludge provides an acceptable hydraulic barrier.

  16. Organic carbon cycling in landfills: Model for a continuum approach

    SciTech Connect (OSTI)

    Bogner, J.; Lagerkvist, A.

    1997-09-01

    Organic carbon cycling in landfills can be addressed through a continuum model where the end-points are conventional anaerobic digestion of organic waste (short-term analogue) and geologic burial of organic material (long-term analogue). Major variables influencing status include moisture state, temperature, organic carbon loading, nutrient status, and isolation from the surrounding environment. Bioreactor landfills which are engineered for rapid decomposition approach (but cannot fully attain) the anaerobic digester end-point and incur higher unit costs because of their high degree of environmental isolation and control. At the other extreme, uncontrolled land disposal of organic waste materials is similar to geologic burial where organic carbon may be aerobically recycled to atmospheric CO{sub 2}, anaerobically converted to CH{sub 4} and CO{sub 2} during early diagenesis, or maintained as intermediate or recalcitrant forms into geologic time (> 1,000 years) for transformations via kerogen pathways. A family of improved landfill models are needed at several scales (molecular to landscape) which realistically address landfill processes and can be validated with field data.

  17. Turbulent burning rates of methane and methane-hydrogen mixtures

    SciTech Connect (OSTI)

    Fairweather, M. [School of Process, Environmental and Materials Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom); Ormsby, M.P.; Sheppard, C.G.W. [School of Mechanical Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom); Woolley, R. [Department of Mechanical Engineering, University of Sheffield, Sheffield S1 3JD (United Kingdom)

    2009-04-15

    Methane and methane-hydrogen (10%, 20% and 50% hydrogen by volume) mixtures have been ignited in a fan stirred bomb in turbulence and filmed using high speed cine schlieren imaging. Measurements were performed at 0.1 MPa (absolute) and 360 K. A turbulent burning velocity was determined for a range of turbulence velocities and equivalence ratios. Experimental laminar burning velocities and Markstein numbers were also derived. For all fuels the turbulent burning velocity increased with turbulence velocity. The addition of hydrogen generally resulted in increased turbulent and laminar burning velocity and decreased Markstein number. Those flames that were less sensitive to stretch (lower Markstein number) burned faster under turbulent conditions, especially as the turbulence levels were increased, compared to stretch-sensitive (high Markstein number) flames. (author)

  18. The Methane to Markets Coal Mine Methane Subcommittee meeting

    SciTech Connect (OSTI)

    2008-07-01

    The presentations (overheads/viewgraphs) include: a report from the Administrative Support Group; strategy updates from Australia, India, Italy, Mexico, Nigeria, Poland and the USA; coal mine methane update and IEA's strategy and activities; the power of VAM - technology application update; the emissions trading market; the voluntary emissions reduction market - creating profitable CMM projects in the USA; an Italian perspective towards a zero emission strategies; and the wrap-up and summary.

  19. Detection and Production of Methane Hydrate

    SciTech Connect (OSTI)

    George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

    2011-12-31

    This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes

  20. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and

  1. May 15, 2014 Methane Hydrates Committee Meeting Agenda | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy May 15, 2014 Methane Hydrates Committee Meeting Agenda May 15, 2014 Methane Hydrates Committee Meeting Agenda May 15, 2014 Methane Hydrates Committee Meeting Agenda Meeting Agenda (443.71 KB) More Documents & Publications Advisory Committee Meeting Minutes, May 7, 2015 Methane Hydrate Program Reports Report of the Task Force on Methane Hydrates

  2. DOE Launches Natural Gas Infrastructure R&D Program Enhancing Pipeline and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Distribution System Operational Efficiency, Reducing Methane Emissions | Department of Energy DOE Launches Natural Gas Infrastructure R&D Program Enhancing Pipeline and Distribution System Operational Efficiency, Reducing Methane Emissions DOE Launches Natural Gas Infrastructure R&D Program Enhancing Pipeline and Distribution System Operational Efficiency, Reducing Methane Emissions September 8, 2014 - 1:04pm Addthis Following the White House and the Department of Energy Capstone

  3. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions

    Broader source: Energy.gov (indexed) [DOE]

    This is a standard form to be used by awarding agencies to collect information related to tangible personal property (equipment and supplies) when required by a Federal financial assistance award. The form consists of the cover sheet (SF-428) and three attachments to be used as required: Annual Report, SF428-A; Final (Award Closeout) Report, SF-428-B; and a Disposition Request/Report, SF-428-C. A Supplemental Sheet, SF-428S, may be used to provide detailed individual item information. Tangible

  4. METHANE HYDRATE STUDIES: DELINEATING PROPERTIES OF HOST SEDIMENTS TO ESTABLISH REPRODUCIBLE DECOMPOSITION KINETICS.

    SciTech Connect (OSTI)

    Mahajan, Devinder; Jones, Keith W.; Feng, Huan; Winters, William J.

    2004-12-01

    The use of methane hydrate as an energy source requires development of a reliable method for its extraction from its highly dispersed locations in oceanic margin sediments and permafrost. The high pressure (up to 70 MPa) and low temperature (272 K to 278 K) conditions under which hydrates are stable in the marine environment can be mimicked in a laboratory setting and several kinetic studies of pure methane hydrate decomposition have been reported. However, the effect of host sediments on methane hydrate occurrence and decomposition are required to develop reliable hydrate models. In this paper, we describe methods to measure sediment properties as they relate to pore-space methane gas hydrate. Traditional geotechnical techniques are compared to the micrometer level by use of the synchrotron Computed Microtomography (CMT) technique. CMT was used to measure the porosity at the micrometer level and to show pore-space pathways through field samples. Porosities for three sediment samples: one from a site on Georges Bank and two from the known Blake Ridge methane hydrate site, from different depths below the mud line were measured by traditional drying and by the new CMT techniques and found to be in good agreement. The integration of the two analytical approaches is necessary to enable better understanding of methane hydrate interactions with the surrounding sediment particles.

  5. New materials for methane capture from dilute and medium-concentration sources

    SciTech Connect (OSTI)

    Kim, J; Maiti, A; Lin, LC; Stolaroff, JK; Smit, B; Aines, RD

    2013-04-16

    Methane (CH4) is an important greenhouse gas, second only to CO2, and is emitted into the atmosphere at different concentrations from a variety of sources. However, unlike CO2, which has a quadrupole moment and can be captured both physically and chemically in a variety of solvents and porous solids, methane is completely non-polar and interacts very weakly with most materials. Thus, methane capture poses a challenge that can only be addressed through extensive material screening and ingenious molecular-level designs. Here we report systematic in silico studies on the methane capture effectiveness of two different materials systems, that is, liquid solvents (including ionic liquids) and nanoporous zeolites. Although none of the liquid solvents appears effective as methane sorbents, systematic screening of over 87,000 zeolite structures led to the discovery of a handful of candidates that have sufficient methane sorption capacity as well as appropriate CH4/CO2 and/or CH4/N-2 selectivity to be technologically promising.

  6. METHOD FOR PRODUCING ISOTOPIC METHANES FROM LITHIUM CARBONATE AND LITHIUM HYDRIDE

    DOE Patents [OSTI]

    Frazer, J.W.

    1959-10-27

    A process is descrlbed for the production of methane and for the production of methane containing isotopes of hydrogen and/or carbon. Finely divided lithium hydrlde and litldum carbonate reactants are mixed in intimate contact and subsequently compacted under pressures of from 5000 to 60,000 psl. The compacted lithium hydride and lithium carbenate reactunts are dispised in a gas collecting apparatus. Subsequently, the compact is heated to a temperature in the range 350 to 400 deg C whereupon a solid-solid reaction takes place and gaseous methane is evolved. The evolved methane is contaminated with gaseous hydrogen and a very small amount of CO/sub 2/; however, the desired methane product is separated from sald impurities by well known chemical processes, e.g., condensation in a cold trap. The product methane contalns isotopes of carbon and hydrogen, the Isotopic composition being determined by the carbon isotopes originally present In the lithium carbonate and the hydrogen isotopes originally present in the lithium hydride.

  7. Effect of silane concentration on the supersonic combustion of a silane/methane mixture

    SciTech Connect (OSTI)

    Northam, G.B.; Mc Lain, A.G.; Pellett, G.L.; Diskin, G.S.

    1986-01-01

    A series of direct connect combustor tests was conducted to determine the effect of silane concentration on the supersonic combustion characteristics of silane/methane mixtures. Shock tube ignition delay data indicated more than an order of magnitude reduction in ignition delay times for both 10 and 20 percent silane/methane mixtures as compared to methane. The ignition delay time of the 10 percent mixture was only a factor of 2.3 greater than that of the 20 percent mixture. Supersonic combustion tests were conducted with the fuel injected into a model scramjet combustor. The combustor was mounted at the exit of a Mach 2 nozzle and a hydrogen fired heater was used to provide a variation in test gas total temperature. Tests using the 20 percent silane/methane mixture indicated considerable combustion enhancement when compared to methane alone. This mixture had an autoignition total temperature of 1650 R. The addition of 20 percent silane to methane resulted in a pyrophoric fuel with good supersonic combustion performance. Reducing the silane concentration below this level, however, yielded a less pyrophoric fuel that exhibited poor supersonic combustion performance.

  8. NREL Advancements in Methane Conversion Lead to Cleaner Air, Useful Products (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Researchers at NREL leveraged the recent on-site development of gas fermentation capabilities and novel genetic tools to directly convert methane to lactic acid using an engineered methanotrophic bacterium. Key Result The results provide proof-of-concept data for a gas-to-liquids bioprocess that concurrently produces fuels and chemicals from methane. NREL researchers developed genetic tools to express heterologous genes in methanotrophic organisms, which have historically been difficult to

  9. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A.; Dugan, Patrick R.

    1995-01-01

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  10. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A.; Dugan, Patrick R.

    1995-04-04

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  11. Methane Hydrate Program Annual Report to Congress

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FY 2010 Methane Hydrate Program Annual Report to Congress September 2011 U.S. Department of ENERGY United States Department of Energy Washington, DC 20585 Department of Energy | September 2011 FY 2010 Methane Hydrate Program Annual Report to Congress | Page 2 Message from the Secretary Section 968 of the Energy Policy Act of 2005 requires the Department of Energy to submit to Congress an annual report on the results of methane hydrate research. I am pleased to submit the enclosed report

  12. Measurements of particulate matter concentrations at a landfill site (Crete, Greece)

    SciTech Connect (OSTI)

    Chalvatzaki, E.; Kopanakis, I.; Kontaksakis, M.; Glytsos, T.; Kalogerakis, N.; Lazaridis, M.

    2010-11-15

    Large amounts of solid waste are disposed in landfills and the potential of particulate matter (PM) emissions into the atmosphere is significant. Particulate matter emissions in landfills are the result of resuspension from the disposed waste and other activities such as mechanical recycling and composting, waste unloading and sorting, the process of coating residues and waste transport by trucks. Measurements of ambient levels of inhalable particulate matter (PM{sub 10}) were performed in a landfill site located at Chania (Crete, Greece). Elevated PM{sub 10} concentrations were measured in the landfill site during several landfill operations. It was observed that the meteorological conditions (mainly wind velocity and temperature) influence considerably the PM{sub 10} concentrations. Comparison between the PM{sub 10} concentrations at the landfill and at a PM{sub 10} background site indicates the influence of the landfill activities on local concentrations at the landfill. No correlation was observed between the measurements at the landfill and the background sites. Finally, specific preventing measures are proposed to control the PM concentrations in landfills.

  13. Passive soil venting at the Chemical Waste Landfill Site at Sandia National Laboratories, Albuquerque, New Mexico

    SciTech Connect (OSTI)

    Phelan, J.M.; Reavis, B.; Cheng, W.C.

    1995-05-01

    Passive Soil Vapor Extraction was tested at the Chemical Waste Landfill (CWL) site at Sandia National Laboratories, New Mexico (SNLIW). Data collected included ambient pressures, differential pressures between soil gas and ambient air, gas flow rates into and out of the soil and concentrations of volatile organic compounds (VOCS) in vented soil gas. From the differential pressure and flow rate data, estimates of permeability were arrived at and compared with estimates from other studies. Flow, differential pressure, and ambient pressure data were collected for nearly 30 days. VOC data were collected for two six-hour periods during this time. Total VOC emissions were calculated and found to be under the limit set by the Resource Conservation and Recovery Act (RCRA). Although a complete process evaluation is not possible with the data gathered, some of the necessary information for designing a passive venting process was determined and the important parameters for designing the process were indicated. More study is required to evaluate long-term VOC removal using passive venting and to establish total remediation costs when passive venting is used as a polishing process following active soil vapor extraction.

  14. Seasonal Production and Emission of Methane from Rice Fields, Final Report

    SciTech Connect (OSTI)

    Khalil, M. Aslam K.; Rasmussen,Reinhold A.

    2002-12-03

    B 139 - Methane (CH4) is a greenhouse gas regarded second only to carbon dioxide in its ability to cause global warming. Methane is important because of its relatively fast increase, and also because it is, per molecule, some 60 times more effective than carbon dioxide in causing global warming. The largest present anthropogenic sources of methane are rice fields, cattle and biomass burning. The global emissions from these sources are still not well known. In the middle 1980s there were few available data on methane emissions from rice fields leading to estimates of a global source between 100-280 Tg/yr. Extensive worldwide research during the last decade has shown that the global emissions from rice fields are more likely to be in the range of 30-80Tg/yr. While this work has led to a substantial reduction in the estimated emissions, the uncertainty is still quite large, and seriously affects our ability to include methane in integrated assessments for future climate change and environmental management.China dominated estimates of methane emissions from rice fields because it was, and is, the largest producer of rice, and major increases in rice production had taken place in the country over the last several decades. This report summarizes the work in Sichuan Province, China, in each of the following areas: the design of the experiment; the main results on methane emissions from rice fields, delineating the factors controlling emissions; production of methane in the soil; a survey of water management practices in sample of counties in Sichuan province; and results of ambient measurements including data from the background continental site. B139

  15. Modeling Methane Adsorption in Interpenetrating Porous Polymer...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling Methane Adsorption in Interpenetrating Porous Polymer Networks Previous Next List Richard L. Martin, Mahdi Niknam Shahrak, Joseph A. Swisher, Cory M. Simon, Julian P....

  16. Cyclic process for producing methane with catalyst regeneration

    DOE Patents [OSTI]

    Frost, Albert C.; Risch, Alan P.

    1980-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. For practical commercial operations utilizing the two-step process of the invention of a cyclic basis, nickel, cobalt, ruthenium, thenium and alloys thereof are especially prepared for use in a metal state, with CO disproportionation being carried out at temperatures up to about 350.degree. C. and with the conversion of active surface carbon to methane being carried out by reaction with steam. The catalyst is employed in such cyclic operations without the necessity for employing a regeneration step as part of each processing cycle. Inactive carbon or coke that tends to form on the catalyst over the course of continuous operations utilizing such cyclic process is effectively and advantageously removed, on a periodic basis, in place of conventional burn off with an inert stream containing a low concentration of oxygen.

  17. Extension - Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption

    SciTech Connect (OSTI)

    Anna Lee Tonkovich

    2008-08-11

    The need for cost effective technologies for upgrading coal mine methane to pipeline quality natural gas is becoming ever greater. The current work presents and investigates a new approach to reduce the impact of the most costly step in the conventional technology, nitrogen rejection. The proposed approach is based on the Velocys microchannel platform, which is being developed to commercialize compact and cost efficient chemical processing technology. For this separation, ultra fast thermal swing sorption is enabled by the very high rates of heat and mass transfer inherent in microchannel processing. In a first phase of the project solid adsorbents were explored. Feasibility of ultrafast thermal swing was demonstrated but the available adsorbents had insufficient differential methane capacity to achieve the required commercial economics. In a second phase, ionic liquids were adopted as absorbents of choice, and experimental work and economic analyses, performed to gauge their potential, showed promise for this novel alternative. Final conclusions suggest that a combination of a required cost target for ionic liquids or a methane capacity increase or a combination of both is required for commercialization.

  18. New Methane Hydrate Research: Investing in Our Energy Future...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Methane Hydrate Research: Investing in Our Energy Future New Methane Hydrate Research: Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ...

  19. Four Corners methane hotspot points to coal-related sources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane hotspot points to coal-related sources Four Corners methane hotspot points to coal-related sources Methane is very efficient at trapping heat in the atmosphere and, like ...

  20. Sanitary landfill groundwater monitoring report. First Quarter 1995

    SciTech Connect (OSTI)

    1995-06-01

    This report contains analytical data for samples taken during first quarter 1994 from wells of the LFW series located at the Sanitary Landfill Operating permit (DWP-0874A). The report presents monitoring results that equaled or exceeded the Safe Drinking Water Act final Primary Drinking Water Standards (PDWS) or screening levels, established by the US Environmental Protection Agency, the South Carolina final Primary Drinking Water Standard for lead, or the SRS flagging criteria.

  1. Inferred performance of surface hydraulic barriers from landfill operational data

    SciTech Connect (OSTI)

    Gross, B.A.; Bonaparte, R.; Othman, M.A.

    1997-12-31

    There are few published data on the field performance of surface hydraulic barriers (SHBs) used in waste containment or remediation applications. In contrast, operational data for liner systems used beneath landfills are widely available. These data are frequently collected and reported as a facility permit condition. This paper uses leachate collection system (LCS) and leak detection system (LDS) liquid flow rate and chemical quality data collected from modem landfill double-liner systems to infer the likely hydraulic performance of SHBs. Operational data for over 200 waste management unit liner systems are currently being collected and evaluated by the authors as part of an ongoing research investigation for the United States Environmental Protection Agency (USEPA). The top liner of the double-liner system for the units is either a geomembrane (GMB) alone, geomembrane overlying a geosynthetic clay liner (GMB/GCL), or geomembrane overlying a compacted clay liner (GMB/CCL). In this paper, select data from the USEPA study are used to: (i) infer the likely efficiencies of SHBs incorporating GMBs and overlain by drainage layers; and (ii) evaluate the effectiveness of SHBs in reducing water infiltration into, and drainage from, the underlying waste (i.e., source control). SHB efficiencies are inferred from calculated landfill liner efficiencies and then used to estimate average water percolation rates through SHBs as a function of site average annual rainfall. The effectiveness of SHBs for source control is investigated by comparing LCS liquid flow rates for open and closed landfill cells. The LCS flow rates for closed cells are also compared to the estimated average water percolation rates through SHBs presented in the paper.

  2. Sanitary Landfill Groundwater Monitoring Report (Data Only) - First Quarter 1999

    SciTech Connect (OSTI)

    Chase, J.

    1999-05-26

    This report contains analytical data for samples taken during First Quarter 1999 from wells of the LFW series located at the Sanitary Landfill at the Savannah River Site (SRS). This report presents monitoring results that equaled or exceeded the Safe Drinking Water Act final Primary Drinking Water Standards or screening levels, established by the U.S. Environmental Proteciton Agency, the South Carolina final Primary Drinking Water Standard for lead, or the SRS flagging criteria.

  3. Hazardous waste site assessment: Inactive landfill, Site 300, Lawrence Livermore National Laboratory

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    This report presents the results of an investigation of an inactive landfill (Pit 6) at Lawrence Livermore National Laboratory's (LLNL) Site 300. The primary objectives were to: collect and review background information pertaining to past waste disposal practices and previous environmental characterization studies; conduct a geophysical survey of the landfill area to locate the buried wastes; conduct a hydrogeologic investigation to provide additional data on the rate and direction of groundwater flow, the extent of any groundwater contamination, and to investigate the connection, if any, of the shallow groundwater beneath the landfill with the local drinking water supply; conduct a risk assessment to identify the degree of threat posed by the landfill to the public health and environment; compile a preliminary list of feasible long-term remedial action alternatives for the landfill; and develop a list of recommendations for any interim measures necessary at the landfill should the long-term remedial action plan be needed.

  4. Data from Innovative Methane Hydrate Test on Alaska's North Slope...

    Office of Environmental Management (EM)

    Data from Innovative Methane Hydrate Test on Alaska's North Slope Now Available on NETL Website Data from Innovative Methane Hydrate Test on Alaska's North Slope Now Available on ...

  5. Methane Hydrate Advisory Committee Meetings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meetings Methane Hydrate Advisory Committee Meetings May 7, 2015 Advisory Committee ... Federal Register Notice for May 15, 2014 Meeting Methane Hydrates Committee Meeting Agenda ...

  6. Estimating global and North American methane emissions with high...

    Office of Scientific and Technical Information (OSTI)

    methane emissions with high spatial resolution using GOSAT satellite data Citation Details In-Document Search Title: Estimating global and North American methane emissions ...

  7. Methane Hydrate Advisory Committee Meeting Minutes, October 2011...

    Office of Environmental Management (EM)

    October 2011 Methane Hydrate Advisory Committee Meeting Minutes, October 2011 Methane Hydrate Advisory Committee Meeting Minutes October 2011 Washington, DC PDF icon Advisory...

  8. New York Coalbed Methane Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Release Date: 11192015 Next Release Date: 12312016 Referring Pages: Coalbed Methane Estimated Production New York Coalbed Methane Proved Reserves, Reserves Changes, and ...

  9. New York Coalbed Methane Proved Reserves (Billion Cubic Feet...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release Date: 11192015 Next Release Date: 12312016 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 New York Coalbed Methane Proved Reserves, Reserves Changes, ...

  10. Methane and Methanotrophic Bacteria as a Biotechnological Platform...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane and Methanotrophic Bacteria as a Biotechnological Platform Methane and Methanotrophic Bacteria as a Biotechnological Platform Breakout Session 2-B: NewEmerging Pathways ...

  11. Louisiana--State Offshore Coalbed Methane Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Louisiana--State Offshore Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade ...312016 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 LA, State Offshore

  12. ,"Lower 48 Federal Offshore Coalbed Methane Proved Reserves ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Lower 48 Federal Offshore Coalbed Methane Proved Reserves (Billion ... to Contents","Data 1: Lower 48 Federal Offshore Coalbed Methane Proved Reserves (Billion ...

  13. Lower 48 Federal Offshore Coalbed Methane Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Lower 48 Federal Offshore Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade ...2016 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 Federal Offshore U.S.

  14. ,"Texas (with State Offshore) Coalbed Methane Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas (with State Offshore) Coalbed Methane Proved Reserves ... to Contents","Data 1: Texas (with State Offshore) Coalbed Methane Proved Reserves ...

  15. ,"Alaska (with Total Offshore) Coalbed Methane Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Alaska (with Total Offshore) Coalbed Methane Proved Reserves ... to Contents","Data 1: Alaska (with Total Offshore) Coalbed Methane Proved Reserves ...

  16. ,"Louisiana--State Offshore Coalbed Methane Proved Reserves ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Louisiana--State Offshore Coalbed Methane Proved Reserves (Billion ... to Contents","Data 1: Louisiana--State Offshore Coalbed Methane Proved Reserves (Billion ...

  17. ,"Federal Offshore--Texas Coalbed Methane Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Federal Offshore--Texas Coalbed Methane Proved Reserves ... AM" "Back to Contents","Data 1: Federal Offshore--Texas Coalbed Methane Proved Reserves ...

  18. ,"Louisiana (with State Offshore) Coalbed Methane Proved Reserves...

    U.S. Energy Information Administration (EIA) Indexed Site

    for" ,"Data 1","Louisiana (with State Offshore) Coalbed Methane Proved Reserves ... Contents","Data 1: Louisiana (with State Offshore) Coalbed Methane Proved Reserves ...

  19. Texas--State Offshore Coalbed Methane Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    State Offshore Coalbed Methane Proved Reserves (Billion Cubic Feet) Decade Year-0 Year-1 ...312016 Referring Pages: Coalbed Methane Proved Reserves as of Dec. 31 TX, State Offshore

  20. ,"Texas--State Offshore Coalbed Methane Proved Reserves (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Texas--State Offshore Coalbed Methane Proved Reserves (Billion ... "Back to Contents","Data 1: Texas--State Offshore Coalbed Methane Proved Reserves (Billion ...