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Sample records for landfill gas conversion

  1. Penrose Landfill Gas Conversion LLC | Open Energy Information

    Open Energy Info (EERE)

    Page Edit with form History Penrose Landfill Gas Conversion LLC Jump to: navigation, search Name: Penrose Landfill Gas Conversion LLC Place: Los Angeles, California Product: Owner...

  2. Landfill Gas Conversion to LNG and LCO{sub 2}. Final Report

    SciTech Connect (OSTI)

    Brown, W.R.; Cook, W. J.; Siwajek, L.A.

    2000-10-20

    This report summarizes work on the development of a process to produce LNG (liquefied methane) for heavy vehicle use from landfill gas (LFG) using Acrion's CO{sub 2} wash process for contaminant removal and CO{sub 2} recovery. Work was done in the following areas: (1) production of natural gas pipeline methane for liquefaction at an existing LNG facility, (2) production of LNG from sewage digester gas, (3) the use of mixed refrigerants for process cooling in the production of LNG, liquid CO{sub 2} and pipeline methane, (4) cost estimates for an LNG production facility at the Arden Landfill in Washington PA.

  3. Landfill Gas | Open Energy Information

    Open Energy Info (EERE)

    Gas Jump to: navigation, search TODO: Add description List of Landfill Gas Incentives Retrieved from "http:en.openei.orgwindex.php?titleLandfillGas&oldid267173...

  4. Using landfill gas for energy: Projects that pay

    SciTech Connect (OSTI)

    1995-02-01

    Pending Environmental Protection Agency regulations will require 500 to 700 landfills to control gas emissions resulting from decomposing garbage. Conversion of landfill gas to energy not only meets regulations, but also creates energy and revenue for local governments.

  5. Sour landfill gas problem solved

    SciTech Connect (OSTI)

    Nagl, G.; Cantrall, R.

    1996-05-01

    In Broward County, Fla., near Pompano Beach, Waste Management of North America (WMNA, a subsidiary of WMX Technologies, Oak Brook, IL) operates the Central Sanitary Landfill and Recycling Center, which includes the country`s largest landfill gas-to-energy plant. The landfill consists of three collection sites: one site is closed, one is currently receiving garbage, and one will open in the future. Approximately 9 million standard cubic feet (scf) per day of landfill gas is collected from approximately 300 wells spread over the 250-acre landfill. With a dramatic increase of sulfur-containing waste coming to a South Florida landfill following Hurricane Andrew, odors related to hydrogen sulfide became a serious problem. However, in a matter of weeks, an innovative desulfurization unit helped calm the landfill operator`s fears. These very high H{sub 2}S concentrations caused severe odor problems in the surrounding residential area, corrosion problems in the compressors, and sulfur dioxide (SO{sub 2}) emission problems in the exhaust gas from the turbine generators.

  6. Hartford Landfill Gas Utilization Proj Biomass Facility | Open...

    Open Energy Info (EERE)

    Landfill Gas Utilization Proj Biomass Facility Jump to: navigation, search Name Hartford Landfill Gas Utilization Proj Biomass Facility Facility Hartford Landfill Gas Utilization...

  7. Albany Landfill Gas Utilization Project Biomass Facility | Open...

    Open Energy Info (EERE)

    Landfill Gas Utilization Project Biomass Facility Jump to: navigation, search Name Albany Landfill Gas Utilization Project Biomass Facility Facility Albany Landfill Gas Utilization...

  8. Balefill Landfill Gas Utilization Proj Biomass Facility | Open...

    Open Energy Info (EERE)

    Balefill Landfill Gas Utilization Proj Biomass Facility Jump to: navigation, search Name Balefill Landfill Gas Utilization Proj Biomass Facility Facility Balefill Landfill Gas...

  9. Woodland Landfill Gas Recovery Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Landfill Gas Recovery Biomass Facility Jump to: navigation, search Name Woodland Landfill Gas Recovery Biomass Facility Facility Woodland Landfill Gas Recovery Sector Biomass...

  10. Lopez Landfill Gas Utilization Project Biomass Facility | Open...

    Open Energy Info (EERE)

    Lopez Landfill Gas Utilization Project Biomass Facility Jump to: navigation, search Name Lopez Landfill Gas Utilization Project Biomass Facility Facility Lopez Landfill Gas...

  11. Olinda Landfill Gas Recovery Plant Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Olinda Landfill Gas Recovery Plant Biomass Facility Jump to: navigation, search Name Olinda Landfill Gas Recovery Plant Biomass Facility Facility Olinda Landfill Gas Recovery Plant...

  12. Spadra Landfill Gas to Energy Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Spadra Landfill Gas to Energy Biomass Facility Jump to: navigation, search Name Spadra Landfill Gas to Energy Biomass Facility Facility Spadra Landfill Gas to Energy Sector Biomass...

  13. Landfill Gas Conversion to LNG and LCO{sub 2}. Phase II Final Report for January 25, 1999 - April 30, 2000

    SciTech Connect (OSTI)

    Brown, W. R.; Cook, W. J.; Siwajek, L. A.

    2000-10-20

    This report summarizes work on the development of a process to produce LNG (liquefied methane) for heavy vehicle use from landfill gas (LFG) using Acrion's CO{sub 2} wash process for contaminant removal and CO{sub 2} recovery.

  14. Tapping Landfill Gas to Provide Significant Energy Savings and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study, 2013 Tapping Landfill Gas to Provide Significant Energy Savings and ...

  15. LANDFILL GAS CONVERSION TO LNG AND LCO{sub 2}. PHASE 1, FINAL REPORT FOR THE PERIOD MARCH 1998-FEBRUARY 1999

    SciTech Connect (OSTI)

    COOK,W.J.; NEYMAN,M.; SIWAJEK,L.A.; BROWN,W.R.; VAN HAUWAERT,P.M.; CURREN,E.D.

    1998-02-25

    Process designs and economics were developed to produce LNG and liquid carbon dioxide (CO{sub 2}) from landfill gas (LFG) using the Acrion CO{sub 2} wash process. The patented Acrion CO{sub 2} wash process uses liquid CO{sub 2} to absorb contaminants from the LFG. The process steps are compression, drying, CO{sub 2} wash contaminant removal and CO{sub 2} recovery, residual CO{sub 2} removal and methane liquefaction. Three flowsheets were developed using different residual CO{sub 2} removal schemes. These included physical solvent absorption (methanol), membranes and molecular sieves. The capital and operating costs of the flowsheets were very similar. The LNG production cost was around ten cents per gallon. In parallel with process flowsheet development, the business aspects of an eventual commercial project have been explored. The process was found to have significant potential commercial application. The business plan effort investigated the economics of LNG transportation, fueling, vehicle conversion, and markets. The commercial value of liquid CO{sub 2} was also investigated. This Phase 1 work, March 1998 through February 1999, was funded under Brookhaven National laboratory contract 725089 under the research program entitled ``Liquefied Natural Gas as a Heavy Vehicle Fuel.'' The Phase 2 effort will develop flowsheets for the following: (1) CO{sub 2} and pipeline gas production, with the pipeline methane being liquefied at a peak shaving site, (2) sewage digester gas as an alternate feedstock to LFG and (3) the use of mixed refrigerants for process cooling. Phase 2 will also study the modification of Acrion's process demonstration unit for the production of LNG and a market site for LNG production.

  16. Franklin County Sanitary Landfill - Landfill Gas (LFG) to Liquefied Natural Gas (LNG) - Project

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    FRANKLIN COUNTY SANITARY LANDFILL - LANDFILL GAS (LFG) TO LIQUEFIED NATURAL GAS (LNG) - PROJECT January/February 2005 Prepared for: National Renewable Energy Laboratory 1617 Cole Boulevard Golden, Colorado 80401 Table of Contents Page BACKGROUND AND INTRODUCTION .......................................................................................1 SUMMARY OF EFFORT PERFORMED ......................................................................................2 Task 2B.1 - Literature Search

  17. Alternative Fuels Data Center: Renewable Natural Gas From Landfill Powers

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Refuse Vehicles Renewable Natural Gas From Landfill Powers Refuse Vehicles to someone by E-mail Share Alternative Fuels Data Center: Renewable Natural Gas From Landfill Powers Refuse Vehicles on Facebook Tweet about Alternative Fuels Data Center: Renewable Natural Gas From Landfill Powers Refuse Vehicles on Twitter Bookmark Alternative Fuels Data Center: Renewable Natural Gas From Landfill Powers Refuse Vehicles on Google Bookmark Alternative Fuels Data Center: Renewable Natural Gas From

  18. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Reductions - Case Study, 2013 | Department of Energy Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study, 2013 Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study, 2013 BroadRock Renewables LLC, in collaboration with DCO Energy, operates combined cycle electric generating plants at the Central Landfill in Johnston, Rhode Island, and Olinda Alpha Landfill in Brea, California. The Rhode

  19. Landfill Gas and Biogas - Energy Explained, Your Guide To Understanding

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy - Energy Information Administration Landfill Gas and Biogas Energy Explained - Home What Is Energy? Forms of Energy Sources of Energy Laws of Energy Units and Calculators Energy Conversion Calculators British Thermal Units (Btu) Degree-Days U.S. Energy Facts State and U.S. Territory Data Use of Energy In Industry For Transportation In Homes In Commercial Buildings Efficiency and Conservation Energy and the Environment Greenhouse Gases Effect on the Climate Where Greenhouse Gases Come

  20. Methane Gas Utilization Project from Landfill at Ellery (NY)

    SciTech Connect (OSTI)

    Pantelis K. Panteli

    2012-01-10

    Landfill Gas to Electric Energy Generation and Transmission at Chautauqua County Landfill, Town of Ellery, New York. The goal of this project was to create a practical method with which the energy, of the landfill gas produced by the decomposing waste at the Chautauqua County Landfill, could be utilized. This goal was accomplished with the construction of a landfill gas to electric energy plant (originally 6.4MW and now 9.6MW) and the construction of an inter-connection power-line, from the power-plant to the nearest (5.5 miles) power-grid point.

  1. Renewable Energy Holdings Landfill Gas Wales Ltd REH Wales |...

    Open Energy Info (EERE)

    Gas Wales Ltd REH Wales Jump to: navigation, search Name: Renewable Energy Holdings Landfill Gas (Wales) Ltd (REH Wales) Place: United Kingdom Product: A joint venture to own and...

  2. Fuel Flexibility: Landfill Gas Contaminant Mitigation for Power Generation

    SciTech Connect (OSTI)

    Storey, John Morse; Theiss, Timothy J; Kass, Michael D; FINNEY, Charles E A; Lewis, Samuel; Kaul, Brian C; Besmann, Theodore M; Thomas, John F; Rogers, Hiram; Sepaniak, Michael

    2014-04-01

    This research project focused on the mitigation of silica damage to engine-based renewable landfill gas energy systems. Characterization of the landfill gas siloxane contamination, combined with characterization of the silica deposits in engines, led to development of two new mitigation strategies. The first involved a novel method for removing the siloxanes and other heavy contaminants from the landfill gas prior to use by the engines. The second strategy sought to interrupt the formation of hard silica deposits in the engine itself, based on inspection of failed landfill gas engine parts. In addition to mitigation, the project had a third task to develop a robust sensor for siloxanes that could be used to control existing and/or future removal processes.

  3. Feasibility study: utilization of landfill gas for a vehicle fuel system, Rossman's landfill, Clackamas County, Oregon

    SciTech Connect (OSTI)

    1981-01-01

    In 1978, a landfill operator in Oregon became interested in the technical and economic feasibility of recovering the methane generated in the landfill for the refueling of vehicles. DOE awarded a grant for a site-specific feasibility study of this concept. This study investigated the expected methane yield and the development of a conceptual gas-gathering system; gas processing, compressing, and storage systems; and methane-fueled vehicle systems. Cost estimates were made for each area of study. The results of the study are presented. Reasoning that gasoline prices will continue to rise and that approximately 18,000 vehicles in the US have been converted to operate on methane, a project is proposed to use this landfill as a demonstration site to produce and process methane and to fuel a fleet (50 to 400) vehicles with the gas produced in order to obtain performance and economic data on the systems used from gas collection through vehicle operation. (LCL)

  4. LIQUID NATURAL GAS (LNG): AN ALTERNATIVE FUEL FROM LANDFILL GAS (LFG) AND WASTEWATER DIGESTER GAS

    SciTech Connect (OSTI)

    VANDOR,D.

    1999-03-01

    This Research and Development Subcontract sought to find economic, technical and policy links between methane recovery at landfill and wastewater treatment sites in New York and Maryland, and ways to use that methane as an alternative fuel--compressed natural gas (CNG) or liquid natural gas (LNG) -- in centrally fueled Alternative Fueled Vehicles (AFVs).

  5. Powering Microturbines With Landfill Gas, October 2002 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants 7.4 Landfill Methane Utilization CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market ...

  6. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 1. Project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  7. Community Renewable Energy Success Stories: Landfill Gas-to-Energy Projects Webinar (text version)

    Broader source: Energy.gov [DOE]

    Below is the text version of the Webinar titled "Community Renewable Energy Success Stories: Landfill Gas-to-Energy Projects," originally presented on July 17, 2012.

  8. Case Studies from the Climate Technology Partnership: Landfill Gas Projects in South Korea and Lessons Learned

    SciTech Connect (OSTI)

    Larney, C.; Heil, M.; Ha, G. A.

    2006-12-01

    This paper examines landfill gas projects in South Korea. Two case studies provide concrete examples of lessons learned and offer practical guidance for future projects.

  9. Methane Gas Conversion Property Tax Exemption

    Broader source: Energy.gov [DOE]

    Under Iowa's methane gas conversion property tax exemption, real and personal property used to decompose waste and convert the waste to gas, collect the methane or other gases, convert the gas to...

  10. Improved methodology to assess modification and completion of landfill gas management in the aftercare period

    SciTech Connect (OSTI)

    Morris, Jeremy W.F.; Crest, Marion; Barlaz, Morton A.; Spokas, Kurt A.; Akerman, Anna; Yuan, Lei

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer Performance-based evaluation of landfill gas control system. Black-Right-Pointing-Pointer Analytical framework to evaluate transition from active to passive gas control. Black-Right-Pointing-Pointer Focus on cover oxidation as an alternative means of passive gas control. Black-Right-Pointing-Pointer Integrates research on long-term landfill behavior with practical guidance. - Abstract: Municipal solid waste landfills represent the dominant option for waste disposal in many parts of the world. While some countries have greatly reduced their reliance on landfills, there remain thousands of landfills that require aftercare. The development of cost-effective strategies for landfill aftercare is in society's interest to protect human health and the environment and to prevent the emergence of landfills with exhausted aftercare funding. The Evaluation of Post-Closure Care (EPCC) methodology is a performance-based approach in which landfill performance is assessed in four modules including leachate, gas, groundwater, and final cover. In the methodology, the objective is to evaluate landfill performance to determine when aftercare monitoring and maintenance can be reduced or possibly eliminated. This study presents an improved gas module for the methodology. While the original version of the module focused narrowly on regulatory requirements for control of methane migration, the improved gas module also considers best available control technology for landfill gas in terms of greenhouse gas emissions, air quality, and emissions of odoriferous compounds. The improved module emphasizes the reduction or elimination of fugitive methane by considering the methane oxidation capacity of the cover system. The module also allows for the installation of biologically active covers or other features designed to enhance methane oxidation. A methane emissions model, CALMIM, was used to assist with an assessment of the methane oxidation capacity of landfill covers.

  11. Tapping Landfill Gas to Provide Significant Energy Savings and Greenhouse Gas Reductions - Case Study

    SciTech Connect (OSTI)

    2013-04-30

    BroadRock Renewables, LLC built two high efficiency electricity generating facilities that utilize landfill gas in California and Rhode Island. The two projects received a total of $25 million in U.S. Department of Energy funding from the American Recovery and Reinvestment Act (ARRA) of 2009. Private-sector cost share for the projects totaled approximately $186 million.

  12. Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill

    SciTech Connect (OSTI)

    Wang, Xiaojun; Jia, Mingsheng; Chen, Xiaohai; Xu, Ying; Lin, Xiangyu; Kao, Chih Ming; Chen, Shaohua

    2014-07-15

    Highlights: • Young and aged leachate works accounted for 89.1% and 10.9% of 33.35 Gg CO{sub 2} yr{sup −1}. • Fresh leachate owned extremely low ORP and high organic matter content. • Strong CH{sub 4} emissions occurred in the fresh leachate ponds, but small in the aged. • N{sub 2}O emissions became dominant in the treatment units of both systems. • 8.45–11.9% of nitrogen was removed as the form of N{sub 2}O under steady-state. - Abstract: With limited assessment, leachate treatment of a specified landfill is considered to be a significant source of greenhouse gas (GHG) emissions. In our study, the cumulative GHG emitted from the storage ponds and process configurations that manage fresh or aged landfill leachate were investigated. Our results showed that strong CH{sub 4} emissions were observed from the fresh leachate storage pond, with the fluxes values (2219–26,489 mg C m{sup −2} h{sup −1}) extremely higher than those of N{sub 2}O (0.028–0.41 mg N m{sup −2} h{sup −1}). In contrast, the emission values for both CH{sub 4} and N{sub 2}O were low for the aged leachate tank. N{sub 2}O emissions became dominant once the leachate entered the treatment plants of both systems, accounting for 8–12% of the removal of N-species gases. Per capita, the N{sub 2}O emission based on both leachate treatment systems was estimated to be 7.99 g N{sub 2}O–N capita{sup −1} yr{sup −1}. An increase of 80% in N{sub 2}O emissions was observed when the bioreactor pH decreased by approximately 1 pH unit. The vast majority of carbon was removed in the form of CO{sub 2}, with a small portion as CH{sub 4} (<0.3%) during both treatment processes. The cumulative GHG emissions for fresh leachate storage ponds, fresh leachate treatment system and aged leachate treatment system were 19.10, 10.62 and 3.63 Gg CO{sub 2} eq yr{sup −1}, respectively, for a total that could be transformed to 9.09 kg CO{sub 2} eq capita{sup −1} yr{sup −1}.

  13. Westchester Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Landfill Biomass Facility Jump to: navigation, search Name Westchester Landfill Biomass Facility Facility Westchester Landfill Sector Biomass Facility Type Landfill Gas Location...

  14. Kiefer Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Kiefer Landfill Biomass Facility Jump to: navigation, search Name Kiefer Landfill Biomass Facility Facility Kiefer Landfill Sector Biomass Facility Type Landfill Gas Location...

  15. Investigation of Integrated Subsurface Processing of Landfill Gas and Carbon Sequestration, Johnson County, Kansas

    SciTech Connect (OSTI)

    K. David Newell; Timothy R. Carr

    2007-03-31

    The Johnson County Landfill in Shawnee, KS is operated by Deffenbaugh Industries and serves much of metropolitan Kansas City. Refuse, which is dumped in large plastic-underlined trash cells covering several acres, is covered over with shale shortly after burial. The landfill waste, once it fills the cell, is then drilled by Kansas City LFG, so that the gas generated by anaerobic decomposition of the refuse can be harvested. Production of raw landfill gas from the Johnson County landfill comes from 150 wells. Daily production is approximately 2.2 to 2.5 mmcf, of which approximately 50% is methane and 50% is carbon dioxide and NMVOCs (non-methane volatile organic compounds). Heating value is approximately 550 BTU/scf. A upgrading plant, utilizing an amine process, rejects the carbon dioxide and NMVOCs, and upgrades the gas to pipeline quality (i.e., nominally a heating value >950 BTU/scf). The gas is sold to a pipeline adjacent to the landfill. With coal-bearing strata underlying the landfill, and carbon dioxide a major effluent gas derived from the upgrading process, the Johnson County Landfill is potentially an ideal setting to study the feasibility of injecting the effluent gas in the coals for both enhanced coalbed methane recovery and carbon sequestration. To these ends, coals below the landfill were cored and then were analyzed for their thickness and sorbed gas content, which ranged up to 79 scf/ton. Assuming 1 1/2 square miles of land (960 acres) at the Johnson County Landfill can be utilized for coalbed and shale gas recovery, the total amount of in-place gas calculates to 946,200 mcf, or 946.2 mmcf, or 0.95 bcf (i.e., 985.6 mcf/acre X 960 acres). Assuming that carbon dioxide can be imbibed by the coals and shales on a 2:1 ratio compared to the gas that was originally present, then 1682 to 1720 days (4.6 to 4.7 years) of landfill carbon dioxide production can be sequestered by the coals and shales immediately under the landfill. Three coal--the Bevier, Fleming, and Mulberry coals--are the major coals of sufficient thickness (nominally >1-foot) that can imbibe carbon dioxide gas with an enhanced coalbed injection. Comparison of the adsorption gas content of coals to the gas desorbed from the coals shows that the degree of saturation decreases with depth for the coals.

  16. Property:Building/SPPurchasedEngyForPeriodMwhYrDigesterLandfillGas...

    Open Energy Info (EERE)

    YrDigesterLandfillGas" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  17. Property:Building/SPPurchasedEngyNrmlYrMwhYrDigesterLandfillGas...

    Open Energy Info (EERE)

    YrDigesterLandfillGas" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  18. Renewable LNG: Update on the World's Largest Landfill Gas to LNG Plant

    Broader source: Energy.gov [DOE]

    Success story about LNG from landfill gas. Presented by Mike McGowan, Linde NA, Inc., at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

  19. Emission assessment at the Burj Hammoud inactive municipal landfill: Viability of landfill gas recovery under the clean development mechanism

    SciTech Connect (OSTI)

    El-Fadel, Mutasem; Abi-Esber, Layale; Salhab, Samer

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer LFG emissions are measured at an abandoned landfill with highly organic waste. Black-Right-Pointing-Pointer Mean headspace and vent emissions are 0.240 and 0.074 l CH{sub 4}/m{sup 2} hr, respectively. Black-Right-Pointing-Pointer At sites with high food waste content, LFG generation drops rapidly after site closure. Black-Right-Pointing-Pointer The viability of LFG recovery for CDMs in developing countries is doubtful. - Abstract: This paper examines landfill gas (LFG) emissions at a large inactive waste disposal site to evaluate the viability of investment in LFG recovery through the clean development mechanism (CDM) initiative. For this purpose, field measurements of LFG emissions were conducted and the data were processed by geospatial interpolation to estimate an equivalent site emission rate which was used to calibrate and apply two LFG prediction models to forecast LFG emissions at the site. The mean CH{sub 4} flux values calculated through tessellation, inverse distance weighing and kriging were 0.188 {+-} 0.014, 0.224 {+-} 0.012 and 0.237 {+-} 0.008 l CH{sub 4}/m{sup 2} hr, respectively, compared to an arithmetic mean of 0.24 l/m{sup 2} hr. The flux values are within the reported range for closed landfills (0.06-0.89 l/m{sup 2} hr), and lower than the reported range for active landfills (0.42-2.46 l/m{sup 2} hr). Simulation results matched field measurements for low methane generation potential (L{sub 0}) values in the range of 19.8-102.6 m{sup 3}/ton of waste. LFG generation dropped rapidly to half its peak level only 4 yrs after landfill closure limiting the sustainability of LFG recovery systems in similar contexts and raising into doubt promoted CDM initiatives for similar waste.

  20. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 2. Appendices to project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  1. Alternative Fuels Data Center: Natural Gas Vehicle Conversions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Conversions to someone by E-mail Share Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Natural Gas Vehicle Conversions on Digg Find More places to share Alternative Fuels Data Center:

  2. BUNCOMBE COUNTY WASTEWATER PRE-TREATMENT AND LANDFILL GAS TO ENERGY PROJECT

    SciTech Connect (OSTI)

    Jon Creighton

    2012-03-13

    The objective of this project was to construct a landfill gas-to-energy (LFGTE) facility that generates a renewable energy source utilizing landfill gas to power a 1.4MW generator, while at the same time reducing the amount of leachate hauled offsite for treatment. The project included an enhanced gas collection and control system, gas conditioning equipment, and a 1.4 MW generator set. The production of cleaner renewable energy will help offset the carbon footprint of other energy sources that are currently utilized.

  3. Recovery Act: Brea California Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2012-12-31

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Olinda Landfill near Brea, California. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting Project reflected a cost effective balance of the following specific sub-objectives: • Meeting the environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas • Utilizing proven and reliable technology and equipment • Maximizing electrical efficiency • Maximizing electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Olinda Landfill • Maximizing equipment uptime • Minimizing water consumption • Minimizing post-combustion emissions • The Project produced and will produce a myriad of beneficial impacts. o The Project created 360 FTE construction and manufacturing jobs and 15 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. o By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). o The Project will annually produce 280,320 MWh’s of clean energy o By destroying the methane in the landfill gas, the Project will generate CO2 equivalent reductions of 164,938 tons annually. The completed facility produces 27.4 MWnet and operates 24 hours a day, seven days a week.

  4. Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2013-06-30

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Central Landfill in Johnston, Rhode Island. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting project reflected a cost effective balance of the following specific sub-objectives. 1) Meet environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas. 2) Utilize proven and reliable technology and equipment. 3) Maximize electrical efficiency. 4) Maximize electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Central Landfill. 5) Maximize equipment uptime. 6) Minimize water consumption. 7) Minimize post-combustion emissions. To achieve the Project Objective the project consisted of several components. 1) The landfill gas collection system was modified and upgraded. 2) A State-of-the Art gas clean up and compression facility was constructed. 3) A high pressure pipeline was constructed to convey cleaned landfill gas from the clean-up and compression facility to the power plant. 4) A combined cycle electric generating facility was constructed consisting of combustion turbine generator sets, heat recovery steam generators and a steam turbine. 5) The voltage of the electricity produced was increased at a newly constructed transformer/substation and the electricity was delivered to the local transmission system. The Project produced a myriad of beneficial impacts. 1) The Project created 453 FTE construction and manufacturing jobs and 25 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. 2) By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). 3) The Project will annually produce 365,292 MWh�s of clean energy. 4) By destroying the methane in the landfill gas, the Project will generate CO{sub 2} equivalent reductions of 164,938 tons annually. The completed facility produces 28.3 MWnet and operates 24 hours a day, seven days a week.

  5. Garbage In, Power Out: South Carolina BMW Plant Demonstrates Landfill Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Hydrogen Fuel | Department of Energy Garbage In, Power Out: South Carolina BMW Plant Demonstrates Landfill Gas to Hydrogen Fuel Garbage In, Power Out: South Carolina BMW Plant Demonstrates Landfill Gas to Hydrogen Fuel August 25, 2015 - 2:15pm Addthis The plant BMW plant in Greer, South Carolina is home to the world's largest fleet of fuel cell forklifts. | Photo courtesy of BMW Manufacturing. The plant BMW plant in Greer, South Carolina is home to the world's largest fleet of fuel cell

  6. Ocean County Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    County Landfill Biomass Facility Jump to: navigation, search Name Ocean County Landfill Biomass Facility Facility Ocean County Landfill Sector Biomass Facility Type Landfill Gas...

  7. Pearl Hollow Landfil Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Hollow Landfil Biomass Facility Jump to: navigation, search Name Pearl Hollow Landfil Biomass Facility Facility Pearl Hollow Landfil Sector Biomass Facility Type Landfill Gas...

  8. Impact of different plants on the gas profile of a landfill cover

    SciTech Connect (OSTI)

    Reichenauer, Thomas G.; Watzinger, Andrea; Riesing, Johann; Gerzabek, Martin H.

    2011-05-15

    Research highlights: > Plants influence gas profile and methane oxidation in landfill covers. > Plants regulate water content and increase the availability of oxygen for methane oxidation. > Plant species with deep roots like alfalfa showed more stimulation of methane oxidation than plants with shallow root systems like grasses. - Abstract: Methane is an important greenhouse gas emitted from landfill sites and old waste dumps. Biological methane oxidation in landfill covers can help to reduce methane emissions. To determine the influence of different plant covers on this oxidation in a compost layer, we conducted a lysimeter study. We compared the effect of four different plant covers (grass, alfalfa + grass, miscanthus and black poplar) and of bare soil on the concentration of methane, carbon dioxide and oxygen in lysimeters filled with compost. Plants were essential for a sustainable reduction in methane concentrations, whereas in bare soil, methane oxidation declined already after 6 weeks. Enhanced microbial activity - expected in lysimeters with plants that were exposed to landfill gas - was supported by the increased temperature of the gas in the substrate and the higher methane oxidation potential. At the end of the first experimental year and from mid-April of the second experimental year, the methane concentration was most strongly reduced in the lysimeters containing alfalfa + grass, followed by poplar, miscanthus and grass. The observed differences probably reflect the different root morphology of the investigated plants, which influences oxygen transport to deeper compost layers and regulates the water content.

  9. Property:Building/SPPurchasedEngyPerAreaKwhM2DigesterLandfillGas...

    Open Energy Info (EERE)

    M2DigesterLandfillGas" Showing 25 pages using this property. (previous 25) (next 25) S Sweden Building 05K0001 + 0.0 + Sweden Building 05K0002 + 0.0 + Sweden Building 05K0003 + 0.0...

  10. Well-to-Wheels analysis of landfill gas-based pathways and their addition to the GREET model.

    SciTech Connect (OSTI)

    Mintz, M.; Han, J.; Wang, M.; Saricks, C.; Energy Systems

    2010-06-30

    Today, approximately 300 million standard cubic ft/day (mmscfd) of natural gas and 1600 MW of electricity are produced from the decomposition of organic waste at 519 U.S. landfills (EPA 2010a). Since landfill gas (LFG) is a renewable resource, this energy is considered renewable. When used as a vehicle fuel, compressed natural gas (CNG) produced from LFG consumes up to 185,000 Btu of fossil fuel and generates from 1.5 to 18.4 kg of carbon dioxide-equivalent (CO{sub 2}e) emissions per million Btu of fuel on a 'well-to-wheel' (WTW) basis. This compares with approximately 1.1 million Btu and 78.2 kg of CO{sub 2}e per million Btu for CNG from fossil natural gas and 1.2 million Btu and 97.5 kg of CO{sub 2}e per million Btu for petroleum gasoline. Because of the additional energy required for liquefaction, LFG-based liquefied natural gas (LNG) requires more fossil fuel (222,000-227,000 Btu/million Btu WTW) and generates more GHG emissions (approximately 22 kg CO{sub 2}e /MM Btu WTW) if grid electricity is used for the liquefaction process. However, if some of the LFG is used to generate electricity for gas cleanup and liquefaction (or compression, in the case of CNG), vehicle fuel produced from LFG can have no fossil fuel input and only minimal GHG emissions (1.5-7.7 kg CO{sub 2}e /MM Btu) on a WTW basis. Thus, LFG-based natural gas can be one of the lowest GHG-emitting fuels for light- or heavy-duty vehicles. This report discusses the size and scope of biomethane resources from landfills and the pathways by which those resources can be turned into and utilized as vehicle fuel. It includes characterizations of the LFG stream and the processes used to convert low-Btu LFG into high-Btu renewable natural gas (RNG); documents the conversion efficiencies and losses of those processes, the choice of processes modeled in GREET, and other assumptions used to construct GREET pathways; and presents GREET results by pathway stage. GREET estimates of well-to-pump (WTP), pump-to-wheel (PTW), and WTW energy, fossil fuel, and GHG emissions for each LFG-based pathway are then summarized and compared with similar estimates for fossil natural gas and petroleum pathways.

  11. Conversion of Coal Mine Gas to LNG

    Office of Scientific and Technical Information (OSTI)

    Conversion of Coal Mine Gas to LNG Final Technical Report Reporting Period Start Date Reporting Period End Date Report issued October 01, 2000 March 31, 2013 February 5, 2016 Cooperative Agreement No. DE-FC26-00NT40978 Submitted by: Appalachian-Pacific Coal Mine Methane Power Company 5053 Glenbrook Terrace NW Washington, DC 20016-2602 1 DISCLAIMER: "This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor

  12. Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications

    Office of Energy Efficiency and Renewable Energy (EERE)

    Landfill gas (LFG), composed largely of methane and carbon dioxide, is used in over 450 operational projects in 43 states. These projects convert a large source of greenhouse gases into a fuel that...

  13. List of Landfill Gas Incentives | Open Energy Information

    Open Energy Info (EERE)

    Waste Photovoltaics Solar Thermal Electric Coal with CCS Energy Storage Nuclear Wind Natural Gas Yes Alternative Energy Portfolio Standard (Pennsylvania) Renewables Portfolio...

  14. Tapping Landfill Gas to Provide Significant Energy Savings and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... The Olinda project won the award because of its creative fnancing, including the ARRA ... "candidate landflls" that have the potential to utilize landfll gas for energy production. ...

  15. Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils

    SciTech Connect (OSTI)

    Jeremy Semrau; Sung-Woo Lee; Jeongdae Im; Sukhwan Yoon; Michael Barcelona

    2010-09-30

    The overall objective of this project, 'Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils' was to develop effective, efficient, and economic methodologies by which microbial production of nitrous oxide can be minimized while also maximizing microbial consumption of methane in landfill cover soils. A combination of laboratory and field site experiments found that the addition of nitrogen and phenylacetylene stimulated in situ methane oxidation while minimizing nitrous oxide production. Molecular analyses also indicated that methane-oxidizing bacteria may play a significant role in not only removing methane, but in nitrous oxide production as well, although the contribution of ammonia-oxidizing archaea to nitrous oxide production can not be excluded at this time. Future efforts to control both methane and nitrous oxide emissions from landfills as well as from other environments (e.g., agricultural soils) should consider these issues. Finally, a methanotrophic biofiltration system was designed and modeled for the promotion of methanotrophic activity in local methane 'hotspots' such as landfills. Model results as well as economic analyses of these biofilters indicate that the use of methanotrophic biofilters for controlling methane emissions is technically feasible, and provided either the costs of biofilter construction and operation are reduced or the value of CO{sub 2} credits is increased, can also be economically attractive.

  16. Landfill Energy Systems LES | Open Energy Information

    Open Energy Info (EERE)

    Energy Systems LES Jump to: navigation, search Name: Landfill Energy Systems (LES) Place: Michigan Zip: 48393 Product: Landfill gas to energy systems project developer, gas...

  17. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida; Del Paggio, Alan Anthony; Nair, Vijay; Roes, Augustinus Wilhelmus Maria

    2011-12-06

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  18. Measuring seasonal variations of moisture in a landfill with the partitioning gas tracer test

    SciTech Connect (OSTI)

    Han, Byunghyun; Jafarpour, Behnam; Gallagher, Victoria N.; Imhoff, Paul T. . E-mail: imhoff@udel.edu; Chiu, Pei C.; Fluman, Daniel A.

    2006-07-01

    Seven pilot-scale partitioning gas tracer tests (PGTTs) were conducted to assess the accuracy and reproducibility of this method for measuring water in municipal solid waste landfills. Tests were conducted in the same location over a 12-month period, and measured moisture conditions ranged from possible dry waste to refuse with a moisture content of 24.7%. The final moisture content of 24.7% was in reasonable agreement with gravimetric measurements of excavated refuse, where the moisture content was 26.5 {+-} 6.0CI%. Laboratory tests were used to assess the utility of the PGTT for measuring water in small pores, water sorbed to solid surfaces, and the influence of dry waste on PGTTs. These experiments indicated that when refuse surfaces are not completely solvated with water, PGTTs may produce misleading results (negative estimates) of water saturation and moisture content.

  19. Conversion method for gas streams containing hydrocarbons

    DOE Patents [OSTI]

    Mallinson, Richard G.; Lobban, Lance; Liu, Chang-jun

    2000-01-01

    An apparatus and a method of using the apparatus are provided for converting a gas stream containing hydrocarbons to a reaction product containing effluent molecules having at least one carbon atom, having at least one interior surface and at least one exterior surface, a first electrode and a second electrode with the first and second electrodes being selectively movable in relation to each other and positioned within the housing so as to be spatially disposed a predetermined distance from each other, a plasma discharge generator between the first and second electrodes, gas stream introducer and a collector for collecting the reaction product effluent produced by the reaction of the gas stream containing hydrocarbons with the plasma discharge between the first and second electrodes.

  20. WC Landfill Energy | Open Energy Information

    Open Energy Info (EERE)

    WC Landfill Energy Place: New Jersey Product: Joint venture between DCO Energy and Marina Energy to develop landfill gas-to-energy plants in New Jersey. References: WC Landfill...

  1. Conversion economics for Alaska North Slope natural gas

    SciTech Connect (OSTI)

    Thomas, C.P.; Robertson, E.P.

    1995-07-01

    For the Prudhoe Bay field, this preliminary analysis provides an indication that major gas sales using a gas pipeline/LNG plant scenario, such as Trans Alaska Gas System, or a gas-to-liquids process with the cost parameters assumed, are essentially equivalent and would be viable and profitable to industry and beneficial to the state of Alaska and the federal government. The cases are compared for the Reference oil price case. The reserves would be 12.7 BBO for the base case without major gas sales, 12.3 BBO and 20 Tcf gas for the major gas sales case, and 14.3 BBO for the gas-to-liquids conversion cases. Use of different parameters will significantly alter these results; e.g., the low oil price case would result in the base case for Prudhoe Bay field becoming uneconomic in 2002 with the operating costs and investments as currently estimated.

  2. Gas conversion opportunities in LILCO's commercial sector

    SciTech Connect (OSTI)

    Pierce, B.

    1993-03-01

    This report presents the results of a preliminary investigation into opportunities for gas conservation in Long Island Lighting Company's commercial sector. It focusses on gas-fired heating equipment. Various sources of data are examined in order to characterize the commercial buildings and equipment in the service territory. Several key pieces of information necessary to predict savings potential are identified. These include the efficiencies and size distribution of existing equipment. Twenty-one specific conservation measures are identified and their applicability is discussed in terms of equipment size. Recommendations include improving the characterization of existing buildings and equipment, and developing a greater understanding of the savings and costs of conservation measures, and their interactions, especially in the middle size range of buildings and equipment.

  3. Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications

    SciTech Connect (OSTI)

    2009-02-01

    Gas Technology Institute will collaborate with Integrated CHP Systems Corporation, West Virginia University, Vronay Engineering Services, KAR Engineering Associates, Pioneer Air Systems, and Energy Concepts Company to recover waste heat from reciprocating engines. The project will integrate waste heat recovery along with gas clean-up technology system improvements. This will address fuel quality issues that have hampered expanded use of opportunity fuels such as landfill gas, digester biogas, and coal mine methane. This will enable increased application of CHP using renewable and domestically derived opportunity fuels.

  4. Co-conversion of Biomass, Shale-natural gas, and process-derived...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and Chemicals Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and ...

  5. Energy potential of modern landfills

    SciTech Connect (OSTI)

    Bogner, J.E.

    1990-01-01

    Methane produced by refuse decomposition in a sanitary landfill can be recovered for commercial use. Landfill methane is currently under-utilized, with commercial recovery at only a small percentage of US landfills. New federal regulations mandating control of landfill gas migration and atmospheric emissions are providing impetus to methane recovery schemes as a means of recovering costs for increased environmental control. The benefits of landfill methane recovery include utilization of an inexpensive renewable energy resource, removal of explosive gas mixtures from the subsurface, and mitigation of observed historic increases in atmospheric methane. Increased commercial interest in landfill methane recovery is dependent on the final form of Clean Air Act amendments pertaining to gaseous emissions from landfills; market shifts in natural gas prices; financial incentives for development of renewable energy resources; and support for applied research and development to develop techniques for increased control of the gas generation process in situ. This paper will discuss the controls on methane generation in landfills. In addition, it will address how landfill regulations affect landfill design and site management practices which, in turn, influence decomposition rates. Finally, future trends in landfilling, and their relationship to gas production, will be examined. 19 refs., 2 figs., 3 tabs.

  6. Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Natural Gas Landfills Convert Biogas Into Renewable Natural Gas to someone by E-mail Share Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable Natural Gas on Facebook Tweet about Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable Natural Gas on Twitter Bookmark Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable Natural Gas on Google Bookmark Alternative Fuels Data Center: Landfills Convert Biogas Into Renewable Natural Gas on

  7. Compressed Natural Gas and Liquefied Petroleum Gas Conversions: The National Renewable Energy Laboratory's Experience

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Compressed Natural Gas and Liquefied Petroleum Gas Conversions: The National Renewable Energy Laboratory's Experience N T Y A U E O F E N E R G D E P A R T M E N I T E D S T A T S O F A E R I C M Compressed Natural Gas and Liquefied Petroleum Gas Conversions: The National Renewable Energy Laboratory's Experience N T Y A U E O F E N E R G D E P A R T M E N I T E D S T A T S O F A E R I C M Robert C. Motta Kenneth J. Kelly William W. Warnock Executive Summary The National Renewable Energy

  8. Compressed natural gas and liquefied petroleum gas conversions: The National Renewable Energy Laboratory`s experience

    SciTech Connect (OSTI)

    Motta, R.C.; Kelly, K.J.; Warnock, W.W.

    1996-04-01

    The National Renewable Energy Laboratory (NREL) contracted with conversion companies in six states to convert approximately 900 light-duty Federal fleet vehicles to operate on compressed natural gas (CNG) or liquefied petroleum gas (LPG). The contracts were initiated in order to help the Federal government meet the vehicle acquisition requirements of the Energy Policy Act of 1992 (EPACT) during a period of limited original equipment manufacturer (OEM) model availability. Approximately 90% of all conversions were performed on compact of full-size vans and pickups, and 90% of the conversions were to bi-fuel operation. With a positive response from the fleet managers, this program helped the Federal government meet the vehicle acquisition requirements of EPACT for fiscal years 1993 and 1994, despite limited OEM model availability. The conversions also helped to establish the infrastructure needed to support further growth in the use of alternative fuel vehicles. In conclusion, the program has been successful in helping the Federal government meet the vehicle acquisition requirements of EPACT, establishing infrastructure, increasing the displacement of imported oil, and evaluating the emissions performance of converted vehicles. With the relatively widespread availability of OEM vehicles in the 1996 model year, the program is now being phased out.

  9. Synthesis gas conversion to LPG over molybdenum catalysts

    SciTech Connect (OSTI)

    Murchison, C.B.; Murdick, D.A.

    1980-01-01

    By using a new Dow Chemical Co. carbon-supported molybdenum oxide catalyst promoted with 4.4% K/sub 2/O or Na/sub 2/O, 90%+ conversions of synthesis gas at space velocities of 500-600/hr were achieved with 60-75% selectivities for C/sub 2/-C/sub 5/ paraffins, including 33 and 27% for ethane and propane, respectively, and no liquid products formed. This LPG product is an excellent ethylene cracking feedstock. The catalyst, which can be used in both oxide and sulfided forms, has demonstrated stable performance with feeds containing up to 20 ppm sulfur (H/sub 2/S + COS) and had no coking problems for up to 2000 hr on stream. Excessive sulfur exposure can be reversed by regeneration with hydrogen. Because of the catalyst's low coking rate, high temperatures, i.e., 350/sup 0/-500/sup 0/C, and near-stoichiometric H/sub 2//CO feed ratios can be used.

  10. One Man's Trash, Another Man's Fuel: BMW Plant Converts Landfill...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    One Man's Trash, Another Man's Fuel: BMW Plant Converts Landfill Gas to Hydrogen Fuel One Man's Trash, Another Man's Fuel: BMW Plant Converts Landfill Gas to Hydrogen Fuel August ...

  11. Experimental and life cycle assessment analysis of gas emission from mechanicallybiologically pretreated waste in a landfill with energy recovery

    SciTech Connect (OSTI)

    Di Maria, Francesco Sordi, Alessio; Micale, Caterina

    2013-11-15

    Highlights: Bio-methane landfill emissions from different period (0, 4, 8, 16 weeks) MTB waste have been evaluated. Electrical energy recoverable from landfill gas ranges from 11 to about 90 kW h/tonne. Correlation between oxygen uptake, energy recovery and anaerobic gas production shows R{sup 2} ranging from 0.78 to 0.98. LCA demonstrate that global impact related to gaseous emissions achieve minimum for 4 week of MBT. - Abstract: The global gaseous emissions produced by landfilling the Mechanically Sorted Organic Fraction (MSOF) with different weeks of Mechanical Biological Treatment (MBT) was evaluated for an existing waste management system. One MBT facility and a landfill with internal combustion engines fuelled by the landfill gas for electrical energy production operate in the waste management system considered. An experimental apparatus was used to simulate 0, 4, 8 and 16 weeks of aerobic stabilization and the consequent biogas potential (Nl/kg) of a large sample of MSOF withdrawn from the full-scale MBT. Stabilization achieved by the waste was evaluated by dynamic oxygen uptake and fermentation tests. Good correlation coefficients (R{sup 2}), ranging from 0.7668 to 0.9772, were found between oxygen uptake, fermentation and anaerobic test values. On the basis of the results of several anaerobic tests, the methane production rate k (year{sup ?1}) was evaluated. k ranged from 0.436 to 0.308 year{sup ?1} and the bio-methane potential from 37 to 12 N m{sup 3}/tonne, respectively, for the MSOF with 0 and 16 weeks of treatment. Energy recovery from landfill gas ranged from about 11 to 90 kW h per tonne of disposed MSOF depending on the different scenario investigated. Life cycle analysis showed that the scenario with 0 weeks of pre-treatment has the highest weighted global impact even if opposite results were obtained with respect to the single impact criteria. MSOF pre-treatment periods longer than 4 weeks showed rather negligible variation in the global impact of system emissions.

  12. Methane emissions from MBT landfills

    SciTech Connect (OSTI)

    Heyer, K.-U. Hupe, K.; Stegmann, R.

    2013-09-15

    Highlights: Compilation of methane generation potential of mechanical biological treated (MBT) municipal solid waste. Impacts and kinetics of landfill gas production of MBT landfills, approach with differentiated half-lives. Methane oxidation in the waste itself and in soil covers. Estimation of methane emissions from MBT landfills in Germany. - Abstract: Within the scope of an investigation for the German Federal Environment Agency (Umweltbundesamt), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 1824 m{sup 3} CH{sub 4}/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH{sub 4}/(m{sup 2} h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD) model of the IPCC Guidelines for National Greenhouse Gas Inventories, 2006, was used to estimate the methane emissions from MBT landfills. Due to the calculation made by the authors emissions in the range of 60,000135,000 t CO{sub 2-eq.}/a for all German MBT landfills can be expected. This wide range shows the uncertainties when the here used procedure and the limited available data are applied. It is therefore necessary to generate more data in the future in order to calculate more precise methane emission rates from MBT landfills. This is important for the overall calculation of the climate gas production in Germany which is required once a year by the German Government.

  13. Method for the photocatalytic conversion of gas hydrates

    DOE Patents [OSTI]

    Taylor, Charles E.; Noceti, Richard P.; Bockrath, Bradley C.

    2001-01-01

    A method for converting methane hydrates to methanol, as well as hydrogen, through exposure to light. The process includes conversion of methane hydrates by light where a radical initiator has been added, and may be modified to include the conversion of methane hydrates with light where a photocatalyst doped by a suitable metal and an electron transfer agent to produce methanol and hydrogen. The present invention operates at temperatures below 0.degree. C., and allows for the direct conversion of methane contained within the hydrate in situ.

  14. Estimation of landfill emission lifespan using process oriented modeling

    SciTech Connect (OSTI)

    Ustohalova, Veronika . E-mail: veronika.ustohalova@uni-essen.de; Ricken, Tim; Widmann, Renatus

    2006-07-01

    Depending on the particular pollutants emitted, landfills may require service activities lasting from hundreds to thousands of years. Flexible tools allowing long-term predictions of emissions are of key importance to determine the nature and expected duration of maintenance and post-closure activities. A highly capable option represents predictions based on models and verified by experiments that are fast, flexible and allow for the comparison of various possible operation scenarios in order to find the most appropriate one. The intention of the presented work was to develop a experimentally verified multi-dimensional predictive model capable of quantifying and estimating processes taking place in landfill sites where coupled process description allows precise time and space resolution. This constitutive 2-dimensional model is based on the macromechanical theory of porous media (TPM) for a saturated thermo-elastic porous body. The model was used to simulate simultaneously occurring processes: organic phase transition, gas emissions, heat transport, and settlement behavior on a long time scale for municipal solid waste deposited in a landfill. The relationships between the properties (composition, pore structure) of a landfill and the conversion and multi-phase transport phenomena inside it were experimentally determined. In this paper, we present both the theoretical background of the model and the results of the simulations at one single point as well as in a vertical landfill cross section.

  15. Microemulsion impregnated catalyst composite and use thereof in a synthesis gas conversion process

    DOE Patents [OSTI]

    Abrevaya, Hayim; Targos, William M.

    1987-01-01

    A catalyst composition for synthesis gas conversion comprising a ruthenium metal component deposited on a support carrier wherein the average metal particle size is less than about 100 A. The method of manufacture of the composition via a reverse micelle impregnation technique and the use of the composition in a Fischer-Tropsch conversion process is also disclosed.

  16. Microemulsion impregnated catalyst composite and use thereof in a synthesis gas conversion process

    DOE Patents [OSTI]

    Abrevaya, H.; Targos, W.M.

    1987-12-22

    A catalyst composition is described for synthesis gas conversion comprising a ruthenium metal component deposited on a support carrier wherein the average metal particle size is less than about 100 A. The method of manufacture of the composition via a reverse micelle impregnation technique and the use of the composition in a Fischer-Tropsch conversion process is also disclosed.

  17. Methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C.; Nelson, Lee O.; Detering, Brent A.

    2009-02-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  18. CONVERSION OF WASTE CO2 AND SHALE GAS TO HIGH VALUE CHEMICALS | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy CONVERSION OF WASTE CO2 AND SHALE GAS TO HIGH VALUE CHEMICALS CONVERSION OF WASTE CO2 AND SHALE GAS TO HIGH VALUE CHEMICALS Novomer - Ithaca, NY Waste CO2 from industrial sources and ethane-derivatives from shale gas can be converted into high value chemical intermediates (e.g. acrylic acid) using combustion-assisted solid oxide electrolysis and 99% selective catalytic carbonylation chemistry. Preliminary estimates suggest a 20-40% reduction in both cradle to grave energy usage and

  19. Coal liquefaction and gas conversion: Proceedings. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  20. Venice Park landfill: Working with the community

    SciTech Connect (OSTI)

    McAdams, C.L.

    1993-09-01

    Venice Park landfill was one of the first sites to be permitted under Michigan's proposed Public Act 641. PA 641 essentially changed the rules and regulations for landfills from the simple design of digging a hole and filling it. It also upgraded standards to those that are more sophisticated, including liners, leachate collection systems, and gas extraction systems. In 1992, methane gas from the landfill was collected into wells drilled into the trash varying in depth from 30-50 feet in depth. A vacuum pulls the gas from the trash into the wells, then through a piping system. The landfill uses about 80-100 kilowatts in-house. The remainder of the gas is sold to Consumers Power Co. which uses landfill gas to supply power to homes.

  1. Gas conversion opportunities in LILCO`s commercial sector

    SciTech Connect (OSTI)

    Pierce, B.

    1993-03-01

    This report presents the results of a preliminary investigation into opportunities for gas conservation in Long Island Lighting Company`s commercial sector. It focusses on gas-fired heating equipment. Various sources of data are examined in order to characterize the commercial buildings and equipment in the service territory. Several key pieces of information necessary to predict savings potential are identified. These include the efficiencies and size distribution of existing equipment. Twenty-one specific conservation measures are identified and their applicability is discussed in terms of equipment size. Recommendations include improving the characterization of existing buildings and equipment, and developing a greater understanding of the savings and costs of conservation measures, and their interactions, especially in the middle size range of buildings and equipment.

  2. Conversion of associated natural gas to liquid hydrocarbons. Final report, June 1, 1995--January 31, 1997

    SciTech Connect (OSTI)

    1997-12-31

    The original concept envisioned for the use of Fischer-Tropsch processing (FTP) of United States associated natural gas in this study was to provide a way of utilizing gas which could not be brought to market because a pipeline was not available or for which there was no local use. Conversion of gas by FTP could provide a means of utilizing offshore associated gas which would not require installation of a pipeline or re-injection. The premium quality F-T hydrocarbons produced by conversion of the gas can be transported in the same way as the crude oil or in combination (blended) with it, eliminating the need for a separate gas transport system. FTP will produce a synthetic crude oil, thus increasing the effective size of the resource. The two conventional approaches currently used in US territory for handling of natural gas associated with crude petroleum production are re-injection and pipelining. Conversion of natural gas to a liquid product which can be transported to shore by tanker can be accomplished by FTP to produce hydrocarbons, or by conversion to chemical products such as methanol or ammonia, or by cryogenic liquefaction (LNG). This study considers FTP and briefly compares it to methanol and LNG. The Energy International Corporation cobalt catalyst, ratio adjusted, slurry bubble column F-T process was used as the basis for the study and the comparisons. An offshore F-T plant can best be accommodated by an FPSO (Floating Production, Storage, Offloading vessel) based on a converted surplus tanker, such as have been frequently used around the world recently. Other structure types used in deep water (platforms) are more expensive and cannot handle the required load.

  3. UNFCCC-Consolidated baseline and monitoring methodology for landfill...

    Open Energy Info (EERE)

    Consolidated baseline and monitoring methodology for landfill gas project activities Jump to: navigation, search Tool Summary LAUNCH TOOL Name: UNFCCC-Consolidated baseline and...

  4. Conversion of a diesel engine to a spark ignition natural gas engine

    SciTech Connect (OSTI)

    1996-09-01

    Requirements for alternatives to diesel-fueled vehicles are developing, particularly in urban centers not in compliance with mandated air quality standards. An operator of fleets of diesel- powered vehicles may be forced to either purchase new vehicles or equip some of the existing fleets with engines designed or modified to run on alternative fuels. In converting existing vehicles, the operator can either replace the existing engine or modify it to burn an alternative fuel. Work described in this report addresses the problem of modifying an existing diesel engine to operate on natural gas. Tecogen has developed a technique for converting turbocharged automotive diesel engines to operate as dedicated spark-ignition engines with natural gas fuel. The engine cycle is converted to a more-complete-expansion cycle in which the expansion ratio of the original engine is unchanged while the effective compression ratio is lowered, so that engine detonation is avoided. The converted natural gas engine, with an expansion ratio higher than in conventional spark- ignition natural gas engines, offers thermal efficiency at wide-open- throttle conditions comparable to its diesel counterpart. This allows field conversion of existing engines. Low exhaust emissions can be achieved when the engine is operated with precise control of the fuel air mixture at stoichiometry with a 3-way catalyst. A Navistar DTA- 466 diesel engine with an expansion ratio of 16.5 to 1 was converted in this way, modifying the cam profiles, increasing the turbocharger boost pressure, incorporating an aftercooler if not already present, and adding a spark-ignition system, natural gas fuel management system, throttle body for load control, and an electronic engine control system. The proof-of-concept engine achieved a power level comparable to that of the diesel engine without detonation. A conversion system was developed for the Navistar DT 466 engine. NOx emissions of 1.5 g/bhp-h have been obtained.

  5. Conversion of forest residues to a methane-rich gas: Interim Report

    SciTech Connect (OSTI)

    Feldmann, H.G.; Paisley, M.A.; Appelbaum, H.R.

    1986-03-01

    A process is being developed that produces a fuel gas with a heating value of 500 Btu/SCF from diverse forms of biomass, including shredded bark, wood chips, and sawdust. The system uses a high throughput, non-oxygen gasifier that employs sand circulation to supply process heat. Results obtained with a 10-inch I.D. gasifier are presented and compared with those in a 6-inch I.D. reactor. Feed rates up to 12 tons/day (dry) have been achieved corresponding to a specific wood throughput of 2000 lbs/ft/sup 2/-hr. Gas compositions in the two reactors are in excellent agreement and performance in the larger reactor, as measured by carbon conversion, is significantly improved. Cost projections comparing this process with direct combustion are presented that indicate gasification technology should have very significant cost advantages for both generation of plant steam and cogeneration of electricity. 5 refs., 14 figs., 5 tabs.

  6. Measurements of gas sorption from seawater and the influence of gas release on open-cycle ocean thermal energy conversion (OC-OTEC) system performance

    SciTech Connect (OSTI)

    Penney, T.R.; Althof, J.A.

    1985-06-01

    The technical community has questioned the validity and cost-effectiveness of open-cycle ocean thermal energy conversion (OC-OTEC) systems because of the unknown effect of noncondensable gas on heat exchanger performance and the power needed to run vacuum equipment to remove this gas. To date, studies of seawater gas desorption have not been prototypical for system level analysis. This study gives preliminary gas desorption data on a vertical spout, direct contact evaporator and multiple condenser geometries. Results indicate that dissolved gas can be substantially removed before the seawater enters the heat exchange process, reducing the uncertainty and effect of inert gas on heat exchanger performance.

  7. Landfill aeration worldwide: Concepts, indications and findings

    SciTech Connect (OSTI)

    Ritzkowski, M.; Stegmann, R.

    2012-07-15

    Highlights: Black-Right-Pointing-Pointer Different landfill aeration concepts and accordant application areas are described. Black-Right-Pointing-Pointer Examples of full scale projects are provided for Europe, North-America and Asia. Black-Right-Pointing-Pointer Major project findings are summarised, including prospects and limitations. Black-Right-Pointing-Pointer Inconsistencies between laboratory and full scale results have been elaborated. Black-Right-Pointing-Pointer An explanatory approach in connection with the inconsistencies is provided. - Abstract: The creation of sustainable landfills is a fundamental goal in waste management worldwide. In this connection landfill aeration contributes towards an accelerated, controlled and sustainable conversion of conventional anaerobic landfills into a biological stabilized state associated with a minimised emission potential. The technology has been successfully applied to landfills in Europe, North America and Asia, following different strategies depending on the geographical region, the specific legislation and the available financial resources. Furthermore, methodologies for the incorporation of landfill aeration into the carbon trade mechanisms have been developed in recent years. This manuscript gives an overview on existing concepts for landfill aeration; their application ranges and specifications. For all of the described concepts examples from different countries worldwide are provided, including details regarding their potentials and limitations. Some of the most important findings from these aeration projects are summarised and future research needs have been identified. It becomes apparent that there is a great demand for a systematisation of the available results and implications in order to further develop and optimise this very promising technology. The IWWG (International Waste Working Group) Task Group 'Landfill Aeration' contributes towards the achievement of this goal.

  8. System dynamics of the competition of municipal solid waste to landfill, electricity, and liquid fuel in California

    SciTech Connect (OSTI)

    Westbrook, Jessica; Malczynski, Leonard A.; Manley, Dawn Kataoka

    2014-03-01

    A quantitative system dynamics model was created to evaluate the economic and environmental tradeoffs between biomass to electricity and to liquid fuel using MSW biomass in the state of California as a case study. From an environmental perspective, landfilling represents the worst use of MSW over time, generating more greenhouse gas (GHG) emissions compared to converting MSW to liquid fuel or to electricity. MSW to ethanol results in the greatest displacement of GHG emissions per dollar spent compared to MSW to electricity. MSW to ethanol could save the state of California approximately $60 billion in energy costs by 2050 compared to landfilling, while also reducing GHG emissions state-wide by approximately 140 million metric tons during that timeframe. MSW conversion to electricity creates a significant cost within the state's electricity sector, although some conversion technologies are cost competitive with existing renewable generation.

  9. Aerobic landfill bioreactor

    DOE Patents [OSTI]

    Hudgins, Mark P; Bessette, Bernard J; March, John; McComb, Scott T.

    2000-01-01

    The present invention includes a method of decomposing municipal solid waste (MSW) within a landfill by converting the landfill to aerobic degradation in the following manner: (1) injecting air via the landfill leachate collection system (2) injecting air via vertical air injection wells installed within the waste mass; (3) applying leachate to the waste mass using a pressurized drip irrigation system; (4) allowing landfill gases to vent; and (5) adjusting air injection and recirculated leachate to achieve a 40% to 60% moisture level and a temperature between 120.degree. F. and 140.degree. F. in steady state.

  10. Aerobic landfill bioreactor

    DOE Patents [OSTI]

    Hudgins, Mark P; Bessette, Bernard J; March, John C; McComb, Scott T.

    2002-01-01

    The present invention includes a system of decomposing municipal solid waste (MSW) within a landfill by converting the landfill to aerobic degradation in the following manner: (1) injecting air via the landfill leachate collection system (2) injecting air via vertical air injection wells installed within the waste mass; (3) applying leachate to the waste mass using a pressurized drip irrigation system; (4) allowing landfill gases to vent; and (5) adjusting air injection and recirculated leachate to achieve a 40% to 60% moisture level and a temperature between 120.degree. F. and 140.degree. F. in steady state.

  11. Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

    2012-08-19

    The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

  12. Reducing Open Cell Landfill Methane Emissions with a Bioactive Alternative Daily

    SciTech Connect (OSTI)

    Helene Hilger; James Oliver; Jean Bogner; David Jones

    2009-03-31

    Methane and carbon dioxide are formed in landfills as wastes degrade. Molecule-for-molecule, methane is about 20 times more potent than carbon dioxide at trapping heat in the earth's atmosphere, and thus, it is the methane emissions from landfills that are scrutinized. For example, if emissions composed of 60% methane and 40% carbon dioxide were changed to a mix that was 40% methane and 60% carbon dioxide, a 30% reduction in the landfill's global warming potential would result. A 10% methane, 90% carbon dioxide ratio will result in a 75% reduction in global warming potential compared to the baseline. Gas collection from a closed landfill can reduce emissions, and it is sometimes combined with a biocover, an engineered system where methane oxidizing bacteria living in a medium such as compost, convert landfill methane to carbon dioxide and water. Although methane oxidizing bacteria merely convert one greenhouse gas (methane) to another (carbon dioxide), this conversion can offer significant reductions in the overall greenhouse gas contribution, or global warming potential, associated with the landfill. What has not been addressed to date is the fact that methane can also escape from a landfill when the active cell is being filled with waste. Federal regulations require that newly deposited solid waste to be covered daily with a 6 in layer of soil or an alternative daily cover (ADC), such as a canvas tarp. The aim of this study was to assess the feasibility of immobilizing methane oxidizing bacteria into a tarp-like matrix that could be used for alternative daily cover at open landfill cells to prevent methane emissions. A unique method of isolating methanotrophs from landfill cover soil was used to create a liquid culture of mixed methanotrophs. A variety of prospective immobilization techniques were used to affix the bacteria in a tarp-like matrix. Both gel encapsulation of methanotrophs and gels with liquid cores containing methanotrophs were readily made but prone to rapid desiccation. Bacterial adsorption onto foam padding, natural sponge, and geotextile was successful. The most important factor for success appeared to be water holding capacity. Prototype biotarps made with geotextiles plus adsorbed methane oxidizing bacteria were tested for their responses to temperature, intermittent starvation, and washing (to simulate rainfall). The prototypes were mesophilic, and methane oxidation activity remained strong after one cycle of starvation but then declined with repeated cycles. Many of the cells detached with vigorous washing, but at least 30% appeared resistant to sloughing. While laboratory landfill simulations showed that four-layer composite biotarps made with two different types of geotextile could remove up to 50% of influent methane introduced at a flux rate of 22 g m{sup -2} d{sup -1}, field experiments did not yield high activity levels. Tests revealed that there were high hour-to-hour flux variations in the field, which, together with frequent rainfall events, confounded the field testing. Overall, the findings suggest that a methanotroph embedded biotarp appears to be a feasible strategy to mitigate methane emission from landfill cells, although the performance of field-tested biotarps was not robust here. Tarps will likely be best suited for spring and summer use, although the methane oxidizer population may be able to shift and adapt to lower temperatures. The starvation cycling of the tarp may require the capacity for intermittent reinoculation of the cells, although it is also possible that a subpopulation will adapt to the cycling and become dominant. Rainfall is not expected to be a major factor, because a baseline biofilm will be present to repopulate the tarp. If strong performance can be achieved and documented, the biotarp concept could be extended to include interception of other compounds beyond methane, such as volatile aromatic hydrocarbons and chlorinated solvents.

  13. Conversion of forest residues to a methane-rich gas in a high-throughput gasifier. Summary report

    SciTech Connect (OSTI)

    Feldmann, H.F.; Paisley, M.A.; Folsom, D.W.; Kim, B.C.

    1981-10-31

    Results of the experimental work conducted thus far have shown that wood can be readily gasified in a steam environment into a hydrocarbon rich fuel gas that can be used as a replacement for petroleum-based fuels or natural gas with minimal boiler retrofit. Further, this conversion can be achieved in a compact gasification reactor with heat supplied by a circulating entrained phase, thereby eliminating the need for an oxygen plant. Tars have not been found except at the lowest gasifier temperatures employed, and therefore heat recovery from the product gas should be much simpler than that from commercially available fixed-bed gasification systems where product gas contains significant quantities of tar. The data generated have been used in a preliminary conceptual design. Evaluation of this design has shown that a medium-Btu gas can be produced from wood at a cost competitive with natural gas or petroleum-based fuels.

  14. LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL

    SciTech Connect (OSTI)

    Don Augenstein; Ramin Yazdani; Rick Moore; Michelle Byars; Jeff Kieffer; Professor Morton Barlaz; Rinav Mehta

    2000-02-26

    Controlled landfilling is an approach to manage solid waste landfills, so as to rapidly complete methane generation, while maximizing gas capture and minimizing the usual emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated to more rapid and earlier completion to full potential by improving conditions (principally moisture, but also temperature) to optimize biological processes occurring within the landfill. Gas is contained through use of surface membrane cover. Gas is captured via porous layers, under the cover, operated at slight vacuum. A field demonstration project has been ongoing under NETL sponsorship for the past several years near Davis, CA. Results have been extremely encouraging. Two major benefits of the technology are reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times, more predictably, than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role both in reduction of US greenhouse gas emissions and in US renewable energy. The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with conventional landfills. This is the highest methane recovery rate per unit waste, and thus progress toward stabilization, documented anywhere for such a large waste mass. This high recovery rate is attributed to moisture, and elevated temperature attained inexpensively during startup. Economic analyses performed under Phase I of this NETL contract indicate ''greenhouse cost effectiveness'' to be excellent. Other benefits include substantial waste volume loss (over 30%) which translates to extended landfill life. Other environmental benefits include rapidly improved quality and stabilization (lowered pollutant levels) in liquid leachate which drains from the waste.

  15. Synthesis gas production by mixed conducting membranes with integrated conversion into liquid products

    DOE Patents [OSTI]

    Nataraj, Shankar; Russek, Steven Lee; Dyer, Paul Nigel

    2000-01-01

    Natural gas or other methane-containing feed gas is converted to a C.sub.5 -C.sub.19 hydrocarbon liquid in an integrated system comprising an oxygenative synthesis gas generator, a non-oxygenative synthesis gas generator, and a hydrocarbon synthesis process such as the Fischer-Tropsch process. The oxygenative synthesis gas generator is a mixed conducting membrane reactor system and the non-oxygenative synthesis gas generator is preferably a heat exchange reformer wherein heat is provided by hot synthesis gas product from the mixed conducting membrane reactor system. Offgas and water from the Fischer-Tropsch process can be recycled to the synthesis gas generation system individually or in combination.

  16. Gas Recovery Systems | Open Energy Information

    Open Energy Info (EERE)

    Systems Jump to: navigation, search Name: Gas Recovery Systems Place: California Zip: 94550 Product: Turnkey landfill gas (LFG) energy extraction systems. References: Gas Recovery...

  17. DFW Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    DFW Gas Recovery Biomass Facility Jump to: navigation, search Name DFW Gas Recovery Biomass Facility Facility DFW Gas Recovery Sector Biomass Facility Type Landfill Gas Location...

  18. Lake Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Gas Recovery Biomass Facility Jump to: navigation, search Name Lake Gas Recovery Biomass Facility Facility Lake Gas Recovery Sector Biomass Facility Type Landfill Gas Location Cook...

  19. CID Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    CID Gas Recovery Biomass Facility Jump to: navigation, search Name CID Gas Recovery Biomass Facility Facility CID Gas Recovery Sector Biomass Facility Type Landfill Gas Location...

  20. CSL Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    CSL Gas Recovery Biomass Facility Jump to: navigation, search Name CSL Gas Recovery Biomass Facility Facility CSL Gas Recovery Sector Biomass Facility Type Landfill Gas Location...

  1. BJ Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    BJ Gas Recovery Biomass Facility Jump to: navigation, search Name BJ Gas Recovery Biomass Facility Facility BJ Gas Recovery Sector Biomass Facility Type Landfill Gas Location...

  2. Nonthermal plasma systems and methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C.; Nelson, Lee O.; Detering, Brent A.

    2005-05-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  3. Illinois Turning Landfill Trash into Future Cash

    Broader source: Energy.gov [DOE]

    Will County, Illinois officials yesterday formally broke ground on a new $7 million project (that includes $1 million of Energy Efficiency Conservation Block Grant funds) to turn methane gas from the Prairie View Landfill into electricity in a partnership with Waste Management. Will County will receive revenue from the sale of the gas created from decomposing garbage which will be harnessed and converted to generate 4.8 megawatts of green electrical power and used to power up to 8,000 homes. The future revenue generated from the sale of the gas and the sale of the electricity could reach $1 million annually.

  4. The contribution of gas-phase reactions in the Pt-catalyzed conversion of ethane-oxygen mixtures

    SciTech Connect (OSTI)

    Huff, M.C.; Androulakis, I.P.; Sinfelt, J.H.; Reyes, S.C.

    2000-04-01

    This paper presents an analysis of the oxidative dehydrogenation of ethane on platinum-containing monoliths. The purpose of the work is to make a quantitative assessment of the extent to which homogeneous gas-phase reactions contribute to the overall conversion of the ethane. In making the analysis, extensive use is made of kinetic information obtained and compiled by A.M. Dean and associates for elementary homogeneous reaction steps and by L.D. Schmidt and associates for elementary surface reactions. A critical part of the analysis is concerned with accounting for the heat effects and for the reactor temperature gradient resulting therefrom. This is absolutely essential for meeting the objective of this investigation. The rise in temperature as the gases proceed through the reactor is responsible for a very substantial contribution of homogeneous gas-phase reactions in the chemical transformation occurring. one can view the process as a sequential one in which ethane is first oxidized on the platinum surface to CO, CO{sub 2} and H{sub 2}O in the front region of the monolith. The formation of these products causes a substantial temperature increase that drives the dehydrogenation of ethane to ethylene (and acetylene) in the gas phase. The heat required to sustain these endothermic reactions in the tail end of the reaction zone is supplied by exothermic gas-phase oxidation reactions that form additional H{sub 2}O and CO. Overall, the system can be viewed as one in which the catalyst initiates gas-phase chemistry through the acceleration of exothermic reactions at the front of the reactor which increase the downstream temperature to the point where gas-phase reactions occur readily.

  5. Catalyst for selective conversion of synthesis gas and method of making the catalyst

    DOE Patents [OSTI]

    Dyer, Paul N.; Pierantozzi, Ronald

    1986-01-01

    A Fischer-Tropsch (F-T) catalyst, a method of making the catalyst and an F-T process utilizing the catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range. In general, the selective and notably stable catalyst, consists of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of an F-T metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

  6. Ocean thermal energy conversion gas desorption studies. Volume 1. Design of experiments. [Open-cycle power systems

    SciTech Connect (OSTI)

    Golshani, A.; Chen, F.C.

    1980-10-01

    Seawater deaeration is a process affecting almost all proposed Ocean Thermal Energy Conversion (OTEC) open-cycle power systems. If the noncondensable dissolved air is not removed from a power system, it will accumulate in thecondenser, reduce the effectiveness of condensation, and result in deterioration of system performance. A gas desorption study is being conducted at Oak Ridge National Laboratory (ORNL) with the goal of mitigating these effects; this study is designed to investigate the vacuum deaeration process for low-temperature OTEC conditions where conventional steam stripping deaeration may not be applicable. The first in a series describing the ORNL studies, this report (1) considers the design of experiments and discusses theories of gas desorption, (2) reviews previous relevant studies, (3) describes the design of a gas desorption test loop, and (4) presents the test plan for achieving program objectives. Results of the first series of verification tests and the uncertainties encountered are also discussed. A packed column was employed in these verification tests and test data generally behaved as in previous similar studies. Results expressed as the height of transfer unit (HTU) can be correlated with the liquid flow rate by HTU = 4.93L/sup 0/ /sup 25/. End effects were appreciable for the vacuum deaeration system, and a correlation of them to applied vacuum pressure was derived.

  7. Phytoremediation of landfill leachate

    SciTech Connect (OSTI)

    Jones, D.L. . E-mail: d.jones@bangor.ac.uk; Williamson, K.L.; Owen, A.G.

    2006-07-01

    Leachate emissions from landfill sites are of concern, primarily due to their toxic impact when released unchecked into the environment, and the potential for landfill sites to generate leachate for many hundreds of years following closure. Consequently, economically and environmentally sustainable disposal options are a priority in waste management. One potential option is the use of soil-plant based remediation schemes. In many cases, using either trees (including short rotation coppice) or grassland, phytoremediation of leachate has been successful. However, there are a significant number of examples where phytoremediation has failed. Typically, this failure can be ascribed to excessive leachate application and poor management due to a fundamental lack of understanding of the plant-soil system. On balance, with careful management, phytoremediation can be viewed as a sustainable, cost effective and environmentally sound option which is capable of treating 250 m{sup 3} ha{sup -1} yr{sup -1}. However, these schemes have a requirement for large land areas and must be capable of responding to changes in leachate quality and quantity, problems of scheme establishment and maintenance, continual environmental monitoring and seasonal patterns of plant growth. Although the fundamental underpinning science is well understood, further work is required to create long-term predictive remediation models, full environmental impact assessments, a complete life-cycle analysis and economic analyses for a wide range of landfill scenarios.

  8. Method for the catalytic conversion of organic materials into a product gas

    DOE Patents [OSTI]

    Elliott, Douglas C.; Sealock, Jr., L. John; Baker, Eddie G.

    1997-01-01

    A method for converting organic material into a product gas includes: a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300.degree. C. to about 450.degree. C.; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen.

  9. Method for the catalytic conversion of organic materials into a product gas

    DOE Patents [OSTI]

    Elliott, D.C.; Sealock, L.J. Jr.; Baker, E.G.

    1997-04-01

    A method for converting organic material into a product gas includes: (a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; (b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and (c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300 C to about 450 C; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen. 5 figs.

  10. Altamont Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    search Name Altamont Gas Recovery Biomass Facility Facility Altamont Gas Recovery Sector Biomass Facility Type Landfill Gas Location Alameda County, California Coordinates...

  11. Advanced Natural Gas Reciprocating Engines (ARES)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    with Stoichiometric combustion, Exhaust Gas Recirculation, Advanced Three Way Catalyst ... (operate with non- std gases: landfill gas and other renewables) Non-std gases ...

  12. Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

  13. Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report

    SciTech Connect (OSTI)

    Mills, G. [Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology

    1993-05-01

    The manufacture of liquid energy fuels from syngas (a mixture of H{sub 2} and CO, usually containing CO{sub 2}) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

  14. Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report

    SciTech Connect (OSTI)

    Mills, G. (Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology)

    1993-05-01

    The manufacture of liquid energy fuels from syngas (a mixture of H[sub 2] and CO, usually containing CO[sub 2]) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

  15. 7.4 Landfill Methane Utilization

    Broader source: Energy.gov [DOE]

    A chapter on Landfill Methane Utilization from the Clean Energy Strategies for Local Governments publication.

  16. Landfill siting in New York: Case studies confirming the importance of site-specific hydrogeologic investigations

    SciTech Connect (OSTI)

    Cloyd, K.C.; Concannon, P.W. )

    1993-03-01

    Landfill siting is one of the most problematic environmental issues facing society today for a variety of both technical and political reasons. New York State has approached many of these issues by requiring both generalized siting studies and detailed hydrogeologic evaluation of any proposed landfill site. Geographic Information Systems (GIS) have emerged as an appropriate tool for accumulating information for preliminary decision making. Recently, Goodman and others have suggested the use of a terrain suitability map (land use map) as a mechanism for simplifying landfill siting. They propose the use of existing geologic and morphologic information to eliminate large areas of New York from consideration as potential landfill locations. The study concludes that the Appalachian Plateau region (the Southern Tier), and the Erie-Ontario Plain are the most suitable areas for landfill development in the state. An evaluation of the geology at existing landfills and the impacts that relate to the facilities has shown that suitable sites do indeed exist in areas deemed unacceptable by Goodman and others. Conversely, a number of landfills located in suitable terranes have proven to be developed on less than suitable sites. While evaluation of existing information plays an obvious role in preliminary siting studies, it is not a substitute for detailed hydrogeologic investigation. It is local hydrogeological conditions that are most important in determining the suitability of a site for landfill development rather than the regional geologic context of the site.

  17. Steam Generator Component Model in a Combined Cycle of Power Conversion Unit for Very High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    Oh, Chang H; Han, James; Barner, Robert; Sherman, Steven R

    2007-06-01

    The Department of Energy and the Idaho National Laboratory are developing a Next Generation Nuclear Plant (NGNP), Very High Temperature Gas-Cooled Reactor (VHTR) to serve as a demonstration of state-of-the-art nuclear technology. The purpose of the demonstration is two fold 1) efficient low cost energy generation and 2) hydrogen production. Although a next generation plant could be developed as a single-purpose facility, early designs are expected to be dual-purpose. While hydrogen production and advanced energy cycles are still in its early stages of development, research towards coupling a high temperature reactor, electrical generation and hydrogen production is under way. A combined cycle is considered as one of the power conversion units to be coupled to the very high-temperature gas-cooled reactor (VHTR). The combined cycle configuration consists of a Brayton top cycle coupled to a Rankine bottoming cycle by means of a steam generator. A detailed sizing and pressure drop model of a steam generator is not available in the HYSYS processes code. Therefore a four region model was developed for implementation into HYSYS. The focus of this study was the validation of a HYSYS steam generator model of two phase flow correlations. The correlations calculated the size and heat exchange of the steam generator. To assess the model, those calculations were input into a RELAP5 model and its results were compared with HYSYS results. The comparison showed many differences in parameters such as the heat transfer coefficients and revealed the different methods used by the codes. Despite differences in approach, the overall results of heat transfer were in good agreement.

  18. Bioelectrochemical Integration of Waste Heat Recovery, Waste-to-Energy Conversion, and Waste-to-Chemical Conversion with Industrial Gas and Chemical Manufacturing Processes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    John Cirucci Air Products and Chemicals, Inc. U.S. DOE Advanced Manufacturing Office Peer Review Meeting Washington, D.C. May 6-7, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Objective Develop a novel system that produces electricity or hydrogen from waste heat conversion and waste effluent oxidation waste water effluent treated effluent dual benefit process waste heat electricity or hydrogen Issues with existing,

  19. Livingston Parish Landfill Methane Recovery Project (Feasibility Study)

    SciTech Connect (OSTI)

    White, Steven

    2012-11-15

    The Woodside Landfill is owned by Livingston Parish, Louisiana and is operated under contract by Waste Management of Louisiana LLC. This public owner/private operator partnership is commonplace in the solid waste industry today. The landfill has been in operation since approximately 1988 and has a permitted capacity of approximately 41 million cubic yards. Based on an assumed in-place waste density of 0.94 ton per cubic yard, the landfill could have an expected design capacity of 39.3 million tons. The landfill does have an active landfill gas collection and control system (LFGCCS) in place because it meets the minimum thresholds for the New Source Performance Standards (NSPS). The initial LFGCS was installed prior to 2006 and subsequent phases were installed in 2007 and 2010. The Parish received a grant from the United States Department of Energy in 2009 to evaluate the potential for landfill gas recovery and utilization at the Woodside Landfill. This includes a technical and economic feasibility study of a project to install a landfill gas to energy (LFGTE) plant and to compare alternative technologies. The LFGTE plant can take the form of on-site electrical generation, a direct use/medium Btu option, or a high-Btu upgrade technology. The technical evaluation in Section 2 of this report concludes that landfill gas from the Woodside landfill is suitable for recovery and utilization. The financial evaluations in sections 3, 4, and 5 of this report provide financial estimates of the returns for various utilization technologies. The report concludes that the most economically viable project is the Electricity Generation option, subject to the Parish’s ability and willingness to allocate adequate cash for initial capital and/or to obtain debt financing. However, even this option does not present a solid return: by our estimates, there is a 19 year simple payback on the electricity generation option. All of the energy recovery options discussed in this report economically stressed. The primary reason for this is the recent fundamental shift in the US energy landscape. Abundant supplies of natural gas have put downward pressure on any project that displaces natural gas or natural gas substitutes. Moreover, this shift appears long-term as domestic supplies for natural gas may have been increased for several hundred years. While electricity prices are less affected by natural gas prices than other thermal projects, they are still significantly affected since much of the power in the Entergy cost structure is driven by natural gas-fired generation. Consequently, rates reimbursed by the power company based on their avoided cost structure also face downward pressure over the near and intermediate term. In addition, there has been decreasing emphasis on environmental concerns regarding the production of thermal energy, and as a result both the voluntary and mandatory markets that drive green attribute prices have softened significantly over the past couple of years. Please note that energy markets are constantly changing due to fundamental supply and demand forces, as well as from external forces such as regulations and environmental concerns. At any point in the future, the outlook for energy prices may change and could deem either the electricity generation or pipeline injection project more feasible. This report is intended to serve as the primary background document for subsequent decisions made at Parish staff and governing board levels.

  20. Landfilling ash/sludge mixtures

    SciTech Connect (OSTI)

    Benoit, J.; Eighmy, T.T.; Crannell, B.S.

    1999-10-01

    The geotechnical properties of a mixture of municipal solid waste incinerator bottom ash and municipal wastewater treatment plant sludge was investigated for a proposed ash/sludge secure landfill. The components as well as mixtures ranging from 10:1 to 5:1 (ash:sludge, by volume) were evaluated, where appropriate, for a number of geotechnical index and mechanical properties including particle size, water content, specific gravity, density-moisture relationships, shear strength, and compressibility. The results from a compactibility study and stability analysis of the proposed landfill were used to help approve a landfill codisposal concept; a full-scale facility was constructed and is currently operating successfully.

  1. Evaluation of methane emissions from Palermo municipal landfill: Comparison between field measurements and models

    SciTech Connect (OSTI)

    Di Bella, Gaetano; Di Trapani, Daniele; Viviani, Gaspare

    2011-08-15

    Methane (CH{sub 4}) diffuse emissions from Municipal Solid Waste (MSW) landfills represent one of the most important anthropogenic sources of greenhouse gas. CH{sub 4} is produced by anaerobic biodegradation of organic matter in landfilled MSW and constitutes a major component of landfill gas (LFG). Gas recovery is a suitable method to effectively control CH{sub 4} emissions from landfill sites and the quantification of CH{sub 4} emissions represents a good tool to evaluate the effectiveness of a gas recovery system in reducing LFG emissions. In particular, LFG emissions can indirectly be evaluated from mass balance equations between LFG production, recovery and oxidation in the landfill, as well as by a direct approach based on LFG emission measurements from the landfill surface. However, up to now few direct measurements of landfill CH{sub 4} diffuse emissions have been reported in the technical literature. In the present study, both modeling and direct emission measuring methodologies have been applied to the case study of Bellolampo landfill located in Palermo, Italy. The main aim of the present study was to evaluate CH{sub 4} diffuse emissions, based on direct measurements carried out with the flux accumulation chamber (static, non-stationary) method, as well as to obtain the CH{sub 4} contoured flux map of the landfill. Such emissions were compared with the estimate achieved by means of CH{sub 4} mass balance equations. The results showed that the emissions obtained by applying the flux chamber method are in good agreement with the ones derived by the application of the mass balance equation, and that the evaluated contoured flux maps represent a reliable tool to locate areas with abnormal emissions in order to optimize the gas recovery system efficiency.

  2. Byxbee Park Sanitary Landfill Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Byxbee Park Sanitary Landfill Biomass Facility Jump to: navigation, search Name Byxbee Park Sanitary Landfill Biomass Facility Facility Byxbee Park Sanitary Landfill Sector Biomass...

  3. Blackburn Landfill Co-Generation Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    Blackburn Landfill Co-Generation Biomass Facility Jump to: navigation, search Name Blackburn Landfill Co-Generation Biomass Facility Facility Blackburn Landfill Co-Generation...

  4. Miramar Landfill Metro Biosolids Center Biomass Facility | Open...

    Open Energy Info (EERE)

    Miramar Landfill Metro Biosolids Center Biomass Facility Jump to: navigation, search Name Miramar Landfill Metro Biosolids Center Biomass Facility Facility Miramar Landfill Metro...

  5. EA-1997: Construction Landfill Expansion, Pantex Plant, Amarillo...

    Office of Environmental Management (EM)

    7: Construction Landfill Expansion, Pantex Plant, Amarillo, Texas EA-1997: Construction Landfill Expansion, Pantex Plant, Amarillo, Texas SUMMARY Construction Landfill Expansion,...

  6. EA-1707: Closure of Nonradioactive Dangerous Waste Landfill and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    07: Closure of Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill, Hanford Site, Richland, Washington EA-1707: Closure of Nonradioactive Dangerous Waste Landfill and...

  7. Prima Desheha Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Prima Desheha Landfill Biomass Facility Jump to: navigation, search Name Prima Desheha Landfill Biomass Facility Facility Prima Desheha Landfill Sector Biomass Facility Type...

  8. Risk assessment of landfill disposal sites - State of the art

    SciTech Connect (OSTI)

    Butt, Talib E. Lockley, Elaine; Oduyemi, Kehinde O.K.

    2008-07-01

    A risk assessment process can assist in drawing a cost-effective compromise between economic and environmental costs, thereby assuring that the philosophy of 'sustainable development' is adhered to. Nowadays risk analysis is in wide use to effectively manage environmental issues. Risk assessment is also applied to other subjects including health and safety, food, finance, ecology and epidemiology. The literature review of environmental risk assessments in general and risk assessment approaches particularly regarding landfill disposal sites undertaken by the authors, reveals that an integrated risk assessment methodology for landfill gas, leachate or degraded waste does not exist. A range of knowledge gaps is discovered in the literature reviewed to date. From the perspective of landfill leachate, this paper identifies the extent to which various risk analysis aspects are absent in the existing approaches.

  9. LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL

    SciTech Connect (OSTI)

    Don Augenstein

    2001-02-01

    The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with conventional landfills. This is the highest methane recovery rate per unit waste, and thus progress toward stabilization, documented anywhere for such a large waste mass. This high recovery rate is attributed to moisture, and elevated temperature attained inexpensively during startup. Economic analyses performed under Phase I of this NETL contract indicate ''greenhouse cost effectiveness'' to be excellent. Other benefits include substantial waste volume loss (over 30%) which translates to extended landfill life. Other environmental benefits include rapidly improved quality and stabilization (lowered pollutant levels) in liquid leachate which drains from the waste.

  10. Chestnut Ridge Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    Chestnut Ridge Gas Recovery Sector Biomass Facility Type Landfill Gas Location Anderson County, Tennessee Coordinates 36.0809574, -84.2278796 Show Map Loading map......

  11. Modified biochemical methane potential (BMP) assays to assess biodegradation potential of landfilled refuse

    SciTech Connect (OSTI)

    Bogner, J.E.; Rose, C.; Piorkowski, R.

    1989-01-01

    Modified Biochemical Methane Potential (BMP) assays were used to assess biogas production potential of solid landfill samples. In landfill samples with visible soil content, moisture addition alone was generally as effective at stimulating biogas production as the addition of a comprehensive nutrient media. In a variety of samples from humid and semiarid landfills, addition of an aqueous nutrient media was the most effective stimulant for biogas production; however, moisture addition was almost as effective for most samples, suggesting that water addition would be the most cost-effective field approach. Onset of methanogenesis was slower in fresh refuse samples (even when inoculated with anaerobic digester sludge) than in landfill samples, indicating that the soil into which materials are landfilled is a major source of microorganisms. High volatile solids loading in fresh refuse and landfill assays retarded methanogenesis. A comparison of anaerobic and aerobic sample handling techniques showed no significant differences with regard to onset of methanogenesis and total gas production. The technique shows initial promise with regard to replication and reproducibility of results and could be a meaningful addition to landfill site evaluations where commercial gas recovery is anticipated. The BMP technique could also be adapted to assess anaerobic biodegradability of other solid waste materials for conventional anaerobic digestion applications. 9 refs., 6 figs., 2 tabs.

  12. Stable isotope signatures for characterising the biological stability of landfilled municipal solid waste

    SciTech Connect (OSTI)

    Wimmer, Bernhard; Hrad, Marlies; Huber-Humer, Marion; Watzinger, Andrea; Wyhlidal, Stefan; Reichenauer, Thomas G.

    2013-10-15

    Highlights: ? The isotopic signature of ?{sup 13}C-DIC of leachates is linked to the reactivity of MSW. ? Isotopic signatures of leachates depend on aerobic/anaerobic conditions in landfills. ? In situ aeration of landfills can be monitored by isotope analysis in leachate. ? The isotopic analysis of leachates can be used for assessing the stability of MSW. ? ?{sup 13}C-DIC of leachates helps to define the duration of landfill aftercare. - Abstract: Stable isotopic signatures of landfill leachates are influenced by processes within municipal solid waste (MSW) landfills mainly depending on the aerobic/anaerobic phase of the landfill. We investigated the isotopic signatures of ?{sup 13}C, ?{sup 2}H and ?{sup 18}O of different leachates from lab-scale experiments, lysimeter experiments and a landfill under in situ aeration. In the laboratory, columns filled with MSW of different age and reactivity were percolated under aerobic and anaerobic conditions. In landfill simulation reactors, waste of a 25 year old landfill was kept under aerobic and anaerobic conditions. The lysimeter facility was filled with mechanically shredded fresh waste. After starting of the methane production the waste in the lysimeter containments was aerated in situ. Leachate and gas composition were monitored continuously. In addition the seepage water of an old landfill was collected and analysed periodically before and during an in situ aeration. We found significant differences in the ?{sup 13}C-value of the dissolved inorganic carbon (?{sup 13}C-DIC) of the leachate between aerobic and anaerobic waste material. During aerobic degradation, the signature of ?{sup 13}C-DIC was mainly dependent on the isotopic composition of the organic matter in the waste, resulting in a ?{sup 13}C-DIC of ?20 to ?25. The production of methane under anaerobic conditions caused an increase in ?{sup 13}C-DIC up to values of +10 and higher depending on the actual reactivity of the MSW. During aeration of a landfill the aerobic degradation of the remaining organic matter caused a decrease to a ?{sup 13}C-DIC of about ?20. Therefore carbon isotope analysis in leachates and groundwater can be used for tracing the oxidationreduction status of MSW landfills. Our results indicate that monitoring of stable isotopic signatures of landfill leachates over a longer time period (e.g. during in situ aeration) is a powerful and cost-effective tool for characterising the biodegradability and stability of the organic matter in landfilled municipal solid waste and can be used for monitoring the progress of in situ aeration.

  13. Design, Synthesis, and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

    SciTech Connect (OSTI)

    Enrique Iglesia; Akio Ishikawa; Manual Ojeda; Nan Yao

    2007-09-30

    A detailed study of the catalyst composition, preparation and activation protocol of Fe-based catalysts for the Fischer-Tropsch Synthesis (FTS) have been carried out in this project. We have studied the effects of different promoters on the catalytic performance of Fe-based catalysts. Specifically, we have focused on how their sequence of addition dramatically influences the performance of these materials in the Fischer-Tropsch synthesis. The resulting procedures have been optimized to improve further upon the already unprecedented rates and C{sub 5+} selectivities of the Fe-based catalysts that we have developed as part of this project. Selectivity to C{sub 5+} hydrocarbon was close to 90 % (CO{sub 2}-free basis) and CO conversion rate was about 6.7 mol h{sup -1} g-at Fe{sup -1} at 2.14 MPa, 508 K and with substoichiometric synthesis gas; these rates were larger than any reported previously for Fe-based FTS catalysts at these conditions. We also tested the stability of Fe-based catalysts during FTS reaction (10 days); as a result, the high hydrocarbon formation rates were maintained during 10 days, though the gradual deactivation was observed. Our investigation has also focused on the evaluation of Fe-based catalysts with hydrogen-poor synthesis gas streams (H{sub 2}/CO=1). We have observed that the Fe-based catalysts prepared in this project display also a high hydrocarbon synthesis rate with substoichiometric synthesis gas (H{sub 2}/CO=1) stream, which is a less desirable reactant mixture than stoichiometric synthesis gas (H{sub 2}/CO=2). We have improved the catalyst preparation protocols and achieved the highest FTS reaction rates and selectivities so far reported at the low temperatures required for selectivity and stability. Also, we have characterized the catalyst structural change and active phases formed, and their catalytic behavior during the activation process to evaluate their influences on FTS reaction. The efforts of this project led to (i) structural evolution of Fe-Zn oxide promoted with K and Cu, and (ii) evaluation of hydrocarbon and CH{sub 4} formation rates during activation procedures at various temperature and H{sub 2}/CO ratios. On the basis of the obtained results, we suggest that lower reactor temperature can be sufficient to activate catalysts and lead to the high FTS performance. In this project, we have also carried out a detailed kinetic and mechanistic study of the Fischer-Tropsch Synthesis with Fe-based catalysts. We have proposed a reaction mechanism with two CO activation pathways: unassisted and H-assisted. Both routes lead to the formation of the same surface monomers (CH{sub 2}). However, the oxygen removal mechanism is different. In the H-assisted route, oxygen is removed exclusively as water, while oxygen is rejected as carbon dioxide in the unassisted CO dissociation. The validity of the mechanism here proposed has been found to be in agreement with the experimental observation and with theoretical calculations over a Fe(110) surface. Also, we have studied the validity of the mechanism that we propose by analyzing the H{sub 2}/D{sub 2} kinetic isotope effect (r{sub H}/r{sub D}) over a conventional iron-based Fischer-Tropsch catalyst Fe-Zn-K-Cu. We have observed experimentally that the use of D{sub 2} instead of H{sub 2} leads to higher hydrocarbons formation rates (inverse kinetic isotopic effect). On the contrary, primary carbon dioxide formation is not influenced. These experimental observations can be explained by two CO activation pathways. We have also explored the catalytic performance of Co-based catalysts prepared by using inverse micelles techniques. We have studied several methods in order to terminate the silanol groups on SiO{sub 2} support including impregnation, urea homogeneous deposition-precipitation, or zirconium (IV) ethoxide titration. Although hydroxyl groups on the SiO{sub 2} surface are difficult to be stoichiometrically titrated by ZrO{sub 2}, a requirement to prevent the formation of strongly-interacting Co oxide species on SiO{sub 2}, modification of ZrO{sub 2} on SiO{sub 2} surface can improve the Co clusters dispersion leading to a marked increase in the number of accessible Co sites. Inverse micelle method allowed the synthesis of small Co clusters on SiO{sub 2}, but the required surfactant removal steps led to the re-oxidation of Co metal clusters and to the formation of difficult to reduce CoO{sub x} species.

  14. Guidelines for Conversion of Diesel Buses to Compressed Natural...

    Open Energy Info (EERE)

    Conversion of Diesel Buses to Compressed Natural Gas Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Guidelines for Conversion of Diesel Buses to Compressed Natural Gas...

  15. Short Mountain Landfill gas recovery project

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The Bonneville Power Administration (BPA), a Federal power marketing agency, has statutory responsibilities to supply electrical power to its utility, industrial, and other customers in the Pacific Northwest. BPA's latest load/resource balance forecast, projects the capability of existing resources to satisfy projected Federal system loads. The forecast indicates a potential resource deficit. The underlying need for action is to satisfy BPA customers' demand for electrical power.

  16. Comparison of slope stability in two Brazilian municipal landfills

    SciTech Connect (OSTI)

    Gharabaghi, B. Singh, M.K.; Inkratas, C. Fleming, I.R. McBean, E.

    2008-07-01

    The implementation of landfill gas to energy (LFGTE) projects has greatly assisted in reducing the greenhouse gases and air pollutants, leading to an improved local air quality and reduced health risks. The majority of cities in developing countries still dispose of their municipal waste in uncontrolled 'open dumps.' Municipal solid waste landfill construction practices and operating procedures in these countries pose a challenge to implementation of LFGTE projects because of concern about damage to the gas collection infrastructure (horizontal headers and vertical wells) caused by minor, relatively shallow slumps and slides within the waste mass. While major slope failures can and have occurred, such failures in most cases have been shown to involve contributory factors or triggers such as high pore pressures, weak foundation soil or failure along weak geosynthetic interfaces. Many researchers who have studied waste mechanics propose that the shear strength of municipal waste is sufficient such that major deep-seated catastrophic failures under most circumstances require such contributory factors. Obviously, evaluation of such potential major failures requires expert analysis by geotechnical specialists with detailed site-specific information regarding foundation soils, interface shearing resistances and pore pressures both within the waste and in clayey barrier layers or foundation soils. The objective of this paper is to evaluate the potential use of very simple stability analyses which can be used to study the potential for slumps and slides within the waste mass and which may represent a significant constraint on construction and development of the landfill, on reclamation and closure and on the feasibility of a LFGTE project. The stability analyses rely on site-specific but simple estimates of the unit weight of waste and the pore pressure conditions and use 'generic' published shear strength envelopes for municipal waste. Application of the slope stability analysis method is presented in a case study of two Brazilian landfill sites; the Cruz das Almas Landfill in Maceio and the Muribeca Landfill in Recife. The Muribeca site has never recorded a slope failure and is much larger and better-maintained when compared to the Maceio site at which numerous minor slumps and slides have been observed. Conventional limit-equilibrium analysis was used to calculate factors of safety for stability of the landfill side slopes. Results indicate that the Muribeca site is more stable with computed factors of safety values in the range 1.6-2.4 compared with computed values ranging from 0.9 to 1.4 for the Maceio site at which slope failures have been known to occur. The results suggest that this approach may be useful as a screening-level tool when considering the feasibility of implementing LFGTE projects.

  17. Sanitary landfill groundwater monitoring data

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-05-01

    This report for first quarter 1992 contains sanitary landfill groundwater monitoring data for the Savannah River Plant. The data tables presented in this report are copies of draft analytical results and therefore do contain errors. These errors will be corrected when the finalized data is received from the laboratory.

  18. Case studies in alternative landfill design

    SciTech Connect (OSTI)

    Barbagallo, J.C.; Druback, G.W.

    1995-12-31

    In the past, landfills or {open_quotes}dumps{close_quotes} were not highly regulated and typically did not require a detailed engineering design. However, landfills are no longer just holes in the ground, and landfill closures entail more than just spreading some dirt on top of piles of garbage. Today landfill design is a highly regulated, complex design effort that integrates soils and geosynthetics into systems aimed at providing long-term protection for the environment and surrounding communities. Integrating these complex design systems into the available landscape and exising landfill configuration often requires the designer go beyond the {open_quotes}typical{close_quotes} landfill and landfill closure design to satisfy regulations and provide cost-effective solutions.

  19. Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and Chemicals

    Broader source: Energy.gov [DOE]

    Breakout Session 1: New Developments and Hot Topics Session 1-D: Natural Gas & Biomass to Liquids Suresh Babu, Senior Program Manager, Biomass Program Development, Brookhaven National Laboratory

  20. Estimating water content in an active landfill with the aid of GPR

    SciTech Connect (OSTI)

    Yochim, April, E-mail: ayochim@regionofwaterloo.ca [Region of Waterloo Waste Management Division, 925 Erb Street West, Waterloo, ON N2J 3Z4 (Canada); Zytner, Richard G., E-mail: rzytner@uoguelph.ca [School of Engineering, University of Guelph, Guelph, ON N1G 2W1 (Canada); McBean, Edward A., E-mail: emcbean@uoguelph.ca [School of Engineering, University of Guelph, Guelph, ON N1G 2W1 (Canada); Endres, Anthony L., E-mail: alendres@sciborg.uwaterloo.ca [Dept. of Earth and Environmental Sciences, University of Waterloo, Waterloo, ON N2L 3G1 (Canada)

    2013-10-15

    Highlights: Limited information in the literature on the use of GPR to measure in situ water content in a landfill. Developed GPR method allows measurement of in situ water content in a landfill. Developed GPR method is appealing to waste management professionals operating landfills. - Abstract: Landfill gas (LFG) receives a great deal of attention due to both negative and positive environmental impacts, global warming and a green energy source, respectively. However, predicting the quantity of LFG generated at a given landfill, whether active or closed is difficult due to the heterogeneities present in waste, and the lack of accurate in situ waste parameters like water content. Accordingly, ground penetrating radar (GPR) was evaluated as a tool for estimating in situ water content. Due to the large degree of subsurface heterogeneity and the electrically conductive clay cap covering landfills, both of which affect the transmission of the electromagnetic pulses, there is much scepticism concerning the use of GPR to quantify in situ water content within a municipal landfill. Two landfills were studied. The first landfill was used to develop the measurement protocols, while the second landfill provided a means of confirming these protocols. GPR measurements were initially completed using the surface GPR approach, but the lack of success led to the use of borehole (BH) GPR. Both zero offset profiling (ZOP) and multiple offset gathers (MOG) modes were tried, with the results indicating that BH GPR using the ZOP mode is the most simple and efficient method to measure in situ water content. The best results were obtained at a separation distance of 2 m, where higher the water content, smaller the effective separation distance. However, an increase in water content did appear to increase the accuracy of the GPR measurements. For the effective separation distance of 2 m at both landfills, the difference between GPR and lab measured water contents were reasonable at 33.9% for the drier landfill and 18.1% for the wetter landfill. Infiltration experiments also showed the potential to measure small increases in water content.

  1. Feasibility study to evaluate plasma quench process for natural gas conversion applications. [Quarterly report], July 1, 1993--September 30, 1993

    SciTech Connect (OSTI)

    Thomas, C.P.; Kong, P.C.; Detering, B.A.

    1993-12-31

    The objective of this work was to conduct a feasibility study on a new process, called the plasma quench process, for the conversion of methane to acetylene. FY-1993 efforts were focused on determining the economic viability of this process using bench scale experimental data which was previously generated. This report presents the economic analysis and conclusions of the analysis. Future research directions are briefly described.

  2. Landfill reduction experience in The Netherlands

    SciTech Connect (OSTI)

    Scharff, Heijo

    2014-11-15

    Highlights: • ‘Zero waste’ initiatives never consider risks, side effects or experience of achieved low levels of landfill. • This paper provides insight into what works and what not. • Where strong gradients in regulations and tax occur between countries, waste will find its way to landfills across borders. • Strong landfill reduction can create a fierce competition over the remaining waste to be landfilled resulting in losses. • At some point a public organisation should take responsibility for the operation of a ‘safety net’ in waste management. - Abstract: Modern waste legislation aims at resource efficiency and landfill reduction. This paper analyses more than 20 years of landfill reduction in the Netherlands. The combination of landfill regulations, landfill tax and landfill bans resulted in the desired landfill reduction, but also had negative effects. A fierce competition developed over the remaining waste to be landfilled. In 2013 the Dutch landfill industry generated €40 million of annual revenue, had €58 million annual costs and therefore incurred an annual loss of €18 million. It is not an attractive option to prematurely end business. There is a risk that Dutch landfill operators will not be able to fulfil the financial obligations for closure and aftercare. Contrary to the polluter pays principle the burden may end up with society. EU regulations prohibiting export of waste for disposal are in place. Strong differentials in landfill tax rate between nations have nevertheless resulted in transboundary shipment of waste and in non-compliance with the self-sufficiency and proximity principles. During the transformation from a disposal society to a recycling society, it is important to carefully plan required capacity and to guide the reorganisation of the landfill sector. At some point, it is no longer profitable to provide landfill services. It may be necessary for public organisations or the state to take responsibility for the continued operation of a ‘safety net’ in waste management. Regulations have created a financial incentive to pass on the burden of monitoring and controlling the impact of waste to future generations. To prevent this, it is necessary to revise regulations on aftercare and create incentives to actively stabilise landfills.

  3. EA-1707: Closure of Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill, Hanford Site, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the potential environmental impacts of closing the Nonradioactive Dangerous Waste Landfill and the Solid Waste Landfill. The Washington State Department of Ecology is a cooperating agency in preparing this EA.

  4. Differences in volatile methyl siloxane (VMS) profiles in biogas from landfills and anaerobic digesters and energetics of VMS transformations

    SciTech Connect (OSTI)

    Tansel, Berrin Surita, Sharon C.

    2014-11-15

    Highlights: • In the digester gas, D4 and D5 comprised the 62% and 27% if siloxanes, respectively. • In landfill gas, the bulk of siloxanes were TMSOH (58%) followed by D4 (17%). • Methane utilization may be a possible mechanism for TMSOH formation in the landfills. • The geometric configurations of D4 and D5 molecules make them very stable. - Abstract: The objectives of this study were to compare the types and levels of volatile methyl siloxanes (VMS) present in biogas generated in the anaerobic digesters and landfills, evaluate the energetics of siloxane transformations under anaerobic conditions, compare the conditions in anaerobic digesters and municipal solid waste (MSW) landfills which result in differences in siloxane compositions. Biogas samples were collected at the South District Wastewater Treatment Plant and South Dade Landfill in Miami, Florida. In the digester gas, D4 and D5 comprised the bulk of total siloxanes (62% and 27%, respectively) whereas in the landfill gas, the bulk of siloxanes were trimethylsilanol (TMSOH) (58%) followed by D4 (17%). Presence of high levels of TMSOH in the landfill gas indicates that methane utilization may be a possible reaction mechanism for TMSOH formation. The free energy change for transformation of D5 and D4 to TMSOH either by hydrogen or methane utilization are thermodynamically favorable. Either hydrogen or methane should be present at relatively high concentrations for TMSOH formation which explains the high levels present in the landfill gas. The high bond energy and bond distance of the Si–O bond, in view of the atomic sizes of Si and O atoms, indicate that Si atoms can provide a barrier, making it difficult to break the Si–O bonds especially for molecules with specific geometric configurations such as D4 and D5 where oxygen atoms are positioned inside the frame formed by the large Si atoms which are surrounded by the methyl groups.

  5. DESIGN, SYNTHESIS, AND MECHANISTIC EVALUATION OF IRON-BASED CATALYSIS FOR SYNTHESIS GAS CONVERSION TO FUELS AND CHEMICALS

    SciTech Connect (OSTI)

    Jian Xu; Enrique Iglesia

    2004-03-31

    This project explores the extension of previously discovered Fe-based catalysts with unprecedented Fischer-Tropsch synthesis rate, selectivity, and ability to convert hydrogen-poor synthesis gas streams typical of those produced from coal and biomass sources. Contract negotiations between the U.S. Department of Energy and the University of California were completed on December 9, 2004. During this first reporting period, we have modified and certified a previously decommissioned microreactor, ordered and installed a budgeted gas chromatograph, developed and reviewed safe operating procedures and data analysis methods, and reproduced successfully previous synthetic protocols and catalytic performance of catalytic materials based on Fe-Zn-Cu-K oxide precursors synthesized using precipitation methods, drying using surface-active agents, and activated in synthesis gas within Fischer-Tropsch synthesis tubular reactors.

  6. I 95 Landfill Phase II Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    I 95 Landfill Phase II Biomass Facility Jump to: navigation, search Name I 95 Landfill Phase II Biomass Facility Facility I 95 Landfill Phase II Sector Biomass Facility Type...

  7. Milliken Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    2006 Database Retrieved from "http:en.openei.orgwindex.php?titleMillikenLandfillBiomassFacility&oldid397777" Feedback Contact needs updating Image needs updating...

  8. Acme Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    NEEDS 2006 Database Retrieved from "http:en.openei.orgwindex.php?titleAcmeLandfillBiomassFacility&oldid397115" Feedback Contact needs updating Image needs updating...

  9. Colton Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    2006 Database Retrieved from "http:en.openei.orgwindex.php?titleColtonLandfillBiomassFacility&oldid397336" Feedback Contact needs updating Image needs updating...

  10. Girvin Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    2006 Database Retrieved from "http:en.openei.orgwindex.php?titleGirvinLandfillBiomassFacility&oldid397500" Feedback Contact needs updating Image needs updating...

  11. Microsoft Word - Final TTR Landfill Extension EA--December 2006...

    National Nuclear Security Administration (NNSA)

    ... Once the landfill reaches capacity, sources of air pollution associated with the landfill would no longer be present. Waste transport vehicles would cause minor increases in car- ...

  12. Briefing: DOE EM Landfill Workshop & Path Forward | Department...

    Broader source: Energy.gov (indexed) [DOE]

    and Recommendations of EM Landfill Workshop Briefing: DOE EM ITR Landfill Assessment Project Lessons Learned Environmental Management Waste Management Facility (EMWMF) at Oak Ridge

  13. US EPA Landfill Methane Outreach Program | Open Energy Information

    Open Energy Info (EERE)

    EPA Landfill Methane Outreach Program Jump to: navigation, search Name US EPA Landfill Methane Outreach Program AgencyCompany Organization United States Environmental Protection...

  14. CHP and Bioenergy for Landfills and Wastewater Treatment Plants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Landfills and Wastewater Treatment Plants: Market Opportunities CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market Opportunities This document explores ...

  15. CHP and Bioenergy Systems for Landfills and Wastewater Treatment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems for Landfills and Wastewater Treatment Plants CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants There are important issues to consider when selecting ...

  16. DOE - Office of Legacy Management -- West Lake Landfill - MO...

    Office of Legacy Management (LM)

    Lake Landfill - MO 05 FUSRAP Considered Sites Site: West Lake Landfill (MO.05) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition:...

  17. Improved energy recovery from municipal solid wastes in sanitary landfills by two-phase digestion of biomass

    SciTech Connect (OSTI)

    Onu, Chukwu.

    1990-01-01

    The concept under investigaton was the separation of the acidogenic and the methanogenic phases of anaerobic fermentation, converting the sanitary landfill into an acid reactor and using a separate upflow fixed-film anaerobic reactor for methanogenesis. Acidic leachate from the landfill simulator was used as the influent substrate to the anaerobic reactor. The goal of the study was to improve both methane yield and concentration through nutrient addition and two-phase digestion of MSW. Sewage sludge was utilized to provide moisture, buffering capacity, nutrients, and an adequate microbial population. Single-phase systems with other enhancement techniques were also compared to the two-phase with sludge addition. Data from this study indicated that gas produced in the anaerobic reactor had methane concentration as high as 80 Mole % at the fixed-bed reactor (FBR) hydraulic retention time (HRT) of 7 days. The system reached a cumulative methane production rate of 78.6 {ell}/kg dry waste at an estimated cumulative production rate of approximately 270 {ell}/kg/yr. This performance was better than that reported in the literature for a similar type of feed. This study has also indicated that sewage sludge addition appears to be a successful enhancement technique for methane gas production from municipal solid waste. The addition of mineral nutrients and buffer solutions appears to have influenced the development of a dominant population of methanogenic bacteria in the FBR as indicated by the COD removal efficiency of 90% and 100% conversion of all influent organic acids. In terms of the overall system performance, the two-phase system was superior to the one-phase technique currently in use for methane generation.

  18. Solar Thermal Conversion of Biomass to Synthesis Gas: Cooperative Research and Development Final Report, CRADA Number CRD-09-00335

    SciTech Connect (OSTI)

    Netter, J.

    2013-08-01

    The CRADA is established to facilitate the development of solar thermal technology to efficiently and economically convert biomass into useful products (synthesis gas and derivatives) that can replace fossil fuels. NREL's High Flux Solar Furnace will be utilized to validate system modeling, evaluate candidate reactor materials, conduct on-sun testing of the process, and assist in the development of solar process control system. This work is part of a DOE-USDA 3-year, $1M grant.

  19. The environmental comparison of landfilling vs. incineration of MSW accounting for waste diversion

    SciTech Connect (OSTI)

    Assamoi, Bernadette; Lawryshyn, Yuri

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Residential waste diversion initiatives are more successful with organic waste. Black-Right-Pointing-Pointer Using a incineration to manage part of the waste is better environmentally. Black-Right-Pointing-Pointer Incineration leads to more power plant emission offsets. Black-Right-Pointing-Pointer Landfilling all of the waste would be preferred financially. - Abstract: This study evaluates the environmental performance and discounted costs of the incineration and landfilling of municipal solid waste that is ready for the final disposal while accounting for existing waste diversion initiatives, using the life cycle assessment (LCA) methodology. Parameters such as changing waste generation quantities, diversion rates and waste composition were also considered. Two scenarios were assessed in this study on how to treat the waste that remains after diversion. The first scenario is the status quo, where the entire residual waste was landfilled whereas in the second scenario approximately 50% of the residual waste was incinerated while the remainder is landfilled. Electricity was produced in each scenario. Data from the City of Toronto was used to undertake this study. Results showed that the waste diversion initiatives were more effective in reducing the organic portion of the waste, in turn, reducing the net electricity production of the landfill while increasing the net electricity production of the incinerator. Therefore, the scenario that incorporated incineration performed better environmentally and contributed overall to a significant reduction in greenhouse gas emissions because of the displacement of power plant emissions; however, at a noticeably higher cost. Although landfilling proves to be the better financial option, it is for the shorter term. The landfill option would require the need of a replacement landfill much sooner. The financial and environmental effects of this expenditure have yet to be considered.

  20. Knowledge based ranking algorithm for comparative assessment of post-closure care needs of closed landfills

    SciTech Connect (OSTI)

    Sizirici, Banu; Tansel, Berrin; Kumar, Vivek

    2011-06-15

    Post-closure care (PCC) activities at landfills include cap maintenance; water quality monitoring; maintenance and monitoring of the gas collection/control system, leachate collection system, groundwater monitoring wells, and surface water management system; and general site maintenance. The objective of this study was to develop an integrated data and knowledge based decision making tool for preliminary estimation of PCC needs at closed landfills. To develop the decision making tool, 11 categories of parameters were identified as critical areas which could affect future PCC needs. Each category was further analyzed by detailed questions which could be answered with limited data and knowledge about the site, its history, location, and site specific characteristics. Depending on the existing knowledge base, a score was assigned to each question (on a scale 1-10, as 1 being the best and 10 being the worst). Each category was also assigned a weight based on its relative importance on the site conditions and PCC needs. The overall landfill score was obtained from the total weighted sum attained. Based on the overall score, landfill conditions could be categorized as critical, acceptable, or good. Critical condition indicates that the landfill may be a threat to the human health and the environment and necessary steps should be taken. Acceptable condition indicates that the landfill is currently stable and the monitoring should be continued. Good condition indicates that the landfill is stable and the monitoring activities can be reduced in the future. The knowledge base algorithm was applied to two case study landfills for preliminary assessment of PCC performance.

  1. Data summary of municipal solid waste management alternatives. Volume 8, Appendix F, Landfills

    SciTech Connect (OSTI)

    1992-10-01

    While the preceding appendices have focused on the thermochemical approaches to managing municipal solid waste (MSW), this appendix and those that follow on composting and anaerobic digestion address more of the bioconversion process technologies. Landfilling is the historical baseline MSW management option central to every community`s solid waste management plan. It generally encompasses shredfills, balefills, landfill gas recovery, and landfill mining. While landfilling is virtually universal in use, it continues to undergo intense scrutiny by the public and regulators alike. Most recently, the US Environmental Protection Agency (EPA) issued its final rule on criteria for designing, operating, monitoring, and closing municipal solid waste landfills. While the Federal government has established nationwide standards and will assist the States in planning and developing their own practices, the States and local governments will carry out the actual planning and direct implementation. The States will also be authorized to devise programs to deal with their specific conditions and needs. While the main body of this appendix and corresponding research was originally prepared in July of 1991, references to the new RCRA Subtitle D, Part 258 EPA regulations have been included in this resubmission (908). By virtue of timing, this appendix is, necessarily, a ``transition`` document, combining basic landfill design and operation information as well as reference to new regulatory requirements. Given the speed with which landfill practices are and will be changing, the reader is encouraged to refer to Part 258 for additional details. As States set additional requirements and schedules and owners and operators of MSW landfills seek to comply, additional guidance and technical information, including case studies, will likely become available in the literature.

  2. Data Summary of Municipal Solid Waste Management Alternatives. Volume VIII: Appendix F - Landfills

    SciTech Connect (OSTI)

    1992-10-01

    While the preceding appendices have focused on the thermochemical approaches to managing municipal solid waste (MSW), this appendix and those that follow on composting and anaerobic digestion address more of the bioconversion process technologies. Landfilling is the historical baseline MSW management option central to every community's solid waste management plan. It generally encompasses shredfills, balefills, landfill gas recovery, and landfill mining. While landfilling is virtually universal in use, it continues to undergo intense scrutiny by the public and regulators alike. Most recently, the US Environmental Protection Agency (EPA) issued its final rule on criteria for designing, operating, monitoring, and closing municipal solid waste landfills. While the Federal government has established nationwide standards and will assist the States in planning and developing their own practices, the States and local governments will carry out the actual planning and direct implementation. The States will also be authorized to devise programs to deal with their specific conditions and needs. While the main body of this appendix and corresponding research was originally prepared in July of 1991, references to the new RCRA Subtitle D, Part 258 EPA regulations have been included in this resubmission (908). By virtue of timing, this appendix is, necessarily, a transition'' document, combining basic landfill design and operation information as well as reference to new regulatory requirements. Given the speed with which landfill practices are and will be changing, the reader is encouraged to refer to Part 258 for additional details. As States set additional requirements and schedules and owners and operators of MSW landfills seek to comply, additional guidance and technical information, including case studies, will likely become available in the literature.

  3. GTZ-Greenhouse Gas Calculator for Waste Management | Open Energy...

    Open Energy Info (EERE)

    a great part of the national greenhouse gas production, because landfills produce methane which has a particularly strong effect on climate change. Therefore, it is essential...

  4. IL conversion technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conversion technology - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  5. Lantana landfill: A history of environmental management 1965--96

    SciTech Connect (OSTI)

    Statom, R.A.

    1997-08-01

    The Lantana Sanitary Landfill (LSL) is located in central Palm Beach County, Florida. The history of this landfill is a case study of the changes in environmental law, demography, solid waste management, hydrogeology, and public opinion in south Florida in the last 30 years. In 1983 Palm Beach County transferred ownership of the LSL to the Palm Beach County Solid Waste Authority (SWA). Environmental regulation enacted by Florida in the mid 1980`s resulted in negotiations to close the LSL. Closure was completed in 1988 utilizing a synthetic top liner, a landfill gas extraction/flare system, and a stormwater management system. In 1990 a groundwater mitigation system was installed to remediate the eastern plume. Closure of the LSL, extension of municipal water to local residents, and extensive public education by the SWA all served to answer most of the complaints of the local residents. In 1996 the LSL fell under a new series of air regulations and was required to apply for a Title V permit.

  6. Direct use of natural gas (methane) for conversion of carbonaceous raw materials to fuels and chemical feedstocks

    SciTech Connect (OSTI)

    Steinberg, M.

    1985-04-01

    It appears that natural gas is almost as abundant as petroleum, if not more so, as a natural resource in many parts of the world. Because of its rich hydrogen content, it is probably the lowest cost source of hydrogen wherever it is available. The most abundant fossil energy resource in the world appears to be coal, and the most abundant renewable resource appears to be biomass (trees and plants), both of which contain a deficiency of hydrogen. It is proposed to use natural gas in conjunction with coal and biomass to produce the preferred liquid fuel simulating petroleum products. Processes are described which include methanolysis that is the direct use of methane for gasification and liquefaction of coal and biomass, and for desulfurization of coal derived liquid and gases. The thermal decomposition of methane is described for hydrogen and carbon particulate production. A cyclical process is described for producing a clean particulate carbon from coal for use in a carbon-water-fuel-mix as a substitute diesel fuel or premium-grade boiler fuel. The hydrogen from methane can be used for flash hydropyrolysis or can be used to produce ammonia fertilizer. 7 refs., 3 figs., 5 tabs.

  7. Design, Synthesis, and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

    SciTech Connect (OSTI)

    Akio Ishikawa; Manuel Ojeda; Nan Yao; Enrique Iglesia

    2006-03-31

    This project extends previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have shown unprecedented Fischer-Tropsch synthesis rate, selectivity for feedstocks consisting of synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic results previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During the third and fourth reporting periods, we improved the catalysts preparation method, which led to Fe-based FT catalysts with the highest FTS reaction rates and selectivities so far reported, a finding that allowed their operation at lower temperatures and pressures with high selectivity to desired products (C{sub 5+}, olefins). During this fifth reporting period, we have studied the effects of different promoters on catalytic performance, specifically how their sequence of addition dramatically influences the performance of these materials in the Fischer-Tropsch synthesis. The resulting procedures have been optimized to improve further upon the already unprecedented rates and C{sub 5+} selectivities of the Fe-based catalysts that we have developed as part of this project. During this fifth reporting period, we have also continued our studies of optimal activation procedures, involving reduction and carburization of oxide precursors during the early stages of contact with synthesis gas. We have completed the analysis of the evolution of oxide, carbide, and metal phases of the active iron components during initial contact with synthesis gas using advanced synchrotron techniques based on X-ray absorption spectroscopy. We have confirmed that the Cu or Ru compensates for inhibitory effects of Zn, a surface area promoter. The kinetic behavior of these materials, specifically the effects of H{sub 2}, CO, and CO{sub 2} on the rates and selectivities of Fischer-Tropsch synthesis reactions has led to a new proposal for the nature of rate-determining steps on Fe and Co Fischer-Tropsch catalysts, and more specifically to the roles of hydrogen-assisted and alkali-assisted dissociation of CO in determining rates and CO{sub 2} selectivities. Finally, we have started an exploratory study of the use of colloidal precipitation methods for the synthesis of small Fe and Co clusters using recently developed methods. During this period, we have had to restrict manpower assigned to this project because some irregularities in reporting and communications have led to the interruption of funding during this period. This has led to less than optimal productivity and to significant disruptions of the technical work. These issues have also led to significant underspending of project funds during this reporting period and to our consequent request for a no-cost extension of one year, which we understand has been granted.

  8. Liquefied Natural Gas for Trucks and Buses

    SciTech Connect (OSTI)

    James Wegrzyn; Michael Gurevich

    2000-06-19

    Liquefied natural gas (LNG) is being developed as a heavy vehicle fuel. The reason for developing LNG is to reduce our dependency on imported oil by eliminating technical and costs barriers associated with its usage. The U.S. Department of Energy (DOE) has a program, currently in its third year, to develop and advance cost-effective technologies for operating and refueling natural gas-fueled heavy vehicles (Class 7-8 trucks). The objectives of the DOE Natural Gas Vehicle Systems Program are to achieve market penetration by reducing vehicle conversion and fuel costs, to increase consumer acceptance by improving the reliability and efficiency, and to improve air quality by reducing tailpipe emissions. One way to reduce fuel costs is to develop new supplies of cheap natural gas. Significant progress is being made towards developing more energy-efficient, low-cost, small-scale natural gas liquefiers for exploiting alternative sources of natural gas such as from landfill and remote gas sites. In particular, the DOE program provides funds for research and development in the areas of; natural gas clean up, LNG production, advanced vehicle onboard storage tanks, improved fuel delivery systems and LNG market strategies. In general, the program seeks to integrate the individual components being developed into complete systems, and then demonstrate the technology to establish technical and economic feasibility. The paper also reviews the importance of cryogenics in designing LNG fuel delivery systems.

  9. Design, Synthesis, and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

    SciTech Connect (OSTI)

    Akio Ishikawa; Manuel Ojeda; Enrique Iglesia

    2005-09-30

    This project extends previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have shown unprecedented Fischer-Tropsch synthesis rate, selectivity for feedstocks consisting of synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic results previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During the third reporting period, we improved the catalysts preparation method, which led to Fe-based FT catalysts with the highest FTS reaction rates and selectivities so far reported, a finding that allowed their operation at lower temperatures and pressures with high selectivity to desired products (C{sub 5+}, olefins). During this fourth reporting period, we have determined the effects of different promoters on catalytic performance. More specifically, we have found that the sequence in which promoters are introduced has a marked positive impact on rates and selectivities. Cu or Ru chemical promoters should be impregnated before K to achieve higher Fischer-Tropsch synthesis rates. The catalyst prepared in this way was evaluated for 240 h, showing a high catalytic activity and stability after an initial period of time necessary for the formation of the active phases. Concurrently, we are studying optimal activation procedures, which involve the reduction and carburization of oxide precursors during the early stages of contact with synthesis gas. Activation at low temperatures (523 K), made possible by optimal introduction of Cu or Ru, leads to lower catalyst surface area than higher activation temperatures, but to higher reaction rates, because such low temperatures avoid concurrent deactivation during the reduction-carburization processes. In this reporting period, we have measured the evolution of oxide, carbide, and metal phases of the active iron components using advanced synchrotron techniques based on X-ray absorption spectroscopy. These studies have revealed that Zn inhibits the isothermal reduction and carburization of iron oxide precursors. The concurrent presence of Cu or Ru compensates for these inhibitory effects and lead to the formation of active carbide phases at the low temperatures required to avoid deactivation via carbon deposition or sintering. Finally, we have also examined the kinetic behavior of these materials, specifically the effects of H{sub 2}, CO, and CO{sub 2} on the rates and selectivities of Fischer-Tropsch synthesis reactions. This has led to a rigorous rate expressions that allows the incorporation of these novel materials into larger scale reactors and to predictions of performance based on the coupling of hydrodynamic and kinetic effects ubiquitous in such reactors.

  10. DESIGN, SYNTHESIS, AND MECHANISTIC EVALUATION OF IRON-BASED CATALYSIS FOR SYNTHESIS GAS CONVERSION TO FUELS AND CHEMICALS

    SciTech Connect (OSTI)

    Akio Ishikawa; Manuel Ojeda; Enrique Iglesia

    2005-03-31

    This project explores the extension of previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have previously shown unprecedented Fischer-Tropsch synthesis rate, selectivity with synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic performance previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During this third reporting period, we have prepared a large number of Fe-based catalyst compositions using precipitation and impregnations methods with both supercritical and subcritical drying and with the systematic use of surface active agents to prevent pore collapse during drying steps required in synthetic protocols. These samples were characterized during this period using X-ray diffraction, surface area, and temperature-programmed reduction measurements. These studies have shown that these synthesis methods lead to even higher surface areas than in our previous studies and confirm the crystalline structures of these materials and their reactivity in both oxide-carbide interconversions and in Fischer-Tropsch synthesis catalysis. Fischer-Tropsch synthesis reaction rates and selectivities with low H{sub 2}/CO ratio feeds (H{sub 2}/CO = 1) were the highest reported in the literature at the low-temperature and relatively low pressure in our measurements. Current studies are exploring the optimization of the sequence of impregnation of Cu, K, and Ru promoters, of the activation and reaction conditions, and of the co-addition of light hydrocarbons to increase diffusion rates of primary olefin products so as to increase the selectivity to unsaturated products. Finally, we are also addressing the detailed kinetic response of optimized catalysts to reaction conditions (temperature, partial pressures of H{sub 2}, CO, H{sub 2}O, CO{sub 2}, olefins) in an effort to further increase rates and olefin and C{sub 5+} selectivities.

  11. Design, Synthesis, and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

    SciTech Connect (OSTI)

    Enrique Iglesia

    2004-09-30

    This project explores the extension of previously discovered Fe-based catalysts with unprecedented Fischer-Tropsch synthesis rate, selectivity, and ability to convert hydrogen-poor synthesis gas streams typical of those produced from coal and biomass sources. Contract negotiations were completed on December 9, 2004. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic performance previously reported. During this second reporting period, we have prepared and tested several Fe-based compositions for Fischer-Tropsch synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. These studies established modest improvements in rates and selectivities with light hydrocarbon recycle without any observed deleterious effects, opening up the opportunities for using of recycle strategies to control temperature profiles in fixed-bed Fe-based Fischer-Tropsch synthesis reactors without any detectable kinetic detriment. In a parallel study, we examined similar effects of recycle for cobalt-based catalysts; marked selectivity improvements were observed as a result of the removal of significant transport restrictions on these catalysts. Finally, we have re-examined some previously unanalyzed data dealing with the mechanism of the Fischer-Tropsch synthesis, specifically kinetic isotope effects on the rate and selectivity of chain growth reactions on Fe-based catalysts.

  12. Design, Synthesis and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

    SciTech Connect (OSTI)

    Akio Ishikawa; Manuel Ojeda; Nan Yao; Enrique Iglesia

    2007-03-31

    This project extends previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have shown unprecedented Fischer-Tropsch synthesis rates and selectivities for synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic results previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch Synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During the third and fourth reporting periods, we improved the catalysts preparation method, which led to Fe-based materials with the highest FTS reaction rates and selectivities so far reported, a finding that allowed their operation at lower temperatures and pressures with high selectivity to desired products (C{sub 5+}, olefins). During the fifth and sixth reporting period, we studied the effects of different promoters on catalytic performance, specifically how their sequence of addition dramatically influenced the performance of these materials in the Fischer-Tropsch synthesis. We also continued our studies of the kinetic behavior of these materials during the sixth reporting period. Specifically, the effects of H{sub 2}, CO, and CO{sub 2} on the rates and selectivities of Fischer-Tropsch Synthesis reactions led us to propose a new sequence of elementary steps on Fe and Co Fischer-Tropsch catalysts. Finally, we also started a study of the use of colloidal precipitation methods for the synthesis small Co clusters using recently developed methods to explore possible further improvements in FTS rates and selectivities. We found that colloidal synthesis makes possible the preparation of small cobalt particles, although large amount of cobalt silicate species, which are difficult to reduce, were formed. During this seventh reporting period, we have explored several methods to modify the silanol groups on SiO{sub 2} by using either a homogeneous deposition-precipitation method or surface titration of Si-OH on SiO{sub 2} with zirconium (IV) ethoxide to prevent the formation of unreducible and unreactive CoO{sub x} species during synthesis and FTS catalysis. We have synthesized monometallic Co/ZrO{sub 2}/SiO{sub 2} catalysts with different Co loadings (11-20 wt%) by incipient wetness impregnation methods and characterized the prepared Co supported catalysts by H{sub 2} temperature-programmed reduction (H{sub 2}-TPR) and H{sub 2}-chemisorption. We have measured the catalytic performance in FTS reactions and shown that although the hydroxyl groups on the SiO{sub 2} surface are difficult to be fully titrated by ZrO{sub 2}, modification of ZrO{sub 2} on SiO{sub 2} surface can improve the Co clusters dispersion and lead to a larger number of exposed Co surface atoms after reduction and during FTS reactions. During this seventh reporting period, we have also advanced our development of the reaction mechanism proposed in the previous reporting period. Specifically, we have shown that our novel proposal for the pathways involved in CO activation on Fe and Co catalysts is consistent with state-of-the-art theoretical calculations carried out in collaboration with Prof. Manos Mavrikakis (University of Wisconsin-Madison). Finally, we have also worked on the preparation of several manuscripts describing our findings about the preparation, activation and mechanism of the FTS with Fe-based catalysts and we have started redacting the final report for this project.

  13. Design, Synthesis, and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

    SciTech Connect (OSTI)

    Akio; Ishikawa; Manuel Ojeda; Nan Yao; Enrique Iglesia

    2006-09-30

    This project extends previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have shown unprecedented Fischer-Tropsch synthesis rates and selectivities for feedstocks consisting of synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic results previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch Synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During the third and fourth reporting periods, we improved the catalysts preparation method, which led to Fe-based FT catalysts with the highest FTS reaction rates and selectivities so far reported, a finding that allowed their operation at lower temperatures and pressures with high selectivity to desired products (C{sub 5+}, olefins). During the fifth reporting period, we studied the effects of different promoters on catalytic performance, specifically how their sequence of addition dramatically influenced the performance of these materials in the Fischer-Tropsch synthesis. We also continued our studies of the kinetic behavior of these materials. Specifically, the effects of H{sub 2}, CO, and CO{sub 2} on the rates and selectivities of Fischer-Tropsch Synthesis reactions led us to propose a new sequence of elementary steps on Fe and Co Fischer-Tropsch catalysts. More specifically, we were focused on the roles of hydrogen-assisted and alkali-assisted dissociation of CO in determining rates and CO{sub 2} selectivities. During this sixth reporting period, we have studied the validity of the mechanism that we propose by analyzing the H{sub 2}/D{sub 2} kinetic isotope effect (r{sub H}/r{sub D}) over a conventional iron-based Fischer-Tropsch catalyst Fe-Zn-K-Cu. We have observed experimentally that the use of D{sub 2} instead of H{sub 2} leads to higher hydrocarbons formation rates (inverse kinetic isotopic effect). On the contrary, primary carbon dioxide formation is not influenced. These experimental observations can be explained by the two CO activation pathways we propose. During this reporting period, the experimental kinetic study has been also complemented with periodic, self-consistent, DFT-GGA investigations in a parallel collaboration with the group of Manos Mavrikakis at the University of Wisconsin-Madison. These DFT calculations suggest minimal energy paths for proposed elementary steps on Fe(110) and Co(0001) surfaces. These calculations support our novel conclusions about the preferential dissociation of CO dissociation via H-assisted pathways on Fe-based catalysts. Unassisted CO dissociation also occurs and lead to the formation of CO{sub 2} as a primary oxygen scavenging mechanism after CO dissociation on Fe-based catalysts. Simulations and our experimental data show also that unassisted CO dissociation route is much less likely on Co surfaces and that hydrocarbons form exclusively via H-assisted pathways with the formation of H{sub 2}O as the sole oxygen rejection product. We have also started a study of the use of colloidal precipitation methods for the synthesis of small Fe and Co clusters using recently developed methods to explore possible further improvements in Fischer-Tropsch synthesis rates and selectivities. We have found that colloidal synthesis makes possible the preparation of small cobalt particles, although large amount of cobalt silicate species, which are difficult to reduce, are formed. The nature of the cobalt precursor and the modification of the support seem to be critical parameters in order to obtain highly dispersed and reducible Co nanoparticles.

  14. Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, ... Analysis of Technology and Policy Tradeoffs, Energy Policy, ...

  15. Waste management health risk assessment: A case study of a solid waste landfill in South Italy

    SciTech Connect (OSTI)

    Davoli, E.; Fattore, E.; Paiano, V.; Colombo, A.; Palmiotto, M.; Rossi, A.N.; Il Grande, M.; Fanelli, R.

    2010-08-15

    An integrated risk assessment study has been performed in an area within 5 km from a landfill that accepts non hazardous waste. The risk assessment was based on measured emissions and maximum chronic population exposure, for both children and adults, to contaminated air, some foods and soil. The toxic effects assessed were limited to the main known carcinogenic compounds emitted from landfills coming both from landfill gas torch combustion (e.g., dioxins, furans and polycyclic aromatic hydrocarbons, PAHs) and from diffusive emissions (vinyl chloride monomer, VCM). Risk assessment has been performed both for carcinogenic and non-carcinogenic effects. Results indicate that cancer and non-cancer effects risk (hazard index, HI) are largely below the values accepted from the main international agencies (e.g., WHO, US EPA) and national legislation ( and ).

  16. Instrumentation of dredge spoil for landfill construction

    SciTech Connect (OSTI)

    Byle, M.J.; McCullough, M.L.; Alexander, R.; Vasuki, N.C.; Langer, J.A.

    1999-07-01

    The Delaware Solid Waste Authority's Northern Solid Waste Management Center is located outside of Wilmington Delaware at Cherry Island, a former dredge disposal site. Dredge spoils, of very low permeability, range in depths up to 30 m (100 feet) which form a natural liner and the foundation for the 140 ha (350-acre) municipal solid waste landfill. The soils beneath the landfill have been extensively instrumented to measure pore pressure, settlement and deflections, using inclinometer casings, standpipe piezometers, vibrating wire piezometers, pneumatic piezometers, settlement plates, liquid settlement gages, total pressure cells and thermistors. The nature of the existing waste and anticipated settlements (up to 6 m (19 feet)) have required some unique installation details. The instrumentation data has been integral in planning the landfilling sequence to maintain perimeter slope stability and has provided key geotechnical parameters needed for operation and construction of the landfill. The performance of the instrumentation and monitoring results are discussed.

  17. Agencies plan continued DOE landfill remediation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Agencies plan continued DOE landfill remediation The U.S. Department of Energy (DOE), Idaho Department of Environmental Quality and U.S. Environmental Protection Agency have released a planning document that specifies how DOE will continue to remediate a landfill containing hazardous and transuranic waste at DOE's Idaho Site located in eastern Idaho. The Phase 1 Remedial Design/Remedial Action Work Plan for Operable Unit 7-13/14 document was issued after the September 2008 Record of Decision

  18. Photovoltaics on Landfills in Puerto Rico

    SciTech Connect (OSTI)

    Salasovich, J.; Mosey, G.

    2011-01-01

    The U.S. Environmental Protection Agency (EPA), in accordance with the RE-Powering America's Land initiative, selected the Commonwealth of Puerto Rico for a feasibility study of m0treAlables on several brownfield sites. The EPA defines a brownfield as 'a property, the expansion, redevelopment, or reuse of which may be complicated by the presence or potential presence of a hazardous substance, pollutant, or contaminant.' All of the brownfields in this study are landfill sites. Citizens of Puerto Rico, city planners, and site managers are interested in redevelopment uses for landfills in Puerto Rico, which are particularly well suited for solar photovoltaic (PV) installation. The purpose of this report is to assess the landfills with the highest potential for possible solar PV installation and estimate cost, performance, and site impacts of three different PV options: crystalline silicon (fixed-tilt), crystalline silicon (single-axis tracking), and thin film (fixed-tilt). Each option represents a standalone system that can be sized to use an entire available site area. In addition, the report outlines financing options that could assist in the implementation of a system. The feasibility of PV systems installed on landfills is highly impacted by the available area for an array, solar resource, operating status, landfill cap status, distance to transmission lines, and distance to major roads. All of the landfills in Puerto Rico were screened according to these criteria in order to determine the sites with the greatest potential. Eight landfills were chosen for site visits based on the screening criteria and location. Because of time constraints and the fact that Puerto Rico is a relatively large island, the eight landfills for this visit were all located in the eastern half of the island. The findings from this report can be applied to landfills in the western half of the island. The economics of a potential PV system on landfills in Puerto Rico depend greatly on the cost of electricity. Currently, PREPA has an average electric rate of $0.119/kWh. Based on past electric rate increases in Puerto Rico and other islands in the Caribbean, this rate could increase to $0.15/kWh or higher in a relatively short amount of time. In the coming years, increasing electrical rates and increased necessity for clean power will continue to improve the feasibility of implementing solar PV systems at these sites.

  19. Thermal conversion of municipal solid waste via hydrothermal carbonization: Comparison of carbonization products to products from current waste management techniques

    SciTech Connect (OSTI)

    Lu Xiaowei; Jordan, Beth; Berge, Nicole D.

    2012-07-15

    Highlights: Black-Right-Pointing-Pointer Hydrothermal carbonization (HTC) is a novel thermal conversion process. Black-Right-Pointing-Pointer HTC converts wastes into value-added resources. Black-Right-Pointing-Pointer Carbonization integrates majority of carbon into solid-phase. Black-Right-Pointing-Pointer Carbonization results in a hydrochar with high energy density. Black-Right-Pointing-Pointer Using hydrochar as an energy source may be beneficial. - Abstract: Hydrothermal carbonization (HTC) is a novel thermal conversion process that may be a viable means for managing solid waste streams while minimizing greenhouse gas production and producing residual material with intrinsic value. HTC is a wet, relatively low temperature (180-350 Degree-Sign C) thermal conversion process that has been shown to convert biomass to a carbonaceous residue referred to as hydrochar. Results from batch experiments indicate HTC of representative waste materials is feasible, and results in the majority of carbon (45-75% of the initially present carbon) remaining within the hydrochar. Gas production during the batch experiments suggests that longer reaction periods may be desirable to maximize the production of energy-favorable products. If using the hydrochar for applications in which the carbon will remain stored, results suggest that the gaseous products from HTC result in fewer g CO{sub 2}-equivalent emissions than the gases associated with landfilling, composting, and incineration. When considering the use of hydrochar as a solid fuel, more energy can be derived from the hydrochar than from the gases resulting from waste degradation during landfilling and anaerobic digestion, and from incineration of food waste. Carbon emissions resulting from the use of the hydrochar as a fuel source are smaller than those associated with incineration, suggesting HTC may serve as an environmentally beneficial alternative to incineration. The type and extent of environmental benefits derived from HTC will be dependent on hydrochar use/the purpose for HTC (e.g., energy generation or carbon storage).

  20. Geophysical exploration and hydrologic impact of the closed Gracelawn landfill in Auburn, ME

    SciTech Connect (OSTI)

    Wisniewski, D. . Geology Dept.)

    1993-03-01

    Several geophysical methods were used over portions of the Gracelawn landfill, in Auburn, Maine to determine the surface boundaries and subsurface structure of this closed landfill, and to determine the landfill's effects on groundwater quality. The landfill was originally a sand and gravel pit excavated in the 1950's and early 1960's, and was used as a landfill from 1964--1977. The site is unlined, has a clay cap, and has been graded and developed as a baseball park. Two seismic refraction lines were performed to obtain a minimum depth to bedrock of 80 m. Seismic velocities of methane gas-saturated trash ranged from 250 to 340 m/s, and sand velocities are approximately 800 m/s. Two electrical resistivity Wenner surveys over the trash yielded the depth to saturated material and thickness of the trash layers. Resistivity values for dry refuse ranged from 1,000-2,000 [Omega]*m. A third electrical resistivity survey yielded the thickness of unsaturated and saturated sands bordering the landfill. Dry sands were found to have a resistivity of 1,000 [Omega]*m, and saturated sands a resistivity of 500 [Omega]*m. Gravity and magnetic survey grids across the site revealed anomalies which were mapped to illustrate the irregular morphology of the buried trash as well as its surface boundaries. Residual magnetic anomalies are on the order of 2,000 nT. Residual gravity anomalies are up to 5 mGal. Groundwater elevations determined by the geophysical survey, combined with a survey of existing water monitoring well logs, indicate that the groundwater flow in the sand and gravel aquifer is to the southeast, away from the public water supply, Lake Auburn, which lies to the north of the site. However, correlations between the bedrock fracture analysis and the geophysical survey illustrate that there is potential for contamination of Lake Auburn via the bedrock aquifer.

  1. Assessment of the methane oxidation capacity of compacted soils intended for use as landfill cover materials

    SciTech Connect (OSTI)

    Rachor, Ingke; Gebert, Julia; Groengroeft, Alexander; Pfeiffer, Eva-Maria

    2011-05-15

    The microbial oxidation of methane in engineered cover soils is considered a potent option for the mitigation of emissions from old landfills or sites containing wastes of low methane generation rates. A laboratory column study was conducted in order to derive design criteria that enable construction of an effective methane oxidising cover from the range of soils that are available to the landfill operator. Therefore, the methane oxidation capacity of different soils was assessed under simulated landfill conditions. Five sandy potential landfill top cover materials with varying contents of silt and clay were investigated with respect to methane oxidation and corresponding soil gas composition over a period of four months. The soils were compacted to 95% of their specific proctor density, resulting in bulk densities of 1.4-1.7 g cm{sup -3}, reflecting considerably unfavourable conditions for methane oxidation due to reduced air-filled porosity. The soil water content was adjusted to field capacity, resulting in water contents ranging from 16.2 to 48.5 vol.%. The investigated inlet fluxes ranged from 25 to about 100 g CH{sub 4} m{sup -2} d{sup -1}, covering the methane load proposed to allow for complete oxidation in landfill covers under Western European climate conditions and hence being suggested as a criterion for release from aftercare. The vertical distribution of gas concentrations, methane flux balances as well as stable carbon isotope studies allowed for clear process identifications. Higher inlet fluxes led to a reduction of the aerated zone, an increase in the absolute methane oxidation rate and a decline of the relative proportion of oxidized methane. For each material, a specific maximum oxidation rate was determined, which varied between 20 and 95 g CH{sub 4} m{sup -2} d{sup -1} and which was positively correlated to the air-filled porosity of the soil. Methane oxidation efficiencies and gas profile data imply a strong link between oxidation capacity and diffusive ingress of atmospheric air. For one material with elevated levels of fine particles and high organic matter content, methane production impeded the quantification of methane oxidation potentials. Regarding the design of landfill cover layers it was concluded that the magnitude of the expected methane load, the texture and expected compaction of the cover material are key variables that need to be known. Based on these, a column study can serve as an appropriate testing system to determine the methane oxidation capacity of a soil intended as landfill cover material.

  2. Landfill Cover Revegetation at the Rocky Flats Environmental Technology

    Energy Savers [EERE]

    Site | Department of Energy Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site PDF icon Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site More Documents & Publications Revegetation of the Rocky Flats Site Smooth Brome Monitoring at Rocky Flats-2005 Results EIS-0285-SA-134: Supplement

  3. CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities | Department of Energy for Landfills and Wastewater Treatment Plants: Market Opportunities CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market Opportunities This document explores opportunities for alternative CHP fuels. PDF icon CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market Opportunities (November 2007) More Documents & Publications CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants Barriers to CHP with

  4. DOE - Office of Legacy Management -- Pfohl Brothers Landfill...

    Office of Legacy Management (LM)

    Landfill (NY.66 ) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials...

  5. Briefing: DOE EM ITR Landfill Assessment Project Lessons Learned |

    Energy Savers [EERE]

    Department of Energy ITR Landfill Assessment Project Lessons Learned Briefing: DOE EM ITR Landfill Assessment Project Lessons Learned By: Craig H. Benson, PhD, PE Where: EM SSAB Teleconference: 1 Briefing provides lessons learned from the DOE EM ITR Landfill Assessment Project. PDF icon EM SSAB ITR Landfill Assessment Project Lessons Learned Presentation - July 2009 More Documents & Publications Disposal Practices at the Nevada Test Site 2008 Proposed On-Site Disposal Facility (OSDF) at

  6. US EPA record of decision review for landfills: Sanitary landfill (740-G), Savannah River Site

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    This report presents the results of a review of the US Environmental Protection Agency (EPA) Record of Decision System (RODS) database search conducted to identify Superfund landfill sites where a Record of Decision (ROD) has been prepared by EPA, the States or the US Army Corps of Engineers describing the selected remedy at the site. ROD abstracts from the database were reviewed to identify site information including site type, contaminants of concern, components of the selected remedy, and cleanup goals. Only RODs from landfill sites were evaluated so that the results of the analysis can be used to support the remedy selection process for the Sanitary Landfill at the Savannah River Site (SRS).

  7. Landfill stabilization focus area: Technology summary

    SciTech Connect (OSTI)

    1995-06-01

    Landfills within the DOE Complex as of 1990 are estimated to contain 3 million cubic meters of buried waste. The DOE facilities where the waste is predominantly located are at Hanford, the Savannah River Site (SRS), the Idaho National Engineering Laboratory (INEL), the Los Alamos National Laboratory (LANL), the Oak Ridge Reservation (ORR), the Nevada Test Site (NTS), and the Rocky Flats Plant (RFP). Landfills include buried waste, whether on pads or in trenches, sumps, ponds, pits, cribs, heaps and piles, auger holes, caissons, and sanitary landfills. Approximately half of all DOE buried waste was disposed of before 1970. Disposal regulations at that time permitted the commingling of various types of waste (i.e., transuranic, low-level radioactive, hazardous). As a result, much of the buried waste throughout the DOE Complex is presently believed to be contaminated with both hazardous and radioactive materials. DOE buried waste typically includes transuranic-contaminated radioactive waste (TRU), low-level radioactive waste (LLW), hazardous waste per 40 CFR 26 1, greater-than-class-C waste per CFR 61 55 (GTCC), mixed TRU waste, and mixed LLW. The mission of the Landfill Stabilization Focus Area is to develop, demonstrate, and deliver safer,more cost-effective and efficient technologies which satisfy DOE site needs for the remediation and management of landfills. The LSFA is structured into five technology areas to meet the landfill remediation and management needs across the DOE complex. These technology areas are: assessment, retrieval, treatment, containment, and stabilization. Technical tasks in each of these areas are reviewed.

  8. Advanced Conversion Roadmap Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Leslie Pezzullo Office of the Biomass Program U.S. Department of Energy Conversion Technologies for Advanced Biofuels - Biomass Program Introduction Report-Out Webinar February 9, 2012 Energy Efficiency & Renewable Energy eere.energy.gov 2 3 2 1 The need to reduce dependence on foreign oil and lower greenhouse gas (GHG) emissions has renewed the urgency for developing sustainable biofuels, bioproducts, and biopower. The transportation sector accounts for about two- thirds of U.S. oil

  9. Thermochemical Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering ...

  10. Full Scale Bioreactor Landfill for Carbon Sequestration and Greenhouse Emission Control

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Kathy Sananikone; Don Augenstein

    2005-03-30

    The Yolo County Department of Planning and Public Works constructed a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective was to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entailed the construction of a 12-acre module that contained a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells were highly instrumented to monitor bioreactor performance. Liquid addition commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell and biofilter has been completed. The current project status and preliminary monitoring results are summarized in this report.

  11. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-08-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Liquid addition has commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell is nearly complete with only the biofilter remaining and is scheduled to be complete by the end of August 2003. The current project status and preliminary monitoring results are summarized in this report.

  12. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-05-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Construction is complete on the 3.5-acre anaerobic cell and liquid addition has commenced. Construction of the 2.5-acre aerobic cell is nearly complete with only the biofilter remaining and construction of the west-side 6-acre anaerobic cell is nearly complete with only the liquid addition system remaining. The current project status and preliminary monitoring results are summarized in this report.

  13. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-12-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Liquid addition has commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell and biofilter has been completed. The remaining task to be completed is to test the biofilter prior to operation, which is currently anticipated to begin in January 2004. The current project status and preliminary monitoring results are summarized in this report.

  14. Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

    SciTech Connect (OSTI)

    1982-01-01

    This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

  15. Request for Qualifications for Sacramento Landfill

    Office of Energy Efficiency and Renewable Energy (EERE)

    This Request for Qualifications (RFQ) solicits experienced companies to design, permit, finance, build, and operate a solar photovoltaic farm (SPV Farm) on the City of Sacramento’s 28th Street Landfill. Respondents to this RFQ must demonstrate experience and capacity to design, permit, finance, build, and operate a SPV Farm that generates electricity that can be sold for electrical use through a power-purchase agreement. Submittals must be prepared and delivered in accordance with the requirements set forth in this document.

  16. CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Systems for Landfills and Wastewater Treatment Plants CHP and Bioenergy Systems for Landfills and Wastewater Treatment Plants There are important issues to consider when selecting a CHP technology, such as size, emissions, location of maintenance personnel, and efficiency. This document summarizes the following CHP technologies: Reciprocating Engine, Microturbine, Combustion Turbines, Stirling Engine, and Fuel Cell. PDF icon CHP and Bioenergy Systems for Landfills and

  17. Landfill Methane Project Development Handbook | Open Energy Informatio...

    Open Energy Info (EERE)

    Methane Project Development Handbook Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Landfill Methane Project Development Handbook AgencyCompany Organization: United...

  18. DOE EM Landfill Workshop and Path Forward - July 2009

    Office of Environmental Management (EM)

    by CRESP DOE EM Landfill Workshop 2 Objective: - Discuss findings & recommendations from ITR visits to DOE facilities - Identify technology gaps and needs to advance EM disposal...

  19. http://ndep.nv.gov/bwm/landfill.htm

    National Nuclear Security Administration (NNSA)

    ... Republic Services, Inc Operating - Class I Permitted Laughlin Nevada Clark County Apex Regional Landfill Republic Services, Inc Operating - Class I Permitted Las Vegas Valley ...

  20. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Landfill Gas, Wind (Small), Hydroelectric (Small), Fuel Cells using Renewable Fuels, Microturbines Energy Conversion and Thermal Efficiency Sales Tax Exemption...

  1. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels, Landfill Gas, Wind (Small), Hydroelectric (Small), Anaerobic Digestion, Fuel Cells using Renewable Fuels, Other Distributed Generation Technologies Energy Conversion...

  2. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Biomass, Hydroelectric, Municipal Solid Waste, Combined Heat & Power, Landfill Gas, Tidal, Wave, Anaerobic Digestion, Microturbines Energy Conversion and Thermal Efficiency...

  3. Survey and Down-Selection of Acid Gas Removal Systems for the Thermochemical Conversion of Biomass to Ethanol with a Detailed Analysis of an MDEA System

    SciTech Connect (OSTI)

    Nexant, Inc., San Francisco, California

    2011-05-01

    The first section (Task 1) of this report by Nexant includes a survey and screening of various acid gas removal processes in order to evaluate their capability to meet the specific design requirements for thermochemical ethanol synthesis in NREL's thermochemical ethanol design report (Phillips et al. 2007, NREL/TP-510-41168). MDEA and selexol were short-listed as the most promising acid-gas removal agents based on work described in Task 1. The second report section (Task 2) describes a detailed design of an MDEA (methyl diethanol amine) based acid gas removal system for removing CO2 and H2S from biomass-derived syngas. Only MDEA was chosen for detailed study because of the available resources.

  4. Plasma-Hydrocarbon conversion - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrocarbon conversion Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL's Plasma-Hydrocarbon Conversion process enables conversion of heavy hydrocarbons, such as heavy crude oil and hydrocarbon gases like natural gas, into lighter hydrocarbon materials (e.g. synthetic light oil). Description It can convert hydrocarbon gases to liquid fuels/chemicals. The dielectric barrier discharge plasma process that adds carbon and hydrogen simultaneously to heavy

  5. Development of Real-Time, Gas Quality Sensor Technology

    Broader source: Energy.gov [DOE]

    Landfill gas (LFG), composed largely of methane and carbon dioxide, is used in over 645 operational projects in 48 states. These projects convert a large source of greenhouse gases into a fuel that...

  6. Case Study - Liquefied Natural Gas

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Environmental Science Enviro Express Kenworth LNG tractor. Connecticut Clean Cities Future Fuels Project Case Study - Liquefied Natural Gas As a part of the U.S. Department of Energy's broad effort to develop cleaner transportation technologies that reduce U.S. dependence on imported oil, this study examines advanced 2011 natural gas fueled trucks using liquefied natural gas (LNG) replacing older diesel fueled trucks. The trucks are used 6 days per week in regional city-to-landfill long hauls of

  7. Short Mountain Landfill Gas Recovery Project : Stage 1 Environmental Assessment.

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration.

    1992-05-01

    The Bonneville Power Administration (BPA), a Federal power marketing agency, has statutory responsibilities to supply electrical power to its utility, industrial, and other customers in the Pacific Northwest. BPA`s latest load/resource balance forecast, projects the capability of existing resources to satisfy projected Federal system loads. The forecast indicates a potential resource deficit. The underlying need for action is to satisfy BPA customers` demand for electrical power.

  8. Renewable LNG: Update on the World's Largest Landfill Gas to...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presented by Mike McGowan, Linde NA, Inc., at the NRELDOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado. PDF icon june2012biogasworkshopmcgowan.pdf ...

  9. RCWMD Badlands Landfill Gas Project Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    mW 1.0e-3 GW Commercial Online Date 2001 Heat Rate (BTUkWh) 12916.67 References EPA Web Site1 Loading map... "minzoom":false,"mappingservice":"googlemaps3","type":"TERRAIN...

  10. Winnebago County Landfill Gas Biomass Facility | Open Energy...

    Open Energy Info (EERE)

    2.72.7 MW 2,700 kW 2,700,000 W 2,700,000,000 mW 0.0027 GW Commercial Online Date 2000 Heat Rate (BTUkWh) 9350.0 References EPA Web Site1 Loading map... "minzoom":false,"map...

  11. Greenhouse gas emissions from landfill leachate treatment plants...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 54 ENVIRONMENTAL SCIENCES; 12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; AGING; CARBON DIOXIDE; GREENHOUSE GASES; LEACHATES; ...

  12. Thermochemical Conversion Processes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processes Thermochemical Conversion Processes Gasification In gasification conversion, lignocellulosic feedstocks such as wood and forest products are broken down to synthesis gas, primarily carbon monoxide and hydrogen, using heat. The feedstock is then partially oxidized, or reformed with a gasifying agent (air, oxygen, or steam), which produces synthesis gas (syngas). The makeup of syngas will vary due to the different types of feedstocks, their moisture content, the type of gasifier used,

  13. Biomass Thermochemical Conversion Program: 1986 annual report

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1987-01-01

    Wood and crop residues constitute a vast majority of the biomass feedstocks available for conversion, and thermochemical processes are well suited for conversion of these materials. Thermochemical conversion processes can generate a variety of products such as gasoline hydrocarbon fuels, natural gas substitutes, or heat energy for electric power generation. The US Department of Energy is sponsoring research on biomass conversion technologies through its Biomass Thermochemical Conversion Program. Pacific Northwest Laboratory has been designated the Technical Field Management Office for the Biomass Thermochemical Conversion Program with overall responsibility for the Program. This report briefly describes the Thermochemical Conversion Program structure and summarizes the activities and major accomplishments during fiscal year 1986. 88 refs., 31 figs., 5 tabs.

  14. Organic and nitrogen removal from landfill leachate in aerobic granular sludge sequencing batch reactors

    SciTech Connect (OSTI)

    Wei Yanjie; Ji Min; Li Ruying; Qin Feifei

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Aerobic granular sludge SBR was used to treat real landfill leachate. Black-Right-Pointing-Pointer COD removal was analyzed kinetically using a modified model. Black-Right-Pointing-Pointer Characteristics of nitrogen removal at different ammonium inputs were explored. Black-Right-Pointing-Pointer DO variations were consistent with the GSBR performances at low ammonium inputs. - Abstract: Granule sequencing batch reactors (GSBR) were established for landfill leachate treatment, and the COD removal was analyzed kinetically using a modified model. Results showed that COD removal rate decreased as influent ammonium concentration increasing. Characteristics of nitrogen removal at different influent ammonium levels were also studied. When the ammonium concentration in the landfill leachate was 366 mg L{sup -1}, the dominant nitrogen removal process in the GSBR was simultaneous nitrification and denitrification (SND). Under the ammonium concentration of 788 mg L{sup -1}, nitrite accumulation occurred and the accumulated nitrite was reduced to nitrogen gas by the shortcut denitrification process. When the influent ammonium increased to a higher level of 1105 mg L{sup -1}, accumulation of nitrite and nitrate lasted in the whole cycle, and the removal efficiencies of total nitrogen and ammonium decreased to only 35.0% and 39.3%, respectively. Results also showed that DO was a useful process controlling parameter for the organics and nitrogen removal at low ammonium input.

  15. Comparison between lab- and full-scale applications of in situ aeration of an old landfill and assessment of long-term emission development after completion

    SciTech Connect (OSTI)

    Hrad, Marlies; Gamperling, Oliver; Huber-Humer, Marion

    2013-10-15

    Highlights: ? Current data on in situ aeration effects from the first Austrian full-scale case study. ? Data on lasting waste stabilisation after aeration completion. ? Information on the transferability of results from lab- to full-scale aeration. - Abstract: Sustainable landfilling has become a fundamental objective in many modern waste management concepts. In this context, the in situ aeration of landfills has been recognised for its potential to convert conventional anaerobic landfills into biological stabilised state, whereby both current and potential (long-term) emissions of the landfilled waste are mitigated. In recent years, different in situ aeration concepts have been successfully applied in Europe, North America and Asia, all pursuing different objectives and strategies. In Austria, the first full-scale application of in situ landfill aeration by means of low pressure air injection and simultaneous off-gas collection and treatment was implemented on an old, small municipal solid waste (MSW) landfill (2.6 ha) in autumn 2007. Complementary laboratory investigations were conducted with waste samples taken from the landfill site in order to provide more information on the transferability of the results from lab- to full-scale aeration measures. In addition, long-term emission development of the stabilised waste after aeration completion was assessed in an ongoing laboratory experiment. Although the initial waste material was described as mostly stable in terms of the biological parameters gas generation potential over 21 days (GP{sub 21}) and respiration activity over 4 days (RA{sub 4}), the lab-scale experiments indicated that aeration, which led to a significant improvement of leachate quality, was accompanied by further measurable changes in the solid waste material under optimised conditions. Even 75 weeks after aeration completion the leachate, as well as gaseous emissions from the stabilised waste material, remained low and stayed below the authorised Austrian discharge limits. However, the application of in situ aeration at the investigated landfill is a factor 10 behind the lab-based predictions after 3 years of operation, mainly due to technical limitations in the full-scale operation (e.g. high air flow resistivity due to high water content of waste and temporarily high water levels within the landfill; limited efficiency of the aeration wells). In addition, material preparation (e.g. sieving, sorting and homogenisation) prior to the emplacement in Landfill Simulation Reactors (LSRs) must be considered when transferring results from lab- to full-scale application.

  16. compressed-gas storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage ...

  17. Industrial Waste Landfill IV upgrade package

    SciTech Connect (OSTI)

    Not Available

    1994-03-29

    The Y-12 Plant, K-25 Site, and ORNL are managed by DOE`s Operating Contractor (OC), Martin Marietta Energy Systems, Inc. (Energy Systems) for DOE. Operation associated with the facilities by the Operating Contractor and subcontractors, DOE contractors and the DOE Federal Building result in the generation of industrial solid wastes as well as construction/demolition wastes. Due to the waste streams mentioned, the Y-12 Industrial Waste Landfill IV (IWLF-IV) was developed for the disposal of solid industrial waste in accordance to Rule 1200-1-7, Regulations Governing Solid Waste Processing and Disposal in Tennessee. This revised operating document is a part of a request for modification to the existing Y-12 IWLF-IV to comply with revised regulation (Rule Chapters 1200-1-7-.01 through 1200-1-7-.08) in order to provide future disposal space for the ORR, Subcontractors, and the DOE Federal Building. This revised operating manual also reflects approved modifications that have been made over the years since the original landfill permit approval. The drawings referred to in this manual are included in Drawings section of the package. IWLF-IV is a Tennessee Department of Environmental and Conservation/Division of Solid Waste Management (TDEC/DSWM) Class 11 disposal unit.

  18. GHG emission factors developed for the collection, transport and landfilling of municipal waste in South African municipalities

    SciTech Connect (OSTI)

    Friedrich, Elena; Trois, Cristina

    2013-04-15

    Highlights: ? An average GHG emission factor for the collection and transport of municipal solid waste in South Africa is calculated. ? A range of GHG emission factors for different types of landfills (including dumps) in South Africa are calculated. ? These factors are compared internationally and their implications for South Africa and developing countries are discussed . ? Areas for new research are highlighted. - Abstract: Greenhouse gas (GHG) emission factors are used with increased frequency for the accounting and reporting of GHG from waste management. However, these factors have been calculated for developed countries of the Northern Hemisphere and are lacking for developing countries. This paper shows how such factors have been developed for the collection, transport and landfilling of municipal waste in South Africa. As such it presents a model on how international results and methodology can be adapted and used to calculate country-specific GHG emission factors from waste. For the collection and transport of municipal waste in South Africa, the average diesel consumption is around 5 dm{sup 3} (litres) per tonne of wet waste and the associated GHG emissions are about 15 kg CO{sub 2} equivalents (CO{sub 2} e). Depending on the type of landfill, the GHG emissions from the landfilling of waste have been calculated to range from ?145 to 1016 kg CO{sub 2} e per tonne of wet waste, when taking into account carbon storage, and from 441 to 2532 kg CO{sub 2} e per tonne of wet waste, when carbon storage is left out. The highest emission factor per unit of wet waste is for landfill sites without landfill gas collection and these are the dominant waste disposal facilities in South Africa. However, cash strapped municipalities in Africa and the developing world will not be able to significantly upgrade these sites and reduce their GHG burdens if there is no equivalent replacement of the Clean Development Mechanism (CDM) resulting from the Kyoto agreement. Other low cost avenues need to be investigated to suit local conditions, in particular landfill covers which enhance methane oxidation.

  19. power conversion efficiency

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    power conversion efficiency - Sandia Energy Energy Search Icon Sandia Home Locations ... Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar ...

  20. Utilization of a fuel cell power plant for the capture and conversion of gob well gas. Final report, June--December, 1995

    SciTech Connect (OSTI)

    Przybylic, A.R.; Haynes, C.D.; Haskew, T.A.; Boyer, C.M. II; Lasseter, E.L.

    1995-12-01

    A preliminary study has been made to determine if a 200 kW fuel cell power plant operating on variable quality coalbed methane can be placed and successfully operated at the Jim Walter Resources No. 4 mine located in Tuscaloosa County, Alabama. The purpose of the demonstration is to investigate the effects of variable quality (50 to 98% methane) gob gas on the output and efficiency of the power plant. To date, very little detail has been provided concerning the operation of fuel cells in this environment. The fuel cell power plant will be located adjacent to the No. 4 mine thermal drying facility rated at 152 M British thermal units per hour. The dryer burns fuel at a rate of 75,000 cubic feet per day of methane and 132 tons per day of powdered coal. The fuel cell power plant will provide 700,000 British thermal units per hour of waste heat that can be utilized directly in the dryer, offsetting coal utilization by approximately 0.66 tons per day and providing an avoided cost of approximately $20 per day. The 200 kilowatt electrical power output of the unit will provide a utility cost reduction of approximately $3,296 each month. The demonstration will be completely instrumented and monitored in terms of gas input and quality, electrical power output, and British thermal unit output. Additionally, real-time power pricing schedules will be applied to optimize cost savings. 28 refs., 35 figs., 13 tabs.

  1. A case study: Environmental benefit plan for Blydenburgh Landfill

    SciTech Connect (OSTI)

    Hansen, J.M.; Druback, G.W.

    1995-12-31

    The Town of Islip, New York, encompasses 285 square kilometers (110 square miles) along the southern shore of Suffolk County, Long Island. The Town relied upon Blydenburgh Landfill for the disposal of its estimated 290 kilotonnes per year (320,000 tons per year) of municipal solid waste (MSW) without having to contract for off-Long Island hauling and disposal. In 1983, the Long Island Landfill Law was enacted and effectively banned landfilling of raw garbage on most of Long Island after December 18, 1990. The act precluded the economic development of new landfill capacity for the Town. Blydenburgh Landfill was projected to reach capacity in early 1987 and close. To conserve landfill capacity for residential use, the Town prohibited commercial haulers from the landfill in the fall of 1986. In response, the Mobro barge departed Long Island City on March 22, 1987 loaded with commercial MSW that was no longer accepted at the Blydenburgh site. Negative publicity surrounded the Mobro barge and the continuing need to provide for waste disposal. In response, the New York State Department of Environmental Conservation (NYSDEC) and the Town`s Resource Recovery Agency entered into an Order on Consent on May 12, 1987. This allowed for continued operations and a vertical MSW {open_quotes}piggyback{close_quotes} expansion on top of a closed and capped portion of the existing 181,000 square meter (44.8 acre) landfill mound. In addition, the Order on Consent permitted construction of a separate 12,000 square meter (3.0 acre) ash residue vertical piggyback expansion adjacent to the MSW piggyback expansion. Both expansions were designed for and constructed on top of existing landfilled MSW.

  2. Landfill mining: A critical review of two decades of research

    SciTech Connect (OSTI)

    Krook, Joakim; Svensson, Niclas; Eklund, Mats

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer We analyze two decades of landfill mining research regarding trends and topics. Black-Right-Pointing-Pointer So far landfill mining has mainly been used to solve waste management issues. Black-Right-Pointing-Pointer A new perspective on landfills as resource reservoirs is emerging. Black-Right-Pointing-Pointer The potential of resource extraction from landfills is significant. Black-Right-Pointing-Pointer We outline several key challenges for realization of resource extraction from landfills. - Abstract: Landfills have historically been seen as the ultimate solution for storing waste at minimum cost. It is now a well-known fact that such deposits have related implications such as long-term methane emissions, local pollution concerns, settling issues and limitations on urban development. Landfill mining has been suggested as a strategy to address such problems, and in principle means the excavation, processing, treatment and/or recycling of deposited materials. This study involves a literature review on landfill mining covering a meta-analysis of the main trends, objectives, topics and findings in 39 research papers published during the period 1988-2008. The results show that, so far, landfill mining has primarily been seen as a way to solve traditional management issues related to landfills such as lack of landfill space and local pollution concerns. Although most initiatives have involved some recovery of deposited resources, mainly cover soil and in some cases waste fuel, recycling efforts have often been largely secondary. Typically, simple soil excavation and screening equipment have therefore been applied, often demonstrating moderate performance in obtaining marketable recyclables. Several worldwide changes and recent research findings indicate the emergence of a new perspective on landfills as reservoirs for resource extraction. Although the potential of this approach appears significant, it is argued that facilitating implementation involves a number of research challenges in terms of technology innovation, clarifying the conditions for realization and developing standardized frameworks for evaluating economic and environmental performance from a systems perspective. In order to address these challenges, a combination of applied and theoretical research is required.

  3. Manhattan Project truck unearthed at landfill cleanup site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manhattan project truck Manhattan Project truck unearthed at landfill cleanup site A LANL excavation crew working on a Recovery Act cleanup project has uncovered the remnants of a 1940s military truck buried in a Manhattan Project-era landfill. April 8, 2011 image description Excavator operator Kevin Miller looks at the remnants of a 1940s military truck buried in a Manhattan Project-era landfill. Contact Fred deSousa Communications Office (505) 665-3430 Email Remnants of a 1940s military truck

  4. DOE - Office of Legacy Management -- Shpack Landfill - MA 06

    Office of Legacy Management (LM)

    Shpack Landfill - MA 06 FUSRAP Considered Sites Shpack Landfill, NY Alternate Name(s): Attleboro, MA Metals and Controls Site Norton Landfill area MA.06-2 MA.06-3 Location: 68 Union Road, Norton, Massachusetts MA.06-2 Historical Operations: No AEC activities were conducted on site. Contamination was suspected from disposal of materials containing uranium and zirconium ash. MA.06-2 MA.06-3 Eligibility Determination: Eligible MA.06-1 Radiological Survey(s): Assessment Surveys MA.06-4 MA.06-5

  5. INVESTIGATION OF HOLOCENE FAULTING PROPOSED C-746-U LANDFILL EXPANSION

    SciTech Connect (OSTI)

    Lettis, William

    2006-07-01

    This report presents the findings of a fault hazard investigation for the C-746-U landfill's proposed expansion located at the Department of Energy's (DOE) Paducah Gaseous Diffusion Plant (PGDP), in Paducah, Kentucky. The planned expansion is located directly north of the present-day C-746-U landfill. Previous geophysical studies within the PGDP site vicinity interpret possible northeast-striking faults beneath the proposed landfill expansion, although prior to this investigation the existence, locations, and ages of these inferred faults have not been confirmed through independent subsurface exploration. The purpose of this investigation is to assess whether or not Holocene-active fault displacement is present beneath the footprint of the proposed landfill expansion.

  6. Briefing: Summary and Recommendations of EM Landfill Workshop...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The briefing is an independent technical review report from the summary and recommendations of the EM Landfill Workshop help in October 2008. By: Craig H. Bendson, PhD, PE; William ...

  7. Sandia National Laboratories: No More Green Waste in the Landfill

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    No More Green Waste in the Landfill June 09, 2011 Dump Truck Image On the heels of Sandia National Laboratories' successful food waste composting program, Pollution Prevention (P2)...

  8. Sandia National Laboratories: No More Green Waste in the Landfill

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    No More Green Waste in the Landfill June 09, 2011 Dump Truck Image On the heels of Sandia National Laboratories' successful food waste composting program, Pollution Prevention (P2) has teamed with the Facilities' Grounds and Roads team and the Solid Waste Transfer Facility to implement green waste composting. Previously, branches and logs were being diverted and mulched by Kirtland Air Force Base at their Construction & Demolition Landfill that is on base and utilized under contract by

  9. Computer Modeling of Saltstone Landfills by Intera Environmental Consultants

    SciTech Connect (OSTI)

    Albenesius, E.L.

    2001-08-09

    This report summaries the computer modeling studies and how the results of these studies were used to estimate contaminant releases to the groundwater. These modeling studies were used to improve saltstone landfill designs and are the basis for the current reference design. With the reference landfill design, EPA Drinking Water Standards can be met for all chemicals and radionuclides contained in Savannah River Plant waste salts.

  10. Appendix B Landfill Inspection Forms and Survey Data

    Office of Legacy Management (LM)

    B Landfill Inspection Forms and Survey Data This page intentionally left blank This page intentionally left blank Original Landfill January 2012 Monthly Inspection-Attachment 1 The monthly inspection of the OLF was completed on January 30. The Rocky Flats Site only received .15 inches of precipitation during the month of January. The cover was dry at the time of the inspection. The slump in the East Perimeter Channel (EPC) remained unchanged. Berm locations that were re-graded during the OLF

  11. Determination of operating limits for radionuclides for a proposed landfill at Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Wang, J.C.; Lee, D.W.; Ketelle, R.H.; Lee, R.R.; Kocher, D.C.

    1994-05-24

    The operating limits for radionuclides in sanitary and industrial wastes were determined for a proposed landfill at the Paducah Gaseous Diffusion Plant (PGDP), Kentucky. These limits, which may be very small but nonzero, are not mandated by law or regulation but are needed for rational operation. The approach was based on analyses of the potential contamination of groundwater at the plant boundary and the potential exposure to radioactivity of an intruder at the landfill after closure. The groundwater analysis includes (1) a source model describing the disposal of waste and the release of radionuclides from waste to the groundwater, (2) site-specific groundwater flow and contaminant transport calculations, and (3) calculations of operating limits from the dose limit and conversion factors. The intruder analysis includes pathways through ingestion of contaminated vegetables and soil, external exposure to contaminated soil, and inhalation of suspended activity from contaminated soil particles. In both analyses, a limit on annual effective dose equivalent of 4 mrem (0.04 mSv) was adopted. The intended application of the results is to refine the radiological monitoring standards employed by the PGDP Health Physics personnel to determine what constitutes radioactive wastes, with concurrence of the Commonwealth of Kentucky.

  12. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Solar Photovoltaics, Wind (All), Biomass, Hydroelectric, Landfill Gas, Wind (Small) Energy Conversion and Thermal Efficiency Sales Tax Exemption Qualifying energy conversion...

  13. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Hydroelectric, Landfill Gas, Wind (Small) Energy Conversion and Thermal Efficiency Sales Tax Exemption Qualifying energy conversion facilities are those that are used for the...

  14. Spatial variability of nitrous oxide and methane emissions from an MBT landfill in operation: Strong N{sub 2}O hotspots at the working face

    SciTech Connect (OSTI)

    Harborth, Peter; Fu, Roland; Mnnich, Kai; Flessa, Heinz; Fricke, Klaus

    2013-10-15

    Highlights: ? First measurements of N{sub 2}O and CH{sub 4} emissions from an MBT landfill. ? High N{sub 2}O emissions from recently deposited material. ? N{sub 2}O emissions associated with aeration and the occurrence of nitrite and nitrate. ? Strong negative correlation between CH{sub 4} and N{sub 2}O production activity. - Abstract: Mechanical biological treatment (MBT) is an effective technique, which removes organic carbon from municipal solid waste (MSW) prior to deposition. Thereby, methane (CH{sub 4}) production in the landfill is strongly mitigated. However, direct measurements of greenhouse gas emissions from full-scale MBT landfills have not been conducted so far. Thus, CH{sub 4} and nitrous oxide (N{sub 2}O) emissions from a German MBT landfill in operation as well as their concentrations in the landfill gas (LFG) were measured. High N{sub 2}O emissions of 20200 g CO{sub 2} eq. m{sup ?2} h{sup ?1} magnitude (up to 428 mg N m{sup ?2} h{sup ?1}) were observed within 20 m of the working face. CH{sub 4} emissions were highest at the landfill zone located at a distance of 3040 m from the working face, where they reached about 10 g CO{sub 2} eq. m{sup ?2} h{sup ?1}. The MBT material in this area has been deposited several weeks earlier. Maximum LFG concentration for N{sub 2}O was 24.000 ppmv in material below the emission hotspot. At a depth of 50 cm from the landfill surface a strong negative correlation between N{sub 2}O and CH{sub 4} concentrations was observed. From this and from the distribution pattern of extractable ammonium, nitrite, and nitrate it has been concluded that strong N{sub 2}O production is associated with nitrification activity and the occurrence of nitrite and nitrate, which is initiated by oxygen input during waste deposition. Therefore, CH{sub 4} mitigation measures, which often employ aeration, could result in a net increase of GHG emissions due to increased N{sub 2}O emissions, especially at MBT landfills.

  15. Risk mitigation methodology for solid waste landfills. Doctoral thesis

    SciTech Connect (OSTI)

    Nixon, W.B.

    1995-05-01

    Several recent models have attempted to simulate or assess the probability and consequences of the leakage of aqueous contaminant leakage from solid waste landfills. These models incorporate common factors, including climatological and geological characteristics. Each model, however, employs a unique approach to the problem, assigns different relative weights to factors, and relies upon extrapolated small-scale experimental data and/or subjective judgment in predicting the full-scale landfill failure mechanisms leading to contaminant migration. As a result, no two models are likely to equally assess a given landfill, and no one model has been validated as a predictor of long-term performance. The United States Air Force maintains a database for characterization of potential hazardous waste sites. Records include more than 500 landfills, providing such information as waste, soil, aquifer, monitoring location data, and the results of sample testing. Through analysis of this information, nearly 300 landfills were assessed to have sufficiently, partially, or inadequately contained hazardous constituents of the wastes placed within them.

  16. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  17. Fossil fuel conversion--measurement and modeling

    SciTech Connect (OSTI)

    Solomon, P.R.; Smoot, L.D.; Serio, M.A.; Hamblen, D.G.; Brewster, B.S.; Radulovic, P.T.

    1994-10-01

    The main objective of this program is to understand the chemical and physical mechanisms in coal conversion processes and incorporate this knowledge in computer-aided reactor engineering technology for the purposes of development, evaluation, design, scale-up, simulation, control and feedstock evaluation in advanced coal conversion devices. To accomplish this objective, this program will: (1) provide critical data on the physical and chemical processes in fossil fuel gasifiers and combustors; (2) further develop a set of comprehensive codes; and (3) apply these codes to model various types of combustors and gasifiers (fixed-bed, transport reactor, and fluidized-bed for coal and gas turbines for natural gas).

  18. 1982 annual report: Biomass Thermochemical Conversion Program

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1983-01-01

    This report provides a brief overview of the Thermochemical Conversion Program's activities and major accomplishments during fiscal year 1982. The objective of the Biomass Thermochemical Conversion Program is to generate scientific data and fundamental biomass converison process information that, in the long term, could lead to establishment of cost effective processes for conversion of biomass resources into clean fuels and petrochemical substitutes. The goal of the program is to improve the data base for biomass conversion by investigating the fundamental aspects of conversion technologies and exploring those parameters which are critical to these conversion processes. To achieve this objective and goal, the Thermochemical Conversion Program is sponsoring high-risk, long-term research with high payoff potential which industry is not currently sponsoring, nor is likely to support. Thermochemical conversion processes employ elevated temperatures to convert biomass materials into energy. Process examples include: combustion to produce heat, steam, electricity, direct mechanical power; gasification to produce fuel gas or synthesis gases for the production of methanol and hydrocarbon fuels; direct liquefaction to produce heavy oils or distillates; and pyrolysis to produce a mixture of oils, fuel gases, and char. A bibliography of publications for 1982 is included.

  19. Corrective Action Plan for Corrective Action Unit 424: Area 3 Landfill Complex, Tonopah Test Range, Nevada

    SciTech Connect (OSTI)

    Bechtel Nevada

    1998-08-31

    This corrective action plan provides the closure implementation methods for the Area 3 Landfill Complex, Corrective Action Unit (CAU) 424, located at the Tonopah Test Range. The Area 3 Landfill Complex consists of 8 landfill sites, each designated as a separate corrective action site.

  20. Sanitary landfill groundwater monitoring report. Third quarter 1995

    SciTech Connect (OSTI)

    1995-11-01

    This report contains analytical data for samples taken during third quarter 1995 from wells of the LFW series located at the Sanitary Landfill at the Savannah River Site (SRS). The data are submitted in reference to the Sanitary Landfill Operating Permit (DWP-087A). The report presents monitoring results that equaled or exceeded the Safe Drinking Water Act final Primary Drinking Water Standards (PDWS) or screening levels, established by the U.S. Environmental Protection Agency, the South Carolina final Primary Drinking Water Standard for lead, or the SRS flagging criteria.

  1. Delineation of landfill migration boundaries using chemical surrogates

    SciTech Connect (OSTI)

    Thielen, D.R.; Foreman, P.S.; Davis, A.; Wyeth, R.

    1987-02-01

    A purge/trap procedures for the determination of monochlorobenzene and monochlorotoluene at the 10 ng/g level in soil is described. The advantages of a heated and stirred vessel for sample preparation are demonstrated. This method was applied to samples from the Hyde Park landfill site in Niagara Falls, NY, and the results were used to define chemical migration is illustrated with both two- and three-dimensional plotting techniques. This study is a first phase in the development of a remedial plan for the Hyde Park landfill.

  2. Sanitary Landfill Groundwater Monitoring Report. Second Quarter 1995

    SciTech Connect (OSTI)

    Chase, J.A.

    1995-08-01

    This report contains analytical data for samples taken during second quarter 1995 from wells of the LFW series located at the Sanitary Landfill at the Savannah River Site (SRS). The data are submitted in reference to the Sanitary landfill Operating Permit (DWP-087A). The report presents monitoring results that equaled or exceeded the Safe Drinking Water Act final Primary Water Standards (PDWS) or screening levels, established by the US Environmental Protection Agency (Appendix A), the South Carolina final Primary Drinking Water Standard for lead (Appendix A), or the SRS flagging criteria (Appendix B).

  3. A study of tritium in municipal solid waste leachate and gas

    SciTech Connect (OSTI)

    Mutch Jr, R. D.; Mahony, J. D.

    2008-07-15

    It has become increasingly clear in the last few years that the vast majority of municipal solid waste landfills produce leachate that contains elevated levels of tritium. The authors recently conducted a study of landfills in New York and New Jersey and found that the mean concentration of tritium in the leachate from ten municipal solid waste (MSW) landfills was 33,800 pCi/L with a peak value of 192,000 pCi/L. A 2003 study in California reported a mean tritium concentration of 99,000 pCi/L with a peak value of 304,000 pCi/L. Studies in Pennsylvania and the UK produced similar results. The USEPA MCL for tritium is 20,000 pCi/L. Tritium is also manifesting itself as landfill gas and landfill gas condensate. Landfill gas condensate samples from landfills in the UK and California were found to have tritium concentrations as high as 54,400 and 513,000 pCi/L, respectively. The tritium found in MSW leachate is believed to derive principally from gaseous tritium lighting devices used in some emergency exit signs, compasses, watches, and even novelty items, such as 'glow stick' key chains. This study reports the findings of recent surveys of leachate from a number of municipal solid waste landfills, both open and closed, from throughout the United States and Europe. The study evaluates the human health and ecological risks posed by elevated tritium levels in municipal solid waste leachate and landfill gas and the implications to their safe management. We also assess the potential risks posed to solid waste management facility workers exposed to tritium-containing waste materials in transfer stations and other solid waste management facilities. (authors)

  4. Algal Polyculture Conversion & Analysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... conversion: Sugar & Protein Fermentation * 70% of theoretical protein ... costly CO 2 supply &or co-location w industrial sources - Can avoid commercial ...

  5. Organic carbon cycling in landfills: Model for a continuum approach

    SciTech Connect (OSTI)

    Bogner, J.; Lagerkvist, A.

    1997-09-01

    Organic carbon cycling in landfills can be addressed through a continuum model where the end-points are conventional anaerobic digestion of organic waste (short-term analogue) and geologic burial of organic material (long-term analogue). Major variables influencing status include moisture state, temperature, organic carbon loading, nutrient status, and isolation from the surrounding environment. Bioreactor landfills which are engineered for rapid decomposition approach (but cannot fully attain) the anaerobic digester end-point and incur higher unit costs because of their high degree of environmental isolation and control. At the other extreme, uncontrolled land disposal of organic waste materials is similar to geologic burial where organic carbon may be aerobically recycled to atmospheric CO{sub 2}, anaerobically converted to CH{sub 4} and CO{sub 2} during early diagenesis, or maintained as intermediate or recalcitrant forms into geologic time (> 1,000 years) for transformations via kerogen pathways. A family of improved landfill models are needed at several scales (molecular to landscape) which realistically address landfill processes and can be validated with field data.

  6. Story Road Landfill Solar Site Evaluation: San Jose

    Broader source: Energy.gov [DOE]

    This report describes the findings of a solar site evaluation conducted at the Story Road Landfill (Site) in the City of San Jose, California (City). This evaluation was conducted as part of a larger study to assess solar potential at multiple public facilities within the City.

  7. Sanitary landfill groundwater monitoring data. First quarter 1992

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-05-01

    This report for first quarter 1992 contains sanitary landfill groundwater monitoring data for the Savannah River Plant. The data tables presented in this report are copies of draft analytical results and therefore do contain errors. These errors will be corrected when the finalized data is received from the laboratory.

  8. NUCLEAR CONVERSION APPARATUS

    DOE Patents [OSTI]

    Seaborg, G.T.

    1960-09-13

    A nuclear conversion apparatus is described which comprises a body of neutron moderator, tubes extending therethrough, uranium in the tubes, a fluid- circulating system associated with the tubes, a thorium-containing fluid coolant in the system and tubes, and means for withdrawing the fluid from the system and replacing it in the system whereby thorium conversion products may be recovered.

  9. Energy Conversion and Thermal Efficiency Sales Tax Exemption

    Broader source: Energy.gov [DOE]

    Qualifying energy conversion facilities are those that are used for the primary purpose of converting natural gas or fuel oil to an alternate fuel or power source excluding propane, butane, napht...

  10. Microsoft Word - Gas-Electricity Briefing Memo 072414 FINAL

    Broader source: Energy.gov (indexed) [DOE]

    ... Conversely, after the "Polar Vortex" of 2013-2014, demand ... net load - a key advantage of natural gas technologies. ... gas power plants - a process that will potentially be ...

  11. Biochemical Conversion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion Biochemical Conversion This area focuses on the research, development and demonstration of biological processes that convert biomass to biofuels, chemicals, and power. Biochemical processes also complement thermochemical conversion by providing residual materials for further processing. Biochemical conversion will advance in the future by enhancing fuel yields in integrated biorefineries which combine conversion types with heat and power efficiencies to produce fuel and products.

  12. Measurements of particulate matter concentrations at a landfill site (Crete, Greece)

    SciTech Connect (OSTI)

    Chalvatzaki, E.; Kopanakis, I.; Kontaksakis, M.; Glytsos, T.; Kalogerakis, N.; Lazaridis, M.

    2010-11-15

    Large amounts of solid waste are disposed in landfills and the potential of particulate matter (PM) emissions into the atmosphere is significant. Particulate matter emissions in landfills are the result of resuspension from the disposed waste and other activities such as mechanical recycling and composting, waste unloading and sorting, the process of coating residues and waste transport by trucks. Measurements of ambient levels of inhalable particulate matter (PM{sub 10}) were performed in a landfill site located at Chania (Crete, Greece). Elevated PM{sub 10} concentrations were measured in the landfill site during several landfill operations. It was observed that the meteorological conditions (mainly wind velocity and temperature) influence considerably the PM{sub 10} concentrations. Comparison between the PM{sub 10} concentrations at the landfill and at a PM{sub 10} background site indicates the influence of the landfill activities on local concentrations at the landfill. No correlation was observed between the measurements at the landfill and the background sites. Finally, specific preventing measures are proposed to control the PM concentrations in landfills.

  13. Passive soil venting at the Chemical Waste Landfill Site at Sandia National Laboratories, Albuquerque, New Mexico

    SciTech Connect (OSTI)

    Phelan, J.M.; Reavis, B.; Cheng, W.C.

    1995-05-01

    Passive Soil Vapor Extraction was tested at the Chemical Waste Landfill (CWL) site at Sandia National Laboratories, New Mexico (SNLIW). Data collected included ambient pressures, differential pressures between soil gas and ambient air, gas flow rates into and out of the soil and concentrations of volatile organic compounds (VOCS) in vented soil gas. From the differential pressure and flow rate data, estimates of permeability were arrived at and compared with estimates from other studies. Flow, differential pressure, and ambient pressure data were collected for nearly 30 days. VOC data were collected for two six-hour periods during this time. Total VOC emissions were calculated and found to be under the limit set by the Resource Conservation and Recovery Act (RCRA). Although a complete process evaluation is not possible with the data gathered, some of the necessary information for designing a passive venting process was determined and the important parameters for designing the process were indicated. More study is required to evaluate long-term VOC removal using passive venting and to establish total remediation costs when passive venting is used as a polishing process following active soil vapor extraction.

  14. Structured luminescence conversion layer

    DOE Patents [OSTI]

    Berben, Dirk; Antoniadis, Homer; Jermann, Frank; Krummacher, Benjamin Claus; Von Malm, Norwin; Zachau, Martin

    2012-12-11

    An apparatus device such as a light source is disclosed which has an OLED device and a structured luminescence conversion layer deposited on the substrate or transparent electrode of said OLED device and on the exterior of said OLED device. The structured luminescence conversion layer contains regions such as color-changing and non-color-changing regions with particular shapes arranged in a particular pattern.

  15. Sanitary landfill groundwater monitoring report. First Quarter 1995

    SciTech Connect (OSTI)

    1995-06-01

    This report contains analytical data for samples taken during first quarter 1994 from wells of the LFW series located at the Sanitary Landfill Operating permit (DWP-0874A). The report presents monitoring results that equaled or exceeded the Safe Drinking Water Act final Primary Drinking Water Standards (PDWS) or screening levels, established by the US Environmental Protection Agency, the South Carolina final Primary Drinking Water Standard for lead, or the SRS flagging criteria.

  16. Appendix B Landfill Inspection Forms and Survey Data

    Office of Legacy Management (LM)

    Original Landfill January 2011 Monthly Inspection - Attachment 1 The January inspection of the OLF was completed on January 28. The cover was fairly dry at the time of the inspection as precipitation has been scarce during the entire month. No new cracks were observed during this inspection. The locations where the previously reported cracks had been filled and compacted were also still in good repair. Project Location Updates Berm 1 and 7 continue to look good with no new slumping or cracking

  17. Hazardous waste site assessment: Inactive landfill, Site 300, Lawrence Livermore National Laboratory

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    This report presents the results of an investigation of an inactive landfill (Pit 6) at Lawrence Livermore National Laboratory's (LLNL) Site 300. The primary objectives were to: collect and review background information pertaining to past waste disposal practices and previous environmental characterization studies; conduct a geophysical survey of the landfill area to locate the buried wastes; conduct a hydrogeologic investigation to provide additional data on the rate and direction of groundwater flow, the extent of any groundwater contamination, and to investigate the connection, if any, of the shallow groundwater beneath the landfill with the local drinking water supply; conduct a risk assessment to identify the degree of threat posed by the landfill to the public health and environment; compile a preliminary list of feasible long-term remedial action alternatives for the landfill; and develop a list of recommendations for any interim measures necessary at the landfill should the long-term remedial action plan be needed.

  18. 488-4D ASH LANDFILL CLOSURE CAP HELP MODELING

    SciTech Connect (OSTI)

    Phifer, M.

    2014-11-17

    At the request of Area Completion Projects (ACP) in support of the 488-4D Landfill closure, the Savannah River National Laboratory (SRNL) has performed Hydrologic Evaluation of Landfill Performance (HELP) modeling of the planned 488-4D Ash Landfill closure cap to ensure that the South Carolina Department of Health and Environmental Control (SCDHEC) limit of no more than 12 inches of head on top of the barrier layer (saturated hydraulic conductivity of no more than 1.0E-05 cm/s) in association with a 25-year, 24-hour storm event is not projected to be exceeded. Based upon Weber 1998 a 25-year, 24-hour storm event at the Savannah River Site (SRS) is 6.1 inches. The results of the HELP modeling indicate that the greatest peak daily head on top of the barrier layer (i.e. geosynthetic clay liner (GCL) or high density polyethylene (HDPE) geomembrane) for any of the runs made was 0.079 inches associated with a peak daily precipitation of 6.16 inches. This is well below the SCDHEC limit of 12 inches.

  19. Partial oxidation of landfill leachate in supercritical water: Optimization by response surface methodology

    SciTech Connect (OSTI)

    Gong, Yanmeng; Wang, Shuzhong; Xu, Haidong; Guo, Yang; Tang, Xingying

    2015-09-15

    Highlights: • Partial oxidation of landfill leachate in supercritical water was investigated. • The process was optimized by Box–Behnken design and response surface methodology. • GY{sub H2}, TRE and CR could exhibit up to 14.32 mmol·gTOC{sup −1}, 82.54% and 94.56%. • Small amounts of oxidant can decrease the generation of tar and char. - Abstract: To achieve the maximum H{sub 2} yield (GY{sub H2}), TOC removal rate (TRE) and carbon recovery rate (CR), response surface methodology was applied to optimize the process parameters for supercritical water partial oxidation (SWPO) of landfill leachate in a batch reactor. Quadratic polynomial models for GY{sub H2}, CR and TRE were established with Box–Behnken design. GY{sub H2}, CR and TRE reached up to 14.32 mmol·gTOC{sup −1}, 82.54% and 94.56% under optimum conditions, respectively. TRE was invariably above 91.87%. In contrast, TC removal rate (TR) only changed from 8.76% to 32.98%. Furthermore, carbonate and bicarbonate were the most abundant carbonaceous substances in product, whereas CO{sub 2} and H{sub 2} were the most abundant gaseous products. As a product of nitrogen-containing organics, NH{sub 3} has an important effect on gas composition. The carbon balance cannot be reached duo to the formation of tar and char. CR increased with the increase of temperature and oxidation coefficient.

  20. Direct Carbon Conversion: Application to the Efficient Conversion of Fossil Fuels to Electricity

    SciTech Connect (OSTI)

    Cooper, J F; Cherepy, N; Berry, G; Pasternak, A; Surles, T; Steinberg, M

    2001-03-07

    We introduce a concept for efficient conversion of fossil fuels to electricity that entails the decomposition of fossil-derived hydrocarbons into carbon and hydrogen, and electrochemical conversion of these fuels in separate fuel cells. Carbon/air fuel cells have the advantages of near zero entropy change and associated heat production (allowing 100% theoretical conversion efficiency). The activities of the C fuel and CO{sub 2} product are invariant, allowing constant EMF and full utilization of fuel in single pass mode of operation. System efficiency estimates were conducted for several routes involving sequential extraction of a hydrocarbon from the fossil resource by (hydro) pyrolysis followed by thermal decomposition. The total energy conversion efficiencies of the processes were estimated to be (1) 80% for direct conversion of petroleum coke; (2) 67% HHV for CH{sub 4}; (3) 72% HHV for heavy oil (modeled using properties of decane); (4) 75.5% HHV (83% LHV) for natural gas conversion with a Rankine bottoming cycle for the H{sub 2} portion; and (5) 69% HHV for conversion of low rank coals and lignite through hydrogenation and pyrolysis of the CH{sub 4} intermediate. The cost of carbon fuel is roughly $7/GJ, based on the cost of the pyrolysis step in the industrial furnace black process. Cell hardware costs are estimated to be less than $500/kW.

  1. INDEPENDENT VERIFICATION SURVEY REPORT FOR THE OPERABLE UNIT-1 LANDFILL TRENCHES, MIAMISBURG CLOSURE PROJECT

    SciTech Connect (OSTI)

    W.C. Adams

    2010-05-24

    INDEPENDENT VERIFICATION SURVEY REPORT FOR THE OPERABLE UNIT-1 LANDFILL TRENCHES, MIAMISBURG CLOSURE PROJECT, MIAMISBURG, OHIO DCN: 0468-SR-02-0

  2. INDEPENDENT VERIFICATION SURVEY REPORT OPERABLE UNIT-1 LANDFILL TRENCHES, MIAMISBURG CLOSURE PROJECT

    SciTech Connect (OSTI)

    W.C. Adams

    2010-07-21

    INDEPENDENT VERIFICATION SURVEY REPORT FOR THE OPERABLE UNIT-1 LANDFILL TRENCHES, MIAMISBURG CLOSURE PROJECT, MIAMISBURG, OHIO DCN: 0468-SR-03-0

  3. Biomass Thermochemical Conversion Program. 1984 annual report

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1985-01-01

    The objective of the program is to generate scientific data and conversion process information that will lead to establishment of cost-effective process for converting biomass resources into clean fuels. The goal of the program is to develop the data base for biomass thermal conversion by investigating the fundamental aspects of conversion technologies and by exploring those parameters that are critical to the conversion processes. The research activities can be divided into: (1) gasification technology; (2) liquid fuels technology; (3) direct combustion technology; and (4) program support activities. These activities are described in detail in this report. Outstanding accomplishments during fiscal year 1984 include: (1) successful operation of 3-MW combustor/gas turbine system; (2) successful extended term operation of an indirectly heated, dual bed gasifier for producing medium-Btu gas; (3) determination that oxygen requirements for medium-Btu gasification of biomass in a pressurized, fluidized bed gasifier are low; (4) established interdependence of temperature and residence times on biomass pyrolysis oil yields; and (5) determination of preliminary technical feasibility of thermally gasifying high moisture biomass feedstocks. A bibliography of 1984 publications is included. 26 figs., 1 tab.

  4. Digital optical conversion module

    DOE Patents [OSTI]

    Kotter, D.K.; Rankin, R.A.

    1988-07-19

    A digital optical conversion module used to convert an analog signal to a computer compatible digital signal including a voltage-to-frequency converter, frequency offset response circuitry, and an electrical-to-optical converter. Also used in conjunction with the digital optical conversion module is an optical link and an interface at the computer for converting the optical signal back to an electrical signal. Suitable for use in hostile environments having high levels of electromagnetic interference, the conversion module retains high resolution of the analog signal while eliminating the potential for errors due to noise and interference. The module can be used to link analog output scientific equipment such as an electrometer used with a mass spectrometer to a computer. 2 figs.

  5. Digital optical conversion module

    DOE Patents [OSTI]

    Kotter, Dale K.; Rankin, Richard A.

    1991-02-26

    A digital optical conversion module used to convert an analog signal to a computer compatible digital signal including a voltage-to-frequency converter, frequency offset response circuitry, and an electrical-to-optical converter. Also used in conjunction with the digital optical conversion module is an optical link and an interface at the computer for converting the optical signal back to an electrical signal. Suitable for use in hostile environments having high levels of electromagnetic interference, the conversion module retains high resolution of the analog signal while eliminating the potential for errors due to noise and interference. The module can be used to link analog output scientific equipment such as an electrometer used with a mass spectrometer to a computer.

  6. Direct conversion technology

    SciTech Connect (OSTI)

    Massier, P.F.; Back, L.H.; Ryan, M.A.; Fabris, G.

    1992-01-07

    The overall objective of the Direct Conversion Technology task is to develop an experimentally verified technology base for promising direct conversion systems that have potential application for energy conservation in the end-use sectors. This report contains progress of research on the Alkali Metal Thermal-to-Electric Converter (AMTEC) and on the Two-Phase Liquid-Metal MHD Electrical Generator (LMMHD) for the period January 1, 1991 through December 31, 1991. Research on AMTEC and on LMMHD was initiated during October 1987. Reports prepared on previous occasions (Refs. 1--5) contain descriptive and performance discussions of the following direct conversion concepts: thermoelectric, pyroelectric, thermionic, thermophotovoltaic, thermoacoustic, thermomagnetic, thermoelastic (Nitionol heat engine); and also, more complete descriptive discussions of AMTEC and LMMHD systems.

  7. Direct Conversion Technology

    SciTech Connect (OSTI)

    Back, L.H.; Fabris, G.; Ryan, M.A.

    1992-07-01

    The overall objective of the Direct Conversion Technology task is to develop an experimentally verified technology base for promising direct conversion systems that have potential application for energy conservation in the end-use sectors. Initially, two systems were selected for exploratory research and advanced development. These are Alkali Metal Thermal-to-Electric Converter (AMTEC) and Two-Phase Liquid Metal MD Generator (LMMHD). This report describes progress that has been made during the first six months of 1992 on research activities associated with these two systems. (GHH)

  8. Integrating remediation and resource recovery: On the economic conditions of landfill mining

    SciTech Connect (OSTI)

    Frändegård, Per Krook, Joakim; Svensson, Niclas

    2015-08-15

    Highlights: • We compare two remediation scenarios; one with resource recovery and one without. • Economic analysis includes relevant direct costs and revenues for the landfill owner. • High degrees of metal and/or combustible contents are important economic factors. • Landfill tax and the access to a CHP can have a large impact on the result. • Combining landfill mining and remediation may decrease the project cost. - Abstract: This article analyzes the economic potential of integrating material separation and resource recovery into a landfill remediation project, and discusses the result and the largest impact factors. The analysis is done using a direct costs/revenues approach and the stochastic uncertainties are handled using Monte Carlo simulation. Two remediation scenarios are applied to a hypothetical landfill. One scenario includes only remediation, while the second scenario adds resource recovery to the remediation project. Moreover, the second scenario is divided into two cases, case A and B. In case A, the landfill tax needs to be paid for re-deposited material and the landfill holder does not own a combined heat and power plant (CHP), which leads to disposal costs in the form of gate fees. In case B, the landfill tax is waived on the re-deposited material and the landfill holder owns its own CHP. Results show that the remediation project in the first scenario costs about €23/ton. Adding resource recovery as in case A worsens the result to −€36/ton, while for case B the result improves to −€14/ton. This shows the importance of landfill tax and the access to a CHP. Other important factors for the result are the material composition in the landfill, the efficiency of the separation technology used, and the price of the saleable material.

  9. Ocean thermal energy conversion

    SciTech Connect (OSTI)

    Avery, W.H.

    1983-03-17

    A brief explanation of the Ocean Thermal Energy Conversion (OTEC) concept and an estimate of the amount of energy that can be produced from the ocean resource without introducing environmental concerns are presented. Use of the OTEC system to generate electric power and products which can replace fossil fuels is shown. The OTEC program status and its prospects for the future are discussed.

  10. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydroelectric, Landfill Gas, Wind (Small), Hydroelectric (Small), Fuel Cells using Renewable Fuels, Microturbines Energy Conversion and Thermal Efficiency Sales Tax Exemption...

  11. Monitoring the Performance of an Alternative Landfill Cover at the Monticello, Utah, Uranium Mill Tailings Disposal Site

    Broader source: Energy.gov [DOE]

    Monitoring the Performance of an Alternative Landfill Cover at the Monticello, Utah, Uranium Mill Tailings Disposal Site

  12. Appendix B Landfill Inspection Forms and Survey Data

    Office of Legacy Management (LM)

    This page intentionally left blank This page intentionally left blank Rocky Flats Site Original Landfill - Settlement Plates Monitoring Quarterly Survey March 26, 2010 Comparison to Previous Survey December 15, 2009 03-26-10 OBSERVATIONS DELTA DELTA DELTA 12-15-09 OBSERVATIONS POINT NUMBER NORTHING EASTING ELEVATION DESCRIPTION NORTHING EASTING ELEVATION POINT NUMBER NORTHING EASTING ELEVATION DESCRIPTION 15053 747913.6883 2082233.082 6005.91 N-RIM-PIPE-AA 0.00 -0.02 -0.02 76527 747913.6913

  13. Superfund Record of Decision (EPA Region 3): Moyer Landfill Site, Collegeville, Pennsylvania, September 1985. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-09-30

    The Moyer Landfill is an inactive privately owned landfill located in Lower Providence Township in Montgomery County, Pennsylvania. The site was operated as a municipal landfill from the 1940's until April 1981, during which time it received municipal refuse and sewage sludges. According to local Federal Bureau of Investigation (FBI) officials, the landfill accepted a variety of solid and liquid hazardous wastes, including polychlorinated biphenyls (PCBs), solvents, paints, low-level radioactive wastes, and incinerated materials in bulk form and/or containerized in drums. In 1972, when the Pennsylvania Dept. of Environmental Resources (PADER) rules and regulations became more restrictive, this landfill was cited, and finally in 1981, it was closed and brought into receivership of the U.S. District Court.

  14. Wind energy conversion system

    DOE Patents [OSTI]

    Longrigg, Paul

    1987-01-01

    The wind energy conversion system includes a wind machine having a propeller connected to a generator of electric power, the propeller rotating the generator in response to force of an incident wind. The generator converts the power of the wind to electric power for use by an electric load. Circuitry for varying the duty factor of the generator output power is connected between the generator and the load to thereby alter a loading of the generator and the propeller by the electric load. Wind speed is sensed electro-optically to provide data of wind speed upwind of the propeller, to thereby permit tip speed ratio circuitry to operate the power control circuitry and thereby optimize the tip speed ratio by varying the loading of the propeller. Accordingly, the efficiency of the wind energy conversion system is maximized.

  15. Research Overview | Solid State Solar Thermal Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Overview Despite great progress in developing efficient thermal energy conversion technologies since the industrial revolution, heat-to-electricity conversion has been primarily based on thermal-mechanical systems such as steam and gas turbines and internal combustion engines. Such engines are most suitable for power generation at large scales with high power density energy sources, but their efficiency suffers when they are used for small-scale installations with low power density

  16. Coal combustion waste management at landfills and surface impoundments 1994-2004.

    SciTech Connect (OSTI)

    Elcock, D.; Ranek, N. L.; Environmental Science Division

    2006-09-08

    On May 22, 2000, as required by Congress in its 1980 Amendments to the Resource Conservation and Recovery Act (RCRA), the U.S. Environmental Protection Agency (EPA) issued a Regulatory Determination on Wastes from the Combustion of Fossil Fuels. On the basis of information contained in its 1999 Report to Congress: Wastes from the Combustion of Fossil Fuels, the EPA concluded that coal combustion wastes (CCWs), also known as coal combustion by-products (CCBs), did not warrant regulation under Subtitle C of RCRA, and it retained the existing hazardous waste exemption for these materials under RCRA Section 3001(b)(3)(C). However, the EPA also determined that national regulations under Subtitle D of RCRA were warranted for CCWs that are disposed of in landfills or surface impoundments. The EPA made this determination in part on the basis of its findings that 'present disposal practices are such that, in 1995, these wastes were being managed in 40 percent to 70 percent of landfills and surface impoundments without reasonable controls in place, particularly in the area of groundwater monitoring; and while there have been substantive improvements in state regulatory programs, we have also identified gaps in State oversight' (EPA 2000). The 1999 Report to Congress (RTC), however, may not have reflected the changes in CCW disposal practices that occurred since the cutoff date (1995) of its database and subsequent developments. The U.S. Department of Energy (DOE) and the EPA discussed this issue and decided to conduct a joint DOE/EPA study to collect new information on the recent CCW management practices by the power industry. It was agreed that such information would provide a perspective on the chronological adoption of control measures in CCW units based on State regulations. A team of experts from the EPA, industry, and DOE (with support from Argonne National Laboratory) was established to develop a mutually acceptable approach for collecting and analyzing data on CCW disposal practices and State regulatory requirements at landfills and surface impoundments that were permitted, built, or laterally expanded between January 1, 1994, and December 31, 2004. The scope of the study excluded waste units that manage CCWs in active or abandoned coal mines. The EPA identified the following three areas of interest: (1) Recent and current CCW industry surface disposal management practices, (2) State regulatory requirements for CCW management, and (3) Implementation of State requirements (i.e., the extent to which States grant or deny operator requests to waive or vary regulatory requirements and the rationales for doing so). DOE and the EPA obtained data on recent and current disposal practices from a questionnaire that the Utility Solid Waste Activities Group (USWAG) distributed to its members that own or operate coal-fired power plants. USWAG, formed in 1978, is responsible for addressing solid and hazardous waste issues on behalf of the utility industry. It is an informal consortium of approximately 80 utility operating companies, the Edison Electric Institute (EEI), the National Rural Electric Cooperative Association (NRECA), the American Public Power Association (APPA), and the American Gas Association (AGA). EEI is the principal national association of investor-owned electric power and light companies. NRECA is the national association of rural electric cooperatives. APPA is the national association of publicly owned electric utilities. AGA is the national association of natural gas utilities. Together, USWAG member companies and trade associations represent more than 85% of the total electric generating capacity of the United States and service more than 95% of the nation's consumers of electricity. To verify the survey findings, the EPA also asked State regulators from nine selected States that are leading consumers of coal for electricity generation for information on disposal units that may not have been covered in the USWAG survey. The selected States were Georgia, Illinois, Indiana, Michigan, Missouri, North Carolina, North Da

  17. TDR calibration for the alternative landfill cover demonstration (ALCD)

    SciTech Connect (OSTI)

    Lopez, J.; Dwyer, S.F.; Swanson, J.N.

    1997-09-01

    The Alternative Landfill Cover Demonstration is a large scale field test that compares the performance of various landfill cover designs in dry environments. An important component of the comparison is the change in the moisture content of the soils throughout the different cover test plots. Time Domain Reflectometry (TDR) is the primary method for the measurement of the volumetric moisture content. Each of the covers is composed of layers of varying types and densities of soils. The probes are therefore calibrated to calculate the volumetric moisture content in each of the different soils in order to gain the optimum performance of the TDR system. The demonstration plots are constructed in two phases; a different probe is used in each phase. The probe that is used in Phase 1 is calibrated for the following soils: compacted native soil, uncompacted native soil, compacted native soil mixed with 6% sodium bentonite by weight, and sand. The probe that is used in Phase 2 is calibrated for the following soils: compacted native soil, uncompacted native soil, and sand. In addition, the probes are calibrated for the varying cable lengths of the TDR probes. The resulting empirically derived equations allow for the calculation of in-situ volumetric moisture content of all of the varying soils throughout the cover test plots in the demonstration.

  18. Conversion of Questionnaire Data

    SciTech Connect (OSTI)

    Powell, Danny H; Elwood Jr, Robert H

    2011-01-01

    During the survey, respondents are asked to provide qualitative answers (well, adequate, needs improvement) on how well material control and accountability (MC&A) functions are being performed. These responses can be used to develop failure probabilities for basic events performed during routine operation of the MC&A systems. The failure frequencies for individual events may be used to estimate total system effectiveness using a fault tree in a probabilistic risk analysis (PRA). Numeric risk values are required for the PRA fault tree calculations that are performed to evaluate system effectiveness. So, the performance ratings in the questionnaire must be converted to relative risk values for all of the basic MC&A tasks performed in the facility. If a specific material protection, control, and accountability (MPC&A) task is being performed at the 'perfect' level, the task is considered to have a near zero risk of failure. If the task is performed at a less than perfect level, the deficiency in performance represents some risk of failure for the event. As the degree of deficiency in performance increases, the risk of failure increases. If a task that should be performed is not being performed, that task is in a state of failure. The failure probabilities of all basic events contribute to the total system risk. Conversion of questionnaire MPC&A system performance data to numeric values is a separate function from the process of completing the questionnaire. When specific questions in the questionnaire are answered, the focus is on correctly assessing and reporting, in an adjectival manner, the actual performance of the related MC&A function. Prior to conversion, consideration should not be given to the numeric value that will be assigned during the conversion process. In the conversion process, adjectival responses to questions on system performance are quantified based on a log normal scale typically used in human error analysis (see A.D. Swain and H.E. Guttmann, 'Handbook of Human Reliability Analysis with Emphasis on Nuclear Power Plant Applications,' NUREG/CR-1278). This conversion produces the basic event risk of failure values required for the fault tree calculations. The fault tree is a deductive logic structure that corresponds to the operational nuclear MC&A system at a nuclear facility. The conventional Delphi process is a time-honored approach commonly used in the risk assessment field to extract numerical values for the failure rates of actions or activities when statistically significant data is absent.

  19. Thermochemical Conversion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion Thermochemical Conversion The Bioenergy Technologies Office conducts research on heat-, pressure-, and catalyst-based conversion of various biomass feedstocks to biofuels, chemicals, and power. These conversion processes, most notably fast pyrolysis (as well as other forms of direct liquefaction) and gasification, are described in detail in the links on the left. The Thermochemical Platform aims to efficiently produce biobased fuels and co-products via liquefaction and pyrolysis,

  20. Conversion | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Conversion A key starting point for material management and minimization is reducing the civilian use of and demands for weapon-grade nuclear material. The Office of Conversion works around the world to convert, or verify the shutdown of, civilian research and test reactors that use or produce weapons-usable nuclear material to materials not of proliferation concern. In support of this, the Office of Conversion works to develop and qualify new fuels and technologies to support conversion efforts

  1. Feasibility Study of Economics and Performance of Solar Photovoltaics at the Refuse Hideaway Landfill in Middleton, Wisconsin

    SciTech Connect (OSTI)

    Salasovich, J.; Mosey, G.

    2011-08-01

    This report presents the results of an assessment of the technical and economic feasibility of deploying a photovoltaics (PV) system on a brownfield site at the Refuse Hideaway Landfill in Middleton, Wisconsin. The site currently has a PV system in place and was assessed for further PV installations. The cost, performance, and site impacts of different PV options were estimated. The economics of the potential systems were analyzed using an electric rate of $0.1333/kWh and incentives offered by the State of Wisconsin and by the serving utility, Madison Gas and Electric. According to the site production calculations, the most cost-effective system in terms of return on investment is the thin-film fixed-tilt technology. The report recommends financing options that could assist in the implementation of such a system.

  2. Certification report for final closure of Y-12 Centralized Sanitary Landfill II, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    1995-12-31

    This report represents the Geotek Engineering Company, Inc., (Geotek) record of activities to support certification of final closure Of the subject Y-12 Centralized Sanitary Landfill II. Ex as noted herein, final closure of the landfill was completed in accordance with the Y-12 Centralized Sanitary Landfill 11 Closure/Post Closure Plan, Revision 2, submitted by the US Department of Energy (DOE) to the Tennessee Department of Environment and Conservation (TDEC) on April 14, 1992, and approved by TDEC on May 27, 1994 (the ``Closure Plan``). minor modification to the Closure Plan allowing partial closure of the Y-12 Centralized Sanitary Landfill II (Phase 1) was approved by TDEC on August 3, 1994. The Phase I portion of the closure for the subject landfill was completed on March 25, 1995. A closure certification report entitled Certification Report for Partial Closure of Y-12 Centralized Sanitary Landfill II was submitted to Lockheed Martin Energy Systems, Inc., (LMES) on March 28, 1995. The final closure represents the completion of the closure activities for the entire Y-12 Centralized Sanitary Landfill II Site. The contents of this report and accompanying certification are based on observations by Geotek engineers and geologists during closure activities and on review of reports, records, laboratory test results, and other information furnished to Geotek by LMES.

  3. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi

    1997-01-01

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate .alpha.-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal.

  4. Zinc phosphate conversion coatings

    DOE Patents [OSTI]

    Sugama, T.

    1997-02-18

    Zinc phosphate conversion coatings for producing metals which exhibit enhanced corrosion prevention characteristics are prepared by the addition of a transition-metal-compound promoter comprising a manganese, iron, cobalt, nickel, or copper compound and an electrolyte such as polyacrylic acid, polymethacrylic acid, polyitaconic acid and poly-L-glutamic acid to a phosphating solution. These coatings are further improved by the incorporation of Fe ions. Thermal treatment of zinc phosphate coatings to generate {alpha}-phase anhydrous zinc phosphate improves the corrosion prevention qualities of the resulting coated metal. 33 figs.

  5. Unconventional gas outlook: resources, economics, and technologies

    SciTech Connect (OSTI)

    Drazga, B.

    2006-08-15

    The report explains the current and potential of the unconventional gas market including country profiles, major project case studies, and new technology research. It identifies the major players in the market and reports their current and forecasted projects, as well as current volume and anticipated output for specific projects. Contents are: Overview of unconventional gas; Global natural gas market; Drivers of unconventional gas sources; Forecast; Types of unconventional gas; Major producing regions Overall market trends; Production technology research; Economics of unconventional gas production; Barriers and challenges; Key regions: Australia, Canada, China, Russia, Ukraine, United Kingdom, United States; Major Projects; Industry Initiatives; Major players. Uneconomic or marginally economic resources such as tight (low permeability) sandstones, shale gas, and coalbed methane are considered unconventional. However, due to continued research and favorable gas prices, many previously uneconomic or marginally economic gas resources are now economically viable, and may not be considered unconventional by some companies. Unconventional gas resources are geologically distinct in that conventional gas resources are buoyancy-driven deposits, occurring as discrete accumulations in structural or stratigraphic traps, whereas unconventional gas resources are generally not buoyancy-driven deposits. The unconventional natural gas category (CAM, gas shales, tight sands, and landfill) is expected to continue at double-digit growth levels in the near term. Until 2008, demand for unconventional natural gas is likely to increase at an AAR corresponding to 10.7% from 2003, aided by prioritized research and development efforts. 1 app.

  6. Limited site investigation of Landfills 1 and 4, Fort Lewis, Washington

    SciTech Connect (OSTI)

    Last, G.V.; Eddy, P.A.; Airhart, S.P.; Olsen, K.R.; Raymond, J.R.; Dahl, D.R.

    1990-08-01

    The information presented in this report was collected during limited site investigation activities conducted in the vicinity of Landfills 1 and 4 at Fort Lewis. The purpose of this work was to provide a means of detecting and evaluating the impacts of these inactive landfills on ground-water quality and adjacent lands. This effort included the design and construction of ground-water monitoring systems for compliance with applicable federal and state regulations governing Resource Conservation and Recovery Act (RCRA)-type landfills. Ground-water samples were collected from both existing (1981 and 1984) wells and the newly installed (1988) wells. The analytical results from the water samples indicate that the ground water in and around Landfill 1 contains limited contamination. Contaminants may include volatile organic compounds and nitrate. The primary concern in the area around Landfill 1 was the determination that ground water from two wells may contain cis-1,2-dichloroethylene and 1,1,1-trichloroethylene above drinking water standards. Nitrate levels in the downgradient wells were greater than those in upgradient wells and exceeded drinking water standards in some of the less-representative samples. Analyses of ground-water samples from wells in and around Landfill 4 indicate several contaminants may be present. These include volatile organic compounds (principally cis-1,2-dichloroethylene and 1,1,1-trichloroethylene), coliform, oil and grease, and perhaps some metals (iron and magnesium). The primary concern in the area around Landfill 4 was the determination that ground water from five wells contained cis-1,2-dichloroethylene and 1,1,1-trichloroethylene above drinking water standards. The source of contaminants beneath either landfill cannot yet be identified. Insufficient data exist to disprove or confirm either landfill as possible contributors. 19 refs., 32 figs., 17 tabs.

  7. Atlantic Biomass Conversions Inc | Open Energy Information

    Open Energy Info (EERE)

    Biomass Conversions Inc Jump to: navigation, search Name: Atlantic Biomass Conversions Inc Place: Frederick, Maryland Sector: Biomass Product: Atlantic Biomass Conversions is...

  8. Energy conversion system

    DOE Patents [OSTI]

    Murphy, Lawrence M.

    1987-01-01

    The energy conversion system includes a photo-voltaic array for receiving solar radiation and converting such radiation to electrical energy. The photo-voltaic array is mounted on a stretched membrane that is held by a frame. Tracking means for orienting the photo-voltaic array in predetermined positions that provide optimal exposure to solar radiation cooperate with the frame. An enclosure formed of a radiation transmissible material includes an inside containment space that accommodates the photo-voltaic array on the stretched membrane, the frame and the tracking means, and forms a protective shield for all such components. The enclosure is preferably formed of a flexible inflatable material and maintains its preferred form, such as a dome, under the influence of a low air pressure furnished to the dome. Under this arrangement the energy conversion system is streamlined for minimizing wind resistance, sufficiently weatherproof for providing protection against weather hazards such as hail, capable of using diffused light, lightweight for low-cost construction, and operational with a minimal power draw.

  9. Energy conversion system

    DOE Patents [OSTI]

    Murphy, L.M.

    1985-09-16

    The energy conversion system includes a photo-voltaic array for receiving solar radiation and converting such radiation to electrical energy. The photo-voltaic array is mounted on a stretched membrane that is held by a frame. Tracking means for orienting the photo-voltaic array in predetermined positions that provide optimal exposure to solar radiation cooperate with the frame. An enclosure formed of a radiation transmissible material includes an inside containment space that accommodates the photo-voltaic array on the stretched membrane, the frame and the tracking means, and forms a protective shield for all such components. The enclosure is preferably formed of a flexible inflatable material and maintains its preferred form, such as a dome, under the influence of a low air pressure furnished to the dome. Under this arrangement the energy conversion system is streamlined for minimizing wind resistance, sufficiently weathproof for providing protection against weather hazards such as hail, capable of using diffused light, lightweight for low-cost construction and operational with a minimal power draw.

  10. Comparison of emissions from landfills, municipal waste combustors, and fossil fuel-fired utilities

    SciTech Connect (OSTI)

    1996-11-01

    Landfilling is the most popular disposal method for managing municipal solid waste (MSW). However, air emissions from MSW landfills have generally been unregulated until recently. Instead, EPA has focused on emissions from municipal waste combustors (MWCs), even though they only manage 15% of MSW generated in the United States. In the past, little data have been available comparing landfill and MWC air emissions. Such information is provided by this paper. It also compares emissions from waste-to-energy MWCs and fossil fuel-fired utilities with equivalent electrical generation capacity. 1 refs., 6 tabs.

  11. Corrective action investigation plan for CAU Number 453: Area 9 Landfill, Tonopah Test Range

    SciTech Connect (OSTI)

    1997-05-14

    This Corrective Action Investigation Plan (CAIP) contains the environmental sample collection objectives and criteria for conducting site investigation activities at the Area 9 Landfill, Corrective Action Unit (CAU) 453/Corrective Action (CAS) 09-55-001-0952, which is located at the Tonopah Test Range (TTR). The TTR, included in the Nellis Air Force Range, is approximately 255 kilometers (140 miles) northwest of Las Vegas, Nevada. The Area 9 Landfill is located northwest of Area 9 on the TTR. The landfill cells associated with CAU 453 were excavated to receive waste generated from the daily operations conducted at Area 9 and from range cleanup which occurred after test activities.

  12. Construction and operation of an industrial solid waste landfill at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    SciTech Connect (OSTI)

    1995-10-01

    The US Department of Energy (DOE), Office of Waste Management, proposes to construct and operate a solid waste landfill within the boundary of the Portsmouth Gaseous Diffusion Plant (PORTS), Piketon, Ohio. The purpose of the proposed action is to provide PORTS with additional landfill capacity for non-hazardous and asbestos wastes. The proposed action is needed to support continued operation of PORTS, which generates non-hazardous wastes on a daily basis and asbestos wastes intermittently. Three alternatives are evaluated in this environmental assessment (EA): the proposed action (construction and operation of the X-737 landfill), no-action, and offsite shipment of industrial solid wastes for disposal.

  13. Carbon aerogel electrodes for direct energy conversion

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Kaschmitter, James L. (Pleasanton, CA); Pekala, Richard W. (Pleasant Hill, CA)

    1997-01-01

    A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome.

  14. Carbon aerogel electrodes for direct energy conversion

    DOE Patents [OSTI]

    Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

    1997-02-11

    A direct energy conversion device, such as a fuel cell, using carbon aerogel electrodes is described, wherein the carbon aerogel is loaded with a noble catalyst, such as platinum or rhodium and soaked with phosphoric acid, for example. A separator is located between the electrodes, which are placed in a cylinder having plate current collectors positioned adjacent the electrodes and connected to a power supply, and a pair of gas manifolds, containing hydrogen and oxygen positioned adjacent the current collectors. Due to the high surface area and excellent electrical conductivity of carbon aerogels, the problems relative to high polarization resistance of carbon composite electrodes conventionally used in fuel cells are overcome. 1 fig.

  15. Greenhouse Gas Source Attribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gas Source Attribution - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  16. Gyroharmonic conversion experiments

    SciTech Connect (OSTI)

    Hirshfield, J.L.; LaPointe, M.A.; Ganguly, A.K. [Omega-P, Inc., New Haven, Connecticut 06520 (United States); LaPointe, M.A. [Yale University, New Haven, Connecticut 06511 (United States)

    1999-05-01

    Generation of high power microwaves has been observed in experiments where a 250{endash}350 kV, 20{endash}30 A electron beam accelerated in a cyclotron autoresonance accelerator (CARA) passes through a cavity tuned gyroharmonic) and at 8.6 GHz (3rd harmonic) will be described. Theory indicates that high conversion efficiency can be obtained for a high quality beam injected into CARA, and when mode competition can be controlled. Comparisons will be made between the experiments and theory. Planned 7th harmonic experiments will also be described, in which phase matching between the TE-72 mode at 20 GHz, and the TE-11 mode at 2.86 GHz, allows efficient 20 GHz co-generation within the CARA waveguide itself. {copyright} {ital 1999 American Institute of Physics.}

  17. Gyroharmonic conversion experiments

    SciTech Connect (OSTI)

    Hirshfield, J. L.; LaPointe, M. A. [Omega-P, Inc., New Haven, Connecticut 06520 (United States); Yale University, New Haven, Connecticut 06511 (United States); Ganguly, A. K. [Omega-P, Inc., New Haven, Connecticut 06520 (United States)

    1999-05-07

    Generation of high power microwaves has been observed in experiments where a 250-350 kV, 20-30 A electron beam accelerated in a cyclotron autoresonance accelerator (CARA) passes through a cavity tuned gyroharmonic) and at 8.6 GHz (3rd harmonic) will be described. Theory indicates that high conversion efficiency can be obtained for a high quality beam injected into CARA, and when mode competition can be controlled. Comparisons will be made between the experiments and theory. Planned 7th harmonic experiments will also be described, in which phase matching between the TE-72 mode at 20 GHz, and the TE-11 mode at 2.86 GHz, allows efficient 20 GHz co-generation within the CARA waveguide itself.

  18. Solar Thermoelectric Energy Conversion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Thermoelectric Energy Conversion Solar Thermoelectric Energy Conversion Efficiencies of different types of solar thermoelectric generators were predicted using theoretical ...

  19. Conversion Technologies for Advanced Biofuels - Carbohydrates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon ctabwebinarcarbohydratesupgrading.pdf More Documents & Publications Conversion Technologies for Advanced Biofuels - Carbohydrates Production Advanced Conversion Roadmap ...

  20. Conversion Technologies for Advanced Biofuels - Carbohydrates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon ctabwebinarcarbohydratesproduction.pdf More Documents & Publications Advanced Conversion Roadmap Workshop Workshop on Conversion Technologies for Advanced Biofuels - ...

  1. Field measurements of frost penetration into a landfill cover that uses a paper sludge barrier

    SciTech Connect (OSTI)

    Moo-Young, H.K.; LaPlante, C.; Zimmie, T.F.; Quiroz, J.

    1999-07-01

    Frost penetration is a major environmental concern in landfill design. Freezing and thawing cycles may deteriorate the permeability of the liner or cap. In this study, the depth of frost penetration into a landfill cover that uses paper sludge as the impermeable barrier (the Hubbardston landfill in Massachusetts) was measured using a frost measurement system. A thermistor probe measured the temperature at various depths. Although temperature measurements are important, soil resistivity measurements are required to accurately predict the freezing level, since soil resistivity increases greatly upon freezing. A conductivity probe measured the half-bridge voltage between conductivity rings and a ground rod. Data were collected in data loggers. The data collected from 1992--1996 showed that the frost level did not penetrate the paper sludge capping layer. Heavy snow cover throughout the winters decreased the depth of frost penetration by insulating the landfill. The high water content in the sludge also contributed to the lack of freezing.

  2. Corrective action investigation plan for CAU No. 424: Area 3 Landfill Complex, Tonopah Test Range, Nevada

    SciTech Connect (OSTI)

    1997-04-01

    This Correction Action Investigation Plan contains the environmental sample collection objectives and the criteria for conducting site investigation activities at the Area 3 Landfill Complex, CAU No. 424, which is located at the Tonopah Test Range (TTR). The TTR, included in the Nellis Air Force Range, is approximately 255 kilometers (140 miles) northwest of Las Vegas, nevada. The CAU 424 is comprised of eight individual landfill sites that are located around and within the perimeter of the Area 3 Compound. Due to the unregulated disposal activities commonly associated with early landfill operations, an investigation will be conducted at each CAS to complete the following tasks: identify the presence and nature of possible contaminant migration from the landfills; determine the vertical and lateral extent of possible contaminant migration; ascertain the potential impact to human health and the environment; and provide sufficient information and data to develop and evaluate appropriate corrective action strategies for each CAS.

  3. Support EM LA Airport Landfill Cover Project by providing 40000 tons of soil

    Broader source: Energy.gov [DOE]

    The purpose of this task order (TO) is to support the EM-LA Field Office in replacing the cover at the Los Alamos County Airport Landfill. The new cover design is an evapotranspiration (ET) cover.

  4. Ground-water monitoring compliance plan for the Hanford Site Solid Waste Landfill

    SciTech Connect (OSTI)

    Fruland, R.M.

    1986-10-01

    Washington state regulations required that solid waste landfill facilities have ground-water monitoring programs in place by May 27, 1987. This document describes the well locations, installation, characterization studies and sampling and analysis plan to be followed in implementing the ground-water monitoring program at the Hanford Site Solid Waste Landfill (SWL). It is based on Washington Administrative Code WAC 173-304-490. 11 refs., 19 figs., 4 tabs.

  5. SPECIAL REPORT Allegations Regarding the Sandia National Laboratories Mixed Waste Landfill

    Energy Savers [EERE]

    Regarding the Sandia National Laboratories Mixed Waste Landfill OAI-SR-16-01 February 2016 U.S. Department of Energy Office of Inspector General Office of Audits and Inspections Department of Energy Washington, DC 20585 February 18, 2016 MEMORANDUM FOR THE MANAGER, SANDIA FIELD OFFICE FROM: David Sedillo, Director Western Audits Division Office of Inspector General SUBJECT: INFORMATION: Special Report on the "Allegations Regarding the Sandia National Laboratories Mixed Waste Landfill"

  6. Trends in Contractor Conversion Rates

    Broader source: Energy.gov [DOE]

    Better Buildings Residential Network Workforce / Business Partners Peer Exchange Call Series: Trends in Contractor Conversion Rates, Call Slides and Discussion Summary, December 5, 2013.

  7. Feasibility Study of Economics and Performance of Solar Photovoltaics at Johnson County Landfill

    SciTech Connect (OSTI)

    Salasovich, J.; Mosey, G.

    2012-01-01

    The U.S. Environmental Protection Agency (EPA), in accordance with the RE-Powering America's Land initiative, selected the Johnson County Landfill in Shawnee, Kansas, for a feasibility study of renewable energy production. Citizens of Shawnee, city planners, and site managers are interested in redevelopment uses for landfills in Kansas that are particularly well suited for grid-tied solar photovoltaic (PV) installation. This report assesses the Johnson County Landfill for possible grid-tied PV installations and estimates the cost, performance, and site impacts of three different PV options: crystalline silicon (fixed tilt), crystalline silicon (single-axis tracking), and thin film (fixed tilt). Each option represents a standalone system that can be sized to use an entire available site area. In addition, the report outlines financing options that could assist in the implementation of a system. The feasibility of PV systems installed on landfills is highly impacted by the available area for an array, solar resource, operating status, landfill cap status, distance to transmission lines, and distance to major roads. The report findings are applicable to other landfills in the surrounding area.

  8. Cost savings associated with landfilling wastes containing very low levels of uranium

    SciTech Connect (OSTI)

    Boggs, C.J.; Shaddoan, W.T.

    1996-03-01

    The Paducah Gaseous Diffusion Plant (PGDP) has operated captive landfills (both residential and construction/demolition debris) in accordance with the Commonwealth of Kentucky regulations since the early 1980s. Typical waste streams allowed in these landfills include nonhazardous industrial and municipal solid waste (such as paper, plastic, cardboard, cafeteria waste, clothing, wood, asbestos, fly ash, metals, and construction debris). In July 1992, the U.S. Environmental Protection Agency issued new requirements for the disposal of sanitary wastes in a {open_quotes}contained landfill.{close_quotes} These requirements were promulgated in the 401 Kentucky Administrative Record Chapters 47 and 48 that became effective 30 June 1995. The requirements for a new contained landfill include a synthetic liner made of high-density polyethylene in addition to the traditional 1-meter (3-foot) clay liner and a leachate collection system. A new landfill at Paducah would accept waste streams similar to those that have been accepted in the past. The permit for the previously existing landfills did not include radioactivity limits; instead, these levels were administratively controlled. Typically, if radioactivity was detected above background levels, the waste was classified as low-level waste (LLW), which would be sent off-site for disposal.

  9. PDB to AMPL Conversion

    Energy Science and Technology Software Center (OSTI)

    2002-09-01

    PDB to AMPL Conversion was written to convert protein data base files to AMPL files. The protein data bases on the internet contain a wealth of information about the structue and makeup of proteins. Each file contains information derived by one or more experiments and contains information on how the experiment waw performed, the amino acid building blocks of each chain, and often the three-dimensional structure of the protein extracted from the experiments. The waymore » a protein folds determines much about its function. Thus, studying the three-dimensional structure of the protein is of great interest. Analysing the contact maps is one way to examine the structure. A contact map is a graph which has a linear back bone of amino acids for nodes (i.e., adjacent amino acids are always connected) and vertices between non-adjacent nodes if they are close enough to be considered in contact. If the graphs are similar then the folds of the protein and their function should also be similar. This software extracts the contact maps from a protein data base file and puts in into AMPL data format. This format is designed for use in AMPL, a programming language for simplifying linear programming formulations.« less

  10. Static Scale Conversion (SSC)

    Energy Science and Technology Software Center (OSTI)

    2007-01-19

    The Static Scale Conversion (SSC) software is a unique enhancement to the AIMVEE system. It enables a SSC to weigh and measure vehicles and cargo dynamically (i.e., as they pass over the large scale. Included in the software is the AIMVEE computer code base. The SSC and AIMVEE computer system electronically continue to retrieve deployment information, identify vehicle automatically and determine total weight, individual axle weights, axle spacing and center-of-balance for any wheeled vehicle inmore » motion. The AIMVEE computer code system can also perform these functions statically for both wheel vehicles and cargo with information. The AIMVEE computer code system incorporates digital images and applies cubing algorithms to determine length, width, height for cubic dimensions of both vehicle and cargo. Once all this information is stored, it electronically links to data collection and dissemination systems to provide “actual” weight and measurement information for planning, deployment, and in-transit visibility.« less

  11. Automotive Fuel Efficiency Improvement via Exhaust Gas Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Electricity Automotive Fuel Efficiency Improvement via Exhaust Gas Waste Heat Conversion to Electricity Working to expand the usage of thermoelectric technology beyond seat ...

  12. Multiple-Reheat Brayton Cycles for Nuclear Power Conversion with Molten

    Office of Scientific and Technical Information (OSTI)

    Coolants (Journal Article) | SciTech Connect Journal Article: Multiple-Reheat Brayton Cycles for Nuclear Power Conversion with Molten Coolants Citation Details In-Document Search Title: Multiple-Reheat Brayton Cycles for Nuclear Power Conversion with Molten Coolants Gas-turbine power conversion systems can have lower capital costs than comparable steam-turbine systems due to their higher power density. The recent commercialization of magnetic bearing systems for large turbomachinery now

  13. Study of the VOC emissions from a municipal solid waste storage pilot-scale cell: Comparison with biogases from municipal waste landfill site

    SciTech Connect (OSTI)

    Chiriac, R.; De Araujos Morais, J.; Carre, J.; Bayard, R.; Chovelon, J.M.; Gourdon, R.

    2011-11-15

    Highlights: > Follow-up of the emission of VOCs in a municipal waste pilot-scale cell during the acidogenesis and acetogenesis phases. > Study from the very start of waste storage leading to a better understanding of the decomposition/degradation of waste. > Comparison of the results obtained on the pilot-scale cell with those from 3 biogases coming from the same landfill site. > A methodology of characterization for the progression of the stabilization/maturation of waste is finally proposed. - Abstract: The emission of volatile organic compounds (VOCs) from municipal solid waste stored in a pilot-scale cell containing 6.4 tonnes of waste (storage facility which is left open during the first period (40 days) and then closed with recirculation of leachates during a second period (100 days)) was followed by dynamic sampling on activated carbon and analysed by GC-MS after solvent extraction. This was done in order to know the VOC emissions before the installation of a methanogenesis process for the entire waste mass. The results, expressed in reference to toluene, were exploited during the whole study on all the analyzable VOCs: alcohols, ketones and esters, alkanes, benzenic and cyclic compounds, chlorinated compounds, terpene, and organic sulphides. The results of this study on the pilot-scale cell are then compared with those concerning three biogases from a municipal waste landfill: biogas (1) coming from waste cells being filled or recently closed, biogas (2) from all the waste storage cells on site, and biogas (3) which is a residual gas from old storage cells without aspiration of the gas. The analysis of the results obtained revealed: (i) a high emission of VOCs, principally alcohols, ketones and esters during the acidogenesis; (ii) a decrease in the alkane content and an increase in the terpene content were observed in the VOCs emitted during the production of methane; (iii) the production of heavier alkanes and an increase in the average number of carbon atoms per molecule of alkane with the progression of the stabilisation/maturation process were also observed. Previous studies have concentrated almost on the analysis of biogases from landfills. Our research aimed at gaining a more complete understanding of the decomposition/degradation of municipal solid waste by measuring the VOCs emitted from the very start of the landfill process i.e. during the acidogenesis and acetogenesis phases.

  14. SYSTEM FOR CONVERSION OF UF$sub 4$ TO UF$sub 6$

    DOE Patents [OSTI]

    Brater, D.G.; Pike, J.W.

    1958-12-01

    Method and apparatus are presented for rapid and complete conversion of solid, powdered uranium tetrafiuorlde to uranlum hexafluorlde by treating the UF/ sub 4/ with fluorine gas at a temperature of about 800 icient laborato C.

  15. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32...

    Office of Scientific and Technical Information (OSTI)

    Lee, G.T.; Sudhoff, F.A. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; FUEL CELL POWER PLANTS; GAS TURBINE...

  16. Biofuel Conversion Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biofuel Conversion Basics Biofuel Conversion Basics August 14, 2013 - 12:31pm Addthis The conversion of biomass solids into liquid or gaseous biofuels is a complex process. Today, the most common conversion processes are biochemical- and thermochemical-based. However, researchers are also exploring photobiological conversion processes. Biochemical Conversion Processes In biochemical conversion processes, enzymes and microorganisms are used as biocatalysts to convert biomass or biomass-derived

  17. Alternative Fuels Data Center: Vehicle Conversions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Conversions Printable Version Share this resource Send a link to Alternative Fuels Data Center: Vehicle Conversions to someone by E-mail Share Alternative Fuels Data Center: Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Vehicle Conversions on Digg Find More

  18. Alternative Fuels Data Center: Conversion Regulations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Conversion Regulations to someone by E-mail Share Alternative Fuels Data Center: Conversion Regulations on Facebook Tweet about Alternative Fuels Data Center: Conversion Regulations on Twitter Bookmark Alternative Fuels Data Center: Conversion Regulations on Google Bookmark Alternative Fuels Data Center: Conversion Regulations on Delicious Rank Alternative Fuels Data Center: Conversion Regulations on Digg Find More places to share Alternative Fuels Data Center: Conversion Regulations on

  19. Trash processing and recycling using the zero landfill solution

    SciTech Connect (OSTI)

    Thompson, W.J.

    1994-12-31

    Each person in the US produces approximately one ton of trash per year. The environmentally friendly municipal trash processing and recycling complex used for illustrative purposes in this paper is designed and sized to handle trash from typical municipalities ranging from 500,000 to 750,000 populations. This translates into a nominal 2,000 ton per day (TPD) facility. A typical component breakdown of municipal solid waste is shown in appendix A. The layout of the complex is shown in appendix B. Today`s municipal trash processing and recycling center should be designed to serve the needs of the municipality for at least the next 20 to 30 years. It should also be designed in such a way as to allow any new technology advancements to be added easily and in a cost effective manner to extend the useful service life of the facility almost indefinitely. 100% of the trash will be recycled. There will be no need for a dump, landfill, or disposal site at all. No curbside separation is required.

  20. Advanced Conversion Roadmap Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Conversion Roadmap Workshop Advanced Conversion Roadmap Workshop DOE introduction slides to the Advanced Conversion Roadmap Workshop webinar. PDF icon ctab_webinar_doe.pdf More Documents & Publications Conversion Technologies for Advanced Biofuels - Bio-Oil Production Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading 2013 Peer Review Presentations-Bio-oil

  1. One Man's Trash, Another Man's Fuel: BMW Plant Converts Landfill Gas to Hydrogen Fuel

    Broader source: Energy.gov [DOE]

    Supported by the U.S. Department of Energys Office of Energy Efficiency and Renewable Energy (EERE), the BMW manufacturing plant in Greer, South Carolina demonstrated the use of unique source to...

  2. Enzymes for improved biomass conversion

    DOE Patents [OSTI]

    Brunecky, Roman; Himmel, Michael E.

    2016-02-02

    Disclosed herein are enzymes and combinations of the enzymes useful for the hydrolysis of cellulose and the conversion of biomass. Methods of degrading cellulose and biomass using enzymes and cocktails of enzymes are also disclosed.

  3. EPA Redesigns Conversion Certification Policies

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    EPA Redesigns Conversion Certification Policies At a recent meeting held in Washington, DC, officials from the U.S. Environmental Protection Agency (EPA) opened dialogue about proposed changes to its emission certification policies that affect alternative fuel vehicles (AFVs). "We are trying to accommo- date the Energy Policy Act (EPAct) and Executive Order requirements while trying to change enforce- ment policies and guidance with respect to conversions," said Rich Ackerman of EPA's

  4. Exploring the Optimum Role of Natural Gas in Biofuels Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Exploring the Optimum Role of Natural Gas in Biofuels Production Exploring the Optimum Role of Natural Gas in Biofuels Production Breakout Session 1: New Developments and Hot Topics Session 1-D: Natural Gas & Biomass to Liquids Vann Bush, Managing Director, Energy Conversion, Gas Technology Institute PDF icon b13_bush_1-d.pdf More Documents & Publications 2013 Peer Review Presentations-Gasification Bioenergy Technologies Office Conversion R&D Pathway: Syngas

  5. An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors

    SciTech Connect (OSTI)

    Townsend, Aaron K.; Webber, Michael E.

    2012-07-15

    This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.

  6. Alternative Fuels Data Center: Propane Vehicle Conversions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Conversions to someone by E-mail Share Alternative Fuels Data Center: Propane Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Propane Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Propane Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Propane Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Propane Vehicle Conversions on Digg Find More places to share Alternative Fuels Data Center: Propane Vehicle

  7. Alternative Fuels Data Center: Vehicle Conversion Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Vehicle Conversion Basics to someone by E-mail Share Alternative Fuels Data Center: Vehicle Conversion Basics on Facebook Tweet about Alternative Fuels Data Center: Vehicle Conversion Basics on Twitter Bookmark Alternative Fuels Data Center: Vehicle Conversion Basics on Google Bookmark Alternative Fuels Data Center: Vehicle Conversion Basics on Delicious Rank Alternative Fuels Data Center: Vehicle Conversion Basics on Digg Find More places to share Alternative Fuels Data Center: Vehicle

  8. Feasibility Study of Solar Photovoltaics on Landfills in Puerto Rico (Second Study)

    SciTech Connect (OSTI)

    Salasovich, J.; Mosey, G.

    2011-08-01

    This report presents the results of an assessment of the technical and economic feasibility of deploying a solar photovoltaics (PV) system on landfill sites in Puerto Rico. The purpose of this report is to assess the landfills with the highest potential for possible solar PV installation and estimate cost, performance, and site impacts of three different PV options: crystalline silicon (fixed tilt), crystalline silicon (single-axis tracking), and thin film (fixed tilt). The report outlines financing options that could assist in the implementation of a system. According to the site production calculations, the most cost-effective system in terms of return on investment is the thin-film fixed-tilt technology. The report recommends financing options that could assist in the implementation of such a system. The landfills and sites considered in this report were all determined feasible areas in which to implement solar PV systems.

  9. Steam plant ash disposal facility and industrial landfill at the Y-12 Plant, Anderson County, Tennessee

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    The US Department of Energy (DOE) is proposing to install a wet ash handling system to dewater bottom ash from the coal-fired steam plant at its Y-12 Plant and to construct a new landfill for disposal of industrial wastes, including the dewatered bottom ash. The DOE operates three major facilities on its Oak Ridge Reservation (ORR). Operation of these facilities results in the production of a variety of nonhazardous, nonradioactive solid wastes (approximately 300 m{sup 3} per day, compacted) including sanitary wastes, common industrial wastes and construction debris. At the current rate of use, this existing landfill will be filled within approximately 18 months, and more space is urgently needed. In an effort to alleviate this problem, DOE and WMD management propose to create additional landfill facilities at a nearby site. The potential environmental impacts associated with this proposed action are the subject of this environmental assessment (EA).

  10. Conversation with Paul Brown | Open Energy Information

    Open Energy Info (EERE)

    Conversation with Paul Brown Jump to: navigation, search OpenEI Reference LibraryAdd to library Personal Communication: Conversation with Paul Brown Author Paul Brown Recipient...

  11. Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste Heat Recovery Nanostructured High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste ...

  12. thermo-electric power conversion technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thermo-electric power conversion technology - Sandia Energy Energy Search Icon Sandia Home ... Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar ...

  13. Landfill impacts on aquatic plant communities and tissue metal levels at Indiana Dunes National Lakeshore

    SciTech Connect (OSTI)

    Stewart, P.M. [National Biological Service, Porter, IN (United States). Lake Michigan Ecological Station; Scribailo, R.W. [Purdue Univ.North Central, Westville, IN (United States). Section of Biology and Chemistry

    1995-12-31

    One important environmental issue facing Northwest Indiana and park management at Indiana Dunes National Lakeshore (INOU) is the contamination of water, sediment and biota by persistent toxic substances. Aquatic plant communities were used to evaluate the water/organismal quality of the Grand Calumet Lagoons and two dunal ponds (pannes) at Gary, Indiana, which are partially located in the Miller Woods Unit of INDU. The lagoon is divided into several areas, the USX Lagoon is located between sections of a large industrial landfill (steel slag and other material). The Marquette Lagoon is located further away from the landfill and tends to be upgradient from the landfill. The West Panne (WP) is located next to the landfill, while the East Panne (EP) is separated from the landfill and the WP by a high dune ridge. Plant populations shift toward fewer submergent aquatics, with a higher abundance of tolerant taxa in the western section of the USX Lagoon. These differences are supported by cluster analysis. Heavy metals in root tissue of Scirpus americanus and other plant species from the pannes were significantly higher than those found in shoots. Shoot tissue metal levels in plants collected from the lagoons were higher than root tissue metal levels. The WP site has the most elevated tissue metal levels for most metals assayed, while the EP site shows similar contaminant levels. The plant distributions observed and tissue metal concentrations measured suggest that INDU`s aquatic plant community has been affected by the industrial landfill and that there exists a hydrological connection between the ponds.

  14. The Basics of Underground Natural Gas Storage

    U.S. Energy Information Administration (EIA) Indexed Site

    States is in depleted natural gas or oil fields that are close to consumption centers. Conversion of a field from production to storage duty takes advantage of existing wells,...

  15. Systems and methods for measuring a parameter of a landfill including a barrier cap and wireless sensor systems and methods

    DOE Patents [OSTI]

    Kunerth, Dennis C.; Svoboda, John M.; Johnson, James T.

    2007-03-06

    A method of measuring a parameter of a landfill including a cap, without passing wires through the cap, includes burying a sensor apparatus in the landfill prior to closing the landfill with the cap; providing a reader capable of communicating with the sensor apparatus via radio frequency (RF); placing an antenna above the barrier, spaced apart from the sensor apparatus; coupling the antenna to the reader either before or after placing the antenna above the barrier; providing power to the sensor apparatus, via the antenna, by generating a field using the reader; accumulating and storing power in the sensor apparatus; sensing a parameter of the landfill using the sensor apparatus while using power; and transmitting the sensed parameter to the reader via a wireless response signal. A system for measuring a parameter of a landfill is also provided.

  16. Method for direct conversion of gaseous hydrocarbons to liquids

    DOE Patents [OSTI]

    Kong, Peter C.; Lessing, Paul A.

    2006-03-07

    A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.

  17. Enhanced catalyst for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, P.K.; Rabo, J.A.

    1985-12-03

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C[sub 5][sup +] hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising a SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  18. Thermal Conversion of Methane to Acetylene Final Report

    SciTech Connect (OSTI)

    Fincke, J.R.; Anderson, R.P.; Hyde, T.; Wright, R.; Bewley, R.; Haggard, D.C.; Swank, W.D.

    2000-01-31

    This report describes the experimental demonstration of a process for the direct thermal conversion of methane to acetylene. The process utilizes a thermal plasma heat source to dissociation products react to form a mixture of acetylene and hydrogen. The use of a supersonic expansion of the hot gas is investigated as a method of rapidly cooling (quenching) the product stream to prevent further reaction or thermal decomposition of the acetylene which can lower the overall efficiency of the process.

  19. Enhanced conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.; Rabo, Jule A.

    1986-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  20. Enhanced catalyst for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.; Rabo, Jule A.

    1985-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  1. Gas-Phase Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Diagnostics - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  2. Biomass Program 2007 Accomplishments - Biochemical Conversion Platform

    SciTech Connect (OSTI)

    none,

    2009-10-27

    This document details accomplishments of the Biomass Program Biochemical Conversion Platform accomplishments in 2007.

  3. Biochemical Conversion - Biorefinery Integration | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research & Development » Conversion Technologies » Biochemical Conversion » Biochemical Conversion - Biorefinery Integration Biochemical Conversion - Biorefinery Integration One of the essential elements in the economical and efficient production of cellulosic biofuels is the development of biorefineries. Similar in concept to traditional petroleum refineries, biorefineries convert various types of biomass feedstock into marketable chemicals, fuels, and products. By taking advantage of

  4. Conversion Technologies for Advanced Biofuels - Carbohydrates Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Production Conversion Technologies for Advanced Biofuels - Carbohydrates Production Purdue University report-out presentation at the CTAB webinar on Carbohydrates Production. PDF icon ctab_webinar_carbohydrates_production.pdf More Documents & Publications Advanced Conversion Roadmap Workshop Workshop on Conversion Technologies for Advanced Biofuels - Carbohydrates Conversion Technologies for Advanced Biofuels - Carbohydrates Upgrading

  5. Biochemical Conversion Pilot Plant (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-06-01

    This fact sheet provides information about Biochemical Conversion Pilot Plant capabilities and resources at NREL.

  6. Biomass Program 2007 Accomplishments - Thermochemical Conversion Platform

    SciTech Connect (OSTI)

    none,

    2009-10-27

    This document details the accomplishments of the Biomass Program Thermochemical Conversion Platform in 2007.

  7. Recirculation in multiple wave conversions

    SciTech Connect (OSTI)

    Kaufman, A. N.; Brizard, A.J.; Kaufman, A.N.; Tracy, E.R.

    2008-07-30

    A one-dimensional multiple wave-conversion model is constructed that allows energy recirculation in ray phase space. Using a modular eikonal approach, the connection coefficients for this model are calculated by ray phase-space methods. Analytical results (confirmed numerically) show that all connection coefficients exhibit interference effects that depend on an interference phase, calculated from the coupling constants and the area enclosed by the intersecting rays. This conceptual model, which focuses on the topology of intersecting rays in phase space, is used to investigate how mode conversion between primary and secondary waves is modified by the presence of a tertiary wave.

  8. Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable Electricity

    Broader source: Energy.gov (indexed) [DOE]

    | Department of Energy Presents successful incorporation of one of the most promising classes of the new materials, the skutterudites, into a working automotive TEG prototype and test results on its performance PDF icon deer11_meisner.pdf More Documents & Publications Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Develop Thermoelectric Technology for Automotive Waste Heat Recovery Development of Cost-Competitive Advanced Thermoelectric Generators for Direct

  9. Coal liquefaction and gas conversion: Proceedings. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    Volume II contains papers presented at the following sessions: Indirect Liquefaction (oxygenated fuels); and Indirect Liquefaction (Fischer-Tropsch technology). Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  10. Thermoelectric Conversion of Exhaust Gas Waste Heat into Usable...

    Broader source: Energy.gov (indexed) [DOE]

    Skutterudite Thermoelectric Generator For Automotive Waste Heat Recovery Develop Thermoelectric Technology for Automotive Waste Heat Recovery Development of Cost-Competitive ...

  11. Biochemical Conversion Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion » Biochemical Conversion Related Links Biochemical Conversion Related Links Further reading about current Bioenergy Technologies Office R&D in the Biochemical Platform can be found in this website's Information Resources section. Key publications will also be provided on this page. Using Fermentation and Catalysis to Make Fuels and Products: Biochemical Conversion (January 2011) Biochemical Conversion 2009 Peer Review Biochemical Production of Ethanol from Corn Stover: 2007 State

  12. Water quality evaluation and geochemical assessment of iron, manganese, and arsenic in a landfill site

    SciTech Connect (OSTI)

    Pisigan, R.A. Jr.

    1995-12-31

    Several monitoring wells at a landfill site were sampled for water quality parameters to determine the nature of groundwater contamination. The landfill, located beneath a limestone and dolomitic bedrock, has been used for about 20 years for trash and garbage disposal. The monitoring parameters include major cations and anions, as well as iron, manganese, arsenic, and other parameters measured in the field to characterize the subsurface conditions. Groundwater samples collected near the landfill and downgradient locations had higher levels of iron, manganese, arsenic, alkalinity, hardness than those samples from an upgradient well. The downgradient and on-site samples were also more acidic and turbid, The dissolved oxygen data tend to suggest reducing conditions in the leachate environment. The elevated groundwater concentrations of the three metals, especially iron, were most probably caused by the acidity generated by carbon dioxide and organic acids released from microbial degradation of organic compounds dumped into the landfill. The acidic pH led to the dissolution of iron, manganese, and arsenic bearing mineral phases. The buffering reactions of limestone and dolomite to neutralize the acidic degradation products increased the hardness cations, Ca{sup +2} and Mg{sup +2}. Inorganic speciation modeling indicates that iron, manganese, and arsenic predominantly exist as Fe {sup +2}, Mn{sup +2}, and H{sub 3}AsO{sub 3}. The possible presence of organic complexes of iron was discussed, but could be modeled due to lack of appropriate equilibrium constant data.

  13. Value engineering: An alternative liner system at the La Paz County Regional Landfill

    SciTech Connect (OSTI)

    Shafer, A.L.; Purdy, S.; Tempelis, D.

    1997-11-01

    The La Paz County Regional Landfill is a 65 hectare (160 acre) municipal waste site located near the western border of Arizona between the cities of Parker and Quartzsite. The site is operated under a public/private partnership between the County of La Paz and Browning-Ferris Industries, Inc. (BFI). The County owns the landfill and infrastructure and BFI is responsible for facility improvements, environmental compliance, and daily operations. Following the initial permitting and construction of the first landfill cell, a value engineering review was conducted on the site design and permit requirements. Based on this review, substantial cost saving opportunities were identified. In order to implement the value engineering ideas, the site permit was modified and a new Solid Waste Facilities Plan was Submitted to the Arizona Department of Environmental Quality. This paper discusses the value engineering modifications that were conducted, the revisions to the permits, and the relative cost savings that were realized. The areas addressed include the liner system design, closure design, disposal capacity, and operations plan. Through the use of alternative liners a cost savings of well over 50 percent (as compared to the original permit) will be realized over the life of the landfill.

  14. A water balance study of four landfill cover designs varying in slope for semiarid regions

    SciTech Connect (OSTI)

    Nyhan, J.W.; Schofield, T.G.; Salazar, J.A.

    1997-02-01

    The goal of disposing of radioactive and hazardous waste in shallow landfills is to reduce risk to human health and to the environment by isolating contaminants until they no longer pose a hazard. In order to achieve this, the performance of a landfill cover design without an engineered barrier (Conventional Design) was compared with three designs containing either a hydraulic barrier (EPA Design) or a capillary barrier (Loam and Clay Loam Capillary Barrier Designs). Water balance parameters were measured since 1991 at six-hour intervals for four different landfill cover designs in 1.0- by 10.0-m plots with downhill slopes of 5, 10, 15, and 25%. Whereas runoff generally accounted for only 2-3% of the precipitation losses on these designs, similar values for evapotranspiration ranged from 86% to 91%, with increased evapotranspiration occurring with increases in slope. Consequently, interflow and seepage usually decreased with increasing slope for each landfill cover design. Seepage consisted of up to 10% of the precipitation on the Conventional Design, whereas the hydraulic barrier in the EPA Design effectively controlled seepage at all slopes, and both of the capillary designs worked effectively to eliminate seepage at the higher slopes.

  15. Sanitary Landfill Groundwater Monitoring Report - Fourth Quarter 1998 and 1998 Summary

    SciTech Connect (OSTI)

    Chase, J.

    1999-04-09

    A maximum of fifty-three wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Water permit and as part of the SRS Groundwater Monitoring Program.

  16. Stability monitoring system for the Fresh Kills Landfill in New York City

    SciTech Connect (OSTI)

    Thomann, T.G.; Khoury, M.A.; Rosenfarb, J.L.; Napolitano, R.A.

    1999-07-01

    The Fresh Kills Landfill, located in Staten Island, New York, serves as the repository of all municipal solid waste from the five boroughs of New York City. Because of the existence of compressible soils under most of the filling areas and the urban environment surrounding the landfill, considerable importance is being placed on the relationship between filling operations and the stability of the landfill. As a result of this concern and to address Order on Consent requirements, a program of geotechnical site characterizations, stability analyses, and design and implementation of a geotechnical instrumentation program was undertaken. Geotechnical instruments have been installed within the refuse fill and foundation soils to monitor both the magnitude and rate of change of pore pressure, lateral and vertical movements, and temperature. This paper presents an overview of the subsurface conditions, the overall instrumentation plan for assessing the landfill stability, a description of the various instruments, the performance of these instruments to date, an overview of the collected measurements, and a description of how these measurements are used to monitor the stability.

  17. Washington Closure Hanford Report of Settlement Monitoring of the ERDF Landfill

    SciTech Connect (OSTI)

    J. T. Cameron

    2008-07-30

    This report summarizes the results of the ERDF Settlement Monitoring Program conducted between August 9, 2007, and April 29, 2008, on the 35-foot and 70-foot levels of the ERDF landfill. The purpose of this monitoring program was to verify that the materials already placed under the 35-foot and 70-foot levels satisfy the settlement criteria of the conceptual cap design.

  18. California Natural Gas Number of Gas and Gas Condensate Wells...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) California Natural Gas Number of Gas and ... Number of Producing Gas Wells Number of Producing Gas Wells (Summary) California Natural ...

  19. Performance evaluation of an anaerobic/aerobic landfill-based digester using yard waste for energy and compost production

    SciTech Connect (OSTI)

    Yazdani, Ramin; Barlaz, Morton A.; Augenstein, Don; Kayhanian, Masoud; Tchobanoglous, George

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Biochemical methane potential decreased by 83% during the two-stage operation. Black-Right-Pointing-Pointer Net energy produced was 84.3 MWh or 46 kWh per million metric tons (Mg). Black-Right-Pointing-Pointer The average removal efficiency of volatile organic compounds (VOCs) was 96-99%. Black-Right-Pointing-Pointer The average removal efficiency of non-methane organic compounds (NMOCs) was 68-99%. Black-Right-Pointing-Pointer The two-stage batch digester proved to be simple to operate and cost-effective. - Abstract: The objective of this study was to evaluate a new alternative for yard waste management by constructing, operating and monitoring a landfill-based two-stage batch digester (anaerobic/aerobic) with the recovery of energy and compost. The system was initially operated under anaerobic conditions for 366 days, after which the yard waste was aerated for an additional 191 days. Off gas generated from the aerobic stage was treated by biofilters. Net energy recovery was 84.3 MWh, or 46 kWh per million metric tons of wet waste (as received), and the biochemical methane potential of the treated waste decreased by 83% during the two-stage operation. The average removal efficiencies of volatile organic compounds and non-methane organic compounds in the biofilters were 96-99% and 68-99%, respectively.

  20. Efficient electrochemical CO2 conversion powered by renewable energy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kauffman, Douglas R.; Thakkar, Jay; Siva, Rajan; Matranga, Christopher; Ohodnicki, Paul R.; Zeng, Chenjie; Jin, Rongchao

    2015-06-29

    The catalytic conversion of CO2 into industrially relevant chemicals is one strategy for mitigating greenhouse gas emissions. Along these lines, electrochemical CO2 conversion technologies are attractive because they can operate with high reaction rates at ambient conditions. However, electrochemical systems require electricity, and CO2 conversion processes must integrate with carbon-free, renewable-energy sources to be viable on larger scales. We utilize Au25 nanoclusters as renewably powered CO2 conversion electrocatalysts with CO2 → CO reaction rates between 400 and 800 L of CO2 per gram of catalytic metal per hour and product selectivities between 80 and 95%. These performance metrics correspond tomore » conversion rates approaching 0.8–1.6 kg of CO2 per gram of catalytic metal per hour. We also present data showing CO2 conversion rates and product selectivity strongly depend on catalyst loading. Optimized systems demonstrate stable operation and reaction turnover numbers (TONs) approaching 6 × 106 mol CO2 molcatalyst–1 during a multiday (36 hours total hours) CO2electrolysis experiment containing multiple start/stop cycles. TONs between 1 × 106 and 4 × 106 molCO2 molcatalyst–1 were obtained when our system was powered by consumer-grade renewable-energy sources. Daytime photovoltaic-powered CO2 conversion was demonstrated for 12 h and we mimicked low-light or nighttime operation for 24 h with a solar-rechargeable battery. This proof-of-principle study provides some of the initial performance data necessary for assessing the scalability and technical viability of electrochemical CO2 conversion technologies. Specifically, we show the following: (1) all electrochemical CO2 conversion systems will produce a net increase in CO2 emissions if they do not integrate with renewable-energy sources, (2) catalyst loading vs activity trends can be used to tune process rates and product distributions, and (3) state-of-the-art renewable-energy technologies are sufficient to power larger-scale, tonne per day CO2 conversion systems.« less

  1. Ocean thermal energy conversion (OTEC)

    SciTech Connect (OSTI)

    Lockerby, R.W.

    1981-01-01

    Ocean thermal energy conversion (OTEC) is reviewed briefly. The two types of OTEC system (open and closed) are described and limitations are pointed out. A bibliography of 148 references on OTEC is given for the time period 1975 to 1980. Entries are arranged alphabetically according to the author's name. (MJJ)

  2. Hydrogen Production: Microbial Biomass Conversion

    Broader source: Energy.gov [DOE]

    Microbial biomass conversion processes take advantage of the ability of microorganisms to consume and digest biomass and release hydrogen. Depending on the pathway, this research could result in commercial-scale systems in the mid- to long-term timeframe that could be suitable for distributed, semi-central, or central hydrogen production scales, depending on the feedstock used.

  3. Nitrogen management in landfill leachate: Application of SHARON, ANAMMOX and combined SHARON-ANAMMOX process

    SciTech Connect (OSTI)

    Sri Shalini, S.; Joseph, Kurian

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer Significant research on ammonia removal from leachate by SHARON and ANAMMOX process. Black-Right-Pointing-Pointer Operational parameters, microbiology, biochemistry and application of the process. Black-Right-Pointing-Pointer SHARON-ANAMMOX process for leachate a new research and this paper gives wide facts. Black-Right-Pointing-Pointer Cost-effective process, alternative to existing technologies for leachate treatment. Black-Right-Pointing-Pointer Address the issues and operational conditions for application in leachate treatment. - Abstract: In today's context of waste management, landfilling of Municipal Solid Waste (MSW) is considered to be one of the standard practices worldwide. Leachate generated from municipal landfills has become a great threat to the surroundings as it contains high concentration of organics, ammonia and other toxic pollutants. Emphasis has to be placed on the removal of ammonia nitrogen in particular, derived from the nitrogen content of the MSW and it is a long term pollution problem in landfills which determines when the landfill can be considered stable. Several biological processes are available for the removal of ammonia but novel processes such as the Single Reactor System for High Activity Ammonia Removal over Nitrite (SHARON) and Anaerobic Ammonium Oxidation (ANAMMOX) process have great potential and several advantages over conventional processes. The combined SHARON-ANAMMOX process for municipal landfill leachate treatment is a new, innovative and significant approach that requires more research to identify and solve critical issues. This review addresses the operational parameters, microbiology, biochemistry and application of both the processes to remove ammonia from leachate.

  4. Modeling of leachate generation from MSW landfills by a 2-dimensional 2-domain approach

    SciTech Connect (OSTI)

    Fellner, Johann

    2010-11-15

    The flow of water through Municipal Solid Waste (MSW) landfills is highly non-uniform and dominated by preferential pathways. Thus, concepts to simulate landfill behavior require that a heterogeneous flow regime is considered. Recent models are based on a 2-domain approach, differentiating between channel domain with high hydraulic conductivity, and matrix domain of slow water movement with high water retention capacity. These models focus on the mathematical description of rapid water flow in channel domain. The present paper highlights the importance of water exchange between the two domains, and expands the 1-dimensional, 2-domain flow model by taking into account water flows in two dimensions. A flow field consisting of a vertical path (channel domain) surrounded by the waste mass (matrix domain) is defined using the software HYDRUS-2D. When the new model is calibrated using data sets from a MSW-landfill site the predicted leachate generation corresponds well with the observed leachate discharge. An overall model efficiency in terms of r{sup 2} of 0.76 was determined for a simulation period of almost 4 years. The results confirm that water in landfills follows a preferential path way characterized by high permeability (K{sub s} = 300 m/d) and zero retention capacity, while the bulk of the landfill (matrix domain) is characterized by low permeability (K{sub s} = 0.1 m/d) and high retention capacity. The most sensitive parameters of the model are the hydraulic conductivities of the channel domain and the matrix domain, and the anisotropy of the matrix domain.

  5. Biomass Thermochemical Conversion Program. 1983 Annual report

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1984-08-01

    Highlights of progress achieved in the program of thermochemical conversion of biomass into clean fuels during 1983 are summarized. Gasification research projects include: production of a medium-Btu gas without using purified oxygen at Battelle-Columbus Laboratories; high pressure (up to 500 psia) steam-oxygen gasification of biomass in a fluidized bed reactor at IGT; producing synthesis gas via catalytic gasification at PNL; indirect reactor heating methods at the Univ. of Missouri-Rolla and Texas Tech Univ.; improving the reliability, performance, and acceptability of small air-blown gasifiers at Univ. of Florida-Gainesville, Rocky Creek Farm Gasogens, and Cal Recovery Systems. Liquefaction projects include: determination of individual sequential pyrolysis mechanisms at SERI; research at SERI on a unique entrained, ablative fast pyrolysis reactor for supplying the heat fluxes required for fast pyrolysis; work at BNL on rapid pyrolysis of biomass in an atmosphere of methane to increase the yields of olefin and BTX products; research at the Georgia Inst. of Tech. on an entrained rapid pyrolysis reactor to produce higher yields of pyrolysis oil; research on an advanced concept to liquefy very concentrated biomass slurries in an integrated extruder/static mixer reactor at the Univ. of Arizona; and research at PNL on the characterization and upgrading of direct liquefaction oils including research to lower oxygen content and viscosity of the product. Combustion projects include: research on a directly fired wood combustor/gas turbine system at Aerospace Research Corp.; adaptation of Stirling engine external combustion systems to biomass fuels at United Stirling, Inc.; and theoretical modeling and experimental verification of biomass combustion behavior at JPL to increase biomass combustion efficiency and examine the effects of additives on combustion rates. 26 figures, 1 table.

  6. Cap and trade schemes on waste management: A case study of the Landfill Allowance Trading Scheme (LATS) in England

    SciTech Connect (OSTI)

    Calaf-Forn, Maria; Roca, Jordi; Puig-Ventosa, Ignasi

    2014-05-01

    Highlights: LATS has been effective to achieve a reduction of the amount of landfilled waste. LATS has been one of the few environmental instruments for waste management with a cap and trade methodology. LATS has achieved to increase recycling of the biodegradable and other waste fractions. - Abstract: The Landfill Allowance Trading Scheme (LATS) is one of the main instruments used in England to enforce the landfill diversion targets established in the Directive 1999/31/EC of the European Parliament and of the Council of 26 April 1999 on the landfill of waste (Landfill Directive). Through the LATS, biodegradable municipal waste (BMW) allowances for landfilling are allocated to each local authority, otherwise known as waste disposal authorities (WDAs). The quantity of landfill allowances received is expected to decrease continuously from 2005/06 to 2019/20 so as to meet the objectives of the Landfill Directive. To achieve their commitments, WDAs can exchange, buy, sell or transfer allowances among each other, or may re-profile their own allocation through banking and/or borrowing. Despite the goals for the first seven years which included two target years (2005/06 and 2009/10) being widely achieved (the average allocation of allowances per WDA was 22.9% higher than those finally used), market activity among WDAs was high and prices were not very stable. Results in terms of waste reduction and recycling levels have been satisfactory. The reduction of BMW landfilled (in percentage) was higher during the first seven years of the LATS period (2005/062011/12) (around 7% annually) than during the previous period (2001/022004/05) (4.2% annually). Since 2008, the significance of the LATS diminished because of an increase in the rate of the UK Landfill Tax. The LATS was suppressed after the 2012/13 target year, before what it was initially scheduled. The purpose of this paper is to describe the particularities of the LATS, analyse its performance as a waste management policy, make a comparison with the Landfill Tax, discuss its main features as regards efficiency, effectiveness and the application of the polluter pays principle and finally discuss if the effect of the increase in the Landfill Tax is what made the LATS ultimately unnecessary.

  7. Electrocatalysts for carbon dioxide conversion

    DOE Patents [OSTI]

    Masel, Richard I; Salehi-Khojin, Amin

    2015-04-21

    Electrocatalysts for carbon dioxide conversion include at least one catalytically active element with a particle size above 0.6 nm. The electrocatalysts can also include a Helper Catalyst. The catalysts can be used to increase the rate, modify the selectivity or lower the overpotential of electrochemical conversion of CO.sub.2. Chemical processes and devices using the catalysts also include processes to produce CO, HCO.sup.-, H.sub.2CO, (HCO.sub.2).sup.-, H.sub.2CO.sub.2, CH.sub.3OH, CH.sub.4, C.sub.2H.sub.4, CH.sub.3CH.sub.2OH, CH.sub.3COO.sup.-, CH.sub.3COOH, C.sub.2H.sub.6, (COOH).sub.2, or (COO.sup.-).sub.2, and a specific device, namely, a CO.sub.2 sensor.

  8. The National Conversion Pilot Project

    SciTech Connect (OSTI)

    Roberts, A.V.

    1995-12-31

    The National Conversion Pilot Project (NCPP) is a recycling project under way at the U.S. Department of Energy (DOE) Rocky Flats Environmental Technology Site (RFETS) in Colorado. The recycling aim of the project is threefold: to reuse existing nuclear weapon component production facilities for the production of commercially marketable products, to reuse existing material (uranium, beryllium, and radioactively contaminated scrap metals) for the production of these products, and to reemploy former Rocky Flats workers in this process.

  9. Brown coal conversion under the action of supercritical water

    SciTech Connect (OSTI)

    A.A. Vostrikov; O.N. Fedyaeva; S.A. Psarov; D.Y. Dubov; M.Ya. Sokol

    2007-10-15

    A test bench was developed and the conversion of the organic matter of coal (OMC) in supercritical water (SCW) was studied under conditions of a continuous supply of a water-coal suspension to a vertical flow reactor at 390-760{sup o}C and a pressure of 30 MPa. From 44 to 63% OMC was released as liquid and gaseous products from coal particles (from the water-coal supension) during the time of fall to the reactor. This stage was referred to as the dynamic conversion of coal. The particles passed through the stage of the dynamic conversion of coal did not agglomerate in the reactor in the subsequent process of batch conversion in a coal layer at T = 550-760{sup o}C. The volatile products of the overall process of the dynamic and batch conversion of coal included saturated hydrocarbons (CH{sub 4} and C{sub 2}H{sub 6}), aromatic hydrocarbons (C{sub 6}H{sub 6}, C{sub 7}H{sub 8}, and C{sub 8}H{sub 10}), synthesis gas (H{sub 2} and CO), and CO{sub 2}. At T < 600{sup o}C, CO{sub 2} and CO were the degradation products of oxygen-containing OMC fragments, whereas they also resulted from the decomposition of water molecules at higher temperatures in accordance with the reaction c + H{sub 2}O = CO + H{sub 2}. The mechanisms were considered, and the parameters responsible for the dynamic conversion of coal were calculated.

  10. EA-0767: Construction and Experiment of an Industrial Solid Waste Landfill at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to construct and operate a solid waste landfill within the boundary at the U.S. Department of Energy's Portsmouth Gaseous Diffusion plant...

  11. Assessment of landfill reclamation and the effects of age on the combustion of recovered municipal solid waste

    SciTech Connect (OSTI)

    Forster, G.A.

    1995-01-01

    This report summarized the Lancaster county Solid Waste Management Authorities`s (LCSWMA)landfill reclamation activities, ongoing since 1991. All aspects have been analyzed from the manpower and equipment requirements at the landfill to the operational impacts felt at the LCSWMA Resource Recovery Facility (RRF) where the material is delivered for processing. Characteristics of the reclaimed refuse and soil recovered from trommeling operations are discussed as are results of air monitoring performed at the landfill excavation site and the RRF. The report also discusses the energy value of the reclaimed material and compares this value with those obtained for significantly older reclaimed waste streams. The effects of waste age on the air emissions and ash residue quality at the RRF are also provided. The report concludes by summarizing the project benefits and provides recommendations for other landfill reclamation operations and areas requiring further research.

  12. Annual Performance Assessment and Composite Analysis Review for the ICDF Landfill FY 2008

    SciTech Connect (OSTI)

    Karen Koslow Arthur Rood

    2009-08-31

    This report addresses low-level waste disposal operations at the Idaho Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Disposal Facility (ICDF) landfill from the start of operations in Fiscal Year 2003 through Fiscal Year 2008. The ICDF was authorized in the Operable Unit 3-13 Record of Decision for disposal of waste from the Idaho National Laboratory Site CERCLA environmental restoration activities. The ICDF has been operating since 2003 in compliance with the CERCLA requirements and the waste acceptance criteria developed in the CERCLA process. In developing the Operable Unit 3-13 Record of Decision, U.S. Department of Energy Order (DOE) 435.1, 'Radioactive Waste Management', was identified as a 'to be considered' requirement for the ICDF. The annual review requirement under DOE Order 435.1 was determined to be an administrative requirement and, therefore, annual reviews were not prepared on an annual basis. However, the landfill has been operating for 5 years and, since the waste forms and inventories disposed of have changed from what was originally envisioned for the ICDF landfill, the ICDF project team has decided that this annual review is necessary to document the changes and provide a basis for any updates in analyses that may be necessary to continue to meet the substantive requirements of DOE Order 435.1. For facilities regulated under DOE Order 435.1-1, U.S. DOE Manual 435.1-1, 'Radioactive Waste Management', IV.P.(4)(c) stipulates that annual summaries of low-level waste disposal operations shall be prepared with respect to the conclusions and recommendations of the performance assessment and composite analysis. Important factors considered in this review include facility operations, waste receipts, and results from monitoring and research and development programs. There have been no significant changes in operations at the landfill in respect to the disposal geometry, the verification of waste characteristics, and the tracking of inventories against total limits that would affect the results and conclusions of the performance assessment. Waste receipts to date and projected waste receipts through Fiscal Year 2012 are both greater than the inventory assessed in the performance assessment and composite analysis. The waste forms disposed of to the landfill are different from the waste form (compacted soil) assessed in the performance assessment. The leak detection system and groundwater monitoring results indicate the landfill has not leaked. The results of the performance assessment/composite analysis are valid (i.e., there is still a reasonable expectation of meeting performance objectives) but the new information indicates less conservatism in the results than previously believed.

  13. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  14. Processing and Conversion | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research & Development » Processing and Conversion Processing and Conversion The strategic goal of Conversion Research and Development (R&D) is to develop technologies for converting feedstocks into commercially viable liquid transportation fuels, as well as bioproducts and biopower. The diversity of the biomass resource requires the development of multiple conversion technologies that can efficiently deal with the broad range of feedstock materials, as well as their physical and

  15. Research Reactor Conversion | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Reactor Conversion | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the...

  16. NREL: Biomass Research - Thermochemical Conversion Capabilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and commercialization of biomass gasification is the integration of the gasifier with downstream syngas processing. ... Biomass Characterization Biochemical Conversion Thermochemical ...

  17. NREL: Biomass Research - Biochemical Conversion Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL's projects in biochemical conversion involve three ... yeast and bacteria) Processing the fermentation product ... Bioprocess Integration Researchers are refining a ...

  18. Conversion Technologies for Advanced Biofuels - Carbohydrates Upgrading |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Upgrading Conversion Technologies for Advanced Biofuels - Carbohydrates Upgrading PNNL report-out presentation at the CTAB webinar on carbohydrates upgrading. PDF icon ctab_webinar_carbohydrates_upgrading.pdf More Documents & Publications Conversion Technologies for Advanced Biofuels - Carbohydrates Production Advanced Conversion Roadmap Workshop Innovative Topics for Advanced Biofuels

  19. Title I conceptual design for Pit 6 landfill closure at Lawrence Livermore National Laboratory Site 300

    SciTech Connect (OSTI)

    MacDonnell, B.A.; Obenauf, K.S.

    1996-08-01

    The objective of this design project is to evaluate and prepare design and construction documents for a closure cover cap for the Pit 6 Landfill located at Lawrence Livermore National Laboratory Site 300. This submittal constitutes the Title I Design (Conceptual Design) for the closure cover of the Pit 6 Landfill. A Title I Design is generally 30 percent of the design effort. Title H Design takes the design to 100 percent complete. Comments and edits to this Title I Design will be addressed in the Title II design submittal. Contents of this report are as follows: project background; design issues and engineering approach; design drawings; calculation packages; construction specifications outline; and construction quality assurance plan outline.

  20. Constructed wetlands for municipal solid waste landfill leachate treatment. Final report

    SciTech Connect (OSTI)

    Peverly, J.; Sanford, W.E.; Steenhuis, T.S.

    1993-11-01

    In 1989, the US Geological Survey and Cornell University, in cooperation with the New York State Energy Research and Development Authority and the Tompkins County Solid Waste Department, began a three-year study at a municipal solid-waste landfill near Ithaca, New York, to test the effectiveness of leachate treatment with constructed wetlands and to examine the associated treatment processes. Specific objectives of the study were to examine: treatment efficiency as function of substrate composition and grain size, degree of plant growth, and seasonal changes in evapotranspiration rates and microbial activity; effects of leachate and plant growth on the hydraulic characteristics of the substrate; and chemical, biological, and physical processes by which nutrients, metals, and organic compounds are removed from leachate as it flows through the substrate. A parallel study at a municipal solid-waste landfill near Fenton, New York was conducted by researchers at Cornell University, Ithaca College, and Hawk Engineering (Trautmann and others, 1989). Results are described.

  1. EM SSAB ITR Landfill Assessment Project Lessons Learned Presentation - July 2009

    Office of Environmental Management (EM)

    Teleconference: 1. DOE EM ITR Landfill Assessment Project: Lessons Learned Craig H. Benson, PhD, PE CRESP July 2009 1 Independent Technical Review Team * Craig H. Benson, PhD, PE - University of Wisconsin-Madison: waste containment systems, civil engineering, geotechnical engineering. * William H. Albright, PhD - Desert Research Institute, Reno, Nevada: waste containment systems, hydrology, regulatory interactions. * David P. Ray, PE - US Army Corps of Engineers, Omaha, NB: waste containment

  2. RADIOLOGICAL SURVEY OF A PORTION OF PROPERTY OWNED BY MODERN LANDFILL, INC. -

    Office of Legacy Management (LM)

    A" 917 RADIOLOGICAL SURVEY OF A PORTION OF PROPERTY OWNED BY MODERN LANDFILL, INC. - FORMER LOOW SITE Summary Report Work performed by the Health and Safety Research Division Oak Ridge National Laboratory Oak Ridge, Tennessee 37830 March 1981 OAK RIDGE NATIONAL LABORATORY operated by UNION. CARBIDE CORPORATION for the DEPARTMENT OF ENERGY as part of the Formerly Utilized Sites-- Remedial Action Program CONTENTS Page LIST OF FIGURES .. .. . .. . . . . . . . ......... iii LIST OF TABLES

  3. Conversion of direct process high-boiling residue to monosilanes

    DOE Patents [OSTI]

    Brinson, Jonathan Ashley (Vale of Glamorgan, GB); Crum, Bruce Robert (Madison, IN); Jarvis, Jr., Robert Frank (Midland, MI)

    2000-01-01

    A process for the production of monosilanes from the high-boiling residue resulting from the reaction of hydrogen chloride with silicon metalloid in a process typically referred to as the "direct process." The process comprises contacting a high-boiling residue resulting from the reaction of hydrogen chloride and silicon metalloid, with hydrogen gas in the presence of a catalytic amount of aluminum trichloride effective in promoting conversion of the high-boiling residue to monosilanes. The present process results in conversion of the high-boiling residue to monosilanes. At least a portion of the aluminum trichloride catalyst required for conduct of the process may be formed in situ during conduct of the direct process and isolation of the high-boiling residue.

  4. Method for regeneration and activity improvement of syngas conversion catalyst

    DOE Patents [OSTI]

    Lucki, Stanley J.; Brennan, James A.

    1980-01-01

    A method is disclosed for the treatment of single particle iron-containing syngas (synthes.s gas) conversion catalysts comprising iron, a crystalline acidic aluminosilicate zeolite having a silica to alumina ratio of at least 12, a pore size greater than about 5 Angstrom units and a constraint index of about 1-12 and a matrix. The catalyst does not contain promoters and the treatment is applicable to either the regeneration of said spent single particle iron-containing catalyst or for the initial activation of fresh catalyst. The treatment involves air oxidation, hydrogen reduction, followed by a second air oxidation and contact of the iron-containing single particle catalyst with syngas prior to its use for the catalytic conversion of said syngas. The single particle iron-containing catalysts are prepared from a water insoluble organic iron compound.

  5. Conversion of raw carbonaceous fuels

    DOE Patents [OSTI]

    Cooper, John F.

    2007-08-07

    Three configurations for an electrochemical cell are utilized to generate electric power from the reaction of oxygen or air with porous plates or particulates of carbon, arranged such that waste heat from the electrochemical cells is allowed to flow upwards through a storage chamber or port containing raw carbonaceous fuel. These configurations allow combining the separate processes of devolatilization, pyrolysis and electrochemical conversion of carbon to electric power into a single unit process, fed with raw fuel and exhausting high BTU gases, electric power, and substantially pure CO.sub.2 during operation.

  6. Fundamentals of thermochemical biomass conversion

    SciTech Connect (OSTI)

    Overend, R.P.; Milne, T.A.; Mudge, L.

    1985-01-01

    The contents of this book are: Wood and biomass ultrastructure; Cellulose, hemicellulose and extractives; Lignin; Pretreatment of biomass for thermochemical biomass conversion; A kinetic isotope effect in the thermal dehydration of cellobiose; Gasification and liquefaction of forest products in supercritical water; Thermochemical fractionation and liquefaction of wood; The pyrolysis and gasification of wood in molten hydroxide eutectics; Influence of alkali carbonates on biomass volatilization; Flash pyrolysis of biomass with reactive and non-reactive gases; Pyrolytic reactions and biomass; Product formation in the pyrolysis of large wood particles; The pyrolysis under vacuum of aspen poplar; Simulation of kraft lignin pyrolysis; and Kinetics of wood gasification by carbon dioxide and steam.

  7. Formation of alcohol conversion catalysts

    DOE Patents [OSTI]

    Wachs, Israel E.; Cai, Yeping

    2001-01-01

    The method of the present invention involves a composition containing an intimate mixture of (a) metal oxide support particles and (b) a catalytically active metal oxide from Groups VA, VIA, or VIIA, its method of manufacture, and its method of use for converting alcohols to aldehydes. During the conversion process, catalytically active metal oxide from the discrete catalytic metal oxide particles migrates to the oxide support particles and forms a monolayer of catalytically active metal oxide on the oxide support particle to form a catalyst composition having a higher specific activity than the admixed particle composition.

  8. Garbage to hydrocarbon fuel conversion system

    SciTech Connect (OSTI)

    Gould, W.A.

    1986-07-15

    A garbage to hydrocarbon fuel conversion system is described which consists of: (a) a source of combustible garbage; (b) means for pulverizing the garbage; (c) a furnace to burn the garbage; (d) means for transporting the pulverized garbage to the furnace which comprises a motor operated worm feed automatic stoker; (e) a steam generating coil inside the furnace which supplies live steam to power a turbine which in turn powers an alternating current generator; and a condenser which returns remaining the steam to a liquid state for re-circulation through the steam generating coils; (f) means for collecting incompletely combusted waste gases from the furnace; precipitating out dust and light oil for re-combustion in the furnace; and, extracting hydrocarbon gas; where in the means for precipitating out dust and light oil for re-combustion in the furnace comprise a cottrell precipitator wherein oil from an external source is mixed with fine dust received from the exhaust port, wherein an electrostatic charge helps to precipitate the dust; a dust and light oil mixer which provides a homogeneous mixture; and, an oil burner mounted to the furnace whose heat output is supplied to the furnace to add energy thereto; and (g) means for burning trapped heavy gases and removing waste ash from the furnace for disposal.

  9. Conversion and enrichment in the Soviet Union

    SciTech Connect (OSTI)

    1991-04-01

    In the Soviet Union, just as in the West, the civilian nuclear industry emerged from research work undertaken for nuclear weapons development. At first, researchers tried various techniques for physical separation of uranium isotopes: electromagnetic and molecular-kinetic thermo-diffusion methods; gaseous diffusion; and centrifuge methods. All of those methods, which are based primarily on differences in the atomic mass of uranium isotopes, called for extensive research and the development of new, technically unprecedented equipment. Gradually gaseous diffusion and gas centrifuge technology became recognized as most feasible for industrial use, so research on other methods was terminated. Industrial-scale uranium enrichment in the Soviet Union began in 1949 using the gaseous diffusion method; by the early 1960s, centrifuge technology was in use on an industrial scale. All Soviet production of highly-enriched, weapons-grade uranium was halted in 1987. The Soviet Union now has four enrichment plants in operation (at classified locations), solely for civilian nuclear power needs. All four enrichment plants have centrifuge modules, and enrichment provided by gaseous diffusion accounts for less than 5% of their total output. Two of the four enrichment plants also incorporate facilities for conversion to uranium hexafluoride (UF{sub 6}).

  10. Process feasibility of DME to olefin conversion

    SciTech Connect (OSTI)

    Tartamella, T.L.; Fullerton, K.L.; Lee, S.; Kulik, C.J.

    1994-12-31

    The production of hydrocarbons via a synthetic route has been extensively studied by Mobil through its methanol based Methanol-to-Gasoline (MTG) process. An alternative approach using dimethyl ether (DME) has been developed by the University of Akron -- UA/EPRI DME-to-Hydrocarbons Process. The process feasibility of the production of hydrocarbons from DME has been illustrated in a bench scale, fluidized bed reactor using ZSM-5 type catalyst. In an effort to satisfy the growing demand for olefins as an intermediate chemical feedstocks a mechanistic/kinetic study was developed. The synthesis of olefins has been studied in packed bed micro-reactor using ZSM-5 catalyst. Experimental work has given details of reaction kinetics and mechanism in the conversion of DME to olefins. DME concentration weight hourly space velocity (WHSV), as well as reactor temperature and pressure were investigated in the study. This work was used as a precursor to the production of olefins/hydrocarbons from DME in a fluidized bed reactor. Product gas analysis was performed using an external GC standard method.

  11. High resolution A/D conversion based on piecewise conversion at lower resolution

    DOE Patents [OSTI]

    Terwilliger, Steve

    2012-06-05

    Piecewise conversion of an analog input signal is performed utilizing a plurality of relatively lower bit resolution A/D conversions. The results of this piecewise conversion are interpreted to achieve a relatively higher bit resolution A/D conversion without sampling frequency penalty.

  12. Biomass thermochemical conversion program. 1985 annual report

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1986-01-01

    Wood and crop residues constitute a vast majority of the biomass feedstocks available for conversion, and thermochemical processes are well suited for conversion of these materials. The US Department of Energy (DOE) is sponsoring research on this conversion technology for renewable energy through its Biomass Thermochemical Conversion Program. The Program is part of DOE's Biofuels and Municipal Waste Technology Division, Office of Renewable Technologies. This report briefly describes the Thermochemical Conversion Program structure and summarizes the activities and major accomplishments during fiscal year 1985. 32 figs., 4 tabs.

  13. Biomass thermochemical conversion program: 1987 annual report

    SciTech Connect (OSTI)

    Schiefelbein, G.F.; Stevens, D.J.; Gerber, M.A.

    1988-01-01

    The objective of the Biomass Thermochemical Conversion Program is to generate a base of scientific data and conversion process information that will lead to establishment of cost-effective processes for conversion of biomass resources into clean fuels. To accomplish this objective, in fiscal year 1987 the Thermochemical Conversion Program sponsored research activities in the following four areas: Liquid Hydrocarbon Fuels Technology; Gasification Technology; Direct Combustion Technology; Program Support Activities. In this report an overview of the Thermochemical Conversion Program is presented. Specific research projects are then described. Major accomplishments for 1987 are summarized.

  14. Biomass conversion processes for energy and fuels

    SciTech Connect (OSTI)

    Sofer, S.S.; Zaborsky, O.R.

    1981-01-01

    The book treats biomass sources, promising processes for the conversion of biomass into energy and fuels, and the technical and economic considerations in biomass conversion. Sources of biomass examined include crop residues and municipal, animal and industrial wastes, agricultural and forestry residues, aquatic biomass, marine biomass and silvicultural energy farms. Processes for biomass energy and fuel conversion by direct combustion (the Andco-Torrax system), thermochemical conversion (flash pyrolysis, carboxylolysis, pyrolysis, Purox process, gasification and syngas recycling) and biochemical conversion (anaerobic digestion, methanogenesis and ethanol fermentation) are discussed, and mass and energy balances are presented for each system.

  15. Complete decay of radionuclides: Implications for low-level waste disposal in municipal landfills

    SciTech Connect (OSTI)

    Meck, R.A.

    1996-05-01

    The time required for the complete decay of a radioactive source can be quantified by specifying an acceptable probability and using an original derivation. The physical phenomenon of complete decay may be used as the technical basis to change regulations and permit, with public acceptance, the inexpensive disposal of short half-lived radioactive waste into municipal landfills. Current regulations require isolation of trash form the biosphere for 30 years during the post-closure control period for municipal landfills. Thirty years is sufficient time for complete decay of significant quantities of short-lived radionuclides, and there is a large decay capacity in the nation`s landfills. As the major generators of low-level radioactive waste with relatively short half-lives, the academic, medical, and research communities likely would benefit most from such regulatory relief. Disposal of such waste is prohibited or costly. The waste must be specially packaged, stored, transported, and disposed in designated repositories. Regulatory relief can be initiated by citizens since the Administrative Procedures Act gives citizens the right to petition for regulatory change. 10 refs., 2 tabs.

  16. Paleo-channel deposits of natural uranium at a Former Air Force Landfill

    SciTech Connect (OSTI)

    Young, C.; Weismann, PGJ.; Nelson, CHPK. [Cabrera Services, Inc., Baltimore, MD (United States)

    2007-07-01

    The US Air Force has sought to understand the provenance of radionuclides that were detected in monitor wells surrounding a closed solid-waste landfill at the former Lowry Air Force Base in Denver, Colorado. Groundwater concentrations of gross alpha, gross beta, and total uranium were thought to exceed regulatory standards. Down-gradient concentrations of these parameters exceeded up-gradient concentrations, suggesting that the landfill is leaching uranium to groundwater. Alternate hypotheses for the occurrence of the uranium included that either equipment containing refined uranium had been discarded or that uranium ore may have been disposed in the landfill, or that the uranium is naturally-occurring. Our study has concluded that the elevated radionuclide concentrations stem from naturally-occurring uranium in the regional watershed which has been preferentially deposited in paleo-channel sediments beneath the site. This study shows that a simple comparison of up-gradient versus down-gradient groundwater samples can be an inadequate method for determining whether heterogeneous geo-systems have been contaminated. It is important to understand the geologic depositional system, plus local geochemistry and how these factors impact contaminant transport. (authors)

  17. Definitional mission report: NAPCOR thermal-power-conversion project, Philippines. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1991-11-01

    The National Power Corporation (NAPCOR) of Philippines has requested the Trade and Development Program (TDP) to fund a study to evaluate the technical and economic feasibility of converting its existing oil and coal fired power plants to natural gas. The decision to undertake the study resulted from preliminary information on a large gas find off the coast of Palawan island. However, a second exploration well has come up dry. Now, the conversion of the existing power plants to natural gas seems very questionable. Even if the proven gas reserves prove to be commercially viable, the gas will not be available until 1998 or later for utilization. At that time several of NAPCOR's plants would have aged further, the political and economic situation in Philippines could have altered significantly, possibly improved, private power companies might be able to use the gas more efficiently by building state-of-the-art combined cycle power plants which will make more economic sense than converting existing old boilers to natural gas. In addition, most of the existing power equipment was manufactured by Japanese and/or European firms. It makes sense for NAPCOR to solicit services from these firms if it decides to go ahead with the implementation of the power plant conversion project. The potential for any follow on work for U.S. businesses is minimal to zero in the thermal conversion project. Therefore, at this time, TDP funding for the feasibility would be premature and not recommended.

  18. Novel Energy Conversion Equipment for Low Temperatures Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Conversion Equipment for Low Temperatures Geothermal Resources Novel Energy Conversion Equipment for Low Temperatures Geothermal Resources Novel Energy Conversion Equipment ...

  19. Word in the Square: Conversation Monitoring and Analysis Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    key insight of the major topics of conversation * Conversation Indexes - gives statistical information about conversations within blogs, forumsmessage boards and newsgroups * ...

  20. Evaluation of aftermarket CNG conversion kits in light-duty vehicle applications. Final report

    SciTech Connect (OSTI)

    Blazek, C.F.; Rowley, P.F.; Grimes, J.W.

    1995-07-01

    The Institute of Gas Technology (IGT) was contracted by the National Renewable Energy Laboratory (NREL) to evaluate three compressed natural gas (CNG) conversion systems using a 1993 Chevrolet Lumina baseline vehicle. A fourth conversion system was added to the test matrix through funding support from Brooklyn Union. The objective of this project was to measure the Federal Test Procedure (FTP) emissions and fuel economy of the different conversion systems, and to compare the performance to gasoline-fueled operation and each other. Different natural gas compositions were selected to represent the 10th percentile, mean, and 90th percentile compositions distributed in the Continental United States. Testing with these different compositions demonstrated the systems` ability to accommodate the spectrum of gas found in the United States. Each compressed natural gas conversion system was installed and adjusted according to the manufacturer`s instructions. In addition to the FTP testing, an evaluation of the comparative installation times and derivability tests (based on AGA and CRC guidelines) were conducted on each system.

  1. Natural gas recovery, storage, and utilization SBIR program

    SciTech Connect (OSTI)

    Shoemaker, H.D.

    1993-12-31

    A Fossil Energy natural-gas topic has been a part of the DOE Small Business Innovation Research (SBIR) program since 1988. To date, 50 Phase SBIR natural-gas applications have been funded. Of these 50, 24 were successful in obtaining Phase II SBIR funding. The current Phase II natural-gas research projects awarded under the SBIR program and managed by METC are presented by award year. The presented information on these 2-year projects includes project title, awardee, and a project summary. The 1992 Phase II projects are: landfill gas recovery for vehicular natural gas and food grade carbon dioxide; brine disposal process for coalbed gas production; spontaneous natural as oxidative dimerization across mixed conducting ceramic membranes; low-cost offshore drilling system for natural gas hydrates; motorless directional drill for oil and gas wells; and development of a multiple fracture creation process for stimulation of horizontally drilled wells.The 1993 Phase II projects include: process for sweetening sour gas by direct thermolysis of hydrogen sulfide; remote leak survey capability for natural gas transport storage and distribution systems; reinterpretation of existing wellbore log data using neural-based patter recognition processes; and advanced liquid membrane system for natural gas purification.

  2. SEP Success Story: State Energy Program Helping Arkansans Convert to Compressed Natural Gas

    Broader source: Energy.gov [DOE]

    The Arkansas Energy Office recently launched a Compressed Natural Gas Conversion Rebate Program, which provides incentives for fleets and individuals to purchase and/or convert their Arkansas-licensed vehicles to compressed natural gas. Learn more.

  3. Conversion of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Chen, N.Y.; Pelrine, B.P.; Yan, T.Y.

    1982-12-14

    This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products. The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.

  4. Coal conversion. 1979 technical report

    SciTech Connect (OSTI)

    1980-09-01

    Individual reports are made on research programs which are being conducted by various organizations and institutions for the commercial development of processes for converting coal into products that substitute for these derived from oil and natural gas. Gasification, liquefaction, and demonstration processes and plants are covered. (DLC)

  5. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  6. Rapid Solar-Thermal Conversion of Biomass to Syngas - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Rapid Solar-Thermal Conversion of Biomass to Syngas Production of synthesis gas or hydrogen by gasification or pyrolysis of biological feedstocks using solar-thermal energy. University of Colorado Contact CU About This Technology Technology Marketing Summary The invention provides processes that perform biomass gasification or pyrolysis for production of hydrogen, synthesis gas, liquid fuels, or other

  7. Power conversion apparatus and method

    DOE Patents [OSTI]

    Su, Gui-Jia (Knoxville, TN)

    2012-02-07

    A power conversion apparatus includes an interfacing circuit that enables a current source inverter to operate from a voltage energy storage device (voltage source), such as a battery, ultracapacitor or fuel cell. The interfacing circuit, also referred to as a voltage-to-current converter, transforms the voltage source into a current source that feeds a DC current to a current source inverter. The voltage-to-current converter also provides means for controlling and maintaining a constant DC bus current that supplies the current source inverter. The voltage-to-current converter also enables the current source inverter to charge the voltage energy storage device, such as during dynamic braking of a hybrid electric vehicle, without the need of reversing the direction of the DC bus current.

  8. Proceedings of the 31. intersociety energy conversion engineering...

    Office of Scientific and Technical Information (OSTI)

    Volume 2: Conversion technologies, electro-chemical technologies, Stirling engines, ... Volume 2: Conversion technologies, electro-chemical technologies, Stirling engines, ...

  9. Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion Technologies - Chemical Conversion Technologies - Process Integration and Separations ... have been developed by other industries * Recent program activities ...

  10. CORRECTIVE ACTION DECISION DOCUMENT FOR THE AREA 3 LANDFILL COMPLEX, TONOPAH TEST RANGE, CAU 424, REVISION 0, MARCH 1998

    SciTech Connect (OSTI)

    DOE /NV

    1998-03-03

    This Corrective Action Decision Document (CADD) has been prepared for the Area 3 Landfill Complex (Corrective Action Unit [CAU] 424) in accordance with the Federal Facility Agreement and Consent Order (FFACO) of 1996. Corrective Action Unit 424 is located at the Tonopah Test Range (TTR) and is comprised of the following Corrective Action Sites (CASs), each an individual landfill located around and within the perimeter of the Area 3 Compound (DOE/NV, 1996a): (1) Landfill A3-1 is CAS No. 03-08-001-A301. (2) Landfill A3-2 is CAS No. 03-08-002-A302. (3) Landfill A3-3 is CAS No. 03-08-002-A303. (4) Landfill A3-4 is CAS No. 03-08-002-A304. (5) Landfill A3-5 is CAS No. 03-08-002-A305. (6) Landfill A3-6 is CAS No. 03-08-002-A306. (7) Landfill A3-7 is CAS No. 03-08-002-A307. (8) Landfill A3-8 is CAS No. 03-08-002-A308. The purpose of this CADD is to identify and provide a rationale for the selection of a recommended corrective action alternative for each CAS. The scope of this CADD consists of the following: (1) Develop corrective action objectives. (2) Identify corrective action alternative screening criteria. (3) Develop corrective action alternatives. (4) Perform detailed and comparative evaluations of the corrective action alternatives in relation to the corrective action objectives and screening criteria. (6) Recommend and justify a preferred corrective action alternative for each CAS. In June and July 1997, a corrective action investigation was performed as set forth in the Corrective Action Investigation Plan (CAIP) for CAU No. 424: Area 3 Landfill Complex, Tonopah Test Range, Nevada (DOE/NV, 1997). Details can be found in Appendix A of this document. The results indicated four groupings of site characteristics as shown in Table ES-1. Based on the potential exposure pathways, the following corrective action objectives have been identified for CAU No. 424: (1) Prevent or mitigate human exposure to subsurface soils containing waste. (2) Remediate the site per applicable state and federal regulations (NAC, 1996c). (3) Prevent adverse impacts to groundwater quality. Based on the review of existing data, future land use, and current operations at the TTR, the following alternatives were developed for consideration at the Area 3 Landfill Complex CAU: Alternative 1 - No Action; Alternative 2 - Administrative Closure; Alternative 3 - Partial Excavation, Backfill, and Recontouring The corrective action alternatives were evaluated based on four general corrective action standards and five remedy-selection decision factors. Based on the results of this evaluation, preferred alternatives were selected for each CAS as indicated in Table ES-2. The preferred corrective action alternatives were evaluated on their technical merits, focusing on performance, reliability, feasibility, and safety. The alternatives were judged to meet all requirements for the technical components evaluated. These alternatives meet all applicable state and federal regulations for closure of the site and will reduce potential future exposure pathways to the contents of the landfills. During corrective action implementation, these alternatives will present minimal potential threat to site workers who come in contact with the waste. However, procedures will be developed and implemented to ensure worker health and safety.

  11. A hybrid method for quasi-three-dimensional slope stability analysis in a municipal solid waste landfill

    SciTech Connect (OSTI)

    Yu, L.; Batlle, F.

    2011-12-15

    Highlights: > A quasi-three-dimensional slope stability analysis method was proposed. > The proposed method is a good engineering tool for 3D slope stability analysis. > Factor of safety from 3D analysis is higher than from 2D analysis. > 3D analysis results are more sensitive to cohesion than 2D analysis. - Abstract: Limited space for accommodating the ever increasing mounds of municipal solid waste (MSW) demands the capacity of MSW landfill be maximized by building landfills to greater heights with steeper slopes. This situation has raised concerns regarding the stability of high MSW landfills. A hybrid method for quasi-three-dimensional slope stability analysis based on the finite element stress analysis was applied in a case study at a MSW landfill in north-east Spain. Potential slides can be assumed to be located within the waste mass due to the lack of weak foundation soils and geosynthetic membranes at the landfill base. The only triggering factor of deep-seated slope failure is the higher leachate level and the relatively high and steep slope in the front. The valley-shaped geometry and layered construction procedure at the site make three-dimensional slope stability analyses necessary for this landfill. In the finite element stress analysis, variations of leachate level during construction and continuous settlement of the landfill were taken into account. The 'equivalent' three-dimensional factor of safety (FoS) was computed from the individual result of the two-dimensional analysis for a series of evenly spaced cross sections within the potential sliding body. Results indicate that the hybrid method for quasi-three-dimensional slope stability analysis adopted in this paper is capable of locating roughly the spatial position of the potential sliding mass. This easy to manipulate method can serve as an engineering tool in the preliminary estimate of the FoS as well as the approximate position and extent of the potential sliding mass. The result that FoS obtained from three-dimensional analysis increases as much as 50% compared to that from two-dimensional analysis implies the significance of the three-dimensional effect for this study-case. Influences of shear parameters, time elapse after landfill closure, leachate level as well as unit weight of waste on FoS were also investigated in this paper. These sensitivity analyses serve as the guidelines of construction practices and operating procedures for the MSW landfill under study.

  12. Energy Conversion Devices | Open Energy Information

    Open Energy Info (EERE)

    Type Test & Evaluation Partner Partnering Center within NREL National Center for Photovoltaics Partnership Year 2003 Energy Conversion Devices is a company located in Rochester...

  13. Center on Nanostructuring for Efficient Energy Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is to engineer catalysts with atomic scale precision for two key electrochemical energy conversion reactions for water splitting, namely, water oxidation (oxygen evolution),...

  14. Technical Market Analysis for Biochemical Conversion Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... This project supports BETO Analysis and Sustainability activities for Biochemical ... and chemical conversion technologies with respect to environmental and economic metrics. ...

  15. The Southern California Conversion Technology Demonstration Project...

    Open Energy Info (EERE)

    Conversion Technology Demonstration Project Sector: Energy, Land Focus Area: - Waste to Energy Phase: Create a Vision Resource Type: Publications User Interface: Website...

  16. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    July--September 1995 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report, July--September 1995 You are accessing...

  17. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    October--December 1994 Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report, October--December 1994 In this Quarter, the...

  18. Molecular catalytic coal liquid conversion. Quarterly report...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly report In this Quarter, the research was focused continually on the two...

  19. Molecular catalytic coal liquid conversion. Quarterly status...

    Office of Scientific and Technical Information (OSTI)

    report Citation Details In-Document Search Title: Molecular catalytic coal liquid conversion. Quarterly status report You are accessing a document from the Department of...

  20. "Fundamental Challenges in Solar Energy Conversion" workshop...

    Office of Science (SC) Website

    Fundamental Challenges in Solar Energy Conversion" workshop hosted by LMI-EFRC Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events ...

  1. "Approaches to Ultrahigh Efficiency Solar Energy Conversion"...

    Office of Science (SC) Website

    "Approaches to Ultrahigh Efficiency Solar Energy Conversion" Webinar Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events EFRC News ...

  2. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals BETO works with the emerging U.S. bioindustry to sustainably convert non-food ...

  3. Battery Chargers | Electrical Power Conversion and Storage

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Chargers | Electrical Power Conversion and Storage 625 West A Street | Lincoln, NE 68522-1794 ... TO: United States Department of Energy (DOE), Via Email, ...

  4. Impact of HFIR LEU Conversion on Beryllium Reflector Degradation Factors

    SciTech Connect (OSTI)

    Ilas, Dan

    2013-10-01

    An assessment of the impact of low enriched uranium (LEU) conversion on the factors that may cause the degradation of the beryllium reflector is performed for the High Flux Isotope Reactor (HFIR). The computational methods, models, and tools, comparisons with previous work, along with the results obtained are documented and discussed in this report. The report documents the results for the gas and neutronic poison production, and the heating in the beryllium reflector for both the highly enriched uranium (HEU) and LEU HFIR configurations, and discusses the impact that the conversion to LEU may have on these quantities. A time-averaging procedure was developed to calculate the isotopic (gas and poisons) production in reflector. The sensitivity of this approach to different approximations is gauged and documented. The results show that the gas is produced in the beryllium reflector at a total rate of 0.304 g/cycle for the HEU configuration; this rate increases by ~12% for the LEU case. The total tritium production rate in reflector is 0.098 g/cycle for the HEU core and approximately 11% higher for the LEU core. A significant increase (up to ~25%) in the neutronic poisons production in the reflector during the operation cycles is observed for the LEU core, compared to the HEU case, for regions close to the core s horizontal midplane. The poisoning level of the reflector may increase by more than two orders of magnitude during long periods of downtime. The heating rate in the reflector is estimated to be approximately 20% lower for the LEU core than for the HEU core. The decrease is due to a significantly lower contribution of the heating produced by the gamma radiation for the LEU core. Both the isotopic (gas and neutronic poisons) production and the heating rates are spatially non-uniform throughout the beryllium reflector volume. The maximum values typically occur in the removable reflector and close to the midplane.

  5. Best Practices for Siting Solar Photovoltaics on Municipal Solid Waste Landfills. A Study Prepared in Partnership with the Environmental Protection Agency for the RE-Powering America's Land Initiative: Siting Renewable Energy on Potentially Contaminated Land and Mine Sites

    SciTech Connect (OSTI)

    Kiatreungwattana, K.; Mosey, G.; Jones-Johnson, S.; Dufficy, C.; Bourg, J.; Conroy, A.; Keenan, M.; Michaud, W.; Brown, K.

    2013-04-01

    The Environmental Protection Agency and the National Renewable Energy Laboratory developed this best practices document to address common technical challenges for siting solar photovoltaics (PV) on municipal solid waste (MSW) landfills. The purpose of this document is to promote the use of MSW landfills for solar energy systems. Closed landfills and portions of active landfills with closed cells represent thousands of acres of property that may be suitable for siting solar photovoltaics (PV). These closed landfills may be suitable for near-term construction, making these sites strong candidate to take advantage of the 30% Federal Business Energy Investment Tax Credit. It was prepared in response to the increasing interest in siting renewable energy on landfills from solar developers; landfill owners; and federal, state, and local governments. It contains examples of solar PV projects on landfills and technical considerations and best practices that were gathered from examining the implementation of several of these projects.

  6. CONVERSION EXTRACTION DESULFURIZATION (CED) PHASE III

    SciTech Connect (OSTI)

    James Boltz

    2005-03-01

    This project was undertaken to refine the Conversion Extraction Desulfurization (CED) technology to efficiently and economically remove sulfur from diesel fuel to levels below 15-ppm. CED is considered a generic term covering all desulfurization processes that involve oxidation and extraction. The CED process first extracts a fraction of the sulfur from the diesel, then selectively oxidizes the remaining sulfur compounds, and finally extracts these oxidized materials. The Department of Energy (DOE) awarded Petro Star Inc. a contract to fund Phase III of the CED process development. Phase III consisted of testing a continuous-flow process, optimization of the process steps, design of a pilot plant, and completion of a market study for licensing the process. Petro Star and the Degussa Corporation in coordination with Koch Modular Process Systems (KMPS) tested six key process steps in a 7.6-centimeter (cm) (3.0-inch) inside diameter (ID) column at gas oil feed rates of 7.8 to 93.3 liters per hour (l/h) (2.1 to 24.6 gallons per hour). The team verified the technical feasibility with respect to hydraulics for each unit operation tested and successfully demonstrated pre-extraction and solvent recovery distillation. Test operations conducted at KMPS demonstrated that the oxidation reaction converted a maximum of 97% of the thiophenes. The CED Process Development Team demonstrated that CED technology is capable of reducing the sulfur content of light atmospheric gas oil from 5,000-ppm to less than 15-ppm within the laboratory scale. In continuous flow trials, the CED process consistently produced fuel with approximately 20-ppm of sulfur. The process economics study calculated an estimated process cost of $5.70 per product barrel. The Kline Company performed a marketing study to evaluate the possibility of licensing the CED technology. Kline concluded that only 13 refineries harbored opportunity for the CED process. The Kline study and the research team's discussions with prospective refineries led to the conclusion that there were not likely prospects for the licensing of the CED process.

  7. Treatment of municipal landfill leachate using a combined anaerobic digester and activated sludge system

    SciTech Connect (OSTI)

    Kheradmand, S.; Karimi-Jashni, A.; Sartaj, M.

    2010-06-15

    The main objective of this study was to assess the feasibility of treating sanitary landfill leachate using a combined anaerobic and activated sludge system. A high-strength leachate from Shiraz municipal landfill site was treated using this system. A two-stage laboratory-scale anaerobic digester under mesophilic conditions and an activated sludge unit were used. Landfill leachate composition and characteristics varied considerably during 8 months experiment (COD concentrations of 48,552-62,150 mg/L). It was found that the system could reduce the COD of the leachate by 94% at a loading rate of 2.25 g COD/L/d and 93% at loading rate of 3.37 g COD/L/d. The anaerobic digester treatment was quite effective in removing Fe, Cu, Mn, and Ni. However, in the case of Zn, removal efficiency was about 50%. For the rest of the HMs the removal efficiencies were in the range 88.8-99.9%. Ammonia reduction did not occur in anaerobic digesters. Anaerobic reactors increased alkalinity about 3.2-4.8% in the 1st digester and 1.8-7.9% in the 2nd digester. In activated sludge unit, alkalinity and ammonia removal efficiency were 49-60% and 48.6-64.7%, respectively. Methane production rate was in the range of 0.02-0.04, 0.04-0.07, and 0.02-0.04 L/g COD{sub rem} for the 1st digester, the 2nd digester, and combination of both digesters, respectively; the methane content of the biogas varied between 60% and 63%.

  8. Environmental review for the conversion of Bellefonte Nuclear Plant to fossil fuel

    SciTech Connect (OSTI)

    Carter, R.; Rucker, H.; Summers, R.

    1998-07-01

    The Tennessee Valley Authority recently issued for public review a Draft Environmental Impact Statement for the conversion of the unfinished Bellefonte Nuclear Plant to fossil fuel. The DEIS was structured to support three tiers of decision making. Tier 1 is to decide between the No-Action Alternative, which is to leave Bellefonte as a partially completed nuclear plant into the indefinite future, and the Proposed Action Alternative, which is to proceed with converting Bellefonte to fossil fuel. Tier 2 is to select one of five conversion options. In the DEIS, TVA indicated no preference among the five competing fossil conversion options. The five conversion pathways would fully repower the plant consistent with fossil fuel availability, would use commercially ready systems and technologies and be designed to fully utilize the capacity of transmission lines serving Bellefonte. Conversion options addressed were pulverized coal (PC), natural gas combined cycle (NGCC), integrated gasification combined cycle (IGCC), IGCC with joint production of electricity and chemicals, and an option, which combines elements of NGCC and IGCC with coproduction. Tier 3 involves decisions about eight sub-option choices, basically types of processes, equipment, and modes of operation, which is part of two or more conversion options. An example of a sub-option choice would be the type of gasifier that would be used in conversion options involving coal or petroleum coke gasification. Other sub-option choices addressed in the DEIS were natural gas pipeline corridors; fuels, feedstocks, and by-products transportation modes; types of combustion turbines; solid fuels; types of boilers for conventional coal-fired options; chemical production mixes; and modes of onsite solid fuel conveyance. The impact of constructing and operating each proposed fossil conversion option at Bellefonte were evaluated for 18 environmental resource and economic categories.

  9. Conversion of fullerenes to diamonds

    DOE Patents [OSTI]

    Gruen, Dieter M.

    1995-01-01

    A method of forming synthetic diamond or diamond-like films on a substrate surface. The method involves the steps of providing a vapor selected from the group of fullerene molecules or an inert gas/fullerene molecule mixture, providing energy to the fullerene molecules consisting of carbon-carbon bonds, the energized fullerene molecules breaking down to form fragments of fullerene molecules including C.sub.2 molecules and depositing the energized fullerene molecules with C.sub.2 fragments onto the substrate with farther fragmentation occurring and forming a thickness of diamond or diamond-like films on the substrate surface.

  10. Conversion of fullerenes to diamond

    DOE Patents [OSTI]

    Gruen, Dieter M.

    1994-01-01

    A method of forming synthetic hydrogen defect free diamond or diamond like films on a substrate. The method involves providing vapor containing fullerene molecules with or without an inert gas, providing a device to impart energy to the fullerene molecules, fragmenting at least in part some of the fullerene molecules in the vapor or energizing the molecules to incipient fragmentation, ionizing the fullerene molecules, impinging ionized fullerene molecules on the substrate to assist in causing fullerene fragmentation to obtain a thickness of diamond on the substrate.

  11. Alternative fuel information: Facts about CNG and LPG conversion

    SciTech Connect (OSTI)

    O`Connor, K.

    1994-06-01

    As new environmental and energy related laws begin to take effect, increasing numbers of alternative fuel vehicles (AFVs) will be required in federal, state, municipal, and private fleets across the country. The National Energy Policy Act of 1992 and the Clean Air Act Amendments of 1990, along with several new state and local laws, will require fleet managers to either purchase original equipment manufacturer (OEM) vehicles, which are produced by automakers, or convert existing vehicles to run on alternative fuels. Because there is a limited availability and selection of OEM vehicles, conversions are seen as a transition to the time when automakers will produce more AFVs for public sale. A converted vehicle is any vehicle that originally was designed to operate on gasoline, and has been altered to run on an alternative fuel such as compressed natural gas (CNG) or propane (liquefied petroleum gas -- LPG), the two most common types of fuel conversions. In the United States, more than 25,000 vehicles already have been converted to COG, and 300,000 have been converted to LPG.

  12. Interim site characterization report and ground-water monitoring program for the Hanford site solid waste landfill

    SciTech Connect (OSTI)

    Fruland, R.M.; Hagan, R.A.; Cline, C.S.; Bates, D.J.; Evans, J.C.; Aaberg, R.L.

    1989-07-01

    Federal and state regulations governing the operation of landfills require utilization of ground-water monitoring systems to determine whether or not landfill operations impact ground water at the point of compliance (ground water beneath the perimeter of the facility). A detection-level ground-water monitoring system was designed, installed, and initiated at the Hanford Site Solid Waste Landfill (SWL). Chlorinated hydrocarbons were detected at the beginning of the ground-water monitoring program and continue to be detected more than 1 year later. The most probable source of the chlorinated hydrocarbons is washwater discharged to the SWL between 1985 and 1987. This is an interim report and includes data from the characterization work that was performed during well installation in 1987, such as field observations, sediment studies, and geophysical logging results, and data from analyses of ground-water samples collected in 1987 and 1988, such as field parameter measurements and chemical analyses. 38 refs., 27 figs., 8 tabs.

  13. Steam plant ash disposal facility and industrial landfill at the Y-12 Plant, Anderson County, Tennessee. Environmental Assessment

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    The US Department of Energy (DOE) is proposing to install a wet ash handling system to dewater bottom ash from the coal-fired steam plant at its Y-12 Plant and to construct a new landfill for disposal of industrial wastes, including the dewatered bottom ash. The DOE operates three major facilities on its Oak Ridge Reservation (ORR). Operation of these facilities results in the production of a variety of nonhazardous, nonradioactive solid wastes (approximately 300 m{sup 3} per day, compacted) including sanitary wastes, common industrial wastes and construction debris. At the current rate of use, this existing landfill will be filled within approximately 18 months, and more space is urgently needed. In an effort to alleviate this problem, DOE and WMD management propose to create additional landfill facilities at a nearby site. The potential environmental impacts associated with this proposed action are the subject of this environmental assessment (EA).

  14. Interdigitated photovoltaic power conversion device

    DOE Patents [OSTI]

    Ward, J.S.; Wanlass, M.W.; Gessert, T.A.

    1999-04-27

    A photovoltaic power conversion device has a top surface adapted to receive impinging radiation. The device includes at least two adjacent, serially connected cells. Each cell includes a semi-insulating substrate and a lateral conductivity layer of a first doped electrical conductivity disposed on the substrate. A base layer is disposed on the lateral conductivity layer and has the same electrical charge conductivity thereof. An emitter layer of a second doped electrical conductivity of opposite electrical charge is disposed on the base layer and forms a p-n junction therebetween. A plurality of spaced channels are formed in the emitter and base layers to expose the lateral conductivity layer at the bottoms thereof. A front contact grid is positioned on the top surface of the emitter layer of each cell. A first current collector is positioned along one outside edge of at least one first cell. A back contact grid is positioned in the channels at the top surface of the device for engagement with the lateral conductivity layer. A second current collector is positioned along at least one outside edge of at least one oppositely disposed second cell. Finally, an interdigitation mechanism is provided for serially connecting the front contact grid of one cell to the back contact grid of an adjacent cell at the top surface of the device. 15 figs.

  15. Interdigitated photovoltaic power conversion device

    DOE Patents [OSTI]

    Ward, James Scott (Englewood, CO); Wanlass, Mark Woodbury (Golden, CO); Gessert, Timothy Arthur (Conifer, CO)

    1999-01-01

    A photovoltaic power conversion device has a top surface adapted to receive impinging radiation. The device includes at least two adjacent, serially connected cells. Each cell includes a semi-insulating substrate and a lateral conductivity layer of a first doped electrical conductivity disposed on the substrate. A base layer is disposed on the lateral conductivity layer and has the same electrical charge conductivity thereof. An emitter layer of a second doped electrical conductivity of opposite electrical charge is disposed on the base layer and forms a p-n junction therebetween. A plurality of spaced channels are formed in the emitter and base layers to expose the lateral conductivity layer at the bottoms thereof. A front contact grid is positioned on the top surface of the emitter layer of each cell. A first current collector is positioned along one outside edge of at least one first cell. A back contact grid is positioned in the channels at the top surface of the device for engagement with the lateral conductivity layer. A second current collector is positioned along at least one outside edge of at least one oppositely disposed second cell. Finally, an interdigitation mechanism is provided for serially connecting the front contact grid of one cell to the back contact grid of an adjacent cell at the top surface of the device.

  16. Large-Scale Field Study of Landfill Covers at Sandia National Laboratories

    SciTech Connect (OSTI)

    Dwyer, S.F.

    1998-09-01

    A large-scale field demonstration comparing final landfill cover designs has been constructed and is currently being monitored at Sandia National Laboratories in Albuquerque, New Mexico. Two conventional designs (a RCRA Subtitle `D' Soil Cover and a RCRA Subtitle `C' Compacted Clay Cover) were constructed side-by-side with four alternative cover test plots designed for dry environments. The demonstration is intended to evaluate the various cover designs based on their respective water balance performance, ease and reliability of construction, and cost. This paper presents an overview of the ongoing demonstration.

  17. Groundwater Strategy for the Ou-1 Landfill Area, Miamisburg Closure Project, Ohio

    SciTech Connect (OSTI)

    LOONEY, BRIANB.

    2004-01-01

    The general objective of the study was to assist the Miamisburg Closure Project in their efforts to develop and refine a comprehensive, technically sound strategy for remediation of groundwater contaminated with trichloroethylene and other volatile organic compounds in the vicinity of the landfill in Operable Unit 1. To provide the necessary flexibility to the site, regulators and stakeholders, the resulting evaluation considered a variety of approaches ranging from ''no further action'' to waste removal. The approaches also included continued soil vapor extraction, continued groundwater pump and treat, monitored natural attenuation, biostimulation, partitioning barriers, hydrologic modification, and others.

  18. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  19. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z. [Newton, MA

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  20. Biomass thermal conversion research at SERI

    SciTech Connect (OSTI)

    Milne, T. A.; Desrosiers, R. E.; Reed, T. B.

    1980-09-01

    SERI's involvement in the thermochemical conversion of biomass to fuels and chemicals is reviewed. The scope and activities of the Biomass Thermal Conversion and Exploratory Branch are reviewed. The current status and future plans for three tasks are presented: (1) Pyrolysis Mechanisms; (2) High Pressure O/sub 2/ Gasifier; and (3) Gasification Test Facility.

  1. Catalytic conversion of solar thermal produced pyrolysis gases to liquid fuels

    SciTech Connect (OSTI)

    Hanley, T.R.; Benham, C.B.

    1981-01-01

    The conversion of a simulated pyrolysis gas and synthesis gas using a Fischer-Tropsch catalyst system in a fluidized-bed reactor is investigated. Liquid fuels were produced between 550 and 660/sup 0/F (288 and 349/sup 0/C) for the simulated pyrolysis gas feed. An analysis of both liquid and gaseous product streams is performed. This investigation indicates a need for more extensive research with respect to hydrogen-to-carbon-monoxide usage ratios and with respect to the role of alkenes in fuel production.

  2. Nebraska Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Nebraska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  3. Missouri Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Missouri Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  4. Michigan Natural Gas Number of Gas and Gas Condensate Wells ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Michigan Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  5. Kentucky Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Kentucky Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  6. Mississippi Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Mississippi Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  7. Maryland Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Maryland Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  8. Louisiana Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Louisiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  9. Effect of landfill leachate organic acids on trace metal adsorption by kaolinite

    SciTech Connect (OSTI)

    Schroth, B.; Garrison, Sposito

    1997-02-01

    Hexanoic (hex) and fulvic acid (FA), representing early and later stages of landfill leachate evolution, were examined for influence on trace metal adsorption by a poorly crystallized kaolinite (KGa-2). Our experiments represented a model approach to examine possible reaction mechanisms in an environmentally important ternary metal-ligand-mineral surface system. Batch experiments were conducted in 0.01 mol kg(-1) NaClO4 at pH 3-8. Concentrations of metals (Cu, Cd, and Pb) and ligands were representative of those found typically in groundwater immediately downgradient of a landfill. The presence of FA resulted in enhancement of metal adsorption below pH 5, whereas the presence of hex produced no significant net change in metal uptake. Measured surface charge properties of KGa-2 were combined with binary and ternary system data in constructing a quantitative model of the system. The simple combination of binary system results was not effective in predicting the observed ternary system behavior. In both ternary systems, the addition of ternary surface complexes (TSCs) to the models resulted in a satisfactory fit to the data. Our work suggests the strong possibility that TSC involvement in surface reactions of natural adsorbents may be a useful concept.

  10. Operating limit study for the proposed solid waste landfill at Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Lee, D.W.; Wang, J.C.; Kocher, D.C.

    1995-06-01

    A proposed solid waste landfill at Paducah Gaseous Diffusion Plant (PGDP) would accept wastes generated during normal operations that are identified as non-radioactive. These wastes may include small amounts of radioactive material from incidental contamination during plant operations. A site-specific analysis of the new solid waste landfill is presented to determine a proposed operating limit that will allow for waste disposal operations to occur such that protection of public health and the environment from the presence of incidentally contaminated waste materials can be assured. Performance objectives for disposal were defined from existing regulatory guidance to establish reasonable dose limits for protection of public health and the environment. Waste concentration limits were determined consistent with these performance objectives for the protection of off-site individuals and inadvertent intruders who might be directly exposed to disposed wastes. Exposures of off-site individuals were estimated using a conservative, site-specific model of the groundwater transport of contamination from the wastes. Direct intrusion was analyzed using an agricultural homesteader scenario. The most limiting concentrations from direct intrusion or groundwater transport were used to establish the concentration limits for radionuclides likely to be present in PGDP wastes.

  11. Intrinsic in situ anaerobic biodegradation of chlorinated solvents at an industrial landfill

    SciTech Connect (OSTI)

    Lee, M.D.; Mazierski, P.F.; Buchanan, R.J. Jr.; Ellis, D.E.; Sehayek, L.S.

    1995-12-31

    The DuPont Necco Park Landfill in Niagara Falls, New York, is contaminated with numerous chlorinated solvents at concentrations of up to hundreds of mg/L in the groundwater. An extensive monitoring program was conducted to determine if intrinsic anaerobic biodegradation was occurring at the site, to determine what might limit this activity, and to characterize this activity with depth and distance away from the landfill. It was determined that anaerobic microbial activity was occurring in all zones, based upon the presence of intermediate products of the breakdown of the chlorinated solvents and the presence of final metabolic end products such as ethene and ethane. Aerobic, iron-reducing, manganese-reducing, sulfate-reducing, and methanogenic redox conditions were identified at the site. High levels of nitrogen and biodegradable organic compounds were present in most areas to support cometabolic anaerobic microbial activity against the chlorinated solvents. Intrinsic biodegradation is clearly evident and is effective in reducing the concentrations of chlorinated organic in the groundwater at the site. Groundwater modeling efforts during development of a site conceptual model indicated that microbial degradation was necessary to account for the downgradient reduction of chlorinated volatile organic compounds as compared to chloride, a conservative indicator parameter.

  12. Sanitary Landfill Groundwater Monitoring Report, Fourth Quarter 1999 and 1999 Summary

    SciTech Connect (OSTI)

    Chase, J.

    2000-03-13

    A maximum of thirty eight-wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill Area at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Water Permit DWP-087A and as part of the SRS Groundwater Monitoring Program. Iron (Total Recoverable), Chloroethene (Vinyl Chloride) and 1,1-Dichloroethane were the most widespread constituents exceeding the Final Primary Drinking Water Standards during 1999. Trichloroethylene, 1,1-Dichloroethylene, 1,2-Dichloroethane, 1,4-Dichlorobenzene, Aluminum (Total Recoverable), Benzene, cis-1,2-Dichloroethylene, Dichlorodifluoromethane, Dichloromethane (Methylene Chloride), Gross Alpha, Mercury (Total Recoverable), Nonvolatile Beta, Tetrachloroethylene, Total Organic Halogens, Trichlorofluoromethane, Tritium also exceeded standards in one or more wells. The groundwater flow direction in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill is to the southeast (universal transverse Mercator coordinates). The flow rate in this unit was approximately 144.175 ft/year during first quarter 1999 and 145.27 ft/year during fourth quarter 1999.

  13. Fuel Economy and Emissions of a Vehicle Equipped with an Aftermarket Flexible-Fuel Conversion Kit

    SciTech Connect (OSTI)

    Thomas, John F; Huff, Shean P; West, Brian H

    2012-04-01

    The U.S. Environmental Protection Agency (EPA) grants Certificates of Conformity for alternative fuel conversion systems and also offers other forms of premarket registration of conversion kits for use in vehicles more than two model years old. Use of alternative fuels such as ethanol, natural gas, and propane are encouraged by the Energy Policy Act of 1992. Several original equipment manufacturers (OEMs) produce emissions-certified vehicles capable of using alternative fuels, and several alternative fuel conversion system manufacturers produce EPA-approved conversion systems for a variety of alternative fuels and vehicle types. To date, only one manufacturer (Flex Fuel U.S.) has received EPA certifications for ethanol fuel (E85) conversion kits. This report details an independent evaluation of a vehicle with a legal installation of a Flex Fuel U.S. conversion kit. A 2006 Dodge Charger was baseline tested with ethanol-free certification gasoline (E0) and E20 (gasoline with 20 vol % ethanol), converted to flex-fuel operation via installation of a Flex Box Smart Kit from Flex Fuel U.S., and retested with E0, E20, E50, and E81. Test cycles included the Federal Test Procedure (FTP or city cycle), the highway fuel economy test (HFET), and the US06 test (aggressive driving test). Averaged test results show that the vehicle was emissions compliant on E0 in the OEM condition (before conversion) and compliant on all test fuels after conversion. Average nitrogen oxide (NOx) emissions exceeded the Tier 2/Bin 5 intermediate life NO{sub X} standard with E20 fuel in the OEM condition due to two of three test results exceeding this standard [note that E20 is not a legal fuel for non-flexible-fuel vehicles (non-FFVs)]. In addition, one E0 test result before conversion and one E20 test result after conversion exceeded the NOX standard, although the average result in these two cases was below the standard. Emissions of ethanol and acetaldehyde increased with increasing ethanol, while nonmethane organic gas and CO emissions remained relatively unchanged for all fuels and cycles. Higher fraction ethanol blends appeared to decrease NO{sub X} emissions on the FTP and HFET (after conversion). As expected, fuel economy (miles per gallon) decreased with increasing ethanol content in all cases.

  14. Alternative fuels and chemicals from synthesis gas

    SciTech Connect (OSTI)

    Unknown

    1998-08-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  15. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-03-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  16. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    Peter Tijrn

    2003-01-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  17. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    1999-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  18. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  19. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-01-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  20. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    2000-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  1. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-09-30

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  2. Proceedings of the 31. intersociety energy conversion engineering

    Office of Scientific and Technical Information (OSTI)

    conference. Volume 2: Conversion technologies, electro-chemical technologies, Stirling engines, thermal management (Conference) | SciTech Connect Proceedings of the 31. intersociety energy conversion engineering conference. Volume 2: Conversion technologies, electro-chemical technologies, Stirling engines, thermal management Citation Details In-Document Search Title: Proceedings of the 31. intersociety energy conversion engineering conference. Volume 2: Conversion technologies,

  3. Energy conversion & storage program. 1994 annual report

    SciTech Connect (OSTI)

    Cairns, E.J.

    1995-04-01

    The Energy Conversion and Storage Program investigates state-of-the-art electrochemistry, chemistry, and materials science technologies for: (1) development of high-performance rechargeable batteries and fuel cells; (2) development of high-efficiency thermochemical processes for energy conversion; (3) characterization of complex chemical processes and chemical species; (4) study and application of novel materials for energy conversion and transmission. Research projects focus on transport process principles, chemical kinetics, thermodynamics, separation processes, organic and physical chemistry, novel materials, and advanced methods of analysis.

  4. Energy Conversion & Storage Program, 1993 annual report

    SciTech Connect (OSTI)

    Cairns, E.J.

    1994-06-01

    The Energy Conversion and Storage Program applies chemistry and materials science principles to solve problems in: production of new synthetic fuels; development of high-performance rechargeable batteries and fuel cells; development of high-efficiency thermochemical processes for energy conversion; characterization of complex chemical processes and chemical species; and the study and application of novel materials for energy conversion and transmission. Projects focus on transport-process principles, chemical kinetics, thermodynamics, chemical kinetics, thermodynamics, separation processes, organic and physical chemistry, novel materials, and advanced methods of analysis.

  5. Task 3.3: Warm Syngas Cleanup and Catalytic Processes for Syngas Conversion to Fuels Subtask 3: Advanced Syngas Conversion to Fuels

    SciTech Connect (OSTI)

    Lebarbier Dagel, Vanessa M.; Li, J.; Taylor, Charles E.; Wang, Yong; Dagle, Robert A.; Deshmane, Chinmay A.; Bao, Xinhe

    2014-03-31

    This collaborative joint research project is in the area of advanced gasification and conversion, within the Chinese Academy of Sciences (CAS)-National Energy Technology Laboratory (NETL)-Pacific Northwest National Laboratory (PNNL) Memorandum of Understanding. The goal for this subtask is the development of advanced syngas conversion technologies. Two areas of investigation were evaluated: Sorption-Enhanced Synthetic Natural Gas Production from Syngas The conversion of synthetic gas (syngas) to synthetic natural gas (SNG) is typically catalyzed by nickel catalysts performed at moderate temperatures (275 to 325°C). The reaction is highly exothermic and substantial heat is liberated, which can lead to process thermal imbalance and destruction of the catalyst. As a result, conversion per pass is typically limited, and substantial syngas recycle is employed. Commercial methanation catalysts and processes have been developed by Haldor Topsoe, and in some reports, they have indicated that there is a need and opportunity for thermally more robust methanation catalysts to allow for higher per-pass conversion in methanation units. SNG process requires the syngas feed with a higher H2/CO ratio than typically produced from gasification processes. Therefore, the water-gas shift reaction (WGS) will be required to tailor the H2/CO ratio. Integration with CO2 separation could potentially eliminate the need for a separate WGS unit, thereby integrating WGS, methanation, and CO2 capture into one single unit operation and, consequently, leading to improved process efficiency. The SNG process also has the benefit of producing a product stream with high CO2 concentrations, which makes CO2 separation more readily achievable. The use of either adsorbents or membranes that selectively separate the CO2 from the H2 and CO would shift the methanation reaction (by driving WGS for hydrogen production) and greatly improve the overall efficiency and economics of the process. The scope of this activity was to develop methods and enabling materials for syngas conversion to SNG with readily CO2 separation. Suitable methanation catalyst and CO2 sorbent materials were developed. Successful proof-of-concept for the combined reaction-sorption process was demonstrated, which culminated in a research publication. With successful demonstration, a decision was made to switch focus to an area of fuels research of more interest to all three research institutions (CAS-NETL-PNNL). Syngas-to-Hydrocarbon Fuels through Higher Alcohol Intermediates There are two types of processes in syngas conversion to fuels that are attracting R&D interest: 1) syngas conversion to mixed alcohols; and 2) syngas conversion to gasoline via the methanol-to-gasoline process developed by Exxon-Mobil in the 1970s. The focus of this task was to develop a one-step conversion technology by effectively incorporating both processes, which is expected to reduce the capital and operational cost associated with the conversion of coal-derived syngas to liquid fuels. It should be noted that this work did not further study the classic Fischer-Tropsch reaction pathway. Rather, we focused on the studies for unique catalyst pathways that involve the direct liquid fuel synthesis enabled by oxygenated intermediates. Recent advances made in the area of higher alcohol synthesis including the novel catalytic composite materials recently developed by CAS using base metal catalysts were used.

  6. Integrating multi-criteria decision analysis for a GIS-based hazardous waste landfill sitting in Kurdistan Province, western Iran

    SciTech Connect (OSTI)

    Sharifi, Mozafar Hadidi, Mosslem Vessali, Elahe Mosstafakhani, Parasto Taheri, Kamal Shahoie, Saber Khodamoradpour, Mehran

    2009-10-15

    The evaluation of a hazardous waste disposal site is a complicated process because it requires data from diverse social and environmental fields. These data often involve processing of a significant amount of spatial information which can be used by GIS as an important tool for land use suitability analysis. This paper presents a multi-criteria decision analysis alongside with a geospatial analysis for the selection of hazardous waste landfill sites in Kurdistan Province, western Iran. The study employs a two-stage analysis to provide a spatial decision support system for hazardous waste management in a typically under developed region. The purpose of GIS was to perform an initial screening process to eliminate unsuitable land followed by utilization of a multi-criteria decision analysis (MCDA) to identify the most suitable sites using the information provided by the regional experts with reference to new chosen criteria. Using 21 exclusionary criteria, as input layers, masked maps were prepared. Creating various intermediate or analysis map layers a final overlay map was obtained representing areas for hazardous waste landfill sites. In order to evaluate different landfill sites produced by the overlaying a landfill suitability index system was developed representing cumulative effects of relative importance (weights) and suitability values of 14 non-exclusionary criteria including several criteria resulting from field observation. Using this suitability index 15 different sites were visited and based on the numerical evaluation provided by MCDA most suitable sites were determined.

  7. Leachate treatment system using constructed wetlands, Town of Fenton sanitary landfill, Broome County, New York. Final report

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    Municipal sanitary landfills generate leachate that New York State regulations require to be collected and treated to avoid contaminating surface water and groundwater. One option for treating leachate is to haul it to municipal wastewater treatment facility. This option may be expensive, may require excessive energy for transportation, and may require pretreatment to protect the receiving facility`s processes. An alternative is on-site treatment and discharge. Personnel from the Town of Fenton, New York; Hawk Engineering, P.C.; Cornell University; and Ithaca College designed, built, and operated a pilot constructed wetland for treating leachate at the Town of Fenton`s municipal landfill. The system, consisting of two overland flow beds and two subsurface flow beds has been effective for 18 months in reducing levels of ammonia (averaging 85% removal by volatilization and denitrification) and total iron (averaging 95% removal by precipitation and sedimentation), two key constituents of the Fenton landfill`s leachate. The system effects these reductions with zero chemical and energy inputs and minimal maintenance. A third key constituent of the leachate, manganese, apparently passes through the beds with minimal removal. Details and wetland considerations are described.

  8. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  9. Gas magnetometer

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2016-05-03

    Measurement of a precessional rate of a gas, such as an alkali gas, in a magnetic field is made by promoting a non-uniform precession of the gas in which substantially no net magnetic field affects the gas during a majority of the precession cycle. This allows sensitive gases that would be subject to spin-exchange collision de-phasing to be effectively used for extremely sensitive measurements in the presence of an environmental magnetic field such as the Earth's magnetic field.

  10. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  11. A Water Balance Study of Four Landfill Cover Designs at Material Disposal Area B in Los Alamos, New Mexico

    SciTech Connect (OSTI)

    David D. Breshears; Fairley J. Barnes; John W. Nyhan; Johnny A. Salazar

    1998-09-01

    The goal of disposing of low-level radioactive and hazardous waste in shallow landfills is to reduce risk to human health and the environment by isolating contaminants until they no longer pose an unacceptable hazard. In order to achieve this, the Department of Energy Environmental Restoration Program is comparing the performance of several different surface covers at Material Disposal Area (MDA) B in Los Alamos. Two conventional landfill were compared with an improved cover designed to minimize plant and animal intrusion and to minimize water infiltration into the underlying wastes. The conventional covers varied in depth and both conventional and improved designs had different combinations of vegetation (grass verses shrub) and gravel mulch (no mulch verses mulch). These treatments were applied to each of 12 plots and water balance parameters were measured from March1987 through June 1995. Adding a gravel mulch significantly influenced the plant covered field plots receiving no gravel mulch averaged 21.2% shrub cover, while plots with gravel had a 20% larger percent cover of shrubs. However, the influence of gravel mulch on the grass cover was even larger than the influence on shrub cover, average grass cover on the plots with no gravel was 16.3%, compared with a 42% increase in grass cover due to gravel mulch. These cover relationships are important to reduce runoff on the landfill cover, as shown by a regression model that predicts that as ground cover is increased from 30 to 90%,annual runoff is reduced from 8.8 to 0.98 cm-a nine-fold increase. We also found that decreasing the slope of the landfill cover from 6 to 2% reduced runoff from the landfill cover by 2.7-fold. To minimize the risk of hazardous waste from landfills to humans, runoff and seepage need to be minimized and evapotranspiration maximized on the landfill cover. This has to be accomplished for dry and wet years at MDA B. Seepage consisted of 1.9% and 6.2% of the precipitation in the average and once in ten year events, respectively, whereas corresponding values for runoff were 13% and 16%; these changes were accompanied by corresponding decreases in evapotranspiration, which accounted for 86% and only 78% of the precipitation occurring on the average and once in ten year even~ respectively.

  12. Advanced energy conversion methods for cold fusion

    SciTech Connect (OSTI)

    Prelas, M.A. )

    1989-09-01

    If cold fusion is verified, then the next important question deals with how it can be used to produce energy. Several direct energy conversion concepts for use with cold fusion are discussed.

  13. Hybrid staging of geothermal energy conversion process

    SciTech Connect (OSTI)

    Steidel, R.F. Jr.

    1984-05-07

    Progress in the demonstration of the feasibility of hybrid staging in geothermal energy conversion is described, particularly processes involving the Lysholm engine. The performance limitations of the Lysholm engine were studied. (MHR)

  14. Summer Series 2012 - Conversation with Kathy Yelick

    ScienceCinema (OSTI)

    Yelick, Kathy

    2013-06-24

    Jeff Miller, head of Public Affairs, sat down in conversation with Kathy Yelick, Associate Berkeley Lab Director, Computing Sciences, in the second of a series of "powerpoint-free" talks on July 18th 2012, at Berkeley Lab.

  15. BETO Conversion Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Breakout Session 2A-Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, ... a Refinery 2013 Peer Review Presentations-Bio-oil 2013 Peer Review Presnentations-Plenari...

  16. Summer Series 2012 - Conversation with Omar Yaghi

    ScienceCinema (OSTI)

    Omar Yaghi

    2013-06-24

    Jeff Miller, head of Public Affairs, sat down in conversation with Omar Yaghi, director of the Molecular Foundry, in the first of a series of "powerpoint-free" talks on July 11th 2012, at Berkeley Lab.

  17. MHK technologies include current energy conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    technologies include current energy conversion (CEC) devices, e.g., hydrokinetic turbines that extract power from water currents (riverine, tidal, and ocean) and wave energy conversion (WEC) devices that extract power from wave motion. Sandia's MHK research leverages decades of experience in engineering and design and analysis (D&A) of wind power technologies, and its vast research complex, including high-performance computing (HPC), advanced materials and coatings, nondestructive

  18. Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Conversions to someone by E-mail Share Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions on Facebook Tweet about Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions on Twitter Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions on Google Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions on Delicious Rank Alternative Fuels Data Center: Flexible Fuel Vehicle Conversions on Digg Find More places to share Alternative Fuels

  19. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Broader source: Energy.gov (indexed) [DOE]

    Energy Conversion for Efficient Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery ...

  20. A Single Multi-Functional Enzyme for Efficient Biomass Conversion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Return to Search A Single Multi-Functional Enzyme for Efficient Biomass Conversion ... Efficient conversion of lignocellulosic biomass, however, remains a challenge due to its ...

  1. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion of Waste Heat to Electricity in an IC Engine-Powered Vehicle Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle...

  2. Thermoelectric Conversion of Waste Heat to Electricity in an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermoelectric Systems Implemented in a Hybrid Configuration Thermoelectric Conversion of Waste Heat to Electricity in an IC Engine Powered Vehicle Thermoelectric Conversion of ...

  3. Pin stack array for thermoacoustic energy conversion (Patent...

    Office of Scientific and Technical Information (OSTI)

    Pin stack array for thermoacoustic energy conversion Title: Pin stack array for thermoacoustic energy conversion A thermoacoustic stack for connecting two heat exchangers in a ...

  4. SCE Societe de Conversion d Energie | Open Energy Information

    Open Energy Info (EERE)

    Societe de Conversion d Energie Jump to: navigation, search Name: SCE Societe de Conversion d'Energie Place: Reunion Island, France Product: PV project developer on Reunion Island,...

  5. Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient Recycling, and Wastewater Algae-to-Fuel: Integrating Thermochemical Conversion, Nutrient Recycling, and Wastewater ...

  6. Conversion and Resource Evaluation Ltd CARE | Open Energy Information

    Open Energy Info (EERE)

    is an independent company providing specialist technical and economic services in the bio-energy and waste conversion sector. References: Conversion and Resource Evaluation Ltd...

  7. Golden Fuel Systems formerly Greasel Conversions Inc | Open Energy...

    Open Energy Info (EERE)

    Fuel Systems formerly Greasel Conversions Inc Jump to: navigation, search Name: Golden Fuel Systems (formerly Greasel Conversions Inc) Place: Drury, Montana Zip: 65638 Sector:...

  8. Multiple-Reheat Brayton Cycles for Nuclear Power Conversion with...

    Office of Scientific and Technical Information (OSTI)

    Brayton Cycles for Nuclear Power Conversion with Molten Coolants Citation Details In-Document Search Title: Multiple-Reheat Brayton Cycles for Nuclear Power Conversion with ...

  9. Novel Energy Conversion Equipment for Low Temperature Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Energy Conversion Equipment for Low Temperature Geothermal Resources Novel Energy Conversion Equipment for Low Temperature Geothermal Resources Project objective: Develop ...

  10. University of Delaware Institute of Energy Conversion | Open...

    Open Energy Info (EERE)

    Institute of Energy Conversion Jump to: navigation, search Name: University of Delaware Institute of Energy Conversion Place: Delaware Product: String representation "University...

  11. Project Profile: Brayton Solar Power Conversion System | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Power Conversion System Project Profile: Brayton Solar Power Conversion System Brayton Energy logo Brayton Energy, under the CSP R&D FOA, is looking to demonstrate the ...

  12. Process Design and Economics for Biochemical Conversion of Lignocellul...

    Office of Scientific and Technical Information (OSTI)

    This report describes one potential biochemical ethanol conversion process, conceptually based upon core conversion and process integration research at NREL. The overarching ...

  13. Global Waste to Energy Conversion Company GWECC | Open Energy...

    Open Energy Info (EERE)

    Waste to Energy Conversion Company GWECC Jump to: navigation, search Name: Global Waste to Energy Conversion Company (GWECC) Place: Washington, DC Product: GWECC is a global...

  14. Novel Vertimass Catalyst for Conversion of Ethanol and Other...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks Novel Vertimass Catalyst for Conversion of Ethanol ...

  15. Biological Conversion of Sugars to Hydrocarbons Technology Pathway...

    Office of Scientific and Technical Information (OSTI)

    Biological Conversion of Sugars to Hydrocarbons Technology Pathway Citation Details In-Document Search Title: Biological Conversion of Sugars to Hydrocarbons Technology Pathway ...

  16. MHK Technologies/Mobil Stabilized Energy Conversion Platform...

    Open Energy Info (EERE)

    Mobil Stabilized Energy Conversion Platform < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Mobil Stabilized Energy Conversion Platform.jpg...

  17. Light-Material Interactions in Energy Conversion - Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New approaches to full spectrum solar energy conversion California Institute of Technology ... Panel Discussion: Enabling Science for Full Spectrum Conversion Harry Atwater Harry ...

  18. Light-Material Interactions in Energy Conversion - Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New approaches to full spectrum solar energy conversion California Institute of Technology ... offer this free public webinar on New Approaches to Full Spectrum Solar Energy Conversion. ...

  19. Light-Material Interactions in Energy Conversion - Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2: Solar Spectrum Control and Conversion RG Leader: John Rogers Affiliated PIs: Paul ... in solar energy conversion efficiency is via exploitation of the full solar spectrum. ...

  20. Light-Material Interactions in Energy Conversion - Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lectures from the LMI-EFRC "New Approaches to Full Spectrum Solar Energy Conversion" ... Discussion: Enabling Science for Full Spectrum Conversion Harry Atwater, California ...